Effect of grain refinement by severe plastic deformation on the next-neighbor misorientation distribution

International Nuclear Information System (INIS)

Toth, L.S.; Beausir, B.; Gu, C.F.; Estrin, Y.; Scheerbaum, N.; Davies, C.H.J.

2010-01-01

Next-neighbor misorientation distributions (NNMD) in severely deformed polycrystalline materials are commonly measured by orientation imaging. A procedure is proposed which enables the separation of NNMD of ultrafine-grained materials into two parts: the distribution of misorientations between newly emerged grains within the original ('parent') grain interior ('internal daughter grains') and the distribution of misorientations between grains adjacent to an original grain boundary on its opposite sides ('grain boundary daughter grains'). The procedure is based on electron backscatter diffraction orientation map analyses carried out on different planes of deformed samples considering the evolution of the grain size and shape during severe plastic deformation. It was applied to copper processed by up to three passes of equal-channel angular pressing. A characteristic feature of the measured NNMD is the occurrence of a double peak, which is clearly due to the differences between the NNMD of the two distinct populations of new grains defined above. The peak at low angles represents mainly the continual grain subdivision process in the interior of a parent grain (and is associated with internal daughter grains), while the peak at large angles is due to the high angle misorientations of the grain boundary daughter grains.

Behavior of Goss, {411}<148>, and {111}<112> Oriented Grains During Recrystallization and Decarburization After Cold-rolling of Fe-3.1% GrainOriented Electrical Steel

Energy Technology Data Exchange (ETDEWEB)

Choi, Sung-Ji; Park, No-Jin [Kumoh National Institute of Technology, Gumi (Korea, Republic of); Joo, Hyung-Don; Park, Jong-Tae [POSCO, Pohang (Korea, Republic of)

2016-07-15

Grain-oriented electrical steel is used as a core material in transformers and motors. To obtain improved magnetic properties from the grain-oriented electrical steel, the steel should have a strong {110}<001> Goss texture. Recently, controlled manufacturing processes have been employed for developing electrical steels with a strong Goss texture. It is important to carry out research on the {411}<148> and {111}<112> oriented grains in relation to coincidence site lattice (CSL) boundaries, as they have an effect on the easy growth of the Goss grains upon secondary recrystallization. In this study, the behavior of the{411}<148> and {111}<112> oriented grains, which are neighbored with Goss grains after recrystallization with rapid and typical heating rates, and after decarburization, was examined by using x-ray diffraction (XRD) and electron back-scattered diffraction (EBSD) measurements. In the decarburized specimen, the Goss grains encroached the {411}<148> and {111}<112> oriented grains to a greater extent with a rapid heating rate than with a typical heating rate, and larger Goss grains were observed with the rapid heating rate. The {111}<112> oriented grains especially affect the easy growth of the Goss grains, as they are located near the Goss grains. Therefore, larger Goss grains can be produced at rapid heating rates, and the product is estimated to exhibit improved magnetic properties after secondary recrystallization.

Mechanism of secondary recrystallization of Goss grains in grain-oriented electrical steel

Science.gov (United States)

Hayakawa, Yasuyuki

2017-12-01

Since its invention by Goss in 1934, grain-oriented (GO) electrical steel has been widely used as a core material in transformers. GO exhibits a grain size of over several millimeters attained by secondary recrystallization during high-temperature final batch annealing. In addition to the unusually large grain size, the crystal direction in the rolling direction is aligned with , which is the easy magnetization axis of α-iron. Secondary recrystallization is the phenomenon in which a certain very small number of {110} (Goss) grains grow selectively (about one in 106 primary grains) at the expense of many other primary recrystallized grains. The question of why the Goss orientation is exclusively selected during secondary recrystallization has long been a main research subject in this field. The general criterion for secondary recrystallization is a small and uniform primary grain size, which is achieved through the inhibition of normal grain growth by fine precipitates called inhibitors. This paper describes several conceivable mechanisms of secondary recrystallization of Goss grains mainly based on the selective growth model.

Relative effect(s) of texture and grain size on magnetic properties in a low silicon non-grain oriented electrical steel

International Nuclear Information System (INIS)

PremKumar, R.; Samajdar, I.; Viswanathan, N.N.; Singal, V.; Seshadri, V.

2003-01-01

Hot rolled low Si (silicon) non-grain oriented electrical steel was cold rolled to different reductions. Cold rolled material was subsequently recrystallized, 650 deg. C and 2 h, and then temper rolled (to 7% reduction) for the final grain growth annealing and decarburization treatment at 850 deg. C for 2-24 h. The development of texture, grain size and magnetic properties were characterized at different stages of processing. Effect of texture on magnetic properties (watt loss and permeability) was observed to be best represented by the ratio of volume fractions of (1 1 1) /(0 0 1) fibers, as estimated by convoluting X-ray ODFs (orientation distribution functions) with respective model functions. Such a ratio was termed as generalized texture factor (tf) for the non-grain oriented electrical steel. An effort was made to delink effects of grain size and texture, as represented by respective tf, on watt loss and permeability by careful analysis of experimental data. In general, low tf and/or high grain size were responsible for low watt loss and high permeability. However, individual effect of grain size or tf on magnetic properties was less significant at low tf or large grain size, respectively. An attempt was made to fit regression equations, namely--linear, exponential and power, relating magnetic properties with tf and grain size, limiting the fitting parameters to 3. Least standard deviations, between experimental and predicted values, were obtained by power regression equations for both magnetic properties

Correlation between grain orientation and the shade of color etching

International Nuclear Information System (INIS)

Szabo, Peter J.; Kardos, I.

2010-01-01

Color etching is an extremely effective metallographic technique not only for making grains well visible, but also for making them distinguishable for automated image analyzers. During color etching, a thin film is formed on the surface of the specimen. The thickness of this layer is in the order of magnitude of the visible light and since both the metal-film boundary and the film surface reflect light, an interference occurs. A wavelength-component of the white line is eliminated and its complementary color will be seen on the surface. As the thickness changes, the colors also change grain by grain. The thickness of the film is dependent on several factors, mostly on the type of the phase. However, different color shades can be observed on the surfaces of single phase materials, which phenomenon is caused by the different crystallographic orientations of the grains. This paper shows a combined color etching electron backscatter diffraction (EBSD) investigation of cast iron. An area of the surface of a gray cast iron specimen was etched. Colors were characterized by their luminescence and their red, green and blue intensity. An EBSD orientation map was taken from the same area and the orientations of the individual grains were determined. Results showed that a strong correlation was found between the luminescence and the R, G, B intensity of the color and the angle between the specimen normal and the direction, while such correlation was not observed between the color parameters and the and directions, respectively. This indicates that film thickness is sensitive to the direction of the crystal.

Effect of texture on grain boundary misorientation distributions in polycrystalline high temperature superconductors

International Nuclear Information System (INIS)

Goyal, A.; Specht, E.D.; Kroeger, D.M.; Mason, T.A.

1996-01-01

Computer simulations were performed to determine the most probable grain boundary misorientation distribution (GBMD) in model polycrystalline superconductors. GBMDs in polycrystalline superconductors can be expected to dictate the macroscopic transport critical current density, J c . Calculations were performed by simulating model polycrystals and then determining the GBMD. Such distributions were calculated for random materials having cubic, tetragonal, and orthorhombic crystal symmetry. In addition, since most high temperature superconductors are tetragonal or pseudotetragonal, the effect of macroscopic uniaxial and biaxial grain orientation texture on the GBMD was determined for tetragonal materials. It is found that macroscopic texture drastically alters the grain boundary misorientation distribution. The fraction of low angle boundaries increases significantly with uniaxial and biaxial texture. The results of this study are important in correlating the macroscopic transport J c with the measured grain orientation texture as determined by x-ray diffraction copyright 1996 American Institute of Physics

Grain orientation, deformation microstructure and flow stress

International Nuclear Information System (INIS)

Hansen, N.; Huang, X.; Winther, G.

2008-01-01

Dislocation structures in deformed metals have been analyzed quantitatively by transmission electron microscopy, high-resolution electron microscopy and Kikuchi line analysis. A general pattern for the microstructural evolution with increasing strain has been established and structural parameters have been defined and quantified. It has been found that two dislocation patterns co-exist in all grains, however, with very different characteristics dependent on grain orientation. This correlation with the grain orientation has been applied in modeling of the tensile flow stress and the flow stress anisotropy of fcc polycrystals. In conclusion some future research areas are briefly outlined

Investigation of grain competitive growth during directional solidification of single-crystal nickel-based superalloys

Energy Technology Data Exchange (ETDEWEB)

Zhao, Xinbao [National Energy R and D Center of Clean and High-Efficiency Fossil-Fired Power Generation Technology, Xi' an Thermal Power Research Institute Co. Ltd., Xi' an (China); Northwestern Polytechnical University, State Key Laboratory of Solidification Processing, Xi' an (China); Liu, Lin; Zhang, Jun [Northwestern Polytechnical University, State Key Laboratory of Solidification Processing, Xi' an (China)

2015-08-15

Grain competitive growth of nickel-based single-crystal superalloys during directional solidification was investigated. A detailed characterization of bi-crystals' competitive growth was performed to explore the competitive grain evolution. It was found that high withdrawal rate improved the efficiency of grain competitive growth. The overgrowth rate was increased when the misorientation increased. Four patterns of grain competitive growth with differently oriented dispositions were characterized. The results indicated that the positive branching of the dendrites played a significant role in the competitive growth process. The effect of crystal orientation and heat flow on the competitive growth can be attributed to the blocking mechanism between the adjacent grains. (orig.)

The spatial distribution of microfabric around gravel grains: indicator of till formation processes

Science.gov (United States)

KalväNs, Andis; Saks, Tomas

2010-05-01

Till micromorphology studies in thin sections is an established tool in the field of glacial geology. Often the thin sections are inspected only visually with help of mineralogical microscope. This can lead to subjective interpretation of observed structures. More objective method used in till micromorphology is measurement of apparent microfabric, usually seen as preferred orientation of elongated sand grains. In theses studies only small fraction of elongated sand grains often confined to small area of thin section usually are measured. We present a method for automated measurement of almost all elongated sand grains across the full area of the thin section. Apparently elongated sand grains are measured using simple image analysis tools, the data are processed in a way similar to regular till fabric data and visualised as a grid of rose diagrams. The method allows to draw statistical information about spatial variation of microfabric preferred orientation and fabric strength with resolution as fine as 1 mm. Late Weichselian tills from several sites in Western Latvia were studied and large variations in fabric strength and spatial distribution were observed in macroscopically similar till units. The observed types of microfabric spatial distributions include strong, monomodal and uniform distribution; weak and highly variable in small distances distribution; consistently bimodal distribution and domain-like pattern of preferred sand grain orientation. We suggest that the method can be readily used to identify the basic deformation and sedimentation processes active during the final stages of till formation. It is understood that the microfabric orientation will be significant affected by nearby large particles. The till is highly heterogonous sediment and the source of microfabric perturbations observed in thin section might lie outside the section plane. Therefore we suggest that microfabric distribution around visible sources of perturbation - gravel grains cut

The origin of dose distributions in fluvial sediments, and the prospect of dating single grains from fluvial deposits using optically stimulated luminescence

International Nuclear Information System (INIS)

Olley, J.M.; Caitcheon, G.G.; Roberts, R.G.

1999-01-01

We examine the causes of the asymmetric distributions of dose observed from measurements of the optically stimulated luminescence emitted by small aliquots of fluvial quartz, and deduce that the asymmetry arises as a result of samples being composed of a mix of mainly well bleached grains with grains that were effectively unbleached at the time of deposition. We demonstrate that the shapes of the dose distributions can be used to assess the likelihood that aliquots consist only of grains that were well-bleached at the time of deposition. The more asymmetric the distribution, the greater the probability that the aliquots with the lowest dose most closely represent the true burial dose. Single grains with differing doses are present in each of the samples examined, and the population with the lowest dose gives an optical age consistent with the expected burial age. This result implies that the beta-dose heterogeneity in these deposits is small, and that the effects of micro-dosimetric variations on optical dating of individual grains are not significant for these samples. We demonstrate that single-grain dating of fluvial material is possible and practicable using standard Risoe optical dating equipment, and we conclude that application of a new regenerative-dose protocol to single grains of quartz, using the lowest dose population to estimate the burial dose, is the best available means of obtaining reliable luminescence ages for heterogeneously bleached fluvial sediments

Grain orientation and strain measurements in sub-micron wide passivated individual aluminum test structures

International Nuclear Information System (INIS)

Tamura, N.; Valek, B.C.; Spolenak, R.; MacDowell, A.A.; Celestre, R.S.; Padmore, H.A.; Brown, W.L.; Marieb, T.; Bravman, J.C.; Batterman, B.W.; Patel, J.R.

2001-01-01

An X-ray microdiffraction dedicated beamline, combining white and monochromatic beam capabilities, has been built at the Advanced Light Source. The purpose of this beamline is to address the myriad of problems in Materials Science and Physics that require submicron x-ray beams for structural characterization. Many such problems are found in the general area of thin films and nano-materials. For instance, the ability to characterize the orientation and strain state in individual grains of thin films allows us to measure structural changes at a very local level. These microstructural changes are influenced heavily by such parameters as deposition conditions and subsequent treatment. The accurate measurement of strain gradients at the micron and sub-micron level finds many applications ranging from the strain state under nano-indenters to gradients at crack tips. Undoubtedly many other applications will unfold in the future as we gain experience with the capabilities and limitations of this instrument. We have applied this technique to measure grain orientation and residual stress in single grains of pure Al interconnect lines and preliminary results on post-electromigration test experiments are presented. It is shown that measurements with this instrument can be used to resolve the complete stress tensor (6 components) in a submicron volume inside a single grain of Al under a passivation layer with an overall precision of about 20 MPa. The microstructure of passivated lines appears to be complex, with grains divided into identifiable subgrains and noticeable local variations of both tensile/compressive and shear stresses within single grains

Grain orientation mapping of passivated aluminum interconnect wires with X-ray micro-diffraction

International Nuclear Information System (INIS)

MacDowell, A.A.; Padmore, H.A.; Thompson, A.C.; Chang, C.H.; Patel, J.R.

1998-06-01

A micro x-ray diffraction facility is under development at the Advanced Light source. Spot sizes are typically about 1-microm size generated by means of grazing incidence Kirkpatrick-Baez focusing mirrors. Photon energy is either white of energy range 6--14 keV or monochromatic generated from a pair of channel cut crystals. A Laue diffraction pattern from a single grain in passivated 2-microm wide bamboo structured Aluminum interconnect line has been recorded. Acquisition times are of the order of a few seconds. The Laue pattern has allowed the determination of the crystallographic orientation of individual grains along the line length. The experimental and analysis procedures used are described, as is a grain orientation result. The future direction of this program is discussed in the context of strain measurements in the area of electromigration

Growth of single crystalline seeds into polycrystalline strontium titanate: Anisotropy of the mobility, intrinsic drag effects and kinetic shape of grain boundaries

International Nuclear Information System (INIS)

Rheinheimer, Wolfgang; Bäurer, Michael; Handwerker, Carol A.; Blendell, John E.; Hoffmann, Michael J.

2015-01-01

We present a suite of measurements and combined analyses of grain growth in SrTiO 3 for oriented single crystals into polycrystals. The growth distance and standard deviation and the microstructure evolution along the single crystal–matrix interface are used to locally characterize the change in migration behavior as a function of temperature, time and interface orientation. The relative grain boundary mobility was determined between 1250 °C and 1600 °C for four crystallographic orientations {1 0 0}, {1 1 0}, {1 1 1} and {3 1 0}. An absolute mobility of these orientations is estimated. Under fast growth conditions the morphology of single crystals shows macroscopic stepping with parts of the interface rotating to low mobility orientations. This effect represents a kinetic influence on the grain boundary morphology. The results also indicate dragging effects on microstructure coarsening, which indicate the existence of a critical driving force for grain growth. This critical driving force seems to be related to an ‘intrinsic’ interface drag similar to the solute drag, but based on intrinsic defects. At 1460 °C the growth of single crystals was significantly faster than expected from the mobility of the polycrystal and was identified as exaggerated grain growth. The findings give new insights into the recently published grain growth anomaly of strontium titanate, leading to a hypothesis based on the temperature dependent relative mobility of {1 0 0} oriented grain boundaries

Bleaching of the post-IR IRSL signal from individual grains of K-feldspar: Implications for single-grain dating

International Nuclear Information System (INIS)

Smedley, R.K.; Duller, G.A.T.; Roberts, H.M.

2015-01-01

Post-IR IRSL (pIRIR) signals from K-feldspar grains measured at elevated temperatures are increasingly being used for dating sediments. Unfortunately the pIRIR signal from K-feldspars bleaches more slowly than other signals (e.g. OSL from quartz) upon exposure to daylight, leading to concerns about residual signals remaining at deposition. However, earlier studies have not assessed whether the pIRIR signal bleaches at the same rate in all feldspar grains. In this study laboratory bleaching experiments have been conducted and for the first time the results show that the rate at which the pIRIR signal from individual K-feldspar grains bleach varies. To determine whether grain-to-grain variability in bleaching rate has a dominant control on equivalent dose (D e ) distributions determined using single grains, analysis was undertaken on three samples with independent age control from different depositional environments (two aeolian and one glaciofluvial). The D e value determined from each grain was compared with the rate at which the pIRIR 225 signal from the grain bleaches. The bleaching rate of each grain was assessed by giving a 52 Gy dose and measuring the residual D e after bleaching for an hour in a solar simulator. There is no clear relationship between the rate at which the pIRIR 225 signal of an individual grain bleaches and the magnitude of its D e . It is concluded that variability in the bleaching rate of the pIRIR 225 signal from one grain to another does not appear to be a dominant control on single grain D e distributions. - Highlights: • The bleaching rate of the pIRIR signal from single K-feldspar grains was assessed. • The pIRIR 225 signal bleaches more rapidly than the pIRIR 290 signal. • pIRIR 225 and pIRIR 290 signals reach the same level after 4–20 h of bleaching. • The bleaching rate of the pIRIR signal varies from one grain to another. • Variable pIRIR bleaching rates do not control single-grain D e distributions

High-Resolution Single-Grain Diffraction of Polycrystalline Materials

DEFF Research Database (Denmark)

Lienert, Ulrich; Ribárik, Gábor; Ungar, Tamas

2017-01-01

. The microstructure usually influences the materials properties critically. It has been demonstrated that, by using high-energy synchrotron radiation, diffraction peaks off individual grains can be recorded in-situ during processing. Important information such as the orientation, average strain, and size...... of individual grains can be obtained, even if the peak shapes are commonly not analyzed. However, it is also well-known that the shape of diffraction peaks, if observed with sufficient resolution, contains significant information about the microstructure. While the intensity distribution in reciprocal space...... of a perfect lattice consists of delta functions located at the reciprocal lattice points, defects induce characteristic peak broadening. In order to exploit the wealth of microstructural information contained in broadened diffraction peaks, the intensity distribution has to be characterized in all three...

Influences of crystallographic orientations on deformation mechanism and grain refinement of Al single crystals subjected to one-pass equal-channel angular pressing

International Nuclear Information System (INIS)

Han, W.Z.; Zhang, Z.F.; Wu, S.D.; Li, S.X.

2007-01-01

The influences of crystallographic orientations on the evolution of dislocation structures and the refinement process of sub-grains in Al single crystals processed by one-pass equal-channel angular pressing (ECAP) were systematically investigated by means of scanning electron microscopy, electron backscatter diffraction and transmission electron microscopy. Three single crystals with different orientations, denoted as crystal I, crystal II and crystal III, were specially designed according to the shape of the ECAP die. For crystal I, its insert direction is parallel to [1 1 0] and its extrusion direction is parallel to [1-bar11]. For crystal II, the (1-bar11) plane is located parallel to the intersection plane of the ECAP die, and the [1 1 0] direction is along the general shear direction on the intersection plane. For crystal III, the (1-bar11) plane is laid on the plane perpendicular to the intersection of the ECAP die, and the [1 1 0] direction is vertical to the general shear direction. For crystal I, abundant cell block structures with multi-slip characters were formed, and they should be induced by four symmetric slip systems, while for crystal II, there are two sets of sub-grain structures with higher misorientation, making an angle of ∼70 deg., which can be attributed to the interactions of the two asymmetric primary slip planes, whereas for crystal III, only one set of ribbon structures was parallel to the traces of (1-bar11) with the lowest misorientation angle among the three single crystals, which should result from the homogeneous slip on the primary slip plane. The different microstructural features of the three single crystals provide clear experimental evidence that the microstructures and misorientation evolution are strongly affected by the crystallographic orientation or by the interaction between shear deformation imposed by the ECAP die and the intrinsic slip deformation of the single crystals. Based on the experimental results and the

Grain orientation mapping of passivated aluminum interconnect lines with X-ray micro-diffraction

International Nuclear Information System (INIS)

Chang, C.H.; Patel, J.R.; MacDowell, A.A.; Padmore, H.A.; Thompson, A.C.

1998-01-01

A micro x-ray diffraction facility is under development at the Advanced Light Source. Spot sizes are typically about 1-microm size generated by means of grazing incidence Kirkpatrick-Baez focusing mirrors. Photon energy is either white of energy range 6--14 keV or monochromatic generated from a pair of channel cut crystals. Laue diffraction pattern from a single grain in a passivated 2-microm wide bamboo structured Aluminum interconnect line has been recorded. Acquisition times are of the order of seconds. The Laue pattern has allowed the determination of the crystallographic orientation of individual grains along the line length. The experimental and analysis procedure used is described, as is the latest grain orientation result. The impact of x-ray micro-diffraction and its possible future direction are discussed in the context of other developments in the area of electromigration, and other technological problems

Grain orientation mapping of passivated aluminum interconnect lines by x-ray micro-diffraction

International Nuclear Information System (INIS)

Chang, C. H.; Patel, J. R.; MacDowell, A. A.; Padmore, H. A.; Thompson, A. C.

1998-01-01

A micro x-ray diffraction facility is under development at the Advanced Light Source. Spot sizes are typically about 1-μm size generated by means of grazing incidence Kirkpatrick-Baez focusing mirrors. Photon energy is either white of energy range 6-14 keV or monochromatic generated from a pair of channel cut crystals. Laue diffraction pattern from a single grain in a passivated 2-μm wide bamboo structured Aluminum interconnect line has been recorded. Acquisition times are of the order of seconds. The Laue pattern has allowed the determination of the crystallographic orientation of individual grains along the line length. The experimental and analysis procedure used is described, as is the latest grain orientation result. The impact of x-ray micro-diffraction and its possible future direction are discussed in the context of other developments in the area of electromigration, and other technological problems

Single-grain dating of young sediments using the pIRIR signal from feldspar

DEFF Research Database (Denmark)

Reimann, Tony; Thomsen, Kristina Jørkov; Jain, Mayank

2012-01-01

In this article we test for the first time the potential of single-grains of K-rich feldspar to date well-bleached and poorly bleached sediments using a post-IR IRSL (pIRIR) protocol. We measure natural dose distributions using K-rich feldspars from four coastal samples applying the pIRIR protocol.......5%.The analysis of the well-bleached samples shows that only the brightest 30% of the grains give pIRIR single-grain ages in agreement with the age control; this effect may arise from the suggested correlation between blue emission and potassium content of individual grains. Comparison of single......-grain quartz and feldspar dose distributions from the poorly bleached samples shows that quartz is relatively better bleached; nevertheless, selection of a reliable ‘minimum’ feldspar dose was achieved using two different statistical models....

Diffraction-amalgamated grain boundary tracking for mapping 3D crystallographic orientation and strain fields during plastic deformation

International Nuclear Information System (INIS)

Toda, Hiroyuki; Kamiko, Takanobu; Tanabe, Yasuto; Kobayashi, Masakazu; Leclere, D.J.; Uesugi, Kentaro; Takeuchi, Akihisa; Hirayama, Kyosuke

2016-01-01

By amalgamating the X-ray diffraction technique with the grain boundary tracking technique, a novel method, diffraction-amalgamated grain boundary tracking (DAGT), has been developed. DAGT is a non-destructive in-situ analysis technique for characterising bulk materials, which can be applied up to near the point of fracture. It provides information about local crystal orientations and detailed grain morphologies in three dimensions, together with high-density strain mapping inside grains. As it obtains the grain morphologies by utilising X-ray imaging instead of X-ray diffraction, which latter is typically vulnerable to plastic deformation, DAGT is a fairly robust technique for analysing plastically deforming materials. Texture evolution and localised deformation behaviours have here been successfully characterised in Al–Cu alloys, during tensile deformation of 27% in applied strain. The characteristic rotation behaviours of grains were identified, and attributed to the effects of interaction with adjacent grains on the basis of the 3D local orientation and plastic strain distributions. It has also been revealed that 3D strain distribution in grains is highly heterogeneous, which is not explained by known mechanisms such as simple incompatibility with adjacent grains or strain percolation through soft grains. It has been clarified that groups consisting of a few adjacent grains may deform coordinately, especially in shear and lateral deformation, and the characteristic deformation pattern is thereby formed on a mesoscopic scale.

The Role of Grain Orientation and Grain Boundary Characteristics in the Mechanical Twinning Formation in a High Manganese Twinning-Induced Plasticity Steel

Science.gov (United States)

Shterner, Vadim; Timokhina, Ilana B.; Rollett, Anthony D.; Beladi, Hossein

2018-04-01

In the current study, the dependence of mechanical twinning on grain orientation and grain boundary characteristics was investigated using quasi in-situ tensile testing. The grains of three main orientations (i.e., , , and parallel to the tensile axis (TA)) and certain characteristics of grain boundaries (i.e., the misorientation angle and the inclination angle between the grain boundary plane normal and the TA) were examined. Among the different orientations, and were the most and the least favored orientations for the formation of mechanical twins, respectively. The orientation was intermediate for twinning. The annealing twin boundaries appeared to be the most favorable grain boundaries for the nucleation of mechanical twinning. No dependence was found for the inclination angle of annealing twin boundaries, but the orientation of grains on either side of the annealing twin boundary exhibited a pronounced effect on the propensity for mechanical twinning. Annealing twin boundaries adjacent to high Taylor factor grains exhibited a pronounced tendency for twinning regardless of their inclination angle. In general, grain orientation has a significant influence on twinning on a specific grain boundary.

Simulation and Experimental Studies on Grain Selection and Structure Design of the Spiral Selector for Casting Single Crystal Ni-Based Superalloy.

Science.gov (United States)

Zhang, Hang; Xu, Qingyan

2017-10-27

Grain selection is an important process in single crystal turbine blades manufacturing. Selector structure is a control factor of grain selection, as well as directional solidification (DS). In this study, the grain selection and structure design of the spiral selector were investigated through experimentation and simulation. A heat transfer model and a 3D microstructure growth model were established based on the Cellular automaton-Finite difference (CA-FD) method for the grain selector. Consequently, the temperature field, the microstructure and the grain orientation distribution were simulated and further verified. The average error of the temperature result was less than 1.5%. The grain selection mechanisms were further analyzed and validated through simulations. The structural design specifications of the selector were suggested based on the two grain selection effects. The structural parameters of the spiral selector, namely, the spiral tunnel diameter ( d w ), the spiral pitch ( h b ) and the spiral diameter ( h s ), were studied and the design criteria of these parameters were proposed. The experimental and simulation results demonstrated that the improved selector could accurately and efficiently produce a single crystal structure.

Giant piezoelectric voltage coefficient in grain-oriented modified PbTiO3 material.

Science.gov (United States)

Yan, Yongke; Zhou, Jie E; Maurya, Deepam; Wang, Yu U; Priya, Shashank

2016-10-11

A rapid surge in the research on piezoelectric sensors is occurring with the arrival of the Internet of Things. Single-phase oxide piezoelectric materials with giant piezoelectric voltage coefficient (g, induced voltage under applied stress) and high Curie temperature (T c ) are crucial towards providing desired performance for sensing, especially under harsh environmental conditions. Here, we report a grain-oriented (with 95% texture) modified PbTiO 3 ceramic that has a high T c (364 °C) and an extremely large g 33 (115 × 10 -3  Vm N -1 ) in comparison with other known single-phase oxide materials. Our results reveal that self-polarization due to grain orientation along the spontaneous polarization direction plays an important role in achieving large piezoelectric response in a domain motion-confined material. The phase field simulations confirm that the large piezoelectric voltage coefficient g 33 originates from maximized piezoelectric strain coefficient d 33 and minimized dielectric permittivity ɛ 33 in [001]-textured PbTiO 3 ceramics where domain wall motions are absent.

The origin of dose distributions in fluvial sediments, and the prospect of dating single grains from fluvial deposits using optically stimulated luminescence

CERN Document Server

Olley, J M; Roberts, R G

1999-01-01

We examine the causes of the asymmetric distributions of dose observed from measurements of the optically stimulated luminescence emitted by small aliquots of fluvial quartz, and deduce that the asymmetry arises as a result of samples being composed of a mix of mainly well bleached grains with grains that were effectively unbleached at the time of deposition. We demonstrate that the shapes of the dose distributions can be used to assess the likelihood that aliquots consist only of grains that were well-bleached at the time of deposition. The more asymmetric the distribution, the greater the probability that the aliquots with the lowest dose most closely represent the true burial dose. Single grains with differing doses are present in each of the samples examined, and the population with the lowest dose gives an optical age consistent with the expected burial age. This result implies that the beta-dose heterogeneity in these deposits is small, and that the effects of micro-dosimetric variations on optical dati...

Methods of assessing grain-size distribution during grain growth

DEFF Research Database (Denmark)

Tweed, Cherry J.; Hansen, Niels; Ralph, Brian

1985-01-01

This paper considers methods of obtaining grain-size distributions and ways of describing them. In order to collect statistically useful amounts of data, an automatic image analyzer is used, and the resulting data are subjected to a series of tests that evaluate the differences between two related...... distributions (before and after grain growth). The distributions are measured from two-dimensional sections, and both the data and the corresponding true three-dimensional grain-size distributions (obtained by stereological analysis) are collected. The techniques described here are illustrated by reference...

Grain interaction mechanisms leading to intragranular orientation spread in tensile deformed bulk grains of interstitial-free steel

DEFF Research Database (Denmark)

Winther, Grethe; Wright, Jonathan P.; Schmidt, Søren

2017-01-01

environments representing the bulk texture, yet their deformation-induced rotations are very different. The ALAMEL model is employed to analyse the grain interaction mechanisms. Predictions of this model qualitatively agree with the directionality and magnitude of the experimental orientation spread. However......, quantitative agreement requires fine-tuning of the boundary conditions. The majority of the modelled slip is accounted for by four slip systems also predicted to be active by the classical Taylor model in uniaxial tension, and most of the orientation spread along the grain boundaries is caused by relative...... variations in the activities of these. Although limited to two grains, the findings prove that shear at the grain boundaries as accounted for by the ALAMEL model is a dominant grain interaction mechanism....

Microstructure Control of Barium Titanate Grain-oriented Ceramics and Their Piezoelectric Properties

International Nuclear Information System (INIS)

Mori, Rintaro; Nakashima, Koichi; Fujii, Ichiro; Wada, Satoshi; Hayashi, Hiroshi; Nagamori, Yoshitaka; Yamamoto, Yuichi

2011-01-01

The Barium titanate (BaTiO 3 , BT) [110] grain-oriented ceramics along [110] direction were prepared by a templated grain growth (TGG) method. The [110] oriented BT platelike particles (t-BT) were used as template particles. The relationship between poling treatment program and piezoelectric constant was investigated. The change in the poling conditions did not greatly influence domain size and the piezoelectric constant. The relationship between piezoelectric properties and domain size in BT grain-oriented ceramics was investigated. The smaller domain size was required to increase the piezoelectric constant.

Characterizing Grain-Oriented Silicon Steel Sheet Using Automated High-Resolution Laue X-ray Diffraction

Science.gov (United States)

Lynch, Peter; Barnett, Matthew; Stevenson, Andrew; Hutchinson, Bevis

2017-11-01

Controlling texture in grain-oriented (GO) silicon steel sheet is critical for optimization of its magnetization performance. A new automated laboratory system, based on X-ray Laue diffraction, is introduced as a rapid method for large scale grain orientation mapping and texture measurement in these materials. Wide area grain orientation maps are demonstrated for both macroetched and coated GO steel sheets. The large secondary grains contain uniform lattice rotations, the origins of which are discussed.

Processing, microstructure and properties of grain-oriented ferroelectric ceramics

International Nuclear Information System (INIS)

Okazaki, K.; Igarashi, H.; Nagata, K.; Yamamoto, T.; Tashiro, S.

1986-01-01

Grain oriented ferroelectric ceramics such as PbBi/sub 2/Nb/sub 2/O/sub 9/, bismuth compound with layer structure, (PbLa)Nb/sub 2/O/sub 6/, tungsten-bronze structure and SbSI were prepared by an uni-axial hot-pressing, a double-stage hot-pressing and tape casting methods. Microstructures of them were examined by SEM and the prefered textures of the ceramics composed of thin plate and/or needle crystallites were ascertained. Grain orientation effects on electrical, piezoelectric, optical and mechanical properties are discussed

Deformation Mechanism and Recrystallization Relationships in Galfenol Single Crystals: On the Origin of Goss and Cube Orientations

Science.gov (United States)

Na, Suok-Min; Smith, Malcolm; Flatau, Alison B.

2018-06-01

In this work, deformation mechanism related to recrystallization behavior in single-crystal disks of Galfenol (Fe-Ga alloy) was investigated to gain insights into the influence of crystal orientations on structural changes and selective grain growth that take place during secondary recrystallization. We started with the three kinds of single-crystal samples with (011)[100], (001)[100], and (001)[110] orientations, which were rolled and annealed to promote the formation of different grain structures and texture evolutions. The initial Goss-oriented (011)[100] crystal mostly rotated into {111} orientations with twofold symmetry and shear band structures by twinning resulted in the exposure of rolled surface along {001} orientation during rolling. In contrast, the Cube-oriented (001)[100] single crystal had no change in texture during rolling with the thickness reduction up to 50 pct. The {123} slip systems were preferentially activated in these single crystals during deformation as well as {112} slip systems that are known to play a role in primary slip of body-centered cubic (BCC) materials such as α-iron and Fe-Si alloys. After annealing, the deformed Cube-oriented single crystal had a small fraction ( orientation, associated with {123} slip systems as well. This was expected to provide potential sites of nucleation for secondary recrystallization; however, no Goss- and Cube-oriented components actually developed in this sample during secondary recrystallization. Those results illustrated how the recrystallization behavior can be influenced by deformed structure and the slip systems.

Interactive contribution of grain size and grain orientation to coercivity of melt spun ribbons

International Nuclear Information System (INIS)

Wang, N.; Li, G.; Yao, W.J.; Wen, X.X.

2010-01-01

During melt spinning process, the improvement of certain grain orientation and the refinement of grain size with surface velocity have interactive and contradictory effects on the magnetic properties. The contributions of these effects have seldom been taken into account and they were discussed in this paper via Fe-2, 4, 6.5 wt% Si alloys. Heat treatment at 1173 K for 1 h was performed to show the annealing impact. The X-ray diffraction patterns show that the high surface velocity and heat treatment increase the intensity ratio of line (2 0 0) to (1 1 0) of A2 phase. The (2 0 0) line corresponds to (2 0 0) plane in direction, easy magnetization direction of α-Fe phase in Fe-Si alloy. The improvement of this grain orientation with the surface velocity decreases the coercivity, which should increase due to the grain refinement. It is revealed that the texture promoted by the anisotropic heat release during melt spinning process is one factor to improve the magnetic properties and should be considered when preparing soft magnetic materials.

Thermomagnetic Stability in Pseudo Single Domain Grains

Science.gov (United States)

Nagy, Lesleis; Williams, Wyn; Muxworthy, Adrian; Fabian, Karl; Conbhuí, Pádraig Ó.

2016-04-01

The reliability of paleomagnetic remanences are well understood for fine grains of magnetite that are single-domain (SD, uniformly magnetized). In particular Néel's theory [1] outlined the thermal energies required to block and unblock magnetic remanences. This lead to determination of thermal stability for magnetization in fine grains as outlined in Pullaiah et. al. [2] and a comprehensive understanding of SD paleomagnetic recordings. It has been known for some time that single domain magnetite is possible only in the grain size range 30 - 80nm, which may only account for a small fraction of the grain size distribution in any rock sample. Indeed rocks are often dominated by grains in the pseudo single domain (PSD) size range, at approximately 80 - 1000nm. Toward the top end of this range multi-domain features begin to dominate. In order to determine thermomagnetic stability in PSD grains we need to identify the energy barriers between all possible pairs of local energy minima (LEM) domain states as a function of both temperature and grain size. We have attempted to do this using the nudged elastic band (NEB) method [3] which searches for minimum energy paths between any given pair of LEM states. Using this technique we have determined, for the first time, complete thermomagnetic stability curves for PSD magnetite. The work presented is at a preliminary stage. However it can be shown that PSD grains of magnetite with simple geometries (e.g. cubes or cuboctahedra) have very few low energy transition paths and the stability is likely to be similar to that observed for SD grains (as expected form experimental observations). The results will provide a basis for a much more rigorous understanding of the fidelity of paleomagnetic signals in assemblages of PSD grains and their ability to retain ancient recordings of the geomagnetic field. References: [1] Néel, Louis. "Théorie du traînage magnétique des ferromagnétiques en grains fins avec applications aux terres

Comparison of single-grain and small-aliquot OSL dose estimates in < 3000 years old river sediments from South India

DEFF Research Database (Denmark)

Thomas, P.J.; Jain, M.; Juyal, N.

2005-01-01

We report on OSL dose distributions derived from small-aliquot and single grains of quartz in young fluvial sediments sampled from the Penner River basin, South India. The single-grain dose distributions suggest that 13 out of 19 samples were well bleached. In many well-bleached samples, there wa......We report on OSL dose distributions derived from small-aliquot and single grains of quartz in young fluvial sediments sampled from the Penner River basin, South India. The single-grain dose distributions suggest that 13 out of 19 samples were well bleached. In many well-bleached samples......, there was an underestimation in the single-aliquot dose estimates as compared to those from the single grain-the difference between average dose estimates determined by the two methods ranged from similar to 1% to 31%. Such a dose underestimation was not detectable in poorly bleached samples. Various possible reasons...... perhaps be one of the reasons; this may occur because the stimulation wavelength affects the proportion of the medium and slow components in the initial signal. (c) 2004 Elsevier Ltd. All rights reserved....

Orientation-dependent evolution of the dislocation density in grain populations with different crystallographic orientations relative to the tensile axis in a polycrystalline aggregate of stainless steel

International Nuclear Information System (INIS)

Ungár, Tamás; Stoica, Alexandru D.; Tichy, Géza; Wang, Xun-Li

2014-01-01

Line profile analysis was carried out on neutron diffraction patterns collected by the energy-dispersive method for an in situ tensile-deformed AISI-316 stainless steel specimen. The experiments were carried out at the VULCAN engineering beam line of the spallation neutron source of the Oak Ridge National Laboratory. Both the dislocation densities and the local stresses in grains oriented with different h k l crystal directions along the tensile axis were determined. The work-hardening equation of Taylor was tested for the h k l-dependent phenomenological constant α. The grain-orientation-dependent α values were directly related to the heterogeneity of dislocation distribution in correlation with previous transmission electron microscopy data

Practical considerations in the calculation of orientation distribution functions from electron back-scattered diffraction patterns

International Nuclear Information System (INIS)

Bowen, A.W.

1994-01-01

Using model data sets for the Brass orientation, the importance of scatter width, angular accuracy and grain size and volume fraction on the sensitivity of the calculated Orientation Distribution Functions have been determined in order to highlight some of the practical considerations needed in the processing of experimental data from individual grain orientation measurements determined by the Electron Back-Scattered Diffraction technique. It is suggested that the most appropriate scatter width can be calculated from the maximum function height versus scatter width curve in order to accommodate variations in texture sharpness. The sensitivity of the ODF to careful sample preparation, mounting and pattern analysis, in order to keep errors in angular accuracy to 1 or less is demonstrated, as is the imperative need to correct for the size of grains, and their volume fractions. (orig.)

THE EFFECTS OF GRAIN SIZE AND TEMPERATURE DISTRIBUTIONS ON THE FORMATION OF INTERSTELLAR ICE MANTLES

Energy Technology Data Exchange (ETDEWEB)

Pauly, Tyler; Garrod, Robin T., E-mail: tap74@cornell.edu [Cornell Center for Astrophysics and Planetary Science, Cornell University, Ithaca, NY 14853-6801 (United States)

2016-02-01

Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the effects of a broad grain-size distribution on the chemistry of dust-grain surfaces and the subsequent build-up of molecular ices on the grains, using a three-phase gas-grain chemical model of a quiescent dark cloud. We include an explicit treatment of the grain temperatures, governed both by the visual extinction of the cloud and the size of each individual grain-size population. We find that the temperature difference plays a significant role in determining the total bulk ice composition across the grain-size distribution, while the effects of geometrical differences between size populations appear marginal. We also consider collapse from a diffuse to a dark cloud, allowing dust temperatures to fall. Under the initial diffuse conditions, small grains are too warm to promote grain-mantle build-up, with most ices forming on the mid-sized grains. As collapse proceeds, the more abundant, smallest grains cool and become the dominant ice carriers; the large population of small grains means that this ice is distributed across many grains, with perhaps no more than 40 monolayers of ice each (versus several hundred assuming a single grain size). This effect may be important for the subsequent processing and desorption of the ice during the hot-core phase of star formation, exposing a significant proportion of the ice to the gas phase, increasing the importance of ice-surface chemistry and surface–gas interactions.

The Effects of Grain Size and Temperature Distributions on the Formation of Interstellar Ice Mantles

Science.gov (United States)

Pauly, Tyler; Garrod, Robin T.

2016-02-01

Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the effects of a broad grain-size distribution on the chemistry of dust-grain surfaces and the subsequent build-up of molecular ices on the grains, using a three-phase gas-grain chemical model of a quiescent dark cloud. We include an explicit treatment of the grain temperatures, governed both by the visual extinction of the cloud and the size of each individual grain-size population. We find that the temperature difference plays a significant role in determining the total bulk ice composition across the grain-size distribution, while the effects of geometrical differences between size populations appear marginal. We also consider collapse from a diffuse to a dark cloud, allowing dust temperatures to fall. Under the initial diffuse conditions, small grains are too warm to promote grain-mantle build-up, with most ices forming on the mid-sized grains. As collapse proceeds, the more abundant, smallest grains cool and become the dominant ice carriers; the large population of small grains means that this ice is distributed across many grains, with perhaps no more than 40 monolayers of ice each (versus several hundred assuming a single grain size). This effect may be important for the subsequent processing and desorption of the ice during the hot-core phase of star formation, exposing a significant proportion of the ice to the gas phase, increasing the importance of ice-surface chemistry and surface-gas interactions.

SILICON CARBIDE GRAIN BOUNDARY DISTRIBUTIONS, IRRADIATION CONDITIONS, AND SILVER RETENTION IN IRRADIATED AGR-1 TRISO FUEL PARTICLES

Energy Technology Data Exchange (ETDEWEB)

Lillo, T. M.; Rooyen, I. J.; Aguiar, J. A.

2016-11-01

Precession electron diffraction in the transmission electron microscope was used to map grain orientation and ultimately determine grain boundary misorientation angle distributions, relative fractions of grain boundary types (random high angle, low angle or coincident site lattice (CSL)-related boundaries) and the distributions of CSL-related grain boundaries in the SiC layer of irradiated TRISO-coated fuel particles. Two particles from the AGR-1 experiment exhibiting high Ag-110m retention (>80%) were compared to a particle exhibiting low Ag-110m retention (<19%). Irradiated particles with high Ag-110m retention exhibited a lower fraction of random, high angle grain boundaries compared to the low Ag-110m retention particle. An inverse relationship between the random, high angle grain boundary fraction and Ag-110m retention is found and is consistent with grain boundary percolation theory. Also, comparison of the grain boundary distributions with previously reported unirradiated grain boundary distributions, based on SEM-based EBSD for similarly fabricated particles, showed only small differences, i.e. a greater low angle grain boundary fraction in unirradiated SiC. It was, thus, concluded that SiC layers with grain boundary distributions susceptible to Ag-110m release were present prior to irradiation. Finally, irradiation parameters were found to have little effect on the association of fission product precipitates with specific grain boundary types.

3D microstructural evolution of primary recrystallization and grain growth in cold rolled single-phase aluminum alloys

Science.gov (United States)

Adam, Khaled; Zöllner, Dana; Field, David P.

2018-04-01

Modeling the microstructural evolution during recrystallization is a powerful tool for the profound understanding of alloy behavior and for use in optimizing engineering properties through annealing. In particular, the mechanical properties of metallic alloys are highly dependent upon evolved microstructure and texture from the softening process. In the present work, a Monte Carlo (MC) Potts model was used to model the primary recrystallization and grain growth in cold rolled single-phase Al alloy. The microstructural representation of two kinds of dislocation densities, statistically stored dislocations and geometrically necessary dislocations were quantified based on the ViscoPlastic Fast Fourier transform method. This representation was then introduced into the MC Potts model to identify the favorable sites for nucleation where orientation gradients and entanglements of dislocations are high. Additionally, in situ observations of non-isothermal microstructure evolution for single-phase aluminum alloy 1100 were made to validate the simulation. The influence of the texture inhomogeneity is analyzed from a theoretical point of view using an orientation distribution function for deformed and evolved texture.

Microstructure-grain orientation relationship in coarse grain nickel cold-rolled to large strain

International Nuclear Information System (INIS)

Chen, H.S.; Godfrey, A.; Hansen, N.; Xie, J.X.; Liu, Q.

2008-01-01

The relationship between crystallographic orientation and the deformation microstructure formed during cold-rolling to high strains (up to ε vM = 4.5) has been investigated. The starting material was Ni (99.96% purity) with a coarse initial average grain size (approximately 500 μm). Microstructural characterization was carried out using a combination of electron channeling contrast imaging and electron back-scatter diffraction orientation mapping. An orientation dependence of the deformation microstructure was observed even at the highest strain examined. A large increase in the average boundary misorientation is found at strains above ε vM = 1.8 for regions with the {1 1 2} and {1 2 3} orientations. This increase accompanies the structural transition from a medium strain microstructure to a high strain lamellar microstructure. In contrast, the average misorientation in regions of {1 1 0} orientation increases only slowly even up to the highest strain examined

Magnetic uni- and tri-axial grain-orientation in superconductors with layered structures

International Nuclear Information System (INIS)

Horii, S.; Yamaki, M.; Ogino, H.; Maeda, T.; Shimoyama, J.

2010-01-01

We report the grain-orientation effects under a modulated rotation magnetic field for Y-based cuprate superconductors and LaFeAsO (La1111). Tri-axial orientation has been successfully achieved only for orthorhombic Y 2 Ba 4 Cu 7 O y and YBa 2 Cu 4 O 8 powders without a twin microstructure, while separation of three crystallographic axes could not be observed in twinned YBa 2 Cu 3 O y (Y123) and tetragonal La1111 powders. The morphology of grains, in addition to the symmetry of crystal structures, seriously affects the degrees of tri-axial orientation, which means that the control of twin microstructures is required for the tri-axial magnetic orientation in Y123.

Optically stimulated luminescence techniques in retrospective dosimetry using single grains of quartz extracted from unheated materials

Energy Technology Data Exchange (ETDEWEB)

Joerkov Thomsen, Kristina

2004-02-01

This work investigates the possibility of applying optically stimulated luminescence (OSL) in retrospective dose determinations using unheated materials. It focuses on identifying materials suitable for use in assessment of doses absorbed as a consequence of radiation accidents (i.e. accident dosimetry). Special attention has been paid to quartz extracted from unheated building materials such as concrete and mortar. The single-aliquot regeneration-dose (SAR) protocol has been used to determine absorbed doses in small aliquots as well as single grains of quartz. It is shown that OSL measurements of single grains of quartz extracted from poorly-bleached building materials can provide useful information on radiation accident doses, even when the luminescence sensitivity is low. Sources of variance in well-bleached single grain dose distributions have been investigated in detail and it is concluded that the observed variability in the data is consistent with the sum (in quadrature) of a component, which depends on the number of photons detected from each grain, and a fixed component independent of light level. Dose depth profiles through laboratory irradiated concrete bricks have successfully been measured and minimum detection limits of less than 100 mGy are derived. Measurements of thermal transfer in single grains of poorly-bleached quartz show that thermal transfer is variable on a grain-to-grain basis and that it can be a source of variance in single-grain dose distributions. Furthermore, the potential of using common household and workplace chemicals, such as table salt, washing powder and water softener, in retrospective dosimetry has been investigated. It is concluded that such materials should be considered as retrospective dosimeters in the event of a radiation accident. (au)

Comparison of single-grain and small-aliquot OSL dose estimates in <3000 years old river sediments from South India

International Nuclear Information System (INIS)

Thomas, P.J.; Jain, M.; Juyal, N.; Singhvi, A.K.

2005-01-01

We report on OSL dose distributions derived from small-aliquot and single grains of quartz in young fluvial sediments sampled from the Penner River basin, South India. The single-grain dose distributions suggest that 13 out of 19 samples were well bleached. In many well-bleached samples, there was an underestimation in the single-aliquot dose estimates as compared to those from the single grain-the difference between average dose estimates determined by the two methods ranged from ∼1% to 31%. Such a dose underestimation was not detectable in poorly bleached samples. Various possible reasons for the discrepancy between single-grain and small-aliquot dose estimates are discussed. Although there is no satisfactory explanation for this discrepancy, we speculate that the difference in the stimulation wavelengths, 470+/-30nm in the case of single-aliquot and 532nm in the case of single grains, could perhaps be one of the reasons; this may occur because the stimulation wavelength affects the proportion of the medium and slow components in the initial signal

Modelling grain-scattered ultrasound in austenitic stainless-steel welds: A hybrid model

International Nuclear Information System (INIS)

Nowers, O.; Duxbury, D. J.; Velichko, A.; Drinkwater, B. W.

2015-01-01

The ultrasonic inspection of austenitic stainless steel welds can be challenging due to their coarse grain structure, charaterised by preferentially oriented, elongated grains. The anisotropy of the weld is manifested as both a ‘steering’ of the beam and the back-scatter of energy due to the macroscopic granular structure of the weld. However, the influence of weld properties, such as mean grain size and orientation distribution, on the magnitude of scattered ultrasound is not well understood. A hybrid model has been developed to allow the study of grain-scatter effects in austenitic welds. An efficient 2D Finite Element (FE) method is used to calculate the complete scattering response from a single elliptical austenitic grain of arbitrary length and width as a function of the specific inspection frequency. A grain allocation model of the weld is presented to approximate the characteristic structures observed in austenitic welds and the complete scattering behaviour of each grain calculated. This model is incorporated into a semi-analytical framework for a single-element inspection of a typical weld in immersion. Experimental validation evidence is demonstrated indicating excellent qualitative agreement of SNR as a function of frequency and a minimum SNR difference of 2 dB at a centre frequency of 2.25 MHz. Additionally, an example Monte-Carlo study is presented detailing the variation of SNR as a function of the anisotropy distribution of the weld, and the application of confidence analysis to inform inspection development

2D magnetization of grain-oriented 3%-Si steel under uniaxial stress

International Nuclear Information System (INIS)

Permiakov, V.; Dupre, L.; Pulnikov, A.; Melkebeek, J.

2005-01-01

Magnetization in electrical steels is strongly affected by mechanical stress. The stress dependence of magnetic properties of non-oriented steels has been studied at one- and two-dimensional magnetization. This paper deals with the stress effect on one- and two-dimensional magnetization in grain-oriented 3%-Si steel. The special magnetic measurements system is applied to combine uniaxial stress and 2D magnetic measurements. The uniaxial stress ranges from 10 MPa compressive stress to 100 MPa tensile stress. A domain theory is a suitable tool for prediction and a physical explanation of stress dependency in grain-oriented steel

Thermal transfer and apparent-dose distributions in poorly bleached mortar samples: results from single grains and small aliquots of quartz

International Nuclear Information System (INIS)

Jain, M.; Thomsen, K.J.; Boetter-Jensen, L.; Urray, A.S.

2004-01-01

In the assessment of doses received from a nuclear accident, considerable attention has been paid to retrospective dosimetry using the optically stimulated luminescence (OSL) of heated materials such as bricks and tiles. quartz extracted from these artefacts was heated during manufacture; this process releases all the prior trapped charge and simultaneously sensitises he quartz. Unfortunately unheated materials such as mortar and concrete are ore common in industrial sites and particularly in nuclear installations. These materials are usually exposed to daylight during quarrying and construction, but in general this exposure is insufficient to completely empty (bleach) any geological trapped charge. This leads to a distribution of apparent doses in the sample at the time of construction with only some (if ny) grains exposed to sufficient light to be considered well bleached for SL dosimetry. The challenge in using such materials as retrospective dosemeters is in identifying these well-bleached grains when an accident dose as been superimposed on the original dose distribution. We investigate here, sing OSL, the background dose in three different mortar samples: render, whitewash and inner wall plaster from a building built in 1964. These samples re found to be both poorly bleached and weakly sensitive (only 0.3% of rains giving a detectable dose response). We study thermal transfer in ingle grains of quartz, investigate the grain-size dependence of bleaching n the size range 90-300 μm and compare the dose-distributions obtained rom small aliquots and single-grain procedures. A comparison of three different methods viz. (a) first 5%, (b) probability plot and (c) comparison f internal and external uncertainties, is made for equivalent dose estimation. The results have implications for accident dosimetry, archaeological studies and dating of poorly bleached sediments

Spall behaviour of single crystal aluminium at three principal orientations

Science.gov (United States)

Owen, G. D.; Chapman, D. J.; Whiteman, G.; Stirk, S. M.; Millett, J. C. F.; Johnson, S.

