WorldWideScience

Sample records for situ atmospheric observations

  1. New Platforms for Suborbital Astronomical Observations and In Situ Atmospheric Measurements: Spacecraft, Instruments, and Facilities

    Science.gov (United States)

    Rodway, K.; DeForest, C. E.; Diller, J.; Vilas, F.; Sollitt, L. S.; Reyes, M. F.; Filo, A. S.; Anderson, E.

    2014-12-01

    Suborbital astronomical observations have over 50 years' history using NASA's sounding rockets and experimental space planes. The new commercial space industry is developing suborbital reusable launch vehicles (sRLV's) to provide low-cost, flexible, and frequent access to space at ~100 km altitude. In the case of XCOR Aerospace's Lynx spacecraft, the vehicle design and capabilities work well for hosting specially designed experiments that can be flown with a human-tended researcher or alone with the pilot on a customized mission. Some of the first-generation instruments and facilities that will conduct solar observations on dedicated Lynx science missions include the SwRI Solar Instrument Pointing Platform (SSIPP) and Atsa Suborbital Observatory, as well as KickSat sprites, which are picosatellites for in situ atmospheric and solar phenomena measurements. The SSIPP is a demonstration two-stage pointed solar observatory that operates inside the Lynx cockpit. The coarse pointing stage includes the pilot in the feedback loop, and the fine stage stabilizes the solar image to achieve arcsecond class pointing. SSIPP is a stepping-stone to future external instruments that can operate with larger apertures and shorter wavelengths in the solar atmosphere. The Planetary Science Institute's Atsa Suborbital Observatory combines the strengths of ground-based observatories and space-based observing to create a facility where a telescope is maintained and used interchangeably with either in-house facility instruments or user-provided instruments. The Atsa prototype is a proof of concept, hand-guided camera that mounts on the interior of the Lynx cockpit to test target acquisition and tracking for human-operated suborbital astronomy. KickSat sprites are mass-producible, one inch printed circuit boards (PCBs) populated by programmable off the shelf microprocessors and radios for real time data transmission. The sprite PCBs can integrate chip-based radiometers, magnetometers

  2. Simultaneous Observations of Atmospheric Tides from Combined in Situ and Remote Observations at Mars from the MAVEN Spacecraft

    Science.gov (United States)

    England, Scott L.; Liu, Guiping; Withers, Paul; Yigit, Erdal; Lo, Daniel; Jain, Sonal; Schneider, Nicholas M. (Inventor); Deighan, Justin; McClintock, William E.; Mahaffy, Paul R.; hide

    2016-01-01

    We report the observations of longitudinal variations in the Martian thermosphere associated with nonmigrating tides. Using the Neutral Gas Ion Mass Spectrometer (NGIMS) and the Imaging Ultraviolet Spectrograph (IUVS) on NASA's Mars Atmosphere and Volatile EvolutioN Mission (MAVEN) spacecraft, this study presents the first combined analysis of in situ and remote observations of atmospheric tides at Mars for overlapping volumes, local times, and overlapping date ranges. From the IUVS observations, we determine the altitude and latitudinal variation of the amplitude of the nonmigrating tidal signatures, which is combined with the NGIMS, providing information on the compositional impact of these waves. Both the observations of airglow from IUVS and the CO2 density observations from NGIMS reveal a strong wave number 2 signature in a fixed local time frame. The IUVS observations reveal a strong latitudinal dependence in the amplitude of the wave number 2 signature. Combining this with the accurate CO2 density observations from NGIMS, this would suggest that the CO2 density variation is as high as 27% at 0-10 deg latitude. The IUVS observations reveal little altitudinal dependence in the amplitude of the wave number 2 signature, varying by only 20% from 160 to 200 km. Observations of five different species with NGIMS show that the amplitude of the wave number 2 signature varies in proportion to the inverse of the species scale height, giving rise to variation in composition as a function of longitude. The analysis and discussion here provide a roadmap for further analysis as additional coincident data from these two instruments become available.

  3. B33C-0612: Evaluation of Simulated Biospheric Carbon Dioxide Fluxes and Atmospheric Concentrations Using Global in Situ Observations

    Science.gov (United States)

    Philip, Sajeev; Johnson, Matthew S.; Potter, Christopher S.; Genovese, Vanessa

    2016-01-01

    Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emission sources and biospheric sources/sinks. Global biospheric fluxes of CO2 are controlled by complex processes facilitating the exchange of carbon between terrestrial ecosystems and the atmosphere. These processes which play a key role in these terrestrial ecosystem-atmosphere carbon exchanges are currently not fully understood, resulting in large uncertainties in the quantification of biospheric CO2 fluxes. Current models with these inherent deficiencies have difficulties simulating the global carbon cycle with high accuracy. We are developing a new modeling platform, GEOS-Chem-CASA by integrating the year-specific NASA-CASA (National Aeronautics and Space Administration - Carnegie Ames Stanford Approach) biosphere model with the GEOS-Chem (Goddard Earth Observation System-Chemistry) chemical transport model to improve the simulation of atmosphere-terrestrial ecosystem carbon exchange. We use NASA-CASA to explicitly represent the exchange of CO2 between terrestrial ecosystem and atmosphere by replacing the baseline GEOS-Chem land net CO2 flux and forest biomass burning CO2 emissions. We will present the estimation and evaluation of these "bottom-up" land CO2 fluxes, simulated atmospheric mixing ratios, and forest disturbance changes over the last decade. In addition, we will present our initial comparison of atmospheric column-mean dry air mole fraction of CO2 predicted by the model and those retrieved from NASA's OCO-2 (Orbiting Carbon Observatory-2) satellite instrument and model-predicted surface CO2 mixing ratios with global in situ observations. This evaluation is the first step necessary for our future work planned to constrain the estimates of biospheric carbon fluxes through "top-down" inverse modeling, which will improve our understanding of the processes controlling atmosphere-terrestrial ecosystem greenhouse gas exchanges, especially over regions which lack in

  4. Evaluating the skills of isotope-enabled general circulation models against in situ atmospheric water vapor isotope observations

    DEFF Research Database (Denmark)

    Steen-Larsen, Hans Christian; Risi, C.; Werner, M.

    2017-01-01

    The skills of isotope-enabled general circulation models are evaluated against atmospheric water vapor isotopes. We have combined in situ observations of surface water vapor isotopes spanning multiple field seasons (2010, 2011, and 2012) from the top of the Greenland Ice Sheet (NEEM site: 77.45°N......: 2014). This allows us to benchmark the ability to simulate the daily water vapor isotope variations from five different simulations using isotope-enabled general circulation models. Our model-data comparison documents clear isotope biases both on top of the Greenland Ice Sheet (1-11% for δ18O and 4...... boundary layer water vapor isotopes of the Baffin Bay region show strong influence on the water vapor isotopes at the NEEM deep ice core-drilling site in northwest Greenland. Our evaluation of the simulations using isotope-enabled general circulation models also documents wide intermodel spatial...

  5. Comparative analysis of atmosphere temperature variability for Northern Eurasia based on the Reanalysis and in-situ observed data

    Science.gov (United States)

    Shulgina, T.; Genina, E.; Gordov, E.; Nikitchuk, K.

    2009-04-01

    At present numerous data archives which include meteorological observations as well as climate processes modeling data are available for Earth Science specialists. Methods of mathematical statistics are widely used for their processing and analysis. In many cases they represent the only way of quantitative assessment of the meteorological and climatic information. Unified set of analysis methods allows us to compare climatic characteristics calculated on the basis of different datasets with the purpose of performing more detailed analysis of climate dynamics for both regional and global levels. The report presents the results of comparative analysis of atmosphere temperature behavior for the Northern Eurasia territory for the period from 1979 to 2004 based on the NCEP/NCAR Reanalysis, NCEP/DOE Reanalysis AMIP II, JMA/CRIEPI JRA-25 Reanalysis, ECMWF ERA-40 Reanalysis data and observation data obtained from meteorological stations of the former Soviet Union. Statistical processing of atmosphere temperature data included analysis of time series homogeneity of climate indices approved by WMO, such as "Number of frost days", "Number of summer days", "Number of icing days", "Number of tropical nights", etc. by means of parametric methods of mathematical statistics (Fisher and Student tests). That allowed conducting comprehensive research of spatio-temporal features of the atmosphere temperature. Analysis of the atmosphere temperature dynamics revealed inhomogeneity of the data obtained for large observation intervals. Particularly, analysis performed for the period 1979 - 2004 showed the significant increase of the number of frost and icing days approximately by 1 day for every 2 years and decrease roughly by 1 day for 2 years for the number of summer days. Also it should be mentioned that the growth period mean temperature have increased by 1.5 - 2° C for the time period being considered. The usage of different Reanalysis datasets in conjunction with in-situ observed

  6. Comparison of atmospheric CH4 concentration observed by GOSAT and in-situ measurements in Thailand and India

    Science.gov (United States)

    Hayashida, S.; Ono, A.; Ishikawa, S.; Terao, Y.; Takeuchi, W.

    2012-12-01

    The concentration of atmospheric methane (CH4) has more than doubled since pre-industrial levels and the observed long-term changes in the CH4 concentration have been attributed to anthropogenic activity. However, despite the importance of atmospheric CH4 in global warming, the strength of individual sources of CH4 remains highly uncertain [e.g.,Dlugokencky et al., 2011]. To characterize and quantify the emissions of CH4 especially in Monsoon Asia and Siberia, which are the most important regions as CH4 source, we started a new project, "Characterization and Quantification of global methane emissions by utilizing GOSAT and in-situ measurements " by support of the Environment Research and Technology Development Fund (ERTDF) from June 2012 under the umbrella of Ministry of Environment Japan. The projects includes (1) satellite data applications, (2) in-situ measurements in Siberia, over Western Pacific and in Monsoon Asia, (3) development of the inverse model to derive CH4 emissions by top-down approach, and (4) flux measurements in Siberia and Asia to improve the bottom-up inventories. As an initiatory approach in the project, we started air sampling in Thailand and India where there are only a few CH4 data of direct sampling with high precision. We took eight air samples at Kohn Kaen and Pimai in Thailand on June 9 and 10, 2012. The high CH4 concentration near rice paddy field contrasted to the lower CH4 concentration near Cassava field. We are planning to take more samples in India in mid-August. The satellite CH4 data including GOSAT and SCIAMACHY are also compared with the Land Surface Water Coverage (LSWC) and the Normalized Difference Vegetation Index (NDVI). The analysis revealed the seasonal variation in of xCH4 is closely related to the variation of the LSWC, coupled with NDVI. However, the satellite measurements are all column-averaged mixing ratio (xCH4), and therefore do not necessarily reflect high CH4 concentration near the surface over the emission

  7. First ever in situ observations of Venus' polar upper atmosphere density using the tracking data of the Venus Express Atmospheric Drag Experiment (VExADE)

    Science.gov (United States)

    Rosenblatt, P.; Bruinsma, S. L.; Müller-Wodarg, I. C. F.; Häusler, B.; Svedhem, H.; Marty, J. C.

    2012-02-01

    On its highly elliptical 24 h orbit around Venus, the Venus Express (VEX) spacecraft briefly reaches a periapsis altitude of nominally 250 km. Recently, however, dedicated and intense radio tracking campaigns have taken place in August 2008, October 2009, February and April 2010, for which the periapsis altitude was lowered to the 186-176 km altitude range in order to be able to probe the upper atmosphere of Venus above the North Pole for the first time ever in situ. As the spacecraft experiences atmospheric drag, its trajectory is measurably perturbed during the periapsis pass, allowing us to infer total atmospheric mass density at the periapsis altitude. A Precise Orbit Determination (POD) of the VEX motion is performed through an iterative least-squares fitting process to the Doppler tracking data, acquired by the VEX radioscience experiment (VeRa). The drag acceleration is modelled using an initial atmospheric density model (VTS3 model, Hedin, A.E., Niemann, H.B., Kasprzak, W.T., Seiff, A. [1983]. J. Geophys. Res. 88, 73-83). A scale factor of the drag acceleration is estimated for each periapsis pass, which scales Hedin's density model in order to best fit the radio tracking data. Reliable density scale factors have been obtained for 10 passes mainly from the second (October 2009) and third (April 2010) VExADE campaigns, which indicate a lower density by a factor of about 1.8 than Hedin's model predicts. These first ever in situ polar density measurements at solar minimum have allowed us to construct a diffusive equilibrium density model for Venus' thermosphere, constrained in the lower thermosphere primarily by SPICAV-SOIR measurements and above 175 km by the VExADE drag measurements (Müller-Wodarg et al., in preparation). The preliminary results of the VExADE campaigns show that it is possible to obtain with the POD technique reliable estimates of Venus' upper atmosphere densities at an altitude of around 175 km. Future VExADE campaigns will benefit from

  8. Global atmospheric budget of acetaldehyde: 3-D model analysis and constraints from in-situ and satellite observations

    Directory of Open Access Journals (Sweden)

    D. B. Millet

    2010-04-01

    Full Text Available We construct a global atmospheric budget for acetaldehyde using a 3-D model of atmospheric chemistry (GEOS-Chem, and use an ensemble of observations to evaluate present understanding of its sources and sinks. Hydrocarbon oxidation provides the largest acetaldehyde source in the model (128 Tg a−1, a factor of 4 greater than the previous estimate, with alkanes, alkenes, and ethanol the main precursors. There is also a minor source from isoprene oxidation. We use an updated chemical mechanism for GEOS-Chem, and photochemical acetaldehyde yields are consistent with the Master Chemical Mechanism. We present a new approach to quantifying the acetaldehyde air-sea flux based on the global distribution of light absorption due to colored dissolved organic matter (CDOM derived from satellite ocean color observations. The resulting net ocean emission is 57 Tg a−1, the second largest global source of acetaldehyde. A key uncertainty is the acetaldehyde turnover time in the ocean mixed layer, with quantitative model evaluation over the ocean complicated by known measurement artifacts in clean air. Simulated concentrations in surface air over the ocean generally agree well with aircraft measurements, though the model tends to overestimate the vertical gradient. PAN:NOx ratios are well-simulated in the marine boundary layer, providing some support for the modeled ocean source. We introduce the Model of Emissions of Gases and Aerosols from Nature (MEGANv2.1 for acetaldehyde and ethanol and use it to quantify their net flux from living terrestrial plants. Including emissions from decaying plants the total direct acetaldehyde source from the land biosphere is 23 Tg a−1. Other terrestrial acetaldehyde sources include biomass burning (3 Tg a−1 and anthropogenic emissions (2 Tg a−1. Simulated concentrations in the continental boundary layer are generally unbiased and capture the spatial

  9. Remote Sensing and In-Situ Observations of Arctic Mixed-Phase and Cirrus Clouds Acquired During Mixed-Phase Arctic Cloud Experiment: Atmospheric Radiation Measurement Uninhabited Aerospace Vehicle Participation

    International Nuclear Information System (INIS)

    McFarquhar, G.M.; Freer, M.; Um, J.; McCoy, R.; Bolton, W.

    2005-01-01

    The Atmospheric Radiation Monitor (ARM) uninhabited aerospace vehicle (UAV) program aims to develop measurement techniques and instruments suitable for a new class of high altitude, long endurance UAVs while supporting the climate community with valuable data sets. Using the Scaled Composites Proteus aircraft, ARM UAV participated in Mixed-Phase Arctic Cloud Experiment (M-PACE), obtaining unique data to help understand the interaction of clouds with solar and infrared radiation. Many measurements obtained using the Proteus were coincident with in-situ observations made by the UND Citation. Data from M-PACE are needed to understand interactions between clouds, the atmosphere and ocean in the Arctic, critical interactions given large-scale models suggest enhanced warming compared to lower latitudes is occurring

  10. In situ TEM observation of the Boudouard reaction: Multi-layered graphene formation from CO on cobalt nanoparticles at atmospheric pressure

    NARCIS (Netherlands)

    Bremmer, G.M.; Zacharaki, E.; Sjåstad, A.O.; Navarro, V.; Frenken, J.W.M.; Kooyman, P.J.

    2017-01-01

    Using a MEMS nanoreactor in combination with a specially designed in situ Transmission Electron Microscope (TEM) holder and gas supply system, we imaged the formation of multiple layers of graphene encapsulating a cobalt nanoparticle, at 1 bar CO:N2 (1:1) and 500 °C. The cobalt nanoparticle was

  11. Changes of atmospheric properties over Belgrade, observed using remote sensing and in situ methods during the partial solar eclipse of 20 March 2015

    Science.gov (United States)

    Ilić, L.; Kuzmanoski, M.; Kolarž, P.; Nina, A.; Srećković, V.; Mijić, Z.; Bajčetić, J.; Andrić, M.

    2018-06-01

    Measurements of atmospheric parameters were carried out during the partial solar eclipse (51% coverage of solar disc) observed in Belgrade on 20 March 2015. The measured parameters included height of the planetary boundary layer (PBL), meteorological parameters, solar radiation, surface ozone and air ions, as well as Very Low Frequency (VLF, 3-30 kHz) and Low Frequency (LF, 30-300 kHz) signals to detect low-ionospheric plasma perturbations. The observed decrease of global solar and UV-B radiation was 48%, similar to the solar disc coverage. Meteorological parameters showed similar behavior at two measurement sites, with different elevations and different measurement heights. Air temperature change due to solar eclipse was more pronounced at the lower measurement height, showing a decrease of 2.6 °C, with 15-min time delay relative to the eclipse maximum. However, at the other site temperature did not decrease; its morning increase ceased with the start of the eclipse, and continued after the eclipse maximum. Relative humidity at both sites remained almost constant until the eclipse maximum and then decreased as the temperature increased. The wind speed decreased and reached minimum 35 min after the last contact. The eclipse-induced decrease of PBL height was about 200 m, with minimum reached 20 min after the eclipse maximum. Although dependent on UV radiation, surface ozone concentration did not show the expected decrease, possibly due to less significant influence of photochemical reactions at the measurement site and decline of PBL height. Air-ion concentration decreased during the solar eclipse, with minimum almost coinciding with the eclipse maximum. Additionally, the referential Line-of-Sight (LOS) radio link was set in the area of Belgrade, using the carrier frequency of 3 GHz. Perturbation of the receiving signal level (RSL) was observed on March 20, probably induced by the solar eclipse. Eclipse-related perturbations in ionospheric D-region were detected

  12. Infrared observations of planetary atmospheres

    International Nuclear Information System (INIS)

    Orton, G.S.; Baines, K.H.; Bergstralh, J.T.

    1988-01-01

    The goal of this research in to obtain infrared data on planetary atmospheres which provide information on several aspects of structure and composition. Observations include direct mission real-time support as well as baseline monitoring preceding mission encounters. Besides providing a broader information context for spacecraft experiment data analysis, observations will provide the quantitative data base required for designing optimum remote sensing sequences and evaluating competing science priorities. In the past year, thermal images of Jupiter and Saturn were made near their oppositions in order to monitor long-term changes in their atmospheres. Infrared images of the Jovian polar stratospheric hot spots were made with IUE observations of auroral emissions. An exploratory 5-micrometer spectrum of Uranus was reduced and accepted for publication. An analysis of time-variability of temperature and cloud properties of the Jovian atomsphere was made. Development of geometric reduction programs for imaging data was initiated for the sun workstation. Near-infrared imaging observations of Jupiter were reduced and a preliminary analysis of cloud properties made. The first images of the full disk of Jupiter with a near-infrared array camera were acquired. Narrow-band (10/cm) images of Jupiter and Saturn were obtained with acousto-optical filters

  13. In situ TEM observation of solid-gas reactions

    International Nuclear Information System (INIS)

    Kishita, K; Kamino, T; Watabe, A; Kuroda, K; Saka, H

    2008-01-01

    Under a gaseous atmosphere at high temperatures, almost all the materials (metal, catalysts, etc.) change their structures and properties. For the research and development of materials, it is of vital importance to clarify mechanisms of solid-gas and liquid-gas reactions. Recently an in situ TEM system combined with an environmental holder, which has a gas injection nozzle close to a specimen-heating element, has been developed. The gas injection nozzle permits gas to flow around the specimens sitting on the heating element made of a fine W filament. The newly developed in situ TEM has a differential pumping system; therefore, the pressure in the specimen chamber is maintained in the range of higher than 1 Pa, while the pressure in the electron gun chamber can be kept in the range of 10 -5 Pa. This system was applied to in situ observation of chemical reactions of metals with gases: Observation of oxidation and reduction under a gas pressure ranging from 10 -5 Pa to 1 Pa at high temperatures (room temperature to ∼1473 K) were successfully carried out on pure metal and rare metal catalysts at near-atomic resolution. This in situ environmental TEM system is promising for clarifying mechanisms of many solid-gas and liquid-gas reactions that take place at high temperatures under a gas atmosphere.

  14. ESTABLISHING THE PAN-EURASIAN EXPERIMENT (PEEX LAND-ATMOSPHERE IN SITU OBSERVATION NETWORK ACROSS THE NORTHERN EURASIAN ARCTIC-BOREAL REGIONS ‒ INTRODUCTION TO THE RUSSIAN STATIONS’ METADATA ENQUIRY

    Directory of Open Access Journals (Sweden)

    H. K. Lappalainen

    2017-01-01

    Full Text Available Pan-Eurasian Experiment (PEEX initiative (https://www.atm.helsinki.fi/peex/, initiated in 2012, is an international, multidisciplinary, multiscale program focused on solving interlinked global challenges influencing societies in the Northern Eurasian region and in China. As a part of the program, PEEX is aimed to establish an in situ observation network, which would cover environments from the Arctic coastal regions, tundra to boreal forests, from pristine to urban megacities. The PEEX network will be based on two components: (i the existing stations activities and (ii establishing new stations. The upgrading plans of the existing stations as well as the new stations will be based on a SMEAR (Stations for Measuring Earth surface ‒ Atmosphere Relations concept. The development of the coordinated, comprehensive PEEX observation network is contributing to the sustainable development of the Northern Eurasian regions. It is aimed at providing quantified information on climate relevant variables for the research communities and for constructing services, such as early warning systems, for the society.

  15. Observations and Modeling of Atmospheric Radiance Structure

    National Research Council Canada - National Science Library

    Wintersteiner, Peter

    2001-01-01

    The overall purpose of the work that we have undertaken is to provide new capabilities for observing and modeling structured radiance in the atmosphere, particularly the non-LTE regions of the atmosphere...

  16. Millimeter Wave Atmospheric Radiometry Observations.

    Science.gov (United States)

    1981-03-27

    structure of the atmosphere would be very important. Rufton [20] combined thermal sensor technology for microthermal measurements with radiosonde...fromT2 h n relationships with CT(h) at least for optical effects. Bufton obtained the mean-square temperature difference between two microthermal probes

  17. Coarsening of Pd nanoparticles in an oxidizing atmosphere studied by in situ TEM

    DEFF Research Database (Denmark)

    Simonsen, Søren Bredmose; Chorkendorff, Ib; Dahl, Søren

    2016-01-01

    The coarsening of supported palladium nanoparticles in an oxidizing atmosphere was studied in situ by means of transmission electron microscopy (TEM). Specifically, the Pd nanoparticles were dispersed on a planar and amorphous Al2O3 support and were observed during the exposure to 10 mbar technical...... for the Ostwald ripening process indicates that the observed change in the particle size distribution can be accounted for by wetting of the Al2O3 support by the larger Pd nanoparticles....

  18. Multiangle lidar observations of the Atmosphere

    Science.gov (United States)

    Lalitkumar Prakash, Pawar; Choukiker, Yogesh Kumar; Raghunath, K.

    2018-04-01

    Atmospheric Lidars are used extensively to get aerosol parameters like backscatter coefficient, backscatter ratio etc. National Atmospheric Research Laboratory, Gadanki (13°N, 79°E), India has a powerful lidar which has alt-azimuth capability. Inversion method is applied to data from observations of lidar system at different azimuth and elevation angles. Data Analysis is described and Observations in 2D and 3D format are discussed. Presence of Cloud and the variation of backscatter parameters are seen in an interesting manner.

  19. Multiangle lidar observations of the Atmosphere

    Directory of Open Access Journals (Sweden)

    Lalitkumar Prakash Pawar

    2018-01-01

    Full Text Available Atmospheric Lidars are used extensively to get aerosol parameters like backscatter coefficient, backscatter ratio etc. National Atmospheric Research Laboratory, Gadanki (13°N, 79°E, India has a powerful lidar which has alt-azimuth capability. Inversion method is applied to data from observations of lidar system at different azimuth and elevation angles. Data Analysis is described and Observations in 2D and 3D format are discussed. Presence of Cloud and the variation of backscatter parameters are seen in an interesting manner.

  20. Ground-based observations of exoplanet atmospheres

    NARCIS (Netherlands)

    Mooij, Ernst Johan Walter de

    2011-01-01

    This thesis focuses on the properties of exoplanet atmospheres. The results for ground-based near-infrared secondary eclipse observations of three different exoplanets, TrES-3b, HAT-P-1b and WASP-33b, are presented which have been obtained with ground-based telescopes as part of the GROUSE project.

  1. MAVEN Observations of Atmospheric Loss at Mars

    Science.gov (United States)

    Curry, Shannon; Luhmann, Janet; Jakosky, Bruce M.; Brain, David; LeBlanc, Francis; Modolo, Ronan; Halekas, Jasper S.; Schneider, Nicholas M.; Deighan, Justin; McFadden, James; Espley, Jared R.; Mitchell, David L.; Connerney, J. E. P.; Dong, Yaxue; Dong, Chuanfei; Ma, Yingjuan; Cohen, Ofer; Fränz, Markus; Holmström, Mats; Ramstad, Robin; Hara, Takuya; Lillis, Robert J.

    2016-06-01

    The Mars Atmosphere and Volatile EvolutioN (MAVEN) mission has been making observations of the Martian upper atmosphere and its escape to space since November 2014. The subject of atmospheric loss at terrestrial planets is a subject of intense interest not only because of the implications for past and present water reservoirs, but also for its impacts on the habitability of a planet. Atmospheric escape may have been especially effective at Mars, relative to Earth or Venus, due to its smaller size as well as the lack of a global dynamo magnetic field. Not only is the atmosphere less gravitationally bound, but also the lack of global magnetic field allows the impinging solar wind to interact directly with the Martian atmosphere. When the upper atmosphere is exposed to the solar wind, planetary neutrals can be ionized and 'picked up' by the solar wind and swept away.Both neutral and ion escape have played significant roles the long term climate change of Mars, and the MAVEN mission was designed to directly measure both escaping planetary neutrals and ions with high energy, mass, and time resolution. We will present 1.5 years of observations of atmospheric loss at Mars over a variety of solar and solar wind conditions, including extreme space weather events. We will report the average ion escape rate and the spatial distribution of escaping ions as measured by MAVEN and place them in context both with previous measurements of ion loss by other spacecraft (e.g. Phobos 2 and Mars Express) and with estimates of neutral escape rates by MAVEN. We will then report on the measured variability in ion escape rates with different drivers (e.g. solar EUV, solar wind pressure, etc.) and the implications for the total ion escape from Mars over time. Additionally, we will also discuss the implications for atmospheric escape at exoplanets, particularly weakly magnetized planetary bodies orbiting M-dwarfs, and the dominant escape mechanisms that may drive atmospheric erosion in other

  2. Global Observations of Inorganic Gases in the Remote Atmosphere - First Observations from the Atmospheric Tomography Mission (ATom)

    Science.gov (United States)

    Veres, P. R.; Neuman, J. A.

    2017-12-01

    The Atmospheric Tomography Mission (ATom) is a NASA field program that investigates the impact of human emissions on air quality and climate in remote regions of the atmosphere. NASA DC-8 flights during the ATom sampled the atmosphere over the Pacific and Atlantic Oceans, up to 12 km altitude and nearly from pole to pole. New observations of key species (e.g. N2O5, reactive halogens, nitrous acid) in these regions are provided during the third deployment of the NASA DC-8 research aircraft (October, 2017) by the NOAA iodide ion time-of-flight chemical ionization mass spectrometer (iCIMS). In this study, we will present the first observations of inorganic gas-phase species using iCIMS from the ATom 3 deployment. Laboratory results detailing the instrument performance including inlet response times, background characterization and sensitivity will be presented. We will show vertical profiles of newly measured trace gases derived from in-situ observations, and discuss the potential impact on the NOx, NOy and reactive halogen budgets.

  3. Observation of Atmospheric Constituents From Space

    Science.gov (United States)

    Burrows, J. P.

    Remote sensing of the atmosphere from space is a growing research field. Surprisingly but for good physical reasons, the mesosphere and stratosphere are easier to probe from space than the troposphere. GOME (Global Ozone Monitoring Experiment) and SCIAMACHY (Scanning Imaging absorption spectroMeter for Atmospheric CHartographY) are related European instruments, which were proposed and been designed to measure atmospheric constituents (gases, aerosols and clouds) by passive remote sensing of the up-welling solar radiation leaving atmosphere. GOME is a smaller version of SCIAMACHY and was launched as part of the core payload of the second European research satellite (ERS-2) on the 20th April 1995. GOME comprises four spectral channels and measures simultaneously the earthshine radiance or solar extra terrestrial irradiance between 240 and 790 nm. Inversion of GOME measurements using the DOAS (Differential Optical Absorption Spectroscopy) yields the total column of trace gases (e.g. O3, NO2, HCHO, BrO and OClO). Application of the FURM (Full Retrieval Method) enables the profiles of O3 to be retrieved. One of the important achievements of GOME has been the separation of tropopsheirc columns of trace gases using TEM (Tropospheric Excess Method). SCIAMACHY has been developed as Germa n, Dutch and Belgian contribution to ENVISAT. It has significantly enhanced capability compared to GOME, measuring a larger spectral range, 220-2380 nm, and observing in alternate nadir and limb modes as well as solar and lunar occultation. ENVISAT is to be launched into a sun synchronous polar orbit, having an equator crossing time of 10.00 a.m. at the beginning of March 2002. SCIAMACHY is thereby able to measure many more species and vertical profiles than GOME. This facilitates improved tropospheric retrievals. Finally GeoTROPE (Geostationary TROPospheric Explorer) is a new mission, which is proposed for launch within the ESA Earth Explorer Opportunity Mission. It comprises two national

  4. In-situ observation of structure formation in polymer processing

    International Nuclear Information System (INIS)

    Murase, Hiroki

    2009-01-01

    In-situ X-ray scattering in polymer processing is a crucial method to elucidate the mechanism of structure formation in the process. Fiber spinning is one such process primarily imposing extensional deformation on polymeric melt at the spin-line during rapid cooling. In-situ small-angle X-ray scattering using synchrotron radiation on the spinning process allows direct observation of the transient structure developing in the process. (author)

  5. MetNet - In situ observational Network and Orbital platform to investigate the Martian environment

    Science.gov (United States)

    Harri, Ari-Matti; Leinonen, Jussi; Merikallio, Sini; Paton, Mark; Haukka, Harri; Polkko, Jouni

    2007-09-01

    MetNet Mars Mission is an in situ observational network and orbital platform mission to investigate the Martian environment and it has been proposed to European Space Agency in response to Call for proposals for the first planning cycle of Cosmic Vision 2015-2025 D/SCI/DJS/SV/val/21851. The MetNet Mars Mission is to be implemented in collaboration with ESA, FMI, LA, IKI and the payload providing science teams. The scope of the MetNet Mission is to deploy 16 MetNet Landers (MNLs) on the Martian surface by using inflatable descent system structures accompanied by an atmospheric sounder and data relay onboard the MetNet Orbiter (MNO), which is based on ESA Mars Express satellite platform. The MNLs are attached on the three sides of the satellite and most of the MNLs are deployed to Mars separately a few weeks prior to the arrival to Mars. The MetNet Orbiter will perform continuous atmospheric soundings thus complementing the accurate in situ observations at the Martian ground produced by the MetNet observation network, as well as the orbiter will serve as the primary data relay between the MetNet Landers and the Earth. The MNLs are equipped with a versatile science payload focused on the atmospheric science of Mars. Detailed characterisation of the Martian atmospheric circulation patterns, boundary layer phenomena, and climatological cycles, as well as interior investigations, require simultaneous in situ meteorological, seismic and magnetic measurements from networks of stations on the Martian surface. MetNet Mars Mission will also provide a crucial support for the safety of large landing missions in general and manned Mars missions in particular. Accurate knowledge of atmospheric conditions and weather data is essential to guarantee safe landings of the forthcoming Mars mission elements.

  6. In situ observation data from the grouper roi (Cephalopholis argus) removal project in West Hawaii from 2010-2011 (NODC Accession 0082197)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — In situ observations of the introduced predatory grouper roi (Cephalopholis argus) were taken within the coral reef ecosystem of Puako, northwest side of the Island...

  7. In situ statistical observations of EMIC waves by Arase satellite

    Science.gov (United States)

    Nomura, R.; Matsuoka, A.; Teramoto, M.; Nose, M.; Yoshizumi, M.; Fujimoto, A.; Shinohara, M.; Tanaka, Y.

    2017-12-01

    We present in situ statistical survey of electromagnetic ion cyclotron (EMIC) waves observed by Arase satellite from 3 March to 16 July 2017. We identified 64 events using the fluxgate magnetometer (MGF) on the satellite. The EMIC wave is the key phenomena to understand the loss dynamics of MeV-energy electrons in the radiation belt. We will show the radial and latitudinal dependence of the wave occurance rate and the wave parameters (frequency band, coherence, polarization, and ellipticity). Especially the EMIC waves observed at localized weak background magnetic field will be discussed for the wave excitation mechanism in the deep inner magnetosphere.

  8. The atmosphere of Pluto as observed by New Horizons.

    Science.gov (United States)

    Gladstone, G Randall; Stern, S Alan; Ennico, Kimberly; Olkin, Catherine B; Weaver, Harold A; Young, Leslie A; Summers, Michael E; Strobel, Darrell F; Hinson, David P; Kammer, Joshua A; Parker, Alex H; Steffl, Andrew J; Linscott, Ivan R; Parker, Joel Wm; Cheng, Andrew F; Slater, David C; Versteeg, Maarten H; Greathouse, Thomas K; Retherford, Kurt D; Throop, Henry; Cunningham, Nathaniel J; Woods, William W; Singer, Kelsi N; Tsang, Constantine C C; Schindhelm, Eric; Lisse, Carey M; Wong, Michael L; Yung, Yuk L; Zhu, Xun; Curdt, Werner; Lavvas, Panayotis; Young, Eliot F; Tyler, G Leonard

    2016-03-18

    Observations made during the New Horizons flyby provide a detailed snapshot of the current state of Pluto's atmosphere. Whereas the lower atmosphere (at altitudes of less than 200 kilometers) is consistent with ground-based stellar occultations, the upper atmosphere is much colder and more compact than indicated by pre-encounter models. Molecular nitrogen (N2) dominates the atmosphere (at altitudes of less than 1800 kilometers or so), whereas methane (CH4), acetylene (C2H2), ethylene (C2H4), and ethane (C2H6) are abundant minor species and likely feed the production of an extensive haze that encompasses Pluto. The cold upper atmosphere shuts off the anticipated enhanced-Jeans, hydrodynamic-like escape of Pluto's atmosphere to space. It is unclear whether the current state of Pluto's atmosphere is representative of its average state--over seasonal or geologic time scales. Copyright © 2016, American Association for the Advancement of Science.

  9. Observational Investigation of Solar Interior and Atmosphere

    Science.gov (United States)

    Kuhn, Jeffrey R.

    2003-01-01

    The Imaging Vector Magnetograph (IVM) has been modified to make it easier to observe at more than one spectral line. The cell holding the blocking filter has been replaced by a four-position filter wheel, so that changing to a different line is a matter of a few minutes rather than the several hours it used to take to disassemble the cell and install a new filter. Three new filters have been obtained, for Na 1589.6 nm, Fe 1630.25 nm, and H 1656.3 nm. The new filters have better bandpass profiles than the ones they replaced: somewhat wider, with flatter tops and steeper wings. This results in a reduction of parasitic light coming from adjacent Fabry-Perot orders, from seven percent to about two percent, and flattens the apparent continuum. The Mees CCD Imaging Spectrograph (MCCD) was upgraded under this grant, with a new control computer and data system. The camera was replaced with a faster, larger-format frame-transfer camera. Final integration of the upgrades is not yet complete, but tests indicate that the system cadence will be improved by a factor of five to ten, while increasing the spatial coverage by a factor of two (depending on observation options). Synoptic observations with the IVM and MCCD continue to be conducted daily, to the extent permitted by the fact that we have a single observer responsible for the observations. The older Haleakala Stokes Polarimeter is also used to make a daily vector magnetogram, normally of the region selected by the Reuven Ramaty High Energy Solar Spectroscopic Imager (RHESSI) duty scientists. This instrument, however, is showing its age to the extent that its maintenance is becoming something of a challenge. We also run a white light full-disk imager and a video H alpha prominence camera, continuously during times of observations. Of particular interest, we obtained rapid-cadence observations of the 2003 July 15 white light flare with both the IVM and MCCD. The vector magnetograms show no obvious difference between the

  10. In Situ Observation of Antisite Defect Formation during Crystal Growth

    International Nuclear Information System (INIS)

    Kramer, M. J.; Napolitano, R. E.; Mendelev, M. I.

    2010-01-01

    In situ x-ray diffraction (XRD) coupled with molecular dynamics (MD) simulations have been used to quantify antisite defect trapping during crystallization. Rietveld refinement of the XRD data revealed a marked lattice distortion which involves an a axis expansion and a c axis contraction of the stable C11b phase. The observed lattice response is proportional in magnitude to the growth rate, suggesting that the behavior is associated with the kinetic trapping of lattice defects. MD simulations demonstrate that this lattice response is due to incorporation of 1% to 2% antisite defects during growth.

  11. Atmospheric correction of Earth-observation remote sensing images

    Indian Academy of Sciences (India)

    In earth observation, the atmospheric particles contaminate severely, through absorption and scattering, the reflected electromagnetic signal from the earth surface. It will be greatly beneficial for land surface characterization if we can remove these atmospheric effects from imagery and retrieve surface reflectance that ...

  12. In situ observation of stress relaxation in epitaxial graphene

    International Nuclear Information System (INIS)

    N'Diaye, Alpha T; Coraux, Johann; Busse, Carsten; Michely, Thomas; Gastel, Raoul van; Poelsema, Bene; MartInez-Galera, Antonio J; Gomez-RodrIguez, Jose M; Hattab, Hichem; Wall, Dirk; Heringdorf, Frank-J Meyer zu; Hoegen, Michael Horn-von

    2009-01-01

    Upon cooling, branched line defects develop in epitaxial graphene grown at high temperature on Pt(111) and Ir(111). Using atomically resolved scanning tunneling microscopy, we demonstrate that these defects are wrinkles in the graphene layer, i.e. stripes of partially delaminated graphene. With low energy electron microscopy (LEEM), we investigate the wrinkling phenomenon in situ. Upon temperature cycling, we observe hysteresis in the appearance and disappearance of the wrinkles. Simultaneously with wrinkle formation a change in bright field imaging intensity of adjacent areas and a shift in the moire spot positions for micro diffraction of such areas takes place. The stress relieved by wrinkle formation results from the mismatch in thermal expansion coefficients of graphene and the substrate. A simple one-dimensional model taking into account the energies related to strain, delamination and bending of graphene is in qualitative agreement with our observations.

  13. [In-situ measurement of atmospheric methyl chloroform at the Shangdianzi GAW regional background station].

    Science.gov (United States)

    Yao, Bo; Zhou, Ling-Xi; Liu, Zhao; Zhang, Gen; Xia, Ling-Jun

    2014-07-01

    An in-situ GC-ECD monitoring system was established at the Shangdianzi GAW regional background station (SDZ) for a 2-year atmospheric methyl chloroform (CH3CCl3) measurement experiment. Robust extraction of baseline signal filter was applied to the CH3CCl3 time series to separate the background and pollution data. The yearly averaged background mixing ratios of atmospheric CH3CCl3 were (9.03 +/- 0.53) x 10(-12) mol x mol(-1) in 2009 and (7.73 +/- 0.47) x 10(-12) in 2010, and the percentages of the background data in the whole data were 61.1% in 2009 and 60.4% in 2010, respectively. The yearly background CH3CCl3 mixing ratios at SDZ were consistent with the northern hemisphere background levels observed at Mace Head and Trinidad Head stations, but lower than the results observed at sites in southern China and some Chinese cities from 2001 to 2005. During the study period, background mixing ratios trends exhibited a decreasing rate of 1.39 x 10 12(-12) a(-1). The wind direction with the maximum CH3CCl3 mixing ratio was from the southwest sector and that with the minimum ratio was from the northeast sector. The differences between the maximum and the minimum average mixing ratios in the 16 wind directions were 0.77 x 10(-12) (2009) and 0.52 x 10(-12) (2010). In the 16 different wind directions, the averaged mixing ratio of CH3CCl3 in 2010 was lower than that in 2009 by 1.03 x 10(-12) -1.68 x 10(-12).

  14. Paloma: In-Situ Measurement of the Isotopic Composition of Mars Atmosphere

    Science.gov (United States)

    Jambon, A.; Quemerais, E.; Chassiefiere, E.; Berthelier, J. J.; Agrinier, P.; Cartigny, P.; Javoy, M.; Moreira, M.; Sabroux, J. -C.; Sarda, P.; Pineau, J. -F.

    2000-07-01

    Scientific objectives for an atmospheric analysis of Mars are presented in the DREAM project. Among the information presently available most are fragmentary or limited in their precision for both major element (H, C, O, N) and noble gas isotopes. These data are necessary for the understanding and modelling of Mars atmospheric formation and evolution, and consequently for other planets, particularly the Earth. To fulfill the above requirements, two approaches can be envisonned: 1) analysis of a returned sample (DREAM project) or 2) in situ analysis, e.g. PALOMA project presented here. Among the advantages of in situ analysis, we notice: the minimal terrestrial contamination, the unlimited availability of gas to be analyzed and the possibility of multiple analyses (replicates, daynight... ). Difficulties specific to in situ analyses are of a very different kind to those of returned samples. In situ analysis could also be viewed as a preparation to future analysis of returned samples. Finally, some of the measurements will not be possible on Earth: for instance, radon and its short lived decay products, will provide complementary information to 4-He analysis and can only be obtained in situ, independently of analytical capabilities.

  15. In-Situ Observation of Sintering Shrinkage of UO2 Compacts Derived from Different Powder Routes

    International Nuclear Information System (INIS)

    Rhee, Young Woo; Oh, Jang Soo; Kim, Dong Joo; Kim, Keon Sik; Kim, Jong Hun; Yang, Jae Ho; Koo, Yang Hyun

    2015-01-01

    In-situ observations on the shrinkage of green pellets with precisely controlled dimensions were carefully conducted by using TOM during H2 atmosphere sintering. The shrinkage retardation in IDR-UO 2 might be attributed to the larger primary particle size of IDRUO 2 than those of ADU- and AUC- UO 2 powders. It would be important to understand the different sintering characteristics of UO 2 powders according to the powder routes, when it comes to designing a new sintering process or choosing a sintering additive for new fuel pellet like PCI (Pellet Cladding Interaction) remedy pellet. In this paper, we have investigated the initial and intermediate sintering shrinkage of UO 2 from different powder routes by in-situ observation of green samples during H2 atmosphere sintering. Effect of powder characteristics of three different UO 2 powders on the initial and intermediate sintering were closely reviewed including crystal structure, powder size, specific surface area, primary crystal size, and O/U ratio

  16. In-situ observation system for dual ion irradiation damage

    International Nuclear Information System (INIS)

    Furuno, Shigemi; Hojou, Kiichi; Otsu, Hitoshi; Sasaki, T.A.; Izui, Kazuhiko; Tukamoto, Tetsuo; Hata, Takao.

    1992-01-01

    We have developed an in-situ observation and analysis system during dual ion beam irradiation in an electron microscope. This system consists of an analytical electron microscope of JEM-4000FX type equipped with a parallel EELS and an EDS attachments and linked with two sets of ion accelerators of 40 kV. Hydrogen and helium dual-ion beam irradiation experiments were performed for SiC crystals. The result of dual-ion beam irradiation was compared with those of helium and hydrogen single ion irradiations. It is clearly seen that the dual-ion irradiation has the effect of suppressing bubble formation and growth in comparison with the case of single helium ion irradiation. (author)

  17. Improving magnetosphere in situ observations using solar sails

    Science.gov (United States)

    Parsay, Khashayar; Schaub, Hanspeter; Schiff, Conrad; Williams, Trevor

    2018-01-01

    Past and current magnetosphere missions employ conventional spacecraft formations for in situ observations of the geomagnetic tail. Conventional spacecraft flying in inertially fixed Keplerian orbits are only aligned with the geomagnetic tail once per year, since the geomagnetic tail is always aligned with the Earth-Sun line, and therefore, rotates annually. Solar sails are able to artificially create sun-synchronous orbits such that the orbit apse line remains aligned with the geomagnetic tail line throughout the entire year. This continuous presence in the geomagnetic tail can significantly increase the science phase for magnetosphere missions. In this paper, the problem of solar sail formation design is explored using nonlinear programming to design optimal two-craft, triangle, and tetrahedron solar sail formations, in terms of formation quality and formation stability. The designed formations are directly compared to the formations used in NASA's Magnetospheric Multi-Scale mission.

  18. In-situ monitoring of etching of bovine serum albumin using low-temperature atmospheric plasma jet

    Science.gov (United States)

    Kousal, J.; Shelemin, A.; Kylián, O.; Slavínská, D.; Biederman, H.

    2017-01-01

    Bio-decontamination of surfaces by means of atmospheric pressure plasma is nowadays extensively studied as it represents promising alternative to commonly used sterilization/decontamination techniques. The non-equilibrium atmospheric pressure plasmas were already reported to be highly effective in removal of a wide range of biological residual from surfaces. Nevertheless the kinetics of removal of biological contamination from surfaces is still not well understood as the majority of performed studies were based on ex-situ evaluation of etching rates, which did not allow investigating details of plasma action on biomolecules. This study therefore presents a real-time, in-situ ellipsometric characterization of removal of bovine serum albumin (BSA) from surfaces by low-temperature atmospheric plasma jet operated in argon. Non-linear and at shorter distances between treated samples and nozzle of the plasma jet also non-monotonic dependence of the removal rate on the treatment duration was observed. According to additional measurements focused on the determination of chemical changes of treated BSA as well as temperature measurements, the observed behavior is most likely connected with two opposing effects: the formation of a thin layer on the top of BSA deposit enriched in inorganic compounds, whose presence causes a gradual decrease of removal efficiency, and slight heating of BSA that facilitates its degradation and volatilization induced by chemically active radicals produced by the plasma.

  19. Hysteresis in YHx films observed with in situ measurements

    International Nuclear Information System (INIS)

    Remhof, A.; Kerssemakers, J.W.J.; Molen, S.J. van der; Griessen, R.; Kooij, E.S.

    2002-01-01

    Giant hysteretic effects in the YH x hydrogen switchable mirror system are observed between x=1.9 and x=3 in pressure composition isotherms, optical and electrical properties, and mechanical stress. Polycrystalline Y films are studied by simultaneous in situ measurements of electrical resistivity, optical transmittance and x-ray diffractometry. These experiments are linked to optical microscopy of the samples. During hydrogen loading above x=1.9 the films stay in the metallic fcc phase until the optical transmittance reaches its minimum and the electrical resistance curve exhibits a characteristic feature at x=2.1. Upon further loading the system crosses the miscibility gap in which the fcc phase coexists with the hcp phase before hydrogen saturation is reached in the pure hcp phase. While the fcc phase stays at a concentration of x=2.1 in the coexistence region during loading, it remains at a concentration of x=1.9 during unloading. The hysteretic effects observed in optical transmission and electrical resistivity result from the different properties of the low concentration fcc phase YH 1.9 and the high concentration fcc phase YH 2.1 . They can be explained on the basis of the bulk phase diagram if the different stress states during loading and unloading are taken into account. These results contradict earlier interpretations of the hysteresis in thin film YH x , based on nonsimultaneous measurements of the optical and structural properties on different films

  20. Global Hawk dropsonde observations of the Arctic atmosphere obtained during the Winter Storms and Pacific Atmospheric Rivers (WISPAR field campaign

    Directory of Open Access Journals (Sweden)

    J. M. Intrieri

    2014-11-01

    Full Text Available In February and March of 2011, the Global Hawk unmanned aircraft system (UAS was deployed over the Pacific Ocean and the Arctic during the Winter Storms and Pacific Atmospheric Rivers (WISPAR field campaign. The WISPAR science missions were designed to (1 mprove our understanding of Pacific weather systems and the polar atmosphere; (2 evaluate operational use of unmanned aircraft for investigating these atmospheric events; and (3 demonstrate operational and research applications of a UAS dropsonde system at high latitudes. Dropsondes deployed from the Global Hawk successfully obtained high-resolution profiles of temperature, pressure, humidity, and wind information between the stratosphere and surface. The 35 m wingspan Global Hawk, which can soar for ~ 31 h at altitudes up to ~ 20 km, was remotely operated from NASA's Dryden Flight Research Center at Edwards Air Force Base (AFB in California. During the 25 h polar flight on 9–10 March 2011, the Global Hawk released 35 sondes between the North Slope of Alaska and 85° N latitude, marking the first UAS Arctic dropsonde mission of its kind. The polar flight transected an unusually cold polar vortex, notable for an associated record-level Arctic ozone loss, and documented polar boundary layer variations over a sizable ocean–ice lead feature. Comparison of dropsonde observations with atmospheric reanalyses reveal that, for this day, large-scale structures such as the polar vortex and air masses are captured by the reanalyses, while smaller-scale features, including low-level jets and inversion depths, are mischaracterized. The successful Arctic dropsonde deployment demonstrates the capability of the Global Hawk to conduct operations in harsh, remote regions. The limited comparison with other measurements and reanalyses highlights the potential value of Arctic atmospheric dropsonde observations where routine in situ measurements are practically nonexistent.

  1. Atmospherical simulations of the OMEGA/MEX observations

    Science.gov (United States)

    Melchiorri, R.; Drossart, P.; Combes, M.; Encrenaz, T.; Fouchet, T.; Forget, F.; Bibring, J. P.; Ignatiev, N.; Moroz, V.; OMEGA Team

    The modelization of the atmospheric contribution in the martian spectrum is an important step for the OMEGA data analysis.A full line by line radiative transfer calculation is made for the gas absorption; the dust opacity component, in a first approximation, is calculated as an optically thin additive component.Due to the large number of parameters needed in the calculations, the building of a huge data base to be interpolated is not envisageable, for each observed OMEGA spectrum with calculation for all the involved parameters (atmospheric pressure, water abundance, CO abundance, dust opacity and geometric angles of observation). The simulation of the observations allows us to fix all the orbital parameters and leave the unknown parameters as the only variables.Starting from the predictions of the current meteorological models of Mars we build a smaller data base corresponding on each observation. We present here a first order simulation, which consists in retrieving atmospheric contribution from the solar reflected component as a multiplicative (for gas absorption) and an additive component (for suspended dust contribution); although a fully consistent approach will require to include surface and atmosphere contributions together in synthetic calculations, this approach is sufficient for retrieving mineralogic information cleaned from atmospheric absorption at first order.First comparison to OMEGA spectra will be presented, with first order retrieval of CO2 pressure, CO and H2O abundance, and dust opacity.

  2. In Situ Measurement of Atmospheric Krypton and Xenon on Mars with Mars Science Laboratory

    Science.gov (United States)

    Conrad, P. G.; Malespin, C. A.; Franz, H. B.; Pepin, R. O.; Trainer, M. G.; Schwenzer, S. P.; Atreya, S. K.; Freissinet, C.; Jones, J. H.; Manning, H.; hide

    2016-01-01

    Mars Science Laboratorys Sample Analysis at Mars (SAM) investigation has measured all of the stable isotopes of the heavy noble gases krypton and xenon in the martian atmosphere, in situ, from the Curiosity Rover at Gale Crater, Mars. Previous knowledge of martian atmospheric krypton and xenon isotope ratios has been based upon a combination of the Viking missions krypton and xenon detections and measurements of noble gas isotope ratios in martian meteorites. However, the meteorite measurements reveal an impure mixture of atmospheric, mantle, and spallation contributions. The xenon and krypton isotopic measurements reported here include the complete set of stable isotopes, unmeasured by Viking. The new results generally agree with Mars meteorite measurements but also provide a unique opportunity to identify various non-atmospheric heavy noble gas components in the meteorites. Kr isotopic measurements define a solar-like atmospheric composition, but deviating from the solar wind pattern at 80Kr and 82Kr in a manner consistent with contributions originating from neutron capture in Br. The Xe measurements suggest an intriguing possibility that isotopes lighter than 132Xe have been enriched to varying degrees by spallation and neutron capture products degassed to the atmosphere from the regolith, and a model is constructed to explore this possibility. Such a spallation component, however, is not apparent in atmospheric Xe trapped in the glassy phases of martian meteorites.

  3. Multi-Sensor Observations of Earthquake Related Atmospheric Signals over Major Geohazard Validation Sites

    Science.gov (United States)

    Ouzounov, D.; Pulinets, S.; Davindenko, D.; Hattori, K.; Kafatos, M.; Taylor, P.

    2012-01-01

    We are conducting a scientific validation study involving multi-sensor observations in our investigation of phenomena preceding major earthquakes. Our approach is based on a systematic analysis of several atmospheric and environmental parameters, which we found, are associated with the earthquakes, namely: thermal infrared radiation, outgoing long-wavelength radiation, ionospheric electron density, and atmospheric temperature and humidity. For first time we applied this approach to selected GEOSS sites prone to earthquakes or volcanoes. This provides a new opportunity to cross validate our results with the dense networks of in-situ and space measurements. We investigated two different seismic aspects, first the sites with recent large earthquakes, viz.- Tohoku-oki (M9, 2011, Japan) and Emilia region (M5.9, 2012,N. Italy). Our retrospective analysis of satellite data has shown the presence of anomalies in the atmosphere. Second, we did a retrospective analysis to check the re-occurrence of similar anomalous behavior in atmosphere/ionosphere over three regions with distinct geological settings and high seismicity: Taiwan, Japan and Kamchatka, which include 40 major earthquakes (M>5.9) for the period of 2005-2009. We found anomalous behavior before all of these events with no false negatives; false positives were less then 10%. Our initial results suggest that multi-instrument space-borne and ground observations show a systematic appearance of atmospheric anomalies near the epicentral area that could be explained by a coupling between the observed physical parameters and earthquake preparation processes.

  4. Diurnal changes of remote sensing reflectance over Chesapeake Bay: Observations from the Airborne Compact Atmospheric Mapper

    Science.gov (United States)

    Zhang, Minwei; Hu, Chuanmin; Cannizzaro, Jennifer; Kowalewski, Matthew G.; Janz, Scott J.

    2018-01-01

    Using hyperspectral data collected by the Airborne Compact Atmospheric Mapper (ACAM) and a shipborne radiometer in Chesapeake Bay in July-August 2011, this study investigates diurnal changes of surface remote sensing reflectance (Rrs). Atmospheric correction of ACAM data is performed using the traditional "black pixel" approach through radiative transfer based look-up-tables (LUTs) with non-zero Rrs in the near-infrared (NIR) accounted for by iterations. The ACAM-derived Rrs was firstly evaluated through comparison with Rrs derived from the Moderate Resolution Imaging Spectroradiometer satellite measurements, and then validated against in situ Rrs using a time window of ±1 h or ±3 h. Results suggest that the uncertainties in ACAM-derived Rrs are generally comparable to those from MODIS satellite measurements over coastal waters, and therefore may be used to assess whether Rrs diurnal changes observed by ACAM are realistic (i.e., with changes > 2 × uncertainties). Diurnal changes observed by repeated ACAM measurements reaches up to 66.8% depending on wavelength and location and are consistent with those from the repeated in situ Rrs measurements. These findings suggest that once airborne data are processed using proper algorithms and validated using in situ data, they are suitable for assessing diurnal changes in moderately turbid estuaries such as Chesapeake Bay. The findings also support future geostationary satellite missions that are particularly useful to assess short-term changes.

  5. Do In Situ Observations Contain Signatures of Intermittent Fast Solar Wind Acceleration?

    Science.gov (United States)

    Matteini, L.; Horbury, T. S.; Stansby, D.

    2017-12-01

    Disentangling local plasma properties and Solar origin structures in in situ data is a crucial aspect for the understanding of solar wind acceleration and evolution. This is particularly challenging at 1 AU and beyond, where structures of various origin have had time to interact and merge, smoothing out their main characteristics. Observations of more pristine plasma closer to the Sun are therefore needed. In preparation of the forthcoming Solar Orbiter and Parker Solar Probe missions, Helios observations as close as to 0.3 AU - although old, not yet fully exploited - can be used to test our expectations and make new predictions. Recent observations (Matteini et al. 2014, 2015) have outlined the presence of intense (up to 1000km/s) and short-living velocity peaks that ubiquitously characterize the typical profile of the fast solar wind at 0.3 AU, suggesting that these features could be remnants of processes occurring in the Solar atmosphere and a signature of intermittent solar wind acceleration from coronal holes. We discuss results about statistics of these events, characterizing their physical properties and trying to link them with typical Solar temporal and spatial scales. Finally we also discuss how these velocity peaks will likely affect the future in situ exploration of the inner heliosphere by Solar Orbiter and the Parker Solar Probe.

  6. Vertical profiles of atmospheric fluorescent aerosols observed by a mutil-channel lidar spectrometer system

    Science.gov (United States)

    Huang, Z.; Huang, J.; Zhou, T.; Sugimoto, N.; Bi, J.

    2015-12-01

    Zhongwei Huang1*, Jianping Huang1, Tian Zhou1, Nobuo Sugimoto2, Jianrong Bi1 and Jinsen Shi11Key Laboratory for Semi-Arid Climate Change of the Ministry of Education, College of Atmospheric Sciences, Lanzhou University, Lanzhou, China. 2Atmospheric Environment Division, National Institutes for Environmental Studies, Tsukuba, Japan Email: huangzhongwei@lzu.edu.cn Abstract Atmospheric aerosols have a significant impact on regional and globe climate. The challenge in quantifying aerosol direct radiative forcing and aerosol-cloud interactions arises from large spatial and temporal heterogeneity of aerosol concentrations, compositions, sizes, shape and optical properties (IPCC, 2007). Lidar offers some remarkable advantages for determining the vertical structure of atmospheric aerosols and their related optical properties. To investigate the characterization of atmospheric aerosols (especially bioaerosols) with high spatial and temporal resolution, we developed a Raman/fluorescence/polarization lidar system employed a multi-channel spectrometer, with capabilities of providing measurements of Raman scattering and laser-induced fluorescence excitation at 355 nm from atmospheric aerosols. Meanwhile, the lidar system operated polarization measurements both at 355nm and 532nm wavelengths, aiming to obtain more information of aerosols. It employs a high power pulsed laser and a received telescope with 350mm diameter. The receiver could simultaneously detect a wide fluorescent spectrum about 178 nm with spectral resolution 5.7 nm, mainly including an F/3.7 Crossed Czerny-Turner spectrograph, a grating (1200 gr/mm) and a PMT array with 32 photocathode elements. Vertical structure of fluorescent aerosols in the atmosphere was observed by the developed lidar system at four sites across northwest China, during 2014 spring field observation that conducted by Lanzhou University. It has been proved that the developed lidar could detect the fluorescent aerosols with high temporal and

  7. Environmental significance of atmospheric emission resulting from in situ burning of oiled salt marsh

    International Nuclear Information System (INIS)

    Devai, I.; DeLaune, R.D.; Henry, C.B. Jr.; Roberts, P.O.; Lindau, C.W.

    1998-01-01

    The environmental significance of atmospheric emissions resulting from in-situ burning used as remediation technique for removal of petroleum hydrocarbons entering Louisiana coastal salt marshes was quantified. Research conducted documented atmospheric pollutants produced and emitted to the atmosphere as the result of burning of oil contaminated wetlands. Samples collected from the smoke plume contained a variety of gaseous sulfur and carbon compounds. Carbonyl sulfide and carbon disulfide were the main volatile sulfur compounds. In contrast, concentrations of sulfur dioxide were almost negligible. Concentrations of methane and carbon dioxide in the smoke plume increased compared to ambient levels. Air samples collected for aromatic hydrocarbons in the smoke plume were dominated by pyrogenic or combustion derived aromatic hydrocarbons. The particulate fraction was dominated by phenanthrene and the C-1 and C-2 alkylated phenanthrene homologues. The vapor fraction was dominated by naphthalene and the C-1 to C-3 naphthalene homologues. (author)

  8. Southeast Atmosphere Studies: learning from model-observation syntheses

    Directory of Open Access Journals (Sweden)

    J. Mao

    2018-02-01

    Full Text Available Concentrations of atmospheric trace species in the United States have changed dramatically over the past several decades in response to pollution control strategies, shifts in domestic energy policy and economics, and economic development (and resulting emission changes elsewhere in the world. Reliable projections of the future atmosphere require models to not only accurately describe current atmospheric concentrations, but to do so by representing chemical, physical and biological processes with conceptual and quantitative fidelity. Only through incorporation of the processes controlling emissions and chemical mechanisms that represent the key transformations among reactive molecules can models reliably project the impacts of future policy, energy and climate scenarios. Efforts to properly identify and implement the fundamental and controlling mechanisms in atmospheric models benefit from intensive observation periods, during which collocated measurements of diverse, speciated chemicals in both the gas and condensed phases are obtained. The Southeast Atmosphere Studies (SAS, including SENEX, SOAS, NOMADSS and SEAC4RS conducted during the summer of 2013 provided an unprecedented opportunity for the atmospheric modeling community to come together to evaluate, diagnose and improve the representation of fundamental climate and air quality processes in models of varying temporal and spatial scales.This paper is aimed at discussing progress in evaluating, diagnosing and improving air quality and climate modeling using comparisons to SAS observations as a guide to thinking about improvements to mechanisms and parameterizations in models. The effort focused primarily on model representation of fundamental atmospheric processes that are essential to the formation of ozone, secondary organic aerosol (SOA and other trace species in the troposphere, with the ultimate goal of understanding the radiative impacts of these species in the southeast and

  9. Southeast Atmosphere Studies: learning from model-observation syntheses

    Science.gov (United States)

    Mao, Jingqiu; Carlton, Annmarie; Cohen, Ronald C.; Brune, William H.; Brown, Steven S.; Wolfe, Glenn M.; Jimenez, Jose L.; Pye, Havala O. T.; Ng, Nga Lee; Xu, Lu; McNeill, V. Faye; Tsigaridis, Kostas; McDonald, Brian C.; Warneke, Carsten; Guenther, Alex; Alvarado, Matthew J.; de Gouw, Joost; Mickley, Loretta J.; Leibensperger, Eric M.; Mathur, Rohit; Nolte, Christopher G.; Portmann, Robert W.; Unger, Nadine; Tosca, Mika; Horowitz, Larry W.

    2018-02-01

    Concentrations of atmospheric trace species in the United States have changed dramatically over the past several decades in response to pollution control strategies, shifts in domestic energy policy and economics, and economic development (and resulting emission changes) elsewhere in the world. Reliable projections of the future atmosphere require models to not only accurately describe current atmospheric concentrations, but to do so by representing chemical, physical and biological processes with conceptual and quantitative fidelity. Only through incorporation of the processes controlling emissions and chemical mechanisms that represent the key transformations among reactive molecules can models reliably project the impacts of future policy, energy and climate scenarios. Efforts to properly identify and implement the fundamental and controlling mechanisms in atmospheric models benefit from intensive observation periods, during which collocated measurements of diverse, speciated chemicals in both the gas and condensed phases are obtained. The Southeast Atmosphere Studies (SAS, including SENEX, SOAS, NOMADSS and SEAC4RS) conducted during the summer of 2013 provided an unprecedented opportunity for the atmospheric modeling community to come together to evaluate, diagnose and improve the representation of fundamental climate and air quality processes in models of varying temporal and spatial scales.This paper is aimed at discussing progress in evaluating, diagnosing and improving air quality and climate modeling using comparisons to SAS observations as a guide to thinking about improvements to mechanisms and parameterizations in models. The effort focused primarily on model representation of fundamental atmospheric processes that are essential to the formation of ozone, secondary organic aerosol (SOA) and other trace species in the troposphere, with the ultimate goal of understanding the radiative impacts of these species in the southeast and elsewhere. Here we

  10. Observations of ionospheric electric fields above atmospheric weather systems

    Science.gov (United States)

    Farrell, W. M.; Aggson, T. L.; Rodgers, E. B.; Hanson, W. B.

    1994-01-01

    We report on the observations of a number of quasi-dc electric field events associated with large-scale atmospheric weather formations. The observations were made by the electric field experiment onboard the San Marco D satellite, operational in an equatorial orbit from May to December 1988. Several theoretical studies suggest that electric fields generated by thunderstorms are present at high altitudes in the ionosphere. In spite of such favorable predictions, weather-related events are not often observed since they are relatively weak. We shall report here on a set of likely E field candidates for atmospheric-ionospheric causality, these being observed over the Indonesian Basin, northern South America, and the west coast of Africa; all known sites of atmospheric activity. As we shall demonstrate, individual events often be traced to specific active weather features. For example, a number of events were associated with spacecraft passages near Hurricane Joan in mid-October 1988. As a statistical set, the events appear to coincide with the most active regions of atmospheric weather.

  11. Observations of atmospheric ammonia from TANSO-FTS/GOSAT

    Science.gov (United States)

    Someya, Yu; Imasu, Ryoichi; Saitoh, Naoko; Shiomi, Kei

    2017-04-01

    Atmospheric ammonia has large impacts on the nitrogen cycles or atmospheric environment such as nucleation of PM2.5 particles. It is reported that ammonia in the atmosphere has been increasing rapidly with the growth of population globally and this trend must continue in the future. Satellite observation is an effective approach to get to know the global perspectives of the gas. Atmospheric ammonia is observable using the thermal infrared (TIR) spectra, and IASI, TES and CrIS had been revealed those distributions. GOSAT also has TIR band including the ammonia absorption bands. GOSAT has the shorter revisit cycle than that of the other hyper-spectral TIR sounders mentioned above, therefore, the shorter time-scale events can be represented. In addition to the importance of the impacts of ammonia itself, the concentration ratio between ammonia and the other trace gases such as CO which is one of the main targets of the GOSAT-2 project is useful as the indicator of their emission sources. In this study, we introduce an algorithm to retrieve the column amount of atmospheric ammonia based on non-linear optimal estimation (Rogers, 2000) from GOSAT spectra in the ammonia absorption band between 960 - 970 cm-1. Temperature and water vapor profiles are estimated in advance of the ammonia retrieval. The preliminary results showed significant high concentrations of ammonia in the Northern India and the Eastern China as pointed out in the previous researches. We will discuss the global distribution of ammonia in the presentation.

  12. Measuring Mass-Based Hygroscopicity of Atmospheric Particles through in situ Imaging

    Energy Technology Data Exchange (ETDEWEB)

    Piens, Dominique` Y.; Kelly, Stephen T.; Harder, Tristan; Petters, Markus D.; O' Brien, Rachel; Wang, Bingbing; Teske, Ken; Dowell, Pat; Laskin, Alexander; Gilles, Mary K.

    2016-04-18

    Quantifying how atmospheric particles interact with water vapor is critical for understanding the effects of aerosols on climate. We present a novel method to measure the mass-based hygroscopicity of particles while characterizing their elemental and carbon functional group compositions. Since mass-based hygroscopicity is insensitive to particle geometry, it is advantageous for probing the hygroscopic behavior of atmospheric particles, which can have irregular morphologies. Combining scanning electron microscopy with energy dispersive X-ray analysis (SEM/EDX), scanning transmission X-ray microscopy (STXM) analysis, and in situ STXM humidification experiments, this method was validated using laboratory-generated, atmospherically relevant particles. Then, the hygroscopicity and elemental composition of 15 complex atmospheric particles were analyzed by leveraging quantification of C, N, and O from STXM, and complementary elemental quantification from SEM/EDX. We found three types of hygroscopic responses, and correlated high hygroscopicity with Na and Cl content. The mixing state determined for 158 particles broadly agreed with those of the humidified particles, indicating the potential to infer the atmospheric hygroscopic behavior from a selected subset of particles. These methods offer unique quantitative capabilities to characterize and correlate the hygroscopicity and chemistry of individual submicron atmospheric particles.

  13. Mars Atmosphere Resource Verification INsitu (MARVIN) - In Situ Resource Demonstration for the Mars 2020 Mission

    Science.gov (United States)

    Sanders, Gerald B.; Araghi, Koorosh; Ess, Kim M.; Valencia, Lisa M.; Muscatello, Anthony C.; Calle, Carlos I.; Clark, Larry; Iacomini, Christie

    2014-01-01

    The making of oxygen from resources in the Martian atmosphere, known as In Situ Resource Utilization (ISRU), has the potential to provide substantial benefits for future robotic and human exploration. In particular, the ability to produce oxygen on Mars for use in propulsion, life support, and power systems can provide significant mission benefits such as a reducing launch mass, lander size, and mission and crew risk. To advance ISRU for possible incorporation into future human missions to Mars, NASA proposed including an ISRU instrument on the Mars 2020 rover mission, through an announcement of opportunity (AO). The purpose of the the Mars Atmosphere Resource Verification INsitu or (MARVIN) instrument is to provide the first demonstration on Mars of oxygen production from acquired and stored Martian atmospheric carbon dioxide, as well as take measurements of atmospheric pressure and temperature, and of suspended dust particle sizes and amounts entrained in collected atmosphere gases at different times of the Mars day and year. The hardware performance and environmental data obtained will be critical for future ISRU systems that will reduce the mass of propellants and other consumables launched from Earth for robotic and human exploration, for better understanding of Mars dust and mitigation techniques to improve crew safety, and to help further define Mars global circulation models and better understand the regional atmospheric dynamics on Mars. The technologies selected for MARVIN are also scalable for future robotic sample return and human missions to Mars using ISRU.

  14. Observations of CO in Titan's Atmosphere Using ALMA

    Science.gov (United States)

    Serigano, Joseph; Nixon, Conor A.; Cordiner, Martin; Irwin, Patrick G. J.; Teanby, Nicholas; Charnley, Steven B.; Lindberg, Johan E.; Remijan, Anthony J.

    2015-11-01

    The advent of the Atacama Large Millimeter/submillimeter Array (ALMA) has provided a powerful facility for probing the atmospheres of solar system targets at long wavelengths (84-720 GHz) where the rotational lines of small, polar molecules are prominent. In the dense, nitrogen-dominated atmosphere of Titan, photodissociation of molecular nitrogen and methane leads to a wealth of complex hydrocarbons and nitriles in small abundances. Past millimeter/submillimeter observations, including ground-based observations as well as those by the Composite Infrared Spectrometer (CIRS) aboard the Cassini spacecraft, have proven the significance of this wavelength region for the derivation of vertical mixing profiles, latitudinal and seasonal variations, and molecular detections. Previous ALMA studies of Titan have presented mapping and vertical column densities of hydrogen isocyanide (HNC) and cyanoacetylene (HC3N) (Cordiner et al. 2014) as well as the first spectroscopic detection of ethyl cyanide (C2H5CN) in Titan’s atmosphere (Cordiner et al. 2015).Here, we report several submillimetric observations of carbon monoxide (CO) and its isotopologues 13CO, C18O, and C17O in Titan’s atmosphere obtained with flux calibration data from the ALMA Science Archive. We employ NEMESIS, a line-by-line radiative transfer code, to determine the stratospheric abundances of these molecules. The abundance of CO in Titan's atmosphere is determined to be approximately 50±1 ppm, constant with altitude, and isotopic ratios are determined to be approximately 12C/13C = 90, 16O/18O = 470, and 16O/17O = 2800. This report presents the first spectroscopic detection of C17O in the outer solar system, detected at >11σ confidence. This talk will focus on isotopic ratios in CO in Titan's atmosphere and will compare our results to previously measured values for Titan and other bodies in the Solar System. General implications for the history of Titan from measurements of CO and its isotopologues will be

  15. Atmospheric CO2 Variability Observed From ASCENDS Flight Campaigns

    Science.gov (United States)

    Lin, Bing; Browell, Edward; Campbell, Joel; Choi, Yonghoon; Dobler, Jeremy; Fan, Tai-Fang; Harrison, F. Wallace; Kooi, Susan; Liu, Zhaoyan; Meadows, Byron; hide

    2015-01-01

    Significant atmospheric CO2 variations on various spatiotemporal scales were observed during ASCENDS flight campaigns. For example, around 10-ppm CO2 changes were found within free troposphere in a region of about 200x300 sq km over Iowa during a summer 2014 flight. Even over extended forests, about 2-ppm CO2 column variability was measured within about 500-km distance. For winter times, especially over snow covered ground, relatively less horizontal CO2 variability was observed, likely owing to minimal interactions between the atmosphere and land surface. Inter-annual variations of CO2 drawdown over cornfields in the Mid-West were found to be larger than 5 ppm due to slight differences in the corn growing phase and meteorological conditions even in the same time period of a year. Furthermore, considerable differences in atmospheric CO2 profiles were found during winter and summer campaigns. In the winter CO2 was found to decrease from about 400 ppm in the atmospheric boundary layer (ABL) to about 392 ppm above 10 km, while in the summer CO2 increased from 386 ppm in the ABL to about 396 ppm in free troposphere. These and other CO2 observations are discussed in this presentation.

  16. An Intercomparison of GPS RO Retrievals with Colocated Analysis and In Situ Observations within Tropical Cyclones

    Directory of Open Access Journals (Sweden)

    Henry R. Winterbottom

    2010-01-01

    Full Text Available Observations from four Global Position System (GPS Radio Occultation (RO missions: Global Positioning System/Meteorology, CHAallenging Minisatellite Payload, Satellite de Aplicaciones Cientificas-C, and Constellation Observing System for Meteorology, Ionosphere and Climate and Taiwan's FORMOsa SATellite Mission #3 (COSMIC/FORMOSAT-3 are collected within a 600 km radius and ±180 minute temporal window of all observed tropical cyclones (TCs from 1995 to 2006 that were recorded in the global hurricane best-track reanalysis data set (Jarvinen et al. (1984; Davis et al. (1984. A composite analysis of tropical cyclone radial mean temperature and water vapor profiles is carried out using the GPS RO retrievals which are colocated with global analysis profiles and available in situ radiosonde observations. The differences between the respective observations and analysis profiles are quantified and the preliminary results show that the observations collected within TCs correspond favorably with both the analysis and radiosonde profiles which are colocated. It is concluded that GPS RO observations will contribute significantly to the understanding and modeling of TC structures, especially those related to vertical variability of the atmospheric state within TCs.

  17. Observing atmospheric tides in Earth rotation parameters with VLBI

    Science.gov (United States)

    Girdiuk, Anastasiia; Böhm, Johannes; Schindelegger, Michael

    2015-04-01

    In this study, we assess the contribution of diurnal (S1) and semi-diurnal (S2) atmospheric tides to variations in Earth rotation by analyzing Very Long Baseline Interferometry (VLBI) observations. Particular emphasis is placed on the dependency of S1 and S2 estimates on varying settings in the a priori delay model. We use hourly Earth rotation parameters (ERP) of polar motion and UT1 as determined with the Vienna VLBI Software (VieVS) from 25 years of VLBI observations and we adjust diurnal and semi-diurnal amplitudes to the hourly ERP estimates after disregarding the effect of high-frequency ocean tides. Prograde and retrograde polar motion coefficients are obtained for several solutions differing in processing strategies (with/without thermal deformation, time span of observations, choice of a priori ERP model and celestial pole offsets) and we compare the corresponding harmonics with those derived from atmospheric and non-tidal oceanic angular momentum estimates.

