New findings for diatomite (Diatomaceous earth) between the villages of manastir and Bešište (Mariovo)

OpenAIRE

Spasovski, Orce; Sijakova-Ivanova, Tena; Doneva, Blagica; Spasovski, Daniel

2016-01-01

Diatomaceous earth as porous, fine granular siliceous sedimentary rock, due to their specific physical-chemical properties, often attracted attention to the study of professional and scientific aspect. For diatomaceous earth from the Manastir–Bešište deposit in geological literature very little has been written, especially its mineralogical and chemical composition. In the paper will be present the latest research and results obtained on samples taken from the surface of the ground from...

Potential use of calcareous mudstones in low hydraulic conductivity earthen barriers for environmental applications.

Science.gov (United States)

Musso, T B; Francisca, F M; Musso, T B; Musso, T B

2013-01-01

Earthen layers play a significant role in isolating contaminants in the subsurface, controlling the migration of contaminant plumes, and as landfill liners and covers. The physical, chemical and mineralogical properties of three calcareous mudstones from the Jagüel and Roca formations in North Patagonia, Argentina, are evaluated to determine their potential for the construction of liners. These mudstones were deposited in a marine environment in the Upper Cretaceous-Paleocene. The tested specimens mainly comprise silt and clay-sized particles, and their mineralogy is dominated by a smectite/illite mixed layer (70-90% Sm) and calcite in smaller proportion. Powdered mudstone samples have little viscosity and swelling potential when suspended in water. The hydraulic conductivity of compacted mudstones and sand-mudstone mixtures is very low (around 1-3 x 10(-10) m/s) and in good agreement with the expected hydraulic behaviour of compacted earthen layers. This behaviour can be attributed to the large amount of fine particles, high specific surface and the close packing of particles as confirmed by scanning electron microscope analysis. The tested materials also show a high cation exchange capacity (50-70 cmol/kg), indicating a high contaminant retardation capability. The calcareous mudstones show satisfactory mineralogical and chemical properties as well as an adequate hydraulic behaviour, demonstrating the potential use of these materials for the construction of compacted liners for the containment of leachate or as covers in landfills. These findings confirm the potential usage of marine calcareous mudstones as a low-cost geomaterial in environmental engineering projects.

Laboratory Testing of Silica Sol Grout in Coal Measure Mudstones

Directory of Open Access Journals (Sweden)

Dongjiang Pan

2016-11-01

Full Text Available The effectiveness of silica sol grout on mudstones is reported in this paper. Using X-ray diffraction (XRD, the study investigates how the silica sol grout modifies mudstone mineralogy. Micropore sizes and mechanical properties of the mudstone before and after grouting with four different materials were determined with a surface area/porosity analyser and by uniaxial compression. Tests show that, after grouting, up to 50% of the mesopore volumes can be filled with grout, the dominant pore diameter decreases from 100 nm to 10 nm, and the sealing capacity is increased. Uniaxial compression tests of silica sol grouted samples shows that their elastic modulus is 21%–38% and their uniaxial compressive strength is 16%–54% of the non-grouted samples. Peak strain, however, is greater by 150%–270%. After grouting, the sample failure mode changes from brittle to ductile. This paper provides an experimental test of anti-seepage and strengthening properties of silica sol.

Elaboration of building materials from industrial waste from solid granular diatomaceous earth

International Nuclear Information System (INIS)

Del Angel S, A.

2015-01-01

In this work the initial characterization of granular solid industrial waste from diatomaceous earth was carried out using techniques of Scanning Electron Microscopy and X-ray Diffraction. In a second stage leaching of the material was undertaken to the US Patent Number 5, 376,000 and 5, 356,601 obtaining the samples M1-S ph 2, M1-L ph, M1-S ph 10 and M1-L ph 10. In the third stage a new characterization of the samples obtained with the techniques of Scanning Electron Microscopy, X-ray Diffraction and Atomic Absorption Spectrometry was performed, the latter in order to determine the efficiency percentage of the leaching process. In the fourth stage the specimens for performing mechanical, physical and chemical tests were manufactured, using molds as PVC pipes of 1 inch in diameter and 2 inches in length, with a composition of 50% of diatomaceous earth and 50% of cement produced in each. Finally, in the fifth stage mechanical testing (compression resistance), physical (moisture absorption rate) and chemical (composition and structure of the material) are performed. In the last stage, when conducting mechanical testing with the test specimens, the presence of bubbles enclosed in each obtaining erroneous results noted, so it was necessary to develop the specimens again, obtaining in this occasion concentrations of 20:80, 40:60, 60:40 and 80:20 of diatomaceous earth with the cement. These results were analyzed to determine if the used material is suitable for the production of building materials such as bricks or partitions, being demonstrated by the tests carried out if they are eligible. (Author)

Porosity, petrophysics and permeability of the Whitby Mudstone (UK)

Science.gov (United States)

Houben, M.; Barnhoorn, A.; Hardebol, N.; Ifada, M.; Boersma, Q.; Douma, L.; Peach, C. J.; Bertotti, G.; Drury, M. R.

2016-12-01

Typically pore diameters in shales range from the µm down to the nm scale and the effective permeability of shale reservoirs is a function of the interconnectivity between the pore space and the natural fracture network present. The length and spacing of mechanical induced and natural fractures is one of the factors controlling gas produtivity from unconventional reservoirs. Permeability of the Whitby Mudstone measured on 1 inch cores was linked to microstructure and combined with natural fracture spacing present in outcrops along the Yorkshire coast (UK) to get insight into possible fluid pathways from reservoir to well. We used a combination of different techniques to characterize the porosity (gas adsorption, Scanning Electron Microscopy), mineralogy (X-Ray Fluorescence, X-Ray Diffraction, Scanning Electron Microscopy) and permeability (pressure step decay) of the Whitby Mudstone. In addition, we mapped the natural fracture network as present in outcrops along the Yorkshire coast (UK) at the 10-2-101m scale. Mineralogically we are dealing with a rock that is high in clay content and has an average organic matter content of about 10%. Results show a low porosity (max. 7%) as well as low permeability for the Whitby Mudstone. The permeability, measured parallel to bedding, depends on the confining pressure and is 86 nanodarcy at 10 MPa effective confining pressure and decreases to 16 nanodarcy at 40 MPa effective confining pressure. At the scale of observation the average distance to nearest natural fracture is in the order of 0.13 meter and 90 percent of all matrix elements are spaced within 0.4 meter to the nearest fracture. By assuming darcy flow, a permeability of 100 nanodarcy and 10% of overpressure we calculated that for the Whitby mudstone most of the gas resides in the matrix for less than 60 days until it reaches the fracture network.

Mineral Trends in Early Hesperian Lacustrine Mudstone at Gale Crater, Mars

Science.gov (United States)

Rampe, E. B.; Ming, D. W.; Grotzinger, J. P.; Morris, R. V.; Blake, D. F.; Vaniman, D. T.; Bristow, T. F.; Morrison, S. M.; Yen, A. S.; Chipera, S. J.;

X-ray diffraction of mineralogical composition of mudstones from eastern Gadaref area, Sudan

International Nuclear Information System (INIS)

Karimeldin, Yassin Ahmed A.

1996-09-01

This study reviews the theoretical and experimental aspects of X-ray diffraction (XRD) technique. Moreover, the mineralogical composition of some mudstones from Gadarif region has been investigated using DIFFRAC-AT software package, by means of searching and matching procedure in the standard XRD patterns edited by International Center for Diffraction Data (ICDD). The X-ray diffraction analysis of the Gadarif mudstones revealed that quartz, kaolinite and tridymite are the major mineral constitutes of these rocks. Whereas other minerals like alunite, coalingate, cristabolite, gutsvechite, hematite, meta-alungen, minamite, monteponite, samarskite, chlorie, illite and smectite represent minor constituents in some samples. Most of the mudstone samples investigated have kaolinite content between 71-100%. This most properly indicates that these rocks were subjected to intense weathering and leaching under warm humid climate. These conditions seems to be less favourable for the formation of clay minerals chlorite, illite and smectite. Generally, the clay mineral types, abundances and distribution appear to be influenced mainly by source rock geology, local environment and climate. Moreover, the high silica content of mudstones reflects the influence of both hydrothermal and weathering process. The high haolinite of these mudstone might suggest a good potential for economic exploitation of the kaoline deposits. Further studies, however, might be needed to investigate other technical properties. Suggestions for further work by XRD are given, and include further additions to the refinement procedures and the purchasing of new computer facilities.(Author)

The occurrence of triglycerides in Namibian Shelf diatomaceous ooze

Science.gov (United States)

Boon, Jaap J.; Irene, W.; Rijpstra, C.; de Leeuw, J. W.; Burlingame, A. L.

1980-01-01

The triglyceride fraction, isolated from extractable lipids of a diatomaceous ooze off shore Walvis Bay (S.W. Africa) by TLC methods, was analyzed by direct probe low and high resolution mass spectrometry. The mass spectral data reveal the fatty acid moieties and their relative distribution in the triglycerides identified. The C 12, C 14, C 15 and C 16 are the major composing fatty acid moieties. The triglycerides are thought to be present in protective structures such as diatom spores, which were found to be present by scanning electron microscopy.

Desulfurization of the exhaust gas with zeolite synthesized from diatomaceous earth

Energy Technology Data Exchange (ETDEWEB)

Miyamoto, M

1975-07-01

Both A type and X type zeolites were prepared from diatomaceous earth and tested for use in flue gas desulfurization. Several diatomaceous earths of known chemical compositions were mixed to obtain a desired molar ratio of silicates, whose maturation was achieved in two steps; room temperature maturation and reflux maturation by heating. If the second maturation was carried out for more than 12 hr, the X type zeolite formation was low. At the best conditions, 80% pure zeolite could be prepared for both types according to their x-ray diffraction spectra. The synthesized x type zeolite adsorbed sulfur dioxide more efficiently than A type zeolite. When a simulated flue gas containing 680 to 840 ppM sulfur dioxide was passed at a flow rate of 9.0 Nl/min through a 250 g zeolite column, the column breaking time (time required for the SO/sub 2/ concentration of the column effluent to reach 10% of the initial SO/sub 2/ concentration) was 5.3 hr, while that for the commercial zeolite and activated carbon was 6.8 hr and 8.0 hr, respectively. If the flue gas contained more than 1% moisture, the adsorbed water reacted with SO/sub 2/ and the zeolite crystal tended to break down. The use of zeolite for flue gas desulfurization was more costly than the use of activated carbon.

Profundal sideritic mudstone from an Eocene lake in Alaska

International Nuclear Information System (INIS)

Dickinson, K.A.

1987-01-01

Sideritic lacustrine mudstone was found in drill core from a uranium deposit in the Death Valley area in the eastern part of the Seward Peninsula, Alaska. The precursor sediments for this rock were deposited in an unusual iron-meromictic Eocene lake, herein named Lake Tubutulik, which occupied part of the Boulder Creek basin, a graben that is probably a southern extension of the larger Death Valley basin. The Boulder Creek basin is bounded on the west by granite of the Upper Cretaceous Darby pluton and on the east by Precambrian to Paleozoic metasedimentary rocks. The lake basin was formed by basaltic flows that dammed the valley of the ancestral Tubutulik River in early Eocene time. The lake sediments included a nearshore facies of fine-grained organic mud and an offshore facies of laminated sideritic mud. The offshore (profundal) laminated mudstone consists of alternating layers of authigenic siderite and detrital grains, mostly quartz and clay minerals. Both lacustrine facies contain turbidites. The lacustrine rocks graded laterally into an onshore facies of colluvial and fluvial sandstone, paludal mudstone, and coal. The ancient lake occupied a small, deep basin in a tectonically active area of high relief. Meromixis was apparently stabilized by reduced iron and bicarbonate dissolved in the monimolimnion. The intensity of meromixis decreased as the lake became shallower from sediment filling. The source of the dissolved iron in the monoimolimnion was probably the Eocene basalt. Carbon isotope analysis of the siderite suggests that the dissolved bicarbonate in the profundal facies was largely inorganic. Sideritic carbon in one sample from the onshore paludal facies has an isotopic signature (δ 13 C = +16.9) consistent with residual carbonate formed during methanogenic fermentation

Mineralogy of a mudstone at Yellowknife Bay, Gale crater, Mars

NARCIS (Netherlands)

Vaniman, D.T.; Bish, D.L.; Ming, D.W.; Bristow, T.F.; Morris, R.V.; Blake, D.F.; Chipera, S.J.; Morrison, S.M.; Treiman, A.H.; Rampe, E.B.; Rice, M.; Achilles, C.N.; Grotzinger, J.P.; McLennan, S.M.; Williams, J.; Bell III, J.F.; Newsom, H.E.; Downs, R.T.; Maurice, S.; Sarrazin, P.; Yen, A.S.; Morookian, J.M.; Farmer, J.D.; Stack, K.; Milliken, R.E.; Ehlmann, B.L.; Sumner, D.Y.; Berger, G.; Crisp, J.A.; Hurowitz, J.A.; Anderson, R.; Des Marais, D.J.; Stolper, E.M.; Edgett, K.S.; Gupta, S.; Spanovich, N.; MSL Science Team, the|info:eu-repo/dai/nl/292012217

2014-01-01

Sedimentary rocks at Yellowknife Bay (Gale crater) on Mars include mudstone sampled by the Curiosity rover. The samples, John Klein and Cumberland, contain detrital basaltic minerals, calcium sulfates, iron oxide or hydroxides, iron sulfides, amorphous material, and trioctahedral smectites. The John

Development of the Portland cement slurries with diatomaceous earth to the oil industry; Desenvolvimento de pastas de cimento Portland com adicao de diatomita para a industria do petroleo

Energy Technology Data Exchange (ETDEWEB)

Brito, Roseane A; Melo, Dulce M.A.; Martinelli, Antonio E.; Simao, Cristina A.; Paiva, Maria D.M. [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil); Melo, Marcus A.F. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES)

2004-07-01

The class-G Portland cement has been used with success in oil well cementing. The material is usually shipped to the Northeast Brazil, because the only plant that manufactures class-G is located in Cantagalo/RJ. The present work investigates the influence of the partial substitution of Portland cement by diatomaceous earth, aiming at reducing the costs in oil well cementing, improving the slurry properties and using local raw material. The diatomaceous earth has pozzolanic properties and can be used as extenders of cement slurries. This properties added to the lower cost and availability of this material in Northeast Brazil, make the diatomaceous earth a candidate material to produce light cements, to well conditions in advanced phases of production. It were evaluated the rheological properties of the slurries (at 25 and 52 deg C), volume of free water, compressive strength after curing for 8, 24 and 48 h at 38 deg C, and consistometry tests. The results show that the diatomaceous earth maintain the viscosity values and gel force suitable for use in oil well cementing. No free water was observed in the formulations. It was also verified that the compressive strength of slurries hardened with diatomaceous earth is similar to those with only Portland cement and that the minimum compressive strength of 300 psi, after curing for 8 h was reached. The thickening time was longer than the average value and the application value. (author)

Compositional controls on early diagenetic pathways in fine-grained sedimentary rocks: Implications for predicting unconventional reservoir attributes of mudstones

Science.gov (United States)

Keller, Margaret A.; Macquaker, Joe H.S.; Taylor, Kevin G.; Polya, David

2014-01-01

Diagenesis significantly impacts mudstone lithofacies. Processes operating to control diagenetic pathways in mudstones are poorly known compared to analogous processes occurring in other sedimentary rocks. Selected organic-carbon-rich mudstones, from the Kimmeridge Clay and Monterey Formations, have been investigated to determine how varying starting compositions influence diagenesis.The sampled Kimmeridge Clay Formation mudstones are organized into thin homogenous beds, composed mainly of siliciclastic detritus, with some constituents derived from water-column production (e.g., coccoliths, S-depleted type-II kerogen, as much as 52.6% total organic carbon [TOC]) and others from diagenesis (e.g., pyrite, carbonate, and kaolinite). The sampled Monterey Formation mudstones are organized into thin beds that exhibit pelleted wavy lamination, and are predominantly composed of production-derived components including diatoms, coccoliths, and foraminifera, in addition to type-IIS kerogen (as much as 16.5% TOC), and apatite and silica cements.During early burial of the studied Kimmeridge Clay Formation mudstones, the availability of detrital Fe(III) and reactive clay minerals caused carbonate- and silicate-buffering reactions to operate effectively and the pore waters to be Fe(II) rich. These conditions led to pyrite, iron-poor carbonates, and kaolinite cements precipitating, preserved organic carbon being S-depleted, and sweet hydrocarbons being generated. In contrast, during the diagenesis of the sampled Monterey Formation mudstones, sulfide oxidation, coupled with opal dissolution and the reduced availability of both Fe(III) and reactive siliciclastic detritus, meant that the pore waters were poorly buffered and locally acidic. These conditions resulted in local carbonate dissolution, apatite and silica cements precipitation, natural kerogen sulfurization, and sour hydrocarbons generation.Differences in mud composition at deposition significantly influence subsequent

Hydrothermal Synthesis of Analcime from Kutingkeng Formation Mudstone

Science.gov (United States)

Hsiao, Yin-Hsiu; Chen, Kuan-Ting; Ray, Dah-Tong

2015-04-01

In southwest of Taiwan, the foothill located in Tainan-Kaohsiung city is the exposed area of Pliocene strata to early Pleistocene strata. The strata are about a depth of five thousand, named as Kutigkeng Formation. The outcrop of Kutigkeng Formation is typical badlands, specifically called 'Moon World.' It is commonly known as no important economic applications of agricultural land. The mineral compositions of Kutingkeng Formation are quartz, clay minerals and feldspar. The clay minerals consist of illite, clinochlore and swelling clays. To study how the phase and morphology of analcime formed by hydrothermal synthesis were affected, analcime was synthesized from the mudstone of Kutinkeng Formation with microwave hydrothermal reaction was investigated. The parameters of the experiment were the reaction temperature, the concentration of mineralizer, solids/liquid ratio and time. The sodium silicate (Na2SiO3) were used as mineralizer. The results showed that the analcime could be synthesized by hydrothermal reaction above 180° from Kutinkeng Formation mudstone samples. At the highest temperature (240°) of this study, the high purity analcime could be produced. When the concentration of Na2SiO3=3~6M, analcime could be synthesized at 240°. The best solids/liquid ratio was approximate 1 to 5. The hydrothermal reaction almost was completed after 4 hours.

Shear Resistance Variations in Experimentally Sheared Mudstone Granules: A Possible Shear-Thinning and Thixotropic Mechanism

Science.gov (United States)

Hu, Wei; Xu, Qiang; Wang, Gonghui; Scaringi, Gianvito; Mcsaveney, Mauri; Hicher, Pierre-Yves

2017-11-01

We present results of ring shear frictional resistance for mudstone granules of different size obtained from a landslide shear zone. Little rate dependency of shear resistance was observed in sand-sized granules in any wet or dry test, while saturated gravel-sized granules exhibited significant and abrupt reversible rate-weakening (from μ = 0.6 to 0.05) at about 2 mm/s. Repeating resistance variations occurred also under constant shear displacement rate. Mudstone granules generate mud as they are crushed and softened. Shear-thinning and thixotropic behavior of the mud can explain the observed behavior: with the viscosity decreasing, the mud can flow through the coarser soil pores and migrate out from the shear zone. This brings new granules into contact which produces new mud. Thus, the process can start over. Similarities between experimental shear zones and those of some landslides in mudstone suggest that the observed behavior may play a role in some landslide kinematics.

Grain Size Distribution in Mudstones: A Question of Nature vs. Nurture

Science.gov (United States)

Schieber, J.

