WorldWideScience

Sample records for shoot internal co2

  1. The oil market and international agreements on CO2 emissions

    International Nuclear Information System (INIS)

    Berger, K.; Fimreite, O.; Golombek, R.; Hoel, M.

    1992-01-01

    According to most scientists, greenhouse gas emissions must be reduced significantly relative to current trends to avoid dramatic adverse climatic changes during the next century. CO 2 is the most important greenhouse gas, so any international agreement will certainly cover CO 2 emissions. Any international agreement to reduce emissions of CO 2 is going to have a significant impact on the markets for fossil fuels. The analysis shows that it is not only the amount of CO 2 emissions permitted in an agreement which matters for fossil fuel prices, but also the type of agreement. Two obvious forms of agreements, which under certain assumptions both are cost efficient, are (a) tradeable emission permits, and (b) an international CO 2 tax. If the fossil fuel markets were perfectly competitive, these two types of agreements would have the same effect on the producer price of fossil fuels. However, fossil fuel markets are not completely competitive. It is shown that, under imperfect competition, direct regulation of the 'tradeable quotas' type tends to imply higher producer prices and a larger efficiency loss than an international CO 2 tax giving the same total CO 2 emissions. A numerical illustration of the oil market indicates that the difference in producer prices for the two types of CO 2 agreements is quite significant. 6 refs., 2 figs., 2 tabs

  2. The oil market and international agreements on CO2 emissions

    International Nuclear Information System (INIS)

    Berger, K.; Fimreite, Oe.; Golombek, R.; Hoel, M.

    1991-01-01

    In order to avoid a relatively large risk of dramatic adverse climatic changes during the next century, greenhouse gas emissions must be reduced significantly relative to present emissions. CO 2 is the most important greenhouse gas, so any international agreement will certainly cover CO 2 emissions. Any international agreement to reduce emissions of CO 2 is going to have a significant impact on the markets for fossil fuels. The analysis shows that is not only the amount of CO 2 emissions permitted in an agreement which matters for fossil fuel prices, but also the type of agreement. Two obvious forms of agreements, which under certain assumptions both are cost efficient, are (a) tradeable emission permits, and (b) an international CO 2 tax. If the fossil fuel markets were perfectly competitive, these two types of agreements would have the same effect on the producer price of fossil fuels. However, fossil fuel markets are not completely competitive. It is shown that, under imperfect competition, direct regulation of the ''tradeable quotas'' type tends to imply higher producer prices than an international CO 2 tax giving the same total CO 2 emissions. A numerical illustration of the oil market indicates that the difference in producer prices for the two types of CO 2 agreements is quite significant. 6 refs., 2 figs., 1 tab

  3. International Collaboration on CO2 Sequestration

    Energy Technology Data Exchange (ETDEWEB)

    Peter H. Israelsson; E. Eric Adams

    2007-06-30

    On December 4, 1997, the US Department of Energy (USDOE), the New Energy and Industrial Technology Development Organization of Japan (NEDO), and the Norwegian Research Council (NRC) entered into a Project Agreement for International Collaboration on CO{sub 2} Ocean Sequestration. Government organizations from Japan, Canada, and Australia, and a Swiss/Swedish engineering firm later joined the agreement, which outlined a research strategy for ocean carbon sequestration via direct injection. The members agreed to an initial field experiment, with the hope that if the initial experiment was successful, there would be subsequent field evaluations of increasingly larger scale to evaluate environmental impacts of sequestration and the potential for commercialization. The evolution of the collaborative effort, the supporting research, and results for the International Collaboration on CO{sub 2} Ocean Sequestration were documented in almost 100 papers and reports, including 18 peer-reviewed journal articles, 46 papers, 28 reports, and 4 graduate theses. These efforts were summarized in our project report issued January 2005 and covering the period August 23, 1998-October 23, 2004. An accompanying CD contained electronic copies of all the papers and reports. This report focuses on results of a two-year sub-task to update an environmental assessment of acute marine impacts resulting from direct ocean sequestration. The approach is based on the work of Auerbach et al. [6] and Caulfield et al. [20] to assess mortality to zooplankton, but uses updated information concerning bioassays, an updated modeling approach and three modified injection scenarios: a point release of negatively buoyant solid CO{sub 2} hydrate particles from a moving ship; a long, bottom-mounted diffuser discharging buoyant liquid CO{sub 2} droplets; and a stationary point release of hydrate particles forming a sinking plume. Results suggest that in particular the first two discharge modes could be

  4. CO2 emissions embodied in international trade: evidence for Spain

    International Nuclear Information System (INIS)

    Sanchez-Choliz, Julio; Duarte, Rosa

    2004-01-01

    The objective of this paper is to analyse the sectoral impacts that Spanish international trade relations have on present levels of atmospheric pollution using an input-output model. We try to evaluate the exports and imports of the Spanish economy in terms of the direct and indirect CO 2 emissions (CO 2 embodied) generated in Spain and abroad. The results show a slightly exporting behaviour in the Spanish economy which, nevertheless, hides important pollution interchanges. Moreover, the sectors transport material, mining and energy, non-metallic industries, chemical and metals are the most relevant CO 2 exporters and other services, construction, transport material and food the biggest CO 2 importers, and those whose final demands also embody more than 70% of the CO 2 emissions

  5. CO2 on the International Space Station: An Operations Update

    Science.gov (United States)

    Law, Jennifer; Alexander, David

    2016-01-01

    PROBLEM STATEMENT: We describe CO2 symptoms that have been reported recently by crewmembers on the International Space Station and our continuing efforts to control CO2 to lower levels than historically accepted. BACKGROUND: Throughout the International Space Station (ISS) program, anecdotal reports have suggested that crewmembers develop CO2-related symptoms at lower CO2 levels than would be expected terrestrially. Since 2010, operational limits have controlled the 24-hour average CO2 to 4.0 mm Hg, or below as driven by crew symptomatology. In recent years, largely due to increasing awareness by crew and ground team, there have been increased reports of crew symptoms. The aim of this presentation is to discuss recent observations and operational impacts to lower CO2 levels on the ISS. CASE PRESENTATION: Crewmembers are routinely asked about CO2 symptoms in their weekly private medical conferences with their crew surgeons. In recent ISS expeditions, crewmembers have noted symptoms attributable to CO2 starting at 2.3 mmHg. Between 2.3 - 2.7 mm Hg, fatigue and full-headedness have been reported. Between 2.7 - 3.0 mm Hg, there have been self-reports of procedure missed steps or procedures going long. Above 3.0 - 3.4 mm Hg, headaches have been reported. A wide range of inter- and intra-individual variability in sensitivity to CO2 have been noted. OPERATIONAL / CLINICAL RELEVANCE: These preliminary data provide semi-quantitative ranges that have been used to inform a new operational limit of 3.0 mmHg as a compromise between systems capabilities and the recognition that there are human health and performance impacts at recent ISS CO2 levels. Current evidence would suggest that an operational limit between 0.5 and 2.0 mm Hg may maintain health and performance. Future work is needed to establish long-term ISS and future vehicle operational limits.

  6. CO2 enrichment inhibits shoot nitrate assimilation in C3 but not C4 plants and slows growth under nitrate in C3 plants.

    Science.gov (United States)

    Bloom, Arnold J; Asensio, Jose Salvador Rubaio; Randall, Lesley; Rachmilevitch, Shimon; Cousins, Asaph B; Carlisle, Eli A

    2012-02-01

    The CO2 concentration in Earth's atmosphere may double during this century. Plant responses to such an increase depend strongly on their nitrogen status, but the reasons have been uncertain. Here, we assessed shoot nitrate assimilation into amino acids via the shift in shoot CO2 and O2 fluxes when plants received nitrate instead of ammonium as a nitrogen source (deltaAQ). Shoot nitrate assimilation became negligible with increasing CO2 in a taxonomically diverse group of eight C3 plant species, was relatively insensitive to CO2 in three C4 species, and showed an intermediate sensitivity in two C3-C4 intermediate species. We then examined the influence of CO2 level and ammonium vs. nitrate nutrition on growth, assessed in terms of changes in fresh mass, of several C3 species and a Crassulacean acid metabolism (CAM) species. Elevated CO2 (720 micromol CO2/mol of all gases present) stimulated growth or had no effect in the five C3 species tested when they received ammonium as a nitrogen source but inhibited growth or had no effect if they received nitrate. Under nitrate, two C3 species grew faster at sub-ambient (approximately 310 micromol/mol) than elevated CO2. A CAM species grew faster at ambient than elevated or sub-ambient CO2 under either ammonium or nitrate nutrition. This study establishes that CO2 enrichment inhibits shoot nitrate assimilation in a wide variety of C3 plants and that this phenomenon can have a profound effect on their growth. This indicates that shoot nitrate assimilation provides an important contribution to the nitrate assimilation of an entire C3 plant. Thus, rising CO2 and its effects on shoot nitrate assimilation may influence the distribution of C3 plant species.

  7. Possibility of reducing CO2 emissions from internal combustion engines

    Science.gov (United States)

    Drabik, Dawid; Mamala, Jarosław; Śmieja, Michał; Prażnowski, Krzysztof

    2017-10-01

    Article defines on the possibility of reduction CO2 of the internal combustion engine and presents the analysis based on originally conducted studies. The increase in overall engine efficiency is sought after by all engineers dealing with engine construction, one of the major ways to reduce CO2 emissions is to increase the compression ratio. The application of the compression ratio that has been increased constructional in the engine will, on one hand, bring about the increase in the theoretical efficiency, but, on the other hand, require a system for pressure control at a higher engine load in order to prevent engine knocking. For the purposes of the article there was carried out a number of studies and compiled results, and on their basis determined what have a major impact on the reducing CO2.

  8. Increase in the activity of fructose-1,6-bisphosphatase in cytosol affects sugar partitioning and increases the lateral shoots in tobacco plants at elevated CO2 levels.

    Science.gov (United States)

    Tamoi, Masahiro; Hiramatsu, Yoshie; Nedachi, Shigeki; Otori, Kumi; Tanabe, Noriaki; Maruta, Takanori; Shigeoka, Shigeru

    2011-05-01

    We generated transgenic tobacco plants with high levels of fructose-1,6-bisphosphatase expressing cyanobacterialfructose-1,6-/sedoheptulose-1,7-bisphosphatase in the cytosol. At ambient CO(2) levels (360 ppm), growth, photosynthetic activity, and fresh weight were unchanged but the sucrose/hexose/starch ratio was slightly altered in the transgenic plants compared with wild-type plants. At elevated CO(2) levels (1200 ppm), lateral shoot, leaf number, and fresh weight were significantly increased in the transgenic plants. Photosynthetic activity was also increased. Hexose accumulated in the upper leaves in the wild-type plants, while sucrose and starch accumulated in the lower leaves and lateral shoots in the transgenic plants. These findings suggest that cytosolic fructose-1,6-bisphosphatase contributes to the efficient conversion of hexose into sucrose, and that the change in carbon partitioning affects photosynthetic capacity and morphogenesis at elevated CO(2) levels.

  9. Carbon dioxide exchange of buds and developing shoots of boreal Norway spruce exposed to elevated or ambient CO2 concentration and temperature in whole-tree chambers.

    Science.gov (United States)

    Hall, Marianne; Räntfors, Mats; Slaney, Michelle; Linder, Sune; Wallin, Göran

    2009-04-01

    Effects of ambient and elevated temperature and atmospheric carbon dioxide concentration ([CO2]) on CO2 assimilation rate and the structural and phenological development of shoots during their first growing season were studied in 45-year-old Norway spruce trees (Picea abies (L.) Karst.) enclosed in whole-tree chambers. Continuous measurements of net assimilation rate (NAR) in individual buds and shoots were made from early bud development to late August in two consecutive years. The largest effect of elevated temperature (TE) was manifest early in the season as an earlier start and completion of shoot length development, and a 1-3-week earlier shift from negative to positive NAR compared with the ambient temperature (TA) treatments. The largest effect of elevated [CO2] (CE) was found later in the season, with a 30% increase in maximum NAR compared with trees in the ambient [CO2] treatments (CA), and shoots assimilating their own mass in terms of carbon earlier in the CE treatments than in the CA treatments. Once the net carbon assimilation compensation point (NACP) had been reached, TE had little or no effect on the development of NAR performance, whereas CE had little effect before the NACP. No interactive effects of TE and CE on NAR were found. We conclude that in a climate predicted for northern Sweden in 2100, current-year shoots of P. abies will assimilate their own mass in terms of carbon 20-30 days earlier compared with the current climate, and thereby significantly contribute to canopy assimilation during their first year.

  10. The urgent need to internalize CO2 emission costs

    International Nuclear Information System (INIS)

    Goodland, R.; El Serafy, S.

    1998-01-01

    Despite growing manifestations of global warming and the commitment of most nations to move towards reducing greenhouse gas (GHG) emissions, a simple device that can be effective in reducing GHG emissions continues to be overlooked or even rejected. This is to acknowledge the fact that carbon emissions inflict global costs that are not borne by emitters. This paper advocates that all activities emitting or saving carbon emissions should internalize the carbon cost inflicted or avoided by new projects involving CO 2 . Considering the current wide range of carbon cost estimates, the paper recommends that a two-stage approach be adopted. Firstly, incorporate carbon costs in project analysis only theoretically in order to differentiate objectively among alternative designs involving carbon emissions of varying degrees. Different estimates of the costs of a ton of carbon would be used in order to test the sensitivity of rates of return to alternative carbon costs. While this process would have the effect of screening the allocation of scarce investment funds among projects that affect global warming in different degrees, it should be viewed as only a first step. Secondly, we advocate a rigorous process of passing through estimated carbon costs to the ultimate users of the services of carbon-emitting projects and processes. It is this ultimate process that will secure the urgently needed transition from the current dependence on fossil fuels to more benign sources of energy that would reduce climate-change risks. Since the time available is limited, the paper points out the urgency of these proposals that are crucial for sustainability

  11. International Symposium on Site Characterization for CO2Geological Storage

    Energy Technology Data Exchange (ETDEWEB)

    Tsang, Chin-Fu

    2006-02-23

    Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

  12. Influence of UV-B radiation on developmental changes, ethylene, CO2 flux and polyamines in cv. Doyenne d'Hiver pear shoots grown in vitro

    International Nuclear Information System (INIS)

    Predieri, S.; Krizek, D.T.; Wang, C.Y.; Mirecki, R.M.; Zimmerman, R.H.

    1993-01-01

    In vitro shoots of cv. Doyenne d'Hiver pear (Pyrus communis L.) were irradiated under controlled environments for 6 h per day at 5 different levels of biologically effective UV-B radiation (UV-B BE ). UV-B exposure caused a progressive increase in apical necrosis above background levels and stimulated leaf abscission. Shoots grown for 2 weeks at 7. 8 mol m −2 day −1 of photosynthetic photon flux (PPF) and treated with 8. 4 or 12. 0 kJ m −2 day −1 UV-B BE produced up to 4 times more ethylene than those given 2. 2 or 5. 1 kJ m −2 day −1 UV-B BE or untreated controls. Exposure of shoots to 12 kJ m −2 day −1 of UV-BBE caused an increase in free putreseine content after 4 to 14 days of irradiation. Shoots showed a decrease in CO2 uptake after 3 days of UV-B: thereafter, they appeared to recover their photosynthetic capacity. Under typical PPF conditions used in micropropagation (90 μmol m −2 s −1 ). 8. 4 kJ m −2 day −1 of UV-B radiation was injurious to realatively tender tissues of in vitro pear shoots: increasing the level of UV-B BE to 12 kJ m −2 day −1 produced even more adverse effects. (author)

  13. The response of Plantago major ssp pleiosperma to elevated CO2 is modulated by the formation of secondary shoots

    NARCIS (Netherlands)

    Coelho Guerra da Fonseca, F.M; den Hertog, J; Stulen, G

    The effect of elevated CO2 on the relative growth rate (RGR) of Plantago major ssp. pleiosperma was studied during the vegetative stage, in relation to plant development, by growing plants at 350 mu l l(-1) or at 700 mu l l(-1) CO2 in non-limiting nutrient solution with nitrate. To minimize

  14. China’s provincial CO2 emissions embodied in international and interprovincial trade

    International Nuclear Information System (INIS)

    Guo Ju’e; Zhang Zengkai; Meng Lei

    2012-01-01

    Trades create a mechanism of embodied CO 2 emissions transfer among regions, causing distortion on the total emissions. As the world’s second largest economy, China has a large scale of trade, which results in the serious problem of embodied CO 2 emissions transfer. This paper analyzes the characteristics of China’s CO 2 emissions embodied in international and interprovincial trade from the provincial perspective. The multi-regional Input–Output Model is used to clarify provincial CO 2 emissions from geographical and sectoral dimensions, including 30 provinces and 28 sectors. Two calculating principles (production accounting principle and consumption accounting principle, ) are applied. The results show that for international trade, the eastern area accounts for a large proportion in China’s embodied CO 2 emissions. The sectors as net exporters and importers of embodied CO 2 emissions belong to labor-intensive and energy-intensive industries, respectively. For interprovincial trade, the net transfer of embodied CO 2 emissions is from the eastern area to the central area, and energy-intensive industries are the main contributors. With the largest amount of direct CO 2 emissions, the eastern area plays an important role in CO 2 emissions reduction. The central and western areas need supportive policies to avoid the transfer of industries with high emissions. - Highlights: ► China’s embodied CO 2 emissions are analyzed from the provincial perspective. ► Eastern provinces have larger CO 2 emissions embodied in international trade. ► Embodied CO 2 emissions are mainly transferred from eastern area to central area. ► Coastal provinces play important roles in CO 2 emissions reduction. ► Inland provinces need supportive policies on emissions reduction.

  15. Long-term effects of CO2 enrichment on bud phenology and shoot growth patterns of Norway spruce juvenile trees

    Czech Academy of Sciences Publication Activity Database

    Pokorný, Radek; Tomášková, Ivana; Drápelová, I.; Kulhavý, J.; Marek, Michal V.

    2010-01-01

    Roč. 56, č. 6 (2010), s. 251-257 ISSN 1212-4834 R&D Projects: GA AV ČR IAA600870701 Institutional research plan: CEZ:AV0Z60870520 Keywords : bud * elevated CO2 * Norway spruce Subject RIV: EH - Ecology, Behaviour

  16. International and European legal aspects on underground geological storage of CO2

    International Nuclear Information System (INIS)

    Wall, C.; Olvstam, M.-L.; Bernstone, C.

    2005-01-01

    The often disconnected international and European legal rules regarding carbon dioxide (CO 2 ) storage in geological formations create legal uncertainty and a slow down in investments. Existing rules for waste dumping, such as the OSPAR and London Conventions implies that CO 2 storage in sub seabed geological formations is not permitted for climate change mitigating purposes. This paper emphasized that even in cases when complete certainty about the exact application of a legal rule is not possible, it is necessary to know if an activity is lawful. It also emphasized that CO 2 storage should be a priority in the international agenda. The current gaps in knowledge concerning the relevant international and European legislation directly related to CO 2 storage were identified in this paper, including long-term liability for risk of damages caused during the injection phase of the well. The current relevant legislation that is not directly concerned with CO 2 storage but which might have an impact on future legislation was also discussed along with relevant legal principles that might influence future legislation. Some of the many ongoing projects concerning CO 2 storage were reviewed along with papers and reports on regulating CO 2 storage. It was concluded that if CO 2 capture and storage is going to be a large-scale concept for mitigating climate change, the legal issues and requirements need to be an area of priority. 16 refs

  17. Efficiencies of subcritical and transcritical CO2 inverse cycles with and without an internal heat exchanger

    International Nuclear Information System (INIS)

    Zhang, F.Z.; Jiang, P.X.; Lin, Y.S.; Zhang, Y.W.

    2011-01-01

    An internal heat exchanger (IHX) is often used to improve the coefficient of performance (COP) of CO 2 inverse cycles. This paper presents a detailed analysis of the IHX's effect in CO 2 inverse cycles and finds suitable operating conditions for the IHX from a thermodynamic performance point of view. The results indicate that the COP is slightly reduced by an IHX in a CO 2 subcritical inverse cycle, so an IHX is not justified. However, for transcritical CO 2 inverse cycles, the compressor discharge pressures and CO 2 gas cooler outlet temperatures both have significant impacts on system performance. The analysis results for transcritical CO 2 inverse cycles show that a transition discharge pressure and a transition CO 2 gas cooler outlet temperature are objective existence above which the IHX improves the cycle performance. - Research highlights: → Find suitable operating conditions for the IHX. → Above transition CO2 gas cooler outlet temperature IHX improves cycle performance. → The IHX is not very useful for optimized space heating and refrigerating cycles.

  18. Internal respiration of Amazon tree stems greatly exceeds external CO2 efflux

    Directory of Open Access Journals (Sweden)

    J. Q. Chambers

    2012-12-01

    Full Text Available Respiration in tree stems is an important component of forest carbon balance. The rate of CO2 efflux from the stem has often been assumed to be a measure of stem respiration. However, recent work in temperate forests has demonstrated that stem CO2 efflux can either overestimate or underestimate respiration rate because of emission or removal of CO2 by transport in xylem water. Here, we studied gas exchange from stems of tropical forest trees using a new approach to better understand respiration in an ecosystem that plays a key role in the global carbon cycle. Our main questions were (1 is internal CO2 transport important in tropical trees, and, if so, (2 does this transport result in net release of CO2 respired in the roots at the stem, or does it cause the opposite effect of net removal of stem-respired CO2? To answer these questions, we measured the ratio of stem CO2 efflux to O2 influx. This ratio, defined here as apparent respiratory quotient (ARQ, is expected to equal 1.0 if carbohydrates are the substrate for respiration, and the net transport of CO2 in the xylem water is negligible. Using a stem chamber approach to quantifying ARQ, we found values of 0.66 ± 0.18. These low ARQ values indicate that a large portion of respired CO2 (~ 35% is not emitted locally, and is probably transported upward in the stem. ARQ values of 0.21 ± 0.10 were found for the steady-state gas concentration within the stem, sampled by in-stem equilibration probes. These lower values may result from the proximity to the xylem water stream. In contrast, we found ARQ values of 1.00 ± 0.13 for soil respiration. Our results indicate the existence of a considerable internal flux of CO2 in the stems of tropical trees. If the transported CO2 is used in the canopy as a substrate for photosynthesis, it could account for up to 10% of the C fixed by the tree, and perhaps serve as a mechanism that buffers the response of the tree to changing CO2 levels. Our results also

  19. Modelling Energy Systems and International Trade in CO2 Emission Quotas - The Kyoto Protocol and Beyond

    International Nuclear Information System (INIS)

    Persson, Tobias A.

    2002-01-01

    A transformation of the energy system in the 21st century is required if the CO 2 concentration in the atmosphere should be stabilized at a level that would prevent dangerous anthropogenic interference with the climate system. The industrialized countries have emitted most of the anthropogenic CO 2 released to the atmosphere since the beginning of the industrial era and still account for roughly two thirds of global fossil fuel related CO 2 emissions. Industrial country CO 2 emissions on a per capita basis are roughly five to ten times higher than those of developing countries. However, a global atmospheric CO 2 concentration target of 450 ppm, if adopted would require that global average per capita CO 2 emissions by the end of this century have to be comparable to those of developing countries today. The industrialized countries would have to reduce their emissions substantially and the emissions in developing countries could not follow a business-as-usual scenario. The transformation of the energy system and abatement of CO 2 emissions would need to occur in industrialized and developing countries. Energy-economy models have been developed to analyze of international trading in CO 2 emission permits. The thesis consists of three papers. The cost of meeting the Kyoto Protocol is estimated in the first paper. The Kyoto Protocol, which defines quantitative greenhouse gas emission commitments for industrialized countries over the period 2008-2012, is the first international agreement setting quantitative goals for abatement of CO 2 emissions from energy systems. The Protocol allows the creation of systems for trade in emission permits whereby countries exceeding their target levels can remain in compliance by purchasing surplus permits from other developed countries. However, a huge carbon surplus, which has been christened hot air, has been created in Russia and Ukraine since 1990 primarily because of the contraction of their economies. The current Unites States

  20. Trends in CO2 Emissions from China-Oriented International Marine Transportation Activities and Policy Implications

    Directory of Open Access Journals (Sweden)

    Hualong Yang

    2017-07-01

    Full Text Available The demand for marine transportation and its associated CO2 emissions are growing rapidly as a result of increasing international trade and economic growth. An activity-based approach is developed for forecasting CO2 emissions from the China-oriented international seaborne trade sector. To accurately estimate the aggregated emissions, CO2 emissions are calculated individually for five categories of vessels: crude oil tanker, product tanker, chemical tanker, bulk carrier, and container. A business-as-usual (BAU scenario was developed to describe the current situation without additional mitigation policies, whilst three alternative scenarios were developed to describe scenarios with various accelerated improvements of the key factors. The aggregated CO2 emissions are predicted to reach 419.97 Mt under the BAU scenario, and 258.47 Mt under the optimal case, AD3. These predictions are 4.5 times and 2.8 times that of the aggregated emissions in 2007. Our analysis suggests that regulations for monitoring, reporting, and verifying the activities of vessels should be proposed, in order to quantify the CO2 emissions of marine transportation activities in Chinese territorial waters. In the long-term future, mitigation policies should be employed to reduce CO2 emissions from the marine trade sector and to address the climatic impact of shipping.

  1. Increase of Internal CO2 of Cotton Plants by Methanol Application to Increase Yield

    International Nuclear Information System (INIS)

    Badron Zakaria; Darmawan; Nurlina Kasim; Joseph Saepuddin

    2004-01-01

    A field experiment has been conducted to increase internal CO 2 and Rubisco activity detected by 14 C and to determinate which factors influence this activities. Plant material used was cotton plants which internal CO 2 concentrations and Rubisco activity was observed at 35, 50, 65, 80 days after planting (DAP). Treatments applied were methanol with concentrations of 0%, 10%,20% and 30% at available water (AW) at 25-50% AW, 50-75% AW, 75-100% AW. Results obtained showed that application of methanol at concentration of 20% at 75-100% AW, increase internal CO 2 from 266.60 ppm to 295.10 ppm (11 % increase) and this will also increase Rubisco activity from 3.81 to 14.28 (μmol. CO 2 menit -1 (μmol. Rubisco -1 ). This increase is expected to push photosynthesis rate and result in increase cotton yield. The use of 14 C was satisfactorily detected the amount of carbon. (author)

  2. Analysis of the international distribution of per capita CO2 emissions using the polarization concept

    International Nuclear Information System (INIS)

    Duro, Juan Antonio; Padilla, Emilio

    2008-01-01

    The concept of polarization is linked to the extent that a given distribution leads to the formation of homogeneous groups with opposing interests. This concept, which is basically different from the traditional one of inequality, is related to the level of inherent potential conflict in a distribution. The polarization approach has been widely applied in the analysis of income distribution. The extension of this approach to the analysis of international distribution of CO 2 emissions is quite useful as it gives a potent informative instrument for characterizing the state and evolution of the international distribution of emissions and its possible political consequences in terms of tensions and the probability of achieving agreements. In this paper we analyze the international distribution of per capita CO 2 emissions between 1971 and 2001 through the adaptation of the polarization concept and measures. We find that the most interesting grouped description deriving from the analysis is a two groups' one, which broadly coincide with Annex B and non-Annex B countries of the Kyoto Protocol, which shows the power of polarization analysis for explaining the generation of groups in the real world. The analysis also shows a significant reduction in international polarization in per capita CO 2 emissions between 1971 and 1995, but not much change since 1995, which might indicate that polarized distribution of emission is still one of the important factors leading to difficulties in achieving agreements for reducing global emissions. (author)

  3. International inequalities in per capita CO2 emissions: a decomposition methodology by Kaya factors

    International Nuclear Information System (INIS)

    Duro, J.A.; Universitat de Barcelona; Padilla, E.

    2006-01-01

    In this paper, we provide a methodology for decomposing international inequalities in per capita CO 2 emissions into Kaya (multiplicative) factors and two interaction terms. We use the Theil index of inequality and show that this decomposition methodology can be extended for analyzing between- and within-group inequality components. We can thus analyze the factors behind inequalities in per capita CO 2 emissions across countries, between groups of countries and within groups of countries. The empirical illustration for international data suggests some points. Firstly, international inequality in per capita CO 2 emissions is mainly attributable to inequalities in per capita income levels, which helps to explain its recent reduction, while differences in carbon intensity of energy and energy intensity have made a less significant contribution. This result is strongly influenced by the performance of China and India. Secondly, the between-group inequality component, which is the biggest component, is also largely explained by the income factor. Thirdly, the within-group inequality component increased slightly during the period, something mainly due to the change in the income factor and the interaction terms in a few regions. (author)

  4. CO2 embodied in international trade with implications for global climate policy.

    Science.gov (United States)

    Peters, Glen P; Hertwich, Edgar G

    2008-03-01

    The flow of pollution through international trade flows has the ability to undermine environmental policies, particularly for global pollutants. In this article we determine the CO2 emissions embodied in international trade among 87 countries for the year 2001. We find that globally there are over 5.3 Gt of CO2 embodied in trade and that Annex B countries are net importers of CO2 emissions. Depending on country characteristics--such as size variables and geographic location--there are considerable variations in the embodied emissions. We argue that emissions embodied in trade may have a significant impact on participation in and effectiveness of global climate policies such as the Kyoto Protocol. We discuss several policy options to reduce the impact of trade in global climate policy. If countries take binding commitments as a part of a coalition, instead of as individual countries, then the impacts of trade can be substantially reduced. Adjusting emission inventories for trade gives a more consistent description of a country's environmental pressures and circumvents many trade related issues. It also gives opportunities to exploit trade as a means of mitigating emissions. Not least, a better understanding of the role that trade plays in a country's economic and environmental development will help design more effective and participatory climate policy post-Kyoto.

  5. The international race for CO2 capture and storage. And the winner is ...?

    International Nuclear Information System (INIS)

    De Coninck, H.C.

    2008-06-01

    Ever since CO2 capture and storage (CCS) has gained prominence among greenhouse gas reduction alternatives, researchers, policymakers, and industry have speculated about who would become the technology leader in this field. Will it be a technology that follows in the footsteps of solar and wind energy and sees European companies as market leaders benefiting from an early mover advantage, strengthened by a favorable internal market? Will the enormous investments of the U.S. government in R and D combined with its greater entrepreneurial power and better investment climate pay off? Or will other countries - like Australia which is very active in this area, or maybe China - become the world's market leader in CO2 capture installations, a highly capital-intensive technology? Given exploding world energy demand, climate-friendly technologies will be indispensable for stabilizing greenhouse gas concentrations. Thus, countries being able to develop and maintain themselves as technology leaders are likely to benefit from the deep reductions in CO2 emissions that we will need to achieve in the near future

  6. The relationships between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

    Directory of Open Access Journals (Sweden)

    H. Jamali

    2013-04-01

    Full Text Available We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a carbon dioxide equivalent (CO2-e basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e fluxes at site. The contribution of CH4 and CO2 emissions from termite mounds to the total CH4 and CO2 emissions from termite mounds and soil in CO2-e was less than 1%. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux; however, these relationships were clearly termite species specific. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in the past would result in errors of more than 5-fold for mound CH4 flux and 3-fold for mound CO2 flux. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a mound, and between the inside mound concentration of a gas and the mound flux emission of the

  7. The relationships between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

    Science.gov (United States)

    Jamali, H.; Livesley, S. J.; Hutley, L. B.; Fest, B.; Arndt, S. K.

    2013-04-01

    We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a carbon dioxide equivalent (CO2-e) basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e) fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e) fluxes at site. The contribution of CH4 and CO2 emissions from termite mounds to the total CH4 and CO2 emissions from termite mounds and soil in CO2-e was less than 1%. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux; however, these relationships were clearly termite species specific. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in the past) would result in errors of more than 5-fold for mound CH4 flux and 3-fold for mound CO2 flux. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a mound, and between the inside mound concentration of a gas and the mound flux emission of the same gas, but

  8. Stomatal and pavement cell density linked to leaf internal CO2 concentration.

    Science.gov (United States)

    Santrůček, Jiří; Vráblová, Martina; Simková, Marie; Hronková, Marie; Drtinová, Martina; Květoň, Jiří; Vrábl, Daniel; Kubásek, Jiří; Macková, Jana; Wiesnerová, Dana; Neuwithová, Jitka; Schreiber, Lukas

    2014-08-01

    Stomatal density (SD) generally decreases with rising atmospheric CO2 concentration, Ca. However, SD is also affected by light, air humidity and drought, all under systemic signalling from older leaves. This makes our understanding of how Ca controls SD incomplete. This study tested the hypotheses that SD is affected by the internal CO2 concentration of the leaf, Ci, rather than Ca, and that cotyledons, as the first plant assimilation organs, lack the systemic signal. Sunflower (Helianthus annuus), beech (Fagus sylvatica), arabidopsis (Arabidopsis thaliana) and garden cress (Lepidium sativum) were grown under contrasting environmental conditions that affected Ci while Ca was kept constant. The SD, pavement cell density (PCD) and stomatal index (SI) responses to Ci in cotyledons and the first leaves of garden cress were compared. (13)C abundance (δ(13)C) in leaf dry matter was used to estimate the effective Ci during leaf development. The SD was estimated from leaf imprints. SD correlated negatively with Ci in leaves of all four species and under three different treatments (irradiance, abscisic acid and osmotic stress). PCD in arabidopsis and garden cress responded similarly, so that SI was largely unaffected. However, SD and PCD of cotyledons were insensitive to Ci, indicating an essential role for systemic signalling. It is proposed that Ci or a Ci-linked factor plays an important role in modulating SD and PCD during epidermis development and leaf expansion. The absence of a Ci-SD relationship in the cotyledons of garden cress indicates the key role of lower-insertion CO2 assimilation organs in signal perception and its long-distance transport. © The Author 2014. Published by Oxford University Press on behalf of the Annals of Botany Company. All rights reserved. For Permissions, please email: journals.permissions@oup.com.

  9. The relationship between termite mound CH4/CO2 emissions and internal concentration ratios are species specific

    Science.gov (United States)

    Jamali, H.; Livesley, S. J.; Hutley, L. B.; Fest, B.; Arndt, S. K.

    2012-12-01

    1. We investigated the relative importance of CH4 and CO2 fluxes from soil and termite mounds at four different sites in the tropical savannas of Northern Australia near Darwin and assessed different methods to indirectly predict CH4 fluxes based on CO2 fluxes and internal gas concentrations. 2. The annual flux from termite mounds and surrounding soil was dominated by CO2 with large variations among sites. On a CO2-e basis, annual CH4 flux estimates from termite mounds were 5- to 46-fold smaller than the concurrent annual CO2 flux estimates. Differences between annual soil CO2 and soil CH4 (CO2-e) fluxes were even greater, soil CO2 fluxes being almost three orders of magnitude greater than soil CH4 (CO2-e) fluxes at site. 3. There were significant relationships between mound CH4 flux and mound CO2 flux, enabling the prediction of CH4 flux from measured CO2 flux, however, these relationships were clearly termite species specific. 4. We also observed significant relationships between mound flux and gas concentration inside mound, for both CH4 and CO2, and for all termite species, thereby enabling the prediction of flux from measured mound internal gas concentration. However, these relationships were also termite species specific. Using the relationship between mound internal gas concentration and flux from one species to predict mound fluxes from other termite species (as has been done in past) would result in errors of more than 5-fold for CH4 and 3-fold for CO2. 5. This study highlights that CO2 fluxes from termite mounds are generally more than one order of magnitude greater than CH4 fluxes. There are species-specific relationships between CH4 and CO2 fluxes from a~mound, and between the inside mound concentration of a gas and the mound flux emission of the same gas, but these relationships vary greatly among termite species. Consequently, there is no generic relationship that will allow for the prediction of CH4 fluxes from termite mounds of all species.

  10. Light-Triggered CO2 Breathing Foam via Nonsurfactant High Internal Phase Emulsion.

    Science.gov (United States)

    Zhang, Shiming; Wang, Dingguan; Pan, Qianhao; Gui, Qinyuan; Liao, Shenglong; Wang, Yapei

    2017-10-04

    Solid materials for CO 2 capture and storage have attracted enormous attention for gaseous separation, environmental protection, and climate governance. However, their preparation and recovery meet the problems of high energy and financial cost. Herein, a controllable CO 2 capture and storage process is accomplished in an emulsion-templated polymer foam, in which CO 2 is breathed-in under dark and breathed-out under light illumination. Such a process is likely to become a relay of natural CO 2 capture by plants that on the contrary breathe out CO 2 at night. Recyclable CO 2 capture at room temperature and release under light irradiation guarantee its convenient and cost-effective regeneration in industry. Furthermore, CO 2 mixed with CH 4 is successfully separated through this reversible breathing in and out system, which offers great promise for CO 2 enrichment and practical methane purification.

  11. Time series pCO2 at a coastal mooring: Internal consistency, seasonal cycles, and interannual variability

    Science.gov (United States)

    Reimer, Janet J.; Cai, Wei-Jun; Xue, Liang; Vargas, Rodrigo; Noakes, Scott; Hu, Xinping; Signorini, Sergio R.; Mathis, Jeremy T.; Feely, Richard A.; Sutton, Adrienne J.; Sabine, Christopher; Musielewicz, Sylvia; Chen, Baoshan; Wanninkhof, Rik

    2017-08-01

    Marine carbonate system monitoring programs often consist of multiple observational methods that include underway cruise data, moored autonomous time series, and discrete water bottle samples. Monitored parameters include all, or some of the following: partial pressure of CO2 of the water (pCO2w) and air, dissolved inorganic carbon (DIC), total alkalinity (TA), and pH. Any combination of at least two of the aforementioned parameters can be used to calculate the others. In this study at the Gray's Reef (GR) mooring in the South Atlantic Bight (SAB) we: examine the internal consistency of pCO2w from underway cruise, moored autonomous time series, and calculated from bottle samples (DIC-TA pairing); describe the seasonal to interannual pCO2w time series variability and air-sea flux (FCO2), as well as describe the potential sources of pCO2w variability; and determine the source/sink for atmospheric pCO2. Over the 8.5 years of GR mooring time series, mooring-underway and mooring-bottle calculated-pCO2w strongly correlate with r-values > 0.90. pCO2w and FCO2 time series follow seasonal thermal patterns; however, seasonal non-thermal processes, such as terrestrial export, net biological production, and air-sea exchange also influence variability. The linear slope of time series pCO2w increases by 5.2 ± 1.4 μatm y-1 with FCO2 increasing 51-70 mmol m-2 y-1. The net FCO2 sign can switch interannually with the magnitude varying greatly. Non-thermal pCO2w is also increasing over the time series, likely indicating that terrestrial export and net biological processes drive the long term pCO2w increase.

  12. Effects of elevated temperature and CO2 on aboveground-belowground systems: a case study with plants, their mutualistic bacteria and root / shoot herbivores

    Directory of Open Access Journals (Sweden)

    James Michael William Ryalls

    2013-11-01

    Full Text Available Interactions between above- and belowground herbivores have been prominent in the field of aboveground-belowground ecology from the outset, although little is known about how climate change affects these organisms when they share the same plant. Additionally, the interactive effects of multiple factors associated with climate change such as elevated temperature (eT and elevated atmospheric carbon dioxide (eCO2 are untested. We investigated how eT and eCO2 affected larval development of the lucerne weevil (Sitona discoideus and colonisation by the pea aphid (Acyrthosiphon pisum, on three cultivars of a common host plant, lucerne (Medicago sativa. Sitona discoideus larvae feed on root nodules housing N2-fixing rhizobial bacteria, allowing us to test the effects of eT and eCO2 on three trophic levels. Moreover, we assessed the influence of these factors on plant growth. eT increased plant growth rate initially (6, 8 and 10 weeks after sowing, with cultivar ‘Sequel’ achieving the greatest height. Inoculation with aphids, however, reduced plant growth at week 14. eT severely reduced root nodulation by 43%, whereas eCO2 promoted nodulation by 56%, but only at ambient temperatures. Weevil presence increased net root biomass and nodulation, by 31 and 45%, respectively, showing an overcompensatory plant growth response. Effects of eT and eCO2 on root nodulation were mirrored by weevil larval development; eT and eCO2 reduced and increased larval development, respectively. Contrary to expectations, aphid colonisation was unaffected by eT or eCO2, but there was a near-significant 10% reduction in colonisation rates on plants with weevils present belowground. The contrasting effects of eT and eCO2 on weevils potentially occurred through changes in root nodulation patterns.

  13. Ion Internal Excitation and Co++ 2 Reactivity: Effect On The Titan, Mars and Venus Ionospheric Chemistry

    Science.gov (United States)

    Nicolas, C.; Zabka, J.; Thissen, R.; Dutuit, O.; Alcaraz, C.

    In planetary ionospheres, primary molecular and atomic photoions can be produced with substantial electronic and vibrational internal energy. In some cases, this is known to strongly affect both the rate constants and the branching ratio between the reac- tion products. A previous experimental study (Nicolas et al.) made at the Orsay syn- chrotron radiation facility has shown that many endothermic charge transfer reactions which were not considered in the ionospheric chemistry models of Mars, Venus and Earth have to be included because they are driven by electronic excitation of the parent ions. New measurements on two important reactions for Titan and Mars ionospheres, N+ + CH4 and O+ + CO2, will be presented. Branching ratios between products are very different when the parent atomic ions are prepared in their ground states, N+(3P) and O+(4S), or in their first electronic metastable states N+(1D) and O+(2D or P). 2 As the lifetime of these states are long enough, they survive during the mean time be- tween two collisions in the ionospheric conditions. So, the reactions of these excited states must be included in the ionospheric models. Absolute cross section measurements of the reactivity of stable doubly charged molec- ular ions CO++ and their implications for the Martian ionosphere will also be pre- 2 sented. The molecular dication CO++ production by VUV photoionisation and elec- 2 tron impact in the upper ionosphere of Mars is far from being negligible. However, to determine its concentration, it was necessary to evaluate the major loss channels of these ions. For this purpose, we measured the absolute reaction cross section of the sta- ble dications with CO2, the major neutral species of the Mars ionosphere. CO++ ions 2 were produced either by photoionisation or by electron impact, and a reaction cross section of 45 Å2 with 13CO2 was measured. The reaction leads to charge transfer or to collision induced dissociation. These results were integrated in a model

  14. Incentive-based regulation of CO2 emissions from international aviation

    International Nuclear Information System (INIS)

    Carlsson, F.; Hammar, H.

    2002-01-01

    We explore the possibilities of using incentive-based environmental regulations of CO 2 emissions from international civil aviation. In theory incentive-based instruments such as an emission charge or a tradable emission permit system are better regulations than so-called command-and-control regulations such as emission limits or technology standards. However, the implementation of these instruments is a complex issue. We therefore describe and discuss how an emission charge and a tradable emission permit system for international aviation should be designed in order to improve efficiency. We also compare these two types of regulations. In brief, we find that an emission charge and a tradable emission permit system in which the permits are auctioned have more or less the same characteristics. The main advantage of a tradable emission permit system is that the effect, in terms of emission reductions, is known. On the other hand, we show that under uncertainty an emission charge is preferred. The choice of regulation is a political decision and it does not seem likely that an environmental charge or a tradable emission permit system would be implemented without consideration of the costs of the regulation. Revenue-neutral charges or gratis distribution of permits would, for this reason, be realistic choices of regulations. However, such actions are likely to result in less stringent regulations and other negative welfare effects.(author)

  15. Attribution of CO2 emissions from Brazilian deforestation to domestic and international drivers

    Science.gov (United States)

    Karstensen, J.; Peters, G.

    2011-12-01

    Efforts to address extensive deforestation to reduce climate change and save primary forests are taking place on a global scale. Whilst several studies have estimated the emissions occurring from deforestation in large rainforests, few studies have investigated the domestic and international drivers sustaining and increasing the deforestation rates. Brazil, having the largest rainforest in the world and one of the highest deforestation rates, is also currently one of the world's largest exporters of soybeans and beef. In this case study we establish the link between Brazilian deforestation and cattle and soybean production, and further attribute emissions to countries and economic sectors through export and import of Brazilian commodities. The emissions from deforestation can therefore be allocated to the countries and sectors consuming goods and services produced on deforested land in Brazil. A land-use change model and deforestation data is coupled with a carbon cycle model to create yearly emission estimates and different emission allocation schemes, depending on emission amortizations and discounting functions for past deforestation. We use an economic multi-regional input-output model (with 112 regions and 57 sectors) to distribute these emissions along agricultural trade routes, through domestic and international consumption in 2004. With our implementation we find that around 80 % of emissions from deforested land is due to cattle grazing, while agricultural transition effects suggests soy beans are responsible for about 20 % of the emissions occurring in 2004. Nearly tree quarters of the soy beans are consumed outside Brazil, of which China, Germany and France are the biggest consumers. Soy beans are consumed by a variety of sectors in the food industry. Brazil exports about 30 % of the cattle it produces, where Russia, USA and Germany are among the largest consumers. Cattle consumption mainly occurs in the meat sectors. In this study we estimate the CO2

  16. Evidence that an internal carbonic anhydrase is present in 5% CO2-grown and air-grown Chlamydomonas

    International Nuclear Information System (INIS)

    Moroney, J.V.; Togasaki, R.K.; Husic, H.D.; Tolbert, N.E.

    1987-01-01

    Inorganic carbon (C/sub i/) uptake was measured in wild-type cells of Chlamydomonas reinhardtii, and in cia-3, a mutant strain of C. reinhardtii that cannot grow with air levels of CO 2 . Both air-grown cells, that have a CO 2 concentrating system, and 5% CO 2 -grown cells that do not have this system, were used. When the external pH was 5.1 or 7.3, air-grown, wild-type cells accumulated inorganic carbon (C/sub i/) and this accumulation was enhanced when the permeant carbonic anhydrase inhibitor, ethoxyzolamide, was added. When the external pH was 5.1, 5% CO 2 -grown cells also accumulated some C/sub i/, although not as much as air-grown cells and this accumulation was stimulated by the addition of ethoxyzolamide. At the same time, ethoxyzolamide inhibited CO 2 fixation by high CO 2 -grown, wild-type cells at both pH 5.1 and 7.3. These observations imply that 5% CO 2 -grown, wild-type cells, have a physiologically important internal carbonic anhydrase, although the major carbonic anhydrase located in the periplasmic space is only present in air-grown cells. Inorganic carbon uptake by cia-3 cells supported this conclusion. This mutant strain, which is thought to lack an internal carbonic anhydrase, was unaffected by ethoxyzolamide at pH 5.1. Other physiological characteristics of cia-3 resemble those of wild-type cells that have been treated with ethoxyzolamide. It is concluded that an internal carbonic anhydrase is under different regulatory control than the periplasmic carbonic anhydrase

  17. Austria's CO2 responsibility and the carbon content of its international trade

    International Nuclear Information System (INIS)

    Munoz, Pablo; Steininger, Karl W.

    2010-01-01

    Seeking to limit global warming to 2 C puts narrow restrictions on the remaining carbon budget. While the prevalent accounting framework for carbon emissions is production based (Production-Based Principle, PBP), we here quantify the CO 2 emissions on the basis of the Consumption-Based Principle (CBP) for Austria. At a methodological level, a Multi-Regional Input-Output model with full linkages is used to account for Austria's CO 2 responsibility on a global scale. Estimates are carried out for the years 1997 and 2004. Results show that during 1997 CO 2 responsibility based on CBP were 36% larger than those based on PBP. This relation has increased through time. The CBP indicator of 2004 was 44% larger than the PBP. In terms of carbon emission location, for each Euro spent on Austrian final demand in 2004, it is estimated that two-thirds of the CO 2 emissions occur outside Austrian borders. Regarding the origin of the emissions embodied in imports, it is estimated that about one-fourth originated in non-Annex I countries in 1997. This proportion increased to one-third by 2004. Due to this divergence between CBP and PBP indicators, there is a need to re-think current accounting bases in order to properly assign CO 2 responsibilities. (author)

  18. International comparison of CO2 emission trends in the iron and steel industry

    International Nuclear Information System (INIS)

    Yeonbae, Kim; Worrell, E.

    2002-01-01

    In this paper, we present an in-depth decomposition analysis of trends in CO 2 emissions in the iron and steel industry using physical indicators. Physical indicators allow a detailed analysis of intra- sectoral trends, in contrast to the mostly used monetary indicators. Detailed decomposition analysis makes it possible to link developments in energy intensity to technology change and (indirectly) to policy. We present an analysis for the iron and steel industry in seven countries, i.e. Brazil, China, India (developing countries), Mexico and South Korea (newly industrialized countries) and the United States (industrialized country). We found substantial differences in energy efficiency among these countries. In most countries the increased (or decreased) production was the main contributor to changes in CO 2 emissions, while energy-efficiency was the main factor reducing emission intensities of steel production in almost all countries. Changes in power generation contributed to a reduction of specific emissions in the case of South Korea only. (Author)

  19. International marine and aviation bunker fuel. Trends, ranking of countries and comparison with national CO2 emission

    International Nuclear Information System (INIS)

    Olivier, J.G.J.; Peters, J.A.H.W.

    1999-01-01

    This report summarises and characterises fuel consumption and associated CO2 emissions from international transport based on energy statistics compiled by the International Energy Agency (IEA). Shares in 1990 and 1970-1995 trends in national and global bunker fuel consumption and associated CO2 emissions are analysed for marine and air transport. Also, the global total of international transport emissions are compared with national emissions and domestic transport emissions. During the last 25 years the average global annual increase was for marine bunkers about 0.8% and for aviation emissions about 3.3%. Annual variations per country of marine bunker fuel use larger than of aviation fuel use, sometimes more than 50%. However, the distinction between fuel use for domestic and for international aviation is more difficult to monitor. The dominant fuel in marine bunker fuel consumption is residual fuel oil ('heavy fuel oil'). The share of diesel oil has slowly increased from 11% in 1970 to 20% in 1990. Aviation fuels sold are predominantly jet fuel ('jet kerosene'). The small share of aviation gasoline is slowly decreasing: from about 4% in 1970 to 1.3% in 1990. Carbon dioxide emissions from combustion of international marine bunker fuels and aviation contributed in 1990 globally about 1.8% and 2.4% expressed as percentage of global total anthropogenic emissions (excluding deforestation). However, aviation emissions include an unknown part of domestic aviation. When comparing with total transport emissions, then international transport has a share of 20%. For both marine and aviation bunker fuel, the Top-10 of largest consuming countries account for about 2/3 of the global total; the Top-25 countries cover already 85% or more of global total CO2 emissions

  20. Change in CO2 emission and its transmissions between Korea and Japan using international input-output analysis

    International Nuclear Information System (INIS)

    Rhee, Hae-Chun; Chung, Hyun-Sik

    2006-01-01

    This paper is intended to analyze CO 2 transmission between Japan and South Korea through international trade based on 1990 and 1995 international input-output data. It applied a residual-free structural decomposition method proposed by Chung and Rhee [Chung, H.S., Rhee, H.C., 2001. A residual-free decomposition of the sources of carbon dioxide emissions: a case of the Korean industries. Energy 26 (1), 15-30] to emission-related international input-output analysis for the first time in the decomposition studies. This paper is a case study regarding the manner and the extent to which CO 2 emissions are influenced by international trade between Japan (an Annex I country) and South Korea (a non-Annex I country), which is of particular interest for the carbon leakage issue. In this paper, we attempted to show which factors contributed to the changes in emission of the major greenhouse gas in South Korea and Japan. The changes in emission are analyzed in terms of emission intensity, input techniques, demand composition, and trade structures. According to our analysis, South Korea, a non-Annex I country, has more energy-intensive production structures than Japan, an Annex I country. South Korea's trade pattern with Japan reflects these production features, resulting in the Korea's comparative advantage in emission intensive products, though the degree has somewhat mitigated in 1995 compared to 1990. (author)

  1. International comparison of fossil power efficiency and CO2 intensity. Update 2011

    Energy Technology Data Exchange (ETDEWEB)

    Klaassen, E.

    2011-08-15

    This study is an update of the 2010 study and aims to compare fossil-fired power generation efficiency and CO2-intensity (coal, oil and gas) for Australia, China (including Hong Kong), France, Germany, India, Japan, Nordic countries (Denmark, Finland, Sweden and Norway aggregated), South Korea, United Kingdom and Ireland, and United States. This selection of countries and regions is based on discussions with the client. United Kingdom and Ireland, and the Nordic countries are aggregated, because of the interconnection between their electricity grids. Although all electricity grids in Europe are interconnected, there are a number of markets that operate fairly independent. These are the Nordic market (Denmark, Finland, Sweden and Norway), the Iberian market (Spain and Portugal), Central (Eastern European countries) and United Kingdom and Ireland. Only public power plants are taken into account, including public CHP plants. For the latter a correction for heat extraction has been applied. This chapter gives an overview of the fuel mix for power generation for the included countries and of the amount of fossil-fired power generation. The methodology for this study is described in Chapter 2. Chapter 3 gives an overview of the efficiency of fossil-fired power generation by fuel source. Chapter 4 gives the conclusions.

  2. Panorama 2010: CO2 markets and the current status of international climate negotiations

    International Nuclear Information System (INIS)

    Alberola, E.

    2010-01-01

    The emission of greenhouse gases (GHGs) to the atmosphere is causing climatic disturbances of increasing severity, representing risks for the entire planet. Existing GHG emissions reduction policies mainly focus on setting up cap and trade systems (carbon markets) geared to achieving such reductions. The Kyoto Protocol, an international treaty established under the auspices of the United Nations, sets forth the guiding principles, objectives and legally binding targets imposed on the parties concerned until 2012. The purpose of the international negotiations underway is to set up a new regulatory framework for the post-2012 period. (author)

  3. Report on survey of international cooperation possibility on chemical CO2 fixation and utilization technology in FY 1997; 1997 nendo chosa hokokusho (kagakuteki CO2 koteika yuko riyo gijutsu ni kakawaru kokusai kyoryoku kanosei chosa)

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    This survey focused on the end of the more promising companion and promoting the international cooperation on chemical CO2 fixation and utilization technology. As a result, the way of the carrying-forward of the international cooperation with more than one companion could be arranged beforehand. It led to getting an arrangement about a secrecy agreement respectively with Lurgi company and ABB company in Europe, and to providing a catalyst sample developed by RITE to implement an examination by the other party and to show related technical information. In addition, it concluded a cooperation agreement about a total system of the chemical CO2 fixation and utilization technology and methanol synthesis with ZSW. In Australia, negotiation about international cooperation with CSIRO which is a federal research organization and CRC (Cooperative Research Centre) for renewable energy has been started. The ideal circumstances are being ready for the chemical CO2 fixation project for which the international cooperation with the country where the natural energy is rich like Australia is essential when coming to practical use. To do alternating current with further high density in the following year it is desired to build a concrete study cooperation system. 1 fig., 4 tabs.

  4. Fiscal 1996 survey of potential international cooperation for a long-term scenario on CO2 reduction; 1996 nendo CO2 sakugen ni kakawaru choki shinario ni kansuru kokusai kyoryoku kanosei chosa

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    For the purpose of working out a CO2 reduction scenario and a CO2 policy introduction scenario, a survey was conducted of comparisons between ten and several models which are world-known and models of the New Earth 21, potential international cooperation to be carried out in the future, etc. The survey included organizations which are developing CO2 policy evaluation models, survey reports made in the past, details of literature for the analysis and arrangement. From the result, details of the questionnaire survey and organizations to be surveyed were decided on for the questionnaire survey. Objects for the survey were 7 countries and 22 organizations, and survey items were places for information exchange, sending/receiving of researchers, exchange of input data, comparative calculation based on the common database, joint research work, economy, the carbon tax, impact, renewable energy, how to handle and think of the carbon isolation, etc. As a result of the survey, proposed were a workshop on CO2 reduction, a comparative study of simulation models, etc. 25 refs., 50 figs., 12 tabs.

  5. Biochemical Basis of CO2-Related Internal Browning Disorders in Pears (Pyrus communis L. cv. Rocha) during Long-Term Storage

    NARCIS (Netherlands)

    Deuchande, Teresa; Larrigaudière, Christian; Giné-bordonaba, Jordi; Pinto de Carvalho, Susana; Vasconcelos, Marta W.

    2016-01-01

    This study aimed at understanding the biochemical basis of internal browning disorders (IBDs) in ‘Rocha’ pear. For this purpose, the effects of storage under normal controlled atmosphere (CA) (3 kPa of O2 + 0.5 kPa of CO2) and IBD-inducing CA (1 kPa of O2 + 10 kPa of CO2) on the antioxidant and

  6. The relative roles of external and internal CO(2) versus H(+) in eliciting the cardiorespiratory responses of Salmo salar and Squalus acanthias to hypercarbia.

    Science.gov (United States)

    Perry, S F; McKendry, J E

    2001-11-01

    Fish breathing hypercarbic water encounter externally elevated P(CO(2)) and proton levels ([H(+)]) and experience an associated internal respiratory acidosis, an elevation of blood P(CO(2)) and [H(+)]. The objective of the present study was to assess the potential relative contributions of CO(2) versus H(+) in promoting the cardiorespiratory responses of dogfish (Squalus acanthias) and Atlantic salmon (Salmo salar) to hypercarbia and to evaluate the relative contributions of externally versus internally oriented receptors in dogfish. In dogfish, the preferential stimulation of externally oriented branchial chemoreceptors using bolus injections (50 ml kg(-1)) of CO(2)-enriched (4 % CO(2)) sea water into the buccal cavity caused marked cardiorespiratory responses including bradycardia (-4.1+/-0.9 min(-1)), a reduction in cardiac output (-3.2+/-0.6 ml min(-1) kg(-1)), an increase in systemic vascular resistance (+0.3+/-0.2 mmHg ml min(-1) kg(-1)), arterial hypotension (-1.6+/-0.2 mmHg) and an increase in breathing amplitude (+0.3+/-0.09 mmHg) (means +/- S.E.M., N=9-11). Similar injections of CO(2)-free sea water acidified to the corresponding pH of the hypercarbic water (pH 6.3) did not significantly affect any of the measured cardiorespiratory variables (when compared with control injections). To preferentially stimulate putative internal CO(2)/H(+) chemoreceptors, hypercarbic saline (4 % CO(2)) was injected (2 ml kg(-1)) into the caudal vein. Apart from an increase in arterial blood pressure caused by volume loading, internally injected CO(2) was without effect on any measured variable. In salmon, injection of hypercarbic water into the buccal cavity caused a bradycardia (-13.9+/-3.8 min(-1)), a decrease in cardiac output (-5.3+/-1.2 ml min(-1) kg(-1)), an increase in systemic resistance (0.33+/-0.08 mmHg ml min(-1) kg(-1)) and increases in breathing frequency (9.7+/-2.2 min(-1)) and amplitude (1.2+/-0.2 mmHg) (means +/- S.E.M., N=8-12). Apart from a small increase

  7. The Binomial Distribution in Shooting

    Science.gov (United States)

    Chalikias, Miltiadis S.

    2009-01-01

    The binomial distribution is used to predict the winner of the 49th International Shooting Sport Federation World Championship in double trap shooting held in 2006 in Zagreb, Croatia. The outcome of the competition was definitely unexpected.

  8. Mitigating CO2 Leakage by Immobilizing CO2 into Solid Reaction Products: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016. 14 November 2016 through 18 November 2016

    NARCIS (Netherlands)

    Wasch, L.J.; Wollenweber, J.; Neele, F.; Fleury, M.

    2017-01-01

    In the unlikely case of CO2 leakage from a storage reservoir, it is desirable to close the leak efficiently and permanently. This could be done by injecting a reactive solution into the leak path, thereby immobilizing migrating CO2 by consuming the gas and forming solid reactants. With regard to

  9. Detection of sodium azide-induced mutagenicity in the regenerated shoots of artemisia annual L., using internal transcribed spacer (its) sequences of nrDNA

    International Nuclear Information System (INIS)

    Al-Qurainy, F.; Al-Hemaidi, F.M.; Khan, S.; Ali, M.A.; Tarroum, M.; Ashraf, M.

    2011-01-01

    Sodium azide (NaN/sub 3/) is a well known chemical mutagen which can effectively cause point mutation in plant genome. The mutagenicity by this potential mutagen was assessed in the regenerated mutant shoots of Artemisia annua using internal transcribed spacer (ITS) sequences of n rDNA. Insertions and/or deletions were detected in n rDNA-ITS sequences of all mutant shoots and compared with control ones using the ClustalX program. The regenerated shoots TS1 and TS2 had deleted bases, whereas TS3, TS4 and TS5 had insertions, because NaN/sub 3/ replaced the cytosine (C) by thymine (T) (C - T) (shoots; TS1 and TS4) and thymine (T) replaced by guanine (G) (T - G) (shoot; TS5), respectively. Artemisinin content was also measured in the regenerated six-week-old shoots of A. annua. All regenerated shoots had enhanced level of this compound as compared to that in the controls, being highest in the regenerated shoot TS3. (author)

  10. Meteorological and small scale internal ecosystem variability characterize the uncertainty of ecosystem level responses to elevated CO2. Insights from the Duke Forest FACE experiment

    Science.gov (United States)

    Paschalis, A.; Katul, G. G.; Fatichi, S.; Palmroth, S.; Way, D.

    2017-12-01

    One of the open questions in climate change research is the pathway by which elevated atmospheric CO2 concentration impacts the biogeochemical and hydrological cycles at the ecosystem scale. This impact leads to significant changes in long-term carbon stocks and the potential of ecosystems to sequester CO2, partially mitigating anthropogenic emissions. While the significance of elevated atmospheric CO2 concentration on instantaneous leaf-level processes such as photosynthesis and transpiration is rarely disputed, its integrated effect at the ecosystem level and at long-time scales remains a subject of debate. This debate has taken on some urgency as illustrated by differences arising between ecosystem modelling studies, and data-model comparisons using Free Air CO2 Enrichment (FACE) sites around the world. Inherent leaf-to-leaf variability in gas exchange rates can generate such inconsistencies. This inherent variability arises from the combined effect of meteorological "temporal" variability and the "spatial" variability of the biochemical parameters regulating vegetation carbon uptake. This combined variability leads to a non-straightforward scaling of ecosystem fluxes from the leaf to ecosystems. To illustrate this scaling behaviour, we used 10 years of leaf gas exchange measurements collected at the Duke Forest FACE experiment. The internal variability of the ecosystem parameters are first quantified and then combined with three different leaf-scale stomatal conductance models and an ecosystem model. The main results are: (a) Variability of the leaf level fluxes is dependent on both the meteorological drivers and differences in leaf age, position within the canopy, nitrogen and CO2 fertilization, which can be accommodated in model parameters; (b) Meteorological variability plays the dominant role at short temporal scales while parameter variability is significant at longer temporal scales. (c) Leaf level results do not necessarily translate to similar ecosystem

  11. Reducing energy consumption and CO2 emissions by energy efficiency measures and international trading: A bottom-up modeling for the U.S. iron and steel sector

    International Nuclear Information System (INIS)

    Karali, Nihan; Xu, Tengfang; Sathaye, Jayant

    2014-01-01

    Highlights: • Use ISEEM to evaluate energy and emission reduction in U.S. Iron and Steel sector. • ISEEM is a new bottom-up optimization model for industry sector energy planning. • Energy and emission reduction includes efficiency measure and international trading. • International trading includes commodity and carbon among U.S., China and India. • Project annual energy use, CO 2 emissions, production, and costs from 2010 to 2050. - Abstract: Using the ISEEM modeling framework, we analyzed the roles of energy efficiency measures, steel commodity and international carbon trading in achieving specific CO 2 emission reduction targets in the U.S iron and steel sector from 2010 to 2050. We modeled how steel demand is balanced under three alternative emission reduction scenarios designed to include national energy efficiency measures, commodity trading, and international carbon trading as key instruments to meet a particular emission restriction target in the U.S. iron and steel sector; and how production, process structure, energy supply, and system costs change with those scenarios. The results advance our understanding of long-term impacts of different energy policy options designed to reduce energy consumption and CO 2 emissions for U.S. iron and steel sector, and generate insight of policy implications for the sector’s environmentally and economically sustainable development. The alternative scenarios associated with 20% emission-reduction target are projected to result in approximately 11–19% annual energy reduction in the medium term (i.e., 2030) and 9–20% annual energy reduction in the long term (i.e., 2050) compared to the Base scenario

  12. International network non-energy use and CO2 emissions (NEU-CO2). An activity within the European Commission's ENRICH programme, DG RTD, 'Environment and Climate'. Final report of the first phase of the network (January 1999 - June 2000)

    International Nuclear Information System (INIS)

    Patel, M.; Gielen, D.; Kilde, N.; Simmons, T.