  18. MODELING ATMOSPHERIC EMISSION FOR CMB GROUND-BASED OBSERVATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Errard, J.; Borrill, J. [Space Sciences Laboratory, University of California, Berkeley, CA 94720 (United States); Ade, P. A. R. [School of Physics and Astronomy, Cardiff University, Cardiff CF10 3XQ (United Kingdom); Akiba, Y.; Chinone, Y. [High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki 305-0801 (Japan); Arnold, K.; Atlas, M.; Barron, D.; Elleflot, T. [Department of Physics, University of California, San Diego, CA 92093-0424 (United States); Baccigalupi, C.; Fabbian, G. [International School for Advanced Studies (SISSA), Trieste I-34014 (Italy); Boettger, D. [Department of Astronomy, Pontifica Universidad Catolica de Chile (Chile); Chapman, S. [Department of Physics and Atmospheric Science, Dalhousie University, Halifax, NS, B3H 4R2 (Canada); Cukierman, A. [Department of Physics, University of California, Berkeley, CA 94720 (United States); Delabrouille, J. [AstroParticule et Cosmologie, Univ Paris Diderot, CNRS/IN2P3, CEA/Irfu, Obs de Paris, Sorbonne Paris Cité (France); Dobbs, M.; Gilbert, A. [Physics Department, McGill University, Montreal, QC H3A 0G4 (Canada); Ducout, A.; Feeney, S. [Department of Physics, Imperial College London, London SW7 2AZ (United Kingdom); Feng, C. [Department of Physics and Astronomy, University of California, Irvine (United States); and others

    2015-08-10

    Atmosphere is one of the most important noise sources for ground-based cosmic microwave background (CMB) experiments. By increasing optical loading on the detectors, it amplifies their effective noise, while its fluctuations introduce spatial and temporal correlations between detected signals. We present a physically motivated 3D-model of the atmosphere total intensity emission in the millimeter and sub-millimeter wavelengths. We derive a new analytical estimate for the correlation between detectors time-ordered data as a function of the instrument and survey design, as well as several atmospheric parameters such as wind, relative humidity, temperature and turbulence characteristics. Using an original numerical computation, we examine the effect of each physical parameter on the correlations in the time series of a given experiment. We then use a parametric-likelihood approach to validate the modeling and estimate atmosphere parameters from the polarbear-i project first season data set. We derive a new 1.0% upper limit on the linear polarization fraction of atmospheric emission. We also compare our results to previous studies and weather station measurements. The proposed model can be used for realistic simulations of future ground-based CMB observations.

  19. Tracking atmospheric boundary layer dynamics with water vapor D-excess observations

    KAUST Repository

    Parkes, Stephen

    2015-04-01

    Stable isotope water vapor observations present a history of hydrological processes that have impacted on an air mass. Consequently, there is scope to improve our knowledge of how different processes impact on humidity budgets by determining the isotopic end members of these processes and combining them with in-situ water vapor measurements. These in-situ datasets are still rare and cover a limited geographical expanse, so expanding the available data can improve our ability to define isotopic end members and knowledge about atmospheric humidity dynamics. Using data collected from an intensive field campaign across a semi-arid grassland site in eastern Australia, we combine multiple methods including in-situ stable isotope observations to study humidity dynamics associated with the growth and decay of the atmospheric boundary layer and the stable nocturnal boundary layer. The deuterium-excess (D-excess) in water vapor is traditionally thought to reflect the sea surface temperature and relative humidity at the point of evaporation over the oceans. However, a number of recent studies suggest that land-atmosphere interactions are also important in setting the D-excess of water vapor. These studies have shown a highly robust diurnal cycle for the D-excess over a range of sites that could be exploited to better understand variations in atmospheric humidity associated with boundary layer dynamics. In this study we use surface radon concentrations as a tracer of surface layer dynamics and combine these with the D-excess observations. The radon concentrations showed an overall trend that was inversely proportional to the D-excess, with early morning entrainment of air from the residual layer of the previous day both diluting the radon concentration and increasing the D-excess, followed by accumulation of radon at the surface and a decrease in the D-excess as the stable nocturnal layer developed in the late afternoon and early evening. The stable nocturnal boundary layer

  20. In situ observation techniques of protective oxide layer

    International Nuclear Information System (INIS)

    Doi, Takashi; Adachi, Takeharu; Usuki, Noriaki

    2015-01-01

    In situ analyzing techniques for investigating a surface and interface change during corrosion and oxidation of metals by using Raman scattering spectroscopy (Raman), X-ray diffraction (XRD) and X-ray photoemission spectroscopy (XPS) are present. The Raman spectra revealed that a crystal structure and distribution of corrosion products varied during corrosion progress at elevated temperature and high pressure electrolyte. Time dependent XRD measurements made clear the behavior of the electrochemical reduction of a rust and the iso thermal transformation of a scale on a steel. It was demonstrated that XPS was capable of the in-situ measurements for initial stage of high temperature oxidation. (author)

  1. ALMA observations of Titan's atmospheric chemistry and seasonal variation

    Science.gov (United States)

    Cordiner, Martin

    2017-04-01

    Titan is the largest moon of Saturn, with a thick (1.45 bar) atmosphere composed primarily of molecular nitrogen and methane. Photochemistry in Titan's upper atmosphere results in the production of a wide range of organic molecules, including hydrocarbons, nitriles and aromatics, some of which could be of pre-biotic relevance. Thus, we obtain insights into the possible molecular inventories of primitive (reducing) planetary atmospheres. Titan's atmosphere also provides a unique laboratory for testing our understanding of fundamental processes involving the chemistry and spectroscopy of complex organic molecules. In this talk, results will be presented from our studies using the Atacama Large Millimeter/submillimeter Array (ALMA) during the period 2012-2015, focussing in particular on the detection and mapping of emission from various nitrile species. By combining data from multiple ALMA observations, our spectra have reached an unprecedented sensitivity level, enabling the first spectroscopic detection and mapping of C2H3CN (vinyl cyanide) on Titan. Liquid-phase simulations of Titan's seas indicate that vinyl cyanide molecules could combine to form vesicle membranes (similar to the cells of terrestrial biology), and the astrobiological implications of this discovery will be discussed. Furthermore, ALMA observations provide instantaneous snapshot mapping of Titan's entire Earth-facing hemisphere, for gases inaccessible to previous instruments. Combined with complementary data obtained from the Cassini Saturn orbiter, as well as theoretical models and laboratory studies, our observed, seasonally variable, spatially resolved abundance patterns are capable of providing new insights into photochemical production and transport in primitive planetary atmospheres in the Solar System and beyond.

  2. Comprehensive Airborne in Situ Characterization of Atmospheric Aerosols: From Angular Light Scattering to Particle Microphysics

    Science.gov (United States)

    Espinosa, W. Reed

    A comprehensive understanding of atmospheric aerosols is necessary both to understand Earth's climate as well as produce skillful air quality forecasts. In order to advance our understanding of aerosols, the Laboratory for Aerosols, Clouds and Optics (LACO) has recently developed the Imaging Polar Nephelometer instrument concept for the in situ measurement of aerosol scattering properties. Imaging Nephelometers provide measurements of absolute phase function and polarized phase function over a wide angular range, typically 3 degrees to 177 degrees, with an angular resolution smaller than one degree. The first of these instruments, the Polarized Imaging Nephelometer (PI-Neph), has taken part in five airborne field experiments and is the only modern aerosol polar nephelometer to have flown aboard an aircraft. A method for the retrieval of aerosol optical and microphysical properties from I-Neph measurements is presented and the results are compared with existing measurement techniques. The resulting retrieved particle size distributions agree to within experimental error with measurements made by commercial optical particle counters. Additionally, the retrieved real part of the refractive index is generally found to be within the predicted error of 0.02 from the expected values for three species of humidified salt particles, whose refractive index is well established. A synopsis is then presented of aerosol scattering measurements made by the PI-Neph during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) and the Deep Convection Clouds and Chemistry (DC3) field campaigns. To better summarize these extensive datasets a novel aerosol classification scheme is developed, making use of ancillary data that includes gas tracers, chemical composition, aerodynamic particle size and geographic location, all independent of PI-Neph measurements. Principal component analysis (PCA) is then used to reduce the

  3. W-band spaceborne radar observations of atmospheric river events

    Science.gov (United States)

    Matrosov, S. Y.

    2010-12-01

    While the main objective of the world first W-band radar aboard the CloudSat satellite is to provide vertically resolved information on clouds, it proved to be a valuable tool for observing precipitation. The CloudSat radar is generally able to resolve precipitating cloud systems in their vertical entirety. Although measurements from the liquid hydrometer layer containing rainfall are strongly attenuated, special retrieval approaches can be used to estimate rainfall parameters. These approaches are based on vertical gradients of observed radar reflectivity factor rather than on absolute estimates of reflectivity. Concurrent independent estimations of ice cloud parameters in the same vertical column allow characterization of precipitating systems and provide information on coupling between clouds and rainfall they produce. The potential of CloudSat for observations atmospheric river events affecting the West Coast of North America is evaluated. It is shown that spaceborne radar measurements can provide high resolution information on the height of the freezing level thus separating areas of rainfall and snowfall. CloudSat precipitation rate estimates complement information from the surface-based radars. Observations of atmospheric rivers at different locations above the ocean and during landfall help to understand evolutions of atmospheric rivers and their structures.

  4. Superconducting-Magnet-Based Faraday Rotation Spectrometer for Real Time in Situ Measurement of OH Radicals at 106 Molecule/cm3 Level in an Atmospheric Simulation Chamber.

    Science.gov (United States)

    Zhao, Weixiong; Fang, Bo; Lin, Xiaoxiao; Gai, Yanbo; Zhang, Weijun; Chen, Wenge; Chen, Zhiyou; Zhang, Haifeng; Chen, Weidong

    2018-03-20

    Atmospheric simulation chambers play vital roles in the validation of chemical mechanisms and act as a bridge between field measurements and modeling. Chambers operating at atmospheric levels of OH radicals (10 6 -10 7 molecule/cm 3 ) can significantly enhance the possibility for investigating the discrepancies between the observation and model predications. However, few chambers can directly detect chamber OH radicals at ambient levels. In this paper, we report on the first combination of a superconducting magnet with midinfrared Faraday rotation spectroscopy (FRS) for real time in situ measurement of the OH concentration in an atmospheric simulation chamber. With the use of a multipass enhanced FRS, a detection limit of 3.2 × 10 6 OH/cm 3 (2σ, 4 s) was achieved with an absorption path length of 108 m. The developed FRS system provided a unique, self-calibrated analytical instrument for in situ direct measurement of chamber OH concentration.

  5. Atmospheric gamma-ray observation with the BETS detectorfor calibrating atmospheric neutrino flux calculations

    CERN Document Server

    Kasahara, K.; Torii, S.; Tamura, T.; Tateyama, N.; Yoshida, K.; Yamagami, T.; Saito, Y.; Nishimura, J.; Murakami, H.; Kobayashi, T.; Komori, Y.; Honda, M.; Ohuchi, T.; Midorikawa, S.; Yuda, T.

    2002-01-01

    We observed atmospheric gamma-rays around 10 GeV at balloon altitudes (15~25 km) and at a mountain (2770 m a.s.l). The observed results were compared with Monte Carlo calculations to find that an interaction model (Lund Fritiof1.6) used in an old neutrino flux calculation was not good enough for describing the observed values. In stead, we found that two other nuclear interaction models, Lund Fritiof7.02 and dpmjet3.03, gave much better agreement with the observations. Our data will serve for examining nuclear interaction models and for deriving a reliable absolute atmospheric neutrino flux in the GeV region.

  6. Observational Evidence of Magnetic Waves in the Solar Atmosphere

    Science.gov (United States)

    McIntosh, Scott W.

    2012-03-01

    The observational evidence in supporting the presence of magnetic waves in the outer solar atmosphere is growing rapidly - we will discuss recent observations and place them in context with salient observations made in the past. While the clear delineation of these magnetic wave "modes" is unclear, much can be learned about the environment in which they originated and possibly how they are removed from the system from the observations. Their diagnostic power is, as yet, untapped and their energy content (both as a mechanical source for the heating of coronal material and acceleration of the solar wind) remains in question, but can be probed observationally - raising challenges for modeling efforts. We look forward to the IRIS mission by proposing some sample observing sequences to help resolve some of the zoological issues present in the literature.

  7. Interpretation of TOMS Observations of Tropical Tropospheric Ozone with a Global Model and In Situ Observations

    Science.gov (United States)

    Martin, Randall V.; Jacob, Daniel J.; Logan, Jennifer A.; Bey, Isabelle; Yantosca, Robert M.; Staudt, Amanda C.; Fiore, Arlene M.; Duncan, Bryan N.; Liu, Hongyu; Ginoux, Paul

    2004-01-01

    We interpret the distribution of tropical tropospheric ozone columns (TTOCs) from the Total Ozone Mapping Spectrometer (TOMS) by using a global three-dimensional model of tropospheric chemistry (GEOS-CHEM) and additional information from in situ observations. The GEOS-CHEM TTOCs capture 44% of the variance of monthly mean TOMS TTOCs from the convective cloud differential method (CCD) with no global bias. Major discrepancies are found over northern Africa and south Asia where the TOMS TTOCs do not capture the seasonal enhancements from biomass burning found in the model and in aircraft observations. A characteristic feature of these northern topical enhancements, in contrast to southern tropical enhancements, is that they are driven by the lower troposphere where the sensitivity of TOMS is poor due to Rayleigh scattering. We develop an efficiency correction to the TOMS retrieval algorithm that accounts for the variability of ozone in the lower troposphere. This efficiency correction increases TTOC's over biomass burning regions by 3-5 Dobson units (DU) and decreases them by 2-5 DU over oceanic regions, improving the agreement between CCD TTOCs and in situ observations. Applying the correction to CCD TTOCs reduces by approximately DU the magnitude of the "tropical Atlantic paradox" [Thompson et al, 2000], i.e. the presence of a TTOC enhancement over the southern tropical Atlantic during the northern African biomass burning season in December-February. We reproduce the remainder of the paradox in the model and explain it by the combination of upper tropospheric ozone production from lightning NOx, peristent subsidence over the southern tropical Atlantic as part of the Walker circulation, and cross-equatorial transport of upper tropospheric ozone from northern midlatitudes in the African "westerly duct." These processes in the model can also account for the observed 13-17 DU persistent wave-1 pattern in TTOCs with a maximum above the tropical Atlantic and a minimum

  8. Abrupt rise in atmospheric CO2 at the onset of the Bølling/Allerød: in-situ ice core data versus true atmospheric signals

    Directory of Open Access Journals (Sweden)

    J. Chappellaz

    2011-05-01

    Full Text Available During the last glacial/interglacial transition the Earth's climate underwent abrupt changes around 14.6 kyr ago. Temperature proxies from ice cores revealed the onset of the Bølling/Allerød (B/A warm period in the north and the start of the Antarctic Cold Reversal in the south. Furthermore, the B/A was accompanied by a rapid sea level rise of about 20 m during meltwater pulse (MWP 1A, whose exact timing is a matter of current debate. In-situ measured CO2 in the EPICA Dome C (EDC ice core also revealed a remarkable jump of 10 ± 1 ppmv in 230 yr at the same time. Allowing for the modelled age distribution of CO2 in firn, we show that atmospheric CO2 could have jumped by 20–35 ppmv in less than 200 yr, which is a factor of 2–3.5 greater than the CO2 signal recorded in-situ in EDC. This rate of change in atmospheric CO2 corresponds to 29–50% of the anthropogenic signal during the last 50 yr and is connected with a radiative forcing of 0.59–0.75 W m−2. Using a model-based airborne fraction of 0.17 of atmospheric CO2, we infer that 125 Pg of carbon need to be released into the atmosphere to produce such a peak. If the abrupt rise in CO2 at the onset of the B/A is unique with respect to other Dansgaard/Oeschger (D/O events of the last 60 kyr (which seems plausible if not unequivocal based on current observations, then the mechanism responsible for it may also have been unique. Available δ13CO2 data are neutral, whether the source of the carbon is of marine or terrestrial origin. We therefore hypothesise that most of the carbon might have been activated as a consequence of continental shelf flooding during MWP-1A. This potential impact of rapid sea level rise on atmospheric CO2 might define the point of no return during the last deglaciation.

  9. Atmospheric interaction with nanosatellites from observed orbital decay

    Science.gov (United States)

    Macario-Rojas, A.; Smith, K. L.; Crisp, N. H.; Roberts, P. C. E.

    2018-06-01

    Nanosatellites have gained considerable presence in low Earth orbits wherein the atmospheric interaction with exposed surfaces plays a fundamental role in the evolution of motion. These aspects become relevant with the increasing applicability of nanosatellites to a broader range of missions objectives. This investigation sets out to determine distinctive drag coefficient development and attributes of atmospheric gas-surface interactions in nanosatellites in the common form of standard 3U CubeSats from observed orbital decay. As orbital decay can be measured with relative accuracy, and its mechanism broken down into its constituent sources, the value of drag-related coefficients can be inferred by fitting modelled orbit predictions to observed data wherein the coefficient of interest is the adjusted parameter. The analysis uses the data of ten historical missions with documented passive attitude stabilisation strategies to reduce uncertainties. Findings indicate that it is possible to estimate fitted drag coefficients in CubeSats with physical representativeness. Assessment of atomic oxygen surface coverage derived from the fitted drag coefficients is broadly consistent with theoretical trends. The proposed methodology opens the possibility to assess atmospheric interaction characteristics by using the unprecedented opportunity arising from the numerous observed orbital decay of nanosatellites.

  10. LIDAR Developments at Clermont-Ferrand—France for Atmospheric Observation

    Science.gov (United States)

    Fréville, Patrick; Montoux, Nadège; Baray, Jean-Luc; Chauvigné, Aurélien; Réveret, François; Hervo, Maxime; Dionisi, Davide; Payen, Guillaume; Sellegri, Karine

    2015-01-01

    We present a Rayleigh-Mie-Raman LIDAR system in operation at Clermont-Ferrand (France) since 2008. The system provides continuous vertical tropospheric profiles of aerosols, cirrus optical properties and water vapour mixing ratio. Located in proximity to the high altitude Puy de Dôme station, labelled as the GAW global station PUY since August 2014, it is a useful tool to describe the boundary layer dynamics and hence interpret in situ measurements. This LIDAR has been upgraded with specific hardware/software developments and laboratory calibrations in order to improve the quality of the profiles, calibrate the depolarization ratio, and increase the automation of operation. As a result, we provide a climatological water vapour profile analysis for the 2009–2013 period, showing an annual cycle with a winter minimum and a summer maximum, consistent with in-situ observations at the PUY station. An overview of a preliminary climatology of cirrus clouds frequency shows that in 2014, more than 30% of days present cirrus events. Finally, the backscatter coefficient profile observed on 27 September 2014 shows the capacity of the system to detect cirrus clouds at 13 km altitude, in presence of aerosols below the 5 km altitude. PMID:25643059

  11. Statistical Similarities Between WSA-ENLIL+Cone Model and MAVEN in Situ Observations From November 2014 to March 2016

    Science.gov (United States)

    Lentz, C. L.; Baker, D. N.; Jaynes, A. N.; Dewey, R. M.; Lee, C. O.; Halekas, J. S.; Brain, D. A.

    2018-02-01

    Normal solar wind flows and intense solar transient events interact directly with the upper Martian atmosphere due to the absence of an intrinsic global planetary magnetic field. Since the launch of the Mars Atmosphere and Volatile EvolutioN (MAVEN) mission, there are now new means to directly observe solar wind parameters at the planet's orbital location for limited time spans. Due to MAVEN's highly elliptical orbit, in situ measurements cannot be taken while MAVEN is inside Mars' magnetosheath. To model solar wind conditions during these atmospheric and magnetospheric passages, this research project utilized the solar wind forecasting capabilities of the WSA-ENLIL+Cone model. The model was used to simulate solar wind parameters that included magnetic field magnitude, plasma particle density, dynamic pressure, proton temperature, and velocity during a four Carrington rotation-long segment. An additional simulation that lasted 18 Carrington rotations was then conducted. The precision of each simulation was examined for intervals when MAVEN was in the upstream solar wind, that is, with no exospheric or magnetospheric phenomena altering in situ measurements. It was determined that generalized, extensive simulations have comparable prediction capabilities as shorter, more comprehensive simulations. Generally, this study aimed to quantify the loss of detail in long-term simulations and to determine if extended simulations can provide accurate, continuous upstream solar wind conditions when there is a lack of in situ measurements.

  12. In situ observation of the formation of FeSe

    DEFF Research Database (Denmark)

    Grivel, Jean-Claude; Wulff, Anders Christian; Yue, Zhao

    2011-01-01

    The formation of the FeSe compound from a mixture of Fe and Se powders encased in a composite Cu/Nb sheath was studied in situ by means of high-energy synchrotron x-ray diffraction. Tetragonal beta-FeSe does not seem to form directly from the starting elements. Instead, a sequence of FeSe2, Fe3Se...

  13. Atmospheric Retrievals from Exoplanet Observations and Simulations with BART

    Science.gov (United States)

    Harrington, Joseph

    This project will determine the observing plans needed to retrieve exoplanet atmospheric composition and thermal profiles over a broad range of planets, stars, instruments, and observing modes. Characterizing exoplanets is hard. The dim planets orbit bright stars, giving orders of magnitude more relative noise than for solar-system planets. Advanced statistical techniques are needed to determine what the data can - and more importantly cannot - say. We therefore developed Bayesian Atmospheric Radiative Transfer (BART). BART explores the parameter space of atmospheric chemical abundances and thermal profiles using Differential-Evolution Markov-Chain Monte Carlo. It generates thousands of candidate spectra, integrates over observational bandpasses, and compares to data, generating a statistical model for an atmosphere's composition and thermal structure. At best, it gives abundances and thermal profiles with uncertainties. At worst, it shows what kinds of planets the data allow. It also gives parameter correlations. BART is open-source, designed for community use and extension (http://github.com/exosports/BART). Three arXived PhD theses (papers in publication) provide technical documentation, tests, and application to Spitzer and HST data. There are detailed user and programmer manuals and community support forums. Exoplanet analysis techniques must be tested against synthetic data, where the answer is known, and vetted by statisticians. Unfortunately, this has rarely been done, and never sufficiently. Several recent papers question the entire body of Spitzer exoplanet observations, because different analyses of the same data give different results. The latest method, pixel-level decorrelation, produces results that diverge from an emerging consensus. We do not know the retrieval problem's strengths and weaknesses relative to low SNR, red noise, low resolution, instrument systematics, or incomplete spectral line lists. In observing eclipses and transits, we assume

  14. Research Opportunities from Emerging Atmospheric Observing and Modeling Capabilities.

    Science.gov (United States)

    Dabberdt, Walter F.; Schlatter, Thomas W.

    1996-02-01

    The Second Prospectus Development Team (PDT-2) of the U.S. Weather Research Program was charged with identifying research opportunities that are best matched to emerging operational and experimental measurement and modeling methods. The overarching recommendation of PDT-2 is that inputs for weather forecast models can best be obtained through the use of composite observing systems together with adaptive (or targeted) observing strategies employing both in situ and remote sensing. Optimal observing systems and strategies are best determined through a three-part process: observing system simulation experiments, pilot field measurement programs, and model-assisted data sensitivity experiments. Furthermore, the mesoscale research community needs easy and timely access to the new operational and research datasets in a form that can readily be reformatted into existing software packages for analysis and display. The value of these data is diminished to the extent that they remain inaccessible.The composite observing system of the future must combine synoptic observations, routine mobile observations, and targeted observations, as the current or forecast situation dictates. High costs demand fuller exploitation of commercial aircraft, meteorological and navigation [Global Positioning System (GPS)] satellites, and Doppler radar. Single observing systems must be assessed in the context of a composite system that provides complementary information. Maintenance of the current North American rawinsonde network is critical for progress in both research-oriented and operational weather forecasting.Adaptive sampling strategies are designed to improve large-scale and regional weather prediction but they will also improve diagnosis and prediction of flash flooding, air pollution, forest fire management, and other environmental emergencies. Adaptive measurements can be made by piloted or unpiloted aircraft. Rawinsondes can be launched and satellites can be programmed to make

  15. Exploring atmospheric blocking with GPS radio occultation observations

    Directory of Open Access Journals (Sweden)

    L. Brunner

    2016-04-01

    Full Text Available Atmospheric blocking has been closely investigated in recent years due to its impact on weather and climate, such as heat waves, droughts, and flooding. We use, for the first time, satellite-based observations from Global Positioning System (GPS radio occultation (RO and explore their ability to resolve blocking in order to potentially open up new avenues complementing models and reanalyses. RO delivers globally available and vertically highly resolved profiles of atmospheric variables such as temperature and geopotential height (GPH. Applying a standard blocking detection algorithm, we find that RO data robustly capture blocking as demonstrated for two well-known blocking events over Russia in summer 2010 and over Greenland in late winter 2013. During blocking episodes, vertically resolved GPH gradients show a distinct anomalous behavior compared to climatological conditions up to 300 hPa and sometimes even further up into the tropopause. The accompanying increase in GPH of up to 300 m in the upper troposphere yields a pronounced tropopause height increase. Corresponding temperatures rise up to 10 K in the middle and lower troposphere. These results demonstrate the feasibility and potential of RO to detect and resolve blocking and in particular to explore the vertical structure of the atmosphere during blocking episodes. This new observation-based view is available globally at the same quality so that blocking in the Southern Hemisphere can also be studied with the same reliability as in the Northern Hemisphere.

  16. Documentation of Atmospheric Conditions During Observed Rising Aircraft Wakes

    Science.gov (United States)

    Zak, J. Allen; Rodgers, William G., Jr.

    1997-01-01

    Flight tests were conducted in the fall of 1995 off the coast of Wallops Island, Virginia in order to determine characteristics of wake vortices at flight altitudes. A NASA Wallops Flight Facility C130 aircraft equipped with smoke generators produced visible wakes at altitudes ranging from 775 to 2225 m in a variety of atmospheric conditions, orientations (head wind, cross wind), and airspeeds. Meteorological and aircraft parameters were collected continuously from a Langley Research Center OV-10A aircraft as it flew alongside and through the wake vortices at varying distances behind the C130. Meteorological data were also obtained from special balloon observations made at Wallops. Differential GPS capabilities were on each aircraft from which accurate altitude profiles were obtained. Vortices were observed to rise at distances beyond a mile behind the C130. The maximum altitude was 150 m above the C130 in a near neutral atmosphere with significant turbulence. This occurred from large vertical oscillations in the wakes. There were several cases when vortices did not descend after a very short initial period and remained near generation altitude in a variety of moderately stable atmospheres and wind shears.

  17. Upper atmospheric planetary-wave and gravity-wave observations

    Science.gov (United States)

    Justus, C. G.; Woodrum, A.

    1973-01-01

    Previously collected data on atmospheric pressure, density, temperature and winds between 25 and 200 km from sources including Meteorological Rocket Network data, ROBIN falling sphere data, grenade release and pitot tube data, meteor winds, chemical release winds, satellite data, and others were analyzed by a daily-difference method, and results on the magnitude of atmospheric perturbations interpreted as gravity waves and planetary waves are presented. Traveling planetary-wave contributions in the 25-85 km range were found to have significant height and latitudinal variation. It was found that observed gravity-wave density perturbations and wind are related to one another in the manner predicted by gravity-wave theory. It was determined that, on the average, gravity-wave energy deposition or reflection occurs at all altitudes except the 55-75 km region of the mesosphere.

  18. Observational constraints on the global atmospheric budget of ethanol

    Directory of Open Access Journals (Sweden)

    V. Naik

    2010-06-01

    Full Text Available Energy security and climate change concerns have led to the promotion of biomass-derived ethanol, an oxygenated volatile organic compound (OVOC, as a substitute for fossil fuels. Although ethanol is ubiquitous in the troposphere, our knowledge of its current atmospheric budget and distribution is limited. Here, for the first time we use a global chemical transport model in conjunction with atmospheric observations to place constraints on the ethanol budget, noting that additional measurements of ethanol (and its precursors are still needed to enhance confidence in our estimated budget. Global sources of ethanol in the model include 5.0 Tg yr−1 from industrial sources and biofuels, 9.2 Tg yr−1 from terrestrial plants, ~0.5 Tg yr−1 from biomass burning, and 0.05 Tg yr−1 from atmospheric reactions of the ethyl peroxy radical (C2H5O2 with itself and with the methyl peroxy radical (CH3O2. The resulting atmospheric lifetime of ethanol in the model is 2.8 days. Gas-phase oxidation by the hydroxyl radical (OH is the primary global sink of ethanol in the model (65%, followed by dry deposition (25%, and wet deposition (10%. Over continental areas, ethanol concentrations predominantly reflect direct anthropogenic and biogenic emission sources. Uncertainty in the biogenic ethanol emissions, estimated at a factor of three, may contribute to the 50% model underestimate of observations in the North American boundary layer. Current levels of ethanol measured in remote regions are an order of magnitude larger than those in the model, suggesting a major gap in understanding. Stronger constraints on the budget and distribution of ethanol and OVOCs are a critical step towards assessing the impacts of increasing the use of ethanol as a fuel.

  19. CAOS: the nested catchment soil-vegetation-atmosphere observation platform

    Science.gov (United States)

    Weiler, Markus; Blume, Theresa

    2016-04-01

    Most catchment based observations linking hydrometeorology, ecohydrology, soil hydrology and hydrogeology are typically not integrated with each other and lack a consistent and appropriate spatial-temporal resolution. Within the research network CAOS (Catchments As Organized Systems), we have initiated and developed a novel and integrated observation platform in several catchments in Luxembourg. In 20 nested catchments covering three distinct geologies the subscale processes at the bedrock-soil-vegetation-atmosphere interface are being monitored at 46 sensor cluster locations. Each sensor cluster is designed to observe a variety of different fluxes and state variables above and below ground, in the saturated and unsaturated zone. The numbers of sensors are chosen to capture the spatial variability as well the average dynamics. At each of these sensor clusters three soil moisture profiles with sensors at different depths, four soil temperature profiles as well as matric potential, air temperature, relative humidity, global radiation, rainfall/throughfall, sapflow and shallow groundwater and stream water levels are measured continuously. In addition, most sensors also measure temperature (water, soil, atmosphere) and electrical conductivity. This setup allows us to determine the local water and energy balance at each of these sites. The discharge gauging sites in the nested catchments are also equipped with automatic water samplers to monitor water quality and water stable isotopes continuously. Furthermore, water temperature and electrical conductivity observations are extended to over 120 locations distributed across the entire stream network to capture the energy exchange between the groundwater, stream water and atmosphere. The measurements at the sensor clusters are complemented by hydrometeorological observations (rain radar, network of distrometers and dense network of precipitation gauges) and linked with high resolution meteorological models. In this

  20. Atmospheric multidecadal variations in the North Atlantic realm: proxy data, observations, and atmospheric circulation model studies

    Directory of Open Access Journals (Sweden)

    K. Grosfeld

    2007-01-01

    Full Text Available We investigate the spatial and temporal characteristics of multidecadal climate variability in the North Atlantic realm, using observational data, proxy data and model results. The dominant pattern of multidecadal variability of SST depicts a monopolar structure in the North Atlantic during the instrumental period with cold (warm phases during 1900–1925 and 1970–1990 (1870–1890 and 1940–1960. Two atmospheric general circulation models of different complexity forced with global SST over the last century show SLP anomaly patterns from the warm and cold phases of the North Atlantic similar to the corresponding observed patterns. The analysis of a sediment core from Cariaco Basin, a coral record from the northern Red Sea, and a long-term sea level pressure (SLP reconstruction reveals that the multidecadal mode of the atmospheric circulation characterizes climate variability also in the pre-industrial era. The analyses of SLP reconstruction and proxy data depict a persistent atmospheric mode at least over the last 300 years, where SLP shows a dipolar structure in response to monopolar North Atlantic SST, in a similar way as the models' responses do. The combined analysis of observational and proxy data with model experiments provides an understanding of multidecadal climate modes during the late Holocene. The related patterns are useful for the interpretation of proxy data in the North Atlantic realm.

  1. Spectral observations of atmospheric #betta#-ray background

    International Nuclear Information System (INIS)

    Jayanthi, U.B.; Blanco, F.G.; Aguiar, O.D. de; Jardim, J.O.D.; Benson, J.L.; Martin, I.M.; Rao, K.R.

    1981-05-01

    Based on the results of two balloon flights, made at Sao Jose dos Campos and at Juazeiro do Norte in Brazil, using omnidirectional gamma ray detectors, the different aspects of atmospheric gamma rays at equatorial latitudes in the energy interval of 0.3 to 4.5 MeV are investigated. The energy loss spectrum in this energy band is found no consist of a continuum and a photo peak at 0.51 MeV in agreement with previous observations. A discussion of the spectral nature of this background and the observed lower intensities of both the continuum and the 0.51 MeV line with reference to observations at other latitudes is presented. (Author) [pt

  2. Atmospheric aerosol layers over Bangkok Metropolitan Region from CALIPSO observations

    Science.gov (United States)

    Bridhikitti, Arika

    2013-06-01

    Previous studies suggested that aerosol optical depth (AOD) from the Earth Observing System satellite retrievals could be used for inference of ground-level air quality in various locations. This application may be appropriate if pollution in elevated atmospheric layers is insignificant. This study investigated the significance of elevated air pollution layers over the Bangkok Metropolitan Region (BMR) from all available aerosol layer scenes taken from Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations (CALIPSO) for years 2007 to 2011. The results show that biomass burning smoke layers alone were the most frequently observed. The smoke layers accounted for high AOD variations and increased AOD levels. In the dry seasons, the smoke layers alone with high AOD levels were likely brought to the BMR via northeasterly to easterly prevailing winds and found at altitudes above the typical BMR mixing heights of approximately 0.7 to 1.5 km. The smoke should be attributed to biomass burning emissions outside the BMR.

  3. Observations of Co-variation in Cloud Properties and their Relationships with Atmospheric State

    Science.gov (United States)

    Sinclair, K.; van Diedenhoven, B.; Fridlind, A. M.; Arnold, T. G.; Yorks, J. E.; Heymsfield, G. M.; McFarquhar, G. M.; Um, J.

    2017-12-01

    Radiative properties of upper tropospheric ice clouds are generally not well represented in global and cloud models. Cloud top height, cloud thermodynamic phase, cloud optical thickness, cloud water path, particle size and ice crystal shape all serve as observational targets for models to constrain cloud properties. Trends or biases in these cloud properties could have profound effects on the climate since they affect cloud radiative properties. Better understanding of co-variation between these cloud properties and linkages with atmospheric state variables can lead to better representation of clouds in models by reducing biases in their micro- and macro-physical properties as well as their radiative properties. This will also enhance our general understanding of cloud processes. In this analysis we look at remote sensing, in situ and reanalysis data from the MODIS Airborne Simulator (MAS), Cloud Physics Lidar (CPL), Cloud Radar System (CRS), GEOS-5 reanalysis data and GOES imagery obtained during the Tropical Composition, Cloud and Climate Coupling (TC4) airborne campaign. The MAS, CPL and CRS were mounted on the ER-2 high-altitude aircraft during this campaign. In situ observations of ice size and shape were made aboard the DC8 and WB57 aircrafts. We explore how thermodynamic phase, ice effective radius, particle shape and radar reflectivity vary with altitude and also investigate how these observed cloud properties vary with cloud type, cloud top temperature, relative humidity and wind profiles. Observed systematic relationships are supported by physical interpretations of cloud processes and any unexpected differences are examined.

  4. A tethered balloon system for observation of atmospheric temperature inversion

    International Nuclear Information System (INIS)

    Hayashi, Takashi; Kakuta, Michio

    1979-05-01

    In environmental assessment of near-shore nuclear plants, information is often required on the development of internal boundary layer (IBL) and associated fumigation condition. Single tower data is not sufficient to clarify the site-dependent IBL structure that affects the atmospheric diffusion in shoreline-stack-site boundary complex. A tethered balloon system has been developed, which comprises a fixed point kitoon and a car-borne small balloon. The system enables us to measure the detailed time-space distribution of temperature without much man-power. The system and example of field observations with it are described. (author)

  5. Application of aerosol speciation data as an in situ dust proxy for validation of the Dust Regional Atmospheric Model (DREAM)

    Science.gov (United States)

    Shaw, Patrick

    The Dust REgional Atmospheric Model (DREAM) predicts concentrations of mineral dust aerosols in time and space, but validation is challenging with current in situ particulate matter (PM) concentration measurements. Measured levels of ambient PM often contain anthropogenic components as well as windblown mineral dust. In this study, two approaches to model validation were performed with data from preexisting air quality monitoring networks: using hourly concentrations of total PM with aerodynamic diameter less than 2.5 μm (PM 2.5); and using a daily averaged speciation-derived soil component. Validation analyses were performed for point locations within the cities of El Paso (TX), Austin (TX), Phoenix (AZ), Salt Lake City (UT) and Bakersfield (CA) for most of 2006. Hourly modeled PM 2.5 did not validate at all with hourly observations among the sites (combined R hourly values). Aerosol chemical speciation data distinguished between mineral (soil) dust from anthropogenic ambient PM. As expected, statistically significant improvements in correlation among all stations (combined R = 0.16, N = 343 daily values) were found when the soil component alone was used to validate DREAM. The validation biases that result from anthropogenic aerosols were also reduced using the soil component. This is seen in the reduction of the root mean square error between hourly in situ versus hourly modeled (RMSE hourly = 18.6 μg m -3) and 24-h in situ speciation values versus daily averaged observed (RMSE soil = 12.0 μg m -3). However, the lack of a total reduction in RMSE indicates there is still room for improvement in the model. While the soil component is the theoretical proxy of choice for a dust transport model, the current sparse and infrequent sampling is not ideal for routine hourly air quality forecast validation.

  6. The grand challenge of developing in situ observational oceanography in South Africa

    CSIR Research Space (South Africa)

    Roberts, M

    2010-12-01

    Full Text Available , underwater temperature recorders (UTRs), wave buoys, as well as locally developed in situ measurement sensor and platform prototypes (dial-out UTRs, coastal and deep ocean buoys) have been incorporated into a regional in-situ observational network. A modular...

  7. Surface-atmospheric water cycle at Gale crater through multi-year MSL/REMS observations

    Science.gov (United States)

    Harri, A. M.; Genzer, M.; McConnochie, T. H.; Savijarvi, H. I.; Smith, M. D.; Martinez, G.; de la Torre Juarez, M.; Haberle, R. M.; Polkko, J.; Gomez-Elvira, J.; Renno, N. O.; Kemppinen, O.; Paton, M.; Richardson, M. I.; Newman, C. E.; Siili, T. T.; Mäkinen, T.

    2017-12-01

    The Mars Science laboratory (MSL) has been successfully operating for almost three Martian years. That includes an unprecedented long time series of atmospheric observations by the REMS instrument performing measurements of atmospheric pressure, relative humidity (REMS-H), temperature of the air, ground temperature, UV and wind speed and direction. The REMS-H relative humidity device is based on polymeric capacitive humidity sensors developed by Vaisala Inc. and it makes use of three (3) humidity sensor heads. The humidity device is mounted on the REMS boom providing ventilation with the ambient atmosphere through a filter protecting the device from airborne dust. The REMS-H humidity instrument has created an unprecedented data record of more than two full Martian. REMS-H measured the relative humidity and temperature at 1.6 m height for a period of 5 minutes every hour as part of the MSL/REMS instrument package. We focus on describing the annual in situ water cycle with the REMS-H instrument data for the period of almost three Martian years. The results will be constrained through comparison with independent indirect observations and through modeling efforts. We inferred the hourly atmospheric VMR from the REMS-H observations and compared these VMR measurements with predictions of VMR from our 1D column Martian atmospheric model and regolith to investigate the local water cycle, exchange processes and the local climate in Gale Crater. The strong diurnal variation suggests there are surface-atmosphere exchange processes at Gale Crater during all seasons, which depletes moisture to the ground in the evening and nighttime and release the moisture back to the atmosphere during the daytime. On the other hand, these processes do not seem to result in significant water deposition on the ground. Hence, our modelling results presumably indicate that adsorption processes take place during the nighttime and desorption during the daytime. Other processes, e.g. convective

  8. Scaling in situ cosmogenic nuclide production rates using analytical approximations to atmospheric cosmic-ray fluxes

    Science.gov (United States)

    Lifton, Nathaniel; Sato, Tatsuhiko; Dunai, Tibor J.

    2014-01-01

    Several models have been proposed for scaling in situ cosmogenic nuclide production rates from the relatively few sites where they have been measured to other sites of interest. Two main types of models are recognized: (1) those based on data from nuclear disintegrations in photographic emulsions combined with various neutron detectors, and (2) those based largely on neutron monitor data. However, stubborn discrepancies between these model types have led to frequent confusion when calculating surface exposure ages from production rates derived from the models. To help resolve these discrepancies and identify the sources of potential biases in each model, we have developed a new scaling model based on analytical approximations to modeled fluxes of the main atmospheric cosmic-ray particles responsible for in situ cosmogenic nuclide production. Both the analytical formulations and the Monte Carlo model fluxes on which they are based agree well with measured atmospheric fluxes of neutrons, protons, and muons, indicating they can serve as a robust estimate of the atmospheric cosmic-ray flux based on first principles. We are also using updated records for quantifying temporal and spatial variability in geomagnetic and solar modulation effects on the fluxes. A key advantage of this new model (herein termed LSD) over previous Monte Carlo models of cosmogenic nuclide production is that it allows for faster estimation of scaling factors based on time-varying geomagnetic and solar inputs. Comparing scaling predictions derived from the LSD model with those of previously published models suggest potential sources of bias in the latter can be largely attributed to two factors: different energy responses of the secondary neutron detectors used in developing the models, and different geomagnetic parameterizations. Given that the LSD model generates flux spectra for each cosmic-ray particle of interest, it is also relatively straightforward to generate nuclide-specific scaling

  9. Attraction of semiconductor nanowires: An in situ observation

    International Nuclear Information System (INIS)

    Chen, Bin; Gao, Qiang; Chang, Li; Wang, Yanbo; Chen, Zibin; Liao, Xiaozhou; Tan, Hark Hoe; Zou, Jin; Ringer, Simon P.; Jagadish, Chennupati

    2013-01-01

    Graphical abstract: -- Abstract: In situ deformation transmission electron microscopy was used to study the attraction behavior of GaAs semiconductor nanowires (NWs). The NWs demonstrated an interesting phenomenon of either head-to-head or body-to-body attraction at distances that depend on the NW diameters. The NWs with a diameter of ∼25 nm attracted at a distance of ∼25 nm, while large-diameter NWs of ∼55 nm showed no obvious attraction. The underlying mechanism governing the attraction of the NWs is proposed and discussed with a mechanistic model. The diameter dependence on the NW attraction behavior is discussed. The finding provides an understanding of the Ampère force in nanostructured materials caused by an electron-beam-induced current while technologically it provides useful hints for designing NW-based devices according to the diameter-dependent attraction behavior of NWs

  10. Observations on the in situ contamination of some marine species

    International Nuclear Information System (INIS)

    Guegueniat, Pierre; Lucas, Yves

    1969-09-01

    Measurements carried out in 1966-1968 in the Bay of Ecalgrain in the La Hague region which is subjected to radioactive waste disposal, have made it possible to begin an in-situ study of fission product transfer, in particular of ruthenium 106, in marine waters. A certain number of concentration factors have been determined and compared to those obtained experimentally. From the monitoring point of view, attention is drawn to the following species which, because of their high accumulation power, give a more sensitive indication of the contamination of the site (indicator species), in particular for ruthenium: Sea-weed: Corallina officinalis; Spongiae: Pachymatisma johnstoni (amongst other species of spongiae); Ascidium: Dendrodoa grossularia. (author) [fr

  11. Atmospheric ions and nucleation: a review of observations

    Directory of Open Access Journals (Sweden)

    A. Hirsikko

    2011-01-01

    Full Text Available This review is based on ca. 260 publications, 93 of which included data on the temporal and spatial variation of the concentration of small ions (<1.6 nm in diameter especially in the lower troposphere, chemical composition, or formation and growth rates of sub-3 nm ions. This information was collected on tables and figures. The small ions exist all the time in the atmosphere, and the average concentrations of positive and negative small ions are typically 200–2500 cm−3. However, concentrations up to 5000 cm−3 have been observed. The results are in agreement with observations of ion production rates in the atmosphere. We also summarised observations on the conversion of small ions to intermediate ions, which can act as embryos for new atmospheric aerosol particles. Those observations include the formation rates (J2[ion] of 2-nm intermediate ions, growth rates (GR[ion] of sub-3 nm ions, and information on the chemical composition of the ions. Unfortunately, there were only a few studies which presented J2[ion] and GR[ion]. Based on the publications, the formation rates of 2-nm ions were 0–1.1 cm−3 s−1, while the total 2-nm particle formation rates varied between 0.001 and 60 cm−3 s−1. Due to small changes in J2[ion], the relative importance of ions in 2-nm particle formation was determined by the large changes in J2[tot], and, accordingly the contribution of ions increased with decreasing J2[tot]. Furthermore, small ions were observed to activate for growth earlier than neutral nanometer-sized particles and at lower saturation ratio of condensing vapours.

  12. In Situ Denitrification and Biological Nitrogen Fixation Under Enhanced Atmospheric Reactive Nitrogen Deposition in UK Peatlands

    Science.gov (United States)

    Ullah, Sami; Saiz Val, Ernesto; Sgouridis, Fotis; Peichl, Matthias; Nilsson, Mats

    2017-04-01

    Dinitrogen (N2) and nitrous oxide (N2O) losses due to denitrification and biological N2 fixation (BNF) are the most uncertain components of the nitrogen (N) cycle in peatlands under enhanced atmospheric reactive nitrogen (Nr) deposition. This uncertainty hampers our ability to assess the contribution of denitrification to the removal of biologically fixed and/or atmospherically deposited Nr in peatlands. This uncertainty emanates from the difficulty in measuring in situ soil N2 and N2O production and consumption in peatlands. In situ denitrification and its contribution to total N2O flux was measured monthly between April 2013 and October 2014 in peatlands in two UK catchments. An adapted 15N-Gas Flux method1 with low level addition of 15N tracer (0.03 ± 0.005 kg 15N ha-1) was used to measure denitrification and its contribution to net N2O production (DN2O/TN2O). BNF was measured in situ through incubation of selected sphagnum species under 15N2 gas tracer. Denitrification2 varied temporally and averaged 8 kg N-N2 ha-1 y-1. The contribution of denitrification was about 48% to total N2O flux3 of 0.05 kg N ha-1 y-1. Soil moisture, temperature, ecosystem respiration, pH and mineral N content mainly regulated the flux of N2 and N2O. Preliminary results showed suppression of BNF, which was 1.8 to 7 times lower in peatland mosses exposed to ˜15 to 20 kg N ha-1 y-1 Nr deposition in the UK than in peatland mosses in northern Sweden with background Nr deposition. Overall, the contribution of denitrification to Nr removal in the selected peatlands was ˜50% of the annual Nr deposition rates, making these ecosystems vulnerable to chronic N saturation. These results point to a need for a more comprehensive annual BNF measurement to more accurately account for total Nr input into peatlands and its atmospheric loss due to denitrification. References Sgouridis F, Stott A & Ullah S, 2016. Application of the 15N-Gas Flux method for measuring in situ N2 and N2O fluxes due to

  13. Evaluation of surface layer flux parameterizations using in-situ observations

    Science.gov (United States)

    Katz, Jeremy; Zhu, Ping

    2017-09-01

    Appropriate calculation of surface turbulent fluxes between the atmosphere and the underlying ocean/land surface is one of the major challenges in geosciences. In practice, the surface turbulent fluxes are estimated from the mean surface meteorological variables based on the bulk transfer model combined with the Monnin-Obukhov Similarity (MOS) theory. Few studies have been done to examine the extent to which such a flux parameterization can be applied to different weather and surface conditions. A novel validation method is developed in this study to evaluate the surface flux parameterization using in-situ observations collected at a station off the coast of Gulf of Mexico. The main findings are: (a) the theoretical prediction that uses MOS theory does not match well with those directly computed from the observations. (b) The largest spread in exchange coefficients is shown in strong stable conditions with calm winds. (c) Large turbulent eddies, which depend strongly on the mean flow pattern and surface conditions, tend to break the constant flux assumption in the surface layer.

  14. Precipitation characteristics in tropical Africa using satellite and in situ observations

    Science.gov (United States)

    Dezfuli, A. K.; Ichoku, I.; Huffman, G. J.; Mohr, K. I.

    2017-12-01

    Tropical Africa receives nearly all its precipitation as a result of convection. The characteristics of rain-producing systems in this region have not been well-understood, despite their crucial role in regional and global circulation. This is mainly due to the lack of in situ observations. Here, we have used precipitation records from the Trans-African Hydro-Meteorological Observatory (TAHMO) ground-based gauge network to improve our knowledge about the rainfall systems in the region, and to validate the recently-released IMERG precipitation product based on satellite observations from the Global Precipitation Measurement (GPM) constellation. The high temporal resolution of the gauge data has allowed us to identify three classes of rain events based on their duration and intensity. The contribution of each class to the total rainfall and the favorable surface atmospheric conditions for each class have been examined. As IMERG aims to continue the legacy of its predecessor, TRMM Multi-Satellite Precipitation Analysis (TMPA), and provide higher resolution data, continent-wide comparisons are made between these two products. Due to its improved temporal resolution, IMERG shows some advantages over TMPA in capturing the diurnal cycle and propagation of the meso-scale convective systems. However, the performance of the two satellite-based products varies by season, region and the evaluation statistics. The results of this study serve as a basis for our ongoing work on the impacts of biomass burning on precipitation processes in Africa.

  15. Source attribution using FLEXPART and carbon monoxide emission inventories for the IAGOS In-situ Observation database

    Science.gov (United States)

    Fontaine, Alain; Sauvage, Bastien; Pétetin, Hervé; Auby, Antoine; Boulanger, Damien; Thouret, Valerie

    2016-04-01

    Since 1994, the IAGOS program (In-Service Aircraft for a Global Observing System http://www.iagos.org) and its predecessor MOZAIC has produced in-situ measurements of the atmospheric composition during more than 46000 commercial aircraft flights. In order to help analyzing these observations and further understanding the processes driving their evolution, we developed a modelling tool SOFT-IO quantifying their source/receptor link. We improved the methodology used by Stohl et al. (2003), based on the FLEXPART plume dispersion model, to simulate the contributions of anthropogenic and biomass burning emissions from the ECCAD database (http://eccad.aeris-data.fr) to the measured carbon monoxide mixing ratio along each IAGOS flight. Thanks to automated processes, contributions are simulated for the last 20 days before observation, separating individual contributions from the different source regions. The main goal is to supply add-value products to the IAGOS database showing pollutants geographical origin and emission type. Using this information, it may be possible to link trends in the atmospheric composition to changes in the transport pathways and to the evolution of emissions. This tool could be used for statistical validation as well as for inter-comparisons of emission inventories using large amounts of data, as Lagrangian models are able to bring the global scale emissions down to a smaller scale, where they can be directly compared to the in-situ observations from the IAGOS database.

  16. Airborne remote sensing and in situ measurements of atmospheric CO2 to quantify point source emissions

    Science.gov (United States)

    Krings, Thomas; Neininger, Bruno; Gerilowski, Konstantin; Krautwurst, Sven; Buchwitz, Michael; Burrows, John P.; Lindemann, Carsten; Ruhtz, Thomas; Schüttemeyer, Dirk; Bovensmann, Heinrich

    2018-02-01

    Reliable techniques to infer greenhouse gas emission rates from localised sources require accurate measurement and inversion approaches. In this study airborne remote sensing observations of CO2 by the MAMAP instrument and airborne in situ measurements are used to infer emission estimates of carbon dioxide released from a cluster of coal-fired power plants. The study area is complex due to sources being located in close proximity and overlapping associated carbon dioxide plumes. For the analysis of in situ data, a mass balance approach is described and applied, whereas for the remote sensing observations an inverse Gaussian plume model is used in addition to a mass balance technique. A comparison between methods shows that results for all methods agree within 10 % or better with uncertainties of 10 to 30 % for cases in which in situ measurements were made for the complete vertical plume extent. The computed emissions for individual power plants are in agreement with results derived from emission factors and energy production data for the time of the overflight.

  17. First In-Situ Observations of Exospheric Response to CME Impact at Mercury

    Science.gov (United States)

    Raines, J. M.; Wallace, K. L.; Sarantos, M.; Jasinksi, J. M.; Tracy, P. J.; Dewey, R. M.; Weberg, M. J.; Slavin, J. A.

    2018-05-01

    We present the first in-situ observations of enhancements to Mercury's He exosphere generated by CME impact. These results have implications for understanding exosphere generation and loss processes, as well space weathering of the planet's surface.

  18. Observations. Surface and Atmospheric Climate Change. Chapter 3

    Energy Technology Data Exchange (ETDEWEB)

    Trenberth, K.E.; Jones, P.D.; Ambenje, P.; Bojariu, R.; Easterling, D.; Klein Tank, A.; Parker, D.; Rahimzadeh, F.; Renwick, J.A.; Rusticucci, M.; Soden, B.; Zhai, P.

    2007-09-15

    This chapter assesses the observed changes in surface and atmospheric climate, placing new observations and new analyses made during the past six years (since the Third Assessment Report TAR) in the context of the previous instrumental record. In previous IPCC reports, palaeo-observations from proxy data for the pre-instrumental past and observations from the ocean and ice domains were included within the same chapter. This helped the overall assessment of the consistency among the various variables and their synthesis into a coherent picture of change. A short synthesis and scrutiny of the consistency of all the observations is included here (see Section 3.9). In the TAR, surface temperature trends were examined from 1860 to 2000 globally, for 1901 to 2000 as maps and for three sub-periods (1910-1945, 1946-1975 and 1976-2000). The first and third sub-periods had rising temperatures, while the second sub-period had relatively stable global mean temperatures. The 1976 divide is the date of a widely acknowledged 'climate shift' and seems to mark a time when global mean temperatures began a discernible upward trend that has been at least partly attributed to increases in greenhouse gas concentrations in the atmosphere. The picture prior to 1976 has essentially not changed and is therefore not repeated in detail here. However, it is more convenient to document the sub-period after 1979, rather than 1976, owing to the availability of increased and improved satellite data since then (in particular Television InfraRed Observation Satellite (TIROS) Operational Vertical Sounder (TOVS) data) in association with the Global Weather Experiment (GWE) of 1979. The post-1979 period allows, for the first time, a global perspective on many fields of variables, such as precipitation, that was not previously available. The availability of high-quality data has led to a focus on the post-1978 period, although physically this new regime seems to have begun in 1976

  19. Detection of CS in Neptune's atmosphere from ALMA observations

    Science.gov (United States)

    Moreno, R.; Lellouch, E.; Cavalié, T.; Moullet, A.

    2017-12-01

    Context. The large and vertically non-uniform abundance of CO in Neptune's atmosphere has been interpreted as the result of past cometary impact(s), either single or distributed in size and time, which could also be at the origin of Neptune's HCN. Aims: We aim to provide observational support for this scenario by searching for other comet-induced species, in particular carbon sulfide (CS) which has been observed continuously in Jupiter since the 1994 Shoemaker-Levy 9 impacts. Methods: In April 2016 we used the ALMA interferometer to search for CS(7-6) at 342.883 GHz in Neptune. Results: We report on the detection of CS in Neptune's atmosphere, the first unambiguous observation of a sulfur-bearing species in a giant planet beyond Jupiter. Carbon sulfide appears to be present only at submillibar levels, with a column density of (2.0-3.1) × 1012 cm-2, and a typical mixing ratio of (2-20) × 10-11 that depends on its precise vertical location. The favoured origin of CS is deposition by a putative large comet impact several centuries ago, and the strong depletion of CS with respect to CO - compared to the Jupiter case - is likely due to the CS sticking to aerosols or clustering to form polymers in Neptune's lower stratosphere. Conclusions: The CS detection, along with recent analyses of the CO profile, reinforces the presumption of a large comet impact into Neptune 1000 yr ago, that delivered CO, CS, and HCN at the same time.

  20. In situ observation of lithium hydride hydrolysis by DRIFT spectroscopy

    International Nuclear Information System (INIS)

    Awbery, Roy P.; Broughton, Duncan A.; Tsang, S.C.

    2008-01-01

    Polycrystalline LiH was studied in situ using diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy to investigate the effect water vapour has on the rate of production of the corrosion products, particularly LiOH. The reaction rate of the formation of surface LiOH was monitored by measurement of the hydroxyl (OH) band at 3676 cm -1 . The initial hydrolysis rate of LiH exposed to water vapour at 50% relative humidity was found to be almost two times faster than LiH exposed to water vapour at 2% relative humidity. The hydrolysis rate was shown to be initially very rapid followed by a much slower, almost linear rate. The change in hydrolysis rate was attributed to the formation of a coherent layer of LiOH on the LiH surface. Exposure to lower levels of water vapour appeared to result in the formation of a more coherent corrosion product, resulting in effective passivation of the surface to further attack from water

  1. Intercomparison of middle-atmospheric wind in observations and models

    Directory of Open Access Journals (Sweden)

    R. Rüfenacht

    2018-04-01

    Full Text Available Wind profile information throughout the entire upper stratosphere and lower mesosphere (USLM is important for the understanding of atmospheric dynamics but became available only recently, thanks to developments in remote sensing techniques and modelling approaches. However, as wind measurements from these altitudes are rare, such products have generally not yet been validated with (other observations. This paper presents the first long-term intercomparison of wind observations in the USLM by co-located microwave radiometer and lidar instruments at Andenes, Norway (69.3° N, 16.0° E. Good correspondence has been found at all altitudes for both horizontal wind components for nighttime as well as daylight conditions. Biases are mostly within the random errors and do not exceed 5–10 m s−1, which is less than 10 % of the typically encountered wind speeds. Moreover, comparisons of the observations with the major reanalyses and models covering this altitude range are shown, in particular with the recently released ERA5, ECMWF's first reanalysis to cover the whole USLM region. The agreement between models and observations is very good in general, but temporally limited occurrences of pronounced discrepancies (up to 40 m s−1 exist. In the article's Appendix the possibility of obtaining nighttime wind information about the mesopause region by means of microwave radiometry is investigated.

  2. Visualization in hydrological and atmospheric modeling and observation

    Science.gov (United States)

    Helbig, C.; Rink, K.; Kolditz, O.

    2013-12-01

    In recent years, visualization of geoscientific and climate data has become increasingly important due to challenges such as climate change, flood prediction or the development of water management schemes for arid and semi-arid regions. Models for simulations based on such data often have a large number of heterogeneous input data sets, ranging from remote sensing data and geometric information (such as GPS data) to sensor data from specific observations sites. Data integration using such information is not straightforward and a large number of potential problems may occur due to artifacts, inconsistencies between data sets or errors based on incorrectly calibrated or stained measurement devices. Algorithms to automatically detect various of such problems are often numerically expensive or difficult to parameterize. In contrast, combined visualization of various data sets is often a surprisingly efficient means for an expert to detect artifacts or inconsistencies as well as to discuss properties of the data. Therefore, the development of general visualization strategies for atmospheric or hydrological data will often support researchers during assessment and preprocessing of the data for model setup. When investigating specific phenomena, visualization is vital for assessing the progress of the ongoing simulation during runtime as well as evaluating the plausibility of the results. We propose a number of such strategies based on established visualization methods that - are applicable to a large range of different types of data sets, - are computationally inexpensive to allow application for time-dependent data - can be easily parameterized based on the specific focus of the research. Examples include the highlighting of certain aspects of complex data sets using, for example, an application-dependent parameterization of glyphs, iso-surfaces or streamlines. In addition, we employ basic rendering techniques allowing affine transformations, changes in opacity as well

  3. Estimating atmospheric visibility using synergy of MODIS data and ground-based observations

    Science.gov (United States)

    Komeilian, H.; Mohyeddin Bateni, S.; Xu, T.; Nielson, J.

    2015-05-01

    Dust events are intricate climatic processes, which can have adverse effects on human health, safety, and the environment. In this study, two data mining approaches, namely, back-propagation artificial neural network (BP ANN) and supporting vector regression (SVR), were used to estimate atmospheric visibility through the synergistic use of Moderate Resolution Imaging Spectroradiometer (MODIS) Level 1B (L1B) data and ground-based observations at fourteen stations in the province of Khuzestan (southwestern Iran), during 2009-2010. Reflectance and brightness temperature in different bands (from MODIS) along with in situ meteorological data were input to the models to estimate atmospheric visibility. The results show that both models can accurately estimate atmospheric visibility. The visibility estimates from the BP ANN network had a root-mean-square error (RMSE) and Pearson's correlation coefficient (R) of 0.67 and 0.69, respectively. The corresponding RMSE and R from the SVR model were 0.59 and 0.71, implying that the SVR approach outperforms the BP ANN.

  4. Observed atmospheric composition change during 1972-2009

    Energy Technology Data Exchange (ETDEWEB)

    T#Latin Small Letter O With Stroke#rseth, K.

    2012-07-01

    From the preface: The main objective of the European Monitoring and Evaluation Programme (EMEP) is to provide governments with information on the deposition and concentration of air pollutants, as well as the quantity and significance of the long-range transmission of air pollutants across boundaries. A network of stations undertakes observations of chemical and physical variables linked to damage to human health and the environment, in particular acidification, eutrophication, photochemical oxidants, heavy metals, persistent organic pollutants and particulate matter. The information provided by EMEP is also fundamental for improving the knowledge of climate change and to assess rural and urban air quality. Supplemented with emission inventories, modelling of atmospheric chemistry and deposition, and integrated assessment modelling, the work of EMEP form the basis for legally binding emission reduction protocols under the UNECE Convention on Long-range Transboundary Air Pollution (www.unece.org/env/lrtap).(Author)

  5. Mercury's Atmosphere and Magnetosphere: MESSENGER Third Flyby Observations

    Science.gov (United States)

    Slavin, James A.; Anderson, Brian J.; Baker, Daniel N.; Benna, Mehdi; Johnson, Catherine L.; Gloeckler, George; Killen, Rosemary M.; Krimigis, Stamatios M.; McClintock, William; McNutt, Ralph L., Jr.; hide

    2009-01-01

    MESSENGER's third flyby of Mercury en route to orbit insertion about the innermost planet took place on 29 September 2009. The earlier 14 January and 6 October 2008 encounters revealed that Mercury's magnetic field is highly dipolar and stable over the 35 years since its discovery by Mariner 10; that a structured, temporally variable exosphere extends to great altitudes on the dayside and forms a long tail in the anti-sunward direction; a cloud of planetary ions encompasses the magnetosphere from the dayside bow shock to the downstream magnetosheath and magnetotail; and that the magnetosphere undergoes extremely intense magnetic reconnect ion in response to variations in the interplanetary magnetic field. Here we report on new results derived from observations from MESSENGER's Mercury Atmospheric and Surface Composition Spectrometer (MASCS), Magnetometer (MAG), and Energetic Particle and Plasma Spectrometer (EPPS) taken during the third flyby.

  6. Near Real Time website for IASI observations of atmospheric anomalies

    Science.gov (United States)

    Hayer, Catherine; Grainger, Don; Marsh, Kevin; Carboni, Elisa; Ventress, Lucy; Smith, Andrew

    2014-05-01

    Rapid analysis of satellite observations of the state of the atmosphere and the contaminant levels within it can be used for pollution monitoring, forest fire detection and volcanic activity monitoring. There are numerous operational satellite instruments for which this is possible. The IASI instruments, currently flying on board the MetOp-A and MetOp-B satellite platforms, are used to produce Near Real Time (NRT) data using analysis algorithms developed by Oxford University. The data is then displayed on a website within 3 hours of measurement. This allows for the semi-continuous monitoring of the state of the atmosphere over most of the globe, both in daylight and at night. Global coverage is achieved 4 times per day, which is a significant advantage over most of the alternatives, either geostationary, giving limited spatial coverage, or UV instruments which are only able to observe during the daylight side of the orbit. The website includes flags for atmospheric contaminants detectable by IASI, including dust, biomass burning-derived species and volcanic ash and SO2. In the near future, the website will be developed to also include a quantitative estimate of the mass loading of SO2 contained within any volcanic cloud. Emissions of volcanic products, such as ash and SO2, are useful indicators of a change in the activity level of a volcano. Since many volcanoes are only monitored by remote sensing methods, such as satellite instruments, this can be the only such indicator available. These emissions are also dangerous to passing aircraft, causing damage to external surfaces of the plane and to the engines, sometimes leading to failure. Evacuation of regions surrounding volcanoes, and cessation or diversion of air traffic around actively erupting volcanoes is costly and highly disruptive but is sometimes required. Up to date information is of critical importance as to when to make these sensitive decisions. An archive of data will be available to allow for easy

  7. Towards soil property retrieval from space: Proof of concept using in situ observations

    Science.gov (United States)

    Bandara, Ranmalee; Walker, Jeffrey P.; Rüdiger, Christoph

    2014-05-01

    Soil moisture is a key variable that controls the exchange of water and energy fluxes between the land surface and the atmosphere. However, the temporal evolution of soil moisture is neither easy to measure nor monitor at large scales because of its high spatial variability. This is mainly a result of the local variation in soil properties and vegetation cover. Thus, land surface models are normally used to predict the evolution of soil moisture and yet, despite their importance, these models are based on low-resolution soil property information or typical values. Therefore, the availability of more accurate and detailed soil parameter data than are currently available is vital, if regional or global soil moisture predictions are to be made with the accuracy required for environmental applications. The proposed solution is to estimate the soil hydraulic properties via model calibration to remotely sensed soil moisture observation, with in situ observations used as a proxy in this proof of concept study. Consequently, the feasibility is assessed, and the level of accuracy that can be expected determined, for soil hydraulic property estimation of duplex soil profiles in a semi-arid environment using near-surface soil moisture observations under naturally occurring conditions. The retrieved soil hydraulic parameters were then assessed by their reliability to predict the root zone soil moisture using the Joint UK Land Environment Simulator model. When using parameters that were retrieved using soil moisture observations, the root zone soil moisture was predicted to within an accuracy of 0.04 m3/m3, which is an improvement of ∼0.025 m3/m3 on predictions that used published values or pedo-transfer functions.

  8. Precipitation Characteristics in Tropical Africa Using Satellite and In-Situ Observations

    Science.gov (United States)

    Dezfuli, Amin; Ichoku, Charles; Huffman, George; Mohr, Karen

    2017-01-01

    Tropical Africa receives nearly all its precipitation as a result of convection. The characteristics of rain-producing systems in this region, despite their crucial role in regional and global circulation, have not been well-understood. This is mainly due to the lack of in situ observations. Here, we have used precipitation records from the Trans-African Hydro-Meteorological Observatory (TAHMO) to improve our knowledge about the rainfall systems in the region, and to validate the recently-released IMERG precipitation product. The high temporal resolution of the gauge data has allowed us to identify three classes of rain events based on their duration and intensity. The contribution of each class to the total rainfall and the favorable surface atmospheric conditions for each class have been examined. As IMERG aims to continue the legacy of its predecessor, TMPA, and provide higher resolution data, continent-wide comparisons are made between these two products. IMERG, due to its improved temporal resolution, shows some advantages over TMPA in capturing the diurnal cycle and propagation of the meso-scale convective systems. However, the performance of the two satellite-based products varies by season, region and the evaluation statistics. The results of this study serve as a basis for our ongoing work on the impacts of biomass burning on precipitation processes in Africa.

  9. Mars MetNet Mission - Martian Atmospheric Observational Post Network

    Science.gov (United States)

    Hari, Ari-Matti; Haukka, Harri; Aleksashkin, Sergey; Arruego, Ignacio; Schmidt, Walter; Genzer, Maria; Vazquez, Luis; Siikonen, Timo; Palin, Matti

    2017-04-01

    accelerometer combined with a 3-axis gyrometer. The data will be sent via auxiliary beacon antenna throughout the descent phase starting shortly after separation from the spacecraft. MetNet Mission payload instruments are specially designed to operate under very low power conditions. MNL flexible solar panels provides a total of approximately 0.7-0.8 W of electric power during the daylight time. As the provided power output is insufficient to operate all instruments simultaneously they are activated sequentially according to a specially designed cyclogram table which adapts itself to the different environmental constraints. 3. Mission Status he eventual goal is to create a network of atmospheric observational posts around the Martian surface. Even if the MetNet mission is focused on the atmospheric science, the mission payload will also include additional kinds of geophysical instrumentation. The next step is the MetNet Precursor Mission that will demonstrate the technical robustness and scientific capabilities of the MetNet type of landing vehicle. Definition of the Precursor Mission and discussions on launch opportunities are currently under way. The first MetNet Science Payload Precursors have already been successfully completed, e,g, the REMS/MSL and DREAMS/Exomars-2016. The next MetNet Payload Precursors will be METEO/Exomars-2018 and MEDA/Mars-2020. The baseline program development funding exists for the next seven years. Flight unit manufacture of the payload bay takes about 18 months, and it will be commenced after the Precursor Mission has been defined. References [1] http://metnet.fmi.fi

  10. In situ TEM observation of the growth and decomposition of monoclinic W18O49 nanowires

    International Nuclear Information System (INIS)

    Chen, C L; Mori, H

    2009-01-01

    The growth of monoclinic W 18 O 49 nanowires by heat treatment of a tungsten filament at ∼873 K and the decomposition of these nanowires under 200 keV electron irradiation at ∼1023 K have been investigated using in situ transmission electron microscopy (TEM). In situ TEM observation of the growth confirmed the vapor-solid growth mechanism of the monoclinic W 18 O 49 nanowires. In situ irradiation experiments revealed the formation of metallic bcc tungsten from monoclinic W 18 O 49 nanowires under 200 keV electron irradiation.

  11. In Situ Atmospheric Pressure Measurements in the Martian Southern Polar Region: Mars Volatiles and Climate Surveyor Meteorology Package on the Mars Polar Lander

    Science.gov (United States)

    Harri, A.-M.; Polkko, J.; Siili, T.; Crisp, D.

    1998-01-01

    Pressure observations are crucial for the success of the Mars Volatiles and Climate Surveyor (MVACS) Meteorology (MET) package onboard the Mars Polar Lander (MPL), due for launch early next year. The spacecraft is expected to land in December 1999 (L(sub s) = 256 degrees) at a high southern latitude (74 degrees - 78 degrees S). The nominal period of operation is 90 sols but may last up to 210 sols. The MVACS/MET experiment will provide the first in situ observations of atmospheric pressure, temperature, wind, and humidity in the southern hemisphere of Mars and in the polar regions. The martian atmosphere goes through a large-scale atmospheric pressure cycle due to the annual condensation/sublimation of the atmospheric CO2. Pressure also exhibits short period variations associated with dust storms, tides, and other atmospheric events. A series of pressure measurements can hence provide us with information on the large-scale state and dynamics of the atmosphere, including the CO2 and dust cycles as well as local weather phenomena. The measurements can also shed light on the shorter time scale phenomena (e.g., passage of dust devils) and hence be important in contributing to our understanding of mixing and transport of heat, dust, and water vapor.

  12. Land-Surface-Atmosphere Coupling in Observations and Models

    Directory of Open Access Journals (Sweden)

    Alan K Betts

    2009-07-01

    Full Text Available The diurnal cycle and the daily mean at the land-surface result from the coupling of many physical processes. The framework of this review is largely conceptual; looking for relationships and information in the coupling of processes in models and observations. Starting from the surface energy balance, the role of the surface and cloud albedos in the shortwave and longwave fluxes is discussed. A long-wave radiative scaling of the diurnal temperature range and the night-time boundary layer is summarized. Several aspects of the local surface energy partition are presented: the role of soilwater availability and clouds; vector methods for understanding mixed layer evolution, and the coupling between surface and boundary layer that determines the lifting condensation level. Moving to larger scales, evaporation-precipitation feedback in models is discussed; and the coupling of column water vapor, clouds and precipitation to vertical motion and moisture convergence over the Amazon. The final topic is a comparison of the ratio of surface shortwave cloud forcing to the diabatic precipitation forcing of the atmosphere in ERA-40 with observations.

  13. The Small Unmanned Meteorological Observer SUMO. A new tool for atmospheric boundary layer research

    Energy Technology Data Exchange (ETDEWEB)

    Reuder, Joachim; Jonassen, Marius; Mayer, Stephanie [Bergen Univ. (Norway). Geophysical Inst.; Brisset, Pascal [Ecole Nationale de l' Aviation Civile (ENAC), Toulouse (France); Mueller, Martin [Martin Mueller Engineering, Hildesheim (Germany)

    2009-04-15

    The Small Unmanned Meteorological Observer SUMO has been developed as a cost-efficient measurement system with the aim to close the existing observational gap of atmospheric measurement systems in between meteorological masts/towers and radiosondes. The system is highly flexible and has the capability for in-situ ABL measurements with unique spatial and temporal resolution. SUMO is based on a light-weighted styrofoam model airplane, equipped with an autopilot system for autonomous flight missions and in its recent version with meteorological sensors for temperature, humidity and pressure. With its wingspan of 80 cm, its length of 75 cm and a total lift-off weight of 580 g, SUMO is easy to transport and operate even in remote areas with limited infrastructure. During several field campaigns in 2007 and 2008 the system has been successfully tested and operated. Atmospheric profiles of temperature, humidity, wind speed and wind direction have been determined up to 3500 m above ground during the FLOHOF (FLOw over and around HOFsjoekull) field campaign in Central Iceland in July/August 2007. During a 3 week campaign on and around Spitsbergen in February/March 2008 the SUMO system also proved its functionality under polar conditions, reaching altitudes above 1500 m even at ground temperatures of -20 C and wind speeds up to 15 m s{sup -1}. (orig.)

  14. Assessing Greenhouse Gas emissions in the Greater Toronto Area using atmospheric observations (Invited)

    Science.gov (United States)

    Vogel, F. R.; Chan, E.; Huang, L.; Levin, I.; Worthy, D.

    2013-12-01

    Urban areas are said to be responsible for approximately 75% of anthropogenic Greenhouse Gases (GHGs) emissions while comprising only two percent of the land area [1]. This limited spatial expansion should facilitate a monitoring of anthropogenic GHGs from atmospheric observations. As major sources of emissions, cities also have a huge potential to drive emissions reductions. To effectively manage emissions, cities must however, first measure and report these publicly [2]. Modelling studies and measurements of CO2 from fossil fuel burning (FFCO2) in densely populated areas does, however, pose several challenges: Besides continuous in-situ observations, i.e. finding an adequate atmospheric transport model, a sufficiently fine-grained FFCO2 emission model and the proper background reference observations to distinguish the large-scale from the local/urban contributions to the observed FFCO2 concentration offsets ( ΔFFCO2) are required. Pilot studies which include the data from two 'sister sites*' in the vicinity of Toronto, Canada helped to derive flux estimates for Non-CO2 GHGs [3] and improve our understanding of urban FFCO2 emissions. Our 13CO2 observations reveal that the contribution of natural gas burning (mostly due to domestic heating) account for 80%×7% of FFCO2 emissions in the Greater Toronto Area (GTA) during winter. Our 14CO2 observations in the GTA, furthermore, show that the local offset of CO2 (ΔCO2) between our two sister sites can be largely attributed to urban FFCO2 emissions. The seasonal cycle of the observed ΔFFCO2 in Toronto, combined with high-resolution atmospheric modeling, helps to independently assess the contribution from different emission sectors (transportation, primary energy and industry, domestic heating) as predicted by a dedicated city-scale emission inventory, which deviates from a UNFCCC-based inventory. [1] D. Dodman. 2009. Blaming cities for climate change? An analysis of urban greenhouse gas emissions inventories

  15. In-Situ Observation of Sintering Shrinkage of UO{sub 2} Compacts Derived from Different Powder Routes

    Energy Technology Data Exchange (ETDEWEB)

    Rhee, Young Woo; Oh, Jang Soo; Kim, Dong Joo; Kim, Keon Sik; Kim, Jong Hun; Yang, Jae Ho; Koo, Yang Hyun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2015-10-15

    In-situ observations on the shrinkage of green pellets with precisely controlled dimensions were carefully conducted by using TOM during H2 atmosphere sintering. The shrinkage retardation in IDR-UO{sub 2} might be attributed to the larger primary particle size of IDRUO{sub 2} than those of ADU- and AUC- UO{sub 2} powders. It would be important to understand the different sintering characteristics of UO{sub 2} powders according to the powder routes, when it comes to designing a new sintering process or choosing a sintering additive for new fuel pellet like PCI (Pellet Cladding Interaction) remedy pellet. In this paper, we have investigated the initial and intermediate sintering shrinkage of UO{sub 2} from different powder routes by in-situ observation of green samples during H2 atmosphere sintering. Effect of powder characteristics of three different UO{sub 2} powders on the initial and intermediate sintering were closely reviewed including crystal structure, powder size, specific surface area, primary crystal size, and O/U ratio.