2011-12-01

Grain size distribution in mudstones is affected by the composition of the source material, the processes of transport and deposition, and post-depositional diagenetic modification. With regard to source, it does make a difference whether for example a slate belt is eroded vs a stable craton. The former setting tends to provide a broad range of detrital quartz in the sub 62 micron size range in addition to clays and greenschist grade rock fragments, whereas the latter may be biased towards coarser quartz silt (30-60 microns), in addition to clays and mica flakes. In flume experiments, when fine grained materials are transported in turbulent flows at velocities that allow floccules to transfer to bedload, a systematic shift of grain size distribution towards an increasingly finer grained suspended load is observed as velocity is lowered. This implies that the bedload floccules are initially constructed of only the coarsest clay particles at high velocities, and that finer clay particles become incorporated into floccules as velocity is lowered. Implications for the rock record are that clay beds deposited from decelerating flows should show subtle internal grading of coarser clay particles; and that clay beds deposited from continuous fast flows should show a uniform distribution of coarse clays. Still water settled clays should show a well developed lower (coarser) and upper (finer) subdivision. A final complication arises when diagenetic processes, such as the dissolution of biogenic silica, give rise to diagenetic quartz grains in the silt to sand size range. This diagenetic silica precipitates in fossil cavities and pore spaces of uncompacted muds, and on casual inspection can be mistaken for detrital quartz. In distal mudstone successions close to 100 % of "apparent" quartz silt can be of that origin, and reworking by bottom currents can further enhance a detrital perception by producing rippled and laminated silt beds. Although understanding how size

Bioactivity of diatomaceous earth to Sitophilus zeamais (Coleoptera: Curculionidae in different application conditions

Directory of Open Access Journals (Sweden)

Adalberto H. Sousa

2013-09-01

Full Text Available The objective of this study was to evaluate the insecticidal activity of diatomaceous earth (DE at different ambient temperatures on adult Sitophilus zeamais and progeny, using different doses and exposure periods. The experiments were performed in Petri dishes containing 40 g of the whole corn kernel, treated with DE at doses of 0, 0.25, 0.5 and 1.0 kg Mg-1. Each dish was infested with 25 S. zeamais adults and kept at climatic chambers under temperatures of 20, 25, 30, 35 and 40 ºC. The insect mortality was recorded after six and 15 days from the beginning of the bioassays. The grains evaluated at 15 days were separated from insects and kept in the dishes for another 75 days under the same temperature conditions. After this period the effect of ambient temperature and of diatomaceous earth doses on the emergence of S. zeamais in the F1 generation was evaluated. It was found that the mortality of S. zeamais increased with the higher dose and temperature during the exposure period of six and 15 days. The number of insects emerged reduced with increasing temperature in these two exposure periods. The increase of temperature and exposure period favored the efficacy of DE in lower doses for control of S. zeamais.

Various causes behind the desorption hysteresis of carboxylic acids on mudstones.

Science.gov (United States)

Rasamimanana, S; Lefèvre, G; Dagnelie, R V H

2017-02-01

Adsorption desorption is a key factor for leaching, migration and (bio)degradation of organic pollutants in soils and sediments. Desorption hysteresis of apolar organic compounds is known to be correlated with adsorption/diffusion into soil organic matter. This work focuses on the desorption hysteresis of polar organic compounds on a natural mudstone sample. Acetic, citric and ortho-phthalic acids displayed adsorption-desorption hysteresis on Callovo-Oxfordian mudstone. The non-reversible behaviours resulted from three different mechanisms. Adsorption and desorption kinetics were evaluated using 14C- and 3H-labelled tracers and an isotopic exchange method. The solid-liquid distribution ratio of acetate decreased using a NaN 3 bactericide, indicating a rapid bacterial consumption compared with negligible adsorption. The desorption hysteresis of phthalate was apparent and suppressed by the equilibration of renewal pore water with mudstone. This confirms the significant and reversible adsorption of phthalate. Finally, persistent desorption hysteresis was evidenced for citrate. In this case, a third mechanism should be considered, such as the incorporation of citrate in the solid or a chemical perturbation, leading to strong desorption resilience. The results highlighted the different pathways that polar organic pollutants might encounter in a similar environment. Data on phthalic acid is useful to predict the retarded transport of phthalate esters and amines degradation products in sediments. The behaviour of citric acid is representative of polydentate chelating agents used in ore and remediation industries. The impact of irreversible adsorption on solid/solution partitioning and transport deserves further investigation. Copyright © 2016 Elsevier Ltd. All rights reserved.

Rill erosion of mudstone slope-a case study of southern Taiwan

Science.gov (United States)

Yang, Ci-Jian; Lin, Jiun-chuan; Cheng, Yuan-Chang

2014-05-01

Soil erosion has been studied by many scientists for decades (Zingg, 1940; Meyer & Wischmeier, 1969; Foster, 1982; Luk, 1988) and many soil erosion prediction equations have already been developed, such as USLE, RUSLE. In spite of WEEP is based on hydrological physical model, all of the above models are restricted to predict concentrate flow. On the other hand, rill erosion is not understood completely. The amounts of rill erosion are always underestimated. Rill Erosion correlate closely to gradient (Cerda & Garcia-Fayos, 1997; Fox & Bryan, 1999; Fu,et al., 2011; Clarke & Rendell, 2006), slope length (Gabriel, 1999; Yair, 2004), particle distribution (Gabriel, 1999), proportion of clay (Luk,1977; Bryan2000), rainfall intensity (Römkens et al. 2001), and land use (Dotterweich, 2008). However, the effect of micromorphology of mud rock surface, such as mud-cracks, could be studied in more details. This research aims to simulate rill development by hydraulic flume to observe the morphological change caused by rill/erosion process. Mudstone specimens sampled from the mudstone area of Long-Chi, southern Taiwan. The results show that: (1) The erosion pattern of mudstone slope can be divided into four steps: (a) inter-rill erosion, ( b) rill erosion, (c) rill development, (d) slope failure. (2) Slopes with mud-cracks caused 125% soil loss than smooth slopes. (3) Mud-cracks affect spatial distribution of rill development (4) The sediment concentration decreased sharply in the beginning of experiments, however increased due to rill development. This paper demonstrated such a rill development. 1: Department of Geography, National Taiwan University. E-mail:maxpossibilism0929@gmail.com

X-ray diffraction analysis of mudstone from nw sudan

International Nuclear Information System (INIS)

Salih, Suad Z.Elabdeen

1997-03-01

This study deals with the theoretical and experimental aspects of the x-ray diffraction technique (XRD). The XRD technique is used to investigate fine structure of matter, and it is most efficient method for the determination of the mineralogical composition of rocks. The XRD technique is used also to investigate the clay mineralogical of mud-stones of the Nubian sandstones of north western Sudan. The XRD results revealed that the mud-stone samples are composed, in decreasing abundance's of kaolinite, smectite, chlorite and illite. Non-clay minerals reported include quartz, feldspars and geothite. Kaolinite dominates in most of samples with percentages ranging between 78-96%. Smectite comes second in abundance and ranges between 10-24%, followed by chlorite and illite which showed the lowest abundance's. The dominance of kaolinite over smectite indicates that intense chemical weathering and leaching occurred under warm humid climate interrupted by dry periods. Most probably these clay minerals were produced by inheritance and partly by neo formation. The variation of the chemical composition of these mud stones is due basically to differences in clay mineralogy which was controlled by source rock geology, weathering physicochemical behavior of elements, local environment and climatic condition in the past. (Author)

Experimental Investigation on Hydraulic Properties of Granular Sandstone and Mudstone Mixtures

Directory of Open Access Journals (Sweden)

Dan Ma

2018-01-01

Full Text Available The caved zone during longwall mining has high permeability, resulting in a mass of groundwater storage which causes a threat of groundwater inrush hazard to the safe mining. To investigate the hazard mechanism of granular sandstone and mudstone mixture (SMM in caved zone, this paper presents an experimental study on the effect of sandstone particle (SP and mudstone particle (MP weight ratio on the non-Darcy hydraulic properties evolution. A self-designed granular rock seepage experimental equipment has been applied to conduct the experiments. The variation of particle size distribution was induced by loading and water seepage during the test, which indicated that the particle crushing and erosion properties of mudstone were higher than those of sandstone. Porosity evolution of SMM was strongly influenced by loading (sample height and SP/MP weight ratio. The sample with higher sample height and higher weight ratio of SP achieved higher porosity value. In particular, a non-Darcy equation, for hydraulic properties (permeability κ and non-Darcy coefficient ζ calculation, was sufficient to fit the relation between the hydraulic gradient and seepage velocity. The test results indicated that, due to the absence and narrowing of fracture and void during loading, the permeability κ decreases and the non-Darcy coefficient ζ increases. The variation of the hydraulic properties of the sample within the same particle size and SP/MP weight ratio indicated that groundwater inrush hazard showed a higher probability of occurrence in sandstone strata and crushed zone (e.g., faults. Moreover, isolated fractures and voids were able to achieve the changeover from self-extension to interconnection at the last loading stage, which caused the fluctuation tendency of κ and ζ. Fluctuation ability in mudstone was higher than that in sandstone. The performance of an empirical model was also investigated for the non-Darcy hydraulic properties evolution prediction of

Diatomaceous earth and activated bauxite used as granular sorbents for the removal of sodium chloride vapor from hot flue gas

Energy Technology Data Exchange (ETDEWEB)

Lee, S.H.D.; Swift, W.M.; Johnson, I.

1980-01-01

Diatomaceous earth and activated bauxite were tested as granular sorbents for use as filter media in granular-bed filters for the removal of gaseous alkali metal compounds from the hot (800/sup 0/C) flue gas of PFBC. Tests were performed at atmospheric pressure, using NaCl vapor transported in relatively dry simulated flue gas of PFBC. Either a fixed-bed combustor or a high-temperature sorption test rig was used. The effects of sorbent bed temperature, superficial gas velocity, gas hourly space velocity, and NaCl-vapor concentration in flue gas on the sorption behavior of these two sorbents and their ultimate sorption capacities were determined. Both diatomaceous earth and activated bauxite were found to be very effective in removing NaCl vapor from flue gas. Preliminary cost evaluations showed that they are economically attractive as granular sorbents for cleaning alkali vapor from simulated flue gas.

Whitby Mudstone, flow from matrix to fractures

Science.gov (United States)

Houben, Maartje; Hardebol, Nico; Barnhoorn, Auke; Boersma, Quinten; Peach, Colin; Bertotti, Giovanni; Drury, Martyn

2016-04-01

Fluid flow from matrix to well in shales would be faster if we account for the duality of the permeable medium considering a high permeable fracture network together with a tight matrix. To investigate how long and how far a gas molecule would have to travel through the matrix until it reaches an open connected fracture we investigated the permeability of the Whitby Mudstone (UK) matrix in combination with mapping the fracture network present in the current outcrops of the Whitby Mudstone at the Yorkshire coast. Matrix permeability was measured perpendicular to the bedding using a pressure step decay method on core samples and permeability values are in the microdarcy range. The natural fracture network present in the pavement shows a connected network with dominant NS and EW strikes, where the NS fractures are the main fracture set with an orthogonal fracture set EW. Fracture spacing relations in the pavements show that the average distance to the nearest fracture varies between 7 cm (EW) and 14 cm (NS), where 90% of the matrix is 30 cm away from the nearest fracture. By making some assumptions like; fracture network at depth is similar to what is exposed in the current pavements and open to flow, fracture network is at hydrostatic pressure at 3 km depth, overpressure between matrix and fractures is 10% and a matrix permeability perpendicular to the bedding of 0.1 microdarcy, we have calculated the time it takes for a gas molecule to travel to the nearest fracture. These input values give travel times up to 8 days for a distance of 14 cm. If the permeability is changed to 1 nanodarcy or 10 microdarcy travel times change to 2.2 years or 2 hours respectively.

Strength and impermeability recovery of siliceous mudstone from complete failure

International Nuclear Information System (INIS)

Sugita, Yutaka; Sanada, Masanori; Fujita, Tomoo; Hashiba, Kimihiro; Fukui, Katsunori; Okubo, Seisuke

2013-01-01

Radionuclide migration can be undesirably increased by weakening the mechanical properties of a rock mass in the excavated disturbed zone (EDZ) around the tunnels of a geological disposal facility for high level radioactive waste. Laboratory testing of loading stress and loading time on failed siliceous mudstone specimens has identified the potential for the long-term recovery of the strength and impermeability of the rock mass in the EDZ. (author)

Making synthetic mudstone: Parametric resedimentation studies at high effective stress to determine controls on breakthrough pressure and permeability

Science.gov (United States)

Guiltinan, E. J.; Cardenas, M. B.; Cockrell, L.; Espinoza, N.

2017-12-01

The geologic sequestration of CO2 is widely considered a potential solution for decreasing anthropogenic atmospheric CO2 emissions. As CO2 rises buoyantly within a reservoir it pools beneath a caprock and a pressure is exerted upon the pores of the caprock proportionally to the height of the pool. The breakthrough pressure is the point at which CO2 begins to flow freely across the caprock. Understanding the mineralogical and grain size controls on breakthrough pressure is important for screening the security of CO2 sequestration sites. However, breakthrough pressure and permeability measurements on caprocks are difficult to conduct in a systematic manner given the variability in and heterogeneity of naturally occurring mudstones and shales causing significant noise and scatter in the literature. Recent work has even revealed the ability for CO2 to pass through thin shale beds at relatively low pressures. To broaden the understanding of shale breakthrough and permeability, we developed an approach that allows for the creation of resedimented mudstones at high effective stresses. Resedimented samples also include calcium carbonate cement. Using this technique, we explore the controls on entry pressure, breakthrough pressure, and permeability of synthetic mudstones. Understanding the effect of mineralogy and grain size on the permeability and breakthrough pressure of mudstones at reservoir stresses will help in the selection and uncertainty quantification of secure CO2 storage sites.

Detailed facies analysis of the Upper Cretaceous Tununk Shale Member, Henry Mountains Region, Utah: Implications for mudstone depositional models in epicontinental seas

Science.gov (United States)

Li, Zhiyang; Schieber, Juergen

2018-02-01

Lower-Middle Turonian strata of the Tununk Shale Member of the greater Mancos Shale were deposited along the western margin of the Cretaceous Western Interior Seaway during the Greenhorn second-order sea level cycle. In order to examine depositional controls on facies development in this mudstone-rich succession, this study delineates temporal and spatial relationships in a process-sedimentologic-based approach. The 3-dimensional expression of mudstone facies associations and their stratal architecture is assessed through a fully integrative physical and biologic characterization as exposed in outcrops in south-central Utah. Sedimentologic characteristics from the millimeter- to kilometer-scale are documented in order to fully address the complex nature of sediment transport mechanisms observed in this shelf muddy environment. The resulting facies model developed from this characterization consists of a stack of four lithofacies packages including: 1) carbonate-bearing, silty and sandy mudstone (CSSM), 2) silt-bearing, calcareous mudstone (SCM), 3) carbonate-bearing, silty mudstone to muddy siltstone (CMS), and 4) non-calcareous, silty and sandy mudstone (SSM). Spatial and temporal variations in lithofacies type and sedimentary facies characteristics indicate that the depositional environments of the Tununk Shale shifted in response to the 2nd-order Greenhorn transgressive-regressive sea-level cycle. During this eustatic event, the Tununk shows a characteristic vertical shift from distal middle shelf to outer shelf (CSSM to SCM facies), then from outer shelf to inner shelf environment (SCM to CMS, and to SSM facies). Shifting depositional environments, as well as changes in dominant paleocurrent direction throughout this succession, indicate multiple source areas and transport mechanisms (i.e. longshore currents, offshore-directed underflows, storm reworking). This study provides a rare documentation of the Greenhorn cycle as exposed across the entire shelf setting

Geology and lithogeochemistry of hydrothermal mudstones from the upper block near the Duck Pond volcanogenic massive sulfide (VMS) deposit, Newfoundland, Canada: evidence for low-temperature venting into oxygenated mid-Cambrian seawater

Science.gov (United States)

Piercey, Stephen J.; Squires, Gerry; Brace, Terry

2018-02-01

Pyrite- and pyrrhotite-rich mudstones are spatially associated with Cambrian ( 512-509 Ma) volcanogenic massive sulfide (VMS) deposits throughout the Tally Pond group, central Newfoundland, Canada. At the Duck Pond mine, sulfide-rich mudstones are hosted within a weakly mineralized upper block that structurally overlies the deposit but is older ( 513 versus 509 Ma). The mudstones are laminated, 10-30-cm thick, and pyrite- and pyrrhotite-rich and occur along pillow lava selvages, or in between pillow lavas, rhyolite flows, and volcaniclastic rocks. The mudstones are laterally extensive and proximal to the mudstone host rocks are hydrothermally altered to epidote-quartz-chlorite (basalt host) and sericite-quartz (rhyolite host). Lithogeochemical data for the sulfide-rich mudstones reflect the varying contributions of elements from sedimentary detritus, hydrothermal discharge, and hydrogenous scavenging from middle Cambrian seawater. The mudstones have minor detrital element abundances and significant hydrothermal element enrichments (i.e., elevated Fe2O3, S, Pb, Zn, Cu, and Ba concentrations, high Fe/Al ratios). The hydrothermal mudstones are also enriched in oxyanions (i.e., P2O5, U, V, Cr, Ni, Co, and Hg), interpreted to have been enriched via oxidative scavenging from seawater by Fe-oxide/oxyhydroxide particles. The mudstones also have REE-Y signatures similar to modern oxygenated seawater with high Y/Ho and negative Ce anomalies (Ce/Ce* = 0.40-0.86; average = 0.58), which correlate with adsorbed oxyanion concentrations. The low Eu/Eu* (1.02-1.86; average = 1.22) in the mudstones suggest that they were deposited from low-temperature (residence time to scavenge oxyanions from seawater and inherit a middle Cambrian seawater signature. The predominant seawater REE-Y-oxyanion signature in the Duck Pond upper block sulfide-rich mudstones suggests that they are distal hydrothermal sedimentary rocks that could have formed up to 10 km from their original vent sources

Native copper in Permian Mudstones from South Devon: A natural analogue of copper canisters for high-level radioactive waste

International Nuclear Information System (INIS)

Milodowski, A.E.; Styles, M.T.; Werme, L.; Oversby, V.M.

2001-01-01

Native copper (>99.9% Cu) sheets associated with complex uraniferous and vanadiferous concretions in Upper Permian Mudstones from south Devon (United Kingdom) have been studied as a 'natural analogue' for copper canisters designed to be used in the isolation of spent fuel and high-level radioactive wastes (HLW) for deep geological disposal. Detailed analysis demonstrates that the copper formed before the mudstones were compacted. The copper displays complex corrosion and alteration. The earliest alteration was to copper oxides, followed sequentially by the formation of copper arsenides, nickel arsenide and copper sulphide, and finally nickel arsenide accompanied by nickel-copper arsenide, copper arsenide and uranium silicates. Petrographic observations demonstrate that these alteration products also formed prior to compaction. Consideration of the published history for the region indicates that maximum compaction of the rocks will have occurred by at least the Lower Jurassic (i.e. over 176 Ma ago). Since that time the copper sheets have remained isolated by the compacted mudstones and were unaffected by further corrosion until uplift and exposure to present-day surface weathering

Initial characterization of mudstone nanoporosity with small angle neutron scattering using caprocks from carbon sequestration sites

International Nuclear Information System (INIS)

McCray, John; Navarre-Sitchler, Alexis; Mouzakis, Katherine; Heath, Jason E.; Dewers, Thomas A.; Rother, Gernot

2010-01-01

Geological carbon sequestration relies on the principle that CO 2 injected deep into the subsurface is unable to leak to the atmosphere. Structural trapping by a relatively impermeable caprock (often mudstone such as a shale) is the main trapping mechanism that is currently relied on for the first hundreds of years. Many of the pores of the caprock are of micrometer to nanometer scale. However, the distribution, geometry and volume of porosity at these scales are poorly characterized. Differences in pore shape and size can cause variation in capillary properties and fluid transport resulting in fluid pathways with different capillary entry pressures in the same sample. Prediction of pore network properties for distinct geologic environments would result in significant advancement in our ability to model subsurface fluid flow. Specifically, prediction of fluid flow through caprocks of geologic CO 2 sequestration reservoirs is a critical step in evaluating the risk of leakage to overlying aquifers. The micro- and nanoporosity was analyzed in four mudstones using small angle neutron scattering (SANS). These mudstones are caprocks of formations that are currently under study or being used for carbon sequestration projects and include the Marine Tuscaloosa Group, the Lower Tuscaloosa Group, the upper and lower shale members of the Kirtland Formation, and the Pennsylvanian Gothic shale. Total organic carbon varies from <0.3% to 4% by weight. Expandable clay contents range from 10% to ∼40% in the Gothic shale and Kirtland Formation, respectively. Neutrons effectively scatter from interfaces between materials with differing scattering length density (i.e. minerals and pores). The intensity of scattered neutrons, I(Q), where Q is the scattering vector, gives information about the volume of pores and their arrangement in the sample. The slope of the scattering data when plotted as log I(Q) vs. log Q provides information about the fractality or geometry of the pore network

Initial characterization of mudstone nanoporosity with small angle neutron scattering using caprocks from carbon sequestration sites.

