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Sample records for singular mixing matrix

  1. Minimal solution for inconsistent singular fuzzy matrix equations

    Directory of Open Access Journals (Sweden)

    M. Nikuie

    2013-10-01

    Full Text Available The fuzzy matrix equations $Ailde{X}=ilde{Y}$ is called a singular fuzzy matrix equations while the coefficients matrix of its equivalent crisp matrix equations be a singular matrix. The singular fuzzy matrix equations are divided into two parts: consistent singular matrix equations and inconsistent fuzzy matrix equations. In this paper, the inconsistent singular fuzzy matrix equations is studied and the effect of generalized inverses in finding minimal solution of an inconsistent singular fuzzy matrix equations are investigated.

  2. A Note on Inclusion Intervals of Matrix Singular Values

    OpenAIRE

    Cui, Shu-Yu; Tian, Gui-Xian

    2012-01-01

    We establish an inclusion relation between two known inclusion intervals of matrix singular values in some special case. In addition, based on the use of positive scale vectors, a known inclusion interval of matrix singular values is also improved.

  3. A Note on Inclusion Intervals of Matrix Singular Values

    Directory of Open Access Journals (Sweden)

    Shu-Yu Cui

    2012-01-01

    Full Text Available We establish an inclusion relation between two known inclusion intervals of matrix singular values in some special case. In addition, based on the use of positive scale vectors, a known inclusion interval of matrix singular values is also improved.

  4. Statistical analysis of effective singular values in matrix rank determination

    Science.gov (United States)

    Konstantinides, Konstantinos; Yao, Kung

    1988-01-01

    A major problem in using SVD (singular-value decomposition) as a tool in determining the effective rank of a perturbed matrix is that of distinguishing between significantly small and significantly large singular values to the end, conference regions are derived for the perturbed singular values of matrices with noisy observation data. The analysis is based on the theories of perturbations of singular values and statistical significance test. Threshold bounds for perturbation due to finite-precision and i.i.d. random models are evaluated. In random models, the threshold bounds depend on the dimension of the matrix, the noisy variance, and predefined statistical level of significance. Results applied to the problem of determining the effective order of a linear autoregressive system from the approximate rank of a sample autocorrelation matrix are considered. Various numerical examples illustrating the usefulness of these bounds and comparisons to other previously known approaches are given.

  5. Analysis of the essential spectrum of singular matrix differential operators

    Czech Academy of Sciences Publication Activity Database

    Ibrogimov, O. O.; Siegl, Petr; Tretter, C.

    2016-01-01

    Roč. 260, č. 4 (2016), s. 3881-3926 ISSN 0022-0396 Institutional support: RVO:61389005 Keywords : essential spectrum * system of singular differential equations * operator matrix * Schur complement * magnetohydrodynamics * Stellar equilibrium model Subject RIV: BE - Theoretical Physics Impact factor: 1.988, year: 2016

  6. S-matrix singularities and CFT correlation functions

    Science.gov (United States)

    Cardona, Carlos; Huang, Yu-tin

    2017-08-01

    In this note, we explore the correspondence between four-dimensional flat space S-matrix and two-dimensional CFT proposed by Pasterski et al. We demonstrate that the factorisation singularities of an n-point cubic diagram reproduces the AdS Witten diagrams if mass conservation is imposed at each vertex. Such configuration arises naturally if we consider the 4-dimensional S-matrix as a compactified massless 5-dimensional theory. This identification allows us to rewrite the massless S-matrix in the CHY formulation, where the factorisation singularities are re-interpreted as factorisation limits of a Riemann sphere. In this light, the map is recast into a form of 2 d/2 d correspondence.

  7. Light-like big bang singularities in string and matrix theories

    International Nuclear Information System (INIS)

    Craps, Ben; Evnin, Oleg

    2011-01-01

    Important open questions in cosmology require a better understanding of the big bang singularity. In string and matrix theories, light-like analogues of cosmological singularities (singular plane wave backgrounds) turn out to be particularly tractable. We give a status report on the current understanding of such light-like big bang models, presenting both solved and open problems.

  8. The physical meaning of scattering matrix singularities in coupled-channel formalisms

    Energy Technology Data Exchange (ETDEWEB)

    S. Capstick; A. Svarc; L. Tiator; J. Gegelia; M.M. Giannini; E. Santopinto; C. Hanhart; S. Scherer; T.-S.H. Lee; T. Sato; N. Suzuki

    2007-09-04

    The physical meaning of bare and dressed scattering matrix singularities has been investigated. Special attention has been attributed to the role of well known invariance of scattering matrix with respect to the field transformation of the effective Lagrangian. Examples of evaluating bare and dressed quantities in various models are given.

  9. Construction Method of Regularization by Singular Value Decomposition of Design Matrix

    Directory of Open Access Journals (Sweden)

    LIN Dongfang

    2016-08-01

    Full Text Available Tikhonov regularization introduces regularization parameter and stable functional to improve the ill-condition. When the stable functional expressed as two-norm constraint, the regularization method is the same as ridge estimation. The analysis of the variance and bias of the ridge estimation shows that ridge estimation improved the ill-condition but introduced more bias. The estimation reliability is lowered. We get that correct the larger singular values cannot decrease the variance effectively but introduced more bias, correcting the smaller singular values can decrease the variance effectively. We choose the eigenvectors of the smaller singular values to construct the regularization matrix. It can adjust the correction of the singular values, decrease the variance and biases and finally get a more reliable estimation.

  10. Maximal Cohen-Macaulay modules over non-isolated surface singularities and matrix problems

    CERN Document Server

    Burban, Igor

    2017-01-01

    In this article the authors develop a new method to deal with maximal Cohen-Macaulay modules over non-isolated surface singularities. In particular, they give a negative answer on an old question of Schreyer about surface singularities with only countably many indecomposable maximal Cohen-Macaulay modules. Next, the authors prove that the degenerate cusp singularities have tame Cohen-Macaulay representation type. The authors' approach is illustrated on the case of \\mathbb{k} x,y,z/(xyz) as well as several other rings. This study of maximal Cohen-Macaulay modules over non-isolated singularities leads to a new class of problems of linear algebra, which the authors call representations of decorated bunches of chains. They prove that these matrix problems have tame representation type and describe the underlying canonical forms.

  11. Geodetic networks of processing by singular decomposition of the configuration matrix

    Directory of Open Access Journals (Sweden)

    Weiss Gabriel

    1996-12-01

    Full Text Available The paper present a solution of the Gauss-Markov Model for processing geodetic networks with constraints using singular decomposition of the network’s design matrix A. The homogenisation and dehomogenisation of the model needed for this purpose is introduced too. Outputs of the solution are presented by the necessary matrices and upon advantages of this way are discoursed.

  12. Local bulk S-matrix elements and conformal field theory singularities

    CERN Document Server

    Gary, Michael; Penedones, Joao

    2009-01-01

    We give a procedure for deriving certain bulk S-matrix elements from corresponding boundary correlators. These are computed in the plane wave limit, via an explicit construction of certain boundary sources that give bulk wavepackets. A critical role is played by a specific singular behavior of the lorentzian boundary correlators. It is shown in examples how correlators derived from the bulk supergravity exhibit the appropriate singular structure, and reproduce the corresponding S-matrix elements. This construction thus provides a nontrivial test for whether a given boundary conformal field theory can reproduce bulk physics, and where it does, supplies a prescription to extract bulk S-matrix elements in the plane wave limit.

  13. A Singular Finite Element on the Mixed-Mode Bimaterial Interfacial Cracks

    Science.gov (United States)

    Yao, W. A.; Hu, X. F.

    2012-07-01

    A singular finite element is presented to study the mixed-mode Dugdale-model-based bimaterial interfacial cracks. Firstly, the bimaterial interfacial crack problem is led into the symplectic space, and the symplectic dual equation is obtained and solved analytically. The cohesive stresses of the Dugdale model are treated as special solutions. Subsequently, the analytical solution is employed to develop a novel singular finite element, which depicts accurately the characteristic of displacements and singular stress fields near the crack tip. Finally, combining the singular finite element and conventional finite element method, the length of plastic zone, crack tip opening, and/or sliding displacement can be solved by iteration. Numerical examples are given to illustrate the validity of the present method.

  14. Mixed-Mode Oscillations Due to a Singular Hopf Bifurcation in a Forest Pest Model

    DEFF Research Database (Denmark)

    Brøns, Morten; Desroches, Mathieu; Krupa, Martin

    2015-01-01

    In a forest pest model, young trees are distinguished from old trees. The pest feeds on old trees. The pest grows on a fast scale, the young trees on an intermediate scale, and the old trees on a slow scale. A combination of a singular Hopf bifurcation and a “weak return” mechanism, characterized...... by a small change in one of the variables, determines the features of the mixed-mode oscillations. Period-doubling and saddle-node bifurcations lead to closed families (called isolas) of periodic solutions in a bifurcation corresponding to a singular Hopf bifurcation....

  15. Controllability of switched singular mix-valued logical control networks with constraints

    Science.gov (United States)

    Deng, Lei; Gong, Mengmeng; Zhu, Peiyong

    2018-03-01

    The present paper investigates the controllability problem of switched singular mix-valued logical control networks (SSMLCNs) with constraints on states and controls. First, using the semi-tenser product (STP) of matrices, the SSMLCN is expressed in an algebraic form, based on which a necessary and sufficient condition is given for the uniqueness of solution of SSMLCNs. Second, a necessary and sufficient criteria is derived for the controllability of constrained SSMLCNs, by converting a constrained SSMLCN into a parallel constrained switched mix-valued logical control network. Third, an algorithm is presented to design a proper switching sequence and a control scheme which force a state to a reachable state. Finally, a numerical example is given to demonstrate the efficiency of the results obtained in this paper.

  16. Application of matrix singular value properties for evaluating gain and phase margins of multiloop systems. [stability margins for wing flutter suppression and drone lateral attitude control

    Science.gov (United States)

    Mukhopadhyay, V.; Newsom, J. R.

    1982-01-01

    A stability margin evaluation method in terms of simultaneous gain and phase changes in all loops of a multiloop system is presented. A universal gain-phase margin evaluation diagram is constructed by generalizing an existing method using matrix singular value properties. Using this diagram and computing the minimum singular value of the system return difference matrix over the operating frequency range, regions of guaranteed stability margins can be obtained. Singular values are computed for a wing flutter suppression and a drone lateral attitude control problem. The numerical results indicate that this method predicts quite conservative stability margins. In the second example if the eigenvalue magnitude is used instead of the singular value, as a measure of nearness to singularity, more realistic stability margins are obtained. However, this relaxed measure generally cannot guarantee global stability.

  17. Large-scale genomic prediction using singular value decomposition of the genotype matrix.

    Science.gov (United States)

    Ødegård, Jørgen; Indahl, Ulf; Strandén, Ismo; Meuwissen, Theo H E

    2018-02-28

    For marker effect models and genomic animal models, computational requirements increase with the number of loci and the number of genotyped individuals, respectively. In the latter case, the inverse genomic relationship matrix (GRM) is typically needed, which is computationally demanding to compute for large datasets. Thus, there is a great need for dimensionality-reduction methods that can analyze massive genomic data. For this purpose, we developed reduced-dimension singular value decomposition (SVD) based models for genomic prediction. Fast SVD is performed by analyzing different chromosomes/genome segments in parallel and/or by restricting SVD to a limited core of genotyped individuals, producing chromosome- or segment-specific principal components (PC). Given a limited effective population size, nearly all the genetic variation can be effectively captured by a limited number of PC. Genomic prediction can then be performed either by PC ridge regression (PCRR) or by genomic animal models using an inverse GRM computed from the chosen PC (PCIG). In the latter case, computation of the inverse GRM will be feasible for any number of genotyped individuals and can be readily produced row- or element-wise. Using simulated data, we show that PCRR and PCIG models, using chromosome-wise SVD of a core sample of individuals, are appropriate for genomic prediction in a larger population, and results in virtually identical predicted breeding values as the original full-dimension genomic model (r = 1.000). Compared with other algorithms (e.g. algorithm for proven and young animals, APY), the (chromosome-wise SVD-based) PCRR and PCIG models were more robust to size of the core sample, giving nearly identical results even down to 500 core individuals. The method was also successfully tested on a large multi-breed dataset. SVD can be used for dimensionality reduction of large genomic datasets. After SVD, genomic prediction using dense genomic data and many genotyped individuals

  18. New Class of Quark Mass Matrix and Calculability of Flavor Mixing Matrix

    OpenAIRE

    Kang, Kyungsik; Kang, Sin Kyu

    1997-01-01

    We discuss a new general class of mass matrix ansatz that respects the fermion mass hierarchy and calculability of the flavor mixing matrix. This is a generalization and justification of the various specific forms of the mass matrix by successive breaking of the maximal permutation symmetry. By confronting the experimental data, a large class of the mass matrices are shown to survive, while certain specific cases are phenomenologically ruled out. Also the CP-violation turns out to be maximal,...

  19. On the matrix singularity problem in the variational Gaussian wave packet method

    Energy Technology Data Exchange (ETDEWEB)

    Fabcic, Tomaz; Main, Joerg; Wunner, Guenter [1. Institut fuer Theoretische Physik, Universitaet Stuttgart, 70550 Stuttgart (Germany)

    2007-07-01

    Variational solutions of the time-dependent Schroedinger equation are often based on Gaussian wave packets (GWP) as trial functions. The equations of motion for the time-dependent Gaussian parameters become ill-conditioned from time to time during the propagation, and this problem increases with the number of propagated GWP, leading to extremely small step sizes of the integration routines. On the other hand a sufficiently large number of GWP is necessary to obtain accurate results. The instabilities of the equations of motion are due to a temporary overcrowding of the set of GWP, making the set of linear equations that has to be solved after each time step of integration nearly singular. We present a novel method to overcome these numerical problems by subjecting the GWP to adequate inequality constraints, rendering the integration process orders of magnitude faster. The power of the method is demonstrated for a two dimensional nonintegrable model potential.

  20. Mixing and Phase Separation in Liquid Crystal/matrix Systems

    Science.gov (United States)

    Smith, George W.

    We review mixing and phase separation (demixing) in mixtures of low molecular weight liquid crystals (LCs) and organic matrices, with emphasis on aspects relevant to the formation of polymer-dispersed liquid crystal films. These films, which contain a myriad of micron-sized LC droplets, are of interest because of their electro-optic properties. Film formation is simple: A liquid crystal and a liquid polymer precursor are initially mixed to form a single phase. Subsequently the polymer is hardened, and LC microdroplets phase-separate from the matrix. Although matrix hardening can be achieved in several ways, this review focuses on curing, during which cross-linking reactions lead to an increased matrix molecular weight. Topics discussed include: phase behavior of the binary system before, during, and after cure and LC/matrix solubilities. The Flory-Huggins model for phase separation (as modified by several workers) has provided a theoretical basis for the studies. Principal experimental tools have been calorimetry and light scattering. Uncured LC/matrix binaries possess phase diagrams with an upper critical solution temperature. Such systems, when heated through the mixing temperature, exhibit a decrease in specific heat, the (negative) excess specific heat of mixing, °Cmix. A plot of °Cmix vs. LC concentration exhibits a minimum, from which we can estimate LC and uncured-matrix solubilities. Matrix cure plays a major role in the phase separation process: In partially-cured samples, °Cmix transitions persist until cure is nearly complete, at which time a fraction of the LC is permanently phase-separated, with the rest remaining dissolved in the matrix. The kinetics of phase separation can be determined by calorimetry or light scattering. Cure rates have been shown to control LC microdroplet size, with fast cures leading to small droplets. Calorimetry of the fully cured system also allows us to determine the solubility of liquid crystal in the polymer matrix, as

  1. Carbon Nano tubes Based Mixed Matrix Membrane for Gas Separation

    International Nuclear Information System (INIS)

    Sanip, S.M.; Ismail, A.F.; Goh, P.S.; Norrdin, M.N.A.; Soga, T.; Tanemura, M.; Yasuhiko, H.

    2011-01-01

    Carbon nano tubes based mixed matrix membrane (MMM) was prepared by the solution casting method in which the functionalized multi walled carbon nano tubes (f-MWNTs) were embedded into the polyimide membrane and the resulting membranes were characterized. The effect of nominal MWNTs content between 0.5 and 1.0 wt % on the gas separation properties were looked into. The morphologies of the MMM also indicated that at 0.7 % loading of f- MWNTs, the structures of the MMM showed uniform finger-like structures which have facilitated the fast gas transport through the polymer matrix. It may also be concluded that addition of open ended and shortened MWNTs to the polymer matrix can improve its permeability by increasing diffusivity through the MWNTs smooth cavity. (author)

  2. Engineering the performance of mixed matrix membranes for gas separations

    Science.gov (United States)

    Shu, Shu

    Mixed matrix membranes that comprise domains of organic and inorganic components are investigated in this research. Such materials effectively circumvent the polymeric 'upper bound trade-off curve' and show properties highly attractive for industrial gas separations. Nevertheless, lack of intrinsic compatibility between the organic polymers and inorganic fillers poses the biggest challenge to successful fabrication of mixed matrix membranes. Consequently, control of the nanoscale interface between the sieve and polymer has been the key technical challenge to the implementation of composite membrane materials. The overarching goal of this research was to devise and explore approaches to enhance the performance of mixed matrix membranes by properly tailoring the sieve/polymer interface. In an effort to pursue the aforementioned objective, three approaches were developed and inspected: (i) use of silane coupling agents, (ii) hydrophobizing of sieve surface through alcohol etherification reactions, and (iii) a two-step modification sequence involving the use of a Grignard reagent. A comparison was drawn to evaluate these methodologies and the most effective strategy (Grignard treatment) was selected and further investigated. Successful formulation and characterization of mixed matrix membranes constituting zeolite 4A modified via the Grignard treatment are described in detail. Membranes with impressive improvements in gas separation efficiency and mechanical properties were demonstrated. The basis for the improvements in polymer/sieve compatibility enabled by this specific process were proposed and investigated. A key aspect of the present study was illuminating the detailed chemical mechanisms involved in the Grignard modification. Systematic characterization and carefully designed experiments revealed that the formation of distinctive surface structures is essentially a heterogeneous nucleation process, where Mg(OH)2 crystals grow from the nuclei previously extracted

  3. The Dirichlet problem for a mixed-type equation with strong characteristic degeneracy and a singular coefficient

    Directory of Open Access Journals (Sweden)

    Rimma M. Safina

    2017-04-01

    Full Text Available In this paper we consider the first boundary value problem in a rectangular area for a mixed-type equation of the second kind with a singular coefficient. The criterion of the uniqueness of the problem solution is determined. The uniqueness of the problem solution is proved on the basis of completeness of the system of eigenfunctions of the corresponding one-dimensional spectral problem. The solution of the problem is built explicitly as a sum of Fourier–Bessel. There is the problem of the small denominators that appears when justifying the uniform convergence of the constructed series. In this regard, an evaluation of separateness from zero with a corresponding small denominator asymptotic behavior is found. This estimate has allowed to prove the convergence of the series and its derivatives up to the second order, and the existence theorem for the class of regular solutions of this equation.

  4. Utilization of Ripe Coconut Fiber in Stone Matrix Asphalt Mixes

    Directory of Open Access Journals (Sweden)

    Mahabir Panda

    2013-12-01

    Full Text Available Stone Matrix Asphalt (SMA is a gap graded mix; characterized by higher proportion of coarse aggregate, lower proportion of middle size aggregate and higher proportion of mineral filler. In the present laboratory study, commonly available one conventional VG 30 bitumen and another modified binder, namely CRMB 60 have been used along with a non-conventional natural fiber, namely coconut fiber which is abundantly available in India to provide improved engineering properties and at the same time preventing the usual draining of binder in SMA. The role of a particular binder and fiber with respect to their concentrations in the mix is studied for various engineering properties. Marshall procedure has been followed to determine the optimum binder and optimum fiber contents and also to study the relative advantages of fiber addition in the SMA mixtures. Thereafter, the engineering properties under both static as well as repeated load conditions and moisture susceptibility characteristics have been studied. It is observed that only a marginal 0.3% coconut fiber addition brings significant improvement in the engineering properties of SMA mixes.

  5. Multiplicity within Singularity: Racial Categorization and Recognizing “Mixed Race” in Singapore

    Directory of Open Access Journals (Sweden)

    Zarine L. Rocha

    2011-01-01

    Full Text Available “Race” and racial categories play a significant role in everyday life and state organization in Singapore. While multiplicity and diversity are important characteristics of Singaporean society, Singapore’s multiracial ideology is firmly based on separate, racialized groups, leaving little room for racial projects reflecting more complex identifications. This article explores national narratives of race, culture and belonging as they have developed over time, used as a tool for the state, and re-emerging in discourses of hybridity and “double-barrelled” racial identifications. Multiracialism, as a maintained structural feature of Singaporean society, is both challenged and reinforced by new understandings of hybridity and older conceptions of what it means to be “mixed race” in a (post-colonial society. Tracing the temporal thread of racial categorization through a lens of mixedness, this article places the Singaporean case within emerging work on hybridity and recognition of “mixed race”. It illustrates how state-led understandings of race and “mixed race” describe processes of both continuity and change, with far-reaching practical and ideological impacts.

  6. SYNTHESIS AND CHARACTERIZATION OF POLYIMIDE-ZEOLITE MIXED MATRIX MEMBRANE

    Directory of Open Access Journals (Sweden)

    Budiyono Budiyono

    2012-02-01

    Full Text Available Biogas has become an attractive alternative energy source due to the limitation of energy from fossil. In this study, a new type of mixed matrix membrane (MMM consisting of polyimide-zeolite was synthesized and characterized for biogas purification. The MMM consists of medium concentration of polymer (20% wt polyimide, 80% N-Methyl-2-pyrrolidone (NMP and 25% zeolite 4A in total solid were prepared by a dry/wet phase inversion technique.  The fabricated MMM was characterized using SEM, DSC, TGA and gas permeation. Post treatment coating procedure was also conducted. The research showed that surface coating by 3% silicone rubber toward MMM PI 20% gave the significant effect to improve membrane selectivity. The ideal selectivity for CO2/CH4 separation increased from 0.99 for before coating to 7.9 after coating for PI-Zeolite MMM, respectively. The results suggest that PI-Zeolite MMM with good post treatment procedure will increase the membrane selectivity and permeability with more saver polymer requirement as well as energy saving due to low energy for mixing.

  7. Hybrid and Mixed Matrix Membranes for Separations from Fermentations.

    Science.gov (United States)

    Davey, Christopher John; Leak, David; Patterson, Darrell Alec

    2016-02-29

    Fermentations provide an alternative to fossil fuels for accessing a number of biofuel and chemical products from a variety of renewable and waste substrates. The recovery of these dilute fermentation products from the broth, however, can be incredibly energy intensive as a distillation process is generally involved and creates a barrier to commercialization. Membrane processes can provide a low energy aid/alternative for recovering these dilute fermentation products and reduce production costs. For these types of separations many current polymeric and inorganic membranes suffer from poor selectivity and high cost respectively. This paper reviews work in the production of novel mixed-matrix membranes (MMMs) for fermentative separations and those applicable to these separations. These membranes combine a trade-off of low-cost and processability of polymer membranes with the high selectivity of inorganic membranes. Work within the fields of nanofiltration, reverse osmosis and pervaporation has been discussed. The review shows that MMMs are currently providing some of the most high-performing membranes for these separations, with three areas for improvement identified: Further characterization and optimization of inorganic phase(s), Greater understanding of the compatibility between the polymer and inorganic phase(s), Improved methods for homogeneously dispersing the inorganic phase.

  8. Hybrid and Mixed Matrix Membranes for Separations from Fermentations

    Directory of Open Access Journals (Sweden)

    Christopher John Davey

    2016-02-01

    Full Text Available Fermentations provide an alternative to fossil fuels for accessing a number of biofuel and chemical products from a variety of renewable and waste substrates. The recovery of these dilute fermentation products from the broth, however, can be incredibly energy intensive as a distillation process is generally involved and creates a barrier to commercialization. Membrane processes can provide a low energy aid/alternative for recovering these dilute fermentation products and reduce production costs. For these types of separations many current polymeric and inorganic membranes suffer from poor selectivity and high cost respectively. This paper reviews work in the production of novel mixed-matrix membranes (MMMs for fermentative separations and those applicable to these separations. These membranes combine a trade-off of low-cost and processability of polymer membranes with the high selectivity of inorganic membranes. Work within the fields of nanofiltration, reverse osmosis and pervaporation has been discussed. The review shows that MMMs are currently providing some of the most high-performing membranes for these separations, with three areas for improvement identified: Further characterization and optimization of inorganic phase(s, Greater understanding of the compatibility between the polymer and inorganic phase(s, Improved methods for homogeneously dispersing the inorganic phase.

  9. Modeling of piezoelectric Langevin transducers by using mixed transfer matrix methods

    International Nuclear Information System (INIS)

    Fu, Bo; Li, Chao; Zhang, Jianming; Huang, Zhenwei; Hemsel, Tobias

    2010-01-01

    In the modeling of piezoelectric Langevin transducers using the usual transfer matrix methods, some simplifications have been adopted. This leads to a reduction in the model quality. A mixed transfer matrix method is employed in the modeling of Langevin transducers, where the pre-stressed bolt is modeled as a separate four-pole element connected to other elements in parallel. Based on the mixed transfer matrix method, the four (six)-pole element description of the piezoelectric Langevin transducer is built up, and the total transfer matrix relation is derived. The resonance frequencies of the transducer are calculated and then measured using an impedance analyzer (HP4192). Experimental results show that the mixed transfer matrix method has better modeling quality than the usual transfer matrix method for the vibration analysis of piezoelectric Langevin transducers.

  10. Highly scalable ZIF-based mixed-matrix hollow fiber membranes for advanced hydrocarbon separations

    KAUST Repository

    Zhang, Chen

    2014-05-29

    ZIF-8/6FDA-DAM, a proven mixed-matrix material that demonstrated remarkably enhanced C3H6/C3H8 selectivity in dense film geometry, was extended to scalable hollow fiber geometry in the current work. We successfully formed dual-layer ZIF-8/6FDA-DAM mixed-matrix hollow fiber membranes with ZIF-8 nanoparticle loading up to 30 wt % using the conventional dry-jet/wet-quench fiber spinning technique. The mixed-matrix hollow fibers showed significantly enhanced C3H6/C3H8 selectivity that was consistent with mixed-matrix dense films. Critical variables controlling successful formation of mixed-matrix hollow fiber membranes with desirable morphology and attractive transport properties were discussed. Furthermore, the effects of coating materials on selectivity recovery of partially defective fibers were investigated. To our best knowledge, this is the first article reporting successful formation of high-loading mixed-matrix hollow fiber membranes with significantly enhanced selectivity for separation of condensable olefin/paraffin mixtures. Therefore, it represents a major step in the research area of advanced mixed-matrix membranes. © 2014 American Institute of Chemical Engineers.

  11. Mixed Matrix Silicone and Fluorosilicone/Zeolite 4A Membranes for Ethanol Dehydration by Pervaporation

    Science.gov (United States)

    The ability of homogeneous and mixed matrix membranes prepared using standard silicone rubber, poly(dimethylsiloxane) (PDMS), and fluorosilicone rubber, poly(trifluoropropylmethylsiloxane) (PTFPMS), to dehydrate ethanol by pervaporation was evaluated. Although PDMS is generally c...

  12. Löslichkeitsselektive Mixed Matrix Membranen zur Gaspermeation:experimentelle Untersuchung und Entwicklung eines Stofftransportmodells

    OpenAIRE

    Kramer, Verena

    2017-01-01

    In this work solubility selective mixed matrix membranes consisting of silicon polymers and activated carbon are investigated for transport and separation properties of n-butane and methane. For mathematical description of the permeation process a new model is developed based on one-dimensional discretisation of the separation layer. This is an innovative approach for modelling of mixed matrix membranes and can also be applied for other systems than the one investigated in this work. For the ...

  13. High pressure gas separation performance of mixed-matrix polymer membranes containing mesoporous FE(BTC)

    NARCIS (Netherlands)

    Shahid, S.; Nijmeijer, Dorothea C.

    2014-01-01

    Mixed-matrix membranes (MMMs), filled with inorganic particles, provide a means to improve the gas separation performance of polymeric membranes. In this work, MMMs containing the mesoporous metal organic framework (MOF) Fe(BTC) in a Matrimid®-PI matrix were characterized in terms of their carbon

  14. A metal ion charged mixed matrix membrane for selective adsorption of hemoglobin

    NARCIS (Netherlands)

    Tetala, K.K.R.; Skrzypek, Katarzyna; Levisson, M.; Stamatialis, Dimitrios

    2013-01-01

    In this work, we developed a mixed matrix membrane by incorporating 20–40 μm size iminodiacetic acid modified immobeads within porous Ethylene vinyl alcohol (EVAL) polymer matrix. The MMM were charged with copper ions for selective adsorption of bovine hemoglobin in presence of bovine serum albumin.

  15. New Class of Quark Mass Matrices and the Flavor Mixing Matrix

    OpenAIRE

    Kang, Kyungsik; Kang, Sin Kyu

    1998-01-01

    We discuss a new general class of mass matrix ansatz that respects the fermion mass hierarchy and calculability of the flavor mixing matrix. This is a generalization of the various specific forms of the mass matrix that is obtained by successive breaking of the maximal permutation symmetry. By confronting the experimental data, a large class of the mass matrices are shown to survive, while certain specific cases are phenomenologically ruled out.

  16. Physical–chemical properties, separation performance, and fouling resistance of mixed-matrix ultrafiltration membranes

    KAUST Repository

    Hoek, Eric M.V.

    2011-12-01

    Herein we report on the formation and characterization of mixed-matrix ultrafiltration (UF) membranes hand-cast by nonsolvent induced phase inversion. We evaluated nanometer-to-micrometer sized inorganic fillers (silver, copper, silica, zeolite, and silver-zeolite) materials with polysulfone (PSf) as the polymeric dispersing matrix. In general, mixed-matrix membranes were rougher, more hydrophilic, and more mechanically robust. Only sub-micron zeolite-PSf mixed-matrix membranes exhibited simultaneous improvements in water permeability and solute selectivity; all other mixed-matrix membranes were more permeable, but less selective due to defects associated with poor polymer-filler binding. Protein and bacterial fouling resistance of mixed-matrix membranes containing silver, zeolite, and silver-zeolite nanoparticles were compared to a low-fouling, poly(acrylonitrile) (PAN) UF membrane. Zeolite and silver containing membranes exhibited better protein fouling resistance (due to higher hydrophilicity), whereas silver and silver-zeolite based membranes produce better bacterial fouling resistance due to antimicrobial properties. Overall, zeolite-PSf and silver exchanged zeolite-PSf membranes offered the best combination of improved permeability, selectivity, and fouling resistance - superior to the commercial PAN membrane. © 2011 Elsevier B.V.

  17. Interval matrices: Regularity generates singularity

    Czech Academy of Sciences Publication Activity Database

    Rohn, Jiří; Shary, S.P.

    2018-01-01

    Roč. 540, 1 March (2018), s. 149-159 ISSN 0024-3795 Institutional support: RVO:67985807 Keywords : interval matrix * regularity * singularity * P-matrix * absolute value equation * diagonally singilarizable matrix Subject RIV: BA - General Mathematics Impact factor: 0.973, year: 2016

  18. All-solid electrodes with mixed conductor matrix

    Science.gov (United States)

    Huggins, Robert A.; Boukamp, Bernard A.

    1984-01-01

    Alkali metal based electrochemical cells offer a great deal of promise for applications in many areas such as electric vehicles and load leveling purposes in stationary power plants. Lithium is an attractive candidate as the electroactive species in such cells since lithium is very electropositive, abundant and light weight. One type of lithium-based cell utilizes a molten salt electrolyte and normally is operated at elevated temperatures. The subject invention provides an electrochemical cell in one embodiment of which lithium is the electroactive species. The cell comprises an electrolyte, a positive electrode, and a negative electrode, either or both of which is an all-solid, composite microstructural electrode containing both a reactant phase and a mixed ionic-electronic conducting phase. The cells of the subject invention exhibit improved kinetic features, current and power densities. Repeated charging and discharging of these cells can be accomplished without appreciable loss of capacity.

  19. FABRICATION AND CHARACTERIZATION OF POLYIMIDE/POLYETHERSULFONE-FUMED SILICA MIXED MATRIX MEMBRANE FOR GAS SEPARATION

    Directory of Open Access Journals (Sweden)

    A. F. Ismail

    2012-01-01

    Full Text Available This study is performed primarily to investigate the feasibility of fumed silica as inorganic material towards gas separation performance of mixed matrix membrane. In this study, polyimide/polyethersulfone (PES-fumed silica mixed matrix membranes were casted using dry/wet technique. The results from the FESEM, DSC and FTIR analysis confirmed that the structure and physical properties of membrane is influenced by inorganic filler. FESEM’s cross-section view indicated good compatibility between polymer and fumed silica for all of range fumed silica used in this study. The gas separation performance of the mixed matrix membranes with fumed silica were relatively higher compared to that of the neat PI/PES membrane. PI/PES-fumed silica 5 wt% yielded significant selectivity enhancement of 7.21 and 40.47 for O2/N2, and CO2/CH4, respectively.

  20. Mixed-linker zeolitic imidazolate framework mixed-matrix membranes for aggressive CO2 separation from natural gas

    KAUST Repository

    Thompson, Joshua A.

    2014-07-01

    Zeolitic imidazolate framework (ZIF) materials are a promising subclass of metal-organic frameworks (MOF) for gas separations. However, due to the deleterious effects of gate-opening phenomena associated with organic linker rotation near the limiting pore apertures of ZIFs, there have been few demonstrations of improved gas separation properties over pure polymer membranes when utilizing ZIF materials in composite membranes for CO2-based gas separations. Here, we report a study of composite ZIF/polymer membranes, containing mixed-linker ZIF materials with ZIF-8 crystal topologies but composed of different organic linker compositions. Characterization of the mixed-linker ZIFs shows that the mixed linker approach offers control over the porosity and pore size distribution of the materials, as determined from nitrogen physisorption and Horváth-Kawazoe analysis. Single gas permeation measurements on mixed-matrix membranes reveal that inclusion of mixed-linker ZIFs yields membranes with better ideal CO2/CH4 selectivity than membranes containing ZIF-8. This improvement is shown to likely occur from enhancement in the diffusion selectivity of the membranes associated with controlling the pore size distribution of the ZIF filler. Mixed-gas permeation experiments show that membranes with mixed-linker ZIFs display an effective plasticization resistance that is not typical of the pure polymeric matrix. Overall, we demonstrate that mixed-linker ZIFs can improve the gas separation properties in composite membranes and may be applicable to aggressive CO2 concentrations in natural gas feeds. © 2013 Elsevier Inc. All rights reserved.

  1. Mixed matrix membranes based on polyamide/montmorillonite for pervaporation of methanol-toluene mixture

    Czech Academy of Sciences Publication Activity Database

    Avagimova, N.; Polotskaya, G.; Saprykina, N.; Toikka, A.; Pientka, Zbyněk

    2013-01-01

    Roč. 48, č. 17 (2013), s. 2513-2523 ISSN 0149-6395 R&D Projects: GA ČR GA104/09/1165 Institutional support: RVO:61389013 Keywords : membranes * pervaporation * mixed matrix Subject RIV: CD - Macromolecular Chemistry Impact factor: 1.200, year: 2013

  2. Theory of quark mixing matrix and invariant functions of mass matrices

    International Nuclear Information System (INIS)

    Jarlskog, C.

    1987-10-01

    The outline of this talk is as follows: The origin of the quark mixing matrix. Super elementary theory of flavour projection operators. Equivalences and invariances. The commutator formalism and CP violation. CP conditions for any number of families. The 'angle' between the quark mass matrices. Application to Fritzsch and Stech matrices. References. (author)

  3. Factors affecting alcohol-water pervaporation performance of hydrophobic zeolite-silicone rubber mixed matrix membranes

    Science.gov (United States)

    Mixed matrix membranes (MMMs) consisting of ZSM-5 zeolite particles dispersed in silicone rubber exhibited ethanol-water pervaporation permselectivities up to 5 times that of silicone rubber alone and 3 times higher than simple vapor-liquid equilibrium (VLE). A number of conditi...

  4. Poisoning of mixed matrix membranes by fermentation components in pervaporation of ethanol

    Science.gov (United States)

    Pervaporation is an alternative to distillation for recovering ethanol produced by fermentation of grains and biomass. Ethanol-selective mixed matrix membranes of the hydrophobic zeolite ZSM-5 in polydimethylsiloxane (PDMS) have superior performance compared to pure PDMS membranes in pervaporation o...

  5. Mixed matrix membranes containing MOF's for ethelyne/ethane separation. Part A: Membrane preparation and characterization

    NARCIS (Netherlands)

    Ploegmakers, J.; Japip, S.; Nijmeijer, Dorothea C.

    2013-01-01

    Mixed matrix membranes (MMMs) containing three different metal organic frameworks (MOFs) (Cu3BTC2, FeBTC and MIL-53 (Al)) as filler in P84 were prepared and characterized in terms of ethylene/ethane separating ability. SEM, TGA and DSC suggest the absence of non-selective voids in the Cu3BTC2 and

  6. Mixed matrix membranes with fast and selective transport pathways for efficient CO2 separation

    Science.gov (United States)

    Hou, Jinpeng; Li, Xueqin; Guo, Ruili; Zhang, Jianshu; Wang, Zhongming

    2018-03-01

    To improve CO2 separation performance, porous carbon nanosheets (PCNs) were used as a filler into a Pebax MH 1657 (Pebax) matrix, fabricating mixed matrix membranes (MMMs). The PCNs exhibited a preferential horizontal orientation within the Pebax matrix because of the extremely large 2D plane and nanoscale thickness of the matrix. Therefore, the micropores of the PCNs provided fast CO2 transport pathways, which led to increased CO2 permeability. The reduced pore size of the PCNs was a consequence of the overlapping of PCNs and the polymer chains penetrating into the pores of the PCNs. The reduction in the pore size of the PCNs improved the CO2/gas selectivity. As a result, the CO2 permeability and CO2/CH4 selectivity of the Pebax membrane with 10 wt% PCNs-loading (Pebax-PCNs-10) were 520 barrer and 51, respectively, for CO2/CH4 mixed-gas. The CO2 permeability and CO2/N2 selectivity of the Pebax-PCNs-10 membrane were 614 barrer and 61, respectively, for CO2/N2 mixed-gas.

  7. Accelerating Correlated Quantum Chemistry Calculations Using Graphical Processing Units and a Mixed Precision Matrix Multiplication Library.

    Science.gov (United States)

    Olivares-Amaya, Roberto; Watson, Mark A; Edgar, Richard G; Vogt, Leslie; Shao, Yihan; Aspuru-Guzik, Alán

    2010-01-12

    Two new tools for the acceleration of computational chemistry codes using graphical processing units (GPUs) are presented. First, we propose a general black-box approach for the efficient GPU acceleration of matrix-matrix multiplications where the matrix size is too large for the whole computation to be held in the GPU's onboard memory. Second, we show how to improve the accuracy of matrix multiplications when using only single-precision GPU devices by proposing a heterogeneous computing model, whereby single- and double-precision operations are evaluated in a mixed fashion on the GPU and central processing unit, respectively. The utility of the library is illustrated for quantum chemistry with application to the acceleration of resolution-of-the-identity second-order Møller-Plesset perturbation theory calculations for molecules, which we were previously unable to treat. In particular, for the 168-atom valinomycin molecule in a cc-pVDZ basis set, we observed speedups of 13.8, 7.8, and 10.1 times for single-, double- and mixed-precision general matrix multiply (SGEMM, DGEMM, and MGEMM), respectively. The corresponding errors in the correlation energy were reduced from -10.0 to -1.2 kcal mol(-1) for SGEMM and MGEMM, respectively, while higher accuracy can be easily achieved with a different choice of cutoff parameter.

  8. Interfacial Design of Mixed Matrix Membranes for Improved Gas Separation Performance.

    Science.gov (United States)

    Wang, Zhenggong; Wang, Dong; Zhang, Shenxiang; Hu, Liang; Jin, Jian

    2016-05-01

    High-performance metal-organic framework (MOF)/polyimide (PI) mixed matrix membranes (MMMs) are fabricated by a facile strategy by designing the MOF/PI matrix interface via poly dopamine coating. The overall separation performance of the designed MMMs surpasses the state-of-the-art 2008 Robeson upper bound for the H2 /CH4 and H2 /N2 gas pairs and approaches the 2008 upper bound for the O2 /N2 gas pair. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  9. Ordered mixed-layer structures in the Mighei carbonaceous chondrite matrix

    Science.gov (United States)

    Mackinnon, I. D. R.

    1982-01-01

    High resolution transmission electron microscopy of the Mighei carbonaceous chondrite matrix has revealed the presence of a new mixed layer structure material. This mixed-layer material consists of an ordered arrangement of serpentine-type (S) and brucite-type (B) layers in the sequence SBBSBB. Electron diffraction and imaging techniques show that the basal periodicity is approximately 17 A. Discrete crystals of SBB-type material are typically curved, of small size (less than 1 micron) and show structural variations similar to the serpentine group minerals. Mixed-layer material also occurs in association with planar serpentine. Characteristics of SBB-type material are not consistent with known terrestrial mixed-layer clay minerals. Evidence for formation by a condensation event or by subsequent alteration of pre-existing material is not yet apparent.

  10. Short-distance matrix elements for $D$-meson mixing for 2+1 lattice QCD

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Chia Cheng [Univ. of Illinois, Champaign, IL (United States)

    2015-01-01

    We study the short-distance hadronic matrix elements for D-meson mixing with partially quenched Nf = 2+1 lattice QCD. We use a large set of the MIMD Lattice Computation Collaboration's gauge configurations with a2 tadpole-improved staggered sea quarks and tadpole-improved Lüscher-Weisz gluons. We use the a2 tadpole-improved action for valence light quarks and the Sheikoleslami-Wohlert action with the Fermilab interpretation for the valence charm quark. Our calculation covers the complete set of five operators needed to constrain new physics models for D-meson mixing. We match our matrix elements to the MS-NDR scheme evaluated at 3 GeV. We report values for the Beneke-Buchalla-Greub-Lenz-Nierste choice of evanescent operators.

  11. Zeolite-imidazolate framework (ZIF-8) membrane synthesis on a mixed-matrix substrate

    KAUST Repository

    Barankova, Eva

    2013-01-01

    A thin, dense, compact and hydrogen selective ZIF-8 membrane was synthesized on a polymer/metal oxide mixed-matrix support by a secondary seeding method. The new concept of incorporating ZnO particles into the support and PDMS coating of the ZIF-8 layer is introduced to improve the preparation of ZIF-polymer composite membranes. © 2013 The Royal Society of Chemistry.

  12. Ultem®/ZIF-8 mixed matrix hollow fiber membranes for CO2/N2 separations

    KAUST Repository

    Dai, Ying

    2012-05-01

    Organic-inorganic hybrid (mixed matrix) membranes can potentially extend the separation performance of traditional polymeric materials while maintaining processing convenience. Although many dense films studies have been reported, there have been few reported cases of these materials being successfully extended to asymmetric hollow fibers. In this work we report the first successful production of mixed matrix asymmetric hollow fiber membranes containing metal-organic-framework (MOF) ZIF-8 fillers. Specifically, we have incorporated ZIF-8 into a polyetherimide (Ultem ® 1000) matrix and produced dual-layer asymmetric hollow fiber membranes via the dry jet-wet quench method. The outer separating layer of these composite fibers contains 13wt% (17vol%) of ZIF-8 filler. These membranes have been tested over a range of temperatures and pressures for a variety of gas pairs. An increase in separation performance for the CO 2/N 2 gas pairs was observed for both pure gas and mixed gas feeds. © 2012 Elsevier B.V.

  13. Carbon dioxide selective mixed matrix composite membrane containing ZIF-7 nano-fillers

    KAUST Repository

    Li, Tao

    2013-01-01

    Mixed matrix materials made from selective inorganic fillers and polymers are very attractive for the manufacturing of gas separation membranes. But only few of these materials could be manufactured into high-performance asymmetric or composite membranes. We report here the first mixed matrix composite membrane made of commercially available poly (amide-b-ethylene oxide) (Pebax®1657, Arkema) mixed with the nano-sized zeolitic imidazole framework ZIF-7. This hybrid material has been successfully deposited as a thin layer (less than 1μm) on a porous polyacrylonitrile (PAN) support. An intermediate gutter layer of PTMSP was applied to serve as a flat and smooth surface for coating to avoid polymer penetration into the porous support. Key features of this work are the preparation and use of ultra-small ZIF-7 nano-particles (around 30-35nm) and the membrane processability of Pebax®1657. SEM pictures show that excellent adhesion and almost ideal morphology between the two phases has been obtained simply by mixing the as-synthesized ZIF-7 suspension into the Pebax®1657 dope, and no voids or clusters can be observed. The performance of the composite membrane is characterized by single gas permeation measurement of CO2, N2 and CH4. Both, permeability (PCO2 up to 145barrer) and gas selectivity (CO2/N2 up to 97 and CO2/CH4 up to 30) can be increased at low ZIF- loading. The CO2/CH4 selectivity can be further increased to 44 with the filler loading of 34wt%, but the permeability is reduced compared to the pure Pebax®1657 membrane. Polymer chain rigidification at high filler loading is supposed to be a reason for the reduced permeability. The composite membranes prepared in this work show better performance in terms of permeance and selectivity when compared with asymmetric mixed matrix membranes described in the recent literature. Overall, the ZIF 7/Pebax mixed matrix membranes show a high performance for CO2 separation from methane and other gas streams. They are easy to

  14. Preliminary study on gas separation performance of flat sheet mixed matrix (PVDF/Zeolite)

    Science.gov (United States)

    Rahman, Sunarti Abd; Abdalla Suliman Haron, Gamal; Krishna Roshan Kanasan, Raj; Hasbullah, Hasrinah

    2018-04-01

    Membrane separation has attracted a lot of attention over the last years mainly due to its separation ability, operational capability and economical viability. Mixed matrix membrane (MMM) combines the superior transport and selectivity properties of inorganic membrane materials and the excellent fabrication properties of organic polymers. This emerging technology can be utilized to purify biogas which can be used in a variety of applications. In this study, flat sheet mixed matrix membranes were synthesized with different percentages of N-Mehtyl-2-pyrrolidone (NMP) as solvent, Polyvinylidene Fluoride (PVDF) as the polymer matrix and zeolite 4A as the dispersed fine particles, membrane A (80: 20: 0), membrane B (80: 18: 2), membrane C (80: 15: 5), and membrane D (75: 15: 10) respectively. The membranes were fabricated using dry/wet phase inversion method. The membrane’s performance in terms of permeability and selectivity was examined using the single gas permeation device. The general trend was that, the permeability of the two gases (CO2/CH4) decreased with the increase of the pressure (0.5, 1, 1.5) bar. Membrane D was found to be suitable to separate the pair gas (CO2/CH4) as the permeability was 65623.412, Barrer and 15587.508, Barrer respectively, and its selectivity for was 4.21 at 0.5 bar.

  15. Functionalized carbon nanotubes mixed matrix membranes of polymers of intrinsic microporosity for gas separation.

    Science.gov (United States)

    Khan, Muntazim Munir; Filiz, Volkan; Bengtson, Gisela; Shishatskiy, Sergey; Rahman, Mushfequr; Abetz, Volker

    2012-09-06

    The present work reports on the gas transport behavior of mixed matrix membranes (MMM) which were prepared from multi-walled carbon nanotubes (MWCNTs) and dispersed within polymers of intrinsic microporosity (PIM-1) matrix. The MWCNTs were chemically functionalized with poly(ethylene glycol) (PEG) for a better dispersion in the polymer matrix. MMM-incorporating functionalized MWCNTs (f-MWCNTs) were fabricated by dip-coating method using microporous polyacrylonitrile membrane as a support and were characterized for gas separation performance. Gas permeation measurements show that MMM incorporated with pristine or functionalized MWCNTs exhibited improved gas separation performance compared to pure PIM-1. The f-MWCNTs MMM show better performance in terms of permeance and selectivity in comparison to pristine MWCNTs. The gas permeances of the derived MMM are increased to approximately 50% without sacrificing the selectivity at 2 wt.% of f-MWCNTs' loading. The PEG groups on the MWCNTs have strong interaction with CO2 which increases the solubility of polar gas and limit the solubility of nonpolar gas, which is advantageous for CO2/N2 selectivity. The addition of f-MWCNTs inside the polymer matrix also improved the long-term gas transport stability of MMM in comparison with PIM-1. The high permeance, selectivity, and long term stability of the fabricated MMM suggest that the reported approach can be utilized in practical gas separation technology.

  16. Prepare and characterization of nanocomposite - mixed matrix membranes based on polycarbonate

    International Nuclear Information System (INIS)

    Paranhos, Caio M.; Pessan, Luiz A.; Gomes, Ana C. de O.

    2009-01-01

    Mixed matrix membranes based on polycarbonate with different content of sepiolite were prepared by casting. The obtained membranes were characterized by wide-angle X-ray diffraction, thermal analysis, optical transparency and permeation to oxygen. The presence of sepiolite leads to the formation of a polymer-clay interface. The presence of the interface causes the increase in O 2 permeation. Increasing content of sepiolite results in aggregates of sepiolite, which forms preferential channels to the O 2 molecules. This fact is directly related to the strong increasing observed in O 2 permeability. (author)

  17. First Constraints on the Complete Neutrino Mixing Matrix with a Sterile Neutrino.

    Science.gov (United States)

    Collin, G H; Argüelles, C A; Conrad, J M; Shaevitz, M H

    2016-11-25

    Neutrino oscillation models involving one extra mass eigenstate beyond the standard three (3+1) are fit to global short baseline experimental data and the recent IceCube ν_{μ}+ν[over ¯]_{μ} disappearance search result. We find a best fit of Δm_{41}^{2}=1.75  eV^{2} with Δχ_{null-min}^{2}/d.o.f. of 50.61/4. We find that the combined IceCube and short baseline data constrain θ_{34} to IceCube information provides the first constraints on all entries of the 3+1 mixing matrix.

  18. Approximate Uniqueness Estimates for Singular Correlation Matrices.

    Science.gov (United States)

    Finkbeiner, C. T.; Tucker, L. R.

    1982-01-01

    The residual variance is often used as an approximation to the uniqueness in factor analysis. An upper bound approximation to the residual variance is presented for the case when the correlation matrix is singular. (Author/JKS)

  19. Dissipative control for singular impulsive dynamical systems

    Directory of Open Access Journals (Sweden)

    Li Yang

    2012-04-01

    Full Text Available The aim of this work is to study the dissipative control problem for singular impulsive dynamical systems. We start by introducing the impulse to the singular systems, and give the definition of the dissipation for singular impulsive dynamical systems. Then we discuss the dissipation of singular impulsive dynamical systems, we obtain some sufficient and necessary conditions for dissipation of these systems by solving some linear matrix inequalities (LMIs. By using this method, we design a state feedback controller to make the closed-loop system dissipative. At last, we testify the feasibility of the method by a numerical example.

  20. Effects of ZnO Nanoparticle on the Gas Separation Performance of Polyurethane Mixed Matrix Membrane.

    Science.gov (United States)

    Soltani, Banafsheh; Asghari, Morteza

    2017-08-11

    Polyurethane (PU)-ZnO mixed matrix membranes (MMM) were fabricated and characterized for gas separation. A thermogravimetric analysis (TGA), a scanning electron microscope (SEM) test and an atomic-force microscopy (AFM) revealed that the physical properties and thermal stability of the membranes were improved through filler loading. Hydrogen Bonding Index, obtained from the Fourier transform infrared spectroscopy (FTIR), demonstrate that the degree of phase separation in PU-ZnO 0.5 wt % MMM was more than the neat PU, while in PU-ZnO 1.0 wt % MMM, the phase mixing had increased. Compared to the neat membrane, the CO₂ permeability of the MMMs increased by 31% for PU-ZnO 0.5 wt % MMM and decreased by 34% for 1.0 wt % ZnO MMM. The CO₂/CH₄ and CO₂/N₂ selectivities of PU-ZnO 0.5 wt % were 18.75 and 64.75, respectively.

  1. Linear matrix inequality approach for synchronization control of fuzzy cellular neural networks with mixed time delays

    International Nuclear Information System (INIS)

    Balasubramaniam, P.; Kalpana, M.; Rakkiyappan, R.

    2012-01-01

    Fuzzy cellular neural networks (FCNNs) are special kinds of cellular neural networks (CNNs). Each cell in an FCNN contains fuzzy operating abilities. The entire network is governed by cellular computing laws. The design of FCNNs is based on fuzzy local rules. In this paper, a linear matrix inequality (LMI) approach for synchronization control of FCNNs with mixed delays is investigated. Mixed delays include discrete time-varying delays and unbounded distributed delays. A dynamic control scheme is proposed to achieve the synchronization between a drive network and a response network. By constructing the Lyapunov—Krasovskii functional which contains a triple-integral term and the free-weighting matrices method an improved delay-dependent stability criterion is derived in terms of LMIs. The controller can be easily obtained by solving the derived LMIs. A numerical example and its simulations are presented to illustrate the effectiveness of the proposed method. (interdisciplinary physics and related areas of science and technology)

  2. CO2–CH4 permeation in high zeolite 4A loading mixed matrix membranes

    KAUST Repository

    Adams, Ryan T.

    2011-02-01

    Mixed matrix membranes (MMMs) with low particle loadings have been shown to improve the properties of pure polymers for many gas separations. Comparatively few reports have been made for high particle loading (≥50vol.%) MMMs. In this work, CO2-CH4 feeds were used to study the potential of 50vol.% zeolite 4A-poly(vinyl acetate) (PVAc) MMMs for natural gas separations. A low CO2 partial pressure mixed feed probed MMM performance below the plasticization pressure of PVAc and a high CO2 partial pressure mixed feed probed MMM performance at industrially relevant conditions above the plasticization pressure.Under both mixed feed conditions at 35°C, substantial improvements in overall separation performance were observed. At low CO2 partial pressures, CO2 permeability roughly doubled with a nearly 50% increase in selectivity versus pure PVAc under the same conditions. For the high CO2 partial pressure feed, CO2 permeability remained effectively unchanged with a 63% increase in selectivity versus pure PVAc. Surprisingly, the performance of these PVAc based MMMs approached the properties of current " upper bound" polymers. Overall, this work shows that significantly improved performance MMMs can be made with traditional techniques from a low cost, low performance polymer without costly adhesion promoters. © 2010.

  3. Mixed Matrix Membranes of Boron Icosahedron and Polymers of Intrinsic Microporosity (PIM-1) for Gas Separation.

    Science.gov (United States)

    Khan, Muntazim Munir; Shishatskiy, Sergey; Filiz, Volkan

    2018-01-02

    This work reports on the preparation and gas transport performance of mixed matrix membranes (MMMs) based on the polymer of intrinsic microporosity (PIM-1) and potassium dodecahydrododecaborate (K₂B 12 H 12 ) as inorganic particles (IPs). The effect of IP loading on the gas separation performance of these MMMs was investigated by varying the IP content (2.5, 5, 10 and 20 wt %) in a PIM-1 polymer matrix. The derived MMMs were characterized by scanning electron microscopy (SEM), thermogravimetric analysis (TGA), single gas permeation tests and sorption measurement. The PIM1/K₂B 12 H 12 MMMs show good dispersion of the IPs (from 2.5 to 10 wt %) in the polymer matrix. The gas permeability of PIM1/K₂B 12 H 12 MMMs increases as the loading of IPs increases (up to 10 wt %) without sacrificing permselectivity. The sorption isotherm in PIM-1 and PIM1/K₂B 12 H 12 MMMs demonstrate typical dual-mode sorption behaviors for the gases CO₂ and CH₄.

  4. Fabrication of Functionalized MOFs Incorporated Mixed Matrix Hollow Fiber Membrane for Gas Separation

    Directory of Open Access Journals (Sweden)

    Haitao Zhu

    2017-01-01

    Full Text Available The metal-organic framework (MOFs of MIL-53 was functionalized by aminosilane grafting and then incorporated into Ultem®1000 polymer matrix to fabricate mixed matrix hollow fiber membrane (MMHFM with high separation performance. SEM, XRD, and TGA were performed to characterize the functionalized MIL-53 and prepared MMHFM. The filler particles were embedded in membrane successfully and dispersed well in the polymer matrix. The incorporation of MOFs endowed MMHFM better thermal stability. Moreover, effects of solvent ratio in spinning dope, spinning condition, and testing temperature on gas separation performance of MMHFM were investigated. By optimizing dope composition, air gap distance, and bore fluid composition, MMHFM containing functionalized MIL-53 achieved excellent gas permeance and CO2/N2 selectivity. The CO2 permeance increased from 12.2 GPU for pure Ultem HFM to 30.9 GPU and the ideal CO2/N2 selectivity was enhanced from 25.4 to 34.7 simultaneously. Additionally, gas permeance increased but the selectivity decreased with the temperature increase, which followed the solution-diffusion based transport mechanism.

  5. Mixed Matrix Composite Membranes Containing POSS Molecules for Carbon Dioxide Removal Application

    KAUST Repository

    Rini, Eki Listya

    2011-05-10

    CO2 removal by membrane processes is considerably potential for several applications such as natural gas and synthesis gas purification, enhanced oil recovery application, and carbon dioxide capture in combat against global warming. Dense polymeric membranes are commonly utilized for these type of gas separation applications. Nevertheless, the intrinsic properties of dense polymeric membranes, which commonly characterize by the low gas permeability versus high gas selectivity trade–off or vice versa, is less desirable. In order to meet the increased demand of CO2 removal, a strategy to improve the gas separation performance of a polymeric membrane is investigated in this study. With this regard, mixed matrix membranes in which inorganic non porous fillers are incorporated into a polymeric matrix were prepared to achieve the aforementioned objective. The mixed matrix membranes were prepared from Pebax® block copolymers and PEG POSS® molecules. These hybrid membranes were formed as both dense and multilayer composite membranes. The dense transparent membranes with well–dispersed fillers could be obtained by variation of the solvent mixture. The DSC analyses showed that incorporation of PEG POSS® into Pebax® matrix altered the thermal properties of the matrix. The multilayer composite membranes were then prepared from a PTMSP gutter layer deposited on a PAN porous support and an adjacent hybrid Pebax®/PEG POSS® as the top layer. These hybrid multilayer composite membranes exhibited an enhanced CO2 selectiv4 ity by a factor of two relative to the pure Pebax®. In these hybrid systems, the CO2 separation was presumably enhanced by the high ether oxides content from PEG POSS® that has high affinities for CO2. For particular composition of Pebax® and PEG POSS® concentrations, the PTMSP gutter layer harnessed the CO2 selectivity without losing the CO2 permeation rate. At the same time, these membrane, however, suffered severe adhesion between the gutter layer

  6. Mixed matrix membranes prepared from high impact polystyrene with dispersed TiO2 nanoparticles for gas separation

    Directory of Open Access Journals (Sweden)

    P. Safaei

    2016-01-01

    Full Text Available The current study presents synthesis and characterization of high impact polystyrene - TiO2 nanoparticles mixed matrix membranes for separation of carbon dioxide from nitrogen. The solution-casting method was used for preparation of membranes. The nano mixed matrix membranes were characterized using scanning electron microscopy to ensure the suitable dispersion of nano particles in high impact polystyrene matrix. The effect of TiO2 nanoparticles loading on membrane performance was investigated. The separation performance of synthesized membranes was investigated in separation of CO2 from CO2/N2 mixture. Effect of feed pressure and TiO2 content on separation of CO2 was studied. The results revealed that increase of feed pressure decreases flux of gases through the mixed matrix membrane. The results also confirmed that the best separation performance can be obtained at TiO2 nanoparticles loading of 7 wt.%.

  7. THE EFFECT OF TYPE ZEOLITE ON THE GAS TRANSPORT PROPERTIES OF POLYIMIDE-BASED MIXED MATRIX MEMBRANES

    Directory of Open Access Journals (Sweden)

    Tutuk Djoko Kusworo

    2012-01-01

    Full Text Available The permeation rates of O2, N2, CO2 and CH4 has been studied for polyimide-polyethersulfone (PI/PES blends-zeolite mixed matrix membranes synthesized in our laboratory. The study investigated the effect of zeolite loading and different zeolite type on the gas separation performance of these mixed matrix membranes. Frequency shifts and absorption intensity changes in the FTIR spectra of the PI/PES blends as compared with those of the pure polymers indicate that there is a mixing of polymer blends at the molecular level. Differential scanning calorimetry measurements of pure and PI/PES blends membranes have showed one unique glass transition temperature that supports the miscible character of the PI/PES mixture. The PI/PES-zeolite 4A mixed matrix membrane with 25 wt % zeolite loading produced the highest O2/N2 and CO2/CH4 selectivity of around 7.45 and 46.05, respectively.