  16. Expectations for Particulate Contamination Relevant to in Situ Atmospheric Sampling for Compositional Analysis at Uranus

    Science.gov (United States)

    Wong, M. H.

    2017-12-01

    NASA and ESA are considering options for in situ science with atmospheric entry probes to the ice giants Uranus and Neptune. Nominal probe entry mass is in the 300-kg range, although a miniaturized secondary probe option is being studied in the 30-kg range. In all cases, compositional sampling would commence near the 100-mbar level at Uranus, after ejection of the heat shield and deployment of the descent parachute. In this presentation, I review existing literature on the composition, mass loading, and vertical distribution of condensed material that the probe may encounter. Sample inlets for measurement of the gas composition should be heated to avoid potential buildup of condensate, which would block the flow of atmospheric gas into composition sensors. Heating rate and temperature values -- sufficient to keep sample inlets clean under various assumptions -- will be presented. Three main types of condensed material will be considered: Stratospheric hydrocarbon ices: Solar UV photolyzes CH4, leading to the production of volatile hydrocarbons with higher C/H ratios. These species diffuse from their production regions into colder levels where the ices of C2H2, C2H6, and C4H2 condense. Some studies have also considered condensation of C3H8, C4H10, C6H6, and C6H2. Gunk: The hydrocarbon ices are thought to become polymerized due to irradiation from solar UV. The exact composition of the resulting gunk is not known. Solid-state photochemical processing may produce the traces of reddish (blue-absorbing) haze material, present in the troposphere at temperatures warm enough to sublimate the simple hydrocarbon ices. Tropospheric ices: In the region accessible to probes under study (P < 10 bar), much thicker condensation clouds may form from volatile gases CH4, NH3, and H2S. If large amounts of NH3 are sequestered in the deeper H2O liquid cloud, then the S/N ratio could exceed 1 in the probe-accessible region of the atmosphere, leading to NH4SH and H2S ices below the CH4

  17. LOCAL AIR: Local Aerosol monitoring combining in-situ and Remote Sensing observations

    Science.gov (United States)

    Mona, Lucia; Caggiano, Rosa; Donvito, Angelo; Giannini, Vincenzo; Papagiannopoulos, Nikolaos; Sarli, Valentina; Trippetta, Serena

    2015-04-01

    The atmospheric aerosols have effects on climate, environment and health. Although the importance of the study of aerosols is well recognized, the current knowledge of the characteristics and their distribution is still insufficient, and there are large uncertainties in the current understanding of the role of aerosols on climate and the environment, both on a regional and local level. Overcoming these uncertainties requires a search strategy that integrates data from multiple platforms (eg, terrestrial, satellite, ships and planes) and the different acquisition techniques (for example, in situ measurements, remote sensing, modeling numerical and data assimilation) (Yu et al., 2006). To this end, in recent years, there have been many efforts such as the creation of networks dedicated to systematic observation of aerosols (eg, European Monitoring and Evaluation Programme-EMEP, European Aerosol Research Lidar NETwork-EARLINET, MicroPulse Lidar Network- MPLNET, and Aerosol Robotic NETwork-AERONET), the development and implementation of new satellite sensors and improvement of numerical models. The recent availability of numerous data to the ground, columnar and profiles of aerosols allows to investigate these aspects. An integrated approach between these different techniques could be able to provide additional information, providing greater insight into the properties of aerosols and their distribution and overcoming the limits of each single technique. In fact, the ground measurements allow direct determination of the physico-chemical properties of aerosols, but cannot be considered representative for large spatial and temporal scales and do not provide any information about the vertical profile of aerosols. On the other hand, the remote sensing techniques from the ground and satellite provide information on the vertical distribution of atmospheric aerosols both in the Planetary Boundary Layer (PBL), mainly characterized by the presence of aerosols originating from

  18. Global and regional emissions estimates of 1,1-difluoroethane (HFC-152a, CH[subscript 3]CHF[subscript 2]) from in situ and air archive observations

    OpenAIRE

    Prinn, Ronald G.

    2015-01-01

    High frequency, in situ observations from 11 globally distributed sites for the period 1994–2014 and archived air measurements dating from 1978 onward have been used to determine the global growth rate of 1,1-difluoroethane (HFC-152a, CH[subscript 3]CHF[subscript 2]). These observations have been combined with a range of atmospheric transport models to derive global emission estimates in a top-down approach. HFC-152a is a greenhouse gas with a short atmospheric lifetime of about 1.5 years. Si...

  19. Atmospheric Variability of CO2 impact on space observation Requirements

    Science.gov (United States)

    Swanson, A. L.; Sen, B.; Newhart, L.; Segal, G.

    2009-12-01

    If International governments are to reduce GHG levels by 80% by 2050, as recommended by most scientific bodies concerned with avoiding the most hazardous changes in climate, then massive investments in infrastructure and new technology will be required over the coming decades. Such an investment will be a huge commitment by governments and corporations, and while it will offer long-term dividends in lower energy costs, a healthier environment and averted additional global warming, the shear magnitude of upfront costs will drive a call for a monitoring and verification system. Such a system will be required to offer accountability to signatories of governing bodies, as well as, for the global public. Measuring the average global distribution of CO2 is straight forward, as exemplified by the long running station measurements managed by NOAA’s Global Monitoring Division that includes the longterm Keeling record. However, quantifying anthropogenic and natural source/sink distributions and atmospheric mixing have been much more difficult to constrain. And, yet, an accurate accounting of all anthropogenic source strengths is required for Global Treaty verification. The only way to accurately assess Global GHG emissions is to construct an integrated system of ground, air and space based observations with extensive chemical modeling capabilities. We look at the measurement requirements for the space based component of the solutions. To determine what space sensor performance requirements for ground resolution, coverage, and revisit, we have analyzed regional CO2 distributions and variability using NASA and NOAA aircraft flight campaigns. The results of our analysis are presented as variograms showing average spatial variability over several Northern Hemispheric regions. There are distinct regional differences with the starkest contrast between urban versus rural and Coastal Asia versus Coastal US. The results suggest specific consequences on what spatial and temporal

  20. 200 and 270 GHz SIS receivers development for atmospheric observation

    International Nuclear Information System (INIS)

    Ochiai, S.; Masuko, H.

    1993-01-01

    Superconducting mixers have been developed for observations of atmospheric minor constituents such as ClO and ozone at Communications Research Laboratory. This paper describes the work at development of 200 and 270 GHz SIS mixers. Nb/AlOx/Nb junctions were fabricated at Nobeyama Radio Observatory. The base Nb layer 200 nm, the Al (AlOx) insulation layer, and the counter Nb electrode 150 nm are sputtered. The area outside of a junction defined by etching of the counter electrode is insulated by anodized Nb layer and sputtered SiO 2 . After sputtering thick SiO 2 layer on the whole wafer, a contact hole is made by etching. The thickness of the wiring Nb layer is 500 nm. The junctions are formed on the 250 μm thick fused quartz substrate. After the process of the junction fabrication, the quartz substrate is shaved from the back side until 150 μm thickness. Each junction for 270 GHz mixer has an area of about 1 μm 2 . The normal resistance of the six junctions series array is around 70 Ω. The mixer block has a reduced waveguide (1.2 x 0.1 mm for 200 GHz and 0.98 x 0. 1 mm for 270 GHz). The waveguide has two tuners in addition to a fixed backshort cavity. This configuration can allow to realize the lower embedding impedance, and less sensitive to the position of the tuners. The SIS mixers are cooled in a closed cycle He refrigerator. The LO is optically injected through a Fabry Perot interferometer. The 5--7 GHz IF is fed to a HEMT amplifier cooled at 15 K. The authors have started a preliminary measurement of the noise temperature of the SIS receivers, and comparing with calculated DSB receiver noise temperature assuming 3-port model. They continue to improve the performance of the SIS mixers now. They intend that the receivers shall be utilized for atmospheric monitor from next winter

  1. Estimation of Regional Carbon Balance from Atmospheric Observations

    Science.gov (United States)

    Denning, S.; Uliasz, M.; Skidmore, J.

    2002-12-01

    Variations in the concentration of CO2 and other trace gases in time and space contain information about sources and sinks at regional scales. Several methods have been developed to quantitatively extract this information from atmospheric measurements. Mass-balance techniques depend on the ability to repeatedly sample the same mass of air, which involves careful attention to airmass trajectories. Inverse and adjoint techniques rely on decomposition of the source field into quasi-independent "basis functions" that are propagated through transport models and then used to synthesize optimal linear combinations that best match observations. A recently proposed method for regional flux estimation from continuous measurements at tall towers relies on time-mean vertical gradients, and requires careful trajectory analysis to map the estimates onto regional ecosystems. Each of these techniques is likely to be applied to measurements made during the North American Carbon Program. We have also explored the use of Bayesian synthesis inversion at regional scales, using a Lagrangian particle dispersion model driven by mesoscale transport fields. Influence functions were calculated for each hypothetical observation in a realistic diurnally-varying flow. These influence functions were then treated as basis functions for the purpose of separate inversions for daytime photosynthesis and 24-hour mean ecosystem respiration. Our results highlight the importance of estimating CO2 fluxes through the lateral boundaries of the model. Respiration fluxes were well constrained by one or two hypothetical towers, regardless of inflow fluxes. Time-varying assimilation fluxes were less well constrained, and much more dependent on knowledge of inflow fluxes. The small net difference between respiration and photosynthesis was the most difficult to determine, being extremely sensitive to knowledge of inflow fluxes. Finally, we explored the feasibility of directly incorporating mid-day concentration

  2. Southeast Atmosphere Studies: learning from model-observation syntheses

    Science.gov (United States)

    Concentrations of atmospheric trace species in the United States have changed dramatically over the past several decades in response to pollution control strategies, shifts in domestic energy policy and economics, and economic development (and resulting emission changes) elsewher...

  3. Atmospheric correction of Earth-observation remote sensing images ...

    Indian Academy of Sciences (India)

    The physics underlying the problem of solar radiation propagations that takes into account ... SART code (Spherical Atmosphere Radiation. Transfer) ... The use of Monte Carlo sampling ..... length because this soil is formed by clay and sand.

  4. Curiosity and the Four Seasons: In Situ Measurements of the Atmospheric Composition over Three Mars Years

    Science.gov (United States)

    Trainer, M. G.; Franz, H. B.; Mahaffy, P. R.; Malespin, C.; Wong, M. H.; Atreya, S. K.; Becker, R. H.; Conrad, P. G.; Lefèvre, F.; Manning, H. L. K.; Martin-Torres, F. J.; McConnochie, T.; McKay, C.; Navarro-Gonzalez, R.; Pepin, R. O.; Webster, C. R.; Zorzano, M. P.

    2017-12-01

    The Sample Analysis at Mars (SAM) instrument onboard the Mars Science Laboratory Curiosity rover measures the chemical composition of major atmospheric species in the vicinity of the rover through a dedicated atmospheric inlet. We report here on measurements of atmospheric volume mixing ratios in Gale Crater using the SAM quadrupole mass spectrometer (QMS), over a period of nearly three Mars years (5 Earth years) from landing. The observation period spans the southern winter of MY 31, solar longitude (Ls) of 175° through southern fall of MY 34, Ls = 12°. The initial mixing ratios measured by the SAM QMS were reported for the first 105 sols of the mission [1], and were updated to account for newly developed calibration factors [2]. The SAM QMS atmospheric measurements were continued, periodically interspersed between solid sample measurements and other rover activities, with a cumulative coverage of 4 or 5 experiments per season. The three major volatiles - CO2, N2, and 40Ar - are compatible with the annual pressure cycle but with a repeatable lag that indicates incomplete mixing and the influences of seasonal circulation patterns. The mixing ratios for the two inert, non-condensable species are qualitatively consistent with what is predicted from annual cycle of CO2 deposition and sublimation at the poles, which is manifested in a large enhancement of Ar mixing ratio at the winter poles (and assumed for N2) [3]. The mixing ratio for the minor species O2 appears to follow a distinct seasonal trend and may be indicative of possible deviations from known atmospheric chemistry or a surface flux of oxygen from an unknown source, or both. This unprecedented seasonal coverage and precision in mixing ratio determination provides valuable data for understanding the seasonal chemical and dynamics cycles. Further, this measurement campaign supplies useful ground-truth data for global climate model simulations, which can study atmospheric effects for other locations on Mars

  5. [Data processing and QA/QC of atmosphere CO2 and CH4 concentrations by a method of GC-FID in-situ measurement at Waliguan station].

    Science.gov (United States)

    Zhang, Fang; Zhou, Ling-Xi; Liu, Li-Xin; Fang, Shuang-Xi; Yao, Bo; Xu, Lin; Zhang, Xiao-Chun; Masarie, Kenneth A; Conway, Thomas J; Worthy, Douglas E J; Ernst, Michele

    2010-10-01

    To strengthen scientific management and sharing of greenhouse gas data obtained from atmospheric background stations in China, it is important to ensure the standardization of observations and establish the data treatment and quality control procedure so as to maintain consistency in atmospheric carbon dioxide (CO2) and methane (CH4) measurements from different background stations. An automated gas chromatographic system (Hewlett Packard 5890GC employing flame ionization detection) for in situ measurements of atmospheric CO2 and CH4 has been developed since 1994 at the China Global Atmosphere Watch Baseline Observatory at Mt. Waliguan, in Qinhai. In this study, processing and quality control flow of CO2 and CH4 data acquired by HP ChemStation are discussed in detail, including raw data acquisition, data merge, time series inspection, operator flag, principal investigator flag, and the comparison of the GC measurement with the flask method. Atmosphere CO2 and CH4 mixing ratios were separated as background and non-background data using a robust local regression method, approximately 72% and 44% observed values had been filtered as background data for CO2 and CH4, respectively. Comparison of the CO1 and CH, in situ data to the flask sampling data were in good agreement, the relative deviations are within +/- 0.5% for CO2 and for CH4. The data has been assimilated into global database (Globalview-CO2, Globalview-CH4), submitted to the World Data Centre for Greenhouse Gases (WDCGG), and applied to World Meteorological Organization (WMO) Greenhouse Gas Bulletin and assessment reports of the United Nations Intergovernmental Panel on Climate Change (IPCC).

  6. Blending Satellite Observed, Model Simulated, and in Situ Measured Soil Moisture over Tibetan Plateau

    Directory of Open Access Journals (Sweden)

    Yijian Zeng

    2016-03-01

    Full Text Available The inter-comparison of different soil moisture (SM products over the Tibetan Plateau (TP reveals the inconsistency among different SM products, when compared to in situ measurement. It highlights the need to constrain the model simulated SM with the in situ measured data climatology. In this study, the in situ soil moisture networks, combined with the classification of climate zones over the TP, were used to produce the in situ measured SM climatology at the plateau scale. The generated TP scale in situ SM climatology was then used to scale the model-simulated SM data, which was subsequently used to scale the SM satellite observations. The climatology-scaled satellite and model-simulated SM were then blended objectively, by applying the triple collocation and least squares method. The final blended SM can replicate the SM dynamics across different climatic zones, from sub-humid regions to semi-arid and arid regions over the TP. This demonstrates the need to constrain the model-simulated SM estimates with the in situ measurements before their further applications in scaling climatology of SM satellite products.

  7. Deriving an atmospheric budget of total organic bromine using airborne in-situ measurements from the Western Pacific during SHIVA

    Science.gov (United States)

    Sala, S.; Bönisch, H.; Keber, T.; Oram, D. E.; Mills, G.; Engel, A.

    2014-02-01

    During the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere) project an extensive dataset of all halogen species relevant for the atmospheric budget of total organic bromine has been collected in the West Pacific region using the FALCON aircraft operated by the German Aerospace agency DLR (Deutsches Zentrum für Luft- und Raumfahrt) covering a vertical range from the planetary boundary layer up to the ceiling altitude of the aircraft of 13 km. In total, more than 700 measurements were performed with the newly developed fully-automated in-situ instrument GHOST-MS (Gas cHromatograph for the Observation of Tracers - coupled with a Mass Spectrometer) by the Goethe University of Frankfurt (GUF) and with the onboard whole-air sampler WASP with subsequent ground based state-of-the-art GC/MS analysis by the University of East Anglia (UEA). Both instruments yield good agreement for all major (CHBr3 and CH2Br2) and minor (CHBrCl, CHBrCl2 and CHBr2Cl) VSLS (very short-lived substances), at least at the level of their 2 σ measurement uncertainties. In contrast to the suggestion that the Western Pacific could be a major source region for VSLS (Pyle et al., 2011), we found only slightly enhanced mixing ratios of brominated halogen source gases relative to the levels reported in Montzka et al. (2011) for other tropical regions. A budget for total organic bromine, including all four halons,CH3Br and the VSLS, is derived for the upper troposphere, the input region for the TTL and thus also for the stratosphere, compiled from the SHIVA dataset. With exception of the two minor VSLS CHBrCl2 and CHBr2Cl, excellent agreement with the values reported in Montzka et al. (2011) is found, while being slightly higher than previous studies from our group based on balloon-borne measurements.

  8. Deriving an atmospheric budget of total organic bromine using airborne in situ measurements from the western Pacific area during SHIVA

    Science.gov (United States)

    Sala, S.; Bönisch, H.; Keber, T.; Oram, D. E.; Mills, G.; Engel, A.

    2014-07-01

    During the recent SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere) project an extensive data set of all halogen species relevant for the atmospheric budget of total organic bromine was collected in the western Pacific region using the Falcon aircraft operated by the German Aerospace agency DLR (Deutsches Zentrum für Luft- und Raumfahrt) covering a vertical range from the planetary boundary layer up to the ceiling altitude of the aircraft of 13 km. In total, more than 700 measurements were performed with the newly developed fully automated in situ instrument GHOST-MS (Gas chromatograph for the Observation of Tracers - coupled with a Mass Spectrometer) by the Goethe University of Frankfurt (GUF) and with the onboard whole-air sampler WASP with subsequent ground-based state-of-the-art GC / MS analysis by the University of East Anglia (UEA). Both instruments yield good agreement for all major (CHBr3 and CH2Br2) and minor (CH2BrCl, CHBrCl2 and CHBr2Cl) VSLS (very short-lived substances), at least at the level of their 2σ measurement uncertainties. In contrast to the suggestion that the western Pacific could be a region of strongly increased atmospheric VSLS abundance (Pyle et al., 2011), we found only in the upper troposphere a slightly enhanced amount of total organic bromine from VSLS relative to the levels reported in Montzka and Reimann et al. (2011) for other tropical regions. From the SHIVA observations in the upper troposphere, a budget for total organic bromine, including four halons (H-1301, H-1211, H-1202, H-2402), CH3Br and the VSLS, is derived for the level of zero radiative heating (LZRH), the input region for the tropical tropopause layer (TTL) and thus also for the stratosphere. With the exception of the two minor VSLS CHBrCl2 and CHBr2Cl, excellent agreement with the values reported in Montzka and Reimann et al. (2011) is found, while being slightly higher than previous studies from our group based on balloon-borne measurements.

  9. Coupled atmosphere and land-surface assimilation of surface observations with a single column model and ensemble data assimilation

    Science.gov (United States)

    Rostkier-Edelstein, Dorita; Hacker, Joshua P.; Snyder, Chris

    2014-05-01

    Numerical weather prediction and data assimilation models are composed of coupled atmosphere and land-surface (LS) components. If possible, the assimilation procedure should be coupled so that observed information in one module is used to correct fields in the coupled module. There have been some attempts in this direction using optimal interpolation, nudging and 2/3DVAR data assimilation techniques. Aside from satellite remote sensed observations, reference height in-situ observations of temperature and moisture have been used in these studies. Among other problems, difficulties in coupled atmosphere and LS assimilation arise as a result of the different time scales characteristic of each component and the unsteady correlation between these components under varying flow conditions. Ensemble data-assimilation techniques rely on flow dependent observations-model covariances. Provided that correlations and covariances between land and atmosphere can be adequately simulated and sampled, ensemble data assimilation should enable appropriate assimilation of observations simultaneously into the atmospheric and LS states. Our aim is to explore assimilation of reference height in-situ temperature and moisture observations into the coupled atmosphere-LS modules(simultaneously) in NCAR's WRF-ARW model using the NCAR's DART ensemble data-assimilation system. Observing system simulation experiments (OSSEs) are performed using the single column model (SCM) version of WRF. Numerical experiments during a warm season are centered on an atmospheric and soil column in the South Great Plains. Synthetic observations are derived from "truth" WRF-SCM runs for a given date,initialized and forced using North American Regional Reanalyses (NARR). WRF-SCM atmospheric and LS ensembles are created by mixing the atmospheric and soil NARR profile centered on a given date with that from another day (randomly chosen from the same season) with weights drawn from a logit-normal distribution. Three

  10. In-situ observation of equilibrium transitions in Ni films; agglomeration and impurity effects

    Energy Technology Data Exchange (ETDEWEB)

    Thron, Andrew M., E-mail: AMThron@lbl.gov [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States); Greene, Peter; Liu, Kai [Department of Physics, University of California, Davis, CA 95616 (United States); Benthem, Klaus van [Department of Chemical Engineering and Materials Science, University of California, Davis, CA 95616 (United States)

    2014-02-01

    Dewetting of ultra-thin Ni films deposited on SiO{sub 2} layers was observed, in cross-section, by in situ scanning transmission electron microscopy. Holes were observed to nucleate by voids which formed at the Ni/SiO{sub 2} interface rather than at triple junctions at the free surface of the Ni film. Ni islands were observed to retract, in attempt to reach equilibrium on the SiO{sub 2} layer. SiO{sub 2} layers with 120 nm thickness were found to limit in situ heating experiments due to poor thermal conductivity of SiO{sub 2}. The formation of graphite was observed during the agglomeration of ultra-thin Ni films. Graphite was observed to wet both the free surface and the Ni/SiO{sub 2} interface of the Ni islands. Cr forms surface oxide layers on the free surface of the SiO{sub 2} layer and the Ni islands. Cr does not prevent the dewetting of Ni, however it will likely alter the equilibrium shape of the Ni islands. - Highlights: • In Situ observation of dewetting in ultra-thin Ni films sputtered on SiO{sub 2} layers. • Dewetting is observed in an edge-on position by in situ STEM. • Characterization of interface structure pre and post in situ annealing by STEM and EELS. • Analyze the effects of Cr{sub 1−x}O{sub x} and graphite impurities on the Ni film agglomeration. • Examine influence of the SiO{sub 2} layers on the dewetting process.

  11. First observations of tropospheric δD data observed by ground- and space-based remote sensing and surface in-situ measurement techniques at MUSICA's principle reference station (Izaña Observatory, Spain)

    Science.gov (United States)

    González, Yenny; Schneider, Matthias; Christner, Emanuel; Rodríguez, Omaira E.; Sepúlveda, Eliezer; Dyroff, Christoph; Wiegele, Andreas

    2013-04-01

    The main goal of the project MUSICA (Multiplatform remote Sensing of Isotopologues for investigating the Cycle of Atmospheric water) is the generation of a quasi global tropospheric water vapor isototopologue dataset of a good and well-documented quality. Therefore, new ground- and space-based remote sensing observations (NDACC-FTIR and IASI/METOP) are combined with in-situ measurements. This work presents the first comparison between in-situ and remote sensing observations made at the Izaña Atmospheric Research Centre (Tenerife, Canary Islands, Spain). The in-situ measurements are made by a Picarro L2120-i water vapor isotopologue analyzer. At Izaña the in-situ data are affected by local small-scale mixing processes: during daylight, the thermally buoyant upslope flow prompts the mixing between the Marine Boundary Layer (MBL) and the low Free Troposphere (FT). However, the remote sensors detect δD values averaged over altitudes that are more representative for the free troposphere. This difference has to be considered for the comparison. In general, a good agreement between the MUSICA remote sensing and the in situ H2O-versus-δD plots is found, which demonstrates that the MUSICA δD remote sensing products add scientifically valuable information to the H2O data.

  12. Direct observations of the atmospheric processing of Asian mineral dust

    Directory of Open Access Journals (Sweden)

    R. C. Sullivan

    2007-01-01

    Full Text Available The accumulation of secondary acids and ammonium on individual mineral dust particles during ACE-Asia has been measured with an online single-particle mass spectrometer, the ATOFMS. Changes in the amounts of sulphate, nitrate, and chloride mixed with dust particles correlate with air masses from different source regions. The uptake of secondary acids depended on the individual dust particle mineralogy; high amounts of nitrate accumulated on calcium-rich dust while high amounts of sulphate accumulated on aluminosilicate-rich dust. Oxidation of S(IV to S(VI by iron in the aluminosilicate dust is a possible explanation for this enrichment of sulphate, which has important consequences for the fertilization of remote oceans by soluble iron. This study shows the segregation of sulphate from nitrate and chloride in individual aged dust particles for the first time. A transport and aging timeline provides an explanation for the observed segregation. Our data suggests that sulphate became mixed with the dust first. This implies that the transport pathway is more important than the reaction kinetics in determining which species accumulate on mineral dust. Early in the study, dust particles in volcanically influenced air masses were mixed predominately with sulphate. Dust mixed with chloride then dominated over sulphate and nitrate when a major dust front reached the R. V. Ronald Brown. We hypothesize that the rapid increase in chloride on dust was due to mixing with HCl(g released from acidified sea salt particles induced by heterogeneous reaction with volcanic SO2(g, prior to the arrival of the dust front. The amount of ammonium mixed with dust correlated strongly with the total amount of secondary acid reaction products in the dust. Submicron dust and ammonium sulphate were internally mixed, contrary to frequent reports that they exist as external mixtures. The size distribution of the mixing state of dust with these secondary species validates previous

  13. An Inversion Analysis of Recent Variability in Natural CO2 Fluxes Using GOSAT and In Situ Observations

    Science.gov (United States)

    Wang, James S.; Kawa, S. Randolph; Collatz, G. James; Baker, David F.; Ott, Lesley

    2015-01-01

    About one-half of the global CO2 emissions from fossil fuel combustion and deforestation accumulates in the atmosphere, where it contributes to global warming. The rest is taken up by vegetation and the ocean. The precise contribution of the two sinks, and their location and year-to-year variability are, however, not well understood. We use two different approaches, batch Bayesian synthesis inversion and variational data assimilation, to deduce the global spatiotemporal distributions of CO2 fluxes during 2009-2010. One of our objectives is to assess different sources of uncertainties in inferred fluxes, including uncertainties in prior flux estimates and observations, and differences in inversion techniques. For prior constraints, we utilize fluxes and uncertainties from the CASA-GFED model of the terrestrial biosphere and biomass burning driven by satellite observations and interannually varying meteorology. We also use measurement-based ocean flux estimates and two sets of fixed fossil CO2 emissions. Here, our inversions incorporate column CO2 measurements from the GOSAT satellite (ACOS retrieval, filtered and bias-corrected) and in situ observations (individual flask and afternoon-average continuous observations) to estimate fluxes in 108 regions over 8-day intervals for the batch inversion and at 3 x 3.75 weekly for the variational system. Relationships between fluxes and atmospheric concentrations are derived consistently for the two inversion systems using the PCTM atmospheric transport model driven by meteorology from the MERRA reanalysis. We compare the posterior fluxes and uncertainties derived using different data sets and the two inversion approaches, and evaluate the posterior atmospheric concentrations against independent data including aircraft measurements. The optimized fluxes generally resemble those from other studies. For example, the results indicate that the terrestrial biosphere is a net CO2 sink, and a GOSAT-only inversion suggests a shift in

  14. In-situ observations of point-defect precipitation at dislocations in electron-irradiated silver

    International Nuclear Information System (INIS)

    Jenkins, M.L.; Hardy, G.J.; Kirk, M.A.

    1986-09-01

    In-situ weak-beam observations of the development of electron irradiation damage at dislocations in silver are described. Dislocations constrict and promote in their vicinity the formation of stacking-fault tetrahedra. The possibility that these are of interstitial nature is discussed

  15. Mud volcanos and mud domes of the central Mediterranean Ridge: near bottom and in situ observations

    NARCIS (Netherlands)

    Huguen, C.; Mascle, J.; Woodside, J.M.; Zitter, T.A.C.; Foucher, J.-P.

    2005-01-01

    The first high-resolution mapping of mud volcanoes and mud domes of the Central Mediterranean Ridge (Eastern Mediterranean) presented here is based on successive in situ observations from the Nautile submersible [MEDINAUT (1998) and NAUTINIL (2003) surveys] and near-bottom side-scan sonar data

  16. In situ observations of Pc1 pearl pulsations by the Van Allen Probes

    Science.gov (United States)

    Paulson, K. W.; Smith, C. W.; Lessard, M. R.; Engebretson, M. J.; Torbert, R. B.; Kletzing, C. A.

    2014-03-01

    We present in situ observations of Pc1 pearl pulsations using the Van Allen Probes. These waves are often observed using ground-based magnetometers, but are rarely observed by orbiting satellites. With the Van Allen Probes, we have seen at least 14 different pearl pulsation events during the first year of operations. These new in situ measurements allow us to identify the wave classification based on local magnetic field conditions. Additionally, by using two spacecraft, we are able to observe temporal changes in the region of observation. The waves appear to be generated at an overall central frequency, as often observed on the ground, and change polarization from left- to right-handedness as they propagate into a region where they are resonant with the crossover frequency (where R- and L-mode waves have the same phase velocity). By combining both in situ and ground-based data, we have found that the region satisfying electromagnetic ion cyclotron wave generation conditions is azimuthally large while radially narrow. The observation of a similar modulation period on the ground as in the magnetosphere contradicts the bouncing wave packet mechanism of generation.

  17. In situ observation of a hydrogel-glass interface during sliding friction

    OpenAIRE

    Yamamoto, Tetsurou; Kurokawa, Takayuki; Ahmed, Jamil; Kamita, Gen; Yashima, Shintaro; Furukawa, Yuichiro; Ota, Yuko; Furukawa, Hidemitsu; Gong, Jian Ping

    2014-01-01

    Direct observation of hydrogel contact with a solid surface in water is indispensable for understanding the friction, lubrication, and adhesion of hydrogels under water. However, this is a difficult task since the refractive index of hydrogels is very close to that of water. In this paper, we present a novel method to in situ observe the macroscopic contact of hydrogels with a solid surface based on the principle of critical refraction. This method was applied to investigate the sliding frict...

  18. Dynamical 'in situ' observation of biological samples using variable pressure scanning electron microscope

    International Nuclear Information System (INIS)

    Nedela, V

    2008-01-01

    Possibilities of 'in-situ' observation of non-conductive biological samples free of charging artefacts in dynamically changed surrounding conditions are the topic of this work. The observed biological sample, the tongue of a rat, was placed on a cooled Peltier stage. We studied the visibility of topographical structure depending on transition between liquid and gas state of water in the specimen chamber of VP SEM.

  19. HVEM in-situ observation of formation of helical dislocations in Ag-10at.%Al

    International Nuclear Information System (INIS)

    Saka, H.; Kondo, T.

    1982-01-01

    Dissociated near-screw dislocations in Ag-10at.%Al were irradiated with 1 MeV electrons at 473K in a HVEM and the transformation of the dissociated screws into helices as a result of the interaction of point defects introduced was observed in situ using the 'weak-beam' electron microscopy. Results of observations have been analysed in terms of the 'loop-jog' model of climb of dissociated dislocations proposed by Cherns, Hirsch and Saka. (author)

  20. Mars MetNet Mission - Martian Atmospheric Observational Post Network

    Science.gov (United States)

    Harri, A.-M.; Haukka, H.; Aleksashkin, S.; Arruego, I.; Schmidt, W.; Genzer, M.; Vazquez, L.; Siikonen, T.; Palin, M.

    2017-09-01

    A new kind of planetary exploration mission for Mars is under development in collaboration between the Finnish Meteorological Institute (FMI), Lavochkin Association (LA), Space Research Institute (IKI) and Institutio Nacional de Tecnica Aerospacial (INTA). The Mars MetNet mission is based on a new semi-hard landing vehicle called MetNet Lander (MNL). The scientific payload of the Mars MetNet Precursor [1] mission is divided into three categories: Atmospheric instruments, Optical devices and Composition and structure devices. Each of the payload instruments will provide significant insights in to the Martian atmospheric behavior. The key technologies of the MetNet Lander have been qualified and the electrical qualification model (EQM) of the payload bay has been built and successfully tested.

  1. MIPAS observations of ozone in the middle atmosphere

    Science.gov (United States)

    López-Puertas, Manuel; García-Comas, Maya; Funke, Bernd; Gardini, Angela; Stiller, Gabriele P.; von Clarmann, Thomas; Glatthor, Norbert; Laeng, Alexandra; Kaufmann, Martin; Sofieva, Viktoria F.; Froidevaux, Lucien; Walker, Kaley A.; Shiotani, Masato

    2018-04-01

    In this paper we describe the stratospheric and mesospheric ozone (version V5r_O3_m22) distributions retrieved from MIPAS observations in the three middle atmosphere modes (MA, NLC, and UA) taken with an unapodized spectral resolution of 0.0625 cm-1 from 2005 until April 2012. O3 is retrieved from microwindows in the 14.8 and 10 µm spectral regions and requires non-local thermodynamic equilibrium (non-LTE) modelling of the O3 v1 and v3 vibrational levels. Ozone is reliably retrieved from 20 km in the MA mode (40 km for UA and NLC) up to ˜ 105 km during dark conditions and up to ˜ 95 km during illuminated conditions. Daytime MIPAS O3 has an average vertical resolution of 3-4 km below 70 km, 6-8 km at 70-80 km, 8-10 km at 80-90, and 5-7 km at the secondary maximum (90-100 km). For nighttime conditions, the vertical resolution is similar below 70 km and better in the upper mesosphere and lower thermosphere: 4-6 km at 70-100 km, 4-5 km at the secondary maximum, and 6-8 km at 100-105 km. The noise error for daytime conditions is typically smaller than 2 % below 50 km, 2-10 % between 50 and 70 km, 10-20 % at 70-90 km, and ˜ 30 % above 95 km. For nighttime, the noise errors are very similar below around 70 km but significantly smaller above, being 10-20 % at 75-95 km, 20-30 % at 95-100 km, and larger than 30 % above 100 km. The additional major O3 errors are the spectroscopic data uncertainties below 50 km (10-12 %) and the non-LTE and temperature errors above 70 km. The validation performed suggests that the spectroscopic errors below 50 km, mainly caused by the O3 air-broadened half-widths of the v2 band, are overestimated. The non-LTE error (including the uncertainty of atomic oxygen in nighttime) is relevant only above ˜ 85 km with values of 15-20 %. The temperature error varies from ˜ 3 % up to 80 km to 15-20 % near 100 km. Between 50 and 70 km, the pointing and spectroscopic errors are the dominant uncertainties. The validation performed in comparisons with

  2. Corrections to the Predicitions for Atmospheric Neutrino Observations

    OpenAIRE

    Poirier, J.

    2000-01-01

    The theoretical Monte Carlo calculations of the production of neutrinos via cosmic rays incident upon the earth's atmosphere are examined. The calculations are sensitive to the assumed ratio of pi+ / pi- production cross sections; this ratio appears to be underestimated in the theory relative to the experimentally measured ratio. Since the neutrino detection cross section is three times larger than that for the antineutrino, the theoretical predicted detection ratio (nu_mu / nu_e) is correspo...

  3. A virtual remote sensing observation network for continuous, near-real-time monitoring of atmospheric instability

    Science.gov (United States)

    Toporov, Maria; Löhnert, Ulrich; Potthast, Roland; Cimini, Domenico; De Angelis, Francesco

    2017-04-01

    Short-term forecasts of current high-resolution numerical weather prediction models still have large deficits in forecasting the exact temporal and spatial location of severe, locally influenced weather such as summer-time convective storms or cool season lifted stratus or ground fog. Often, the thermodynamic instability - especially in the boundary layer - plays an essential role in the evolution of weather events. While the thermodynamic state of the atmosphere is well measured close to the surface (i.e. 2 m) by in-situ sensors and in the upper troposphere by satellite sounders, the planetary boundary layer remains a largely under-sampled region of the atmosphere where only sporadic information from radiosondes or aircraft observations is available. The major objective of the presented DWD-funded project ARON (Extramural Research Programme) is to overcome this observational gap and to design an optimized network of ground based microwave radiometers (MWR) and compact Differential Absorption Lidars (DIAL) for a continuous, near-real-time monitoring of temperature and humidity in the atmospheric boundary layer in order to monitor thermodynamic (in)stability. Previous studies showed, that microwave profilers are well suited for continuously monitoring the temporal development of atmospheric stability (i.e. Cimini et al., 2015) before the initiation of deep convection, especially in the atmospheric boundary layer. However, the vertical resolution of microwave temperature profiles is best in the lowest kilometer above the surface, decreasing rapidly with increasing height. In addition, humidity profile retrievals typically cannot be resolved with more than two degrees of freedom for signal, resulting in a rather poor vertical resolution throughout the troposphere. Typical stability indices used to assess the potential of convection rely on temperature and humidity values not only in the region of the boundary layer but also in the layers above. Therefore, satellite

  4. In situ observation of a soap-film catenoid-a simple educational physics experiment

    International Nuclear Information System (INIS)

    Ito, Masato; Sato, Taku

    2010-01-01

    The solution to the Euler-Lagrange equation is an extremal functional. To understand that the functional is stationary at local extrema (maxima or minima), we propose a physics experiment that involves using a soap film to form a catenoid. A catenoid is a surface that is formed between two coaxial circular rings and is classified mathematically as a minimal surface. Using the soap film, we create catenoids between two rings and characterize the catenoid in situ while varying the distance between the rings. The shape of the soap film is very interesting and can be explained using dynamic mechanics. By observing the catenoid, physics students can observe local extrema phenomena. We stress that in situ observation of soap-film catenoids is an appropriate physics experiment that combines theory and experimentation.

  5. In situ observation of a soap-film catenoid-a simple educational physics experiment

    Energy Technology Data Exchange (ETDEWEB)

    Ito, Masato; Sato, Taku [Department of Physics, Aichi University of Education, Kariya, 448-8542 (Japan)], E-mail: mito@auecc.aichi-edu.ac.jp

    2010-03-15

    The solution to the Euler-Lagrange equation is an extremal functional. To understand that the functional is stationary at local extrema (maxima or minima), we propose a physics experiment that involves using a soap film to form a catenoid. A catenoid is a surface that is formed between two coaxial circular rings and is classified mathematically as a minimal surface. Using the soap film, we create catenoids between two rings and characterize the catenoid in situ while varying the distance between the rings. The shape of the soap film is very interesting and can be explained using dynamic mechanics. By observing the catenoid, physics students can observe local extrema phenomena. We stress that in situ observation of soap-film catenoids is an appropriate physics experiment that combines theory and experimentati0008.

  6. In situ observation of mechanical damage within a SiC-SiC ceramic matrix composite

    International Nuclear Information System (INIS)

    Saucedo-Mora, L.; Lowe, T.; Zhao, S.; Lee, P.D.; Mummery, P.M.; Marrow, T.J.

    2016-01-01

    SiC-SiC ceramic matrix composites are candidate materials for fuel cladding in Generation IV nuclear fission reactors and as accident tolerant fuel clad in current generation plant. Experimental methods are needed that can detect and quantify the development of mechanical damage, to support modelling and qualification tests for these critical components. In situ observations of damage development have been obtained of tensile and C-ring mechanical test specimens of a braided nuclear grade SiC-SiC ceramic composite tube, using a combination of ex situ and in situ computed X-ray tomography observation and digital volume correlation analysis. The gradual development of damage by matrix cracking and also the influence of non-uniform loading are examined. - Highlights: • X-ray tomography with digital volume correlation measures 3D deformation in situ. • Cracking and damage in the microstructure can be detected using the strain field. • Fracture can initiate from the monolithic coating of a SiC-SiC ceramic composite.

  7. In situ observation of mechanical damage within a SiC-SiC ceramic matrix composite

    Energy Technology Data Exchange (ETDEWEB)

    Saucedo-Mora, L. [Institute Eduardo Torroja for Construction Sciences-CSIC, Madrid (Spain); Department of Materials, University of Oxford (United Kingdom); Lowe, T. [Manchester X-ray Imaging Facility, The University of Manchester (United Kingdom); Zhao, S. [Department of Materials, University of Oxford (United Kingdom); Lee, P.D. [Research Complex at Harwell, Rutherford Appleton Laboratory (United Kingdom); Mummery, P.M. [School of Mechanical, Aerospace and Civil Engineering, The University of Manchester (United Kingdom); Marrow, T.J., E-mail: james.marrow@materials.ox.ac.uk [Department of Materials, University of Oxford (United Kingdom)

    2016-12-01

    SiC-SiC ceramic matrix composites are candidate materials for fuel cladding in Generation IV nuclear fission reactors and as accident tolerant fuel clad in current generation plant. Experimental methods are needed that can detect and quantify the development of mechanical damage, to support modelling and qualification tests for these critical components. In situ observations of damage development have been obtained of tensile and C-ring mechanical test specimens of a braided nuclear grade SiC-SiC ceramic composite tube, using a combination of ex situ and in situ computed X-ray tomography observation and digital volume correlation analysis. The gradual development of damage by matrix cracking and also the influence of non-uniform loading are examined. - Highlights: • X-ray tomography with digital volume correlation measures 3D deformation in situ. • Cracking and damage in the microstructure can be detected using the strain field. • Fracture can initiate from the monolithic coating of a SiC-SiC ceramic composite.

  8. The Isinglass Auroral Sounding Rocket Campaign: data synthesis incorporating remote sensing, in situ observations, and modelling

    Science.gov (United States)

    Lynch, K. A.; Clayton, R.; Roberts, T. M.; Hampton, D. L.; Conde, M.; Zettergren, M. D.; Burleigh, M.; Samara, M.; Michell, R.; Grubbs, G. A., II; Lessard, M.; Hysell, D. L.; Varney, R. H.; Reimer, A.

    2017-12-01

    The NASA auroral sounding rocket mission Isinglass was launched from Poker Flat Alaska in winter 2017. This mission consists of two separate multi-payload sounding rockets, over an array of groundbased observations, including radars and filtered cameras. The science goal is to collect two case studies, in two different auroral events, of the gradient scale sizes of auroral disturbances in the ionosphere. Data from the in situ payloads and the groundbased observations will be synthesized and fed into an ionospheric model, and the results will be studied to learn about which scale sizes of ionospheric structuring have significance for magnetosphere-ionosphere auroral coupling. The in situ instrumentation includes thermal ion sensors (at 5 points on the second flight), thermal electron sensors (at 2 points), DC magnetic fields (2 point), DC electric fields (one point, plus the 4 low-resource thermal ion RPA observations of drift on the second flight), and an auroral precipitation sensor (one point). The groundbased array includes filtered auroral imagers, the PFISR and SuperDarn radars, a coherent scatter radar, and a Fabry-Perot interferometer array. The ionospheric model to be used is a 3d electrostatic model including the effects of ionospheric chemistry. One observational and modelling goal for the mission is to move both observations and models of auroral arc systems into the third (along-arc) dimension. Modern assimilative tools combined with multipoint but low-resource observations allow a new view of the auroral ionosphere, that should allow us to learn more about the auroral zone as a coupled system. Conjugate case studies such as the Isinglass rocket flights allow for a test of the models' intepretation by comparing to in situ data. We aim to develop and improve ionospheric models to the point where they can be used to interpret remote sensing data with confidence without the checkpoint of in situ comparison.

  9. Atmospheric pressure loading parameters from very long baseline interferometry observations

    Science.gov (United States)

    Macmillan, D. S.; Gipson, John M.

    1994-01-01

    Atmospheric mass loading produces a primarily vertical displacement of the Earth's crust. This displacement is correlated with surface pressure and is large enough to be detected by very long baseline interferometry (VLBI) measurements. Using the measured surface pressure at VLBI stations, we have estimated the atmospheric loading term for each station location directly from VLBI data acquired from 1979 to 1992. Our estimates of the vertical sensitivity to change in pressure range from 0 to -0.6 mm/mbar depending on the station. These estimates agree with inverted barometer model calculations (Manabe et al., 1991; vanDam and Herring, 1994) of the vertical displacement sensitivity computed by convolving actual pressure distributions with loading Green's functions. The pressure sensitivity tends to be smaller for stations near the coast, which is consistent with the inverted barometer hypothesis. Applying this estimated pressure loading correction in standard VLBI geodetic analysis improves the repeatability of estimated lengths of 25 out of 37 baselines that were measured at least 50 times. In a root-sum-square (rss) sense, the improvement generally increases with baseline length at a rate of about 0.3 to 0.6 ppb depending on whether the baseline stations are close to the coast. For the 5998-km baseline from Westford, Massachusetts, to Wettzell, Germany, the rss improvement is about 3.6 mm out of 11.0 mm. The average rss reduction of the vertical scatter for inland stations ranges from 2.7 to 5.4 mm.

  10. Ultrasensitive Mid-Infrared In Situ Spectrometer for Planetary Atmospheric Analysis, Phase II

    Data.gov (United States)

    National Aeronautics and Space Administration — The Small Business Innovative Research Phase I proposal seeks to develop a compact, robust in situ spectrometer capable of detecting multiple gas-phase species in...

  11. Are Global In-Situ Ocean Observations Fit-for-purpose? Applying the Framework for Ocean Observing in the Atlantic.

    Science.gov (United States)

    Visbeck, M.; Fischer, A. S.; Le Traon, P. Y.; Mowlem, M. C.; Speich, S.; Larkin, K.

    2015-12-01

    There are an increasing number of global, regional and local processes that are in need of integrated ocean information. In the sciences ocean information is needed to support physical ocean and climate studies for example within the World Climate Research Programme and its CLIVAR project, biogeochemical issues as articulated by the GCP, IMBER and SOLAS projects of ICSU-SCOR and Future Earth. This knowledge gets assessed in the area of climate by the IPCC and biodiversity by the IPBES processes. The recently released first World Ocean Assessment focuses more on ecosystem services and there is an expectation that the Sustainable Development Goals and in particular Goal 14 on the Ocean and Seas will generate new demands for integrated ocean observing from Climate to Fish and from Ocean Resources to Safe Navigation and on a healthy, productive and enjoyable ocean in more general terms. In recognition of those increasing needs for integrated ocean information we have recently launched the Horizon 2020 AtlantOS project to promote the transition from a loosely-coordinated set of existing ocean observing activities to a more integrated, more efficient, more sustainable and fit-for-purpose Atlantic Ocean Observing System. AtlantOS takes advantage of the Framework for Ocean observing that provided strategic guidance for the design of the project and its outcome. AtlantOS will advance the requirements and systems design, improving the readiness of observing networks and data systems, and engaging stakeholders around the Atlantic. AtlantOS will bring Atlantic nations together to strengthen their complementary contributions to and benefits from the internationally coordinated Global Ocean Observing System (GOOS) and the Blue Planet Initiative of the Global Earth Observation System of Systems (GEOSS). AtlantOS will fill gaps of the in-situ observing system networks and will ensure that their data are readily accessible and useable. AtlantOS will demonstrate the utility of

  12. Direct in situ observations of single Fe atom catalytic processes and anomalous diffusion at graphene edges

    Science.gov (United States)

    Zhao, Jiong; Deng, Qingming; Avdoshenko, Stanislav M.; Fu, Lei; Eckert, Jürgen; Rümmeli, Mark H.

    2014-01-01

    Single-atom catalysts are of great interest because of their high efficiency. In the case of chemically deposited sp2 carbon, the implementation of a single transition metal atom for growth can provide crucial insight into the formation mechanisms of graphene and carbon nanotubes. This knowledge is particularly important if we are to overcome fabrication difficulties in these materials and fully take advantage of their distinct band structures and physical properties. In this work, we present atomically resolved transmission EM in situ investigations of single Fe atoms at graphene edges. Our in situ observations show individual iron atoms diffusing along an edge either removing or adding carbon atoms (viz., catalytic action). The experimental observations of the catalytic behavior of a single Fe atom are in excellent agreement with supporting theoretical studies. In addition, the kinetics of Fe atoms at graphene edges are shown to exhibit anomalous diffusion, which again, is in agreement with our theoretical investigations. PMID:25331874

  13. Photometric observations of local rocket-atmosphere interactions

    Science.gov (United States)

    Greer, R. G. H.; Murtagh, D. P.; Witt, G.; Stegman, J.

    1983-06-01

    Photometric measurements from rocket flights which recorded a strong foreign luminance in the altitude region between 90 and 130 km are reported. From one Nike-Orion rocket the luminance appeared on both up-leg and down-leg; from a series of Petrel rockets the luminance was apparent only on the down-leg. The data suggest that the luminance may be distributed mainly in the wake region along the rocket trajectory. The luminance is believed to be due to a local interaction between the rocket and the atmosphere although the precise nature of the interaction is unknown. It was measured at wavelengths ranging from 275 nm to 1.61 microns and may be caused by a combination of reactions.

  14. Total observed organic carbon (TOOC in the atmosphere: a synthesis of North American observations

    Directory of Open Access Journals (Sweden)

    C. L. Heald

    2008-04-01

    Full Text Available Measurements of organic carbon compounds in both the gas and particle phases made upwind, over and downwind of North America are synthesized to examine the total observed organic carbon (TOOC in the atmosphere over this region. These include measurements made aboard the NOAA WP-3 and BAe-146 aircraft, the NOAA research vessel Ronald H. Brown, and at the Thompson Farm and Chebogue Point surface sites during the summer 2004 ICARTT campaign. Both winter and summer 2002 measurements during the Pittsburgh Air Quality Study are also included. Lastly, the spring 2002 observations at Trinidad Head, CA, surface measurements made in March 2006 in Mexico City and coincidentally aboard the C-130 aircraft during the MILAGRO campaign and later during the IMPEX campaign off the northwestern United States are incorporated. Concentrations of TOOC in these datasets span more than two orders of magnitude. The daytime mean TOOC ranges from 4.0 to 456 μgC m−3 from the cleanest site (Trinidad Head to the most polluted (Mexico City. Organic aerosol makes up 3–17% of this mean TOOC, with highest fractions reported over the northeastern United States, where organic aerosol can comprise up to 50% of TOOC. Carbon monoxide concentrations explain 46 to 86% of the variability in TOOC, with highest TOOC/CO slopes in regions with fresh anthropogenic influence, where we also expect the highest degree of mass closure for TOOC. Correlation with isoprene, formaldehyde, methyl vinyl ketone and methacrolein also indicates that biogenic activity contributes substantially to the variability of TOOC, yet these tracers of biogenic oxidation sources do not explain the variability in organic aerosol observed over North America. We highlight the critical need to develop measurement techniques to routinely detect total gas phase VOCs, and to deploy comprehensive suites of TOOC instruments in diverse environments to quantify the ambient evolution of organic carbon from source

  15. In situ Microscopic Observation of Sodium Deposition/Dissolution on Sodium Electrode

    OpenAIRE

    Yuhki Yui; Masahiko Hayashi; Jiro Nakamura

    2016-01-01

    Electrochemical sodium deposition/dissolution behaviors in propylene carbonate-based electrolyte solution were observed by means of in situ light microscopy. First, granular sodium was deposited at pits in a sodium electrode in the cathodic process. Then, the sodium particles grew linearly from the electrode surface, becoming needle-like in shape. In the subsequent anodic process, the sodium dissolved near the base of the needles on the sodium electrode and the so-called ?dead sodium? broke a...

  16. In-situ observation of damage evolution in TiC crystals during helium ion irradiation

    International Nuclear Information System (INIS)

    Hojou, K.; Otsu, H.; Furuno, S.; Izui, K.; Tsukamoto, T.

    1994-01-01

    In-situ observations were performed on bubble formation and growth in TiC during 20 keV helium ion irradiation over the wide range of irradiation temperatures from 12 to 1523 K. No amorphization occurred over this temperature range. The bubble densities and sizes were almost independent of irradiation temperatures from 12 to 1273 K. Remarkable growth and coalescence occurred during irradiation at high temperature above 1423 K and during annealing above 1373 K after irradiation. ((orig.))

  17. Regional Evaluation of ERA-40 Reanalysis Data with Marine Atmospheric Observations in the North Sea Area

    Directory of Open Access Journals (Sweden)

    Nils H. Schade

    2013-12-01

    Full Text Available An important task of the departmental research programme KLIWAS is the evaluation and assessment of climate model results by means of a comprehensive reference data set. For validation purposes, and to create a North Sea wide maritime atmospheric and oceanographic reference database, in-situ observations of the Centre for Global Marine Meteorological Observations (GZS of the National Meteorological Service DWD have been compared to the ERA-40 reanalysis. ERA-40 is used as forcing for the hindcast runs of the ENSEMBLES regional climate models, which is used within the KLIWAS model chain. The GZS hosts a regularly updated, quality controlled, world-wide data bank of weather observations from the oceans. It includes data from all sorts of observation platforms as Voluntary Observing Ships (VOS, drifting and moored buoys, light vessels, and offshore platforms, either from real-time (RT via the Global Telecommunication System (GTS or from international exchange in delayed-mode (DM. In addition to the automated set of programs applied for high quality control, erroneous data are also manually corrected to a certain extent, if possible. To assure reliable statistics for the evaluation, the corrected observations are gridded to a resolution of 2.25 degree, so each grid box includes four ERA-40 reanalysis grid points. The temporal coverage of the grid boxes depends on shipping routes and the positions of automated systems. Observed air temperatures, covering a period of 40 years (1961?2000, show noticeable differences to the reanalysis data for all land influenced boxes, specifically in the winter months. The same differences can be found if ERA-40 data alone are compared between land- and sea facing boxes. They can not be found in GZS data. It can be assumed that the differences are not resulting from measurement errors or uncertain fraction variabilities, since they are small during the winter months. A comparison of the differences basing on the 1981

  18. Southeast Atmosphere Studies: learning from model-observation syntheses

    Data.gov (United States)

    U.S. Environmental Protection Agency — Observed and modeled data shown in figure 2b-c. This dataset is associated with the following publication: Mao, J., A. Carlton, R. Cohen, W. Brune, S. Brown, G....

  19. Development of a Ground-Based Atmospheric Monitoring Network for the Global Mercury Observation System (GMOS

    Directory of Open Access Journals (Sweden)

    Sprovieri F.

    2013-04-01

    Full Text Available Consistent, high-quality measurements of atmospheric mercury (Hg are necessary in order to better understand Hg emissions, transport, and deposition on a global scale. Although the number of atmospheric Hg monitoring stations has increased in recent years, the available measurement database is limited and there are many regions of the world where measurements have not been extensively performed. Long-term atmospheric Hg monitoring and additional ground-based monitoring sites are needed in order to generate datasets that will offer new insight and information about the global scale trends of atmospheric Hg emissions and deposition. In the framework of the Global Mercury Observation System (GMOS project, a coordinated global observational network for atmospheric Hg is being established. The overall research strategy of GMOS is to develop a state-of-the-art observation system able to provide information on the concentration of Hg species in ambient air and precipitation on the global scale. This network is being developed by integrating previously established ground-based atmospheric Hg monitoring stations with newly established GMOS sites that are located both at high altitude and sea level locations, as well as in climatically diverse regions. Through the collection of consistent, high-quality atmospheric Hg measurement data, we seek to create a comprehensive assessment of atmospheric Hg concentrations and their dependence on meteorology, long-range atmospheric transport and atmospheric emissions.

  20. Atmospheric methane variability at the Peterhof station (Russia): ground-based observations and modeling

    Science.gov (United States)

    Makarova, Maria; Kirner, Oliver; Poberovskii, Anatoliy; Imhasin, Humud; Timofeyev, Yuriy; Virolainen, Yana; Makarov, Boris

    2014-05-01

    MF from the true ones were detected for the Peterhof station (0.4% for TC and -0.2% for MF). It should be also noted that the limited number of sunny days may distort the annual cycle estimated from FTIR data (comparing to true). This fact have to take into account when mean levels of CH4 TC and MF obtained from FTIR compare against climatological or averaged model data. Ground-based in situ (local) observations of CH4 mole fraction (LMF) are being performed by LGR GGA-24r-EP gas analyzer since 2013 (at the Peterhof station). The monthly averaged amplitude of LMF diurnal cycle shows variations which are similar to the temporal behavior of MF CH4 retrieved from FTIR for 2013. It is suggested that the value of the amplitude of CH4 LMF diurnal variation characterizes the intensity of methane sources for the North-western region of Russia and can be used to explain the observed features of the annual variation of FTIR MF CH4. However, to prove this statement further simultaneous FTIR and in situ measurements of CH4 should be continued. Both, FTIR observations and EMAC simulations, revealed the positive trend of CH4 over 2009-2012 of about 0.2% per year (statistically significant). FTIR data for 2013 that were taken into account led to a decrease in trend value from 0.2%/yr (2009-2012) to 0.13%/yr (2009-2013). It may indicate the end of the period of extremely high growth rates of methane in the atmosphere that have been registered by different observational systems since 2006. Acknowledgements: This study was funded by Saint-Petersburg State University (grant No.11.0.44.2010), Russian Foundation for Basic Research (grants No.12-05-00596, 14-05-897). Measurement facilities were provided by Geo Environmental Research Center "Geomodel" of Saint-Petersburg State University.

  1. The solar wind at solar maximum: comparisons of EISCAT IPS and in situ observations

    Directory of Open Access Journals (Sweden)

    A. R. Breen

    Full Text Available The solar maximum solar wind is highly structured in latitude, longitude and in time. Coronal measurements show a very high degree of variability, with large variations that are less apparent within in situ spacecraft measurements. Interplanetary scintillation (IPS observations from EISCAT, covering distances from 20 to 100 solar radii (RS, are an ideal source of information on the inner solar wind and can be used, therefore, to cast light on its evolution with distance from the Sun. Earlier comparisons of in situ and IPS measurements under solar minimum conditions showed good large-scale agreement, particularly in the fast wind. In this study we attempt a quantitative comparison of measurements made over solar maximum by EISCAT (20–100 RS and the Wind and Ulysses spacecraft (at 215 RS and 300–1000 RS, respectively. The intervals studied were August–September 1999, May 2000, September 2000 and May 2001, the last-named being the period of the second Ulysses fast latitude scan. Both ballistic and – when possible – MHD/ballistic hybrid models were used to relate the data sets, and we compare the results obtained from these two mapping methods. The results of this study suggest that solar wind velocities measured in situ were less variable than those estimated from IPS measurements closer to the Sun, with the greatest divergence between IPS velocities and in situ measurements occurring in regions where steep longitudinal velocity gradients were seen in situ. We suggest that the interaction between streams of solar wind with different velocities leads to "smoothing" of solar wind velocities between 30–60 RS and 1 AU, and that this process continues at greater distances from the Sun.

    Key words. Interplanetary physics (solar wind plasma; sources of the solar wind; instruments and techniques

  2. Observations of atmospheric structure using an acoustic sounder

    International Nuclear Information System (INIS)

    Shaw, N.A.

    1974-11-01

    An acoustic sounder has been used to monitor the vertical temperature structure of the lowest 1.5 km of the atmosphere over the meteorological field site at Argonne National Laboratory since February 1972. Additional records were obtained near St. Louis, Mo., during the month of August. Sounder records obtained during cloudless days on which no major synoptic events occurred are separated into three characteristic phases. The first phase is the rise of the morning inversion associated with increasing solar heating of the surface after dawn. The second phase is the period of strong convective activity that usually exists between about 1100 and 1600 local time in summer and which typically destroys the inversion. The third phase includes the gradual regeneration of the low level inversion through radiation cooling of the lowest levels, followed by a period of persistence throughout the night until the first phase begins again after sunrise. Analysis of records obtained from a single acoustic sounder operating in the vertically-pointing, monostatic mode is subject to the usual ambiguity regarding the relative importance of advective effects and local changes with time. To provide a spatial sampling facility, a mobile acoustic sounding system was constructed during 1972. Details of the mobile antenna acoustic baffle or cuff are given in the Appendix. (19 figures, 1 table) (U.S.)

  3. In-situ observations of stress-induced thin film failures

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Z.B., E-mail: zzhao@firstsolar.co [Delphi Research Labs, 51786 Shelby Parkway, Shelby Twp., MI 48315 (United States); Hershberger, J. [Laird Technologies, 4707 Detroit Avenue, Cleveland, Ohio, 44102 (United States); Bilello, J.C. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109-2136 (United States)

    2010-02-01

    In this work, the failure modes of thin films under thermo-mechanical treatments were observed via in-situ white beam X-ray topography. The in-situ experiments were carried out using an experimental setup on Beamline 2-2 at the Stanford Synchrotron Radiation Laboratory. Magnetron sputtered polycrystalline thin films of Ta and CrN on Si substrates were selected for the present study due to their disparate states of intrinsic residual stresses: the Ta film was anisotropically compressive and the CrN film was isotropically tensile. Under a similar heating-cooling cycle in air, the two types of films exhibited distinct failure modes, which were observed in-situ and in a quasi-real-time fashion. The failures of the samples have been interpreted based on their distinctive growth stress states, superimposed on the additional stress development associated with different forms of thermal instabilities upon heating. These included the formation of oxide for the Ta/Si sample, which led to an increase in compressive stress, and a phase change for the CrN/Si sample, which caused the isotropic stress in the film to become increasingly tensile.

  4. In-situ observations of stress-induced thin film failures

    International Nuclear Information System (INIS)

    Zhao, Z.B.; Hershberger, J.; Bilello, J.C.

    2010-01-01

    In this work, the failure modes of thin films under thermo-mechanical treatments were observed via in-situ white beam X-ray topography. The in-situ experiments were carried out using an experimental setup on Beamline 2-2 at the Stanford Synchrotron Radiation Laboratory. Magnetron sputtered polycrystalline thin films of Ta and CrN on Si substrates were selected for the present study due to their disparate states of intrinsic residual stresses: the Ta film was anisotropically compressive and the CrN film was isotropically tensile. Under a similar heating-cooling cycle in air, the two types of films exhibited distinct failure modes, which were observed in-situ and in a quasi-real-time fashion. The failures of the samples have been interpreted based on their distinctive growth stress states, superimposed on the additional stress development associated with different forms of thermal instabilities upon heating. These included the formation of oxide for the Ta/Si sample, which led to an increase in compressive stress, and a phase change for the CrN/Si sample, which caused the isotropic stress in the film to become increasingly tensile.

  5. 3D in situ observations of glass fibre/matrix interfacial debonding

    DEFF Research Database (Denmark)

    Martyniuk, Karolina; Sørensen, Bent F.; Modregger, Peter

    2013-01-01

    X-ray microtomography was used for 3D in situ observations of the evolution of fibre/matrix interfacial debonding. A specimen with a single fibre oriented perpendicular to the tensile direction was tested at a synchrotron facility using a special loading rig which allowed for applying a load...... transverse to the fibre. Three distinguishable damage stages were observed: (i) interfacial debond initiation at the free surface, (ii) debond propagation from the surface into the specimen and (iii) unstable debonding along the full length of the scanned volume. The high resolution microtomography provides...

  6. In situ transmission electron microscope observation of the formation of fuzzy structures on tungsten

    International Nuclear Information System (INIS)

    Miyamoto, M; Watanabe, T; Nagashima, H; Nishijima, D; Doerner, R P; Krasheninnikov, S I; Sagara, A; Yoshida, N

    2014-01-01

    To investigate the formation processes of tungsten nano-structures, so called fuzz, in situ transmission electron microscope observations during helium ion irradiation and high temperature annealing have been performed. The irradiation with 3 keV He + from room temperature to 1273 K is found to cause high-density helium bubbles in tungsten with no significant change in the surface structure. At higher temperatures, surface morphology changes were observed even without helium irradiation due probably to surface diffusion of tungsten atoms driven by surface tension. It is clearly shown that this morphology change is enhanced with helium irradiation, i.e. the formation of helium bubbles. (paper)

  7. In-Situ atomic force microscopic observation of ion beam bombarded plant cell envelopes

    International Nuclear Information System (INIS)

    Sangyuenyongpipat, S.; Yu, L.D.; Brown, I.G.; Seprom, C.; Vilaithong, T.

    2007-01-01

    A program in ion beam bioengineering has been established at Chiang Mai University (CMU), Thailand, and ion beam induced transfer of plasmid DNA molecules into bacterial cells (Escherichia coli) has been demonstrated. However, a good understanding of the fundamental physical processes involved is lacking. In parallel work, onion skin cells have been bombarded with Ar + ions at energy 25 keV and fluence1-2 x 10 15 ions/cm 2 , revealing the formation of microcrater-like structures on the cell wall that could serve as channels for the transfer of large macromolecules into the cell interior. An in-situ atomic force microscope (AFM) system has been designed and installed in the CMU bio-implantation facility as a tool for the observation of these microcraters during ion beam bombardment. Here we describe some of the features of the in-situ AFM and outline some of the related work

  8. Viking orbiter imaging observations of dust in the Martian atmosphere

    International Nuclear Information System (INIS)

    Briggs, G.A.; Baum, W.A.; Barnes, J.

    1979-01-01

    More than 20 local Martian dust clouds and two global dust storms were observed with the Viking orbiter camera. Sixteen of the local clouds were imaged in two colors or were observed with other instruments confirming their identification as dust clouds. These Viking results are compared with earth-based observations of Martian dust storms and with Mariner 9 data. Most of the dust activity seen by Viking occurred during southern hemisphere spring and early summer, when Mars was near perihelion and isolation was near maximum. About half the local clouds occurred near the edge of the southern polar cap, where winds are presumably enhanced by a strong regional temperature gradient. The other half occurred mainly in the southern hemisphere near regions where circulation models incorporating topography predict positive vertical velocities. Although dust clouds observed from earth show a similar partial correlation with models, some ambiguity exists concerning interpretation of regions near Hellespontus that have spawned the most spectacular Martian dust storms on record

  9. Early Winter Sea Ice Dynamics in the Ross Sea from In Situ and Satellite Observations

    Science.gov (United States)

    Maksym, T.; Ackley, S. F.; Stammerjohn, S. E.; Tison, J. L.; Hoeppner, K.

    2017-12-01

    The Ross Sea sea ice cover is one of the few regions of the cryosphere that have been expanding in recent decades. However, 2017 saw a significantly delayed autumn ice advance and record low early winter sea ice extent. Understanding the causes and impacts of this variability has been hampered by a lack of in situ observations. A winter cruise into the Ross Sea in April-June 2017 provided some of the only in situ winter observations of sea ice processes in this region in almost 20 years. We present a first look at data from arrays of drifting buoys deployed in the ice pack and outflow from these polynyas, supplemented by a suite of high-resolution synthetic aperture radar (SAR) data. Additional observations included high-resolution sonar imagery of ice deformation features from an autonomous underwater vehicle, shipboard visual observations of sea ice properties, and in situ measurements of snow and thickness and structural properties. These data show that the delay in ice advance led to a thin, highly dynamic sea ice pack, with substantial ice production and export from the Ross Ice Shelf and Terra Nova Bay polynyas. Despite these high rates of ice production, the pack ice remained thin due to rapid export and northward drift. Compared to the only prior winter observations made in 1995 and 1998, the ice was thinner, with less ridging and snow cover, reflecting a younger ice cover. Granular ice was less prevalent than in these prior cruises, particularly in the outer pack, likely due to less snow ice formation and less pancake ice formation at the advancing ice edge. Despite rapid basal ice growth, the buoy data suggest that deformation may be the dominant mechanism for sea ice thickening in the pack once an initial ice cover forms.

  10. Developing a western Siberia reference site for tropospheric water vapour isotopologue observations obtained by different techniques (in situ and remote sensing

    Directory of Open Access Journals (Sweden)

    K. Gribanov

    2014-06-01

    water cycle, affected by changes in air mass origin, non-convective and convective processes and continental recycling. Novel remote sensing and in situ measuring techniques have recently offered opportunities for monitoring atmospheric water vapour isotopic composition. Recently developed infrared laser spectrometers allow for continuous in situ measurements of surface water vapour δDv and δ18Ov. So far, very few intercomparisons of measurements conducted using different techniques have been achieved at a given location, due to difficulties intrinsic to the comparison of integrated with local measurements. Nudged simulations conducted with high-resolution isotopically enabled general circulation models (GCMs provide a consistent framework for comparison with the different types of observations. Here, we compare simulations conducted with the ECHAM5-wiso model with two types of water vapour isotopic data obtained during summer 2012 at the forest site of Kourovka, western Siberia: hourly ground-based FTIR total atmospheric columnar δDv amounts, and in situ hourly Picarro δDv measurements. There is an excellent correlation between observed and predicted δDv at surface while the comparison between water column values derived from the model compares well with FTIR estimates.

  11. In-situ observation of equilibrium transitions in Ni films; agglomeration and impurity effects.

    Science.gov (United States)

    Thron, Andrew M; Greene, Peter; Liu, Kai; van Benthem, Klaus

    2014-02-01

    Dewetting of ultra-thin Ni films deposited on SiO2 layers was observed, in cross-section, by in situ scanning transmission electron microscopy. Holes were observed to nucleate by voids which formed at the Ni/SiO2 interface rather than at triple junctions at the free surface of the Ni film. Ni islands were observed to retract, in attempt to reach equilibrium on the SiO2 layer. SiO2 layers with 120 nm thickness were found to limit in situ heating experiments due to poor thermal conductivity of SiO2. The formation of graphite was observed during the agglomeration of ultra-thin Ni films. Graphite was observed to wet both the free surface and the Ni/SiO2 interface of the Ni islands. Cr forms surface oxide layers on the free surface of the SiO2 layer and the Ni islands. Cr does not prevent the dewetting of Ni, however it will likely alter the equilibrium shape of the Ni islands. © 2013 Published by Elsevier B.V.

  12. Results of Joint Observations of Jupiter's Atmosphere by Juno and a Network of Earth-Based Observing Stations

    Science.gov (United States)

    Orton, Glenn; Momary, Thomas; Bolton, Scott; Levin, Steven; Hansen, Candice; Janssen, Michael; Adriani, Alberto; Gladstone, G. Randall; Bagenal, Fran; Ingersoll, Andrew

    2017-04-01

    The Juno mission has promoted and coordinated a network of Earth-based observations, including both Earth-proximal and ground-based facilities, to extend and enhance observations made by the Juno mission. The spectral region and timeline of all of these observations are summarized in the web site: https://www.missionjuno.swri.edu/planned-observations. Among the earliest of these were observation of Jovian auroral phenomena at X-ray, ultraviolet and infrared wavelengths and measurements of Jovian synchrotron radiation from the Earth simultaneously with the measurement of properties of the upstream solar wind. Other observations of significance to the magnetosphere measured the mass loading from Io by tracking its observed volcanic activity and the opacity of its torus. Observations of Jupiter's neutral atmosphere included observations of reflected sunlight from the near-ultraviolet through the near-infrared and thermal emission from 5 μm through the radio region. The point of these measurements is to relate properties of the deep atmosphere that are the focus of Juno's mission to the state of the "weather layer" at much higher atmospheric levels. These observations cover spectral regions not included in Juno's instrumentation, provide spatial context for Juno's often spatially limited coverage of Jupiter, and they describe the evolution of atmospheric features in time that are measured only once by Juno. We will summarize the results of measurements during the approach phase of the mission that characterized the state of the atmosphere, as well as observations made by Juno and the supporting campaign during Juno's perijoves 1 (2016 August 27), 3 (2016 December 11), 4 (2017 February 2) and possibly "early" results from 5 (2017 March 27). Besides a global network of professional astronomers, the Juno mission also benefited from the enlistment of a network of dedicated amateur astronomers who provided a quasi-continuous picture of the evolution of features observed by

  13. Fusing Mobile In Situ Observations and Satellite Remote Sensing of Chemical Release Emissions to Improve Disaster Response

    Directory of Open Access Journals (Sweden)

    Ira Leifer

    2016-09-01

    Full Text Available Chemical release disasters have serious consequences, disrupting ecosystems, society, and causing significant loss of life. Mitigating the destructive impacts relies on identification and mapping, monitoring, and trajectory forecasting. Improvements in sensor capabilities are enabling airborne and spacebased remote sensing to support response activities. Key applications are improving transport models in complex terrain and improved disaster response.Chemical release disasters have serious consequences, disrupting ecosystems, society, and causing significant loss of life. Mitigating the destructive impacts relies on identification and mapping, monitoring, and trajectory forecasting. Improvements in sensor capabilities are enabling airborne and space-based remote sensing to support response activities. Key applications are improving transport models in complex terrain and improved disaster response.Understanding urban atmospheric transport in the Los Angeles Basin, where topographic influences on transport patterns are significant, was improved by leveraging the Aliso Canyon leak as an atmospheric tracer. Plume characterization data was collected by the AutoMObile trace Gas (AMOG Surveyor, a commuter car modified for science. Mobile surface in situ CH4 and winds were measured by AMOG Surveyor under Santa Ana conditions to estimate an emission rate of 365±30% Gg yr-1. Vertical profiles were collected by AMOG Surveyor by leveraging local topography for vertical profiling to identify the planetary boundary layer at ~700 m. Topography significantly constrained plume dispersion by up to a factor of two. The observed plume trajectory was used to validate satellite aerosol optical depth-inferred atmospheric transport, which suggested the plume first was driven offshore, but then veered back towards land. Numerical long-range transport model predictions confirm this interpretation. This study demonstrated a novel application of satellite aerosol remote

  14. Evaluation of a cavity ring-down spectrometer for in situ observations of 13CO2

    Directory of Open Access Journals (Sweden)

    D. E. J. Worthy

    2013-02-01

    Full Text Available With the emergence of wide-spread application of new optical techniques to monitor δ13C in atmospheric CO2 there is a growing need to ensure well-calibrated measurements. We characterized one commonly available instrument, a cavity ring-down spectrometer (CRDS system used for continuous in situ monitoring of atmospheric 13CO2. We found no dependency of δ13C on the CO2 concentration in the range of 303–437 ppm. We designed a calibration scheme according to the diagnosed instrumental drifts and established a quality assurance protocol. We find that the repeatability (1-σ of measurements is 0.25‰ for 10 min and 0.15‰ for 20 min integrated averages, respectively. Due to a spectral overlap, our instrument displays a cross-sensitivity to CH4 of 0.42 ± 0.024‰ ppm−1. Our ongoing target measurements yield standard deviations of δ13C from 0.22‰ to 0.28‰ for 10 min averages. We furthermore estimate the reproducibility of our system for ambient air samples from weekly measurements of a long-term target gas to be 0.18‰. We find only a minuscule offset of 0.002 ± 0.025‰ between the CRDS and Environment Canada's isotope ratio mass spectrometer (IRMS results for four target gases used over the course of one year.

  15. Impact of atmospheric refraction: how deeply can we probe exo-earth's atmospheres during primary eclipse observations?