2017-10-01

A series of plate impact experiments have been conducted to study the spall strength of the three principal crystallographic orientations of single crystal aluminium ([100], [110] and, [111]) and ultra-pure polycrystalline aluminium. The samples have been shock loaded at two impact stresses (4 GPa and 10 GPa). Significant differences have been observed in the elastic behaviour, the pullback velocities, and the general shape of the wave profiles, which can be accounted for by considerations of the microscale homogeneity, the dislocation density, and the absence of grain boundaries in the single crystal materials. The data have shown that there is a consistent order of spall strength measured for the four sample materials. The [111] orientation has the largest spall strength and elastic limit, followed closely by [110], [100], and then the polycrystalline material. This order is consistent with both quasi-static data and geometrical consideration of Schmid factors.

Effect of crystal orientation on grain boundary migration and radiation-induced segregation

International Nuclear Information System (INIS)

Hashimoto, N.; Eda, Y.; Takahashi, H.

1996-01-01

Fe-Cr-Ni, Ni-Al and Ni-Si alloys were electron-irradiated using a high voltage electron microscope (1 MeV), and in situ observations of the structural evolution and micro-chemical analysis were carried out. During the irradiation, the grain boundaries in the irradiated region migrated, while no grain boundary migration occurred in the unirradiated area. The occurrence of boundary migration depended on the orientation relationship of the boundary interfaces. Grain boundary migration took place in Fe-Cr-Ni and Ni-Si alloys with large crystal orientation difference between the two grains across a grain boundary. In Ni-Al, however, the grain boundary migration did not occur. The solute segregation was caused at grain boundary under irradiation and this segregation behavior was closely related to solute size, namely the concentrations of undersized Ni and oversized Cr elements in Fe-Cr-Ni alloy increased and reduced at grain boundary, respectively. The same dependence of segregation on the solute size was derived in Ni-Si and Ni-Al alloys, in which Si and Al solutes are undersized and oversized elements, respectively. Therefore, Si solute enriched and Al solute depleted at grain boundary. From the present segregation behavior, it is suggested that the flow of point defects into the boundary is the cause of grain boundary migration. (orig.)

Effects of seed geometry on the crystal growth and the magnetic properties of single grain REBCO bulk superconductors

Energy Technology Data Exchange (ETDEWEB)

Lee, Hwi Joo; Lee, Hee Gyoun [Korea Polytechnic University, Siheung (Korea, Republic of); Park, Soon Dong; Jun, Bung Hyack; Kim, Chan Joong [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2017-09-15

This study presents that the orientation and the geometry of seed affect on the growth behavior of melt processed single grain REBCO bulk superconductor and its magnetic properties. The effects of seed geometry have been investigated for thin 30mm x 30mm rectangular powder compacts. Single grain REBCO bulk superconductors have been grown successfully by a top seed melt growth method for 8-mm thick vertical thin REBCO slab. Asymmetric structures have been developed at the front surface and at the rear surface of the specimen. Higher magnetic properties have been obtained for the specimen that c-axis is normal to the specimen surface. The relationships between microstructure, grain growth and magnetic properties have been discussed.

Synthesis of few layer single crystal graphene grains on platinum by chemical vapour deposition

Directory of Open Access Journals (Sweden)

S. Karamat

2015-08-01

Full Text Available The present competition of graphene electronics demands an efficient route which produces high quality and large area graphene. Chemical vapour deposition technique, where hydrocarbons dissociate in to active carbon species and form graphene layer on the desired metal catalyst via nucleation is considered as the most suitable method. In this study, single layer graphene with the presence of few layer single crystal graphene grains were grown on Pt foil via chemical vapour deposition. The higher growth temperature changes the surface morphology of the Pt foil so a delicate process of hydrogen bubbling was used to peel off graphene from Pt foil samples with the mechanical support of photoresist and further transferred to SiO2/Si substrates for analysis. Optical microscopy of the graphene transferred samples showed the regions of single layer along with different oriented graphene domains. Two type of interlayer stacking sequences, Bernal and twisted, were observed in the graphene grains. The presence of different stacking sequences in the graphene layers influence the electronic and optical properties; in Bernal stacking the band gap can be tunable and in twisted stacking the overall sheet resistance can be reduced. Grain boundaries of Pt provides low energy sites to the carbon species, therefore the nucleation of grains are more at the boundaries. The stacking order and the number of layers in grains were seen more clearly with scanning electron microscopy. Raman spectroscopy showed high quality graphene samples due to very small D peak. 2D Raman peak for single layer graphene showed full width half maximum (FWHM value of 30 cm−1. At points A, B and C, Bernal stacked grain showed FWHM values of 51.22, 58.45 and 64.72 cm−1, while twisted stacked grain showed the FWHM values of 27.26, 28.83 and 20.99 cm−1, respectively. FWHM values of 2D peak of Bernal stacked grain showed an increase of 20–30 cm−1 as compare to single layer graphene

78 FR 70574 - Grain-Oriented Electrical Steel From China, Czech Republic, Germany, Japan, Korea, Poland, and...

Science.gov (United States)

2013-11-26

...)] Grain-Oriented Electrical Steel From China, Czech Republic, Germany, Japan, Korea, Poland, and Russia..., Germany, Japan, Korea, Poland, and Russia of grain-oriented electrical steel, provided for in subheadings... alleged to be sold in the United States at less than fair value (LTFV), and by reason of imports of grain...

New orientation formation and growth during primary recrystallization in stable single crystals of three face-centred cubic metals

International Nuclear Information System (INIS)

Miszczyk, M.; Paul, H.; Driver, J.H.; Maurice, C.

2015-01-01

Graphical abstract: For Ni, Cu and Cu-2%Al and (1 1 0)[0 0 −1] and (1 1 0)[1 −1 −2] initial orientations at the initial stages of recrystallization, the appearance of a specific number of new orientation groups of new grains has been demonstrated. The orientation relations across the recrystallization front are characterized by a high proportion of angles in the range 25–35° and 45–55° around axes mostly grouped about the 〈1 2 2〉, 〈1 1 1〉, 〈1 2 3〉 and 〈1 1 2〉 directions. A local minimum was noted for the disorientation angle densities close to 40° in all cases. For a single isolated nucleus of uniform orientation, the rotation axes are usually grouped around one of the normals of all four {1 1 1} planes but do not (or only rarely) coincide with them. The orientation of the growing new grain quickly transforms through the formation of a first generation twins. The most frequent situation occurs when the normal of the twinning face plane is situated near the rotation axis, around which the crystal lattice of the ‘primary nuclei’ rotates. Based on the anisotropy of grain growth a possible mechanism of orientation generation and grain growth by thermally activation movement of dislocation families, on {1 1 1} planes is proposed. - Abstract: The early stages of recrystallization have been systematically characterized in single crystal metals of medium and low stacking fault energy. Goss {1 1 0}〈0 0 1〉 and brass {1 1 0}〈1 1 2〉 oriented samples of Ni, Cu and Cu–2 wt.% Al alloy were deformed in a channel die to a logarithmic strain of 0.51 to develop a homogeneous structure composed of two sets of symmetrical primary microbands and then lightly annealed. Scanning electron microscopy/electron backscattered diffraction analyses demonstrate a strong relation between as-deformed orientations and the limited number of recrystallized grain orientations. The disorientation angles across the recrystallization front are mostly grouped in

Role of crystal orientation on chemical mechanical polishing of single crystal copper

Energy Technology Data Exchange (ETDEWEB)

Zhu, Aibin, E-mail: abzhu@mail.xjtu.edu.cn; He, Dayong; Luo, Wencheng; Liu, Yangyang

2016-11-15

Highlights: • The role of crystal orientation in cooper CMP by quasi-continuum was studied. • The atom displacement diagrams were obtained and analyzed. • The stress distribution diagrams and load-displacement curves were analyzed. • This research is helpful to revealing the material removal mechanism of CMP. - Abstract: The material removal mechanism of single crystal copper in chemical mechanical polishing (CMP) has not been intensively investigated. And the role of crystal orientation in CMP of single crystal cooper is not quite clear yet. Quasi-continuum method was adopted in this paper to simulate the process of nano-particles grinding on single crystal copper in CMP process. Three different crystal orientations, i.e. x[100]y[001], x[001]y[110] and x[–211]y[111], were chosen for analysis. The atom displacement diagrams, stress distribution diagrams and load-displacement curves were obtained. After analyzing the deformation mechanism, residual stress of the work piece material and cutting force, results showed that, the crystal orientation of work piece has great influence on the deformation characteristics and surface quality of work piece during polishing. In the A(001)[100] orientation, the residual stress distribution after polishing is deeper, and the stress is larger than that in the B(110)[001] and C(111)[–211] orientations. And the average tangential cutting force in the A(001)[100] orientation is much larger than those in the other two crystal orientation. This research is helpful to revealing the material removal mechanism of CMP process.

Effect of Grain Orientation and Boundary Distributions on Hydrogen-Induced Cracking in Low-Carbon-Content Steels

Science.gov (United States)

Masoumi, Mohammad; Coelho, Hana Livia Frota; Tavares, Sérgio Souto Maior; Silva, Cleiton Carvalho; de Abreu, Hamilton Ferreira Gomes

2017-08-01

Hydrogen-induced cracking (HIC) causes considerable economic losses in a wide range of steels exposed to corrosive environments. The effect of crystallographic texture and grain boundary distributions tailored by rolling at 850 °C in three different steels with a body-centered cube structure was investigated on HIC resistance. The x-ray and electron backscattered diffraction techniques were used to characterize texture evolutions during the rolling process. The findings revealed a significant improvement against HIC based on texture engineering. In addition, increasing the number of {111} and {110} grains, associated with minimizing the number of {001} grains in warm-rolled samples, reduced HIC susceptibility. Moreover, the results showed that boundaries associated with low {hkl} indexing and denser packing planes had more resistance against crack propagation.

Applications of the rotating orientation XRD method to oriented materials

International Nuclear Information System (INIS)

Guo Zhenqi; Li Fei; Jin Li; Bai Yu

2009-01-01

The rotating orientation x-ray diffraction (RO-XRD) method, based on conventional XRD instruments by a modification of the sample stage, was introduced to investigate the orientation-related issues of such materials. In this paper, we show its applications including the determination of single crystal orientation, assistance in crystal cutting and evaluation of crystal quality. The interpretation of scanning patterns by RO-XRD on polycrystals with large grains, bulk material with several grains and oriented thin film is also presented. These results will hopefully expand the applications of the RO-XRD method and also benefit the conventional XRD techniques. (fast track communication)

Measurement of magnetic properties of grain-oriented silicon steel using round rotational single sheet tester (RRSST)

International Nuclear Information System (INIS)

Gorican, Viktor; Hamler, Anton; Jesenik, Marko; Stumberger, Bojan; Trlep, Mladen

2004-01-01

The magnetic properties of grain-oriented material under rotational magnetic flux condition were measured, using two different pairs of B coils with different angle with respect to the rolling direction. It is known that induced voltages in two perpendicularly positioned B coils do not represent the actual amplitude and the angular speed of vector B in the measuring region. Consequently, the control of the induced voltages in the B coils at different positions means that the sample is measured under different magnetic flux condition. This leads to a difference between the results of vector H and the rotational loss

Strain Amount Dependent Grain Size and Orientation Developments during Hot Compression of a Polycrystalline Nickel Based Superalloy

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Guoai He

2017-02-01

Full Text Available Controlling grain size in polycrystalline nickel base superalloy is vital for obtaining required mechanical properties. Typically, a uniform and fine grain size is required throughout forging process to realize the superplastic deformation. Strain amount occupied a dominant position in manipulating the dynamic recrystallization (DRX process and regulating the grain size of the alloy during hot forging. In this article, the high-throughput double cone specimen was introduced to yield wide-range strain in a single sample. Continuous variations of effective strain ranging from 0.23 to 1.65 across the whole sample were achieved after reaching a height reduction of 70%. Grain size is measured to be decreased from the edge to the center of specimen with increase of effective strain. Small misorientation tended to generate near the grain boundaries, which was manifested as piled-up dislocation in micromechanics. After the dislocation density reached a critical value, DRX progress would be initiated at higher deformation region, leading to the refinement of grain size. During this process, the transformations from low angle grain boundaries (LAGBs to high angle grain boundaries (HAGBs and from subgrains to DRX grains are found to occur. After the accomplishment of DRX progress, the neonatal grains are presented as having similar orientation inside the grain boundary.

Sources of variability in OSL dose measurements using single grains of quartz

DEFF Research Database (Denmark)

Thomsen, Kristina Jørkov; Murray, A.S.; Bøtter-Jensen, L.

2005-01-01

spread. In this preliminary study, dose distributions have been studied using single grains of heated and laboratory irradiated quartz. By heating the sample, the contribution from incomplete zeroing was excluded and at the same time the sample was sensitised. The laboratory gamma irradiation...

Determination of burial dose in incompletely bleached fluvial samples using single grains of quartz

DEFF Research Database (Denmark)

Thomsen, Kristina Jørkov; Murray, A.S.; Bøtter-Jensen, Lars

2007-01-01

We determine the burial dose in three known-age incompletely bleached fluvial samples using single grains of quartz. Estimation of burial dose in incompletely bleached samples requires that the characteristics of the well-bleached part of the distribution are known in order to distinguish between...... well-bleached and poorly bleached grains. It is especially important to investigate if the uncertainties assigned to individual estimates of dose adequately describe the observed variability in well-bleached dose distributions. We investigate this by quantifying the overdispersion in laboratory-bleached...

Anisotropy and intergrain current density in oriented grained bulk YBa2Cu3Ox superconductor

International Nuclear Information System (INIS)

Selvamanickam, V.; Salama, K.

1990-01-01

The intergrain transport current density and its anisotropy have been studied in oriented grained bulk YBa 2 Cu 3 O x superconductors fabricated by the liquid phase processing method. Current density measurements were performed on oriented grained samples with the transport current aligned at different angles to the a-b plane. In these measurements, the transport current passed through several oriented grain boundaries. The results indicate that the critical current density drops rapidly when the transport current flows at small angles to the a-b plane and then decreases slowly at larger angles. At 77 K and zero magnetic field, an anisotropy ratio of about 25 is observed between J c along a-b plane and that perpendicular to the plane. Further, the critical current density in these samples is found to depend weakly on magnetic field even though the current crosses grain boundaries. These results support the notion that grain boundaries of these superconductors are different in nature from those of solid-state sintered samples.

Misorientation related microstructure at the grain boundary in a nickel-based single crystal superalloy

International Nuclear Information System (INIS)

Huang, Ming; Zhuo, Longchao; Liu, Zhanli; Lu, Xiaogang; Shi, Zhenxue; Li, Jiarong; Zhu, Jing

2015-01-01

The mechanical properties of nickel-based single crystal superalloys deteriorate with increasing misorientation, thus the finished product rate of the casting of single crystal turbine airfoils may be reduced due to the formation of grain boundaries especially when the misorientation angle exceeds to some extent. To this day, evolution of the microstructures at the grain boundaries with misorientation and the relationship between the microstructures and the mechanical properties are still unclear. In this work a detailed characterization of the misorientation related microstructure at the grain boundary in DD6 single crystal superalloy has been carried out using scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques; the elemental distribution at the grain boundaries has been analyzed by energy dispersive (EDS) X-ray mapping; and the effect of precipitation of μ phases at the grain boundary on the mechanical property has been evaluated by finite element calculation. It is shown that the proportion of γ phase at the grain boundaries decreases, while the proportion of γ′ phase at the grain boundaries increases with increasing misorientation; the μ phase is precipitated at the grain boundaries when the misorientation angle exceeds about 10° and thus it could lead to a dramatic deterioration of the mechanical properties, as well as that the enrichment of Re and W gradually disappears as the misorientation angle increases. All these factors may result in the degradation of the mechanical properties at the grain boundaries as the misorientation increases. Furthermore, the finite element calculation confirms that precipitation of μ phases at the grain boundary is responsible for the significant deterioration of the mechanical properties when the misorientation exceeds about 10°. This work provides a physical imaging of the microstructure for understanding the relationship between the mechanical properties and the misorientation

Evolution of surface topography in dependence on the grain orientation during surface thermal fatigue of polycrystalline copper

CERN Document Server

Aicheler, M; Taborelli, M; Calatroni, S; Neupert, H; Wuensch, W; Sgobba, S

2011-01-01

Surface degradation due to cyclic thermal loading plays a major role in the Accelerating Structures (AS) of the future Compact Linear Collider (CLIC) In this article results on surface degradation of thermally cycled polycrystalline copper as a function of the orientation of surface grains are presented Samples with different grain sizes were subjected to thermal fatigue using two different methods and were then characterized using roughness measurements and Orientation Imaging Scanning-Electron-Microscopy (OIM-SEM) Samples fatigued by a pulsed laser show the same trend in the orientation-fatigue damage accumulation as the sample fatigued by pulsed Radio-Frequency-heating (RF) it is clearly shown that 11 1 1] surface grains develop significantly more damage than the surface grains oriented in {[}100] and three reasons for this behaviour are pointed out Based on observations performed near grain boundaries their role in the crack initiation process is discussed The results are in good agreement with previous f...

Grain-Boundary Resistance in Copper Interconnects: From an Atomistic Model to a Neural Network

Science.gov (United States)

Valencia, Daniel; Wilson, Evan; Jiang, Zhengping; Valencia-Zapata, Gustavo A.; Wang, Kuang-Chung; Klimeck, Gerhard; Povolotskyi, Michael

2018-04-01

Orientation effects on the specific resistance of copper grain boundaries are studied systematically with two different atomistic tight-binding methods. A methodology is developed to model the specific resistance of grain boundaries in the ballistic limit using the embedded atom model, tight- binding methods, and nonequilibrium Green's functions. The methodology is validated against first-principles calculations for thin films with a single coincident grain boundary, with 6.4% deviation in the specific resistance. A statistical ensemble of 600 large, random structures with grains is studied. For structures with three grains, it is found that the distribution of specific resistances is close to normal. Finally, a compact model for grain-boundary-specific resistance is constructed based on a neural network.

Grain-size distributions and grain boundaries of chalcopyrite-type thin films

International Nuclear Information System (INIS)

Abou-Ras, D.; Schorr, S.; Schock, H.W.

2007-01-01

CuInSe 2 , CuGaSe 2 , Cu(In,Ga)Se 2 and CuInS 2 thin-film solar absorbers in completed solar cells were studied in cross section by means of electronbackscatter diffraction. From the data acquired, grain-size distributions were extracted, and also the most frequent grain boundaries were determined. The grain-size distributions of all chalcopyrite-type thin films studied can be described well by lognormal distribution functions. The most frequent grainboundary types in these thin films are 60 - left angle 221 right angle tet and 71 - left angle 110 right angle tet (near) Σ3 twin boundaries. These results can be related directly to the importance of {112} tet planes during the topotactical growth of chalcopyrite-type thin films. Based on energetic considerations, it is assumed that the most frequent twin boundaries exhibit a 180 - left angle 221 right angle tet constellation. (orig.)

Study of secondary recrystallization in grain-oriented steel treated under dynamical heat treatment conditions

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V. Stoyka

2009-04-01

Full Text Available The present study was made to investigate secondary recrystallization in grain-oriented steels annealed at short time temperature exposures with application of dynamical heating. The investigated GO steels for experiments were taken from one industrial line after final cold rolling reduction and subsequent box annealing. It was shown that application of short time heat treatment conditions could lead to complete abnormal grain growth in the investigated GO steel. The texture and microstructure obtained in the laboratory treated material is similar to that observed in the same GO steel taken after industrial final box-annealing. However, some “parasitic” grains were observed in the secondary recrystallized matrix of the laboratory treated GO steel. These “parasitic” grains possess the unwanted from magnetic properties point of view {111} orientation components.

A comparison of grain boundary evolution during grain growth in fcc metals

International Nuclear Information System (INIS)

Brons, J.G.; Thompson, G.B.

2013-01-01

Grain growth of Cu and Ni thin films, subjected to in situ annealing within a transmission electron microscope, has been quantified using a precession-enhanced electron diffraction technique. The orientation of each grain and its misorientation with respect to its neighboring grains were calculated. The Cu underwent grain growth that maintained a monomodal grain size distribution, with its low-angle grain boundaries being consumed, and the Ni exhibited grain size distributions in stages, from monomodal to bimodal to monomodal. The onset of Ni’s abnormal grain growth was accompanied by a sharp increase in the Σ3 and Σ9 boundary fractions, which is attributed to simulation predictions of their increased mobility. These Σ3 and Σ9 fractions then dropped to their room temperature values during the third stage of grain growth. In addition to the Σ3 and Σ9 boundaries, the Σ5 and Σ7 boundaries also underwent an increase in total boundary fraction with increasing temperature in both metals

Effects of grain size distribution on the interstellar dust mass growth

OpenAIRE

Hirashita, Hiroyuki; Kuo, Tzu-Ming

2011-01-01

Grain growth by the accretion of metals in interstellar clouds (called `grain growth') could be one of the dominant processes that determine the dust content in galaxies. The importance of grain size distribution for the grain growth is demonstrated in this paper. First, we derive an analytical formula that gives the grain size distribution after the grain growth in individual clouds for any initial grain size distribution. The time-scale of the grain growth is very sensitive to grain size di...

Ultra-large single crystals by abnormal grain growth.

Science.gov (United States)

Kusama, Tomoe; Omori, Toshihiro; Saito, Takashi; Kise, Sumio; Tanaka, Toyonobu; Araki, Yoshikazu; Kainuma, Ryosuke

2017-08-25

Producing a single crystal is expensive because of low mass productivity. Therefore, many metallic materials are being used in polycrystalline form, even though material properties are superior in a single crystal. Here we show that an extraordinarily large Cu-Al-Mn single crystal can be obtained by abnormal grain growth (AGG) induced by simple heat treatment with high mass productivity. In AGG, the sub-boundary energy introduced by cyclic heat treatment (CHT) is dominant in the driving pressure, and the grain boundary migration rate is accelerated by repeating the low-temperature CHT due to the increase of the sub-boundary energy. With such treatment, fabrication of single crystal bars 70 cm in length is achieved. This result ensures that the range of applications of shape memory alloys will spread beyond small-sized devices to large-scale components and may enable new applications of single crystals in other metallic and ceramics materials having similar microstructural features.Growing large single crystals cheaply and reliably for structural applications remains challenging. Here, the authors combine accelerated abnormal grain growth and cyclic heat treatments to grow a superelastic shape memory alloy single crystal to 70 cm.

Determination of grain boundary mobility during recrystallization by statistical evaluation of electron backscatter diffraction measurements

International Nuclear Information System (INIS)

Basu, I.; Chen, M.; Loeck, M.; Al-Samman, T.; Molodov, D.A.

2016-01-01

One of the key aspects influencing microstructural design pathways in metallic systems is grain boundary motion. The present work introduces a method by means of which direct measurement of grain boundary mobility vs. misorientation dependence is made possible. The technique utilizes datasets acquired by means of serial electron backscatter diffraction (EBSD) measurements. The experimental EBSD measurements are collectively analyzed, whereby datasets were used to obtain grain boundary mobility and grain aspect ratio with respect to grain boundary misorientation. The proposed method is further validated using cellular automata (CA) simulations. Single crystal aluminium was cold rolled and scratched in order to nucleate random orientations. Subsequent annealing at 300 °C resulted in grains growing, in the direction normal to the scratch, into a single deformed orientation. Growth selection was observed, wherein the boundaries with misorientations close to Σ7 CSL orientation relationship (38° 〈111〉) migrated considerably faster. The obtained boundary mobility distribution exhibited a non-monotonic behavior with a maximum corresponding to misorientation of 38° ± 2° about 〈111〉 axes ± 4°, which was 10–100 times higher than the mobility values of random high angle boundaries. Correlation with the grain aspect ratio values indicated a strong growth anisotropy displayed by the fast growing grains. The observations have been discussed in terms of the influence of grain boundary character on grain boundary motion during recrystallization. - Highlights: • Statistical microstructure method to measure grain boundary mobility during recrystallization • Method implementation independent of material or crystal structure • Mobility of the Σ7 boundaries in 5N Al was calculated as 4.7 × 10"–"8 m"4/J ⋅ s. • Pronounced growth selection in the recrystallizing nuclei in Al • Boundary mobility values during recrystallization 2–3 orders of magnitude

Investigations of Residual Stresses and Mechanical Properties of Single Crystal Niobium for SRF Cavities

Science.gov (United States)

Gnäupel-Herold, Thomas; Myneni, Ganapati Rao; Ricker, Richard E.

2007-08-01

This work investigates properties of large grained, high purity niobium with respect to the forming of superconducting radio frequency (SRF) cavities from such large grained sheets. The yield stresses were examined using tensile specimens that were essentially single crystals in orientations evenly distributed in the standard projection triangle. No distinct yield anisotropy was found, however, vacuum annealing increased the yield strength by a factor 2…3. The deep drawing forming operation of the half cells raises the issues of elastic shape changes after the release of the forming tool (springback) and residual stresses, both of which are indicated to be negligible. This is a consequence of the low yield stress (sheet metal forming). However, the significant anisotropy of the transversal plastic strains after uniaxial deformation points to potentially critical thickness variations for large grained / single crystal half cells, thus raising the issue of controlling grain orientation or using single crystal sheet material.

Investigations of Residual Stresses and Mechanical Properties of Single Crystal Niobium for SRF Cavities

International Nuclear Information System (INIS)

Gnaeupel-Herold, Thomas; Myneni, Ganapati Rao; Ricker, Richard E.

2007-01-01

This work investigates properties of large grained, high purity niobium with respect to the forming of superconducting radio frequency (SRF) cavities from such large grained sheets. The yield stresses were examined using tensile specimens that were essentially single crystals in orientations evenly distributed in the standard projection triangle. No distinct yield anisotropy was found, however, vacuum annealing increased the yield strength by a factor 2...3. The deep drawing forming operation of the half cells raises the issues of elastic shape changes after the release of the forming tool (springback) and residual stresses, both of which are indicated to be negligible. This is a consequence of the low yield stress (< 100 MPa) and the large thickness (compared to typical thicknesses in sheet metal forming). However, the significant anisotropy of the transversal plastic strains after uniaxial deformation points to potentially critical thickness variations for large grained / single crystal half cells, thus raising the issue of controlling grain orientation or using single crystal sheet material

Grain-to-grain variations in NbC particle size distributions in an austenitic stainless steel

International Nuclear Information System (INIS)

Barlow, C.Y.; Ralph, B.; Silverman, B.; Jones, A.R.

1979-01-01

Quantitative information has been obtained concerning the size distributions of NbC precipitate particles in different grains in a deformed and aged austenitic stainless steel specimen. The precipitate size distributions obtained differ from one grain to another. The average disparity measured between the mean precipitate sizes was a function of the distance between the grains compared. The results obtained are considered in terms of differences in precipitation behaviour due to variations in the levels of plastic strain in constituent grains of the deformed specimen. (author)

Debris flow rheology: Experimental analysis of fine-grained slurries

Science.gov (United States)

Major, Jon J.; Pierson, Thomas C.

1992-01-01

The rheology of slurries consisting of ≤2-mm sediment from a natural debris flow deposit was measured using a wide-gap concentric-cylinder viscometer. The influence of sediment concentration and size and distribution of grains on the bulk rheological behavior of the slurries was evaluated at concentrations ranging from 0.44 to 0.66. The slurries exhibit diverse rheological behavior. At shear rates above 5 s−1 the behavior approaches that of a Bingham material; below 5 s−1, sand exerts more influence and slurry behavior deviates from the Bingham idealization. Sand grain interactions dominate the mechanical behavior when sand concentration exceeds 0.2; transient fluctuations in measured torque, time-dependent decay of torque, and hysteresis effects are observed. Grain rubbing, interlocking, and collision cause changes in packing density, particle distribution, grain orientation, and formation and destruction of grain clusters, which may explain the observed behavior. Yield strength and plastic viscosity exhibit order-of-magnitude variation when sediment concentration changes as little as 2–4%. Owing to these complexities, it is unlikely that debris flows can be characterized by a single rheological model.

Changing distribution and geometry of S′ in Al–Cu–Mg single crystals during stress aging by controlling the loading orientation

International Nuclear Information System (INIS)

Chen, Jiqiang; Chen, Zhiguo; Guo, Xiaobin; Deng, Yunlai

2016-01-01

The precipitation behavior of S′ phase in Al–Cu–Mg single crystals during stress-free and stress aging was investigated by transmission electron microscopy (TEM). Different compressive stress magnitudes and loading orientations were applied to determine their effects on the precipitation of S′ in Al–Cu–Mg alloy during stress aging. The results indicate that a noticeable preferential orientation of S′ is generated in the sample under applied compressive stress of 33 MPa loading along close to [001] Al , whilst no obviously preferential orientation of S′ can be observed in the sample loaded along close to [101] Al under the same applied stress or even larger applied stress. The precipitation distribution of S′ phase during stress aging can be changed by the loading orientation of the applied stress. Moreover, compressive stress aging may lead to S′ phase shorter in length, and the length of S′ phase shows a decreasing tendency with increasing applied stress, which are associated with the positive misfit between S′ and Al matrix.

Evaluation of stress distribution due to shearing in non-oriented electrical steel by using synchrotron radiation

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Yoshiaki Zaizen

2016-05-01

Full Text Available The influence of the shearing process on the iron loss of non-oriented electrical steels with grain sizes of 10 μm-150 μm was investigated. The deterioration ratio of iron loss was clearly smaller in sample with small grain sizes. The droop height, reflecting the amount of plastic deformation, displayed a good relationship with the deterioration of iron loss under the effect of the material grain size. To clarify the strain distribution around the sheared edge, the elastic strain in a sheet sample with the thickness of 0.30 mm and grain size of 10 μm was evaluated by using synchrotron radiation. The width of the region of elastic strain due to shearing was two or three times of the material thickness. The results of the plastic strain distribution obtained by the measurements were then used to estimate the iron loss deterioration rate in 5 mm width sheared samples. The estimated loss deteriotation coincided with the actual measured iron loss.

Evaluation of stress distribution due to shearing in non-oriented electrical steel by using synchrotron radiation

Energy Technology Data Exchange (ETDEWEB)

Zaizen, Yoshiaki, E-mail: y-zaizen@jfe-steel.co.jp; Omura, Takeshi; Senda, Kunihiro [Steel Research Laboratory, JFE Steel Corporation, Kawasakidori 1,Mizushima, Kurashiki,712-8511 (Japan); Fukumura, Masaru [Steel Research Laboratory, JFE Steel Corporation, Kawasaki, Kanagawa 210-0855 (Japan); Toda, Hiroaki [Steel Business Planning Dept, JFE Steel Corporation, Tokyo 100-0011 (Japan)

2016-05-15

The influence of the shearing process on the iron loss of non-oriented electrical steels with grain sizes of 10 μm-150 μm was investigated. The deterioration ratio of iron loss was clearly smaller in sample with small grain sizes. The droop height, reflecting the amount of plastic deformation, displayed a good relationship with the deterioration of iron loss under the effect of the material grain size. To clarify the strain distribution around the sheared edge, the elastic strain in a sheet sample with the thickness of 0.30 mm and grain size of 10 μm was evaluated by using synchrotron radiation. The width of the region of elastic strain due to shearing was two or three times of the material thickness. The results of the plastic strain distribution obtained by the measurements were then used to estimate the iron loss deterioration rate in 5 mm width sheared samples. The estimated loss deteriotation coincided with the actual measured iron loss.

Comparison of grain to grain orientation and stiffness mapping by spatially resolved acoustic spectroscopy and EBSD.

Science.gov (United States)

Mark, A F; Li, W; Sharples, S; Withers, P J

2017-07-01

Our aim was to establish the capability of spatially resolved acoustic spectroscopy (SRAS) to map grain orientations and the anisotropy in stiffness at the sub-mm to micron scale by comparing the method with electron backscatter diffraction (EBSD) undertaken within a scanning electron microscope. In the former the grain orientations are deduced by measuring the spatial variation in elastic modulus; conversely, in EBSD the elastic anisotropy is deduced from direct measurements of the crystal orientations. The two test-cases comprise mapping the fusion zones for large TIG and MMA welds in thick power plant austenitic and ferritic steels, respectively; these are technologically important because, among other things, elastic anisotropy can cause ultrasonic weld inspection methods to become inaccurate because it causes bending in the paths of sound waves. The spatial resolution of SRAS is not as good as that for EBSD (∼100 μm vs. ∼a few nm), nor is the angular resolution (∼1.5° vs. ∼0.5°). However the method can be applied to much larger areas (currently on the order of 300 mm square), is much faster (∼5 times), is cheaper and easier to perform, and it could be undertaken on the manufacturing floor. Given these advantages, particularly to industrial users, and the on-going improvements to the method, SRAS has the potential to become a standard method for orientation mapping, particularly in cases where the elastic anisotropy is important over macroscopic/component length scales. © 2017 The Authors Journal of Microscopy © 2017 Royal Microscopical Society.

Effect of non-metallic precipitates and grain size on core loss of non-oriented electrical silicon steels

Science.gov (United States)

Wang, Jiayi; Ren, Qiang; Luo, Yan; Zhang, Lifeng

2018-04-01

In the current study, the number density and size of non-metallic precipitates and the size of grains on the core loss of the 50W800 non-oriented electrical silicon steel sheets were investigated. The number density and size of precipitates and grains were statistically analyzed using an automatic scanning electron microscope (ASPEX) and an optical microscope. Hypothesis models were established to reveal the physical feature for the function of grain size and precipitates on the core loss of the steel. Most precipitates in the steel were AlN particles smaller than 1 μm so that were detrimental to the core loss of the steel. These finer AlN particles distributed on the surface of the steel sheet. The relationship between the number density of precipitates (x in number/mm2 steel area) and the core loss (P1.5/50 in W/kg) was regressed as P1.5/50 = 4.150 + 0.002 x. The average grain size was approximately 25-35 μm. The relationship between the core loss and grain size (d in μm) was P1.5/50 = 3.851 + 20.001 d-1 + 60.000 d-2.

A new approach to texture measurements: Orientation distribution function (ODF) determination by Rietveld refinement

International Nuclear Information System (INIS)

Vondreele, R.; Larson, A.; Lawson, A.; Sheldon, R.; Wright, S.

1996-01-01

The preferred orientation of crystal grains within a manufactured part is described most fully by its orientation distribution function (ODF), which is a mapping of the probability of each of the possible grain orientations with respect to the exterior dimensions. Traditionally, an ODF is determined from pole figures for a relatively small number of reflections. These pole figures are measured with x-rays or neutrons using short detector scans over the center of an individual diffraction peak for a large number of different sample orientations. This is efficient if the selected diffraction peaks are reasonably strong (relative to background) and well separated, such as in pure fcc and bcc metals. It is also appropriate for constant wavelength sources where collection of individual diffraction peak intensities is a reasonably efficient use of the source. However, the traditional method is not very efficient for neutron diffraction at a spallation source such as LANSCE where the entire diffraction pattern is accessible for each sample setting. Moreover, a different approach is necessary for complicated diffraction patterns, such as from composite materials, intermetallic compounds, high T c ceramics, polyphasic minerals and polymers where there is expected to be heavy overlap of adjacent diffraction peaks. In addition, the large number of settings normally collected for an individual pole figure may not be necessary, since the entire pattern is obtained at each setting. Thus, a new method of ODF analysis needs to be developed to handle the more complex diffraction patterns obtained from modern technological materials as well as take advantage of the particular characteristics of spallation neutron sources. This project sought to develop the experimental procedures and the mathematical treatment needed to produce an orientation distribution function (ODF) directly from full diffraction patterns from a sample in a limited number of orientations

Shape preferred orientation of iron grains compatible with Earth's uppermost inner core hemisphericity

Science.gov (United States)

Calvet, Marie; Margerin, Ludovic

2018-01-01

Constraining the possible patterns of iron fabrics in the Earth's Uppermost Inner Core (UIC) is key to unravel the mechanisms controlling its growth and dynamics. In the framework of crystalline micro-structures composed of ellipsoidal, aligned grains, we discuss possible textural models of UIC compatible with observations of P-wave attenuation and velocity dispersion. Using recent results from multiple scattering theory in textured heterogeneous materials, we compute the P-wave phase velocity and scattering attenuation as a function of grain volume, shape, and orientation wrt to the propagation direction of seismic P-waves. Assuming no variations of the grain volume between the Eastern and Western hemisphere, we show that two families of texture are compatible with the degree-one structure of the inner core as revealed by the positive correlation between seismic velocity and attenuation. (1) Strong flattening of grains parallel to the Inner Core Boundary in the Western hemisphere and weak anisometry in the Eastern hemisphere. (2) Strong radial elongation of grains in the Western hemisphere and again weak anisometry in the Eastern hemisphere. Both textures can quantitatively explain the seismic data in a limited range of grain volumes. Furthermore, the velocity and attenuation anisotropy locally observed under Africa demands that the grains be locally elongated in the direction of Earth's meridians. Our study demonstrates that the hemispherical seismic structure of UIC can be entirely explained by changes in the shape and orientation of grains, thereby offering an alternative to changes in grain volumes. In the future, our theoretical toolbox could be used to systematically test the compatibility of textures predicted by geodynamical models with seismic observations.

Grain-to-Grain Variations in NbC Particle Size Distributions in an Austenitic Stainless Steel

DEFF Research Database (Denmark)

Barlow, Claire; Ralph, B.; Silverman, B.

1979-01-01

Quantitative information has been obtained concerning the size distributions of NbC precipitate particles in different grains in a deformed and aged austenitic stainless steel specimen. The precipitate size distributions obtained differ from one grain to another. The average disparity measured be...

Origin of grain orientation during solidification of an aluminum alloy

International Nuclear Information System (INIS)

Wei, H.L.; Elmer, J.W.; DebRoy, T.

2016-01-01

The evolution of grain morphology during solidification of a moving aluminum alloy pool is simulated by considering heat transfer, flow of liquid metal in the molten pool and solidification parameters. The computationally efficient model consists of a 3D coupled heat transfer and fluid flow simulation to predict the molten pool shape and temperature field, and a 2D model of grain formation in the molten pool. The results demonstrate that columnar grains grow in a curved pattern rather than along straight lines from the fusion boundary towards the center of the molten pool. The calculated results are validated with independent experimental data. The computed ratio of local temperature gradient to solidification rate, G/R, is used to model the columnar to equiaxed transition during solidification. The simulated results show that only curved columnar grains are formed when the scanning speed is low (2.0 mm/s). In contrast, a transition from curved columnar to equiaxed morphologies occurs at the higher scanning speeds of 8.0 mm/s and 11.5 mm/s, with higher equiaxed grain fraction at higher speed. The similarities between the physical processes governing fusion welding and additive manufacturing (AM) make the model capable of predicting grain orientation in both processes.

Nanocompositional Electron Microscopic Analysis and Role of Grain Boundary Phase of Isotropically Oriented Nd-Fe-B Magnets

Directory of Open Access Journals (Sweden)

Gregor A. Zickler

2017-01-01

Full Text Available Nanoanalytical TEM characterization in combination with finite element micromagnetic modelling clarifies the impact of the grain misalignment and grain boundary nanocomposition on the coercive field and gives guidelines how to improve coercivity in Nd-Fe-B based magnets. The nanoprobe electron energy loss spectroscopy measurements obtained an asymmetric composition profile of the Fe-content across the grain boundary phase in isotropically oriented melt-spun magnets and showed an enrichment of iron up to 60 at% in the Nd-containing grain boundaries close to Nd2Fe14B grain surfaces parallel to the c-axis and a reduced iron content up to 35% close to grain surfaces perpendicular to the c-axis. The numerical micromagnetic simulations on isotropically oriented magnets using realistic model structures from the TEM results reveal a complex magnetization reversal starting at the grain boundary phase and show that the coercive field increases compared to directly coupled grains with no grain boundary phase independently of the grain boundary thickness. This behaviour is contrary to the one in aligned anisotropic magnets, where the coercive field decreases compared to directly coupled grains with an increasing grain boundary thickness, if Js value is > 0.2 T, and the magnetization reversal and expansion of reversed magnetic domains primarily start as Bloch domain wall at grain boundaries at the prismatic planes parallel to the c-axis and secondly as Néel domain wall at the basal planes perpendicular to the c-axis. In summary our study shows an increase of coercive field in isotropically oriented Nd-Fe-B magnets for GB layer thickness > 5 nm and an average Js value of the GB layer < 0.8 T compared to the magnet with perfectly aligned grains.

Shock fabrics in fine-grained micrometeorites

Science.gov (United States)

Suttle, M. D.; Genge, M. J.; Russell, S. S.

2017-10-01

The orientations of dehydration cracks and fracture networks in fine-grained, unmelted micrometeorites were analyzed using rose diagrams and entropy calculations. As cracks exploit pre-existing anisotropies, analysis of their orientation provides a mechanism with which to study the subtle petrofabrics preserved within fine-grained and amorphous materials. Both uniaxial and biaxial fabrics are discovered, often with a relatively wide spread in orientations (40°-60°). Brittle deformation cataclasis and rotated olivine grains are reported from a single micrometeorite. This paper provides the first evidence for impact-induced shock deformation in fine-grained micrometeorites. The presence of pervasive, low-grade shock features in CM chondrites and CM-like dust, anomalously low-density measurements for C-type asteroids, and impact experiments which suggest CM chondrites are highly prone to disruption all imply that CM parent bodies are unlikely to have remained intact and instead exist as a collection of loosely aggregated rubble-pile asteroids, composed of primitive shocked clasts.

Monte Carlo simulation of grain growth

Directory of Open Access Journals (Sweden)

Paulo Blikstein

1999-07-01

Full Text Available Understanding and predicting grain growth in Metallurgy is meaningful. Monte Carlo methods have been used in computer simulations in many different fields of knowledge. Grain growth simulation using this method is especially attractive as the statistical behavior of the atoms is properly reproduced; microstructural evolution depends only on the real topology of the grains and not on any kind of geometric simplification. Computer simulation has the advantage of allowing the user to visualize graphically the procedures, even dynamically and in three dimensions. Single-phase alloy grain growth simulation was carried out by calculating the free energy of each atom in the lattice (with its present crystallographic orientation and comparing this value to another one calculated with a different random orientation. When the resulting free energy is lower or equal to the initial value, the new orientation replaces the former. The measure of time is the Monte Carlo Step (MCS, which involves a series of trials throughout the lattice. A very close relationship between experimental and theoretical values for the grain growth exponent (n was observed.

Study of rapid grain boundary migration in a nanocrystalline Ni thin film

International Nuclear Information System (INIS)

Kacher, Josh; Robertson, I.M.; Nowell, Matt; Knapp, J.; Hattar, Khalid

2011-01-01

Research highlights: → Abnormal growth is distributed randomly in the foil and initiates at different times. → Growth occurs from seemingly uncorrelated regions of the grain boundary. → Growth twins are created during all stages of abnormal grain growth. → Grain growth patterns are qualitatively similar to a vacancy diffusion model. → Grain boundaries and orientations evolve during growth to minimize system energy. - Abstract: Grain boundary migration associated with abnormal grain growth in pulsed-laser deposited Ni was studied in real time by annealing electron transparent films in situ in the transmission electron microscope. The resulting texture evolution and grain boundary types produced were evaluated by ex situ electron backscatter diffraction of interrupted anneals. The combination of these two techniques allowed for the investigation of grain growth rates, grain morphologies, and the evolution of the orientation and grain boundary distributions. Grain boundaries were found to progress in a sporadic, start/stop fashion with no evidence of a characteristic grain growth rate. The orientations of the abnormally growing grains were found to be predominately //ND throughout the annealing process. A high fraction of twin boundaries developed during the annealing process. The intermittent growth from different locations of the grain boundary is discussed in terms of a vacancy diffusion model for grain growth.

Inferential statistics of electron backscatter diffraction data from within individual crystalline grains

DEFF Research Database (Denmark)

Bachmann, Florian; Hielscher, Ralf; Jupp, Peter E.

2010-01-01

-spatial statistical analysis adapts ideas borrowed from the Bingham quaternion distribution on . Special emphasis is put on the mathematical definition and the numerical determination of a `mean orientation' characterizing the crystallographic grain as well as on distinguishing several types of symmetry......Highly concentrated distributed crystallographic orientation measurements within individual crystalline grains are analysed by means of ordinary statistics neglecting their spatial reference. Since crystallographic orientations are modelled as left cosets of a given subgroup of SO(3), the non...... of the orientation distribution with respect to the mean orientation, like spherical, prolate or oblate symmetry. Applications to simulated as well as to experimental data are presented. All computations have been done with the free and open-source texture toolbox MTEX....

Orientation and thickness dependence of magnetic levitation force and trapped magnetic field of single grain YBa{sub 2}Cu{sub 3}O{sub 7-y} bulk superconductors

Energy Technology Data Exchange (ETDEWEB)

Jung, Y.; Go, S. J.; Joo, H. T. [Korea Science Academy of Korea Advanced Institute of Science and Technology, Pusan (Korea, Republic of); Lee, Y. J.; Park, S. D.; Jun, B. H.; KIm, C. J. [Neutron Utilization Technology Division, Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2017-03-15

The effects of the crystallographic orientation and sample thickness on the magnetic levitation forces (F) and trapped magnetic field (B) of single grain YBCO bulk superconductors were examined. Single grain YBCO samples with a (001), (110) or (100) surface were used as the test samples. The samples used for the force-distance (F-d) measurement were cooled at 77 K without a magnetic field (zero field cooling, ZFC), whereas the samples used for the B measurement were cooled under the external magnetic field of a Nd-B-Fe permanent magnet (field cooling, FC). It was found that F and B of the (001) surface were higher than those of the (110) or (100) surface, which is attributed to the higher critical current density (J{sub c}) of the (001) surface. For the (001) samples with t=5–18 mm, the maximum magnetic levitation forces (F{sub max}s) of the ZFC samples were larger than 40 N. About 80% of the applied magnetic field was trapped in the FC samples. However, the F and B decreased rapidly as t decreased below 5 mm. There exists a critical sample thickness (t=5 mm for the experimental condition of this study) for maintaining the large levitation/trapping properties, which is dependent on the material properties and magnitude of the external magnetic fields.

Photoemission of Single Dust Grains for Heliospheric Conditions

Science.gov (United States)

Spann, James F., Jr.; Venturini, Catherine C.; Abbas, Mian M.; Comfort, Richard H.

2000-01-01

Initial results of an experiment to measure the photoemission of single dust grains as a function of far ultraviolet wavelengths are presented. Coulombic forces dominate the interaction of the dust grains in the heliosphere. Knowledge of the charge state of dust grains, whether in a dusty plasma (Debye length grains is primarily determined by primary electron and ion collisions, secondary electron emission and photoemission due to ultraviolet sunlight. We have established a unique experimental technique to measure the photoemission of individual micron-sized dust grains in vacuum. This technique resolves difficulties associated with statistical measurements of dust grain ensembles and non-static dust beams. The photoemission yield of Aluminum Oxide 3-micron grains For wavelengths from 120-300 nm with a spectral resolution of 1 nm FWHM is reported. Results are compared to interplanetary conditions.

Effect of loading orientations on the microstructure and property of Al−Cu single crystal during stress aging

Energy Technology Data Exchange (ETDEWEB)

Chen, Jiqiang [School of Material Science and Engineering, Central South University, Changsha 410083 (China); Chen, Zhiguo, E-mail: zgchen@mail.csu.edu.cn [School of Material Science and Engineering, Central South University, Changsha 410083 (China); Hunan University of Humanities, Science and Technology, Loudi 417000 (China); Deng, Yunlai [School of Material Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of High Performance and Complex Manufacturing, Central South University, Changsha 410083 (China); Guo, Xiaobin; Ren, Jieke [School of Material Science and Engineering, Central South University, Changsha 410083 (China)

2016-07-15

The precipitation behavior and property of Al−Cu alloy during stress aging under various loading orientations were investigated using single crystals. The resulting microstructures and the strength property were examined by transmission electron microscope (TEM) and compression test, respectively, and the effect of the distribution of θ′-plates on strength property were discussed. The results show that the precipitation distribution of θ′ was significantly affected by the loading orientation during stress aging of Al−Cu single crystals. Loading along close to 〈011〉{sub Al} directions provided more uniform precipitation distribution of θ′ as compared to loading along close to 〈001〉{sub Al} directions, and therefore provided higher strengthening stress of the θ′-plates for the stress aging sample. The results suggested that regulating the distribution of θ′ and therefore improving strength property are possible via controlling the loading orientation during stress aging. - Highlights: • We studied the effect of loading directions on stress aging of Al−Cu single crystal. • Precipitation distribution of θ′ was noticeably affected by the loading direction. • Loading along close to 〈011〉{sub Al} directions reduced the stress-orienting effect. • The strength property is closely related to the precipitation distribution of θ′. • It is possible to regulate the distribution of θ′ and improve strength property.

Barium Isotopes in Single Presolar Grains

Science.gov (United States)

Pellin, M. J.; Davis, A. M.; Savina, M. R.; Kashiv, Y.; Clayton, R. N.; Lewis, R. S.; Amari, S.

2001-01-01

Barium isotopic compositions of single presolar grains were measured by laser ablation laser resonant ionization mass spectrometry and the implications of the data for stellar processes are discussed. Additional information is contained in the original extended abstract.

Changing distribution and geometry of S′ in Al–Cu–Mg single crystals during stress aging by controlling the loading orientation

Energy Technology Data Exchange (ETDEWEB)

Chen, Jiqiang [School of Material Science and Engineering, Central South University, Yuelu Section, Changsha, Hunan 410083 (China); Chen, Zhiguo [School of Material Science and Engineering, Central South University, Yuelu Section, Changsha, Hunan 410083 (China); Hunan University of Humanities, Science and Technology, Loudi 417000 (China); Guo, Xiaobin [School of Material Science and Engineering, Central South University, Yuelu Section, Changsha, Hunan 410083 (China); Deng, Yunlai, E-mail: luckdeng@csu.edu.cn [School of Material Science and Engineering, Central South University, Yuelu Section, Changsha, Hunan 410083 (China); State Key Laboratory of High Performance and Complex Manufacturing, Central South University, Changsha 410083 (China)

2016-01-05

The precipitation behavior of S′ phase in Al–Cu–Mg single crystals during stress-free and stress aging was investigated by transmission electron microscopy (TEM). Different compressive stress magnitudes and loading orientations were applied to determine their effects on the precipitation of S′ in Al–Cu–Mg alloy during stress aging. The results indicate that a noticeable preferential orientation of S′ is generated in the sample under applied compressive stress of 33 MPa loading along close to [001]{sub Al}, whilst no obviously preferential orientation of S′ can be observed in the sample loaded along close to [101]{sub Al} under the same applied stress or even larger applied stress. The precipitation distribution of S′ phase during stress aging can be changed by the loading orientation of the applied stress. Moreover, compressive stress aging may lead to S′ phase shorter in length, and the length of S′ phase shows a decreasing tendency with increasing applied stress, which are associated with the positive misfit between S′ and Al matrix.

Determining the K-content of single-grains of feldspar for luminescence dating

International Nuclear Information System (INIS)

Smedley, R.K.; Duller, G.A.T.; Pearce, N.J.G.; Roberts, H.M.

2012-01-01

Feldspars form a solid-solution series whereby the K-content may range from 0 to 14%. LA-ICP-MS measurements for density-separated single-grains of feldspar yielded realistic concentrations of K within the range of those naturally occurring, and also highlighted the difficulty in isolating the pure end members during density-separation. No direct relationship was found between the thermal stability of the infrared-stimulated luminescence (IRSL) signal and measured K-content of individual grains. However, the brightest IRSL and post-IR IRSL signals originated from grains with ∼12% K-content. All grains giving a measurable signal had K-content between 6 and 13%, therefore it is suggested that an internal K-content of 10 ± 2% can be assumed for routine single-grain dating of density-separated K-feldspars. - Highlights: ► Measure range of K for single-grains of density separated feldspar using LA-ICP-MS. ► Single-grain thermal stability and brightness do not directly relate to K-content. ► Brightest 3 grains measured ∼12% K and provided the majority of the IRSL signals.

Effect of Primary Recrystallized Microstructure and Nitriding on Secondary Recrystallization in Grain Oriented Silicon Steel by Low Temperature Slab Reheating

Directory of Open Access Journals (Sweden)

LIU Gong-tao

2018-01-01

Full Text Available Different primary recrystallized grain sizes were obtained by controlling decarburization process in grain oriented silicon steel produced by low temperature slab reheating technique. The effect of primary grain size on secondary recrystallization and magnetic properties was studied. The appropriate nitrogen content after nitriding was explored in case of very large primary grain size, and the effect of {411}〈148〉 primary recrystallized texture on the abnormal growth behavior was discussed. The results show that an increase in average primary grain size from 10μm to 15μm leads to an increase of secondary recrystallization temperature and a sharper Goss texture with higher magnetic permeability, in the condition of a very large average primary grain size of 28μm, the suitable amount of nitrogen increases to about 6×10-4. The {411}〈148〉 oriented grains in primary recrystallized microstructure can easily grow into larger sizes due to their size advantage, and thus hinder the abnormal growth of secondary grains, moreover, the hindering effect is more pronounced in the abnormal growth of Brass-oriented grains due to their misorientation with low migration rate other than Goss grains.