  8. Nano-ZnO embedded mixed matrix polyethersulfone (PES) membrane: Influence of nanofiller shape on characterization and fouling resistance

    Energy Technology Data Exchange (ETDEWEB)

    Rajabi, Hamid [Membrane Research Centre, Department of Chemical Engineering, Razi University, Tagh Bostan, 67149 Kermanshah (Iran, Islamic Republic of); Department of Civil Engineering, Razi University, 67149 Kermanshah (Iran, Islamic Republic of); Ghaemi, Negin, E-mail: negin_ghaemi@kut.ac.ir [Department of Chemical Engineering, Kermanshah University of Technology, 67178 Kermanshah (Iran, Islamic Republic of); Madaeni, Sayed S. [Membrane Research Centre, Department of Chemical Engineering, Razi University, Tagh Bostan, 67149 Kermanshah (Iran, Islamic Republic of); Daraei, Parisa [Department of Chemical Engineering, Kermanshah University of Technology, 67178 Kermanshah (Iran, Islamic Republic of); Astinchap, Bandar [Physics Department, Faculty of Science, University of Kurdistan, Sanandaj (Iran, Islamic Republic of); Zinadini, Sirus [Water and Wastewater Research Center (WWRC), Department of Applied Chemistry, Faculty of Chemistry, Razi University, Kermanshah (Iran, Islamic Republic of); Razavizadeh, Sayed Hossein [Department of Chemical Engineering, Kermanshah University of Technology, 67178 Kermanshah (Iran, Islamic Republic of)

    2015-09-15

    Graphical abstract: - Highlights: • ZnO nanofillers with different shape (nanorod and nanoparticle) were synthesized. • Mixed matrix PES membranes were fabricated by different concentrations of nanofillers. • Embedding nanofillers affected on morphology and hydrophilicity of PES membranes. • Nanorod MM membranes revealed the highest water flux and antifouling characteristic. • ZnO nanorod-embedded membrane showed an acceptable reusability and durability. - Abstract: Two different kinds of nano-ZnO (nanoparticle and nanorod) were synthesized, characterized, and embedded in a PES membrane matrix to investigate the effects of a nanofiller shape on the mixed matrix membrane characteristics and the antifouling capability. The mixed matrix membranes were fabricated by mixing different amounts of nanofillers with dope solution followed by a phase inversion precipitation technique. The effect of the shape of the embedded nanofillers on the morphology and performance of the fabricated membranes was studied in terms of pure water flux, fouling resistance, hydrophilicity, surface, and bulk morphology by means of permeation tests, milk powder solution filtration, water contact angle and porosity measurements, scanning electron microscopy (SEM), and atomic force microscopy (AFM) techniques. Water flux of the mixed matrix membranes significantly improved after the addition of both types of ZnO nanofillers due to a higher hydrophilicity and porosity of the prepared membranes. The water contact angle measurements confirmed the increased hydrophilicity of the modified membranes, particularly in the ZnO nanorod mixed membranes. Fouling resistance of the membranes assessed by powder milk solution filtration revealed that 0.1 wt% ZnO nanorod membrane has the best antifouling property. The prepared mixed matrix membranes embedded with 0.1 wt% of both types of ZnO nanofillers showed a remarkable durability and reusability during the filtration tests; however, the best

  9. Exploring Mixed Membership Stochastic Block Models via Non-negative Matrix Factorization

    KAUST Repository

    Peng, Chengbin

    2014-12-01

    Many real-world phenomena can be modeled by networks in which entities and connections are represented by nodes and edges respectively. When certain nodes are highly connected with each other, those nodes forms a cluster, which is called community in our context. It is usually assumed that each node belongs to one community only, but evidences in biology and social networks reveal that the communities often overlap with each other. In other words, one node can probably belong to multiple communities. In light of that, mixed membership stochastic block models (MMB) have been developed to model those networks with overlapping communities. Such a model contains three matrices: two incidence matrices indicating in and out connections and one probability matrix. When the probability of connections for nodes between communities are significantly small, the parameter inference problem to this model can be solved by a constrained non-negative matrix factorization (NMF) algorithm. In this paper, we explore the connection between the two models and propose an algorithm based on NMF to infer the parameters of MMB. The proposed algorithms can detect overlapping communities regardless of knowing or not the number of communities. Experiments show that our algorithm can achieve a better community detection performance than the traditional NMF algorithm. © 2014 IEEE.

  10. Characterizations of Polysulfone/Ferrihydrite Mixed Matrix Membranes for Water/Wastewater Treatment.

    Science.gov (United States)

    Abdullah, Norfadhilatuladha; Yusof, Norhaniza; Gohari, Rasool J; Ismail, Ahmad F; Jaafar, Juhana; Lau, Woei J; Misdan, Nurasyikin; Hairom, Nur H H

    2018-01-01

      This study aimed to investigate the effects of ferrihydrite (Fh) nanoparticle loading on the physicochemical properties of polysulfone (PSf) membranes fabricated via the phase inversion method. The morphologies and physicochemical properties of prepared Fh and PSf/Fh mixed matrix membranes (MMMs) were characterized using transmission electron microscopy (TEM), X-ray diffraction analysis (XRD), Fourier transmission infra-red (FTIR), scanning electron microscopy (SEM), atomic force microscopy (AFM), pure water flux analysis, contact angle measurement, and membrane porosity analysis. FTIR study indicated that a new O-H band was formed when Fh was added into the membrane matrix. SEM analysis showed the formation of typical asymmetric membrane structures with elongated fingerlike and looser porous layers. Increasing the loading of Fh significantly enhanced membrane pure water flux from 230.2 L/m2•h (M-Fh 0%) to 726.6 L/m2•h (M-Fh 15.3%), attributed to the improved membranes structures, membranes wettability, surface roughness, and overall porosity. The findings suggest incorporation of Fh into PSf membranes improves physicochemical properties of the membranes which are applicable for water/wastewater treatment.

  11. Studies on carboxylated graphene oxide incorporated polyetherimide mixed matrix ultrafiltration membranes

    Energy Technology Data Exchange (ETDEWEB)

    Kaleekkal, Noel Jacob, E-mail: noeljacob89@gmail.com [Membrane Laboratory, Department of Chemical Engineering, ACT, Anna University, Chennai, 600025 (India); Thanigaivelan, A., E-mail: thanichemstar@gmail.com [Membrane Laboratory, Department of Chemical Engineering, ACT, Anna University, Chennai, 600025 (India); Rana, Dipak, E-mail: rana@uottawa.ca [Department of Chemical and Biological Engineering, University of Ottawa, 161 Louis Pasteur Private, Ottawa, Ontario, K1N 6N5 (Canada); Mohan, D., E-mail: mohantarun@gmail.com [Membrane Laboratory, Department of Chemical Engineering, ACT, Anna University, Chennai, 600025 (India)

    2017-01-15

    In this work the graphene oxide prepared by the modified Hummers’ method was effectively carboxylated. These carboxylated graphene oxide (c-GO) microsheets was characterized by X-ray diffraction analysis, Raman shift, zeta potential, and their morphology was observed using a high resolution scanning/transmission electron microscopy. Polyetherimide mixed matrix membranes (MMMs) were fabricated by the non-solvent induced phase separation technique with varying concentration of this microsheet. The presence of these microsheets on the membrane surface was confirmed by Fourier transform infrared spectroscopy, Raman spectroscopy and could also be confirmed visually by optical images. The membranes were further characterized; they showed a greater water flux, higher porosity, and sufficient thermal stability. Incorporation of these microsheets improved the hydrophilicity of the membrane confirmed by the lower contact angle values, which in turn explained the lower interfacial free energy, the increase in work of adhesion, the higher solid-vapor free energy and the spreading coefficient. Membranes loaded with 0.3 wt% of c-GO showed a flux recovery of 94% and only a small flux decline even after 180 min of filtration of humic acid (HA) solution. The efficiency of these membranes in removal of HA, toxic metal ions was also investigated. The bacterial anti-adhesion property of c-GO in the membranes was also explored using Escherichia coli, as a model bio-foulant. The charge of the microsheets and their unique architecture imparts higher hydrophilicity and greater fouling resistance along with improved permeation flux when incorporated into the polymer matrix. - Highlights: • Novel membranes by incorporating carboxylated GO into polyetherimide matrix. • Modified membranes exhibited greater porosity, flux and high humic acid rejection. • Nanoplatelets improved the flux recovery ratio to >94%. • Liquid phase polymer based retention utilized for toxic heavy metal

  12. Modeling the Effects of Interfacial Characteristics on Gas Permeation Behavior of Nanotube-Mixed Matrix Membranes.

    Science.gov (United States)

    Chehrazi, Ehsan; Sharif, Alireza; Omidkhah, Mohammadreza; Karimi, Mohammad

    2017-10-25

    Theoretical approaches that accurately predict the gas permeation behavior of nanotube-containing mixed matrix membranes (nanotube-MMMs) are scarce. This is mainly due to ignoring the effects of nanotube/matrix interfacial characteristics in the existing theories. In this paper, based on the analogy of thermal conduction in polymer composites containing nanotubes, we develop a model to describe gas permeation through nanotube-MMMs. Two new parameters, "interfacial thickness" (a int ) and "interfacial permeation resistance" (R int ), are introduced to account for the role of nanotube/matrix interfacial interactions in the proposed model. The obtained values of a int , independent of the nature of the permeate gas, increased by increasing both the nanotubes aspect ratio and polymer-nanotube interfacial strength. An excellent correlation between the values of a int and polymer-nanotube interaction parameters, χ, helped to accurately reproduce the existing experimental data from the literature without the need to resort to any adjustable parameter. The data includes 10 sets of CO 2 /CH 4 permeation, 12 sets of CO 2 /N 2 permeation, 3 sets of CO 2 /O 2 permeation, and 2 sets of CO 2 /H 2 permeation through different nanotube-MMMs. Moreover, the average absolute relative errors between the experimental data and the predicted values of the proposed model are very small (less than 5%) in comparison with those of the existing models in the literature. To the best of our knowledge, this is the first study where such a systematic comparison between model predictions and such extensive experimental data is presented. Finally, the new way of assessing gas permeation data presented in the current work would be a simple alternative to complex approaches that are usually utilized to estimate interfacial thickness in polymer composites.

  13. Carbon capture from natural gas using multi-walled CNTs based mixed matrix membranes.

    Science.gov (United States)

    Hussain, Abid; Farrukh, Sarah; Hussain, Arshad; Ayoub, Muhammad

    2017-12-05

    Most of the polymers and their blends, utilized in carbon capture membranes, are costly, but cellulose acetate (CA) being inexpensive is a lucrative choice. In this research, pure and mixed matrix membranes (MMMs) have been fabricated to capture carbon from natural gas. Polyethylene glycol (PEG) has been utilized in the fabrication of membranes to modify the chain flexibility of polymers. Multi-walled carbon nanotubes (MWCNTs) provide mechanical strength, thermal stability, an extra free path for CO 2 molecules and augment CO 2 /CH 4 selectivity. Membranes of pure CA, CA/PEG blend of different PEG concentrations (5%, 10%, 15%) and CA/PEG/MWCNTs blend of 10% PEG with different MWCNTs concentrations (5%, 10%, 15%) were prepared in acetone using solution casting techniques. Fabricated membranes were characterized using SEM, TGA and tensile testing. Permeation results revealed remarkable improvement in CO 2 /CH 4 selectivity. In single gas experiments, CO 2 /CH 4 selectivity is enhanced 8 times for pure membranes containing 10% PEG and 14 times for MMMs containing 10% MWCNTs. In mix gas experiments, the CO 2 /CH 4 selectivity is increased 13 times for 10% PEG and 18 times for MMMs with 10% MWCNTs. Fabricated MMMs have a tensile strength of 13 MPa and are more thermally stable than CA membranes.

  14. Preparation and performance study of a novel liquid scintillator with mixed solvent as the matrix

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Zhanlong [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010 (China); Joint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology and Research Center of Laser Fusion, Mianyang 621010 (China); Zhu, Jiayi [Joint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology and Research Center of Laser Fusion, Mianyang 621010 (China); Luo, Xuan, E-mail: luox76@gmail.com [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); Xu, Yewei [School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010 (China); Zhang, Qianfeng [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); Joint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology and Research Center of Laser Fusion, Mianyang 621010 (China); Zhang, Xing [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); Bi, Yutie, E-mail: biyutie@sina.com [Joint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology and Research Center of Laser Fusion, Mianyang 621010 (China); Zhang, Lin [Research Center of Laser Fusion, China Academy of Engineering Physics, Mianyang 621900 (China); School of Material Science and Engineering, Southwest University of Science and Technology, Mianyang 621010 (China); Joint Laboratory for Extreme Conditions Matter Properties, Southwest University of Science and Technology and Research Center of Laser Fusion, Mianyang 621010 (China)

    2017-04-01

    A novel liquid scintillator with the mixed solvent as the matrix was prepared for obtaining a good comprehensive performance. In this ternary liquid scintillator, the combination of 20% pseudocumene (PC) and 80% linear-alkyl benzene (LAB) by volume was chosen as the mixed solvent, and 2,5-diphenyloxazole (PPO) and 1,4-bis(2-Methylstyryl) benzene (bis-MSB) were as the primary fluor and wavelength shifter, respectively. The optimum prescription was obtained with regard to the light yield. Some characterizations based on the optimal formulation were conducted. The fluorescence emission spectra and wavelength-dependent optical attenuation length of the sample were measured by the fluorescence spectrophotometer and an UV–Vis spectrometer, respectively. The light yield was characterized by adopting the home-made optical platform device. The decay time was tested by adopting the time-correlated single photon counting (TCSPC) technique featured in high dynamic range of several orders of magnitude in light intensity. The experimental test results showed that the sample had a fairly good comprehensive performance.

  15. EXPERIMENTAL DESIGN AND RESPONSE SURFACE MODELING OF PI/PES-ZEOLITE 4A MIXED MATRIX MEMBRANE FOR CO2 SEPARATION

    Directory of Open Access Journals (Sweden)

    T. D. KUSWORO

    2015-09-01

    Full Text Available This paper investigates the effect of preparation of polyimide/polyethersulfone (PI/PES blending-zeolite mixed matrix membrane through the manipulation of membrane production variables such as polymer concentration, blending composition and zeolite loading. Combination of central composite design and response surface methodology were applied to determine the main effect and interaction effects of these variables on membrane separation performance. The quadratic models between each response and the independent parameters were developed and the response surface models were tested with analysis of variance (ANOVA. In this study, PI/ (PES–zeolite 4A mixed matrix membranes were casted using dry/wet phase inversion technique. The separation performance of mixed matrix membrane had been tested using pure gases such as CO2 and CH4. The results showed that zeolite loading was the most significant variable that influenced the CO2/CH4 selectivity among three variables and the experimental results were in good agreement with those predicted by the proposed regression models. The gas separation performance of the membrane was relatively higher as compare to polymeric membrane. Therefore, combination of central composite design and response surface methodology can be used to prepare optimal condition for mixed matrix membrane fabrication. The incorporation of 20 wt% zeolite 4A into 25 wt% of PI/PES matrix had resulted in a high separation performance of membrane material.

  16. Biclustering via Sparse Singular Value Decomposition

    KAUST Repository

    Lee, Mihee

    2010-02-16

    Sparse singular value decomposition (SSVD) is proposed as a new exploratory analysis tool for biclustering or identifying interpretable row-column associations within high-dimensional data matrices. SSVD seeks a low-rank, checkerboard structured matrix approximation to data matrices. The desired checkerboard structure is achieved by forcing both the left- and right-singular vectors to be sparse, that is, having many zero entries. By interpreting singular vectors as regression coefficient vectors for certain linear regressions, sparsity-inducing regularization penalties are imposed to the least squares regression to produce sparse singular vectors. An efficient iterative algorithm is proposed for computing the sparse singular vectors, along with some discussion of penalty parameter selection. A lung cancer microarray dataset and a food nutrition dataset are used to illustrate SSVD as a biclustering method. SSVD is also compared with some existing biclustering methods using simulated datasets. © 2010, The International Biometric Society.

  17. Flavour from partially resolved singularities

    Energy Technology Data Exchange (ETDEWEB)

    Bonelli, G. [International School of Advanced Studies (SISSA) and INFN, Sezione di Trieste, via Beirut 2-4, 34014 Trieste (Italy)]. E-mail: bonelli@sissa.it; Bonora, L. [International School of Advanced Studies (SISSA) and INFN, Sezione di Trieste, via Beirut 2-4, 34014 Trieste (Italy); Ricco, A. [International School of Advanced Studies (SISSA) and INFN, Sezione di Trieste, via Beirut 2-4, 34014 Trieste (Italy)

    2006-06-15

    In this Letter we study topological open string field theory on D-branes in a IIB background given by non-compact CY geometries O(n)-bar O(-2-n) on P{sup 1} with a singular point at which an extra fiber sits. We wrap N D5-branes on P{sup 1} and M effective D3-branes at singular points, which are actually D5-branes wrapped on a shrinking cycle. We calculate the holomorphic Chern-Simons partition function for the above models in a deformed complex structure and find that it reduces to multi-matrix models with flavour. These are the matrix models whose resolvents have been shown to satisfy the generalized Konishi anomaly equations with flavour. In the n=0 case, corresponding to a partial resolution of the A{sub 2} singularity, the quantum superpotential in the N=1 unitary SYM with one adjoint and M fundamentals is obtained. The n=1 case is also studied and shown to give rise to two-matrix models which for a particular set of couplings can be exactly solved. We explicitly show how to solve such a class of models by a quantum equation of motion technique.

  18. D-branes at toric singularities: model building, Yukawa couplings and flavour physics

    International Nuclear Information System (INIS)

    Krippendorf, Sven; Dolan, Matthew J.; Maharana, Anshuman; Quevedo, Fernando

    2010-02-01

    We discuss general properties of D-brane model building at toric singularities. Using dimer techniques to obtain the gauge theory from the structure of the singularity, we extract results on the matter sector and superpotential of the corresponding gauge theory. We show that the number of families in toric phases is always less than or equal to three, with a unique exception being the zeroth Hirzebruch surface. With the physical input of three generations we find that the lightest family of quarks is massless and the masses of the other two can be hierarchically separated. We compute the CKM matrix for explicit models in this setting and find the singularities possess sufficient structure to allow for realistic mixing between generations and CP violation. (author)

  19. The augmented lagrange multipliers method for matrix completion from corrupted samplings with application to mixed Gaussian-impulse noise removal.

    Science.gov (United States)

    Meng, Fan; Yang, Xiaomei; Zhou, Chenghu

    2014-01-01

    This paper studies the problem of the restoration of images corrupted by mixed Gaussian-impulse noise. In recent years, low-rank matrix reconstruction has become a research hotspot in many scientific and engineering domains such as machine learning, image processing, computer vision and bioinformatics, which mainly involves the problem of matrix completion and robust principal component analysis, namely recovering a low-rank matrix from an incomplete but accurate sampling subset of its entries and from an observed data matrix with an unknown fraction of its entries being arbitrarily corrupted, respectively. Inspired by these ideas, we consider the problem of recovering a low-rank matrix from an incomplete sampling subset of its entries with an unknown fraction of the samplings contaminated by arbitrary errors, which is defined as the problem of matrix completion from corrupted samplings and modeled as a convex optimization problem that minimizes a combination of the nuclear norm and the l(1)-norm in this paper. Meanwhile, we put forward a novel and effective algorithm called augmented Lagrange multipliers to exactly solve the problem. For mixed Gaussian-impulse noise removal, we regard it as the problem of matrix completion from corrupted samplings, and restore the noisy image following an impulse-detecting procedure. Compared with some existing methods for mixed noise removal, the recovery quality performance of our method is dominant if images possess low-rank features such as geometrically regular textures and similar structured contents; especially when the density of impulse noise is relatively high and the variance of Gaussian noise is small, our method can outperform the traditional methods significantly not only in the simultaneous removal of Gaussian noise and impulse noise, and the restoration ability for a low-rank image matrix, but also in the preservation of textures and details in the image.

  20. The augmented lagrange multipliers method for matrix completion from corrupted samplings with application to mixed Gaussian-impulse noise removal.

    Directory of Open Access Journals (Sweden)

    Fan Meng

    Full Text Available This paper studies the problem of the restoration of images corrupted by mixed Gaussian-impulse noise. In recent years, low-rank matrix reconstruction has become a research hotspot in many scientific and engineering domains such as machine learning, image processing, computer vision and bioinformatics, which mainly involves the problem of matrix completion and robust principal component analysis, namely recovering a low-rank matrix from an incomplete but accurate sampling subset of its entries and from an observed data matrix with an unknown fraction of its entries being arbitrarily corrupted, respectively. Inspired by these ideas, we consider the problem of recovering a low-rank matrix from an incomplete sampling subset of its entries with an unknown fraction of the samplings contaminated by arbitrary errors, which is defined as the problem of matrix completion from corrupted samplings and modeled as a convex optimization problem that minimizes a combination of the nuclear norm and the l(1-norm in this paper. Meanwhile, we put forward a novel and effective algorithm called augmented Lagrange multipliers to exactly solve the problem. For mixed Gaussian-impulse noise removal, we regard it as the problem of matrix completion from corrupted samplings, and restore the noisy image following an impulse-detecting procedure. Compared with some existing methods for mixed noise removal, the recovery quality performance of our method is dominant if images possess low-rank features such as geometrically regular textures and similar structured contents; especially when the density of impulse noise is relatively high and the variance of Gaussian noise is small, our method can outperform the traditional methods significantly not only in the simultaneous removal of Gaussian noise and impulse noise, and the restoration ability for a low-rank image matrix, but also in the preservation of textures and details in the image.

  1. Cranberry Flavonoids Modulate Cariogenic Properties of Mixed-Species Biofilm through Exopolysaccharides-Matrix Disruption.

    Science.gov (United States)

    Kim, Dongyeop; Hwang, Geelsu; Liu, Yuan; Wang, Yifei; Singh, Ajay P; Vorsa, Nicholi; Koo, Hyun

    2015-01-01

    The exopolysaccharides (EPS) produced by Streptococcus mutans-derived glucosyltransferases (Gtfs) are essential virulence factors associated with the initiation of cariogenic biofilms. EPS forms the core of the biofilm matrix-scaffold, providing mechanical stability while facilitating the creation of localized acidic microenvironments. Cranberry flavonoids, such as A-type proanthocyanidins (PACs) and myricetin, have been shown to inhibit the activity of Gtfs and EPS-mediated bacterial adhesion without killing the organisms. Here, we investigated whether a combination of cranberry flavonoids disrupts EPS accumulation and S. mutans survival using a mixed-species biofilm model under cariogenic conditions. We also assessed the impact of cranberry flavonoids on mechanical stability and the in situ pH at the biofilm-apatite interface. Topical application of an optimized combination of PACs oligomers (100-300 μM) with myricetin (2 mM) twice daily was used to simulate treatment regimen experienced clinically. Treatments with cranberry flavonoids effectively reduced the insoluble EPS content (>80% reduction vs. vehicle-control; pcranberry-treated biofilms was severely compromised, showing a defective EPS-matrix and failure to develop microcolonies on the saliva-coated hydroxyapatite (sHA) surface. Furthermore, topical applications of cranberry flavonoids significantly weaken the mechanical stability of the biofilms; nearly 90% of the biofilm was removed from sHA surface after exposure to a shear stress of 0.449 N/m2 (vs. 36% removal in vehicle-treated biofilms). Importantly, in situ pH measurements in cranberry-treated biofilms showed significantly higher pH values (5.2 ± 0.1) at the biofilm-apatite interface vs. vehicle-treated biofilms (4.6 ± 0.1). Altogether, the data provide important insights on how cranberry flavonoids treatments modulate virulence properties by disrupting the biochemical and ecological changes associated with cariogenic biofilm development, which

  2. Evaluation of the Compressive Strength of Cement-Spent Resins Matrix Mixed with Bio char

    International Nuclear Information System (INIS)

    Zalina Laili; Muhamad Samudi Yasir; Zalina Laili; Mohd Abdul Wahab; Nur Azna Mahmud; Nurfazlina Zainal Abidin

    2015-01-01

    The evaluation of compressive strength of cement-spent resins matrix mixed with bio char was investigated. In this study, bio char with different percentage (5 %, 8 %, 11 % 14 % and 18 %) was used as alternative admixture material for cement solidification of spent resins. Some properties of the physical and chemical of spent resins and bio char were also investigated. The performance of cemented spent resins with the addition of bio char was evaluated based on their compressive strength and the water resistance test. The compressive strength was evaluated at three different curing periods of 7, 14 and 28 days, while 4 weeks of immersion in distilled water was chosen for water resistance test. The result indicated that the compressive strength at 7, 14 and 28 days of curing periods were above the minimum criterion for example > 3.45 MPa of acceptable level for cemented waste form. Statistical analysis showed that there was no significant relationship between the compressive strength of the specimen and the percentage of bio char content. Result from the water resistance test showed that only one specimen that contained of 5 % of bio char failed the water resistance test due to the high of spent resins/ bio char ratio. The compressive strength of cement solidified spent resins was found increased after the water resistance test indicating further hydration occurred after immersed in water. The results of this study also suggest that the specimen with 8 %, 11 %, 14 % and 18 % of bio char content were resistance in water and suitable for the leaching study of radionuclides from cement-bio char-spent resins matrix. (author)

  3. Cranberry Flavonoids Modulate Cariogenic Properties of Mixed-Species Biofilm through Exopolysaccharides-Matrix Disruption.

    Directory of Open Access Journals (Sweden)

    Dongyeop Kim

    Full Text Available The exopolysaccharides (EPS produced by Streptococcus mutans-derived glucosyltransferases (Gtfs are essential virulence factors associated with the initiation of cariogenic biofilms. EPS forms the core of the biofilm matrix-scaffold, providing mechanical stability while facilitating the creation of localized acidic microenvironments. Cranberry flavonoids, such as A-type proanthocyanidins (PACs and myricetin, have been shown to inhibit the activity of Gtfs and EPS-mediated bacterial adhesion without killing the organisms. Here, we investigated whether a combination of cranberry flavonoids disrupts EPS accumulation and S. mutans survival using a mixed-species biofilm model under cariogenic conditions. We also assessed the impact of cranberry flavonoids on mechanical stability and the in situ pH at the biofilm-apatite interface. Topical application of an optimized combination of PACs oligomers (100-300 μM with myricetin (2 mM twice daily was used to simulate treatment regimen experienced clinically. Treatments with cranberry flavonoids effectively reduced the insoluble EPS content (>80% reduction vs. vehicle-control; p<0.001, while hindering S. mutans outgrowth within mixed-species biofilms. As a result, the 3D architecture of cranberry-treated biofilms was severely compromised, showing a defective EPS-matrix and failure to develop microcolonies on the saliva-coated hydroxyapatite (sHA surface. Furthermore, topical applications of cranberry flavonoids significantly weaken the mechanical stability of the biofilms; nearly 90% of the biofilm was removed from sHA surface after exposure to a shear stress of 0.449 N/m2 (vs. 36% removal in vehicle-treated biofilms. Importantly, in situ pH measurements in cranberry-treated biofilms showed significantly higher pH values (5.2 ± 0.1 at the biofilm-apatite interface vs. vehicle-treated biofilms (4.6 ± 0.1. Altogether, the data provide important insights on how cranberry flavonoids treatments modulate

  4. Engineering of Mixed Matrix Membranes for Water Treatment, Protective Coating and Gas Separation

    KAUST Repository

    Hammami, Mohamed Amen

    2017-11-01

    Mixed Matrix Membranes (MMMs) have received worldwide attention during the last decades. This is due to the fact that the resulting materials can combine the good processability and low cost of polymer membranes with the diverse functionality, high performance and thermal properties of the fillers. This work explores the fabrication and application of MMMs. We focused on the design and fabrication of nanofillers to impart target functionality to the membrane for water treatment, protective coating and gas separation. This thesis is divided into three sections according to the application including: I- Water Treatment: This part is divided into three chapters, two related to the membrane distillation (MD) and one related to the oil spill. Three different nanofillers have been used: Periodic mesoporous organosilica (PMO), graphene and carbon nanotube (CNT). Those nanofillers were homogeneously incorporated into polyetherimide (PEI) electrospun nanofiber membranes. The doped nanoparticle not only improved the mechanical properties and thermal stability of the pristine fiber but also enhanced the MD and oil spill performance due to the functionality of those nanofillers. II- Protective coating: This part includes two chapters describing the design and the fabrication of a smart antibacterial and anti-corrosion coating. In the first project, we fabricated colloidal lysozyme-templated gold nanoclusters gating antimicrobial-loaded silica nanoparticles (MSN-AuNCs@lys) as nano-fillers in poly(ethylene oxide)/poly(butylene terephthalate) polymer matrix. MSN-AuNCs@lys dispersed homogeneously within the polymer matrix with zero NPs leaching. The system was coated on a common radiographic dental imaging device that is prone to oral bacteria contamination. This coating can successfully sense and inhibit bacterial contamination via a controlled release mechanism that is only triggered by bacteria. In the second project, the coaxial electrospinning approach has been applied to

  5. Revealing Transient Concentration of CO2 in a Mixed Matrix Membrane by IR Microimaging and Molecular Modeling

    KAUST Repository

    Hwang, Seungtaik

    2018-02-21

    Through IR microimaging the spatially and temporally resolved development of the CO2 concentration in a ZIF-8@6FDA-DAM mixed matrix membrane was visualized during transient adsorption. By recording the evolution of the CO2 concentration, it is observed that the CO2 molecules propagate from the ZIF-8 filler, which acts as a transport

  6. Preparation and characterization of polysulfone/zeolite mixed matrix membranes for removal of low-concentration ammonia from aquaculture wastewater.

    Science.gov (United States)

    Moradihamedani, Pourya; Abdullah, Abdul Halim

    2018-01-01

    Removal of low-concentration ammonia (1-10 ppm) from aquaculture wastewater was investigated via polysulfone (PSf)/zeolite mixed matrix membrane. PSf/zeolite mixed matrix membranes with different weight ratios (90/10, 80/20, 70/30 and 60/40 wt.%) were prepared and characterized. Results indicate that PSf/zeolite (80/20) was the most efficient membrane for removal of low-concentration ammonia. The ammonia elimination by PSf/zeolite (80/20) from aqueous solution for 10, 7, 5, 3 and 1 ppm of ammonia was 100%, 99%, 98.8%, 96% and 95% respectively. The recorded results revealed that pure water flux declined in higher loading of zeolite in the membrane matrix due to surface pore blockage caused by zeolite particles. On the other hand, ammonia elimination from water was decreased in higher contents of zeolite because of formation of cavities and macrovoids in the membrane substructure.

  7. Partial mitigation of gold nanoparticle interactions with human lymphocytes by surface functionalization with a 'mixed matrix'.

    Science.gov (United States)

    Liptrott, Neill J; Kendall, Emily; Nieves, Daniel J; Farrell, John; Rannard, Steve; Fernig, David G; Owen, Andrew

    2014-11-01

    To investigate interactions of gold nanoparticles with primary human lymphocytes and determine if the addition of a self-assembled monolayer of 'mixed-matrix' ligands influenced these interactions. The effect of gold nanoparticles was measured by exposure to peripheral blood mononuclear cells (PBMCs) from healthy volunteers with subsequent examination of cell proliferation, cytokine secretion and CD4(+) T-cell activation relative to controls. Capped and as-synthesized gold nanoparticles augmented PBMC proliferation in response to phytohemagglutinin and this effect was greater for as-synthesized than for capped gold nanoparticles. Release of IL-10 and IFN-γ from PBMCs was increased and the effect was again more marked for as-synthesized than capped gold nanoparticles. This method provides an ex vivo approach for studying the interaction of nanoparticles with the human immune system. Further research is required to determine the specific mechanisms for reduction of immune activation seen here which could then be used to design a truly 'stealth' nanoparticle.

  8. PES-Kaolin Mixed Matrix Membranes for Arsenic Removal from Water.

    Science.gov (United States)

    Marino, Tiziana; Russo, Francesca; Rezzouk, Lina; Bouzid, Abderrazak; Figoli, Alberto

    2017-09-30

    The aim of this work was the fabrication and the characterization of mixed matrix membranes (MMMs) for arsenic (As) removal from water. Membrane separation was combined with an adsorption process by incorporating the kaolin (KT2) Algerian natural clay in polymeric membranes. The effects of casting solution composition was explored using different amounts of polyethersufone (PES) as a polymer, polyvinyl-pyrrolidone (PVP K17) and polyethylene glycol (PEG 200) as pore former agents, N -methyl pyrrolidone (NMP) as a solvent, and kaolin. Membranes were prepared by coupling Non-solvent Induced Phase Separation and Vapour Induced Phase Separation (NIPS and VIPS, respectively). The influence of the exposure time to controlled humid air and temperature was also investigated. The MMMs obtained were characterized in terms of morphology, pore size, porosity, thickness, contact angle and pure water permeability. Adsorption membrane-based tests were carried out in order to assess the applicability of the membranes produced for As removal from contaminated water. Among the investigated kaolin concentrations (ranging from 0 wt % to 5 wt %), a content of 1.25 wt % led to the MMM with the most promising performance.

  9. Modified ZIF-8 mixed matrix membrane for CO2/CH4 separation

    Science.gov (United States)

    Nordin, Nik Abdul Hadi Md; Ismail, Ahmad Fauzi; Misdan, Nurasyikin; Nazri, Noor Aina Mohd

    2017-10-01

    Tunability of metal-organic frameworks (MOFs) properties enables them to be tailored for specific applications. In this study, zeolitic imidazole framework 8 (ZIF-8), sub-class of MOF, underwent pre-synthesis and post-synthesis modifications. The pre-synthesis modification using GO (ZIF-8/GO) shows slight decrease in textural properties, while the post-synthesis modification using amine solution (ZIF-8/NH2) resulted in superior BET surface area and pore volume. Mixed matrix membranes (MMMs) derived from polysulfone (PSf) and the modified ZIF-8s were then prepared via dry/wet phase inversion. The polymer chain flexibility of the resulted MMMs shows rigidification, where ZIF-8/NH2 as filler resulting higher rigidification compared to ZIF-8/GO. The MMMs were further subjected to pure CO2 and CH4 gas permeation experiments. The PSf/ZIF-8/NH2 shows superior CO2/CH4 selectivity (88% increased) while sacrificing CO2 permeance due to combination of severe polymer chain rigidification and the presence of CO2-philic group, amine. Whereas, the PSf/ZIF-8/GO possess 64% increase in CO2 permeance without notable changes in CO2/CH4 selectivity.

  10. Computational Screening of MOF-Based Mixed Matrix Membranes for CO2/N2 Separations

    Directory of Open Access Journals (Sweden)

    Zeynep Sumer

    2016-01-01

    Full Text Available Atomically detailed simulations were used to examine CO2/N2 separation potential of metal organic framework- (MOF- based mixed matrix membranes (MMMs in this study. Gas permeability and selectivity of 700 new MMMs composed of 70 different MOFs and 10 different polymers were calculated for CO2/N2 separation. This is the largest number of MOF-based MMMs for which computational screening is done to date. Selecting the appropriate MOFs as filler particles in polymers resulted in MMMs that have higher CO2/N2 selectivities and higher CO2 permeabilities compared to pure polymer membranes. We showed that, for polymers that have low CO2 permeabilities but high CO2 selectivities, the identity of the MOF used as filler is not important. All MOFs enhanced the CO2 permeabilities of this type of polymers without changing their selectivities. Several MOF-based MMMs were identified to exceed the upper bound established for polymers. The methods we introduced in this study will create many opportunities to select the MOF/polymer combinations with useful properties for CO2 separation applications.

  11. Mixed Matrix Membranes for O2/N2 Separation: The Influence of Temperature

    Directory of Open Access Journals (Sweden)

    Ana Fernández-Barquín

    2016-05-01

    Full Text Available In this work, mixed matrix membranes (MMMs composed of small-pore zeolites with various topologies (CHA (Si/Al = 5, LTA (Si/Al = 1 and 5, and Rho (Si/Al = 5 as dispersed phase, and the hugely permeable poly(1-trimethylsilyl-1-propyne (PTMSP as continuous phase, have been synthesized via solution casting, in order to obtain membranes that could be attractive for oxygen-enriched air production. The O2/N2 gas separation performance of the MMMs has been analyzed in terms of permeability, diffusivity, and solubility in the temperature range of 298–333 K. The higher the temperature of the oxygen-enriched stream, the lower the energy required for the combustion process. The effect of temperature on the gas permeability, diffusivity, and solubility of these MMMs is described in terms of the Arrhenius and Van’t Hoff relationships with acceptable accuracy. Moreover, the O2/N2 permselectivity of the MMMs increases with temperature, the O2/N2 selectivities being considerably higher than those of the pure PTMSP. In consequence, most of the MMMs prepared in this work exceeded the Robeson’s upper bound for the O2/N2 gas pair in the temperature range under study, with not much decrease in the O2 permeabilities, reaching O2/N2 selectivities of up to 8.43 and O2 permeabilities up to 4,800 Barrer at 333 K.

  12. High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations

    KAUST Repository

    Zhang, Chen

    2012-02-01

    We report significantly enhanced propylene/propane (C 3H 6/C 3H 8) selectivity in mixed matrix membranes fabricated using 6FDA-DAM polyimide and a zeolitic imidazolate framework (ZIF-8). Equilibrium isotherms and sorption kinetics of C 3H 6 and C 3H 8 at 35°C were studied on a 200nm commercially available ZIF-8 sample produced by BASF. Mixed matrix dense films were formed with 6FDA-DAM and 200nm BASF ZIF-8 particles. SEM imaging showed generally good adhesion between the ZIF-8 and 6FDA-DAM without the need for surface-treating ZIF-8. Pure gas permeation showed significantly enhanced mixed matrix ZIF-8/6FDA-DAM membrane C 3H 6/C 3H 8 separation performance over the pure 6FDA-DAM membrane performance. A C 3H 6 permeability of 56.2Barrer and C 3H 6/C 3H 8 ideal selectivity of 31.0 was found in ZIF-8/6FDA-DAM mixed matrix membrane with 48.0wt% ZIF-8 loading, which are 258% and 150% higher than the pure 6FDA-DAM membrane, respectively for permeability and selectivity. Permeation properties of C 3H 6 and C 3H 8 in ZIF-8 were back-calculated by the Maxwell model for composite permeability using pure gas permeation data, leading to a C 3H 6 permeability of 277Barrer and C 3H 6/C 3H 8 selectivity of 122. Mixed gas permeation also verified that selectivity enhancements were achievable in mixed gas environment by ZIF-8. © 2011 Elsevier B.V.

  13. Metal-organic frameworks in mixed-matrix membranes for gas separation.

    Science.gov (United States)

    Tanh Jeazet, Harold B; Staudt, Claudia; Janiak, Christoph

    2012-12-14

    Mixed-matrix membranes (MMMs) with metal-organic frameworks (MOFs) as additives (fillers) exhibit enhanced gas permeabilities and possibly also selectivities when compared to the pure polymer. Polyimides (Matrimid®) and polysulfones are popular polymer matrices for MOF fillers. Presently investigated MOFs for MMMs include [Cu(SiF(6))(4,4'-BIPY)(2)], [Cu(3)(BTC)(2)(H(2)O)(3)] (HKUST-1, Cu-BTC), [Cu(BDC)(DMF)], [Zn(4)O(BDC)(3)] (MOF-5), [Zn(2-methylimidazolate)(2)] (ZIF-8), [Zn(purinate)(2)] (ZIF-20), [Zn(2-carboxyaldehyde imidazolate)(2)] (ZIF-90), Mn(HCOO)(2), [Al(BDC)(μ-OH)] (MIL-53(Al)), [Al(NH(2)-BDC)(μ-OH)] (NH(2)-MIL-53(Al)) and [Cr(3)O(BDC)(3)(F,OH)(H(2)O)(2)] (MIL-101) (4,4'-BIPY = 4,4'-bipyridine, BTC = benzene-1,3,5-tricarboxylate, BDC = benzene-1,4-dicarboxylate, terephthalate). MOF particle adhesion to polyimide and polysulfone organic polymers does not represent a problem. MOF-polymer MMMs are investigated for the permeability of the single gases H(2), N(2), O(2), CH(4), CO(2) and of the gas mixtures O(2)/N(2), H(2)/CH(4), CO(2)/CH(4), H(2)/CO(2), CH(4)/N(2) and CO(2)/N(2) (preferentially permeating gas named first). Permeability increases can be traced to the MOF porosity. Since the porosity of MOFs can be tuned very precisely, which is not possible with polymeric material, MMMs offer the opportunity of significantly increasing the selectivity compared to the pure polymeric matrix. Additionally in most of the cases the permeability is increased for MMM membranes compared to the pure polymer. Addition of MOFs to polymers in MMMs easily yields performances similar to the best polymer membranes and gives higher selectivities than those reported to date for any pure MOF membrane for the same gas separation. MOF-polymer MMMs allow for easier synthesis and handability compared to pure MOF membranes.

  14. The singular seesaw mechanism with hierarchical Dirac neutrino mass

    International Nuclear Information System (INIS)

    Chikira, Y.; Mimura, Y.

    2000-01-01

    The singular seesaw mechanism can naturally explain the atmospheric neutrino deficit by maximal oscillations between ν μ L and ν μ R . This mechanism can also induce three different scales of the neutrino mass squared differences, which can explain the neutrino deficits of three independent experiments (solar, atmospheric, and LSND) by neutrino oscillations. In this paper we show that realistic mixing angles among the neutrinos can be obtained by introducing a hierarchy in the Dirac neutrino mass. In the case where the Majorana neutrino mass matrix has rank 2, the solar neutrino deficit is explained by vacuum oscillations between ν e and ν τ . We also consider the case where the Majorana neutrino mass matrix has rank 1. In this case, the matter enhanced Mikheyev-Smirnov-Wolfenstein solar neutrino solution is preferred as the solution of the solar neutrino deficit. (orig.)

  15. Integrated Water Gas Shift Membrane Reactors Utilizing Novel, Non Precious Metal Mixed Matrix Membrane

    Energy Technology Data Exchange (ETDEWEB)

    Ferraris, John P. [Univ. of Texas-Dallas, Richardson, TX (United States). Dept. of Chemistry

    2013-09-30

    Nanoparticles of zeolitic imidazolate frameworks and other related hybrid materials were prepared by modifying published synthesis procedures by introducing bases, changing stoichiometric ratios, or adjusting reaction conditions. These materials were stable at temperatures >300 °C and were compatible with the polymer matrices used to prepare mixed- matrix membranes (MMMs). MMMs tested at 300 °C exhibited a >30 fold increase in permeability, compared to those measured at 35 °C, while maintaining H2/CO2 selectivity. Measurements at high pressure (up to 30 atm) and high temperature (up to 300 °C) resulted in an increase in gas flux across the membrane with retention of selectivity. No variations in permeability were observed at high pressures at either 35 or 300 °C. CO2-induced plasticization was not observed for Matrimid®, VTEC, and PBI polymers or their MMMs at 30 atm and 300 °C. Membrane surface modification by cross-linking with ethanol diamine resulted in an increase in H2/CO2 selectivity at 35 °C. Spectrometric analysis showed that the cross-linking was effective to temperatures <150 °C. At higher temperatures, the cross-linked membranes exhibit a H2/CO2 selectivity similar to the uncross-linked polymer. Performance of the polybenzimidazole (PBI) hollow fibers prepared at Santa Fe Science and Technology (SFST, Inc.) showed increased flux and selectivity at 300 °C, which is comparable to a flat PBI membrane. A water-gas shift reactor has been built and currently being optimized for testing under DOE conditions.

  16. Mixed lineage kinase 3 is required for matrix metalloproteinase expression and invasion in ovarian cancer cells

    International Nuclear Information System (INIS)

    Zhan, Yu; Abi Saab, Widian F.; Modi, Nidhi; Stewart, Amanda M.; Liu, Jinsong; Chadee, Deborah N.

    2012-01-01

    Mixed lineage kinase 3 (MLK3) is a mitogen-activated protein kinase kinase kinase (MAP3K) that activates MAPK signaling pathways and regulates cellular responses such as proliferation, migration and apoptosis. Here we report high levels of total and phospho-MLK3 in ovarian cancer cell lines in comparison to immortalized nontumorigenic ovarian epithelial cell lines. Using small interfering RNA (siRNA)-mediated gene silencing, we determined that MLK3 is required for the invasion of SKOV3 and HEY1B ovarian cancer cells. Furthermore, mlk3 silencing substantially reduced matrix metalloproteinase (MMP)-1, -2, -9 and -12 gene expression and MMP-2 and -9 activities in SKOV3 and HEY1B ovarian cancer cells. MMP-1, -2, -9 and-12 expression, and MLK3-induced activation of MMP-2 and MMP-9 requires both extracellular signal-regulated kinase (ERK) and c-Jun N-terminal kinase (JNK) activities. In addition, inhibition of activator protein-1 (AP-1) reduced MMP-1, MMP-9 and MMP-12 gene expression. Collectively, these findings establish MLK3 as an important regulator of MMP expression and invasion in ovarian cancer cells. -- Highlights: ► Ovarian cancer cell lines have high levels of total and phosphorylated MLK3. ► MLK3 is required for MMP expression and activity in ovarian cancer cells. ► MLK3 is required for invasion of SKOV3 and HEY1B ovarian cancer cells. ► MLK3-dependent regulation of MMP-2 and MMP-9 activities requires ERK and JNK.

  17. Sulfur removal from fuel using zeolites/polyimide mixed matrix membrane adsorbents

    International Nuclear Information System (INIS)

    Lin, Ligang; Wang, Andong; Dong, Meimei; Zhang, Yuzhong; He, Benqiao; Li, Hong

    2012-01-01

    Graphical abstract: Membrane adsorption process is proposed for sulfur removal. Three-dimensional network structure is key to fulfill adsorption function of MMMs, which adsorption/desorption behavior is markedly related with binding force with sulfur molecules. Highlights: ► Membrane adsorption process is proposed for sulfur removal. ► Three-dimensional network structure of MMMs is key to fulfill adsorption function. ► Adsorption/desorption behavior is markedly related with binding force. - Abstract: A novel membrane adsorption process was proposed for the sulfur removal from fuels. The mixed matrix membranes (MMMs) adsorbents composed of polyimide (PI) and various Y zeolites were prepared. By the detailed characterization of FT-IR, morphology, thermal and mechanical properties of MMMs adsorbents, combining the adsorption and desorption behavior research, the process–structure–function relationship was discussed. Field-emission scanning electron microscope (FESEM) images show that the functional particles are incorporated into the three-dimensional network structure. MMMs adsorbents with 40% of zeolites content possess better physical properties, which was confirmed by mechanical strength and thermo stability analysis. Influence factors including post-treatment, content of incorporated zeolites, adsorption time, temperature, initial sulfur concentration as well as sulfur species on the adsorption performance of MMMs adsorbents have been evaluated. At 4 wt.% zeolites content, adsorption capacity for NaY/PI, AgY/PI and CeY/PI MMMs adsorbents come to 2.0, 7.5 and 7.9 mg S/g, respectively. And the regeneration results suggest that the corresponding spent membranes can recover about 98%, 90% and 70% of the desulfurization capacity, respectively. The distinct adsorption and desorption behavior of MMMs adsorbents with various functional zeolites was markedly related with their various binding force and binding mode with sulfur compounds.

  18. Stable computation of generalized singular values

    Energy Technology Data Exchange (ETDEWEB)

    Drmac, Z.; Jessup, E.R. [Univ. of Colorado, Boulder, CO (United States)

    1996-12-31

    We study floating-point computation of the generalized singular value decomposition (GSVD) of a general matrix pair (A, B), where A and B are real matrices with the same numbers of columns. The GSVD is a powerful analytical and computational tool. For instance, the GSVD is an implicit way to solve the generalized symmetric eigenvalue problem Kx = {lambda}Mx, where K = A{sup {tau}}A and M = B{sup {tau}}B. Our goal is to develop stable numerical algorithms for the GSVD that are capable of computing the singular value approximations with the high relative accuracy that the perturbation theory says is possible. We assume that the singular values are well-determined by the data, i.e., that small relative perturbations {delta}A and {delta}B (pointwise rounding errors, for example) cause in each singular value {sigma} of (A, B) only a small relative perturbation {vert_bar}{delta}{sigma}{vert_bar}/{sigma}.

  19. Development and characterization of polyethersulfone/TiO2 mixed matrix membranes for CO2/CH4 separation

    Science.gov (United States)

    Galaleldin, S.; Mannan, H. A.; Mukhtar, H.

    2017-12-01

    In this study, mixed matrix membranes comprised of polyethersulfone as the bulk polymer phase and titanium dioxide (TiO2) nanoparticles as the inorganic discontinuous phase were prepared for CO2/CH4 separation. Membranes were synthesized at filler loading of 0, 5, 10 and 15 wt % via dry phase inversion method. Morphology, chemical bonding and thermal characteristics of membranes were scrutinized utilizing different techniques, namely: Field Emission Scanning Electron Microscopy (FESEM), Fourier Transform InfraRed (FTIR) spectra and Thermogravimetric analysis (TGA) respectively. Membranes gas separation performance was evaluated for CO2 and CH4 gases at 4 bar feed pressure. The highest separation performance was achieved by mixed matrix membrane (MMM) at 5 % loading of TiO2.

  20. Colloidal Gold Nanoclusters Spiked Silica Fillers in Mixed Matrix Coatings: Simultaneous Detection and Inhibition of Healthcare-Associated Infections.

    Science.gov (United States)

    Alsaiari, Shahad K; Hammami, Mohammed A; Croissant, Jonas G; Omar, Haneen W; Neelakanda, Pradeep; Yapici, Tahir; Peinemann, Klaus-Viktor; Khashab, Niveen M

    2017-03-01

    Healthcare-associated infections (HAIs) are the infections that patients get while receiving medical treatment in a medical facility with bacterial HAIs being the most common. Silver and gold nanoparticles (NPs) have been successfully employed as antibacterial motifs; however, NPs leaching in addition to poor dispersion and overall reproducibility are major hurdles to further product development. In this study, the authors design and fabricate a smart antibacterial mixed-matrix membrane coating comprising colloidal lysozyme-templated gold nanoclusters as nanofillers in poly(ethylene oxide)/poly(butylene terephthalate) amphiphilic polymer matrix. Mesoporous silica nanoparticles-lysozyme functionalized gold nanoclusters disperse homogenously within the polymer matrix with no phase separation and zero NPs leaching. This mixed-matrix coating can successfully sense and inhibit bacterial contamination via a controlled release mechanism that is only triggered by bacteria. The system is coated on a common radiographic dental imaging device (photostimulable phosphor plate) that is prone to oral bacteria contamination. Variation and eventually disappearance of the red fluorescence surface under UV light signals bacterial infection. Kanamycin, an antimicrobial agent, is controllably released to instantly inhibit bacterial growth. Interestingly, the quality of the images obtained with these coated surfaces is the same as uncoated surfaces and thus the safe application of such smart coatings can be expanded to include other medical devices without compromising their utility. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  1. Colloidal Gold Nanoclusters Spiked Silica Fillers in Mixed Matrix Coatings: Simultaneous Detection and Inhibition of Healthcare-Associated Infections

    KAUST Repository

    Alsaiari, Shahad K.

    2017-01-25

    Healthcare-associated infections (HAIs) are the infections that patients get while receiving medical treatment in a medical facility with bacterial HAIs being the most common. Silver and gold nanoparticles (NPs) have been successfully employed as antibacterial motifs; however, NPs leaching in addition to poor dispersion and overall reproducibility are major hurdles to further product development. In this study, the authors design and fabricate a smart antibacterial mixed-matrix membrane coating comprising colloidal lysozyme-templated gold nanoclusters as nanofillers in poly(ethylene oxide)/poly(butylene terephthalate) amphiphilic polymer matrix. Mesoporous silica nanoparticles-lysozyme functionalized gold nanoclusters disperse homogenously within the polymer matrix with no phase separation and zero NPs leaching. This mixed-matrix coating can successfully sense and inhibit bacterial contamination via a controlled release mechanism that is only triggered by bacteria. The system is coated on a common radiographic dental imaging device (photostimulable phosphor plate) that is prone to oral bacteria contamination. Variation and eventually disappearance of the red fluorescence surface under UV light signals bacterial infection. Kanamycin, an antimicrobial agent, is controllably released to instantly inhibit bacterial growth. Interestingly, the quality of the images obtained with these coated surfaces is the same as uncoated surfaces and thus the safe application of such smart coatings can be expanded to include other medical devices without compromising their utility.

  2. Preparation of mixed matrix PES-based nanofiltration membrane filled with PANI-co-MWCNT composite nanoparticles

    International Nuclear Information System (INIS)

    Bagheripour, Ehsan; Moghadassi, Abdolreza; Hosseini, Sayed Mohsen

    2016-01-01

    Mixed matrix polyethersulfone/PANI-co-MWCNTs composite nanoparticle nanofiltration membrane was prepared by casting solution technique. Polyvinylpyrrolidone was also used as membrane pore former in membrane fabrication. The effect of polyaniline-co-multi walled carbon nanotubes composite nanoparticle concentration in the casting solution on membrane structure and performance was investigated. Scanning optical microscopy and scanning electron microscopy, FTIR analysis, porosity, mean pore size, contact angle, water content, NaCl/Na2SO4 rejection, water flux, tensile strength measurements and 3D surface image were also carried out in membrane characterization. SOM images showed nanoparticle agglomeration at high additive loading ratio. SEM images showed the membrane sub-layer porosity and thickness were changed by use of nanoparticles in membrane matrix. The membrane water content, porosity and pore size were increased by increase of nanoparticle concentration, except for 1%wt. Use of PANI-co- MWCNT nanoparticles in the membrane matrix caused a decrease of membrane contact angle from 63.43 to 46.76o. Salt rejection and water flux were improved initially by increase of nanoparticle concentration up to 0.1%wt and then decreased by more additive concentration. In addition, the membranes tensile strength was reduced by increase of PANI-co-MWCNTs composite nanoparticle concentration. 3D surface images showed a smoother surface for mixed matrix membrane filled with 0.1wt% PANI-co-MWCNTs. Modified membrane containing 0.1wt% composite nanoparticles showed better performance compared to others.

  3. Enhanced selectivity in mixed matrix membranes for CO2 capture through efficient dispersion of amine-functionalized MOF nanoparticles

    Science.gov (United States)

    Ghalei, Behnam; Sakurai, Kento; Kinoshita, Yosuke; Wakimoto, Kazuki; Isfahani, Ali Pournaghshband; Song, Qilei; Doitomi, Kazuki; Furukawa, Shuhei; Hirao, Hajime; Kusuda, Hiromu; Kitagawa, Susumu; Sivaniah, Easan

    2017-07-01

    Mixed matrix membranes (MMMs) for gas separation applications have enhanced selectivity when compared with the pure polymer matrix, but are commonly reported with low intrinsic permeability, which has major cost implications for implementation of membrane technologies in large-scale carbon capture projects. High-permeability polymers rarely generate sufficient selectivity for energy-efficient CO2 capture. Here we report substantial selectivity enhancements within high-permeability polymers as a result of the efficient dispersion of amine-functionalized, nanosized metal-organic framework (MOF) additives. The enhancement effects under optimal mixing conditions occur with minimal loss in overall permeability. Nanosizing of the MOF enhances its dispersion within the polymer matrix to minimize non-selective microvoid formation around the particles. Amination of such MOFs increases their interaction with thepolymer matrix, resulting in a measured rigidification and enhanced selectivity of the overall composite. The optimal MOF MMM performance was verified in three different polymer systems, and also over pressure and temperature ranges suitable for carbon capture.

  4. Preparation of mixed matrix PES-based nanofiltration membrane filled with PANI-co-MWCNT composite nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Bagheripour, Ehsan; Moghadassi, Abdolreza; Hosseini, Sayed Mohsen [Faculty of Engineering, Arak University, Arak (Iran, Islamic Republic of)

    2016-04-15

    Mixed matrix polyethersulfone/PANI-co-MWCNTs composite nanoparticle nanofiltration membrane was prepared by casting solution technique. Polyvinylpyrrolidone was also used as membrane pore former in membrane fabrication. The effect of polyaniline-co-multi walled carbon nanotubes composite nanoparticle concentration in the casting solution on membrane structure and performance was investigated. Scanning optical microscopy and scanning electron microscopy, FTIR analysis, porosity, mean pore size, contact angle, water content, NaCl/Na2SO4 rejection, water flux, tensile strength measurements and 3D surface image were also carried out in membrane characterization. SOM images showed nanoparticle agglomeration at high additive loading ratio. SEM images showed the membrane sub-layer porosity and thickness were changed by use of nanoparticles in membrane matrix. The membrane water content, porosity and pore size were increased by increase of nanoparticle concentration, except for 1%wt. Use of PANI-co- MWCNT nanoparticles in the membrane matrix caused a decrease of membrane contact angle from 63.43 to 46.76o. Salt rejection and water flux were improved initially by increase of nanoparticle concentration up to 0.1%wt and then decreased by more additive concentration. In addition, the membranes tensile strength was reduced by increase of PANI-co-MWCNTs composite nanoparticle concentration. 3D surface images showed a smoother surface for mixed matrix membrane filled with 0.1wt% PANI-co-MWCNTs. Modified membrane containing 0.1wt% composite nanoparticles showed better performance compared to others.

  5. Structure and Transport Properties of Mixed-Matrix Membranes Based on Polyimides with ZrO2 Nanostars

    Directory of Open Access Journals (Sweden)

    Maria P. Sokolova

    2016-11-01

    Full Text Available Mixed-matrix membranes based on amorphous and semi-crystalline polyimides with zirconium dioxide (ZrO2 nanostars were synthesized. Amorphous poly(4,4′-oxydiphenylenepyromellitimide and semi-crystalline polyimide prepared from 1,4-bis(4-aminophenoxybenzene and 4,4’-oxydiphthalic anhydride were used. The effect of ZrO2 nanostars on the structure and morphology of nanocomposite membranes was studied by wide-angle X-ray scattering, scanning electron microscopy, atomic force microscopy, and contact angle measurements. Thermal properties and stability were investigated by thermogravimetric analysis and differential scanning calorimetry. Transport properties of hybrid membranes containing 5 wt % ZrO2 were tested for pervaporation of a mixture of butanol–water with 10 wt % H2O content. It was found that a significant amount of the ZrO2 added to the semi-crystalline polyimide is encapsulated inside spherulites. Therefore, the beneficial influence of inorganic filler on the selectivity of mixed-matrix membrane with respect to water was hampered. Mixed-matrix membranes based on amorphous polymer demonstrated the best performance, because water molecules had higher access to inorganic particles.

  6. Geodesic fields with singularities

    International Nuclear Information System (INIS)

    Kafker, A.H.