    Energy Technology Data Exchange (ETDEWEB)

    Bétrémieux, Yan [Max-Planck-Institut für Astronomie, Königstuhl 17, D-69117 Heidelberg (Germany); Kaltenegger, Lisa, E-mail: betremieux@mpia.de [Also at Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138, USA. (United States)

    2014-08-10

    Most models used to predict or fit exoplanet transmission spectra do not include all the effects of atmospheric refraction. Namely, the angular size of the star with respect to the planet can limit the lowest altitude, or highest density and pressure, probed during primary eclipses as no rays passing below this critical altitude can reach the observer. We discuss this geometrical effect of refraction for all exoplanets and tabulate the critical altitude, density, and pressure for an exoplanet identical to Earth with a 1 bar N{sub 2}/O{sub 2} atmosphere as a function of both the incident stellar flux (Venus, Earth, and Mars-like) at the top of the atmosphere and the spectral type (O5-M9) of the host star. We show that such a habitable exo-Earth can be probed to a surface pressure of 1 bar only around the coolest stars. We present 0.4-5.0 μm model transmission spectra of Earth's atmosphere viewed as a transiting exoplanet, and show how atmospheric refraction modifies the transmission spectrum depending on the spectral type of the host star. We demonstrate that refraction is another phenomenon that can potentially explain flat transmission spectra over some spectral regions.

  16. A unique airborne observation. [Martian atmospheric temperature and abundances from occultation of Epsilon Geminorum

    Science.gov (United States)

    Elliot, J. L.; Dunham, E.; Church, C.

    1976-01-01

    The occultation of 3rd magnitude Epsilon Geminorum by Mars was observed using a 36-inch telescope equipped with a photoelectric photometer at the bent Cassegrain focus, carried aboard the Kuiper Airborne Observatory at altitudes up to 45,000 feet. Scintillation from the earth's atmosphere was greatly reduced in comparison with ground observations. The observations clearly show the central flash, caused by the symmetrical refraction of light by the atmosphere of Mars. The data are being analyzed to obtain temperature profiles and to assess the relative abundance of argon and carbon dioxide in the atmosphere of the planet.

  17. Gridded sunshine duration climate data record for Germany based on combined satellite and in situ observations

    Science.gov (United States)

    Walawender, Jakub; Kothe, Steffen; Trentmann, Jörg; Pfeifroth, Uwe; Cremer, Roswitha

    2017-04-01

    The purpose of this study is to create a 1 km2 gridded daily sunshine duration data record for Germany covering the period from 1983 to 2015 (33 years) based on satellite estimates of direct normalised surface solar radiation and in situ sunshine duration observations using a geostatistical approach. The CM SAF SARAH direct normalized irradiance (DNI) satellite climate data record and in situ observations of sunshine duration from 121 weather stations operated by DWD are used as input datasets. The selected period of 33 years is associated with the availability of satellite data. The number of ground stations is limited to 121 as there are only time series with less than 10% of missing observations over the selected period included to keep the long-term consistency of the output sunshine duration data record. In the first step, DNI data record is used to derive sunshine hours by applying WMO threshold of 120 W/m2 (SDU = DNI ≥ 120 W/m2) and weighting of sunny slots to correct the sunshine length between two instantaneous image data due to cloud movement. In the second step, linear regression between SDU and in situ sunshine duration is calculated to adjust the satellite product to the ground observations and the output regression coefficients are applied to create a regression grid. In the last step regression residuals are interpolated with ordinary kriging and added to the regression grid. A comprehensive accuracy assessment of the gridded sunshine duration data record is performed by calculating prediction errors (cross-validation routine). "R" is used for data processing. A short analysis of the spatial distribution and temporal variability of sunshine duration over Germany based on the created dataset will be presented. The gridded sunshine duration data are useful for applications in various climate-related studies, agriculture and solar energy potential calculations.

  18. Atmospheric diurnal variations observed with GPS radio occultation soundings

    Directory of Open Access Journals (Sweden)

    F. Xie

    2010-07-01

    Full Text Available The diurnal variation, driven by solar forcing, is a fundamental mode in the Earth's weather and climate system. Radio occultation (RO measurements from the six COSMIC satellites (Constellation Observing System for Meteorology, Ionosphere and Climate provide nearly uniform global coverage with high vertical resolution, all-weather and diurnal sampling capability. This paper analyzes the diurnal variations of temperature and refractivity from three-year (2007–2009 COSMIC RO measurements in the troposphere and stratosphere between 30° S and 30° N. The RO observations reveal both propagating and trapped vertical structures of diurnal variations, including transition regions near the tropopause where data with high vertical resolution are critical. In the tropics the diurnal amplitude in refractivity shows the minimum around 14 km and increases to a local maximum around 32 km in the stratosphere. The upward propagating component of the migrating diurnal tides in the tropics is clearly captured by the GPS RO measurements, which show a downward progression in phase from stratopause to the upper troposphere with a vertical wavelength of about 25 km. At ~32 km the seasonal variation of the tidal amplitude maximizes at the opposite side of the equator relative to the solar forcing. The vertical structure of tidal amplitude shows strong seasonal variations and becomes asymmetric along the equator and tilted toward the summer hemisphere in the solstice months. Such asymmetry becomes less prominent in equinox months.

  19. STS-39 Earth observation of Earth's limb at sunset shows atmospheric layers

    Science.gov (United States)

    1991-01-01

    STS-39 Earth observation taken aboard Discovery, Orbiter Vehicle (OV) 103, shows the Earth's limb at sunset with numerous atmospheric scattering layers highlighted. The layers consist of fine particles suspended in very stable layers of the atmosphere. The layers act as a prism for the sunlight.

  20. Gulf of Maine Harmful Algal Bloom in summer 2005 - Part 1: In Situ Observations of Coastal Hydrography and Circulation

    OpenAIRE

    He, Ruoying; McGillicuddy, Dennis J.

    2008-01-01

    An extensive Alexandrium fundyense bloom occurred along the coast of the Gulf of Maine in late spring and early summer, 2005. To understand the physical aspects of bloom?s initiation and development, in-situ observations from both a gulf-wide ship survey and the coastal observing network were used to characterize coastal circulation and hydrography during that time period. Comparisons between these in-situ observations and their respective long term means revealed anomalous ocean conditions d...

  1. Remote Sensing of the Reconnection Electric Field From In Situ Multipoint Observations of the Separatrix Boundary

    Science.gov (United States)

    Nakamura, T. K. M.; Nakamura, R.; Varsani, A.; Genestreti, K. J.; Baumjohann, W.; Liu, Y.-H.

    2018-05-01

    A remote sensing technique to infer the local reconnection electric field based on in situ multipoint spacecraft observation at the reconnection separatrix is proposed. In this technique, the increment of the reconnected magnetic flux is estimated by integrating the in-plane magnetic field during the sequential observation of the separatrix boundary by multipoint measurements. We tested this technique by applying it to virtual observations in a two-dimensional fully kinetic particle-in-cell simulation of magnetic reconnection without a guide field and confirmed that the estimated reconnection electric field indeed agrees well with the exact value computed at the X-line. We then applied this technique to an event observed by the Magnetospheric Multiscale mission when crossing an energetic plasma sheet boundary layer during an intense substorm. The estimated reconnection electric field for this event is nearly 1 order of magnitude higher than a typical value of magnetotail reconnection.

  2. Deteriorating water clarity in shallow waters: Evidence from long term MODIS and in-situ observations

    Science.gov (United States)

    Shi, Kun; Zhang, Yunlin; Zhu, Guangwei; Qin, Boqiang; Pan, Delu

    2018-06-01

    Water clarity (Secchi disk depth: SDD), as a proxy of water transparency, provides important information on the light availability to the water or lake ecosystem. Shallow lakes have been experienced dramatic environmental and climatic change. This study demonstrated using combination of long-term MODIS and in-situ measurements to track the dynamics of SDD with these environmental and climate changes in shallow water environments. We selected a typical turbid shallow Lake Taihu as our case study. Based on MODIS-Aqua data, an empirical model for estimating SDD was developed and validated. Subsequently, we employed the proposed model to derive the spatial and temporal SDD distribution patterns of Lake Taihu from 2003 to 2015. Combining MODIS-derived SDD time series of 2003-2015 and long-term in-situ SDD observations dated back to 1993, we elucidated SDD long-term variation trends and driving mechanism. Deteriorating water clarity from the long-term SDD observations indicated that Lake Taihu became more and more turbid and water quality was decreasing. Increasing in cyanobacterial bloom area, as a result of decreasing in wind speed and eutrophication, may partially be responsible for the decreasing trend. A predicted future decrease in the wind speed in Lake Taihu region could enhance the formation of cyanobacterial blooms and consequently lead to a further decrease in water clarity. This study suggested that coupling remote sensing monitoring and long-term in-situ observations could provide robust evidence and new insights to elucidate long-term dynamics in aquatic ecosystem evolution.

  3. In situ TEM observation of microcrack nucleation and propagation in pure tin solder

    International Nuclear Information System (INIS)

    Ding Ying; Wang Chunqing; Li, Mingyu; Wang Weiqiang

    2006-01-01

    Microcrack nucleation and propagation behavior in pure tin solder was investigated by using transmission electron microscopy (TEM) through in situ tensile test. Observation results showed that fracture process was completed in this visco-plastic material by connecting discontinuous cracks or voids. Depending on remarkable vacancy diffusion ability, microvoids were nucleated and developed in the dislocation free zone (DFZ) or super thinned area ahead of crack tip under local high stress concentration. The cracks were linked with each other by mutual dislocation emission which expedites the propagation of crack tips effectively

  4. In-situ observation of atomic self-organization processes in Xe nanocrystals embedded in Al

    International Nuclear Information System (INIS)

    Mitsuishi, K.; Song, M.; Furuya, K.; Birtcher, R. C.; Allen, C. W.; Donnelly, S. E.

    1998-01-01

    Self-organization processes in Xe nanocrystals embedded in Al are observed with in-situ high-resolution electron microscopy. Under electron irradiation, stacking fault type defects are produced in Xe nanocrystals. The defects recover in a layer by layer manner. Detailed analysis of the video reveals that the displacement of Xe atoms in the stacking fault was rather small for the Xe atoms at boundary between Xe and Al, suggesting the possibility of the stacking fault in Xe precipitate originating inside of precipitate, not at the Al/Xe interface

  5. In-situ observation of crack propagation in thermally sprayed coatings

    Czech Academy of Sciences Publication Activity Database

    Mušálek, R.; Kovářík, O.; Matějíček, Jiří

    2010-01-01

    Roč. 205, č. 7 (2010), s. 1807-1811 ISSN 0257-8972 R&D Projects: GA MŠk ME 901 Institutional research plan: CEZ:AV0Z20430508 Keywords : coating fracture * in-situ observation * alumina * stainless steel * plasma spraying Subject RIV: JL - Materials Fatigue, Friction Mechanics Impact factor: 2.135, year: 2010 http://www.sciencedirect.com/science?_ob=GatewayURL&_method=citationSearch&_uoikey=B6TVV-4YTFBCY-5&_origin=SDEMFRHTML&_version=1&md5=896533bcc989ebaa374ff209558fbcf1

  6. Atmospheric gravity waves due to the Tohoku-Oki tsunami observed in the thermosphere by GOCE

    NARCIS (Netherlands)

    Garcia, R.F.; Doornbos, E.N.; Bruinsma, S.; Hebert, H.

    2014-01-01

    Oceanic tsunami waves couple with atmospheric gravity waves, as previously observed through ionospheric and airglow perturbations. Aerodynamic velocities and density variations are computed from Gravity Field and Steady-State Ocean Circulation Explorer (GOCE) accelerometer and thruster data during

  7. A century of ocean warming on Florida Keys coral reefs: historic in situ observations

    Science.gov (United States)

    Kuffner, Ilsa B.; Lidz, Barbara H.; Hudson, J. Harold; Anderson, Jeffery S.

    2015-01-01

    There is strong evidence that global climate change over the last several decades has caused shifts in species distributions, species extinctions, and alterations in the functioning of ecosystems. However, because of high variability on short (i.e., diurnal, seasonal, and annual) timescales as well as the recency of a comprehensive instrumental record, it is difficult to detect or provide evidence for long-term, site-specific trends in ocean temperature. Here we analyze five in situ datasets from Florida Keys coral reef habitats, including historic measurements taken by lighthouse keepers, to provide three independent lines of evidence supporting approximately 0.8 °C of warming in sea surface temperature (SST) over the last century. Results indicate that the warming observed in the records between 1878 and 2012 can be fully accounted for by the warming observed in recent decades (from 1975 to 2007), documented using in situ thermographs on a mid-shore patch reef. The magnitude of warming revealed here is similar to that found in other SST datasets from the region and to that observed in global mean surface temperature. The geologic context and significance of recent ocean warming to coral growth and population dynamics are discussed, as is the future prognosis for the Florida reef tract.

  8. EVIDENCE OF THE SOLAR EUV HOT CHANNEL AS A MAGNETIC FLUX ROPE FROM REMOTE-SENSING AND IN SITU OBSERVATIONS

    Energy Technology Data Exchange (ETDEWEB)

    SONG, H. Q.; CHEN, Y.; Wang, B. [Shandong Provincial Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment, and Institute of Space Sciences, Shandong University, Weihai, Shandong 264209 (China); ZHANG, J. [School of Physics, Astronomy and Computational Sciences, George Mason University, Fairfax, VA 22030 (United States); CHENG, X. [School of Astronomy and Space Science, Nanjing University, Nanjing, Jiangsu 210093 (China); HU, Q.; LI, G. [Department of Space Science and CSPAR, University of Alabama in Huntsville, Huntsville, AL 35899 (United States); WANG, Y. M., E-mail: hqsong@sdu.edu.cn [Key Laboratory of Geospace Environment, University of Science and Technology of China, Chinese Academy of Sciences (CAS), Hefei, Anhui 230026 (China)

    2015-07-20

    Hot channels (HCs), high-temperature erupting structures in the lower corona of the Sun, have been proposed as a proxy of magnetic flux ropes (MFRs) since their initial discovery. However, it is difficult to provide definitive proof given the fact that there is no direct measurement of the magnetic field in the corona. An alternative method is to use the magnetic field measurement in the solar wind from in situ instruments. On 2012 July 12, an HC was observed prior to and during a coronal mass ejection (CME) by the Atmospheric Imaging Assembly high-temperature images. The HC is invisible in the EUVI low-temperature images, which only show the cooler leading front (LF). However, both the LF and an ejecta can be observed in the coronagraphic images. These are consistent with the high temperature and high density of the HC and support that the ejecta is the erupted HC. Meanwhile, the associated CME shock was identified ahead of the ejecta and the sheath through the COR2 images, and the corresponding ICME was detected by the Advanced Composition Explorer, showing the shock, sheath, and magnetic cloud (MC) sequentially, which agrees with the coronagraphic observations. Further, the MC average Fe charge state is elevated, containing a relatively low-ionization-state center and a high-ionization-state shell, consistent with the preexisting HC observation and its growth through magnetic reconnection. All of these observations support that the MC detected near the Earth is the counterpart of the erupted HC in the corona for this event. The study provides strong observational evidence of the HC as an MFR.

  9. Evidence of the Solar EUV Hot Channel as a Magnetic Flux Rope from Remote-sensing and in situ Observations

    Science.gov (United States)

    Song, H.

    2015-12-01

    Hot channels (HCs), high-temperature erupting structures in the lower corona of the Sun, have been proposed as a proxy of magnetic flux ropes (MFRs) since their initial discovery. However, it is difficult to provide definitive proof given the fact that there is no direct measurement of the magnetic field in the corona. An alternative method is to use the magnetic field measurement in the solar wind from in situ instruments. On 2012 July 12, an HC was observed prior to and during a coronal mass ejection (CME) by the Atmospheric Imaging Assembly high-temperature images. The HC is invisible in the EUVI low-temperature images, which only show the cooler leading front (LF). However, both the LF and an ejecta can be observed in the coronagraphic images. These are consistent with the high temperature and high density of the HC and support that the ejecta is the erupted HC. Meanwhile, the associated CME shock was identified ahead of the ejecta and the sheath through the COR2 images, and the corresponding ICME was detected by the Advanced Composition Explorer, showing the shock, sheath, and magnetic cloud (MC) sequentially, which agrees with the coronagraphic observations. Further, the MC average Fe charge state is elevated, containing a relatively low-ionization-state center and a high-ionization-state shell, consistent with the preexisting HC observation and its growth through magnetic reconnection. All of these observations support that the MC detected near the Earth is the counterpart of the erupted HC in the corona for this event. The study provides strong observational evidence of the HC as an MFR.

  10. Atmospheric characterization through fused mobile airborne and surface in situ surveys: methane emissions quantification from a producing oil field

    Science.gov (United States)

    Leifer, Ira; Melton, Christopher; Fischer, Marc L.; Fladeland, Matthew; Frash, Jason; Gore, Warren; Iraci, Laura T.; Marrero, Josette E.; Ryoo, Ju-Mee; Tanaka, Tomoaki; Yates, Emma L.

    2018-03-01

    Methane (CH4) inventory uncertainties are large, requiring robust emission derivation approaches. We report on a fused airborne-surface data collection approach to derive emissions from an active oil field near Bakersfield, central California. The approach characterizes the atmosphere from the surface to above the planetary boundary layer (PBL) and combines downwind trace gas concentration anomaly (plume) above background with normal winds to derive flux. This approach does not require a well-mixed PBL; allows explicit, data-based, uncertainty evaluation; and was applied to complex topography and wind flows. In situ airborne (collected by AJAX - the Alpha Jet Atmospheric eXperiment) and mobile surface (collected by AMOG - the AutoMObile trace Gas - Surveyor) data were collected on 19 August 2015 to assess source strength. Data included an AMOG and AJAX intercomparison transect profiling from the San Joaquin Valley (SJV) floor into the Sierra Nevada (0.1-2.2 km altitude), validating a novel surface approach for atmospheric profiling by leveraging topography. The profile intercomparison found good agreement in multiple parameters for the overlapping altitude range from 500 to 1500 m for the upper 5 % of surface winds, which accounts for wind-impeding structures, i.e., terrain, trees, buildings, etc. Annualized emissions from the active oil fields were 31.3 ± 16 Gg methane and 2.4 ± 1.2 Tg carbon dioxide. Data showed the PBL was not well mixed at distances of 10-20 km downwind, highlighting the importance of the experimental design.

  11. Results from Joint Observations of Jupiter's Atmosphere by Juno and a Network of Earth-Based Observing Stations

    Science.gov (United States)

    Orton, G. S.; Bolton, S. J.; Levin, S.; Hansen, C. J.; Janssen, M. A.; Adriani, A.; Gladstone, R.; Bagenal, F.; Ingersoll, A. P.; Momary, T.; Payne, A.

    2016-12-01

    The Juno mission has promoted and coordinated a network of Earth-based observations, including both space- and ground-based facilities, to extend and enhance observations made by the Juno mission. The spectral region and timeline of all of these observations are summarized in the web site: https://www.missionjuno.swri.edu/planned-observations. Among the earliest of these were observation of Jovian auroral phenomena at X-ray, ultraviolet and infrared wavelengths and measurements of Jovian synchrotron radiation from the Earth simultaneously with the measurement of properties of the upstream solar wind described elsewhere in this meeting. Other observations of significance to the magnetosphere measured the mass loading from Io by tracking its observed volcanic activity and the opacity of its torus. Observations of Jupiter's neutral atmosphere included observations of reflected sunlight from the near-ultraviolet through the near-infrared and thermal emission from 5 microns through the radio region. The point of these measurements is to relate properties of the deep atmosphere that are the focus of Juno's mission to the state of the "weather layer" at much higher atmospheric levels. These observations cover spectral regions not included in Juno's instrumentation, provide spatial context for Juno's often spatially limited coverage of Jupiter, and they describe the evolution of atmospheric features in time that are measured only once by Juno. We will summarize the results of measurements during the approach phase of the mission that characterized the state of the atmosphere, as well as observations made by Juno and the supporting campaign during Juno's perijoves 1 (August 27), 2 (October 19), 3 (November 2), 4 (November 15), and 5 (November 30). The Juno mission also benefited from the enlistment of a network of dedicated amateur astronomers who, besides providing input needed for public operation of the JunoCam visible camera, tracked the evolution of features in Jupiter

  12. A simulation of the OMEGA/Mars Express observations: Analysis of the atmospheric contribution

    Science.gov (United States)

    Melchiorri, R.; Drossart, P.; Fouchet, T.; Bézard, B.; Forget, F.; Gendrin, A.; Bibring, J. P.; Manaud, N.; OMEGA Team; Berthé, M.; Bibring, J.-P.; Langevin, Y.; Forni, O.; Gendrin, A.; Gondet, B.; Manaud, N.; Poulet, F.; Poulleau, G.; Soufflot, A.; Mangold, N.; Bonello, G.; Forget, F.; Bezard, B.; Combes, M.; Drossart, P.; Encrenaz, T.; Fouchet, T.; Melchiorri, R.; Erard, S.; Bellucci, G.; Altieri, F.; Formisano, V.; Fonti, S.; Capaccioni, F.; Cerroni, P.; Coradini, A.; Kottsov, V.; Ignatiev, N.; Moroz, V.; Titov, D.; Zasova, L.; Pinet, P.; Schmitt, B.; Sotin, C.; Hauber, E.; Hoffmann, H.; Jaumann, R.; Keller, U.; Arvidson, R.; Mustard, J.; Duxbary, T.

    2006-08-01

    Spectral images of Mars obtained by the Mars Express/OMEGA experiment in the near infrared are the result of a complex combination of atmospheric, aerosol and ground features. Retrieving the atmospheric information from the data is important, not only to decorrelate mineralogical against atmospheric features, but also to retrieve the atmospheric variability. Once the illumination conditions have been taken into account, the main source of variation on the CO2 absorption is due to the altitude of the surface, which governs atmospheric pressure variation by more than an order of magnitude between the summit of Olympus Mons down to the bottom of Valles Marineris. In this article we present a simplified atmospheric spectral model without scattering, specially developed for the OMEGA observations, which is used to retrieve the local topography through the analysis of the 2.0μmCO2 band. OMEGA atmospheric observations increase the horizontal resolution compared to MOLA altimetry measurements, and therefore complement the mineralogical studies from the same instrument. Finally, residual variations of the pressure can be related to atmospheric structure variation.

  13. Paloma: In-situ Measurement of The Elemental and Isotopic Composition of The Mars Atmosphere

    Science.gov (United States)

    Chassefiere, E.; Jambon, A.; Berthelier, J.-J.; Correia, J.-J.; Covinhes, J.; Goulpeau, G.; Leblanc, F.; Malique, Ch.; Sarda, P.; Schaetzel, P.; Sabroux, J.-C.; Ferry, C.; Richon, P.; Pineau, J.-F.; Desjean, M.-C.

    The PALOMA instrument, presently under study in the frame of the NASA/CNES Mars exploration program, is devoted to the accurate measurement of isotopic and el- emental ratios in Mars atmosphere. It consists of a mass spectrometer coupled with a gas preparation line for separation of reactive and noble gas species, and noble gas species (and reactive gases) from each other, by chemical and cryogenic trapping, and possibly permeation techniques. This instrument, ranked among the most important four types of measurement recommended by the US Committee on Planetary and Lu- nar Exploration (COMPLEX), will be proposed as a part of the payload of the 07 NASA smart landers. The general objectives of PALOMA are to provide instanta- neous and time-varying patterns of noble gas isotopic spectra, and stable isotopes. Such measurements will allow to improve our general understanding of volatile cy- cles on Mars, and to better decipher the history of the atmosphere and climate. Past escape processes, exchanges between solid planet and atmosphere, post-accretional addition of volatil-rich matter from comets, are expected to have imprinted specific isotopic signatures. Although these signatures are strongly interlocked, a compara- tive Earth-Mars approach may allow to discriminate between them, and therefore to reconstruct the history of Martian volatiles. The evolution of atmospheric mass and composition may have had a major impact on climate evolution, e.g. through massive escape of carbon dioxide and water. In addition, precise measurements of isotopes in the present Mars atmosphere are the most promising way on the short term to confirm that SNC meteorites are from Martian origin. PALOMA also includes a small separate device for measuring ambient natural radioactivity, which might provide information about the presence of a near subsurface permafrost, possible residual volcanic activity, vertical mixing rate in the boundary layer.

  14. TAMOAS: In Situ Gasometry in the Atmosphere with Solid Electrolyte Sensors on BEXUS-19

    Science.gov (United States)

    Bronowski, A.; Clemens, R.; Jaster, T.; Kosel, F.; Matyash, I.; Westphal, A.

    2015-09-01

    A student experiment developed for testing gas sensors in the stratosphere is described. The setup consists of a measurement electronic running miniaturized in situ amperiometric gas sensors based on different solid state electrolytes dedicated for oxygen, ozone and atomic oxygen. The experiment took place at Esrange Space Center in October 2014. The setup was attached to the high-altitude balloon BEXUS-19 and reached an altitude of 27 km at night. The primary objective was to test the prototype sensors and to gain data during flight.

  15. Retrieval and analysis of atmospheric XCO2 using ground-based spectral observation.

    Science.gov (United States)

    Qin, Xiu-Chun; Lei, Li-Ping; Kawasaki, Masahiro; Masafumi, Ohashi; Takahiro, Kuroki; Zeng, Zhao-Cheng; Zhang, Bing

    2014-07-01

    Atmospheric CO2 column concentration (column-averaged dry air mole fractions of atmospheric carbon dioxide) data obtained by ground-based hyperspectral observation is an important source of data for the verification and improvement of the results of CO2 retrieval based on satellite hyperspectral observation. However, few studies have been conducted on atmospheric CO2 column concentration retrieval based on ground-based spectral hyperspectral observation in China. In the present study, we carried out the ground-based hyperspectral observation in Xilingol Grassland, Inner Mongolia of China by using an observation system which is consisted of an optical spectral analyzer, a sun tracker, and some other elements. The atmospheric CO2 column concentration was retrieved using the observed hyperspectral data. The effect of a wavelength shift of the observation spectra and the meteorological parameters on the retrieval precision of the atmospheric CO2 concentration was evaluated and analyzed. The results show that the mean value of atmospheric CO2 concentration was 390.9 microg x mL(-1) in the study area during the observing period from July to September. The shift of wavelength in the range between -0.012 and 0.042 nm will generally lead to 1 microg x mL(-1) deviation in the CO2 retrievals. This study also revealed that the spectral transmittance was sensitive to meteorological parameters in the wavelength range of 6 357-6 358, 6 360-6 361, and 6 363-6 364 cm(-1). By comparing the CO2 retrievals derived from the meteorological parameters observed in synchronous and non-synchronous time, respectively, with the spectral observation, it was showed that the concentration deviation caused by using the non-synchronously observed meteorological parameters is ranged from 0.11 to 4 microg x mL(-1). These results can be used as references for the further improvement of retrieving CO2 column concentration based on spectral observation.

  16. In situ observations from STEREO/PLASTIC: a test for L5 space weather monitors

    Directory of Open Access Journals (Sweden)

    K. D. C. Simunac

    2009-10-01

    Full Text Available Stream interaction regions (SIRs that corotate with the Sun (corotating interaction regions, or CIRs are known to cause recurrent geomagnetic storms. The Earth's L5 Lagrange point, separated from the Earth by 60 degrees in heliographic longitude, is a logical location for a solar wind monitor – nearly all SIRs/CIRs will be observed at L5 several days prior to their arrival at Earth. Because the Sun's heliographic equator is tilted about 7 degrees with respect to the ecliptic plane, the separation in heliographic latitude between L5 and Earth can be more than 5 degrees. In July 2008, during the period of minimal solar activity at the end of solar cycle 23, the two STEREO observatories were separated by about 60 degrees in longitude and more than 4 degrees in heliographic latitude. This time period affords a timely test for the practical application of a solar wind monitor at L5. We compare in situ observations from PLASTIC/AHEAD and PLASTIC/BEHIND, and report on how well the BEHIND data can be used as a forecasting tool for in situ conditions at the AHEAD spacecraft with the assumptions of ideal corotation and minimal source evolution. Preliminary results show the bulk proton parameters (density and bulk speed are not in quantitative agreement from one observatory to the next, but the qualitative profiles are similar.

  17. In situ observations from STEREO/PLASTIC: a test for L5 space weather monitors

    Directory of Open Access Journals (Sweden)

    K. D. C. Simunac

    2009-10-01

    Full Text Available Stream interaction regions (SIRs that corotate with the Sun (corotating interaction regions, or CIRs are known to cause recurrent geomagnetic storms. The Earth's L5 Lagrange point, separated from the Earth by 60 degrees in heliographic longitude, is a logical location for a solar wind monitor – nearly all SIRs/CIRs will be observed at L5 several days prior to their arrival at Earth. Because the Sun's heliographic equator is tilted about 7 degrees with respect to the ecliptic plane, the separation in heliographic latitude between L5 and Earth can be more than 5 degrees. In July 2008, during the period of minimal solar activity at the end of solar cycle 23, the two STEREO observatories were separated by about 60 degrees in longitude and more than 4 degrees in heliographic latitude. This time period affords a timely test for the practical application of a solar wind monitor at L5. We compare in situ observations from PLASTIC/AHEAD and PLASTIC/BEHIND, and report on how well the BEHIND data can be used as a forecasting tool for in situ conditions at the AHEAD spacecraft with the assumptions of ideal corotation and minimal source evolution. Preliminary results show the bulk proton parameters (density and bulk speed are not in quantitative agreement from one observatory to the next, but the qualitative profiles are similar.

  18. Remote sensing, hydrological modeling and in situ observations in snow cover research: A review

    Science.gov (United States)

    Dong, Chunyu

    2018-06-01

    Snow is an important component of the hydrological cycle. As a major part of the cryosphere, snow cover also represents a valuable terrestrial water resource. In the context of climate change, the dynamics of snow cover play a crucial role in rebalancing the global energy and water budgets. Remote sensing, hydrological modeling and in situ observations are three techniques frequently utilized for snow cover investigations. However, the uncertainties caused by systematic errors, scale gaps, and complicated snow physics, among other factors, limit the usability of these three approaches in snow studies. In this paper, an overview of the advantages, limitations and recent progress of the three methods is presented, and more effective ways to estimate snow cover properties are evaluated. The possibility of improving remotely sensed snow information using ground-based observations is discussed. As a rapidly growing source of volunteered geographic information (VGI), web-based geotagged photos have great potential to provide ground truth data for remotely sensed products and hydrological models and thus contribute to procedures for cloud removal, correction, validation, forcing and assimilation. Finally, this review proposes a synergistic framework for the future of snow cover research. This framework highlights the cross-scale integration of in situ and remotely sensed snow measurements and the assimilation of improved remote sensing data into hydrological models.

  19. In Situ Observation of the Dislocation Structure Evolution During a Strain Path Change in Copper

    DEFF Research Database (Denmark)

    Wejdemann, Christian; Poulsen, Henning Friis; Lienert, Ulrich

    2013-01-01

    The evolution of deformation structures in individual grains embedded in polycrystalline copper specimens during strain path changes is observed in situ by high-resolution reciprocal space mapping with high-energy synchrotron radiation. A large number of individual subgrains is resolved; their be......The evolution of deformation structures in individual grains embedded in polycrystalline copper specimens during strain path changes is observed in situ by high-resolution reciprocal space mapping with high-energy synchrotron radiation. A large number of individual subgrains is resolved...... and orientation of the resolved subgrains change only slightly, while their elastic stresses are significantly altered. This indicates the existence of a microplastic regime during which only the subgrains deform plastically and no yielding of the dislocation walls occurs. After reloading above 0.3% strain......, the elastic stresses of individual subgrains are about the same as in unidirectionally deformed reference specimens. They increase only slightly during further straining—accompanied by occasional emergence of new subgrains, abundant orientation changes, and disappearance of existing subgrains....

  20. In-situ observations of Eyjafjallajökull ash particles by hot-air balloon

    Science.gov (United States)

    Petäjä, T.; Laakso, L.; Grönholm, T.; Launiainen, S.; Evele-Peltoniemi, I.; Virkkula, A.; Leskinen, A.; Backman, J.; Manninen, H. E.; Sipilä, M.; Haapanala, S.; Hämeri, K.; Vanhala, E.; Tuomi, T.; Paatero, J.; Aurela, M.; Hakola, H.; Makkonen, U.; Hellén, H.; Hillamo, R.; Vira, J.; Prank, M.; Sofiev, M.; Siitari-Kauppi, M.; Laaksonen, A.; lehtinen, K. E. J.; Kulmala, M.; Viisanen, Y.; Kerminen, V.-M.

    2012-03-01

    The volcanic ash cloud from Eyjafjallajökull volcanic eruption seriously distracted aviation in Europe. Due to the flight ban, there were only few in-situ measurements of the properties and dispersion of the ash cloud. In this study we show in-situ observations onboard a hot air balloon conducted in Central Finland together with regional dispersion modelling with SILAM-model during the eruption. The modeled and measured mass concentrations were in a qualitative agreement but the exact elevation of the layer was slightly distorted. Some of this discrepancy can be attributed to the uncertainty in the initial emission height and strength. The observed maximum mass concentration varied between 12 and 18 μg m -3 assuming a density of 2 g m -3, whereas the gravimetric analysis of the integrated column showed a maximum of 45 μg m -3 during the first two descents through the ash plume. Ion chromatography data indicated that a large fraction of the mass was insoluble to water, which is in qualitative agreement with single particle X-ray analysis. A majority of the super-micron particles contained Si, Al, Fe, K, Na, Ca, Ti, S, Zn and Cr, which are indicative for basalt-type rock material. The number concentration profiles indicated that there was secondary production of particles possibly from volcano-emitted sulfur dioxide oxidized to sulfuric acid during the transport.

  1. Long-Term Water Temperature Variations in Daya Bay, China Using Satellite and In Situ Observations

    Directory of Open Access Journals (Sweden)

    Jing Yu

    2010-01-01

    Full Text Available Daya Bay is a shallow, semi-en closed bay in the northern section of the South China Sea. The present study analyzed variations of water temperature in Daya Bay over the past 21 years (1985 - 2005 using Advanced Very High Resolution Radiometer (AVHRR satellite remote sensing data and in situ observations. Results showed that AVHRR readings of sea surface temperature (SST increased by 0.07°C y-1. Linear regression anal y sis for monthly SST anomalies (SSTA showed a shift from negative to positive from 1995 - 1996, when the Daya Bay nuclear power station commenced operations in 1994. The slope of linear regression analysis for SSTA nearly doubled from 0.05 (1985 - 1993 to 0.09 (1994 - 2005. Monthly AVHRR images showed a thermal plume from the power station and revealed the in crease of SST over 21 years. In situ observations in water temperature also showed an in creasing trend for the same period (1985 - 2005. Variations in water temperature in Daya Bay were connected with climatic perturbations and in creasing human activity including thermal discharge from nuclear power stations and the rapid economic development around the bay area.

  2. In-situ TEM observation of nano-void formation in UO2 under irradiation

    Science.gov (United States)

    Sabathier, C.; Martin, G.; Michel, A.; Carlot, G.; Maillard, S.; Bachelet, C.; Fortuna, F.; Kaitasov, O.; Oliviero, E.; Garcia, P.

    2014-05-01

    Transmission electron microscopy (TEM) observations of UO2 polycrystals irradiated in situ with 4 MeV Au ions were performed at room temperature (RT) to better understand the mechanisms of cavity and ultimately fission products nucleation in UO2. Experiments were carried out at the JANNuS Orsay facility that enables in situ ion irradiations inside the microscope to be carried out. The majority of 4 MeV gold ions were transmitted through the thin foil, and the induced radiation defects were investigated by TEM. Observations showed that nano-void formation occurs at ambient temperature in UO2 thin foils irradiated with energetic heavy ions under an essentially nuclear energy loss regime. The diameter and density of nano-objects were measured as a function of the gold irradiation dose at RT. A previous paper has also revealed a similar nano-object population after a Xe implantation performed at 390 keV at 870 K. The nano-object density was modelled using simple concepts derived from Classical Molecular Dynamics simulations. The results are in good agreement, which suggests a mechanism of heterogeneous nucleation induced by energetic cascade overlaps. This indicates that nano-void formation mechanism is controlled by radiation damage. Such nanovoids are likely to act as sinks for mobile fission products during reactor operation.

  3. Ex-situ and in-situ observations of the effects of gamma radiation on lithium ion battery performance

    Science.gov (United States)

    Tan, Chuting; Bashian, Nicholas H.; Hemmelgarn, Chase W.; Thio, Wesley J.; Lyons, Daniel J.; Zheng, Yuan F.; Cao, Lei R.; Co, Anne C.

    2017-07-01

    Radiation effects induced by gamma rays on battery performance were investigated by measuring the capacity and resistance of a series of battery coin cells in-situ directly under gamma radiation and ex-situ. An experimental setup was developed to charge and discharge batteries directly under gamma radiation, equipped with precise temperature control, at The Ohio State University Nuclear Reactor Lab. Latent effects induced by gamma radiation on battery components directly influence their performance. Charge and discharge capacity and overall resistance throughout a time span of several weeks post irradiation were monitored and compared to control groups. It was found that exposure to gamma radiation does not significantly alter the available capacity and the overall cell resistance immediately, however, battery performance significantly decreases with time post irradiation. Also, batteries exposed to a higher cumulative dose showed close-to-zero capacity at two-week post irradiation.

  4. ALMA Long Baseline Observations of the Dynamical Atmospheres of AGB Stars

    Science.gov (United States)

    Vlemmings, Wouter

    2018-04-01

    I will present the current status of ALMA long baseline observations of W Hya, R Leo, R Dor and Mira. We have recently obtained band 4, 6 and 7 observations of the line and continuum emission tracing the temperature and dynamics in their extended atmosphere. Our preliminary analysis confirms our previous detection of a hotspot on W Hya, and reveals unexpected lines in most of the sources, as well as possible fast rotation in the atmopshere of one of the stars. The observations show the unique power of ALMA in observing the extended stellar atmospheres.

  5. Atmosphere influence on in situ ion beam analysis of thin film growth

    International Nuclear Information System (INIS)

    Lin, Yuping; Krauss, A.R.; Gruen, D.M.; Chang, R.P.H.; Auciello, O.H.; Schultz, J.A.

    1994-01-01

    In situ, nondestructive surface characterization of thin-film growth processes in an environment of chemically active gas at pressures of several mTorr is required both for the understanding of growth processes in multicomponent films and layered heterostructures and for the improvement of process reproducibility and device reliability. The authors have developed a differentially pumped pulsed ion beam surface analysis system that includes ion scattering spectroscopy (ISS) and direct recoil spectroscopy (DRS), coupled to an automated ion beam sputter-deposition system (IBSD), to study film growth processes in an environment of chemically active gas, such as required for the growth of oxide, nitride, or diamond thin films. The influence of gas-phase scattering and gas-surface interactions on the ISS and DRS signal intensity and peak shape have been studied. From the intensity variation as a function of ambient gas pressure, the authors have calculated the mean free path and the scattering cross-section for a given combination of primary ion species and ambient gas. Depending on the system geometry and the combination of primary beam and background, it is shown that surface-specific data can be obtained during thin-film growth at pressures ranging from a few mtorr to approximately 1 Torr. Detailed information such as surface composition, structure, and film growth mechanism may be obtained in real-time, making ion beam analysis an ideal nondestructive, in situ probe of thin-film growth processes

  6. In situ EELS and TEM observation of Al implanted with nitrogen ions

    International Nuclear Information System (INIS)

    Hojou, K.; Furuno, S.; Kushita, K.N.; Otsu, H.; Izui, K.

    1995-01-01

    Formation processes of Aluminum nitride (AIN) in Aluminum (AI) implanted with nitrogen were examined by in situ EELS and TEM observations during nitrogen ion implantation in an electron microscope at room temperature and 400 deg C. AIN phase was identified both by EDP and EELS after nitrogen ion implantation to 6 x 10 20 (N + )/m 2 . The observed peak (20.8 eV) in EELS spectra was identified as plasmon loss peak of AIN formed in AI. The binding energy of N ls in AI was found to shift by about 4 eV to the lower side with increasing nitrogen-ion fluence. Unreacted AI was also found to remain in the AIN films after high fluence implantation both at room temperature and 400 deg C. (authors). 11 refs., 5 figs., 2 tabs

  7. In situ TEM observations of reverse dislocation motion upon unloading in tensile-deformed UFG aluminium

    International Nuclear Information System (INIS)

    Mompiou, Frédéric; Caillard, Daniel; Legros, Marc; Mughrabi, Haël

    2012-01-01

    Loading–unloading cycles have been performed on ultrafine-grained (UFG) aluminium inside a transmission electron microscope (TEM). The interaction of dislocations with grain boundaries, which is supposed to be at the origin of the inelastic behaviour of this class of materials, differs according to the main character of the dislocation segments involved in pile-ups. Pile-ups are formed by spiral sources and lead to the incorporation of dislocations into grain boundaries (GBs) during loading. Upon unloading, partial re-emission of dislocations from GBs can be observed. Stress and strain measurements performed during these in situ TEM loading–unloading experiments are in agreement with the rather large inelastic reverse strains observed during unloading in loading–unloading tests on bulk macroscopic UFG aluminium specimens.

  8. In situ observation of Ag-Cu-Ti liquid alloy/solid oxide interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Durov, O.V. [Frantsevich Institute for Problems of Materials Science of NASU, 3 Krzhyzhanovsky Street, Kiev 142, 03680 (Ukraine)], E-mail: avdu@ukr.net; Krasovskyy, V.P. [Frantsevich Institute for Problems of Materials Science of NASU, 3 Krzhyzhanovsky Street, Kiev 142, 03680 (Ukraine)

    2008-11-15

    In situ investigation methods are a very interesting means for understanding high-temperature interface processes. A method of direct observation of the interactions between transparent materials (Al{sub 2}O{sub 3}, SiO{sub 2}, CaF{sub 2}) and metal melts was elaborated. For the Ag-36.65 at.%Cu-8.15 at.%Ti/sapphire system, the formation of a dark compound at the interface was observed to occur at high temperature. This result does not confirm the conclusion of a neutron spectroscopy study which indicated that titanium oxides form at the interface only during solidification of the alloy. Interactions of the same alloy with SiO{sub 2} and CaF{sub 2} were also considered.

  9. Data Quality Assessment of In Situ and Altimeter Observations Through Two-Way Intercomparison Methods

    Science.gov (United States)

    Guinehut, Stephanie; Valladeau, Guillaume; Legeais, Jean-Francois; Rio, Marie-Helene; Ablain, Michael; Larnicol, Gilles

    2013-09-01

    This proceeding presents an overview of the two-way inter-comparison activities performed at CLS for both space and in situ observation agencies and why this activity is a required step to obtain accurate and homogenous data sets that can then be used together for climate studies or in assimilation/validation tools. We first describe the work performed in the frame of the SALP program to assess the stability of altimeter missions through SSH comparisons with tide gauges (GLOSS/CLIVAR network). Then, we show how the SSH comparison between the Argo array and altimeter time series allows the detection of drifts or jumps in altimeter (SALP program) but also for some Argo floats (Ifremer/Coriolis center). Lastly, we describe how the combine use of altimeter and wind observations helps the detection of drogue loss of surface drifting buoys (GDP network) and allow the computation of a correction term for wind slippage.

  10. In situ observation of structural change of nanostructured tungsten during annealing

    International Nuclear Information System (INIS)

    Yajima, Miyuki; Yoshida, Naoaki; Kajita, Shin; Tokitani, Masayuki; Baba, Tomotsugu; Ohno, Noriyasu

    2014-01-01

    Deformation of fiberform nanostructure and the dynamic behavior of helium (He) bubbles in fuzz tungsten (W) during annealing have been investigated by means of in situ cross-section observation using transmission electron microscopy and He desorption rate observation using thermal desorption spectroscopy (TDS). Thermal recovery of the nanostructure, such as shrinkage and coalescence of fine structure, annihilation of He bubbles, and large desorption of He gas, occurred around 1073–1173 K. The activation energy of He was estimated from a TDS peak that appeared around 300–400 K by using the Kissinger–Akahira–Sunose model-free-kinetics method. In addition, the TDS results of fiberform nanostructured tungsten were compared with those of tungsten samples irradiated with a high-energy He ion beam

  11. In situ observation of the role of alumina particles on the crystallization behavior of slags

    Energy Technology Data Exchange (ETDEWEB)

    Orrling, C.

    2000-09-01

    The confocal laser scanning microscope (CLSM) allows crystallization behavior in liquid slags to he observed in situ at high temperatures. Slags in the lime-silica-alumina-magnesia system are easily tinder cooled and it is possible to construct time temperature transformation (TTT) diagrams for this system. The presence of solid alumina particles its these liquid slags was studied to determine if these particles act as heterogeneous nucleation sites that cause she precipitation of solid material within slags. The introduction of alumina particles reduced the incubation time for the onset of crystallization and increased the temperature at which crystallization was observed in the slags to close to the liquidus temperature for the slag. Crystal growth rates are in a good agreement with Ivantsov's solution of the problem of diffusion controlled dendritic growth. Alumina appears to be a potent nucleating agent in the slag systems that were studied. (author)

  12. Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

    Science.gov (United States)

    Yanxu Zhang,; Daniel J. Jacob,; Hannah M. Horowitz,; Long Chen,; Helen M. Amos,; Krabbenhoft, David P.; Franz Slemr,; Vincent L. St. Louis,; Elsie M. Sunderland,

    2015-01-01

    Observations of elemental mercury (Hg0) at sites in North America and Europe show large decreases (∼1–2% y−1) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg0 concentrations and in HgII wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO2 and NOx emission controls on coal-fired utilities.

  13. Mars Atmospheric In Situ Resource Utilization Projects at the Kennedy Space Center

    Science.gov (United States)

    Muscatello, A. C.; Hintze, P. E.; Caraccio, A. J.; Bayliss, J. A.; Karr, L. J.; Paley, M. S.; Marone, M. J.; Gibson, T. L.; Surma, J. M.; Mansell, J. M.; hide

    2016-01-01

    The atmosphere of Mars, which is approximately 95% carbon dioxide (CO2), is a rich resource for the human exploration of the red planet, primarily by the production of rocket propellants and oxygen for life support. Three recent projects led by NASA's Kennedy Space Center have been investigating the processing of CO2. The first project successfully demonstrated the Mars Atmospheric Processing Module (APM), which freezes CO2 with cryocoolers and combines sublimated CO2 with hydrogen to make methane and water. The second project absorbs CO2 with Ionic Liquids and electrolyzes it with water to make methane and oxygen, but with limited success so far. A third project plans to recover up to 100% of the oxygen in spacecraft respiratory CO2. A combination of the Reverse Water Gas Shift reaction and the Boudouard reaction eventually fill the reactor up with carbon, stopping the process. A system to continuously remove and collect carbon is under construction.

  14. Mars Atmospheric In Situ Resource Utilization Projects at the Kennedy Space Center

    Science.gov (United States)

    Muscatello, Anthony; Hintze, Paul; Meier, Anne; Bayliss, Jon; Karr, Laurel; Paley, Steve; Marone, Matt; Gibson, Tracy; Surma, Jan; Mansell, Matt; hide

    2016-01-01

    The atmosphere of Mars, which is 96 percent carbon dioxide (CO2), is a rich resource for the human exploration of the red planet, primarily by the production of rocket propellants and oxygen for life support. Three recent projects led by NASAs Kennedy Space Center have been investigating the processing of CO2. The first project successfully demonstrated the Mars Atmospheric Processing Module (APM), which freezes CO2 with cryocoolers and combines sublimated CO2 with hydrogen to make methane and water. The second project absorbs CO2 with Ionic Liquids and electrolyzes it with water to make methane and oxygen, but with limited success so far. A third project plans to recover up to 100 of the oxygen in spacecraft respiratory CO2. A combination of the Reverse Water Gas Shift reaction and the Boudouard reaction eventually fill the reactor up with carbon, stopping the process. A system to continuously remove and collect carbon has been tested with encouraging results.

  15. Deep and surface circulation in the Northwest Indian Ocean from Argo, surface drifter, and in situ profiling current observations

    Science.gov (United States)

    Stryker, S. A.; Dimarco, S. F.; Stoessel, M. M.; Wang, Z.

    2010-12-01

    The northwest Indian Ocean is a region of complex circulation and atmospheric influence. The Persian (Arabian) Gulf and Red Sea contribute toward the complexity of the region. This study encompasses the surface and deep circulation in the region ranging from 0°N-35°N and 40°E-80°E from January 2002-December 2009. Emphasis is in the Persian Gulf, Oman Sea and Arabian Sea (roughly from 21°N-26°N and 56°E-63°E) using a variety of in situ and observation data sets. While there is a lot known about the Persian Gulf and Arabian Sea, little is known about the Oman Sea. Circulation in the northwest Indian Ocean is largely influenced by seasonal monsoon winds. From the winter monsoon to the summer monsoon, current direction reverses. Marginal sea inflow and outflow are also seasonally variable, which greatly impacts the physical water mass properties in the region. In situ and observation data sets include data from Argo floats (US GODAE), surface drifters (AOML) and an observation system consisting of 4 independent moorings and a cabled ocean observatory in the Oman Sea. The observing system in the Oman Sea was installed by Lighthouse R & D Enterprises, Inc. beginning in 2005, and measures current, temperature, conductivity, pressure, dissolved oxygen and turbidity, using the Aanderaa Recording Doppler Current Profiler (RDCP) 600 and the Aanderaa Recording Current Meter (RCM) 11. The cabled ocean observatory measures dissolved oxygen, temperature and salinity between 65 m and 1000 m and reports in real-time. Argo floats in the region have a parking depth range from 500 m to 2000 m. At 1000 m depth, 98% of the velocity magnitudes range from less than 1 cm/s to 20 cm/s. The Somali Current and Northeast/Southwest Monsoon Currents are present, reversing from summer to winter. At 2000 m depth, the Somali and Monsoon Currents are still present but have smaller velocities with 98% ranging from less than 1 cm/s to 13 cm/s. At both 1000 m and 2000 m, larger velocities occur

  16. Seasonal variability of the Red Sea, from satellite gravity, radar altimetry, and in situ observations

    Science.gov (United States)

    Wahr, John; Smeed, David A.; Leuliette, Eric; Swenson, Sean

    2014-08-01

    Seasonal variations of sea surface height (SSH) and mass within the Red Sea are caused mostly by exchange of heat with the atmosphere and by flow through the strait opening into the Gulf of Aden to the south. That flow involves a net mass transfer into the Red Sea during fall and out during spring, though in summer there is an influx of cool water at intermediate depths. Thus, summer water in the south is warmer near the surface due to higher air temperatures, but cooler at intermediate depths. Summer water in the north experiences warming by air-sea exchange only. The temperature affects water density, which impacts SSH but has no effect on mass. We study this seasonal cycle by combining GRACE mass estimates, altimeter SSH measurements, and steric contributions derived from the World Ocean Atlas temperature climatology. Among our conclusions are: mass contributions are much larger than steric contributions; the mass is largest in winter, consistent with winds pushing water into the Red Sea in fall and out during spring; the steric signal is largest in summer, consistent with surface warming; and the cool, intermediate-depth water flowing into the Red Sea in spring has little impact on the steric signal, because contributions from the lowered temperature are offset by effects of decreased salinity. The results suggest that the combined use of altimeter and GRACE measurements can provide a useful alternative to in situ data for monitoring the steric signal.

  17. Evaluating the Capacity of Global CO2 Flux and Atmospheric Transport Models to Incorporate New Satellite Observations

    Science.gov (United States)

    Kawa, S. R.; Collatz, G. J.; Erickson, D. J.; Denning, A. S.; Wofsy, S. C.; Andrews, A. E.

    2007-01-01

    As we enter the new era of satellite remote sensing for CO2 and other carbon cyclerelated quantities, advanced modeling and analysis capabilities are required to fully capitalize on the new observations. Model estimates of CO2 surface flux and atmospheric transport are required for initial constraints on inverse analyses, to connect atmospheric observations to the location of surface sources and sinks, and ultimately for future projections of carbon-climate interactions. For application to current, planned, and future remotely sensed CO2 data, it is desirable that these models are accurate and unbiased at time scales from less than daily to multi-annual and at spatial scales from several kilometers or finer to global. Here we focus on simulated CO2 fluxes from terrestrial vegetation and atmospheric transport mutually constrained by analyzed meteorological fields from the Goddard Modeling and Assimilation Office for the period 1998 through 2006. Use of assimilated meteorological data enables direct model comparison to observations across a wide range of scales of variability. The biospheric fluxes are produced by the CASA model at lxi degrees on a monthly mean basis, modulated hourly with analyzed temperature and sunlight. Both physiological and biomass burning fluxes are derived using satellite observations of vegetation, burned area (as in GFED-2), and analyzed meteorology. For the purposes of comparison to CO2 data, fossil fuel and ocean fluxes are also included in the transport simulations. In this presentation we evaluate the model's ability to simulate CO2 flux and mixing ratio variability in comparison to in situ observations at sites in Northern mid latitudes and the continental tropics. The influence of key process representations is inferred. We find that the model can resolve much of the hourly to synoptic variability in the observations, although there are limits imposed by vertical resolution of boundary layer processes. The seasonal cycle and its

  18. SEALEX in-situ experiments-performance tests of repository seals: experimental observations and modelling

    Directory of Open Access Journals (Sweden)

    Mokni Nadia

    2016-01-01

    Full Text Available The paper describes observations and numerical analysis of SEALEX performance tests installed in Tournemire Underground Research Laboratory (URL. One of the objectives of the large scale in-situ tests is to investigate the impact of technological gaps on the long term performance of bentonite based seals. The swelling cores consist of pre-compacted blocks of a natural sodic Wyoming bentonite (MX80 type mixed with quartz sand in a ratio of 70/30 (in dry mass with different geometries (monolithic disks or four jointed disks. Several technological gaps exist within the in situ tests: Gaps between the blocks and annular gap with variable width between the bentonite-based core and the host rock. All the tests are extensively instrumented for monitoring the main Hydro-Mechanical (HM variables. Comparison of the experimental results showed that the presence of technological gaps constituted new hydration sources (annular gaps and flow paths (gaps between the blocks that changed the saturation kinetics. A coupled HM formulation that incorporates the relevant processes involved in the problem under consideration has been adopted to analyse the effect of the annular technological gap on dry density homogenization of the bentonite based core as hydration progresses. Technological gaps were demonstrated to have an impact on dry density distribution.

  19. In-situ observation of the energy dependence of defect production in Cu and Ni

    International Nuclear Information System (INIS)

    King, W.E.; Merkel, K.L.; Baily, A.C.; Haga, K.; Meshii, M.

    1983-01-01

    The damage function, the average number of Frenkel pairs created as a function of lattice atom recoil energy, was investigated in Cu and Ni using in-situ electrical-resistivity damage-rate measurements in the high-voltage electron micrscope (HVEM) at T < 10K. Electron and proton irradiations were performed in-situ on the same polycrystalline specimens using the Argonne National Laboratory HVEM-Ion Beam Interface. Both Ni and Cu exhibit a sharp rise in the damage function above the minimum threshold energy (approx. 18 eV for Cu and approx. 20 eV for Ni) as displacements in the low-threshold energy regions of the threshold energy surface become possible. A plateau is observed for both materials (0.54 Frenkel pairs for Cu and 0.46 Frenkel pairs for Ni) indicating that no further directions become productive until much higher recoil energies. These damage functions show strong deviations from simple theoretical models, such as the Modified Kinchin-Pease damage function. The results are discussed in terms of the mechanisms of defect production that govern the single-displacement regime of the damage function and are compared with results from recent molecular-dynamics simulations

  20. Structure observation of single solidified droplet by in situ controllable quenching based on nanocalorimetry

    International Nuclear Information System (INIS)

    Zhao, Bingge; Li, Linfang; Yang, Bin; Yan, Ming; Zhai, Qijie; Gao, Yulai

    2013-01-01

    Highlights: •Controllable quenching rate up to 15,000 K/s was realized by FSC. •FSC sample was novelly characterized by FIB and HRTEM. •Solidification structure with undercooling of 110.9 K was investigated. •This study opens a new approach in rapid solidification and FSC measurement. -- Abstract: Fast scanning calorimetry (FSC) based on nanocalorimetry and thin film technique is a newly developed attractive tool to investigate the solidification behavior of single droplet by in situ controllable ultrafast cooling. In this paper, we introduced this novel technique to in situ control the quenching of single Sn3.5Ag metallic droplet at cooling rate up to 15,000 K/s with corresponding undercooling of 110.9 K. In particular, the solidification structure of this real time quenched single droplet was observed and analyzed with focused ion beam (FIB), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). This research proposed a new approach to research the solidification structure of single droplet with precisely controlled size and extreme cooling rate

  1. Deriving an atmospheric budget of total organic bromine using airborne in-situ measurements of brominated hydrocarbons in the Western Pacific during SHIVA

    Science.gov (United States)

    Sala, Stephan; Bönisch, Harald; Keber, Timo; Oram, Dave; Mills, Graham; Engel, Andreas

    2014-05-01

    Halogenated hydrocarbons play a major role as precursors for stratospheric ozone depletion. Released from the surface in the troposphere, the halocarbons reach the stratosphere via transport through the tropical tropopause layer. The contribution of the so called very short lived species (VSLS), having atmospheric lifetimes of less than half a year as sources gases for stratospheric bromine is significant. Source gas observations of long-lived bromine compounds and VSLS have so far not been able to explain the amount of bromine derived in the stratosphere from observations of BrO and modeling of the ratio of BrO to total bromine. Due to the short lifetimes and the high atmospheric variability, the representativeness of the available observations of VSLS source gases remains unclear, as these may vary with region and display seasonal variability. During the SHIVA (Stratospheric Ozone: Halogen Impacts in a Varying Atmosphere) project an extensive dataset with over 700 samples of ambient air of all halogen species relevant for the atmospheric budget of total organic bromine (long lived halocarbons: H-1301, H-1211, H-1202, H-2402 and CH3Br, very short lived substances: CHBr3, CH2Br2, CHBr2Cl, CHBrCl2 and CHBrCl) have been collected from onboard the FALCON aircraft in the West Pacific region. Measurements were performed with the newly developed fully-automated in-situ instrument GHOST-MS (Gas chromatograph for the Observation of Tracers - coupled with a Mass Spectrometer) by the Goethe University of Frankfurt and with the onboard whole-air sampler WASP with subsequent ground based state-of-the-art GC/MS analysis by the University of East Anglia. We will present the datasets, compare these to other observation, derive a bromine budget for the West Pacific and derive an estimate of the amount of bromine from VSLS reaching the stratosphere. Using the mean mixing ratios in the upper troposphere of the halocarbons mentioned above, the calculated budget of the total organic

  2. Real time, in situ observation of the photocatalytic inactivation of Saccharomyces cerevisiae cells

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Jingtao [School of Food and Bioengineering, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Environment Functional Materials Division, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Wang, Xiaoxin [Environment Functional Materials Division, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Li, Qi, E-mail: qili@imr.ac.cn [Environment Functional Materials Division, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Shang, Jian Ku [Environment Functional Materials Division, Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, Urbana, IL 61801 (United States)

    2015-04-01

    An in situ microscopy technique was developed to observe in real time the photocatalytic inactivation process of Saccharomyces cerevisiae (S. cerevisiae) cells by palladium-modified nitrogen-doped titanium oxide (TiON/PdO) under visible light illumination. The technique was based on building a photocatalytic micro-reactor on the sample stage of a fluorescence/phase contrast microscopy capable of simultaneously providing the optical excitation to activate the photocatalyst in the micro-reactor and the illumination to acquire phase contrast images of the cells undergoing the photocatalytic inactivation process. Using TiON/PdO as an example, the technique revealed for the first time the vacuolar activities inside S. cerevisiae cells subjected to a visible light photocatalytic inactivation. The vacuoles responded to the photocatalytic attack by the first expansion of the vacuolar volume and then contraction, before the vacuole disappeared and the cell structure collapsed. Consistent with the aggregate behavior observed from the cell culture experiments, the transition in the vacuolar volume provided clear evidence that photocatalytic disinfection of S. cerevisiae cells started with an initiation period in which cells struggled to offset the photocatalytic damage and moved rapidly after the photocatalytic damage overwhelmed the defense mechanisms of the cells against oxidative attack. - Highlights: • Palladium-modified nitrogen-doped titanium oxidephotocatalyst (TiON/PdO) • Effective visible-light photocatalytic disinfection of yeast cells by TiON/PdO • Real time, in situ observation technique was developed for photocatalytic disinfection. • The fluorescence/phase contrast microscope with a photocatalytic micro-reactor • Yeast cell disinfection happened before the cell structure collapsed.

  3. PREDICTION OF GEOMAGNETIC STORM STRENGTH FROM INNER HELIOSPHERIC IN SITU OBSERVATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Kubicka, M.; Möstl, C.; Amerstorfer, T.; Boakes, P. D.; Törmänen, O. [Space Research Institute, Austrian Academy of Sciences, 8042 Graz (Austria); Feng, L. [Purple Mountain Observatory, Chinese Academy of Sciences, West Beijing Road 2 Nanjing, 210008 (China); Eastwood, J. P., E-mail: christian.moestl@oeaw.ac.at [Space and Atmospheric Physics, The Blackett Laboratory, Imperial College London, London SW7 2AZ (United Kingdom)

    2016-12-20

    Prediction of the effects of coronal mass ejections (CMEs) on Earth strongly depends on knowledge of the interplanetary magnetic field southward component, B{sub z}. Predicting the strength and duration of B{sub z} inside a CME with sufficient accuracy is currently impossible, forming the so-called B{sub z} problem. Here, we provide a proof-of-concept of a new method for predicting the CME arrival time, speed, B{sub z}, and resulting disturbance storm time ( Dst ) index on Earth based only on magnetic field data, measured in situ in the inner heliosphere (<1 au). On 2012 June 12–16, three approximately Earthward-directed and interacting CMEs were observed by the Solar Terrestrial Relations Observatory imagers and Venus Express (VEX) in situ at 0.72 au, 6° away from the Sun–Earth line. The CME kinematics are calculated using the drag-based and WSA–Enlil models, constrained by the arrival time at VEX , resulting in the CME arrival time and speed on Earth. The CME magnetic field strength is scaled with a power law from VEX to Wind . Our investigation shows promising results for the Dst forecast (predicted: −96 and −114 nT (from 2 Dst models); observed: −71 nT), for the arrival speed (predicted: 531 ± 23 km s{sup −1}; observed: 488 ± 30 km s{sup −1}), and for the timing (6 ± 1 hr after the actual arrival time). The prediction lead time is 21 hr. The method may be applied to vector magnetic field data from a spacecraft at an artificial Lagrange point between the Sun and Earth or to data taken by any spacecraft temporarily crossing the Sun–Earth line.

  4. First in-situ observations of exospheric response to CME impact at Mercury

    Science.gov (United States)

    Raines, J. M.; Wallace, K. L.; Sarantos, M.; Jasinski, J. M.; Tracy, P.; Dewey, R. M.; Weberg, M. J.; Slavin, J. A.

    2017-12-01

    We present the first in-situ observations of enhancements to Mercury's He exosphere generated by CME impact. We analyzed both plasma and magnetic field measurements from the Mercury Surface Space Environment, Geochemistry and Mapping (MESSENGER) spacecraft over a 60-hour period as a coronal mass ejection (CME) passed by the planet. We identified the shock, magnetic cloud and cavity regions of the moderate intensity CME while MESSENGER was in the solar wind. Inside the magnetosphere just after the CME shock passage, we observed a very active dayside magnetosphere, as evident from the high flux plasma parcels passing through the dayside and a broad northern magnetospheric cusp with exceptionally high planetary ion content. All of these signatures indicate substantial reconnection at the dayside magnetopause, making conditions that were excellent for solar wind access to Mercury's surface. The CME appeared to have been particularly enriched in He2+, causing the observed density of solar wind He2+ in the cusp to rise above 0.1 cm-3 and putting it in the top 1% of the over 3200 cusps analyzed. As the low-density CME cavity passed over the planet on the next orbit, the magnetosphere appeared much quieter, with smoother magnetic fields and a smaller, less intense northern cusp but with greatly enhanced He+ content. The elevated He+ observed density continued to increase on subsequent cusp crossings, peaking at 0.1 cm-3 36 hours after CME impact, the highest observed throughout the entire MESSENGER mission. We suggest that the enhancement in He+ indicates an increase to the neutral He exosphere density from the He-enriched CME, a phenomenon observed at the moon, possibly acting as follows: Increased access to the surface from CME-enhanced reconnection, combined with high He2+ flux, enhanced surface implantation. Neutral He atoms were then liberated at an increased rate by surface processes supplying the exosphere, causing a gradual increase in He exosphere density. This

  5. Evaluating Land-Atmosphere Moisture Feedbacks in Earth System Models With Spaceborne Observations

    Science.gov (United States)

    Levine, P. A.; Randerson, J. T.; Lawrence, D. M.; Swenson, S. C.

    2016-12-01

    We have developed a set of metrics for measuring the feedback loop between the land surface moisture state and the atmosphere globally on an interannual time scale. These metrics consider both the forcing of terrestrial water storage (TWS) on subsequent atmospheric conditions as well as the response of TWS to antecedent atmospheric conditions. We designed our metrics to take advantage of more than one decade's worth of satellite observations of TWS from the Gravity Recovery and Climate Experiment (GRACE) along with atmospheric variables from the Atmospheric Infrared Sounder (AIRS), the Global Precipitation Climatology Project (GPCP), and Clouds and the Earths Radiant Energy System (CERES). Metrics derived from spaceborne observations were used to evaluate the strength of the feedback loop in the Community Earth System Model (CESM) Large Ensemble (LENS) and in several models that contributed simulations to Phase 5 of the Coupled Model Intercomparison Project (CMIP5). We found that both forcing and response limbs of the feedback loop were generally stronger in tropical and temperate regions in CMIP5 models and even more so in LENS compared to satellite observations. Our analysis suggests that models may overestimate the strength of the feedbacks between the land surface and the atmosphere, which is consistent with previous studies conducted across different spatial and temporal scales.

  6. The Ocean Colour Climate Change Initiative: I. A Methodology for Assessing Atmospheric Correction Processors Based on In-Situ Measurements

    Science.gov (United States)

    Muller, Dagmar; Krasemann, Hajo; Brewin, Robert J. W.; Deschamps, Pierre-Yves; Doerffer, Roland; Fomferra, Norman; Franz, Bryan A.; Grant, Mike G.; Groom, Steve B.; Melin, Frederic; hide

    2015-01-01

    The Ocean Colour Climate Change Initiative intends to provide a long-term time series of ocean colour data and investigate the detectable climate impact. A reliable and stable atmospheric correction procedure is the basis for ocean colour products of the necessary high quality. In order to guarantee an objective selection from a set of four atmospheric correction processors, the common validation strategy of comparisons between in-situ and satellite derived water leaving reflectance spectra, is extended by a ranking system. In principle, the statistical parameters such as root mean square error, bias, etc. and measures of goodness of fit, are transformed into relative scores, which evaluate the relationship of quality dependent on the algorithms under study. The sensitivity of these scores to the selected database has been assessed by a bootstrapping exercise, which allows identification of the uncertainty in the scoring results. Although the presented methodology is intended to be used in an algorithm selection process, this paper focusses on the scope of the methodology rather than the properties of the individual processors.

  7. In-situ SEM observation on fracture behavior of austempered silicon alloyed steel

    Directory of Open Access Journals (Sweden)

    Chen Xiang

    2009-08-01

    Full Text Available Crack initiation, propagation and microfracture processes of austempered high silicon cast steel have been investigated by using an in-situ tensile stage installed inside a scanning electron microscope chamber. It is revealed that micro cracks always nucleate at the yielding near imperfections and the boundary of matrix-inclusions due to the stress concentration. There are four types of crack propagations in the matrix: crack propagates along the boundary of two clusters of bainitic ferrite; crack propagates along the boundary of ferrite朼ustenite in bainitic ferrite laths; crack propagates into bainitic ferrite laths; crack nucleates and propagates in the high carbon brittle plate shape martensite which is transformed from some blocky retained austenite due to plastic deformation. Based on the observation and analysis of microfracture processes, a schematic diagram of the crack nucleation and propagation process of high silicon cast steel is proposed

  8. In situ observations of crack formation in multi-filament Bi-2223 HTS tapes

    DEFF Research Database (Denmark)

    Sørensen, Bent F.; Horsewell, Andy; Skov-Hansen, P.

    2002-01-01

    High temperature superconducting tapes (BSCCO filaments embedded in Ag) were subjected to Uniaxial tension in an environmental scanning electron microscope, allowing in situ observation of cracking of the ceramic filaments. The first cracks were found to appear in the ceramic filaments at a strain...... around 0.15%, More cracks formed with increasing strain. The cracks covered the entire thickness of the filament. but did not Continue into the surrounding (ductile) Ag matrix. These 'tunnel cracks' appeared somewhat zigzag, indicating intergranular cracking mode. At low strains, crack blunting occurred...... at the ceramic/Ag interfaces of the tunnel cracks, At higher strain 'split cracks' formed at the tunnel cracks. The split cracks ran parallel with the ceramic/Ag interface just inside the ceramic layer....

  9. In situ observations of microstructural changes in SOFC anodes during redox cycling

    DEFF Research Database (Denmark)

    Klemensø, Trine; Appel, C. C.; Mogensen, Mogens Bjerg

    2006-01-01

    The anode-supported solid oxide fuel cell (SOFC) degrades when the anode is subjected to redox cycling. The degradation has qualitatively been related to microstructural changes in the nickel-yttria stabilized zirconia anode of the tested cells. In this work, the microstructural changes were...... observed in situ using environmental scanning electron microscopy. In the reduced state, a dynamic rounding of the nickel particles occurred. The oxide growth upon re-oxidation depended on the oxidation kinetics. During rapid oxidation, the NiO particles divided into 2-4 particles, which grew...... into the surrounding voids. For slower oxidation, an external oxide layer was seen to develop around the individual particles. (c) 2006 The Electrochemical Society....

  10. In situ observations of crack arrest and bridging by nanoscale twins in copper thin films

    International Nuclear Information System (INIS)

    Kim, Seong-Woong; Li Xiaoyan; Gao Huajian; Kumar, Sharvan

    2012-01-01

    In situ tensile experiments in a transmission electron microscope revealed that micro-cracks in ultrafine grained, free-standing, thin copper foils containing nanoscale twins initiated in matrix domains separated by the twins and then arrested at twin boundaries as twin boundary sliding proceeded. The adjacent microcracks eventually coalesced through shear failure of the bridging twins. To investigate the atomic mechanism of this rarely seen nanoscale crack bridging behavior, molecular dynamics simulations were performed to show that during crack propagation twin boundaries are impinged upon by numerous dislocations from the plastically deforming matrix. These dislocations react at the interface and evolve into substantially impenetrable dislocation walls that strongly confine crack nucleation and resist crack propagation, leading to the experimentally observed crack bridging behavior. The present results raise an approach to significantly toughening polycrystalline thin films by incorporating nanoscale twin structures into individual grains that serve as crack bridging ligaments.

  11. In situ observations of solidification processes in γ-TiAl alloys by synchrotron radiation

    International Nuclear Information System (INIS)

    Shuleshova, Olga; Holland-Moritz, Dirk; Loeser, Wolfgang; Voss, Andrea; Hartmann, Helena; Hecht, Ulrike; Witusiewicz, Victor T.; Herlach, Dieter M.; Buechner, Bernd

    2010-01-01

    In situ observations of phase transformations involving melts are performed using energy-dispersive diffraction of synchrotron X-rays on electromagnetically levitated γ-TiAl alloys containing Nb. The determined primary solidification modes, confirmed by microstructure analysis, delivered new reliable data about the boundary of the α(Ti) solidification domain, which differs in the various Ti-Al-Nb phase diagram descriptions. These data have been used for a reassessment of the thermodynamic database of the ternary Ti-Al-Nb system. The new description realistically reflects the experimental findings. Liquidus and solidus temperatures determined by the pyrometric method agree fairly well with the calculated values. Direct experimental information on the nature of the reactions along the univariant lines is provided.

  12. In-situ observations of the development of heavy-ion damage in semiconductors

    International Nuclear Information System (INIS)

    Jenkins, M.L.; Chandler, T.J.; Robertson, I.M.; Kirk, M.A.

    1985-01-01

    In-situ observations on ion-beam induced amorphisation of GaAs, GaP and Si are reported. Direct-impact amorphisation was found to occur in GaAs irradiated with 100-keV Xe + ions to low doses at low temperature (approx. 40K) in contrast to previous room temperature irradiations. In GaP and in silicon, where heavy projectiles do cause direct impact amorphisation at room temperature, the evolution of the damage structure with ion-dose was studied. The defect yield both in GaP irradiated with 100-keV Kr + ions and in Si irradiated with 100-keV Xe + ions was found to decrease monotonically with increasing dose over the dose range 10 15 to 10 17 ions m -2

  13. In situ observation of morphological change in CdTe nano- and submicron wires

    Energy Technology Data Exchange (ETDEWEB)

    Davami, Keivan; Lee, Jeong-Soo; Meyyappan, M [Division of IT Convergence Engineering, Pohang University of Science and Technology, Pohang (Korea, Republic of); Ghassemi, Hessam M; Yassar, Reza S [Department of Mechanical Engineering, Michigan Technological University, Houghton, MI 49931 (United States); Sun, Xuhui, E-mail: ljs6951@postech.ac.kr, E-mail: m.meyyappan@nasa.gov [Institute of Functional Nano and Soft Materials (FUNSOM), Soochow University, Suzhou, Jiangsu 215123 (China)

    2011-10-28

    We report growth and characterization of CdTe wires 30-400 nm in diameter by the vapor-liquid-solid technique. Individual nanowires were placed on a movable piezotube, which allowed three-dimensional motion toward a scanning tunneling microscope (STM). A bias was applied to the STM tip in contact with the nanowire, and the morphological changes due to Joule heating were observed in situ using a transmission electron microscope (TEM) in real time. For thick CdTe wires (d > {approx} 150 nm), the process results in the growth of superfine nanowires (SFNWs) of 2-4 nm diameter on the surface of the wire. Smaller diameter nanowires, in contrast, disintegrate under the applied bias before the complete evolution of SFNWs on the surface.

  14. In situ observations of microscale damage evolution in unidirectional natural fibre composites

    DEFF Research Database (Denmark)

    Rask, Morten; Madsen, Bo; Sørensen, Bent F.

    2012-01-01

    Synchrotron X-ray tomographic microscopy (XTM) has been used to observe in situ damage evolution in unidirectional flax fibre yarn/polypropylene composites loaded in uniaxial tension at stress levels between 20% and 95% of the ultimate failure stress. XTM allows for 3D visualization of the internal...... damage state at each stress level. The overall aim of the study is to gain a better understanding of the damage mechanisms in natural fibre composites. This is necessary if they are to be optimized to fulfil their promising potential. Three dominating damage mechanisms have been identified: (i) interface...... splitting cracks typically seen at the interfaces of bundles of unseparated fibres, (ii) matrix shear cracks, and (iii) fibre failures typically seen at fibre defects. Based on the findings in the present study, well separated fibres with a low number of defects are recommended for composite reinforcements....

  15. In Situ Transmission Electron Microscopy Observation of Nanostructural Changes in Phase-Change Memory

    KAUST Repository

    Meister, Stefan

    2011-04-26

    Phase-change memory (PCM) has been researched extensively as a promising alternative to flash memory. Important studies have focused on its scalability, switching speed, endurance, and new materials. Still, reliability issues and inconsistent switching in PCM devices motivate the need to further study its fundamental properties. However, many investigations treat PCM cells as black boxes; nanostructural changes inside the devices remain hidden. Here, using in situ transmission electron microscopy, we observe real-time nanostructural changes in lateral Ge2Sb2Te5 (GST) PCM bridges during switching. We find that PCM devices with similar resistances can exhibit distinct threshold switching behaviors due to the different initial distribution of nanocrystalline and amorphous domains, explaining variability of switching behaviors of PCM cells in the literature. Our findings show a direct correlation between nanostructure and switching behavior, providing important guidelines in the design and operation of future PCM devices with improved endurance and lower variability. © 2011 American Chemical Society.