Energy Technology Data Exchange (ETDEWEB)

McCray, John (Colorado School of Mines); Navarre-Sitchler, Alexis (Colorado School of Mines); Mouzakis, Katherine (Colorado School of Mines); Heath, Jason E.; Dewers, Thomas A.; Rother, Gernot (Oak Ridge National Laboratory)

2010-11-01

Geological carbon sequestration relies on the principle that CO{sub 2} injected deep into the subsurface is unable to leak to the atmosphere. Structural trapping by a relatively impermeable caprock (often mudstone such as a shale) is the main trapping mechanism that is currently relied on for the first hundreds of years. Many of the pores of the caprock are of micrometer to nanometer scale. However, the distribution, geometry and volume of porosity at these scales are poorly characterized. Differences in pore shape and size can cause variation in capillary properties and fluid transport resulting in fluid pathways with different capillary entry pressures in the same sample. Prediction of pore network properties for distinct geologic environments would result in significant advancement in our ability to model subsurface fluid flow. Specifically, prediction of fluid flow through caprocks of geologic CO{sub 2} sequestration reservoirs is a critical step in evaluating the risk of leakage to overlying aquifers. The micro- and nanoporosity was analyzed in four mudstones using small angle neutron scattering (SANS). These mudstones are caprocks of formations that are currently under study or being used for carbon sequestration projects and include the Marine Tuscaloosa Group, the Lower Tuscaloosa Group, the upper and lower shale members of the Kirtland Formation, and the Pennsylvanian Gothic shale. Total organic carbon varies from <0.3% to 4% by weight. Expandable clay contents range from 10% to {approx}40% in the Gothic shale and Kirtland Formation, respectively. Neutrons effectively scatter from interfaces between materials with differing scattering length density (i.e. minerals and pores). The intensity of scattered neutrons, I(Q), where Q is the scattering vector, gives information about the volume of pores and their arrangement in the sample. The slope of the scattering data when plotted as log I(Q) vs. log Q provides information about the fractality or geometry of

Evidence for Smectite Clays from MSL SAM Analyses of Mudstone at Yellowknife Bay, Gale Crater, Mars

Science.gov (United States)

McAdam, Amy; Franz, Heather; Mahaffy, Paul R.; Eigenbrode, Jennifer L.; Stern, Jennifer C.; Brunner, Anna; Archer, Paul Douglas; Ming, Douglas W.; Morris, Richard V.; Atreya, Sushil K.

2013-01-01

Drilled samples of mudstone from the Sheepbed unit at Yellowknife Bay were analyzed by MSL instruments including the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments in MSL's Analytical Laboratory. CheMin analyses revealed the first in situ X-ray diffraction based evidence of clay minerals on Mars, which are likely trioctahedral smectites (e.g., saponite) and comprise approx 20% of the mudstone sample (e.g., Bristow et al., this meeting). SAM analyses, which heated the mudstone samples to 1000 C and monitored volatiles evolved to perform in situ evolved gas analysis mass spectrometry (EGA-MS), resulted in a H2O trace exhibiting a wide evolution at temperatures smectite interlayer H2O, and structural H2O/OH from bassanite and akaganeite (identified by CheMin) and H2O/OH from amorphous phases in the sample. The high temperature H2O is consistent with the evolution of H2O from the dehydroxylation of the smectite clay mineral. Comparison to EGA-MS data collected under SAM-like conditions on a variety of clay mineral reference materials indicate that a trioctahedral smectite, such as saponite, is most consistent with the high temperature H2O evolution observed. There may also be SAM EGA-MS evidence for a small high temperature H2O evolution from scoop samples from the Yellowknife Bay Rocknest sand shadow bedform. As in the mudstone samples, this evolution may indicate the detection of smectite clays, and the idea that minor clays may be present in Rocknest materials that could be expected to be at least partially derived from local sources is reasonable. But, because smectite clays were not definitively observed in CheMin analyses of Rocknest materials, they must be present at much lower abundances than the approx 20% observed in the mudstone samples. This potential detection underscores the complementary nature of the MSL CheMin and SAM instruments for investigations of martian sample mineralogy. Information on the nature of Yellowknife

The nature of porosity in organic-rich mudstones of the Upper Jurassic Kimmeridge Clay Formation, North Sea, offshore United Kingdom

Science.gov (United States)

Fishman, Neil S.; Hackley, Paul C.; Lowers, Heather; Hill, Ronald J.; Egenhoff, Sven O.; Eberl, Dennis D.; Blum, Alex E.

2012-01-01

Analyses of organic-rich mudstones from wells that penetrated the Upper Jurassic Kimmeridge Clay Formation, offshore United Kingdom, were performed to evaluate the nature of both organic and inorganic rock constituents and their relation to porosity in this world-class source rock. The formation is at varying levels of thermal maturity, ranging from immature in the shallowest core samples to mature in the deepest core samples. The intent of this study was to evaluate porosity as a function of both organic macerals and thermal maturity. At least four distinct types of organic macerals were observed in petrographic and SEM analyses and they all were present across the study area. The macerals include, in decreasing abundance: 1) bituminite admixed with clays; 2) elongate lamellar masses (alginite or bituminite) with small quartz, feldspar, and clay entrained within it; 3) terrestrial (vitrinite, fusinite, semifusinite) grains; and 4) Tasmanites microfossils. Although pores in all maceral types were observed on ion-milled surfaces of all samples, the pores (largely nanopores with some micropores) vary as a function of maceral type. Importantly, pores in the macerals do not vary systematically as a function of thermal maturity, insofar as organic pores are of similar size and shape in both the immature and mature Kimmeridge rocks. If any organic pores developed during the generation of hydrocarbons, they were apparently not preserved, possibly because of the highly ductile nature of much of the rock constituents of Kimmeridge mudstones (clays and organic material). Inorganic pores (largely micropores with some nanopores) have been observed in all Kimmeridge mudstones. These pores, particularly interparticle (i.e., between clay platelets), and intraparticle (i.e., in framboidal pyrite, in partially dissolved detrital K-feldspar, and in both detrital and authigenic dolomite) are noteworthy because they compose much of the observable porosity in the shales in both

Uranium and diagenesis in evaporitic lacustrine mudstone of the Oligocene White River Group, Dawes County, Nebraska. Bulletin

International Nuclear Information System (INIS)

Dickinson, K.A.

1991-01-01

The Oligocene White River Group consists of the Chadron and the overlying Brule Formations in northwestern Nebraska. The Chadron Formation consists of alluvial and colluvial vitric mudstone beds, but in addition contains white persistent layers (purplish-white layers) that probably resulted from soil formation on vitric parent material. West of the current study area a basal sandstone facies of the Chadron is host rock for the Crow Butte uranium deposit. The Brule, which consists mostly of pedogenically altered alluvial and fluvial vitric mudstone deposits, contains a uraniferous lacustrine facies northwest of Chadron, Nebraska. Detrital minerals in rocks of the White River Group include quartz, feldspar, volcanic glass, smectite, and illite. Chemical precipitate minerals in the lacustrine facies are calcite, dolomite, and gypsum. Authigenic minerals include calcite, dolomite, gypsum, smectite, opal, chalcedony, together with oxidized uranium minerals

Properties of cement based composites modified using diatomaceous earth

Science.gov (United States)

Pokorný, Jaroslav; Pavlíková, Milena; Záleská, Martina; Pavlík, Zbyšek

2017-07-01

Diatomite belongs among natural materials rich on amorphous silica (a-SiO2). When finely milled, it can potentially substitute part of cement binder and positively support formation of more dense composite structure. In this connection, two types of diatomaceous earth applied as a partial substitution of 5, 10, 15, and 20 mass% of Portland cement in the composition of cement paste were studied. In the tested mixtures with cement blends, the amount of batch water remained same, with water/binder ratio 0.5. For fresh paste mixtures, initial and final setting times were measured. First, hardened pastes cured 28 days in water were characterized by their physical properties such as bulk density, matrix density and open porosity. Then, their mechanical and thermophysical parameters were assessed. Obtained results gave clear evidence of setting time shortening for pastes with diatomite what brought negative effect with respect to the impaired workability of fresh mixtures. On the other hand, there was observed strength improvement for mixtures containing diatomite with higher amount of SiO2. Here, the increase in mechanical resistivity was distinct up to 15 mass% of cement replacement. Higher cement substitution by diatomite resulted in an increase in porosity and thus improvement of thermal insulation properties.

JOINTS AND SYN-SEDIMENTARY FAULTS NETWORKS IN MARINE CLAYS AND MUDSTONES. Importance for Radwaste storage

Science.gov (United States)

Arnould, M.

2009-12-01

There is a number of marine clays, mudstones, marls, 100 to 200 m thick, showing smectites, mixed layers illite/smectite, with a small percentage of organic matter and sulphides with a variable clay, silt, and carbonate content. I published (Arnould , 2006) examples from Lower Cambrian to Miocene in age and from the Baltic shore to Spain in Europe. Observations were made mostly in quarries and pits down to more than 40 m and in underground research laboratories (URL). Only visible on fresh cuts amongst a variety of fissures there is always a network of joints. Schematically one family is the bedding (horizontal) the two others are normal to the bedding and orthogonal between them. The orientations of vertical joints are different from the orientations of pits and quarries’s walls. The networks are intrinsic. It was first well described by Skempton & al (1969) in Eocene London Clay. Joints are matt in texture, clean, without filling or cement. The order of magnitude of their linear dimensions is decimeter to meter. It is necessary to start from the original sediment: mud. Deposited in flakes mud has a bee’s nest microscopic structure. Each nest is full of water. Hence mud may have a water content up to 300%, reported to its dry weight. Paradoxically mud is impervious. As proposed by Cosgrove (2001) progressive but discontinuous hydraulic fracturing could be the origin of vertical joints, with drainage upwards and compaction of the sediment. Geological observations show that ioints are formed during the sedimentation process. There is also a world literature concluding at the necessary early fracturing of mudstones and marls hosts of sand dykes. Very few faults are identified in field observations and on exploration logs. But it is obvious that drainage and compaction of mud over thousands square kilometers induced differential settlements with many syn-sedimentary non tectonic faults constituting another discontinuity network. These faults inside the same

Ultra-Sensitive Lab-on-a-Chip Detection of Sudan I in Food using Plasmonics-Enhanced Diatomaceous Thin Film.

Science.gov (United States)

Kong, Xianming; Squire, Kenny; Chong, Xinyuan; Wang, Alan X

2017-09-01

Sudan I is a carcinogenic compound containing an azo group that has been illegally utilized as an adulterant in food products to impart a bright red color to foods. In this paper, we develop a facile lab-on-a-chip device for instant, ultra-sensitive detection of Sudan I from real food samples using plasmonics-enhanced diatomaceous thin film, which can simultaneously perform on-chip separation using thin layer chromatography (TLC) and highly specific sensing using surface-enhanced Raman scattering (SERS) spectroscopy. Diatomite is a kind of nature-created photonic crystal biosilica with periodic pores and was used both as the stationary phase of the TLC plate and photonic crystals to enhance the SERS sensitivity. The on-chip chromatography capability of the TLC plate was verified by isolating Sudan I in a mixture solution containing Rhodamine 6G, while SERS sensing was achieved by spraying gold colloidal nanoparticles into the sensing spot. Such plasmonics-enhanced diatomaceous film can effectively detect Sudan I with more than 10 times improvement of the Raman signal intensity than commercial silica gel TLC plates. We applied this lab-on-a-chip device for real food samples and successfully detected Sudan I in chili sauce and chili oil down to 1 ppm, or 0.5 ng/spot. This on-chip TLC-SERS biosensor based on diatomite biosilica can function as a cost-effective, ultra-sensitive, and reliable technology for screening Sudan I and many other illicit ingredients to enhance food safety.

Application of Unmanned Aerial System-based Photogrammetry to Monitor Landforms Evolution of Mudstone Badlands

Science.gov (United States)

Chen, Yichin

2017-04-01

Mudstone badlands are the area characteristized by its rapid erosion and steep, fractured, and barren landforms. Monitoring the topography changes in badland help improve our knowledge of the hillslope and river processing on landforms and develop susceptibility model for surface erosion hazards. Recently, advances in unmanned aerial system (UAS) and close-range photogrammetry technology have opened up the possibility of effectively measuring topography changes with high spatiotemporal resolutions. In this study, we used the UAS and close-range photogrammetry technology to monitor the topography changes in a rapidly eroded badland, south-western Taiwan. A small mudstone hillslope with area of 0.2 ha approximately and with slope gradient of 37 degrees was selected as the study site. A widely used and commercial quadcopter equipped non-metric camera was used to take images with ground sampling distance (GSD) 5 mm approximately. The Pix4DMapper, a commercial close-range photogrammetry software, was used to perform stereo matching, extract point clouds, generate digital surface models (DSMs) and orthoimage. To control model accuracy, a set of ground control points was surveyed by using eGPS. The monitoring was carried out after every significant rainfall event that may induced observable erosion in the badland site. The results show that DSMs have the GSDs of 4.0 5.4 mm and vertical accuracy of 61 116 mm. The accuracy largely depends on the quality of ground control points. The spatial averaged erosion rate during six months of monitoring was 328 mm, which is higher in the gully sides than in the ridges. The erosion rate is positively correlated with the slope gradient and drainage contributing area that implies the important role of surface gully erosion in mudstone badland erosion. This study shows that UAS and close-range photogrammetry technology can be used to monitor the topography change in badland areas effectively and can provide high spatiotemporal

Effectiveness of an improved form of insecticide-based diatomaceous earth against four stored grain pests on different grain commodities.

Science.gov (United States)

Saeed, Nadia; Farooq, Muhammad; Shakeel, Muhammad; Ashraf, Misbah

2018-04-07

The effectiveness of Grain-Guard, an improved form of diatomaceous earth (DE), with low risk to the environment, was evaluated against the storage pests Liposcelis paeta, Cryptolestes ferrugineus, Rhyzopertha dominica, and Tribolium castaneum on four grain commodities, wheat, rice, maize and sorghum. The overall mortality of stored grain pests increased with the rise of application rate and exposure intervals of diatomaceous earth and decreased over 120 days of post-treatment period. Our results revealed that mortality of adults 14 days post-disclosure was > 80% on wheat at the start of post-treatment than rice, maize, and sorghum, respectively. During the first 60 days of post-treatment, adult mortality increased, whereas later on, a steady decrease in adult mortality was observed. Considerable differences in dose rates were observed on mortality levels along with grain commodities. Following 14 days of exposure, all adults of four species were dead on wheat at 100 ppm and on rice at 150 ppm except maize and sorghum. The suppression of progeny was noticeably higher at the beginning of post-treatment duration while after 60-days of post-treatment, progeny numbers started to increase with the rise in post-treatment durations. This new improved DE formulation was found to be effective at dose rates that are extensively lower than required with previous DE formulations and will contribute to lower the risk of health and environment.

Origin of Chlorobenzene Detected by the Curiosity Rover in Yellowknife Bay: Evidence for Martian Organics in the Sheepbed Mudstone

Science.gov (United States)

Glavin, D.; Freissnet, C.; Eigenbrode, J.; Miller, K.; Martin, M.; Summons, R. E.; Steele, A.; Archer, D.; Brunner, A.; Buch, A.;

Chemical characterization of vermicompost of sewage sludge with different proportions of diatomaceous material

Directory of Open Access Journals (Sweden)

Fabíola M. Braga

Full Text Available ABSTRACT The pursuit for waste recovery has been the best way to contribute to environmental sustainability. The mix of sewage sludge (SS from Sewage Treatment Plant with diatomaceous material containing oil (DE, used as a filter in biofuel production, can form a substrate rich in minerals and organic matter through vermicomposting. Therefore, this study aimed to produce vermicompost using worms, Eisenia foetida, from a pre-compost (PC of sewage sludge and garden pruning residues mixed with different proportions of DE in relation to PC: 0; 7.53; 15.06; 22.59; and 30.12% v/v. The design was randomized complete blocks with five treatment replicates. The chemical characteristics of the vermicompost were analyzed after a period of four months. The proportion of up to 30.12% v/v of DE met the criteria established for agriculture uses, registration and marketing of the product as organic compost in accordance with the Normative Instructions SDA 27/2006 and 25/2009 from the Ministry of Agriculture.

Dawsonite and other carbonate veins in the Cretaceous Izumi Group, SW Japan: a natural support for fracture self-sealing in mud-stone cap-rock in CGS?

Energy Technology Data Exchange (ETDEWEB)

Okuyama, Yasuko; Funatsu, Takahiro; Fujii, Takashi [Institute for Geo-Resources and environment, GSJ, AISI, 1-1-1 Higashi, Central 7, Tsukuba, ibaraki 305-8567 (Japan); Take, Shuji [Kishiwada Nature Club, c/o Kishiwada City Natural History Museum, Sakai-Machi 5-6, Kishiwada, Osaka 596-0072 (Japan)

2013-07-01

Dawsonite-bearing carbonate veins are abundant in a compact mud-stone layer of the lower part of the Izumi Group, SW Japan. The mode of occurrence of the veins probably indicates fracturing and mineral sealing associated with upwelling of CO{sub 2}-rich fluid evolved in the reservoir beneath. The carbonate veins studied here can be a natural support to fracturing and healing of mud-stone cap-rock in the CO{sub 2} geological storage. (authors)

Elaboration of building materials from industrial waste from solid granular diatomaceous earth; Elaboracion de material de construccion a partir de residuos industriales solidos granulares procedentes de tierras diatomaceas

Energy Technology Data Exchange (ETDEWEB)

Del Angel S, A.

2015-07-01

In this work the initial characterization of granular solid industrial waste from diatomaceous earth was carried out using techniques of Scanning Electron Microscopy and X-ray Diffraction. In a second stage leaching of the material was undertaken to the US Patent Number 5, 376,000 and 5, 356,601 obtaining the samples M1-S ph 2, M1-L ph, M1-S ph 10 and M1-L ph 10. In the third stage a new characterization of the samples obtained with the techniques of Scanning Electron Microscopy, X-ray Diffraction and Atomic Absorption Spectrometry was performed, the latter in order to determine the efficiency percentage of the leaching process. In the fourth stage the specimens for performing mechanical, physical and chemical tests were manufactured, using molds as PVC pipes of 1 inch in diameter and 2 inches in length, with a composition of 50% of diatomaceous earth and 50% of cement produced in each. Finally, in the fifth stage mechanical testing (compression resistance), physical (moisture absorption rate) and chemical (composition and structure of the material) are performed. In the last stage, when conducting mechanical testing with the test specimens, the presence of bubbles enclosed in each obtaining erroneous results noted, so it was necessary to develop the specimens again, obtaining in this occasion concentrations of 20:80, 40:60, 60:40 and 80:20 of diatomaceous earth with the cement. These results were analyzed to determine if the used material is suitable for the production of building materials such as bricks or partitions, being demonstrated by the tests carried out if they are eligible. (Author)

Martian Chlorobenzene Identified by Curiosity in Yellowknife Bay: Evidence for the Preservation of Organics in a Mudstone on Mars

Science.gov (United States)

Glavin, Daniel P.; Freissinet, Caroline; Mahaffy, P.; Miller, K.; Eigenbrode, J.; Summons, R.; Martin, M.; Franz, H.; Steele, A.; Archer, D.;

The origin of native selenium microparticles during the oxidation of sideritic mudstones in the Veřovice Formation (Outer Western Carpathians

Directory of Open Access Journals (Sweden)

Matýsek Dalibor

2015-08-01

Full Text Available Microparticles of native selenium were detected in weathered sideritic mudstones of the Veřovice Formation (Aptian of the Silesian Unit (Outer Western Carpatians, NE part of the Czech Republic. This mineral forms small needle-like crystals with lengths of up to 20 μm, and is confined to fissures in sideritic mudstones covered by goethite or rarely also by hydrated Mn-oxide minerals. The oxidized sideritic mudstones show zonal structure and resemble the initial stage of the formation of the so-called rattle stones. From the superposition of phase diagrams of selenium and Fe-oxyhydroxides, Fe apparently occupies a large field in which Se(0 and FeOOH and/or Fe(OH3 can co-exist. The reduction of selenites or selenates by pyrite or by any other phase, capable of charge transfer, is likely to have been responsible for the formation of microparticles of native selenium. The crucial factor controlling the origin of these particles is the extremely low solubility of Se(0. The source of Se is not obvious. It can be released in trace concentrations during the weathering of pyrite. Sediments of the Veřovice Formation correspond to the anoxic event OAE1b and accumulation of siderophile elements in similar sediments is very probable. A probable mechanism for the origin of Se microcrystals is gradual crystallization from solution.