    2000-07-01

    This report concludes the first phase of the NEU-CO 2 network, covering the period from January 1999 to June 2000. Within this period, two workshops were held, one in Paris in September 1999 and the other in Brussels in April 2000. The results of these workshops represent the basis of this report. The workshop papers have also been compiled in workshop proceedings which are publicly available. Due to the success of the NEU-CO 2 network, the partners decided to apply for the continuation of this activity which was recently accepted by the European Commission. The second phase of the of the NEU-CO 2 network will start in Fall 2000 and will continue for 18 months. This will allow the NEU-CO 2 network to improve the methods applied, to close data gaps, to check the preliminary conclusions given in this report and to provide consolidated results and recommendations by mid 2002. The ultimate goal of the NEU-CO 2 network is to contribute to an improvement of the IPCC guidelines in the area of non-energy use and to provide inventorists with tools and methods to estimate more accurately non-energy CO 2 emissions. (orig.)

  13. CO2 blood test

    Science.gov (United States)

    Bicarbonate test; HCO3-; Carbon dioxide test; TCO2; Total CO2; CO2 test - serum; Acidosis - CO2; Alkalosis - CO2 ... Many medicines can interfere with blood test results. Your health ... need to stop taking any medicines before you have this test. DO ...

  14. CO2 sequestration

    International Nuclear Information System (INIS)

    Favre, E.; Jammes, L.; Guyot, F.; Prinzhofer, A.; Le Thiez, P.

    2009-01-01

    This document presents the summary of a conference-debate held at the Academie des Sciences (Paris, France) on the topic of CO 2 sequestration. Five papers are reviewed: problems and solutions for the CO 2 sequestration; observation and surveillance of reservoirs; genesis of carbonates and geological storage of CO 2 ; CO 2 sequestration in volcanic and ultra-basic rocks; CO 2 sequestration, transport and geological storage: scientific and economical perspectives

  15. Effect of Leaf Water Potential on Internal Humidity and CO2 Dissolution: Reverse Transpiration and Improved Water Use Efficiency under Negative Pressure.

    Science.gov (United States)

    Vesala, Timo; Sevanto, Sanna; Grönholm, Tiia; Salmon, Yann; Nikinmaa, Eero; Hari, Pertti; Hölttä, Teemu

    2017-01-01

    The pull of water from the soil to the leaves causes water in the transpiration stream to be under negative pressure decreasing the water potential below zero. The osmotic concentration also contributes to the decrease in leaf water potential but with much lesser extent. Thus, the surface tension force is approximately balanced by a force induced by negative water potential resulting in concavely curved water-air interfaces in leaves. The lowered water potential causes a reduction in the equilibrium water vapor pressure in internal (sub-stomatal/intercellular) cavities in relation to that over water with the potential of zero, i.e., over the flat surface. The curved surface causes a reduction also in the equilibrium vapor pressure of dissolved CO 2 , thus enhancing its physical solubility to water. Although the water vapor reduction is acknowledged by plant physiologists its consequences for water vapor exchange at low water potential values have received very little attention. Consequences of the enhanced CO 2 solubility to a leaf water-carbon budget have not been considered at all before this study. We use theoretical calculations and modeling to show how the reduction in the vapor pressures affects transpiration and carbon assimilation rates. Our results indicate that the reduction in vapor pressures of water and CO 2 could enhance plant water use efficiency up to about 10% at a leaf water potential of -2 MPa, and much more when water potential decreases further. The low water potential allows for a direct stomatal water vapor uptake from the ambient air even at sub-100% relative humidity values. This alone could explain the observed rates of foliar water uptake by e.g., the coastal redwood in the fog belt region of coastal California provided the stomata are sufficiently open. The omission of the reduction in the water vapor pressure causes a bias in the estimates of the stomatal conductance and leaf internal CO 2 concentration based on leaf gas exchange

  16. Foraminiferal calcification and CO2

    Science.gov (United States)

    Nooijer, L. D.; Toyofuku, T.; Reichart, G. J.

    2017-12-01

    Ongoing burning of fossil fuels increases atmospheric CO2, elevates marine dissolved CO2 and decreases pH and the saturation state with respect to calcium carbonate. Intuitively this should decrease the ability of CaCO3-producing organisms to build their skeletons and shells. Whereas on geological time scales weathering and carbonate deposition removes carbon from the geo-biosphere, on time scales up to thousands of years, carbonate precipitation increases pCO2 because of the associated shift in seawater carbon speciation. Hence reduced calcification provides a potentially important negative feedback on increased pCO2 levels. Here we show that foraminifera form their calcium carbonate by active proton pumping. This elevates the internal pH and acidifies the direct foraminiferal surrounding. This also creates a strong pCO2 gradient and facilitates the uptake of DIC in the form of carbon dioxide. This finding uncouples saturation state from calcification and predicts that the added carbon due to ocean acidification will promote calcification by these organisms. This unknown effect could add substantially to atmospheric pCO2 levels, and might need to be accounted for in future mitigation strategies.

  17. CO2NNIE

    DEFF Research Database (Denmark)

    Krogh, Benjamin Bjerre; Andersen, Ove; Lewis-Kelham, Edwin

    2015-01-01

    We propose a system for calculating the personalized annual fuel consumption and CO2 emissions from transportation. The system, named CO2NNIE, estimates the fuel consumption on the fastest route between the frequent destinations of the user. The travel time and fuel consumption estimated are based......% of the actual fuel consumption (4.6% deviation on average). We conclude, that the system provides new detailed information on CO2 emissions and fuel consumption for any make and model....

  18. FY 2000 report on the promotion projects by Research Institute of Innovative Technology for the Earth. Proceedings of the international seminar (Reports on photosynthetic CO2-assimilating enzymes by the international workshops); 2000 nendo chikyu kankyo sangyo gijutsu kaihatsu suishin jigyo kokusai seminar jigyo shiryo. Kogosei CO2 kotei koso kokusai workshop hokokusho

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the reports on photosynthetic CO2-assimilating enzymes, presented to the international symposium. These enzymes are important for assimilating CO2 in air, maintaining the environments and production of foods. For genes and proteins, the topics include diversification and function evolution of the RuBisCO (ribulose 1,5-bisphosphate carboxylase/oxygenase) in the natural environments, in particular in microorganisms. For activity regulation of PEPC, the topics include three-dimensional structures of PEPC and phosphorylation mechanisms and activity regulation therefor. For activity regulation of RuBisCO, the topics include post-translational activity of the enzymes (e.g., methylated enzyme); molecular regulation mechanisms involved in the biosynthesis and decomposition of RuBisCO; and activity regulation mechanisms in the chloroplast. For leaf photosynthesis and RuBisCO, the topics include importance of enzymes and involved in-vivo reaction steps for leaf photosynthesis CO2 assimilation reactions. For function of PEPC, the topics include the biochemically and molecular biologically necessary and sufficient conditions for the C4 mechanism as the special photosynthesis mechanism. For transgenic approaches, the topics include procedure for allowing the RuBisCO gene of a dissimilar organism to function in the tobacco chloroplast, and introduction of enzymes involved in the C4 photosynthesis pathway in C3 plants. (NEDO)

  19. CO2-laser fusion

    International Nuclear Information System (INIS)

    Stark, E.E. Jr.

    1978-01-01

    The basic concept of laser fusion is described, with a set of requirements on the laser system. Systems and applications concepts are presented and discussed. The CO 2 laser's characteristics and advantages for laser fusion are described. Finally, technological issues in the development of CO 2 laser systems for fusion applications are discussed

  20. Feasible study of international cooperation on the long-term scenario for reducing CO2. DNE-21 simulation database; CO2 sakugen ni kakawaru choki scenario ni kansuru kokusai kyoryoku kanosei chosa. DNE21 simulation database

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-03-01

    This report describes calculation codes of DNE-21 which can simulate the optimization model for reducing CO2. The DNE-21 was modified from the former NE-21. The term was set between 2000 and 2100. Optimization can be conducted across the different time. Non-conventional petroleum was removed from the primary energy. Capacity of nuclear power generation facilities was taken in the model for the optimization. Decision making analysis can be done by considering the uncertainty. The DNE-21 has eleven input files including the model operation, technical property related data, cost related data, data of tax, subsidy and customs, and scenario data of future energy demand and supply, GNP, population and nuclear power. The DNE-21 has fifteen output files including the optimization calculation results for the world, Oceania, the Middle East, North Africa, Central America, South America, former USSR, and OECD countries. 2 figs.

  1. Interactive effects of high CO2 and SO2 on growth and antioxidant levels in wheat

    NARCIS (Netherlands)

    Rao, M.V.; De Kok, L.J.

    1994-01-01

    The impact of elevated CO2 and/or SO2 on the growth and antioxidant levels of wheat {Triticum aestivum L. cv. Urban) plants has been studied. High CO2 (0.7 ml I-1) significantly enhanced shoot biomass and photosynthetic capacity, while exposure to SO2 (0.14 ul I-1) resulted in a decreased shoot

  2. Outsourcing CO2 Emissions

    Science.gov (United States)

    Davis, S. J.; Caldeira, K. G.

    2009-12-01

    CO2 emissions from the burning of fossil fuels are the primary cause of global warming. Much attention has been focused on the CO2 directly emitted by each country, but relatively little attention has been paid to the amount of emissions associated with consumption of goods and services in each country. This consumption-based emissions inventory differs from the production-based inventory because of imports and exports of goods and services that, either directly or indirectly, involved CO2 emissions. Using the latest available data and reasonable assumptions regarding trans-shipment of embodied carbon through third-party countries, we developed a global consumption-based CO2 emissions inventory and have calculated associated consumption-based energy and carbon intensities. We find that, in 2004, 24% of CO2 emissions are effectively outsourced to other countries, with much of the developed world outsourcing CO2 emissions to emerging markets, principally China. Some wealthy countries, including Switzerland and Sweden, outsource over half of their consumption-based emissions, with many northern Europeans outsourcing more than three tons of emissions per person per year. The United States is both a big importer and exporter of emissions embodied in trade, outsourcing >2.6 tons of CO2 per person and at the same time as >2.0 tons of CO2 per person are outsourced to the United States. These large flows indicate that CO2 emissions embodied in trade must be taken into consideration when considering responsibility for increasing atmospheric greenhouse gas concentrations.

  3. The CO2nnect activities

    Science.gov (United States)

    Eugenia, Marcu

    2014-05-01

    Climate change is one of the biggest challenges we face today. A first step is the understanding the problem, more exactly what is the challenge and the differences people can make. Pupils need a wide competencies to meet the challenges of sustainable development - including climate change. The CO2nnect activities are designed to support learning which can provide pupils the abilities, skills, attitudes and awareness as well as knowledge and understanding of the issues. The project "Together for a clean and healthy world" is part of "The Global Educational Campaign CO2nnect- CO2 on the way to school" and it was held in our school in the period between February and October 2009. It contained a variety of curricular and extra-curricular activities, adapted to students aged from 11 to 15. These activities aimed to develop in students the necessary skills to understanding man's active role in improving the quality of the environment, putting an end to its degrading process and to reducing the effects of climate changes caused by the human intervention in nature, including transport- a source of CO2 pollution. The activity which I propose can be easily adapted to a wide range of age groups and linked to the curricula of many subjects: - Investigate CO2 emissions from travel to school -Share the findings using an international database -Compare and discuss CO2 emissions -Submit questions to a climate- and transport expert -Partner with other schools -Meet with people in your community to discuss emissions from transport Intended learning outcomes for pupils who participate in the CO2nnect campaign are: Understanding of the interconnected mobility- and climate change issue climate change, its causes and consequences greenhouse-gas emissions from transport and mobility the interlinking of social, environmental, cultural and economic aspects of the local transport system how individual choices and participation can contribute to creating a more sustainable development

  4. Clean Coal: myth or reality? At the heart of the energy-climate equation, capturing and storing CO2 - Proceedings of the 2007 Le Havre's international meetings

    International Nuclear Information System (INIS)

    Rufenacht, Antoine; Brodhag, Christian; Mocilnikar, Antoine-Tristan; Bennaceur, Kamel; Esseid, Ablaziz; Lemoine, Stephane; Prevot, Henri; Diercks, Thorsten; Jaclot, Francois; Fache, Dominique; Coulon, Pierre-Jean; Capris, Renaud; TRANIE, Jean-Pascal; Le Thiez, Pierre; Marliave, Luc de; Perrin, Nicolas; Paelinck, Philippe; Clodic, Denis; Thabussot, Laurent; Alf, Martin; Boon, Gustaaf; Giger, Francois; Bisseaud, Jean-Michel; Michel, Patrick; Poyer, Luc; Biebuyck, Christian; Kalaydjian, Francois; Roulet, Claude; Bonijoly, Didier; Gresillon, Francois Xavier; Bonneville, Alain; Tauziede, Christian; Munier, Gilles; Moncomble, Jean-Eudes; Frois, Bernard; Charmant, Marcel; Thybaud, Nathalie; Fares, Tewfik; Lacave, Jean-Marc; Duret, Benoit; Gerard, Bernard

    2007-03-01

    This document comprises the French and English versions of the executive summary of the RIH 2007 meetings, followed by the available presentations (slides). Content: - Symposium Opening: Government and the Coal Issue; 1 - First Session - Energy, Climate, Coal: - Scenarios for energy technologies and CO 2 emissions: Energy outlooks, CO 2 emissions, Technologies (Kamel BENNACEUR); - The global situation of coal: The situation of the international steam coal market, Change in this market, Total's position in this business, Major challenges for the future (Ablaziz ESSEID); - Coal markets: availability, competitiveness, and growing maturity (Stephane LEMOINE); - Coal in the geopolitics of greenhouse gases (Henri PREVOT); - Questions; 2 - Second Session - Coal Economy: - Opportunities and challenges for coal in the European energy mix: the Commission's energy package: The European situation, The European energy mix, The role of EURACOAL (Thorsten DIERCKS); - The development of a coal bed in Lucenay-les-Aix and Cossaye in the Massif Central (Francois JACLOT); - The Russian view of coal's place in the energy mix (Dominique FACHE); - Coal, a key to development in Niger (Pierre-Jean COULON); - The energy and environmental efficiency of coal-fired power plants associated with heating networks (Renaud CAPRIS); - The Valorca project: efficient and immediate use of coal, and strong outlooks for the future (Jean-Pascal TRANIE); - Questions; 3 - Third and Forth Sessions - Clean Power Plants: - CO 2 capture systems (Pierre LE THIEZ); - CO 2 geological capture and storage in the Lacq basin (Luc de MARLIAVE); - Clean coal: Air Liquide technology developments and industrial solutions (Nicolas PERRIN); - Clean combustion and CO 2 (Philippe PAELINCK); - CO 2 capture by freezing/defrosting at low temperatures (Denis CLODIC); - Questions; - Using the experience of a large corporation (ENDESA), to develop clean energy: coal (Laurent THABUSSOT); - Pathways to reduce CO 2

  5. CO2 chemical valorization

    International Nuclear Information System (INIS)

    Kerlero De Rosbo, Guillaume; Rakotojaona, Loic; Bucy, Jacques de; Clodic, Denis; Roger, Anne-Cecile; El Khamlichi, Aicha; Thybaud, Nathalie; Oeser, Christian; Forti, Laurent; Gimenez, Michel; Savary, David; Amouroux, Jacques

    2014-07-01

    Facing global warming, different technological solutions exist to tackle carbon dioxide (CO 2 ) emissions. Some inevitable short term emissions can be captured so as to avoid direct emissions into the atmosphere. This CO 2 must then be managed and geological storage seems to currently be the only way of dealing with the large volumes involved. However, this solution faces major economic profitability and societal acceptance challenges. In this context, alternative pathways consisting in using CO 2 instead of storing it do exist and are generating growing interest. This study ordered by the French Environment and Energy Management Agency (ADEME), aims at taking stock of the different technologies used for the chemical conversion of CO 2 in order to have a better understanding of their development potential by 2030, of the conditions in which they could be competitive and of the main actions to be implemented in France to foster their emergence. To do this, the study was broken down into two main areas of focus: The review and characterization of the main CO 2 chemical conversion routes for the synthesis of basic chemical products, energy products and inert materials. This review includes a presentation of the main principles underpinning the studied routes, a preliminary assessment of their performances, advantages and drawbacks, a list of the main R and D projects underway, a focus on emblematic projects as well as a brief analysis of the markets for the main products produced. Based on these elements, 3 routes were selected from among the most promising by 2030 for an in-depth modelling and assessment of their energy, environmental and economic performances. The study shows that the processes modelled do have favorable CO 2 balances (from 1 to 4 t-CO 2 /t-product) and effectively constitute solutions to reduce CO 2 emissions, despite limited volumes of CO 2 in question. Moreover, the profitability of certain solutions will remain difficult to reach, even with an

  6. CO2 storage in Sweden

    International Nuclear Information System (INIS)

    Ekstroem, Clas; Andersson, Annika; Kling, Aasa; Bernstone, Christian; Carlsson, Anders; Liljemark, Stefan; Wall, Caroline; Erstedt, Thomas; Lindroth, Maria; Tengborg, Per; Edstroem, Mikael

    2004-07-01

    with the expansions of natural gas networks for Sweden should be looked for. Issues that need more deep studies are how the injection infrastructures for aquifers need to be modified compared to those used for oil fields, successively improved validation of CO 2 handling costs for Europe and Sweden, regarding i.a. ship transport and industrial compression and cooling of large CO 2 flows in connection to CO 2 capture. It is likely that the local environment would be affected by a possible leakage. Many organisms and ecosystems are sensitive to small changes in the CO 2 concentration. Knowledge exists on how humans, animals and plants would be affected by enhanced contents of carbon dioxide in their immediate surroundings, and on how the physical part of soils and water would be influenced by higher CO 2 concentrations. How individual ecosystems would be affected will have to be assessed based on the conditions in each specific system. Further studies are needed on consequences for ecosystems, especially for ecosystems in the ground, particularly those deep in the ground. Severe environmental damages (large short-term emissions that would damage the surrounding environment, i.e. concentrations around 25 % CO 2 ) would be limited to a few tens of meters from the plant and will therefore not need to be considered. No calculations have been performed for any transport means besides pipelines. Two parallels to CO 2 transport and storage are geothermic projects and natural gas pipelines. For geothermic projects there is a basic positive attitude already before the project start and the operations take place deep in the ground, i.e. at a safe distance from those concerned, and no threatening picture has been felt. No overall legal framework applicable to CO 2 transport and storage exist today, neither within the national Swedish law nor within international/European law. There are however adjacent legal frameworks mainly regarding transport. Providing that the construction of

  7. Shooting stars

    International Nuclear Information System (INIS)

    Maurette, M.; Hammer, C.

    1985-01-01

    A shooting star passage -even a star shower- can be sometimes easily seen during moonless black night. They represent the partial volatilization in earth atmosphere of meteorites or micrometeorites reduced in cosmic dusts. Everywhere on earth, these star dusts are searched to be gathered. This research made one year ago on the Greenland ice-cap is this article object; orbit gathering projects are also presented [fr

  8. CO2 cycle

    Science.gov (United States)

    Titus, Timothy N.; Byrne, Shane; Colaprete, Anthony; Forget, Francois; Michaels, Timothy I.; Prettyman, Thomas H.

    2017-01-01

    This chapter discusses the use of models, observations, and laboratory experiments to understand the cycling of CO2 between the atmosphere and seasonal Martian polar caps. This cycle is primarily controlled by the polar heat budget, and thus the emphasis here is on its components, including solar and infrared radiation, the effect of clouds (water- and CO2-ice), atmospheric transport, and subsurface heat conduction. There is a discussion about cap properties including growth and regression rates, albedos and emissivities, grain sizes and dust and/or water-ice contamination, and curious features like cold gas jets and araneiform (spider-shaped) terrain. The nature of the residual south polar cap is discussed as well as its long-term stability and ability to buffer atmospheric pressures. There is also a discussion of the consequences of the CO2 cycle as revealed by the non-condensable gas enrichment observed by Odyssey and modeled by various groups.

  9. FY 2000 Project of developing international standards for supporting new industries. Standardization of the marine environment analyzers (Analyzers for measuring CO2 in ocean); 2000 nendo shinki sangyo shiengata kokusai hyojun kaihatsu jigyo seika hokokusho. Kaiyo kankyo keisoku kiki (kaiyo CO2 sokutei kanren kikirui) no hyojunka

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2001-03-01

    Described herein are the FY 2000 results of the research and development of analyzers and analytical procedures necessary for evaluating CO2 abatement effects and fixed quantities in ocean, for proposing the international standards. The program for studying the analytical procedures makes a literature survey mainly on papers and also on patent publications, to collect the data related to this project and establish the database. The program for measuring CO2 in deep ocean studies a suspension type CO2 profiler with a liquid-liquid leveler and develops a small-size, high-precision device serviceable at a depth of 3,000m, around 1m in length and 40kg in weight. The program for flux meters tests various commercial sensors, to obtain the design requirements for the sensor of improved functions to withstand splashes and rolling/pitching. The program for CO2 flux measurement methods study aims at the eddy correlation method, which is the most direct procedure involving limited number of assumptions, after having investigated various procedures, to improve precision of the sensor. (NEDO)

  10. CO2-strategier

    DEFF Research Database (Denmark)

    Jørgensen, Michael Søgaard

    2008-01-01

    I 2007 henvendte Lyngby-Taarbæk kommunens Agenda 21 koordinator sig til Videnskabsbutikken og spurgte om der var interesse for at samarbejde om CO2-strategier. Da Videnskabsbutikken DTU er en åben dør til DTU for borgerne og deres organisationer, foreslog Videnskabsbutikken DTU at Danmarks...

  11. High-flux MFI-alumina hollow fibres: a membrane-based process for on-board CO2 capture from internal combustion vehicles

    International Nuclear Information System (INIS)

    Nicolas, C.H.

    2011-01-01

    This work focuses on the conception and development of a membrane-based process for an on-board CO 2 capture/storage application. In a first part, we simulate an on-board CO 2 capture unit based on a membrane process for the case study of a heavy vehicle (≥3500 kg). This study includes an energy analysis of the impact of gas separation and compression on the required membrane surface and module volume, as well the autonomy of the storage unit and the energy overconsumption involved in the process. In a second part, we study the influence of the hollow-fibre support quality on the final intergrowth level of nano-composite MFI-alumina membranes. Special attention is devoted to the influence of the isomorphic substitution of silica by boron and germanium, and replacement of the counter-cation (proton) by other elements, on the CO 2 /N 2 separation and permeance properties. Next, a complete chapter has been devoted to the evaluation of the thermodynamic (adsorption) and kinetic (diffusion) parameters in the CO 2 /N 2 separation. Finally, we analyze the influence of standard pollutants (water, NO x , hydrocarbons) on the CO 2 separation properties of the synthesized membranes. (author)

  12. CO2-neutral fuels

    Directory of Open Access Journals (Sweden)

    Goede A. P. H.

    2015-01-01

    Full Text Available The need for storage of renewable energy (RE generated by photovoltaic, concentrated solar and wind arises from the fact that supply and demand are ill-matched both geographically and temporarily. This already causes problems of overcapacity and grid congestion in countries where the fraction of RE exceeds the 20% level. A system approach is needed, which focusses not only on the energy source, but includes conversion, storage, transport, distribution, use and, last but not least, the recycling of waste. Furthermore, there is a need for more flexibility in the energy system, rather than relying on electrification, integration with other energy systems, for example the gas network, would yield a system less vulnerable to failure and better adapted to requirements. For example, long-term large-scale storage of electrical energy is limited by capacity, yet needed to cover weekly to seasonal demand. This limitation can be overcome by coupling the electricity net to the gas system, considering the fact that the Dutch gas network alone has a storage capacity of 552 TWh, sufficient to cover the entire EU energy demand for over a month. This lecture explores energy storage in chemicals bonds. The focus is on chemicals other than hydrogen, taking advantage of the higher volumetric energy density of hydrocarbons, in this case methane, which has an approximate 3.5 times higher volumetric energy density. More importantly, it allows the ready use of existing gas infrastructure for energy storage, transport and distribution. Intermittent wind electricity generated is converted into synthetic methane, the Power to Gas (P2G scheme, by splitting feedstock CO2 and H2O into synthesis gas, a mixture of CO and H2. Syngas plays a central role in the synthesis of a range of hydrocarbon products, including methane, diesel and dimethyl ether. The splitting is accomplished by innovative means; plasmolysis and high-temperature solid oxygen electrolysis. A CO2-neutral fuel

  13. Outsourcing CO2 within China.

    Science.gov (United States)

    Feng, Kuishuang; Davis, Steven J; Sun, Laixiang; Li, Xin; Guan, Dabo; Liu, Weidong; Liu, Zhu; Hubacek, Klaus

    2013-07-09

    Recent studies have shown that the high standard of living enjoyed by people in the richest countries often comes at the expense of CO2 emissions produced with technologies of low efficiency in less affluent, developing countries. Less apparent is that this relationship between developed and developing can exist within a single country's borders, with rich regions consuming and exporting high-value goods and services that depend upon production of low-cost and emission-intensive goods and services from poorer regions in the same country. As the world's largest emitter of CO2, China is a prominent and important example, struggling to balance rapid economic growth and environmental sustainability across provinces that are in very different stages of development. In this study, we track CO2 emissions embodied in products traded among Chinese provinces and internationally. We find that 57% of China's emissions are related to goods that are consumed outside of the province where they are produced. For instance, up to 80% of the emissions related to goods consumed in the highly developed coastal provinces are imported from less developed provinces in central and western China where many low-value-added but high-carbon-intensive goods are produced. Without policy attention to this sort of interprovincial carbon leakage, the less developed provinces will struggle to meet their emissions intensity targets, whereas the more developed provinces might achieve their own targets by further outsourcing. Consumption-based accounting of emissions can thus inform effective and equitable climate policy within China.

  14. CO2 flowrate calculator

    International Nuclear Information System (INIS)

    Carossi, Jean-Claude

    1969-02-01

    A CO 2 flowrate calculator has been designed for measuring and recording the gas flow in the loops of Pegase reactor. The analog calculator applies, at every moment, Bernoulli's formula to the values that characterize the carbon dioxide flow through a nozzle. The calculator electronics is described (it includes a sampling calculator and a two-variable function generator), with its amplifiers, triggers, interpolator, multiplier, etc. Calculator operation and setting are presented

  15. Large CO2 Sinks: Their role in the mitigation of greenhouse gases from an international, national (Canadian) and provincial (Alberta) perspective

    International Nuclear Information System (INIS)

    Gunter, W.D.; Wong, S.; Cheel, D.B.; Sjostrom, G.

    1998-01-01

    Significant reduction of CO 2 emissions on a global scale may be achieved by reduction of energy intensity, by reduction of carbon intensity or by capture and storage of CO 2 . A portfolio of these methods is required to achieve the large reductions required; of which utilization of carbon sinks (i.e. material, geosphere and biosphere) will be an important player. Material sinks will probably only play a minor role as compared to biosphere and geosphere sinks in storage of CO 2 . Biosphere sinks are attractive because they can sequester CO 2 from a diffuse source whereas geosphere sinks require a pure waste stream of CO 2 (obtained by using expensive separation methods). On the other hand, environmental factors and storage time favor geosphere sinks. It is expected that a combination of the two will be used in order to meet emission reduction targets over the next 100 yr.A critical look is taken at capacities, retention/residence times, rates of uptake and relative cost of utilization of biosphere and geosphere sinks at three scales - global, national (Canada) and provincial (Alberta). Biosphere sinks considered are oceans, forests and soils. Geosphere sinks considered are enhanced oil recovery, coal beds, depleted oil and gas reservoirs and deep aquifers. The largest sinks are oceans and deep aquifers. The other biosphere and geosphere sinks have total capacities approximately of an order of lower magnitude. The sinks that will probably be used first are those that are economically viable such as enhanced oil-recovery, agriculture, forestry and possibly enhanced coalbed methane-recovery. The other sinks will be used when these options have been exhausted or are not available or a penalty (e.g. carbon tax) exists. Although the data tabulated for these sinks is only regarded as preliminary, it provides a starting point for assessment of the role of large sinks in meeting greenhouse gas emission reduction targets. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam

  16. CO2 laser development

    International Nuclear Information System (INIS)

    Anon.

    1976-01-01

    The research and development programs on high-energy, short-pulse CO 2 lasers were begun at LASL in 1969. Three large systems are now either operating or are being installed. The Single-Beam System (SBS), a four-stage prototype, was designed in 1971 and has been in operation since 1973 with an output energy of 250 J in a 1-ns pulse with an on-target intensity of 3.5 x 10 14 W/cm 2 . The Dual-Beam System (DBS), now in the final stages of electrical and optical checkout, will provide about ten times more power for two-beam target irradiation experiments. Four such dual-beam modules are being installed in the Laser-Fusion Laboratory to provide an Eight-Beam System (EBS) scheduled for operation at the 5- to 10-TW level in 1977. A fourth system, a 100- to 200-TW CO 2 laser, is being designed for the High-Energy Gas Laser Facility (HEGLF) program

  17. CO2 emissions of nuclear power supply

    International Nuclear Information System (INIS)

    Wissel, S.; Mayer-Spohn, O.; Fahl, U.; Voss, A.

    2007-01-01

    Increasingly, supported by the recent reports of the IPCC (International Panel on Climate Change), political, social and scientific institutions call for the use of atomic energy for reducing CO2 emissions. In Germany, the discussion is highly controversial. A life-cycle balance of nuclear power shows that its CO2 emissions are much lower than those of other technologies, even if changes in the nuclear fuel cycle are taken into account. (orig.)

  18. Studies on CO2 removal and reduction. CO2 taisaku kenkyu no genjo

    Energy Technology Data Exchange (ETDEWEB)

    Shindo, Y [National Institute of Materials and Chemical Research, Tsukuba (Japan)

    1993-02-01

    This paper summarizes study trends mainly in CO2 fixing processes. Underground CO2 storage is a most promising method because it can fix a huge amount of CO2 and has low effects on ecological systems. Storing CO2 in ocean includes such methods as storing it in deep oceans; storing it in deep ocean beds; dissolving it into sea water; neutralizing it with calcium carbonates; and precipitating it as dry ice. Japan, disposing CO2 in these ways, may create international problems. Separation of CO2 may use a chemical absorption process as a superior method. Other processes discussed include a physical adsorption method and a membrane separation method. A useful method for CO2 fixation using marine organisms is fixation using coral reefs. This process will require an overall study including circulation of phosphorus and nitrogen. Marine organisms may include planktons and algae. CO2 fixation using land plants may be able to fix one trillion and 8 hundred billion tons of CO2 as converted to carbon. This process would require forest protection, prevention of desertification, and tree planting. Discussions are being given also on improving power generation cycles, recovering CO2 from automotive exhausts, and backfilling carbons into ground by means of photosynthesis. 23 refs., 7 figs., 1 tab.

  19. Response of Sphagnum mosses to increased CO2 concentration and nitrogen deposition

    International Nuclear Information System (INIS)

    Jauhiainen, J.

    1998-01-01

    The main objective of this work was to study the effects of different CO 2 concentration and N deposition rates on Sphagna adapted to grow along a nutrient availability gradient (i.e. ombrotrophy-mesotrophy-eutrophy). The study investigated: (i) the effects of various longterm CO 2 concentrations on the rate of net photosynthesis in Sphagna, (ii) the effects of the CO 2 and N treatments on the moss density, shoot dry masses, length increment and dry mass production in Sphagna, (iii) the concentrations of the major nutrients in Sphagna after prolonged exposure to the CO 2 and N treatments, and (iv) species dependent differences in potential NH 4 + and NO 3 - uptake rates. The internal nutrient concentration of the capitulum and the production of biomass were effected less by the elevated CO 2 concentrations because the availability of N was a controlling factor. In addition responses to the N treatments were related to ecological differences between the Sphagna species. Species with a high tolerance of N availability were able to acclimatise to the increased N deposition rates. The data suggests a high nutrient status is less significant than the adaptation of the Sphagna to their ecological niche (e.g. low tolerance of meso-eutrophic S. warnstorfii to high N deposition rate). At the highest N deposition rate the ombrotrophic S. fuscum had the highest increase in tissue N concentration among the Sphagna studied. S. fuscum almost died at the highest N deposition rate because of the damaging effects of N to the plant's metabolism. Ombrotrophic hummock species such as S. fuscum, were also found to have the highest potential N uptake rate (on density of dry mass basis) compared to lawn species. The rate of net photosynthesis was initially increased with elevated CO 2 concentrations, but photosynthesis was down regulated with prolonged exposure to CO 2 . The water use efficiency in Sphagna appeared not to be coupled with exposure to the long-term CO 2 concentration. The

  20. Outsourcing CO2 within China

    Science.gov (United States)

    Feng, Kuishuang; Davis, Steven J.; Sun, Laixiang; Li, Xin; Guan, Dabo; Liu, Weidong; Liu, Zhu; Hubacek, Klaus

    2013-01-01

    Recent studies have shown that the high standard of living enjoyed by people in the richest countries often comes at the expense of CO2 emissions produced with technologies of low efficiency in less affluent, developing countries. Less apparent is that this relationship between developed and developing can exist within a single country’s borders, with rich regions consuming and exporting high-value goods and services that depend upon production of low-cost and emission-intensive goods and services from poorer regions in the same country. As the world’s largest emitter of CO2, China is a prominent and important example, struggling to balance rapid economic growth and environmental sustainability across provinces that are in very different stages of development. In this study, we track CO2 emissions embodied in products traded among Chinese provinces and internationally. We find that 57% of China’s emissions are related to goods that are consumed outside of the province where they are produced. For instance, up to 80% of the emissions related to goods consumed in the highly developed coastal provinces are imported from less developed provinces in central and western China where many low–value-added but high–carbon-intensive goods are produced. Without policy attention to this sort of interprovincial carbon leakage, the less developed provinces will struggle to meet their emissions intensity targets, whereas the more developed provinces might achieve their own targets by further outsourcing. Consumption-based accounting of emissions can thus inform effective and equitable climate policy within China. PMID:23754377

  1. CO2 Laser Market

    Science.gov (United States)

    Simonsson, Samuel

    1989-03-01

    It gives me a great deal of pleasure to introduce our final speaker of this morning's session for two reasons: First of all, his company has been very much in the news not only in our own community but in the pages of Wall Street Journal and in the world economic press. And, secondly, we would like to welcome him to our shores. He is a temporary resident of the United States, for a few months, forsaking his home in Germany to come here and help with the start up of a new company which we believe, probably, ranks #1 as the world supplier of CO2 lasers now, through the combination of former Spectra Physics Industrial Laser Division and Rofin-Sinar GMBH. Samuel Simonsson is the Chairman of the Board of Rofin-Sinar, Inc., here in the U.S. and managing director of Rofin-Sinar GMBH. It is a pleasure to welcome him.

  2. CO2 Emissions from Fuel Combustion 2011: Highlights

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    How much CO2 are countries emitting? Where is it coming from? In the lead-up to the UN climate negotiations in Durban, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process the IEA is making available for free download the 'Highlights' version of CO2 Emissions from Fuel Combustion. This annual publication contains: - estimates of CO2 emissions by country from 1971 to 2009; - selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; - CO2 emissions from international marine and aviation bunkers, and other relevant information. These estimates have been calculated using the IEA energy databases and the default methods and emission factors from the Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories.

  3. CO2 Emissions from Fuel Combustion - 2012 Highlights

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    How much CO2 are countries emitting? Where is it coming from? In the lead-up to the UN climate negotiations in Doha, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process the IEA is making available for free download the 'Highlights' version of CO2 Emissions from Fuel Combustion. This annual publication contains: estimates of CO2 emissions by country from 1971 to 2010; selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; and CO2 emissions from international marine and aviation bunkers, and other relevant information.

  4. CO2 Emissions from Fuel Combustion 2011: Highlights

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2011-07-01

    How much CO2 are countries emitting? Where is it coming from? In the lead-up to the UN climate negotiations in Durban, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process the IEA is making available for free download the 'Highlights' version of CO2 Emissions from Fuel Combustion. This annual publication contains: - estimates of CO2 emissions by country from 1971 to 2009; - selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; - CO2 emissions from international marine and aviation bunkers, and other relevant information. These estimates have been calculated using the IEA energy databases and the default methods and emission factors from the Revised 1996 IPCC Guidelines for National Greenhouse Gas Inventories.

  5. CO2 Emissions from Fuel Combustion - 2012 Highlights

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-07-01

    How much CO2 are countries emitting? Where is it coming from? In the lead-up to the UN climate negotiations in Doha, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process the IEA is making available for free download the 'Highlights' version of CO2 Emissions from Fuel Combustion. This annual publication contains: estimates of CO2 emissions by country from 1971 to 2010; selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; and CO2 emissions from international marine and aviation bunkers, and other relevant information.

  6. CO2 hydrogenation to hydrocarbons over iron nanoparticles ...

    Indian Academy of Sciences (India)

    481–486. c Indian Academy of Sciences. CO2 ... degrees of CO2 conversion shows that reverse water gas shift equilibrium had been ... rise in CO2 emission.1 Additionally, depletion in crude .... detectors (FID) using argon as internal standard.

  7. Geological storage of CO2

    International Nuclear Information System (INIS)

    Czernichowski-Lauriol, I.

    2005-01-01

    The industrial storage of CO 2 is comprised of three steps: - capture of CO 2 where it is produced (power plants, cement plants, etc.); - transport (pipe lines or boats); - storage, mainly underground, called geological sequestration... Three types of reservoirs are considered: - salted deep aquifers - they offer the biggest storage capacity; - exhausted oil and gas fields; - non-exploited deep coal mine streams. The two latter storage types may allow the recovery of sellable products, which partially or totally offsets the storage costs. This process is largely used in the petroleum industry to improve the productivity of an oil field, and is called FOR (Enhanced Oil Recovery). A similar process is applied in the coal mining industry to recover the imprisoned gas, and is called ECBM (Enhanced Coal Bed methane). Two storage operations have been initiated in Norway and in Canada, as well as research programmes in Europe, North America, Australia and Japan. International organisations to stimulate this technology have been created such as the 'Carbon Sequestration Leadership Forum' and 'the Intergovernmental Group for Climate Change'. This technology will be taken into account in the instruments provided by the Tokyo Protocol. (author)

  8. Forecasting global atmospheric CO2

    International Nuclear Information System (INIS)

    Agusti-Panareda, A.; Massart, S.; Boussetta, S.; Balsamo, G.; Beljaars, A.; Engelen, R.; Jones, L.; Peuch, V.H.; Chevallier, F.; Ciais, P.; Paris, J.D.; Sherlock, V.

    2014-01-01

    A new global atmospheric carbon dioxide (CO 2 ) real-time forecast is now available as part of the preoperational Monitoring of Atmospheric Composition and Climate - Interim Implementation (MACC-II) service using the infrastructure of the European Centre for Medium-Range Weather Forecasts (ECMWF) Integrated Forecasting System (IFS). One of the strengths of the CO 2 forecasting system is that the land surface, including vegetation CO 2 fluxes, is modelled online within the IFS. Other CO 2 fluxes are prescribed from inventories and from off-line statistical and physical models. The CO 2 forecast also benefits from the transport modelling from a state-of-the-art numerical weather prediction (NWP) system initialized daily with a wealth of meteorological observations. This paper describes the capability of the forecast in modelling the variability of CO 2 on different temporal and spatial scales compared to observations. The modulation of the amplitude of the CO 2 diurnal cycle by near-surface winds and boundary layer height is generally well represented in the forecast. The CO 2 forecast also has high skill in simulating day-to-day synoptic variability. In the atmospheric boundary layer, this skill is significantly enhanced by modelling the day-to-day variability of the CO 2 fluxes from vegetation compared to using equivalent monthly mean fluxes with a diurnal cycle. However, biases in the modelled CO 2 fluxes also lead to accumulating errors in the CO 2 forecast. These biases vary with season with an underestimation of the amplitude of the seasonal cycle both for the CO 2 fluxes compared to total optimized fluxes and the atmospheric CO 2 compared to observations. The largest biases in the atmospheric CO 2 forecast are found in spring, corresponding to the onset of the growing season in the Northern Hemisphere. In the future, the forecast will be re-initialized regularly with atmospheric CO 2 analyses based on the assimilation of CO 2 products retrieved from satellite

  9. CO2 emissions vs. CO2 responsibility: An input-output approach for the Turkish economy

    International Nuclear Information System (INIS)

    Ipek Tunc, G.; Tueruet-Asik, Serap; Akbostanci, Elif

    2007-01-01

    Recently, global warming (greenhouse effect) and its effects have become one of the hottest topics in the world agenda. There have been several international attempts to reduce the negative effects of global warming. The Kyoto Protocol can be cited as the most important agreement which tries to limit the countries' emissions within a time horizon. For this reason, it becomes important to calculate the greenhouse gas emissions of countries. The aim of this study is to estimate the amount of CO 2 -the most important greenhouse gas-emissions, for the Turkish economy. An extended input-output model is estimated by using 1996 data in order to identify the sources of CO 2 emissions and to discuss the share of sectors in total emission. Besides, 'CO 2 responsibility', which takes into account the CO 2 content of imports, is estimated for the Turkish economy. The sectoral CO 2 emissions and CO 2 responsibilities are compared and these two notions are linked to foreign trade volume. One of the main conclusions is that the manufacturing industry has the first place in both of the rankings for CO 2 emissions and CO 2 responsibilities, while agriculture and husbandry has the last place

  10. Natural Analogues of CO2 Geological Storage

    International Nuclear Information System (INIS)

    Perez del Villar, L.; Pelayo, M.; Recreo, F.

    2007-01-01

    Geological storage of carbon dioxide is nowadays, internationally considered as the most effective method for greenhouse gas emission mitigation, in order to minimize the global climate change universally accepted. Nevertheless, the possible risks derived of this long-term storage have a direct influence on its public acceptance. Among the favourable geological formations to store CO2, depleted oil and gas fields, deep saline reservoirs, and unamiable coal seams are highlighted. One of the most important objectives of the R and D projects related to the CO2 geological storage is the evaluation of the CO2 leakage rate through the above mentioned geological formations. Therefore, it is absolutely necessary to increase our knowledge on the interaction among CO2, storage and sealing formations, as well as on the flow paths and the physical resistance of the sealing formation. The quantification of the CO2 leakage rate is essential to evaluate the effects on the human and animal health, as well as for the ecosystem and water quality. To achieve these objectives, the study of the natural analogues is very useful in order to know the natural leakage rate to the atmosphere, its flow paths, the physical, chemical and mineralogical modifications due to the long term interaction processes among the CO2 and the storage and sealing formations, as well as the effects on the groundwaters and ecosystems. In this report, we have tried to summarise the main characteristics of the natural reservoirs and surficial sources of CO2, which are both natural analogues of the geological storage and CO2 leakage, studied in EEUU, Europe and Australia. The main objective of this summary is to find the possible applications for long-term risk prediction and for the performance assessment by means of conceptual and numerical modelling, which will allow to validate the predictive models of the CO2 storage behaviour, to design and develop suitable monitoring techniques to control the CO2 behaviour

  11. CO2 as a refrigerant

    CERN Document Server

    2014-01-01

    A first edition, the IIR guide “CO2 as a Refrigerant” highlights the application of carbon dioxide in supermarkets, industrial freezers, refrigerated transport, and cold stores as well as ice rinks, chillers, air conditioning systems, data centers and heat pumps. This guide is for design and development engineers needing instruction and inspiration as well as non-technical experts seeking background information on a specific topic. Written by Dr A.B. Pearson, a well-known expert in the field who has considerable experience in the use of CO2 as a refrigerant. Main topics: Thermophysical properties of CO2 – Exposure to CO2, safety precautions – CO2 Plant Design – CO2 applications – Future prospects – Standards and regulations – Bibliography.

  12. Phytophthora quercina infections in elevated CO2 concentrations

    Directory of Open Access Journals (Sweden)

    Oszako Tomasz

    2016-09-01

    Full Text Available In the last decades, a new wave of oak decline has been observed in Poland. The most important pathogenic organisms involved in this phenomenon are probably soil-borne pathogens Phytophthoragenus, especially P. quercina. In this work, we sought to test the influence of elevated CO2 concentration on the susceptibility of oaks (Quercus robur L. to infection by P. quercina. In order to test the susceptibility of oak fine roots to infection, we applied phosphite-based fertiliser Actifos in 0.6% concentration. One-year-old oak seedlings were grown for one year in greenhouse with either an ambient atmosphere (400 ppm CO2 or an elevated (800 ppm concentration of CO2. Oaks grown at the elevated CO2 concentration developed longer shoots as proved by statistically significant differences. However, there was no difference in the development of root systems. The application of Actifos had a positive significant effect on the development of shoots and the surface area of fine roots under the elevated CO2 concentration.

  13. New era for CO2 as a working fluid

    International Nuclear Information System (INIS)

    Stene, Joern

    2000-01-01

    During the past decade there has been extensive international activity to find acceptable alternatives to ozone-depleting CFC and HCFC substances that have been widely used as working fluids in refrigerating and heat pump plants. At present, the so-called natural working fluids constitute the most environmentally friendly alternative, and they include first of all ammonia, hydrocarbons and carbon dioxide (CO2). NTNU and SINTEF Energy Research, Norway, have been pioneers in the development of refrigerating and heat pump systems that use CO2 as a working fluid. The favourable technical and environmental properties of CO2 as well as the promising results have now led to considerable international interest in CO2 technology for refrigerating and heat pump applications. Two examples are international licensing for Norwegian CO2 technology and co-operation with Indonesia on CO2 for refrigeration

  14. Decoupling of CO2 emissions and GDP

    Directory of Open Access Journals (Sweden)

    Yves Rocha de Salles Lima

    2016-12-01

    Full Text Available The objetive of this work is to analyze the variation of CO2 emissions and GDP per capita throughout the years and identify the possible interaction between them. For this purpose, data from the International Energy Agency was collected on two countries, Brazil and the one with the highest GDP worldwide, the United States. Thus, the results showed that CO2 emissions have been following the country’s economic growth for many years. However, these two indicators have started to decouple in the US in 2007 while in Brazil the same happened in 2011. Furthermore, projections for CO2 emissions are made until 2040, considering 6 probable scenarios. These projections showed that even if the oil price decreases, the emissions will not be significantly affected as long as the economic growth does not decelerate.

  15. The sequestration of CO2

    International Nuclear Information System (INIS)

    Le Thiez, P.

    2004-01-01

    The reduction of greenhouse gas emissions, especially CO 2 , represents a major technological and societal challenge in the fight against climate change. Among the measures likely to reduce anthropic CO 2 emissions, capture and geological storage holds out promise for the future. (author)

  16. CO2 Sequestration short course

    Energy Technology Data Exchange (ETDEWEB)

    DePaolo, Donald J. [Lawrence Berkeley National Laboratory; Cole, David R [The Ohio State University; Navrotsky, Alexandra [University of California-Davis; Bourg, Ian C [Lawrence Berkeley National Laboratory

    2014-12-08

    Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

  17. Enzymes in CO2 Capture

    DEFF Research Database (Denmark)

    Fosbøl, Philip Loldrup; Gladis, Arne; Thomsen, Kaj

    The enzyme Carbonic Anhydrase (CA) can accelerate the absorption rate of CO2 into aqueous solutions by several-fold. It exist in almost all living organisms and catalyses different important processes like CO2 transport, respiration and the acid-base balances. A new technology in the field...... of carbon capture is the application of enzymes for acceleration of typically slow ternary amines or inorganic carbonates. There is a hidden potential to revive currently infeasible amines which have an interesting low energy consumption for regeneration but too slow kinetics for viable CO2 capture. The aim...... of this work is to discuss the measurements of kinetic properties for CA promoted CO2 capture solvent systems. The development of a rate-based model for enzymes will be discussed showing the principles of implementation and the results on using a well-known ternary amine for CO2 capture. Conclusions...

  18. Sirococcus Shoot Blight

    Science.gov (United States)

    Thomas H. Nicholls; Kathryn Robbins

    1984-01-01

    Sirococcus shoot blight, caused by the fungus Sirococcus strobilinus Preuss, affects conifers in the Northern United States and southern Canada. The fungus infects the new shoots; diseased seedlings and saplings are especially affected. In the United States, sirococcus shoot blight has become increasingly widespread since the early 1970's. When favorable...

  19. Economics show CO2 EOR potential in central Kansas

    Science.gov (United States)

    Dubois, M.K.; Byrnes, A.P.; Pancake, R.E.; Willhite, G.P.; Schoeling, L.G.

    2000-01-01

    Carbon dioxide (CO2) enhanced oil recovery (EOR) may be the key to recovering hundreds of millions of bbl of trapped oil from the mature fields in central Kansas. Preliminary economic analysis indicates that CO2 EOR should provide an internal rate of return (IRR) greater than 20%, before income tax, assuming oil sells for \\$20/bbl, CO2 costs \\$1/Mcf, and gross utilization is 10 Mcf of CO2/bbl of oil recovered. If the CO2 cost is reduced to \\$0.75/Mcf, an oil price of $17/bbl yields an IRR of 20%. Reservoir and economic modeling indicates that IRR is most sensitive to oil price and CO2 cost. A project requires a minimum recovery of 1,500 net bbl/acre (about 1 million net bbl/1-mile section) under a best-case scenario. Less important variables to the economics are capital costs and non-CO2 related lease operating expenses.

  20. CO2 pellet blasting studies

    International Nuclear Information System (INIS)

    Archibald, K.E.

    1997-01-01

    Initial tests with CO 2 pellet blasting as a decontamination technique were completed in 1993 at the Idaho Chemical Processing Plant (ICPP) at the Idaho National Engineering Laboratory (INEL). During 1996, a number of additional CO 2 pellet blasting studies with Alpheus Cleaning Technologies, Oak Ridge National Laboratory, and Pennsylvania State University were conducted. After the testing with Alpheus was complete, an SDI-5 shaved CO 2 blasting unit was purchased by the ICPP to test and determine its capabilities before using in ICPP decontamination efforts. Results of the 1996 testing will be presented in this report

  1. CO2: a worldwide myth

    International Nuclear Information System (INIS)

    Gerondeau, Ch.

    2009-01-01

    In this book, the author demonstrates the paradox that reducing CO 2 emissions leads to no CO 2 abatement at all. This assertion is based on an obvious statement. Everybody knows that oil resources are going to be exhausted in few decades. The oil that industrialized countries will not use will be consumed by emerging countries and the CO 2 emissions will remain the same. Who would believe that the oil, gas or coal still available will remain unused? The Kyoto protocol, the national policies, the European agreements of emissions abatement, the carbon taxes, the emissions abatement requests sent to the rest of the world, all these actions cost a lot and are useless. CO 2 concentration in the atmosphere will inescapably double during the 21. century but, according to the author, without any catastrophic consequence for the Earth. (J.S.)

  2. Use of sediment CO2 by submersed rooted plants

    DEFF Research Database (Denmark)

    Winkel, Anders; Borum, Jens

    2009-01-01

    freshwater plants with different morphology and growth characteristics (Lobelia dortmanna, Lilaeopsis macloviana, Ludwigia repens, Vallisneria americana and Hydrocotyle verticillata) are able to support photosynthesis supplied by uptake of CO2 from the sediment. Methods: Gross photosynthesis was measured......Background and Aims: Submersed plants have different strategies to overcome inorganic carbon limitation. It is generally assumed that only small rosette species (isoetids) are able to utilize the high sediment CO2 availability. The present study examined to what extent five species of submersed......, the shoot to root ratio on an areal basis was the single factor best explaining variability in the importance of sediment CO2. For Ludwigia, diffusion barriers limited uptake or transport from roots to stems and transport from stems to leaves. Conclusions: Submersed plants other than isoetids can utilize...

  3. Connecting CO2. Feasibility study CO2 network Southwest Netherlands; Connecting CO2. Haalbaarheidsstudie CO2-netwerk Zuidwest-Nederland

    Energy Technology Data Exchange (ETDEWEB)

    Rutten, M.

    2009-06-10

    An overview is given of supply and demand of CO2 in the region Southwest Netherlands and the regions Antwerp and Gent in Belgium. Also attention is paid to possible connections between these regions [Dutch] Een inventarisatie wordt gegeven van vraag en aanbod van CO2 in de regio Zuidwest- Nederland en de regios Antwerpen en Gent in Belgie. Ook worden mogelijke koppelingen tussen de regios besproken.

  4. Techno-economic Issues and Trade-offs for CO2 Purity in CCS Chains: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016. 14 November 2016 through 18 November 2016

    NARCIS (Netherlands)

    Eickhoff, C.; Brown, A.; Neele, F.

    2017-01-01

    The IMPACTS project has the objective to develop the knowledge base of CO2 quality required for establishing norms and regulations to ensure safe and reliable design, construction and operation of CO2 pipelines and injection equipment, and safe long-term geological storage of CO2. More specifically

  5. Stem girdling affects the quantity of CO2 transported in xylem as well as CO2 efflux from soil.

    Science.gov (United States)

    Bloemen, Jasper; Agneessens, Laura; Van Meulebroek, Lieven; Aubrey, Doug P; McGuire, Mary Anne; Teskey, Robert O; Steppe, Kathy

    2014-02-01

    There is recent clear evidence that an important fraction of root-respired CO2 is transported upward in the transpiration stream in tree stems rather than fluxing to the soil. In this study, we aimed to quantify the contribution of root-respired CO2 to both soil CO2 efflux and xylem CO2 transport by manipulating the autotrophic component of belowground respiration. We compared soil CO2 efflux and the flux of root-respired CO2 transported in the transpiration stream in girdled and nongirdled 9-yr-old oak trees (Quercus robur) to assess the impact of a change in the autotrophic component of belowground respiration on both CO2 fluxes. Stem girdling decreased xylem CO2 concentration, indicating that belowground respiration contributes to the aboveground transport of internal CO2 . Girdling also decreased soil CO2 efflux. These results confirmed that root respiration contributes to xylem CO2 transport and that failure to account for this flux results in inaccurate estimates of belowground respiration when efflux-based methods are used. This research adds to the growing body of evidence that efflux-based measurements of belowground respiration underestimate autotrophic contributions. © 2013 The Authors. New Phytologist © 2013 New Phytologist Trust.

  6. Capture and Geological Storage of CO2

    International Nuclear Information System (INIS)

    Kerr, T.; Brockett, S.; Hegan, L.; Barbucci, P.; Tullius, K.; Scott, J.; Otter, N.; Cook, P.; Hill, G.; Dino, R.; Aimard, N.; Giese, R.; Christensen, N.P.; Munier, G.; Paelinck, Ph.; Rayna, L.; Stromberg, L.; Birat, J.P.; Audigane, P.; Loizzo, M.; Arts, R.; Fabriol, H.; Radgen, P.; Hartwell, J.; Wartmann, S.; Drosin, E.; Willnow, K.; Moisan, F.

    2009-01-01

    To build on the growing success of the first two international symposia on emission reduction and CO 2 capture and geological storage, held in Paris in 2005 and again in 2007, IFP, ADEME and BRGM organised a third event on the same topic the 5-6 November 2009. This time, the focus was on the urgency of industrial deployment. Indeed, the IPCC 4. assessment report indicates that the world must achieve a 50 to 85% reduction in CO 2 emissions by 2050 compared to 2000, in order to limit the global temperature increase to around 2 deg. C. Moreover, IPCC stresses that a 'business as usual' scenario could lead to a temperature increase of between 4 deg. C to 7 deg. C across the planet. The symposium was organized in 4 sessions: Session I - Regulatory framework and strategies for enabling CCS deployment: - CCS: international status of political, regulatory and financing issues (Tom Kerr, IEA); - EC regulatory framework (Scott Brockett, European Commission, DG ENV); - Canada's investments towards implementation of CCS in Canada (Larry Hegan, Office of Energy Research and Development - Government of Canada); - A power company perspective (Pietro Barbucci, ENEL); - EC CCS demonstration network (Kai Tullius, European Commission, DG TREN); - Strategies and policies for accelerating global CCS deployment (Jesse Scott, E3G); - The global CCS Institute, a major initiative to facilitate the rapid deployment of CCS (Nick Otter, GCCSI); Session II - From pilot to demonstration projects: - Otway project, Australia (David Hilditch, CO2 CRC); - US regional partnerships (Gerald Hill, Southeast Regional Carbon Sequestration Partnership - SECARB); - CCS activities in Brazil (Rodolfo Dino, Petrobras); - Lessons learnt from Ketzin CO2Sink project in Germany (Ruediger Giese, GFZ); - CO 2 storage - from laboratory to reality (Niels-Peter Christensen, Vattenfall); - Valuation and storage of CO 2 : A global project for carbon management in South-East France (Gilles Munier, Geogreen); Session III

  7. State of Energy Consumption and CO2 Emission in Bangladesh

    International Nuclear Information System (INIS)

    Azad, Abul K.; Nashreen, S.W.; Sultana, J.

    2006-01-01

    Carbon dioxide (CO 2 ) is one of the most important gases in the atmosphere, and is necessary for sustaining life on Earth. It is also considered to be a major greenhouse gas contributing to global warming and climate change. In this article, energy consumption in Bangladesh is analyzed and estimates are made of CO 2 emission from combustion of fossil fuel (coal, gas, petroleum products) for the period 1977 to 1995. International Panel for Climate Change guidelines for national greenhouse gas inventories were used in estimating CO 2 emission. An analysis of energy data shows that the consumption of fossil fuels in Bangladesh is growing by more than 5% per year. The proportion of natural gas in total energy consumption is increasing, while that of petroleum products and coal is decreasing. The estimated total CO 2 release from all primary fossil fuels used in Bangladesh amounted to 5,072 Gg in 1977, and 14,423 Gg in 1995. The total amounts of CO 2 released from petroleum products, natural gas, and coal in the period 1977-1995 were 83,026 Gg (50% of CO 2 emission), 72,541 Gg (44% of CO 2 emission), and 9,545 Gg (6% CO 2 emission), respectively. A trend in CO 2 emission with projections to 2070 is generated. In 2070, total estimated CO 2 emission will be 293,260 Gg with a current growth rate of 6.34%/y. CO 2 emission from fossil fuels is increasing. Petroleum products contribute the majority of CO 2 emission load, and although the use of natural gas is increasing rapidly, its contribution to CO 2 emission is less than that of petroleum products. The use of coal as well as CO 2 emission from coal is expected to gradually decrease

  8. CO2 Capture and Reuse

    International Nuclear Information System (INIS)

    Thambimuthu, K.; Gupta, M.; Davison, J.

    2003-01-01

    CO2 capture and storage including its utilization or reuse presents an opportunity to achieve deep reductions in greenhouse gas emissions from fossil energy use. The development and deployment of this option could significantly assist in meeting a future goal of achieving stabilization of the presently rising atmospheric concentration of greenhouse gases. CO2 capture from process streams is an established concept that has achieved industrial practice. Examples of current applications include the use of primarily, solvent based capture technologies for the recovery of pure CO2 streams for chemical synthesis, for utilization as a food additive, for use as a miscible agent in enhanced oil recovery operations and removal of CO2 as an undesired contaminant from gaseous process streams for the production of fuel gases such as hydrogen and methane. In these applications, the technologies deployed for CO2 capture have focused on gas separation from high purity, high pressure streams and in reducing (or oxygen deficient) environments, where the energy penalties and cost for capture are moderately low. However, application of the same capture technologies for large scale abatement of greenhouse gas emissions from fossil fuel use poses significant challenges in achieving (at comparably low energy penalty and cost) gas separation in large volume, dilute concentration and/or low pressure flue gas streams. This paper will focus on a review of existing commercial methods of CO2 capture and the technology stretch, process integration and energy system pathways needed for their large scale deployment in fossil fueled processes. The assessment of potential capture technologies for the latter purpose will also be based on published literature data that are both 'transparent' and 'systematic' in their evaluation of the overall cost and energy penalties of CO2 capture. In view of the of the fact that many of the existing commercial processes for CO2 capture have seen applications in

  9. CO2 reduction strategies for the Northern Netherlands

    NARCIS (Netherlands)

    Benders, Rene; Moll, Henk; Noorman, Klaas Jan; Wiersma, Gerwin

    2011-01-01

    The concern about global warming initiated ambitious CO2 reduction goals in cities and regions in the Netherlands. This article describes a study of such a local initiative for the Northern Netherlands. The research aimed to develop CO2 reduction scenarios for 2035 with national and international

  10. Natural Analogues of CO2 Geological Storage; Analogos Naturales del Almacenamiento Geologico de CO2

    Energy Technology Data Exchange (ETDEWEB)

    Perez del Villar, L; Pelayo, M; Recreo, F

    2007-07-20

    Geological storage of carbon dioxide is nowadays, internationally considered as the most effective method for greenhouse gas emission mitigation, in order to minimize the global climate change universally accepted. Nevertheless, the possible risks derived of this long-term storage have a direct influence on its public acceptance. Among the favourable geological formations to store CO2, depleted oil and gas fields, deep saline reservoirs, and unamiable coal seams are highlighted. One of the most important objectives of the R and D projects related to the CO2 geological storage is the evaluation of the CO2 leakage rate through the above mentioned geological formations. Therefore, it is absolutely necessary to increase our knowledge on the interaction among CO2, storage and sealing formations, as well as on the flow paths and the physical resistance of the sealing formation. The quantification of the CO2 leakage rate is essential to evaluate the effects on the human and animal health, as well as for the ecosystem and water quality. To achieve these objectives, the study of the natural analogues is very useful in order to know the natural leakage rate to the atmosphere, its flow paths, the physical, chemical and mineralogical modifications due to the long term interaction processes among the CO2 and the storage and sealing formations, as well as the effects on the groundwaters and ecosystems. In this report, we have tried to summarise the main characteristics of the natural reservoirs and surficial sources of CO2, which are both natural analogues of the geological storage and CO2 leakage, studied in EEUU, Europe and Australia. The main objective of this summary is to find the possible applications for long-term risk prediction and for the performance assessment by means of conceptual and numerical modelling, which will allow to validate the predictive models of the CO2 storage behaviour, to design and develop suitable monitoring techniques to control the CO2 behaviour

  11. Capture and geologic storage of carbon dioxide (CO2)

    International Nuclear Information System (INIS)

    2004-11-01

    This dossier about carbon sequestration presents: 1 - the world fossil fuels demand and its environmental impact; 2 - the solutions to answer the climatic change threat: limitation of fossil fuels consumption, development of nuclear and renewable energies, capture and storage of CO 2 (environmental and industrial advantage, cost); 3 - the CO 2 capture: post-combustion smokes treatment, oxi-combustion techniques, pre-combustion techniques; 4 - CO 2 storage: in hydrocarbon deposits (Weyburn site in Canada), in deep saline aquifers (Sleipner and K12B (North Sea)), in non-exploitable coal seams (Recopol European project); 5 - international and national mobilization: IEA R and D program, USA (FutureGen zero-emission coal-fired power plant, Carbon Sequestration Leadership forum), European Union (AZEP, GRACE, GESTCO, CO2STORE, NASCENT, RECOPOL, Castor, ENCAP, CO2sink etc programs), French actions (CO 2 club, network of oil and gas technologies (RTPG)), environmental stake, competitiveness, research stake. (J.S.)

  12. Membrane-assisted CO2 liquefaction: performance modelling of CO2 capture from flue gas in cement production

    NARCIS (Netherlands)

    Bouma, R.H.B.; Vercauteren, F.F.; Os, P.J. van; Goetheer, E.L.V.; Berstad, D.; Anantharaman, R.

    2017-01-01

    CEMCAP is an international R&D project under the Horizon 2020 Programme preparing the ground for the large-scale implementation of CO2 capture in the European cement industry. This paper concerns the performance modeling of membraneassisted CO2 liquefaction as a possible retrofit application for

  13. INTERNATIONAL COLLABORATION ON CO2 SEQUESTRATION

    Energy Technology Data Exchange (ETDEWEB)

    Howard J. Herzog; E. Eric Adams

    2003-04-01

    The main goal of our work during this time period (August 23, 2001-August 23, 2002) was to conduct a field experiment in Norwegian waters. Preparation for the field experiment included building the apparatus, designing and obtaining the measurement systems, planning the logistics (ships, crew, supplies, etc.) and conducting a survey cruise. The survey cruise, conducted in July 2002, is documented in this report. The field experiment, scheduled for August 2002, was postponed when the Norwegian environmental minister revoked our permit under pressure from Greenpeace. Events surrounding the permitting situation are documented in the Appendix.

  14. INTERNATIONAL COLLABORATION ON CO2 SEQUESTRATION

    Energy Technology Data Exchange (ETDEWEB)

    H.J. Herzog; E.E. Adams

    2000-08-23

    The specific objective of our project on CO{sub 2} ocean sequestration is to investigate its technical feasibility and to improve the understanding of any associated environmental impacts. Our ultimate goal is to minimize any impacts associated with the eventual use of ocean carbon sequestration to reduce greenhouse gas concentrations in the atmosphere. The project will continue through March 31, 2002, with a field experiment to take place in the summer of 2001 off the Kona Coast of Hawaii. At GHGT-4 in Interlaken, we presented a paper detailing our plans. The purpose of this paper is to present an update on our progress to date and our plans to complete the project. The co-authors of this paper are members of the project's Technical Committee, which has been formed to supervise the technical aspects and execution of this project.