  16. In situ observations of the isotopic composition of methane at the Cabauw tall tower site

    Directory of Open Access Journals (Sweden)

    T. Röckmann

    2016-08-01

    Full Text Available High-precision analyses of the isotopic composition of methane in ambient air can potentially be used to discriminate between different source categories. Due to the complexity of isotope ratio measurements, such analyses have generally been performed in the laboratory on air samples collected in the field. This poses a limitation on the temporal resolution at which the isotopic composition can be monitored with reasonable logistical effort. Here we present the performance of a dual isotope ratio mass spectrometric system (IRMS and a quantum cascade laser absorption spectroscopy (QCLAS-based technique for in situ analysis of the isotopic composition of methane under field conditions. Both systems were deployed at the Cabauw Experimental Site for Atmospheric Research (CESAR in the Netherlands and performed in situ, high-frequency (approx. hourly measurements for a period of more than 5 months. The IRMS and QCLAS instruments were in excellent agreement with a slight systematic offset of (+0.25 ± 0.04 ‰ for δ13C and (−4.3 ± 0.4 ‰ for δD. This was corrected for, yielding a combined dataset with more than 2500 measurements of both δ13C and δD. The high-precision and high-temporal-resolution dataset not only reveals the overwhelming contribution of isotopically depleted agricultural CH4 emissions from ruminants at the Cabauw site but also allows the identification of specific events with elevated contributions from more enriched sources such as natural gas and landfills. The final dataset was compared to model calculations using the global model TM5 and the mesoscale model FLEXPART-COSMO. The results of both models agree better with the measurements when the TNO-MACC emission inventory is used in the models than when the EDGAR inventory is used. This suggests that high-resolution isotope measurements have the potential to further constrain the methane budget when they are performed at multiple sites that are representative for

  17. Atmospheric characterization through fused mobile airborne and surface in situ surveys: methane emissions quantification from a producing oil field

    Directory of Open Access Journals (Sweden)

    I. Leifer

    2018-03-01

    Full Text Available Methane (CH4 inventory uncertainties are large, requiring robust emission derivation approaches. We report on a fused airborne–surface data collection approach to derive emissions from an active oil field near Bakersfield, central California. The approach characterizes the atmosphere from the surface to above the planetary boundary layer (PBL and combines downwind trace gas concentration anomaly (plume above background with normal winds to derive flux. This approach does not require a well-mixed PBL; allows explicit, data-based, uncertainty evaluation; and was applied to complex topography and wind flows. In situ airborne (collected by AJAX – the Alpha Jet Atmospheric eXperiment and mobile surface (collected by AMOG – the AutoMObile trace Gas – Surveyor data were collected on 19 August 2015 to assess source strength. Data included an AMOG and AJAX intercomparison transect profiling from the San Joaquin Valley (SJV floor into the Sierra Nevada (0.1–2.2 km altitude, validating a novel surface approach for atmospheric profiling by leveraging topography. The profile intercomparison found good agreement in multiple parameters for the overlapping altitude range from 500 to 1500 m for the upper 5 % of surface winds, which accounts for wind-impeding structures, i.e., terrain, trees, buildings, etc. Annualized emissions from the active oil fields were 31.3 ± 16 Gg methane and 2.4 ± 1.2 Tg carbon dioxide. Data showed the PBL was not well mixed at distances of 10–20 km downwind, highlighting the importance of the experimental design.

  18. In situ observation of a hydrogel-glass interface during sliding friction.

    Science.gov (United States)

    Yamamoto, Tetsurou; Kurokawa, Takayuki; Ahmed, Jamil; Kamita, Gen; Yashima, Shintaro; Furukawa, Yuichiro; Ota, Yuko; Furukawa, Hidemitsu; Gong, Jian Ping

    2014-08-14

    Direct observation of hydrogel contact with a solid surface in water is indispensable for understanding the friction, lubrication, and adhesion of hydrogels under water. However, this is a difficult task since the refractive index of hydrogels is very close to that of water. In this paper, we present a novel method to in situ observe the macroscopic contact of hydrogels with a solid surface based on the principle of critical refraction. This method was applied to investigate the sliding friction of a polyacrylamide (PAAm) hydrogel with glass by using a strain-controlled parallel-plate rheometer. The study revealed that when the compressive pressure is not very high, the hydrogel forms a heterogeneous contact with the glass, and a macro-scale water drop is trapped at the soft interface. The pre-trapped water spreads over the interface to decrease the contact area with the increase in sliding velocity, which dramatically reduces the friction of the hydrogel. The study also revealed that this heterogeneous contact is the reason for the poor reproducibility of hydrogel friction that has been often observed in previous studies. Under the condition of homogeneous full contact, the molecular origin of hydrogel friction in water is discussed. This study highlights the importance of direct interfacial observation to reveal the friction mechanism of hydrogels.

  19. In situ observation of rolling contact fatigue cracks by laminography using ultrabright synchrotron radiation

    Directory of Open Access Journals (Sweden)

    Y. Nakai

    2015-10-01

    Full Text Available In rolling contact fatigue (RCF, cracks usually initiate from inclusions beneath the surface and propagate to the contact surface. In the present study, synchrotron radiation computed laminography (SRCL imaging was performed to observe flaking defects during the RCF of a high-strength steel. Specially fabricated inclusion-rich steel plate specimens were employed in the experiments. For the in situ observation of crack propagation, a compact RCF testing machine was developed, and a 4D analysis scheme was applied to the data obtained by SRCL. RCF tests were carried out near the measurement hatch of the beam line used SRCL to enable the successive observation of crack initiation and growth behaviors. Specimens before and after the occurrence of flaking were observed by SRCL, and flaking defects and cracks under the surface were successfully detected. As a result, details of the crack initiation and flaking process in RCF could be discussed. Shear-type horizontal cracks were found to initiate after the initiation and propagation of tensile-type vertical cracks along inclusions, where the face of the vertical cracks was perpendicular to the rolling direction and rolling surface. Therefore, the formation of vertical cracks is considered to affect shear-type crack formation and flaking, where the shape and length of inclusions also affect the initiation and propagation of vertical cracks.

  20. Atmospheric Responses from Radiosonde Observations of the 2017 Total Solar Eclipse

    Science.gov (United States)

    Fowler, J.

    2017-12-01

    The Atmospheric Responses from Radiosonde Observations project during the August 21st, 2017 Total Solar Eclipse was to observe the atmospheric response under the shadow of the Moon using both research and operational earth science instruments run primarily by undergraduate students not formally trained in atmospheric science. During the eclipse, approximately 15 teams across the path of totality launched radiosonde balloon platforms in very rapid, serial sonde deployment. Our strategy was to combine a dense ground observation network with multiple radiosonde sites, located within and along the margins of the path of totality. This can demonstrate how dense observation networks leveraged among various programs can "fill the gaps" in data sparse regions allowing research ideas and questions that previously could not be approached with courser resolution data and improving the scientific understanding and prediction of geophysical and hazardous phenomenon. The core scientific objectives are (1) to make high-resolution surface and upper air observations in several sites along the eclipse path (2) to quantitatively study atmospheric responses to the rapid disappearance of the Sun across the United States, and (3) to assess the performance of high-resolution weather forecasting models in simulating the observed response. Such a scientific campaign, especially unique during a total solar eclipse, provides a rare but life-altering opportunity to attract and enable next-generation of observational scientists. It was an ideal "laboratory" for graduate, undergraduate, citizen scientists and k-12 students and staff to learn, explore and research in STEM.

  1. In-situ observation of irradiation quantities using a tethered balloon

    Science.gov (United States)

    Becker, Ralf; Gross, Steffen; Behrens, Klaus

    2014-05-01

    Irradiance is a key parameter in Earth's weather and climate system. Accurate observations of the components of the radiation budget are therefore essential to create reliable time series, to analyse spatial variability and to test, validate and adapt satellite-based algorithms. This holds true for near surface measurements as well as for in-situ observations in the lower troposphere. Such measurements are difficult to realise and therefore rarely performed. A tethered balloon system manufactured by Vailsala (9 cbm) is utilised as a carrier of a radiation budget sonde operating up to 1000 m above ground. Application is limited to fair weather conditions with maximum winds of 20 km/h and visibility greater than 3 km at ground level. The experimental setup is composed of a downward and upward looking pair of Kipp&Zonen CM11 (0.305-2.8 μm) and a corresponding pair of Kipp&Zonen CG4 (4.5 - 42 μm). Instruments are categorized as WMO 'secondary standard' according to ISO9660 and can be characterised as sufficiently robust and with acceptable response time for this purpose. Instrumentation is complemented by meteorological sensors (wind, temperature, humidity) flown on a dedicated suspension close (less than 50 m distance) to radiation sonde. In-situ measurements of irradiation in flowing and turbulent air are subjected to errors due to moving platform (roll/yaw/pitch). Potential deviations to near-surface measurements are discussed and an error estimate is given. Some comparisons of results of radiative transfer calculations for simple meteorological conditions have been made so far. It can be accomplished either by referring to profiles or by evaluating time series taken at elevated levels. Profiling lacks stationarity most time of a day due to high variability of shortwave downward and thus must be interpreted carefully. First results for longwave profiles as well as evaluation of time series obtained at distinct levels above ground show good correspondence.

  2. In situ observations of oxide fracture on austenitic stainless steels relevant to IASCC

    International Nuclear Information System (INIS)

    Duff, J.; Burke, M.G.; Scenini, F.

    2015-01-01

    Stress Corrosion Cracking (SCC) and Irradiation-Assisted Stress Corrosion Cracking (IASCC) are important failure modes in the nuclear industry, yet the exact mechanism(s) responsible for these complex failure phenomena are not fully understood. In particular, considerable attention is being focused on SCC and IASCC initiation and the behaviour of the oxidised metal surface during straining in a relevant environment. Experimental observations and data for oxide fracture at the grain boundary are limited, but are also required for the development of crack growth models. In this work, the role of strain localization on surface oxide fracture has been examined via: 1) in situ straining experiments using a state-of-the-art imaging autoclave; and 2) ex situ studies using pre-oxidised samples in a FEG-SEM with a micro-tensile stage. The work was conducted using three materials: 1) a non-irradiated archive Type 316 Stainless Steel, 2) a 1 dpa proton-irradiated Type 316 Stainless Steel, and 3) a model alloy designed to simulate the grain boundary composition resulting from radiation induced segregation. The observations were performed on samples pre-oxidized at 320 C. degrees in high purity, water containing 30 cm 3 /kg of dissolved H 2 and 2 ppm Li additions. The samples were strained in tension and the surface deformation measured via Digital Image Correlation. This technique provided quantitative data regarding the intergranular strains associated with oxide fracture. Oxide fracture and strain development were also related to the local irradiation-induced microstructure and grain boundary character. The results from this work contribute to the mechanistic information on the role of strain localization and composition on the incubation stages of IASCC. (authors)

  3. A note on sea level variability at Clipperton Island from GEOSAT and in-situ observations

    Science.gov (United States)

    Maul, George A.; Hansen, Donald V.; Bravo, Nicolas J.

    During the 1986-1989 Exact Repeat Mission (ERM) of GEOSAT, in-situ observations of sea level at Clipperton Island (10°N/109°W) and satellite-tracked free-drifting drogued buoys in the eastern tropical Pacific Ocean are concurrently available. A map of the standard deviations of GEOSAT sea surface heights (2.9 years) shows a variance maximum along ˜12°N from Central America, past Clipperton to ˜160°W. Sea floor pressure gauge observations from a shallow (10m depth) site on Clipperton Island and an ERM crossover point in deep water nearby show a correlation of r = 0.76 with a residual of ±6.7 cm RMS. Approximately 17% of the difference (GEOSAT minus sea level) is characterized by a 4 cm amplitude 0° phase annual harmonic, which is probably caused by unaccounted-for tropospheric water vapor affecting the altimeter and/or ERM orbit error removal. Wintertime anticyclonic mesoscale eddies advecting past Clipperton Island each year have GEOSAT sea surface height and in-situ sea level signals of more than 30 cm, some of which are documented by the satellite-tracked drifters. Meridional profiles of the annual harmonic of zonal geostrophic current from GEOSAT and from the drifters both show synchronous maxima in the North Equatorial Countercurrent and the North Equatorial Current. Other Clipperton sea level maxima seen during late spring of each year may involve anticyclonic vortices formed along Central America the previous winter.

  4. Undoped and in-situ B doped GeSn epitaxial growth on Ge by atmospheric pressure-chemical vapor deposition

    DEFF Research Database (Denmark)

    Vincent, B.; Gencarelli, F.; Bender, H.

    2011-01-01

    In this letter, we propose an atmospheric pressure-chemical vapor deposition technique to grow metastable GeSn epitaxial layers on Ge. We report the growth of defect free fully strained undoped and in-situ B doped GeSn layers on Ge substrates with Sit contents up to 8%. Those metastable layers stay...

  5. Influence of gas atmospheres and ceria on the stability of nanoporous gold studied by environmental electron microscopy and In situ ptychography

    DEFF Research Database (Denmark)

    Baier, Sina; Wittstock, Arne; Damsgaard, Christian Danvad

    2016-01-01

    A novel complementary approach of electron microscopy/environmental TEM and in situ hard X-ray ptychography was used to study the thermally induced coarsening of nanoporous gold under different atmospheres, pressures and after ceria deposition. The temperature applied during ptychographic imaging...

  6. Study of the thermal transformations of Co- and Fe-exchanged zeolites A and X by 'in situ' XRD under reducing atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Ronchetti, Silvia, E-mail: silvia.ronchetti@polito.it [Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy); Turcato, Elisa Aurelia; Delmastro, Alessandro [Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy); Esposito, Serena; Ferone, Claudio; Pansini, Michele [Laboratorio Materiali del Dipartimento di Meccanica, Strutture, Ambiente e Territorio, Facolta di Ingegneria dell' Universita di Cassino, Via G. Di Biasio 43, 03043 Cassino (Italy); Onida, Barbara; Mazza, Daniele [Dipartimento di Scienza dei Materiali e Ingegneria Chimica, Politecnico di Torino, Corso Duca degli Abruzzi 24, 10129 Torino (Italy)

    2010-06-15

    'In situ' high temperature X-ray diffraction under reducing atmosphere is used for the first time to study the thermal stability and transformations of Co- and Fe-exchanged A and X zeolites. TG-DTA and 'ex situ' XRD characterization were also carried out. The temperature of incipient crystallization of metallic phase was found to be 700 {sup o}C in Fe-zeolites and 800 {sup o}C in Co-zeolites. Moreover, ex situ X-ray experiments, after thermal treatment both under inert and reducing atmosphere, revealed the formation of ceramic phases upon the thermal collapse of the zeolitic framework. Metal nanoparticles were obtained by reduction and the size of metal clusters was found to range between 24 and 40 nm.

  7. Disturbance observer based model predictive control for accurate atmospheric entry of spacecraft

    Science.gov (United States)

    Wu, Chao; Yang, Jun; Li, Shihua; Li, Qi; Guo, Lei

    2018-05-01

    Facing the complex aerodynamic environment of Mars atmosphere, a composite atmospheric entry trajectory tracking strategy is investigated in this paper. External disturbances, initial states uncertainties and aerodynamic parameters uncertainties are the main problems. The composite strategy is designed to solve these problems and improve the accuracy of Mars atmospheric entry. This strategy includes a model predictive control for optimized trajectory tracking performance, as well as a disturbance observer based feedforward compensation for external disturbances and uncertainties attenuation. 500-run Monte Carlo simulations show that the proposed composite control scheme achieves more precise Mars atmospheric entry (3.8 km parachute deployment point distribution error) than the baseline control scheme (8.4 km) and integral control scheme (5.8 km).

  8. Implementing earth observation and advanced satellite based atmospheric sounders for water resource and climate modelling

    DEFF Research Database (Denmark)

    Boegh, E.; Dellwik, Ebba; Hahmann, Andrea N.

    2010-01-01

    This paper discusses preliminary remote sensing (MODIS) based hydrological modelling results for the Danish island Sjælland (7330 km2) in relation to project objectives and methodologies of a new research project “Implementing Earth observation and advanced satellite based atmospheric sounders....... For this purpose, a) internal catchment processes will be studied using a Distributed Temperature Sensing (DTS) system, b) Earth observations will be used to upscale from field to regional scales, and c) at the largest scale, satellite based atmospheric sounders and meso-scale climate modelling will be used...

  9. Characteristics of atmospheric gravity waves observed using the MU (Middle and Upper atmosphere) radar and GPS (Global Positioning System) radio occultation.

    Science.gov (United States)

    Tsuda, Toshitaka

    2014-01-01

    The wind velocity and temperature profiles observed in the middle atmosphere (altitude: 10-100 km) show perturbations resulting from superposition of various atmospheric waves, including atmospheric gravity waves. Atmospheric gravity waves are known to play an important role in determining the general circulation in the middle atmosphere by dynamical stresses caused by gravity wave breaking. In this paper, we summarize the characteristics of atmospheric gravity waves observed using the middle and upper atmosphere (MU) radar in Japan, as well as novel satellite data obtained from global positioning system radio occultation (GPS RO) measurements. In particular, we focus on the behavior of gravity waves in the mesosphere (50-90 km), where considerable gravity wave attenuation occurs. We also report on the global distribution of gravity wave activity in the stratosphere (10-50 km), highlighting various excitation mechanisms such as orographic effects, convection in the tropics, meteorological disturbances, the subtropical jet and the polar night jet.

  10. Observations of linear dependence between sulfate and nitrate in atmospheric particles

    Science.gov (United States)

    Kong, Lingdong; Yang, Yiwei; Zhang, Shuanqin; Zhao, Xi; Du, Huanhuan; Fu, Hongbo; Zhang, Shicheng; Cheng, Tiantao; Yang, Xin; Chen, Jianmin; Wu, Dui; Shen, Jiandong; Hong, Shengmao; Jiao, Li

    2014-01-01

    Hourly measurements of water-soluble inorganic ionic species in ambient atmospheric particles were conducted at Shanghai, Hangzhou, and Guangzhou sampling sites in China during the period of 2009-2011. The relation between sulfate and nitrate in particulate matter (PM10 and PM2.5) was examined based on these measurements. Results showed that the mass fraction of sulfate was strongly negatively correlated with that of nitrate in atmospheric particles on most of the sampling days, especially when sulfate and nitrate made up the vast majority of the total soluble anions and cations (Na+, K+, Ca2+, and Mg2+) made a small contribution to the total water-soluble ions, revealing that the formation mechanisms of sulfate and nitrate in the atmosphere are highly correlated, and there exists a significant negative correlation trend between sulfate and nitrate mass fractions in the atmospheric particles. We found that local meteorological conditions presented opposite influences on the mass fractions of sulfate and nitrate. Further analysis indicated that the two mass fractions were modulated by the neutralizing level of atmospheric aerosols, and the negative correlation could be found in acidic atmospheric particles. Strong negative correlation was usually observed on clear days, hazy days, foggy days, and respirable particulate air pollution days, whereas poor negative correlation was often observed during cloud, rain, snow, dust storm, and suspended dust events. The results can help to better understand the formation mechanisms of atmospheric sulfate and nitrate during air pollution episodes and to better explain field results of atmospheric chemistry concerning sulfate and nitrate.

  11. In situ alkali-silica reaction observed by x-ray microscopy

    International Nuclear Information System (INIS)

    Kurtis, K.E.; Monteiro, P.J.M.; Brown, J.T.; Meyer-Ilse, W.

    1997-01-01

    In concrete, alkali metal ions and hydroxyl ions contributed by the cement and reactive silicates present in aggregate can participate in a destructive alkali-silica reaction (ASR). This reaction of the alkalis with the silicates produces a gel that tends to imbibe water found in the concrete pores, leading to swelling of the gel and eventual cracking of the affected concrete member. Over 104 cases of alkali-aggregate reaction in dams and spillways have been reported around the world. At present, no method exists to arrest the expansive chemical reaction which generates significant distress in the affected structures. Most existing techniques available for the examination of concrete microstructure, including ASR products, demand that samples be dried and exposed to high pressure during the observation period. These sample preparation requirements present a major disadvantage for the study of alkali-silica reaction. Given the nature of the reaction and the affect of water on its products, it is likely that the removal of water will affect the morphology, creating artifacts in the sample. The purpose of this research is to observe and characterize the alkali-silica reaction, including each of the specific reactions identified previously, in situ without introducing sample artifacts. For observation of unconditioned samples, x-ray microscopy offers an opportunity for such an examination of the alkali-silica reaction. Currently, this investigation is focusing on the effect of calcium ions on the alkali-silica reaction

  12. In-situ observation of weld joint of austenitic stainless steel due to helium irradiation

    International Nuclear Information System (INIS)

    Hamada, S.; Hojou, K.; Hishinuma, A.

    1992-01-01

    Microstructural evolution during helium ions irradiation in a weld metal containing 10% delta-ferrite of a weld joint of Ti-modified austenitic stainless steel were in-situ observed through a transmission electron microcopy. Very fine helium bubbles were observed in high number density in both a delta ferrite phase and a matrix to a dose of 3 x 10 19 ions·m -2 . Entirely different behavior appeared in both phases with increasing dose. Bubbles in a delta-ferrite phase were readily converted into voids during slight increment of dose, and these rapidly grew with additional increasing of dose. On the other hand, finer bubbles in a matrix were very stable during irradiation and did not grow any more up to 2 x 10 20 ions·m -2 . Swelling became much larger in a delta-ferrite phase than in a fcc matrix phase, resultantly ; This means an inverse phenomenon for conventional results that swelling is smaller in a ferrite phase than in a fcc phase. Sigma phase radiation-enhanced precipitated at the grain boundary between a delta-ferrite phase and a matrix at a dose 9 x 10 19 ions·m -2 . This phase grew in two dimensions with increasing dose. The chemical composition of the sigma phase observed during irradiation showed Cr and Mo enrichment, and Fe and Ni depletion compared with those of a sigma phase thermally produced. (author)

  13. In situ alkali-silica reaction observed by x-ray microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Kurtis, K.E.; Monteiro, P.J.M. [Univ. of California, Berkeley, CA (United States); Brown, J.T.; Meyer-Ilse, W. [Ernest Orlando Lawrence Berkeley National Lab., CA (United States)

    1997-04-01

    In concrete, alkali metal ions and hydroxyl ions contributed by the cement and reactive silicates present in aggregate can participate in a destructive alkali-silica reaction (ASR). This reaction of the alkalis with the silicates produces a gel that tends to imbibe water found in the concrete pores, leading to swelling of the gel and eventual cracking of the affected concrete member. Over 104 cases of alkali-aggregate reaction in dams and spillways have been reported around the world. At present, no method exists to arrest the expansive chemical reaction which generates significant distress in the affected structures. Most existing techniques available for the examination of concrete microstructure, including ASR products, demand that samples be dried and exposed to high pressure during the observation period. These sample preparation requirements present a major disadvantage for the study of alkali-silica reaction. Given the nature of the reaction and the affect of water on its products, it is likely that the removal of water will affect the morphology, creating artifacts in the sample. The purpose of this research is to observe and characterize the alkali-silica reaction, including each of the specific reactions identified previously, in situ without introducing sample artifacts. For observation of unconditioned samples, x-ray microscopy offers an opportunity for such an examination of the alkali-silica reaction. Currently, this investigation is focusing on the effect of calcium ions on the alkali-silica reaction.

  14. Deep pelagic food web structure as revealed by in situ feeding observations.

    Science.gov (United States)

    Choy, C Anela; Haddock, Steven H D; Robison, Bruce H

    2017-12-06

    Food web linkages, or the feeding relationships between species inhabiting a shared ecosystem, are an ecological lens through which ecosystem structure and function can be assessed, and thus are fundamental to informing sustainable resource management. Empirical feeding datasets have traditionally been painstakingly generated from stomach content analysis, direct observations and from biochemical trophic markers (stable isotopes, fatty acids, molecular tools). Each approach carries inherent biases and limitations, as well as advantages. Here, using 27 years (1991-2016) of in situ feeding observations collected by remotely operated vehicles (ROVs), we quantitatively characterize the deep pelagic food web of central California within the California Current, complementing existing studies of diet and trophic interactions with a unique perspective. Seven hundred and forty-three independent feeding events were observed with ROVs from near-surface waters down to depths approaching 4000 m, involving an assemblage of 84 different predators and 82 different prey types, for a total of 242 unique feeding relationships. The greatest diversity of prey was consumed by narcomedusae, followed by physonect siphonophores, ctenophores and cephalopods. We highlight key interactions within the poorly understood 'jelly web', showing the importance of medusae, ctenophores and siphonophores as key predators, whose ecological significance is comparable to large fish and squid species within the central California deep pelagic food web. Gelatinous predators are often thought to comprise relatively inefficient trophic pathways within marine communities, but we build upon previous findings to document their substantial and integral roles in deep pelagic food webs. © 2017 The Authors.

  15. Interpretation of the Haestholmen in situ state of stress based on core damage observations

    International Nuclear Information System (INIS)

    Hakala, M.

    2000-01-01

    At the Haestholmen investigation site, direct in situ stress measurements, overcoring and hydraulic fracturing have been unsuccessful because of ring disking and horizontal hydraulic fracturing. Prior to this study, a detailed study on both core disking and ring disking was made, and based on those results an in situ state of stress interpretation method was developed. In this work this method is applied to the Haestholmen site. The interpretation is based on disk fracture type, spacing and shape. Also, the Hoek-Brown strength envelope and Poisson's ratio of intact rock are needed. The interpretation result is most reliable if both core disking and ring disking information at the same depth levels is available. A detailed core logging showed that ring disking is systematic below the -365 m level in the vertical overcoring stress measurement hole, HH-KR6. On the other hand, no representative core disking exists except for two points in two differently oriented subvertical boreholes HH-KR2 and HHKR7. Because the interpretation has to be based on ring disking only, upper and lower estimates for the vertical stress were set. These were gravitational and 67% of gravitational. Furthermore, the in situ stress state was assumed to be in horizontal and vertical planes, because the disking in vertical borehole HH-KR6 was not inclined. The interpretation resulted in a good estimate for the major horizontal stress but none of the horizontal stress rations ( 0.25, 0.5, 0.75 and 1.0 ) or vertical stress assumptions studied are clearly more probable the others. At the 500 m level the resulting maximum horizontal stress is 41 MPa. If a linear fit through the zero depth and zero stress point is applied, the maximum horizontal stress gradient is 0.0818 z MPa/m with a standard deviation between 5 and 12 per cent. The orientation of the major horizontal stress is 108 with standard deviation of 21 degrees. The interpreted major horizontal stress state also indicated that systematic

  16. Combining soundscape analysis with in situ observations and oceanographic data for future ecosystem evaluation techniques.

    Science.gov (United States)

    Freeman, S. E.; Freeman, L. A.

    2016-02-01

    Coral reef ecosystems face many anthropogenic threats. There are urgent requirements for improved monitoring and management. Conventional assessment methods using SCUBA are costly and prone to bias and under-sampling. Here, three approaches to understanding coral reef ecology are combined to aid the goal of enhanced passive monitoring in the future: statistical analysis of oceanographic habitats, remote cameras for nocturnal surveys of benthic fauna, and soundscape analysis in the context of oceanographic setting and ecological metrics collected in-situ. Hawaiian reefs from Kure Atoll to the island of Hawaii, an area spanning two oceanographic habitats, are assessed. Multivariate analysis of acoustic, remote camera, and in-situ observational data showed significant differences in more than 20 percent of ecological and acoustic variables when grouped by oceanic regime, suggesting that large-scale oceanography substantially influences local ecological states and associated soundscapes. Acoustic variables further delineated sites by island, suggesting local conditions influence the soundscape to a greater degree. While the number of invertebrates (with an emphasis on crustaceans and echinoderms) imaged using remote cameras correlated with a number of acoustic metrics, an increasingly higher correlation between invertebrate density and spectral level was observed as acoustic bands increased in frequency from 2 to 20 kHz. In turn, correlation was also observed between the number of predatory fish and sound levels above 2 kHz, suggesting a connection between the number of invertebrates, sound levels at higher frequencies, and the presence of their predators. Comparisons between sound recordings and diversity indices calculated from observational and remote camera data indicate that greater diversity in fishes and benthic invertebrates is associated with a larger change in sound levels between day and night. Interdisciplinary analyses provide a novel view to underwater

  17. Spectroscopy of carbonated chains: experimental investigation and observation of Titan's atmosphere

    International Nuclear Information System (INIS)

    Jolly, Antoine

    2012-01-01

    In this report for an Accreditation to Supervise Research (HDR), the author proposes an overview of his research works. These works first addressed quantitative spectroscopy and more particularly the measurement of absolute absorption coefficients which are necessary parameters for the quantification of molecules which are remotely sensed through their spectroscopic signature. Secondly, the author addresses the adjustment of line lists in the infrared for a better investigation of recent observations of Titan's atmosphere made by the Cassini mission. Thirdly, he reports the use of this line list for the processing of observations of Titan. The last part addresses an experimental atmospheric simulation which aims at reproducing Titan's atmosphere by submitting its main components (nitrogen and methane) to an energetic flow representative of what is present on Titan

  18. Two-dimensional characterization of atmospheric profile retrievals from limb sounding observations

    International Nuclear Information System (INIS)

    Worden, J.R.; Bowman, K.W.; Jones, D.B.

    2004-01-01

    Limb sounders measure atmospheric radiation that is dependent on atmospheric temperature and constituents that have a radial and angular distribution in Earth-centered coordinates. In order to evaluate the sensitivity of a limb retrieval to radial and angular distributions of trace gas concentrations, we perform and characterize one-dimensional (vertical) and two-dimensional (radial and angular) atmospheric profile retrievals. Our simulated atmosphere for these retrievals is a distribution of carbon monoxide (CO), which represents a plume off the coast of south-east Asia. Both the one-dimensional (1D) and two-dimensional (2D) limb retrievals are characterized by evaluating their averaging kernels and error covariances on a radial and angular grid that spans the plume. We apply this 2D characterization of a limb retrieval to a comparison of the 2D retrieval with the 1D (vertical) retrieval. By characterizing a limb retrieval in two dimensions the location of the air mass where the retrievals are most sensitive can be determined. For this test case the retrievals are most sensitive to the CO concentrations about 2 deg.latitude in front of the tangent point locations. We find the information content for the 2D retrieval is an order of magnitude larger and the degrees of freedom is about a factor of two larger than that of the 1D retrieval primarily because the 2D retrieval can estimate angular distributions of CO concentrations. This 2D characterization allows the radial and angular resolution as well as the degrees of freedom and information content to be computed for these limb retrievals. We also use the 2D averaging kernel to develop a strategy for validation of a limb retrieval with an in situ measurement

  19. Atmospheric Radionuclides from the Fukushima Nuclear Accident-Two years observations in Tsukuba, Japan

    Science.gov (United States)

    Igarashi, Yasuhito; Kajino, Mizuo; Zaizen, Yuji; Adachi, Koji; Mikami, Masao; Kita, Kazuyuki; Hatano, Yuko

    2013-04-01

    The accident of Fukushima Dai-Ichi Nuclear Power Plant of the Tokyo Electric Power Corporation arisen by the hit of great earthquake and tsunami in March 11, 2011, emitted abundant fresh radioactive material to the atmospheric environment. The amount has been estimated to be at least a few-tenth of those from the Chernobyl accident (by NISA, etc.). By this large-scale contamination, atmospheric environments over Japan, especially the eastern part, were seriously impacted with such a massive amount of the anthropogenic radionuclides (e.g. typical hotspots). So the persisting aftermath is one of the concerns. Although the heavy primary emission seems to be terminated until April of 2011, 2ndary emissions from contaminated ground surface, coppices, fields, roads, any burnings of the contaminated materials generated the resuspension of radionuclides into the atmosphere. With 2-years observation for the Fukushima radioactivity at the Meteorological Research Institute, Japan (MRI) such persisting resuspension is considered in this presentation. The resuspension seems still in difficulty to give forecast by computer modeling; the observations are indispensable bodies of the research even in the future. The MRI has carried out observations of the atmospheric radionuclides, which are long-lived with potentials of environmental and health impacts, for more than 50 years. Aiming at to clarify temporal change in concentration of anthropogenic radionuclides in the atmosphere and its control factors, the observations have continued over the long period. The long-lasting impacts of the Fukushima accident are addressed with our long-term time series of the atmospheric radioactivity as a reference.

  20. Dual ion beam irradiation system for in situ observation with electron microscope

    International Nuclear Information System (INIS)

    Tsukamoto, Tetuo; Hojou, Kiiti; Furuno, Sigemi; Otsu, Hitosi; Izui, Kazuhiko.

    1993-01-01

    We have developed a new in situ observation system for dynamic processes under dual ion beam irradiation. The system consists of a modified 400 keV analytical electron microscope (JEOL, JEM-4000FX) and two 40 kV ion beam accelerators. This system allows evaluation of microscopic changes of structure and chemical bonding state of materials in the dynamic processes under two kinds of ion beam irradiations, that is required for the simulation test of the first wall of nuclear fusion reactors onto which He + , H + , and H 2 + ions are irradiated simultaneously. These two ion accelerators were equipped symmetrically both sides of the electron microscope and individually controlled. Each ion beam extracted from a duo-plasmatron ion gun is bent downward by an angle of 30deg with a mass-separating magnet, and introduced into specimen chamber of the electron microscope. Inside the specimen chamber the beam is deflected again by an angle of 30deg with an electrostatic prism so as to be incident on the specimen surface. Finally, two ion beams from both side are incident on the specimen surface at an angle of 60deg. The maximum ion current density of helium is more than 250μA/cm 2 at the specimen at an ion energy of 17 keV. Images of the electron microscope during dual ion beam irradiation are observed through a TV camera and recorded with a VTR. (author)

  1. In situ observation of shear-driven amorphization in silicon crystals

    Energy Technology Data Exchange (ETDEWEB)

    He, Yang; Zhong, Li; Fan, Feifei; Wang, Chongmin; Zhu, Ting; Mao, Scott X.

    2016-09-19

    Amorphous materials have attracted great interest in the scientific and technological fields. An amorphous solid usually forms under the externally driven conditions of melt-quenching, irradiation and severe mechanical deformation. However, its dynamic formation process remains elusive. Here we report the in situ atomic-scale observation of dynamic amorphization processes during mechanical straining of nanoscale silicon crystals by high resolution transmission electron microscopy (HRTEM). We observe the shear-driven amorphization (SDA) occurring in a dominant shear band. The SDA involves a sequence of processes starting with the shear-induced diamond-cubic to diamond-hexagonal phase transition that is followed by dislocation nucleation and accumulation in the newly formed phase, leading to the formation of amorphous silicon. The SDA formation through diamond-hexagonal phase is rationalized by its structural conformity with the order in the paracrystalline amorphous silicon, which maybe widely applied to diamond-cubic materials. Besides, the activation of SDA is orientation-dependent through the competition between full dislocation nucleation and partial gliding.

  2. [Observation in situ of differentiation from PGC to hematopoietic system cells in chicken embryo].

    Science.gov (United States)

    Zhou, Dong-Yu; Liu, Rong-Xiu; Pei, Yue-Hu

    2009-02-01

    To study the relationship between hematopoiesis and primordial germ cells, chick embryos at different developing stages were flatbed and located. After fixed by glutaral, the embryos were PAS and HE stained respectively, dehydrated serially, transparent, mounted, and were observed in situ or in cut sheet condition. The results showed: (1) the cellule amorphous and the disposition in chick embryo of PGCs were coincident no matter stained by PAS or HE staining, and HE staining could disclose the morphologic characteristics more clearly, exactly and completely; (2) genesis of blood island could be observed at the boundary of light and dark region of the extraembryonic blastoderm at about 26 hours; (3) both the blood vessel endothelium cells and free cells of the blood island were differentiated from PGCs. The generating of genuine yolk sac was at about 44 - 48 hours. It is concluded that the initial anatomic site of blood island genesis may be is mesoblast of extraembryonic blastoderm rather than the yolk sac; the blood vessel endothelium cells and the blood cells are generated parallel; the PGCs are the common ancestry of angioblast and HSC.

  3. CONSTRAINING HIGH-SPEED WINDS IN EXOPLANET ATMOSPHERES THROUGH OBSERVATIONS OF ANOMALOUS DOPPLER SHIFTS DURING TRANSIT

    International Nuclear Information System (INIS)

    Miller-Ricci Kempton, Eliza; Rauscher, Emily

    2012-01-01

    Three-dimensional (3D) dynamical models of hot Jupiter atmospheres predict very strong wind speeds. For tidally locked hot Jupiters, winds at high altitude in the planet's atmosphere advect heat from the day side to the cooler night side of the planet. Net wind speeds on the order of 1-10 km s –1 directed towards the night side of the planet are predicted at mbar pressures, which is the approximate pressure level probed by transmission spectroscopy. These winds should result in an observed blueshift of spectral lines in transmission on the order of the wind speed. Indeed, Snellen et al. recently observed a 2 ± 1 km s –1 blueshift of CO transmission features for HD 209458b, which has been interpreted as a detection of the day-to-night (substellar to anti-stellar) winds that have been predicted by 3D atmospheric dynamics modeling. Here, we present the results of a coupled 3D atmospheric dynamics and transmission spectrum model, which predicts the Doppler-shifted spectrum of a hot Jupiter during transit resulting from winds in the planet's atmosphere. We explore four different models for the hot Jupiter atmosphere using different prescriptions for atmospheric drag via interaction with planetary magnetic fields. We find that models with no magnetic drag produce net Doppler blueshifts in the transmission spectrum of ∼2 km s –1 and that lower Doppler shifts of ∼1 km s –1 are found for the higher drag cases, results consistent with—but not yet strongly constrained by—the Snellen et al. measurement. We additionally explore the possibility of recovering the average terminator wind speed as a function of altitude by measuring Doppler shifts of individual spectral lines and spatially resolving wind speeds across the leading and trailing terminators during ingress and egress.

  4. Seven years of recent European net terrestrial carbon dioxide exchange constrained by atmospheric observations

    NARCIS (Netherlands)

    Peters, W.; Krol, M. C.; van der Werf, G. R.; Houweling, S.; Jones, C. D.; Hughes, J.; Schaefer, K.; Masarie, K. A.; Jacobson, A. R.; Miller, J. B.; Cho, C. H.; Ramonet, M.; Schmidt, M.; Ciattaglia, L.; Apadula, F.; Heltai, D.; Meinhardt, F.; di Sarra, A. G.; Piacentino, S.; Sferlazzo, D.; Aalto, T.; Hatakka, J.; StröM, J.; Haszpra, L.; Meijer, H. A J; van Der Laan, S.; Neubert, R. E M; Jordan, A.; Rodó, X.; Morguí, J. A.; Vermeulen, A. T.; Popa, Maria Elena; Rozanski, K.; Zimnoch, M.; Manning, A. C.; Leuenberger, M.; Uglietti, C.; Dolman, A. J.; Ciais, P.; Heimann, M.; Tans, P.

    2010-01-01

    We present an estimate of net ecosystem exchange (NEE) of CO2 in Europe for the years 2001-2007. It is derived with a data assimilation that uses a large set of atmospheric CO2 mole fraction observations (∼70 000) to guide relatively simple descriptions of terrestrial and oceanic net exchange, while

  5. Seven years of recent European net terrestrial carbon dioxide exchange constrained by atmospheric observations

    NARCIS (Netherlands)

    Peters, W.; Krol, M.C.; Werf, van der G.R.; Houweling, S.; Jones, C.D.; Hughes, J.; Schaefer, K.; Masarie, K.A.

    2010-01-01

    We present an estimate of net ecosystem exchange (NEE) of CO2 in Europe for the years 2001–2007. It is derived with a data assimilation that uses a large set of atmospheric CO2 mole fraction observations (~70 000) to guide relatively simple descriptions of terrestrial and oceanic net exchange, while

  6. Seven years of recent European net terrestrial carbon dioxide exchange constrained by atmospheric observations

    NARCIS (Netherlands)

    Peters, W.; Krol, M; van der Werf, G. R.; Houweling, S.; Jones, C. D.; Hughes, J.; Schaefer, K.; Masarie, K. A.; Jacobson, A. R.; Miller, J. B.; Cho, C. H.; Ramonet, M.; Schmidt, M.; Ciattaglia, L.; Apadula, F.; Helta, D.; Meinhardt, F.; di Sarra, A. G.; Piacentino, S.; Sferlazzo, D.; Aalto, T.; Hatakka, J.; Strom, J.; Haszpra, L.; Meijer, H. A. J.; van der Laan, S.; Neubert, R. E. M.; Jordan, A.; Rodo, X.; Morgui, J. -A.; Vermeulen, A. T.; Popa, E.; Rozanski, K.; Zimnoch, M.; Manning, A. C.; Leuenberger, M.; Uglietti, C.; Dolman, A. J.; Ciais, P.; Heimann, M.; Tans, P. P.; Heltai, D.; Ström, J.

    We present an estimate of net ecosystem exchange (NEE) of CO(2) in Europe for the years 2001-2007. It is derived with a data assimilation that uses a large set of atmospheric CO(2) mole fraction observations (similar to 70 000) to guide relatively simple descriptions of terrestrial and oceanic net

  7. Estimating Terrestrial Wood Biomass from Observed Concentrations of Atmospheric Carbon Dioxide

    NARCIS (Netherlands)

    Schaefer, K. M.; Peters, W.; Carvalhais, N.; van der Werf, G.; Miller, J.

    2008-01-01

    We estimate terrestrial disequilibrium state and wood biomass from observed concentrations of atmospheric CO2 using the CarbonTracker system coupled to the SiBCASA biophysical model. Starting with a priori estimates of carbon flux from the land, ocean, and fossil fuels, CarbonTracker estimates net

  8. UAV-borne coherent doppler lidar for marine atmospheric boundary layer observations

    Science.gov (United States)

    Wu, Songhua; Wang, Qichao; Liu, Bingyi; Liu, Jintao; Zhang, Kailin; Song, Xiaoquan

    2018-04-01

    A compact UAV-borne Coherent Doppler Lidar (UCDL) has been developed at the Ocean University of China for the observation of wind profile and boundary layer structure in Marine Atmospheric Boundary Layer (MABL). The design, specifications and motion-correction methodology of the UCDL are presented. Preliminary results of the first flight campaign in Hailing Island in December 2016 is discussed.

  9. Ground-based Observations for the Upper Atmosphere at King Sejong Station, Antarctica

    Science.gov (United States)

    Jee, Geonhwa; Kim, Jeong-Han; Lee, Changsup; Kim, Yong Ha

    2014-06-01

    Since the operation of the King Sejong Station (KSS) started in Antarctic Peninsula in 1989, there have been continuous efforts to perform the observation for the upper atmosphere. The observations during the initial period of the station include Fabry-Perot Interferometer (FPI) and Michelson Interferometer for the mesosphere and thermosphere, which are no longer in operation. In 2002, in collaboration with York University, Canada, the Spectral Airglow Temperature Imager (SATI) was installed to observe the temperature in the mesosphere and lower thermosphere (MLT) region and it has still been producing the mesopause temperature data until present. The observation was extended by installing the meteor radar in 2007 to observe the neutral winds and temperature in the MLT region during the day and night in collaboration with Chungnam National University. We also installed the all sky camera in 2008 to observe the wave structures in the MLT region. All these observations are utilized to study on the physical characteristics of the MLT region and also on the wave phenomena such as the tide and gravity wave in the upper atmosphere over KSS that is well known for the strong gravity wave activity. In this article, brief introductions for the currently operating instruments at KSS will be presented with their applications for the study of the upper atmosphere

  10. Ground-based Observations for the Upper Atmosphere at King Sejong Station, Antarctica

    Directory of Open Access Journals (Sweden)

    Geonhwa Jee

    2014-06-01

    Full Text Available Since the operation of the King Sejong Station (KSS started in Antarctic Peninsula in 1989, there have been continuous efforts to perform the observation for the upper atmosphere. The observations during the initial period of the station include Fabry-Perot Interferometer (FPI and Michelson Interferometer for the mesosphere and thermosphere, which are no longer in operation. In 2002, in collaboration with York University, Canada, the Spectral Airglow Temperature Imager (SATI was installed to observe the temperature in the mesosphere and lower thermosphere (MLT region and it has still been producing the mesopause temperature data until present. The observation was extended by installing the meteor radar in 2007 to observe the neutral winds and temperature in the MLT region during the day and night in collaboration with Chungnam National University. We also installed the all sky camera in 2008 to observe the wave structures in the MLT region. All these observations are utilized to study on the physical characteristics of the MLT region and also on the wave phenomena such as the tide and gravity wave in the upper atmosphere over KSS that is well known for the strong gravity wave activity. In this article, brief introductions for the currently operating instruments at KSS will be presented with their applications for the study of the upper atmosphere.

  11. In-situ observations of nucleation in Al-0.1Mg

    DEFF Research Database (Denmark)

    Wu, G.L.; Ubhi, H.S.; Petrenec, M.

    2015-01-01

    A tensile sample of an Al-0.1Mg alloy was in-situ tested in a SEM followed by in-situ annealing to develop recrystallizing nuclei/grains. The evolution of microstructure and crystallographic orientations were characterized using the EBSD technique. Changes in the same area within the sample durin...

  12. In-situ observation of recrystallization in an AlMgScZr alloy using confocal laser scanning microscopy

    International Nuclear Information System (INIS)

    Taendl, J.; Nambu, S.; Orthacker, A.; Kothleitner, G.; Inoue, J.; Koseki, T.; Poletti, C.

    2015-01-01

    In this work we present a novel in-situ approach to study the recrystallization behavior of age hardening alloys. We use confocal laser scanning microscopy (CLSM) at 400 °C to investigate the static recrystallization of an AlMg4Sc0.4Zr0.12 alloy in-situ. The results are combined with electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM) analyses. It was found that CLSM is a powerful tool to visualize both the local initiation and temporal sequence of recrystallization. After fast nucleation and initial growth, the grain growth rate decreases and the grain boundary migration stops after some minutes due to Zener pinning from Al 3 (Sc,Zr) precipitates produced during the heat treatment. EBSD and TEM analyses confirm both the boundary movements and the particle-boundary interactions. - Highlights: • First time that CLSM is used to study recrystallization in-situ. • The start and end of recrystallization can be directly observed. • The procedure is easy to apply and requires only simple data interpretation. • In-situ observations on the surface correlate to modifications inside the bulk. • In-situ observations correlate to EBSD and EFTEM analyses.

  13. In-situ observation of recrystallization in an AlMgScZr alloy using confocal laser scanning microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Taendl, J., E-mail: johannes.taendl@tugraz.atl [Institute of Materials Science and Welding, Graz University of Technology, Graz (Austria); Nambu, S. [Department of Materials Engineering, The University of Tokyo, Tokyo 113-8656 (Japan); Orthacker, A.; Kothleitner, G. [Institute of Electron Microscopy and Nanoanalysis, Graz University of Technology, Graz (Austria); Graz Center for Electron Microscopy, Graz (Austria); Inoue, J.; Koseki, T. [Department of Materials Engineering, The University of Tokyo, Tokyo 113-8656 (Japan); Poletti, C. [Institute of Materials Science and Welding, Graz University of Technology, Graz (Austria)

    2015-10-15

    In this work we present a novel in-situ approach to study the recrystallization behavior of age hardening alloys. We use confocal laser scanning microscopy (CLSM) at 400 °C to investigate the static recrystallization of an AlMg4Sc0.4Zr0.12 alloy in-situ. The results are combined with electron backscatter diffraction (EBSD) and transmission electron microscopy (TEM) analyses. It was found that CLSM is a powerful tool to visualize both the local initiation and temporal sequence of recrystallization. After fast nucleation and initial growth, the grain growth rate decreases and the grain boundary migration stops after some minutes due to Zener pinning from Al{sub 3}(Sc,Zr) precipitates produced during the heat treatment. EBSD and TEM analyses confirm both the boundary movements and the particle-boundary interactions. - Highlights: • First time that CLSM is used to study recrystallization in-situ. • The start and end of recrystallization can be directly observed. • The procedure is easy to apply and requires only simple data interpretation. • In-situ observations on the surface correlate to modifications inside the bulk. • In-situ observations correlate to EBSD and EFTEM analyses.

  14. Satellite observations of middle atmosphere-thermosphere vertical coupling by gravity waves

    Science.gov (United States)

    Trinh, Quang Thai; Ern, Manfred; Doornbos, Eelco; Preusse, Peter; Riese, Martin

    2018-03-01

    Atmospheric gravity waves (GWs) are essential for the dynamics of the middle atmosphere. Recent studies have shown that these waves are also important for the thermosphere/ionosphere (T/I) system. Via vertical coupling, GWs can significantly influence the mean state of the T/I system. However, the penetration of GWs into the T/I system is not fully understood in modeling as well as observations. In the current study, we analyze the correlation between GW momentum fluxes observed in the middle atmosphere (30-90 km) and GW-induced perturbations in the T/I. In the middle atmosphere, GW momentum fluxes are derived from temperature observations of the Sounding of the Atmosphere using Broadband Emission Radiometry (SABER) satellite instrument. In the T/I, GW-induced perturbations are derived from neutral density measured by instruments on the Gravity field and Ocean Circulation Explorer (GOCE) and CHAllenging Minisatellite Payload (CHAMP) satellites. We find generally positive correlations between horizontal distributions at low altitudes (i.e., below 90 km) and horizontal distributions of GW-induced density fluctuations in the T/I (at 200 km and above). Two coupling mechanisms are likely responsible for these positive correlations: (1) fast GWs generated in the troposphere and lower stratosphere can propagate directly to the T/I and (2) primary GWs with their origins in the lower atmosphere dissipate while propagating upwards and generate secondary GWs, which then penetrate up to the T/I and maintain the spatial patterns of GW distributions in the lower atmosphere. The mountain-wave related hotspot over the Andes and Antarctic Peninsula is found clearly in observations of all instruments used in our analysis. Latitude-longitude variations in the summer midlatitudes are also found in observations of all instruments. These variations and strong positive correlations in the summer midlatitudes suggest that GWs with origins related to convection also propagate up to the T

  15. Observational study of atmospheric surface layer and coastal weather in northern Qatar

    Science.gov (United States)

    Samanta, Dhrubajyoti; Sadr, Reza

    2016-04-01

    Atmospheric surface layer is the interaction medium between atmosphere and Earth's surface. Better understanding of its turbulence nature is essential in characterizing the local weather, climate variability and modeling of turbulent exchange processes. The importance of Middle East region, with its unique geographical, economical and weather condition is well recognized. However, high quality micrometeorological observational studies are rare in this region. Here we show experimental results from micrometeorological observations from an experimental site in the coastal region of Qatar during August-December 2015. Measurements of winds are obtained from three sonic anemometers installed on a 9 m tower placed at Al Ghariyah beach in northern Qatar (26.08 °N, 51.36 °E). Different surface layer characteristics is analyzed and compared with earlier studies in equivalent weather conditions. Monthly statistics of wind speed, wind direction, temperature, humidity and heat index are made from concurrent observations from sonic anemometer and weather station to explore variations with surface layer characteristics. The results also highlights potential impact of sea breeze circulation on local weather and atmospheric turbulence. The observed daily maximum temperature and heat index during morning period may be related to sea breeze circulations. Along with the operational micrometeorological observation system, a camera system and ultrasonic wave measurement system are installed recently in the site to study coastline development and nearshore wave dynamics. Overall, the complete observational set up is going to provide new insights about nearshore wind dynamics and wind-wave interaction in Qatar.

  16. Evaluation of in situ measurements of atmospheric carbon monoxide at Mount Waliguan, China

    Directory of Open Access Journals (Sweden)

    F. Zhang

    2011-06-01

    Full Text Available Quasicontinuous measurements of carbon monoxide (CO recorded over three years at Mount Waliguan (WLG, a global baseline station in remote western China, were examined using back trajectory analysis. The data include a revision to correct the working reference scale to the WMO2000 scale and corrections for drift in the reference gases. Between July 2004 and June 2007, CO exhibited large fluctuations and the 5 %, 50 % and 95 %-percentiles of relevant CO mixing ratios were 102 ppb, 126 ppb and 194 ppb. Approximately 50 % of all observed data were selected as CO background data using a mathematical procedure of robust local regression, with the remainder affected by regional-scale pollution. The monthly mean background CO mixing ratios showed a minimum in summer and a maximum in late winter, although all seasons were affected by short-term enhancements that exceeded background levels. The CO data were compared to values observed at the high alpine research station at Jungfraujoch, Switzerland. Smaller seasonal amplitudes were observed at WLG compared to the Jungfraujoch due to lower winter and spring CO levels, however, episodic enhancements of polluted air were greater at WLG. The air parcels arriving at WLG came predominately from the west, except in summer when advection from the east and southeast prevailed. Transport from the east or southeast typically brought polluted air to the site, having passed over populated urban areas upwind. A large number of elevated CO mixing ratios could also be associated with advection from the northwest of WLG via the central Xinjiang Uygur Autonomous Region (XUAR and the Ge'ermu urban area where growing industrial activities as well as crops residue burning provide sources of CO. Air masses passing over northwestern Gansu were associated with relatively high CO values suggesting an anthropogenic influence, which was likely due to anthropogenic emissions from northwestern China (based on back-trajectory and

  17. Some problems in interpretation of the New Horizons observations of Pluto's atmosphere

    Science.gov (United States)

    Krasnopolsky, Vladimir A.

    2018-02-01

    Here I briefly discuss the following problems related to Pluto's atmosphere: (1) restrictions to LTE in the rotational lines of H2O and HCN above 700 km that affect thermal balance of the atmosphere; (2) contradictions in the estimates of H2O influx from ablation of the interplanetary dust; (3) great difference between the haze volume surface area in the LORRI and MVIC observations and that in the UV solar occultations and the models, including significant corrections to sticking coefficients of C2H2, C2H4, C2H6, and HCN in condensation, and (4) Triton's thermosphere during the Voyager 2 flyby.

  18. In situ observation of syntactic foams under hydrostatic pressure using X-ray tomography

    International Nuclear Information System (INIS)

    Lachambre, J.; Maire, E.; Adrien, J.; Choqueuse, D.

    2013-01-01

    Syntactic foams (hollow glass microspheres embedded in a polymeric matrix) are being used increasingly for the purpose of thermal insulation in ultradeep water. A better understanding of the damage mechanisms of these materials at the microsphere scale under such a hydrostatic loading condition is of prior importance in determining actual material limits, improving phenomenological modelling and developing novel formulations in the future. To achieve this goal, a study based on X-ray microtomography was performed on two syntactic foam materials (polypropylene and polyurethane matrix) and a standard foamed PP. A special set up has been designed in order to allow the X-ray microtomographic observation of the material during hydrostatic pressure loading using ethanol as the pressure fluid. Spatial resolution of (3.5 μm) 3 and in situ non-destructive scanning allowed a unique qualitative and quantitative analysis of the composite microstructure during stepwise isotropic compression by hydrostatic pressure up to 50 MPa. The collapse of weaker microspheres were observed during pressure increase and the damage parameters could be estimated. It is shown that the microspheres which are broken or the porosities which are close to the surface in the foamed PP are filled by a fluid (either the ethanol or the polymeric matrix itself). The hydrostatic pressure decreases the volume of the foam only slightly. In the PU matrix, ethanol diffusion is seen to induce swelling of the matrix, which is an unexpected phenomenon but reveals the high potential of X-ray microtomographic observation to improve diffusion analysis in complex media

  19. Diagnostics of the Tropical Tropopause Layer from in-situ observations and CCM data

    Directory of Open Access Journals (Sweden)

    C. M. Volk

    2009-12-01

    Full Text Available A suite of diagnostics is applied to in-situ aircraft measurements and one Chemistry-Climate Model (CCM data to characterize the vertical structure of the Tropical Tropopause Layer (TTL. The diagnostics are based on vertical tracer profiles and relative vertical tracer gradients, using tropopause-referenced coordinates, and tracer-tracer relationships in the tropical Upper Troposphere/Lower Stratosphere (UT/LS.

    Observations were obtained during four tropical campaigns performed from 1999 to 2006 with the research aircraft Geophysica and have been compared to the output of the ECHAM5/MESSy CCM. The model vertical resolution in the TTL (~500 m allows for appropriate comparison with high-resolution aircraft observations and the diagnostics used highlight common TTL features between the model and the observational data.

    The analysis of the vertical profiles of water vapour, ozone, and nitrous oxide, in both the observations and the model, shows that concentration mixing ratios exhibit a strong gradient change across the tropical tropopause, due to the role of this latter as a transport barrier and that transition between the tropospheric and stratospheric regimes occurs within a finite layer. The use of relative vertical ozone and carbon monoxide gradients, in addition to the vertical profiles, helps to highlight the region where this transition occurs and allows to give an estimate of its thickness. The analysis of the CO-O3 and H2O-O3 scatter plots and of the Probability Distribution Function (PDF of the H2O-O3 pair completes this picture as it allows to better distinguish tropospheric and stratospheric regimes that can be identified by their different chemical composition.

    The joint analysis and comparison of observed and modelled data allows to state that the model can represent the background TTL structure and its seasonal variability rather accurately. The model

  20. Real time in situ detection of organic nitrates in atmospheric aerosols.

    Science.gov (United States)

    Rollins, Andrew W; Smith, Jared D; Wilson, Kevin R; Cohen, Ronald C

    2010-07-15

    A novel instrument is described that quantifies total particle-phase organic nitrates in real time with a detection limit of 0.11 microg m(-3) min(-1), 45 ppt min(-1) (-ONO(2)). Aerosol nitrates are separated from gas-phase nitrates with a short residence time activated carbon denuder. Detection of organic molecules containing -ONO(2) subunits is accomplished using thermal dissociation coupled to laser induced fluorescence detection of NO(2). This instrument is capable of high time resolution (seconds) measurements of particle-phase organic nitrates, without interference from inorganic nitrate. Here we use it to quantify organic nitrates in secondary organic aerosol generated from high-NO(x) photooxidation of limonene, alpha-pinene, Delta-3-carene, and tridecane. In these experiments the organic nitrate moiety is observed to be 6-15% of the total SOA mass.

  1. Hot Ta filament resistance in-situ monitoring under silane containing atmosphere

    International Nuclear Information System (INIS)

    Grunsky, D.; Schroeder, B.

    2008-01-01

    Monitoring of the electrical resistance of the Ta catalyst during the hot wire chemical vapor deposition (HWCVD) of thin silicon films gives information about filament condition. Using Ta filaments for silane decomposition not only the well known strong changes at the cold ends, but also changes of the central part of the filament were observed. Three different phenomena can be distinguished: silicide (stoichiometric Ta X Si Y alloys) growth on the filament surfaces, diffusion of Si into the Ta filament and thick silicon deposits (TSD) formation on the filament surface. The formation of different tantalum silicides on the surface as well as the in-diffusion of silicon increase the filament resistance, while the TSDs form additional electrical current channels and that result in a decrease of the filament resistance. Thus, the filament resistance behaviour during ageing is the result of the competition between these two processes

  2. Long-Term Observations of Atmospheric CO2, O3 and BrO over the Transitioning Arctic Ocean Pack-ice: The O-Buoy Chemical Network

    Science.gov (United States)

    Matrai, P.

    2016-02-01

    Autonomous, sea ice-tethered O-Buoys have been deployed (2009-2016) across the Arctic sea ice for long-term atmospheric measurements (http://www.o-buoy.org). O-Buoys (15) provide in-situ concentrations of three sentinel atmospheric chemicals, ozone, CO2 and BrO, as well as meteorological parameters and imagery, over the frozen ocean. O-Buoys were designed to transmit daily data over a period of 2 years while deployed in sea ice, as part of automated ice-drifting stations that include snow/ice measurement systems (e.g. Ice Mass Balance buoys) and oceanographic measurements (e.g. Ice Tethered Profilers). Seasonal changes in Arctic atmospheric chemistry are influenced by changes in the characteristics and presence of the sea ice vs. open water as well as air mass trajectories, especially during the winter-spring and summer-fall transitions when sea ice is melting and freezing, respectively. The O-Buoy Chemical Network provides the unique opportunity to observe these transition periods in real-time with high temporal resolution, and to compare them with those collected on land-based monitoring stations located. Due to the logistical challenges of measurements over the Arctic Ocean region, most long term, in-situ observations of atmospheric chemistry have been made at coastal or island sites around the periphery of the Arctic Ocean, leaving large spatial and temporal gaps that O-Buoys overcome. Advances in floatation, communications, power management, and sensor hardware have been made to overcome the challenges of diminished Arctic sea ice. O-Buoy data provide insights into enhanced seasonal, interannual and spatial variability in atmospheric composition, atmospheric boundary layer control on the amount of halogen activation, enhancement of the atmospheric CO2 signal over the more variable and porous pack ice, and to develop an integrated picture of the coupled ocean/ice/atmosphere system. As part of the Arctic Observing Network, we provide data to the community (www.aoncadis.org).

  3. In Situ Observation of Hard Surrounding Rock Displacement at 2400-m-Deep Tunnels

    Science.gov (United States)

    Feng, Xia-Ting; Yao, Zhi-Bin; Li, Shao-Jun; Wu, Shi-Yong; Yang, Cheng-Xiang; Guo, Hao-Sen; Zhong, Shan

    2018-03-01

    This paper presents the results of in situ investigation of the internal displacement of hard surrounding rock masses within deep tunnels at China's Jinping Underground Laboratory Phase II. The displacement evolution of the surrounding rock during the entire excavation processes was monitored continuously using pre-installed continuous-recording multi-point extensometers. The evolution of excavation-damaged zones and fractures in rock masses were also observed using acoustic velocity testing and digital borehole cameras, respectively. The results show four kinds of displacement behaviours of the hard surrounding rock masses during the excavation process. The displacement in the inner region of the surrounding rock was found to be greater than that of the rock masses near the tunnel's side walls in some excavation stages. This leads to a multi-modal distribution characteristic of internal displacement for hard surrounding rock masses within deep tunnels. A further analysis of the evolution information on the damages and fractures inside the surrounding rock masses reveals the effects of excavation disturbances and local geological conditions. This recognition can be used as the reference for excavation and supporting design and stability evaluations of hard-rock tunnels under high-stress conditions.

  4. In situ observation of the reaction of scandium and carbon by neutron diffraction

    Energy Technology Data Exchange (ETDEWEB)

    Juarez-Arellano, Erick A., E-mail: eajuarez@unpa.edu.m [Institut fuer Geowissenschaften, Universitaet Frankfurt, Altenhoeferallee 1, 60438 Frankfurt a.M. (Germany); Universidad del Papaloapan, Circuito Central 200, Parque Industrial, Tuxtepec 68301 (Mexico); Winkler, Bjorn [Institut fuer Geowissenschaften, Universitaet Frankfurt, Altenhoeferallee 1, 60438 Frankfurt a.M. (Germany); Vogel, Sven C. [Los Alamos National Laboratory, Lujan Center. Mail Stop H805, Los Alamos, NM 87545 (United States); Senyshyn, Anatoliy [Forschungsneutronenquelle Heinz Maier-Leibnitz (FRM II), Technische Universitaet Muenchen, Lichtenbergstr. 1, D-85747 Garching (Germany); Materialwissenschaft, TU Darmstadt, Petersensstr. 23, D-64287 Darmstadt (Germany); Kammler, Daniel R. [Sandia National Laboratories, Albuquerque, NM 87185 (United States); Avalos-Borja, Miguel [CNyN, UNAM, A. Postal 2681, Ensenada, B.C. (Mexico)

    2011-01-05

    Research highlights: {yields} Exist two ScC cubic phases with B1-structure type differing in site occupancy of C. {yields} A new orthorhombic scandium carbide phase is formed at 1473(50) K. {yields} The recrystallization of alpha-Sc occurs between 1000 and 1223 K. - Abstract: The formation of scandium carbides by reaction of the elements has been investigated by in situ neutron diffraction up to 1823 K. On heating, the recrystallization of {alpha}-Sc occurs between 1000 and 1223 K. The formation of Sc{sub 2}C and ScC (NaCl-B1 type structure) phases has been detected at 1323 and 1373 K, respectively. The formation of a new orthorhombic scandium carbide phase was observed at 1473(50) K. Once the scandium carbides are formed they are stable upon heating or cooling. No other phases were detected in the present study, in which the system was always carbon saturated. The thermal expansion coefficients of all phases have been determined, they are constant throughout the temperature interval studied.

  5. Observed variations in U.S. frost timing linked to atmospheric circulation patterns.

    Science.gov (United States)

    Strong, Courtenay; McCabe, Gregory J

    2017-05-23

    Several studies document lengthening of the frost-free season within the conterminous United States (U.S.) over the past century, and report trends in spring and fall frost timing that could stem from hemispheric warming. In the absence of warming, theory and case studies link anomalous frost timing to atmospheric circulation anomalies. However, recent efforts to relate a century of observed changes in U.S. frost timing to various atmospheric circulations yielded only modest correlations, leaving the relative importance of circulation and warming unclear. Here, we objectively partition the U.S. into four regions and uncover atmospheric circulations that account for 25-48% of spring and fall-frost timing. These circulations appear responsive to historical warming, and they consistently account for more frost timing variability than hemispheric or regional temperature indices. Reliable projections of future variations in growing season length depend on the fidelity of these circulation patterns in global climate models.

  6. Information Content Analysis for Selection of Optimal JWST  Observing Modes for Transiting Exoplanet Atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Batalha, Natasha E. [Department of Astronomy and Astrophysics, Pennsylvania State University, State College, PA 16802 (United States); Line, M. R., E-mail: neb149@psu.edu [School of Earth and Space Exploration, Arizona State University, Phoenix, AZ 85282 (United States)

    2017-04-01

    The James Webb Space Telescope ( JWST ) is nearing its launch date of 2018, and is expected to revolutionize our knowledge of exoplanet atmospheres. In order to specifically identify which observing modes will be most useful for characterizing a diverse range of exoplanetary atmospheres, we use an information content (IC) based approach commonly used in the studies of solar system atmospheres. We develop a system based upon these IC methods to trace the instrumental and atmospheric model phase space in order to identify which observing modes are best suited for particular classes of planets, focusing on transmission spectra. Specifically, the atmospheric parameter space we cover is T  = 600–1800 K, C/O = 0.55–1, [M/H] = 1–100 × Solar for an R  = 1.39 R{sub J}, M  = 0.59 M{sub J} planet orbiting a WASP-62-like star. We also explore the influence of a simplified opaque gray cloud on the IC. We find that obtaining broader wavelength coverage over multiple modes is preferred over higher precision in a single mode given the same amount of observing time. Regardless of the planet temperature and composition, the best modes for constraining terminator temperatures, C/O ratios, and metallicity are NIRISS SOSS+NIRSpec G395. If the target’s host star is dim enough such that the NIRSpec prism is applicable, then it can be used instead of NIRISS SOSS+NIRSpec G395. Lastly, observations that use more than two modes should be carefully analyzed because sometimes the addition of a third mode results in no gain of information. In these cases, higher precision in the original two modes is favorable.

  7. Indium hydroxide to oxide decomposition observed in one nanocrystal during in situ transmission electron microscopy studies

    Science.gov (United States)

    Miehe, Gerhard; Lauterbach, Stefan; Kleebe, Hans-Joachim; Gurlo, Aleksander

    2013-02-01

    The high-resolution transmission electron microscopy (HR-TEM) is used to study, in situ, spatially resolved decomposition in individual nanocrystals of metal hydroxides and oxyhydroxides. This case study reports on the decomposition of indium hydroxide (c-In(OH)3) to bixbyite-type indium oxide (c-In2O3). The electron beam is focused onto a single cube-shaped In(OH)3 crystal of {100} morphology with ca. 35 nm edge length and a sequence of HR-TEM images was recorded during electron beam irradiation. The frame-by-frame analysis of video sequences allows for the in situ, time-resolved observation of the shape and orientation of the transformed crystals, which in turn enables the evaluation of the kinetics of c-In2O3 crystallization. Supplementary material (video of the transformation) related to this article can be found online at 10.1016/j.jssc.2012.09.022. After irradiation the shape of the parent cube-shaped crystal is preserved, however, its linear dimension (edge) is reduced by the factor 1.20. The corresponding spotted selected area electron diffraction (SAED) pattern representing zone [001] of c-In(OH)3 is transformed to a diffuse strongly textured ring-like pattern of c-In2O3 that indicates the transformed cube is no longer a single crystal but is disintegrated into individual c-In2O3 domains with the size of about 5-10 nm. The induction time of approximately 15 s is estimated from the time-resolved Fourier transforms. The volume fraction of the transformed phase (c-In2O3), calculated from the shrinkage of the parent c-In(OH)3 crystal in the recorded HR-TEM images, is used as a measure of the kinetics of c-In2O3 crystallization within the framework of Avrami-Erofeev formalism. The Avrami exponent of ˜3 is characteristic for a reaction mechanism with fast nucleation at the beginning of the reaction and subsequent three-dimensional growth of nuclei with a constant growth rate. The structural transformation path in reconstructive decomposition of c-In(OH)3 to c

  8. Observations of leaf stomatal conductance at the canopy scale: an atmospheric modeling perspective

    International Nuclear Information System (INIS)

    Avissar, R.

    1993-01-01

    Plant stomata play a key role in the redistribution of energy received on vegetated land into sensible and latent heat. As a result, they have a considerable impact on the atmospheric planetary boundary layer, the hydrologic cycle, the climate, and the weather. Current parameterizations of the stomatal mechanism in state-of-the-art atmospheric models are based on empirical relations that are established at the leaf scale between stomatal conductance and environmental conditions. In order to evaluate these parameterizations, an experiment was carried out on a potato field in New Jersey during the summer of 1989. Stomatal conductances were measured within a small homogeneous area in the middle of the potato field and under a relatively broad range of atmospheric conditions. A large variability of stomatal conductances was observed. This variability, which was associated with the variability of micro-environmental and physiological conditions that is found even in a homogeneous canopy, cannot be simulated explicitly on the scale of a single agricultural field and,a fortiori, on the scale of atmospheric models. Furthermore, this variability could not be related to the environmental conditions measured at a height of 2 m above the plant canopy simultaneously with the conductances, reinforcing the concept of scale decoupling suggested by Jarvis and McNaughton (1986) and McNaughton and Jarvis (1991). Thus, for atmospheric modeling purposes, a parameterization of stomatal conductance at the canopy scale using external environmental forcing conditions seems more appropriate than a parameterization based on leaf-scale stomatal conductance, as currently adopted in state-of-the-art atmospheric models. The measured variability was characterized by a lognormal probability density function (pdf) that remained relatively stable during the entire measuring period. These observations support conclusions by McNaughton and Jarvis (1991) that, unlike current parameterizations, a

  9. Observations of leaf stomatal conductance at the canopy scale: an atmospheric modeling perspective

    International Nuclear Information System (INIS)

    Avissar, R.

    1993-01-01

    Plant stomata play a key role in the redistribution of energy received on vegetated land into sensible and latent heat. As a result, they have a considerable impact on the atmospheric planetary boundary layer, the hydrologic cycle, the climate, and the weather. Current parameterizations of the stomatal mechanism in state-of-the-art atmospheric models are based on empirical relations that are established at the leaf scale between stomatal conductance and environmental conditions. In order to evaluate these parameterizations, an experiment was carried out on a potato field in New Jersey during the summer of 1989. Stomatal conductances were measured within a small homogeneous area in the middle of the potato field and under a relatively broad range of atmospheric conditions. A large variability of stomatal conductances was observed. This variability, which was associated with the variability of micro-environmental and physiological conditions that is found even in a homogeneous canopy, cannot be simulated explicitly on the scale of a single agricultural field and, a fortiori, on the scale of atmospheric models. Furthermore, this variability could not be related to the environmental conditions measured at a height of 2 m above the plant canopy simultaneously with the conductances, reinforcing the concept of scale decoupling suggested by Jarvis and McNaughton (1986) and McNaughton and Jarvis (1991). Thus, for atmospheric modeling purposes, a parameterization of stomatal conductance at the canopy scale using external environmental forcing conditions seems more appropriate than a parameterization based on leaf-scale stomatal conductance, as currently adopted in state-of-the-art atmospheric models. The measured variability was characterized by a lognormal probability density function (pdf) that remained relatively stable during the entire measuring period. These observations support conclusions by McNaughton and Jarvis (1991) that, unlike current parameterizations, a

  10. Results of an interactively coupled atmospheric chemistry – general circulation model: Comparison with observations

    Directory of Open Access Journals (Sweden)

    R. Hein

    Full Text Available The coupled climate-chemistry model ECHAM4.L39(DLR/CHEM is presented which enables a simultaneous treatment of meteorology and atmospheric chemistry and their feedbacks. This is the first model which interactively combines a general circulation model with a chemical model, employing most of the important reactions and species necessary to describe the stratospheric and upper tropospheric ozone chemistry, and which is computationally fast enough to allow long-term integrations with currently available computer resources. This is possible as the model time-step used for the chemistry can be chosen as large as the integration time-step for the dynamics. Vertically the atmosphere is discretized by 39 levels from the surface up to the top layer which is centred at 10 hPa, with a relatively high vertical resolution of approximately 700 m near the extra-tropical tropopause. We present the results of a control simulation representing recent conditions (1990 and compare it to available observations. The focus is on investigations of stratospheric dynamics and chemistry relevant to describe the stratospheric ozone layer. ECHAM4.L39(DLR/CHEM reproduces main features of stratospheric dynamics in the arctic vortex region, including stratospheric warming events. This constitutes a major improvement compared to earlier model versions. However, apparent shortcomings in Antarctic circulation and temperatures persist. The seasonal and interannual variability of the ozone layer is simulated in accordance with observations. Activation and deactivation of chlorine in the polar stratospheric vortices and their inter-hemispheric differences are reproduced. Considering methane oxidation as part of the dynamic-chemistry feedback results in an improved representation of the spatial distribution of stratospheric water vapour concentrations. The current model constitutes a powerful tool to investigate, for instance, the combined direct and indirect effects of anthropogenic

  11. Observing the Atmospheres of Known Temperate Earth-sized Planets with JWST

    Science.gov (United States)

    Morley, Caroline V.; Kreidberg, Laura; Rustamkulov, Zafar; Robinson, Tyler; Fortney, Jonathan J.

    2017-12-01

    Nine transiting Earth-sized planets have recently been discovered around nearby late-M dwarfs, including the TRAPPIST-1 planets and two planets discovered by the MEarth survey, GJ 1132b and LHS 1140b. These planets are the smallest known planets that may have atmospheres amenable to detection with the James Webb Space Telescope (JWST). We present model thermal emission and transmission spectra for each planet, varying composition and surface pressure of the atmosphere. We base elemental compositions on those of Earth, Titan, and Venus and calculate the molecular compositions assuming chemical equilibrium, which can strongly depend on temperature. Both thermal emission and transmission spectra are sensitive to the atmospheric composition; thermal emission spectra are sensitive to surface pressure and temperature. We predict the observability of each planet’s atmosphere with JWST. GJ 1132b and TRAPPIST-1b are excellent targets for emission spectroscopy with JWST/MIRI, requiring fewer than 10 eclipse observations. Emission photometry for TRAPPIST-1c requires 5-15 eclipses; LHS 1140b and TRAPPIST-1d, TRAPPIST-1e, and TRAPPIST-1f, which could possibly have surface liquid water, may be accessible with photometry. Seven of the nine planets are strong candidates for transmission spectroscopy measurements with JWST, although the number of transits required depends strongly on the planets’ actual masses. Using the measured masses, fewer than 20 transits are required for a 5σ detection of spectral features for GJ 1132b and six of the TRAPPIST-1 planets. Dedicated campaigns to measure the atmospheres of these nine planets will allow us, for the first time, to probe formation and evolution processes of terrestrial planetary atmospheres beyond our solar system.

