The Origin and Evolution of the Infrared Light Curve of SN2010jl

Science.gov (United States)

Dwek, Eli; Sarangi, Arkaprabha; Arendt, Richard; Fox, Ori; Kallman, Timothy; Kazanas, Demosthenes

2018-01-01

SN2010jl is a luminous core-collapse supernova (CCSN) of Type IIn that is surrounded by a dense circumstellar medium (CSM). The supernova (SN) luminosity vastly exceeds the available power from radiactive elements in the ejecta, and is powered by the interaction of the SN shock wave with the ambient medium. Upper limits on the UV and near-IR (NIR) emission from pre-explosion images of the region suggest that any progenitor star was hidden by pre-existing CSM dust. After day ~80, the SN spectrum shows the development of an IR excess above the extrapolated UVO emission arising from the shocked CSM. This IR component is attributed to thermal emission from dust.After day ~300, the light curve exhibits a rise in the NIR luminosity, concurrent with a steep decline at UVO wavelengths. Ruling out any possible contribution of SN-condensed dust to the IR light curve, we show that the early IR emission arises from the pre-existing CSM dust that survived the flash of radiation from the shock breakout. The late IR emission arises from newly-formed CSM dust that condensed in the cooling dust-free postshock gas of the advancing SN shock wave. Our analysis presents the first detailed modeling of dust formation in a cooling postshock environment, and provides important insights into the interaction of the SN shock wave with the CSM.

Shock ignition targets: gain and robustness vs ignition threshold factor

Science.gov (United States)

Atzeni, Stefano; Antonelli, Luca; Schiavi, Angelo; Picone, Silvia; Volponi, Gian Marco; Marocchino, Alberto

2017-10-01

Shock ignition is a laser direct-drive inertial confinement fusion scheme, in which the stages of compression and hot spot formation are partly separated. The hot spot is created at the end of the implosion by a converging shock driven by a final ``spike'' of the laser pulse. Several shock-ignition target concepts have been proposed and relevant gain curves computed (see, e.g.). Here, we consider both pure-DT targets and more facility-relevant targets with plastic ablator. The investigation is conducted with 1D and 2D hydrodynamic simulations. We determine ignition threshold factors ITF's (and their dependence on laser pulse parameters) by means of 1D simulations. 2D simulations indicate that robustness to long-scale perturbations increases with ITF. Gain curves (gain vs laser energy), for different ITF's, are generated using 1D simulations. Work partially supported by Sapienza Project C26A15YTMA, Sapienza 2016 (n. 257584), Eurofusion Project AWP17-ENR-IFE-CEA-01.

Studies on the robustness of shock-ignited laser fusion targets

International Nuclear Information System (INIS)

Atzeni, S; Schiavi, A; Marocchino, A

2011-01-01

Several aspects of the sensitivity of a shock-ignited inertial fusion target to variation of parameters and errors or imperfections are studied by means of one-dimensional and two-dimensional numerical simulations. The study refers to a simple all-DT target, initially proposed for fast ignition (Atzeni et al 2007 Phys. Plasmas 7 052702) and subsequently shown to be also suitable for shock ignition (Ribeyre et al 2009 Plasma Phys. Control. Fusion 51 015013). It is shown that the growth of both Richtmyer-Meshkov and Rayleigh-Taylor instability (RTI) at the ablation front is reduced by laser pulses with an adiabat-shaping picket. An operating window for the parameters of the ignition laser spike is described; the threshold power depends on beam focusing and synchronization with the compression pulse. The time window for spike launch widens with beam power, while the minimum spike energy is independent of spike power. A large parametric scan indicates good tolerance (at the level of a few percent) to target mass and laser power errors. 2D simulations indicate that the strong igniting shock wave plays an important role in reducing deceleration-phase RTI growth. Instead, the high hot-spot convergence ratio (ratio of initial target radius to hot-spot radius at ignition) makes ignition highly sensitive to target mispositioning.

Laser-driven shock-wave propagation in pure and layered targets

International Nuclear Information System (INIS)

Salzmann, D.; Eliezer, S.; Krumbein, A.D.; Gitter, L.

1983-01-01

The propagation properties of laser-driven shock waves in pure and layered polyethylene and aluminum slab targets are studied for a set of laser intensities and pulse widths. The laser-plasma simulations were carried out by means of our one-dimensional Lagrangian hydrodynamic code. It is shown that the various parts of a laser-driven compression wave undergo different thermodynamic trajectories: The shock front portion is on the Hugoniot curve whereas the rear part is closer to an adiabat. It is found that the shock front is accelerated into the cold material till troughly-equal0.8tau (where tau is the laser pulse width) and only later is a constant velocity propagation attained. The scaling laws obtained for the pressure and temperature of the compression wave in pure targets are in good agreement with those published in other works. In layered targets, high compression and pressure were found to occur at the interface of CH 2 on Al targets due to impedance mismatch but were not found when the layers were reversed. The persistence time of the high pressure on the interface in the CH 2 on Al case is long enough relative to the characteristic times of the plasma to have an appreciable influence on the shock-wave propagation into the aluminum layer. This high pressure and compression on the interface can be optimized by adjusting the CH 2 layer thickness

SnO{sub 2}:F thin films deposited by RF magnetron sputtering: effect of the SnF{sub 2} amount in the target on the physical properties

Energy Technology Data Exchange (ETDEWEB)

De Moure F, F. [universidad Autonoma de Queretaro, Facultad de Quimica Materiales, Queretaro 76010, Queretaro (Mexico); Guillen C, A.; Nieto Z, K. E.; Quinones G, J. G.; Hernandez H, A.; Melendez L, M.; Olvera, M. de la L., E-mail: fcomoure@hotmail.com [IPN, Centro de Investigacion y de Estudios Avanzados, Departamento de Fisica, Apdo. Postal 14-740, 07360 Mexico D. F. (Mexico)

2013-08-01

SnO{sub 2}:F thin films were prepared by RF magnetron sputtering onto glass substrates using SnF{sub 2} as fluorine source. The films were deposited under a mixed argon/hydrogen atmosphere at a substrate temperature of 500 C. The X-ray diffraction shows that polycrystalline films were grown with a phases mixture of SnO{sub 2} and Sn O. The optical transmittance is between 80 and 90%. The physical properties of the films suggest that SnO{sub 2} thin films grown with small SnF{sub 2} content in the target can be considered as candidates for transparent electrodes. (Author)

Melting along the Hugoniot and solid phase transition for Sn via sound velocity measurements

Science.gov (United States)

Song, Ping; Cai, Ling-cang; Tao, Tian-jiong; Yuan, Shuai; Chen, Hong; Huang, Jin; Zhao, Xin-wen; Wang, Xue-jun

2016-11-01

It is very important to determine the phase boundaries for materials with complex crystalline phase structures to construct their corresponding multi-phase equation of state. By measuring the sound velocity of Sn with different porosities, different shock-induced melting pressures along the solid-liquid phase boundary could be obtained. The incipient shock-induced melting of porous Sn samples with two different porosities occurred at a pressure of about 49.1 GPa for a porosity of 1.01 and 45.6 GPa for a porosity of 1.02, based on measurements of the sound velocity. The incipient shock-induced melting pressure of solid Sn was revised to 58.1 GPa using supplemental measurements of the sound velocity. Trivially, pores in Sn decreased the shock-induced melting pressure. Based on the measured longitudinal sound velocity data, a refined solid phase transition and the Hugoniot temperature-pressure curve's trend are discussed. No bcc phase transition occurs along the Hugoniot for porous Sn; further investigation is required to understand the implications of this finding.

Strong shock wave and areal mass oscillations associated with impulsive loading of planar laser targets

International Nuclear Information System (INIS)

Velikovich, A.L.; Schmitt, A.J.; Metzler, N.; Gardner, J.H.

2003-01-01

When a rippled surface of a planar target is irradiated with a short (subnanosecond) laser pulse, the shock wave launched into the target and the mass distribution of the shocked plasma will oscillate. These oscillations are found to be surprisingly strong compared, for example, to the case when the laser radiation is not turned off but rather keeps pushing the shock wave into the target. Being stronger than the areal mass oscillations due to ablative Richtmyer-Meshkov instability and feedout in planar targets, which have recently been observed at the Naval Research Laboratory (NRL) [Aglitskiy et al., Phys. Plasmas 9, 2264 (2002)], these oscillations should therefore be directly observable with the same diagnostic technique. Irradiation of a target with a short laser pulse represents a particular case of an impulsive loading, a fast release of finite energy in a thin layer near the surface of a target. Renewed interest to the impulsive loading in the area of direct-drive laser fusion is due to the recent proposals of using a short pulse prior to the drive pulse to make the target more resistant to laser imprint and Rayleigh-Taylor growth. Impulsive loading produces a shock wave that propagates into the target and is immediately followed by an expansion wave, which gradually reduces the shock strength. If the irradiated surface is rippled, then, while the shock wave propagates through the target, its modulation amplitude grows, exceeding the initial ripple amplitude by a factor of 2 or more. The oscillating areal mass reaches the peak values that exceed the initial mass modulation amplitude (density times ripple height) by a factor of 5-7 or more, and reverses its phase several times after the laser pulse is over. The oscillatory growth is more pronounced in fluids with higher shock compressibility and is probably related to the Vishniac's instability of a blast wave. Frequency of the oscillations is determined by the speed of sound in the shocked material, and

Circumstellar X-ray Emission from SN1978K

Science.gov (United States)

Schlegel, Eric M.; Colbert, E.; Petre, R.

1995-02-01

We present the X-ray light curve in the 0.2 2.4 keV band based on fiveROSAT observations of SN1978K in NGC 1313. The X-ray emission is believed to arise from the interaction of the reverse shock and the expanding debris from the supernova. The reverse shock becomes established after the outgoing shock runs into circumstellar matter.

Contact-facilitated drug delivery with Sn2 lipase labile prodrugs optimize targeted lipid nanoparticle drug delivery.

Science.gov (United States)

Pan, Dipanjan; Pham, Christine T N; Weilbaecher, Katherine N; Tomasson, Michael H; Wickline, Samuel A; Lanza, Gregory M

2016-01-01

Sn2 lipase labile phospholipid prodrugs in conjunction with contact-facilitated drug delivery offer an important advancement in Nanomedicine. Many drugs incorporated into nanosystems, targeted or not, are substantially lost during circulation to the target. However, favorably altering the pharmacokinetics and volume of distribution of systemic drug delivery can offer greater efficacy with lower toxicity, leading to new prolonged-release nanoexcipients. However, the concept of achieving Paul Erhlich's inspired vision of a 'magic bullet' to treat disease has been largely unrealized due to unstable nanomedicines, nanosystems achieving low drug delivery to target cells, poor intracellular bioavailability of endocytosed nanoparticle payloads, and the substantial biological barriers of extravascular particle penetration into pathological sites. As shown here, Sn2 phospholipid prodrugs in conjunction with contact-facilitated drug delivery prevent premature drug diffusional loss during circulation and increase target cell bioavailability. The Sn2 phospholipid prodrug approach applies equally well for vascular constrained lipid-encapsulated particles and micelles the size of proteins that penetrate through naturally fenestrated endothelium in the bone marrow or thin-walled venules of an inflamed microcirculation. At one time Nanomedicine was considered a 'Grail Quest' by its loyal opposition and even many in the field adsorbing the pains of a long-learning curve about human biology and particles. However, Nanomedicine with innovations like Sn2 phospholipid prodrugs has finally made 'made the turn' toward meaningful translational success. © 2015 The Authors. WIREs Nanomedicine and Nanobiotechnology published by Wiley Periodicals, Inc.

Rear surface light emission measurements from laser-produced shock waves in clear and Al-coated polystyrene targets

Science.gov (United States)

McLean, E. A.; Deniz, A. V.; Schmitt, A. J.; Stamper, J. A.; Obenschain, S. P.; Lehecka, T.; Mostovych, A. N.; Seely, J.

1999-08-01

The Nike KrF laser, with its very uniform focal distributions, has been used at intensities near 10 14 W/cm 2 to launch shock waves in polystyrene targets. The rear surface visible light emission differed between clear polystyrene (CH) targets and targets with a thin (125 nm) Al coating on the rear side. The uncoated CH targets showed a relatively slowly rising emission followed by a sudden fall when the shock emerges, while the Al-coated targets showed a rapid rise in emission when the shock emerges followed by a slower fall, allowing an unambiguous determination of the time the shock arrived at the rear surface. A half-aluminized target allowed us to observe this difference in a single shot. The brightness temperature of both the aluminized targets and the non-aluminized targets was slightly below but close to rear surface temperature predictions of a hydrodynamic code. A discussion of preheat effects is given.

X-RAY EMISSION FROM SUPERNOVAE IN DENSE CIRCUMSTELLAR MATTER ENVIRONMENTS: A SEARCH FOR COLLISIONLESS SHOCKS

International Nuclear Information System (INIS)

Ofek, E. O.; Gal-Yam, A.; Yaron, O.; Arcavi, I.; Fox, D.; Cenko, S. B.; Filippenko, A. V.; Bloom, J. S.; Sullivan, M.; Gnat, O.; Frail, D. A.; Horesh, A.; Kulkarni, S. R.; Corsi, A.; Quimby, R. M.; Gehrels, N.; Nugent, P. E.; Kasliwal, M. M.; Bildsten, L.; Poznanski, D.

2013-01-01

The optical light curve of some supernovae (SNe) may be powered by the outward diffusion of the energy deposited by the explosion shock (the so-called shock breakout) in optically thick (τ ∼> 30) circumstellar matter (CSM). Recently, it was shown that the radiation-mediated and radiation-dominated shock in an optically thick wind must transform into a collisionless shock and can produce hard X-rays. The X-rays are expected to peak at late times, relative to maximum visible light. Here we report on a search, using Swift/XRT and Chandra, for X-ray emission from 28 SNe that belong to classes whose progenitors are suspected to be embedded in dense CSM. Our sample includes 19 Type IIn SNe, one Type Ibn SN, and eight hydrogen-poor superluminous SNe (SLSN-I such as SN 2005ap). Two SNe (SN 2006jc and SN 2010jl) have X-ray properties that are roughly consistent with the expectation for X-rays from a collisionless shock in optically thick CSM. However, the X-ray emission from SN 2006jc can also be explained as originating in an optically thin region. Thus, we propose that the optical light curve of SN 2010jl is powered by shock breakout in CSM. We suggest that two other events (SN 2010al and SN 2011ht) were too X-ray bright during the SN maximum optical light to be explained by the shock-breakout model. We conclude that the light curves of some, but not all, SNe IIn/Ibn are powered by shock breakout in CSM. For the rest of the SNe in our sample, including all of the SLSN-I events, our X-ray limits are not deep enough and were typically obtained too early (i.e., near the SN maximum light) for definitive conclusions about their nature. Late-time X-ray observations are required in order to further test whether these SNe are indeed embedded in dense CSM. We review the conditions required for a shock breakout in a wind profile. We argue that the timescale, relative to maximum light, for the SN to peak in X-rays is a probe of the column density and the density profile above the

Electric response of Pb0.99[(Zr0.90Sn0.10)0.968Ti0.032]0.98Nb0.02O3 ceramics to the shock-wave-induced ferroelectric-to-antiferroelectric phase transition

International Nuclear Information System (INIS)

Jiang Dongdong; Zhang Na; Feng Yujun; Du Jinmei; Gu Yan

2012-01-01

Highlights: ► Shock wave induces the FE-to-AFE phase transition in PbNb(Zr,Sn,Ti)O 3 . ► Depoling current due to phase transition depends on shock pressure and load resistance. ► Shock pressure promotes the phase transition in short-circuit case. ► Increasing load resistance decreases the released charge. - Abstract: Shock-wave-enforced ferroelectric (FE)-to-antiferroelectric (AFE) phase transition releases a large electrical polarization, having application in pulse power technology. In the present work, the depoling currents under shock wave compression were investigated in Pb 0.99 [(Zr 0.90 Sn 0.10 ) 0.968 Ti 0.032 ] 0.98 Nb 0.02 O 3 (PZST) ceramics with composition close to the FE/AFE phase boundary. Shock wave was generated by gas-gun and propagated in a direction perpendicular to the remanent polarization. It was found that the shock pressure promoted the phase transition under the short-circuit condition. The shock pressure dependence of the released charge was associated with the evolution of FE-to-AFE phase transition. The onset of phase transition was about 0.40 GPa and complete transformation occurred at 1.23 GPa. However, the released charge decreased with increasing load resistance. The reason may be that the electric field suppresses the phase transition in uncompressed zone and/or shock induces conductivity in compressed zone. Results lay the foundation for application of PZST ceramics in shock-activated power supply.

Design of a deuterium and tritium-ablator shock ignition target for the National Ignition Facility

International Nuclear Information System (INIS)

Terry, Matthew R.; Perkins, L. John; Sepke, Scott M.

2012-01-01

Shock ignition presents a viable path to ignition and high gain on the National Ignition Facility (NIF). In this paper, we describe the development of the 1D design of 0.5 MJ class, all-deuterium and tritium (fuel and ablator) shock ignition target that should be reasonably robust to Rayleigh-Taylor fluid instabilities, mistiming, and hot electron preheat. The target assumes “day one” NIF hardware and produces a yield of 31 MJ with reasonable allowances for laser backscatter, absorption efficiency, and polar drive power variation. The energetics of polar drive laser absorption require a beam configuration with half of the NIF quads dedicated to launching the ignitor shock, while the remaining quads drive the target compression. Hydrodynamic scaling of the target suggests that gains of 75 and yields 70 MJ may be possible.

Study of the dynamic fragmentation of laser shock-loaded metallic target

International Nuclear Information System (INIS)

Lescoute, E.

2010-01-01

The irradiation of a metallic target by a high power laser pulse induces a shock wave in the material. Under some conditions, it leads to the production of high velocity ejecta which can damage the optical environment (lenses, mirrors, windows, etc.). With the ongoing development of high energy laser facilities designed to achieve inertial confinement fusion, such as the Laser MegaJoule in France or the National Ignition Facility in the USA, the question of debris ejection from metallic samples subjected to intense laser irradiation has become a key issue. It is necessary to understand fragmentation processes induced by laser shock, and to anticipate and quantify generated fragments, in order to design suitable protections and experiments, and to preserve laser facilities. The main fragmentation processes which can occur in a laser-shock-loaded metallic target and generate high velocity ejecta are: (i) micro-jetting, which occurs upon reflection of the incident compressive front from the free surface, (ii) spallation, which is due to the later interaction of the release wave reflected from that surface with the incident unloading wave and (iii) dynamic punching of thin targets. Experimental campaigns have been performed on high energy laser facilities in the Centre d'Etudes Scientifiques et Techniques d'Aquitaine (CESTA, CEA, Alise facility) and in the Laboratoire pour l'Utilisation des Lasers Intenses (LULI, Ecole Polytechnique, LULI 2000 facility). Gold and aluminium have been mainly studied because they are the two main metallic components of the target which will be used to achieved the inertial confinement fusion. Specific diagnostics have been developed and used during these experiments to study the dynamic fragmentation: transverse shadowgraphy, free surface velocity measurement and recovery of generated fragments. Experimental results have been compared with numerical predictions obtained with a bi-dimensional hydrodynamic code, where a specific numerical

Numerical investigation on target implosions driven by radiation ablation and shock compression in dynamic hohlraums

Energy Technology Data Exchange (ETDEWEB)

Xiao, Delong; Sun, Shunkai; Zhao, Yingkui; Ding, Ning; Wu, Jiming; Dai, Zihuan; Yin, Li; Zhang, Yang; Xue, Chuang [Institute of Applied Physics and Computational Mathematics, Beijing 100088 (China)

2015-05-15

In a dynamic hohlraum driven inertial confinement fusion (ICF) configuration, the target may experience two different kinds of implosions. One is driven by hohlraum radiation ablation, which is approximately symmetric at the equator and poles. The second is caused by the radiating shock produced in Z-pinch dynamic hohlraums, only taking place at the equator. To gain a symmetrical target implosion driven by radiation ablation and avoid asymmetric shock compression is a crucial issue in driving ICF using dynamic hohlraums. It is known that when the target is heated by hohlraum radiation, the ablated plasma will expand outward. The pressure in the shocked converter plasma qualitatively varies linearly with the material temperature. However, the ablation pressure in the ablated plasma varies with 3.5 power of the hohlraum radiation temperature. Therefore, as the hohlraum temperature increases, the ablation pressure will eventually exceed the shock pressure, and the expansion of the ablated plasma will obviously weaken the shock propagation and decrease its velocity after propagating into the ablator plasma. Consequently, longer time duration is provided for the symmetrical target implosion driven by radiation ablation. In this paper these processes are numerically investigated by changing drive currents or varying load parameters. The simulation results show that a critical hohlraum radiation temperature is needed to provide a high enough ablation pressure to decelerate the shock, thus providing long enough time duration for the symmetric fuel compression driven by radiation ablation.

Microscopic Examination of Cold Spray Cermet Sn+In2O3 Coatings for Sputtering Target Materials.

Science.gov (United States)

Winnicki, M; Baszczuk, A; Rutkowska-Gorczyca, M; Jasiorski, M; Małachowska, A; Posadowski, W; Znamirowski, Z; Ambroziak, A

2017-01-01

Low-pressure cold spraying is a newly developed technology with high application potential. The aim of this study was to investigate potential application of this technique for producing a new type of transparent conductive oxide films target. Cold spraying technique allows the manufacture of target directly on the backing plate; therefore the proposed sputtering target has a form of Sn+In 2 O 3 coating sprayed onto copper substrate. The microstructure and properties of the feedstock powder prepared using three various methods as well as the deposited ones by low-pressure cold spraying coatings were evaluated, compared, and analysed. Produced cermet Sn+In 2 O 3 targets were employed in first magnetron sputtering process to deposit preliminary, thin, transparent conducting oxide films onto the glass substrates. The resistivity of obtained preliminary films was measured and allows believing that fabrication of TCO (transparent conducting oxide) films using targets produced by cold spraying is possible in the future, after optimization of the deposition conditions.

Microscopic Examination of Cold Spray Cermet Sn+In2O3 Coatings for Sputtering Target Materials

Directory of Open Access Journals (Sweden)

M. Winnicki

2017-01-01

Full Text Available Low-pressure cold spraying is a newly developed technology with high application potential. The aim of this study was to investigate potential application of this technique for producing a new type of transparent conductive oxide films target. Cold spraying technique allows the manufacture of target directly on the backing plate; therefore the proposed sputtering target has a form of Sn+In2O3 coating sprayed onto copper substrate. The microstructure and properties of the feedstock powder prepared using three various methods as well as the deposited ones by low-pressure cold spraying coatings were evaluated, compared, and analysed. Produced cermet Sn+In2O3 targets were employed in first magnetron sputtering process to deposit preliminary, thin, transparent conducting oxide films onto the glass substrates. The resistivity of obtained preliminary films was measured and allows believing that fabrication of TCO (transparent conducting oxide films using targets produced by cold spraying is possible in the future, after optimization of the deposition conditions.

Liquid metal targets for high-power applications : pulsed heating and shock hydrodynamics

International Nuclear Information System (INIS)

Hassanein, A.

2000-01-01

Significant interest has recently focused on the use of liquid-metal targets flowing with high velocities for various high-power nuclear and high-energy physics applications such as fusion reactor first-walls, the Spallation Neutron Source, Isotope Separation On Line, and Muon Collider projects. This is because the heat generated in solid targets due to beam or plasma bombardment cannot be removed easily and the resulting thermal shock damage could be a serious lifetime problem for long-term operation. More recently, the use of free or open flying-liquid jets has been proposed for higher-power-density applications. The behavior of a free-moving liquid mercury or gallium jet subjected to proton beam deposition in a strong magnetic field has been modeled and analyzed for the Muon Collider project. Free-liquid-metal jets can offer significant advantages over conventional solid targets, particularly for the more demanding and challenging high-power applications. However, the use of free-moving liquid-metal targets raises a number of new and challenging problems such as instabilities of the jet in a strong magnetic field, induced eddy-current effects on jet shape, thermal-shock formation, and possible jet fragmentation. Problems associated with shock heating of liquid jets in a strong magnetic field are analyzed in this study

Shock dynamics induced by double-spot laser irradiation of layered targets

Directory of Open Access Journals (Sweden)

Aliverdiev Abutrab A.

2015-06-01

Full Text Available We studied the interaction of a double-spot laser beam with targets using the Prague Asterix Laser System (PALS iodine laser working at 0.44 μm wavelength and intensity of about 1015 W/cm2. Shock breakout signals were recorder using time-resolved self-emission from target rear side of irradiated targets. We compared the behavior of pure Al targets and of targets with a foam layer on the laser side. Results have been simulated using hydrodynamic numerical codes.

SN 2008D: A WOLF-RAYET EXPLOSION THROUGH A THICK WIND

International Nuclear Information System (INIS)

Svirski, Gilad; Nakar, Ehud

2014-01-01

Supernova (SN) 2008D/XRT 080109 is considered to be the only direct detection of a shock breakout from a regular SN to date. While a breakout interpretation was favored by several papers, inconsistencies remain between the observations and current SN shock breakout theory. Most notably, the duration of the luminous X-ray pulse is considerably longer than expected for a spherical breakout through the surface of a type Ibc SN progenitor, and the X-ray radiation features, mainly its flat spectrum and its luminosity evolution, are enigmatic. We apply a recently developed theoretical model for the observed radiation from a Wolf-Rayet SN exploding through a thick wind and show that it naturally explains all of the observed features of SN 2008D X-ray emission, including the energetics, the spectrum, and the detailed luminosity evolution. We find that the inferred progenitor and SN parameters are typical for an exploding Wolf-Rayet. A comparison of the wind density found at the breakout radius and the density at much larger radii, as inferred by late radio observations, suggests an enhanced mass-loss rate taking effect about 10 days prior to the SN explosion. This finding joins accumulating evidence for a possible late phase in the stellar evolution of massive stars, involving vigorous mass loss a short time before the SN explosion

SN 2008D: A WOLF-RAYET EXPLOSION THROUGH A THICK WIND

Energy Technology Data Exchange (ETDEWEB)

Svirski, Gilad; Nakar, Ehud [Raymond and Beverly Sackler School of Physics and Astronomy, Tel Aviv University, Tel Aviv 69978 (Israel)

2014-06-10

Supernova (SN) 2008D/XRT 080109 is considered to be the only direct detection of a shock breakout from a regular SN to date. While a breakout interpretation was favored by several papers, inconsistencies remain between the observations and current SN shock breakout theory. Most notably, the duration of the luminous X-ray pulse is considerably longer than expected for a spherical breakout through the surface of a type Ibc SN progenitor, and the X-ray radiation features, mainly its flat spectrum and its luminosity evolution, are enigmatic. We apply a recently developed theoretical model for the observed radiation from a Wolf-Rayet SN exploding through a thick wind and show that it naturally explains all of the observed features of SN 2008D X-ray emission, including the energetics, the spectrum, and the detailed luminosity evolution. We find that the inferred progenitor and SN parameters are typical for an exploding Wolf-Rayet. A comparison of the wind density found at the breakout radius and the density at much larger radii, as inferred by late radio observations, suggests an enhanced mass-loss rate taking effect about 10 days prior to the SN explosion. This finding joins accumulating evidence for a possible late phase in the stellar evolution of massive stars, involving vigorous mass loss a short time before the SN explosion.

SN 2016X: a type II-P supernova with a signature of shock breakout from explosion of a massive red supergiant

Science.gov (United States)

Huang, F.; Wang, X.-F.; Hosseinzadeh, G.; Brown, P. J.; Mo, J.; Zhang, J.-J.; Zhang, K.-C.; Zhang, T.-M.; Howell, D.-A.; Arcavi, I.; McCully, C.; Valenti, S.; Rui, L.-M.; Song, H.; Xiang, D.-F.; Li, W.-X.; Lin, H.; Wang, L.-F.

2018-04-01

We present extensive ultraviolet (UV) and optical photometry, as well as dense optical spectroscopy, for type II Plateau (IIP) supernova SN 2016X that exploded in the nearby (˜15 Mpc) spiral galaxy UGC 08041. The observations span the period from 2 to 180 d after the explosion; in particular, the Swift UV data probably captured the signature of shock breakout associated with the explosion of SN 2016X. It shows very strong UV emission during the first week after explosion, with a contribution of ˜20-30 per cent to the bolometric luminosity (versus ≲15 per cent for normal SNe IIP). Moreover, we found that this supernova has an unusually long rise time of about 12.6 ± 0.5 d in the R band (versus ˜7.0 d for typical SNe IIP). The optical light curves and spectral evolution are quite similar to the fast-declining type IIP object SN 2013ej, except that SN 2016X has a relatively brighter tail. Based on the evolution of photospheric temperature as inferred from the Swift data in the early phase, we derive that the progenitor of SN 2016X has a radius of about 930 ± 70 R⊙. This large-size star is expected to be a red supergiant star with an initial mass of ≳19-20 M⊙ based on the mass-radius relation of the Galactic red supergiants, and it represents one of the most largest and massive progenitors found for SNe IIP.

SHOCK BREAKOUT IN TYPE II PLATEAU SUPERNOVAE: PROSPECTS FOR HIGH-REDSHIFT SUPERNOVA SURVEYS

International Nuclear Information System (INIS)

Tominaga, N.; Morokuma, T.; Blinnikov, S. I.; Nomoto, K.; Baklanov, P.; Sorokina, E. I.

2011-01-01

Shock breakout is the brightest radiative phenomenon in a supernova (SN) but is difficult to be observed owing to the short duration and X-ray/ultraviolet (UV)-peaked spectra. After the first observation from the rising phase reported in 2008, its observability at high redshift is attracting enormous attention. We perform multigroup radiation hydrodynamics calculations of explosions for evolutionary presupernova models with various main-sequence masses M MS , metallicities Z, and explosion energies E. We present multicolor light curves of shock breakouts in Type II plateau SNe, being the most frequent core-collapse SNe, and predict apparent multicolor light curves of shock breakout at various redshifts z. We derive the observable SN rate and reachable redshift as functions of filter x and limiting magnitude m x,lim by taking into account an initial mass function, cosmic star formation history, intergalactic absorption, and host galaxy extinction. We propose a realistic survey strategy optimized for shock breakout. For example, the g'-band observable SN rate for m g',lim = 27.5 mag is 3.3 SNe deg -2 day -1 and half of them are located at z ≥ 1.2. It is clear that the shock breakout is a beneficial clue for probing high-z core-collapse SNe. We also establish ways to identify shock breakout and constrain SN properties from the observations of shock breakout, brightness, timescale, and color. We emphasize that the multicolor observations in blue optical bands with ∼hour intervals, preferably over ≥2 continuous nights, are essential to efficiently detect, identify, and interpret shock breakout.

Supernova mechanisms: Before and after SN1987a

International Nuclear Information System (INIS)

Kahana, S.H.

1987-01-01

The impact of SN1987a on theoretical studies of the specific mechanism generating Type II supernovae is examined. The explosion energy extracted from analysis of the light curve for SN 1987a is on the edge of distinguishing between a prompt explosion from a hydrodynamic shock and a delayed, neutrino-induced, explosion. The detection of neutrinos from 1987a is also reanalyzed. 30 refs., 2 tabs

Decay of a laser generated shock wave in an aluminium target

International Nuclear Information System (INIS)

Werdiger, M.

1993-09-01

When a shock wave arrives at the near surface of a solid material, a radical and fast change occurs in the reflection properties of the material. The phenomenon is used in the present work in order to develop a new way to measure the transit time of a shock wave in a target. A 10 milliwatt He:Ne laser is directed toward the rear surface of the target. The reflected beam arrives at a photo-diode with a fast rise time of 150 psec which detects the instant of the change in the reflection. This technique, called 'continuous back lightning', is used in experiments with aluminium foil thickness in the range of 40μm ≤x≥ 1000μm. The shock wave is induced by a laser pulse of an intensity of 3*10 13 W/cm 2 . The results show two main physical regimes: in the first one 40μ ≤x≥ 210μm, there is a constant shock wave velocity which in our experiments was measured to be (12.81±0.67)km/s. In the second range of the thickness where 300μm there is a decay of the shock velocity. For x ≥ 210μm the geometry is one dimensional for our experimental conditions, while for x ≥ 300μm the 1-D geometry changes to 2 dimensional (2-D) geometry. The 2-D shock wave decay asymptotically (x→∞ to an acoustic wave. shock wave is described by a pressure scaling as x -n (n is a positive constant). The phenomenological equation of the state is taken to be P=A**u s + B*u s 2 +Bu s , where P is the pressure, u s - the shock velocity, A and B are constants. Applying our experimental results to the solution of the differential equation in this model A*x 2 ± B*x=C*x -n yields a value of n in the range 3.16 ≤n≥ 3.51. This pressure scaling law agrees with the self-similar solution of a concentrated impact on a surface between two media. This situation is well simulated by the laser deposition energy on a metal surface. In the experiment a 5% accuracy is achieved. Such a good accuracy has not been achieved so far in a laser induced shock-wave measurements in solids. (author). 52 refs

Shock pressure induced by 0.44 mu m laser radiation on aluminum targets

Czech Academy of Sciences Publication Activity Database

Batani, D.; Stabile, H.; Ravasio, A.; Desai, T.; Lucchini, G.; Strati, F.; Ullschmied, Jiří; Krouský, Eduard; Skála, Jiří; Králiková, Božena; Pfeifer, Miroslav; Kadlec, Christelle; Mocek, Tomáš; Präg R., Ansgar; Nishimura, H.; Ochi, Y.; Kilpio, A.; Shashkov, E.; Stuchebrukhov, I.; Vovchenko, V.; Krasuyk, I.

2003-01-01

Roč. 21, č. 4 (2003), s. 481-487 ISSN 0263-0346 R&D Projects: GA MŠk LN00A100 Grant - others:HPRI-CT(XX) 1999-00053 Institutional research plan: CEZ:AV0Z2043910 Keywords : rear target luminosity, shock pressure, shock waves Subject RIV: BH - Optics, Masers, Lasers Impact factor: 0.646, year: 2003

SN 1987 A: A Unique Laboratory for Shock Physics

Science.gov (United States)

Sonneborn, George

2012-01-01

Supernova 1987 A has given us an unprecedented view of the evolution of the explosion debris and its interaction with circumstellar matter. The outer supernova debris, now expanding with velocities approx.8000 km/s, encountered the relatively dense circumstellar ring formed by presupernova mass loss in the early 1990s. The shock interaction is manifested by UV-optical "hotspots", an expanding X-ray ring, an expanding ring of knotty non-thermal radio emission, and a ring of thermal IR emission from silicate dust Recent ultraviolet observations of the emissions from the reverse shock and the ring with the HST/COS reveal new details about the shock interaction. Lyman alpha emission from the reverse shock is much stronger than H alpha and they have different emission morphologies, pointing to different emission mechanisms. The reverse shock was detected for the first time in C IV 1550. The N V to C IV brightness ratio indicates the N/C abundance ratio in the expanding debris is about 100X solar, about 3X N/C in the inner ring.

A target concept for intense radioactive beams in the 132Sn Region

International Nuclear Information System (INIS)

Nolen, J.A. Jr.

1993-01-01

To produce intense secondary beams of radioactive isotopes, primary beams of up to 100 kW are being proposed at some facilities. There are plans to test production targets with 800 MeV protons at such higher power at the Rutherford Appleton Laboratory. In this paper the use of high energy neutrons as a possible alternative is presented. The concept is to generate an intense beam of neutrons in a well-cooled target with a primary deuteron beam. The neutrons have a high cross section for producing fission fragments in a thick uranium target which is coupled to the ion source for the secondary beams. The effective target thickness is large and the power dissipated in the ISOL target is relatively small, which should lead to intense beams of neutron-rich, intermediate-mass isotopes such as 132 Sn

Simulations of Converging Shock Collisions for Shock Ignition

Science.gov (United States)

Sauppe, Joshua; Dodd, Evan; Loomis, Eric

2016-10-01

Shock ignition (SI) has been proposed as an alternative to achieving high gain in inertial confinement fusion (ICF) targets. A central hot spot below the ignition threshold is created by an initial compression pulse, and a second laser pulse drives a strong converging shock into the fuel. The collision between the rebounding shock from the compression pulse and the converging shock results in amplification of the converging shock and increases the hot spot pressure above the ignition threshold. We investigate shock collision in SI drive schemes for cylindrical targets with a polystyrene foam interior using radiation-hydrodynamics simulations with the RAGE code. The configuration is similar to previous targets fielded on the Omega laser. The CH interior results in a lower convergence ratio and the cylindrical geometry facilitates visualization of the shock transit using an axial X-ray backlighter, both of which are important for comparison to potential experimental measurements. One-dimensional simulations are used to determine shock timing, and the effects of low mode asymmetries in 2D computations are also quantified. LA-UR-16-24773.

Controlling the antibacterial activity of CuSn thin films by varying the contents of Sn

Energy Technology Data Exchange (ETDEWEB)

Kang, Yujin; Park, Juyun; Kim, Dong-Woo; Kim, Hakjun; Kang, Yong-Cheol, E-mail: yckang@pknu.ac.kr

2016-12-15

Highlights: • We deposit CuSn thin films on a Si substrate with various Cu/Sn ratio. • Antibacterial activities of CuSn thin films increased as the ratio of Cu and the contact time increased. • XPS was utilized to assign the chemical environment of CuSn thin films before and after antibacterial test. - Abstract: We investigated antibacterial activity of CuSn thin films against Gram positive Staphylococcus aureus (S. aureus). CuSn thin films with different Cu to Sn ratios were deposited on Si(100) by radio frequency (RF) magnetron sputtering method using Cu and Sn metal anodes. The film thickness was fixed at 200 nm by varying the sputtering time and RF power on the metal targets. The antibacterial test was conducted in various conditions such as different contact times and Cu to Sn ratios in the CuSn films. The antibacterial activities of CuSn thin films increased as the ratio of Cu and the contact time between the film and bacteria suspension increased execpt in the case of CuSn-83. The oxidation states of Cu and Sn and the chemical composition of CuSn thin films before and after the antibacterial test were investigated by X-ray photoelectron spectroscopy (XPS). When the contact time was fixed, the Cu species was further oxidized as the RF power on Cu target increased. The intensity of Sn 3d decreased with increasing Cu ratio. When the sample was fixed, the peak intensity of Sn 3d decreased as the contact time increased due to the permeation of Sn into the cell.

Two-dimensional study of shock breakout at the rear face of laser irradiated metallic targets

Energy Technology Data Exchange (ETDEWEB)

Cottet, F.; Marty, L.; Hallouin, M.; Romain, J.P.; Virmont, J.; Fabbro, R.; Faral, B.

1988-11-01

The two-dimensional propagation dynamics of laser-driven shock waves in solids is studied through the analysis of the shock breakout at the rear face of the target for a set of materials and laser intensities. The laser shock simulations were carried out by means of a two-dimensional hydrodynamics code in which the laser-ablation pressure is replaced by an equivalent pressure pulse. It is shown that the two-dimensional code is a very useful tool to analyze laser-shock experiments where two-dimensional effects arise from a finite laser-spot size or a heterogeneous energy deposition.

Two-dimensional study of shock breakout at the rear face of laser irradiated metallic targets

International Nuclear Information System (INIS)

Cottet, F.; Marty, L.; Hallouin, M.; Romain, J.P.; Virmont, J.; Fabbro, R.; Faral, B.

1988-01-01

The two-dimensional propagation dynamics of laser-driven shock waves in solids is studied through the analysis of the shock breakout at the rear face of the target for a set of materials and laser intensities. The laser shock simulations were carried out by means of a two-dimensional hydrodynamics code in which the laser-ablation pressure is replaced by an equivalent pressure pulse. It is shown that the two-dimensional code is a very useful tool to analyze laser-shock experiments where two-dimensional effects arise from a finite laser-spot size or a heterogeneous energy deposition

SN 2010jl: Optical to hard X-ray observations reveal an explosion embedded in a ten solar mass cocoon

International Nuclear Information System (INIS)

Ofek, Eran O.; Gal-Yam, Avishay; Arcavi, Iair; Zoglauer, Andreas; Boggs, Steven E.; Barriére, Nicolas M.; Reynolds, Stephen P.; Fryer, Chris L.; Even, Wesley; Harrison, Fiona A.; Kulkarni, Shrinivas R.; Bellm, Eric; Grefenstette, Brian; Cenko, S. Bradley; Bloom, Joshua S.; Filippenko, Alexei V.; Christensen, Finn; Craig, William W.; Hailey, Charles J.; Laher, Russ

2014-01-01

Some supernovae (SNe) may be powered by the interaction of the SN ejecta with a large amount of circumstellar matter (CSM). However, quantitative estimates of the CSM mass around such SNe are missing when the CSM material is optically thick. Specifically, current estimators are sensitive to uncertainties regarding the CSM density profile and the ejecta velocity. Here we outline a method to measure the mass of the optically thick CSM around such SNe. We present new visible-light and X-ray observations of SN 2010jl (PTF 10aaxf), including the first detection of an SN in the hard X-ray band using NuSTAR. The total radiated luminosity of SN 2010jl is extreme—at least 9 × 10 50 erg. By modeling the visible-light data, we robustly show that the mass of the circumstellar material within ∼10 16 cm of the progenitor of SN 2010jl was in excess of 10 M ☉ . This mass was likely ejected tens of years prior to the SN explosion. Our modeling suggests that the shock velocity during shock breakout was ∼6000 km s –1 , decelerating to ∼2600 km s –1 about 2 yr after maximum light. Furthermore, our late-time NuSTAR and XMM spectra of the SN presumably provide the first direct measurement of SN shock velocity 2 yr after the SN maximum light—measured to be in the range of 2000-4500 km s –1 if the ions and electrons are in equilibrium, and ≳ 2000 km s –1 if they are not in equilibrium. This measurement is in agreement with the shock velocity predicted by our modeling of the visible-light data. Our observations also show that the average radial density distribution of the CSM roughly follows an r –2 law. A possible explanation for the ≳ 10 M ☉ of CSM and the wind-like profile is that they are the result of multiple pulsational pair instability events prior to the SN explosion, separated from each other by years.

Implications of the Discovery of Millisecond Pulsar in SN 1987A

OpenAIRE

Nagataki, S.; Sato, K.

2000-01-01

From the observation of a millisecond pulsar in SN 1987A, the following implications are obtained. 1) The pulsar spindown in SN 1987A is caused by radiating gravitational waves rather than by magnetic dipole radiation and/or relativistic pulsar winds. 2) A mildly deformed shock wave would be formed at the core-collapse and explosion in SN 1987A, which is consistent with the conclusion given in Nagataki (2000). 3) The gravitational waves from the pulsar should be detected in several years usin...

Production of Sn/SnO2/MWCNT composites by plasma oxidation after thermal evaporation from pure Sn targets onto buckypapers.

Science.gov (United States)

Alaf, M; Gultekin, D; Akbulut, H

2012-12-01

In this study, tin/tinoxide/multi oxide/multi walled carbon nano tube (Sn/SnO2/MWCNT) composites were produced by thermal evaporation and then subsequent plasma oxidation. Buckypapers having controlled porosity were prepared by vacuum filtration from functionalized MWCNTs. Pure metallic tin was thermally evaporated on the buckypapers in argon atmosphere with different thicknesses. It was determined that the evaporated pure tin nano crystals were mechanically penetrated into pores of buckypaper to form a nanocomposite. The tin/MWCNT composites were subjected to plasma oxidation process at oxygen/argon gas mixture. Three different plasma oxidation times (30, 45 and 60 minutes) were used to investigate oxidation and physical and microstructural properties. The effect of coating thickness and oxidation time was investigated to understand the effect of process parameters on the Sn and SnO2 phases after plasma oxidation. Quantitative phase analysis was performed in order to determine the relative phase amounts. The structural properties were studied by field-emission gun scanning electron microscopy (FEG-SEM), atomic force microscopy (AFM) and X-ray diffraction (XRD).

Spallation reactions in shock waves at supernova explosions and related problems

Energy Technology Data Exchange (ETDEWEB)

Ustinova, G. K., E-mail: ustinova@dubna.net.ru [RAS, V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry (Russian Federation)

2013-05-15

The isotopic anomalies of some extinct radionuclides testify to the outburst of a nearby supernova just before the collapse of the protosolar nebula, and to the fact that the supernova was Sn Ia, i.e. the carbon-detonation supernova. A key role of spallation reactions in the formation of isotopic anomalies in the primordial matter of the Solar System is revealed. It is conditioned by the diffusive acceleration of particles in the explosive shock waves, which leads to the amplification of rigidity of the energy spectrum of particles and its enrichment with heavier ions. The quantitative calculations of such isotopic anomalies of many elements are presented. It is well-grounded that the anomalous Xe-HL in meteoritic nanodiamonds was formed simultaneously with nanodiamonds themselves during the shock wave propagation at the Sn Ia explosion. The possible effects of shock wave fractionation of noble gases in the atmosphere of planets are considered. The origin of light elements Li, Be and B in spallation reactions, predicted by Fowler in the middle of the last century, is argued. All the investigated isotopic anomalies give the evidence for the extremely high magnetohydrodynamics (MHD) conditions at the initial stage of free expansion of the explosive shock wave from Sn Ia, which can be essential in solution of the problem of origin of cosmic rays. The specific iron-enriched matter of Sn Ia and its MHD-separation in turbulent processes must be taking into account in the models of origin of the Solar System.

Shock ignition: a brief overview and progress in the design of robust targets

International Nuclear Information System (INIS)

Atzeni, S; Marocchino, A; Schiavi, A

2015-01-01

Shock ignition is a laser direct-drive inertial confinement fusion (ICF) scheme in which the stages of compression and hot spot formation are partly separated. The fuel is first imploded at a lower velocity than in conventional ICF, reducing the threats due to Rayleigh–Taylor instability. Close to stagnation, an intense laser spike drives a strong converging shock, which contributes to hot spot formation. This paper starts with a brief overview of the theoretical studies, target design and experimental results on shock ignition. The second part of the paper illustrates original work aiming at the design of robust targets and computation of the relevant gain curves. Following Chang et al (2010 Phys. Rev. Lett. 104 135002) a safety factor for high gain, ITF* (analogous to the ignition threshold factor ITF introduced by Clark et al (2008 Phys. Plasmas 15 056305)), is evaluated by means of parametric 1D simulations with artificially reduced reactivity. SI designs scaled as in Atzeni et al (2013 New J. Phys. 15 045004) are found to have nearly the same ITF*. For a given target, such ITF* increases with implosion velocity and laser spike power. A gain curve with a prescribed ITF* can then be simply generated by upscaling a reference target with that value of ITF*. An interesting option is scaling in size by reducing the implosion velocity to keep the ratio of implosion velocity to self-ignition velocity constant. At a given total laser energy, targets with higher ITF* are driven to higher implosion velocity and achieve a somewhat lower gain. However, a 1D gain higher than 100 is achieved at an (incident) energy below 1 MJ, an implosion velocity below 300 km s −1 and a peak incident power below 400 TW. 2D simulations of mispositioned targets show that targets with a higher ITF* indeed tolerate larger displacements. (paper)

Three-dimensional simulations of core-collapse supernovae: from shock revival to shock breakout

Science.gov (United States)

Wongwathanarat, A.; Müller, E.; Janka, H.-Th.

2015-05-01

We present three-dimensional hydrodynamic simulations of the evolution of core-collapse supernovae (SN) from blast-wave initiation by the neutrino-driven mechanism to shock breakout from the stellar surface, using an axis-free Yin-Yang grid and considering two 15 M⊙ red supergiants (RSG) and two blue supergiants (BSG) of 15 M⊙ and 20 M⊙. We demonstrate that the metal-rich ejecta in homologous expansion still carry fingerprints of asymmetries at the beginning of the explosion, but the final metal distribution is massively affected by the detailed progenitor structure. The most extended and fastest metal fingers and clumps are correlated with the biggest and fastest-rising plumes of neutrino-heated matter, because these plumes most effectively seed the growth of Rayleigh-Taylor (RT) instabilities at the C+O/He and He/H composition-shell interfaces after the passage of the SN shock. The extent of radial mixing, global asymmetry of the metal-rich ejecta, RT-induced fragmentation of initial plumes to smaller-scale fingers, and maximum Ni and minimum H velocities depend not only on the initial asphericity and explosion energy (which determine the shock and initial Ni velocities), but also on the density profiles and widths of C+O core and He shell and on the density gradient at the He/H transition, which leads to unsteady shock propagation and the formation of reverse shocks. Both RSG explosions retain a large global metal asymmetry with pronounced clumpiness and substructure, deep penetration of Ni fingers into the H-envelope (with maximum velocities of 4000-5000 km s-1 for an explosion energy around 1.5 bethe) and efficient inward H-mixing. While the 15 M⊙ BSG shares these properties (maximum Ni speeds up to ~3500 km s-1), the 20 M⊙ BSG develops a much more roundish geometry without pronounced metal fingers (maximum Ni velocities only ~2200 km s-1) because of reverse-shock deceleration and insufficient time for strong RT growth and fragmentation at the He

X-ray emission from reverse-shocked ejecta in supernova remnants

Science.gov (United States)

Cioffi, Denis F.; Mckee, Christopher F.

1990-01-01

A simple physical model of the dynamics of a young supernova remnant is used to derive a straightforward kinematical description of the reverse shock. With suitable approximations, formulae can then be developed to give the X-ray emission of the reverse-shocked ejecta. The results are found to agree favorably with observations of SN1006.

On the Fielding of a High Gain, Shock-Ignited Target on the National Ignitiion Facility in the Near Term

International Nuclear Information System (INIS)

Perkins, L.J.; Betti, R.; Schurtz, G.P.; Craxton, R.S.; Dunne, A.M.; LaFortune, K.N.; Schmitt, A.J.; McKenty, P.W.; Bailey, D.S.; Lambert, M.A.; Ribeyre, X.; Theobald, W.R.; Strozzi, D.J.; Harding, D.R.; Casner, A.; Atzemi, S.; Erbert, G.V.; Andersen, K.S.; Murakami, M.; Comley, A.J.; Cook, R.C.; Stephens, R.B.

2010-01-01

Shock ignition, a new concept for igniting thermonuclear fuel, offers the possibility for a near-term (∼3-4 years) test of high gain inertial confinement fusion on the National Ignition Facility at less than 1MJ drive energy and without the need for new laser hardware. In shock ignition, compressed fusion fuel is separately ignited by a strong spherically converging shock and, because capsule implosion velocities are significantly lower than those required for conventional hotpot ignition, fusion energy gains of ∼60 may be achievable on NIF at laser drive energies around ∼0.5MJ. Because of the simple all-DT target design, its in-flight robustness, the potential need for only 1D SSD beam smoothing, minimal early time LPI preheat, and use of present (indirect drive) laser hardware, this target may be easier to field on NIF than a conventional (polar) direct drive hotspot ignition target. Like fast ignition, shock ignition has the potential for high fusion yields at low drive energy, but requires only a single laser with less demanding timing and spatial focusing requirements. Of course, conventional symmetry and stability constraints still apply. In this paper we present initial target performance simulations, delineate the critical issues and describe the immediate-term R and D program that must be performed in order to test the potential of a high gain shock ignition target on NIF in the near term.

Dual-targeting hybrid nanoparticles for the delivery of SN38 to Her2 and CD44 overexpressed human gastric cancer

Science.gov (United States)

Yang, Zhe; Luo, Huiyan; Cao, Zhong; Chen, Ya; Gao, Jinbiao; Li, Yingqin; Jiang, Qing; Xu, Ruihua; Liu, Jie

2016-06-01

Gastric cancer (GC), particularly of the type with high expression of both human epidermal growth factor receptor 2 (Her2) and cluster determinant 44 (CD44), is one of the most malignant human tumors which causes a high mortality rate due to rapid tumor growth and metastasis. To develop effective therapeutic treatments, a dual-targeting hybrid nanoparticle (NP) system was designed and constructed to deliver the SN38 agent specifically to human solid gastric tumors bearing excessive Her2 and CD44. The hybrid NPs consist of a particle core made of the biodegradable polymer PLGA and a lipoid shell prepared by conjugating the AHNP peptides and n-hexadecylamine (HDA) to the carboxyl groups of hyaluronic acid (HA). Upon encapsulation of the SN38 agent in the NPs, the AHNP peptides and HA on the NP surface allow preferential delivery of the drug to gastric cancer cells (e.g., HGC27 cells) by targeting Her2 and CD44. Cellular uptake and in vivo biodistribution experiments verified the active targeting and prolonged in vivo circulation properties of the dual-targeting hybrid NPs, leading to enhanced accumulation of the drug in tumors. Furthermore, the anti-proliferation mechanism studies revealed that the inhibition of the growth and invasive activity of HGC27 cells was not only attributed to the enhanced cellular uptake of dual-targeting NPs, but also benefited from the suppression of CD44 and Her2 expression by HA and AHNP moieties. Finally, intravenous administration of the SN38-loaded dual-targeting hybrid NPs induced significant growth inhibition of HGC27 tumor xenografted in nude mice compared with a clinical antitumor agent, Irinotecan (CPT-11), and the other NP formulations. These results demonstrate that the designed dual-targeting hybrid NPs are promising for targeted anti-cancer drug delivery to treat human gastric tumors over-expressing Her2 and CD44.Gastric cancer (GC), particularly of the type with high expression of both human epidermal growth factor receptor

Rayleigh-Taylor instability and mixing in SN 1987A

International Nuclear Information System (INIS)

Ebisuzaki, T.; Shigeyama, T.; Nomoto, K.

1989-01-01

The stability of the supernova ejecta is compared with the Rayleigh-Taylor instability for a realistic model of SN 1987A. A linear analysis indicates that the layers around the composition interface between the hydrogen-rich and helium zones, and become Rayleigh-Taylor unstable between the helium and metal zones. In these layers, the pressure increases outward because of deceleration due to the reverse shock which forms when the blast shock hits the massive hydrogen-rich envelope. On the contrary, the density steeply decreases outward because of the preexisting nuclear burning shell. Then, these layers undergo the Raleigh-Taylor instability because of the opposite signs of the pressure and density gradients. The estimated growth rate is larger than the expansion rate of the supernova. The Rayleigh-Taylor instability near the composition interface is likely to induce mixing, which has been strongly suggested from observations of SN 1987A. 25 refs

Thermal shock analysis of liquid-mercury spallation target

CERN Document Server

Ishikura, S; Futakawa, M; Hino, R; Date, H

2002-01-01

The developments of the neutron scattering facilities are carried out under the high-intensity proton accelerator project promoted by JAERI and KEK. To estimate the structural integrity of the heavy liquid-metal (Hg) target used as a spallation neutron source in a MW-class neutron scattering facility, dynamic stress behavior due to the incident of a 1 MW-pulsed proton beam was analyzed by using FEM code. Two-type target containers with semi-cylindrical type and flat-plate type window were used as models for analyses. As a result, it is confirmed that the stress (pressure wave) generated by dynamic thermal shock becomes the largest at the center of window, and the flat-plate type window is more advantageous from the structural viewpoint than the semi-cylindrical type window. It has been understood that the stress generated in the window by the pressure wave can be treated as the secondary stress. (author)

High-rate deposition of high-quality Sn-doped In2O3 films by reactive magnetron sputtering using alloy targets

International Nuclear Information System (INIS)

Oka, Nobuto; Kawase, Yukari; Shigesato, Yuzo

2012-01-01

Sn-doped In 2 O 3 (ITO) films were deposited on heated (200 °C) fused silica glass substrates by reactive DC sputtering with mid-frequency pulsing (50 kHz) and a plasma control unit combined with a feedback system of the optical emission intensity for the atomic O* line at 777 nm. A planar In–Sn alloy target was connected to the switching unit, which was operated in the unipolar pulse mode. The power density on the target was maintained at 4.4 W cm −2 during deposition. The feedback system precisely controlled the oxidation of the target surface in “the transition region.” The ITO film with lowest resistivity (3.1 × 10 −4 Ω cm) was obtained with a deposition rate of 310 nm min −1 and transmittance in the visible region of approximately 80%. The deposition rate was about 6 times higher than that of ITO films deposited by conventional sputtering using an oxide target.

Confinement effects of shock waves on laser-induced plasma from a graphite target

Energy Technology Data Exchange (ETDEWEB)

Huang, Feiling; Liang, Peipei; Yang, Xu; Cai, Hua; Wu, Jiada; Xu, Ning; Ying, Zhifeng; Sun, Jian, E-mail: jsun@fudan.edu.cn [Shanghai Ultra-Precision Optical Manufacturing Engineering Center, Department of Optical Science and Engineering, Fudan University, Shanghai 200433 (China)

2015-06-15

The spatial confinement effects of shock waves on the laser-induced plasma (LIP) from a graphite target in air were studied by probe beam deflection (PBD) measurements and optical emission spectroscopy (OES). A clear relationship between the confinement of the LIP by the shock wave and the effects on the LIP emission was observed, and the underlying mechanisms are discussed. PBD monitoring revealed that the laser-ablation induced shock wave could be well analogized to the shock wave generated by a point explosion and would be reflected by a block. OES measurements indicated that the optical emission of the LIP exhibited significant variations with the block placement. A first enhancement and then a fast decay of CN molecular emission as well as a suppression of carbon atomic emission were observed in the presence of the block. The results revealed that the reflected shock wave spatially confined the expansion of the LIP and compressed the LIP after encountering it, pushing back the species of the LIP and changing the density of the LIP species including luminous carbon atoms and CN molecules. It is suggested that the change of the LIP emission is attributed to the density variation of the LIP species due to the compression of the LIP and the reactions occurring in the plasma.

Spherical strong-shock generation for shock-ignition inertial fusion

Energy Technology Data Exchange (ETDEWEB)

Theobald, W.; Seka, W.; Lafon, M.; Anderson, K. S.; Hohenberger, M.; Marshall, F. J.; Michel, D. T.; Solodov, A. A.; Stoeckl, C.; Edgell, D. H.; Yaakobi, B.; Shvydky, A. [Laboratory for Laser Energetics and Fusion Science Center, University of Rochester, Rochester, New York 14623 (United States); Nora, R.; Betti, R. [Laboratory for Laser Energetics and Fusion Science Center, University of Rochester, Rochester, New York 14623 (United States); Department of Mechanical Engineering and Department of Physics, University of Rochester, Rochester, New York 14623 (United States); Casner, A.; Reverdin, C. [CEA, DAM, DIF, F-91297 Arpajon (France); Ribeyre, X.; Vallet, A. [Université de Bordeaux-CNRS-CEA, CELIA (Centre Lasers Intenses et Applications) UMR 5107 F-33400 Talence (France); Peebles, J.; Beg, F. N. [University of California, San Diego, La Jolla, California 92093 (United States); and others

2015-05-15

Recent experiments on the Laboratory for Laser Energetics' OMEGA laser have been carried out to produce strong shocks in solid spherical targets with direct laser illumination. The shocks are launched at pressures of several hundred Mbars and reach Gbar upon convergence. The results are relevant to the validation of the shock-ignition scheme and to the development of an OMEGA experimental platform to study material properties at Gbar pressures. The experiments investigate the strength of the ablation pressure and the hot-electron production at incident laser intensities of ∼2 to 6 × 10{sup 15 }W/cm{sup 2} and demonstrate ablation pressures exceeding 300 Mbar, which is crucial to developing a shock-ignition target design for the National Ignition Facility. The timing of the x-ray flash from shock convergence in the center of the solid plastic target is used to infer the ablation and shock pressures. Laser–plasma instabilities produce hot-electrons with a moderate temperature (<100 keV). The instantaneous conversion efficiencies of laser power into hot-electron power reached up to ∼15% in the intensity spike. The large amount of hot electrons is correlated with an earlier x-ray flash and a strong increase in its magnitude. This suggests that hot electrons contribute to the augmentation of the shock strength.