Notes on representing grain size distributions obtained by electron backscatter diffraction

International Nuclear Information System (INIS)

Toth, Laszlo S.; Biswas, Somjeet; Gu, Chengfan; Beausir, Benoit

2013-01-01

Grain size distributions measured by electron backscatter diffraction are commonly represented by histograms using either number or area fraction definitions. It is shown here that they should be presented in forms of density distribution functions for direct quantitative comparisons between different measurements. Here we make an interpretation of the frequently seen parabolic tales of the area distributions of bimodal grain structures and a transformation formula between the two distributions are given in this paper. - Highlights: • Grain size distributions are represented by density functions. • The parabolic tales corresponds to equal number of grains in a bin of the histogram. • A simple transformation formula is given to number and area weighed distributions. • The particularities of uniform and lognormal distributions are examined

Austenite Grain Size Estimtion from Chord Lengths of Logarithmic-Normal Distribution

Directory of Open Access Journals (Sweden)

Adrian H.

2017-12-01

Full Text Available Linear section of grains in polyhedral material microstructure is a system of chords. The mean length of chords is the linear grain size of the microstructure. For the prior austenite grains of low alloy structural steels, the chord length is a random variable of gamma- or logarithmic-normal distribution. The statistical grain size estimation belongs to the quantitative metallographic problems. The so-called point estimation is a well known procedure. The interval estimation (grain size confidence interval for the gamma distribution was given elsewhere, but for the logarithmic-normal distribution is the subject of the present contribution. The statistical analysis is analogous to the one for the gamma distribution.

A Study on the Effects on Low Cycle Fatigue Life of a High Pressure Turbine Nozzle due to the Perturbation of Crystal Orientation of Grain of DS Materials

Energy Technology Data Exchange (ETDEWEB)

Huh, Jae Sung; Kang, Young Seok; Rhee, Dong Ho [Korea Aerospace Research Institute, Daejeon (Korea, Republic of)

2016-07-15

High pressure components of a gas turbine engine are generally made of nickel-base superalloys, using precision casting process due to complicated geometries with intricate channels and cooling holes. Turbine components manufactured from directionally solidified and single crystal materials have columnar grains; however, it is found that the crystals do not grow in its preferred direction, although the orientation can be controlled. This anisotropy can lead to the variations of elastic and Hill's parameters in constitutive equations, and they alter stress distributions and the low cycle fatigue life. We aims to evaluate the effects of perturbed crystal orientations on the structural integrity of a directionally solidified nozzle using low cycle fatigue life. We also attempt to show the necessity for the control of allowed manufacturing errors and stochastic analysis. Our approaches included conjugate heat transfer and structural analysis, along with low cycle fatigue life assessment.

Precipitation of grain boundary α in a laser deposited compositionally graded Ti-8Al-xV alloy - an orientation microscopy study

International Nuclear Information System (INIS)

Banerjee, R.; Bhattacharyya, D.; Collins, P.C.; Viswanathan, G.B.; Fraser, H.L.

2004-01-01

A graded ternary Ti-8Al-xV alloy (all compositions in wt%) has been deposited using the laser engineered net-shaping (LENS TM ) process. A compositional gradient in the alloy, from binary Ti-8Al to Ti-8Al-20V, has been achieved within a length of ∼25 mm. The feedstock used for depositing the graded alloy consisted of elemental Ti, Al, and V powders. Due to the columnar growth morphology of the β grains in these LENS TM deposited Ti alloys, the same prior β grain boundary often extends across lengths ∼10 mm. Using orientation microscopy techniques in a scanning electron microscope, the crystallography of precipitation of grain boundary α across the same boundary with changing composition has been investigated in detail. It was observed that while most grain boundary α precipitates maintain a Burgers or near-Burgers orientation relationship with only one of the β grains, a few of these precipitates develop a Burgers orientation relationship with the other β grain. In some rare instances, the grain boundary α did not develop a Burgers or near-Burgers orientation relationship with either β grains. Interestingly, in many cases while the grain boundary α maintained Burgers relationship with one of the β grains, precipitates of two different variants decorated the boundary, in a near-alternate fashion

Effect of grain orientation and heat treatment on mechanical properties of pure W

Energy Technology Data Exchange (ETDEWEB)

Noto, Hiroyuki, E-mail: noto_hiroyuki@iae.kyoto-u.ac.jp [Graduate School of Energy Science, Kyoto University, Kyoto 611-0011 (Japan); Research Fellow of Japan Society for the Promotion of Science (Japan); Taniguchi, Shuichi [Graduate School of Energy Science, Kyoto University, Kyoto 611-0011 (Japan); Kurishita, Hiroaki; Matsuo, Satoru [International Research Center for Nuclear Materials Science, Institute for Materials Research, Tohoku University, Oarai, Ibaraki 311-1313 (Japan); Ukita, Takashi; Tokunaga, Kazutoshi [Institute for Applied Mechanics, Kyushu University, Kasuga, Fukuoka 816-8580 (Japan); Kimura, Akihiko [Institute of Advanced Energy, Kyoto University, Kyoto 611-0011 (Japan)

2014-12-15

The effect of grain orientation, heat-treatment temperature and test temperature on the mechanical properties of tungsten (W), which vary depending on plastic working and fabrication process, was investigated by mechanical testing of tensile or bending. Heavily worked W samples (1.5–2.0 mm in the final thickness) exhibit degradation of fracture strength due to recrystallization embrittlement after heat-treatment at 1240 °C (temperature of diffusion bonding between W and a candidate material of the Fe base support structure). On the other hand, W samples with lower thickness reduction rates do not suffer degradation of fracture strength after heating up to around 1300 °C, and show somewhat higher fracture strength by heat-treatment below 1300 °C than the samples in the as-received state. The observed behavior is a reflection of recovery of dislocations introduced by plastic working. High temperature tensile testing of ITER grade W with an anisotropic grain structure and S-TUN with an equiaxed grain structure revealed that both W grades exhibit plastic elongation at temperatures higher than 200 °C with essentially the same temperature dependence of yield strength, which is relatively insensitive to grain orientation in the structure at 200–1300 °C.

Effect of grain orientation and heat treatment on mechanical properties of pure W

International Nuclear Information System (INIS)

Noto, Hiroyuki; Taniguchi, Shuichi; Kurishita, Hiroaki; Matsuo, Satoru; Ukita, Takashi; Tokunaga, Kazutoshi; Kimura, Akihiko

2014-01-01

The effect of grain orientation, heat-treatment temperature and test temperature on the mechanical properties of tungsten (W), which vary depending on plastic working and fabrication process, was investigated by mechanical testing of tensile or bending. Heavily worked W samples (1.5–2.0 mm in the final thickness) exhibit degradation of fracture strength due to recrystallization embrittlement after heat-treatment at 1240 °C (temperature of diffusion bonding between W and a candidate material of the Fe base support structure). On the other hand, W samples with lower thickness reduction rates do not suffer degradation of fracture strength after heating up to around 1300 °C, and show somewhat higher fracture strength by heat-treatment below 1300 °C than the samples in the as-received state. The observed behavior is a reflection of recovery of dislocations introduced by plastic working. High temperature tensile testing of ITER grade W with an anisotropic grain structure and S-TUN with an equiaxed grain structure revealed that both W grades exhibit plastic elongation at temperatures higher than 200 °C with essentially the same temperature dependence of yield strength, which is relatively insensitive to grain orientation in the structure at 200–1300 °C

Influence of crystal orientation on magnetostriction waveform in grain orientated electrical steel

Energy Technology Data Exchange (ETDEWEB)

Kijima, Gou, E-mail: g-kijima@jfe-steel.co.jp [Steel Research Laboratory, JFE Steel Corporation, Kawasaki, 210-0855 (Japan); Yamaguchi, Hiroi; Senda, Kunihiro; Hayakawa, Yasuyuki [Steel Research Laboratory, JFE Steel Corporation, Kurashiki, 712-8511 (Japan)

2014-08-01

Aiming to gain insight into the mechanisms of grain-oriented electrical steel sheet magnetostriction waveforms, we investigated the influence of crystal orientations. An increase in the β angle results in an increase in the amplitude of magnetostriction waveform, but does not affect the waveform itself. By slanting the excitation direction to simulate the change of the α angle, change in the magnetostriction waveform and a constriction–extension transition point in the steel plate was observed. The amplitude, however, was not significantly affected. We explained the nature of constriction–extension transition point in the magnetostriction waveform by considering the magnetization rotation. We speculated that the change of waveform resulting from the increase in the coating tensile stress can be attributed to the phenomenon of the magnetization rotation becoming hard to be generated due to the increase of magnetic anisotropy toward [001] axis. - Highlights: • β angle is related with the amplitude of magnetostriction waveform. • α angle is related with the magnetostriction waveform itself. • The effect of α angle can be controlled by the effect of coating tensile stress.

Electrodeposited copper oxide films: Effect of bath pH on grain orientation and orientation-dependent interfacial behavior

International Nuclear Information System (INIS)

Wang, L.C.; Tacconi, N.R. de; Chenthamarakshan, C.R.; Rajeshwar, K.; Tao, M.

2007-01-01

Copper (I) oxide (Cu 2 O) films were cathodically electrodeposited on Sn-doped indium oxide substrates. The influence of electrodeposition bath pH on grain orientation and crystallite shape was carefully re-examined using X-ray diffraction and scanning electron microscopy. In addition to the (100) and (111) preferred orientations identified in two previous sets of studies, as the bath pH was varied in the present study from ∼ 7.5 to ∼ 12, a third preferred orientation, (110), was identified in a narrow pH range, ∼ 9.4 to ∼ 9.9. A remarkable shift in the flat-band potential (spanning ∼ 500 mV) was measured in a non-aqueous electrolyte medium for the various Cu 2 O samples obtained from baths of varying pH

Spatially resolved acoustic spectroscopy for rapid imaging of material microstructure and grain orientation

International Nuclear Information System (INIS)

Smith, Richard J; Li, Wenqi; Coulson, Jethro; Clark, Matt; Somekh, Michael G; Sharples, Steve D

2014-01-01

Measuring the grain structure of aerospace materials is very important to understand their mechanical properties and in-service performance. Spatially resolved acoustic spectroscopy is an acoustic technique utilizing surface acoustic waves to map the grain structure of a material. When combined with measurements in multiple acoustic propagation directions, the grain orientation can be obtained by fitting the velocity surface to a model. The new instrument presented here can take thousands of acoustic velocity measurements per second. The spatial and velocity resolution can be adjusted by simple modification to the system; this is discussed in detail by comparison of theoretical expectations with experimental data. (paper)

The Relevance of Grain Dissection for Grain Size Reduction in Polar Ice: Insights from Numerical Models and Ice Core Microstructure Analysis

Directory of Open Access Journals (Sweden)

Florian Steinbach

2017-09-01

Full Text Available The flow of ice depends on the properties of the aggregate of individual ice crystals, such as grain size or lattice orientation distributions. Therefore, an understanding of the processes controlling ice micro-dynamics is needed to ultimately develop a physically based macroscopic ice flow law. We investigated the relevance of the process of grain dissection as a grain-size-modifying process in natural ice. For that purpose, we performed numerical multi-process microstructure modeling and analyzed microstructure and crystallographic orientation maps from natural deep ice-core samples from the North Greenland Eemian Ice Drilling (NEEM project. Full crystallographic orientations measured by electron backscatter diffraction (EBSD have been used together with c-axis orientations using an optical technique (Fabric Analyser. Grain dissection is a feature of strain-induced grain boundary migration. During grain dissection, grain boundaries bulge into a neighboring grain in an area of high dislocation energy and merge with the opposite grain boundary. This splits the high dislocation-energy grain into two parts, effectively decreasing the local grain size. Currently, grain size reduction in ice is thought to be achieved by either the progressive transformation from dislocation walls into new high-angle grain boundaries, called subgrain rotation or polygonisation, or bulging nucleation that is assisted by subgrain rotation. Both our time-resolved numerical modeling and NEEM ice core samples show that grain dissection is a common mechanism during ice deformation and can provide an efficient process to reduce grain sizes and counter-act dynamic grain-growth in addition to polygonisation or bulging nucleation. Thus, our results show that solely strain-induced boundary migration, in absence of subgrain rotation, can reduce grain sizes in polar ice, in particular if strain energy gradients are high. We describe the microstructural characteristics that can be

The relevance of grain dissection for grain size reduction in polar ice: insights from numerical models and ice core microstructure analysis

Science.gov (United States)

Steinbach, Florian; Kuiper, Ernst-Jan N.; Eichler, Jan; Bons, Paul D.; Drury, Martyn R.; Griera, Albert; Pennock, Gill M.; Weikusat, Ilka

2017-09-01

The flow of ice depends on the properties of the aggregate of individual ice crystals, such as grain size or lattice orientation distributions. Therefore, an understanding of the processes controlling ice micro-dynamics is needed to ultimately develop a physically based macroscopic ice flow law. We investigated the relevance of the process of grain dissection as a grain-size-modifying process in natural ice. For that purpose, we performed numerical multi-process microstructure modelling and analysed microstructure and crystallographic orientation maps from natural deep ice-core samples from the North Greenland Eemian Ice Drilling (NEEM) project. Full crystallographic orientations measured by electron backscatter diffraction (EBSD) have been used together with c-axis orientations using an optical technique (Fabric Analyser). Grain dissection is a feature of strain-induced grain boundary migration. During grain dissection, grain boundaries bulge into a neighbouring grain in an area of high dislocation energy and merge with the opposite grain boundary. This splits the high dislocation-energy grain into two parts, effectively decreasing the local grain size. Currently, grain size reduction in ice is thought to be achieved by either the progressive transformation from dislocation walls into new high-angle grain boundaries, called subgrain rotation or polygonisation, or bulging nucleation that is assisted by subgrain rotation. Both our time-resolved numerical modelling and NEEM ice core samples show that grain dissection is a common mechanism during ice deformation and can provide an efficient process to reduce grain sizes and counter-act dynamic grain-growth in addition to polygonisation or bulging nucleation. Thus, our results show that solely strain-induced boundary migration, in absence of subgrain rotation, can reduce grain sizes in polar ice, in particular if strain energy gradients are high. We describe the microstructural characteristics that can be used to

Comparison of Deformation in High-Purity Single/Large Grain and Polycrystalline Niobium Superconducting Cavities

International Nuclear Information System (INIS)

Ganapati Rao Myneni; Peter Kneisel

2005-01-01

The current approach for the fabrication of superconducting radio frequency (SRF) cavities is to roll and deep draw sheets of polycrystalline high-purity niobium. Recently, a new technique was developed at Jefferson Laboratory that enables the fabrication of single-crystal high-purity Nb SRF cavities. To better understand the differences between SRF cavities fabricated out of fine-grained polycrystalline sheet in the standard manner and single crystal cavities fabricated by the new technique, two half-cells were produced according to the two different procedures and compared using a variety of analytical techniques including optical microscopy, scanning laser confocal microscopy, profilometry, and X-ray diffraction. Crystallographic orientations, texture, and residual stresses were determined in the samples before and after forming and this poster presents the results of this ongoing study

Investigation of cross talk in single grain luminescence measurements using an EMCCD camera

International Nuclear Information System (INIS)

Gribenski, Natacha; Preusser, Frank; Greilich, Steffen; Huot, Sebastien; Mittelstraß, Dirk

2015-01-01

Highly sensitive electron multiplying charges coupled devices (EMCCD) enable the spatial detection of luminescence emissions from samples and have a high potential in single grain luminescence dating. However, the main challenge of this approach is the potential effect of cross talk, i.e. the influence of signal emitted by neighbouring grains, which will bias the information recorded from individual grains. Here, we present the first investigations into this phenomenon when performing single grain luminescence measurements of quartz grains spread over the flat surface of a sample carrier. Dose recovery tests using mixed populations show an important effect of cross talk, even when some distance is kept between grains. This issue is further investigated by focusing just on two grains and complemented by simulated experiments. Creation of an additional rejection criteria based on the brightness properties of the grains is inefficient in selecting grains unaffected by their surroundings. Therefore, the use of physical approaches or image processing algorithms to directly counteract cross talk is essential to allow routine single grain luminescence dating using EMCCD cameras. - Highlights: • We have performed single grain OSL measurements using an EMCCD detector. • Individual equivalent dose cannot be accurately recovered from a mixed dose population. • Grains are influenced by signal emitted by their neighbours during the measurements. • Simulated data confirm the strong effect of this phenomenon. • Increasing the distance between grains or applying brightness criteria are inefficient.

Influence of Substrate on Crystal Orientation of Large-Grained Si Thin Films Formed by Metal-Induced Crystallization

Directory of Open Access Journals (Sweden)

Kaoru Toko

2015-01-01

Full Text Available Producing large-grained polycrystalline Si (poly-Si film on glass substrates coated with conducting layers is essential for fabricating Si thin-film solar cells with high efficiency and low cost. We investigated how the choice of conducting underlayer affected the poly-Si layer formed on it by low-temperature (500°C Al-induced crystallization (AIC. The crystal orientation of the resulting poly-Si layer strongly depended on the underlayer material: (100 was preferred for Al-doped-ZnO (AZO and indium-tin-oxide (ITO; (111 was preferred for TiN. This result suggests Si heterogeneously nucleated on the underlayer. The average grain size of the poly-Si layer reached nearly 20 µm for the AZO and ITO samples and no less than 60 µm for the TiN sample. Thus, properly electing the underlayer material is essential in AIC and allows large-grained Si films to be formed at low temperatures with a set crystal orientation. These highly oriented Si layers with large grains appear promising for use as seed layers for Si light-absorption layers as well as for advanced functional materials.

Place oriented ecological footprint analysis. The case of Israel's grain supply

International Nuclear Information System (INIS)

Kissinger, Meidad; Gottlieb, Dan

2010-01-01

In today's world, any nation's ecological footprint is spread all over the globe. Still, most footprint studies are not yet sensitive to the specific locations on which the footprint falls and to the unique production characteristics of each supporting region. In recent years some studies have acknowledged the need to quantify the 'real land' footprints and particularly the share of the footprint embodied in trade. Our goal is to analyse the ecological footprint of grain-based consumption in the state of Israel during the last two decades. We present a detailed, place oriented calculation procedure of Israel's grain footprint on specific locations around the world. We document modes of production, major energy inputs in specific sources of supply, the energy required for shipping from each source, and the CO 2 emissions from those operations. Our research reveals that most of Israel's grain footprint falls on North America followed by the Black Sea region. It also shows that while the overall consumption of grain products has increased throughout the research period, the size of the footprint has been dropping in recent years as a consequence of changing sources of supply and grain composition. Finally, we discuss some of the implications of the method presented here for future footprint calculations and environmental resource management. (author)

NON-COHESIVE SOILS’ COMPRESSIBILITY AND UNEVEN GRAIN-SIZE DISTRIBUTION RELATION

Directory of Open Access Journals (Sweden)

Anatoliy Mirnyy

2016-03-01

Full Text Available This paper presents the results of laboratory investigation of soil compression phases with consideration of various granulometric composition. Materials and Methods Experimental soil box with microscale video recording for compression phases studies is described. Photo and video materials showing the differences of microscale particle movements were obtained for non-cohesive soils with different grain-size distribution. Results The analysis of the compression tests results and elastic and plastic deformations separation allows identifying each compression phase. It is shown, that soil density is correlating with deformability parameters only for the same grain-size distribution. Basing on the test results the authors suggest that compaction ratio is not sufficient for deformability estimating without grain-size distribution taken into account. Discussion and Conclusions Considering grain-size distribution allows refining technological requirements for artificial soil structures, backfills, and sand beds. Further studies could be used for developing standard documents, SP45.13330.2012 in particular.

Some regularity of the grain size distribution in nuclear fuel with controllable structure

International Nuclear Information System (INIS)

Loktev, Igor

2008-01-01

It is known, the fission gas release from ceramic nuclear fuel depends from average size of grains. To increase grain size they use additives which activate sintering of pellets. However, grain size distribution influences on fission gas release also. Fuel with different structures, but with the same average size of grains has different fission gas release. Other structure elements, which influence operational behavior of fuel, are pores and inclusions. Earlier, in Kyoto, questions of distribution of grain size for fuel with 'natural' structure were discussed. Some regularity of grain size distribution of fuel with controllable structure and high average size of grains are considered in the report. Influence of inclusions and pores on an error of the automated definition of parameters of structure is shown. The criterion, which describe of behavior of fuel with specific grain size distribution, is offered

Influence of initial heating during final high temperature annealing on the offset of primary and secondary recrystallization in Cu-bearing grain oriented electrical steels

Science.gov (United States)

Rodriguez-Calvillo, P.; Leunis, E.; Van De Putte, T.; Jacobs, S.; Zacek, O.; Saikaly, W.

2018-04-01

The industrial production route of Grain Oriented Electrical Steels (GOES) is complex and fine-tuned for each grade. Its metallurgical process requires in all cases the abnormal grain growth (AGG) of the Goss orientation during the final high temperature annealing (HTA). The exact mechanism of AGG is not yet fully understood, but is controlled by the different inhibition systems, namely MnS, AlN and CuxS, their size and distribution, and the initial primary recrystallized grain size. Therefore, among other parameters, the initial heating stage during the HTA is crucial for the proper development of primary and secondary recrystallized microstructures. Cold rolled 0.3 mm Cu-bearing Grain Oriented Electrical Steel has been submitted to interrupted annealing experiments in a lab tubular furnace. Two different annealing cycles were applied:• Constant heating at 30°C/h up to 1000°C. Two step cycle with initial heating at 100°C/h up to 600°C, followed by 18 h soaking at 600°C and then heating at 30°C/h up to 1050°C. The materials are analyzed in terms of their magnetic properties, grain size, texture and precipitates. The characteristic magnetic properties are analyzed for the different extraction temperatures and Cycles. As the annealing was progressing, the coercivity values (Hc 1.7T [A/m]) decreased, showing two abrupt drops, which can be associated to the on-set of primary and secondary recrystallization. The primary recrystallized grain sizes and recrystallized fractions are fitted to a model using a non-isothermal approach. This analysis shows that, although the resulting grain sizes were similar, the kinetics for the two step annealing were faster due to the lower recovery. The on-set of secondary recrystallization was also shifted to higher temperatures in the case of the continuous heating cycle, which might end in different final grain sizes and final magnetic properties. In both samples, nearly all the observed precipitates are Al-Si-Mn nitrides

Influence of initial heating during final high temperature annealing on the offset of primary and secondary recrystallization in Cu-bearing grain oriented electrical steels

Directory of Open Access Journals (Sweden)

P. Rodriguez-Calvillo

2018-04-01

Full Text Available The industrial production route of Grain Oriented Electrical Steels (GOES is complex and fine-tuned for each grade. Its metallurgical process requires in all cases the abnormal grain growth (AGG of the Goss orientation during the final high temperature annealing (HTA. The exact mechanism of AGG is not yet fully understood, but is controlled by the different inhibition systems, namely MnS, AlN and CuxS, their size and distribution, and the initial primary recrystallized grain size. Therefore, among other parameters, the initial heating stage during the HTA is crucial for the proper development of primary and secondary recrystallized microstructures. Cold rolled 0.3 mm Cu-bearing Grain Oriented Electrical Steel has been submitted to interrupted annealing experiments in a lab tubular furnace. Two different annealing cycles were applied:• Constant heating at 30°C/h up to 1000°C. Two step cycle with initial heating at 100°C/h up to 600°C, followed by 18 h soaking at 600°C and then heating at 30°C/h up to 1050°C. The materials are analyzed in terms of their magnetic properties, grain size, texture and precipitates. The characteristic magnetic properties are analyzed for the different extraction temperatures and Cycles. As the annealing was progressing, the coercivity values (Hc 1.7T [A/m] decreased, showing two abrupt drops, which can be associated to the on-set of primary and secondary recrystallization. The primary recrystallized grain sizes and recrystallized fractions are fitted to a model using a non-isothermal approach. This analysis shows that, although the resulting grain sizes were similar, the kinetics for the two step annealing were faster due to the lower recovery. The on-set of secondary recrystallization was also shifted to higher temperatures in the case of the continuous heating cycle, which might end in different final grain sizes and final magnetic properties. In both samples, nearly all the observed precipitates are Al

SPICE Modeling of Single-Grain Si TFTs using BSIMSOI

NARCIS (Netherlands)

Baiano, A.; Ishihara, R.; Saputra, N.; Long, J.; Karaki, N.; Inoue, S.; Metselaar, W.; Beenakker, C.I.M.

2007-01-01

Single Grain Thin-film transistors (SG-TFTs) fabricated inside a location-controlled grain by µ-Czochralski process have as high as SOI performance. To model them, BSIMSOI with a proper modification of the mobility is proposed. The model has been verified for n- and p-channel DC and low frequency AC

Single Molecule 3D Orientation in Time and Space: A 6D Dynamic Study on Fluorescently Labeled Lipid Membranes

DEFF Research Database (Denmark)

Börner, Richard; Ehrlich, Nicky; Hohlbein, Johannes

2016-01-01

Interactions between single molecules profoundly depend on their mutual three-dimensional orientation. Recently, we demonstrated a technique that allows for orientation determination of single dipole emitters using a polarization-resolved distribution of fluorescence into several detection channels...... interesting in non-isotropic environments such as lipid membranes, which are of great importance in biology. We used giant unilamellar vesicles (GUVs) labeled with fluorescent dyes down to a single molecule concentration as a model system for both, assessing the robustness of the orientation determination...

Recent progress in large grain/single crystal high RRR niobium

International Nuclear Information System (INIS)

Ganapati Rao Myneni; Peter Kneisel; Tadeu Carneiro; S.R. Agnew; F. Stevie

2005-01-01

High RRR bulk niobium Superconducting Radio Frequency (SRF) cavity technology is chosen for the International Linear Collider (ILC). The SRF community was convinced until now that fine grain polycrystalline RRR niobium sheets obtained via forging and cross rolling are essential for forming the SRF Cavities. However, it was recently discovered under a joint Reference Metals Company, Inc., - JLAB CRADA that large grain/single crystal RRR niobium sliced directly from ingots is highly ductile reaching 100 percent elongation. This discovery led to the successful fabrication of several SRF single and/or multi cell structures, formed with sliced RRR discs from the ingots, operating at 2.3, 1.5 and 1.3 GHz. This new exciting development is expected to offer high performance accelerator structures not only at reduced costs but also with simpler fabrication and processing conditions. As a result there is a renewed interest in the evaluation and understanding of the large grain and single crystal niobium with respect to their mechanical and physical properties as well as the oxidation behavior and the influence of impurities such as hydrogen and Ta. In this paper the results of many collaborative studies on large grain and single crystal high RRR niobium between JLAB, Universities and Industry are presented

Three-dimensional investigation of grain orientation effects on void growth in commercially pure titanium

International Nuclear Information System (INIS)

Pushkareva, Marina; Adrien, Jérôme; Maire, Eric; Segurado, Javier; Llorca, Javier; Weck, Arnaud

2016-01-01

The fracture process of commercially pure titanium was visualized in model materials containing artificial holes. These model materials were fabricated using a femtosecond laser coupled with a diffusion bonding technique to obtain voids in the interior of titanium samples. Changes in void dimensions during in-situ straining were recorded in three dimensions using x-ray computed tomography. Void growth obtained experimentally was compared with the Rice and Tracey model which predicted well the average void growth. A large scatter in void growth data was explained by differences in grain orientation which was confirmed by crystal plasticity simulations. It was also shown that grain orientation has a stronger effect on void growth than intervoid spacing and material strength. Intervoid spacing, however, appears to control whether the intervoid ligament failure is ductile or brittle.

Three-dimensional investigation of grain orientation effects on void growth in commercially pure titanium

Energy Technology Data Exchange (ETDEWEB)

Pushkareva, Marina [Department of Mechanical Engineering, University of Ottawa, 150 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); Adrien, Jérôme; Maire, Eric [Université de Lyon, INSA-Lyon, MATEIS CNRS UMR5510, 7 Avenue Jean Capelle, F-69621 Villeurbanne (France); Segurado, Javier; Llorca, Javier [IMDEA Materials Institute, C/Eric Kandel 2, 28906 Getafe, Madrid (Spain); Department of Materials Science, Polytechnic University of Madrid, E. T. S. de Ingenieros de Caminos, 28040 Madrid (Spain); Weck, Arnaud, E-mail: aweck@uottawa.ca [Department of Mechanical Engineering, University of Ottawa, 150 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); IMDEA Materials Institute, C/Eric Kandel 2, 28906 Getafe, Madrid (Spain); Department of Physics, University of Ottawa, 150 Louis Pasteur, Ottawa, ON, Canada K1N 6N5 (Canada); Centre for Research in Photonics at the University of Ottawa, 800 King Edward Ave., Ottawa, ON, Canada K1N 6N5 (Canada)

2016-08-01

The fracture process of commercially pure titanium was visualized in model materials containing artificial holes. These model materials were fabricated using a femtosecond laser coupled with a diffusion bonding technique to obtain voids in the interior of titanium samples. Changes in void dimensions during in-situ straining were recorded in three dimensions using x-ray computed tomography. Void growth obtained experimentally was compared with the Rice and Tracey model which predicted well the average void growth. A large scatter in void growth data was explained by differences in grain orientation which was confirmed by crystal plasticity simulations. It was also shown that grain orientation has a stronger effect on void growth than intervoid spacing and material strength. Intervoid spacing, however, appears to control whether the intervoid ligament failure is ductile or brittle.

Interior seeding for the fabrication of single-grain REBCO bulk superconductors

International Nuclear Information System (INIS)

Kim, C-J; Park, S-D; Jun, B-H; Park, H-W

2016-01-01

This study presents a new seeding technique, named ‘interior seeding’ which allows the growth of a single REBCO (RE: rare-earth elements) grain in the interior of REBCO compacts. The key techniques of interior seeding are to provide appropriate open space for seeds in the interior of REBCO powder compacts to supply air or oxygen to the seeds, and to minimize the contact area between the seeds and liquid. The advantages of interior seeding are as follows: (1) simultaneous growth from the seed to the top and bottom of the REBCO compacts is possible, (2) fractions of the a-b growth sector and the a-c growth sector on the top surface can be controlled and (3) the top surfaces of the single-grain REBCO bulk superconductors are free from samarium or neodymium contamination from the used seeds. The very large single-grain Y 1.5 Ba 2 Cu 3 O 7−y (Y1.5) bulk superconductors (42 mm) were successfully fabricated using a melt growth (MG) process combined with interior seeding. Also, large-grain Y1.5 bulk superconductors (41 mm) with 〈110〉/〈110〉 and 〈100〉/〈100〉 grain junctions were fabricated using multiple interior seeding. In this paper, the detailed process of interior seeding, the development of top surface patterns and the properties of single-grain Y123 bulk superconductors fabricated using interior seeding were reported. (paper)

Bandgap tunability at single-layer molybdenum disulphide grain boundaries

KAUST Repository

Huang, Yu Li

2015-02-17

Two-dimensional transition metal dichalcogenides have emerged as a new class of semiconductor materials with novel electronic and optical properties of interest to future nanoelectronics technology. Single-layer molybdenum disulphide, which represents a prototype two-dimensional transition metal dichalcogenide, has an electronic bandgap that increases with decreasing layer thickness. Using high-resolution scanning tunnelling microscopy and spectroscopy, we measure the apparent quasiparticle energy gap to be 2.40±0.05 eV for single-layer, 2.10±0.05 eV for bilayer and 1.75±0.05 eV for trilayer molybdenum disulphide, which were directly grown on a graphite substrate by chemical vapour deposition method. More interestingly, we report an unexpected bandgap tunability (as large as 0.85±0.05 eV) with distance from the grain boundary in single-layer molybdenum disulphide, which also depends on the grain misorientation angle. This work opens up new possibilities for flexible electronic and optoelectronic devices with tunable bandgaps that utilize both the control of two-dimensional layer thickness and the grain boundary engineering.

The magnetized sheath of a dusty plasma with grains size distribution

International Nuclear Information System (INIS)

Ou, Jing; Gan, Chunyun; Lin, Binbin; Yang, Jinhong

2015-01-01

The structure of a plasma sheath in the presence of dust grains size distribution (DGSD) is investigated in the multi-fluid framework. It is shown that effect of the dust grains with different sizes on the sheath structure is a collective behavior. The spatial distributions of electric potential, the electron and ion densities and velocities, and the dust grains surface potential are strongly affected by DGSD. The dynamics of dust grains with different sizes in the sheath depend on not only DGSD but also their radius. By comparison of the sheath structure, it is found that under the same expected value of DGSD condition, the sheath length is longer in the case of lognormal distribution than that in the case of uniform distribution. In two cases of normal and lognormal distributions, the sheath length is almost equal for the small variance of DGSD, and then the difference of sheath length increases gradually with increase in the variance

Effect of grain alignment distribution on magnetic properties in (MM, Nd)-Fe-B sintered magnets

Science.gov (United States)

Yu, Xiaoqiang; Yue, Ming; Zhu, Minggang; Liu, Weiqiang; Li, Yuqing; Xi, Longlong; Li, Jiajie; Zhang, Jiuxing; Li, Wei

2018-03-01

H cj of (MM x Nd1-x )-Fe-B sintered magnets decreases distinctly with x increasing when misch metal (MM) content (x) ranges from 0.3 to 1. Practical application is taken into consideration so that the (MM0.6Nd0.4)-Fe-B components are chosen to analyze the changes in behavior of the magnetic properties. Both Magnet II and Magnet III belong to (MM0.6Nd0.4)-Fe-B sintered magnets, however, it should be noted that Magnet II is prepared by the single alloying method (SAM) and Magnet III is prepared by the double main phase alloy method (DMPAM). Core-shell structures of the magnets prepared by DMPAM can result in the higher H cj and lower knee-point coercivity (H k) compared with that by SAM. Furthermore, for Magnet II, the abnormal grain growth contributes to a better grain alignment and smaller distribution coefficient (σ) defined as the degree of grain alignment, which will enforce a higher tendency of the H cj decreasing and H k increasing. The expression of their normalized coercivity h(σ) is deduced by combining Gao’s starting field model with Kronmüller’s nucleation mechanism. Based on the overall h(σ) ~ σ curve, the best desirable h(σ) value is calculated when σ  =  0.09. Theoretically, for Magnet III, the resultant larger σ should be attributed to the more uniform grain alignment. In addition, the deviations of grain size distributions on the c-plane become more remarkable with more MM concentrates, which can be presented by SEM images. Meanwhile, by means of the pole figures, it is also verified that the grain alignment distribution becomes much more diverse with x increasing. Therefore, it can be predicted whether the grain alignment distribution is significant for H k and H cj of (MM x Nd1-x )-Fe-B sintered magnets (x  ≠  0.6) prepared by SAM/DMPAM or not.

The role of grain size in He bubble formation: Implications for swelling resistance

Science.gov (United States)

El-Atwani, O.; Nathaniel, J. E.; Leff, A. C.; Muntifering, B. R.; Baldwin, J. K.; Hattar, K.; Taheri, M. L.

2017-02-01

Nanocrystalline metals are postulated as radiation resistant materials due to their high defect and particle (e.g. Helium) sink density. Here, the performance of nanocrystalline iron films is investigated in-situ in a transmission electron microscope (TEM) using He irradiation at 700 K. Automated crystal orientation mapping is used in concert with in-situ TEM to explore the role of grain orientation and grain boundary character on bubble density trends. Bubble density as a function of three key grain size regimes is demonstrated. While the overall trend revealed an increase in bubble density up to a saturation value, grains with areas ranging from 3000 to 7500 nm2 show a scattered distribution. An extrapolated swelling resistance based on bubble size and areal density indicated that grains with sizes less than 2000 nm2 possess the greatest apparent resistance. Moreover, denuded zones are found to be independent of grain size, grain orientation, and grain boundary misorientation angle.

The role of grain size in He bubble formation: Implications for swelling resistance

Energy Technology Data Exchange (ETDEWEB)

El-Atwani, O., E-mail: oelatwan25@gmail.com [Drexel University, Department of Materials Science & Engineering, Philadelphia, PA (United States); Nathaniel, J.E.; Leff, A.C. [Drexel University, Department of Materials Science & Engineering, Philadelphia, PA (United States); Muntifering, B.R. [Department of Radiation Solid Interactions, Sandia National Laboratories, NM (United States); Baldwin, J.K. [Center for Integrated Nanotechnologies, Los Alamos National Laboratory, Los Alamos, NM (United States); Hattar, K. [Department of Radiation Solid Interactions, Sandia National Laboratories, NM (United States); Taheri, M.L. [Drexel University, Department of Materials Science & Engineering, Philadelphia, PA (United States)

2017-02-15

Nanocrystalline metals are postulated as radiation resistant materials due to their high defect and particle (e.g. Helium) sink density. Here, the performance of nanocrystalline iron films is investigated in-situ in a transmission electron microscope (TEM) using He irradiation at 700 K. Automated crystal orientation mapping is used in concert with in-situ TEM to explore the role of grain orientation and grain boundary character on bubble density trends. Bubble density as a function of three key grain size regimes is demonstrated. While the overall trend revealed an increase in bubble density up to a saturation value, grains with areas ranging from 3000 to 7500 nm{sup 2} show a scattered distribution. An extrapolated swelling resistance based on bubble size and areal density indicated that grains with sizes less than 2000 nm{sup 2} possess the greatest apparent resistance. Moreover, denuded zones are found to be independent of grain size, grain orientation, and grain boundary misorientation angle.

A novel ultra-low carbon grain oriented silicon steel produced by twin-roll strip casting

Energy Technology Data Exchange (ETDEWEB)

Wang, Yang, E-mail: wy069024019@163.com [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Zhang, Yuan-Xiang; Lu, Xiang; Fang, Feng; Xu, Yun-Bo; Cao, Guang-Ming; Li, Cheng-Gang [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China); Misra, R.D.K. [Laboratory for Excellence in Advanced Steel Research, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, TX 79968 (United States); Wang, Guo-Dong [State Key Laboratory of Rolling and Automation, Northeastern University, Shenyang 110819 (China)

2016-12-01

A novel ultra-low carbon grain oriented silicon steel was successfully produced by strip casting and two-stage cold rolling method. The microstructure, texture and precipitate evolution under different first cold rolling reduction were investigated. It was shown that the as-cast strip was mainly composed of equiaxed grains and characterized by very weak Goss texture ({110}<001>) and λ-fiber (<001>//ND). The coarse sulfides of size ~100 nm were precipitated at grain boundaries during strip casting, while nitrides remained in solution in the as-cast strip and the fine AlN particles of size ~20–50 nm, which were used as grain growth inhibitors, were formed in intermediate annealed sheet after first cold rolling. In addition, the suitable Goss nuclei for secondary recrystallization were also formed during intermediate annealing, which is totally different from the conventional process that the Goss nuclei originated in the subsurface layer of the hot rolled sheet. Furthermore, the number of AlN inhibitors and the intensity of desirable Goss texture increased with increasing first cold rolling reduction. After secondary recrystallization annealing, very large grains of size ~10–40 mm were formed and the final magnetic induction, B{sub 8}, was as high as 1.9 T. - Highlights: • A novel chemical composition base on strip casting silicon steel was proposed. • The ultra-low carbon design could shorten the processing routes. • The novel composition and processes were beneficial to obtain more inhibitors. • The magnetic induction of grain oriented silicon steel was significantly improved.

Effect of texture and grain size on magnetic flux density and core loss in non-oriented electrical steel containing 3.15% Si

Energy Technology Data Exchange (ETDEWEB)

Lee, K.M.; Park, S.Y. [Department of Materials Science and Engineering, Korea University, 5-1, Anam-dong, Sungbuk-Gu, Seoul 136-701 (Korea, Republic of); Huh, M.Y., E-mail: myhuh@korea.ac.kr [Department of Materials Science and Engineering, Korea University, 5-1, Anam-dong, Sungbuk-Gu, Seoul 136-701 (Korea, Republic of); Kim, J.S. [Electrical Steel Sheet Research Group, Technical Research Laboratories, POSCO, Goedong-dong, Pohang (Korea, Republic of); Engler, O. [Hydro Aluminium Rolled Products GmbH, R and D Center Bonn, P.O. Box 2468, D-53014 Bonn (Germany)

2014-03-15

In an attempt to differentiate the impact of grain size and crystallographic texture on magnetic properties of non-oriented (NO) electrical steel sheets, samples with different grain sizes and textures were produced and analyzed regarding magnetic flux density B and core loss W. The textures of the NO electrical steel samples could be precisely quantified with the help of elliptical Gaussian distributions. In samples with identical textures, small grain sizes resulted in about 15% higher core loss W than larger grains, whereas grain size only moderately affected the magnetic flux density B. In samples having nearly the same grain size, a correlation of the magneto-crystalline anisotropic properties of B and W with texture was obtained via the anisotropy parameter A(h{sup →}). With increasing A(h{sup →}) a linear decrease of B and a linear increase of W were observed. - Highlights: • We produced electrical steel sheets having different grain size and texture. • Magnetic flux density B and core loss W were varied with grain size and texture. • Correlation of B and W with texture was established via anisotropy parameter A(h{sup →}). • With increasing A(h{sup →}) a linear decrease of B and a linear increase of W were observed. • Grain size mainly affected W with only minor impact on B.

Crystalline orientation dependent photoresponse and heterogeneous behaviors of grain boundaries in perovskite solar cells

Science.gov (United States)

Jiang, Chuanpeng; Zhang, Pengpeng

2018-02-01

Using photoconductive atomic force microscopy and Kelvin probe force microscopy, we characterize the local electrical properties of grains and grain boundaries of organic-inorganic hybrid perovskite (CH3NH3PbI3) thin films on top of a poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate (PEDOT:PSS)/ITO substrate. Three discrete photoconductivity levels are identified among perovskite grains, likely corresponding to the crystal orientation of each grain. Local J-V curves recorded on these grains further suggest an anti-correlation behavior between the short circuit current (JSC) and open circuit voltage (VOC). This phenomenon can be attributed to diffusion-limited surface recombination at the non-selective perovskite-tip contact, where a higher carrier mobility established in the perovskite grain results in an enhanced surface recombination and thus a lower VOC. In addition, the photoresponse of perovskite films displays a pronounced heterogeneity across the grain boundaries, with the boundaries formed between grains of the same photoconductivity level displaying even enhanced photocurrent and open circuit voltage compared to those of the adjacent grain interiors. These observations highlight the significance of controlling the microstructure of perovskite thin films, which will be a necessary route for further improving the efficiency of perovskite solar cells.

Optimizing detection filters for single-grain optical dating of quartz

International Nuclear Information System (INIS)

Ballarini, M.; Wallinga, J.; Duller, G.A.T.; Brouwer, J.C.; Bos, A.J.J.; Van Eijk, C.W.E.

2005-01-01

We investigate the use of different optical detection filters for single-grain optically stimulated luminescence (OSL) measurements of quartz samples with a Riso TL/OSL single-grain reader. We selected three filter combinations that considerably improve the light detection efficiency when compared with the 7.5 mm U340 filters that are routinely used. These are the UG1+BG4 filter combination, the 2 mm UG1 and the 2.5 mm U340 filters, which allow a greater transmission in the quartz emission band. This leads to two benefits: (1) more grains can be accepted for equivalent dose analysis, and (2) OSL responses on individual grains are determined with a greater precision. While these three alternative filter combinations perform equally well if compared to each other, we suggest the 2.5 mm thick Hoya U340 to be the filter of choice as it allows the use of blue-diode and IR-diode stimulation sources for bleaching purposes and feldspar detection

Size distribution of dust grains: A problem of self-similarity

International Nuclear Information System (INIS)

Henning, TH.; Dorschner, J.; Guertler, J.

1989-01-01

Distribution functions describing the results of natural processes frequently show the shape of power laws. It is an open question whether this behavior is a result simply coming about by the chosen mathematical representation of the observational data or reflects a deep-seated principle of nature. The authors suppose the latter being the case. Using a dust model consisting of silicate and graphite grains Mathis et al. (1977) showed that the interstellar extinction curve can be represented by taking a grain radii distribution of power law type n(a) varies as a(exp -p) with 3.3 less than or equal to p less than or equal to 3.6 (example 1) as a basis. A different approach to understanding power laws like that in example 1 becomes possible by the theory of self-similar processes (scale invariance). The beta model of turbulence (Frisch et al., 1978) leads in an elementary way to the concept of the self-similarity dimension D, a special case of Mandelbrot's (1977) fractal dimension. In the frame of this beta model, it is supposed that on each stage of a cascade the system decays to N clumps and that only the portion beta N remains active further on. An important feature of this model is that the active eddies become less and less space-filling. In the following, the authors assume that grain-grain collisions are such a scale-invarient process and that the remaining grains are the inactive (frozen) clumps of the cascade. In this way, a size distribution n(a) da varies as a(exp -(D+1))da (example 2) results. It seems to be highly probable that the power law character of the size distribution of interstellar dust grains is the result of a self-similarity process. We can, however, not exclude that the process leading to the interstellar grain size distribution is not fragmentation at all

Statistics of grain misorientations in molybdenum

Energy Technology Data Exchange (ETDEWEB)

Rybin, V V; Titovets, Yu F; Teplitskij, D M; Zolotorevskij, N Yu

1982-03-01

Sets of misorientations between neighbouring grains for three recrystallized molybdenum polycrystals differing in purity, phase composition and prehistory are experimentally determined. The data obtained are analyzed according to modern representations of intergrain boundary structure. In the two materials among the three mentioned above the share of boundaries close to special boundaries with high density of coinciding points turned to be 1.5 times higher than in the polycrystal with chaotic distribution of grains by orientations.

Influence of grain size and additions of Al and Mn on the magnetic properties of non-oriented electrical steels with 3 wt. (% Si

Directory of Open Access Journals (Sweden)

Rodrigo Felix de Araujo Cardoso

2008-03-01

Full Text Available The influence of hot-band grain size and additions of aluminum and manganese on the magnetic properties of non-oriented grain (NOG low-carbon electrical steel with about 3 wt. (% Si were investigated using optical microscopy and X ray diffraction. The addition of manganese resulted in larger grains after final annealing. Coarse grains in the hot-band and addition of Mn led to a Goss orientation component after final annealing, which resulted in an increase in the magnetic permeability.

Determination of lattice orientation in aluminium alloy grains by low energy gallium ion-channelling

Energy Technology Data Exchange (ETDEWEB)

Silk, Jonathan R. [Aerospace Metal Composites Ltd., RAE Road, Farnborough, GU14 6XE (United Kingdom); Dashwood, Richard J. [WMG, University of Warwick, Coventry, CV4 7AL (United Kingdom); Chater, Richard J., E-mail: r.chater@imperial.ac.u [Department of Materials, Imperial College, London SW7 2AZ (United Kingdom)

2010-06-15

Polished sections of a fine-grained aluminium, silicon carbide metal matrix composite (MMC) alloy were prepared by sputtering using a low energy gallium ion source and column (FIB). The MMC had been processed by high temperature extrusion. Images of the polished surface were recorded using the ion-induced secondary electron emission. The metal matrix grains were distinguished by gallium ion-channelling contrast from the silicon carbide component. The variation of the contrast from the aluminium grains with tilt angle can be recorded and used to determine lattice orientation with the contrast from the silicon carbide (SiC) component as a reference. This method is rapid and suits site-specific investigations where classical methods of sample preparation fail.

Branching-induced grain boundary evolution during directional solidification of columnar dendritic grains

International Nuclear Information System (INIS)

Guo, Chunwen; Li, Junjie; Yu, Honglei; Wang, Zhijun; Lin, Xin; Wang, Jincheng

2017-01-01

We present an investigation of secondary and tertiary branching behavior in diverging grain boundaries (GBs) between two columnar dendritic grains with different crystallographic orientations, both by two-dimensional phase-field simulations and thin-sample experiments. The stochasticity of the GB trajectories and the statistically averaged GB orientations were analyzed in detail. The side-branching dynamics and subsequent branch competition behaviors found in the simulations agreed well with the experimental results. When the orientations of two grains are given, the experimental results indicated that the average GB orientation was independent of the pulling velocity in the dendritic growth regime. The simulation and experimental results, as well as the results reported in the literature exhibit a uniform relation between the percentage of the whole gap region occupied by the favorably oriented grain and the difference in the absolute values of the secondary arm growth directions of the two competitive grains. By describing such a uniform relation with a simple fitting equation, we proposed a simple analytical model for the GB orientation at diverging GBs, which gives a more accurate description of GB orientation selection than the existing models.

Integrating security in a group oriented distributed system

Science.gov (United States)

Reiter, Michael; Birman, Kenneth; Gong, LI

1992-01-01

A distributed security architecture is proposed for incorporation into group oriented distributed systems, and in particular, into the Isis distributed programming toolkit. The primary goal of the architecture is to make common group oriented abstractions robust in hostile settings, in order to facilitate the construction of high performance distributed applications that can tolerate both component failures and malicious attacks. These abstractions include process groups and causal group multicast. Moreover, a delegation and access control scheme is proposed for use in group oriented systems. The focus is the security architecture; particular cryptosystems and key exchange protocols are not emphasized.

Quantitative characterization of the orientation spread within individual grains in copper after tensile deformation

DEFF Research Database (Denmark)

Krog-Pedersen, Stine; Bowen, Jacob R.; Pantleon, Wolfgang

2009-01-01

By means of electron backscatter diffraction, orientations are determined on a regular grid on a polished section of a copper specimen after tensile deformation to 25%. Individual grains separated by boundaries with disorientation angles above 7° are identified and the microtexture in the form...

Species distribution model transferability and model grain size - finer may not always be better.

Science.gov (United States)

Manzoor, Syed Amir; Griffiths, Geoffrey; Lukac, Martin

2018-05-08

Species distribution models have been used to predict the distribution of invasive species for conservation planning. Understanding spatial transferability of niche predictions is critical to promote species-habitat conservation and forecasting areas vulnerable to invasion. Grain size of predictor variables is an important factor affecting the accuracy and transferability of species distribution models. Choice of grain size is often dependent on the type of predictor variables used and the selection of predictors sometimes rely on data availability. This study employed the MAXENT species distribution model to investigate the effect of the grain size on model transferability for an invasive plant species. We modelled the distribution of Rhododendron ponticum in Wales, U.K. and tested model performance and transferability by varying grain size (50 m, 300 m, and 1 km). MAXENT-based models are sensitive to grain size and selection of variables. We found that over-reliance on the commonly used bioclimatic variables may lead to less accurate models as it often compromises the finer grain size of biophysical variables which may be more important determinants of species distribution at small spatial scales. Model accuracy is likely to increase with decreasing grain size. However, successful model transferability may require optimization of model grain size.

Forecasting grain size distribution of coal cut by a shearer loader

Energy Technology Data Exchange (ETDEWEB)

Sikora, W; Chodura, J; Siwiec, J

1983-02-01

Analyzed are effects of shearer loader design on grain size distribution of coal, particularly on proportion of the finest size group and proportion of largest coal grains. The method developed by the IGD im. A.A. Skochinski Institute in Moscow is used. Effects of cutting tool design and mechanical coal properties are analyzed. Of the evaluated factors, two are of decisive importance: thickness of the coal chip cut by a cutting tool and coefficient of coal disintegration which characterizes coal behavior during cutting. Grain size distribution is also influenced by cutting tool geometry. Two elements of cutting tool design are of major importance: dimensions of the cutting edge and angle of attack. Effects of cutting tool design and coal mechanical properties on grain size distribution are shown in 12 diagrams. Using the forecasting method developed by the IGD im. A.A. Skochinski Institute in Moscow grain size distribution of coal cut by three shearer loaders is calculated: the KWB-3RDU with a drum 1600 mm in diameter, the KWB-6W with a drum 2500 mm in diameter, and a shearer loader being developed with a 1550 mm drum. The results of comparative evaluations are shown in two tables. 5 references.

Development of microtextures in cold rolled iron-oligocrystals

International Nuclear Information System (INIS)

Boeslau, J.; Raabe, D.

1994-01-01

The evolution of microtexture in cold rolled Fe-oligocrystals was investigated. The use of oligocrystals, i.e. polycrystals consisting of only a few large grains, allows the investigation of the development of the orientation distribution (OD) within single grains with respect to the rolling degree, to the initial grain orientation and to the geometrical and orientational constraints imposed by the neighbouring grains. It is shown that during deformation the average misorientation between adjacent regions within a single grain increases and that fragmentation of initially homogeneous grains occurs. It is revealed that the starting orientation of the grain has a considerable impact on the formation of the single grain OD. The experiments were carried out by use of single orientation measurement in the scanning electron microscope and by taking X-ray pole figures (PF). (orig.)

Microwave single-scattering properties of randomly oriented soft-ice hydrometeors

Directory of Open Access Journals (Sweden)

D. Casella

2008-11-01

Full Text Available Large ice hydrometeors are usually present in intense convective clouds and may significantly affect the upwelling radiances that are measured by satellite-borne microwave radiometers – especially, at millimeter-wavelength frequencies. Thus, interpretation of these measurements (e.g., for precipitation retrieval requires knowledge of the single scattering properties of ice particles. On the other hand, shape and internal structure of these particles (especially, the larger ones is very complex and variable, and therefore it is necessary to resort to simplifying assumptions in order to compute their single-scattering parameters.

In this study, we use the discrete dipole approximation (DDA to compute the absorption and scattering efficiencies and the asymmetry factor of two kinds of quasi-spherical and non-homogeneous soft-ice particles in the frequency range 50–183 GHz. Particles of the first kind are modeled as quasi-spherical ice particles having randomly distributed spherical air inclusions. Particles of the second kind are modeled as random aggregates of ice spheres having random radii. In both cases, particle densities and dimensions are coherent with the snow hydrometeor category that is utilized by the University of Wisconsin – Non-hydrostatic Modeling System (UW-NMS cloud-mesoscale model. Then, we compare our single-scattering results for randomly-oriented soft-ice hydrometeors with corresponding ones that make use of: a effective-medium equivalent spheres, b solid-ice equivalent spheres, and c randomly-oriented aggregates of ice cylinders. Finally, we extend to our particles the scattering formulas that have been developed by other authors for randomly-oriented aggregates of ice cylinders.