    1979-01-01

    The question considered is whether or not a Riemannian metric can be found to make a given curve field on a closed surface into geodesics. Allowing singularities removes the restriction to Euler characteristic zero. The main results are the following: only two types of isolated singularities can occur in a geodesic field on a surface. No geodsic fields exist on a surface with Euler characteristic less than zero. If the Euler characteristic is zero, such a geodesic field can have only removable singularities. Only a limited number of geodesic fields exist on S 2 and RP 2 . A closed geodesic (perhaps made from several curves and singularities) always appears in such a field

  7. The Exopolysaccharide Matrix Modulates the Interaction between 3D Architecture and Virulence of a Mixed-Species Oral Biofilm

    Science.gov (United States)

    Xiao, Jin; Klein, Marlise I.; Falsetta, Megan L.; Lu, Bingwen; Delahunty, Claire M.; Yates, John R.; Heydorn, Arne; Koo, Hyun

    2012-01-01

    Virulent biofilms are responsible for a range of infections, including oral diseases. All biofilms harbor a microbial-derived extracellular-matrix. The exopolysaccharides (EPS) formed on tooth-pellicle and bacterial surfaces provide binding sites for microorganisms; eventually the accumulated EPS enmeshes microbial cells. The metabolic activity of the bacteria within this matrix leads to acidification of the milieu. We explored the mechanisms through which the Streptococcus mutans-produced EPS-matrix modulates the three-dimensional (3D) architecture and the population shifts during morphogenesis of biofilms on a saliva-coated-apatitic surface using a mixed-bacterial species system. Concomitantly, we examined whether the matrix influences the development of pH-microenvironments within intact-biofilms using a novel 3D in situ pH-mapping technique. Data reveal that the production of the EPS-matrix helps to create spatial heterogeneities by forming an intricate network of exopolysaccharide-enmeshed bacterial-islets (microcolonies) through localized cell-to-matrix interactions. This complex 3D architecture creates compartmentalized acidic and EPS-rich microenvironments throughout the biofilm, which triggers the dominance of pathogenic S. mutans within a mixed-species system. The establishment of a 3D-matrix and EPS-enmeshed microcolonies were largely mediated by the S. mutans gtfB/gtfC genes, expression of which was enhanced in the presence of Actinomyces naeslundii and Streptococcus oralis. Acidic pockets were found only in the interiors of bacterial-islets that are protected by EPS, which impedes rapid neutralization by buffer (pH 7.0). As a result, regions of low pH (<5.5) were detected at specific locations along the surface of attachment. Resistance to chlorhexidine was enhanced in cells within EPS-microcolony complexes compared to those outside such structures within the biofilm. Our results illustrate the critical interaction between matrix architecture and p

  8. Mixed-Matrix Membranes containing an Azine-Linked Covalent Organic Framework: Influence of the polymeric matrix on Post-Combustion CO 2 -capture

    KAUST Repository

    Shan, Meixia

    2017-12-07

    The use of an azine-linked covalent organic framework (ACOF-1) as filler in mixed-matrix membranes (MMMs) has been studied for the separation of CO2 from N2. To better understand the mechanisms that govern separation in complex composites, MMMs were prepared with different loadings of ACOF-1 and three different polymers as continuous phase: low flux-mid selectivity Matrimid®, mid flux-high selectivity Polyactive™ and high flux-low selectivity 6FDA:DAM. The homogeneous distribution of ACOF-1 together with the good adhesion between the ACOF-1 particles and the polymer matrices were confirmed by scanning electron microscopy. In mixed-gas CO2/N2 separation a clear influence of the polymer used was observed on the performance of the composite membranes. While for Matrimid® and 6FDA:DAM an overall enhancement of the polymer\\'s separation properties could be achieved, in case of Polyactive™ penetration of the more flexible polymer into the COF porosity resulted in a decreased membrane permeability. The best improvement was obtained for Matrimid®-based MMMs, for which a selectivity increase from 29 to 35, together with an enhancement in permeability from 9.5 to 17.7 Barrer for 16wt% COF loading, was observed. Our results demonstrate that the combination of the filler-polymeric matrix pair chosen is crucial. For a given filler the polymer performance improvement strongly depends on the polymeric matrix selected, where a good match between the discontinuous and continuous phase, both in the terms of compatibility and gas separation properties, is necessary to optimize membrane performance.

  9. Crosslinkable mixed matrix membranes with surface modified molecular sieves for natural gas purification: II. Performance characterization under contaminated feed conditions

    KAUST Repository

    Ward, Jason K.

    2011-07-01

    Mixed matrix membranes (MMMs) composed of the crosslinkable polyimide PDMC and surface modified (SM) SSZ-13 have recently been shown to enhance carbon dioxide permeability and carbon dioxide/methane selectivity versus neat PDMC films by as much as 47% and 13%, respectively (Part I). The previous film characterization, however, was performed using ideal, clean mixed gas feeds. In this paper, PDMC/SSZ-13 MMMs are further characterized using more realistic mixed gases containing low concentrations (500 or 1000. ppm) of toluene as a model contaminant. Mixed matrix membranes are shown to outperform pure PDMC films in the presence of toluene with 43% greater carbon dioxide permeability and 12% greater carbon dioxide/selectivity at 35 °C and 700 psia feed pressure. These results suggest that MMMs-in addition to exhibiting enhanced transport properties-may mitigate performance degradation due to antiplasticization effects. Moreover, the analyses presented here show that the reduction in separation performance by trace contaminant-accelerated physical aging can be suppressed greatly with MMMs. © 2011 Elsevier B.V.

  10. Analytical development of disturbed matrix eigenvalue problem applied to mixed convection stability analysis in Darcy media

    Science.gov (United States)

    Hamed, Haikel Ben; Bennacer, Rachid

    2008-08-01

    This work consists in evaluating algebraically and numerically the influence of a disturbance on the spectral values of a diagonalizable matrix. Thus, two approaches will be possible; to use the theorem of disturbances of a matrix depending on a parameter, due to Lidskii and primarily based on the structure of Jordan of the no disturbed matrix. The second approach consists in factorizing the matrix system, and then carrying out a numerical calculation of the roots of the disturbances matrix characteristic polynomial. This problem can be a standard model in the equations of the continuous media mechanics. During this work, we chose to use the second approach and in order to illustrate the application, we choose the Rayleigh-Bénard problem in Darcy media, disturbed by a filtering through flow. The matrix form of the problem is calculated starting from a linear stability analysis by a finite elements method. We show that it is possible to break up the general phenomenon into other elementary ones described respectively by a disturbed matrix and a disturbance. A good agreement between the two methods was seen. To cite this article: H.B. Hamed, R. Bennacer, C. R. Mecanique 336 (2008).

  11. Polynomial computation of Hankel singular values

    NARCIS (Netherlands)

    Kwakernaak, H.

    1992-01-01

    A revised and improved version of a polynomial algorithm is presented. It was published by N.J. Young (1990) for the computation of the singular values and vectors of the Hankel operator defined by a linear time-invariant system with a rotational transfer matrix. Tentative numerical experiments

  12. Isotopy of Morin singularities

    OpenAIRE

    Saji, Kentaro

    2015-01-01

    We define an equivalence relation called A-isotopy between finitely determined map-germs, which is a strengthened version of A-equivalence. We consider the number of A-isotopy classes of equidimensional Morin singularities, and some other well-known low-dimensional singularities. We also give an application to stable perturbations of simple equi-dimensional map-germs.

  13. MATRIX (Multiconfiguration Aerosol TRacker of mIXing state: an aerosol microphysical module for global atmospheric models

    Directory of Open Access Journals (Sweden)

    S. E. Bauer

    2008-10-01

    Full Text Available A new aerosol microphysical module MATRIX, the Multiconfiguration Aerosol TRacker of mIXing state, and its application in the Goddard Institute for Space Studies (GISS climate model (ModelE are described. This module, which is based on the quadrature method of moments (QMOM, represents nucleation, condensation, coagulation, internal and external mixing, and cloud-drop activation and provides aerosol particle mass and number concentration and particle size information for up to 16 mixed-mode aerosol populations. Internal and external mixing among aerosol components sulfate, nitrate, ammonium, carbonaceous aerosols, dust and sea-salt particles are represented. The solubility of each aerosol population, which is explicitly calculated based on its soluble and insoluble components, enables calculation of the dependence of cloud drop activation on the microphysical characterization of multiple soluble aerosol populations.

    A detailed model description and results of box-model simulations of various aerosol population configurations are presented. The box model experiments demonstrate the dependence of cloud activating aerosol number concentration on the aerosol population configuration; comparisons to sectional models are quite favorable. MATRIX is incorporated into the GISS climate model and simulations are carried out primarily to assess its performance/efficiency for global-scale atmospheric model application. Simulation results were compared with aircraft and station measurements of aerosol mass and number concentration and particle size to assess the ability of the new method to yield data suitable for such comparison. The model accurately captures the observed size distributions in the Aitken and accumulation modes up to particle diameter 1 μm, in which sulfate, nitrate, black and organic carbon are predominantly located; however the model underestimates coarse-mode number concentration and size, especially in the marine environment

  14. MATRIX (Multiconfiguration Aerosol TRacker of mIXing state): an aerosol microphysical module for global atmospheric models

    Science.gov (United States)

    Bauer, S. E.; Wright, D. L.; Koch, D.; Lewis, E. R.; McGraw, R.; Chang, L.-S.; Schwartz, S. E.; Ruedy, R.

    2008-10-01

    A new aerosol microphysical module MATRIX, the Multiconfiguration Aerosol TRacker of mIXing state, and its application in the Goddard Institute for Space Studies (GISS) climate model (ModelE) are described. This module, which is based on the quadrature method of moments (QMOM), represents nucleation, condensation, coagulation, internal and external mixing, and cloud-drop activation and provides aerosol particle mass and number concentration and particle size information for up to 16 mixed-mode aerosol populations. Internal and external mixing among aerosol components sulfate, nitrate, ammonium, carbonaceous aerosols, dust and sea-salt particles are represented. The solubility of each aerosol population, which is explicitly calculated based on its soluble and insoluble components, enables calculation of the dependence of cloud drop activation on the microphysical characterization of multiple soluble aerosol populations. A detailed model description and results of box-model simulations of various aerosol population configurations are presented. The box model experiments demonstrate the dependence of cloud activating aerosol number concentration on the aerosol population configuration; comparisons to sectional models are quite favorable. MATRIX is incorporated into the GISS climate model and simulations are carried out primarily to assess its performance/efficiency for global-scale atmospheric model application. Simulation results were compared with aircraft and station measurements of aerosol mass and number concentration and particle size to assess the ability of the new method to yield data suitable for such comparison. The model accurately captures the observed size distributions in the Aitken and accumulation modes up to particle diameter 1 μm, in which sulfate, nitrate, black and organic carbon are predominantly located; however the model underestimates coarse-mode number concentration and size, especially in the marine environment. This is more likely due to

  15. Introduction to singularities

    CERN Document Server

    Ishii, Shihoko

    2014-01-01

    This book is an introduction to singularities for graduate students and researchers. It is said that algebraic geometry originated in the seventeenth century with the famous work Discours de la méthode pour bien conduire sa raison, et chercher la vérité dans les sciences by Descartes. In that book he introduced coordinates to the study of geometry. After its publication, research on algebraic varieties developed steadily. Many beautiful results emerged in mathematicians’ works. Most of them were about non-singular varieties. Singularities were considered “bad” objects that interfered with knowledge of the structure of an algebraic variety. In the past three decades, however, it has become clear that singularities are necessary for us to have a good description of the framework of varieties. For example, it is impossible to formulate minimal model theory for higher-dimensional cases without singularities. Another example is that the moduli spaces of varieties have natural compactification, the boundar...

  16. String theory and cosmological singularities

    Indian Academy of Sciences (India)

    time' can have a beginning or end. Well-known examples are singularities inside black holes and initial or final singularities in expanding or contracting universes. In recent times, string theory is providing new perspectives of such singularities ...

  17. Preparation of Ethylene Vinyl Acetate/Zeolite 4A Mixed Matrix Membrane for CO2/N2 Separation

    Directory of Open Access Journals (Sweden)

    Iman Khalilinejad

    2016-07-01

    Full Text Available A great contribution in research activities on carbon dioxide (CO2 separation, as the most important challenge in greenhouse gases control, has been made to develop new polymeric membranes. In this case, mixed matrix membranes (MMMs, comprised of rigid particles dispersed in a continuous polymeric matrix, was proposed as an effective method to improve the separation properties of polymeric membranes. In this research, ethylene vinyl acetate (EVA copolymer and zeolite 4A powders were applied to prepare MMMs using solution casting/solvent evaporation method and CO2/N2 separation performance of the membranes was examined under different feed pressures (3-8 bar and operating temperatures (25-50°C. Morphological and structural characterizations of the membranes were evaluated using scanning electron microscopy (SEM, Fourier transform infrared (FTIR spectroscopy, differential scanning calorimetry (DSC, thermogravimetric analysis (TGA, density and solvent-induced swelling measurements. The gas permeability measurements through the constant-volume method showed the permeability of two gases increased in the presence of zeolite 4A nanoparticles in the polymer matrix. Calculation of diffusivity coefficients of gases revealed that improvement in the diffusivity of all gases into membrane matrix was the main reason for permeability enhancement. In addition, the increase in the CO2/N2 ideal selectivity with the presence of zeolite 4A nanoparticles in the polymer matrix was attributed to the increment in CO2/N2 diffusion selectivity. Under optimum condition, with the addition of 10 wt% zeolite 4A nanoparticles into the membrane matrix, the CO2 permeability increased from 20.81 to 35.24 Barrer and its related selectivity increased 20% compared to that of neat EVA membrane. Furthermore, the membrane performances increased upon feed pressure rise, while the selectivity decreased with the increase in temperature.

  18. Calculating the permeability coefficients of mixed matrix membranes of polydimethylsiloxane and silicalite crystals to various ethanol-water solutions using molecular simulations.

    Science.gov (United States)

    The permeability coefficients of mixed matrix membranes of polydimethylsiloxane (PDMS) and silicalite crystal are taken as the sum of the permeability coefficients of membrane components each weighted by their associated mass fraction. The permeability coefficient of a membrane c...

  19. Effect of Cell-to-matrix Ratio in Polyvinyl Alcohol Immobilized Pure and Mixed Cultures on Atrazine Degradation

    International Nuclear Information System (INIS)

    Siripattanakul, Sumana; Wirojanagud, Wanpen; McEvoy, John; Khan, Eakalak

    2008-01-01

    Atrazine biodegradation by immobilized pure and mixed cultures was examined. A pure atrazine-degrading culture, Agrobacterium radiobacter J14a (J14a), and a mixed culture (MC), isolated from an atrazine-contaminated crop field, were immobilized using phosphorylated-polyvinyl alcohol (PPVA). An existing cell immobilization procedure was modified to enhance PPVA matrix stability. The results showed that the matrices remained mechanically and chemically stable after shaking with glass beads over 15 days under various salt solutions and pH values. The immobilization process had a slight effect on cell viability. With the aid of scanning electron microscopy, a suitable microstructure of PPVA matrices for cell entrapment was observed. There were two porous layers of spherical gel matrices, the outside having an encapsulation property and the inside containing numerous pores for bacteria to occupy. J14a and MC were immobilized at three cell-to-matrix ratios of 3.5, 6.7, and 20 mg dry cells/mL matrix. The atrazine biodegradation tests were conducted in an aerobic batch system, which was inoculated with cells at 2,000 mg/L. The tests were also conducted using free (non-immobilized) J14a and MC for comparative purpose. The cell-to-matrix ratio of 3.5 mg/mL provided the highest atrazine removal efficiency of 40-50% in 120 h for both J14a and MC. The free cell systems, for both cultures, presented much lower atrazine removal efficiencies compared to the immobilized cell systems at the same level of inoculation

  20. Matrix-Matched Iron-Oxide Laser Ablation ICP-MS U–Pb Geochronology Using Mixed Solution Standards

    Directory of Open Access Journals (Sweden)

    Liam Courtney-Davies

    2016-08-01

    Full Text Available U–Pb dating of the common iron-oxide hematite (α-Fe2O3, using laser-ablation inductively-coupled-plasma mass-spectrometry (LA-ICP-MS, provides unparalleled insight into the timing and processes of mineral deposit formation. Until now, the full potential of this method has been negatively impacted by the lack of suitable matrix-matched standards. To achieve matrix-matching, we report an approach in which a U–Pb solution and ablated material from 99.99% synthetic hematite are simultaneously mixed in a nebulizer chamber and introduced to the ICP-MS. The standard solution contains fixed U- and Pb-isotope ratios, calibrated independently, and aspiration of the isotopically homogeneous solution negates the need for a matrix-matched, isotopically homogenous natural iron-oxide standard. An additional advantage of using the solution is that the individual U–Pb concentrations and isotope ratios can be adjusted to approximate that in the unknown, making the method efficient for dating hematite containing low (~10 ppm to high (>1 wt % U concentrations. The above-mentioned advantage to this solution method results in reliable datasets, with arguably-better accuracy in measuring U–Pb ratios than using GJ-1 Zircon as the primary standard, which cannot be employed for such low U concentrations. Statistical overlaps between 207Pb/206Pb weighted average ages (using GJ-1 Zircon and U–Pb upper intercept ages (using the U–Pb mixed solution method of two samples from iron-oxide copper-gold (IOCG deposits in South Australia demonstrate that, although fractionation associated with a non-matrix matched standard does occur when using GJ-1 Zircon as the primary standard, it does not impact the 207Pb/206Pb or upper intercept age. Thus, GJ-1 Zircon can be considered reliable for dating hematite using LA-ICP-MS. Downhole fractionation of 206Pb/238U is observed to occur in spot analyses of hematite. The use of rasters in future studies will hopefully minimize

  1. Enzymatic conversion in ion-exchange mixed matrix hollow fiber membranes

    NARCIS (Netherlands)

    Andre, Joao; Borneman, Zandrie; Wessling, Matthias

    2013-01-01

    This work reports the adsorption of glucose oxidase (GOx) in particle-loaded hollow fibers using polyethersulfone as the matrix and Lewatit strong cation-exchange resins as the functional support. The activity of adsorbed GOx was evaluated under the same pH conditions as the adsorption. Static

  2. Mixed Analog/Digital Matrix-Vector Multiplier for Neural Network Synapses

    DEFF Research Database (Denmark)

    Lehmann, Torsten; Bruun, Erik; Dietrich, Casper

    1996-01-01

    In this work we present a hardware efficient matrix-vector multiplier architecture for artificial neural networks with digitally stored synapse strengths. We present a novel technique for manipulating bipolar inputs based on an analog two's complements method and an accurate current rectifier...

  3. MOF-mixed matrix membranes: Precise dispersion of MOF particles with better compatibility via a particle fusion approach for enhanced gas separation properties

    NARCIS (Netherlands)

    Shahid, S.; Nijmeijer, Dorothea C.; Nehache, Sabrina; Vankelecom, Ivo; Deratani, Andre; Quemener, Damien

    2015-01-01

    Mixed matrix membranes (MMMs) incorporating conventional fillers frequently suffer from insufficient adhesion between the polymer matrix and the fillers. This often results in the formation of non-selective voids at the filler/polymer interface, which decreases the performance of the membrane. A

  4. The Big Bang Singularity

    Science.gov (United States)

    Ling, Eric

    The big bang theory is a model of the universe which makes the striking prediction that the universe began a finite amount of time in the past at the so called "Big Bang singularity." We explore the physical and mathematical justification of this surprising result. After laying down the framework of the universe as a spacetime manifold, we combine physical observations with global symmetrical assumptions to deduce the FRW cosmological models which predict a big bang singularity. Next we prove a couple theorems due to Stephen Hawking which show that the big bang singularity exists even if one removes the global symmetrical assumptions. Lastly, we investigate the conditions one needs to impose on a spacetime if one wishes to avoid a singularity. The ideas and concepts used here to study spacetimes are similar to those used to study Riemannian manifolds, therefore we compare and contrast the two geometries throughout.

  5. Surface Plasmon Singularities

    Directory of Open Access Journals (Sweden)

    Gabriel Martínez-Niconoff

    2012-01-01

    Full Text Available With the purpose to compare the physical features of the electromagnetic field, we describe the synthesis of optical singularities propagating in the free space and on a metal surface. In both cases the electromagnetic field has a slit-shaped curve as a boundary condition, and the singularities correspond to a shock wave that is a consequence of the curvature of the slit curve. As prototypes, we generate singularities that correspond to fold and cusped regions. We show that singularities in free space may generate bifurcation effects while plasmon fields do not generate these kinds of effects. Experimental results for free-space propagation are presented and for surface plasmon fields, computer simulations are shown.

  6. Algorithms in Singular

    Directory of Open Access Journals (Sweden)

    Hans Schonemann

    1996-12-01

    Full Text Available Some algorithms for singularity theory and algebraic geometry The use of Grobner basis computations for treating systems of polynomial equations has become an important tool in many areas. This paper introduces of the concept of standard bases (a generalization of Grobner bases and the application to some problems from algebraic geometry. The examples are presented as SINGULAR commands. A general introduction to Grobner bases can be found in the textbook [CLO], an introduction to syzygies in [E] and [St1]. SINGULAR is a computer algebra system for computing information about singularities, for use in algebraic geometry. The basic algorithms in SINGULAR are several variants of a general standard basis algorithm for general monomial orderings (see [GG]. This includes wellorderings (Buchberger algorithm ([B1], [B2] and tangent cone orderings (Mora algorithm ([M1], [MPT] as special cases: It is able to work with non-homogeneous and homogeneous input and also to compute in the localization of the polynomial ring in 0. Recent versions include algorithms to factorize polynomials and a factorizing Grobner basis algorithm. For a complete description of SINGULAR see [Si].

  7. Estimation in a multiplicative mixed model involving a genetic relationship matrix

    Directory of Open Access Journals (Sweden)

    Eccleston John A

    2009-04-01

    Full Text Available Abstract Genetic models partitioning additive and non-additive genetic effects for populations tested in replicated multi-environment trials (METs in a plant breeding program have recently been presented in the literature. For these data, the variance model involves the direct product of a large numerator relationship matrix A, and a complex structure for the genotype by environment interaction effects, generally of a factor analytic (FA form. With MET data, we expect a high correlation in genotype rankings between environments, leading to non-positive definite covariance matrices. Estimation methods for reduced rank models have been derived for the FA formulation with independent genotypes, and we employ these estimation methods for the more complex case involving the numerator relationship matrix. We examine the performance of differing genetic models for MET data with an embedded pedigree structure, and consider the magnitude of the non-additive variance. The capacity of existing software packages to fit these complex models is largely due to the use of the sparse matrix methodology and the average information algorithm. Here, we present an extension to the standard formulation necessary for estimation with a factor analytic structure across multiple environments.

  8. On the direct synthesis of Cu(BDC) MOF nanosheets and their performance in mixed matrix membranes

    Energy Technology Data Exchange (ETDEWEB)

    Shete, Meera; Kumar, Prashant; Bachman, Jonathan E.; Ma, Xiaoli; Smith, Zachary P.; Xu, Wenqian; Mkhoyan, K. Andre; Long, Jeffrey R.; Tsapatsis, Michael

    2018-03-01

    High aspect-ratio nanosheets of metal-organic frameworks (MOFs) hold promise for use as selective flakes in gas separation membranes. However, simple and scalable methods for the synthesis of MOF nanosheets have thus far remained elusive. Here, we describe the direct synthesis of Cu(BDC) (BDC2-= 1,4-benzenedicarboxylate) nanosheets with an average lateral size of 2.5 mu m and a thickness of 25 nm from a well-mixed solution. Characterization of the nanosheets by powder and thin film X-ray diffraction, electron microscopy, and electron diffraction reveals pronounced structural disorder that may affect their pore structure. Incorporation of the Cu (BDC) nanosheets into a Matrimid polymer matrix results in mixed matrix membranes (MMMs) that exhibit a 70% increase in the CO2/CH4 selectivity compared with that of Matrimid. Analysis of new and previously reported permeation data for Cu(BDC) MMMs using a mathematical model for selective flake composites indicates that further performance improvements could be achieved with the selection of different polymers for use in the continuous phase.

  9. STRUCTURAL CHARACTERIZATION AND GAS PERMEATION PROPERTIES OF POLYETHERIMIDE (PEI/ZEOLITIC IMIDAZOLATE (ZIF-11 MIXED MATRIX MEMBRANES

    Directory of Open Access Journals (Sweden)

    Mehtap Şafak Boroğlu

    2016-06-01

    Full Text Available In this study, the preparation of polyetherimide (PEI-Ultem1000/ZIF-11 mixed matrix membranes was studied in various ZIF-11 nanoparticles loadings (0, 10, 15, 20, and 30 wt.%. The newly synthesized ZIF-11 nanoparticles with an average particle size of ~280 nm were integrated in PEI membranes as novel mixed matrix membranes (MMMs. The effect of ZIF-11 loading was scrutinised for H2, CO2, and CH4 gas separation performance at 35 °C and 4 bar. The incorporation of ZIF-11 nanoparticles improved the gas permeation properties of the MMMs with an increase in ZIF-11 loading. As the ZIF-11 loading increased up to 20 wt.%, the permeability of H2 and CO2 increased to four times higher than that of the pure polymer. Moderate increase of CH4 permeability was also recorded. At higher loadings above 20 wt.%, the permeability decreased for all gases and the CO2/CH4, and H2/CH4 selectivities increased consistent with the ZIF-11 loading.

  10. Holographic subregion complexity for singular surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Bakhshaei, Elaheh [Isfahan University of Technology, Department of Physics, Isfahan (Iran, Islamic Republic of); Mollabashi, Ali [Institute for Research in Fundamental Sciences (IPM), School of Physics, Tehran (Iran, Islamic Republic of); Shirzad, Ahmad [Isfahan University of Technology, Department of Physics, Isfahan (Iran, Islamic Republic of); Institute for Research in Fundamental Sciences (IPM), School of Particles and Accelerators, Tehran (Iran, Islamic Republic of)

    2017-10-15

    Recently holographic prescriptions were proposed to compute the quantum complexity of a given state in the boundary theory. A specific proposal known as 'holographic subregion complexity' is supposed to calculate the complexity of a reduced density matrix corresponding to a static subregion. We study different families of singular subregions in the dual field theory and find the divergence structure and universal terms of holographic subregion complexity for these singular surfaces. We find that there are new universal terms, logarithmic in the UV cut-off, due to the singularities of a family of surfaces including a kink in (2 + 1) dimensions and cones in even dimensional field theories. We also find examples of new divergent terms such as squared logarithm and negative powers times the logarithm of the UV cut-off parameter. (orig.)

  11. Numerical Approaches to Spacetime Singularities

    Directory of Open Access Journals (Sweden)

    Beverly K. Berger

    1998-05-01

    Full Text Available This review updates a previous review article. Numerical explorationof the properties of singularities could, in principle, yield detailed understanding of their nature in physically realistic cases. Examples of numerical investigations into the formation of naked singularities, critical behavior in collapse, passage through the Cauchy horizon, chaos of the Mixmaster singularity, and singularities in spatially inhomogeneous cosmologies are discussed.

  12. Improved Interfacial Affinity and CO2 Separation Performance of Asymmetric Mixed Matrix Membranes by Incorporating Postmodified MIL-53(Al).

    Science.gov (United States)

    Zhu, Haitao; Wang, Lina; Jie, Xingming; Liu, Dandan; Cao, Yiming

    2016-08-31

    Asymmetric mixed matrix membranes(MMMs) with MOFs hold great application potential for energy-efficient gas separations. However, the particle aggregation and nonselective interfacial microvoids restrict the gas separation performance of asymmetric MMMs. Herein, nanoporous metal-organic framework (MOF) of MIL-53(Al) was modified with aminosilane after solvothermal synthesis. The postfunctionalization by grafting alkyl chains can form hydrogen bonds with polymer chains to enhance the affinity with polymer matrix and facilitate the preferential adsorption of CO2 by dipole-quadrupole interaction with the functional group. Then the postmodified MIL-53(Al) was incorporated as filler into poly(ether imide) Ultem1000 to fabricate high-quality asymmetric MMMs with well dispersed particles in polymer matrix and good adhesion at the MOFs-polymer interface. The Ultem/S-MIL-53(Al) asymmetric MMMs exhibited remarkable combinations of gas permeance and ideal selectivity for CO2/N2 separation at 10 wt % filler loading. The CO2 permeance achieved 24.1 GPU, an increase of 165% compared with pure Ultem membrane. Meanwhile, the ideal CO2/N2 selectivity also increased from 31.0 up to 41.1. The strategy of post covalent modification for MOFs provides an effective way to improve the interfacial affinity and gas separation performance.

  13. Permeability and Selectivity of PPO/Graphene Composites as Mixed Matrix Membranes for CO2 Capture and Gas Separation

    Directory of Open Access Journals (Sweden)

    Riccardo Rea

    2018-01-01

    Full Text Available We fabricated novel composite (mixed matrix membranes based on a permeable glassy polymer, Poly(2,6-dimethyl-1,4-phenylene oxide (PPO, and variable loadings of few-layer graphene, to test their potential in gas separation and CO2 capture applications. The permeability, selectivity and diffusivity of different gases as a function of graphene loading, from 0.3 to 15 wt %, was measured at 35 and 65 °C. Samples with small loadings of graphene show a higher permeability and He/CO2 selectivity than pure PPO, due to a favorable effect of the nanofillers on the polymer morphology. Higher amounts of graphene lower the permeability of the polymer, due to the prevailing effect of increased tortuosity of the gas molecules in the membrane. Graphene also allows dramatically reducing the increase of permeability with temperature, acting as a “stabilizer” for the polymer matrix. Such effect reduces the temperature-induced loss of size-selectivity for He/N2 and CO2/N2, and enhances the temperature-induced increase of selectivity for He/CO2. The study confirms that, as observed in the case of other graphene-based mixed matrix glassy membranes, the optimal concentration of graphene in the polymer is below 1 wt %. Below such threshold, the morphology of the nanoscopic filler added in solution affects positively the glassy chains packing, enhancing permeability and selectivity, and improving the selectivity of the membrane at increasing temperatures. These results suggest that small additions of graphene to polymers can enhance their permselectivity and stabilize their properties.

  14. Preparation of a mixed-matrix hydrogel of vorinostat for topical administration on the rats as experimental model.

    Science.gov (United States)

    Dai, Wenwen; Wang, Chenhui; Yu, Changhui; Yao, Ju; Sun, Fengying; Teng, Lesheng; Li, Youxin

    2015-10-12

    Oral vorinostat has the remarkable curative effect on aggravated and recurrent cutaneous T-cell lymphoma (CTCL), but is accompanied by serious adverse effects. Therefore, oral vorinostat is not applicable to the treatment of early stage CTCL. The aim of this study is to develop a novel vorinostat formulation which is effective for early stage CTCL and free of the serious adverse effects. A mixed-matrix hydrogel of vorinostat was prepared and characterized as a potential topical skin delivery system. Moisture retention, swelling behavior, viscosity, real-time morphology and differential scanning calorimeter analysis (DSC) of hydrogel were evaluated to select the solvent, matrix and humectant. The optimal HPMC/HPC ratio, pH, additive, dose and drug loading of vorinostat hydrogel were determined by evaluating the cumulative vorinostat amount of skin retention and transdermal amount of vorinostat through the skin in vitro. The optimal hydrogel presented a low transdermal amount of vorinostat through the skin, suggesting that the hydrogel reduced the amount of vorinostat that was absorbed in the systemic circulation. More importantly, in vivo percutaneous permeation experiments were also performed to evaluate the permeation behavior of vorinostat into the skin. The topical application with a much lower dose showed higher AUC (the cumulative vorinostat amount of skin retention) than oral application and the hydrogel achieved a sustained permeation of vorinostat in the skin for 24h in vivo. It indicated that a higher relative bioavailability for hydrogel was achieved compared with oral vorinostat. Moreover, there was no damage, inflammation or cell swelling of the skin after administration. Thus, the mixed-matrix vorinostat hydrogel prepared in this study could deliver vorinostat into local skin more efficiently than oral administration. Copyright © 2015 Elsevier B.V. All rights reserved.

  15. Reconstructing the microstructure of polyimide-silicalite mixed-matrix membranes and their particle connectivity using FIB-SEM tomography.

    Science.gov (United States)

    Diblíková, P; Veselý, M; Sysel, P; Čapek, P

    2018-03-01

    Properties of a composite material made of a continuous matrix and particles often depend on microscopic details, such as contacts between particles. Focusing on processing raw focused-ion beam scanning electron microscope (FIB-SEM) tomography data, we reconstructed three mixed-matrix membrane samples made of 6FDA-ODA polyimide and silicalite-1 particles. In the first step of image processing, backscattered electron (BSE) and secondary electron (SE) signals were mixed in a ratio that was expected to obtain a segmented 3D image with a realistic volume fraction of silicalite-1. Second, after spatial alignment of the stacked FIB-SEM data, the 3D image was smoothed using adaptive median and anisotropic nonlinear diffusion filters. Third, the image was segmented using the power watershed method coupled with a seeding algorithm based on geodesic reconstruction from the markers. If the resulting volume fraction did not match the target value quantified by chemical analysis of the sample, the BSE and SE signals were mixed in another ratio and the procedure was repeated until the target volume fraction was achieved. Otherwise, the segmented 3D image (replica) was accepted and its microstructure was thoroughly characterized with special attention paid to connectivity of the silicalite phase. In terms of the phase connectivity, Monte Carlo simulations based on the pure-phase permeability values enabled us to calculate the effective permeability tensor, the main diagonal elements of which were compared with the experimental permeability. In line with the hypothesis proposed in our recent paper (Čapek, P. et al. (2014) Comput. Mater. Sci. 89, 142-156), the results confirmed that the existence of particle clusters was a key microstructural feature determining effective permeability. © 2017 The Authors Journal of Microscopy © 2017 Royal Microscopical Society.

  16. Sulfur polymer cement encapsulation of oily matrix mixed low-level sludge

    International Nuclear Information System (INIS)

    Calhoun, C.L. Jr.; Nulf, L.E.; Fedorov, V.V.

    1996-01-01

    The U.S. Department of Energy (DOE) has been investigating a variety of stabilization technologies for the treatment of mixed low-level debris and sludges. Sulfur Polymer Cement (SPC) is being considered as one possible alternative final waste form for that segment of these wastes that does not readily lend itself to vitrification and/or grout stabilization. Earlier work demonstrated that SPC effectively immobilizes some Resource Conservation and Recovery Act (RCRA) toxic metal and metal salt species. However, the use of SPC as an encapsulant is relatively new, and the scope of tested waste streams has been limited. Accordingly, the authors' intent was to identify and ascertain the effects of process variables on final waste form properties for encapsulated mixed low-level sludge. The authors conducted an optimal design factorial experiment to study the effects of eight variables in twelve trials with replication. Factors for consideration included waste spike level, waste loading, additive type, additive loading, mixing method, hold time, hold temperature, and cooling rate. Toxic metal leachability was assessed for samples and was the basis for factor comparison. Trials were typically conducted with 150-g of total material per batch. Experimental results demonstrated that a number of process variables -- process hold time, cooling rate, waste loading, spike level, process temperature, additive type, and additive loading -- can influence toxic metal leachability. Also, the effects of different factors may weigh more heavily on different individual species; accordingly, optimum process conditions may vary considerably based on waste composition

  17. Magnetoresponsive Poly(ether sulfone)-Based Iron Oxide cum Hydrogel Mixed Matrix Composite Membranes for Switchable Molecular Sieving.

    Science.gov (United States)

    Lin, Xi; Nguyen Quoc, Bao; Ulbricht, Mathias

    2016-10-26

    Stimuli-responsive membranes that can adjust mass transfer and interfacial properties "on demand" have drawn large interest over the last few decades. Here, we designed and prepared a novel magnetoresponsive separation membrane with remote switchable molecular sieving effect by simple one-step and scalable nonsolvent induced phase separation (NIPS) process. Specifically, poly(ether sulfone) (PES) as matrix for an anisotropic membrane, prefabricated poly(N-isopropylacrylamide) (PNIPAAm) nanogel (NG) particles as functional gates, and iron oxide magnetic nanoparticles (MNP) as localized heaters were combined in a synergistic way. Before membrane casting, the properties of the building blocks, including swelling property and size distribution for NG, and magnetic property and heating efficiency for MNP, were investigated. Further, to identify optimal film casting conditions for membrane preparation by NIPS, in-depth rheological study of the effects of composition and temperature on blend dope solutions was performed. At last, a composite membrane with 10% MNP and 10% NG blended in a porous PES matrix was obtained, which showed a large, reversible, and stable magneto-responsivity. It had 9 times higher water permeability at the "on" state of alternating magnetic field (AMF) than at the "off"-state. Moreover, the molecular weight cutoff of such membrane could be reversibly shifted from ∼70 to 1750 kDa by switching off or on the external AMF, as demonstrated in dextran ultrafiltration tests. Overall, it has been proved that the molecular sieving performance of the novel mixed matrix composite membrane can be controlled by the swollen/shrunken state of PNIPAAm NG embedded in the nanoporous barrier layer of a PES-based anisotropic porous matrix, via the heat generation of nearby MNP. And the structure of such membrane can be tailored by the NIPS process conditions. Such membrane has potential as enabling material for remote-controlled drug release systems or devices for

  18. Electrochemical characterization of mixed matrix heterogeneous cation exchange membranes modified by simultaneous using ilmenite-co-iron oxide nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Hosseini, Sayed Mohsen; Hamidi, Alireza; Moghadassi, Abdolreza [Faculty of Engineering, Arak University, Arak (Iran, Islamic Republic of); Madaeni, Sayed Siavash [Razi University, Kermanshah (Iran, Islamic Republic of)

    2015-03-15

    Mixed matrix heterogeneous cation exchange membranes were prepared by solution casting technique. Ilmenite-co-iron oxide nanoparticle was also employed as inorganic filler additive in membrane fabrication. The effect of the used additives on membrane electrochemical properties was studied. Membrane ion exchange capacity, membrane potential, transport number and selectivity all were improved by use of FeTiO{sub 3}/Fe{sub 3}O{sub 4} nanoparticles in membrane matrix. Utilizing FeTiO{sub 3}-co-Fe{sub 3}O{sub 4} nanoparticles in the casting solution also led to increase in ionic flux obviously. The modified membranes containing FeTiO{sub 3}-co-Fe{sub 3}O{sub 4} nanoparticles showed higher transport number, selectivity and ionic flux compared to modified membrane containing ilmenite. Electrodialysis experiment in laboratory scale also showed higher cation removal for modified membrane containing FeTiO{sub 3}-co-Fe{sub 3}O{sub 4} nanoparticles compared to other modified membranes and pristine ones. Results showed that membrane areal electrical resistance declined sharply by use of FeTiO{sub 3}-co-Fe{sub 3}O{sub 4} nanoparticles in membrane matrix. Moreover, modified membrane containing ilmenite showed lower electrical resistance compared to others. Results showed that oxidative stability of membranes was decreased slightly by use of FeTiO{sub 3}/Fe{sub 3}O{sub 4} nanoparticles in membrane matrix. The results revealed that modified membranes in this study are comparable with that of other commercial ones.

  19. Comparison of ethylcellulose matrix characteristics prepared by solid dispersion technique or physical mixing

    Directory of Open Access Journals (Sweden)

    Fatemeh Sadeghi

    2003-07-01

    Full Text Available The characteristics of ethylcellulose matrices prepared from solid dispersion systems were compared with those prepared from physical mixture of drug and polymer. Sodium diclofenac was used as a model drug and the effect of the drug:polymer ratio and the method of matrix production on tablet crushing strength, friability, drug release profile and drug release mechanism were evaluated. The results showed that increasing the polymer content in matrices increased the crushing strengths of tablets. However the friability of tablets was independent of polymer content. Drug release rate was greatly affected by the amount of polymer in the matrices and considerable decrease in release rate was observed by increasing the polymer content. It was also found that the type of mixture used for matrix production had great influence on the tablet crushing strength and drug release rate. Matrices prepared from physical mixtures of drug and polymer was harder than those prepared from solid dispersion systems, but their release rates were considerably faster. This phenomenon was attributed to the encapsulation of drug particles by polymer in matrices prepared from solid dispersion system which caused a great delay in diffusion of the drug through polymer and made diffusion as a rate retarding process in drug release mechanism.

  20. Remarks on the hadronic matrix elements relevant to the SUSY K-Kbar mixing amplitude

    CERN Document Server

    Becirevic, D; Becirevic, Damir; Villadoro, Giovanni

    2004-01-01

    We compute the 1-loop chiral corrections to the bag parameters which are needed for the discussion of the SUSY K-Kbar mixing problem in both finite and infinite volume. We then show how the bag parameters can be combined among themselves and with some auxiliary quantities and thus sensibly reduce the systematic errors due to chiral extrapolations as well as those due to finite volume artefacts present in the results obtained from lattice QCD. We also show that in some cases these advantages remain as such even after including the 2-loop chiral corrections. Similar discussion is also made for the K --> pi electro-weak penguin operators.

  1. CO2/CH4 Separation by a Mixed Matrix Membrane of Polymethylpentyne/MIL-53 Particles

    Directory of Open Access Journals (Sweden)

    Reza Abedini

    2014-10-01

    Full Text Available The effect of Materials Institute Lavoisier-53 (MIL-53 particles on gas transport properties of polymethylpentyne (PMP was investigated. MIL-53 was added to the polymer matrix with different loadings of 10, 20 and 30 wt%. The properties of MIL-53 and prepared membranes were analyzed through FTIR, SEM and TGA methods. The adsorption of CO2 and CH4 was conducted and analyzed accurately through Langmuir equation to investigate the gas transport properties of membranes. The results from TGA showed that degradation temperature (Td increases significantly with increasing MIL-53 loading. SEM images demonstrated that MIL-53 particles dispersed well in polymer matrix with no considerable agglomeration and no non-selective void formation at polymer/filler interface. In addition, CO2 and CH4 permeability measurement along with calculation of CO2/CH4 selectivity were performed. The results showed that the permeability of gases (especially for CO2 increased significantly by increasing the MIL-53 loading. Additionally, CO2/CH4 selectivity showed an increasing trend with increasing the MIL-53 weight percent. Unlike CH4, the CO2 solubility coefficient increased with increasing the MIL-53 loading because of high free volume of membrane and selective adsorption of CO2 with MIL-53. Despite CO2 solubility enhancement its diffusivity coefficient remained more or less unchanged. The enhancement in CH4 permeability has been mainly attributed to its slight incremental diffusivity due to the membrane's increasingly higher free volume. Finally, a comparison between membranes performance and CO2/CH4 Robeson upper bound showed that, the performance of membranes improved due to the presence of MIL-53 which was very close to the Robeson bound.

  2. Singularities in FLRW spacetimes

    Science.gov (United States)

    het Lam, Huibert; Prokopec, Tomislav

    2017-12-01

    We point out that past-incompleteness of geodesics in FLRW spacetimes does not necessarily imply that these spacetimes start from a singularity. Namely, if a test particle that follows such a trajectory has a non-vanishing velocity, its energy was super-Planckian at some time in the past if it kept following that geodesic. That indicates a breakdown of the particle's description, which is why we should not consider those trajectories for the definition of an initial singularity. When one only considers test particles that do not have this breakdown of their trajectory, it turns out that the only singular FLRW spacetimes are the ones that have a scale parameter that vanishes at some initial time.

  3. Predictions for the Majorana CP violation phases in the neutrino mixing matrix and neutrinoless double beta decay

    Science.gov (United States)

    Girardi, I.; Petcov, S. T.; Titov, A. V.

    2016-10-01

    We obtain predictions for the Majorana phases α21 / 2 and α31 / 2 of the 3 × 3 unitary neutrino mixing matrix U = Ue† Uν, Ue and Uν being the 3 × 3 unitary matrices resulting from the diagonalisation of the charged lepton and neutrino Majorana mass matrices, respectively. We focus on forms of Ue and Uν permitting to express α21 / 2 and α31 / 2 in terms of the Dirac phase δ and the three neutrino mixing angles of the standard parametrisation of U, and the angles and the two Majorana-like phases ξ21 / 2 and ξ31 / 2 present, in general, in Uν. The concrete forms of Uν considered are fixed by, or associated with, symmetries (tri-bimaximal, bimaximal, etc.), so that the angles in Uν are fixed. For each of these forms and forms of Ue that allow to reproduce the measured values of the three neutrino mixing angles θ12, θ23 and θ13, we derive predictions for phase differences (α21 / 2 -ξ21 / 2), (α31 / 2 -ξ31 / 2), etc., which are completely determined by the values of the mixing angles. We show that the requirement of generalised CP invariance of the neutrino Majorana mass term implies ξ21 = 0 or π and ξ31 = 0 or π. For these values of ξ21 and ξ31 and the best fit values of θ12, θ23 and θ13, we present predictions for the effective Majorana mass in neutrinoless double beta decay for both neutrino mass spectra with normal and inverted ordering.

  4. Constraints on parity-mixing matrix elements from hard-pion exchange corrections to first-forbidden beta decays

    International Nuclear Information System (INIS)

    Kirchbach, M.

    1986-01-01

    In this paper the experience in extracting the value of the weak pion-nucleon coupling constant f/sub π//sup l/ from the parity-mixing matrix element + , T = 1; 1.042 MeV | V/sub PNC/ | O - , T = 0; 1.081 MeV> in 18 F is summarized with the aim to reveal some sources of uncertainties of the models exploited. We show that beyond of the long wavelenth approximation and in treating non-soft pion corrections to the two-body nuclear chiral charge density an upper bound for f/sub π//sup l/ is obtained which is about two times smaller as compared to results of previous analyses of similar character. Finally, we accentuate on the importance of the heavy-meson exchanges in the weak NN-potential for understanding recent measurement results of f/sub π//sup l/ which strongly deviate from earlier data. (author)

  5. Separation of carbon dioxide from flue gas by mixed matrix membranes using dual phase microporous polymeric constituents.

    Science.gov (United States)

    Sekizkardes, Ali K; Kusuma, Victor A; Dahe, Ganpat; Roth, Elliot A; Hill, Lawrence J; Marti, Anne; Macala, Megan; Venna, Surendar R; Hopkinson, David

    2016-09-27

    This study presents the fabrication of a new mixed matrix membrane using two microporous polymers: a polymer of intrinsic microporosity PIM-1 and a benzimidazole linked polymer, BILP-101, and their CO 2 separation properties from post-combustion flue gas. 17, 30 and 40 wt% loadings of BILP-101 into PIM-1 were tested, resulting in mechanically stable films showing very good interfacial interaction due to the inherent H-bonding capability of the constituent materials. Gas transport studies showed that BILP-101/PIM-1 membranes exhibit high CO 2 permeability (7200 Barrer) and selectivity over N 2 (15). The selected hybrid membrane was further tested for CO 2 separation using actual flue gas from a coal-fired power plant.

  6. Nanoclay embedded mixed matrix PVDF nanocomposite membrane: Preparation, characterization and biofouling resistance

    Energy Technology Data Exchange (ETDEWEB)

    Rajabi, Hamid [Membrane Research Centre, Department of Chemical Engineering, Razi University, Tagh Bostan, 67149 Kermanshah (Iran, Islamic Republic of); Department of Civil Engineering, Razi University, 67149 Kermanshah (Iran, Islamic Republic of); Ghaemi, Negin, E-mail: negin_ghaemi@kut.ac.ir [Department of Chemical Engineering, Kermanshah University of Technology, 67178 Kermanshah (Iran, Islamic Republic of); Madaeni, Sayed S. [Membrane Research Centre, Department of Chemical Engineering, Razi University, Tagh Bostan, 67149 Kermanshah (Iran, Islamic Republic of); Daraei, Parisa [Department of Chemical Engineering, Kermanshah University of Technology, 67178 Kermanshah (Iran, Islamic Republic of); Khadivi, Mohammad Ali [Friedrich-Alexander University, Erlangen-Nuremberg, Egerland Strasse 3, D-91058 Erlangen (Germany); Falsafi, Monir [Department of Chemistry, Faculty of Science, Razi University, 67149 Kermanshah (Iran, Islamic Republic of)

    2014-09-15

    Highlights: • Nanocomposite membranes were prepared by addition of OMMT to PVDF membrane. • Addition of nanoclay considerably increased the hydrophilicity of PVDF membrane. • Nanocomposite membranes had higher water flux and antifouling properties. • Fouling of membranes blended with nanoclay (<4 wt.%) reduced. - Abstract: In this paper, nanocomposite PVDF/nanoclay membranes were prepared with addition of different concentrations of organically modified montmorillonite (OMMT) into the polymeric casting solution using combination of solution dispersion and phase inversion methods. Membranes were characterized by use of X-ray diffraction (XRD), water contact angle, scanning electron microscopy (SEM) and atomic force microscopy (AFM), and their performances were evaluated in terms of pure water flux and fouling parameters. The surface hydrophilicity of all nanocomposites markedly improved compared to nascent PVDF. In addition, XRD patterns revealed the formation of intercalated layers of mineral clays in PVDF matrix. SEM and AFM images showed that addition of OMMT resulted in nanocomposite membranes with thinner skin layer and higher porosity rather than PVDF membranes. Pure water flux of PVDF/OMMT membranes increased significantly (particularly for fabricated membranes by 4 and 6 wt.% OMMT) compared to that of PVDF membrane. Moreover, nanocomposite membranes showed the elevated antifouling properties, and flux recovery of nascent PVDF membranes increased from 51 to 72% with addition of 2 wt.% OMMT nanoparticles. These nanocomposite membranes also offered a remarkable reusability and durability against biofouling.

  7. In-situ fabrication of cobalt oxide / sulphide mixed phase nanoparticles in Polyphenylenesulphide matrix

    Directory of Open Access Journals (Sweden)

    Narendra Rumale

    2013-03-01

    Full Text Available A novel approach for the in-situ fabrication of combined cobalt oxide / sulphide nanoparticles in sulphur containing polymer polyphenylenesulphide (PPS by polymer inorganic solid-solid reaction technique is reported here. At present, there is considerable interest in polymer-metal chalcogenides / oxides based nano-composites on account of their optical, magnetic, electronic and catalytic properties. We have demonstrated the suitability of solid-solid reaction methodology by reacting commonly available cobalt precursors with engineering thermoplastic PPS. The cobalt precursor was reacted with PPS in 1:1, 1:5, 1:10, and 1:15 molar ratios, respectively, by heating the mixture at the melting temperature of the polymer (285 ºC for six hours. The resultant products were characterized by X-ray diffractometry (XRD, Field-emission scanning electron microscopy (FESEM, Thermogravimetric analysis (TGA, Differential scanning calorimetry (DSC, Diffuse reflectance spectroscopy (DRS techniques and High resolution transmission electron microscope (HRTEM. The shift in melting temperature of PPS was observed. Increase in absorption peak is observed in the range of 320 to 370 nm with the increase in PPS concentration. Resultant nanoparticles of cobalt sulphide and cobalt oxide embedded in the PPS matrix showed spherical and distorted rod like morphology.

  8. Metal Organic Framework Crystals in Mixed-Matrix Membranes: Impact of the Filler Morphology on the Gas Separation Performance.

    Science.gov (United States)

    Sabetghadam, Anahid; Seoane, Beatriz; Keskin, Damla; Duim, Nicole; Rodenas, Tania; Shahid, Salman; Sorribas, Sara; Le Guillouzer, Clément; Clet, Guillaume; Tellez, Carlos; Daturi, Marco; Coronas, Joaquin; Kapteijn, Freek; Gascon, Jorge

    2016-05-10

    Mixed-matrix membranes (MMMs) comprising NH 2 -MIL-53(Al) and Matrimid ® or 6FDA-DAM have been investigated. The MOF loading has been varied between 5 and 20 wt%, while NH 2 -MIL-53(Al) with three different morphologies: nanoparticles, nanorods and microneedles have been dispersed in Matrimid ® . The synthesized membranes have been tested in the separation of CO 2 from CH 4 in an equimolar mixture. At 3 bar and 298 K for 8 wt% MOF loading, incorporation of NH 2 -MIL-53(Al) nanoparticles leads to the largest improvement compared to nanorods and microneedles. The incorporation of the best performing filler, i.e. NH 2 -MIL-53(Al) nanoparticles, to the highly permeable 6FDA-DAM has a larger effect, and the CO 2 permeability increased up to 85 % with slightly lower selectivities for 20 wt% MOF loading. Specifically, these membranes have a permeability of 660 Barrer with CO 2 /CH 4 separation factor of 28, leading to a performance very close to the Robeson limit of 2008. Furthermore, a new non-destructive technique based on Raman spectroscopy mapping is introduced to assess the homogeneity of the filler dispersion in the polymer matrix. The MOF contribution can be calculated by modelling the spectra. The determined homogeneity of the MOF filler distribution in the polymer is confirmed by FIB-SEM analysis.

  9. Characterization and fuel cell performance analysis of polyvinylalcohol-mordenite mixed-matrix membranes for direct methanol fuel cell use

    Energy Technology Data Exchange (ETDEWEB)

    Uctug, Fehmi Goerkem, E-mail: gorkem.uctug@bahcesehir.edu.t [University of Manchester, School of Chemical Engineering and Analytical Science, M60 1QD (United Kingdom); Holmes, Stuart M. [University of Manchester, School of Chemical Engineering and Analytical Science, M60 1QD (United Kingdom)

    2011-10-01

    Highlights: > We investigated the availability of PVA-mordenite membranes for DMFC use. > We measured the methanol permeability of PVA-mordenite membranes via pervaporation. > We did the fuel cell testing of these membranes, which had not been done before. > We showed that PVA-mordenite membranes have poorer DMFC performance than Nafion. > Membrane performance can be improved by increasing the proton conductivity of PVA. - Abstract: Polyvinylalcohol-mordenite (PVA-MOR) mixed matrix membranes were synthesized for direct methanol fuel cell (DMFC) use. For the structural and the morphological characterization, Scanning Electron Microscopy and Thermal Gravimetric Analysis methods were used. Zeolite distribution within the polymer matrix was found to be homogeneous. An impedance spectroscope was used to measure the proton conductivity. In order to obtain information about methanol permeation characteristics, swelling tests and a series of pervaporation experiments were carried out. 60-40 wt% PVA-MOR membranes were found to give the optimum transport properties. Proton conductivity of these membranes was found to be slightly lower than that of Nafion117{sup TM} whereas their methanol permeability was at least two orders of magnitude lower than Nafion117{sup TM}. DMFC performance of the PVA-MOR membranes was also measured. The inferior DMFC performance of PVA-MOR membranes was linked to drying in the fuel cell medium and the consequent proton conductivity loss. Their performance was improved by adding a dilute solution of sulfuric acid into the feed methanol solution. Future studies on the improvement of the proton conductivity of PVA-MOR membranes, especially via sulfonation of the polymer matrix, can overcome the low-performance problem associated with insufficient proton conductivity.

  10. Singularities in a Teacup

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 19; Issue 9. Singularities in a Teacup: Good Mathematics from Bad Lenses. Rajaram Nityananda. General Article Volume 19 Issue 9 September 2014 pp 787-796. Fulltext. Click here to view fulltext PDF. Permanent link:

  11. Singularities in a Teacup

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 19; Issue 9. Singularities in a Teacup: Good ... Author Affiliations. Rajaram Nityananda1. Azim Premji University, PES Institute of Technology Campus, Pixel Park, B Block, Electronics City, Hosur Road (Beside NICE Road) Bangalore – 560100 ...

  12. Singularities in a Teacup

    Indian Academy of Sciences (India)

    IAS Admin

    Standard presentations of optics concentrate on ideal systems made for imaging which bring all rays from a point ... One of the standard topics we study in school is the action of a spherical mirror. Figure 1 shows a set of ..... singularities of smooth maps, and the beauty of the mathematics needed to understand them, Arnold ...

  13. Stochastic singular optics

    CSIR Research Space (South Africa)

    Roux, FS

    2013-09-01

    Full Text Available Roux Presented at the International Conference on Correlation Optics 2013 Chernivtsi, Ukraine 18-20 September 2013 CSIR National Laser Centre, Pretoria, South Africa – p. 1/24 Contents ⊲ Defining Stochastic Singular Optics (SSO) ⊲ Tools of Stochastic...

  14. Pseudospherical surfaces with singularities

    DEFF Research Database (Denmark)

    Brander, David

    2017-01-01

    We study a generalization of constant Gauss curvature −1 surfaces in Euclidean 3-space, based on Lorentzian harmonic maps, that we call pseudospherical frontals. We analyse the singularities of these surfaces, dividing them into those of characteristic and non-characteristic type. We give methods...

  15. Singularities in FLRW Spacetimes

    NARCIS (Netherlands)

    Lam, Huibert het; Prokopec, Tom

    2017-01-01

    We point out that past-incompleteness of geodesics in FLRW spacetimes does not necessarily imply that these spacetimes start from a singularity. Namely, if a test particle that follows such a trajectory has a non-vanishing velocity, its energy was super-Planckian at some time in the past if it kept

  16. l-Arginine Modifies the Exopolysaccharide Matrix and Thwarts Streptococcus mutans Outgrowth within Mixed-Species Oral Biofilms.

    Science.gov (United States)

    He, Jinzhi; Hwang, Geelsu; Liu, Yuan; Gao, Lizeng; Kilpatrick-Liverman, LaTonya; Santarpia, Peter; Zhou, Xuedong; Koo, Hyun

    2016-10-01

    l-Arginine, a ubiquitous amino acid in human saliva, serves as a substrate for alkali production by arginolytic bacteria. Recently, exogenous l-arginine has been shown to enhance the alkalinogenic potential of oral biofilm and destabilize its microbial community, which might help control dental caries. However, l-arginine exposure may inflict additional changes in the biofilm milieu when bacteria are growing under cariogenic conditions. Here, we investigated how exogenous l-arginine modulates biofilm development using a mixed-species model containing both cariogenic (Streptococcus mutans) and arginolytic (Streptococcus gordonii) bacteria in the presence of sucrose. We observed that 1.5% (wt/vol) l-arginine (also a clinically effective concentration) exposure suppressed the outgrowth of S. mutans, favored S. gordonii dominance, and maintained Actinomyces naeslundii growth within biofilms (versus vehicle control). In parallel, topical l-arginine treatments substantially reduced the amounts of insoluble exopolysaccharides (EPS) by >3-fold, which significantly altered the three-dimensional (3D) architecture of the biofilm. Intriguingly, l-arginine repressed S. mutans genes associated with insoluble EPS (gtfB) and bacteriocin (SMU.150) production, while spxB expression (H2O2 production) by S. gordonii increased sharply during biofilm development, which resulted in higher H2O2 levels in arginine-treated biofilms. These modifications resulted in a markedly defective EPS matrix and areas devoid of any bacterial clusters (microcolonies) on the apatitic surface, while the in situ pH values at the biofilm-apatite interface were nearly one unit higher in arginine-treated biofilms (versus the vehicle control). Our data reveal new biological properties of l-arginine that impact biofilm matrix assembly and the dynamic microbial interactions associated with pathogenic biofilm development, indicating the multiaction potency of this promising biofilm disruptor. Dental caries is one

  17. Crosslinkable mixed matrix membranes with surface modified molecular sieves for natural gas purification: I. Preparation and experimental results

    KAUST Repository

    Ward, Jason K.

    2011-07-01

    Dense film mixed matrix membranes (MMMs) comprised of SSZ-13 dispersed in a crosslinkable polyimide (PDMC) were fabricated and evaluated for carbon dioxide/methane separations. MMMs containing 25% (w/w) as-received (AR) SSZ-13 exhibited a carbon dioxide permeability of 153 Barrers with a carbon dioxide/methane ideal selectivity of 34.7 at 65. psia and 35 °C. This represents a permeability enhancement of 129% and a decline in selectivity of 4.7% over neat PDMC (PCO2=66.9 Barrers, αCO2/CH4=36.4). A sieve surface modification procedure was developed with the aim of improving SSZ-13/PDMC MMM transport properties. MMMs containing 25% (w/w) surface modified (SM) SSZ-13 exhibited a carbon dioxide permeability of 148 Barrers and carbon dioxide/methane selectivity of 38.9 at 65. psia and 35 °C, representing enhancements in both permeability and selectivity of 121% and 6.9%, respectively. Mixed gas permeation analyses of MMMs containing SM-SSZ-13 using a 10% carbon dioxide/90% methane mixture shows that permeability and selectivity enhancements of 47% and 13%, respectively, over neat PDMC are possible at 700. psia and 35 °C. © 2011 Elsevier B.V.

  18. PES mixed matrix nanofiltration membrane embedded with polymer wrapped MWCNT: Fabrication and performance optimization in dye removal by RSM.

    Science.gov (United States)

    Ghaemi, Negin; Madaeni, Sayed S; Daraei, Parisa; Rajabi, Hamid; Shojaeimehr, Tahereh; Rahimpour, Farshad; Shirvani, Bita

    2015-11-15

    MWCNTs were wrapped by poly(sodium 4-styrenesulfonate) (PSS), and different amounts of raw and polymer wrapped MWCNTs were implemented to fabricate PES mixed matrix membranes by phase inversion method. Success of wrapping was probed by FTIR spectroscopy, and prepared membranes were characterized by SEM, AFM, porosity, and water contact angle measurements. Response surface methodology (RSM) was employed to optimize the permeate flux and dye removal efficiency of membranes with three variables of concentration, pH of dye solution, and membrane composition. A response surface (RS) with a D-optimal design was defined to build the mathematical model, minimize the number of experiments, and investigate the effect of parameters on the response. Adequacy of the obtained model was confirmed by means of variance analysis and additional experiments. Based on observed and predicted results, wrapping CNTs by PSS improved permeation flux and dye removal efficiency of MMMs. Validity of model was verified according to the good agreement between predicted and experimental results. Membrane mixed with 0.1 wt.% polymer wrapped MWCNTs offered the highest permeation flux as well as dye removal efficiency. According to the model response, in order to achieve a higher dye removal, an acidic pH and a moderate dye solution concentration are recommended. Additionally, basic solution pH (9.0) and a dilute dye solution are suggested to reach a higher permeation flux. Copyright © 2015 Elsevier B.V. All rights reserved.