Power law and exponential ejecta size distributions from the dynamic fragmentation of shock-loaded Cu and Sn metals under melt conditions

Energy Technology Data Exchange (ETDEWEB)

Durand, O.; Soulard, L. [CEA, DAM, DIF, F-91297 Arpajon (France)

2013-11-21

Large scale molecular dynamics (MD) simulations are performed to study and to model the ejecta production from the dynamic fragmentation of shock-loaded metals under melt conditions. A generic 3D crystal in contact with vacuum containing about 10{sup 8} atoms and with a sinusoidal free surface roughness is shock loaded so as to undergo a solid-liquid phase change on shock. The reflection of the shock wave at the interface metal/vacuum gives rise to the ejection of 2D jets/sheets of atoms (Richtmyer-Meshkov instabilities in the continuum limit), which develop and break up, forming ejecta (fragments) of different volumes (or mass). The fragmentation process is investigated by analyzing the evolution of the resulting volume distribution of the ejecta as a function of time. Two metals are studied (Cu and Sn) and the amplitude of the roughness is varied. The simulations show that the associated distributions exhibit a generic behavior with the sum of two distinct terms of varying weight, following the expansion rate of the jets: in the small size limit, the distribution obeys a power law dependence with an exponent equal to 1.15 ± 0.08; and in the large size limit, it obeys an exponential form. These two components are interpreted, with the help of additional simple simulations, as the signature of two different basic mechanisms of fragmentation. The power law dependence results from the fragmentation of a 2D network of ligaments arranged following a fractal (scale free) geometry and generated when the sheets of liquid metal expand and tear. The exponential distribution results from a 1D Poisson fragmentation process of the largest ligaments previously generated. Unlike the power law distribution, it is governed by a characteristic length scale, which may be provided by energy balance principle.

Power law and exponential ejecta size distributions from the dynamic fragmentation of shock-loaded Cu and Sn metals under melt conditions

International Nuclear Information System (INIS)

Durand, O.; Soulard, L.

2013-01-01

Large scale molecular dynamics (MD) simulations are performed to study and to model the ejecta production from the dynamic fragmentation of shock-loaded metals under melt conditions. A generic 3D crystal in contact with vacuum containing about 10 8 atoms and with a sinusoidal free surface roughness is shock loaded so as to undergo a solid-liquid phase change on shock. The reflection of the shock wave at the interface metal/vacuum gives rise to the ejection of 2D jets/sheets of atoms (Richtmyer-Meshkov instabilities in the continuum limit), which develop and break up, forming ejecta (fragments) of different volumes (or mass). The fragmentation process is investigated by analyzing the evolution of the resulting volume distribution of the ejecta as a function of time. Two metals are studied (Cu and Sn) and the amplitude of the roughness is varied. The simulations show that the associated distributions exhibit a generic behavior with the sum of two distinct terms of varying weight, following the expansion rate of the jets: in the small size limit, the distribution obeys a power law dependence with an exponent equal to 1.15 ± 0.08; and in the large size limit, it obeys an exponential form. These two components are interpreted, with the help of additional simple simulations, as the signature of two different basic mechanisms of fragmentation. The power law dependence results from the fragmentation of a 2D network of ligaments arranged following a fractal (scale free) geometry and generated when the sheets of liquid metal expand and tear. The exponential distribution results from a 1D Poisson fragmentation process of the largest ligaments previously generated. Unlike the power law distribution, it is governed by a characteristic length scale, which may be provided by energy balance principle

THE DESTRUCTION OF THE CIRCUMSTELLAR RING OF SN 1987A

International Nuclear Information System (INIS)

Fransson, Claes; Migotto, Katia; Lundqvist, Peter; Taddia, Francesco; Sollerman, Jesper; Larsson, Josefin; Pesce, Dominic; Chevalier, Roger A.; Challis, Peter; Kirshner, Robert P.; France, Kevin; Leibundgut, Bruno; Spyromilio, Jason; McCray, Richard; Jerkstrand, Anders; Mattila, Seppo; Smith, Nathan; Wheeler, J. Craig; Crotts, Arlin; Garnavich, Peter

2015-01-01

We present imaging and spectroscopic observations with Hubble Space Telescope and Very Large Telescope of the ring of SN 1987A from 1994 to 2014. After an almost exponential increase of the shocked emission from the hotspots up to day ∼8000 (∼2009), both this and the unshocked emission are now fading. From the radial positions of the hotspots we see an acceleration of these up to 500–1000 km s −1 , consistent with the highest spectroscopic shock velocities from the radiative shocks. In the most recent observations (2013 and 2014), we find several new hotspots outside the inner ring, excited by either X-rays from the shocks or by direct shock interaction. All of these observations indicate that the interaction with the supernova ejecta is now gradually dissolving the hotspots. We predict, based on the observed decay, that the inner ring will be destroyed by ∼2025

Low-debris, efficient laser-produced plasma extreme ultraviolet source by use of a regenerative liquid microjet target containing tin dioxide (SnO2) nanoparticles

Science.gov (United States)

Higashiguchi, Takeshi; Dojyo, Naoto; Hamada, Masaya; Sasaki, Wataru; Kubodera, Shoichi

2006-05-01

We demonstrated a low-debris, efficient laser-produced plasma extreme ultraviolet (EUV) source by use of a regenerative liquid microjet target containing tin-dioxide (SnO2) nanoparticles. By using a low SnO2 concentration (6%) solution and dual laser pulses for the plasma control, we observed the EUV conversion efficiency of 1.2% with undetectable debris.

Low-debris, efficient laser-produced plasma extreme ultraviolet source by use of a regenerative liquid microjet target containing tin dioxide (SnO2) nanoparticles

International Nuclear Information System (INIS)

Higashiguchi, Takeshi; Dojyo, Naoto; Hamada, Masaya; Sasaki, Wataru; Kubodera, Shoichi

2006-01-01

We demonstrated a low-debris, efficient laser-produced plasma extreme ultraviolet (EUV) source by use of a regenerative liquid microjet target containing tin-dioxide (SnO 2 ) nanoparticles. By using a low SnO 2 concentration (6%) solution and dual laser pulses for the plasma control, we observed the EUV conversion efficiency of 1.2% with undetectable debris

Performing a stellar autopsy using the radio-bright remnant of SN 1996cr

Science.gov (United States)

Meunier, C.; Bauer, F. E.; Dwarkadas, V. V.; Koribalski, B.; Emonts, B.; Hunstead, R. W.; Campbell-Wilson, D.; Stockdale, C.; Tingay, S. J.

2013-05-01

We present newly reduced archival radio observations of SN 1996cr in the Circinus Galaxy from the Australia Telescope Compact Array and the Molonglo Observatory Synthesis Telescope, and attempt to model its radio light curves using recent hydrodynamical simulations of the interaction between the supernova (SN) ejecta and the circumstellar material (CSM) at X-ray wavelengths. The radio data within the first 1000 d show clear signs of free-free absorption (FFA), which decreases gradually and is minimal above 1.4 GHz after day ˜3000. Constraints on the FFA optical depth provide estimates of the CSM free electron density, which allows insight into the ionization of SN 1996cr's CSM and offers a test on the density distribution adopted by the hydrodynamical simulation. The intrinsic spectral index of the radiation shows evidence for spectral flattening, which is characterized by α = 0.852 ± 0.002 at day 3000 and a decay rate of Δα = -0.014 ± 0.001 yr-1. The striking similarity in the spectral flattening of SN 1987A, SN 1993J and SN 1996cr suggests this may be a relatively common feature of SNe/CSM shocks. We adopt this spectral index variation to model the synchrotron radio emission of the shock, and consider several scalings that relate the parameters of the hydrodynamical simulation to the magnetic field and electron distribution. The simulated light curves match the large-scale features of the observed light curves, but fail to match certain tightly constraining sections. This suggests that simple energy density scalings may not be able to account for the complexities of the true physical processes at work, or alternatively, that the parameters of the simulation require modification in order to accurately represent the surroundings of SN 1996cr.

Supernova 2008J: early time observations of a heavily reddened SN 2002ic-like transient

DEFF Research Database (Denmark)

Taddia, F.; Stritzinger, M. D.; Phillips, M. M.

2012-01-01

Aims: We provide additional observational evidence that some Type Ia supernovae (SNe Ia) show signatures of circumstellar interaction (CSI) with hydrogen-rich material. Methods: Early phase optical and near-infrared (NIR) light curves and spectroscopy of SN 2008J obtained by the Carnegie Supernova...... that their CSI emissions are similarly robust. The high-resolution spectrum reveals narrow emission lines produced from un-shocked gas characterized by a wind velocity of ~50 km s-1. We conclude that SN 2008J best matches an explosion of a SN Ia that interacts with its CSM....

Interferometric investigation of shock waves induced by a TEA-CO2 laser produced plasma in air in front of a solid target

International Nuclear Information System (INIS)

Apostol, D.; Apostol, I.; Cojocaru, E.; Draganescu, V.; Mihailescu, N.I.; Morjan, I.; Konov, I.V.

1979-06-01

The shock waves induced in the surrounding atmosphere by an air plasma were investigated by laser interferometry. The air breakdown plasma was produced by a TEA-CO 2 laser in front of a solid target. The results were compared to the predictions of theory of intense explosions in gases and a good agreement was inferred. It was also determined that the symmetry of the expansion of the initial shock wave is determined by the plasma source shape and, accordingly, depends on the laser power density incident on the target surface. However, for further stages all the shock waves expand spherically. (author)

0(gs)+ -->2(1)+ transition strengths in 106Sn and 108Sn.

Science.gov (United States)

Ekström, A; Cederkäll, J; Fahlander, C; Hjorth-Jensen, M; Ames, F; Butler, P A; Davinson, T; Eberth, J; Fincke, F; Görgen, A; Górska, M; Habs, D; Hurst, A M; Huyse, M; Ivanov, O; Iwanicki, J; Kester, O; Köster, U; Marsh, B A; Mierzejewski, J; Reiter, P; Scheit, H; Schwalm, D; Siem, S; Sletten, G; Stefanescu, I; Tveten, G M; Van de Walle, J; Van Duppen, P; Voulot, D; Warr, N; Weisshaar, D; Wenander, F; Zielińska, M

2008-07-04

The reduced transition probabilities, B(E2; 0(gs)+ -->2(1)+), have been measured in the radioactive isotopes (108,106)Sn using subbarrier Coulomb excitation at the REX-ISOLDE facility at CERN. Deexcitation gamma rays were detected by the highly segmented MINIBALL Ge-detector array. The results, B(E2;0(gs)+ -->2(1)+)=0.222(19)e2b2 for 108Sn and B(E2; 0(gs)+-->2(1)+)=0.195(39)e2b2 for 106Sn were determined relative to a stable 58Ni target. The resulting B(E2) values are approximately 30% larger than shell-model predictions and deviate from the generalized seniority model. This experimental result may point towards a weakening of the N=Z=50 shell closure.

Ultrafast streak and framing technique for the observation of laser driven shock waves in transparent solid targets

International Nuclear Information System (INIS)

Van Kessel, C.G.M.; Sachsenmaier, P.; Sigel, R.

1975-01-01

Shock waves driven by laser ablation in plane transparent plexiglass and solid hydrogen targets have been observed with streak and framing techniques using a high speed image converter camera, and a dye laser as a light source. The framing pictures have been made by mode locking the dye laser and using a wide streak slit. In both materials a growing hemispherical shock wave is observed with the maximum velocity at the onset of laser radiation. (author)

INVERSE COMPTON X-RAY EMISSION FROM SUPERNOVAE WITH COMPACT PROGENITORS: APPLICATION TO SN2011fe

International Nuclear Information System (INIS)

Margutti, R.; Soderberg, A. M.; Chomiuk, L.; Milisavljevic, D.; Foley, R. J.; Slane, P.; Moe, M.; Chevalier, R.; Hurley, K.; Hughes, J. P.; Fransson, C.; Barthelmy, S.; Cummings, J.; Boynton, W.; Enos, H.; Fellows, C.; Briggs, M.; Connaughton, V.; Costa, E.; Del Monte, E.

2012-01-01

We present a generalized analytic formalism for the inverse Compton X-ray emission from hydrogen-poor supernovae and apply this framework to SN 2011fe using Swift X-Ray Telescope (XRT), UVOT, and Chandra observations. We characterize the optical properties of SN 2011fe in the Swift bands and find them to be broadly consistent with a 'normal' SN Ia, however, no X-ray source is detected by either XRT or Chandra. We constrain the progenitor system mass-loss rate M-dot -9 M ☉ yr -1 (3σ c.l.) for wind velocity v w = 100 km s –1 . Our result rules out symbiotic binary progenitors for SN 2011fe and argues against Roche lobe overflowing subgiants and main-sequence secondary stars if ∼> 1% of the transferred mass is lost at the Lagrangian points. Regardless of the density profile, the X-ray non-detections are suggestive of a clean environment (n CSM –3 ) for 2 × 10 15 ∼ 16 cm around the progenitor site. This is either consistent with the bulk of material being confined within the binary system or with a significant delay between mass loss and supernova explosion. We furthermore combine X-ray and radio limits from Chomiuk et al. to constrain the post-shock energy density in magnetic fields. Finally, we searched for the shock breakout pulse using gamma-ray observations from the Interplanetary Network and find no compelling evidence for a supernova-associated burst. Based on the compact radius of the progenitor star we estimate that the shock breakout pulse was likely not detectable by current satellites.

Experimental and numerical study of the micro-spalling of metallic targets subjected to laser shock

International Nuclear Information System (INIS)

Loison, D.

2012-01-01

Micro-spalling is a failure phenomenon consisting in dynamic fragmentation of a material after partial or full melting under intense shock wave loading. High power pulsed lasers are used as shock wave generators in laboratory for scientific and industrial purposes, such as research on inertial confinement fusion. In this context, the production of high velocity fragments can damage the facilities where shock experiments are conducted. This thesis, realized in collaboration with different teams from CEA, aims at understanding and modeling the different processes involved in micro-spalling phenomenon. Experiments to study micro-spalling of laser shock-loaded tin and aluminum targets have been performed. Various and complementary diagnostics (photonic Doppler velocimetry, soft recovery of debris and microtomography) have been used to characterize the ballistic properties (size distributions and velocities) of droplets constituting the micro-spalling cloud. In parallel, phase transition and fragmentation models have been adapted to simulate micro-spalling. These models have been implemented in a code to predict the sizes and velocities of debris. The combination of experimental and numerical results allows characterizing the successive stages of micro-spalling from laser-matter interaction to the ejection of droplets. (author)

The recruitment of the U5 snRNP to nascent transcripts requires internal loop 1 of U5 snRNA.

Science.gov (United States)

Kim, Rebecca; Paschedag, Joshua; Novikova, Natalya; Bellini, Michel

2012-12-01

In this study, we take advantage of the high spatial resolution offered by the nucleus and lampbrush chromosomes of the amphibian oocyte to investigate the mechanisms that regulate the intranuclear trafficking of the U5 snRNP and its recruitment to nascent transcripts. We monitor the fate of newly assembled fluorescent U5 snRNP in Xenopus oocytes depleted of U4 and/or U6 snRNAs and demonstrate that the U4/U6.U5 tri-snRNP is not required for the association of U5 snRNP with Cajal bodies, splicing speckles, and nascent transcripts. In addition, using a mutational analysis, we show that a non-functional U5 snRNP can associate with nascent transcripts, and we further characterize internal loop structure 1 of U5 snRNA as a critical element for licensing U5 snRNP to target both nascent transcripts and splicing speckles. Collectively, our data support the model where the recruitment of snRNPs onto pre-mRNAs is independent of spliceosome assembly and suggest that U5 snRNP may promote the association of the U4/U6.U5 tri-snRNP with nascent transcripts.

Multi-layer protective armour for underwater shock wave mitigation

OpenAIRE

Ahmed Hawass; Hosam Mostafa; Ahmed Elbeih

2015-01-01

The effect of underwater shock wave on different target plates has been studied. An underwater shock wave generator (shock tube) was used to study the interactions between water and different constructed targets which act as shock wave mitigation. Target plates, composed of sandwich of two aluminum sheets with rubber and foam in between, were prepared and studied. For comparison, the target plates composed of triple aluminum sheets were tested. The study includes the testing of the selected p...

Composite Liner, Multi-Megabar Shock Driver Development

International Nuclear Information System (INIS)

Cochrane, J.C. Jr.; Bartsch, R.R.; Clark, D.A.; Morgan, D.V.; Anderson, W.E.; Lee, H.; Bowers, R.L.; Atchison, W.L.; Oona, H.; Stokes, J.L.; Veeser, L.R.; Broste, W.B.

1998-01-01

The multi-megabar shock driver development is a series of experiments in support of the Los Alamos High Energy Density Physics Experimental Program. Its purpose is to develop techniques to impact a uniform, stable, composite liner upon a high Z target to produce a multi-megabar shock for EOS studies. To date, experiments have been done on the Pegasus II capacitor bank with a current of approximately12MA driving the impactor liner. The driving field is approximately200 T at the target radius of 1cm. Data will be presented on the impactor liner. The driving field is approximately200 T at the target radius of 1 cm. Data will be presented on the stability and uniformity of the impactor liner when it impacts the target cylinder. Three experiments have been done with emphasis on liner development. Shock pressures greater than a megabar have been done with emphasis on liner development. Shock pressures greater than a megabar have been produced with an Al target cylinder. A Pt target cylinder should produce shock pressures in th e 5-megabar range

Electron transport and shock ignition

Energy Technology Data Exchange (ETDEWEB)

Bell, A R; Tzoufras, M, E-mail: t.bell1@physics.ox.ac.uk [Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU (United Kingdom)

2011-04-15

Inertial fusion energy (IFE) offers one possible route to commercial energy generation. In the proposed 'shock ignition' route to fusion, the target is compressed at a relatively low temperature and then ignited using high intensity laser irradiation which drives a strong converging shock into the centre of the fuel. With a series of idealized calculations we analyse the electron transport of energy into the target, which produces the pressure responsible for driving the shock. We show that transport in shock ignition lies near the boundary between ablative and heat front regimes. Moreover, simulations indicate that non-local effects are significant in the heat front regime and might lead to increased efficiency by driving the shock more effectively and reducing heat losses to the plasma corona.

Whisker and Hillock formation on Sn, Sn-Cu and Sn-Pb electrodeposits

International Nuclear Information System (INIS)

Boettinger, W.J.; Johnson, C.E.; Bendersky, L.A.; Moon, K.-W.; Williams, M.E.; Stafford, G.R.

2005-01-01

High purity bright Sn, Sn-Cu and Sn-Pb layers, 3, 7 and 16 μm thick were electrodeposited on phosphor bronze cantilever beams in a rotating disk apparatus. Beam deflection measurements within 15 min of plating proved that all electrodeposits had in-plane compressive stress. In several days, the surfaces of the Sn-Cu deposits, which have the highest compressive stress, develop 50 μm contorted hillocks and 200 μm whiskers, pure Sn deposits develop 20 μm compact conical hillocks, and Sn-Pb deposits, which have the lowest compressive stress, remain unchanged. The differences between the initial compressive stresses for each alloy and pure Sn is due to the rapid precipitation of Cu 6 Sn 5 or Pb particles, respectively, within supersaturated Sn grains produced by electrodeposition. Over longer time, analysis of beam deflection measurements indicates that the compressive stress is augmented by the formation of Cu 6 Sn 5 on the bronze/Sn interface, while creep of the electrodeposit tends to decrease the compressive stress. Uniform creep occurs for Sn-Pb because it has an equi-axed grain structure. Localized creep in the form of hillocks and whiskers occurs for Sn and Sn-Cu because both have columnar structures. Compact hillocks form for the Sn deposits because the columnar grain boundaries are mobile. Contorted hillocks and whiskers form for the Sn-Cu deposits because the columnar grain boundary motion is impeded

Shock-wave induced mechanoluminescence: A new technique for studying effects of shock pressure on crystals

Energy Technology Data Exchange (ETDEWEB)

Chandra, B.P.; Parganiha, S.; Sonwane, V.D. [School of Studies in Physics and Astrophysics, Pt. Ravishankar Shukla University, Raipur 492010, Chhattisgarh (India); Chandra, V.K. [Department of Electrical and Electronics Engineering, Chhatrapati Shivaji Institute of Technology, Shivaji Nagar, Kolihapuri, Durg 491001, Chhattisgarh (India); Jha, Piyush, E-mail: piyushjha22@rediffmail.com [Department of Applied Physics, Raipur Institute of Technology, Chhatauna, Mandir Hasuad, Raipur 492101, Chhattisgarh (India); Baghel, R.N. [School of Studies in Physics and Astrophysics, Pt. Ravishankar Shukla University, Raipur 492010, Chhattisgarh (India)

2016-10-15

The impact of a projectile propelled to velocities in the range of 0.5–2.5 km/s on to a target (X-cut quartz crystal) produces shock waves travelling at velocity of nearly 10 km/s in target, in which intense mechanoluminescence (ML) pulses of microsecond duration are produced, both in compression and post-compression conditions. The piezoelectric field produced due to surface charges of fractured target, causes band bending and subsequently, the free charge carriers are generated in the respective bands and the emission of ML occurs. The ML appears after a delay time t{sub th} whose value decreases with increasing value of the shock pressure. Initially, the ML intensity increases with the shock pressure because of the creation of more surfaces; however, for higher values of the shock pressure, the ML intensity tends to attain a saturation value because of the hardening of the crystals due to the creation of small crystallites in which the creation of new surfaces becomes difficult. The ratio between peak ML intensity in the uncompressed region and the maximum ML intensity in the compressed region decreases with increasing shock pressure because more defects produced at high pressure generate higher barrier for the relaxation of blocked cracks under compression. The expressions derived for characteristics of shock-induced ML are able to explain satisfactorily the experimental results. Shock-wave velocity, shock pressure, transit time, lifetime of electrons in conduction band, etc. can be determined by the shock-induced ML.As such, the shock-induced ML provides a new optical technique for the studies of materials under shock pressure.

Convective instabilities in SN 1987A

Science.gov (United States)

Benz, Willy; Thielemann, Friedrich-Karl

1990-01-01

Following Bandiera (1984), it is shown that the relevant criterion to determine the stability of a blast wave, propagating through the layers of a massive star in a supernova explosion, is the Schwarzschild (or Ledoux) criterion rather than the Rayleigh-Taylor criterion. Both criteria coincide only in the incompressible limit. Results of a linear stability analysis are presented for a one-dimensional (spherical) explosion in a realistic model for the progenitor of SN 1987A. When applying the Schwarzschild criterion, unstable regions get extended considerably. Convection is found to develop behind the shock, with a characteristic growth rate corresponding to a time scale much smaller than the shock traversal time. This ensures that efficient mixing will take place. Since the entire ejected mass is found to be convectively unstable, Ni can be transported outward, even into the hydrogen envelope, while hydrogen can be mixed deep into the helium core.

Beta-decay studies near 100Sn

International Nuclear Information System (INIS)

Rykaczewski, Krzysztof Piotr; Karny, M.; Batist, L.; Banu, A.; Becker, F.; Blazhev, A.; Burkard, K.; Bruchle, W.; Doring, J.; Faestermann, T.; Gorska, M.; Grawe, H.; Janas, Z.; Jungclaus, A.; Kavatsyuk, M.; Kavatsyuk, O.; Kirchner, R.; La Commara, M.; Mandal, S.; Mazzocchi, C.; Miernik, K.; Mukha, I.; Muralithar, S.; Plettner, C.; Plochocki, A.; Roeckl, E.; Romoli, M.; Schadel, M.; Schmidt, K.; Schwengner, R.; Zylicz, J.

2005-01-01

The β-decay of 102 Sn was studied by using high-resolution germanium detectors as well as a Total Absorption Spectrometer (TAS). A decay scheme has been constructed based on the γ-γ coincidence data. The total experimental Gamow-Teller strength B GT exp of 102 Sn was deduced from the TAS data to be 4.2(9). A search for β-delayed γ-rays of 100 Sn decay remained unsuccessful. However, a Gamow-Teller hindrance factor h = 2.2(3), and a cross-section of about 3nb for the production of 100 Sn in fusion-evaporation reaction between 58 Ni beam and 50 Cr target have been estimated from the data on heavier tin isotopes. The estimated hindrance factor is similar to the values derived for lower shell nuclei

Pulsed laser deposition of Cu-Sn-S for thin film solar cells

DEFF Research Database (Denmark)

Ettlinger, Rebecca Bolt; Crovetto, Andrea; Bosco, Edoardo

Thin films of copper tin sulfide were deposited from a target of the stoichiometry Cu:Sn:S ~1:2:3 using pulsed laser deposition (PLD). Annealing with S powder resulted in films close to the desired Cu2SnS3 stoichiometry although the films remained Sn rich. Xray diffraction showed that the final...... films contained both cubic-phase Cu2SnS3 and orthorhombic-phase SnS...

Studies of Nuclei Close to 132Sn Using Single-Neutron Transfer Reactions

International Nuclear Information System (INIS)

Jones, K.L.; Pain, S.D.; Kozub, R.L.; Adekola, Aderemi S.; Bardayan, Daniel W.; Blackmon, Jeff C.; Catford, Wilton N.; Chae, K.Y.; Chipps, K.; Cizewski, J.A.; Erikson, Luke; Gaddis, A.L.; Greife, U.; Grzywacz, R.K.; Harlin, Christopher W.; Hatarik, Robert; Howard, Joshua A.; James, J.; Kapler, R.; Krolas, W.; Liang, J. Felix; Ma, Zhanwen; Matei, Catalin; Moazen, Brian; Nesaraja, Caroline D.; O'Malley, Patrick; Patterson, N.P.; Paulauskas, Stanley; Shapira, Dan; Shriner, J.F. Jr.; Sikora, M.; Sissom, D.J.; Smith, Michael Scott; Swan, T.P.; Thomas, J.S.; Wilson, Gemma L.

2009-01-01

Neutron transfer reactions were performed in inverse kinematics using radioactive ion beams of 132Sn, 130Sn, and 134Te and deuterated polyethylene targets. Preliminary results are presented. The Q-value spectra for 133Sn, 131Sn and 135Te reveal a number of previously unobserved peaks. The angular distributions are compatible with the expected lf7/2 nature of the ground state of 133Sn, and 2p3/2 for the 3.4 MeV state in 131Sn.

Geometry of the non-thermal emission in SN 1006. Azimuthal variations of cosmic-ray acceleration

OpenAIRE

Rothenflug, R.; Ballet, J.; Dubner, Gloria Mabel; Giacani, Elsa Beatriz; Decourchelle, A.; Ferrando, P.

2017-01-01

SN 1006 is the prototype of shell supernova remnants, in which non-thermal synchrotron emission dominates the X-ray spectrum. The non-thermal emission is due to the cosmic-ray electrons accelerated behind the blast wave. The X-ray synchrotron emission is due to the highest energy electrons, and is thus a tracer of the maximum energy electrons may reach behind a shock. We have put together all XMM-Newton observations to build a full map of SN 1006. The very low brightness a...

Shock wave compression and self-generated electric field repolarization in ferroelectric ceramics Pb0.99[(Zr0.90Sn0.10)0.96Ti0.04]0.98Nb0.02O3

Science.gov (United States)

Jiang, Dongdong; Du, Jinmei; Gu, Yan; Feng, Yujun

2012-03-01

The shock wave induced depoling current of Pb0.99[(Zr0.90Sn0.10)0.96Ti0.04]0.98Nb0.02O3 ceramics was investigated with a system composed of a resistive load and an unpoled ceramic. Disparity in the depoling current was explained by considering the drawing charge effect of unpoled ceramic. The drawing effect for poled ceramics was analysed by developing a model incorporating a time- and electric-field-dependent repolarization. This model predicts that the high-impedance current eventually becomes higher than the short-circuit current, which is consistent with the experimental results in the literature. This work indicates that both the repolarization of uncompressed ceramics caused by the self-generated electric field and depolarization of compressed ceramics caused by the shock wave govern the output current.

Shock wave compression and self-generated electric field repolarization in ferroelectric ceramics Pb0.99[(Zr0.90Sn0.10)0.96Ti0.04]0.98Nb0.02O3

International Nuclear Information System (INIS)

Jiang Dongdong; Du Jinmei; Gu Yan; Feng Yujun

2012-01-01

The shock wave induced depoling current of Pb 0.99 [(Zr 0.90 Sn 0.10 ) 0.96 Ti 0.04 ] 0.98 Nb 0.02 O 3 ceramics was investigated with a system composed of a resistive load and an unpoled ceramic. Disparity in the depoling current was explained by considering the drawing charge effect of unpoled ceramic. The drawing effect for poled ceramics was analysed by developing a model incorporating a time- and electric-field-dependent repolarization. This model predicts that the high-impedance current eventually becomes higher than the short-circuit current, which is consistent with the experimental results in the literature. This work indicates that both the repolarization of uncompressed ceramics caused by the self-generated electric field and depolarization of compressed ceramics caused by the shock wave govern the output current. (paper)

Evaluation of Cu2ZnSnS4 Absorber Films Sputtered from a Single, Quaternary Target

OpenAIRE

Carlhamn Rasmussen, Liv

2013-01-01

Cu2ZnSnS4 (CZTS) is a promising absorber material for thin-film solar cells since it contains no rare or toxic elements, has a high absorption coefficient and a near ideal bandgap energy. It does, however, present some challenges due to the limited single-phase region of the desired kesterite phase and its instability towards decomposition. Sputtering of CZTS from quaternary, compound targets using RF magnetron sputtering is known. In this thesis work CZTS absorbers were made using pulsed DC ...

Nuclear-spectroscopic studies in the {sup 132}Sn region; Kernspektroskopische Untersuchungen in der {sup 132}Sn-Region

Energy Technology Data Exchange (ETDEWEB)

Arndt, Oliver

2007-10-15

In this work investigations on r-process nuclides around the N = 82 shell closure are done. The so far unknown half-lives and P{sub n}-values of {sup 137-139}Sb and {sup 139}Te and their impact to r-process theory are given. Further the results of Shergur et. al. of neutron rich tin ({sup 137,138}Sn) are verified and in some points improved. New data on {gamma}-decay spectroscopy for {sup 136}Sn from single spectra is published. To improve beam quality and solve long known problems on ISOL-facilities with isobaric contamination, new techniques are discussed. A special focus is on molecular sidebands, which is first time adapted to a target/ion source unit in a mass separation facility. It was possible to create a strong SnS{sup +} sideband and in this way to reduce isobaric background with good beam intensities. On the other hand, a target with temperature controlled transfer line was build and its characteristics are discussed. To improve selectivity of a given experiment on neutron rich nuclei a new detector system for n{gamma}-coincidences was developed. Due to a special electronically setup of the new system it was possible to downsize the coincidence window compared to earlier attempts. (orig.)

Growth of intermetallics between Sn/Ni/Cu, Sn/Ag/Cu and Sn/Cu layered structures

International Nuclear Information System (INIS)

Horváth, Barbara; Illés, Balázs; Shinohara, Tadashi

2014-01-01

Intermetallic growth mechanisms and rates are investigated in Sn/Ni/Cu, Sn/Ag/Cu and Sn/Cu layer systems. An 8–10 μm thick Sn surface finish layer was electroplated onto a Cu substrate with a 1.5–2 μm thick Ni or Ag barrier layer. In order to induce intermetallic layer growth, the samples were aged in elevated temperatures: 50 °C and 125 °C. Intermetallic layer growth was checked by focused ion beam–scanning ion microscope. The microstructures and chemical compositions of the intermetallic layers were observed with a transmission electron microscope. It has been found that Ni barrier layers can effectively block the development of Cu 6 Sn 5 intermetallics. The intermetallic growth characteristics in the Sn/Cu and Sn/Ni/Cu systems are very similar. The intermetallic layer grows towards the Sn layer and forms a discrete layer. Differences were observed only in the growth gradients and surface roughness of the intermetallic layer which may explain the different tin whiskering properties. It was observed that the intermetallic layer growth mechanisms are completely different in the Ag barrier layers compared to the Ni layers. In the case of Sn/Ag/Cu systems, the Sn and Cu diffused through the Ag layer, formed Cu 6 Sn 5 intermetallics mainly at the Sn/Ag interface and consumed the Ag barrier layer. - Highlights: • Intermetallic growth was characterised in Sn/Ni/Cu, Sn/Ag/Cu and Sn/Cu layer systems. • Intermetallic growth rates and roughness are similar in the Sn/Cu and Sn/Ni/Cu systems. • Sn/Ni/Cu system contains the following intermetallic layer structure Sn–Ni3Sn4–Ni3Sn2–Ni3Sn–Ni. • In the case of Sn/Ag/Cu systems the Sn and Cu diffusion consumes the Ag barrier layer. • When Cu reaches the Sn/Ag interface a large amount of Cu 6 Sn 5 forms above the Ag layer

TARGETED DELETION OF INDUCIBLE HEAT SHOCK PROTEIN 70 ABROGATES THE LATE INFARCT-SPARING EFFECT OF MYOCARDIAL ISCHEMIC PRECONDITIONING

Science.gov (United States)

Abstract submitted for 82nd annual meeting of the American Association for Thoracic Surgery, May 4-8, 2002 in Washington D.C.Targeted Deletion of Inducible Heat Shock Protein 70 Abrogates the Late Infarct-Sparing Effect of Myocardial Ischemic PreconditioningCraig...

Comparison of the electrochemical performance of mesoscopic Cu2Sb, SnSb and Sn/SnSb alloy powders

International Nuclear Information System (INIS)

Zhang Ge; Huang Kelong; Liu Suqin; Zhang Wei; Gong Benli

2006-01-01

Cu 2 Sb, SnSb and Sn/SnSb mesoscopic alloy powders were prepared by chemical reduction, respectively. The crystal structures and particle morphology of Cu 2 Sb, SnSb and Sn/SnSb were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM). The electrochemical performances of the Cu 2 Sb, SnSb and Sn/SnSb electrodes were investigated by galvanostatic charge and discharge cycling and electrochemical impedance spectroscopy (EIS). The results showed the first charge and discharge capacities of SnSb and Sn/SnSb were higher than Cu 2 Sb, but after 15 cycles, the charge capacity fading rates of Cu 2 Sb, Sn/SnSb and Sn/SnSb were 26.16%, 55.33% and 47.39%, respectively. Cu 2 Sb had a better cycle performance, and Sn/SnSb multiphase alloy was prior to pure SnSb due to the existence of excessive Sn in Sn/SnSb system

Detection of DNA hybridization based on SnO2 nanomaterial enhanced fluorescence

International Nuclear Information System (INIS)

Gu Cuiping; Huang Jiarui; Ni Ning; Li Minqiang; Liu Jinhuai

2008-01-01

In this paper, enhanced fluorescence emissions were firstly investigated based on SnO 2 nanomaterial, and its application in the detection of DNA hybridization was also demonstrated. The microarray of SnO 2 nanomaterial was fabricated by the vapour phase transport method catalyzed by patterned Au nanoparticles on a silicon substrate. A probe DNA was immobilized on the substrate with patterned SnO 2 nanomaterial, respectively, by covalent and non-covalent linking schemes. When a fluorophore labelled target DNA was hybridized with a probe DNA on the substrate, fluorescence emissions were only observed on the surface of SnO 2 nanomaterial, which indicated the property of enhancing fluorescence signals from the SnO 2 nanomaterial. By comparing the different fluorescence images from covalent and non-covalent linking schemes, the covalent method was confirmed to be more effective for immobilizing a probe DNA. With the combined use of SnO 2 nanomaterial and the covalent linking scheme, the target DNA could be detected at a very low concentration of 10 fM. And the stability of SnO 2 nanomaterial under the experimental conditions was also compared with silicon nanowires. The findings strongly suggested that SnO 2 nanomaterial could be extensively applied in detections of biological samples with enhancing fluorescence property and high stability

Heat shock protein 90 (Hsp90) chaperone complex. A molecular target for enhancement of thermosensitivity and radiosensitivity

International Nuclear Information System (INIS)

Akimoto, Tetsuo; Nonaka, Tetsuo; Kitamoto, Yoshizumi; Sakurai, Hideyuki

2002-01-01

Heat shock protein 90 (Hsp90) is a highly conserved heat shock protein in animal and plants, and exists abundantly in the cytoplasm in unstressed condition, accounting for 1-2% in cytoplasmic proteins. Main difference of Hsp90 from other Hsps are its substrate that Hsp90 binds to. These substrates include various signal transduction proteins, kinase, steroid receptors and transcription factors, therefore, Hsp90 plays a key role in maintaining cellular signal transduction networks. Many chaperoned proteins (client proteins) of Hsp90 are associated with cellular proliferation or malignant transformation, thus Hsp90 chaperone complex has been focused as targets for cancer therapy. Among the client proteins, there are several molecules that have been defined as targets or factors for determination or enhancement of radiosensitivity or thermosensitivity. Thus, it is easily speculated that Hsp90 chaperone complex inhibitors that disrupt association of Hsp90 and client protein in combination with radiation or/and heat has potential effect on enhancement of radiosensitivity or thermosensitivity. In this paper, possible mechanisms in enhancing radiosensitivity or thermosensitivity according to the client proteins will be summarized. (author)

Electrical and optical characteristics of ITO films by pulsed laser deposition using a 10 wt.% SnO2-doped In2O3 ceramic target

International Nuclear Information System (INIS)

Kim, Sang Hyeob; Park, Nae-Man; Kim, TaeYoub; Sung, GunYong

2005-01-01

We have investigated the effect of the oxygen pressure and the deposition temperature on the electrical and optical properties of the Sn-doped indium oxide (ITO) films on quartz glass substrate by pulsed laser deposition (PLD) using a 10 wt.% SnO 2 -doped In 2 O 3 target. The resistivity and the carrier concentration of the films were decreased due to the decrease of the oxygen vacancy while increasing the oxygen pressure. With increasing deposition temperature, the resistivity of the films was decreased and the carrier concentration was increased due to the grain growth and the enhancement of the Sn diffusion. We have optimized the PLD process to deposit a highly conductive and transparent ITO film, which shows the optical transmittance of 88% and the resistivity of 2.49x10 -4 Ω cm for the film thickness of 180 nm

Decay properties of nuclei in the neighbourhood of {sup 100}Sn; Zerfallseigenschaften von Nukliden in der Umgebung von {sup 100}Sn

Energy Technology Data Exchange (ETDEWEB)

Straub, Katrin

2011-01-24

This thesis concentrates on nuclear properties of very neutron deficient nuclei near the proton dripline in the neighbourhood of doubly-magic {sup 100}Sn. In an experiment performed in March 2008 at the GSI in Darmstadt, the exotic nuclei were produced in a projectile fragmentation reaction using a {sup 124}Xe primary beam with an energy of 100 AMeV impinging on a 4000 Beryllium target, separated and identified in the FRS and eventually stopped for decay spectroscopy in a complex implantation detector developed at the institute E12. The Germanium array RISING was employed for the measurement of prompt and delayed gamma radiation. Production cross sections and half lives were determined along the proton dripline. The isotopes {sup 99}Sn, {sup 97}In and {sup 95}Cd were identified for the first time. additional nuclei studied in this thesis are {sup 103}Sn, {sup 96}Cd as well as the two tin isotopes {sup 101}Sn and {sup 102}Sn. (orig.)

Biotin decorated PLGA nanoparticles containing SN-38 designed for cancer therapy.

Science.gov (United States)

Mehdizadeh, Mozhdeh; Rouhani, Hasti; Sepehri, Nima; Varshochian, Reyhaneh; Ghahremani, Mohammad Hossein; Amini, Mohsen; Gharghabi, Mehdi; Ostad, Seyed Nasser; Atyabi, Fatemeh; Baharian, Azin; Dinarvand, Rassoul

2017-05-01

Active targeted chemotherapy is expected to provide more specific delivery of cytotoxic drugs to the tumor cells and hence reducing the side effects on healthy tissues. Due to the over expression of biotin receptors on cancerous cells as a result of further requirement for rapid proliferations, biotin can be a good candidate as a targeting agent. In this study, biotin decorated PLGA nanoparticles (NPs) containing SN-38 were prepared and in vitro studies were evaluated for their improved anti-cancer properties. In conclusion, biotin targeted PLGA NPs containing SN-38 showed preferential anticancer properties against tumor cells with biotin receptor over expression.

EARLY ULTRAVIOLET/OPTICAL EMISSION OF THE TYPE Ib SN 2008D

Energy Technology Data Exchange (ETDEWEB)

Bersten, Melina C.; Nomoto, Ken' ichi [Kavli Institute for the Physics and Mathematics of the Universe, Todai Institutes for Advanced Study, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8583 (Japan); Tanaka, Masaomi [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Tominaga, Nozomu [Department of Physics, Faculty of Science and Engineering, Konan University, 8-9-1 Okamoto, Kobe, Hyogo 658-8501 (Japan); Benvenuto, Omar G., E-mail: melina.bersten@ipmu.jp [Facultad de Ciencias Astronomicas y Geofisicas, Universidad Nacional de La Plata, Paseo del Bosque S/N, B1900FWA La Plata (Argentina)

2013-04-20

We propose an alternative explanation for the post-breakout emission of SN 2008D associated with the X-ray transient 080109. Observations of this object show a very small contrast of 0.35 dex between the light-curve minimum occurring soon after the breakout, and the main luminosity peak which is due to radioactive heating of the ejecta. Hydrodynamical models show that the cooling of a shocked Wolf-Rayet star leads to a much greater difference ({approx}> 0.9 dex). Our proposed scenario is that of a jet produced during the explosion which deposits {sup 56}Ni-rich material in the outer layers of the ejecta. The presence of high-velocity radioactive material allows us to reproduce the complete luminosity evolution of the object. Without outer {sup 56}Ni it could be possible to reproduce the early emission purely from cooling of the shocked envelope by assuming a larger progenitor than a Wolf-Rayet star, but that would require an initial density structure significantly different from what is predicted by stellar evolution models. Analytic models of the cooling phase have been proposed reproduce the early emission of SN 2008D with an extended progenitor. However, we found that the models are valid only until 1.5 days after the explosion where only two data of SN 2008D are available. We also discuss the possibility of the interaction of the ejecta with a binary companion, based on published analytic expressions. However, the binary separation required to fit the early emission should be {approx}< 3 R{sub Sun }, which is too small for a system containing two massive stars.

Direct Observation of Strong Ion Coupling in Laser-Driven Shock-Compressed Targets

International Nuclear Information System (INIS)

Ravasio, A.; Benuzzi-Mounaix, A.; Loupias, B.; Ozaki, N.; Rabec le Gloahec, M.; Koenig, M.; Gregori, G.; Daligault, J.; Delserieys, A.; Riley, D.; Faenov, A. Ya.; Pikuz, T. A.

2007-01-01

In this Letter we report on a near collective x-ray scattering experiment on shock-compressed targets. A highly coupled Al plasma was generated and probed by spectrally resolving an x-ray source forward scattered by the sample. A significant reduction in the intensity of the elastic scatter was observed, which we attribute to the formation of an incipient long-range order. This speculation is confirmed by x-ray scattering calculations accounting for both electron degeneracy and strong coupling effects. Measurements from rear side visible diagnostics are consistent with the plasma parameters inferred from x-ray scattering data. These results give the experimental evidence of the strongly coupled ionic dynamics in dense plasmas

Incidence of cavitation in the fragmentation process of extracorporeal shock wave lithotriptors

Science.gov (United States)

Rink, K.; Delacrétaz, G.; Pittomvils, G.; Boving, R.; Lafaut, J. P.

1994-05-01

The fragmentation mechanism occurring in extracorporeal shock wave lithotripsy (ESWL) is investigated using a fiber optic stress sensing technique. With our technique, we demonstrate that cavitation is a major cause of fragmentation in ESWL procedures. When a target is placed in the operating area of the lithotriptor, two shock waves are detected. The first detected shock wave corresponds to the incoming shock wave generated by the lithotriptor. The second shock wave, detected some hundreds of microseconds later, is generated in situ. It results from the collapse of a cavitation bubble, formed by the reflection of the incoming shock wave at the target boundary. This cavitation induced shock wave generates the largest stress in the target area according to our stress sensing measurements.

Production and application of Sn-117m

International Nuclear Information System (INIS)

Vucina, J.; Nikolic, N.; Orlic, M.

2005-01-01

For targeted therapy in nuclear medicine, besides the usually used, like 32 P, 89 Sr, 131 I, 186,188 Re, new radioisotopes are intensively investigated. Particular interest is devoted to 117m Sn. It decays by isomeric transition with the emission of low energy conversion electrons and short range. Their potent lethality, due to high LET, particularly when the emitter is located inside the cell, on or near nucleus, is well known. The accompanying gamma rays (Eγ = 159 keV) are also suitable for detection. At present, the specific activity which can be achieved in nuclear reactors is is sufficient for the production of agents for bone palliation. The best results so far were achieved with 117m Sn(IV)-DTPA. It is expected that the use of this radioisotope will increase when a method of its production in the no-carrier form will be developed. In the paper the production of 117m Sn and 117m Sn radiopharmaceuticals is briefly reviewed. (author) [sr

SN Refsdal

DEFF Research Database (Denmark)

Kelly, P. L.; Brammer, G.; Selsing, J.

2016-01-01

(SNe), and we find strong evidence for a broad H-alpha P-Cygni profile in the HST grism spectrum at the redshift (z = 1.49) of the spiral host galaxy. SNe IIn, powered by circumstellar interaction, could provide a good match to the light curve of SN Refsdal, but the spectrum of a SN IIn would not show...... in the rest frame, provide additional evidence that supports the SN 1987A-like classification. In comparison with other examples of SN 1987A-like SNe, SN Refsdal has a blue B-V color and a high luminosity for the assumed range of potential magnifications. If SN Refsdal can be modeled as a scaled version of SN...

Shock physics with the nova laser for ICF applications. Revision 1

International Nuclear Information System (INIS)

Hammel, B.A.; Cauble, R.; Celliers, P.

1995-01-01

The physics of high pressure shocks plays a central role in Inertial Confinement Fusion (ICF). In indirect drive ICF, x-rays from a gold cavity (hohlraum) are used to ablatively drive a series of high pressure shocks into a spherical target (capsule). These shocks converge at the center, compressing the fuel and forming a hot dense core. The target performance, such as peak fuel density and temperature and neutron yield, depends critically on hock timing, and material compressibility. Accurate predictions of NIF target performance depends critically on shock timing and material compressibility. Current measurement techniques enable us to accurately determine shock timing in planar samples of abator material as a function of laser drive. Although this technique does not separately address uncertainties in material EOS and opacity, it does allow us to tune the laser drive until the desired shock timing is achieved. Experiments to directly address the EOS of D 2 ice are planned to further increase the margin for ignition in current target designs

XRF 100316D/SN 2010bh AND THE NATURE OF GAMMA-RAY BURST SUPERNOVAE

International Nuclear Information System (INIS)

Cano, Z.; Bersier, D.; Guidorzi, C.; Kobayashi, S.; Melandri, A.; Mundell, C. G.; Levan, A. J.; Tanvir, N. R.; Wiersema, K.; D'Avanzo, P.; Margutti, R.; Fruchter, A. S.; Garnavich, P.; Gomboc, A.; Kopac, D.; Gorosabel, J.; Kasen, D.; Mazzali, P. A.; Nugent, P. E.; Pian, E.

2011-01-01

We present ground-based and Hubble Space Telescope optical and infrared observations of Swift XRF 100316D/SN 2010bh. It is seen that the optical light curves of SN 2010bh evolve at a faster rate than the archetype gamma-ray burst supernova (GRB-SN) 1998bw, but at a similar rate to SN 2006aj, an SN that was spectroscopically linked with XRF 060218, and at a similar rate to the non-GRB associated Type Ic SN 1994I. We estimate the rest-frame extinction of this event from our optical data to be E(B - V) = 0.18 ± 0.08 mag. We find the V-band absolute magnitude of SN 2010bh to be M V = -18.62 ± 0.08, which is the faintest peak V-band magnitude observed to date for spectroscopically confirmed GRB-SNe. When we investigate the origin of the flux at t - t 0 = 0.598 days, it is shown that the light is not synchrotron in origin, but is likely coming from the SN shock breakout. We then use our optical and infrared data to create a quasi-bolometric light curve of SN 2010bh, which we model with a simple analytical formula. The results of our modeling imply that SN 2010bh synthesized a nickel mass of M Ni ∼ 0.1 M sun , ejected M ej ∼ 2.2 M sun , and has an explosion energy of E k ∼ 1.4 x 10 52 erg. Thus, while SN 2010bh is an energetic explosion, the amount of nickel created during the explosion is much less than that of SN 1998bw and only marginally more than SN 1994I. Finally, for a sample of 22 GRB-SNe we check for a correlation between the stretch factors and luminosity factors in the R band and conclude that no statistically significant correlation exists.

Nuclear-spectroscopic studies in the 132Sn region

International Nuclear Information System (INIS)

Arndt, Oliver

2007-10-01

In this work investigations on r-process nuclides around the N = 82 shell closure are done. The so far unknown half-lives and P n -values of 137-139 Sb and 139 Te and their impact to r-process theory are given. Further the results of Shergur et. al. of neutron rich tin ( 137,138 Sn) are verified and in some points improved. New data on γ-decay spectroscopy for 136 Sn from single spectra is published. To improve beam quality and solve long known problems on ISOL-facilities with isobaric contamination, new techniques are discussed. A special focus is on molecular sidebands, which is first time adapted to a target/ion source unit in a mass separation facility. It was possible to create a strong SnS + sideband and in this way to reduce isobaric background with good beam intensities. On the other hand, a target with temperature controlled transfer line was build and its characteristics are discussed. To improve selectivity of a given experiment on neutron rich nuclei a new detector system for nγ-coincidences was developed. Due to a special electronically setup of the new system it was possible to downsize the coincidence window compared to earlier attempts. (orig.)

Elastic and inelastic {alpha}-scattering cross-sections obtained with the 44 MeV fixed energy Saclay cyclotron on separated targets of {sup 24}Mg, {sup 25}Mg, {sup 26}Mg, {sup 40}Ca, {sup 46}Ti, {sup 48}Ti, {sup 50}Ti, {sup 52}Cr, {sup 54}Fe, {sup 56}Fe, {sup 58}Fe, {sup 58}Ni, {sup 60}Ni, {sup 62}Ni, {sup 64}Ni, {sup 63}Cu, {sup 65}Cu, {sup 64}Zn, {sup 112}Sn, {sup 114}Sn, {sup 116}Sn, {sup 118}Sn, {sup 120}Sn, {sup 122}Sn, {sup 124}Sn and {sup 208}Pb using the Saclay fixed-energy cyclotron; Sections efficaces differentielles elastiques et inelastiques obtenues par diffusion de particules {alpha} de 44 MeV sur des cibles de {sup 24}Mg, {sup 25}Mg, {sup 26}Mg, {sup 40}Ca, {sup 46}Ti, {sup 48}Ti, {sup 50}Ti, {sup 52}Cr, {sup 54}Fe, {sup 56}Fe, {sup 58}Fe, {sup 58}Ni, {sup 60}Ni, {sup 62}Ni, {sup 64}Ni, {sup 63}Cu, {sup 65}Cu, {sup 64}Zn, {sup 112}Sn, {sup 114}Sn, {sup 116}Sn, {sup 118}Sn, {sup 120}Sn, {sup 122}Sn, {sup 124}Sn et {sup 208}Pb au cyclotron a energie fixe de saclay

Energy Technology Data Exchange (ETDEWEB)

Bruge, G [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires. Departement de physique nucleaire, service de physique nucleaire a moyenne energie

1967-01-01

This report contains elastic and inelastic {alpha}-scattering cross-sections obtained with the 44 MeV fixed energy Saclay cyclotron on Mg, Ca, Ti, Cr, Fe, Ni, Co, Zn, Sn and Pb enriched targets. (author) [French] Ce rapport contient les tableaux des sections efficaces differentielles obtenues par diffusion elastique et inelastique des particules {alpha} de 44 MeV, fournies par le cyclotron a energie fixe de Saclay, sur des cibles d'isotopes separes de Mg, Ca, Ti, Cr, Fe, Ni, Co, Zn, Sn et Pb. (auteur)

Simulations of embedded lateral stress gauge profiles in shocked targets

International Nuclear Information System (INIS)

Winter, R E; Harris, E J

2008-01-01

In principle, stress gauges mounted to measure lateral stresses in a shocked matrix allow the shear strength of the material to be determined. However, interpreting the resistance profiles from lateral stress gauges is hindered by the fact that the stress field in the vicinity of the insulating layer in which the gauges are embedded can differ significantly from the stress field that would be generated in the sample if no gauge were present. A series of high resolution Eulerian hydrocode simulations have been run which suggest that the stresses in the insulating layer vary with distance and time in a way that depends on the thickness of the layer, the shock strength and the elastic and plastic properties of both the layer and the matrix. In particular, if the shock velocity in the matrix material is high the stress at a typical gauge position initially rises to a sharp peak then falls with time, but when the shock velocity in the matrix is low the stress rises relatively gradually throughout the time of interest. The shapes of the stress versus time profiles predicted by the hydrocode compare well with the results of lateral gauge experiments on several different materials. It is concluded that lateral gauges can be used to measure the dynamic strength of materials provided high resolution computer simulation is used to take account of the perturbation of the stress field in the shocked sample caused by the gauges

Gas-gun facility for shock wave research at BARC

International Nuclear Information System (INIS)

Gupta, S.C.; Jyoti, G.; Suresh, N.; Sikka, S.K.; Chidambaram, R.; Agarwal, R.G.; Roy, S.; Kakodkar, A.

1995-01-01

For carrying out shock-wave experiments on materials, we have built a 63 mm diameter gas-gun facility at our laboratory. It is capable of accelerating projectiles (about half kg in weight) to velocities up to 1 km/s using N 2 and He gases. These on impacting a target generate shock pressures up to 40 GPa, depending upon the impedance of the impactor and the target. The barrel of the gun is slotted so that a keyed projectile can be fired for combined compression- shear studies. Large samples can be shocked (about 60 mm diameter and 5-10 mm thick), with pressures lasting for a few microseconds. The gun is similar in design to the one at Washington State University. A number of diagnostic techniques have also been developed. These include measurement of projectile velocity, tilt between the impactor and the target, shock velocity in the target, and time resolved in-material stress wave histories in the shock loaded samples. Recovery capsules have also been made to retrieve shocked samples on unloading, which are then analysed using microscopic techniques like x-ray diffraction, Raman and electron microscopy. The gun has been performing well and has already been used for a few phase transition studies. (author). 73 refs., 42 figs

21 CFR 876.5990 - Extracorporeal shock wave lithotripter.

Science.gov (United States)

2010-04-01

..., control console, imaging/localization system, and patient table. Prior to treatment, the urinary stone is targeted using either an integral or stand-alone localization/imaging system. Shock waves are typically... shock wave lithotripter. (a) Identification. An extracorporeal shock wave lithotripter is a device that...

SUPERNOVA PTF 09UJ: A POSSIBLE SHOCK BREAKOUT FROM A DENSE CIRCUMSTELLAR WIND

International Nuclear Information System (INIS)

Ofek, E. O.; Neill, J. D.; Kulkarni, S. R.; Forster, K.; Kasliwal, M. M.; Law, N.; Martin, C.; Quimby, R. M.; Rabinak, I.; Arcavi, I.; Waxman, E.; Gal-Yam, A.; Cenko, S. B.; Bloom, J. S.; Filippenko, A. V.; Poznanski, D.; Nugent, P. E.; Jacobsen, J.; Bildsten, L.; Howell, D. A.

2010-01-01

Type-IIn supernovae (SNe IIn), which are characterized by strong interaction of their ejecta with the surrounding circumstellar matter (CSM), provide a unique opportunity to study the mass-loss history of massive stars shortly before their explosive death. We present the discovery and follow-up observations of an SN IIn, PTF 09uj, detected by the Palomar Transient Factory (PTF). Serendipitous observations by Galaxy Evolution Explorer (GALEX) at ultraviolet (UV) wavelengths detected the rise of the SN light curve prior to the PTF discovery. The UV light curve of the SN rose fast, with a timescale of a few days, to a UV absolute AB magnitude of about -19.5. Modeling our observations, we suggest that the fast rise of the UV light curve is due to the breakout of the SN shock through the dense CSM (n ∼ 10 10 cm -3 ). Furthermore, we find that prior to the explosion the progenitor went through a phase of high mass-loss rate (∼0.1 M sun yr -1 ) that lasted for a few years. The decay rate of this SN was fast relative to that of other SNe IIn.

Deposition of the low resistive ITO-films by means of reactive magnetron sputtering of the In/Sn target on the cold substrate

OpenAIRE

Zhidik, Y. S.; Troyan, P. E.; Baturina, E. V.; Korzhenko, Dmitry Vladimirovich; Yuriev, Yuri Nikolaevich

2016-01-01

Detailed information on the deposition technology of the low-resistive ITO-films in oxygen-containing media by magnetron reactive sputtering from the In(90%)/Sn(10%) target on the cold substrate is given. Developed technology allows deposition ITO-films with sheet resistance transparency higher than 90%. Developed technology is notable for high reproducibility of results and is compatible with production technology of semiconductor devices of optoelectronics.

The high-temperature modification of LuAgSn and high-pressure high-temperature experiments on DyAgSn, HoAgSn, and YbAgSn

Energy Technology Data Exchange (ETDEWEB)

Heying, B.; Rodewald, U.C.; Hermes, W.; Schappacher, F.M.; Riecken, J.F.; Poettgen, R. [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie; Heymann, G.; Huppertz, H. [Muenchen Univ. (Germany). Dept. fuer Chemie und Biochemie; Sebastian, C.P. [Max-Planck-Institut fuer Chemische Physik Fester Stoffe, Dresden (Germany)

2008-02-15

The high-temperature modification of LuAgSn was obtained by arc-melting an equiatomic mixture of the elements followed by quenching the melt on a water-cooled copper crucible. HT-LuAgSn crystallizes with the NdPtSb-type structure, space group P6{sub 3}mc: a = 463.5(1), c = 723.2(1) pm, wR2 = 0.0270, 151 F{sup 2}, and 11 variables. The silver and tin atoms build up two-dimensional, puckered [Ag{sub 3}Sn{sub 3}] networks (276 pm Ag-Sn) that are charge-balanced and separated by the lutetium atoms. The Ag-Sn distances between the [Ag{sub 3}Sn{sub 3}] layers of 294 pm are much longer. Single crystals of isotypic DyAgSn (a = 468.3(1), c = 734.4(1) pm, wR2 = 0.0343, 411 F{sup 2}, and 11 variables) and HoAgSn (a = 467.2(1), c = 731.7(2) pm, wR2 = 0.0318, 330 F{sup 2}, and 11 variables) were obtained from arc-melted samples. Under high-pressure (up to 12.2 GPa) and high-temperature (up to 1470 K) conditions, no transitions to a ZrNiAl-related phase have been observed for DyAgSn, HoAgSn, and YbAgSn. HT-TmAgSn shows Curie-Weiss paramagnetism with {mu}{sub eff} = 7.53(1) {mu}{sub B}/Tm atom and {theta}P = -15.0(5) K. No magnetic ordering was evident down to 3 K. HT-LuAgSn is a Pauli paramagnet. Room-temperature {sup 119}Sn Moessbauer spectra of HT-TmAgSn and HT-LuAgSn show singlet resonances with isomer shifts of 1.78(1) and 1.72(1) mm/s, respectively. (orig.)

High Power Proton Beam Shocks and Magnetohydrodynamics in a Mercury Jet Target for a Neutrino Factory

CERN Document Server

Fabich, A; Fabjan, Christian

2002-01-01

The feasibility of liquid metal jet targets for secondary particle production with high power proton beams has been studied. The main aspects of the thesis were benchmark experiments covering the behaviour of liquid targets under thermal shock waves induced by high power proton beams, and also magnetohydrodynamic effects. Severe challenges were imposed by safety issues and the restricted beam time to the tests in ISOLDE at CERN and at the High Magnetic Field Laboratory at Grenoble. Restricted access times in high radiation level areas were of the order of minutes and in this short time span, the complete experimental setup had to be performed and verified. The involvement of mercury as liquid target material and its activation during beam tests demanded special confinement precautions. The setup for both experiments was based on the use of a high speed camera system for observation of the mercury target. The presence of high radiation or high magnetic field required the installation of the sensitive camera sy...

The Transition of a Type IIL Supernova into a Supernova Remnant: Late-time Observations of SN 2013by

Energy Technology Data Exchange (ETDEWEB)

Black, C. S.; Fesen, R. A. [6127 Wilder Lab, Department of Physics and Astronomy, Dartmouth College, Hanover, NH 03755 (United States); Milisavljevic, D.; Patnaude, D. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Margutti, R. [Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA) and Department of Physics and Astronomy, Northwestern University, Evanston, IL 60208 (United States); Parker, S. [Parkdale Observatory, 225 Warren Road, RDl Oxford, Canterbury 7495 (New Zealand)

2017-10-10

We present early-time Swift and Chandra X-ray data along with late-time optical and near-infrared observations of SN 2013by, a Type IIL supernova (SN) that occurred in the nearby spiral galaxy ESO 138−G10 ( D ∼ 14.8 Mpc). Optical and NIR photometry and spectroscopy follow the late-time evolution of the SN from days +89 to +457 post maximum brightness. The optical spectra and X-ray light curves are consistent with the picture of an SN having prolonged interaction with circumstellar material (CSM) that accelerates the transition from SN to supernova remnant (SNR). Specifically, we find SN 2013by’s H α profile exhibits significant broadening (∼10,000 km s{sup −1}) on day +457, the likely consequence of high-velocity, H-rich material being excited by a reverse shock. A relatively flat X-ray light curve is observed that cannot be modeled using Inverse Compton scattering processes alone, but requires an additional energy source most likely originating from the SN-CSM interaction. In addition, we see the first overtone of CO emission near 2.3 μ m on day +152, signaling the formation of molecules and dust in the SN ejecta and is the first time CO has been detected in a Type IIL SN. We compare SN 2013by with Type IIP SNe, whose spectra show the rarely observed SN-to-SNR transition in varying degrees and conclude that Type IIL SNe may enter the remnant phase at earlier epochs than their Type IIP counterparts.