  15. Shooting mechanisms in nature

    NARCIS (Netherlands)

    Sakes, Aimée; Wiel, van der Marleen; Henselmans, Paul W.J.; Leeuwen, van Johan L.; Dodou, Dimitra; Breedveld, Paul

    2016-01-01

    Background In nature, shooting mechanisms are used for a variety of purposes, including prey capture, defense, and reproduction. This review offers insight into the working principles of shooting mechanisms in fungi, plants, and animals in the light of the specific functional demands that these

  16. On a CO2 ration

    International Nuclear Information System (INIS)

    De Wit, P.

    2003-01-01

    In 2 years all the large energy companies in the European Union will have a CO2 ration, including a system to trade a shortage or surplus of emission rights. A cost effective system to reduce emission, provided that the government does not auction the emission rights [nl

  17. Reducing cement's CO2 footprint

    Science.gov (United States)

    van Oss, Hendrik G.

    2011-01-01

    The manufacturing process for Portland cement causes high levels of greenhouse gas emissions. However, environmental impacts can be reduced by using more energy-efficient kilns and replacing fossil energy with alternative fuels. Although carbon capture and new cements with less CO2 emission are still in the experimental phase, all these innovations can help develop a cleaner cement industry.

  18. Differences in response of two Sphagnum species to elevated CO2 and nitrogen input

    International Nuclear Information System (INIS)

    Jauhiainen, J.; Vasander, H.; Silvola, J.

    1992-01-01

    Cushions of Sphagnum fuscum and S. angustifolium were grown in the laboratory in four different CO 2 concentrations (350, 700, 1000 and 2000 ppm) and N deposition levels (0, 10, 30 and 100 kg/ha - 1 a - 1). The same N deposition levels were also applied in the field. CO 2 concentration increases both the shoot density and dry mass of S. fuscum but decreased the length increment. There was no net effect on production. For S. angustifolium, shoot density did not alter with elevated CO 2 concentration but the CO 2 induced increment in dry mass and length caused increased production. S. angustifolium suffered from nutrient deficiency on the 0kg/ha - 1 a - 1 treatment and S. fuscum had difficulties to survive at heaviest N load. No clear trends in length increment or cover was noticed in the field study during the first year

  19. CO2 Emissions From Fuel Combustion. Highlights. 2013 Edition

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-07-01

    In the lead-up to the UN climate negotiations in Warsaw, the latest information on the level and growth of CO2 emissions, their source and geographic distribution will be essential to lay the foundation for a global agreement. To provide input to and support for the UN process, the IEA is making available for free download the ''Highlights'' version of CO2 Emissions from Fuel Combustion now for sale on IEA Bookshop. This annual publication contains, for more than 140 countries and regions: estimates of CO2 emissions from 1971 to 2011; selected indicators such as CO2/GDP, CO2/capita, CO2/TPES and CO2/kWh; a decomposition of CO2 emissions into driving factors; and CO2emissions from international marine and aviation bunkers, key sources, and other relevant information. The nineteenth session of the Conference of the Parties to the Climate Change Convention (COP-19), in conjunction with the ninth meeting of the Parties to the Kyoto Protocol (CMP 9), met in Warsaw, Poland from 11 to 22 November 2013. This volume of ''Highlights'', drawn from the full-scale study, was specially designed for delegations and observers of the meeting in Warsaw.

  20. Limitations to CO2-induced growth enhancement in pot studies.

    Science.gov (United States)

    McConnaughay, K D M; Berntson, G M; Bazzaz, F A

    1993-07-01

    Recently, it has been suggested that small pots may reduce or eliminate plant responses to enriched CO 2 atmospheres due to root restriction. While smaller pot volumes provide less physical space available for root growth, they also provide less nutrients. Reduced nutrient availability alone may reduce growth enhancement under elevated CO 2 . To investigate the relative importance of limited physical rooting space separate from and in conjunction with soil nutrients, we grew plants at ambient and double-ambient CO 2 levels in growth containers of varied volume, shape, nutrient concentration, and total nutrient content. Two species (Abutilon theophrasti, a C 3 dicot with a deep tap root andSetaria faberii, a C 4 monocot with a shallow diffuse root system) were selected for their contrasting physiology and root architecture. Shoot demography was determined weekly and biomass was determined after eight and ten weeks of growth. Increasing total nutrients, either by increasing nutrient concentration or by increasing pot size, increased plant growth. Further, increasing pot size while maintaining equal total nutrients per pot resulted in increased total biomass for both species. CO 2 -induced growth and reproductive yield enhancements were greatest in pots with high nutrient concentrations, regardless of total nutrient content or pot size, and were also mediated by the shape of the pot. CO 2 -induced growth and reproductive yield enhancements were unaffected by pot size (growth) or were greater in small pots (reproductive yield), regardless of total nutrient content, contrary to predictions based on earlier studies. These results suggest that several aspects of growth conditions within pots may influence the CO 2 responses of plants; pot size, pot shape, the concentration and total amount of nutrient additions to pots may lead to over-or underestimates of the CO 2 responses of real-world plants.

  1. Global energy / CO2 projections

    International Nuclear Information System (INIS)

    Sinyak, Y.

    1990-09-01

    Section headings are: (1) Social and economic problems of the 21 st century and the role of energy supply systems (2) Energy-environment interactions as a central point of energy research activities (3) New ways of technological progress and its impacts on energy demand and supply (4) Long-term global energy projections (5) Comparative analysis of global long-term energy / CO 2 studies (6) Conclusions. The author shows that, in order to alleviate the negative impacts of energy systems on the climate, it will be necessary to undertake tremendous efforts to improve the energy use efficiency, to drastically change the primary energy mix, and, at the same time, to take action to reduce greenhouse emissions from other sources and increase the CO 2 sink through enhanced reforestation. (Quittner)

  2. CO2 Acquisition Membrane (CAM)

    Science.gov (United States)

    Mason, Larry W.; Way, J. Douglas; Vlasse, Marcus

    2003-01-01

    The objective of CAM is to develop, test, and analyze thin film membrane materials for separation and purification of carbon dioxide (CO2) from mixtures of gases, such as those found in the Martian atmosphere. The membranes are targeted toward In Situ Resource Utilization (ISRU) applications that will operate in extraterrestrial environments and support future unmanned and human space missions. A primary application is the Sabatier Electrolysis process that uses Mars atmosphere CO2 as raw material for producing water, oxygen, and methane for rocket fuel and habitat support. Other applications include use as an inlet filter to collect and concentrate Mars atmospheric argon and nitrogen gases for habitat pressurization, and to remove CO2 from breathing gases in Closed Environment Life Support Systems (CELSS). CAM membrane materials include crystalline faujasite (FAU) zeolite and rubbery polymers such as silicone rubber (PDMS) that have been shown in the literature and via molecular simulation to favor adsorption and permeation of CO2 over nitrogen and argon. Pure gas permeation tests using commercial PDMS membranes have shown that both CO2 permeance and the separation factor relative to other gases increase as the temperature decreases, and low (Delta)P(Sub CO2) favors higher separation factors. The ideal CO2/N2 separation factor increases from 7.5 to 17.5 as temperature decreases from 22 C to -30 C. For gas mixtures containing CO2, N2, and Ar, plasticization decreased the separation factors from 4.5 to 6 over the same temperature range. We currently synthesize and test our own Na(+) FAU zeolite membranes using standard formulations and secondary growth methods on porous alumina. Preliminary tests with a Na(+) FAU membrane at 22 C show a He/SF6 ideal separation factor of 62, exceeding the Knudsen diffusion selectivity by an order of magnitude. This shows that the membrane is relatively free from large defects and associated non-selective (viscous flow) transport

  3. Fang CO2 med Aminosyrer

    DEFF Research Database (Denmark)

    Lerche, Benedicte Mai

    2010-01-01

    Med såkaldte “carbon capture-teknikker” er det muligt at rense røgen fra kulfyrede kraftværker, således at den er næsten helt fri for drivhusgassen CO2. Kunsten er at gøre processen tilstrækkeligt billig. Et lovende fangstredskab i denne proces er aminosyrer.......Med såkaldte “carbon capture-teknikker” er det muligt at rense røgen fra kulfyrede kraftværker, således at den er næsten helt fri for drivhusgassen CO2. Kunsten er at gøre processen tilstrækkeligt billig. Et lovende fangstredskab i denne proces er aminosyrer....

  4. CO2 reduction by dematerialization

    Energy Technology Data Exchange (ETDEWEB)

    Hekkert, M.P. [Department of Innovation Studies, Copernicus Institute, Utrecht University, Utrecht (Netherlands)

    2002-04-01

    Current policy for the reduction of greenhouse gases is mainly concerned with a number of types of solutions: energy saving, shifting to the use of low-carbon fuels and the implementation of sustainable energy technologies. Recent research has shown that a strategy directed at a more efficient use of materials could make a considerable contribution to reducing CO2 emissions. Moreover, the costs to society as a whole of such a measure appear to be very low.

  5. Growth strategy of Norway spruce under air elevated [CO2

    Science.gov (United States)

    Pokorny, R.; Urban, O.; Holisova, P.; Sprtova, M.; Sigut, L.; Slipkova, R.

    2012-04-01

    Plants will respond to globally increasing atmospheric CO2 concentration ([CO2]) by acclimation or adaptation at physiological and morphological levels. Considering the temporal onset, physiological responses may be categorized as short-term and morphological ones as long-term responses. The degree of plant growth responses, including cell division and cell expansion, is highly variable. It depends mainly on the specie's genetic predisposition, environment, mineral nutrition status, duration of CO2 enrichment, and/or synergetic effects of other stresses. Elevated [CO2] causes changes in tissue anatomy, quantity, size, shape and spatial orientation and can result in altered sink strength. Since, there are many experimental facilities for the investigation of elevated [CO2] effects on trees: i) closed systems or open top chambers (OTCs), ii) semi-open systems (for example glass domes with adjustable lamella windows - DAWs), and iii) free-air [CO2] enrichments (FACE); the results are still unsatisfactory due to: i) relatively short-term duration of experiments, ii) cultivation of young plants with different growth strategy comparing to old ones, iii) plant cultivation under artificial soil and weather conditions, and iv) in non-representative stand structure. In this contribution we are discussing the physiological and morphological responses of Norway spruce trees cultivated in DAWs during eight consecutive growing seasons in the context with other results from Norway spruce cultivation under air-elevated [CO2] conditions. On the level of physiological responses, we discuss the changes in the rate of CO2 assimilation, assimilation capacity, photorespiration, dark respiration, stomatal conductance, water potential and transpiration, and the sensitivity of these physiological processes to temperature. On the level of morphological responses, we discuss the changes in bud and growth phenology, needle and shoot morphology, architecture of crown and root system, wood

  6. Practical guidebook about the market of CO2 emission quotas

    International Nuclear Information System (INIS)

    2005-01-01

    Since January 1, 2005, the European directive about the trading of CO 2 emission quotas foresees the allocation of CO 2 emission quotas to the industrial sectors that generate huge amounts of greenhouse gases (energy generation, cement, glass, steel-making, mineral and paper industries). A system of trading of CO 2 quotas has been implemented and allows the companies to exchange, sale or purchase quotas in order to be conformable with the volume of CO 2 they have been authorized to release in the atmosphere. This guidebook is a vade mecum of the management of emission quotas. It explains the actions of the international community in favor of the fight against greenhouse emissions, the 3 flexibility mechanisms, the French environmental policy, the European system of fight against climatic change, the CO 2 quotas system and its practical implementation. (J.S.)

  7. Violence and school shootings.

    Science.gov (United States)

    Flannery, Daniel J; Modzeleski, William; Kretschmar, Jeff M

    2013-01-01

    Multiple-homicide school shootings are rare events, but when they happen they significantly impact individuals, the school and the community. We focus on multiple-homicide incidents and identified mental health issues of shooters. To date, studies of school shootings have concluded that no reliable profile of a shooter exists, so risk should be assessed using comprehensive threat assessment protocols. Existing studies primarily utilize retrospective case histories or media accounts. The field requires more empirical and systematic research on all types of school shootings including single victim incidents, those that result in injury but not death and those that are successfully averted. We discuss current policies and practices related to school shootings and the role of mental health professionals in assessing risk and supporting surviving victims.

  8. Capture, transport and storage of CO2

    International Nuclear Information System (INIS)

    De Boer, B.

    2008-01-01

    The emission of greenhouse gas CO2 in industrial processes and electricity production can be reduced on a large scale. Available techniques include post-combustion, pre-combustion, the oxy-fuel process, CO2 fixation in industrial processes and CO2 mineralization. In the Netherlands, plans for CO2 capture are not developing rapidly (CCS - carbon capture and storage). [mk] [nl

  9. RODZAJE METOD SEKWESTRACJI CO2

    Directory of Open Access Journals (Sweden)

    Zofia LUBAŃSKA

    Full Text Available Z pojęciem ochrony środowiska wiąże się bardzo szeroko w ostatnim czasie omawiane zagadnienie dotyczące ograniczenia emisji CO2. Konsekwencją globalnych zmian klimatu wywołanego przez ludzi jest wzrost stężenia atmosferycznego gazów cieplarnianych, które powodują nasilający się efekt cieplarniany. Wzrasta na świecie liczba ludności, a co za tym idzie wzrasta konsumpcja na jednego mieszkańca, szczególnie w krajach szeroko rozwiniętych gospodarczo. Protokół z Kioto ściśle określa działania jakie należy podjąć w celu zmniejszenia stężenia dwutlenku węgla w atmosferze. Pomimo maksymalnej optymalizacji procesu spalania paliw kopalnianych wykorzystywanych do produkcji energii, zastosowania odnawialnych źródeł energii zmiana klimatu jest nieunikniona i konsekwentnie będzie postępować przez kolejne dekady. Prognozuje się, że duże znaczenie odegra nowoczesna technologia, która ma za zadanie wychwycenie CO2 a następnie składowanie go w odpowiednio wybranych formacjach geologicznych (CCS- Carbon Capture and Storage. Eksperci są zgodni, że ta technologia w niedalekiej przyszłości stanie się rozwiązaniem pozwalającym ograniczyć ogromną ilość emisji CO2 pochodzącą z procesów wytwarzania energii z paliw kopalnych. Z analiz Raportu IPCC wynika, iż technologia CSS może się przyczynić do ok. 20% redukcji emisji dwutlenku węgla przewidzianej do 2050 roku [3]. Zastosowanie jej napotyka na wiele barier, nie tylko technologicznych i ekonomicznych, ale także społecznych. Inną metodą dającą ujemne źródło emisji CO2 jest możliwość wykorzystania obszarów leśnych o odpowiedniej strukturze drzewostanu. Środkiem do tego celu, oprócz ograniczenia zużycia emisjogennych paliw kopalnych (przy zachowaniu zasad zrównoważonego rozwoju może być intensyfikacja zalesień. Zwiększanie lesistości i prawidłowa gospodarka leśna należy do najbardziej efektywnych sposobów kompensowania

  10. Effect of elevated atmospheric CO2 on carbohydrate partitioning and plant growth

    NARCIS (Netherlands)

    Stulen, G; mw. Steg, K.; mw. Schalkwijk, I.; Posthumus, F.S

    2000-01-01

    The effect of elevated CO2 on changes in shoot and root soluble carbohydrate and starch content, and various growth parameters was investigated in an apoplastic (Bellis perennis) and a symplastic loader (Epilobium hirsutum). Comparison with data on other plant species, grown under the same climatic

  11. Dolomite decomposition under CO2

    International Nuclear Information System (INIS)

    Guerfa, F.; Bensouici, F.; Barama, S.E.; Harabi, A.; Achour, S.

    2004-01-01

    Full text.Dolomite (MgCa (CO 3 ) 2 is one of the most abundant mineral species on the surface of the planet, it occurs in sedimentary rocks. MgO, CaO and Doloma (Phase mixture of MgO and CaO, obtained from the mineral dolomite) based materials are attractive steel-making refractories because of their potential cost effectiveness and world wide abundance more recently, MgO is also used as protective layers in plasma screen manufacture ceel. The crystal structure of dolomite was determined as rhombohedral carbonates, they are layers of Mg +2 and layers of Ca +2 ions. It dissociates depending on the temperature variations according to the following reactions: MgCa (CO 3 ) 2 → MgO + CaO + 2CO 2 .....MgCa (CO 3 ) 2 → MgO + Ca + CaCO 3 + CO 2 .....This latter reaction may be considered as a first step for MgO production. Differential thermal analysis (DTA) are used to control dolomite decomposition and the X-Ray Diffraction (XRD) was used to elucidate thermal decomposition of dolomite according to the reaction. That required samples were heated to specific temperature and holding times. The average particle size of used dolomite powders is 0.3 mm, as where, the heating temperature was 700 degree celsius, using various holding times (90 and 120 minutes). Under CO 2 dolomite decomposed directly to CaCO 3 accompanied by the formation of MgO, no evidence was offered for the MgO formation of either CaO or MgCO 3 , under air, simultaneous formation of CaCO 3 , CaO and accompanied dolomite decomposition

  12. Australian Mass Shootings: An Analysis of Incidents and Offenders.

    Science.gov (United States)

    McPhedran, Samara

    2017-06-01

    Mass shooting events are relatively underresearched, and most study comes from the United States. Despite significant international interest, little is known about other countries' experiences of these events. The current study examines Australian mass shooting incidents and offenders, with emphasis on mental illness, life strains, and offenders' life histories. Australia had 14 mass shootings between 1964 and 2014. Most offenders experienced acute life stressors and/or chronic strains leading up to the event; however, diagnosed mental illness was less commonly documented. These observations provide new information about mass shooting incidents and offenders, and can help to inform international policy development.

  13. Nonphotosynthetic CO2 fixation by alfalfa (Medicago sativa L.) roots and nodules

    International Nuclear Information System (INIS)

    Anderson, M.P.; Heichel, G.H.; Vance, C.P.

    1987-01-01

    The dependence of alfalfa (Medicago sativa L.) root and nodule nonphotosynthetic CO 2 fixation on the supply of currently produced photosynthate and nodule nitrogenase activity was examined a various times after phloem-girdling and exposure of nodules to Ar:O 2 . Phloem-girdling was effected 20 hours and exposure to Ar:O 2 was effected 2 to 3 hours before initiation of experiments. Nodule and root CO 2 fixation rates of phloem-girdled plants were reduced to 38 and 50%, respectively, of those of control plants. Exposure to Ar:O 2 decreased nodule CO 2 fixation rates to 45%, respiration rates to 55%, and nitrogenase activities to 51% of those of the controls. The products of nodule CO 2 fixation were exported through the xylem to the shoot mainly as amino acids within 30 to 60 minutes after exposure to 14 CO 2 . In contrast to nodules, roots exported very little radioactivity, and most of the 14 C was exported as organic acids. The nonphotosynthetic CO 2 fixation rate of roots and nodules averaged 26% of the gross respiration rate, i.e. the sum of net respiration and nonphotosynthetic CO 2 assimilation. Nodules fixed CO 2 at a rate 5.6 times that of roots, but since nodules comprised a small portion of root system mass, roots accounted for 76% of the nodulated roots system CO 2 fixation. The results indicate that nodule CO 2 fixation in alfalfa is associated with N assimilation

  14. CO2 emissions: a peak level in 2010

    International Nuclear Information System (INIS)

    Anon.

    2011-01-01

    After a reduction of CO 2 emissions in 2009 due to the financial crisis, these emissions have again reached a peak in 2010: 30.6 Gt, it means an increase by 5% compared to the previous peak. According to IEA (International Energy Agency): 44% of the emissions come from coal, 36% from oil and 20% from natural gas, and OECD countries are responsible of 40% of the CO 2 global emissions but only of 25% of their increase since 2009. For China and India the emissions of CO 2 have increased sharply due to their strong economic growth. (A.C.)

  15. CO2 maximum in the oxygen minimum zone (OMZ)

    OpenAIRE

    Paulmier, Aurélien; Ruiz-Pino, D.; Garcon, V.

    2011-01-01

    International audience; Oxygen minimum zones (OMZs), known as suboxic layers which are mainly localized in the Eastern Boundary Upwelling Systems, have been expanding since the 20th "high CO2" century, probably due to global warming. OMZs are also known to significantly contribute to the oceanic production of N2O, a greenhouse gas (GHG) more efficient than CO2. However, the contribution of the OMZs on the oceanic sources and sinks budget of CO2, the main GHG, still remains to be established. ...

  16. Predictive value of 14CO2 breath tests for clinical use of 13CO2 breath tests

    International Nuclear Information System (INIS)

    Glaubitt, D.M.H.

    1975-01-01

    The knowledge of the efficiency of 14 CO 2 breath tests makes possible the comparison of the efficiency of analogous tests using the stable isotope 13 C. 14 CO 2 exhalation studies render overall information. After parenteral administration of a 14 C labeled substrate, 14 CO 2 breath tests permit insight into the metabolism of the 14 C substrate and the associated intermediary metabolism. If the 14 C substrate is given orally or by intraduodenal instillation, 14 CO 2 breath tests supply information not only about gastrointenstinal absorption and digestion but also about the intermediary metabolism yielding 14 CO 2 , after the administered substrate or its degradation products have been absorbed in the gastrointestinal tract. The fraction of 14 CO 2 arising from absorption, digestion and intermediary metabolism can be estimated only by additional methods. 14 CO 2 breath tests are unable to delineate single metabolic reactions involved in the formation of carbon dioxide. Under these considerations the clinical application of 14 CO 2 breath tests may provide diagnostically useful results, especially in internal medicine and surgery. The tests are suitable for intraindividual assessment of the course of a disease and of therapeutic effects. They may be important in the research of the metabolism of 14 C labeled substrates

  17. Trading CO2 emission; Verhandelbaarheid van CO2-emissies

    Energy Technology Data Exchange (ETDEWEB)

    De Waal, J.F.; Looijenga, A.; Moor, R.; Wissema, E.W.J. [Afdeling Energie, Ministerie van VROM, The Hague (Netherlands)

    2000-06-01

    Systems for CO2-emission trading can take many shapes as developments in Europe show. European developments for emission trading tend to comprehend cap and-trade systems for large emission sources. In the Netherlands a different policy is in preparation. A trading system for sheltered sectors with an option to buy reductions from exposed sectors will be further developed by a Commission, appointed by the minister of environment. Exposed sectors are committed to belong to the top of the world on the area of energy-efficiency. The authors point out that a cap on the distribution of energy carriers natural gas, electricity and fuel seems to be an interesting option to shape the trade scheme. A cap on the distribution of electricity is desirable, but not easy to implement. The possible success of the system depends partly on an experiment with emission reductions. 10 refs.

  18. Does low stomatal conductance or photosynthetic capacity enhance growth at elevated CO2 in Arabidopsis?

    Science.gov (United States)

    Easlon, Hsien Ming; Carlisle, Eli; McKay, John K; Bloom, Arnold J

    2015-03-01

    The objective of this study was to determine if low stomatal conductance (g) increases growth, nitrate (NO3 (-)) assimilation, and nitrogen (N) utilization at elevated CO2 concentration. Four Arabidopsis (Arabidopsis thaliana) near isogenic lines (NILs) differing in g were grown at ambient and elevated CO2 concentration under low and high NO3 (-) supply as the sole source of N. Although g varied by 32% among NILs at elevated CO2, leaf intercellular CO2 concentration varied by only 4% and genotype had no effect on shoot NO3 (-) concentration in any treatment. Low-g NILs showed the greatest CO2 growth increase under N limitation but had the lowest CO2 growth enhancement under N-sufficient conditions. NILs with the highest and lowest g had similar rates of shoot NO3 (-) assimilation following N deprivation at elevated CO2 concentration. After 5 d of N deprivation, the lowest g NIL had 27% lower maximum carboxylation rate and 23% lower photosynthetic electron transport compared with the highest g NIL. These results suggest that increased growth of low-g NILs under N limitation most likely resulted from more conservative N investment in photosynthetic biochemistry rather than from low g. © 2015 American Society of Plant Biologists. All Rights Reserved.

  19. Grey forecasting model for CO2 emissions: A Taiwan study

    International Nuclear Information System (INIS)

    Lin, Chiun-Sin; Liou, Fen-May; Huang, Chih-Pin

    2011-01-01

    Highlights: → CO 2 is the most frequently implicated in global warming. → The CARMA indicates that the Taichung coal-fired power plants had the highest CO 2 emissions in the world. → GM(1,1) prediction accuracy is fairly high. → The results show that the average residual error of the GM(1,1) was below 10%. -- Abstract: Among the various greenhouse gases associated with climate change, CO 2 is the most frequently implicated in global warming. The latest data from Carbon Monitoring for Action (CARMA) shows that the coal-fired power plant in Taichung, Taiwan emitted 39.7 million tons of CO 2 in 2007 - the highest of any power plant in the world. Based on statistics from Energy International Administration, the annual CO 2 emissions in Taiwan have increased 42% from 1997 until 2006. Taiwan has limited natural resources and relies heavily on imports to meet its energy needs, and the government must take serious measures control energy consumption to reduce CO 2 emissions. Because the latest data was from 2009, this study applied the grey forecasting model to estimate future CO 2 emissions in Taiwan from 2010 until 2012. Forecasts of CO 2 emissions in this study show that the average residual error of the GM(1,1) was below 10%. Overall, the GM(1,1) predicted further increases in CO 2 emissions over the next 3 years. Although Taiwan is not a member of the United Nations and is not bound by the Kyoto Protocol, the findings of this study provide a valuable reference with which the Taiwanese government could formulate measures to reduce CO 2 emissions by curbing the unnecessary the consumption of energy.

  20. Alberta industrial synergy CO2 programs initiative

    International Nuclear Information System (INIS)

    Yildirim, E.

    1998-01-01

    The various industrial sectors within Alberta produce about 350,000 tonnes of CO 2 per day. This presentation was concerned with how this large volume and high concentration of CO 2 can be used in industrial and agricultural applications, because every tonne of CO 2 used for such purposes is a tonne that does not end up in the atmosphere. There is a good potential for an industrial synergy between the producers and users of CO 2 . The Alberta Industrial Synergy CO 2 Programs Initiative was established to ultimately achieve a balance between the producers of CO 2 and the users of CO 2 by creating ways to use the massive quantities of CO 2 produced by Alberta's hydrocarbon-based economy. The Alberta CO 2 Research Steering Committee was created to initiate and support CO 2 programs such as: (1) CO 2 use in enhanced oil recovery, (2) creation of a CO 2 production inventory, (3) survey of CO 2 users and potential users, (4) investigation of process issues such as power generation, oil sands and cement manufacturing, and (5) biofixation by plants, (6) other disposal options (e.g. in depleted oil and gas reservoirs, in aquifers, in tailings ponds, in coal beds). The single most important challenge was identified as 'rationalizing the formation of the necessary infrastructure'. Failing to do that will greatly impede efforts directed towards CO 2 utilization

  1. PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP

    Energy Technology Data Exchange (ETDEWEB)

    Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O' Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

    2006-01-01

    During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

  2. PEAT-CO2. Assessment of CO2 emissions from drained peatlands in SE Asia

    International Nuclear Information System (INIS)

    Hooijer, A.; Silvius, M.; Woesten, H.; Page, S.

    2006-12-01

    Forested tropical peatlands in SE Asia store at least 42,000 Megatonnes of soil carbon. This carbon is increasingly released to the atmosphere due to drainage and fires associated with plantation development and logging. Peatlands make up 12% of the SE Asian land area but account for 25% of current deforestation. Out of 27 million hectares of peatland, 12 million hectares (45%) are currently deforested and mostly drained. One important crop in drained peatlands is palm oil, which is increasingly used as a biofuel in Europe. In the PEAT-CO2 project, present and future emissions from drained peatlands were quantified using the latest data on peat extent and depth, present and projected land use and water management practice, decomposition rates and fire emissions. It was found that current likely CO2 emissions caused by decomposition of drained peatlands amounts to 632 Mt/y (between 355 and 874 Mt/y). This emission will increase in coming decades unless land management practices and peatland development plans are changed, and will continue well beyond the 21st century. In addition, over 1997-2006 an estimated average of 1400 Mt/y in CO2 emissions was caused by peatland fires that are also associated with drainage and degradation. The current total peatland CO2 emission of 2000 Mt/y equals almost 8% of global emissions from fossil fuel burning. These emissions have been rapidly increasing since 1985 and will further increase unless action is taken. Over 90% of this emission originates from Indonesia, which puts the country in 3rd place (after the USA and China) in the global CO2 emission ranking. It is concluded that deforested and drained peatlands in SE Asia are a globally significant source of CO2 emissions and a major obstacle to meeting the aim of stabilizing greenhouse gas emissions, as expressed by the international community. It is therefore recommended that international action is taken to help SE Asian countries, especially Indonesia, to better conserve

  3. Influence of root-bed size on the response of tobacco to elevated CO2 as mediated by cytokinins

    Science.gov (United States)

    Schaz, Ulrike; Düll, Barbara; Reinbothe, Christiane; Beck, Erwin

    2014-01-01

    The extent of growth stimulation of C3 plants by elevated CO2 is modulated by environmental factors. Under optimized environmental conditions (high light, continuous water and nutrient supply, and others), we analysed the effect of an elevated CO2 atmosphere (700 ppm, EC) and the importance of root-bed size on the growth of tobacco. Biomass production was consistently higher under EC. However, the stimulation was overridden by root-bed volumes that restricted root growth. Maximum growth and biomass production were obtained at a root bed of 15 L at ambient and elevated CO2 concentrations. Starting with seed germination, the plants were strictly maintained under ambient or elevated CO2 until flowering. Thus, the well-known acclimation effect of growth to enhanced CO2 did not occur. The relative growth rates of EC plants exceeded those of ambient-CO2 plants only during the initial phases of germination and seedling establishment. This was sufficient for a persistently higher absolute biomass production by EC plants in non-limiting root-bed volumes. Both the size of the root bed and the CO2 concentration influenced the quantitative cytokinin patterns, particularly in the meristematic tissues of shoots, but to a smaller extent in stems, leaves and roots. In spite of the generally low cytokinin concentrations in roots, the amounts of cytokinins moving from the root to the shoot were substantially higher in high-CO2 plants. Because the cytokinin patterns of the (xylem) fluid in the stems did not match those of the shoot meristems, it is assumed that cytokinins as long-distance signals from the roots stimulate meristematic activity in the shoot apex and the sink leaves. Subsequently, the meristems are able to synthesize those phytohormones that are required for the cell cycle. Root-borne cytokinins entering the shoot appear to be one of the major control points for the integration of various environmental cues into one signal for optimized growth. PMID:24790131

  4. CO2 reduction through energy conservation

    International Nuclear Information System (INIS)

    1991-05-01

    A study was carried out of the potential to economically reduce carbon dioxide emissions through energy conservation in the petroleum and natural gas industry. The study examined current and projected emissions levels, cogeneration at gas plants, flaring, economics, regulation, reporting requirements, implementation, and research and development. Economically attractive energy conservation measures can reduce oil and gas industry, exclusive of Athabasca oil sands operations, CO 2 emissions by 6-7%. The energy conservation options identified range from field energy awareness committees through to equipment retrofits and replacement. At ca 3 million tonnes/y, these reductions will not offset the increases in oil and gas related CO 2 emissions anticipated by producers and Alberta government agencies. There will be increasing emphasis on in-situ bitumen production, more energy intensive light crude oil production and increasing natural gas sales, increasing energy inputs in excess of reductions. Cogeneration of electricity for utility company distribution and for internally required steam at gas plants and in-situ production sites is not economic due to low electricity prices. 8 tabs

  5. Plant growth and leaf-spot severity on eucalypt at different CO2 concentrations in the air

    Directory of Open Access Journals (Sweden)

    Carlos Eduardo Oliveira da Silva

    2014-03-01

    Full Text Available The objective of this work was to evaluate the effects of increased air-CO2 concentration on plant growth and on leaf-spot caused by Cylindrocladium candelabrum in Eucalyptus urophylla. Seedlings were cultivated for 30 days at 451, 645, 904, and 1,147 µmol mol-1 CO2 ; then, they were inoculated with the pathogen and kept under the same conditions for seven days. Increased CO2 concentration increased plant height and shoot dry matter mass, and decreased disease incidence and severity. Stem diameter was not affected by the treatments. Increased concentrations of atmospheric CO2 favorably affect eucalypt growth and reduce leaf-spot severity.

  6. ISLSCP II Globalview: Atmospheric CO2 Concentrations

    Data.gov (United States)

    National Aeronautics and Space Administration — The GlobalView Carbon Dioxide (CO2) data product contains synchronized and smoothed time series of atmospheric CO2 concentrations at selected sites that were created...

  7. Bioelectrochemical conversion of CO2 to chemicals

    NARCIS (Netherlands)

    Bajracharya, Suman; Vanbroekhoven, Karolien; Buisman, Cees J.N.; Strik, David P.B.T.B.; Pant, Deepak

    2017-01-01

    The recent concept of microbial electrosynthesis (MES) has evolved as an electricity-driven production technology for chemicals from low-value carbon dioxide (CO2) using micro-organisms as biocatalysts. MES from CO2 comprises bioelectrochemical reduction of CO2 to multi-carbon organic compounds

  8. A multi-regional MARKAL-MACRO model to study an international market of CO2 emission permits. A detailed analysis of a burden sharing strategy among the Netherlands, Sweden and Switzerland

    International Nuclear Information System (INIS)

    Bahn, O.; Barreto, L.; Bueeler, B.; Kypreos, S.

    1997-11-01

    The development of a multi-regional MARKAL-MACRO (mMM) model and associated solution techniques have been actively continued during the first year (July 1996 - June 1997) of the IEA/ETSAP/Annex VI. This has been a joint research effort between: - the Systems Analysis Section of the Paul Scherrer Institute (PSI), - the Inst. for Operations Research (IFOR) of the Swiss Federal Inst. of Technology at Zurich, - the Logistics Lab. (Logilab) of the Univ. of Geneva, and - the different ETSAP partners that provide the regional MARKAL-MACRO (MM) models. This report intends to give an update on the development of mMM and associated solution techniques, highlighting the progress made since July 1996. It details also first JI study performed with mMM. The mMM model enables one to study an international co-operation to curb jointly carbon dioxide (CO 2 ) emissions through a market of emission permits, and to evaluate the economic implications of co-ordinating abatement policies on the participating regions. Along with emission permits, the regions may exchange other goods. So far, only an aggregate good in monetary unit has been considered. The mMM model integrates regional MM models into a meta-modelling framework. This integration can be done following two equivalent alternatives: mMM can be formulated either with market equilibrium conditions, or with an aggregated utility function and a global excess constraint. In both alternatives, regional MM models have to be extended by coherent budget and/or trade relationships. A first coding of a mMM model with three countries had been done in GAMS. Work has been done to generalise this coding to consider more traded goods and more countries. To solve mMM, two alternative mathematical methods can be used. The first one considers mMM formulated with market equilibrium conditions, and solves it as a variational inequality problem using a cutting plane algorithm. The second one considers mMM formulated with an aggregated utility

  9. Possibilities for reducing CO2 emissions by rational energy used as viewed by enterprises

    International Nuclear Information System (INIS)

    Preuss, H.J.

    1993-01-01

    From the view of the industry, energy conservation offers many options for CO 2 reduction. CO 2 reduction in electric power generation is particularly important. The global CO 2 problem cannot be solved by any single measure, but international efforts are required in all production and consumption sectors. Providing energy for the growing world population while at the same time reducing CO 2 is one of the biggest challenges ever faced by mankind. (orig./UA) [de

  10. Analysis of ex situ processes of CO2 sequestration. Final report

    International Nuclear Information System (INIS)

    Touze, S.; Bourgeois, F.; Baranger, P.; Durst, P.

    2004-01-01

    The aim of this study is to bring quantitative elements to evaluate the validation of the CO 2 mineral sequestration to limit the greenhouse effect gases. This analysis aims to calculate the CO 2 accounting of the system (internal energy production balance the energy expend) sequestrated CO 2 and produced CO 2 . The first part detailed the possible experimental solutions. Then two carbonation processes, direct and indirect, have been chosen of the analysis. (A.L.B.)

  11. Millet's Shooting Stars

    Science.gov (United States)

    Beech, M.

    1988-12-01

    In this essay two paintings by the French artist Jean-Francois Millet are described. These paintings, Les Etoiles Filantes and Nuit Etoilée are particularly interesting since they demonstrate the rare artistic employment of the shooting-star image and metaphor.

  12. Distributed trouble-shooting

    NARCIS (Netherlands)

    Post, W.M.; Bogaard, S.A.A. van den; Rasker, P.C.

    2004-01-01

    When knowledge, required for trouble-shooting at sea, can be supplied real-time but from a distance, problems, such as with the limited availability of specialists, and the high costs of maintenance, may be tackled. Unclear is, however, how this redistribution of knowledge will work in practice. We

  13. School Shootings Stun Reservation

    Science.gov (United States)

    Borja, Rhea R.; Cavanagh, Sean

    2005-01-01

    This article deals with the impact brought by the school shootings at Red Lake Indian Reservation in Minnesota to the school community. A deeply troubled 16-year-old student shot and killed seven other people and himself at a high school. The nation's deadliest school attack since the 1999 slayings at Colorado's suburban Columbine High School took…

  14. The greenhouse effect and the amount of CO2 emissions in Romania

    International Nuclear Information System (INIS)

    Manea, Gh.

    1992-01-01

    In order to reduce the CO 2 emissions, responsible by the greenhouse effect on Terra, an international control for monitoring them is to be instated. The development of methods for reducing the CO 2 emissions, implies the identification and evaluation of the CO 2 sources, the forecasting of probable evolution of the CO 2 emissions, and also the assessment of the economic impact. This paper tries to accomplish such an evaluation and to draft several scenarios for reduction of the CO 2 emissions. Also considerations about the suitability of the Romanian adhesion to the international treaties regarding the greenhouse effect monitoring are presented. (author). 7 tabs

  15. Monitoring CO2 emissions to gain a dynamic view of carbon allocation to arbuscular mycorrhizal fungi.

    Science.gov (United States)

    Slavíková, Renata; Püschel, David; Janoušková, Martina; Hujslová, Martina; Konvalinková, Tereza; Gryndlerová, Hana; Gryndler, Milan; Weiser, Martin; Jansa, Jan

    2017-01-01

    Quantification of carbon (C) fluxes in mycorrhizal plants is one of the important yet little explored tasks of mycorrhizal physiology and ecology. 13 CO 2 pulse-chase labelling experiments are increasingly being used to track the fate of C in these plant-microbial symbioses. Nevertheless, continuous monitoring of both the below- and aboveground CO 2 emissions remains a challenge, although it is necessary to establish the full C budget of mycorrhizal plants. Here, a novel CO 2 collection system is presented which allows assessment of gaseous CO 2 emissions (including isotopic composition of their C) from both belowground and shoot compartments. This system then is used to quantify the allocation of recently fixed C in mycorrhizal versus nonmycorrhizal Medicago truncatula plants with comparable biomass and mineral nutrition. Using this system, we confirmed substantially greater belowground C drain in mycorrhizal versus nonmycorrhizal plants, with the belowground CO 2 emissions showing large variation because of fluctuating environmental conditions in the glasshouse. Based on the assembled 13 C budget, the C allocation to the mycorrhizal fungus was between 2.3% (increased 13 C allocation to mycorrhizal substrate) and 2.9% (reduction of 13 C allocation to mycorrhizal shoots) of the plant gross photosynthetic production. Although the C allocation to shoot respiration (measured during one night only) did not differ between the mycorrhizal and nonmycorrhizal plants under our experimental conditions, it presented a substantial part (∼10%) of the plant C budget, comparable to the amount of CO 2 released belowground. These results advocate quantification of both above- and belowground CO 2 emissions in future studies.

  16. Tritium removal by CO2 laser heating

    International Nuclear Information System (INIS)

    Skinner, C.H.; Kugel, H.; Mueller, D.

    1997-10-01

    Efficient techniques for rapid tritium removal will be necessary for ITER (International Thermonuclear Experimental Reactor) to meet its physics and engineering goals. One potential technique is transient surface heating by a scanning CO 2 or Nd:YAG laser that would release tritium without the severe engineering difficulties of bulk heating of the vessel. The authors have modeled the heat propagation into a surface layer and find that a multi-kW/cm 2 flux with an exposure time of order 10 msec is suitable to heat a 50 micron co-deposited layer to 1,000--2,000 degrees. Improved wall conditioning may be a significant side benefit. They identify remaining issues that need to be addressed experimentally

  17. US calls for CO2 cut

    International Nuclear Information System (INIS)

    Roberts, M.

    1996-01-01

    The US Government has outraged energy-intensive industries by calling for an international agreement to reduce global emissions of carbon dioxide (CO 2 ) and other greenhouse gases. In a clear policy shift, the US--the world's largest emitter of greenhouse gases and not previously an advocate of curbing them--says it now intends to lead moves to prevent global warming. At last week's Second Conference of the Parties (COP-2) to the United Nations Framework Convention on Climate Change (FCCC), US Undersecretary for Global Affairs Timothy Wirth called for open-quotes an agreement that sets a realistic, verifiable, and binding medium-term emissions target.close quotes Individual countries should be free to choose how to meet targets, and the US favors market-based mechanisms, he says. open-quotes Climate change is a serious problem and will require sustained long-term investment to be addressed successfully,close quotes Wirth says

  18. Integrated system for capturing CO2 as feedstock for algae production: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016, 14-18 November 2016, Lausanne, Switzerland

    NARCIS (Netherlands)

    Könst, P.M.; Hernandez Mireles, I.; Stel, R.W. van der; Os, P.M van; Goetheer, E.L.V.

    2017-01-01

    In view of its promise as sustainable process for CO2 capture and its potential in the production of feed, food and natural high value products such as omega-3 fatty acids and anti-oxidants such as astaxanthin, large scale algae cultivation is gaining commercial interest. Currently, most systems are

  19. A multinational model for CO2 reduction: defining boundaries of future CO2 emissions in nine countries

    International Nuclear Information System (INIS)

    Kram, Tom; Hill, Douglas.

    1996-01-01

    A need to make substantial future reductions in greenhouse gas emissions would require major changes in national energy systems. Nine industrialized countries have explored the technical boundaries of CO 2 emission restrictions during the next 40 to 50 years using comparable scenario assumptions and a standard model, MARKAL. Quantitative results for the countries are shown side by side in a set of energy maps that compare the least-cost evolution of the national energy systems by the main factors that contribute to CO 2 emissions. The ability to restrict future CO 2 emissions and the most cost-effective measures for doing so differ among the countries; an international agreement that would mandate substantial emission restrictions among countries by an equal percentage reduction is clearly impossible. The results are a first step toward a basis for allocating such international reductions, and the multinational process by which they were produced provides an example for further international greenhouse gas abatement costing studies. (Author)

  20. Monoterpene and herbivore-induced emissions from cabbage plants grown at elevated atmospheric CO 2 concentration

    Science.gov (United States)

    Vuorinen, Terhi; Reddy, G. V. P.; Nerg, Anne-Marja; Holopainen, Jarmo K.

    The warming of the lower atmosphere due to elevating CO 2 concentration may increase volatile organic compound (VOC) emissions from plants. Also, direct effects of elevated CO 2 on plant secondary metabolism are expected to lead to increased VOC emissions due to allocation of excess carbon on secondary metabolites, of which many are volatile. We investigated how growing at doubled ambient CO 2 concentration affects emissions from cabbage plants ( Brassica oleracea subsp. capitata) damaged by either the leaf-chewing larvae of crucifer specialist diamondback moth ( Plutella xylostella L.) or generalist Egyptian cotton leafworm ( Spodoptera littoralis (Boisduval)). The emission from cabbage cv. Lennox grown in both CO 2 concentrations, consisted mainly of monoterpenes (sabinene, limonene, α-thujene, 1,8-cineole, β-pinene, myrcene, α-pinene and γ-terpinene). ( Z)-3-Hexenyl acetate, sesquiterpene ( E, E)- α-farnesene and homoterpene ( E)-4,8-dimethyl-1,3,7-nonatriene (DMNT) were emitted mainly from herbivore-damaged plants. Plants grown at 720 μmol mol -1 of CO 2 had significantly lower total monoterpene emissions per shoot dry weight than plants grown at 360 μmol mol -1 of CO 2, while damage by both herbivores significantly increased the total monoterpene emissions compared to intact plants. ( Z)-3-Hexenyl acetate, ( E, E)- α-farnesene and DMNT emissions per shoot dry weight were not affected by the growth at elevated CO 2. The emission of DMNT was significantly enhanced from plants damaged by the specialist P. xylostella compared to the plants damaged by the generalist S. littoralis. The relative proportions of total monoterpenes and total herbivore-induced compounds of total VOCs did not change due to the growth at elevated CO 2, while insect damage increased significantly the proportion of induced compounds. The results suggest that VOC emissions that are induced by the leaf-chewing herbivores will not be influenced by elevated CO 2 concentration.

  1. Effect of Mineral Dissolution/Precipitation and CO2 Exsolution on CO2 transport in Geological Carbon Storage.

    Science.gov (United States)

    Xu, Ruina; Li, Rong; Ma, Jin; He, Di; Jiang, Peixue

    2017-09-19

    Geological carbon sequestration (GCS) in deep saline aquifers is an effective means for storing carbon dioxide to address global climate change. As the time after injection increases, the safety of storage increases as the CO 2 transforms from a separate phase to CO 2 (aq) and HCO 3 - by dissolution and then to carbonates by mineral dissolution. However, subsequent depressurization could lead to dissolved CO 2 (aq) escaping from the formation water and creating a new separate phase which may reduce the GCS system safety. The mineral dissolution and the CO 2 exsolution and mineral precipitation during depressurization change the morphology, porosity, and permeability of the porous rock medium, which then affects the two-phase flow of the CO 2 and formation water. A better understanding of these effects on the CO 2 -water two-phase flow will improve predictions of the long-term CO 2 storage reliability, especially the impact of depressurization on the long-term stability. In this Account, we summarize our recent work on the effect of CO 2 exsolution and mineral dissolution/precipitation on CO 2 transport in GCS reservoirs. We place emphasis on understanding the behavior and transformation of the carbon components in the reservoir, including CO 2 (sc/g), CO 2 (aq), HCO 3 - , and carbonate minerals (calcite and dolomite), highlight their transport and mobility by coupled geochemical and two-phase flow processes, and consider the implications of these transport mechanisms on estimates of the long-term safety of GCS. We describe experimental and numerical pore- and core-scale methods used in our lab in conjunction with industrial and international partners to investigate these effects. Experimental results show how mineral dissolution affects permeability, capillary pressure, and relative permeability, which are important phenomena affecting the input parameters for reservoir flow modeling. The porosity and the absolute permeability increase when CO 2 dissolved water is

  2. Forest succession at elevated CO2; TOPICAL

    International Nuclear Information System (INIS)

    Clark, James S.; Schlesinger, William H.

    2002-01-01

    We tested hypotheses concerning the response of forest succession to elevated CO2 in the FACTS-1 site at the Duke Forest. We quantified growth and survival of naturally recruited seedlings, tree saplings, vines, and shrubs under ambient and elevated CO2. We planted seeds and seedlings to augment sample sites. We augmented CO2 treatments with estimates of shade tolerance and nutrient limitation while controlling for soil and light effects to place CO2 treatments within the context of natural variability at the site. Results are now being analyzed and used to parameterize forest models of CO2 response

  3. The Level of Vision Necessary for Competitive Performance in Rifle Shooting: Setting the Standards for Paralympic Shooting with Vision Impairment

    NARCIS (Netherlands)

    Allen, P.M.; Latham, K.; Mann, D.L.; Ravensbergen, H.J.C.; Myint, J.

    2016-01-01

    The aim of this study was to investigate the level of vision impairment (VI) that would reduce performance in shooting; to guide development of entry criteria to visually impaired (VI) shooting. Nineteen international-level shooters without VI took part in the study. Participants shot an air rifle,

  4. Residual CO2 trapping in Indiana limestone.

    Science.gov (United States)

    El-Maghraby, Rehab M; Blunt, Martin J

    2013-01-02

    We performed core flooding experiments on Indiana limestone using the porous plate method to measure the amount of trapped CO(2) at a temperature of 50 °C and two pressures: 4.2 and 9 MPa. Brine was mixed with CO(2) for equilibration, then the mixture was circulated through a sacrificial core. Porosity and permeability tests conducted before and after 884 h of continuous core flooding confirmed negligible dissolution. A trapping curve for supercritical (sc)CO(2) in Indiana showing the relationship between the initial and residual CO(2) saturations was measured and compared with that of gaseous CO(2). The results were also compared with scCO(2) trapping in Berea sandstone at the same conditions. A scCO(2) residual trapping end point of 23.7% was observed, indicating slightly less trapping of scCO(2) in Indiana carbonates than in Berea sandstone. There is less trapping for gaseous CO(2) (end point of 18.8%). The system appears to be more water-wet under scCO(2) conditions, which is different from the trend observed in Berea; we hypothesize that this is due to the greater concentration of Ca(2+) in brine at higher pressure. Our work indicates that capillary trapping could contribute to the immobilization of CO(2) in carbonate aquifers.

  5. CO2 clearance by membrane lungs.

    Science.gov (United States)

    Sun, Liqun; Kaesler, Andreas; Fernando, Piyumindri; Thompson, Alex J; Toomasian, John M; Bartlett, Robert H

    2018-05-01

    Commercial membrane lungs are designed to transfer a specific amount of oxygen per unit of venous blood flow. Membrane lungs are much more efficient at removing CO 2 than adding oxygen, but the range of CO 2 transfer is rarely reported. Commercial membrane lungs were studied with the goal of evaluating CO 2 removal capacity. CO 2 removal was measured in 4 commercial membrane lungs under standardized conditions. CO 2 clearance can be greater than 4 times that of oxygen at a given blood flow when the gas to blood flow ratio is elevated to 4:1 or 8:1. The CO 2 clearance was less dependent on surface area and configuration than oxygen transfer. Any ECMO system can be used for selective CO 2 removal.

  6. CO2 and nutrient-driven changes across multiple levels of organization in Zostera noltii ecosystems

    Science.gov (United States)

    Martínez-Crego, B.; Olivé, I.; Santos, R.

    2014-12-01

    Increasing evidence emphasizes that the effects of human impacts on ecosystems must be investigated using designs that incorporate the responses across levels of biological organization as well as the effects of multiple stressors. Here we implemented a mesocosm experiment to investigate how the individual and interactive effects of CO2 enrichment and eutrophication scale-up from changes in primary producers at the individual (biochemistry) or population level (production, reproduction, and/or abundance) to higher levels of community (macroalgae abundance, herbivory, and global metabolism), and ecosystem organization (detritus release and carbon sink capacity). The responses of Zostera noltii seagrass meadows growing in low- and high-nutrient field conditions were compared. In both meadows, the expected CO2 benefits on Z. noltii leaf production were suppressed by epiphyte overgrowth, with no direct CO2 effect on plant biochemistry or population-level traits. Multi-level meadow response to nutrients was faster and stronger than to CO2. Nutrient enrichment promoted the nutritional quality of Z. noltii (high N, low C : N and phenolics), the growth of epiphytic pennate diatoms and purple bacteria, and shoot mortality. In the low-nutrient meadow, individual effects of CO2 and nutrients separately resulted in reduced carbon storage in the sediment, probably due to enhanced microbial degradation of more labile organic matter. These changes, however, had no effect on herbivory or on community metabolism. Interestingly, individual effects of CO2 or nutrient addition on epiphytes, shoot mortality, and carbon storage were attenuated when nutrients and CO2 acted simultaneously. This suggests CO2-induced benefits on eutrophic meadows. In the high-nutrient meadow, a striking shoot decline caused by amphipod overgrazing masked the response to CO2 and nutrient additions. Our results reveal that under future scenarios of CO2, the responses of seagrass ecosystems will be complex and

  7. Extraction of stevia glycosides with CO2 + water, CO2 + ethanol, and CO2 + water + ethanol

    Directory of Open Access Journals (Sweden)

    A. Pasquel

    2000-09-01

    Full Text Available Stevia leaves are an important source of natural sugar substitute. There are some restrictions on the use of stevia extract because of its distinctive aftertaste. Some authors attribute this to soluble material other than the stevia glycosides, even though it is well known that stevia glycosides have to some extent a bitter taste. Therefore, the purpose of this work was to develop a process to obtain stevia extract of a better quality. The proposed process includes two steps: i Pretreatment of the leaves by SCFE; ii Extraction of the stevia glycosides by SCFE using CO2 as solvent and water and/or ethanol as cosolvent. The mean total yield for SCFE pretreatment was 3.0%. The yields for SCFE with cosolvent of stevia glycosides were below 0.50%, except at 120 bar, 16°C, and 9.5% (molar of water. Under this condition, total yield was 3.4%. The quality of the glycosidic fraction with respect to its capacity as sweetener was better for the SCFE extract as compared to extract obtained by the conventional process. The overall extraction curves were well described by the Lack extended model.

  8. Combined impact of water column oxygen and temperature on internal oxygen status and growth of Zostera marina seedlings and adult shoots

    DEFF Research Database (Denmark)

    Raun, Ane-Marie Løvendahl; Borum, Jens

    2013-01-01

    Eelgrass (Zostera marina L.) occasionally experiences severe die-offs during warm summer periods with variable water column oxygen partial pressures (pO). Eelgrass is known to be very intolerant to tissue anoxia with reduced growth and increasing mortality after ≤12h anoxia in the dark...... at temperatures of ≥25°C. In the present study we experimentally examine the impact of combined water column oxygen and temperature on oxygen dynamics in leaf meristems of seedlings and adult shoots to better understand how stressful environmental conditions affect eelgrass oxygen dynamics and subsequent growth...... and mortality. There was a strong interaction between water column oxygen and temperature on meristem pO implying that eelgrass is rather resistant to unfavorable oxygen conditions in winter but becomes increasingly vulnerable in summer, especially at high temperatures. At 25°C meristems became anoxic...

  9. Variability in soil CO2 production and surface CO2 efflux across riparian-hillslope transitions

    Science.gov (United States)

    Vincent Jerald. Pacific

    2007-01-01

    The spatial and temporal controls on soil CO2 production and surface CO2 efflux have been identified as an outstanding gap in our understanding of carbon cycling. I investigated both the spatial and temporal variability of soil CO2 concentrations and surface CO2 efflux across eight topographically distinct riparian-hillslope transitions in the ~300 ha subalpine upper-...

  10. CO2 flux from Javanese mud volcanism.

    Science.gov (United States)

    Queißer, M; Burton, M R; Arzilli, F; Chiarugi, A; Marliyani, G I; Anggara, F; Harijoko, A

    2017-06-01

    Studying the quantity and origin of CO 2 emitted by back-arc mud volcanoes is critical to correctly model fluid-dynamical, thermodynamical, and geochemical processes that drive their activity and to constrain their role in the global geochemical carbon cycle. We measured CO 2 fluxes of the Bledug Kuwu mud volcano on the Kendeng Fold and thrust belt in the back arc of Central Java, Indonesia, using scanning remote sensing absorption spectroscopy. The data show that the expelled gas is rich in CO 2 with a volume fraction of at least 16 vol %. A lower limit CO 2 flux of 1.4 kg s -1 (117 t d -1 ) was determined, in line with the CO 2 flux from the Javanese mud volcano LUSI. Extrapolating these results to mud volcanism from the whole of Java suggests an order of magnitude total CO 2 flux of 3 kt d -1 , comparable with the expected back-arc efflux of magmatic CO 2 . After discussing geochemical, geological, and geophysical evidence we conclude that the source of CO 2 observed at Bledug Kuwu is likely a mixture of thermogenic, biogenic, and magmatic CO 2 , with faulting controlling potential pathways for magmatic fluids. This study further demonstrates the merit of man-portable active remote sensing instruments for probing natural gas releases, enabling bottom-up quantification of CO 2 fluxes.

  11. Modeling of CO2 storage in aquifers

    International Nuclear Information System (INIS)

    Savioli, Gabriela B; Santos, Juan E

    2011-01-01

    Storage of CO 2 in geological formations is a means of mitigating the greenhouse effect. Saline aquifers are a good alternative as storage sites due to their large volume and their common occurrence in nature. The first commercial CO 2 injection project is that of the Sleipner field in the Utsira Sand aquifer (North Sea). Nevertheless, very little was known about the effectiveness of CO 2 sequestration over very long periods of time. In this way, numerical modeling of CO 2 injection and seismic monitoring is an important tool to understand the behavior of CO 2 after injection and to make long term predictions in order to prevent CO 2 leaks from the storage into the atmosphere. The description of CO 2 injection into subsurface formations requires an accurate fluid-flow model. To simulate the simultaneous flow of brine and CO 2 we apply the Black-Oil formulation for two phase flow in porous media, which uses the PVT data as a simplified thermodynamic model. Seismic monitoring is modeled using Biot's equations of motion describing wave propagation in fluid-saturated poroviscoelastic solids. Numerical examples of CO 2 injection and time-lapse seismics using data of the Utsira formation show the capability of this methodology to monitor the migration and dispersal of CO 2 after injection.

  12. Explaining CO2 fluctuations observed in snowpacks

    Science.gov (United States)

    Graham, Laura; Risk, David

    2018-02-01

    Winter soil carbon dioxide (CO2) respiration is a significant and understudied component of the global carbon (C) cycle. Winter soil CO2 fluxes can be surprisingly variable, owing to physical factors such as snowpack properties and wind. This study aimed to quantify the effects of advective transport of CO2 in soil-snow systems on the subdiurnal to diurnal (hours to days) timescale, use an enhanced diffusion model to replicate the effects of CO2 concentration depletions from persistent winds, and use a model-measure pairing to effectively explore what is happening in the field. We took continuous measurements of CO2 concentration gradients and meteorological data at a site in the Cape Breton Highlands of Nova Scotia, Canada, to determine the relationship between wind speeds and CO2 levels in snowpacks. We adapted a soil CO2 diffusion model for the soil-snow system and simulated stepwise changes in transport rate over a broad range of plausible synthetic cases. The goal was to mimic the changes we observed in CO2 snowpack concentration to help elucidate the mechanisms (diffusion, advection) responsible for observed variations. On subdiurnal to diurnal timescales with varying winds and constant snow levels, a strong negative relationship between wind speed and CO2 concentration within the snowpack was often identified. Modelling clearly demonstrated that diffusion alone was unable to replicate the high-frequency CO2 fluctuations, but simulations using above-atmospheric snowpack diffusivities (simulating advective transport within the snowpack) reproduced snow CO2 changes of the observed magnitude and speed. This confirmed that wind-induced ventilation contributed to episodic pulsed emissions from the snow surface and to suppressed snowpack concentrations. This study improves our understanding of winter CO2 dynamics to aid in continued quantification of the annual global C cycle and demonstrates a preference for continuous wintertime CO2 flux measurement systems.

  13. Porous Organic Polymers for CO2 Capture

    KAUST Repository

    Teng, Baiyang

    2013-05-01

    Carbon dioxide (CO2) has long been regarded as the major greenhouse gas, which leads to numerous negative effects on global environment. The capture and separation of CO2 by selective adsorption using porous materials proves to be an effective way to reduce the emission of CO2 to atmosphere. Porous organic polymers (POPs) are promising candidates for this application due to their readily tunable textual properties and surface functionalities. The objective of this thesis work is to develop new POPs with high CO2 adsorption capacities and CO2/N2 selectivities for post-combustion effluent (e.g. flue gas) treatment. We will also exploit the correlation between the CO2 capture performance of POPs and their textual properties/functionalities. Chapters Two focuses on the study of a group of porous phenolic-aldehyde polymers (PPAPs) synthesized by a catalyst-free method, the CO2 capture capacities of these PPAPs exceed 2.0 mmol/g at 298 K and 1 bar, while keeping CO2/N2 selectivity of more than 30 at the same time. Chapter Three reports the gas adsorption results of different hyper-cross-linked polymers (HCPs), which indicate that heterocyclo aromatic monomers can greatly enhance polymers’ CO2/N2 selectivities, and the N-H bond is proved to the active CO2 adsorption center in the N-contained (e.g. pyrrole) HCPs, which possess the highest selectivities of more than 40 at 273 K when compared with other HCPs. Chapter Four emphasizes on the chemical modification of a new designed polymer of intrinsic microporosity (PIM) with high CO2/N2 selectivity (50 at 273 K), whose experimental repeatability and chemical stability prove excellent. In Chapter Five, we demonstrate an improvement of both CO2 capture capacity and CO2/N2 selectivity by doping alkali metal ions into azo-polymers, which leads a promising method to the design of new porous organic polymers.

  14. Radiographing roots and shoots

    International Nuclear Information System (INIS)

    Shariffah Noor Khamseah Al Idid

    1985-01-01

    The effect of seed orientation on germination time and on shoot and root growth patterns is studied. Neutron radiography is used to observe the development of 4 types of plants, maize, greenpea, soya bean and padi. These plants were grown in varying orientations; sand sizes, sand thicknesses, and level of water content. Radiography of the seeds and plants were obtained for time exposure ranging from 3-12 hours and at reactor thermal power level, ranging from 500-750 kilowatts. Results obtained showed that seeds planted in varying orientations need different length of time for shoot emergence. Neutron radiography is now developed to other areas of non-industrial applications in Malaysia. (A.J.)

  15. Root damage by insects reverses the effects of elevated atmospheric CO2 on Eucalypt seedlings.

    Directory of Open Access Journals (Sweden)

    Scott N Johnson

    Full Text Available Predicted increases in atmospheric carbon dioxide (CO2 are widely anticipated to increase biomass accumulation by accelerating rates of photosynthesis in many plant taxa. Little, however, is known about how soil-borne plant antagonists might modify the effects of elevated CO2 (eCO2, with root-feeding insects being particularly understudied. Root damage by insects often reduces rates of photosynthesis by disrupting root function and imposing water deficits. These insects therefore have considerable potential for modifying plant responses to eCO2. We investigated how root damage by a soil-dwelling insect (Xylotrupes gideon australicus modified the responses of Eucalyptus globulus to eCO2. eCO2 increased plant height when E. globulus were 14 weeks old and continued to do so at an accelerated rate compared to those grown at ambient CO2 (aCO2. Plants exposed to root-damaging insects showed a rapid decline in growth rates thereafter. In eCO2, shoot and root biomass increased by 46 and 35%, respectively, in insect-free plants but these effects were arrested when soil-dwelling insects were present so that plants were the same size as those grown at aCO2. Specific leaf mass increased by 29% under eCO2, but at eCO2 root damage caused it to decline by 16%, similar to values seen in plants at aCO2 without root damage. Leaf C:N ratio increased by >30% at eCO2 as a consequence of declining leaf N concentrations, but this change was also moderated by soil insects. Soil insects also reduced leaf water content by 9% at eCO2, which potentially arose through impaired water uptake by the roots. We hypothesise that this may have impaired photosynthetic activity to the extent that observed plant responses to eCO2 no longer occurred. In conclusion, soil-dwelling insects could modify plant responses to eCO2 predicted by climate change plant growth models.

  16. Changes in plants and soil microorganisms in an artificial CO2 leakage experiment

    Science.gov (United States)

    Ko, D.; Kim, Y.; Yoo, G.; Chung, H.

    2017-12-01

    Carbon capture and storage (CCS) technology is considered to be a promising technology that can mitigate global climate change by greatly reducing anthropogenic CO2 emissions. Despite the advantage, potential risks of leakage of CO2 from CO2 storage site exists, which may negatively affect organisms in the soil ecosystems. To investigate the short- term impacts of geological CO2 leakage on soil ecosystem, we conducted an artificial CO2 leakage experiment in a greenhouse where plants and soils were exposed to high levels of CO2. Corn was grown in a 1:1 (v/v) mixture of potting and field soil, and 99.99% CO2 gas was injected at a flow rate of 0.1l min-1 for 30 days whereas no gas was injected to control pots. Changes in plant growth, soil characteristics, and bacterial community composition were determined. Mean soil CO2 and O2 concentrations were 31.6% and 15.6%, respectively, in CO2-injected pots, while they were at ambient levels in control pots. The shoot and root length, and chlorophyll contents decreased in CO2-injected pots by 19.4%, 9.7%, and 11.9%, respectively. In addition, the concentration of available N such as NH4+-N and NO3-N was 83.3 to 90.8% higher in CO2-injected pots than in control pots likely due to inhibited plant growth. The results of bacterial 16S rRNA gene pyrosequencing showed that the major phyla in the soils were Actinobacteria, Proteobacteria, Acidobacteria, Chloroflexi, and Saccharibacteria_TM7. Among these, the relative abundance of Proteobacteria was lower in CO2-injected than in control pots (28.8% vs. 34.1%) likely due to decreased C availability. On the other hand, the abundance of Saccharibacteria_TM7 was significantly higher in CO2-injected than in control pots (6.0% vs. 1.3%). The changes in soil mineral N and microorganisms in response to injected CO2 was likely due to inhibited plant growth under high soil CO2 conditions, and further studies are needed to determine if belowground CO2 leakage from CO2 storage sites can directly

  17. Ship and Shoot

    Science.gov (United States)

    Woods, Ron

    2012-01-01

    Ron Woods shared incredibly valuable insights gained during his 28 years at the Kennedy Space Center (KSC) packaging Flight Crew Equipment for shuttle and ISS missions. In particular, Woods shared anecdotes and photos from various processing events. The moral of these stories and the main focus of this discussion were the additional processing efforts and effects related to a "ship-and-shoot" philosophy toward flight hardware.