Growth rate of YBCO-Ag superconducting single grains

Science.gov (United States)

Congreve, J. V. J.; Shi, Y. H.; Dennis, A. R.; Durrell, J. H.; Cardwell, D. A.

2017-12-01

The large scale use of (RE)Ba2Cu3O7 bulk superconductors, where RE=Y, Gd, Sm, is, in part, limited by the relatively poor mechanical properties of these inherently brittle ceramic materials. It is reported that alloying of (RE)Ba2Cu3O7 with silver enables a significant improvement in the mechanical strength of bulk, single grain samples without any detrimental effect on their superconducting properties. However, due to the complexity and number of inter-related variables involved in the top seeded melt growth (TSMG) process, the growth of large single grains is difficult and the addition of silver makes it even more difficult to achieve successful growth reliably. The key processing variables in the TSMG process include the times and temperatures of the stages within the heating profile, which can be derived from the growth rate during the growth process. To date, the growth rate of the YBa2Cu3O7-Ag system has not been reported in detail and it is this lacuna that we have sought to address. In this work we measure the growth rate of the YBCO-Ag system using a method based on continuous cooling and isothermal holding (CCIH). We have determined the growth rate by measuring the side length of the crystallised region for a number of samples for specified isothermal hold temperatures and periods. This has enabled the growth rate to be modelled and from this an optimized heating profile for the successful growth of YBCO-Ag single grains to be derived.

Thin resolver using the easy magnetization axis of the grain-oriented silicon steel as an angle indicator

Directory of Open Access Journals (Sweden)

Jisho Oshino

2017-05-01

Full Text Available A new type of thin resolver is presented, in which the easy axis of the magnetic anisotropy in the grain-oriented silicon steel is used as an angle indicator. The total thickness including a rotor, PCB coils and a back yoke can be made less than 4 mm. With a rotor of 50 mm diameter, a good linear response (non-linearity error < 0.4% between the mechanical angle input and the electrical angle output has been obtained. The influence of a weak magnetic anisotropy in the non-grain-oriented silicon steel used for the back yoke on the accuracy of the resolver can be deleted by the method proposed in this paper.

Simulation of grain boundary effects on electronic transport in metals, and detailed causes of scattering

Energy Technology Data Exchange (ETDEWEB)

Feldman, Baruch [Process Technology Modeling, Design and Technology Solutions, Technology and Manufacturing Group, Intel Corporation, Santa Clara, CA 95052 (United States); Department of Physics, University of Washington, Seattle, WA 98195 (United States); Park, Seongjun; Haverty, Michael; Shankar, Sadasivan [Process Technology Modeling, Design and Technology Solutions, Technology and Manufacturing Group, Intel Corporation, Santa Clara, CA 95052 (United States); Dunham, Scott T. [Department of Physics, University of Washington, Seattle, WA 98195 (United States); Department of Electrical Engineering, University of Washington, Seattle, WA 98195 (United States)

2010-07-15

We present first-principles simulations of single grain boundary reflectivity of electrons in noble metals, Cu and Ag. We examine twin and non-twin grain boundaries using non-equilibrium Green's function and first principles methods. We also investigate the determinants of reflectivity in grain boundaries by modeling atomic vacancies, disorder, and orientation and find that both the change in grain orientation and disorder in the boundary itself contribute significantly to reflectivity. We find that grain boundary reflectivity may vary widely depending on the grain boundary structure, consistent with published experimental results. Finally, we examine the reflectivity from multiple grain boundaries and find that grain boundary reflectivity may depend on neighboring grain boundaries. This study raises some potential limitations in the independent grain boundary assumptions of the Mayadas-Shatzkes (MS) model. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

Grain interaction effects in polycrystalline Cu

DEFF Research Database (Denmark)

Thorning, C.; Somers, Marcel A.J.; Wert, John A.

2005-01-01

Crystal orientation maps for a grain in a deformed Cu polycrystal have been analysed with the goal of understanding the effect of grain interactions on orientation subdivision. The polycrystal was incrementally strained in tension to 5, 8, 15 and 25% extension; a crystal orientation map...... was measured after each strain increment. The measurements are represented as rotations from the initial crystal orientation. A coarse domain structure forms in the initial 5% strain increment and persists at higher strains. Crystal rotations for all coarse domains in the grain are consistent with the full...... range of Tailor solutions for axisymmetric strain; grain interactions are not required to account for the coarse domain structure. Special orientation domains extend 20-100 µm into the grain at various locations around its periphery. The special orientation domain morphologies include layers along...

Estimation of Single-Crystal Elastic Constants of Polycrystalline Materials from Back-Scattered Grain Noise

International Nuclear Information System (INIS)

Haldipur, P.; Margetan, F. J.; Thompson, R. B.

2006-01-01

Single-crystal elastic stiffness constants are important input parameters for many calculations in material science. There are well established methods to measure these constants using single-crystal specimens, but such specimens are not always readily available. The ultrasonic properties of metal polycrystals, such as velocity, attenuation, and backscattered grain noise characteristics, depend in part on the single-crystal elastic constants. In this work we consider the estimation of elastic constants from UT measurements and grain-sizing data. We confine ourselves to a class of particularly simple polycrystalline microstructures, found in some jet-engine Nickel alloys, which are single-phase, cubic, equiaxed, and untextured. In past work we described a method to estimate the single-crystal elastic constants from measured ultrasonic velocity and attenuation data accompanied by metallographic analysis of grain size. However, that methodology assumes that all attenuation is due to grain scattering, and thus is not valid if appreciable absorption is present. In this work we describe an alternative approach which uses backscattered grain noise data in place of attenuation data. Efforts to validate the method using a pure copper specimen are discussed, and new results for two jet-engine Nickel alloys are presented

Inductive current measurements in an oriented grained YBa2Cu3Ox superconductor

International Nuclear Information System (INIS)

Kupfer, H.; Keller, C.; Salama, K.; Selvamanickam, V.

1989-01-01

The critical current of grain aligned YBa 2 Cu 3 O x bulk material was investigated by inductive flux profile and ac susceptibility measurements. The induced current was directed perpendicular to the a-b plane oriented grains where high values of the transport current, have been previously reported. In spite of the unfavorable geometry of the investigated shielding current, no features of granularity were observed. The results yield a uniform bulk critical current density j c of 3x10 4 A/cm 2 at zero field and 77 K. Field and temperature dependences of this j c are discussed and compared with those in a granular Y-Ba-Cu-O material

An Overview of Grain Growth Theories for Pure Single Phase Systems,

Science.gov (United States)

1986-10-01

the fundamental causes for these distributions. This Blanc and Mocellin (1979) and Carnal and Mocellin (1981j set out to do. 7.1 Monte-Carlo Simulations...termed event B) (in 2-D) of 3-sided grains. (2) Neighbour-switching (termed event C). Blanc and Mocellin (1979) dealt with 2-D sections through...Kurtz and Carpay (1980a). 7.2 Analytical Method to Obtain fn Carnal and Mocellin (1981) obtained the distribution of grain coordination numbers in

Preparation and characterization of Grain-Oriented Barium Titanate Ceramics Using Electrophoresis Deposition Method under A High Magnetic Field

Energy Technology Data Exchange (ETDEWEB)

Kita, T; Kondo, S; Takei, T; Kumada, N; Nakashima, K; Fujii, I; Wada, S [Material Science and Technology, Interdisciplinary Graduate School of Medical and Engineering, University of Yamanashi, 4-4-37 Takeda, Kofu, Yamanashi 400-8510 (Japan); Suzuki, T S; Uchikoshi, T; Sakka, Y [National Institute for materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Miwa, Y; Kawada, S; Kimura, M, E-mail: swada@yamanashi.ac.jp [Murata Manufacturing Co., Ltd. 2288 Ooshinohara, Yasu, Shiga 520-2393 (Japan)

2011-10-29

Barium titanate (BaTiO{sub 3}) grain-oriented ceramics were prepared using electrophoresis deposition (EPD) method under high magnetic field of 12 T. First, BaTiO{sub 3} nanoparticles with high c/a ratio of 1.008 and size of 84 nm were prepared by two-step thermal decomposition method with barium titanyl oxalate nanoparticles. Using the BaTiO{sub 3} slurry, BaTiO{sub 3} nanoparticle accumulations were prepared by EPD method under high magnetic field. After binder burnout, the accumulations were sintered and BaTiO{sub 3} grain-oriented ceramics were prepared. Moreover, dielectric properties of their ceramics were investigated

Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum.

Science.gov (United States)

Gao, Libo; Ren, Wencai; Xu, Huilong; Jin, Li; Wang, Zhenxing; Ma, Teng; Ma, Lai-Peng; Zhang, Zhiyong; Fu, Qiang; Peng, Lian-Mao; Bao, Xinhe; Cheng, Hui-Ming

2012-02-28

Large single-crystal graphene is highly desired and important for the applications of graphene in electronics, as grain boundaries between graphene grains markedly degrade its quality and properties. Here we report the growth of millimetre-sized hexagonal single-crystal graphene and graphene films joined from such grains on Pt by ambient-pressure chemical vapour deposition. We report a bubbling method to transfer these single graphene grains and graphene films to arbitrary substrate, which is nondestructive not only to graphene, but also to the Pt substrates. The Pt substrates can be repeatedly used for graphene growth. The graphene shows high crystal quality with the reported lowest wrinkle height of 0.8 nm and a carrier mobility of greater than 7,100 cm(2) V(-1) s(-1) under ambient conditions. The repeatable growth of graphene with large single-crystal grains on Pt and its nondestructive transfer may enable various applications.

Grain refinement and hardness distribution in cryogenically cooled ferritic stainless steel welds

International Nuclear Information System (INIS)

Amuda, M.O.H.; Mridha, S.

2013-01-01

Highlights: ► Grain refinement was undertaken in AISI 430 FSS welds using cryogenic cooling. ► Flow rates of the cryogenic liquid influenced weld grain structure. ► Cryogenic cooling of welds generates about 45% grain refinement in welds. ► Phase structure of welds is not affected by flow rates of cryogenic liquid. ► Hardness profile in cryogenically cooled and conventional welds is similar. - Abstract: The energy input and heat dissipation dynamics during fusion welding generates coarse grain in the welds resulting in poor mechanical properties. While grain refinement in welds via the control of the energy input is quite common, the influence of heat dissipation on grain morphology and properties is not fully established. This paper characterized cryogenically cooled ferritic stainless steel (FSS) welds in terms of grain structure and hardness distribution along transverse and thickness directions. Cryogenic cooling reduces the weld dimension by more than 30% and provides grain refinement of almost 45% compared to conventional weld. The hardness distribution in the thickness direction gives slightly higher profile because of decreased grain growth caused by faster cooling effects of cryogenic liquid

Influence of cold rolling direction on texture, inhibitor and magnetic properties in strip-cast grain-oriented 3% silicon steel

Energy Technology Data Exchange (ETDEWEB)

Fang, F., E-mail: fangfengdbdx@163.com [State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China); Lu, X.; Zhang, Y.X.; Wang, Y.; Jiao, H.T.; Cao, G.M.; Yuan, G.; Xu, Y.B. [State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China); Misra, R.D.K. [Laboratory for Excellence in Advanced Steel Research, Department of Metallurgical, Materials and Biomedical Engineering, University of Texas at El Paso, EL Paso, TX 79968 (United States); Wang, G.D. [State Key Laboratory of Rolling Technology and Automation, Northeastern University, Shenyang 110819 (China)

2017-02-15

An unconventional cold rolling scheme (inclined rolling at 0°, 30°, 45°, 90° during second-stage cold rolling process) was adopted to process grain-oriented silicon steel based on strip casting process. The influences of inclination angles on microstructure, texture, inhibitor and magnetic properties were studied by a combination of EBSD, XRD and TEM. It was found that the α-fiber texture was weakened and γ-fiber was strengthened in cold rolled sheet with increase in inclination angle. The primary recrystallization sheet exhibited more homogeneous microstructure with relatively strong γ-fiber, medium α-fiber texture, weak λ-fiber texture and Goss component at high inclination angles. Fine and homogeneous inhibitors were obtained after primary annealing with increase in inclination angle from 0° to 90° because of more uniform deformation after inclined rolling. The grain-oriented silicon steel experienced completely secondary recrystallization at various inclination angles after final annealing process, with superior magnetic properties at 0° and 90°. Furthermore, Goss nuclei capable of final secondary recrystallization in strip casting process newly formed both in-grain shear bands and grain boundaries region during second-stage cold rolling and subsequent annealing process, which is different from the well-accepted results that Goss texture originated from the subsurface layer of the hot rolled sheet or during intermediate annealing process. In addition, the Goss texture that nucleated in-grain shear bands was weaker but more accurate as compared to that in grain boundaries region. - Highlights: • Inclined cold rolling was adopted to process strip-cast grain-oriented silicon steel. • Influence of inclination angles on texture, inhibitor and magnetic properties was studied. • The initial texture was changed with respect to the inclination angle. • Homogeneous inhibitors were obtained after primary annealing at various inclination angles. �

The orientation distribution of tunneling-related quantities

Science.gov (United States)

Seif, W. M.; Refaie, A. I.; Botros, M. M.

2018-03-01

In the nuclear tunneling processes involving deformed nuclei, most of the tunneling-related quantities depend on the relative orientations of the participating nuclei. In the presence of different multipole deformations, we study the variation of a few relevant quantities for the α-decay and the sub-barrier fusion processes, in an orientation degree of freedom. The knocking frequency and the penetration probability are evaluated within the Wentzel-Kramers-Brillouin approximation. The interaction potential is calculated with Skyrme-type nucleon-nucleon interaction. We found that the width of the potential pocket, the Coulomb barrier radius, the penetration probability, the α-decay width, and the fusion cross-section follow consistently the orientation-angle variation of the radius of the deformed nucleus. The orientation distribution patterns of the pocket width, the barrier radius, the logarithms of the penetrability, the decay width, and the fusion cross-section are found to be highly analogous to pattern of the deformed-nucleus radius. The curve patterns of the orientation angle distributions of the internal pocket depth, the Coulomb barrier height and width, as well as the knocking frequency simulate inversely the variation of the deformed nucleus radius. The predicted orientation behaviors will be of a special interest in predicting the optimum orientations for the tunneling processes.

Grain destruction in interstellar shocks

International Nuclear Information System (INIS)

Seab, C.G.; Shull, J.M.

1984-01-01

One of the principal methods for removing grains from the Interstellar Medium is to destroy them in shock waves. Previous theoretical studies of shock destruction have generally assumed only a single size and type of grain; most do not account for the effect of the grain destruction on the structure of the shock. Earlier calculations have been improved in three ways: first, by using a ''complete'' grain model including a distribution of sizes and types of grains; second, by using a self-consistent shock structure that incorporates the changing elemental depletions as the grains are destroyed; and third, by calculating the shock-processed ultraviolet extinction curves for comparison with observations. (author)

Grain growth studies on nanocrystalline Ni powder

International Nuclear Information System (INIS)

Rane, G.K.; Welzel, U.; Mittemeijer, E.J.

2012-01-01

The microstructure of nanocrystalline Ni powder produced by ball-milling and its thermal stability were investigated by applying different methods of X-ray diffraction line-profile analysis: single-line analysis, whole powder-pattern modelling and the (modified) Warren–Averbach method were employed. The kinetics of grain growth were investigated by both ex-situ and in-situ X-ray diffraction measurements. With increasing milling time, the grain-size reduction is accompanied by a considerable narrowing of the size distribution and an increase in the microstrain. Upon annealing, initial, rapid grain growth occurs, accompanied by the (almost complete) annihilation of microstrain. For longer annealing times, the grain-growth kinetics depend on the initial microstructure: a smaller microstrain with a broad grain-size distribution leads to linear grain growth, followed by parabolic grain growth, whereas a larger microstrain with a narrow grain-size distribution leads to incessant linear grain growth. These effects have been shown to be incompatible with grain-boundary curvature driven growth. The observed kinetics are ascribed to the role of excess free volume at the grain boundaries of nanocrystalline material and the prevalence of an “abnormal grain-growth” mechanism.

On the colour of wing scales in butterflies: iridescence and preferred orientation of single gyroid photonic crystals.

Science.gov (United States)

Corkery, Robert W; Tyrode, Eric C

2017-08-06

Lycaenid butterflies from the genera Callophrys , Cyanophrys and Thecla have evolved remarkable biophotonic gyroid nanostructures within their wing scales that have only recently been replicated by nanoscale additive manufacturing. These nanostructures selectively reflect parts of the visible spectrum to give their characteristic non-iridescent, matte-green appearance, despite a distinct blue-green-yellow iridescence predicted for individual crystals from theory. It has been hypothesized that the organism must achieve its uniform appearance by growing crystals with some restrictions on the possible distribution of orientations, yet preferential orientation observed in Callophrys rubi confirms that this distribution need not be uniform. By analysing scanning electron microscope and optical images of 912 crystals in three wing scales, we find no preference for their rotational alignment in the plane of the scales. However, crystal orientation normal to the scale was highly correlated to their colour at low (conical) angles of view and illumination. This correlation enabled the use of optical images, each containing up to 10 4 -10 5 crystals, for concluding the preferential alignment seen along the [Formula: see text] at the level of single scales, appears ubiquitous. By contrast, [Formula: see text] orientations were found to occur at no greater rate than that expected by chance. Above a critical cone angle, all crystals reflected bright green light indicating the dominant light scattering is due to the predicted band gap along the [Formula: see text] direction, independent of the domain orientation. Together with the natural variation in scale and wing shapes, we can readily understand the detailed mechanism of uniform colour production and iridescence suppression in these butterflies. It appears that the combination of preferential alignment normal to the wing scale, and uniform distribution within the plane is a near optimal solution for homogenizing the angular

Novel analytical model for the determination of grain size distributions in nanocrystalline materials with low lattice microstrains by X-ray diffractometry

International Nuclear Information System (INIS)

Sanchez-Bajo, F.; Ortiz, A.L.; Cumbrera, F.L.

2006-01-01

We have developed a novel, analytical model for the determination of grain size distributions in nanocrystalline (nc) materials with low internal stresses by X-ray diffractometry (XRD). The model assumes explicitly that the XRD peaks are pseudo-Voigtian and that the grain size distributions are lognormal, both of which are assumptions amply supported by the experimental evidence. It was found analytically that the grain size dispersion depends on the shape of the XRD peaks only, whereas the grain size median depends on both the shape and width of the XRD peaks. In addition, the theoretical predictions resulting from the model were validated using standard XRD peaks obtained by computer simulation from first principles. Particular emphasis is given to the discussion of the validity limits of the model, and to the analysis of the influence of the characteristics of the grain size distributions on the nature of the XRD peaks. We then show how to calculate the average and apparent grain sizes from the grain size distribution determined with the model, and how this compares with the Scherrer method. Implications for the characterization of (undistorted and distorted) nc-materials are indicated, and a case study of an nc-powder of cubic ZrO 2 is presented. The application of the model itself is simple, involving only the fit of a pseudo-Voigt function to a single XRD peak followed by the use of two equations. This suggests that the model may have an important role to play in the characterization of nc-materials

Novel analytical model for the determination of grain size distributions in nanocrystalline materials with low lattice microstrains by X-ray diffractometry

Energy Technology Data Exchange (ETDEWEB)

Sanchez-Bajo, F. [Departamento de Electronica e Ingenieria Electromecanica, Escuela de Ingenierias Industriales, Universidad de Extremadura, Avda. de Elvas S/N, Badajoz 06071 (Spain); Ortiz, A.L. [Departamento de Electronica e Ingenieria Electromecanica, Escuela de Ingenierias Industriales, Universidad de Extremadura, Avda. de Elvas S/N, Badajoz 06071 (Spain)]. E-mail: alortiz@unex.es; Cumbrera, F.L. [Departamento de Fisica, Facultad de Ciencias, Universidad de Extremadura, Badajoz 06071 (Spain)

2006-01-15

We have developed a novel, analytical model for the determination of grain size distributions in nanocrystalline (nc) materials with low internal stresses by X-ray diffractometry (XRD). The model assumes explicitly that the XRD peaks are pseudo-Voigtian and that the grain size distributions are lognormal, both of which are assumptions amply supported by the experimental evidence. It was found analytically that the grain size dispersion depends on the shape of the XRD peaks only, whereas the grain size median depends on both the shape and width of the XRD peaks. In addition, the theoretical predictions resulting from the model were validated using standard XRD peaks obtained by computer simulation from first principles. Particular emphasis is given to the discussion of the validity limits of the model, and to the analysis of the influence of the characteristics of the grain size distributions on the nature of the XRD peaks. We then show how to calculate the average and apparent grain sizes from the grain size distribution determined with the model, and how this compares with the Scherrer method. Implications for the characterization of (undistorted and distorted) nc-materials are indicated, and a case study of an nc-powder of cubic ZrO{sub 2} is presented. The application of the model itself is simple, involving only the fit of a pseudo-Voigt function to a single XRD peak followed by the use of two equations. This suggests that the model may have an important role to play in the characterization of nc-materials.

Influence of welding passes on grain orientation – The example of a multi-pass V-weld

International Nuclear Information System (INIS)

Ye, Jing; Moysan, Joseph; Song, Sung-Jin; Kim, Hak-Joon; Chassignole, Bertrand; Gueudré, Cécile; Dupond, Olivier

2012-01-01

The accurate modelling of grain orientations in a weld is important, when accurate ultrasonic test predictions of a welded assembly are needed. To achieve this objective, Electricité de France (EDF) and the Laboratoire de Caractérisation Non Destructive (LCND) have developed a dedicated code, which makes use of information recorded in the welding procedure. Among the welding parameters recorded, although the order in which the welding passes are made is of primary importance in the welding process, this information is not always well known or accurately described. In the present paper we analyse in greater detail the influence of the order of welding passes, using data obtained from the Centre for Advanced Non Destructive Evaluation (CANDE), derived from a dissimilar metal weld (DMW) with buttering. Comparisons are made using grain orientation measurements on a macrograph. - Highlights: ► Influence of welding process on grain structure is studied using the MINA model. ► For the first time the importance of a slight slope of the layers is evaluated. ► Two orders of passes are compared for the modelling approach. ► A major effect is observed due to a change in the order of passes.

On the Orientation Barrier Distribution of the interacting spherical- Deformed Nuclei

International Nuclear Information System (INIS)

Ismail, M.; Seif, W.M.

2009-01-01

The effect of different multipole deformations on the Coulomb barrier distribution in the orientation degrees of freedom is studied. The demonstrated Coulomb barriers are calculated microscopically using the double folding model which is based on realistic density dependent nucleon nucleon interaction. A simple straight forward method, presented in recent work, has been used to predict the distribution of barriers at arbitrary orientations in presence of different deformations far away the complicated numerical calculations. The proposed interpretation is related to the half density radius change of the deformed nucleus involved in interaction where the orientation Coulomb barrier parameters distributions show similar patterns to that of orientation deformed nucleus one. The orientation Coulomb barrier radius distribution follows the same variation of the deformed nucleus radius, while the barrier height distribution is directly proportional to it. This correlation allows a simple evaluation of the orientation barrier distribution which greatly helps us to estimate when the barrier parameters will increase or decrease and at which orientations they will be independent of the deformation. It helps also to estimate the optimum orientations for hot and cold fusion of colliding nuclei.

Selective Electron Beam Manufacturing of Ti-6Al-4V Strips: Effect of Build Orientation, Columnar Grain Orientation, and Hot Isostatic Pressing on Tensile Properties

Science.gov (United States)

Wang, J.; Tang, H. P.; Yang, K.; Liu, N.; Jia, L.; Qian, M.

2018-03-01

Many novel designs for additive manufacturing (AM) contain thin-walled (≤ 3 mm) sections in different orientations. Selective electron beam melting (SEBM) is particularly suited to AM of such thin-walled titanium components because of its high preheating temperature and high vacuum. However, experimental data on SEBM of Ti-6Al-4V thin sections remains scarce because of the difficulty and high cost of producing long, thin and smooth strip tensile specimens (see Fig. 1). In this study, 80 SEBM Ti-6Al-4V strips (180 mm long, 42 mm wide, 3 mm thick) were built both vertically (V-strips) and horizontally (H-strips). Their density, microstructure and tensile properties were investigated. The V-strips showed clearly higher tensile strengths but lower elongation than the H-strips. Hot isostatic pressing (HIP) produced the same lamellar α-β microstructures in terms of the average α-lath thickness in both types of strips. The retained prior-β columnar grain boundaries after HIP showed no measurable influence on the tensile properties, irrespective of their length and orientation, because of the formation of randomly distributed fine α-laths.[Figure not available: see fulltext.

Grain Size Distribution in Mudstones: A Question of Nature vs. Nurture

Science.gov (United States)

Schieber, J.

2011-12-01

Grain size distribution in mudstones is affected by the composition of the source material, the processes of transport and deposition, and post-depositional diagenetic modification. With regard to source, it does make a difference whether for example a slate belt is eroded vs a stable craton. The former setting tends to provide a broad range of detrital quartz in the sub 62 micron size range in addition to clays and greenschist grade rock fragments, whereas the latter may be biased towards coarser quartz silt (30-60 microns), in addition to clays and mica flakes. In flume experiments, when fine grained materials are transported in turbulent flows at velocities that allow floccules to transfer to bedload, a systematic shift of grain size distribution towards an increasingly finer grained suspended load is observed as velocity is lowered. This implies that the bedload floccules are initially constructed of only the coarsest clay particles at high velocities, and that finer clay particles become incorporated into floccules as velocity is lowered. Implications for the rock record are that clay beds deposited from decelerating flows should show subtle internal grading of coarser clay particles; and that clay beds deposited from continuous fast flows should show a uniform distribution of coarse clays. Still water settled clays should show a well developed lower (coarser) and upper (finer) subdivision. A final complication arises when diagenetic processes, such as the dissolution of biogenic silica, give rise to diagenetic quartz grains in the silt to sand size range. This diagenetic silica precipitates in fossil cavities and pore spaces of uncompacted muds, and on casual inspection can be mistaken for detrital quartz. In distal mudstone successions close to 100 % of "apparent" quartz silt can be of that origin, and reworking by bottom currents can further enhance a detrital perception by producing rippled and laminated silt beds. Although understanding how size

Effects of artificial holes in very large single-grain Y_1_._5Ba_2Cu_3O_7_-_y bulk superconductors

International Nuclear Information System (INIS)

Park, S. D.; Jun, B. H.; Kim, C. J.; Park, H. W.

2017-01-01

The effects of artificial holes on the trapped magnetic fields and magnetic levitation forces of very large single-grain Y_1_._5Ba_2Cu_3O_7_-_y (Y1.5) bulk superconductors were studied. Artificial holes were made for Y1.5 powder compacts by die pressing using cylindrical dies with a diameter of 30 mm or 40 m, or rectangular dies with a side length of 50 mm. The single grain Y1.5 bulk superconductors (25 mm, 33 mm in diameter and 42 mm in side length) with artificial holes were fabricated using a top-seeded melt growth (TSMG) process for the die-pressed Y1.5 powder compacts. The magnetic levitation forces at 77 K of the 25 mm single grain Y1.5 samples with one (diameters of 4.2 mm) or six artificial holes (diameters of 2.5 mm) were 10-17% higher than that of the Y1.5 sample without artificial holes. The trapped magnetic fields at 77 K of the Y1.5 samples with artificial holes were also 9.6-18% higher than that of the Y1.5 sample without artificial holes. The 33 mm and 42 mm single grain Y1.5 samples with artificial holes (2.5 mm and 4.2 mm in diameter) also showed trapped magnetic fields 10-13% higher than that of the Y1.5 samples without artificial holes in spite of the reduced superconducting volume fraction due to the presence of artificial holes. The property enhancement in the large single grain Y1.5 bulk superconductors appears to be attributed to the formation of the pore-free regions near the artificial holes and the homogeneous oxygen distribution in the large Y123 grains

Grain growth competition during thin-sample directional solidification of dendritic microstructures: A phase-field study

International Nuclear Information System (INIS)

Tourret, D.; Song, Y.; Clarke, A.J.; Karma, A.

2017-01-01

We present the results of a comprehensive phase-field study of columnar grain growth competition in bi-crystalline samples in two dimensions (2D) and in three dimensions (3D) for small sample thicknesses allowing a single row of dendrites to form. We focus on the selection of grain boundary (GB) orientation during directional solidification in the steady-state dendritic regime, and study its dependence upon the orientation of two competing grains. In 2D, we map the entire orientation range for both grains, performing several simulations for each configuration to account for the stochasticity of GB orientation selection and to assess the average GB behavior. We find that GB orientation selection depends strongly on whether the primary dendrite growth directions have lateral components (i.e. components perpendicular to the axis of the temperature gradient) that point in the same or opposite directions in the two grains. We identify a range of grain orientations in which grain selection follows the classical description of Walton and Chalmers. We also identify conditions that favor unusual overgrowth of favorably-oriented dendrites at a converging GB. We propose a simple analytical description that reproduces the average GB orientation selection from 2D simulations within statistical fluctuations of a few degrees. In 3D, we find a similar GB orientation selection as in 2D when secondary branches grow in planes parallel and perpendicular to the sample walls. Remarkably, quasi-2D behavior is also observed even when those perpendicular sidebranching planes are rotated by a finite azimuthal angle about the primary dendrite growth axis as long as the absolute values of those azimuthal angles are equal in both grains. In contrast, when the absolute values of those azimuthal angles differ markedly, we find that unusual overgrowth events at a converging GB are promoted by a high azimuthal angle in the least-favorably-oriented grain. We also find that diverging GBs can be

Plant Density Effect on Grain Number and Weight of Two Winter Wheat Cultivars at Different Spikelet and Grain Positions

Science.gov (United States)

Ni, Yingli; Zheng, Mengjing; Yang, Dongqing; Jin, Min; Chen, Jin; Wang, Zhenlin; Yin, Yanping

2016-01-01

In winter wheat, grain development is asynchronous. The grain number and grain weight vary significantly at different spikelet and grain positions among wheat cultivars grown at different plant densities. In this study, two winter wheat (Triticum aestivum L.) cultivars, ‘Wennong6’ and ‘Jimai20’, were grown under four different plant densities for two seasons, in order to study the effect of plant density on the grain number and grain weight at different spikelet and grain positions. The results showed that the effects of spikelet and grain positions on grain weight varied with the grain number of spikelets. In both cultivars, the single-grain weight of the basal and middle two-grain spikelets was higher at the 2nd grain position than that at the 1st grain position, while the opposite occurred in the top two-grain spikelets. In the three-grain spikelets, the distribution of the single-grain weight was different between cultivars. In the four-grain spikelets of Wennong6, the single-grain weight was the highest at the 2nd grain position, followed by the 1st, 3rd, and 4th grain positions. Regardless of the spikelet and grain positions, the single-grain weight was the highest at the 1st and 2nd grain positions and the lowest at the 3rd and 4th grain positions. Overall, plant density affected the yield by controlling the seed-setting characteristics of the tiller spike. Therefore, wheat yield can be increased by decreasing the sterile basal and top spikelets and enhancing the grain weight at the 3rd and 4th grain positions, while maintaining it at the 1st and 2nd grain positions on the spikelet. PMID:27171343

The effects of particle size distribution and induced unpinning during grain growth

International Nuclear Information System (INIS)

Thompson, G.S.; Rickman, J.M.; Harmer, M.P.; Holm, E.A.

1996-01-01

The effect of a second-phase particle size distribution on grain boundary pinning was studied using a Monte Carlo simulation technique. Simulations were run using a constant number density of both whisker and rhombohedral particles, and the effect of size distribution was studied by varying the standard deviation of the distribution around a constant mean particle size. The results of present simulations indicate that, in accordance with the stereological assumption of the topological pinning model, changes in distribution width had no effect on the pinned grain size. The effect of induced unpinning of particles on microstructure was also studied. In contrast to predictions of the topological pinning model, a power law dependence of pinned grain size on particle size was observed at T=0.0. Based on this, a systematic deviation to the stereological predictions of the topological pinning model is observed. The results of simulations at higher temperatures indicate an increasing power law dependence of pinned grain size on particle size, with the slopes of the power law dependencies fitting an Arrhenius relation. The effect of induced unpinning of particles was also studied in order to obtain a correlation between particle/boundary concentration and equilibrium grain size. The results of simulations containing a constant number density of monosized rhombohedral particles suggest a strong power law correlation between the two parameters. copyright 1996 Materials Research Society

ON ESTIMATION AND HYPOTHESIS TESTING OF THE GRAIN SIZE DISTRIBUTION BY THE SALTYKOV METHOD

Directory of Open Access Journals (Sweden)

Yuri Gulbin

2011-05-01

Full Text Available The paper considers the problem of validity of unfolding the grain size distribution with the back-substitution method. Due to the ill-conditioned nature of unfolding matrices, it is necessary to evaluate the accuracy and precision of parameter estimation and to verify the possibility of expected grain size distribution testing on the basis of intersection size histogram data. In order to review these questions, the computer modeling was used to compare size distributions obtained stereologically with those possessed by three-dimensional model aggregates of grains with a specified shape and random size. Results of simulations are reported and ways of improving the conventional stereological techniques are suggested. It is shown that new improvements in estimating and testing procedures enable grain size distributions to be unfolded more efficiently.

Passive acoustic measurement of bedload grain size distribution using self-generated noise

Directory of Open Access Journals (Sweden)

T. Petrut

2018-01-01

Full Text Available Monitoring sediment transport processes in rivers is of particular interest to engineers and scientists to assess the stability of rivers and hydraulic structures. Various methods for sediment transport process description were proposed using conventional or surrogate measurement techniques. This paper addresses the topic of the passive acoustic monitoring of bedload transport in rivers and especially the estimation of the bedload grain size distribution from self-generated noise. It discusses the feasibility of linking the acoustic signal spectrum shape to bedload grain sizes involved in elastic impacts with the river bed treated as a massive slab. Bedload grain size distribution is estimated by a regularized algebraic inversion scheme fed with the power spectrum density of river noise estimated from one hydrophone. The inversion methodology relies upon a physical model that predicts the acoustic field generated by the collision between rigid bodies. Here we proposed an analytic model of the acoustic energy spectrum generated by the impacts between a sphere and a slab. The proposed model computes the power spectral density of bedload noise using a linear system of analytic energy spectra weighted by the grain size distribution. The algebraic system of equations is then solved by least square optimization and solution regularization methods. The result of inversion leads directly to the estimation of the bedload grain size distribution. The inversion method was applied to real acoustic data from passive acoustics experiments realized on the Isère River, in France. The inversion of in situ measured spectra reveals good estimations of grain size distribution, fairly close to what was estimated by physical sampling instruments. These results illustrate the potential of the hydrophone technique to be used as a standalone method that could ensure high spatial and temporal resolution measurements for sediment transport in rivers.

Passive acoustic measurement of bedload grain size distribution using self-generated noise

Science.gov (United States)

Petrut, Teodor; Geay, Thomas; Gervaise, Cédric; Belleudy, Philippe; Zanker, Sebastien

2018-01-01

Monitoring sediment transport processes in rivers is of particular interest to engineers and scientists to assess the stability of rivers and hydraulic structures. Various methods for sediment transport process description were proposed using conventional or surrogate measurement techniques. This paper addresses the topic of the passive acoustic monitoring of bedload transport in rivers and especially the estimation of the bedload grain size distribution from self-generated noise. It discusses the feasibility of linking the acoustic signal spectrum shape to bedload grain sizes involved in elastic impacts with the river bed treated as a massive slab. Bedload grain size distribution is estimated by a regularized algebraic inversion scheme fed with the power spectrum density of river noise estimated from one hydrophone. The inversion methodology relies upon a physical model that predicts the acoustic field generated by the collision between rigid bodies. Here we proposed an analytic model of the acoustic energy spectrum generated by the impacts between a sphere and a slab. The proposed model computes the power spectral density of bedload noise using a linear system of analytic energy spectra weighted by the grain size distribution. The algebraic system of equations is then solved by least square optimization and solution regularization methods. The result of inversion leads directly to the estimation of the bedload grain size distribution. The inversion method was applied to real acoustic data from passive acoustics experiments realized on the Isère River, in France. The inversion of in situ measured spectra reveals good estimations of grain size distribution, fairly close to what was estimated by physical sampling instruments. These results illustrate the potential of the hydrophone technique to be used as a standalone method that could ensure high spatial and temporal resolution measurements for sediment transport in rivers.

A high sensitivity optically stimulated luminescence scanning system for measurement of single sand-sized grains

DEFF Research Database (Denmark)

Duller, G.A.T.; Bøtter-Jensen, L.; Kohsiek, P.

1999-01-01

An instrument has been designed for the routine analysis of the optically stimulated luminescence signal from single grains of sand. The system is capable of analysing over 3000 individual grains in a single measurement sequence, and the OSL signal from each grain can be read in less than 3 s....... The design principles are described, along with preliminary measurements that illustrate the operation of the system and its capabilities....

Development of a red TL detection system for a single grain of quartz

International Nuclear Information System (INIS)

Yawata, T.; Hashimoto, T.

2007-01-01

Red thermoluminescence (RTL) of natural quartz grains offers many desirable properties for quaternary chronology and archaeological dating, although RTL measurements suffer from high thermal background due to black-body radiation on heating. To reduce the thermal background to as low a level as possible, a silver sample disc covered with a biotite plate with a sample hole was used in combination with a light guide, cluster heater, optical filters, and photomultiplier tube cooling to -20 deg. C in the present system. As a result, the thermal background decreased from 2x10 4 to 1000 cps in the temperature range 350-380 deg. C, resulting in a detection limit of approximately 100 cps, corresponding to the RTL signal from a single quartz grain (250-500μm) irradiated with 4.0 Gy. In addition, application of lower heating rates retarded the thermal quenching effect, resulting in high RTL signals, which are preferable for young or insensitive quartz samples. Using RTL measurements with the single quartz grain method under optimal RTL conditions, comparison of equivalent doses from artificially irradiated single quartz grains to the known dose was within the 20% measurement error. Based on equivalent dose determinations for single quartz grains, large irregularities on non-etched quartz surfaces might be very detrimental to the TL detection process. This result confirms that surface etching treatment is required to achieve reliable dating with high counting efficiency

Scaling-based prediction of magnetic anisotropy in grain-oriented steels

Directory of Open Access Journals (Sweden)

Najgebauer Mariusz

2017-06-01

Full Text Available The paper presents the scaling-based approach to analysis and prediction of magnetic anisotropy in grain-oriented steels. Results of the anisotropy scaling indicate the existence of two universality classes. The hybrid approach to prediction of magnetic anisotropy, combining the scaling analysis with the ODFs method, is proposed. This approach is examined in prediction of angular dependencies of magnetic induction as well as magnetization curves for the 111-35S5 steel. It is shown that it is possible to predict anisotropy of magnetic properties based on measurements in three arbitrary directions for φ = 0°, 60° and 90°. The relatively small errors between predicted and measured values of magnetic induction are obtained.

Size Distribution and Rate of Dust Generated During Grain Elevator Handling

Science.gov (United States)

Dust generated during grain handling is an air pollutant that produces safety and health hazards. This study was conducted to characterize the particle size distribution (PSD) of dust generated during handling of wheat and shelled corn in the research elevator of the USDA Grain Marketing and Product...

Reshock and release response of aluminum single crystal

International Nuclear Information System (INIS)

Huang, H.; Asay, J. R.

2007-01-01

Reshock and release experiments were performed on single crystal aluminum along three orientations and on polycrystalline 1050 aluminum with 50 μm grain size at shock stresses of 13 and 21 GPa to investigate the mechanisms for previously observed quasielastic recompression behavior. Particle velocity profiles obtained during reshocking both single crystals and polycrystalline aluminum from initial shock stresses of 13-21 GPa show similar quasielastic recompression behavior. Quasielastic release response is also observed in all single crystals, but the magnitude of the effect is crystal orientation dependent, with [111] and [110] exhibiting more ideal elastic-plastic release for unloading from the shocked state than for the [100] orientation and polycrystalline aluminum. The quasielastic response of 1050 aluminum is intermediate to that of the [100] and [111] orientations. Comparison of the wave profiles obtained for both unloading and reloading of single crystals and polycrystalline 1050 aluminum from shocked states suggests that the observed quasielastic response of polycrystalline aluminum results from the averaging response of single crystals for shock propagation along different orientations, and that the response of 1050 aluminum with large grain boundaries is not significantly different from the results obtained on single crystal aluminum. The yield strength of the single crystals and 1050 aluminum is found to increase with shock stress, which is consistent with previous results [H. Huang and I. R. Asay, J. Appl. Phys. 98, 033524 (2005)

The Relevance of Grain Dissection for Grain Size Reduction in Polar Ice : Insight from Numerical Models and Ice Core Microstructure Analysis

NARCIS (Netherlands)

Steinbach, F.; Kuiper, E.N.; Eichler, J.; Bons, P. D.; Drury, M. R.; Griera, A.; Pennock, G.M.; Weikusat, I.

2017-01-01

The flow of ice depends on the properties of the aggregate of individual ice crystals, such as grain size or lattice orientation distributions. Therefore, an understanding of the processes controlling ice micro-dynamics is needed to ultimately develop a physically based macroscopic ice flow law. We

Influence of grain size distribution on dynamic shear modulus of sands

Directory of Open Access Journals (Sweden)

Dyka Ireneusz

2017-11-01

Full Text Available The paper presents the results of laboratory tests, that verify the correlation between the grain-size characteristics of non-cohesive soils and the value of the dynamic shear modulus. The problem is a continuation of the research performed at the Institute of Soil Mechanics and Rock Mechanics in Karlsruhe, by T. Wichtmann and T. Triantafyllidis, who derived the extension of the applicability of the Hardin’s equation describing the explicite dependence between the grain size distribution of sands and the values of dynamic shear modulus. For this purpose, piezo-ceramic bender elements generating elastic waves were used to investigate the mechanical properties of the specimens with artificially generated particle distribution. The obtained results confirmed the hypothesis that grain size distribution of non-cohesive soils has a significant influence on the dynamic shear modulus, but at the same time they have shown that obtaining unambiguous results from bender element tests is a difficult task in practical applications.

Sources of variability in OSL dose measurements using single grains of quartz

International Nuclear Information System (INIS)

Thomsen, K.J.; Murray, A.S.; Boetter-Jensen, L.

2005-01-01

In luminescence-based measurements of dose distributions in unheated mineral samples, the observed spread in dose values is usually attributed to four main factors: fluctuations in the number of photons counted, incomplete zeroing of any prior trapped charge (including signals arising from thermal transfer), heterogeneity in dosimetry, and instrument reproducibility. For correct interpretation of measured dose distributions in retrospective dosimetry, it is important to understand the relative importance of these components, and to establish whether other factors also contribute to the observed spread. In this preliminary study, dose distributions have been studied using single grains of heated and laboratory irradiated quartz. By heating the sample, the contribution from incomplete zeroing was excluded and at the same time the sample was sensitised. The laboratory gamma irradiation was designed to deliver a uniform dose to the sample. Thus it was anticipated that statistical fluctuations in the number of photons counted and instrument reproducibility, both quantifiable entities, should be able to account for all the observed variance in the measured dose distributions. We examine this assumption in detail, and discuss the origins and importance of the residual variance in our data

In situ neutron diffraction study of grain-orientation-dependent phase transformation in 304L stainless steel at a cryogenic temperature

International Nuclear Information System (INIS)

Tao Kaixiang; Wall, James J.; Li, Hongqi; Brown, Donald W.; Vogel, Sven C.; Choo, Hahn

2006-01-01

In situ time-of-flight neutron diffraction was performed to investigate the martensitic phase transformation during quasistatic uniaxial compression testing of 304L stainless steel at 300 and 203 K. In situ neutron diffraction enabled the bulk measurement of intensity evolution for various hkl atomic planes during the austenite (fcc) to martensite (hcp and bcc) phase transformation. Based on the neutron diffraction patterns, the martensite phases were observed from the very beginning of the plastic deformation at 203 K. However, at 300 K, no newly formed martensite, except a small amount of preexisting hcp phase, was observed throughout the test. From the changes in the relative intensities of individual hkl atomic planes, the grain-orientation-dependent phase transformation was investigated. The preferred orientation of the newly formed martensite grains was also investigated for the sample deformed at 203 K using neutron diffraction. The results reveal the orientation relationships between the austenite and the newly formed martensites. The fcc grain family diffracting with (200) plane normal parallel to the loading axis is favored for the fcc to bcc transformation and the bcc (200) plane normals are primarily aligned along the loading direction. For the fcc to hcp transformation, the fcc grains with (111) plane normals at an angle in between about 10 deg. and 50 deg. to the loading direction are favored

Structure analysis of aluminium silicon manganese nitride precipitates formed in grain-oriented electrical steels

International Nuclear Information System (INIS)

Bernier, Nicolas; Xhoffer, Chris; Van De Putte, Tom; Galceran, Montserrat; Godet, Stéphane

2013-01-01

We report a detailed structural and chemical characterisation of aluminium silicon manganese nitrides that act as grain growth inhibitors in industrially processed grain-oriented (GO) electrical steels. The compounds are characterised using energy dispersive X-ray spectrometry (EDX) and energy filtered transmission electron microscopy (EFTEM), while their crystal structures are analysed using X-ray diffraction (XRD) and TEM in electron diffraction (ED), dark-field, high-resolution and automated crystallographic orientation mapping (ACOM) modes. The chemical bonding character is determined using electron energy loss spectroscopy (EELS). Despite the wide variation in composition, all the precipitates exhibit a hexagonal close-packed (h.c.p.) crystal structure and lattice parameters of aluminium nitride. The EDX measurement of ∼ 900 stoichiometrically different precipitates indicates intermediate structures between pure aluminium nitride and pure silicon manganese nitride, with a constant Si/Mn atomic ratio of ∼ 4. It is demonstrated that aluminium and silicon are interchangeably precipitated with the same local arrangement, while both Mn 2+ and Mn 3+ are incorporated in the h.c.p. silicon nitride interstitial sites. The oxidation of the silicon manganese nitrides most likely originates from the incorporation of oxygen during the decarburisation annealing process, thus creating extended planar defects such as stacking faults and inversion domain boundaries. The chemical composition of the inhibitors may be written as (AlN) x (SiMn 0.25 N y O z ) 1−x with x ranging from 0 to 1. - Highlights: • We study the structure of (Al,Si,Mn)N inhibitors in grain oriented electrical steels. • Inhibitors have the hexagonal close-packed symmetry with lattice parameters of AlN. • Inhibitors are intermediate structures between pure AlN and (Si,Mn)N with Si/Mn ∼ 4. • Al and Si share the same local arrangement; Mn is incorporated in both Mn 2+ and Mn 3+ . • Oxygen

Single-grain OSL dating of Early Middle Palaeolithic deposits at Cuesta de la Bajada, Ebro Basin, Spain

Science.gov (United States)

Arnold, Lee; Demuro, Martina; Santonja, Manuel; Perez-Gonzalez, Alfredo; Pares, Josep

2013-04-01

-response curves with very high saturation limits. The latter offers the advantage of extending the age range over which single-grain techniques can be applied in this Middle Pleistocene context. Dose-recovery tests performed at high doses of 470 Gy yielded accurate equivalent dose (De) results with low overdispersion, providing reasonable confidence in the chosen measurement conditions. Three of the samples display single-grain De distributions with low levels of dispersion indicating that the sediments were adequately bleached prior to burial and remained undisturbed thereafter. The fourth sample displays higher De dispersion and a younger subpopulation of grains, which could be explained by beta-dose heterogeneity associated with interspersed gravels within the basal archaeological horizon. We apply various statistical age models to derive final chronologies and compare the resultant single-grain ages with those obtained using different absolute dating methods. We also report on experiments performed using 'synthetic multi-grain aliquots' created from the single-grain De datasets, and discuss their implications for the reliability of multi-grain OSL dating techniques in this context.

78 FR 59059 - Grain-Oriented Electrical Steel From China, Czech Republic, Germany, Japan, Korea, Poland, and...

Science.gov (United States)

2013-09-25

...)] Grain-Oriented Electrical Steel From China, Czech Republic, Germany, Japan, Korea, Poland, and Russia... Republic, Germany, Japan, Korea, Poland, and Russia that are alleged to be sold in the United States at less than fair value. Unless the Department of Commerce extends the time for initiation pursuant to...

Analysis of microstructure and microtexture in grain-oriented electrical steel (GOES during manufacturing process

Directory of Open Access Journals (Sweden)

A. Volodarskaja

2015-10-01

Full Text Available The final Goss texture in grain-oriented electrical steels (GOES is affected by microstructure evolution and inheritance during the whole production process. This paper presents the results of detailed microtexture and microstructure investigations on GOES after the basic steps of the industrial AlN + Cu manufacturing process: hot rolling, first cold rolling + decarburization annealing, second cold rolling and final high temperature annealing. Microstructure studies showed that a copper addition to GOES affected solubility of sulphides. Copper rich sulphides dissolved during hot rolling and re-precipitated during decarburization annealing. An intensive precipitation of AlN and Si3N4 took place during decarburization annealing. No ε - Cu precipitation was detected. After high temperature annealing the misorientation of individual grains reached up to 8°.

Evolution of grain boundary character distributions in alloy 825 tubes during high temperature annealing: Is grain boundary engineering achieved through recrystallization or grain growth?

International Nuclear Information System (INIS)

Bai, Qin; Zhao, Qing; Xia, Shuang; Wang, Baoshun; Zhou, Bangxin; Su, Cheng

2017-01-01

Grain boundary engineering (GBE) of nickel-based alloy 825 tubes was carried out with different cold drawing deformations by using a draw-bench on a factory production line and subsequent annealing at various temperatures. The microstructure evolution of alloy 825 during thermal-mechanical processing (TMP) was characterized by means of the electron backscatter diffraction (EBSD) technique to study the TMP effects on the grain boundary network and the evolution of grain boundary character distributions during high temperature annealing. The results showed that the proportion of ∑ 3 n coincidence site lattice (CSL) boundaries of alloy 825 tubes could be increased to > 75% by the TMP of 5% cold drawing and subsequent annealing at 1050 °C for 10 min. The microstructures of the partially recrystallized samples and the fully recrystallized samples suggested that the proportion of low ∑ CSL grain boundaries depended on the annealing time. The frequency of low ∑ CSL grain boundaries increases rapidly with increasing annealing time associating with the formation of large-size highly-twinned grains-cluster microstructure during recrystallization. However, upon further increasing annealing time, the frequency of low ∑ CSL grain boundaries decreased markedly during grain growth. So it is concluded that grain boundary engineering is achieved through recrystallization rather than grain growth. - Highlights: •The grain boundary engineering (GBE) is applicable to 825 tubes. •GBE is achieved through recrystallization rather than grain growth. •The low ∑ CSL grain boundaries in 825 tubes can be increased to > 75%.

Grain Refinement and Texture Mitigation in Low Boron Containing TiAl-Alloys

Science.gov (United States)

Hecht, Ulrike; Witusiewicz, Victor T.

2017-12-01

Controlling the grain size and texture of lamellar TiAl-alloys is essential for well-balanced creep and fatigue properties. Excellent refinement and texture mitigation are achieved in aluminum lean alloys by low boron additions of 0.2 at.%. This amount is sufficient to promote in situ formation of ultrafine borides during the last stages of body centered cubic (BCC) solidification. The borides subsequently serve as nucleation sites for hexagonal close packed (HCP) during the BCC-HCP phase transformation. Bridgman solidification experiments with alloy Ti-43Al-8Nb-0.2C-0.2B were performed under a different growth velocity, i.e., cooling rate, to evaluate the HCP grain size distribution and texture. For slow-to-moderate cooling rates, about 65% of HCP grains are randomly oriented, despite the pronounced texture of the parent BCC phase resulting from directional solidification. For high cooling rates, obtained by quenching, texture mitigation is less pronounced. Only 28% of the HCP grains are randomly oriented, the majority being crystallographic variants of the Burgers orientation relationship.

Modeling the effect of neighboring grains on twin growth in HCP polycrystals

Science.gov (United States)

Kumar, M. Arul; Beyerlein, I. J.; Lebensohn, R. A.; Tomé, C. N.

2017-09-01

In this paper, we study the dependence of neighboring grain orientation on the local stress state around a deformation twin in a hexagonal close packed (HCP) crystal and its effects on the resistance against twin thickening. We use a recently developed, full-field elasto-visco-plastic formulation based on fast Fourier transforms that account for the twinning shear transformation imposed by the twin lamella. The study is applied to Mg, Zr and Ti, since these HCP metals tend to deform by activation of different types of slip modes. The analysis shows that the local stress along the twin boundary are strongly controlled by the relative orientation of the easiest deformation modes in the neighboring grain with respect to the twin lamella in the parent grain. A geometric expression that captures this parent-neighbor relationship is proposed and incorporated into a larger scale, mean-field visco-plastic self-consistent model to simulate the role of neighboring grain orientation on twin thickening. We demonstrate that the approach improves the prediction of twin area fraction distribution when compared with experimental observations.