Toward connecting core-collapse supernova theory with observations. I. Shock revival in a 15 M ☉ blue supergiant progenitor with SN 1987A energetics

International Nuclear Information System (INIS)

Handy, Timothy; Plewa, Tomasz; Odrzywołek, Andrzej

2014-01-01

We study the evolution of the collapsing core of a 15 M ☉ blue supergiant supernova progenitor from the core bounce until 1.5 s later. We present a sample of hydrodynamic models parameterized to match the explosion energetics of SN 1987A. We find the spatial model dimensionality to be an important contributing factor in the explosion process. Compared to two-dimensional (2D) simulations, our three-dimensional (3D) models require lower neutrino luminosities to produce equally energetic explosions. We estimate that the convective engine in our models is 4% more efficient in 3D than in 2D. We propose that the greater efficiency of the convective engine found in 3D simulations might be due to the larger surface-to-volume ratio of convective plumes, which aids in distributing energy deposited by neutrinos. We do not find evidence of the standing accretion shock instability or turbulence being a key factor in powering the explosion in our models. Instead, the analysis of the energy transport in the post-shock region reveals characteristics of penetrative convection. The explosion energy decreases dramatically once the resolution is inadequate to capture the morphology of convection on large scales. This shows that the role of dimensionality is secondary to correctly accounting for the basic physics of the explosion. We also analyze information provided by particle tracers embedded in the flow and find that the unbound material has relatively long residency times in 2D models, while in 3D a significant fraction of the explosion energy is carried by particles with relatively short residency times.

High-Gain Shock Ignition on the National Ignition Facility

Science.gov (United States)

Perkins, L. J.; Lafortune, K.; Bailey, D.; Lambert, M.; MacKinnon, A.; Blackfield, D.; Comley, A.; Schurtz, G.; Ribeyre, X.; Lebel, E.; Casner, A.; Craxton, R. S.; Betti, R.; McKenty, P.; Anderson, K.; Theobald, W.; Schmitt, A.; Atzeni, S.; Schiavi, A.

2010-11-01

Shock ignition offers the possibility for a near-term test of high-gain ICF on the NIF at less than 1MJ drive energy and with day-1 laser hardware. We will summarize the status of target performance simulations, delineate the critical issues and describe the R&D program to be performed in order to test the potential of a shock-ignited target on NIF. In shock ignition, compressed fuel is separately ignited by a late-time laser-driven shock and, because capsule implosion velocities are significantly lower than those required for conventional hotpot ignition, simulations indicate that fusion energy gains of 60 may be achievable at laser energies around 0.5MJ. Like fast ignition, shock ignition offers high gain but requires only a single laser with less demanding timing and focusing requirements. Conventional symmetry and stability constraints apply, thus a key immediate step towards attempting shock ignition on NIF is to demonstrate adequacy of low-mode uniformity and shock symmetry under polar drive

Pseudomorphic GeSiSn, SiSn and Ge layers in strained heterostructures

Science.gov (United States)

Timofeev, V. A.; Nikiforov, A. I.; Tuktamyshev, A. R.; Mashanov, V. I.; Loshkarev, I. D.; Bloshkin, A. A.; Gutakovskii, A. K.

2018-04-01

The GeSiSn, SiSn layer growth mechanisms on Si(100) were investigated and the kinetic diagrams of the morphological GeSiSn, SiSn film states in the temperature range of 150 °C-450 °C at the tin content from 0% to 35% were built. The phase diagram of the superstructural change on the surface of Sn grown on Si(100) in the annealing temperature range of 0 °C-850 °C was established. The specular beam oscillations were first obtained during the SiSn film growth from 150 °C to 300 °C at the Sn content up to 35%. The transmission electron microscopy and x-ray diffractometry data confirm the crystal perfection and the pseudomorphic GeSiSn, SiSn film state, and also the presence of smooth heterointerfaces between GeSiSn or SiSn and Si. The photoluminescence for the multilayer periodic GeSiSn/Si structures in the range of 0.6-0.8 eV was detected. The blue shift with the excitation power increase is observed suggesting the presence of a type II heterostructure. The creation of tensile strained Ge films, which are pseudomorphic to the underlying GeSn layer, is confirmed by the results of the formation and analysis of the reciprocal space map in the x-ray diffractometry. The tensile strain in the Ge films reached the value in the range of 0.86%-1.5%. The GeSn buffer layer growth in the Sn content range from 8% to 12% was studied. The band structure of heterosystems based on pseudomorphic GeSiSn, SiSn and Ge layers was calculated and the valence and conduction band subband position dependences on the Sn content were built. Based on the calculation, the Sn content range in the GeSiSn, SiSn, and GeSn layers, which corresponds to the direct bandgap GeSiSn, SiSn, and Ge material, was obtained.

Reference Data for the Density, Viscosity, and Surface Tension of Liquid Al-Zn, Ag-Sn, Bi-Sn, Cu-Sn, and Sn-Zn Eutectic Alloys

Science.gov (United States)

Dobosz, Alexandra; Gancarz, Tomasz

2018-03-01

The data for the physicochemical properties viscosity, density, and surface tension obtained by different experimental techniques have been analyzed for liquid Al-Zn, Ag-Sn, Bi-Sn, Cu-Sn, and Sn-Zn eutectic alloys. All experimental data sets have been categorized and described by the year of publication, the technique used to obtain the data, the purity of the samples and their compositions, the quoted uncertainty, the number of data in the data set, the form of data, and the temperature range. The proposed standard deviations of liquid eutectic Al-Zn, Ag-Sn, Bi-Sn, Cu-Sn, and Sn-Zn alloys are 0.8%, 0.1%, 0.5%, 0.2%, and 0.1% for the density, 8.7%, 4.1%, 3.6%, 5.1%, and 4.0% for viscosity, and 1.0%, 0.5%, 0.3%, N/A, and 0.4% for surface tension, respectively, at a confidence level of 95%.

Hydrodynamic modeling and simulations of shock ignition thresholds

Directory of Open Access Journals (Sweden)

Lafon M.

2013-11-01

Full Text Available The Shock Ignition (SI scheme [1] offers to reduce the laser requirements by relaxing the implosion phase to sub-ignition velocities and later adding an intense laser spike. Depending on laser energy, target characteristics and implosion velocity, high gains are expected [2,3]. Relevant intensities for scaled targets imploded in the velocity range from 150 to 400 km/s are defined at ignition thresholds. A range of moderate implosion velocities is specified to match safe implosions. These conditions for target design are then inferred for relevant NIF and LMJ shock-ignited targets.

Deposition of the low resistive ITO-films by means of reactive magnetron sputtering of the In/Sn target on the cold substrate

Science.gov (United States)

Zhidik, Y. S.; Troyan, P. E.; Baturina, E. V.; Korzhenko, D. V.; Yurjev, Y. N.

2016-06-01

Detailed information on the deposition technology of the low-resistive ITO-films in oxygen-containing media by magnetron reactive sputtering from the In(90%)/Sn(10%) target on the cold substrate is given. Developed technology allows deposition ITO-films with sheet resistance 2-3 Ω/□, transparency higher than 90%. Developed technology is notable for high reproducibility of results and is compatible with production technology of semiconductor devices of optoelectronics.

PROBING SHOCK BREAKOUT AND PROGENITORS OF STRIPPED-ENVELOPE SUPERNOVAE THROUGH THEIR EARLY RADIO EMISSIONS

Energy Technology Data Exchange (ETDEWEB)

Maeda, Keiichi, E-mail: keiichi.maeda@ipmu.jp [Kavli Institute for the Physics and Mathematics of the Universe (Kavli-IPMU), Todai Institutes for Advanced Study (TODIAS), University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8583 (Japan)

2013-01-01

We study properties of early radio emission from stripped-envelope supernovae (SNe; those of Type IIb/Ib/Ic). We suggest there is a sub-class of stripped-envelope SNe based on their radio properties, including the optically well-studied Type Ic SNe (SNe Ic) 2002ap and 2007gr, showing a rapid rise to a radio peak within {approx}10 days and reaching a low luminosity (at least an order of magnitude fainter than a majority of SNe IIb/Ib/Ic). They show a decline after the peak that is shallower than that of other stripped-envelope SNe while their spectral index is similar. We show that all these properties are naturally explained if the circumstellar material (CSM) density is low and therefore the forward shock is expanding into the CSM without deceleration. Since the forward shock velocity in this situation, as estimated from the radio properties, still records the maximum velocity of the SN ejecta following the shock breakout, observing these SNe in radio wavelengths provides new diagnostics on the nature of both the breakout and the progenitor which otherwise require a quite rapid follow-up in other wavelengths. The inferred post-shock breakout velocities of SNe Ic 2002ap and 2007gr are sub-relativistic, {approx}0.3c. These are higher than that inferred for SN II 1987A, in line with suggested compact progenitors. However, these are lower than expected for a Wolf-Rayet (W-R) progenitor. It may reflect an as yet unresolved nature of the progenitors just before the explosion, and we suggest that the W-R progenitor envelopes might have been inflated which could quickly reduce the maximum ejecta velocity from the initial shock breakout velocity.

Shock timing measurements in DT ice layers

Science.gov (United States)

Robey, H. F.; Celliers, P. M.; Moody, J. D.; Sater, J.; Parham, T.; Kozioziemski, B.; Dylla-Spears, R. J.; Ross, J. S.; Lepape, S.; Ralph, J. E.; Berzak Hopkins, L. F.; Kroll, J. J.; Yoxall, B. E.; Hamza, A. V.; Boehly, T. R.; Nikroo, A.; Landen, O. L.; Edwards, M. J.

2013-10-01

Shock timing experiments on the National Ignition Facility (NIF) are routinely conducted using the keyhole target geometry, in which the strength and timing of multiple shocks are measured in a liquid-deuterium (D2) filled capsule interior. These targets have recently been modified to improve the surrogacy to ignition implosions by replacing the standard, continuous liquid D2 capsule fill with a deuterium-tritium (DT) ice layer with a central DT gas fill. These experiments remove any possible material surrogacy difference between D2 and DT as well as incorporating the physics of multiple shock release and recompression events from an ice layer of finite thickness, an effect that is absent in the liquid-filled targets. Experimental results and comparisons with numerical simulation are presented. Prepared by LLNL under Contract DE-AC52-07NA27344.

Porcine, murine and human sialoadhesin (Sn/Siglec-1/CD169): portals for porcine reproductive and respiratory syndrome virus entry into target cells.

Science.gov (United States)

Van Breedam, Wander; Verbeeck, Mieke; Christiaens, Isaura; Van Gorp, Hanne; Nauwynck, Hans J

2013-09-01

Porcine sialoadhesin (pSn; a sialic acid-binding lectin) and porcine CD163 (pCD163) are molecules that facilitate infectious entry of porcine reproductive and respiratory syndrome virus (PRRSV) into alveolar macrophages. In this study, it was shown that murine Sn (mSn) and human Sn (hSn), like pSn, can promote PRRSV infection of pCD163-expressing cells. Intact sialic acid-binding domains are crucial, since non-sialic acid-binding mutants of pSn, mSn and hSn did not promote infection. Endodomain-deletion mutants of pSn, mSn and hSn promoted PRRSV infection less efficiently, but also showed markedly reduced expression levels, making further research into the potential role of the Sn endodomain in PRRSV receptor activity necessary. These data further complement our knowledge on Sn as an important PRRSV receptor, and suggest - in combination with other published data - that species differences in the main PRRSV entry mediators Sn and CD163 do not account for the strict host species specificity displayed by the virus.

THIRTY YEARS OF SN 1980K: EVIDENCE FOR LIGHT ECHOES

Energy Technology Data Exchange (ETDEWEB)

Sugerman, Ben E. K. [Department of Physics and Astronomy, Goucher College, 1021 Dulaney Valley Road, Baltimore, MD 21208 (United States); Andrews, Jennifer E. [Department of Astronomy, University of Massachusetts, 710 North Pleasant Street, Amherst, MA 01003 (United States); Barlow, Michael J. [Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom); Clayton, Geoffrey C. [Department of Physics and Astronomy, Lousiana State University, 202 Nicholson Hall, Baton Roughe, LA 70803 (United States); Ercolano, Barbara [Excellence Cluster ' Universe' , Universitaets-Sternwarte Muenchen, Scheinerstr. 1, 81679 Muenchen (Germany); Ghavamian, Parviz [Department of Physics, Astronomy and Geosciences, Towson University, Smith Hall, Towson, MD 21252 (United States); Kennicutt, Robert C. Jr. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CM3 0HA (United Kingdom); Krause, Oliver [Max Planck Institute for Astronomy, Koenigstuhl 17, 69117 Heidelberg (Germany); Meixner, Margaret [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Otsuka, Masaaki, E-mail: ben.sugerman@goucher.edu [Institute of Astronomy and Astrophysics, Academia Sinica, Taipei 10617, Taiwan (China)

2012-04-20

We report optical and mid-infrared photometry of SN 1980K between 2004 and 2010, which shows slow monotonic fading consistent with previous spectroscopic and photometric observations made 8-17 yr after outburst. The slow rate of change over two decades suggests that this evolution may result from scattered and thermal light echoes off of extended circumstellar material. We present a semi-analytic dust radiative-transfer model that uses an empirically corrected effective optical depth to provide a fast and robust alternative to full Monte Carlo radiative-transfer modeling for homogenous dust at low to intermediate optical depths. We find that unresolved echoes from a thin circumstellar shell 14-15 lt-yr from the progenitor, and containing {approx}< 0.02 M{sub Sun} of carbon-rich dust, can explain the broadband spectral and temporal evolution. The size, mass, and dust composition are in good agreement with the contact discontinuity observed in scattered echoes around SN 1987A. The origin of slowly changing high-velocity [O I] and H{alpha} lines is also considered. We propose an origin in shocked high-velocity metal-rich clumps of ejecta, rather than arising in the impact of ejecta on slowly moving circumstellar material, as is the case with hot spots in SN 1987A.

Laser Spectroscopy Studies in the Neutron-Rich Sn Region

CERN Multimedia

Obert, J

2002-01-01

We propose to use the powerful laser spectroscopy method to determine the magnetic moment $\\mu$ and the variation of the mean square charge radius ($\\delta\\,\\langle$r$_{c}^{2}\\,\\rangle$) for ground and long-lived isomeric states of the Sn isotopes from A=125 to the doubly-magic $^{132}$Sn isotope and beyond. For these neutron-rich Sn nuclei, numerous $\\delta\\,\\langle$r$^{2}_{c}\\,\\rangle$ curves have already been calculated and the predictions depend upon the effective interactions used. Therefore, a study of the effect of the shell closure N=82 on the $\\delta\\,\\langle$r$^{2}_{c}\\,\\rangle$ values in the Z=50 magic nuclei is of great interest, especially because $^{132}$Sn is located far from the stability valley. It will help to improve the parameters of the effective interactions and make them more suitable to predict the properties of exotic nuclei. \\\\ \\\\The neutron-rich Sn isotopes produced with an uranium carbide target, are ionized using either a hot plasma ion source or the resonant ionization laser ion ...

Decay properties of nuclei in the neighbourhood of 100Sn

International Nuclear Information System (INIS)

Straub, Katrin

2011-01-01

This thesis concentrates on nuclear properties of very neutron deficient nuclei near the proton dripline in the neighbourhood of doubly-magic 100 Sn. In an experiment performed in March 2008 at the GSI in Darmstadt, the exotic nuclei were produced in a projectile fragmentation reaction using a 124 Xe primary beam with an energy of 100 AMeV impinging on a 4000 Beryllium target, separated and identified in the FRS and eventually stopped for decay spectroscopy in a complex implantation detector developed at the institute E12. The Germanium array RISING was employed for the measurement of prompt and delayed gamma radiation. Production cross sections and half lives were determined along the proton dripline. The isotopes 99 Sn, 97 In and 95 Cd were identified for the first time. additional nuclei studied in this thesis are 103 Sn, 96 Cd as well as the two tin isotopes 101 Sn and 102 Sn. (orig.)

High-rate deposition of Ta-doped SnO2 films by reactive magnetron sputtering using a Sn–Ta metal-sintered target

International Nuclear Information System (INIS)

Muto, Y.; Nakatomi, S.; Oka, N.; Iwabuchi, Y.; Kotsubo, H.; Shigesato, Y.

2012-01-01

Ta-doped SnO 2 films were deposited on glass substrate (either unheated or heated at 200 °C) by reactive magnetron sputtering with a Sn–Ta metal-sintered target using a plasma control unit (PCU) and mid-frequency (mf, 50 kHz) unipolar pulsing. The PCU feedback system precisely controlled the flow of the reactive and sputtering gases (O 2 and Ar, respectively) by monitoring either discharge impedance or the plasma emission of the atomic O* line at 777 nm. The planar target was connected to the switching unit, which was operated in unipolar pulse mode. Power density on the target was maintained at 4.4 W cm −2 during deposition. The lowest obtained resistivity for the films deposited on heated substrate was 6.4 × 10 −3 Ωcm, where the deposition rate was 250 nm min −1 .

Specific phosphorylation of histone demethylase KDM3A determines target gene expression in response to heat shock.

Directory of Open Access Journals (Sweden)

Mo-bin Cheng

2014-12-01

Full Text Available Histone lysine (K residues, which are modified by methyl- and acetyl-transferases, diversely regulate RNA synthesis. Unlike the ubiquitously activating effect of histone K acetylation, the effects of histone K methylation vary with the number of methyl groups added and with the position of these groups in the histone tails. Histone K demethylases (KDMs counteract the activity of methyl-transferases and remove methyl group(s from specific K residues in histones. KDM3A (also known as JHDM2A or JMJD1A is an H3K9me2/1 demethylase. KDM3A performs diverse functions via the regulation of its associated genes, which are involved in spermatogenesis, metabolism, and cell differentiation. However, the mechanism by which the activity of KDM3A is regulated is largely unknown. Here, we demonstrated that mitogen- and stress-activated protein kinase 1 (MSK1 specifically phosphorylates KDM3A at Ser264 (p-KDM3A, which is enriched in the regulatory regions of gene loci in the human genome. p-KDM3A directly interacts with and is recruited by the transcription factor Stat1 to activate p-KDM3A target genes under heat shock conditions. The demethylation of H3K9me2 at the Stat1 binding site specifically depends on the co-expression of p-KDM3A in the heat-shocked cells. In contrast to heat shock, IFN-γ treatment does not phosphorylate KDM3A via MSK1, thereby abrogating its downstream effects. To our knowledge, this is the first evidence that a KDM can be modified via phosphorylation to determine its specific binding to target genes in response to thermal stress.

Shock timing on the National Ignition Facility: First Experiments

International Nuclear Information System (INIS)

Celliers, P.M.; Robey, H.F.; Boehly, T.R.; Alger, E.; Azevedo, S.; Berzins, L.V.; Bhandarkar, S.D.; Bowers, M.W.; Brereton, S.J.; Callahan, D.; Castro, C.; Chandrasekaran, H.; Choate, C.; Clark, D.; Coffee, K.R.; Datte, P.S.; Dewald, E.L.; DiNicola, P.; Dixit, S.; Doeppner, T.; Dzenitis, E.; Edwards, M.J.; Eggert, J.H.; Fair, J.; Farley, D.R.; Frieders, G.; Gibson, C.R.; Giraldez, E.; Haan, S.; Haid, B.; Hamza, A.V.; Haynam, C.; Hicks, D.G.; Holunga, D.M.; Horner, J.B.; Jancaitis, K.; Jones, O.S.; Kalantar, D.; Kline, J.L.; Krauter, K.G.; Kroll, J.J.; LaFortune, K.N.; Pape, S.L.; Malsbury, T.; Maypoles, E.R.; Milovich, J.L.; Moody, J.D.; Moreno, K.; Munro, D.H.; Nikroo, A.; Olson, R.E.; Parham, T.; Pollaine, S.; Radousky, H.B.; Ross, G.F.; Sater, J.; Schneider, M.B.; Shaw, M.; Smith, R.F.; Thomas, C.A.; Throop, A.; Town, R.J.; Trummer, D.; Van Wonterghem, B.M.; Walters, C.F.; Widmann, K.; Widmayer, C.; Young, B.K.; Atherton, L.J.; Collins, G.W.; Landen, O.L.; Lindl, J.D.; MacGowan, B.J.; Meyerhofer, D.D.; Moses, E.I.

2011-01-01

An experimental campaign to tune the initial shock compression sequence of capsule implosions on the National Ignition Facility (NIF) was initiated in late 2010. The experiments use a NIF ignition-scale hohlraum and capsule that employs a reentrant cone to provide optical access to the shocks as they propagate in the liquid deuterium-filled capsule interior. The strength and timing of the shock sequence is diagnosed with velocity interferometry that provides target performance data used to set the pulse shape for ignition capsule implosions that follow. From the start, these measurements yielded significant new information on target performance, leading to improvements in the target design. We describe the results and interpretation of the initial tuning experiments.

Isomer shifts and chemical bonding in crystalline Sn(II) and Sn(IV) compounds

International Nuclear Information System (INIS)

Terra, J.; Guenzburger, D.

1991-01-01

First-principles self-consistent Local Density calculations of the electronic structure of clusters representing Sn(II) (SnO, SnF 2 , SnS, SnSe) and Sn(IV) (SnO 2 , SnF 4 ) crystalline compounds were performed. Values of the electron density at the Sn nucleus were obtained and related to measured values of the Moessbauer Isomer Shifts reported in the literature. The nuclear parameter of 119 Sn derived was ΔR/R=(1.58±0.14)x10 -4 . The chemical bonding in the solids was analysed and related to the electron densities obtained. (author)

Production of dissociated hydrogen gas by electro-magnetically driven shock

International Nuclear Information System (INIS)

Kondo, Kotaro; Moriyama, Takao; Hasegawa, Jun; Horioka, Kazuhiko; Oguri, Yoshiyuki

2013-01-01

Evaluation of ion stopping power which has a dependence on target temperature and density is an essential issue for heavy-ion-driven high energy density experiment. We focus on experimentally unknown dissociated hydrogen atoms as target for stopping power measurement. The precise measurement of shock wave velocity is required because the dissociated gas is produced by electro-magnetically driven shock. For beam-dissociated hydrogen gas interaction experiment, shock velocity measurement using laser refraction is proposed. (author)

Deposition and characterization of single magnetron deposited Fe:SnO{sub x} coatings

Energy Technology Data Exchange (ETDEWEB)

Kormunda, Martin, E-mail: martin.kormunda@ujep.cz [J.E. Purkinje University, Faculty of Science, Department of Physics, Ceske mladeze 8, 400 96 Usti nad Labem (Czech Republic); Fischer, Daniel; Hertwig, Andreas; Beck, Uwe [BAM Federal Institute for Materials Research and Testing, Division 6 4 Surface Technologies, Unter den Eichen 44-46, 12203 Berlin (Germany); Sebik, Matej; Pavlik, Jaroslav [J.E. Purkinje University, Faculty of Science, Department of Physics, Ceske mladeze 8, 400 96 Usti nad Labem (Czech Republic); Esser, Norbert [Leibniz-Institut für Analytische Wissenschaften — ISAS e.V., Department Berlin, Schwarzschildstr. 12, 12489 Berlin (Germany)

2015-11-30

Coatings deposited by magnetron co-sputtering from a single RF magnetron with a ceramic SnO{sub 2} target with iron inset in argon plasma were studied. The mass spectra of the process identified Sn{sup +} and SnO{sup +} species as the dominant species sputtered from the target, but no SnO{sub 2}{sup +} species were detected. The dominant positive ions in argon plasma are Ar{sup +} species. The only detected negative ions were O{sup −}. Sputtered neutral tin related species were not detected. Iron related species were also not detected because their concentration is below the detection limit. The concentration of iron dopant in the tin oxide coatings was controlled by the RF bias applied on the substrate holder while the discharge pressure also has some influence. The iron concentration was in the range from 0.9 at.% up to 19 at.% increasing with the substrate bias while the sheet resistivity decreases. The stoichiometry ratio of O/(Sn + Fe) in the coatings increased from 1.7 up to 2 in dependence on the substrate bias from floating bias (− 5 V) up to − 120 V of RF self-bias, respectively. The tin in the coatings was mainly bonded in Sn{sup 4+} state and iron was mainly in Fe{sup 2+} state when other tin bonding states were detected only in a small amounts. Iron bonding states in contrary to elemental compositions of the coatings were not influenced by the RF bias applied on the substrate. The coatings showed high transparency in the visible spectral range. However, an increased metallic behavior could be detected by using a higher RF bias for the deposition. The X-ray diffraction patterns and electron microscopy pictures made on the coatings confirmed the presence of an amorphous phase. - Highlights: • RF magnetron sputtering of SnO{sub 2} target with Fe inset in argon investigated by mass spectrometry • Optical properties of Fe doped SnO{sub x} coatings characterized • Analyses of overlapped XPS peaks at a spectrum from Fe doped SnO{sub x} coatings �

Suppression of suprathermal ions from a colloidal microjet target containing SnO2 nanoparticles by using double laser pulses

International Nuclear Information System (INIS)

Higashiguchi, Takeshi; Kaku, Masanori; Katto, Masahito; Kubodera, Shoichi

2007-01-01

We have demonstrated suppression of suprathermal ions from a colloidal microjet target plasma containing tin-dioxide (SnO 2 ) nanoparticles irradiated by double laser pulses. We observed a significant decrease of the tin and oxygen ion signals in the charged-state-separated energy spectra when double laser pulses were irradiated. The peak energy of the singly ionized tin ions decreased from 9 to 3 keV when a preplasma was produced. The decrease in the ion energy, considered as debris suppression, is attributed to the interaction between an expanding low-density preplasma and a main laser pulse

Suppression of suprathermal ions from a colloidal microjet target containing SnO2 nanoparticles by using double laser pulses

Science.gov (United States)

Higashiguchi, Takeshi; Kaku, Masanori; Katto, Masahito; Kubodera, Shoichi

2007-10-01

We have demonstrated suppression of suprathermal ions from a colloidal microjet target plasma containing tin-dioxide (SnO2) nanoparticles irradiated by double laser pulses. We observed a significant decrease of the tin and oxygen ion signals in the charged-state-separated energy spectra when double laser pulses were irradiated. The peak energy of the singly ionized tin ions decreased from 9to3keV when a preplasma was produced. The decrease in the ion energy, considered as debris suppression, is attributed to the interaction between an expanding low-density preplasma and a main laser pulse.

Tomography of massive stars from core collapse to supernova shock breakout

Energy Technology Data Exchange (ETDEWEB)

Kistler, Matthew D.; Haxton, W. C. [Lawrence Berkeley National Laboratory and Department of Physics, University of California, Berkeley, CA 94720 (United States); Yüksel, Hasan [Theoretical Division, MS B285, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2013-11-20

Neutrinos and gravitational waves are the only direct probes of the inner dynamics of a stellar core collapse. They are also the first signals to arrive from a supernova (SN) and, if detected, establish the moment when the shock wave is formed that unbinds the stellar envelope and later initiates the optical display upon reaching the stellar surface with a burst of UV and X-ray photons, the shock breakout (SBO). We discuss how neutrino observations can be used to trigger searches to detect the elusive SBO event. Observation of the SBO would provide several important constraints on progenitor structure and the explosion, including the shock propagation time (the duration between the neutrino burst and SBO), an observable that is important in distinguishing progenitor types. Our estimates suggest that next-generation neutrino detectors could exploit the overdensity of nearby SNe to provide several such triggers per decade, more than an order-of-magnitude improvement over the present.

Tomography of massive stars from core collapse to supernova shock breakout

International Nuclear Information System (INIS)

Kistler, Matthew D.; Haxton, W. C.; Yüksel, Hasan

2013-01-01

Neutrinos and gravitational waves are the only direct probes of the inner dynamics of a stellar core collapse. They are also the first signals to arrive from a supernova (SN) and, if detected, establish the moment when the shock wave is formed that unbinds the stellar envelope and later initiates the optical display upon reaching the stellar surface with a burst of UV and X-ray photons, the shock breakout (SBO). We discuss how neutrino observations can be used to trigger searches to detect the elusive SBO event. Observation of the SBO would provide several important constraints on progenitor structure and the explosion, including the shock propagation time (the duration between the neutrino burst and SBO), an observable that is important in distinguishing progenitor types. Our estimates suggest that next-generation neutrino detectors could exploit the overdensity of nearby SNe to provide several such triggers per decade, more than an order-of-magnitude improvement over the present.

Attenuation of shock waves in copper and stainless steel

International Nuclear Information System (INIS)

Harvey, W.B.

1986-06-01

By using shock pins, data were gathered on the trajectories of shock waves in stainless steel (SS-304L) and oxygen-free-high-conductivity copper (OFHC-Cu). Shock pressures were generated in these materials by impacting the appropriate target with thin (approx.1.5 mm) flying plates. The flying plates in these experiments were accelerated to high velocities (approx.4 km/s) by high explosives. Six experiments were conducted, three using SS-304L as the target material and three experiments using OFHC-Cu as the target material. Peak shock pressures generated in the steel experiments were approximately 109, 130, and 147 GPa and in the copper experiments, the peak shock pressures were approximately 111, 132, and 143 GPa. In each experiment, an attenuation of the shock wave by a following release wave was clearly observed. An extensive effort using two characteristic codes (described in this work) to theoretically calculate the attenuation of the shock waves was made. The efficacy of several different constitutive equations to successfully model the experiments was studied by comparing the calculated shock trajectories to the experimental data. Based on such comparisons, the conclusion can be drawn that OFHC-Cu enters a melt phase at about 130 GPa on the principal Hugoniot. There was no sign of phase changes in the stainless-steel experiments. In order to match the observed attenuation of the shock waves in the SS-304L experiments, it was necessary to include strength effects in the calculations. It was found that the values for the parameters in the strength equations were dependent on the equation of state used in the modeling of the experiments. 66 refs., 194 figs., 77 tabs

Attenuation of shock waves in copper and stainless steel

Energy Technology Data Exchange (ETDEWEB)

Harvey, W.B.

1986-06-01

By using shock pins, data were gathered on the trajectories of shock waves in stainless steel (SS-304L) and oxygen-free-high-conductivity copper (OFHC-Cu). Shock pressures were generated in these materials by impacting the appropriate target with thin (approx.1.5 mm) flying plates. The flying plates in these experiments were accelerated to high velocities (approx.4 km/s) by high explosives. Six experiments were conducted, three using SS-304L as the target material and three experiments using OFHC-Cu as the target material. Peak shock pressures generated in the steel experiments were approximately 109, 130, and 147 GPa and in the copper experiments, the peak shock pressures were approximately 111, 132, and 143 GPa. In each experiment, an attenuation of the shock wave by a following release wave was clearly observed. An extensive effort using two characteristic codes (described in this work) to theoretically calculate the attenuation of the shock waves was made. The efficacy of several different constitutive equations to successfully model the experiments was studied by comparing the calculated shock trajectories to the experimental data. Based on such comparisons, the conclusion can be drawn that OFHC-Cu enters a melt phase at about 130 GPa on the principal Hugoniot. There was no sign of phase changes in the stainless-steel experiments. In order to match the observed attenuation of the shock waves in the SS-304L experiments, it was necessary to include strength effects in the calculations. It was found that the values for the parameters in the strength equations were dependent on the equation of state used in the modeling of the experiments. 66 refs., 194 figs., 77 tabs.

Properties of SN1978K from multi-wavelength observations

Science.gov (United States)

Schlegel, Eric M.; Ryder, Stuart; Staveley-Smith, L.; Colbert, E.; Petre, R.; Dopita, M.; Campbell-Wilson, D.

2000-06-01

We update the light curves from the X-ray, optical, and radio bandpasses which we have assembled over the past decade, and present two observations in the ultraviolet using the Hubble Space Telescope Faint Object Spectrograph. The HRI X-ray light curve is constant within the errors over the entire observation period which is confirmed by ASCA GIS data obtained in 1993 and 1995. In the UV, we detected the Mg II doublet at 2800 Å and a line at ~3190 Å attributed to He I 3187 at SN1978K's position. The optical light curve is formally constant within the errors, although a slight upward trend may be present. The radio light curve continues its steep decline. The longer time span of our radio observations compared to previous studies shows that SN1978K belongs in the class of highly X-ray and radio-luminous supernovae. The Mg II doublet flux ratio implies the quantity of line optical depth times density is ~1014 cm-3. The emission site must lie in the shocked gas. .

A polar-drive shock-ignition design for the National Ignition Facility

Energy Technology Data Exchange (ETDEWEB)

Anderson, K. S.; McKenty, P. W.; Collins, T. J. B.; Craxton, R. S.; Delettrez, J. A.; Marozas, J. A.; Skupsky, S.; Shvydky, A. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623 (United States); Betti, R. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623 (United States); Fusion Science Center, University of Rochester, Rochester, New York 14623 (United States); Departments of Mechanical Engineering and Physics, University of Rochester, Rochester, New York 14627 (United States); Hohenberger, M.; Theobald, W.; Lafon, M.; Nora, R. [Laboratory for Laser Energetics, University of Rochester, 250 East River Road, Rochester, New York 14623 (United States); Fusion Science Center, University of Rochester, Rochester, New York 14623 (United States)

2013-05-15

Shock ignition [R. Betti et al., Phys. Rev. Lett. 98, 155001 (2007)] is being pursued as a viable option to achieve ignition on the National Ignition Facility (NIF). Shock-ignition target designs use a high-intensity laser spike at the end of a low-adiabat assembly pulse to launch a spherically convergent strong shock to ignite the hot spot of an imploding capsule. A shock-ignition target design for the NIF is presented. One-dimensional simulations indicate an ignition threshold factor of 4.1 with a gain of 58. A polar-drive beam-pointing configuration for shock-ignition experiments on the NIF at 750 kJ is proposed. The capsule design is shown to be robust to the various one- and two-dimensional effects and nonuniformities anticipated on the NIF. The target is predicted to ignite with a gain of 38 when including all anticipated levels of nonuniformity and system uncertainty.

Gamma spectroscopy of multiple nucleon transfer reactions in Sn

International Nuclear Information System (INIS)

Grabowski, Z.W.; Mayer, R.H.; Fornal, B.; Nisius, D.T.; Bearden, I.G.; Daly, P.J.; Broda, R.; Carpenter, M.P.; Janssens, R.V.F.; Khoo, T.L.; Lauritsen, T.

1992-01-01

The decay of (πh 11/2 ) n yrast isomers was studied in a series of proton-rich N = 82 isotones culminating in determination of B(E2) values in 153 Lu and 154 Hf. In the N = 82 isotones however, it seems unlikely that the measurements could be extended beyond 154 Hf (n = 8). The opportunity to investigate the (h 11/2 ) n ) isomers across the whole h 11/2 subshell exists, at least in principle, in Sn isotopes where the counterpart νh 11/2 subshell is being filled with neutrons starting at 116 Sn. Before our measurements were initiated, the (νh 11/2 ) n 10 + isomers were known to exist in 116, 118, 120 Sn, where the νh 11/2 subshell begins to fill, and in 128,130 Sn at the other end. Important information, however, was missing about the 10 + isomers in 122,124,126 Sn where the long lifetimes are expected. The υ = 3 (h 11/2 ) isomers in odd tin isomers for A ≥ 119 were also not identified. A serious experimental difficulty in populating high spin states in heavier Sn isotopes is that they are not accessible by fusion-evaporation reactions. We decided to search for these missing tin isotopes among the products of heavy ion reactions on 122,124 Sn targets. Using this approach we were able to identify the isomeric decays and measure the lifetimes of the (νh 11/2 n ) υ = 2 isomeric states in 122,124 Sn. In odd tin isotopes we identified new I = 19/2 + yrast isomers in 119,121,123 Sn and measured their lifetimes. In addition (νh 11/2 ) n υ = 3, I = 27/2 - isomers in 119,121 Sn were observed for the first time

Effects of non-local electron transport in one-dimensional and two-dimensional simulations of shock-ignited inertial confinement fusion targets

Energy Technology Data Exchange (ETDEWEB)

Marocchino, A.; Atzeni, S.; Schiavi, A. [Dipartimento SBAI, Università di Roma “La Sapienza” and CNISM, Roma 00161 (Italy)

2014-01-15

In some regions of a laser driven inertial fusion target, the electron mean-free path can become comparable to or even longer than the electron temperature gradient scale-length. This can be particularly important in shock-ignited (SI) targets, where the laser-spike heated corona reaches temperatures of several keV. In this case, thermal conduction cannot be described by a simple local conductivity model and a Fick's law. Fluid codes usually employ flux-limited conduction models, which preserve causality, but lose important features of the thermal flow. A more accurate thermal flow modeling requires convolution-like non-local operators. In order to improve the simulation of SI targets, the non-local electron transport operator proposed by Schurtz-Nicolaï-Busquet [G. P. Schurtz et al., Phys. Plasmas 7, 4238 (2000)] has been implemented in the DUED fluid code. Both one-dimensional (1D) and two-dimensional (2D) simulations of SI targets have been performed. 1D simulations of the ablation phase highlight that while the shock profile and timing might be mocked up with a flux-limiter; the electron temperature profiles exhibit a relatively different behavior with no major effects on the final gain. The spike, instead, can only roughly be reproduced with a fixed flux-limiter value. 1D target gain is however unaffected, provided some minor tuning of laser pulses. 2D simulations show that the use of a non-local thermal conduction model does not affect the robustness to mispositioning of targets driven by quasi-uniform laser irradiation. 2D simulations performed with only two final polar intense spikes yield encouraging results and support further studies.

Effects of non-local electron transport in one-dimensional and two-dimensional simulations of shock-ignited inertial confinement fusion targets

International Nuclear Information System (INIS)

Marocchino, A.; Atzeni, S.; Schiavi, A.

2014-01-01

In some regions of a laser driven inertial fusion target, the electron mean-free path can become comparable to or even longer than the electron temperature gradient scale-length. This can be particularly important in shock-ignited (SI) targets, where the laser-spike heated corona reaches temperatures of several keV. In this case, thermal conduction cannot be described by a simple local conductivity model and a Fick's law. Fluid codes usually employ flux-limited conduction models, which preserve causality, but lose important features of the thermal flow. A more accurate thermal flow modeling requires convolution-like non-local operators. In order to improve the simulation of SI targets, the non-local electron transport operator proposed by Schurtz-Nicolaï-Busquet [G. P. Schurtz et al., Phys. Plasmas 7, 4238 (2000)] has been implemented in the DUED fluid code. Both one-dimensional (1D) and two-dimensional (2D) simulations of SI targets have been performed. 1D simulations of the ablation phase highlight that while the shock profile and timing might be mocked up with a flux-limiter; the electron temperature profiles exhibit a relatively different behavior with no major effects on the final gain. The spike, instead, can only roughly be reproduced with a fixed flux-limiter value. 1D target gain is however unaffected, provided some minor tuning of laser pulses. 2D simulations show that the use of a non-local thermal conduction model does not affect the robustness to mispositioning of targets driven by quasi-uniform laser irradiation. 2D simulations performed with only two final polar intense spikes yield encouraging results and support further studies

Effects of non-local electron transport in one-dimensional and two-dimensional simulations of shock-ignited inertial confinement fusion targets

Science.gov (United States)

Marocchino, A.; Atzeni, S.; Schiavi, A.

2014-01-01

In some regions of a laser driven inertial fusion target, the electron mean-free path can become comparable to or even longer than the electron temperature gradient scale-length. This can be particularly important in shock-ignited (SI) targets, where the laser-spike heated corona reaches temperatures of several keV. In this case, thermal conduction cannot be described by a simple local conductivity model and a Fick's law. Fluid codes usually employ flux-limited conduction models, which preserve causality, but lose important features of the thermal flow. A more accurate thermal flow modeling requires convolution-like non-local operators. In order to improve the simulation of SI targets, the non-local electron transport operator proposed by Schurtz-Nicolaï-Busquet [G. P. Schurtz et al., Phys. Plasmas 7, 4238 (2000)] has been implemented in the DUED fluid code. Both one-dimensional (1D) and two-dimensional (2D) simulations of SI targets have been performed. 1D simulations of the ablation phase highlight that while the shock profile and timing might be mocked up with a flux-limiter; the electron temperature profiles exhibit a relatively different behavior with no major effects on the final gain. The spike, instead, can only roughly be reproduced with a fixed flux-limiter value. 1D target gain is however unaffected, provided some minor tuning of laser pulses. 2D simulations show that the use of a non-local thermal conduction model does not affect the robustness to mispositioning of targets driven by quasi-uniform laser irradiation. 2D simulations performed with only two final polar intense spikes yield encouraging results and support further studies.

States in 118Sn from 117Sn(d,p) 118Sn at 12 MeV

International Nuclear Information System (INIS)

Frota-Pessoa, E.

1983-01-01

118 Sn energy levels up to = 5.2 MeV excitation energy are studied in the reaction 117 Sn (d,p) 118 Sn. Deuterons had a bombarding energy of 12 MeV. The protons were analized by a magnetic spectrograph. The detector was nuclear emulsion and the resolution in energy about 10 KeV. The distorted-wave analysis was used to determine l values and spectroscopic strengths. Centers of gravity and the sums of reduced spectroscopic factors are presented for the levels when it was possible to determine the S' value. 66 levels of excitation energy were found which did not appear in previous 117 Sn (d,p) reactions. 40 levels were not found previously in any reaction giving 118 Sn. The results are compared with the known ones. (Author) [pt

Shock propagation in a heterogeneous medium

International Nuclear Information System (INIS)

Elbaz, D.

2011-01-01

In the frame of the inertial confinement fusion in direct drive, the use of foams as ablator allows the reduction of hydrodynamic instabilities created on the target by the direct laser irradiation. The foam is made up of carbon (CH) fibers impregnated of cryogenic deuterium-tritium (DT). In the past, studies have been carried out considering this foam to be a homogeneous medium. Yet, the foam presents heterogeneous features. We study the effects of this heterogeneity on the shock velocity when the laser irradiates the target. Thanks to experimental and numerical studies, we show that the shock propagates faster in the heterogeneous medium than in the homogeneous one with the same averaged density. This velocity gap depends on the presence rate of the CH fibers in the foam, the density ratio, the adiabatic coefficient and the foam geometry. We model the foam by different ways, more and more complex. The shock velocity modification is due to the baroclinicity which, during the interaction between the shock front and the interface, creates a vorticity deposition, responsible for the shock acceleration. Accordingly, an interface, which is plane and perpendicular to the front shock, maximizes the vorticity deposition and increases the velocity gaps between heterogeneous and homogeneous media. We found a correlation between the kinetic energy behind the shock front and the velocities relative difference. We compared our results with two analytical models. However, the system is not closed, so we can't for the moment develop a predictive model. (author) [fr

The X-Ray Light Curve of the Very Luminous Supernova SN 1978K in NGC 1313

Science.gov (United States)

Schlegel, Eric M.; Petre, R.; Colbert, E. J. M.

1996-01-01

We present the 0.5-2.0 keV light curve of the X-ray luminous supernova SN 1978K in NGC 1313, based on six ROSAT observations spanning 1990 July to t994 July. SN 1978K is one of a few supernovae or supernova remnants that are very luminous (˜1039-1040 ergs s-1) in the X-ray, optical, and radio bands, and the first, at a supernova age of 10-20 yr, for which sufficient data exist to create an X-ray light curve. The X-ray flux is approximately constant over the 4 yr sampled by our observations, which were obtained 12-16 yr after the initial explosion. Three models exist to explain the large X-ray luminosity: pulsar input, a reverse shock running back into the expanding debris of the supernova, and the outgoing shock crushing of cloudlets in the debris field. Based upon calculations of Chevalier & Fransson, a pulsar cannot provide sufficient energy to produce the soft X-ray luminosity. Based upon the models and the light curve to date, it is not possible to discern the evolutionary phase of the supernova.

Energy shocks and detecting influential industries

International Nuclear Information System (INIS)

Kang, Dongsuk; Lee, Duk Hee

2017-01-01

An industry's relationship of supply and demand with the energy sector can be a critical factor in the stability of its economic performance. Furthermore, the patterns of industry dependence on energy industries can be a major characteristic of entire industrial structure. This research evaluates industries' impact scores for their overall influence on other industries and vulnerability to supply and demand shocks from the energy sector. The study utilizes a sample of Korea's industrial input–output tables from 2010 to 2012. Using a chain of complementary methodologies, this study finds that among four clusters, energy, services, and raw materials are key members that can spread energy shocks to other industries. Therefore, governments need to prepare effective energy efficiency policies for these target industries. - Highlights: • We analyze an industry's impact score of its vulnerability to energy shock and inter-industrial effects. • We utilize the sample of input-output tables in Korea from 2010 to 2012. • We implement simulation, PCA, TOPSIS, cluster analysis about energy shock and industrial trades. • Subsectors of energy, services, raw material are subject to energy shock and influential to others. • These bridge industries can be targets that require policies for effective energy efficiency.

Effects of interlayer Sn-Sn lone pair interaction on the band gap of bulk and nanosheet SnO

Science.gov (United States)

Umezawa, Naoto; Zhou, Wei

2015-03-01

Effects of interlayer lone-pair interactions on the electronic structure of SnO are firstly explored by the density-functional theory. Our comprehensive study reveals that the band gap of SnO opens as increase in the interlayer Sn-Sn distance. The effect is rationalized by the character of band edges which consists of bonding and anti-bonding states from interlayer lone pair interactions. The band edges for several nanosheets and strained double-layer SnO are estimated. We conclude that the double-layer SnO is a promising material for visible-light driven photocatalyst for hydrogen evolution. This work is supported by the Japan Science and Technology Agency (JST) Precursory Research for Embryonic Science and Technology (PRESTO) program.

Shock timing on the National Ignition Facility: First experiments

Directory of Open Access Journals (Sweden)

Celliers P.M.

2013-11-01

Full Text Available An experimental campaign to tune the initial shock compression sequence of capsule implosions on the National Ignition Facility (NIF was initiated in late 2010. The experiments use a NIF ignition-scale hohlraum and capsule that employs a re-entrant cone to provide optical access to the shocks as they propagate in the liquid deuterium-filled capsule interior. The strength and timing of the shock sequence is diagnosed with velocity interferometry that provides target performance data used to set the pulse shape for ignition capsule implosions that follow. From the start, these measurements yielded significant new information on target performance, leading to improvements in the target design. We describe the results and interpretation of the initial tuning experiments.

Controlling Cu–Sn mixing so as to enable higher critical current densities in RRP® Nb3Sn wires

Science.gov (United States)

Sanabria, Charlie; Field, Michael; Lee, Peter J.; Miao, Hanping; Parrell, Jeff; Larbalestier, David C.

2018-06-01

only one stage at 350 °C for 400 h which minimizes Nausite formation while encouraging the formation of the higher melting point ε phase through better Cu–Sn mixing. At a D s of 41 μm, the Nausite control heat treatment increases the J c at 16 T by 36%, reaching 1300 A mm‑2 (i.e. 2980 A mm‑2 at 12 T), and moving RRP® closer to the FCC targets.

Oxidation of Pb-Sn and Pb-Sn-In alloys

International Nuclear Information System (INIS)

Sluzewski, D.A.; Chang, Y.A.; Marcotte, V.C.

1990-01-01

Air oxidized Pb-Sn and Pb-Sn-In single phase alloys have been studied with scanning Auger microscopy. Line scans across grain boundaries combined with argon ion sputter etching revealed grain boundary oxidation. In the Pb-Sn samples, tin is preferentially oxidized with the grain boundary regions having a much higher percentage of tin oxide than the bulk surface oxide. In the Pb-Sn-In alloys, both tin and indium are preferentially oxidized with the grain boundary regions being enriched with tin and indium oxides

Temporally resolved characterization of shock-heated foam target with Al absorption spectroscopy for fast electron transport study

Energy Technology Data Exchange (ETDEWEB)

Yabuuchi, T.; Sawada, H.; Wei, M. S.; Beg, F. N. [Center for Energy Research, University of California, San Diego, La Jolla, California 92093 (United States); Regan, S. P.; Anderson, K.; Betti, R. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States); Hund, J.; Paguio, R. R.; Saito, K. M.; Stephens, R. B. [General Atomics, San Diego, California 92186 (United States); Key, M. H.; Mackinnon, A. J.; McLean, H. S.; Patel, P. K.; Wilks, S. C. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

2012-09-15

The CH foam plasma produced by a laser-driven shock wave has been characterized by a temporally resolved Al 1s-2p absorption spectroscopy technique. A 200 mg/cm{sup 3} foam target with Al dopant was developed for this experiment, which used an OMEGA EP [D. D. Meyerhofer et al., J. Phys.: Conf. Ser. 244, 032010 (2010)] long pulse beam with an energy of 1.2 kJ and 3.5 ns pulselength. The plasma temperatures were inferred with the accuracy of 5 eV from the fits to the measurements using an atomic physics code. The results show that the inferred temperature is sustained at 40-45 eV between 6 and 7 ns and decreases to 25 eV at 8 ns. 2-D radiation hydrodynamic simulations show a good agreement with the measurements. Application of the shock-heated foam plasma platform toward fast electron transport experiments is discussed.

Thin films of thermoelectric compound Mg2Sn deposited by co-sputtering assisted by multi-dipolar microwave plasma

International Nuclear Information System (INIS)

Le-Quoc, H.; Lacoste, A.; Hlil, E.K.; Bes, A.; Vinh, T. Tan; Fruchart, D.; Skryabina, N.

2011-01-01

Highlights: → Mg 2 Sn thin films deposited by plasma co-sputtering, on silicon and glass substrates. → Formation of nano-grained polycrystalline films on substrates at room temperature. → Structural properties vary with target biasing and target-substrate distance. → Formation of the hexagonal phase of Mg 2 Sn in certain deposition conditions. → Power factor ∼5.0 x 10 -3 W K -2 m -1 for stoichiometric Mg 2 Sn films doped with ∼1 at.% Ag. - Abstract: Magnesium stannide (Mg 2 Sn) thin films doped with Ag intended for thermoelectric applications are deposited on both silicon and glass substrates at room temperature by plasma assisted co-sputtering. Characterization by scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray diffraction confirms the formation of fine-grained polycrystalline thin films with thickness of 1-3 μm. Stoichiometry, microstructure and crystal structure of thin films are found to vary with target biasing and the distance from targets to substrate. Measurements of electrical resistivity and Seebeck coefficient at room temperature show the maximum power factor of ∼5.0 x 10 -3 W K -2 m -1 for stoichiometric Mg 2 Sn thin films doped with ∼1 at.% Ag.

Analyses of the Sn IX-Sn XII spectra in the EUV region

International Nuclear Information System (INIS)

Churilov, S S; Ryabtsev, A N

2006-01-01

The Sn IX-Sn XII spectra excited in a vacuum spark have been analysed in the 130-160 A wavelength region. The analysis was based on the energy parameter extrapolation in the isonuclear Sn VI-VIII and Sn XIII-XIV sequence. 266 spectral lines belonging to the 4d m -(4d m-1 4f+4p 5 4d m+1 ) (m=6-3) transition arrays were classified in the Sn IX-Sn XII spectra for the first time. All 18 level energies of the 4d 3 configuration and 39 level energies of the strongly interacting 4d 2 4f and 4p 5 4d 4 configurations were established in the Sn XII spectrum. The energy differences between the majority of the 4d m levels and about 40 levels of the 4d m-1 4f+4p 5 4d m+1 configurations were determined in each of the Sn IX, Sn X and Sn XI spectra (m=6-4). As a result, all intense lines were classified in the 130-140 A region relevant to the extreme ultraviolet (EUV) lithography. It was shown that the most of the intense lines in the 2% bandwidth at 135 A belong to the transitions in the Sn XI-Sn XIII spectra

Temperature measurement of tin under shock compression

International Nuclear Information System (INIS)

Hereil, Pierre-Louis; Mabire, Catherine

2002-01-01

The results of pyrometric measurements performed at the interface of a tin target with a LiF window material are presented for stresses ranging from 38 to 55 GPa. The purpose of the study is to analyze the part of the interface in the temperature measurement by a multi-channel pyrometric device. The results show that the glue used at target/window interface remains transparent under shock. The values of temperature measured at the tin/LiF interface are consistent with the behavior of tin under shock

Rod-like hierarchical Sn/SnOx@C nanostructures with enhanced lithium storage properties

Science.gov (United States)

Yang, Juan; Chen, Sanmei; Tang, Jingjing; Tian, Hangyu; Bai, Tao; Zhou, Xiangyang

2018-03-01

Rod-like hierarchical Sn/SnOx@C nanostructures have been designed and synthesized via calcining resorcinol-formaldehyde (RF) resin coated Sn-based metal-organic frameworks. The rod-like hierarchical Sn/SnOx@C nanostructures are made of a great number of carbon-wrapped primary Sn/SnOx nanospheres of 100-200 nm in diameter. The as-prepared hierarchical Sn/SnOx@C nanocomposite manifests a high initial reversible capacity of 1177 mAh g-1 and remains 1001 mAh g-1 after 240 cycles at a current density of 200 mA g-1. It delivers outstanding high-rate performance with a reversible capacity of 823 mAh g-1 even at a high current density of 1000 mA g-1. The enhanced electrochemical performances of the Sn/SnOx@C electrode are mainly attributed to the synergistic effect of the unique hierarchical micro/nanostructures and the protective carbon layer.

Discrimination of Thermal versus Mechanical Effects of Shock on Rock Magnetic Properties of Spherically Shocked up to 10-160 GPa Basalt and Diabase

Science.gov (United States)

Bezaeva, N. S.; Swanson-Hysell, N.; Tikoo, S.; Badyukov, D. D.; Kars, M. A. C.; Egli, R.; Chareev, D. A.; Fairchild, L. M.

2016-12-01

Understanding how shock waves generated during hypervelocity impacts affect rock magnetic properties is key for interpreting the paleomagnetic records of lunar rocks, meteorites, and cratered planetary surfaces. Laboratory simulations of impacts show that ultra-high shocks may induce substantial post-shock heating of the target material. At high pressures (>10 GPa), shock heating occurs in tandem with mechanical effects, such as grain fracturing and creation of crystallographic defects and dislocations within magnetic grains. This makes it difficult to conclude whether shock-induced changes in the rock magnetic properties of target materials are primarily associated with mechanical or thermal effects. Here we present novel experimental methods to discriminate between mechanical and thermal effects of shock on magnetic properties and illustrate it with two examples of spherically shocked terrestrial basalt and diabase [1], which were shocked to pressures of 10 to >160 GPa, and investigate possible explanations for the observed shock-induced magnetic hardening (i.e., increase in remanent coercivity Bcr). The methods consist of i) conducting extra heating experiments at temperatures resembling those experienced during high-pressure shock events on untreated equivalents of shocked rocks (with further comparison of Bcr of shocked and heated samples) and ii) quantitative comparison of high-resolution first-order reversal curve (FORC) diagrams (field step: 0.5-0.7 mT) for shocked, heated and untreated specimens. Using this approach, we demonstrated that the shock-induced coercivity hardening in our samples is predominantly due to solid-state, mechanical effects of shock rather than alteration associated with shock heating. Indeed, heating-induced changes in Bcr in the post-shock temperature range were minor. Visual inspection of FORC contours (in addition to detailed analyses) reveals a stretching of the FORC distribution of shocked sample towards higher coercivities

Simple model for decay of laser generated shock waves

International Nuclear Information System (INIS)

Trainor, R.J.

1980-01-01

A simple model is derived to calculate the hydrodynamic decay of laser-generated shock waves. Comparison with detailed hydrocode simulations shows good agreement between calculated time evolution of shock pressure, position, and instantaneous pressure profile. Reliability of the model decreases in regions of the target where superthermal-electron preheat effects become comparable to shock effects

Direct-drive shock-ignition for the Laser MégaJoule

Directory of Open Access Journals (Sweden)

Canaud B.

2013-11-01

Full Text Available We present a review of direct-drive shock ignition studies done as an alternative for the Laser MégaJoule (LMJ. One and two dimensional systematic analyses of HiPER-like shock-ignited target designs are performed for the fuel assembly irradiation uniformity using the whole LMJ configuration or a part of the facility, and for the uniformity of the ignitor spike. High-gain shock-ignition is shown to be possible with intensity of each quad less than 1015 W/cm2 but low modes asymmetries displace the power required in the ignitor spike towards higher powers. Shock-ignition of Direct-Drive Double-Shell non-cryogenic targets is also addressed.

Shock Wave Propagation in Layered Planetary Interiors: Revisited

Science.gov (United States)

Arkani-Hamed, J.; Monteux, J.

2017-12-01

The end of the terrestrial planet accretion is characterized by numerous large impacts. About 90% of the mass of a large planet is accreted while the core mantle separation is occurring, because of the accretionary and the short-lived radio-isotope heating. The characteristics of the shockwave propagation, hence the existing scaling laws are poorly known within the layered planets. Here, we use iSALE-2D hydrocode simulations to calculate shock pressure in a differentiated Mars type body for impact velocities of 5-20 km/s, and impactor sizes of 100-400 km. We use two different rheologies for the target interior, an inviscid model ("no-stress model") and a pressure and damage-dependent strength model ("elaborated model"). To better characterize the shock pressure within the whole mantle as a function of distance from the impact site, we propose the following distribution: (1) a near field zone larger than the isobaric core that extends to 7-15 times the projectile radius into the target, where the peak shock pressure decays exponentially with increasing distance, (2) a far field zone where the pressure decays with distance following a power law. The shock pressure decreases more rapidly with distance in the near field for the elaborated model than for the no-stress model because of the influence of acoustic fluidization and damage. However to better illustrate the influence of the rheology on the shock propagation, we use the same expressions to fit the shock pressure with distance for both models. At the core-mantle boundary, CMB, the peak shock pressure jumps as the shock wave enters the core. We derived the boundary condition at CMB for the peak shock pressure. It is less sensitive to the impact velocity or the impactor size, but strongly depends on the rheology of the planet's mantle. Because of the lower shock wave velocity in the core compared to that in the mantle, the refracted shockwave propagates toward the symmetry axis of the planet, and the shock

Stripped-envelope supernova SN 2004dk is now interacting with hydrogen-rich circumstellar material

Science.gov (United States)

Mauerhan, Jon C.; Filippenko, Alexei V.; Zheng, WeiKang; Brink, Thomas; Graham, Melissa L.; Shivvers, Isaac; Clubb, Kelsey

2018-05-01

The dominant mechanism and time scales over which stripped-envelope supernovae (SNe) progenitor stars shed their hydrogen envelopes are uncertain. Observations of Type Ib and Ic SNe at late phases could reveal the optical signatures of interaction with distant circumstellar material (CSM) providing important clues on the origin of the necessary pre-SN mass loss. We report deep late-time optical spectroscopy of the Type Ib explosion SN 2004dk 4684 days (13 years) after discovery. We detect strong Hα emission with an intermediate line width of ˜400 km s-1 and luminosity ˜2.5 × 1039 erg s-1, signaling that the SN blast wave has caught up with the hydrogen-rich CSM lost by the progenitor system. The line luminosity is the highest ever reported for a SN at this late stage. Prominent emission features of He I, Fe, and Ca are also detected. The spectral characteristics are consistent with CSM energized by the forward shock, and resemble the late-time spectra of the persistently interacting Type IIn SNe 2005ip and 1988Z. We suggest that the onset of interaction with H-rich CSM was associated with a previously reported radio rebrightening at ˜1700 days. The data indicate that the mode of pre-SN mass loss was a relatively slow dense wind that persisted millennia before the SN, followed by a short-lived Wolf-Rayet phase that preceded core-collapse and created a cavity within an extended distribution of CSM. We also present new spectra of SNe 2014C, PTF11iqb, and 2009ip, all of which also exhibit continued interaction with extended CSM distributions.