  18. School Shootings and Student Performance

    OpenAIRE

    Panu Poutvaara; Olli Ropponen

    2010-01-01

    In this paper, we study how high school students reacted to the shocking news of a school shooting. The shooting coincided with national high-school matriculation exams. As there were exams both before and after the shooting, we can use a difference-in-differences analysis to uncover how the school shooting affected the test scores compared to previous years. We find that the average performance of young men declined due to the school shooting, whereas we do not observe a similar pattern for ...

  19. Potential gains from CO2 trading in the EU

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard; Vesterdal, Morten

    2003-01-01

    A new Green Paper from the European Commission on emissions trading foresees the setting-up of a CO2 trading system within the EU for the energy sector. Because any such international environmental agreement is self-enforcing, the participants must have an economic net gain from joining the propo......A new Green Paper from the European Commission on emissions trading foresees the setting-up of a CO2 trading system within the EU for the energy sector. Because any such international environmental agreement is self-enforcing, the participants must have an economic net gain from joining...... the proposed system. Our contribution is therefore to follow the Green Paper proposal and investigate whether member countries and the largest industrial boilers in the electricity sector actually will get significant net gains from CO2 trade in the European Union rather than undertaking domestic actions...... solely. We show, based on PRIMES model, that a full CO2 emission trading system between Annex B countries suggest overall cost savings in the order of 40 % compared to a situation with no trading at all between Member States. A tradable CO2 permit scheme with comprehensive coverage of emissions within...

  20. Metal-Organic Framework-Stabilized CO2/Water Interfacial Route for Photocatalytic CO2 Conversion.

    Science.gov (United States)

    Luo, Tian; Zhang, Jianling; Li, Wei; He, Zhenhong; Sun, Xiaofu; Shi, Jinbiao; Shao, Dan; Zhang, Bingxing; Tan, Xiuniang; Han, Buxing

    2017-11-29

    Here, we propose a CO 2 /water interfacial route for photocatalytic CO 2 conversion by utilizing a metal-organic framework (MOF) as both an emulsifier and a catalyst. The CO 2 reduction occurring at the CO 2 /water interface produces formate with remarkably enhanced efficiency as compared with that in conventional solvent. The route is efficient, facile, adjustable, and environmentally benign, which is applicable for the CO 2 transformation photocatalyzed by different kinds of MOFs.

  1. Impacts of Elevated Atmospheric CO2 and O3 on Paper Birch (Betula papyrifera: Reproductive Fitness

    Directory of Open Access Journals (Sweden)

    Joseph N. T. Darbah

    2007-01-01

    Full Text Available Atmospheric CO2 and tropospheric O3 are rising in many regions of the world. Little is known about how these two commonly co-occurring gases will affect reproductive fitness of important forest tree species. Here, we report on the long-term effects of CO3 and O3 for paper birch seedlings exposed for nearly their entire life history at the Aspen FACE (Free Air Carbon Dioxide Enrichment site in Rhinelander, WI. Elevated CO2 increased both male and female flower production, while elevated O3 increased female flower production compared to trees in control rings. Interestingly, very little flowering has yet occurred in combined treatment. Elevated CO2 had significant positive effect on birch catkin size, weight, and germination success rate (elevated CO2 increased germination rate of birch by 110% compared to ambient CO2 concentrations, decreased seedling mortality by 73%, increased seed weight by 17%, increased root length by 59%, and root-to-shoot ratio was significantly decreased, all at 3 weeks after germination, while the opposite was true of elevated O3 (elevated O3 decreased the germination rate of birch by 62%, decreased seed weight by 25%, and increased root length by 15%. Under elevated CO2, plant dry mass increased by 9 and 78% at the end of 3 and 14 weeks, respectively. Also, the root and shoot lengths, as well as the biomass of the seedlings, were increased for seeds produced under elevated CO2, while the reverse was true for seedlings from seeds produced under the elevated O3. Similar trends in treatment differences were observed in seed characteristics, germination, and seedling development for seeds collected in both 2004 and 2005. Our results suggest that elevated CO2 and O3 can dramatically affect flowering, seed production, and seed quality of paper birch, affecting reproductive fitness of this species.

  2. Advanced technology development reducing CO2 emissions

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Dong Sup

    2010-09-15

    Responding to Korean government policies on green growth and global energy/ environmental challenges, SK energy has been developing new technologies to reduce CO2 emissions by 1) CO2 capture and utilization, 2) efficiency improvement, and 3) Li-ion batteries. The paper introduces three advanced technologies developed by SK energy; GreenPol, ACO, and Li-ion battery. Contributing to company vision, a more energy and less CO2, the three technologies are characterized as follows. GreenPol utilizes CO2 as a feedstock for making polymer. Advanced Catalytic Olefin (ACO) reduces CO2 emission by 20% and increase olefin production by 17%. Li-ion Batteries for automotive industries improves CO2 emission.

  3. Influence of trade on national CO2 emissions

    International Nuclear Information System (INIS)

    Munksgaard, Jesper; Pade, Lise-Lotte; Minx, Jan; Lenzen, Manfred

    2005-01-01

    International trade has an impact on national CO 2 emissions and consequently on the ability to fulfil national CO 2 reduction targets. Through goods and services traded in a globally interdependent world, the consumption in each country is linked to greenhouse gas emissions in other countries. It has been argued that in order to achieve equitable reduction targets, international trade has to be taken into account when assessing nations' responsibility for abating climate change. Especially for open economies such as Denmark, greenhouse gases embodied in internationally traded commodities can have a considerable influence on the national 'greenhouse gas responsibility'. By using input-output modelling, we analyse the influence from international trade on national CO 2 emissions. The aim is to show that trade is the key to define CO 2 responsibility on a macroeconomic level and that imports should be founded in a multi-region model approach. Finally, the paper concludes on the need to consider the impact from foreign trade when negotiating reduction targets and base line scenarios. (Author)

  4. CO2 Allowance and Electricity Price Interaction

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-07-01

    With the introduction of CO2 emission constraints on power generators in the European Union, climate policy is starting to have notable effects on energy markets. This paper sheds light on the links between CO2 prices, electricity prices, and electricity costs to industry. It is based on a series of interviews with industrial and electricity stakeholders, as well as a rich literature seeking to estimate the exact effect of CO2 prices on electricity prices.

  5. CO2 sequestration: Storage capacity guideline needed

    Science.gov (United States)

    Frailey, S.M.; Finley, R.J.; Hickman, T.S.

    2006-01-01

    Petroleum reserves are classified for the assessment of available supplies by governmental agencies, management of business processes for achieving exploration and production efficiency, and documentation of the value of reserves and resources in financial statements. Up to the present however, the storage capacity determinations made by some organizations in the initial CO2 resource assessment are incorrect technically. New publications should thus cover differences in mineral adsorption of CO2 and dissolution of CO2 in various brine waters.

  6. Economic effects on taxing CO2 emissions

    International Nuclear Information System (INIS)

    Haaparanta, P.; Jerkkola, J.; Pohjola, J.

    1996-01-01

    The CO 2 emissions can be reduced by using economic instruments, like carbon tax. This project included two specific questions related to CO 2 taxation. First one was the economic effects of increasing CO 2 tax and decreasing other taxes. Second was the economic adjustment costs of reducing net emissions instead of gross emissions. A computable general equilibrium (CGE) model was used in this analysis. The study was taken place in Helsinki School of Economics

  7. Experimental Ion Mobility measurements in Ne-CO$_2$ and CO$_2$-N$_2$ mixtures

    CERN Document Server

    Encarnação, P.M.C.C.; Veenhof, R.; Neves, P.N.B.; Santos, F.P.; Trindade, A.M.F.; Borges, F.I.G.M.; Conde, C.A.N.

    2016-01-01

    In this paper we present the experimental results for the mobility, K0, of ions in neon-carbon dioxide (Ne-CO2) and carbon dioxide-nitrogen (CO2-N2) gaseous mixtures for total pressures ranging from 8–12 Torr, reduced electric fields in the 10–25 Td range, at room temperature. Regarding the Ne-CO2 mixture only one peak was observed for CO2 concentrations above 25%, which has been identified as an ion originated in CO2, while below 25% of CO2 a second-small peak appears at the left side of the main peak, which has been attributed to impurities. The mobility values for the main peak range between 3.51 ± 0.05 and 1.07 ± 0.01 cm2V−1s−1 in the 10%-99% interval of CO2, and from 4.61 ± 0.19 to 3.00 ± 0.09 cm2V−1s−1 for the second peak observed (10%–25% of CO2). For the CO2-N2, the time-of-arrival spectra displayed only one peak for CO2 concentrations above 10%, which was attributed to ions originated in CO2, namely CO2+(CO2), with a second peak appearing for CO2 concentrations below 10%. This secon...

  8. Review of Project Permits under the London Protocol - An Assessment of the Proposed P18-4 CO2 Storage Site: 13th International Conference on Greenhouse Gas Control Technologies, GHGT 2016. 14 November 2016 through 18 November

    OpenAIRE

    Mikunda, T.; Dixon, T.

    2017-01-01

    The London Protocol (1996) is a global agreement to promote the protection of the marine environment by prohibiting the dumping of wastes and other matter into the sea. Under the Protocol all dumping is prohibited, with the exception of a limited number of selected wastes on the so-called "reverse list", which can be considered for dumping. In 2007, an amendment entered into force which permitted CO2 streams to be considered for dumping under the London Protocol. The amendment was shortly fol...

  9. Supercritical CO2 uptake by nonswelling phyllosilicates.

    Science.gov (United States)

    Wan, Jiamin; Tokunaga, Tetsu K; Ashby, Paul D; Kim, Yongman; Voltolini, Marco; Gilbert, Benjamin; DePaolo, Donald J

    2018-01-30

    Interactions between supercritical (sc) CO 2 and minerals are important when CO 2 is injected into geologic formations for storage and as working fluids for enhanced oil recovery, hydraulic fracturing, and geothermal energy extraction. It has previously been shown that at the elevated pressures and temperatures of the deep subsurface, scCO 2 alters smectites (typical swelling phyllosilicates). However, less is known about the effects of scCO 2 on nonswelling phyllosilicates (illite and muscovite), despite the fact that the latter are the dominant clay minerals in deep subsurface shales and mudstones. Our studies conducted by using single crystals, combining reaction (incubation with scCO 2 ), visualization [atomic force microscopy (AFM)], and quantifications (AFM, X-ray photoelectron spectroscopy, X-ray diffraction, and off-gassing measurements) revealed unexpectedly high CO 2 uptake that far exceeded its macroscopic surface area. Results from different methods collectively suggest that CO 2 partially entered the muscovite interlayers, although the pathways remain to be determined. We hypothesize that preferential dissolution at weaker surface defects and frayed edges allows CO 2 to enter the interlayers under elevated pressure and temperature, rather than by diffusing solely from edges deeply into interlayers. This unexpected uptake of CO 2 , can increase CO 2 storage capacity by up to ∼30% relative to the capacity associated with residual trapping in a 0.2-porosity sandstone reservoir containing up to 18 mass % of illite/muscovite. This excess CO 2 uptake constitutes a previously unrecognized potential trapping mechanism. Copyright © 2018 the Author(s). Published by PNAS.

  10. Effect of the long-term elevation of CO2 concentration in the field on the quantum yield of photosynthesis of the C3 sedge, Scirpus olneyi

    International Nuclear Information System (INIS)

    Long, S.P.; Drake, B.G.

    1991-01-01

    CO 2 concentration was elevated throughout 3 years around stands of the C 3 sedge Scirpus olneyi on a tidal marsh of the Chesapeake Bay. The hypothesis that tissues developed in an elevated CO 2 atmosphere will show an acclimatory decrease in photosynthetic capacity under light-limiting conditions was examined. The absorbed light quantum yield of CO 2 uptake (φ abs ) and the efficiency of photosystem II photochemistry were determined for plants which had developed in open top chambers with CO 2 concentrations in air of 680 micromoles per mole, and of 351 micromoles per mole as controls. When measured in an atmosphere with 10 millimoles per mole O 2 to suppress photorespiration, shoots showed a φ abs of 0.093 ± 0.003, with no statistically significant difference between shoots grown in elevated or control CO 2 concentration. Efficiency of photosystem II photochemistry was also unchanged by development in an elevated CO 2 atmosphere. Shoots grown and measured in 680 micromoles per mole of CO 2 in air showed a φ abs of 0.078 ± 0.004 compared with 0.065 ± for leaves grown and measured in 351 micromoles per mole CO 2 in air; a highly significant increase. In accordance with the change in φ abs , the light compensation point of photosynthesis decreased from 51 ± 3 to 31 ± 3 micromoles per square meter per second for stems grown and measured in 351 and 680 micromoles per mole of CO 2 in air, respectively

  11. Trends in global CO2 emissions. 2013 Report

    Energy Technology Data Exchange (ETDEWEB)

    Olivier, J.G.J.; Peters, J.A.H.W. [PBL Netherlands Environmental Assessment Agency, Den Haag (Netherlands); Janssens-Maenhout, G. [Institute for Environment and Sustainability IES, European Commission' s Joint Research Centre JRC, Ispra (Italy); Muntean, M. [Institute for Environment and Sustainability IES, Joint Research Centre JRC, Ispra (Italy)

    2013-10-15

    This report discusses the results of a trend assessment of global CO2 emissions up to 2012 and updates last year's assessment. This assessment focuses on the changes in annual CO2 emissions from 2011 to 2012, and includes not only fossil-fuel combustion on which the BP reports are based, but also incorporates other relevant CO2 emissions sources including flaring of waste gas during gas and oil production, cement clinker production and other limestone uses, feedstock and other non-energy uses of fuels, and several other small sources. The report clarifies the CO2 emission sources covered, and describes the methodology and data sources. More details are provided in Annex 1 over the 2010-2012 period, including a discussion of the degree of uncertainty in national and global CO2 emission estimates. Chapter 2 presents a summary of recent CO2 emission trends, per main country or region, including a comparison between emissions per capita and per unit of Gross Domestic Product (GDP), and of the underlying trend in fossil-fuel production and use, non-fossil energy and other CO2 sources. Specific attention is given to developments in shale gas and oil production and oil sands production and their impact on CO2 emissions. To provide a broader context of global emissions trends, international greenhouse gas mitigation targets and agreements are also presented, including different perspectives of emission accounting per country. In particular, annual trends with respect to the Kyoto Protocol target and Cancun agreements and cumulative global CO2 emissions of the last decade are compared with scientific literature that analyses global emissions in relation to the target of 2{sup 0}C maximum global warming in the 21st century, which was adopted in the UN climate negotiations. In addition, we briefly discuss the rapid development and implementation of various emission trading schemes, because of their increasing importance as a cross-cutting policy instrument for mitigating

  12. Effect of CO2 Enrichment on the Growth and Nutrient Uptake of Tomato Seedlings

    Institute of Scientific and Technical Information of China (English)

    LI Juan; ZHOU Jian-Min; DUAN Zeng-Qiang; DU Chang-Wen; WANG Huo-Yan

    2007-01-01

    Exposing tomato seedlings to elevated CO2 concentrations may have potentially profound impacts on the tomato yield and quality. A growth chamber experiment was designed to estimate how different nutrient concentrations influenced the effect of elevated CO2 on the growth and nutrient uptake of tomato seedlings. Tomato (Hezuo 906) was grown in pots placed in controlled growth chambers and was subjected to ambient or elevated CO2 (360 or 720 μL L-1), and four nutrient solutions of different strengths (1/2-, 1/4-, 1/8-, and 1/16-strength Japan Yamazaki nutrient solutions) in a completely randomized design. The results indicated that some agricultural characteristics of the tomato seedlings such as the plant height, stem thickness, total dry and fresh weights of the leaves, stems and roots, the G value (G value = total plant dry weight/seedling age),and the seedling vigor index (seedling vigor index = stem thickness/(plant height × total plant dry weight) increased with the elevated CO2, and the increases were strongly dependent on the nutrient solution concentrations, being greater with higher nutrient solution concentrations. The elevated CO2 did not alter the ratio of root to shoot. The total N, P, K, and C absorbed from all the solutions except P in the 1/8- and 1/16-strength nutrient solutions increased in the elevated CO2 treatment. These results demonstrate that the nutrient demands of the tomato seedlings increased at elevated CO2 concentrations.

  13. Corn residue removal and CO2 emissions

    Science.gov (United States)

    Carbon dioxide (CO2), nitrous oxide (N2O), and methane (CH4) are the primary greenhouse gases (GHG) emitted from the soil due to agricultural activities. In the short-term, increases in CO2 emissions indicate increased soil microbial activity. Soil micro-organisms decompose crop residues and release...

  14. Increasing CO2 storage in oil recovery

    International Nuclear Information System (INIS)

    Jessen, K.; Kovscek, A.R.; Orr, F.M. Jr.

    2005-01-01

    Oil fields offer a significant potential for storing CO 2 and will most likely be the first large scale geological targets for sequestration as the infrastructure, experience and permitting procedures already exist. The problem of co-optimizing oil production and CO 2 storage differs significantly from current gas injection practice due to the cost-benefit imbalance resulting from buying CO 2 for enhanced oil recovery projects. Consequently, operators aim to minimize the amount of CO 2 required to sweep an oil reservoir. For sequestration purposes, where high availability of low cost CO 2 is assumed, the design parameters of enhanced oil recovery processes must be re-defined to optimize the amount of CO 2 left in the reservoir at the time of abandonment. To redefine properly the design parameters, thorough insight into the mechanisms controlling the pore scale displacement efficiency and the overall sweep efficiency is essential. We demonstrate by calculation examples the different mechanisms controlling the displacement behavior of CO 2 sequestration schemes, the interaction between flow and phase equilibrium and how proper design of the injection gas composition and well completion are required to co-optimize oil production and CO 2 storage. [Author

  15. NIST Photoionization of CO2 (ARPES) Database

    Science.gov (United States)

    SRD 119 NIST Photoionization of CO2 (ARPES) Database (Web, free access)   CO2 is studied using dispersed synchrotron radiation in the 650 Å to 850 Å spectral region. The vibrationally resolved photoelectron spectra are analyzed to generate relative vibrational transition amplitudes and the angular asymmetry parameters describing the various transitions observed.

  16. CO2 Capture with Enzyme Synthetic Analogue

    Energy Technology Data Exchange (ETDEWEB)

    Cordatos, Harry

    2010-11-08

    Overview of an ongoing, 2 year research project partially funded by APRA-E to create a novel, synthetic analogue of carbonic anhydrase and incorporate it into a membrane for removal of CO2 from flue gas in coal power plants. Mechanism background, preliminary feasibility study results, molecular modeling of analogue-CO2 interaction, and program timeline are provided.

  17. Eindhoven Airport : towards zero CO2 emissions

    NARCIS (Netherlands)

    Jorge Simoes Pedro, Joana

    2015-01-01

    Eindhoven airport is growing and it is strongly committed to take this opportunity to invest in innovative solutions for a sustainable development. Therefore, this document proposes a strategic plan for reaching Zero CO2 emissions at Eindhoven airport. This document proposes to reduce the CO2

  18. Thermodynamic modeling of CO2 mixtures

    DEFF Research Database (Denmark)

    Bjørner, Martin Gamel

    Knowledge of the thermodynamic properties and phase equilibria of mixtures containing carbon dioxide (CO2) is important in several industrial processes such as enhanced oil recovery, carbon capture and storage, and supercritical extractions, where CO2 is used as a solvent. Despite this importance...

  19. Increasing CO2 storage in oil recovery

    International Nuclear Information System (INIS)

    Jessen, Kristian; Kovscek, Anthony R.; Orr, Franklin M.

    2005-01-01

    Oil fields offer a significant potential for storing CO 2 and will most likely be the first large scale geological targets for sequestration as the infrastructure, experience and permitting procedures already exist. The problem of co-optimizing oil production and CO 2 storage differs significantly from current gas injection practice due to the cost-benefit imbalance resulting from buying CO 2 for enhanced oil recovery projects. Consequently, operators aim to minimize the amount of CO 2 required to sweep an oil reservoir. For sequestration purposes, where high availability of low cost CO 2 is assumed, the design parameters of enhanced oil recovery processes must be re-defined to optimize the amount of CO 2 left in the reservoir at the time of abandonment. To redefine properly the design parameters, thorough insight into the mechanisms controlling the pore scale displacement efficiency and the overall sweep efficiency is essential. We demonstrate by calculation examples the different mechanisms controlling the displacement behavior of CO 2 sequestration schemes, the interaction between flow and phase equilibrium and how proper design of the injection gas composition and well completion are required to co-optimize oil production and CO 2 storage

  20. CO2 emission calculations and trends

    International Nuclear Information System (INIS)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-01-01

    Evidence that the atmospheric CO 2 concentration has risen during the past several decades is irrefutable. Most of the observed increase in atmospheric CO 2 is believed to result from CO 2 releases from fossil-fuel burning. The United Nations (UN) Framework Convention on Climate Change (FCCC), signed in Rio de Janeiro in June 1992, reflects global concern over the increasing CO 2 concentration and its potential impact on climate. One of the convention's stated objectives was the ''stabilization of greenhouse gas concentrations in the atmosphere at a level that would prevent dangerous anthropogenic interference with the climate system. '' Specifically, the FCCC asked all 154 signing countries to conduct an inventory of their current greenhouse gas emissions, and it set nonbinding targets for some countries to control emissions by stabilizing them at 1990 levels by the year 2000. Given the importance of CO 2 as a greenhouse gas, the relationship between CO 2 emissions and increases in atmospheric CO 2 levels, and the potential impacts of a greenhouse gas-induced climate change; it is important that comprehensive CO 2 emissions records be compiled, maintained, updated, and documented

  1. Recent development of capture of CO2

    CERN Document Server

    Chavez, Rosa Hilda

    2014-01-01

    "Recent Technologies in the capture of CO2" provides a comprehensive summary on the latest technologies available to minimize the emission of CO2 from large point sources like fossil-fuel power plants or industrial facilities. This ebook also covers various techniques that could be developed to reduce the amount of CO2 released into the atmosphere. The contents of this book include chapters on oxy-fuel combustion in fluidized beds, gas separation membrane used in post-combustion capture, minimizing energy consumption in CO2 capture processes through process integration, characterization and application of structured packing for CO2 capture, calcium looping technology for CO2 capture and many more. Recent Technologies in capture of CO2 is a valuable resource for graduate students, process engineers and administrative staff looking for real-case analysis of pilot plants. This eBook brings together the research results and professional experiences of the most renowned work groups in the CO2 capture field...

  2. Flow assurance studies for CO2 transport

    NARCIS (Netherlands)

    Veltin, J.; Belfroid, S.P.C.

    2013-01-01

    In order to compensate for the relative lack of experience of the CCTS community, Flow Assurance studies of new CO2 pipelines and networks are a very important step toward reliable operation. This report details a typical approach for Flow Assurance study of CO2 transport pipeline. Considerations to

  3. Influence of Common Bean (Phaseolus vulgaris) Grown in Elevated CO2 on Apatite Dissolution

    Science.gov (United States)

    Olsen, A. A.; Morra, B.

    2016-12-01

    We ran a series of experiments to test the hypothesis that release of plant nutrients contained in apatite will be accelerated by the growth of Langstrath Stringless green bean in the presence of atmospheric CO2 meant to simulate possible future atmospheric conditions due a higher demand of nutrients and growth rate caused by elevated CO2. We hypothesize that elevated atmospheric CO2 will lead to both increased root growth and organic acid exudation. These two traits will lead to improved acquisition of P derived from apatite. Experiments were designed to investigate the effect of these changes on soil mineral weathering using plants grown under two conditions, ambient CO2 (400ppm) and elevated CO2 (1000ppm). Plants were grown in flow-through microcosms consisting of a mixture of quartz and apatite sands. Mini-greenhouses were utilized to control CO2 levels. Plant growth was sustained by a nutrient solution lacking in Ca and P. Calcium and P content of the leachate and plant tissue served as a proxy for apatite dissolution. Plants were harvested biweekly during the eight-week experiment and analyzed for Ca and P to calculate apatite dissolution kinetics. Preliminary results suggest that approximately four times more P and Ca are present in the leachate from experiments containing plants under both ambient and elevated CO2 levels than in abiotic experiments; however, the amounts of both P and Ca released in experiments conducted under both ambient and elevated CO2 levels are similar. Additionally, the amount of P in plant tissue grown under ambient and elevated CO2 conditions is similar. Plants grown in elevated CO2 had a greater root to shoot ratio. The planted microcosms were found to have a lower pH than abiotic controls most likely due to root respiration and exudation of organic acids.

  4. Silvering substrates after CO2 snow cleaning

    Science.gov (United States)

    Zito, Richard R.

    2005-09-01

    There have been some questions in the astronomical community concerning the quality of silver coatings deposited on substrates that have been cleaned with carbon dioxide snow. These questions center around the possible existence of carbonate ions left behind on the substrate by CO2. Such carbonate ions could react with deposited silver to produce insoluble silver carbonate, thereby reducing film adhesion and reflectivity. Carbonate ions could be produced from CO2 via the following mechanism. First, during CO2 snow cleaning, a small amount of moisture can condense on a surface. This is especially true if the jet of CO2 is allowed to dwell on one spot. CO2 gas can dissolve in this moisture, producing carbonic acid, which can undergo two acid dissociations to form carbonate ions. In reality, it is highly unlikely that charged carbonate ions will remain stable on a substrate for very long. As condensed water evaporates, Le Chatelier's principle will shift the equilibrium of the chain of reactions that produced carbonate back to CO2 gas. Furthermore, the hydration of CO2 reaction of CO2 with H20) is an extremely slow process, and the total dehydrogenation of carbonic acid is not favored. Living tissues that must carry out the equilibration of carbonic acid and CO2 use the enzyme carbonic anhydrase to speed up the reaction by a factor of one million. But no such enzymatic action is present on a clean mirror substrate. In short, the worst case analysis presented below shows that the ratio of silver atoms to carbonate radicals must be at least 500 million to one. The results of chemical tests presented here support this view. Furthermore, film lift-off tests, also presented in this report, show that silver film adhesion to fused silica substrates is actually enhanced by CO2 snow cleaning.

  5. The ins and outs of CO2

    Science.gov (United States)

    Raven, John A.; Beardall, John

    2016-01-01

    It is difficult to distinguish influx and efflux of inorganic C in photosynthesizing tissues; this article examines what is known and where there are gaps in knowledge. Irreversible decarboxylases produce CO2, and CO2 is the substrate/product of enzymes that act as carboxylases and decarboxylases. Some irreversible carboxylases use CO2; others use HCO3 –. The relative role of permeation through the lipid bilayer versus movement through CO2-selective membrane proteins in the downhill, non-energized, movement of CO2 is not clear. Passive permeation explains most CO2 entry, including terrestrial and aquatic organisms with C3 physiology and biochemistry, terrestrial C4 plants and all crassulacean acid metabolism (CAM) plants, as well as being part of some mechanisms of HCO3 – use in CO2 concentrating mechanism (CCM) function, although further work is needed to test the mechanism in some cases. However, there is some evidence of active CO2 influx at the plasmalemma of algae. HCO3 – active influx at the plasmalemma underlies all cyanobacterial and some algal CCMs. HCO3 – can also enter some algal chloroplasts, probably as part of a CCM. The high intracellular CO2 and HCO3 – pools consequent upon CCMs result in leakage involving CO2, and occasionally HCO3 –. Leakage from cyanobacterial and microalgal CCMs involves up to half, but sometimes more, of the gross inorganic C entering in the CCM; leakage from terrestrial C4 plants is lower in most environments. Little is known of leakage from other organisms with CCMs, though given the leakage better-examined organisms, leakage occurs and increases the energetic cost of net carbon assimilation. PMID:26466660

  6. Effects of elevated root zone CO2 and air temperature on photosynthetic gas exchange, nitrate uptake, and total reduced nitrogen content in aeroponically grown lettuce plants.

    Science.gov (United States)

    He, Jie; Austin, Paul T; Lee, Sing Kong

    2010-09-01

    Effects of elevated root zone (RZ) CO(2) and air temperature on photosynthesis, productivity, nitrate (NO(3)(-)), and total reduced nitrogen (N) content in aeroponically grown lettuce plants were studied. Three weeks after transplanting, four different RZ [CO(2)] concentrations [ambient (360 ppm) and elevated concentrations of 2000, 10,000, and 50,000 ppm] were imposed on plants grown at two air temperature regimes of 28 degrees C/22 degrees C (day/night) and 36 degrees C/30 degrees C. Photosynthetic CO(2) assimilation (A) and stomatal conductance (g(s)) increased with increasing photosynthetically active radiation (PAR). When grown at 28 degrees C/22 degrees C, all plants accumulated more biomass than at 36 degrees C/30 degrees C. When measured under a PAR >or=600 micromol m(-2) s(-1), elevated RZ [CO(2)] resulted in significantly higher A, lower g(s), and higher midday leaf relative water content in all plants. Under elevated RZ [CO(2)], the increase of biomass was greater in roots than in shoots, causing a lower shoot/root ratio. The percentage increase in growth under elevated RZ [CO(2)] was greater at 36 degrees C/30 degrees C although the total biomass was higher at 28 degrees C/22 degrees C. NO(3)(-) and total reduced N concentrations of shoot and root were significantly higher in all plants under elevated RZ [CO(2)] than under ambient RZ [CO(2)] of 360 ppm at both temperature regimes. At each RZ [CO(2)], NO(3)(-) and total reduced N concentration of shoots were greater at 28 degrees C/22 degrees C than at 36 degrees C/30 degrees C. At all RZ [CO(2)], roots of plants at 36 degrees C/30 degrees C had significantly higher NO(3)(-) and total reduced N concentrations than at 28 degrees C/22 degrees C. Since increased RZ [CO(2)] caused partial stomatal closure, maximal A and maximal g(s) were negatively correlated, with a unique relationship for each air temperature. However, across all RZ [CO(2)] and temperature treatments, there was a close correlation between

  7. Large-scale CO2 storage — Is it feasible?

    Directory of Open Access Journals (Sweden)

    Johansen H.

    2013-06-01

    Full Text Available CCS is generally estimated to have to account for about 20% of the reduction of CO2 emissions to the atmosphere. This paper focuses on the technical aspects of CO2 storage, even if the CCS challenge is equally dependent upon finding viable international solutions to a wide range of economic, political and cultural issues. It has already been demonstrated that it is technically possible to store adequate amounts of CO2 in the subsurface (Sleipner, InSalah, Snøhvit. The large-scale storage challenge (several Gigatons of CO2 per year is more an issue of minimizing cost without compromising safety, and of making international regulations.The storage challenge may be split into 4 main parts: 1 finding reservoirs with adequate storage capacity, 2 make sure that the sealing capacity above the reservoir is sufficient, 3 build the infrastructure for transport, drilling and injection, and 4 set up and perform the necessary monitoring activities. More than 150 years of worldwide experience from the production of oil and gas is an important source of competence for CO2 storage. The storage challenge is however different in three important aspects: 1 the storage activity results in pressure increase in the subsurface, 2 there is no production of fluids that give important feedback on reservoir performance, and 3 the monitoring requirement will have to extend for a much longer time into the future than what is needed during oil and gas production. An important property of CO2 is that its behaviour in the subsurface is significantly different from that of oil and gas. CO2 in contact with water is reactive and corrosive, and may impose great damage on both man-made and natural materials, if proper precautions are not executed. On the other hand, the long-term effect of most of these reactions is that a large amount of CO2 will become immobilized and permanently stored as solid carbonate minerals. The reduced opportunity for direct monitoring of fluid samples

  8. Large-scale CO2 storage — Is it feasible?

    Science.gov (United States)

    Johansen, H.

    2013-06-01

    CCS is generally estimated to have to account for about 20% of the reduction of CO2 emissions to the atmosphere. This paper focuses on the technical aspects of CO2 storage, even if the CCS challenge is equally dependent upon finding viable international solutions to a wide range of economic, political and cultural issues. It has already been demonstrated that it is technically possible to store adequate amounts of CO2 in the subsurface (Sleipner, InSalah, Snøhvit). The large-scale storage challenge (several Gigatons of CO2 per year) is more an issue of minimizing cost without compromising safety, and of making international regulations.The storage challenge may be split into 4 main parts: 1) finding reservoirs with adequate storage capacity, 2) make sure that the sealing capacity above the reservoir is sufficient, 3) build the infrastructure for transport, drilling and injection, and 4) set up and perform the necessary monitoring activities. More than 150 years of worldwide experience from the production of oil and gas is an important source of competence for CO2 storage. The storage challenge is however different in three important aspects: 1) the storage activity results in pressure increase in the subsurface, 2) there is no production of fluids that give important feedback on reservoir performance, and 3) the monitoring requirement will have to extend for a much longer time into the future than what is needed during oil and gas production. An important property of CO2 is that its behaviour in the subsurface is significantly different from that of oil and gas. CO2 in contact with water is reactive and corrosive, and may impose great damage on both man-made and natural materials, if proper precautions are not executed. On the other hand, the long-term effect of most of these reactions is that a large amount of CO2 will become immobilized and permanently stored as solid carbonate minerals. The reduced opportunity for direct monitoring of fluid samples close to the

  9. Photosynthetic CO2 affinity of the aquatic carnivorous plant Utricularia australis (Lentibulariaceae) and its investment in carnivory

    Czech Academy of Sciences Publication Activity Database

    Adamec, Lubomír

    2009-01-01

    Roč. 24, č. 2 (2009), s. 327-333 ISSN 0912-3814 Institutional research plan: CEZ:AV0Z60050516 Keywords : CO2 compensation point * investment in carnivory * apical shoot growth Subject RIV: EF - Botanics Impact factor: 1.485, year: 2009

  10. Recycling CO 2 ? Computational Considerations of the Activation of CO 2 with Homogeneous Transition Metal Catalysts

    KAUST Repository

    Drees, Markus; Cokoja, Mirza; Kü hn, Fritz E.

    2012-01-01

    . A similar approach, storing energy from renewable sources in chemical bonds with CO 2 as starting material, may lead to partial recycling of CO 2 created by human industrial activities. Unfortunately, currently available routes for the transformation

  11. Carbonation and CO2 uptake of concrete

    International Nuclear Information System (INIS)

    Yang, Keun-Hyeok; Seo, Eun-A; Tae, Sung-Ho

    2014-01-01

    This study developed a reliable procedure to assess the carbon dioxide (CO 2 ) uptake of concrete by carbonation during the service life of a structure and by the recycling of concrete after demolition. To generalize the amount of absorbable CO 2 per unit volume of concrete, the molar concentration of carbonatable constituents in hardened cement paste was simplified as a function of the unit content of cement, and the degree of hydration of the cement paste was formulated as a function of the water-to-cement ratio. The contribution of the relative humidity, type of finishing material for the concrete surface, and the substitution level of supplementary cementitious materials to the CO 2 diffusion coefficient in concrete was reflected using various correction factors. The following parameters varying with the recycling scenario were also considered: the carbonatable surface area of concrete crusher-runs and underground phenomena of the decreased CO 2 diffusion coefficient and increased CO 2 concentration. Based on the developed procedure, a case study was conducted for an apartment building with a principal wall system and an office building with a Rahmen system, with the aim of examining the CO 2 uptake of each structural element under different exposure environments during the service life and recycling of the building. As input data necessary for the case study, data collected from actual surveys conducted in 2012 in South Korea were used, which included data on the surrounding environments, lifecycle inventory database, life expectancy of structures, and recycling activity scenario. Ultimately, the CO 2 uptake of concrete during a 100-year lifecycle (life expectancy of 40 years and recycling span of 60 years) was estimated to be 15.5%–17% of the CO 2 emissions from concrete production, which roughly corresponds to 18%–21% of the CO 2 emissions from the production of ordinary Portland cement. - Highlights: • CO 2 uptake assessment approach owing to the

  12. Potential and economics of CO2 sequestration

    International Nuclear Information System (INIS)

    Jean-Baptiste, Ph.; Ciais, Ph.; Orr, J.

    2001-01-01

    Increasing atmospheric level of greenhouse gases are causing global warming and putting at risk the global climate system. The main anthropogenic greenhouse gas is CO 2 . Some techniques could be used to reduced CO 2 emission and stabilize atmospheric CO 2 concentration, including i) energy savings and energy efficiency, ii) switch to lower carbon content fuels (natural gas) and use energy sources with zero CO 2 emissions such as renewable or nuclear energy, iii) capture and store CO 2 from fossil fuels combustion, and enhance the natural sinks for CO 2 (forests, soils, ocean...). The purpose of this report is to provide an overview of the technology and cost for capture and storage of CO 2 and to review the various options for CO 2 sequestration by enhancing natural carbon sinks. Some of the factors which will influence application, including environmental impact, cost and efficiency, are discussed. Capturing CO 2 and storing it in underground geological reservoirs appears as the best environmentally acceptable option. It can be done with existing technology, however, substantial R and D is needed to improve available technology and to lower the cost. Applicable to large CO 2 emitting industrial facilities such as power plants, cement factories, steel industry, etc., which amount to about 30% of the global anthropic CO 2 emission, it represents a valuable tool in the baffle against global warming. About 50% of the anthropic CO 2 is being naturally absorbed by the biosphere and the ocean. The 'natural assistance' provided by these two large carbon reservoirs to the mitigation of climate change is substantial. The existing natural sinks could be enhanced by deliberate action. Given the known and likely environmental consequences, which could be very damaging indeed, enhancing ocean sinks does not appears as a satisfactory option. In contrast, the promotion of land sinks through demonstrated carbon-storing approach to agriculture, forests and land management could

  13. CO2 emissions abatement and geologic sequestration - industrial innovations and stakes - status of researches in progress

    International Nuclear Information System (INIS)

    2005-01-01

    This colloquium was jointly organized by the French institute of petroleum (IFP), the French agency of environmental and energy mastery (Ademe) and the geological and mining research office (BRGM). This press kit makes a status of the advances made in CO 2 emissions abatement and geological sequestration: technological advances of CO 2 capture and sequestration, geological reservoir dimensioning with respect to the problem scale, duration of such an interim solution, CO 2 emissions abatement potentialities of geological sequestration, regulatory, economical and financial implications, international stakes of greenhouse gas emissions. This press kit comprises a press release about the IFP-Ademe-BRGM colloquium, a slide presentation about CO 2 abatement and sequestration, and four papers: a joint IFP-Ademe-BRGM press conference, IFP's answers to CO 2 emissions abatement, Ademe's actions in CO 2 abatement and sequestration, and BRGM's experience in CO 2 sequestration and climatic change expertise. (J.S.)

  14. Evaluation Analysis of the CO2 Emission and Absorption Life Cycle for Precast Concrete in Korea

    Directory of Open Access Journals (Sweden)

    Taehyoung Kim

    2016-07-01

    Full Text Available To comply with recent international trends and initiatives, and in order to help achieve sustainable development, Korea has established a greenhouse gas (GHG emission reduction target of 37% (851 million tons of the business as usual (BAU rate by 2030. Regarding environmentally-oriented standards such as the IGCC (International Green Construction Code, there are also rising demands for the assessment on CO2 emissions during the life cycle in accordance with ISO (International Standardization Organization’s Standard 14040. At present, precast concrete (PC engineering-related studies primarily cover structural and construction aspects, including improvement of structural performance in the joint, introduction of pre-stressed concrete and development of half PC. In the manufacture of PC, steam curing is mostly used for the early-strength development of concrete. In steam curing, a large amount of CO2 is produced, causing an environmental problem. Therefore, this study proposes a method to assess CO2 emissions (including absorption throughout the PC life cycle by using a life cycle assessment (LCA method. Using the proposed assessment method, CO2 emissions during the life cycle of a precast concrete girder (PCG were assessed. In addition, CO2 absorption was assessed against a PCG using conventional carbonation and CO2 absorption-related models. As a result, the CO2 emissions throughout the life cycle of the PCG were 1365.6 (kg-CO2/1 PCG. The CO2 emissions during the production of raw materials among the CO2 emissions throughout the life cycle of the PCG were 1390 (kg-CO2/1 PCG, accounting for a high portion to total CO2 emissions (nearly 90%. In contrast, the transportation and manufacture stages were 1% and 10%, respectively, having little effect on total CO2 emissions. Among the use of the PCG, CO2 absorption was mostly decided by the CO2 diffusion coefficient and the amount of CO2 absorption by cement paste. The CO2 absorption by carbonation

  15. Electrocatalytic Alloys for CO2 Reduction.

    Science.gov (United States)

    He, Jingfu; Johnson, Noah J J; Huang, Aoxue; Berlinguette, Curtis P

    2018-01-10

    Electrochemically reducing CO 2 using renewable energy is a contemporary global challenge that will only be met with electrocatalysts capable of efficiently converting CO 2 into fuels and chemicals with high selectivity. Although many different metals and morphologies have been tested for CO 2 electrocatalysis over the last several decades, relatively limited attention has been committed to the study of alloys for this application. Alloying is a promising method to tailor the geometric and electric environments of active sites. The parameter space for discovering new alloys for CO 2 electrocatalysis is particularly large because of the myriad products that can be formed during CO 2 reduction. In this Minireview, mixed-metal electrocatalyst compositions that have been evaluated for CO 2 reduction are summarized. A distillation of the structure-property relationships gleaned from this survey are intended to help in the construction of guidelines for discovering new classes of alloys for the CO 2 reduction reaction. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. CO2 Accounting and Risk Analysis for CO2 Sequestration at Enhanced Oil Recovery Sites.

    Science.gov (United States)

    Dai, Zhenxue; Viswanathan, Hari; Middleton, Richard; Pan, Feng; Ampomah, William; Yang, Changbing; Jia, Wei; Xiao, Ting; Lee, Si-Yong; McPherson, Brian; Balch, Robert; Grigg, Reid; White, Mark

    2016-07-19

    Using CO2 in enhanced oil recovery (CO2-EOR) is a promising technology for emissions management because CO2-EOR can dramatically reduce sequestration costs in the absence of emissions policies that include incentives for carbon capture and storage. This study develops a multiscale statistical framework to perform CO2 accounting and risk analysis in an EOR environment at the Farnsworth Unit (FWU), Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil/gas-water flow and transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major risk metrics: CO2/water injection/production rates, cumulative net CO2 storage, cumulative oil/gas productions, and CO2 breakthrough time. The median and confidence intervals are estimated for quantifying uncertainty ranges of the risk metrics. A response-surface-based economic model has been derived to calculate the CO2-EOR profitability for the FWU site with a current oil price, which suggests that approximately 31% of the 1000 realizations can be profitable. If government carbon-tax credits are available, or the oil price goes up or CO2 capture and operating expenses reduce, more realizations would be profitable. The results from this study provide valuable insights for understanding CO2 storage potential and the corresponding environmental and economic risks of commercial-scale CO2-sequestration in depleted reservoirs.

  17. Effects of tillage practice and atmospheric CO2 level on soil CO2 efflux

    Science.gov (United States)

    Elevated atmospheric carbon dioxide (CO2) affects both the quantity and quality of plant tissues, which impacts the cycling and storage of carbon (C) within plant/soil systems and thus the rate of CO2 release back to the atmosphere. Research to accurately quantify the effects of elevated CO2 and as...

  18. Estimating CO2 Emission Reduction of Non-capture CO2 Utilization (NCCU) Technology

    International Nuclear Information System (INIS)

    Lee, Ji Hyun; Lee, Dong Woog; Gyu, Jang Se; Kwak, No-Sang; Lee, In Young; Jang, Kyung Ryoung; Shim, Jae-Goo; Choi, Jong Shin

    2015-01-01

    Estimating potential of CO 2 emission reduction of non-capture CO 2 utilization (NCCU) technology was evaluated. NCCU is sodium bicarbonate production technology through the carbonation reaction of CO 2 contained in the flue gas. For the estimating the CO 2 emission reduction, process simulation using process simulator (PRO/II) based on a chemical plant which could handle CO 2 of 100 tons per day was performed, Also for the estimation of the indirect CO 2 reduction, the solvay process which is a conventional technology for the production of sodium carbonate/sodium bicarbonate, was studied. The results of the analysis showed that in case of the solvay process, overall CO 2 emission was estimated as 48,862 ton per year based on the energy consumption for the production of NaHCO 3 (7.4 GJ/tNaHCO 3 ). While for the NCCU technology, the direct CO 2 reduction through the CO 2 carbonation was estimated as 36,500 ton per year and the indirect CO 2 reduction through the lower energy consumption was 46,885 ton per year which lead to 83,385 ton per year in total. From these results, it could be concluded that sodium bicarbonate production technology through the carbonation reaction of CO 2 contained in the flue was energy efficient and could be one of the promising technology for the low CO 2 emission technology.

  19. Physiological acclimation dampens initial effects of elevated temperature and atmospheric CO2 concentration in mature boreal Norway spruce.

    Science.gov (United States)

    Lamba, Shubhangi; Hall, Marianne; Räntfors, Mats; Chaudhary, Nitin; Linder, Sune; Way, Danielle; Uddling, Johan; Wallin, Göran

    2018-02-01

    Physiological processes of terrestrial plants regulate the land-atmosphere exchange of carbon, water, and energy, yet few studies have explored the acclimation responses of mature boreal conifer trees to climate change. Here we explored the acclimation responses of photosynthesis, respiration, and stomatal conductance to elevated temperature and/or CO 2 concentration ([CO 2 ]) in a 3-year field experiment with mature boreal Norway spruce. We found that elevated [CO 2 ] decreased photosynthetic carboxylation capacity (-23% at 25 °C) and increased shoot respiration (+64% at 15 °C), while warming had no significant effects. Shoot respiration, but not photosynthetic capacity, exhibited seasonal acclimation. Stomatal conductance at light saturation and a vapour pressure deficit of 1 kPa was unaffected by elevated [CO 2 ] but significantly decreased (-27%) by warming, and the ratio of intercellular to ambient [CO 2 ] was enhanced (+17%) by elevated [CO 2 ] and decreased (-12%) by warming. Many of these responses differ from those typically observed in temperate tree species. Our results show that long-term physiological acclimation dampens the initial stimulation of plant net carbon assimilation to elevated [CO 2 ], and of plant water use to warming. Models that do not account for these responses may thus overestimate the impacts of climate change on future boreal vegetation-atmosphere interactions. © 2017 John Wiley & Sons Ltd.

  20. CO2 content of electricity losses

    International Nuclear Information System (INIS)

    Daví-Arderius, Daniel; Sanin, María-Eugenia; Trujillo-Baute, Elisa

    2017-01-01

    Countries are implementing policies to develop greener energy markets worldwide. In Europe, the ¨2030 Energy and Climate Package¨ asks for further reductions of green house gases, renewable sources integration, and energy efficiency targets. But the polluting intensity of electricity may be different in average than when considering market inefficiencies, in particular losses, and therefore the implemented policy must take those differences into account. Precisely, herein we study the importance in terms of CO2 emissions the extra amount of energy necessary to cover losses. With this purpose we use Spanish market and system data with hourly frequency from 2011 to 2013. Our results show that indeed electricity losses significantly explain CO2 emissions, with a higher CO2 emissions rate when covering losses than the average rate of the system. Additionally, we find that the market closing technologies used to cover losses have a positive and significant impact on CO2 emissions: when polluting technologies (coal or combined cycle) close the market, the impact of losses on CO2 emissions is high compared to the rest of technologies (combined heat and power, renewables or hydropower). To the light of these results we make some policy recommendations to reduce the impact of losses on CO2 emissions. - Highlights: • Electricity losses significantly explain CO2 emissions. • Policies aimed to reducing losses have a positive impact on CO2 emissions. • The market closing technology used to cover losses have impacts on CO2 emissions. • Pollutant technologies that close the market should be replaced by renewables.

  1. Inequality aspects of alternative CO2 agreement designs

    International Nuclear Information System (INIS)

    Welsch, Heinz

    1992-01-01

    In recent years, the expected climate change, due to the atmospheric accumulation of CO 2 and other trace gases, has become an increasingly important issue in energy policy. Given the important contribution of CO 2 to the greenhouse effect, and the global character of the problem, an international agreement on curbing CO 2 emissions is under current consideration. The design of such an agreement inevitably raises significant questions of equity and efficiency. In the international political debate, most emphasis is generally put on the distributive aspect. Interestingly, the discussion usually focuses on equity in terms of the distribution of emissions. From an economic perspective, it appears more natural to address the equity issue from the point of view of income. It is obvious that a given degree of abatement can have dramatically different economic effects in different countries. Of course, this aspect is implicitly at the centre of all CO 2 related equity considerations. In what follows, this issue will be addressed explicitly, by examining the applicability and the implications of various economic approaches to distributive justice. (author)

  2. CO2 fluxes near a forest edge

    DEFF Research Database (Denmark)

    Sogachev, Andrey; Leclerc, Monique Y.; Zhang, Gensheng

    2008-01-01

    In contrast with recent advances on the dynamics of the flow at a forest edge, few studies have considered its role on scalar transport and, in particular, on CO2 transfer. The present study addresses the influence of the abrupt roughness change on forest atmosphere CO2 exchange and contrasts...... as a function of both sources/sinks distribution and the vertical structure of the canopy. Results suggest that the ground source plays a major role in the formation of wave-like vertical CO2 flux behavior downwind of a forest edge, despite the fact that the contribution of foliage sources/sinks changes...

  3. CO2, the promises of geological sequestration

    International Nuclear Information System (INIS)

    Rouat, S.

    2006-01-01

    Trapping part of the world CO 2 effluents in the deep underground is a profitable and ecological way to limit the global warming. This digest paper presents the different ways of CO 2 sequestration (depleted oil and gas fields, unexploited coal seams, saline aquifers), the other possible solutions for CO 2 abatement (injection in the bottom of the ocean, conversion into carbonates by injection into basic rocks, fixation by photosynthesis thanks to micro-algae cultivation), and takes stock of the experiments in progress (Snoehvit field in Norway, European project Castor). (J.S.)

  4. Climate change and the CO2 myth

    International Nuclear Information System (INIS)

    Boettcher, C.J.F.

    1994-01-01

    Further increase of the CO 2 concentration in the atmosphere has little effect on the greenhouse effect contrary to the effect of the increase of other greenhouse gases. However, politicians are using targets for the reduction of CO 2 emissions that are unrealistic, taking into account the scientific uncertainties of the applied models, the doubts about the feasibility of quantitative targets and the economic consequences of such drastic measures. Some recommendations are given for a more realistic CO 2 policy. Also attention is paid to the important role that coal will play in the future of the energy supply. 5 figs., 3 ills

  5. CO2 fixation in alfalfa and birdsfoot trefoil root nodules and partitioning of 14C to the plant

    International Nuclear Information System (INIS)

    Maxwell, C.A.; Vance, C.P.; Heichel, G.H.; Stade, S.

    1984-01-01

    The objectives of this study were to determine if nonphotosynthetic CO 2 fixation by root nodules contributes carbon for the assimilation of fixed N 2 in alfalfa (Medicago sativa L.) and birdsfoot trefoil (Lotus corniculatus L.) and if assimilation products are partitioned to different plant organs. Effective alfalfa nodules excised from or attached to roots had apparent 14 CO 2 fixation rates of 50 to 80 μg CO 2 kg -1 s -1 (dry weight) at 0.0012 to 0.0038 mole fraction CO 2 . Nodule CO 2 fixation rates increased six- to seven-fold as ambient CO 2 was raised from 0.0038 to 0.0663 mole fraction. Respiration rates of nodules (3 to 4 mg CO 2 kg -1 s -1 ) were 10 to 100-fold higher than 14 CO 2 fixation rates of nodules. Pulse chase experiments with 14 CO 2 combined with nodule and xylem sap analysis demonstrated the initial products of root and nodule CO 2 fixation were organic acids. However, the export of fixed 14 C from effective nodules was primarily in the form of amino acids. In contrast, nodule and/or root fixed 14 C in ineffectively nodulated alfalfa and denodulated effective alfalfa and birdsfoot trefoil was transported primarily as organic acids. Aspartate, asparagine, alanine, glutamate, and glutamine were the most heavily labeled compounds in the amino acid fraction of both effective alfalfa and birdsfoot trefoil nodules exposed to 14 CO 2 . By contrast, asparate, asparagine, and glutamine were the predominantly labeled amino acids in xylem sap collected from nodulated effective roots exposed to 14 CO 2 . The occurrence of nodule CO 2 fixation in alfalfa and birdsfoot trefoil and the export of fixed carbon as asparagine and aspartate to roots and shoots is consistent with a role for CO 2 fixation by nodules in providing carbon skeletons for assimilation and transport of symbiotically fixed N 2

  6. Carbon dioxide exchange in Norway spruce at the shoot, tree and ecosystem scale.

    Science.gov (United States)

    Wallin, G; Linder, S; Lindroth, A; Räntfors, M; Flemberg, S; Grelle, A

    2001-08-01

    Net CO2 exchange in a 35-year-old boreal Norway spruce (Picea abies (L.) Karst.) forest in northern Sweden was measured at the shoot (NSE), tree (NTE) and ecosystem levels (NEE) by means of shoot cuvettes, whole-tree chambers and the eddy covariance technique, respectively. We compared the dynamics of gross primary production (GPP) at the three levels during the course of a single week. The diurnal dynamics of GPP at each level were estimated by subtracting half-hourly or hourly model-estimated values of total respiration (excluding light-dependent respiration) from net CO(2) exchange. The relationship between temperature and total respiration at each level was derived from nighttime measurements of NSE, NTE and NEE over the course of 1 month. There was a strong linear relationship (r2 = 0.93) between the hourly estimates of GPP at the shoot and tree levels, but the correlation between shoot- and ecosystem-level GPP was weaker (r2 = 0.69). However, the correlation between shoot- and ecosystem-level GPP was improved (r2 = 0.88) if eddy covariance measurements were restricted to periods when friction velocity was > or = 0.5 m s(-1). Daily means were less dependent on friction velocity, giving an r2 value of 0.94 between shoot- and ecosystem-level GPP. The correlation between shoot and tree levels also increased when daily means were compared (r2 = 0.98). Most of the measured variation in carbon exchange rate among the shoot, tree and ecosystem levels was the result of periodic low coupling between vegetation and the atmosphere at the ecosystem level. The results validate the use of measurements at the shoot and tree level for analyzing the contribution of different compartments to net ecosystem CO2 exchange.

  7. Microbial association with the dynamics of particulate organic carbon in response to the amendment of elevated CO2-derived wheat residue into a Mollisol.

    Science.gov (United States)

    Wang, Yanhong; Yu, Zhenhua; Li, Yansheng; Wang, Guanghua; Liu, Junjie; Liu, Judong; Liu, Xiaobing; Jin, Jian

    2017-12-31

    As the chemical quality of crop residue is likely to be affected by elevated CO 2 (eCO 2 ), residue amendments may influence soil organic carbon (SOC) sequestration. However, in Mollisols, the dynamics of the SOC fractions in response to amendment with wheat residue produced under eCO 2 and the corresponding microbial community composition remain unknown. Such investigation is essential to residue management, which affects the soil quality and productivity of future farming systems. To narrow this knowledge gap, 13 C-labeled shoot and root residue derived from ambient CO 2 (aCO 2 ) or eCO 2 were amended into Mollisols and incubated for 200days. The soil was sampled during the incubation period to determine the residue-C retained in the three SOC fractions, i.e., coarse intra-aggregate particulate organic C (coarse iPOC), fine iPOC and mineral-associated organic C (MOC). The soil bacterial community was assessed using a MiSeq sequencing instrument. The results showed that the increase in SOC concentrations attributable to the application of the wheat residue primarily occurred in the coarse iPOC fraction. Compared with the aCO 2 -derived shoot residue, the amendment of eCO 2 -derived shoot residue resulted in greater SOC concentrations, whereas no significant differences (P>0.05) were observed between the aCO 2 - and eCO 2 -derived roots. Principal coordinates analysis (PCoA) showed that the residue amendment significantly (P≤0.05) altered the bacterial community composition compared with the non-residue amendment. Additionally, the bacterial community in the aCO 2 -derived shoot treatment differed from those in the other residue treatments until day 200 of the incubation period. The eCO 2 -derived shoot treatment significantly increased (P≤0.05) the relative abundances of the genera Acidobacteriaceae_(Subgroup_1)_uncultured, Bryobacter, Candidatus_Solibacter, Gemmatimonas and Nitrosomonadaceae_uncultured, whereas the opposite trend was observed in Nonomuraea

  8. Equilibration of metabolic CO2 with preformed CO2 and bicarbonate

    International Nuclear Information System (INIS)

    Hems, R.; Saez, G.T.

    1983-01-01

    Entry of metabolic 14 CO 2 into urea is shown to occur more readily than it equilibrates with the general pool of cellular plus extracellular bicarbonate plus CO 2 . Since the sites of CO 2 production (pyruvate dehydrogenase and oxoglutarate dehydrogenase) and of fixation (carbamoylphosphate synthetase) are intramitochondrial, it is likely that the fixation of CO 2 is also more rapid than its equilibration with the cytoplasmic pool of bicarbonate plus CO 2 . This observation may point to a more general problem concerning the interpretation of isotope data, with compartmentation or proximity of sites of production and utilisation of metabolites may result in the isotope following a preferred pathway. (Auth.)

  9. CO2 Capture by Cement Raw Meal

    DEFF Research Database (Denmark)

    Pathi, Sharat Kumar; Lin, Weigang; Illerup, Jytte Boll

    2013-01-01

    The cement industry is one of the major sources of CO2 emissions and is likely to contribute to further increases in the near future. The carbonate looping process has the potential to capture CO2 emissions from the cement industry, in which raw meal for cement production could be used...... as the sorbent. Cyclic experiments were carried out in a TGA apparatus using industrial cement raw meal and synthetic raw meal as sorbents, with limestone as the reference. The results show that the CO2 capture capacities of the cement raw meal and the synthetic raw meal are comparable to those of pure limestone...... that raw meal could be used as a sorbent for the easy integration of the carbonate looping process into the cement pyro process for reducing CO2 emissions from the cement production process....

  10. Energy Efficiency instead of CO2 levy

    International Nuclear Information System (INIS)

    Uetz, R.

    2005-01-01

    This article takes a look at ways of avoiding a future, planned Swiss CO 2 levy by improving the efficiency of energy use. The political situation concerning the reduction of CO 2 emissions in Switzerland is reviewed and the likeliness of the introduction of a CO 2 levy is discussed. Strategies for the reduction of fossil fuel consumption and therefore of CO 2 emissions are looked at, including process optimisation. Recommendations are made on how to approach this work systematically - data collection, assessment of the potential for reduction and the planning of measures to be taken are looked at. The high economic efficiency of immediate action is stressed and typical middle and long-term measures are listed

  11. The ATLAS IBL CO2 Cooling System

    CERN Document Server

    Verlaat, Bartholomeus; The ATLAS collaboration

    2016-01-01

    The Atlas Pixel detector has been equipped with an extra B-layer in the space obtained by a reduced beam pipe. This new pixel detector called the ATLAS Insertable B-Layer (IBL) is installed in 2014 and is operational in the current ATLAS data taking. The IBL detector is cooled with evaporative CO2 and is the first of its kind in ATLAS. The ATLAS IBL CO2 cooling system is designed for lower temperature operation (<-35⁰C) than the previous developed CO2 cooling systems in High Energy Physics experiments. The cold temperatures are required to protect the pixel sensors for the high expected radiation dose up to 550 fb^-1 integrated luminosity. This paper describes the design, development, construction and commissioning of the IBL CO2 cooling system. It describes the challenges overcome and the important lessons learned for the development of future systems which are now under design for the Phase-II upgrade detectors.

  12. Capture and geological storage of CO2

    International Nuclear Information System (INIS)

    2013-03-01

    Capture and geological storage of CO 2 could be a contribution to reduce CO 2 emissions, and also a way to meet the factor 4 objective of reduction of greenhouse gas emissions. This publication briefly presents the capture and storage definitions and principles, and comments some key data related to CO 2 emissions, and their natural trapping by oceans, soils and forests. It discusses strengths (a massive and perennial reduction of CO 2 emissions, a well defined regulatory framework) and weaknesses (high costs and uncertain cost reduction perspectives, a technology which still consumes a lot of energy, geological storage capacities still to be determined, health environmental impacts and risks to be controlled, a necessary consultation of population for planned projects) of this option. Actions undertaken by the ADEME are briefly reviewed

  13. CO2 Washout Capability with Breathing Manikin

    Data.gov (United States)

    National Aeronautics and Space Administration — Carbon Dioxide (CO2) Washout performance is a critical parameter needed to ensure proper and sufficient designs in a spacesuit and in vehicle applications such as...

  14. Emerging terawatt picosecond CO2 laser technology

    International Nuclear Information System (INIS)

    Pogorelsky, I.V.

    1997-09-01

    The first terawatt picosecond (TWps) CO 2 laser is under construction at the BNL Accelerator Test Facility (ATF). TWps-CO 2 lasers, having an order of magnitude longer wavelength than the well-known table-top terawatt solid state lasers, offer new opportunities for strong-field physics research. For laser wakefield accelerators (LWFA) the advantage of the new class of lasers is due to a gain of two orders of magnitude in the ponderomotive potential. The large average power of CO 2 lasers is important for the generation of hard radiation through Compton back-scattering of the laser off energetic electron beams. The authors discuss applications of TWps-CO 2 lasers for LWFA modules of a tentative electron-positron collider, for γ-γ (or γ-lepton) colliders, for a possible table-top source of high-intensity x-rays and gamma rays, and the generation of polarized positron beams

  15. Porous Organic Polymers for CO2 Capture

    KAUST Repository

    Teng, Baiyang

    2013-01-01

    to reduce the emission of CO2 to atmosphere. Porous organic polymers (POPs) are promising candidates for this application due to their readily tunable textual properties and surface functionalities. The objective of this thesis work is to develop new POPs

  16. Upscaling of enzyme enhanced CO2 capture

    DEFF Research Database (Denmark)

    Gladis, Arne Berthold

    Fossil fuels are the backbone of the energy generation in the coming decades for USA, China, India and Europe, hence high greenhouse gas emissions are expected in future. Carbon capture and storage technology (CCS) is the only technology that can mitigate greenhouse gas emissions from fossil fuel...... the mass transfer of CO2 with slow-capturing but energetically favorable solvents can open up a variety of new process options for this technology. The ubiquitous enzyme carbonic anhydrase (CA), which enhances the mass transfer of CO2 in the lungs by catalyzing the reversible hydration of CO2, is one very...... enhanced CO2 capture technology by identifying the potentials and limitations in lab and in pilot scale and benchmarking the process against proven technologies. The main goal was to derive a realistic process model for technical size absorbers with a wide range of validity incorporating a mechanistic...

  17. A School Shooting Plot Foiled

    Science.gov (United States)

    Swezey, James A.; Thorp, Kimberly A.

    2010-01-01

    Dinkes, Cataldi, and Lin-Kelly (2007) claims that 78% of public schools reported one or more violent incidents during the 2005/2006 school year. School shootings are a rare but real threat on school campuses. Shootings at private schools are even less frequent with only a few recorded examples in the United States. This case study examines how a…

  18. Photoacoustic CO2-Sensor for Automotive Applications

    OpenAIRE

    Huber, J.; Weber, C.; Eberhardt, A.; Wöllenstein, J.

    2016-01-01

    We present a field-tested miniaturized spectroscopic CO2 sensor which is based on the photoacoustic effect. The sensor is developed for automotive applications and considers the requirements for the usage in vehicles. The sensor measures two measurement ranges simultaneously: The monitoring of the indoor air quality and the detection of possible leakages of the coolant in CO2 air-conditioning systems. The sensor consists of a miniaturized innovative photoacoustic sensor unit with integrated e...

  19. Study on CO2 global recycling system

    International Nuclear Information System (INIS)

    Takeuchi, M.; Sakamoto, Y.; Niwa, S.

    2001-01-01

    In order to assist in finding ways to mitigate CO 2 emission and to slow the depletion of fossil fuels we have established and evaluated a representative system, which consists of three technologies developed in our laboratory. These technologies were in CO 2 recovery, hydrogen production and methanol synthesis and in addition we established the necessary supporting systems. Analysis of outline designs of the large scale renewable energy power generation system and this system and energy input for building plant, energy input for running plant has been conducted based on a case using this system for a 1000-MW coal fired power plant, followed by an evaluation of the material balance and energy balance. The results are as follows. Energy efficiency is 34%, the CO 2 reduction rate is 41%, the balance ratio of the energy and CO 2 of the system is 2.2 and 1.8, respectively, on the assumption that the primary renewable energy is solar thermal power generation, the stationary CO 2 emission source is a coal-fired power plant and the generation efficiency of the methanol power plant is 60%. By adopting the system, 3.7 million tons of CO 2 can be recovered, approximately 2.7 million tons of methanol can be produced, and 15.4 billion kWh of electricity can be generated per year. Compared to generating all electrical power using only coal, approximately 2.6 million tons of coal per year can be saved and approximately 2.15 million tons of CO 2 emission can be reduced. Therefore, it is clearly revealed that this system would be effective to reduce CO 2 emissions and to utilize renewable energy

  20. Effects of high CO2 on growth and metabolism of Arabidopsis seedlings during growth with a constantly limited supply of nitrogen.