Effect of the diatomaceous earth in the soil chemical properties in corn crops (Zea mays L.

Directory of Open Access Journals (Sweden)

Lucia Fabila Martínez

2013-10-01

Full Text Available This study was developed out of the need to provide products and services intended for the field that meet the nutritional needs of plants without implicating environmental damage by means of chemical fertilizers and insecticides. The study assessed the fertilizer effect of two diatomaceous earth and a liquid fertilizer to corroborate empirical evidence of several producers who used a commercial product based on the study`s materials and achieved higher levels of performance in different crops. A sample of the experimental area was carried out before establishing the crop after its completion. Two commercial diatomaceous earth identified as 289 and 400 P produced by International Celite, were assessed at two concentrations 20 kg ha-1 and 40 kg ha-1 and 18 kg ha-1 and 36 kg ha-1 res­pectively, and a organic liquid fertilizer (FOL at doses of 2 L ha-1 and 4 L ha-1 was considered as control soil sample taken before the application of treatments. The experimental design used in the field for the application of the treatments was randomized complete block (DBA with 5 repetitions. The test plant was the corn hybrid HC8. The variables evaluated in the soil throudgh laboratory analysis were: physical properties of texture and bulk density (BD, and chemical pH, organic carbon (OC, organic matter (OM, electrical conductivity (EC, cation exchange capacity (CIC, nitrogen (N, phosphorus (P, potassium (K, calcium (Ca, magnesium (Mg and sodium (Na. The results were analyzed under a ANOVA and Tukey test for comparison of means for treatment, using the JMP statistical package. Laboratory results indicated that the­re were changes in the chemical characteristics of the soil between the control and treatments in the majority of the chemical characteristics analyzed (pH, CO, MO, N, P, K, Ca, Mg and Na. However statistically and under a statistical significance of 5%, differences were only observed in the properties of CO, MO, CE, N, K and Na.  

Analysis of the saturated hydrocarbon in coal, carbonaceous mudstone and oils from the lower Jurassic coal measures in the Turpan Basin by GC/MS

International Nuclear Information System (INIS)

Fang Xuan; Meng Qianxiang; Sun Minzhuo; Du Li; Ding Wanren

2005-01-01

Saturated hydrocarbon of coal, carbonaceous mudstone and oils from the Lower Jurassic coal measures in the Turpan basin were studied, and biomarker characteristics and coal thermal maturity analyzed to draw the following conclusions. T here are many similar biomarker characteristics between oil from middle-lower Jurassic of Turpan Basin and coal and carbonaceous mudstone in the same strata. They all contain specific r-lupane, I-norbietane, C 24 -tetracyclic and high content of C 29 -steranes. These characteristics suggest that they have similar matter source of the organic matter derived from matter with abundant high plants. Meanwhile, biomarkers often used to indicate depositional environments characterized by high Pr/Ph ratio, little or no gammacerane and high abundance dibenzofurans, such biomarker distributions are indicative of suboxic and freshwater environment. Although coal and carbonaceous mudstone remain in lower thermal maturity (Ro=0.47-0.53), but C 29 -ββ/(αα+ββ) sterane ratio (0.294-0.489) and bezohopane are detected. Because these ferture are related to bacterial activity, bacterial degradation of organic matter maybe take an important role in coal-derived oil. (authors)

Origin of Chlorobenzene Detected by the Curiosity Rover in Yellowknife Bay: Evidence for Martian Organics in the Sheepbed Mudstone?

Science.gov (United States)

Glavin, Daniel P.; Freissinet, Caroline; Eigenbrode, J.; Miller, K.; Martin, M.; Summons, R.; Steele, A.; Franz, H.; Archer, D.; Brinkerhoff, W.;

The results of the investigations on rock mechanics in HDB-9-11 boreholes and update of the rock mechanical model around the Horonobe URL construction area

International Nuclear Information System (INIS)

Sanada, Hiroyuki; Niunoya, Sumio; Matsui, Hiroya

2008-09-01

Horonobe URL (Underground Research Laboratory) Project is conducted at Horonobe-cho, Teshio-gun, Hokkaido. This research report shows the result of the rock mechanical investigations which have been carried out from 2004 to 2005 as a part of the project. The objectives of the rock mechanical investigation are as follows: To obtain the data which were necessary for construction design of URL. To confirm the distribution of rock mechanical properties in and around URL construction area. The results of the investigations are summarized as follows: 1) Variation and values of depth direction of physical and mechanical properties in the laboratory construction area corresponded approximately to the results obtained from the rock mechanical investigations of HDB-1-8. 2) The major redesign had been not had about physical and mechanical properties in the laboratory construction area being able to divide into three zones and length of its own zone in updating rock mechanical model. 3) From the results of initial stress measured by hydraulic fracturing, the results that the direction of the maximum principle stress is E-W was no different from results obtained from the investigations of HDB-1-8, but the magnitude correlation among maximum, minimum principle stress and overburden pressure measured around G.L.-927 m showed different trends compared with the results of HDB-1-8. 4) Diatomaceous mudstone was yielded under isotropic compression. Cam-clay model as constitutive law of diatomaceous mudstone should be used for tunnel excavation analysis. 5) Uniaxial compression strength of rock saturated under saline water is larger than that of saturated under freshwater. Poisson's ratio of rock saturated under saline water is smaller than that of saturated under saline water. 6) The effective confining pressure increases with the equivalent opening width and permeability decreases. 7) The value of principle stress obtained from DSCA method is larger than that obtained from hydraulic

Variations in petrophysical properties of shales along a stratigraphic section in the Whitby mudstone (UK)

Science.gov (United States)

Barnhoorn, Auke; Houben, Maartje; Lie-A-Fat, Joella; Ravestein, Thomas; Drury, Martyn

2015-04-01

In unconventional tough gas reservoirs (e.g. tight sandstones or shales) the presence of fractures, either naturally formed or hydraulically induced, is almost always a prerequisite for hydrocarbon productivity to be economically viable. One of the formations classified so far as a potential interesting formation for shale gas exploration in the Netherlands is the Lower Jurassic Posidonia Shale Formation (PSF). However data of the Posidonia Shale Formation is scarce so far and samples are hard to come by, especially on the variability and heterogeneity of the petrophysical parameters of this shale little is known. Therefore research and sample collection is conducted on a time and depositional analogue of the PSF: the Whitby Mudstone Formation (WMF) in the United Kingdom. A large number of samples along a ~7m stratigraphic section of the Whitby Mudstone Formation have been collected and analysed. Standard petrophysical properties such as porosity and matrix densities are quantified for a number of samples throughout the section, as well as mineral composition analysis based on XRD/XRF and SEM analyses. Seismic velocity measurements are also conducted at multiple heights in the section and in multiple directions to elaborate on anisotropy of the material. Attenuation anisotropy is incorporated as well as Thomsen's parameters combined with elastic parameters, e.g. Young's modulus and Poisson's ratio, to quantify the elastic anisotropy. Furthermore rock mechanical experiments are conducted to determine the elastic constants, rock strength, fracture characteristics, brittleness index, fraccability and rock mechanical anisotropy across the stratigraphic section of the Whitby mudstone formation. Results show that the WMF is highly anisotropic and it exhibits an anisotropy on the large limit of anisotropy reported for US gas shales. The high anisotropy of the Whitby shales has an even larger control on the formation of the fracture network. Furthermore, most petrophysical

The Impact of Climate Change in Rainfall Erosivity Index on Humid Mudstone Area

Science.gov (United States)

Yang, Ci-Jian; Lin, Jiun-Chuan

2017-04-01

It has been quite often pointed out in many relevant studies that climate change may result in negative impacts on soil erosion. Then, humid mudstone area is highly susceptible to climate change. Taiwan has extreme erosion in badland area, with annual precipitation over 2000 mm/y which is a considerably 3 times higher than other badland areas around the world, and with around 9-13 cm/y in denudation rate. This is the reason why the Erren River, a badland dominated basin has the highest mean sediment yield in the world, over 105 t km2 y. This study aims to know how the climate change would affect soil erosion from the source in the Erren River catchment. Firstly, the data of hourly precipitation from 1992 to 2016 are used to establish the regression between rainfall erosivity index (R, one of component for USLE) and precipitation. Secondly, using the 10 climate change models (provide form IPCC AR5) simulates the changes of monthly precipitation in different scenario from 2017 to 2216, and then over 200 years prediction R values can be use to describe the tendency of soil erosion in the future. The results show that (1) the relationship between rainfall erosion index and precipitation has high correction (>0.85) during 1992-2016. (2) From 2017 to 2216, 7 scenarios show that annual rainfall erosion index will increase over 2-18%. In contrast, the others will decrease over 7-14%. Overall, the variations of annual rainfall erosion index fall in the range of -14 to 18%, but it is important to pay attention to the variation of annual rainfall erosion index in extreme years. These fall in the range of -34 to 239%. This explains the extremity of soil erosion will occur easily in the future. Keywords: Climate Change, Mudstone, Rainfall Erosivity Index, IPCC AR5

Age and speciation of iodine in groundwater and mudstones of the Horonobe area, Hokkaido, Japan: Implications for the origin and migration of iodine during basin evolution

Science.gov (United States)

Togo, Yoko S.; Takahashi, Yoshio; Amano, Yuki; Matsuzaki, Hiroyuki; Suzuki, Yohey; Terada, Yasuko; Muramatsu, Yasuyuki; Ito, Kazumasa; Iwatsuki, Teruki

2016-10-01

This paper reports the concentration, speciation and isotope ratio (129I/127I) of iodine from both groundwater and host rocks in the Horonobe area, northern Hokkaido, Japan, to clarify the origin and migration of iodine in sedimentary rocks. Cretaceous to Quaternary sedimentary rocks deposited nearly horizontally in Tenpoku Basin and in the Horonobe area were uplifted above sea level during active tectonics to form folds and faults in the Quaternary. Samples were collected from the Pliocene Koetoi and late Miocene Wakkanai formations (Fms), which include diatomaceous and siliceous mudstones. The iodine concentration in groundwater, up to 270 μmol/L, is significantly higher than that of seawater, with the iodine enrichment factor relative to seawater reaching 800-1500. The iodine concentration in the rocks decreases from the Koetoi to Wakkanai Fms, suggesting that iodine was released into the water from the rocks of deeper formations. The iodine concentration in the rocks is sufficiently high for forming iodine-rich groundwater as found in this area. X-ray absorption near edge structure (XANES) analysis shows that iodine exists as organic iodine and iodide (I-) in host rocks, whereas it exists mainly as I- in groundwater. The isotope ratio is nearly constant for iodine in the groundwater, at [0.11-0.23] × 10-12, and it is higher for iodine in rocks, at [0.29-1.1] × 10-12, giving iodine ages of 42-60 Ma and 7-38 Ma, respectively. Some iodine in groundwater must have originated from Paleogene and even late Cretaceous Fms, which are also considered as possible sources of oil and gas, in view of the old iodine ages of the groundwater. The iodine ages of the rocks are older than the depositional ages, implying that the rocks adsorbed some iodine from groundwater, which was sourced from greater depths. The iodine concentration in groundwater decreases with decreasing chlorine concentration due to mixing of iodine-rich connate water and meteoric water. A likely scenario

Diagenetic evolution and chemical changes of deep-water mudstones of Shahejie Formation in the Dongying Sag, Jiyang Depression, Eastern China

DEFF Research Database (Denmark)

Yang, Tian; Cao, Yingchang; Friis, Henrik

2018-01-01

), which were formed in a lacustrine basin during 43.7-38.2 Ma. Optical microscopy and XRD analysis show that the mudstones are dominated by clay minerals (56.8%) followed by carbonate (18.2 %), quartz (14.9 %), feldspar (8.4 %), pyrite (0.9 %), anhydrite (0.8 %), and total organic carbon (TOC: 2...

The connectivity of pore space in mudstones: insights from high-pressure Wood's metal injection, BIB-SEM imaging, and mercury intrusion porosimetry

NARCIS (Netherlands)

Klaver, J.; Hemes, S.; Houben, M.; Desbois, G.; Radi, Z.; Urai, J.L.

2015-01-01

Study of the pore space in mudstones by mercury intrusion porosimetry is a common but indirect technique and it is not clear which part of the pore space is actually filled with mercury. We studied samples from the Opalinus Clay, Boom Clay, Haynesville Shale, and Bossier Shale Formations using

Increase the Visibility of Microbial Growth in a Winogradsky Column by Substituting Diatomaceous Earth for Sediment

Directory of Open Access Journals (Sweden)

Thomas G. Benoit

2015-02-01

Full Text Available The difficulty students have seeing the color associated with microbial growth in a traditional Winogradsky column can be overcome by substituting diatomaceous earth (DE for sediment. Microbial growth in a DE column is visible from the early stages of ecological succession and the colors produced appear more vibrant. A flat-sided tissue culture flask can be used as a column container to provide a large surface area for observation. The enhanced visual experience provided by a DE column increases student engagement and learning. Editor's Note:The ASM advocates that students must successfully demonstrate the ability to explain and practice safe laboratory techniques. For more information, read the laboratory safety section of the ASM Curriculum Recommendations: Introductory Course in Microbiology and the Guidelines for Biosafety in Teaching Laboratories, available at www.asm.org. The Editors of JMBE recommend that adopters of the protocols included in this article follow a minimum of Biosafety Level 1 practices.

Virus removal in ceramic depth filters based on diatomaceous earth.

Science.gov (United States)

Michen, Benjamin; Meder, Fabian; Rust, Annette; Fritsch, Johannes; Aneziris, Christos; Graule, Thomas

2012-01-17

Ceramic filter candles, based on the natural material diatomaceous earth, are widely used to purify water at the point-of-use. Although such depth filters are known to improve drinking water quality by removing human pathogenic protozoa and bacteria, their removal regarding viruses has rarely been investigated. These filters have relatively large pore diameters compared to the physical dimension of viruses. However, viruses may be retained by adsorption mechanisms due to intermolecular and surface forces. Here, we use three types of bacteriophages to investigate their removal during filtration and batch experiments conducted at different pH values and ionic strengths. Theoretical models based on DLVO-theory are applied in order to verify experimental results and assess surface forces involved in the adsorptive process. This was done by calculation of interaction energies between the filter surface and the viruses. For two small spherically shaped viruses (MS2 and PhiX174), these filters showed no significant removal. In the case of phage PhiX174, where attractive interactions were expected, due to electrostatic attraction of oppositely charged surfaces, only little adsorption was reported in the presence of divalent ions. Thus, we postulate the existence of an additional repulsive force between PhiX174 and the filter surface. It is hypothesized that such an additional energy barrier originates from either the phage's specific knobs that protrude from the viral capsid, enabling steric interactions, or hydration forces between the two hydrophilic interfaces of virus and filter. However, a larger-sized, tailed bacteriophage of the family Siphoviridae was removed by log 2 to 3, which is explained by postulating hydrophobic interactions.

Factors affecting Diatomaceous Earth effectiveness in the control of Alphitobius diaperinus (Panzer) (Coleoptera: Tenebrionidae) adults

International Nuclear Information System (INIS)

Alves, Luis F.A.; Oliveira, Daian G.P.; Neves, Pedro M.O.J

2008-01-01

Diatomaceous earth (DE) is a potential alternative to control the lesser mealworm of poultry farms Alphitobius diaperinus (Panzer). Our study aimed to understand the role of some of the environmental and insect behavioral factors play on DE effectiveness, such as the substrate (chicken food and poultry house litter), temperature and DE repellent activity on lesser mealworm adults. Mortality was higher at the highest temperature (32 deg C), and it increased with DE concentration (53 and 84% respectively, for concentrations of 86 and 172 g/m2) (P < 0.05). The substrate also influenced DE effectiveness: 95% mortality was observed in the feed, against 4% in the poultry litter. Part of these results can be attributed to the removal of DE particles by the poultry bedding, as supported by scanning electron microscopy (SEM) observations and rhodamine concentration on the surface of the insects. As to insect behavior, DE had a repellent effect, since trap capture decreased nearly 50% in traps containing DE as opposed to those containing only food. Therefore, environmental factors do affect the DE effectiveness, and they must be taken into consideration when looking into developing control strategies in the field. (author)

Scenario development of long-term evolution for deep hydrochemical conditions in Horonobe area, Hokkaido, Japan

International Nuclear Information System (INIS)

Iwatsuki, Teruki; Ishii, Eiichi; Niizato, Tadafumi

2009-01-01

A methodology to estimate long-term hydrochemical evolution of deep underground is indispensable for the safe geological isolation of high-level radioactive waste (HLW). This study demonstrates the methodology by illustrating scenarios of past geological events, processes, and their interrelationships with present-day hydrochemical conditions. Besides, we infer long-term variations of groundwater chemistry at Horonobe, Hokkaido, Japan. The region is underlain mainly by Neogene to Quaternary marine sedimentary rocks, (the Wakkanai Formation (Fm) and the overlying Koetoi Fm: siliceous and diatomaceous mudstones). During various events in the geological past, such as deposition, compaction, uplift, and denudation, and the more recent Neotectonic activities in this area, highly permeable hydrogeological structures formed at depths not over than 400 m below ground level in the Wakkanai Fm. The hydrogeological system can be subdivided into three hydrogeological sub-systems: (1) overlying, relatively low permeability Koetoi Fm., (2) highly permeable, upper Wakkanai Fm at depths less than 400 m and (3) relatively low permeability Wakkanai Fm, at depths greater than 400 m. The present-day hydrochemical conditions in each sub-system have been influenced by hydrogeological properties and hydraulic conditions over a long period. In subsystems 1 and 2, recharging with meteoric water flushed connate seawater during uplifting and denudation during the last 1 Ma. In contrast, fossil seawater with one-third to one-half the salinity of present-day seawater has been preserved in subsystem 3. The relatively low permeability sequence in sub-system 3 was formed by the compaction of diatomaceous mudstone during subsidence prior to 1.0 Ma. After that, changes of climatic conditions and geographical features would not have influenced groundwater flow. The groundwater chemistry evolved from seawater during long-term geochemical diagenesis in a relatively closed system. The long

The Paleo-environmental significance of the iron-formations and iron-rich mudstones of the Mesoarchean Witwatersrand-Mozaan Basin, South Africa

OpenAIRE

2009-01-01

M.Sc. The Mesoarchean Witwatersrand and Pongola Supergroups of South Africa are the oldest, well preserved supracratonic successions worldwide. Various banded iron formation (BIF) and iron-rich mudstone units occur within the West Rand Group of the Witwatersrand Supergroup and the Mozaan Group of the Pongola Supergroup. A granular iron formation (GIF) occurs in a single unit in the Nconga Formation of the Mozaan Group. The Witwatersrand Supergroup and Mozaan Group have been lithostratigrap...