Synthesis, characterization and photocatalytic performance of SnS nanofibers and SnSe nanofibers derived from the electrospinning-made SnO{sub 2} nanofibers

Energy Technology Data Exchange (ETDEWEB)

Cheng, Li; Li, Dan; Dong, Xiangting; Ma, Qianli; Yu, Wensheng; Wang, Xinlu; Yu, Hui; Wang, Jinxian; Liu, Guixia, E-mail: dongxiangting888@163.com [Key Laboratory of Applied Chemistry and Nanotechnology at Universities of Jilin Province, Changchun University of Science and Technology, Changchun (China)

2017-11-15

SnO{sub 2} nanofibers were fabricated by calcination of the electrospun PVP/SnCl{sub 4} composite nanofibers. For the first time, SnS nanofibers and SnSe nanofibers were successfully synthesized by double crucible sulfurization and selenidation methods via inheriting the morphology of SnO{sub 2} nanofibers used as precursors, respectively. X-ray diffraction (XRD) analysis shows SnS nanofibers and SnSe nanofibers are respectively pure orthorhombic phase with space group of Pbnm and Cmcm. Scanning electron microscope (SEM) observation indicates that the diameters of SnS nanofibers and SnSe nanofibers are respectively 140.54±12.80 nm and 96.52±14.17 nm under the 95 % confidence level. The photocatalytic activities of samples were studied by using rhodamine B (Rh B) as degradation agent. When SnS or SnSe nanofibers are employed as the photocatalysts, the respective degradation rates of Rh B solution under the ultraviolet light irradiation after 200 min irradiation are 92.55 % and 92.86 %. The photocatalytic mechanism and formation process of SnS and SnSe nanofibers are also provided. More importantly, this preparation technique is of universal significance to prepare other metal chalcogenides nanofibers. (author)

SN 2017dio: A Type-Ic Supernova Exploding in a Hydrogen-rich Circumstellar Medium

Science.gov (United States)

Kuncarayakti, Hanindyo; Maeda, Keiichi; Ashall, Christopher J.; Prentice, Simon J.; Mattila, Seppo; Kankare, Erkki; Fransson, Claes; Lundqvist, Peter; Pastorello, Andrea; Leloudas, Giorgos; Anderson, Joseph P.; Benetti, Stefano; Bersten, Melina C.; Cappellaro, Enrico; Cartier, Régis; Denneau, Larry; Della Valle, Massimo; Elias-Rosa, Nancy; Folatelli, Gastón; Fraser, Morgan; Galbany, Lluís; Gall, Christa; Gal-Yam, Avishay; Gutiérrez, Claudia P.; Hamanowicz, Aleksandra; Heinze, Ari; Inserra, Cosimo; Kangas, Tuomas; Mazzali, Paolo; Melandri, Andrea; Pignata, Giuliano; Rest, Armin; Reynolds, Thomas; Roy, Rupak; Smartt, Stephen J.; Smith, Ken W.; Sollerman, Jesper; Somero, Auni; Stalder, Brian; Stritzinger, Maximilian; Taddia, Francesco; Tomasella, Lina; Tonry, John; Weiland, Henry; Young, David R.

2018-02-01

SN 2017dio shows both spectral characteristics of a type-Ic supernova (SN) and signs of a hydrogen-rich circumstellar medium (CSM). Prominent, narrow emission lines of H and He are superposed on the continuum. Subsequent evolution revealed that the SN ejecta are interacting with the CSM. The initial SN Ic identification was confirmed by removing the CSM interaction component from the spectrum and comparing with known SNe Ic and, reversely, adding a CSM interaction component to the spectra of known SNe Ic and comparing them to SN 2017dio. Excellent agreement was obtained with both procedures, reinforcing the SN Ic classification. The light curve constrains the pre-interaction SN Ic peak absolute magnitude to be around {M}g=-17.6 mag. No evidence of significant extinction is found, ruling out a brighter luminosity required by an SN Ia classification. These pieces of evidence support the view that SN 2017dio is an SN Ic, and therefore the first firm case of an SN Ic with signatures of hydrogen-rich CSM in the early spectrum. The CSM is unlikely to have been shaped by steady-state stellar winds. The mass loss of the progenitor star must have been intense, \\dot{M}∼ 0.02{({ε }{{H}α }/0.01)}-1 ({v}{wind}/500 km s‑1) ({v}{shock}/10,000 km s‑1)‑3 M ⊙ yr‑1, peaking at a few decades before the SN. Such a high mass-loss rate might have been experienced by the progenitor through eruptions or binary stripping. Based on observations made with the NOT, operated by the Nordic Optical Telescope Scientific Association at the Observatorio del Roque de los Muchachos, La Palma, Spain, of the Instituto de Astrofisica de Canarias. This work is based (in part) on observations collected at the European Organisation for Astronomical Research in the Southern Hemisphere, Chile as part of PESSTO, (the Public ESO Spectroscopic Survey for Transient Objects Survey) ESO program 188.D-3003, 191.D-0935, 197.D-1075. Based on observations made with the Liverpool Telescope operated on the

Sn-In-Ag phase equilibria and Sn-In-(Ag)/Ag interfacial reactions

International Nuclear Information System (INIS)

Chen Sinnwen; Lee Wanyu; Hsu Chiaming; Yang Chingfeng; Hsu Hsinyun; Wu Hsinjay

2011-01-01

Research highlights: → Thermodynamic models of Sn-In and Sn-In-Ag are developed using the CALPHAD approach. → Reaction layer in the Sn-In-(Ag)/Ag couples at 100 deg. C is thinner than those at 25 deg. C, 50 deg. C, and 75 deg. C. → Reactions in the Sn-20 wt%In-2.8 wt%Ag/Ag couples are faster than those in the Sn-20 wt%In/Ag couples. - Abstract: Experimental verifications of the Sn-In and Sn-In-Ag phase equilibria have been conducted. The experimental measurements of phase equilibria and thermodynamic properties are used for thermodynamic modeling by the CALPHAD approach. The calculated results are in good agreement with experimental results. Interfacial reactions in the Sn-In-(Ag)/Ag couples have been examined. Both Ag 2 In and AgIn 2 phases are formed in the Sn-51.0 wt%In/Ag couples reacted at 100 and 150 deg. C, and only the Ag 2 In phase is formed when reacted at 25, 50 and 75 deg. C. Due to the different growth rates of different reaction phases, the reaction layer at 100 deg. C is thinner than those at 25 deg. C, 50 deg. C, and 75 deg. C. In the Sn-20.0 wt%In/Ag couples, the ζ phase is formed at 250 deg. C and ζ/AgIn 2 phases are formed at 125 deg. C. Compared with the Sn-20 wt%In/Ag couples, faster interfacial reactions are observed in the Sn-20.0 wt%In-2.8 wt%Ag/Ag couples, and minor Ag addition to Sn-20 wt%In solder increases the growth rates of the reaction phases.

Magnetic behaviour of cerium in Ce2 Sn5 and Ce3 Sn7, surstructures of Ce Sn3

International Nuclear Information System (INIS)

Stunault, A.

1988-07-01

The compound studied, Ce 2 Sn 5 and Ce 3 Sn 7 are both orthorhombic, surstructure of cubic Ce Sn 3 . Magnetic susceptibility measurements show in both compounds an antiferromagnetic order at low temperature and magnetization shows a high anisotropy. Magnetization densities are determined by polarized neutron diffraction. The cerium site which has two Ce atoms as nearest neighbourgs carries all the magnetism in both structures. For Ce 2 Sn 5 moments are directed as the high magnetization axis and structure is modulated. Ce 3 Sn 7 presents a simple antiferromagnetic order but moment are directed as low magnetization axis. Various transitions towards a ferromagnetic order are presented. Results are interpreted by measuring the difference between energy levels of crystalline field. A model of crystalline field and isotrope exchange agrees well with Ce 3 Sn 7 , but for Ce 2 Sn 7 it is necessary to reduce the magnetic moment which is typical of the Kondo effect [fr

Transfer reactions and multiple Coulomb excitation in the $^{100}$Sn Region

CERN Multimedia

It is proposed to continue our REX-ISOLDE program in the $^{100}$Sn region at HIE-ISOLDE at ~5 MeV/u. Earlier measurements, with a precision of 10-20%, at 3 MeV/u with REX-ISOLDE point to a deviation between the measured B(E2) values for the first excited 2$^{+}$ states in $^{110,108,106}$Sn compared to theoretical predictions. In addition, the trend of B(E2) values for the lighter isotopes, in particular $^{106}$Sn, appear to differ between low- and high-energy measurements. In line with our letter-of-intent we aim in a first step to address the electromagnetic properties of the first 2$^{+}$and 4$^{+}$ states in $^{110,108,106}$Sn using Coulomb excitation. In these measurements we will directly access the lifetimes of the first excited 4$^{+}$ states in $^{110,108,106}$Sn for the first time. The yield of $^{104}$Sn from the LaC$_{x}$ target will be revisited to clarify if the new solid state RILIS gives sufficient yield to expand the measurements to this isotope. Following this proposal we plan similar meas...

A novel snowflake-like SnO2 hierarchical architecture with superior gas sensing properties

Science.gov (United States)

Li, Yanqiong

2018-02-01

Snowflake-like SnO2 hierarchical architecture has been synthesized via a facile hydrothermal method and followed by calcination. The SnO2 hierarchical structures are assembled with thin nanoflakes blocks, which look like snowflake shape. A possible mechanism for the formation of the SnO2 hierarchical structures is speculated. Moreover, gas sensing tests show that the sensor based on snowflake-like SnO2 architectures exhibited excellent gas sensing properties. The enhancement may be attributed to its unique structures, in which the porous feature on the snowflake surface could further increase the active surface area of the materials and provide facile pathways for the target gas.

CHANDRA OBSERVATIONS OF SN 1987A: THE SOFT X-RAY LIGHT CURVE REVISITED

Energy Technology Data Exchange (ETDEWEB)

Helder, E. A.; Broos, P. S.; Burrows, D. N. [Department of Astronomy and Astrophysics, The Pennsylvania State University, 525 Davey Laboratory, University Park, PA 16802 (United States); Dewey, D. [MIT Kavli Institute, Cambridge, MA 02139 (United States); Dwek, E. [Observational Cosmology Laboratory, Code 665, NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); McCray, R. [JILA, University of Colorado and NIST, 440 UCB, Boulder, CO 80309 (United States); Park, S. [Department of Physics, University of Texas at Arlington, Box 19059, Arlington, TX 76019 (United States); Racusin, J. L. [NASA, Goddard Space Flight Center, Code 661, Greenbelt, MD 20771 (United States); Zhekov, S. A. [Space Research and Technology Institute, Akad. G. Bonchev str., bl.1, Sofia 1113 (Bulgaria)

2013-02-10

We report on the present stage of SN 1987A as observed by the Chandra X-Ray Observatory. We reanalyze published Chandra observations and add three more epochs of Chandra data to get a consistent picture of the evolution of the X-ray fluxes in several energy bands. We discuss the implications of several calibration issues for Chandra data. Using the most recent Chandra calibration files, we find that the 0.5-2.0 keV band fluxes of SN 1987A have increased by {approx}6 Multiplication-Sign 10{sup -13} erg s{sup -1} cm{sup -2} per year since 2009. This is in contrast with our previous result that the 0.5-2.0 keV light curve showed a sudden flattening in 2009. Based on our new analysis, we conclude that the forward shock is still in full interaction with the equatorial ring.

Experimental tests of LiSn alloys as potential liquid metal for the divertor target in a fusion reactor

Directory of Open Access Journals (Sweden)

F.L. Tabarés

2017-08-01

Full Text Available The first experiments of exposure of a LiSn alloy (Li/Sn atomic ratio= 20/80 to a hydrogen plasma in TJ-II are here presented. Solid and liquid samples have been inserted at the edge and evidence of sample melting of a solid sample during plasma exposure has been observed. A negligible perturbation of the plasma has been recorded, even when stellarator plasmas are particularly sensitive to high Z elements due to the tendency to central impurity accumulation. Melting of the sample by the plasma thermal load did not lead to any deleterious effect on the plasma performance. Strong lithium emission was detected at the LiSn sample but no sign of Sn contamination and low values of Zeff and radiated power were deduced. Hydrogen recycling was studied at two different temperatures and no change was detected in the range of 300–750K. The retention of H2 by the alloy was addressed in separate experiments at the laboratory. Values in the order of 0.01% H/(Sn+Li were deduced in agreement with in situ TDS analysis of the plasma exposed samples and previous reports.

Ethanol electrooxidation on Pt-Sn and Pt-Sn-W bulk alloys

Energy Technology Data Exchange (ETDEWEB)

Anjos, D.M. dos; Hahn, F.; Leger, J.M.; Kokoh, K.B. [Universite de Poitiers, Poitiers Cedex (France). Centre National de la Recherche Scientifique (CNRS). Equipe Electrocatalyse; Tremiliosi-Filho, G. [Universidade de Sao Paulo (USP), Sao Carlos, SP (Brazil). Inst. de Quimica

2008-07-01

Ethanol oxidation has been studied on Pt-Sn and Pt-Sn-W electrodes prepared in an arc-melting furnace. Different electrochemical techniques like cyclic voltammetry and chronoamperometry were used to evaluate the catalytic activity of these materials. The electro-oxidation process was also investigated by in situ infrared reflectance spectroscopy in order to determine adsorbed intermediates and reaction products. Experimental results indicated that Pt-Sn and Pt-Sn-W alloys are able to oxidize ethanol mainly to acetaldehyde and acetic acid. Adsorbed CO was also detected, demonstrating the viability of splitting the C-C bond in the ethanol molecule during the oxidation process. The adsorbed CO was further oxidized to CO{sub 2}.This reaction product was clearly detected by SNIFTIRS. Pt-Sn-W catalyst showed a better electrochemical performance than Pt-Sn that, in it turn, is better than Pt-alone. (author)

Ultraviolet emission from low resistance Cu2SnS3/SnO2 and CuInS2/Sn:In2O3 nanowires

Directory of Open Access Journals (Sweden)

E. Karageorgou

2014-11-01

Full Text Available SnO2 and Sn:In2O3 nanowires were grown on Si(001, and p-n junctions were fabricated in contact with p-type Cu2S which exhibited rectifying current–voltage characteristics. Core-shell Cu2SnS3/SnO2 and CuInS2/Sn:In2O3 nanowires were obtained by depositing copper and post-growth processing under H2S between 100 and 500 °C. These consist mainly of tetragonal rutile SnO2 and cubic bixbyite In2O3. We observe photoluminescence at 3.65 eV corresponding to band edge emission from SnO2 quantum dots in the Cu2SnS3/SnO2 nanowires due to electrostatic confinement. The Cu2SnS3/SnO2 nanowires assemblies had resistances of 100 Ω similar to CuInS2/In2O3 nanowires which exhibited photoluminescence at 3.0 eV.

Optical Probes for Laser Induced Shocks

Science.gov (United States)

1992-03-01

target by the strong water. As the shock passes the material interface, it is pressure transients. only partially transmitted. The shock pressure is...T. Swimm , J. Appl. Phys. 61, evaporated, t1137(1987). vapor flow substantially. The coupling coefficient thus de- 3 v. A. Batanov and V. B. Fedorov...Waist-Surface Distance [mm] isurface on the drilling mechanismC Positive ( negative ) To roughly estimate the total recoil momentum positions

Phase diagram of SnTe-CdSe cross-section of SnTe+CdSe reversible SnSe+CdTe ternary reciprocal system

International Nuclear Information System (INIS)

Dubrovin, I.V.; Budennaya, L.D.; Mizetskaya, I.B.; Sharkina, Eh.V.

1986-01-01

Phase equilibrium diagram of SnTe-CdSe cross-section of Sn, Cd long Te, Se ternary reciprocal system is investigated using the methods of differential thermal, X-ray phase, and microstructural analyses. Maximum length of solid solutions on the base of SnTe corresponds to approximately 14 mol.% at 1050 K and approximately 3 mol.% of CdSe at 670 K. Region of solid solutions on the base of CdSe corresponds to less than 1 mol.% of SnTe at room temperature. SnTe-CdSe cross-section is not a quasibinar one. Equilibrium is shifted to the left in the SnTe+CdSe reversible SnSe+CdTe reciprocal system

Targeting of tolerogenic dendritic cells towards heat-shock proteins: a novel therapeutic strategy for autoimmune diseases?

Science.gov (United States)

Jansen, Manon A A; Spiering, Rachel; Broere, Femke; van Laar, Jacob M; Isaacs, John D; van Eden, Willem; Hilkens, Catharien M U

2018-01-01

Tolerogenic dendritic cells (tolDCs) are a promising therapeutic tool to restore immune tolerance in autoimmune diseases. The rationale of using tolDCs is that they can specifically target the pathogenic T-cell response while leaving other, protective, T-cell responses intact. Several ways of generating therapeutic tolDCs have been described, but whether these tolDCs should be loaded with autoantigen(s), and if so, with which autoantigen(s), remains unclear. Autoimmune diseases, such as rheumatoid arthritis, are not commonly defined by a single, universal, autoantigen. A possible solution is to use surrogate autoantigens for loading of tolDCs. We propose that heat-shock proteins may be a relevant surrogate antigen, as they are evolutionarily conserved between species, ubiquitously expressed in inflamed tissues and have been shown to induce regulatory T cells, ameliorating disease in various arthritis mouse models. In this review, we provide an overview on how immune tolerance may be restored by tolDCs, the problem of selecting relevant autoantigens for loading of tolDCs, and why heat-shock proteins could be used as surrogate autoantigens. © 2017 John Wiley & Sons Ltd.

Astrophysically relevant radiatively cooled hypersonic bow shocks in nested wire arrays

Science.gov (United States)

Ampleford, David

2009-11-01

We have performed laboratory experiments which introduce obstructions into hypersonic plasma flows to study the formation of shocks. Astrophysical observations have demonstrated many examples of equivalent radiatively cooled bow shocks, for example the head of protostellar jets or supernova remnants passing through the interstellar medium or between discrete clumps in jets. Wire array z-pinches allow us to study quasi-planar radiatively cooled flows in the laboratory. The early stage of a wire array z-pinch implosion consists of a steady flow of the wire material towards the axis. Given a high rate of radiative cooling, these flows reach high sonic- Mach numbers, typically up to 5. The 2D nature of this configuration allows the insertion of obstacles into the flow, such as a concentric ``inner'' wire array, as has previously been studied for ICF research. Here we study the application of such a nested array to laboratory astrophysics where the inner wires act as obstructions perpendicular to the flow, and induce bow shocks. By varying the wire array material (W/Al), the significance of radiative cooling on these shocks can be controlled, and is shown to change the shock opening angle. As multiple obstructions are present, the experiments show the interaction of multiple bow shocks. It is also possible to introduce a magnetic field around the static object, increasing the opening angle of the shocks. Further experiments can be designed to control the flow density, magnetic field structure and obstruction locations. In collaboration with: S.V. Lebedev, M.E. Cuneo, C.A. Jennings, S.N. Bland, J.P. Chittenden, A. Ciardi, G.N. Hall, S.C. Bott, M. Sherlock, A. Frank, E. Blackman

70 °C synthesis of high-Sn content (25%) GeSn on insulator by Sn-induced crystallization of amorphous Ge

Energy Technology Data Exchange (ETDEWEB)

Toko, K., E-mail: toko@bk.tsukuba.ac.jp; Oya, N.; Suemasu, T. [Institute of Applied Physics, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573 (Japan); Saitoh, N.; Yoshizawa, N. [Electron Microscope Facility, TIA, AIST, 16-1 Onogawa, Tsukuba 305-8569 (Japan)

2015-02-23

Polycrystalline GeSn thin films are fabricated on insulating substrates at low temperatures by using Sn-induced crystallization of amorphous Ge (a-Ge). The Sn layer stacked on the a-Ge layer (100-nm thickness each) had two roles: lowering the crystallization temperature of a-Ge and composing GeSn. Slow annealing at an extremely low temperature of 70 °C allowed for a large-grained (350 nm) GeSn layer with a lattice constant of 0.590 nm, corresponding to a Sn composition exceeding 25%. The present investigation paves the way for advanced electronic optical devices integrated on a flexible plastic substrate as well as on a Si platform.

Spectral and ion emission features of laser-produced Sn and SnO2 plasmas

Science.gov (United States)

Hui, Lan; Xin-Bing, Wang; Du-Luo, Zuo

2016-03-01

We have made a detailed comparison of the atomic and ionic debris, as well as the emission features of Sn and SnO2 plasmas under identical experimental conditions. Planar slabs of pure metal Sn and ceramic SnO2 are irradiated with 1.06 μm, 8 ns Nd:YAG laser pulses. Fast photography employing an intensified charge coupled device (ICCD), optical emission spectroscopy (OES), and optical time of flight emission spectroscopy are used as diagnostic tools. Our results show that the Sn plasma provides a higher extreme ultraviolet (EUV) conversion efficiency (CE) than the SnO2 plasma. However, the kinetic energies of Sn ions are relatively low compared with those of SnO2. OES studies show that the Sn plasma parameters (electron temperature and density) are lower compared to those of the SnO2 plasma. Furthermore, we also give the effects of the vacuum degree and the laser pulse energy on the plasma parameters. Project supported by the National Natural Science Foundation of China (Grant No. 11304235) and the Director Fund of WNLO, China.

Physical Properties of the X-Ray-Luminous SN 1978K in NGC 1313 from Multiwavelength Observations

Science.gov (United States)

Schlegel, Eric M.; Ryder, Stuart; Staveley-Smith, L.; Petre, R.; Colbert, E.; Dopita, M.; Campbell-Wilson, D.

1999-12-01

We update the light curves from the X-ray, optical, and radio bandpasses which we have assembled over the past decade and present two observations in the ultraviolet using the Hubble Space Telescope Faint Object Spectrograph. The HRI X-ray light curve is constant within the errors over the entire observation period. This behavior is confirmed in the ASCA GIS data obtained in 1993 and 1995. In the ultraviolet, we detected Lyα, the [Ne IV] 2422/2424 Å doublet, the Mg II doublet at 2800 Å, and a line at approximately 3190 Å that we attribute to He I 3187. Only the Mg II and He I lines are detected at SN 1978K's position. The optical light curve is formally constant within the errors, although a slight upward trend may be present. The radio light curve continues its steep decline. The longer time span of our radio observations compared to previous studies shows that SN 1978K is in the same class of highly X-ray and radio-luminous supernovae as SN 1986J and SN 1988Z. The [Ne IV] emission is spatially distant from the location of SN 1978K and originates in the preshocked matter. The Mg II doublet flux ratio implies the quantity of line optical depth times density of approximately 1014 cm-3 for its emission region. The emission site must lie in the shocked gas.

Investigation of magnetic flux transport and shock formation in a staged Z-pinch

Science.gov (United States)

Narkis, J.; Rahman, H. U.; Wessel, F. J.; Beg, F. N.

2017-10-01

Target preheating is an integral component of magnetized inertial fusion in reducing convergence ratio. In the staged Z-pinch concept, it is achieved via one or more shocks. Previous work [Narkis et al., Phys. Plasmas 23, 122706 (2016)] found that shock formation in the target occurred earlier in higher-Z liners due to faster flux transport to the target/liner interface. However, a corresponding increase in magnitude of magnetic pressure was not observed, and target implosion velocity (and therefore shock strength) remained unchanged. To investigate other means of increasing the magnitude of transported flux, a Korteweg-de Vries-Burgers equation from the 1-D single-fluid, resistive magnetohydrodynamic equations is obtained. Solutions to the nondispersive (i.e., Burgers) equation depend on nondimensional coefficients, whose dependence on liner density, temperature, etc., suggests an increase in target implosion velocity, and therefore shock strength, can be obtained by tailoring the mass of a single-liner gas puff to a double-liner configuration. In the selected test cases of 1-D simulated implosions of krypton on deuterium, the peak Mach number increased from ˜ 5 to ˜ 8 . While a notable increase was seen, Mach numbers exceeding 10 (implosion velocities exceeding ˜25 cm/μs) are necessary for adequate shock preheating.

Fabrication of textured SnO2 transparent conductive films using self-assembled Sn nanospheres

Science.gov (United States)

Fukumoto, Michitaka; Nakao, Shoichiro; Hirose, Yasushi; Hasegawa, Tetsuya

2018-06-01

We present a novel method to fabricate textured surfaces on transparent conductive SnO2 films by processing substrates through a bottom-up technique with potential for industrially scalable production. The substrate processing consists of three steps: deposition of precursor Sn films on glass substrates, formation of a self-assembled Sn nanosphere layer with reductive annealing, and conversion of Sn to SnO2 by oxidative annealing. Ta-doped SnO2 films conformally deposited on the self-assembled nanospherical SnO2 templates exhibited attractive optical and electrical properties, namely, enhanced haze values and low sheet resistances, for applications as transparent electrodes in photovoltaics.

Undercuts by Laser Shock Forming

International Nuclear Information System (INIS)

Wielage, Hanna; Vollertsen, Frank

2011-01-01

In laser shock forming TEA-CO 2 -laser induced shock waves are used to form metal foils, such as aluminum or copper. The process utilizes an initiated plasma shock wave on the target surface, which leads to a forming of the foil. A challenge in forming technologies is the manufacturing of undercuts. By conventional forming methods these special forms are not feasible. In this article, it is presented that undercuts in the micro range can be produced by laser shock deep drawing. Different drawing die diameters, drawing die depths and the material aluminum in the thicknesses 20 and 50 μm were investigated. It will be presented that smaller die diameters facilitate undercuts compared to bigger die diameters. The phenomena can be explained by Barlow's formula. Furthermore, it is shown which maximum undercut depth at different die diameters can be reached. To this end, cross-sections of the different parameter combinations are displayed.

First shock tuning and backscatter measurements for large case-to-capsule ratio beryllium targets

Science.gov (United States)

Loomis, Eric; Yi, Austin; Kline, John; Kyrala, George; Simakov, Andrei; Wilson, Doug; Ralph, Joe; Dewald, Eduard; Strozzi, David; Celliers, Peter; Millot, Marius; Tommasini, Riccardo

2016-10-01

The current under performance of target implosions on the National Ignition Facility (NIF) has necessitated scaling back from high convergence ratio to access regimes of reduced physics uncertainties. These regimes, we expect, are more predictable by existing radiation hydrodynamics codes giving us a better starting point for isolating key physics questions. One key question is the lack of predictable in-flight and hot spot shape due to a complex hohlraum radiation environment. To achieve more predictable, shape tunable implosions we have designed and fielded a large 4.2 case-to-capsule ratio (CCR) target at the NIF using 6.72 mm diameter Au hohlraums and 1.6 mm diameter Cu-doped Be capsules. Simulations show that at these dimensions during a 10 ns 3-shock laser pulse reaching 270 eV hohlraum temperatures, the interaction between hohlraum and capsule plasma, which at lower CCR lead to beam propagation impedance by artificial plasma stagnation, are reduced. In this talk we will present measurements of early time drive symmetry using two-axis line-imaging velocimetry (VISAR) and streaked radiography measuring velocity of the imploding shell and their comparisons to post-shot calculations using the code HYDRA (Lawrence Livermore National Laboratory).

Ordered CoSn-type ternary phases in Co3Sn3-xGex

DEFF Research Database (Denmark)

Allred, Jared M.; Jia, Shuang; Bremholm, Martin

2012-01-01

. By taking advantage of the chemical differences between the two crystallographically inequivalent Sn sites in the structure, we observe ordered ternary phases, nominally Co3SnGe2 and Co3Sn2Ge. The electron count and unit cell configuration remain unchanged from CoSn; these observations thus help to clarify...

Fusion barrier distributions in 28,30Si + 124Sn reactions

International Nuclear Information System (INIS)

Danu, L.S.; Nayak, B.K.; Biswas, D.C.; Saxena, A.; Thomas, R.G.; Mirgule, E.T.; Choudhury, R.K.

2009-01-01

The coupling of various degrees of freedom such as static deformation, inelastic excitation and nucleon transfer with the relative motion gives rise to a distribution of barrier in heavy ion induced fusion reactions. The barrier distribution is a fingerprint of the reaction characterizing the important channel couplings. The relative importance of various couplings in fusion reaction is of topical interest. In an earlier study with deformed projectiles 28,30 Si on 115 In target, it was observed that the barrier distributions get affected due to coulomb reorientation of the deformed projectile nuclei in the field of target nucleus thus giving rise to fusion hindrance at sub-barrier energies. In that study, we considered deformed projectile rotational and positive Q-value transfer channel couplings to relative motion in fusion for investigation of Coulomb reorientation and no inelastic coupling of the 115 In target was considered. In the present work, we have extended the measurements with 124 Sn target and inelastic coupling of target has been considered in the coupled channel calculations. The fusion barrier distributions for 28,30 Si + 124 Sn systems have been obtained by quasi-elastic scattering measurements at backward angles and the results compared with the predictions of coupled channel calculations

Multi-dimensional simulations of the expanding supernova remnant of SN 1987A

Energy Technology Data Exchange (ETDEWEB)

Potter, T. M.; Staveley-Smith, L. [International center for Radio Astronomy Research (ICRAR) M468, The University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 (Australia); Reville, B. [Center for Plasma Physics, Queen' s University Belfast, University Road, Belfast BT7 1NN (United Kingdom); Ng, C.-Y. [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); Bicknell, G. V.; Sutherland, R. S. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 0200 (Australia); Wagner, A. Y., E-mail: tobympotter@gmail.com [Center for Computational Sciences, Tsukuba University, Tsukuba, Ibaraki, 305-8577 (Japan)

2014-10-20

The expanding remnant from SN 1987A is an excellent laboratory for investigating the physics of supernovae explosions. There is still a large number of outstanding questions, such as the reason for the asymmetric radio morphology, the structure of the pre-supernova environment, and the efficiency of particle acceleration at the supernova shock. We explore these questions using three-dimensional simulations of the expanding remnant between days 820 and 10,000 after the supernova. We combine a hydrodynamical simulation with semi-analytic treatments of diffusive shock acceleration and magnetic field amplification to derive radio emission as part of an inverse problem. Simulations show that an asymmetric explosion, combined with magnetic field amplification at the expanding shock, is able to replicate the persistent one-sided radio morphology of the remnant. We use an asymmetric Truelove and McKee progenitor with an envelope mass of 10 M {sub ☉} and an energy of 1.5 × 10{sup 44} J. A termination shock in the progenitor's stellar wind at a distance of 0.''43-0.''51 provides a good fit to the turn on of radio emission around day 1200. For the H II region, a minimum distance of 0.''63 ± 0.''01 and maximum particle number density of (7.11 ± 1.78) × 10{sup 7} m{sup –3} produces a good fit to the evolving average radius and velocity of the expanding shocks from day 2000 to day 7000 after explosion. The model predicts a noticeable reduction, and possibly a temporary reversal, in the asymmetric radio morphology of the remnant after day 7000, when the forward shock left the eastern lobe of the equatorial ring.

ON THE RADIO POLARIZATION SIGNATURE OF EFFICIENT AND INEFFICIENT PARTICLE ACCELERATION IN SUPERNOVA REMNANT SN 1006

Energy Technology Data Exchange (ETDEWEB)

Reynoso, Estela M. [Instituto de Astronomia y Fisica del Espacio (IAFE), C. C. 67, Suc. 28, 1428 Buenos Aires (Argentina); Hughes, John P. [Department of Physics and Astronomy, Rutgers University, Piscataway, NJ 08854-8019 (United States); Moffett, David A., E-mail: ereynoso@iafe.uba.ar, E-mail: jph@physics.rutgers.edu, E-mail: david.moffett@furman.edu [Department of Physics, Furman University, Greenville, SC 29613 (United States)

2013-04-15

Radio polarization observations provide essential information on the degree of order and orientation of magnetic fields, which themselves play a key role in the particle acceleration processes that take place in supernova remnants (SNRs). Here we present a radio polarization study of SN 1006, based on combined Very Large Array and Australia Telescope Compact Array observations at 20 cm that resulted in sensitive images with an angular resolution of 10 arcsec. The fractional polarization in the two bright radio and X-ray lobes of the SNR is measured to be 0.17, while in the southeastern sector, where the radio and non-thermal X-ray emission are much weaker, the polarization fraction reaches a value of 0.6 {+-} 0.2, close to the theoretical limit of 0.7. We interpret this result as evidence of a disordered, turbulent magnetic field in the lobes, where particle acceleration is believed to be efficient, and a highly ordered field in the southeast, where the acceleration efficiency has been shown to be very low. Utilizing the frequency coverage of our observations, an average rotation measure of {approx}12 rad m{sup -2} is determined from the combined data set, which is then used to obtain the intrinsic direction of the magnetic field vectors. While the orientation of magnetic field vectors across the SNR shell appear to be radial, a large fraction of the magnetic vectors lie parallel to the Galactic plane. Along the highly polarized southeastern rim, the field is aligned tangent to the shock, and therefore also nearly parallel to the Galactic plane. These results strongly suggest that the ambient field surrounding SN 1006 is aligned with this direction (i.e., from northeast to southwest) and that the bright lobes are due to a polar cap geometry. Our study establishes that the most efficient particle acceleration and generation of magnetic turbulence in SN 1006 is attained for shocks in which the magnetic field direction and shock normal are quasi-parallel, while

ON THE RADIO POLARIZATION SIGNATURE OF EFFICIENT AND INEFFICIENT PARTICLE ACCELERATION IN SUPERNOVA REMNANT SN 1006

International Nuclear Information System (INIS)

Reynoso, Estela M.; Hughes, John P.; Moffett, David A.

2013-01-01

Radio polarization observations provide essential information on the degree of order and orientation of magnetic fields, which themselves play a key role in the particle acceleration processes that take place in supernova remnants (SNRs). Here we present a radio polarization study of SN 1006, based on combined Very Large Array and Australia Telescope Compact Array observations at 20 cm that resulted in sensitive images with an angular resolution of 10 arcsec. The fractional polarization in the two bright radio and X-ray lobes of the SNR is measured to be 0.17, while in the southeastern sector, where the radio and non-thermal X-ray emission are much weaker, the polarization fraction reaches a value of 0.6 ± 0.2, close to the theoretical limit of 0.7. We interpret this result as evidence of a disordered, turbulent magnetic field in the lobes, where particle acceleration is believed to be efficient, and a highly ordered field in the southeast, where the acceleration efficiency has been shown to be very low. Utilizing the frequency coverage of our observations, an average rotation measure of ∼12 rad m –2 is determined from the combined data set, which is then used to obtain the intrinsic direction of the magnetic field vectors. While the orientation of magnetic field vectors across the SNR shell appear to be radial, a large fraction of the magnetic vectors lie parallel to the Galactic plane. Along the highly polarized southeastern rim, the field is aligned tangent to the shock, and therefore also nearly parallel to the Galactic plane. These results strongly suggest that the ambient field surrounding SN 1006 is aligned with this direction (i.e., from northeast to southwest) and that the bright lobes are due to a polar cap geometry. Our study establishes that the most efficient particle acceleration and generation of magnetic turbulence in SN 1006 is attained for shocks in which the magnetic field direction and shock normal are quasi-parallel, while inefficient

Growth of highly textured SnS on mica using an SnSe buffer layer

International Nuclear Information System (INIS)

Wang, S.F.; Fong, W.K.; Wang, W.; Surya, C.

2014-01-01

We report the growth of SnS thin films on mica substrates by molecular beam epitaxy. Excellent 2D layered structure and strong (001) texture were observed with a record low rocking curve full width at half maximum of ∼ 0.101° for the SnS(004) diffraction. An interface model is used to investigate the nucleation of SnS on mica which indicates the co-existence of six pairs of lateral growth orientations and is in excellent agreement with the experimental Φ-scan measurements indicating 12 peaks separated by 30° from each other. To control the lateral growth of the SnS epilayers we investigate the utilization of a thin SnSe buffer layer deposited on the mica substrate prior to the growth of the SnS thin film. The excellent lattice match between SnSe and mica enhances the alignment of the nucleation of SnS and suppresses the minor lateral orientations along the mica[110] direction and its orthogonal axis. Detailed low-frequency noise measurement was performed to characterize the trap density in the films and our results clearly demonstrate substantial reduction in the density of the localized states in the SnS epilayer with the use of an SnSe buffer layer. - Highlights: • A record low rocking curve FWHM for deposited SnS on mica • Investigation of the nucleation of SnS on mica using the interface model • Investigation of nucleation mechanism by phi-scan measurement • Grain boundary formation from crystallites of various nucleation orientations • Suppression of nucleation orientations using an SnSe buffer layer

Space power distribution of soft x-ray source ANGARA-5-1

Energy Technology Data Exchange (ETDEWEB)

Dyabilin, K S [High Energy Density Research Center, Moscow (Russian Federation); Fortov, V E; Grabovskij, E V; Lebedev, M E; Smirnov, V P [Troitsk Inst. of Innovative and Fusion Research, Troitsk (Russian Federation)

1997-12-31

The contribution deals with the investigation of shock waves in condensed targets generated by intense pulses of soft X radiation. Main attention is paid to the spatial distribution of the soft x-ray power, which influence strongly the shock wave front uniformity. Hot z-pinch plasma with the temperature of 60-100 eV produced by imploding double liner in the ANGARA-5-1 machine was used as a source of x rays. The maximum pinch current was as high as 3.5 MA. In order to eliminate the thermal heating of the targets, thick stepped Al/Pb, Sn/Pb, or pure Pb targets were used. The velocity of shock waves was determined by means of optical methods. Very uniform shock waves and shock pressures of up to several hundreds of GPa have been achieved. (J.U.). 3 figs., 2 refs.

Shock Timing Plan for the National Ignition Campaign

Science.gov (United States)

Munro, D. H.; Robey, H. F.; Spears, B. K.; Boehly, T. R.

2006-10-01

We report progress on the design of the shock timing tuning procedure for the 2010 ignition campaign at the National Ignition Facility. Our keyhole target design provides adequate drive surrogacy for us to time the first three shocks empirically. The major risk to our plan is hard x-ray preheat, which can cause the diagnostic window to become opaque.

Emissive spectra of shock-heated argon

International Nuclear Information System (INIS)

Tang Jingyou; Gu Yan; Peng Qixian; Bai Yulin; Li Ping

2003-01-01

To study the radiant properties of argon under weak shock compression, an aluminum target filled with gaseous argon at ambient states was impacted by a tungsten alloy projectile which was launched from a two-stage light gun to 2.00 km/s. The radiant signals of single shock-compressed argon were recorded by a six-channel pyrometer and oscilloscopes, which varied with time linearly for the five channels from 405 nm to 700 nm and exponentially for the channel 800 nm, and the corresponding velocity of shock wave was determined to be 4.10 ± 0.09 km/s. By the present experiment, it has been shown that the absorbability of the shock-heated argon is low for visual light and the optical depths of argon gas turn from thin to thick as wavelengths gradually increase. The time-resolved spectra in the rising-front of the radiant signal in the re-shocked argon were recorded by means of an OMA, and strong emissive spectrum bands near 450 nm light-wave length but no linear spectrum were found. The emissive spectrum properties of shock-compression argon were qualitatively explained by the state parameters and ionization degree

Electrical and optical properties of SnEuTe and SnSrTe films

Science.gov (United States)

Ishida, Akihiro; Tsuchiya, Takuro; Yamada, Tomohiro; Cao, Daoshe; Takaoka, Sadao; Rahim, Mohamed; Felder, Ferdinand; Zogg, Hans

2010-06-01

The SnTe, Sn1-xEuxTe and Sn1-xSrxTe (x<0.06) films were prepared by hot wall epitaxy. The ternary alloy films prepared in cation rich condition had hole concentration around 1×1019 cm-3 with high mobility exceeding 2000 cm2/V s at room temperature. Optical transmission spectra were also measured in the temperature range from 100 to 400 K and compared with theoretical calculations. Optical transmission spectra of the SnTe were simulated successfully assuming bumped band edge structures. A band inversion model was proposed for the Sn1-xEuxTe and Sn1-xSrxTe systems, and the optical transmission spectra were also simulated successfully assuming the band inversion model.

A model for the acceleration of laser irradiated targets

International Nuclear Information System (INIS)

Babonneau, D.; Di Bona, G.; Fortin, X.

1986-11-01

Starting from the self-similar propagation of an electronic conduction wave and the consequent ablation pressure, we describe, in a simplified way, the shock ahead of this wave, then the effects of the rarefaction and compression waves which follow the shock emergence at the target rear surface. So, we obtain the temporal evolution of the rear velocity which is compared with the experimental one. For thick targets, the shock alone is able to emerge during the experimental time and consequently gives the velocity vsub(min). For thin targets, besides the shock accumulation mechanism, it is necessary to take into account the electronic heat wave emergence that is to say the ''complete'' ablation of the target which gives the velocity vsub(max)

Ejection of the Massive Hydrogen-rich Envelope Timed with the Collapse of the Stripped SN 2014C

Energy Technology Data Exchange (ETDEWEB)

Margutti, Raffaella [Center for Interdisciplinary Exploration and Research in Astrophysics (CIERA), Department of Physics and Astronomy, Northwestern University, Evanston, IL 60208 (United States); Kamble, A.; Milisavljevic, D.; Drout, M.; Chakraborti, S.; Kirshner, R.; Parrent, J. T.; Patnaude, D.; Soderberg, A. M. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Zapartas, E.; De Mink, S. E. [Anton Pannenkoek Institute for Astronomy, University of Amsterdam, 1090 GE Amsterdam (Netherlands); Chornock, R. [Astrophysical Institute, Department of Physics and Astronomy, 251B Clippinger Lab, Ohio University, Athens, OH 45701 (United States); Risaliti, G. [INAF-Arcetri Astrophysical Observatory, Largo E. Fermi 5, I-50125 Firenze (Italy); Zauderer, B. A. [Center for Cosmology and Particle Physics, New York University, 4 Washington Place, New York, NY 10003 (United States); Bietenholz, M. [Department of Physics and Astronomy, York University, Toronto, ON M3J 1P3 (Canada); Cantiello, M. [Kavli Institute for Theoretical Physics, University of California, Santa Barbara, CA 93106 (United States); Chomiuk, L. [Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Fong, W. [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Grefenstette, B. [Cahill Center for Astrophysics, 1216 E. California Boulevard, California Institute of Technology, Pasadena, CA 91125 (United States); Guidorzi, C. [University of Ferrara, Department of Physics and Earth Sciences, via Saragat 1, I-44122 Ferrara (Italy); and others

2017-02-01

We present multi-wavelength observations of SN 2014C during the first 500 days. These observations represent the first solid detection of a young extragalactic stripped-envelope SN out to high-energy X-rays ∼40 keV. SN 2014C shows ordinary explosion parameters ( E {sub k} ∼ 1.8 × 10{sup 51} erg and M {sub ej} ∼ 1.7 M{sub ⊙}). However, over an ∼1 year timescale, SN 2014C evolved from an ordinary hydrogen-poor supernova into a strongly interacting, hydrogen-rich supernova, violating the traditional classification scheme of type-I versus type-II SNe. Signatures of the SN shock interaction with a dense medium are observed across the spectrum, from radio to hard X-rays, and revealed the presence of a massive shell of ∼1 M {sub ⊙} of hydrogen-rich material at ∼6 × 10{sup 16} cm. The shell was ejected by the progenitor star in the decades to centuries before collapse. This result challenges current theories of massive star evolution, as it requires a physical mechanism responsible for the ejection of the deepest hydrogen layer of H-poor SN progenitors synchronized with the onset of stellar collapse. Theoretical investigations point at binary interactions and/or instabilities during the last nuclear burning stages as potential triggers of the highly time-dependent mass loss. We constrain these scenarios utilizing the sample of 183 SNe Ib/c with public radio observations. Our analysis identifies SN 2014C-like signatures in ∼10% of SNe. This fraction is reasonably consistent with the expectation from the theory of recent envelope ejection due to binary evolution if the ejected material can survive in the close environment for 10{sup 3}–10{sup 4} years. Alternatively, nuclear burning instabilities extending to core C-burning might play a critical role.

RCI Simulation for EUV spectra from Sn ions

International Nuclear Information System (INIS)

Kagawa, T; Tanuma, H; Ohashi, H; Nishihara, K

2007-01-01

Using the relativistic-configuration-interaction atomic structure code, RCI simulations for EUV spectra from Sn 10+ , Sn 11+ and Sn 12+ ions are carried out, where it is assumed that each ion is embedded in a LTE plasma with the electron temperature of 30 eV. To make clear assignment of the measured spectra, the value of the excitation energy limit, which is introduced to limit the number of excited states in the simulation, is changed to see the excitation-energy-limit dependence of the spectral shape. The simulated spectra are obtained as a superposition of line intensities due to all possible transitions between two states whose excitation energy from the ground state is lower than the excitation energy limit assumed. The RCI simulated spectra are compared to the spectra measured with the chargeexchange- collision experiment in which a rare gas such as Xe or He as a target is bombarded by a charge-selected tin ion. Applicability of the LTE model to a decay model in the charge exchange collision experiment is also discussed

In-beam studies of {sup 98}Cd and {sup 102}Sn

Energy Technology Data Exchange (ETDEWEB)

Lipoglavsek, M. [Uppsala Univ. (Sweden)]|[J. Stefan Institute, Ljubljana (Slovenia); Gorska, M.; Schubart, R. [GSI, Darmstadt (Germany)] [and others

1996-12-31

For the first time excited states of the neutron deficient nuclei {sup 98}Cd and {sup 102}Sn were identified using in-beam spectroscopy following fusion evaporation reactions. Half lives of long lived isomeric states in both nuclei were also measured. Due to very low cross sections for producing {sup 98}Cd and {sup 102}Sn with stable beams and targets, a special detector setup utilizing NORDBALL ancillary detectors and a recoil catcher device was used. High {gamma}-ray detection efficiency was achieved with two EUROBALL Ge cluster detectors.

Advances in NIF Shock Timing Experiments

Science.gov (United States)

Robey, Harry

2012-10-01

Experiments are underway to tune the shock timing of capsule implosions on the National Ignition Facility (NIF). These experiments use a modified cryogenic hohlraum geometry designed to precisely match the performance of ignition hohlraums. The targets employ a re-entrant Au cone to provide optical access to multiple shocks as they propagate in the liquid deuterium-filled capsule interior. The strength and timing of all four shocks is diagnosed with VISAR (Velocity Interferometer System for Any Reflector). Experiments are now routinely conducted in a mirrored keyhole geometry, which allows for simultaneous diagnosis of the shock timing at both the hohlraum pole and equator. Further modifications are being made to improve the surrogacy to ignition hohlraums by replacing the standard liquid deuterium (D2) capsule fill with a deuterium-tritium (DT) ice layer. These experiments will remove any possible surrogacy difference between D2 and DT as well as incorporate the physics of shock release from the ice layer, which is absent in current experiments. Experimental results and comparisons with numerical simulation are presented.

Shock ignition of thermonuclear fuel: principles and modelling

International Nuclear Information System (INIS)

Atzeni, S.; Ribeyre, X.; Schurtz, G.; Schmitt, A.J.; Canaud, B.; Betti, R.; Perkins, L.J.

2014-01-01

Shock ignition is an approach to direct-drive inertial confinement fusion (ICF) in which the stages of compression and hot spot formation are partly separated. The fuel is first imploded at a lower velocity than in conventional ICF. Close to stagnation, an intense laser spike drives a strong converging shock, which contributes to hot spot formation. Shock ignition shows potentials for high gain at laser energies below 1 MJ, and could be tested on the National Ignition Facility or Laser MegaJoule. Shock ignition principles and modelling are reviewed in this paper. Target designs and computer-generated gain curves are presented and discussed. Limitations of present studies and research needs are outlined. (special topic)

Laser soldering of Sn-Ag-Cu and Sn-Zn-Bi lead-free solder pastes

Science.gov (United States)

Takahashi, Junichi; Nakahara, Sumio; Hisada, Shigeyoshi; Fujita, Takeyoshi

2004-10-01

It has reported that a waste of an electronics substrate including lead and its compound such as 63Sn-37Pb has polluted the environment with acid rain. For that environment problem the development of lead-free solder alloys has been promoted in order to find out the substitute for Sn-Pb solders in the United States, Europe, and Japan. In a present electronics industry, typical alloys have narrowed down to Sn-Ag-Cu and Sn-Zn lead-free solder. In this study, solderability of Pb-free solder that are Sn-Ag-Cu and Sn-Zn-Bi alloy was studied on soldering using YAG (yttrium aluminum garnet) laser and diode laser. Experiments were peformed in order to determine the range of soldering parameters for obtaining an appropriate wettability based on a visual inspection. Joining strength of surface mounting chip components soldered on PCB (printed circuit board) was tested on application thickness of solder paste (0.2, 0.3, and 0.4 mm). In addition, joining strength characteristics of eutectic Sn-Pb alloy and under different power density were examined. As a result, solderability of Sn-Ag-Cu (Pb-free) solder paste are equivalent to that of coventional Sn-Pb solder paste, and are superior to that of Sn-Zn-Bi solder paste in the laser soldering method.

SN 2009E

DEFF Research Database (Denmark)

Pastorello...[], A.; Pumo, M.L.; Navasardyan, H.

2012-01-01

. In this paper we investigate the properties of SN 2009E, which exploded in a relatively nearby spiral galaxy (NGC 4141) and that is probably the faintest 1987A-like supernova discovered so far. We also attempt to characterize this subgroup of core-collapse supernovae with the help of the literature and present...... observations which started about 2 months after the supernova explosion, highlight significant differences between SN 2009E and the prototypical SN 1987A. Modelling the data of SN 2009E allows us to constrain the explosion parameters and the properties of the progenitor star, and compare the inferred estimates...... 2009E ejected about 0.04 M⊙ of 56Ni, which is the smallest 56Ni mass in our sample of 1987A-like events. Modelling the observations with a radiation hydrodynamics code, we infer for SN 2009E a kinetic plus thermal energy of about 0.6 foe, an initial radius of ~7 × 1012 cm and an ejected mass of ~19 M...

Interface analysis of embedded chip resistor device package and its effect on drop shock reliability.

Science.gov (United States)

Park, Se-Hoon; Kim, Sun Kyoung; Kim, Young-Ho

2012-04-01

In this study, the drop reliability of an embedded passive package is investigated under JESD22-B111 condition. Chip resistors were buried in a PCB board, and it was electrically interconnected by electroless and electrolytic copper plating on a tin pad of a chip resistor without intermetallic phase. However tin, nickel, and copper formed a complex intermetallic phase, such as (Cu, Ni)6Sn5, (Cu, Ni)3Sn, and (Ni, Cu)3Sn2, at the via interface and via wall after reflow and aging. Since the amount of the tin layer was small compared with the solder joint, excessive intermetallic layer growth was not observed during thermal aging. Drop failures are always initiated at the IMC interface, and as aging time increases Cu-Sn-Ni IMC phases are transformed continuously due to Cu diffusion. We studied the intermetallic formation of the Cu via interface and simulated the stress distribution of drop shock by using material properties and board structure of embedded passive boards. The drop simulation was conducted according to the JEDEC standard. It was revealed that the crack starting point related to failure fracture changed due to intermetallic phase transformation along the via interface, and the position where failure occurs experimentally agrees well with our simulation results.

Preparation, deformation, and failure of functional Al-Sn and Al-Sn-Pb nanocrystalline alloys

Science.gov (United States)

Noskova, N. I.; Vil'Danova, N. F.; Filippov, Yu. I.; Churbaev, R. V.; Pereturina, I. A.; Korshunov, L. G.; Korznikov, A. V.

2006-12-01

Changes in the structure, hardness, mechanical properties, and friction coefficient of Al-30% Sn, Al-15% Sn-25% Pb, and Al-5% Sn-35% Pb (wt %) alloys subjected to severe plastic deformation by equal-channel angular pressing (with a force of 40 tonne) and by shear at a pressure of 5 GPa have been studied. The transition into the nanocrystalline state was shown to occur at different degrees of plastic deformation. The hardness exhibits nonmonotonic variations, namely, first it increases and subsequently decreases. The friction coefficient of the Al-30% Sn, Al-15% Sn-25% Pb, and Al-5% Sn-35% Pb alloys quenched from the melt was found to be 0.33; the friction coefficients of these alloys in the submicrocrystalline state (after equal-channel angular pressing) equal 0.24, 0.32, and 0.35, respectively. The effect of disintegration into nano-sized powders was found to occur in the Al-15% Sn-25% Pb, and Al-5% Sn-35% Pb alloys after severe plastic deformation to ɛ = 6.4 and subsequent short-time holding.

Study of neutron-deficient Sn isotopes

International Nuclear Information System (INIS)

Auger, G.

1982-05-01

The formation of neutron deficient nuclei by heavy ion reactions is investigated. The experimental technique is presented, and the results obtained concerning Sn et In isotopes reported: first excited states of 106 Sn, high spin states in 107 Sn and 107 In; Yrast levels of 106 Sn, 107 Sn, 108 Sn; study of neutron deficient Sn and In isotopes formed by the desintegration of the compound nucleus 112 Xe. All these results are discussed [fr

Electrochemical properties of Ti-Ni-Sn materials predicted by {sup 119}Sn Mössbauer spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Ladam, A., E-mail: alix.ladam@univ-montp2.fr; Aldon, L.; Lippens, P.-E.; Olivier-Fourcade, J.; Jumas, J.-C. [Université de Montpellier, Institut Charles Gerhardt, UMR 5253 CNRS (France); Cenac-Morthe, C. [CNES, Service DCT/TV/El (France)

2016-12-15

The electrochemical activity of TiNiSn, TiNi {sub 2}Sn and Ti {sub 6}Sn {sub 5} compounds considered as negative electrode materials for Li-ion batteries has been predicted from the isomer shift- Hume-Rothery electronic density correlation diagram. The ternary compounds were obtained from solid-state reactions and Ti {sub 6}Sn {sub 5} by ball milling. The {sup 119}Sn Mössbauer parameters were experimentally determined and used to evaluate the Hume-Rothery electronic density [e {sub av}]. The values of [e {sub av}] are in the region of Li-rich Li-Sn alloys for Ti {sub 6}Sn {sub 5} and outside this region for the ternary compounds, suggesting that the former compound is electrochemically active but not the two latter ones. Electrochemical tests were performed for these different materials confirming this prediction. The close values of [e {sub av}] for Ti {sub 6}Sn {sub 5} and Li-rich Li-Sn alloys indicate that the observed good capacity retention could be related to small changes in the global structures during cycling.

Theoretical study of electronic structures and spectroscopic properties of Ga 3Sn, GaSn 3, and their ions

Science.gov (United States)

Zhu, Xiaolei

2007-01-01

Ground and excited states of mixed gallium stannide tetramers (Ga 3Sn, Ga 3Sn +, Ga 3Sn -, GaSn 3, GaSn 3+, and GaSn 3-) are investigated employing the complete active space self-consistent-field (CASSCF), density function theory (DFT), and the coupled-cluster single and double substitution (including triple excitations) (CCSD(T)) methods. The ground states of Ga 3Sn, Ga 3Sn +, and Ga 3Sn - are found to be the 2A 1, 3B 1, and 1A 1 states in C2v symmetry with a planar quadrilateral geometry, respectively. The ground states of GaSn 3 and GaSn 3- is predicted to be the 2A 1 and 1A 1 states in C2v point group with a planar quadrilateral structure, respectively, while the ground state of GaSn 3+ is the 1A 1 state with ideal triangular pyramid C3v geometry. Equilibrium geometries, vibrational frequencies, binding energies, electron affinities, ionization energies, and other properties of Ga 3Sn and GaSn 3 are computed and discussed. The anion photoelectron spectra of Ga 3Sn - and GaSn 3- are also predicted. It is interesting to find that the amount of charge transfer between Ga and Sn 2 atoms in the 1A 1 state of GaSn 3+ greatly increases upon electron ionization from the 2A 1 state of GaSn 3, which may be caused by large geometry change. On the other hand, the results of the low-lying states of Ga 3Sn and GaSn 3 are compared with those of Ga 3Si and GaSi 3.

Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts

Directory of Open Access Journals (Sweden)

Nur Hidayati

2016-03-01

Full Text Available Even though platinum is known as an active electro-catalyst for ethanol oxidation at low temperatures (< 100 oC, choosing the electrode material for ethanol electro-oxidation is a crucial issue. It is due to its property which easily poisoned by a strong adsorbed species such as CO. PtSn-based electro-catalysts have been identified as better catalysts for ethanol electro-oxidation. The third material is supposed to improved binary catalysts performance. This work presents a study of the ethanol electro-oxidation on carbon supported Pt-Sn and Pt-Sn-Ni catalysts. These catalysts were prepared by alcohol reduction. Nano-particles with diameters between 2.5-5.0 nm were obtained. The peak of (220 crystalline face centred cubic (fcc Pt phase for PtSn and PtSnNi alloys was repositioned due to the presence of Sn and/or Ni in the alloy. Furthermore, the modification of Pt with Sn and SnNi improved ethanol and CO electro-oxidation. Copyright © 2016 BCREC GROUP. All rights reserved Received: 10th November 2015; Revised: 1st February 2016; Accepted: 1st February 2016 How to Cite: Hidayati, N., Scott, K. (2016. Electro-oxidation of Ethanol on Carbon Supported PtSn and PtSnNi Catalysts. Bulletin of Chemical Reaction Engineering & Catalysis, 11 (1: 10-20. (doi:10.9767/bcrec.11.1.394.10-20 Permalink/DOI: http://dx.doi.org/10.9767/bcrec.11.1.394.10-20

Sn ion energy distributions of ns- and ps-laser produced plasmas

Science.gov (United States)

Bayerle, A.; Deuzeman, M. J.; van der Heijden, S.; Kurilovich, D.; de Faria Pinto, T.; Stodolna, A.; Witte, S.; Eikema, K. S. E.; Ubachs, W.; Hoekstra, R.; Versolato, O. O.

2018-04-01

Ion energy distributions arising from laser-produced plasmas of Sn are measured over a wide laser parameter space. Planar-solid and liquid-droplet targets are exposed to infrared laser pulses with energy densities between 1 J cm‑2 and 4 kJ cm‑2 and durations spanning 0.5 ps to 6 ns. The measured ion energy distributions are compared to two self-similar solutions of a hydrodynamic approach assuming isothermal expansion of the plasma plume into vacuum. For planar and droplet targets exposed to ps-long pulses, we find good agreement between the experimental results and the self-similar solution of a semi-infinite simple planar plasma configuration with an exponential density profile. The ion energy distributions resulting from solid Sn exposed to ns-pulses agrees with solutions of a limited-mass model that assumes a Gaussian-shaped initial density profile.

Two-Dimensional Simulations of Electron Shock Ignition at the Megajoule Scale

Science.gov (United States)

Shang, W.; Betti, R.

2016-10-01

Shock ignition uses a late strong shock to ignite the hot spot of an inertial confinement fusion capsule. In the standard shock-ignition scheme, an ignitor shock is launched by the ablation pressure from a spike in laser intensity. Recent experiments on OMEGA have shown that focused beams with intensity up to 6 ×1015 W /cm2 can produce copious amounts of hot electrons. The hot electrons are produced by laser-plasma instabilities (LPI's) and can carry up to 15 % of the instantaneous laser power. Megajoule-scale targets will likely produce even more hot electrons because of the large plasma scale length. We show that it is possible to design ignition targets with low implosion velocities that can be shock ignited using LPI-generated hot electrons to obtain high energy gains. These designs are robust to low-mode asymmetries and they ignite even for highly distorted implosions. Electron shock ignition requires tens of kilojoules of hot electrons, which can only be produced on a large laser facility like the National Ignition Facility. This material is based upon work supported by the Department of Energy National Nuclear Security Administration under Award Number DE-NA0001944.

CONSTRUÇÕES BINOMINAIS DO TIPO SN1 DE SN2

Directory of Open Access Journals (Sweden)

Karen Sampaio Braga Alonso

2017-04-01

Full Text Available Este artigo tem por objetivo investigar a flutuação de sentido quantidade-qualidade licenciada pelo uso de construtos binominais do tipo SN1 de SN2, como xícara de chá, no Português do Brasil.A pesquisa é baseada na perspectiva teórica da Linguística Funcional Centrada no Uso (BYBEE, 2010; BARLOW E KEMMER, 2000; TOMASELLO, 2003, TRAUGOTT, 2008 e busca descrever as propriedades morfossintáticas, semântico-pragmáticas e cognitivas dos usos das construções que favorecem uma leitura ora qualitativa ora quantitativa, no que se refere à relação entre SN1 e SN2.