    Science.gov (United States)

    Takatani, Nobuyuki; Ito, Takuro; Kiba, Takatoshi; Mori, Marie; Miyamoto, Tetsuro; Maeda, Shin-Ichi; Omata, Tatsuo

    2014-02-01

    Elevated CO2 has been reported to stimulate plant growth under nitrogen-sufficient conditions, but the effects of CO2 on growth in a constantly nitrogen-limited state, which is relevant to most natural habitats of plants, remain unclear. Here, we maintained Arabidopsis seedlings under such conditions by growing a mutant with reduced nitrate uptake activity on a medium containing nitrate as the sole nitrogen source. Under nitrogen-sufficient conditions (i.e. in the presence of ammonium), growth of shoots and roots of both the wild type (WT) and the mutant was increased approximately 2-fold by elevated CO2. Growth stimulation of shoots and roots by elevated CO2 was observed in the WT growing with nitrate as the sole nitrogen source, but in the mutant grown with nitrate, the high-CO2 conditions stimulated only the growth of roots. In the mutant, elevated CO2 caused well-known symptoms of nitrogen-starved plants, including decreased shoot/root ratio, reduced nitrate content and accumulation of anthocyanin, but also had an increased Chl content in the shoot, which was contradictory to the known effect of nitrogen depletion. A high-CO2-responsive change specific to the mutant was not observed in the levels of the major metabolites, although CO2 responses were observed in the WT and the mutant. These results indicated that elevated CO2 causes nitrogen limitation in the seedlings grown with a constantly limited supply of nitrogen, but the Chl content and the root biomass of the plant increase to enhance the activities of both photosynthesis and nitrogen uptake, while maintaining normal metabolism and response to high CO2.

  1. Anthropogenic CO2 in the ocean

    Directory of Open Access Journals (Sweden)

    Tsung-Hung Peng

    2005-06-01

    Full Text Available The focus of this review article is on the anthropogenic CO2 taken up by the ocean. There are several methods of identifying the anthropogenic CO2 signal and quantifying its inventory in the ocean. The ?C* method is most frequently used to estimate the global distribution of anthropogenic CO2 in the ocean. Results based on analysis of the dataset obtained from the comprehensive surveys of inorganic carbon distribution in the world oceans in the 1990s are given. These surveys were jointly conducted during the World Ocean Circulation Experiment (WOCE and the Joint Global Ocean Flux Study (JGOFS. This data set consists of 9618 hydrographic stations from a total of 95 cruises, which represents the most accurate and comprehensive view of the distribution of inorganic carbon in the global ocean available today. The increase of anthropogenic CO2 in the ocean during the past few decades is also evaluated using direct comparison of results from repeat surveys and using statistical method of Multi-parameter Linear Regression (MLR. The impact of increasing oceanic anthropogenic CO2 on the calcium carbonate system in the ocean is reviewed briefly as well. Extensive studies of CaCO3 dissolution as a result of increasing anthropogenic CO2 in the ocean have revealed several distinct oceanic regions where the CaCO3 undersaturation zone has expanded.

  2. Recent developments in CO2 lasers

    Science.gov (United States)

    Du, Keming

    1993-05-01

    CO2 lasers have been used in industry mainly for such things as cutting, welding, and surface processing. To conduct a broad spectrum of high-speed and high-quality applications, most of the developments in industrial CO2 lasers at the ILT are aimed at increasing the output power, optimizing the beam quality, and reducing the production costs. Most of the commercial CO2 lasers above 5 kW are transverse-flow systems using dc excitation. The applications of these lasers are limited due to the lower beam quality, the poor point stability, and the lower modulation frequency. To overcome the problems we developed a fast axial- flow CO2 laser using rf excitation with an output of 13 kW. In section 2 some of the results are discussed concerning the gas flow, the discharge, the resonator design, optical effects of active medium, the aerodynamic window, and the modulation of the output power. The first CO2 lasers ever built are diffusion-cooled systems with conventional dc excited cylindrical discharge tubes surrounded by cooling jackets. The output power per unit length is limited to 50 W/m by those lasers with cylindrical tubes. In the past few years considerable increases in the output power were achieved, using new mechanical geometries, excitation- techniques, and resonator designs. This progress in diffusion-cooled CO2 lasers is presented in section 3.

  3. CO2 efflux from cleared mangrove peat.

    Directory of Open Access Journals (Sweden)

    Catherine E Lovelock

    Full Text Available CO(2 emissions from cleared mangrove areas may be substantial, increasing the costs of continued losses of these ecosystems, particularly in mangroves that have highly organic soils.We measured CO(2 efflux from mangrove soils that had been cleared for up to 20 years on the islands of Twin Cays, Belize. We also disturbed these cleared peat soils to assess what disturbance of soils after clearing may have on CO(2 efflux. CO(2 efflux from soils declines from time of clearing from ∼10,600 tonnes km(-2 year(-1 in the first year to 3000 tonnes km(2 year(-1 after 20 years since clearing. Disturbing peat leads to short term increases in CO(2 efflux (27 umol m(-2 s(-1, but this had returned to baseline levels within 2 days.Deforesting mangroves that grow on peat soils results in CO(2 emissions that are comparable to rates estimated for peat collapse in other tropical ecosystems. Preventing deforestation presents an opportunity for countries to benefit from carbon payments for preservation of threatened carbon stocks.

  4. Reduction of emissions and geological storage of CO2. Innovation an industrial stakes

    International Nuclear Information System (INIS)

    Mandil, C.; Podkanski, J.; Socolow, R.; Dron, D.; Reiner, D.; Horrocks, P.; Fernandez Ruiz, P.; Dechamps, P.; Stromberg, L.; Wright, I.; Gazeau, J.C.; Wiederkehr, P.; Morcheoine, A.; Vesseron, P.; Feron, P.; Feraud, A.; Torp, N.T.; Christensen, N.P.; Le Thiez, P.; Czernichowski, I.; Hartman, J.; Roulet, C.; Roberts, J.; Zakkour, P.; Von Goerne, G.; Armand, R.; Allinson, G.; Segalen, L.; Gires, J.M.; Metz, B.; Brillet, B.

    2005-01-01

    An international symposium on the reduction of emissions and geological storage of CO 2 was held in Paris from 15 to 16 September 2005. The event, jointly organized by IFP, ADEME and BRGM, brought together over 400 people from more than 25 countries. It was an opportunity to review the international stakes related to global warming and also to debate ways of reducing CO 2 emissions, taking examples from the energy and transport sectors. The last day was dedicated to technological advances in the capture and geological storage of CO 2 and their regulatory and economic implications. This document gathers the available transparencies and talks presented during the colloquium: Opening address by F. Loos, French Minister-delegate for Industry; Session I - Greenhouse gas emissions: the international stakes. Outlook for global CO 2 emissions. The global and regional scenarios: Alternative scenarios for energy use and CO 2 emissions until 2050 by C. Mandil and J. Podkanski (IEA), The stabilization of CO 2 emissions in the coming 50 years by R. Socolow (Princeton University). Evolution of the international context: the stakes and 'factor 4' issues: Costs of climate impacts and ways towards 'factor 4' by D. Dron (ENS Mines de Paris), CO 2 emissions reduction policy: the situation in the United States by D. Reiner (MIT/Cambridge University), Post-Kyoto scenarios by P. Horrocks (European Commission), Possibilities for R and D in CO 2 capture and storage in the future FP7 program by P. Fernandez Ruiz and P. Dechamps (European Commission). Session II - CO 2 emission reductions in the energy and transport sectors. Reducing CO 2 emissions during the production and conversion of fossil energies (fixed installations): Combined cycles using hydrogen by G. Haupt (Siemens), CO 2 emission reductions in the oil and gas industry by I. Wright (BP). Reducing CO 2 emissions in the transport sector: Sustainable transport systems by P. Wiederkehr (EST International), The prospects for reducing

  5. How much CO2 is trapped in carbonate minerals of a natural CO2 occurrence?

    Science.gov (United States)

    Király, Csilla; Szabó, Zsuzsanna; Szamosfalvi, Ágnes; Cseresznyés, Dóra; Király, Edit; Szabó, Csaba; Falus, György

    2017-04-01

    Carbon Capture and Storage (CCS) is a transitional technology to decrease CO2 emissions from human fossil fuel usage and, therefore, to mitigate climate change. The most important criteria of a CO2 geological storage reservoir is that it must hold the injected CO2 for geological time scales without its significant seepage. The injected CO2 undergoes physical and chemical reactions in the reservoir rocks such as structural-stratigraphic, residual, dissolution or mineral trapping mechanisms. Among these, the safest is the mineral trapping, when carbonate minerals such as calcite, ankerite, siderite, dolomite and dawsonite build the CO2 into their crystal structures. The study of natural CO2 occurrences may help to understand the processes in CO2 reservoirs on geological time scales. This is the reason why the selected, the Mihályi-Répcelak natural CO2 occurrence as our research area, which is able to provide particular and highly significant information for the future of CO2 storage. The area is one of the best known CO2 fields in Central Europe. The main aim of this study is to estimate the amount of CO2 trapped in the mineral phase at Mihályi-Répcelak CO2 reservoirs. For gaining the suitable data, we apply petrographic, major and trace element (microprobe and LA-ICP-MS) and stable isotope analysis (mass spectrometry) and thermodynamic and kinetic geochemical models coded in PHREEQC. Rock and pore water compositions of the same formation, representing the pre-CO2 flooding stages of the Mihályi-Répcelak natural CO2 reservoirs are used in the models. Kinetic rate parameters are derived from the USGS report of Palandri and Kharaka (2004). The results of petrographic analysis show that a significant amount of dawsonite (NaAlCO3(OH)2, max. 16 m/m%) precipitated in the rock due to its reactions with CO2 which flooded the reservoir. This carbonate mineral alone traps about 10-30 kg/m3 of the reservoir rock from the CO2 at Mihályi-Répcelak area, which is an

  6. How secure is subsurface CO2 storage? Controls on leakage in natural CO2 reservoirs

    Science.gov (United States)

    Miocic, Johannes; Gilfillan, Stuart; McDermott, Christopher; Haszeldine, Stuart

    2014-05-01

    Carbon Capture and Storage (CCS) is the only industrial scale technology available to directly reduce carbon dioxide (CO2) emissions from fossil fuelled power plants and large industrial point sources to the atmosphere. The technology includes the capture of CO2 at the source and transport to subsurface storage sites, such as depleted hydrocarbon reservoirs or saline aquifers, where it is injected and stored for long periods of time. To have an impact on the greenhouse gas emissions it is crucial that there is no or only a very low amount of leakage of CO2 from the storage sites to shallow aquifers or the surface. CO2 occurs naturally in reservoirs in the subsurface and has often been stored for millions of years without any leakage incidents. However, in some cases CO2 migrates from the reservoir to the surface. Both leaking and non-leaking natural CO2 reservoirs offer insights into the long-term behaviour of CO2 in the subsurface and on the mechanisms that lead to either leakage or retention of CO2. Here we present the results of a study on leakage mechanisms of natural CO2 reservoirs worldwide. We compiled a global dataset of 49 well described natural CO2 reservoirs of which six are leaking CO2 to the surface, 40 retain CO2 in the subsurface and for three reservoirs the evidence is inconclusive. Likelihood of leakage of CO2 from a reservoir to the surface is governed by the state of CO2 (supercritical vs. gaseous) and the pressure in the reservoir and the direct overburden. Reservoirs with gaseous CO2 is more prone to leak CO2 than reservoirs with dense supercritical CO2. If the reservoir pressure is close to or higher than the least principal stress leakage is likely to occur while reservoirs with pressures close to hydrostatic pressure and below 1200 m depth do not leak. Additionally, a positive pressure gradient from the reservoir into the caprock averts leakage of CO2 into the caprock. Leakage of CO2 occurs in all cases along a fault zone, indicating that

  7. Photosynthetic response to globally increasing CO2 of co-occurring temperate seagrass species.

    Science.gov (United States)

    Borum, Jens; Pedersen, Ole; Kotula, Lukasz; Fraser, Matthew W; Statton, John; Colmer, Timothy D; Kendrick, Gary A

    2016-06-01

    Photosynthesis of most seagrass species seems to be limited by present concentrations of dissolved inorganic carbon (DIC). Therefore, the ongoing increase in atmospheric CO2 could enhance seagrass photosynthesis and internal O2 supply, and potentially change species competition through differential responses to increasing CO2 availability among species. We used short-term photosynthetic responses of nine seagrass species from the south-west of Australia to test species-specific responses to enhanced CO2 and changes in HCO3 (-) . Net photosynthesis of all species except Zostera polychlamys were limited at pre-industrial compared to saturating CO2 levels at light saturation, suggesting that enhanced CO2 availability will enhance seagrass performance. Seven out of the nine species were efficient HCO3 (-) users through acidification of diffusive boundary layers, production of extracellular carbonic anhydrase, or uptake and internal conversion of HCO3 (-) . Species responded differently to near saturating CO2 implying that increasing atmospheric CO2 may change competition among seagrass species if co-occurring in mixed beds. Increasing CO2 availability also enhanced internal aeration in the one species assessed. We expect that future increases in atmospheric CO2 will have the strongest impact on seagrass recruits and sparsely vegetated beds, because densely vegetated seagrass beds are most often limited by light and not by inorganic carbon. © 2015 John Wiley & Sons Ltd.

  8. CO2 Emission Factors for Coals

    Directory of Open Access Journals (Sweden)

    P. Orlović-Leko

    2015-03-01

    Full Text Available Emission factors are used in greenhouse gas inventories to estimate emissions from coal combustion. In the absence of direct measures, emissions factors are frequently used as a quick, low cost way to estimate emissions values. Coal combustion has been a major contributor to the CO2 flux into the atmosphere. Nearly all of the fuel carbon (99 % in coal is converted to CO2 during the combustion process. The carbon content is the most important coal parameter which is the measure of the degree of coalification (coal rank. Coalification is the alteration of vegetation to form peat, succeeded by the transformation of peat through lignite, sub-bituminous, bituminous to anthracite coal. During the geochemical or metamorphic stage, the progressive changes that occur within the coal are an increase in the carbon content and a decrease in the hydrogen and oxygen content resulting in a loss of volatiles. Heterogeneous composition of coal causes variation in CO2 emission from different coals. The IPCC (Intergovernmental Panel on Climate Change has produced guidelines on how to produce emission inventories which includes emission factors. Although 2006 IPCC Guidelines provided the default values specified according to the rank of the coal, the application of country-specific emission factors was recommended when estimating the national greenhouse gas emissions. This paper discusses the differences between country-specific emission factors and default IPCC CO2 emission factors, EF(CO2, for coals. Also, this study estimated EF(CO2 for two different types of coals and peat from B&H, on the basis fuel analyses. Carbon emission factors for coal mainly depend on the carbon content of the fuel and vary with both rank and geographic origin, which supports the idea of provincial variation of carbon emission factors. Also, various other factors, such as content of sulphur, minerals and macerals play an important role and influence EF(CO2 from coal. Carbonate minerals

  9. Potential maternal effects of elevated atmospheric CO2 on development and disease severity in a Mediterranean legume

    Directory of Open Access Journals (Sweden)

    José M. Grünzweig

    2011-07-01

    Full Text Available Global change can greatly affect plant populations both directly by influencing growing conditions and indirectly by maternal effects on development of offspring. More information is needed on transgenerational effects of global change on plants and on their interactions with pathogens. The current study assessed potential maternal effects of atmospheric CO2 enrichment on performance and disease susceptibility of first-generation offspring of the Mediterranean legume Onobrychis crista-galli. Mother plants were grown at three CO2 concentrations, and the study focused on their offspring that were raised under common ambient climate and CO2. In addition, progeny were exposed to natural infection by the fungal pathogen powdery mildew. In one out of three years, offspring of high-CO2 treatments (440 and 600 ppm had lower shoot biomass and reproductive output than offspring of low-CO2 treatment (280 ppm. Disease severity in a heavy-infection year was higher in high-CO2 than in low-CO2 offspring. However, some of the findings on maternal effects changed when the population was divided into two functionally diverging plant types distinguishable by flower color (pink, Type P; white Type W. Disease severity in a heavy-infection year was higher in high-CO2 than in low-CO2 progeny in the more disease-resistant (Type P, but not in the more susceptible plant type (Type W. In a low-infection year, maternal CO2 treatments did not differ in disease severity. Mother plants of Type P exposed to low CO2 produced larger seeds than all other combinations of CO2 and plant type, which might contribute to higher offspring performance. This study showed that elevated CO2 potentially exerts environmental maternal effects on performance of progeny and, notably, also on their susceptibility to natural infection by a pathogen. Maternal effects of global change might differently affect functionally divergent plant types, which could impact population fitness and alter plant

  10. Does the oil fortune vanish with Kyoto. The effects on energy consumption and emissions from stabilising the CO2 concentration

    International Nuclear Information System (INIS)

    Lindholt, Lars; Rosendahl, Knut Einar

    2000-01-01

    The article discusses measures for and the consequences of stabilising the CO 2 concentration at various levels on the oil industry, the environment and the energy policies. The structure of an international taxation scenario will depend on which CO 2 level and forecasting model are selected as well as the time profiles and levels of CO 2 emissions in the various countries

  11. Fingerprinting captured CO2 using natural tracers: Determining CO2 fate and proving ownership

    Science.gov (United States)

    Flude, Stephanie; Gilfillan, Stuart; Johnston, Gareth; Stuart, Finlay; Haszeldine, Stuart

    2016-04-01

    In the long term, captured CO2 will most likely be stored in large saline formations and it is highly likely that CO2 from multiple operators will be injected into a single saline formation. Understanding CO2 behavior within the reservoir is vital for making operational decisions and often uses geochemical techniques. Furthermore, in the event of a CO2 leak, being able to identify the owner of the CO2 is of vital importance in terms of liability and remediation. Addition of geochemical tracers to the CO2 stream is an effective way of tagging the CO2 from different power stations, but may become prohibitively expensive at large scale storage sites. Here we present results from a project assessing whether the natural isotopic composition (C, O and noble gas isotopes) of captured CO2 is sufficient to distinguish CO2 captured using different technologies and from different fuel sources, from likely baseline conditions. Results include analytical measurements of CO2 captured from a number of different CO2 capture plants and a comprehensive literature review of the known and hypothetical isotopic compositions of captured CO2 and baseline conditions. Key findings from the literature review suggest that the carbon isotope composition will be most strongly controlled by that of the feedstock, but significant fractionation is possible during the capture process; oxygen isotopes are likely to be controlled by the isotopic composition of any water used in either the industrial process or the capture technology; and noble gases concentrations will likely be controlled by the capture technique employed. Preliminary analytical results are in agreement with these predictions. Comparison with summaries of likely storage reservoir baseline and shallow or surface leakage reservoir baseline data suggests that C-isotopes are likely to be valuable tracers of CO2 in the storage reservoir, while noble gases may be particularly valuable as tracers of potential leakage.

  12. Atmospheric inversion of the surface CO2 flux with 13CO2 constraint

    Science.gov (United States)

    Chen, J. M.; Mo, G.; Deng, F.

    2013-10-01

    Observations of 13CO2 at 73 sites compiled in the GLOBALVIEW database are used for an additional constraint in a global atmospheric inversion of the surface CO2 flux using CO2 observations at 210 sites for the 2002-2004 period for 39 land regions and 11 ocean regions. This constraint is implemented using the 13CO2/CO2 flux ratio modeled with a terrestrial ecosystem model and an ocean model. These models simulate 13CO2 discrimination rates of terrestrial photosynthesis and respiration and ocean-atmosphere diffusion processes. In both models, the 13CO2 disequilibrium between fluxes to and from the atmosphere is considered due to the historical change in atmospheric 13CO2 concentration. For the 2002-2004 period, the 13CO2 constraint on the inversion increases the total land carbon sink from 3.40 to 3.70 Pg C yr-1 and decreases the total oceanic carbon sink from 1.48 to 1.12 Pg C yr-1. The largest changes occur in tropical areas: a considerable decrease in the carbon source in the Amazon forest, and this decrease is mostly compensated by increases in the ocean region immediately west of the Amazon and the southeast Asian land region. Our further investigation through different treatments of the 13CO2/CO2 flux ratio used in the inversion suggests that variable spatial distributions of the 13CO2 isotopic discrimination rate simulated by the models over land and ocean have considerable impacts on the spatial distribution of the inverted CO2 flux over land and the inversion results are not sensitive to errors in the estimated disequilibria over land and ocean.

  13. Schools under fire? : school shootings and the construction of a cultural discourse of emergency

    OpenAIRE

    Braselmann, Silke

    2016-01-01

    Contrary to popular belief, rampage violence at suburban and rural schools occurred before the infamous Columbine High School shooting in April 1999. While school shootings — before Columbine gained international media attention — were treated as a local rather than a national or even international problem, they are now seen as an emergent phenomenon that has to be addressed with appropriate urgency. In this paper, I want to examine whether school shootings are in fact increasing and addre...

  14. Diffuse CO2 degassing at Vesuvio, Italy

    Science.gov (United States)

    Frondini, Francesco; Chiodini, Giovanni; Caliro, Stefano; Cardellini, Carlo; Granieri, Domenico; Ventura, Guido

    2004-10-01

    At Vesuvio, a significant fraction of the rising hydrothermal-volcanic fluids is subjected to a condensation and separation process producing a CO2-rich gas phase, mainly expulsed through soil diffuse degassing from well defined areas called diffuse degassing structures (DDS), and a liquid phase that flows towards the outer part of the volcanic cone. A large amount of thermal energy is associated with the steam condensation process and subsequent cooling of the liquid phase. The total amount of volcanic-hydrothermal CO2 discharged through diffuse degassing has been computed through a sequential Gaussian simulation (sGs) approach based on several hundred accumulation chamber measurements and, at the time of the survey, amounted to 151 t d-1. The steam associated with the CO2 output, computed assuming that the original H2O/CO2 ratio of hydrothermal fluids is preserved in fumarolic effluents, is 553 t d-1, and the energy produced by the steam condensation and cooling of the liquid phase is 1.47×1012 J d-1 (17 MW). The location of the CO2 and temperature anomalies show that most of the gas is discharged from the inner part of the crater and suggests that crater morphology and local stratigraphy exert strong control on CO2 degassing and subsurface steam condensation. The amounts of gas and energy released by Vesuvio are comparable to those released by other volcanic degassing areas of the world and their estimates, through periodic surveys of soil CO2 flux, can constitute a useful tool to monitor volcanic activity.

  15. Capture and geological storage of CO2. Innovation, industrial stakes and realizations

    International Nuclear Information System (INIS)

    Lavergne, R.; Podkanski, J.; Rohner, H.; Otter, N.; Swift, J.; Dance, T.; Vesseron, Ph.; Reich, J.P.; Reynen, B.; Wright, L.; Marliave, L. de; Stromberg, L.; Aimard, N.; Wendel, H.; Erdol, E.; Dino, R.; Renzenbrink, W.; Birat, J.P.; Czernichowski-Lauriol, I.; Christensen, N.P.; Le Thiez, P.; Paelinck, Ph.; David, M.; Pappalardo, M.; Moisan, F.; Marston, Ph.; Law, M.; Zakkour, P.; Singer, St.; Philippe, Th.; Philippe, Th.

    2007-01-01

    The awareness of the international community and the convergence of scientific data about the global warming confirm the urgency of implementing greenhouse gases abatement technologies at the world scale. The growth of world energy demand will not allow to rapidly get rid of the use of fossil fuels which are the main sources of greenhouse gases. Therefore, the capture and disposal of CO 2 is a promising way to conciliate the use of fossil fuels and the abatement of pollutants responsible for the global warming. The economical and industrial stakes of this technique are enormous. In front of the success of a first international colloquium on this topic held in Paris in 2005, the IFP, the BRGM and the Ademe have jointly organized a second colloquium in October 2007, in particular to present the first experience feedbacks of several pilot experiments all over the world. This document gathers the transparencies of 27 presentations given at this colloquium and dealing with: the 4. IPCC report on the stakes of CO 2 capture and storage; the factor 4: how to organize the French economy transition from now to 2050; the technology perspectives, scenarios and strategies up to 2050; the European technological platform on 'zero-emission thermal plants'; the CO 2 capture and storage road-map in the USA; research, development and implementation of CO 2 capture and storage in Australia; the Canadian experience; ten years of CO 2 capture and storage in Norway; the In Salah operations (Algeria); CO 2 capture and storage: from vision to realisation; the oxi-combustion and storage pilot unit of Lacq (France); the Altmark gas field (Germany): analysis of CO 2 capture and storage potentialities in the framework of a gas assisted recovery project; oil assisted recovery and CO 2 related storage activities in Brazil: the Buracica and Miranga fields experience; carbon capture and storage, an option for coal power generation; steel-making industries and their CO 2 capture and storage needs

  16. An update to the Surface Ocean CO2 Atlas (SOCAT version 2)

    NARCIS (Netherlands)

    Bakker, D.C.E.; Pfeil, B.; Smith, K.; Hankin, S.; Olsen, A.; Alin, S. R.; Cosca, C.; Harasawa, S.; Kozyr, A.; Nojiri, Y.; O'Brien, K. M.; Schuster, U.; Telszewski, M.; Tilbrook, B.; Wada, C.; Akl, J.; Barbero, L.; Bates, N. R.; Boutin, J.; Bozec, Y.; Cai, W. -J.; Castle, R. D.; Chavez, F. P.; Chen, L.; Chierici, M.; Currie, K.; de Baar, H. J. W.; Evans, W.; Feely, R. A.; Fransson, A.; Gao, Z.; Hales, B.; Hardman-Mountford, N. J.; Hoppema, M.; Huang, W. -J.; Hunt, C. W.; Huss, B.; Ichikawa, T.; Johannessen, T.; Jones, E. M.; Jones, S. D.; Jutterstrom, S.; Kitidis, V.; Koertzinger, A.; Landschuetzer, P.; Lauvset, S. K.; Lefevre, N.; Manke, A. B.; Mathis, J. T.; Merlivat, L.; Metzl, N.; Murata, A.; Newberger, T.; Omar, A. M.; Ono, T.; Park, G. -H.; Paterson, K.; Pierrot, D.; Rios, A. F.; Sabine, C. L.; Saito, S.; Salisbury, J.; Sarma, V. V. S. S.; Schlitzer, R.; Sieger, R.; Skjelvan, I.; Steinhoff, T.; Sullivan, K. F.; Sun, H.; Sutton, A. J.; Suzuki, T.; Sweeney, C.; Takahashi, T.; Tjiputra, J.; Tsurushima, N.; van Heuven, S. M. A. C.; Vandemark, D.; Vlahos, P.; Wallace, D. W. R.; Wanninkhof, R.; Watson, A.J.

    2014-01-01

    The Surface Ocean CO2 Atlas (SOCAT), an activity of the international marine carbon research community, provides access to synthesis and gridded fCO(2) (fugacity of carbon dioxide) products for the surface oceans. Version 2 of SOCAT is an update of the previous release (version 1) with more data

  17. Initial Results of an Intercomparison of AMS-Based Atmospheric 14CO2 Measurements

    NARCIS (Netherlands)

    Miller, John; Lehman, Scott; Wolak, Chad; Turnbull, Jocelyn; Dunn, Gregory; Graven, Heather; Keeling, Ralph; Meijer, Harro A. J.; Aerts-Bijma, Anita Th; Palstra, Sanne W. L.; Smith, Andrew M.; Allison, Colin; Southon, John; Xu, Xiaomei; Nakazawa, Takakiyo; Aoki, Shuji; Nakamura, Toshio; Guilderson, Thomas; LaFranchi, Brian; Mukai, Hitoshi; Terao, Yukio; Uchida, Masao; Kondo, Miyuki

    2013-01-01

    This article presents results from the first 3 rounds of an international intercomparison of measurements of Delta(CO2)-C-14 in liter-scale samples of whole air by groups using accelerator mass spectrometry (AMS). The ultimate goal of the intercomparison is to allow the merging of Delta(CO2)-C-14

  18. A STELLA model to estimate soil CO2 emissions from a short-rotation woody crop

    Science.gov (United States)

    Ying Ouyang; Theodor D. Leininger; Jeff Hatten; Prem B. Parajuli

    2012-01-01

    The potential for climatic factors as well as soil–plant–climate interactions to change as a result of rising levels of atmospheric CO2 concentration is an issue of increasing international environmental concern. Agricultural and forest practices and managements may be important contributors to mitigating elevated atmospheric CO2...

  19. CO2-Water-Rock Wettability: Variability, Influencing Factors, and Implications for CO2 Geostorage.

    Science.gov (United States)

    Iglauer, Stefan

    2017-05-16

    Carbon geosequestration (CGS) has been identified as a key technology to reduce anthropogenic greenhouse gas emissions and thus significantly mitigate climate change. In CGS, CO 2 is captured from large point-source emitters (e.g., coal fired power stations), purified, and injected deep underground into geological formations for disposal. However, the CO 2 has a lower density than the resident formation brine and thus migrates upward due to buoyancy forces. To prevent the CO 2 from leaking back to the surface, four trapping mechanisms are used: (1) structural trapping (where a tight caprock acts as a seal barrier through which the CO 2 cannot percolate), (2) residual trapping (where the CO 2 plume is split into many micrometer-sized bubbles, which are immobilized by capillary forces in the pore network of the rock), (3) dissolution trapping (where CO 2 dissolves in the formation brine and sinks deep into the reservoir due to a slight increase in brine density), and (4) mineral trapping (where the CO 2 introduced into the subsurface chemically reacts with the formation brine or reservoir rock or both to form solid precipitates). The efficiency of these trapping mechanisms and the movement of CO 2 through the rock are strongly influenced by the CO 2 -brine-rock wettability (mainly due to the small capillary-like pores in the rock which form a complex network), and it is thus of key importance to rigorously understand CO 2 -wettability. In this context, a substantial number of experiments have been conducted from which several conclusions can be drawn: of prime importance is the rock surface chemistry, and hydrophilic surfaces are water-wet while hydrophobic surfaces are CO 2 -wet. Note that CO 2 -wet surfaces dramatically reduce CO 2 storage capacities. Furthermore, increasing pressure, salinity, or dissolved ion valency increases CO 2 -wettability, while the effect of temperature is not well understood. Indeed theoretical understanding of CO 2 -wettability and the

  20. Elevated CO2 increases Cs uptake and alters microbial communities and biomass in the rhizosphere of Phytolacca americana Linn (pokeweed) and Amaranthus cruentus L. (purple amaranth) grown on soils spiked with various levels of Cs

    International Nuclear Information System (INIS)

    Song, Ningning; Zhang, Ximei; Wang, Fangli; Zhang, Changbo; Tang, Shirong

    2012-01-01

    General concern about increasing global atmospheric CO 2 levels owing to the ongoing fossil fuel combustion and elevated levels of radionuclides in the environment, has led to growing interest in the responses of plants to interactive effects of elevated CO 2 and radionuclides in terms of phytoremediation and food safety. To assess the combined effects of elevated CO 2 and cesium contamination on plant biomass, microbial activities in the rhizosphere soil and Cs uptake, Phytolacca americana Linn (pokeweed, C3 specie) and Amaranthus cruentus L. (purple amaranth, C4 specie) were grown in pots of soils containing five levels of cesium (0, 100, 300, 500 and 1000 mg Cs kg −1 ) under two levels of CO 2 (360 and 860 μL L −1 , respectively). Shoot and root biomass of P. americana and Amaranthus crentus was generally higher under elevated CO 2 than under ambient CO 2 for all treatments. Both plant species exhibited higher Cs concentration in the shoots and roots under elevated CO 2 than ambient CO 2 . For P. americana grown at 0, 100, 300, 500 and 1000 mg Cs kg −1 , the increase magnitude of Cs concentration due to elevated CO 2 was 140, 18, 11, 34 and 15% in the shoots, and 150, 20, 14, 15 and 19% in the roots, respectively. For A. cruentus, the corresponding value was 118, 28, 21, 14 and 17% in the shoots, and 126, 6, 11, 17 and 22% in the roots, respectively. Higher bioaccumulation factors were noted for both species grown under elevated CO 2 than ambient CO 2 . The populations of bacteria, actinomycetes and fungi, and the microbial C and N in the rhizosphere soils of both species were higher at elevated CO 2 than at ambient CO 2 with the same concentration of Cs. The results suggested that elevated CO 2 significantly affected plant biomass, Cs uptake, soil C and N concentrations, and community composition of soil microbes associated with P. americana and A. cruentus roots. The knowledge gained from this investigation constitutes an important advancement in

  1. A cost effective CO2 strategy

    DEFF Research Database (Denmark)

    , a scenario-part and a cost-benefit part. Air and sea modes are not analyzed. The model adopts a bottom-up approach to allow a detailed assessment of transport policy measures. Four generic areas of intervention were identified and the likely effect on CO2 emissions, socioeconomic efficiency and other...... are evaluated according to CO2 reduction potential and according to the ‘shadow price’ on a reduction of one ton CO2. The shadow price reflects the costs (and benefits) of the different measures. Comparing the measures it is possible to identify cost effective measures, but these measures are not necessarily...... by the Ministry of Transport, with the Technical University of Denmark as one of the main contributors. The CO2-strategy was to be based on the principle of cost-effectiveness. A model was set up to assist in the assessment. The model consists of a projection of CO2-emissions from road and rail modes from 2020...

  2. Rangeland -- plant response to elevated CO2

    International Nuclear Information System (INIS)

    Owensby, C.E.; Coyne, P.I.; Ham, J.M.; Parton, W.; Rice, C.; Auen, L.M.; Adam, N.

    1993-01-01

    Plots of a tallgrass prairie ecosystem were exposed to ambient and twice-ambient CO 2 concentrations in open-top chambers and compared to unchambered ambient CO 2 plots during the entire growing season from 1989 through 1992. Relative root production among treatments was estimated using root ingrowth bags which remained in place throughout the growing season. Latent heat flux was simulated with and without water stress. Botanical composition was estimated annuallyin all treatments. Open-top chambers appeared to reduce latent heat flux and increase water use efficiency similar to elevated CO 2 when water stress was not severe, but under severe water stress, chamber effect on water use efficiency was limited. In natural ecosystems with periodic moisture stress, increased water use efficiency under elevated CO 2 apparently would have a greater impact on productivity than photosynthetic pathway. Root ingrowth biomass was greater in 1990 and 1991 on elevated CO 2 plots compared to ambient or chambered-ambient plots. In 1992, there was no difference in root ingrowth biomass among treatments

  3. Economic efficiency of CO2 reduction programs

    International Nuclear Information System (INIS)

    Tahvonen, O.; Storch, H. von; Storch, J. von

    1993-01-01

    A highly simplified time-dependent low-dimensional system has been designed to describe conceptually the interaction of climate and economy. Enhanced emission of carbon dioxide (CO 2 ) is understood as the agent that not only favors instantaneous consumption but also causes unfavorable climate changes at a later time. The problem of balancing these two counterproductive effects of CO 2 emissions on a finite time horizon is considered. The climate system is represented by just two parameters, namely a globally averaged near-surface air-temperature and a globally averaged troposheric CO 2 concentration. The costs of abating CO 2 emissions are monitored by a function which depends quadratically on the percentage reduction of emission compared to an 'uncontrolled emission' scenario. Parameters are fitted to historical climate data and to estimates from studies of CO 2 abatement costs. Two optimization approaches, which differ from earlier attempts to describe the interaction of economy and climate, are discussed. In the 'cost oriented' strategy an optimal emission path is identified which balances the abatement costs and explicitly formulated damage costs. These damage costs, whose estimates are very uncertain, are hypothesized to be a linear function of the time-derivative of temperature. In the 'target oriented' strategy an emission path is chosen so that the abatement costs are minimal while certain restrictions on the terminal temperature and concentration change are met. (orig.)

  4. CO2-Switchable Membranes Prepared by Immobilization of CO2-Breathing Microgels.

    Science.gov (United States)

    Zhang, Qi; Wang, Zhenwu; Lei, Lei; Tang, Jun; Wang, Jianli; Zhu, Shiping

    2017-12-20

    Herein, we report the development of a novel CO 2 -responsive membrane system through immobilization of CO 2 -responsive microgels into commercially available microfiltration membranes using a method of dynamic adsorption. The microgels, prepared from soap-free emulsion polymerization of CO 2 -responsive monomer 2-(diethylamino)ethyl methacrylate (DEA), can be reversibly expanded and shrunken upon CO 2 /N 2 alternation. When incorporated into the membranes, this switching behavior was preserved and further led to transformation between microfiltration and ultrafiltration membranes, as indicated from the dramatic changes on water flux and BSA rejection results. This CO 2 -regulated performance switching of membranes was caused by the changes of water transportation channel, as revealed from the dynamic water contact angle tests and SEM observation. This work represents a simple yet versatile strategy for making CO 2 -responsive membranes.

  5. CO2 sensing and CO2 regulation of stomatal conductance: advances and open questions

    Science.gov (United States)

    Engineer, Cawas; Hashimoto-Sugimoto, Mimi; Negi, Juntaro; Israelsson-Nordstrom, Maria; Azoulay-Shemer, Tamar; Rappel, Wouter-Jan; Iba, Koh; Schroeder, Julian

    2015-01-01

    Guard cells form epidermal stomatal gas exchange valves in plants and regulate the aperture of stomatal pores in response to changes in the carbon dioxide (CO2) concentration in leaves. Moreover, the development of stomata is repressed by elevated CO2 in diverse plant species. Evidence suggests that plants can sense CO2 concentration changes via guard cells and via mesophyll tissues in mediating stomatal movements. We review new discoveries and open questions on mechanisms mediating CO2-regulated stomatal movements and CO2 modulation of stomatal development, which together function in CO2-regulation of stomatal conductance and gas exchange in plants. Research in this area is timely in light of the necessity of selecting and developing crop cultivars which perform better in a shifting climate. PMID:26482956

  6. Which are the most important parameters for modelling carbon assimilation in boreal Norway spruce under elevated [CO(2)] and temperature conditions?

    Science.gov (United States)

    Hall, Marianne; Medlyn, Belinda E; Abramowitz, Gab; Franklin, Oskar; Räntfors, Mats; Linder, Sune; Wallin, Göran

    2013-11-01

    Photosynthesis is highly responsive to environmental and physiological variables, including phenology, foliage nitrogen (N) content, atmospheric CO2 concentration ([CO2]), irradiation (Q), air temperature (T) and vapour pressure deficit (D). Each of these responses is likely to be modified by long-term changes in climatic conditions such as rising air temperature and [CO2]. When modelling photosynthesis under climatic changes, which parameters are then most important to calibrate for future conditions? To assess this, we used measurements of shoot carbon assimilation rates and microclimate conditions collected at Flakaliden, northern Sweden. Twelve 40-year-old Norway spruce trees were enclosed in whole-tree chambers and exposed to elevated [CO2] and elevated air temperature, separately and in combination. The treatments imposed were elevated temperature, +2.8 °C in July/August and +5.6 °C in December above ambient, and [CO2] (ambient CO2 ∼370 μ mol mol(-1), elevated CO2 ∼700 μ mol mol(-1)). The relative importance of parameterization of Q, T and D responses for effects on the photosynthetic rate, expressed on a projected needle area, and the annual shoot carbon uptake was quantified using an empirical shoot photosynthesis model, which was developed and fitted to the measurements. The functional form of the response curves was established using an artificial neural network. The [CO2] treatment increased annual shoot carbon (C) uptake by 50%. Most important was effects on the light response curve, with a 67% increase in light-saturated photosynthetic rate, and a 52% increase in the initial slope of the light response curve. An interactive effect of light saturated photosynthetic rate was found with foliage N status, but no interactive effect for high temperature and high CO2. The air temperature treatment increased the annual shoot C uptake by 44%. The most important parameter was the seasonality, with an elongation of the growing season by almost 4

  7. Canadian CO2 Capture and Storage Technology Network : promoting zero emissions technologies

    International Nuclear Information System (INIS)

    2004-11-01

    This brochure provided information on some Canadian initiatives in carbon dioxide (CO 2 ) capture and storage. There has been growing interest in the implementation of components of CO 2 capture, storage and utilization technologies in Canada. Technology developments by the CANMET Energy Technology Centre concerning CO 2 capture using oxy-fuel combustion and amine separation were examined. Techniques concerning gasification of coal for electricity production and CO 2 capture were reviewed. Details of a study of acid gas underground injection were presented. A review of monitoring technologies in CO 2 storage in enhanced oil recovery was provided. Issues concerning the enhancement of methane recovery through the monitoring of CO 2 injected into deep coal beds were discussed. Storage capacity assessment of Canadian sedimentary basins, coal seams and oil and gas reservoirs were reviewed, in relation to their suitability for CO 2 sequestration. Details of the International Test Centre for Carbon Dioxide Capture in Regina, Saskatchewan were presented, as well as issues concerning the sequestration of CO 2 in oil sands tailings streams. A research project concerning the geologic sequestration of CO 2 and simultaneous CO 2 and methane production from natural gs hydrate reservoirs was also discussed. 12 figs.

  8. CO2 capture and geological storage: The BRGM, sixteen years of involvement in major research projects. The contribution of technical abilities and expertise in Earth Sciences to the work of national and international authorities

    International Nuclear Information System (INIS)

    2009-01-01

    This press document presents the abilities and the activities of the French BRGM (Bureau de Recherches Geologiques et Minieres, Office for geological and mining researches) in developing knowledge on storage capacities and on the behaviour of deep aquifers, in contributing to the main national and European research programs, in actively participating to European and international networks, in being an expert for the MEEDDM (the French ministry of energy, ecology, sustainable development and sea) and the ADEME (the French agency for energy conservation), and as the French representative in several international authorities

  9. Evasion of CO2 injected into the ocean in the context of CO2 stabilization

    International Nuclear Information System (INIS)

    Kheshgi, Haroon S.

    2004-01-01

    The eventual evasion of injected CO 2 to the atmosphere is one consideration when assessing deep-sea disposal of CO 2 as a potential response option to climate change concerns. Evasion estimated using an ocean carbon cycle model is compared to long-term trajectories for future CO 2 emissions, including illustrative cases leading to stabilization of CO 2 concentration at various levels. Modeled residence time for CO 2 injected into the deep ocean exceeds the 100-year time-scale usually considered in scenarios for future emissions, and the potential impacts of climate change. Illustrative cases leading monotonically to constant CO 2 concentration have been highlighted by the Intergovernmental Panel on Climate Change to give guidance on possible timing of emission reductions that may be required to stabilize greenhouse gas concentrations at various levels. For stabilization cases considered, significant modeled evasion does not occur until long after CO 2 emissions have reached a maximum and begun to decline. Illustrative cases can also lead to a maximum in CO 2 concentration followed by a decline to slowly decreasing concentrations. In such cases, future injection of emissions into the deep ocean leads to lower maximum CO 2 concentration, with less effect on concentration later on in time

  10. Effect of Uncertainties in CO2 Property Databases on the S-CO2 Compressor Performance

    International Nuclear Information System (INIS)

    Lee, Je Kyoung; Lee, Jeong Ik; Ahn, Yoonhan; Kim, Seong Gu; Cha, Je Eun

    2013-01-01

    Various S-CO 2 Brayton cycle experiment facilities are on the state of construction or operation for demonstration of the technology. However, during the data analysis, S-CO 2 property databases are widely used to predict the performance and characteristics of S-CO 2 Brayton cycle. Thus, a reliable property database is very important before any experiment data analyses or calculation. In this paper, deviation of two different property databases which are widely used for the data analysis will be identified by using three selected properties for comparison, C p , density and enthalpy. Furthermore, effect of above mentioned deviation on the analysis of test data will be briefly discussed. From this deviation, results of the test data analysis can have critical error. As the S-CO 2 Brayton cycle researcher knows, CO 2 near the critical point has dramatic change on thermodynamic properties. Thus, it is true that a potential error source of property prediction exists in CO 2 properties near the critical point. During an experiment data analysis with the S-CO 2 Brayton cycle experiment facility, thermodynamic properties are always involved to predict the component performance and characteristics. Thus, construction or defining of precise CO 2 property database should be carried out to develop Korean S-CO 2 Brayton cycle technology

  11. Surface CO2 leakage during the first shallow subsurface CO2 release experiment

    OpenAIRE

    Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

    2008-01-01

    A new field facility was used to study CO2 migration processes and test techniques to detect and quantify potential CO2 leakage from geologic storage sites. For 10 days starting 9 July 2007, and for seven days starting 5 August 2007, 0.1 and 0.3 t CO2 d-1, respectively, were released from a ~;100-m long, sub-water table (~;2.5-m depth) horizontal well. The spatio-temporal evolution of leakage was mapped through repeated grid measurements of soil CO2 flux (FCO2). The surface leakage onset...

  12. The idea of global CO2 trade

    International Nuclear Information System (INIS)

    Svendsen, G.T.

    1999-01-01

    The US has been criticized for wanting to earn a fortune on a global CO 2 market. However, compared to the situation without trade and provided that such a market is designed so that it does not pay to cheat, a global CO 2 market may provide the world with an epoch-making means of cost-effective control which can solve future global environmental problems. The economic gains from 'hot air' distributions of permits and CO 2 trade make the system politically attractive to potential participants. For example, vital financial subsidies from the EU to Eastern Europe are to be expected. It will probably not pay to cheat if quotas are renewed periodically by the UN. Cheating countries are then to be excluded from further profitable trade. Also, a periodical renewal of permits makes it possible to tighten target levels in the future

  13. CO2 utilization: Developments in conversion processes

    Directory of Open Access Journals (Sweden)

    Erdogan Alper

    2017-03-01

    The potential utilization of CO2, captured at power plants, should also been taken into consideration for sustainability. This CO2 source, which is potentially a raw material for the chemical industry, will be available at sufficient quality and at gigantic quantity upon realization of on-going tangible capture projects. Products resulting from carboxylation reactions are obvious conversions. In addition, provided that enough supply of energy from non-fossil resources, such as solar [1], is ensured, CO2 reduction reactions can produce several valuable commodity chemicals including multi-carbon compounds, such as ethylene and acrylic acid, in addition to C1 chemicals and polymers. Presently, there are only few developing technologies which can find industrial applications. Therefore, there is a need for concerted research in order to assess the viability of these promising exploratory technologies rationally.

  14. Crop responses to CO2 enrichment

    International Nuclear Information System (INIS)

    Rogers, H.H.; Dahlman, R.C.

    1993-01-01

    Carbon dioxide is rising in the global atmosphere, and this increase can be expected to continue into the foreseeable future. This compound is an essential input to plant life. Crop function is affected across all scales from biochemical to agroecosystem. An array of methods (leaf cuvettes, field chambers, free-air release systems) are available for experimental studies of CO 2 effects. Carbon dioxide enrichment of the air in which crops grow usually stimulates their growth and yield. Plant structure and physiology are markedly altered. Interactions between CO 2 and environmental factors that influence plants are known to occur. Implications for crop growth and yield are enormous. Strategies designed to assure future global food security must include a consideration of crop responses to elevated atmospheric CO 2 . 137 refs., 4 figs., 4 tabs

  15. Waste cleaning using CO2-acid microemulsion

    International Nuclear Information System (INIS)

    Park, Kwangheon; Sung, Jinhyun; Koh, Moonsung; Ju, Minsu

    2011-01-01

    Frequently we need to decontaminate radioactive wastes for volume reduction purposes. Metallic contaminants in wastes can be removed by dissolution to acid; however, this process produces a large amount of liquid acid waste. To reduce this 2ndary liquid waste, we suggest CO 2 -acid emulsion in removing metallic contaminants. Micro- and macro-emulsion of acid in liquid/supercritical CO 2 were successfully made. The formation region of microemulsion (water or acid in CO 2 ) was measured, and stability of the microemulsion was analyzed with respect to surfactant types. We applied micro- and macro-emulsion containing acid to the decontamination of radioactive metallic parts contaminated on the surface. The cleaning methods of micro- and macro-emulsion seemed better compared to the conventional acid cleaning. Moreover, these methods produce very small amount of secondary wastes. (author)

  16. Direct electroreduction of CO2 into hydrocarbon

    International Nuclear Information System (INIS)

    Winea, Gauthier; Ledoux, Marc-Jacques; Pham-Huu, Cuong; Gangeri, Miriam; Perathoner, Siglinda; Centi, Gabriele

    2006-01-01

    A lot of methods exist to directly reduce carbon dioxide into hydrocarbons: the photoelectrochemical process is certainly the most interesting, essentially due to the similarities with photosynthesis. As the human activities produce a great quantity of CO 2 , this one can then be considered as an infinite source of carbon. The products of this reaction are identical to those obtained during a Fischer-Tropsch reaction, that is to say hydrocarbons, alcohols and carboxylic acids. These works deal with the electrochemical reduction of CO 2 in standard conditions of temperature and pressure. The photochemical part has been replaced by a current generator as electrons source and a KHCO 3 aqueous solution as protons source. The first catalytic results clearly show that it is possible to reduce CO 2 into light hydrocarbons, typically from C1 to C9. (O.M.)

  17. Cutting weeds with a CO2 laser

    DEFF Research Database (Denmark)

    Heisel, T.; Schou, Jørgen; Christensen, S.

    2001-01-01

    Stems of Chenopodium album. and Sinapis arvensis. and leaves of Lolium perenne. were cut with a CO2 laser or with a pair of scissors. Treatments were carried out on greenhouse-grown pot plants at three different growth stages and at two heights. Plant dry matter was measured 2 to 5 weeks after...... treatment. The relationship between dry weight and laser energy was analysed using a non-linear dose-response regression model. The regression parameters differed significantly between the weed species. At all growth stages and heights S. arvensis was more difficult to cut with a CO2 laser than C. album....... When stems were cut below the meristems, 0.9 and 2.3 J mm(-1) of CO2 laser energy dose was sufficient to reduce by 90% the biomass of C. album and S. arvensis respectively. Regrowth appeared when dicotyledonous plant stems were cut above meristems, indicating that it is important to cut close...

  18. Assessment of CO2 free energy options

    International Nuclear Information System (INIS)

    Cavlina, N.; Raseta, D.; Matutinovic, I.

    2014-01-01

    One of the European Union climate and energy targets is to significantly reduce CO 2 emissions, at least 20% by 2020, compared to 1990. In the power industry, most popular solution is use of solar and wind power. Since their production varies significantly during the day, for the purpose of base-load production they can be paired with gas-fired power plant. Other possible CO 2 -free solution is nuclear power plant. This article compared predicted cost of energy production for newly built nuclear power plant and newly built combination of wind or solar and gas-fired power plant. Comparison was done using Levelized Unit of Energy Cost (LUEC). Calculations were performed using the Monte Carlo method. For input parameters that have biggest uncertainty (gas cost, CO 2 emission fee) those uncertainties were addressed not only through probability distribution around predicted value, but also through different scenarios. Power plants were compared based on their economic lifetime. (authors)

  19. The ATLAS IBL CO2 Cooling System

    CERN Document Server

    AUTHOR|(INSPIRE)INSPIRE-00237783; The ATLAS collaboration; Zwalinski, L.; Bortolin, C.; Vogt, S.; Godlewski, J.; Crespo-Lopez, O.; Van Overbeek, M.; Blaszcyk, T.

    2017-01-01

    The ATLAS Pixel detector has been equipped with an extra B-layer in the space obtained by a reduced beam pipe. This new pixel detector called the ATLAS Insertable B-Layer (IBL) is installed in 2014 and is operational in the current ATLAS data taking. The IBL detector is cooled with evaporative CO2 and is the first of its kind in ATLAS. The ATLAS IBL CO2 cooling system is designed for lower temperature operation (<-35⁰C) than the previous developed CO2 cooling systems in High Energy Physics experiments. The cold temperatures are required to protect the pixel sensors for the high expected radiation dose up to 550 fb^-1 integrated luminosity.

  20. Novel concepts for CO2 capture

    International Nuclear Information System (INIS)

    Dijkstra, J.W.; Jansen, D.

    2004-01-01

    This paper describes the possibilities for power generation with CO 2 capture using envisaged key technologies: gas turbines, membranes and solid oxide fuel cells (SOFCs). First, the underlying programs in the Netherlands and at ECN are introduced. Then the key technologies are introduced, and concepts using these technologies are discussed. A literature overview of systems for power generation with fuel cells in combination with CO 2 capture is presented. Then a novel concept is introduced. This concept uses a water gas shift membrane reactor to convert the CO and H 2 in the SOFC anode off-gas to gain a CO 2 rich stream, which can be used for sequestration without elaborate treatment. Several implementation schemes of the technique are discussed such as atmospheric systems and hybrid SOFC-GT systems

  1. Equilibrium Solubility of CO2 in Alkanolamines

    DEFF Research Database (Denmark)

    Waseem Arshad, Muhammad; Fosbøl, Philip Loldrup; von Solms, Nicolas

    2014-01-01

    Equilibrium solubility of CO2 were measured in aqueous solutions of Monoethanolamine (MEA) and N,N-diethylethanolamine(DEEA). Equilibrium cells are generally used for these measurements. In this study, the equilibrium data were measured from the calorimetry. For this purpose a reaction calorimeter...... (model CPA 122 from ChemiSens AB, Sweden) was used. The advantage of this method is being the measurement of both heats of absorption and equilibrium solubility data of CO2 at the same time. The measurements were performed for 30 mass % MEA and 5M DEEA solutions as a function of CO2 loading at three...... different temperatures 40, 80 and 120 ºC. The measured 30 mass % MEA and 5M DEEA data were compared with the literature data obtained from different equilibrium cells which validated the use of calorimeters for equilibrium solubility measurements....

  2. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    International Nuclear Information System (INIS)

    Reid B. Grigg; Robert K. Svec; Zheng-Wen Zeng; Liu Yi; Baojun Bai

    2004-01-01

    A three-year contract for the project, DOE Contract No. DE-FG26-01BC15364, ''Improving CO 2 Efficiency for Recovering Oil in Heterogeneous Reservoirs'', was started on September 28, 2001. This project examines three major areas in which CO 2 flooding can be improved: fluid and matrix interactions, conformance control/sweep efficiency, and reservoir simulation for improved oil recovery. The project has received a one-year, no-cost extension to September 27, 2005. During this extra time additional deliverables will be (1) the version of MASTER that has been debugged and a foam option added for CO 2 mobility control and (2) adsorption/desorption data on pure component minerals common in reservoir rock that will be used to improve predictions of chemical loss to adsorption in reservoirs. This report discusses the activity during the six-month period covering October 1, 2003 through March 31, 2004 that comprises the first and second fiscal quarters of the project's third year. During this period of the project several areas have advanced: reservoir fluid/rock interactions and their relationships to changing injectivity, and surfactant adsorption on quarried core and pure component granules, foam stability, and high flow rate effects. Presentations and papers included: a papers covered in a previous report was presented at the fall SPE ATCE in Denver in October 2003, a presentation at the Southwest ACS meeting in Oklahoma City, presentation on CO 2 flood basic behavior at the Midland Annual CO 2 Conference December 2003; two papers prepared for the biannual SPE/DOE Symposium on IOR, Tulsa, April 2004; one paper accepted for the fall 2004 SPE ATCE in Houston; and a paper submitted to an international journal Journal of Colloid and Interface Science which is being revised after peer review

  3. Spectroscopic technique for measuring atmospheric CO2

    International Nuclear Information System (INIS)

    Stokes, G.M.; Stokes, R.A.

    1979-01-01

    As part of a continuing effort to identify areas in which astronomical techniques and data may be profitably applied to atmospheric problems, both new and archival solar spectra have been collected to prepare for an analysis of their use for studying the changes of the atmospheric CO 2 burden. This analysis has resulted in the initiation of an observing program using the Fourier Transform Spectrometer (FTS) of the McMath Solar Telescope at Kitt Peak National Observatory (KPNO). This program is generating spectra, the quality of which should not only aid the archival CO 2 study but also lead to analyses of other trace gases

  4. 10 MW Supercritical CO2 Turbine Test

    Energy Technology Data Exchange (ETDEWEB)

    Turchi, Craig

    2014-01-29

    The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late

  5. 14CO2 fixation pattern of cyanobacteria

    International Nuclear Information System (INIS)

    Erdmann, N.; Schiewer, U.

    1985-01-01

    The 14 CO 2 fixation pattern of three cyanobacteria in the light and dark were studied. Two different chromatographic methods widely used for separating labelled photosynthetic intermediates were compared. After ethanolic extraction, a rather uniform fixation pattern reflecting mainly the β-carboxylation pathway is obtained for all 3 species. Of the intermediates, glucosylglycerol is specific and high citrulline and low malate contents are fairly specific to cyanobacteria. The composition of the 14 CO 2 fixation pattern is hardly affected by changes in temperature or light intensity, but it is severely affected by changes in the water potential of the medium. (author)

  6. Effects of climate factors and vegetation on the CO2 fluxes and δ13C from re-established grassland

    Science.gov (United States)

    Bezyk, Yaroslav; Dorodnikov, Maxim; Sówka, Izabela

    2017-11-01

    The relationship between stable carbon isotope composition (δ13C -CO2) of soil CO2 flux, vegetation cover and weather conditions was investigated in a short-term campaign at a temperate re-established grassland in Germany. During August-September 2016, we measured surface CO2 flux with a closed-chamber method at high and low soil moisture content (`wet', `dry'), with and without above ground vegetation (`planted', `clear-cut') and estimated the effects of treatments on respective δ13C -CO2 values. The concentration and stable carbon isotope composition of CO2 were determined using the gas chromatography and mass spectrometry analyses. The δ13C -CO2 of the soil fluxes decreased over sampling time for the `dry-warm' conditions and canopy manipulation. The ecosystem-derived δ13C -CO2 values (corrected for the atmospheric δ13C -CO2) which included predominately soil-and rhizosphere respiration were -26.2 ± 0.8‰ for the `dry-warm' conditions and decreased down to -28.1 ± 1.4‰ over a period of 28 days from late August to the end of September. The decrease coincided with the lowering of CO2 flux and could be attributed to changes in plant physiological processes at the end of the vegetation season. Though the removal of shoots did not significantly affect the δ13C -CO2 values as compared with the control, the pattern of further δ13C -CO2 decrease (down to -28.8 ± 0.8‰) supported the role of living vegetation in a contribution of 13C-enriched CO2 to the ecosystem respiration.

  7. CO2 deficit in temperate forest soils receiving high atmospheric N-deposition.

    Science.gov (United States)

    Fleischer, Siegfried

    2003-02-01

    Evidence is provided for an internal CO2 sink in forest soils, that may have a potential impact on the global CO2-budget. Lowered CO2 fraction in the soil atmosphere, and thus lowered CO2 release to the aboveground atmosphere, is indicated in high N-deposition areas. Also at forest edges, especially of spruce forest, where additional N-deposition has occurred, the soil CO2 is lowered, and the gradient increases into the closed forest. Over the last three decades the capacity of the forest soil to maintain the internal sink process has been limited to a cumulative supply of approximately 1000 and 1500 kg N ha(-1). Beyond this limit the internal soil CO2 sink becomes an additional CO2 source, together with nitrogen leaching. This stage of "nitrogen saturation" is still uncommon in closed forests in southern Scandinavia, however, it occurs in exposed forest edges which receive high atmospheric N-deposition. The soil CO2 gradient, which originally increases from the edge towards the closed forest, becomes reversed.

  8. Transport and partitioning of CO2 fixed by root nodules of ureide and amide producing legumes

    International Nuclear Information System (INIS)

    Vance, C.P.; Boylan, K.L.M.; Maxwell, C.A.; Heichel, G.H.; Hardman, L.L.

    1985-01-01

    Nodulated and denodulated roots of adzuki bean (Vigna angularis), soybean (Glycine max), and alfalfa (Medicago sativa) were exposed to 14 CO 2 to investigate the contribution of nodule CO 2 fixation to assimilation and transport of fixed nitrogen. The distribution of radioactivity in xylem sap and partitioning of carbon fixed by nodules to the whole plant were measured. Radioactivity in the xylem sap of nodulated soybean and adzuki bean was located primarily (70 to 87%) in the acid fraction while the basic (amino acid) fraction contained 10 to 22%. In contrast radioactivity in the xylem sap of nodulated alfalfa was primarily in amino acids with about 20% in organic acids. Total ureide concentration was 8.1, 4.7, and 0.0 micromoles per milliliter xylem sap for soybean, adzuki bean, and alfalfa, respectively. While the major nitrogen transport products in soybeans and adzuki beans are ureides, this class of metabolites contained less than 20% of the the total radioactivity. When nodules of plants were removed, radioactivity in xylem sap decreased by 90% or more. Pulse-chase experiments indicated that CO 2 fixed by nodules was rapidly transported to shoots and incorporated into acid stable constituents. The data are consistent with a role for nodule CO 2 fixation providing carbon for the assimilation and transport of fixed nitrogen in amide-based legumes. In contrast, CO 2 fixation by nodules of ureide transporting legumes appears to contribute little to assimilation and transport of fixed nitrogen. 19 references, 2 figures, 5 tables

  9. Amelioration of boron toxicity in sweet pepper as affected by calcium management under an elevated CO2 concentration.

    Science.gov (United States)

    Piñero, María Carmen; Pérez-Jiménez, Margarita; López-Marín, Josefa; Del Amor, Francisco M

    2017-04-01

    We investigated B tolerance in sweet pepper plants (Capsicum annuun L.) under an elevated CO 2 concentration, combined with the application of calcium as a nutrient management amelioration technique. The data show that high B affected the roots more than the aerial parts, since there was an increase in the shoot/root ratio, when plants were grown with high B levels; however, the impact was lessened when the plants were grown at elevated CO 2 , since the root FW reduction caused by excess B was less marked at the high CO 2 concentration (30.9% less). Additionally, the high B concentration affected the membrane permeability of roots, which increased from 39 to 54% at ambient CO 2 concentration, and from 38 to 51% at elevated CO 2 concentration, producing a cation imbalance in plants, which was differentially affected by the CO 2 supply. The Ca surplus in the nutrient solution reduced the nutritional imbalance in sweet pepper plants produced by the high B concentration, at both CO 2 concentrations. The medium B concentration treatment (toxic according to the literature) did not result in any toxic effect. Hence, there is a need to review the literature on critical and toxic B levels taking into account increases in atmospheric CO 2 .

  10. Effect of elevated atmospheric CO2 concentration on growth and leaf litter decomposition of Quercus acutissima and Fraxinus rhynchophylla.

    Directory of Open Access Journals (Sweden)

    Sangsub Cha

    Full Text Available The atmospheric carbon dioxide (CO2 level is expected to increase substantially, which may change the global climate and carbon dynamics in ecosystems. We examined the effects of an elevated atmospheric CO2 level on the growth of Quercus acutissima and Fraxinus rhynchophylla seedlings. We investigated changes in the chemical composition of leaf litter, as well as litter decomposition. Q. acutissima and F. rhynchophylla did not show differences in dry weight between ambient CO2 and enriched CO2 treatments, but they exhibited different patterns of carbon allocation, namely, lower shoot/root ratio (S/R and decreased specific leaf area (SLA under CO2-enriched conditions. The elevated CO2 concentration significantly reduced the nitrogen concentration in leaf litter while increasing lignin concentrations and carbon/nitrogen (C/N and lignin/N ratios. The microbial biomass associated with decomposing Q. acutissima leaf litter was suppressed in CO2 enrichment chambers, while that of F. rhynchophylla was not. The leaf litter of Q. acutissima from the CO2-enriched chambers, in contrast with F. rhynchophylla, contained much lower nutrient concentrations than that of the litter in the ambient air chambers. Consequently, poorer litter quality suppressed decomposition.

  11. Effect of elevated atmospheric CO2 concentration on growth and leaf litter decomposition of Quercus acutissima and Fraxinus rhynchophylla.

    Science.gov (United States)

    Cha, Sangsub; Chae, Hee-Myung; Lee, Sang-Hoon; Shim, Jae-Kuk

    2017-01-01

    The atmospheric carbon dioxide (CO2) level is expected to increase substantially, which may change the global climate and carbon dynamics in ecosystems. We examined the effects of an elevated atmospheric CO2 level on the growth of Quercus acutissima and Fraxinus rhynchophylla seedlings. We investigated changes in the chemical composition of leaf litter, as well as litter decomposition. Q. acutissima and F. rhynchophylla did not show differences in dry weight between ambient CO2 and enriched CO2 treatments, but they exhibited different patterns of carbon allocation, namely, lower shoot/root ratio (S/R) and decreased specific leaf area (SLA) under CO2-enriched conditions. The elevated CO2 concentration significantly reduced the nitrogen concentration in leaf litter while increasing lignin concentrations and carbon/nitrogen (C/N) and lignin/N ratios. The microbial biomass associated with decomposing Q. acutissima leaf litter was suppressed in CO2 enrichment chambers, while that of F. rhynchophylla was not. The leaf litter of Q. acutissima from the CO2-enriched chambers, in contrast with F. rhynchophylla, contained much lower nutrient concentrations than that of the litter in the ambient air chambers. Consequently, poorer litter quality suppressed decomposition.