Crystallographic orientation study of silicon steels using X-ray diffraction, electrons diffraction and the Etch Pit method

International Nuclear Information System (INIS)

Santos, Hamilta de Oliveira

1999-01-01

The aim of the present study is the microstructural and crystallographic orientation of Fe-3%Si steel. The silicon steel shows good electrical properties and it is used in the nuclear and electrical power fields. The studied steel was supplied by Cia. Acos Especiais Itabira S/A - ACESITA. The material was received in the hot compressed condition, in one or two passes. The hot compressing temperatures used were 900, 1000 and 1100 deg C with soaking times ranging from 32 to 470 s. The material preferential crystallographic orientation was evaluated in every grain of the samples. The characterization techniques used were: scanning electron microscopy (SEM) using the etch pit method; X ray diffraction using the Laue back-reflection method; orientation imaging microscopy (OIM). Microstructural characterization in terms of grain size measurement and mean number of grains in the sample were also undertaken. The Laue method was found an easy technique to access crystallographic orientation of this work polycrystalline samples 2.5 mm average grain size. This was due to the inability to focus the X-rays on a single grain of the material. The scanning electron microscopy showed microcavities left by the etch pit method, which allowed the observation of the crystallographic orientation of each grain from the samples. No conclusive grain crystallographic orientation was possible to obtain by the OIM technique due to the non-existing rolling direction. A more extensive work with the OIM technique must be undertaken on the Fe-3%Si with oriented grains and non oriented grains. (author)

Effect of Strain Restored Energy on Abnormal Grain Growth in Mg Alloy Simulated by Phase Field Methods

Science.gov (United States)

Wu, Yan; Huang, Yuan-yuan

2018-03-01

Abnormal grain growth of single phase AZ31 Mg alloy in the spatio-temporal process has been simulated by phase field models, and the influencing factors of abnormal grain growth are studied in order to find the ways to control secondary recrystallization in the microstructure. The study aims to find out the mechanisms for abnormal grain growth in real alloys. It is shown from the simulated results that the abnormal grain growth can be controlled by the strain restored energy. Secondary recrystallization after an annealing treatment can be induced if there are grains of a certain orientation in the microstructure with local high restored energy. However, if the value of the local restored energy at a certain grain orientation is not greater than 1.1E 0, there may be no abnormal grain growth in the microstructure.

Interactions between the phase stress and the grain-orientation-dependent stress in duplex stainless steel during deformation

International Nuclear Information System (INIS)

Jia, N.; Peng, R. Lin; Wang, Y.D.; Chai, G.C.; Johansson, S.; Wang, G.; Liaw, P.K.

2006-01-01

The development of phase stress and grain-orientation-dependent stress under uniaxial compression was investigated in a duplex stainless steel consisting of austenite and ferrite. Using in situ neutron diffraction measurements, the strain response of several h k l planes to the applied compressive stress was mapped as a function of applied stress and sample direction. Analysis based on the experimental results and elastoplastic self-consistent simulations shows that phase stresses of thermal origin further increase during elastic loading but decrease with increased plastic deformation. Grain-orientation-dependent stresses become significant in both austenite and ferrite after loading into the plastic region. After unloading from the plastic regime, a considerable intergranular stress remains in the austenitic phase and dominates over the phase stress. This study provides fundamental experimental inputs for future micromechanical modeling aiming at the evaluation and prediction of the mechanical performance of multiphase materials

Oriented hydroxyapatite single crystals produced by the electrodeposition method

Energy Technology Data Exchange (ETDEWEB)

Santos, E.A. dos, E-mail: euler@ufs.br [INSA - Groupe Ingenierie des Surfaces, 24, Bld de la Victoire, 67084 Strasbourg (France); IPCMS - Departement de Surfaces et Interfaces, 23, rue du Loess, BP 43, 67034 Strasbourg (France); Moldovan, M.S. [INSA - Groupe Ingenierie des Surfaces, 24, Bld de la Victoire, 67084 Strasbourg (France); IPCMS - Departement de Surfaces et Interfaces, 23, rue du Loess, BP 43, 67034 Strasbourg (France); Jacomine, L. [INSA - Groupe Ingenierie des Surfaces, 24, Bld de la Victoire, 67084 Strasbourg (France); Mateescu, M. [IS2M - Equipe Interaction Surface-Matiere Vivant, 15, rue Jean Starcky, BP 2488, 68057 Mulhouse (France); Werckmann, J. [IPCMS - Departement de Surfaces et Interfaces, 23, rue du Loess, BP 43, 67034 Strasbourg (France); Anselme, K. [IS2M - Equipe Interaction Surface-Matiere Vivant, 15, rue Jean Starcky, BP 2488, 68057 Mulhouse (France); Mille, P.; Pelletier, H. [INSA - Groupe Ingenierie des Surfaces, 24, Bld de la Victoire, 67084 Strasbourg (France)

2010-05-25

We propose here the use of cathodic electrodeposition as tool to fabricate implant coatings consisting in nano/micro single crystals of hydroxyapatite (HA), preferentially orientated along the c-axis. Coating characterization is the base of this work, where we discuss the mechanisms related to the deposition of oriented hydroxyapatite thin films. It is shown that when deposited on titanium alloys, the HA coating is constituted by two distinct regions with different morphologies: at a distance of few microns from the substrate, large HA single crystals are oriented along the c-axis and appear to grow up from a base material, consisting in an amorphous HA. This organized system has a great importance for cell investigation once the variables involved in the cell/surface interaction are reduced. The use of such systems could give a new insight on the effect of particular HA orientation on the osteoblast cells.

Single-Sex Schooling: Friendships, Dating, and Sexual Orientation.

Science.gov (United States)

Li, Gu; Wong, Wang Ivy

2018-05-01

Single-sex schooling has been controversial for decades. The current study investigated the differences in friendships, dating, and past, present, and ideal sexual orientation, between 207 college students who attended single-sex secondary schools and 249 college students who attended coeducational secondary schools in Hong Kong, controlling for personal characteristics such as socioeconomic status. We found that, compared to graduates of coeducational schools, graduates of single-sex schools reported a different gender composition in intimate friendships favoring the same sex, less romantic involvement with other-sex close friends, older age at first date, fewer boyfriends or girlfriends, and more past same-sex sexuality. In contrast, we found no significant differences in the interactions with same-sex versus other-sex friends, most aspects of past or present dating engagement, or self-reported present or ideal sexual orientation. These findings give insight into the interpersonal outcomes of single-sex schooling and fill a gap in previous research which has focused on academic achievement and gender role stereotypes.

Oriented growing and anisotropy of emission properties of lanthanum hexaboride single crystals

International Nuclear Information System (INIS)

Lazorenko, V.I.; Lotsko, D.V.; Platonov, V.F.; Kovalev, A.V.; Galasun, A.P.; Matvienko, A.A.; Klinkov, A.E.

1987-01-01

Single crystals of lanthanum hexaboride with preset crystallographic orientation are grown by the method of crucible-free zone melting. It is shown that oriented growing of single crystals of the given compound is possible only when using seed crystals of the required orientation because no predominant orientation of the LaB 6 growth is found in case of spontaneous crystallization. Orientation of spontaneously growing LaB 6 crystals does not depend on their growth rate, degree of the melt diffusion annealing, purity of the inital powder. Anisotropy of the electronic work function for single crystal lanthanum hexaboride is confirmed. Its value grows as (100)<(110)<(111). Conditions of the preliminary thermovacuum purification of the surface are shown to affect the measured work function

Micromagnetic simulation of the orientation dependence of grain boundary properties on the coercivity of Nd-Fe-B sintered magnets

Directory of Open Access Journals (Sweden)

Jun Fujisaki

2016-05-01

Full Text Available This paper is focused on the micromagnetic simulation study about the orientation dependence of grain boundary properties on the coercivity of polycrystalline Nd-Fe-B sintered magnets. A multigrain object with a large number of meshes is introduced to analyze such anisotropic grain boundaries and the simulation is performed by combining the finite element method and the parallel computing. When the grain boundary phase parallel to the c-plane is less ferromagnetic the process of the magnetization reversal changes and the coercivity of the multigrain object increases. The simulations with various magnetic properties of the grain boundary phases are executed to search for the way to enhance the coercivity of polycrystalline Nd-Fe-B sintered magnets.

Formation of {1 0 0} textured columnar grain structure in a non-oriented electrical steel by phase transformation

Energy Technology Data Exchange (ETDEWEB)

Xie, Li; Yang, Ping, E-mail: yangp@mater.ustb.edu.cn; Zhang, Ning; Zong, Cui; Xia, Dongsheng; Mao, Weimin

2014-04-01

This study confirms the effect of anisotropic strain energy on the formation of {1 0 0} textured columnar grain structure induced by temperature gradient during γ to α phase transformation in pure hydrogen atmosphere. Results indicate that high temperature gradient in pure hydrogen atmosphere induces a significant strain energy difference across grain boundaries during γ to α phase transformation, leading to the formation of {1 0 0} texture with columnar grains. Given its simplicity in processing and its ability to obtain good texture-related magnetic properties, the proposed approach is helpful to the development of new types of non-oriented electrical steel. - Highlights: • A strong {1 0 0} texture with columnar grains was obtained. • Good texture and magnetic properties are attributed to the anisotropic strain energy. • The anisotropy in elastic strain energy was induced by the temperature gradient. • The phase transformation rate affects columnar grain morphology.

Investigation of the role of grain boundary on the mechanical properties of metals

International Nuclear Information System (INIS)

Kheradmand, Nousha; Barnoush, Afrooz; Vehoff, Horst

2010-01-01

Compression testing of micropillars was used to investigate the gain boundary effect on the strength of metals which is especially interesting in ultra fine grained and nanocrystalline metals. Single and bicrystal micropillars of different sizes and crystallographic orientations were fabricated using a focused ion beam system and the compression test was performed with a nanoindenter. A reduction of the pillar size as well as the introduction of a grain boundary results in an increase in the yield strength. The results show that the size and the orientation of different adjoining crystals in bicrystalline pillars have an obvious effect on dislocation nucleation and multiplication.

Environmental monitoring of Columbia River sediments: Grain-size distribution and contaminant association

Energy Technology Data Exchange (ETDEWEB)

Blanton, M.L.; Gardiner, W.W.; Dirkes, R.L.

1995-04-01

Based on the results of this study and literature review, the following conclusions can be made: Sediment grain size and TOC (total organic carbon) influence contaminant fate and transport (in general, sediments with higher TOC content and finer grain-size distribution can have higher contaminant burdens than sediments from a given river section that have less TOC and greater amounts of coarse-grained sediments). Physiochemical sediment characteristics are highly variable among monitoring sites along the Columbia River. Sediment grain characterization and TOC analysis should be included in interpretations of sediment-monitoring data.

Environmental monitoring of Columbia River sediments: Grain-size distribution and contaminant association

International Nuclear Information System (INIS)

Blanton, M.L.; Gardiner, W.W.; Dirkes, R.L.

1995-04-01

Based on the results of this study and literature review, the following conclusions can be made: Sediment grain size and TOC (total organic carbon) influence contaminant fate and transport (in general, sediments with higher TOC content and finer grain-size distribution can have higher contaminant burdens than sediments from a given river section that have less TOC and greater amounts of coarse-grained sediments). Physiochemical sediment characteristics are highly variable among monitoring sites along the Columbia River. Sediment grain characterization and TOC analysis should be included in interpretations of sediment-monitoring data

Grain-size dependent accommodation due to intragranular distributions of dislocation loops

International Nuclear Information System (INIS)

Richeton, T.; Berbenni, S.; Berveiller, M.

2009-01-01

A grain-size dependent accommodation law for polycrystals is deduced from an inclusion/matrix problem (i.e., each grain is seen as embedded in a homogeneous equivalent medium) where plastic strain inside the inclusion is given as a discrete distribution of circular coaxial glide dislocation loops. The loops are assumed constrained at spherical grain boundaries. From thermodynamic considerations specific to a process of identical plastification in all the loops (considered as 'super-dislocations'), an average back-stress over the grain is derived. In order to compute the very early stages of plastic deformation in a face-centred cubic polycrystal, this back-stress is incorporated into a diluted model in terms of concentration of plastic grains. Contrary to conventional mean-field approaches, a grain-size effect is obtained for the initial overall strain-hardening behaviour. This size effect results from an intrinsic contribution of intragranular slip heterogeneities on the kinematical hardening

Transmural variation in elastin fiber orientation distribution in the arterial wall.

Science.gov (United States)

Yu, Xunjie; Wang, Yunjie; Zhang, Yanhang

2018-01-01

The complex three-dimensional elastin network is a major load-bearing extracellular matrix (ECM) component of an artery. Despite the reported anisotropic behavior of arterial elastin network, it is usually treated as an isotropic material in constitutive models. Our recent multiphoton microscopy study reported a relatively uniform elastin fiber orientation distribution in porcine thoracic aorta when imaging from the intima side (Chow et al., 2014). However it is questionable whether the fiber orientation distribution obtained from a small depth is representative of the elastin network structure in the arterial wall, especially when developing structure-based constitutive models. To date, the structural basis for the anisotropic mechanical behavior of elastin is still not fully understood. In this study, we examined the transmural variation in elastin fiber orientation distribution in porcine thoracic aorta and its association with elastin anisotropy. Using multi-photon microscopy, we observed that the elastin fibers orientation changes from a relatively uniform distribution in regions close to the luminal surface to a more circumferential distribution in regions that dominate the media, then to a longitudinal distribution in regions close to the outer media. Planar biaxial tensile test was performed to characterize the anisotropic behavior of elastin network. A new structure-based constitutive model of elastin network was developed to incorporate the transmural variation in fiber orientation distribution. The new model well captures the anisotropic mechanical behavior of elastin network under both equi- and nonequi-biaxial loading and showed improvements in both fitting and predicting capabilities when compared to a model that only considers the fiber orientation distribution from the intima side. We submit that the transmural variation in fiber orientation distribution is important in characterizing the anisotropic mechanical behavior of elastin network and

Monte carlo simulation of anisotropic grain growth in liquid phase sintering

International Nuclear Information System (INIS)

Han, Yoon Soo; Kim, Do Kyung

2003-01-01

One of the key techniques in modern engineering ceramic system is microstructural control of anisotropic grain growth because grain orientation and shape proved to have an influence on mechanic, dielectric and electric behavior of ceramics. But until now, computer simulation for grain growth has not sufficiently addressed to this subject. The reason is that simulation algorithm was laborious because it has to contain mass transfer through liquid phase and especially anisotropic grain growth has to be considered based on interfacial properties in real system. The goal of present study is simulation of anisotropic grain growth in liquid phase by Q-states model. To give anisotropic inherency to grains, constraint on mobility to specific boundaries was applied. For comparison, we measured grain size distribution and deduced grain growth kinetics from relation ship between average grain size and time. As a result, the grain size distribution functions become broader and the peak height decreases as the anisotropy is increased. The growth exponent 0.67 and 0.47 found by linear fitting have slightly different values in comparison with work of Grest et al. but similar is trend to the decrease of exponent with anisotropy

Developing Distributed System With Service Resource Oriented Architecture

Directory of Open Access Journals (Sweden)

Hermawan Hermawan

2012-06-01

Full Text Available Service Oriented Architecture is a design paradigm in software engineering with which a distributed system is built for an enterprise. This paradigm aims at providing the system as a service through a protocol in web service technology, namely Simple Object Access Protocol (SOAP. However, SOA is service level agreements of webservice. For this reason, this reasearch aims at combining SOA with Resource Oriented Architecture in order to expand scalability of services. This combination creates Sevice Resource Oriented Architecture (SROA with which a distributed system is developed that integrates services within project management software. Following this design, the software is developed according to a framework of Agile Model Driven Development which can reduce complexities of the whole process of software development.

Influence of orientation mismatch on charge transport across grain boundaries in tri-isopropylsilylethynyl (TIPS) pentacene thin films.

Science.gov (United States)

Steiner, Florian; Poelking, Carl; Niedzialek, Dorota; Andrienko, Denis; Nelson, Jenny

2017-05-03

We present a multi-scale model for charge transport across grain boundaries in molecular electronic materials that incorporates packing disorder, electrostatic and polarisation effects. We choose quasi two-dimensional films of tri-isopropylsilylethynyl pentacene (TIPS-P) as a model system representative of technologically relevant crystalline organic semiconductors. We use atomistic molecular dynamics, with a force-field specific for TIPS-P, to generate and equilibrate polycrystalline two-dimensional thin films. The energy landscape is obtained by calculating contributions from electrostatic interactions and polarization. The variation in these contributions leads to energetic barriers between grains. Subsequently, charge transport is simulated using a kinetic Monte-Carlo algorithm. Two-grain systems with varied mutual orientation are studied. We find relatively little effect of long grain boundaries due to the presence of low impedance pathways. However, effects could be more pronounced for systems with limited inter-grain contact areas. Furthermore, we present a lattice model to generalize the model for small molecular systems. In the general case, depending on molecular architecture and packing, grain boundaries can result in interfacial energy barriers, traps or a combination of both with qualitatively different effects on charge transport.

Orientation-controlled synthesis and magnetism of single crystalline Co nanowires

International Nuclear Information System (INIS)

Huang, Gui-Fang; Huang, Wei-Qing; Wang, Ling-Ling; Zou, B.S.; Pan, Anlian

2012-01-01

Orientation control and the magnetic properties of single crystalline Co nanowires fabricated by electrodeposition have been systematically investigated. It is found that the orientation of Co nanowires can be effectively controlled by varying either the current density or the pore diameter of AAO templates. Lower current density or small diameter is favorable for forming the (1 0 0) texture, while higher current values or larger diameter leads to the emergence and enhancement of (1 1 0) texture of Co nanowires. The mechanism for the manipulated growth characterization is discussed in detail. The orientation of Co nanowires has a significant influence on the magnetic properties, resulting from the competition between the magneto-crystalline and shape anisotropy of Co nanowires. This work offers a simple method to manipulate the orientation and magnetic properties of nanowires for future applications. - Highlights: ► Single crystalline Co nanowires have successfully been grown by DC electrodeposition. ► Orientation controlling and its effect on magnetism of Co nanowires were investigated. ► The orientation of Co nanowires can be effectively controlled by varying current density. ► The crystalline orientation of Co nanowires has significant influence on the magnetic properties.

Optical dating of single sand-sized grains of quartz: Sources of variability

DEFF Research Database (Denmark)

Duller, G.A.T.; Bøtter-Jensen, L.; Murray, A.S.

2000-01-01

of measuring single grains it is feasible to routinely measure the equivalent dose from many hundreds of grains from each sample. Analysis of such datasets requires assessment of the uncertainties on each equivalent dose since these may vary significantly. This paper assesses the significance of signal...... intensity, dose saturation characteristics and instrument uncertainty in equivalent dose calculation. (C) 2000 Elsevier Science Ltd. All rights reserved....

Non-destructive analysis of micro texture and grain boundary character from X-ray diffraction contrast tomography

DEFF Research Database (Denmark)

King, A.; Herbig, M.; Ludwig, W.

2010-01-01

Recent advances in synchrotron based X-ray imaging and diffraction techniques offer interesting new possibilities for mapping 3D grain shapes and crystallographic orientations in different classes of polycrystalline materials. X-ray diffraction contrast tomography (DCT) is a monochromatic beam...... imaging technique combining the principles of X-ray micro-tomography and three-dimensional X-ray diffraction microscopy (3DXRD). DCT provides simultaneous access to 3D grain shape, crystallographic orientation and attenuation coefficient distribution at the micrometer length scale. The microtexture...

The mechanical behavior of metal alloys with grain size distribution in a wide range of strain rates

Science.gov (United States)

Skripnyak, V. A.; Skripnyak, V. V.; Skripnyak, E. G.

2017-12-01

The paper discusses a multiscale simulation approach for the construction of grain structure of metals and alloys, providing high tensile strength with ductility. This work compares the mechanical behavior of light alloys and the influence of the grain size distribution in a wide range of strain rates. The influence of the grain size distribution on the inelastic deformation and fracture of aluminium and magnesium alloys is investigated by computer simulations in a wide range of strain rates. It is shown that the yield stress depends on the logarithm of the normalized strain rate for light alloys with a bimodal grain distribution and coarse-grained structure.

Cyclic saturation dislocation structures of multiple-slip-oriented copper single crystals

International Nuclear Information System (INIS)

Li, X.W.; Chinese Academy of Sciences, Shenyang; Umakoshi, Y.; Li, S.X.; Wang, Z.G.

2001-01-01

The dislocation structures of [011] and [ anti 111] multiple-slip-oriented Cu single crystals cyclically saturated at constant plastic strain amplitudes were investigated through transmission electron microscopy. The results obtained on [001] multiple-slip-oriented Cu single crystals were also included for summarization. Unlike the case for single-slip-oriented Cu single crystals, the crystallographic orientation has a strong effect on the saturation dislocation structure in these three multiple-slip-oriented crystals. For the [011] crystal, different dislocation patterns such as veins, PSB walls, labyrinths and PSB ladders were observed. The formation of PSB ladders is believed to be a major reason for the existence of a plateau region in the cyclic stress-strain (CSS) curve for the [011] crystal. The cyclic saturation dislocation structure of a [ anti 111] crystal cycled at a low applied strain amplitude γ pl of 2.0 x 10 -4 was found to consist of irregular cells, which would develop into a more regular arrangement (e. g. PSB ladder-like) and the scale of which tends to decrease with increasing γ pl . Finally, three kinds of representative micro-deformation mode were summarized and termed as labyrinth-mode (or [001]-mode), cell-mode (or [ anti 111]-mode) and PSB ladder-mode (or [011]-mode). (orig.)

Orientation Characterisation of Aerospace Materials by Spatially Resolved Acoustic Spectroscopy

International Nuclear Information System (INIS)

Li, Wenqi; Coulson, Jethro; Smith, Richard J; Clark, Matt; Somekh, Michael G; Sharples, Steve D; Aveson, John W

2014-01-01

Material characteristics in metals such as strength, stiffness and fracture resistance are strongly related to the underlying microstructure. The crystallographic structure and orientation are related to the ultrasonic properties through the stiffness matrix. In individual grains it is possible to analytically determine the ultrasonic velocity from the orientation and stiffness, or determine the stiffness from the known orientation and measured velocity. In this paper we present a technique for imaging the crystallographic orientation of grains in metals using spatially resolved acoustic spectroscopy (SRAS) and a novel inverse solver that can determine the crystallographic orientation from the known stiffness matrix for the material and the SRAS velocity measurement. Previously we have shown the ability of this technique to determine the orientation on single crystal nickel samples; we extended the technique to multigrain industrial metals, such as aluminium, nickel and Inconel. The comparison between SRAS and electron backscatter diffraction (EBSD) on the nickel sample is presented. SRAS is a fast, accurate, quantitative and robust technique for imaging material microstructure and orientation over a wide range of scales and industrial materials

Transport properties of olivine grain boundaries from electrical conductivity experiments

Science.gov (United States)

Pommier, Anne; Kohlstedt, David L.; Hansen, Lars N.; Mackwell, Stephen; Tasaka, Miki; Heidelbach, Florian; Leinenweber, Kurt

2018-05-01

Grain boundary processes contribute significantly to electronic and ionic transports in materials within Earth's interior. We report a novel experimental study of grain boundary conductivity in highly strained olivine aggregates that demonstrates the importance of misorientation angle between adjacent grains on aggregate transport properties. We performed electrical conductivity measurements of melt-free polycrystalline olivine (Fo90) samples that had been previously deformed at 1200 °C and 0.3 GPa to shear strains up to γ = 7.3. The electrical conductivity and anisotropy were measured at 2.8 GPa over the temperature range 700-1400 °C. We observed that (1) the electrical conductivity of samples with a small grain size (3-6 µm) and strong crystallographic preferred orientation produced by dynamic recrystallization during large-strain shear deformation is a factor of 10 or more larger than that measured on coarse-grained samples, (2) the sample deformed to the highest strain is the most conductive even though it does not have the smallest grain size, and (3) conductivity is up to a factor of 4 larger in the direction of shear than normal to the shear plane. Based on these results combined with electrical conductivity data for coarse-grained, polycrystalline olivine and for single crystals, we propose that the electrical conductivity of our fine-grained samples is dominated by grain boundary paths. In addition, the electrical anisotropy results from preferential alignment of higher-conductivity grain boundaries associated with the development of a strong crystallographic preferred orientation of the grains.

Antigorite crystallographic preferred orientations in serpentinites from Japan

Science.gov (United States)

Soda, Yusuke; Wenk, Hans-Rudolf

2014-03-01

Foliated antigorite serpentinites are contributing to seismic anisotropy in subduction zones. However, uncertainty remains regarding the development of antigorite crystal preferred orientations (CPO). This study analyzes the CPOs of antigorite and olivine in variably serpentinized samples of antigorite serpentinite from three localities in Southwest Japan, using U-stage, EBSD, and synchrotron X-rays. In all samples (010) poles show a maximum parallel to the lineation, and (001) poles concentrate normal to the foliation with a partial girdle about the lineation. (100) poles are less distinct and scatter widely. The three measurement methods give similar results, though orientation distributions from X-ray analysis which averages over larger sample volumes are more regular and weaker than U-stage and EBSD which focuses on local well-crystallized grains. In olivine-bearing serpentinite, the olivine CPO does not appear to control the antigorite CPO, though there are some topotactic relationships. The antigorite CPO formed contemporaneously with serpentinization and shear deformation. Based on our analyses, in a subduction zone mantle wedge, the (010) pole of antigorite is parallel to the direction of the subduction, and (001) lattice planes are parallel to the interface of the subducting oceanic plate. By averaging single crystal elastic properties over orientation distributions wave velocities have been calculated. Fast P velocities are parallel to the subduction direction and slow velocities are perpendicular to the subducting plate with an anisotropy of 10-15%.

LM-OSL from single grains of quartz: A preliminary study

DEFF Research Database (Denmark)

Bulur, E.; Duller, G.A.T.; Solongo, S.

2002-01-01

the easy-to-bleach component, those with only the hard-to-bleach component, and those exhibiting all components. The results of this preliminary study show that LM-OSL experiments carried out at the single grain level may give important insights into the luminescence properties observed when viewing...

Single molecule fluorescence image patterns linked to dipole orientation and axial position: application to myosin cross-bridges in muscle fibers.

Directory of Open Access Journals (Sweden)

Thomas P Burghardt

2011-02-01

Full Text Available Photoactivatable fluorescent probes developed specifically for single molecule detection extend advantages of single molecule imaging to high probe density regions of cells and tissues. They perform in the native biomolecule environment and have been used to detect both probe position and orientation.Fluorescence emission from a single photoactivated probe captured in an oil immersion, high numerical aperture objective, produces a spatial pattern on the detector that is a linear combination of 6 independent and distinct spatial basis patterns with weighting coefficients specifying emission dipole orientation. Basis patterns are tabulated for single photoactivated probes labeling myosin cross-bridges in a permeabilized muscle fiber undergoing total internal reflection illumination. Emitter proximity to the glass/aqueous interface at the coverslip implies the dipole near-field and dipole power normalization are significant affecters of the basis patterns. Other characteristics of the basis patterns are contributed by field polarization rotation with transmission through the microscope optics and refraction by the filter set. Pattern recognition utilized the generalized linear model, maximum likelihood fitting, for Poisson distributed uncertainties. This fitting method is more appropriate for treating low signal level photon counting data than χ(2 minimization.Results indicate that emission dipole orientation is measurable from the intensity image except for the ambiguity under dipole inversion. The advantage over an alternative method comparing two measured polarized emission intensities using an analyzing polarizer is that information in the intensity spatial distribution provides more constraints on fitted parameters and a single image provides all the information needed. Axial distance dependence in the emission pattern is also exploited to measure relative probe position near focus. Single molecule images from axial scanning fitted

A method of producing small grain Ru intermediate layers for perpendicular magnetic media

International Nuclear Information System (INIS)

Yuan Hua; Qin Yueling; Laughlin, David E.

2008-01-01

NiAl + SiO 2 thin films were used as a grain size reducing seedlayer for cobalt alloy granular perpendicular magnetic recording media. The effect of this NiAl + SiO 2 seedlayer on the microstructure and crystalline orientation of Ru intermediate layer has been investigated. By co-sputtering the composite NiAl + SiO 2 seedlayer, the smallest average grain diameter of NiAl was significantly reduced to about 2.5 nm. The grain size of the subsequent Ru intermediate layer was reduced to about 4 nm. X-ray diffraction results indicate an epitaxial orientation relationship of NiAl (110) // Ru (0002) between the two layers. Moreover, significant improvement of this epitaxial relationship was developed, which produced narrow c-axis distribution of the Ru intermediate layer with small grain size. The addition of the NiAl + SiO 2 seedlayer is a very promising approach to reduce the Ru intermediate layer grain size and eventually the magnetic layer grain size for perpendicular magnetic recording media without deterioration of other properties of thin films

Grain-orientation-dependent of γ–ε–α′ transformation and twinning in a super-high-strength, high ductility austenitic Mn-steel

Energy Technology Data Exchange (ETDEWEB)

Eskandari, M., E-mail: m.eskandari@scu.ac.ir [Department of Materials Science & Engineering, Faculty of Engineering, Shahid Chamran University of Ahvaz, Ahvaz (Iran, Islamic Republic of); Zarei-Hanzaki, A. [Hot Deformation & Thermo-mechanical Processing of High Performance Engineering Materials, School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Mohtadi-Bonab, M.A. [Department of Mechanical Engineering, University of Bonab, Velayat Highway (Iran, Islamic Republic of); Onuki, Y. [Frontier Research Center for Applied Atomic Sciences, Ibaraki University (Japan); Basu, R. [Department of Mechanical Engineering, ITM University, Gurgaon (India); Asghari, A. [Electrical and Computer Engineering Department, University of Texas at San Antonio, Texas (United States); Szpunar, J.A. [Advanced Materials for Clean Energy, Department of Mechanical Engineering, University of Saskatchewan (Canada)

2016-09-30

A newly developed, austenitic lightweight steel, containing a low-density element, Al, exhibits tensile elongation up to 50% as well as high ultimate-tensile stress (tensile fracture at 1800 MPa) without necking behavior. Electron backscatter diffraction analysis is carried out to investigate the orientation dependence of the martensitic transformation in tensile testing to 30% strain at 323 K (25 °C). A pronounced γ→ε→α′ transformation is observed in <111> and <110>∥TD (TD: tensile direction) γ-grains. The α′-transformation textures is analyzed. Large misorientation spreads is seen in the <100>∥TD γ-grains. Interestingly, twin-assisted martensitic transformation is detected in the <111>∥TD followed by the twin boundary directly moving to a γ/α′ phase boundary. These phenomena are related to a change of Schmid factor for different orientations of grains.

Effects of magnetic pre-alignment of nano-powders on formation of high textured barium hexa-ferrite quasi-single crystals via a magnetic forming and liquid participation sintering route

International Nuclear Information System (INIS)

Liu, Junliang; Zeng, Yanwei; Zhang, Xingkai; Zhang, Ming

2015-01-01

Highly textured barium hexa-ferrite quasi-single crystal with narrow ferromagnetic resonance line-width is believed to be a potential gyromagnetic material for self-biased microwave devices. To fabricate barium hexa-ferrite quasi-single crystal with a high grain orientation degree, a magnetic forming and liquid participation sintering route has been developed. In this paper, the effects of the pre-alignment of the starting nano-powders on the formation of barium quasi-single crystal structures have been investigated. The results indicated that: the crystallites with large sizes and small specific surfaces were easily aligned for they got higher driving forces and lower resistances during magnetic forming. The average restricting magnetic field was about 4.647 kOe to overcome the average friction barrier between crystallites. The pre-aligned crystallites in magnetic forming acted as the “crystal seeds” for oriented growth of the un-aligned crystallites during liquid participation sintering to achieve a high grain orientation. To effectively promote the grain orientation degrees of the sintered pellets, the grain orientation degrees of the green compacts must be higher than a limited value of 15.0%. Barium hexa-ferrite quasi-single crystal with a high grain orientation degree of 98.6% was successfully fabricated after sintering the green compact with its grain orientation degree of 51.1%. - Highlights: • Aligned particles acted as “crystal seeds” for un-aligned ones' oriented growth. • Magnetic field of 4.647 kOe was needed to overcome crystallites' friction barrier. • GOD dramatically increased after sintering if starting GOD exceeded to 15.0%. • Quasi-single crystal was prepared by sintering green compact with GOD of 51.1%

Effects of magnetic pre-alignment of nano-powders on formation of high textured barium hexa-ferrite quasi-single crystals via a magnetic forming and liquid participation sintering route

Energy Technology Data Exchange (ETDEWEB)

Liu, Junliang, E-mail: liujunliang@yzu.edu.cn [Key Laboratory of Environmental Materials and Engineering of Jiangsu Province, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002 (China); Zeng, Yanwei [State Key Laboratory of Materials-Oriented Chemical Engineering, School of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009 (China); Zhang, Xingkai [Key Laboratory of Environmental Materials and Engineering of Jiangsu Province, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002 (China); Zhang, Ming [Key Laboratory of Environmental Materials and Engineering of Jiangsu Province, School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002 (China); Testing Center of Yangzhou University, Yangzhou 225002 (China)

2015-05-15

Highly textured barium hexa-ferrite quasi-single crystal with narrow ferromagnetic resonance line-width is believed to be a potential gyromagnetic material for self-biased microwave devices. To fabricate barium hexa-ferrite quasi-single crystal with a high grain orientation degree, a magnetic forming and liquid participation sintering route has been developed. In this paper, the effects of the pre-alignment of the starting nano-powders on the formation of barium quasi-single crystal structures have been investigated. The results indicated that: the crystallites with large sizes and small specific surfaces were easily aligned for they got higher driving forces and lower resistances during magnetic forming. The average restricting magnetic field was about 4.647 kOe to overcome the average friction barrier between crystallites. The pre-aligned crystallites in magnetic forming acted as the “crystal seeds” for oriented growth of the un-aligned crystallites during liquid participation sintering to achieve a high grain orientation. To effectively promote the grain orientation degrees of the sintered pellets, the grain orientation degrees of the green compacts must be higher than a limited value of 15.0%. Barium hexa-ferrite quasi-single crystal with a high grain orientation degree of 98.6% was successfully fabricated after sintering the green compact with its grain orientation degree of 51.1%. - Highlights: • Aligned particles acted as “crystal seeds” for un-aligned ones' oriented growth. • Magnetic field of 4.647 kOe was needed to overcome crystallites' friction barrier. • GOD dramatically increased after sintering if starting GOD exceeded to 15.0%. • Quasi-single crystal was prepared by sintering green compact with GOD of 51.1%.

Strong exciton-photon coupling in organic single crystal microcavity with high molecular orientation

Energy Technology Data Exchange (ETDEWEB)

Goto, Kaname [Department of Electronics, Graduate School of Science and Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan); Yamashita, Kenichi, E-mail: yamasita@kit.ac.jp [Faculty of Electrical Engineering and Electronics, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan); Yanagi, Hisao [Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma, Nara 630-0192 (Japan); Yamao, Takeshi; Hotta, Shu [Faculty of Materials Science and Technology, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585 (Japan)

2016-08-08

Strong exciton-photon coupling has been observed in a highly oriented organic single crystal microcavity. This microcavity consists of a thiophene/phenylene co-oligomer (TPCO) single crystal laminated on a high-reflection distributed Bragg reflector. In the TPCO crystal, molecular transition dipole was strongly polarized along a certain horizontal directions with respect to the main crystal plane. This dipole polarization causes significantly large anisotropies in the exciton transition and optical constants. Especially the anisotropic exciton transition was found to provide the strong enhancement in the coupling with the cavity mode, which was demonstrated by a Rabi splitting energy as large as ∼100 meV even in the “half-vertical cavity surface emitting lasing” microcavity structure.

Strong exciton-photon coupling in organic single crystal microcavity with high molecular orientation

Science.gov (United States)

Goto, Kaname; Yamashita, Kenichi; Yanagi, Hisao; Yamao, Takeshi; Hotta, Shu

2016-08-01

Strong exciton-photon coupling has been observed in a highly oriented organic single crystal microcavity. This microcavity consists of a thiophene/phenylene co-oligomer (TPCO) single crystal laminated on a high-reflection distributed Bragg reflector. In the TPCO crystal, molecular transition dipole was strongly polarized along a certain horizontal directions with respect to the main crystal plane. This dipole polarization causes significantly large anisotropies in the exciton transition and optical constants. Especially the anisotropic exciton transition was found to provide the strong enhancement in the coupling with the cavity mode, which was demonstrated by a Rabi splitting energy as large as ˜100 meV even in the "half-vertical cavity surface emitting lasing" microcavity structure.

Strong exciton-photon coupling in organic single crystal microcavity with high molecular orientation

International Nuclear Information System (INIS)

Goto, Kaname; Yamashita, Kenichi; Yanagi, Hisao; Yamao, Takeshi; Hotta, Shu

2016-01-01

Strong exciton-photon coupling has been observed in a highly oriented organic single crystal microcavity. This microcavity consists of a thiophene/phenylene co-oligomer (TPCO) single crystal laminated on a high-reflection distributed Bragg reflector. In the TPCO crystal, molecular transition dipole was strongly polarized along a certain horizontal directions with respect to the main crystal plane. This dipole polarization causes significantly large anisotropies in the exciton transition and optical constants. Especially the anisotropic exciton transition was found to provide the strong enhancement in the coupling with the cavity mode, which was demonstrated by a Rabi splitting energy as large as ∼100 meV even in the “half-vertical cavity surface emitting lasing” microcavity structure.

Effect of hot band grain size on development of textures and magnetic properties in 2.0% Si non-oriented electrical steel sheet

Energy Technology Data Exchange (ETDEWEB)

Lee, K.M. [Department of Materials Science and Engineering, Korea University, 5-1, Anam-dong, Sungbuk-Gu, Seoul 136-701 (Korea, Republic of); Huh, M.Y., E-mail: myhuh@korea.ac.kr [Department of Materials Science and Engineering, Korea University, 5-1, Anam-dong, Sungbuk-Gu, Seoul 136-701 (Korea, Republic of); Lee, H.J.; Park, J.T.; Kim, J.S. [Electrical Steel Sheet Research Group, Technical Research Laboratories, POSCO, Goedong-dong, Pohang (Korea, Republic of); Shin, E.J. [Korea Atomic Energy Research Institute, Neutron Science Division, Daejeon 305-353 (Korea, Republic of); Engler, O. [Hydro Aluminium Rolled Products GmbH, Research and Development Bonn, P.O. Box 2468, D-53014 Bonn (Germany)

2015-12-15

The effect of hot band grain size on the development of crystallographic texture and magnetic properties in non-oriented electrical steel sheet was studied. After cold rolling the samples with different initial grain sizes displayed different microstructures and micro-textures but nearly identical macro-textures. The homogeneous recrystallized microstructure and micro-texture in the sample having small grains caused normal continuous grain growth. The quite irregular microstructure and micro-texture in the recrystallized sample with large initial grain size provided a preferential growth of grains in 〈001〉//ND and 〈113〉//ND which were beneficial for developing superior magnetic properties. - Highlights: • We produced hot bands of electrical steel with different grain size but same texture. • Hot band grain size strongly affected cold rolling and subsequent annealing textures. • Homogeneous recrystallized microstructure caused normal continuous grain growth. • Irregular recrystallized microstructure led to selective growth of <001>//ND grains. • Hot band with large grains was beneficial for superior magnetic properties.

Grain size distributions and their effects on auto-acoustic compaction

Science.gov (United States)

Taylor, S.; Brodsky, E. E.

2013-12-01

dependent on the largest grain sizes present in the mixture. Establishing governing rules for how mixtures of grain sizes interact will aid our understanding of how the different fault gouge configurations and size distributions observed in natural systems affect shear behavior and earthquake stability on faults.

Thin grain oriented electrical steel for PWM voltages fed magnetic cores

Directory of Open Access Journals (Sweden)

Thierry Belgrand

2018-04-01

Full Text Available This paper reports on performances of high permeability grain oriented electrical steel when used in association with power electronic switching devices. Loss measurement results obtained from the Epstein test, using sinusoidal or various PWM voltages in medium frequency range, show that for both studied thicknesses (HGO 0.23mm and HGO 0.18mm, comparing performances at a fixed induction level between the various situations may not be the most convenient method. The effect of magnetic domain refinement has been investigated. After having shown the interest of lowering the thickness, an alternative way of looking at losses is proposed that may help to design the magnetic core when it comes to the matter of reducing size in considering frequency and magnetization levels.

Dating ice shelf edge marine sediments: A new approach using single-grain quartz luminescence

DEFF Research Database (Denmark)

Berger, G.W.; Murray, A.S.; Thomsen, Kristina Jørkov

2010-01-01

the Antarctic Peninsula, sediment-water-interface (“zero-age” analogs), silt-rich short cores were collected in 2001–2003, originally only for fine silt dating tests. Later access to suitable instrumentation also permitted testing the potential of single-grain quartz (SGQ) dating of sand grains from these cores...

TRAJECTORIES AND DISTRIBUTION OF INTERSTELLAR DUST GRAINS IN THE HELIOSPHERE

Energy Technology Data Exchange (ETDEWEB)

Slavin, Jonathan D. [Harvard-Smithsonian Center for Astrophysics, MS 83, 60 Garden Street, Cambridge, MA 02138 (United States); Frisch, Priscilla C. [Department of Astronomy and Astrophysics, University of Chicago, 5460 S. Ellis Avenue, Chicago, IL 60637 (United States); Mueller, Hans-Reinhard [Department of Physics and Astronomy, Dartmouth College, Hanover, NH 03755 (United States); Heerikhuisen, Jacob; Pogorelov, Nikolai V. [Department of Physics and Center for Space Physics and Aeronomic Research, University of Alabama, Huntsville, AL 35899 (United States); Reach, William T. [Universities Space Research Association, MS 211-3, Moffett Field, CA 94035 (United States); Zank, Gary [Department of Physics and Center for Space Plasma and Aeronomic Research, University of Alabama, Huntsville, AL 35805 (United States)

2012-11-20

The solar wind carves a bubble in the surrounding interstellar medium (ISM) known as the heliosphere. Charged interstellar dust grains (ISDG) encountering the heliosphere may be diverted around the heliopause or penetrate it depending on their charge-to-mass ratio. We present new calculations of trajectories of ISDG in the heliosphere, and the dust density distributions that result. We include up-to-date grain charging calculations using a realistic UV radiation field and full three-dimensional magnetohydrodynamic fluid + kinetic models for the heliosphere. Models with two different (constant) polarities for the solar wind magnetic field (SWMF) are used, with the grain trajectory calculations done separately for each polarity. Small grains a {sub gr} {approx}< 0.01 {mu}m are completely excluded from the inner heliosphere. Large grains, a {sub gr} {approx}> 1.0 {mu}m, pass into the inner solar system and are concentrated near the Sun by its gravity. Trajectories of intermediate size grains depend strongly on the SWMF polarity. When the field has magnetic north pointing to ecliptic north, the field de-focuses the grains resulting in low densities in the inner heliosphere, while for the opposite polarity the dust is focused near the Sun. The ISDG density outside the heliosphere inferred from applying the model results to in situ dust measurements is inconsistent with local ISM depletion data for both SWMF polarities but is bracketed by them. This result points to the need to include the time variation in the SWMF polarity during grain propagation. Our results provide valuable insights for interpretation of the in situ dust observations from Ulysses.

Multi-scale simulation of single crystal hollow turbine blade manufactured by liquid metal cooling process

Directory of Open Access Journals (Sweden)

Xuewei Yan

2018-02-01

Full Text Available Liquid metal cooling (LMC process as a powerful directional solidification (DS technique is prospectively used to manufacture single crystal (SC turbine blades. An understanding of the temperature distribution and microstructure evolution in LMC process is required in order to improve the properties of the blades. For this reason, a multi-scale model coupling with the temperature field, grain growth and solute diffusion was established. The temperature distribution and mushy zone evolution of the hollow blade was simulated and discussed. According to the simulation results, the mushy zone might be convex and ahead of the ceramic beads at a lower withdrawal rate, while it will be concave and laggard at a higher withdrawal rate, and a uniform and horizontal mushy zone will be formed at a medium withdrawal rate. Grain growth of the blade at different withdrawal rates was also investigated. Single crystal structures were all selected out at three different withdrawal rates. Moreover, mis-orientation of the grains at 8 mm/min reached ~30°, while it was ~5° and ~15° at 10 mm/min and 12 mm/min, respectively. The model for predicting dendritic morphology was verified by corresponding experiment. Large scale for 2D dendritic distribution in the whole sections was investigated by experiment and simulation, and they presented a well agreement with each other. Keywords: Hollow blade, Single crystal, Multi-scale simulation, Liquid metal cooling

Effects of artificial holes in very large single-grain Y{sub 1.5}Ba{sub 2}Cu{sub 3}O{sub 7-y} bulk superconductors

Energy Technology Data Exchange (ETDEWEB)

Park, S. D.; Jun, B. H.; Kim, C. J. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Park, H. W. [Korea University of Technology and Education, Cheonan (Korea, Republic of)

2017-09-15

The effects of artificial holes on the trapped magnetic fields and magnetic levitation forces of very large single-grain Y{sub 1.5}Ba{sub 2}Cu{sub 3}O{sub 7-y} (Y1.5) bulk superconductors were studied. Artificial holes were made for Y1.5 powder compacts by die pressing using cylindrical dies with a diameter of 30 mm or 40 m, or rectangular dies with a side length of 50 mm. The single grain Y1.5 bulk superconductors (25 mm, 33 mm in diameter and 42 mm in side length) with artificial holes were fabricated using a top-seeded melt growth (TSMG) process for the die-pressed Y1.5 powder compacts. The magnetic levitation forces at 77 K of the 25 mm single grain Y1.5 samples with one (diameters of 4.2 mm) or six artificial holes (diameters of 2.5 mm) were 10-17% higher than that of the Y1.5 sample without artificial holes. The trapped magnetic fields at 77 K of the Y1.5 samples with artificial holes were also 9.6-18% higher than that of the Y1.5 sample without artificial holes. The 33 mm and 42 mm single grain Y1.5 samples with artificial holes (2.5 mm and 4.2 mm in diameter) also showed trapped magnetic fields 10-13% higher than that of the Y1.5 samples without artificial holes in spite of the reduced superconducting volume fraction due to the presence of artificial holes. The property enhancement in the large single grain Y1.5 bulk superconductors appears to be attributed to the formation of the pore-free regions near the artificial holes and the homogeneous oxygen distribution in the large Y123 grains.

Grain Interactions in Crystal Plasticity

International Nuclear Information System (INIS)

Boyle, K.P.; Curtin, W.A.

2005-01-01

The plastic response of a sheet metal is governed by the collective response of the underlying grains. Intragranular plasticity depends on intrinsic variables such as crystallographic orientation and on extrinsic variables such as grain interactions; however, the role of the latter is not well understood. A finite element crystal plasticity formulation is used to investigate the importance of grain interactions on intragranular plastic deformation in initially untextured polycrystalline aggregates. A statistical analysis reveals that grain interactions are of equal (or more) importance for determining the average intragranular deviations from the applied strain as compared to the orientation of the grain itself. Furthermore, the influence of the surrounding grains is found to extend past nearest neighbor interactions. It is concluded that the stochastic nature of the mesoscale environment must be considered for a proper understanding of the plastic response of sheet metals at the grain-scale

Testing single-grain quartz OSL methods using sediment samples with independent age control from the Bordes-Fitte rockshelter (Roches d'Abilly site, Central France)

DEFF Research Database (Denmark)

Thomsen, Kristina Jørkov; Murray, Andrew Sean; Buylaert, Jan-Pieter

2016-01-01

We present quartz single-grain dose distributions for four well-bleached and unmixed sediment samples with independent age control (22–48 ka), from the archaeologically important Bordes-Fitte rockshelter at Roches d'Abilly, France. This site has previously been dated using 14C AMS dating and stan...

TRAJECTORIES AND DISTRIBUTION OF INTERSTELLAR DUST GRAINS IN THE HELIOSPHERE

International Nuclear Information System (INIS)

Slavin, Jonathan D.; Frisch, Priscilla C.; Müller, Hans-Reinhard; Heerikhuisen, Jacob; Pogorelov, Nikolai V.; Reach, William T.; Zank, Gary

2012-01-01

The solar wind carves a bubble in the surrounding interstellar medium (ISM) known as the heliosphere. Charged interstellar dust grains (ISDG) encountering the heliosphere may be diverted around the heliopause or penetrate it depending on their charge-to-mass ratio. We present new calculations of trajectories of ISDG in the heliosphere, and the dust density distributions that result. We include up-to-date grain charging calculations using a realistic UV radiation field and full three-dimensional magnetohydrodynamic fluid + kinetic models for the heliosphere. Models with two different (constant) polarities for the solar wind magnetic field (SWMF) are used, with the grain trajectory calculations done separately for each polarity. Small grains a gr ∼ gr ∼> 1.0 μm, pass into the inner solar system and are concentrated near the Sun by its gravity. Trajectories of intermediate size grains depend strongly on the SWMF polarity. When the field has magnetic north pointing to ecliptic north, the field de-focuses the grains resulting in low densities in the inner heliosphere, while for the opposite polarity the dust is focused near the Sun. The ISDG density outside the heliosphere inferred from applying the model results to in situ dust measurements is inconsistent with local ISM depletion data for both SWMF polarities but is bracketed by them. This result points to the need to include the time variation in the SWMF polarity during grain propagation. Our results provide valuable insights for interpretation of the in situ dust observations from Ulysses.

Elaboration of austenitic stainless steel samples with bimodal grain size distributions and investigation of their mechanical behavior

Science.gov (United States)

Flipon, B.; de la Cruz, L. Garcia; Hug, E.; Keller, C.; Barbe, F.

2017-10-01

Samples of 316L austenitic stainless steel with bimodal grain size distributions are elaborated using two distinct routes. The first one is based on powder metallurgy using spark plasma sintering of two powders with different particle sizes. The second route applies the reverse-annealing method: it consists in inducing martensitic phase transformation by plastic strain and further annealing in order to obtain two austenitic grain populations with different sizes. Microstructural analy ses reveal that both methods are suitable to generate significative grain size contrast and to control this contrast according to the elaboration conditions. Mechanical properties under tension are then characterized for different grain size distributions. Crystal plasticity finite element modelling is further applied in a configuration of bimodal distribution to analyse the role played by coarse grains within a matrix of fine grains, considering not only their volume fraction but also their spatial arrangement.

Influence of grain orientation on evolution of surface features in fatigued polycrystalline copper: A comparison of thermal and uniaxial mechanical fatigue results

International Nuclear Information System (INIS)

Aicheler, Markus

2010-01-01

Surface state plays a major role in the crack nucleation process of pure metals in the High-Cycle-Fatigue (HCF) as well as in the Ultra-High-Cycle-Fatigue (UHCF) regime. Therefore, in studies dealing with HCF or UHCF, special attention is paid to the evolution of surface degradation during fatigue life. The accelerating structures of the future Compact Linear Collider (CLIC) under study at CERN will be submitted to a high number of thermal-mechanical fatigue cycles, arising from Radio Frequency (RF) induced eddy currents, causing local superficial cyclic heating. The number of cycles during the foreseen lifetime of CLIC reaches 2x10 11 . Fatigue may limit the lifetime of CLIC structures. In order to assess the effects of superficial fatigue, specific tests are defined and performed on polycrystalline Oxygen Free Electronic (OFE) grade Copper, a candidate material for the structures. Surface degradation depends on the orientation of near-surface grains. Copper samples thermally fatigued in two different fatigue experiments, pulsed laser and pulsed RF-heating, underwent postmortem Electron Backscattered Diffraction measurements. Samples fatigued by pulsed laser show the same trend in the orientation-fatigue damage behavior as samples fatigued by pulsed RF-heating. It is clearly observed that surface grains, oriented [1 1 1] with respect to the surface, show significantly more damage than surface grains oriented [1 0 0]. Results arising from a third fatigue experiment, the ultrasound (US) swinger, are compared to the results of the mentioned experiments. The US swinger is an uniaxial mechanical fatigue test enabling to apply within several days a total number of cycles representative of the life of the CLIC structures, thanks to a high repetition rate of 24 kHz. For comparison, laser fatigue experiments have much lower repetition rates. The dependence of surface degradation on grain orientation of samples tested by the US swinger was monitored during the fatigue life

Orientation sensors by defocused imaging of single gold nano-bipyramids

Science.gov (United States)

Zhang, Fanwei; Li, Qiang; Rao, Wenye; Hu, Hongjin; Gao, Ye; Wu, Lijun

2018-01-01

Optical probes for nanoscale orientation sensing have attracted much attention in the field of single-molecule detections. Noble metal especially Au nanoparticles (NPs) exhibit extraordinary plasmonic properties, great photostability, excellent biocompatibility and nontoxicity, and thereby could be alternative labels to conventional applied organic dyes or quantum dots. One type of the most interesting metallic NPs is Au nanorods (AuNRs). Its anisotropic emission accompanied with anisotropic shape is potentially applicable in orientation sensing. Recently, we resolved the 3D orientation of single AuNRs within one frame by deliberately introducing an aberration (slight shift of the dipole away from the focal plane) to the imaging system1 . This defocused imaging technique is based on the electron transition dipole approximation and the fact that the dipole radiation exhibits an angular anisotropy. Since the photoluminescence quantum yield (PLQY) can be enhanced by the "lightning rod effect" (at a sharp angled surface) and localized SPR modes, that of the single Au nano-bipyramid (AuNB) with more sharp tips or edges was found to be doubled comparing to AuNRs with a same effective size2. Here, with a 532 nm excitation, we find that the PL properties of individual AuNBs can be described by three perpendicularly-arranged dipoles (with different ratios). Their PL defocused images are bright, clear and exhibit obvious anisotropy. These properties suggest that AuNBs are excellent candidates for orientation sensing labels in single molecule detections.