Analysis of Methanol Sensitivity on SnO2-ZnO Nanocomposite

Science.gov (United States)

Bassey, Enobong E.; Sallis, Philip; Prasad, Krishnamachar

This research reports on the sensing behavior of a nanocomposite of tin dioxide (SnO2) and zinc oxide (ZnO). SnO2-ZnO nanocomposites were fabricated into sensor devices by the radio frequency sputtering method, and used for the characterization of the sensitivity behavior of methanol vapor. The sensor devices were subjected to methanol concentration of 200 ppm at operating temperatures of 150, 250 and 350 °C. A fractional difference model was used to normalize the sensor response, and determine the sensitivity of methanol on the sensor. Response analysis of the SnO2-ZnO sensors to the methanol was most sensitive at 350 °C, followed by 250 and 150 °C. Supported by the morphology (FE-SEM, AFM) analyses of the thin films, the sensitivity behavior confirmed that the nanoparticles of coupled SnO2 and ZnO nanocomposites can promote the charge transportation, and be used to fine-tune the sensitivity of methanol and sensor selectivity to a desired target gas.

study on 113 Sn-113m In generator of the chromatographic column elution mode

International Nuclear Information System (INIS)

Abdel-Halim, A.A.

2002-01-01

this work has been carried out to study the optimum conditions required for local preparation of 113 Sn- 113m In radioisotope generator based on 12- molybdocerate- 113 Sn column matrix. this work was directed to: 1- investigate the optimum conditions of the tin target irradiation and dissolution processes. 2- study the different preparative conditions which affect the loading of 113 Sn radionuclide onto 12- molybdocerate (IV) columns and the elution of the generated 113m In radionuclide. 3- study the effect of generator life- time on the elution performance and quality control of the generated 113m In radionuclide over a period of 190 days

SN 2013fs and SN 2013fr: exploring the circumstellar-material diversity in Type II supernovae

Science.gov (United States)

Bullivant, Christopher; Smith, Nathan; Williams, G. Grant; Mauerhan, Jon C.; Andrews, Jennifer E.; Fong, Wen-Fai; Bilinski, Christopher; Kilpatrick, Charles D.; Milne, Peter A.; Fox, Ori D.; Cenko, S. Bradley; Filippenko, Alexei V.; Zheng, WeiKang; Kelly, Patrick L.; Clubb, Kelsey I.

2018-05-01

We present photometry and spectroscopy of SN 2013fs and SN 2013fr in the first ˜100 d post-explosion. Both objects showed transient, relatively narrow H α emission lines characteristic of SNe IIn, but later resembled normal SNe II-P or SNe II-L, indicative of fleeting interaction with circumstellar material (CSM). SN 2013fs was discovered within 8 h of explosion; one of the earliest SNe discovered thus far. Its light curve exhibits a plateau, with spectra revealing strong CSM interaction at early times. It is a less luminous version of the transitional SN IIn PTF11iqb, further demonstrating a continuum of CSM interaction intensity between SNe II-P and SNe IIn. It requires dense CSM within 6.5 × 1014 cm of the progenitor, from a phase of advanced pre-SN mass loss beginning shortly before explosion. Spectropolarimetry of SN 2013fs shows little continuum polarization (˜0.5 per cent, consistent with zero), but noticeable line polarization during the plateau phase. SN 2013fr morphed from an SN IIn at early times to an SN II-L. After the first epoch, its narrow lines probably arose from host-galaxy emission, but the bright, narrow H α emission at early times may be intrinsic to the SN. As for SN 2013fs, this would point to a short-lived phase of strong CSM interaction if proven to be intrinsic, suggesting a continuum between SNe IIn and SNe II-L. It is a low-velocity SN II-L like SN 2009kr, but more luminous. SN 2013fr also developed an infrared excess at later times, due to warm CSM dust that requires a more sustained phase of strong pre-SN mass loss.

SnO and SnO·CoO nanocomposite as high capacity anode materials for lithium ion batteries

Energy Technology Data Exchange (ETDEWEB)

Das, B., E-mail: bijoy822000@gmail.com; Reddy, M.V.; Chowdari, B.V.R, E-mail: phychowd@nus.edu.sg

2016-02-15

Highlights: • The preparation methods are simple, low cost and can be scaled up for large production. • SnO is cheap, non-toxic and eco-friendly. • SnO shows high reversible capacity (Theoretical reversible capacity: 875 mA h g{sup −1}). • We showed high reversible capacity and columbic efficiency for SnO and SnO based composites. • We addressed the capacity degradation by introducing secondary phase (CoO and CNT etc.) - Abstract: We prepared SnO nanoparticles (SnO–S) and SnO·CoO nanocomposites (SnO·CoO–B) as anodes for lithium ion batteries (LIBs) by chemical and ball-milling approaches, respectively. They are characterized by X-ray diffraction and TEM techniques. The Li- storage performance are evaluated by galvanostatic cycling and cyclic voltammetry. The SnO–S and SnO·CoO–B showed improved cycling performance due to their finite particle size (i.e. nano-size) and presence of secondary phase (CoO). Better cycling stability is noticed for SnO·CoO–B with the expense of their reversible capacity. Also, addition of carbon nanotubes (CNT) to SnO–S further improved the cycling performance of SnO–S. When cycled at 60 mA g{sup −1}, the first-cycle reversible capacities of 635, 590 and 460 (±10) mA h g{sup −1} are noticed for SnO–S, SnO@CNT and SnO·CoO–B, respectively. The capacity fading observed are 3.7 and 1.8 mA h g{sup −1} per cycle for SnO–S and SnO@CNT, respectively; whereas 1–1.2 mA h g{sup −1} per cycle for SnO·CoO–B. All the samples show high coulombic efficiency, 96–98% in the range of 5–50 cycles.

Reactive pulsed laser deposition of Cu2ZnSnS4 thin films in H2S

International Nuclear Information System (INIS)

Surgina, G.D.; Zenkevich, A.V.; Sipaylo, I.P.; Nevolin, V.N.; Drube, W.; Teterin, P.E.; Minnekaev, M.N.

2013-01-01

Cu 2 ZnSnS 4 (CZTS) thin films have been grown by reactive pulsed laser deposition in H 2 S atmosphere, combining the alternate ablation from the metallic (Cu) and alloyed (Zn x Sn) targets at room temperature. The morphological, structural and optical properties of as grown CZTS thin films with varying compositions as well as upon annealing in N 2 atmosphere are investigated by Rutherford backscattering spectrometry, X-ray diffraction, Raman spectroscopy and optical spectrophotometry. The chemical bonding in the “bulk” of the CZTS films is elucidated via hard X-ray photoemission spectroscopy measurements. The formation of the good quality stoichiometric polycrystalline CZTS films is demonstrated upon optimization of the growth parameters. - Highlights: ► The new method of Cu 2 ZnSnS 4 (CZTS) thin films growth in H 2 S was realized. ► CZTS films were grown by pulsed laser deposition from Cu and alloyed Zn–Sn targets. ► The effect of the processing parameters on the CZTS properties was investigated. ► The chemical bonding in the “bulk” of CZTS films was studied

Sn powder as reducing agents and SnO2 precursors for the synthesis of SnO2-reduced graphene oxide hybrid nanoparticles.

Science.gov (United States)

Chen, Mingxi; Zhang, Congcong; Li, Lingzhi; Liu, Yu; Li, Xichuan; Xu, Xiaoyang; Xia, Fengling; Wang, Wei; Gao, Jianping

2013-12-26

A facile approach to prepare SnO2/rGO (reduced graphene oxide) hybrid nanoparticles by a direct redox reaction between graphene oxide (GO) and tin powder was developed. Since no acid was used, it is an environmentally friendly green method. The SnO2/rGO hybrid nanoparticles were characterized by ultraviolet-visible spectroscopy, Raman spectroscopy, thermogravimetric analysis, X-ray diffraction analysis, and X-ray photoelectron spectroscopy. The microstructure of the SnO2/rGO was observed with scanning electron microscopy and transmission electron microscopy. The tin powder efficiently reduced GO to rGO, and the Sn was transformed to SnO2 nanoparticles (∼45 nm) that were evenly distributed on the rGO sheets. The SnO2/rGO hybrid nanoparticles were then coated on an interdigital electrode to fabricate a humidity sensor, which have an especially good linear impedance response from 11% to 85% relative humidity.

Detection and quantitative determination by PIXE of the mutagen Sn2+ in yeast cells

International Nuclear Information System (INIS)

Viau, C.M.; Yoneama, M.-L.; Dias, J.F.; Pungartnik, C.; Brendel, M.; Henriques, J.A.P.

2006-01-01

The main goal of this work was to determine the concentration of Sn 2+ ions in cells of the yeast Saccharomyces cerevisiae and to correlate their quantity with the genotoxicity of intracellularly accumulated metal ions. The intracellular metal content of yeast cells was determined by PIXE (particle-induced X-ray emission) after cell exposure to SnCl 2 . To that end, a thick target protocol was developed for PIXE analysis. The samples were irradiated with a 2 MeV proton beam, while the induced X-rays were detected with a high-purity germanium detector. The results of the toxicity of SnCl 2 and the PIXE analysis performed with two different yeast strains (haploid and diploid) suggest that the exposure of haploid and diploid yeast to Sn 2+ induces DNA lesions and that the absorption depends on the genetic background of each strain

Behavior of Sn atoms in GeSn thin films during thermal annealing: Ex-situ and in-situ observations

Science.gov (United States)

Takase, Ryohei; Ishimaru, Manabu; Uchida, Noriyuki; Maeda, Tatsuro; Sato, Kazuhisa; Lieten, Ruben R.; Locquet, Jean-Pierre

2016-12-01

Thermally induced crystallization processes for amorphous GeSn thin films with Sn concentrations beyond the solubility limit of the bulk crystal Ge-Sn binary system have been examined by X-ray photoelectron spectroscopy, grazing incidence X-ray diffraction, and (scanning) transmission electron microscopy. We paid special attention to the behavior of Sn before and after recrystallization. In the as-deposited specimens, Sn atoms were homogeneously distributed in an amorphous matrix. Prior to crystallization, an amorphous-to-amorphous phase transformation associated with the rearrangement of Sn atoms was observed during heat treatment; this transformation is reversible with respect to temperature. Remarkable recrystallization occurred at temperatures above 400 °C, and Sn atoms were ejected from the crystallized GeSn matrix. The segregation of Sn became more pronounced with increasing annealing temperature, and the ejected Sn existed as a liquid phase. It was found that the molten Sn remains as a supercooled liquid below the eutectic temperature of the Ge-Sn binary system during the cooling process, and finally, β-Sn precipitates were formed at ambient temperature.

A facile inexpensive route for SnS thin film solar cells with SnS{sub 2} buffer

Energy Technology Data Exchange (ETDEWEB)

Gedi, Sreedevi [School of Chemical Engineering, Yeungnam University, 280Daehak-ro, Gyeongsan 712-749, Republic of Korea (Korea, Republic of); Solar Photovoltaic Laboratory, Department of Physics, Sri Venkateswasra University, Tirupati 517 502 (India); Minna Reddy, Vasudeva Reddy, E-mail: drmvasudr9@gmail.com [School of Chemical Engineering, Yeungnam University, 280Daehak-ro, Gyeongsan 712-749, Republic of Korea (Korea, Republic of); Solar Photovoltaic Laboratory, Department of Physics, Sri Venkateswasra University, Tirupati 517 502 (India); Pejjai, Babu [School of Chemical Engineering, Yeungnam University, 280Daehak-ro, Gyeongsan 712-749, Republic of Korea (Korea, Republic of); Solar Photovoltaic Laboratory, Department of Physics, Sri Venkateswasra University, Tirupati 517 502 (India); Jeon, Chan-Wook [School of Chemical Engineering, Yeungnam University, 280Daehak-ro, Gyeongsan 712-749, Republic of Korea (Korea, Republic of); Park, Chinho, E-mail: chpark@ynu.ac.kr [School of Chemical Engineering, Yeungnam University, 280Daehak-ro, Gyeongsan 712-749, Republic of Korea (Korea, Republic of); Ramakrishna Reddy, K.T., E-mail: ktrkreddy@gmail.com [Solar Photovoltaic Laboratory, Department of Physics, Sri Venkateswasra University, Tirupati 517 502 (India)

2016-05-30

Graphical abstract: PYS spectra of SnS/SnS{sub 2} interface and the related band diagram. - Highlights: • A low cost SnS solar cell is developed using chemical bath deposition. • We found E{sub I} & χ of SnS (5.3 eV & 4.0 eV) and SnS{sub 2} (6.9 eV & 4.1 eV) films from PYS. • Band offsets of 0.1 eV (E{sub c}) and 1.6 eV (E{sub v}) are estimated for SnS/SnS{sub 2} junction. • SnS based solar cell showed a conversion efficiency of 0.51%. - Abstract: Environment-friendly SnS based thin film solar cells with SnS{sub 2} as buffer layer were successfully fabricated from a facile inexpensive route, chemical bath deposition (CBD). Layer studies revealed that as-grown SnS and SnS{sub 2} films were polycrystalline; (1 1 1)/(0 0 1) peaks as the preferred orientation; 1.3 eV/2.8 eV as optical band gaps; and showed homogeneous microstructure with densely packed grains respectively. Ionization energy and electron affinity values were found by applying photoemission yield spectroscopy (PYS) to the CBD deposited SnS and SnS{sub 2} films for the first time. These values obtained as 5.3 eV and 4.0 eV for SnS films; 6.9 eV and 4.1 eV for SnS{sub 2} films. The band alignment of SnS/SnS{sub 2} junction showed TYPE-II heterostructure. The estimated conduction and valance band offsets were 0.1 eV and 1.6 eV respectively. The current density–voltage (J–V) measurements of the cell showed open circuit voltage (V{sub oc}) of 0.12 V, short circuit current density (J{sub sc}) of 10.87 mA cm{sup −2}, fill factor (FF) of 39% and conversion efficiency of 0.51%.

Experimental Shock Transformation of Gypsum to Anhydrite: A New Low Pressure Regime Shock Indicator

Science.gov (United States)

Bell, Mary S.; Zolensky, Michael E.

2011-01-01

The shock behavior of gypsum is important in understanding the Cretaceous/Paleogene event and other terrestrial impacts that contain evaporite sediments in their targets (e.g., Mars Exploration Rover Spirit detected sulfate at Gusev crater, [1]). Most interest focuses on issues of devolatilization to quantify the production of SO2 to better understand its role in generating a temporary atmosphere and its effects on climate and biota [2,3]. Kondo and Ahrens [4] measured induced radiation emitted from single crystal gypsum shocked to 30 and 40 GPa. They observed greybody emission spectra corresponding to temperatures in the range of 3,000 to 4,000 K that are a factor of 2 to 10 times greater than calculated pressure-density energy equation of state temperatures (Hugoniot) and are high enough to melt gypsum. Chen et al. [5] reported results of shock experiments on anhydrite, gypsum, and mixtures of these phases with silica. Their observations indicated little or no devolatilization of anhydrite shocked to 42 GPa and that the fraction of sulfur, by mass, that degassed is approx.10(exp -2) of theoretical prediction. In another report of shock experiments on calcite, anhydrite, and gypsum, Badjukov et al. [6] observed only intensive plastic deformation in anhydrite shock loaded at 63 GPa, and gypsum converted to anhydrite when shock loaded at 56 GPa but have not experimentally shocked gypsum in a step-wise manner to constrain possible incipient transformation effects. Schmitt and Hornemann [7] shock loaded anhydrite and quartz to a peak pressure of 60 GPa and report the platy anhydrite grains were completely pseudomorphed by small crystallized anhydrite grains. However, no evidence of interaction between the two phases could be observed and they suggested that recrystallization of anhydrite grains is the result of a solid-state transformation. They concluded that significant decomposition of anhydrite requires shock pressures higher than 60 GPa. Gupta et al. [8

Barcoding heat shock proteins to human diseases: looking beyond the heat shock response.

Science.gov (United States)

Kakkar, Vaishali; Meister-Broekema, Melanie; Minoia, Melania; Carra, Serena; Kampinga, Harm H

2014-04-01

There are numerous human diseases that are associated with protein misfolding and the formation of toxic protein aggregates. Activating the heat shock response (HSR)--and thus generally restoring the disturbed protein homeostasis associated with such diseases--has often been suggested as a therapeutic strategy. However, most data on activating the HSR or its downstream targets in mouse models of diseases associated with aggregate formation have been rather disappointing. The human chaperonome consists of many more heat shock proteins (HSPs) that are not regulated by the HSR, however, and researchers are now focusing on these as potential therapeutic targets. In this Review, we summarize the existing literature on a set of aggregation diseases and propose that each of them can be characterized or 'barcoded' by a different set of HSPs that can rescue specific types of aggregation. Some of these 'non-canonical' HSPs have demonstrated effectiveness in vivo, in mouse models of protein-aggregation disease. Interestingly, several of these HSPs also cause diseases when mutated--so-called chaperonopathies--which are also discussed in this Review.

The 7SK snRNP associates with the little elongation complex to promote snRNA gene expression.

Science.gov (United States)

Egloff, Sylvain; Vitali, Patrice; Tellier, Michael; Raffel, Raoul; Murphy, Shona; Kiss, Tamás

2017-04-03

The 7SK small nuclear RNP (snRNP), composed of the 7SK small nuclear RNA (snRNA), MePCE, and Larp7, regulates the mRNA elongation capacity of RNA polymerase II (RNAPII) through controlling the nuclear activity of positive transcription elongation factor b (P-TEFb). Here, we demonstrate that the human 7SK snRNP also functions as a canonical transcription factor that, in collaboration with the little elongation complex (LEC) comprising ELL, Ice1, Ice2, and ZC3H8, promotes transcription of RNAPII-specific spliceosomal snRNA and small nucleolar RNA (snoRNA) genes. The 7SK snRNA specifically associates with a fraction of RNAPII hyperphosphorylated at Ser5 and Ser7, which is a hallmark of RNAPII engaged in snRNA synthesis. Chromatin immunoprecipitation (ChIP) and chromatin isolation by RNA purification (ChIRP) experiments revealed enrichments for all components of the 7SK snRNP on RNAPII-specific sn/snoRNA genes. Depletion of 7SK snRNA or Larp7 disrupts LEC integrity, inhibits RNAPII recruitment to RNAPII-specific sn/snoRNA genes, and reduces nascent snRNA and snoRNA synthesis. Thus, through controlling both mRNA elongation and sn/snoRNA synthesis, the 7SK snRNP is a key regulator of nuclear RNA production by RNAPII. © 2017 The Authors.

Effect of Sn addition on the microstructure and superelasticity in Ti-Nb-Mo-Sn alloys.

Science.gov (United States)

Zhang, D C; Yang, S; Wei, M; Mao, Y F; Tan, C G; Lin, J G

2012-09-01

Ti-7.5Nb-4Mo-xSn (x=0-4at%) alloys were developed as the biomedical materials. The effect of the Sn content on the microstructure and superelasticity of the alloys was investigated. It is found that Sn is a strong stabilizer of the β phase, which is effective in suppressing the formation of α″ and ω phases in the alloys. Moreover, the Sn addition has a significant impact on the mechanical properties of the alloys. With the increase of Sn addition, the yield stress of the alloys increase, but their elastic modulus, the fracture strength and the ductility decrease, and the deformation mode of the alloys changes from (322) twining to α″ transformation and then to slip. The Ti-7.5Nb-4Mo-1Sn and Ti-7.5Nb-4Mo-3Sn alloys exhibit a good superelasticity with a high σ(SIM) due to the relatively high athermal ω phases containing or the solution hardening at room temperature. Under the maximum strain of 5%, Ti-7.5Nb-4Mo-3Sn (at%) alloy exhibits higher super elastic stability than that of Ti-7.5Nb-4Mo-1Sn alloy. Copyright © 2012 Elsevier Ltd. All rights reserved.

Advances in shock timing experiments on the National Ignition Facility

International Nuclear Information System (INIS)

Robey, H F; Celliers, P M; Moody, J D; Sater, J; Parham, T; Kozioziemski, B; Dylla- Spears, R; Ross, J S; LePape, S; Ralph, J E; Hohenberger, M; Dewald, E L; Berzak Hopkins, L; Kroll, J J; Yoxall, B E; Hamza, A V; Landen, O L; Edwards, M J; Boehly, T R; Nikroo, A

2016-01-01

Recent advances in shock timing experiments and analysis techniques now enable shock measurements to be performed in cryogenic deuterium-tritium (DT) ice layered capsule implosions on the National Ignition Facility (NIF). Previous measurements of shock timing in inertial confinement fusion (ICF) implosions were performed in surrogate targets, where the solid DT ice shell and central DT gas were replaced with a continuous liquid deuterium (D2) fill. These previous experiments pose two surrogacy issues: a material surrogacy due to the difference of species (D2 vs. DT) and densities of the materials used and a geometric surrogacy due to presence of an additional interface (ice/gas) previously absent in the liquid-filled targets. This report presents experimental data and a new analysis method for validating the assumptions underlying this surrogate technique. (paper)

Advances in shock timing experiments on the National Ignition Facility

Science.gov (United States)

Robey, H. F.; Celliers, P. M.; Moody, J. D.; Sater, J.; Parham, T.; Kozioziemski, B.; Dylla-Spears, R.; Ross, J. S.; LePape, S.; Ralph, J. E.; Hohenberger, M.; Dewald, E. L.; Berzak Hopkins, L.; Kroll, J. J.; Yoxall, B. E.; Hamza, A. V.; Boehly, T. R.; Nikroo, A.; Landen, O. L.; Edwards, M. J.

2016-03-01

Recent advances in shock timing experiments and analysis techniques now enable shock measurements to be performed in cryogenic deuterium-tritium (DT) ice layered capsule implosions on the National Ignition Facility (NIF). Previous measurements of shock timing in inertial confinement fusion (ICF) implosions were performed in surrogate targets, where the solid DT ice shell and central DT gas were replaced with a continuous liquid deuterium (D2) fill. These previous experiments pose two surrogacy issues: a material surrogacy due to the difference of species (D2 vs. DT) and densities of the materials used and a geometric surrogacy due to presence of an additional interface (ice/gas) previously absent in the liquid-filled targets. This report presents experimental data and a new analysis method for validating the assumptions underlying this surrogate technique.

Fabrication of high crystalline SnS and SnS2 thin films, and their switching device characteristics

Science.gov (United States)

Choi, Hyeongsu; Lee, Jeongsu; Shin, Seokyoon; Lee, Juhyun; Lee, Seungjin; Park, Hyunwoo; Kwon, Sejin; Lee, Namgue; Bang, Minwook; Lee, Seung-Beck; Jeon, Hyeongtag

2018-05-01

Representative tin sulfide compounds, tin monosulfide (SnS) and tin disulfide (SnS2) are strong candidates for future nanoelectronic devices, based on non-toxicity, low cost, unique structures and optoelectronic properties. However, it is insufficient for synthesizing of tin sulfide thin films using vapor phase deposition method which is capable of fabricating reproducible device and securing high quality films, and their device characteristics. In this study, we obtained highly crystalline SnS thin films by atomic layer deposition and obtained highly crystalline SnS2 thin films by phase transition of the SnS thin films. The SnS thin film was transformed into SnS2 thin film by annealing at 450 °C for 1 h in H2S atmosphere. This phase transition was confirmed by x-ray diffractometer and x-ray photoelectron spectroscopy, and we studied the cause of the phase transition. We then compared the film characteristics of these two tin sulfide thin films and their switching device characteristics. SnS and SnS2 thin films had optical bandgaps of 1.35 and 2.70 eV, and absorption coefficients of about 105 and 104 cm‑1 in the visible region, respectively. In addition, SnS and SnS2 thin films exhibited p-type and n-type semiconductor characteristics. In the images of high resolution-transmission electron microscopy, SnS and SnS2 directly showed a highly crystalline orthorhombic and hexagonal layered structure. The field effect transistors of SnS and SnS2 thin films exhibited on–off drain current ratios of 8.8 and 2.1 × 103 and mobilities of 0.21 and 0.014 cm2 V‑1 s‑1, respectively. This difference in switching device characteristics mainly depends on the carrier concentration because it contributes to off-state conductance and mobility. The major carrier concentrations of the SnS and SnS2 thin films were 6.0 × 1016 and 8.7 × 1013 cm‑3, respectively, in this experiment.

Physics of laser-plasma interaction for shock ignition of fusion reactions

International Nuclear Information System (INIS)

Tikhonchuk, V T; Colaïtis, A; Vallet, A; Llor Aisa, E; Duchateau, G; Nicolaï, Ph; Ribeyre, X

2016-01-01

The shock ignition scheme is an alternative approach, which aims to achieve ignition of fusion reactions in two subsequent steps: first, the target is compressed at a low implosion velocity and second, a strong converging shock is launched during the stagnation phase and ignites the hot spot. In this paper we describe the major elements of this scheme and recent achievements concerning the laser-plasma interaction, the crucial role of hot electrons in the shock generation, the shock amplification in the imploding shell and the ignition conditions. (paper)

Fast-shock ignition: a new approach to inertial confinement fusion

Directory of Open Access Journals (Sweden)

AH Farahbod

2013-03-01

Full Text Available  A new concept for inertial confinement fusion called fast-shock ignition (FSI is introduced as a credible scheme in order to obtain high target gain. In the proposed model, the separation of fuel ignition into two successive steps, under the suitable conditions, reduces required ignitor energy for the fuel ignition. The main procedure in FSI concept is compressing the fuel up to stagnation. Then, two high intensity short pulse laser spikes with energy and power lower than those required for shock ignition (SI and fast ignition (FI with a proper delay time are launched at the fuel which increases the central hot-spot temperature and completes the ignition of the precompressed fuel. The introduced semi-analytical model indicates that with fast-shock ignition, the total required energy for compressing and igniting the fuel can be slightly reduced in comparison to pure shock ignition. Furthermore, for fuel mass greater than , the target energy gain increases up to 15 percent and the contribution of fast ignitor under the proper conditions could be decreased about 20 percent compared with pure fast ignition. The FSI scheme is beneficial from technological considerations for the construction of short pulse high power laser drivers. The general advantages of fast-shock ignition over pure shock ignition in terms of figure of merit can be more than 1.3.

Rational design of Sn/SnO{sub 2}/porous carbon nanocomposites as anode materials for sodium-ion batteries

Energy Technology Data Exchange (ETDEWEB)

Li, Xiaojia [Tianjin International Joint Research Centre of Surface Technology for Energy Storage Materials, College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China); Li, Xifei, E-mail: xfli2011@hotmail.com [Tianjin International Joint Research Centre of Surface Technology for Energy Storage Materials, College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China); Center for Advanced Energy Materials and Devices, Xi’an University of Technology, Xi’an 710048 (China); Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering, College of Chemistry, Nankai University, Tianjin 300071 (China); Fan, Linlin; Yu, Zhuxin; Yan, Bo; Xiong, Dongbin; Song, Xiaosheng; Li, Shiyu [Tianjin International Joint Research Centre of Surface Technology for Energy Storage Materials, College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China); Adair, Keegan R. [Nanomaterials and Energy Lab., Department of Mechanical and Materials Engineering, Western University, London, Ontario N6A 5B9 (Canada); Li, Dejun, E-mail: dejunli@mail.tjnu.edu.cn [Tianjin International Joint Research Centre of Surface Technology for Energy Storage Materials, College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China); Sun, Xueliang, E-mail: xsun9@uwo.ca [Nanomaterials and Energy Lab., Department of Mechanical and Materials Engineering, Western University, London, Ontario N6A 5B9 (Canada); Tianjin International Joint Research Centre of Surface Technology for Energy Storage Materials, College of Physics and Materials Science, Tianjin Normal University, Tianjin 300387 (China)

2017-08-01

Highlights: • Sn/SnO{sub 2}/porous carbon nanocomposites are rationally designed via a facile strategy. • The porous carbon mitigates the volume change and poor conductivity of Sn/SnO{sub 2}. • The nanocomposites exhibit the enhanced sodium storage performance. - Abstract: Sodium-ion batteries (SIBs) have successfully attracted considerable attention for application in energy storage, and have been proposed as an alternative to lithium ion batteries (LIBs) due to the abundance of sodium resources and low price. Sn has been deemed as a promising anode material in SIBs which holds high theoretical specific capacity of 845 mAh g{sup −1}. In this work we design nanocomposite materials consisting of porous carbon (PC) with SnO{sub 2} and Sn (Sn/SnO{sub 2}/PC) via a facile reflux method. Served as an anode material for SIBs, the Sn/SnO{sub 2}/PC nanocomposite delivers the primary discharge and charge capacities of 1148.1 and 303.0 mAh g{sup −1}, respectively. Meanwhile, it can preserve the discharge capacity approximately of 265.4 mAh g{sup −1} after 50 cycles, which is much higher than those of SnO{sub 2}/PC (138.5 mAh g{sup −1}) and PC (92.2 mAh g{sup −1}). Furthermore, the Sn/SnO{sub 2}/PC nanocomposite possesses better cycling stability with 77.8% capacity retention compared to that of SnO{sub 2}/PC (61.88%) over 50 cycles. Obviously, the Sn/SnO{sub 2}/PC composite with excellent electrochemical performance shows the great possibility of application in SIBs.

Shock response of a gamma titanium aluminide

International Nuclear Information System (INIS)

Shazly, Mostafa; Prakash, Vikas

2008-01-01

Potential use of γ-TiAl alloys in aerospace and other structural applications require knowledge of their impact behavior for better evaluation and modeling. In the present study plate impact experiments are conducted using a single-stage gas gun to better understand the shock behavior of the recently developed class of gamma titanium aluminide alloys--the Gamma-Met PX. The Gamma-Met PX showed superior shock properties when compared to the conventional titanium aluminide alloys. The spall strength of Gamma-Met PX is 1.8±0.09 GPa, which is four to six times higher than those reported for other gamma titanium aluminide alloys. Moreover, it has a Hugoniot elastic limit of 1.88 GPa at a target thickness of 3.86 mm, which drops to 1.15 GPa at target thickness of 15.8 mm. The decay in the elastic precursor is continuous without showing an asymptote to a constant level within the range of target thicknesses studied

Hierarchical Graphene-Encapsulated Hollow SnO2@SnS2 Nanostructures with Enhanced Lithium Storage Capability.

Science.gov (United States)

Xu, Wangwang; Xie, Zhiqiang; Cui, Xiaodan; Zhao, Kangning; Zhang, Lei; Dietrich, Grant; Dooley, Kerry M; Wang, Ying

2015-10-14

Complex hierarchical structures have received tremendous attention due to their superior properties over their constitute components. In this study, hierarchical graphene-encapsulated hollow SnO2@SnS2 nanostructures are successfully prepared by in situ sulfuration on the backbones of hollow SnO2 spheres via a simple hydrothermal method followed by a solvothermal surface modification. The as-prepared hierarchical SnO2@SnS2@rGO nanocomposite can be used as anode material in lithium ion batteries, exhibiting excellent cyclability with a capacity of 583 mAh/g after 100 electrochemical cycles at a specific current of 200 mA/g. This material shows a very low capacity fading of only 0.273% per cycle from the second to the 100th cycle, lower than the capacity degradation of bare SnO2 hollow spheres (0.830%) and single SnS2 nanosheets (0.393%). Even after being cycled at a range of specific currents varied from 100 mA/g to 2000 mA/g, hierarchical SnO2@SnS2@rGO nanocomposites maintain a reversible capacity of 664 mAh/g, which is much higher than single SnS2 nanosheets (374 mAh/g) and bare SnO2 hollow spheres (177 mAh/g). Such significantly improved electrochemical performance can be attributed to the unique hierarchical hollow structure, which not only effectively alleviates the stress resulting from the lithiation/delithiation process and maintaining structural stability during cycling but also reduces aggregation and facilitates ion transport. This work thus demonstrates the great potential of hierarchical SnO2@SnS2@rGO nanocomposites for applications as a high-performance anode material in next-generation lithium ion battery technology.

Novel diagnostics for warm dense matter: application to shock compressed target; Nouveaux diagnostics pour l'etude de la matiere dense et chaude: application aux cibles comprimees par choc laser

Energy Technology Data Exchange (ETDEWEB)

Ravasio, A

2007-03-15

In this work, we present 3 novel diagnostics for warm dense plasma (WDM) investigations: hard X-ray radiography, proton radiography and X-ray Thomson scattering. Each of these techniques is applied in shock compression experiments. The main objective consists in accessing a new parameter, in addition to shock and particle velocity, for EOS (Equation of State) measurements. In the first chapter we give a deep description of WDM states as strongly coupled and Fermi degenerate states. Then, we introduce how we have generated a WDM state in our experiment: the shock wave. We, in particular, illustrate its formation in the classical laser-matter interaction regime. In the second chapter the principles of standard probing techniques are presented. We see that energetic probe sources are necessary to investigate high Z dense plasmas. The third chapter is dedicated to X-ray radiography results. We report on a first direct density measurement of a shock compressed high Z target using K{alpha} hard X-ray radiation. These results are of great interests as they allow an in-situ characterization of high Z material, impossible with standard techniques. We show that probing a well known material as Al will allow the comparison between our data and the results from already validated simulations. In the fourth chapter, we present the results obtained from proton radiography on low density carbon foam. The data analysis will require the development of a specific Monte-Carlo code to simulate the proton propagation through the shocked target. The comparison of the simulations with the experimental data show a low dependency on density. The fifth chapter is devoted to X-ray Thomson scattering results. For the first time, we have performed collective x-ray Thomson scattering measurement from a shock compressed target, accessing to electron density and temperature. The obtained results are compared with simulated x-ray scattered spectra. The novel technique is then used in the

In situ 119Sn Moessbauer spectroscopy used to study lithium insertion in c-Mg2Sn

International Nuclear Information System (INIS)

Aldon, L.; Ionica, C. M.; Lippens, P. E.; Larcher, D.; Tarascon, J.-M.; Olivier-Fourcade, J.; Jumas, J.-C.

2006-01-01

The electrochemical reactions of Li with c-Mg 2 Sn have been investigated by in situ Moessbauer spectroscopy of 119 Sn and X-ray diffraction. The lithiation transforms initially c-Mg 2 Sn part into Li x Mg 2 Sn alloy (x 2 MgSn ternary alloy. In situ Moessbauer spectroscopy provides valuable information on local environment of tin and swelling behavior and cracking of the particles during discharge and charge processes.

Heat shock-induced interactions among nuclear HSFs detected by fluorescence cross-correlation spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Pack, Chan-Gi, E-mail: changipack@amc.seoul.kr [Asan Institute for Life Sciences, University of Ulsan, College of Medicine, Asan Medical Center, Seoul 138-736 (Korea, Republic of); Ahn, Sang-Gun [Dept. of Pathology, College of Dentistry, Chosun University, Seosuk-dong, Dong-gu, Gwangju 501-759 (Korea, Republic of)

2015-07-31

The cellular response to stress is primarily controlled in cells via transcriptional activation by heat shock factor 1 (HSF1). HSF1 is well-known to form homotrimers for activation upon heat shock and subsequently bind to target DNAs, such as heat-shock elements, by forming stress granules. A previous study demonstrated that nuclear HSF1 and HSF2 molecules in live cells interacted with target DNAs on the stress granules. However, the process underlying the binding interactions of HSF family in cells upon heat shock remains unclear. This study demonstrate for the first time that the interaction kinetics among nuclear HSF1, HSF2, and HSF4 upon heat shock can be detected directly in live cells using dual color fluorescence cross-correlation spectroscopy (FCCS). FCCS analyses indicated that the binding between HSFs was dramatically changed by heat shock. Interestingly, the recovery kinetics of interaction between HSF1 molecules after heat shock could be represented by changes in the relative interaction amplitude and mobility. - Highlights: • The binding interactions among nuclear HSFs were successfully detected. • The binding kinetics between HSF1s during recovery was quantified. • HSF2 and HSF4 strongly formed hetero-complex, even before heat shock. • Nuclear HSF2 and HSF4 bound to HSF1 only after heat shock.

ATF1 Modulates the Heat Shock Response by Regulating the Stress-Inducible Heat Shock Factor 1 Transcription Complex

Science.gov (United States)

Takii, Ryosuke; Fujimoto, Mitsuaki; Tan, Ke; Takaki, Eiichi; Hayashida, Naoki; Nakato, Ryuichiro; Shirahige, Katsuhiko

2014-01-01

The heat shock response is an evolutionally conserved adaptive response to high temperatures that controls proteostasis capacity and is regulated mainly by an ancient heat shock factor (HSF). However, the regulation of target genes by the stress-inducible HSF1 transcription complex has not yet been examined in detail in mammalian cells. In the present study, we demonstrated that HSF1 interacted with members of the ATF1/CREB family involved in metabolic homeostasis and recruited them on the HSP70 promoter in response to heat shock. The HSF1 transcription complex, including the chromatin-remodeling factor BRG1 and lysine acetyltransferases p300 and CREB-binding protein (CBP), was formed in a manner that was dependent on the phosphorylation of ATF1. ATF1-BRG1 promoted the establishment of an active chromatin state and HSP70 expression during heat shock, whereas ATF1-p300/CBP accelerated the shutdown of HSF1 DNA-binding activity during recovery from acute stress, possibly through the acetylation of HSF1. Furthermore, ATF1 markedly affected the resistance to heat shock. These results revealed the unanticipated complexity of the primitive heat shock response mechanism, which is connected to metabolic adaptation. PMID:25312646

The European Nb3Sn advanced strand development programme

International Nuclear Information System (INIS)

Vostner, A.; Salpietro, E.

2005-01-01

Strands relevant for fusion with high critical current densities and moderate hysteresis losses were developed and already produced on industrial scale. Based on these achievements EFDA-CSU Garching has launched a Nb 3 Sn strand development and procurement action inside Europe in order to assess the current status of the Nb 3 Sn strand production capability. All six addressed companies have replied positively to the strand R and D programme which includes the three major Nb 3 Sn production techniques namely the bronze, internal-tin and powder-in-tube (PIT) route. According to the strand requirements for the ITER TF conductor a critical current density of 800 A/mm 2 (at 12 T, 4.2 K and 10 μV/m) and overall strand hysteresis losses below 500 kJ/m 3 have been specified as the minimum guaranteed strand performance. The second major objective of this programme is to motivate the strand manufacturers to develop and design high performance Nb 3 Sn strands optimised for the ITER conductor. For this purpose, a target critical current density of 1100 A/mm 2 has been added to the specification. This paper describes the strategy behind the strand development programme, the actual status of the strand production as well as first preliminary results obtained from the strand suppliers

Characterization of amorphous multilayered ZnO-SnO2 heterostructure thin films and their field effect electronic properties

International Nuclear Information System (INIS)

Lee, Su-Jae; Hwang, Chi-Sun; Pi, Jae-Eun; Yang, Jong-Heon; Oh, Himchan; Cho, Sung Haeng; Cho, Kyoung-Ik; Chu, Hye Yong

2014-01-01

Multilayered ZnO-SnO 2 heterostructure thin films were produced using pulsed laser ablation of pie-shaped ZnO-SnO 2 oxides target, and their structural and field effect electronic transport properties were investigated as a function of the thickness of the ZnO and SnO 2 layers. The films have an amorphous multilayered heterostructure composed of the periodic stacking of the ZnO and SnO 2 layers. The field effect electronic properties of amorphous multilayered ZnO-SnO 2 heterostructure thin film transistors (TFTs) are highly dependent on the thickness of the ZnO and SnO 2 layers. The highest electron mobility of 37 cm 2 /V s, a low subthreshold swing of a 0.19 V/decade, a threshold voltage of 0.13 V, and a high drain current on-to-off ratio of ∼10 10 obtained for the amorphous multilayered ZnO(1.5 nm)-SnO 2 (1.5 nm) heterostructure TFTs. These results are presumed to be due to the unique electronic structure of an amorphous multilayered ZnO-SnO 2 heterostructure film consisting of ZnO, SnO 2 , and ZnO-SnO 2 interface layers

Theoretical and experimental investigation of the Z pinch plasma as a source of power pulse of soft X radiation for generation of shock waves in condensed targets

International Nuclear Information System (INIS)

Grabovskij, E.V.; Smirnov, V.P.; Zakharov, S.V.; Vorob'ev, O.Yu.; Dyabilin, K.S.; Lebedev, M.E.; Fortov, V.E.; Frolov, A.A.

1996-01-01

Paper presents the results of theoretical analysis of processes occurring in Z-pinch plasma under conditions initiating a powerful pulse of soft X-radiation. The main attention is focused on double liner circuit designs. Estimations of power of radiation and spectrum are studied. The results are used to simulate processes occurring at generation of shock waves under the effect of soft X-radiation on the target. Experiments to generate shock waves with up to 3 Mbar amplitude pressure in lead under the effect of soft X-radiation were conducted using Angara-5 plant. 24 refs., 9 figs

Stable and metastable equilibria in PbSe + SnI2=SnSe + PbI2

International Nuclear Information System (INIS)

Odin, I.N.; Grin'ko, V.V.; Kozlovskij, V.F.; Demidova, E.D.

2003-01-01

T-x-y phase diagrams of the PbSe + SnI 2 =SnSe + PbI 2 mutual system (stable states) are plotted for the first time. It is shown that melt, solid solutions on the base of components of the mutual system and phase on the base of Sn 2 SeI 4 take part in phase equilibria. Transformations in the PbSe + SnI 2 =SnSe + PbI 2 mutual system leading to crystallization of metastable polytype modifications of lead iodides and metastable ternary compound forming in PbSe-PbI 2 system are investigated for the first time [ru

Shock-timing experiments for Inertial Confinement Fusion

International Nuclear Information System (INIS)

Debras, G.

2012-01-01

The Laser Megajoule (LMJ), which should achieve energy gain in an indirect drive inertial confinement fusion configuration, is being built in France by the CEA (Commissariat a l'Energie Atomique et aux Energies Alternatives). To achieve thermonuclear ignition, the compression of a spherical target will have to be controlled by a series of accurately timed centripetal shocks, with a finely tuned level. A first experiment, performed in 2010 on the LIL (Ligne d'Integration Laser) facility at CEA, has allowed us to study the coalescence of two planar shocks in an indirectly-driven sample of polystyrene, within the framework of shock timing. The main objectives were to validate the experimental concept and the numerical simulations, as a proof-of-principle for future shock-timing campaigns. The main diagnostics used for this study are VISAR (Velocity Interferometer System for Any Reflection) and an optical shock breakout diagnostic, taking into account optical perturbations caused by X-rays. In another experiment, conducted on the LULI (Laboratoire pour l'Utilisation des Lasers Intenses) laser facility in 2010, we studied the timing of two planar directly-driven shocks using the same diagnostics. This latter study is related to the shock ignition concept, with the long-term perspective of energy production. This thesis presents these two experiments and their results. (author) [fr

Band Alignments, Valence Bands, and Core Levels in the Tin Sulfides SnS, SnS2, and Sn2S3: Experiment and Theory

OpenAIRE

Whittles, TJ; Burton, LA; Skelton, JM; Walsh, A; Veal, TD; Dhanak, VR

2016-01-01

Tin sulfide solar cells show relatively poor efficiencies despite attractive photovoltaic properties, and there is difficulty in identifying separate phases, which are also known to form during Cu2ZnSnS4 depositions. We present X-ray photoemission spectroscopy (XPS) and inverse photoemission spectroscopy measurements of single crystal SnS, SnS2, and Sn2S3, with electronic-structure calculations from density functional theory (DFT). Differences in the XPS spectra of the three phases, including...

Comparative study of SnS recrystallization in molten CdI{sub 2}, SnCl{sub 2}and KI

Energy Technology Data Exchange (ETDEWEB)

Timmo, Kristi; Kauk-Kuusik, Marit; Pilvet, Maris; Mikli, Valdek; Kaerber, Erki; Raadik, Taavi; Leinemann, Inga; Altosaar, Mare; Raudoja, Jaan [Department of Materials Science, Tallinn University of Technology, Tallinn (Estonia)

2016-01-15

In the present study, the recrystallization of polycrystalline SnS in different molten salts CdI{sub 2}, SnCl{sub 2} and KI as flux materials are presented. The recrystallization and growth of polycrystalline material in molten salts produces unique SnS monograin powders usable in monograin layer solar cells. XRD and Raman analysis revealed that single phase SnS powder can be obtained in KI at 740 C and in SnCl{sub 2} at 500 C. Long time heating of SnS in molten CdI{sub 2} was accompanied by chemical interaction between SnS and CdI{sub 2} that resulted in a mixture of CdS and Sn{sub 2}S{sub 3} crystals. SEM images showed that morphology of crystals can be controlled by the nature of the flux materials: needle-like Sn{sub 2}S{sub 3} together with round edged crystals of CdS in CdI{sub 2}, flat crystals of SnS with smooth surfaces in SnCl{sub 2} and well-formed SnS crystals with rounded edges in KI had been formed. The temperatures of phase transitions and/or the interactions of SnS and flux materials were determined by differential thermal analysis. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

PROTEUS-SN User Manual

Energy Technology Data Exchange (ETDEWEB)

Shemon, Emily R. [Argonne National Lab. (ANL), Argonne, IL (United States); Smith, Micheal A. [Argonne National Lab. (ANL), Argonne, IL (United States); Lee, Changho [Argonne National Lab. (ANL), Argonne, IL (United States)

2016-02-16

PROTEUS-SN is a three-dimensional, highly scalable, high-fidelity neutron transport code developed at Argonne National Laboratory. The code is applicable to all spectrum reactor transport calculations, particularly those in which a high degree of fidelity is needed either to represent spatial detail or to resolve solution gradients. PROTEUS-SN solves the second order formulation of the transport equation using the continuous Galerkin finite element method in space, the discrete ordinates approximation in angle, and the multigroup approximation in energy. PROTEUS-SN’s parallel methodology permits the efficient decomposition of the problem by both space and angle, permitting large problems to run efficiently on hundreds of thousands of cores. PROTEUS-SN can also be used in serial or on smaller compute clusters (10’s to 100’s of cores) for smaller homogenized problems, although it is generally more computationally expensive than traditional homogenized methodology codes. PROTEUS-SN has been used to model partially homogenized systems, where regions of interest are represented explicitly and other regions are homogenized to reduce the problem size and required computational resources. PROTEUS-SN solves forward and adjoint eigenvalue problems and permits both neutron upscattering and downscattering. An adiabatic kinetics option has recently been included for performing simple time-dependent calculations in addition to standard steady state calculations. PROTEUS-SN handles void and reflective boundary conditions. Multigroup cross sections can be generated externally using the MC2-3 fast reactor multigroup cross section generation code or internally using the cross section application programming interface (API) which can treat the subgroup or resonance table libraries. PROTEUS-SN is written in Fortran 90 and also includes C preprocessor definitions. The code links against the PETSc, METIS, HDF5, and MPICH libraries. It optionally links against the MOAB library and

HST-COS Observations on Hydrogen, Helium, Carbon, and Nitrogen Emission from the SN 1987A Reverse Shock

Science.gov (United States)

France, Kevin; McCray, Richard; Penton, Steven V.; Kirshner, Robert P.; Challis, Peter; Laming, J. Martin; Bouchet, Patrice; Chevalier, Roger; Garnavich, Peter M.; Fransson, Claes;

Geometrical shock dynamics for magnetohydrodynamic fast shocks

KAUST Repository

Mostert, W.; Pullin, D. I.; Samtaney, Ravi; Wheatley, V.

2016-01-01

We describe a formulation of two-dimensional geometrical shock dynamics (GSD) suitable for ideal magnetohydrodynamic (MHD) fast shocks under magnetic fields of general strength and orientation. The resulting area–Mach-number–shock-angle relation is then incorporated into a numerical method using pseudospectral differentiation. The MHD-GSD model is verified by comparison with results from nonlinear finite-volume solution of the complete ideal MHD equations applied to a shock implosion flow in the presence of an oblique and spatially varying magnetic field ahead of the shock. Results from application of the MHD-GSD equations to the stability of fast MHD shocks in two dimensions are presented. It is shown that the time to formation of triple points for both perturbed MHD and gas-dynamic shocks increases as (Formula presented.), where (Formula presented.) is a measure of the initial Mach-number perturbation. Symmetry breaking in the MHD case is demonstrated. In cylindrical converging geometry, in the presence of an azimuthal field produced by a line current, the MHD shock behaves in the mean as in Pullin et al. (Phys. Fluids, vol. 26, 2014, 097103), but suffers a greater relative pressure fluctuation along the shock than the gas-dynamic shock. © 2016 Cambridge University Press

Geometrical shock dynamics for magnetohydrodynamic fast shocks

KAUST Repository

Mostert, W.

2016-12-12

We describe a formulation of two-dimensional geometrical shock dynamics (GSD) suitable for ideal magnetohydrodynamic (MHD) fast shocks under magnetic fields of general strength and orientation. The resulting area–Mach-number–shock-angle relation is then incorporated into a numerical method using pseudospectral differentiation. The MHD-GSD model is verified by comparison with results from nonlinear finite-volume solution of the complete ideal MHD equations applied to a shock implosion flow in the presence of an oblique and spatially varying magnetic field ahead of the shock. Results from application of the MHD-GSD equations to the stability of fast MHD shocks in two dimensions are presented. It is shown that the time to formation of triple points for both perturbed MHD and gas-dynamic shocks increases as (Formula presented.), where (Formula presented.) is a measure of the initial Mach-number perturbation. Symmetry breaking in the MHD case is demonstrated. In cylindrical converging geometry, in the presence of an azimuthal field produced by a line current, the MHD shock behaves in the mean as in Pullin et al. (Phys. Fluids, vol. 26, 2014, 097103), but suffers a greater relative pressure fluctuation along the shock than the gas-dynamic shock. © 2016 Cambridge University Press

GeSn growth kinetics in reduced pressure chemical vapor deposition from Ge2H6 and SnCl4

Science.gov (United States)

Aubin, J.; Hartmann, J. M.

2018-01-01

We have investigated the low temperature epitaxy of high Sn content GeSn alloys in a 200 mm industrial Reduced Pressure - Chemical Vapor Deposition tool from Applied Materials. Gaseous digermane (Ge2H6) and liquid tin tetrachloride (SnCl4) were used as the Ge and Sn precursors, respectively. The impact of temperature (in the 300-350 °C range), Ge2H6 and SnCl4 mass-flows on the GeSn growth kinetics at 100 Torr has been thoroughly explored. Be it at 300 °C or 325 °C, a linear GeSn growth rate increase together with a sub-linear Sn concentration increase occurred as the SnCl4 mass-flow increased, irrespective of the Ge2H6 mass flow (fixed or varying). The Sn atoms seemed to catalyze H desorption from the surface, resulting in higher GeSn growth rates for high SnCl4 mass-flows (in the 4-21 nm min-1 range). The evolution of the Sn content x with the F (SnCl4) 2 ·/F (Ge2H6) mass-flow ratio was fitted by x2/(1 - x) = n ·F (SnCl4) 2 ·/F (Ge2H6), with n = 0.25 (325 °C) and 0.60 (300 °C). We have otherwise studied the impact of temperature, in the 300-350 °C range, on the GeSn growth kinetics. The GeSn growth rate exponentially increased with the temperature, from 15 up to 32 nm min-1. The associated activation energy was low, i.e. Ea = 10 kcal mol-1. Meanwhile, the Sn content decreased linearly as the growth temperature increased, from 15% at 300 °C down to 6% at 350 °C.

HPLC method for determination of SN-38 content and SN-38 entrapment efficiency in a novel liposome-based formulation, LE-SN38.

Science.gov (United States)

Xuan, Tong; Zhang, J Allen; Ahmad, Imran

2006-05-03

A simple HPLC method was developed for quantification of SN-38, 7-ethyl-10-hydroxycamptothecin, in a novel liposome-based formulation (LE-SN38). The chromatographic separation was achieved on an Agilent Zorbax SB-C18 (4.6 mmx250 mm, 5 microm) analytical column using a mobile phase consisting of a mixture of NaH2PO4 (pH 3.1, 25 mM) and acetonitrile (50:50, v/v). SN-38 was detected at UV wavelength of 265 nm and quantitatively determined using an external calibration method. The limit of detection (LOD) and limit of quantitation (LOQ) were found to be 0.05 and 0.25 microg/mL, respectively. The individual spike recovery of SN-38 ranged from 100 to 101%. The percent of relative standard deviation (%R.S.D.) of intra-day and inter-day analyses were less than 1.6%. The method validation results confirmed that the method is specific, linear, accurate, precise, robust and sensitive for its intended use. The current method was successfully applied to the determination of SN-38 content and drug entrapment efficiency in liposome-based formulation, LE-SN38 during early stage formulation development.

Differential Targeting of Hsp70 Heat Shock Proteins HSPA6 and HSPA1A with Components of a Protein Disaggregation/Refolding Machine in Differentiated Human Neuronal Cells following Thermal Stress

Directory of Open Access Journals (Sweden)

Ian R. Brown

2017-04-01

Full Text Available Heat shock proteins (Hsps co-operate in multi-protein machines that counter protein misfolding and aggregation and involve DNAJ (Hsp40, HSPA (Hsp70, and HSPH (Hsp105α. The HSPA family is a multigene family composed of inducible and constitutively expressed members. Inducible HSPA6 (Hsp70B' is found in the human genome but not in the genomes of mouse and rat. To advance knowledge of this little studied HSPA member, the targeting of HSPA6 to stress-sensitive neuronal sites with components of a disaggregation/refolding machine was investigated following thermal stress. HSPA6 targeted the periphery of nuclear speckles (perispeckles that have been characterized as sites of transcription. However, HSPA6 did not co-localize at perispeckles with DNAJB1 (Hsp40-1 or HSPH1 (Hsp105α. At 3 h after heat shock, HSPA6 co-localized with these members of the disaggregation/refolding machine at the granular component (GC of the nucleolus. Inducible HSPA1A (Hsp70-1 and constitutively expressed HSPA8 (Hsc70 co-localized at nuclear speckles with components of the machine immediately after heat shock, and at the GC layer of the nucleolus at 1 h with DNAJA1 and BAG-1. These results suggest that HSPA6 exhibits targeting features that are not apparent for HSPA1A and HSPA8.

Compact all-fiber interferometer system for shock acceleration measurement

Science.gov (United States)

Zhao, Jiang; Pi, Shaohua; Hong, Guangwei; Zhao, Dong; Jia, Bo

2013-08-01

Acceleration measurement plays an important role in a variety of fields in science and engineering. In particular, the accurate, continuous and non-contact recording of the shock acceleration profiles of the free target surfaces is considered as a critical technique in shock physics. Various kinds of optical interferometers have been developed to monitor the motion of the surfaces of shocked targets since the 1960s, for instance, the velocity interferometer system for any reflector, the fiber optic accelerometer, the photonic Doppler velocimetry system and the displacement interferometer. However, most of such systems rely on the coherent quasi-monochromatic illumination and discrete optic elements, which are costly in setting-up and maintenance. In 1996, L. Levin et al reported an interferometric fiber-optic Doppler velocimeter with high-dynamic range, in which fiber-coupled components were used to replace the discrete optic elements. However, the fringe visibility of the Levin's system is low because of the coupled components, which greatly limits the reliability and accuracy in the shock measurement. In this paper, a compact all-fiber interferometer system for measuring the shock acceleration is developed and tested. The advantage of the system is that not only removes the non-interfering light and enhances the fringe visibility, but also reduces polarization induced signal fading and the polarization induced phase shift. Moreover, it also does not require a source of long coherence length. The system bases entirely on single-mode fiber optics and mainly consists of a polarization beam splitter, a faraday rotator, a depolarizer and a 3×3 single-mode fiber coupler which work at 1310 nm wavelength. The optical systems of the interferometer are described and the experimental results compared with a shock acceleration calibration system with a pneumatic exciter (PneuShockTM Model 9525C by The Modal Shop) are reported. In the shock acceleration test, the

Fabrication and Characterization of Targets for Shock Propagation and Radiation Burnthrough Measurements on Be-0.9 AT. % Cu Alloy

International Nuclear Information System (INIS)

Nobile, A.; Dropinski, S.C.; Edwards, J.M.; Rivera, G.; Margevicius, R.W.; Sebring, R.J.; Olson, R. E.; Tanner, D.L.

2004-01-01

Beryllium-copper alloy (Be0.9%Cu) ICF capsules are being developed for the pursuit of thermonuclear ignition at the National Ignition Facility (NIF). Success of this capsule material requires that its shock propagation and radiation burnthrough characteristics be accurately understood. To this end, experiments are being conducted to measure the shock propagation and radiation burnthrough properties of Be0.9%Cu alloy. These experiments involve measurements on small Be0.9%Cu wedge, step and flat samples. Samples are mounted on 1.6-mm-diameter x 1.2-mm-length hohlraums that are illuminated by the OMEGA laser at the University of Rochester. X-rays produced by the hohlraum drive the sample. A streaked optical pyrometer detects breakout of the shock produced by the X-ray pulse. In this paper we describe synthesis of the alloy material, fabrication and characterization of samples, and assembly of the targets. Samples were produced from Be0.9%Cu alloy that was synthesized by hot isostatic pressing of Be powder and copper flake. Samples were 850 μm diameter disks with varying thickness in the case of wedge and step samples, and uniform thickness in the case of flat samples. Sample thickness varied in the range 10-90 μm. Samples were prepared by precision lathe machining and electric discharge machining. The samples were characterized by a Veeco white light interferometer and an optical thickness measurement device that simultaneously measured the upper and lower surface contours of samples using two confocal laser probes. Several campaigns with these samples have been conducted over the past two years

Gain curves and hydrodynamic modeling for shock ignition

International Nuclear Information System (INIS)

Lafon, M.; Ribeyre, X.; Schurtz, G.

2010-01-01

Ignition of a precompressed thermonuclear fuel by means of a converging shock is now considered as a credible scheme to obtain high gains for inertial fusion energy. This work aims at modeling the successive stages of the fuel time history, from compression to final thermonuclear combustion, in order to provide the gain curves of shock ignition (SI). The leading physical mechanism at work in SI is pressure amplification, at first by spherical convergence, and by collision with the shock reflected at center during the stagnation process. These two effects are analyzed, and ignition conditions are provided as functions of the shock pressure and implosion velocity. Ignition conditions are obtained from a non-isobaric fuel assembly, for which we present a gain model. The corresponding gain curves exhibit a significantly lower ignition threshold and higher target gains than conventional central ignition.

In Situ High-Resolution Transmission Electron Microscopy (TEM) Observation of Sn Nanoparticles on SnO2 Nanotubes Under Lithiation.

Science.gov (United States)

Cheong, Jun Young; Chang, Joon Ha; Kim, Sung Joo; Kim, Chanhoon; Seo, Hyeon Kook; Shin, Jae Won; Yuk, Jong Min; Lee, Jeong Yong; Kim, Il-Doo

2017-12-01

We trace Sn nanoparticles (NPs) produced from SnO2 nanotubes (NTs) during lithiation initialized by high energy e-beam irradiation. The growth dynamics of Sn NPs is visualized in liquid electrolytes by graphene liquid cell transmission electron microscopy. The observation reveals that Sn NPs grow on the surface of SnO2 NTs via coalescence and the final shape of agglomerated NPs is governed by surface energy of the Sn NPs and the interfacial energy between Sn NPs and SnO2 NTs. Our result will likely benefit more rational material design of the ideal interface for facile ion insertion.

Early time implosion symmetry from two-axis shock-timing measurements on indirect drive NIF experiments

Energy Technology Data Exchange (ETDEWEB)

Moody, J. D., E-mail: moody4@llnl.gov; Robey, H. F.; Celliers, P. M.; Munro, D. H.; Barker, D. A.; Baker, K. L.; Döppner, T.; Hash, N. L.; Berzak Hopkins, L.; LaFortune, K.; Landen, O. L.; LePape, S.; MacGowan, B. J.; Ralph, J. E.; Ross, J. S.; Widmayer, C. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Nikroo, A.; Giraldez, E. [General Atomics, San Diego, California 92186-5608 (United States); Boehly, T. [Laboratory for Laser Energetics, Rochester, New York 14623-1299 (United States)

2014-09-15

An innovative technique has been developed and used to measure the shock propagation speed along two orthogonal axes in an inertial confinement fusion indirect drive implosion target. This development builds on an existing target and diagnostic platform for measuring the shock propagation along a single axis. A 0.4 mm square aluminum mirror is installed in the ablator capsule which adds a second orthogonal view of the x-ray-driven shock speeds. The new technique adds capability for symmetry control along two directions of the shocks launched in the ablator by the laser-generated hohlraum x-ray flux. Laser power adjustments in four different azimuthal cones based on the results of this measurement can reduce time-dependent symmetry swings during the implosion. Analysis of a large data set provides experimental sensitivities of the shock parameters to the overall laser delivery and in some cases shows the effects of laser asymmetries on the pole and equator shock measurements.