  12. Indium hydroxide to oxide decomposition observed in one nanocrystal during in situ transmission electron microscopy studies

    International Nuclear Information System (INIS)

    Miehe, Gerhard; Lauterbach, Stefan; Kleebe, Hans-Joachim; Gurlo, Aleksander

    2013-01-01

    The high-resolution transmission electron microscopy (HR-TEM) is used to study, in situ, spatially resolved decomposition in individual nanocrystals of metal hydroxides and oxyhydroxides. This case study reports on the decomposition of indium hydroxide (c-In(OH) 3 ) to bixbyite-type indium oxide (c-In 2 O 3 ). The electron beam is focused onto a single cube-shaped In(OH) 3 crystal of {100} morphology with ca. 35 nm edge length and a sequence of HR-TEM images was recorded during electron beam irradiation. The frame-by-frame analysis of video sequences allows for the in situ, time-resolved observation of the shape and orientation of the transformed crystals, which in turn enables the evaluation of the kinetics of c-In 2 O 3 crystallization. Supplementary material (video of the transformation) related to this article can be found online at (10.1016/j.jssc.2012.09.022). After irradiation the shape of the parent cube-shaped crystal is preserved, however, its linear dimension (edge) is reduced by the factor 1.20. The corresponding spotted selected area electron diffraction (SAED) pattern representing zone [001] of c-In(OH) 3 is transformed to a diffuse strongly textured ring-like pattern of c-In 2 O 3 that indicates the transformed cube is no longer a single crystal but is disintegrated into individual c-In 2 O 3 domains with the size of about 5–10 nm. The induction time of approximately 15 s is estimated from the time-resolved Fourier transforms. The volume fraction of the transformed phase (c-In 2 O 3 ), calculated from the shrinkage of the parent c-In(OH) 3 crystal in the recorded HR-TEM images, is used as a measure of the kinetics of c-In 2 O 3 crystallization within the framework of Avrami–Erofeev formalism. The Avrami exponent of ∼3 is characteristic for a reaction mechanism with fast nucleation at the beginning of the reaction and subsequent three-dimensional growth of nuclei with a constant growth rate. The structural transformation path in reconstructive

  13. NSF Lower Atmospheric Observing Facilities (LAOF) in support of science and education

    Science.gov (United States)

    Baeuerle, B.; Rockwell, A.

    2012-12-01

    Researchers, students and teachers who want to understand and describe the Earth System require high quality observations of the atmosphere, ocean, and biosphere. Making these observations requires state-of-the-art instruments and systems, often carried on highly capable research platforms. To support this need of the geosciences community, the National Science Foundation's (NSF) Division of Atmospheric and Geospace Sciences (AGS) provides multi-user national facilities through its Lower Atmospheric Observing Facilities (LAOF) Program at no cost to the investigator. These facilities, which include research aircraft, radars, lidars, and surface and sounding systems, receive NSF financial support and are eligible for deployment funding. The facilities are managed and operated by five LAOF partner organizations: the National Center for Atmospheric Research (NCAR); Colorado State University (CSU); the University of Wyoming (UWY); the Center for Severe Weather Research (CSWR); and the Center for Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS). These observational facilities are available on a competitive basis to all qualified researchers from US universities, requiring the platforms and associated services to carry out various research objectives. The deployment of all facilities is driven by scientific merit, capabilities of a specific facility to carry out the proposed observations, and scheduling for the requested time. The process for considering requests and setting priorities is determined on the basis of the complexity of a field campaign. The poster will describe available observing facilities and associated services, and explain the request process researchers have to follow to secure access to these platforms for scientific as well as educational deployments. NSF/NCAR GV Aircraft

  14. In situ observation and analysis of ultrasonic capillary effect in molten aluminium.

    Science.gov (United States)

    Tzanakis, I; Xu, W W; Eskin, D G; Lee, P D; Kotsovinos, N

    2015-11-01

    An in situ synchrotron radiographic study of a molten Al-10 wt% Cu alloy under the influence of an external ultrasonic field was carried out using the Diamond-Manchester Branchline pink X-ray imaging at the Diamond Light Source in UK. A bespoke test rig was used, consisting of an acoustic transducer with a titanium sonotrode coupled with a PID-controlled resistance furnace. An ultrasonic frequency of 30 kHz, with a peak to peak amplitude at 140 microns, was used, producing a pressure output of 16.9 MPa at the radiation surface of the 1-mm diameter sonotrode. This allowed quantification of not only the cavitation bubble formation and collapse, but there was also evidence of the previously hypothesised ultrasonic capillary effect (UCE), providing the first direct observations of this phenomenon in a molten metallic alloy. This was achieved by quantifying the re-filling of a pre-existing groove in the shape of a tube (which acted as a micro-capillary channel) formed by the oxide envelope of the liquid sample. Analytical solutions of the flow suggest that the filling process, which took place in very small timescales, was related to micro-jetting from the collapsing cavitation bubbles. In addition, a secondary mechanism of liquid penetration through the groove, which is related with the density distribution of the oxides inside the groove, and practically to the filtration of aluminium melt from oxides, was revealed. The observation of the almost instantaneous re-filling of a micro-capillary channel with the metallic melt supports the hypothesised sono-capillary effect in technologically important liquids other than water, like metallic alloys with substantially higher surface tension and density. Crown Copyright © 2015. Published by Elsevier B.V. All rights reserved.

  15. In-situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts

    Science.gov (United States)

    Masotta, M.; Ni, H.; Keppler, H.

    2013-12-01

    Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in-situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1100 to 1240 °C and 1 bar, obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate (GR) ranges from 3.4*10-6 to 5.2*10-7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density (NB) at nucleation ranges from 1.8*108 to 7.9*107 cm-3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble-size distribution (BSD) through time, the BSD's of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSD's may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow bubble nucleation already at very small degrees of supersaturation and could therefore be an important trigger for volatile release and

  16. Detection of Bay of Bengal eddies from TOPEX and in situ observations

    Digital Repository Service at National Institute of Oceanography (India)

    Gopalan, A.K.S.; Gopalakrishna, V.V.; Ali, M.M.; Sharma, R.

    good qualitative agreement with the subsurface isotherm features (troughs and ridges) of the in situ temperature profiles. However, this agreement does not extend to the surface and hence SST patterns are not good indicators of eddy positions in the Bay...

  17. Atmospheric structure and helium abundance on Saturn from Cassini/UVIS and CIRS observations

    Science.gov (United States)

    Koskinen, T. T.; Guerlet, S.

    2018-06-01

    We combine measurements from stellar occultations observed by the Cassini Ultraviolet Imaging Spectrograph (UVIS) and limb scans observed by the Composite Infrared Spectrometer (CIRS) to create empirical atmospheric structure models for Saturn corresponding to the locations probed by the occultations. The results cover multiple locations at low to mid-latitudes between the spring of 2005 and the fall of 2015. We connect the temperature-pressure (T-P) profiles retrieved from the CIRS limb scans in the stratosphere to the T-P profiles in the thermosphere retrieved from the UVIS occultations. We calculate the altitudes corresponding to the pressure levels in each case based on our best fit composition model that includes H2, He, CH4 and upper limits on H. We match the altitude structure to the density profile in the thermosphere that is retrieved from the occultations. Our models depend on the abundance of helium and we derive a volume mixing ratio of 11 ± 2% for helium in the lower atmosphere based on a statistical analysis of the values derived for 32 different occultation locations. We also derive the mean temperature and methane profiles in the upper atmosphere and constrain their variability. Our results are consistent with enhanced heating at the polar auroral region and a dynamically active upper atmosphere.

  18. Atmospheric monitoring in the millimetre and submillimetre bands for cosmological observations: CASPER2

    Science.gov (United States)

    De Petris, M.; De Gregori, S.; Decina, B.; Lamagna, L.; Pardo, J. R.

    2013-02-01

    Cosmological observations from ground at millimetre and submillimetre wavelengths are affected by atmospheric absorption and consequent emission. The low- and high-frequency (sky-noise) fluctuations of atmospheric performance necessitate careful observational strategies and/or instrumental technical solutions. Measurements of atmospheric emission spectra are necessary for accurate calibration procedures as well as for site-testing statistics. CASPER2, an instrument designed to explore the 90-450 GHz (3-15 cm-1) spectral region, was developed and had its operation verified in the Alps. A Martin-Puplett interferometer (MPI) operates by comparing sky radiation, coming from a field of view (FOV) of 28 arcmin (full width at half-maximum) and collected by a 62-cm-diameter Pressman-Camichel telescope, with a reference source. The signals at the two output ports of the interferometer are detected by two bolometers cooled to 300 mK inside a wet cryostat. Three different but complementary interferometric techniques can be performed with CASPER2: amplitude modulation (AM), fast-scan (FS) and phase modulation (PM). An altazimuthal mount allows sky pointing, possibly co-aligned with the optical axis of the 2.6-m-diameter telescope of MITO (Millimetre and Infrared Testagrigia Observatory, Italy). The optimal time-scale to average acquired spectra is inferred by Allan variance analysis at five fiducial frequencies. We present the motivation for and design of the atmospheric spectrometer CASPER2. The procedure adopted to calibrate the instrument and the preliminary performance of it are described. Instrument capabilities were checked during the summer observational campaign at MITO in 2010 July by measuring atmospheric emission spectra with the three procedures.

  19. Challenges in the Management and Stewardship of Airborne Observational Data at the National Center for Atmospheric Research (NCAR) Earth Observing Laboratory (EOL)

    Science.gov (United States)

    Aquino, J.; Daniels, M. D.

    2015-12-01

    The National Science Foundation (NSF) provides the National Center for Atmospheric Research (NCAR) Earth Observing Laboratory (EOL) funding for the operation, maintenance and upgrade of two research aircraft: the NSF/NCAR High-performance Instrumented Airborne Platform for Environmental Research (HIAPER) Gulfstream V and the NSF/NCAR Hercules C-130. A suite of in-situ and remote sensing airborne instruments housed at the EOL Research Aviation Facility (RAF) provide a basic set of measurements that are typically deployed on most airborne field campaigns. In addition, instruments to address more specific research requirements are provided by collaborating participants from universities, industry, NASA, NOAA or other agencies (referred to as Principal Investigator, or PI, instruments). At the 2014 AGU Fall Meeting, a poster (IN13B-3639) was presented outlining the components of Airborne Data Management included field phase data collection, formats, data archival and documentation, version control, storage practices, stewardship and obsolete data formats, and public data access. This talk will cover lessons learned, challenges associated with the above components, and current developments to address these challenges, including: tracking data workflows for aircraft instrumentation to facilitate identification, and correction, of gaps in these workflows; implementation of dataset versioning guidelines; and assignment of Digital Object Identifiers (DOIs) to data and instrumentation to facilitate tracking data and facility use in publications.

  20. Observed decrease in atmospheric mercury explained by global decline in anthropogenic emissions

    Science.gov (United States)

    Yanxu Zhang,; Daniel J. Jacob,; Hannah M. Horowitz,; Long Chen,; Helen M. Amos,; Krabbenhoft, David P.; Franz Slemr,; Vincent L. St. Louis,; Elsie M. Sunderland,

    2015-01-01

    Observations of elemental mercury (Hg0) at sites in North America and Europe show large decreases (∼1–2% y−1) from 1990 to present. Observations in background northern hemisphere air, including Mauna Loa Observatory (Hawaii) and CARIBIC (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) aircraft flights, show weaker decreases (inventories indicating flat or increasing emissions over that period. However, the inventories have three major flaws: (i) they do not account for the decline in atmospheric release of Hg from commercial products; (ii) they are biased in their estimate of artisanal and small-scale gold mining emissions; and (iii) they do not properly account for the change in Hg0/HgII speciation of emissions from coal-fired utilities after implementation of emission controls targeted at SO2 and NOx. We construct an improved global emission inventory for the period 1990 to 2010 accounting for the above factors and find a 20% decrease in total Hg emissions and a 30% decrease in anthropogenic Hg0 emissions, with much larger decreases in North America and Europe offsetting the effect of increasing emissions in Asia. Implementation of our inventory in a global 3D atmospheric Hg simulation [GEOS-Chem (Goddard Earth Observing System-Chemistry)] coupled to land and ocean reservoirs reproduces the observed large-scale trends in atmospheric Hg0 concentrations and in HgII wet deposition. The large trends observed in North America and Europe reflect the phase-out of Hg from commercial products as well as the cobenefit from SO2 and NOx emission controls on coal-fired utilities.

  1. Sideband characterization and atmospheric observations with various 340 GHz heterodyne receivers

    Energy Technology Data Exchange (ETDEWEB)

    Renker, Matthias, E-mail: renker@iap.unibe.ch; Murk, Axel [Institute of Applied Physics, University of Bern, Bern (Switzerland); Rea, Simon P. [STFC Rutherford Appleton Laboratory, Didcot, Oxfordshire (United Kingdom); Emrich, A.; Frisk, U. [OMNISYS Instruments, Västra Frölunda (Sweden)

    2014-08-15

    This paper describes sideband response measurements and atmospheric observations with a double sideband and two Single Sideband (SSB) receiver prototypes developed for the multi-beam limb sounder instrument stratosphere-troposphere exchange and climate monitor radiometer. We first show an advanced Fourier-Transform Spectroscopy (FTS) method for sideband response and spurious signal characterization. We then present sideband response measurements of the different prototype receivers and we compare the results of the SSB receivers with sideband measurements by injecting a continuous wave signal into the upper and lower sidebands. The receivers were integrated into a total-power radiometer and atmospheric observations were carried out. The observed spectra were compared to forward model spectra to conclude on the sideband characteristics of the different receivers. The two sideband characterization methods show a high degree of agreement for both SSB receivers with various local oscillator settings. The measured sideband response was used to correct the forward model simulations. This improves the agreement with the atmospheric observations and explains spectral features caused by an unbalanced sideband response. The FTS method also allows to quantify the influence of spurious harmonic responses of the receiver.

  2. A Pilot Study to Evaluate California's Fossil Fuel CO2 Emissions Using Atmospheric Observations

    Science.gov (United States)

    Graven, H. D.; Fischer, M. L.; Lueker, T.; Guilderson, T.; Brophy, K. J.; Keeling, R. F.; Arnold, T.; Bambha, R.; Callahan, W.; Campbell, J. E.; Cui, X.; Frankenberg, C.; Hsu, Y.; Iraci, L. T.; Jeong, S.; Kim, J.; LaFranchi, B. W.; Lehman, S.; Manning, A.; Michelsen, H. A.; Miller, J. B.; Newman, S.; Paplawsky, B.; Parazoo, N.; Sloop, C.; Walker, S.; Whelan, M.; Wunch, D.

    2016-12-01

    Atmospheric CO2 concentration is influenced by human activities and by natural exchanges. Studies of CO2 fluxes using atmospheric CO2 measurements typically focus on natural exchanges and assume that CO2 emissions by fossil fuel combustion and cement production are well-known from inventory estimates. However, atmospheric observation-based or "top-down" studies could potentially provide independent methods for evaluating fossil fuel CO2 emissions, in support of policies to reduce greenhouse gas emissions and mitigate climate change. Observation-based estimates of fossil fuel-derived CO2 may also improve estimates of biospheric CO2 exchange, which could help to characterize carbon storage and climate change mitigation by terrestrial ecosystems. We have been developing a top-down framework for estimating fossil fuel CO2 emissions in California that uses atmospheric observations and modeling. California is implementing the "Global Warming Solutions Act of 2006" to reduce total greenhouse gas emissions to 1990 levels by 2020, and it has a diverse array of ecosystems that may serve as CO2 sources or sinks. We performed three month-long field campaigns in different seasons in 2014-15 to collect flask samples from a state-wide network of 10 towers. Using measurements of radiocarbon in CO2, we estimate the fossil fuel-derived CO2 present in the flask samples, relative to marine background air observed at coastal sites. Radiocarbon (14C) is not present in fossil fuel-derived CO2 because of radioactive decay over millions of years, so fossil fuel emissions cause a measurable decrease in the 14C/C ratio in atmospheric CO2. We compare the observations of fossil fuel-derived CO2 to simulations based on atmospheric modeling and published fossil fuel flux estimates, and adjust the fossil fuel flux estimates in a statistical inversion that takes account of several uncertainties. We will present the results of the top-down technique to estimate fossil fuel emissions for our field

  3. In-situ investigation on the oxidation behaviour of low alloyed steels annealed under N{sub 2}-5%H{sub 2} protective atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, C.; Cremer, R. [RWTH Aachen (Germany). Lehrstuhl fuer Theoretische Huettenkunde; Loison, D. [Institut de Recherches de la Siderurgie Francaise (IRSID), 57 - Maizieres-les-Metz (France); Servais, J.P. [Centre de Recherches Metallurgiques, Liege (Belgium)

    2001-12-01

    The oxidation behaviour of low alloyed steels, Fe-0.6%Mn and Fe-1.5%Mn, under different annealing conditions was studied. Due to the crucial importance of the surface state of the sample, the experiments were performed in an in-situ device to avoid any contact with air after the annealings. The annealing experiments were carried out under different conditions: high vacuum ({proportional_to}10{sup -6} mbar), N{sub 2}/H{sub 2} protective atmospheres with traces of water (dew point -30 C) and temperatures ranging from 873 to 1073 K. Under this variety of heat treatments, the reconstruction of the Fe surface and the formation of different oxides was observed and characterised, paying special attention to the selective oxidation of manganese. The surface structure and composition was investigated by means of the combined use of reflection high-energy electron diffraction (RHEED) and X-ray photoelectron spectroscopy (XPS). The analyses show that the use of RHEED is a good alternative for determining the crystallographic structure of the outermost layers of the surface. With this technique the structures of iron and manganese oxides can be distinguished despite the similar structures and lattice parameters. It is also possible to identify the crystallographic textures present on the oxidation products and to give qualitative information about the surface reconstruction of the grains. (orig.)

  4. Comparison of the HadGEM2 climate-chemistry model against in situ and SCIAMACHY atmospheric methane data

    Directory of Open Access Journals (Sweden)

    G. D. Hayman

    2014-12-01

    Full Text Available Wetlands are a major emission source of methane (CH4 globally. In this study, we evaluate wetland emission estimates derived using the UK community land surface model (JULES, the Joint UK Land Earth Simulator against atmospheric observations of methane, including, for the first time, total methane columns derived from the SCIAMACHY instrument on board the ENVISAT satellite. Two JULES wetland emission estimates are investigated: (a from an offline run driven with Climatic Research Unit–National Centers for Environmental Prediction (CRU-NCEP meteorological data and (b from the same offline run in which the modelled wetland fractions are replaced with those derived from the Global Inundation Extent from Multi-Satellites (GIEMS remote sensing product. The mean annual emission assumed for each inventory (181 Tg CH4 per annum over the period 1999–2007 is in line with other recently published estimates. There are regional differences as the unconstrained JULES inventory gives significantly higher emissions in the Amazon (by ~36 Tg CH4 yr−1 and lower emissions in other regions (by up to 10 Tg CH4 yr−1 compared to the JULES estimates constrained with the GIEMS product. Using the UK Hadley Centre's Earth System model with atmospheric chemistry (HadGEM2, we evaluate these JULES wetland emissions against atmospheric observations of methane. We obtain improved agreement with the surface concentration measurements, especially at high northern latitudes, compared to previous HadGEM2 runs using the wetland emission data set of Fung et al. (1991. Although the modelled monthly atmospheric methane columns reproduce the large-scale patterns in the SCIAMACHY observations, they are biased low by 50 part per billion by volume (ppb. Replacing the HadGEM2 modelled concentrations above 300 hPa with HALOE–ACE assimilated TOMCAT output results in a significantly better agreement with the SCIAMACHY observations. The use of the GIEMS product to constrain the JULES

  5. Plasma Observations During the Mars Atmospheric Plume Event of March-April 2012

    Science.gov (United States)

    Andrews, D. J.; Barabash, S.; Edberg, N. J. T.; Gurnett, D. A.; Hall, B. E. S.; Holmstrom, M.; Lester, M.; Morgan, D. D.; Opgenoorth, H. J.; Ramstad, R.; hide

    2016-01-01

    We present initial analysis and conclusions from plasma observations made during the reported Mars Dust plume event of March - April 2012. During this period, multiple independent amateur observers detected a localized, high-altitude plume over the Martian dawn terminator [Sanchez-Lavega7 et al., Nature, 2015, doi:10.1038nature14162], the origin of which remains to be explained. We report on in-situ measurements of ionospheric plasma density and solar wind parameters throughout this interval made by Mars Express, obtained over the surface region, but at the opposing terminator. We tentatively conclude that the formation and/or transport of this plume to the altitudes where it was observed could be due in part the result of a large interplanetary coronal mass ejection (ICME) encountering the Martian system. Interestingly, we note that a similar plume detection in May 1997 may also have been associated with a large ICME impact at Mars.

  6. A phase-space approach to atmospheric dynamics based on observational data. Theory and applications

    International Nuclear Information System (INIS)

    Wang Risheng.

    1994-01-01

    This thesis is an attempt to develop systematically a phase-space approach to the atmospheric dynamics based on the theoretical achievement and application experiences in nonlinear time-series analysis. In particular, it is concerned with the derivation of quantities for describing the geometrical structure of the observed dynamics in phase-space (dimension estimation) and the examination of the observed atmospheric fluctuations in the light of phase-space representation. The thesis is, therefore composed of three major parts, i.e. an general survey of the theory of statistical approaches to dynamic systems, the methodology designed for the present study and specific applications with respect to dimension estimation and to a phase-space analysis of the tropical stratospheric quasi-biennial oscillation. (orig./KW)

  7. Venus surface peeking through the atmosphere - gaining a global perspective on the surface composition through near infrared observations

    Science.gov (United States)

    Helbert, J.; Dyar, M. D.; Maturilli, A.; D'Amore, M.; Ferrari, S.; Mueller, N. T.; Smrekar, S. E.

    2017-12-01

    Venus is the most Earth-like of the terrestrial planets, though very little is known about its surface composition. Thanks to recent advances in laboratory spectroscopy and spectral analysis techniques, this is about to change. Although the atmosphere prohibits observations of the surface with traditional imaging techniques over much of the EM spectral range, five transparent windows between 0.86 µm and 1.18 µm occur in the atmosphere's CO2 spectrum. New high temperature laboratory spectra from the Planetary Spectroscopy Laboratory at DLR show that spectra in these windows are highly diagnostic for surface mineralogy [1]. The Venus Emissivity Mapper (VEM) [2] builds on these recent advances. It is proposed for NASA's Venus Origins Explorer where a radar will provided the needed high-resolution altimetry and ESA's EnVision would provide stereo topography instead. VEM is the first flight instrument specially designed to focus solely on mapping Venus' surface using the windows around 1 µm. Operating in situ from Venus orbit, VEM will provide a global map of composition as well as redox state of the surface, enabling a comprehensive picture of surface-atmosphere interaction on Venus. VEM will return a complex data set containing surface, atmospheric, cloud, and scattering information. Total planned data volume for a typical mission scenario exceeds 1TB. Classical analysis techniques have been successfully used for VIRTIS on Venus Express [3-5] and could be employed with the VEM data. However, application of machine learning approaches to this rich dataset is vastly more efficient, as has already been confirmed with laboratory data. Binary classifiers [6] demonstrate that at current best estimate errors, basalt spectra are confidently discriminated from basaltic andesites, andesites, and rhyolite/granite. Applying the approach of self-organizing maps to the increasingly large set of laboratory measurements allows searching for additional mineralogical indicators

  8. Dynamics of the middle atmosphere as observed by the ARISE project

    Science.gov (United States)

    Blanc, E.

    2015-12-01

    It has been strongly demonstrated that variations in the circulation of the middle atmosphere influence weather and climate all the way to the Earth's surface. A key part of this coupling occurs through the propagation and breaking of planetary and gravity waves. However, limited observations prevent to faithfully reproduce the dynamics of the middle atmosphere in numerical weather prediction and climate models. The main challenge of the ARISE (Atmospheric dynamics InfraStructure in Europe) project is to combine existing national and international observation networks including: the International infrasound monitoring system developed for the CTBT (Comprehensive nuclear-Test-Ban Treaty) verification, the NDACC (Network for the Detection of Atmospheric Composition Changes) lidar network, European observation infrastructures at mid latitudes (OHP observatory), tropics (Maïdo observatory), high latitudes (ALOMAR and EISCAT), infrasound stations which form a dense European network and satellites. The ARISE network is unique by its coverage (polar to equatorial regions in the European longitude sector), its altitude range (from troposphere to mesosphere and ionosphere) and the involved scales both in time (from seconds to tens of years) and space (from tens of meters to thousands of kilometers). Advanced data products are produced with the scope to assimilate data in the Weather Prediction models to improve future forecasts over weeks and seasonal time scales. ARISE observations are especially relevant for the monitoring of extreme events such as thunderstorms, volcanoes, meteors and at larger scales, deep convection and stratospheric warming events for physical processes description and study of long term evolution with climate change. Among the applications, ARISE fosters integration of innovative methods for remote detection of non-instrumented volcanoes including distant eruption characterization to provide notifications with reliable confidence indices to the

  9. Coupling between the lower and middle atmosphere observed during a very severe cyclonic storm 'Madi'

    Science.gov (United States)

    Hima Bindu, H.; Venkat Ratnam, M.; Yesubabu, V.; Narayana Rao, T.; Eswariah, S.; Naidu, C. V.; Vijaya Bhaskara Rao, S.

    2018-04-01

    Synoptic-scale systems like cyclones can generate broad spectrum of waves, which propagate from its source to the middle atmosphere. Coupling between the lower and middle atmosphere over Tirupati (13.6°N, 79.4°E) is studied during a very severe cyclonic storm 'Madi' (06-13 December 2013) using Weather Research and Forecast (WRF) model assimilated fields and simultaneous meteor radar observations. Since high temporal and spatial measurements are difficult to obtain during these disturbances, WRF model simulations are obtained by assimilating conventional and satellite observations using 3DVAR technique. The obtained outputs are validated for their consistency in predicting cyclone track and vertical structure by comparing them with independent observations. The good agreement between the assimilated outputs and independent observations prompted us to use the model outputs to investigate the gravity waves (GWs) and tides over Tirupati. GWs with the periods 1-5 h are observed with clear downward phase propagation in the lower stratosphere. These upward propagating waves obtained from the model are also noticed in the meteor radar horizontal wind observations in the MLT region (70-110 km). Interestingly, enhancement in the tidal activity in both the zonal and meridional winds in the mesosphere and lower thermosphere (MLT) region is noticed during the peak cyclonic activity except the suppression of semi-diurnal tide in meridional wind. A very good agreement in the tidal activity is also observed in the horizontal winds in the troposphere and lower stratosphere from the WRF model outputs and ERA5. These results thus provide evidence on the vertical coupling of lower and middle atmosphere induced by the tropical cyclone.

  10. The Nitrous Oxide (N2O) Budget: Constraints from Atmospheric Observations and Models

    Science.gov (United States)

    Tian, H.; Thompson, R.; Canadell, J.; Winiwarter, W.; Tian, H.; Thompson, R.; Prather, M. J.

    2017-12-01

    The increasing global abundance of N2O poses a threat to human health and society over this coming century through both climate change and ozone depletion. In the sense of greenhouse gases, N2O ranks third behind CO2 and CH4. In the sense of ozone depletion, N2O stands alone. In order to identify the cause of these increases and hopefully reverse them, we need to have a thorough understanding of the sources and sinks (a.k.a. the budget) of N2O and how they can be altered. A bottom-up approach to the budget evaluates individual biogeochemical sources of N2O from the land and ocean; whereas, a top-down approach uses atmospheric observations of the variability, combined with modeling of the atmospheric chemistry and transport, to infer the magnitude of sources and sinks throughout the Earth system. This paper reviews top-down approaches using atmospheric data; a similar top-down approach can be taken with oceanic measurements of N2O, but is not covered here. Stratospheric chemistry is the predominant loss of N2O, and here we review how a merging of new measurements with stratospheric chemistry models is able to provide a constrained budget for the global N2O sink. N2O surface sources are transported and mixed throughout the atmosphere, providing positive anomalies in the N2O abundance (mole fraction of N2O with respect to dry air); while N2O-depleted air from the stratosphere provides negative anomalies. With accurate atmospheric transport models, including for stratosphere-troposphere exchange, the observed tropospheric variability in N2O is effectively a fingerprint of the location and magnitude of sources. This inverse modeling of sources is part of the top-down constraints and is reviewed here.

  11. Differences in rain rate intensities between TRMM observations and community atmosphere model simulations

    Science.gov (United States)

    Deng, Yi; Bowman, Kenneth P.; Jackson, Charles

    2007-01-01

    Precipitation related latent heating is important in driving the atmospheric general circulation and in generating intraseasonal to decadal atmospheric variability. Our ability to project future climate change, especially trends in costly precipitation extremes, hinges upon whether coupled GCMs capture processes that affect precipitation characteristics. Our study compares the tropical-subtropical precipitation characteristics of simulations by the NCAR CAM3.1 atmospheric GCM and observations derived from the NASA Tropical Rainfall Measuring Mission (TRMM) satellite. Despite a fairly good simulation of the annual mean rain rate, CAM rains about 10-50% more often than the real world and fails to capture heavy rainfall associated with deep convective systems over subtropical South America and U.S. Southern Plains. When it rains, there is a likelihood of 0.96-1.0 that it rains lightly in the model, compared to values of 0.84-1.0 in TRMM data. On the other hand, the likelihood of the occurrence of moderate to heavy rainfall is an order of magnitude higher in observations (0.12-0.2) than that in the model (model compensates for the lack of heavy precipitation through raining more frequently within the light rain category, which leads to an annual rainfall amount close to what is observed. CAM captures the qualitative change of rain rate PDF from a "dry" oceanic to a "wet" oceanic region, but it fails to simulate the change of precipitation characteristics from an oceanic region to a land region where thunderstorm rainfall dominates.

  12. An observational study of the evolution of the atmospheric boundary-layer over Cabo Frio, Brazil

    Directory of Open Access Journals (Sweden)

    S. H. Franchito

    2007-08-01

    Full Text Available The effect of coastal upwelling on the evolution of the atmospheric boundary layer (ABL in Cabo Frio (Brazil is investigated. For this purpose, radiosounding data collected in two experiments made during the austral summer (upwelling case and austral winter (no upwelling case are analysed. The results show that during the austral summer, cold waters that crop up near the Cabo Frio coast favour the formation of an atmospheric stable layer, which persists during the upwelling episode. Due to the low SSTs, the descending branch of the sea-breeze circulation is located close to the coast, inhibiting the development of a mixed layer mainly during the day. At night, with the reduction of the land-sea thermal contrast the descending motion is weaker, allowing a vertical mixing. The stable ABL favours the formation of a low level jet, which may also contribute to the development of a nocturnal atmospheric mixed layer. During the austral winter, due to the higher SSTs observed near the coast, the ABL is less stable compared with that in the austral summer. Due to warming, a mixed layer is observed during the day. The observed vertical profiles of the zonal winds show that the easterlies at low levels are stronger in the austral summer, indicating that the upwelling modulates the sea-breeze signal, thus confirming model simulations.

  13. Modeling Exoplanetary Atmospheres using BART, TEA, and Drift-RHD; Theoretical studies and Observational Implications

    Science.gov (United States)

    Dobbs-Dixon, Ian

    The explosion in the number of exoplanets detected to date has revealed a surprising diversity. When attempting to model this diversity, it is crucial to account for the uncertainties resulting from our limited knowledge of chemical, dynamical, and cloud formation processes in their atmospheres. Combining a retrieval technique with theorydriven models is a particularly promising way to address these processes and constrain a physically plausible atmospheric structure. In particular, a detailed micro-physical treatment of clouds and the longitudinal and latitudinal assessments of temperature and chemical profiles, have yet to be addressed in the field. Our team members are experts in radiative-hydrodynamic modeling (Dr. Ian DobbsDixon), cloud kinetics (Dr. Christiana Helling), retrievals and thermo-equilibrium chemistry (Dr. Jasmina Blecic), and observational diagnostics and predictions (Dr. Thomas Greene). The key goals of this proposal are to extend our understanding of the 3D atmospheric structure of gas-giant exoplanets by coupling state-of-the-art selfconsistent models together with a retrieval framework to 1) address cloud kinetics in retrievals, 2) assess 3D temperature and chemical structures in retrievals, 3) model a suite of well-observed planets within the framework of our models, and 4) make observational predictions for current and future NASA missions. To address these goals we have developed a number of tools: Drift-RHD, TEA, BART, and OBS. Drift-RHD solves both the 3D radiative-hydrodynamic equations and a time dependent kinetic cloud model. TEA, Thermochemical Equilibrium Abundances, calculates abundances of chemical species present in the atmosphere. BART, a Bayesian Atmospheric Radiative Transfer code, is a statistical retrieval framework to explore the parameter space of atmospheric chemical abundances and thermal profiles. OBS is a suite of tools developed to simulate observations. Though these tools exist and have been utilized independently in

  14. The Atmospheric Scanning Electron Microscope with open sample space observes dynamic phenomena in liquid or gas.

    Science.gov (United States)

    Suga, Mitsuo; Nishiyama, Hidetoshi; Konyuba, Yuji; Iwamatsu, Shinnosuke; Watanabe, Yoshiyuki; Yoshiura, Chie; Ueda, Takumi; Sato, Chikara

    2011-12-01

    Although conventional electron microscopy (EM) requires samples to be in vacuum, most chemical and physical reactions occur in liquid or gas. The Atmospheric Scanning Electron Microscope (ASEM) can observe dynamic phenomena in liquid or gas under atmospheric pressure in real time. An electron-permeable window made of pressure-resistant 100 nm-thick silicon nitride (SiN) film, set into the bottom of the open ASEM sample dish, allows an electron beam to be projected from underneath the sample. A detector positioned below captures backscattered electrons. Using the ASEM, we observed the radiation-induced self-organization process of particles, as well as phenomena accompanying volume change, including evaporation-induced crystallization. Using the electrochemical ASEM dish, we observed tree-like electrochemical depositions on the cathode. In silver nitrate solution, we observed silver depositions near the cathode forming incidental internal voids. The heated ASEM dish allowed observation of patterns of contrast in melting and solidifying solder. Finally, to demonstrate its applicability for monitoring and control of industrial processes, silver paste and solder paste were examined at high throughput. High resolution, imaging speed, flexibility, adaptability, and ease of use facilitate the observation of previously difficult-to-image phenomena, and make the ASEM applicable to various fields. Copyright © 2011 Elsevier B.V. All rights reserved.

  15. In situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts

    Science.gov (United States)

    Masotta, M.; Ni, H.; Keppler, H.

    2014-02-01

    Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1,100 to 1,240 °C and 0.1 MPa (1 bar), obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate ( G R) ranges from 3.4 × 10-6 to 5.2 × 10-7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density ( N B) at nucleation ranges from 7.9 × 104 mm-3 to 1.8 × 105 mm-3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble size distribution (BSD) through time, the BSDs of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSDs may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow bubble nucleation already at very small degrees of supersaturation and could therefore be an important

  16. A telescope for observation from space of extreme lightnings in the upper atmosphere

    International Nuclear Information System (INIS)

    Nam, S.; Artikova, S.; Chung, T.; Garipov, G.; Jeon, J.A.; Jeong, S.; Jin, J.Y.; Khrenov, B.A.; Kim, J.E.; Kim, M.; Kim, Y.K.; Klimov, P.; Lee, J.; Lee, H.Y.; Na, G.W.; Oh, S.J.; Panasyuk, M.; Park, I.H.; Park, J.H.; Park, Y.-S.

    2008-01-01

    A new type of telescope with a wide field-of-view and functions of fast zoom-in has been introduced. Two kinds of MEMS (Micro-Electro-Mechanical Systems) micromirrors, digital and analog, are used for reflectors of the telescope, placed at different focal lengths. We apply this technology to the observation from space of TLE (Transient Luminous Events), extremely large transient sparks occurring at the upper atmosphere. TLE are one type of important backgrounds to be understood for future space observation of UHECR (Ultra-High Energy Cosmic Rays). The launch of the payload carried by a Russian microsatellite is foreseen in the middle of 2008

  17. Quasi-periodic fluctuations of atmospheric pressure and cosmic rays observed in the stratosphere

    International Nuclear Information System (INIS)

    Kodama, Masahiro; Abe, Toshiaki; Sakai, Takasuke; Kato, Masato; Kogami, Shinichi.

    1976-01-01

    Quasi-periodicities of barometric pressure and cosmic ray intensity, with 5.5-minute period and one hour persistency, have been observed by means of a high-precision barometer and a large plastic scintillation counter in a balloon at an altitude of --18 km over the Pacific Ocean. From characteristics of such short period fluctuations, it is suggested that the observed pressure fluctuation may possibly be caused by the internal atmospheric gravity wave whose amplitude and wave length are --30 m and --30 km respectively. (auth.)

  18. First observation of the fourth neutral polarization point in the atmosphere

    Science.gov (United States)

    Horvath, Gabor; Bernath, Balazs; Suhai, Bence; Barta, Andras; Wehner, Rudiger

    2002-10-01

    In the clear sky there are three commonly known loci, the Arago, Babinet, and Brewster neutral points, where the skylight is unpolarized. These peculiar celestial points, bearing the names of their discoverers, have been the subject of many ground-based investigations, because their positions are sensitive indicators of the amount and type of atmospheric turbidity. According to theoretical considerations and computer simulations, there should exist an additional neutral point approximately opposite to the Babinet point, which can be observed only at higher altitudes in the air or space. Until now, this anonymous fourth neutral point has not been observed during air- or space-borne polarimetric experiments and has been forgotten, in spite of the fact that the neutral points were a basic tool in atmospheric research for a century. Here, we report on the first observation of this fourth neutral point from a hot air balloon. Using 180-field-of-view imaging polarimetry, we could observe the fourth neutral point at 450, 550, and 650 nm from different altitudes between 900 and 3500 m during and after sunrise at approximately 2240 below the anti-solar point along the anti-solar meridian, depending on the wavelength and solar elevation. We show that the fourth neutral point exists at the expected location and has characteristics similar to those of the Arago, Babinet, and Brewster points. We discuss why the fourth neutral point has not been observed in previous air- or space-borne polarimetric experiments. 2002 Optical Society of America

  19. Mars atmosphere studies with the SPICAM IR emission phase function observations

    Science.gov (United States)

    Trokhimovskiy, Alexander; Fedorova, Anna; Montmessin, Franck; Korablev, Oleg; Bertaux, Jean-Loup

    Emission Phase Function (EPF) observations is a powerful tool for characterization of atmosphere and surface. EPF sequence provides the extensive coverage of scattering angles above the targeted surface location which allow to separate the surface and aerosol scattering, study a vertical distribution of minor species and aerosol properties. SPICAM IR instrument on Mars Express mission provides continuous atmospheric observations in near IR (1-1.7 mu) in nadir and limb starting from 2004. For the first years of SPICAM operation only a very limited number of EPFs was performed. But from the mid 2013 (Ls=225, MY31) SPICAM EPF observations become rather regular. Based on the multiple-scattering radiative transfer model SHDOM, we analyze equivalent depths of carbon dioxide (1,43 mu) and water vapour (1,38 mu) absorption bands and their dependence on airmass during observation sequence to get aerosol optical depths and properties. The derived seasonal dust opacities from near IR can be used to retrieve the size distribution from comparison with simultaneous results of other instruments in different spectral ranges. Moreover, the EPF observations of water vapour band allow to access poorly known H2O vertical distribution for different season and locations.

  20. Regional scale variations of atmospheric CO2 and CH4 from satellite observation

    International Nuclear Information System (INIS)

    Ru, F; Lei, L; Guan, X; Bu, R; Qi, J

    2014-01-01

    To identify the sources, sinks and changes of atmospheric CO 2 and CH 4 , this study investigates the spatio-temporal changes of atmospheric CO 2 and CH 4 concentration on the regional scale by the satellite observations. In this paper, choosing the land region of China as the study area, we investigate the spatio-temporal changes of atmospheric CO 2 and CH 4 concentrations using the data of the CO 2 dry air mixing ratio (XCO 2 ), and the CH 4 dry air mixing ratio (XCH 4 ), retrieved by the Greenhouse Gases Observing Satellite (GOSAT) from Jan. 2010 to Dec. 2012. The results show that (1) both XCO 2 and XCH 4 show higher concentrations in southeastern regions than that in the northwestern, and tend to yearly increasing from 2010 to 2013; (2) XCO 2 shows obvious seasonal change with higher values in the spring than that in summer. The seasonal peak-to-peak amplitude is 8 ppm and the annual growth is about 2 ppm. XCH 4 , however, does not show a seasonal change; (3) With regard to different land-use backgrounds, XCO 2 shows larger concentrations over the areas of urban agglomeration than that over the grasslands and deserts, and XCH 4 shows lower concentrations over deserts than that over the Yangtze River Delta region and Sichuan Basin

  1. NEPTUNE'S DYNAMIC ATMOSPHERE FROM KEPLER K2 OBSERVATIONS: IMPLICATIONS FOR BROWN DWARF LIGHT CURVE ANALYSES.

    Science.gov (United States)

    Simon, Amy A; Rowe, Jason F; Gaulme, Patrick; Hammel, Heidi B; Casewell, Sarah L; Fortney, Jonathan J; Gizis, John E; Lissauer, Jack J; Morales-Juberias, Raul; Orton, Glenn S; Wong, Michael H; Marley, Mark S

    2016-02-01

    Observations of Neptune with the Kepler Space Telescope yield a 49 day light curve with 98% coverage at a 1 minute cadence. A significant signature in the light curve comes from discrete cloud features. We compare results extracted from the light curve data with contemporaneous disk-resolved imaging of Neptune from the Keck 10-m telescope at 1.65 microns and Hubble Space Telescope visible imaging acquired nine months later. This direct comparison validates the feature latitudes assigned to the K2 light curve periods based on Neptune's zonal wind profile, and confirms observed cloud feature variability. Although Neptune's clouds vary in location and intensity on short and long timescales, a single large discrete storm seen in Keck imaging dominates the K2 and Hubble light curves; smaller or fainter clouds likely contribute to short-term brightness variability. The K2 Neptune light curve, in conjunction with our imaging data, provides context for the interpretation of current and future brown dwarf and extrasolar planet variability measurements. In particular we suggest that the balance between large, relatively stable, atmospheric features and smaller, more transient, clouds controls the character of substellar atmospheric variability. Atmospheres dominated by a few large spots may show inherently greater light curve stability than those which exhibit a greater number of smaller features.

  2. Observations of atmospheric Hg species and depositions in remote areas of China

    Directory of Open Access Journals (Sweden)

    Feng X.

    2013-04-01

    Full Text Available From September 2007, we conducted continuous measurements of speciated atmospheric mercury (Hg and atmospheric mercury depositions at five remote sites in China. Four of these sites were involved in the Global Mercury Observation System (GMOS as ground-based stations. These stations were located in the northwest, southwest, northeast, and east part of China, respectively, which represent the regional atmospheric Hg budgets in different areas of China. The preliminary results showed that mean TGM concentrations were in the range of 1.60 – 2.88 ng m-3, with relatively higher levels observed at sites in Eastern China and Southwestern China and lower levels at sites in Northeastern and Northwestern China. TGM concentrations at remote sites of China were also higher than those reported from background sites in North America and Europe, and this is corresponding very well with the Chinese great anthropogenic Hg emissions. Gaseous oxidized mercury (GOM and particulate bounded mercury (PBM were in the ranges of 3.2 – 7.4 pg m−3 and 19.4 – 43.5 pg m-3, respectively. The preliminary result on precipitation showed mean precipitation THg concentrations were in the range of 2.7 – 18.0 ng L-1.

  3. SUMO: A small unmanned meteorological observer for atmospheric boundary layer research

    International Nuclear Information System (INIS)

    Reuder, J; Jonassen, M; Mayer, S; Brisset, P; Mueller, M

    2008-01-01

    A new system for atmospheric measurements in the lower troposphere has been developed and successfully tested. The presented Small Unmanned Meteorological Observer (SUMO) is based on a light-weighted commercially available model airplane, equipped with an autopilot and meteorological sensors for temperature, humidity and pressure. During the 5 week field campaign FLOHOF (Flow over and around HofsjoUkull) in Central Iceland the system has been successfully tested in July/August 2007. Atmospheric profiles of temperature, humidity, wind speed and wind direction have been determined up to 3500 m above ground. In addition the applicability of SUMO for horizontal surveys up to 4 km away from the launch site has been approved. During a 3 week campaign on and around Spitsbergen in February/March 2008 the SUMO system also proved its functionality under harsh polar conditions, reaching altitudes above 1500 m at ground temperatures of -20 deg. C and wind speeds up to 15 m s -1 . With its wingspan of 80 cm, its length of 75 cm and its weight of below 600 g, SUMO is easy to transport and operate even in remote areas. The direct material costs for one SUMO unit, including airplane, autopilot and sensors are below 1200 Euro. Assuming at least several tenths of flights for each airframe, SUMO provides a cost-efficient measurement system with a large potential to close the existing observational gap of reasonable atmospheric measurement systems in between meteorological masts/towers and radiosondes

  4. SUMO: A small unmanned meteorological observer for atmospheric boundary layer research

    Energy Technology Data Exchange (ETDEWEB)

    Reuder, J; Jonassen, M; Mayer, S [Geophysical Institute, University of Bergen, Allegaten 70, 5009 Bergen (Norway); Brisset, P [Ecole Nationale de l' Aviation Civile (ENAC), 7 avenue Edouard Belin, 31055 Toulouse (France); Mueller, M [Orleansstrasse 26a, 31135 Hildesheim (Germany)], E-mail: joachim.reuder@gfi.uib.no, E-mail: pascal.brisset@enac.fr, E-mail: marius.jonassen@gfi.uib.no, E-mail: martin@pfump.org, E-mail: stephanie.mayer@gfi.uib.no

    2008-05-01

    A new system for atmospheric measurements in the lower troposphere has been developed and successfully tested. The presented Small Unmanned Meteorological Observer (SUMO) is based on a light-weighted commercially available model airplane, equipped with an autopilot and meteorological sensors for temperature, humidity and pressure. During the 5 week field campaign FLOHOF (Flow over and around HofsjoUkull) in Central Iceland the system has been successfully tested in July/August 2007. Atmospheric profiles of temperature, humidity, wind speed and wind direction have been determined up to 3500 m above ground. In addition the applicability of SUMO for horizontal surveys up to 4 km away from the launch site has been approved. During a 3 week campaign on and around Spitsbergen in February/March 2008 the SUMO system also proved its functionality under harsh polar conditions, reaching altitudes above 1500 m at ground temperatures of -20 deg. C and wind speeds up to 15 m s{sup -1}. With its wingspan of 80 cm, its length of 75 cm and its weight of below 600 g, SUMO is easy to transport and operate even in remote areas. The direct material costs for one SUMO unit, including airplane, autopilot and sensors are below 1200 Euro. Assuming at least several tenths of flights for each airframe, SUMO provides a cost-efficient measurement system with a large potential to close the existing observational gap of reasonable atmospheric measurement systems in between meteorological masts/towers and radiosondes.

  5. On the possibility of space objects invasion observations into the Earth's atmosphere with the help of a multifunctional polarimeter

    Science.gov (United States)

    Nevodovskyi, P. V.; Steklov, A. F.; Vidmachenko, A. P.

    2018-05-01

    Relevance of the tasks associated with the observation of the invasion of space objects into the Earth's atmosphere increases with each passing year. We used astronomical panoramic polarimeter for carrying out of polarimetric observations of objects, that flying into the atmosphere of the Earth from the surrounding outer space.

  6. WaterML, an Information Standard for the Exchange of in-situ hydrological observations

    Science.gov (United States)

    Valentine, D.; Taylor, P.; Zaslavsky, I.

    2012-04-01

    The WaterML 2.0 Standards Working Group (SWG), working within the Open Geospatial Consortium (OGC) and in cooperation with the joint OGC-World Meteorological Organization (WMO) Hydrology Domain Working Group (HDWG), has developed an open standard for the exchange of water observation data; WaterML 2.0. The focus of the standard is time-series data, commonly generated from in-situ style monitoring. This is high value data for hydrological applications such as flood forecasting, environmental reporting and supporting hydrological infrastructure (e.g. dams, supply systems), which is commonly exchanged, but a lack of standards inhibits efficient reuse and automation. The process of developing WaterML required doing a harmonization analysis of existing standards to identify overlapping concepts and come to agreement on a harmonized definition. Generally the formats captured similar requirements, all with subtle differences, such as how time-series point metadata was handled. The in-progress standard WaterML 2.0 incorporates the semantics of the hydrologic information: location, procedure, and observations, and is implemented as an application schema of the Geography Markup Language version 3.2.1, making use of the OGC Observations & Measurements standards. WaterML2.0 is designed as an extensible schema to allow encoding of data to be used in a variety of exchange scenarios. Example areas of usage are: exchange of data for operational hydrological monitoring programs; supporting operation of infrastructure (e.g. dams, supply systems); cross-border exchange of observational data; release of data for public dissemination; enhancing disaster management through data exchange; and exchange in support of national reporting The first phase of WaterML2.0 focused on structural definitions allowing for the transfer of time-series, with less work on harmonization of vocabulary items such as quality codes. Vocabularies from various organizations tend to be specific and take time to

  7. Neutral molecular cluster formation of sulfuric acid–dimethylamine observed in real time under atmospheric conditions

    CERN Document Server

    Kürten, Andreas; Simon, Mario; Sipilä, Mikko; Sarnela, Nina; Junninen, Heikki; Adamov, Alexey; Almeida, João; Amorim, Antonio; Bianchi, Federico; Breitenlechner, Martin; Dommen, Josef; Donahue, Neil M; Duplissy, Jonathan; Ehrhart, Sebastian; Flagan, Richard C; Franchin, Alessandro; Hakala, Jani; Hansel, Armin; Heinritzi, Martin; Hutterli, Manuel; Kangasluoma, Juha; Kirkby, Jasper; Laaksonen, Ari; Lehtipalo, Katrianne; Leiminger, Markus; Makhmutov, Vladimir; Mathot, Serge; Onnela, Antti; Petäjä, Tuukka; Praplan, Arnaud P; Riccobono, Francesco; Rissanen, Matti P; Rondo, Linda; Schobesberger, Siegfried; Seinfeld, John H; Steiner, Gerhard; Tomé, António; Tröstl, Jasmin; Winkler, Paul M; Williamson, Christina; Wimmer, Daniela; Ye, Penglin; Baltensperger, Urs; Carslaw, Kenneth S; Kulmala, Markku; Worsnop, Douglas R; Curtius, Joachim

    2014-01-01

    For atmospheric sulfuric acid (SA) concentrations the presence of dimethylamine (DMA) at mixing ratios of several parts per trillion by volume can explain observed boundary layer new particle formation rates. However, the concentration and molecular composition of the neutral (uncharged) clusters have not been reported so far due to the lack of suitable instrumentation. Here we report on experiments from the Cosmics Leaving Outdoor Droplets chamber at the European Organization for Nuclear Research revealing the formation of neutral particles containing up to 14 SA and 16 DMA molecules, corresponding to a mobility diameter of about 2 nm, under atmospherically relevant conditions. These measurements bridge the gap between the molecular and particle perspectives of nucleation, revealing the fundamental processes involved in particle formation and growth. The neutral clusters are found to form at or close to the kinetic limit where particle formation is limited only by the collision rate of SA molecules. Even tho...

  8. Internal gravity waves in Titan's atmosphere observed by Voyager radio occultation

    Science.gov (United States)

    Hinson, D. P.; Tyler, G. L.

    1983-01-01

    The radio scintillations caused by scattering from small-scale irregularities in Titan's neutral atmosphere during a radio occultation of Voyager 1 by Titan are investigated. Intensity and frequency fluctuations occurred on time scales from about 0.1 to 1.0 sec at 3.6 and 13 cm wavelengths whenever the radio path passed within 90 km of the surface, indicating the presence of variations in refractivity on length scales from a few hundred meters to a few kilometers. Above 25 km, the altitude profile of intensity scintillations closely agrees with the predictions of a simple theory based on the characteristics of internal gravity waves propagating with little or no attenuation through the vertical stratification in Titan's atmosphere. These observations support a hypothesis of stratospheric gravity waves, possibly driven by a cloud-free convective region in the lowest few kilometers of the stratosphere.

  9. The CEOS Atmospheric Composition Constellation: Enhancing the Value of Space-Based Observations

    Science.gov (United States)

    Eckman, Richard; Zehner, Claus; Al-Saadi, Jay

    2015-01-01

    The Committee on Earth Observation Satellites (CEOS) coordinates civil space-borne observations of the Earth. Participating agencies strive to enhance international coordination and data exchange and to optimize societal benefit. In recent years, CEOS has collaborated closely with the Group on Earth Observations (GEO) in implementing the Global Earth Observing System of Systems (GEOSS) space-based objectives. The goal of the CEOS Atmospheric Composition Constellation (ACC) is to collect and deliver data to improve monitoring, assessment and predictive capabilities for changes in the ozone layer, air quality and climate forcing associated with changes in the environment through coordination of existing and future international space assets. A project to coordinate and enhance the science value of a future constellation of geostationary sensors measuring parameters relevant to air quality supports the forthcoming European Sentinel-4, Korean GEMS, and US TEMPO missions. Recommendations have been developed for harmonization to mutually improve data quality and facilitate widespread use of the data products.

  10. [Observation on atmospheric pollution in Xianghe during Beijing 2008 Olympic Games].

    Science.gov (United States)

    Pan, Yue-Peng; Wang, Yue-Si; Hu, Bo; Liu, Quan; Wang, Ying-Hong; Nan, Wei-Dong

    2010-01-01

    There is a concern that much of the atmospheric pollution experienced in Beijing is regional in nature and not attributable to local sources. The objective of this study is to examine the contribution of sources outside Beijing to atmospheric pollution levels during Beijing 2008 Olympic Games. The observations of SO2, NO(x), O3, PM2.5 and PM10 were conducted from June 1 to September 30, 2008 in Xianghe, a rural site about 70 km southeast of Beijing. Sources and transportation of atmospheric pollution during the experiment were discussed with surface meteorology data and backward trajectories calculated using HYSPLIT model. The results showed that the daily average maximum (mean +/- standard deviation) concentrations of SO2, NO(x), O3, PM2.5, and PM10 during observation reached 84.4(13.4 +/- 15.2), 43.3 (15.9 +/- 9.1), 230 (82 +/- 38), 184 (76 +/- 42) and 248 (113 +/- 52) microg x m(-3), respectively. In particular, during the pollution episodes from July 20 to August 12, the hourly average concentration of O3 exceeded the National Ambient Air Quality Standard II for 46 h (9%), and the daily average concentration of PM10 exceeded the Standard for 11 d (46%); PM2.5 exceeded the US EPA Standard for 18 d (75%). The daily average concentrations of SO2, NO(x), O3, PM2.5 and PM10 decreased from 27.7, 18.6, 96, 90, 127 microg x m(-3) in June-July to 5.8, 13.2, 80, 60, 106 microg x m(-3) during Olympic Games (August-September), respectively. The typical diurnal variations of NO(x), PM2.5 and PM10 were similar, peaking at 07:00 and 20:00, while the maximum of O3 occurred between 14:00 to 16:00 local time. The findings also suggested that the atmospheric pollution in Xianghe is related to local emission, regional transport as well as the meteorological conditions. Northerly wind and precipitation are favorable for diffusion and wet deposition of pollutants, while sustained south flows make the atmospheric pollution more serious. The lead-lag correlation analysis during the

  11. Spectrometer and Radiative Transfer Model Comparison using High Sun In-Situ Observations in Pretoria

    CSIR Research Space (South Africa)

    Lysko, MD

    2012-08-01

    Full Text Available There is need for reliable in-situ spectral solar irradiance measurements. For instance, the spectrally resolved irradiance may be used to infer its influence on radiative forcing of climate and in solar energy applications. In any case, reliable...

  12. Direct Observations of Oxygen-induced Platinum Nanoparticle Ripening Studied by In Situ TEM

    DEFF Research Database (Denmark)

    Simonsen, Søren Bredmose; Chorkendorff, Ib; Dahl, Søren

    2010-01-01

    This study addresses the sintering mechanism of Pt nanoparticles dispersed on a planar, amorphous Al2O3 support as a model system for a catalyst for automotive exhaust abatement. By means of in situ transmission electron microscopy (TEM), the model catalyst was monitored during the exposure to 10...

  13. Dynamic restoration of severely predeformed, ultrafine-grained pure Cu at 373 K observed in situ

    Czech Academy of Sciences Publication Activity Database

    Král, Petr; Blum, W.; Dvořák, Jiří; Eisenlohr, P.; Petrenec, M.; Sklenička, Václav

    2017-01-01

    Roč. 134, DEC (2017), s. 329-334 ISSN 1044-5803 R&D Projects: GA MŠk(CZ) LQ1601 Institutional support: RVO:68081723 Keywords : ECAP * Dynamic grain coarsening * UFG copper * In situ Subject RIV: JG - Metallurgy OBOR OECD: Materials engineering Impact factor: 2.714, year: 2016

  14. Observed atmospheric total column ozone distribution from SCIAMACHY over Peninsular Malaysia

    International Nuclear Information System (INIS)

    Chooi, T K; San, L H; Jafri, M Z M

    2014-01-01

    The increase in atmospheric ozone has received great attention because it degrades air quality and brings hazard to human health and ecosystems. The aim of this study was to assess the seasonal variations of ozone concentrations in Peninsular Malaysia from January 2003 to December 2009 using Scanning Imaging Absorption Spectrometer for Atmospheric Cartography (SCIAMACHY). Level-2 data of total column ozone WFMD version 1.0 with spatial resolution 1° × 1.25° were acquired through SCIAMACHY. Analysis for trend of five selected sites exhibit strong seasonal variation in atmospheric ozone concentrations, where there is a significant difference between northeast monsoon and southwest monsoon. The highest ozone values occurred over industrial and congested urban zones (280.97 DU) on August at Bayan Lepas. The lowest ozone values were observed during northeast monsoon on December at Subang (233.08 DU). In addition, the local meteorological factors also bring an impact on the atmospheric ozone. During northeast monsoon, with the higher rate of precipitation, higher relative humidity, low temperature, and less sunlight hours let to the lowest ozone concentrations. Inversely, the highest ozone concentrations observed during southwest monsoon, with the low precipitation rate, lower relative humidity, higher temperature, and more sunlight hours. Back trajectories analysis is carried out, in order to trace the path of the air parcels with high ozone concentration event, suggesting cluster of trajectory (from southwest of the study area) caused by the anthropogenic sources associated with biogenic emissions from large tropical forests, which can make important contribution to regional and global pollution

  15. In-situ observation of the transformation of amorphous calcium phosphate to crystalline hydroxyapatite

    Science.gov (United States)

    Stammeier, Jessica; Hippler, Dorothee; Mavromatis, Vasileios; Sacher, Stephan; Dietzel, Martin

    2016-04-01

    Amorphous calcium phosphate (Ca3(PO4)2*nH2O; ACP) is often a precursor phase of the mineral (hydroxy-) apatite (Ca5(PO4)3(OH)) that can be formed in natural settings during both authigenic and biogenic mineral formation. Particularly, in the biomineralization process of fish tissue, ACP has shown to be an important transient phase. In solution ACP rapidly transforms into the crystalline phase. The transformation rate highly depends on the physico-chemical conditions of the solution: Ca & P availability, pH and temperature. In natural settings Ca can be provided by different sources: from (1) seawater, (2) porewater, or (3) diagenetically-altered carbonates, whereas local supersaturation of P can be induced by microbial activity. In this study, we performed phosphate precipitation experiments in order to monitor the transformation process of the ACP to crystalline hydroxyapatite (HAP) using in-situ Raman spectroscopy. During the experiments the temperature was kept constant at 20.0 ± 0.01 ° C and pH at 9 ± 0.1. 50 ml of 0.3 CaCl 2H2O was titrated at a rate of 5 ml/min to an equal volume of 0.2 M Na2HPO4. The pH was kept constant by titration of 1 M NaOH. During the experiment samples were taken from the solution and instantly filtered. The obtained solid samples were lyophilized and analyzed with XRD, ATR and SEM. The respective solution samples were analyzed using ion chromatography and ICP OES, coupling the spectroscopic data with detailed solution chemistry data. We observed transformation of ACP to HAP to occur within 14 hours, illustrated in a clear peak shift in Raman spectra from 950 cm-1 to 960 cm-1. The obtained results are discussed in the aspects of distribution of major elements during the formation of phosphates and/or the diagenetic alteration of carbonates to phosphates in geologic settings. Financial support by DFG-FG 736 and NAWI Graz is kindly acknowledged.

  16. Harmonising and semantically linking key variables from in-situ observing networks of an Integrated Atlantic Ocean Observing System, AtlantOS

    Science.gov (United States)

    Darroch, Louise; Buck, Justin

    2017-04-01

    Atlantic Ocean observation is currently undertaken through loosely-coordinated, in-situ observing networks, satellite observations and data management arrangements at regional, national and international scales. The EU Horizon 2020 AtlantOS project aims to deliver an advanced framework for the development of an Integrated Atlantic Ocean Observing System that strengthens the Global Ocean Observing System (GOOS) and contributes to the aims of the Galway Statement on Atlantic Ocean Cooperation. One goal is to ensure that data from different and diverse in-situ observing networks are readily accessible and useable to a wider community, including the international ocean science community and other stakeholders in this field. To help achieve this goal, the British Oceanographic Data Centre (BODC) produced a parameter matrix to harmonise data exchange, data flow and data integration for the key variables acquired by multiple in-situ AtlantOS observing networks such as ARGO, Seafloor Mapping and OceanSITES. Our solution used semantic linking of controlled vocabularies and metadata for parameters that were "mappable" to existing EU and international standard vocabularies. An AtlantOS Essential Variables list of terms (aggregated level) based on Global Climate Observing System (GCOS) Essential Climate Variables (ECV), GOOS Essential Ocean Variables (EOV) and other key network variables was defined and published on the Natural Environment Research Council (NERC) Vocabulary Server (version 2.0) as collection A05 (http://vocab.nerc.ac.uk/collection/A05/current/). This new vocabulary was semantically linked to standardised metadata for observed properties and units that had been validated by the AtlantOS community: SeaDataNet parameters (P01), Climate and Forecast (CF) Standard Names (P07) and SeaDataNet units (P06). Observed properties were mapped to biological entities from the internationally assured AphiaID from the WOrld Register of Marine Species (WoRMS), http

  17. Liquid-solid phase transition of Ge-Sb-Te alloy observed by in-situ transmission electron microscopy

    International Nuclear Information System (INIS)

    Berlin, Katja; Trampert, Achim

    2017-01-01

    Melting and crystallization dynamics of the multi-component Ge-Sb-Te alloy have been investigated by in-situ transmission electron microscopy (TEM). Starting point of the phase transition study is an ordered hexagonal Ge 1 Sb 2 Te 4 thin film on Si(111) where the crystal structure and the chemical composition are verified by scanning TEM and electron energy-loss spectroscopy, respectively. The in-situ observation of the liquid phase at 600°C including the liquid-solid and liquid-vacuum interfaces and their movements was made possible due to an encapsulation of the TEM sample. The solid-liquid interface during melting displays a broad and diffuse transition zone characterized by a vacancy induced disordered state. Although the velocities of interface movements are measured to be in the nanometer per second scale, both, for crystallization and solidification, the underlying dynamic processes are considerably different. Melting reveals linear dependence on time, whereas crystallization exhibits a non-linear time-dependency featuring a superimposed start-stop motion. Our results may provide valuable insight into the atomic mechanisms at interfaces during the liquid-solid phase transition of Ge-Sb-Te alloys. - Highlights: • In-situ TEM observation of liquid Ge-Sb-Te phase transition due to encapsulation. • During melting: Observation of non-ordered interface transition due to premelting. • During solidification: Observation of non-linear time-dependent crystallization.

  18. Liquid-solid phase transition of Ge-Sb-Te alloy observed by in-situ transmission electron microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Berlin, Katja, E-mail: katja.berlin@pdi-berlin.de; Trampert, Achim

    2017-07-15

    Melting and crystallization dynamics of the multi-component Ge-Sb-Te alloy have been investigated by in-situ transmission electron microscopy (TEM). Starting point of the phase transition study is an ordered hexagonal Ge{sub 1}Sb{sub 2}Te{sub 4} thin film on Si(111) where the crystal structure and the chemical composition are verified by scanning TEM and electron energy-loss spectroscopy, respectively. The in-situ observation of the liquid phase at 600°C including the liquid-solid and liquid-vacuum interfaces and their movements was made possible due to an encapsulation of the TEM sample. The solid-liquid interface during melting displays a broad and diffuse transition zone characterized by a vacancy induced disordered state. Although the velocities of interface movements are measured to be in the nanometer per second scale, both, for crystallization and solidification, the underlying dynamic processes are considerably different. Melting reveals linear dependence on time, whereas crystallization exhibits a non-linear time-dependency featuring a superimposed start-stop motion. Our results may provide valuable insight into the atomic mechanisms at interfaces during the liquid-solid phase transition of Ge-Sb-Te alloys. - Highlights: • In-situ TEM observation of liquid Ge-Sb-Te phase transition due to encapsulation. • During melting: Observation of non-ordered interface transition due to premelting. • During solidification: Observation of non-linear time-dependent crystallization.

  19. Modeling of coronal mass ejections with the STEREO heliospheric imagers verified with in situ observations by the Heliophysics System Observatory

    Science.gov (United States)

    Möstl, Christian; Isavnin, Alexey; Kilpua, Emilia; Bothmer, Volker; Mrotzek, Nicolas; Boakes, Peter; Rodriguez, Luciano; Krupar, Vratislav; Eastwood, Jonathan; Davies, Jackie; Harrison, Richard; Barnes, David; Winslow, Reka; Helcats Team

    2017-04-01

    We present the first study to verify modeling of CMEs as observed by the heliospheric imagers on the two STEREO spacecraft with a large scale dataset of in situ plasma and magnetic field observations from the Heliophysics System Observatory, including MESSENGER, VEX, Wind, and the in situ measurements on the two STEREO spacecraft. To this end, we have established a new interplanetary CME catalog (ICMECAT) for these spacecraft by gathering and updating individual ICME lists. In addition, we have re-calculated the in situ parameters in a consistent way, resulting in 668 events observed between 2007-2015. We then calculated the efficacy of the STEREO/HI instruments for predicting (in hindsight) with the SSEF30 model the arrival time and speed of CMEs as well as hit/miss ratios. We also show how ICMECAT gives decent statistics concerning CME impacts on all of the terrestrial planets, including Mars. The results show some major implications for future heliospheric imagers which may be used for space weather forecasting. Our effort should also serve as a baseline for the upcoming new era in heliospheric science with Solar Orbiter, Solar Probe Plus, BepiColombo returning partly comparable observations in the next decade. The presented work has received funding from the European Union Seventh Framework Programme (FP7/ 2007-2013) under grant agreement No. 606692 [HELCATS].

  20. Atmospheric extinction coefficients and night sky brightness at the Xuyi Observation Station

    International Nuclear Information System (INIS)

    Zhang Hui-Hua; Liu Xiao-Wei; Zhang Hua-Wei; Xiang Mao-Sheng; Yuan Hai-Bo; Zhao Hai-Bin; Yao Jin-Sheng

    2013-01-01

    We present measurements of the optical broadband atmospheric extinction coefficients and the night sky brightness at the Xuyi Observation Station of Purple Mountain Observatory. The measurements are based on CCD imaging data taken in the Sloan Digital Sky Survey's g, r and i bands with the Xuyi 1.04/1.20 m Schmidt Telescope for the Xuyi Schmidt Telescope Photometric Survey of the Galactic Anti-center (XSTPS-GAC), the photometric part of the Digital Sky Survey of the Galactic Anti-center (DSS-GAC). The data were collected during more than 140 winter nights from 2009 to 2011. We find that the atmospheric extinction coefficients for the g, r and i bands are 0.69, 0.55 and 0.38 mag/airmass, respectively, based on observations taken on several photometric nights. The night sky brightness determined from images with good quality has median values of 21.7, 20.8 and 20.0 mag arcsec −2 and reaches 22.1, 21.2 and 20.4 mag arcsec −2 under the best observing conditions for the g, r and i bands, respectively. The relatively large extinction coefficients compared with other good astronomical observing sites are mainly due to the relatively low elevation (i.e. 180 m) and high humidity at the station.

  1. Development of Innovative Technology to Provide Low-Cost Surface Atmospheric Observations in Data Sparse Regions

    Science.gov (United States)

    Kucera, Paul; Steinson, Martin

    2017-04-01

    Accurate and reliable real-time monitoring and dissemination of observations of surface weather conditions is critical for a variety of societal applications. Applications that provide local and regional information about temperature, precipitation, moisture, and winds, for example, are important for agriculture, water resource monitoring, health, and monitoring of hazard weather conditions. In many regions of the World, surface weather stations are sparsely located and/or of poor quality. Existing stations have often been sited incorrectly, not well-maintained, and have limited communications established at the site for real-time monitoring. The University Corporation for Atmospheric Research (UCAR)/National Center for Atmospheric Research (NCAR), with support from USAID, has started an initiative to develop and deploy low-cost weather instrumentation in sparsely observed regions of the world. The project is focused on improving weather observations for environmental monitoring and early warning alert systems on a regional to global scale. Instrumentation that has been developed use innovative new technologies such as 3D printers, Raspberry Pi computing systems, and wireless communications. The goal of the project is to make the weather station designs, software, and processing tools an open community resource. The weather stations can be built locally by agencies, through educational institutions, and residential communities as a citizen effort to augment existing networks to improve detection of natural hazards for disaster risk reduction. The presentation will provide an overview of the open source weather station technology and evaluation of sensor observations for the initial networks that have been deployed in Africa.

  2. Export of Atmospheric Mercury from East Asia Observed at Various Monitoring Sites in Taiwan

    Science.gov (United States)

    Sheu, G.; Lin, N.; Wang, J.; Lee, C.; Chang, S.

    2009-12-01

    East Asia is the major atmospheric mercury (Hg) source region in the world due to the excessive coal combustion, industrial emission, and biomass burning in this area. Nonetheless, studies concerning the export of atmospheric Hg from East Asia are still limited. Accordingly, atmospheric Hg has been measured at various sites in Taiwan to study its temporal and spatial distribution, and the significance of long-range transport from the East Asian continent as well. Here we report the data collected in Fu-guei-jiao (121.97°E, 25.47°N, ~30 m a.s.l.), Mt. Bamboo (121.54°E, 25.19°N, 1025 m a.s.l.), and Lulin Atmospheric Background Station (LABS; 120.87°E, 23.47°N, 2862 m a.s.l.) to discuss the atmospheric Hg export from the East Asian continent. Twenty-four hour-integrated total atmospheric Hg (THg) samples were manually collected in Fu-guei-jiao and Mt. Bamboo in 2007-2008 and quantified by dual amalgamation CVAFS. On the other hand, continuous measurements of gaseous elemental Hg (GEM), reactive gaseous Hg (RGM), and particulate Hg (PHg) at LABS began since April 13, 2006 using the Tekran 2537A/1130/1135 speciation system. Mean(±S.D.) THg concentrations were 2.09±0.71 and 1.86±0.50 ng m-3 for Fu-guei-jiao and Mt. Bamboo, respectively. At LABS between April 2006 and April 2009, the mean(±S.D.) concentrations of GEM, RGM and PHg were 1.77±0.54 ng m-3, 22.4±43.8 pg m-3 and 6.3±10.9 pg m-3, respectively. Evident seasonal distribution in THg/GEM concentrations was observed at all sites with higher values usually occurred between fall and spring when the air masses were mainly from the East Asian continent, indicating the influence of the East Asian atmospheric Hg outflow. This also demonstrated that the atmospheric Hg export is occurring both in the boundary layer and in the free troposphere. Concentrations of PHg were usually low at LABS; however, elevated values were detected in spring when the Indochina Peninsula biomass burning plumes frequently affected

  3. Simultaneous observations of SAO and QBO in winds, temperature and ozone in the tropical middle atmosphere over Thumba (8.5 N, 77 E)

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Karanam Kishore; Swain, Debadatta; John, Sherine Rachel; Ramkumar, Geetha [Vikram Sarabhai Space Center, Space Physics Laboratory, Thiruvananthapuram (India)

    2011-11-15

    Owing to the importance of middle atmosphere, recently, a Middle Atmospheric Dynamics (MIDAS) program was carried out during the period 2002-2007 at Thumba (8.5 N, 77 E). The measurements under this program, involving regular radiosonde/rocket flights as well as atmospheric radars, provided long period observations of winds and temperature in the middle atmospheric region from which waves and oscillations as well as their forcing mechanisms particularly in the low-latitude middle atmosphere could be analyzed. However, a detailed analysis of the forcing mechanisms remains incomplete due to the lack of important measurements like ozone which is a significant contributor to atmospheric dynamics. Presently, profiles of ozone are available from TIMED/SABER (Thermosphere, Ionosphere, Mesosphere Energetics and Dynamics/Sounding of the Atmosphere using Broad Emission Radiometry) satellite globally from about 15 to 100 km, over multiple years since 2002. In this regard, a comprehensive study has been carried out on ozone and its variability at Quasi Biennial Oscillation (QBO) and Semiannual Oscillation (SAO) scales using TIMED/SABER ozone observations during the MIDAS campaign period. Before using the TIMED/SABER ozone measurements, an inter-comparison has been carried out with in situ measurements of ozone obtained under the Southern Hemisphere Additional Ozonesondes (SHADOZ) campaign for the year 2007 at few stations. The inter-comparison showed very good agreement between SABER and ozonesonde derived ozone profiles. After validating the SABER observations, ozone profiles are used extensively to study the QBO and SAO along with temperature and winds in the 20-100 km height region. It is known that the SAO in mesosphere and stratosphere are in opposite phases, but the present study for the first time reports the aspect of opposite phases in the mesosphere itself. Thus, the present work attempts to study the long-period oscillations in stratosphere and mesosphere in ozone

  4. In-situ Observation of Fracture Behavior on Nano Structure in NITE SiC/SiC Composite by HVEM

    International Nuclear Information System (INIS)

    Shibayama, Tamaki; Hamada, Kouichi; Watanabe, Seiichi; Matsuo, Genichiro; Kishimoto, Hirotatsu

    2011-01-01

    We have been successfully done in situ observation on the sequence of fracture event at the interface of NITE SiC/SiC composite examined by using miniaturized double notched shear specimen for TEM prepared by Focused Ion Beam method. In this study, we used nano-mechanics TEM experimental apparatus to investigate not only microstructure evolution and but also load and displacement curve at once in High Voltage Electron Microscope. Our results summarize as follows. Cracks were initiated at the interface between carbon coating layer on the SiC fiber and SiC matrices, and propagated along the interface. Load drop in the load and displacement curve during in-situ TEM was clearly observed at the crack initiation. The shear strength by using the miniaturized specimen is about ten times higher than that obtained by the standard testing.

  5. In-situ aircraft observations of ice concentrations within clouds over the Antarctic Peninsula and Larsen Ice Shelf

    OpenAIRE

    Grosvenor, D. P.; Choularton, T. W.; Lachlan-Cope, T.; Gallagher, M. W.; Crosier, J.; Bower, K. N.; Ladkin, R. S.; Dorsey, J. R.

    2012-01-01

    In-situ aircraft observations of ice crystal concentrations in Antarctic clouds are presented for the first time. Orographic, layer and wave clouds around the Antarctic Peninsula and Larsen Ice shelf regions were penetrated by the British Antarctic Survey's Twin Otter aircraft, which was equipped with modern cloud physics probes. The clouds studied were mostly in the free troposphere and hence ice crystals blown from the surface are unlikely to have been a major source for the ice phas...