Distribution of discontinuous mudstone beds within wave-dominated shallow-marine deposits: Star Point Sandstone and Blackhawk Formation, Eastern Utah, USA

OpenAIRE

Eide, Christian; Buckley, Simon; Howell, John

2017-01-01

Deposits of wave-dominated shorelines are typically considered to act as relatively simple hydrocarbon reservoirs and are commonly modeled as “tanks of sand”. However, important heterogeneities that can act as barriers to fluid flow occur at the parasequence, bedset and bed scales, especially in viscous oil or low permeability oil fields. Heterogeneities at the parasequence and bedset scale have been well-studied, but discontinuous mudstone-beds occurring within the shoreface have received li...

欠压实泥岩顶底板形成机理及其对油气运移的影响%Formation Mechanism of the Undercompacting Mudstone's Roof and Floor and Their Influence on Hydrocarbon Migration

Institute of Scientific and Technical Information of China (English)

冯冲; 邹华耀; 汪斌

2012-01-01

欠压实泥岩顶底板是指比中部欠压实泥岩较致密的泥岩表层,是趋于正常压实的泥岩层,发育于低渗透率的厚层泥岩的上、下部位.以低速渗流定律为理论基础,从微观机理上分析欠压实泥岩顶底板的形成过程,提出穿过欠压实泥岩顶底板流体运移阻力的计算公式.当含顶底板泥岩作为盖层时,分为连续沉积型、抬升型和压裂型3种.压裂型泥岩盖层的封闭能力等于底板排替压力与达到顶板破裂的剩余压力之和,其他两种盖层的封闭能力就等于盖层顶底板的排替压力之和.当含顶底板泥岩作为源岩时,在连续型源岩中,油气排放的方向主要取决于泥岩顶底板渗透性地层的发育程度；在压裂型源岩中,大量油气沿裂缝向上排烃.此外,源岩的排烃方向还受断层的控制.通过欠压实泥岩顶底板形成机理的研究,有助于评价泥岩盖层的封烃能力,了解泥质烃源岩油气初次运移的方向.%Undercompacting mudstone's roof and floor (UMRF) are the mudstone surface layers that are tighter than the central undercompaction, and are close to the normal compacting mudstone. UMRF develops in upper and lower parts of thick-layered mudstone with low permeability. This paper, by the Laws of Low-speed Flow, analyzed formation process of the UMRF from the microscopic mechanism, and proposed the resistance force formula of the fluid passing UMRF. The mudstone with the UMRF as a cap rock, can be divided into three types; the continuous sedimentary type, the uplift type and the fracture type. The sealing ability of the fracture type mudstone cap rock is equal to the floor's displacement pressure plus the roofs overpressure when it breaks down. The other two types of mudstone cap rocks' sealing abilities are equal to the floor's displacement pressure plus the roofs displacement pressure. When the mudstone with the UMRF as a source rock, in the continuous type, the expulsion direction

Possible effects of two-phase flow pattern on the mechanical behavior of mudstones

Science.gov (United States)

Goto, H.; Tokunaga, T.; Aichi, M.

2016-12-01

To investigate the influence of two-phase flow pattern on the mechanical behavior of mudstones, laboratory experiments were conducted. In the experiment, air was injected from the bottom of the water-saturated Quaternary Umegase mudstone sample under hydrostatic external stress condition. Both axial and circumferential strains at half the height of the sample and volumetric discharge of water at the outlet were monitored during the experiment. Numerical simulation of the experiment was tried by using a simulator which can solve coupled two-phase flow and poroelastic deformation assuming the extended-Darcian flow with relative permeability and capillary pressure as functions of the wetting-phase fluid saturation. In the numerical simulation, the volumetric discharge of water was reproduced well while both strains were not. Three dimensionless numbers, i.e., the viscosity ratio, the Capillary number, and the Bond number, which characterize the two-phase flow pattern (Lenormand et al., 1988; Ewing and Berkowitz, 1998) were calculated to be 2×10-2, 2×10-11, and 7×10-11, respectively, in the experiment. Because the Bond number was quite small, it was possible to apply Lenormand et al. (1988)'s diagram to evaluate the flow regime, and the flow regime was considered to be capillary fingering. While, in the numerical simulation, air moved uniformly upward with quite low non-wetting phase saturation conditions because the fluid flow obeyed the two-phase Darcy's law. These different displacement patterns developed in the experiment and assumed in the numerical simulation were considered to be the reason why the deformation behavior observed in the experiment could not be reproduced by numerical simulation, suggesting that the two-phase flow pattern could affect the changes of internal fluid pressure patterns during displacement processes. For further studies, quantitative analysis of the experimental results by using a numerical simulator which can solve the coupled

Influence of various amount of diatomaceous earth used as cement substitute on mechanical properties of cement paste

Science.gov (United States)

Pokorný, Jaroslav; Pavlíková, Milena; Medved, Igor; Pavlík, Zbyšek; Zahálková, Jana; Rovnaníková, Pavla; Černý, Robert

2016-06-01

Active silica containing materials in the sub-micrometer size range are commonly used for modification of strength parameters and durability of cement based composites. In addition, these materials also assist to accelerate cement hydration. In this paper, two types of diatomaceous earths are used as partial cement replacement in composition of cement paste mixtures. For raw binders, basic physical and chemical properties are studied. The chemical composition of tested materials is determined using classical chemical analysis combined with XRD method that allowed assessment of SiO2 amorphous phase content. For all tested mixtures, initial and final setting times are measured. Basic physical and mechanical properties are measured on hardened paste samples cured 28 days in water. Here, bulk density, matrix density, total open porosity, compressive and flexural strength, are measured. Relationship between compressive strength and total open porosity is studied using several empirical models. The obtained results give evidence of high pozzolanic activity of tested diatomite earths. Their application leads to the increase of both initial and final setting times, decrease of compressive strength, and increase of flexural strength.

Copper removal from acid mine drainage-polluted water using glutaraldehyde-polyethyleneimine modified diatomaceous earth particles

Directory of Open Access Journals (Sweden)

Mikael Larsson

2018-02-01

Full Text Available Mine waters and tailings generated from mining and mineral processing activities often have detrimental impact on the local environment. One example is acid mine drainage, in which sulphides in the mining waste react with water and oxygen to produce an acidic environment that subsequently dissolves host rock minerals from the waste containing toxic metals and trace elements. Copper is one such metal of significance, as it is mined at large volumes in sulphide containing ores. It has strong biocidal activity that greatly affects ecosystems. We have previously reported that glutaraldehyde (GA-crosslinked polyethyleneimine (PEI has strong affinity and selectivity for copper and that diatomaceous earth (DE particles can be modified with the material to form a copper-extraction resin. In this study, the copper uptake of GA-PEI-DE particles was investigated from synthetic and real acid mine drainage samples under different pHs and their copper removal performance was compared with that of selected commercial resins. The results revealed that copper could effectively and preferentially bind to the material at pH 4, and that the copper could be completely eluted by lowering of the pH. In addition, effective copper uptake and elution was demonstrated using real legacy acid mine drainage water from Mount Lyell in Tasmania.

Study on characteristics of sedimentary rock at the Horonobe site (2). Report of collaboration research between CRIEPI and JAEA

International Nuclear Information System (INIS)

Oyama, Takahiro; Kiho, Kenzo; Suzuki, Koichi; Nakata, Eiji; Tanaka, Shiro; Hasegawa, Takuma; Nakata, Kotaro; Nagaoka, Toru; Nakamura, Takamichi; Fukushima, Tatsuo; Ishii, Eiichi; Kunimaru; Takanori; Hama, Katsuhiro; Iwatsuki, Teruki; Sugita, Yutaka; Yabuuchi, Satoshi; Miyahara, Shigenori; Takahashi, Kazuharu

2010-01-01

CRIEPI (Central Research Institute of Electric Power Industry) and JAEA (Japan Atomic Energy Agency) have been conducting a collaboration research to develop methodology for the characterization of geological environment since FY 2002. This report describes the results of the collaboration research in mainly from FY 2004 to FY 2008. As the collaboration research, the following research results were obtained. (1) Study on the slaking property. We discovered the spherical silica (amorphous silica) in siliceous rock (Opalin chert) between the Koetoi and Wakkanai Formation. The permeability of this chert (10 -12 m/sec) decreases to compare with near depth diatomaceous mudstone (10 -10 m/sec). This diatomaceous mudstone dose not rapidly slakes. Excavated disturbed zone(EdZ) at -140 m tunnel was estimated with drilled cores and gas flows from the tunnel wall. (2) Study on the chemical weathering of the sedimentary rock. The weathering property was investigated of mudstone at an outcrop and east shaft. Weathering profile was divided oxidized, dissolved, transition and fresh zone. Oxidation was limited to the vicinity of surface. (3) Study on the pore water extraction methodology. Sample preparation under N 2 condition before porewater squeezing to prevent oxidation showed that the squeezed porewater chemistry was affected by the sample storage period before squeezing. (4) Study on exploration method considering the physical property of the rock. The depth profile of the mechanical and permeability properties can be estimated by the results of physical logging in the borehole and laboratory measurements of core samples. (5) Study on the applicability of the controlled drilling system to the Horonobe site. The controlled drilling system was applied to the Hokushin site and the Kami-horonobe site in the Horonobe town. At the Kami-horonobe site, the system was applied to drill the Omagari fault and characterize the hydro-geology around the fault. The controlled drilling was

Uniform surface modification of diatomaceous earth with amorphous manganese oxide and its adsorption characteristics for lead ions

Energy Technology Data Exchange (ETDEWEB)

Li, Song; Li, Duanyang; Su, Fei; Ren, Yuping; Qin, Gaowu, E-mail: lis@atm.neu.edu.cn

2014-10-30

Graphical abstract: - Highlights: • A uniform MnO{sub 2} layer was anchored onto diatomite surface. • Kinetics and isotherms over MnO{sub 2} modified diatomite were studied. • The Pb(II) adsorption is based on ion-exchange mechanism. - Abstract: A novel method to produce composite sorbent material compromising porous diatomaceous earth (DE) and surface functionalized amorphous MnO{sub 2} is reported. Via a simple in situ redox reaction over the carbonized DE powders, a uniform layer of amorphous MnO{sub 2} was anchored onto the DE surface. The hybrid adsorbent was characterized by X-ray diffraction, scanning electron microscopy, and infrared spectroscopy. The batch method has been employed to investigate the effects of surface coating on adsorption performance of DE. According to the equilibrium studies, the adsorption capacity of DE for adsorbing lead ions after MnO{sub 2} modification increased more than six times. And the adsorption of Pb{sup 2+} on the MnO{sub 2} surface is based on ion-exchange mechanism. The developed strategy presents a novel opportunity to prepare composite adsorbent materials by integrating nanocrystals with porous matrix.

The Jurassic of Denmark and Greenland: An offshore transgressive–regressive mudstone-dominated succession from the Sinemurian of Skåne, Sweden

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Surlyk, Finn

2003-10-01

Full Text Available A Sinemurian mudstone-dominated succession was exposed until recently in the Gantofta quarry in Skåne, southern Sweden. The deposits are placed in the Döshult and Pankarp Members of the Sinemurian–Aalenian Rya Formation. Similar facies of the same age are widespread in the Danish Basin where they constitute the F-Ib unit (F-I member of the Fjerritslev Formation. The Gantofta succession thus represents the easternmost extension of the environment characteristic of the Fjerritslev Formation and is essentially the only locality where it has been possible tostudy the facies of this formation in outcrop. Sedimentation seems to have taken place under relatively quiet tectonic conditions except for the possible fault-control of the basin margin. Thelower part of the Gantofta section is of Early and early Late Sinemurian age. It represents the upper part of the Döshult Member and consists of muddy, lower shoreface sandstones, abruptlyoverlain by dark, bioturbated, fossiliferous mudstones with thin storm siltstones and sandstones. They are overlain by the Upper Sinemurian Pankarp Member which comprises red-brown, restricted marine calcareous mudstones with an upwards increasing number of storm siltstones and sandstones reflecting general shallowing and shoreline progradation.The succession spans the greater part of two simple sequences with a distal sequence boundary located at the boundary between the Döshult Member and the Pankarp Member. The exposed part of the lower sequence includes a thick transgressive systems tract and a very thin highstand systems tract. The upper sequence is represented by an undifferentiated transgressive and highstand systems tract. An Early Sinemurian sea-level rise, a late Early Sinemurian highstand, an early Late Sinemurian fall and a Late Sinemurian minor rise and a major fall are recognised. Nearby boreholes show evidence for an end-Sinemurian – Early Pliensbachian major rise. This evolution corresponds well with

Long-term migration of iodine in sedimentary rocks based on iodine speciation and 129I/127I ratio

Science.gov (United States)

Togo, Y.; Takahashi, Y.; Amano, Y.; Matsuzaki, H.; Suzuki, Y.; Muramatsu, Y.; Iwatsuki, T.

2012-12-01

[Introduction] 129I is one of the available indexes of long-term migration of groundwater solutes, because of its long half-life (15.7 million years) and low sorption characteristics. The Horonobe underground research center (Japan Atomic Energy Agency), at which are conducted research and development of fundamental techniques on geological disposal of high-level radioactive waste, is an appropriate site for natural analogue studies, because iodine concentration in groundwater is high in this area. To predict iodine behavior in natural systems, speciation of iodine is essential because of different mobility among each species. In this study, we determined iodine speciation and129I/127I isotope ratios of rock and groundwater samples to investigate long term migration of iodine. [Methods] All rock and groundwater samples were collected at Horonobe underground research center. The region is underlain mainly by Neogene to Quaternary marine sedimentary rocks, the Wakkanai Formation (Wk Fm, siliceous mudstones), and the overlying Koetoi Formation (Kt Fm, diatomaceous mudstones). Iodine species in rock samples were determined by iodine K-edge X-ray absorption near edge structure (SPring-8 BL01B1). Thin sections of rock samples were prepared, and iodine mapping were obtained by micro-XRF analysis (SPring-8 BL37XU). Iodine species (IO3-, I-, and organic I) in groundwater were separately detected by high performance liquid chromatography connected to ICP-MS. The 129I/127I ratios in groundwater and rock samples were measured by accelerator mass spectrometry (MALT, Univ. of Tokyo). Iodine in rock samples were separated by pyrohydrolysis and water extraction. [Results and discussion] Concentration of iodine in groundwater varied widely and was much higher than that of seawater showing a high correlation with that of chlorine (R2 = 0.90). Species of iodine in groundwater was mainly I-. Iodine in rock samples decreased near the boundary between Wk and Kt Fms. Iodine K-edge XANES

STUDY ON EFFICACY OF DIATOMACEOUS EARTH TO AMELIORATE AFLATOXIN - INDUCED PATHO-MORPHOLOGICAL CHANGES IN LYMPHOID ORGANS OF BROILER CHICKEN

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A.W. Lakkawar

2017-12-01

Full Text Available The efficacy of Diatomaceous earth (DAE in reducing the detrimental effects of aflatoxin (AF in broiler diet was evaluated. DAE was supplemented 2000 mg/kg of feed along with 0.5 and 1 ppm of AF in feed. A total of 240 healthy day old broiler chicks were divided into 6 groups comprising of control and treatment groups. Feeding of AF resulted in reduction in size of the thymus, spleen and bursa of Fabricius. In addition, petechial haemorrhages were observed on the surface of the thymus. Histopathology revealed varying degree of lymphocytolysis and depletion of lymphoid cells in thymus, spleen and bursa of Fabricius. In addition, the ceacal tonsils also revealed a mild to moderate degree of lymphoid depletion. The supplementation of DAE to aflatoxin-mixed feed revealed significant improvement characterised by decreased severity of lesions in lymphoid organs. The macroscopic and microscopic changes in the birds fed DAE in combination with AF included those that were observed in AF- alone fed birds, but of reduced magnitude and severity. The study concluded that 2% DAE in feed can be effectively used to reduce the the histotoxic effects of aflatoxin on lymphoid organs in broiler chicken.

High-resolution delineation of chlorinated volatile organic compounds in a dipping, fractured mudstone: depth- and strata-dependent spatial variability from rock-core sampling

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Goode, Daniel J.; Imbrigiotta, Thomas E.; Lacombe, Pierre J.

2014-01-01

Synthesis of rock-core sampling and chlorinated volatile organic compound (CVOC) analysis at five coreholes, with hydraulic and water-quality monitoring and a detailed hydrogeologic framework, was used to characterize the fine-scale distribution of CVOCs in dipping, fractured mudstones of the Lockatong Formation of Triassic age, of the Newark Basin in West Trenton, New Jersey. From these results, a refined conceptual model for more than 55 years of migration of CVOCs and depth- and strata-dependent rock-matrix contamination was developed. Industrial use of trichloroethene (TCE) at the former Naval Air Warfare Center (NAWC) from 1953 to 1995 resulted in dense non-aqueous phase liquid (DNAPL) TCE and dissolved TCE and related breakdown products, including other CVOCs, in underlying mudstones. Shallow highly weathered and fractured strata overlie unweathered, gently dipping, fractured strata that become progressively less fractured with depth. The unweathered lithology includes black highly fractured (fissile) carbon-rich strata, gray mildly fractured thinly layered (laminated) strata, and light-gray weakly fractured massive strata. CVOC concentrations in water samples pumped from the shallow weathered and highly fractured strata remain elevated near residual DNAPL TCE, but dilution by uncontaminated recharge, and other natural and engineered attenuation processes, have substantially reduced concentrations along flow paths removed from sources and residual DNAPL. CVOCs also were detected in most rock-core samples in source areas in shallow wells. In many locations, lower aqueous concentrations, compared to rock core concentrations, suggest that CVOCs are presently back-diffusing from the rock matrix. Below the weathered and highly fractured strata, and to depths of at least 50 meters (m), groundwater flow and contaminant transport is primarily in bedding-plane-oriented fractures in thin fissile high-carbon strata, and in fractured, laminated strata of the gently

Comparative organic petrology of interlayered sandstones, siltstones, mudstones and coals in the Upper Carboniferous Ruhr basin, northwest Germany, and their thermal history and methane generation

Energy Technology Data Exchange (ETDEWEB)

Scheidt, G.; Littke, R. (Harress Geotechnik GmbH, Floersheim (Germany, F.R.))

1989-01-01

In the coal-mining Ruhr-area, Upper Carboniferous rocks consist of interlayered sandstones, siltstones, mudstones and coals. They were deposited in a tropical, paralic environment where alternating fluvial sedimentation, occasional marine ingressions, and swamp growth resulted in an irregular cyclic succession. The total sedimentary package contains on an average 6 Vol.% of organic manner. About 70 Vol. % of the organic matter occurs in coal seams, the rest as dispersed organic matter in clastic rocks. The organic matter is autochthonous in the coals and allochthonous in associated sandstones and siltstones. It consists of about 70% vitrinite, 20% inertinite, and 10% liptinite. The overall maceral group composition is the same for coals and dispersed organic matter. This surprising similarity is caused by a nearly exclusive input of land-plant derived organic matter to swamps and fluvial systems and a similar degree of preservation. Highest average liptinite contents were found in unrooted mudstones, highest average inertinite contents in coarse-grained siltstones and highest average vitrinite percentages in sandstones. Maturities of the sediments studied are well within the hydrocarbon generation window, e.g. vitrinite reflectivities range from 0.6% to 1.6%. Reflectivities measured on dispersed particles in clastic rocks are similar to those measured in coal seams. Calculations of the amount of methane generated indicate that coal seams contributed more to the total hydrocarbon generation than dispersed organic matter. 51 refs., 13 figs.