  12. Heterotrophic fixation of CO2 in soil

    Czech Academy of Sciences Publication Activity Database

    Šantrůčková, Hana; Bird, M. I.; Elhottová, Dana; Novák, Jaroslav; Picek, T.; Šimek, Miloslav; Tykva, Richard

    2005-01-01

    Roč. 49, č. 2 (2005), s. 218-225 ISSN 0095-3628 R&D Projects: GA ČR(CZ) GA206/02/1036; GA AV ČR(CZ) IAA6066901 Institutional research plan: CEZ:AV0Z60660521 Keywords : heterotrophic fixation * CO2 * soil Subject RIV: EH - Ecology, Behaviour Impact factor: 2.674, year: 2005

  13. Managing CO2 emissions in Nigeria

    International Nuclear Information System (INIS)

    Obioh, I.B.; Oluwole, A.F.; Akeredolu, F.A.

    1994-01-01

    The energy resources in Nigeria are nearly equally divided between fossil fuels and biofuels. The increasing pressure on them, following expected increased population growth, may lead to substantial emissions of carbon into the atmosphere. Additionally agricultural and forestry management practices in vogue are those related to savannah burning and rotational bush fallow systems, which have been clearly implicated as important sources of CO 2 and trace gases. An integrated model for the prediction of future CO 2 emissions based on fossil fuels and biomass fuels requirements, rates of deforestation and other land-use indices is presented. This is further based on trends in population and economic growth up to the year 2025, with a base year in 1988. A coupled carbon cycle-climate model based on the contribution of CO 2 and other trace gases is established from the proportions of integrated global warming effects for a 20-year averaging time using the product of global warming potential (GWP) and total emissions. An energy-technology inventory approach to optimal resources management is used as a tool for establishing the future scope of reducing the CO 2 emissions through improved fossil fuel energy efficiencies. Scenarios for reduction based on gradual to swift shifts from biomass to fossil and renewable fuels are presented together with expected policy options required to effect them

  14. Detection of 14CO2 in radiotoxicology

    International Nuclear Information System (INIS)

    Simonnet, Francoise; Bocquet, Colette.

    1980-12-01

    14 CO 2 is detected in exhaled air by conversion to Ba 14 CO 3 which is then filtered, dried and weighed. The radioactivity is measured by liquid scintillation counting. The radioactivity is expressed in μCi per litre of exhaled air according to the ICRP recommendations. The detection threshold is well below the values indicated by the ICRP [fr

  15. Stereotactic CO2 laser therapy for hydrocephalus

    Science.gov (United States)

    Kozodoy-Pins, Rebecca L.; Harrington, James A.; Zazanis, George A.; Nosko, Michael G.; Lehman, Richard M.

    1994-05-01

    A new fiber-optic delivery system for CO2 radiation has been used to successfully treat non-communicating hydrocephalus. This system consists of a hollow sapphire waveguide employed in the lumen of a stereotactically-guided neuroendoscope. CO2 gas flows through the bore of the hollow waveguide, creating a path for the laser beam through the cerebrospinal fluid (CSF). This delivery system has the advantages of both visualization and guided CO2 laser radiation without the same 4.3 mm diameter scope. Several patients with hydrocephalus were treated with this new system. The laser was used to create a passage in the floor of the ventricle to allow the flow of CSF from the ventricles to the sub-arachnoid space. Initial postoperative results demonstrated a relief of the clinical symptoms. Long-term results will indicate if this type of therapy will be superior to the use of implanted silicone shunts. Since CO2 laser radiation at 10.6 micrometers is strongly absorbed by the water in tissue and CSF, damage to tissue surrounding the lesion with each laser pulse is limited. The accuracy and safety of this technique may prove it to be an advantageous therapy for obstructive hydrocephalus.

  16. Chilled ammonia process for CO2 capture

    DEFF Research Database (Denmark)

    Darde, Victor Camille Alfred; Thomsen, Kaj; van Well, Willy J. M

    2009-01-01

    The chilled ammonia process absorbs the CO2 at low temperature (2-10 degrees C). The heat of absorption of carbon dioxide by ammonia is significantly lower than for amines. In addition, degradation problems can be avoided and a high carbon dioxide capacity is achieved. Hence, this process shows...

  17. Chilled Ammonia Process for CO2 Capture

    DEFF Research Database (Denmark)

    Darde, Victor Camille Alfred; Thomsen, Kaj; Well, Willy J.M. van

    2010-01-01

    The chilled ammonia process absorbs the CO2 at low temperature (2–10°C). The heat of absorption of carbon dioxide by ammonia is significantly lower than for amines. In addition, degradation problems can be avoided and a high carbon dioxide capacity is achieved. Hence, this process shows good...

  18. The Idea of Global CO2 Trade

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard

    1998-01-01

    -effective control which can solve future global environmental problems. The gains from CO2 trade may give vital financial subsidies from the EU to Eastern Europe, for example, and it will probably not pay to cheat if quotas are renewed periodically by the UN. Cheating countries are then to be excluded from further...

  19. Climate change and CO2 emission reductions

    International Nuclear Information System (INIS)

    Ha Duong, M.; Campos, A.S.

    2007-04-01

    This paper presents the results of an opinion poll performed on a representative sample of 1000 persons about their sensitivity to climate change and to environment protection, their knowledge about technologies which are useful for environment protection, their opinion about geological CO 2 sequestration, and technologies to be developed to struggle against climate warming

  20. CO2 emissions of nuclear electricity generation

    International Nuclear Information System (INIS)

    Wissel, Steffen; Mayer-Spohn, Oliver; Fahl, Ulrich; Blesl, Markus; Voss, Alfred

    2008-01-01

    A survey of LCA studies on nuclear electricity generation revealed life cycle CO 2 emissions ranging between 3 g/kWhe to 60 g/kWhe and above. Firstly, this paper points out the discrepancies in studies by estimating the CO 2 emissions of nuclear power generation. Secondly, the paper sets out to provide critical review of future developments of the fuel cycle for light water reactors and illustrates the impact of uncertainties on the specific CO 2 emissions of nuclear electricity generation. Each step in the fuel cycle will be considered and with regard to the CO 2 emissions analysed. Thereby different assumptions and uncertainty levels are determined for the nuclear fuel cycle. With the impacts of low uranium ore grades for mining and milling as well as higher burn-up rates future fuel characteristics are considered. Sensitivity analyses are performed for all fuel processing steps, for different technical specifications of light water reactors as well as for further external frame conditions. (authors)

  1. CO2 effect on porous concrete

    Directory of Open Access Journals (Sweden)

    Sauman, Zdenek

    1974-09-01

    Full Text Available Not availableDebido a la acción del CO2 y de la humedad sobre un hormigón poroso, la tobermorita 11 A se descompone en vaterita, calcita y SÍO2 gel. A causa de la pseudomorfosis, la morfología de los cristales de la fase cementante no sufre cambios notables. La menor resistencia a la compresión se obtuvo después de 30 días de conservación en atmósferas de un 10 y un 30% de CO2. Después de un año de conservación, las resistencias no bajaron más de un 10%. En lo que respecta a la retracción de un hormigón poroso, la principal influencia fue la ejercida por la acción del CO2 y solamente en segundo lugar figura la acción ejercida por la humedad ambiente. Los hormigones porosos expuestos al aire (con su 0,03% de CO2 a h. r. de 50, 70 y 100% sufrieron al cabo de un año una expansión muy ligera.

  2. CO2 capture by Condensed Rotational Separation

    NARCIS (Netherlands)

    Benthum, van R.J.; Kemenade, van H.P.; Brouwers, J.J.H.; Golombok, M.

    2010-01-01

    Condensed Rotational Separation (CRS) technology is a patented method to upgrade gas mixtures. A novel application is thecapture of CO2 from coal-combustion fired power stations: Condensed Contaminant Centrifugal Separation in Coal Combustion(C5sep). CRS involves partial condensation of a gas

  3. CO2 contain of the electric heating

    International Nuclear Information System (INIS)

    Bacher, P.

    2008-02-01

    A recent announcement of the RTE and the ADEME on the CO 2 contain of the electric kW, refuting a 2005 study of EDF and ADEME, perturbed the public opinion and was presented as the proof that the nuclear has no part in the fight against the climatic change. The author aims to set things straight. (A.L.B.)

  4. Towards Verifying National CO2 Emissions

    Science.gov (United States)

    Fung, I. Y.; Wuerth, S. M.; Anderson, J. L.

    2017-12-01

    With the Paris Agreement, nations around the world have pledged their voluntary reductions in future CO2 emissions. Satellite observations of atmospheric CO2 have the potential to verify self-reported emission statistics around the globe. We present a carbon-weather data assimilation system, wherein raw weather observations together with satellite observations of the mixing ratio of column CO2 from the Orbiting Carbon Observatory-2 are assimilated every 6 hours into the NCAR carbon-climate model CAM5 coupled to the Ensemble Kalman Filter of DART. In an OSSE, we reduced the fossil fuel emissions from a country, and estimated the emissions innovations demanded by the atmospheric CO2 observations. The uncertainties in the innovation are analyzed with respect to the uncertainties in the meteorology to determine the significance of the result. The work follows from "On the use of incomplete historical data to infer the present state of the atmosphere" (Charney et al. 1969), which maps the path for continuous data assimilation for weather forecasting and the five decades of progress since.

  5. Ocean acidification: the other CO2 problem.

    Science.gov (United States)

    Doney, Scott C; Fabry, Victoria J; Feely, Richard A; Kleypas, Joan A

    2009-01-01

    Rising atmospheric carbon dioxide (CO2), primarily from human fossil fuel combustion, reduces ocean pH and causes wholesale shifts in seawater carbonate chemistry. The process of ocean acidification is well documented in field data, and the rate will accelerate over this century unless future CO2 emissions are curbed dramatically. Acidification alters seawater chemical speciation and biogeochemical cycles of many elements and compounds. One well-known effect is the lowering of calcium carbonate saturation states, which impacts shell-forming marine organisms from plankton to benthic molluscs, echinoderms, and corals. Many calcifying species exhibit reduced calcification and growth rates in laboratory experiments under high-CO2 conditions. Ocean acidification also causes an increase in carbon fixation rates in some photosynthetic organisms (both calcifying and noncalcifying). The potential for marine organisms to adapt to increasing CO2 and broader implications for ocean ecosystems are not well known; both are high priorities for future research. Although ocean pH has varied in the geological past, paleo-events may be only imperfect analogs to current conditions.

  6. The Idea of Global CO2 Trade

    DEFF Research Database (Denmark)

    Svendsen, Gert Tinggaard

    1999-01-01

    -effective control which can solve future global environmental problems. The economic gains from 'hot air' distributions of permits and CO2 trade make the system politically attractive to potential participants. For example, vital financial subsidies from the EU to Eastern Europe are to be expected. It will probably...

  7. Literatuuronderzoek CAM-fotosynthese en CO2-bemesting en CO2-bemesting bij bromelia's

    NARCIS (Netherlands)

    Marissen, A.; Warmenhoven, M.G.

    2004-01-01

    De ‘normale’ wijze van CO2-opname gebeurt bij de meeste planten overdag, wanneer er licht is om de opgenomen CO2 door middel van fotosynthese direct om te zetten in suikers. Hiervoor is het nodig dat de huidmondjes overdag open staan, ‘s nachts zijn huidmondjes meestal dicht. Via de huidmondjes gaat

  8. The Li–CO2 battery: a novel method for CO2 capture and utilization

    KAUST Repository

    Xu, Shaomao; Das, Shyamal K.; Archer, Lynden A.

    2013-01-01

    We report a novel primary Li-CO2 battery that consumes pure CO2 gas as its cathode. The battery exhibits a high discharge capacity of around 2500 mA h g-1 at moderate temperatures. At 100 °C the discharge capacity is close to 1000% higher than

  9. Rechargeable Al-CO2 Batteries for Reversible Utilization of CO2.

    Science.gov (United States)

    Ma, Wenqing; Liu, Xizheng; Li, Chao; Yin, Huiming; Xi, Wei; Liu, Ruirui; He, Guang; Zhao, Xian; Luo, Jun; Ding, Yi

    2018-05-21

    The excessive emission of CO 2 and the energy crisis are two major issues facing humanity. Thus, the electrochemical reduction of CO 2 and its utilization in metal-CO 2 batteries have attracted wide attention because the batteries can simultaneously accelerate CO 2 fixation/utilization and energy storage/release. Here, rechargeable Al-CO 2 batteries are proposed and realized, which use chemically stable Al as the anode. The batteries display small discharge/charge voltage gaps down to 0.091 V and high energy efficiencies up to 87.7%, indicating an efficient battery performance. Their chemical reaction mechanism to produce the performance is revealed to be 4Al + 9CO 2 ↔ 2Al 2 (CO 3 ) 3 + 3C, by which CO 2 is reversibly utilized. These batteries are envisaged to effectively and safely serve as a potential CO 2 fixation/utilization strategy with stable Al. © 2018 The Authors. Published by WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Sustained effects of atmospheric [CO2] and nitrogen availability on forest soil CO2 efflux

    Science.gov (United States)

    A. Christopher Oishi; Sari Palmroth; Kurt H. Johnsen; Heather R. McCarthy; Ram. Oren

    2014-01-01

    Soil CO2 efflux (Fsoil) is the largest source of carbon from forests and reflects primary productivity as well as how carbon is allocated within forest ecosystems. Through early stages of stand development, both elevated [CO2] and availability of soil nitrogen (N; sum of mineralization, deposition, and fixation) have been shown to increase gross primary productivity,...

  11. Well technologies for CO2 geological storage: CO2-resistant cement

    International Nuclear Information System (INIS)

    Barlet-Gouedard, V.; Rimmele, G.; Porcherie, O.; Goffe, B.

    2007-01-01

    Storing carbon dioxide (CO 2 ) underground is considered the most effective way for long-term safe and low-cost CO 2 sequestration. This recent application requires long-term well-bore integrity. A CO 2 leakage through the annulus may occur much more rapidly than geologic leakage through the formation rock, leading to economic loss, reduction of CO 2 storage efficiency, and potential compromise of the field for storage. The possibility of such leaks raises considerable concern about the long-term well-bore isolation and the durability of hydrated cement that is used to isolate the annulus across the producing/injection intervals in CO 2 -storage wells. We propose a new experimental procedure and methodology to study reactivity of CO 2 -Water-Cement systems in simulating the interaction of the set cement with injected supercritical CO 2 under downhole conditions. The conditions of experiments are 90 deg. C under 280 bars. The evolution of mechanical, physical and chemical properties of Portland cement with time is studied up to 6 months. The results are compared to equivalent studies on a new CO 2 -resistant material; the comparison shows significant promise for this new material. (authors)

  12. Uncertainties in the CO2 buget associated to boundary layer dynamics and CO2-advection

    NARCIS (Netherlands)

    Kaikkonen, J.P.; Pino, D.; Vilà-Guerau de Arellano, J.

    2012-01-01

    The relationship between boundary layer dynamics and carbon dioxide (CO2) budget in the convective boundary layer (CBL) is investigated by using mixed-layer theory. We derive a new set of analytical relations to quantify the uncertainties on the estimation of the bulk CO2 mixing ratio and the

  13. Surface Ocean CO2 Atlas Database Version 5 (SOCATv5) (NCEI Accession 0163180)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Surface Ocean CO2 Atlas (SOCAT, www.socat.info) is a synthesis activity by the international marine carbon research community and has more than 100 contributors...

  14. CO2 reduction strategies for the Czech Republic

    International Nuclear Information System (INIS)

    De Kruijk, H.; Van den Broek, M.A.; Van Harmelen, T.; Van Oostvoorn, F.; Maly, M.

    1994-08-01

    Reduction of CO 2 emissions now has high priority on the international political agenda. The UN Convention on Climate Change provides countries the option for fulfilling the CO 2 reduction obligations individually or jointly. But before identifying opportunities, a reference path or scenario is needed to indicate how emissions will vary without joint implementation of projects or policies. This paper looks at the situation in the Czech Republic. First objective of the study concerns collecting information on CO 2 emissions in the Czech Republic, a reference scenario for CO 2 developments, and the reduction scope till the year 2015. Second objective is development of CEC energy/environmental model EFOM-ENV (Energy Flow and Optimization Model - ENVironment) for the Czech Republic. In the new orientation towards a market economy it is important to start preparing policy recommendations for energy and environmental needs based on the least cost approach. Presently the energy/environmental model EFOM-ENV is used for this type of studies by CEC, Directorate-General 12, and research institutes in almost all EC countries. It showed usefulness in EC countries for developing integrated energy /environmental strategies. Furthermore, based on its experience with this type of studies, the Netherlands Energy Research Foundation has the last years developed a GAMS PC-version of EFOM-ENV, very flexible and efficient to use. Increasing international cooperation in areas of energy and environmental policies requires a common analytical approach. Particularly for preparing harmonized emission control policies in Europe the use of the EC model EFOM-ENV for all Central European countries can provide comparable and useful insight in the relation between energy use and emissions in Central Europe. In fact similar studies have been and will be conducted for the Slovak Republic, Hungary, Bulgaria, other Central European countries. 4 figs., 5 tabs., 6 refs

  15. Development of Novel CO2 Adsorbents for Capture of CO2 from Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Fauth, D.J.; Filburn, T.P. (University of Hartford, West Hartford, CT); Gray, M.L.; Hedges, S.W.; Hoffman, J.; Pennline, H.W.; Filburn, T.

    2007-06-01

    Capturing CO2 emissions generated from fossil fuel-based power plants has received widespread attention and is considered a vital course of action for CO2 emission abatement. Efforts are underway at the Department of Energy’s National Energy Technology Laboratory to develop viable energy technologies enabling the CO2 capture from large stationary point sources. Solid, immobilized amine sorbents (IAS) formulated by impregnation of liquid amines within porous substrates are reactive towards CO2 and offer an alternative means for cyclic capture of CO2 eliminating, to some degree, inadequacies related to chemical absorption by aqueous alkanolamine solutions. This paper describes synthesis, characterization, and CO2 adsorption properties for IAS materials previously tested to bind and release CO2 and water vapor in a closed loop life support system. Tetraethylenepentamine (TEPA), acrylonitrile-modified tetraethylenepentamine (TEPAN), and a single formulation consisting of TEPAN and N, N’-bis(2-hydroxyethyl)ethylenediamine (BED) were individually supported on a poly (methyl methacrylate) (PMMA) substrate and examined. CO2 adsorption profiles leading to reversible CO2 adsorption capacities were obtained using thermogravimetry. Under 10% CO2 in nitrogen at 25°C and 1 atm, TEPA supported on PMMA over 60 minutes adsorbed ~3.2 mmol/g{sorbent} whereas, TEPAN supported on PMMA along with TEPAN and BED supported on PMMA adsorbed ~1.7 mmol/g{sorbent} and ~2.3 mmol/g{sorbent} respectively. Cyclic experiments with a 1:1 weight ratio of TEPAN and BED supported on poly (methyl methacrylate) beads utilizing a fixed-bed flow system with 9% CO2, 3.5% O2, nitrogen balance with trace gas constituents were studied. CO2 adsorption capacity was ~ 3 mmols CO2/g{sorbent} at 40°C and 1.4 atm. No beneficial effect on IAS performance was found using a moisture-laden flue gas mixture. Tests with 750 ppmv NO in a humidified gas stream revealed negligible NO sorption onto the IAS. A high SO2

  16. CO2 capture by ionic liquids - an answer to anthropogenic CO2 emissions?

    Science.gov (United States)

    Sanglard, Pauline; Vorlet, Olivier; Marti, Roger; Naef, Olivier; Vanoli, Ennio

    2013-01-01

    Ionic liquids (ILs) are efficient solvents for the selective removal of CO2 from flue gas. Conventional, offthe-shelf ILs are limited in use to physisorption, which restricts their absorption capacity. After adding a chemical functionality like amines or alcohols, absorption of CO2 occurs mainly by chemisorption. This greatly enhances CO2 absorption and makes ILs suitable for potential industrial applications. By carefully choosing the anion and the cation of the IL, equimolar absorption of CO2 is possible. This paper reviews the current state of the art of CO2 capture by ILs and presents the current research in this field performed at the ChemTech Institute of the Ecole d'Ingénieurs et d'Architectes de Fribourg.

  17. The Li–CO2 battery: a novel method for CO2 capture and utilization

    KAUST Repository

    Xu, Shaomao

    2013-01-01

    We report a novel primary Li-CO2 battery that consumes pure CO2 gas as its cathode. The battery exhibits a high discharge capacity of around 2500 mA h g-1 at moderate temperatures. At 100 °C the discharge capacity is close to 1000% higher than that at 40 °C, and the temperature dependence is significantly weaker for higher surface area carbon cathodes. Ex-situ FTIR and XRD analyses convincingly show that lithium carbonate (Li2CO3) is the main component of the discharge product. The feasibility of similar primary metal-CO2 batteries based on earth abundant metal anodes, such as Al and Mg, is demonstrated. The metal-CO2 battery platform provides a novel approach for simultaneous capturing of CO2 emissions and producing electrical energy. © 2013 The Royal Society of Chemistry.

  18. City density and CO_2 efficiency

    International Nuclear Information System (INIS)

    Gudipudi, Ramana; Fluschnik, Till; Ros, Anselmo García Cantú; Walther, Carsten; Kropp, Jürgen P.

    2016-01-01

    Cities play a vital role in the global climate change mitigation agenda. City population density is one of the key factors that influence urban energy consumption and the subsequent GHG emissions. However, previous research on the relationship between population density and GHG emissions led to contradictory results due to urban/rural definition conundrum and the varying methodologies for estimating GHG emissions. This work addresses these ambiguities by employing the City Clustering Algorithm (CCA) and utilizing the gridded CO_2 emissions data. Our results, derived from the analysis of all inhabited areas in the US, show a sub-linear relationship between population density and the total emissions (i.e. the sum of on-road and building emissions) on a per capita basis. Accordingly, we find that doubling the population density would entail a reduction in the total CO_2 emissions in buildings and on-road sectors typically by at least 42%. Moreover, we find that population density exerts a higher influence on on-road emissions than buildings emissions. From an energy consumption point of view, our results suggest that on-going urban sprawl will lead to an increase in on-road energy consumption in cities and therefore stresses the importance of developing adequate local policy measures to limit urban sprawl. - Highlights: •We use gridded population, land use and CO_2 emissions data. •We attribute building and on-road sectoral emissions to populated settlements. •We apply CCA to identify unique city extents and population densities. •Doubling the population density increases CO_2 efficiency typically by 42%. •Population density has more influence on-road CO_2 efficiency than buildings sector.

  19. Imaging volcanic CO2 and SO2

    Science.gov (United States)

    Gabrieli, A.; Wright, R.; Lucey, P. G.; Porter, J. N.

    2017-12-01

    Detecting and quantifying volcanic carbon dioxide (CO2) and sulfur dioxide (SO2) emissions is of relevance to volcanologists. Changes in the amount and composition of gases that volcanoes emit are related to subsurface magma movements and the probability of eruptions. Volcanic gases and related acidic aerosols are also an important atmospheric pollution source that create environmental health hazards for people, animals, plants, and infrastructures. For these reasons, it is important to measure emissions from volcanic plumes during both day and night. We present image measurements of the volcanic plume at Kīlauea volcano, HI, and flux derivation, using a newly developed 8-14 um hyperspectral imaging spectrometer, the Thermal Hyperspectral Imager (THI). THI is capable of acquiring images of the scene it views from which spectra can be derived from each pixel. Each spectrum contains 50 wavelength samples between 8 and 14 um where CO2 and SO2 volcanic gases have diagnostic absorption/emission features respectively at 8.6 and 14 um. Plume radiance measurements were carried out both during the day and the night by using both the lava lake in the Halema'uma'u crater as a hot source and the sky as a cold background to detect respectively the spectral signatures of volcanic CO2 and SO2 gases. CO2 and SO2 path-concentrations were then obtained from the spectral radiance measurements using a new Partial Least Squares Regression (PLSR)-based inversion algorithm, which was developed as part of this project. Volcanic emission fluxes were determined by combining the path measurements with wind observations, derived directly from the images. Several hours long time-series of volcanic emission fluxes will be presented and the SO2 conversion rates into aerosols will be discussed. The new imaging and inversion technique, discussed here, are novel allowing for continuous CO2 and SO2 plume mapping during both day and night.

  20. CO2 Orbital Trends in Comets

    Science.gov (United States)

    Kelley, Michael; Feaga, Lori; Bodewits, Dennis; McKay, Adam; Snodgrass, Colin; Wooden, Diane

    2014-12-01

    Spacecraft missions to comets return a treasure trove of details of their targets, e.g., the Rosetta mission to comet 67P/Churyumov-Gerasimenko, the Deep Impact experiment at comet 9P/Tempel 1, or even the flyby of C/2013 A1 (Siding Spring) at Mars. Yet, missions are rare, the diversity of comets is large, few comets are easily accessible, and comet flybys essentially return snapshots of their target nuclei. Thus, telescopic observations are necessary to place the mission data within the context of each comet's long-term behavior, and to further connect mission results to the comet population as a whole. We propose a large Cycle 11 project to study the long-term activity of past and potential future mission targets, and select bright Oort cloud comets to infer comet nucleus properties, which would otherwise require flyby missions. In the classical comet model, cometary mass loss is driven by the sublimation of water ice. However, recent discoveries suggest that the more volatile CO and CO2 ices are the likely drivers of some comet active regions. Surprisingly, CO2 drove most of the activity of comet Hartley 2 at only 1 AU from the Sun where vigorous water ice sublimation would be expected to dominate. Currently, little is known about the role of CO2 in comet activity because telluric absorptions prohibit monitoring from the ground. In our Cycle 11 project, we will study the CO2 activity of our targets through IRAC photometry. In conjunction with prior observations of CO2 and CO, as well as future data sets (JWST) and ongoing Earth-based projects led by members of our team, we will investigate both long-term activity trends in our target comets, with a particular goal to ascertain the connections between each comet's coma and nucleus.

  1. Spring photosynthetic recovery of boreal Norway spruce under conditions of elevated [CO(2)] and air temperature.

    Science.gov (United States)

    Wallin, Göran; Hall, Marianne; Slaney, Michelle; Räntfors, Mats; Medhurst, Jane; Linder, Sune

    2013-11-01

    Accumulated carbon uptake, apparent quantum yield (AQY) and light-saturated net CO2 assimilation (Asat) were used to assess the responses of photosynthesis to environmental conditions during spring for three consecutive years. Whole-tree chambers were used to expose 40-year-old field-grown Norway spruce trees in northern Sweden to an elevated atmospheric CO2 concentration, [CO2], of 700 μmol CO2 mol(-1) (CE) and an air temperature (T) between 2.8 and 5.6 °C above ambient T (TE), during summer and winter. Net shoot CO2 exchange (Anet) was measured continuously on 1-year-old shoots and was used to calculate the accumulated carbon uptake and daily Asat and AQY. The accumulated carbon uptake, from 1 March to 30 June, was stimulated by 33, 44 and 61% when trees were exposed to CE, TE, and CE and TE combined, respectively. Air temperature strongly influenced the timing and extent of photosynthetic recovery expressed as AQY and Asat during the spring. Under elevated T (TE), the recovery of AQY and Asat commenced ∼10 days earlier and the activity of these parameters was significantly higher throughout the recovery period. In the absence of frost events, the photosynthetic recovery period was less than a week. However, frost events during spring slowed recovery so that full recovery could take up to 60 days to complete. Elevated [CO2] stimulated AQY and Asat on average by ∼10 and ∼50%, respectively, throughout the recovery period, but had minimal or no effect on the onset and length of the photosynthetic recovery period during the spring. However, AQY, Asat and Anet all recovered at significantly higher T (average +2.2 °C) in TE than in TA, possibly caused by acclimation or by shorter days and lower light levels during the early part of the recovery in TE compared with TA. The results suggest that predicted future climate changes will cause prominent stimulation of photosynthetic CO2 uptake in boreal Norway spruce forest during spring, mainly caused by elevated T

  2. Sustained effects of atmospheric [CO2] and nitrogen availability on forest soil CO2 efflux.

    Science.gov (United States)

    Oishi, A Christopher; Palmroth, Sari; Johnsen, Kurt H; McCarthy, Heather R; Oren, Ram

    2014-04-01

    Soil CO2 efflux (Fsoil ) is the largest source of carbon from forests and reflects primary productivity as well as how carbon is allocated within forest ecosystems. Through early stages of stand development, both elevated [CO2] and availability of soil nitrogen (N; sum of mineralization, deposition, and fixation) have been shown to increase gross primary productivity, but the long-term effects of these factors on Fsoil are less clear. Expanding on previous studies at the Duke Free-Air CO2 Enrichment (FACE) site, we quantified the effects of elevated [CO2] and N fertilization on Fsoil using daily measurements from automated chambers over 10 years. Consistent with previous results, compared to ambient unfertilized plots, annual Fsoil increased under elevated [CO2] (ca. 17%) and decreased with N (ca. 21%). N fertilization under elevated [CO2] reduced Fsoil to values similar to untreated plots. Over the study period, base respiration rates increased with leaf productivity, but declined after productivity saturated. Despite treatment-induced differences in aboveground biomass, soil temperature and water content were similar among treatments. Interannually, low soil water content decreased annual Fsoil from potential values - estimated based on temperature alone assuming nonlimiting soil water content - by ca. 0.7% per 1.0% reduction in relative extractable water. This effect was only slightly ameliorated by elevated [CO2]. Variability in soil N availability among plots accounted for the spatial variability in Fsoil , showing a decrease of ca. 114 g C m(-2) yr(-1) per 1 g m(-2) increase in soil N availability, with consistently higher Fsoil in elevated [CO2] plots ca. 127 g C per 100 ppm [CO2] over the +200 ppm enrichment. Altogether, reflecting increased belowground carbon partitioning in response to greater plant nutritional needs, the effects of elevated [CO2] and N fertilization on Fsoil in this stand are sustained beyond the early stages of stand development and

  3. The role of metabolism in modulating CO2 fluxes in boreal lakes

    Science.gov (United States)

    Bogard, Matthew J.; del Giorgio, Paul A.

    2016-10-01

    Lake CO2 emissions are increasingly recognized as an important component of the global CO2 cycle, yet the origin of these emissions is not clear, as specific contributions from metabolism and in-lake cycling, versus external inputs, are not well defined. To assess the coupling of lake metabolism with CO2 concentrations and fluxes, we estimated steady state ratios of gross primary production to respiration (GPP:R) and rates of net ecosystem production (NEP = GPP-R) from surface water O2 dynamics (concentration and stable isotopes) in 187 boreal lakes spanning long environmental gradients. Our findings suggest that internal metabolism plays a dominant role in regulating CO2 fluxes in most lakes, but this pattern only emerges when examined at a resolution that accounts for the vastly differing relationships between lake metabolism and CO2 fluxes. Fluxes of CO2 exceeded those from NEP in over half the lakes, but unexpectedly, these effects were most common and typically largest in a subset ( 30% of total) of net autotrophic lakes that nevertheless emitted CO2. Equally surprising, we found no environmental characteristics that distinguished this category from the more common net heterotrophic, CO2 outgassing lakes. Excess CO2 fluxes relative to NEP were best predicted by catchment structure and hydrologic properties, and we infer from a combination of methods that both catchment inputs and internal anaerobic processes may have contributed this excess CO2. Together, our findings show that the link between lake metabolism and CO2 fluxes is often strong but can vary widely across the boreal biome, having important implications for catchment-wide C budgets.

  4. CO2 dispersion modelling over Paris region within the CO2-MEGAPARIS project

    Directory of Open Access Journals (Sweden)

    C. Lac

    2013-05-01

    Full Text Available Accurate simulation of the spatial and temporal variability of tracer mixing ratios over urban areas is a challenging and interesting task needed to be performed in order to utilise CO2 measurements in an atmospheric inverse framework and to better estimate regional CO2 fluxes. This study investigates the ability of a high-resolution model to simulate meteorological and CO2 fields around Paris agglomeration during the March field campaign of the CO2-MEGAPARIS project. The mesoscale atmospheric model Meso-NH, running at 2 km horizontal resolution, is coupled with the Town Energy Balance (TEB urban canopy scheme and with the Interactions between Soil, Biosphere and Atmosphere CO2-reactive (ISBA-A-gs surface scheme, allowing a full interaction of CO2 modelling between the surface and the atmosphere. Statistical scores show a good representation of the urban heat island (UHI with stronger urban–rural contrasts on temperature at night than during the day by up to 7 °C. Boundary layer heights (BLH have been evaluated on urban, suburban and rural sites during the campaign, and also on a suburban site over 1 yr. The diurnal cycles of the BLH are well captured, especially the onset time of the BLH increase and its growth rate in the morning, which are essential for tall tower CO2 observatories. The main discrepancy is a small negative bias over urban and suburban sites during nighttime (respectively 45 m and 5 m, leading to a few overestimations of nocturnal CO2 mixing ratios at suburban sites and a bias of +5 ppm. The diurnal CO2 cycle is generally well captured for all the sites. At the Eiffel tower, the observed spikes of CO2 maxima occur every morning exactly at the time at which the atmospheric boundary layer (ABL growth reaches the measurement height. At suburban ground stations, CO2 measurements exhibit maxima at the beginning and at the end of each night, when the ABL is fully contracted, with a strong spatio-temporal variability. A

  5. Elevated CO2 Increases Nitrogen Fixation at the Reproductive Phase Contributing to Various Yield Responses of Soybean Cultivars

    Directory of Open Access Journals (Sweden)

    Yansheng Li

    2017-09-01

    Full Text Available Nitrogen deficiency limits crop performance under elevated CO2 (eCO2, depending on the ability of plant N uptake. However, the dynamics and redistribution of N2 fixation, and fertilizer and soil N use in legumes under eCO2 have been little studied. Such an investigation is essential to improve the adaptability of legumes to climate change. We took advantage of genotype-specific responses of soybean to increased CO2 to test which N-uptake phenotypes are most strongly related to enhanced yield. Eight soybean cultivars were grown in open-top chambers with either 390 ppm (aCO2 or 550 ppm CO2 (eCO2. The plants were supplied with 100 mg N kg−1 soil as 15N-labeled calcium nitrate, and harvested at the initial seed-filling (R5 and full-mature (R8 stages. Increased yield in response to eCO2 correlated highly (r = 0.95 with an increase in symbiotically fixed N during the R5 to R8 stage. In contrast, eCO2 only led to small increases in the uptake of fertilizer-derived and soil-derived N during R5 to R8, and these increases did not correlate with enhanced yield. Elevated CO2 also decreased the proportion of seed N redistributed from shoot to seeds, and this decrease strongly correlated with increased yield. Moreover, the total N uptake was associated with increases in fixed-N per nodule in response to eCO2, but not with changes in nodule biomass, nodule density, or root length.

  6. Global CO2 fluxes estimated from GOSAT retrievals of total column CO2

    Directory of Open Access Journals (Sweden)

    S. Basu

    2013-09-01

    Full Text Available We present one of the first estimates of the global distribution of CO2 surface fluxes using total column CO2 measurements retrieved by the SRON-KIT RemoTeC algorithm from the Greenhouse gases Observing SATellite (GOSAT. We derive optimized fluxes from June 2009 to December 2010. We estimate fluxes from surface CO2 measurements to use as baselines for comparing GOSAT data-derived fluxes. Assimilating only GOSAT data, we can reproduce the observed CO2 time series at surface and TCCON sites in the tropics and the northern extra-tropics. In contrast, in the southern extra-tropics GOSAT XCO2 leads to enhanced seasonal cycle amplitudes compared to independent measurements, and we identify it as the result of a land–sea bias in our GOSAT XCO2 retrievals. A bias correction in the form of a global offset between GOSAT land and sea pixels in a joint inversion of satellite and surface measurements of CO2 yields plausible global flux estimates which are more tightly constrained than in an inversion using surface CO2 data alone. We show that assimilating the bias-corrected GOSAT data on top of surface CO2 data (a reduces the estimated global land sink of CO2, and (b shifts the terrestrial net uptake of carbon from the tropics to the extra-tropics. It is concluded that while GOSAT total column CO2 provide useful constraints for source–sink inversions, small spatiotemporal biases – beyond what can be detected using current validation techniques – have serious consequences for optimized fluxes, even aggregated over continental scales.

  7. Geochemical Interaction of Middle Bakken Reservoir Rock and CO2 during CO2-Based Fracturing

    Science.gov (United States)

    Nicot, J. P.; Lu, J.; Mickler, P. J.; Ribeiro, L. H.; Darvari, R.

    2015-12-01

    This study was conducted to investigate the effects of geochemical interactions when CO2 is used to create the fractures necessary to produce hydrocarbons from low-permeability Middle Bakken sandstone. The primary objectives are to: (1) identify and understand the geochemical reactions related to CO2-based fracturing, and (2) assess potential changes of reservoir property. Three autoclave experiments were conducted at reservoir conditions exposing middle Bakken core fragments to supercritical CO2 (sc-CO2) only and to CO2-saturated synthetic brine. Ion-milled core samples were examined before and after the reaction experiments using scanning electron microscope, which enabled us to image the reaction surface in extreme details and unambiguously identify mineral dissolution and precipitation. The most significant changes in the reacted rock samples exposed to the CO2-saturated brine is dissolution of the carbonate minerals, particularly calcite which displays severely corrosion. Dolomite grains were corroded to a lesser degree. Quartz and feldspars remained intact and some pyrite framboids underwent slight dissolution. Additionally, small amount of calcite precipitation took place as indicated by numerous small calcite crystals formed at the reaction surface and in the pores. The aqueous solution composition changes confirm these petrographic observations with increase in Ca and Mg and associated minor elements and very slight increase in Fe and sulfate. When exposed to sc-CO2 only, changes observed include etching of calcite grain surface and precipitation of salt crystals (halite and anhydrite) due to evaporation of residual pore water into the sc-CO2 phase. Dolomite and feldspars remained intact and pyrite grains were slightly altered. Mercury intrusion capillary pressure tests on reacted and unreacted samples shows an increase in porosity when an aqueous phase is present but no overall porosity change caused by sc-CO2. It also suggests an increase in permeability

  8. High CO2 triggers preferential root growth of Arabidopsis thaliana via two distinct systems under low pH and low N stresses.

    Science.gov (United States)

    Hachiya, Takushi; Sugiura, Daisuke; Kojima, Mikiko; Sato, Shigeru; Yanagisawa, Shuichi; Sakakibara, Hitoshi; Terashima, Ichiro; Noguchi, Ko

    2014-02-01

    Biomass allocation between shoots and roots is an important strategy used by plants to optimize growth in various environments. Root to shoot mass ratios typically increase in response to high CO2, a trend particularly evident under abiotic stress. We investigated this preferential root growth (PRG) in Arabidopsis thaliana plants cultivated under low pH/high CO2 or low nitrogen (N)/high CO2 conditions. Previous studies have suggested that changes in plant hormone, carbon (C) and N status may be related to PRG. We therefore examined the mechanisms underlying PRG by genetically modifying cytokinin (CK) levels, C and N status, and sugar signaling, performing sugar application experiments and determining primary metabolites, plant hormones and expression of related genes. Both low pH/high CO2 and low N/high CO2 stresses induced increases in lateral root (LR) number and led to high C/N ratios; however, under low pH/high CO2 conditions, large quantities of C were accumulated, whereas under low N/high CO2 conditions, N was severely depleted. Analyses of a CK-deficient mutant and a starchless mutant, in conjunction with sugar application experiments, revealed that these stresses induce PRG via different mechanisms. Metabolite and hormone profile analysis indicated that under low pH/high CO2 conditions, excess C accumulation may enhance LR number through the dual actions of increased auxin and decreased CKs.

  9. Atmospheric verification of anthropogenic CO2 emission trends

    Science.gov (United States)

    Francey, Roger J.; Trudinger, Cathy M.; van der Schoot, Marcel; Law, Rachel M.; Krummel, Paul B.; Langenfelds, Ray L.; Paul Steele, L.; Allison, Colin E.; Stavert, Ann R.; Andres, Robert J.; Rödenbeck, Christian

    2013-05-01

    International efforts to limit global warming and ocean acidification aim to slow the growth of atmospheric CO2, guided primarily by national and industry estimates of production and consumption of fossil fuels. Atmospheric verification of emissions is vital but present global inversion methods are inadequate for this purpose. We demonstrate a clear response in atmospheric CO2 coinciding with a sharp 2010 increase in Asian emissions but show persisting slowing mean CO2 growth from 2002/03. Growth and inter-hemispheric concentration difference during the onset and recovery of the Global Financial Crisis support a previous speculation that the reported 2000-2008 emissions surge is an artefact, most simply explained by a cumulative underestimation (~ 9PgC) of 1994-2007 emissions; in this case, post-2000 emissions would track mid-range of Intergovernmental Panel on Climate Change emission scenarios. An alternative explanation requires changes in the northern terrestrial land sink that offset anthropogenic emission changes. We suggest atmospheric methods to help resolve this ambiguity.

  10. Reducing CO2 emissions in Sierra Leone and Ghana

    International Nuclear Information System (INIS)

    Davidson, O.

    1991-01-01

    With soring population growth rates and minimal economic growth, the nations of Africa are afflicted with innumerable problems. Why then should Africa's developing countries worry about CO 2 emissions? First, because agricultural activities form the backbone of most African economies; thus, these nations may be particularly vulnerable to the negative impacts of climate change. Second, acting to reduce carbon emissions will bring about more efficient energy use. All of Africa could benefit from the improved use of energy. Finally, the accumulation of CO 2 in the atmosphere is a global problem with individual solutions; in order to reduce international emissions, all countries, including those in Africa, must contribute. Typical of many African countries, Ghana and Sierra Leone have among the lowest levels of energy demand per capita across the globe. primary energy demand per capita in these two West African nations equals about one quarter of the world's average and about one twentieth of the US average. This work summarizes the results of two long-term energy use and carbon emissions scenarios for Sierra Leone and Ghana. In the high emissions (HE) scenario for 2025, policy changes focused on galvanizing economic growth lead to significant increases in energy use and carbon emissions in Ghana and Sierra Leone between 1985 and 2025. In the low emissions (LE) scenario, the implementation of policies aimed specifically at curtailing CO 2 emissions significantly limits the increase in carbon in both nations by 2025

  11. Monitoring Exchange of CO2 - A KISS Workshop Report 2009

    Science.gov (United States)

    Miller, Charles; Wennberg, Paul

    2009-01-01

    The problem and context: Can top-down estimates of carbon dioxide (CO2) fluxes resolve the anthropogenic emissions of China, India, the United States, and the European Union with an accuracy of +/-10% or better?The workshop "Monitoring Exchange of Carbon Dioxide" was convened at the Keck Institute for Space Studies in Pasadena, California in February 2010 to address this question. The Workshop brought together an international, interdisciplinary group of 24 experts in carbon cycle science, remote sensing, emissions inventory estimation, and inverse modeling. The participants reviewed the potential of space-based and sub-orbital observational and modeling approaches to monitor anthropogenic CO2 emissions in the presence of much larger natural fluxes from the exchange of CO2 between the land, atmosphere, and ocean. This particular challenge was motivated in part by the NRC Report "Verifying Greenhouse Gas Emissions" [Pacala et al., 2010]. This workshop report includes several recommendations for improvements to observing strategies and modeling frameworks for optimal and cost-effective monitoring of carbon exchange

  12. Mastering the market of CO2 emission quotas

    International Nuclear Information System (INIS)

    2004-05-01

    On January 1, 2005, a system of trade of carbon dioxide emission quotas, also called 'market of tradable emission permits', will be implemented in the European Union. This system is one of the 3 flexibility mechanisms foreseen by the Kyoto protocol in order to reduce the global economic cost of the fight against climatic change. The aim of this seminar is to clarify the process of transfer of the European directive into French law. It comprises 8 presentations dealing with: the objectives of tradable emission quotas (greenhouse effect, Kyoto commitments, short and long term stakes); presentation of the European directive about the trade system of greenhouse gas emissions; transposition of the directive into French law (fields of application, sectors and facilities concerned, possible exemptions, first national plan of quotas allocation); voluntary emission abatement commitments by industrial companies member of the AERES; quotas recording and management, control of trades; companies strategy (investment for CO 2 abatement or purchase of quotas, impact on industries and competitiveness); experience feedback of emission quotas trading in foreign countries (international CO 2 market development); CO 2 emission quotas linked with cogeneration (emissions from cogeneration facilities, possible allocation, impact for cogeneration companies, approaches in other European countries in this domain); perspectives and conclusions. (J.S.)

  13. Economics of reducing CO2 emissions from China

    International Nuclear Information System (INIS)

    Wu Zhongxin

    1991-01-01

    Relative to the nations of the industrialized world, developing countries emit far lower levels of CO 2 per capita. In coming years, however, as the developing world experiences more rapid rates of economic and population growth, their carbon emissions per capita inevitably will rise. Therefore, developing countries should be encouraged both to adopt more advanced energy technologies in order to improve the efficiency of energy exploration, transportation, generation and end-use and to replace carbon-intensive fuels sources with less carbon-intensive sources (non-fossil fuels and renewable energy). By incorporating methods aimed at curtailing carbon emissions into their energy development strategies, developing nations can reduce the risks posed by higher CO 2 emissions. However, adopting more advanced energy technologies generally entails high costs. These higher prices serve as a particularly large obstacle for developing nations. In order to serve the common interest of protecting the global environment, international funds should be devoted to cover the high costs of reducing developing world CO 2 emissions

  14. National CO2 emissions trading in European perspective; Nationale CO2-emissiehandel in Europees perspectief

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2003-06-01

    This report is the reaction of the Social and economic council (SER) in the Netherlands to the request of the Dutch Ministry of Housing, Spatial Planning en Environment (VROM) to formulate an advice on the final report of the Committee CO2 Trade (a.k.a the Vogtlander Committee). This Committee has drafted a proposal for a CO2 emission trade system in the Netherlands. The SER has also taken into account the proposal of the European Committee on a guideline for CO2 emission trade in the European Union (EU)

  15. Solubility of krypton in liquid CO2

    International Nuclear Information System (INIS)

    Notz, K.J.; Meservey, A.B.

    1976-06-01

    The solubility of krypton in liquid CO 2 was measured experimentally over essentially the entire liquid range of CO 2 , from -53 to 29 0 C. A tracer technique using 85 Kr was employed, and equilibrated gas-liquid samples were analyzed in situ with a collimated counter. Dilute concentrations of krypton were used, and the data are expressed as a distribution ratio, Y/sub Kr//X/sub Kr/, the log of which is nearly linear with respect to temperature from the lowest temperature to about 20 0 C, above which the values fall off rapidly toward a value of unity at the critical temperature. The numerical values obtained for the distribution ratio increase from 1.44 at 29 0 C to 29.4 at -53 0 C

  16. Toxic emissions and devalued CO2-neutrality

    DEFF Research Database (Denmark)

    Czeskleba-Dupont, Rolf

    With reference to the paradigme shift regarding the formation of dioxins in municiplan solid waste incinerators experimental results are taken into account which lead to the suspicion that the same mechanism of de-novo-synthesis also applies to fireplace chimneys. This can explain the dioxin...... friendly effects of substituting wood burning for fossil fuels. With reference to Bent Sørensen's classical work on 'Renewable Energy' the assumption of CO2-neutrality regarding incineration is problematised when applied to plants with long rotation periods as trees. Registered CO2-emissions from wood...... burning are characterised together with particle and PAH emissions. The positive treatment of wood stove-technology in the Danish strategy for sustainable development (draft 2007) is critically evaluated and approaches to better regulation are identified....

  17. A centrifuge CO2 pellet cleaning system

    International Nuclear Information System (INIS)

    Foster, C.A.; Fisher, P.W.; Nelson, W.D.; Schechter, D.E.

    1993-01-01

    Centrifuge-based cryogenic pellet accelerator technology, originally developed at Oak Ridge National Laboratory (ORNL) for the purpose of refueling fusion reactors with high-speed pellets of frozen deuterium/tritium,is now being developed as a method of cleaning without the use of conventional solvents. In these applications large quantities of pellets made of frozen CO 2 or argon are accelerated in a high-speed rotor. The accelerated pellet stream is used to clean or etch surfaces. The advantage of this system is that the spent pellets and debris resulting from the cleaning process can be filtered leaving only the debris for disposal. This paper discusses the centrifuge CO 2 pellet cleaning system, the physics model of the pellet impacting the surface, the centrifuge apparatus, and some initial cleaning and etching tests

  18. Molecular simulations of CO2 at interfaces

    DEFF Research Database (Denmark)

    Silvestri, Alessandro

    trapping mechanisms that act over dierent time scales, where eectiveness is determined by phenomena that occur at the interfaces between CO2, pore uids and the pore surfaces. Solid theoretical understanding of the nanoscale interactions that result from the interplay of intermolecular and surface forces...... variety of conditions: pressure, temperature, pore solution salinity and various mineral surfaces. However, achieving representative subsurface conditions in experiments is challenging and reported data are aected by experimental uncertainties and sometimes are contradictory. Molecular modelling...... rock record and the formations are generally porous so their probable response to CO2 sequestration needs to be investigated. However, despite the large number of geologic sequestration publications on water{rock interactions over the last decade, studies on carbonate reservoirs remain scarce...

  19. Toxic emissions and devaluated CO2-neutrality

    DEFF Research Database (Denmark)

    Czeskleba-Dupont, Rolf

    Environmental, energy and climate policies need fresh reflections. In order to evaluate toxics reduction policies the Stockholm Convention on Persistent Organic Pollutants is mandatory. Denmark's function as lead country for dioxin research in the context of the OSPAR Convention is contrasted...... with a climate policy whose goals of CO2-reduction were made operational by green-wash. Arguments are given for the devaluation of CO2- neutrality in case of burning wood. Alternative practices as storing C in high quality wood products and/or leaving wood in the forest are recommended. A counter......-productive effect of dioxin formation in the cooling phase of wood burning appliances has been registered akin to de-novo-synthesis in municipal solid waste incinerators. Researchers, regulators and the public are, however, still preoccupied by notions of oven design and operation parameters, assuming that dioxin...

  20. Sustainable Process Networks for CO2 Conversion

    DEFF Research Database (Denmark)

    Frauzem, Rebecca; Kongpanna, P.; Pavarajam, V.

    According to various organizations, especially the Intergovernmental Panel on Climate Change, global warming is an ever-increasing threat to the environment and poses a problem if not addressed. As a result, efforts are being made across academic and industrial fields to find methods of reducing...... drawbacks to this geologic storage system: the CO2 is not eliminated, the implementation is limited due to natural phenomena, and the capturing methods are often expensive. Thus, it is desirable to develop an alternative strategy for reducing the CO2 emissions [2]. An additional process that reduces...... that are thermodynamically feasible, including the co-reactants, catalysts, operating conditions and reactions. Research has revealed that there are a variety of reactions that fulfill the aforementioned criteria. The products that are formed fall into categories: fuels, bulk chemicals and specialty chemicals. While fuels...

  1. Risk Assessment and Monitoring of Stored CO2 in Organic Rocks Under Non-Equilibrium Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Malhotra, Vivak

    2014-06-30

    The USA is embarking upon tackling the serious environmental challenges posed to the world by greenhouse gases, especially carbon dioxide (CO2). The dimension of the problem is daunting. In fact, according to the Energy Information Agency, nearly 6 billion metric tons of CO2 were produced in the USA in 2007 with coal-burning power plants contributing about 2 billion metric tons. To mitigate the concerns associated with CO2 emission, geological sequestration holds promise. Among the potential geological storage sites, unmineable coal seams and shale formations in particular show promise because of the probability of methane recovery while sequestering the CO2. However. the success of large-scale sequestration of CO2 in coal and shale would hinge on a thorough understanding of CO2's interactions with host reservoirs. An important parameter for successful storage of CO2 reservoirs would be whether the pressurized CO2 would remain invariant in coal and shale formations under reasonable internal and/or external perturbations. Recent research has brought to the fore the potential of induced seismicity, which may result in caprock compromise. Therefore, to evaluate the potential risks involved in sequestering CO2 in Illinois bituminous coal seams and shale, we studied: (i) the mechanical behavior of Murphysboro (Illinois) and Houchin Creek (Illinois) coals, (ii) thermodynamic behavior of Illinois bituminous coal at - 100oC ≤ T ≤ 300oC, (iii) how high pressure CO2 (up to 20.7 MPa) modifies the viscosity of the host, (iv) the rate of emission of CO2 from Illinois bituminous coal and shale cores if the cores, which were pressurized with high pressure (≤ 20.7 MPa) CO2, were exposed to an atmospheric pressure, simulating the development of leakage pathways, (v) whether there are any fractions of CO2 stored in these hosts which are resistance to emission by simply exposing the cores to atmospheric pressure, and (vi) how compressive shockwaves applied to the coal and

  2. Continuous CO2 extractor and methods

    Energy Technology Data Exchange (ETDEWEB)

    None listed

    2010-06-15

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  3. Continuous CO2 extractor and methods

    International Nuclear Information System (INIS)

    2010-01-01

    The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

  4. Throat gases against the CO2

    International Nuclear Information System (INIS)

    Michaut, C.

    2006-01-01

    The steel production needs carbon consumption and generates carbon dioxide, the main greenhouse gases. It represents about 6 % of the greenhouse gases emissions in the world. That is why the steel industry began last year a research program, Ideogaz, to reduce its CO 2 releases. The first results on the throat gases recovery seems very promising: it uses 25 % less of carbon. The author presents the program and the main technical aspects of the method. (A.L.B.)

  5. Panorama 2016 - Chemical recycling of CO2

    International Nuclear Information System (INIS)

    Forti, Laurent; Fosse, Florian

    2015-12-01

    The ongoing rise of atmospheric carbon dioxide concentration is a major environmental and societal concern. Among the potential solutions for reducing carbon emissions in the energy sector, the chemical recycling of CO 2 has received considerable attention. Conversion of carbon dioxide into other recoverable substances offers the benefit of reducing the carbon footprint of newly developed products and of shifting away from the use of fossil resources. Various methods to create a wide range of products are currently being studied. (authors)

  6. Influence of CO2 on the climate

    International Nuclear Information System (INIS)

    Junod, A.

    1989-01-01

    The earth's climate is subject to long and short term fluctuations. The recent ones are being caused by mankind. The most important result is the increase in the CO 2 -content of the atmosphere, caused by burning of fossil fuels. This leads to the so-called greenhouse effect. It is judged that the average temperature of the earth's surface will rise by 2 o C between the years 2030 and 2050

  7. CO2 capture takes its industrial turn

    International Nuclear Information System (INIS)

    Remoue, A.; Lutzky, A.

    2009-01-01

    The CO 2 capture and sequestration is entering the industrial era. The technologies are ready, the regulation is progressively put into action, the financing of demonstration facilities is unfreezing and companies are on the starting line from Canada to China, including the USA and Europe. The market takeoff is expected for 2015 but the competition is already hard between equipment manufacturers who wish to develop proprietary technologies. (J.S.)

  8. Aridity under conditions of increased CO2

    Science.gov (United States)

    Greve, Peter; Roderick, Micheal L.; Seneviratne, Sonia I.

    2016-04-01

    A string of recent of studies led to the wide-held assumption that aridity will increase under conditions of increasing atmospheric CO2 concentrations and associated global warming. Such results generally build upon analyses of changes in the 'aridity index' (the ratio of potential evaporation to precipitation) and can be described as a direct thermodynamic effect on atmospheric water demand due to increasing temperatures. However, there is widespread evidence that contradicts the 'warmer is more arid' interpretation, leading to the 'global aridity paradox' (Roderick et al. 2015, WRR). Here we provide a comprehensive assessment of modeled changes in a broad set of dryness metrics (primarily based on a range of measures of water availability) over a large range of realistic atmospheric CO2 concentrations. We use an ensemble of simulations from of state-of-the-art climate models to analyse both equilibrium climate experiments and transient historical simulations and future projections. Our results show that dryness is, under conditions of increasing atmospheric CO2 concentrations and related global warming, generally decreasing at global scales. At regional scales we do, however, identify areas that undergo changes towards drier conditions, located primarily in subtropical climate regions and the Amazon Basin. Nonetheless, the majority of regions, especially in tropical and mid- to northern high latitudes areas, display wetting conditions in a warming world. Our results contradict previous findings and highlight the need to comprehensively assess all aspects of changes in hydroclimatological conditions at the land surface. Roderick, M. L., P. Greve, and G. D. Farquhar (2015), On the assessment of aridity with changes in atmospheric CO2, Water Resour. Res., 51, 5450-5463

  9. Towards Overhauser DNP in supercritical CO(2).

    Science.gov (United States)

    van Meerten, S G J; Tayler, M C D; Kentgens, A P M; van Bentum, P J M

    2016-06-01

    Overhauser Dynamic Nuclear Polarization (ODNP) is a well known technique to improve NMR sensitivity in the liquid state, where the large polarization of an electron spin is transferred to a nucleus of interest by cross-relaxation. The efficiency of the Overhauser mechanism for dipolar interactions depends critically on fast local translational dynamics at the timescale of the inverse electron Larmor frequency. The maximum polarization enhancement that can be achieved for (1)H at high magnetic fields benefits from a low viscosity solvent. In this paper we investigate the option to use supercritical CO2 as a solvent for Overhauser DNP. We have investigated the diffusion constants and longitudinal nuclear relaxation rates of toluene in high pressure CO2. The change in (1)H T1 by addition of TEMPO radical was analyzed to determine the Overhauser cross-relaxation in such a mixture, and is compared with calculations based on the Force Free Hard Sphere (FFHS) model. By analyzing the relaxation data within this model we find translational correlation times in the range of 2-4ps, depending on temperature, pressure and toluene concentration. Such short correlation times may be instrumental for future Overhauser DNP applications at high magnetic fields, as are commonly used in NMR. Preliminary DNP experiments have been performed at 3.4T on high pressure superheated water and model systems such as toluene in high pressure CO2. Copyright © 2016 Elsevier Inc. All rights reserved.

  10. Development of longitudinally excited CO2 laser

    Science.gov (United States)

    Masroon, N. S.; Tanaka, M.; Tei, M.; Uno, K.; Tsuyama, M.; Nakano, H.

    2018-05-01

    Simple, compact, and affordable discharged-pumped CO2 laser controlled by a fast high voltage solid state switch has been developed. In this study, longitudinal excitation scheme has been adapted for simple configuration. In the longitudinal excitation scheme, the discharge is produced along the direction of the laser axis, and the electrodes are well separated with a small discharge cross-section. Triggered spark gap switch is usually used to switch out the high voltage because of simple and low cost. However, the triggered spark gap operates in the arc mode and suffer from recovery problem causing a short life time and low efficiency for high repetition rate operation. As a result, there is now considerable interest in replacing triggered spark gap switch with solid state switches. Solid state switches have significant advantages compared to triggered spark gap switch which include longer service lifetime, low cost and stable high trigger pulse. We have developed simple and low cost fast high voltage solid state switch that consists of series connected-MOSFETs. It has been installed to the longitudinally excited CO2 laser to realize the gap switch less operation. Characteristics of laser oscillation by varying the discharge length, charging voltage, capacitance and gas pressure have been evaluated. Longer discharge length produce high power of laser oscillation. Optimum charging voltage and gas pressure were existed for longitudinally excited CO2 laser.

  11. Martian Gullies: Formation by CO2 Fluidification

    Science.gov (United States)

    Cedillo-Flores, Y.; Durand-Manterola, H. J.

    2006-12-01

    Some of the geomorphological features in Mars are the gullies. Some theories developed tried explain its origin, either by liquid water, liquid carbon dioxide or flows of dry granular material. We made a comparative analysis of the Martian gullies with the terrestrial ones. We propose that the mechanism of formation of the gullies is as follows: In winter CO2 snow mixed with sand falls in the terrain. In spring the CO2 snow sublimate and gaseous CO2 make fluid the sand which flows like liquid eroding the terrain and forming the gullies. By experimental work with dry granular material, we simulated the development of the Martian gullies injecting air in the granular material. We present the characteristics of some terrestrial gullies forms at cold environment, sited at Nevado de Toluca Volcano near Toluca City, México. We compare them with Martian gullies choose from four different areas, to target goal recognize or to distinguish, (to identify) possible processes evolved in its formation. Also, we measured the lengths of those Martian gullies and the range was from 24 m to 1775 meters. Finally, we present results of our experimental work at laboratory with dry granular material.

  12. Seasonal climate change patterns due to cumulative CO2 emissions

    Science.gov (United States)

    Partanen, Antti-Ilari; Leduc, Martin; Damon Matthews, H.

    2017-07-01

    Cumulative CO2 emissions are near linearly related to both global and regional changes in annual-mean surface temperature. These relationships are known as the transient climate response to cumulative CO2 emissions (TCRE) and the regional TCRE (RTCRE), and have been shown to remain approximately constant over a wide range of cumulative emissions. Here, we assessed how well this relationship holds for seasonal patterns of temperature change, as well as for annual-mean and seasonal precipitation patterns. We analyzed an idealized scenario with CO2 concentration growing at an annual rate of 1% using data from 12 Earth system models from the Coupled Model Intercomparison Project Phase 5 (CMIP5). Seasonal RTCRE values for temperature varied considerably, with the highest seasonal variation evident in the Arctic, where RTCRE was about 5.5 °C per Tt C for boreal winter and about 2.0 °C per Tt C for boreal summer. Also the precipitation response in the Arctic during boreal winter was stronger than during other seasons. We found that emission-normalized seasonal patterns of temperature change were relatively robust with respect to time, though they were sub-linear with respect to emissions particularly near the Arctic. Moreover, RTCRE patterns for precipitation could not be quantified robustly due to the large internal variability of precipitation. Our results suggest that cumulative CO2 emissions are a useful metric to predict regional and seasonal changes in precipitation and temperature. This extension of the TCRE framework to seasonal and regional climate change is helpful for communicating the link between emissions and climate change to policy-makers and the general public, and is well-suited for impact studies that could make use of estimated regional-scale climate changes that are consistent with the carbon budgets associated with global temperature targets.

  13. Abatement of CO2 emissions in the European Union

    International Nuclear Information System (INIS)

    Lesourne, J.; Keppler, J.H.; Jaureguy-Naudin, Maite; Smeers, Yves; Bouttes, Jean-Paul; Trochet, Jean-Michel; Dassa, Francois; Neuhoff, Karsten

    2008-01-01

    This first monograph of the Ifri program on European Governance and Geopolitics of Energy is devoted to the control of carbon dioxide emissions within the European Union. Since it is almost unanimously accepted that Greenhouse Gas emissions constitute the main cause of the observed increase of the world average temperature, the system implemented by the European Union to limit and decrease the CO 2 emissions is a significant pillar of the EU energy policy, the two others being the acceptance by the Member States of long-term commitments (for instance on the future share of renewable energy sources in their energy balance sheet) and the establishment of an internal market for electricity and gas. Though simple in principle, the European Union Greenhouse Gas Emission Trading Scheme (EU ETS) is in fact rather complex, and only experts really understand its merits and its deficiencies. These deficiencies are real and will have to be corrected in the future for the system to be effective. At this moment, when the 2005-2007 trial phase of the EU ETS is ending, the monograph has the purpose to stimulate the discussion between experts and to enable all those interested in the topic to understand the issues and to take part in the public debates on the subject. The monograph contains five papers: - 'An Overview of the CO 2 Emission Control System in the European Union' by Jacques Lesourne and Maite Jaureguy-Naudin. - 'Description and Assessment of EU CO 2 Regulations' by Yves Smeers. - 'Assessment of EU CO 2 Regulations' by Jean-Paul Bouttes, Jean-Michel Trochet and Francois Dassa. - 'Investment in Low Carbon Technologies, Policies for the Power Sector' by Karsten Neuhoff. - 'Lessons Learned from the 2005-2007 Trial Phase of the EU Emission Trading System' by Jan Horst Keppler

  14. Root dynamics in an artificially constructed regenerating longleaf pine ecosystem are affected by atmospheric CO(2) enrichment.

    Science.gov (United States)

    Pritchard, S G.; Davis, M A.; Mitchell, R J.; Prior, S A.; Boykin, D L.; Rogers, H H.; Runion, G B.