  6. Comparison of continuous in situ CO2 observations at Jungfraujoch using two different measurement techniques

    Science.gov (United States)

    Schibig, M. F.; Steinbacher, M.; Buchmann, B.; van der Laan-Luijkx, I. T.; van der Laan, S.; Ranjan, S.; Leuenberger, M. C.

    2015-01-01

    Since 2004, atmospheric carbon dioxide (CO2) is being measured at the High Altitude Research Station Jungfraujoch by the division of Climate and Environmental Physics at the University of Bern (KUP) using a nondispersive infrared gas analyzer (NDIR) in combination with a paramagnetic O2 analyzer. In January 2010, CO2 measurements based on cavity ring-down spectroscopy (CRDS) as part of the Swiss National Air Pollution Monitoring Network were added by the Swiss Federal Laboratories for Materials Science and Technology (Empa). To ensure a smooth transition - a prerequisite when merging two data sets, e.g., for trend determinations - the two measurement systems run in parallel for several years. Such a long-term intercomparison also allows the identification of potential offsets between the two data sets and the collection of information about the compatibility of the two systems on different time scales. A good agreement of the seasonality, short-term variations and, to a lesser extent mainly due to the short common period, trend calculations is observed. However, the comparison reveals some issues related to the stability of the calibration gases of the KUP system and their assigned CO2 mole fraction. It is possible to adapt an improved calibration strategy based on standard gas determinations, which leads to better agreement between the two data sets. By excluding periods with technical problems and bad calibration gas cylinders, the average hourly difference (CRDS - NDIR) of the two systems is -0.03 ppm ± 0.25 ppm. Although the difference of the two data sets is in line with the compatibility goal of ±0.1 ppm of the World Meteorological Organization (WMO), the standard deviation is still too high. A significant part of this uncertainty originates from the necessity to switch the KUP system frequently (every 12 min) for 6 min from ambient air to a working gas in order to correct short-term variations of the O2 measurement system. Allowing additional time for

  7. Comparison of continuous in-situ CO2 observations at Jungfraujoch using two different measurement techniques

    Science.gov (United States)

    Schibig, M. F.; Steinbacher, M.; Buchmann, B.; van der Laan-Luijkx, I. T.; van der Laan, S.; Ranjan, S.; Leuenberger, M. C.

    2014-07-01

    Since 2004, atmospheric carbon dioxide (CO2) is measured at the High Altitude Research Station Jungfraujoch by the division of Climate and Environmental Physics at the University of Bern (KUP) using a nondispersive infrared gas analyzer (NDIR) in combination with a paramagnetic O2 analyzer. In January 2010, CO2 measurements based on cavity ring down spectroscopy (CRDS) as part of the Swiss National Air Pollution Monitoring Network have been added by the Swiss Federal Laboratories for Materials Science and Technology (Empa). To ensure a smooth transition - a prerequisite when merging two datasets e.g. for trend determinations - the two measurement systems run in parallel for several years. Such a long-term intercomparison also allows identifying potential offsets between the two datasets and getting information about the compatibility of the two systems on different time scales. A good agreement of the seasonality as well as for the short-term variations was observed and to a lesser extent for trend calculations mainly due to the short common period. However, the comparison revealed some issues related to the stability of the calibration gases of the KUP system and their assigned CO2 mole fraction. It was possible to adapt an improved calibration strategy based on standard gas determinations, which lead to better agreement between the two data sets. By excluding periods with technical problems and bad calibration gas cylinders, the average hourly difference (CRDS - NDIR) of the two systems is -0.03 ppm ± 0.25 ppm. Although the difference of the two datasets is in line with the compatibility goal of ±0.1 ppm of the World Meteorological Organization (WMO), the standard deviation is still too high. A significant part of this uncertainty originates from the necessity to switch the KUP system frequently (every 12 min) for 6 min from ambient air to a working gas in order to correct short-term variations of the O2 measurement system. Allowing additionally for signal

  8. Viscoplastic behaviour including damage for deep argillaceous rocks: from in situ observations to constitutives equations

    International Nuclear Information System (INIS)

    Souley, Mountaka; Ghoreychi, Mehdi; Armand, Gilles

    2010-01-01

    Document available in extended abstract form only. In order to demonstrate the feasibility of a radioactive waste repository in clay-stone formation, French national radioactive waste management agency (ANDRA) started in 2000 to build an underground research laboratory CMHM) at Bure located at nearly 300 km East of Paris. The host formation consists of a clay-stone (Callovo-Oxfordian argillites) and lies between 430 m and 550 m deep. On the basis of numerous campaigns of laboratory tests (uniaxial/triaxial, mono/multi stage creep and relaxation) undertaken for characterizing mechanical and hydro-mechanical short-term or long-term behaviour of these argillites, several constitutive models were developed in the framework of MODEXREP European project and scientific cooperation between ANDRA and national institutions. Moreover, more than 400 m horizontal galleries at the main level of -490 m at CMHM laboratory have been instrumented since April 2005 with the aim to understand the rock behaviour (especially the long term behaviour) needed for the repository design. The continuous measurements of convergencies of the galleries are available contributing to better understand the time-dependent response of the argillites at natural scale. Analysis of convergence data over a period of 2 years leads to the following conclusions: (a) viscoplastic strains are anisotropic and depend on the gallery orientation with regard to the initial stress anisotropy in the investigated formation; (b) the viscoplastic strain rates observed in the undamaged area far from the galleries walls are in the same order of magnitude as those obtained on samples, whereas those recorded in the damaged or fractured zone near to the walls are one to two orders of magnitude higher; indicating the damage and created macroscopic fractures influences on the viscoplastic strains. This influence has not been taken into account in the previous constitutive models. From these observations, a macroscopic

  9. An Analysis of Cassini Observations Regarding the Structure of Jupiter's Equatorial Atmosphere

    Science.gov (United States)

    Choi, David S.; Simon-Miller, Amy A.

    2012-01-01

    A variety of intriguing atmospheric phenomena reside on both sides of Jupiter's equator. 5-micron bright hot spots and opaque plumes prominently exhibit dynamic behavior to the north, whereas compact, dark chevron-shaped features and isolated anticyclonic disturbances periodically occupy the southern equatorial latitudes. All of these phenomena are associated with the vertical and meridional perturbations of Rossby waves disturbing the mean atmospheric state. As previous observational analysis and numerical simulations have investigated the dynamics of the region, an examination of the atmosphere's vertical structure though radiative transfer analysis is necessary for improved understanding of this unique environment. Here we present preliminary analysis of a multispectral Cassini imaging data set acquired during the spacecraft's flyby of Jupiter in 2000. We evaluated multiple methane and continuum spectral channels at available viewing angles to improve constraints on the vertical structure of the haze and cloud layers comprising these interesting features. Our preliminary results indicate distinct differences in the structure for both hemispheres. Upper troposphere hazes and cloud layers are prevalent in the northern equatorial latitudes, but are not present in corresponding southern latitudes. Continued analysis will further constrain the precise structure present in these phenomena and the differences between them.

  10. Observation and analysis of speciated atmospheric mercury in Shangri-La, Tibetan Plateau, China

    Science.gov (United States)

    Zhang, H.; Fu, X. W.; Lin, C.-J.; Wang, X.; Feng, X. B.

    2015-01-01

    This study reports the concentrations and potential sources of speciated atmospheric mercury at the Shangri-La Atmosphere Watch Regional Station (SAWRS), a pristine high-altitude site (3580 m a.s.l.) in Tibetan Plateau, China. Total gaseous mercury (TGM, defined as the sum of gaseous elemental mercury, GEM, and gaseous oxidized mercury, GOM), GOM and particulate-bound mercury (PBM) were monitored from November 2009 to November 2010 to investigate the characteristics and potential influence of the Indian summer monsoon (ISM) and the Westerlies on atmospheric transport of mercury. The mean concentrations (± standard deviation) of TGM, PBM and GOM were 2.55 ± 0.73 ng m-3, 38.82 ± 31.26 pg m-3 and 8.22 ± 7.90 pg m-3, respectively. A notable seasonal pattern of TGM concentrations was observed with higher concentrations at the beginning and the end of the ISM season. High TGM concentrations (> 2.5 ng m-3) were associated with the transport of dry air that carried regional anthropogenic emissions from both Chinese domestic and foreign (e.g., Myanmar, Bay of Bengal, and northern India) sources based on analysis of HYSPLIT4 back trajectories. Somewhat lower PBM and GOM levels during the ISM period were attributed to the enhanced wet scavenging. The high GOM and PBM were likely caused by local photo-chemical transformation under low RH and the domestic biofuel burning in cold seasons.

  11. An Observational Diagnostic for Distinguishing Between Clouds and Haze in Hot Exoplanet Atmospheres

    Science.gov (United States)

    Kempton, Eliza; Bean, Jacob; Parmentier, Vivien

    2018-01-01

    The nature of aerosols in hot exoplanet atmospheres is one of the primary vexing questions facing the exoplanet field. The complex chemistry, multiple formation pathways, and lack of easily identifiable spectral features associated with aerosols make it especially challenging to constrain their key properties. We present a transmission spectroscopy technique to identify the primary aerosol formation mechanism for the most highly irradiated hot Jupiters (HIHJs). The technique is based on the idea that the two key types of aerosols -- photochemically generated hazes and equilibrium condensate clouds -- are expected to form and persist in different regions of a highly irradiated planet's atmosphere. Haze can only be produced on the permanent daysides of tidally-locked hot Jupiters, and will be carried downwind by atmospheric dynamics to the evening terminator (seen as the trailing limb during transit). Clouds can only form in cooler regions on the night side and morning terminator of HIHJs (seen as the leading limb during transit). Because opposite limbs are expected to be impacted by different types of aerosols, ingress and egress spectra, which primarily probe opposing sides of the planet, will reveal the dominant aerosol formation mechanism. We show that the benchmark HIHJ, WASP-121b, has a transmission spectrum consistent with partial aerosol coverage and that ingress-egress spectroscopy would constrain the location and formation mechanism of those aerosols. In general, we find that observations with JWST and potentially with HST should be able to distinguish between clouds and haze for currently known HIHJs.

  12. Land–biosphere–atmosphere interactions over the Tibetan plateau from MODIS observations

    International Nuclear Information System (INIS)

    Jin, Menglin S; Mullens, Terrence J

    2012-01-01

    Eleven years (2000–10) of monthly observations from the National Aeronautics and Space Administration (NASA) Terra Moderate-resolution Imaging Spectroradiometer (MODIS) show the diurnal, seasonal, and inter-annual variations of skin temperature over the Tibetan plateau (75–100°E, 27–45°N) at 0.05° × 0.05° resolution. A slight warming trend is observed during this period of time, although the relatively short duration of the observation makes such a trend uncertain. More importantly, using the most recent climatology of land skin temperature, spatially high correlation coefficients are found among normalized difference vegetation index (NDVI), water vapor and cloud relations, indicating that the land surface, vegetation and atmosphere influence one another. Such a quantitative understanding of these relationships at high spatial resolution would be helpful for modeling the biosphere–atmosphere–land surface interaction processes over the Tibetan plateau. (letter)

  13. Weather and atmosphere observation with the ATOM all-sky camera

    Directory of Open Access Journals (Sweden)

    Jankowsky Felix

    2015-01-01

    Full Text Available The Automatic Telescope for Optical Monitoring (ATOM for H.E.S.S. is an 75 cm optical telescope which operates fully automated. As there is no observer present during observation, an auxiliary all-sky camera serves as weather monitoring system. This device takes an all-sky image of the whole sky every three minutes. The gathered data then undergoes live-analysis by performing astrometric comparison with a theoretical night sky model, interpreting the absence of stars as cloud coverage. The sky monitor also serves as tool for a meteorological analysis of the observation site of the the upcoming Cherenkov Telescope Array. This overview covers design and benefits of the all-sky camera and additionally gives an introduction into current efforts to integrate the device into the atmosphere analysis programme of H.E.S.S.

  14. An Information-theoretic Approach to Optimize JWST Observations and Retrievals of Transiting Exoplanet Atmospheres

    Science.gov (United States)

    Howe, Alex R.; Burrows, Adam; Deming, Drake

    2017-01-01

    We provide an example of an analysis to explore the optimization of observations of transiting hot Jupiters with the James Webb Space Telescope (JWST) to characterize their atmospheres based on a simple three-parameter forward model. We construct expansive forward model sets for 11 hot Jupiters, 10 of which are relatively well characterized, exploring a range of parameters such as equilibrium temperature and metallicity, as well as considering host stars over a wide range in brightness. We compute posterior distributions of our model parameters for each planet with all of the available JWST spectroscopic modes and several programs of combined observations and compute their effectiveness using the metric of estimated mutual information per degree of freedom. From these simulations, clear trends emerge that provide guidelines for designing a JWST observing program. We demonstrate that these guidelines apply over a wide range of planet parameters and target brightnesses for our simple forward model.

  15. AN INFORMATION-THEORETIC APPROACH TO OPTIMIZE JWST OBSERVATIONS AND RETRIEVALS OF TRANSITING EXOPLANET ATMOSPHERES

    Energy Technology Data Exchange (ETDEWEB)

    Howe, Alex R.; Burrows, Adam [Department of Astronomy, University of Michigan, 1085 S. University, Ann Arbor, MI 48109 (United States); Deming, Drake, E-mail: arhowe@umich.edu, E-mail: burrows@astro.princeton.edu, E-mail: ddeming@astro.umd.edu [Department of Astronomy, University of Maryland College Park, MD 20742 (United States)

    2017-01-20

    We provide an example of an analysis to explore the optimization of observations of transiting hot Jupiters with the James Webb Space Telescope ( JWST ) to characterize their atmospheres based on a simple three-parameter forward model. We construct expansive forward model sets for 11 hot Jupiters, 10 of which are relatively well characterized, exploring a range of parameters such as equilibrium temperature and metallicity, as well as considering host stars over a wide range in brightness. We compute posterior distributions of our model parameters for each planet with all of the available JWST spectroscopic modes and several programs of combined observations and compute their effectiveness using the metric of estimated mutual information per degree of freedom. From these simulations, clear trends emerge that provide guidelines for designing a JWST observing program. We demonstrate that these guidelines apply over a wide range of planet parameters and target brightnesses for our simple forward model.

  16. ULTRAVIOLET AND EXTREME-ULTRAVIOLET EMISSIONS AT THE FLARE FOOTPOINTS OBSERVED BY ATMOSPHERE IMAGING ASSEMBLY

    Energy Technology Data Exchange (ETDEWEB)

    Qiu Jiong; Longcope, Dana W.; Liu Wenjuan [Department of Physics, Montana State University, Bozeman, MT 59717-3840 (United States); Sturrock, Zoe [Department of Applied Mathematics, University of St. Andrews (United Kingdom); Klimchuk, James A. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)

    2013-09-01

    A solar flare is composed of impulsive energy release events by magnetic reconnection, which forms and heats flare loops. Recent studies have revealed a two-phase evolution pattern of UV 1600 A emission at the feet of these loops: a rapid pulse lasting for a few seconds to a few minutes, followed by a gradual decay on timescales of a few tens of minutes. Multiple band EUV observations by the Atmosphere Imaging Assembly further reveal very similar signatures. These two phases represent different but related signatures of an impulsive energy release in the corona. The rapid pulse is an immediate response of the lower atmosphere to an intense thermal conduction flux resulting from the sudden heating of the corona to high temperatures (we rule out energetic particles due to a lack of significant hard X-ray emission). The gradual phase is associated with the cooling of hot plasma that has been evaporated into the corona. The observed footpoint emission is again powered by thermal conduction (and enthalpy), but now during a period when approximate steady-state conditions are established in the loop. UV and EUV light curves of individual pixels may therefore be separated into contributions from two distinct physical mechanisms to shed light on the nature of energy transport in a flare. We demonstrate this technique using coordinated, spatially resolved observations of UV and EUV emissions from the footpoints of a C3.2 thermal flare.

  17. A SAR Observation and Numerical Study on Ocean Surface Imprints of Atmospheric Vortex Streets

    Directory of Open Access Journals (Sweden)

    William G. Pichel

    2008-05-01

    Full Text Available The sea surface imprints of Atmospheric Vortex Street (AVS off Aleutian Volcanic Islands, Alaska were observed in two RADARSAT-1 Synthetic Aperture Radar (SAR images separated by about 11 hours. In both images, three pairs of distinctive vortices shedding in the lee side of two volcanic mountains can be clearly seen. The length and width of the vortex street are about 60-70 km and 20 km, respectively. Although the AVS’s in the two SAR images have similar shapes, the structure of vortices within the AVS is highly asymmetrical. The sea surface wind speed is estimated from the SAR images with wind direction input from Navy NOGAPS model. In this paper we present a complete MM5 model simulation of the observed AVS. The surface wind simulated from the MM5 model is in good agreement with SAR-derived wind. The vortex shedding rate calculated from the model run is about 1 hour and 50 minutes. Other basic characteristics of the AVS including propagation speed of the vortex, Strouhal and Reynolds numbers favorable for AVS generation are also derived. The wind associated with AVS modifies the cloud structure in the marine atmospheric boundary layer. The AVS cloud pattern is also observed on a MODIS visible band image taken between the two RADARSAT SAR images. An ENVISAT advance SAR image taken 4 hours after the second RADARSAT SAR image shows that the AVS has almost vanished.

  18. Approach to simultaneously denoise and invert backscatter and extinction from photon-limited atmospheric lidar observations.

    Science.gov (United States)

    Marais, Willem J; Holz, Robert E; Hu, Yu Hen; Kuehn, Ralph E; Eloranta, Edwin E; Willett, Rebecca M

    2016-10-10

    Atmospheric lidar observations provide a unique capability to directly observe the vertical column of cloud and aerosol scattering properties. Detector and solar-background noise, however, hinder the ability of lidar systems to provide reliable backscatter and extinction cross-section estimates. Standard methods for solving this inverse problem are most effective with high signal-to-noise ratio observations that are only available at low resolution in uniform scenes. This paper describes a novel method for solving the inverse problem with high-resolution, lower signal-to-noise ratio observations that are effective in non-uniform scenes. The novelty is twofold. First, the inferences of the backscatter and extinction are applied to images, whereas current lidar algorithms only use the information content of single profiles. Hence, the latent spatial and temporal information in noisy images are utilized to infer the cross-sections. Second, the noise associated with photon-counting lidar observations can be modeled using a Poisson distribution, and state-of-the-art tools for solving Poisson inverse problems are adapted to the atmospheric lidar problem. It is demonstrated through photon-counting high spectral resolution lidar (HSRL) simulations that the proposed algorithm yields inverted backscatter and extinction cross-sections (per unit volume) with smaller mean squared error values at higher spatial and temporal resolutions, compared to the standard approach. Two case studies of real experimental data are also provided where the proposed algorithm is applied on HSRL observations and the inverted backscatter and extinction cross-sections are compared against the standard approach.

  19. Characterising fifteen years of continuous atmospheric radon activity observations at Cape Point (South Africa)

    Science.gov (United States)

    Botha, R.; Labuschagne, C.; Williams, A. G.; Bosman, G.; Brunke, E.-G.; Rossouw, A.; Lindsay, R.

    2018-03-01

    This paper describes and discusses fifteen years (1999-2013) of continuous hourly atmospheric radon (222Rn) monitoring at the coastal low-altitude Southern Hemisphere Cape Point Station in South Africa. A strong seasonal cycle is evident in the observed radon concentrations, with maxima during the winter months, when air masses arriving at the Cape Point station from over the African continental surface are more frequently observed, and minima during the summer months, when an oceanic fetch is predominant. An atmospheric mean radon activity concentration of 676 ± 2 mBq/m3 is found over the 15-year record, having a strongly skewed distribution that exhibits a large number of events falling into a compact range of low values (corresponding to oceanic air masses), and a smaller number of events with high radon values spread over a wide range (corresponding to continental air masses). The mean radon concentration from continental air masses (1 004 ± 6 mBq/m3) is about two times higher compared to oceanic air masses (479 ± 3 mBq/m3). The number of atmospheric radon events observed is strongly dependent on the wind direction. A power spectral Fast Fourier Transform analysis of the 15-year radon time series reveals prominent peaks at semi-diurnal, diurnal and annual timescales. Two inter-annual radon periodicities have been established, the diurnal 0.98 ± 0.04 day-1 and half-diurnal 2.07 ± 0.15 day-1. The annual peak reflects major seasonal changes in the patterns of offshore versus onshore flow associated with regional/hemispheric circulation patterns, whereas the diurnal and semi-diurnal peaks together reflect the influence of local nocturnal radon build-up over land, and the interplay between mesoscale sea/land breezes. The winter-time diurnal radon concentration had a significant decrease of about 200 mBq/m3 (17%) while the summer-time diurnal radon concentration revealed nearly no changes. A slow decline in the higher radon percentiles (75th and 95th) for the

  20. South African carbon observations: CO2 measurements for land, atmosphere and ocean

    CSIR Research Space (South Africa)

    Feig, Gregor T

    2017-11-01

    Full Text Available , Mudau AE, Monteiro PMS. South African carbon observations: CO2 measurements for land, atmosphere and ocean. S Afr J Sci. 2017;113(11/12), Art. #a0237, 4 pages. http://dx.doi. org/10.17159/sajs.2017/a0237 Carbon dioxide plays a central role in earth... References 1. Houghton RA. Balancing the global carbon budget. Annu Rev Earth Planet Sci. 2007;35:313–347. https://doi.org/10.1146/annurev. earth.35.031306.140057 2. Denman KL. Climate change, ocean processes and ocean iron fertilization. Mar Ecol Prog Ser...

  1. Potentialities and Limits of ICESAT-2 Observation for Atmospheric Aerosol Investigation

    Directory of Open Access Journals (Sweden)

    Mona L.

    2016-01-01

    Full Text Available ICESat-2(Ice, Cloud, and land Elevation Satellite-2, slated for launch in 2017, will continue the important observations of ice-sheet elevation change, sea-ice freeboard, and vegetation canopy height begun by ICESat in 2003. Among the other potential applications, ICESat-2 could provide some information about atmospheric aerosol over Polar Regions thanks to the lidar instrument. In this context, it is essential to demonstrate the ICESat-2 capability of providing vertical profiles of the aerosol backscatter coefficient and to define its potentialities and limits. First results of this investigation are reported and will be presented at the conference.

  2. A global perspective on atmospheric blocking using GPS radio occultation – one decade of observations

    Directory of Open Access Journals (Sweden)

    L. Brunner

    2017-12-01

    Full Text Available Atmospheric blocking represents a weather pattern where a stationary high-pressure system weakens or reverses the climatological westerly flow at mid-latitudes for up to several weeks. It is closely connected to strong anomalies in key atmospheric variables such as geopotential height, temperature, and humidity. Here we provide, for the first time, a comprehensive, global perspective on atmospheric blocking and related impacts by using an observation-based data set from Global Positioning System (GPS radio occultation (RO from 2006 to 2016. The main blocking regions in both hemispheres and seasonal variations are found to be represented well in RO data. The effect of blocking on vertically resolved temperature and humidity anomalies in the troposphere and lower stratosphere is investigated for blocking regions in the Northern and Southern hemispheres, respectively. We find a statistically significant correlation of blocking with positive temperature anomalies, exceeding 3 K in the troposphere, and a reversal above the tropopause with negative temperature anomalies below −3 K in the lower stratosphere. Specific humidity is positively correlated with temperature throughout the troposphere with larger anomalies revealed in the Southern Hemisphere. At the eastern and equatorward side of the investigated blocking regions, a band of tropospheric cold anomalies reveals advection of cold air by anticyclonic motion around blocking highs, which is less distinct in the Southern Hemisphere due to stronger zonal flow. We find GPS RO to be a promising new data set for blocking research that gives insight into the vertical atmospheric structure, especially in light of the expected increase in data coverage that future missions will provide.

  3. In-situ transmission electron microscopy observation of slip propagation in ä3 bicrystals

    Czech Academy of Sciences Publication Activity Database

    Gemperlová, Juliana; Jacques, A.; Gemperle, Antonín; Vystavěl, Tomáš; Zárubová, Niva; Janecek, M.

    2002-01-01

    Roč. 324, - (2002), s. 183-189 ISSN 0921-5093 R&D Projects: GA ČR GA202/98/1281 Institutional research plan: CEZ:AV0Z1010914 Keywords : in- situ TEM deformation * propagation of slip * plastic deformation * grain boundary * symmetrical ä3 bicrystal Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 1.107, year: 2002

  4. Observation of methanol behavior in fuel cells in situ by NMR spectroscopy.

    Science.gov (United States)

    Han, Oc Hee; Han, Kee Sung; Shin, Chang Woo; Lee, Juhee; Kim, Seong-Soo; Um, Myung Sup; Joh, Han-Ik; Kim, Soo-Kil; Ha, Heung Yong

    2012-04-16

    The chemical conversion of methanol in direct methanol fuel cells was followed in situ by NMR spectroscopy. Comparing data of the methanol oxidation on Pt and PtRu anode catalysts allowed the role of Ru in both Faradaic and non-Faradaic reactions to be investigated. The spatial distributions of chemicals could also be determined. (Picture: T1-T4=inlet and outlet tubes.). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. In situ observation and neutron diffraction of NiTi powder sintering

    International Nuclear Information System (INIS)

    Chen, Gang; Liss, Klaus-Dieter; Cao, Peng

    2014-01-01

    This study investigated NiTi powder sintering behaviour from elemental powder mixtures of Ni/Ti and Ni/TiH 2 using in situ neutron diffraction and in situ scanning electron microscopy. The sintered porous alloys have open porosities ranging from 2.7% to 36.0%. In comparison to the Ni/Ti compact, dehydrogenation occurring in the Ni/TiH 2 compact leads to less densification yet higher chemical homogenization only after high-temperature sintering. For the first time, direct evidence of the eutectoid phase transformation of NiTi at 620 °C is reported by in situ neutron diffraction. A comparative study of cyclic stress–strain behaviours of the porous NiTi alloys made from Ni/Ti and Ni/TiH 2 compacts indicate that the samples sintered from the Ni/TiH 2 compact exhibited a much higher porosity, larger pore size, lower fracture strength, lower close-to-overall porosity ratio and lower Young’s modulus. Instead of enhanced densification by the use of TiH 2 as reported in the literature, this study shows an adverse effect of TiH 2 on powder densification in NiTi

  6. In situ observations of meteor smoke particles (MSP during the Geminids 2010: constraints on MSP size, work function and composition

    Directory of Open Access Journals (Sweden)

    M. Rapp

    2012-12-01

    Full Text Available We present in situ observations of meteoric smoke particles (MSP obtained during three sounding rocket flights in December 2010 in the frame of the final campaign of the Norwegian-German ECOMA project (ECOMA = Existence and Charge state Of meteoric smoke particles in the Middle Atmosphere. The flights were conducted before, at the maximum activity, and after the decline of the Geminids which is one of the major meteor showers over the year. Measurements with the ECOMA particle detector yield both profiles of naturally charged particles (Faraday cup measurement as well as profiles of photoelectrons emitted by the MSPs due to their irradiation by photons of a xenon-flash lamp. The column density of negatively charged MSPs decreased steadily from flight to flight which is in agreement with a corresponding decrease of the sporadic meteor flux recorded during the same period. This implies that the sporadic meteors are a major source of MSPs while the additional influx due to the shower meteors apparently did not play any significant role. Surprisingly, the profiles of photoelectrons are only partly compatible with this observation: while the photoelectron current profiles obtained during the first and third flight of the campaign showed a qualitatively similar behaviour as the MSP charge density data, the profile from the second flight (i.e., at the peak of the Geminids shows much smaller photoelectron currents. This may tentatively be interpreted as a different MSP composition (and, hence, different photoelectric properties during this second flight, but at this stage we are not in a position to conclude that there is a cause and effect relation between the Geminids and this observation. Finally, the ECOMA particle detector used during the first and third flight employed three instead of only one xenon flash lamp where each of the three lamps used for one flight had a different window material resulting in different cut off wavelengths for these

  7. Global emissions of the hydrofluorocarbons (HFCs) HFC-365mfc, HFC-245fa, HFC-227ea, and HFC-236fa based on atmospheric observations

    Science.gov (United States)

    Vollmer, M. K.; Miller, B. R.; Rigby, M. L.; Reimann, S.; Muhle, J.; Agage, Soge, Snu Members, Kopri Members

    2010-12-01

    We report on the atmospheric measurements and global emissions of the hydrofluorocarbons (HFCs) HFC-365mfc (CH3CH2CF2CF3, 1,1,1,3,3-pentafluorobutane), HFC-245fa (CHF2CH2CF3, 1,1,1,3,3-pentafluoropropane), HFC-227ea (CF3CHFCF3, 1,1,1,2,3,3,3-heptafluoropropane), and HFC-236fa (CF3CH2CF3, 1,1,1,3,3,3-hexafluoropropane). These measurements are from in-situ observations at stations of AGAGE (Advanced Global Atmospheric Gases Experiment) and SOGE (System for Observations of Halogenated Greenhouse Gases in Europe), and from the Korean station Gosan. We also report on flask sample measurements from the Antarctic stations King Sejong and Troll, and extend our records back to the 1970s using archived air samples of both hemispheres. All data are used in a global 12-box 2-dimensional atmospheric transport model to derive global abundances and emission estimates. All four HFCs have strongly increased in the atmosphere in recent years with growth rates at nearly 10 %, resulting in dry air mole fractions at the end of 2009 of 0.49 ppt for HFC-365mfc, 1.00 ppt for HFC-245fa, and 0.51 ppt for HFC-227ea. HFC-236fa, for which we report the first atmospheric measurements, is less abundant and has grown to 0.069 ppt at the end of 2009. Our model results show rapidly growing emissions of HFC-365mfc and HFC-245fa after 2002 but surprisingly these have now started to decline to globally 2.7 kt/yr (HFC-365mfc) and 6.1 kt/yr (HFC-245fa). On the other hand HFC-227ea and HFC-236fa show uninterrupted growth in their emissions of 2.5 kt/yr and 0.2 kt/yr at the end of 2009.

  8. Ground-based Observations and Atmospheric Modelling of Energetic Electron Precipitation Effects on Antarctic Mesospheric Chemistry

    Science.gov (United States)

    Newnham, D.; Clilverd, M. A.; Horne, R. B.; Rodger, C. J.; Seppälä, A.; Verronen, P. T.; Andersson, M. E.; Marsh, D. R.; Hendrickx, K.; Megner, L. S.; Kovacs, T.; Feng, W.; Plane, J. M. C.

    2016-12-01

    The effect of energetic electron precipitation (EEP) on the seasonal and diurnal abundances of nitric oxide (NO) and ozone in the Antarctic middle atmosphere during March 2013 to July 2014 is investigated. Geomagnetic storm activity during this period, close to solar maximum, was driven primarily by impulsive coronal mass ejections. Near-continuous ground-based atmospheric measurements have been made by a passive millimetre-wave radiometer deployed at Halley station (75°37'S, 26°14'W, L = 4.6), Antarctica. This location is directly under the region of radiation-belt EEP, at the extremity of magnetospheric substorm-driven EEP, and deep within the polar vortex during Austral winter. Superposed epoch analyses of the ground based data, together with NO observations made by the Solar Occultation For Ice Experiment (SOFIE) onboard the Aeronomy of Ice in the Mesosphere (AIM) satellite, show enhanced mesospheric NO following moderate geomagnetic storms (Dst ≤ -50 nT). Measurements by co-located 30 MHz riometers indicate simultaneous increases in ionisation at 75-90 km directly above Halley when Kp index ≥ 4. Direct NO production by EEP in the upper mesosphere, versus downward transport of NO from the lower thermosphere, is evaluated using a new version of the Whole Atmosphere Community Climate Model incorporating the full Sodankylä Ion Neutral Chemistry Model (WACCM SIC). Model ionization rates are derived from the Polar orbiting Operational Environmental Satellites (POES) second generation Space Environment Monitor (SEM 2) Medium Energy Proton and Electron Detector instrument (MEPED). The model data are compared with observations to quantify the impact of EEP on stratospheric and mesospheric odd nitrogen (NOx), odd hydrogen (HOx), and ozone.

  9. Video Observations, Atmospheric Path, Orbit and Fragmentation Record of the Fall of the Peekskill Meteorite

    Science.gov (United States)

    Ceplecha, Z.; Brown, P.; Hawkes, R. L.; Wertherill, G.; Beech, M.; Mossman, K.

    1996-02-01

    Large Near-Earth-Asteroids have played a role in modifying the character of the surface geology of the Earth over long time scales through impacts. Recent modeling of the disruption of large meteoroids during atmospheric flight has emphasized the dramatic effects that smaller objects may also have on the Earth's surface. However, comparison of these models with observations has not been possible until now. Peekskill is only the fourth meteorite to have been recovered for which detailed and precise data exist on the meteoroid atmospheric trajectory and orbit. Consequently, there are few constraints on the position of meteorites in the solar system before impact on Earth. In this paper, the preliminary analysis based on 4 from all 15 video recordings of the fireball of October 9, 1992 which resulted in the fall of a 12.4 kg ordinary chondrite (H6 monomict breccia) in Peekskill, New York, will be given. Preliminary computations revealed that the Peekskill fireball was an Earth-grazing event, the third such case with precise data available. The body with an initial mass of the order of 104 kg was in a pre-collision orbit with a = 1.5 AU, an aphelion of slightly over 2 AU and an inclination of 5‡. The no-atmosphere geocentric trajectory would have lead to a perigee of 22 km above the Earth's surface, but the body never reached this point due to tremendous fragmentation and other forms of ablation. The dark flight of the recovered meteorite started from a height of 30 km, when the velocity dropped below 3 km/s, and the body continued 50 km more without ablation, until it hit a parked car in Peekskill, New York with a velocity of about 80 m/s. Our observations are the first video records of a bright fireball and the first motion pictures of a fireball with an associated meteorite fall.

  10. Mapping Submerged Habitats and Mangroves of Lampi Island Marine National Park (Myanmar from in Situ and Satellite Observations

    Directory of Open Access Journals (Sweden)

    Claudia Giardino

    2015-12-01

    Full Text Available In this study we produced the first thematic maps of submerged and coastal habitats of Lampi Island (Myanmar from in situ and satellite data. To focus on key elements of bio-diversity typically existing in tropical islands the detection of corals, seagrass, and mangrove forests was addressed. Satellite data were acquired from Landsat-8; for the purpose of validation Rapid-Eye data were also used. In situ data supporting image processing were collected in a field campaign performed from 28 February to 4 March 2015 at the time of sensors overpasses. A hybrid approach based on bio-optical modeling and supervised classification techniques was applied to atmospherically-corrected Landsat-8 data. Bottom depth estimations, to be used in the classification process of shallow waters, were in good agreement with depth soundings (R2 = 0.87. Corals were classified with producer and user accuracies of 58% and 77%, while a lower accuracy (producer and user accuracies of 50% was found for the seagrass due to the patchy distribution of meadows; accuracies more than 88% were obtained for mangrove forests. The classification indicated the presence of 18 mangroves sites with extension larger than 5 km2; for 15 of those the coexistence of corals and seagrass were also found in the fronting bays, suggesting a significant rate of biodiversity for the study area.

  11. In-situ observation of deuteride formation in palladium electrochemical cathode by X-ray diffraction method

    International Nuclear Information System (INIS)

    Yamamoto, Takao; Oka, Takashi; Taniguchi, Ryoichi

    1990-01-01

    In-situ X-ray diffraction observation of palladium foil cathode (10 μm) was carried out during electrolysis of 0.1N-LiOD heavy water solution in order to estimate the deuterium content in palladium during the detection of charged particles in our previous work. A complete transformation into β-palladium deuteride phase was observed, and its maximum lattice constant 4.06 A was evaluated as corresponding to D/Pd = 0.73. The deuterium concentration in the previous work was estimated as higher than this considering the difference in cell conditions. (author)

  12. Microphysical Characteristics of Atmospheric Particulate Matter from NASA’s MODIS, MISR, and AERONET Observations

    International Nuclear Information System (INIS)

    Gad, N; Ibrahim, Alaa; Shokr, M

    2017-01-01

    We present a comparative study of atmospheric particulate matter (also known as aerosols) observed by satellite remote sensing and ground-based observations. We compare satellite measurements obtained by NASA’s Moderate Resolution Imaging Spectro-Radiometer (MODIS) and Multi-angle Imaging Spectro-Radiometer (MISR) instruments against the ground-based aerosol sun-photometer data from the Aerosol Robotic Network (AERONET) station in Cairo, Egypt from 2003 to 2014 to build a long-term database for climatological studies and to improve upon the accuracy and coverage achievable from the satellite data. We deduce microphysical and geometrical properties about the dominant aerosols based on key optical properties including aerosol optical depth (AOD), single scattering albedo (SSA), and Ångström exponent (AE). This has allowed us to place important constraints on the type of aerosols (natural, anthropogenic, and biogenic). (paper)

  13. Astronomical and Atmospheric Observations in the Anglo-Saxon Chronicle and in Bede

    Science.gov (United States)

    Härke, H.

    2012-01-01

    Textual sources of the early Middle Ages (fifth to tenth centuries AD) contain more astronomical observations than is popularly assumed. The Anglo-Saxon Chronicle lists some 40 observations of astronomical and atmospheric events for the just over 600 years it covers. But the contexts in which these are set show that eclipses, comets, meteor showers and aurorae were seen as portents of evil events, not as objects of early scientific curiosity. The case of Bede in the early eighth century shows that this was true, to an extent, even for the educated ecclesiastical elite. BedeÕs eclipse records also appear to show that astronomical events could be used to explain unusual phenomena such as the postulated volcanic Ôdust-veilÕ event of AD 536.

  14. In situ QXAFS observation of the reduction of Fe2O3 and CaFe2O4

    International Nuclear Information System (INIS)

    Kimura, Masao; Takayama, Toru; Murao, Reiko; Nomura, Masaharu; Uemura, Yohei; Asakura, Kiyotaka

    2013-01-01

    In situ QXAFS studies of the reduction of α-Fe 2 O 3 and CaFe 2 O 4 were conducted to determine their reduction kinetics and mechanisms. The reduction of α-Fe 2 O 3 involved two steps, the first being a very fast process in which Fe 3+ was reduced to Fe 2+ and the second being the reduction of Fe 2+ to Fe metal over a longer period. In contrast, the reduction of Fe in CaFe 2 O 4 was a single first-order reaction, although an induction period was clearly observed at the beginning of the reduction process. The reduction processes were successfully studied using a combination of in situ QXAFS spectra at the Ca and Fe K-edges.

  15. In situ TEM observations of unusual nanocrystallization in a Ti-based bulk metallic glass

    International Nuclear Information System (INIS)

    Yan, M.; Wang, D.J.; Shen, J.; Qian, M.

    2011-01-01

    In situ transmission electron microscopy (TEM) has been used to witness the nanocrystallization of amorphous Ti 42.5 Cu 40 Zr 10 Ni 5 Sn 2.5 . A crystallization front exists to separate the TEM sample into two parts with different thermal stabilities. The number density of the crystallization products varies significantly, with the precipitate sizes ranging from a few nanometres to ∼100 nm. Detailed TEM analysis suggests that oxygen is the most likely reason for realizing the unusual nanocrystallization. External thermal analysis also indicates that oxygen affects the crystallization.

  16. In situ observation of triple junction motion during recovery of heavily deformed aluminum

    DEFF Research Database (Denmark)

    Yu, Tianbo; Hughes, Darcy A.; Hansen, Niels

    2015-01-01

    -junctions are pinned by deformation-induced interconnecting and lamellar boundaries, which slow down the recovery process and lead to a stop-go migration pattern. This pinning mechanism stabilizes the deformation microstructure, i.e. the structure is stabilized by balancing the driving and pinning forces controlling......Microstructural evolution during in situ annealing of heavily cold-rolled aluminum has been studied by transmission electron microscopy, confirming that an important recovery mechanism is migration of triple junctions formed by three lamellar boundaries (Y-junctions). The migrating Y...

  17. Nucleation of recrystallization observed in situ in the bulk of a deformed metal

    International Nuclear Information System (INIS)

    Larsen, Axel W.; Poulsen, Henning F.; Margulies, Lawrence; Gundlach, Carsten; Xing Qingfeng; Huang Xiaoxu; Jensen, Dorte Juul

    2005-01-01

    Nucleation of recrystallization is studied in situ in the bulk by three-dimensional X-ray diffraction. Copper samples cold rolled 20% are investigated. The crystallographic orientations near triple junction lines are characterized before, during and after annealing. Three nuclei are identified and it is shown that two nuclei are twin related to their parent grain and one nucleus has an orientation, which is neither present in the deformed parent grains nor first order twin related to any of them. Data on the nucleation kinetics is also presented

  18. Global observations and modeling of atmosphere-surface exchange of elemental mercury: a critical review

    Science.gov (United States)

    Zhu, Wei; Lin, Che-Jen; Wang, Xun; Sommar, Jonas; Fu, Xuewu; Feng, Xinbin

    2016-04-01

    Reliable quantification of air-surface fluxes of elemental Hg vapor (Hg0) is crucial for understanding mercury (Hg) global biogeochemical cycles. There have been extensive measurements and modeling efforts devoted to estimating the exchange fluxes between the atmosphere and various surfaces (e.g., soil, canopies, water, snow, etc.) in the past three decades. However, large uncertainties remain due to the complexity of Hg0 bidirectional exchange, limitations of flux quantification techniques and challenges in model parameterization. In this study, we provide a critical review on the state of science in the atmosphere-surface exchange of Hg0. Specifically, the advancement of flux quantification techniques, mechanisms in driving the air-surface Hg exchange and modeling efforts are presented. Due to the semi-volatile nature of Hg0 and redox transformation of Hg in environmental media, Hg deposition and evasion are influenced by multiple environmental variables including seasonality, vegetative coverage and its life cycle, temperature, light, moisture, atmospheric turbulence and the presence of reactants (e.g., O3, radicals, etc.). However, the effects of these processes on flux have not been fundamentally and quantitatively determined, which limits the accuracy of flux modeling. We compile an up-to-date global observational flux database and discuss the implication of flux data on the global Hg budget. Mean Hg0 fluxes obtained by micrometeorological measurements do not appear to be significantly greater than the fluxes measured by dynamic flux chamber methods over unpolluted surfaces (p = 0.16, one-tailed, Mann-Whitney U test). The spatiotemporal coverage of existing Hg0 flux measurements is highly heterogeneous with large data gaps existing in multiple continents (Africa, South Asia, Middle East, South America and Australia). The magnitude of the evasion flux is strongly enhanced by human activities, particularly at contaminated sites. Hg0 flux observations in East

  19. Some characteristics of atmospheric gravity waves observed by radio-interferometry

    Directory of Open Access Journals (Sweden)

    Claude Mercier

    Full Text Available Observations of atmospheric acoustic-gravity waves (AGWs are considered through their effect on the horizontal gradient G of the slant total electron content (slant TEC, which can be directly obtained from two-dimensional radio-interferometric observations of cosmic radio-sources with the Nançay radioheligraph (2.2°E, 47.3°N. Azimuths of propagation can be deduced (modulo 180°. The total database amounts to about 800 h of observations at various elevations, local time and seasons. The main results are:

    a AGWs are partially directive, confirming our previous results.

    b The propagation azimuths considered globally are widely scattered with a preference towards the south.

    c They show a bimodal time distribution with preferential directions towards the SE during daytime and towards the SW during night-time (rather than a clockwise rotation as reported by previous authors.

    d The periods are scattered but are larger during night-time than during daytime by about 60%.

    e The effects observed with the solar radio-sources are significantly stronger than with other radio-sources (particularly at higher elevations, showing the role of the geometry in line of sight-integrated observations.

  20. Constraining atmospheric ammonia emissions through new observations with an open-path, laser-based sensor

    Science.gov (United States)

    Sun, Kang

    As the third most abundant nitrogen species in the atmosphere, ammonia (NH3) is a key component of the global nitrogen cycle. Since the industrial revolution, humans have more than doubled the emissions of NH3 to the atmosphere by industrial nitrogen fixation, revolutionizing agricultural practices, and burning fossil fuels. NH3 is a major precursor to fine particulate matter (PM2.5), which has adverse impacts on air quality and human health. The direct and indirect aerosol radiative forcings currently constitute the largest uncertainties for future climate change predictions. Gas and particle phase NH3 eventually deposits back to the Earth's surface as reactive nitrogen, leading to the exceedance of ecosystem critical loads and perturbation of ecosystem productivity. Large uncertainties still remain in estimating the magnitude and spatiotemporal patterns of NH3 emissions from all sources and over a range of scales. These uncertainties in emissions also propagate to the deposition of reactive nitrogen. To improve our understanding of NH3 emissions, observational constraints are needed from local to global scales. The first part of this thesis is to provide quality-controlled, reliable NH3 measurements in the field using an open-path, quantum cascade laser-based NH3 sensor. As the second and third part of my research, NH3 emissions were quantified from a cattle feedlot using eddy covariance (EC) flux measurements, and the similarities between NH3 turbulent fluxes and those of other scalars (temperature, water vapor, and CO2) were investigated. The fourth part involves applying a mobile laboratory equipped with the open-path NH3 sensor and other important chemical/meteorological measurements to quantify fleet-integrated NH3 emissions from on-road vehicles. In the fifth part, the on-road measurements were extended to multiple major urban areas in both the US and China in the context of five observation campaigns. The results significantly improved current urban NH3

  1. Decomposing Shortwave Top-of-Atmosphere Radiative Flux Variability in Terms of Surface and Atmospheric Contributions Using CERES Observations

    Science.gov (United States)

    Loeb, N. G.; Wong, T.; Wang, H.

    2017-12-01

    Earth's climate is determined by the exchange of radiant energy between the Sun, Earth and space. The absorbed solar radiation (ASR) fuels the climate system, providing the energy required for atmospheric and oceanic motions, while the system cools by emitting outgoing longwave (LW) radiation to space. A central objective of the Clouds and the Earth's Radiant Energy System (CERES) is to produce a long-term global climate data record of Earth's radiation budget along with the associated atmospheric and surface properties that influence it. CERES data products utilize a number of data sources, including broadband radiometers measuring incoming and reflected solar radiation and OLR, polar orbiting and geostationary spectral imagers, meteorological, aerosol and ozone assimilation data, and snow/sea-ice maps based on microwave radiometer data. Here we use simple diagnostic model of Earth's albedo and CERES Energy Balanced and Filled (EBAF) Ed4.0 data for March 2000-February 2016 to quantify interannual variations in SW TOA flux associated with surface albedo and atmospheric reflectance and transmittance variations. Surface albedo variations account for cloud properties over the Arctic Ocean.

  2. Emergence of granular-sized magnetic bubbles through the solar atmosphere. I. Spectropolarimetric observations and simulations

    Energy Technology Data Exchange (ETDEWEB)

    Ortiz, Ada; Hansteen, Viggo H.; Van der Voort, Luc Rouppe [Institute of Theoretical Astrophysics, University of Oslo, P.O. Box 1029 Blindern, N-0315 Oslo (Norway); Bellot Rubio, Luis R. [Instituto de Astrofísica de Andalucía (CSIC), Apdo. 3040, E-18080 Granada (Spain); De la Cruz Rodríguez, Jaime, E-mail: ada@astro.uio.no [Department of Physics and Astronomy, Uppsala University, Box 516, SE-75120 Uppsala (Sweden)

    2014-02-01

    We study a granular-sized magnetic flux emergence event that occurred in NOAA 11024 in 2009 July. The observations were made with the CRISP spectropolarimeter at the Swedish 1 m Solar Telescope achieving a spatial resolution of 0.''14. Simultaneous full Stokes observations of the two photospheric Fe I lines at 630.2 nm and the chromospheric Ca II 854.2 nm line allow us to describe in detail the emergence process across the solar atmosphere. We report here on three-dimensional (3D) semi-spherical bubble events, where instead of simple magnetic footpoints, we observe complex semi-circular feet straddling a few granules. Several phenomena occur simultaneously, namely, abnormal granulation, separation of opposite-polarity legs, and brightenings at chromospheric heights. However, the most characteristic signature in these events is the observation of a dark bubble in filtergrams taken in the wings of the Ca II 854.2 nm line. There is a clear coincidence between the emergence of horizontal magnetic field patches and the formation of the dark bubble. We can infer how the bubble rises through the solar atmosphere as we see it progressing from the wings to the core of Ca II 854.2 nm. In the photosphere, the magnetic bubble shows mean upward Doppler velocities of 2 km s{sup –1} and expands at a horizontal speed of 4 km s{sup –1}. In about 3.5 minutes it travels some 1100 km to reach the mid chromosphere, implying an average ascent speed of 5.2 km s{sup –1}. The maximum separation attained by the magnetic legs is 6.''6. From an inversion of the observed Stokes spectra with the SIR code, we find maximum photospheric field strengths of 480 G and inclinations of nearly 90° in the magnetic bubble interior, along with temperature deficits of up to 250 K at log τ = –2 and above. To aid the interpretation of the observations, we carry out 3D numerical simulations of the evolution of a horizontal, untwisted magnetic flux sheet injected in the convection

  3. Observable Effects of Atmospheric Pollution on Outpatient and Inpatient Morbidity in Bulgaria.

    Science.gov (United States)

    Platikanova, Magdalena; Penkova-Radicheva, Mariana

    2016-04-01

    One of Europe's most well-developed industrial regions is found in the Republic of Bulgaria. The industrialization of the region has a big impact on air pollution. Thermal power plant "Maritza East" (the largest of its kind in southeastern Europe), the army training range, machine manufacturers, household heating and high volume of automobile traffic are all major sources of pollution in the region. A five year study (2009-2013) followed yearly concentrations of principal atmospheric pollutants such as sulfur dioxide, dust, nitrogen dioxide, lead aerosols and hydrogen sulfide, and the way in which those levels had an effect on morbidity (outpatient and inpatient medical care) in the area. Statistical processing of data has been completed to represent and analyze the collected data in nonparametric and alternative format. Atmospheric pollution affects human health directly through pathological changes in the human organism. The registered outpatient care provided for the period 2009-2013 is highest for diseases of the cardiovascular system (11.85%), the respiratory system (17.34%) and the genitourinary system (9.76%). The registered rate of hospitalization for the same period is for diseases of the digestive system (11.90%), the cardiovascular system (11.85%), respiratory system (10.86%) and the genitourinary system (8.88%). The observed period shows a decrease in average yearly concentrations of the principal atmospheric pollutants in the industrial region (Bulgaria) and reflects a decrease in morbidity based on outpatient care and an increase in morbidity by inpatient care (hospitalization). Our findings should be corroborated in future longitudinal studies.

  4. An Observational Diagnostic for Distinguishing between Clouds and Haze in Hot Exoplanet Atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Kempton, Eliza M.-R. [Department of Physics, Grinnell College, 1116 8th Avenue, Grinnell, IA 50112 (United States); Bean, Jacob L. [Department of Astronomy and Astrophysics, University of Chicago, 5640 S. Ellis Avenue, Chicago, IL 60637 (United States); Parmentier, Vivien, E-mail: kemptone@grinnell.edu [Department of Planetary Sciences and Lunar and Planetary Laboratory, The University of Arizona, Tucson, AZ 85721 (United States)

    2017-08-20

    The nature of aerosols in hot exoplanet atmospheres is one of the primary vexing questions facing the exoplanet field. The complex chemistry, multiple formation pathways, and lack of easily identifiable spectral features associated with aerosols make it especially challenging to constrain their key properties. We propose a transmission spectroscopy technique to identify the primary aerosol formation mechanism for the most highly irradiated hot Jupiters (HIHJs). The technique is based on the expectation that the two key types of aerosols—photochemically generated hazes and equilibrium condensate clouds—are expected to form and persist in different regions of a highly irradiated planet’s atmosphere. Haze can only be produced on the permanent daysides of tidally locked hot Jupiters, and will be carried downwind by atmospheric dynamics to the evening terminator (seen as the trailing limb during transit). Clouds can only form in cooler regions on the nightside and morning terminator of HIHJs (seen as the leading limb during transit). Because opposite limbs are expected to be impacted by different types of aerosols, ingress and egress spectra, which primarily probe opposing sides of the planet, will reveal the dominant aerosol formation mechanism. We show that the benchmark HIHJ, WASP-121b, has a transmission spectrum consistent with partial aerosol coverage and that ingress–egress spectroscopy would constrain the location and formation mechanism of those aerosols. In general, using this diagnostic we find that observations with the James Webb Space Telescope and potentially with the Hubble Space Telescope should be able to distinguish between clouds and haze for currently known HIHJs.

  5. An Observational Diagnostic for Distinguishing between Clouds and Haze in Hot Exoplanet Atmospheres

    International Nuclear Information System (INIS)

    Kempton, Eliza M.-R.; Bean, Jacob L.; Parmentier, Vivien

    2017-01-01

    The nature of aerosols in hot exoplanet atmospheres is one of the primary vexing questions facing the exoplanet field. The complex chemistry, multiple formation pathways, and lack of easily identifiable spectral features associated with aerosols make it especially challenging to constrain their key properties. We propose a transmission spectroscopy technique to identify the primary aerosol formation mechanism for the most highly irradiated hot Jupiters (HIHJs). The technique is based on the expectation that the two key types of aerosols—photochemically generated hazes and equilibrium condensate clouds—are expected to form and persist in different regions of a highly irradiated planet’s atmosphere. Haze can only be produced on the permanent daysides of tidally locked hot Jupiters, and will be carried downwind by atmospheric dynamics to the evening terminator (seen as the trailing limb during transit). Clouds can only form in cooler regions on the nightside and morning terminator of HIHJs (seen as the leading limb during transit). Because opposite limbs are expected to be impacted by different types of aerosols, ingress and egress spectra, which primarily probe opposing sides of the planet, will reveal the dominant aerosol formation mechanism. We show that the benchmark HIHJ, WASP-121b, has a transmission spectrum consistent with partial aerosol coverage and that ingress–egress spectroscopy would constrain the location and formation mechanism of those aerosols. In general, using this diagnostic we find that observations with the James Webb Space Telescope and potentially with the Hubble Space Telescope should be able to distinguish between clouds and haze for currently known HIHJs.

  6. A global climatology of stratospheric gravity waves from Atmospheric Infrared Sounder observations

    Science.gov (United States)

    Hoffmann, Lars; Xue, Xianghui; Alexander, M. Joan

    2014-05-01

    We present the results of a new study that aims on the detection and classification of `hotspots' of stratospheric gravity waves on a global scale. The analysis is based on a nine-year record (2003 to 2011) of radiance measurements by the Atmospheric Infrared Sounder (AIRS) aboard NASA's Aqua satellite. We detect the presence of stratospheric gravity waves based on 4.3 micron brightness temperature variances. Our method is optimized for peak events, i.e., strong gravity wave events for which the local variance considerably exceeds background levels. We estimated the occurrence frequencies of these peak events for different seasons and time of day and used the results to find local maxima of gravity wave activity. In addition, we use AIRS radiances at 8.1 micron to simultaneously detect convective events, including deep convection in the tropics and mesoscale convective systems at mid latitudes. We classified the gravity waves according to their sources, based on seasonal occurrence frequencies for convection and by means of topographic data. Our study reproduces well-known hotspots of gravity waves, e.g., the mountain wave hotspots at the Andes and the Antarctic Peninsula or the convective hotspot during the thunderstorm season over the North American Great Plains. However, the high horizontal resolution of the AIRS observations also helped us to locate several smaller hotspots, which were partly unknown or poorly studied so far. Most of these smaller hotspots are found near orographic features like small mountain ranges, in coastal regions, in desert areas, or near isolated islands. This new study will help to select the most promising regions and seasons for future observational studies of gravity waves. Reference: Hoffmann, L., X. Xue, and M. J. Alexander, A global view of stratospheric gravity wave hotspots located with Atmospheric Infrared Sounder observations, J. Geophys. Res., 118, 416-434, doi:10.1029/2012JD018658, 2013.

  7. Development of Innovative Technology to Provide Low-Cost Surface Atmospheric Observations

    Science.gov (United States)

    Kucera, Paul; Steinson, Martin

    2016-04-01

    Accurate and reliable real-time monitoring and dissemination of observations of surface weather conditions is critical for a variety of societal applications. Applications that provide local and regional information about temperature, precipitation, moisture, and winds, for example, are important for agriculture, water resource monitoring, health, and monitoring of hazard weather conditions. In many regions in Africa (and other global locations), surface weather stations are sparsely located and/or of poor quality. Existing stations have often been sited incorrectly, not well-maintained, and have limited communications established at the site for real-time monitoring. The US National Weather Service (NWS) International Activities Office (IAO) in partnership with University Corporation for Atmospheric Research (UCAR)/National Center for Atmospheric Research (NCAR) and funded by the United States Agency for International Development (USAID) Office of Foreign Disaster Assistance (OFDA) has started an initiative to develop and deploy low-cost weather instrumentation in sparsely observed regions of the world. The goal is to provide observations for environmental monitoring, and early warning alert systems that can be deployed at weather services in developing countries. Instrumentation is being designed using innovative new technologies such as 3D printers, Raspberry Pi computing systems, and wireless communications. The initial effort is focused on designing a surface network using GIS-based tools, deploying an initial network in Zambia, and providing training to Zambia Meteorological Department (ZMD) staff. The presentation will provide an overview of the project concepts, design of the low cost instrumentation, and initial experiences deploying a surface network deployment in Zambia.

  8. Characterization of Jupiter's Atmosphere from Observation of Thermal Emission by Juno and Ground-Based Supporting Observations

    Science.gov (United States)

    Orton, G. S.; Momary, T.; Tabataba-Vakili, F.; Janssen, M. A.; Hansen, C. J.; Bolton, S. J.; Li, C.; Adriani, A.; Mura, A.; Grassi, D.; Fletcher, L. N.; Brown, S. T.; Fujiyoshi, T.; Greathouse, T. K.; Kasaba, Y.; Sato, T. M.; Stephens, A.; Donnelly, P.; Eichstädt, G.; Rogers, J.

    2017-12-01

    Ground-breaking measurements of thermal emission at very long wavelengths have been made by the Juno mission's Microwave Radiometer (MWR). We examine the relationship between these and other thermal emission measurements by the Jupiter Infrared Auroral Mapper (JIRAM) at 5 µm and ground-based supporting observations in the thermal infrared that cover the 5-25 µm range. The relevant ground-based observations of thermal emission are constituted from imaging and scanning spectroscopy obtained at the NASA Infrared Telescope Facility (IRTF), the Gemini North Telescope, the Subaru Telescope and the Very Large Telescope. A comparison of these results clarifies the physical properties responsible for the observed emissions, i.e. variability of the temperature field, the cloud field or the distribution of gaseous ammonia. Cross-references to the visible cloud field from Juno's JunoCam experiment and Earth-based images are also useful. This work continues an initial comparison by Orton et al. (2017, GRL 44, doi: 10.1002/2017GL073019) between MWR and JIRAM results, together with ancillary 5-µm IRTF imaging and with JunoCam and ground-based visible imaging. These showed a general agreement between MWR and JIRAM results for the 5-bar NH3 abundance in specific regions of low cloud opacity but only a partial correlation between MWR and 5-µm radiances emerging from the 0.5-5 bar levels of the atmosphere in general. Similar to the latter, there appears to be an inconsistent correlation between MWR channels sensitive to 0.5-10 bars and shorter-wavelength radiances in the "tails" of 5-µm hot spots , which may be the result of the greater sensitivity of the latter to particulate opacity that could depend on the evolution history of the particular features sampled. Of great importance is the interpretation of MWR radiances in terms of the variability of temperature vs. NH3 abundances in the 0.5-5 bar pressure range. This is particularly important to understand MWR results in

  9. How Cool was the Eclipse? Atmospheric Measurements and Citizen Science via NASA's GLOBE Observer

    Science.gov (United States)

    Weaver, K. L. K.; Riebeek Kohl, H.

    2017-12-01

    The solar eclipse of 2017 presented an extraordinary opportunity to engage the public in shared science activity across the entire United States. While a natural focus of the eclipse was on astronomy and heliophysics, there was also an opening for excellent connections to Earth science. Because of the excitement of the event, many people gathered for long periods before and after totality, a perfect opportunity for observations and data collection to explore the impact of the eclipse on the atmosphere. The data was collected via NASA's GLOBE Observer app, a subset of the Global Learning and Observations to Benefit the Environment Program, a citizen science project which has been active for more than 20 years training teachers to collect many different types of environmental science data with their students. GLOBE Observer expands that audience to citizen scientists who might not be connected to a school, but are still interested in collecting data. In addition to the clouds observations that are normally part of GLOBE Observer, a special temporary protocol was added for the eclipse to include air temperature. Both types of measurements were collected at regular intervals for several hours before and after the point of maximum eclipse. By crowdsourcing data from all across the United States, on and off the path of totality, the hope was to be able to see patterns that wouldn't be apparent with fewer data points. In particular, there are few sources of detailed cloud data from the ground, including cloud type as well as overall cloud cover, especially as collected during a unique natural experiment such as an eclipse. This presentation will report preliminary results of the GLOBE Observer eclipse citizen science project, including participation totals and impact, data site distribution, as well as early analyses of both temperature and cloud data.

  10. AMS Observations over Coastal California from the Biological and Oceanic Atmospheric Study (BOAS)

    Science.gov (United States)

    Bates, K. H.; Coggon, M. M.; Hodas, N.; Negron, A.; Ortega, A. M.; Crosbie, E.; Sorooshian, A.; Nenes, A.; Flagan, R. C.; Seinfeld, J.

    2015-12-01

    In July 2015, fifteen research flights were conducted on a US Navy Twin Otter aircraft as part of the Biological and Oceanic Atmospheric Study (BOAS) campaign. The flights took place near the California coast at Monterey, to investigate the effects of sea surface temperature and algal blooms on oceanic particulate emissions, the diurnal mixing of urban pollution with other airmasses, and the impacts of biological aerosols on the California atmosphere. The aircraft's payload included an aerosol mass spectrometer (AMS), a differential mobility analyzer, a cloud condensation nuclei counter, a counterflow virtual impactor, a cloudwater collector, and two instruments designed to detect biological aerosols - a wideband integrated biological spectrometer and a SpinCon II - as well as a number of meteorology and aerosol probes, two condensation particle counters, and instruments to measure gas-phase CO, CO2, O3, and NOx. Here, we describe in depth the objectives and outcomes of BOAS and report preliminary results, primarily from the AMS. We detail the spatial characteristics and meteorological variability of speciated aerosol components over a strong and persistent bloom of Pseudo-Nitzschia, the harmful algae that cause 'red tide', and report newly identified AMS markers for biological particles. Finally, we compare these results with data collected during BOAS over urban, forested, and agricultural environments, and describe the mixing observed between oceanic and terrestrial airmasses.

  11. Radon anomalies prior to earthquakes (2). Atmospheric radon anomaly observed before the Hyogoken-Nanbu earthquake

    International Nuclear Information System (INIS)

    Ishikawa, Tetsuo; Tokonami, Shinji; Yasuoka, Yumi; Shinogi, Masaki; Nagahama, Hiroyuki; Omori, Yasutaka; Kawada, Yusuke

    2008-01-01

    Before the 1995 Hyogoken-Nanbu earthquake, various geochemical precursors were observed in the aftershock area: chloride ion concentration, groundwater discharge rate, groundwater radon concentration and so on. Kobe Pharmaceutical University (KPU) is located about 25 km northeast from the epicenter and within the aftershock area. Atmospheric radon concentration had been continuously measured from 1984 at KPU, using a flow-type ionization chamber. The radon concentration data were analyzed using the smoothed residual values which represent the daily minimum of radon concentration with the exclusion of normalized seasonal variation. The radon concentration (smoothed residual values) demonstrated an upward trend about two months before the Hyogoken-Nanbu earthquake. The trend can be well fitted to a log-periodic model related to earthquake fault dynamics. As a result of model fitting, a critical point was calculated to be between 13 and 27 January 1995, which was in good agreement with the occurrence date of earthquake (17 January 1995). The mechanism of radon anomaly before earthquakes is not fully understood. However, it might be possible to detect atmospheric radon anomaly as a precursor before a large earthquake, if (1) the measurement is conducted near the earthquake fault, (2) the monitoring station is located on granite (radon-rich) areas, and (3) the measurement is conducted for more than several years before the earthquake to obtain background data. (author)

  12. A New Metric for Land-Atmosphere Coupling Strength: Applications on Observations and Modeling

    Science.gov (United States)

    Tang, Q.; Xie, S.; Zhang, Y.; Phillips, T. J.; Santanello, J. A., Jr.; Cook, D. R.; Riihimaki, L.; Gaustad, K.

    2017-12-01

    A new metric is proposed to quantify the land-atmosphere (LA) coupling strength and is elaborated by correlating the surface evaporative fraction and impacting land and atmosphere variables (e.g., soil moisture, vegetation, and radiation). Based upon multiple linear regression, this approach simultaneously considers multiple factors and thus represents complex LA coupling mechanisms better than existing single variable metrics. The standardized regression coefficients quantify the relative contributions from individual drivers in a consistent manner, avoiding the potential inconsistency in relative influence of conventional metrics. Moreover, the unique expendable feature of the new method allows us to verify and explore potentially important coupling mechanisms. Our observation-based application of the new metric shows moderate coupling with large spatial variations at the U.S. Southern Great Plains. The relative importance of soil moisture vs. vegetation varies by location. We also show that LA coupling strength is generally underestimated by single variable methods due to their incompleteness. We also apply this new metric to evaluate the representation of LA coupling in the Accelerated Climate Modeling for Energy (ACME) V1 Contiguous United States (CONUS) regionally refined model (RRM). This work is performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under Contract DE-AC52-07NA27344. LLNL-ABS-734201

  13. Retrieving 4-dimensional atmospheric boundary layer structure from surface observations and profiles over a single station

    Energy Technology Data Exchange (ETDEWEB)

    Pu, Zhaoxia [Univ. of Utah, Salt Lake City, UT (United States)

    2015-10-06

    Most routine measurements from climate study facilities, such as the Department of Energy’s ARM SGP site, come from individual sites over a long period of time. While single-station data are very useful for many studies, it is challenging to obtain 3-dimensional spatial structures of atmospheric boundary layers that include prominent signatures of deep convection from these data. The principal objective of this project is to create realistic estimates of high-resolution (~ 1km × 1km horizontal grids) atmospheric boundary layer structure and the characteristics of precipitating convection. These characteristics include updraft and downdraft cumulus mass fluxes and cold pool properties over a region the size of a GCM grid column from analyses that assimilate surface mesonet observations of wind, temperature, and water vapor mixing ratio and available profiling data from single or multiple surface stations. The ultimate goal of the project is to enhance our understanding of the properties of mesoscale convective systems and also to improve their representation in analysis and numerical simulations. During the proposed period (09/15/2011–09/14/2014) and the no-cost extension period (09/15/2014–09/14/2015), significant accomplishments have been achieved relating to the stated goals. Efforts have been extended to various research and applications. Results have been published in professional journals and presented in related science team meetings and conferences. These are summarized in the report.

  14. 100 years aerology in Lindenberg and first long-time observations in the free atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Berger, F.H.; Hantel, M. [Deutscher Wetterdienst, Meteorologisches Observatorium, Lindenberg (Germany)

    2005-10-01

    This contribution gives a short overview of 100 years aerological observation at Lindenberg Observatory. It describes the geographical location and the climatological characteristics of the observatory. The first part of the paper is a short version of the chronicle: It starts with the opening ceremony on October 16, 1905 and considers the main scientific achievements of the observatory from 1905 to 2005, characterized by its directors Assmann, Hergesell, von Ficker, Marten, Koschmieder, Hearth, Beelitz, Robitzsch, Dubois, Gloede, Leiterer, Schwirner, Neisser and Berger. In the second part of the paper we present the results of a time series of the 100 years period for temperature and relative humidity measured by tethered kite and balloon techniques and radiosondes. For both atmospheric parameters we find a positive trend in the lower and a negative trend in the upper troposphere. Finally we discuss our plans, aims, and the difficulties in creating a homogeneous 100 year time series of significant meteorological parameters in the free atmosphere for detailed scientific investigations. (orig.)

  15. Comparing Stable Water Isotope Variation in Atmospheric Moisture Observed over Coastal Water and Forests

    Science.gov (United States)

    Lai, C. T.; Rambo, J. P.; Welp, L. R.; Bible, K.; Hollinger, D. Y.

    2014-12-01

    Stable oxygen (δ18O) and hydrogen (δD) isotopologues of atmospheric moisture are strongly influenced by large-scale synoptic weather cycles, surface evapotranspiration and boundary layer mixing. Atmospheric water isotope variation has been shown to empirically relate to relative humidity (Rh) of near surface moisture, and to a less degree, air temperature. Continuous δ18O and δD measurements are becoming more available, providing new opportunities to investigate processes that control isotope variability. This study shows the comparison of δ18O and δD measured at a continental location and over coastal waters for 3 seasons (spring to fall, 2014). The surface moisture isotope measurements were made using two LGR spectroscopy water vapor isotope analyzers (Los Gatos Research Inc.), one operated in an old-growth coniferous forest at Wind River field station, WA (45.8205°N, 121.9519°W), and another sampling marine air over seawater at the Scripps Pier in San Diego, CA (32.8654°N, 117.2536°W), USA. Isotope variations were measured at 1Hz and data were reported as hourly averages with an overall accuracy of ±0.1‰ for δ18O, ±0.5‰ for δ2H. Day-to-day variations in δ18O and δD are shown strongly influenced by synoptic weather events at both locations. Boundary layer mixing between surface moisture and the dry air entrained from the free troposphere exerts a midday maximum and a consistent diel pattern in deuterium excess (dx). At the forest site, surface moisture also interacts with leaf water through transpiration during the day and re-equilibration at night. The latter occurs by retro-diffusion of atmospheric H2O molecules into leaf intercellular space, which becomes intensified as Rh increaes after nightfall, and continues until sunrise, to counter-balance the evaporative isotopic enrichment in leaf water on a daily basis. These vegetation effects lead to negative dx values consistently observed at nighttime in this continental location that were not

  16. Evaluation of OMI operational standard NO2 column retrievals using in situ and surface-based NO2 observations

    Directory of Open Access Journals (Sweden)

    L. N. Lamsal

    2014-11-01

    Full Text Available We assess the standard operational nitrogen dioxide (NO2 data product (OMNO2, version 2.1 retrieved from the Ozone Monitoring Instrument (OMI onboard NASA's Aura satellite using a combination of aircraft and surface in~situ measurements as well as ground-based column measurements at several locations and a bottom-up NOx emission inventory over the continental US. Despite considerable sampling differences, NO2 vertical column densities from OMI are modestly correlated (r = 0.3–0.8 with in situ measurements of tropospheric NO2 from aircraft, ground-based observations of NO2 columns from MAX-DOAS and Pandora instruments, in situ surface NO2 measurements from photolytic converter instruments, and a bottom-up NOx emission inventory. Overall, OMI retrievals tend to be lower in urban regions and higher in remote areas, but generally agree with other measurements to within ± 20%. No consistent seasonal bias is evident. Contrasting results between different data sets reveal complexities behind NO2 validation. Since validation data sets are scarce and are limited in space and time, validation of the global product is still limited in scope by spatial and temporal coverage and retrieval conditions. Monthly mean vertical NO2 profile shapes from the Global Modeling Initiative (GMI chemistry-transport model (CTM used in the OMI retrievals are highly consistent with in situ aircraft measurements, but these measured profiles exhibit considerable day-to-day variation, affecting the retrieved daily NO2 columns by up to 40%. This assessment of OMI tropospheric NO2 columns, together with the comparison of OMI-retrieved and model-simulated NO2 columns, could offer diagnostic evaluation of the model.

  17. One year observations of atmospheric reactive gases (O3, CO, NOx, SO2) at Jang Bogo base in Terra Nova Bay, Antarctica

    Science.gov (United States)

    Siek Rhee, Tae; Seo, Sora

    2016-04-01

    Antarctica is a remote area surrounded by the Southern Ocean and far from the influence of human activities, giving us unique opportunity to investigate the background variation of trace gases which are sensitive to the human activities. Korean Antarctic base, Jang Bogo, was established as a unique permanent overwintering base in Terra Nova Bay in February, 2014. One year later, we installed a package of instruments to monitor atmospheric trace gases at the base, which includes long-lived greenhouse gases, CO2, CH4, and N2O, and reactive gases, O3, CO, NOx, and SO2. The atmospheric chemistry observatory, where these scientific instruments were installed, is located ca. 1 km far from the main building and power plant, minimizing the influence of pollution that may come from the operation of the base. Here we focus on the reactive gases measured in-situ at the base; O3 displays a typical seasonal variation with high in winter and low in summer with seasonal amplitude of ~18 ppb, CO was high in September at ~56 ppb, probably implying the invasion of lower latitude air mass with biomass burning, and low in late summer due to photochemical oxidation. NO did not show clear seasonal variation, but SO2 reveals larger values in summer than in winter. We will discuss potential atmospheric processes behind these first observations of reactive gases in Terra Nova Bay, Antarctica.

  18. In situ observations of contrail micro-physics and implications for their radiative impact

    Energy Technology Data Exchange (ETDEWEB)

    Poellot, M R [North Dakota Univ., Grand Forks, ND (United States); Arnott, W P; Hallett, J [Nevada Univ., Reno, NV (United States). Desert Research Inst.

    1998-12-31

    Increasing levels of air traffic have raised concerns about the potential effects of aircraft exhaust on the climate. Current knowledge is expanded by examining in situ data from 21 contrails sampled at altitudes of 9.3 - 12.5 km and temperatures of -47 deg C to -66 deg C. The airborne equipment allowed measurements of particles as small as 2 {mu}m in diameter, which have not previously been reported. The microphysical characteristics of the contrails, which occurred in both clear and cloudy air, are presented and compared with natural cirrus properties. Computations of the wavelength-dependent radiative properties of the sampled particle distributions are also presented and compared with laboratory measurements. Finally, implications of these findings for climatic assessment are discussed. (R.P.) 9 refs.

  19. Atoms in Action: Observing Atomic Motion with Dynamic in situ X-ray Diffraction

    Science.gov (United States)

    Cox, Jordan Michael

    Metal-organic framework (MOF) materials are rich in both structural diversity and application. These materials are comprised of metal atoms or clusters which are connected in a three-dimensional polymer-like network by bridging organic linker molecules. One of the major attractive features in MOFs is their permanent pore space which can potentially be used to adsorb or exchange foreign molecules from/with the surrounding environment. While MOFs are an active area of scientific interest, MOF materials are still relatively new, only 20 years old. As such, there is still much that needs to be understood about these materials before they can be effectively applied to widespread chemical problems like CO2 sequestration or low-pressure hydrogen fuel storage. One of the most important facets of MOF chemistry to understand in order to rationally design MOF materials with tailor-made properties is the relationship between the structural features in a MOF and the chemical and physical properties of that material. By examining in detail the atomic structure of a MOF with known properties under a variety of conditions, scientists can begin to unravel the guiding principles which govern these relationships. X-ray diffraction remains one of the most effective tools for determining the structure of a crystalline material with atomic resolution, and has been applied to the determination of MOF structures for years. Typically these experiments have been carried out using powder X-ray diffraction, but this technique lacks the high-resolution structural information found in single-crystal methods. Some studies have been reported which use specialized devices, sometimes called Environmental Control Cells, to study single crystalline MOFs under non-ambient chemical conditions in situ . However, these in situ studies are performed under static conditions. Even in cases where the ECC provides continued access to the local chemical environment during diffraction data collections, the

  20. In situ observations of contrail micro-physics and implications for their radiative impact

    Energy Technology Data Exchange (ETDEWEB)

    Poellot, M.R. [North Dakota Univ., Grand Forks, ND (United States); Arnott, W.P.; Hallett, J. [Nevada Univ., Reno, NV (United States). Desert Research Inst.