Lithium insertion mechanism in SnS2

International Nuclear Information System (INIS)

Lefebvre-Devos, I.; Olivier-Fourcade, J.; Jumas, J.C.; Lavela, P.

2000-01-01

We study lithium insertion in SnS 2 by means of 119 Sn Moessbauer spectroscopy, x-ray absorption spectroscopy at Sn L I,III , and S K edges, and theoretical electronic structures (calculated in the density-functional theory framework). An insertion mechanism is derived according to the Li amount. It shows the influence of the SnS 2 -layered structure on the Sn reduction, particularly the possibility of an intermediate oxidation state between Sn IV and Sn II , which is not observed during Li insertion in three-dimensional sulfides

Sandwich-like C@SnO2/Sn/void@C hollow spheres as improved anode materials for lithium ion batteries

Science.gov (United States)

Wang, Huijun; Jiang, Xinya; Chai, Yaqin; Yang, Xia; Yuan, Ruo

2018-03-01

As lithium ion batteries (LIBs) anode, SnO2 suffers fast capacity fading due to its large volume expansion during discharge/charge process. To overcome the problem, sandwich-like C@SnO2/Sn/void@C hollow spheres (referred as C@SnO2/Sn/void@C HSs) are prepared by in-situ polymerization and carbonization, using hollow SnO2 as self-template and dopamine as carbon source. The C@SnO2/Sn/void@C HSs possesses the merits of hollow and core/void/shell structure, so that they can accommodate the volume change under discharge/charge process, shorten the transmission distance of Li ions, own more contact area for the electrolyte. Thanks to these advantages, C@SnO2/Sn/void@C HSs display excellent electrochemical performance as anode materials for LIBs, which deliver a high capacity of 786.7 mAh g-1 at the current density of 0.5 A g-1 after 60 cycles. The simple synthesis method for C@SnO2/Sn/void@C HSs with special structure will provide a promising method for preparing other anode materials for LIBs.

Centrifugal extraction of highly enriched tin isotopes and increase of specific activity of the radionuclide 119mSn on the gas centrifuge cascade

International Nuclear Information System (INIS)

Suvorov, I.A.; Tcheltsov, A.N.; Sosnin, L.Yu.; Sazikin, A.A.; Rudnev, A.I.

2002-01-01

This work contains the results of research on centrifugal enrichment of 118 Sn isotope followed by irradiation and, finally, a second centrifugal enrichment to produce high specific activity 119m Sn. Non-steady-state separation methods were used for the effective extraction of the radionuclide 119m Sn from the irradiated target. As a result of this work, radiation sources based on 119m Sn were obtained with a specific activity of 500 mCi/g. This is 100 times greater than the specific activity obtained after irradiation in the reactor alone. In addition, the sources had an previously unattainable radio-purity ratio of 113 Sn/ 119m Sn of approximately 10 -6

Sn surface-enriched Pt-Sn bimetallic nanoparticles as a selective and stable catalyst for propane dehydrogenation

KAUST Repository

Zhu, Haibo

2014-12-01

A new one pot, surfactant-free, synthetic route based on the surface organometallic chemistry (SOMC) concept has been developed for the synthesis of Sn surface-enriched Pt-Sn nanoparticles. Bu3SnH selectively reacts with [Pt]-H formed in situ at the surface of Pt nanoparticles, Pt NPs, obtained by reduction of K2PtCl4 by LiB(C2H5)3H. Chemical analysis, 1H MAS and 13C CP/MAS solid-state NMR as well as two-dimensional double-quantum (DQ) and triple-quantum (TQ) experiments show that organo-tin moieties Sn(n-C4H9) are chemically linked to the surface of Pt NPs to produce, in fine, after removal of most of the n-butyl fragment, bimetallic Pt-Sn nanoparticles. The Sn(n-CH2CH2CH2CH3) groups remaining at the surface are believed to stabilize the as-synthesized Pt-Sn NPs, enabling the bimetallic NPs to be well dispersed in THF. Additionally, the Pt-Sn nanoparticles can be supported on MgAl2O4 during the synthesis of the nanoparticles. Some of the Pt-Sn/MgAl2O4 catalyst thus prepared exhibits high activity in PROX of CO and an extremely high selectivity and stability in propane dehydrogenation to propylene. The enhanced activity in propane dehydrogenation is associated with the high concentration of inactive Sn at the surface of Pt nanoparticles which ”isolates” the active Pt atoms. This conclusion is confirmed by XRD, NMR, TEM, and XPS analysis.

Shock compression profiles in ceramics

Energy Technology Data Exchange (ETDEWEB)

Grady, D.E.; Moody, R.L.

1996-03-01

An investigation of the shock compression properties of high-strength ceramics has been performed using controlled planar impact techniques. In a typical experimental configuration, a ceramic target disc is held stationary, and it is struck by plates of either a similar ceramic or by plates of a well-characterized metal. All tests were performed using either a single-stage propellant gun or a two-stage light-gas gun. Particle velocity histories were measured with laser velocity interferometry (VISAR) at the interface between the back of the target ceramic and a calibrated VISAR window material. Peak impact stresses achieved in these experiments range from about 3 to 70 GPa. Ceramics tested under shock impact loading include: Al{sub 2}O{sub 3}, AlN, B{sub 4}C, SiC, Si{sub 3}N{sub 4}, TiB{sub 2}, WC and ZrO{sub 2}. This report compiles the VISAR wave profiles and experimental impact parameters within a database-useful for response model development, computational model validation studies, and independent assessment of the physics of dynamic deformation on high-strength, brittle solids.

Microstructural investigation and SnO nanodefects in spray-pyrolyzed SnO2 thin films

DEFF Research Database (Denmark)

Thanachayanont, Chanchana; Yordsri, Visittapong; Boothroyd, Chris

2011-01-01

Spray pyrolysis is one of the most cost-effective methods to prepare SnO2 films due to its ability to deposit large uniform area, low fabrication cost, simplicity and low deposition temperature. Conventionally, scanning electron microscopy (SEM) and X-Ray Diffraction (XRD) are routinely used...... diffraction (CBED). It was found that large grain-size vertically-aligned columnar SnO2 grains were formed after a few layers of small grain-size randomly oriented SnO2 grains. Moreover, CBED showed the presence of SnO nanodefects that had not been reported before and could not be detected by SEM or XRD....

Fluid sensitive nanoscale switching with quantum levitation controlled by $\\alpha$-Sn/$\\beta$-Sn phase transition

OpenAIRE

Boström, Mathias; Dou, Maofeng; Malyi, Oleksandr I.; Parashar, Prachi; Parsons, Drew F.; Brevik, Iver; Persson, Clas

2018-01-01

We analyze the Lifshitz pressure between silica and tin separated by a liquid mixture of bromobenzene and chlorobenzene. We show that the phase transition from semimetallic α−Sn to metallic β−Sn can switch Lifshitz forces from repulsive to attractive. This effect is caused by the difference in dielectric functions of α−Sn and β−Sn, giving both attractive and repulsive contributions to the total Lifshitz pressure in different frequency regions controlled by the composition of the intervening l...

Analytical criterion for shock ignition of fusion reaction in hot spot

OpenAIRE

Ribeyre X.; Tikhonchuk V.T.; Breil J.; Lafon M.; Vallet A.; Bel E. Le

2013-01-01

Shock ignition of DT capsules involves two major steps. First, the fuel is assembled by means of a low velocity conventional implosion. At stagnation, the central core has a temperature lower than the one needed for ignition. Then a second, strong spherical converging shock, launched from a high intensity laser spike, arrives to the core. This shock crosses the core, rebounds at the target center and increases the central pressure to the ignition conditions. In this work we consider this latt...

Laser shocks: A tool for experimental simulation of damage into materials

Energy Technology Data Exchange (ETDEWEB)

Boustie, M.; Cuq Lelandais, J. P.; Berthe, L.; Ecault, R. [Institut PPRIME, Departement Physique et Mecanique des Materiaux, CNRS-ENSMA-Universite de Poitiers, 1 av Clement Ader, 86961 FUTUROSCOPE Cedex (France); CEA-DAM Valduc, 21120 Is-sur-Tille (France); Laboratoire Procedes et Ingenierie en Mecanique et Materiaux (CNRS), Arts et Metiers ParisTech, 151 bd de l' Hopital, 75013 PARIS (France); Institut PPRIME, Departement Physique et Mecanique des Materiaux, CNRS-ENSMA-Universite de Poitiers, 1 av Clement Ader, 86961 FUTUROSCOPE Cedex (France)

2012-07-30

High power laser irradiation of solids results in a strong shock wave propagation, driving very high amplitude pressure loadings with very short durations. These particular characteristics offer the possibility to study the behaviour of matter under extreme dynamic conditions in continuity with what is possible with the conventional generators of shock (launchers of projectiles, explosives). An advantage of laser shocks is a possible recovery of the shocked samples presenting the metallurgical effects of the shock in most cases. We introduce the principle of the laser shock generation, the characterization of these shocks, the principal mechanisms and effects associated with their propagation in the solids. We show how laser shocks can be a laboratory tool for simulating shock effects at ultra high strain rate, providing a high in information experimental layout for validation of damage modelling on an extended strain rate range compared to conventional shock generators. New data have been obtained with ultra short femtosecond range irradiation. Experimental data gathered through post mortem observation, time resolved velocity measurement are shown along with numerical associated simulations, showing the possibility to predict the damage behaviour of metallic targets under extreme strain rate up to 10{sup 8} s{sup -1}.

Overview and recent progress of the Magnetized Shock Experiment (MSX)

Science.gov (United States)

Weber, T. E.; Intrator, T. P.; Smith, R. J.; Hutchinson, T. M.; Boguski, J. C.; Sears, J. A.; Swan, H. O.; Gao, K. W.; Chapdelaine, L. J.; Winske, D.; Dunn, J. P.

2013-10-01

The Magnetized Shock Experiment (MSX) has been constructed to study the physics of super-Alfvènic, supercritical, magnetized shocks. Exhibiting transitional length and time scales much smaller than can be produced through collisional processes, these shocks are observed to create non-thermal distributions, amplify magnetic fields, and accelerate particles to relativistic velocities. Shocks are produced through the acceleration and subsequent stagnation of Field Reversed Configuration (FRC) plasmoids against a high-flux magnetic mirror with a conducting boundary or a plasma target with embedded field. Adjustable shock velocity, density, and magnetic geometry (B parallel, perpendicular, or oblique to k) provide unique access to a wide range of dimensionless parameters relevant to astrophysical shocks. Information regarding the experimental configuration, diagnostics suite, recent simulations, experimental results, and physics goals will be presented. This work is supported by DOE OFES and NNSA under LANS contract DE-AC52-06NA25369 Approved for Public Release: LA-UR-13-24859.

99mTc bone scanning agents preparation and chemical analysis of Tc(Sn)pyrophosphate, Tc(Sn)MDP and Tc(Sn)HMDP

International Nuclear Information System (INIS)

Kroesbergen, J.

1986-01-01

This thesis describes a comparison of the preparation, composition and properties of three bone scanning agents: 99m Tc(Sn)pyrophosphate, 99m Tc(Sn)MDP and 99m Tc(Sn)HMDP. This study has been performed for two reasons: First to investigate the preparation and composition of the radiopharmaceuticals as a function of experimental conditions. Together with previously reported results for 99m Tc(Sn)EHDP, obtained in a similar way, this enables to use well-defined preparations of the bone scanning agents. Secondly to gain an insight in the mechanism in which the agents behave 'in vivo'. Because the 'in vivo' process is too complicated to study directly, it seemed more appropriate to perform 'in vitro' investigations as simplifications of the 'in vivo' situation. 304 refs.; 26 figs.; 31 tabs

Optical diagnostics on the Magnetized Shock Experiment (MSX)

Science.gov (United States)

Boguski, J. C.; Weber, T. E.; Intrator, T. P.; Smith, R. J.; Dunn, J. P.; Hutchinson, T. M.; Gao, K. W.

2013-10-01

The Magnetized Shock Experiment (MSX) at Los Alamos National Laboratory was built to investigate the physics of high Alfvén Mach number, supercritical, magnetized shocks through the acceleration and subsequent stagnation of a Field Reversed Configuration (FRC) plasmoid against a magnetic mirror and/or plasma target. A suite of optical diagnostics has recently been fielded on MSX to characterize plasma conditions during the formation, acceleration, and stagnation phases of the experiment. CCD-backed streak and framing cameras, and a fiber-based visible light array, provide information regarding FRC shape, velocity, and instability growth. Time-resolved narrow and broadband spectroscopy provides information on pre-shock plasma temperature, impurity levels, shock location, and non-thermal ion distributions within the shock region. Details of the diagnostic design, configuration, and characterization will be presented along with initial results. This work is supported by the Center for Magnetic Self Organization, DoE OFES and NNSA under LANS contract DE-AC52-06NA25369. Approved for public release: LA-UR- 13-25190.

A general protocol for the synthesis of Pt-Sn/C catalysts for the ethanol electrooxidation reaction

Energy Technology Data Exchange (ETDEWEB)

Liu, B.; Lee, Z.Y.; Cheng, C.H.; Lee, J.Y. [Chemical and Biomolecular Engineering, National University of Singapore (Singapore); Chia, Z.W. [NUS Graduate School for Integrative Sciences and Engineering (NGS), Centre for Life Sciences (CeLS), Singapore (Singapore); Liu, Z.L. [Institute of Materials Research and Engineering, 3 Research Link, Singapore 117602 (Singapore)

2012-08-15

A general protocol for the synthesis of Pt-Sn/C catalysts for ethanol electrooxidation by the polyol method is developed after a systematic variation of the preparation variables. This protocol enables the complete transfer of all catalytic elements in the preparation solution to the catalyst support; thereby providing a convenient means of catalyst composition control. Water is a necessary co-solvent for ethylene glycol in the polyol synthesis of Pt-Sn/C catalysts. The best preparation medium for controlling the particle size to small sizes is 0.1 M NaOH solution in a mixture of equal volumes of water and ethylene glycol. With this medium composition Pt-Sn/C catalysts with the optimized target Pt:Sn atomic ratio of 3:1 could be expeditiously prepared for ethanol electrooxidation. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

Direct Numerical Simulation of Passive Scalar Mixing in Shock Turbulence Interaction

Science.gov (United States)

Gao, Xiangyu; Bermejo-Moreno, Ivan; Larsson, Johan

2017-11-01

Passive scalar mixing in the canonical shock-turbulence interaction configuration is investigated through shock-capturing Direct Numerical Simulations (DNS). Scalar fields with different Schmidt numbers are transported by an initially isotropic turbulent flow field passing across a nominally planar shock wave. A solution-adaptive hybrid numerical scheme on Cartesian structured grids is used, that combines a fifth-order WENO scheme near shocks and a sixth-order central-difference scheme away from shocks. The simulations target variations in the shock Mach number, M (from 1.5 to 3), turbulent Mach number, Mt (from 0.1 to 0.4, including wrinkled- and broken-shock regimes), and scalar Schmidt numbers, Sc (from 0.5 to 2), while keeping the Taylor microscale Reynolds number constant (Reλ 40). The effects on passive scalar statistics are investigated, including the streamwise evolution of scalar variance budgets, pdfs and spectra, in comparison with their temporal evolution in decaying isotropic turbulence.

SnSAG5 is an alternative surface antigen of Sarcocystis neurona strains that is mutually exclusive to SnSAG1.

Science.gov (United States)

Crowdus, Carolyn A; Marsh, Antoinette E; Saville, Willliam J; Lindsay, David S; Dubey, J P; Granstrom, David E; Howe, Daniel K

2008-11-25

Sarcocystis neurona is an obligate intracellular parasite that causes equine protozoal myeloencephalitis (EPM). Previous work has identified a gene family of paralogous surface antigens in S. neurona called SnSAGs. These surface proteins are immunogenic in their host animals, and are therefore candidate molecules for development of diagnostics and vaccines. However, SnSAG diversity exists in strains of S. neurona, including the absence of the major surface antigen gene SnSAG1. Instead, sequence for an alternative SnSAG has been revealed in two of the SnSAG1-deficient strains. Herein, we present data characterizing this new surface protein, which we have designated SnSAG5. The results indicated that the protein encoded by the SnSAG5 sequence is indeed a surface-associated molecule that has characteristics consistent with the other SAGs identified in S. neurona and related parasites. Importantly, Western blot analyses of a collection of S. neurona strains demonstrated that 6 of 13 parasite isolates express SnSAG5 as a dominant surface protein instead of SnSAG1. Conversely, SnSAG5 was not detected in SnSAG1-positive strains. One strain, which was isolated from the brain of a sea otter, did not express either SnSAG1 or SnSAG5. Genetic analysis with SnSAG5-specific primers confirmed the presence of the SnSAG5 gene in Western blot-positive strains, while also suggesting the presence of a novel SnSAG sequence in the SnSAG1-deficient, SnSAG5-deficient otter isolate. The findings provide further indication of S. neurona strain diversity, which has implications for diagnostic testing and development of vaccines against EPM as well as the population biology of Sarcocystis cycling in the opossum definitive host.

Electronic and magnetic properties of rare earth-Sn3 compounds for 119Sn Moessbauer spectroscopy

International Nuclear Information System (INIS)

Sanchez, J.P.; Friedt, J.M.; Shenoy, G.K.; Percheron, A.; Achard, J.C.

1975-01-01

The electronic and magnetic properties of RESn 3 compounds (RE=La, Ce, Pr, Nd, Sm, Eu, Gd, Yb) have been investigated using the 23.8keV Moessbauer resonance of 119 Sn. The isomer shifts and quadrupole interactions are nearly the same in all compounds. The transferred magnetic fields and their orientation with respect to the principal electric field gradient axis at various Sn sites in the magnetically ordered state of RESn 3 (RE=Pr, Nd, Sm, Eu, Gd) have been utilized to get information about the magnetic structure. An evaluation of the transferred fields in PrSn 3 and NdSn 3 shows that the spin density at the Sn nucleus is nearly the same in both compounds [fr

The tin-rich copper lithium stannides: Li3Cu6Sn4 and Li2CuSn2

International Nuclear Information System (INIS)

Fuertauer, Siegfried; Flandorfer, Hans; Effenberger, Herta S.

2015-01-01

The Sn rich ternary intermetallic compounds Li 3 Cu 6 Sn 4 (CSD-427097) and Li 2 CuSn 2 (CSD-427098) were synthesized from the pure elements by induction melting and annealing at 400 C. Structural investigations were performed by powder- and single-crystal XRD. Li 3 Cu 6 Sn 4 crystallizes in space group P6/mmm; it is structurally related to but not isotypic with MgFe 6 Ge 6 (a = 5.095(2) Aa, c = 9.524(3) Aa; wR 2 = 0.059; 239 unique F 2 -values, 17 free variables). Li 3 Cu 6 Sn 4 is characterized by two sites with a mixed Cu:Sn occupation. In contrast to all other Cu-Li-Sn compounds known so far, any mixed occupation was found for Cu-Li pairs only. In addition, one Li site is only half occupied. The second Sn rich phase is Li 2 CuSn 2 (space group I4 1 /amd, a = 4.4281(15) Aa, c = 19.416(4) Aa; wR 2 = 0.033; 213 unique F 2 -values, 12 atom free variables); it is the only phase in the Cu-Li-Sn system which is noted for full ordering. Both crystal structures exhibit 3D-networks which host Li atoms in channels. They are important for understanding the lithiation mechanism in Cu-Sn electrodes for Li-ion batteries.

SN REFSDAL: CLASSIFICATION AS A LUMINOUS AND BLUE SN 1987A-LIKE TYPE II SUPERNOVA

Energy Technology Data Exchange (ETDEWEB)

Kelly, P. L.; Filippenko, A. V.; Graham, M. L. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); Brammer, G.; Strolger, L.-G.; Riess, A. G. [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Selsing, J.; Hjorth, J.; Christensen, L. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Foley, R. J. [Department of Physics, University of Illinois at Urbana-Champaign, 1110 W. Green Street, Urbana, IL 61801 (United States); Rodney, S. A. [Department of Physics and Astronomy, University of South Carolina, 712 Main St., Columbia, SC 29208 (United States); Treu, T. [University of California, Los Angeles, CA 90095 (United States); Steidel, C. C.; Strom, A.; Zitrin, A. [California Institute of Technology, 1200 East California Boulevard, Pasadena, CA 91125 (United States); Schmidt, K. B.; McCully, C. [Department of Physics, University of California, Santa Barbara, CA 93106-9530 (United States); Bradač, M. [University of California, Davis, 1 Shields Avenue, Davis, CA 95616 (United States); Jha, S. W. [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, Piscataway, NJ 08854 (United States); Graur, O., E-mail: pkelly@astro.berkeley.edu [Center for Cosmology and Particle Physics, New York University, New York, NY 10003 (United States); and others

2016-11-10

We have acquired Hubble Space Telescope (HST) and Very Large Telescope near-infrared spectra and images of supernova (SN) Refsdal after its discovery as an Einstein cross in fall 2014. The HST light curve of SN Refsdal has a shape consistent with the distinctive, slowly rising light curves of SN 1987A-like SNe, and we find strong evidence for a broad H α P-Cygni profile and Na I D absorption in the HST grism spectrum at the redshift ( z = 1.49) of the spiral host galaxy. SNe IIn, largely powered by circumstellar interaction, could provide a good match to the light curve of SN Refsdal, but the spectrum of a SN IIn would not show broad and strong H α and Na I D absorption. From the grism spectrum, we measure an H α expansion velocity consistent with those of SN 1987A-like SNe at a similar phase. The luminosity, evolution, and Gaussian profile of the H α emission of the WFC3 and X-shooter spectra, separated by ∼2.5 months in the rest frame, provide additional evidence that supports the SN 1987A-like classification. In comparison with other examples of SN 1987A-like SNe, photometry of SN Refsdal favors bluer B - V and V - R colors and one of the largest luminosities for the assumed range of potential magnifications. The evolution of the light curve at late times will provide additional evidence about the potential existence of any substantial circumstellar material. Using MOSFIRE and X-shooter spectra, we estimate a subsolar host-galaxy metallicity (8.3 ± 0.1 dex and <8.4 dex, respectively) near the explosion site.

Development of in situ time-resolved Raman spectroscopy facility for dynamic shock loading in materials

Science.gov (United States)

Chaurasia, S.; Rastogi, V.; Rao, U.; Sijoy, C. D.; Mishra, V.; Deo, M. N.

2017-11-01

The transient state of excitation and relaxation processes in materials under shock compression can be investigated by coupling the laser driven shock facility with Raman spectroscopy. For this purpose, a time resolved Raman spectroscopy setup has been developed to monitor the physical and the chemical changes such as phase transitions, chemical reactions, molecular kinetics etc., under shock compression with nanosecond time resolution. This system consist of mainly three parts, a 2 J/8 ns Nd:YAG laser system used for generation of pump and probe beams, a Raman spectrometer with temporal and spectral resolution of 1.2 ns and 3 cm-1 respectively and a target holder in confinement geometry assembly. Detailed simulation for the optimization of confinement geometry targets is performed. Time resolved measurement of polytetrafluoroethylene (PTFE) targets at focused laser intensity of 2.2 GW/cm2 has been done. The corresponding pressure in the Aluminum and PTFE are 3.6 and 1.7 GPa respectively. At 1.7 GPa in PTFE, a red shift of 5 cm-1 is observed for the CF2 twisting mode (291 cm-1). Shock velocity in PTFE is calculated by measuring rate of change of ratios of the intensity of Raman lines scattered from shocked volume to total volume of sample in the laser focal spot along the laser axis. The calculated shock velocity in PTFE is found to be 1.64 ± 0.16 km/s at shock pressure of 1.7 GPa, for present experimental conditions.

Preparation of PtSnCu/C and PtSn/C electrocatalysts and activation by dealloying processes for ethanol electrooxidation; Preparacao de eletrocatalisadores PtSnCu/C e PtSn/C e ativacao por processos de dealloying para aplicacao na oxidacao eletroquuimica do etanol

Energy Technology Data Exchange (ETDEWEB)

Crisafulli, Rudy

2013-06-01

PtSnCu/C (with different Pt:Sn:Cu atomic ratios) and PtSn/C (50:50) electrocatalysts were prepared by borohydride (BR) and alcohol-reduction (AR) processes using H{sub 2}PtCl{sub 6}.6H{sub 2}O, SnCl{sub 2}.2H{sub 2}O and CuCl{sub 2}.2H{sub 2}O as metal sources, NaBH{sub 4} and ethylene glycol as reducing agents, 2-propanol and ethylene glycol/water as solvents and carbon black as support. In a further step, these electrocatalysts were activated by chemical (CD) and electrochemical (ED) dealloying processes through acid treatment and thin porous coating technique, respectively. These materials were characterized by energy dispersive X-ray, Xray diffraction, transmission electron microscopy, line scan energy dispersive Xray and cyclic voltammetry. Electrochemical studies for ethanol electro-oxidation were performed by cyclic voltammetry, chronoamperometry and in single Direct Ethanol Fuel Cell using Membrane Electrode Assembly (MEA). The anodic effluents were analysed by gas chromatography. The X-ray diffractograms of the as-synthesized electrocatalysts showed the typical face-centered cubic structure (FCC) of platinum and its alloys. After dealloying, the X-ray diffractograms showed that the Pt FCC structure was preserved. The crystallite sizes of the assynthesized electrocatalysts were in the range of <=2 nm to 3 nm and after dealloying there were no significant variations in sizes. The energy dispersive Xray analysis of the as-synthesized electrocatalysts showed a Pt:Sn and Pt:Sn:Cu atomic ratios similar to the nominal values. After chemical and electrochemical dealloying of the electrocatalysts the ranged Pt:Sn and Pt:Sn:Cu atomic ratios showed that Cu and Sn atoms were removed. However, chemical dealloying process proved to be more efficient for removing Cu and electrochemical dealloying for removing Sn. The line scan energy dispersive X-ray analysis showed that acid and electrochemical treatments were efficient to dealloying Cu and/or Sn superficial atoms of

MAPLE deposition and characterization of SnO2 colloidal nanoparticle thin films

International Nuclear Information System (INIS)

Caricato, A P; Martino, M; Romano, F; Tunno, T; Valerini, D; Epifani, M; Rella, R; Taurino, A

2009-01-01

In this paper we report on the deposition and characterization of tin oxide (SnO 2 ) nanoparticle thin films. The films were deposited by the matrix-assisted pulsed laser evaporation (MAPLE) technique. SnO 2 colloidal nanoparticles with a trioctylphosphine capping layer were diluted in toluene with a concentration of 0.2 wt% and frozen at liquid nitrogen temperature. The frozen target was irradiated with a KrF (248 nm, τ = 20 ns) excimer laser (6000 pulses at 10 Hz). The nanoparticles were deposited on silica (SiO 2 ) and (1 0 0) Si substrates and submitted to morphological (high resolution scanning electron microscopy (SEM)), structural Fourier transform infrared spectroscopy (FTIR) and optical (UV-Vis transmission) characterizations. SEM and FTIR analyses showed that trioctylphosphine was the main component in the as-deposited films. The trioctylphosphine was removed after an annealing in vacuum at 400 0 C, thus allowing to get uniform SnO 2 nanoparticle films in which the starting nanoparticle dimensions were preserved. The energy gap value, determined by optical characterizations, was 4.2 eV, higher than the bulk SnO 2 energy gap (3.6 eV), due to quantum confinement effects.

Polarographic determination of Sn (II) and total Sn in PYRO and MDP radiopharmaceutical kits

International Nuclear Information System (INIS)

Sebastian, Maria V.A.; Lugon, Marcelo Di M.V.; Silva, Jose L. da; Fukumori, Neuza T.O.; Pereira, Nilda P.S. de; Silva, Constancia P.G. da; Matsuda, Margareth M.N.

2007-01-01

A sensitive, alternative method to atom absorption spectrometry, fluorimetry or potentiometry for the evaluation of tin(II) ions (0.1- 10 mg) and total tin in radiopharmaceutical kits was investigated. Differential pulse polarography was chosen. The supporting electrolyte was H 2 SO 4 3 mol L -1 and HCl 3 mol L -1 solution. The potential was swept from -250 to -800 mV vs Ag/AgCl/saturated KCl, using a dropping mercury electrode with 1 s drop time, 50 mV s -1 scan rate, -50 mV pulse amplitude, 40 ms pulse time and 10 mV step amplitude. Pure nitrogen was used to deaerate the polarographic cell solution for 5 min, before and after each sample introduction. Oxidation of Sn(II) was made in the same sample vial by adding H 2 O 2 (hydrogen peroxide) 10 mol L -1 , at 37 deg C, in order to quantify the total Sn. The calibration curve for Sn(II) and Sn(IV) was obtained in the concentration range of 0-10 ppm from a 1000 ppm standard solution. The detection limit of Sn(II) is 0.5 ppm and for Sn(IV) is 0.6 ppm. Differential pulse polarography was performed in the pyrophosphate (PYRO) and methylenediphosphonic acid (MDP) radiopharmaceutical kits, containing 2 mg and 1 mg of SnCl 2 .2H 2 O per vial, respectively. The described method for determination of stannous ion (Sn(II)), is selective, reproducible and adequate to be used in the quality control of lyophilized reagents and it shall be performed for other cold kits produced at IPEN. (author)

Extension of the excitation functions of deuteron induced reactions on {sup nat}Sn up to 50 MeV

Energy Technology Data Exchange (ETDEWEB)

Hermanne, A., E-mail: aherman@vub.ac.be [Cyclotron Laboratory, Vrije Universiteit Brussel, B1050 Brussels (Belgium); Tárkányi, F.; Ditrói, F.; Takács, S. [Institute of Nuclear Research of the Hungarian Academy of Sciences, H4026 Debrecen (Hungary)

2017-01-15

Using the stacked-foil activation technique, cross-sections of deuteron induced reactions on natural Sn targets were determined up to 50 MeV. Excitation functions are reported for the product nuclides {sup 116m}Sb, {sup 117}Sb, {sup 118m}Sb, {sup 120m}Sb {sup 122m+g}Sb, {sup 124m+g}Sb, {sup 110}Sn(cum), {sup 113m+g}Sn(cum), {sup 117m}Sn, {sup 110m}In(cum), {sup 110g}In, {sup 111m+g}In(cum), {sup 113m}In, {sup 114m}In {sup 115m}In. Comparison with earlier published data at lower energy is discussed. For all excitation functions a theoretical calculation using the TALYS 1.6 (on-line TENDL-2015 library) code is shown.

Ligand-conjugated mesoporous silica nanorattles based on enzyme targeted prodrug delivery system for effective lung cancer therapy

Energy Technology Data Exchange (ETDEWEB)

Sundarraj, Shenbagamoorthy, E-mail: sundarrajbu09@gmail.com [Proteomics and Molecular Cell Physiology Laboratory, Department of Zoology, Bharathiar University, Coimbatore 641 046, TN (India); Thangam, Ramar [Proteomics and Molecular Cell Physiology Laboratory, Department of Zoology, Bharathiar University, Coimbatore 641 046, TN (India); Department of Virology, King Institute of Preventive Medicine and Research, Guindy, Chennai 600 032, TN (India); Sujitha, Mohanan V.; Vimala, Karuppaiya [Proteomics and Molecular Cell Physiology Laboratory, Department of Zoology, Bharathiar University, Coimbatore 641 046, TN (India); Kannan, Soundarapandian, E-mail: skperiyaruniv@gmail.com [Proteomics and Molecular Cell Physiology Laboratory, Department of Zoology, Bharathiar University, Coimbatore 641 046, TN (India); Department of Zoology, Periyar University, Salem 636 011, TN (India)

2014-03-15

Epidermal growth factor receptor antibody (EGFRAb) conjugated silica nanorattles (SNs) were synthesized and used to develop receptor mediated endocytosis for targeted drug delivery strategies for cancer therapy. The present study determined that the rate of internalization of silica nanorattles was found to be high in lung cancer cells when compared with the normal lung cells. EGFRAb can specifically bind to EGFR, a receptor that is highly expressed in lung cancer cells, but is expressed at low levels in other normal cells. Furthermore, in vitro studies clearly substantiated that the cPLA{sub 2}α activity, arachidonic acid release and cell proliferation were considerably reduced by pyrrolidine-2 loaded EGFRAb-SN in H460 cells. The cytotoxicity, cell cycle arrest and apoptosis were significantly induced by the treatment of pyrrolidine-2 loaded EGFRAb-SN when compared with free pyrrolidine-2 and pyrrolidine-2 loaded SNs in human non-small cell lung cancer cells. An in vivo toxicity assessment showed that silica nanorattles and EGFRAb-SN-pyrrolidine-2 exhibited low systemic toxicity in healthy Balb/c mice. The EGFRAb-SN-pyrrolidine-2 showed a much better antitumor activity (38%) with enhanced tumor inhibition rate than the pyrrolidine-2 on the non-small cell lung carcinoma subcutaneous model. Thus, the present findings validated the low toxicity and high therapeutic potentials of EGFRAb-SN-pyrrolidine-2, which may provide a convincing evidence of the silica nanorattles as new potential carriers for targeted drug delivery systems. - Highlights: • EGFRAb-SN developed for receptor-mediated Drug delivery system (DDS). • EGFRAb-SN-pyrrolidine-2 targeted DDS for cPLA2α inhibition in NSLC. • Study indicates EGFRAb-SN-pyrrolidine-2 as an efficient in target dug delivery carrier. • Study explains entire efficiency of EGFRAb-SN-pyrrolidine-2 in vitro and in vivo models.

Ligand-conjugated mesoporous silica nanorattles based on enzyme targeted prodrug delivery system for effective lung cancer therapy

International Nuclear Information System (INIS)

Sundarraj, Shenbagamoorthy; Thangam, Ramar; Sujitha, Mohanan V.; Vimala, Karuppaiya; Kannan, Soundarapandian

2014-01-01

Epidermal growth factor receptor antibody (EGFRAb) conjugated silica nanorattles (SNs) were synthesized and used to develop receptor mediated endocytosis for targeted drug delivery strategies for cancer therapy. The present study determined that the rate of internalization of silica nanorattles was found to be high in lung cancer cells when compared with the normal lung cells. EGFRAb can specifically bind to EGFR, a receptor that is highly expressed in lung cancer cells, but is expressed at low levels in other normal cells. Furthermore, in vitro studies clearly substantiated that the cPLA 2 α activity, arachidonic acid release and cell proliferation were considerably reduced by pyrrolidine-2 loaded EGFRAb-SN in H460 cells. The cytotoxicity, cell cycle arrest and apoptosis were significantly induced by the treatment of pyrrolidine-2 loaded EGFRAb-SN when compared with free pyrrolidine-2 and pyrrolidine-2 loaded SNs in human non-small cell lung cancer cells. An in vivo toxicity assessment showed that silica nanorattles and EGFRAb-SN-pyrrolidine-2 exhibited low systemic toxicity in healthy Balb/c mice. The EGFRAb-SN-pyrrolidine-2 showed a much better antitumor activity (38%) with enhanced tumor inhibition rate than the pyrrolidine-2 on the non-small cell lung carcinoma subcutaneous model. Thus, the present findings validated the low toxicity and high therapeutic potentials of EGFRAb-SN-pyrrolidine-2, which may provide a convincing evidence of the silica nanorattles as new potential carriers for targeted drug delivery systems. - Highlights: • EGFRAb-SN developed for receptor-mediated Drug delivery system (DDS). • EGFRAb-SN-pyrrolidine-2 targeted DDS for cPLA2α inhibition in NSLC. • Study indicates EGFRAb-SN-pyrrolidine-2 as an efficient in target dug delivery carrier. • Study explains entire efficiency of EGFRAb-SN-pyrrolidine-2 in vitro and in vivo models

Physics of Collisionless Shocks Space Plasma Shock Waves

CERN Document Server

Balogh, André

2013-01-01

The present book provides a contemporary systematic treatment of shock waves in high-temperature collisionless plasmas as are encountered in near Earth space and in Astrophysics. It consists of two parts. Part I develops the complete theory of shocks in dilute hot plasmas under the assumption of absence of collisions among the charged particles when the interaction is mediated solely by the self-consistent electromagnetic fields. Such shocks are naturally magnetised implying that the magnetic field plays an important role in their evolution and dynamics. This part treats both subcritical shocks, which dissipate flow energy by generating anomalous resistance or viscosity, and supercritical shocks. The main emphasis is, however, on super-critical shocks where the anomalous dissipation is insufficient to retard the upstream flow. These shocks, depending on the direction of the upstream magnetic field, are distinguished as quasi-perpendicular and quasi-parallel shocks which exhibit different behaviours, reflecti...

Internal friction behavior of liquid Bi-Sn alloys

International Nuclear Information System (INIS)

Wu Aiqing; Guo Lijun; Liu Changsong; Jia Erguang; Zhu Zhengang

2005-01-01

Pure Bi and Sn and four Bi-Sn alloys distributed on the entire concentration range were selected for internal-friction investigation over a wide temperature range. There exist two peaks in the plots of internal friction versus temperature for liquid Sn, Bi-Sn60 and Bi-Sn90 alloys, one peak being located at about 480 - bar Cand another at about 830 - bar C. Only a single internal-friction peak at about 830 - bar C occurs in liquid Bi-Sn43 (eutectic composition). No internal-friction peak appears in liquid Bi-Sn20 alloy and pure Bi. The height of the internal-friction peaks depends on the content of Sn. The present finding suggests that Sn-rich Bi-Sn alloys may inherit the internal-friction behaviors of pure Sn, whereas Bi-rich Bi-Sn alloy seems to be like pure Bi. The position of the internal-friction peaks is frequency dependent, which resembles the internal-friction feature in structure transition in solids

Internal friction behavior of liquid Bi-Sn alloys

Energy Technology Data Exchange (ETDEWEB)

Wu Aiqing [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031 (China); Guo Lijun [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031 (China); Liu Changsong [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031 (China); Jia Erguang [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031 (China); Zhu Zhengang [Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P.O. Box 1129, Hefei 230031 (China)]. E-mail: zgzhu@issp.ac.cn

2005-12-01

Pure Bi and Sn and four Bi-Sn alloys distributed on the entire concentration range were selected for internal-friction investigation over a wide temperature range. There exist two peaks in the plots of internal friction versus temperature for liquid Sn, Bi-Sn60 and Bi-Sn90 alloys, one peak being located at about 480{sup -}bar Cand another at about 830{sup -}bar C. Only a single internal-friction peak at about 830{sup -}bar C occurs in liquid Bi-Sn43 (eutectic composition). No internal-friction peak appears in liquid Bi-Sn20 alloy and pure Bi. The height of the internal-friction peaks depends on the content of Sn. The present finding suggests that Sn-rich Bi-Sn alloys may inherit the internal-friction behaviors of pure Sn, whereas Bi-rich Bi-Sn alloy seems to be like pure Bi. The position of the internal-friction peaks is frequency dependent, which resembles the internal-friction feature in structure transition in solids.

Influence of laser induced hot electrons on the threshold for shock ignition of fusion reactions

Energy Technology Data Exchange (ETDEWEB)

Colaïtis, A.; Ribeyre, X.; Le Bel, E.; Duchateau, G.; Nicolaï, Ph.; Tikhonchuk, V. [Centre Lasers Intenses et Applications, Université de Bordeaux - CNRS - CEA, UMR 5107,351 Cours de la Libération, 33400 Talence (France)

2016-07-15

The effects of Hot Electrons (HEs) generated by the nonlinear Laser-Plasma Interaction (LPI) on the dynamics of Shock Ignition Inertial Confinement Fusion targets are investigated. The coupling between the laser beam, plasma dynamics and hot electron generation and propagation is described with a radiative hydrodynamics code using an inline model based on Paraxial Complex Geometrical Optics [Colaïtis et al., Phys. Rev. E 92, 041101 (2015)]. Two targets are considered: the pure-DT HiPER target and a CH-DT design with baseline spike powers of the order of 200–300 TW. In both cases, accounting for the LPI-generated HEs leads to non-igniting targets when using the baseline spike powers. While HEs are found to increase the ignitor shock pressure, they also preheat the bulk of the imploding shell, notably causing its expansion and contamination of the hotspot with the dense shell material before the time of shock convergence. The associated increase in hotspot mass (i) increases the ignitor shock pressure required to ignite the fusion reactions and (ii) significantly increases the power losses through Bremsstrahlung X-ray radiation, thus rapidly cooling the hotspot. These effects are less prominent for the CH-DT target where the plastic ablator shields the lower energy LPI-HE spectrum. Simulations using higher laser spike powers of 500 TW suggest that the CH-DT capsule marginally ignites, with an ignition window width significantly smaller than without LPI-HEs, and with three quarters of the baseline target yield. The latter effect arises from the relation between the shock launching time and the shell areal density, which becomes relevant in presence of a LPI-HE preheating.

Phase Equilibria of the Ternary Sn-Pb-Co System at 250°C and Interfacial Reactions of Co with Sn-Pb Alloys

Science.gov (United States)

Wang, Chao-hong; Kuo, Chun-yi; Yang, Nian-cih

2015-11-01

The isothermal section of the ternary Sn-Pb-Co system at 250°C was experimentally determined through a series of the equilibrated Sn-Pb-Co alloys of various compositions. The equilibrium phases were identified on the basis of compositional analysis. For the Sn-Co intermetallic compounds (IMCs), CoSn3, CoSn2, CoSn and Co3Sn2, the Pb solubility was very limited. There exist five tie-triangle regions. The Co-Pb system involves one monotectic reaction, so the phase separation of liquid alloys near the Co-Pb side occurred prior to solidification. The immiscibility field was also determined. Additionally, interfacial reactions between Co and Sn-Pb alloys were conducted. The reaction phase for the Sn-48 at.%Pb and Sn-58 at.%Pb at 250°C was CoSn3 and CoSn2, respectively. Both of them were simultaneously formed in the Sn-53 at.%Pb/Co. The formed IMCs were closely associated to the phase equilibria relationship of the liquid-CoSn3-CoSn2 tie-triangle. Furthermore, with increasing temperatures, the phase formed in equilibrium with Sn-37 wt.%Pb was found to transit from CoSn3 to CoSn2 at 275°C. We propose a simple method of examining the phase transition temperature in the interfacial reactions to determine the boundaries of the liquid-CoSn3-CoSn2 tie-triangles at different temperatures.

STRESS a SN survey at ESO

Science.gov (United States)

Botticella, M. T.

We performed the Southern inTermediate Redshift ESO Supernova Search (STRESS), a survey specifically designed to measure the rate of both SNe Ia and CC SNe, in order to obtain a direct comparison of the high redshift and local rates and to investigate the dependence of the rates on specific galaxy properties, most notably their colour. We found that the type Ia SN rate, at mean redshift z = 0.3, is 0.22+0.10+0.16-0.08-0.14 h270 SNu, while the CC SN rate, at z = 0.21, is 0.82+0.31+0.300.24-0.26 h270 SNu. The quoted errors are the statistical and systematic uncertainties. With respect to the local value, the CC SN rate at z = 0.2 is higher by a factor of ˜ 2, whereas the type Ia SN rate remains almost constant. We also measured the SN rates in the red and blue galaxies and found that the SN Ia rate seems to be constant in galaxies of different colour, whereas the CC SN rate seems to peak in blue galaxies, as in the local Universe. Finally we exploited the link between SFH and SN rates to predict the evolutionary behaviour of the SN rates and compare it with the path indicated by observations.

Pulsed laser deposition of chalcogenide sulfides from multi- and single-component targets: the non-stoichiometric material transfer

DEFF Research Database (Denmark)

Schou, Jørgen; Ganskukh, Mungunshagai; Ettlinger, Rebecca Bolt

2018-01-01

The mass transfer from target to films is incongruent for chalcogenide sulfides in contrast to the expectations of pulsed laser deposition (PLD) as a stoichiometric film growth process. Films produced from a CZTS (Cu2ZnSnS4) multi-component target have no Cu below a fluence threshold of 0.2 J/cm2......, and the Cu content is also very low at low fluence from a single-component target. Above this threshold, the Cu content in the films increases almost linearly up to a value above the stoichiometric value, while the ratio of the concentration of the other metals Zn to Sn (Zn/Sn) remains constant. Films...... of a similar material CTS (Cu2SnS3) have been produced by PLD from a CTS target and exhibits a similar trend in the same fluence region. The results are discussed on the basis of solid-state data and the existing data from the literature....

Integral Field Spectroscopy of Balmer-dominated Shocks in the Magellanic Cloud Supernova Remnant N103B

Energy Technology Data Exchange (ETDEWEB)

Ghavamian, Parviz [Department of Physics, Astronomy and Geosciences, Towson University, Towson, MD 21252 (United States); Seitenzahl, Ivo R.; Dopita, M. A. [Research School of Astronomy and Astrophysics, Australian National University, Canberra, ACT 2611 (Australia); Vogt, Frédéric P. A. [European Southern Observatory, Av. Alonso de Córdova 3107, 763 0355 Vitacura, Santiago (Chile); Terry, Jason P. [Department of Physics and Astronomy, University of Georgia (United States); Williams, Brian J. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Winkler, P. Frank, E-mail: pghavamian@towson.edu [Department of Physics, Middlebury College, Middlebury, VT 05753 (United States)

2017-10-01

We present results of integral field spectroscopy of Balmer-dominated shocks in the LMC supernova remnant (SNR) N103B, carried out using the Wide Field Integral Spectrograph (WiFeS ) on the 2.3 m telescope at the Siding Spring Observatory in Australia. Existing X-ray studies of N103B have indicated an SN Ia origin. Radiative shock emission from clumpy material surrounding the SNR may result from interaction of the forward shock with relic stellar wind material, possibly implicating a thermonuclear explosion in a single-degenerate binary system. The recently discovered Balmer-dominated shocks mark the impact of the forward shock with low density, partially neutral CSM gas, and form a partial shell encircling clumps of material exhibiting radiative shocks. The WiFeS spectra of N103B reveal broad H α emission having a width as high as 2350 km s{sup −1} along the northern rim, and both H α and H β broad profiles having widths around 1300 km s{sup −1} along the southern rim. Fits to the H α line profiles indicate that in addition to the usual broad and narrow emission components, a third component of intermediate width exists in these Balmer-dominated shocks, ranging from around 125 km s{sup −1} up to 225 km s{sup −1} in width. This is consistent with predictions of recent Balmer-dominated shock models, which predict that an intermediate-width component will be generated in a fast neutral precursor. We derive a Sedov age of approximately 685 ± 20 years for N103B from the Balmer-dominated spectra, consistent with the young age of 380–860 years estimated from light echo studies.

Fluid resuscitation does not improve renal oxygenation during hemorrhagic shock in rats

OpenAIRE

Legrand, Matthieu; Mik, Egbert; Balestra, Gianmarco; Lutter, Rene; Pirracchio, Romain; Payen, Didier; Ince, Can

2010-01-01

textabstractBackground: The resuscitation strategy for hemorrhagic shock remains controversial, with the kidney being especially prone to hypoxia. Methods: The authors used a three-phase hemorrhagic shock model to investigate the effects of fluid resuscitation on renal oxygenation. After a 1-h shock phase, rats were randomized into four groups to receive either normal saline or hypertonic saline targeting a mean arterial pressure (MAP) of either 40 or 80 mmHg. After such resuscitation, rats w...

Shock wave generation in laser ablation studied using pulsed digital holographic interferometry

Energy Technology Data Exchange (ETDEWEB)

Amer, Eynas; Gren, Per; Sjoedahl, Mikael [Division of Experimental Mechanics, Luleaa University of Technology, SE-971 87 Luleaa (Sweden)], E-mail: eynas.amer@ltu.se, E-mail: per.gren@ltu.se, E-mail: mikael.sjodahl@ltu.se

2008-11-07

Pulsed digital holographic interferometry has been used to study the shock wave induced by a Q-switched Nd-YAG laser ({lambda} = 1064 nm and pulse duration 12 ns) on a polycrystalline boron nitride (PCBN) ceramic target under atmospheric air pressure. A special setup based on using two synchronized wavelengths from the same laser for processing and measurement simultaneously has been introduced. Collimated laser light ({lambda} = 532 nm) passed through the volume along the target and digital holograms were recorded for different time delays after processing starts. Numerical data of the integrated refractive index field were calculated and presented as phase maps showing the propagation of the shock wave generated by the process. The location of the induced shock wave front was observed for different focusing and time delays. The amount of released energy, i.e. the part of the incident energy of the laser pulse that is eventually converted to a shock wave has been estimated using the point explosion model. The released energy is normalized by the incident laser pulse energy and the energy conversion efficiency between the laser pulse and PCBN target has been calculated at different power densities. The results show that the energy conversion efficiency seems to be constant around 80% at high power densities.

Sn whiskers removed by energy photo flashing

International Nuclear Information System (INIS)

Jiang, N.; Yang, M.; Novak, J.; Igor, P.; Osterman, M.

2012-01-01

Highlights: ► Sn whiskers were sintered by intense light flashing (Photosintering). ► Photosintering can effectively eliminate Sn whiskers. ► Photosintering would not damage electronic devices. ► Photosintering is a very promising approach to improve Sn-based electronic surface termination. - Abstract: Sn whiskers have been known to be the major issue resulting in electronic circuit shorts. In this study, we present a novel energy photo flashing approach (photosintering) to shorten and eliminate Sn whiskers. It has been found that photosintering is very effective to modify and remove Sn whiskers; only a sub-millisecond duration photosintering can amazingly get rid of over 90 vol.% of Sn whiskers. Moreover, this photosintering approach has also been proved to cause no damages to electronic devices, suggesting it is a potentially promising way to improve Sn-based electronic surface termination.

Li2SnO3 derived secondary Li-Sn alloy electrode for lithium-ion batteries

International Nuclear Information System (INIS)

Zhang, D.W.; Zhang, S.Q.; Jin, Y.; Yi, T.H.; Xie, S.; Chen, C.H.

2006-01-01

As a possible high-capacity Li-ion battery anode material, Li 2 SnO 3 was prepared via a solid-state reaction route and a sol-gel route, separately. Its electrochemical performance was tested in coin-type cells with metallic Li as the counter electrode. The results show that the sol-gel derived Li 2 SnO 3 has uniform nano-sized particles (200-300 nm) and can deliver a better reversible capacity (380 mAh/g after 50 cycles in the voltage window of 0-1 V) than that from the solid-state reaction route. The characterizations by means of galvanostatic cycling, cyclic voltammetry and ex situ X-ray diffraction indicate that the electrochemical process of the Li 2 SnO 3 lithiation proceeds with an initial structural reduction of the composite oxide into Sn-metal and Li 2 O followed by a reversible Li-Sn alloy formation in the Li 2 O matrix. Due to the buffer role of the Li 2 O matrix, the reversibility of the secondary Li-Sn alloy electrode is largely secured

Improving cycle stability of SnS anode for sodium-ion batteries by limiting Sn agglomeration

Science.gov (United States)

Wang, Wenhui; Shi, Liang; Lan, Danni; Li, Quan

2018-02-01

Flower-like SnS nanostructures are obtained by a simple solvothermal method for anode applications in Na-ion batteries. We show experimental evidence of progressive Sn agglomeration and crystalline Na2S enrichment at the end of de-sodiation process of the SnS electrode, both of which contribute to the capacity decay of the electrode upon repeated cycles. By replacing the commonly adopted acetylene black conductive additive with multi-wall carbon nanotubes (MWCNT), the cycle stability of the SnS electrode is largely improved, which correlates well with the observed suppression of both Sn agglomeration and Na2S enrichment at the end of de-sodiation cycle. A full cell is assembled with the SnS/MWCNT anode and the P2-Na2/3Ni1/3Mn1/2Ti1/6O2 cathode. An initial energy density of 262 Wh/kg (normalized to the total mass of cathode and anode) is demonstrated for the full cell, which retains 71% of the first discharge capacity after 40 cycles.

Interfacial Bonding Energy on the Interface between ZChSnSb/Sn Alloy Layer and Steel Body at Microscale

Directory of Open Access Journals (Sweden)

Jianmei Wang

2017-09-01

Full Text Available To investigate the performance of bonding on the interface between ZChSnSb/Sn and steel body, the interfacial bonding energy on the interface of a ZChSnSb/Sn alloy layer and the steel body with or without Sn as an intermediate layer was calculated under the same loadcase using the molecular dynamics simulation software Materials Studio by ACCELRYS, and the interfacial bonding energy under different Babbitt thicknesses was compared. The results show that the bonding energy of the interface with Sn as an intermediate layer is 10% larger than that of the interface without a Sn layer. The interfacial bonding performances of Babbitt and the steel body with Sn as an intermediate layer are better than those of an interface without a Sn layer. When the thickness of the Babbitt layer of bushing is 17.143 Å, the interfacial bonding energy reaches the maximum, and the interfacial bonding performance is optimum. These findings illustrate the bonding mechanism of the interfacial structure from the molecular level so as to ensure the good bonding properties of the interface, which provides a reference for the improvement of the bush manufacturing process from the microscopic point of view.

Interfacial Bonding Energy on the Interface between ZChSnSb/Sn Alloy Layer and Steel Body at Microscale.

Science.gov (United States)

Wang, Jianmei; Xia, Quanzhi; Ma, Yang; Meng, Fanning; Liang, Yinan; Li, Zhixiong

2017-09-25

To investigate the performance of bonding on the interface between ZChSnSb/Sn and steel body, the interfacial bonding energy on the interface of a ZChSnSb/Sn alloy layer and the steel body with or without Sn as an intermediate layer was calculated under the same loadcase using the molecular dynamics simulation software Materials Studio by ACCELRYS, and the interfacial bonding energy under different Babbitt thicknesses was compared. The results show that the bonding energy of the interface with Sn as an intermediate layer is 10% larger than that of the interface without a Sn layer. The interfacial bonding performances of Babbitt and the steel body with Sn as an intermediate layer are better than those of an interface without a Sn layer. When the thickness of the Babbitt layer of bushing is 17.143 Å, the interfacial bonding energy reaches the maximum, and the interfacial bonding performance is optimum. These findings illustrate the bonding mechanism of the interfacial structure from the molecular level so as to ensure the good bonding properties of the interface, which provides a reference for the improvement of the bush manufacturing process from the microscopic point of view.

Electronic structure and isomer shifts of Sn halides

International Nuclear Information System (INIS)

Terra, J.; Guenzburger, D.

1988-01-01

The all-electron first-principles Discrete Variational method was employed to study the electronic structure of SnF 4 , SnCl 4 , SnBr 4 and SnI 4 . Values of the electronic density at the Sn nucleus were derived and related to 119 Sn Isomer Shifts to obtain the nuclear constant Δ 2 >. Differences in values of ρ(o) area discussed in terms of the chemical bonding between Sn and halogen atoms. (author) [pt

Electron heating, magnetic field amplification, and cosmic-ray precursor length at supernova remnant shocks

Energy Technology Data Exchange (ETDEWEB)

Laming, J. Martin [Space Science Division, Naval Research Laboratory, Code 7684, Washington, DC 20375 (United States); Hwang, Una [Department of Astronomy, University of Maryland, College Park, MD 20742 (United States); Ghavamian, Parviz [Department of Physics, Astronomy and Geosciences, Towson University, Towson, MD 21252 (United States); Rakowski, Cara, E-mail: laming@nrl.navy.mil, E-mail: Una.Hwang-1@nasa.gov, E-mail: pghavamian@towson.edu

2014-07-20

We investigate the observability, by direct and indirect means, of a shock precursor arising from magnetic field amplification by cosmic rays. We estimate the depth of such a precursor under conditions of nonresonant amplification, which can provide magnetic field strengths comparable to those inferred for supernova remnants. Magnetic field generation occurs as the streaming cosmic rays induce a plasma return current, and it may be quenched by either nonresonant or resonant channels. In the case of nonresonant saturation, the cosmic rays become magnetized and amplification saturates at higher magnetic fields. The precursor can extend out to 10{sup 17}-10{sup 18} cm and is potentially detectable. If resonant saturation occurs, the cosmic rays are scattered by turbulence and the precursor length will likely be much smaller. The dependence of precursor length on shock velocity has implications for electron heating. In the case of resonant saturation, this dependence is similar to that in the more familiar resonantly generated shock precursor, which when expressed in terms of the cosmic-ray diffusion coefficient kappav and shock velocity v{sub s} is kappav/v{sub s} . In the nonresonantly saturated case, the precursor length declines less quickly with increasing v{sub s} . Where precursor length proportional to 1/v{sub s} gives constant electron heating, this increased precursor length could be expected to lead to higher electron temperatures for nonresonant amplification. This should be expected at faster supernova remnant shocks than studied by previous works. Existing results and new data analysis of SN 1006 and Cas A suggest some observational support for this idea.

195Pt and 119Sn Knight shifts of U3Pt3Sn4

International Nuclear Information System (INIS)

Kojima, K.; Takabatake, T.; Harada, A.; Hihara, T.

1995-01-01

The 195 Pt and 119 Sn Knight shifts in U 3 Pt 3 Sn 4 have been measured in the temperature range 4.2-298K. They exhibit Curie-Weiss like behaviors above about 50K and remain constant below about 10K. This suggests that the deviation of χ(T) from the modified Curie-Weiss law is an intrinsic property of U 3 Pt 3 Sn 4 . ((orig.))

Solid Liquid Interdiffusion Bonding of (Pb, Sn)Te Thermoelectric Modules with Cu Electrodes Using a Thin-Film Sn Interlayer

Science.gov (United States)

Chuang, T. H.; Lin, H. J.; Chuang, C. H.; Yeh, W. T.; Hwang, J. D.; Chu, H. S.

2014-12-01

A (Pb, Sn)Te thermoelectric element plated with a Ni barrier layer and a Ag reaction layer has been joined with a Cu electrode coated with Ag and Sn thin films using a solid-liquid interdiffusion bonding method. This method allows the interfacial reaction between Ag and Sn such that Ag3Sn intermetallic compounds form at low temperature and are stable at high temperature. In this study, the bonding strength was about 6.6 MPa, and the specimens fractured along the interface between the (Pb, Sn)Te thermoelectric element and the Ni barrier layer. Pre-electroplating a film of Sn with a thickness of about 1 μm on the thermoelectric element and pre-heating at 250°C for 3 min ensures the adhesion between the thermoelectric material and the Ni barrier layer. The bonding strength is thus increased to a maximal value of 12.2 MPa, and most of the fractures occur inside the thermoelectric material. During the bonding process, not only the Ag3Sn intermetallics but also Cu6Sn5 forms at the Ag3Sn/Cu interface, which transforms into Cu3Sn with increases in the bonding temperature or bonding time.

Shock ignition of high gain inertial fusion capsules

International Nuclear Information System (INIS)

Schurtz, G.; Ribeyre, X.; Lebel, E.; Casner, A.

2010-01-01

Complete text of publication follows. Inertial Confinement Fusion relies on the compression of small amounts of an equimolar mix of Deuterium and Tritium (DT) up to volumic masses of several hundreds of g/cm 3 . Such high densities are obtained by means of the implosion of a spherical shell made of cryogenic DT fuel. In the conventional scheme a hot spot is formed in the central part of the pellet at the end of the implosion. If the pressure of this hot spot is large enough (several hundreds of Gbars), thermonuclear heating occurs with a characteristic time shorter than the hydrodynamic confinement time and the target self ignites. Since the central hot spot pressure results from the conversion of the shell kinetic energy into thermal energy, the threshold for the ignition of a given mass of DT is a direct function of the implosion velocity. Typical implosion velocities for central self ignition are of the order of 400 km/s. Such high velocities imply both a strong acceleration of the shell and the use of large aspect ration shells in order to optimize the hydrodynamic efficiency of the implosion, at least in direct drive. These two features strongly enhance the risk of shell beak up at time of acceleration under the Rayleigh-Taylor instability. Furthermore the formation of the hot spot may itself the unstable, this reducing its effective mass. High compression may be achieved at much lower velocities, thus reducing the energy budget and enhancing the implosion safety, but the corresponding fuel assembly requires an additional heating in order to reach ignition. This heating may be obtained from a 70-100 kJ laser pulse, delivered in 10-15 ps (Fast Ignition). An alternative idea is to boost up the central pressure of a target imploded at a sub-ignition velocity by means of a convergent strong shock launched at the end of the compression phase. This Shock Ignition (SI) concept has been suggested in 1983 by Scherbakov et al. More recently, R. Betti et al. developed

Targeted tissue perfusion versus macrocirculation-guided standard care in patients with septic shock (TARTARE-2S)

DEFF Research Database (Denmark)

Pettilä, Ville; Merz, Tobias; Wilkman, Erika

2016-01-01

at least 200 patients with septic shock in four European intensive care units (ICUs) to test whether a tissue perfusion-guided treatment strategy based on capillary refill time, peripheral temperature, arterial lactate concentrations, and accepting lower MAP levels, leads to a faster resolution of shock...