  19. Singular value correlation functions for products of Wishart random matrices

    International Nuclear Information System (INIS)

    Akemann, Gernot; Kieburg, Mario; Wei, Lu

    2013-01-01

    We consider the product of M quadratic random matrices with complex elements and no further symmetry, where all matrix elements of each factor have a Gaussian distribution. This generalizes the classical Wishart–Laguerre Gaussian unitary ensemble with M = 1. In this paper, we first compute the joint probability distribution for the singular values of the product matrix when the matrix size N and the number M are fixed but arbitrary. This leads to a determinantal point process which can be realized in two different ways. First, it can be written as a one-matrix singular value model with a non-standard Jacobian, or second, for M ⩾ 2, as a two-matrix singular value model with a set of auxiliary singular values and a weight proportional to the Meijer G-function. For both formulations, we determine all singular value correlation functions in terms of the kernels of biorthogonal polynomials which we explicitly construct. They are given in terms of the hypergeometric and Meijer G-functions, generalizing the Laguerre polynomials for M = 1. Our investigation was motivated from applications in telecommunication of multi-layered scattering multiple-input and multiple-output channels. We present the ergodic mutual information for finite-N for such a channel model with M − 1 layers of scatterers as an example. (paper)

  20. Rapid screening of mixed edible oils and gutter oils by matrix-assisted laser desorption/ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Ng, Tsz-Tsun; So, Pui-Kin; Zheng, Bo [Food Safety and Technology Research Centre, State Key Laboratory of Chirosciences and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom Kowloon, Hong Kong Special Administrative Region (China); Shenzhen Key Laboratory of Food Biological Safety Control and State Key Laboratory of Chinese Medicine and Molecular Pharmacology (Incubation), Shenzhen Research Institute of The Hong Kong Polytechnic University, Shenzhen (China); Yao, Zhong-Ping, E-mail: zhongping.yao@polyu.edu.hk [Food Safety and Technology Research Centre, State Key Laboratory of Chirosciences and Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hom Kowloon, Hong Kong Special Administrative Region (China); Shenzhen Key Laboratory of Food Biological Safety Control and State Key Laboratory of Chinese Medicine and Molecular Pharmacology (Incubation), Shenzhen Research Institute of The Hong Kong Polytechnic University, Shenzhen (China)

    2015-07-16

    Highlights: • Simplified sample preparation method for direct analysis of edible oils by MALDI-MS. • Establishment of a preliminary MALDI-MS spectral database of edible oils. • Rapid screening of mixed edible oils and gutter oils. - Abstract: Authentication of edible oils is a long-term issue in food safety, and becomes particularly important with the emergence and wide spread of gutter oils in recent years. Due to the very high analytical demand and diversity of gutter oils, a high throughput analytical method and a versatile strategy for authentication of mixed edible oils and gutter oils are highly desirable. In this study, an improved matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) method has been developed for direct analysis of edible oils. This method involved on-target sample loading, automatic data acquisition and simple data processing. MALDI-MS spectra with high quality and high reproducibility have been obtained using this method, and a preliminary spectral database of edible oils has been set up. The authenticity of an edible oil sample can be determined by comparing its MALDI-MS spectrum and principal component analysis (PCA) results with those of its labeled oil in the database. This method is simple and the whole process only takes several minutes for analysis of one oil sample. We demonstrated that the method was sensitive to change in oil compositions and can be used for measuring compositions of mixed oils. The capability of the method for determining mislabeling enables it for rapid screening of gutter oils since fraudulent mislabeling is a common feature of gutter oils.

  1. Resonance scattering and singularities of the scattering function

    Energy Technology Data Exchange (ETDEWEB)

    Heiss, W.D. [National Institute for Theoretical Physics, Stellenbosch Institute for Advanced Study, and Institute of Theoretical Physics, University of Stellenbosch (South Africa); Nazmitdinov, R.G. [Department de Fisica, Universitat de les Illes Balears, Palma de Mallorca (Spain); Bogoliubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, Dubna (Russian Federation)

    2010-05-15

    Recent studies of transport phenomena with complex potentials are explained by generic square root singularities of spectrum and eigenfunctions of non-Hermitian Hamiltonians. Using a two channel problem we demonstrate that such singularities produce a significant effect upon the pole behaviour of the scattering matrix, and more significantly upon the associated residues. This mechanism explains why by proper choice of the system parameters the resonance cross section is increased drastically in one channel and suppressed in the other channel. (authors)

  2. Singular potentials in quantum mechanics

    Energy Technology Data Exchange (ETDEWEB)

    Aguilera-Navarro, V.C. [Instituto de Fisica Teorica (IFT), Sao Paulo, SP (Brazil); Koo, E. Ley [Universidad Nacional Autonoma de Mexico, Mexico City (Mexico). Inst. de Fisica

    1995-10-01

    This paper is a review of some mathematical methods as recently developed and applied to deal with singular potentials in Quantum Mechanics. Regular and singular perturbative methods as well as variational treatments are considered. (author). 25 refs.

  3. An investigation of singular Lagrangians as field systems

    International Nuclear Information System (INIS)

    Rabei, E.M.

    1995-07-01

    The link between the treatment of singular Lagrangians as field systems and the general approach is studied. It is shown that singular Lagrangians as field systems are always in exact agreement with the general approach. Two examples and the singular Lagrangian with zero rank Hessian matrix are studied. The equations of motion in the field systems are equivalent to the equations which contain acceleration, and the constraints are equivalent to the equations which do not contain acceleration in the general approach treatment. (author). 10 refs

  4. Singularities: the Brieskorn anniversary volume

    National Research Council Canada - National Science Library

    Brieskorn, Egbert; Arnolʹd, V. I; Greuel, G.-M; Steenbrink, J. H. M

    1998-01-01

    ...... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Main theorem ... 3 Ideals of ideal-unimodal plane curve singularities. . . . . . . . . . . . . . . . References ... Gert-Martin Greuel and Gerhard Pfister...

  5. String theory and cosmological singularities

    Indian Academy of Sciences (India)

    Well-known examples are singularities inside black holes and initial or final singularities in expanding or contracting universes. In recent times, string theory is providing new perspectives of such singularities which may lead to an understanding of these in the standard framework of time evolution in quantum mechanics.

  6. Holographic complexity and spacetime singularities

    International Nuclear Information System (INIS)

    Barbón, José L.F.; Rabinovici, Eliezer

    2016-01-01

    We study the evolution of holographic complexity in various AdS/CFT models containing cosmological crunch singularities. We find that a notion of complexity measured by extremal bulk volumes tends to decrease as the singularity is approached in CFT time, suggesting that the corresponding quantum states have simpler entanglement structure at the singularity.

  7. An Efficient and Robust Singular Value Method for Star Pattern Recognition and Attitude Determination

    Science.gov (United States)

    Juang, Jer-Nan; Kim, Hye-Young; Junkins, John L.

    2003-01-01

    A new star pattern recognition method is developed using singular value decomposition of a measured unit column vector matrix in a measurement frame and the corresponding cataloged vector matrix in a reference frame. It is shown that singular values and right singular vectors are invariant with respect to coordinate transformation and robust under uncertainty. One advantage of singular value comparison is that a pairing process for individual measured and cataloged stars is not necessary, and the attitude estimation and pattern recognition process are not separated. An associated method for mission catalog design is introduced and simulation results are presented.

  8. Study on the Fouling Behavior of Polyethylene and Silica Nanoparticles Mixed Matrix Membranes in Filtration of Humic Acid Solution

    Directory of Open Access Journals (Sweden)

    Ali Akbari

    2016-09-01

    Full Text Available Because most contaminants in water create strong interactions with hydrophobic surfaces, there are usually problems such as flux decline and pore blocking in polyethylene (PE membranes due to irreversible adsorption of foulants on their intrinsic hydrophobic surface. Therefore, in this work, attempts were made to improve the properties of PE membranes in terms of water flux and membrane fouling resistance by dispersion of silica nanoparticles (NPs. First, NPs were synthesized by sol-gel method at two concentrations of ammonia (0.5 and 1 mol/L. The synthesized NPs with smaller size were used to fabricate the mixed matrix PE membranes containing 0, 0.5, 1 and 2 wt% NPs. FE-SEM and EDX analyses were employed to evaluate the morphology and structure of the fabricated membranes and confirmed the presence of NPs in the membranes matrix. The results of pure water flux test revealed that the membrane containing 1 wt% NPs displayed the maximum flux of 30 L/m2.h. Furthermore, the performance and fouling behaviors of membranes during filtration of humic acid solution, one of the most important contaminants of water resources, were studied using a classical fouling model. Fouling mechanism analysis showed that for neat and NPs-embedded membranes containing 0.5 and 2 wt% NPs, the best fit of the data was obtained by cake layer formation as well as the intermediate blocking mechanisms. However, the best fit of the experimental data of NPs-embedded membrane containing 1 wt% occurred with only cake layer formation mechanism. The investigation on membrane fouling resistance showed that 1 wt% NPs-embedded membrane displayed 58% maximum flux recovery and 52% reversibility to total fouling ratio, respectively.

  9. Infinitesimal Structure of Singularities

    Directory of Open Access Journals (Sweden)

    Michael Heller

    2017-02-01

    Full Text Available Some important problems of general relativity, such as the quantisation of gravity or classical singularity problems, crucially depend on geometry on very small scales. The so-called synthetic differential geometry—a categorical counterpart of the standard differential geometry—provides a tool to penetrate infinitesimally small portions of space-time. We use this tool to show that on any “infinitesimal neighbourhood” the components of the curvature tensor are themselves infinitesimal, and construct a simplified model in which the curvature singularity disappears, owing to this effect. However, one pays a price for this result. Using topoi as a generalisation of spaces requires a weakening of arithmetic (the existence of infinitesimals and of logic (to the intuitionistic logic. Is this too high a price to pay for acquiring a new method of solving unsolved problems in physics? Without trying, we shall never know the answer.

  10. Deformations of surface singularities

    CERN Document Server

    Szilárd, ágnes

    2013-01-01

    The present publication contains a special collection of research and review articles on deformations of surface singularities, that put together serve as an introductory survey of results and methods of the theory, as well as open problems, important examples and connections to other areas of mathematics. The aim is to collect material that will help mathematicians already working or wishing to work in this area to deepen their insight and eliminate the technical barriers in this learning process. This also is supported by review articles providing some global picture and an abundance of examples. Additionally, we introduce some material which emphasizes the newly found relationship with the theory of Stein fillings and symplectic geometry.  This links two main theories of mathematics: low dimensional topology and algebraic geometry. The theory of normal surface singularities is a distinguished part of analytic or algebraic geometry with several important results, its own technical machinery, and several op...

  11. The cosmological singularity

    CERN Document Server

    Belinski, Vladimir

    2018-01-01

    Written for researchers focusing on general relativity, supergravity, and cosmology, this is a self-contained exposition of the structure of the cosmological singularity in generic solutions of the Einstein equations, and an up-to-date mathematical derivation of the theory underlying the Belinski–Khalatnikov–Lifshitz (BKL) conjecture on this field. Part I provides a comprehensive review of the theory underlying the BKL conjecture. The generic asymptotic behavior near the cosmological singularity of the gravitational field, and fields describing other kinds of matter, is explained in detail. Part II focuses on the billiard reformulation of the BKL behavior. Taking a general approach, this section does not assume any simplifying symmetry conditions and applies to theories involving a range of matter fields and space-time dimensions, including supergravities. Overall, this book will equip theoretical and mathematical physicists with the theoretical fundamentals of the Big Bang, Big Crunch, Black Hole singula...

  12. Multiscale singularity trees

    DEFF Research Database (Denmark)

    Somchaipeng, Kerawit; Sporring, Jon; Johansen, Peter

    2007-01-01

    We propose MultiScale Singularity Trees (MSSTs) as a structure to represent images, and we propose an algorithm for image comparison based on comparing MSSTs. The algorithm is tested on 3 public image databases and compared to 2 state-of-theart methods. We conclude that the computational complexity...... of our algorithm only allows for the comparison of small trees, and that the results of our method are comparable with state-of-the-art using much fewer parameters for image representation....

  13. HYDROPHOBIC ZEOLITE-SILICONE RUBBER MIXED MATRIX MEMBRANES FOR ETHANOL-WATER SEPARATION: EFFECT OF ZEOLITE AND SILICONE COMPONENT SELECTION ON PERVAPORATION PERFORMANCE

    Science.gov (United States)

    High-silica ZSM 5 zeolites were incorporated into poly(dimethyl siloxane) (PDMS) polymers to form mixed matrix membranes for ethanol removal from water via pervaporation. Membrane formulation and preparation parameters were varied to determine the effect on pervaporation perform...

  14. Mixed matrix membranes containing MOF's for ethelyne/ethane separation. Part B: Effect of CU3BTC2 on membrane transport properties

    NARCIS (Netherlands)

    Ploegmakers, J.; Japip, S.; Nijmeijer, Dorothea C.

    2013-01-01

    Mixed matrix membranes (MMMs) containing various amounts of the metal-organic framework (MOF) Cu3BTC2 as filler in P84 were characterized in terms of their ethylene and ethane separating performance. Previous research showed that especially the use of the MOF Cu3BTC2 improves the ethylene/ethane

  15. Efficient multiple-trait association and estimation of genetic correlation using the matrix-variate linear mixed model.

    Science.gov (United States)

    Furlotte, Nicholas A; Eskin, Eleazar

    2015-05-01

    Multiple-trait association mapping, in which multiple traits are used simultaneously in the identification of genetic variants affecting those traits, has recently attracted interest. One class of approaches for this problem builds on classical variance component methodology, utilizing a multitrait version of a linear mixed model. These approaches both increase power and provide insights into the genetic architecture of multiple traits. In particular, it is possible to estimate the genetic correlation, which is a measure of the portion of the total correlation between traits that is due to additive genetic effects. Unfortunately, the practical utility of these methods is limited since they are computationally intractable for large sample sizes. In this article, we introduce a reformulation of the multiple-trait association mapping approach by defining the matrix-variate linear mixed model. Our approach reduces the computational time necessary to perform maximum-likelihood inference in a multiple-trait model by utilizing a data transformation. By utilizing a well-studied human cohort, we show that our approach provides more than a 10-fold speedup, making multiple-trait association feasible in a large population cohort on the genome-wide scale. We take advantage of the efficiency of our approach to analyze gene expression data. By decomposing gene coexpression into a genetic and environmental component, we show that our method provides fundamental insights into the nature of coexpressed genes. An implementation of this method is available at http://genetics.cs.ucla.edu/mvLMM. Copyright © 2015 by the Genetics Society of America.

  16. Technical Note: Application of positive matrix factor analysis in heterogeneous kinetics studies utilizing the mixed-phase relative rates technique

    Science.gov (United States)

    Liu, Y.; Li, S.-M.; Liggio, J.

    2014-09-01

    The mixed-phase relative rates approach for determining aerosol particle organic heterogeneous reaction kinetics is often performed utilizing mass spectral tracers as a proxy for particle-phase reactant concentration. However, this approach may be influenced by signal contamination from oxidation products during the experiment. In the current study, the mixed-phase relative rates technique has been improved by combining a positive matrix factor (PMF) analysis with electron ionization aerosol mass spectrometry (unit-mass resolution), thereby removing the influence of m / z fragments from reaction products on the reactant signals. To demonstrate the advantages of this approach, the heterogeneous reaction between OH radicals and citric acid (CA) was investigated using a photochemical flow tube coupled to a compact time-of-flight aerosol mass spectrometer (C-ToF-AMS). The measured heterogeneous rate constant (k2) of citric acid toward OH was (3.31 ± 0.29) × 10-12 cm3 molecule-1 s-1 at 298 K and (30 ± 3)% relative humidity (RH) and was several times greater than the results utilizing individual m / z fragments. This phenomenon was further evaluated for particulate-phase organophosphates (triphenyl phosphate (TPhP), tris-1,3-dichloro-2-propyl phosphate (TDCPP) and tris-2-ethylhexyl phosphate (TEHP)), leading to k2 values significantly larger than previously reported. The results suggest that heterogeneous kinetics can be significantly underestimated when the structure of the products is highly similar to the reactant and when a non-molecular tracer is measured with a unit-mass resolution aerosol mass spectrometer. The results also suggest that the heterogeneous lifetime of organic aerosol in models can be overestimated due to underestimated OH uptake coefficients. Finally, a comparison of reported rate constants implies that the heterogeneous oxidation of aerosols will be dependent upon a number of factors related to the reaction system, and that a single rate

  17. Application of positive matrix factor analysis in heterogeneous kinetics studies: an improvement to the mixed-phase relative rates technique

    Science.gov (United States)

    Liu, Y.; Li, S.-M.; Liggio, J.

    2014-03-01

    The mixed-phase relative rate approach for determining aerosol particle organic component heterogeneous reaction kinetics and OH uptake coefficients to particles is often performed utilizing mass spectral tracers as a proxy for particle phase reactant concentration. However, this approach may be influenced by signal contaminations from oxidation products during the experiment. In the current study, the mixed-phase relative rates technique has been improved by combining a Positive Matrix Factor (PMF) analysis with electron ionization Aerosol Mass Spectrometry, thereby removing the influence of m / z fragments from reaction products on the reactant signals. To demonstrate the advantages of this approach, the heterogeneous reaction between OH radicals and citric acid (CA) was investigated using a photochemical flow tube coupled to a compact time-of-flight aerosol mass spectrometer (C-ToF-AMS). The measured heterogeneous rate constant (k2) of citric acid toward OH was (3.31 ± 0.29) × 10-12 cm3 molecule-1 s-1 at 298 K and (30 ± 3)% RH and was ∼7.7 times greater than previously reported results utilizing individual m / z fragments. This phenomenon was further confirmed for particulate-phase organophosphates (TPhP, TDCPP, and TEHP), leading to k2 values significantly larger than previously reported. The results suggest that heterogeneous kinetics can be significantly underestimated when a non-molecular ion peak is used as the tracer. Finally, the results suggest that the heterogeneous lifetime of organic aerosol in models can be overestimated due to underestimated OH uptake coefficients, and that it may be necessary to revisit the heterogeneous kinetic data of organic aerosol components which were derived in the context of the relative rates technique.

  18. Stepwise observation and quantification and mixed matrix membrane separation of CO2 within a hydroxy-decorated porous host.

    Science.gov (United States)

    Morris, Christopher G; Jacques, Nicholas M; Godfrey, Harry G W; Mitra, Tamoghna; Fritsch, Detlev; Lu, Zhenzhong; Murray, Claire A; Potter, Jonathan; Cobb, Tom M; Yuan, Fajin; Tang, Chiu C; Yang, Sihai; Schröder, Martin

    2017-04-01

    The identification of preferred binding domains within a host structure provides important insights into the function of materials. State-of-the-art reports mostly focus on crystallographic studies of empty and single component guest-loaded host structures to determine the location of guests. However, measurements of material properties ( e.g. , adsorption and breakthrough of substrates) are usually performed for a wide range of pressure (guest coverage) and/or using multi-component gas mixtures. Here we report the development of a multifunctional gas dosing system for use in X-ray powder diffraction studies on Beamline I11 at Diamond Light Source. This facility is fully automated and enables in situ crystallographic studies of host structures under (i) unlimited target gas loadings and (ii) loading of multi-component gas mixtures. A proof-of-concept study was conducted on a hydroxyl-decorated porous material MFM-300(V III ) under (i) five different CO 2 pressures covering the isotherm range and (ii) the loading of equimolar mixtures of CO 2 /N 2 . The study has successfully captured the structural dynamics underpinning CO 2 uptake as a function of surface coverage. Moreover, MFM-300(V III ) was incorporated in a mixed matrix membrane (MMM) with PIM-1 in order to evaluate the CO 2 /N 2 separation potential of this material. Gas permeation measurements on the MMM show a great improvement over the bare PIM-1 polymer for CO 2 /N 2 separation based on the ideal selectivity.

  19. Origins and Evolution of Inorganic-Based and MOF-Based Mixed-Matrix Membranes for Gas Separations

    Directory of Open Access Journals (Sweden)

    Edson V. Perez

    2016-09-01

    Full Text Available Gas separation for industrial, energy, and environmental applications requires low energy consumption and small footprint technology to minimize operating and capital costs for the processing of large volumes of gases. Among the separation methods currently being used, like distillation, amine scrubbing, and pressure and temperature swing adsorption, membrane-based gas separation has the potential to meet these demands. The key component, the membrane, must then be engineered to allow for high gas flux, high selectivity, and chemical and mechanical stability at the operating conditions of feed composition, pressure, and temperature. Among the new type of membranes studied that show promising results are the inorganic-based and the metal-organic framework-based mixed-matrix membranes (MOF-MMMs. A MOF is a unique material that offers the possibility of tuning the porosity of a membrane by introducing diffusional channels and forming a compatible interface with the polymer. This review details the origins of these membranes and their evolution since the first inorganic/polymer and MOF/polymer MMMs were reported in the open literature. The most significant advancements made in terms of materials, properties, and testing conditions are described in a chronological fashion.

  20. New low-flux mixed matrix membranes that offer superior removal of protein-bound toxins from human plasma

    Science.gov (United States)

    Pavlenko, Denys; van Geffen, Esmée; van Steenbergen, Mies J.; Glorieux, Griet; Vanholder, Raymond; Gerritsen, Karin G. F.; Stamatialis, Dimitrios

    2016-10-01

    Hemodialysis is a widely available and well-established treatment for patients with End Stage Renal Disease (ESRD). However, although life-sustaining, patient mortality rates are very high. Several recent studies corroborated the link between dialysis patients’ outcomes and elevated levels of protein-bound uremic toxins (PBUT) that are poorly removed by conventional hemodialysis. Therefore, new treatments are needed to improve their removal. Recently, our group showed that the combination of dialysis and adsorption on one membrane, the mixed matrix membrane (MMM), can effectively remove those toxins from human plasma. However, these first MMMs were rather large in diameter and their mass transport characteristics needed improvement before application in the clinical setting. Therefore, in this study we developed a new generation of MMMs that have a smaller diameter and optimized characteristics offering superior ability in removing the PBUT indoxyl sulfate (IS) and p-cresyl sulfate (pCS) in comparison to first generation MMMs (30 and 125% respectively), as well as, a commercial dialysis membrane (more than 100% better removal).

  1. Reinforcing copper matrix composites through molecular-level mixing of functionalized nanodiamond by co-deposition route

    Energy Technology Data Exchange (ETDEWEB)

    He Jie [School of Materials Science and Engineering, Tianjin University, Tianjin 30072 (China); Zhao Naiqin [School of Materials Science and Engineering, Tianjin University, Tianjin 30072 (China); Tianjin Key Laboratory of Composite and Functional Materials (China)], E-mail: nqzhao@tju.edu.cn; Shi Chunsheng; Du Xiwen; Li Jiajun [School of Materials Science and Engineering, Tianjin University, Tianjin 30072 (China); Nash, Philip [Department of Mechanical, Materials and Aerospace Engineering, Illinois Institute of Technology, Chicago, IL 60616 (United States)

    2008-08-25

    This work reports a chemical method called 'co-deposition route' for fabricating ND (nanodiamond)/Cu composite at a molecular-level mixing. The main procedure of 'co-deposition route' includes four steps. ND particles have been functionalized by HF acid before co-deposition. SEM, HRTEM (high-resolution transmission electron spectroscopy), XRD (X-ray diffraction), EDS (energy-dispersive spectrum analysis) and optical microscope were carried out to characterize the as-prepared composite powders and bulk composites. Results indicated that copper matrix composite with a homogeneous dispersion of functionalized ND particles can be prepared. The modification of ND particles was performed by HF (30 vol%) acid at 70 deg. C, and C-F bond was successfully detected by XPS (X-ray photoelectron spectrum) and IR (Infrared spectroscopy). The properties of relative density, microhardness and electric conductivity of ND/Cu composites have been measured. With the comparison of conventional methods, it showed that the as-prepared ND/Cu composites with good combined performances have a promising future for industry application.

  2. Mixed

    Directory of Open Access Journals (Sweden)

    Pau Baya

    2011-05-01

    Full Text Available Remenat (Catalan (Mixed, "revoltillo" (Scrambled in Spanish, is a dish which, in Catalunya, consists of a beaten egg cooked with vegetables or other ingredients, normally prawns or asparagus. It is delicious. Scrambled refers to the action of mixing the beaten egg with other ingredients in a pan, normally using a wooden spoon Thought is frequently an amalgam of past ideas put through a spinner and rhythmically shaken around like a cocktail until a uniform and dense paste is made. This malleable product, rather like a cake mixture can be deformed pulling it out, rolling it around, adapting its shape to the commands of one’s hands or the tool which is being used on it. In the piece Mixed, the contortion of the wood seeks to reproduce the plasticity of this slow heavy movement. Each piece lays itself on the next piece consecutively like a tongue of incandescent lava slowly advancing but with unstoppable inertia.

  3. Cosmological models without singularities

    International Nuclear Information System (INIS)

    Petry, W.

    1981-01-01

    A previously studied theory of gravitation in flat space-time is applied to homogeneous and isotropic cosmological models. There exist two different classes of models without singularities: (i) ever-expanding models, (ii) oscillating models. The first class contains models with hot big bang. For these models there exist at the beginning of the universe-in contrast to Einstein's theory-very high but finite densities of matter and radiation with a big bang of very short duration. After short time these models pass into the homogeneous and isotropic models of Einstein's theory with spatial curvature equal to zero and cosmological constant ALPHA >= O. (author)

  4. Quantum singular-value decomposition of nonsparse low-rank matrices

    Science.gov (United States)

    Rebentrost, Patrick; Steffens, Adrian; Marvian, Iman; Lloyd, Seth

    2018-01-01

    We present a method to exponentiate nonsparse indefinite low-rank matrices on a quantum computer. Given access to the elements of the matrix, our method allows one to determine the singular values and their associated singular vectors in time exponentially faster in the dimension of the matrix than known classical algorithms. The method extends to non-Hermitian and nonsquare matrices via matrix embedding. Moreover, our method preserves the phase relations between the singular spaces allowing for efficient algorithms that require operating on the entire singular-value decomposition of a matrix. As an example of such an algorithm, we discuss the Procrustes problem of finding a closest isometry to a given matrix.

  5. Plane waves with weak singularities

    International Nuclear Information System (INIS)

    David, Justin R.

    2003-03-01

    We study a class of time dependent solutions of the vacuum Einstein equations which are plane waves with weak null singularities. This singularity is weak in the sense that though the tidal forces diverge at the singularity, the rate of divergence is such that the distortion suffered by a freely falling observer remains finite. Among such weak singular plane waves there is a sub-class which does not exhibit large back reaction in the presence of test scalar probes. String propagation in these backgrounds is smooth and there is a natural way to continue the metric beyond the singularity. This continued metric admits string propagation without the string becoming infinitely excited. We construct a one parameter family of smooth metrics which are at a finite distance in the space of metrics from the extended metric and a well defined operator in the string sigma model which resolves the singularity. (author)

  6. Thermo-mechanical properties of mixed-matrix membranes encompassing zeolitic imidazolate framework-90 and polyvinylidine difluoride: ZIF-90/PVDF nanocomposites

    Science.gov (United States)

    Flyagina, Irina S.; Mahdi, E. M.; Titov, Kirill; Tan, Jin-Chong

    2017-08-01

    Mixed-matrix membranes are contemporary nanocomposite materials with many potential applications, from liquid and gas separations to chemical sensors and biomedicine. We report fabrication of a metal-organic framework (MOF)-based nanocomposite, combining polyvinylidene difluoride (PVDF) polymer as the matrix and ZIF-90 nanocrystals of up to 30 wt. % filler content. The focus is to establish the processing—microstructure—mechanical property relationships. We reveal the importance for quantifying salient effects of the filler contents: (i) tensile strength degrades beyond 10 wt. % and (ii) mechanical toughness declines due to membrane embrittlement. These are vital mechanical aspects but widely overlooked in the emergent field of MOF membranes and composites.

  7. Mixed matrix membranes with HF acid etched ZSM-5 for ethanol/water separation: Preparation and pervaporation performance

    Science.gov (United States)

    Zhan, Xia; Lu, Juan; Tan, Tingting; Li, Jiding

    2012-10-01

    The mixed matrix membranes (MMMs) were prepared from crosslinked PDMS incorporated with HF acid etched ZSM-5. ZSM-5 zeolite was etched with a series of HF aqueous-acetone solution and characterized by SEM, BET, XRD and FT-IR. It was found that HF etching process was very effective for removing organic impurities in zeolite and micro-pores were observed out of the surface of zeolite particles, which enhanced the hydrophobicity and surface roughness of ZSM-5 successfully. Both tensile strength and swelling resistance of ZSM-5/PDMS MMMs increased with the rising concentration of HF solution, which can mainly be attributed to the improved zeolite-PDMS interfacial adhesion resulted from the intrusion of PDMS into micro-pores out of the ZSM-5 surface. Subsequently, the sorption experiment was performed with the results suggesting preferential sorption of ethanol by MMMs. Moreover, the sorption selectivity of ZSM-5/PDMS MMMs increased notably as the concentration of HF solution increased. The pervaporation performance of ethanol/water mixtures using MMMs was also investigated in detail. The MMMs filled with etched ZSM-5 showed much better selectivity than that filled with non-etched ones, with a little expense of permeability. It was found that with the same zeolite loading, increasing the HF acid concentration in etching process enhanced the zeolite-PDMS interfacial adhesion which promoted the ethanol selectivity of MMMs, while depressed the total permeation flux a little. In addition, both ethanol permeation and the selectivity increased with an increase of the zeolite loading from 10% to 30%. Nevertheless, excessive zeolite loading or decreasing thickness of selective layer led to the poor selectivity to ethanol. A decline of the ethanol selectivity was also observed as the feed ethanol concentration as well as feed temperature increased.

  8. Residues and duality for singularity categories of isolated Gorenstein singularities

    OpenAIRE

    Murfet, Daniel

    2009-01-01

    We study Serre duality in the singularity category of an isolated Gorenstein singularity and find an explicit formula for the duality pairing in terms of generalised fractions and residues. For hypersurfaces we recover the residue formula of the string theorists Kapustin and Li. These results are obtained from an explicit construction of complete injective resolutions of maximal Cohen-Macaulay modules.

  9. Gravitational collapse and naked singularities

    Indian Academy of Sciences (India)

    Recent developments have revealed that there are examples of naked singularity formation in the collapse of physically reasonable matter fields, although the stability of these examples is still uncertain. We propose the concept of `effective naked singularities', which will be quite helpful because general relativity has ...

  10. String theory and cosmological singularities

    Indian Academy of Sciences (India)

    recent times, string theory is providing new perspectives of such singularities which may lead to an understanding of these in the standard framework of time evolution in quantum mechanics. In this article, we describe some of these approaches. Keywords. String theory; cosmological singularities. PACS Nos 11.25.

  11. Singularities and the geometry of spacetime

    Science.gov (United States)

    Hawking, Stephen

    2014-11-01

    the occurrence of singularities are discussed and then a number of theorems are presented which prove the occurrence of singularities in most cosmological solutions. A procedure is given which could be used to describe and classify the singularites and their expected nature is discussed. Sections 2 and 3 are reviews of standard work. In Section 4, the deviation equation is standard but the matrix method used to analyse it is the author's own as is the decomposition given of the Bianchi identities (this was also obtained independently by Trümper). Variation of curves and conjugate points are standard in a positive-definite metric but this seems to be the first full account for timelike and null curves in a Lorentz metric. Except where otherwise indicated in the text, Sections 5 and 6 are the work of the author who, however, apologises if through ignorance or inadvertance he has failed to make acknowledgements where due. Some of this work has been described in [Hawking S.W. 1965b. Occurrence of singularities in open universes. Phys. Rev. Lett. 15: 689-690; Hawking S.W. and G.F.R. Ellis. 1965c. Singularities in homogeneous world models. Phys. Rev. Lett. 17: 246-247; Hawking S.W. 1966a. Singularities in the universe. Phys. Rev. Lett. 17: 444-445; Hawking S.W. 1966c. The occurrence of singularities in cosmology. Proc. Roy. Soc. Lond. A 294: 511-521]. Undoubtedly, the most important results are the theorems in Section 6 on the occurrence of singularities. These seem to imply either that the General Theory of Relativity breaks down or that there could be particles whose histories did not exist before (or after) a certain time. The author's own opinion is that the theory probably does break down, but only when quantum gravitational effects become important. This would not be expected to happen until the radius of curvature of spacetime became about 10-14 cm.

  12. Double parton scattering singularity in one-loop integrals

    Science.gov (United States)

    Gaunt, Jonathan R.; Stirling, W. James

    2011-06-01

    We present a detailed study of the double parton scattering (DPS) singularity, which is a specific type of Landau singularity that can occur in certain one-loop graphs in theories with massless particles. A simple formula for the DPS singular part of a four-point diagram with arbitrary internal/external particles is derived in terms of the transverse momentum integral of a product of light cone wavefunctions with tree-level matrix elements. This is used to reproduce and explain some results for DPS singularities in box integrals that have been obtained using traditional loop integration techniques. The formula can be straightforwardly generalised to calculate the DPS singularity in loops with an arbitrary number of external particles. We use the generalised version to explain why the specific MHV and NMHV six-photon amplitudes often studied by the NLO multileg community are not divergent at the DPS singular point, and point out that whilst all NMHV amplitudes are always finite, certain MHV amplitudes do contain a DPS divergence. It is shown that our framework for calculating DPS divergences in loop diagrams is entirely consistent with the `two-parton GPD' framework of Diehl and Schafer for calculating proton-proton DPS cross sections, but is inconsistent with the `double PDF' framework of Snigirev.

  13. Influence of the non-singular stress on the crack extension and fatigue life

    International Nuclear Information System (INIS)

    Cheng, C.Z.; Recho, N.; Niu, Z.R.

    2012-01-01

    Highlights: ► BEM is combined by characteristic analysis to calculate the singular stress field. ► A new method is proposed to evaluate the full stress field at crack tip region. ► Effect of non-singular stress on the propagation direction of the fatigue crack is analyzed. ► The influence of non-singular stress on the fatigue crack life is evaluated. - Abstract: The complete elasticity stress field at a crack tip region can be presented by the sum of the singular stress and several non-singular stress terms according to the Williams asymptotic expansion theory. The non-singular stress has a non-negligible influence on the prediction of the crack extension direction and crack growth rate under the fatigue loading. A novel method combining the boundary element method and the singularity characteristic analysis is proposed here to evaluate the complete stress field at a crack tip region. In this new method, any non-singular stress term in the Williams series expansion can be evaluated according to the computational accuracy requirement. Then, a modified Paris law is introduced to predict the crack propagation under the mixed-mode loading for exploring the influence of the non-singular stress on the fatigue life duration. By comparing with the existed experimental results, the predicted crack fatigue life when the non-singular stress is taken into consideration is more accurate than the predicted ones only considering the singular stress.

  14. Loop quantum cosmology and singularities.

    Science.gov (United States)

    Struyve, Ward

    2017-08-15

    Loop quantum gravity is believed to eliminate singularities such as the big bang and big crunch singularity. This belief is based on studies of so-called loop quantum cosmology which concerns symmetry-reduced models of quantum gravity. In this paper, the problem of singularities is analysed in the context of the Bohmian formulation of loop quantum cosmology. In this formulation there is an actual metric in addition to the wave function, which evolves stochastically (rather than deterministically as the case of the particle evolution in non-relativistic Bohmian mechanics). Thus a singularity occurs whenever this actual metric is singular. It is shown that in the loop quantum cosmology for a homogeneous and isotropic Friedmann-Lemaître-Robertson-Walker space-time with arbitrary constant spatial curvature and cosmological constant, coupled to a massless homogeneous scalar field, a big bang or big crunch singularity is never obtained. This should be contrasted with the fact that in the Bohmian formulation of the Wheeler-DeWitt theory singularities may exist.

  15. The theory of singular perturbations

    CERN Document Server

    De Jager, E M

    1996-01-01

    The subject of this textbook is the mathematical theory of singular perturbations, which despite its respectable history is still in a state of vigorous development. Singular perturbations of cumulative and of boundary layer type are presented. Attention has been given to composite expansions of solutions of initial and boundary value problems for ordinary and partial differential equations, linear as well as quasilinear; also turning points are discussed. The main emphasis lies on several methods of approximation for solutions of singularly perturbed differential equations and on the mathemat

  16. Evaluation of Aerosol Mixing State Classes in the GISS Modele-matrix Climate Model Using Single-particle Mass Spectrometry Measurements

    Science.gov (United States)

    Bauer, Susanne E.; Ault, Andrew; Prather, Kimberly A.

    2013-01-01

    Aerosol particles in the atmosphere are composed of multiple chemical species. The aerosol mixing state, which describes how chemical species are mixed at the single-particle level, provides critical information on microphysical characteristics that determine the interaction of aerosols with the climate system. The evaluation of mixing state has become the next challenge. This study uses aerosol time-of-flight mass spectrometry (ATOFMS) data and compares the results to those of the Goddard Institute for Space Studies modelE-MATRIX (Multiconfiguration Aerosol TRacker of mIXing state) model, a global climate model that includes a detailed aerosol microphysical scheme. We use data from field campaigns that examine a variety of air mass regimens (urban, rural, and maritime). At all locations, polluted areas in California (Riverside, La Jolla, and Long Beach), a remote location in the Sierra Nevada Mountains (Sugar Pine) and observations from Jeju (South Korea), the majority of aerosol species are internally mixed. Coarse aerosol particles, those above 1 micron, are typically aged, such as coated dust or reacted sea-salt particles. Particles below 1 micron contain large fractions of organic material, internally-mixed with sulfate and black carbon, and few external mixtures. We conclude that observations taken over multiple weeks characterize typical air mass types at a given location well; however, due to the instrumentation, we could not evaluate mass budgets. These results represent the first detailed comparison of single-particle mixing states in a global climate model with real-time single-particle mass spectrometry data, an important step in improving the representation of mixing state in global climate models.

  17. Singular traces theory and applications

    CERN Document Server

    Sukochev, Fedor; Zanin, Dmitriy

    2012-01-01

    This text is the first complete study and monograph dedicated to singular traces. For mathematical readers the text offers, due to Nigel Kalton's contribution, a complete theory of traces on symmetrically normed ideals of compact operators. For mathematical physicists and other users of Connes' noncommutative geometry the text offers a complete reference to Dixmier traces and the deeper mathematical features of singular traces. An application section explores the consequences of these features, which previously were not discussed in general texts on noncommutative geometry.

  18. Form of phytosterols and food matrix in which they are incorporated modulate their incorporation into mixed micelles and impact cholesterol micellarization.

    Science.gov (United States)

    Gleize, Béatrice; Nowicki, Marion; Daval, Christophe; Koutnikova, Hana; Borel, Patrick

    2016-04-01

    The ability of different plant sterols/stanols (PS) mixtures, which differed in the degree of B-ring saturation and aliphatic side chain structure and saturation, to reduce cholesterol (CH) micellarization was explored. Experiments were performed using an in vitro digestion model, synthetic mixed micelles, and pure porcine pancreatic lipases. Sterols were measured by GC-FID. The ability of PS to reduce CH micellarization was dependent on the form of PS and on the type of delivery matrix (low-fat yogurt or olive oil). Long-chain PS esters delivered in the yogurt matrix, and medium chain PS esters delivered in olive oil provided the greatest reduction in CH micellarization. In yogurt, the ability to impair CH micellarization was inversely related (rho = -0.41, p < 0.0005) to PS melting point. In olive oil, the more hydrophobic PS mixtures, i.e. those rich in long-chain PS esters, had the lower ability to impair CH micellarization. Different forms of PS have a different ability to impair CH micellarization. This ability depends on the transfer efficiency of PS from the food matrix to the micelle, which in turn depends on the melting point and the hydrophobicity of PS and on the delivery food matrix. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  19. Dynkin graphs and quadrilateral singularities

    CERN Document Server

    Urabe, Tohsuke

    1993-01-01

    The study of hypersurface quadrilateral singularities can be reduced to the study of elliptic K3 surfaces with a singular fiber of type I * 0 (superscript *, subscript 0), and therefore these notes consider, besides the topics of the title, such K3 surfaces too. The combinations of rational double points that can occur on fibers in the semi-universal deformations of quadrilateral singularities are examined, to show that the possible combinations can be described by a certain law from the viewpoint of Dynkin graphs. This is equivalent to saying that the possible combinations of singular fibers in elliptic K3 surfaces with a singular fiber of type I * 0 (superscript *, subscript 0) can be described by a certain law using classical Dynkin graphs appearing in the theory of semi-simple Lie groups. Further, a similar description for thecombination of singularities on plane sextic curves is given. Standard knowledge of algebraic geometry at the level of graduate students is expected. A new method based on graphs wil...

  20. 787 Singularities in

    Indian Academy of Sciences (India)

    IAS Admin

    Two themes with a strong geometric content, relating to the work of Vladimir Arnold. The upper figure shows his famous 'cat map' which illus- trates how a simple, reversible transformation of the plane applied to a rather orderly figure (a cat) can apparently create a fully mixed figure. The lower panel shows how a simple rule ...

  1. Neutral kaon mixing beyond the Standard Model with nf=2+1 chiral fermions. Part 1: bare matrix elements and physical results

    International Nuclear Information System (INIS)

    Garron, Nicolas; Hudspith, Renwick J.; Lytle, Andrew T.

    2016-01-01

    We compute the hadronic matrix elements of the four-quark operators relevant for K 0 −K̄ 0 mixing beyond the Standard Model. Our results are from lattice QCD simulations with n f =2+1 flavours of domain-wall fermion, which exhibit continuum-like chiral-flavour symmetry. The simulations are performed at two different values of the lattice spacing (a∼0.08 and a∼0.11 fm) and with lightest unitary pion mass ∼300 MeV. For the first time, the full set of relevant four-quark operators is renormalised non-perturbatively through RI-SMOM schemes; a detailed description of the renormalisation procedure is presented in a companion paper. We argue that the intermediate renormalisation scheme is responsible for the discrepancies found by different collaborations. We also study different normalisations and determine the matrix elements of the relevant four-quark operators with a precision of ∼5% or better.

  2. Local and nonlocal space-time singularities

    International Nuclear Information System (INIS)

    Konstantinov, M.Yu.

    1985-01-01

    The necessity to subdivide the singularities into two classes: local and nonlocal, each of them to be defined independently, is proved. Both classes of the singularities are defined, and the relation between the definitions introduced and the standard definition of singularities, based on space-time, incompleteness, is established. The relation between definitions introduced and theorems on the singularity existence is also established

  3. A Comparison on Gas Separation between PES(polyethersulfone)/MMT (Na-montmorillonite) and PES/TiO2 Mixed Matrix Membranes

    Czech Academy of Sciences Publication Activity Database

    Liang, Ch.-Y.; Uchytil, Petr; Petričkovič, Roman; Lai, Y.-Ch.; Friess, K.; Šípek, M.; Reddy, M.M.; Suen, S.-Y.

    2012-01-01

    Roč. 92, MAY 18 (2012), s. 57-63 ISSN 1383-5866 R&D Projects: GA ČR GCP106/10/J038 Grant - others:NSCT(TW) NSC:99-2911-I-005-002; NSCT(TW) NSC:99-2923-E-005-001-MY2 Institutional research plan: CEZ:AV0Z40720504 Keywords : mixed matrix membrane * polyethersulfone membrane * sodium montmorillonite Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 2.894, year: 2012

  4. Numerical stability of the Saul'yev finite difference algorithms for electrochemical kinetic simulations: Matrix stability analysis for an example problem involving mixed boundary conditions

    DEFF Research Database (Denmark)

    Bieniasz, Leslaw K.; Østerby, Ole; Britz, Dieter

    1995-01-01

    The stepwise numerical stability of the Saul'yev finite difference discretization of an example diffusional initial boundary value problem from electrochemical kinetics has been investigated using the matrix method of stability analysis. Special attention has been paid to the effect...... of unconditional stability of the Saul'yev algorithms, reported in the literature, the left-right variant of the Saul'yev algorithm becomes unstable for large values of the dimensionless diffusion parameter λ = δt/h2, under mixed boundary conditions. This limitation is not, however, severe for most practical...

  5. Analysis of scintigrams by singular value decomposition (SVD) technique

    Energy Technology Data Exchange (ETDEWEB)

    Savolainen, S.E.; Liewendahl, B.K. (Helsinki Univ. (Finland). Dept. of Physics)

    1994-05-01

    The singular value decomposition (SVD) method is presented as a potential tool for analyzing gamma camera images. Mathematically image analysis is a study of matrixes as the standard scintigram is a digitized matrix presentation of the recorded photon fluence from radioactivity of the object. Each matrix element (pixel) consists of a number, which equals the detected counts of the object position. The analysis of images can be reduced to the analysis of the singular values of the matrix decomposition. In the present study the clinical usefulness of SVD was tested by analyzing two different kinds of scintigrams: brain images by single photon emission tomography (SPET), and liver and spleen planar images. It is concluded that SVD can be applied to the analysis of gamma camera images, and that it provides an objective method for interpretation of clinically relevant information contained in the images. In image filtering, SVD provides results comparable to conventional filtering. In addition, the study of singular values can be used for semiquantitation of radionuclide images as exemplified by brain SPET studies and liver-spleen planar studies. (author).

  6. Embedding Dimension Selection for Adaptive Singular Spectrum Analysis of EEG Signal

    Directory of Open Access Journals (Sweden)

    Shanzhi Xu

    2018-02-01

    Full Text Available The recorded electroencephalography (EEG signal is often contaminated with different kinds of artifacts and noise. Singular spectrum analysis (SSA is a powerful tool for extracting the brain rhythm from a noisy EEG signal. By analyzing the frequency characteristics of the reconstructed component (RC and the change rate in the trace of the Toeplitz matrix, it is demonstrated that the embedding dimension is related to the frequency bandwidth of each reconstructed component, in consistence with the component mixing in the singular value decomposition step. A method for selecting the embedding dimension is thereby proposed and verified by simulated EEG signal based on the Markov Process Amplitude (MPA EEG Model. Real EEG signal is also collected from the experimental subjects under both eyes-open and eyes-closed conditions. The experimental results show that based on the embedding dimension selection method, the alpha rhythm can be extracted from the real EEG signal by the adaptive SSA, which can be effectively utilized to distinguish between the eyes-open and eyes-closed states.

  7. Brane singularities and their avoidance

    International Nuclear Information System (INIS)

    Antoniadis, Ignatios; Cotsakis, Spiros; Klaoudatou, Ifigeneia

    2010-01-01

    The singularity structure and the corresponding asymptotic behavior of a 3-brane coupled to a scalar field or to a perfect fluid in a five-dimensional bulk is analyzed in full generality using the method of asymptotic splittings. In the case of the scalar field, it is shown that the collapse singularity at a finite distance from the brane can be avoided only at the expense of making the brane world-volume positively or negatively curved. In the case where the bulk field content is parametrized by an analog of perfect fluid with an arbitrary equation of state P = γρ between the 'pressure' P and the 'density' ρ, our results depend crucially on the constant fluid parameter γ. (i) For γ > -1/2, the flat brane solution suffers from a collapse singularity at a finite distance that disappears in the curved case. (ii) For γ < -1, the singularity cannot be avoided and it becomes of the big rip type for a flat brane. (iii) For -1 < γ ≤ -1/2, the surprising result is found that while the curved brane solution is singular, the flat brane is not, opening the possibility for a revival of the self-tuning proposal.

  8. Mesoporous Silica Gel–Based Mixed Matrix Membranes for Improving Mass Transfer in Forward Osmosis: Effect of Pore Size of Filler

    Science.gov (United States)

    Lee, Jian-Yuan; Wang, Yining; Tang, Chuyang Y.; Huo, Fengwei

    2015-01-01

    The efficiency of forward osmosis (FO) process is generally limited by the internal concentration polarization (ICP) of solutes inside its porous substrate. In this study, mesoporous silica gel (SG) with nominal pore size ranging from 4–30 nm was used as fillers to prepare SG-based mixed matrix substrates. The resulting mixed matrix membranes had significantly reduced structural parameter and enhanced membrane water permeability as a result of the improved surface porosity of the substrates. An optimal filler pore size of ~9 nm was observed. This is in direct contrast to the case of thin film nanocomposite membranes, where microporous nanoparticle fillers are loaded to the membrane rejection layer and are designed in such a way that these fillers are able to retain solutes while allowing water to permeate through them. In the current study, the mesoporous fillers are designed as channels to both water and solute molecules. FO performance was enhanced at increasing filler pore size up to 9 nm due to the lower hydraulic resistance of the fillers. Nevertheless, further increasing filler pore size to 30 nm was accompanied with reduced FO efficiency, which can be attributed to the intrusion of polymer dope into the filler pores. PMID:26592565

  9. Mixed-Matrix Membranes for CO2 and H2 Gas Separations Using Metal-Organic Framework and Mesoporus Hybrid Silicas

    International Nuclear Information System (INIS)

    Musselman, Inga; Balkus, Kenneth Jr.; Ferraris, John

    2009-01-01

    In this work, we have investigated the separation performance of polymer-based mixed-matrix membranes containing metal-organic frameworks and mesoporous hybrid silicas. The MOF/Matrimid(reg s ign) and MOP-18/Matrimid(reg s ign) membranes exhibited improved dispersion and mechanical strength that allowed high additive loadings with reduced aggregation, as is the case of the 80 wt% MOP-18/Matrimid(reg s ign) and the 80% (w/w) Cu-MOF/Matrimid(reg s ign) membranes. Membranes with up to 60% (w/w) ZIF-8 content exhibited similar mechanical strength and improved dispersion. The H 2 /CO 2 separation properties of MOF/Matrimid(reg s ign) mixed-matrix membranes was improved by either keeping the selectivity constant and increasing the permeability (MOF-5, Cu-MOF) or by improving both selectivity and permeability (ZIF-8). In the case of MOF-5/Matrimid(reg s ign) mixed-matrix membranes, the H 2 /CO 2 selectivity was kept at 2.6 and the H 2 permeability increased from 24.4 to 53.8 Barrers. For the Cu-MOF/Matrimid(reg s ign) mixed-matrix membranes, the H 2 /CO 2 selectivity was kept at 2.05 and the H 2 permeability increased from 17.1 to 158 Barrers. These two materials introduced porosity and uniform paths that enhanced the gas transport in the membranes. When ZIF-8/Matrimid(reg s ign) mixed-matrix membranes were studied, the H 2 /CO 2 selectivity increased from 2.9 to 4.4 and the permeability of H 2 increased from 26.5 to 35.8 Barrers. The increased H 2 /CO 2 selectivity in ZIF-8/Matrimid(reg s ign) membranes was explained by the sieving effect introduced by the ZIF-8 crystals (pore window 0.34 nm) that restricted the transport of molecules larger than H 2 . Materials with microporous and/or mesoporous cavities like carbon aerogel composites with zeolite A and zeolite Y, and membranes containing mesoporous ZSM-5 showed sieving effects for small molecules (e.g. H 2 and CO 2 ), however, the membranes were most selective for CO 2 due to the strong interaction of the zeolites with

  10. A Mixed Matrix Membrane of Poly (4-methyl-1-pentyne Filled with MIL 53 Particles and Its Application in Carbon Dioxide and Nitrogen Separation

    Directory of Open Access Journals (Sweden)

    Reza Abedini

    2016-05-01

    Full Text Available The performance of poly (4-metyl-1-pentyne as mixed matrix membrane (MMM mixed with MIL 53 particles was studied to separate mixtures of carbon dioxide and nitrogen. MIL 53 particles was added to the polymer matrix with 10, 20 and 30 weight percentages. The adsorption of CO2 and N2 gases by MIL 53 was evaluated and the adsorption data was analyzed by Langmuir equation. Structure and thermal/mechanical properties of prepared membranes were characterized by means of FTIR, SEM, TGA and elongation test. Moreover, the gas permeation properties of membranes were studied by measuring the permeation of pure CO2 and N2. Furthermore, for accurate understanding of the gas permeation properties of the membranes, diffusion and solution coefficient of gases in neat membrane and MMMs were calculated using modified time-lag method. The results from TGA analysis showed that the degradation temperature of MMMs was enhanced and increased to 348ºC for membrane containing 30 wt% of MIL 53. The SEM images also illustrated a relatively uniform dispersion of particles with proper polymer/filler interfaces in the polymer matrix. The gas permeation results revealed that the permeability of both gases (especially CO2 increased with increasing MIL 53 loading, in which the permeability of CO2 increased from 98.74 Barrer in neat membrane to 217.65 Barrer in MMM containing 30 wt% filler. Moreover, calculation of CO2/N2 selectivity depicted that the selectivity enhanced from 16.66 to 22.70. Finally, the performance of MMMs was compared with Robeson’s upper bound in CO2/N2 separation and results showed that the MMM having 30 wt% of MIL 53 took over the Robeson bound.

  11. A 1 + 5-dimensional gravitational-wave solution. Curvature singularity and spacetime singularity

    International Nuclear Information System (INIS)

    Chen, Yu-Zhu; Li, Wen-Du; Dai, Wu-Sheng

    2017-01-01

    We solve a 1 + 5-dimensional cylindrical gravitational-wave solution of the Einstein equation, in which there are two curvature singularities. Then we show that one of the curvature singularities can be removed by an extension of the spacetime. The result exemplifies that the curvature singularity is not always a spacetime singularity; in other words, the curvature singularity cannot serve as a criterion for spacetime singularities. (orig.)

  12. A 1 + 5-dimensional gravitational-wave solution. Curvature singularity and spacetime singularity

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Yu-Zhu [Tianjin University, Department of Physics, Tianjin (China); Li, Wen-Du [Tianjin University, Department of Physics, Tianjin (China); Nankai University, Theoretical Physics Division, Chern Institute of Mathematics, Tianjin (China); Dai, Wu-Sheng [Nankai University, Theoretical Physics Division, Chern Institute of Mathematics, Tianjin (China); Nankai University and Tianjin University, LiuHui Center for Applied Mathematics, Tianjin (China)

    2017-12-15

    We solve a 1 + 5-dimensional cylindrical gravitational-wave solution of the Einstein equation, in which there are two curvature singularities. Then we show that one of the curvature singularities can be removed by an extension of the spacetime. The result exemplifies that the curvature singularity is not always a spacetime singularity; in other words, the curvature singularity cannot serve as a criterion for spacetime singularities. (orig.)

  13. The effect of mixing methods and polymer infiltration and pyrolysis (PIP) cycles on the densification of silicon carbide inert matrix fuel through a polymer precursor route

    International Nuclear Information System (INIS)

    Shih Chunghao; Tulenko, J.S.; Baney, R.H.

    2011-01-01

    Highlights: ► A pre-ceramic polymer precursor route was utilized to fabricate SiC based inert matrix fuel (IMF). ► The effect of mixing and polymer infiltration and pyrolysis (PIP) cycles on the fabrication of the SiC IMF was investigated. ► A theoretical density of ∼86% has been achieved after one PIP cycle. ► Pore size distributions before and after PIP cycles have been determined. ► SEM images showed a “springback” effect for 600 MPa pressed pellets. - Abstract: The effect of mixing methods on the fabrication of silicon carbide (SiC) inert matrix fuel through a polymer precursor route was investigated in order to break up the agglomerates of the SiC particles observed in earlier studies. It was found that a high energy shaker mill could effectively break up the agglomerates and thereby achieve a higher pellet density. Moreover, it was found that the pellet density depended less on the pressing pressure, when the particles are well mixed. SEM images showed cracks caused by the springback effect on pellets with a high cold pressing pressure of 600 MPa, but no signs of springback effect were observed for the 200 MPa pressed pellets. The polymer infiltration and pyrolysis (PIP) cycles were used to further increase the pellet density and close the open pores. The first PIP cycle was found to increase the theoretical density of the pellets from 81.2% to 86.0% and close ∼50% of the open pores. The pore size distribution showed that most of the remaining open pores had diameters smaller than 10 nm. The successive second PIP cycle is not as effective on either the density or the pore size distribution because the small pores present before the second PIP cycle made the infiltration process difficult.

  14. Ambient cosmology and spacetime singularities

    CERN Document Server

    Antoniadis, Ignatios

    2015-01-01

    We present a new approach to the issues of spacetime singularities and cosmic censorship in general relativity. This is based on the idea that standard 4-dimensional spacetime is the conformal infinity of an ambient metric for the 5-dimensional Einstein equations with fluid sources. We then find that the existence of spacetime singularities in four dimensions is constrained by asymptotic properties of the ambient 5-metric, while the non-degeneracy of the latter crucially depends on cosmic censorship holding on the boundary.

  15. Singularity Theory and its Applications

    CERN Document Server

    Stewart, Ian; Mond, David; Montaldi, James

    1991-01-01

    A workshop on Singularities, Bifuraction and Dynamics was held at Warwick in July 1989, as part of a year-long symposium on Singularity Theory and its applications. The proceedings fall into two halves: Volume I mainly on connections with algebraic geometry and volume II on connections with dynamical systems theory, bifurcation theory and applications in the sciences. The papers are original research, stimulated by the symposium and workshop: All have been refereed and none will appear elsewhere. The main topic of volume II is new methods for the study of bifurcations in nonlinear dynamical systems, and applications of these.

  16. Ambient cosmology and spacetime singularities

    Energy Technology Data Exchange (ETDEWEB)

    Antoniadis, Ignatios [Bern University, Albert Einstein Center for Fundamental Physics, Institute for Theoretical Physics, Bern (Switzerland); Ecole Polytechnique, Palaiseau (France); Cotsakis, Spiros [CERN, Theory Division, Department of Physics, Geneva 23 (Switzerland); National Technical University, School of Applied Mathematics and Physical Sciences, Athens (Greece)

    2015-01-01

    We present a new approach to the issues of spacetime singularities and cosmic censorship in general relativity. This is based on the idea that standard 4-dimensional spacetime is the conformal infinity of an ambient metric for the 5-dimensional Einstein equations with fluid sources. We then find that the existence of spacetime singularities in four dimensions is constrained by asymptotic properties of the ambient 5-metric, while the non-degeneracy of the latter crucially depends on cosmic censorship holding on the boundary. (orig.)

  17. Monodromy of a two degrees of freedom Liouville integrable system with many focus-focus singular points

    International Nuclear Information System (INIS)

    Cushman, Richard; Zhilinskii, Boris

    2002-01-01

    This letter deals with the global monodromy of singular Lagrangian toral fibrations defined by two degrees of freedom Liouville integrable systems with only focus-focus singular points. We show that any global monodromy matrix in Sl(2,Ζ ) is realizable by such a system. (author). Letter-to-the-editor

  18. Biplot and Singular Value Decomposition Macros for Excel©

    OpenAIRE

    Lipkovich, Ilya A.; Smith, Eric P.

    2002-01-01

    The biplot display is a graph of row and column markers obtained from data that forms a two-way table. The markers are calculated from the singular value decomposition of the data matrix. The biplot display may be used with many multivariate methods to display relationships between variables and objects. It is commonly used in ecological applications to plot relationships between species and sites. This paper describes a set of Excel macros that may be used to draw a biplot display based ...

  19. Parallelism in matrix computations

    CERN Document Server

    Gallopoulos, Efstratios; Sameh, Ahmed H

    2016-01-01

    This book is primarily intended as a research monograph that could also be used in graduate courses for the design of parallel algorithms in matrix computations. It assumes general but not extensive knowledge of numerical linear algebra, parallel architectures, and parallel programming paradigms. The book consists of four parts: (I) Basics; (II) Dense and Special Matrix Computations; (III) Sparse Matrix Computations; and (IV) Matrix functions and characteristics. Part I deals with parallel programming paradigms and fundamental kernels, including reordering schemes for sparse matrices. Part II is devoted to dense matrix computations such as parallel algorithms for solving linear systems, linear least squares, the symmetric algebraic eigenvalue problem, and the singular-value decomposition. It also deals with the development of parallel algorithms for special linear systems such as banded ,Vandermonde ,Toeplitz ,and block Toeplitz systems. Part III addresses sparse matrix computations: (a) the development of pa...

  20. A matrix big bang

    Science.gov (United States)

    Craps, Ben; Sethi, Savdeep; Verlinde, Erik

    2005-10-01

    The light-like linear dilaton background represents a particularly simple time-dependent 1/2 BPS solution of critical type-IIA superstring theory in ten dimensions. Its lift to M-theory, as well as its Einstein frame metric, are singular in the sense that the geometry is geodesically incomplete and the Riemann tensor diverges along a light-like subspace of codimension one. We study this background as a model for a big bang type singularity in string theory/M-theory. We construct the dual Matrix theory description in terms of a (1+1)-d supersymmetric Yang-Mills theory on a time-dependent world-sheet given by the Milne orbifold of (1+1)-d Minkowski space. Our model provides a framework in which the physics of the singularity appears to be under control.