    2001-08-01

    Differential responses to elevated atmospheric CO(2) concentration exhibited by different plant functional types may alter competition for above- and belowground resources in a higher CO(2) world. Because C allocation to roots is often favored over C allocation to shoots in plants grown with CO(2) enrichment, belowground function of forest ecosystems may change significantly. We established an outdoor facility to examine the effects of elevated CO(2) on root dynamics in artificially constructed communities of five early successional forest species: (1) a C(3) evergreen conifer (longleaf pine, Pinus palustris Mill.); (2) a C(4) monocotyledonous bunch grass (wiregrass, Aristida stricta Michx.); (3) a C(3) broadleaf tree (sand post oak, Quercus margaretta); (4) a C(3) perennial herbaceous legume (rattlebox, Crotalaria rotundifolia Walt. ex Gemel); and (5) an herbaceous C(3) dicotyledonous perennial (butterfly weed, Asclepias tuberosa L.). These species are common associates in early successional longleaf pine savannahs throughout the southeastern USA and represent species that differ in life-form, growth habit, physiology, and symbiotic relationships. A combination of minirhizotrons and soil coring was used to examine temporal and spatial rooting dynamics from October 1998 to October 1999. CO(2)-enriched plots exhibited 35% higher standing root crop length, 37% greater root length production per day, and 47% greater root length mortality per day. These variables, however, were enhanced by CO(2) enrichment only at the 10-30 cm depth. Relative root turnover (flux/standing crop) was unchanged by elevated CO(2). Sixteen months after planting, root biomass of pine was 62% higher in elevated compared to ambient CO(2) plots. Conversely, the combined biomass of rattlebox, wiregrass, and butterfly weed was 28% greater in ambient compared to high CO(2) plots. There was no difference in root biomass of oaks after 16 months of exposure to elevated CO(2). Using root and shoot

  15. 2007 CO2 emissions due to energy combustion in the world

    International Nuclear Information System (INIS)

    2010-01-01

    Worldwide energy combustion contributes to more than 95% of the global CO 2 emissions. According to the last International Energy Agency (IEA) results, these emissions have raised by 3.3% with respect to 2006 and by 38% with respect to 1990 with a total of about 29 Gt of CO 2 . After a new 8% boom in 2007, China's emissions have tripled since 1990 with a total exceeding 6 Gt of CO 2 . China has become the first CO 2 emitter in front of the USA. When compared to the number of inhabitants, China's emissions are comparable to the world average (4.4 t CO 2 /hab) but remain four times lower than the ones of the USA. (J.S.)

  16. The influence of using LPG device on the CO2 emissions from personal passenger cars

    Directory of Open Access Journals (Sweden)

    Viliam Carach

    2007-12-01

    Full Text Available Traffic, mostly the air and car traffic is the biggest producer of CO2 (51% at present. CO2 is one of the most important greenhouse gases with more than 50 % of emissions contributing to this major global ecological problem. A rising concetration of CO2 in the atmosphere leads to higher global temperatures. The main problem is the rise of CO2 emissions in most developed countries despite international undertakings accepted in 80´s. This is the main reason for finding solutions to reduce the amount of CO2 emissions in the traffic. One of many solutions is the use of LPG fuel. The purpose of this article is to quantify the efficiency of using LPG in personal passenger cars.

  17. CO2 uptake potential due to concrete carbonation: A case study

    Directory of Open Access Journals (Sweden)

    Edna Possan

    2017-06-01

    Full Text Available The cement manufacturing process accounts for about 5% CO2 (carbon dioxide released into the atmosphere. However, during its life cycle, concrete may capture CO2 through carbonation, in order to, partially, offset the impact of its production. Thus, this paper aims at studying the CO2 uptake potential of the Itaipu Dam due to concrete carbonation of such material. So, 155 cores were extracted from the concrete dam in different points to measure carbonation depth. In order to evaluate its influence on carbonation, the measurement of internal moisture distribution in concrete was also carried out. The results have shown that carbonation takes part of the whole dam area, indicating CO2 uptake potential. Up to the present moment, 13,384 tons of CO2 have been absorbed by concrete carbonation of the Itaipu Dam.

  18. Photosynthetic response to globally increasing CO2 of co-occurring temperate seagrass species

    DEFF Research Database (Denmark)

    Borum, Jens; Pedersen, Ole; Kotula, Lukasz

    2016-01-01

    Photosynthesis of most seagrass species seems to be limited by present concentrations of dissolved inorganic carbon (DIC). Therefore, the ongoing increase in atmospheric CO2 could enhance seagrass photosynthesis and internal O2 supply, and potentially change species competition through differential...... responses to increasing CO2 availability among species. We used short-term photosynthetic responses of nine seagrass species from the south-west of Australia to test species-specific responses to enhanced CO2 and changes in HCO3 -. Net photosynthesis of all species except Zostera polychlamys were limited...... at pre-industrial compared to saturating CO2 levels at light saturation, suggesting that enhanced CO2 availability will enhance seagrass performance. Seven out of the nine species were efficient HCO3 - users through acidification of diffusive boundary layers, production of extracellular carbonic...

  19. Tree and forest water use under elevated CO2 and temperature in Scandinavian boreal forest

    Science.gov (United States)

    Berg Hasper, Thomas; Wallin, Göran; Lamba, Shubhangi; Sigurdsson, Bjarni D.; Laudon, Hjalmar; Medhurst, Jane L.; Räntfors, Mats; Linder, Sune; Uddling, Johan

    2014-05-01

    According to experimental studies and models, rising atmospheric carbon dioxide concentration ([CO2]) and temperature have the potential to affect stomatal conductance and, consequently, tree and forest transpiration. This effect has in turn the capacity to influence the terrestrial energy and water balance, including affecting of the magnitude of river runoff. Furthermore, forest productivity is currently water-limited in southern Scandinavia and in a near future, under the projected climatic change, this limitation may become a reality in the central and northern parts of Scandinavia. In this study we examine the water-use responses in 12 40-year old native boreal Norway spruce (Picea abies (L.) Karst.) trees exposed to a factorial combination of two levels of [CO2] (ambient and doubled) and temperature (ambient and +2.8 °C in summer / +5.6 °C in winter), as well as of entire boreal forests to temporal variation in [CO2], temperature and precipitation over the past 50 years in central and northern Sweden. The controlled factorial CO2 and temperature whole-tree chamber experiment at Flakaliden study site demonstrated that Norway spruce trees lacked elevated [CO2]-induced water savings at guard cell, shoot, and tree levels in the years of measurements. Experimentally, elevated temperature did not result in increased shoot or tree water use as stomatal closure fully cancelled the effect of higher vapour pressure deficit in warmed air environment. Consistent with these results, large scale river runoff data and evapotranspiration estimates from large forested watersheds in central Sweden supported lack of elevated CO2-mediated water savings, and rather suggested that the increasing evapotranspiration trend found in this study was primarily linked to increasing precipitation, rising temperature and more efficient forest management. The results from the whole-tree chamber experiment and boreal forested watersheds have important implications for more accurate

  20. Stomatal responses to CO2 during a diel Crassulacean acid metabolism cycle in Kalanchoe daigremontiana and Kalanchoe pinnata.

    Science.gov (United States)

    von Caemmerer, Susanne; Griffiths, Howard

    2009-05-01

    To investigate the diurnal variation of stomatal sensitivity to CO2, stomatal response to a 30 min pulse of low CO2 was measured four times during a 24 h time-course in two Crassulacean acid metabolism (CAM) species Kalanchoe daigremontiana and Kalanchoe pinnata, which vary in the degree of succulence, and hence, expression and commitment to CAM. In both species, stomata opened in response to a reduction in pCO2 in the dark and in the latter half of the light period, and thus in CAM species, chloroplast photosynthesis is not required for the stomatal response to low pCO2. Stomata did not respond to a decreased pCO2 in K. daigremontiana in the light when stomata were closed, even when the supply of internal CO2 was experimentally reduced. We conclude that stomatal closure during phase III is not solely mediated by high internal pCO2, and suggest that in CAM species the diurnal variability in the responsiveness of stomata to pCO2 could be explained by hypothesizing the existence of a single CO2 sensor which interacts with other signalling pathways. When not perturbed by low pCO2, CO2 assimilation rate and stomatal conductance were correlated both in the light and in the dark in both species.

  1. Recycling CO 2 ? Computational Considerations of the Activation of CO 2 with Homogeneous Transition Metal Catalysts

    KAUST Repository

    Drees, Markus

    2012-08-10

    Faced with depleting fossil carbon sources, the search for alternative energy carriers and energy storage possibilities has become an important issue. Nature utilizes carbon dioxide as starting material for storing sun energy in plant hydrocarbons. A similar approach, storing energy from renewable sources in chemical bonds with CO 2 as starting material, may lead to partial recycling of CO 2 created by human industrial activities. Unfortunately, currently available routes for the transformation of CO 2 involve high temperatures and are often not selective. With the development of more sophisticated methods and better software, theoretical studies have become both increasingly widespread and useful. This concept article summarizes theoretical investigations of the current state of the feasibility of CO 2 activation with molecular transition metal catalysts, highlighting the most promising reactions of CO 2 with olefins to industrially relevant acrylic acid/acrylates, and the insertion of CO 2 into metal-element bonds, particularly for the synthesis of cyclic carbonates and polymers. Rapidly improving computational power and methods help to increase the importance and accuracy of calculations continuously and make computational chemistry a useful tool helping to solve some of the most important questions for the future. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. CO2 capture by gas hydrate crystallization: Application on the CO2-N2 mixture

    International Nuclear Information System (INIS)

    Bouchemoua, A.

    2012-01-01

    CO 2 capture and sequestration represent a major industrial and scientific challenge of this century. There are different methods of CO 2 separation and capture, such as solid adsorption, amines adsorption and cryogenic fractionation. Although these processes are well developed at industrial level, they are energy intensive. Hydrate formation method is a less energy intensive and has an interesting potential to separate carbon dioxide. Gas hydrates are Document crystalline compounds that consist of hydrogen bonded network of water molecules trapping a gas molecule. Gas hydrate formation is favored by high pressure and low temperature. This study was conducted as a part of the SECOHYA ANR Project. The objective is to study the thermodynamic and kinetic conditions of the process to capture CO 2 by gas hydrate crystallization. Firstly, we developed an experimental apparatus to carry out experiments to determine the thermodynamic and kinetic formation conditions of CO 2 -N 2 gas hydrate mixture in water as liquid phase. We showed that the operative pressure may be very important and the temperature very low. For the feasibility of the project, we used TBAB (Tetrabutylammonium Bromide) as thermodynamic additive in the liquid phase. The use of TBAB may reduce considerably the operative pressure. In the second part of this study, we presented a thermodynamic model, based on the van der Waals and Platteeuw model. This model allows the estimation of thermodynamic equilibrium conditions. Experimental equilibrium data of CO 2 -CH 4 and CO 2 -N 2 mixtures are presented and compared to theoretical results. (author)

  3. Intertidal oysters reach their physiological limit in a future high-CO2 world.

    Science.gov (United States)

    Scanes, Elliot; Parker, Laura M; O'Connor, Wayne A; Stapp, Laura S; Ross, Pauline M

    2017-03-01

    Sessile marine molluscs living in the intertidal zone experience periods of internal acidosis when exposed to air (emersion) during low tide. Relative to other marine organisms, molluscs have been identified as vulnerable to future ocean acidification; however, paradoxically it has also been shown that molluscs exposed to high CO 2 environments are more resilient compared with those molluscs naive to CO 2 exposure. Two competing hypotheses were tested using a novel experimental design incorporating tidal simulations to predict the future intertidal limit of oysters in a high-CO 2 world; either high-shore oysters will be more tolerant of elevated P CO 2 because of their regular acidosis, or elevated P CO 2  will cause high-shore oysters to reach their limit. Sydney rock oysters, Saccostrea glomerata , were collected from the high-intertidal and subtidal areas of the shore and exposed in an orthogonal design to either an intertidal or a subtidal treatment at ambient or elevated P CO 2 , and physiological variables were measured. The combined treatment of tidal emersion and elevated P CO 2  interacted synergistically to reduce the haemolymph pH (pH e ) of oysters, and increase the P CO 2  in the haemolymph ( P e,CO 2 ) and standard metabolic rate. Oysters in the intertidal treatment also had lower condition and growth. Oysters showed a high degree of plasticity, and little evidence was found that intertidal oysters were more resilient than subtidal oysters. It is concluded that in a high-CO 2 world the upper vertical limit of oyster distribution on the shore may be reduced. These results suggest that previous studies on intertidal organisms that lacked tidal simulations may have underestimated the effects of elevated P CO 2 . © 2017. Published by The Company of Biologists Ltd.

  4. Metabolic effects of Carbon Dioxide (CO 2 ) insufflation during ...

    African Journals Online (AJOL)

    Metabolic effects of Carbon Dioxide (CO 2 ) insufflation during laparoscopic surgery: changes in pH, arterial partial Pressure of Carbon Dioxide (PaCo 2 ) and End Tidal Carbon Dioxide (EtCO 2 ) ... Respiratory adjustments were done for EtCO2 levels above 60mmHg or SPO2 below 92% or adverse haemodynamic changes.

  5. Characterization of CO2 leakage into the freshwater body

    DEFF Research Database (Denmark)

    Singh, Ashok; Delfs, Jens Olaf; Shao, H.

    2013-01-01

    urrent research into CO2 capture and storage is dominated by improving the CO2 storage capacity. In this context, risk related to CO2 leakage is an important issue which may cause environmental problems, particularly when freshwater resources nearby are intruded by the CO2 plume. In this work...

  6. Reduction of CO2 emissions by influencing fuel prices

    International Nuclear Information System (INIS)

    Keller, M.; Zbinden, R.; Haan, P.; Gruetter, J.; Ott, W.

    2002-01-01

    The CO 2 law stipulates quantitative targets for CO 2 emissions (reductions of 10% by 2010 compared with 1990, 15% for heating fuels, 8% for motor fuels). For motor fuels, it is currently estimated that the target will be missed by about 15%, or 2 to 2.5 million tonnes of CO 2 . In order to reach the targets, therefore, all measures that can be taken to reduce emissions are to be checked out and, where sensible and possible, implemented too. The subject of this study is the preferential treatment of diesel, natural gas, liquefied gas and bio-fuels as far as taxation is concerned, with compensation of tax losses on the petrol side. Also, the possibilities for promoting energy-efficient cars are looked at. The reduction of the price for diesel (at least 25 Swiss cents when compensated for via the petrol price) is considered to be unsuitable for reaching the targets because, in the final analysis, fuel sales - the determining factor for the CO 2 emissions that are charged to Switzerland - will increase instead of decreasing. Also, reservations are expressed from the environmental point of view (increased NO x emissions and, in particular, emissions of particulate matter). The modified measure proposed (fixed difference between the prices for petrol and diesel of 25 Swiss cents, for example) is looked at less critically, because it does actually lead to a reduction of CO 2 , even if only a modest one (approx. 10% of the gap to be bridged). On the environmental side, the same reservations apply. Bonus-malus systems, on the other hand, permit a selective choice of the objects of promotion (efficient and, possibly, low-emission vehicles), avoid the unjust preferential treatment of goods traffic and can be implemented without disturbing international price structures (fuel tourism). A bonus-malus system applied at purchase (e.g. different levels of car taxation) is considered to be more efficient than a differentiation in vehicle (road) tax. The promotion of gas is a

  7. Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II

    Energy Technology Data Exchange (ETDEWEB)

    George J. Koperna Jr.; Vello A. Kuuskraa; David E. Riestenberg; Aiysha Sultana; Tyler Van Leeuwen

    2009-06-01

    This report serves as the final technical report and users manual for the 'Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II SBIR project. Advanced Resources International has developed a screening tool by which users can technically screen, assess the storage capacity and quantify the costs of CO2 storage in four types of CO2 storage reservoirs. These include CO2-enhanced oil recovery reservoirs, depleted oil and gas fields (non-enhanced oil recovery candidates), deep coal seems that are amenable to CO2-enhanced methane recovery, and saline reservoirs. The screening function assessed whether the reservoir could likely serve as a safe, long-term CO2 storage reservoir. The storage capacity assessment uses rigorous reservoir simulation models to determine the timing, ultimate storage capacity, and potential for enhanced hydrocarbon recovery. Finally, the economic assessment function determines both the field-level and pipeline (transportation) costs for CO2 sequestration in a given reservoir. The screening tool has been peer reviewed at an Electrical Power Research Institute (EPRI) technical meeting in March 2009. A number of useful observations and recommendations emerged from the Workshop on the costs of CO2 transport and storage that could be readily incorporated into a commercial version of the Screening Tool in a Phase III SBIR.

  8. CO_2 emission trends of China's primary aluminum industry: A scenario analysis using system dynamics model

    International Nuclear Information System (INIS)

    Li, Qiang; Zhang, Wenjuan; Li, Huiquan; He, Peng

    2017-01-01

    China announced its promise on CO_2 emission peak. When and what level of CO_2 emission peak China's primary aluminum industry will reach is in suspense. In this paper, a system dynamic model is established, with five subsystems of economy development, primary aluminum production, secondary aluminum production, CO_2 emission intensity and policies making involved. The model is applied to examine potential CO_2 emission trends of China's primary aluminum industry in next fifteen years with three scenarios of “no new policies”, “13th five-year plan” and “additional policies”. Simulation results imply that: merely relying on rapid expansion of domestic scarps recycling and reuse could not mitigate CO_2 emission continuously. Combination of energy-saving technology application and electrolytic technology innovation, as well as promoting hydropower utilization in primary aluminum industry are necessary for long term low-carbon development. From a global prospective, enhancing international cooperation on new primary aluminum capacity construction in other countries, especially with rich low-carbon energy, could bring about essential CO_2 emission for both China's and global primary aluminum industry. - Highlights: • A system dynamic model is established for future CO_2 emission trend of China's primary aluminum industry. • Three potential policy scenarios are simulated. • The impacts of potential policies implication on the CO_2 emission trend are discussed.

  9. Impacts of CO2 Enrichment on Productivity and Light Requirements of Eelgrass.

    Science.gov (United States)

    Zimmerman, R. C.; Kohrs, D. G.; Steller, D. L.; Alberte, R. S.

    1997-10-01

    Seagrasses, although well adapted for submerged existence, are CO2-limited and photosynthetically inefficient in seawater. This leads to high light requirements for growth and survival and makes seagrasses vulnerable to light limitation. We explored the long-term impact of increased CO2 availability on light requirements, productivity, and C allocation in eelgrass (Zostera marina L.). Enrichment of seawater CO2 increased photosynthesis 3-fold, but had no long-term impact on respiration. By tripling the rate of light-saturated photosynthesis, CO2 enrichment reduced the daily period of irradiance-saturated photosynthesis (Hsat) that is required for the maintenance of positive whole-plant C balance from 7 to 2.7 h, allowing plants maintained under 4 h of Hsat to perform like plants growing in unenriched seawater with 12 h of Hsat. Eelgrass grown under 4 h of Hsat without added CO2 consumed internal C reserves as photosynthesis rates and chlorophyll levels dropped. Growth ceased after 30 d. Leaf photosynthesis, respiration, chlorophyll, and sucrose-phosphate synthase activity of CO2-enriched plants showed no acclimation to prolonged enrichment. Thus, the CO2-stimulated improvement in photosynthesis reduced light requirements in the long term, suggesting that globally increasing CO2 may enhance seagrass survival in eutrophic coastal waters, where populations have been devastated by algal proliferation and reduced water-column light transparency.

  10. Techno-Economic Assessment of Four CO2 Storage Sites

    Directory of Open Access Journals (Sweden)

    Gruson J.-F.

    2015-04-01

    Full Text Available Carbon Capture and Storage (CCS should be a key technology in order to achieve a decline in the CO2 emissions intensity of the power sector and other intensive industry, but this potential deployment could be restricted by cost issues as the International Energy Agency (IEA in their last projections (World Energy Outlook 2013 has considered only around 1% of global fossil fuel-fired power plants could be equipped with CCS by 2035. The SiteChar project funded by 7th Framework Programme of European Commission gives the opportunity to evaluate the most influential parameters of techno-economic evaluations of four feasible European projects for CO2 geological storage located onshore and offshore and related to aquifer storage or oil and gas reservoirs, at different stages of characterization. Four potential CO2 storage sites have been assessed in terms of storage costs per tonne of CO2 permanently stored (equivalent cost based. They are located offshore UK, onshore Denmark, offshore Norway and offshore Italy. The four SiteChar techno-economic evaluations confirm it is not possible to derive any meaningful average cost for a CO2 storage site. The results demonstrate that the structure of costs for a project is heterogeneous and the storage cost is consequently site dependent. The strategy of the site development is fundamental, the technical choices such as the timing, rate and duration of injection are also important. The way monitoring is managed, using observation wells and logging has a strong impact on the estimated monitoring costs. Options to lower monitoring costs, such as permanent surveys, exist and should be further investigated. Table 1 below summarizes the cost range in Euro per tonne (Discount Rate (DR at 8% for the different sites, which illustrates the various orders of magnitude due to the specificities of each site. These figures have how to be considered with care. In particular the Italian and Norwegian sites present very specific

  11. PERBANDINGAN JUMP SHOOT DENGAN AWALAN DAN TANPA AWALAN TERHADAP PENINGKATAN KETEPATAN SHOOTING DALAM PERMAINAN BOLABASKET

    OpenAIRE

    I Gusti Ngurah Agung Cahya Prananta; N. Adiputra; I P G Adiatmika

    2015-01-01

    The effectiveness of  jump-shoot technique step jump shoot and still jump shoot in a game is still questionable,  because many different assumptions arise. One opinion stated that step jump shoot was more effective and the other stated that and still jump shoot was more efective. Therefore it is necessary to do research on the analysis of the results of step jump shoot and and still jump shoot to improve the accuracy of shooting in a basketball. The experimental research had been conducted on...

  12. Shootings Revive Debates on Security

    Science.gov (United States)

    Shah, Nirvi

    2013-01-01

    By nearly all accounts, the staff and students at Sandy Hook Elementary School did everything right on Dec. 14--and with the security measures they took before that day--when a young man armed with powerful weapons blasted his way into the school. But the deadliest K-12 school shooting in American history, a day that President Barack Obama has…

  13. School Shootings as Organizational Deviance.

    Science.gov (United States)

    Fox, Cybelle; Harding, David J.

    2005-01-01

    This article argues that rampage school shootings in American public schools can be understood as instances of organizational deviance, which occurs when events created by or in organizations do not conform to an organization's goals or expectations and produce unanticipated and harmful outcomes. Drawing on data from qualitative case studies of…

  14. School Shootings in Policy Spotlight

    Science.gov (United States)

    Maxwell, Lesli A.

    2006-01-01

    The three school shootings that left a principal and six students dead in less than a week have sparked a barrage of pledges from national and state political leaders to tighten campus security. School safety experts urged caution against overreacting to the horrific, but rare, incidents in rural schools in Colorado, Pennsylvania, and Wisconsin.…

  15. School Shootings and Critical Pedagogy

    Science.gov (United States)

    Schiller, Juliet

    2013-01-01

    What has been left out of studying school violence and shootings is a comprehensive look at the culture that creates violence and the lack of support for those deemed "different" in an educational setting that promotes and rewards competition. If parents, teachers, and other adults associated with children were teaching the values of…

  16. A method for permanent CO2 mineral carbonation

    Energy Technology Data Exchange (ETDEWEB)

    Dahlin, David C.; O' Connor, William K.; Nilsen, David N.; Rush, G.E.; Walters, Richard P.; Turner, Paul C.

    2000-01-01

    The Albany Research Center (ARC) of the U.S. Department of Energy (DOE) has been conducting research to investigate the feasibility of mineral carbonation as a method for carbon dioxide (CO2) sequestration. The research is part of a Mineral Carbonation Study Program within the Office of Fossil Energy in DOE. Other participants in this Program include DOE?s Los Alamos National Laboratory and National Energy Technology Laboratory, Arizona State University, and Science Applications International Corporation. The research has focused on ex-situ mineral carbonation in an aqueous system. The process developed at ARC reacts a slurry of magnesium silicate mineral with supercritical CO2 to produce a solid magnesium carbonate product. To date, olivine and serpentine have been used as the mineral reactant, but other magnesium silicates could be used as well. The process is designed to simulate the natural serpentinization reaction of ultramafic minerals, and consequently, these results may also be applicable to strategies for in-situ geological sequestration. Baseline tests were begun in distilled water on ground products of foundry-grade olivine. Tests conducted at 150 C and subcritical CO2 pressures (50 atm) resulted in very slow conversion to carbonate. Increasing the partial pressure of CO2 to supercritical (>73 atm) conditions, coupled with agitation of the slurry and gas dispersion within the water column, resulted in significant improvement in the extent of reaction in much shorter reaction times. A change from distilled water to a bicarbonate/salt solution further improved the rate and extent of reaction. When serpentine, a hydrated mineral, was used instead of olivine, extent of reaction was poor until heat treatment was included prior to the carbonation reaction. Removal of the chemically bound water resulted in conversion to carbonate similar to those obtained with olivine. Recent results have shown that conversions of nearly 80 pct are achievable after 30 minutes

  17. Laboratory Experiments to Stimulate CO2 Ocean Disposal

    International Nuclear Information System (INIS)

    Masutani, S.M.

    1997-01-01

    This Technical Progress Report summarizes activities conducted over the period 8/16/96-2/15/97 as part of this project. This investigation responds to the possibility that restrictions on greenhouse gas emissions may be imposed in the future to comply with the Framework Convention on Climate Change. The primary objective of the investigation is to obtain experimental data that can be applied to assess the technical feasibility and environmental impacts of oceanic containment strategies to limit release of carbon dioxide (CO 2 ) from coal and other fossil fuel combustion systems into the atmosphere. Critical technical uncertainties of ocean disposal of CO 2 will be addressed by performing experiments that: (1) characterize size spectra and velocities of a dispersed CO 2 phase in the near-field of a discharge jet; and (2) estimate rates of mass transfer from dissolving droplets of liquid CO 2 encased in a thin hydrate shell. Experiments will be conducted in a laboratory facility that can reproduce conditions in the ocean to depths of 600 m (1,969 ft). Between 8/16/96 and 2/15/97, activities focused on modifications to the experimental apparatus and the testing of diagnostics. Following completion of these tasks, experiments will be initiated and will continue through the end of the 36 month period of performance. Major accomplishments of this reporting period were: (1) delivery, set-up, and testing of the PDPA (Phase Doppler Particle Analyzer), which will be the principal diagnostic of the continuous CO 2 jet injection tests; (2) presentation of research papers and posters at the 212th American Chemical Society National Meeting and the Third International Conference on Carbon Dioxide Removal; (3) participation in the 4th Expert Workshop on Ocean Storage of Carbon Dioxide; (4) execution of an Agreement with ABB Management, Ltd. to support and extend the activities of this grant; and (5) initiation of research collaborations with Dr. P.M. Haugen of the University of

  18. Changes in carbon uptake and allocation patterns in Quercus robur seedlings in response to elevated CO2 and water stress: an evaluation with 13C labelling

    International Nuclear Information System (INIS)

    Vivin, P.; Guehl, J.M.

    1997-01-01

    A semi-closed (CO2)-C-13 labelling system (1.5% C-13) was used to assess both carbon uptake and allocation within pedunculate oak seedlings (Quercus robur L) grown under ambient (350 vpm) and elevated (700 vpm) atmospheric CO2 concentration ([CO2]) and in either well-watered or droughted conditions. Pulse-chase C-13 labelling data highlighted the direct positive effect of elevated CO2 on photosynthetic carbon acquisition. Consequently, in well-watered conditions, CO2-enriched plants produced 1.52 times more biomass (dry mass at harvest) and 1.33 times more dry root matter (coarse plus fine roots) over the 22-week growing period than plants grown under ambient [CO2]. The root/shoot biomass ratio was decreased both by drought and [CO2], despite lower N concentrations in CO2-enriched plants. However, both long-term and short-term C allocation to fine roots were not altered by CO2, and relative specific allocation (RSA), a parameter expressing sink strength, was hip her in all plant organs under 700 vpm compared to 350 vpm. Results showed that C availability for growth and metabolic processes was greater in fine roots of oaks grown under an elevated CO2 atmosphere irrespective of soil water availability [fr

  19. Gas exchange, growth, and defense responses of invasive Alliaria petiolata (Brassicaceae) and native Geum vernum (Rosaceae) to elevated atmospheric CO2 and warm spring temperatures.

    Science.gov (United States)

    Anderson, Laurel J; Cipollini, Don

    2013-08-01

    Global increases in atmospheric CO2 and temperature may interact in complex ways to influence plant physiology and growth, particularly for species that grow in cool, early spring conditions in temperate forests. Plant species may also vary in their responses to environmental changes; fast-growing invasives may be more responsive to rising CO2 than natives and may increase production of allelopathic compounds under these conditions, altering species' competitive interactions. We examined growth and physiological responses of Alliaria petiolata, an allelopathic, invasive herb, and Geum vernum, a co-occurring native herb, to ambient and elevated spring temperatures and atmospheric CO2 conditions in a factorial growth chamber experiment. At 5 wk, leaves were larger at high temperature, and shoot biomass increased under elevated CO2 only at high temperature in both species. As temperatures gradually warmed to simulate seasonal progression, G. vernum became responsive to CO2 at both temperatures, whereas A. petiolata continued to respond to elevated CO2 only at high temperature. Elevated CO2 increased thickness and decreased nitrogen concentrations in leaves of both species. Alliaria petiolata showed photosynthetic downregulation at elevated CO2, whereas G. vernum photosynthesis increased at elevated temperature. Flavonoid and cyanide concentrations decreased significantly in A. petiolata leaves in the elevated CO2 and temperature treatment. Total glucosinolate concentrations and trypsin inhibitor activities did not vary among treatments. Future elevated spring temperatures and CO2 will interact to stimulate growth for A. petiolata and G. vernum, but there may be reduced allelochemical effects in A. petiolata.

  20. Effects of atmospheric CO2 enrichment on soil CO2 efflux in a young longleaf pine system

    Science.gov (United States)

    Elevated atmospheric carbon dioxide (CO2) can affect the quantity and quality of plant tissues which will impact carbon (C) cycling and storage in plant/soil systems and the release of CO2 back to the atmosphere. Research is needed to quantify the effects of elevated CO2 on soil CO2 efflux to predi...

  1. DETERMINATION OF CO2 MASSES IN THE EXHAUST GASES OF THE MARINE DIESEL ENGINES

    Directory of Open Access Journals (Sweden)

    Doru COSOFRET

    2016-05-01

    Full Text Available Currently, reducing CO2 emissions that contribute to the greenhouse effect is currently under attention of the relevant international bodies. In the field of maritime transport, in 2011 International Maritime Organization (IMO has taken steps to reduce emissions of CO2 from the exhaust gases of marine diesel engines on ships, by imposing their energy efficiency standards. In this regard, we conducted a laboratory study on a 4-stroke diesel engine naturally aspirated by using to power it diesel and different blends of biodiesel with diesel fuel. The purpose of the study was to determine the formulas for calculating the mass flow rates of CO2 from exhaust gases’ concentrations experimentally determined. Determining the mass flow of CO2 is necessary to calculate the energy efficiency coefficient of the ship to assess the energy efficiency of the board of the limits imposed by the IMO.

  2. Shooting responses of potato ( Solanum tuberosum L.) varieties in ...

    African Journals Online (AJOL)

    A study was conducted in 2012 and 2013 at IRAD Bambui (Cameroon) to evaluate the rate of shooting in four improved IRAD potato varieties: Cipira, Tubira, Mafo and Bambui wonder. Liquid and solid media stocks prepared according to the International Potato Center (CIP)'s protocol were used. A randomized complete ...

  3. Legal aspects of storing CO2. Update and recommendations

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2007-06-21

    CO2 emissions from energy production and consumption are a major contributor to climate change. Thus, stabilising CO2 concentrations in the atmosphere by reducing these emissions is an increasingly urgent international necessity. Carbon capture and storage (CCS) represents one of the most promising potential solutions to contain emissions resulting from continued use of coal and other fossil fuels. However, challenges such as a lack of legal and regulatory frameworks to guide near-term demonstration projects and long-term technology expansion must be addressed to facilitate the expanded use of CCS. In October 2006, the International Energy Agency (IEA) and the Carbon Sequestration Leadership Forum (CSLF) convened with legal experts,to discuss the range of legal issues associated with expanded use of CCS and to identify ways to facilitate further CCS development and implementation Participants examined gaps and barriers to the deployment of CCS and identified recommendations to guide further development of appropriate legal and regulatory frameworks. This publication provides policymakers with a detailed summary of the main legal issues surrounding the CCS debate, including up-to-date background information, case studies and conclusions on the best legal and regulatory approaches to advance CCS. These strategies can be used to enable further development, deployment and demonstration of CCS technology, potentially an essential element in global efforts to mitigate climate change.

  4. Shooting Stars over China

    Science.gov (United States)

    Hodges, John

    International cultural exchange and education in the sciences and arts is one of the chief aims of the British Council (BC). The 1998 Leonids Meteor Shower was recognised by the BC in China as an event that would offer an opportunity, both to promote the public understanding of space science at an international level, and to encourage on-going cultural links between the United Kingdom and China. Predictions suggested that the 1998 shower, which was likely to be the most intense for more than three decades, would be best viewed in north-east Asia. The BC contracted the Orbital Mechanics Educational Network, an independent organisation that promotes space education amongst young people, to organise several activities aimed particularly at teenagers. The culmination of the project was a visit to Beijing by a party of British teenagers, to take part in meteor observation at China's Mi Yun Observatory. The paper focusses on the practicalities of organising and running such a project and reports on the achievements and shortcomings of the overall venture. It also reports on the observations and findings that were made by the UK group and their Chinese student partners, all of whom were observing a meteor shower for the first time. It reports on the techniques of observing that were tried, the observations themselves and the findings that were made by the group. It also offers advice to those who might wish to set up similar bi-lateral ventures, particularly with China and the UK, and outlines plans to continue and improve the relationships that have been established. (Please note: I realise this is topic not directly covered by the Conference, but how the subject of the meteor phenomenon in particular and, for that matter, science in general is conveyed to the " man in the street" should be important to all scientists, not least because they depend on external funding and public goodwill! Perhaps a suitable slot can be made for this presentation on Tuesday, which is the

  5. Shoot water relations of mature black spruce families displaying a genotype × environment interaction in growth rate. III. Diurnal patterns as influenced by vapor pressure deficit and internal water status

    Science.gov (United States)

    John E. Major; Kurt H. Johnsen

    2001-01-01

    Pressure­volume curves were constructed and shoot water potentials measured for +20-year-old black spruce (Picea mariana (Mill.) BSP) trees from four full-sib families growing on a moist site and a dry site at the Petawawa Research Forest, Ontario, to determine whether differences in diurnal water relations traits were related to productivity. To...

  6. Reconsideration of atmospheric CO2 lifetime: potential mechanism for explaining CO2 missing sink

    Science.gov (United States)

    Kikuchi, R.; Gorbacheva, T.; Gerardo, R.

    2009-04-01

    Carbon cycle data (Intergovernmental Panel on Climate Change 1996) indicate that fossil fuel use accounts for emissions to the atmosphere of 5.5±0.5 GtC (Gigatons of carbon) annually. Other important processes in the global CO2 budget are tropical deforestation, estimated to generate about 1.6±1.0 GtC/yr; absorption by the oceans, removing about 2.0±0.8 GtC/yr; and regrowth of northern forests, taking up about 0.5±0.5 GtC/yr. However, accurate measurements of CO2 show that the atmosphere is accumulating only about 3.3±0.2 GtC/yr. The imbalance of about 1.3±1.5 GtC/yr, termed the "missing sink", represents the difference between the estimated sources and the estimated sinks of CO2; that is, we do not know where all of the anthropogenic CO2 is going. Several potential mechanisms have been proposed to explain this missing carbon, such as CO2 fertilization, climate change, nitrogen deposition, land use change, forest regrowth et al. Considering the complexity of ecosystem, most of ecosystem model cannot handle all the potential mechanisms to reproduce the real world. It has been believed that the dominant sink mechanism is the fertilizing effects of increased CO2 concentrations in the atmosphere and the addition to soils of fixed nitrogen from fossil-fuel burning and agricultural fertilizers. However, a recent analysis of long-term observations of the change in biomass and growth rates suggests that such fertilization effects are much too small to explain more than a small fraction of the observed sink. In addition, long-term experiments in which small forest patches and other land ecosystems have been exposed to elevated CO2 levels for extended periods show a rapid decrease of the fertilization effect after an initial enhancement. We will explore this question of the missing sink in atmospheric CO2 residence time. Radioactive and stable carbon isotopes (13-C/12-C) show the real CO2 lifetime is about 5 years; i.e. CO2 is quickly taken out of the atmospheric

  7. Interactions between CO2, saline water and minerals during geological storage of CO2

    International Nuclear Information System (INIS)

    Hellevang, Helge

    2006-06-01

    The topic of this thesis is to gain a better understanding of interactions between injected CO 2 , aqueous solutions and formation mineralogies. The main focus is concerned with the potential role mineral reactions play in safe long term storage of CO 2 . The work is divided into an experimental part concentrated on the potential of dawsonite (NaAl(OH) 2 CO 3 ) as a permanent storage host of CO 2 , and the development of a new geochemical code ACCRETE that is coupled with the ATHENA multiphase flow simulator. The thesis is composed of two parts: (I) the first part introducing CO 2 storage, geochemical interactions and related work; and (II) the second part that consists of the papers. Part I is composed as follows: Chapter 2 gives a short introduction to geochemical reactions considered important during CO 2 storage, including a thermodynamic framework. Chapter 3 presents objectives of numerical work related to CO 2 -water-rock interactions including a discussion of factors that influence the outcome of numerical simulations. Chapter 4 presents the main results from paper A to E. Chapter 5 give some details about further research that we propose based on the present work and related work in the project. Several new activities have emerged from research on CO 2 -water-rock interaction during the project. Several of the proposed activities are already initiated. Papers A to F are then listed in Part II of the thesis after the citation list. The thesis presents the first data on the reaction kinetics of dawsonite at different pH (Paper A), and comprehensive numerical simulations, both batch- and large scale 3D reactive transport, that illustrate the role different carbonates have for safe storage of CO 2 in geological formations (Papers C to F). The role of dawsonite in CO 2 storage settings is treated throughout the study (Papers A to E) After the main part of the thesis (Part I and II), two appendices are included: Appendix A lists reactions that are included in the

  8. Stable isotope measurements of atmospheric CO2

    International Nuclear Information System (INIS)

    White, J.W.C.; Ferretti, D.F.; Vaughn, B.H.; Francey, R.J.; Allison, C.E.

    2002-01-01

    The measurement of stable carbon isotope ratios of atmospheric carbon dioxide, δ 13 CO 2 are useful for partitioning surface-atmospheric fluxes into terrestrial and oceanic components. δC 18 OO also has potential for segregating photosynthetic and respiratory fluxes in terrestrial ecosystems. Here we describe in detail the techniques for making these measurements. The primary challenge for all of the techniques used to measure isotopes of atmospheric CO 2 is to achieve acceptable accuracy and precision and to maintain them over the decades needed to observe carbon cycle variability. The keys to success such an approach are diligent intercalibrations of laboratories from around the world, as well as the use of multiple techniques such as dual inlet and GC-IRMS and the intercomparison of such measurements. We focus here on two laboratories, the Stable Isotope Lab at the Institute for Arctic and Alpine Research (INSTAAR) at the University of Colorado is described and the Commonwealth Scientific and Industrial Research Organisation - Atmospheric Research (CSIRO). Different approaches exist at other laboratories (e.g. programs operated by Scripps Institution of Oceanography (SIO) and The Center for Atmospheric and Oceanic Studies, Toboku University (TU)) however these are not discussed here. Finally, we also discuss the recently developed Gas Chromatography - Isotope Ratio Mass Spectrometry (GC-IRMS) technique which holds significant promise for measuring ultra-small samples of gas with good precision. (author)

  9. Global CO2 emissions from cement production

    Science.gov (United States)

    Andrew, Robbie M.

    2018-01-01

    The global production of cement has grown very rapidly in recent years, and after fossil fuels and land-use change, it is the third-largest source of anthropogenic emissions of carbon dioxide. The required data for estimating emissions from global cement production are poor, and it has been recognised that some global estimates are significantly inflated. Here we assemble a large variety of available datasets and prioritise official data and emission factors, including estimates submitted to the UNFCCC plus new estimates for China and India, to present a new analysis of global process emissions from cement production. We show that global process emissions in 2016 were 1.45±0.20 Gt CO2, equivalent to about 4 % of emissions from fossil fuels. Cumulative emissions from 1928 to 2016 were 39.3±2.4 Gt CO2, 66 % of which have occurred since 1990. Emissions in 2015 were 30 % lower than those recently reported by the Global Carbon Project. The data associated with this article can be found at https://doi.org/10.5281/zenodo.831455.

  10. Public Acceptance for Geological CO2-Storage

    Science.gov (United States)

    Schilling, F.; Ossing, F.; Würdemann, H.; Co2SINK Team

    2009-04-01

    Public acceptance is one of the fundamental prerequisites for geological CO2 storage. In highly populated areas like central Europe, especially in the vicinity of metropolitan areas like Berlin, underground operations are in the focus of the people living next to the site, the media, and politics. To gain acceptance, all these groups - the people in the neighbourhood, journalists, and authorities - need to be confident of the security of the planned storage operation as well as the long term security of storage. A very important point is to show that the technical risks of CO2 storage can be managed with the help of a proper short and long term monitoring concept, as well as appropriate mitigation technologies e.g adequate abandonment procedures for leaking wells. To better explain the possible risks examples for leakage scenarios help the public to assess and to accept the technical risks of CO2 storage. At Ketzin we tried the following approach that can be summed up on the basis: Always tell the truth! This might be self-evident but it has to be stressed that credibility is of vital importance. Suspiciousness and distrust are best friends of fear. Undefined fear seems to be the major risk in public acceptance of geological CO2-storage. Misinformation and missing communication further enhance the denial of geological CO2 storage. When we started to plan and establish the Ketzin storage site, we ensured a forward directed communication. Offensive information activities, an information centre on site, active media politics and open information about the activities taking place are basics. Some of the measures were: - information of the competent authorities through meetings (mayor, governmental authorities) - information of the local public, e.g. hearings (while also inviting local, regional and nation wide media) - we always treated the local people and press first! - organizing of bigger events to inform the public on site, e.g. start of drilling activities (open

  11. Does Size Matter? Atmospheric CO2 May Be a Stronger Driver of Stomatal Closing Rate Than Stomatal Size in Taxa That Diversified under Low CO2.

    Science.gov (United States)

    Elliott-Kingston, Caroline; Haworth, Matthew; Yearsley, Jon M; Batke, Sven P; Lawson, Tracy; McElwain, Jennifer C

    2016-01-01

    One strategy for plants to optimize stomatal function is to open and close their stomata quickly in response to environmental signals. It is generally assumed that small stomata can alter aperture faster than large stomata. We tested the hypothesis that species with small stomata close faster than species with larger stomata in response to darkness by comparing rate of stomatal closure across an evolutionary range of species including ferns, cycads, conifers, and angiosperms under controlled ambient conditions (380 ppm CO2; 20.9% O2). The two species with fastest half-closure time and the two species with slowest half-closure time had large stomata while the remaining three species had small stomata, implying that closing rate was not correlated with stomatal size in these species. Neither was response time correlated with stomatal density, phylogeny, functional group, or life strategy. Our results suggest that past atmospheric CO2 concentration during time of taxa diversification may influence stomatal response time. We show that species which last diversified under low or declining atmospheric CO2 concentration close stomata faster than species that last diversified in a high CO2 world. Low atmospheric [CO2] during taxa diversification may have placed a selection pressure on plants to accelerate stomatal closing to maintain adequate internal CO2 and optimize water use efficiency.

  12. Vehicle technology under CO2 constraint: a general equilibrium analysis

    International Nuclear Information System (INIS)

    Schaefer, Andreas; Jacoby, Henry D.

    2006-01-01

    A study is presented of the rates of penetration of different transport technologies under policy constraints on CO 2 emissions. The response of this sector is analyzed within an overall national level of restriction, with a focus on automobiles, light trucks, and heavy freight trucks. Using the US as an example, a linked set of three models is used to carry out the analysis: a multi-sector computable general equilibrium model of the economy, a MARKAL-type model of vehicle and fuel supply technology, and a model simulating the split of personal and freight transport among modes. Results highlight the importance of incremental improvements in conventional internal combustion engine technology, and, in the absence of policies to overcome observed consumer discount rates, the very long time horizons before radical alternatives like the internal combustion engine hybrid drive train vehicle are likely to take substantial market share

  13. Impact of elevated CO2 on a Florida Scrub-oak Ecosystems

    Energy Technology Data Exchange (ETDEWEB)

    Drake, Bert G

    2013-01-01

    Since May of 1996, we have conducted an experiment in Florida Scrub Oak to determine the impact of elevated atmospheric CO2 and climate change on carbon, water, and nutrient cycling in this important terrestrial ecosystem. Florida scrub oak is the name for a collective of species occupying much of the Florida peninsula. The dominant tree species are oaks and the dwarf structure of this community makes it an excellent system in which to test hypotheses regarding the potential capacity of woody ecosystems to assimilate and sequester anthropogenic carbon. Scrub oak is fire dependent with a return cycle of 10-15 years, a time which would permit an experiment to follow the entire cycle. Our site is located on Cape Canaveral at the Kennedy Space Center, Florida. After burning in 1995, we built 16 open top chambers, half of which have been fumigated with pure CO2 sufficient to raise the concentration around the plants to 350 ppm above ambient. In the intervening 10 years we have non destructively measured biomass of shoots and roots, ecosystem gas exchange using chambers and eddy flux, leaf photosynthesis and respiration, soil respiration, and relevant environmental factors such as soil water availability, temperature, light, etc. The overwhelming result from analysis of our extensive data base is that elevated CO2 has had a profound impact on this ecosystem that, overall, has resulted in increased carbon accumulation in plant shoots, roots and litter. Our measurements of net ecosystem gas exchange also indicate that the ecosystem has accumulated carbon much in excess of the increased biomass or soil carbon suggesting a substantial export of carbon through the porous, sandy soil into the water table several meters below the surface. A major discovery is the powerful interaction between the stimulation of growth, photosynthesis, and respiration by elevated CO2 and other environmental factors particularly precipitation and nitrogen. Our measurements focused attention on

  14. CO2 como refrigerante: del pasado al futuro CO2 as refrigerant: from the past to future

    Directory of Open Access Journals (Sweden)

    Juan Manuel Belman Flores

    2013-05-01

    Full Text Available En años recientes y debido a la problemática que ha originado el calentamiento mundial, en el campo de la refrigeración y climatización se ha incrementado el interés por utilizar refrigerantes naturales e hidrocarburos con bajo potencial de calentamiento mundial, este es el caso de la utilización del CO2 como fluido frigorígeno que ha sido visto como una alter­nativa adecuada a los actuales refrigerantes en la comunidad científica. Hoy en día, el CO2 cada vez está retomando presencia en el campo de la refrigeración y climatización a nivel internacional, así pues, el presente trabajo tiene la finalidad de dar a conocer su potencial como refrigerante natural, las causas por las cuales este fluido fue relevado momentánea­mente por refrigerantes clorofluorocarbonados y su renacer en pleno siglo XXI. Además, se plantea su aplicación en la generación de frío en nuestro país mediante la tecnología de compresión de vapor basado en ciclo transcrítico.  In recent years, and due to problems resulting from global warming, interest has grown in the fields of refrigeration and air conditioning, specifically regarding the use of natural refrigerants and hydrocarbons with low potential for global warming. Such is the case of the use of CO2 as a cold fluid, which has been considered in the scientific community as an adequate alternative to common refrigerants. Nowadays, the use of CO2 in the areas of refrigeration and air conditioning has been recognized at international levels. Therefore, this work aims to show its potential as a natural refrigerant, the causes why this fluid was temporarily replaced by chlorofluorocarbon refrigerants, and its reappearance in the XXI century. It also proposes the use of CO2 in air conditioning in our country by using vapor compression technology, based on the transcritical cycle.

  15. Field demonstration of CO2 leakage detection in potable aquifers with a pulselike CO2-release test.

    Science.gov (United States)

    Yang, Changbing; Hovorka, Susan D; Delgado-Alonso, Jesus; Mickler, Patrick J; Treviño, Ramón H; Phillips, Straun

    2014-12-02

    This study presents two field pulselike CO2-release tests to demonstrate CO2 leakage detection in a shallow aquifer by monitoring groundwater pH, alkalinity, and dissolved inorganic carbon (DIC) using the periodic groundwater sampling method and a fiber-optic CO2 sensor for real-time in situ monitoring of dissolved CO2 in groundwater. Measurements of groundwater pH, alkalinity, DIC, and dissolved CO2 clearly deviated from their background values, showing responses to CO2 leakage. Dissolved CO2 observed in the tests was highly sensitive in comparison to groundwater pH, DIC, and alkalinity. Comparison of the pulselike CO2-release tests to other field tests suggests that pulselike CO2-release tests can provide reliable assessment of geochemical parameters indicative of CO2 leakage. Measurements by the fiber-optic CO2 sensor, showing obvious leakage signals, demonstrated the potential of real-time in situ monitoring of dissolved CO2 for leakage detection at a geologic carbon sequestration (GCS) site. Results of a two-dimensional reactive transport model reproduced the geochemical measurements and confirmed that the decrease in groundwater pH and the increases in DIC and dissolved CO2 observed in the pulselike CO2-release tests were caused by dissolution of CO2 whereas alkalinity was likely affected by carbonate dissolution.

  16. Response of atmospheric CO2 to changes in land use

    International Nuclear Information System (INIS)

    King, A.W.; Emanuel, W.R.; Post, W.M.

    1991-01-01

    This chapter examines how different histories of CO 2 release from past changes in land use influence the simulation of past and future changes in atmospheric CO 2 . The authors first simulate past change in atmospheric CO 2 using reconstructed histories of land-use CO 2 release from a historical-ecological model of land-use change and CO 2 release. They examine the impact of each history on the coincidence between simulated and observed atmospheric CO 2 . They then compare these CO 2 release histories, and their contribution to coincidence or noncoincidence of simulation and observation, with histories reconstructed by deconvolution of the atmospheric CO 2 record. They conclude by exploring the implications of these deconvolved reconstructions for the simulation of future changes in atmospheric CO 2

  17. Tackling CO2 reduction in India through use of CO2 capture and storage (CCS): Prospects and challenges

    International Nuclear Information System (INIS)

    Shackley, Simon; Verma, Preeti

    2008-01-01

    CO 2 capture and storage (CCS) is not currently a priority for the Government of India (GOI) because, whilst a signatory to the UNFCCC and Kyoto Protocol, there are no existing greenhouse gas emission reduction targets and most commentators do not envisage compulsory targets for India in the post-2012 phase. The overwhelming priority for the GOI is to sustain a high level of economic growth (8%+) and provision of secure, reliable energy (especially electricity) is one of the widely recognised bottlenecks in maintaining a high growth rate. In such a supply-starved context, it is not easy to envisage adoption of CCS-which increases overall generation capacity and demand for coal without increasing actual electricity supply-as being acceptable. Anything which increases costs-even slightly-is very unlikely to happen, unless it is fully paid for by the international community. The majority viewpoint of the industry and GOI interviewees towards CCS appears to be that it is a frontier technology, which needs to be developed further in the Annex-1 countries to bring down the cost through RD and D and deployment. More RD and D is required to assess in further detail the potential for CO 2 storage in geological reservoirs in India and the international community has an important role to play in cultivating such research

  18. CO2 point sources and subsurface storage capacities for CO2 in aquifers in Norway

    International Nuclear Information System (INIS)

    Boee, Reidulv; Magnus, Christian; Osmundsen, Per Terje; Rindstad, Bjoern Ivar

    2002-01-01

    The GESTCO project comprises a study of the distribution and coincidence of thermal CO 2 emission sources and location/quality of geological storage capacity in Europe. Four of the most promising types of geological storage are being studied. 1. Onshore/offshore saline aquifers with or without lateral seal. 2. Low entalpy geothermal reservoirs. 3. Deep methane-bearing coal beds and abandoned coal and salt mines. 4. Exhausted or near exhausted hydrocarbon structures. In this report we present an inventory of CO 2 point sources in Norway (1999) and the results of the work within Study Area C: Deep saline aquifers offshore/near shore Northern and Central Norway. Also offshore/near shore Southern Norway has been included while the Barents Sea is not described in any detail. The most detailed studies are on the Tilje and Aare Formations on the Troendelag Platform off Mid-Norway and on the Sognefjord, Fensfjord and Krossfjord Formations, southeast of the Troll Field off Western Norway. The Tilje Formation has been chosen as one of the cases to be studied in greater detail (numerical modelling) in the project. This report shows that offshore Norway, there are concentrations of large CO 2 point sources in the Haltenbanken, the Viking Graben/Tampen Spur area, the Southern Viking Graben and the central Trough, while onshore Norway there are concentrations of point sources in the Oslofjord/Porsgrund area, along the coast of western Norway and in the Troendelag. A number of aquifers with large theoretical CO 2 storage potential are pointed out in the North Sea, the Norwegian Sea and in the Southern Barents Sea. The storage capacity in the depth interval 0.8 - 4 km below sea level is estimated to be ca. 13 Gt (13000000000 tonnes) CO 2 in geological traps (outside hydrocarbon fields), while the storage capacity in aquifers not confined to traps is estimated to be at least 280 Gt CO 2 . (Author)

  19. Plasma catalytic process for CO2 methanation

    International Nuclear Information System (INIS)

    Nizio, Magdalena

    2016-01-01

    The limited resources of oil and natural gas, together with an increasing energy demand, forces us to seek more and more efficient and cleaner energy production alternatives. Hydrogen has been recently considered as a promising energy carrier. However, there are several inherent problems to the utilization of H 2 , from its transportation to its distribution. Transformation of the H 2 molecule by fixing into a carbon-containing compound, i.e. CH 4 , will offer the possibility of using the conventional transportation network. Indeed, the Sabatier reaction, which is highly exothermic, involves the reaction of carbon dioxide and hydrogen gas in order to produce methane and water. This process, called methanation, represents a feasible approach contributing to the reduction of the CO 2 emissions in our atmosphere, through a closed carbon cycle involving the valorization of CO 2 , i.e. from capture. However, below a temperature of 250 C, the conversion becomes practically close to 0 %, whereas at higher temperatures, i.e., (≥300 C), the co-existence of secondary reactions favours the formation of CO and H 2 . This is the reason why new catalysts and process conditions are continuously being investigated in order to maximize the methane selectivity at low reaction temperatures at atmospheric pressure. Therefore, by using catalysts combined to Dielectric Barrier Discharge plasmas (DBD), the activation of the methanation reaction can be enhanced and overcome the drawbacks of existing conventional processes. Several Ni-containing catalysts were prepared using various ceria-zirconia oxides as supports, with different Ce/Zr ratios. The results obtained in the adiabatic conditions at low temperatures (ranging between 100-150 C), in the presence of catalysts activated by plasma, are promising. Indeed, the conversion of CO 2 to CH 4 is about 85 % with a selectivity close to 100 %. The same conversion in the absence of the plasma activation of the catalyst is observed at 350 C

  20. Training visual control in wheelchair basketball shooting

    NARCIS (Netherlands)

    Oudejans, R.R.D.; Heubers, S.; Ruitenbeek, J-R.J.A.C.; Janssen, T.W.J.

    2012-01-01

    We examined the effects of visual control training on expert wheelchair basketball shooting, a skill more difficult than in regular basketball, as players shoot from a seated position to the same rim height. The training consisted of shooting with a visual constraint that forced participants to use

  1. Training Visual Control in Wheelchair Basketball Shooting

    Science.gov (United States)

    Oudejans, Raoul R. D.; Heubers, Sjoerd; Ruitenbeek, Jean-Rene J. A. C.; Janssen, Thomas W. J.

    2012-01-01

    We examined the effects of visual control training on expert wheelchair basketball shooting, a skill more difficult than in regular basketball, as players shoot from a seated position to the same rim height. The training consisted of shooting with a visual constraint that forced participants to use target information as late as possible.…

  2. Shoot regeneration and embryogenesis in lily shoot tips cryopreserved by droplet vitrification

    Science.gov (United States)

    Shoot regeneration and embryogenesis were, for the first time, achieved directly in shoot tips of Lilium Oriental hybrid ‘Siberia’ following cryopreservation by droplet-vitrification. Shoot tips (2 mm in length) including 2-3 leaf primordia were excised from 4-week-old adventitious shoots directly r...

  3. Plasma Arc Augmented CO2 laser welding

    DEFF Research Database (Denmark)

    Bagger, Claus; Andersen, Mikkel; Frederiksen, Niels

    2001-01-01

    In order to reduce the hardness of laser beam welded 2.13 mm medium strength steel CMn 250, a plasma arc has been used simultaneously with a 2.6 kW CO2 laser source. In a number of systematic laboratory tests, the plasma arc current, plasma gas flow and distance to the laser source were varied...... with all laser parameters fixed. The welds were quality assessed and hardness measured transversely to the welding direction in the top, middle and root of the seam. In the seams welded by laser alone, hardness values between 275 and 304 HV1 were measured, about the double of the base material, 150 HV1...

  4. Tritium removal by CO2 laser heating

    International Nuclear Information System (INIS)

    Skinner, C.H.; Kugel, H.; Mueller, D.

    1997-01-01

    Efficient techniques for rapid tritium removal will be necessary for ITER to meet its physics and engineering goals. One potential technique is transient surface heating by a scanning CO 2 or Nd:Yag laser that would release tritium without the severe engineering difficulties of bulk heating of the vessel. The authors have modeled the heat propagation into a surface layer and find that a multi-kW/cm 2 flux with an exposure time of order 10 ms is suitable to heat a 50 micron co-deposited layer to 1,000--2,000 degrees. Improved wall conditioning may be a significant side benefit. They identify remaining issues that need to be addressed experimentally

  5. CO2 Capture for Cement Technology

    DEFF Research Database (Denmark)

    Pathi, Sharat Kumar

    , whereas in a normal cement plant, it is 0.9 kg/ kg cl. However the thermal energy demand in the integrated plant increases from 3.9 MJ/ kg cl to 5.6 MJ/ kg cl. But on the other side this additional energy spent can be recovered as a high quality heat to generate electricity. The potential to generate...... electricity depends on the scale of the plant, the bigger the production capacity of cement plant the better, with capacity higher than 3400 tons of clinker/day is required to produce captive electricity to meet the demand both from the cement plant operations and from the CO2 capture system operations....

  6. Smart Transportation CO2 Emission Reduction Strategies

    Science.gov (United States)

    Tarulescu, S.; Tarulescu, R.; Soica, A.; Leahu, C. I.

    2017-10-01

    Transport represents the sector with the fastest growing greenhouse gas emissions around the world. The main global objective is to reduce energy usage and associated greenhouse gas emissions from the transportation sector. For this study it was analyzed the road transportation system from Brasov Metropolitan area. The study was made for the transportation route that connects Ghimbav city to the main surrounding objectives. In this study ware considered four optimization measures: vehicle fleet renewal; building the detour belt for the city; road increasing the average travel speed; making bicycle lanes; and implementing an urban public transport system for Ghimbav. For each measure it was used a mathematical model to calculate the energy consumption and carbon emissions from the road transportation sector. After all four measures was analyzed is calculated the general energy consumption and CO2 reduction if this are applied from year 2017 to 2020.

  7. Power stabilized CO2 gas transport laser

    International Nuclear Information System (INIS)

    Foster, J.D.; Kirk, R.F.; Moreno, F.E.; Ahmed, S.A.

    1975-01-01

    The output power of a high power (1 kW or more) CO 2 gas transport laser is stabilized by flowing the gas mixture over copper plated baffles in the gas channel during operation of the laser. Several other metals may be used instead of copper, for example, nickel, manganese, palladium, platinum, silver and gold. The presence of copper in the laser gas circuit stabilizes output power by what is believed to be a compensation of the chemical changes in the gas due to the cracking action of the electrical discharge which has the effect of diminishing the capactiy of the carbon dioxide gas mixture to maintain the rated power output of the laser. (U.S.)

  8. CO2 laser-aided waste incineration

    International Nuclear Information System (INIS)

    Costes, J.R.; Guiberteau, P.; Caminat, P.; Bournot, P.

    1994-01-01

    Lasers are widely employed in laboratories and in certain industrial applications, notably for welding, cutting and surface treatments. This paper describes a new application, incineration, which appears warranted when the following features are required: high-temperature incineration (> 1500 deg C) with close-tolerance temperature control in an oxidizing medium while ensuring containment of toxic waste. These criteria correspond to the application presented here. Following a brief theoretical introduction concerning the laser/surface interaction, the paper describes the incineration of graphite waste contaminated with alpha-emitting radionuclides. Process feasibility has been demonstrated on a nonradioactive prototype capable of incinerating 10 kg -h-1 using a 7 kW CO 2 laser. An industrial facility with the same capacity, designed to operate within the constraints of an alpha-tight glove box environment, is now at the project stage. Other types of applications with similar requirements may be considered. (authors). 3 refs., 7 figs

  9. Anterior capsulotomy using the CO2 laser

    Science.gov (United States)

    Barak, Adiel; Ma-Naim, Tova; Rosner, Mordechai; Eyal, Ophir; Belkin, Michael

    1998-06-01

    Continuous circular capsulorhexis (CCC) is the preferred technique for removal of the anterior capsule during cataract surgery due to this technique assuring accurate centration of the intraocular lens. During modern cataract surgery, especially with small or foldable intra ocular lenses, centration of the lens is obligatory. Radial tears at the margin of an anterior capsulotomy may be associated with the exit of at least one loop of an intraocular lens out of the capsular bag ('pea pod' effect) and its subsequent decentration. The anterior capsule is more likely to ream intact if the continuous circular capsulorhexis (CCC) technique is used. Although manual capsulorhexis is an ideal anterior capsulectomy technique for adults, many ophthalmologists are still uncomfortable with it and find it difficult to perform, especially in complicated cases such as these done behind small pupil, cataract extraction in children and pseudoexfoliation syndrome. We have developed a technique using a CO2 laser system for safe anterior capsulotomy and tested it in animal eyes.

  10. Experimental Investigations into CO2 Interactions with Injection Well Infrastructure for CO2 Storage

    Science.gov (United States)

    Syed, Amer; Shi, Ji-Quan; Durucan, Sevket; Nash, Graham; Korre, Anna

    2013-04-01

    Wellbore integrity is an essential requirement to ensure the success of a CO2 Storage project as leakage of CO2 from the injection or any other abandoned well in the storage complex, could not only severely impede the efficiency of CO2 injection and storage but also may result in potential adverse impact on the surrounding environment. Early research has revealed that in case of improper well completions and/or significant changes in operating bottomhole pressure and temperature could lead to the creation of microannulus at cement-casing interface which may constitute a preferential pathway for potential CO2 leakage during and post injection period. As a part of a European Commission funded CO2CARE project, the current research investigates the sealing behaviour of such microannulus at the cement-casing interface under simulated subsurface reservoir pressure and temperature conditions and uses the findings to develop a methodology to assess the overall integrity of CO2 storage. A full scale wellbore experimental test set up was constructed for use under elevated pressure and temperature conditions as encountered in typical CO2 storage sites. The wellbore cell consists of an assembly of concentric elements of full scale casing (Diameter= 0.1524m), cement sheath and an outer casing. The stainless steel outer ring is intended to simulate the stiffness offered by the reservoir rock to the displacement applied at the wellbore. The Central Loading Mechanism (CLM) consists of four case hardened shoes that can impart radial load onto the well casing. The radial movement of the shoes is powered through the synchronised movement of four precision jacks controlled hydraulically which could impart radial pressures up to 15 MPa. The cell body is a gas tight enclosure that houses the wellbore and the central loading mechanism. The setup is enclosed in a laboratory oven which acts both as temperature and safety enclosure. Prior to a test, cement mix is set between the casing and

  11. CO2 laser milling of hard tissue

    Science.gov (United States)

    Werner, Martin; Ivanenko, Mikhail; Harbecke, Daniela; Klasing, Manfred; Steigerwald, Hendrik; Hering, Peter

    2007-02-01

    Drilling of bone and tooth tissue belongs to recurrent medical procedures (screw- and pin-bores, bores for implant inserting, trepanation etc.). Small round bores can be in general quickly produced with mechanical drills. Problems arise however by angled drilling, by the necessity to fulfill the drilling without damaging of sensitive soft tissue beneath the bone, or by the attempt to mill precisely noncircular small cavities. We present investigations on laser hard tissue "milling", which can be advantageous for solving these problems. The "milling" is done with a CO2 laser (10.6 μm) with pulse duration of 50 - 100 μs, combined with a PC-controlled galvanic beam scanner and with a fine water-spray, which helps to avoid thermal side-effects. The damaging of underlying soft tissue can be prevented through control of the optical or acoustical ablation signal. The ablation of hard tissue is accompanied with a strong glowing, which is absent during the laser beam action on soft tissue. The acoustic signals from the diverse tissue types exhibit distinct differences in the spectral composition. Also computer image analysis could be a useful tool to control the operation. Laser "milling" of noncircular cavities with 1 - 4 mm width and about 10 mm depth is particularly interesting for dental implantology. In ex-vivo investigations we found conditions for fast laser "milling" of the cavities without thermal damage and with minimal tapering. It included exploration of different filling patterns (concentric rings, crosshatch, parallel lines and their combinations), definition of maximal pulse duration, repetition rate and laser power, optimal position of the spray. The optimized results give evidences for the applicability of the CO2 laser for biologically tolerable "milling" of deep cavities in the hard tissue.