Fluid-sensitive nanoscale switching with quantum levitation controlled by α -Sn/β -Sn phase transition

Science.gov (United States)

Boström, Mathias; Dou, Maofeng; Malyi, Oleksandr I.; Parashar, Prachi; Parsons, Drew F.; Brevik, Iver; Persson, Clas

2018-03-01

We analyze the Lifshitz pressure between silica and tin separated by a liquid mixture of bromobenzene and chlorobenzene. We show that the phase transition from semimetallic α -Sn to metallic β -Sn can switch Lifshitz forces from repulsive to attractive. This effect is caused by the difference in dielectric functions of α -Sn and β -Sn , giving both attractive and repulsive contributions to the total Lifshitz pressure in different frequency regions controlled by the composition of the intervening liquid mixture. In this way, one may be able to produce phase-transition-controlled quantum levitation in a liquid medium.

Magnetic Diagnostics on the Magnetized Shock Experiment (MSX)

Science.gov (United States)

Hutchinson, T. M.; Weber, T. E.; Boguski, J. C.; Intrator, T. P.; Smith, R. J.; Dunn, J. P.

2013-10-01

The Magnetized Shock Experiment (MSX) at Los Alamos National Laboratory was built to investigate the physics of high-Alfvénic, supercritical, magnetized shocks through the acceleration and subsequent stagnation of a Field Reversed Configuration (FRC) plasmoid against a magnetic mirror and/or plasma target. An array of high-bandwidth, multi-axis, robust, internal magnetic probes has been constructed to characterize flux compression ratios, instability formation, and turbulent macro-scale features of the post-shock plasma. The mirror magnet is mounted on a linear translation stage, providing a capability to axially move the shock layer through the probe field of view. An independent, external probe array also provides conventional information on the FRC shape, velocity, and total pressure during the formation and acceleration phases. Probe design, characterization, configuration, and initial results are presented. This work is supported by the DOE OFES and NNSA under LANS contract DE-AC52-06NA25369. LA-UR-13-25189.

α-Sn and β-Sn precipitates in annealed epitaxial Si_0.95Sn_0.05

DEFF Research Database (Denmark)

Fyhn, M.F.; Chevallier, J.; Larsen, A.N.

1999-01-01

-Sn and beta-Sn crystallites. The presence of alpha-Sn at temperatures far above the bulk alpha beta transition temperature is explained by interface and pressure effects; the latter is likely to be due to the difference in thermal expansion of the precipitates and the matrix.......-temperature molecular-beam epitaxy on Si (001) and relaxed Si1-xGex substrates. Two different phases of solid Sn were identified in the annealed layers: the semiconductor phase, alpha-Sn, and the metallic phase beta-Sn The precipitates were found to consist of either only beta-Sn or to contain crystallites of both...... solid Sn phases. The orientations, the sizes and the relative number densities of the alpha-Sn and beta-Sn crystallites were investigated. in situ heating and cooling experiments were performed in the transmission electron microscope to study the melting and solidification characteristics of the alpha...

Moving finite element method for ICF target implosion

Science.gov (United States)

Furuta, J.; Kawata, S.; Niu, K.

1985-03-01

One dimensional hydrodynamic codes for the analysis of internal confinement fusion (ICF) target implosion which include various effects were developed, but most of them utilize the artificial viscosity (e.g., Von Neumann's viscosity) which cannot reveal accurately the shock waves. A gain of ICF target implosion is much due to the dissipation at the shock fronts, so it is necessary to express correctly the shock waves which are affected by the viscosity. The width of the shock waves is usually a few times as large as the length of mean free path, therefore the meshes for the shock waves must be set to about 10 to the 4th to 10 to the 5th power. It is a serious problem because of the computational memories or CPU time. In the moving finite element (MPE) method, both nodal amplitudes and nodal positions move continuously with time in such a way as to satisfy simultaneous ordinary differential equations (OPDs) which minimize partial differential equation (PDE) residuals.

Preparation of PtSnCu/C and PtSn/C electrocatalysts and activation by dealloying processes for ethanol electrooxidation

International Nuclear Information System (INIS)

Crisafulli, Rudy

2013-01-01

PtSnCu/C (with different Pt:Sn:Cu atomic ratios) and PtSn/C (50:50) electrocatalysts were prepared by borohydride (BR) and alcohol-reduction (AR) processes using H 2 PtCl 6 .6H 2 O, SnCl 2 .2H 2 O and CuCl 2 .2H 2 O as metal sources, NaBH 4 and ethylene glycol as reducing agents, 2-propanol and ethylene glycol/water as solvents and carbon black as support. In a further step, these electrocatalysts were activated by chemical (CD) and electrochemical (ED) dealloying processes through acid treatment and thin porous coating technique, respectively. These materials were characterized by energy dispersive X-ray, Xray diffraction, transmission electron microscopy, line scan energy dispersive Xray and cyclic voltammetry. Electrochemical studies for ethanol electro-oxidation were performed by cyclic voltammetry, chronoamperometry and in single Direct Ethanol Fuel Cell using Membrane Electrode Assembly (MEA). The anodic effluents were analysed by gas chromatography. The X-ray diffractograms of the as-synthesized electrocatalysts showed the typical face-centered cubic structure (FCC) of platinum and its alloys. After dealloying, the X-ray diffractograms showed that the Pt FCC structure was preserved. The crystallite sizes of the assynthesized electrocatalysts were in the range of PtSnCu/C (50:40:10) AR/ED > PtSnCu/C (50:10:40) BR/CD. PtSn/C (50:50) BR/CD, PtSnCu/C (50:10:40) BR/CD, PtSnCu/C (50:40:10) AR/CD electrocatalysts and Pt/C BASF, PtSn/C (75:25) BASF commercial electrocatalysts were tested in single Direct Ethanol Fuel Cell. The results showed the following performance for ethanol electro-oxidation: PtSn/C (50:50) BR/CD > PtSnCu/C (50:40:10) AR/CD > PtSnCu/C > PtSn/C (75:25) BASF > PtSnCu/C (50:10:40) BR/CD > Pt/C BASF. (author)

Anomalous temperature behavior of Sn impurities

International Nuclear Information System (INIS)

Haskel, D.; Shechter, H.; Stern, E.A.; Newville, M.; Yacoby, Y.

1993-01-01

Sn impurities in Pb and Ag hosts have been investigated by Moessbauer effect and in Pb by x-ray-absorption fine-structure (XAFS) studies. The Sn atoms are dissolved up to at least 2 at. % in Pb and up to at least 8 at. % in Ag for the temperature ranges investigated. The concentration limit for Sn-Sn interactions is 1 at. % for Pb and 2 at. % for Ag as determined experimentally by lowering the Sn concentration until no appreciable change occurs in the Moessbauer effect. XAFS measurements verify that the Sn impurities in Pb are dissolved and predominantly at substitutional sites. For both hosts the temperature dependence of the spectral intensities of isolated Sn impurities below a temperature T 0 is as expected for vibrating about a lattice site. Above T 0 the Moessbauer spectral intensity exhibits a greatly increased rate of drop-off with temperature without appreciable broadening. This drop-off is too steep to be explained by ordinary anharmonic effects and can be explained by a liquidlike rapid hopping of the Sn, localized about a lattice site. Higher-entropy-density regions of radii somewhat more than an atomic spacing surround such impurities, and can act as nucleation sites for three-dimensional melting

Relative Shock Effects in Mixed Powders of Calcite, Gypsum, and Quartz: A Calibration Scheme from Shock Experiments

Science.gov (United States)

Bell, Mary S.

2009-01-01

The shock behavior of calcite and gypsum is important in understanding the Cretaceous/Tertiary event and other terrestrial impacts that contain evaporite sediments in their targets. Most interest focuses on issues of devolatilization to quantify the production of CO2 or SO2 to better understand their role in generating a temporary atmosphere and its effects on climate and biota [e.g., papers in 1,2,3,4]. Devolatilization of carbonate is also important because the dispersion and fragmentation of ejecta is strongly controlled by the expansion of large volumes of gas during the impact process as well [5,6]. Shock recovery experiments for calcite yield seemingly conflicting results: early experimental devolatilization studies [7,8,9] suggested that calcite was substantially outgassed at 30 GPa (> 50%). However, the recent petrographic work of [10,11,12] presented evidence that essentially intact calcite is recovered from 60 GPa experiments. [13] reported results of shock experiments on anhydrite, gypsum, and mixtures of those phases with silica. Their observations indicate little or no devolatilization of anhydrite shocked to 42 GPa and that the fraction of sulfur, by mass, that degassed is approx.10(exp -2) of theoretical prediction. In another (preliminary) report of shock experiments on calcite, anhydrite, and gypsum, [14] observe calcite recrystallization when shock loaded at 61 GPa, only intensive plastic deformation in anhydrite shock loaded at 63 GPa, and gypsum converted to anhydrite when shock loaded at 56 GPa. [15] shock loaded anhydrite and quartz to a peak pressure of 60 GPa. All of the quartz grains were trans-formed to glass and the platy anhydrite grains were completely pseudomorphed by small crystallized anhydrite grains. However, no evidence of interaction between the two phases could be observed and they suggest that recrystallization of anhydrite grains is the result of a solid state transformation. [16] reanalyzed the calcite and anhydrite shock

Effect of Sn Composition in Ge1- x Sn x Layers Grown by Using Rapid Thermal Chemical Vapor Deposition

Science.gov (United States)

Kil, Yeon-Ho; Kang, Sukill; Jeong, Tae Soo; Shim, Kyu-Hwan; Kim, Dae-Jung; Choi, Yong-Dae; Kim, Mi Joung; Kim, Taek Sung

2018-05-01

The Ge1- x Sn x layers were grown by using rapid thermal chemical-vapor deposition (RTCVD) on boron-doped p-type Si (100) substrates with Sn compositions up to x = 0.83%. In order to obtain effect of the Sn composition on the structural and the optical characteristics, we utilized highresolution X-ray diffraction (HR-XRD), etch pit density (EPD), atomic force microscopy (AFM), Raman spectroscopy, and photocurrent (PC) spectra. The Sn compositions in the Ge1- x Sn x layers were found to be of x = 0.00%, 0.51%, 0.65%, and 0.83%. The root-mean-square (RMS) of the surface roughness of the Ge1- x Sn x layer increased from 2.02 nm to 3.40 nm as the Sn composition was increased from 0.51% to 0.83%, and EPD was on the order of 108 cm-2. The Raman spectra consist of only one strong peak near 300 cm-1, which is assigned to the Ge-Ge LO peaks and the Raman peaks shift to the wave number with increasing Sn composition. Photocurrent spectra show near energy band gap peaks and their peak energies decrease with increasing Sn composition due to band-gap bowing in the Ge1- x Sn x layer. An increase in the band gap bowing parameter was observed with increasing Sn composition.

Synthesis, Characterization, and Photocatalytic Activity of Zn-Doped SnO2/Zn2SnO4 Coupled Nanocomposites

Directory of Open Access Journals (Sweden)

Tiekun Jia

2014-01-01

Full Text Available Zn-doped SnO2/Zn2SnO4 nanocomposites were prepared via a two-step hydrothermal synthesis method. The as-prepared samples were characterized by X-ray diffraction (XRD, field-emission scanning electron microscopy (FESEM, transmission electron microscopy (TEM, UV-vis diffuse reflection spectroscopy, and adsorption-desorption isotherms. The results of FESEM and TEM showed that the as-prepared Zn-doped SnO2/Zn2SnO4 nanocomposites are composed of numerous nanoparticles with the size ranging from 20 nm to 50 nm. The specific surface area of the as-prepared Zn-doped SnO2/Zn2SnO4 nanocomposites is estimated to be 71.53 m2/g by the Brunauer-Emmett-Teller (BET method. The photocatalytic activity was evaluated by the degradation of methylene blue (MB, and the resulting showed that Zn-doped SnO2/Zn2SnO4 nanocomposites exhibited excellent photocatalytic activity due to their higher specific surface area and surface charge carrier transfer.

Optimal exploration target zones

CSIR Research Space (South Africa)

Debba, Pravesh

2008-09-01

Full Text Available prospective map are the weights-of-evidence (WofE) method logistic regression canonical favorability analysis neural networks evidential belief functions Optimal Exploration Target Zones Debba, Carranza, Stein, van der Meer Introduction to Remote.... . . ): FITNESS FUNCTION φWMSD+V(Sn) = λ N(A) ∑ −→x ∈A P(−→x ) ∣ ∣ ∣ ∣−→x −QSn( −→x ) ∣ ∣ ∣ ∣ +(1− λ)s2(OSn) , (2) where QSn( −→x ) is the location vector of an optimal exploration focal point in Sn nearest to −→x , and s2(OSn) is the variance...

Oxidation and reduction kinetics of eutectic SnPb, InSn, and AuSn: a knowledge base for fluxless solder bonding applications

DEFF Research Database (Denmark)

Kuhmann, Jochen Friedrich; Preuss, A.; Adolphi, B.

1998-01-01

: (1) SnPb; (2) InSn; (3) AuSn. The studies of the oxidation kinetics show that the growth of the native oxide, which covers the solder surfaces from the start of all soldering operations is self-limiting. The rate of oxidation on the molten, metallic solder surfaces is significantly reduced...... and reduction kinetics, are applied to flip-chip (FC) bonding experiments in vacuum with and without the injection of H2. Wetting in vacuum is excellent but the self-alignment during flip-chip soldering is restricted. The desired, perfectly self-aligned FC-bonds have been only achieved, using evaporated...

$\\gamma$ and fast-timing spectroscopy of the doubly magic $^{132}$Sn and its one- and two-neutron particle/hole neighbours

CERN Multimedia

We propose to use fast-timing and spectroscopy to study five nuclei including the doubly magic $^{132}$Sn and its four neighbours: two-neutron hole $^{130}$Sn, one-neutron hole $^{131}$Sn, one-neutron particle $^{133}$Sn and two-neutron particle $^{134}$Sn. There is an increasing interest in these nuclei since they serve to test nuclear models using state-of-the-art interactions and many body approaches, and they provide information relevant to deduce single particle states. In addition properties of these nuclei are very important to model the astrophysical $\\textit{r-process}$. The present ISOLDE facility provides unique capabilities to study these Sn nuclei populated in the $\\beta$-decay of In isomers, produced from a UCx target unit equipped with neutron converter and ionized with RILIS, capable of selective isomer ionization. The increased production yields for $^{132}$In are estimated to be 200 larger than in the previous work done at OSIRIS. We will use the recently commissioned Isolde Decay Station (I...

Zn{sub 2}SnO{sub 4}-SnO{sub 2} heterojunction nanocomposites for dye-sensitized solar cells

Energy Technology Data Exchange (ETDEWEB)

Li Bihui; Luo Lijuan; Xiao Ting; Hu Xiaoyan [Institute of Nano-science and Technology, Central China Normal University, Wuhan, 430079 (China); Lu Lu; Wang, Jianbo [Department of Physics, Wuhan University, Wuhan 430072 (China); Tang Yiwen, E-mail: ywtang@phy.ccnu.edu.cn [Institute of Nano-science and Technology, Central China Normal University, Wuhan, 430079 (China)

2011-02-03

Graphical abstract: Display Omitted Research highlights: > The ZTO-SnO{sub 2} based DSSC shows superior photovoltaic performance than single phase ZTO or Pm-ZTO-SnO{sub 2} (physical mixture of ZTO and SnO{sub 2} nanoparticles having the same ZTO/SnO{sub 2} composition) based DSSC. > The obvious improvement in the photovoltaic performance is mainly ascribed to the efficient injected electrons transfer between the two materials via heterojunctions and consequent suppress the recombination. - Abstract: Zn{sub 2}SnO{sub 4}-SnO{sub 2} heterojunction nanocomposites (ZTO-SnO{sub 2}) with high mass amount of ZTO were synthesized by a two-step technique. The route involves firstly the synthesis of monodispersed ZnSn(OH){sub 6} nanocubes with a 50-60 nm edge length as precursors by simple coprecipitation of Na{sub 2}SnO{sub 3}.3H{sub 2}O and ZnCl{sub 2} aqueous solution, assisted by ultrasonic treatment and then followed by calcination of the precursors at 800 deg. C under N{sub 2} atmosphere. The as-synthesized nanoparticles were characterized by X-ray diffractometer (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). Heterojunction between ZTO and SnO{sub 2} nanoparticle was confirmed by the electron energy loss spectroscopy (EELS) elemental mapping and high-resolution TEM (HRTEM). The photovoltaic performance of the ZTO-SnO{sub 2} based DSSC was examined by measuring the J-V curves both in dark and under illumination. The results show that the ZTO-SnO{sub 2} based DSSC exhibits superior photovoltaic performance as compared to the single phase ZTO based DSSCs. Under illumination of AM 1.5 simulated sunlight (100 mW/cm{sup 2}), the open circuit voltage of the cell based on ZTO-SnO{sub 2} is 706 mV, the short-current density is 2.85 mA/cm{sup 2}, and the efficiency is 1.29% which is increased by 43% from 0.90% to 1.29% compared with pure ZTO. The formation of the heterojunctions between ZTO and SnO{sub 2} nanoparticles is believed to reduce

Physical properties of some Sn-based melts

Directory of Open Access Journals (Sweden)

Ilinykh N.

2011-05-01

Full Text Available The physical properties (viscosity, density, electroresistivity and magnetic susceptibility of pure tin, copper, silver, some binary (Sn - Ag, Sn - Cu, Sn - Bi, Sn - Zn and ternary (Sn-Ag-Cu, Sn-BiAg, Sn-Bi-Zn alloys with near eutectic compositions are investigated in wide temperature ranges. The irreversible decrease of viscosity in pure tin melt is discovered at 820 °С during heating. The similar anomaly with the following hysteresis of dynamic viscosity was fixed for binary and ternary alloys but at higher temperatures – 900 °С and 950 °С respectively. For all the systems it was shown that the alloys with eutectic compositions differ significantly in their electric and magnetic properties from hypo- and hypereutectic ones. Qualitative and quantitative metallographic analysis for Sn-3.8wt.%Ag-0.7wt.%Cu samples, heated low and above characteristic temperatures, showed the influence of melt overheating on crystallization kinetics.

2-Shock layered tuning campaign

Science.gov (United States)

Masse, Laurent; Dittrich, T.; Khan, S.; Kyrala, G.; Ma, T.; MacLaren, S.; Ralph, J.; Salmonson, J.; Tipton, R.; Los Alamos Natl Lab Team; Lawrence Livermore Natl Lab Team

2016-10-01

The 2-Shock platform has been developed to maintain shell sphericity throughout the compression phase of an indirect-drive target implosion and produce a stagnating hot spot in a quasi 1D-like manner. A sub-scale, 1700 _m outer diameter, and thick, 200 _m, uniformly Silicon doped, gas-filled plastic capsule is driven inside a nominal size 5750 _m diameter ignition hohlraum. The hohlraum fill is near vacuum to reduce back-scatter and improve laser/drive coupling. A two-shock pulse of about 1 MJ of laser energy drives the capsule. The thick capsule prevents ablation front feed-through to the imploded core. This platform has demonstrated its efficiency to tune a predictable and reproducible 1-D implosion with a nearly round shape. It has been shown that the high foot performance was dominated by the local defect growth due to the ablation front instability and by the hohlraum radiation asymmetries. The idea here is to take advantage of this 2-Shock platform to design a 1D-like layered implosion and eliminates the deleterious effects of radiation asymmetries and ablation front instability growth. We present the design work and our first experimental results of this near one-dimensional 2-Shock layered design. This work was performed under the auspices of the Lawrence Livermore National Security, LLC, (LLNS) under Contract No. DE-AC52-07NA27344.

Implication of Heat Shock Factors in Tumorigenesis: Therapeutical Potential

Energy Technology Data Exchange (ETDEWEB)

Thonel, Aurelie de [INSERM U866, Dijon (France); Faculty of Medicine and Pharmacy, University of Burgundy, 21033 Dijon (France); Mezger, Valerie, E-mail: valerie.mezger@univ-paris-diderot.fr [CNRS, UMR7216 Epigenetics and Cell Fate, Paris (France); University Paris Diderot, 75013 Paris (France); Garrido, Carmen, E-mail: valerie.mezger@univ-paris-diderot.fr [INSERM U866, Dijon (France); Faculty of Medicine and Pharmacy, University of Burgundy, 21033 Dijon (France); CHU, Dijon BP1542, Dijon (France)

2011-03-07

Heat Shock Factors (HSF) form a family of transcription factors (four in mammals) which were named according to the discovery of their activation by a heat shock. HSFs trigger the expression of genes encoding Heat Shock Proteins (HSPs) that function as molecular chaperones, contributing to establish a cytoprotective state to various proteotoxic stresses and in pathological conditions. Increasing evidence indicates that this ancient transcriptional protective program acts genome-widely and performs unexpected functions in the absence of experimentally defined stress. Indeed, HSFs are able to re-shape cellular pathways controlling longevity, growth, metabolism and development. The most well studied HSF, HSF1, has been found at elevated levels in tumors with high metastatic potential and is associated with poor prognosis. This is partly explained by the above-mentioned cytoprotective (HSP-dependent) function that may enable cancer cells to adapt to the initial oncogenic stress and to support malignant transformation. Nevertheless, HSF1 operates as major multifaceted enhancers of tumorigenesis through, not only the induction of classical heat shock genes, but also of “non-classical” targets. Indeed, in cancer cells, HSF1 regulates genes involved in core cellular functions including proliferation, survival, migration, protein synthesis, signal transduction, and glucose metabolism, making HSF1 a very attractive target in cancer therapy. In this review, we describe the different physiological roles of HSFs as well as the recent discoveries in term of non-cogenic potential of these HSFs, more specifically associated to the activation of “non-classical” HSF target genes. We also present an update on the compounds with potent HSF1-modulating activity of potential interest as anti-cancer therapeutic agents.

Implication of Heat Shock Factors in Tumorigenesis: Therapeutical Potential

International Nuclear Information System (INIS)

Thonel, Aurelie de; Mezger, Valerie; Garrido, Carmen

2011-01-01

Heat Shock Factors (HSF) form a family of transcription factors (four in mammals) which were named according to the discovery of their activation by a heat shock. HSFs trigger the expression of genes encoding Heat Shock Proteins (HSPs) that function as molecular chaperones, contributing to establish a cytoprotective state to various proteotoxic stresses and in pathological conditions. Increasing evidence indicates that this ancient transcriptional protective program acts genome-widely and performs unexpected functions in the absence of experimentally defined stress. Indeed, HSFs are able to re-shape cellular pathways controlling longevity, growth, metabolism and development. The most well studied HSF, HSF1, has been found at elevated levels in tumors with high metastatic potential and is associated with poor prognosis. This is partly explained by the above-mentioned cytoprotective (HSP-dependent) function that may enable cancer cells to adapt to the initial oncogenic stress and to support malignant transformation. Nevertheless, HSF1 operates as major multifaceted enhancers of tumorigenesis through, not only the induction of classical heat shock genes, but also of “non-classical” targets. Indeed, in cancer cells, HSF1 regulates genes involved in core cellular functions including proliferation, survival, migration, protein synthesis, signal transduction, and glucose metabolism, making HSF1 a very attractive target in cancer therapy. In this review, we describe the different physiological roles of HSFs as well as the recent discoveries in term of non-cogenic potential of these HSFs, more specifically associated to the activation of “non-classical” HSF target genes. We also present an update on the compounds with potent HSF1-modulating activity of potential interest as anti-cancer therapeutic agents

Spliceosomal small nuclear RNAs of Tetrahymena thermophila and some possible snRNA-snRNA base-pairing interactions

DEFF Research Database (Denmark)

Orum, H; Nielsen, Henrik; Engberg, J

1991-01-01

We have identified and characterized the full set of spliceosomal small nuclear RNAs (snRNAs; U1, U2, U4, U5 and U6) from the ciliated protozoan Tetrahymena thermophila. With the exception of U4 snRNA, the sizes of the T. thermophila snRNAs are closely similar to their metazoan homologues. The T....... thermophila snRNAs all have unique 5' ends, which start with an adenine residue. In contrast, with the exception of U6, their 3' ends show some size heterogeneity. The primary sequences of the T. thermophila snRNAs contain the sequence motifs shown, or proposed, to be of functional importance in other...

The interfacial free energy of solid Sn on the boundary interface with liquid Cd-Sn eutectic solution

International Nuclear Information System (INIS)

Saatci, B; Cimen, S; Pamuk, H; Guenduez, M

2007-01-01

Equilibrated grain boundary groove shapes for solid Sn in equilibrium with Cd-Sn liquid were directly observed after annealing a sample at the eutectic temperature for about 8 days. The thermal conductivities of the solid phase, K S , and the liquid phase, K L , for the groove shapes were measured. From the observed groove shapes, the Gibbs-Thomson coefficients were obtained with a numerical method, using the measured G, K S and K L values. The solid-liquid interfacial energy of solid Sn in equilibrium with Cd-Sn liquid was determined from the Gibbs-Thomson equation. The grain boundary energy for solid Sn was also calculated from the observed groove shapes

Microstructural evolution and tensile properties of Sn-Ag-Cu mixed with Sn-Pb solder alloys

Energy Technology Data Exchange (ETDEWEB)

Wang Fengjiang [Department of Materials Science and Engineering and Materials Research Center, Missouri University of Science and Technology, Rolla, MO 65401 (United States); O' Keefe, Matthew [Department of Materials Science and Engineering and Materials Research Center, Missouri University of Science and Technology, Rolla, MO 65401 (United States)], E-mail: mjokeefe@mst.edu; Brinkmeyer, Brandon [Department of Materials Science and Engineering and Materials Research Center, Missouri University of Science and Technology, Rolla, MO 65401 (United States)

2009-05-27

The effect of incorporating eutectic Sn-Pb solder with Sn-3.0Ag-0.5Cu (SAC) Pb-free solder on the microstructure and tensile properties of the mixed alloys was investigated. Alloys containing 100, 75, 50, 25, 20, 15, 10, 5 and 0 wt% SAC, with the balance being Sn-37Pb eutectic solder alloy, were prepared and characterized. Optical and scanning electron microscopy were used to analyze the microstructures while 'mini-tensile' test specimens were fabricated and tested to determine mechanical properties at the mm length scale, more closely matching that of the solder joints. Microstructural analysis indicated that a Pb-rich phase formed and was uniformly distributed at the boundary between the Sn-rich grains or between the Sn-rich and the intermetallic compounds in the solder. Tensile results showed that mixing of the alloys resulted in an increase in both the yield and the ultimate tensile strength compared to the original solders, with the 50% SAC-50% Sn-Pb mixture having the highest measured strength. Initial investigations indicate the formation and distribution of a Pb-rich phase in the mixed solder alloys as the source of the strengthening mechanism.

α-Eleostearic acid-containing triglycerides for a continuous assay to determine lipase sn-1 and sn-3 regio-preference.

Science.gov (United States)

El Alaoui, Meddy; Soulère, Laurent; Noiriel, Alexandre; Queneau, Yves; Abousalham, Abdelkarim

2017-08-01

Lipases are essentially described as sn-1 and sn-3 regio-selective. Actually few methods are available to measure this lipase regio-selectivity, moreover they require chiral chromatography analysis or specific derivations which are discontinuous and time consuming. In this study we describe a new, convenient, sensitive and continuous spectrophotometric method to screen lipases regio-selectivity using synthetic triglycerides (TG) containing α-eleostearic acid (9Z, 11E, 13E-octadecatrienoic acid) either at the sn-1 position [1-α-eleostearoyl-2,3-octadecyl-sn-glycerol (sn-EOO)] or at the sn-3 position [1,2-octadecyl-3-α-eleostearoyl-sn-glycerol (sn-OOE)] and coated onto the wells of microtiter plates. A non-hydrolysable ether bond, with a non UV-absorbing alkyl chain, was introduced at the other sn positions to prevent acyl chain migration during TG synthesis or lipolysis. The synthesis of TG containing α-eleostearic acid was performed from S-glycidol in six steps to obtain sn-EOO and in five steps to sn-OOE. The α-eleostearic acid conjugated triene constitutes an intrinsic chromophore and, consequently, confers the strong UV absorption properties of this free fatty acid as well as of the TG harboring it. The lipase activity on coated sn-EOO or sn-OOE was measured by the increase in the absorbance at 272nm due to the transition of α-eleostearic acid from the adsorbed to the soluble state. Human and porcine pancreatic lipases, guinea pig pancreatic lipase related protein 2, Thermomyces lanuginosus lipase, Candida antarctica lipase A and Candida antarctica lipase B were all used to validate the assay. This continuous high-throughput screening method could determine directly without any processes after lipolysis the regio-selectivity of various lipases. Copyright © 2017 Elsevier B.V. All rights reserved.

X-RAY AND RADIO EMISSION FROM TYPE IIn SUPERNOVA SN 2010jl

Energy Technology Data Exchange (ETDEWEB)

Chandra, Poonam [National Centre for Radio Astrophysics, Tata Institute of Fundamental Research, Pune University Campus, Pune 411 007 (India); Chevalier, Roger A. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904-4325 (United States); Chugai, Nikolai [Institute of Astronomy of Russian Academy of Sciences, Pyatnitskaya St. 48, 109017 Moscow (Russian Federation); Fransson, Claes [Oskar Klein Centre, Department of Astronomy, Stockholm University, AlbaNova, SE-106 91 Stockholm (Sweden); Soderberg, Alicia M., E-mail: poonam@ncra.tifr.res.in [Smithsonian Astrophysical Observatory, 60 Garden St., MS-20, Cambridge, MA 02138 (United States)

2015-09-01

We present all X-ray and radio observations of the Type IIn supernova SN 2010jl. The X-ray observations cover a period up to day 1500 with Chandra, XMM-Newton, NuSTAR, and Swift-X-ray Telescope (XRT). The Chandra observations after 2012 June, the XMM-Newton observation in 2013 November, and most of the Swift-XRT observations until 2014 December are presented for the first time. All the spectra can be fitted by an absorbed hot thermal model except for Chandra spectra on 2011 October and 2012 June when an additional component is needed. Although the origin of this component is uncertain, it is spatially coincident with the supernova and occurs when there are changes to the supernova spectrum in the energy range close to that of the extra component, indicating that the emission is related to the supernova. The X-ray light curve shows an initial plateau followed by a steep drop starting at day ∼300. We attribute the drop to a decrease in the circumstellar density. The column density to the X-ray emission drops rapidly with time, showing that the absorption is in the vicinity of the supernova. We also present Very Large Array radio observations of SN 2010jl. Radio emission was detected from SN 2010jl from day 570 onwards. The radio light curves and spectra suggest that the radio luminosity was close to its maximum at the first detection. The velocity of the shocked ejecta derived assuming synchrotron self-absorption is much less than that estimated from the optical and X-ray observations, suggesting that free–free absorption dominates.

Effect of Pt:Sn atomic ratio on the preparation of PtSn/C electrocatalysts using electron beam irradiation

Energy Technology Data Exchange (ETDEWEB)

Silva, Dionisio F.; Oliveira Neto, Almir; Pino, Eddy S.; Linardi, Marcelo; Spinace, Estevam V., E-mail: dfsilva@ipen.b, E-mail: espinace@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)

2009-07-01

PtSn/C electrocatalysts were prepared with Pt:Sn atomic ratios of 3:1, 1:1 and 1:3 in water/2-propanol using electron beam irradiation. The obtained materials were characterized by EDX, XRD and cyclic voltammetry. The ethanol electro-oxidation was studied by chronoamperometry. The XRD diffractograms of the PtSn/C electrocatalysts showed typical face-centered cubic (fcc) structure of platinum and the presence of a SnO{sub 2} phase (cassiterite). The mean crystallite sizes of Pt fcc phase was in the range of 3.0-3.5 nm. The PtSn/C electrocatalysts were active for ethanol electro-oxidation at room temperature and the material prepared with Pt:Sn atomic ratio of 1:1 showed the best activity. (author)

Effect of Pt:Sn atomic ratio on the preparation of PtSn/C electrocatalysts using electron beam irradiation

International Nuclear Information System (INIS)

Silva, Dionisio F.; Oliveira Neto, Almir; Pino, Eddy S.; Linardi, Marcelo; Spinace, Estevam V.

2009-01-01

PtSn/C electrocatalysts were prepared with Pt:Sn atomic ratios of 3:1, 1:1 and 1:3 in water/2-propanol using electron beam irradiation. The obtained materials were characterized by EDX, XRD and cyclic voltammetry. The ethanol electro-oxidation was studied by chronoamperometry. The XRD diffractograms of the PtSn/C electrocatalysts showed typical face-centered cubic (fcc) structure of platinum and the presence of a SnO 2 phase (cassiterite). The mean crystallite sizes of Pt fcc phase was in the range of 3.0-3.5 nm. The PtSn/C electrocatalysts were active for ethanol electro-oxidation at room temperature and the material prepared with Pt:Sn atomic ratio of 1:1 showed the best activity. (author)

Shock Dynamics in Stellar Outbursts. I. Shock Formation

Energy Technology Data Exchange (ETDEWEB)

Ro, Stephen; Matzner, Christopher D., E-mail: ro@astro.utoronto.ca [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street, Toronto, ON M5S 3H4 (Canada)

2017-05-20

Wave-driven outflows and non-disruptive explosions have been implicated in pre-supernova outbursts, supernova impostors, luminous blue variable eruptions, and some narrow-line and superluminous supernovae. To model these events, we investigate the dynamics of stars set in motion by strong acoustic pulses and wave trains, focusing on nonlinear wave propagation, shock formation, and an early phase of the development of a weak shock. We identify the shock formation radius, showing that a heuristic estimate based on crossing characteristics matches an exact expansion around the wave front and verifying both with numerical experiments. Our general analytical condition for shock formation applies to one-dimensional motions within any static environment, including both eruptions and implosions. We also consider the early phase of shock energy dissipation. We find that waves of super-Eddington acoustic luminosity always create shocks, rather than damping by radiative diffusion. Therefore, shock formation is integral to super-Eddington outbursts.

Political shocks and public debt: The case for a conservative central bank revisited

NARCIS (Netherlands)

Beetsma, R.M.W.J.; Bovenberg, A.L.

2006-01-01

We explore the dynamics of public debt and optimal institutions in the presence of political shocks arising from electoral uncertainty. Under commitment, optimal stabilization is established by combining an inflation target with a debt target. The inflation target should be contingent on the

Properties of second phase (BaSnO3, Sn) added-YBCO thick films

International Nuclear Information System (INIS)

Ban, E.; Matsuoka, Y.

1997-01-01

The improvement of the critical current density J c of YBCO thick films has been attempted by adding BaSnO 3 powder and ultrafine Sn particles, whose diameter is about 2 μm and 7 x 10 -2 μm, respectively. It was found that the addition of a small amount of these particles was effective for the enhancement of J c of thick films prepared by a liquid-phase processing method. The 1 wt.% BaSnO 3 films fired at T s =1040-1060 C and the 3 wt.% Sn films (T s =1030-1060 C) showed J c values (77 K, 0 T) of about 2.1-2.4 x 10 3 Acm -2 and 3.1-3.5 x 10 3 Acm -2 , respectively, as compared to 2.0 x 10 3 Acm -2 for the undoped films. (orig.)

Late-time spectral line formation in Type IIb supernovae, with application to SN 1993J, SN 2008ax, and SN 2011dh

Science.gov (United States)

Jerkstrand, A.; Ergon, M.; Smartt, S. J.; Fransson, C.; Sollerman, J.; Taubenberger, S.; Bersten, M.; Spyromilio, J.

2015-01-01

We investigate line formation processes in Type IIb supernovae (SNe) from 100 to 500 days post-explosion using spectral synthesis calculations. The modelling identifies the nuclear burning layers and physical mechanisms that produce the major emission lines, and the diagnostic potential of these. We compare the model calculations with data on the three best observed Type IIb SNe to-date - SN 1993J, SN 2008ax, and SN 2011dh. Oxygen nucleosynthesis depends sensitively on the main-sequence mass of the star and modelling of the [O I] λλ6300, 6364 lines constrains the progenitors of these three SNe to the MZAMS = 12-16 M⊙ range (ejected oxygen masses 0.3-0.9 M⊙), with SN 2011dh towards the lower end and SN 1993J towards the upper end of the range. The high ejecta masses from MZAMS ≳ 17 M⊙ progenitors give rise to brighter nebular phase emission lines than observed. Nucleosynthesis analysis thus supports a scenario of low-to-moderate mass progenitors for Type IIb SNe, and by implication an origin in binary systems. We demonstrate how oxygen and magnesium recombination lines may be combined to diagnose the magnesium mass in the SN ejecta. For SN 2011dh, a magnesium mass of 0.02-0.14 M⊙ is derived, which gives a Mg/O production ratio consistent with the solar value. Nitrogen left in the He envelope from CNO burning gives strong [N II] λλ6548, 6583 emission lines that dominate over Hα emission in our models. The hydrogen envelopes of Type IIb SNe are too small and dilute to produce any noticeable Hα emission or absorption after ~150 days, and nebular phase emission seen around 6550 Å is in many cases likely caused by [N II] λλ6548, 6583. Finally, the influence of radiative transport on the emergent line profiles is investigated. Significant line blocking in the metal core remains for several hundred days, which affects the emergent spectrum. These radiative transfer effects lead to early-time blueshifts of the emission line peaks, which gradually

Sn surface-enriched Pt-Sn bimetallic nanoparticles as a selective and stable catalyst for propane dehydrogenation

KAUST Repository

Zhu, Haibo; Anjum, Dalaver H.; Wang, Qingxiao; Abou-Hamad, Edy; Emsley, Lyndon; Dong, Hailin; Laveille, Paco; Li, Lidong; Samal, Akshaya Kumar; Basset, Jean-Marie

2014-01-01

Sn(n-C4H9) are chemically linked to the surface of Pt NPs to produce, in fine, after removal of most of the n-butyl fragment, bimetallic Pt-Sn nanoparticles. The Sn(n-CH2CH2CH2CH3) groups remaining at the surface are believed to stabilize the as

A highly stable (SnOx-Sn)@few layered graphene composite anode of sodium-ion batteries synthesized by oxygen plasma assisted milling

Science.gov (United States)

Cheng, Deliang; Liu, Jiangwen; Li, Xiang; Hu, Renzong; Zeng, Meiqing; Yang, Lichun; Zhu, Min

2017-05-01

The (SnOx-Sn)@few layered graphene ((SnOx-Sn)@FLG) composite has been synthesized by oxygen plasma-assisted milling. Owing to the synergistic effect of rapid plasma heating and ball mill grinding, SnOx (1 ≤ x ≤ 2) nanoparticles generated from the reaction of Sn with oxygen are tightly wrapped by FLG nanosheets which are simultaneously exfoliated from expanded graphite, forming secondary micro granules. Inside the granules, the small size of the SnOx nanoparticles enables the fast kinetics for Na+ transfer. The in-situ formed FLG and residual Sn nanoparticles improve the electrical conductivity of the composite, meanwhile alleviate the aggregation of SnOx nanoparticles and relieve the volume change during the cycling, which is beneficial for the cyclic stability for the Na+ storage. As an anode material for sodium-ion batteries, the (SnOx-Sn)@FLG composite exhibits a high reversible capacity of 448 mAh g-1 at a current density of 100 mA g-1 in the first cycle, with 82.6% capacity retention after 250 cycles. Even when the current density increases to 1000 mA g-1, this composite retains 316.5 mAh g-1 after 250 cycles. With superior Na+ storage stability, the (SnOx-Sn)@FLG composite can be a promising anode material for high performance sodium-ion batteries.

Loss of proteostatic control as a substrate for Atrial Fibrillation; a novel target for upstream therapy by Heat Shock Proteins

Directory of Open Access Journals (Sweden)

Roelien Amanda Marjolein Meijering

2012-02-01

Full Text Available Atrial Fibrillation (AF is the most common, sustained clinical tachyarrhythmia associated with significant morbidity and mortality. AF is a persistent condition with progressive structural remodeling of the atrial cardiomyocytes due to the AF itself, resulting in cellular changes commonly observed in ageing and in other heart diseases. While rhythm control by electrocardioversion or drug treatment is the treatment of choice in symptomatic AF patients, its effectiveness is still limited. Current research is directed at preventing new-onset AF by limiting the development of substrates underlying AF promotion and resembles mechanism-based therapy. Upstream therapy refers to the use of non-ion channel anti-arrhythmic drugs that modify the atrial substrate- or target-specific mechanisms of AF, with the ultimate aim to prevent the occurrence (primary prevention or recurrence of the arrhythmia following (spontaneous conversion (secondary prevention.Heat shock proteins (HSPs are molecular chaperones and comprise a large family of proteins involved in the protection against various forms of cellular stress. Their classical function is the conservation of proteostasis via prevention of toxic protein aggregation by binding to (partially unfolded proteins. Our recent data reveal that HSPs prevent electrical, contractile and structural remodeling of cardiomyocytes, thus attenuating the AF substrate in cellular, Drosophila melanogaster and animal experimental models. Furthermore, studies in humans suggest a protective role for HSPs against the progression from paroxysmal AF to persistent AF and in recurrence of AF. In this review, we discuss upregulation of the heat shock response system as a novel target for upstream therapy to prevent derailment of proteostasis and consequently promotion and recurrence of AF.

Electronic structure and electric fields gradients of crystalline Sn(II) and Sn(IV) compounds

International Nuclear Information System (INIS)

Terra, J.; Guenzburger, D.

1991-01-01

The electronic structures of clusters representing crystalline compounds of Sn(II) and Sn(IV) were investigated, employing the first-principles Discrete Variational method and Local Density theory. Densities of states and related parameters were obtained and compared with experimental measurements and with results from band structure calculations. Effects of cluster size and of cluster truncated bonds are discussed. Electric field gradients at the Sn nucleus were calculated; results are analysed in terms of charge distribution and chemical bonding in the crystals. (author)

Generation of sub-gigabar-pressure shocks by a hyper-velocity impact in the collider driven by laser-induced cavity pressure

Science.gov (United States)

Badziak, J.; Kucharik, M.; Liska, R.

2018-02-01

The generation of high-pressure shocks in the newly proposed collider in which the projectile impacting a solid target is driven by the laser-induced cavity pressure acceleration (LICPA) mechanism is investigated using two-dimensional hydrodynamic simulations. The dependence of parameters of the shock generated in the target by the impact of a gold projectile on the impacted target material and the laser driver energy is examined. It is found that both in case of low-density (CH, Al) and high-density (Au, Cu) solid targets the shock pressures in the sub-Gbar range can be produced in the LICPA-driven collider with the laser energy of only a few hundreds of joules, and the laser-to-shock energy conversion efficiency can reach values of 10 - 20 %, by an order of magnitude higher than the conversion efficiencies achieved with other laser-based methods used so far.

SN 1986J VLBI. IV. The Nature of the Central Component

Science.gov (United States)

Bietenholz, Michael F.; Bartel, Norbert

2017-12-01

We report on Very Large Array measurements between 1 and 45 GHz of the evolving radio spectral energy distribution (SED) of SN 1986J, made in conjunction with very long baseline interferometry (VLBI) imaging. The SED of SN 1986J is unique among supernovae, and shows an inversion point and a high-frequency turnover. Both are due to the central component seen in the VLBI images, and both are progressing downward in frequency with time. The optically thin spectral index of the central component is almost the same as that of the shell. We fit a simple model to the evolving SED consisting of an optically thin shell and a partly absorbed central component. The evolution of the SED is consistent with that of a homologously expanding system. Both components are fading, but the shell is fading more rapidly. We conclude that the central component is physically inside the expanding shell, and not a surface hotspot central only in projection. Our observations are consistent with the central component being due to interaction of the shock with the dense and highly structured circumstellar medium that resulted from a period of common-envelope evolution of the progenitor. However, a young pulsar-wind nebula or emission from an accreting black hole can also not be ruled out at this point.

Synthesis of Pt{sub 75}Sn{sub 25}/SnO{sub 2}/CNT nanoscaled electrode: Low onset potential of ethanol electrooxidation

Energy Technology Data Exchange (ETDEWEB)

Tabet-Aoul, Amel [Institut National de la Recherche Scientifique (INRS)-Énergie, Matériaux et Télécommunications (EMT), 1650 Boulevard Lionel Boulet, Varennes, Québec, Canada J3X 1S2 (Canada); Mohamedi, Mohamed, E-mail: mohamedi@emt.inrs.ca [Institut National de la Recherche Scientifique (INRS)-Énergie, Matériaux et Télécommunications (EMT), 1650 Boulevard Lionel Boulet, Varennes, Québec, Canada J3X 1S2 (Canada)

2013-03-15

Highlights: ► A pulsed laser synthesis is used for the deposition of Pt, SnO{sub 2} and PtSn alloy thin films onto carbon nanotubes. ► These nanoscaled materials were characterized by FESEM, TEM, XRD and XPS. ► Enhanced electrocatalytic properties toward ethanol oxidation. -- Abstract: With the objective of lowering the potential oxidation of ethanol at PtSn nanocatalyst, we present the synthesis of free-standing catalyst layer comprising a current collector/carbon nanotubes (catalyst support)/SnO{sub 2}/Pt{sub 75}Sn{sub 25} (catalyst) nanostructured layers, each layer constructed upon the one below it. The CNTs are grown by chemical vapor deposition (CVD), whereas SnO{sub 2} and Pt{sub 75}Sn{sub 25} are synthesized by pulsed laser deposition and cross-beam laser deposition, respectively. FESEM revealed that Pt{sub 75}Sn{sub 25} nanoparticles assemble into cauliflower-like arrangement. TEM and HR-TEM showed that the Pt{sub 75}Sn{sub 25} layer thickness is of ca. 25 nm with a particle mean diameter of 4.3 nm. It was found that addition of SnO{sub 2} to Pt{sub 75}Sn{sub 25} promotes significantly the oxidation of ethanol at Pt{sub 75}Sn{sub 25} nanoparticles relative to a carbon nanotubes support. Indeed, the electrooxidation of ethanol at CNTs/SnO{sub 2}/Pt{sub 75}Sn{sub 25} electrode starts at about 100 mV negative with respect to that at CNT/Pt{sub 75}Sn{sub 25}. This decreased overpotential required to oxidize ethanol is very significant and has profound implications to developing high performing anodes for direct ethanol fuel cells technology.

Massive stars dying alone: Extremely remote environments of SN2009ip and SN2010jp

Science.gov (United States)

Smith, Nathan

2014-10-01

We propose an imaging study of the astonishingly remote environments of two recent supernovae (SNe): SN2009ip and SN2010jp. Both were unusual Type IIn explosions that crashed into dense circumstellar material (CSM) ejected by the star shortly before explosion. The favored progenitors of these SNe are very massive luminous blue variable (LBV) stars. In fact, SN2009ip presents an extraordinay case where the LBV-like progenitor was actually detected directly in archival HST data, and where we obtained spectra and photometry for numerous pre-SN eruptions. No other SN has this treasure trove of detailed information about the progenitor (not even SN1987A). SN2010jp represents a possible collapsar-powered event, since it showed evidence of a fast bipolar jet in spectra and a low 56Ni mass; this would be an analog of the black-hole forming explosions that cause gamma ray bursts, but where the relativistic jet is damped by a residual H envelope on the star. In both cases, the only viable models for these SNe involve extremely massive (initial masses of 40-100 Msun) progenitor stars. This seems at odds with their extremely remote environments in the far outskirts of their host galaxies, with no detected evidence for an underlying massive star population in ground-based data (nor in the single shallow WFPC2/F606W image of SN2009ip). Here we propose deep UV HST images to search for any mid/late O-type stars nearby, deep red images to detect any red supergiants, and an H-alpha image to search for any evidence of ongoing star formation in the vicinity. These observations will place important and demanding constraints on the initial masses and ages of these progenitors.

WSEAT Shock Testing Margin Assessment Using Energy Spectra Final Report.

Energy Technology Data Exchange (ETDEWEB)

Sisemore, Carl; Babuska, Vit; Booher, Jason

2018-02-01

Several programs at Sandia National Laboratories have adopted energy spectra as a metric to relate the severity of mechanical insults to structural capacity. The purpose being to gain insight into the system's capability, reliability, and to quantify the ultimate margin between the normal operating envelope and the likely system failure point -- a system margin assessment. The fundamental concern with the use of energy metrics was that the applicability domain and implementation details were not completely defined for many problems of interest. The goal of this WSEAT project was to examine that domain of applicability and work out the necessary implementation details. The goal of this project was to provide experimental validation for the energy spectra based methods in the context of margin assessment as they relate to shock environments. The extensive test results concluded that failure predictions using energy methods did not agree with failure predictions using S-N data. As a result, a modification to the energy methods was developed following the form of Basquin's equation to incorporate the power law exponent for fatigue damage. This update to the energy-based framework brings the energy based metrics into agreement with experimental data and historical S-N data.

Cytoplasmic assembly of snRNP particles from stored proteins and newly transcribed snRNA's in L929 mouse fibroblasts

International Nuclear Information System (INIS)

Sauterer, R.A.; Feeney, R.J.; Zieve, G.W.

1988-01-01

Newly synthesized snRNAs appear transiently in the cytoplasm where they assemble into ribonucleoprotein particles, the snRNP particles, before returning permanently to the interphase nucleus. In this report, bona fide cytoplasmic fractions, prepared by cell enucleation, are used for a quantitative analysis of snRNP assembly in growing mouse fibroblasts. The half-lives and abundances of the snRNP precursors in the cytoplasm and the rates of snRNP assembly are calculated in L929 cells. With the exception of U6, the major snRNAs are stable RNA species; U1 is almost totally stable while U2 has a half-life of about two cell cycles. In contrast, the majority of newly synthesized U6 decays with a half-life of about 15 h. The relative abundances of the newly synthesized snRNA species U1, U2, U3, U4 and U6 in the cytoplasm are determined by Northern hybridization using cloned probes and are approximately 2% of their nuclear abundance. The half-lives of the two major snRNA precursors in the cytoplasm (U1 and U2) are approximately 20 min as determined by labeling to steady state. The relative abundance of the snRNP B protein in the cytoplasm is determined by Western blotting with the Sm class of autoantibodies and is approximately 25% of the nuclear abundance. Kinetic studies, using the Sm antiserum to immunoprecipitate the methionine-labeled snRNP proteins, suggest that the B protein has a half-life of 90 to 120 min in the cytoplasm. These data are discussed and suggest that there is a large pool of more stable snRNP proteins in the cytoplasm available for assembly with the less abundant but more rapidly turning-over snRNAs

Time to achieve target mean arterial pressure during resuscitation from experimental anaphylactic shock in an animal model. A comparison of adrenaline alone or in combination with different volume expanders.

Science.gov (United States)

Tajima, K; Zheng, F; Collange, O; Barthel, G; Thornton, S N; Longrois, D; Levy, B; Audibert, G; Malinovsky, J M; Mertes, P M

2013-11-01

Anaphylactic shock is a rare, but potentially lethal complication, combining life-threatening circulatory failure and massive fluid shifts. Treatment guidelines rely on adrenaline and volume expansion by intravenous fluids, but there is no solid evidence for the choice of one specific type of fluid over another. Our purpose was to compare the time to achieve target mean arterial pressure upon resuscitation using adrenaline alone versus adrenaline with different resuscitation fluids in an animal model and to compare the tissue oxygen pressures (PtiO2) with the various strategies. Twenty-five ovalbumin-sensitised Brown Norway rats were allocated to five groups after anaphylactic shock induction: vehicle (CON), adrenaline alone (AD), or adrenaline with isotonic saline (AD+IS), hydroxyethyl starch (AD+HES) or hypertonic saline (AD+HS). Time to reach a target mean arterial pressure value of 75 mmHg, cardiac output, skeletal muscle PtiO2, lactate/pyruvate ratio and cumulative doses of adrenaline were recorded. Non-treated rats died within 15 minutes. The target mean arterial pressure value was reached faster with AD+HES (median: 10 minutes, range: 7.5 to 12.5 minutes) and AD+IS (median: 17.5 minutes, range: 5 to 25 minutes) versus adrenaline alone (median: 25 minutes, range: 20-30 minutes). There were also reduced adrenaline requirements in these groups. The skeletal muscle PtiO2 was restored only in the AD+HES group. Although direct extrapolation to humans should be made with caution, our results support the combined use of adrenaline and volume expansion for resuscitation from anaphylactic shock. When used with adrenaline the most effective fluid was hydroxyethyl starch, whereas hypertonic saline was the least effective.

Shock timing measurements and analysis in deuterium-tritium-ice layered capsule implosions on NIF

Energy Technology Data Exchange (ETDEWEB)

Robey, H. F.; Celliers, P. M.; Moody, J. D.; Sater, J.; Parham, T.; Kozioziemski, B.; Dylla-Spears, R.; Ross, J. S.; LePape, S.; Ralph, J. E.; Dewald, E. L.; Berzak Hopkins, L.; Kroll, J. J.; Yoxall, B. E.; Hamza, A. V.; Landen, O. L.; Edwards, M. J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Hohenberger, M.; Boehly, T. R. [Laboratory for Laser Energetics, Rochester, New York 14623 (United States); Nikroo, A. [General Atomics, San Diego, California 92196 (United States)

2014-02-15

Recent advances in shock timing experiments and analysis techniques now enable shock measurements to be performed in cryogenic deuterium-tritium (DT) ice layered capsule implosions on the National Ignition Facility (NIF). Previous measurements of shock timing in inertial confinement fusion implosions [Boehly et al., Phys. Rev. Lett. 106, 195005 (2011); Robey et al., Phys. Rev. Lett. 108, 215004 (2012)] were performed in surrogate targets, where the solid DT ice shell and central DT gas were replaced with a continuous liquid deuterium (D2) fill. These previous experiments pose two surrogacy issues: a material surrogacy due to the difference of species (D2 vs. DT) and densities of the materials used and a geometric surrogacy due to presence of an additional interface (ice/gas) previously absent in the liquid-filled targets. This report presents experimental data and a new analysis method for validating the assumptions underlying this surrogate technique. Comparison of the data with simulation shows good agreement for the timing of the first three shocks, but reveals a considerable discrepancy in the timing of the 4th shock in DT ice layered implosions. Electron preheat is examined as a potential cause of the observed discrepancy in the 4th shock timing.

Shock timing measurements and analysis in deuterium-tritium-ice layered capsule implosions on NIF

Science.gov (United States)

Robey, H. F.; Celliers, P. M.; Moody, J. D.; Sater, J.; Parham, T.; Kozioziemski, B.; Dylla-Spears, R.; Ross, J. S.; LePape, S.; Ralph, J. E.; Hohenberger, M.; Dewald, E. L.; Berzak Hopkins, L.; Kroll, J. J.; Yoxall, B. E.; Hamza, A. V.; Boehly, T. R.; Nikroo, A.; Landen, O. L.; Edwards, M. J.

2014-02-01

Recent advances in shock timing experiments and analysis techniques now enable shock measurements to be performed in cryogenic deuterium-tritium (DT) ice layered capsule implosions on the National Ignition Facility (NIF). Previous measurements of shock timing in inertial confinement fusion implosions [Boehly et al., Phys. Rev. Lett. 106, 195005 (2011); Robey et al., Phys. Rev. Lett. 108, 215004 (2012)] were performed in surrogate targets, where the solid DT ice shell and central DT gas were replaced with a continuous liquid deuterium (D2) fill. These previous experiments pose two surrogacy issues: a material surrogacy due to the difference of species (D2 vs. DT) and densities of the materials used and a geometric surrogacy due to presence of an additional interface (ice/gas) previously absent in the liquid-filled targets. This report presents experimental data and a new analysis method for validating the assumptions underlying this surrogate technique. Comparison of the data with simulation shows good agreement for the timing of the first three shocks, but reveals a considerable discrepancy in the timing of the 4th shock in DT ice layered implosions. Electron preheat is examined as a potential cause of the observed discrepancy in the 4th shock timing.

Shock timing measurements and analysis in deuterium-tritium-ice layered capsule implosions on NIF

International Nuclear Information System (INIS)

Robey, H. F.; Celliers, P. M.; Moody, J. D.; Sater, J.; Parham, T.; Kozioziemski, B.; Dylla-Spears, R.; Ross, J. S.; LePape, S.; Ralph, J. E.; Dewald, E. L.; Berzak Hopkins, L.; Kroll, J. J.; Yoxall, B. E.; Hamza, A. V.; Landen, O. L.; Edwards, M. J.; Hohenberger, M.; Boehly, T. R.; Nikroo, A.

2014-01-01

Recent advances in shock timing experiments and analysis techniques now enable shock measurements to be performed in cryogenic deuterium-tritium (DT) ice layered capsule implosions on the National Ignition Facility (NIF). Previous measurements of shock timing in inertial confinement fusion implosions [Boehly et al., Phys. Rev. Lett. 106, 195005 (2011); Robey et al., Phys. Rev. Lett. 108, 215004 (2012)] were performed in surrogate targets, where the solid DT ice shell and central DT gas were replaced with a continuous liquid deuterium (D2) fill. These previous experiments pose two surrogacy issues: a material surrogacy due to the difference of species (D2 vs. DT) and densities of the materials used and a geometric surrogacy due to presence of an additional interface (ice/gas) previously absent in the liquid-filled targets. This report presents experimental data and a new analysis method for validating the assumptions underlying this surrogate technique. Comparison of the data with simulation shows good agreement for the timing of the first three shocks, but reveals a considerable discrepancy in the timing of the 4th shock in DT ice layered implosions. Electron preheat is examined as a potential cause of the observed discrepancy in the 4th shock timing

Polymer-SnO₂ composite membranes

DEFF Research Database (Denmark)

Nørgaard, Casper Frydendal; Skou, Eivind Morten

. This work utilizes the latter approach and makes use of particles of tin dioxide (SnO2). Polymer-SnO2 composite membranes were successfully prepared using an ion-exchange method. SnO2 was incorporated into membranes by ion-exchange in solutions of SnCl2 ∙ 2 H2O in methanol, followed by oxidation to SnO2...... in air. The content of SnO2 proved controllable by adjusting the concentration of the ion-exchange solution. The prepared nanocomposite membranes were characterized by powder XRD, 119Sn MAS NMR, electrochemical impedance spectroscopy, water uptake and tensile stress-strain measurements. For Nafion 117...

Improvements in the critical current densities of Nb3Sn by solid solution additions of Sn in Nb

International Nuclear Information System (INIS)

Luhman, T.; Suenaga, M.

1975-01-01

The effectiveness of solid solution additions of Sn to Nb in improving the superconducting properties of diffusion processed Nb 3 Sn conductors was examined. It was found that an increase in the superconducting critical current density, Jc, as function of layer thickness (d) may be obtained for thick Nb 3 Sn layers by solid solution additions of Sn in Nb. A large increase in J/sub c/ (d) is also achieved by increasing the Sn content in the bronze matrix material. In addition to uses of this material in magnet fabrications a potential application of these improved J/sub c/(d) values may lie in the use of Nb 3 Sn in power transmission lines. Here, a high superconducting critical current density is necessary throughout the material to carry the increased current during fault conditions. The magnetic field dependence of J/sub c/ is a function of alloy content but the alloying changes studied here do not increase the high field critical current capability of Nb 3 Sn. (auth)

Production of superconducting Nb3Sn wire using Nb or Nb(Ti) and Sn(Ga) solid solution powders

International Nuclear Information System (INIS)

Thieme, C.L.H.; Foner, S.

1991-01-01

This paper reports on superconducting Nb 3 Sn wire produced by the powder metallurgy method using Nb or Nb-2.9 at% Ti powder in combination with Sn-x at% Ga powders (x = 3, 4.2, 6.2 and 9.0). Ga additions to the Sn caused considerable solid solution hardening which improved its workability. It made the Nb-Sn(Ga) powder combinations convenient for swaging and extensive wire drawing. Anneals at 950 degrees C produced wires with an overall J c of 10 4 A/cm 2 at 21.9 T for wires with both Ti in the Nb and 6.2 at% Ga in the Sn. Comparison of this wire with the best Nb(Ti)-Cu-internal Sn(Ti) shows a higher J c per A15 areas, especially in fields of 22T and above

Microstructure control of Zr-Nb-Sn alloy with Mo addition for HWR pressure tube application

International Nuclear Information System (INIS)

Hwang, S. K.; Kim, M. H.; Kim, J. H.; Kwon, S. I.; Kim, Y. S.