  1. A matrix big bang

    International Nuclear Information System (INIS)

    Craps, Ben; Sethi, Savdeep; Verlinde, Erik

    2005-01-01

    The light-like linear dilaton background represents a particularly simple time-dependent 1/2 BPS solution of critical type-IIA superstring theory in ten dimensions. Its lift to M-theory, as well as its Einstein frame metric, are singular in the sense that the geometry is geodesically incomplete and the Riemann tensor diverges along a light-like subspace of codimension one. We study this background as a model for a big bang type singularity in string theory/M-theory. We construct the dual Matrix theory description in terms of a (1+1)-d supersymmetric Yang-Mills theory on a time-dependent world-sheet given by the Milne orbifold of (1+1)-d Minkowski space. Our model provides a framework in which the physics of the singularity appears to be under control

  2. A matrix big bang

    Energy Technology Data Exchange (ETDEWEB)

    Craps, Ben [Instituut voor Theoretische Fysica, Universiteit van Amsterdam, Valckenierstraat 65, 1018 XE Amsterdam (Netherlands); Sethi, Savdeep [Enrico Fermi Institute, University of Chicago, Chicago, IL 60637 (United States); Verlinde, Erik [Instituut voor Theoretische Fysica, Universiteit van Amsterdam, Valckenierstraat 65, 1018 XE Amsterdam (Netherlands)

    2005-10-15

    The light-like linear dilaton background represents a particularly simple time-dependent 1/2 BPS solution of critical type-IIA superstring theory in ten dimensions. Its lift to M-theory, as well as its Einstein frame metric, are singular in the sense that the geometry is geodesically incomplete and the Riemann tensor diverges along a light-like subspace of codimension one. We study this background as a model for a big bang type singularity in string theory/M-theory. We construct the dual Matrix theory description in terms of a (1+1)-d supersymmetric Yang-Mills theory on a time-dependent world-sheet given by the Milne orbifold of (1+1)-d Minkowski space. Our model provides a framework in which the physics of the singularity appears to be under control.

  3. Mixed fertilizers incorporated in organic polimer matrix and pressed in tablets as means of enhancing the nutrients productive use in increased crop yields

    International Nuclear Information System (INIS)

    Gavriluta, I.; Borlan, Z.; Alexandrescu, A; Budoi, G.; Bireescu, L.; Bireescu, G.

    1999-01-01

    In view of increasing productive use of fertilizer nutrients in crops an admixture of brown coal dust containing up to 40 % carbon ammonia lignosulfonate with 50 % lignoles dry matter as binding agent were used to press water soluble fertilizer sources with a total of N+P 2 O 5 +K 2 O content of up to 26 % in tablets. These may be manufactured at different N:P 2 O 5 :K 2 O ratios as for instance 1:1:1; 1:0.75:0.50 etc. Brown coal and coal refuse dust were used as matrix for inclusion while lignosulfonates served for binding the ingredients when pressing them in tablets of 15-20 g dry mass each. These were tested in accurate field experiments to compare the agronomic effectiveness of equal amounts of NPK in tablets with equivalent rates of powdered sources of nutrients in the same chemical forms. NPK pressed in tablets were applied locally along the plant row, while the powdered mixed fertilizer have been thoroughly mixed in the ploughed layer. Accurate field experiments have pointed out the higher agronomical effectiveness of NPK pressed in tablets as compared to equal amounts of NPK powdered and thoroughly mixed into the ploughed layer of soil. Indicators were higher yield increases per nutrient unit and higher degrees of apparent productive use of nutrients in crops. Refs. 4 (author)

  4. The Relaxation Matrix for Symmetric Tops with Inversion Symmetry. II; Line Mixing Effects in the V1 Band of NH3

    Science.gov (United States)

    Boulet, C.; Ma, Q.

    2016-01-01

    Line mixing effects have been calculated in the ?1 parallel band of self-broadened NH3. The theoretical approach is an extension of a semi-classical model to symmetric-top molecules with inversion symmetry developed in the companion paper [Q. Ma and C. Boulet, J. Chem. Phys. 144, 224303 (2016)]. This model takes into account line coupling effects and hence enables the calculation of the entire relaxation matrix. A detailed analysis of the various coupling mechanisms is carried out for Q and R inversion doublets. The model has been applied to the calculation of the shape of the Q branch and of some R manifolds for which an obvious signature of line mixing effects has been experimentally demonstrated. Comparisons with measurements show that the present formalism leads to an accurate prediction of the available experimental line shapes. Discrepancies between the experimental and theoretical sets of first order mixing parameters are discussed as well as some extensions of both theory and experiment.

  5. Dirac CP phase in the neutrino mixing matrix and the Froggatt-Nielsen mechanism with det[Mν]=0

    Science.gov (United States)

    Kaneta, Yuya; Tanimoto, Morimitsu; Yanagida, Tsutomu T.

    2017-07-01

    We discuss the Dirac CP violating phase δCP in the Froggatt-Nielsen model for a neutrino mass matrix Mν imposing a condition det [Mν ] = 0. This additional condition restricts the CP violating phase δCP drastically. We find that the phase δCP is predicted in the region of ± (0.4- 2.9) radian, which is consistent with the recent T2K and NOνA data. There is a remarkable correlation between δCP and sin2 ⁡θ23. The phase δCP converges to ∼ ± π / 2 if sin2 ⁡θ23 is larger than 0.5. Thus, the accurate measurement of sin2 ⁡θ23 is important for a test of our model. The effective mass mee for the neutrinoless double beta decay is predicted in the rage 3.3-4.0 meV.

  6. Gravitational collapse and naked singularities

    Indian Academy of Sciences (India)

    We propose the concept of 'effective naked singularities', which will be quite helpful ... If a pressure gradient force is not sufficiently strong, a body can continue collapsing due to its self-gravity. This phenomenon is called gravitational collapse. .... approaches a self-similar solution, which is called a critical solution, and then it.

  7. Gravitational collapse and naked singularities

    Indian Academy of Sciences (India)

    Abstract. Gravitational collapse is one of the most striking phenomena in gravitational physics. The cosmic censorship conjecture has provided strong motivation for research in this field. In the absence of a general proof for censorship, many examples have been proposed, in which naked singularity is the outcome of ...

  8. Singularity: Raychaudhuri equation once again

    Indian Academy of Sciences (India)

    birth of the Universe in a Big Bang. Nothing could be happier and more persuasive than the observation verifying the prediction of theory. This gave rise to a general belief that singularities were inevitable in general relativity (GR) so long as the dynamics were governed by Einstein's equations and more over positive energy ...

  9. String theory and cosmological singularities

    Indian Academy of Sciences (India)

    of space and time needs revision near these singularities where quantum effects of gravity become important, it is still not clear what structure could replace space ..... The dimensionful parameter μ is a Lagrange multiplier which ensures that the total number of eigenvalues is fixed. 98. Pramana – J. Phys., Vol. 69, No. 1, July ...

  10. Analysis and design of singular Markovian jump systems

    CERN Document Server

    Wang, Guoliang; Yan, Xinggang

    2014-01-01

    This monograph is an up-to-date presentation of the analysis and design of singular Markovian jump systems (SMJSs) in which the transition rate matrix of the underlying systems is generally uncertain, partially unknown and designed. The problems addressed include stability, stabilization, H∞ control and filtering, observer design, and adaptive control. applications of Markov process are investigated by using Lyapunov theory, linear matrix inequalities (LMIs), S-procedure and the stochastic Barbalat's Lemma, among other techniques.Features of the book include:·???????? study of the stability pr

  11. Predictive error dependencies when using pilot points and singular value decomposition in groundwater model calibration

    DEFF Research Database (Denmark)

    Christensen, Steen; Doherty, John

    2008-01-01

    over the model area. Singular value decomposition (SVD) of the (possibly weighted) sensitivity matrix of the pilot point based model produces eigenvectors of which we pick a small number corresponding to significant eigenvalues. Super parameters are defined as factors through which parameter...... nonlinear functions. Recommendations concerning the use of pilot points and singular value decomposition in real-world groundwater model calibration are finally given. (c) 2008 Elsevier Ltd. All rights reserved....

  12. Remarks on gauge variables and singular Lagrangians

    International Nuclear Information System (INIS)

    Chela-Flores, J.; Janica-de-la-Torre, R.; Kalnay, A.J.; Rodriguez-Gomez, J.; Rodriguez-Nunez, J.; Tascon, R.

    1977-01-01

    The relevance is discussed of gauge theory, based on a singular Lagrangian density, to the foundations of field theory. The idea that gauge transformations could change the physics of systems where the Lagrangian is singular is examined. (author)

  13. Effective enhancement of gas separation performance in mixed matrix membranes using core/shell structured multi-walled carbon nanotube/graphene oxide nanoribbons

    Science.gov (United States)

    Xue, Qingzhong; Pan, Xinglong; Li, Xiaofang; Zhang, Jianqiang; Guo, Qikai

    2017-02-01

    Novel core/shell structured multi-walled carbon nanotube/graphene oxide nanoribbons (MWCNT@GONRs) nanohybrids were successfully prepared using a modified chemical longitudinal unzipping method. Subsequently, the MWCNT@GONRs nanohybrids were used as fillers to enhance the gas separation performance of polyimide based mixed matrix membranes (MMMs). It is found that MMMs concurrently exhibited higher gas selectivity and higher gas permeability compared to pristine polyimide. The high gas selectivity could be attributed to the GONRs shell, which provided a selective barrier and large gas adsorbed area, while the high gas permeability resulted from the hollow structured MWCNTs core with smooth internal surface, which acted as a rapid transport channel. MWCNT@GONRs could be promising candidates to improve gas separation performance of MMMs due to the unique microstructures, ease of synthesis and low filling loading.

  14. Modeling and multi-objective optimization of powder mixed electric discharge machining process of aluminum/alumina metal matrix composite

    Directory of Open Access Journals (Sweden)

    Gangadharudu Talla

    2015-09-01

    Full Text Available Low material removal rate (MRR and high surface roughness values hinder large-scale application of electro discharge machining (EDM in the fields like automobile, aerospace and medical industry. In recent years, however, EDM has gained more significance in these industries as the usage of difficult-to-machine materials including metal matrix composites (MMCs increased. In the present work, an attempt has been made to fabricate and machine aluminum/alumina MMC using EDM by adding aluminum powder in kerosene dielectric. Results showed an increase in MRR and decrease in surface roughness (Ra compared to those for conventional EDM. Semi empirical models for MRR and Ra based on machining parameters and important thermo physical properties were established using a hybrid approach of dimensional and regression analysis. A multi response optimization was also performed using principal component analysis-based grey technique (Grey-PCA to determine optimum settings of process parameters for maximum MRR and minimum Ra within the experimental range. The recommended setting of process parameters for the proposed process has been found to be powder concentration (Cp = 4 g/l, peak current (Ip = 3 A, pulse on time (Ton = 150 μs and duty cycle (Tau = 85%.

  15. Review of singular potential integrals for method of moments solutions of surface integral equations

    Directory of Open Access Journals (Sweden)

    A. Tzoulis

    2004-01-01

    Full Text Available Accurate evaluation of singular potential integrals is essential for successful method of moments (MoM solutions of surface integral equations. In mixed potential formulations for metallic and dielectric scatterers, kernels with 1/R and r1/R singularities must be considered. Several techniques for the treatment of these singularities will be reviewed. The most common approach solves the MoM source integrals analytically for specific observation points, thus regularizing the integral. However, in the case of r1/R a logarithmic singularity remains for which numerical evaluation of the testing integral is still difficult. A recently by Yl¨a-Oijala and Taskinen proposed remedy to this issue is discussed and evaluated within a hybrid finite element – boundary integral technique. Convergence results for the MoM coupling integrals are presented where also higher-order singularity extraction is considered.

  16. Singularities and Conjugate Points in FLRW Spacetimes

    NARCIS (Netherlands)

    Lam, Huibert het; Prokopec, Tom

    2017-01-01

    Conjugate points play an important role in the proofs of the singularity theorems of Hawking and Penrose. We examine the relation between singularities and conjugate points in FLRW spacetimes with a singularity. In particular we prove a theorem that when a non-comoving, non-spacelike geodesic in a

  17. Analysis of singularity in redundant manipulators

    International Nuclear Information System (INIS)

    Watanabe, Koichi

    2000-03-01

    In the analysis of arm positions and configurations of redundant manipulators, the singularity avoidance problems are important themes. This report presents singularity avoidance computations of a 7 DOF manipulator by using a computer code based on human-arm models. The behavior of the arm escaping from the singular point can be identified satisfactorily through the use of 3-D plotting tools. (author)

  18. Synthesis and Characterisation of ETS-10/Acetate-based Ionic Liquid/Chitosan Mixed Matrix Membranes for CO2/N2 Permeation

    Directory of Open Access Journals (Sweden)

    Clara Casado-Coterillo

    2014-06-01

    Full Text Available Mixed matrix membranes (MMMs were prepared by incorporating organic surfactant-free hydrothermally synthesised ETS-10 and 1-ethyl-3-methylimidazolium acetate ionic liquid (IL to chitosan (CS polymer matrix. The membrane material characteristics and permselectivity performance of the two-component membranes were compared with the three-component membrane and the pure CS membrane. The addition of IL increased CO2 solubility of the polymer, and, thus, the CO2 affinity was maintained for the MMMs, which can be correlated with the crystallinity, measured by FT-IR, and void fraction calculations from differences between theoretical and experimental densities. The mechanical resistance was enhanced by the ETS-10 nanoparticles, and flexibility decreased in the two-component ETS-10/CS MMMs, but the flexibility imparted by the IL remained in three-component ETS-10/IL/CS MMMs. The results of this work provide insight into another way of facing the adhesion challenge in MMMs and obtain CO2 selective MMMs from renewable or green chemistry materials.

  19. Neutral kaon mixing beyond the Standard Model with n{sub f}=2+1 chiral fermions. Part 1: bare matrix elements and physical results

    Energy Technology Data Exchange (ETDEWEB)

    Garron, Nicolas [Theoretical Physics Division, Department of Mathematical Sciences, University of Liverpool,Brownlow Hill, Liverpool, L69 3BX (United Kingdom); Hudspith, Renwick J. [Department of Physics and Astronomy, York University,4700 Keele Street, Toronto, Ontario, M3J 1P3 (Canada); Lytle, Andrew T. [SUPA, School of Physics and Astronomy, University of Glasgow,University Avenue, Glasgow, G12 8QQ (United Kingdom); Collaboration: The RBC/UKQCD collaboration

    2016-11-02

    We compute the hadronic matrix elements of the four-quark operators relevant for K{sup 0}−K̄{sup 0} mixing beyond the Standard Model. Our results are from lattice QCD simulations with n{sub f}=2+1 flavours of domain-wall fermion, which exhibit continuum-like chiral-flavour symmetry. The simulations are performed at two different values of the lattice spacing (a∼0.08 and a∼0.11 fm) and with lightest unitary pion mass ∼300 MeV. For the first time, the full set of relevant four-quark operators is renormalised non-perturbatively through RI-SMOM schemes; a detailed description of the renormalisation procedure is presented in a companion paper. We argue that the intermediate renormalisation scheme is responsible for the discrepancies found by different collaborations. We also study different normalisations and determine the matrix elements of the relevant four-quark operators with a precision of ∼5% or better.

  20. Matrimid-JUC-62 and Matrimid-PCN-250 mixed matrix membranes displaying light-responsive gas separation and beneficial ageing characteristics for CO2/N2 separation.

    Science.gov (United States)

    Prasetya, Nicholaus; Teck, Anastasia A; Ladewig, Bradley P

    2018-02-13

    The performance of two generation-3 light-responsive metal-organic framework (MOF), namely JUC-62 and PCN-250, was investigated in a mixed matrix membrane (MMM) form. Both of them were incorporated inside the matrimid as the polymer matrix. Using our custom-designed membrane testing cell, it was observed that the MMMs showed up to 9% difference in CO 2 permeability between its pristine and UV-irradiated condition. This shows that the light-responsive ability of the light-responsive MOFs could still be maintained. Thus, this finding is applicable in designing a smart material. Apart from that, the MMMs also has the potential to be applied for post-combustion carbon capture. At loadings up to 15 wt%, both CO 2 permeability and CO 2 /N 2 ideal selectivity could be significantly improved and surpassed the value exhibited by most of the MOF-matrimid MMM. Lastly the long term performance of the MMM was also evaluated and it was observed that both MMM could maintain their performance up to 1 month with only a slight decrease in CO 2 permeability observed for 10 wt% PCN-250-matrimid. This study then opens up the possibility to fabricate a novel anti-aging multifunctional membrane material that is applicable as a smart material and also in post combustion carbon capture applications.

  1. Correlation of Gas Permeability in a Metal-Organic Framework MIL-101(Cr)-Polysulfone Mixed-Matrix Membrane with Free Volume Measurements by Positron Annihilation Lifetime Spectroscopy (PALS).

    Science.gov (United States)

    Jeazet, Harold B Tanh; Koschine, Tönjes; Staudt, Claudia; Raetzke, Klaus; Janiak, Christoph

    2013-10-25

    Hydrothermally stable particles of the metal-organic framework MIL-101(Cr) were incorporated into a polysulfone (PSF) matrix to produce mixed-matrix or composite membranes with excellent dispersion of MIL-101 particles and good adhesion within the polymer matrix. Pure gas (O2, N2, CO2 and CH4) permeation tests showed a significant increase of gas permeabilities of the mixed-matrix membranes without any loss in selectivity. Positron annihilation lifetime spectroscopy (PALS) indicated that the increased gas permeability is due to the free volume in the PSF polymer and the added large free volume inside the MIL-101 particles. The trend of the gas transport properties of the composite membranes could be reproduced by a Maxwell model.

  2. Correlation of Gas Permeability in a Metal-Organic Framework MIL-101(Cr)–Polysulfone Mixed-Matrix Membrane with Free Volume Measurements by Positron Annihilation Lifetime Spectroscopy (PALS)

    Science.gov (United States)

    Jeazet, Harold B. Tanh; Koschine, Tönjes; Staudt, Claudia; Raetzke, Klaus; Janiak, Christoph

    2013-01-01

    Hydrothermally stable particles of the metal-organic framework MIL-101(Cr) were incorporated into a polysulfone (PSF) matrix to produce mixed-matrix or composite membranes with excellent dispersion of MIL-101 particles and good adhesion within the polymer matrix. Pure gas (O2, N2, CO2 and CH4) permeation tests showed a significant increase of gas permeabilities of the mixed-matrix membranes without any loss in selectivity. Positron annihilation lifetime spectroscopy (PALS) indicated that the increased gas permeability is due to the free volume in the PSF polymer and the added large free volume inside the MIL-101 particles. The trend of the gas transport properties of the composite membranes could be reproduced by a Maxwell model. PMID:24957061

  3. Numerical treatments for solving nonlinear mixed integral equation

    Directory of Open Access Journals (Sweden)

    M.A. Abdou

    2016-12-01

    Full Text Available We consider a mixed type of nonlinear integral equation (MNLIE of the second kind in the space C[0,T]×L2(Ω,T<1. The Volterra integral terms (VITs are considered in time with continuous kernels, while the Fredholm integral term (FIT is considered in position with singular general kernel. Using the quadratic method and separation of variables method, we obtain a nonlinear system of Fredholm integral equations (NLSFIEs with singular kernel. A Toeplitz matrix method, in each case, is then used to obtain a nonlinear algebraic system. Numerical results are calculated when the kernels take a logarithmic form or Carleman function. Moreover, the error estimates, in each case, are then computed.

  4. Singularities formation, structure, and propagation

    CERN Document Server

    Eggers, J

    2015-01-01

    Many key phenomena in physics and engineering are described as singularities in the solutions to the differential equations describing them. Examples covered thoroughly in this book include the formation of drops and bubbles, the propagation of a crack and the formation of a shock in a gas. Aimed at a broad audience, this book provides the mathematical tools for understanding singularities and explains the many common features in their mathematical structure. Part I introduces the main concepts and techniques, using the most elementary mathematics possible so that it can be followed by readers with only a general background in differential equations. Parts II and III require more specialised methods of partial differential equations, complex analysis and asymptotic techniques. The book may be used for advanced fluid mechanics courses and as a complement to a general course on applied partial differential equations.

  5. Historical developments in singular perturbations

    CERN Document Server

    O'Malley, Robert E

    2014-01-01

    This engaging text describes the development of singular perturbations, including its history, accumulating literature, and its current status. While the approach of the text is sophisticated, the literature is accessible to a broad audience. A particularly valuable bonus are the historical remarks. These remarks are found throughout the manuscript. They demonstrate the growth of mathematical thinking on this topic by engineers and mathematicians. The book focuses on detailing how the various methods are to be applied. These are illustrated by a  number and variety of examples. Readers are expected to have a working knowledge of elementary ordinary differential equations, including some familiarity with power series techniques, and of some advanced calculus. Dr. O'Malley  has written a number of books on singular perturbations.  This book has developed from many of his works in the field of perturbation theory.

  6. Energy conditions and spacetime singularities

    International Nuclear Information System (INIS)

    Tipler, F.J.

    1978-01-01

    In this paper, a number of theorems are proven which collectively show that singularities will occur in spacetime under weaker energy conditions than the strong energy condition. In particular, the Penrose theorem, which uses only the weak energy condition but which applies only to open universes, is extended to all closed universes which have a Cauchy surface whose universal covering manifold is not a three-sphere. Furthermore, it is shown that the strong energy condition in the Hawking-Penrose theorem can be replaced by the weak energy condition and the assumption that the strong energy condition holds only on the average. In addition, it is demonstrated that if the Universe is closed, then the existence of singularities follows from the averaged strong energy condition alone. It is argued that any globally hyperbolic spacetime which satisfies the weak energy condition and which contains a black hole must be null geodesically incomplete

  7. Numerical Quadrature of Periodic Singular Integral Equations

    DEFF Research Database (Denmark)

    Krenk, Steen

    1978-01-01

    This paper presents quadrature formulae for the numerical integration of a singular integral equation with Hilbert kernel. The formulae are based on trigonometric interpolation. By integration a quadrature formula for an integral with a logarithmic singularity is obtained. Finally it is demonstra......This paper presents quadrature formulae for the numerical integration of a singular integral equation with Hilbert kernel. The formulae are based on trigonometric interpolation. By integration a quadrature formula for an integral with a logarithmic singularity is obtained. Finally...... it is demonstrated how a singular integral equation with infinite support can be solved by use of the preceding formulae....

  8. Fundamental solutions of singular SPDEs

    Energy Technology Data Exchange (ETDEWEB)

    Selesi, Dora, E-mail: dora@dmi.uns.ac.rs [Department of Mathematics and Informatics, University of Novi Sad (Serbia)

    2011-07-15

    Highlights: > Fundamental solutions of linear SPDEs are constructed. > Wick-convolution product is introduced for the first time. > Fourier transformation maps Wick-convolution into Wick product. > Solutions of linear SPDEs are expressed via Wick-convolution with fundamental solutions. > Stochastic Helmholtz equation is solved. - Abstract: This paper deals with some models of mathematical physics, where random fluctuations are modeled by white noise or other singular Gaussian generalized processes. White noise, as the distributional derivative od Brownian motion, which is the most important case of a Levy process, is defined in the framework of Hida distribution spaces. The Fourier transformation in the framework of singular generalized stochastic processes is introduced and its applications to solving stochastic differential equations involving Wick products and singularities such as the Dirac delta distribution are presented. Explicit solutions are obtained in form of a chaos expansion in the Kondratiev white noise space, while the coefficients of the expansion are tempered distributions. Stochastic differential equations of the form P({omega}, D) Lozenge u(x, {omega}) = A(x, {omega}) are considered, where A is a singular generalized stochastic process and P({omega}, D) is a partial differential operator with random coefficients. We introduce the Wick-convolution operator * which enables us to express the solution as u = s*A Lozenge I{sup Lozenge (-1)}, where s denotes the fundamental solution and I is the unit random variable. In particular, the stochastic Helmholtz equation is solved, which in physical interpretation describes waves propagating with a random speed from randomly appearing point sources.

  9. Why the Singularity Cannot Happen

    OpenAIRE

    Modis, Theodore

    2012-01-01

    The concept of a Singularity as described in Ray Kurzweil's book cannot happen for a number of reasons. One reason is that all natural growth processes that follow exponential patterns eventually reveal themselves to be following S-curves thus excluding runaway situations. The remaining growth potential from Kurzweil's ''knee'', which could be approximated as the moment when an S-curve pattern begins deviating from the corresponding exponential, is a factor of only one order of magnitude grea...

  10. Fundamental solutions of singular SPDEs

    International Nuclear Information System (INIS)

    Selesi, Dora

    2011-01-01

    Highlights: → Fundamental solutions of linear SPDEs are constructed. → Wick-convolution product is introduced for the first time. → Fourier transformation maps Wick-convolution into Wick product. → Solutions of linear SPDEs are expressed via Wick-convolution with fundamental solutions. → Stochastic Helmholtz equation is solved. - Abstract: This paper deals with some models of mathematical physics, where random fluctuations are modeled by white noise or other singular Gaussian generalized processes. White noise, as the distributional derivative od Brownian motion, which is the most important case of a Levy process, is defined in the framework of Hida distribution spaces. The Fourier transformation in the framework of singular generalized stochastic processes is introduced and its applications to solving stochastic differential equations involving Wick products and singularities such as the Dirac delta distribution are presented. Explicit solutions are obtained in form of a chaos expansion in the Kondratiev white noise space, while the coefficients of the expansion are tempered distributions. Stochastic differential equations of the form P(ω, D) ◊ u(x, ω) = A(x, ω) are considered, where A is a singular generalized stochastic process and P(ω, D) is a partial differential operator with random coefficients. We introduce the Wick-convolution operator * which enables us to express the solution as u = s*A ◊ I ◊(-1) , where s denotes the fundamental solution and I is the unit random variable. In particular, the stochastic Helmholtz equation is solved, which in physical interpretation describes waves propagating with a random speed from randomly appearing point sources.

  11. On singularities of lattice varieties

    OpenAIRE

    Mukherjee, Himadri

    2013-01-01

    Toric varieties associated with distributive lattices arise as a fibre of a flat degeneration of a Schubert variety in a minuscule. The singular locus of these varieties has been studied by various authors. In this article we prove that the number of diamonds incident on a lattice point $\\a$ in a product of chain lattices is more than or equal to the codimension of the lattice. Using this we also show that the lattice varieties associated with product of chain lattices is smooth.

  12. Quantum propagation across cosmological singularities

    Science.gov (United States)

    Gielen, Steffen; Turok, Neil

    2017-05-01

    The initial singularity is the most troubling feature of the standard cosmology, which quantum effects are hoped to resolve. In this paper, we study quantum cosmology with conformal (Weyl) invariant matter. We show that it is natural to extend the scale factor to negative values, allowing a large, collapsing universe to evolve across a quantum "bounce" into an expanding universe like ours. We compute the Feynman propagator for Friedmann-Robertson-Walker backgrounds exactly, identifying curious pathologies in the case of curved (open or closed) universes. We then include anisotropies, fixing the operator ordering of the quantum Hamiltonian by imposing covariance under field redefinitions and again finding exact solutions. We show how complex classical solutions allow one to circumvent the singularity while maintaining the validity of the semiclassical approximation. The simplest isotropic universes sit on a critical boundary, beyond which there is qualitatively different behavior, with potential for instability. Additional scalars improve the theory's stability. Finally, we study the semiclassical propagation of inhomogeneous perturbations about the flat, isotropic case, at linear and nonlinear order, showing that, at least at this level, there is no particle production across the bounce. These results form the basis for a promising new approach to quantum cosmology and the resolution of the big bang singularity.

  13. Singularities in Free Surface Flows

    Science.gov (United States)

    Thete, Sumeet Suresh

    Free surface flows where the shape of the interface separating two or more phases or liquids are unknown apriori, are commonplace in industrial applications and nature. Distribution of drop sizes, coalescence rate of drops, and the behavior of thin liquid films are crucial to understanding and enhancing industrial practices such as ink-jet printing, spraying, separations of chemicals, and coating flows. When a contiguous mass of liquid such as a drop, filament or a film undergoes breakup to give rise to multiple masses, the topological transition is accompanied with a finite-time singularity . Such singularity also arises when two or more masses of liquid merge into each other or coalesce. Thus the dynamics close to singularity determines the fate of about-to-form drops or films and applications they are involved in, and therefore needs to be analyzed precisely. The primary goal of this thesis is to resolve and analyze the dynamics close to singularity when free surface flows experience a topological transition, using a combination of theory, experiments, and numerical simulations. The first problem under consideration focuses on the dynamics following flow shut-off in bottle filling applications that are relevant to pharmaceutical and consumer products industry, using numerical techniques based on Galerkin Finite Element Methods (GFEM). The second problem addresses the dual flow behavior of aqueous foams that are observed in oil and gas fields and estimates the relevant parameters that describe such flows through a series of experiments. The third problem aims at understanding the drop formation of Newtonian and Carreau fluids, computationally using GFEM. The drops are formed as a result of imposed flow rates or expanding bubbles similar to those of piezo actuated and thermal ink-jet nozzles. The focus of fourth problem is on the evolution of thinning threads of Newtonian fluids and suspensions towards singularity, using computations based on GFEM and experimental

  14. On the resultant property of the Fisher information matrix of a vector ARMA process

    NARCIS (Netherlands)

    Klein, A.; Mélard, G.; Spreij, P.

    2004-01-01

    A matrix is called a multiple resultant matrix associated to two matrix polynomials when it becomes singular if and only if the two matrix polynomials have at least one common eigenvalue. In this paper a new multiple resultant matrix is introduced. It concerns the Fisher information matrix (FIM) of

  15. Biplot and Singular Value Decomposition Macros for Excel©

    Directory of Open Access Journals (Sweden)

    Ilya A. Lipkovich

    2002-06-01

    Full Text Available The biplot display is a graph of row and column markers obtained from data that forms a two-way table. The markers are calculated from the singular value decomposition of the data matrix. The biplot display may be used with many multivariate methods to display relationships between variables and objects. It is commonly used in ecological applications to plot relationships between species and sites. This paper describes a set of Excel macros that may be used to draw a biplot display based on results from principal components analysis, correspondence analysis, canonical discriminant analysis, metric multidimensional scaling, redundancy analysis, canonical correlation analysis or canonical correspondence analysis. The macros allow for a variety of transformations of the data prior to the singular value decomposition and scaling of the markers following the decomposition.

  16. Evaluation of hydrophobic micro-zeolite-mixed matrix membrane and integrated with acetone-butanol-ethanol fermentation for enhanced butanol production.

    Science.gov (United States)

    Xue, Chuang; Yang, Decai; Du, Guangqing; Chen, Lijie; Ren, Jiangang; Bai, Fengwu

    2015-01-01

    Butanol is regarded as an advanced biofuel that can be derived from renewable biomass. However, the main challenge for microbial butanol production is low butanol titer, yield and productivity, leading to intensive energy consumption in product recovery. Various alternative separation technologies such as extraction, adsorption and gas stripping, etc., could be integrated with acetone-butanol-ethanol (ABE) fermentation with improving butanol productivity, but their butanol selectivities are not satisfactory. The membrane-based pervaporation technology is recently attracting increasing attention since it has potentially desirable butanol selectivity. The performance of the zeolite-mixed polydimethylsiloxane (PDMS) membranes were evaluated to recover butanol from butanol/water binary solution as well as fermentation broth in the integrated ABE fermentation system. The separation factor and butanol titer in permeate of the zeolite-mixed PDMS membrane were up to 33.0 and 334.6 g/L at 80°C, respectively, which increased with increasing zeolite loading weight in the membrane as well as feed temperature. The enhanced butanol separation factor was attributed to the hydrophobic zeolites with large pore size providing selective routes preferable for butanol permeation. In fed-batch fermentation incorporated with pervaporation, 54.9 g/L ABE (34.5 g/L butanol, 17.0 g/L acetone and 3.4 g/L ethanol) were produced from 172.3 g/L glucose. The overall butanol productivity and yield increased by 16.0 and 11.1%, respectively, which was attributed to the alleviated butanol inhibition by pervaporation and reassimilation of acids for ABE production. The zeolite-mixed membrane produced a highly concentrated condensate containing 169.6 g/L butanol or 253.3 g/L ABE, which after phase separation easily gave the final product containing >600 g/L butanol. Zeolite loading in the PDMS matrix was attributed to improving the pervaporative performance of the membrane, showing great

  17. Mathematical models with singularities a zoo of singular creatures

    CERN Document Server

    Torres, Pedro J

    2015-01-01

    The book aims to provide an unifying view of a variety (a 'zoo') of mathematical models with some kind of singular nonlinearity, in the sense that it becomes infinite when the state variable approaches a certain point. Up to 11 different concrete models are analyzed in separate chapters. Each chapter starts with a discussion of the basic model and its physical significance. Then the main results and typical proofs are outlined, followed by open problems. Each chapter is closed by a suitable list of references. The book may serve as a guide for researchers interested in the modelling of real world processes.

  18. Mixed-matrix membranes with enhanced antifouling activity: probing the surface-tailoring potential of Tiron and chromotropic acid for nano-TiO2.

    Science.gov (United States)

    Pal, Avishek; Dey, T K; Debnath, A K; Bhushan, Bharat; Sahu, A K; Bindal, R C; Kar, Soumitra

    2017-09-01

    Mixed-matrix membranes (MMMs) were developed by impregnating organofunctionalized nanoadditives within fouling-susceptible polysulfone matrix following the non-solvent induced phase separation (NIPS) method. The facile functionalization of nanoparticles of anatase TiO 2 (nano-TiO 2 ) by using two different organoligands, viz . Tiron and chromotropic acid, was carried out to obtain organofunctionalized nanoadditives, F T -nano-TiO 2 and F C -nano-TiO 2 , respectively. The structural features of nanoadditives were evaluated by X-ray diffraction, X-ray photoelectron spectroscopy, Raman and Fourier transform infrared spectroscopy, which established that Tiron leads to the blending of chelating and bridging bidentate geometries for F T -nano-TiO 2 , whereas chromotropic acid produces bridging bidentate as well as monodentate geometries for F C -nano-TiO 2 . The surface chemistry of the studied membranes, polysulfone (Psf): F T -nano-TiO 2 UF and Psf: F C -nano-TiO 2 UF, was profoundly influenced by the benign distributions of the nanoadditives enriched with distinctly charged sites ([Formula: see text]), as evidenced by superior morphology, improved topography, enhanced surface hydrophilicity and altered electrokinetic features. The membranes exhibited enhanced solvent throughputs, viz . 3500-4000 and 3400-4300 LMD at 1 bar of transmembrane pressure, without significant compromise in their rejection attributes. The flux recovery ratios and fouling resistive behaviours of MMMs towards bovine serum albumin indicated that the nanoadditives could impart stable and appreciable antifouling activity, potentially aiding in a sustainable ultrafiltration performance.

  19. On important precursor of singular optics (tutorial)

    Science.gov (United States)

    Polyanskii, Peter V.; Felde, Christina V.; Bogatyryova, Halina V.; Konovchuk, Alexey V.

    2018-01-01

    The rise of singular optics is usually associated with the seminal paper by J. F. Nye and M. V. Berry [Proc. R. Soc. Lond. A, 336, 165-189 (1974)]. Intense development of this area of modern photonics has started since the early eighties of the XX century due to invention of the interfrence technique for detection and diagnostics of phase singularities, such as optical vortices in complex speckle-structured light fields. The next powerful incentive for formation of singular optics into separate area of the science on light was connectected with discovering of very practical technique for creation of singular optical beams of various kinds on the base of computer-generated holograms. In the eghties and ninetieth of the XX century, singular optics evolved, almost entirely, under the approximation of complete coherency of light field. Only at the threshold of the XXI century, it has been comprehended that the singular-optics approaches can be fruitfully expanded onto partially spatially coherent, partially polarized and polychromatic light fields supporting singularities of new kinds, that has been resulted in establishing of correlation singular optics. Here we show that correlation singular optics has much deeper roots, ascending to "pre-singular" and even pre-laser epoch and associated with the concept of partial coherence and polarization. It is remarcable that correlation singular optics in its present interpretation has forestalled the standard coherent singular optics. This paper is timed to the sixtieth anniversary of the most profound precursor of modern correlation singular optics [J. Opt. Soc. Am., 47, 895-902 (1957)].

  20. Minimum-error quantum distinguishability bounds from matrix monotone functions: A comment on 'Two-sided estimates of minimum-error distinguishability of mixed quantum states via generalized Holevo-Curlander bounds' [J. Math. Phys. 50, 032106 (2009)

    International Nuclear Information System (INIS)

    Tyson, Jon

    2009-01-01

    Matrix monotonicity is used to obtain upper bounds on minimum-error distinguishability of arbitrary ensembles of mixed quantum states. This generalizes one direction of a two-sided bound recently obtained by the author [J. Tyson, J. Math. Phys. 50, 032106 (2009)]. It is shown that the previously obtained special case has unique properties.

  1. Synchronization and Control of Linearly Coupled Singular Systems

    Directory of Open Access Journals (Sweden)

    Fang Qingxiang

    2013-01-01

    Full Text Available The synchronization and control problem of linearly coupled singular systems is investigated. The uncoupled dynamical behavior at each node is general and can be chaotic or, otherwise the coupling matrix is not assumed to be symmetrical. Some sufficient conditions for globally exponential synchronization are derived based on Lyapunov stability theory. These criteria, which are in terms of linear matrix inequality (LMI, indicate that the left and right eigenvectors corresponding to eigenvalue zero of the coupling matrix play key roles in the stability analysis of the synchronization manifold. The controllers are designed for state feedback control and pinning control, respectively. Finally, a numerical example is provided to illustrate the effectiveness of the proposed conditions.

  2. On AC-Field-Induced Nonlinear Electroosmosis next to the Sharp Corner-Field-Singularity of Leaky Dielectric Blocks and Its Application in on-Chip Micro-Mixing

    Directory of Open Access Journals (Sweden)

    Yukun Ren

    2018-02-01

    Full Text Available Induced-charge electroosmosis has attracted lots of attention from the microfluidic community over the past decade. Most previous researches on this subject focused on induced-charge electroosmosis (ICEO vortex streaming actuated on ideally polarizable surfaces immersed in electrolyte solutions. Starting from this point, we conduct herein a linear asymptotic analysis on nonlinear electroosmotic flow next to leaky dielectric blocks of arbitrary electrical conductivity and dielectric permittivity in harmonic AC electric fields, and theoretically demonstrate that observable ICEO fluid motion can be generated at high field frequencies in the vicinity of nearly insulating semiconductors, a very low electrical conductivity, of which can evidently increase the double-layer relaxation frequency (inversely proportional to the solid permittivity to be much higher than the typical reciprocal RC time constant for induced double-layer charging on ideally polarizable surfaces. A computational model is developed to study the feasibility of this high-frequency vortex flow field of ICEO for sample mixing in microfluidics, in which the usage of AC voltage signal at high field frequencies may be beneficial to suppress electrochemical reactions to some extent. The influence of various parameters for developing an efficient mixer is investigated, and an integrated arrangement of semiconductor block array is suggested for achieving a reliable mixing performance at relatively high sample fluxes. Our physical demonstration with high-frequency ICEO next to leaky dielectric blocks using a simple channel structure offers valuable insights into the design of high-throughput micromixers for a variety of lab-on-a-chip applications.

  3. Symmetry generators in singular theories

    International Nuclear Information System (INIS)

    Lavrov, P.M.; Tyutin, I.V.

    1989-01-01

    It is proved that in the singular nondegenerate theories any symmetry of the lagrangian under non-point transformations of lagrangian variables with the open (in the general case) algebra in the hamiltonian approach generates corresponding transformations of canonical variables the generator of which is the Noether charge with respect to the Dirac brackets. On the surface of all constraints these transformations leave the hamiltonian invariant and the algebra of the Noether charges is closed. As a consequence it is shown that the nilpotent BRST charge operator always exists in gauge theories of the general form (if possible anomalies are not taken into account)

  4. Classification of subsurface objects using singular values derived from signal frames

    Science.gov (United States)

    Chambers, David H; Paglieroni, David W

    2014-05-06

    The classification system represents a detected object with a feature vector derived from the return signals acquired by an array of N transceivers operating in multistatic mode. The classification system generates the feature vector by transforming the real-valued return signals into complex-valued spectra, using, for example, a Fast Fourier Transform. The classification system then generates a feature vector of singular values for each user-designated spectral sub-band by applying a singular value decomposition (SVD) to the N.times.N square complex-valued matrix formed from sub-band samples associated with all possible transmitter-receiver pairs. The resulting feature vector of singular values may be transformed into a feature vector of singular value likelihoods and then subjected to a multi-category linear or neural network classifier for object classification.

  5. Topological resolution of gauge theory singularities

    Energy Technology Data Exchange (ETDEWEB)

    Saracco, Fabio; Tomasiello, Alessandro; Torroba, Gonzalo

    2013-08-21

    Some gauge theories with Coulomb branches exhibit singularities in perturbation theory, which are usually resolved by nonperturbative physics. In string theory this corresponds to the resolution of timelike singularities near the core of orientifold planes by effects from F or M theory. We propose a new mechanism for resolving Coulomb branch singularities in three-dimensional gauge theories, based on Chern-Simons interactions. This is illustrated in a supersymmetric S U ( 2 ) Yang-Mills-Chern-Simons theory. We calculate the one-loop corrections to the Coulomb branch of this theory and find a result that interpolates smoothly between the high-energy metric (that would exhibit the singularity) and a regular singularity-free low-energy result. We suggest possible applications to singularity resolution in string theory and speculate a relationship to a similar phenomenon for the orientifold six-plane in massive IIA supergravity.

  6. Topological resolution of gauge theory singularities

    Science.gov (United States)

    Saracco, Fabio; Tomasiello, Alessandro; Torroba, Gonzalo

    2013-08-01

    Some gauge theories with Coulomb branches exhibit singularities in perturbation theory, which are usually resolved by nonperturbative physics. In string theory this corresponds to the resolution of timelike singularities near the core of orientifold planes by effects from F or M theory. We propose a new mechanism for resolving Coulomb branch singularities in three-dimensional gauge theories, based on Chern-Simons interactions. This is illustrated in a supersymmetric SU(2) Yang-Mills-Chern-Simons theory. We calculate the one-loop corrections to the Coulomb branch of this theory and find a result that interpolates smoothly between the high-energy metric (that would exhibit the singularity) and a regular singularity-free low-energy result. We suggest possible applications to singularity resolution in string theory and speculate a relationship to a similar phenomenon for the orientifold six-plane in massive IIA supergravity.

  7. The geometry of warped product singularities

    Science.gov (United States)

    Stoica, Ovidiu Cristinel

    In this article, the degenerate warped products of singular semi-Riemannian manifolds are studied. They were used recently by the author to handle singularities occurring in General Relativity, in black holes and at the big-bang. One main result presented here is that a degenerate warped product of semi-regular semi-Riemannian manifolds with the warping function satisfying a certain condition is a semi-regular semi-Riemannian manifold. The connection and the Riemann curvature of the warped product are expressed in terms of those of the factor manifolds. Examples of singular semi-Riemannian manifolds which are semi-regular are constructed as warped products. Applications include cosmological models and black holes solutions with semi-regular singularities. Such singularities are compatible with a certain reformulation of the Einstein equation, which in addition holds at semi-regular singularities too.

  8. Treatment of methylene blue containing wastewater by a cost-effective micro-scale biochar/polysulfone mixed matrix hollow fiber membrane: Performance and mechanism studies.

    Science.gov (United States)

    He, Jinsong; Cui, Anan; Deng, Shihuai; Chen, J Paul

    2018-02-15

    Dye containing wastewater has increasingly become an important contamination due to operation of various industries such as textile industry. In this study, a micro-scale biochar particles/polysulfone mixed matrix hollow fiber membrane (MMM) was applied for the removal of methylene blue from water. The static and dynamic adsorption performance was investigated. We found that the MMM exhibited a high removal efficiency of methylene blue under a wide pH range of 4-10. The adsorption process on biochar and MMM obeyed the intraparticle surface diffusion model and Langmuir isotherm model. At neutral pH, the maximum adsorption capacity was 544.459 mg/g for biochar and 165.808 mg/g for MMM. Better regeneration with a desorption rate above 92% was achieved by 1-M NaCl in 90% ethanol aqueous solution. Furthermore, the MMM displayed good performance in treating methylene blue containing wastewater through a continuous filtration mode. More importantly, the MMM showed an excellent reusability for methylene blue removal; it was able to achieve 81% of the permeate yield of the fresh MMM after three regeneration cycles. Finally, the adsorption mechanism studies indicated that the removal of methylene blue was associated with electrostatic interaction, hydrogen bonding and hydrophobic interaction. Copyright © 2017 Elsevier Inc. All rights reserved.

  9. Simultaneous wastewater treatment and bioelectricity production in microbial fuel cells using cross-linked chitosan-graphene oxide mixed-matrix membranes.

    Science.gov (United States)

    Holder, Shima L; Lee, Ching-Hwa; Popuri, Srinivasa R

    2017-05-01

    Microbial fuel cells (MFCs) are emerging technology for wastewater treatment by chemical oxygen demand (COD) reduction and simultaneous bioelectricity production. Fabrication of an effective proton exchange membrane (PEM) is a vital component for MFC performance. In this work, green chitosan-based (CS) PEMs were fabricated with graphene oxide (GO) as filler material (CS-GO) and cross-linked with phosphoric acid (CS-GO-P(24)) or sulfuric acid (CS-GO-S(24)) to determine their effect on PEM properties. Interrogation of the physicochemical, thermal, and mechanical properties of the cross-linked CS-GO PEMs demonstrated that ionic cross-linking based on the incorporation of PO 4 3- groups in the CS-GO mixed-matrix composites, when compared with sulfuric acid cross-linking commonly used in proton exchange membrane fuel cell (PEMFC) studies, generated additional density of ionic cluster domains, rendered enhanced sorption properties, and augmented the thermal and mechanical stability of the composite structure. Consequently, bioelectricity performance analysis in MFC application showed that CS-GO-P(24) membrane produced 135% higher power density than the CS-GO-S(24) MFC system. Simultaneously, 89.52% COD removal of primary clarifier municipal wastewater was achieved in the MFC operated with the CS-GO-P(24) membrane.

  10. The role of tetragonal-metal-organic framework-5 loadings with extra ZnO molecule on the gas separation performance of mixed matrix membrane

    International Nuclear Information System (INIS)

    Arjmandi, Mehrzad; Pakizeh, Majid; Pirouzram, Omid

    2015-01-01

    The effect of more ZnO molecule in tetragonal structure of MOF-5 than cubic structure on the gas permeation properties of T-MOF-5/polyetherimide mixed matrix membranes was investigated. T-MOF-5 was first successfully synthesized and carefully characterized by XRD, FTIR, SEM and N 2 adsorption technique at 77 K. Novel T-MOF-5/PEI MMMs were prepared using solution casting method and characterized by FTIR and SEM. The SEM pictures of the MMMs showed that T-MOF-5 nanocrystals changed the morphology of PEI and exhibited acceptable contacts between the filler particles and the polymer chains. Gas permeation properties of these membranes with different T-MOF-5 contents were studied for pure H 2 , CO 2 , CH 4 and N 2 gases. Permeation measurement showed that the all gases' permeability, diffusivity and solubility were increased with T-MOF-5 loading. H 2 permeability and the ideal selectivity of H 2 /CO 2 and H 2 /CH 4 in MMM with 25 wt% loading of T-MOF-5 nanocrystals were increased. This behavior was attributed to more ZnO molecule in T-MOF-5 structure. The experimental gas permeations through T-MOF-5/PEI nanocomposite with different filler loadings were fitted on Higuchi model. Good agreement between the experimental data and the predicted gas permeability was obtained

  11. The role of tetragonal-metal-organic framework-5 loadings with extra ZnO molecule on the gas separation performance of mixed matrix membrane

    Energy Technology Data Exchange (ETDEWEB)

    Arjmandi, Mehrzad; Pakizeh, Majid [Ferdowsi University of Mashhad, Mashhad (Iran, Islamic Republic of); Pirouzram, Omid [Kurdistan University, Kurdistan (Iran, Islamic Republic of)

    2015-06-15

    The effect of more ZnO molecule in tetragonal structure of MOF-5 than cubic structure on the gas permeation properties of T-MOF-5/polyetherimide mixed matrix membranes was investigated. T-MOF-5 was first successfully synthesized and carefully characterized by XRD, FTIR, SEM and N{sub 2} adsorption technique at 77 K. Novel T-MOF-5/PEI MMMs were prepared using solution casting method and characterized by FTIR and SEM. The SEM pictures of the MMMs showed that T-MOF-5 nanocrystals changed the morphology of PEI and exhibited acceptable contacts between the filler particles and the polymer chains. Gas permeation properties of these membranes with different T-MOF-5 contents were studied for pure H{sub 2}, CO{sub 2}, CH{sub 4} and N{sub 2} gases. Permeation measurement showed that the all gases' permeability, diffusivity and solubility were increased with T-MOF-5 loading. H{sub 2} permeability and the ideal selectivity of H{sub 2}/CO{sub 2} and H{sub 2}/CH{sub 4} in MMM with 25 wt% loading of T-MOF-5 nanocrystals were increased. This behavior was attributed to more ZnO molecule in T-MOF-5 structure. The experimental gas permeations through T-MOF-5/PEI nanocomposite with different filler loadings were fitted on Higuchi model. Good agreement between the experimental data and the predicted gas permeability was obtained.

  12. Revisiting the Aluminum Trimesate-based MOF (MIL-96): from Structure Determination to the Processing of Mixed Matrix Membranes for CO2 Capture.

    KAUST Repository

    Benzaqui, Marvin

    2017-11-08

    A microporous Al trimesate-based metal-organic framework (MOF), denoted MIL-96-(Al), was selected as a porous hybrid filler for the processing of mixed matrix membranes (MMMs) for CO2/N-2 postcombustion separation. First, the structural model of MIL-96-(Al) initially reported was revisited using a combination of synchrotron-based single-crystal X-ray diffraction, solid-state nuclear magnetic resonance spectroscopy, and density functional theory (DFT) calculations. In a second step, pure MIL-96-(Al) crystals differing by their size and aspect ratio, including anisotropic hexagonal platelets and nanoparticles of about 70 nm in diameter, were prepared. Then, a combination of in situ IR spectroscopy, single-gas, and CO2/N-2 coadsorption experiments, calorimetry, and molecular simulations revealed that MIL-96-(Al) nanoparticles show a relatively high CO2 affinity over N-2 owing to strong interactions between CO2 molecules and several adsorption sites such as Al3+ Lewis centers, coordinated water, and hydroxyl groups. Finally, the high compatibility between MIL-96-(Al) nanoparticles and the 6FDA-DAM polymer allowed the processing of homogeneous and defect-free MMMs with a high MOF loading (up to 25 wt %) that outperform pure polymer membranes for CO2/N-2 separation.

  13. Development and Characterization of Defect-Free Matrimid® Mixed-Matrix Membranes Containing Activated Carbon Particles for Gas Separation

    Directory of Open Access Journals (Sweden)

    Fynn Weigelt

    2018-01-01

    Full Text Available In this work, mixed-matrix membranes (MMMs for gas separation in the form of thick films were prepared via the combination of the polymer Matrimid® 5218 and activated carbons (AC. The AC particles had a mean particle size of 1.5 μm and a mean pore diameter of 1.9 nm. The films were prepared by slow solvent evaporation from casting solutions in chloroform, which had a varying polymer–AC ratio. It was possible to produce stable films with up to a content of 50 vol % of AC. Thorough characterization experiments were accomplished via differential scanning calorimetry and thermogravimetric analysis, while the morphology of the MMMs was also investigated via scanning electron microscopy. The gas transport properties were revealed by employing time-lag measurements for different pure gases as well as sorption balance experiments for the filler particles. It was found that defect free Matrimid® MMMs with AC were prepared and the increase of the filler content led to a higher effective permeability for different gases. The single gas selectivity αij of different gas pairs maintained stable values with the increase of AC content, regardless of the steep increase in the effective permeability of the pure gases. Estimation of the solubilities and the diffusivities of the Matrimid®, AC, and MMMs allowed for the explanation of the increasing permeabilities of the MMMs, with the increase of AC content by modelling.

  14. Amino-Functionalized ZIF-7 Nanocrystals: Improved Intrinsic Separation Ability and Interfacial Compatibility in Mixed-Matrix Membranes for CO2 /CH4 Separation.

    Science.gov (United States)

    Xiang, Long; Sheng, Luqian; Wang, Chongqing; Zhang, Lixiong; Pan, Yichang; Li, Yanshuo

    2017-08-01

    Highly permeable and selective, as well as plasticization-resistant membranes are desired as promising alternatives for cost- and energy-effective CO 2 separation. Here, robust mixed-matrix membranes based on an amino-functionalized zeolitic imidazolate framework ZIF-7 (ZIF-7-NH 2 ) and crosslinked poly(ethylene oxide) rubbery polymer are successfully fabricated with filler loadings up to 36 wt%. The ZIF-7-NH 2 materials synthesized from in situ substitution of 2-aminobenzimidazole into the ZIF-7 structure exhibit enlarged aperture size compared with monoligand ZIF-7. The intrinsic separation ability for CO 2 /CH 4 on ZIF-7-NH 2 is remarkably enhanced as a result of improved CO 2 uptake capacity and diffusion selectivity. The incorporation of ZIF-7-NH 2 fillers simultaneously makes the neat polymer more permeable and more selective, surpassing the state-of-the-art 2008 Robeson upper bound. The chelating effect between metal (zinc) nodes of fillers and ester groups of a polymer provides good bonding, enhancing the mechanical strength and plasticization resistance of the neat polymer membrane. The developed novel ZIF-7 structure with amino-function and the resulting nanocomposite membranes are very attractive for applications like natural-gas sweetening or biogas purification. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Enhanced interfacial interaction and CO2 separation performance of mixed matrix membrane by incorporating polyethylenimine-decorated metal-organic frameworks.

    Science.gov (United States)

    Xin, Qingping; Ouyang, Jingyi; Liu, Tianyu; Li, Zhao; Li, Zhen; Liu, Yuchen; Wang, Shaofei; Wu, Hong; Jiang, Zhongyi; Cao, Xingzhong

    2015-01-21

    Polyethylenimine (PEI) was immobilized by MIL-101(Cr) (∼550 nm) via a facile vacuum-assisted method, and the obtained PEI@MIL-101(Cr) was then incorporated into sulfonated poly(ether ether ketone) (SPEEK) to fabricate mixed matrix membranes (MMMs). High loading and uniform dispersion of PEI in MIL-101(Cr) were achieved as demonstrated by ICP, FT-IR, XPS, and EDS-mapping. The PEI both in the pore channels and on the surface of MIL-101(Cr) improved the filler-polymer interface compatibility due to the electrostatic interaction and hydrogen bond between sulfonic acid group and PEI, and simultaneously rendered abundant amine carriers to facilitate the transport of CO2 through reversible reaction. MMMs were evaluated in terms of gas separation performance, thermal stability, and mechanical property. The as-prepared SPEEK/PEI@MIL-101(Cr) MMMs showed increased gas permeability and selectivity, and the highest ideal selectivities for CO2/CH4 and CO2/N2 were 71.8 and 80.0 (at a CO2 permeability of 2490 Barrer), respectively. Compared with the membranes doped with unfilled MIL-101(Cr), the ideal selectivities of CO2/CH4 and CO2/N2 for PEI@MIL-101(Cr)-doped membranes were increased by 128.1 and 102.4 %, respectively, at 40 wt % filler loading, surpassing the 2008 Robeson upper bound line. Moreover, the mechanical property and thermal stability of SPEEK/PEI@MIL-101(Cr) were enhanced.

  16. Integrating seawater desalination and wastewater reclamation forward osmosis process using thin-film composite mixed matrix membrane with functionalized carbon nanotube blended polyethersulfone support layer.

    Science.gov (United States)

    Choi, Hyeon-Gyu; Son, Moon; Choi, Heechul

    2017-10-01

    Thin-film composite mixed matrix membrane (TFC MMM) with functionalized carbon nanotube (fCNT) blended in polyethersulfone (PES) support layer was synthesized via interfacial polymerization and phase inversion. This membrane was firstly tested in lab-scale integrating seawater desalination and wastewater reclamation forward osmosis (FO) process. Water flux of TFC MMM was increased by 72% compared to that of TFC membrane due to enhanced hydrophilicity. Although TFC MMM showed lower water flux than TFC commercial membrane, enhanced reverse salt flux selectivity (RSFS) of TFC MMM was observed compared to TFC membrane (15% higher) and TFC commercial membrane (4% higher), representing membrane permselectivity. Under effluent organic matter (EfOM) fouling test, 16% less normalized flux decline of TFC MMM was observed compared to TFC membrane. There was 8% less decline of TFC MMM compared to TFC commercial membrane due to fCNT effect on repulsive foulant-membrane interaction enhancement, caused by negatively charged membrane surface. After 10 min physical cleaning, TFC MMM displayed higher recovered normalized flux than TFC membrane (6%) and TFC commercial membrane (4%); this was also supported by visualized characterization of fouling layer. This study presents application of TFC MMM to integrated seawater desalination and wastewater reclamation FO process for the first time. It can be concluded that EfOM fouling of TFC MMM was suppressed due to repulsive foulant-membrane interaction. Copyright © 2017 Elsevier Ltd. All rights reserved.

  17. Exact solutions and singularities in string theory

    International Nuclear Information System (INIS)

    Horowitz, G.T.; Tseytlin, A.A.

    1994-01-01

    We construct two new classes of exact solutions to string theory which are not of the standard plane wave of gauged WZW type. Many of these solutions have curvature singularities. The first class includes the fundamental string solution, for which the string coupling vanishes near the singularity. This suggests that the singularity may not be removed by quantum corrections. The second class consists of hybrids of plane wave and gauged WZW solutions. We discuss a four-dimensional example in detail

  18. DEKOMPOSISI NILAI SINGULAR PADA SISTEM PENGENALAN WAJAH

    OpenAIRE

    Beni Utomo

    2012-01-01

    Dekomposisi Nilai Singular atau Singular Value Decomposition (SVD)merupakan salah satu cara untuk menyatakan Principal Component Analysis (PCA).PCA sendiri merupakan suatu proses untuk menemukan kontributor-kontributorpenting dari suatu data berdasarkan besaran statistika deviasi standart dan variansi.SVD merupakan proses untuk mendapatkan matriks diagonal yang elementak nolnya merupakan nilai singular yang akarnya merupakan eigenvalue.SVD atas matriks kovarian C berbentuk C = U?V T dengan ma...

  19. Box graphs and singular fibers

    International Nuclear Information System (INIS)

    Hayashi, Hirotaka; Lawrie, Craig; Morrison, David R.; Schäfer-Nameki, Sakura

    2014-01-01

    We determine the higher codimension fibers of elliptically fibered Calabi-Yau fourfolds with section by studying the three-dimensional N=2 supersymmetric gauge theory with matter which describes the low energy effective theory of M-theory compactified on the associated Weierstrass model, a singular model of the fourfold. Each phase of the Coulomb branch of this theory corresponds to a particular resolution of the Weierstrass model, and we show that these have a concise description in terms of decorated box graphs based on the representation graph of the matter multiplets, or alternatively by a class of convex paths on said graph. Transitions between phases have a simple interpretation as “flopping' of the path, and in the geometry correspond to actual flop transitions. This description of the phases enables us to enumerate and determine the entire network between them, with various matter representations for all reductive Lie groups. Furthermore, we observe that each network of phases carries the structure of a (quasi-)minuscule representation of a specific Lie algebra. Interpreted from a geometric point of view, this analysis determines the generators of the cone of effective curves as well as the network of flop transitions between crepant resolutions of singular elliptic Calabi-Yau fourfolds. From the box graphs we determine all fiber types in codimensions two and three, and we find new, non-Kodaira, fiber types for E 6 , E 7 and E 8

  20. Naked singularity, firewall, and Hawking radiation.

    Science.gov (United States)

    Zhang, Hongsheng

    2017-06-21

    Spacetime singularity has always been of interest since the proof of the Penrose-Hawking singularity theorem. Naked singularity naturally emerges from reasonable initial conditions in the collapsing process. A recent interesting approach in black hole information problem implies that we need a firewall to break the surplus entanglements among the Hawking photons. Classically, the firewall becomes a naked singularity. We find some vacuum analytical solutions in R n -gravity of the firewall-type and use these solutions as concrete models to study the naked singularities. By using standard quantum theory, we investigate the Hawking radiation emitted from the black holes with naked singularities. Here we show that the singularity itself does not destroy information. A unitary quantum theory works well around a firewall-type singularity. We discuss the validity of our result in general relativity. Further our result demonstrates that the temperature of the Hawking radiation still can be expressed in the form of the surface gravity divided by 2π. This indicates that a naked singularity may not compromise the Hakwing evaporation process.