300% Enhancement of Carrier Mobility in Uniaxial-Oriented Perovskite Films Formed by Topotactic-Oriented Attachment.

Science.gov (United States)

Kim, Dong Hoe; Park, Jaehong; Li, Zhen; Yang, Mengjin; Park, Ji-Sang; Park, Ik Jae; Kim, Jin Young; Berry, Joseph J; Rumbles, Garry; Zhu, Kai

2017-06-01

Organic-inorganic perovskites with intriguing optical and electrical properties have attracted significant research interests due to their excellent performance in optoelectronic devices. Recent efforts on preparing uniform and large-grain polycrystalline perovskite films have led to enhanced carrier lifetime up to several microseconds. However, the mobility and trap densities of polycrystalline perovskite films are still significantly behind their single-crystal counterparts. Here, a facile topotactic-oriented attachment (TOA) process to grow highly oriented perovskite films, featuring strong uniaxial-crystallographic texture, micrometer-grain morphology, high crystallinity, low trap density (≈4 × 10 14 cm -3 ), and unprecedented 9 GHz charge-carrier mobility (71 cm 2 V -1 s -1 ), is demonstrated. TOA-perovskite-based n-i-p planar solar cells show minimal discrepancies between stabilized efficiency (19.0%) and reverse-scan efficiency (19.7%). The TOA process is also applicable for growing other state-of-the-art perovskite alloys, including triple-cation and mixed-halide perovskites. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Autonomy-oriented mechanisms for efficient energy distribution

Energy Technology Data Exchange (ETDEWEB)

Liu, Jiming; Shi, Benyun

2010-09-15

Due to the uneven geographical availability of energy resources, it is essential for the energy suppliers and consumers in different countries/regions to most efficiently, economically, as well as reliably distribute energy resources. In this paper, starting from a specific energy distribution problem, we present a decentralized behavior-based paradigm that draws on the methodology of autonomy-oriented computing. The goal is twofold: (i) to characterize the underlying mechanism of the energy distribution systems, (ii) to provide scalable solutions for efficient energy distribution. We conjecture that efficient energy trading markets can emerge from appropriate behavior-based mechanisms, which can autonomously improve energy distribution efficiency.

Grain breakage under uniaxial compression, through 3D DEM modelling

Directory of Open Access Journals (Sweden)

Nader François

2017-01-01

Full Text Available A breakable grain model is presented, using the concept of particles assembly. Grains of polyhedral shapes are generated, formed by joining together tetrahedral subgrains using cohesive bonds. Single grain crushing simulations are performed for multiple values of the intra-granular cohesion to study the effect on the grain’s strength. The same effect of intra-granular cohesion is studied under oedometric compression on samples of around 800 grains, which allows the evaluation of grain breakage model on the macroscopic behaviour. Grain size distribution curves and grain breakage ratios are monitored throughout the simulations.

Influence of specimen size and grain orientation to the life of a polycrystalline Ni-base alloy at LCF stress

International Nuclear Information System (INIS)

Seibel, Thomas

2014-01-01

In the present work the LCF (Low Cycle Fatigue) crack initiation life of the conventionally cast Ni-base alloy RENE 80 was analyzed as a function of specimen size and grain orientation. Five specimen geometries with distinctly different gauge sections were used: 3 geometries with cylindrical gauge section (G1-G3) and two notched geometries with a stress concentration factor of α 1 = 1,62 (KG1) and α 2 = 2,60 (KG2), resulting in a maximum difference of the damage relevant surface area up to a factor of approximately 72. Correction factors were determined by FEM calculations for all specimen geometries with highly reduced gauge sections where direct strain measurement was not possible. Additionally a uniform failure criterion with a relatively small crack size of 0,962 mm 2 was defined. Totally, 116 isothermal LCF tests were carried out at the different specimen types at a temperature of 850 C in total strain control with a load ratio (minimum strain / maximum strain) of R ε = -1. The load cycles were applied with triangular waveform at a frequency of 0.1 Hz for high strain amplitudes and 1 Hz for low strain amplitudes, respectively. After the LCF-Tests the fracture surfaces of all samples were analyzed in more detail by SEM to identify the crack initiation mechanisms as well as the crack initiation sites. In this context it could be shown, that fatigue cracks were generally initiated at slip bands in surface grains. Accordingly, the grain orientations at the crack initiation sites were measured by electron back scatter diffraction (EBSD) and the maximum shear stresses in the respective principal slip system (111) <110> was calculated using the Schmid approach. For this, longitudinal sections were be prepared exactly at the crack initiation sites of samples loaded with low strain amplitudes where clearly defined single crack initiation sites were observed. Afterwards the maximum shear stress in the principal slip system at the crack initiation site was correlated

Object oriented distributed programming: studies and proposals

International Nuclear Information System (INIS)

Guerraoui, Rachid

1992-01-01

This thesis contributes to the investigation of the object concept in distributed programming. Henceforth, this programming style has become a reality in the computer science world, since it allows to increase of the availability of applications and to decrease their execution time. Nevertheless, designing a distributed application is a hard task: the various abstraction levels that must be considered hinder the software reusability and maintenance, while errors and concurrent accesses are often sources of executions incoherence. The object concept improves the software modularity, and raises the computing abstraction level. Integrating distribution related aspects into the object model brings up the issues of expressing the concurrency and maintaining the coherency. The investigation of these problems in this thesis has been guided by a major concern for the preservation of the intrinsic properties of object-orientation, and the orthogonality of the solutions given. The main contributions of the thesis are: (i) the classification, regarding modularity, of the different design alternatives for object-oriented concurrent languages; (ii) the evaluation of various transactional mechanisms in object-based concurrent languages, and the design of an atomic asynchronous communication protocol named ACS; (iii) the definition of a transaction-based object-oriented concurrent language called KAROS; (iv) the implementation of a modular framework which allows to combine in a same application, various concurrency control and error recovery mechanisms; (v) the identification of a formal property, named general atomicity, which constitutes a correctness criteria for atomic objects specifications. (author) [fr

Dual-modality single particle orientation and rotational tracking of intracellular transport of nanocargos.

Science.gov (United States)

Sun, Wei; Gu, Yan; Wang, Gufeng; Fang, Ning

2012-01-17

The single particle orientation and rotational tracking (SPORT) technique was introduced recently to follow the rotational motion of plasmonic gold nanorod under a differential interference contrast (DIC) microscope. In biological studies, however, cellular activities usually involve a multiplicity of molecules; thus, tracking the motion of a single molecule/object is insufficient. Fluorescence-based techniques have long been used to follow the spatial and temporal distributions of biomolecules of interest thanks to the availability of multiplexing fluorescent probes. To know the type and number of molecules and the timing of their involvement in a biological process under investigation by SPORT, we constructed a dual-modality DIC/fluorescence microscope to simultaneously image fluorescently tagged biomolecules and plasmonic nanoprobes in living cells. With the dual-modality SPORT technique, the microtubule-based intracellular transport can be unambiguously identified while the dynamic orientation of nanometer-sized cargos can be monitored at video rate. Furthermore, the active transport on the microtubule can be easily separated from the diffusion before the nanocargo docks on the microtubule or after it undocks from the microtubule. The potential of dual-modality SPORT is demonstrated for shedding new light on unresolved questions in intracellular transport.

Precipitation and Evolution Behavior of Second Phase Particles in Grain-oriented Silicon Steel with Cu

Directory of Open Access Journals (Sweden)

LI Zhi-chao

2017-12-01

Full Text Available The precipitation behavior and distribution of second phase particles in conventional grain-oriented silicon steel during manufacturing process were observed by field emission scanning electron microscopy, and the average particle size, the areal particle density, and the Zener factor were statistically analyzed. The results show that the samples mainly contain two kinds of precipitates:A class is the (Cu,MnS composite precipitates with the average size of 1μm; B class is the Cu2S precipitates with the size of 10-30nm, the key inhibition effect is produced by Cu2S. Hot rolling leads to a large amount of fine second phase particles precipitation, which has the minimum average particle size and the highest areal density; in the manufacturing process before high temperature annealing, the average particle size is increasing and the areal density is decreasing; in the process of high temperature annealing, with the decrease of volume fraction of precipitates, the inhibition ability exhibits reducing trend,obvious aggregation occurs at 960℃,secondary recrystallization will happen when Zener factor A decreases below the critical value of 0.19nm-1, and the residual particles will not produce valid inhibition effect.

Investigations of the post-IR IRSL protocol applied to single K-feldspar grains from fluvial sediment samples

International Nuclear Information System (INIS)

Nian, Xiaomei; Bailey, Richard M.; Zhou, Liping

2012-01-01

The post-IR IRSL protocol with single K-feldspar grains was applied to three samples taken from a fluvial sedimentary sequence at the archaeological site of the Dali Man, Shaanxi Province, China. K-feldspar coarse grains were extracted for measurement. Approximately 30–40% of the grains were sufficiently bright to measure, and after application of rejection criteria based on signal strength, recuperation, recycling ratio and saturation dose, ∼10–15% of the grains were used for D e calculation. The relationship of signal decay rate and form of D e (t) with the recovery dose were investigated. The dose recovery ratios of the samples after initial bleaching with the four different light sources were within uncertainties of unity. No anomalous fading was observed. The over-dispersion of the recovered dose and D e values were similar, suggesting neither incomplete resetting of the post-IR IRSL signals nor spatially heterogeneous dose rates significantly affected the natural dose estimates. The values of D e obtained with the single K-feldspar grain post-IR IRSL protocol were in the range ∼400–490 Gy. Combining all of the measured single-grain signals for each of the individual samples (into a ‘synthetic single aliquot’) increased the D e estimates to the range ∼700–900 Gy, suggesting that the grains screened-out by the rejection criteria may have the potential to cause palaeodose over-estimation, although this finding requires a more extensive investigation. Thermally transferred signals were found in the single K-feldspar grains post-IR IRSL protocol, and the proportion of thermally transferred signal to test-dose OSL signal (stimulation at 290 °C) from the natural dose was higher than from regenerative doses, and the proportion was grain- and dose-dependent. As such, TT-post-IR IRSL signals at 290 °C have the potential to cause dose underestimation, although this may be reduced by using larger test-dose irradiations. Our study demonstrates

Mechanical stability of individual austenite grains in TRIP steel studied by synchrotron X-ray diffraction during tensile loading

Energy Technology Data Exchange (ETDEWEB)

Blondé, R. [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Materials Innovation Institute, Mekelweg 2, 2628 CD Delft (Netherlands); Jimenez-Melero, E. [Dalton Cumbrian Facility, The University of Manchester, Westlakes Science and Technology Park, Moor Row, Cumbria, CA24 3HA (United Kingdom); Zhao, L. [Materials Innovation Institute, Mekelweg 2, 2628 CD Delft (Netherlands); Department of Materials Science and Engineering, Delft University of Technology, Mekelweg 2, 2628 CD Delft (Netherlands); Wright, J.P. [European Synchrotron Radiation Facility, 6 Rue Jules Horowitz, BP 220, 38043 Grenoble Cedex (France); Brück, E. [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands); Zwaag, S. van der [Novel Aerospace Materials Group, Faculty of Aerospace Engineering, Delft University of Technology, Kluyverweg 1, 2629 HS, Delft (Netherlands); Dijk, N.H. van, E-mail: N.H.vanDijk@tudelft.nl [Fundamental Aspects of Materials and Energy, Faculty of Applied Sciences, Delft University of Technology, Mekelweg 15, 2629 JB Delft (Netherlands)

2014-11-17

The stability of individual metastable austenite grains in low-alloyed TRIP steels has been studied during tensile loading using high-energy X-ray diffraction. The carbon concentration, grain volume and grain orientation with respect to the loading direction was monitored for a large number of individual grains in the bulk microstructure. Most austenite grains transform into martensite in a single transformation step once a critical load is reached. The orientation-dependent stability of austenite grains was found to depend on their Schmid factor with respect to the loading direction. Under the applied tensile stress the average Schmid factor decreased from an initial value of 0.44 to 0.41 at 243 MPa. The present study reveals the complex interplay of microstructural parameters on the mechanical stability of individual austenite grains, where the largest grains with the lowest carbon content tend to transform first. Under the applied tensile stress the average carbon concentration of the austenite grains increased from an initial value of 0.90 to 1.00 wt% C at 243 MPa, while the average grain volume of the austenite grains decreased from an initial value of 19 to 15 µm{sup 3} at 243 MPa.

Friction stir welding of single crystal aluminium

DEFF Research Database (Denmark)

Fonda, Richard Warren; Wert, John A.; Reynolds, A.P.

2007-01-01

Friction stir welds were prepared in different orientations in an aluminium single crystal. The welds were quenched to preserve the microstructure surrounding the tool and then electron backscattered diffraction was used to reveal the generation of grain boundaries and the evolution...... of crystallographic texture around the tool in each weld. The extent of both dynamic recrystallisation and conventional recrystallisation varied considerably as a function of weld orientation. As the base plate begins to interact with the deformation field surrounding the tool, regions of the single crystal rotate...

Calibration of reconstruction parameters in atom probe tomography using a single crystallographic orientation

International Nuclear Information System (INIS)

Suram, Santosh K.; Rajan, Krishna

2013-01-01

The purpose of this work is to develop a methodology to estimate the APT reconstruction parameters when limited crystallographic information is available. Reliable spatial scaling of APT data currently requires identification of multiple crystallographic poles from the field desorption image for estimating the reconstruction parameters. This requirement limits the capacity of accurately reconstructing APT data for certain complex systems, such as highly alloyed systems and nanostructured materials wherein more than one pole is usually not observed within one grain. To overcome this limitation, we develop a quantitative methodology for calibrating the reconstruction parameters in an APT dataset by ensuring accurate inter-planar spacing and optimizing the curvature correction for the atomic planes corresponding to a single crystallographic orientation. We validate our approach on an aluminum dataset and further illustrate its capabilities by computing geometric reconstruction parameters for W and Al–Mg–Sc datasets. - Highlights: ► Quantitative approach is developed to accurately reconstruct APT data. ► Curvature of atomic planes in APT data is used to calibrate the reconstruction. ► APT reconstruction parameters are determined from a single crystallographic axis. ► Quantitative approach is demonstrated on W, Al and Al–Mg–Sc systems. ► Accurate APT reconstruction of complex materials is now possible

Task-oriented control of Single-Master Multi-Slave Manipulator System

International Nuclear Information System (INIS)

Kosuge, Kazuhiro; Ishikawa, Jun; Furuta, Katsuhisa; Hariki, Kazuo; Sakai, Masaru.

1994-01-01

A master-slave manipulator system, in general, consists of a master arm manipulated by a human and a slave arm used for real tasks. Some tasks, such as manipulation of a heavy object, etc., require two or more slave arms operated simultaneously. A Single-Master Multi-Slave Manipulator System consists of a master arm with six degrees of freedom and two or more slave arms, each of which has six or more degrees of freedom. In this system, a master arm controls the task-oriented variables using Virtual Internal Model (VIM) based on the concept of 'Task-Oriented Control'. VIM is a reference model driven by sensory information and used to describe the desired relation between the motion of a master arm and task-oriented variables. The motion of slave arms are controlled based on the task oriented variables generated by VIM and tailors the system to meet specific tasks. A single-master multi-slave manipulator system, having two slave arms, is experimentally developed and illustrates the concept. (author)

Transport current anisotropy in oriented grained bulk YBa2Cu3Ox superconductor

International Nuclear Information System (INIS)

Selvamanickam, V.; Salama, K.

1990-01-01

The anisotropy in transport current density has been studied on bulk YBa 2 Cu 3 O x superconductor. The transport current density measurements were performed on oriented grained YBa 2 Cu 3 O x superconductor with the current aligned at different angles to the a endash b plane. The angular dependence of J c shows a rapid drop when the transport current is misaligned from the a endash b plane at small angles and then a slow decrease at higher angles. An anisotropy ratio of about 25 is observed at 77 K and zero field between the J c along a endash b plane and that perpendicular to the plane

Effect of deformation mode and grain orientation on misorientation development in a body-centered cubic steel

International Nuclear Information System (INIS)

Kang, J.-Y.; Bacroix, B.; Regle, H.; Oh, K.H.; Lee, H.-C.

2007-01-01

Strain-induced misorientation development was studied in an IF steel as a function of strain for two deformation modes, plane strain compression and simple shear. Using electron back-scattered diffraction, orientation maps of 'large' areas were obtained, from which several individual grains associated with the principal texture components could be extracted so that only intragranular misorientations could be estimated for these orientations. It was observed that the increase of the misorientation angle was more prominent in simple shear than in plane strain compression and that the orientation influence was different for each mode. Considering texture evolution as a possible source of misorientation development, the lattice spin tensor was estimated with the Taylor model for the two deformation modes; both reorientation axis and angle were compared with misorientation angle and axis. The striking concordance of both quantities allows us to conclude that there is a direct contribution of texture evolution to misorientation accumulation with strain

Crystal orientation effects on helium ion depth distributions and adatom formation processes in plasma-facing tungsten

International Nuclear Information System (INIS)

Hammond, Karl D.; Wirth, Brian D.

2014-01-01

We present atomistic simulations that show the effect of surface orientation on helium depth distributions and surface feature formation as a result of low-energy helium plasma exposure. We find a pronounced effect of surface orientation on the initial depth of implanted helium ions, as well as a difference in reflection and helium retention across different surface orientations. Our results indicate that single helium interstitials are sufficient to induce the formation of adatom/substitutional helium pairs under certain highly corrugated tungsten surfaces, such as (1 1 1)-orientations, leading to the formation of a relatively concentrated layer of immobile helium immediately below the surface. The energies involved for helium-induced adatom formation on (1 1 1) and (2 1 1) surfaces are exoergic for even a single adatom very close to the surface, while (0 0 1) and (0 1 1) surfaces require two or even three helium atoms in a cluster before a substitutional helium cluster and adatom will form with reasonable probability. This phenomenon results in much higher initial helium retention during helium plasma exposure to (1 1 1) and (2 1 1) tungsten surfaces than is observed for (0 0 1) or (0 1 1) surfaces and is much higher than can be attributed to differences in the initial depth distributions alone. The layer thus formed may serve as nucleation sites for further bubble formation and growth or as a source of material embrittlement or fatigue, which may have implications for the formation of tungsten “fuzz” in plasma-facing divertors for magnetic-confinement nuclear fusion reactors and/or the lifetime of such divertors.

Effects of DC bias on magnetic performance of high grades grain-oriented silicon steels

Energy Technology Data Exchange (ETDEWEB)

Ma, Guang; Cheng, Ling [Global Energy Interconnection Research Institute, State Key Laboratory of Advanced Transmission Technology,Beijing 102211 (China); Lu, Licheng [State Grid Corporation of China, Beijing 100031 (China); Yang, Fuyao; Chen, Xin [Global Energy Interconnection Research Institute, State Key Laboratory of Advanced Transmission Technology,Beijing 102211 (China); Zhu, Chengzhi [State Grid Zhejiang Electric Power Company, Hangzhou 310007 (China)

2017-03-15

When high voltage direct current (HVDC) transmission adopting mono-polar ground return operation mode or unbalanced bipolar operation mode, the invasion of DC current into neutral point of alternating current (AC) transformer will cause core saturation, temperature increasing, and vibration acceleration. Based on the MPG-200D soft magnetic measurement system, the influence of DC bias on magnetic performance of 0.23 mm and 0.27 mm series (P{sub 1.7}=0.70–1.05 W/kg, B{sub 8}>1.89 T) grain-oriented (GO) silicon steels under condition of AC / DC hybrid excitation were systematically realized in this paper. For the high magnetic induction GO steels (core losses are the same), greater thickness can lead to stronger ability of resisting DC bias, and the reasons for it were analyzed. Finally, the magnetostriction and A-weighted magnetostriction velocity level of GO steel under DC biased magnetization were researched. - Highlights: • Magnetic properties of 0.23 mm and 0.27 mm series (P{sub 1.7}=0.70–1.05 W/kg, B{sub 8}>1.89 T) grain-oriented (GO) silicon steels under condition of AC / DC hybrid excitation were systematically analyzed. • Influence of DC biased magnetization on core loss, magnetostriction, and A-weighted magnetostriction velocity level of GO steel were researched. • Greater thickness and relatively lower magnetic induction (B{sub 8}>1.89 T yet) of GO steel can lead to stronger ability of resisting DC bias, and the reasons for it were analyzed.

Effects by the microstructure after hot and cold rolling on the texture and grain size after final annealing of ferritic non-oriented FeSi electrical steel

Science.gov (United States)

Schneider, J.; Stöcker, A.; Franke, A.; Kawalla, R.

2018-04-01

The magnetic properties of fully processed non-oriented FeSi electrical steel are characterized by their magnetization behavior and specific magnetic losses. The magnetic properties are determined by the texture and microstructure. Less gamma fiber intensity and a high intensity of preferable texture components, especially cube fiber texture, are desirable to obtain an excellent magnetizing behavior. Furthermore, large grain sizes are necessary to reach low values of the specific magnetic losses. The fabrication route of the fully processed non-oriented electrical steels comprises a heavy cold rolling of the hot rolled material before final annealing. To fulfill the requirements on large grain size for low loss materials, grain growth, which appears after complete recrystallization, plays an important role. In this paper we will analyze the influence of different microstructures of the hot strip and the resulting microstructure after cold rolling on the appearance of recrystallization and grain growth after final annealing. The evolution of texture reflects the present ongoing softening processes: recovery, recrystallization and finally grain growth at the given annealing conditions. It will be shown that the image of texture at recrystallization is remarkable different from the texture at grain growth. Substantially grain growth is obtained at lower annealing temperatures for an optimum microstructure of the hot rolled material.

Effects by the microstructure after hot and cold rolling on the texture and grain size after final annealing of ferritic non-oriented FeSi electrical steel

Directory of Open Access Journals (Sweden)

J. Schneider

2018-04-01

Full Text Available The magnetic properties of fully processed non-oriented FeSi electrical steel are characterized by their magnetization behavior and specific magnetic losses. The magnetic properties are determined by the texture and microstructure. Less gamma fiber intensity and a high intensity of preferable texture components, especially cube fiber texture, are desirable to obtain an excellent magnetizing behavior. Furthermore, large grain sizes are necessary to reach low values of the specific magnetic losses. The fabrication route of the fully processed non-oriented electrical steels comprises a heavy cold rolling of the hot rolled material before final annealing. To fulfill the requirements on large grain size for low loss materials, grain growth, which appears after complete recrystallization, plays an important role. In this paper we will analyze the influence of different microstructures of the hot strip and the resulting microstructure after cold rolling on the appearance of recrystallization and grain growth after final annealing. The evolution of texture reflects the present ongoing softening processes: recovery, recrystallization and finally grain growth at the given annealing conditions. It will be shown that the image of texture at recrystallization is remarkable different from the texture at grain growth. Substantially grain growth is obtained at lower annealing temperatures for an optimum microstructure of the hot rolled material.

Deformation-induced microstructural evolution at grain scale

DEFF Research Database (Denmark)

Winther, Grethe

During plastic deformation metals develop microstructures which may be analysed on several scales,spanning from crystallographic textures averaged over the entire sample to the scale of individualgrains. Even within individual grains, intragranular phenomena in the form of orientation gradients...... aswell as dislocation patterning by formation of dislocation boundaries occur. Experimental data andassociated data analysis at the grain scale and below will be presented to illustrate our current level ofunderstanding. The basis for the analysis is the crystallographic orientation of the grain as well...... is presented for both fcc and bcc materials inseveral deformation modes, demonstrating a clear grain orientation dependence [Huang & Winther,2007]. This dependence has its origin in a dependence on the slip systems [Winther & Huang, 2007].This further implies that the dislocations in the boundaries come from...

CrAlN coating to enhance the power loss and magnetostriction in grain oriented electrical steel

Directory of Open Access Journals (Sweden)

Vishu Goel

2016-05-01

Full Text Available Grain oriented electrical steels (GOES are coated with aluminium orthophosphate on top of a forsterite (Mg2SiO4 layer to provide stress and insulation resistance to reduce the power loss and magnetostriction. In this work Chromium Aluminium Nitride (CrAlN was coated on GOES samples with electron beam physical vapour deposition and was tested in the single strip and magnetostriction tester to measure the power loss and magnetostriction before and after coating. Power loss was reduced by 2% after coating and 6 % post annealing at 800 °C. For applied compressive stress of 6 MPa, the magnetostrictive strain was zero with the CrAlN coating as compared to 22 and 24 μϵ for fully finished GOES and GOES without phosphate coating. The thickness of the coating was found to be 1.9 ± 0.2 μm estimated with Glow Discharge Optical Emission Spectroscopy (GDOES. The magnetic domain imaging showed domain narrowing after coating. The reduction in power loss and magnetostriction was due to the large residual compressive stress and Young’s modulus (270 GPa of the coating.

CrAlN coating to enhance the power loss and magnetostriction in grain oriented electrical steel

Energy Technology Data Exchange (ETDEWEB)

Goel, Vishu; Anderson, Philip; Hall, Jeremy [Wolfson Centre for Magnetics, Cardiff University, Cardiff- CF243AA (United Kingdom); Robinson, Fiona [Cogent power Ltd., Newport-NP190RB (United Kingdom); Bohm, Siva [Dept. of metallurgical engineering & materials science, IIT Bombay, Mumbai-400076 (India)

2016-05-15

Grain oriented electrical steels (GOES) are coated with aluminium orthophosphate on top of a forsterite (Mg{sub 2}SiO{sub 4}) layer to provide stress and insulation resistance to reduce the power loss and magnetostriction. In this work Chromium Aluminium Nitride (CrAlN) was coated on GOES samples with electron beam physical vapour deposition and was tested in the single strip and magnetostriction tester to measure the power loss and magnetostriction before and after coating. Power loss was reduced by 2% after coating and 6 % post annealing at 800 °C. For applied compressive stress of 6 MPa, the magnetostrictive strain was zero with the CrAlN coating as compared to 22 and 24 μϵ for fully finished GOES and GOES without phosphate coating. The thickness of the coating was found to be 1.9 ± 0.2 μm estimated with Glow Discharge Optical Emission Spectroscopy (GDOES). The magnetic domain imaging showed domain narrowing after coating. The reduction in power loss and magnetostriction was due to the large residual compressive stress and Young’s modulus (270 GPa) of the coating.

Orientation dependence of the thermal fatigue of nickel alloy single crystals

Energy Technology Data Exchange (ETDEWEB)

Dul' nev, R A; Svetlov, I L; Bychkov, N G; Rybina, T V; Sukhanov, N N

1988-11-01

The orientation dependence of the thermal stability and the thermal fatigue fracture characteristics of single crystals of MAR-M200 nickel alloy are investigated experimentally using X-ray diffraction analysis and optical and scanning electron microscopy. It is found that specimens with the 111-line orientation have the highest thermal stability and fatigue strength. Under similar test conditions, the thermal fatigue life of single crystals is shown to be a factor of 1.5-2 higher than that of the directionally solidified and equiaxed alloys. 6 references.

The grain-size distribution of pyroclasts: Primary fragmentation, conduit sorting or abrasion?

Science.gov (United States)

Kueppers, U.; Schauroth, J.; Taddeucci, J.

2013-12-01

Explosive volcanic eruptions expel a mixture of pyroclasts and lithics. Pyroclasts, fragments of the juvenile magma, record the state of the magma at fragmentation in terms of porosity and crystallinity. The grain size distribution of pyroclasts is generally considered to be a direct consequence of the conditions at magma fragmentation that is mainly driven by gas overpressure in bubbles, high shear rates, contact with external water or a combination of these factors. Stress exerted by any of these processes will lead to brittle fragmentation by overcoming the magma's relaxation timescale. As a consequence, most pyroclasts exhibit angular shapes. Upon magma fragmentation, the gas pyroclast mixture is accelerated upwards and eventually ejected from the vent. The total grain size distribution deposited is a function of fragmentation conditions and transport related sorting. Porous pyroclasts are very susceptible to abrasion by particle-particle or particle-conduit wall interaction. Accordingly, pyroclastic fall deposits with angular clasts should proof a low particle abrasion upon contact to other surfaces. In an attempt to constrain the degree of particle interaction during conduit flow, monomodal batches of washed pyroclasts have been accelerated upwards by rapid decompression and subsequently investigated for their grain size distribution. In our set-up, we used a vertical cylindrical tube without surface roughness as conduit. We varied grain size (0.125-0.25; 0.5-1; 1-2 mm), porosity (0; 10; 30 %), gas-particle ratio (10 and 40%), conduit length (10 and 28 cm) and conduit diameter (2.5 and 6 cm). All ejected particles were collected after settling at the base of a 3.3 m high tank and sieved at one sieve size below starting size (half-Φ). Grain size reduction showed a positive correlation with starting grain size, porosity and overpressure at the vent. Although milling in a volcanic conduit may take place, porous pyroclasts are very likely to be a primary product

Grain Oriented Perovskite Layer Structure Ceramics for High-Temperature Piezoelectric Applications

Science.gov (United States)

Fuierer, Paul Anton

The perovskite layer structure (PLS) compounds have the general formula (A^{2+}) _2(B^{5+})_2 O_7, or (A^ {3+})_2(B^{4+ })_2O_7, and crystallize in a very anisotropic layered structure consisting of parallel slabs made up of perovskite units. Several of these compounds possess the highest Curie temperatures (T_{rm c} ) of any known ferroelectrics. Two examples are Sr_2Nb_2O _7 with T_{rm c} of 1342^circC, and La_2Ti_2O _7 with T_{rm c} of 1500^circC. This thesis is an investigation of PLS ceramics and their feasibility as a high temperature transducer material. Piezoelectricity in single crystals has been measured, but the containerless float zone apparatus necessary to grow high quality crystals of these refractory compounds is expensive and limited to a small number of research groups. Previous attempts to pole polycrystalline Sr_2Nb _2O_7 have failed, and to this point piezoelectricity has been absent. The initiative taken in this research was to investigate PLS ceramics by way of composition and processing schemes such that polycrystalline bodies could be electrically poled. The ultimate objective then was to demonstrate piezoelectricity in PLS ceramics, especially at high temperatures. Donor-doping of both La_2Ti _2O_7 and Sr_2Nb_2O _7 was found to increase volume resistivities at elevated temperatures, an important parameter to consider during the poling process. Sr_2Ta _2O_7 (T _{rm c} = -107 ^circC) was used to make solid solution compositions with moderately high Curie temperatures, of about 850^circC, and lower coercive fields. A hot-forging technique was employed to produce ceramics with high density (>99% of theoretical) and high degree of grain orientation (>90%). Texturing was characterized by x-ray diffraction and microscopy. Considerable anisotropy was observed in physical and electrical properties, including thermal expansion, resistivity, dielectric constant, and polarization. The direction perpendicular to the forging axis proved to be the

Effect of grain boundary on the field-effect mobility of microrod single crystal organic transistors.

Science.gov (United States)

Kim, Jaekyun; Kang, Jingu; Cho, Sangho; Yoo, Byungwook; Kim, Yong-Hoon; Park, Sung Kyu

2014-11-01

High-performance microrod single crystal organic transistors based on a p-type 2,7-dioctyl[1]benzothieno[3,2-b][1]benzothiophene (C8-BTBT) semiconductor are fabricated and the effects of grain boundaries on the carrier transport have been investigated. The spin-coating of C8-BTBT and subsequent solvent vapor annealing process enabled the formation of organic single crystals with high aspect ratio in the range of 10 - 20. It was found that the organic field-effect transistors (OFETs) based on these single crystals yield a field-effect mobility and an on/off current ratio of 8.04 cm2/Vs and > 10(5), respectively. However, single crystal OFETs with a kink, in which two single crystals are fused together, exhibited a noticeable drop of field-effect mobility, and we claim that this phenomenon results from the carrier scattering at the grain boundary.

Grain boundary migration

International Nuclear Information System (INIS)

Dimitrov, O.

1975-01-01

Well-established aspects of grain-boundary migration are first briefly reviewed (influences of driving force, temperature, orientation and foreign atoms). Recent developments of the experimental methods and results are then examined, by considering the various driving of resistive forces acting on grain boundaries. Finally, the evolution in the theoretical models of grain-boundary motion is described, on the one hand for ideally pure metals and, on the other hand, in the presence of solute impurity atoms [fr

Microstructure and texture evolution of ultra-thin grain-oriented silicon steel sheet fabricated using strip casting and three-stage cold rolling method

Energy Technology Data Exchange (ETDEWEB)

Song, Hong-Yu; Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn; Wang, Yin-Ping; Wang, Guo-Dong

2017-03-15

A 0.1 mm-thick grain-oriented silicon steel sheet was successfully produced using strip casting and three-stage cold rolling method. The microstructure, texture and inhibitor evolution during the processing was briefly analyzed. It was found that Goss texture was absent in the hot rolled sheet because of the lack of shear deformation. After normalizing, a large number of dispersed MnS precipitates with the size range of 15–90 nm were produced. During first cold rolling, dense shear bands were generated in the deformed ferrite grains, resulting in the intense Goss texture after first intermediate annealing. The microstructure was further refined and homogenized during the subsequent cold rolling and annealing processes. After primary recrystallization annealing, a homogeneous microstructure consisting of fine and equiaxed grains was produced while the associated texture was characterized by a strong γ-fiber texture. Finally, a complete secondary recrystallization microstructure consisting of entirely large Goss grains was produced. The magnetic induction B{sub 8} and iron loss P{sub 10/400} was 1.79 T and 6.9 W/kg, respectively. - Highlights: • Ultra-thin grain-oriented silicon steel was produced by strip casting process. • Microstructure, texture and inhibitor evolution was briefly investigated. • Goss texture was absent in primary recrystallization annealed sheet. • MnS precipitates with a size range of 15–90 nm formed after normalizing. • A complete secondary recrystallization microstructure was produced.

Propensity rules for orientation in singly-charged ion-atom collisions

International Nuclear Information System (INIS)

Nielsen, S.E.; Dubois, A.; Hansen, J.P.

1990-01-01

Orientation effects for electron capture and excitation in singly-charged ion-atom collisions are analysed using the atomic basis impact parameter method with full inclusion of electron translational factors. We find that the orientation preferences previously predicted for excitation in terms of propensity rules may still be observed when capture is present in ion-atom collisions. Furthermore, in spite of intricate behaviour of the direct capture couplings during the collision, we draw some parallel conclusions for the orientation of the capture states. We illustrate these perturbative predictions by close-coupling calculations for H + -Na(3s) collisions where clear propensity for orientation of the H(2p) capture state is demonstrated in impact parameter and velocity dependences. Finally we predict pronounced orientation effects for H(2s) and H(2p) capture in collisions of H + with initially oriented Na(3p) states. (author)

A method to calculate flux distribution in reactor systems containing materials with grain structure

International Nuclear Information System (INIS)

Stepanek, J.

1980-01-01

A method is proposed to compute the neutron flux spatial distribution in slab, spherical or cylindrical systems containing zones with close grain structure of material. Several different types of equally distributed particles embedded in the matrix material are allowed in one or more zones. The multi-energy group structure of the flux is considered. The collision probability method is used to compute the fluxes in the grains and in an ''effective'' part of the matrix material. Then the overall structure of the flux distribution in the zones with homogenized materials is determined using the DPN ''surface flux'' method. Both computations are connected using the balance equation during the outer iterations. The proposed method is written in the code SURCU-DH. Two testcases are computed and discussed. One testcase is the computation of the eigenvalue in simplified slab geometry of an LWR container of one zone with boral grains equally distributed in an aluminium matrix. The second is the computation of the eigenvalue in spherical geometry of the HTR pebble-bed cell with spherical particles embedded in a graphite matrix. The results are compared to those obtained by repeated use of the WIMS Code. (author)

In Situ Sampling of Relative Dust Devil Particle Loads and Their Vertical Grain Size Distributions.

Science.gov (United States)

Raack, Jan; Reiss, Dennis; Balme, Matthew R; Taj-Eddine, Kamal; Ori, Gian Gabriele

2017-04-19

During a field campaign in the Sahara Desert in southern Morocco, spring 2012, we sampled the vertical grain size distribution of two active dust devils that exhibited different dimensions and intensities. With these in situ samples of grains in the vortices, it was possible to derive detailed vertical grain size distributions and measurements of the lifted relative particle load. Measurements of the two dust devils show that the majority of all lifted particles were only lifted within the first meter (∼46.5% and ∼61% of all particles; ∼76.5 wt % and ∼89 wt % of the relative particle load). Furthermore, ∼69% and ∼82% of all lifted sand grains occurred in the first meter of the dust devils, indicating the occurrence of "sand skirts." Both sampled dust devils were relatively small (∼15 m and ∼4-5 m in diameter) compared to dust devils in surrounding regions; nevertheless, measurements show that ∼58.5% to 73.5% of all lifted particles were small enough to go into suspension (grain size classification). This relatively high amount represents only ∼0.05 to 0.15 wt % of the lifted particle load. Larger dust devils probably entrain larger amounts of fine-grained material into the atmosphere, which can have an influence on the climate. Furthermore, our results indicate that the composition of the surface, on which the dust devils evolved, also had an influence on the particle load composition of the dust devil vortices. The internal particle load structure of both sampled dust devils was comparable related to their vertical grain size distribution and relative particle load, although both dust devils differed in their dimensions and intensities. A general trend of decreasing grain sizes with height was also detected. Key Words: Mars-Dust devils-Planetary science-Desert soils-Atmosphere-Grain sizes. Astrobiology 17, xxx-xxx.

[Characteristics and its forming mechanism on grain size distribution of suspended matter at Changjiang Estuary].

Science.gov (United States)

Pang, Chong-guang; Yu, Wei; Yang, Yang

2010-03-01

In July of 2008, under the natural condition of sea water, the Laser in-situ scattering and transmissometry (LISST-100X Type C) was used to measure grain size distribution spectrum and volume concentration of total suspended matter in the sea water, including flocs at different layers of 24 sampling stations at Changjiang Estuary and its adjacent sea. The characteristics and its forming mechanism on grain size distribution of total suspended matter were analyzed based on the observation data of LISST-100X Type C, and combining with the temperature, salinity and turbidity of sea water, simultaneously observed by Alec AAQ1183. The observation data showed that the average median grain size of total suspended matter was about 4.69 phi in the whole measured sea area, and the characteristics of grain size distribution was relatively poor sorted, wide kurtosis, and basically symmetrical. The conclusion could be drawn that vertically average volume concentration decreased with the distance from the coastline, while median grain size had an increase trend with the distance, for example, at 31.0 degrees N section, the depth-average median grain size had been increased from 11 microm up to 60 microm. With the increasing of distance from the coast, the concentration of fine suspended sediment reduced distinctly, nevertheless some relatively big organic matter or big flocs appeared in quantity, so its grain size would rise. The observation data indicated that the effective density was ranged from 246 kg/m3 to 1334 kg/m, with average was 613 kg/m3. When the concentration of total suspended matter was relatively high, median grain size of total suspended matter increased with the water depth, while effective density decreased with the depth, because of the faster settling velocity and less effective density of large flocs that of small flocs. As for station 37 and 44, their correlation coefficients between effective density and median grain size were larger than 0.9.

Model for phonon transmission through a NbN grain-size distribution: Comparison with tunneling-spectroscopy observations

International Nuclear Information System (INIS)

Chicault, R.; Joly, Y.

1990-01-01

Transport properties of phonons in granular NbN thin film with left-angle 111 right-angle texture are discussed. We propose a model in which each grain has an acoustic resonance when phonons propagate parallel to the film and where a coupling through the amorphous boundaries exists. A statistical study shows that the most homogeneous chains in the grain stack are selected because of the strong efficiency of their transport properties and that they give a fine structure of phonon modes even if the grain-size distribution is quite large. A reasonable agreement is obtained between our tunneling-spectroscopy experiments and the model. A typical experimental result has been fitted using an inelastic phonon-electron-interaction mean free path Λ ph ∼215 nm and a mean grain size d M ∼25.7 nm, the full width at half maximum of the grain distribution being 14 nm

Strength and deformation of shocked diamond single crystals: Orientation dependence

Science.gov (United States)

Lang, J. M.; Winey, J. M.; Gupta, Y. M.

2018-03-01

Understanding and quantifying the strength or elastic limit of diamond single crystals is of considerable scientific and technological importance, and has been a subject of long standing theoretical and experimental interest. To examine the effect of crystalline anisotropy on strength and deformation of shocked diamond single crystals, plate impact experiments were conducted to measure wave profiles at various elastic impact stresses up to ˜120 GPa along [110] and [111] crystal orientations. Using laser interferometry, particle velocity histories and shock velocities in the diamond samples were measured and were compared with similar measurements published previously for shock compression along the [100] direction. Wave profiles for all three orientations showed large elastic wave amplitudes followed by time-dependent inelastic deformation. From the measured wave profiles, the elastic limits were determined under well characterized uniaxial strain loading conditions. The measured elastic wave amplitudes for the [110] and [111] orientations were lower for higher elastic impact stress (stress attained for an elastic diamond response), consistent with the result reported previously for [100] diamond. The maximum resolved shear stress (MRSS) on the {111}⟨110⟩ slip systems was determined for each orientation, revealing significant orientation dependence. The MRSS values for the [100] and [110] orientations (˜33 GPa) are 25%-30% of theoretical estimates; the MRSS value for the [111] orientation is significantly lower (˜23 GPa). Our results demonstrate that the MRSS depends strongly on the stress component normal to the {111} planes or the resolved normal stress (RNS), suggesting that the RNS plays a key role in inhibiting the onset of inelastic deformation. Lower elastic wave amplitudes at higher peak stress and the effect of the RNS are inconsistent with typical dislocation slip mechanisms of inelastic deformation, suggesting instead an inelastic response

The Formation of High-Coercivity, Oriented, Nanophase Cobalt Precipitates in Al2O3 single cyrstals by ion implantation

International Nuclear Information System (INIS)

Honda, S.; Modine, F.A.; Haynes, T.E.; Meldrum, A.; Budai, J.D.; SOng, K.J.; Thompson, J.R.; Boatner, L.A.

1999-01-01

Ion-implantation and thermal-processing methods have been used to form nanophase magnetic precipitates of metallic cobalt that are embedded in the near-surface region of single crystals of Al 2 O 3 . The Co precipitates are isolated, single-crystal particles that are crystallographically oriented with respect to the host Al 2 O 3 lattice. Embedded nanophase Co precipitates were formed by the implantation of Co+ at an energy of 140 keV and a dose of 8 x l0 16 ions/cm 2 followed by annealing in a reducing atmosphere. The implanted/annealed Co depth profile, particle size distributions and shapes, and the orientational relationship between the nanophase precipitates and the host crystal lattice were determined using RBS/channeling, transmission electron microscopy, and x-ray diffraction

The effect of coarse second-phase particles on the rate of grain refinement during severe deformation processing

DEFF Research Database (Denmark)

Apps, P.J.; Bowen, Jacob R.; Prangnell, P.B.

2003-01-01

The effect of second-phase particles on the rate of grain refinement during severe deformation processing has been investigated, by comparing the microstructure evolution in an AA8079 aluminium alloy, containing 2.5 vol.% of ~2 μm particles, with that in a high purity, single-phase, Al-0.13% Mg a...... by an effective strain of only five in the particle-containing alloy, compared to ten in the single-phase material. The mechanisms that contribute to this acceleration of the grain refinement process are discussed.......The effect of second-phase particles on the rate of grain refinement during severe deformation processing has been investigated, by comparing the microstructure evolution in an AA8079 aluminium alloy, containing 2.5 vol.% of ~2 μm particles, with that in a high purity, single-phase, Al-0.13% Mg...... alloy, deformed identically by ECAE to an effective strain of ten. The materials were analysed by high-resolution EBSD orientation mapping, which revealed that grain refinement occurred at a dramatically higher rate in the particle-containing alloy. A submicron grain structure could be achieved...

A visual basic program to generate sediment grain-size statistics and to extrapolate particle distributions

Science.gov (United States)

Poppe, L.J.; Eliason, A.H.; Hastings, M.E.

2004-01-01

Measures that describe and summarize sediment grain-size distributions are important to geologists because of the large amount of information contained in textural data sets. Statistical methods are usually employed to simplify the necessary comparisons among samples and quantify the observed differences. The two statistical methods most commonly used by sedimentologists to describe particle distributions are mathematical moments (Krumbein and Pettijohn, 1938) and inclusive graphics (Folk, 1974). The choice of which of these statistical measures to use is typically governed by the amount of data available (Royse, 1970). If the entire distribution is known, the method of moments may be used; if the next to last accumulated percent is greater than 95, inclusive graphics statistics can be generated. Unfortunately, earlier programs designed to describe sediment grain-size distributions statistically do not run in a Windows environment, do not allow extrapolation of the distribution's tails, or do not generate both moment and graphic statistics (Kane and Hubert, 1963; Collias et al., 1963; Schlee and Webster, 1967; Poppe et al., 2000)1.Owing to analytical limitations, electro-resistance multichannel particle-size analyzers, such as Coulter Counters, commonly truncate the tails of the fine-fraction part of grain-size distributions. These devices do not detect fine clay in the 0.6–0.1 μm range (part of the 11-phi and all of the 12-phi and 13-phi fractions). Although size analyses performed down to 0.6 μm microns are adequate for most freshwater and near shore marine sediments, samples from many deeper water marine environments (e.g. rise and abyssal plain) may contain significant material in the fine clay fraction, and these analyses benefit from extrapolation.The program (GSSTAT) described herein generates statistics to characterize sediment grain-size distributions and can extrapolate the fine-grained end of the particle distribution. It is written in Microsoft

Grain centre mapping - 3DXRD measurements of average grain characteristics

DEFF Research Database (Denmark)

Oddershede, Jette; Schmidt, Søren; Lyckegaard, Allan

2014-01-01

characteristics of each grain (such as their centre-of-mass positions, volumes, phases, orientations and/or elastic strain tensor components), while the exact locations of the grain boundaries are unknown. In the present chapter a detailed description of the setup and software for both grain centre mapping...... and the closely related boxscan method is given. Both validation experiments and applications for in situ studies of microstructural changes during plastic deformation and crack growth are given. Finally an outlook with special emphasis on coupling the measured results with modelling is given....

CREATION OF EXPORT-ORIENTED NETWORK OF GRAIN ELEVATORS IN UKRAINE

Directory of Open Access Journals (Sweden)

D. M. Kozachenko

2017-04-01

Full Text Available Purpose. The scientific paper highlights improving the efficiency of export rail transportation of grain cargoes in Ukraine by introducing shipper routing and concentration of loading at the terminal grain elevators. Methodology. According to the experience of the USA and Canada, one of the most effective ways to reduce costs in the grain to-port supply chain is a shipper routing of the rail traffic. Shipper routing for transportation of grain cargoes involves the concentration of their loading on the multiple junctions. The junctions are proposed to be selected with the use of cluster analysis methods. For the formation of the grain loading concentration areas the authors used methods of set theory and multi-criteria optimization. Findings. Based on agglomerative cluster analysis algorithm, the junctions on a network of Ukrainian railways are selected and the areas of possible concentration of grain loading are formed. DSU-algorithm allowed distinguishing the overlapping and non-overlapping areas of concentration. The problem of selecting non-overlapping areas of the grain loading concentration is formalized as the problem of multiobjective integer programming with boolean variables. The solution of this problem by a modified simplex algorithm allows selecting on the railway network of Ukraine 24 districts of possible grain loading concentration, which cover 70 stations and at minimal additional cost provide routing of about 7.5 million tons of grain per year. Originality. The originality of the work lies in the fact that the authors developed the mathematical procedure for selection of junctions and concentration areas of grain loading at the Ukrainian railway network, taking into account the economic efficiency of the process. Practicalvalue. Application of the developed method of grain loading concentration for the formation of unit trains will significantly reduce the logistics costs in the supply chain of grain to Ukrainian ports for

Formation of oriented nitrides by N+ ion implantation in iron single crystals

International Nuclear Information System (INIS)

Costa, A.R.G.; Silva, R.C. da; Ferreira, L.P.; Carvalho, M.D.; Silva, C.; Franco, N.; Godinho, M.

2014-01-01

Iron single crystals were implanted with nitrogen at room temperature, with a fluence of 5×10 17 cm −2 and 50 keV energy, to produce iron nitride phases and characterize the influence of the crystal orientation. The stability and evolution of the nitride phases and diffusion of implanted nitrogen were studied as a function of successive annealing treatments at 250 °C in vacuum. The composition, structure and magnetic properties were characterized using RBS/channeling, X-Ray Diffraction, Magnetic Force Microscopy, Magneto-optical Kerr Effect and Conversion Electron Mössbauer Spectroscopy. In the as-implanted state the formation of Fe 2 N phase was clearly identified in all single crystals. This phase is not stable at 250 °C and annealing at this temperature promotes the formation of ε-Fe 3 N, or γ′-Fe 4 N, depending on the orientation of the substrate. - Highlights: • Oriented magnetic iron nitrides were obtained by nitrogen implantation into iron single crystals. • The stable magnetic nitride phase at 250 °C depends on the orientation of the host single crystal, being γ'-Fe 4 N or ε-Fe 3 N. • The easy magnetization axis was found to lay in the (100) plane for cubic γ'-Fe 4 N and out of (100) plane for hexagonal ε-Fe 3 N

Transport current anisotropy in oriented grained bulk YBa2Cu3O(x) superconductor

International Nuclear Information System (INIS)

Selvamanickam, V.; Salama, K.

1990-01-01

The anisotropy in transport current density has been studied on bulk YBa2Cu3O(x) superconductor. The transport current density measurements were performed on oriented grained YBa2Cu3O(x) superconductor with the current aligned at different angles to the a-b plane. The angular dependence of Jc shows a rapid drop when the transport current is misaligned from the a-b plane at small angles and then a slow decrease at higher angles. An anisotropy ratio of about 25 is observed at 77 K and zero field between the Jc along a-b plane and that perpendicular to the plane. 15 refs

Movement and Orientation Decision Modeling of Rhyzopertha dominica (Coleoptera: Bostrichidae) in the Grain Mass.

Science.gov (United States)

Cordeiro, Erick M G; Campbell, James F; Phillips, Thomas W

2016-04-01

Grain stored in bins is initially a relatively homogenous resource patch for stored-product insects, but over time, spatial pattern in insect distribution can form, due in part to insect movement patterns. However, the factors that influence stored-product insect movement patterns in grain are not well-understood. This research focused on the movement of the lesser grain borer, Rhyzopertha dominica (F.), within a simulated wheat grain mass (vertical monolayer of wheat) and the identification of factors that contribute to overall and upward movement (age since adult emergence from an infested kernel [1, 7, and 14 d], sex, strain, and different levels of environment quality). We also used the model selection approach to select the most relevant factors and determine the relationships among them. Three-week-old adults tended to stay closer to the surface compared with 1- or 2-wk-old insects. Also, females tended to be more active and to explore a larger area compared with males. Explored area and daily displacement were also significantly strain-dependent, and increasing grain infestation level decreased daily displacement and explored area. Variation in movement pattern is likely to influence the formation of spatial pattern and affect probability to disperse. Understanding movement behavior within a grain bin is crucial to designing better strategies to implement and interpret monitoring programs and to target control tactics. Published by Oxford University Press on behalf of Entomological Society of America 2016. This work is written by US Government employees and is in the public domain in the US.

Behaviors of Deformation, Recrystallization and Textures Evolution of Columnar Grains in 3%Si Electrical Steel Slabs

Directory of Open Access Journals (Sweden)

SHAO Yuan-yuan

2017-11-01

Full Text Available The behaviors of deformation and recrystallization and textures evolution of 3% (mass fraction Si columnar-grained electrical steel slabs were investigated by electron backscatter diffractometer technique and X-ray diffraction. The results indicate that the three columnar-grained samples have different initial textures with the long axes arranged along rolling, transverse and normal directions. Three shear orientations can be obtained in surface layer after hot rolling, of which Goss orientation is formed easily. The α and γ fibre rolling orientations are obtained in RD sample, while strong γ fibre orientations in TD sample and sharp {100} orientations in ND sample are developed respectively. In addition, cube orientation can be found in all the three samples. The characteristics of hot rolled orientations in center region reveal distinct dependence on initial columnar-grained orientations. Strong {111}〈112〉 orientation in RD and TD samples separately comes from Goss orientation of hot rolled sheets, and sharp rotated cube orientation in ND sample originates from the initial {100} orientation of hot rolled sheets after cold rolling. Influenced by initial deviated orientations and coarse grain size, large orientation gradient of rotated cube oriented grain can be observed in ND sample. The coarse {100} orientated grains of center region in the annealed sheets show the heredity of the initial columnar-grained orientations.

Optically stimulated luminescence techniques in retrospective dosimetry using single grains of quartz extracted from unheated materials

DEFF Research Database (Denmark)

Thomsen, Kristina Jørkov

dosimetry). Special attention has been paid to quartz extracted from unheated building materials such as concrete and mortar. The single-aliquot regeneration-dose (SAR) protocol has been used to determine absorbeddoses in small aliquots as well as single grains of quartz. It is shown that OSL measurements...... that the observed variability in the data is consistent with the sum (in quadrature) of a component,which depends on the number of photons detected from each grain, and a fixed component independent of light level. Dose depth profiles through laboratory irradiated concrete bricks have successfully been measured...

Distribution of gluten proteins in bread wheat (Triticum aestivum) grain.