Impacts of Biochar on Physical Properties and Erosion Potential of a Mudstone Slopeland Soil

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Zeng-Yei Hseu

2014-01-01

Full Text Available Food demand and soil sustainability have become urgent issues recently because of the global climate changes. This study aims to evaluate the application of a biochar produced by rice hull, on changes of physiochemical characteristics and erosion potential of a degraded slopeland soil. Rice hull biochar pyrolized at 400°C was incorporated into the soil at rates of 2.5%, 5%, and 10% (w/w and was incubated for 168 d in this study. The results indicated that biochar application reduced the Bd by 12% to 25% and the PR by 57% to 92% after incubation, compared with the control. Besides, porosity and aggregate size increased by 16% to 22% and by 0.59 to 0.94 mm, respectively. The results presented that available water contents significantly increased in the amended soils by 18% to 89% because of the obvious increase of micropores. The water conductivity of the biochar-amended soils was only found in 10% biochar treatment, which might result from significant increase of macropores and reduction of soil strength (Bd and PR. During a simulated rainfall event, soil loss contents significantly decreased by 35% to 90% in the biochar-amended soils. In conclusion, biochar application could availably raise soil quality and physical properties for tilth increasing in the degraded mudstone soil.

Impacts of Biochar on Physical Properties and Erosion Potential of a Mudstone Slopeland Soil

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Chien, Wei-Hsin; Liou, Ruei-Cheng

2014-01-01

Food demand and soil sustainability have become urgent issues recently because of the global climate changes. This study aims to evaluate the application of a biochar produced by rice hull, on changes of physiochemical characteristics and erosion potential of a degraded slopeland soil. Rice hull biochar pyrolized at 400°C was incorporated into the soil at rates of 2.5%, 5%, and 10% (w/w) and was incubated for 168 d in this study. The results indicated that biochar application reduced the Bd by 12% to 25% and the PR by 57% to 92% after incubation, compared with the control. Besides, porosity and aggregate size increased by 16% to 22% and by 0.59 to 0.94 mm, respectively. The results presented that available water contents significantly increased in the amended soils by 18% to 89% because of the obvious increase of micropores. The water conductivity of the biochar-amended soils was only found in 10% biochar treatment, which might result from significant increase of macropores and reduction of soil strength (Bd and PR). During a simulated rainfall event, soil loss contents significantly decreased by 35% to 90% in the biochar-amended soils. In conclusion, biochar application could availably raise soil quality and physical properties for tilth increasing in the degraded mudstone soil. PMID:25548787

Development of in-situ rock shear test under low compressive to tensile normal stress

International Nuclear Information System (INIS)

Nozaki, Takashi; Shin, Koichi

2003-01-01

The purpose of this study is to develop an in-situ rock shear testing method to evaluate the shear strength under low normal stress condition including tensile stress, which is usually ignored in the assessment of safety factor of the foundations for nuclear power plants against sliding. The results are as follows. (1) A new in-situ rock shear testing method is devised, in which tensile normal stress can be applied on the shear plane of a specimen by directly pulling up a steel box bonded to the specimen. By applying the counter shear load to cancel the moment induced by the main shear load, it can obtain shear strength under low normal stress. (2) Some model tests on Oya tuff and diatomaceous mudstone have been performed using the developed test method. The shear strength changed smoothly from low values at tensile normal stresses to higher values at compressive normal stresses. The failure criterion has been found to be bi-linear on the shear stress vs normal stress plane. (author)

Effect of diatomaceous earth on parasite load, egg production, and egg quality of free-range organic laying hens.

Science.gov (United States)

Bennett, D C; Yee, A; Rhee, Y-J; Cheng, K M

2011-07-01

The effectiveness of diatomaceous earth (DE) as a treatment against parasites and to increase feed efficiency and egg production of organically raised free-range layer hens was evaluated in 2 breeds of commercial egg layers [Bovan Brown (BB) and Lowmann Brown (LB)] that differ in their resistance to internal parasitic infections. Half the hens of each breed were fed diets supplemented with DE (2%). Their internal parasite loads were assessed by biweekly fecal egg counts (FEC) and by postmortem examination of the gastrointestinal tract. Supplementing DE in diets of LB hens, the more parasite-resistant breed, did not significantly affect their FEC and adult parasite load. However, BB hens treated with dietary DE had significantly lower Capillaria FEC, slightly lower Eimeria FEC, fewer birds infected with Heterakis, and significantly lower Heterakis worm burden than control BB hens. Both BB and LB hens fed the diet containing DE were significantly heavier, laid more eggs, and consumed more feed than hens fed the control diet, but feed efficiency did not differ between the 2 dietary treatments. Additionally, BB hens consuming the DE diet laid larger eggs containing more albumen and yolk than hens consuming the control diet. In a subsequent experiment, the effectiveness of DE to treat a Northern fowl mite (Ornithonyssus sylviarum) infestation was tested. Relative to controls, both breeds of hens that were dusted with DE had reduced number of mites. The results of this study indicate the DE has the potential to be an effective treatment to help control parasites and improve production of organically raised, free-range layer hens.

The occurrence, origin and stratigraphic significance of bone-bearing mudstone pellet conglomerates from the Beaufort group in the Jansenville district, Cape Province, South Africa

International Nuclear Information System (INIS)

Turner, B.R.

1981-01-01

The lack of useful lithostratigraphic markers in the Beaufort Group in the southern Karoo Basin has focused attention on the biostratigraphy of the sediments. As a result a more refined scheme of biostratigraphic classification is now possible which may prove useful in fixing the stratigraphic position of the uranium mineralized horizons. The most important mineralized horizon in the Beaufort West area (contains about 90 per cent of all known uranium occurrences) is associated with the Pristerognathus/Diictodon assemblage zone, but the way in which this relates to the important uranium occurrences farther east, between Graaff-Reinet and Jansenville, is uncertain because of the lack of biostratigraphic control. Vertebrate remains have recently been found in mudstone pellet conglomerates in Beaufort channel sandstones along the Bullrivier in the Jansenville District, in an area that is extensively mineralized. The sandstones were deposited as point bar sands within a meandering river system flowing towards the north-east. The rivers drained a dry, arid to semi-arid alluvial plain and were characterized by fluctuating discharge and periods of low or negligible flow. These conditions promoted flood scour and fill activity and the deposition of internal mudstone pellet conglomerates. Hydrodynamic considerations suggest that estimates of bone transport velocity from their hydrodynamically equivalent quartz sphere is of limited value and can seldom, if ever, be applied to fossil bone accumulations. Identification of the bones from the conglomerates indicates that they belong to the Dino-cephalia biozone and not the overlying Pristerognathus/Diictodon zone. This suggests that the lower part of the Beaufort succession (formerly the Tapinocephalus zone) extends farther east than previously thought, and that the main mineralized horizon in this area occurs lower down in the succession than that around Beaufort West

Effect of Paecilomyces fumosoroseus (Wise) Brown and Smith(Ascomycota: Hypocreales) alone or in combination with diatomaceous earth against Tribolium confusum Jacquelin du Val (Coleoptera:Tenebrionidae) and Ephestia kuehniella Zeller (Lepidoptera: Pyralidae)

DEFF Research Database (Denmark)

Michalaki, M P; Athanassiou, C G; Steenberg, Tove

2007-01-01

moth, Ephestia kuehniella Zeller (Lepidoptera: Pyralidae). The fungus was added in stored wheat at two dose rates, 200 and 400 ppm, at two temperature levels, 20 and 25 °C alone or in combination with the diatomaceous earth formulation SilicoSec®. Mortality of the exposed individuals was measured after...... 7, 14 and 21 d of exposure. For both T. confusum adults and larvae, mortality was higher at 20 than at 25 °C. In the case of T. confusum larvae, after 14 d of exposure, mortality on wheat treated with the highest dose of P. fumosoroseus with SilicoSec® was signiWcantly higher than that of Silico...

Microstructure and permeability of the Whitby Mudstone (UK) as an analogue for the Posidonia shale (NL)

Science.gov (United States)

Houben, Maartje; Barnhoorn, Auke; Drury, Martyn; Peach, Colin; Spiers, Christopher

2015-04-01

In order to make gas productivity from a shale economically interesting we should find ways to better connect the in-situ pore network to the natural occurring and mechanical induced fractures in the rock. When trying to improve gas productivity a first aim is to understand gas storage and gas flow potential through the rock by investigating the microstructure and measure the matrix porosity and permeability of the unfractured shales. Using a combination of methods we have characterized the porosity and permeability of the Jet Dogger section of the Whitby Mudstone Formation (UK), which we use as an analogue for the Posidonia Shale (NL). The Posidonia shale is a possible unconventional source for gas in Northern Europe. A combination of Precision Ion Polishing (PIPS) and Scanning Electron Microscopy (SEM) has been used to investigate the microstructure and the pores. Microstructurally the circa 8 meter thick Jet section of the Whitby Mudstone Formation can be subdivided into a fossil rich (>15 %) top half with an organic matter content of 7-10% and a sub-mm laminated (alternating clay-rich, carbonate-rich, not necessarily fossils, layers) lower half were the organic matter content varies from 0.3-16%. In addition, any possible flow in the rock has to go through the fine-grained clay matrix (all grains 100 nm) is in the order of 0.5-2.5% and is not connected in 2D. Furthermore, overall more than 40% of the visible porosity is present within the clay matrix (sometimes even up to 80%). Porosity and pore size distributions for pores with smaller diameters (2 < diameter < 100 nm) were determined using Ar and N2 gas adsorption. The adsorption porosity was in the order of 1-5%, were we found 1-2.5% porosity for the top half of the section and 2-5% porosity for the bottom half. Ar gas permeability of the samples was measured on 1-inch diameter cores using Ar-gas-permeametry with a pressure step of 0.2 MPa. The permeability measured was in the order of 2•10-19 - 1•10

A Comparative Study of Mn/Co Binary Metal Catalysts Supported on Two Commercial Diatomaceous Earths for Oxidation of Benzene

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Marco Tomatis

2018-03-01

Full Text Available Two commercial diatomaceous earths were used as supports for the preparation of Mn/Co binary metal catalysts at different metal loads (5 to 10 wt % Mn and 5 to 15 wt % Co by incipient wetness deposition. The activity of the prepared catalysts towards the complete oxidation of benzene to CO2 and water was investigated between 100 and 400 °C. Raw supports and synthesized catalysts were characterized by XRD, N2 physisorption, SEM-EDS, H2-TPR, and TPD. The purification treatment of food-grade diatomite significantly affected the crystallinity of this support while reducing its specific surface area (SSA. A loss of SSA, associated with the increase in the metal load, was observed on samples prepared on natural diatomite, while the opposite trend occurred with food-grade diatomite-supported catalysts. Metal nanoparticles of around 50 nm diameter were observed on the catalysts’ surface by SEM analysis. EDS analysis confirmed the uniform deposition of the active phases on the support’s surface. A larger H2 consumption was found by TPR analysis of natural diatomite-based samples in comparison to those prepared at the same metal load on food-grade diatomite. During the catalytic oxidation experiment, over 90% conversion of benzene were achieved at a reaction temperature of 225 °C by all of the prepared samples. In addition, the formation of coke during the oxidation tests was demonstrated by TGA analysis and the soluble fraction of the produced coke was characterized by GC-MS.

Development of a promising filtration method for liquid clarification in nuclear facilities

International Nuclear Information System (INIS)

Collins, E.D.; Knauer, J.B.; Byrd, L.A.; Ross, R.G.; Savage, H.C.

1982-01-01

Conclusions reached are that deep beds of diatomaceous earths are especially attractive for clarification of radioactive solutions, or slurries containing insoluble radioactive material, because the diatomaceous material provides a noncompressible medium that is retentive for a wide variety of particle sizes. Also, the diatomaceous material, because of its inorganic composition, is resistant to degradation by radiation from the retained particulate matter. Its silicious character is especially appropriate for conversion to vitrified or cement-type waste forms. This paper studied the use of diatomaceous earth to filter synthetic TMI-2 water, reprocessing dissolver solutions, and zinc bromide solutions (hot-cell shielding)

LABORATORY TESTS ON INSECTICIDAL EFFECTIVENESS OF DISODIUM OCTABORATE TETRAHYDRATE, DIATOMACEOUS EARTH AND AMORPHOUS SILICA GEL AGAINST Sitophilus oryzae (L. AND THEIR EFFECT ON WHEAT BULK DENSITY

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Zlatko Korunić

2017-01-01

Full Text Available We examined insecticide effectiveness of three different inert dusts: disodium octaborate tetrahydrate (DOT and diatomaceous earth (DE Celatom® Mn 51 applied as powder and suspension, and silica gel Sipernat® 50 S applied as powder against Sitophilus oryzae (L. and their reduction of grain bulk density. Sipernat® 50 S was the most effective dust with a very fast initial effectiveness. DE and DOT generated similar effectiveness against S. oryzae. DOT generated low initial effectiveness but after prolonged exposure time of 8 and especially after 21 days, the mortality was very high (100%, similar to the effectiveness of DE. The similar order of dusts was obtained in the reduction of wheat bulk density. Applied at dose of 200 and 500 ppm, the lowest bulk density difference in regard to bulk density of untreated wheat had DOT (-1.1 and -1.9 kg hl-1, respectively, followed by Celatom® Mn 51 (-3.5 and -4.3 kg hl-1, respectively and Sipernat® 50 S (-5.2 and -5.5 kg hl-1, respectively. Due to the effect on wheat bulk density DOT belongs to the group with the least negative effect on bulk density and therefore, it is a promising dust to control stored grain insect pests.

Formation of a vitreous phase at the surface of some commercial diatomaceous earth prevents the onset of oxidative stress effects.

Science.gov (United States)

Ghiazza, Mara; Gazzano, Elena; Bonelli, Barbara; Fenoglio, Ivana; Polimeni, Manuela; Ghigo, Dario; Garrone, Edoardo; Fubini, Bice

2009-01-01

To understand the effect of the commercial processing of diatomaceous earths (DEs) on their ultimate surface structure and potential toxicity, we investigated the influence of the industrial processing and the nature of the deposit. Two flux calcined specimens from different deposits, DE/1-FC and DE/2-FC, and the simply calcined sample DE/1-C, from the same deposit as DE/1-FC, were compared in both their bulk and their surface properties. X-ray diffraction (XRD) analysis in a heating chamber revealed the presence of cristobalite in all samples, more abundant on the flux calcined ones. The crystal lattice is probably imperfect, as the alpha-beta transition, visible by XRD in DE/1-FC and DE/2-FC, is not detected by differential scanning calorimetry. Progressive etching with HF solutions suggests that most of the crystalline phase is at the core and not at the outer region of the samples. The combined use of spectroscopic (UV-vis and IR) and calorimetric techniques (heat of adsorption of water as a measure of hydrophilicity) reveals that DE/1-FC and DE/2-FC particles have an external layer of glass, absent in DE/1-C, where iron impurities act as network-forming and sodium ions as modifier species, with few patches of a hydrophobic phase, the latter relatable to a heated pure silica phase. When tested on a macrophage cell line (MH-S) in comparison with appropriate positive and negative controls (an active and an inactive quartz dust, respectively), only DE/1-C exhibited a cell damage and activation similar to that of active quartz (measured by lactate dehydrogenase release, peroxidation of membrane lipids and synthesis of NO). It is likely that the presence of a vitreous phase mitigates or even eliminates the cellular responses of silica in DE.

Efficacy of adsorbents (bentonite and diatomaceous earth) and turmeric (Curcuma longa) in alleviating the toxic effects of aflatoxin in chicks.

Science.gov (United States)

Dos Anjos, F R; Ledoux, D R; Rottinghaus, G E; Chimonyo, M

2015-01-01

A study was conducted to determine the efficacy of bentonite clay (BC), diatomaceous earth (DE) and turmeric powder (TUM) in alleviating the toxic effects of aflatoxin B1 (AFB1). A total of 250 Ross-308 d-old male broiler chicks were assigned to 10 dietary treatments (5 replicates of 5 chicks) from hatch to d 21. Dietary treatments were: basal diet; basal diet plus AFB1 (2 mg) or BC (0.75%), or DE (0.75%), or TUM (200 mg/kg curcuminoids) and different combinations of AFB1, BC, DE and TUM. Feed intake (FI), body weight gain (BWG) and feed gain (FG) of the birds fed on BC or DE separately were not different from control birds. Birds fed on TUM only had similar FI and FG but lower BWG than control chicks. Aflatoxin B1 reduced FI, BWG and serum concentrations of glucose, albumin, total protein calcium, but increased FG and relative liver and kidney weights. Chicks fed on the combination of AFB1 and BC had similar FI and FG to control chicks. Chicks fed on the combination of DE and AFB1 had lower FI (23.1%) and BWG (28.6%) compared with control chicks. Chicks fed on the combination of TUM and AFB1 also had decreased FI (26.2 %) and BWG (31%) compared with control chicks. Chicks fed on the combination of AFB1, BC and TUM consumed significantly higher amounts of feed compared with chicks fed on only AF, but gained less when compared with control diet chicks. Chicks fed on the combination of AFB1, DE and TUM diet had poorer growth performance than those fed on AFB1 alone. None of the combination diets reduced the severity of liver lesions.

Estudo de fundente e argilito com potencial para uso em formulações de porcelanato Study of flux and mudstone with potential for using in porcelainized stoneware tile compositions

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F. S. Hoffmann

2012-06-01

baixas. Composições com ambas as matérias-primas apresentaram baixos valores de absorção de água ( 45 MPa, apesar de maior deformação piroplástica a 1150 ºC.The porcelain tile is distinguished in the current market for ceramic tiles, with excellent technical and esthetic characteristics. In the present study traditional ceramic raw materials were selected and a standard formulation conventionally reported in the literature was adopted aiming to replace the melting phase (feldspar of the composition for a raw material that forms liquid phase at high temperature, and replacement of the clay fraction by a mudstone of lower refractoriness. The aim of this study was to evaluate the use of these materials as alternative techniques and lower cost, since, in a mass of porcelain tile, the amount of flux is very large (representing approximately 50% of total raw materials used. The nepheline syenite was the natural raw material selected to replace the feldspar due to the fact that it belongs to the family of feldspathoids, and has similar physicochemical characteristics, therefore, a high fluxing efficiency. To replace the clay fraction was chosen a mudstone naturally occurring, abundant in the region of Santa Gertrudes, SP. Substitutions to the feldspar and clay fraction were completely and/or partially by means of combinations between the flux and mudstones. The masses were processed from the mixing of powders, wet milling, drying, disagglomeration, compaction and firing. In addition to the vitrification curves, techniques such as dilatometry, measurements of porosity, flexure strength test, electron microscopy and X-ray diffraction were used to characterize the material after firing at various temperatures. The results showed that, in principle, it is possible the combination of raw materials such as nepheline and mudstone to replace potassium feldspar and S. Simão clay, as they provide the vitrification at lower temperatures. Compositions with both materials showed

Characterizing the Phyllosilicate Component of the Sheepbed Mudstone in Gale Crater, Mars Using Laboratory XRD and EGA

Science.gov (United States)

Rampe, E. B.; Morris, R. V.; Ming, D. W.; Archer, P. D.; Bish, D. L.; Chipera, S. J.; Vaniman, D. T.; Blake, D. F.; Bristow, T. F.; Sutter, B.;

Effects of smectite to illite transformation on the frictional strength and sliding stability of intact marine mudstones

Science.gov (United States)

Saffer, Demian M.; Lockner, David A.; McKiernan, Alex

2012-01-01

At subduction zones, earthquake nucleation and coseismic slip occur only within a limited depth range, known as the “seismogenic zone”. One leading hypothesis for the upper aseismic-seismic transition is that transformation of smectite to illite at ∼100–150°C triggers a change from rate-strengthening frictional behavior that allows only stable sliding, to rate weakening behavior considered a prerequisite for unstable slip. Previous studies on powdered gouges have shown that changes in clay mineralogy alone are unlikely to control this transition, but associated fabric and cementation developed during diagenesis remain possible candidates. We conducted shearing experiments designed specifically to evaluate this hypothesis, by using intact wafers of mudstone from Ocean Drilling Program Site 1174, offshore SW Japan, which have undergone progressive smectite transformation in situ. We sheared specimens along a sawcut in a triaxial configuration, oriented parallel to bedding, at normal stresses of ∼20–150 MPa and a pore pressure of 1 MPa. During shearing, we conducted velocity-stepping tests to measure the friction rate parameter (a-b). Friction coefficient ranges from 0.28–0.40 and values of (a-b) are uniformly positive; both are independent of clay transformation progress. Our work represents the most direct and comprehensive test of the clay transformation hypothesis to date, and suggests that neither illitization, nor accompanying fabric development and cementation, trigger a transition to unstable frictional behavior. We suggest that strain localization, in combination with precipitation of calcite and quartz, is a viable alternative that is consistent with both field observations and recent conceptual models of a heterogeneous seismogenic zone.