  1. Spacetime averaging of exotic singularity universes

    International Nuclear Information System (INIS)

    Dabrowski, Mariusz P.

    2011-01-01

    Taking a spacetime average as a measure of the strength of singularities we show that big-rips (type I) are stronger than big-bangs. The former have infinite spacetime averages while the latter have them equal to zero. The sudden future singularities (type II) and w-singularities (type V) have finite spacetime averages. The finite scale factor (type III) singularities for some values of the parameters may have an infinite average and in that sense they may be considered stronger than big-bangs.

  2. On local invariants of singular symplectic forms

    Science.gov (United States)

    Domitrz, Wojciech

    2017-04-01

    We find a complete set of local invariants of singular symplectic forms with the structurally stable Martinet hypersurface on a 2 n-dimensional manifold. In the C-analytic category this set consists of the Martinet hypersurface Σ2, the restriction of the singular symplectic form ω to TΣ2 and the kernel of ω n - 1 at the point p ∈Σ2. In the R-analytic and smooth categories this set contains one more invariant: the canonical orientation of Σ2. We find the conditions to determine the kernel of ω n - 1 at p by the other invariants. In dimension 4 we find sufficient conditions to determine the equivalence class of a singular symplectic form-germ with the structurally smooth Martinet hypersurface by the Martinet hypersurface and the restriction of the singular symplectic form to it. We also study the singular symplectic forms with singular Martinet hypersurfaces. We prove that the equivalence class of such singular symplectic form-germ is determined by the Martinet hypersurface, the canonical orientation of its regular part and the restriction of the singular symplectic form to its regular part if the Martinet hypersurface is a quasi-homogeneous hypersurface with an isolated singularity.

  3. Necessary and sufficient conditions for big bangs, bounces, crunches, rips, sudden singularities and extremality events

    International Nuclear Information System (INIS)

    Cattoen, Celine; Visser, Matt

    2005-01-01

    Until recently, the physically relevant singularities occurring in FRW cosmologies had traditionally been thought to be limited to the 'big bang', and possibly a 'big crunch'. However, over the last few years, the zoo of cosmological singularities considered in the literature has become considerably more extensive, with 'big rips' and 'sudden singularities' added to the mix, as well as renewed interest in nonsingular cosmological events such as 'bounces' and 'turnarounds'. In this paper we present an extensive catalogue of such cosmological milestones, both at the kinematical and dynamical level. First, using generalized power series, purely kinematical definitions of these cosmological events are provided in terms of the behaviour of the scale factor a(t). The notion of a 'scale-factor singularity' is defined, and its relation to curvature singularities (polynomial and differential) is explored. Second, dynamical information is extracted by using the Friedmann equations (without assuming even the existence of any equation of state) to place constraints on whether or not the classical energy conditions are satisfied at the cosmological milestones. We use these considerations to derive necessary and sufficient conditions for the existence of cosmological milestones such as bangs, bounces, crunches, rips, sudden singularities and extremality events. Since the classification is extremely general and, modulo certain technical assumptions, is complete, the corresponding results are to a high degree model independent: in particular, we provide a characterization of the class of bangs, crunches and sudden singularities for which the dominant energy condition is satisfied

  4. Differential forms on singular varieties De Rham and Hodge theory simplified

    CERN Document Server

    Ancona, Vincenzo

    2005-01-01

    Differential Forms on Singular Varieties: De Rham and Hodge Theory Simplified uses complexes of differential forms to give a complete treatment of the Deligne theory of mixed Hodge structures on the cohomology of singular spaces. This book features an approach that employs recursive arguments on dimension and does not introduce spaces of higher dimension than the initial space. It simplifies the theory through easily identifiable and well-defined weight filtrations. It also avoids discussion of cohomological descent theory to maintain accessibility. Topics include classical Hodge theory, differential forms on complex spaces, and mixed Hodge structures on noncompact spaces.

  5. Using many pilot points and singular value decomposition in groundwater model calibration

    DEFF Research Database (Denmark)

    Christensen, Steen; Doherty, John

    2008-01-01

    over the model area. Singular value decomposition (SVD) of the normal matrix is used to reduce the large number of pilot point parameters to a smaller number of so-called super parameters that can be estimated by nonlinear regression from the available observations. A number of eigenvectors...

  6. On the inequivalence of renormalization and self-adjoint extensions for quantum singular interactions

    International Nuclear Information System (INIS)

    Camblong, Horacio E.; Epele, Luis N.; Fanchiotti, Huner; Garcia Canal, Carlos A.; Ordonez, Carlos R.

    2007-01-01

    A unified S-matrix framework of quantum singular interactions is presented for the comparison of self-adjoint extensions and physical renormalization. For the long-range conformal interaction the two methods are not equivalent, with renormalization acting as selector of a preferred extension and regulator of the unbounded Hamiltonian

  7. Quantum transitions through cosmological singularities

    Energy Technology Data Exchange (ETDEWEB)

    Bramberger, Sebastian F.; Lehners, Jean-Luc [Max Planck Institute for Gravitational Physics (Albert Einstein Institute), 14476 Potsdam-Golm (Germany); Hertog, Thomas; Vreys, Yannick, E-mail: sebastian.bramberger@aei.mpg.de, E-mail: thomas.hertog@kuleuven.be, E-mail: jlehners@aei.mpg.de, E-mail: yannick.vreys@kuleuven.be [Institute for Theoretical Physics, KU Leuven, 3001 Leuven (Belgium)

    2017-07-01

    In a quantum theory of cosmology spacetime behaves classically only in limited patches of the configuration space on which the wave function of the universe is defined. Quantum transitions can connect classical evolution in different patches. Working in the saddle point approximation and in minisuperspace we compute quantum transitions connecting inflationary histories across a de Sitter like throat or a singularity. This supplies probabilities for how an inflating universe, when evolved backwards, transitions and branches into an ensemble of histories on the opposite side of a quantum bounce. Generalising our analysis to scalar potentials with negative regions we identify saddle points describing a quantum transition between a classically contracting, crunching ekpyrotic phase and an inflationary universe.

  8. Economías singulares

    Directory of Open Access Journals (Sweden)

    Elvio Alccinelli

    2001-07-01

    Full Text Available En este artículo pretendemos mostrar que le conjunto de las economías singulares, si bien pequeño desde el punto de vista de la topología y/o desde el punto de vista de la teoría de la medida, tiene importantes efectos en el desarrollo de los regímenes económicos. Es el responsable de los cambios abruptos en los estados de equilibrio y de la multiplicidad de tales estados. Permite además establecer a partir de los tipos de singularidades posibles, una partición del conjunto de economías según tenga lugar uno u otro tipo de singularidad cuya presencia o no, caracteriza el comportamiento posible de la economía en cuestión.

  9. Vector fields on singular varieties

    CERN Document Server

    Brasselet, Jean-Paul; Suwa, Tatsuo

    2009-01-01

    Vector fields on manifolds play a major role in mathematics and other sciences. In particular, the Poincaré-Hopf index theorem gives rise to the theory of Chern classes, key manifold-invariants in geometry and topology. It is natural to ask what is the ‘good’ notion of the index of a vector field, and of Chern classes, if the underlying space becomes singular. The question has been explored by several authors resulting in various answers, starting with the pioneering work of M.-H. Schwartz and R. MacPherson. We present these notions in the framework of the obstruction theory and the Chern-Weil theory. The interplay between these two methods is one of the main features of the monograph.

  10. Cold atoms in singular potentials

    International Nuclear Information System (INIS)

    Denschlag, J. P.

    1998-09-01

    We studied both theoretically and experimentally the interaction between cold Li atoms from a magnetic-optical trap (MOT) and a charged or current-carrying wire. With this system, we were able to realize 1/r 2 and 1/r potentials in two dimensions and to observe the motion of cold atoms in both potentials. For an atom in an attractive 1/r 2 potential, there exist no stable trajectories, instead there is a characteristic class of trajectories for which atoms fall into the singularity. We were able to observe this falling of atoms into the center of the potential. Moreover, by probing the singular 1/r 2 potential with atomic clouds of varying size and temperature we extracted scaling properties of the atom-wire interaction. For very cold atoms, and very thin wires the motion of the atoms must be treated quantum mechanically. Here we predict that the absorption cross section for the 1/r 2 potential should exhibit quantum steps. These quantum steps are a manifestation of the quantum mechanical decomposition of plane waves into partial waves. For the second part of this work, we realized a two dimensional 1/r potential for cold atoms. If the potential is attractive, the atoms can be bound and follow Kepler-like orbits around the wire. The motion in the third dimension along the wire is free. We were able to exploit this property and constructed a novel cold atom guide, the 'Kepler guide'. We also demonstrated another type of atom guide (the 'side guide'), by combining the magnetic field of the wire with a homogeneous offset magnetic field. In this case, the atoms are held in a potential 'tube' on the side of the wire. The versatility, simplicity, and scaling properties of this guide make it an interesting technique. (author)

  11. Singular multiparameter dynamic equations with distributional ...

    African Journals Online (AJOL)

    In this paper, we consider both singular single and several multiparameter second order dynamic equations with distributional potentials on semi-innite time scales. At rst we construct Weyl's theory for the single singular multiparameter dynamic equation with distributional potentials and we prove that the forward jump of at ...

  12. Building Reproducible Science with Singularity Containers

    CERN Document Server

    CERN. Geneva

    2018-01-01

    Michael Bauer first began working with containers at GSI national lab in Darmstadt, Germany, in 2017 while taking a semester off of school at the University of Michigan. Michael met Greg Kurtzer, project lead of Singularity, during his time at GSI and he began contributing heavily to the Singularity project. At the start of summer 2017, Greg hired Michael to work at the ...

  13. Spectral analysis for differential operators with singularities

    Directory of Open Access Journals (Sweden)

    Vjacheslav Anatoljevich Yurko

    2004-01-01

    Full Text Available Nonselfadjoint boundary value problems for second-order differential equations on a finite interval with nonintegrable singularities inside the interval are considered under additional sewing conditions for solutions at the singular point. We study properties of the spectrum, prove the completeness of eigen- and associated functions, and investigate the inverse problem of recovering the boundary value problem from its spectral characteristics.

  14. Singularities in the nonisotropic Boltzmann equation

    International Nuclear Information System (INIS)

    Garibotti, C.R.; Martiarena, M.L.; Zanette, D.

    1987-09-01

    We consider solutions of the nonlinear Boltzmann equation (NLBE) with anisotropic singular initial conditions, which give a simplified model for the penetration of a monochromatic beam on a rarified target. The NLBE is transformed into an integral equation which is solved iteratively and the evolution of the initial singularities is discussed. (author). 5 refs

  15. Timelike Constant Mean Curvature Surfaces with Singularities

    DEFF Research Database (Denmark)

    Brander, David; Svensson, Martin

    2014-01-01

    We use integrable systems techniques to study the singularities of timelike non-minimal constant mean curvature (CMC) surfaces in the Lorentz–Minkowski 3-space. The singularities arise at the boundary of the Birkhoff big cell of the loop group involved. We examine the behavior of the surfaces...

  16. Reasons for singularity in robot teleoperation

    DEFF Research Database (Denmark)

    Marhenke, Ilka; Fischer, Kerstin; Savarimuthu, Thiusius Rajeeth

    2014-01-01

    In this paper, the causes for singularity of a robot arm in teleoperation for robot learning from demonstration are analyzed. Singularity is the alignment of robot joints, which prevents the configuration of the inverse kinematics. Inspired by users' own hypotheses, we investigated speed and delay...

  17. On the genericity of spacetime singularities

    Indian Academy of Sciences (India)

    in terms of the incompleteness of non-space-like geodesics in spacetime. It is possible that such ... outside. The above discussion does not imply the absence of singularity-free solutions to Einstein's equations. ..... spherical collapse also turns out to be a stable feature as implied by the singularity theorems discussed above.

  18. The Geometry of Black Hole Singularities

    Directory of Open Access Journals (Sweden)

    Ovidiu Cristinel Stoica

    2014-01-01

    Full Text Available Recent results show that important singularities in General Relativity can be naturally described in terms of finite and invariant canonical geometric objects. Consequently, one can write field equations which are equivalent to Einstein's at nonsingular points but, in addition remain well-defined and smooth at singularities. The black hole singularities appear to be less undesirable than it was thought, especially after we remove the part of the singularity due to the coordinate system. Black hole singularities are then compatible with global hyperbolicity and do not make the evolution equations break down, when these are expressed in terms of the appropriate variables. The charged black holes turn out to have smooth potential and electromagnetic fields in the new atlas. Classical charged particles can be modeled, in General Relativity, as charged black hole solutions. Since black hole singularities are accompanied by dimensional reduction, this should affect Feynman's path integrals. Therefore, it is expected that singularities induce dimensional reduction effects in Quantum Gravity. These dimensional reduction effects are very similar to those postulated in some approaches to make Quantum Gravity perturbatively renormalizable. This may provide a way to test indirectly the effects of singularities, otherwise inaccessible.

  19. Nietzsche, immortality, singularity and eternal recurrence | Olivier ...

    African Journals Online (AJOL)

    Moreover, once anything has existed, it is in a certain sense, for Nietzsche, necessary despite its temporal singularity. Therefore, to be able to rise to the task of affirming certain actions or experiences in one's own life, bestows on it not merely this kind of necessary singularity, but what he thought of as 'eternal recurrence' –

  20. Discrete variable representation for singular Hamiltonians

    DEFF Research Database (Denmark)

    Schneider, B. I.; Nygaard, Nicolai

    2004-01-01

    We discuss the application of the discrete variable representation (DVR) to Schrodinger problems which involve singular Hamiltonians. Unlike recent authors who invoke transformations to rid the eigenvalue equation of singularities at the cost of added complexity, we show that an approach based...

  1. Singularity is the Future of ICT Research

    African Journals Online (AJOL)

    PROF. OLIVER OSUAGWA

    2014-06-01

    Jun 1, 2014 ... tech systems, and how in the near future. Artificial Intelligence may impact our lives, AI, Robotics, nanotechnology, mechatronics are collaborative agents of technological singularity. The singularity is already here! Think of modern houses now remotely controlled from far distances, think of e-commerce and.

  2. Finite-Time Robust H∞ Control for Uncertain Linear Continuous-Time Singular Systems with Exogenous Disturbances

    Directory of Open Access Journals (Sweden)

    Songlin Wo

    2018-01-01

    Full Text Available Singular systems arise in a great deal of domains of engineering and can be used to solve problems which are more difficult and more extensive than regular systems to solve. Therefore, in this paper, the definition of finite-time robust H∞ control for uncertain linear continuous-time singular systems is presented. The problem we address is to design a robust state feedback controller which can deal with the singular system with time-varying norm-bounded exogenous disturbance, such that the singular system is finite-time robust bounded (FTRB with disturbance attenuation γ. Sufficient conditions for the existence of solutions to this problem are obtained in terms of linear matrix equalities (LMIs. When these LMIs are feasible, the desired robust controller is given. A detailed solving method is proposed for the restricted linear matrix inequalities. Finally, examples are given to show the validity of the methodology.

  3. A singularity extraction technique for computation of antenna aperture fields from singular plane wave spectra

    DEFF Research Database (Denmark)

    Cappellin, Cecilia; Breinbjerg, Olav; Frandsen, Aksel

    2008-01-01

    An effective technique for extracting the singularity of plane wave spectra in the computation of antenna aperture fields is proposed. The singular spectrum is first factorized into a product of a finite function and a singular function. The finite function is inverse Fourier transformed...... numerically using the Inverse Fast Fourier Transform, while the singular function is inverse Fourier transformed analytically, using the Weyl-identity, and the two resulting spatial functions are then convolved to produce the antenna aperture field. This article formulates the theory of the singularity...

  4. Singularity: Scientific containers for mobility of compute.

    Directory of Open Access Journals (Sweden)

    Gregory M Kurtzer

    Full Text Available Here we present Singularity, software developed to bring containers and reproducibility to scientific computing. Using Singularity containers, developers can work in reproducible environments of their choosing and design, and these complete environments can easily be copied and executed on other platforms. Singularity is an open source initiative that harnesses the expertise of system and software engineers and researchers alike, and integrates seamlessly into common workflows for both of these groups. As its primary use case, Singularity brings mobility of computing to both users and HPC centers, providing a secure means to capture and distribute software and compute environments. This ability to create and deploy reproducible environments across these centers, a previously unmet need, makes Singularity a game changing development for computational science.

  5. 32 CFR 1602.22 - Singular and plural.

    Science.gov (United States)

    2010-07-01

    ....22 Singular and plural. Words importing the singular number shall include the plural number, and words importing the plural number shall include the singular, except where the context clearly indicates...

  6. Quaternion from rotation matrix. [four-parameter representation of coordinate transformation matrix

    Science.gov (United States)

    Shepperd, S. W.

    1978-01-01

    A quaternion is regarded as a four-parameter representation of a coordinate transformation matrix, where the four components of the quaternion are treated on an equal basis. This leads to a unified, compact, and singularity-free approach to determining the quaternion when the matrix is given.

  7. Filtering and frequency interpretations of Singular Spectrum Analysis

    Science.gov (United States)

    Harris, T. J.; Yuan, Hui

    2010-10-01

    New filtering and spectral interpretations of Singular Spectrum Analysis (SSA) are provided. It is shown that the variables reconstructed from diagonal averaging of reduced-rank approximations to the trajectory matrix can be obtained from a noncausal convolution filter with zero-phase characteristics. The reconstructed variables are readily constructed using a two-pass filtering algorithm that is well known in the signal processing literature. When the number of rows in the trajectory matrix is much larger than number of columns, many results reported in the signal processing literature can be used to derive the properties of the resulting filters and their spectra. New features of the reconstructed series are revealed using these results. Two examples are used to illustrate the results derived in this paper.

  8. Singular value decomposition for collaborative filtering on a GPU

    Science.gov (United States)

    Kato, Kimikazu; Hosino, Tikara

    2010-06-01

    A collaborative filtering predicts customers' unknown preferences from known preferences. In a computation of the collaborative filtering, a singular value decomposition (SVD) is needed to reduce the size of a large scale matrix so that the burden for the next phase computation will be decreased. In this application, SVD means a roughly approximated factorization of a given matrix into smaller sized matrices. Webb (a.k.a. Simon Funk) showed an effective algorithm to compute SVD toward a solution of an open competition called "Netflix Prize". The algorithm utilizes an iterative method so that the error of approximation improves in each step of the iteration. We give a GPU version of Webb's algorithm. Our algorithm is implemented in the CUDA and it is shown to be efficient by an experiment.

  9. The Matrix Organization Revisited

    DEFF Research Database (Denmark)

    Gattiker, Urs E.; Ulhøi, John Parm

    1999-01-01

    This paper gives a short overview of matrix structure and technology management. It outlines some of the characteristics and also points out that many organizations may actualy be hybrids (i.e. mix several ways of organizing to allocate resorces effectively).......This paper gives a short overview of matrix structure and technology management. It outlines some of the characteristics and also points out that many organizations may actualy be hybrids (i.e. mix several ways of organizing to allocate resorces effectively)....

  10. Big bang and big crunch in matrix string theory

    OpenAIRE

    Bedford, J; Papageorgakis, C; Rodríguez-Gómez, D; Ward, J

    2007-01-01

    Following the holographic description of linear dilaton null Cosmologies with a Big Bang in terms of Matrix String Theory put forward by Craps, Sethi and Verlinde, we propose an extended background describing a Universe including both Big Bang and Big Crunch singularities. This belongs to a class of exact string backgrounds and is perturbative in the string coupling far away from the singularities, both of which can be resolved using Matrix String Theory. We provide a simple theory capable of...

  11. Enhanced aging properties of HKUST-1 in hydrophobic mixed-matrix membranes for ammonia adsorption? ?Electronic supplementary information (ESI) available: Experimental procedures. See DOI: 10.1039/c5sc04368a Click here for additional data file.

    OpenAIRE

    DeCoste, Jared B.; Denny, Jr., Michael S.; Peterson, Gregory W.; Mahle, John J.; Cohen, Seth M.

    2016-01-01

    Metal?organic frameworks (MOFs) in their free powder form have exhibited superior capacities for many gases when compared to other materials, due to their tailorable functionality and high surface areas. Specifically, the MOF HKUST-1 binds small Lewis bases, such as ammonia, with its coordinatively unsaturated copper sites. We describe here the use of HKUST-1 in mixed-matrix membranes (MMMs) prepared from polyvinylidene difluoride (PVDF) for the removal of ammonia gas. These MMMs exhibit ammo...

  12. On bulk singularity structures and all order α′ contact terms of BPS string amplitudes

    Directory of Open Access Journals (Sweden)

    Ehsan Hatefi

    2016-10-01

    Full Text Available The entire form of the amplitude of three SYM (involving two transverse scalar fields, a gauge field and a potential Cn−1 Ramond–Ramond (RR form field is found out. We first derive and then start constructing an infinite number of t,s channel bulk singularity structures by means of all order α′ corrections to pull-back of brane in an Effective Field Theory (EFT. Due to presence of the complete form of S-matrix, several new contact interactions as well as new couplings are explored. It is also shown that these couplings can be verified at the level of EFT by either the combinations of Myers terms, pull-back, Taylor expanded of scalar fields or the mixed combination of the couplings of this paper as well as employed Bianchi identities. For the first time, we also derive the algebraic and the complete form of the integrations for some arbitrary combinations of Mandelstam variables and for the most general case ∫d2z|1−z|a|z|b(z−z¯c(z+z¯3 on upper half plane as well.

  13. Topology of singular fibers of differentiable maps

    CERN Document Server

    Saeki, Osamu

    2004-01-01

    The volume develops a thorough theory of singular fibers of generic differentiable maps. This is the first work that establishes the foundational framework of the global study of singular differentiable maps of negative codimension from the viewpoint of differential topology. The book contains not only a general theory, but also some explicit examples together with a number of very concrete applications. This is a very interesting subject in differential topology, since it shows a beautiful interplay between the usual theory of singularities of differentiable maps and the geometric topology of manifolds.

  14. Quantization function for attractive, singular potential tails

    International Nuclear Information System (INIS)

    Raab, Patrick N.

    2010-01-01

    The interaction between atoms and molecules with each other are deep potential wells with attractive, singular tails. Bound state energies are determined by a quantization function according to a simple quantization rule. This function is dominantly determined by the singular potential tail for near-threshold states. General expressions for the low- and high-energy contributions of the singular potential tail to the quantization function, as well as the connection to the scattering length are presented in two and three dimensions. Precise analytical expressions for the quantization function are determined for the case of potential tails proportional to -1/r 4 and -1/r 6 for three dimensions. (orig.)

  15. DEKOMPOSISI NILAI SINGULAR PADA SISTEM PENGENALAN WAJAH

    Directory of Open Access Journals (Sweden)

    Beni Utomo

    2012-11-01

    Full Text Available Dekomposisi Nilai Singular atau Singular Value Decomposition (SVDmerupakan salah satu cara untuk menyatakan Principal Component Analysis (PCA.PCA sendiri merupakan suatu proses untuk menemukan kontributor-kontributorpenting dari suatu data berdasarkan besaran statistika deviasi standart dan variansi.SVD merupakan proses untuk mendapatkan matriks diagonal yang elementak nolnya merupakan nilai singular yang akarnya merupakan eigenvalue.SVD atas matriks kovarian C berbentuk C = U?V T dengan matriks U dan Vmemuat eigenvektor yang sudah terurut dari nilai variansi terbesar ke nilai variansiterkecilnya. Variansi terbesar memiliki arti eigenvektor menangkap ciri-ciri yangpaling banyak berubah. Sifat inilah yang dipakai untuk membentuk eigenface.

  16. Singular mean-filed games

    KAUST Repository

    Cirant, Marco

    2016-11-22

    Here, we prove the existence of smooth solutions for mean-field games with a singular mean-field coupling; that is, a coupling in the Hamilton-Jacobi equation of the form $g(m)=-m^{-\\\\alpha}$. We consider stationary and time-dependent settings. The function $g$ is monotone, but it is not bounded from below. With the exception of the logarithmic coupling, this is the first time that MFGs whose coupling is not bounded from below is examined in the literature. This coupling arises in models where agents have a strong preference for low-density regions. Paradoxically, this causes the agents to spread and prevents the creation of solutions with a very-low density. To prove the existence of solutions, we consider an approximate problem for which the existence of smooth solutions is known. Then, we prove new a priori bounds for the solutions that show that $\\\\frac 1 m$ is bounded. Finally, using a limiting argument, we obtain the existence of solutions. The proof in the stationary case relies on a blow-up argument and in the time-dependent case on new bounds for $m^{-1}$.

  17. Singularity structure of the two-point function in quantum field theory in curved spacetime, II

    International Nuclear Information System (INIS)

    Fulling, S.A.; Narcowich, F.J.; Wald, R.M.

    1981-01-01

    We prove that, for a massive, scalar, quantum field in a wide class of static spacetimes, the two-point function has singularity structure of the Hadamard form. In particular, this implies that the point-splitting renormalization prescription is well defined in these spacetimes. As a corollary of this result and a previous result of Fulling, Sweeny, and Wald, we show that in an arbitrary globally hyperbolic spacetime there always exists a large class of states for which the singular part of the two-point function has the Hadamard form. In addition, we prove that, for a closed universe which is both initially and finally static, the S-matrix exists

  18. Relative Error Model Reduction via Time-Weighted Balanced Stochastic Singular Perturbation

    DEFF Research Database (Denmark)

    Tahavori, Maryamsadat; Shaker, Hamid Reza

    2012-01-01

    A new mixed method for relative error model reduction of linear time invariant (LTI) systems is proposed in this paper. This order reduction technique is mainly based upon time-weighted balanced stochastic model reduction method and singular perturbation model reduction technique. Compared...

  19. Algunas aclaraciones acerca del conocimiento del singular.

    Directory of Open Access Journals (Sweden)

    Carlos Llano Cifuentes

    2013-11-01

    Full Text Available Llano tries to explain the main purpose of El Conocimiento del Singular, showing how the individuals about which the book is concerned are basically human individuals: people as decision makers.

  20. Technological Singularity: What Do We Really Know?

    Directory of Open Access Journals (Sweden)

    Alexey Potapov

    2018-04-01

    Full Text Available The concept of the technological singularity is frequently reified. Futurist forecasts inferred from this imprecise reification are then criticized, and the reified ideas are incorporated in the core concept. In this paper, I try to disentangle the facts related to the technological singularity from more speculative beliefs about the possibility of creating artificial general intelligence. I use the theory of metasystem transitions and the concept of universal evolution to analyze some misconceptions about the technological singularity. While it may be neither purely technological, nor truly singular, we can predict that the next transition will take place, and that the emerged metasystem will demonstrate exponential growth in complexity with a doubling time of less than half a year, exceeding the complexity of the existing cybernetic systems in few decades.

  1. Topological Signals of Singularities in Ricci Flow

    Directory of Open Access Journals (Sweden)

    Paul M. Alsing

    2017-08-01

    Full Text Available We implement methods from computational homology to obtain a topological signal of singularity formation in a selection of geometries evolved numerically by Ricci flow. Our approach, based on persistent homology, produces precise, quantitative measures describing the behavior of an entire collection of data across a discrete sample of times. We analyze the topological signals of geometric criticality obtained numerically from the application of persistent homology to models manifesting singularities under Ricci flow. The results we obtain for these numerical models suggest that the topological signals distinguish global singularity formation (collapse to a round point from local singularity formation (neckpinch. Finally, we discuss the interpretation and implication of these results and future applications.

  2. Finite conformal quantum gravity and spacetime singularities

    Science.gov (United States)

    Modesto, Leonardo; Rachwał, Lesław

    2017-12-01

    We show that a class of finite quantum non-local gravitational theories is conformally invariant at classical as well as at quantum level. This is actually a range of conformal anomaly-free theories in the spontaneously broken phase of the Weyl symmetry. At classical level we show how the Weyl conformal invariance is able to tame all the spacetime singularities that plague not only Einstein gravity, but also local and weakly non-local higher derivative theories. The latter statement is proved by a singularity theorem that applies to a large class of weakly non-local theories. Therefore, we are entitled to look for a solution of the spacetime singularity puzzle in a missed symmetry of nature, namely the Weyl conformal symmetry. Following the seminal paper by Narlikar and Kembhavi, we provide an explicit construction of singularity-free black hole exact solutions in a class of conformally invariant theories.

  3. Geometric Singularities of the Stokes Problem

    Directory of Open Access Journals (Sweden)

    Nejmeddine Chorfi

    2014-01-01

    Full Text Available When the domain is a polygon of ℝ2, the solution of a partial differential equation is written as a sum of a regular part and a linear combination of singular functions. The purpose of this paper is to present explicitly the singular functions of Stokes problem. We prove the Kondratiev method in the case of the crack. We finish by giving some regularity results.

  4. Singularity analysis, Hadamard products, and tree recurrences

    Science.gov (United States)

    Fill, James Allen; Flajolet, Philippe; Kapur, Nevin

    2005-02-01

    We present a toolbox for extracting asymptotic information on the coefficients of combinatorial generating functions. This toolbox notably includes a treatment of the effect of Hadamard products on singularities in the context of the complex Tauberian technique known as singularity analysis. As a consequence, it becomes possible to unify the analysis of a number of divide-and-conquer algorithms, or equivalently random tree models, including several classical methods for sorting, searching, and dynamically managing equivalence relations.

  5. Finite-Time Stability Analysis of Discrete-Time Linear Singular Systems

    Directory of Open Access Journals (Sweden)

    Songlin Wo

    2014-01-01

    Full Text Available The finite-time stability (FTS problem of discrete-time linear singular systems (DTLSS is considered in this paper. A necessary and sufficient condition for FTS is obtained, which can be expressed in terms of matrix inequalities. Then, another form of the necessary and sufficient condition for FTS is also given by using matrix-null space technology. In order to solve the stability problem expediently, a sufficient condition for FTS is given via linear matrix inequality (LMI approach; this condition can be expressed in terms of LMIs. Finally, an illustrating example is also given to show the effectiveness of the proposed method.

  6. Observational constraints on cosmological future singularities

    Energy Technology Data Exchange (ETDEWEB)

    Beltran Jimenez, Jose [Aix Marseille Univ, Universite de Toulon CNRS, CPT, Marseille (France); Lazkoz, Ruth [Euskal Herriko Unibertsitatea, Fisika Teorikoaren eta Zientziaren Historia Saila, Zientzia eta Teknologia Fakultatea, Bilbao (Spain); Saez-Gomez, Diego [Faculdade de Ciencias da Universidade de Lisboa, Departamento de Fisica, Instituto de Astrofisica e Ciencias do Espaco, Lisbon (Portugal); Salzano, Vincenzo [University of Szczecin, Institute of Physics, Szczecin (Poland)

    2016-11-15

    In this work we consider a family of cosmological models featuring future singularities. This type of cosmological evolution is typical of dark energy models with an equation of state violating some of the standard energy conditions (e.g. the null energy condition). Such a kind of behavior, widely studied in the literature, may arise in cosmologies with phantom fields, theories of modified gravity or models with interacting dark matter/dark energy. We briefly review the physical consequences of these cosmological evolution regarding geodesic completeness and the divergence of tidal forces in order to emphasize under which circumstances the singularities in some cosmological quantities correspond to actual singular spacetimes. We then introduce several phenomenological parameterizations of the Hubble expansion rate to model different singularities existing in the literature and use SN Ia, BAO and H(z) data to constrain how far in the future the singularity needs to be (under some reasonable assumptions on the behavior of the Hubble factor). We show that, for our family of parameterizations, the lower bound for the singularity time cannot be smaller than about 1.2 times the age of the universe, what roughly speaking means ∝2.8 Gyrs from the present time. (orig.)

  7. Singular formalism and admissible control of spacecraft with rotating flexible solar array

    Directory of Open Access Journals (Sweden)

    Lu Dongning

    2014-02-01

    Full Text Available This paper is concerned with the attitude control of a three-axis-stabilized spacecraft which consists of a central rigid body and a flexible sun-tracking solar array driven by a solar array drive assembly. Based on the linearization of the dynamics of the spacecraft and the modal identities about the flexible and rigid coupling matrices, the spacecraft attitude dynamics is reduced to a formally singular system with periodically varying parameters, which is quite different from a spacecraft with fixed appendages. In the framework of the singular control theory, the regularity and impulse-freeness of the singular system is analyzed and then admissible attitude controllers are designed by Lyapunov’s method. To improve the robustness against system uncertainties, an H∞ optimal control is designed by optimizing the H∞ norm of the system transfer function matrix. Comparative numerical experiments are performed to verify the theoretical results.

  8. Singular and degenerate cauchy problems

    CERN Document Server

    Carroll, R.W

    1976-01-01

    In this book, we study theoretical and practical aspects of computing methods for mathematical modelling of nonlinear systems. A number of computing techniques are considered, such as methods of operator approximation with any given accuracy; operator interpolation techniques including a non-Lagrange interpolation; methods of system representation subject to constraints associated with concepts of causality, memory and stationarity; methods of system representation with an accuracy that is the best within a given class of models; methods of covariance matrix estimation;methods for low-rank mat

  9. Treating singularities present in the Sutcliffe-Tennyson vibrational Hamiltonian in orthogonal internal coordinates

    Science.gov (United States)

    Czakó, Gábor; Szalay, Viktor; Császár, Attila G.; Furtenbacher, Tibor

    2005-01-01

    Two methods are developed, when solving the related time-independent Schrödinger equation (TISE), to cope with the singular terms of the vibrational kinetic energy operator of a triatomic molecule given in orthogonal internal coordinates. The first method provides a mathematically correct treatment of all singular terms. The vibrational eigenfunctions are approximated by linear combinations of functions of a three-dimensional nondirect-product basis, where basis functions are formed by coupling Bessel-DVR functions, where DVR stands for discrete variable representation, depending on distance-type coordinates and Legendre polynomials depending on angle bending. In the second method one of the singular terms related to a distance-type coordinate, deemed to be unimportant for spectroscopic applications, is given no special treatment. Here the basis set is obtained by taking the direct product of a one-dimensional DVR basis with a two-dimensional nondirect-product basis, the latter formed by coupling Bessel-DVR functions and Legendre polynomials. With the basis functions defined, matrix representations of the TISE are set up and solved numerically to obtain the vibrational energy levels of H3+. The numerical calculations show that the first method treating all singularities is computationally inefficient, while the second method treating properly only the singularities having physical importance is quite efficient.

  10. Measurement of the leaching rate of radionuclide 134Cs from the solidified radioactive sources in Portland cement mixed with microsilica and barite matrixes

    International Nuclear Information System (INIS)

    Shaaban, Ismail; Assi, Nasim

    2011-01-01

    Portland cement was mixed with radionuclide 134 Cs to produce low-level radioactive sources. These sources were surrounded with cement mixed with different materials like microsilica and barite. The leaching rate of 134 Cs from the solidified radioactive source in Portland cement alone was found to be 4.481 x 10 -4 g/cm 2 per day. Mixing this Portland cement with microsilica and with barite reduced significantly the leaching rate to 1.091 x 10 -4 g/cm 2 per day and 3.153 x 10 -4 g/cm 2 per day for 1 wt.% mixing, and to 1.401 x 10 -5 g/cm 2 per day and 1.703 x 10 -4 g/cm 2 per day for 3 wt.% mixing, respectively. It was also found that the application of a latex paint reduced these leaching rates by about 6.5%, 20.3% and 13.3% for Portland cement, cement mixed with microsilica and with barite, respectively. The leaching data were also analyzed using the polynomial method. The obtained results showed that cement mixed with microsilica and with barite can be effectively used for radioactive sources solidification.

  11. The Analysis of Two-Way Functional Data Using Two-Way Regularized Singular Value Decompositions

    KAUST Repository

    Huang, Jianhua Z.

    2009-12-01

    Two-way functional data consist of a data matrix whose row and column domains are both structured, for example, temporally or spatially, as when the data are time series collected at different locations in space. We extend one-way functional principal component analysis (PCA) to two-way functional data by introducing regularization of both left and right singular vectors in the singular value decomposition (SVD) of the data matrix. We focus on a penalization approach and solve the nontrivial problem of constructing proper two-way penalties from oneway regression penalties. We introduce conditional cross-validated smoothing parameter selection whereby left-singular vectors are cross- validated conditional on right-singular vectors, and vice versa. The concept can be realized as part of an alternating optimization algorithm. In addition to the penalization approach, we briefly consider two-way regularization with basis expansion. The proposed methods are illustrated with one simulated and two real data examples. Supplemental materials available online show that several "natural" approaches to penalized SVDs are flawed and explain why so. © 2009 American Statistical Association.

  12. EISPACK, Subroutines for Eigenvalues, Eigenvectors, Matrix Operations

    International Nuclear Information System (INIS)

    Garbow, Burton S.; Cline, A.K.; Meyering, J.

    1993-01-01

    1 - Description of problem or function: EISPACK3 is a collection of 75 FORTRAN subroutines, both single- and double-precision, that compute the eigenvalues and eigenvectors of nine classes of matrices. The package can determine the Eigen-system of complex general, complex Hermitian, real general, real symmetric, real symmetric band, real symmetric tridiagonal, special real tridiagonal, generalized real, and generalized real symmetric matrices. In addition, there are two routines which use the singular value decomposition to solve certain least squares problem. The individual subroutines are - Identification/Description: BAKVEC: Back transform vectors of matrix formed by FIGI; BALANC: Balance a real general matrix; BALBAK: Back transform vectors of matrix formed by BALANC; BANDR: Reduce sym. band matrix to sym. tridiag. matrix; BANDV: Find some vectors of sym. band matrix; BISECT: Find some values of sym. tridiag. matrix; BQR: Find some values of sym. band matrix; CBABK2: Back transform vectors of matrix formed by CBAL; CBAL: Balance a complex general matrix; CDIV: Perform division of two complex quantities; CG: Driver subroutine for a complex general matrix; CH: Driver subroutine for a complex Hermitian matrix; CINVIT: Find some vectors of complex Hess. matrix; COMBAK: Back transform vectors of matrix formed by COMHES; COMHES: Reduce complex matrix to complex Hess. (elementary); COMLR: Find all values of complex Hess. matrix (LR); COMLR2: Find all values/vectors of cmplx Hess. matrix (LR); CCMQR: Find all values of complex Hessenberg matrix (QR); COMQR2: Find all values/vectors of cmplx Hess. matrix (QR); CORTB: Back transform vectors of matrix formed by CORTH; CORTH: Reduce complex matrix to complex Hess. (unitary); CSROOT: Find square root of complex quantity; ELMBAK: Back transform vectors of matrix formed by ELMHES; ELMHES: Reduce real matrix to real Hess. (elementary); ELTRAN: Accumulate transformations from ELMHES (for HQR2); EPSLON: Estimate unit roundoff

  13. Infrared singularities of scattering amplitudes in perturbative QCD

    Energy Technology Data Exchange (ETDEWEB)

    Becher, Thomas [Fermi National Accelerator Laboratory (FNAL), Batavia, IL (United States); Neubert, Matthias [Johannes Gutenberg-Universitaet Mainz, Mainz (Germany)

    2013-11-01

    An exact formula is derived for the infrared singularities of dimensionally regularized scattering amplitudes in massless QCD with an arbitrary number of legs, valid at any number of loops. It is based on the conjecture that the anomalous-dimension matrix of n-jet operators in soft-collinear effective theory contains only a single non-trivial color structure, whose coefficient is the cusp anomalous dimension of Wilson loops with light-like segments. Its color-diagonal part is characterized by two anomalous dimensions, which are extracted to three-loop order from known perturbative results for the quark and gluon form factors. This allows us to predict the three-loop coefficients of all 1/epsilon^k poles for an arbitrary n-parton scattering amplitudes, generalizing existing two-loop results.

  14. Singularity hypotheses a scientific and philosophical assessment

    CERN Document Server

    Moor, James; Søraker, Johnny; Steinhart, Eric

    2012-01-01

    Singularity Hypotheses: A Scientific and Philosophical Assessment offers authoritative, jargon-free essays and critical commentaries on accelerating technological progress and the notion of technological singularity. It focuses on conjectures about the intelligence explosion, transhumanism, and whole brain emulation. Recent years have seen a plethora of forecasts about the profound, disruptive impact that is likely to result from further progress in these areas. Many commentators however doubt the scientific rigor of these forecasts, rejecting them as speculative and unfounded. We therefore invited prominent computer scientists, physicists, philosophers, biologists, economists and other thinkers to assess the singularity hypotheses. Their contributions go beyond speculation, providing deep insights into the main issues and a balanced picture of the debate.

  15. Phantom cosmology without Big Rip singularity

    Energy Technology Data Exchange (ETDEWEB)

    Astashenok, Artyom V. [Baltic Federal University of I. Kant, Department of Theoretical Physics, 236041, 14, Nevsky st., Kaliningrad (Russian Federation); Nojiri, Shin' ichi, E-mail: nojiri@phys.nagoya-u.ac.jp [Department of Physics, Nagoya University, Nagoya 464-8602 (Japan); Kobayashi-Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Odintsov, Sergei D. [Department of Physics, Nagoya University, Nagoya 464-8602 (Japan); Institucio Catalana de Recerca i Estudis Avancats - ICREA and Institut de Ciencies de l' Espai (IEEC-CSIC), Campus UAB, Facultat de Ciencies, Torre C5-Par-2a pl, E-08193 Bellaterra (Barcelona) (Spain); Tomsk State Pedagogical University, Tomsk (Russian Federation); Yurov, Artyom V. [Baltic Federal University of I. Kant, Department of Theoretical Physics, 236041, 14, Nevsky st., Kaliningrad (Russian Federation)

    2012-03-23

    We construct phantom energy models with the equation of state parameter w which is less than -1, w<-1, but finite-time future singularity does not occur. Such models can be divided into two classes: (i) energy density increases with time ('phantom energy' without 'Big Rip' singularity) and (ii) energy density tends to constant value with time ('cosmological constant' with asymptotically de Sitter evolution). The disintegration of bound structure is confirmed in Little Rip cosmology. Surprisingly, we find that such disintegration (on example of Sun-Earth system) may occur even in asymptotically de Sitter phantom universe consistent with observational data. We also demonstrate that non-singular phantom models admit wormhole solutions as well as possibility of Big Trip via wormholes.

  16. Dispersion and betatron function correction in the Advanced Photon Source storage ring using singular value decomposition.

    Energy Technology Data Exchange (ETDEWEB)

    Emery, L.

    1999-04-13

    Magnet errors and off-center orbits through sextuples perturb the dispersion and beta functions in a storage ring (SR), which affects machine performance. In a large ring such as the Advanced Photon Source (APS), the magnet errors are difficult to determine with beam-based methods. Also the non-zero orbit through sextuples result from user requests for steering at light source points. For expediency, a singular value decomposition (SVD) matrix method analogous to orbit correction was adopted to make global corrections to these functions using strengths of several quadrupoles as correcting elements. The direct response matrix is calculated from the model of the perfect lattice. The inverse is calculated by SVD with a selected number of singular vectors. Resulting improvement in the lattice functions and machine performance will be presented.

  17. Computing singularly perturbed differential equations

    Science.gov (United States)

    Chatterjee, Sabyasachi; Acharya, Amit; Artstein, Zvi

    2018-02-01

    A computational tool for coarse-graining nonlinear systems of ordinary differential equations in time is discussed. Three illustrative model examples are worked out that demonstrate the range of capability of the method. This includes the averaging of Hamiltonian as well as dissipative microscopic dynamics whose 'slow' variables, defined in a precise sense, can often display mixed slow-fast response as in relaxation oscillations, and dependence on initial conditions of the fast variables. Also covered is the case where the quasi-static assumption in solid mechanics is violated. The computational tool is demonstrated to capture all of these behaviors in an accurate and robust manner, with significant savings in time. A practically useful strategy for accurately initializing short bursts of microscopic runs for the evolution of slow variables is integral to our scheme, without the requirement that the slow variables determine a unique invariant measure of the microscopic dynamics.

  18. Singular vectors for the WN algebras

    Science.gov (United States)

    Ridout, David; Siu, Steve; Wood, Simon

    2018-03-01

    In this paper, we use free field realisations of the A-type principal, or Casimir, WN algebras to derive explicit formulae for singular vectors in Fock modules. These singular vectors are constructed by applying screening operators to Fock module highest weight vectors. The action of the screening operators is then explicitly evaluated in terms of Jack symmetric functions and their skew analogues. The resulting formulae depend on sequences of pairs of integers that completely determine the Fock module as well as the Jack symmetric functions.

  19. A singular value decomposition linear programming (SVDLP) optimization technique for circular cone based robotic radiotherapy

    Science.gov (United States)

    Liang, Bin; Li, Yongbao; Wei, Ran; Guo, Bin; Xu, Xuang; Liu, Bo; Li, Jiafeng; Wu, Qiuwen; Zhou, Fugen

    2018-01-01

    With robot-controlled linac positioning, robotic radiotherapy systems such as CyberKnife significantly increase freedom of radiation beam placement, but also impose more challenges on treatment plan optimization. The resampling mechanism in the vendor-supplied treatment planning system (MultiPlan) cannot fully explore the increased beam direction search space. Besides, a sparse treatment plan (using fewer beams) is desired to improve treatment efficiency. This study proposes a singular value decomposition linear programming (SVDLP) optimization technique for circular collimator based robotic radiotherapy. The SVDLP approach initializes the input beams by simulating the process of covering the entire target volume with equivalent beam tapers. The requirements on dosimetry distribution are modeled as hard and soft constraints, and the sparsity of the treatment plan is achieved by compressive sensing. The proposed linear programming (LP) model optimizes beam weights by minimizing the deviation of soft constraints subject to hard constraints, with a constraint on the l 1 norm of the beam weight. A singular value decomposition (SVD) based acceleration technique was developed for the LP model. Based on the degeneracy of the influence matrix, the model is first compressed into lower dimension for optimization, and then back-projected to reconstruct the beam weight. After beam weight optimization, the number of beams is reduced by removing the beams with low weight, and optimizing the weights of the remaining beams using the same model. This beam reduction technique is further validated by a mixed integer programming (MIP) model. The SVDLP approach was tested on a lung case. The results demonstrate that the SVD acceleration technique speeds up the optimization by a factor of 4.8. Furthermore, the beam reduction achieves a similar plan quality to the globally optimal plan obtained by the MIP model, but is one to two orders of magnitude faster. Furthermore, the SVDLP

  20. Existence of positive solutions and eigenvalues intervals for nonlinear Sturm Liouville problems with a singular interface

    Directory of Open Access Journals (Sweden)

    D. K. K. Vamsi

    2012-03-01

    Full Text Available In this article, we define the Green's matrix for a nonlinear Sturm Liouville problem associated with a pair of dynamic equations on time scales with a singularity at the point of interface. Then using iterative techniques, we obtain eigenvalue intervals for which there exist positive solutions. Then we present iterative schemes for approximating the solutions, and discus an example that illustrates the the results obtained.

  1. Interaction of two singular Lissajous lines in free space.

    Science.gov (United States)

    Chen, Haitao; Gao, Zenghui; Wang, Wanqing

    2017-05-20

    The interaction of two singular Lissajous lines emergent from a polychromatic vector beam is studied. It is shown that singular Lissajous lines disappear with propagation; meanwhile Lissajous singularities take place. The handedness reversal, the changes in the shape of Lissajous figures, and the degree of polarization of Lissajous singularities, as well as the creation and annihilation of a single singularity, may appear by varying the control parameters. In addition, the transformation of the shape of line h=0, the creation and annihilation of pairs of Lissajous singularities not only with opposite topological charge and same handedness, but also with same degree of polarization, take place with propagation.

  2. The setting time of a clay-slag geopolymer matrix: the influence of blast-furnace-slag addition and the mixing method

    Czech Academy of Sciences Publication Activity Database

    Perná, Ivana; Hanzlíček, Tomáš

    112, Part 1, JAN 20 (2016), s. 1150-1155 ISSN 0959-6526 Institutional support: RVO:67985891 Keywords : blast-furnace slag * geopolymer * setting time * mixing method * solidification * recycling Subject RIV: DM - Solid Waste and Recycling Impact factor: 5.715, year: 2016

  3. DLCQ and plane wave matrix Big Bang models

    Science.gov (United States)

    Blau, Matthias; O'Loughlin, Martin

    2008-09-01

    We study the generalisations of the Craps-Sethi-Verlinde matrix big bang model to curved, in particular plane wave, space-times, beginning with a careful discussion of the DLCQ procedure. Singular homogeneous plane waves are ideal toy-models of realistic space-time singularities since they have been shown to arise universally as their Penrose limits, and we emphasise the role played by the symmetries of these plane waves in implementing the flat space Seiberg-Sen DLCQ prescription for these curved backgrounds. We then analyse various aspects of the resulting matrix string Yang-Mills theories, such as the relation between strong coupling space-time singularities and world-sheet tachyonic mass terms. In order to have concrete examples at hand, in an appendix we determine and analyse the IIA singular homogeneous plane wave - null dilaton backgrounds.

  4. DLCQ and plane wave matrix Big Bang models

    International Nuclear Information System (INIS)

    Blau, Matthias; O'Loughlin, Martin

    2008-01-01

    We study the generalisations of the Craps-Sethi-Verlinde matrix big bang model to curved, in particular plane wave, space-times, beginning with a careful discussion of the DLCQ procedure. Singular homogeneous plane waves are ideal toy-models of realistic space-time singularities since they have been shown to arise universally as their Penrose limits, and we emphasise the role played by the symmetries of these plane waves in implementing the flat space Seiberg-Sen DLCQ prescription for these curved backgrounds. We then analyse various aspects of the resulting matrix string Yang-Mills theories, such as the relation between strong coupling space-time singularities and world-sheet tachyonic mass terms. In order to have concrete examples at hand, in an appendix we determine and analyse the IIA singular homogeneous plane wave - null dilaton backgrounds.

  5. Singular Linear Differential Equations in Two Variables

    NARCIS (Netherlands)

    Braaksma, B.L.J.; Put, M. van der

    2008-01-01

    The formal and analytic classification of integrable singular linear differential equations has been studied among others by R. Gerard and Y. Sibuya. We provide a simple proof of their main result, namely: For certain irregular systems in two variables there is no Stokes phenomenon, i.e. there is no

  6. A singularity theorem based on spatial averages

    Indian Academy of Sciences (India)

    Inspired by Raychaudhuri's work, and using the equation named after him as a basic ingredient, a new singularity theorem is proved. Open non-rotating Universes, expanding everywhere with a non-vanishing spatial average of the matter variables, show severe geodesic incompletness in the past. Another way of stating ...

  7. Supersymmetric quantum mechanics under point singularities

    International Nuclear Information System (INIS)

    Uchino, Takashi; Tsutsui, Izumi

    2003-01-01

    We provide a systematic study on the possibility of supersymmetry (SUSY) for one-dimensional quantum mechanical systems consisting of a pair of lines R or intervals [-l, l] each having a point singularity. We consider the most general singularities and walls (boundaries) at x = ±l admitted quantum mechanically, using a U(2) family of parameters to specify one singularity and similarly a U(1) family of parameters to specify one wall. With these parameter freedoms, we find that for a certain subfamily the line systems acquire an N = 1 SUSY which can be enhanced to N = 4 if the parameters are further tuned, and that these SUSY are generically broken except for a special case. The interval systems, on the other hand, can accommodate N = 2 or N = 4 SUSY, broken or unbroken, and exhibit a rich variety of (degenerate) spectra. Our SUSY systems include the familiar SUSY systems with the Dirac δ(x)-potential, and hence are extensions of the known SUSY quantum mechanics to those with general point singularities and walls. The self-adjointness of the supercharge in relation to the self-adjointness of the Hamiltonian is also discussed

  8. Resolving curvature singularities in holomorphic gravity

    NARCIS (Netherlands)

    Mantz, C.L.M.; Prokopec, T.

    2011-01-01

    We formulate a holomorphic theory of gravity and study how the holomorphy symmetry alters the two most important singular solutions of general relativity: black holes and cosmology. We show that typical observers (freely) falling into a holomorphic black hole do not encounter a curvature

  9. Classical resolution of singularities in dilaton cosmologies

    NARCIS (Netherlands)

    Bergshoeff, EA; Collinucci, A; Roest, D; Russo, JG; Townsend, PK

    2005-01-01

    For models of dilaton gravity with a possible exponential potential, such as the tensor-scalar sector of ITA supergravity, we show how cosmological solutions correspond to trajectories in a 2D Milne space (parametrized by the dilaton and the scale factor). Cosmological singularities correspond to

  10. Mobile communications technology: The singular factor responsible ...

    African Journals Online (AJOL)

    This paper investigated the factors responsible for the growth of Internet usage on the African continent. The principal finding was that increasing growth of Internet usage is also down to one singular factor: mobile communications technology. The proliferation of mobile phone usage in Africa has resulted in the sustained ...

  11. Singular Nonlinear H∞ Optimal Control Problem

    NARCIS (Netherlands)

    Schaft, A.J. van der

    1996-01-01

    The theory of nonlinear H∞ optimal control for affine nonlinear systems is extended to the more general context of singular H∞ optimal control of nonlinear systems using ideas from the linear H∞ theory. Our approach yields under certain assumptions a necessary and sufficient condition for

  12. Ray tracing in anisotropic media with singularities

    Czech Academy of Sciences Publication Activity Database

    Vavryčuk, Václav

    2001-01-01

    Roč. 145, č. 1 (2001), s. 265-276 ISSN 0956-540X R&D Projects: GA ČR GA205/00/1350 Institutional research plan: CEZ:AV0Z3012916 Keywords : anisotropic media * ray tracing * singularities Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 1.366, year: 2001

  13. Inverting dedevelopment: geometric singularity theory in embryology

    Science.gov (United States)

    Bookstein, Fred L.; Smith, Bradley R.

    2000-10-01

    The diffeomorphism model so useful in the biomathematics of normal morphological variability and disease is inappropriate for applications in embryogenesis, where whole coordinate patches are created out of single points. For this application we need a suitable algebra for the creation of something from nothing in a carefully organized geometry: a formalism for parameterizing discrete nondifferentiabilities of invertible functions on Rk, k $GTR 1. One easy way to begin is via the inverse of the development map - call it the dedevelopment map, the deformation backwards in time. Extrapolated, this map will inevitably have singularities at which its derivative is zero. When the dedevelopment map is inverted to face forward in time, the singularities become appropriately isolated infinities of derivative. We have recently introduced growth visualizations via extrapolations to the isolated singularities at which only one directional derivative is zero. Maps inverse to these create new coordinate patches directionally rather than radically. The most generic singularity that suits this purpose is the crease f(x,y) equals (x,x2y+y3), which has already been applied in morphometrics for the description of focal morphogenetic phenomena. We apply it to embryogenesis in the form of its analytic inverse, and demonstrate its power using a priceless new data set of mouse embryos imaged in 3D by micro-MR with voxels smaller than 100micrometers 3.

  14. On the genericity of spacetime singularities

    Indian Academy of Sciences (India)

    the framework of a general spacetime without any symmetry conditions, in terms of the overall behaviour of .... We now outline the basic idea and the chain of logic behind the proof of a typical singularity theorem ..... a detailed investigation of the dynamics of gravitational collapse within the frame- work of Einstein's theory.

  15. 'Footballs', conical singularities, and the Liouville equation

    International Nuclear Information System (INIS)

    Redi, Michele

    2005-01-01

    We generalize the football shaped extra dimensions scenario to an arbitrary number of branes. The problem is related to the solution of the Liouville equation with singularities, and explicit solutions are presented for the case of three branes. The tensions of the branes do not need to be tuned with each other but only satisfy mild global constraints

  16. Preparation and electrochemical characterization of polyvinylchloride/ FeTiO{sub 3}-co-Fe{sub 3}O{sub 4} nanoparticles mixed matrix ion exchange membranes: Investigation of concentration and pH effects

    Energy Technology Data Exchange (ETDEWEB)

    Hosseini, Sayedmohsen; Hamidi, Alireza; Moghadassi, Abdolreza; Parvizian, Fahime [Faculty of Engineering, Arak University, Arak (Iran, Islamic Republic of); Madaeni, Sayed Siavash [Faculty of Engineering, Razi University, Kermanshah (Iran, Islamic Republic of)

    2015-09-15

    Polyvinyl chloride based/FeTiO{sub 3}-co-Fe{sub 3}O{sub 4} nanoparticles mixed matrix heterogeneous cation exchange membranes were prepared by solution casting technique. The effect of using filler additives in casting solution and also electrolyte concentration and pH on electrochemical properties of membrane was studied. Membrane potential, transport number and selectivity were improved by using FeTiO{sub 3}/Fe{sub 3}O{sub 4} nanoparticles in membrane matrix. Utilizing FeTiO{sub 3}/ Fe{sub 3}O{sub 4} nanoparticles in membrane matrix also led to improvement of membrane ionic flux from 2.95*10{sup -5} to 4.15*10{sup -5} (mol/m{sup 2}·s) obviously. Similar trend was also found for membrane electrical conductivity. Moreover, the transport number, selectivity and membrane electrical conductivity were enhanced by increase of electrolyte concentration. Prepared membranes exhibited higher transport number/selectivity at pH 7 compared to other pH values. Obtained results showed that the membrane electrical resistance decreased initially by increase of electrolyte pH sharply and then began to increase. Membranes exhibited lower selectivity for bivalent ions compared to monovalent type. Modified membranes containing FeTiO{sub 3}/Fe{sub 3}O{sub 4} nanoparticles showed more appropriate electrochemical properties compared to other prepared membranes.

  17. On RR couplings and bulk singularity structures of non-BPS branes

    Directory of Open Access Journals (Sweden)

    Ehsan Hatefi

    2016-09-01

    Full Text Available We compute the five point world sheet scattering amplitude of a symmetric closed string Ramond–Ramond, a transverse scalar field, a world volume gauge field and a real tachyon in both world volume and transverse directions of brane in type IIA and IIB superstring theory. We provide the complete analysis of S-matrix and show that both u′=u+14 and t channel bulk singularity structures can also be examined by this S-matrix. Various remarks about new restricted Bianchi identities on world volume for the other pictures have also been made.

  18. Generalized Parton Distributions and their Singularities

    Energy Technology Data Exchange (ETDEWEB)

    Anatoly Radyushkin

    2011-04-01

    A new approach to building models of generalized parton distributions (GPDs) is discussed that is based on the factorized DD (double distribution) Ansatz within the single-DD formalism. The latter was not used before, because reconstructing GPDs from the forward limit one should start in this case with a very singular function $f(\\beta)/\\beta$ rather than with the usual parton density $f(\\beta)$. This results in a non-integrable singularity at $\\beta=0$ exaggerated by the fact that $f(\\beta)$'s, on their own, have a singular $\\beta^{-a}$ Regge behavior for small $\\beta$. It is shown that the singularity is regulated within the GPD model of Szczepaniak et al., in which the Regge behavior is implanted through a subtracted dispersion relation for the hadron-parton scattering amplitude. It is demonstrated that using proper softening of the quark-hadron vertices in the regions of large parton virtualities results in model GPDs $H(x,\\xi)$ that are finite and continuous at the "border point'' $x=\\xi$. Using a simple input forward distribution, we illustrate the implementation of the new approach for explicit construction of model GPDs. As a further development, a more general method of regulating the $\\beta=0$ singularities is proposed that is based on the separation of the initial single DD $f(\\beta, \\alpha)$ into the "plus'' part $[f(\\beta,\\alpha)]_{+}$ and the $D$-term. It is demonstrated that the "DD+D'' separation method allows to (re)derive GPD sum rules that relate the difference between the forward distribution $f(x)=H(x,0)$ and the border function $H(x,x)$ with the $D$-term function $D(\\alpha)$.

  19. São Carlos Workshop on Real and Complex Singularities

    CERN Document Server

    Ruas, Maria

    2007-01-01

    The São Carlos Workshop on Real and Complex Singularities is the longest running workshop in singularities. It is held every two years and is a key international event for people working in the field. This volume contains papers presented at the eighth workshop, held at the IML, Marseille, July 19–23, 2004. The workshop offers the opportunity to establish the state of the art and to present new trends, new ideas and new results in all of the branches of singularities. This is reflected by the contributions in this book. The main topics discussed are equisingularity of sets and mappings, geometry of singular complex analytic sets, singularities of mappings, characteristic classes, classification of singularities, interaction of singularity theory with some of the new ideas in algebraic geometry imported from theoretical physics, and applications of singularity theory to geometry of surfaces in low dimensional euclidean spaces, to differential equations and to bifurcation theory.