Science.gov (United States)

Tosi, Paola; Gritsch, Cristina Sanchis; He, Jibin; Shewry, Peter R

2011-07-01

Gluten proteins are the major storage protein fraction in the mature wheat grain. They are restricted to the starchy endosperm, which forms white flour on milling, and interact during grain development to form large polymers which form a continuous proteinaceous network when flour is mixed with water to give dough. This network confers viscosity and elasticity to the dough, enabling the production of leavened products. The starchy endosperm is not a homogeneous tissue and quantitative and qualitative gradients exist for the major components: protein, starch and cell wall polysaccharides. Gradients in protein content and composition are the most evident and are of particular interest because of the major role played by the gluten proteins in determining grain processing quality. Protein gradients in the starchy endosperm were investigated using antibodies for specific gluten protein types for immunolocalization in developing grains and for western blot analysis of protein extracts from flour fractions obtained by sequential abrasion (pearling) to prepare tissue layers. Differential patterns of distribution were found for the high-molecular-weight subunits of glutenin (HMW-GS) and γ-gliadins when compared with the low-molecular-weight subunits of glutenin (LMW-GS), ω- and α-gliadins. The first two types of gluten protein are more abundant in the inner endosperm layers and the latter more abundant in the subaleurone. Immunolocalization also showed that segregation of gluten proteins occurs both between and within protein bodies during protein deposition and may still be retained in the mature grain. Quantitative and qualitative gradients in gluten protein composition are established during grain development. These gradients may be due to the origin of subaleurone cells, which unlike other starchy endosperm cells derive from the re-differentiation of aleurone cells, but could also result from the action of specific regulatory signals produced by the maternal tissue

Precession electron diffraction for SiC grain boundary characterization in unirradiated TRISO fuel

International Nuclear Information System (INIS)

Lillo, T.M.; Rooyen, I.J. van; Wu, Y.Q.

2016-01-01

Highlights: • SiC grain orientation determined by TEM-based precession electron diffraction. • Orientation data improved with increasing TEM sample thickness. • Fraction of low angle grain boundaries lower from PED data than EBSD data. • Fractions of high angle and CSL-related boundaries similar to EBSD data. - Abstract: Precession electron diffraction (PED), a transmission electron microscopy-based technique, has been evaluated for the suitability for evaluating grain boundary character in the SiC layer of tristructural isotropic (TRISO) fuel. This work reports the effect of transmission electron microscope (TEM) lamella thickness on the quality of data and establishes a baseline comparison to SiC grain boundary characteristics, in an unirradiated TRISO particle, determined previously using a conventional electron backscatter diffraction (EBSD) scanning electron microscope (SEM)-based technique. In general, it was determined that the lamella thickness produced using the standard focused ion beam (FIB) fabrication process (∼80 nm), is sufficient to provide reliable PED measurements, although thicker lamellae (∼120 nm) were found to produce higher quality orientation data. Also, analysis of SiC grain boundary character from the TEM-based PED data showed a much lower fraction of low-angle grain boundaries compared to SEM-based EBSD data from the SiC layer of a TRISO-coated particle made using the same fabrication parameters and a SiC layer deposited at a slightly lower temperature from a surrogate TRISO particle. However, the fractions of high-angle and coincident site lattice (CSL)-related grain boundaries determined by PED are similar to those found using SEM-based EBSD. Since the grain size of the SiC layer of TRSIO fuel can be as small as 250 nm (Kirchhofer et al., 2013), depending on the fabrication parameters, and since grain boundary fission product precipitates in irradiated TRISO fuel can be nano-sized, the TEM-based PED orientation data

Bimodal grain-size distribution of Chinese loess, and its palaeoclimatic implications

NARCIS (Netherlands)

Sun, D.G.; Bloemendal, J.; Rea, D.K.; An, Z.S.; Vandenberghe, J.; Lu, H.; Su, R.; Liu, T.S.

2004-01-01

Grain-size analysis indicates that Chinese loess generally shows a bimodal distribution with a coarse and a fine component. The coarse component, comprising the main part of the loess, has pronounced kurtosis and is well sorted, which is interpreted to be the product of dust storms generated by

Production and several properties of single crystal austenitic stainless steels

International Nuclear Information System (INIS)

Okamoto, Kazutaka; Yoshinari, Akira; Kaneda, Junya; Aono, Yasuhisa; Kato, Takahiko

1998-01-01

The single crystal austenitic stainless steels Type 316L and 304L were grown in order to improve the resistance to stress corrosion cracking (SCC) using a unidirectional solidification method which can provide the large size single crystals. The mechanical properties and the chemical properties were examined. The orientation and temperature dependence of tensile properties of the single crystals were measured. The yield stress of the single crystal steels are lower than those of the conventional polycrystal steels because of the grain boundary strength cannot be expected in the single crystal steels. The tensile properties of the single crystal austenitic stainless steel Type 316L depend strongly on the orientation. The tensile strength in orientation are about 200 MPa higher than those in the and orientations. The microstructure of the single crystal consists of a mixture of the continuous γ-austenitic single crystal matrix and the δ-ferrite phase so that the effects of the γ/δ boundaries on the chemical properties were studied. The effects of the δ-ferrite phases and the γ/δ boundaries on the resistance to SCC were examined by the creviced bent beam test (CBB test). No crack is observed in all the CBB test specimens of the single crystals, even at the γ/δ boundaries. The behavior of the radiation induced segregation (RIS) at the γ/δ boundaries in the single crystal austenitic stainless steel Type 316L was evaluated by the electron irradiation test in the high voltage electron microscope (HVEM). The depletion of oversized solute chromium at the γ/δ boundary in the single crystal austenitic stainless steel Type 316L is remarkably lower than that at the grain boundary in the polycrystalline-type 316L. (author)

Preferential orientation relationships in Ca2MnO4 Ruddlesden-Popper thin films

International Nuclear Information System (INIS)

Lacotte, M.; David, A.; Prellier, W.; Rohrer, G. S.; Salvador, P. A.

2015-01-01

A high-throughput investigation of local epitaxy (called combinatorial substrate epitaxy) was carried out on Ca 2 MnO 4 Ruddlesden-Popper thin films of six thicknesses (from 20 to 400 nm), all deposited on isostructural polycrystalline Sr 2 TiO 4 substrates. Electron backscatter diffraction revealed grain-over-grain local epitaxial growth for all films, resulting in a single orientation relationship (OR) for each substrate-film grain pair. Two preferred epitaxial ORs accounted for more than 90% of all ORs on 300 different microcrystals, based on analyzing 50 grain pairs for each thickness. The unit cell over unit cell OR ([100][001] film ∥ [100][001] substrate , or OR1) accounted for approximately 30% of each film. The OR that accounted for 60% of each film ([100][001] film ∥ [100][010] substrate , or OR2) corresponds to a rotation from OR1 by 90° about the a-axis. OR2 is strongly favored for substrate orientations in the center of the stereographic triangle, and OR1 is observed for orientations very close to (001) or to those near the edge connecting (100) and (110). While OR1 should be lower in energy, the majority observation of OR2 implies kinetic hindrances decrease the frequency of OR1. Persistent grain over grain growth and the absence of variations of the OR frequencies with thickness implies that the growth competition is finished within the first few nm, and local epitaxy persists thereafter during growth

Inhomogeneity of the grain size of aircraft engine turbine polycrystalline blades

Directory of Open Access Journals (Sweden)

J. Chmiela

2011-10-01

Full Text Available The determination of the behaviour of inhomogeneous materials with a complex microstructure requires taking into account the inhomogeneity of the grain size, as it is the basis for the process of designing and modelling effective behaviours. Therefore, the functional description of the inhomogeneity is becoming an important issue. The paper presents an analytical approach to the grain size inhomogeneity, based on the derivative of a logarithmic-logistic function. The solution applied enabled an effective evaluation of the inhomogeneity of two macrostructures of aircraft engine turbine blades, characterized by a high degree of diversity in the grain size. For the investigated single-modal and bimodal grain size distributions on a perpendicular projection and for grains with a non-planar surface, we identified the parameters that describe the degree of inhomogeneity of the constituents of weight distributions and we also derived a formula describing the overall degree of inhomogeneity of bimodal distributions. The solution presented in the paper is of a general nature and it can be used to describe the degree of inhomogeneity of multi-modal distributions. All the calculations were performed using the Mathematica® package.

The production of grain oriented lanthanum titanate (La2Ti2O7) ceramics by uniaxial hot-forging process for improved fracture toughness

International Nuclear Information System (INIS)

Ceylan, Ali

2008-01-01

The layered-structural ceramics, such as lanthanum titanate (La 2 Ti 2 O 7 ), have been known for their good electrical and optical properties at high frequencies and temperatures. However, few studies have been conducted on the mechanical properties of these ceramics. The interest in ceramic hot-forging (HF) has been greatly increased recently due to the enhancement in fracture toughness via bridging effect of oriented grains. In this study, grain oriented lanthanum titanate was produced by the hot-forging process. The characterizations of the samples were achieved by density measurement, scanning electron microscopy (SEM), optical microscopy, X-ray diffraction (XRD), Vickers indentation and three-point bending test. According to X-ray diffraction patterns, the orientation factor (f) was found to be 0.73 for certain hot-forging conditions resulting an improved fracture toughness. The improved fracture toughness of La 2 Ti 2 O 7 (3.2 MPa m 1/2 ) reached to the value of monolithic alumina (Al 2 O 3 ) between 3 and 4 MPa m 1/2

Inter-grain coupling and grain charge in dusty plasma Coulomb crystals

International Nuclear Information System (INIS)

Smith, M. A.; Goodrich, J.; Mohideen, U.; Rahman, H. U.; Rosenberg, M.; Mendis, D. A.

1998-01-01

We have studied the lattice structure and grain charge of dusty plasma Coulomb crystals formed in rectangular conductive grooves as a function of plasma temperature and density. The crystal appears to be made of mutually repulsive columns of grains confined by the walls of the groove. The columns are oriented along the direction of the electrode sheath electric field. A simple phenomenological model wherein the inter-grain spacing results from an attractive electric field induced dipole-dipole force balanced by a repulsive monopole Coulomb force is consistent with observed features of the Coulomb crystal

Predictive modelling of grain size distributions from marine electromagnetic profiling data using end-member analysis and a radial basis function network

Science.gov (United States)

Baasch, B.; M"uller, H.; von Dobeneck, T.

2018-04-01

In this work we present a new methodology to predict grain-size distributions from geophysical data. Specifically, electric conductivity and magnetic susceptibility of seafloor sediments recovered from electromagnetic profiling data are used to predict grain-size distributions along shelf-wide survey lines. Field data from the NW Iberian shelf are investigated and reveal a strong relation between the electromagnetic properties and grain-size distribution. The here presented workflow combines unsupervised and supervised machine learning techniques. Nonnegative matrix factorisation is used to determine grain-size end-members from sediment surface samples. Four end-members were found which well represent the variety of sediments in the study area. A radial-basis function network modified for prediction of compositional data is then used to estimate the abundances of these end-members from the electromagnetic properties. The end-members together with their predicted abundances are finally back transformed to grain-size distributions. A minimum spatial variation constraint is implemented in the training of the network to avoid overfitting and to respect the spatial distribution of sediment patterns. The predicted models are tested via leave-one-out cross-validation revealing high prediction accuracy with coefficients of determination (R2) between 0.76 and 0.89. The predicted grain-size distributions represent the well-known sediment facies and patterns on the NW Iberian shelf and provide new insights into their distribution, transition and dynamics. This study suggests that electromagnetic benthic profiling in combination with machine learning techniques is a powerful tool to estimate grain-size distribution of marine sediments.

Competitive grain growth in directional solidification investigated by phase field simulation

International Nuclear Information System (INIS)

Li Junjie; Wang Zhijun; Wang Jincheng; Yang Yujuan

2012-01-01

During directional solidification, the competitive dendritic growth between various oriented grains is a key factor to obtain desirable texture. In order to understand the mechanism of competitive dendritic growth, the phase field method was adopted to simulate the microstructure evolution of bicrystal samples. The simulation has well reproduced the whole competitive growth process for both diverging and converging dendrites. In converging case, besides the block of the unfavorably oriented dendrite by the favorably oriented one, the unfavorably oriented dendrite is also able to overgrow the favorable one under the condition of relatively low pulling velocity. This unusual overgrowth is dictated by the solute interaction of the converging dendrite tips. In diverging case, it was found that the grain boundary can be either inclined or parallel to the favorably oriented grain depending on the disposition of two grains.

A revisited Johnson-Mehl-Avrami-Kolmogorov model and the evolution of grain-size distributions in steel

OpenAIRE

Hömberg, D.; Patacchini, F. S.; Sakamoto, K.; Zimmer, J.

2016-01-01

The classical Johnson-Mehl-Avrami-Kolmogorov approach for nucleation and growth models of diffusive phase transitions is revisited and applied to model the growth of ferrite in multiphase steels. For the prediction of mechanical properties of such steels, a deeper knowledge of the grain structure is essential. To this end, a Fokker-Planck evolution law for the volume distribution of ferrite grains is developed and shown to exhibit a log-normally distributed solution. Numerical parameter studi...

Characterization of plastic strains and crystallographic properties surrounding defects in steam generator tubes by orientation imaging microscopy

International Nuclear Information System (INIS)

Lehockey, E.M.; Brennenstuhl, A.M.

2002-01-01

Orientation Imaging Microscopy (OIM) has become a valuable technique for characterizing grain boundary structure, texture, and grain size distribution, which govern material susceptibility to degenerative effects (e.g. IGSCC). Methods recently developed, by Kinectrics, have extended OIM capabilities toward mapping and quantifying residual plastic strains in materials. OIM is applied in the present work to characterize the distribution of plastic strains, that accumulate in CANDU steam generator tubing during installation and service potentially undermining the performance, reliability, and fitness-for-service of these components. Plastic strain that evolves in response to roller-expansion was characterized in simulated roll joints constructed from Alloy 600 tubing. Results underscore the effect of over-rolling in generating intense gradients with broad variations in strain that extend significant distances through the wall thickness. Of greater relevance is the orientation of these gradients in the transverse direction, relative to the tube axis and potential for the development of abnormal grain growth during post-expansion heat treatments. The magnitude and distribution of strain measured by OIM are remarkably consistent with Finite Element Analysis (FEA) predictions offering compelling evidence as to the reliability of the OIM technique. OIM offers superior resolution than can be practically achieved with FEA having particular relevance in identifying highly localized concentrations of strain surrounding metallurgical defects that can serve as precursors to stress-related degenerative effects (e.g. IGSCC). The spatial distribution of residual plastic strain was also characterized within the context of localized texture, and grain size morphology surrounding (OD) 'pits' and indentations found in ex-service Monel 400 and Alloy 800 SG tubes, respectively. An absence of strain surrounding these surface defects suggests their propensity for promoting more deleterious

Analysis on the energetics, magnetism and electronic properties in a 45° ZnO grain boundary doped with Gd

KAUST Repository

Devi, Assa Aravindh Sasikala; Roqan, Iman S.

2018-01-01

The structural stability and magnetic properties of a grain boundary (GB) formed by aligning two ZnO single crystals oriented at an angle of 45° is investigated by density functional theory, using generalized gradient approximation (GGA) and taking

Angular distribution of oriented nucleus fission neutrons

International Nuclear Information System (INIS)

Barabanov, A.L.; Grechukhin, D.P.

1982-01-01

Calculations of anisotropy of angular distribution of oriented 235 U nuclei thermal fission neutrons have been carried out. the neutrons were assumed to evaporate isotropically by completely accelerated fragements in the fragment system with only its small part, i. e. fission-producing neutrons, emitted at the moment of neck break. It has been found out that at low energies of neutrons Esub(n)=1-2 MeV the sensitivity of the angular distribution anisotropy to variations of spectrum of neutron evaporation from fragments and the magnitude of a share of fission-producing neutrons reaches approximately 100%, which at high energies, Esub(n) > 5 MeV it does not exceed approximately 20%. Therefore the angular distribution of fast neutrons to a greater degree of confidence may be used for restoring the angular distribution anisotropy of fragments while the angular distribution of low energy neutrons may be used for deriving information on the fission process, but only in case 6f the experiment accuracy is better than approximately 3%

Establishment of Grain Farmers' Supply Response Model and Empirical Analysis under Minimum Grain Purchase Price Policy

OpenAIRE

Zhang, Shuang

2012-01-01

Based on farmers' supply behavior theory and price expectations theory, this paper establishes grain farmers' supply response model of two major grain varieties (early indica rice and mixed wheat) in the major producing areas, to test whether the minimum grain purchase price policy can have price-oriented effect on grain production and supply in the major producing areas. Empirical analysis shows that the minimum purchase price published annually by the government has significant positive imp...

Optimal configuration of microstructure in ferroelectric materials by stochastic optimization

Science.gov (United States)

Jayachandran, K. P.; Guedes, J. M.; Rodrigues, H. C.

2010-07-01

An optimization procedure determining the ideal configuration at the microstructural level of ferroelectric (FE) materials is applied to maximize piezoelectricity. Piezoelectricity in ceramic FEs differs significantly from that of single crystals because of the presence of crystallites (grains) possessing crystallographic axes aligned imperfectly. The piezoelectric properties of a polycrystalline (ceramic) FE is inextricably related to the grain orientation distribution (texture). The set of combination of variables, known as solution space, which dictates the texture of a ceramic is unlimited and hence the choice of the optimal solution which maximizes the piezoelectricity is complicated. Thus, a stochastic global optimization combined with homogenization is employed for the identification of the optimal granular configuration of the FE ceramic microstructure with optimum piezoelectric properties. The macroscopic equilibrium piezoelectric properties of polycrystalline FE is calculated using mathematical homogenization at each iteration step. The configuration of grains characterized by its orientations at each iteration is generated using a randomly selected set of orientation distribution parameters. The optimization procedure applied to the single crystalline phase compares well with the experimental data. Apparent enhancement of piezoelectric coefficient d33 is observed in an optimally oriented BaTiO3 single crystal. Based on the good agreement of results with the published data in single crystals, we proceed to apply the methodology in polycrystals. A configuration of crystallites, simultaneously constraining the orientation distribution of the c-axis (polar axis) while incorporating ab-plane randomness, which would multiply the overall piezoelectricity in ceramic BaTiO3 is also identified. The orientation distribution of the c-axes is found to be a narrow Gaussian distribution centered around 45°. The piezoelectric coefficient in such a ceramic is found to

Variation in orgasm occurrence by sexual orientation in a sample of U.S. singles.

Science.gov (United States)

Garcia, Justin R; Lloyd, Elisabeth A; Wallen, Kim; Fisher, Helen E

2014-11-01

Despite recent advances in understanding orgasm variation, little is known about ways in which sexual orientation is associated with men's and women's orgasm occurrence. To assess orgasm occurrence during sexual activity across sexual orientation categories. Data were collected by Internet questionnaire from 6,151 men and women (ages 21-65+ years) as part of a nationally representative sample of single individuals in the United States. Analyses were restricted to a subsample of 2,850 singles (1,497 men, 1,353 women) who had experienced sexual activity in the past 12 months. Participants reported their sex/gender, self-identified sexual orientation (heterosexual, gay/lesbian, bisexual), and what percentage of the time they experience orgasm when having sex with a familiar partner. Mean occurrence rate for experiencing orgasm during sexual activity with a familiar partner was 62.9% among single women and 85.1% among single men, which was significantly different (F1,2848  = 370.6, P sexual orientation: heterosexual men 85.5%, gay men 84.7%, bisexual men 77.6% (F2,1494  = 2.67, P = 0.07, η(2)  = 0.004). For women, however, mean occurrence rate of orgasm varied significantly by sexual orientation: heterosexual women 61.6%, lesbian women 74.7%, bisexual women 58.0% (F2,1350  = 10.95, P sexual orientation, have less predictable, more varied orgasm experiences than do men and that for women, but not men, the likelihood of orgasm varies with sexual orientation. These findings demonstrate the need for further investigations into the comparative sexual experiences and sexual health outcomes of sexual minorities. © 2014 International Society for Sexual Medicine.

Grain by grain study of the mechanisms of crack propagation during iodine SCC of Zry-4

International Nuclear Information System (INIS)

Haddad Andalag, R.E.

1993-01-01

This paper describes the tests conducted to determine the conditions leading to cracking of a specified grain of metal, focussing on the crystallographic orientation of crack paths, the critical stress conditions and the significance of the fractographic features encountered. In order to get orientable cracking, a technique was developed to produce iodine SCC, by means of pressurizing tubes of a specially heat treated Zry-4 having very large grains, shaped as discs of a few millimeters in diameter and grown up to the wall thickness. Careful orientation of fractured grains, performed by means of a back-reflection Laue technique with a precision better than one degree, has proved that transgranular cracking occurs only along basal planes. The effect of anisotropy, plasticity, triaxiality and residual stresses originated in thermal contraction, has to be considered to account for the influence of the stress state . A grain by grain calculation led to the conclusion that transgranular cracking always occurs on those bearing the maximum resolved tensile stress on basal planes. There are clear indications of the need of a triaxial stress state for the process to occur. Fracture modes other than pseudo-cleavage have been encountered, including intergranular separation, ductile tearing produced by prismatic slip and propagation along twin boundaries. In each case the fractographic features have been identified, and associations have been made with fractographs obtained in normal fuel cladding. (Author)

Measurement of baseline and orientation between distributed aerospace platforms.

Science.gov (United States)

Wang, Wen-Qin

2013-01-01

Distributed platforms play an important role in aerospace remote sensing, radar navigation, and wireless communication applications. However, besides the requirement of high accurate time and frequency synchronization for coherent signal processing, the baseline between the transmitting platform and receiving platform and the orientation of platform towards each other during data recording must be measured in real time. In this paper, we propose an improved pulsed duplex microwave ranging approach, which allows determining the spatial baseline and orientation between distributed aerospace platforms by the proposed high-precision time-interval estimation method. This approach is novel in the sense that it cancels the effect of oscillator frequency synchronization errors due to separate oscillators that are used in the platforms. Several performance specifications are also discussed. The effectiveness of the approach is verified by simulation results.

Grain dissection as a grain size reducing mechanism during ice microdynamics

Science.gov (United States)

Steinbach, Florian; Kuiper, Ernst N.; Eichler, Jan; Bons, Paul D.; Drury, Martin R.; Griera, Albert; Pennock, Gill M.; Weikusat, Ilka

2017-04-01

Ice sheets are valuable paleo-climate archives, but can lose their integrity by ice flow. An understanding of the microdynamic mechanisms controlling the flow of ice is essential when assessing climatic and environmental developments related to ice sheets and glaciers. For instance, the development of a consistent mechanistic grain size law would support larger scale ice flow models. Recent research made significant progress in numerically modelling deformation and recrystallisation mechanisms in the polycrystalline ice and ice-air aggregate (Llorens et al., 2016a,b; Steinbach et al., 2016). The numerical setup assumed grain size reduction is achieved by the progressive transformation of subgrain boundaries into new high angle grain boundaries splitting an existing grain. This mechanism is usually termed polygonisation. Analogue experiments suggested, that strain induced grain boundary migration can cause bulges to migrate through the whole of a grain separating one region of the grain from another (Jessell, 1986; Urai, 1987). This mechanism of grain dissection could provide an alternative grain size reducing mechanism, but has not yet been observed during ice microdynamics. In this contribution, we present results using an updated numerical approach allowing for grain dissection. The approach is based on coupling the full field theory crystal visco-plasticity code (VPFFT) of Lebensohn (2001) to the multi-process modelling platform Elle (Bons et al., 2008). VPFFT predicts the mechanical fields resulting from short strain increments, dynamic recrystallisation process are implemented in Elle. The novel approach includes improvements to allow for grain dissection, which was topologically impossible during earlier simulations. The simulations are supported by microstructural observations from NEEM (North Greenland Eemian Ice Drilling) ice core. Mappings of c-axis orientations using the automatic fabric analyser and full crystallographic orientations using electron

Distribution and Orientation of Steel Fibres in UHPFRC

DEFF Research Database (Denmark)

Nezhentseva, Anastasia; Sørensen, Eigil V.; Andersen, Lars Vabbersgaard

The technical report “Distribution and Orientation of Steel Fibres in UHPFRC” is a part of a larger research project entitled “Design of Transition Pieces for Bucket Foundations for Offshore Wind Turbines”. This report is divided into five numbered sections, and a list of references, situated after...

Grain scale stresses and strains determination by X-ray diffraction; Contribution a l'analyse par diffractometrie X des deformations et des contraintes a l'echelle des grains

Energy Technology Data Exchange (ETDEWEB)

Huang, W

2007-03-15

A new methodology for strain and stress analysis by X ray diffraction (XRD) in single crystal was developed. It can be applied to determine the second order stress (in grain scale) in single and multi-crystal material with non-cubic lattice. This method is based on the method Ortner I. It has introduced the metric tensor G which is deduced from the lattice space measured by XRD. In the developed method, when the crystal reference is non-orthonormal, an orthonormal reference associated with the crystal basis is defined, so all calculation could be done with usual calculation laws. The use of the least square method allows the acquisition of many more measurements than the six absolute necessary. Then a better metric tensor G is calculated and the statistical error is obtained. This developed method was applied in a bi crystal copper. The experimental results have shown that this method is also effective. The second order residuals stresses for coarse Zn grains in a galvanized coating were determined after annealing. The four coarse grains with different orientations were also characterized and demonstrated the elastic and plastic deformation mechanism in a grain or between the grains during in situ tensile loading. So this method is well able to determine the strains and stresses in grain scale in a mono crystal or multi crystal with any crystalline structure. (author)

Optimal numerical methods for determining the orientation averages of single-scattering properties of atmospheric ice crystals

International Nuclear Information System (INIS)

Um, Junshik; McFarquhar, Greg M.

2013-01-01

The optimal orientation averaging scheme (regular lattice grid scheme or quasi Monte Carlo (QMC) method), the minimum number of orientations, and the corresponding computing time required to calculate the average single-scattering properties (i.e., asymmetry parameter (g), single-scattering albedo (ω o ), extinction efficiency (Q ext ), scattering efficiency (Q sca ), absorption efficiency (Q abs ), and scattering phase function at scattering angles of 90° (P 11 (90°)), and 180° (P 11 (180°))) within a predefined accuracy level (i.e., 1.0%) were determined for four different nonspherical atmospheric ice crystal models (Gaussian random sphere, droxtal, budding Bucky ball, and column) with maximum dimension D=10μm using the Amsterdam discrete dipole approximation at λ=0.55, 3.78, and 11.0μm. The QMC required fewer orientations and less computing time than the lattice grid. The calculations of P 11 (90°) and P 11 (180°) required more orientations than the calculations of integrated scattering properties (i.e., g, ω o , Q ext , Q sca , and Q abs ) regardless of the orientation average scheme. The fewest orientations were required for calculating g and ω o . The minimum number of orientations and the corresponding computing time for single-scattering calculations decreased with an increase of wavelength, whereas they increased with the surface-area ratio that defines particle nonsphericity. -- Highlights: •The number of orientations required to calculate the average single-scattering properties of nonspherical ice crystals is investigated. •Single-scattering properties of ice crystals are calculated using ADDA. •Quasi Monte Carlo method is more efficient than lattice grid method for scattering calculations. •Single-scattering properties of ice crystals depend on a newly defined parameter called surface area ratio

Significant effect of grain size distribution on compaction rates in granular aggregates

NARCIS (Netherlands)

Niemeijer, André|info:eu-repo/dai/nl/370832132; Elsworth, Derek; Marone, Chris

2009-01-01

We investigate the role of pressure solution in deformation of upper- to mid-crustal rocks using aggregates of halite as a room temperature analog for fluid-assisted deformation processes in the Earth's crust. Experiments evaluate the effects of initial grain size distribution on macroscopic

Two-motor single-inverter field-oriented induction machine drive ...

Indian Academy of Sciences (India)

Multi-machine, single-inverter induction motor drives are attractive in situations in which all machines are of similar ratings, and operate at approximately the same load torques. The advantages include small size compared to multi-inverter system, lower weight and overall cost. However, field oriented control of such drives ...

Coarse-graining using the relative entropy and simplex-based optimization methods in VOTCA

Science.gov (United States)

Rühle, Victor; Jochum, Mara; Koschke, Konstantin; Aluru, N. R.; Kremer, Kurt; Mashayak, S. Y.; Junghans, Christoph

2014-03-01

Coarse-grained (CG) simulations are an important tool to investigate systems on larger time and length scales. Several methods for systematic coarse-graining were developed, varying in complexity and the property of interest. Thus, the question arises which method best suits a specific class of system and desired application. The Versatile Object-oriented Toolkit for Coarse-graining Applications (VOTCA) provides a uniform platform for coarse-graining methods and allows for their direct comparison. We present recent advances of VOTCA, namely the implementation of the relative entropy method and downhill simplex optimization for coarse-graining. The methods are illustrated by coarse-graining SPC/E bulk water and a water-methanol mixture. Both CG models reproduce the pair distributions accurately. SYM is supported by AFOSR under grant 11157642 and by NSF under grant 1264282. CJ was supported in part by the NSF PHY11-25915 at KITP. K. Koschke acknowledges funding by the Nestle Research Center.

Determination of size distribution using neural networks

NARCIS (Netherlands)

Stevens, JH; Nijhuis, JAG; Spaanenburg, L; Mohammadian, M

1999-01-01

In this paper we present a novel approach to the estimation of size distributions of grains in water from images. External conditions such as the concentrations of grains in water cannot be controlled. This poses problems for local image analysis which tries to identify and measure single grains.

75 FR 60161 - WTO Dispute Settlement Proceeding Regarding China-Countervailing and Antidumping Duties on Grain...

Science.gov (United States)

2010-09-29

... Proceeding Regarding China--Countervailing and Antidumping Duties on Grain Oriented Flat-Rolled Electrical... States of grain oriented flat-rolled electrical steel. That request may be found at http://www.wto.org... countervailing and antidumping duties on grain oriented flat-rolled electrical steel (``GOES'') exported from the...

Simple die pressing for making artificial holes in single-grain Gd1.5Ba2Cu3O7−y superconductors

International Nuclear Information System (INIS)

Kim, K-M; Park, S-D; Jun, B-H; Kim, C-J; Ko, T K

2012-01-01

The presence of artificial holes in single-grain REBa 2 Cu 3 O 7−y (RE123, RE: rare-earth elements) bulk superconductors can facilitate oxygen diffusion into superconducting grains through the increased surface area. In addition to the enhancement of oxygen diffusion, the mechanical properties and thermal conductivity of bulk superconductors can be improved by filling holes with a metallic conductive phase. This study presents a new and simple hole-making process for single-grain RE123 bulk superconductors. Artificial holes 3 or 5 mm in diameter were made for Gd 1.5 Ba 2 Cu 3 O 7−y (Gd1.5) powder compacts prior to the sintering/melt growth process using specially designed pressing dies. The die pressing neither induced cracking in powder compacts nor influenced thermal procedures for the Gd123 growth. Single-grain Gd1.5 bulk superconductors with holes were successfully fabricated by a top-seeded melt growth (TSMG) process using Gd1.5 powder compacts with holes. The die pressing was proven as a time-saving process in comparison with the conventional method which makes holes in sintered or melt-processed hard bodies by mechanical drilling. The detailed fabrication process of single-grain Gd1.5 bulk superconductor with holes, magnetic levitation forces, and magnetic flux density, estimated for the single-grain Gd123 bulk superconductors with holes, are reported. (paper)

Magnetic properties in an ash flow tuff with continuous grain size variation: a natural reference for magnetic particle granulometry

Science.gov (United States)

Till, J.L.; Jackson, M.J.; Rosenbaum, J.G.; Solheid, P.

2011-01-01

The Tiva Canyon Tuff contains dispersed nanoscale Fe-Ti-oxide grains with a narrow magnetic grain size distribution, making it an ideal material in which to identify and study grain-size-sensitive magnetic behavior in rocks. A detailed magnetic characterization was performed on samples from the basal 5 m of the tuff. The magnetic materials in this basal section consist primarily of (low-impurity) magnetite in the form of elongated submicron grains exsolved from volcanic glass. Magnetic properties studied include bulk magnetic susceptibility, frequency-dependent and temperature-dependent magnetic susceptibility, anhysteretic remanence acquisition, and hysteresis properties. The combined data constitute a distinct magnetic signature at each stratigraphic level in the section corresponding to different grain size distributions. The inferred magnetic domain state changes progressively upward from superparamagnetic grains near the base to particles with pseudo-single-domain or metastable single-domain characteristics near the top of the sampled section. Direct observations of magnetic grain size confirm that distinct transitions in room temperature magnetic susceptibility and remanence probably denote the limits of stable single-domain behavior in the section. These results provide a unique example of grain-size-dependent magnetic properties in noninteracting particle assemblages over three decades of grain size, including close approximations of ideal Stoner-Wohlfarth assemblages, and may be considered a useful reference for future rock magnetic studies involving grain-size-sensitive properties.

Micro-PIXE mapping of mineral distribution in mature grain of two pearl millet cultivars

Energy Technology Data Exchange (ETDEWEB)

Minnis-Ndimba, R., E-mail: rminnis@tlabs.ac.za [iThemba LABS, National Research Foundation (South Africa); Kruger, J.; Taylor, J.R.N. [Department of Food Science and Institute for Food, Nutrition and Well-being, University of Pretoria (South Africa); Mtshali, C. [iThemba LABS, National Research Foundation (South Africa); Pineda-Vargas, C.A. [iThemba LABS, National Research Foundation (South Africa); Faculty of Health and Wellness Sciences, CPUT, Bellville (South Africa)

2015-11-15

Micro-proton-induced X-ray emission (micro-PIXE) was used to map the distribution of several nutritionally important minerals found in the grain tissue of two cultivars of pearl millet (Pennisetum glaucum (L.) R. Br.). The distribution maps revealed that the predominant localisation of minerals was within the germ (consisting of the scutellum and embryo) and the outer grain layers (specifically the pericarp and aleurone); whilst the bulk of the endosperm tissue featured relatively low concentrations of the surveyed minerals. Within the germ, the scutellum was revealed as a major storage tissue for P and K, whilst Ca, Mn and Zn were more prominent within the embryo. Fe was revealed to have a distinctive distribution pattern, confined to the dorsal end of the scutellum; but was also highly concentrated in the outer grain layers. Interestingly, the hilar region was also revealed as a site of high accumulation of minerals, particularly for S, Ca, Mn, Fe and Zn, which may be part of a defensive strategy against infection or damage. Differences between the two cultivars, in terms of the bulk Fe and P content obtained via inductively coupled plasma optical emission spectrometry (ICP-OES), concurred with the average concentration data determined from the analysis of micro-PIXE spectra specifically extracted from the endosperm tissue.

Development of a generic seed crystal for the fabrication of large grain (RE)-Ba-Cu-O bulk superconductors

International Nuclear Information System (INIS)

Shi, Y; Babu, N Hari; Cardwell, D A

2005-01-01

The critical current density, J c , irreversibility field, B irr , and magnetic field trapping ability of (LRE)-Ba-Cu-O bulk superconductors, where LRE is a light rare earth element such as Nd, Sm, Eu and Gd, are generally superior to those of the more common melt-processed Y-Ba-Cu-O (YBCO). The lack of availability of a suitable seed crystal to grow large, single grain (LRE)-Ba-Cu-O superconductors with controlled orientation, however, has hindered severely the development of these materials for engineering applications over the past ten years. In this communication we report for the first time the development of a generic seed crystal that can be used to fabricate any rare earth (RE) based (RE)-Ba-Cu-O ((RE)BCO) superconductor in the form of a large single grain with controlled orientation. The new seed crystal will potentially enable large grain (LRE)-Ba-Cu-O bulk superconductors to be fabricated routinely, as is the case for YBCO. This will enable the field trapping and current-carrying characteristics of these materials to be explored in more detail than has been possible to date. (rapid communication)

An ultrasonic methodology to non-destructively estimate the grain orientation in an anisotropic weld

Directory of Open Access Journals (Sweden)

Wirdelius Håkan

2014-06-01

Full Text Available The initial step towards a non-destructive technique that estimates grain orientation in an anisotropic weld is presented in this paper. The purpose is to aid future forward simulations of ultrasonic NDT of this kind of weld to achieve a better result. A forward model that consists of a weld model, a transmitter model, a receiver model and a 2D ray tracing algorithm is introduced. An inversion based on a multi-objective genetic algorithm is also presented. Experiments are conducted for both P and SV waves in order to collect enough data used in the inversion. Calculation is conducted to fulfil the estimation with both the synthetic data and the experimental data. Concluding remarks are presented at the end of the paper.

Determination of hydraulic conductivity from grain-size distribution for different depositional environments

KAUST Repository

Rosas, Jorge

2013-06-06

Over 400 unlithified sediment samples were collected from four different depositional environments in global locations and the grain-size distribution, porosity, and hydraulic conductivity were measured using standard methods. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations (e.g., Hazen, Carman-Kozeny) commonly used to estimate hydraulic conductivity from grain-size distribution. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly to the measured hydraulic conductivity values with errors ranging to over 500%. To improve the empirical estimation methodology, the samples were grouped by depositional environment and subdivided into subgroups based on lithology and mud percentage. The empirical methods were then analyzed to assess which methods best estimated the measured values. Modifications of the empirical equations, including changes to special coefficients and addition of offsets, were made to produce modified equations that considerably improve the hydraulic conductivity estimates from grain size data for beach, dune, offshore marine, and river sediments. Estimated hydraulic conductivity errors were reduced to 6 to 7.1m/day for the beach subgroups, 3.4 to 7.1m/day for dune subgroups, and 2.2 to 11m/day for offshore sediments subgroups. Improvements were made for river environments, but still produced high errors between 13 and 23m/day. © 2013, National Ground Water Association.

Determination of hydraulic conductivity from grain-size distribution for different depositional environments

KAUST Repository

Rosas, Jorge; Lopez Valencia, Oliver Miguel; Missimer, Thomas M.; Coulibaly, Kapo M.; Dehwah, Abdullah; Sesler, Kathryn; Rodri­ guez, Luis R. Lujan; Mantilla, David

2013-01-01

Over 400 unlithified sediment samples were collected from four different depositional environments in global locations and the grain-size distribution, porosity, and hydraulic conductivity were measured using standard methods. The measured hydraulic conductivity values were then compared to values calculated using 20 different empirical equations (e.g., Hazen, Carman-Kozeny) commonly used to estimate hydraulic conductivity from grain-size distribution. It was found that most of the hydraulic conductivity values estimated from the empirical equations correlated very poorly to the measured hydraulic conductivity values with errors ranging to over 500%. To improve the empirical estimation methodology, the samples were grouped by depositional environment and subdivided into subgroups based on lithology and mud percentage. The empirical methods were then analyzed to assess which methods best estimated the measured values. Modifications of the empirical equations, including changes to special coefficients and addition of offsets, were made to produce modified equations that considerably improve the hydraulic conductivity estimates from grain size data for beach, dune, offshore marine, and river sediments. Estimated hydraulic conductivity errors were reduced to 6 to 7.1m/day for the beach subgroups, 3.4 to 7.1m/day for dune subgroups, and 2.2 to 11m/day for offshore sediments subgroups. Improvements were made for river environments, but still produced high errors between 13 and 23m/day. © 2013, National Ground Water Association.

Modelling of grain refinement driven by negative grain boundary energy

Czech Academy of Sciences Publication Activity Database

Fischer, F. D.; Zickler, G. A.; Svoboda, Jiří

2017-01-01

Roč. 97, č. 23 (2017), s. 1963-1977 ISSN 1478-6435 R&D Projects: GA ČR(CZ) GA15-06390S Institutional support: RVO:68081723 Keywords : grain refinement * grain nucleation * distribution concept * jump on distribution function Subject RIV: BJ - Thermodynamics OBOR OECD: Thermodynamics Impact factor: 1.505, year: 2016

Radical distributions in ammonium tartrate single crystals exposed to photon and neutron beams

International Nuclear Information System (INIS)

Marrale, M.; Longo, A.; Brai, M.; Barbon, A.; Brustolon, M.

2014-01-01

distribution of free radicals in the material. A more convenient approach is proposed for a direct determination of the ID contribution, allowing an easier treatment of the data and which shows larger concentration of free radical in the case of neutron irradiation with respect to photon irradiation. As far as the DEER technique is concerned, it is noted that the study of irradiated single crystals has advantages and disadvantages with respect to powders. An advantage is that for particular orientations of the crystal in the magnetic field the EPR spectrum is given by intense and well-separated lines, allowing the necessary separate microwave double excitation. A further advantage could derive from the dependence of DEER results on the crystal orientation in the magnetic field, as this could in principle provide much more information on the effects of different radiation beams. In particular, it was observed that the spatial spin distribution has largest peak centred at lower distances for neutron irradiation than for gamma irradiation. However, this would require a demanding thorough analysis of the DEER response exploring a number of different orientations of the crystal. (authors)

Micromechanical Modeling of Grain Boundaries Damage in a Copper Alloy Under Creep

International Nuclear Information System (INIS)

Voese, Markus

2015-01-01

In order to include the processes on the scale of the grain structure into the description of the creep behaviour of polycrystalline materials, the damage development of a single grain boundary has been initially investigated in the present work. For this purpose, a special simulationmethod has been used, whose resolution procedure based on holomorphic functions. The mechanisms taken into account for the simulations include nucleation, growth by grain boundary diffusion, coalescence and shrinkage until complete sintering of grain boundary cavities. These studies have then been used to develop a simplified cavitation model, which describes the grain boundary damage by two state variables and the time-dependent development by a mechanism-oriented rate formulation. To include the influence of grain boundaries within continuum mechanical considerations of polycrystals, an interface model has been developed, that incorporates both damage according to the simplified cavitation model and grain boundary sliding in dependence of a phenomenological grain boundary viscosity. Furthermore a micromechanical model of a polycrystal has been developed that allows to include a material's grain structure into the simulation of the creep behaviour by means of finite element simulations. Thereby, the deformations of individual grains are expressed by a viscoplastic single crystal model and the grain boundaries are described by the proposed interface model. The grain structure is represented by a finite element model, in which the grain boundaries are modelled by cohesive elements. From the evaluation of experimental creep data, the micromechanical model of a polycrystal has been calibrated for a copper-antimony alloy at a temperature of 823 K. Thereby, the adjustment of the single crystal model has been carried out on the basis of creep rates of pure copper single crystal specimens. The experimental determination of grain boundary sliding and grain boundary porosity for coarse-grained

Single molecule optical measurements of orientation and rotations of biological macromolecules.

Science.gov (United States)

Shroder, Deborah Y; Lippert, Lisa G; Goldman, Yale E

2016-11-22

Subdomains of macromolecules often undergo large orientation changes during their catalytic cycles that are essential for their activity. Tracking these rearrangements in real time opens a powerful window into the link between protein structure and functional output. Site-specific labeling of individual molecules with polarized optical probes and measurement of their spatial orientation can give insight into the crucial conformational changes, dynamics, and fluctuations of macromolecules. Here we describe the range of single molecule optical technologies that can extract orientation information from these probes, review the relevant types of probes and labeling techniques, and highlight the advantages and disadvantages of these technologies for addressing specific inquiries.

Evolution of microstructure, texture and inhibitor along the processing route for grain-oriented electrical steels using strip casting

Energy Technology Data Exchange (ETDEWEB)

Liu, Hai-Tao, E-mail: liuht@ral.neu.edu.cn [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Institute of Research of Iron and Steel, Shasteel, Zhangjiagang 215625, Jiangsu (China); Yao, Sheng-Jie [School of Materials Science and Engineering, Harbin Institute of Technology at Weihai, 264209 (China); Sun, Yu; Gao, Fei; Song, Hong-Yu; Liu, Guo-Huai [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China); Li, Lei; Geng, Dian-Qiao [Key Laboratory of Electromagnetic Processing of Materials, Ministry of Education, Northeastern University, Shenyang 110819 (China); Liu, Zhen-Yu; Wang, Guo-Dong [State Key Laboratory of Rolling and Automation, Northeastern University, P.O. Box 105, Shenyang 110819 (China)

2015-08-15

In the present work, a regular grade GO sheet was produced successively by strip casting, hot rolling, normalizing annealing, two-stage cold rolling with intermediate annealing, primary recrystallization annealing, secondary recrystallization annealing and purification. The aim of this paper was to characterize the evolution of microstructure, texture and inhibitor along the new processing route by comprehensive utilization of optical microscopy, X-ray diffraction and transmission electron microscopy. It was found that a fine microstructure with the ferrite grain size range of 7–12 μm could be obtained in the primary recrystallization annealed sheet though a very coarse microstructure was produced in the initial as-cast strip. The main finding was that the “texture memory” effect on Goss texture started on the through-thickness intermediate annealed strip after first cold rolling, which was not similar to the “texture memory” effect on Goss texture starting on the surface layers of the hot rolled strip in the conventional production route. As a result, the origin of Goss nuclei capable of secondary recrystallization lied in the grains already presented in Goss orientation in the intermediate annealed strip after first cold rolling. Another finding was that fine and dispersive inhibitors (mainly AlN) were easy to be produced in the primary recrystallization microstructure due to the initial rapid solidification during strip casting and the subsequent rapid cooling, and the very high temperature reheating usually used before hot rolling in the conventional production route could be avoided. - Highlights: • A regular grade grain-oriented electrical steel was produced. • Evolution of microstructure, texture and inhibitor was characterized. • Origin of Goss nuclei lied in the intermediate annealed strip. • A fine primary recrystallization microstructure could be produced. • Effective inhibitors were easy to be obtained in the new processing route.

The Effect of Grain Size on Mechanical Instability in Single-Phase Li-Alloy Anodes

National Research Council Canada - National Science Library

Wolfenstine, Jeff

2000-01-01

.... The results of this study suggest that decreasing the particle and/or grain size is not a practical approach to solving the mechanical instability problem of single phase Li alloys that are intended to be used as anodes in Li-ion batteries.

Orientational imaging of a single plasmonic nanoparticle using dark-field hyperspectral imaging

Science.gov (United States)

Mehta, Nishir; Mahigir, Amirreza; Veronis, Georgios; Gartia, Manas Ranjan

2017-08-01

Orientation of plasmonic nanostructures is an important feature in many nanoscale applications such as catalyst, biosensors DNA interactions, protein detections, hotspot of surface enhanced Raman spectroscopy (SERS), and fluorescence resonant energy transfer (FRET) experiments. However, due to diffraction limit, it is challenging to obtain the exact orientation of the nanostructure using standard optical microscope. Hyperspectral Imaging Microscopy is a state-of-the-art visualization technology that combines modern optics with hyperspectral imaging and computer system to provide the identification and quantitative spectral analysis of nano- and microscale structures. In this work, initially we use transmitted dark field imaging technique to locate single nanoparticle on a glass substrate. Then we employ hyperspectral imaging technique at the same spot to investigate orientation of single nanoparticle. No special tagging or staining of nanoparticle has been done, as more likely required in traditional microscopy techniques. Different orientations have been identified by carefully understanding and calibrating shift in spectral response from each different orientations of similar sized nanoparticles. Wavelengths recorded are between 300 nm to 900 nm. The orientations measured by hyperspectral microscopy was validated using finite difference time domain (FDTD) electrodynamics calculations and scanning electron microscopy (SEM) analysis. The combination of high resolution nanometer-scale imaging techniques and the modern numerical modeling capacities thus enables a meaningful advance in our knowledge of manipulating and fabricating shaped nanostructures. This work will advance our understanding of the behavior of small nanoparticle clusters useful for sensing, nanomedicine, and surface sciences.

Electroless Co–P-Carbon Nanotube composite coating to enhance magnetic properties of grain-oriented electrical steel

International Nuclear Information System (INIS)

Goel, Vishu; Anderson, Philip; Hall, Jeremy; Robinson, Fiona; Bohm, Siva

2016-01-01

The effect of Co–P-CNT coating on the magnetic properties of grain oriented electrical steel was investigated. To analyse the coating, Raman spectroscopy, Superconducting QUantum Interference Device (SQUID), single strip testing, Scanning Electron Microscopy (SEM) and talysurf surface profilometry were performed. Raman spectra showed the D and G band which corroborates the presence of Multi-Walled Carbon Nanotubes (MWCNT) in the coating. The magnetic nature of the coating was confirmed by SQUID results. Power loss results show an improvement ranging 13–15% after coating with Co–P-CNT. The resistivity of the coating was measured to be 10 4 µΩ cm. Loss separation graphs were plotted before and after coating to study the improvement in power loss. It was found that the coating helps in reducing the hysteresis loss. The thickness of the coating was found to be 414±40 nm. The surface profilometry results showed that the surface roughness improved after coating the sample. - Highlights: • Co–P-CNT coating on Fe–3%Si steel was able to reduce the power loss by 13–15%. • Co–P-CNT coating reduced the surface roughness and enhanced the magnetic properties. • The decrease in coating thickness increased the stacking factor. • The stacking factor was further improved by the magnetic nature of the coating.

Electroless Co–P-Carbon Nanotube composite coating to enhance magnetic properties of grain-oriented electrical steel

Energy Technology Data Exchange (ETDEWEB)

Goel, Vishu, E-mail: vishu.goel.nit@gmail.com [Wolfson Centre for Magnetics, Cardiff University, Cardiff CF243AA (United Kingdom); Anderson, Philip, E-mail: AndersonPI1@cf.ac.uk [Wolfson Centre for Magnetics, Cardiff University, Cardiff CF243AA (United Kingdom); Hall, Jeremy, E-mail: HallJP@cf.ac.uk [Wolfson Centre for Magnetics, Cardiff University, Cardiff CF243AA (United Kingdom); Robinson, Fiona, E-mail: fiona.cj.robinson@tatasteel.com [Cogent power Ltd., Newport NP19 0RB (United Kingdom); Bohm, Siva, E-mail: siva.bohm@tatasteel.com [IIT Bombay, Mumbai 400076 (India)

2016-06-01

The effect of Co–P-CNT coating on the magnetic properties of grain oriented electrical steel was investigated. To analyse the coating, Raman spectroscopy, Superconducting QUantum Interference Device (SQUID), single strip testing, Scanning Electron Microscopy (SEM) and talysurf surface profilometry were performed. Raman spectra showed the D and G band which corroborates the presence of Multi-Walled Carbon Nanotubes (MWCNT) in the coating. The magnetic nature of the coating was confirmed by SQUID results. Power loss results show an improvement ranging 13–15% after coating with Co–P-CNT. The resistivity of the coating was measured to be 10{sup 4} µΩ cm. Loss separation graphs were plotted before and after coating to study the improvement in power loss. It was found that the coating helps in reducing the hysteresis loss. The thickness of the coating was found to be 414±40 nm. The surface profilometry results showed that the surface roughness improved after coating the sample. - Highlights: • Co–P-CNT coating on Fe–3%Si steel was able to reduce the power loss by 13–15%. • Co–P-CNT coating reduced the surface roughness and enhanced the magnetic properties. • The decrease in coating thickness increased the stacking factor. • The stacking factor was further improved by the magnetic nature of the coating.

Stress-assisted grain growth in nanocrystalline metals: Grain boundary mediated mechanisms and stabilization through alloying

International Nuclear Information System (INIS)

Zhang, Yang; Tucker, Garritt J.; Trelewicz, Jason R.

2017-01-01

The mechanisms of stress-assisted grain growth are explored using molecular dynamics simulations of nanoindentation in nanocrystalline Ni and Ni-1 at.% P as a function of grain size and deformation temperature. Grain coalescence is primarily confined to the high stress region beneath the simulated indentation zone in nanocrystalline Ni with a grain size of 3 nm. Grain orientation and atomic displacement vector mapping demonstrates that coalescence transpires through grain rotation and grain boundary migration, which are manifested in the grain interior and grain boundary components of the average microrotation. A doubling of the grain size to 6 nm and addition of 1 at.% P eliminates stress-assisted grain growth in Ni. In the absence of grain coalescence, deformation is accommodated by grain boundary-mediated dislocation plasticity and thermally activated in pure nanocrystalline Ni. By adding solute to the grain boundaries, the temperature-dependent deformation behavior observed in both the lattice and grain boundaries inverts, indicating that the individual processes of dislocation and grain boundary plasticity will exhibit different activity based on boundary chemistry and deformation temperature.

Grain dynamics and inter-grain coupling in dusty plasma Coulomb crystals

International Nuclear Information System (INIS)

Rahman, H.U.; Mohideen, U.; Smith, M.A.; Rosenberg, M.; Mendis, D.A.

2001-01-01

We review our results on the lattice structure and the lattice dynamics of dusty plasma Coulomb crystals formed in rectangular conductive grooves. The basic structure appears to be made of mutually repulsive columns of grains confined by the walls of the groove. The columns are oriented along the direction of the electrode sheath electric field. Inter-grain coupling as a function of plasma temperature and density were investigated by measurement of these parameters. A simple phenomenological model wherein the inter-grain spacing along the column results from an attractive electric field induced dipole-dipole force balanced by a repulsive monopole Coulomb force is consistent with observed features of the Coulomb crystal. In addition, here we present some preliminary measurements of the vibration and rotation dynamics of the individual grains in the Coulomb crystal. The thermal energy of the dust grain thus calculated is much less than the inter-grain Coulomb potential energy as required for the formation of stable structures. Also the observed rotational frequency is consistent with the assumption of thermal equilibrium between the dust grains and the neutral gas. (orig.)

Density, distribution, and orientation of water molecules inside and outside carbon nanotubes.