Orbital- to Sub-Orbital-Scale Cyclicity in Seismic Reflections and Sediment Character in Early to Middle Pleistocene Mudstone, Santa Barbara Basin, California

Science.gov (United States)

Peterson, C. D.; Behl, R. J.; Nicholson, C.; Lisiecki, L. E.; Sorlien, C. C.

2009-12-01

High-resolution seismic reflection records and well logs from the Santa Barbara Channel suggest that large parts of the Pleistocene succession records climate variability on orbital to sub-orbital scales with remarkable sensitivity, much like the well-studied sediments of the last glacial cycle (ODP Site 893). Spectral analysis of seismic reflection data and gamma ray logs from stratigraphically similar Pleistocene sections finds similar cyclic character and shifts through the section. This correlation suggests that acoustic impedance and physical properties of sediment are linked by basin-scale, likely climatically-driven, oscillations in lithologic composition and fabric during deposition, and that seismic profiling can provide a method for remote identification and correlation of orbital- and sub-orbital-scale sedimentary cyclicity. Where it crops out along the northern shelf of the central Santa Barbara Channel, the early to middle Pleistocene succession (~1.8-1.2 Ma) is a bathyal hemipelagic mudstone with remarkably rhythmic planar bedding, finely laminated fabric, and well-preserved foraminifera, none of which have been significantly altered, or obscured by post-depositional diagenesis or tectonic deformation. Unlike the coarser, turbiditic successions in the central Ventura and Los Angeles basins, this sequence has the potential to record Quaternary global climate change at high resolution. Seismic reflection data (towed chirp) collected on the R/V Melville 2008 Cruise (MV08) penetrate 10's of meters below seafloor into a ~1 km-long sequence of south-dipping seismic reflectors. Sampling parallel to the seafloor permits acquisition of consistent signal amplitude for similar reflectors without spreading loss. Based on established age ranges for this section, sedimentation rates may range from 0.4 to 1.4 meters/kyr, therefore suggesting that the most powerful cycles are orbital- to sub-orbital-scale. Discrete sets of cycles with high power show an abrupt shift

Influence of entomopathogenic fungus, Metarhizium anisopliae, alone and in combination with diatomaceous earth and thiamethoxam on mortality, progeny production, mycosis, and sporulation of the stored grain insect pests.

Science.gov (United States)

Ashraf, Misbah; Farooq, Muhammad; Shakeel, Muhammad; Din, Naima; Hussain, Shahbaz; Saeed, Nadia; Shakeel, Qaiser; Rajput, Nasir Ahmed

2017-12-01

The stored grain insects cause great damage to grains under storage conditions. Synthetic insecticides and fumigants are considered as key measures to control these stored grain insect pests. However, the major issue with these chemicals is grain contamination with chemical residues and development of resistance by insect pests to these chemicals. Biological control is considered as a potential alternative to chemical control especially with the use of pathogens, alone or in combination with selective insecticides. The present study was conducted to evaluate the synergism of Metarhizium anisopliae with diatomaceous earth (DE) and thiamethoxam against four insect pests on the stored wheat grains. In the first bioassay, the M. anisopliae was applied at 1.4 × 10 4 and 1.4 × 10 6 conidia/ml alone and in integration with two concentrations (250 and 500 ppm) of tested DE. The tested fungus when combined with DE and thiamethoxam possessed synergistic impact as compared to their individual efficacy. Adult mortality increased with respect to increased exposure interval and doses. In the second bioassay, M. anisopliae was applied at 1.4 × 10 4 conidia/ml individually and in combination with three concentrations (0.50, 0.75, and 1.00 ppm) of thiamethoxam. Results concluded that M. anisopliae integrated with DE and thiamethoxam provides more effective control of stored grain insect pests.

Rock Formation and Cosmic Radiation Exposure Ages in Gale Crater Mudstones from the Mars Science Laboratory

Science.gov (United States)

Mahaffy, Paul; Farley, Ken; Malespin, Charles; Gellert, Ralph; Grotzinger, John

2014-05-01

The quadrupole mass spectrometer (QMS) in the Sample Analysis at Mars (SAM) suite of the Mars Science Laboratory (MSL) has been utilized to secure abundances of 3He, 21Ne, 36Ar, and 40Ar thermally evolved from the mudstone in the stratified Yellowknife Bay formation in Gale Crater. As reported by Farley et al. [1] these measurements of cosmogenic and radiogenic noble gases together with Cl and K abundances measured by MSL's alpha particle X-ray spectrometer enable a K-Ar rock formation age of 4.21+0.35 Ga to be established as well as a surface exposure age to cosmic radiation of 78+30 Ma. Understanding surface exposures to cosmic radiation is relevant to the MSL search for organic compounds since even the limited set of studies carried out, to date, indicate that even 10's to 100's of millions of years of near surface (1-3 meter) exposure may transform a significant fraction of the organic compounds exposed to this radiation [2,3,4]. Transformation of potential biosignatures and even loss of molecular structural information in compounds that could point to exogenous or endogenous sources suggests a new paradigm in the search for near surface organics that incorporates a search for the most recently exposed outcrops through erosional processes. The K-Ar rock formation age determination shows promise for more precise in situ measurements that may help calibrate the martian cratering record that currently relies on extrapolation from the lunar record with its ground truth chronology with returned samples. We will discuss the protocol for the in situ noble gas measurements secured with SAM and ongoing studies to optimize these measurements using the SAM testbed. References: [1] Farley, K.A.M Science Magazine, 342, (2013). [2] G. Kminek et al., Earth Planet Sc Lett 245, 1 (2006). [3] Dartnell, L.R., Biogeosciences 4, 545 (2007). [4] Pavlov, A. A., et al. Geophys Res Lett 39, 13202 (2012).

Study on U-Ra equilibrium coefficient of the in-situ leaching sandstone-type uranium deposits: A case study of Qianjiadian uranium deposit

International Nuclear Information System (INIS)

Xia Yuliang; Xiu Qunye; Han Jun; Li Linqiang; Zheng Jiwei

2013-01-01

This paper investigated the U-Ra equilibrium coefficient (K-p) of mineralized sandstone and mudstone, and unmineralized sandstone and mudstone for the in-situ leaching sandstone-type uranium deposits. It is surprised that all of the mineralized sandstone and mudstone are both relatively to be partial to uranium, but all of the unmineralized sandstone and mudstone are both relatively to be partial to radium. Meanwhile the uranium in mineralized mudstone is relatively richer than that in mineralized sandstone, and the radium in unmineralized mudstone is relatively richer than that in unmineralized sandstone. It is suggested that mudstones were permeable at the uranium mineralized phase and the unmineralized mudstone and sandstone could serve as important mineralized uranium source. (authors)

Geomorphic Drainage Capture Recorded by Oxygen Isotopes of Green River Formation Lacustrine Mudstone, Eocene, Wyoming

Science.gov (United States)

Doebbert, A. C.; Booth, A. L.; Carroll, A.; Chamberlain, C.; Rhodes, M.

2005-12-01

The isotopic composition of cement and other meteoric precipitates are increasingly being used to interpret orogenic uplift histories, based on the relationship between altitude and rainwater δ18O. However, other variables such as changing regional drainage patterns may also affect the downstream composition of surface waters, especially when multiple drainages commingle in a lake. The Green River Formation contains some of the best documented lacustrine deposits in the world, making it ideal for examining such issues. Carbonate mudstone in balanced-fill facies of the lower LaClede Bed averages 3.41‰ (PDB), and records a deep, saline to brackish lake that fluctuated near its sill. In contrast, overfilled facies of the upper LaClede Bed record a freshwater lake, and δ18O reaches values as low as -9.72‰. This transition occurred shortly after deposition of the Analcite Tuff at 48.94 ± 0.12 Ma (Smith et al., 2003), and was geologically abrupt. Based on 40Ar/39Ar-calibrated sediment accumulation rates it required no more than 200-300 ky. An almost identical transition occurs in two cores separated by about 30 km, making local diagenesis an unlikely cause. The magnitude of δ18O change is similar to that in some uplift studies, but its rapidity virtually excludes uplift as a controlling mechanism. Instead, we propose that both the change in sedimentation and the sharp decrease in δ18O are the result of a drainage capture event. The addition of a new drainage to the basin may have adjusted isotopic values in two ways: by introducing runoff with relatively low δ18O, and by decreasing residence time (and therefore evaporation) of lake water. Decreasing 87Sr/86Sr across the same transition suggests that the newly added waters may have been sourced from rising volcanic topography to the north in the Absaroka province. Although this rising topography allows for the possibility of some uplift component, the rate of change in lacustrine δ18O is consistent with

Novel approach to high-throughput determination of endocrine disruptors using recycled diatomaceous earth as a green sorbent phase for thin-film solid-phase microextraction combined with 96-well plate system.

Science.gov (United States)

Kirschner, Nicolas; Dias, Adriana Neves; Budziak, Dilma; da Silveira, Cristian Berto; Merib, Josias; Carasek, Eduardo

2017-12-15

A sustainable approach to TF-SPME is presented using recycled diatomaceous earth, obtained from a beer purification process, as a green sorbent phase for the determination of bisphenol A (BPA), benzophenone (BzP), triclocarban (TCC), 4-methylbenzylidene camphor (4-MBC) and 2-ethylhexyl-p-methoxycinnamate (EHMC) in environmental water samples. TF-SPME was combined with a 96-well plate system allowing for high-throughput analysis due to the simultaneous extraction/desorption up to 96 samples. The proposed sorbent phase exhibited good stability in organic solvents, as well as satisfactory analytical performance. The optimized method consisted of 240 min of extraction at pH 6 with the addition of NaCl (15% w/v). A mixture of MeOH:ACN (50:50 v/v) was used for the desorption the analytes, using a time of 30 min. Limits of detection varied from 1 μg L -1 for BzP and TCC to 8 μg L -1 for the other analytes, and R 2 ranged from 0.9926 for 4-MBC to 0.9988 for BPA. This novel and straightforward approach offers an environmentally-friendly and very promising alternative for routine analysis. . The total sample preparation time per sample was approximately 2.8 min, which is a significant advantage when a large number of analytical run is required. Copyright © 2017 Elsevier B.V. All rights reserved.

Traces in the dark: sedimentary processes and facies gradients in the upper shale member of the Upper Devonian-Lower Mississippian Bakken Formation, Williston Basin, North Dakota, U.S.A.

Science.gov (United States)

Egenhoff, Sven O.; Fishman, Neil S.

2013-01-01

Black, organic-rich rocks of the upper shale member of the Upper Devonian–Lower Mississippian Bakken Formation, a world-class petroleum source rock in the Williston Basin of the United States and Canada, contain a diverse suite of mudstone lithofacies that were deposited in distinct facies belts. The succession consists of three discrete facies associations (FAs). These comprise: 1) siliceous mudstones; 2) quartz- and carbonate-bearing, laminated mudstones; and 3) macrofossil-debris-bearing massive mudstones. These FAs were deposited in three facies belts that reflect proximal to distal relationships in this mudstone system. The macrofossil-debris-bearing massive mudstones (FA 3) occur in the proximal facies belt and contain erosion surfaces, some with overlying conodont and phosphate–lithoclast lag deposits, mudstones with abundant millimeter-scale siltstone laminae showing irregular lateral thickness changes, and shell debris. In the medial facies belt, quartz- and carbonate-bearing, laminated mudstones dominate, exhibiting sub-millimeter-thick siltstone layers with variable lateral thicknesses and localized mudstone ripples. In the distal siliceous mudstone facies belt, radiolarites, radiolarian-bearing mudstones, and quartz- and carbonate-bearing, laminated mudstones dominate. Overall, total organic carbon (TOC) contents range between about 3 and 10 wt %, with a general proximal to distal decrease in TOC content. Abundant evidence of bioturbation exists in all FAs, and the lithological and TOC variations are paralleled by changes in burrowing style and trace-fossil abundance. While two horizontal traces and two types of fecal strings are recognized in the proximal facies belt, only a single horizontal trace fossil and one type of fecal string characterize mudstones in the distal facies belt. Radiolarites intercalated into the most distal mudstones are devoid of traces and fecal strings. Bedload transport processes, likely caused by storm-induced turbidity

Numerical Simulation on Open Wellbore Shrinkage and Casing Equivalent Stress in Bedded Salt Rock Stratum

Directory of Open Access Journals (Sweden)

Jianjun Liu

2013-01-01

Full Text Available Most salt rock has interbed of mudstone in China. Owing to the enormous difference of mechanical properties between the mudstone interbed and salt rock, the stress-strain and creep behaviors of salt rock are significantly influenced by neighboring mudstone interbed. In order to identify the rules of wellbore shrinkage and casings equivalent stress in bedded salt rock stratum, three-dimensional finite difference models were established. The effects of thickness and elasticity modulus of mudstone interbed on the open wellbore shrinkage and equivalent stress of casing after cementing operation were studied, respectively. The results indicate that the shrinkage of open wellbore and equivalent stress of casings decreases with the increase of mudstone interbed thickness. The increasing of elasticity modulus will reduce the shrinkage of open wellbore and casing equivalent stress. Research results can provide the scientific basis for the design of mud density and casing strength.

Hydrogeologic framework of fractured sedimentary rock, Newark Basin, New Jersey

Science.gov (United States)

Lacombe, Pierre J.; Burton, William C.

2010-01-01

The hydrogeologic framework of fractured sedimentary bedrock at the former Naval Air Warfare Center (NAWC), Trenton, New Jersey, a trichloroethylene (TCE)-contaminated site in the Newark Basin, is developed using an understanding of the geologic history of the strata, gamma-ray logs, and rock cores. NAWC is the newest field research site established as part of the U.S. Geological Survey Toxic Substances Hydrology Program, Department of Defense (DoD) Strategic Environmental Research and Development Program, and DoD Environmental Security Technology Certification Program to investigate contaminant remediation in fractured rock. Sedimentary bedrock at the NAWC research site comprises the Skunk Hollow, Byram, and Ewing Creek Members of the Lockatong Formation and Raven Rock Member of the Stockton Formation. Muds of the Lockatong Formation that were deposited in Van Houten cycles during the Triassic have lithified to form the bedrock that is typical of much of the Newark Basin. Four lithotypes formed from the sediments include black, carbon-rich laminated mudstone, dark-gray laminated mudstone, light-gray massive mudstone, and red massive mudstone. Diagenesis, tectonic compression, off-loading, and weathering have altered the rocks to give some strata greater hydraulic conductivity than other strata. Each stratum in the Lockatong Formation is 0.3 to 8 m thick, strikes N65 degrees E, and dips 25 degrees to 70 degrees NW. The black, carbon-rich laminated mudstone tends to fracture easily, has a relatively high hydraulic conductivity and is associated with high natural gamma-ray count rates. The dark-gray laminated mudstone is less fractured and has a lower hydraulic conductivity than the black carbon-rich laminated mudstone. The light-gray and the red massive mudstones are highly indurated and tend to have the least fractures and a low hydraulic conductivity. The differences in gamma-ray count rates for different mudstones allow gamma-ray logs to be used to correlate and

Método QuEChERS para determinação de ocratoxina a e citrinina em arroz e farelo de arroz

Directory of Open Access Journals (Sweden)

Helen C. dos S. Hackbart

2012-01-01

Full Text Available The present study was carried out to establish the optimal conditions for performing ochratoxin A (OTA and citrinin (CIT extraction using the QuEChERS method in rice. Employing the factorial experimental design, variables that significantly influenced the extraction stages were determined. The following variables were analyzed: addition of water, acidification of acetonitrile with glacial acetic acid, as well as amounts of magnesium sulfate, sodium acetate, sodium citrate and diatomaceous earth. The best combining procedure resulted in a predictive model using more water and less diatomaceous earth. Recoveries of CIT and OTA were 78-105%.

Self-assembled micro-structured sensors for food safety in paper based food packaging

Energy Technology Data Exchange (ETDEWEB)

Hakovirta, M., E-mail: marko.hakovirta@storaenso.com; Aksoy, B.; Hakovirta, J.

2015-08-01

Natural self-assembled microstructured particles (diatomaceous earth) were used to develop a gas sensor paper with detection mechanism based on visible and distinct color changes of the sensor paper when exposed to volatile basic nitrogen compounds. The coating formulation for paper was prepared by applying diatomites, polyvinyl alcohol (PVOH), and pH sensitive dyes on acidic paper substrate. The surface coating was designed to allow a maximum gas flow through the diatomite sensors. The produced sensor paper was tested for sensitivity using different ammonia concentrations and we observed a sensitivity lower limit at 63 ppm. As a comparison, the results show comparable sensitivity levels to carbon nanotube based sensor technologies reported in literature. - Highlights: • Novel sensor paper was developed using micro-structured diatomaceous earth and pH sensitive dye. • The functionality is based on pH sensitive dye to indicate spoilage of meat or fish by color change. • Diatomaceous earth was successfully immobilized to the polyvinyl alcohol coating. • The coating was engineered to maximize the exposure of the diatom morphology. • The sensor paper achieved very high sensitivities for ammonia gas detection.

Self-assembled micro-structured sensors for food safety in paper based food packaging

International Nuclear Information System (INIS)

Hakovirta, M.; Aksoy, B.; Hakovirta, J.

2015-01-01

Natural self-assembled microstructured particles (diatomaceous earth) were used to develop a gas sensor paper with detection mechanism based on visible and distinct color changes of the sensor paper when exposed to volatile basic nitrogen compounds. The coating formulation for paper was prepared by applying diatomites, polyvinyl alcohol (PVOH), and pH sensitive dyes on acidic paper substrate. The surface coating was designed to allow a maximum gas flow through the diatomite sensors. The produced sensor paper was tested for sensitivity using different ammonia concentrations and we observed a sensitivity lower limit at 63 ppm. As a comparison, the results show comparable sensitivity levels to carbon nanotube based sensor technologies reported in literature. - Highlights: • Novel sensor paper was developed using micro-structured diatomaceous earth and pH sensitive dye. • The functionality is based on pH sensitive dye to indicate spoilage of meat or fish by color change. • Diatomaceous earth was successfully immobilized to the polyvinyl alcohol coating. • The coating was engineered to maximize the exposure of the diatom morphology. • The sensor paper achieved very high sensitivities for ammonia gas detection

Insecticidal effect and impact of fitness of three diatomaceous earths on different maize hybrids for the eco-friendly control of the invasive stored-product pest Prostephanus truncatus (Horn).