  20. Human Acellular Dermal Matrix Paired With Silver-zinc Coupled Electroceutical Dressing Results in Rapid Healing of Complicated Diabetic Wounds of Mixed Etiology: A Novel Case Series.

    Science.gov (United States)

    Cole, Windy

    2016-07-01

    Patients with diabetes are well known for having difficult-to-close wounds. When additional factors are added, such as gouty tophi or tumors, the difficulty is compounded and conventional care often fails to heal the wound. In this case series, an innovative wound modality that combined a human acellular dermal matrix with a silver-zinc coupled electroceutical wound dressing was used in 3 particularly difficult and complex cases. In all 3 cases, this alternative treatment provided full healing within 6 weeks in wounds that conventional care had been unable to close in up to 2 years.

  1. Aluminum Matrix Composite (AlSi7Mg2Sr0.03/SiCp) Pistons Obtained by Mechanical Mixing Method

    Science.gov (United States)

    2017-01-01

    Metal matrix composites are undoubtedly a group of advanced engineering materials. Compared to unreinforced matrix material, they are characterized by increased strength, greater stiffness, increased wear resistance, better mechanical properties and dimensional stability at elevated temperatures as well as lower density. Due to its very favorable tribological properties for many years research has been conducted on the application of MMC in friction node. The article presents important technological aspects related to the production and properties of composite pistons. Under industrial conditions, a composite suspension (AlSi7Mg2Sr0.03/SiCp 10 vol %) was prepared to allow casting of the semi-finished pistons series. Machining parameters of the working surfaces of the piston were selected on the basis of the turning test made on PCD, PCNM and uncoated carbide tools. The tribological properties of the composite pistons were determined on the basis of the pin-on-disc and the abrasion wear. The scuffing tests carried out under real operating conditions have confirmed the possibility of using composite pistons in air compressors. PMID:29283419

  2. Stability of naked singularity arising in gravitational collapse of Type ...

    Indian Academy of Sciences (India)

    ... )) leads the collapse to the formation of naked singularity. We further prove that the occurrence of such a naked singularity is stable with respect to small changes in the initial data. We remark that though the initial data leading to both black hole (BH) and naked singularity (NS) form a `big' subset of the true initial data set ...

  3. THE EXT RACORPOREAL FERTILIZATION TECHNOLOGIES AND THE SINGULARITY PROBLEMS

    Directory of Open Access Journals (Sweden)

    S. V. Denysenko

    2013-05-01

    Full Text Available The peculiarities of modern medicine development connected with the technological and informative singularity are analyzed. The risks of realization of extracorporeal fertilization are examined from positions of development of informative singularity. The warning problems of origin of singularity are discussed on t h e base of t h e newest technologies development.

  4. Positive solutions for higher order singular p-Laplacian boundary ...

    Indian Academy of Sciences (India)

    of positive solutions for sublinear 2m-th order singular p-Laplacian BVPs on closed interval. Keywords. Positive solution; singular BVPs; sufficient and necessary conditions; p-Laplacian equations. 1. Introduction. In this paper, we are concerned with higher order singular p-Laplacian boundary value problems. ⎧. ⎨. ⎩.

  5. Pontryagin-Thom-Szucs type construction for non-positive codimensional singular maps with prescribed singular fibers

    OpenAIRE

    Kalmar, Boldizsar

    2006-01-01

    We give a Pontryagin-Thom-Szucs type construction for non-positive codimensional singular maps, and obtain results about cobordism and bordism groups of -1 codimensional stable maps with prescribed singular fibers.

  6. Singular value decomposition metrics show limitations of detector design in diffuse fluorescence tomography.

    Science.gov (United States)

    Leblond, Frederic; Tichauer, Kenneth M; Pogue, Brian W

    2010-11-29

    The spatial resolution and recovered contrast of images reconstructed from diffuse fluorescence tomography data are limited by the high scattering properties of light propagation in biological tissue. As a result, the image reconstruction process can be exceedingly vulnerable to inaccurate prior knowledge of tissue optical properties and stochastic noise. In light of these limitations, the optimal source-detector geometry for a fluorescence tomography system is non-trivial, requiring analytical methods to guide design. Analysis of the singular value decomposition of the matrix to be inverted for image reconstruction is one potential approach, providing key quantitative metrics, such as singular image mode spatial resolution and singular data mode frequency as a function of singular mode. In the present study, these metrics are used to analyze the effects of different sources of noise and model errors as related to image quality in the form of spatial resolution and contrast recovery. The image quality is demonstrated to be inherently noise-limited even when detection geometries were increased in complexity to allow maximal tissue sampling, suggesting that detection noise characteristics outweigh detection geometry for achieving optimal reconstructions.

  7. Singularities of affine fibrations in the regularity theory of Fourier integral operators

    International Nuclear Information System (INIS)

    Ruzhansky, M V

    2000-01-01

    We consider regularity properties of Fourier integral operators in various function spaces. The most interesting case is the L p spaces, for which survey of recent results is given. For example, sharp orders are known for operators satisfying the so-called smooth factorization condition. Here this condition is analyzed in both real and complex settings. In the letter case, conditions for the continuity of Fourier integral operators are related to singularities of affine fibrations in C n (or subsets of C n ) specified by the kernels of Jacobi matrices of holomorphic maps. Singularities of such fibrations are analyzed in this paper in the general case. In particular, it is shown that if the dimension n or the rank of the Jacobi matrix is small, then all singularities of an affine fibration are removable. The fibration associated with a Fourier integral operator is given by the kernels of the Hessian of the phase function of the operator. On the basis of an analysis of singularities for operators commuting with translations we show in a number of cases that the factorization condition is satisfied, which leads to L p estimates for operators. In other cases, examples are given in which the factorization condition fails. The results are applied to deriving L p estimates for solutions of the Cauchy problem for hyperbolic partial differential operators

  8. Matrix theory

    CERN Document Server

    Franklin, Joel N

    2003-01-01

    Mathematically rigorous introduction covers vector and matrix norms, the condition-number of a matrix, positive and irreducible matrices, much more. Only elementary algebra and calculus required. Includes problem-solving exercises. 1968 edition.

  9. Singular electrostatic energy of nanoparticle clusters

    Science.gov (United States)

    Qin, Jian; Krapf, Nathan W.; Witten, Thomas A.

    2016-02-01

    The binding of clusters of metal nanoparticles is partly electrostatic. We address difficulties in calculating the electrostatic energy when high charging energies limit the total charge to a single quantum, entailing unequal potentials on the particles. We show that the energy at small separation h has a singular logarithmic dependence on h . We derive a general form for this energy in terms of the singular capacitance of two spheres in near contact c (h ) , together with nonsingular geometric features of the cluster. Using this form, we determine the energies of various clusters, finding that more compact clusters are more stable. These energies are proposed to be significant for metal-semiconductor binary nanoparticle lattices found experimentally. We sketch how these effects should dictate the relative abundances of metal nanoparticle clusters in nonpolar solvents.

  10. Spectral asymptotics for nonsmooth singular Green operators

    DEFF Research Database (Denmark)

    Grubb, Gerd

    2014-01-01

    Singular Green operators G appear typically as boundary correction terms in resolvents for elliptic boundary value problems on a domain Ω ⊂ ℝ n , and more generally they appear in the calculus of pseudodifferential boundary problems. In particular, the boundary term in a Krein resolvent formula...... is a singular Green operator. It is well-known in smooth cases that when G is of negative order −t on a bounded domain, its eigenvalues ors-numbers have the behavior (*)s j (G) ∼ cj −t/(n−1) for j → ∞, governed by the boundary dimension n − 1. In some nonsmooth cases, upper estimates (**)s j (G) ≤ Cj −t/(n−1...

  11. Further holographic investigations of big bang singularities

    Energy Technology Data Exchange (ETDEWEB)

    Engelhardt, Netta [Department of Physics, UCSB,Santa Barbara, CA 93106 (United States); Hertog, Thomas [Institute for Theoretical Physics, KU Leuven,3001 Leuven (Belgium); Horowitz, Gary T. [Department of Physics, UCSB,Santa Barbara, CA 93106 (United States)

    2015-07-09

    We further explore the quantum dynamics near past cosmological singularities in anisotropic Kasner-AdS solutions using gauge/gravity duality. The dual description of the bulk evolution involves N=4 super Yang-Mills on the contracting branch of an anisotropic de Sitter space and is well defined. We compute two-point correlators of Yang-Mills operators of large dimensions using spacelike geodesics anchored on the boundary. The correlator between two points separated in a direction with negative Kasner exponent p always exhibits a pole at horizon scales, in any dimension, which we interpret as a dual signature of the classical bulk singularity. This indicates that the geodesic approximation selects a non-normalizable Yang-Mills state.

  12. Further holographic investigations of big bang singularities

    Science.gov (United States)

    Engelhardt, Netta; Hertog, Thomas; Horowitz, Gary T.

    2015-07-01

    We further explore the quantum dynamics near past cosmological singularities in anisotropic Kasner-AdS solutions using gauge/gravity duality. The dual description of the bulk evolution involves super Yang-Mills on the contracting branch of an anisotropic de Sitter space and is well defined. We compute two-point correlators of Yang-Mills operators of large dimensions using spacelike geodesics anchored on the boundary. The correlator between two points separated in a direction with negative Kasner exponent p always exhibits a pole at horizon scales, in any dimension, which we interpret as a dual signature of the classical bulk singularity. This indicates that the geodesic approximation selects a non-normalizable Yang-Mills state.

  13. Singular tachyon kinks from regular profiles

    International Nuclear Information System (INIS)

    Copeland, E.J.; Saffin, P.M.; Steer, D.A.

    2003-01-01

    We demonstrate how Sen's singular kink solution of the Born-Infeld tachyon action can be constructed by taking the appropriate limit of initially regular profiles. It is shown that the order in which different limits are taken plays an important role in determining whether or not such a solution is obtained for a wide class of potentials. Indeed, by introducing a small parameter into the action, we are able circumvent the results of a recent paper which derived two conditions on the asymptotic tachyon potential such that the singular kink could be recovered in the large amplitude limit of periodic solutions. We show that this is explained by the non-commuting nature of two limits, and that Sen's solution is recovered if the order of the limits is chosen appropriately

  14. Method of rotations for bilinear singular integrals

    Czech Academy of Sciences Publication Activity Database

    Diestel, G.; Grafakos, L.; Honzík, Petr; Zengyan, S.; Terwilleger, E.

    2011-01-01

    Roč. 3, - (2011), s. 99-107 ISSN 1938-9787. [Analysis, Mathematical Physics and Applications. Ixtapa, 01.03.2010-05.03.2010] R&D Projects: GA AV ČR KJB100190901 Institutional research plan: CEZ:AV0Z10190503 Keywords : bilinear singular integrals * bilinear Hilbert transform * Fourier multipliers Subject RIV: BA - General Mathematics http://projecteuclid.org/DPubS?verb=Display&version=1.0&service=UI&handle=euclid.cma/1298670006&page=record

  15. Non-singular spiked harmonic oscillator

    International Nuclear Information System (INIS)

    Aguilera-Navarro, V.C.; Guardiola, R.

    1990-01-01

    A perturbative study of a class of non-singular spiked harmonic oscillators defined by the hamiltonian H = d sup(2)/dr sup(2) + r sup(2) + λ/r sup(α) in the domain [0,∞] is carried out, in the two extremes of a weak coupling and a strong coupling regimes. A path has been found to connect both expansions for α near 2. (author)

  16. Space-time singularities in Weyl manifolds

    Energy Technology Data Exchange (ETDEWEB)

    Lobo, I.P. [CAPES Foundation, Ministry of Education of Brazil, Brasilia (Brazil); Sapienza Universita di Roma, Dipartimento di Fisica, Rome (Italy); Barreto, A.B.; Romero, C. [Universidade Federal da Paraiba, Departamento de Fisica, C. Postal 5008, Joao Pessoa, PB (Brazil)

    2015-09-15

    We extend one of the Hawking-Penrose singularity theorems in general relativity to the case of some scalar-tensor gravity theories in which the scalar field has a geometrical character and space-time has the mathematical structure of a Weyl integrable space-time. We adopt an invariant formalism, so that the extended version of the theorem does not depend on a particular frame. (orig.)

  17. The technological singularity and exponential medicine

    OpenAIRE

    Iraj Nabipour; Majid Assadi

    2016-01-01

    The "technological singularity" is forecasted to occur in 2045. It is a point when non-biological intelligence becomes more intelligent than humans and each generation of intelligent machines re-designs itself smarter. Beyond this point, there is a symbiosis between machines and humans. This co-existence will produce incredible impacts on medicine that its sparkles could be seen in healthcare industry and the future medicine since 2025. Ray Kurzweil, the great futurist, suggested th...

  18. Singular reduction of Nambu-Poisson manifolds

    Science.gov (United States)

    Das, Apurba

    The version of Marsden-Ratiu Poisson reduction theorem for Nambu-Poisson manifolds by a regular foliation have been studied by Ibáñez et al. In this paper, we show that this reduction procedure can be extended to the singular case. Under a suitable notion of Hamiltonian flow on the reduced space, we show that a set of Hamiltonians on a Nambu-Poisson manifold can also be reduced.

  19. Efficient and Stable CsPbBr3 Quantum-Dot Powders Passivated and Encapsulated with a Mixed Silicon Nitride and Silicon Oxide Inorganic Polymer Matrix.

    Science.gov (United States)

    Yoon, Hee Chang; Lee, Soyoung; Song, Jae Kyu; Yang, Heesun; Do, Young Rag

    2018-04-11

    Despite the excellent optical features of fully inorganic cesium lead halide (CsPbX 3 ) perovskite quantum dots (PeQDs), their unstable nature has limited their use in various optoelectronic devices. To mitigate the instability issues of PeQDs, we demonstrate the roles of dual-silicon nitride and silicon oxide ligands of the polysilazane (PSZ) inorganic polymer to passivate the surface defects and form a barrier layer coated onto green CsPbBr 3 QDs to maintain the high photoluminescence quantum yield (PLQY) and improve the environmental stability. The mixed SiN x /SiN x O y /SiO y passivated and encapsulated CsPbBr 3 /PSZ core/shell composite can be prepared by a simple hydrolysis reaction involving the addition of adding PSZ as a precursor and a slight amount of water into a colloidal CsPbBr 3 QD solution. The degree of the moisture-induced hydrolysis reaction of PSZ can affect the compositional ratio of SiN x , SiN x O y , and SiO y liganded to the surfaces of the CsPbBr 3 QDs to optimize the PLQY and the stability of CsPbBr 3 /PSZ core/shell composite, which shows a high PLQY (∼81.7%) with improved thermal, photo, air, and humidity stability as well under coarse conditions where the performance of CsPbBr 3 QDs typically deteriorate. To evaluate the suitability of the application of the CsPbBr 3 /PSZ powder to down-converted white-light-emitting diodes (DC-WLEDs) as the backlight of a liquid crystal display (LCD), we fabricated an on-package type of tricolor-WLED by mixing the as-synthesized green CsPbBr 3 /PSZ composite powder with red K 2 SiF 6 :Mn 4+ phosphor powder and a poly(methyl methacrylate)-encapsulating binder and coating this mixed paste onto a cup-type blue LED. The fabricated WLED show high luminous efficacy of 138.6 lm/W (EQE = 51.4%) and a wide color gamut of 128% and 111% without and with color filters, respectively, at a correlated color temperature of 6762 K.

  20. A copyright protection scheme for digital images based on shuffled singular value decomposition and visual cryptography.

    Science.gov (United States)

    Devi, B Pushpa; Singh, Kh Manglem; Roy, Sudipta

    2016-01-01

    This paper proposes a new watermarking algorithm based on the shuffled singular value decomposition and the visual cryptography for copyright protection of digital images. It generates the ownership and identification shares of the image based on visual cryptography. It decomposes the image into low and high frequency sub-bands. The low frequency sub-band is further divided into blocks of same size after shuffling it and then the singular value decomposition is applied to each randomly selected block. Shares are generated by comparing one of the elements in the first column of the left orthogonal matrix with its corresponding element in the right orthogonal matrix of the singular value decomposition of the block of the low frequency sub-band. The experimental results show that the proposed scheme clearly verifies the copyright of the digital images, and is robust to withstand several image processing attacks. Comparison with the other related visual cryptography-based algorithms reveals that the proposed method gives better performance. The proposed method is especially resilient against the rotation attack.

  1. Singular inflation from generalized equation of state fluids

    Energy Technology Data Exchange (ETDEWEB)

    Nojiri, S., E-mail: nojiri@gravity.phys.nagoya-u.ac.jp [Department of Physics, Nagoya University, Nagoya 464-8602 (Japan); Kobayashi-Maskawa Institute for the Origin of Particles and the Universe, Nagoya University, Nagoya 464-8602 (Japan); Odintsov, S.D., E-mail: odintsov@ieec.uab.es [Institut de Ciencies de lEspai (IEEC-CSIC), Campus UAB, Carrer de Can Magrans, s/n, 08193 Cerdanyola del Valles, Barcelona (Spain); ICREA, Passeig Lluîs Companys, 23, 08010 Barcelona (Spain); National Research Tomsk State University, 634050 Tomsk (Russian Federation); Tomsk State Pedagogical University, 634061 Tomsk (Russian Federation); Oikonomou, V.K., E-mail: v.k.oikonomou1979@gmail.com [Department of Theoretical Physics, Aristotle University of Thessaloniki, 54124 Thessaloniki (Greece); National Research Tomsk State University, 634050 Tomsk (Russian Federation); Tomsk State Pedagogical University, 634061 Tomsk (Russian Federation)

    2015-07-30

    We study models with a generalized inhomogeneous equation of state fluids, in the context of singular inflation, focusing to so-called Type IV singular evolution. In the simplest case, this cosmological fluid is described by an equation of state with constant w, and therefore a direct modification of this constant w fluid is achieved by using a generalized form of an equation of state. We investigate from which models with generalized phenomenological equation of state, a Type IV singular inflation can be generated and what the phenomenological implications of this singularity would be. We support our results with illustrative examples and we also study the impact of the Type IV singularities on the slow-roll parameters and on the observational inflationary indices, showing the consistency with Planck mission results. The unification of singular inflation with singular dark energy era for specific generalized fluids is also proposed.

  2. Algorithms for large scale singular value analysis of spatially variant tomography systems

    International Nuclear Information System (INIS)

    Cao-Huu, Tuan; Brownell, G.; Lachiver, G.

    1996-01-01

    The problem of determining the eigenvalues of large matrices occurs often in the design and analysis of modem tomography systems. As there is an interest in solving systems containing an ever-increasing number of variables, current research effort is being made to create more robust solvers which do not depend on some special feature of the matrix for convergence (e.g. block circulant), and to improve the speed of already known and understood solvers so that solving even larger systems in a reasonable time becomes viable. Our standard techniques for singular value analysis are based on sparse matrix factorization and are not applicable when the input matrices are large because the algorithms cause too much fill. Fill refers to the increase of non-zero elements in the LU decomposition of the original matrix A (the system matrix). So we have developed iterative solutions that are based on sparse direct methods. Data motion and preconditioning techniques are critical for performance. This conference paper describes our algorithmic approaches for large scale singular value analysis of spatially variant imaging systems, and in particular of PCR2, a cylindrical three-dimensional PET imager 2 built at the Massachusetts General Hospital (MGH) in Boston. We recommend the desirable features and challenges for the next generation of parallel machines for optimal performance of our solver

  3. CO{sub 2}/CH{sub 4} separation with poly(4-methyl-1-pentyne) (TPX) based mixed matrix membrane filled with Al{sub 2}O{sub 3} nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Nematollahi, Mohammad Hadi [Islamic Azad University, Shahreza (Iran, Islamic Republic of); Dehaghani, Amir Hossein Saeedi [Tarbiat Modares University, Tehran (Iran, Islamic Republic of); Abedini, Reza [Babol Noshirvani University of Technology, Babol (Iran, Islamic Republic of)

    2016-02-15

    The effect of alumina (Al{sub 2}O{sub 3}) nano-particles on gas separation properties of poly(4-methyl-1-pentyne) known as TPX was evaluated. Mixed matrix membranes (MMMs) were prepared with various weight percent (5, 10, 15, 20 and 30) of alumina nano-particles through solution casting along with solvent evaporation method. TPX and consequent MMMs were characterized using FT-IR, SEM and TGA methods. The MMMs permselectivities were determined through pure CO{sub 2} and CH{sub 4} permeation measurement and CO{sub 2}/CH{sub 4} selectivity calculation. SEM images demonstrated the proper dispersion of alumina nano-particles in TPX matrix. Results from gas permeation showed that the permeability of both CO{sub 2} and CH{sub 4} as well as CO{sub 2}/CH{sub 4} selectivities were increased with increasing alumina content. Significant increase of CO{sub 2} permeability (from 157.43 Barrer at 8 bar and no loading of Al{sub 2}O{sub 3} to 527.78 Barrer at 8 bar and 30 wt% loading of Al{sub 2}O{sub 3}) and conspicuous enhancement of selectivity, from 7.73 to 12.51, were obtained in TPX MMMs.

  4. Architecture of chaotic attractors for flows in the absence of any singular point

    Energy Technology Data Exchange (ETDEWEB)

    Letellier, Christophe [CORIA-UMR 6614 Normandie Université, CNRS-Université et INSA de Rouen, Campus Universitaire du Madrillet, F-76800 Saint-Etienne du Rouvray (France); Malasoma, Jean-Marc [Université de Lyon, ENTPE, Laboratoire Génie Civil et Bâtiment, 3 Rue Maurice Audin, F-69518 Vaulx-en-Velin Cedex (France)

    2016-06-15

    Some chaotic attractors produced by three-dimensional dynamical systems without any singular point have now been identified, but explaining how they are structured in the state space remains an open question. We here want to explain—in the particular case of the Wei system—such a structure, using one-dimensional sets obtained by vanishing two of the three derivatives of the flow. The neighborhoods of these sets are made of points which are characterized by the eigenvalues of a 2 × 2 matrix describing the stability of flow in a subspace transverse to it. We will show that the attractor is spiralling and twisted in the neighborhood of one-dimensional sets where points are characterized by a pair of complex conjugated eigenvalues. We then show that such one-dimensional sets are also useful in explaining the structure of attractors produced by systems with singular points, by considering the case of the Lorenz system.

  5. Fuzzy Stochastic Optimal Guaranteed Cost Control of Bio-Economic Singular Markovian Jump Systems.

    Science.gov (United States)

    Li, Li; Zhang, Qingling; Zhu, Baoyan

    2015-11-01

    This paper establishes a bio-economic singular Markovian jump model by considering the price of the commodity as a Markov chain. The controller is designed for this system such that its biomass achieves the specified range with the least cost in a finite-time. Firstly, this system is described by Takagi-Sugeno fuzzy model. Secondly, a new design method of fuzzy state-feedback controllers is presented to ensure not only the regularity, nonimpulse, and stochastic singular finite-time boundedness of this kind of systems, but also an upper bound achieved for the cost function in the form of strict linear matrix inequalities. Finally, two examples including a practical example of eel seedling breeding are given to illustrate the merit and usability of the approach proposed in this paper.

  6. Nonlinear singularly perturbed optimal control problems with singular arcs. [flight mechanics application

    Science.gov (United States)

    Ardema, M. D.

    1979-01-01

    Singular perturbation techniques are studied for dealing with singular arc problems by analyzing a relatively low-order but otherwise general system. This system encompasses many flight mechanic problems including Goddard's problem and a version of the minimum time-to-climb problem. Boundary layer solutions are constructed which are stable and reach the outer solution in a finite time. A uniformly valid composite solution is then formed from the reduced and boundary layer solutions. The value of the approximate solution is that it is relatively easy to obtain and does not involve singular arcs. To illustrate the utility of the results, the technique is used to obtain an approximate solution of a simplified version of the aircraft minimum time-to-climb problem.

  7. Robust Guaranteed Cost Observer Design for Singular Markovian Jump Time-Delay Systems with Generally Incomplete Transition Probability

    Directory of Open Access Journals (Sweden)

    Yanbo Li

    2014-01-01

    Full Text Available This paper is devoted to the investigation of the design of robust guaranteed cost observer for a class of linear singular Markovian jump time-delay systems with generally incomplete transition probability. In this singular model, each transition rate can be completely unknown or only its estimate value is known. Based on stability theory of stochastic differential equations and linear matrix inequality (LMI technique, we design an observer to ensure that, for all uncertainties, the resulting augmented system is regular, impulse free, and robust stochastically stable with the proposed guaranteed cost performance. Finally, a convex optimization problem with LMI constraints is formulated to design the suboptimal guaranteed cost filters for linear singular Markovian jump time-delay systems with generally incomplete transition probability.

  8. Big bang and big crunch in matrix string theory

    International Nuclear Information System (INIS)

    Bedford, J.; Ward, J.; Papageorgakis, C.; Rodriguez-Gomez, D.

    2007-01-01

    Following the holographic description of linear dilaton null cosmologies with a big bang in terms of matrix string theory put forward by Craps, Sethi, and Verlinde, we propose an extended background describing a universe including both big bang and big crunch singularities. This belongs to a class of exact string backgrounds and is perturbative in the string coupling far away from the singularities, both of which can be resolved using matrix string theory. We provide a simple theory capable of describing the complete evolution of this closed universe

  9. On low-rank updates to the singular value and Tucker decompositions

    Energy Technology Data Exchange (ETDEWEB)

    O' Hara, M J

    2009-10-06

    The singular value decomposition is widely used in signal processing and data mining. Since the data often arrives in a stream, the problem of updating matrix decompositions under low-rank modification has been widely studied. Brand developed a technique in 2006 that has many advantages. However, the technique does not directly approximate the updated matrix, but rather its previous low-rank approximation added to the new update, which needs justification. Further, the technique is still too slow for large information processing problems. We show that the technique minimizes the change in error per update, so if the error is small initially it remains small. We show that an updating algorithm for large sparse matrices should be sub-linear in the matrix dimension in order to be practical for large problems, and demonstrate a simple modification to the original technique that meets the requirements.

  10. The Singularity May Never Be Near

    OpenAIRE

    Walsh, Toby

    2017-01-01

    There is both much optimisim and pessimism around artificial intelligence (AI) today. The optimists are investing millions of dollars, and even in some cases billions of dollars into AI. The pessimists, on the other hand, predict that AI will end many things: jobs, warfare, and even the human race. Both the optimists and the pessimists often appeal to the idea of a technological singularity, a point in time where machine intelligence starts to run away, and a new, more in- telligent “species”...

  11. Singularity Structure of Maximally Supersymmetric Scattering Amplitudes

    DEFF Research Database (Denmark)

    Arkani-Hamed, Nima; Bourjaily, Jacob L.; Cachazo, Freddy

    2014-01-01

    We present evidence that loop amplitudes in maximally supersymmetric (N=4) Yang-Mills theory (SYM) beyond the planar limit share some of the remarkable structures of the planar theory. In particular, we show that through two loops, the four-particle amplitude in full N=4 SYM has only logarithmic ...... singularities and is free of any poles at infinity—properties closely related to uniform transcendentality and the UV finiteness of the theory. We also briefly comment on implications for maximal (N=8) supergravity theory (SUGRA)....

  12. Clifford wavelets, singular integrals, and Hardy spaces

    CERN Document Server

    Mitrea, Marius

    1994-01-01

    The book discusses the extensions of basic Fourier Analysis techniques to the Clifford algebra framework. Topics covered: construction of Clifford-valued wavelets, Calderon-Zygmund theory for Clifford valued singular integral operators on Lipschitz hyper-surfaces, Hardy spaces of Clifford monogenic functions on Lipschitz domains. Results are applied to potential theory and elliptic boundary value problems on non-smooth domains. The book is self-contained to a large extent and well-suited for graduate students and researchers in the areas of wavelet theory, Harmonic and Clifford Analysis. It will also interest the specialists concerned with the applications of the Clifford algebra machinery to Mathematical Physics.

  13. Noncommutative spaces from matrix models

    Science.gov (United States)

    Lu, Lei

    Noncommutative (NC) spaces commonly arise as solutions to matrix model equations of motion. They are natural generalizations of the ordinary commutative spacetime. Such spaces may provide insights into physics close to the Planck scale, where quantum gravity becomes relevant. Although there has been much research in the literature, aspects of these NC spaces need further investigation. In this dissertation, we focus on properties of NC spaces in several different contexts. In particular, we study exact NC spaces which result from solutions to matrix model equations of motion. These spaces are associated with finite-dimensional Lie-algebras. More specifically, they are two-dimensional fuzzy spaces that arise from a three-dimensional Yang-Mills type matrix model, four-dimensional tensor-product fuzzy spaces from a tensorial matrix model, and Snyder algebra from a five-dimensional tensorial matrix model. In the first part of this dissertation, we study two-dimensional NC solutions to matrix equations of motion of extended IKKT-type matrix models in three-space-time dimensions. Perturbations around the NC solutions lead to NC field theories living on a two-dimensional space-time. The commutative limit of the solutions are smooth manifolds which can be associated with closed, open and static two-dimensional cosmologies. One particular solution is a Lorentzian fuzzy sphere, which leads to essentially a fuzzy sphere in the Minkowski space-time. In the commutative limit, this solution leads to an induced metric that does not have a fixed signature, and have a non-constant negative scalar curvature, along with singularities at two fixed latitudes. The singularities are absent in the matrix solution which provides a toy model for resolving the singularities of General relativity. We also discussed the two-dimensional fuzzy de Sitter space-time, which has irreducible representations of su(1,1) Lie-algebra in terms of principal, complementary and discrete series. Field

  14. Beyond the singularity of the 2-D charged black hole

    International Nuclear Information System (INIS)

    Giveon, Amit; Rabinovici, Eliezer; Sever, Amit

    2003-01-01

    Two dimensional charged black holes in string theory can be obtained as exact SL(2,R) x U(1)/U(1) quotient CFTs. The geometry of the quotient is induced from that of the group, and in particular includes regions beyond the black hole singularities. Moreover, wavefunctions in such black holes are obtained from gauge invariant vertex operators in the SL(2,R) CFT, hence their behavior beyond the singularity is determined. When the black hole is charged we find that the wavefunctions are smooth at the singularities. Unlike the uncharged case, scattering waves prepared beyond the singularity are not fully reflected; part of the wave is transmitted through the singularity. Hence, the physics outside the horizon of a charged black hole is sensitive to conditions set behind the past singularity. (author)

  15. Pursell-Shanks type theorems for fewnomial singularities

    International Nuclear Information System (INIS)

    Khimshiashvili, G.

    2006-04-01

    We discuss certain situations in which the analytic isomorphism class of an isolated hypersurface singularity is determined by the Lie algebra of derivations of its moduli algebra. Our main attention is given to singularities defined by polynomials with the number of monomials equal to the number of variables. In this context, we indicate several classes of singularities which are classified by the associated Lie algebras. In particular, it is shown that this takes place for isolated singularities defined by binomials in two variables with the Milnor number not less than 7, which implies that simple singularities with Milnor number not less than 7 can be classified by the associated Lie algebras. Similar results are obtained for several other classes of isolated hypersurfaces singularities. A number of related results and open problems are also presented. (author)

  16. Identify Foot of Continental Slope by singular spectrum and fractal singularity analysis

    Science.gov (United States)

    Li, Q.; Dehler, S.

    2012-04-01

    Identifying the Foot of Continental Slope (FOCS) plays a critical role in the determination of exclusive economic zone (EEZ) for coastal nations. The FOCS is defined by the Law of the Sea as the point of maximum change of the slope and it is mathematically equivalent to the point which has the maximum curvature value in its vicinity. However, curvature is the second derivative and the calculation of second derivative is a high pass and noise-prone filtering procedure. Therefore, identification of FOCS with curvature analysis methods is often uncertain and erroneous because observed bathymetry profiles or interpolated raster maps commonly include high frequency noises and artifacts, observation errors, and local sharp changes. Effective low-pass filtering methods and robust FOCS indicator algorithms are highly desirable. In this approach, nonlinear singular spectral filtering and singularity FOCS-indicator methods and software tools are developed to address this requirement. The normally used Fourier domain filtering methods decompose signals into Fourier space, composed of a fixed base that depends only on the acquisition interval of the signal; the signal is required to be stationary or at least weak stationary. In contrast to that requirement, the developed singular spectral filtering method constructs orthogonal basis functions dynamically according to different signals, and it does not require the signal to be stationary or weak stationary. Furthermore, singular spectrum analysis (SSA) can assist in designing suitable filters to carefully remove high-frequency local or noise components while reserving useful global and local components according to energy distribution. Geoscientific signals, including morphological ocean bathymetry data, often demonstrate fractal or multifractal properties. With proper definition of scales in the vicinity of a certain point and related measures, it is found that 1-dimensional bathymetry profiles and 2-dimensional raster maps

  17. Mega-History and the 21st century singularity puzzle

    Directory of Open Access Journals (Sweden)

    Akop P. Nazaretyan

    2015-06-01

    Full Text Available A series of calculations carried out independently by the Australian, Russian and American re- searchers have demonstrated that a crucial global polyfurcation is expected near the middle of the 21st century. This result is drawn by extrapolating into the future the logarithmic acceleration law, which involves the phase transitions in the evolution of biosphere and anthroposphere. The paper investigates the palliatives of the planetary civilization beyond the big evolutionary Singularity in the context of Mega-history and complexity theory worldviews. It gives the mathematical deduction a universal ground and besides, helps involve some recent discoveries in psychology and cultural anthropology to tracing the forecasting attractors and scenarios. The destiny of the Earth (as well as any other planetary civilization may conclusively depend on whether or not the intellectual ac- tor succeeds in developing his inner regulation to balance the potentially unlimited developments in technological power. Particularly, this includes overcoming the macro-group identities, religious and quasi-religious ideologies, which always suggest a friend-or-foe discrimination matrix.

  18. Robust regularized singular value decomposition with application to mortality data

    KAUST Repository

    Zhang, Lingsong

    2013-09-01

    We develop a robust regularized singular value decomposition (RobRSVD) method for analyzing two-way functional data. The research is motivated by the application of modeling human mortality as a smooth two-way function of age group and year. The RobRSVD is formulated as a penalized loss minimization problem where a robust loss function is used to measure the reconstruction error of a low-rank matrix approximation of the data, and an appropriately defined two-way roughness penalty function is used to ensure smoothness along each of the two functional domains. By viewing the minimization problem as two conditional regularized robust regressions, we develop a fast iterative reweighted least squares algorithm to implement the method. Our implementation naturally incorporates missing values. Furthermore, our formulation allows rigorous derivation of leaveone- row/column-out cross-validation and generalized cross-validation criteria, which enable computationally efficient data-driven penalty parameter selection. The advantages of the new robust method over nonrobust ones are shown via extensive simulation studies and the mortality rate application. © Institute of Mathematical Statistics, 2013.

  19. INTERVAL STATE ESTIMATION FOR SINGULAR DIFFERENTIAL EQUATION SYSTEMS WITH DELAYS

    Directory of Open Access Journals (Sweden)

    T. A. Kharkovskaia

    2016-07-01

    Full Text Available The paper deals with linear differential equation systems with algebraic restrictions (singular systems and a method of interval observer design for this kind of systems. The systems contain constant time delay, measurement noise and disturbances. Interval observer synthesis is based on monotone and cooperative systems technique, linear matrix inequations, Lyapunov function theory and interval arithmetic. The set of conditions that gives the possibility for interval observer synthesis is proposed. Results of synthesized observer operation are shown on the example of dynamical interindustry balance model. The advantages of proposed method are that it is adapted to observer design for uncertain systems, if the intervals of admissible values for uncertain parameters are given. The designed observer is capable to provide asymptotically definite limits on the estimation accuracy, since the interval of admissible values for the object state is defined at every instant. The obtained result provides an opportunity to develop the interval estimation theory for complex systems that contain parametric uncertainty, varying delay and nonlinear elements. Interval observers increasingly find applications in economics, electrical engineering, mechanical systems with constraints and optimal flow control.

  20. Quantum singularities in the FRW universe revisited

    International Nuclear Information System (INIS)

    Letelier, Patricio S.; Pitelli, Joao Paulo M.

    2010-01-01

    The components of the Riemann tensor in the tetrad basis are quantized and, through the Einstein equation, we find the local expectation value in the ontological interpretation of quantum mechanics of the energy density and pressure of a perfect fluid with equation of state p=(1/3)ρ in the flat Friedmann-Robertson-Walker quantum cosmological model. The quantum behavior of the equation of state and energy conditions are then studied, and it is shown that the energy conditions are violated since the singularity is removed with the introduction of quantum cosmology, but in the classical limit both the equation of state and the energy conditions behave as in the classical model. We also calculate the expectation value of the scale factor for several wave packets in the many-worlds interpretation in order to show the independence of the nonsingular character of the quantum cosmological model with respect to the wave packet representing the wave function of the Universe. It is also shown that, with the introduction of nonnormalizable wave packets, solutions of the Wheeler-DeWitt equation, the singular character of the scale factor, can be recovered in the ontological interpretation.

  1. Electricity consumption forecasting using singular spectrum analysis

    Directory of Open Access Journals (Sweden)

    Moisés Lima de Menezes

    2015-01-01

    Full Text Available El Análisis Espectral Singular (AES es una técnica no paramétrica que permite la descomposición de una serie de tiempo en una componente de señal y otra de ruido. De este modo, AES es una técnica útil para la extracción de la tendencia, la suavización y el filtro una serie de tiempo. En este artículo se investiga el efecto sobre el desempeño los modelos de Holt-Winters y de Box & Jenkins al ser aplicados a una serie de tiempo filtrada por AES. Tres diferentes metodologías son evaluadas con el enfoque de AES: Análisis de Componentes Principales (ACP, análisis de conglomerados y análisis gráfico de vectores singulares. Con el fin de ilustrar y comparar dichas metodologías, en este trabajo también se presentaron los principales resultados de un experimento computacional para el consumo residencial mensual de electricidad en Brasil.

  2. On Absence of Pure Singular Spectrum of Random Perturbations and in Anderson Model at Low Disorde

    CERN Document Server

    Grinshpun, V

    2006-01-01

    Absence of singular component, with probability one, in the conductivity spectra of bounded random perturbations of multidimensional finite-difference Hamiltonians, is for the first time rigorously established under certain conditions ensuring either absence of pure point, or absence of pure absolutely continuous component in the corresponding regions of spectra. The main technical tool applied is the theory of rank-one perturbations of singular spectra. The respective new result (the non-mixing property) is applied to establish existence and bounds of the (non-empty) pure absolutely continuous component in the spectrum of the Anderson model with bounded random potential in dimension 2 at low disorder. The new (1999) result implies, via the trace-class perturbation analysis, the Anderson model with the unbounded potential to have only pure point spectrum (complete system of localized wave-functions) with probability one in arbitrary dimension. The new technics, based on the resolvent reduction formula, and ex...

  3. A complete metric in the set of mixing transformations

    International Nuclear Information System (INIS)

    Tikhonov, Sergei V

    2007-01-01

    A metric in the set of mixing measure-preserving transformations is introduced making of it a complete separable metric space. Dense and massive subsets of this space are investigated. A generic mixing transformation is proved to have simple singular spectrum and to be a mixing of arbitrary order; all its powers are disjoint. The convolution powers of the maximal spectral type for such transformations are mutually singular if the ratio of the corresponding exponents is greater than 2. It is shown that the conjugates of a generic mixing transformation are dense, as are also the conjugates of an arbitrary fixed Cartesian product. Bibliography: 28 titles.

  4. Identification of discrete chaotic maps with singular points

    Directory of Open Access Journals (Sweden)

    P. G. Akishin

    2001-01-01

    Full Text Available We investigate the ability of artificial neural networks to reconstruct discrete chaotic maps with singular points. We use as a simple test model the Cusp map. We compare the traditional Multilayer Perceptron, the Chebyshev Neural Network and the Wavelet Neural Network. The numerical scheme for the accurate determination of a singular point is also developed. We show that combining a neural network with the numerical algorithm for the determination of the singular point we are able to accurately approximate discrete chaotic maps with singularities.

  5. Metric dimensional reduction at singularities with implications to Quantum Gravity

    Science.gov (United States)

    Stoica, Ovidiu Cristinel

    2014-08-01

    A series of old and recent theoretical observations suggests that the quantization of gravity would be feasible, and some problems of Quantum Field Theory would go away if, somehow, the spacetime would undergo a dimensional reduction at high energy scales. But an identification of the deep mechanism causing this dimensional reduction would still be desirable. The main contribution of this article is to show that dimensional reduction effects are due to General Relativity at singularities, and do not need to be postulated ad-hoc. Recent advances in understanding the geometry of singularities do not require modification of General Relativity, being just non-singular extensions of its mathematics to the limit cases. They turn out to work fine for some known types of cosmological singularities (black holes and FLRW Big-Bang), allowing a choice of the fundamental geometric invariants and physical quantities which remain regular. The resulting equations are equivalent to the standard ones outside the singularities. One consequence of this mathematical approach to the singularities in General Relativity is a special, (geo)metric type of dimensional reduction: at singularities, the metric tensor becomes degenerate in certain spacetime directions, and some properties of the fields become independent of those directions. Effectively, it is like one or more dimensions of spacetime just vanish at singularities. This suggests that it is worth exploring the possibility that the geometry of singularities leads naturally to the spontaneous dimensional reduction needed by Quantum Gravity.

  6. Numerical investigation of stress singularities in cracked bimaterial body

    Czech Academy of Sciences Publication Activity Database

    Náhlík, Luboš; Šestáková, Lucie; Hutař, Pavel

    2008-01-01

    Roč. 385-387, - (2008), s. 125-128 ISSN 1013-9826. [International Conference on Fracture and Damage Mechanics /7./. Seoul, 09.09.2008-11.09.2008] R&D Projects: GA AV ČR(CZ) KJB200410803; GA ČR GP106/06/P239; GA ČR GA106/08/1409 Institutional research plan: CEZ:AV0Z20410507 Keywords : bimaterial interface * stress singularity exponent * corner singularity * vertex singularity * general singular stress concentrator Subject RIV: JL - Materials Fatigue, Friction Mechanics

  7. Can non-commutativity resolve the big-bang singularity?

    Energy Technology Data Exchange (ETDEWEB)

    Maceda, M.; Madore, J. [Laboratoire de Physique Theorique, Universite de Paris-Sud, Batiment 211, 91405, Orsay (France); Manousselis, P. [Department of Engineering Sciences, University of Patras, 26110, Patras (Greece); Physics Department, National Technical University, Zografou Campus, 157 80, Zografou, Athens (Greece); Zoupanos, G. [Physics Department, National Technical University, Zografou Campus, 157 80, Zografou, Athens (Greece); Theory Division, CERN, 1211, Geneva 23 (Switzerland)

    2004-08-01

    A possible way to resolve the singularities of general relativity is proposed based on the assumption that the description of space-time using commuting coordinates is not valid above a certain fundamental scale. Beyond that scale it is assumed that the space-time has non-commutative structure leading in turn to a resolution of the singularity. As a first attempt towards realizing the above programme a modification of the Kasner metric is constructed which is commutative only at large time scales. At small time scales, near the singularity, the commutation relations among the space coordinates diverge. We interpret this result as meaning that the singularity has been completely delocalized. (orig.)

  8. Paths correlation matrix.

    Science.gov (United States)

    Qian, Weixian; Zhou, Xiaojun; Lu, Yingcheng; Xu, Jiang

    2015-09-15

    Both the Jones and Mueller matrices encounter difficulties when physically modeling mixed materials or rough surfaces due to the complexity of light-matter interactions. To address these issues, we derived a matrix called the paths correlation matrix (PCM), which is a probabilistic mixture of Jones matrices of every light propagation path. Because PCM is related to actual light propagation paths, it is well suited for physical modeling. Experiments were performed, and the reflection PCM of a mixture of polypropylene and graphite was measured. The PCM of the mixed sample was accurately decomposed into pure polypropylene's single reflection, pure graphite's single reflection, and depolarization caused by multiple reflections, which is consistent with the theoretical derivation. Reflection parameters of rough surface can be calculated from PCM decomposition, and the results fit well with the theoretical calculations provided by the Fresnel equations. These theoretical and experimental analyses verify that PCM is an efficient way to physically model light-matter interactions.

  9. Handling The Singularities of The Perturbed Kratzer and Inverted Kratzer Potentials

    International Nuclear Information System (INIS)

    Nasser, I.; Abdelmonem, M.S.; Abdel-Hady, A.

    2011-01-01

    The singularities in the Kratzer and inverted Kratzer potentials have been absorbed in the reference Hamiltonian. With the help of the Laguerre basis, the full Hamiltonian becomes tridiagonal. The bound state energies are calculated by diagonalizing the full Hamiltonian matrix. However, the resonance state energies are calculated using the complex rotation method. Our results were found to be in excellent agreement with the exact analytic expressions for these potentials. In addition, we considered adding a squelched harmonic oscillator (SQHO) potential to the Kratzer potential and new results of bound state energies are reported here for the first time

  10. Using many pilot points and singular value decomposition in groundwater model calibration

    DEFF Research Database (Denmark)

    Christensen, Steen; Doherty, John

    2008-01-01

    over the model area. Singular value decomposition (SVD) of the normal matrix is used to reduce the large number of pilot point parameters to a smaller number of so-called super parameters that can be estimated by nonlinear regression from the available observations. A number of eigenvectors...... corresponding to significant Eigen values (resulting from the decomposition) is used to transform the model from having many pilot point parameters to having a few super parameters. A synthetic case model is used to analyze and demonstrate the application of the presented method of model parameterization...

  11. Point force singularities outside a drop covered with an incompressible surfactant: Image systems and their applications

    Science.gov (United States)

    Shaik, Vaseem A.; Ardekani, Arezoo M.

    2017-11-01

    In this work we derive the image flow fields for point force singularities placed outside a stationary drop covered with an insoluble, nondiffusing, and incompressible surfactant. We assume the interface to be Newtonian and use the Boussinesq-Scriven constitutive law for the interfacial stress tensor. We use this analytical solution to investigate two different problems. First, we derive the mobility matrix for two drops of arbitrary sizes covered with an incompressible surfactant. In the second example, we calculate the velocity of a swimming microorganism (modeled as a Stokes dipole) outside a drop covered with an incompressible surfactant.

  12. Mechanical quadrature method as applied to singular integral equations with logarithmic singularity on the right-hand side

    Science.gov (United States)

    Amirjanyan, A. A.; Sahakyan, A. V.

    2017-08-01

    A singular integral equation with a Cauchy kernel and a logarithmic singularity on its righthand side is considered on a finite interval. An algorithm is proposed for the numerical solution of this equation. The contact elasticity problem of a П-shaped rigid punch indented into a half-plane is solved in the case of a uniform hydrostatic pressure occurring under the punch, which leads to a logarithmic singularity at an endpoint of the integration interval. The numerical solution of this problem shows the efficiency of the proposed approach and suggests that the singularity has to be taken into account in solving the equation.

  13. Fast matrix factorization algorithm for DOSY based on the eigenvalue decomposition and the difference approximation focusing on the size of observed matrix

    International Nuclear Information System (INIS)

    Tanaka, Yuho; Uruma, Kazunori; Furukawa, Toshihiro; Nakao, Tomoki; Izumi, Kenya; Utsumi, Hiroaki

    2017-01-01

    This paper deals with an analysis problem for diffusion-ordered NMR spectroscopy (DOSY). DOSY is formulated as a matrix factorization problem of a given observed matrix. In order to solve this problem, a direct exponential curve resolution algorithm (DECRA) is well known. DECRA is based on singular value decomposition; the advantage of this algorithm is that the initial value is not required. However, DECRA requires a long calculating time, depending on the size of the given observed matrix due to the singular value decomposition, and this is a serious problem in practical use. Thus, this paper proposes a new analysis algorithm for DOSY to achieve a short calculating time. In order to solve matrix factorization for DOSY without using singular value decomposition, this paper focuses on the size of the given observed matrix. The observed matrix in DOSY is also a rectangular matrix with more columns than rows, due to limitation of the measuring time; thus, the proposed algorithm transforms the given observed matrix into a small observed matrix. The proposed algorithm applies the eigenvalue decomposition and the difference approximation to the small observed matrix, and the matrix factorization problem for DOSY is solved. The simulation and a data analysis show that the proposed algorithm achieves a lower calculating time than DECRA as well as similar analysis result results to DECRA. (author)

  14. Matrix calculus

    CERN Document Server

    Bodewig, E

    1959-01-01

    Matrix Calculus, Second Revised and Enlarged Edition focuses on systematic calculation with the building blocks of a matrix and rows and columns, shunning the use of individual elements. The publication first offers information on vectors, matrices, further applications, measures of the magnitude of a matrix, and forms. The text then examines eigenvalues and exact solutions, including the characteristic equation, eigenrows, extremum properties of the eigenvalues, bounds for the eigenvalues, elementary divisors, and bounds for the determinant. The text ponders on approximate solutions, as well

  15. A vida singular de um jovem militante

    Directory of Open Access Journals (Sweden)

    Áurea Maria Guimarães

    2012-01-01

    Full Text Available Esse artigo é fruto de uma pesquisa realizada no período de 2007 a 2010, junto a jovens militantes da cidade de Campinas, com o objetivo de compreender as diferentes maneiras que conduziam esses jovens tanto a reproduzir um modelo de vida quanto a criar outras possibilidades de militância na relação com esse modelo. Entre as histórias orais de vida narradas por jovens que militavam em diferentes grupos ou instituições, escolhi a vida de Biula, representante do movimento estudantil secundarista, procurando evidenciar que a singularidade desta vida, como também e a de outros jovens, estava conectada à problematização que faziam no interior de certas práticas, histórica e culturalmente constituídas, possibilitando a criação de novas formas de subjetivação nas quais se modificava a experiência que tinham deles mesmos na relação com os seus heróis ou modelos de referência. Palavras-chave: história oral – transcriação – heróis – resistência - processos de singularização.   THE SINGULAR LIFE OF A YOUNG MILITANT ABSTRACT   This article is the result of a research carried out from 2007 to 2010 with   young militants in the city of Campinas, aiming to understand the different ways which conducted these youngsters to both reproduce a life model and create other possibilities of militancy in the relationship with this model. Among oral stories narrated by young militants from different groups or institutions, I have chosen the life of Biula, a representative of the secondary students’ movement, trying to show that the singularity of this life and other youngsters’ lives was connected to the problematization they promoted within certain practices, historically and culturally built, thus enabling the creation of new subjectification modes in which the experience they had of themselves in the relationship with their heroes or reference models has changed. Key words: oral history -  transcreation – heroes

  16. Localizing heart sounds in respiratory signals using singular spectrum analysis.

    Science.gov (United States)

    Ghaderi, Foad; Mohseni, Hamid R; Sanei, Saeid

    2011-12-01

    Respiratory sounds are always contaminated by heart sound interference. An essential preprocessing step in some of the heart sound cancellation methods is localizing primary heart sound components. Singular spectrum analysis (SSA), a powerful time series analysis technique, is used in this paper. Despite the frequency overlap of the heart and lung sound components, two different trends in the eigenvalue spectra are recognizable, which leads to find a subspace that contains more information about the underlying heart sound. Artificially mixed and real respiratory signals are used for evaluating the performance of the method. Selecting the appropriate length for the SSA window results in good decomposition quality and low computational cost for the algorithm. The results of the proposed method are compared with those of well-established methods, which use the wavelet transform and entropy of the signal to detect the heart sound components. The proposed method outperforms the wavelet-based method in terms of false detection and also correlation with the underlying heart sounds. Performance of the proposed method is slightly better than that of the entropy-based method. Moreover, the execution time of the former is significantly lower than that of the latter.

  17. Matrix superpotentials

    Science.gov (United States)

    Nikitin, Anatoly G.; Karadzhov, Yuri

    2011-07-01

    We present a collection of matrix-valued shape invariant potentials which give rise to new exactly solvable problems of SUSY quantum mechanics. It includes all irreducible matrix superpotentials of the generic form W=kQ+\\frac{1}{k} R+P, where k is a variable parameter, Q is the unit matrix multiplied by a real-valued function of independent variable x, and P and R are the Hermitian matrices depending on x. In particular, we recover the Pron'ko-Stroganov 'matrix Coulomb potential' and all known scalar shape invariant potentials of SUSY quantum mechanics. In addition, five new shape invariant potentials are presented. Three of them admit a dual shape invariance, i.e. the related Hamiltonians can be factorized using two non-equivalent superpotentials. We find discrete spectrum and eigenvectors for the corresponding Schrödinger equations and prove that these eigenvectors are normalizable.

  18. Singular Instantons and Painlevé VI

    Science.gov (United States)

    Muñiz Manasliski, Richard

    2016-06-01

    We consider a two parameter family of instantons, which is studied in [Sadun L., Comm. Math. Phys. 163 (1994), 257-291], invariant under the irreducible action of SU_2 on S^4, but which are not globally defined. We will see that these instantons produce solutions to a one parameter family of Painlevé VI equations (P_VI}) and we will give an explicit expression of the map between instantons and solutions to P_{VI}. The solutions are algebraic only for that values of the parameters which correspond to the instantons that can be extended to all of S^4. This work is a generalization of [Muñiz Manasliski R., Contemp. Math., Vol. 434, Amer. Math. Soc., Providence, RI, 2007, 215-222] and [Muñiz Manasliski R., J. Geom. Phys. 59 (2009), 1036-1047, arXiv:1602.07221], where instantons without singularities are studied.

  19. Generalized decomposition methods for singular oscillators

    International Nuclear Information System (INIS)

    Ramos, J.I.

    2009-01-01

    Generalized decomposition methods based on a Volterra integral equation, the introduction of an ordering parameter and a power series expansion of the solution in terms of the ordering parameter are developed and used to determine the solution and the frequency of oscillation of a singular, nonlinear oscillator with an odd nonlinearity. It is shown that these techniques provide solutions which are free from secularities if the unknown frequency of oscillation is also expanded in power series of the ordering parameter, require that the nonlinearities be analytic functions of their arguments, and, at leading-order, provide the same frequency of oscillation as two-level iterative techniques, the homotopy perturbation method if the constants that appear in the governing equation are expanded in power series of the ordering parameter, and modified artificial parameter - Linstedt-Poincare procedures.

  20. The technological singularity and exponential medicine

    Directory of Open Access Journals (Sweden)

    Iraj Nabipour

    2016-01-01

    Full Text Available The "technological singularity" is forecasted to occur in 2045. It is a point when non-biological intelligence becomes more intelligent than humans and each generation of intelligent machines re-designs itself smarter. Beyond this point, there is a symbiosis between machines and humans. This co-existence will produce incredible impacts on medicine that its sparkles could be seen in healthcare industry and the future medicine since 2025. Ray Kurzweil, the great futurist, suggested that three revolutions in science and technology consisting genetic and molecular science, nanotechnology, and robotic (artificial intelligence provided an exponential growth rate for medicine. The "exponential medicine" is going to create more disruptive technologies in healthcare industry. The exponential medicine shifts the paradigm of medical philosophy and produces significant impacts on the healthcare system and patient-physician relationship.   

  1. Spectral singularities and zero energy bound states

    Energy Technology Data Exchange (ETDEWEB)

    Heiss, W.D. [National Institute for Theoretical Physics, Stellenbosch Institute for Advanced Study, and Institute of Theoretical Physics, University of Stellenbosch, 7602 Matieland (South Africa); Nazmitdinov, R.G. [Department de Fisica, Universitat de les Illes Balears, E-07122 Palma de Mallorca (Spain); Bogoliubov Laboratory of Theoretical Physics, Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation)

    2011-08-15

    Single particle scattering around zero energy is re-analysed in view of recent experiments with ultra-cold atoms, nano-structures and nuclei far from the stability valley. For non-zero orbital angular momentum the low energy scattering cross section exhibits dramatic changes depending on the occurrence of either a near resonance or a bound state or the situation in between, that is a bound state at zero energy. Such state is singular in that it has an infinite scattering length, behaves for the eigenvalues but not for the eigenfunctions as an exceptional point and has no pole in the scattering function. These results should be observable whenever the interaction or scattering length can be controlled. (authors)

  2. On reliability of singular-value decomposition in attractor reconstruction

    International Nuclear Information System (INIS)

    Palus, M.; Dvorak, I.

    1990-12-01

    Applicability of singular-value decomposition for reconstructing the strange attractor from one-dimensional chaotic time series, proposed by Broomhead and King, is extensively tested and discussed. Previously published doubts about its reliability are confirmed: singular-value decomposition, by nature a linear method, is only of a limited power when nonlinear structures are studied. (author). 29 refs, 9 figs

  3. K3-fibered Calabi-Yau threefolds II, singular fibers

    OpenAIRE

    Hunt, Bruce

    1999-01-01

    In part I of this paper we constructed certain fibered Calabi-Yaus by a quotient construction in the context of weighted hypersurfaces. In this paper look at the case of K3 fibrations more closely and study the singular fibers which occur. This differs from previous work since the fibrations we discuss have constant modulus, and the singular fibers have torsion monodromy.

  4. Stability of naked singularity arising in gravitational collapse of Type ...

    Indian Academy of Sciences (India)

    to choose the velocity function and rest of the initial data so that the end state of collapse is either a black hole (BH) or a naked singularity (NS). This result is significant for two reasons: (1) It produces a substantially 'big' initial data set which under gravitational collapse results into a naked singularity. (2) Type I matter fields.

  5. A numerical method for solving singular De`s

    Energy Technology Data Exchange (ETDEWEB)

    Mahaver, W.T.

    1996-12-31

    A numerical method is developed for solving singular differential equations using steepest descent based on weighted Sobolev gradients. The method is demonstrated on a variety of first and second order problems, including linear constrained, unconstrained, and partially constrained first order problems, a nonlinear first order problem with irregular singularity, and two second order variational problems.

  6. The Notion of 'Singularity' in the Work of Gilles Deleuze

    DEFF Research Database (Denmark)

    Borum, Peter

    2017-01-01

    In Deleuze, singularity replaces generality in the economy of thought. A Deleuzian singularity is an event, but the notion comprises the effectuation of the event into form. The triptych émission–distribution–répartition itself distributes the dimensions of the passage from form-giving event...

  7. Reliable finite element methods for self-adjoint singular perturbation ...

    African Journals Online (AJOL)

    It is well known that the standard finite element method based on the space Vh of continuous piecewise linear functions is not reliable in solving singular perturbation problems. It is also known that the solution of a two-point boundaryvalue singular perturbation problem admits a decomposition into a regular part and a finite ...

  8. Singular Differential Equations and g-Drazin Invertible Operators

    Directory of Open Access Journals (Sweden)

    Alrazi Abdeljabbar

    2016-01-01

    Full Text Available We extend results of Favini, Nashed, and Zhao on singular differential equations using the g-Drazin inverse and the order of a quasinilpotent operator in the sense of Miekka and Nevanlinna. Two classes of singularly perturbed differential equations are studied using the continuity properties of the g-Drazin inverse obtained by Koliha and Rakočević.

  9. Singular Differential Equations and g-Drazin Invertible Operators

    OpenAIRE

    Abdeljabbar, Alrazi; Tran, Trung Dinh

    2016-01-01

    We extend results of Favini, Nashed, and Zhao on singular differential equations using the g-Drazin inverse and the order of a quasinilpotent operator in the sense of Miekka and Nevanlinna. Two classes of singularly perturbed differential equations are studied using the continuity properties of the g-Drazin inverse obtained by Koliha and Rakočević.

  10. Periodic solutions to second-order indefinite singular equations

    Czech Academy of Sciences Publication Activity Database

    Hakl, Robert; Zamora, M.

    2017-01-01

    Roč. 263, č. 1 (2017), s. 451-469 ISSN 0022-0396 Institutional support: RVO:67985840 Keywords : degree theory * indefinite singularity * periodic solution * singular differential equation Subject RIV: BA - General Mathematics OBOR OECD: Pure mathematics Impact factor: 1.988, year: 2016 http://www.sciencedirect.com/science/article/pii/S0022039617301134

  11. Some BMO estimates for vector-valued multilinear singular integral ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    the multilinear operator related to some singular integral operators is obtained. The main purpose of this paper is to establish the BMO end-point estimates for some vector-valued multilinear operators related to certain singular integral operators. First, let us introduce some notations [10,16]. Throughout this paper, Q = Q(x,r).

  12. Infinite derivative gravity : non-singular cosmology & blackhole solutions

    NARCIS (Netherlands)

    Mazumdar, Anupam

    2017-01-01

    Both Einstein's theory of General Relativity and Newton's theory of gravity possess a short dis- tance and small time scale catastrophe. The blackhole singularity and cosmological Big Bang singularity problems highlight that current theories of gravity are incomplete description at early times and

  13. The Metaphysics and Epistemology of Singular Terms | Borg ...

    African Journals Online (AJOL)

    Can we draw apart questions of what it is to be a singular term (a metaphysical issue) from questions about how we tell when some expression is a singular term (an epistemological matter)? Prima facie, it might seem we can't: language, as a man-made edifice, might seem to prohibit such a distinction, and, indeed, some ...