1997-01-01

As a basic research to develop the material for heavy water reactor pressure tube application the effect of Mo addition to Zr-Nb-Sn alloy was studied for the purpose of minimizing the amount of cold working while maintaining a high strength. To select the target alloy system we first designed various alloy compositions and chose Zr-Nb-Sn and Zr-Nb-Mo through multi-regression analysis of the relationship between the basic properties and the compositions. Plasma arc melting was used to produce the alloys and the microstructure change introduced by the processing steps including hot forging, beta-heat treatment, hot rolling, cold rolling and recrystallization heat treatment was investigated. Recrystallization of Zr-Nb-Sn was retarded by adding Mo and this resulted in a fine grain structure in Zr-Nb-Sn-Mo alloy. Beside the retarding effect recrystallization, Mo increased the amount of residual beta phase and showed an indication of precipitation hardening, which added up to the possibility of applying the alloy for the desired usage. (author)

Slow shocks and their transition to fast shocks in the inner solar wind

International Nuclear Information System (INIS)

Wang, Y.C.

1987-01-01

The jump conditions of MHD shocks may be directly calculated as functions of three upstream conditions: the shock Alfven number based on the normal component of the relative shock speed, the shock angle, and the plasma β value. The shock Alfven number is less than 1 for a slow shock and greater than 1 for a fast shock. A traveling, forward shock can be a slow shock in coronal space, where the Alfven speed is of the order of 1000 km/s. The surface of a forward slow shock has a bow-shaped geometry with its nose facing toward the sun. The decrease in the Alfven speed at increasing heliocentric distance causes the shock Alfven number of a forward slow shock to become greater than 1, and the shock eventually evolves from a slow shock into a fast shock. During the transition the shock system consists of a slow shock, a fast shock, and a rotational discontinuity. They intersect along a closed transition line. As the system moves outward from the sun, the area enclosed by the transition line expands, the fast shock grows stronger, and the slow shock becomes weaker. Eventually, the slow shock diminishes, and the entire shock system evolves into a forward fast shock. copyrightAmerican Geophysical Union 1987

Rayleigh-Taylor stability for a shock wave-density discontinuity interaction

International Nuclear Information System (INIS)

Fraley, G.S.

1981-01-01

Shells in inertial fusion targets are typically accelerated and decelerated by two or three shocks followed by continuous acceleration. The analytic solution for perturbation growth of a shock wave striking a density discontinuity in an inviscid fluid is investigated. The Laplace transform of the solution results in a functional equation, which has a simple solution for weak shock waves. The solution for strong shock waves may be given by a power series. It is assumed that the equation of state is given by a gamma law. The four independent parameters of the solution are the gamma values on each side of the material interface, the density ratio at the interface, and the shock strength. The asymptotic behavior (for large distances and times) of the perturbation velocity is given. For strong shocks the decay of the perturbation away from the interface is much weaker than the exponential decay of an incompressible fluid. The asymptotic value is given by a constant term and a number of slowly decaying discreet frequencies. The number of frequencies is roughly proportional to the logarithm of the density discontinuity divided by that of the shock strength. The asymptotic velocity at the interface is tabulated for representative values of the independent parameters. For weak shocks the solution is compared with results for an incompressible fluid. The range of density ratios with possible zero asymptotic velocities is given

Kinetics of plasma oxidation of germanium-tin (GeSn)

Science.gov (United States)

Wang, Wei; Lei, Dian; Dong, Yuan; Zhang, Zheng; Pan, Jisheng; Gong, Xiao; Tok, Eng-Soon; Yeo, Yee-Chia

2017-12-01

The kinetics of plasma oxidation of GeSn at low temperature is investigated. The oxidation process is described by a power-law model where the oxidation rate decreases rapidly from the initial oxidation rate with increasing time. The oxidation rate of GeSn is higher than that of pure Ge, which can be explained by the higher chemical reaction rate at the GeSn-oxide/GeSn interface. In addition, the Sn atoms at the interface region exchange positions with the underlying Ge atoms during oxidation, leading to a SnO2-rich oxide near the interface. The bandgap of GeSn oxide is extracted to be 5.1 ± 0.2 eV by XPS, and the valence band offset at the GeSn-oxide/GeSn heterojunction is found to be 3.7 ± 0.2 eV. Controlled annealing experiments demonstrate that the GeSn oxide is stable with respect to annealing temperatures up to 400 °C. However, after annealing at 450 °C, the GeO2 is converted to GeO, and desorbs from the GeSn-oxide/GeSn, leaving behind Sn oxide.

Fatigue and thermal fatigue of Pb-Sn solder joints

International Nuclear Information System (INIS)

Frear, D.; Grivas, D.; McCormack, M.; Tribula, D.; Morris, J.W. Jr.

1987-01-01

This paper presents a fundamental investigation of the fatigue and thermal fatigue characteristics, with an emphasis on the microstructural development during fatigue, of Sn-Pb solder joints. Fatigue tests were performed in simple shear on both 60Sn-40Pb and 5Sn-95Pb solder joints. Isothermal fatigue tests show increasing fatigue life of 60Sn-40Pb solder joints with decreasing strain and temperature. In contrast, such behavior was not observed in the isothermal fatigue of 5Sn-95Pb solder joints. Thermal fatigue results on 60Sn-40Pb solder cycled between -55 0 C and 125 0 C show that a coarsened region develops in the center of the joint. Both Pb-rich and Sn-rich phases coarsen, and cracks form within these coarsened regions. The failure mode 60Sn-40Pb solder joints in thermal and isothermal fatigue is similar: cracks form intergranularly through the Sn-rich phase or along Sn/Pb interphase boundaries. Extensive cracking is found throughout the 5Sn-95Pb joint for both thermal and isothermal fatigue. In thermal fatigue the 5Sn-95Pb solder joints failed after fewer cycles than 60Sn-40Pb

Evaluation of sublingual microcirculation in children with dengue shock

Directory of Open Access Journals (Sweden)

Daniella Mancino da Luz Caixeta

2013-07-01

Full Text Available OBJECTIVE: To report the sublingual microcirculation observed using Sidestream Dark Field imaging in two children with dengue shock. METHOD: Two children, aged 9 and 10 years, were admitted to the pediatric intensive care unit with dengue shock and multiple organ dysfunction. Sublingual microcirculation was assessed in each patient on the first and second days of shock and was assessed a final time when the patients were no longer in shock (on the day prior to extubation using Sidestream Dark Field technology. The De Backer score and microvascular flow index were used for the analyses. RESULTS: Both patients had reduced perfused small vessel density in the first two days and showed predominantly intermittent or no microcirculation flow, as demonstrated by a low microvascular flow index. The blood flow in the large vessels was not affected. Prior to the extubation, the microvascular flow index had increased, although the perfused small vessel density remained diminished, suggesting persistent endothelial dysfunction. CONCLUSIONS: Severe microcirculation changes may be involved in the pathophysiological mechanisms that lead to the final stages of dengue shock, which is frequently irreversible and associated with high mortality rates. Microcirculatory monitoring may help elucidate the physiopathology of dengue shock and prove useful as a prognostic tool or therapeutic target.

DO22-(Cu,Ni)3Sn intermetallic compound nanolayer formed in Cu/Sn-nanolayer/Ni structures

International Nuclear Information System (INIS)

Liu Lilin; Huang, Haiyou; Fu Ran; Liu Deming; Zhang Tongyi

2009-01-01

The present work conducts crystal characterization by High Resolution Transmission Electron Microscopy (HRTEM) on Cu/Sn-nanolayer/Ni sandwich structures associated with the use of Energy Dispersive X-ray (EDX) analysis. The results show that DO 22 -(Cu,Ni) 3 Sn intermetallic compound (IMC) ordered structure is formed in the sandwich structures at the as-electrodeposited state. The formed DO 22 -(Cu,Ni) 3 Sn IMC is a homogeneous layer with a thickness about 10 nm. The DO 22 -(Cu,Ni) 3 Sn IMC nanolayer is stable during annealing at 250 deg. C for 810 min. The formation and stabilization of the metastable DO 22 -(Cu,Ni) 3 Sn IMC nanolayer are attributed to the less strain energy induced by lattice mismatch between the DO 22 IMC and fcc Cu crystals in comparison with that between the equilibrium DO 3 IMC and fcc Cu crystals.

Liquidus Projection and Isothermal Section of the Sb-Se-Sn System

Science.gov (United States)

Chang, Jui-shen; Chen, Sinn-wen

2017-12-01

Sb-Se-Sn ternary alloys are promising chalcogenide materials. The liquidus projection and 673.2 K (400 °C) isothermal section of the Sb-Se-Sn ternary system are determined. Numerous Sb-Se-Sn alloys are prepared, and their primary solidification phases are examined. In addition to the three terminal phases, (Sb), (Se) and (Sn), there are Sb2Sn3, SbSn, SnSe, SnSe2, Sb2Se3, Sn2Sb9Se9, and SnSb2Se4 phases. In addition, there are two miscibility gaps along the Sb-Se and Se-Sn and sides. There are ten invariant reactions in the Sb-Se-Sn ternary system, and seven of them are experimentally determined in this study. The lowest reaction temperature of determined invariant reaction is L + SbSn = (Sn) + SnSe at 515.4 K ± 5 K (242.2 °C ± 5 °C). There are nine tie-triangles, which are Liquid + SbSn + SnSe, SbSn + SnSe + (Sb), SnSe + (Sb) + Sn2Sb9Se9, (Sb) + Sb2Se3 + Sn2Sb9Se9, SnSe + Sn2Sb9Se9 + SnSb2Se4, Sb2Se3 + Sn2Sb9Se9 + SnSb2Se4, SnSe + SnSe2 + SnSb2Se4, SnSe2 + SnSb2Se4 + Sb2Se3, and SnSe2 + Sb2Se3 + Liquid in the 673.2 K (400 °C) isothermal section of the Sb-Se-Sn ternary system.

Shock and Release Response of Unreacted Epon 828: Shot 2s-905

Energy Technology Data Exchange (ETDEWEB)

Pisa, Matthew Alexander [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Fredenburg, David A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Dattelbaum, Dana M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lang, John Michael [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Sandoval, Donald Leon [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2016-11-16

This document summarizes the shock and release response of Epon 828 measured in the dynamic impact experiment 2s-905. Experimentally, a thin Kel-F impactor backed by a low impedance foam impacted an Epon 828 target with embedded electromagnetic gauges. Computationally, a one dimensional simulation of the impact event was performed, and tracer particles were located at the corresponding electromagnetic gauge locations. The experimental configuration was such that the Epon 828 target was initially shocked, and then allowed to release from the high-pressure state. Comparisons of the experimental gauge and computational tracer data were made to assess the performance of equation of state (EOS) 7603, a SESAME EOS for Epon 828, on and off the principal shock Hugoniot. Results indicate that while EOS 7603 can capture the Hugoniot response to better that 1%, while the sound speeds at pressure are under-predicted by 6 - 7%.

SHOCK BREAKOUT FROM TYPE Ia SUPERNOVA

International Nuclear Information System (INIS)

Piro, Anthony L.; Chang, Philip; Weinberg, Nevin N.

2010-01-01

The mode of explosive burning in Type Ia supernovae (SNe Ia) remains an outstanding problem. It is generally thought to begin as a subsonic deflagration, but this may transition into a supersonic detonation (the delayed detonation transition, DDT). We argue that this transition leads to a breakout shock, which would provide the first unambiguous evidence that DDTs occur. Its main features are a hard X-ray flash (∼20 keV) lasting ∼10 -2 s with a total radiated energy of ∼10 40 erg, followed by a cooling tail. This creates a distinct feature in the visual light curve, which is separate from the nickel decay. This cooling tail has a maximum absolute visual magnitude of M V ∼ -9 to -10 at ∼1 day, which depends most sensitively on the white dwarf radius at the time of the DDT. As the thermal diffusion wave moves in, the composition of these surface layers may be imprinted as spectral features, which would help to discern between SN Ia progenitor models. Since this feature should accompany every SNe Ia, future deep surveys (e.g., m = 24) will see it out to a distance of ∼80 Mpc, giving a maximum rate of ∼60 yr -1 . Archival data sets can also be used to study the early rise dictated by the shock heating (at ∼20 days before maximum B-band light). A similar and slightly brighter event may also accompany core bounce during the accretion-induced collapse to a neutron star, but with a lower occurrence rate.

The crystallisation of Cu2ZnSnS4 thin film solar cell absorbers from co-electroplated Cu-Zn-Sn precursors

International Nuclear Information System (INIS)

Schurr, R.; Hoelzing, A.; Jost, S.; Hock, R.; Voss, T.; Schulze, J.; Kirbs, A.; Ennaoui, A.; Lux-Steiner, M.; Weber, A.; Koetschau, I.; Schock, H.-W.

2009-01-01

The best CZTS solar cell so far was produced by co-sputtering continued with vapour phase sulfurization method. Efficiencies of up to 5.74% were reached by Katagiri et al. The one step electrochemical deposition of copper, zinc, tin and subsequent sulfurization is an alternative fabrication technique for the production of Cu 2 ZnSnS 4 based thin film solar cells. A kesterite based solar cell (size 0.5 cm 2 ) with a conversion efficiency of 3.4% (AM1.5) was produced by vapour phase sulfurization of co-electroplated Cu-Zn-Sn films. We report on results of in-situ X-ray diffraction (XRD) experiments during crystallisation of kesterite thin films from electrochemically co-deposited metal films. The kesterite crystallisation is completed by the solid state reaction of Cu 2 SnS 3 and ZnS. The measurements show two different reaction paths depending on the metal ratios in the as deposited films. In copper-rich metal films Cu 3 Sn and CuZn were found after electrodeposition. In copper-poor or near stoichiometric precursors additional Cu 6 Sn 5 and Sn phases were detected. The formation mechanism of Cu 2 SnS 3 involves the binary sulphides Cu 2-x S and SnS 2 in the absence of the binary precursor phase Cu 6 Sn 5 . The presence of Cu 6 Sn 5 leads to a preferred formation of Cu 2 SnS 3 via the reaction educts Cu 2-x S and SnS 2 in the presence of a SnS 2 (Cu 4 SnS 6 ) melt. The melt phase may be advantageous in crystallising the kesterite, leading to enhanced grain growth in the presence of a liquid phase

Weibel instability mediated collisionless shocks using intense laser-driven plasmas

Science.gov (United States)

Palaniyappan, Sasikumar; Fiuza, Federico; Huang, Chengkun; Gautier, Donald; Ma, Wenjun; Schreiber, Jorg; Raymer, Abel; Fernandez, Juan; Shimada, Tom; Johnson, Randall

2017-10-01

The origin of cosmic rays remains a long-standing challenge in astrophysics and continues to fascinate physicists. It is believed that ``collisionless shocks'' - where the particle Coulomb mean free path is much larger that the shock transition - are a dominant source of energetic cosmic rays. These shocks are ubiquitous in astrophysical environments such as gamma-ray bursts, supernova remnants, pulsar wind nebula and coronal mass ejections from the sun. A particular type of electromagnetic plasma instability known as Weibel instability is believed to be the dominant mechanism behind the formation of these collisionless shocks in the cosmos. The understanding of the microphysics behind collisionless shocks and their particle acceleration is tightly related with nonlinear basic plasma processes and remains a grand challenge. In this poster, we will present results from recent experiments at the LANL Trident laser facility studying collisionless shocks using intense ps laser (80J, 650 fs - peak intensity of 1020 W/cm2) driven near-critical plasmas using carbon nanotube foam targets. A second short pulse laser driven protons from few microns thick gold foil is used to radiograph the main laser-driven plasma. Work supported by the LDRD program at LANL.

A Bivalent Securinine Compound SN3-L6 Induces Neuronal Differentiation via Translational Upregulation of Neurogenic Transcription Factors

Directory of Open Access Journals (Sweden)

Yumei Liao

2018-04-01

Full Text Available Developing therapeutic approaches that target neuronal differentiation will be greatly beneficial for the regeneration of neurons and synaptic networks in neurological diseases. Protein synthesis (mRNA translation has recently been shown to regulate neurogenesis of neural stem/progenitor cells (NSPCs. However, it has remained unknown whether engineering translational machinery is a valid approach for manipulating neuronal differentiation. The present study identifies that a bivalent securinine compound SN3-L6, previously designed and synthesized by our group, induces potent neuronal differentiation through a novel translation-dependent mechanism. An isobaric tag for relative and absolute quantitation (iTRAQ-based proteomic analysis in Neuro-2a progenitor cells revealed that SN3-L6 upregulated a group of neurogenic transcription regulators, and also upregulated proteins involved in RNA processing, translation, and protein metabolism. Notably, puromycylation and metabolic labeling of newly synthesized proteins demonstrated that SN3-L6 induced rapid and robust activation of general mRNA translation. Importantly, mRNAs of the proneural transcription factors Foxp1, Foxp4, Hsf1, and Erf were among the targets that were translationally upregulated by SN3-L6. Either inhibition of translation or knockdown of these transcription factors blocked SN3-L6 activity. We finally confirmed that protein synthesis of a same set of transcription factors was upregulated in primary cortical NPCs. These findings together identify a new compound for translational activation and neuronal differentiation, and provide compelling evidence that reprogramming transcriptional regulation network at translational levels is a promising strategy for engineering NSPCs.

Very Deep inside the SN 1987A Core Ejecta: Molecular Structures Seen in 3D

Energy Technology Data Exchange (ETDEWEB)

Abellán, F. J.; Marcaide, J. M. [Departamento de Astronomía y Astrofísica, Universidad de Valencia, C/Dr. Moliner 50, E-46100 Burjassot (Spain); Indebetouw, R.; Chevalier, R. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); Gabler, M.; Janka, H.-Th. [Max-Planck-Institut für Astrophysik, Karl-Schwarzschild-Straße 1, D-85748 Garching (Germany); Fransson, C.; Lundqvist, P. [Department of Astronomy, The Oskar Klein Centre, Stockholm University, Alba Nova University Centre, SE-106 91 Stockholm (Sweden); Spyromilio, J. [ESO, Karl-Schwarzschild-Straße 2, D-85748 Garching (Germany); Burrows, D. N. [Department of Astronomy and Astrophysics, The Pennsylvania State University, University Park, PA 16802 (United States); Cigan, P.; Gomez, H. L.; Matsuura, M. [School of Physics and Astronomy, Cardiff University, Queens Buildings, The Parade, Cardiff CF24 3AA (United Kingdom); Gaensler, B. M. [Dunlap Institute for Astronomy and Astrophysics, University of Toronto, Toronto, ON M5S 3H4 (Canada); Kirshner, R. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Larsson, J. [KTH, Department of Physics, and the Oskar Klein Centre, AlbaNova, SE-106 91 Stockholm (Sweden); McCray, R. [Department of Astronomy, University of California, Berkeley, CA 94720-3411 (United States); Ng, C.-Y. [Department of Physics, The University of Hong Kong, Pokfulam Road, Hong Kong (China); Park, S. [Department of Physics, University of Texas at Arlington, 108 Science Hall, Box 19059, Arlington, TX 76019 (United States); Roche, P., E-mail: francisco.abellan@uv.es [Department of Physics, University of Oxford, Oxford OX1 3RH (United Kingdom); and others

2017-06-20

Most massive stars end their lives in core-collapse supernova explosions and enrich the interstellar medium with explosively nucleosynthesized elements. Following core collapse, the explosion is subject to instabilities as the shock propagates outward through the progenitor star. Observations of the composition and structure of the innermost regions of a core-collapse supernova provide a direct probe of the instabilities and nucleosynthetic products. SN 1987A in the Large Magellanic Cloud is one of very few supernovae for which the inner ejecta can be spatially resolved but are not yet strongly affected by interaction with the surroundings. Our observations of SN 1987A with the Atacama Large Millimeter/submillimeter Array are of the highest resolution to date and reveal the detailed morphology of cold molecular gas in the innermost regions of the remnant. The 3D distributions of carbon and silicon monoxide (CO and SiO) emission differ, but both have a central deficit, or torus-like distribution, possibly a result of radioactive heating during the first weeks (“nickel heating”). The size scales of the clumpy distribution are compared quantitatively to models, demonstrating how progenitor and explosion physics can be constrained.

Very Deep inside the SN 1987A Core Ejecta: Molecular Structures Seen in 3D

International Nuclear Information System (INIS)

Abellán, F. J.; Marcaide, J. M.; Indebetouw, R.; Chevalier, R.; Gabler, M.; Janka, H.-Th.; Fransson, C.; Lundqvist, P.; Spyromilio, J.; Burrows, D. N.; Cigan, P.; Gomez, H. L.; Matsuura, M.; Gaensler, B. M.; Kirshner, R.; Larsson, J.; McCray, R.; Ng, C.-Y.; Park, S.; Roche, P.

2017-01-01

Most massive stars end their lives in core-collapse supernova explosions and enrich the interstellar medium with explosively nucleosynthesized elements. Following core collapse, the explosion is subject to instabilities as the shock propagates outward through the progenitor star. Observations of the composition and structure of the innermost regions of a core-collapse supernova provide a direct probe of the instabilities and nucleosynthetic products. SN 1987A in the Large Magellanic Cloud is one of very few supernovae for which the inner ejecta can be spatially resolved but are not yet strongly affected by interaction with the surroundings. Our observations of SN 1987A with the Atacama Large Millimeter/submillimeter Array are of the highest resolution to date and reveal the detailed morphology of cold molecular gas in the innermost regions of the remnant. The 3D distributions of carbon and silicon monoxide (CO and SiO) emission differ, but both have a central deficit, or torus-like distribution, possibly a result of radioactive heating during the first weeks (“nickel heating”). The size scales of the clumpy distribution are compared quantitatively to models, demonstrating how progenitor and explosion physics can be constrained.

Laser-generated shock wave attenuation aimed at microscale pyrotechnic device design

Directory of Open Access Journals (Sweden)

Hyeonju Yu

2016-05-01

Full Text Available To meet the rising demand for miniaturizing the pyrotechnic device that consists of donor/acceptor pair separated by a bulkhead or a thin gap, the shock initiation sensitivity in the microscale gap test configuration is investigated. For understanding the shock attenuation within a gap sample (304 stainless steel thickness of 10∼800 μm, the laser-generated shock wave in water confinement is adopted. The shock properties are obtained from the free surface velocity by making use of a velocity interferometer system for any reflector (VISAR. Analytical models for plasma generation in a confined geometry and for evolution and decay of shock waves during the propagation are considered. The shape and amplitude of the laser-driven initial pressure load and its attenuation pattern in the gap are effectively controlled for targeting the microscale propagation distance and subsequent triggering pressure for the acceptor charge. The reported results are important in the precise controlling of the shock strength during the laser initiation of microscale pyrotechnic devices.

All Small Nuclear RNAs (snRNAs) of the [U4/U6.U5] Tri-snRNP Localize to Nucleoli; Identification of the Nucleolar Localization Element of U6 snRNA

Science.gov (United States)

Gerbi, Susan A.; Lange, Thilo Sascha

2002-01-01

Previously, we showed that spliceosomal U6 small nuclear RNA (snRNA) transiently passes through the nucleolus. Herein, we report that all individual snRNAs of the [U4/U6.U5] tri-snRNP localize to nucleoli, demonstrated by fluorescence microscopy of nucleolar preparations after injection of fluorescein-labeled snRNA into Xenopus oocyte nuclei. Nucleolar localization of U6 is independent from [U4/U6] snRNP formation since sites of direct interaction of U6 snRNA with U4 snRNA are not nucleolar localization elements. Among all regions in U6, the only one required for nucleolar localization is its 3′ end, which associates with the La protein and subsequently during maturation of U6 is bound by Lsm proteins. This 3′-nucleolar localization element of U6 is both essential and sufficient for nucleolar localization and also required for localization to Cajal bodies. Conversion of the 3′ hydroxyl of U6 snRNA to a 3′ phosphate prevents association with the La protein but does not affect U6 localization to nucleoli or Cajal bodies. PMID:12221120

P-type SnO thin films and SnO/ZnO heterostructures for all-oxide electronic and optoelectronic device applications

Energy Technology Data Exchange (ETDEWEB)

Saji, Kachirayil J. [Nanostructured Materials Research Laboratory, Department of Materials Science & Engineering, University of Utah, Salt Lake City, UT 84112 (United States); Department of Physics, Govt. Victoria College, University of Calicut, Palakkad 678 001 (India); Venkata Subbaiah, Y.P. [Nanostructured Materials Research Laboratory, Department of Materials Science & Engineering, University of Utah, Salt Lake City, UT 84112 (United States); Department of Physics, Yogi Vemana University, Kadapa, Andhra Pradesh 516003 (India); Tian, Kun [Nanostructured Materials Research Laboratory, Department of Materials Science & Engineering, University of Utah, Salt Lake City, UT 84112 (United States); Tiwari, Ashutosh, E-mail: tiwari@eng.utah.edu [Nanostructured Materials Research Laboratory, Department of Materials Science & Engineering, University of Utah, Salt Lake City, UT 84112 (United States)

2016-04-30

Tin monoxide (SnO) is considered as one of the most important p-type oxides available to date. Thin films of SnO have been reported to possess both an indirect bandgap (~ 0.7 eV) and a direct bandgap (~ 2.8 eV) with quite high hole mobility (~ 7 cm{sup 2}/Vs) values. Moreover, the hole density in these films can be tuned from 10{sup 15}–10{sup 19} cm{sup −3} just by controlling the thin film deposition parameters. Because of the above attributes, SnO thin films offer great potential for fabricating modern electronic and optoelectronic devices. In this article, we are reviewing the most recent developments in this field and also presenting some of our own results on SnO thin films grown by pulsed laser deposition technique. We have also proposed a p–n heterostructure comprising of p-type SnO and n-type ZnO which can pave way for realizing next-generation, all-oxide transparent electronic devices. - Highlights: • We reviewed recent developments on p-type SnO thin film research. • Discussed the optical and electrical properties of SnO thin films • Bipolar conduction in SnO is discussed. • Optoelectronic properties of SnO–ZnO composite system are discussed. • Proposed SnO–ZnO heterojunction band structure.

Spectroscopic ellipsometry characterization of ZnO:Sn thin films with various Sn composition deposited by remote-plasma reactive sputtering

Science.gov (United States)

Janicek, Petr; Niang, Kham M.; Mistrik, Jan; Palka, Karel; Flewitt, Andrew J.

2017-11-01

ZnO:Sn thin films were deposited onto thermally oxidized silicon substrates using a remote plasma reactive sputtering. Their optical constants (refractive index n and extinction coefficient k) were determined from ellipsometric data recorded over a wide spectral range (0.05-6 eV). Parametrization of ZnO:Sn complex dielectric permittivity consists of a parameterized semiconductor oscillator function describing the short wavelength absorption edge, a Drude oscillator describing free carrier absorption in near-infrared part of spectra and a Lorentz oscillator describing the long wavelength absorption edge and intra-band absorption in the ultra-violet part of the spectra. Using a Mott-Davis model, the increase in local disorder with increasing Sn doping is quantified from the short wavelength absorption edge onset. Using the Wemple-DiDomenico single oscillator model for the transparent part of the optical constants spectra, an increase in the centroid distance of the valence and conduction bands with increasing Sn doping is shown and only slight increase in intensity of the inter-band optical transition due to Sn doping occurs. The Drude model applied in the near-infrared part of the spectra revealed the free carrier concentration and mobility of ZnO:Sn. Results show that the range of transparency of prepared ZnO:Sn layers is not dramatically affected by Sn doping whereas electrical conductivity could be controlled by Sn doping. Refractive index in the transparent part is comparable with amorphous Indium Gallium Zinc Oxide allowing utilization of prepared ZnO:Sn layers as an indium-free alternative.

Crystal structure of R.E. NiSn and R.E. PdSn equiatomic compounds

International Nuclear Information System (INIS)

Dwight, A.E.

1983-03-01

Call constants and volume per formula weight are tabulated for RE NiSn (RE = La to Lu, Y) and RE PdSn (RE = Nd to Ho). The unit cell constants are also plotted versus ionic radius of the RE; trends are noted

Electrical, optical and etching properties of Zn-Sn-O thin films deposited by combinatorial sputtering

International Nuclear Information System (INIS)

Kim, J. S.; Park, J. K.; Baik, Y. J.; Kim, W. M.; Jeong, J.; Seong, T. Y.

2012-01-01

Zn-Sn-O (ZTO) films are known to be able to form an amorphous phase, which provides a smooth surface morphology as well as etched side wall, when deposited by using the conventional sputtering technique and, therefore, to have a potential to be applied as transparent thin film transistors. In this study, ZTO thin films were prepared by using combined sputtering of ZnO and SnO 2 targets, and the dependences of their electrical and optical properties on the composition and the deposition parameters were examined. The Sn content in the films was varied in the range of 35 ∼ 85 at .%. The deposition was carried out at room temperature, 150 and 300 .deg. C, and the oxygen content in sputtering gas was varied from 0 to 1 vol.%. Sn-rich films had better electrical properties, but showed large oxygen deficiency when deposited at low oxygen partial pressures. ZTO films with Sn contents lower than 55 at.% had good optical transmission, but the electrical properties were poor due to very low carrier concentrations. A high Hall mobility of larger than 10 cm 2 /Vs could be obtained in the carrier density range 10 17 ∼ 10 20 cm -3 , and the etching rate was measurable for films with Sn content up to 70 at.% when using a dilute HCl solution, indicating a good possibility of utilizing ZTO films for device applications.

Synthesis and fundamental properties of stable Ph(3)SnSiH(3) and Ph(3)SnGeH(3) hydrides: model compounds for the design of Si-Ge-Sn photonic alloys.

Science.gov (United States)

Tice, Jesse B; Chizmeshya, Andrew V G; Groy, Thomas L; Kouvetakis, John

2009-07-06

The compounds Ph(3)SnSiH(3) and Ph(3)SnGeH(3) (Ph = C(6)H(5)) have been synthesized as colorless solids containing Sn-MH(3) (M = Si, Ge) moieties that are stable in air despite the presence of multiple and highly reactive Si-H and Ge-H bonds. These molecules are of interest since they represent potential model compounds for the design of new classes of IR semiconductors in the Si-Ge-Sn system. Their unexpected stability and high solubility also makes them a safe, convenient, and potentially useful delivery source of -SiH(3) and -GeH(3) ligands in molecular synthesis. The structure and composition of both compounds has been determined by chemical analysis and a range of spectroscopic methods including multinuclear NMR. Single crystal X-ray structures were determined and indicated that both compounds condense in a Z = 2 triclinic (P1) space group with lattice parameters (a = 9.7754(4) A, b = 9.8008(4) A, c = 10.4093(5) A, alpha = 73.35(10)(o), beta = 65.39(10)(o), gamma = 73.18(10)(o)) for Ph(3)SnSiH(3) and (a = 9.7927(2) A, b = 9.8005(2) A, c = 10.4224(2) A, alpha = 74.01(3)(o), beta = 65.48(3)(o), gamma = 73.43(3)(o)) for Ph(3)SnGeH(3). First principles density functional theory simulations are used to corroborate the molecular structures of Ph(3)SnSiH(3) and Ph(3)SnGeH(3), gain valuable insight into the relative stability of the two compounds, and provide correlations between the Si-Sn and Ge-Sn bonds in the molecules and those in tetrahedral Si-Ge-Sn solids.

Tim50a, a nuclear isoform of the mitochondrial Tim50, interacts with proteins involved in snRNP biogenesis

Directory of Open Access Journals (Sweden)

Robinson Melvin L

2005-07-01

Full Text Available Abstract Background The Cajal body (CB is a nuclear suborganelle involved in the biogenesis of small nuclear ribonucleoproteins (snRNPs, which are vital for pre-mRNA splicing. Newly imported Sm-class snRNPs traffic through CBs, where the snRNA component of the snRNP is modified, and then target to other nuclear domains such as speckles and perichromatin fibrils. It is not known how nascent snRNPs localize to the CB and are released from this structure after modification. The marker protein for CBs, coilin, may play a role in snRNP biogenesis given that it can interact with snRNPs and SMN, the protein mutated in Spinal Muscular Atrophy. Loss of coilin function in mice leads to significant viability and fertility problems and altered CB formation. Results In this report, we identify a minor isoform of the mitochondrial Tim50, Tim50a, as a coilin interacting protein. The Tim50a transcript can be detected in some cancer cell lines and normal brain tissue. The Tim50a protein differs only from Tim50 in that it contains an additional 103 aa N-terminal to the translation start of Tim50. Importantly, a putative nuclear localization signal is found within these 103 residues. In contrast to Tim50, which localizes to the cytoplasm and mitochondria, Tim50a is strictly nuclear and is enriched in speckles with snRNPs. In addition to coilin, Tim50a interacts with snRNPs and SMN. Competition binding experiments demonstrate that coilin competes with Sm proteins of snRNPs and SMN for binding sites on Tim50a. Conclusion Tim50a may play a role in snRNP biogenesis given its cellular localization and protein interaction characteristics. We hypothesize that Tim50a takes part in the release of snRNPs and SMN from the CB.

Rippled shock front solutions for testing hydrodynamic stability simulations

International Nuclear Information System (INIS)

Munro, D.H.

1989-01-01

The response of a shock front to arbitrary small perturbations can be calculated analytically. Such rippled shock front solutions are useful for determining the accuracy of hydrodynamic simulation codes such as LASNEX [Comments Plasma Phys. Controlled Fusion 2, 51 (1977)], which are used to compute perturbation growth in inertial fusion targets. The LASNEX fractional errors are of order κ 2 L 2 , where κ is the transverse wavenumber of the perturbation, and L is the largest zone dimension. Numerical errors are about 25% for a calculation using 26 zones per transverse wavelength

Development and evaluation of the LiSN & learn auditory training software for deficit-specific remediation of binaural processing deficits in children: preliminary findings.

Science.gov (United States)

Cameron, Sharon; Dillon, Harvey

2011-01-01

The LiSN & Learn auditory training software was developed specifically to improve binaural processing skills in children with suspected central auditory processing disorder who were diagnosed as having a spatial processing disorder (SPD). SPD is defined here as a condition whereby individuals are deficient in their ability to use binaural cues to selectively attend to sounds arriving from one direction while simultaneously suppressing sounds arriving from another. As a result, children with SPD have difficulty understanding speech in noisy environments, such as in the classroom. To develop and evaluate the LiSN & Learn auditory training software for children diagnosed with the Listening in Spatialized Noise-Sentences Test (LiSN-S) as having an SPD. The LiSN-S is an adaptive speech-in-noise test designed to differentially diagnose spatial and pitch-processing deficits in children with suspected central auditory processing disorder. Participants were nine children (aged between 6 yr, 9 mo, and 11 yr, 4 mo) who performed outside normal limits on the LiSN-S. In a pre-post study of treatment outcomes, participants trained on the LiSN & Learn for 15 min per day for 12 weeks. Participants acted as their own control. Participants were assessed on the LiSN-S, as well as tests of attention and memory and a self-report questionnaire of listening ability. Performance on all tasks was reassessed after 3 mo where no further training occurred. The LiSN & Learn produces a three-dimensional auditory environment under headphones on the user's home computer. The child's task was to identify a word from a target sentence presented in background noise. A weighted up-down adaptive procedure was used to adjust the signal level of the target based on the participant's response. On average, speech reception thresholds on the LiSN & Learn improved by 10 dB over the course of training. As hypothesized, there were significant improvements in posttraining performance on the LiSN-S conditions

Toxic shock syndrome

Science.gov (United States)

Staphylococcal toxic shock syndrome; Toxic shock-like syndrome; TSLS ... Toxic shock syndrome is caused by a toxin produced by some types of staphylococcus bacteria. A similar problem, called toxic shock- ...

Identify and Quantify the Mechanistic Sources of Sensor Performance Variation Between Individual Sensors SN1 and SN2

Energy Technology Data Exchange (ETDEWEB)

Diaz, Aaron A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Baldwin, David L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Cinson, Anthony D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Jones, Anthony M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Larche, Michael R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mathews, Royce [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mullen, Crystal A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Pardini, Allan F. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Posakony, Gerald J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Prowant, Matthew S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hartman, Trenton S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Edwards, Matthew K. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2014-08-06

This Technical Letter Report satisfies the M3AR-14PN2301022 milestone, and is focused on identifying and quantifying the mechanistic sources of sensor performance variation between individual 22-element, linear phased-array sensor prototypes, SN1 and SN2. This effort constitutes an iterative evolution that supports the longer term goal of producing and demonstrating a pre-manufacturing prototype ultrasonic probe that possesses the fundamental performance characteristics necessary to enable the development of a high-temperature sodium-cooled fast reactor inspection system. The scope of the work for this portion of the PNNL effort conducted in FY14 includes performing a comparative evaluation and assessment of the performance characteristics of the SN1 and SN2 22 element PA-UT probes manufactured at PNNL. Key transducer performance parameters, such as sound field dimensions, resolution capabilities, frequency response, and bandwidth are used as a metric for the comparative evaluation and assessment of the SN1 and SN2 engineering test units.

Controlling the Sn-C bonds content in SnO2@CNTs composite to form in situ pulverized structure for enhanced electrochemical kinetics.

Science.gov (United States)

Cheng, Yayi; Huang, Jianfeng; Qi, Hui; Cao, Liyun; Luo, Xiaomin; Li, Jiayin; Xu, Zhanwei; Yang, Jun

2017-12-07

The Sn-C bonding content between the SnO 2 and CNTs interface was controlled by the hydrothermal method and subsequent heat treatment. Electrochemical analysis found that the SnO 2 @CNTs with high Sn-C bonding content exhibited much higher capacity contribution from alloying and conversion reaction compared with the low content of Sn-C bonding even after 200 cycles. The high Sn-C bonding content enabled the SnO 2 nanoparticles to stabilize on the CNTs surface, realizing an in situ pulverization process of SnO 2 . The in situ pulverized structure was beneficial to maintain the close electrochemical contact of the working electrode during the long-term cycling and provide ultrafast transfer paths for lithium ions and electrons, which promoted the alloying and conversion reaction kinetics greatly. Therefore, the SnO 2 @CNTs composite with high Sn-C bonding content displayed highly reversible alloying and conversion reaction. It is believed that the composite could be used as a reference for design chemically bonded metal oxide/carbon composite anode materials in lithium-ion batteries.

Nano-grain SnO{sub 2} electrodes for high conversion efficiency SnO{sub 2}-DSSC

Energy Technology Data Exchange (ETDEWEB)

Lee, Jung-Hoon; Shin, Yu-Ju [Department of Chemistry, the Catholic University of Korea, Bucheon, Gyeonggi-do 422-743 (Korea, Republic of); Park, Nam-Gyu [School of Chemical Engineering, Sungkyunkwan University, Suwon, Gyeonggi-do 440-746 (Korea, Republic of)

2011-01-15

The nano-grain ZnO/SnO{sub 2} composite electrode was prepared by adding 5 w% of the 200-250 nm ZnO particles to the 5 nm SnO{sub 2} colloid in the presence of hydroxypropylcellulose (M.W.=80,000). The nano-grain SnO{sub 2} electrode was obtained by removing the ZnO particles from the composite electrode using acetic acid. The FE-SEM micrographs revealed that both electrodes consisted of interconnected nano-grains that were ca. 800 nm in size, and the large pores between the grains furnished the wide electrolyte diffusion channels within the electrodes. The photovoltaic properties of the nano-grain electrodes were investigated by measuring the I-V behaviors, the IPCE spectra and the ac-impedance spectra. The nano-grain electrodes exhibited remarkably improved conversion efficiencies of 3.96% for the composite and 2.98% for the SnO{sub 2} electrode compared to the value of 1.66% for the usual nano-particle SnO{sub 2} electrode. The improvement conversion efficiencies were mainly attributed to the formation of nano-grains, which facilitated the electron diffusion within the grains. The improved electrolyte diffusion as well as the light-scattering effects enhanced the photovoltaic performance of the SnO{sub 2} electrode. (author)

Theoretical quantification of shock-timing sensitivities for direct-drive inertial confinement fusion implosions on OMEGA

Science.gov (United States)

Cao, D.; Boehly, T. R.; Gregor, M. C.; Polsin, D. N.; Davis, A. K.; Radha, P. B.; Regan, S. P.; Goncharov, V. N.

2018-05-01

Using temporally shaped laser pulses, multiple shocks can be launched in direct-drive inertial confinement fusion implosion experiments to set the shell on a desired isentrope or adiabat. The velocity of the first shock and the times at which subsequent shocks catch up to it are measured through the velocity interferometry system for any reflector diagnostic [T. R. Boehly et al., Phys. Plasmas 18, 092706 (2011)] on OMEGA [T. R. Boehly et al., Opt. Commun. 133, 495 (1997)]. Simulations reproduce these velocity and shock-merger time measurements when using laser pulses designed for setting mid-adiabat (α ˜ 3) implosions, but agreement degrades for lower-adiabat (α ˜ 1) designs. Simulation results indicate that the shock timing discrepancy is most sensitive to details of the density and temperature profiles in the coronal plasma, which influences the laser energy coupled into the target, and only marginally sensitive to the target offset and beam power imbalance. To aid in verifying the coronal profile's influence, a new technique under development to infer coronal profiles using x-ray self-emission imaging [A. K. Davis et al., Bull. Am. Phys. Soc. 61, BAPS.2016.DPP.NO8.7 (2016)] can be applied to the pulse shapes used in shock-timing experiments.

Qualitative analysis of plasma created by shock laser

International Nuclear Information System (INIS)

Grevey, D.; Maiffredy, L.; Vannes, A.B.; Gobin, P.F.

1987-01-01

The origin of effects observed of the surface of metals treated by lasers was studied. High speed cinematography (20,000 frames/sec) was used to follow the evolution of plasma shape from start to finish. An Nd glass laser and FeNi targets were used. The irradiated surface was examined using optical and scanning electron-microscopes. The phenomenology of plasma formation, and plasma expansion are summarized. Liquid spattering and concentric waves on the target surface are revealed. Results suggest that the main agent of the effects in laser-target interactions is the plasma, which creates compression waves inside the target. These waves quickly become a shock wave which can modify the microstructure of the target [fr

Temperature varying photoconductivity of GeSn alloys grown by chemical vapor deposition with Sn concentrations from 4% to 11%

Energy Technology Data Exchange (ETDEWEB)

Hart, John; Hazbun, Ramsey; Gupta, Jay; Kolodzey, James [Department of Electrical Engineering, University of Delaware, 140 Evans Hall, Newark, Delaware 19716 (United States); Adam, Thomas [College of Nanoscale Science and Engineering, SUNY, Albany, New York 12203 (United States); Kim, Yihwan; Huang, Yi-Chiau [Applied Materials, Sunnyvale, California 94085 (United States); Reznicek, Alexander [IBM Research at Albany Nanotech, Albany, New York 12203 (United States)

2016-03-07

Pseudomorphic GeSn layers with Sn atomic percentages between 4.5% and 11.3% were grown by chemical vapor deposition using digermane and SnCl{sub 4} precursors on Ge virtual substrates grown on Si. The layers were characterized by x-ray diffraction rocking curves and reciprocal space maps. Photoconductive devices were fabricated, and the dark current was found to increase with Sn concentration. The responsivity of the photoconductors was measured at a wavelength of 1.55 μm using calibrated laser illumination at room temperature and a maximum value of 2.7 mA/W was measured for a 4.5% Sn device. Moreover, the responsivity for higher Sn concentration was found to increase with decreasing temperature. Spectral photoconductivity was measured using Fourier transform infrared spectroscopy. The photoconductive absorption edge continually increased in wavelength with increasing tin percentage, out to approximately 2.4 μm for an 11.3% Sn device. The direct band gap was extracted using Tauc plots and was fit to a bandgap model accounting for layer strain and Sn concentration. This direct bandgap was attributed to absorption from the heavy-hole band to the conduction band. Higher energy absorption was also observed, which was thought to be likely from absorption in the light-hole band. The band gaps for these alloys were plotted as a function of temperature. These experiments show the promise of GeSn alloys for CMOS compatible short wave infrared detectors.

Temperature varying photoconductivity of GeSn alloys grown by chemical vapor deposition with Sn concentrations from 4% to 11%

International Nuclear Information System (INIS)

Hart, John; Hazbun, Ramsey; Gupta, Jay; Kolodzey, James; Adam, Thomas; Kim, Yihwan; Huang, Yi-Chiau; Reznicek, Alexander

2016-01-01

Pseudomorphic GeSn layers with Sn atomic percentages between 4.5% and 11.3% were grown by chemical vapor deposition using digermane and SnCl 4 precursors on Ge virtual substrates grown on Si. The layers were characterized by x-ray diffraction rocking curves and reciprocal space maps. Photoconductive devices were fabricated, and the dark current was found to increase with Sn concentration. The responsivity of the photoconductors was measured at a wavelength of 1.55 μm using calibrated laser illumination at room temperature and a maximum value of 2.7 mA/W was measured for a 4.5% Sn device. Moreover, the responsivity for higher Sn concentration was found to increase with decreasing temperature. Spectral photoconductivity was measured using Fourier transform infrared spectroscopy. The photoconductive absorption edge continually increased in wavelength with increasing tin percentage, out to approximately 2.4 μm for an 11.3% Sn device. The direct band gap was extracted using Tauc plots and was fit to a bandgap model accounting for layer strain and Sn concentration. This direct bandgap was attributed to absorption from the heavy-hole band to the conduction band. Higher energy absorption was also observed, which was thought to be likely from absorption in the light-hole band. The band gaps for these alloys were plotted as a function of temperature. These experiments show the promise of GeSn alloys for CMOS compatible short wave infrared detectors.

Temperature varying photoconductivity of GeSn alloys grown by chemical vapor deposition with Sn concentrations from 4% to 11%

Science.gov (United States)

Hart, John; Adam, Thomas; Kim, Yihwan; Huang, Yi-Chiau; Reznicek, Alexander; Hazbun, Ramsey; Gupta, Jay; Kolodzey, James

2016-03-01

Pseudomorphic GeSn layers with Sn atomic percentages between 4.5% and 11.3% were grown by chemical vapor deposition using digermane and SnCl4 precursors on Ge virtual substrates grown on Si. The layers were characterized by x-ray diffraction rocking curves and reciprocal space maps. Photoconductive devices were fabricated, and the dark current was found to increase with Sn concentration. The responsivity of the photoconductors was measured at a wavelength of 1.55 μm using calibrated laser illumination at room temperature and a maximum value of 2.7 mA/W was measured for a 4.5% Sn device. Moreover, the responsivity for higher Sn concentration was found to increase with decreasing temperature. Spectral photoconductivity was measured using Fourier transform infrared spectroscopy. The photoconductive absorption edge continually increased in wavelength with increasing tin percentage, out to approximately 2.4 μm for an 11.3% Sn device. The direct band gap was extracted using Tauc plots and was fit to a bandgap model accounting for layer strain and Sn concentration. This direct bandgap was attributed to absorption from the heavy-hole band to the conduction band. Higher energy absorption was also observed, which was thought to be likely from absorption in the light-hole band. The band gaps for these alloys were plotted as a function of temperature. These experiments show the promise of GeSn alloys for CMOS compatible short wave infrared detectors.

Radiating shocks and condensations in flares

International Nuclear Information System (INIS)

Fisher, G.H.

1985-01-01

Rapid energy release (by either ''thick target'' (beam) or ''thermal'' models of heating) in solar flare loop models usually leads to ''chromospheric evaporation,'' the process of heating cool chromospheric material to coronal temperatures, and the resulting increase in hot soft x-ray emitting plasma. The evaporated plasma flows up into the coronal portion of the loop because of the increased pressure in the evaporated region. However, the pressure increase also leads to a number of interesting phenomena in the flare chromosphere, which will be the subject of this paper. The sudden pressure increase in the evaporated plasma initiates a downward moving ''chromospheric condensation,'' an overdense region which gradually decelerates as it accretes material and propagates into the gravitationally stratified chromosphere. Solutions to an equation of motion for this condensation shows that its motion decays after about one minute of propagation into the chromosphere. When the front of this downflowing region is supersonic relative to the atmosphere ahead of it, a radiating shock will form. If the downflow is rapid enough, the shock strength should be sufficient to excite uv radiation normally associated with the transition region, and furthermore, the radiating shock will be brighter than the transition region. These results lead to a number of observationally testable relationships between the optical and ultraviolet spectra from the condensation and radiating shock

Electrodeposition of nanostructured Sn-Zn coatings

Science.gov (United States)

Salhi, Y.; Cherrouf, S.; Cherkaoui, M.; Abdelouahdi, K.

2016-03-01

The electrodeposition of Sn-Zn coating at ambient temperature was investigated. The bath consists of metal salts SnCl2·2H2O and ZnSO4·7H2O and sodium citrate (NaC6H5Na3O7·2H2O) as complexing agent. To prevent precipitation, the pH is fixed at 5. Reducing tin and zinc through Sncit2- and ZnHcit- complex respectively is confirmed by the presence of two cathodic peaks on the voltammogram. The kinetic of tin (II) reduction process is limited by the SnCit2- dissociation. The SEM and TEM observations have showed that the coating consists of a uniform Sn-Zn layer composed of fine grains on which tin aggregates grow up. XRD revealed peaks corresponding to the hexagonal Zn phase and the tetragonal β-Sn phase.

SN 2006oz

DEFF Research Database (Denmark)

Leloudas, Georgios; Chatzopoulos, E.; Dilday, B.

2012-01-01

to contribute to a better understanding of these objects by studying SN 2006oz, a newly-recognized member of this class. Methods. We present multi-color light curves of SN 2006oz from the SDSS-II SN Survey that cover its rise time, as well as an optical spectrum that shows that the explosion occurred at z ~ 0.......376. We fitted black-body functions to estimate the temperature and radius evolution of the photosphere and used the parametrized code SYNOW to model the spectrum. We constructed a bolometric light curve and compared it with explosion models. In addition, we conducted a deep search for the host galaxy...... to a recombination wave in a circumstellar medium (CSM) and discuss whether this is a common property of all similar explosions. The subsequent rise can be equally well described by input from a magnetar or by ejecta-CSM interaction, but the models are not well constrained owing to the lack of post...

Coronal mass ejection shock fronts containing the two types of intermediate shocks

International Nuclear Information System (INIS)

Steinolfson, R.S.; Hundhausen, A.J.

1990-01-01

Numerical solutions of the time-dependent, magnetohydrodynamic (MHD) equations in two dimensions are used to demonstrate the formation of both types of intermediate shocks in a single shock front for physical conditions that are an idealization of those expected to occur in some observed coronal mass ejections. The key to producing such a shock configuration in the simulations is the use of an initial atmosphere containing a magnetic field representative of that in a coronal streamer with open field lines overlying a region of closed field lines. Previous attempts using just open field lines (perpendicular to the surface) produced shock configurations containing just one of the two intermediate shock types. A schematic of such a shock front containing both intermediate shock types has been constructed previously based solely on the known properties of MHD shocks from the Rankine-Hugoniot equations and specific requirements placed on the shock solution at points along the front where the shock normal and upstream magnetic field are aligned. The shock front also contains, at various locations along the front, a hydrodynamic (nonmagnetic) shock, a switch-on shock, and a fast shock in addition to the intermediate shocks. This particular configuration occurs when the shock front speed exceeds the upstream (preshock) intermediate wave speed but is less than a critical speed defined in the paper (equation 1) along at least some portion of the shock front. A distinctive feature of the front is that it is concave upward (away from the surface) near the region where the field in the preshock plasma is normal to the front of near the central portion of the shock front

Phase Equilibria of Sn-Co-Cu Ternary System

Science.gov (United States)

Chen, Yu-Kai; Hsu, Chia-Ming; Chen, Sinn-Wen; Chen, Chih-Ming; Huang, Yu-Chih

2012-10-01

Sn-Co-Cu ternary alloys are promising lead-free solders, and isothermal sections of Sn-Co-Cu phase equilibria are fundamentally important for the alloys' development and applications. Sn-Co-Cu ternary alloys were prepared and equilibrated at 523 K, 1073 K, and 1273 K (250 °C, 800 °C, and 1000 °C), and the equilibrium phases were experimentally determined. In addition to the terminal solid solutions and binary intermetallic compounds, a new ternary compound, Sn3Co2Cu8, was found. The solubilities of Cu in the α-CoSn3 and CoSn2 phases at 523 K (250 °C) are 4.2 and 1.6 at. pct, respectively, while the Cu solubility in the α-Co3Sn2 phase is as high as 20.0 at. pct. The Cu solubility increases with temperature and is around 30.0 at. pct in the β-Co3Sn2 at 1073 K (800 °C). The Co solubility in the η-Cu6Sn5 phase is also significant and is 15.5 at. pct at 523 K (250 °C).

Reactivity and stability of thallium oxide for fabricating TlSnZnO toward thin-film transistors with high mobility

Energy Technology Data Exchange (ETDEWEB)

Kishimoto, Katsushi [Graduate School of Materials Science, Nara Institute of Science and Technology, Nara, 630-0192 (Japan); Nose, Yoshitaro [Department of Materials Science and Engineering, Kyoto University, Kyoto, 606-8501 (Japan); Ishikawa, Yasuaki, E-mail: yishikawa@ms.naist.jp [Graduate School of Materials Science, Nara Institute of Science and Technology, Nara, 630-0192 (Japan); Fujii, Mami N.; Uraoka, Yukiharu [Graduate School of Materials Science, Nara Institute of Science and Technology, Nara, 630-0192 (Japan)

2016-07-05

Thermal reaction between thallium oxide (Tl{sub 2}O{sub 3}) and zinc oxide (ZnO), tin oxide (SnO{sub 2}) or indium oxide (In{sub 2}O{sub 3}) annealed at 600 °C for 18 h in the air atmosphere was investigated. From XRD results of 600 °C annealed samples, Tl{sub 2}O{sub 3} had the biggest reactivity compared with ZnO. The EDX results suggest the mechanism in which the thallium atoms scattered and attached uniformly only on ZnO particles. We also analyzed XPS data to compare O 1s bond and Tl 4f bond of as-mixed samples with that of annealed samples, and found that Zn and Sn can contribute in improving Tl and O bonding stability. However, the affinity of In for Tl is weaker than that of Zn or Sn. Finally, we prepared the samples mixed with ZnO, SnO{sub 2}, and Tl{sub 2}O{sub 3} powder and the samples mixed with Zn{sub 2}SnO{sub 4} and Tl{sub 2}O{sub 3} powder annealed at 600 °C for 18 h. Results show that Zn{sub 2}SnO{sub 4} has the same or more reactivity than SnO{sub 2} and ZnO mixed particle despite of the more stable and sufficient dispersion of Zn and Sn atoms. More stable TlSnZnO can be fabricated from Zn{sub 2}SnO{sub 4} + Tl{sub 2}O{sub 3} powder by suitable thermal processes. It is expected that TlSnZnO sputtering target can be fabricated by suitable calcination. - Highlights: • Thermal reaction of Tl{sub 2}O{sub 3} and ZnO, SnO or In{sub 2}O{sub 3} were investigate. • It is found that Tl{sub 2}O{sub 3} is reactive with ZnO rather than SnO or In{sub 2}O{sub 3}. • Two-step annealing process is promising route for forming TlSnZnO tablet.

Targeting nominal income growth or inflation?

DEFF Research Database (Denmark)

Jensen, Henrik

2002-01-01

Within a simple New Keynesian model emphasizing forward-looking behavior of private agents, I evaluate optimal nominal income growth targeting versus optimal inflation targeting. When the economy is mainly subject to shocks that do not involve monetary policy trade-offs for society, inflation...

Peculiarities of component interaction in {Gd, Er}-V-Sn Ternary systems at 870 K and crystal structure of RV6Sn6 stannides

International Nuclear Information System (INIS)

Romaka, L.; Stadnyk, Yu.; Romaka, V.V.; Demchenko, P.; Stadnyshyn, M.; Konyk, M.

2011-01-01

Highlights: → {Gd, Er}-V-Sn ternary systems at 870 K are characterized by formation of stannides with general compositions RV 6 Sn 6 . → Isostructural RV 6 Sn 6 compounds were also found with Y, Dy, Ho, Tm, and Lu. → The crystal structure of RV 6 Sn 6 compounds was determined by powder diffraction method. → Structural analysis showed that RV 6 Sn 6 compounds (R = Gd, Dy-Tm, Lu) are disordered; YV 6 Sn 6 is characterized by structure ordering. - Abstract: The phase equilibria in the Gd-V-Sn and Er-V-Sn ternary systems were studied at 870 K by means of X-ray and metallographic analyses in the whole concentration range. Both Gd-V-Sn and Er-V-Sn systems are characterized by formation of one ternary compound at investigated temperature, with stoichiometry RV 6 Sn 6 (SmMn 6 Sn 6 -type, space group P6/mmm, a = 0.55322(3) nm, c = 0.91949(7) nm for Gd, a = 0.55191(2) nm, c = 0.91869(8) nm for Er). Solubility of the third component in the binary compounds was not observed. Compounds with the SmMn 6 Sn 6 -type were also found with Dy, Ho, Tm, and Lu, while YV 6 Sn 6 compound crystallizes in HfFe 6 Ge 6 structure type. All investigated compounds are the first ternary stannides with rare earth elements and vanadium.

Dominant effect of high anisotropy in β-Sn grain on electromigration-induced failure mechanism in Sn-3.0Ag-0.5Cu interconnect

Energy Technology Data Exchange (ETDEWEB)

Huang, M.L., E-mail: huang@dlut.edu.cn; Zhao, J.F.; Zhang, Z.J.; Zhao, N.

2016-09-05

The effect of high diffusivity anisotropy in β-Sn grain on electromigration behavior of micro-bumps was clearly demonstrated using Sn-3.0Ag-0.5Cu solder interconnects with only two β-Sn grains. The orientation of β-Sn grain (θ is defined as the angle between the c-axis of β-Sn grain and the electron flow direction) is becoming the most crucial factor to dominate the different electromigration-induced failure modes: 1) the excessive dissolution of the cathode Cu, blocking at the grain boundary and massive precipitation of columnar Cu{sub 6}Sn{sub 5} intermetallic compounds (IMCs) in the small angle θ β-Sn grain occur when electrons flow from a small angle θ β-Sn grain to a large one; 2) void formation and propagation occur at the cathode IMC/solder interface and no Cu{sub 6}Sn{sub 5} IMCs precipitate within the large angle θ β-Sn grain when electrons flow in the opposite direction. The EM-induced failure mechanism of the two β-Sn grain solder interconnects is well explained in viewpoint of atomic diffusion flux in β-Sn. - Highlights: • High anisotropy in β-Sn dominates different electromigration-induced failure mode. • Excessive dissolution of cathode Cu occurs if electrons flow in forward direction. • Voids initiate and propagate at cathode if electrons flow in reverse direction. • Failure modes are well explained in viewpoint of atomic diffusion flux in β-Sn.

Ethanol electrooxidation on novel carbon supported Pt/SnOx/C catalysts with varied Pt:Sn ratio

International Nuclear Information System (INIS)

Jiang, L.; Colmenares, L.; Jusys, Z.; Sun, G.Q.; Behm, R.J.

2007-01-01

Novel carbon supported Pt/SnO x /C catalysts with Pt:Sn atomic ratios of 5:5, 6:4, 7:3 and 8:2 were prepared by a modified polyol method and characterized with respect to their structural properties (X-ray diffraction (XRD) and transmission electron microscopy (TEM)), chemical composition (XPS), their electrochemical properties (base voltammetry, CO ad stripping) and their electrocatalytic activity and selectivity for ethanol oxidation (ethanol oxidation reaction (EOR)). The data show that the Pt/SnO x /C catalysts are composed of Pt and tin oxide nanoparticles with an average Pt particle diameter of about 2 nm. The steady-state activity of the Pt/SnO x /C catalysts towards the EOR decreases with tin content at room temperature, but increases at 80 deg. C. On all Pt/SnO x /C catalysts, acetic acid and acetaldehyde represent dominant products, CO 2 formation contributes 1-3% for both potentiostatic and potentiodynamic reaction conditions. With increasing potential, the acetaldehyde yield decreases and the acetic acid yield increases. The apparent activation energies of the EOR increase with tin content (19-29 kJ mol -1 ), but are lower than on Pt/C (32 kJ mol -1 ). The somewhat better performance of the Pt/SnO x /C catalysts compared to alloyed PtSn x /C catalysts is attributed to the presence of both sufficiently large Pt ensembles for ethanol dehydrogenation and C-C bond splitting and of tin oxide for OH generation. Fuel cell measurements performed for comparison largely confirm the results obtained in model studies

Syntheses, structural variants and characterization of AInM′S4 (A=alkali metals, Tl; M′ = Ge, Sn) compounds; facile ion-exchange reactions of layered NaInSnS4 and KInSnS4 compounds

International Nuclear Information System (INIS)

Yohannan, Jinu P.; Vidyasagar, Kanamaluru

2016-01-01