    1997-12-31

    Increasing levels of air traffic have raised concerns about the potential effects of aircraft exhaust on the climate. Current knowledge is expanded by examining in situ data from 21 contrails sampled at altitudes of 9.3 - 12.5 km and temperatures of -47 deg C to -66 deg C. The airborne equipment allowed measurements of particles as small as 2 {mu}m in diameter, which have not previously been reported. The microphysical characteristics of the contrails, which occurred in both clear and cloudy air, are presented and compared with natural cirrus properties. Computations of the wavelength-dependent radiative properties of the sampled particle distributions are also presented and compared with laboratory measurements. Finally, implications of these findings for climatic assessment are discussed. (R.P.) 9 refs.

  1. International Comprehensive Ocean Atmosphere Data Set (ICOADS) And NCEI Global Marine Observations

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — International Comprehensive Ocean Atmosphere Data Set (ICOADS) consists of digital data set DSI-1173, archived at the National Center for Environmental Information...

  2. The possibility to observe the non-standard interaction by the Hyperkamiokande atmospheric neutrino experiment

    Energy Technology Data Exchange (ETDEWEB)

    Fukasawa, Shinya; Yasuda, Osamu, E-mail: yasuda@phys.se.tmu.ac.jp

    2017-01-15

    It was suggested that a tension between the mass-squared differences obtained from the solar neutrino and KamLAND experiments can be solved by introducing the non-standard flavor-dependent interaction in neutrino propagation. In this paper we discuss the possibility to test such a hypothesis by atmospheric neutrino observations at the future Hyper-Kamiokande experiment. Assuming that the mass hierarchy is known, we find that the best-fit value from the solar neutrino and KamLAND data can be tested at more than 8σ, while the one from the global analysis can be examined at 5.0σ (1.4σ) for the normal (inverted) mass hierarchy.

  3. Optical aging observation in suspended core tellurite microstructured fibers under atmospheric conditions

    Science.gov (United States)

    Strutynski, C.; Mouawad, O.; Picot-Clémente, J.; Froidevaux, P.; Désévédavy, F.; Gadret, G.; Jules, J.-C.; Kibler, B.; Smektala, F.

    2017-11-01

    Tellurite glasses are good candidates for the development of broadband supercontinuum (SC) laser sources in the 1-5 μm range. At the moment, beside very few exceptions, SC generation in TeO2-based microstructured optical fibers (MOFs) is limited to 3 μm in the mid-infrared (MIR). We present here an observation of an optical aging occurring in six-hole suspended-core tellurite MOFs. When exposed to atmospheric conditions, such fibers show an alteration of their transmission between 3 and 4 μm. This aging phenomenon leads to the growth of strong additional losses in this wavelengths range over time. Impact of the transmission degradation on spectral broadening is studied through numerical simulations of SC generation.

  4. Two centuries of observed atmospheric variability and change over the North Sea region

    Science.gov (United States)

    Stendel, Martin; van den Besselaar, Else; Hannachi, Abdel; Kent, Elizabeth; Lefebvre, Christiana; Rosenhagen, Gudrun; Schenk, Frederik; van der Schrier, Gerard; Woollings, Tim

    2016-04-01

    In the upcoming North Sea Region Climate Change Assessment (NOSCCA), we present a synthesis of current knowledge about past, present and possible future climate change in the North Sea region. A climate change assessment from published scientific work has been conducted as a kind of regional IPCC report, and a book has been produced that will be published by Springer in 2016. In the framework of the NOSCCA project, we examine past and present studies of variability and changes in atmospheric variables within the North Sea region over the instrumental period, roughly the past 200 years, based on observations and reanalyses. The variables addressed in this presentation are large-scale circulation, pressure and wind, surface air temperature, precipitation and radiative properties (clouds, solar radiation, and sunshine duration). While air temperature over land, not unexpectedly, has increased everywhere in the North Sea region, with strongest trends in spring and in the north of the region, a precipitation increase has been observed in the north and a decrease in the south of the region. This pattern goes along with a north-eastward shift of storm tracks and is in agreement with climate model projections under enhanced greenhouse gas concentrations. For other variables, it is not obvious which part of the observed changes may be due to anthropogenic activities and which is internally forced. It remains also unclear to what extent atmospheric circulation over the North Sea region is influenced by distant factors, in particular Arctic sea-ice decline in recent decades. There are indications of an increase in the number of deep cyclones (but not in the total number of cyclones), while storminess since the late 19th century shows no robust trends. The persistence of circulation types appears to have increased over the last century, and consequently, there is an indication for 'more extreme' extreme events. However, changes in extreme weather events are difficult to assess

  5. Altitude-temporal behaviour of atmospheric ozone, temperature and wind velocity observed at Svalbard

    Czech Academy of Sciences Publication Activity Database

    Petkov, B. H.; Vitale, V.; Svendby, T. M.; Hansen, G. H.; Sobolewski, P. S.; Láska, K.; Elster, Josef; Pavlova, K.; Viola, A.; Mazzola, M.; Lupi, A.; Solomatnikova, A.

    2018-01-01

    Roč. 207, JUL 15 (2018), s. 100-110 ISSN 0169-8095 Institutional support: RVO:67985939 Keywords : Arctic atmosphere * Atmospheric ozone * Ozone depletion Subject RIV: DG - Athmosphere Sciences, Meteorology OBOR OECD: Meteorology and atmospheric sciences Impact factor: 3.778, year: 2016

  6. Combined Multipoint Remote and In Situ Observations of the Asymmetric Evolution of a Fast Solar Coronal Mass Ejection

    OpenAIRE

    Rollett, T.; Moestl, C.; Temmer, M.; Frahm, R. A.; Davies, J. A.; Veronig, A. M.; Vrsnak, B.; Amerstorfer, U. V.; Farrugia, C. J.; Zic, T.; Zhang, T. L.

    2014-01-01

    We present an analysis of the fast coronal mass ejection (CME) of 2012 March 7, which was imaged by both STEREO spacecraft and observed in situ by MESSENGER, Venus Express, Wind and Mars Express. Based on detected arrivals at four different positions in interplanetary space, it was possible to strongly constrain the kinematics and the shape of the ejection. Using the white-light heliospheric imagery from STEREO-A and B, we derived two different kinematical profiles for the CME by applying the...

  7. Implementing an integrated in-situ coaching, observational audit, and story-telling intervention to support safe surgery.

    Science.gov (United States)

    Carthey, Jane; McCormack, Katie; Coombes, Julie; Gilbert, Douglas; Farrar, Daniel

    2016-12-01

    This article describes an intervention that combined in-situ coaching, observational audits and story-telling to educate theatre teams at University College London Hospitals about the Five steps to safer surgery (NPSA 2010). Our philosophy was to educate theatre teams about 'what goes right' (good catches, exemplary leadership etc) as well as 'what could be improved'. Results showed improvements on 'behavioural reliability' metrics, a 68% increase in near miss reporting and a reduction in surgical harm incidents. Copyright the Association for Perioperative Practice.

  8. Urban light pollution - The effect of atmospheric aerosols on astronomical observations at night

    Science.gov (United States)

    Joseph, Joachim H.; Mekler, Yuri; Kaufman, Yoram J.

    1991-01-01

    The transfer of diffuse city light from a localized source through a dust-laden atmosphere with optical depth less than 0.5 has been analyzed in the source-observer plane on the basis of an approximate treatment. The effect on several types of astronomical observation at night has been studied, considering different size distributions and amounts as well as particle shapes of the aerosols. The analysis is made in terms of the signal-to-noise ratios for a given amount of aerosol. The model is applied to conditions at the Wise Astronomical Observatory in the Negev desert, and limiting backgrounds for spectroscopy, photometry, and photography of stars and extended objects have been calculated for a variety of signal-to-noise ratios. Applications to observations with different equipment at various distances from an urban area of any size are possible. Due to the use of signal-to-noise ratios, the conclusions are different for the different experimental techniques used in astronomy.

  9. High temperature in-situ observations of multi-segmented metal nanowires encapsulated within carbon nanotubes by in-situ filling technique.

    Science.gov (United States)

    Hayashi, Yasuhiko; Tokunaga, Tomoharu; Iijima, Toru; Iwata, Takuya; Kalita, Golap; Tanemura, Masaki; Sasaki, Katsuhiro; Kuroda, Kotaro

    2012-08-08

    Multi-segmented one-dimensional metal nanowires were encapsulated within carbon nanotubes (CNTs) through in-situ filling technique during plasma-enhanced chemical vapor deposition process. Transmission electron microscopy (TEM) and environmental TEM were employed to characterize the as-prepared sample at room temperature and high temperature. The selected area electron diffractions revealed that the Pd4Si nanowire and face-centered-cubic Co nanowire on top of the Pd nanowire were encapsulated within the bottom and tip parts of the multiwall CNT, respectively. Although the strain-induced deformation of graphite walls was observed, the solid-state phases of Pd4Si and Co-Pd remain even at above their expected melting temperatures and up to 1,550 ± 50°C. Finally, the encapsulated metals were melted and flowed out from the tip of the CNT after 2 h at the same temperature due to the increase of internal pressure of the CNT.

  10. Observational description of the atmospheric and oceanic boundary layers over the Atlantic Ocean

    Directory of Open Access Journals (Sweden)

    Marcelo Dourado

    2001-01-01

    Full Text Available Time evolution of atmospheric and oceanic boundary layers are described for an upwelling region in the Atlantic Ocean located in Cabo Frio, Brazil (23°00'S, 42°08'W. The observations were obtained during a field campaign carried out by the "Instituto de Estudos do Mar Almirante Paulo Moreira", on board of the oceanographic ship Antares of the Brazilian Navy, between July 7 and 10 of 1992. The analysis shown here was based on 19 simultaneous vertical soundings of atmosphere and ocean, carried out consecutively every 4 hours. The period of observation was characterized by a passage of a cold front that penetrated in Cabo Frio on July 6. During the cold front passage the vertical extension of atmospheric (and oceanic mixed layer varied from 200 m (and 13 m to 1000 m (and 59 m. These changes occurred in the first day of observation and were followed by an increase of 1.2°C in the oceanic mixed layer temperature and by a decrease of 6 K and 6 g/kg in the virtual potential temperature and specific humidity of the atmospheric mixed layer. The short time scale variations in the ocean can be explained in terms of the substitution of cold upwelling water by warm downwelling water regime, as the surface winds shift from pre-frontal NE to post-frontal SSW during the cold front passage in Cabo Frio. The large vertical extent of the atmospheric mixed layer can be explained in terms of an intensification of the thermal mixing induced by the warming of the oceanic upper layers combined with the cooling of the lower atmospheric layers during the cold front passage. An intensification of the mechanical mixing, observed during the cold front passage, may also be contributing to the observed variations in the vertical extent of both layers.A evolução temporal das camadas limites atmosféricas e oceânicas são descritas para a região de ressurgência do Oceano Atlântico localizada em Cabo Frio. As observações foram obtidas durante a campanha de medidas

  11. In situ observation of sol-gel transition of agarose aqueous solution by fluorescence measurement.

    Science.gov (United States)

    Wang, Zheng; Yang, Kun; Li, Haining; Yuan, Chaosheng; Zhu, Xiang; Huang, Haijun; Wang, Yongqiang; Su, Lei; Fang, Yapeng

    2018-06-01

    Sol-gel transition behavior of agarose aqueous solution was investigated by using rheology and fluorescence measurement. On heating, the storage modulus G' decreased gradually, then deviated abruptly at the temperature of about 65°C, and finally decreased slowly again. For fluorescence measurement, the phase transition point kept almost at the temperature of 65°C, which was consistent with that in rheology measurement. Upon compression, it was indicated that the fluorescence lifetime for the probe in the agarose aqueous solution showed a dramatic change in the vicinity of the phase transition point. T vs. P phase diagram of agarose aqueous solution was constructed, which showed that the melting point was an increasing function of pressure. Based on the phase diagram, the agarose gels were prepared by cooling under atmospheric pressure and the pressure of 300MPa, respectively. From the result of the recovered samples studied by optical rheometry, it was found that agarose gel prepared under high pressure had a higher elasticity and lower viscosity index, compared with that under atmospheric pressure. It could be speculated that such kinds of properties might be attributed to the smaller pore size during gelation under high pressure. Copyright © 2018. Published by Elsevier B.V.

  12. Investigation of Arctic mixed-phase clouds by combining airborne remote sensing and in situ observations during VERDI, RACEPAC and ACLOUD

    Science.gov (United States)

    Ehrlich, André; Bierwirth, Eike; Borrmann, Stephan; Crewell, Susanne; Herber, Andreas; Hoor, Peter; Jourdan, Olivier; Krämer, Martina; Lüpkes, Christof; Mertes, Stephan; Neuber, Roland; Petzold, Andreas; Schnaiter, Martin; Schneider, Johannes; Weigel, Ralf; Weinzierl, Bernadett; Wendisch, Manfred

    2016-04-01

    To improve our understanding of Arctic mixed-phase clouds a series of airborne research campaigns has been initiated by a collaboration of German research institutes. Clouds in areas dominated by a close sea-ice cover were observed during the research campaign Vertical distribution of ice in Arctic mixed-phase clouds (VERDI, April/May 2012) and the Radiation-Aerosol-Cloud Experiment in the Arctic Circle (RACEPAC, April/May 2014) which both were based in Inuvik, Canada. The aircraft (Polar 5 & 6, Basler BT-67) operated by the Alfred Wegener Institute for Polar and Marine Research, Germany did cover a wide area above the Canadian Beaufort with in total 149 flight hours (62h during VERDI, 87h during RACEPAC). For May/June 2017 a third campaign ACLOUD (Arctic Clouds - Characterization of Ice, aerosol Particles and Energy fluxes) with base in Svalbard is planned within the Transregional Collaborative Research Centre TR 172 ArctiC Amplification: Climate Relevant Atmospheric and SurfaCe Processes, and Feedback Mechanisms (AC)3 to investigate Arctic clouds in the transition zone between open ocean and sea ice. The aim of all campaigns is to combine remote sensing and in-situ cloud, aerosol and trace gas measurements to investigate interactions between radiation, cloud and aerosol particles. While during VERDI remote sensing and in-situ measurements were performed by one aircraft subsequently, for RACEPAC and ACLOUD two identical aircraft are coordinated at different altitudes to horizontally collocate both remote sensing and in-situ measurements. The campaign showed that in this way radiative and microphysical processes in the clouds can by studied more reliably and remote sensing methods can be validated efficiently. Here we will illustrate the scientific strategy of the projects including the progress in instrumentation. Differences in the general synoptic and sea ice situation and related changes in cloud properties at the different locations and seasons will be

  13. In Situ Observation of Gypsum-Anhydrite Transition at High Pressure and High Temperature

    Institute of Scientific and Technical Information of China (English)

    LIU Chuan-Jiang; ZHENG Hai-Fei

    2012-01-01

    An in-situ Raman spectroscopic study of gypsum-anhydrite transition under a saturated water condition at high pressure and high temperature is performed using a hydrothermal diamond anvil cell (HDAC).The experimental results show that gypsum dissolvs in water at ambient temperature and above 496 MPa.With increasing temperature,the anhydrite (CaSO4) phase precipitates at 250 320℃ in the pressure range of 1.0 1.5 GPa,indicating that under a saturated water condition,both stable conditions of pressure and temperature and high levels of Ca and SO4 ion concentrations in aqueous solution are essential for the formation of anhydrite.A linear relationship between the pressure and temperature for the precipitation of anhydrite is established as P(GPa) =0.0068T - 0.7126 (250℃≤T≤320℃).Anhydrite remained stable during rapid cooling of the sample chamber,showing that the gypsum-anhydrite transition involving both dissolution and precipitation processes is irreversible at high pressure and high temperature.%An in-situ Raman spectroscopic study of gypsum-anhydrite transition under a saturated water condition at high pressure and high temperature is performed using a hydrothermal diamond anvil cell (HDAC). The experimental results show that gypsum dissolvs in water at ambient temperature and above 496 Mpa. With increasing temperature, the anhydrite (CaSO4) phase precipitates at 250-320℃ in the pressure range of 1.0-1.5 Gpa, indicating that under a saturated water condition, both stable conditions of pressure and temperature and high levels of Ca and SO4 ion concentrations in aqueous solution are essential for the formation of anhydrite. A linear relationship between the pressure and temperature for the precipitation of anhydrite is established as P(Gpa) = 0.0068T - 0.7126 (250℃≤T≤320℃). Anhydrite remained stable during rapid cooling of the sample chamber, showing that the gypsum-anhydrite transition involving both dissolution and precipitation processes is

  14. In situ NMR observation of the lithium extraction/insertion from LiCoO2 cathode

    International Nuclear Information System (INIS)

    Shimoda, Keiji; Murakami, Miwa; Takamatsu, Daiko; Arai, Hajime; Uchimoto, Yoshiharu; Ogumi, Zempachi

    2013-01-01

    Abstract: Rechargeable lithium-ion batteries (LIBs) are currently accepted to be one of the most suitable energy storage resources in portable electronic devices because of their high gravimetric and volumetric energy density. To understand the behavior of Li + ions on electrochemical lithium extraction/insertion process, we performed in situ 7 Li nuclear magnetic resonance (NMR) measurements for LiCoO 2 cathode in a plastic cell battery, and the spectral evolutions of the 7 Li NMR signal of Li x CoO 2 (0 ≤ x ≤ 1) were well investigated. Very narrow solid solution region of Li x CoO 2 (∼0.99 ≤ x 2 signal at ∼0 ppm, which is related to the localized nature of the electronic spin of paramagnetic Co 4+ ion formed at the very early delithiation stage. With further decreasing the signal intensity of LiCoO 2 , a Knight-shifted signal corresponding to an electrically conductive Li x CoO 2 phase emerged at x = 0.97, which then monotonously decreased in intensity for x x CoO 2 . These observations acquired in situ fully confirm the earlier studies obtained in ex situ measurements, although the present study offers more quantitative information. Moreover, it was shown that the peak position of the NMR shift for Li x CoO 2 moved as a function of lithium content, which behavior is analogous to the change in its c lattice parameter. Also, the growth and consumption of dendritic/mossy metallic lithium on the counter electrode was clearly observed during the charge/discharge cycles

  15. HONO and Inorganic Fine Particle Composition in Typical Monsoon Region with Intensive Anthropogenic Emission: In-situ Observations and Source Identification.

    Science.gov (United States)

    Xie, Y.; Nie, W.; Ding, A.; Huang, X.

    2015-12-01

    Yangtze River Delta (YRD) is one of the most typical monsoon area with probably the most largest population intensity in the world. With sharply economic development and the large anthropogenic emissions, fine particle pollution have been one of the major air quality problem and may further have impact on the climate system. Though a lot of control policy (sulfur emission have been decreasing from 2007) have been conducted in the region, studies showed the sulfate in fine particles still take major fraction as the nitrate from nitrogen oxides increased significantly. In this study, the role of inorganic chemical compositions in fine particles was investigated with two years in-situ observation. Sulfate and Nitrate contribute to fine particle mass equally in general, but sulfate contributes more during summer and nitrate played more important role in winter. Using lagrangian dispersion backward modeling and source contribution clustering method, the impact of airmass coming from different source region (industrial, dust, biogenic emissions, etc) on fine particle inorganic compositions were discussed. Furthermore, we found two unique cases showing in-situ implications for sulfate formation by nitrogen dioxide oxidation mechanisms. It was showed that the mixing of anthropogenic pollutants with long-range transported mineral dust and biomass burning plume would enhance the sulfate formation by different chemistry mechanisms. This study focus on the complex aspects of fine particle formation in airmasses from different source regions: . It highlights the effect of NOx in enhancing the atmospheric oxidization capacity and indicates a potentially very important impact of increasing NOx on air pollution formation and regional climate change in East Asia.

  16. In-situ observation of Asian pollution transported into the Arctic lowermost stratosphere

    Directory of Open Access Journals (Sweden)

    A. Roiger

    2011-11-01

    Full Text Available On a research flight on 10 July 2008, the German research aircraft Falcon sampled an air mass with unusually high carbon monoxide (CO, peroxyacetyl nitrate (PAN and water vapour (H2O mixing ratios in the Arctic lowermost stratosphere. The air mass was encountered twice at an altitude of 11.3 km, ~800 m above the dynamical tropopause. In-situ measurements of ozone, NO, and NOy indicate that this layer was a mixed air mass containing both air from the troposphere and stratosphere. Backward trajectory and Lagrangian particle dispersion model analysis suggest that the Falcon sampled the top of a polluted air mass originating from the coastal regions of East Asia. The anthropogenic pollution plume experienced strong up-lift in a warm conveyor belt (WCB located over the Russian east-coast. Subsequently the Asian air mass was transported across the North Pole into the sampling area, elevating the local tropopause by up to ~3 km. Mixing with surrounding Arctic stratospheric air most likely took place during the horizontal transport when the tropospheric streamer was stretched into long and narrow filaments. The mechanism illustrated in this study possibly presents an important pathway to transport pollution into the polar tropopause region.

  17. Advanced electron holography techniques for in situ observation of solid-state lithium ion conductors

    Energy Technology Data Exchange (ETDEWEB)

    Hirayama, Tsukasa, E-mail: t-hirayama@jfcc.or.jp [Nanostructures Research Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta-ku, Nagoya, Aichi 456-8587 (Japan); Aizawa, Yuka; Yamamoto, Kazuo; Sato, Takeshi [Nanostructures Research Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta-ku, Nagoya, Aichi 456-8587 (Japan); Murata, Hidekazu [Faculty of Science and Technology, Meijo University, 1-501 Shiogamaguchi, Tempaku-ku, Nagoya, Aichi 468-8502 (Japan); Yoshida, Ryuji; Fisher, Craig A.J. [Nanostructures Research Laboratory, Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta-ku, Nagoya, Aichi 456-8587 (Japan); Kato, Takehisa; Iriyama, Yasutoshi [Department of Materials, Physics and Energy Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya, Aichi 464-8601 (Japan)

    2017-05-15

    Advanced techniques for overcoming problems encountered during in situ electron holography experiments in which a voltage is applied to an ionic conductor are reported. The three major problems encountered were 1) electric-field leakage from the specimen and its effect on phase images, 2) high electron conductivity of damage layers formed by the focused ion beam method, and 3) chemical reaction of the specimen with air. The first problem was overcome by comparing experimental phase distributions with simulated images in which three-dimensional leakage fields were taken into account, the second by removing the damage layers using a low-energy narrow Ar ion beam, and the third by developing an air-tight biasing specimen holder. - Highlights: • Phase distributions derived by comparing experimental and simulated measurements. • Simulations take into account leakage electric fields. • Electric potential distributions inside Li-ion conductors are obtained. • FIB damage layers are removed using a low-energy narrow Ar ion beam. • An air-tight biasing TEM holder for protecting air-sensitive specimens is reported.

  18. Precipitation Characteristics in West and East Africa from Satellite and in Situ Observations

    Science.gov (United States)

    Dezfuli, Amin K.; Ichoku, Charles M.; Mohr, Karen I.; Huffman, George J.

    2017-01-01

    Using in situ data, three precipitation classes are identified for rainy seasons of West and East Africa: weak convective rainfall (WCR), strong convective rainfall (SCR), and mesoscale convective systems (MCSs).Nearly 75% of the total seasonal precipitation is produced by the SCR and MCSs, even though they represent only 8% of the rain events. Rain events in East Africa tend to have a longer duration and lower intensity than in West Africa, reflecting different characteristics of the SCR and MCS events in these two regions. Surface heating seems to be the primary convection trigger for the SCR, particularly in East Africa, whereas the WCR requires a dynamical trigger such as low-level convergence. The data are used to evaluate the performance of the recently launched Integrated Multi-satellite Retrievals for Global Precipitation Measurement (IMERG)project. The IMERG-based precipitation shows significant improvement over its predecessor, the Tropical Rainfall Measuring Mission (TRMM) Multi-satellite Precipitation Analysis (TMPA), particularly in capturing the MCSs, due to its improved temporal resolution.

  19. In situ observation of carbon nanotube layer growth on microbolometers with substrates at ambient temperature

    Science.gov (United States)

    Svatoš, Vojtěch; Gablech, Imrich; Ilic, B. Robert; Pekárek, Jan; Neužil, Pavel

    2018-03-01

    Carbon nanotubes (CNTs) have near unity infrared (IR) absorption efficiency, making them extremely attractive for IR imaging devices. Since CNT growth occurs at elevated temperatures, the integration of CNTs with IR imaging devices is challenging and has not yet been achieved. Here, we show a strategy for implementing CNTs as IR absorbers using differential heating of thermally isolated microbolometer membranes in a C2H2 environment. During the process, CNTs were catalytically grown on the surface of a locally heated membrane, while the substrate was maintained at an ambient temperature. CNT growth was monitored in situ in real time using optical microscopy. During growth, we measured the intensity of light emission and the reflected light from the heated microbolometer. Our measurements of bolometer performance show that the CNT layer on the surface of the microbolometer membrane increases the IR response by a factor of (2.3 ± 0.1) (mean ± one standard deviation of the least-squares fit parameters). This work opens the door to integrating near unity IR absorption, CNT-based, IR absorbers with hybrid complementary metal-oxide-semiconductor focal plane array architectures.

  20. In situ observations of the atomistic mechanisms of Ni catalyzed low temperature graphene growth.

    Science.gov (United States)

    Patera, Laerte L; Africh, Cristina; Weatherup, Robert S; Blume, Raoul; Bhardwaj, Sunil; Castellarin-Cudia, Carla; Knop-Gericke, Axel; Schloegl, Robert; Comelli, Giovanni; Hofmann, Stephan; Cepek, Cinzia

    2013-09-24

    The key atomistic mechanisms of graphene formation on Ni for technologically relevant hydrocarbon exposures below 600 °C are directly revealed via complementary in situ scanning tunneling microscopy and X-ray photoelectron spectroscopy. For clean Ni(111) below 500 °C, two different surface carbide (Ni2C) conversion mechanisms are dominant which both yield epitaxial graphene, whereas above 500 °C, graphene predominantly grows directly on Ni(111) via replacement mechanisms leading to embedded epitaxial and/or rotated graphene domains. Upon cooling, additional carbon structures form exclusively underneath rotated graphene domains. The dominant graphene growth mechanism also critically depends on the near-surface carbon concentration and hence is intimately linked to the full history of the catalyst and all possible sources of contamination. The detailed XPS fingerprinting of these processes allows a direct link to high pressure XPS measurements of a wide range of growth conditions, including polycrystalline Ni catalysts and recipes commonly used in industrial reactors for graphene and carbon nanotube CVD. This enables an unambiguous and consistent interpretation of prior literature and an assessment of how the quality/structure of as-grown carbon nanostructures relates to the growth modes.

  1. In Situ Observation of Gypsum-Anhydrite Transition at High Pressure and High Temperature

    International Nuclear Information System (INIS)

    Liu Chuan-Jiang; Zheng Hai-Fei

    2012-01-01

    An in-situ Raman spectroscopic study of gypsum-anhydrite transition under a saturated water condition at high pressure and high temperature is performed using a hydrothermal diamond anvil cell (HDAC). The experimental results show that gypsum dissolvs in water at ambient temperature and above 496 MPa. With increasing temperature, the anhydrite (CaSO 4 ) phase precipitates at 250–320°C in the pressure range of 1.0–1.5GPa, indicating that under a saturated water condition, both stable conditions of pressure and temperature and high levels of Ca and SO 4 ion concentrations in aqueous solution are essential for the formation of anhydrite. A linear relationship between the pressure and temperature for the precipitation of anhydrite is established as P(GPa) = 0.0068T−0.7126 (250°C≤T≤320°C). Anhydrite remained stable during rapid cooling of the sample chamber, showing that the gypsum-anhydrite transition involving both dissolution and precipitation processes is irreversible at high pressure and high temperature. (geophysics, astronomy, and astrophysics)

  2. What would dense atmospheric observation networks bring to the quantification of city CO2 emissions?

    Science.gov (United States)

    Wu, Lin; Broquet, Grégoire; Ciais, Philippe; Bellassen, Valentin; Vogel, Felix; Chevallier, Frédéric; Xueref-Remy, Irène; Wang, Yilong

    2016-06-01

    Cities currently covering only a very small portion ( directly release to the atmosphere about 44 % of global energy-related CO2, but they are associated with 71-76 % of CO2 emissions from global final energy use. Although many cities have set voluntary climate plans, their CO2 emissions are not evaluated by the monitoring, reporting, and verification (MRV) procedures that play a key role for market- or policy-based mitigation actions. Here we analyze the potential of a monitoring tool that could support the development of such procedures at the city scale. It is based on an atmospheric inversion method that exploits inventory data and continuous atmospheric CO2 concentration measurements from a network of stations within and around cities to estimate city CO2 emissions. This monitoring tool is configured for the quantification of the total and sectoral CO2 emissions in the Paris metropolitan area (˜ 12 million inhabitants and 11.4 TgC emitted in 2010) during the month of January 2011. Its performances are evaluated in terms of uncertainty reduction based on observing system simulation experiments (OSSEs). They are analyzed as a function of the number of sampling sites (measuring at 25 m a.g.l.) and as a function of the network design. The instruments presently used to measure CO2 concentrations at research stations are expensive (typically ˜ EUR 50 k per sensor), which has limited the few current pilot city networks to around 10 sites. Larger theoretical networks are studied here to assess the potential benefit of hypothetical operational lower-cost sensors. The setup of our inversion system is based on a number of diagnostics and assumptions from previous city-scale inversion experiences with real data. We find that, given our assumptions underlying the configuration of the OSSEs, with 10 stations only the uncertainty for the total city CO2 emission during 1 month is significantly reduced by the inversion by ˜ 42 %. It can be further reduced by extending the

  3. Temporal characteristics of atmospheric ammonia and nitrogen dioxide over China based on emission data, satellite observations and atmospheric transport modeling since 1980

    Science.gov (United States)

    Liu, Lei; Zhang, Xiuying; Xu, Wen; Liu, Xuejun; Li, Yi; Lu, Xuehe; Zhang, Yuehan; Zhang, Wuting

    2017-08-01

    China is experiencing intense air pollution caused in large part by anthropogenic emissions of reactive nitrogen (Nr). Atmospheric ammonia (NH3) and nitrogen dioxide (NO2) are the most important precursors for Nr compounds (including N2O5, HNO3, HONO and particulate NO3- and NH4+) in the atmosphere. Understanding the changes in NH3 and NO2 has important implications for the regulation of anthropogenic Nr emissions and is a requirement for assessing the consequence of environmental impacts. We conducted the temporal trend analysis of atmospheric NH3 and NO2 on a national scale since 1980 based on emission data (during 1980-2010), satellite observation (for NH3 since 2008 and for NO2 since 2005) and atmospheric chemistry transport modeling (during 2008-2015).Based on the emission data, during 1980-2010, significant continuous increasing trends in both NH3 and NOx were observed in REAS (Regional Emission inventory in Asia, for NH3 0.17 and for NOx 0.16 kg N ha-1 yr-2) and EDGAR (Emissions Database for Global Atmospheric Research, for NH3 0.24 and for NOx 0.17 kg N ha-1 yr-2) over China. Based on the satellite data and atmospheric chemistry transport model (CTM) MOZART-4 (Model for Ozone and Related chemical Tracers, version 4), the NO2 columns over China increased significantly from 2005 to 2011 and then decreased significantly from 2011 to 2015; the satellite-retrieved NH3 columns from 2008 to 2014 increased at a rate of 2.37 % yr-1. The decrease in NO2 columns since 2011 may result from more stringent strategies taken to control NOx emissions during the 12th Five Year Plan, while no control policy has focused on NH3 emissions. Our findings provided an overall insight into the temporal trends of both NO2 and NH3 since 1980 based on emission data, satellite observations and atmospheric transport modeling. These findings can provide a scientific background for policy makers that are attempting to control atmospheric pollution in China. Moreover, the multiple datasets

  4. Temporal characteristics of atmospheric ammonia and nitrogen dioxide over China based on emission data, satellite observations and atmospheric transport modeling since 1980

    Directory of Open Access Journals (Sweden)

    L. Liu

    2017-08-01

    Full Text Available China is experiencing intense air pollution caused in large part by anthropogenic emissions of reactive nitrogen (Nr. Atmospheric ammonia (NH3 and nitrogen dioxide (NO2 are the most important precursors for Nr compounds (including N2O5, HNO3, HONO and particulate NO3− and NH4+ in the atmosphere. Understanding the changes in NH3 and NO2 has important implications for the regulation of anthropogenic Nr emissions and is a requirement for assessing the consequence of environmental impacts. We conducted the temporal trend analysis of atmospheric NH3 and NO2 on a national scale since 1980 based on emission data (during 1980–2010, satellite observation (for NH3 since 2008 and for NO2 since 2005 and atmospheric chemistry transport modeling (during 2008–2015.Based on the emission data, during 1980–2010, significant continuous increasing trends in both NH3 and NOx were observed in REAS (Regional Emission inventory in Asia, for NH3 0.17 and for NOx 0.16 kg N ha−1 yr−2 and EDGAR (Emissions Database for Global Atmospheric Research, for NH3 0.24 and for NOx 0.17 kg N ha−1 yr−2 over China. Based on the satellite data and atmospheric chemistry transport model (CTM MOZART-4 (Model for Ozone and Related chemical Tracers, version 4, the NO2 columns over China increased significantly from 2005 to 2011 and then decreased significantly from 2011 to 2015; the satellite-retrieved NH3 columns from 2008 to 2014 increased at a rate of 2.37 % yr−1. The decrease in NO2 columns since 2011 may result from more stringent strategies taken to control NOx emissions during the 12th Five Year Plan, while no control policy has focused on NH3 emissions. Our findings provided an overall insight into the temporal trends of both NO2 and NH3 since 1980 based on emission data, satellite observations and atmospheric transport modeling. These findings can provide a scientific background for policy makers that are attempting to control atmospheric

  5. Aircraft Observations of Soil Hydrological Influence on the Atmosphere in Northern India

    Science.gov (United States)

    Taylor, Christopher M.; Barton, Emma J.; Belusic, Danijel; Böing, Steven J.; Hunt, Kieran M. R.; Mitra, Ashis K.; Parker, Douglas J.; Turner, Andrew G.

    2017-04-01

    temperature, humidity and winds in the PBL. These unique observations will provide a powerful tool for understanding the dominant land-atmosphere coupling mechanisms operating on a range of multiple length scales, and which help to shape the Indian monsoon.

  6. Observation of oscillations of atmospheric neutrinos with the IceCube Neutrino Observatory

    International Nuclear Information System (INIS)

    Euler, Sebastian

    2014-01-01

    Neutrino oscillations have become one of the most important research topics in particle physics since their discovery 15 years ago. In the past, the study of neutrino oscillations has been largely the domain of dedicated experiments, but in the last year also the large-volume neutrino telescopes ANTARES and IceCube reported their results on the oscillations of atmospheric muon neutrinos and thus joined the community of experiments studying neutrino oscillations. The precision of their results is not yet competitive, but their sheer size and the consequently enormous statistics give rise to the expectation of a competitive measurement in the future. This thesis describes an analysis that was done on IceCube data taken with the nearly complete detector in the years 2010/2011. IceCube is the world's largest neutrino detector, located at the geographic South Pole, where it uses the Antarctic ice sheet as its detection medium. It detects neutrinos interacting within or close to the instrumented volume by observing the Cherenkov light which is emitted by secondary particles produced in these interactions. An array of optical sensors deployed within a cubic kilometer of ice detects the Cherenkov light and makes it possible to reconstruct the energy and direction of the initial neutrino. Unfortunately, IceCube detects not only neutrinos: the desired neutrino signal is buried in a huge background of atmospheric muons, produced in air showers induced by cosmic rays. This background has to be rejected first. The analysis presented here employs an event selection that is based on the idea of using the outer layers of IceCube as an active veto against the background of atmospheric muons and achieves the necessary background rejection of more than 6 orders of magnitude while keeping a high-statistics sample of several thousands of muon neutrinos. In contrast to the earlier IceCube analysis, which used only the zenith angle, it then performs a 2-dimensional likelihood fit on

  7. Photochemistry in Saturn’s Ring-Shadowed Atmosphere: Photochemistry and Haze Observations

    Science.gov (United States)

    Edgington, Scott G.; Atreya, Sushil K.; Baines, Kevin H.; West, Robert A.; Bjoraker, Gordon L.; Fletcher, Leigh; Momary, Thomas W.; Wilson, Eric; CIRS, ISS, UVIS, VIMS

    2017-10-01

    After 13 years of observing Saturn, Cassini would have ended nearly a half Saturnian year. During this epoch, the ring shadow has moved from covering much of the northern hemisphere to covering a large swath southern hemisphere. The net effect is that the intensity of both ultraviolet and visible sunlight penetrating through the rings to any particular latitude will vary depending on both Saturn’s axis relative to the Sun and the optical thickness of each ring system. In essence, the rings act like semi-transparent venetian blinds. This effect magnifies the effect due to axial tilt alone and acts to turn off photochemistry and haze generation. This effect is seen in both the presence of a bluish Rayleigh-scattering atmosphere in 2004 in the northern hemisphere and color change to blue in the northern hemisphere.Previous work examined the variation of the solar flux as a function of solar inclination, i.e. for each 7.25-year season at Saturn. We report on the impact of the oscillating ring shadow, in addition to variation due to axial tilt, on photolysis and production rates of hydrocarbons and phosphine in Saturn’s stratosphere and upper troposphere. The impact of these production and loss rates on the abundance of long-lived photochemical products leading to haze formation are explored. We assess their impact on a disequilibrium species whose presence in the upper troposphere can be used as a tracer of convective processes in the deeper atmosphere.We will also present our ongoing analysis of Cassini’s CIRS, UVIS, and VIMS datasets that provide an estimate of the evolving haze content. In particular, we will examine how the region inside Saturn’s famous hexagonal jet stream changes over time from a relatively clear atmosphere to a hazy one. We also explore how the hexagon acts like a barrier to transport, isolating Saturn’s north polar region from outside influences of photochemically-generated molecules and haze.The research described in this paper was

  8. MAVEN Observations of Escaping Planetary Ions from the Martian Atmosphere: Mass, Velocity, and Spatial Distributions

    Science.gov (United States)

    Dong, Yaxue; Fang, Xiaohua; Brain, D. A.; McFadden, James P.; Halekas, Jasper; Connerney, Jack

    2015-04-01

    The Mars-solar wind interaction accelerates and transports planetary ions away from the Martian atmosphere through a number of processes, including ‘pick-up’ by electromagnetic fields. The MAVEN spacecraft has made routine observations of escaping planetary ions since its arrival at Mars in September 2014. The SupraThermal And Thermal Ion Composition (STATIC) instrument measures the ion energy, mass, and angular spectra. It has detected energetic planetary ions during most of the spacecraft orbits, which are attributed to the pick-up process. We found significant variations in the escaping ion mass and velocity distributions from the STATIC data, which can be explained by factors such as varying solar wind conditions, contributions of particles from different source locations and different phases during the pick-up process. We also study the spatial distributions of different planetary ion species, which can provide insight into the physics of ion escaping process and enhance our understanding of atmospheric erosion by the solar wind. Our results will be further interpreted within the context of the upstream solar wind conditions measured by the MAVEN Solar Wind Ion Analyzer (SWIA) instrument and the magnetic field environment measured by the Magnetometer (MAG) instrument. Our study shows that the ion spatial distribution in the Mars-Sun-Electric-Field (MSE) coordinate system and the velocity space distribution with respect to the local magnetic field line can be used to distinguish the ions escaping through the polar plume and those through the tail region. The contribution of the polar plume ion escape to the total escape rate will also be discussed.

  9. Onboard measurement system of atmospheric carbon monoxide over the Pacific Ocean by voluntary observing ships

    Science.gov (United States)

    Nara, H.; Tanimoto, H.; Nojiri, Y.; Mukai, H.; Machida, T.; Tohjima, Y.

    2011-07-01

    Long-term monitoring of carbon monoxide (CO) mixing ratios in the atmosphere over the Pacific Ocean is being carried out on commercial cargo vessels participating in the National Institute for Environmental Studies Voluntary Observing Ships program. The program provides a regular platform for measurement of atmospheric CO along four cruising routes: from Japan to Oceania, from Japan to the United States, from Japan to Canada, and from Japan to Southeast Asia. Flask samples are collected during every cruise for subsequent analysis in the laboratory, and in 2005, continuous shipboard CO measurements were initiated on three of the routes. Here, we describe the system we developed for onboard measurement of CO mixing ratios with a commercially available gas filter correlation CO analyzer. The fully automated system measures CO in ambient air, and the detector sensitivity and background signals are calibrated by referencing the measurements to a CO-in-air standard gas (~1 ppmv) and to CO-free air scrubbed with a catalyst, respectively. We examined the artificial production of CO in the high-pressure working gas standards (CO balanced with purified air at ppmv levels) during storage by referencing the measurements to CO standard gases maintained as our primary scale before and after use on the ships. The onboard performance of the continuous CO measurement system was evaluated by comparing its data with data from laboratory analyses of flask samples using gas chromatography with a reduction gas detector. The reasonably good consistency between the two independent measurement methods demonstrated the good performance of both methods over the course of 3-5 yr. The continuous measurement system was more useful than the flask sampling method for regionally polluted air masses, which were often encountered on Southeast Asian cruises.

  10. Onboard measurement system of atmospheric carbon monoxide in the Pacific by voluntary observing ships

    Science.gov (United States)

    Nara, H.; Tanimoto, H.; Nojiri, Y.; Mukai, H.; Machida, T.; Tohjima, Y.

    2011-11-01

    Long-term monitoring of carbon monoxide (CO) mixing ratios in the atmosphere over the Pacific Ocean is being carried out on commercial cargo vessels participating in the National Institute for Environmental Studies Voluntary Observing Ships program. The program provides a regular platform for measurement of atmospheric CO along four cruise routes: from Japan to Oceania, the United States, Canada, and Southeast Asia. Flask samples are collected during every cruise for subsequent analysis in the laboratory, and in 2005, continuous shipboard CO measurements were initiated on three of the routes. Here, we describe the system we developed for onboard measurement of CO mixing ratios with a commercially available gas filter correlation CO analyzer. The fully automated system measures CO in ambient air, and the detector sensitivity and background signals are calibrated by referencing the measurements to a CO-in-air standard gas (~1 ppmv) and to CO-free air scrubbed with a catalyst, respectively. We examined the artificial production of CO in the high-pressure working gas standards during storage by referencing the measurements to CO standard gases maintained as our primary scale before and after use on the ships. The onboard performance of the continuous CO measurement system was evaluated by comparing its data with data from laboratory analyses of flask samples using gas chromatography with a reduction gas detector. The reasonably good consistency between the two independent measurement methods demonstrated the good performance of both methods over the course of 3-5 years. The continuous measurement system was more useful than the flask sampling method for regionally polluted air masses, which were often encountered on Southeast Asian cruises.

  11. Onboard measurement system of atmospheric carbon monoxide in the Pacific by voluntary observing ships

    Directory of Open Access Journals (Sweden)

    H. Nara

    2011-11-01

    Full Text Available Long-term monitoring of carbon monoxide (CO mixing ratios in the atmosphere over the Pacific Ocean is being carried out on commercial cargo vessels participating in the National Institute for Environmental Studies Voluntary Observing Ships program. The program provides a regular platform for measurement of atmospheric CO along four cruise routes: from Japan to Oceania, the United States, Canada, and Southeast Asia. Flask samples are collected during every cruise for subsequent analysis in the laboratory, and in 2005, continuous shipboard CO measurements were initiated on three of the routes. Here, we describe the system we developed for onboard measurement of CO mixing ratios with a commercially available gas filter correlation CO analyzer. The fully automated system measures CO in ambient air, and the detector sensitivity and background signals are calibrated by referencing the measurements to a CO-in-air standard gas (~1 ppmv and to CO-free air scrubbed with a catalyst, respectively. We examined the artificial production of CO in the high-pressure working gas standards during storage by referencing the measurements to CO standard gases maintained as our primary scale before and after use on the ships. The onboard performance of the continuous CO measurement system was evaluated by comparing its data with data from laboratory analyses of flask samples using gas chromatography with a reduction gas detector. The reasonably good consistency between the two independent measurement methods demonstrated the good performance of both methods over the course of 3–5 years. The continuous measurement system was more useful than the flask sampling method for regionally polluted air masses, which were often encountered on Southeast Asian cruises.

  12. Seasonal Variations of Atmospheric CO2 over Fire Affected Regions Based on GOSAT Observations

    Science.gov (United States)

    Shi, Y.; Matsunaga, T.

    2016-12-01

    Abstract: The carbon dioxide (CO2) emissions released from biomass burning significantly affect the temporal variations of atmospheric CO2 concentrations. Based on a long-term (July 2009-June 2015) retrieved datasets by the Greenhouse Gases Observing Satellite (GOSAT), the seasonal cycle and interannual variations of column-averaged volume mixing ratios of atmospheric carbon dioxide (XCO2) in four fire affected continental regions were investigated. The results showed Northern Africa had the largest seasonal variations after removing its regional long-term trend of XCO2 with peak-to-peak amplitude of 6.2 ppm within the year, higher than central South America (2.4 ppm), Southern Africa (3.8 ppm) and Australia (1.7 ppm). The detrended regional XCO2 was found to be positively correlated with the fire CO2 emissions during fire activity period and negatively correlated with vegetation photosynthesis activity with different seasonal variabilities. Northern Africa recorded the largest change of seasonal variations of detrended XCO2 with a total of 12.8 ppm during fire seasons, higher than central South America, Southern Africa and Australia with 5.4 ppm, 6.7 ppm and 2.2 ppm, respectively. During fire episode, the positive detrended XCO2 was noticed during June-November in central South America, December-June in Northern Africa, May-November in Southern Africa. The Pearson correlation coefficients between the variations of detrended XCO2 and fire CO2 emissions from GFED4 (Global Fire Emissions Database v4) achieved best correlations in Southern Africa (R=0.77, p<0.05). Meanwhile, Southern Africa also experienced a significant negative relationship between the variations of detrended XCO2 and vegetation activity (R=-0.84, p<0.05). This study revealed that fire CO2 emissions and vegetation activity contributed greatly to the seasonal variations of GOSAT XCO2 dataset.

  13. 1D Atmosphere Models from Inversion of Fe i 630 nm Observations with an Application to Solar Irradiance Studies

    Energy Technology Data Exchange (ETDEWEB)

    Cristaldi, Alice; Ermolli, Ilaria, E-mail: alice.cristaldi@oaroma.inaf.it [INAF Osservatorio Astronomico di Roma, via Frascati 33, Monte Porzio Catone, I-00078 (Italy)

    2017-06-01

    Present-day semi-empirical models of solar irradiance (SI) variations reconstruct SI changes measured on timescales greater than a day by using spectra computed in one dimensional atmosphere models (1D models), which are representative of various solar surface features. Various recent studies have pointed out, however, that the spectra synthesized in 1D models do not reflect the radiative emission of the inhomogenous atmosphere revealed by high-resolution solar observations. We aimed to derive observation-based atmospheres from such observations and test their accuracy for SI estimates. We analyzed spectropolarimetric data of the Fe i 630 nm line pair in photospheric regions that are representative of the granular quiet-Sun pattern (QS) and of small- and large-scale magnetic features, both bright and dark with respect to the QS. The data were taken on 2011 August 6, with the CRisp Imaging Spectropolarimeter at the Swedish Solar Telescope, under excellent seeing conditions. We derived atmosphere models of the observed regions from data inversion with the SIR code. We studied the sensitivity of results to spatial resolution and temporal evolution, and discuss the obtained atmospheres with respect to several 1D models. The atmospheres derived from our study agree well with most of the 1D models we compare our results with, both qualitatively and quantitatively (within 10%), except for pore regions. Spectral synthesis computations of the atmosphere obtained from the QS observations return an SI between 400 and 2400 nm that agrees, on average, within 2.2% with standard reference measurements, and within −0.14% with the SI computed on the QS atmosphere employed by the most advanced semi-empirical model of SI variations.

  14. Atmospheric gravity wave detection following the 2011 Tohoku earthquakes combining COSMIC occultation and GPS observations

    Science.gov (United States)

    Yan, X.; Tao, Y.; Xia, C.; Qi, Y.; Zuo, X.

    2017-12-01

    Several studies have reported the earthquake-induced atmospheric gravity waves detected by some new technologies such as airglow (Makela et al., 2011), GOCE (Garcia et al., 2013), GRACE (Yang et al., 2014), F3/C radio occultation sounding (Coïsson et al., 2015). In this work, we collected all occultation events on 11 March, and selected four events to analyze at last. The original and filtered podTEC is represented as function of the altitude of the impact parameter and UT of the four events. Then, the travel time diagrams of filtered podTEC derived from the events were analyzed. The occultation signal from one event (marked as No.73) is consistent with the previous results reported by Coïsson. 2015, which is corresponds to the ionospheric signal induced from tsunami gravity wave. What is noticeable, in this work, is that three occultation events of No.403, 77 and 118 revealed a disturbance of atmospheric gravity wave with velocity 300m/s, preceding the tsunami. It would probably be correspond to the gravity waves caused by seismic rupture but not tsunami. In addition, it can be seen that the perturbation height of occultation observation TEC is concentrated at 200-400km, corresponding ionosphere F region. The signals detected above are compared with GPS measurements of TEC from GEONET and IGS. From GPS data, traveling ionospheric disturbances were observed spreading out from the epicenter as a quasi-circular propagation pattern with the time. Exactly, we observed an acoustic wave coupled with Rayleigh wave starting from the epicenter with a speed of 3.0km/s and a superimposed acoustic-gravity wave moving with a speed of 800m/s. The acoustic-gravity wave generated at the epicenter and gradually attenuated 800km away, then it is replaced by a gravity wave coupled with the tsunami that moves with a speed of between 100 and 300m/s. It is necessary to confirm the propagation process of the waves if we attempt to evaluate the use of ionospheric seismology as a

  15. A propagation tool to connect remote-sensing observations with in-situ measurements of heliospheric structures

    Science.gov (United States)

    Rouillard, A. P.; Lavraud, B.; Génot, V.; Bouchemit, M.; Dufourg, N.; Plotnikov, I.; Pinto, R. F.; Sanchez-Diaz, E.; Lavarra, M.; Penou, M.; Jacquey, C.; André, N.; Caussarieu, S.; Toniutti, J.-P.; Popescu, D.; Buchlin, E.; Caminade, S.; Alingery, P.; Davies, J. A.; Odstrcil, D.; Mays, L.

    2017-11-01

    The remoteness of the Sun and the harsh conditions prevailing in the solar corona have so far limited the observational data used in the study of solar physics to remote-sensing observations taken either from the ground or from space. In contrast, the 'solar wind laboratory' is directly measured in situ by a fleet of spacecraft measuring the properties of the plasma and magnetic fields at specific points in space. Since 2007, the solar-terrestrial relations observatory (STEREO) has been providing images of the solar wind that flows between the solar corona and spacecraft making in-situ measurements. This has allowed scientists to directly connect processes imaged near the Sun with the subsequent effects measured in the solar wind. This new capability prompted the development of a series of tools and techniques to track heliospheric structures through space. This article presents one of these tools, a web-based interface called the 'Propagation Tool' that offers an integrated research environment to study the evolution of coronal and solar wind structures, such as Coronal Mass Ejections (CMEs), Corotating Interaction Regions (CIRs) and Solar Energetic Particles (SEPs). These structures can be propagated from the Sun outwards to or alternatively inwards from planets and spacecraft situated in the inner and outer heliosphere. In this paper, we present the global architecture of the tool, discuss some of the assumptions made to simulate the evolution of the structures and show how the tool connects to different databases.

  16. In situ observation of modulated light emission of fiber fuse synchronized with void train over hetero-core splice point.

    Directory of Open Access Journals (Sweden)

    Shin-ichi Todoroki

    Full Text Available BACKGROUND: Fiber fuse is a process of optical fiber destruction under the action of laser radiation, found 20 years ago. Once initiated, opical discharge runs along the fiber core region to the light source and leaves periodic voids whose shape looks like a bullet pointing the direction of laser beam. The relation between damage pattern and propagation mode of optical discharge is still unclear even after the first in situ observation three years ago. METHODOLOGY/PRINCIPAL FINDINGS: Fiber fuse propagation over hetero-core splice point (Corning SMF-28e and HI 1060 was observed in situ. Sequential photographs obtained at intervals of 2.78 micros recorded a periodic emission at the tail of an optical discharge pumped by 1070 nm and 9 W light. The signal stopped when the discharge ran over the splice point. The corresponding damage pattern left in the fiber core region included a segment free of periodicity. CONCLUSIONS: The spatial modulation pattern of the light emission agreed with the void train formed over the hetero-core splice point. Some segments included a bullet-shaped void pointing in the opposite direction to the laser beam propagation although the sequential photographs did not reveal any directional change in the optical discharge propagation.

  17. Solar Radiation Transport in the Cloudy Atmosphere: A 3D Perspective on Observations and Climate Impacts

    Science.gov (United States)

    Davis, Anthony B.; Marshak, Alexander

    2010-01-01

    The interplay of sunlight with clouds is a ubiquitous and often pleasant visual experience, but it conjures up major challenges for weather, climate, environmental science and beyond. Those engaged in the characterization of clouds (and the clear air nearby) by remote sensing methods are even more confronted. The problem comes, on the one hand, from the spatial complexity of real clouds and, on the other hand, from the dominance of multiple scattering in the radiation transport. The former ingredient contrasts sharply with the still popular representation of clouds as homogeneous plane-parallel slabs for the purposes of radiative transfer computations. In typical cloud scenes the opposite asymptotic transport regimes of diffusion and ballistic propagation coexist. We survey the three-dimensional (3D) atmospheric radiative transfer literature over the past 50 years and identify three concurrent and intertwining thrusts: first, how to assess the damage (bias) caused by 3D effects in the operational 1D radiative transfer models? Second, how to mitigate this damage? Finally, can we exploit 3D radiative transfer phenomena to innovate observation methods and technologies? We quickly realize that the smallest scale resolved computationally or observationally may be artificial but is nonetheless a key quantity that separates the 3D radiative transfer solutions into two broad and complementary classes: stochastic and deterministic. Both approaches draw on classic and contemporary statistical, mathematical and computational physics.

  18. HIFI observations of water in the atmosphere of comet C/2008 Q3 (Garradd)

    Science.gov (United States)

    Hartogh, P.; Crovisier, J.; de Val-Borro, M.; Bockelée-Morvan, D.; Biver, N.; Lis, D. C.; Moreno, R.; Jarchow, C.; Rengel, M.; Emprechtinger, M.; Szutowicz, S.; Banaszkiewicz, M.; Bensch, F.; Blecka, M. I.; Cavalié, T.; Encrenaz, T.; Jehin, E.; Küppers, M.; Lara, L.-M.; Lellouch, E.; Swinyard, B. M.; Vandenbussche, B.; Bergin, E. A.; Blake, G. A.; Blommaert, J. A. D. L.; Cernicharo, J.; Decin, L.; Encrenaz, P.; de Graauw, T.; Hutsemekers, D.; Kidger, M.; Manfroid, J.; Medvedev, A. S.; Naylor, D. A.; Schieder, R.; Thomas, N.; Waelkens, C.; Roelfsema, P. R.; Dieleman, P.; Güsten, R.; Klein, T.; Kasemann, C.; Caris, M.; Olberg, M.; Benz, A. O.

    2010-07-01

    High-resolution far-infrared and sub-millimetre spectroscopy of water lines is an important tool to understand the physical and chemical properties of cometary atmospheres. We present observations of several rotational ortho- and para-water transitions in comet C/2008 Q3 (Garradd) performed with HIFI on Herschel. These observations have provided the first detection of the 212-101 (1669 GHz) ortho and 111-000 (1113 GHz) para transitions of water in a cometary spectrum. In addition, the ground-state transition 110-101 at 557 GHz is detected and mapped. By detecting several water lines quasi-simultaneously and mapping their emission we can constrain the excitation parameters in the coma. Synthetic line profiles are computed using excitation models which include excitation by collisions, solar infrared radiation, and radiation trapping. We obtain the gas kinetic temperature, constrain the electron density profile, and estimate the coma expansion velocity by analyzing the map and line shapes. We derive water production rates of 1.7-2.8 × 1028 s-1 over the range rh = 1.83-1.85 AU. Herschel is an ESA space observatory with science instruments provided by European-led Principal Investigator consortia and with important participation from NASA.Figure 5 is only available in electronic form at http://www.aanda.org

  19. Zonal asymmetry of daytime 150-km echoes observed by Equatorial Atmosphere Radar in Indonesia

    Directory of Open Access Journals (Sweden)

    T. Yokoyama

    2009-03-01

    Full Text Available Multi-beam observations of the daytime ionospheric E-region irregularities and the so-called 150-km echoes with the 47-MHz Equatorial Atmosphere Radar (EAR in West Sumatra, Indonesia (0.20° S, 100.32° E, 10.36° S dip latitude are presented. 150-km echoes have been frequently observed by the EAR, and their characteristics are basically the same as the equatorial ones, except for an intriguing zonal asymmetry; stronger echoes in lower altitudes in the east directions, and weaker echoes in higher altitudes in the west. The highest occurrence is seen at 5.7° east with respect to the magnetic meridian, and the altitude gradually increases as viewing from the east to west. Arc structures which return backscatter echoes are proposed to explain the asymmetry. While the strength of radar echoes below 105 km is uniform within the wide coverage of azimuthal directions, the upper E-region (105–120 km echoes also show a different type of zonal asymmetry, which should be generated by an essentially different mechanism from the lower E-region and 150-km echoes.

  20. The atmospheric boundary layer in the CSIRO global climate model: simulations versus observations

    Science.gov (United States)

    Garratt, J. R.; Rotstayn, L. D.; Krummel, P. B.

    2002-07-01

    A 5-year simulation of the atmospheric boundary layer in the CSIRO global climate model (GCM) is compared with detailed boundary-layer observations at six locations, two over the ocean and four over land. Field observations, in the form of surface fluxes and vertical profiles of wind, temperature and humidity, are generally available for each hour over periods of one month or more in a single year. GCM simulations are for specific months corresponding to the field observations, for each of five years. At three of the four land sites (two in Australia, one in south-eastern France), modelled rainfall was close to the observed climatological values, but was significantly in deficit at the fourth (Kansas, USA). Observed rainfall during the field expeditions was close to climatology at all four sites. At the Kansas site, modelled screen temperatures (Tsc), diurnal temperature amplitude and sensible heat flux (H) were significantly higher than observed, with modelled evaporation (E) much lower. At the other three land sites, there is excellent correspondence between the diurnal amplitude and phase and absolute values of each variable (Tsc, H, E). Mean monthly vertical profiles for specific times of the day show strong similarities: over land and ocean in vertical shape and absolute values of variables, and in the mixed-layer and nocturnal-inversion depths (over land) and the height of the elevated inversion or height of the cloud layer (over the sea). Of special interest is the presence climatologically of early morning humidity inversions related to dewfall and of nocturnal low-level jets; such features are found in the GCM simulations. The observed day-to-day variability in vertical structure is captured well in the model for most sites, including, over a whole month, the temperature range at all levels in the boundary layer, and the mix of shallow and deep mixed layers. Weaknesses or unrealistic structure include the following, (a) unrealistic model mixed

  1. In Situ Measurements of Sulfur Hexafluoride (SF6) and age of air from NH sources during the Atmospheric Tomography (ATom) global airborne survey

    Science.gov (United States)

    Elkins, J. W.; Moore, F. L.; Hintsa, E. J.; Ray, E. A.; Dutton, G. S.; Nance, J. D.; Hall, B. D.; Dlugokencky, E. J.; Sweeney, C.; Montzka, S. A.; Newman, P. A.

    2017-12-01

    Atmospheric SF6 is an excellent tracer of atmospheric transport in the troposphere, because of its long lifetime (850 years), mostly northern hemispheric (NH) emissions (95%), and high atmospheric growth rate ( 4%/yr.). The gas is used in the distribution of electrical power, because it is an excellent insulator. It is primarily released through its use (leaking and refilling) in high voltage power transformers. Two NOAA/GMD airborne, in situ gas chromatographs (GCs), PAN and other Trace Hydrohalocarbons ExpeRiment (PANTHER) and UAS Chromatograph for Atmospheric Trace Species (UCATS), operated on the first two circuits of the Atmospheric Tomography Mission (ATom-1 & ATom-2). Both instruments measure nitrous oxide (N2O) and sulfur hexafluoride (SF6) once every 70 seconds using a very sensitive electron capture detector (ECD). We combined both measurements into one data set for analysis of twice the amount of data, since both instruments are comparable and used the same gas standards. The main purpose of ATom is to study the influence of air quality on climate during the four seasons, where two seasons are completed so far. The altitude-latitude cross sections of SF6 mixing ratios during the ATom-1 (left) shows sources are mostly located in the NH ( 95%). The upper troposphere shows inter-hemispheric mixing. The polar stratosphere shows older air that is mixed with air from the mesospheric sink. Using the procedure described by Waugh et al., (2013) [JGR-Atmos. 10.1002/jgrd.50189] and a recent growth rate of 0.32 ppt yr-1, we have calculated the mean age of each SF6 measurement from its source at ground level in the NH (lat. range of 30-50°N). The contours of age (right) are in agreement with the mean inter-hemispheric exchange time (τNS) of 1.2 yr and higher ages in the polar stratosphere (2.5-3.0 yr).

  2. Extension of SCIATRAN by coupling atmospheric and oceanic radiative transfer: First results of comparisons for in-situ and satellite data

    Science.gov (United States)

    Blum, Mirjam; Rozanov, Vladimir; Bracher, Astrid; Burrows, John P.

    The radiative transfer model SCIATRAN [V. V. Rozanov et al., 2002; A. Rozanov et al., 2005, 2008] has been developed to model atmospheric radiative transfer. This model is mainly applied to improve the analysis of high spectrally resolved satellite data as, for instance, data of the instrument SCIAMACHY (Scanning Imaging Absorption Spectrometer for Atmospheric CHar-tographY) onboard the ENVISAT satellite. Within the present study, SCIATRAN has been extended by taking radiative processes as well as at the atmosphere-water interface as within the water into account, which were caused by water itself and its constituents. Comparisons of this extended version of SCIATRAN for in-situ data and for MERIS satellite information yield first results, which will be shown. It is expected that the new version of SCIATRAN, including the coupling of atmospheric and oceanic radiative transfer, will widen the use of high spectrally resolved data in the form of achieving new findings, such as information about ocean biooptics and biogeochemistry like, for example, biomass of different phytoplankton groups or CDOM fluorescence. In addition, it is awaited that the new version improves the retrieval of atmospheric trace gases above oceanic waters. References: 1. V. V. Rozanov, M. Buchwitz, K.-U. Eichmann, R. de Beek, and J. P. Burrows. Sciatran -a new radiative transfer model for geophysical applications in the 240-2400nm spectral region: the pseudo-spherical version. Adv. in Space Res. 29, 1831-1835 (2002) 2. A. Rozanov, V. V. Rozanov, M. Buchwitz, A. Kokhanovsky, and J. P. Burrows. SCIA-TRAN 2.0 -A new radiative tranfer model for geophysical applications in the 175-2400nm spectral region. Adv. in Space Res. 36, 1015-1019 (2005) 3. A. Rozanov. SCIATRAN 2.X: Radiative transfer model and retrieval software package. URL = http://www.iup.physik.uni-bremen.de/sciatran (2008)

  3. Formation and growth rates of atmospheric nanoparticles: four years of observations at two West Siberian stations

    Science.gov (United States)

    Arshinov, Mikhail Yu.; Belan, Boris D.; Davydov, Denis K.; Kozlov, Artem V.; Arshinova, Victoria

    2015-04-01

    In spite of fact that the first report on the new particle formation (NPF) itself was done by John Aitken more than one century ago (Aitken, 1898), a phenomenon of NPF bursts taken place in the atmosphere was discovered not very long ago. Nevertheless, to date it is known that they may occur quite often in a variety of environments (Kulmala et al., 2004; Hirsikko et al., 2011). Siberia occupies a vast area covered by forests, but the comprehensive data on burst frequency, as well as on formation and growth rates of freshly nucleated particles in this key region are still lacking. Continuous measurements of aerosol size distribution carried out in recent years at two West Siberian stations (TOR-station - 56o28'41"N, 85o03'15"E; Fonovaya Observatory - 56o25'07"N, 84o04'27"E) allowed this gap in data to be filled up. Analysis of the size spectra classified in accordance with criteria proposed by Dal Maso et al. (2005) and Hammed et al. (2007) enabled a conclusion to be drawn that NPF events in Wets Siberia are more often observed during spring (from March to May) and early autumn (secondary frequency peak in September). On average, particle formation bursts took place on 23-28 % of all days. Such a seasonal pattern of the NPF occurrence is very similar to one observed at SMEAR II Station (Hyytiälä, Finland; Dal Maso et al. 2005, 2007). Formation rates (FR) of particles with diameters below 25 nm varied in a wide range from 0.1 to 10 cm-3 s-1. Mean values of FR for the entire period of observations were 1.7 cm-3s-1 (median = 1.13 cm-3 s-1) at TOR-station and 0.88 cm-3 s-1 (median = 0.69 cm-3 s-1) at Fonovaya Observatory. Enhanced values of FR are usually observed from spring to autumn. Mean growth rates of observed at TOR-station and Fonovaya Observatory were 6.5 nm h-1 (median = 5.0 nm h-1) and 8.3 nm h-1 (median = 6.4 nm h-1), respectively. This work was supported by the Branch of Geology, Geophysics and Mining Sciences of RAS (Program No. 5); State contracts of

  4. In-situ observation of strain evolution in CP-Ti during uniaxial tensile loading

    Science.gov (United States)

    Bettles, C. J.; Gibson, M. A.; Stevenson, A. W.; Tomus, D.; Lynch, P. A.

    2010-07-01

    First results are presented for in-situ tensile loading experiments performed on the Powder Diffraction beamline at the Australian Synchrotron facility. For direct measurement of strain evolution, the beamline was fitted with a uniaxial tensile stage and a high-resolution CCD detector. Precise calibration of the experimental diffraction geometry, taking into account slight misalignment of the detector (pitch, roll, yaw), was achieved by simulation of the ring patterns recorded from the standard reference material LaB 6 (660). The material examined was a commercially pure titanium strip, which from prior electron microscopy studies, was found to have an average grain size of ˜20-30 μm. Tensile specimens conformed to ASTM E8, with a gauge length of 25 mm. To probe the bulk material properties all experiments were performed at 20 keV. In these preliminary experiments, measurement of the relative change in the interplanar lattice spacing was used to monitor the elastic response in seven crystallographic orientations during the loading cycle. To overcome problems encountered with grain size and associated discontinuous Debye-Scherrer ring patterns, two strategies were implemented to measure the Bragg peak (2 θB) positions. In cases where the radial integration routine provided inconsistent results for peak determination, a new approach based on determining the averaged sum of 2 θB positions from individual spots making up the ring pattern was utilised. Results obtained for the diffraction elastic modulus were found to be in agreement with predictions based on the single-crystal and Neerfield-Hill crystal coupling models.

  5. In Situ Observations of Snow Metamorphosis Acceleration Induced by Dust and Black Carbon

    Science.gov (United States)

    Schneider, A. M.; Flanner, M.

    2017-12-01

    Previous studies demonstrate the dependence of shortwave infrared (SWIR) reflectance on snow specific surface area (SSA) and others examine the direct darkening effect dust and black carbon (BC) deposition has on snow and ice-covered surfaces. The extent to which these light absorbing aerosols (LAAs) accelerate snow metamorphosis, however, is challenging to assess in situ as measurement techniques easily disturb snowpack. Here, we use two Near-Infrared Emitting Reflectance Domes (NERDs) to measure 1300 and 1550nm bidirectional reflectance factors (BRFs) of natural snow and experimental plots with added dust and BC. We obtain NERD measurements and subsequently collect and transport snow samples to the nearby U.S. Army Corps of Engineers' Cold Regions Research and Engineering Lab for micro computed tomography (micro-CT) analysis. Snow 1300 (1550) nm BRFs evolve from 0.6 (0.15) in fresh snow to 0.2 (0.03) after metamorphosis. Hourly-scale time evolving snow surface BRFs and SSA estimates from micro-CT reveal more rapid SWIR darkening and snow metamorphosis in contaminated versus natural plots. Cloudiness and high wind speeds can completely obscure these results if LAAs mobilize before absorbing enough radiant energy. These findings verify experimentally that dust and BC deposition can accelerate snow metamorphosis and enhance snow albedo feedback in sunny, calm weather conditions. Although quantifying the enhancement of snow albedo feedback induced by LAAs requires further surface temperature, solar irradiance, and impurity concentration measurements, this study provides experimental verification of positive feedback occurring where dust and BC accelerate snow metamorphosis.

  6. Chandra Observations of Pluto's Escaping Atmosphere in Support of the New Horizons Mission

    Science.gov (United States)

    McNutt, Ralph, Jr.

    2013-09-01

    Current models of Pluto's extended N2+CH4 atmosphere are still very uncertain, causing numerous difficulties in optimizing the New Horizons fast flyby operations plan for the dwarf planet. Applying knowledge gained from studying cometary X-ray emission, Chandra ACIS-S photometric imaging of X-rays produced by CXE between the solar wind and Pluto's atmosphere will address both the run of atmospheric density and the interaction of the solar wind with the extended Plutonian atmosphere. Determining the atmosphere's extent and amount of free molecular escape will aid the atmospheric sounding measurements of the NH ALICE instrument, while determining the x-ray luminosity will help the NH PEPSI instrument characterize the solar wind particle environment.

  7. In-situ observation of intergranular stress corrosion cracking in AA2024-T3 under constant load conditions

    International Nuclear Information System (INIS)

    Liu Xiaodong; Frankel, G.S.; Zoofan, B.; Rokhlin, S.I.

    2007-01-01

    A specially designed setup was used to apply a constant load to a thin sheet sample of AA2024-T3 and, using microfocal X-ray radiography, to observe in situ the resulting intergranular stress corrosion cracking (IGSCC) from the exposed edge of the sample. The growth of and competition between multiple IGSCC sites was monitored. In many experiments twin cracks initiated close to each other. Furthermore, the deepest crack at the beginning of every experiment was found to slow or stop growing, and was then surpassed by another crack that eventually penetrated through the sample. These observations cannot be explained by the theory of fracture mechanics in inert environments. The possible mechanisms underlying the competition between cracks are discussed

  8. Timing Sunsets with Smartphones: Proof of Concept for a Citizen Science Project that Quantifies the Atmosphere and Supports Astronomical Observations

    Science.gov (United States)

    Wilson, Teresa; Kantamneni, A.; Bartlett, J. L.; Nemiroff, R. J.

    2014-01-01

    Current models that predict the times of sunrise and sunset are only accurate, typically, to a few minutes. Variations in atmospheric refraction contribute to the differences between computed and observed times. At high latitudes, slight changes in refraction can cause the Sun to remain continuously above the horizon instead of appearing to set. A substantial collection of observations would help constrain atmospheric models, which should, in turn, complement astronomical observations through improved understanding of air stability, refraction, and transparency. We report on a small project recording data from a few smartphones as a proof of concept for a possible larger scale citizen science effort.

  9. Land and Atmosphere Near-Real-Time Capability for Earth Observing System

    Science.gov (United States)

    Murphy, Kevin J.

    2011-01-01

    The past decade has seen a rapid increase in availability and usage of near-real-time data from satellite sensors. The EOSDIS (Earth Observing System Data and Information System) was not originally designed to provide data with sufficiently low latency to satisfy the requirements for near-real-time users. The EOS (Earth Observing System) instruments aboard the Terra, Aqua and Aura satellites make global measurements daily, which are processed into higher-level 'standard' products within 8-40 hours of observation and then made available to users, primarily earth science researchers. However, applications users, operational agencies, and even researchers desire EOS products in near-real-time to support research and applications, including numerical weather and climate prediction and forecasting, monitoring of natural hazards, ecological/invasive species, agriculture, air quality, disaster relief and homeland security. These users often need data much sooner than routine science processing allows, usually within 3 hours, and are willing to trade science product quality for timely access. While Direct Broadcast provides more timely access to data, it does not provide global coverage. In 2002, a joint initiative between NASA (National Aeronautics and Space Administration), NOAA (National Oceanic and Atmospheric Administration), and the DOD (Department of Defense) was undertaken to provide data from EOS instruments in near-real-time. The NRTPE (Near Real Time Processing Effort) provided products within 3 hours of observation on a best-effort basis. As the popularity of these near-real-time products and applications grew, multiple near-real-time systems began to spring up such as the Rapid Response System. In recognizing the dependence of customers on this data and the need for highly reliable and timely data access, NASA's Earth Science Division sponsored the Earth Science Data and Information System Project (ESDIS)-led development of a new near-real-time system called

  10. Significant Atmospheric Boundary Layer Change Observed above an Agulhas Current Warm Cored Eddy

    Directory of Open Access Journals (Sweden)

    C. Messager

    2016-01-01

    Full Text Available The air-sea impact of a warm cored eddy ejected from the Agulhas Retroflection region south of Africa was assessed through both ocean and atmospheric profiling measurements during the austral summer. The presence of the eddy causes dramatic atmospheric boundary layer deepening, exceeding what was measured previously over such a feature in the region. This deepening seems mainly due to the turbulent heat flux anomaly above the warm eddy inducing extensive deep and persistent changes in the atmospheric boundary layer thermodynamics. The loss of heat by turbulent processes suggests that this kind of oceanic feature is an important and persistent source of heat for the atmosphere.

  11. Drift velocities of 150-km Field-Aligned Irregularities observed by the Equatorial Atmosphere Radar

    Directory of Open Access Journals (Sweden)

    Yuichi Otsuka

    2013-11-01

    Full Text Available Between 130 and 170 km altitude in the daytime ionosphere, the so-called 150-km field-aligned irregularities (FAIs have been observed since the 1960s at equatorial regions with several very high frequency (VHF radars. We report statistical results of 150-km FAI drift velocities on a plane perpendicular to the geomagnetic field, acquired by analyzing the Doppler velocities of 150-km FAIs observed with the Equatorial Atmosphere Radar (EAR at Kototabang, Indonesia during the period from Aug. 2007 to Oct. 2009. We found that the southward/upward perpendicular drift velocity of the 150-km FAIs tends to decrease in the afternoon and that this feature is consistent with that of F-region plasma drift velocities over the magnetic equator. The zonal component of the 150-km FAI drift velocity is westward and decreases with time, whereas the F-region plasma drift velocity observed with the incoherent scatter radar at Jicamarca, Peru, which is westward, reaches a maximum at about noon. The southward/upward and zonal drift velocities of the 150-km FAIs are smaller than that of the F-region plasma drift velocity by approximately 3 m/s and 25 m/s, respectively, on average. The large difference between the 150-km FAI and F-region plasma drift velocities may not arise from a difference in the magnetic latitudes at which their electric fields are generated. Electric fields generated at the altitude at which the 150-km FAIs occur may not be negligible.

  12. Winter precipitation characteristics in western US related to atmospheric river landfalls: observations and model evaluations

    Science.gov (United States)

    Kim, J.; Guan, B.; Waliser, D. E.; Ferraro, R. D.; Case, J. L.; Iguchi, T.; Kemp, E.; Putman, W.; Wang, W.; Wu, D.; Tian, B.

    2018-01-01

    Winter precipitation (PR) characteristics in western United States (WUS) related to atmospheric river (AR) landfalls are examined using the observation-based PRISM data. The observed AR-related precipitation characteristics are in turn used to evaluate model precipitation data from the NASA MERRA2 reanalysis and from seven dynamical downscaling simulations driven by the MERRA2. Multiple metrics including mean bias, Taylor diagram, and two skill scores are used to measure model performance for three climatological sub-regions in WUS, Pacific Northwest (PNW), Pacific Southwest (PSW) and Great Basin (GB). All model data well represent the winter-mean PR with spatial patte