  14. Dynamics of Learning in MLP: Natural Gradient and Singularity Revisited.

    Science.gov (United States)

    Amari, Shun-Ichi; Ozeki, Tomoko; Karakida, Ryo; Yoshida, Yuki; Okada, Masato

    2018-01-01

    The dynamics of supervised learning play a main role in deep learning, which takes place in the parameter space of a multilayer perceptron (MLP). We review the history of supervised stochastic gradient learning, focusing on its singular structure and natural gradient. The parameter space includes singular regions in which parameters are not identifiable. One of our results is a full exploration of the dynamical behaviors of stochastic gradient learning in an elementary singular network. The bad news is its pathological nature, in which part of the singular region becomes an attractor and another part a repulser at the same time, forming a Milnor attractor. A learning trajectory is attracted by the attractor region, staying in it for a long time, before it escapes the singular region through the repulser region. This is typical of plateau phenomena in learning. We demonstrate the strange topology of a singular region by introducing blow-down coordinates, which are useful for analyzing the natural gradient dynamics. We confirm that the natural gradient dynamics are free of critical slowdown. The second main result is the good news: the interactions of elementary singular networks eliminate the attractor part and the Milnor-type attractors disappear. This explains why large-scale networks do not suffer from serious critical slowdowns due to singularities. We finally show that the unit-wise natural gradient is effective for learning in spite of its low computational cost.

  15. One Critical Case in Singularly Perturbed Control Problems

    Science.gov (United States)

    Sobolev, Vladimir

    2017-02-01

    The aim of the paper is to describe the special critical case in the theory of singularly perturbed optimal control problems. We reduce the original singularly perturbed problem to a regularized one such that the existence of slow integral manifolds can be established by means of the standard theory. We illustrate our approach by an example of control problem.

  16. Singularity is the future of ICT research | Osuagwu | West African ...

    African Journals Online (AJOL)

    Proponents of the singularity call the event an "intelligence explosion" which is a key factor of the Singularity where super-intelligence design successive generations of increasingly powerful minds. The originator of the term – Vernor Vinge - and popularized by Ray Kurzwei has proposed that Artificial Intelligence, human ...

  17. Singular Null Hypersurfaces in General Relativity

    International Nuclear Information System (INIS)

    Dray, T

    2006-01-01

    Null hypersurfaces are a mathematical consequence of the Lorentzian signature of general relativity; singularities in mathematical models usually indicate where the interesting physics takes place. This book discusses what happens when you combine these ideas. Right from the preface, this is a no-nonsense book. There are two principal approaches to singular shells, one distributional and the other 'cut and paste'; both are treated in detail. A working knowledge of GR is assumed, including familiarity with null tetrads, differential forms, and 3 + 1 decompositions. Despite my own reasonably extensive, closely related knowledge, there was material unfamiliar to me already in chapter 3, although I was reunited with some old friends in later chapters. The exposition is crisp, with a minimum of transition from chapter to chapter. In fact, my main criticism is that there is no clear statement of the organization of the book, nor is there an index. Everything is here, and the story is compelling if you know what to look for, although it is less easy to follow the story if you are not already familiar with it. But this is really a book for experts, and the authors certainly qualify, having played a significant role in developing and extending the results they describe. It is also entirely appropriate that the book is dedicated to Werner Israel, who pioneered the thin-shell approach to (non-null) singular surfaces and later championed the use of similar methods for analysing null shells. After an introductory chapter on impulsive signals, the authors show how the Bianchi identities can be used to classify spacetimes with singular null hypersurfaces. This approach, due to the authors, generalizes the framework originally proposed by Penrose. While astrophysical applications are discussed only briefly, the authors point out that detailed physical characteristics of signals from isolated sources can be determined in this manner. In particular, they describe the behaviour of

  18. Workshop on Singularities in Geometry, Topology, Foliations and Dynamics

    CERN Document Server

    Lê, Dung; Oka, Mutsuo; Snoussi, Jawad

    2017-01-01

    This book features state-of-the-art research on singularities in geometry, topology, foliations and dynamics and provides an overview of the current state of singularity theory in these settings. Singularity theory is at the crossroad of various branches of mathematics and science in general. In recent years there have been remarkable developments, both in the theory itself and in its relations with other areas. The contributions in this volume originate from the “Workshop on Singularities in Geometry, Topology, Foliations and Dynamics”, held in Merida, Mexico, in December 2014, in celebration of José Seade’s 60th Birthday. It is intended for researchers and graduate students interested in singularity theory and its impact on other fields.

  19. The structure of singularities in nonlocal transport equations

    Energy Technology Data Exchange (ETDEWEB)

    Hoz, F de la [Departamento de Matematica Aplicada, Universidad del PaIs Vasco-Euskal Herriko Unibertsitatea, Escuela Universitaria de IngenierIa Tecnica Industrial, Plaza de la Casilla 3, 48012 Bilbao (Spain); Fontelos, M A [Instituto de Matematicas y Fisica Fundamental, Consejo Superior de Investigaciones CientIficas, C/Serrano 123, 28006 Madrid (Spain)

    2008-05-09

    We describe the structure of solutions developing singularities in the form of cusps in finite time in nonlocal transport equations of the family: {theta}{sub t}-{delta}({theta}H({theta})){sub x}-(1-{delta})H({theta}){theta}{sub x}=0, 0<={delta}<=1, where H represents the Hilbert transform. Equations of this type appear in various contexts: evolution of vortex sheets, models for quasi-geostrophic equation and evolution equations for order parameters. Equation (1) was studied, and the existence of singularities developing in finite time was proved. The structure of such singularities was, nevertheless, not described. In this paper, we will describe the geometry of the solution in the neighborhood of the singularity once it develops and the (self-similar) way in which it is approached as t {yields} t{sub 0}, where t{sub 0} is the singular time.

  20. Complexity, Analysis and Control of Singular Biological Systems

    CERN Document Server

    Zhang, Qingling; Zhang, Xue

    2012-01-01

    Complexity, Analysis and Control of Singular Biological Systems follows the control of real-world biological systems at both ecological and phyisological levels concentrating on the application of now-extensively-investigated singular system theory. Much effort has recently been dedicated to the modelling and analysis of developing bioeconomic systems and the text establishes singular examples of these, showing how proper control can help to maintain sustainable economic development of biological resources. The book begins from the essentials of singular systems theory and bifurcations before tackling  the use of various forms of control in singular biological systems using examples including predator-prey relationships and viral vaccination and quarantine control. Researchers and graduate students studying the control of complex biological systems are shown how a variety of methods can be brought to bear and practitioners working with the economics of biological systems and their control will also find the ...

  1. Detection of Singularities in Fingerprint Images Using Linear Phase Portraits

    Science.gov (United States)

    Ram, Surinder; Bischof, Horst; Birchbauer, Josef

    abstract The performance of fingerprint recognition depends heavily on the reliable extraction of singularities. Common algorithms are based on a Poinc’are Index estimation. These algorithms are only robust when certain heuristics and rules are applied. In this chapter we present a model-based approach for the detection of singular points. The presented method exploits the geometric nature of linear differential equation systems. Our method is robust against noise in the input image and is able to detect singularities even if they are partly occluded. The algorithm proceeds by fitting linear phase portraits at each location of a sliding window and then analyses its parameters. Using a well-established mathematical background, our algorithm is able to decide if a singular point is existent. Furthermore, the parameters can be used to classify the type of the singular point into whorls, deltas and loops.

  2. On the efficiency of treating singularities in triatomic variational vibrational computations. The vibrational states of H(+)3 up to dissociation.

    Science.gov (United States)

    Szidarovszky, Tamás; Császár, Attila G; Czakó, Gábor

    2010-08-01

    Several techniques of varying efficiency are investigated, which treat all singularities present in the triatomic vibrational kinetic energy operator given in orthogonal internal coordinates of the two distances-one angle type. The strategies are based on the use of a direct-product basis built from one-dimensional discrete variable representation (DVR) bases corresponding to the two distances and orthogonal Legendre polynomials, or the corresponding Legendre-DVR basis, corresponding to the angle. The use of Legendre functions ensures the efficient treatment of the angular singularity. Matrix elements of the singular radial operators are calculated employing DVRs using the quadrature approximation as well as special DVRs satisfying the boundary conditions and thus allowing for the use of exact DVR expressions. Potential optimized (PO) radial DVRs, based on one-dimensional Hamiltonians with potentials obtained by fixing or relaxing the two non-active coordinates, are also studied. The numerical calculations employed Hermite-DVR, spherical-oscillator-DVR, and Bessel-DVR bases as the primitive radial functions. A new analytical formula is given for the determination of the matrix elements of the singular radial operator using the Bessel-DVR basis. The usually claimed failure of the quadrature approximation in certain singular integrals is revisited in one and three dimensions. It is shown that as long as no potential optimization is carried out the quadrature approximation works almost as well as the exact DVR expressions. If wave functions with finite amplitude at the boundary are to be computed, the basis sets need to meet the required boundary conditions. The present numerical results also confirm that PO-DVRs should be constructed employing relaxed potentials and PO-DVRs can be useful for optimizing quadrature points for calculations applying large coordinate intervals and describing large-amplitude motions. The utility and efficiency of the different algorithms

  3. PREFACE: Singular interactions in quantum mechanics: solvable models

    Science.gov (United States)

    Dell'Antonio, Gianfausto; Exner, Pavel; Geyler, Vladimir

    2005-06-01

    This issue comprises two dozen research papers which are all in one sense or another devoted to models in which the interaction is singular and sharply localized; a typical example is a quantum particle interacting with a family of δ-type potentials. Such an idealization usually makes analysis of their properties considerably easier, sometimes allowing us to reduce it to a simple algebraic problem—this is why one speaks about solvable models. The subject can be traced back to the early days of quantum mechanics; however, the progress in this field was slow and uneven until the 1960s, mostly because singular interactions are often difficult to deal with mathematically and intuitive arguments do not work. After overcoming the initial difficulties the `classical' theory of point interactions was developed, and finally summarized in 1988 in a monograph by Albeverio, Gesztesy, Høegh-Krohn, and Holden, which you will find quoted in numerous places within this issue. A reliable way to judge theories is to observe the progress they make within one or two decades. In this case there is no doubt that the field has witnessed a continuous development and covered areas which nobody had thought of when the subject first emerged. The reader may see it in the second edition of the aforementioned book which was published by AMS Chelsea only recently and contained a brief survey of these new achievements. It is no coincidence that this topical issue appears at the same time; it has been conceived as its counterpart and a forum at which fresh results in the field can demonstrated. Let us briefly survey the contents of the issue. While the papers included have in common the basic subject, they represent a broad spectrum philosophically as well as technically, and any attempt to classify them is somewhat futile. Nevertheless, we will divide them into a few groups. The first comprises contributions directly related to the usual point-interaction ideology. M Correggi and one of the

  4. A note on the Fisher information matrix for the skew-generalized-normal model

    OpenAIRE

    Arellano-Valle, Reinaldo B.

    2013-01-01

    In this paper, the exact form of the Fisher information matrix for the skew-generalized normal (SGN) distribution is determined. The existence of singularity problems of this matrix for the skewnormal and normal particular cases is investigated. Special attention is given to the asymptotic properties of the MLEs under the skew-normality hypothesis.

  5. A note on the Fisher information matrix for the skew-generalized-normal model

    OpenAIRE

    Arellano-Valle, Reinaldo B.; Gómez, Héctor W.; Salinas, Hugo S.

    2013-01-01

    In this paper, the exact form of the Fisher information matrix for the skew-generalized normal (SGN) distribution is determined. The existence of singularity problems of this matrix for the skew-normal and normal particular cases is investigated. Special attention is given to the asymptotic properties of the MLEs under the skew-normality hypothesis. Peer Reviewed

  6. Descriptive vector, relative error matrix, and interaction analysis of multivariable plants

    NARCIS (Netherlands)

    Monshizadeh-Naini, Nima; Fatehi, Alireza; Kahki-Sedigh, Ali

    In this paper, we introduce a vector which is able to describe the Niederlinski Index (NI), Relative Gain array (RGA), and the characteristic equation of the relative error matrix. The spectral radius and the structured singular value of the relative error matrix are investigated. The cases where

  7. Mitigating Wind Induced Noise in Outdoor Microphone Signals Using a Singular Spectral Subspace Method

    Directory of Open Access Journals (Sweden)

    Omar Eldwaik

    2018-01-01

    Full Text Available Wind induced noise is one of the major concerns of outdoor acoustic signal acquisition. It affects many field measurement and audio recording scenarios. Filtering such noise is known to be difficult due to its broadband and time varying nature. In this paper, a new method to mitigate wind induced noise in microphone signals is developed. Instead of applying filtering techniques, wind induced noise is statistically separated from wanted signals in a singular spectral subspace. The paper is presented in the context of handling microphone signals acquired outdoor for acoustic sensing and environmental noise monitoring or soundscapes sampling. The method includes two complementary stages, namely decomposition and reconstruction. The first stage decomposes mixed signals in eigen-subspaces, selects and groups the principal components according to their contributions to wind noise and wanted signals in the singular spectrum domain. The second stage reconstructs the signals in the time domain, resulting in the separation of wind noise and wanted signals. Results show that microphone wind noise is separable in the singular spectrum domain evidenced by the weighted correlation. The new method might be generalized to other outdoor sound acquisition applications.

  8. 3rd Singularity Theory Meeting of Northeast region & the Brazil-Mexico 2nd Meeting on Singularities

    CERN Document Server

    Neto, Aurélio; Mond, David; Saia, Marcelo; Snoussi, Jawad; BMMS 2/NBMS 3; ENSINO; Singularities and foliations geometry, topology and applications

    2018-01-01

    This proceedings book brings selected works from two conferences, the 2nd Brazil-Mexico Meeting on Singularity and the 3rd Northeastern Brazilian Meeting on Singularities, that were hold in Salvador, in July 2015. All contributions were carefully peer-reviewed and revised, and cover topics like Equisingularity, Topology and Geometry of Singularities, Topological Classification of Singularities of Mappings, and more. They were written by mathematicians from several countries, including Brazil, Spain, Mexico, Japan and the USA, on relevant topics on Theory of Singularity, such as studies on deformations, Milnor fibration, foliations, Catastrophe theory, and myriad applications. Open problems are also introduced, making this volume a must-read both for graduate students and active researchers in this field.

  9. An evaluation of parallel multigrid as a solver and a preconditioner for singular perturbed problems

    Energy Technology Data Exchange (ETDEWEB)

    Oosterlee, C.W. [Inst. for Algorithms and Scientific Computing, Sankt Augustin (Germany); Washio, T. [C& C Research Lab., Sankt Augustin (Germany)

    1996-12-31

    In this paper we try to achieve h-independent convergence with preconditioned GMRES and BiCGSTAB for 2D singular perturbed equations. Three recently developed multigrid methods are adopted as a preconditioner. They are also used as solution methods in order to compare the performance of the methods as solvers and as preconditioners. Two of the multigrid methods differ only in the transfer operators. One uses standard matrix- dependent prolongation operators from. The second uses {open_quotes}upwind{close_quotes} prolongation operators, developed. Both employ the Galerkin coarse grid approximation and an alternating zebra line Gauss-Seidel smoother. The third method is based on the block LU decomposition of a matrix and on an approximate Schur complement. This multigrid variant is presented in. All three multigrid algorithms are algebraic methods.

  10. Neutrino mixing in a grand unified theory

    International Nuclear Information System (INIS)

    Milton, K.; Tanaka, K.

    1980-01-01

    Neutrino mixing in a grand unified theory in which the neutrino mass matrix is determined by the Gell-Mann-Ramond-Slansky mechanism was investigated. With an arbitrary real right-handed Majorana mass matrix which incorporates three neutrino mass scales, the effects of the up-quark mass matrix are found to be dominant and as a result no significant mixing of ν/sub e/ occurs, while ν/sub μ/ - ν/sub γ/ mixing can be substantial

  11. Constructing diabatic representations using adiabatic and approximate diabatic data - Coping with diabolical singularities

    Science.gov (United States)

    Zhu, Xiaolei; Yarkony, David R.

    2016-01-01

    We have recently introduced a diabatization scheme, which simultaneously fits and diabatizes adiabatic ab initio electronic wave functions, Zhu and Yarkony J. Chem. Phys. 140, 024112 (2014). The algorithm uses derivative couplings in the defining equations for the diabatic Hamiltonian, Hd, and fits all its matrix elements simultaneously to adiabatic state data. This procedure ultimately provides an accurate, quantifiably diabatic, representation of the adiabatic electronic structure data. However, optimizing the large number of nonlinear parameters in the basis functions and adjusting the number and kind of basis functions from which the fit is built, which provide the essential flexibility, has proved challenging. In this work, we introduce a procedure that combines adiabatic state and diabatic state data to efficiently optimize the nonlinear parameters and basis function expansion. Further, we consider using direct properties based diabatizations to initialize the fitting procedure. To address this issue, we introduce a systematic method for eliminating the debilitating (diabolical) singularities in the defining equations of properties based diabatizations. We exploit the observation that if approximate diabatic data are available, the commonly used approach of fitting each matrix element of Hd individually provides a starting point (seed) from which convergence of the full Hd construction algorithm is rapid. The optimization of nonlinear parameters and basis functions and the elimination of debilitating singularities are, respectively, illustrated using the 1,2,3,41A states of phenol and the 1,21A states of NH3, states which are coupled by conical intersections.

  12. Constructing diabatic representations using adiabatic and approximate diabatic data – Coping with diabolical singularities

    International Nuclear Information System (INIS)

    Zhu, Xiaolei; Yarkony, David R.

    2016-01-01

    We have recently introduced a diabatization scheme, which simultaneously fits and diabatizes adiabatic ab initio electronic wave functions, Zhu and Yarkony J. Chem. Phys. 140, 024112 (2014). The algorithm uses derivative couplings in the defining equations for the diabatic Hamiltonian, H d , and fits all its matrix elements simultaneously to adiabatic state data. This procedure ultimately provides an accurate, quantifiably diabatic, representation of the adiabatic electronic structure data. However, optimizing the large number of nonlinear parameters in the basis functions and adjusting the number and kind of basis functions from which the fit is built, which provide the essential flexibility, has proved challenging. In this work, we introduce a procedure that combines adiabatic state and diabatic state data to efficiently optimize the nonlinear parameters and basis function expansion. Further, we consider using direct properties based diabatizations to initialize the fitting procedure. To address this issue, we introduce a systematic method for eliminating the debilitating (diabolical) singularities in the defining equations of properties based diabatizations. We exploit the observation that if approximate diabatic data are available, the commonly used approach of fitting each matrix element of H d individually provides a starting point (seed) from which convergence of the full H d construction algorithm is rapid. The optimization of nonlinear parameters and basis functions and the elimination of debilitating singularities are, respectively, illustrated using the 1,2,3,4 1 A states of phenol and the 1,2 1 A states of NH 3 , states which are coupled by conical intersections

  13. Matrix thermalization

    Energy Technology Data Exchange (ETDEWEB)

    Craps, Ben [Theoretische Natuurkunde, Vrije Universiteit Brussel (VUB), and International Solvay Institutes, Pleinlaan 2, B-1050 Brussels (Belgium); Evnin, Oleg [Department of Physics, Faculty of Science, Chulalongkorn University, Thanon Phayathai, Pathumwan, Bangkok 10330 (Thailand); Theoretische Natuurkunde, Vrije Universiteit Brussel (VUB), and International Solvay Institutes, Pleinlaan 2, B-1050 Brussels (Belgium); Nguyen, Kévin [Theoretische Natuurkunde, Vrije Universiteit Brussel (VUB), and International Solvay Institutes, Pleinlaan 2, B-1050 Brussels (Belgium)

    2017-02-08

    Matrix quantum mechanics offers an attractive environment for discussing gravitational holography, in which both sides of the holographic duality are well-defined. Similarly to higher-dimensional implementations of holography, collapsing shell solutions in the gravitational bulk correspond in this setting to thermalization processes in the dual quantum mechanical theory. We construct an explicit, fully nonlinear supergravity solution describing a generic collapsing dilaton shell, specify the holographic renormalization prescriptions necessary for computing the relevant boundary observables, and apply them to evaluating thermalizing two-point correlation functions in the dual matrix theory.

  14. Propagation property of the non-paraxial vector Lissajous singularity beams in free space

    Science.gov (United States)

    Chen, Haitao; Gao, Zenghui

    2016-12-01

    The analytic expressions for the free-space propagation of paraxial and non-paraxial vector Lissajous singularity beams are derived, and used to compare the propagation property of a Lissajous singularity carried by paraxial and non-paraxial vector beams in free space. It is found that the creation of a single Lissajous singularity, the creation and annihilation of pairs Lissajous singularities may take place for the both cases. However, after the annihilation of a pair of singularities, no Lissajous singularities appear in the output field for non-paraxial vector Lissajous singularity beams, which is different from the paraxial vector Lissajous singularity beams.

  15. Quantum healing of classical singularities in power-law spacetimes

    Energy Technology Data Exchange (ETDEWEB)

    Helliwell, T M [Department of Physics, Harvey Mudd College, Claremont, CA 91711 (United States); Konkowski, D A [Department of Mathematics, US Naval Academy, Annapolis, MD 21402 (United States)

    2007-07-07

    We study a broad class of spacetimes whose metric coefficients reduce to powers of a radius r in the limit of small r. Among these four-parameter 'power-law' metrics, we identify those parameters for which the spacetimes have classical singularities as r {yields} 0. We show that a large set of such classically-singular spacetimes is nevertheless non-singular quantum mechanically, in that the Hamiltonian operator is essentially self-adjoint, so that the evolution of quantum wave packets lacks the ambiguity associated with scattering off singularities. Using these metrics, the broadest class yet studied to compare classical with quantum singularities, we explore the physical reasons why some that are singular classically are 'healed' quantum mechanically, while others are not. We show that most (but not all) of the remaining quantum-mechanically singular spacetimes can be excluded if either the weak energy condition or the dominant energy condition is invoked, and we briefly discuss the effect of this work on the strong cosmic censorship conjecture.

  16. Terminal singularities, Milnor numbers, and matter in F-theory

    Science.gov (United States)

    Arras, Philipp; Grassi, Antonella; Weigand, Timo

    2018-01-01

    We initiate a systematic investigation of F-theory on elliptic fibrations with singularities which cannot be resolved without breaking the Calabi-Yau condition, corresponding to Q-factorial terminal singularities. It is the purpose of this paper to elucidate the physical origin of such non-crepant singularities in codimension two and to systematically analyze F-theory compactifications containing such singularities. The singularities reflect the presence of localized matter states from wrapped M2-branes which are not charged under any massless gauge potential. We identify a class of Q-factorial terminal singularities on elliptically fibered Calabi-Yau threefolds for which we can compute the number of uncharged localized hypermultiplets in terms of their associated Milnor numbers. These count the local complex deformations of the singularities. The resulting six-dimensional spectra are shown to be anomaly-free. We exemplify this in a variety of cases, including models with non-perturbative gauge groups with both charged and uncharged localized matter. The underlying mathematics will be discussed further in a forthcoming publication.

  17. Boundary singularities produced by the motion of soap films.

    Science.gov (United States)

    Goldstein, Raymond E; McTavish, James; Moffatt, H Keith; Pesci, Adriana I

    2014-06-10

    Recent work has shown that a Möbius strip soap film rendered unstable by deforming its frame changes topology to that of a disk through a "neck-pinching" boundary singularity. This behavior is unlike that of the catenoid, which transitions to two disks through a bulk singularity. It is not yet understood whether the type of singularity is generally a consequence of the surface topology, nor how this dependence could arise from an equation of motion for the surface. To address these questions we investigate experimentally, computationally, and theoretically the route to singularities of soap films with different topologies, including a family of punctured Klein bottles. We show that the location of singularities (bulk or boundary) may depend on the path of the boundary deformation. In the unstable regime the driving force for soap-film motion is the mean curvature. Thus, the narrowest part of the neck, associated with the shortest nontrivial closed geodesic of the surface, has the highest curvature and is the fastest moving. Just before onset of the instability there exists on the stable surface the shortest closed geodesic, which is the initial condition for evolution of the neck's geodesics, all of which have the same topological relationship to the frame. We make the plausible conjectures that if the initial geodesic is linked to the boundary, then the singularity will occur at the boundary, whereas if the two are unlinked initially, then the singularity will occur in the bulk. Numerical study of mean curvature flows and experiments support these conjectures.

  18. Solutions of dissimilar material singularity and contact problems

    International Nuclear Information System (INIS)

    Yang, Y.

    2003-09-01

    Due to the mismatch of the material properties of joined components, after a homogeneous temperature change or under a mechanical loading, very high stresses occur near the intersection of the interface and the outer surface, or near the intersection of two interfaces. For most material combinations and joint geometries, there exists even a stress singularity. These high stresses may cause fracture of the joint. The investigation of the stress situation near the singular point, therefore, is of great interest. Especially, the relationship between the singular stress exponent, the material data and joint geometry is important for choosing a suitable material combination and joint geometry. In this work, the singular stress field is described analytically in case of the joint having a real and a complex eigenvalue. Solutions of different singularity problems are given, which are two dissimilar materials joint with free edges; dissimilar materials joint with edge tractions; joint with interface corner; joint with a given displacement at one edge; cracks in dissimilar materials joint; contact problem in dissimilar materials and logarithmic stress singularity. For an arbitrary joint geometry and material combination, the stress singular exponent, the angular function and the regular stress term can be calculated analytically. The stress intensity factors for a finite joint can be determined applying numerical methods, e.g. the finite element method (FEM). The method to determine more than one stress intensity factor is presented. The characteristics of the eigenvalues and the stress intensity factors are shown for different joint conditions. (orig.)

  19. Singular Dimensions of theN= 2 Superconformal Algebras. I

    Science.gov (United States)

    Dörrzapf, Matthias; Gato-Rivera, Beatriz

    Verma modules of superconfomal algebras can have singular vector spaces with dimensions greater than 1. Following a method developed for the Virasoro algebra by Kent, we introduce the concept of adapted orderings on superconformal algebras. We prove several general results on the ordering kernels associated to the adapted orderings and show that the size of an ordering kernel implies an upper limit for the dimension of a singular vector space. We apply this method to the topological N= 2 algebra and obtain the maximal dimensions of the singular vector spaces in the topological Verma modules: 0, 1, 2 or 3 depending on the type of Verma module and the type of singular vector. As a consequence we prove the conjecture of Gato-Rivera and Rosado on the possible existing types of topological singular vectors (4 in chiral Verma modules and 29 in complete Verma modules). Interestingly, we have found two-dimensional spaces of singular vectors at level 1. Finally, by using the topological twists and the spectral flows, we also obtain the maximal dimensions of the singular vector spaces for the Neveu-Schwarz N= 2 algebra (0, 1 or 2) and for the Ramond N= 2 algebra (0, 1, 2 or 3).

  20. Mixed nickel-gallium tellurides Ni{sub 3−x}GaTe{sub 2} as a matrix for incorporating magnetic cations: A Ni{sub 3−x}Fe{sub x}GaTe{sub 2} series

    Energy Technology Data Exchange (ETDEWEB)

    Kuznetsov, Alexey N., E-mail: alexei@inorg.chem.msu.ru [Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, GSP-1, 119991 Moscow (Russian Federation); N.S. Kurnakov Institute of General and Inorganic Chemistry, RAS, Leninsky pr. 31, GSP-1, 119991 Moscow (Russian Federation); Stroganova, Ekaterina A.; Zakharova, Elena Yu; Solopchenko, Alexander V.; Sobolev, Alexey V.; Presniakov, Igor A. [Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, GSP-1, 119991 Moscow (Russian Federation); Kirdyankin, Denis I.; Novotortsev, Vladimir M. [N.S. Kurnakov Institute of General and Inorganic Chemistry, RAS, Leninsky pr. 31, GSP-1, 119991 Moscow (Russian Federation)

    2017-06-15

    Using a high-temperature ampoule technique, a series of mixed nickel-iron-gallium metal-rich tellurides with layered structures, Ni{sub 3-x}Fe{sub x}GaTe{sub 2}, were prepared and characterized based on X-ray powder diffraction, energy-dispersive spectroscopy, and {sup 57}Fe Mössbauer spectroscopy data. These compounds may be regarded as a result of partial substitution of nickel by iron in the recently reported ternary Ni{sub 3-x}GaTe{sub 2} series, which are based on NiAs/Ni{sub 2}In type of structure. The compositional boundary for the substitution was found to be at x~1. According to the Mössbauer spectroscopy data, the substitution is not statistical, and iron atoms with the increase in x tend to preferentially occupy those nickel positions that are partially vacant in the initial ternary compound. Magnetic measurements data for the Ni{sub 3-x}Fe{sub x}GaTe{sub 2} series show dramatic change in behavior from temperature-independent paramagnetic properties of the initial matrix to a low-temperature (~75 K) ferromagnetic ordering in the Ni{sub 2}FeGaTe{sub 2}. - Graphical abstract: Ordered substitution of nickel by iron in the Ni{sub 3−x}GaTe{sub 2} series leading to ferromagnetic ordering. - Highlights: • A series of Ni{sub 3−x}Fe{sub x}GaTe{sub 2} compounds were synthesized. • They adopt the NiAs/Ni{sub 2}In type of structure with ordered iron distribution. • The distribution of iron was studied using {sup 57}Fe Mössbauer spectroscopy. • An increase in iron content leads to the strong ferromagnetic coupling.

  1. Mixed nickel-gallium tellurides Ni3−xGaTe2 as a matrix for incorporating magnetic cations: A Ni3−xFexGaTe2 series

    International Nuclear Information System (INIS)

    Kuznetsov, Alexey N.; Stroganova, Ekaterina A.; Zakharova, Elena Yu; Solopchenko, Alexander V.; Sobolev, Alexey V.; Presniakov, Igor A.; Kirdyankin, Denis I.; Novotortsev, Vladimir M.

    2017-01-01

    Using a high-temperature ampoule technique, a series of mixed nickel-iron-gallium metal-rich tellurides with layered structures, Ni 3-x Fe x GaTe 2 , were prepared and characterized based on X-ray powder diffraction, energy-dispersive spectroscopy, and 57 Fe Mössbauer spectroscopy data. These compounds may be regarded as a result of partial substitution of nickel by iron in the recently reported ternary Ni 3-x GaTe 2 series, which are based on NiAs/Ni 2 In type of structure. The compositional boundary for the substitution was found to be at x~1. According to the Mössbauer spectroscopy data, the substitution is not statistical, and iron atoms with the increase in x tend to preferentially occupy those nickel positions that are partially vacant in the initial ternary compound. Magnetic measurements data for the Ni 3-x Fe x GaTe 2 series show dramatic change in behavior from temperature-independent paramagnetic properties of the initial matrix to a low-temperature (~75 K) ferromagnetic ordering in the Ni 2 FeGaTe 2 . - Graphical abstract: Ordered substitution of nickel by iron in the Ni 3−x GaTe 2 series leading to ferromagnetic ordering. - Highlights: • A series of Ni 3−x Fe x GaTe 2 compounds were synthesized. • They adopt the NiAs/Ni 2 In type of structure with ordered iron distribution. • The distribution of iron was studied using 57 Fe Mössbauer spectroscopy. • An increase in iron content leads to the strong ferromagnetic coupling.

  2. Singularity Preserving Numerical Methods for Boundary Integral Equations

    Science.gov (United States)

    Kaneko, Hideaki (Principal Investigator)

    1996-01-01

    In the past twelve months (May 8, 1995 - May 8, 1996), under the cooperative agreement with Division of Multidisciplinary Optimization at NASA Langley, we have accomplished the following five projects: a note on the finite element method with singular basis functions; numerical quadrature for weakly singular integrals; superconvergence of degenerate kernel method; superconvergence of the iterated collocation method for Hammersteion equations; and singularity preserving Galerkin method for Hammerstein equations with logarithmic kernel. This final report consists of five papers describing these projects. Each project is preceeded by a brief abstract.

  3. Repulsive and attractive timelike singularities in vacuum cosmologies

    International Nuclear Information System (INIS)

    Miller, B.D.

    1979-01-01

    Spherically symmetric cosmologies whose big bang is partially spacelike and partially timelike are constrained to occur only in the presence of certain types of matter, and in such cosmologies the timelike part of the big bang is a negative-mass singularity. In this paper examples are given of cylindrically symmetric cosmologies whose big bang is partially spacelike and partially timelike. These cosmologies are vacuum. In some of them, the timelike part of the big bang is clearly a (generalized) negative-mass singularity, while in others it is a (generalized) positive-mass singularity

  4. Finger image quality based on singular point localization

    DEFF Research Database (Denmark)

    Wang, Jinghua; Olsen, Martin A.; Busch, Christoph

    2014-01-01

    Singular points are important global features of fingerprints and singular point localization is a crucial step in biometric recognition. Moreover the presence and position of the core point in a captured fingerprint sample can reflect whether the finger is placed properly on the sensor. Therefore...... and analyze the importance of singular points on biometric accuracy. The experiment is based on large scale databases and conducted by relating the measured quality of a fingerprint sample, given by the positions of core points, to the biometric performance. The experimental results show the positions of core...

  5. Singularity fitting in hydrodynamical calculations II

    International Nuclear Information System (INIS)

    Richtmyer, R.D.; Lazarus, R.B.

    1975-09-01

    This is the second report in a series on the development of techniques for the proper handling of singularities in fluid-dynamical calculations; the first was called Progress Report on the Shock-Fitting Project. This report contains six main results: derivation of a free-surface condition, which relates the acceleration of the surface with the gradient of the square of the sound speed just behind it; an accurate method for the early and middle stages of the development of a rarefaction wave, two orders of magnitude more accurate than a simple direct method used for comparison; the similarity theory of the collapsing free surface, where it is shown that there is a two-parameter family of self-similar solutions for γ = 3.9; the similarity theory for the outgoing shock, which takes into account the entropy increase; a ''zooming'' method for the study of the asymptotic behavior of solutions of the full initial boundary-value problem; comparison of two methods for determining the similarity parameter delta by zooming, which shows that the second method is preferred. Future reports in the series will contain discussions of the self-similar solutions for this problem, and for that of the collapsing shock, in more detail and for the full range (1, infinity) of γ; the values of certain integrals related to neutronic and thermonuclear rates near collapse; and methods for fitting shocks, contact discontinuities, interfaces, and free surfaces in two-dimensional flows

  6. Singular perturbation in the physical sciences

    CERN Document Server

    Neu, John C

    2015-01-01

    This book is the testimony of a physical scientist whose language is singular perturbation analysis. Classical mathematical notions, such as matched asymptotic expansions, projections of large dynamical systems onto small center manifolds, and modulation theory of oscillations based either on multiple scales or on averaging/transformation theory, are included. The narratives of these topics are carried by physical examples: Let's say that the moment when we "see" how a mathematical pattern fits a physical problem is like "hitting the ball." Yes, we want to hit the ball. But a powerful stroke includes the follow-through. One intention of this book is to discern in the structure and/or solutions of the equations their geometric and physical content. Through analysis, we come to sense directly the shape and feel of phenomena. The book is structured into a main text of fundamental ideas and a subtext of problems with detailed solutions. Roughly speaking, the former is the initial contact between mathematics and p...

  7. Singular limits in thermodynamics of viscous fluids

    CERN Document Server

    Feireisl, Eduard

    2017-01-01

    This book is about singular limits of systems of partial differential equations governing the motion of thermally conducting compressible viscous fluids. "The main aim is to provide mathematically rigorous arguments how to get from the compressible Navier-Stokes-Fourier system several less complex systems of partial differential equations used e.g. in meteorology or astrophysics. However, the book contains also a detailed introduction to the modelling in mechanics and thermodynamics of fluids from the viewpoint of continuum physics. The book is very interesting and important. It can be recommended not only to specialists in the field, but it can also be used for doctoral students and young researches who want to start to work in the mathematical theory of compressible fluids and their asymptotic limits." Milan Pokorný (zbMATH) "This book is of the highest quality from every point of view. It presents, in a unified way, recent research material of fundament al importance. It is self-contained, thanks to Chapt...

  8. Unified Singularity Modeling and Reconfiguration of 3rTPS Metamorphic Parallel Mechanisms with Parallel Constraint Screws

    Directory of Open Access Journals (Sweden)

    Yufeng Zhuang

    2015-01-01

    Full Text Available This paper presents a unified singularity modeling and reconfiguration analysis of variable topologies of a class of metamorphic parallel mechanisms with parallel constraint screws. The new parallel mechanisms consist of three reconfigurable rTPS limbs that have two working phases stemming from the reconfigurable Hooke (rT joint. While one phase has full mobility, the other supplies a constraint force to the platform. Based on these, the platform constraint screw systems show that the new metamorphic parallel mechanisms have four topologies by altering the limb phases with mobility change among 1R2T (one rotation with two translations, 2R2T, and 3R2T and mobility 6. Geometric conditions of the mechanism design are investigated with some special topologies illustrated considering the limb arrangement. Following this and the actuation scheme analysis, a unified Jacobian matrix is formed using screw theory to include the change between geometric constraints and actuation constraints in the topology reconfiguration. Various singular configurations are identified by analyzing screw dependency in the Jacobian matrix. The work in this paper provides basis for singularity-free workspace analysis and optimal design of the class of metamorphic parallel mechanisms with parallel constraint screws which shows simple geometric constraints with potential simple kinematics and dynamics properties.

  9. The Reciprocal Pascal Matrix

    OpenAIRE

    Richardson, Thomas M.

    2014-01-01

    The reciprocal Pascal matrix is the Hadamard inverse of the symmetric Pascal matrix. We show that the ordinary matrix inverse of the reciprocal Pascal matrix has integer elements. The proof uses two factorizations of the matrix of super Catalan numbers.

  10. Singular perturbation for nonlinear boundary-value problems

    Directory of Open Access Journals (Sweden)

    Rina Ling

    1979-01-01

    studied. The problem is a model arising in nuclear energy distribution. For large values of the parameter, the differential equations are of the singular-perturbation type and approximations are constructed by the method of matched asymptotic expansions.

  11. A constraint algorithm for singular Lagrangians subjected to nonholonomic constraints

    Energy Technology Data Exchange (ETDEWEB)

    de Leon, M. [Instituto de Matematicas y Fisica Fundamental, Consejo Superior de Investigaciones Cientificas, Serrano 123, 28006 Madrid (Spain); de Diego, D.M. [Departamento de Economia Aplicada Cuantitativa, Facultad de Ciencias Economicas y Empresariales, UNED, 28040 Madrid (Spain)

    1997-06-01

    We construct a constraint algorithm for singular Lagrangian systems subjected to nonholonomic constraints which generalizes that of Dirac for constrained Hamiltonian systems. {copyright} {ital 1997 American Institute of Physics.}

  12. A singular value sensitivity approach to robust eigenstructure assignment

    DEFF Research Database (Denmark)

    Søgaard-Andersen, Per; Trostmann, Erik; Conrad, Finn

    1986-01-01

    A design technique for improving the feedback properties of multivariable state feedback systems designed using eigenstructure assignment is presented. Based on a singular value analysis of the feedback properties a design parameter adjustment procedure is outlined. This procedure allows...

  13. Quantum gravitational collapse: non-singularity and non-locality

    International Nuclear Information System (INIS)

    Greenwood, Eric; Stojkovic, Dejan

    2008-01-01

    We investigate gravitational collapse in the context of quantum mechanics. We take primary interest in the behavior of the collapse near the horizon and near the origin (classical singularity) from the point of view of an infalling observer. In the absence of radiation, quantum effects near the horizon do not change the classical conclusions for an infalling observer, meaning the horizon is not an obstacle for him. However, quantum effects are able to remove the classical singularity at the origin, since the wave function is non-singular at the origin. Also, near the classical singularity, some non-local effects become important. In the Schrodinger equation describing behavior near the origin, derivatives of the wave function at one point are related to the value of the wave function at some other distant point.

  14. A singularity-free WEC-respecting time machine

    OpenAIRE

    Krasnikov, S. V.

    1997-01-01

    A time machine (TM) is constructed whose creating in contrast to all TMs known so far requires neither singularities, nor violation of the weak energy condition (WEC). The spacetime exterior to the TM closely resembles the Friedmann universe.

  15. Pulses in singularly perturbed reaction-diffusion systems

    NARCIS (Netherlands)

    Veerman, Frederik Willem Johan

    2013-01-01

    In this thesis, the existence and stability of pulse solutions in two-component, singularly perturbed reaction-diffusion systems is analysed using dynamical systems techniques. New phenomena in very general types of systems emerge when geometrical techniques are applied.

  16. Propagation of singularities for linearised hybrid data impedance tomography

    DEFF Research Database (Denmark)

    Bal, Guillaume; Hoffmann, Kristoffer; Knudsen, Kim

    2017-01-01

    For a general formulation of linearised hybrid inverse problems in impedance tomography, the qualitative properties of the solutions are analysed. Using an appropriate scalar pseudo-differential formulation, the problems are shown to permit propagating singularities under certain non...

  17. Object detection with a multistatic array using singular value decomposition

    Science.gov (United States)

    Hallquist, Aaron T.; Chambers, David H.

    2014-07-01

    A method and system for detecting the presence of subsurface objects within a medium is provided. In some embodiments, the detection system operates in a multistatic mode to collect radar return signals generated by an array of transceiver antenna pairs that is positioned across a surface and that travels down the surface. The detection system converts the return signals from a time domain to a frequency domain, resulting in frequency return signals. The detection system then performs a singular value decomposition for each frequency to identify singular values for each frequency. The detection system then detects the presence of a subsurface object based on a comparison of the identified singular values to expected singular values when no subsurface object is present.

  18. Geometric singular perturbation analysis of systems with friction

    DEFF Research Database (Denmark)

    Bossolini, Elena

    This thesis is concerned with the application of geometric singular perturbation theory to mechanical systems with friction. The mathematical background on geometric singular perturbation theory, on the blow-up method, on non-smooth dynamical systems and on regularization is presented. Thereafter...... use a Poincaré compactification to study the system near infinity. At infinity, the critical manifold loses hyperbolicity with an exponential rate. We use an adaptation of the blow-up method to recover the hyperbolicity. This enables the identification of a new attracting manifold, that organises...... singular, in contrast to the regular stiction solutions that are forward unique. In order to further the understanding of the non-unique dynamics, we introduce a regularization of the model. This gives a singularly perturbed problem that captures the main features of the original discontinuous problem. We...

  19. Singularities of robot mechanisms numerical computation and avoidance path planning

    CERN Document Server

    Bohigas, Oriol; Ros, Lluís

    2017-01-01

    This book presents the singular configurations associated with a robot mechanism, together with robust methods for their computation, interpretation, and avoidance path planning. Having such methods is essential as singularities generally pose problems to the normal operation of a robot, but also determine the workspaces and motion impediments of its underlying mechanical structure. A distinctive feature of this volume is that the methods are applicable to nonredundant mechanisms of general architecture, defined by planar or spatial kinematic chains interconnected in an arbitrary way. Moreover, singularities are interpreted as silhouettes of the configuration space when seen from the input or output spaces. This leads to a powerful image that explains the consequences of traversing singular configurations, and all the rich information that can be extracted from them. The problems are solved by means of effective branch-and-prune and numerical continuation methods that are of independent interest in themselves...

  20. On the singularities of massive superstring amplitudes

    International Nuclear Information System (INIS)

    Foda, O.

    1987-01-01

    Superstring one-loop amplitudes with massive external states are shown to be in general ill-defined due to internal on-shell propagators. However, we argue that since any massive string state (in the uncompactified theory) has a finite lifetime to decay into massless particles, such amplitudes are not terms in the perturbative expansion of physical S-matrix elements: These can be defined only with massless external states. Consistent massive amplitudes repuire an off-shell formalism. (orig.)

  1. On the singularities of massive superstring amplitudes

    Energy Technology Data Exchange (ETDEWEB)

    Foda, O.

    1987-06-04

    Superstring one-loop amplitudes with massive external states are shown to be in general ill-defined due to internal on-shell propagators. However, we argue that since any massive string state (in the uncompactified theory) has a finite lifetime to decay into massless particles, such amplitudes are not terms in the perturbative expansion of physical S-matrix elements: These can be defined only with massless external states. Consistent massive amplitudes repuire an off-shell formalism.

  2. Two-Sided Gravitational Mirror: Sealing off Curvature Singularities

    OpenAIRE

    Davidson, Aharon; Yellin, Ben

    2011-01-01

    A gravitational mirror is a non-singular finite redshift surface which bounces all incident null geodesics. While a white mirror (outward bouncing) resembles 't Hooft's brick wall, a black mirror (inward bouncing) offers a novel mechanism for sealing off curvature singularities. The geometry underlying a two-sided mirror is characterized by a single signature change, to be contrasted with the signature flip which governs the black hole geometry. To demonstrate the phenomenon analytically, we ...

  3. Wave-breaking and generic singularities of nonlinear hyperbolic equations

    International Nuclear Information System (INIS)

    Pomeau, Yves; Le Berre, Martine; Guyenne, Philippe; Grilli, Stephan

    2008-01-01

    Wave-breaking is studied analytically first and the results are compared with accurate numerical simulations of 3D wave-breaking. We focus on the time dependence of various quantities becoming singular at the onset of breaking. The power laws derived from general arguments and the singular behaviour of solutions of nonlinear hyperbolic differential equations are in excellent agreement with the numerical results. This shows the power of the analysis by methods using generic concepts of nonlinear science. (open problem)

  4. Uniqueness of singular solution of semilinear elliptic equation

    Indian Academy of Sciences (India)

    Nonhomogeneous semilinear elliptic equation; positive solutions; asymptotic behavior; singular ... a removable singular point of a solution of equation (1.1), the existence of the derivatives of the solution depends on the 'blow up' ..... On the other hand, for 0 <ε

  5. Singularity confinement for maps with the Laurent property

    International Nuclear Information System (INIS)

    Hone, A.N.W.

    2007-01-01

    The singularity confinement test is very useful for isolating integrable cases of discrete-time dynamical systems, but it does not provide a sufficient criterion for integrability. Quite recently a new property of the bilinear equations appearing in discrete soliton theory has been noticed: The iterates of such equations are Laurent polynomials in the initial data. A large class of non-integrable mappings of the plane are presented which both possess this Laurent property and have confined singularities

  6. Multifractal signal reconstruction based on singularity power spectrum

    International Nuclear Information System (INIS)

    Xiong, Gang; Yu, Wenxian; Xia, Wenxiang; Zhang, Shuning

    2016-01-01

    Highlights: • We propose a novel multifractal reconstruction method based on singularity power spectrum analysis (MFR-SPS). • The proposed MFR-SPS method has better power characteristic than the algorithm in Fraclab. • Further, the SPS-ISE algorithm performs better than the SPS-MFS algorithm. • Based on the proposed MFR-SPS method, we can restructure singularity white fractal noise (SWFN) and linear singularity modulation (LSM) multifractal signal, in equivalent sense, similar with the linear frequency modulation(LFM) signal and WGN in the Fourier domain. - Abstract: Fractal reconstruction (FR) and multifractal reconstruction (MFR) can be considered as the inverse problem of singularity spectrum analysis, and it is challenging to reconstruct fractal signal in accord with multifractal spectrum (MFS). Due to the multiple solutions of fractal reconstruction, the traditional methods of FR/MFR, such as FBM based method, wavelet based method, random wavelet series, fail to reconstruct fractal signal deterministically, and besides, those methods neglect the power spectral distribution in the singular domain. In this paper, we propose a novel MFR method based singularity power spectrum (SPS). Supposing the consistent uniform covering of multifractal measurement, we control the traditional power law of each scale of wavelet coefficients based on the instantaneous singularity exponents (ISE) or MFS, simultaneously control the singularity power law based on the SPS, and deduce the principle and algorithm of MFR based on SPS. Reconstruction simulation and error analysis of estimated ISE, MFS and SPS show the effectiveness and the improvement of the proposed methods compared to those obtained by the Fraclab package.

  7. Modified Differential Transform Method for Two Singular Boundary Values Problems

    Directory of Open Access Journals (Sweden)

    Yinwei Lin

    2014-01-01

    Full Text Available This paper deals with the two singular boundary values problems of second order. Two singular points are both boundary values points of the differential equation. The numerical solutions are developed by modified differential transform method (DTM for expanded point. Linear and nonlinear models are solved by this method to get more reliable and efficient numerical results. It can also solve ordinary differential equations where the traditional one fails. Besides, we give the convergence of this new method.

  8. Averaging approximation to singularly perturbed nonlinear stochastic wave equations

    Science.gov (United States)

    Lv, Yan; Roberts, A. J.

    2012-06-01

    An averaging method is applied to derive effective approximation to a singularly perturbed nonlinear stochastic damped wave equation. Small parameter ν > 0 characterizes the singular perturbation, and να, 0 ⩽ α ⩽ 1/2, parametrizes the strength of the noise. Some scaling transformations and the martingale representation theorem yield the effective approximation, a stochastic nonlinear heat equation, for small ν in the sense of distribution.

  9. Classical resolution of black hole singularities via wormholes

    Energy Technology Data Exchange (ETDEWEB)

    Olmo, Gonzalo J. [Universidad de Valencia, Departamento de Fisica Teorica and IFIC, Centro Mixto Universidad de Valencia-CSIC, Valencia (Spain); Universidade Federal da Paraiba, Departamento de Fisica, Joao Pessoa, Paraiba (Brazil); Rubiera-Garcia, D. [Universidade de Lisboa, Faculdade de Ciencias, Instituto de Astrofisica e Ciencias do Espaco, Lisbon (Portugal); Fudan University, Department of Physics, Center for Field Theory and Particle Physics, Shanghai (China); Sanchez-Puente, A. [Universidad de Valencia, Departamento de Fisica Teorica and IFIC, Centro Mixto Universidad de Valencia-CSIC, Valencia (Spain)

    2016-03-15

    In certain extensions of General Relativity, wormholes generated by spherically symmetric electric fields can resolve black hole singularities without necessarily removing curvature divergences. This is shown by studying geodesic completeness, the behavior of time-like congruences going through the divergent region, and by means of scattering of waves off the wormhole. This provides an example of the logical independence between curvature divergences and space-time singularities, concepts very often identified with each other in the literature. (orig.)

  10. Fields generated by sums and products of singular moduli

    OpenAIRE

    Faye, Bernadette; Riffaut, Antonin

    2017-01-01

    We show that the field $\\mathbb{Q}(x,y)$, generated by two singular moduli~$x$ and~$y$, is generated by their sum ${x+y}$, unless~$x$ and~$y$ are conjugate over~$\\mathbb{Q}$, in which case ${x+y}$ generates a subfield of degree at most~$2$. We obtain a similar result for the product of two singular moduli.

  11. Removal of apparent singularity in grid computations

    International Nuclear Information System (INIS)

    Jakubovics, J.P.

    1993-01-01

    A self-consistency test for magnetic domain wall models was suggested by Aharoni. The test consists of evaluating the ratio S = var-epsilon wall /var-epsilon wall , where var-epsilon wall is the wall energy, and var-epsilon wall is the integral of a certain function of the direction cosines of the magnetization, α, β, γ over the volume occupied by the domain wall. If the computed configuration is a good approximation to one corresponding to an energy minimum, the ratio is close to 1. The integrand of var-epsilon wall contains terms that are inversely proportional to γ. Since γ passes through zero at the centre of the domain wall, these terms have a singularity at these points. The integral is finite and its evaluation does not usually present any problems when the direction cosines are known in terms of continuous functions. In many cases, significantly better results for magnetization configurations of domain walls can be obtained by computations using finite element methods. The direction cosines are then only known at a set of discrete points, and integration over the domain wall is replaced by summation over these points. Evaluation of var-epsilon wall becomes inaccurate if the terms in the summation are taken to be the values of the integrand at the grid points, because of the large contribution of points close to where γ changes sign. The self-consistency test has recently been generalised to a larger number of cases. The purpose of this paper is to suggest a method of improving the accuracy of the evaluation of integrals in such cases. Since the self-consistency test has so far only been applied to two-dimensional magnetization configurations, the problem and its solution will be presented for that specific case. Generalisation to three or more dimensions is straight forward

  12. Matrix inequalities

    CERN Document Server

    Zhan, Xingzhi

    2002-01-01

    The main purpose of this monograph is to report on recent developments in the field of matrix inequalities, with emphasis on useful techniques and ingenious ideas. Among other results this book contains the affirmative solutions of eight conjectures. Many theorems unify or sharpen previous inequalities. The author's aim is to streamline the ideas in the literature. The book can be read by research workers, graduate students and advanced undergraduates.

  13. On the singular values decoupling in the Singular Spectrum Analysis of volcanic tremor at Stromboli

    Directory of Open Access Journals (Sweden)

    R. Carniel

    2006-01-01

    Full Text Available The well known strombolian activity at Stromboli volcano is occasionally interrupted by rarer episodes of paroxysmal activity which can lead to considerable hazard for Stromboli inhabitants and tourists. On 5 April 2003 a powerful explosion, which can be compared in size with the latest one of 1930, covered with bombs a good part of the normally tourist-accessible summit area. This explosion was not forecasted, although the island was by then effectively monitored by a dense deployment of instruments. After having tackled in a previous paper the problem of highlighting the timescale of preparation of this event, we investigate here the possibility of highlighting precursors in the volcanic tremor continuously recorded by a short period summit seismic station. We show that a promising candidate is found by examining the degree of coupling between successive singular values that result from the Singular Spectrum Analysis of the raw seismic data. We suggest therefore that possible anomalies in the time evolution of this parameter could be indicators of volcano instability to be taken into account e.g. in a bayesian eruptive scenario evaluator. Obviously, further (and possibly forward testing on other cases is needed to confirm the usefulness of this parameter.

  14. Singular vectors, predictability and ensemble forecasting for weather and climate

    International Nuclear Information System (INIS)

    Palmer, T N; Zanna, Laure

    2013-01-01

    The local instabilities of a nonlinear dynamical system can be characterized by the leading singular vectors of its linearized operator. The leading singular vectors are perturbations with the greatest linear growth and are therefore key in assessing the system’s predictability. In this paper, the analysis of singular vectors for the predictability of weather and climate and ensemble forecasting is discussed. An overview of the role of singular vectors in informing about the error growth rate in numerical models of the atmosphere is given. This is followed by their use in the initialization of ensemble weather forecasts. Singular vectors for the ocean and coupled ocean–atmosphere system in order to understand the predictability of climate phenomena such as ENSO and meridional overturning circulation are reviewed and their potential use to initialize seasonal and decadal forecasts is considered. As stochastic parameterizations are being implemented, some speculations are made about the future of singular vectors for the predictability of weather and climate for theoretical applications and at the operational level. This article is part of a special issue of Journal of Physics A: Mathematical and Theoretical devoted to ‘Lyapunov analysis: from dynamical systems theory to applications’. (review)

  15. Symmetry breaking and singularity structure in Bose-Einstein condensates

    Science.gov (United States)

    Commeford, K. A.; Garcia-March, M. A.; Ferrando, A.; Carr, Lincoln D.

    2012-08-01

    We determine the trajectories of vortex singularities that arise after a single vortex is broken by a discretely symmetric impulse in the context of Bose-Einstein condensates in a harmonic trap. The dynamics of these singularities are analyzed to determine the form of the imprinted motion. We find that the symmetry-breaking process introduces two effective forces: a repulsive harmonic force that causes the daughter trajectories to be ejected from the parent singularity and a Magnus force that introduces a torque about the axis of symmetry. For the analytical noninteracting case we find that the parent singularity is reconstructed from the daughter singularities after one period of the trapping frequency. The interactions between singularities in the weakly interacting system do not allow the parent vortex to be reconstructed. Analytic trajectories were compared to the actual minima of the wave function, showing less than 0.5% error for an impulse strength of v=0.00005. We show that these solutions are valid within the impulse regime for various impulse strengths using numerical integration of the Gross-Pitaevskii equation. We also show that the actual duration of the symmetry-breaking potential does not significantly change the dynamics of the system as long as the strength is below v=0.0005.

  16. Curing Black Hole Singularities with Local Scale Invariance

    Directory of Open Access Journals (Sweden)

    Predrag Dominis Prester

    2016-01-01

    Full Text Available We show that Weyl-invariant dilaton gravity provides a description of black holes without classical space-time singularities. Singularities appear due to the ill behaviour of gauge fixing conditions, one example being the gauge in which theory is classically equivalent to standard General Relativity. The main conclusions of our analysis are as follows: (1 singularities signal a phase transition from broken to unbroken phase of Weyl symmetry; (2 instead of a singularity, there is a “baby universe” or a white hole inside a black hole; (3 in the baby universe scenario, there is a critical mass after which reducing mass makes the black hole larger as viewed by outside observers; (4 if a black hole could be connected with white hole through the “singularity,” this would require breakdown of (classical geometric description; (5 the singularity of Schwarzschild BH solution is nongeneric and so it is dangerous to rely on it in deriving general results. Our results may have important consequences for resolving issues related to information loss puzzle. Though quantum effects are still crucial and may change the proposed classical picture, a position of building quantum theory around essentially regular classical solutions normally provides a much better starting point.

  17. On new bulk singularity structures, RR couplings in the asymmetric picture and their all order α{sup '} corrections

    Energy Technology Data Exchange (ETDEWEB)

    Hatefi, Ehsan [Queen Mary University of London, Centre for Research in String Theory, School of Physics and Astronomy, London (United Kingdom); TU Wien, Institute for Theoretical Physics, Vienna (Austria)

    2017-08-15

    We have analyzed in detail four and five point functions of the string theory amplitudes, including a closed string Ramond-Ramond (RR) in an asymmetric picture and either two or three transverse scalar fields in both IIA and IIB. The complete forms of these S-matrices are derived and these asymmetric S-matrices are also compared with their own symmetric results. This leads us to explore two different kinds of bulk singularity structures as well as various new couplings in the asymmetric picture of the amplitude in type II string theory. All order α{sup '} higher derivative corrections to these new couplings have been discovered as well. Several remarks for these two new bulk singularity structures and for contact interactions of the S-matrix have also been made. (orig.)

  18. On new bulk singularity structures, RR couplings in the asymmetric picture and their all order α ' corrections

    Science.gov (United States)

    Hatefi, Ehsan

    2017-08-01

    We have analyzed in detail four and five point functions of the string theory amplitudes, including a closed string Ramond-Ramond (RR) in an asymmetric picture and either two or three transverse scalar fields in both IIA and IIB. The complete forms of these S-matrices are derived and these asymmetric S-matrices are also compared with their own symmetric results. This leads us to explore two different kinds of bulk singularity structures as well as various new couplings in the asymmetric picture of the amplitude in type II string theory. All order α ' higher derivative corrections to these new couplings have been discovered as well. Several remarks for these two new bulk singularity structures and for contact interactions of the S-matrix have also been made.

  19. Geometric Desingularization of a Cusp Singularity in Slow-Fast Systems with Applications to Zeeman's Examples

    NARCIS (Netherlands)

    Broer, Henk W.; Kaper, Tasso J.; Krupa, Martin

    2013-01-01

    The cusp singularity-a point at which two curves of fold points meet-is a prototypical example in Takens' classification of singularities in constrained equations, which also includes folds, folded saddles, folded nodes, among others. In this article, we study cusp singularities in singularly

  20. Convex nonnegative matrix factorization with manifold regularization.

    Science.gov (United States)

    Hu, Wenjun; Choi, Kup-Sze; Wang, Peiliang; Jiang, Yunliang; Wang, Shitong

    2015-03-01

    Nonnegative Matrix Factorization (NMF) has been extensively applied in many areas, including computer vision, pattern recognition, text mining, and signal processing. However, nonnegative entries are usually required for the data matrix in NMF, which limits its application. Besides, while the basis and encoding vectors obtained by NMF can represent the original data in low dimension, the representations do not always reflect the intrinsic geometric structure embedded in the data. Motivated by manifold learning and Convex NMF (CNMF), we propose a novel matrix factorization method called Graph Regularized and Convex Nonnegative Matrix Factorization (GCNMF) by introducing a graph regularized term into CNMF. The proposed matrix factorization technique not only inherits the intrinsic low-dimensional manifold structure, but also allows the processing of mixed-sign data matrix. Clustering experiments on nonnegative and mixed-sign real-world data sets are conducted to demonstrate the effectiveness of the proposed method. Copyright © 2014 Elsevier Ltd. All rights reserved.