  12. Elevated atmospheric CO2 in a semi-natural grassland: Root dynamics, decomposition and soil C balances

    International Nuclear Information System (INIS)

    Sindhoej, Erik

    2001-01-01

    This thesis focuses on how elevated atmospheric CO 2 affects a semi-natural grassland, with emphasis on root growth, decomposition and the subsequent long-term effects on soil C balances. Parts of a semi-natural grassland in Central Sweden were enclosed in open-top chambers and exposed to ambient and elevated levels of CO 2 (+350 μmol mol -1 ) from 1995 to 2000, while chamberless rings were used for controls. Root dynamics were observed with minirhizotrons while root biomass and production were studied with soil cores and ingrowth cores. Roots collected from ingrowth cores were incubated under controlled conditions for 160 days to measure root decomposition rates. Treatment-induced differences in microclimate, C input and root decomposability were entered into the ICBM soil C balance model for 30-year projections of soil C balances for the three treatments. Elevated CO 2 chambers had higher biomass production both above and below ground compared to ambient, however the root response increased over the years while the shoot response decreased. Plants grown under elevated CO 2 had greater water-use efficiency compared to ambient, which was shown in higher soil moisture and greater biomass production during slightly dry years. Elevated CO 2 chambers showed higher root appearance rates in spring and higher disappearance rates during autumn and winter. Roots from plants grown under elevated CO 2 decomposed more rapidly. The decreased input and the drier conditions in the ambient chambers were projected to lead to a 1.7% decrease in soil C over 30 years. Under elevated CO 2 , however, the increased input compensated for the higher root decomposability and moister soil conditions and lead only to a projected 1.3% decrease in soil C. This work shows that six years of elevated CO 2 exposure had extensive effects on this semi-natural grassland. The CO 2 response of the grassland was dependent on weather conditions and production increased most when under slight water stress

  13. Techno-economic assessment of four CO2 storage sites = Évaluation technico-économique de quatre sites de stockage de CO2

    NARCIS (Netherlands)

    Gruson, J.F.; Serbutoviez, S.; Delprat-Jannaud, F.; Akhurst, M.; Nielsen, C.; Dalhoff, F.; Bergmo, P.; Bos, C.; Volpi, V.; Iacobellis, S.

    2015-01-01

    Carbon Capture and Storage (CCS) should be a key technology in order to achieve a decline in the CO2 emissions intensity of the power sector and other intensive industry, but this potential deployment could be restricted by cost issues as the International Energy Agency (IEA) in their last

  14. Dynamics of soil CO2 efflux under varying atmospheric CO2 concentrations reveal dominance of slow processes.

    Science.gov (United States)

    Kim, Dohyoung; Oren, Ram; Clark, James S; Palmroth, Sari; Oishi, A Christopher; McCarthy, Heather R; Maier, Chris A; Johnsen, Kurt

    2017-09-01

    We evaluated the effect on soil CO 2 efflux (F CO 2 ) of sudden changes in photosynthetic rates by altering CO 2 concentration in plots subjected to +200 ppmv for 15 years. Five-day intervals of exposure to elevated CO 2 (eCO 2 ) ranging 1.0-1.8 times ambient did not affect F CO 2 . F CO 2 did not decrease until 4 months after termination of the long-term eCO 2 treatment, longer than the 10 days observed for decrease of F CO 2 after experimental blocking of C flow to belowground, but shorter than the ~13 months it took for increase of F CO 2 following the initiation of eCO 2 . The reduction of F CO 2 upon termination of enrichment (~35%) cannot be explained by the reduction of leaf area (~15%) and associated carbohydrate production and allocation, suggesting a disproportionate contraction of the belowground ecosystem components; this was consistent with the reductions in base respiration and F CO 2 -temperature sensitivity. These asymmetric responses pose a tractable challenge to process-based models attempting to isolate the effect of individual processes on F CO2 . © 2017 John Wiley & Sons Ltd.

  15. Towards a CO2 infrastructure in North-Western Europe. Legalities, costs and organizational aspects

    International Nuclear Information System (INIS)

    Mikunda, T.; Van Deurzen, J.; Seebregts, A.J.; Kerssemakers, K.; Tetteroo, M.; Buit, L.

    2011-01-01

    This paper serves to highlight work completed within the EU FP7 CO2Europipe project, which aims to provide guidance to elements of an EU master plan for the development of large scale European CO2 infrastructure. In the last 5 years there have been some significant advancements in EU and international regulations that serve to facilitate CO2 transportation, however there is little guidance on how multi-user transport networks should be organized and financed. Poor planning and initial underinvestment in CO2 pipeline capacity can lead to inefficient networks and higher lifetime costs. Although shipping of CO2 may be a favourable transport option under certain circumstances, the monitoring and verification guidelines for this form of CO2 transportation are currently deficient. Cost estimates have been provided by industrial project members for CO2 pipelines (on/offshore), compression and shipping. Economies of scale are exhibited for pipelines, shipping and compression installations, however in order for operators to take advantage of economies of scale in pipelines, the intentions of governments regarding the regulation of tariffs for third-party network users need to be consolidated as soon as possible.

  16. Risk factors in school shootings.

    Science.gov (United States)

    Verlinden, S; Hersen, M; Thomas, J

    2000-01-01

    Nine incidents of multiple-victim homicide in American secondary schools are examined and common risk factors are identified. The literature dealing with individual, family, social, societal, and situational risk factors for youth violence and aggression is reviewed along with existing risk assessment methods. Checklists of risk factors for serious youth violence and school violence are used in reviewing each school shooting case. Commonalties among the cases and implications for psychologists practicing in clinical and school settings are discussed.

  17. Interface characteristics in Co2MnSi/Ag/Co2MnSi trilayer

    International Nuclear Information System (INIS)

    Li, Yang; Chen, Hong; Wang, Guangzhao; Yuan, Hongkuan

    2016-01-01

    Highlights: • Inferface DO 3 disorder is most favorable in Co 2 MnSi/Ag/Co 2 MnSi trilayer. • Interface itself and inferface DO 3 disorder destroy the half-metallicity of interface layers. • Magnetoresistance is reduced by the interface itself and interface disorder. • Magnetotransport coefficient is largely reduced by the interface itself and interface disorder. - Abstract: Interface characteristics of Co 2 MnSi/Ag/Co 2 MnSi trilayer have been investigated by means of first-principles. The most likely interface is formed by connecting MnSi-termination to the bridge site between two Ag atoms. As annealed at high temperature, the formation of interface DO 3 disorder is most energetically favorable. The spin polarization is reduced by both the interface itself and interface disorder due to the interface state occurs in the minority-spin gap. As a result, the magneto-resistance ratio has a sharp drop based on the estimation of a simplified modeling.

  18. CO2-ECBM and CO2 Sequestration in Polish Coal Seam – Experimental Study

    Directory of Open Access Journals (Sweden)

    Paweł Baran

    2014-01-01

    Originality/value: The results indicate successful sorption of carbon dioxide in each experiment. This provides the rationale to study the application of the coal tested to obtain methane genetic origin genetic methane with the use of the CO2 injection.

  19. DEPLETED HYDROCARBON RESERVOIRS AND CO2 INJECTION WELLS –CO2 LEAKAGE ASSESSMENT

    Directory of Open Access Journals (Sweden)

    Nediljka Gaurina-Međimurec

    2017-03-01

    Full Text Available Migration risk assessment of the injected CO2 is one of the fi rst and indispensable steps in determining locations for the implementation of projects for carbon dioxide permanent disposal in depleted hydrocarbon reservoirs. Within the phase of potential storage characterization and assessment, it is necessary to conduct a quantitative risk assessment, based on dynamic reservoir models that predict the behaviour of the injected CO2, which requires good knowledge of the reservoir conditions. A preliminary risk assessment proposed in this paper can be used to identify risks of CO2 leakage from the injection zone and through wells by quantifying hazard probability (likelihood and severity, in order to establish a risk-mitigation plan and to engage prevention programs. Here, the proposed risk assessment for the injection well is based on a quantitative risk matrix. The proposed assessment for the injection zone is based on methodology used to determine a reservoir probability in exploration and development of oil and gas (Probability of Success, abbr. POS, and modifi ed by taking into account hazards that may lead to CO2 leakage through the cap rock in the atmosphere or groundwater. Such an assessment can eliminate locations that do not meet the basic criteria in regard to short-term and long-term safety and the integrity of the site

  20. Faults as Windows to Monitor Gas Seepage: Application to CO2 Sequestration and CO2-EOR

    Directory of Open Access Journals (Sweden)

    Ronald W. Klusman

    2018-03-01

    Full Text Available Monitoring of potential gas seepage for CO2 sequestration and CO2-EOR (Enhanced Oil Recovery in geologic storage will involve geophysical and geochemical measurements of parameters at depth and at, or near the surface. The appropriate methods for MVA (Monitoring, Verification, Accounting are needed for both cost and technical effectiveness. This work provides an overview of some of the geochemical methods that have been demonstrated to be effective for an existing CO2-EOR (Rangely, CA, USA and a proposed project at Teapot Dome, WY, USA. Carbon dioxide and CH4 fluxes and shallow soil gas concentrations were measured, followed by nested completions of 10-m deep holes to obtain concentration gradients. The focus at Teapot Dome was the evaluation of faults as pathways for gas seepage in an under-pressured reservoir system. The measurements were supplemented by stable carbon and oxygen isotopic measurements, carbon-14, and limited use of inert gases. The work clearly demonstrates the superiority of CH4 over measurements of CO2 in early detection and quantification of gas seepage. Stable carbon isotopes, carbon-14, and inert gas measurements add to the verification of the deep source. A preliminary accounting at Rangely confirms the importance of CH4 measurements in the MVA application.

  1. SOLUBILITY OF ORGANIC BIOCIDES IN SUPERCRITICAL CO2 AND CO2+ COSOLVENT MIXTURES

    Science.gov (United States)

    Solubilities of four organic biocides in supercritical carbon dioxide (Sc-CO2) were measured using a dynamic flowr apparatus over a pressure range of 10 to 30 MPa and temperature of 35-80 degrees C. The biocides studied were: Amical-48 (diiodomethyl p-tolyl sulfone), chlorothalo...

  2. Enhanced transport phenomena in CO2 sequestration and CO2 EOR

    NARCIS (Netherlands)

    Farajzadeh, R.

    2009-01-01

    The results of this thesis give insight into the (mass)-transfer during flow of gases, especially CO2, in various gas-liquid systems. A number of experiments was performed to investigate the transport phenomena through interfaces with and without surfactant monolayers. The observed phenomena have

  3. Evolutionary history and novel biotic interactions determine plant responses to elevated CO2 and nitrogen fertilization.

    Directory of Open Access Journals (Sweden)

    Rachel Wooliver

    Full Text Available A major frontier in global change research is predicting how multiple agents of global change will alter plant productivity, a critical component of the carbon cycle. Recent research has shown that plant responses to climate change are phylogenetically conserved such that species within some lineages are more productive than those within other lineages in changing environments. However, it remains unclear how phylogenetic patterns in plant responses to changing abiotic conditions may be altered by another agent of global change, the introduction of non-native species. Using a system of 28 native Tasmanian Eucalyptus species belonging to two subgenera, Symphyomyrtus and Eucalyptus, we hypothesized that productivity responses to abiotic agents of global change (elevated CO2 and increased soil N are unique to lineages, but that novel interactions with a non-native species mediate these responses. We tested this hypothesis by examining productivity of 1 native species monocultures and 2 mixtures of native species with an introduced hardwood plantation species, Eucalyptus nitens, to experimentally manipulated soil N and atmospheric CO2. Consistent with past research, we found that N limits productivity overall, especially in elevated CO2 conditions. However, monocultures of species within the Symphyomyrtus subgenus showed the strongest response to N (gained 127% more total biomass in elevated CO2 conditions, whereas those within the Eucalyptus subgenus did not respond to N. Root:shoot ratio (an indicator of resource use was on average greater in species pairs containing Symphyomyrtus species, suggesting that functional traits important for resource uptake are phylogenetically conserved and explaining the phylogenetic pattern in plant response to changing environmental conditions. Yet, native species mixtures with E. nitens exhibited responses to CO2 and N that differed from those of monocultures, supporting our hypothesis and highlighting that both

  4. Multiple vantage points on the mental health effects of mass shootings.

    Science.gov (United States)

    Shultz, James M; Thoresen, Siri; Flynn, Brian W; Muschert, Glenn W; Shaw, Jon A; Espinel, Zelde; Walter, Frank G; Gaither, Joshua B; Garcia-Barcena, Yanira; O'Keefe, Kaitlin; Cohen, Alyssa M

    2014-09-01

    The phenomenon of mass shootings has emerged over the past 50 years. A high proportion of rampage shootings have occurred in the United States, and secondarily, in European nations with otherwise low firearm homicide rates; yet, paradoxically, shooting massacres are not prominent in the Latin American nations with the highest firearm homicide rates in the world. A review of the scientific literature from 2010 to early 2014 reveals that, at the individual level, mental health effects include psychological distress and clinically significant elevations in posttraumatic stress, depression, and anxiety symptoms in relation to the degree of physical exposure and social proximity to the shooting incident. Psychological repercussions extend to the surrounding affected community. In the aftermath of the deadliest mass shooting on record, Norway has been in the vanguard of intervention research focusing on rapid delivery of psychological support and services to survivors of the "Oslo Terror." Grounded on a detailed review of the clinical literature on the mental health effects of mass shootings, this paper also incorporates wide-ranging co-author expertise to delineate: 1) the patterning of mass shootings within the international context of firearm homicides, 2) the effects of shooting rampages on children and adolescents, 3) the psychological effects for wounded victims and the emergency healthcare personnel who care for them, 4) the disaster behavioral health considerations for preparedness and response, and 5) the media "framing" of mass shooting incidents in relation to the portrayal of mental health themes.

  5. Effect of CO_2 dilution on combustion and emissions characteristics of the hydrogen-enriched gasoline engine

    International Nuclear Information System (INIS)

    Wang, Shuofeng; Ji, Changwei; Zhang, Bo; Cong, Xiaoyu; Liu, Xiaolong

    2016-01-01

    CO_2 (Carbon dioxide) dilution is a feasible way for controlling NOx (Nitrogen oxides) emissions and loads of the internal combustion engines. This paper investigated the effect of CO_2 dilution on the combustion and emissions characteristics of a hydrogen-enriched gasoline engine. The experiment was conducted on a 1.6 L spark-ignition engine with electronically controlled hydrogen and gasoline injection systems. At two hydrogen volume fractions of 0 and 3%, the CO_2 volume fraction in the intake was gradually increased from 0 to 4%. The fuel-air mixtures were kept at the stoichiometric. The experimental results demonstrated that brake mean effective pressure of the gasoline engine was quickly reduced after adopting CO_2 dilution. Comparatively, Bmep (Brake mean effective pressure) of the 3% hydrogen-enriched engine was gently decreased with the increase of CO_2 dilution level. Thermal efficiency of the 3% hydrogen-enriched gasoline engine was raised under properly increased CO_2 dilution levels. However, thermal efficiency of the pure gasoline engine was generally dropped after the CO_2 dilution. The addition of hydrogen could shorten flame development and propagation durations under CO_2 diluent conditions for the gasoline engine. Increasing CO_2 fraction in the intake caused the dropped NOx and raised HC (Hydrocarbon) emissions. Increasing hydrogen fraction in the intake could effectively reduce HC emissions under CO_2 diluent conditions. - Highlights: • CO_2 dilution reduces cooling loss and NOx of H_2-enriched gasoline engines. • H_2-blended gasoline engine gains better efficiency after CO_2 dilution. • CoVimep of H_2-blended gasoline engine is kept at low level after CO_2 addition. • CO_2 dilution has small effect on reducing Bmep of H_2-blended gasoline engine.

  6. Decontamination of solid matrices using supercritical CO2: study of contaminant-additives-CO2

    International Nuclear Information System (INIS)

    Galy, J.

    2006-11-01

    This work deals with the decontamination of solid matrices by supercritical CO 2 and more particularly with the study of the interactions between the surfactants and the CO 2 in one part, and with the interactions between the contaminant and the surfactants in another part. The first part of this study has revealed the different interactions between the Pluronics molecules and the supercritical CO 2 . The diagrams graphs have shown that the pluronics (PE 6100, PE 8100 and PE 10100) present a solubility in the supercritical CO 2 low but sufficient (0.1% m/m at 25 MPa and 313 K) for the studied application: the treatment of weak quantities of cerium oxide (or plutonium). An empirical approach based on the evolutions of the slops value and of the origin ordinates of the PT diagrams has been carried out to simulate the phase diagrams PT of the Pluronics. A modeling based on the state equations 'SAFT' (Statistical Associating Fluid Theory) has been studied in order to confirm the experimental results of the disorder points and to understand the role of the different blocks 'PEO' and 'PPO' in the behaviour of Pluronics; this modeling confirms the evolution of the slopes value with the 'CO 2 -phily' of the system. The measure of the surface tension in terms of the Pluronics concentration (PE 6100, 81000 and 10100) has shown different behaviours. For the PE 6100, the surface tension decreases when the surfactant concentration increases (at constant pressure and temperature); on the other hand, for the PE 8100 a slop rupture appears and corresponds to the saturation of the interface water/CO 2 and allows then to determine the Interface Saturation Concentration (ISC). The ISC value (at constant pressure and temperature) increases with an increase of the 'CO 2 -phily'). The model hydrophilous medium being an approximation, it has been replaced by a solid polar phase of CeO 2 . A parallel has been established between the evolution of the surface tension between the water and

  7. CO2 maximum in the oxygen minimum zone (OMZ

    Directory of Open Access Journals (Sweden)

    V. Garçon

    2011-02-01

    Full Text Available Oxygen minimum zones (OMZs, known as suboxic layers which are mainly localized in the Eastern Boundary Upwelling Systems, have been expanding since the 20th "high CO2" century, probably due to global warming. OMZs are also known to significantly contribute to the oceanic production of N2O, a greenhouse gas (GHG more efficient than CO2. However, the contribution of the OMZs on the oceanic sources and sinks budget of CO2, the main GHG, still remains to be established. We present here the dissolved inorganic carbon (DIC structure, associated locally with the Chilean OMZ and globally with the main most intense OMZs (O2−1 in the open ocean. To achieve this, we examine simultaneous DIC and O2 data collected off Chile during 4 cruises (2000–2002 and a monthly monitoring (2000–2001 in one of the shallowest OMZs, along with international DIC and O2 databases and climatology for other OMZs. High DIC concentrations (>2225 μmol kg−1, up to 2350 μmol kg−1 have been reported over the whole OMZ thickness, allowing the definition for all studied OMZs a Carbon Maximum Zone (CMZ. Locally off Chile, the shallow cores of the OMZ and CMZ are spatially and temporally collocated at 21° S, 30° S and 36° S despite different cross-shore, long-shore and seasonal configurations. Globally, the mean state of the main OMZs also corresponds to the largest carbon reserves of the ocean in subsurface waters. The CMZs-OMZs could then induce a positive feedback for the atmosphere during upwelling activity, as potential direct local sources of CO2. The CMZ paradoxically presents a slight "carbon deficit" in its core (~10%, meaning a DIC increase from the oxygenated ocean to the OMZ lower than the corresponding O2 decrease (assuming classical C/O molar ratios. This "carbon deficit" would be related to regional thermal mechanisms affecting faster O2 than DIC (due to the carbonate buffer effect and occurring upstream in warm waters (e.g., in the Equatorial Divergence

  8. CO2 maximum in the oxygen minimum zone (OMZ)

    Science.gov (United States)

    Paulmier, A.; Ruiz-Pino, D.; Garçon, V.

    2011-02-01

    Oxygen minimum zones (OMZs), known as suboxic layers which are mainly localized in the Eastern Boundary Upwelling Systems, have been expanding since the 20th "high CO2" century, probably due to global warming. OMZs are also known to significantly contribute to the oceanic production of N2O, a greenhouse gas (GHG) more efficient than CO2. However, the contribution of the OMZs on the oceanic sources and sinks budget of CO2, the main GHG, still remains to be established. We present here the dissolved inorganic carbon (DIC) structure, associated locally with the Chilean OMZ and globally with the main most intense OMZs (O2Chile during 4 cruises (2000-2002) and a monthly monitoring (2000-2001) in one of the shallowest OMZs, along with international DIC and O2 databases and climatology for other OMZs. High DIC concentrations (>2225 μmol kg-1, up to 2350 μmol kg-1) have been reported over the whole OMZ thickness, allowing the definition for all studied OMZs a Carbon Maximum Zone (CMZ). Locally off Chile, the shallow cores of the OMZ and CMZ are spatially and temporally collocated at 21° S, 30° S and 36° S despite different cross-shore, long-shore and seasonal configurations. Globally, the mean state of the main OMZs also corresponds to the largest carbon reserves of the ocean in subsurface waters. The CMZs-OMZs could then induce a positive feedback for the atmosphere during upwelling activity, as potential direct local sources of CO2. The CMZ paradoxically presents a slight "carbon deficit" in its core (~10%), meaning a DIC increase from the oxygenated ocean to the OMZ lower than the corresponding O2 decrease (assuming classical C/O molar ratios). This "carbon deficit" would be related to regional thermal mechanisms affecting faster O2 than DIC (due to the carbonate buffer effect) and occurring upstream in warm waters (e.g., in the Equatorial Divergence), where the CMZ-OMZ core originates. The "carbon deficit" in the CMZ core would be mainly compensated locally at the

  9. Framework for Assessing Biogenic CO2 Emissions from Stationary Sources

    Science.gov (United States)

    This revision of the 2011 report, Accounting Framework for Biogenic CO2 Emissions from Stationary Sources, evaluates biogenic CO2 emissions from stationary sources, including a detailed study of the scientific and technical issues associated with assessing biogenic carbon dioxide...

  10. Vertically averaged approaches for CO 2 migration with solubility trapping

    KAUST Repository

    Gasda, S. E.; Nordbotten, J. M.; Celia, M. A.

    2011-01-01

    The long-term storage security of injected carbon dioxide (CO2) is an essential component of geological carbon sequestration operations. In the postinjection phase, the mobile CO2 plume migrates in large part because of buoyancy forces, following

  11. CO2 Capture and Storage in Coal Gasification Projects

    Science.gov (United States)

    Rao, Anand B.; Phadke, Pranav C.

    2017-07-01

    concerns about climate change problem. Carbon Capture and Storage (CCS) is being considered as a promising carbon mitigation technology, especially for large point sources such as coal power plants. Gasification of coal helps in better utilization of this resource offering multiple advantages such as pollution prevention, product flexibility (syngas and hydrogen) and higher efficiency (combined cycle). It also enables the capture of CO2 prior to the combustion, from the fuel gas mixture, at relatively lesser cost as compared to the post-combustion CO2 capture. CCS in gasification projects is considered as a promising technology for cost-effective carbon mitigation. Although many projects (power and non-power) have been announced internationally, very few large-scale projects have actually come up. This paper looks at the various aspects of CCS applications in gasification projects, including the technical feasibility and economic viability and discusses an Indian perspective. Impacts of including CCS in gasification projects (e.g. IGCC plants) have been assessed using a simulation tool. Integrated Environmental Control Model (IECM) - a modelling framework to simulate power plants - has been used to estimate the implications of adding CCS units in IGCC plants, on their performance and costs.

  12. CO2 angiography of vascular access in hemodialysis: a preliminary report

    International Nuclear Information System (INIS)

    Li Huimin; Xiao Xiangsheng; Yan Bing; Dong Sheng; Li Wentao; Dong Yonghua; Ye Chaoyang; Rong Shu

    2005-01-01

    Objective: To explore the technique and value of CO 2 angiography in surveillance of vascular access in hemodialysis. Methods: CO 2 angiography was undertaken in 10 chronic renal failure (CRF) patients with native arteriovenous fistulas for hemodialysis. The injection sites were the vein dorsale manus (n=7) and the fistula (n=3). The whole draining veins were obtained using a Toshiba DSA unit, when 40-60 ml gas were injected by hands every time. The compression on elbow and image stacking technique were used. Results: All patients had a safe examination, and the vessels on the CO 2 venogram were tubular or bubble-flow. A significant draining vein was revealed in 4 cases (3 of them injection from fistula). The elbow compression had the effect on venogram in 2 cases. All of the draining veins above the elbow were clearly visualized, and the stacking technique imp roved the display of veins. Conclusion: Internal fistula CO 2 angiography is safe, cheap, and efficacy for dialysis access surveillance. The draining veins of vascular access in CRF patients have their own characteristics, and can be best revealed by direct internal fistula CO 2 venography. CO 2 angiogram of the vascular access can be improved with various kinds of skills. (authors)

  13. An analysis of the driving forces of CO2 emissions embodied in Japan-China trade

    International Nuclear Information System (INIS)

    Dong Yanli; Ishikawa, Masanobu; Liu Xianbing; Wang Can

    2010-01-01

    By using the latest China-Japan input-output data sets and the index decomposition analysis (IDA) approach, this article analyzes the driving forces of CO 2 emissions embodied in trade between the two countries during 1990-2000. We found that the growth of trade volume had a large influence on the increase of CO 2 emissions embodiments in bilateral trade. The dramatic decline in carbon intensity of the Chinese economy is a primary cause in offsetting CO 2 emissions exported from China to Japan over 1995-2000. We argue that a better understanding of the factors affecting CO 2 emissions embodied in international trade will assist in seeking more effective climate policies with wider participation in the post-Kyoto regime.

  14. CO2 emissions, energy consumption, trade and income: A comparative analysis of China and India

    International Nuclear Information System (INIS)

    Jayanthakumaran, Kankesu; Verma, Reetu; Liu Ying

    2012-01-01

    In order to prevent the destabilisation of the Earth's biosphere, CO 2 emissions must be reduced quickly and significantly. The causes of CO 2 emissions by individual countries need to be apprehended in order to understand the processes required for reducing emissions around the globe. China and India are the two largest transitional countries and growing economies, but are in two entirely different categories in terms of structural changes in growth, trade and energy use. CO 2 emissions from the burning of fossil fuels have significantly increased in the recent past. This paper compares China and India using the bounds testing approach to cointegration and the ARDL methodology to test the long- and short-run relationships between growth, trade, energy use and endogenously determined structural breaks. The CO 2 emissions in China were influenced by per capita income, structural changes and energy consumption. A similar causal connection cannot be established for India with regard to structural changes and CO 2 emissions, because India's informal economy is much larger than China's. India possesses an extraordinarily large number of micro-enterprises that are low energy consumers and not competitive enough to reach international markets. Understanding these contrasting scenarios is prerequisite to reaching an international agreement on climate change affecting these two countries. - Highlights: ► The bounds testing approach to cointegration and the ARDL methodology were used to test CO 2 emissions–energy consumption–income–international trade nexus in China and India. ► The CO 2 emissions in China were influenced by structural changes and associated energy consumption, income and foreign trade. ► A similar causal connection (structural change) cannot be established in India. ► Understanding these contrasting scenarios is prerequisite to reaching an international agreement on climate change affecting these countries.

  15. [Effects of plastic film mulching on soil CO2 efflux and CO2 concentration in an oasis cotton field].

    Science.gov (United States)

    Yu, Yong-xiang; Zhao, Cheng-yi; Jia, Hong-tao; Yu, Bo; Zhou, Tian-he; Yang, Yu-guang; Zhao, Hua

    2015-01-01

    A field study was conducted to compare soil CO2 efflux and CO2 concentration between mulched and non-mulched cotton fields by using closed chamber method and diffusion chamber technique. Soil CO2 efflux and CO2 concentration exhibited a similar seasonal pattern, decreasing from July to October. Mulched field had a lower soil CO2 efflux but a higher CO2 concentration, compared to those of non-mulched fields. Over the measurement period, cumulative CO2 efflux was 1871.95 kg C . hm-2 for mulched field and 2032.81 kg C . hm-2 for non-mulched field. Soil CO2 concentration was higher in mulched field (ranging from 5137 to 25945 µL . L-1) than in non- mulched field (ranging from 2165 to 23986 µL . L-1). The correlation coefficients between soil CO2 concentrations at different depths and soil CO2 effluxes were 0.60 to 0.73 and 0.57 to 0.75 for the mulched and non-mulched fields, indicating that soil CO2 concentration played a crucial role in soil CO2 emission. The Q10 values were 2.77 and 2.48 for the mulched and non-mulched fields, respectively, suggesting that CO2 efflux in mulched field was more sensitive to the temperature.

  16. The Influence of CO2 Solubility in Brine on Simulation of CO2 Injection into Water Flooded Reservoir and CO2 WAG

    DEFF Research Database (Denmark)

    Yan, Wei; Stenby, Erling Halfdan

    2010-01-01

    Injection of CO2 into depleted oil reservoirs is not only a traditional way to enhance oil recovery but also a relatively cheaper way to sequester CO2 underground since the increased oil production can offset some sequestration cost. CO2 injection process is often applied to water flooded...... simulations were made for seven oil samples within a wide range of temperature, pressure and salinity. The results were analyzed in terms of the change in oil recovery due to different phase equilibrium descriptions, the delay in breakthrough and the CO2 lost to the aqueous phase. The influence of different...

  17. CO2 in Alberta - a vision of the future

    International Nuclear Information System (INIS)

    Edwards, K.

    1999-01-01

    The potential to develop a province-wide infrastructure for carbon dioxide (CO 2 ) collection and transmission was discussed. The petroleum industry's original interest in CO 2 was its potential for enhanced oil recovery (EOR) for Alberta's depleted oil fields. However, new interest has stemmed from its perceived role in global climate change and the potentially negative business and economic implications of emitting CO 2 into the atmosphere. It was suggested that the development of a province wide infrastructure to collect CO 2 would address both interests. A simple screening of the reservoirs was carried out to determine if Alberta has the right oil reservoirs and sufficient CO 2 supplies to support a large-scale CO 2 infrastructure. The proposed infrastructure would consist of CO 2 supplies from electrical power generation plants, CO 2 trunklines, feeder pipelines to deliver CO 2 from the trunklines to the field and the oil reservoirs where the CO 2 would be injected. Such infrastructures already exist in Texas and Mexico where more than 1 billion scf per day of CO 2 is used for EOR. This study compared the factors leading to a large-scale CO 2 industry with factors in place during the 1970s and 1980s, when most of the hydrocarbon miscible floods were initiated in Alberta. It was concluded that the preliminary economics suggest that the concept has merit. 12 refs., 3 tabs., 9 figs

  18. Polyether based block copolymer membranes for CO2 separation

    NARCIS (Netherlands)

    Reijerkerk, Sander

    2010-01-01

    The work described in this thesis is dedicated to the development of polymeric membrane materials for the separation of CO2 from light gases, and in particular to the separation of CO2 from nitrogen as required in a post-combustion capture conguration for the separation of CO2 from flue gases. An

  19. Effect of CO2 supply strategy on specific energy consumption

    NARCIS (Netherlands)

    Zwart, de H.F.

    1998-01-01

    This paper studies the effect of CO2-dosing with exhaust gases on the efficiency of glasshouse tomato production. The paper shows that it can be recommended to ensure a continuing CO2 supply during the warm period. The discussion focuses on exhaust gases as a CO2 source, but the results also

  20. A model for estimating CO2 solubility in aqueous alkanolamines

    DEFF Research Database (Denmark)

    Gabrielsen, Jostein; Michelsen, Michael Locht; Stenby, Erling Halfdan

    2005-01-01

    of CO2 over an aqueous alkanolamine solution. Accurate values for the partial pressure of CO2 are obtained for a limited loading, temperature, and pressure range that is useful in modeling CO2 capture from coal-fired power plants. Heat of absorption values derived from the model agree with experimental...

  1. Detection Test for Leakage of CO2 into Sodium Loop

    International Nuclear Information System (INIS)

    Park, Sun Hee; Wi, Myung-Hwan; Min, Jae Hong

    2015-01-01

    This report is about the facility for the detection test for leakage of CO 2 into sodium loop. The facility for the detection test for leakage of CO 2 into sodium loop was introduced. The test will be carried out. Our experimental results are going to be expected to be used for approach methods to detect CO 2 leaking into sodium in heat exchangers. A sodium-and-carbon dioxide (Na-CO 2 ) heat exchanger is one of the key components for the supercritical CO 2 Brayton cycle power conversion system of sodium-cooled fast reactors (SFRs). A printed circuit heat exchanger (PCHE) is considered for the Na-CO 2 heat exchanger, which is known to have potential for reducing the volume occupied by the exchangers compared to traditional shell-and-tube heat exchangers. Among various issues about the Na- CO 2 exchanger, detection of CO 2 leaking into sodium in the heat exchanger is most important thing for its safe operation. It is known that reaction products from sodium and CO 2 such as sodium carbonate (Na 2 CO 3 ) and amorphous carbon are hardly soluble in sodium, which cause plug sodium channels. Detection technique for Na 2 CO 3 in sodium loop has not been developed yet. Therefore, detection of CO 2 and CO from reaction of sodium and CO 2 are proper to detect CO 2 leakage into sodium loop

  2. CO2 emission trade from a fiscal perspective

    International Nuclear Information System (INIS)

    Klaassen, F.A.H.; Derksen, R.T.; Keijel, J.J.C.

    2004-06-01

    The report gives answers to questions as 'are CO2 emission permits assets or supplies?'; how to deal with forward contracts and options in CO2 emission permits 'fiscal-wise'; and 'which are the consequences of CO2 emissions trade for the rebate of pre-taxes?' Als attention is paid to trading system for NOx emission [nl

  3. The Level of Vision Necessary for Competitive Performance in Rifle Shooting: Setting the Standards for Paralympic Shooting with Vision Impairment.

    Science.gov (United States)

    Allen, Peter M; Latham, Keziah; Mann, David L; Ravensbergen, Rianne H J C; Myint, Joy

    2016-01-01

    The aim of this study was to investigate the level of vision impairment (VI) that would reduce performance in shooting; to guide development of entry criteria to visually impaired (VI) shooting. Nineteen international-level shooters without VI took part in the study. Participants shot an air rifle, while standing, toward a regulation target placed at the end of a 10 m shooting range. Cambridge simulation glasses were used to simulate six different levels of VI. Visual acuity (VA) and contrast sensitivity (CS) were assessed along with shooting performance in each of seven conditions of simulated impairment and compared to that with habitual vision. Shooting performance was evaluated by calculating each individual's average score in every level of simulated VI and normalizing this score by expressing it as a percentage of the baseline performance achieved with habitual vision. Receiver Operating Characteristic curves were constructed to evaluate the ability of different VA and CS cut-off criteria to appropriately classify these athletes as achieving 'expected' or 'below expected' shooting results based on their performance with different levels of VA and CS. Shooting performance remained relatively unaffected by mild decreases in VA and CS, but quickly deteriorated with more moderate losses. The ability of visual function measurements to classify shooting performance was good, with 78% of performances appropriately classified using a cut-off of 0.53 logMAR and 74% appropriately classified using a cut-off of 0.83 logCS. The current inclusion criteria for VI shooting (1.0 logMAR) is conservative, maximizing the chance of including only those with an impairment that does impact performance, but potentially excluding some who do have a genuine impairment in the sport. A lower level of impairment would include more athletes who do have a genuine impairment but would potentially include those who do not actually have an impairment that impacts performance in the sport. An

  4. The Level of Vision Necessary for Competitive Performance in Rifle Shooting: Setting the Standards for Paralympic Shooting With Vision Impairment

    Directory of Open Access Journals (Sweden)

    Peter M Allen

    2016-11-01

    Full Text Available The aim of this study was to investigate the level of vision impairment that would reduce performance in shooting; to guide development of entry criteria to visually impaired (VI shooting. Nineteen international-level shooters without vision impairment took part in the study. Participants shot an air rifle, while standing, towards a regulation target placed at the end of a 10m shooting range. Cambridge simulation glasses were used to simulate six different levels of vision impairment. Visual acuity (VA and contrast sensitivity (CS were assessed along with shooting performance in each of seven conditions of simulated impairment and compared to that with habitual vision. Shooting performance was evaluated by calculating each individual’s average score in every level of simulated vision impairment and normalising this score by expressing it as a percentage of the baseline performance achieved with habitual vision. Receiver Operating Characteristic (ROC curves were constructed to evaluate the ability of different VA and CS cut-off criteria to appropriately classify these athletes as achieving ‘expected’ or ‘below expected’ shooting results based on their performance with different levels of VA and CS. Shooting performance remained relatively unaffected by mild decreases in VA and CS, but quickly deteriorated with more moderate losses. The ability of visual function measurements to classify shooting performance was good, with 78% of performances appropriately classified using a cut-off of 0.53 logMAR and 74% appropriately classified using a cut-off of 0.83 logCS. The current inclusion criteria for VI shooting (1.0 logMAR is conservative, maximising the chance of including only those with an impairment that does impact performance, but potentially excluding some who do have a genuine impairment in the sport. A lower level of impairment would include more athletes who do have a genuine impairment but would potentially include those who do not

  5. Elevated CO2-mitigation of high temperature stress associated with maintenance of positive carbon balance and carbohydrate accumulation in Kentucky bluegrass.

    Science.gov (United States)

    Song, Yali; Yu, Jingjin; Huang, Bingru

    2014-01-01

    Elevated CO2 concentration may promote plant growth while high temperature is inhibitory for C3 plant species. The interactive effects of elevated CO2 and high temperatures on C3 perennial grass growth and carbon metabolism are not well documented. Kentucky bluegrass (Poa pratensis) plants were exposed to two CO2 levels (400 and 800 μmol mol-1) and five temperatures (15/12, 20/17, 25/22, 30/27, 35/32°C, day/night) in growth chambers. Increasing temperatures to 25°C and above inhibited leaf photosynthetic rate (Pn) and shoot and root growth, but increased leaf respiration rate (R), leading to a negative carbon balance and a decline in soluble sugar content under ambient CO2. Elevated CO2 did not cause shift of optimal temperatures in Kentucky bluegrass, but promoted Pn, shoot and root growth under all levels of temperature (15, 20, 25, 30, and 35°C) and mitigated the adverse effects of severe high temperatures (30 and 35°C). Elevated CO2-mitigation of adverse effects of high temperatures on Kentucky bluegrass growth could be associated with the maintenance of a positive carbon balance and the accumulation of soluble sugars and total nonstructural carbohydrates through stimulation of Pn and suppression of R and respiratory organic acid metabolism.

  6. Advanced turbine/CO2 pellet accelerator

    International Nuclear Information System (INIS)

    Foster, C.A.; Fisher, P.W.

    1994-01-01

    An advanced turbine/CO 2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory. The program, sponsored by Warner Robins Air Logistics Center, Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air sandblast pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies. Applications include removal of epoxy-based points from aircraft and the cleaning of surfaces contaminated with toxic, hazardous, or radioactive substances. The lack of a secondary contaminated waste stream is of great benefit

  7. Charcoal cuts the CO2-emissions

    International Nuclear Information System (INIS)

    Aakervik, Anne Lise.

    1999-01-01

    According to this article, bio carbon, or charcoal, may be the way out for the Norwegian processing industry in attempting to reduce the emission of carbon dioxide. Norwegian ferro-alloy plants emit 3 million ton carbon dioxide per year, which comes from the use of coal and coke as reducing agents in the smelting process. If the fraction of bio carbon is increased by 15%, the emission of CO 2 may be reduced by about 1/2 million tonne per year. But the price of charcoal is much greater than that of fix C from coal and coke. Research is in progress on trying to produce bio carbon cheaper. Charcoal can be produced from all types of forest by pyrolysis. Waste heat from the pyrolysis can be sold and used for district heating. The most expensive part in the use of bio carbon will be timber felling and transport to the log pile. Small-scale and large-scale tests will be made to see if it is possible to make adequate charcoal from subarctic timber

  8. A centrifuge CO2 pellet cleaning system

    Science.gov (United States)

    Foster, C. A.; Fisher, P. W.; Nelson, W. D.; Schechter, D. E.

    1995-01-01

    An advanced turbine/CO2 pellet accelerator is being evaluated as a depaint technology at Oak Ridge National Laboratory (ORNL). The program, sponsored by Warner Robins Air Logistics Center (ALC), Robins Air Force Base, Georgia, has developed a robot-compatible apparatus that efficiently accelerates pellets of dry ice with a high-speed rotating wheel. In comparison to the more conventional compressed air 'sandblast' pellet accelerators, the turbine system can achieve higher pellet speeds, has precise speed control, and is more than ten times as efficient. A preliminary study of the apparatus as a depaint technology has been undertaken. Depaint rates of military epoxy/urethane paint systems on 2024 and 7075 aluminum panels as a function of pellet speed and throughput have been measured. In addition, methods of enhancing the strip rate by combining infra-red heat lamps with pellet blasting and by combining the use of environmentally benign solvents with the pellet blasting have also been studied. The design and operation of the apparatus will be discussed along with data obtained from the depaint studies.

  9. CO2 Emission Reduction in Energy Sector

    International Nuclear Information System (INIS)

    Bole, A.; Sustersic, A.; Voncina, R.

    2013-01-01

    Due to human activities, concentrations of the greenhouse gases increase in the atmosphere much quicker than they naturally would. Today it is clear that climate change is the result of human activities. With the purpose of preventing, reducing and mitigating of climate change, the EU, whose member is also Slovenia, set ambitious goals. In order to keep rise of the global atmosphere temperature below 2 degrees of C, the European Council set an objective of reducing greenhouse gas emissions by 80 - 95 % by 2050 compared to 1990. It is important that every single individual is included in achieving of these goals. Certainly, the most important role is assumed by individual sectors especially Public Electricity and Heat Production sector as one of the greatest emitters of the greenhouse gases. As a possible solution of radical reduction of the greenhouse gases emission from mentioned sector Carbon Capture and Storage (CCS) technology is implemented. In the article the range of CO 2 reduction possibilities, technology demands and environmental side effects of CCS technology are described. Evaluation of CCS implementation possibilities in Slovenia is also included.(author)

  10. DF--CO2 transfer laser development

    International Nuclear Information System (INIS)

    Tregay, G.W.; Drexhage, M.G.; Wood, L.M.; Andrysiak, S.J.

    1975-01-01

    Power extraction and chemiluminescence experiments have been conducted in the large-scale DF-CO 2 transfer chemical laser (TCL) (IRIS-I and IRIS-II) facility at Bell Aerospace Company (BAC). The modular design of the device allowed testing to be conducted with both a supersonic nozzle bank and also in subsonic flow with sonic injection for the deuterium. Power levels of 15 kW at 10.6 μ were obtained in IRIS-I (subsonic) employing an unstable resonator with a 50 percent output coupling ratio and cavity pressure of 35 torr. For IRIS-II (supersonic) somewhat lower power was obtained. In both systems the fluorine dissociation (α = F/F + 2F 2 ) was less than 0.01. Chemiluminescent emission from HF and DF was monitored under zero-power conditions along an axis parallel to the laser-mirror axis. From the measured DF-concentration profiles it can be inferred that vibrationally excited DF is being produced throughout the cavity and, accordingly, the production of DF must be attributed largely to the chain reaction

  11. Differential response of hexaploid and tetraploid wheat to interactive effects of elevated [CO2] and low phosphorus.

    Science.gov (United States)

    Pandey, Renu; Lal, Milan Kumar; Vengavasi, Krishnapriya

    2018-06-04

    Hexaploid wheat is more responsive than tetraploid to the interactive effects of elevated [CO 2 ] and low P in terms of carboxylate efflux, enzyme activity and gene expression (TaPT1 and TaPAP). Availability of mineral nutrients to plants under changing climate has become a serious challenge to food security and economic development. An understanding of how elevated [CO 2 ] influences phosphorus (P) acquisition processes at the whole-plant level would be critical in selecting cultivars as well as to maintain optimum yield in limited-P conditions. Wheat (Triticum aestivum and T. durum) grown hydroponically with sufficient and low P concentration were exposed to elevated and ambient [CO 2 ]. Improved dry matter partitioning towards root resulted in increased root-to-shoot ratio, root length, volume, surface area, root hair length and density at elevated [CO 2 ] with low P. Interaction of low P and [CO 2 ] induced activity of enzymes (phosphoenolpyruvate carboxylase, malate dehydrogenase and citrate synthase) in root tissue resulting in twofold increase in carboxylates and acid phosphatase exudation. Physiological absorption capacity of roots showed that plants alter their uptake kinetics by increasing affinity (low K m ) in response to elevated [CO 2 ] under low P supply. Increased relative expression of genes, purple acid phosphatase (TaPAP) and high-affinity Pi transporter (TaPT1) in roots induced by elevated [CO 2 ] and low P supported our physiological observations. Hexaploid wheat (PBW-396) being more responsive to elevated [CO 2 ] at low P supply as compared to tetraploid (PDW-233) necessitates the ploidy effect to be explored further which might be advantageous under changing climate.

  12. Energy solutions for CO2 emission peak and subsequent decline

    DEFF Research Database (Denmark)

    Risø International Energy Conference 2009 took place 14 – 16 September 2009. The conference focused on: • Future global energy development options Scenario and policy issues • Measures to achieve CO2 emission peak in 2015 – 2020 and subsequent decline • Renewable energy supply technologies...... such as bioenergy, wind and solar • Centralized energy technologies such as clean coal technologies • Energy conversion, energy carriers and energy storage, including fuel cells and hydrogen technologies • Providing renewable energy for the transport sector • Systems aspects for the various regions throughout...... the world • End-use technologies, efficiency improvements in supply and end use • Energy savings The proceedings are prepared from papers presented at the conference and received with corrections, if any, until the final deadline on 3 August 2009....

  13. Lateral diffusion of CO2 in leaves of the crassulacean acid metabolism plant Kalanchoe daigremontiana Hamet et Perrier.

    Science.gov (United States)

    Duarte, Heitor M; Jakovljevic, Ivona; Kaiser, Friedemann; Lüttge, Ulrich

    2005-04-01

    Dynamic patchiness of photosystem II (PSII) activity in leaves of the crassulacean acid metabolism (CAM) plant Kalanchoe daigremontiana Hamet et Perrier, which was independent of stomatal control and was observed during both the day/night cycle and circadian endogenous oscillations of CAM, was previously explained by lateral CO2 diffusion and CO2 signalling in the leaves [Rascher et al. (2001) Proc Natl Acad Sci USA 98:11801-11805; Rascher and Luttge (2002) Plant Biol 4:671-681]. The aim here was to actually demonstrate the importance of lateral CO2 diffusion and its effects on localized PSII activity. Covering small sections of entire leaves with silicone grease was used for local exclusion of a contribution of atmospheric CO2 to internal CO2 via transport through stomata. A setup for combined measurement of gas exchange and chlorophyll fluorescence imaging was used for recording photosynthetic activity with a spatiotemporal resolution. When remobilization of malic acid from vacuolar storage and its decarboxylation in the CAM cycle caused increasing internal CO2 concentrations sustaining high PSII activity behind closed stomata, PSII activity was also increased in adjacent leaf sections where vacuolar malic acid accumulation was minimal as a result of preventing external CO2 supply due to leaf-surface greasing, and where therefore CO2 could only be supplied by diffusion from the neighbouring malic acid-remobilizing leaf tissue. This demonstrates lateral CO2 diffusion and its effect on local photosynthetic activity.

  14. Determining CO2 storage potential during miscible CO2 enhanced oil recovery: Noble gas and stable isotope tracers

    Science.gov (United States)

    Shelton, Jenna L.; McIntosh, Jennifer C.; Hunt, Andrew; Beebe, Thomas L; Parker, Andrew D; Warwick, Peter D.; Drake, Ronald; McCray, John E.

    2016-01-01

    Rising atmospheric carbon dioxide (CO2) concentrations are fueling anthropogenic climate change. Geologic sequestration of anthropogenic CO2 in depleted oil reservoirs is one option for reducing CO2 emissions to the atmosphere while enhancing oil recovery. In order to evaluate the feasibility of using enhanced oil recovery (EOR) sites in the United States for permanent CO2 storage, an active multi-stage miscible CO2flooding project in the Permian Basin (North Ward Estes Field, near Wickett, Texas) was investigated. In addition, two major natural CO2 reservoirs in the southeastern Paradox Basin (McElmo Dome and Doe Canyon) were also investigated as they provide CO2 for EOR operations in the Permian Basin. Produced gas and water were collected from three different CO2 flooding phases (with different start dates) within the North Ward Estes Field to evaluate possible CO2 storage mechanisms and amounts of total CO2retention. McElmo Dome and Doe Canyon were sampled for produced gas to determine the noble gas and stable isotope signature of the original injected EOR gas and to confirm the source of this naturally-occurring CO2. As expected, the natural CO2produced from McElmo Dome and Doe Canyon is a mix of mantle and crustal sources. When comparing CO2 injection and production rates for the CO2 floods in the North Ward Estes Field, it appears that CO2 retention in the reservoir decreased over the course of the three injections, retaining 39%, 49% and 61% of the injected CO2 for the 2008, 2010, and 2013 projects, respectively, characteristic of maturing CO2 miscible flood projects. Noble gas isotopic composition of the injected and produced gas for the flood projects suggest no active fractionation, while δ13CCO2 values suggest no active CO2dissolution into formation water, or mineralization. CO2 volumes capable of dissolving in residual formation fluids were also estimated along with the potential to store pure-phase supercritical CO2. Using a combination

  15. The feasibility of domestic CO2 emissions trading in Poland

    International Nuclear Information System (INIS)

    Missfeldt, F.; Hauff, J.

    2000-09-01

    refineries, and with them the growing CO 2 emissions from transport, seem possible. Such a pilot program would allow firms and the policy maker to gather relevant experiences for the possible future introduction of a comprehensive system and for the emerging international emissions trading system. To determine whether a pilot system is desirable, however, an extensive and comparative analysis of different climate protection policy options is still needed for Poland. It should include a close look at the implications of EU climate protection policies and the effects of the liberalization of international electricity markets on domestic policy options. (au)

  16. El CO2 como disolvente y como reactivo

    OpenAIRE

    La Franca Pitarresi, Vincenzo Rosario

    2016-01-01

    Existen numerosas ventajas asociada con el uso de CO2 , tanto como disolvente que como reactivo, y todas se pueden resumir en cuatro categorías generales: beneficios ambiental, beneficios de salud y seguridad, beneficios en el procedimiento y beneficios químicos. Los procesos que implican el CO2 como disolvente no aumentaría las emisiones de CO2, más bien proporcionaría una oportunidad para el reciclaje de CO2 residual. Además, los esfuerzos para secuestrar el CO2 producido de los gases de co...

  17. Least cost planning for CO2-reduction strategies

    International Nuclear Information System (INIS)

    Seifritz, W.

    1990-01-01

    A first recommendation for the determination of the minimum costs for a carbon-dioxide reduction strategy is presented. For this, the tabulation of so-called, 'CO 2 -ranking-lists', containing the relationship between the costs of a distinct measure to avoid the emission of certain amount of CO 2 (in dollar/t CO 2 ) versus its potential (in t CO 2 /yr), is indispensable. Some basic aspects of this approach are discussed and a first guess of the costs of some measures to avoid CO 2 -emissions into the atmosphere is presented. (orig.) [de

  18. The effects of CO2-differentiated vehicle tax systems on car choice, CO2 emissions and tax revenues

    NARCIS (Netherlands)

    Kok, R.

    2011-01-01

    This paper assesses the impacts of a CO2-differentiated tax policy designed to influence car purchasing trends towards lower CO2 emitting vehicles in the Netherlands. Since 2009, gasoline and diesel cars up to 110 and 95 gram CO2 per km are exempted from the vehicle registration tax (VRT). In

  19. Modeling CO2 Storage in Fractured Reservoirs: Fracture-Matrix Interactions of Free-Phase and Dissolved CO2

    Science.gov (United States)

    Oldenburg, C. M.; Zhou, Q.; Birkholzer, J. T.

    2017-12-01

    The injection of supercritical CO2 (scCO2) in fractured reservoirs has been conducted at several storage sites. However, no site-specific dual-continuum modeling for fractured reservoirs has been reported and modeling studies have generally underestimated the fracture-matrix interactions. We developed a conceptual model for enhanced CO2 storage to take into account global scCO2 migration in the fracture continuum, local storage of scCO2 and dissolved CO2 (dsCO2) in the matrix continuum, and driving forces for scCO2 invasion and dsCO2 diffusion from fractures. High-resolution discrete fracture-matrix models were developed for a column of idealized matrix blocks bounded by vertical and horizontal fractures and for a km-scale fractured reservoir. The column-scale simulation results show that equilibrium storage efficiency strongly depends on matrix entry capillary pressure and matrix-matrix connectivity while the time scale to reach equilibrium is sensitive to fracture spacing and matrix flow properties. The reservoir-scale modeling results shows that the preferential migration of scCO2 through fractures is coupled with bulk storage in the rock matrix that in turn retards the fracture scCO2 plume. We also developed unified-form diffusive flux equations to account for dsCO2 storage in brine-filled matrix blocks and found solubility trapping is significant in fractured reservoirs with low-permeability matrix.

  20. CO2 niet meer dan genoeg: Teelt van Tomaat in 2012 bij Improvement Centre met lichtafhankelijk doseren van CO2

    NARCIS (Netherlands)

    Gelder, de A.; Warmenhoven, M.G.; Dieleman, J.A.; Klapwijk, P.; Baar, van P.H.

    2014-01-01

    Wageningen UR Glastuinbouw heeft met financiering van Kas als Energiebron en Samenwerken aan Vaardigheden onderzoek gedaan naar efficienter gebruik van CO2. In een kasproef bij GreenQ/Improvement Centre is een CO2 doseerstrategie getest, waarbij iets meer CO2 wordt gegeven dan er op basis van de

  1. Detection of CO2 leaks from carbon capture and storage sites with combined atmospheric CO2 and O-2 measurements

    NARCIS (Netherlands)

    van Leeuwen, Charlotte; Meijer, Harro A. J.

    2015-01-01

    This paper presents a transportable instrument that simultaneously measures the CO2 and (relative) O-2 concentration of the atmosphere with the purpose to aid in the detection of CO2 leaks from CCS sites. CO2 and O-2 are coupled in most processes on earth (e.g., photosynthesis, respiration and

  2. Recent global CO2 flux inferred from atmospheric CO2 observations and its regional analyses

    Directory of Open Access Journals (Sweden)

    J. M. Chen

    2011-11-01

    Full Text Available The net surface exchange of CO2 for the years 2002–2007 is inferred from 12 181 atmospheric CO2 concentration data with a time-dependent Bayesian synthesis inversion scheme. Monthly CO2 fluxes are optimized for 30 regions of the North America and 20 regions for the rest of the globe. Although there have been many previous multiyear inversion studies, the reliability of atmospheric inversion techniques has not yet been systematically evaluated for quantifying regional interannual variability in the carbon cycle. In this study, the global interannual variability of the CO2 flux is found to be dominated by terrestrial ecosystems, particularly by tropical land, and the variations of regional terrestrial carbon fluxes are closely related to climate variations. These interannual variations are mostly caused by abnormal meteorological conditions in a few months in the year or part of a growing season and cannot be well represented using annual means, suggesting that we should pay attention to finer temporal climate variations in ecosystem modeling. We find that, excluding fossil fuel and biomass burning emissions, terrestrial ecosystems and oceans absorb an average of 3.63 ± 0.49 and 1.94 ± 0.41 Pg C yr−1, respectively. The terrestrial uptake is mainly in northern land while the tropical and southern lands contribute 0.62 ± 0.47, and 0.67 ± 0.34 Pg C yr−1 to the sink, respectively. In North America, terrestrial ecosystems absorb 0.89 ± 0.18 Pg C yr−1 on average with a strong flux density found in the south-east of the continent.

  3. Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Grigg, Reid B.; Schechter, David S.

    1999-10-15

    The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

  4. Photosynthetic responses of yellow poplar and white oak to long term atmospheric CO2 enrichment in the field

    International Nuclear Information System (INIS)

    Gunderson, C.A.; Norby, R.J.

    1991-01-01

    A critical consideration in evaluating forest response to rising atmospheric CO 2 is whether the enhancement of net photosynthesis (P N ) by elevated CO 2 can be sustained over the long term. There are reports of declining enhancement of P N with duration of exposure to elevated CO 2 , associated with decreases in photosynthetic capacity and carboxylation efficiency. We investigated whether this photosynthetic acclimation occurs in two tree species under field conditions. Seedlings of yellow-poplar (Liriodendron tulipifera L.) and white oak (Quercus alba L.) were planted in the ground within six open-top field chambers in May 1989 and have been exposed continuously to CO 2 enrichment during the last two growing seasons. The three CO 2 treatment levels were: ambient, ambient +150, and ambient +300 μL/L. Throughout the second season, gas exchange of upper, light-saturated leaves was surveyed periodically, and leaves of different ages and canopy positions were measured occasionally. Net photosynthesis remained higher at higher CO 2 levels (28-32% higher in +150 and 49-67% higher in +300 seedlings) in both species throughout the season, regardless of increasing leaf age and duration of exposure to CO 2 enrichment. Stomatal conductance remained unchanged or decreased slightly with increasing CO 2 , but instantaneous water use efficiency (P N /transpiration) increased significantly with CO 2 . Analysis of P N versus internal CO 2 concentration indicated no significant treatment differences in carboxylation efficiency, CO 2 -saturated P N , or CO 2 compensation point. There was no evidence of a downward acclimation of photosynthesis to CO 2 enrichment in this system

  5. CO2 reforming of methane: valorizing CO2 by means of Dielectric Barrier Discharge

    Science.gov (United States)

    Machrafi, H.; Cavadias, S.; Amouroux, J.

    2011-03-01

    The impact of pollution on the environment is causing several problems that are to be reduced as much as possible. One important example is the production of CO2 that is emitted by many transport and industrial applications. An interesting solution is to view CO2 as a source instead of a product that can be stocked. The case considered in this work is the CO2 reformation of methane producing hydrogen and CO. It is an endothermic reaction, for which the activition barrier needs to be overcome. The method of Dielectric Barrier Discharge can do this efficiently. The process relies on the collision of electrons, which are accelerated under an electrical field that is created in the discharge area. This leads to the formation of reactive species, which facilitate the abovementioned reaction. The determination of the electron density is performed by PLASIMO. The study is subsequently continued using the Reaction Engineering module in COMSOL (with an incorporated kinetic mechanism) in order to model the discharge phase. Then COMSOL (continuity and Navier-Stokes equations) is used to model the flow in the post-discharge phase. The results showed that both a 2D and 3D model can be used to model the chemical-plasma process. These methods need strongly reduced kinetic mechanism, which in some cases can cause loss of precision. It is also observed that the present experimental set-up that is modeled needs to be improved. A suggestion is made.

  6. CO2 recovery system using solar energy; Taiyo energy wo riyoshita CO2 bunri kaishu system

    Energy Technology Data Exchange (ETDEWEB)

    Hosho, F; Naito, H; Yugami, H; Arashi, H [Tohoku University, Sendai (Japan)

    1997-11-25

    As a part of studies on chemical absorption process with MEA (monoethanolamine) for CO2 recovery from boiler waste gas in thermal power plants, use of solar heat as MEA regenerating energy was studied. An integrated stationary evacuated concentrator (ISEC) effective as collector in a medium temperature range was used to realize a regenerating temperature range of 100-120degC. ISEC is featured by vacuum insulation, use of selective absorbing membranes for an absorber, a CPC (compound parabolic concentrator)-shaped reflection mirror, and high-efficiency. An MEA regenerator is composed of an ISEC and PG(propylene glycol)-MEA heat exchanger, and circulates PG as heat medium. Heat collection experiment was also made using water instead of MEA. Both batch and continuous systems could supply a heat quantity necessary for MEA regeneration. CO2 concentration in the top of the regenerator rapidly decreased with PG circulation regenerating MEA. As mol ratios of CO2/MEA were compared between before and after regeneration, a recovery rate was estimated to be 59.4% for the batch system. 8 figs., 4 tabs.

  7. [School shooting in statu nascendi].

    Science.gov (United States)

    Knecht, Thomas

    2012-01-01

    In the last few years, amok-like killings and especially so-called "school shootings" have received a great deal of public attention both in the Old and the New world. Meanwhile, criminal psychological research has gained a thorough insight into this dangerous development in young people. Thus, the possibility to assess the concrete threat of such a multiple killing before it is carried out has been considerably improved, as many prognostic criteria have been worked out in the meantime. The case report presented shows that it is possible to exercise a favourable influence on this critical negative trend.

  8. Supercritical CO2 Compressor with Active Magnetic Bearing

    International Nuclear Information System (INIS)

    Cha, Jae Eun; Cho, Seong Kuk; Lee, JeKyoung; Lee, Jeong Ik

    2016-01-01

    For the stable operation of the sCO 2 integral test facility SCIEL, KAERI prepared Active Magnetic Bearing sCO 2 compressor for the 70,000RPM operation. Power generation test with AMB compressor will be finished within first half year of 2016 under supercritical state. The principal advantages of the sCO 2 Cycle are high efficiency at moderate temperature range, compact components size, simple cycle configuration, and compatibility with various heat sources. The Supercritical CO 2 Brayton Cycle Integral Experiment Loop (SCIEL) has been installed in Korea Atomic Energy Research Institute (KAERI) to develop the base technologies for the sCO 2 cycle power generation system. The operation of the SCIEL has mainly focused on sCO 2 compressor development and establishing sCO 2 system control logic

  9. Modeling CO2-facilitated transport across a diethanolamine liquid membrane

    Energy Technology Data Exchange (ETDEWEB)

    Lihong Bao; Michael C. Trachtenberg [Carbozyme Inc., Monmouth Junction, NJ (United States)

    2005-12-15

    We compared experimental and model data for the facilitated transport of CO2 from a CO2-air mixture across an aqueous solution of diethanolamine (DEA) via a hollow fiber, contained liquid membrane (HFCLM) permeator. A two-step carbamate formation model was devised to analyze the data instead of the one-step mechanism used by previous investigators. The effects of DEA concentration, liquid membrane thickness and feed CO2 concentration were also studied. With a 20% (wt) DEA liquid membrane and feed of 15% CO2 in CO2-air mixture at atmosphere pressure, the permeance reached 1.51E-8 mol/m{sup 2} s Pa with a CO2/N2 selectivity of 115. Model predictions compared well with the experimental results at CO2 concentrations of industrial importance. Short-term stability of the HFCLM permeator performance was examined. The system was stable during 5-days of testing.

  10. What does CO2 geological storage really mean?

    International Nuclear Information System (INIS)

    2008-01-01

    It is now accepted that human activities are disturbing the carbon cycle of the planet. CO 2 , a greenhouse gas, has accumulated in the atmosphere where it contributes to climate change. Amongst the spectrum of short term measures that need to be urgently implemented to mitigate climate change, CO 2 capture and storage can play a decisive role as it could contribute 33% of the CO 2 reduction needed by 2050. This document aims to explain this solution by answering the following questions: where and how much CO 2 can we store underground, How can we transport and inject large quantities of CO 2 , What happens to the CO 2 once in the storage reservoir? Could CO 2 leak from the reservoir and if so, what might be the consequences? How can we monitor the storage site at depth and at the surface? What safety criteria need to be imposed and respected? (A.L.B.)

  11. Impact of elevated carbon dioxide concentration and temperature on bud burst and shoot growth of boreal Norway spruce

    International Nuclear Information System (INIS)

    Slaney, M.; Linder, S.

    2007-01-01

    Atmospheric carbon dioxide (CO 2 ) concentrations are predicted to double during the next century, and recent studies have suggested that temperature changes as a result of global warming will be pronounced over the mid and high latitudes of northern continents. The phenology of boreal forests is mainly driven by temperature, and is a reliable indicator of climate change. This article presented the results of a study investigating the effects of elevated carbon dioxide (CO 2 ) and temperature on bud and shoot phenology of mature Norway spruce trees grown in northern Sweden. The trees were grown in whole tree chambers over a period of 3 years and supplied with either ambient or elevated CO 2 at either ambient, or elevated temperatures, which were altered on a monthly time step based on simulations by the Swedish Regional Climate Modelling Program. Temperature elevation ranged between 2.8 and 5.6 degrees C above ambient temperatures, with a CO 2 elevation of 700 μmol per mol. Bud development and shoot extension were monitored from early spring until the termination of elongation growth. Results of the study showed that elevated air temperature hastened both bud development and the initiation and termination of shoot growth by 2 to 3 weeks in each of the study years. It was noted that elevated CO 2 had no significant effect on bud development patterns or on the length of the shoot growth period. Although there was a distinct correlation between temperature sum and shoot elongation, a precise timing of bud burst could not be obtained by using an accumulation of temperature sums. It was concluded that climate warming will results in earlier bud burst in boreal Norway spruce. 59 refs., 3 tabs., 7 figs

  12. Study of the hyperfine magnetic field at Ta181 site in the Heusler Co2 Sc Sn, Co2 Sc Ga and Co2 Hf Sn alloys

    International Nuclear Information System (INIS)

    Attili, R.N.

    1992-01-01

    The hyperfine magnetic fields acting on 181 Ta nucle