Science.gov (United States)

Thomas, J A; McGaughey, A J H

2008-02-28

The behavior of water molecules inside and outside 1.1, 2.8, 6.9, and 10.4 nm diameter armchair carbon nanotubes (CNTs) is predicted using molecular dynamics simulations. The effects of CNT diameter on mass density, molecular distribution, and molecular orientation are identified for both the confined and unconfined fluids. Within 1 nm of the CNT surface, unconfined water molecules assume a spatially varying density profile. The molecules distribute nonuniformly around the carbon surface and have preferred orientations. The behavior of the unconfined water molecules is invariant with CNT diameter. The behavior of the confined water, however, can be correlated to tube diameter. Inside the 10.4 nm CNT, the molecular behavior is indistinguishable from that of the unconfined fluid. Within the smaller CNTs, surface curvature effects reduce the equilibrium water density and force water molecules away from the surface. This effect changes both the molecular distribution and preferred molecular orientations.

Normal and abnormal grain growth in fine-grained Nd-Fe-B sintered magnets prepared from He jet milled powders

Energy Technology Data Exchange (ETDEWEB)

Bittner, F., E-mail: f.bittner@ifw-dresden.de [IFW Dresden, Institute for Metallic Materials, PO Box 270116, 01171 Dresden (Germany); Technische Universität Dresden, Institute of Materials Science, 01062 Dresden (Germany); Woodcock, T.G. [IFW Dresden, Institute for Metallic Materials, PO Box 270116, 01171 Dresden (Germany); Schultz, L. [IFW Dresden, Institute for Metallic Materials, PO Box 270116, 01171 Dresden (Germany); Technische Universität Dresden, Institute of Materials Science, 01062 Dresden (Germany); Schwöbel, C. [Technische Universität Darmstadt, Materialwissenschaft, Alarich-Weiß-Str. 16, 64287 Darmstadt (Germany); Gutfleisch, O. [Technische Universität Darmstadt, Materialwissenschaft, Alarich-Weiß-Str. 16, 64287 Darmstadt (Germany); Fraunhofer ISC, Projektgruppe für Werkstoffkreisläufe und Ressourcenstrategie IWKS, Rodenbacher Chaussee 4, 63457 Hanau (Germany); Zickler, G.A.; Fidler, J. [Technische Universität Wien, Institute of Solid State Physics, Wiedner Hauptstr. 8-10, 1040 Wien (Austria); Üstüner, K.; Katter, M. [Vacuumschmelze GmbH & Co. KG, 63412 Hanau (Germany)

2017-03-15

Fine-grained, heavy rare earth free Nd-Fe-B sintered magnets were prepared from He jet milled powders with an average particle size of 1.5 µm by low temperature sintering at 920 °C or 980 °C. A coercivity of >1600 kA/m was achieved for an average grain size of 1.68 µm. Transmission electron microscopy showed that the distribution and composition of intergranular and grain boundary junction phases was similar to that in conventionally processed magnets. Microstructural analysis on different length scales revealed the occurrence of abnormal grain growth, which is unexpected for sintering temperatures below 1000 °C. A larger area fraction of abnormal grains was observed in the sample sintered at 920 °C compared to that sintered at 980 °C. Microtexture investigation showed a better crystallographic alignment of the abnormal grains compared to the fine-grained matrix, which is explained by a size dependent alignment of the powder particles during magnetic field alignment prior to sintering. Slightly larger particles in the initial powder show a better alignment and will act as nucleation sites for abnormal grain growth. Magneto-optical Kerr investigations confirmed the lower switching field of the abnormal grains compared to the fine-grained matrix. The demagnetisation curve of the sample sintered at 920 °C showed reduced rectangularity and this was attributed to a cooperative effect of the larger fraction of abnormal grains with low switching field and, as a minor effect, a reduced degree of crystallographic texture in this sample compared to the material sintered at 980 °C, which did not show the reduced rectangularity of the demagnetisation curve. - Highlights: • He Jet milling to reduce Nd-Fe-B grain size and to enhance coercivity. • Normal and abnormal grain growth observed for low temperature sintering. • Well oriented abnormal grown grains explained by size dependent field alignment. • Poor rectangularity is caused by low nucleation field of

Normal and abnormal grain growth in fine-grained Nd-Fe-B sintered magnets prepared from He jet milled powders

International Nuclear Information System (INIS)

Bittner, F.; Woodcock, T.G.; Schultz, L.; Schwöbel, C.; Gutfleisch, O.; Zickler, G.A.; Fidler, J.; Üstüner, K.; Katter, M.

2017-01-01

Fine-grained, heavy rare earth free Nd-Fe-B sintered magnets were prepared from He jet milled powders with an average particle size of 1.5 µm by low temperature sintering at 920 °C or 980 °C. A coercivity of >1600 kA/m was achieved for an average grain size of 1.68 µm. Transmission electron microscopy showed that the distribution and composition of intergranular and grain boundary junction phases was similar to that in conventionally processed magnets. Microstructural analysis on different length scales revealed the occurrence of abnormal grain growth, which is unexpected for sintering temperatures below 1000 °C. A larger area fraction of abnormal grains was observed in the sample sintered at 920 °C compared to that sintered at 980 °C. Microtexture investigation showed a better crystallographic alignment of the abnormal grains compared to the fine-grained matrix, which is explained by a size dependent alignment of the powder particles during magnetic field alignment prior to sintering. Slightly larger particles in the initial powder show a better alignment and will act as nucleation sites for abnormal grain growth. Magneto-optical Kerr investigations confirmed the lower switching field of the abnormal grains compared to the fine-grained matrix. The demagnetisation curve of the sample sintered at 920 °C showed reduced rectangularity and this was attributed to a cooperative effect of the larger fraction of abnormal grains with low switching field and, as a minor effect, a reduced degree of crystallographic texture in this sample compared to the material sintered at 980 °C, which did not show the reduced rectangularity of the demagnetisation curve. - Highlights: • He Jet milling to reduce Nd-Fe-B grain size and to enhance coercivity. • Normal and abnormal grain growth observed for low temperature sintering. • Well oriented abnormal grown grains explained by size dependent field alignment. • Poor rectangularity is caused by low nucleation field of

Local Plasticity of Al Thin Films as Revealed by X-Ray Microdiffraction

Science.gov (United States)

Spolenak, R.; Brown, W. L.; Tamura, N.; MacDowell, A. A.; Celestre, R. S.; Padmore, H. A.; Valek, B.; Bravman, J. C.; Marieb, T.; Fujimoto, H.; Batterman, B. W.; Patel, J. R.

2003-03-01

Grain-to-grain interactions dominate the plasticity of Al thin films and establish effective length scales smaller than the grain size. We have measured large strain distributions and their changes under plastic strain in 1.5-μm-thick Al0.5%Cu films using a 0.8-μm-diameter white x-ray probe at the Advanced Light Source. Strain distributions arise not only from the distribution of grain sizes and orientation, but also from the differences in grain shape and from stress environment. Multiple active glide plane domains have been found within single grains. Large grains behave like multiple smaller grains even before a dislocation substructure can evolve.

Results on the Coherent Interaction of High Energy Electrons and Photons in Oriented Single Crystals

CERN Document Server

Apyan, A.; Badelek, B.; Ballestrero, S.; Biino, C.; Birol, I.; Cenci, P.; Connell, S.H.; Eichblatt, S.; Fonseca, T.; Freund, A.; Gorini, B.; Groess, R.; Ispirian, K.; Ketel, T.J.; Kononets, Yu.V.; Lopez, A.; Mangiarotti, A.; van Rens, B.; Sellschop, J.P.F.; Shieh, M.; Sona, P.; Strakhovenko, V.; Uggerhoj, E.; Uggerhj, Ulrik Ingerslev; Unel, G.; Velasco, M.; Vilakazi, Z.Z.; Wessely, O.; Kononets, Yu.V.

2005-01-01

The CERN-NA-59 experiment examined a wide range of electromagnetic processes for multi-GeV electrons and photons interacting with oriented single crystals. The various types of crystals and their orientations were used for producing photon beams and for converting and measuring their polarisation. The radiation emitted by 178 GeV unpolarised electrons incident on a 1.5 cm thick Si crystal oriented in the Coherent Bremsstrahlung (CB) and the String-of-Strings (SOS) modes was used to obtain multi-GeV linearly polarised photon beams. A new crystal polarimetry technique was established for measuring the linear polarisation of the photon beam. The polarimeter is based on the dependence of the Coherent Pair Production (CPP) cross section in oriented single crystals on the direction of the photon polarisation with respect to the crystal plane. Both a 1 mm thick single crystal of Germanium and a 4 mm thick multi-tile set of synthetic Diamond crystals were used as analyzers of the linear polarisation. A birefringence ...

Distribution of orientation selectivity in recurrent networks of spiking neurons with different random topologies.

Science.gov (United States)

Sadeh, Sadra; Rotter, Stefan

2014-01-01

Neurons in the primary visual cortex are more or less selective for the orientation of a light bar used for stimulation. A broad distribution of individual grades of orientation selectivity has in fact been reported in all species. A possible reason for emergence of broad distributions is the recurrent network within which the stimulus is being processed. Here we compute the distribution of orientation selectivity in randomly connected model networks that are equipped with different spatial patterns of connectivity. We show that, for a wide variety of connectivity patterns, a linear theory based on firing rates accurately approximates the outcome of direct numerical simulations of networks of spiking neurons. Distance dependent connectivity in networks with a more biologically realistic structure does not compromise our linear analysis, as long as the linearized dynamics, and hence the uniform asynchronous irregular activity state, remain stable. We conclude that linear mechanisms of stimulus processing are indeed responsible for the emergence of orientation selectivity and its distribution in recurrent networks with functionally heterogeneous synaptic connectivity.

Communication Optimizations for Fine-Grained UPCApplications

Energy Technology Data Exchange (ETDEWEB)

Chen, Wei-Yu; Iancu, Costin; Yelick, Katherine

2005-07-08

Global address space languages like UPC exhibit high performance and portability on a broad class of shared and distributed memory parallel architectures. The most scalable applications use bulk memory copies rather than individual reads and writes to the shared space, but finer-grained sharing can be useful for scenarios such as dynamic load balancing, event signaling, and distributed hash tables. In this paper we present three optimization techniques for global address space programs with fine-grained communication: redundancy elimination, use of split-phase communication, and communication coalescing. Parallel UPC programs are analyzed using static single assignment form and a data flow graph, which are extended to handle the various shared and private pointer types that are available in UPC. The optimizations also take advantage of UPC's relaxed memory consistency model, which reduces the need for cross thread analysis. We demonstrate the effectiveness of the analysis and optimizations using several benchmarks, which were chosen to reflect the kinds of fine-grained, communication-intensive phases that exist in some larger applications. The optimizations show speedups of up to 70 percent on three parallel systems, which represent three different types of cluster network technologies.

Single grains, thermal histories, and the 40Ar/39Ar method

International Nuclear Information System (INIS)

Wright, Norrie

1989-01-01

A key part in unraveling the history of the physical evolution of the earth is knowledge of the earth's thermal history. 40 Ar/ 39 Ar step heating of mineral samples provides a means of defining a local thermal history. to do this accurately the challenge is to extract meaningful diffusion parameters from a mineral's Arrhenius plot. In the case of biotite single grains, where the laboratory release of argon is a complex process, this can be a difficult task. (12 refs., 5 figs.)

Reversal of asymmetry of X-ray peak profiles from individual grains during a strain path change

DEFF Research Database (Denmark)

Wejdemann, Christian; Lienert, U.; Pantleon, Wolfgang

2010-01-01

X-ray peak profiles are measured from individual bulk grains during tensile deformation. Two differently oriented copper samples pre-deformed in tension show the expected peak profile asymmetry caused by intra-grain stresses. One of the samples is oriented to achieve a significant change of the i......X-ray peak profiles are measured from individual bulk grains during tensile deformation. Two differently oriented copper samples pre-deformed in tension show the expected peak profile asymmetry caused by intra-grain stresses. One of the samples is oriented to achieve a significant change...

In situ grain fracture mechanics during uniaxial compaction of granular solids

Science.gov (United States)

Hurley, R. C.; Lind, J.; Pagan, D. C.; Akin, M. C.; Herbold, E. B.

2018-03-01

Grain fracture and crushing are known to influence the macroscopic mechanical behavior of granular materials and be influenced by factors such as grain composition, morphology, and microstructure. In this paper, we investigate grain fracture and crushing by combining synchrotron x-ray computed tomography and three-dimensional x-ray diffraction to study two granular samples undergoing uniaxial compaction. Our measurements provide details of grain kinematics, contacts, average intra-granular stresses, inter-particle forces, and intra-grain crystal and fracture plane orientations. Our analyses elucidate the complex nature of fracture and crushing, showing that: (1) the average stress states of grains prior to fracture vary widely in their relation to global and local trends; (2) fractured grains experience inter-particle forces and stored energies that are statistically higher than intact grains prior to fracture; (3) fracture plane orientations are primarily controlled by average intra-granular stress and contact fabric rather than the orientation of the crystal lattice; (4) the creation of new surfaces during fracture accounts for a very small portion of the energy dissipated during compaction; (5) mixing brittle and ductile grain materials alters the grain-scale fracture response. The results highlight an application of combined x-ray measurements for non-destructive in situ analysis of granular solids and provide details about grain fracture that have important implications for theory and modeling.

Preferred orientation of ettringite in concrete fractures

KAUST Repository

Wenk, Hans-Rudolf

2009-05-15

Sulfate attack and the accompanying crystallization of fibrous ettringite [Ca6Al2(OH)12(SO4) 3·26H2O] cause cracking and loss of strength in concrete structures. Hard synchrotron X-ray microdiffraction is used to quantify the orientation distribution of ettringite crystals. Diffraction images are analyzed using the Rietveld method to obtain information on textures. The analysis reveals that the c axes of the trigonal crystallites are preferentially oriented perpendicular to the fracture surfaces. By averaging single-crystal elastic properties over the orientation distribution, it is possible to estimate the elastic anisotropy of ettringite aggregates. © 2009 International Union of Crystallography.

Secondary recrystallization in non-sag W filament wires -- On the possible role of relative grain boundary character distribution

International Nuclear Information System (INIS)

Samajdar, I.; Watte, P.; Mertens, F.

1999-01-01

Non-Sag tungsten (W) wire is indispensable for the lighting industry. For the necessary creep resistance, large elongated grains are considered as the desired microstructure. These large grains are obtained by primary and secondary recrystallization. In the present study an effort has been made to characterize and to understand the origin of such large elongated grains. In secondary recrystallization, often called abnormal grain growth, a few of the grains grow massive. The mechanisms of normal and abnormal grain growth are essentially the same, involving high angle boundary migration and driven by the reduction of surface energy. The abnormal grain growth can be visualized as a growth advantage for a few of the grains or growth disadvantage for the majority. Such an advantage/disadvantage may be caused by (1) differences in grain size and/or (2) differences in grain boundary character distribution (GBCD). In other words, a grain may grow massive if it has large size and/or possibilities of more favorable (i.e., of higher mobility) grain boundaries with the matrix grains

Effect of noise-induced nucleation on grain size distribution studied via the phase-field crystal method

International Nuclear Information System (INIS)

Hubert, J; Cheng, M; Emmerich, H

2009-01-01

We contribute to the more detailed understanding of the phase-field crystal model recently developed by Elder et al (2002 Phys. Rev. Lett. 88 245701), by focusing on its noise term and examining its impact on the nucleation rate in a homogeneously solidifying system as well as on successively developing grain size distributions. In this context we show that principally the grain size decreases with increasing noise amplitude, resulting in both a smaller average grain size and a decreased maximum grain size. Despite this general tendency, which we interpret based on Panfilis and Filiponi (2000 J. Appl. Phys. 88 562), we can identify two different regimes in which nucleation and successive initial growth are governed by quite different mechanisms.

Improvement of corrosion resistance in austenitic stainless steel by grain boundary character distribution control

International Nuclear Information System (INIS)

Wang, Yun; Kaneda, Junya; Kasahara, Shigeki; Shigenaka, Naoto

2012-01-01

Strauss test, Coriou test and Huey test were conducted on a Type 316L austenitic stainless steel. Improvement in grain boundary corrosion resistance was verified after raising low Σ coincidence site lattice (CSL) grain boundary (GB) frequency by controlling grain boundary character distribution (GBCD). During crevice corrosion test under gamma-ray irradiation, initiation frequency of GB corrosion after GBCD controlled specimens decreased to 1/10 of GBCD uncontrolled counterpart along with lower depth of corrosion. Stress corrosion cracking (SCC) propagation rate of GBCD controlled specimen decreased to less than 1/2 of GBCD uncontrolled specimen in high temperature and high pressure water. Based on these results, we expect that GBCD control will improve corrosion resistance of austenitic material in a wide range of application and environment. (author)

Assessing the grain structure of highly X-ray absorbing metallic alloys

Energy Technology Data Exchange (ETDEWEB)

Bormann, Therese [Basel Univ. (Switzerland). Biomaterials Science Center; University of Applied Sciences Northwestern Switzerland, Muttenz (Switzerland). Inst. for Medical and Analytical Technologies; Beckmann, Felix [Helmholtz-Zentrum Geesthacht (Germany). Inst. of Materials Research; Schinhammer, Michael [Eidgenoessische Technische Hochschule (ETH), Zuerich (Switzerland). Dept. of Materials; Deyhle, Hans; Mueller, Bert [Basel Univ. (Switzerland). Biomaterials Science Center; Wild, Michael de [University of Applied Sciences Northwestern Switzerland, Muttenz (Switzerland). Inst. for Medical and Analytical Technologies

2014-07-15

Selective laser melting allows the fabrication of NiTi implants with pre-defined, complex shapes. The control of the process parameters regulates the arrangement of the granular microstructure of the NiTi alloy. We prepared specimens with elongated grains, which build a sound basis for diffraction contrast tomography experiments using synchrotron radiation and for electron backscatter diffraction measurements. Both approaches reveal the orientation and size of the individual grains within the specimen. Still, electron backscatter diffraction is confined to two-dimensional cross-sections while diffraction contrast tomography reveals these microstructural features in three dimensions. We demonstrate that the grains in the selective laser melted specimen, which are oriented along the building direction, do not exhibit a well-defined planar grain orientation but are twisted. These twisted grains give rise to diffraction spots observable for several degrees of specimen rotation simultaneously to the acquisition of tomography data. (orig.)

Orientation effect on recovery and recrystallization of cold rolled niobium single crystals

Energy Technology Data Exchange (ETDEWEB)

Srinivasan, R. [Center for Accelerated Maturation of Materials, Department of Materials Science and Engineering, Ohio State University, Columbus, OH 43210 (United States)], E-mail: rajagopalan.5@osu.edu; Viswanathan, G.B.; Levit, V.I.; Fraser, H.L. [Center for Accelerated Maturation of Materials, Department of Materials Science and Engineering, Ohio State University, Columbus, OH 43210 (United States)

2009-05-15

Single crystal sheets of niobium with initial orientations of (0 0 1) [11-bar0], (1 1 0) [11-bar 0] and (1 1 1) [11-bar0] were rolled at room temperature in the strain range of 25-50%. The deformed specimens were vacuum annealed at temperatures of 800 deg. C, 1000 deg. C, and 1200 deg. C for 3 h. TEM, SEM-OIM and optical microscopy revealed orientation stability in (0 0 1) and (1 1 0) rolled samples with no recrystallization observed after annealing. Samples rolled along (1 1 1) partially recrystallized after annealing at 1000 deg. C and 1200 deg. C. A relatively small increase was observed in hardness of (0 0 1) rolled crystals between 25% and 50% strain, implying low work hardening rates. (1 1 1) rolled samples showed higher hardening rates, and enhanced recovery in hardness values after annealing, due to partial recrystallization. Conditions have been identified for the deformation and annealing of niobium single crystals, enabling the preservation of single crystal structure and near-complete recovery of mechanical properties. A simple crystallographic model is proposed, giving an explanation for the observed orientation stability in (0 0 1) and (1 1 0) rolled samples, and the tendency towards instability and recrystallization in (1 1 1) rolled samples.

Influence of fibre distribution and grain size on the mechanical behaviour of friction stir processed Mg–C composites

Energy Technology Data Exchange (ETDEWEB)

Mertens, A., E-mail: anne.mertens@ulg.ac.be [Université de Liège, Faculty of Applied Science, A& M Department, Metallic Materials Science Unit (Belgium); Simar, A. [Université catholique de Louvain, Institute of Mechanics, Materials and Civil Engineering (Belgium); Adrien, J.; Maire, E. [Institut National des Sciences Appliquées de Lyon (INSA Lyon), MATEIS Laboratory (France); Montrieux, H.-M. [Université de Liège, Faculty of Applied Science, A& M Department, Metallic Materials Science Unit (Belgium); Delannay, F. [Université catholique de Louvain, Institute of Mechanics, Materials and Civil Engineering (Belgium); Lecomte-Beckers, J. [Université de Liège, Faculty of Applied Science, A& M Department, Metallic Materials Science Unit (Belgium)

2015-09-15

Short C fibres–Mg matrix composites have been produced by friction stir processing sandwiches made of a layer of C fabric stacked between two sheets of Mg alloy AZ31B or AZ91D. This novel processing technique can allow the easy production of large-scale metal matrix composites. The paper investigates the microstructure of FSPed C fibre–Mg composites in relation with the fragmentation of the C fibres during FSP and their influence on the tensile properties. 3D X-ray tomography reveals that the fibres orient like onion rings and are more or less fragmented depending on the local shear stress during the process. The fibre volume fraction can be increased from 2.3% to 7.1% by reducing the nugget volume, i.e. by using a higher advancing speed in AZ31B alloy or a stronger matrix alloy, like AZ91D alloy. A higher fibre volume fraction leads to a smaller grain size which brings about an increase of the composite yield strength by 15 to 25%. However, a higher fibre volume fraction also leads to a lower fracture strain. Fracture surface observations reveal that damage occurs by fibre/matrix decohesion along fibres oriented perpendicularly to the loading direction. - Graphical abstract: Display Omitted - Highlights: • C–Mg MMCs were produced by FSP sandwiches made of a C fabric between Mg sheets. • Fibre fragmentation and erosion is larger when the temperature reached during FSP is lower. • A lower advancing speed brings a lower fibre volume fraction and a lower grain size. • X-ray tomography reveals that fibres orient along the FSP material flow. • The fibres and grain size reduction increase the yield strength by 15 to 25%.

Preferential orientation relationships in Ca{sub 2}MnO{sub 4} Ruddlesden-Popper thin films

Energy Technology Data Exchange (ETDEWEB)

Lacotte, M.; David, A.; Prellier, W., E-mail: wilfrid.prellier@ensicaen.fr [Laboratoire CRISMAT, CNRS UMR 6508, ENSICAEN, Université de Basse-Normandie, 6 Bd Maréchal Juin, F-14050 Caen Cedex 4 (France); Rohrer, G. S.; Salvador, P. A. [Department of Materials Science and Engineering, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, Pennsylvania 15213 (United States)

2015-07-28

A high-throughput investigation of local epitaxy (called combinatorial substrate epitaxy) was carried out on Ca{sub 2}MnO{sub 4} Ruddlesden-Popper thin films of six thicknesses (from 20 to 400 nm), all deposited on isostructural polycrystalline Sr{sub 2}TiO{sub 4} substrates. Electron backscatter diffraction revealed grain-over-grain local epitaxial growth for all films, resulting in a single orientation relationship (OR) for each substrate-film grain pair. Two preferred epitaxial ORs accounted for more than 90% of all ORs on 300 different microcrystals, based on analyzing 50 grain pairs for each thickness. The unit cell over unit cell OR ([100][001]{sub film} ∥ [100][001]{sub substrate}, or OR1) accounted for approximately 30% of each film. The OR that accounted for 60% of each film ([100][001]{sub film} ∥ [100][010]{sub substrate}, or OR2) corresponds to a rotation from OR1 by 90° about the a-axis. OR2 is strongly favored for substrate orientations in the center of the stereographic triangle, and OR1 is observed for orientations very close to (001) or to those near the edge connecting (100) and (110). While OR1 should be lower in energy, the majority observation of OR2 implies kinetic hindrances decrease the frequency of OR1. Persistent grain over grain growth and the absence of variations of the OR frequencies with thickness implies that the growth competition is finished within the first few nm, and local epitaxy persists thereafter during growth.

Effects of arbuscular mycorrhizal fungi inoculation on carbon and nitrogen distribution and grain yield and nutritional quality in rice (Oryza sativa L.).

Science.gov (United States)

Zhang, Xue; Wang, Li; Ma, Fang; Yang, Jixian; Su, Meng

2017-07-01

The importance of arbuscular mycorrhizal fungi (AMF) for nutrient uptake and growth in rice has been widely recognized. However, little is known about the distribution of carbon (C) and nitrogen (N) in rice under AMF inoculation, which can affect grain yield and quality. This study was conducted to investigate the distribution of C and N within rice plants under AMF inoculation and the effects on grain yield and quality. AMF inoculation significantly increased N accumulation and distribution in vegetative tissues at tillering, and N translocation into seeds from heading to maturity. Consequently, AMF inoculation more strongly impacted the distribution of N than that of C in seeds, with significantly reduced C:N ratios and increased protein content (by 7.4%). Additionally, AMF inoculation significantly increased grain yield by 28.2% through increasing the grain:straw ratio by 18.4%. In addition, the roots of inoculated rice exhibited greater change in C distribution, with significantly higher C concentrations, C accumulations, and C:N ratios at tillering and maturity. AMF inoculation affected the distribution of N in seeds and C in roots. As such, AMF inoculation may be a potential method for improving grain yield and quality. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

Ferroelectric domain continuity over grain boundaries

DEFF Research Database (Denmark)

Mantri, Sukriti; Oddershede, Jette; Damjanovic, Dragan

2017-01-01

Formation and mobility of domain walls in ferroelectric materials is responsible for many of their electrical and mechanical properties. Domain wall continuity across grain boundaries has been observed since the 1950's and is speculated to affect the grain boundary-domain interactions, thereby...... impacting macroscopic ferroelectric properties in polycrystalline systems. However detailed studies of such correlated domain structures across grain boundaries are limited. In this work, we have developed the mathematical requirements for domain wall plane matching at grain boundaries of any given...... orientation. We have also incorporated the effect of grain boundary ferroelectric polarization charge created when any two domains meet at the grain boundary plane. The probability of domain wall continuity for three specific grain misorientations is studied. Use of this knowledge to optimize processing...

Microstructure and properties of laser clad coatings studied by orientation imaging microscopy

International Nuclear Information System (INIS)

Ocelik, V.; Furar, I.; De Hosson, J.Th.M.

2010-01-01

In this work orientation imaging microscopy (OIM), based on electron backscatter diffraction in scanning electron microscopy, was employed to examine in detail the relationship between laser cladding processing parameters and he properties and the microstructure of single and overlapping laser tracks. The study was performed on thick (∼1 mm) Co-based coatings prepared by 2 kW Nd:YAG laser cladding a 42CrMo4 steel substrate using different laser beam scanning speeds (1.0-15 mm s -1 ). It was found that the directional growth of individual primary grains led to the formation of a typical solidification fiber texture. The dependence of this texture on the processing speed and the shape of the solidification front were investigated in detail. Strong epitaxial growth of Co grains on austenitic steel substrate grains was found, which did not depend on the laser beam scanning velocity. During laser cladding a strong temperature gradient exists just below the coating-substrate interface that promotes the formation of a Greninger-Troiano orientation relationship between martensitic plates and the original austenitic grain inside the heat affected zone: {1 1 1} γ ∼ 1 o to {1 1 0} α and γ ∼ 2 o to α . Relatively drastic changes in grain size at the internal coating interfaces did not exhibit sharp changes in microhardness.

Advection-diffusion model for normal grain growth and the stagnation of normal grain growth in thin films

International Nuclear Information System (INIS)

Lou, C.

2002-01-01

An advection-diffusion model has been set up to describe normal grain growth. In this model grains are divided into different groups according to their topological classes (number of sides of a grain). Topological transformations are modelled by advective and diffusive flows governed by advective and diffusive coefficients respectively, which are assumed to be proportional to topological classes. The ordinary differential equations governing self-similar time-independent grain size distribution can be derived analytically from continuity equations. It is proved that the time-independent distributions obtained by solving the ordinary differential equations have the same form as the time-dependent distributions obtained by solving the continuity equations. The advection-diffusion model is extended to describe the stagnation of normal grain growth in thin films. Grain boundary grooving prevents grain boundaries from moving, and the correlation between neighbouring grains accelerates the stagnation of normal grain growth. After introducing grain boundary grooving and the correlation between neighbouring grains into the model, the grain size distribution is close to a lognormal distribution, which is usually found in experiments. A vertex computer simulation of normal grain growth has also been carried out to make a cross comparison with the advection-diffusion model. The result from the simulation did not verify the assumption that the advective and diffusive coefficients are proportional to topological classes. Instead, we have observed that topological transformations usually occur on certain topological classes. This suggests that the advection-diffusion model can be improved by making a more realistic assumption on topological transformations. (author)

Orientation relationship in Eurofer martensitic steels

International Nuclear Information System (INIS)

Barcelo, F.; De Carlan, Y.; Bechade, J.L.; Fournier, B.

2009-01-01

Both TEM and SEM/EBSD orientation measurements are carried out on a Eurofer97 martensitic steel. The influence of the prior austenitic grain size is studied using dedicated heat treatments. The intra laths misorientation is estimated by TEM. SEM/EBSD orientation mapping enable to study the actual orientation relationship (OR) between the parent austenitic phase and the martensitic phase. Neither the Nishiyama-Wasserman nor the Kurdjumov-Sachs OR is able to account for both the misorientation angle distributions, the pole figure and the misorientation axes measured. The mixed OR recently proposed by Gourgues et al. (Electron backscattering diffraction study of acicular ferrite, bainite, and martensite steel microstructures, Mater. Sci. Tech. 16 (2000), p. 26-40.) and Sonderegger et al. (Martensite laths in creep resistant martensitic 9-12% Cr steels - Calculation and measurement of misorientations, Mater. Characterization (2006), in Press.) seems to be able to account for most of these results. Based on this OR, a new angular criterion is proposed to detect blocks of laths. (authors)

Strain hardening behavior and microstructural evolution during plastic deformation of dual phase, non-grain oriented electrical and AISI 304 steels

Energy Technology Data Exchange (ETDEWEB)

Soares, Guilherme Corrêa; Gonzalez, Berenice Mendonça; Arruda Santos, Leandro de, E-mail: leandro.arruda@demet.ufmg.br

2017-01-27

Strain hardening behavior and microstructural evolution of non-grain oriented electrical, dual phase, and AISI 304 steels, subjected to uniaxial tensile tests, were investigated in this study. Tensile tests were performed at room temperature and the strain hardening behavior of the steels was characterized by three different parameters: modified Crussard–Jaoul stages, strain hardening rate and instantaneous strain hardening exponent. Optical microscopic analysis, X-ray diffraction measurements, phase quantification by Rietveld refinement and hardness tests were also carried out in order to correlate the microstructural and mechanical responses to plastic deformation. Distinct strain hardening stages were observed in the steels in terms of the instantaneous strain hardening exponent and the strain hardening rate. The dual phase and non-grain oriented steels exhibited a two-stage strain hardening behavior while the AISI 304 steel displayed multiple stages, resulting in a more complex strain hardening behavior. The dual phase steels showed a high work hardening capacity in stage 1, which was gradually reduced in stage 2. On the other hand, the AISI 304 steel showed high strain hardening capacity, which continued to increase up to the tensile strength. This is a consequence of its additional strain hardening mechanism, based on a strain-induced martensitic transformation, as shown by the X-ray diffraction and optical microscopic analyses.

Reconstruction of the domain orientation distribution function of polycrystalline PZT ceramics using vector piezoresponse force microscopy.

Science.gov (United States)

Kratzer, Markus; Lasnik, Michael; Röhrig, Sören; Teichert, Christian; Deluca, Marco

2018-01-11

Lead zirconate titanate (PZT) is one of the prominent materials used in polycrystalline piezoelectric devices. Since the ferroelectric domain orientation is the most important parameter affecting the electromechanical performance, analyzing the domain orientation distribution is of great importance for the development and understanding of improved piezoceramic devices. Here, vector piezoresponse force microscopy (vector-PFM) has been applied in order to reconstruct the ferroelectric domain orientation distribution function of polished sections of device-ready polycrystalline lead zirconate titanate (PZT) material. A measurement procedure and a computer program based on the software Mathematica have been developed to automatically evaluate the vector-PFM data for reconstructing the domain orientation function. The method is tested on differently in-plane and out-of-plane poled PZT samples, and the results reveal the expected domain patterns and allow determination of the polarization orientation distribution function at high accuracy.

Photoelectron angular distributions from strong-field ionization of oriented molecules

DEFF Research Database (Denmark)

Holmegaard, Lotte; Hansen, Jonas Lerche; Kalhøj, Line

2010-01-01

The combination of ultrafast light sources with detection of molecular-frame photoelectron angular distributions (MFPADs) is setting new standards for detailed interrogation of molecular dynamics. However, until recently measurement of MFPADs relied on determining the molecular orientation after...... ionization, which is limited to species and processes where ionization leads to fragmentation. An alternative is to fix the molecular frame before ionization. The only demonstrations of such spatial orientation involved aligned small linear nonpolar molecules. Here we extend these techniques to the general...... class of polar molecules. Carbonylsulphide and benzonitrile molecules, fixed in space by combined laser and electrostatic fields, are ionized with intense, circularly polarized 30-fs laser pulses. For carbonylsulphide and benzonitrile oriented in one dimension, the MFPADs exhibit pronounced anisotropies...

Coarse-grain parallelism using remote method invocation

Energy Technology Data Exchange (ETDEWEB)

Hebert, A. [Ecole Polytechnique de Montreal, Qc. (Canada)

2003-07-01

The paper describes a user-oriented framework specifically designed to facilitate the development and supervision of coarse-grain parallel applications in reactor physics. The proposed user-oriented framework was designed and implemented in Java, in such a way to obtain a simple and robust application. The proposed approach is based on Java Native Interface(JNI) for integrating the Fortran legacy code and on Remote Method Invocation (RMI) for distributing the calculation load over the farm of processors. Dynamic code downloading over the network is possible. We are presenting the application of this approach to supervision of lattice calculations using the open source Dragon code. The Java layer surrounding Dragon can also be used to construct execution procedures, computational schemes and graphical user interfaces. This approach can be used with any existing legacy Fortran code, as soon as its input/output data structures are Dragon-compatible. (author)

Coarse-grain parallelism using remote method invocation

International Nuclear Information System (INIS)

Hebert, A.

2003-01-01

The paper describes a user-oriented framework specifically designed to facilitate the development and supervision of coarse-grain parallel applications in reactor physics. The proposed user-oriented framework was designed and implemented in Java, in such a way to obtain a simple and robust application. The proposed approach is based on Java Native Interface(JNI) for integrating the Fortran legacy code and on Remote Method Invocation (RMI) for distributing the calculation load over the farm of processors. Dynamic code downloading over the network is possible. We are presenting the application of this approach to supervision of lattice calculations using the open source Dragon code. The Java layer surrounding Dragon can also be used to construct execution procedures, computational schemes and graphical user interfaces. This approach can be used with any existing legacy Fortran code, as soon as its input/output data structures are Dragon-compatible. (author)

Investigation on magnetic properties of orientated nanocomposite Pr2Fe14B/α-Fe permanent magnets by micromagnetic finite-element method

International Nuclear Information System (INIS)

He, Shu-li; Zhang, Hong-wei; Rong, Chuan-bing; Chen, Juan; Sun, Ji-rong; Shen, Bao-gen

2012-01-01

Demagnetization curves for nanocomposite Pr 2 Fe 14 B/α-Fe permanent magnets with different hard grain alignment are calculated by a micromagnetic finite-element method. The results show that both remanence and coercivity increase with improving hard grains alignment. The demagnetization curves show a single-phase demagnetization behavior for the samples with grain size d of 10 nm and two-phase behavior for the samples with d of 20 and 30 nm. H ex (reflecting the magnetic hardening of α-Fe) and H irr (expressing the irreversible reversal of hard phase) are both enhanced with improving the hard grain alignment. The magnetic reversal in orientated nanocomposite permanent magnets is mainly controlled by inhomogeneous pinning of the nucleated type. - Highlights: ► The magnetic properties of nanocomposite Pr 2 Fe 14 B/α-Fe permanent magnets with different hard grains alignment are investigated by micromagnetic finite-element method. ► The calculated results show that both remanence and coercivity increase with improving hard grains alignment. ► Highly ordered orientation of hard phase is the critical factor to improve the properties of nanocomposites.

Microstructure, microtexture and precipitation in the ultrafine-grained surface layer of an Al-Zn-Mg-Cu alloy processed by sliding friction treatment

Energy Technology Data Exchange (ETDEWEB)

Chen, Yanxia [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi' an 710072 (China); Yang, Yanqing, E-mail: yqyang@nwpu.edu.cn [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi' an 710072 (China); Feng, Zongqiang [College of Materials Science and Engineering, Chongqing University, Chongqing 400044 (China); Zhao, Guangming; Huang, Bin; Luo, Xian [State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi' an 710072 (China); Zhang, Yusheng; Zhang, Wei [Northwest Institute for Nonferrous Metal Research, Xi' an 710016 (China)

2017-01-15

Precipitate redistribution and texture evolution are usually two concurrent aspects accompanying grain refinement induced by various surface treatment. However, the detailed precipitate redistribution characteristics and process, as well as crystallographic texture in the surface refined grain layer, are still far from full understanding. In this study, we focused on the microstructural and crystallographic features of the sliding friction treatment (SFT) induced surface deformation layer in a 7050 aluminum alloy. With the combination of transmission electron microscopy (TEM) and high angle angular dark field scanning TEM (HAADF-STEM) observations, a surface ultrafine grain (UFG) layer composed of both equiaxed and lamellar ultrafine grains and decorated by high density of coarse grain boundary precipitates (GBPs) were revealed. Further precession electron diffraction (PED) assisted orientation mapping unraveled that high angle grain boundaries rather than low angle grain boundaries are the most favorable nucleation sites for GBPs. The prominent precipitate redistribution can be divided into three successive and interrelated stages, i.e. the mechanically induced precipitate dissolution, solute diffusion and reprecipitation. The quantitative prediction based on pipe diffusion along dislocations and grain boundary diffusion proved the distribution feasibility of GBPs around UFGs. Based on PED and electron backscatter diffraction (EBSD) analyses, the crystallographic texture of the surface UFG layer was identified as a shear texture composed of major rotated cube texture (001) 〈110〉 and minor (111) 〈112〉, while that of the adjoining lamellar coarse grained matrix was pure brass. The SFT induced surface severe shear deformation is responsible for texture evolution. - Highlights: •The surface ultrafine grain layer in a 7050 aluminum alloy was focused. •Precipitate redistribution and texture evolution were discussed. •The quantitative prediction proved the

Giant strain with ultra-low hysteresis and high temperature stability in grain oriented lead-free K0.5Bi0.5TiO3-BaTiO3-Na0.5Bi0.5TiO3 piezoelectric materials.

Science.gov (United States)

Maurya, Deepam; Zhou, Yuan; Wang, Yaojin; Yan, Yongke; Li, Jiefang; Viehland, Dwight; Priya, Shashank

2015-02-26

We synthesized grain-oriented lead-free piezoelectric materials in (K0.5Bi0.5TiO3-BaTiO3-xNa0.5Bi0.5TiO3 (KBT-BT-NBT) system with high degree of texturing along the [001]c (c-cubic) crystallographic orientation. We demonstrate giant field induced strain (~0.48%) with an ultra-low hysteresis along with enhanced piezoelectric response (d33 ~ 190pC/N) and high temperature stability (~160°C). Transmission electron microscopy (TEM) and piezoresponse force microscopy (PFM) results demonstrate smaller size highly ordered domain structure in grain-oriented specimen relative to the conventional polycrystalline ceramics. The grain oriented specimens exhibited a high degree of non-180° domain switching, in comparison to the randomly axed ones. These results indicate the effective solution to the lead-free piezoelectric materials.

Microscopic determination of the PuO2 grain size and pore size distribution of MOX pellets with an image analysis system

International Nuclear Information System (INIS)

Vandezande, J.

2000-01-01

The industrial way to obtain the Pu distribution in a MOX pellet is by Image Analysis. The PuO 2 grains are made visible by alpha-autoradiography. Along with the Pu distribution the pore structure is an item which is examined, the latter is determined on the unetched sample. After the visualization of the sample structure, the sample is evaluated with an Image Analysis System. Each image is enhanced and a distinction is made between the objects to be measured and the matrix. The relevant parameters are then analyzed. When the overall particle distribution is wanted, all identified particles are measured and classified in size groups, based on a logarithmic scale. The possible conversion of two-dimensional diameters to three-dimensional diameters is accomplished by application of the Saltykov algorithm. When a single object is of interest, the object is selected interactively, and the result is reported to the user. (author)

The influence of slow cooling on Y211 size and content in single-grain YBCO bulk superconductor through the infiltration-growth process

Energy Technology Data Exchange (ETDEWEB)

Ouerghi, A [Systems and Applied Mechanics Laboratory LASMAP, Polytechnic School of Tunisia, Rue El Kawarezmi La Marsa 743, Université de Carthage Tunis (Tunisia); Moutalbi, N., E-mail: nahed.moutalbi@yahoo.fr [Systems and Applied Mechanics Laboratory LASMAP, Polytechnic School of Tunisia, Rue El Kawarezmi La Marsa 743, Université de Carthage Tunis (Tunisia); Noudem, J.G. [CRISMAT-ENSICAEN (UMR-CNRS 6508), Université de Caen-Basse-Normandie, F-14050 Caen (France); LUSAC, Université de Caen-Basse-Normandie F-50130 Cherbourg-Octeville (France); M' chirgui, A. [Systems and Applied Mechanics Laboratory LASMAP, Polytechnic School of Tunisia, Rue El Kawarezmi La Marsa 743, Université de Carthage Tunis (Tunisia)

2017-03-15

Highlights: • YBCO bulk superconductors are produced by optimized Seeded Infiltration and Growth process. • The slow cooling time, in a fixed slow cooling temperature window, affects considerably the surface morphology and the bulk’s microstructure. • The Y211 particle’s size and content depend on the slow cooling time and its distribution behavior changes from one position to another. • There is an optimum slow cooling time, estimated to 88h, over which the shrinkage for both the liquid phase and the Y211 pellet is maximal, without any improvement of the crystal grain growth. • The magnetic trapped flux distribution for a given sample brings out the single grain characteristic. - Abstract: Highly textured YBa{sub 2}Cu{sub 3}O{sub 7-δ} (Y123) superconductors were produced using modified Textured Top Seeded Infiltration Growth (TSIG) process. The liquid source is made of only Y123 powder whereas the solid source is composed of Y{sub 2}BaCuO{sub 5} (Y211) powder. We aim to control the amount of liquid that infiltrates the solid pellet, which in turn controls the final amount of Y{sub 2}BaCuO{sub 5} particles in Y123 matrix. The effect of the slow cooling kinetics on sample morphology, on grain growth and on final microstructure was too investigated. It is shown that appropriate slow cooling time may also contribute to the control of the amount of Y211 inclusions in the final structure of Y123 bulk. We report herein the Y211 particle size and density distribution in the whole Y123 matrix. The present work proves that finest Y211 particles locate under the seed and that their size and density increase with distance from the seed.

A combined experimental and computational study of deformation in grains of biomedical grade 316LVM stainless steel

International Nuclear Information System (INIS)

You, X.; Connolley, T.; McHugh, P.E.; Cuddy, H.; Motz, C.

2006-01-01

In this work three-dimensional crystal plasticity finite element models are used to simulate the tensile deformation of a thin 316LVM stainless steel specimen. Such models are of interest for predicting the mechanical response of cardiovascular stents, typically made from thin struts of this material. Detailed experimental analysis of the mechanical response of the specimen during deformation is performed using scanning electron microscopy, digital photogrammetry and orientation imaging microscopy to examine microscale strain distribution, plastic slip and grain reorientation. At the macroscale, the models are found to give good predictions of the stress-strain response of the specimen, and at the microscale the models are found to give good predictions of the strain distribution and the active slip systems in the different grains. The models are less successful in predicting grain reorientations. This, however, is shown to be quite sensitive to the choice of latent hardening ratio

A combined experimental and computational study of deformation in grains of biomedical grade 316LVM stainless steel

Energy Technology Data Exchange (ETDEWEB)

You, X. [National Centre for Biomedical Engineering Science, National University of Ireland, Galway (Ireland); Connolley, T. [National Centre for Biomedical Engineering Science, National University of Ireland, Galway (Ireland); McHugh, P.E. [National Centre for Biomedical Engineering Science, National University of Ireland, Galway (Ireland) and Department of Mechanical and Biomedical Engineering, National University of Ireland, University Road, Galway (Ireland)]. E-mail: peter.mchugh@nuigalway.ie; Cuddy, H. [National Centre for Biomedical Engineering Science, National University of Ireland, Galway (Ireland); Motz, C. [Erich Schmid Institute, Austrian Academy of Sciences, Jahnstrasse 12, A-8700 Leoben (Austria)

2006-10-15

In this work three-dimensional crystal plasticity finite element models are used to simulate the tensile deformation of a thin 316LVM stainless steel specimen. Such models are of interest for predicting the mechanical response of cardiovascular stents, typically made from thin struts of this material. Detailed experimental analysis of the mechanical response of the specimen during deformation is performed using scanning electron microscopy, digital photogrammetry and orientation imaging microscopy to examine microscale strain distribution, plastic slip and grain reorientation. At the macroscale, the models are found to give good predictions of the stress-strain response of the specimen, and at the microscale the models are found to give good predictions of the strain distribution and the active slip systems in the different grains. The models are less successful in predicting grain reorientations. This, however, is shown to be quite sensitive to the choice of latent hardening ratio.

Investigation on orientation, epitaxial growth and microstructure of a-axis-, c-axis-, (103)/(110)- and (113)-oriented YBa2Cu3O7-δ films prepared on (001), (110) and (111) SrTiO3 single crystal substrates by spray atomizing and coprecipitating laser chemical vapor deposition

Science.gov (United States)

Zhao, Pei; Wang, Ying; Huang, Zhi liang; Mao, Yangwu; Xu, Yuan Lai

2015-04-01

a-axis-, c-axis-, (103)/(110)- and (113)-oriented YBa2Cu3O7-δ (YBCO) films were pareared by spray atomizing and coprecipitating laser chemical vapor deposition. The surface of the a-axis-oriented YBCO film consisted of rectangular needle-like grains whose in-plane epitaxial growth relationship was YBCO [100] // STO [001] (YBCO [001] // STO [100]), and that of the c-axis-oriented YBCO film consisted of dense flat surface with epitaxial growth relationship of YBCO [001] // STO [001] (YBCO [100] //STO [100]). For the (103)/(110)-oriented and (113)-oriented YBCO film, they showed wedge-shaped and triangle-shaped grains, with corresponding in-plane epitaxial growth relationship of YBCO [110] // STO [110] (YBCO [010] // STO [010]) and YBCO [100] // STO [100] (YBCO [113] // STO [111], respectively.

Polycrystal deformation and single crystal deformation: Dislocation structure and flow stress in copper

DEFF Research Database (Denmark)

Huang, X.; Borrego, A.; Pantleon, W.

2001-01-01

of microstructures have been identified. A correlation is found between microstructure and grain orientation, which agrees well with earlier observations in tensile deformed aluminum polycrystals and copper single crystals. The stress–strain curve of the copper polycrystal is calculated with good accuracy from...

Magnetic losses reduction in grain oriented silicon steel by pulse and continuous fiber laser processing

Science.gov (United States)

Petryshynets, Ivan; Kováč, František; Puchý, Viktor; Šebek, Martin; Füzer, Ján; Kollár, Peter

2018-04-01

The present paper shows the impact of different laser scribing conditions on possible reduction of magnetic losses in grain oriented electrical steel sheets. The experimental Fe-3%Si steel was taken from industrial line after final box annealing. The surface of investigated steel was subjected to fiber laser processing using both pulse and continuous scribing regimes in order to generate residual thermal stresses inducing the magnetic domains structure refinement. The magnetic losses of experimental samples before and after individual laser scribing regimes were tested in AC magnetic field with 50Hz frequency and induction of 1.5T. The most significant magnetic losses reduction of 38% was obtained at optimized conditions of continuous laser scribing regime. A semi quantitative relationship has been found between the domain patterns and the used fiber laser processing.

Microstructure and crystallographic preferred orientation of polycrystalline microgarnet aggregates developed during progressive creep, recovery, and grain boundary sliding

Science.gov (United States)

Massey, M.A.; Prior, D.J.; Moecher, D.P.

2011-01-01

Optical microscopy, electron probe microanalysis, and electron backscatter diffraction methods have been used to examine a broad range of garnet microstructures within a high strain zone that marks the western margin of a major transpression zone in the southern New England Appalachians. Garnet accommodated variable states of finite strain, expressed as low strain porphyroclasts (Type 1), high strain polycrystalline aggregates (Type 2), and transitional morphologies (Type 3) that range between these end members. Type 1 behaved as rigid porphyroclasts and is characterized by four concentric Ca growth zones. Type 2 help define foliation and lineation, are characterized by three Ca zones, and possess a consistent bulk crystallographic preferred orientation of (100) symmetrical to the tectonic fabric. Type 3 show variable degrees of porphyroclast associated with aggregate, where porphyroclasts display complex compositional zoning that corresponds to lattice distortion, low-angle boundaries, and subgrains, and aggregate CPO mimics porphyroclast orientation. All aggregates accommodated a significant proportion of greenschist facies deformation through grain boundary sliding, grain rotation and impingement, and pressure solution, which lead to a cohesive behavior and overall strain hardening of the aggregates. The characteristic CPO could not have been developed in this manner, and was the result of an older phase of partitioned amphibolite facies dislocation creep, recovery including chemical segregation, and recrystallization of porphyroclasts. This study demonstrates the significance of strain accommodation within garnet and its affect on composition under a range of PT conditions, and emphasizes the importance of utilizing EBSD methods with studies that rely upon a sound understanding of garnet. ?? 2010 Elsevier Ltd.

Woodland Mapping at Single-Tree Levels Using Object-Oriented Classification of Unmanned Aerial Vehicle (uav) Images

Science.gov (United States)

Chenari, A.; Erfanifard, Y.; Dehghani, M.; Pourghasemi, H. R.

2017-09-01

Remotely sensed datasets offer a reliable means to precisely estimate biophysical characteristics of individual species sparsely distributed in open woodlands. Moreover, object-oriented classification has exhibited significant advantages over different classification methods for delineation of tree crowns and recognition of species in various types of ecosystems. However, it still is unclear if this widely-used classification method can have its advantages on unmanned aerial vehicle (UAV) digital images for mapping vegetation cover at single-tree levels. In this study, UAV orthoimagery was classified using object-oriented classification method for mapping a part of wild pistachio nature reserve in Zagros open woodlands, Fars Province, Iran. This research focused on recognizing two main species of the study area (i.e., wild pistachio and wild almond) and estimating their mean crown area. The orthoimage of study area was consisted of 1,076 images with spatial resolution of 3.47 cm which was georeferenced using 12 ground control points (RMSE=8 cm) gathered by real-time kinematic (RTK) method. The results showed that the UAV orthoimagery classified by object-oriented method efficiently estimated mean crown area of wild pistachios (52.09±24.67 m2) and wild almonds (3.97±1.69 m2) with no significant difference with their observed values (α=0.05). In addition, the results showed that wild pistachios (accuracy of 0.90 and precision of 0.92) and wild almonds (accuracy of 0.90 and precision of 0.89) were well recognized by image segmentation. In general, we concluded that UAV orthoimagery can efficiently produce precise biophysical data of vegetation stands at single-tree levels, which therefore is suitable for assessment and monitoring open woodlands.

Impact of the Crystallite Orientation Distribution on Exciton Transport in Donor–Acceptor Conjugated Polymers

KAUST Repository

Ayzner, Alexander L.; Mei, Jianguo; Appleton, Anthony; DeLongchamp, Dean; Nardes, Alexandre; Benight, Stephanie; Kopidakis, Nikos; Toney, Michael F.; Bao, Zhenan

2015-01-01

© 2015 American Chemical Society. Conjugated polymers are widely used materials in organic photovoltaic devices. Owing to their extended electronic wave functions, they often form semicrystalline thin films. In this work, we aim to understand whether distribution of crystallographic orientations affects exciton diffusion using a low-band-gap polymer backbone motif that is representative of the donor/acceptor copolymer class. Using the fact that the polymer side chain can tune the dominant crystallographic orientation in the thin film, we have measured the quenching of polymer photoluminescence, and thus the extent of exciton dissociation, as a function of crystal orientation with respect to a quenching substrate. We find that the crystallite orientation distribution has little effect on the average exciton diffusion length. We suggest several possibilities for the lack of correlation between crystallographic texture and exciton transport in semicrystalline conjugated polymer films.

Impact of the Crystallite Orientation Distribution on Exciton Transport in Donor–Acceptor Conjugated Polymers

KAUST Repository

Ayzner, Alexander L.

2015-12-30

© 2015 American Chemical Society. Conjugated polymers are widely used materials in organic photovoltaic devices. Owing to their extended electronic wave functions, they often form semicrystalline thin films. In this work, we aim to understand whether distribution of crystallographic orientations affects exciton diffusion using a low-band-gap polymer backbone motif that is representative of the donor/acceptor copolymer class. Using the fact that the polymer side chain can tune the dominant crystallographic orientation in the thin film, we have measured the quenching of polymer photoluminescence, and thus the extent of exciton dissociation, as a function of crystal orientation with respect to a quenching substrate. We find that the crystallite orientation distribution has little effect on the average exciton diffusion length. We suggest several possibilities for the lack of correlation between crystallographic texture and exciton transport in semicrystalline conjugated polymer films.