Science.gov (United States)

Kavallieratos, Nickolas G; Athanassiou, Christos G; Peteinatos, Gerassimos G; Boukouvala, Maria C; Benelli, Giovanni

2018-04-01

Diatomaceous earths (DEs) are able to successfully protect grain commodities from noxious stored-product insect and mite infestations; however, their effectiveness may be moderated by the grain hybrid or variety they are applied to. There is a gap of information on the comparison of the efficacy of different DEs when are applied on different maize hybrids against Prostephanus truncatus (Horn). Therefore, here we tested three commercially available DEs (DEA-P at 75 and 150 ppm, Protect-It at 500 ppm, and PyriSec at 500 ppm) on five different maize hybrids (Calaria, Doxa, Rio Grande, Sisco, and Studio) for the control of P. truncatus adults in terms of mortality (at 7 and 14 days), progeny production, properties of the infested maize hybrids (number and weight of kernels with or without holes, number of holes per kernel) and the adherence level of the tested DEs to the kernels. DEA-P was very effective at 75 ppm while a considerable proportion of the exposed P. truncatus adults was still alive after 14 days of exposure on all maize hybrids treated with 500 ppm of Protect-It or PyriSec, even though it was 3.3 times higher than the maximal application tested dose of DEA-P. Apart from parental mortality, DEA-P was able to reduce P. truncatus progeny production in all hybrids contrary to Protect-It or PyriSec. The adherence ratios were always higher for DEA-P than Protect-It or PyriSec to all maize hybrids. The highest numbers of kernels (or weight of kernels) without holes were noticed after their treatment with DEA-P. Doxa and Sisco performed better than Calaria, Rio Grande, or Studio based on the differences found concerning the numbers of kernels without holes at treatments with DEA-P and Protect-It. Overall, the findings of our study indicate the high potentiality of DEA-P as protectant of different maize hybrids to P. truncatus infestations at low doses, a fact that could help the eco-friendly management of this noxious species in the stored

Stratigraphy of Eocene Sediments in the Soutwest Thrace

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Muhsin SÜMENGEN

1991-06-01

Full Text Available The area concerned is situated in the Gelibolu peninsula, north of the Saros Bay and northwest of the Marmara sea sediments of Upper Cretaceous to Miocene age, having a variety of fades crop out SW of Thrace. During the present survey, the goal was to examine the stratigraphic features of the Eocene sediments in the region. The Tertiary basin is underlain by an ophiolitic complex emplaced prior to Maastrichtian and limestone of Maastrichtian to Palaeocene age. The base of the limestone is not exposed within the region. The Tertiary transgression began in the Early Eocene in the Gelibolu peninsula. Massive mudstones, sandstone sequences that become thicker and coarser upward, and channel fill sediments are the first products of this transgression (Karaağaç limanı formation. This sequence is overlain by deltaic sediments beginning with massive mudstones and becoming thicker and coarser upward (Koyun limanı formation. These sediments are conformably and transitionally overlain by interbedded mudstone and sandstone, cut by channel fill deposits (Rcitepe formation. This formation was formed by meandering rivers. The sea that progressed inward to the Gelibolu peninsula during the Early Eocene began to become shallower again at the beginning of Lutetian and as a result, the region as a whole became a positive area during the Middle Lutetian. During the Late Lutetian, a new transgression occurred in the entire region. The first product of this transgression was a limestone (Soğucak formation. This limestone which was deposited in a shallow sea environment is locally intercalated with sandstone and conglomerate. The sea became deeper from the beginning of Upper Eocene. Firstly, turbiditic sandstone, and mudstone interbedded hemipelagic mudstone (Gaziköy formation with tuff, and carbonate mudstone and massive mudstone (Burgaz formation were deposited. These units are products of flat basins. These are, in turn, overlain by sequences consisting of

Geochemical evidences for palaeoclimatic fluctuations at the Triassic-Jurassic boundary: southwestern margin of the Neotethys in the Salt Range, Pakistan

Science.gov (United States)

Iqbal, Shahid; Wagreich, Michael; Jan, Irfanullah; Kürschner, Wolfram Michael; Gier, Susanne

2017-04-01

The Triassic-Jurassic boundary interval reveals a change from warm-arid to a warm and humid climate in the Tethyan domain. Sea-level reconstruction records across the European basins during this interval reveal an end-Triassic global regression event and is linked to the Central Atlantic Magmatic Province (CAMP) activity and Pangaea breakup. In the Tethyan Salt Range of Pakistan a succession of Upper Triassic dolomites/green-black mudstones (Kingriali Formation), overlying quartzose sandstone, mudstones, laterites and Lower Jurassic conglomerates/pebbly sandstones (Datta Formation) provides information on the palaeoclimatic evolution of the area. Preliminary palynological results from the mudstones indicate a Rhaetian age for the Kingriali Formation and a Hettangian age for the Datta Formation. X-ray diffraction (XRD) analysis of the mudstones (upper part of the Kingriali Formation) indicates the presence of mainly illite while kaolinite is a minor component. The kaolinite content, a reflection of the advanced stage of chemical weathering and hence warm-humid conditions, increases up-section in the overlying sandstone-mudstone succession. The overlying laterite-bauxite horizons lack illite/smectite and are entirely composed of kaolinite, boehmite and haematite. At places these kaolinite rich horizons are mined in the area (Western Salt Range). The bulk rock geochemistry of the succession confirms a similar trend. The Chemical Index of Alteration (CIA) displays an increasing trend from the Upper Triassic shales (CIA 75-80) through the overlying sandstones/mudstones-laterites to the overlying quartz rich sandstones and mudstones (CIA 90-97). The overall results for the succession reveal an increasing chemical maturity trend (increase in the intensity of chemical weathering) from Rhaetian to Hettangian thereby supporting a change from warm-arid to a warm-humid palaeoclimate, probably extreme greenhouse conditions.

Karoo airborne geophysical survey

International Nuclear Information System (INIS)

Cole, D.J.; Stettler, E.H.

1984-01-01

Thirty four uranium anomalies were selected for ground follow-up from the analogue spectrometer records of Block 4 of the Karoo Airborne Geophysical Survey. The anomalies were plotted on 1:50 000 scale topographic maps and to 1:250 000 scale maps which are included in this report. The anomaly co-ordinates are tabulated together with the farms on which they occur. Results of the ground follow-up of the aerial anomalies are described. Twenty two anomalies are related to uranium mineralisation of which seventeen occur over baked mudstone adjacent to a dolerite intrusion. Five are located over fluvial channel sandstone of the Beaufort Group and subsurface mineralised sandstone may be present. The other twelve anomalies are spurious. Of the anomalies located over baked mudstone, fifteen emanate from ferruginous mudstone of the Whitehill Formation west of longitude 21 degrees 15 minutes. One of the two remaining anomalies over baked mudstone occurs over the Prince Albert Formation and the other anomaly is over baked mudstone and calcareous nodules of the Beaufort Group. The general low uranium values (less than 355 ppm eU3O8) render the occurrences uneconomic

Sedimentology of SPICE (Steptoean positive carbon isotope excursion): A high-resolution trace fossil and microfabric analysis of the middle to late Cambrian Alum Shale Formation, southern Sweden

Science.gov (United States)

Egenhoff, Sven; Fishman, Neil; Ahlberg, Per; Maletz, Jorg; Jackson, Allison; Kolte, Ketki; Lowers, Heather; Mackie, James; Newby, Warren; Petrowsky, Matthew

2015-01-01

The Cambrian Alum Shale Formation in the Andrarum-3 core from Scania, southern Sweden, consists of black siliciclastic mudstone with minor carbonate intercalations. Four facies comprise three siliciclastic mudstones and one fine-grained carbonate. The facies reflect deposition along a transect from deep ramp to basin on a Cambrian shelf. The three mudstone facies contain abundant clay clasts and laterally variable siltstone laminae. Bed-load transport processes seem to have dominated deposition on this deep shelf. These sedimentary rocks record mainly event deposition, and only relatively few, thin laminae probably resulted from suspension settling. The Alum Shale Formation deep shelf did not show a bioturbation gradient, but fecal strings are common and Planolites burrows are rare in all mudstone facies. Evidence for biotic colonization indicates that this mudstone environment was not persistently anoxic, but rather was most likely intermittently dysoxic. The Alum Shale Formation in the Andrarum-3 core shows an overall decrease of grain size, preserved energy indicators, and carbonate content upsection interpreted to reflect a deepening upward. The succession can also be divided into four small-scale fining-upward cycles that represent deepening, and four overlying coarsening-upward cycles that represent upward shallowing.

Chalk as a reservoir

DEFF Research Database (Denmark)

Fabricius, Ida Lykke

, and the best reservoir properties are typically found in mudstone intervals. Chalk mudstones vary a lot though. The best mudstones are purely calcitic, well sorted and may have been redeposited by traction currents. Other mudstones are rich in very fine grained silica, which takes up pore space and thus...... basin, so stylolite formation in the chalk is controlled by effective burial stress. The stylolites are zones of calcite dissolution and probably are the source of calcite for porefilling cementation which is typical in water zone chalk and also affect the reservoirs to different extent. The relatively...... have hardly any stylolites and can have porosity above 40% or even 50% and thus also have relatively high permeability. Such intervals have the problem though, that increasing effective stress caused by hydrocarbon production results in mechanical compaction and overall subsidence. Most other chalk...

EFFICACY OF NIGERIA-DERIVED DIATOMACEOUS EARTH ...

African Journals Online (AJOL)

ACSS

DE, was tested as a standard check. The rates tested ..... (Cressington Carbon Coater; Balzers Union Med. 010 Au/Pt ..... particles may have offset the benefits of its high. Silica content .... In: A study of Private Sector Participation in National.

75 FR 12723 - Notice of Meeting of the National Organic Standards Board

Science.gov (United States)

2010-03-17

...); Paprika color--dried powder and vegetable oil extract (CAS 68917-78-2); Pumpkin juice color (pigment CAS...; Calcium carbonate; Calcium chloride; Carageenan; Dairy cultures; Diatomaceous earth; Enzymes; Flavors...

Possible Significance of Early Paleozoic Fluctuations in Bottom Current Intensity, Northwest Iapetus Ocean

Science.gov (United States)

Lash, Gary G.

1986-06-01

Sedimentologic and geochemical characteristics of red and green deep water mudstone exposed in the central Appalachian orogen define climatically-induced fluctuations in bottom current intensity along the northwest flank of the Iapetus Ocean in Early and Middle Ordovician time. Red mudstone accumulated under the influence of moderate to vigorous bottom current velocities in oxygenated bottom water produced during climatically cool periods. Interbedded green mudstone accumulated at greater sedimentation rates, probably from turbidity currents, under the influence of reduced thermohaline circulation during global warming periods. The close association of green mudstone and carbonate turbidites of Early Ordovician (late Tremadocian to early Arenigian) age suggests that a major warming phase occurred at this time. Increasing temperatures reduced bottom current velocities and resulted in increased production of carbonate sediment and organic carbon on the carbonate platform of eastern North America. Much of the excess carbonate sediment and organic carbon was transported into deep water by turbidity currents. Although conclusive evidence is lacking, this eustatic event may reflect a climatic warming phase that followed the postulated glacio-eustatic Black Mountain event. Subsequent Middle Ordovician fluctuations in bottom current intensity recorded by thin red-green mudstone couplets probably reflect periodic growth and shrinkage of an ice cap rather than major glacial episodes.

21 CFR 178.3620 - Mineral oil.

Science.gov (United States)

2010-04-01

... Mansville Company, diatomaceous earth, or equivalent. Magnesium oxide-Celite 545 mixture (2+1) by weight... seeds (for example, beans, peas, rice, and lentils); whole root crop vegetables of the types identified...

The Laminated Marca Shale: High-Frequency Climate Cycles From the Latest Cretaceous

Science.gov (United States)

Davies, A.; Kemp, A. E.; Weedon, G.; Barron, J. A.

2005-12-01

The Latest Cretaceous (Maastrichtian) Marca Shale Member, California, displays a well-preserved record of alternating terrigenous and diatomaceous laminae couplets, remarkably similar in lithology to recent laminated sediments from the Gulf of California and Santa Barbara Basin. This similarity, together with the recognition of intra- and inter-annual variability in the diatom flora, implies an annual origin for these couplets. High-resolution backscattered electron imagery has identified two sublaminae types within the varved succession; near monospecific lamina of Chaetoceros-type resting spore and of large Azpeitiopsis morenoensis. The composition and occurrence of these laminae is similar to ENSO forced intra-annual variability of diatom flora along the modern Californian margin. Relative thickness variations in terrigenous and biogenic laminae (proxies for precipitation and productivity respectively) also exhibit similar characteristics to variability in Quaternary varves from the Santa Barbara Basin, shown to be imparted by ENSO forcing. In order to track changes in the levels of bottom water oxygenation within the basin, a bioturbation index was established. Periods when bioturbation was minimal (enhanced benthic anoxia) coincide with times of greatest diatomaceous export flux and also lowest flux of detrital material. Conversely, periods of enhanced bioturbation correspond with reduced diatomaceous export flux and an increased flux of detrital material, comparable with ENSO forced variations in diatomaceous and terrigenous export flux and associated benthic oxygenation levels in Pleistocene varves off the Californian margin. Power spectra obtained from time-series analysis of the bioturbation index and laminae thickness variations exhibit strong signals within the ENSO band. This research implies that high-frequency climate perturbations are inherent components of the climate system and that ENSO-type variability was not confined to the dynamic climate

Significance of Kaduna River to Kaduna Refining and ...

African Journals Online (AJOL)

User

River through the Kaduna Refining and Petrochemicals Company (KRPC) plants and .... Other less-common process involves filtering heated crude using diatomaceous earth ..... Water is polluted by the fallout from air pollution and by refinery.

Application of self-balanced loading test to socketed pile in weak rock

Science.gov (United States)

Cheng, Ye; Gong, Weiming; Dai, Guoliang; Wu, JingKun

2008-11-01

Method of self-balanced loading test differs from the traditional methods of pile test. The key equipment of the test is a cell. The cell specially designed is used to exert load which is placed in pile body. During the test, displacement values of the top plate and the bottom plate of the cell are recorded according to every level of load. So Q-S curves can be obtained. In terms of test results, the bearing capacity of pile can be judged. Equipments of the test are simply and cost of it is low. Under some special conditions, the method will take a great advantage. In Guangxi Province, tertiary mudstone distributes widely which is typical weak rock. It is usually chosen as the bearing stratum of pile foundation. In order to make full use of its high bearing capacity, pile is generally designed as belled pile. Foundations of two high-rise buildings which are close to each other are made up of belled socketed piles in weak rock. To obtain the bearing capacity of the belled socketed pile in weak rock, loading test in situ should be taken since it is not reasonable that experimental compression strength of the mudstone is used for design. The self-balanced loading test was applied to eight piles of two buildings. To get the best test effect, the assembly of cell should be taken different modes in terms of the depth that pile socketed in rock and the dimension of the enlarged toe. The assembly of cells had been taken three modes, and tests were carried on successfully. By the self-balanced loading test, the large bearing capacities of belled socketed piles were obtained. Several key parameters required in design were achieved from the tests. For the data of tests had been analyzed, the bearing performance of pile tip, pile side and whole pile was revealed. It is further realized that the bearing capacity of belled socketed pile in the mudstone will decrease after the mudstone it socketed in has been immerged. Among kinds of mineral ingredient in the mudstone

40 CFR 141.550 - Is my system required to meet subpart T combined filter effluent turbidity limits?

Science.gov (United States)

2010-07-01

... ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) WATER PROGRAMS (CONTINUED) NATIONAL PRIMARY DRINKING WATER REGULATIONS Enhanced Filtration and Disinfection-Systems Serving Fewer Than 10,000 People Combined Filter... utilize filtration other than slow sand filtration or diatomaceous earth filtration must meet the combined...

Original Researc Original Research

African Journals Online (AJOL)

RAGHAVENDRA

2015-03-15

Mar 15, 2015 ... powder were evaluated against the maize weevil in n laid out in a randomized complete ..... diatomaceous earth with plant extracts, insecticides and ... commercial neem product Azal-T/S (1 gm kg-1) resulted in higher mortality ...

Pliocene benthonic foraminifera from homogeneous and laminated marls on Crete

NARCIS (Netherlands)

Jonkers, H.A.

1984-01-01

In the Pliocene, the paleogeography of central Crete consisted of a number of basins which were filled by predominantly marly sediments. In the sedimentary sequence numerous laminated sapropelic intercalations can be observed. At a higher stratigraphic level diatomaceous laminites appear.

Mit Wasser aushärtende Alginatzusammensetzungen

NARCIS (Netherlands)

Ippel, D.; Timmerman, G.; Timmermans, J.W.; Soest, van J.J.G.

2005-01-01

Water-hardenable alginate compositions contain as filler a combination comprising (A) cellulose or a water-insoluble derivative and (B) starch or a water-insoluble derivative, optionally together with a diatomaceous earth, perlite, talc or argillaceous earth filler. Water-hardenable alginate

The salt that wasn't there: Mudflat facies equivalents to halite of the Permian Rustler Formation, southeastern New Mexico

International Nuclear Information System (INIS)

Powers, D.W.; Holt, R.M.

2000-01-01

Four halite beds of the Permian Restler Formation in southeastern New Mexico thin dramatically over horst lateral distances to correlative classic (mudstone) beds. The mudstones have long been considered residues after post-burial dissolution (subrosion) of halite, assumed to have been deposited continuously across the area. Hydraulic properties of the Culebra Dolomite Member have often been related to Rustler subrosion. In cores and three shafts at the Waste Isolation Pilot Plant (WIPP), however, these mudstones display flat bedding, graded bedding, cross-bedding, erosional contacts, and channels filled with intraformational conglomerates. Cutans indicate early stages of soil development during subaerial exposure. Smeared intraclasts developed locally as halite was removed syndepositionally during subaerial exposure. The authors interpret these beds as facies formed in salt-pan or hypersaline-lagoon, transitional, and mudflat environments. Halite is distributed approximately as it was deposited. Breccia in limited areas along one halite margin indicates post-burial dissolution, and these breccials are key to identifying areas of subrosion. A depositional model accounts for observed sedimentary features of Restler mudstones. Marked facies and thickness changes are consistent with influence by subsidence boundaries, as found in some modern continental evaporites. A subrosion model accounts for limited brecciated zones along (depositional)halite margins, but bedding observed in the mudstones would not survive 90% reduction in rock volume. Depositional margins for these halite beds will be useful in reconstructing detailed subsidence history of the Late Permian in the northern Delaware Basin, It also no longer is tenable to attribute large variations in Culebra transmissivity to Rustler subrosion

78 FR 65561 - D-Glucopyranose, oligomeric, decyl octyl glycosides; Exemption from the Requirement of a Tolerance

Science.gov (United States)

2013-11-01

... metabolize D-glucopyranose, oligomeric, C 10 -C 16 -alkyl glycosides to water-soluble substances... polyoxyethylene polymers and fatty acids; carriers such as clay and diatomaceous earth; thickeners such as... exposure through drinking water and in residential settings, but does not include occupational exposure...

26 CFR 1.613-2 - Percentage depletion rates.

Science.gov (United States)

2010-04-01

.... Clay, refractory and fire. 6 Diatomaceous earth. Dolomite. Fedlspar. Flake Graphite. 5 Applicable only... dimension stone or ornamental stone. Fluorspar Fullers earth. Barnet. Gilsonite. Granite Lepidolite...). (ii) Clay, refractory and fire—Clay which has a pyrometric cone equivalent of 19 or higher. (iii...

Courtland Target Assembly Facility Environmental Assessment

Science.gov (United States)

2006-10-01

Draft Environmental Assessment 2-17 tributyl phosphate (TBP)6, diatomaceous earth, talcum powder, cornmeal , water, steel, and plastic. 2.2.2... cornmeal , water, steel, and plastic that would not qualify as hazardous materials. TBP is non-explosive, non-flammable, and stable under normal

Uranium distribution in Baikal sediments using SSNTD method for paleoclimate reconstruction

CERN Document Server

Zhmodik, S M; Nemirovskaya, N A; Zhatnuev, N S

1999-01-01

First data on local distribution of uranium in the core of Lake Baikal floor sediments (Academician ridge, VER-95-2, St 3 BC, 53 deg. 113'12'N/108 deg. 25'01'E) are presented in this paper. They have been obtained using (n,f)-radiography. Various forms of U-occurrence in floor sediments are shown, i.e. evenly disseminated, associated with clayey and diatomaceous components; micro- and macroinclusions of uranium bearing minerals - microlocations with uranium content 10-50 times higher than U-concentrations associated with clayey and diatomaceous components. Relative and absolute U-concentration can be determined for every mineral. Signs of various order periodicity of U-distribution in the core of Lake Baikal floor sediments have been found. Using (n,f)-radiography method of the study of Baikal floor sediment permits gathering of new information that can be used at paleoclimate reconstruction.

Origin of allochthonous limestone bodies of the miocene Megami formation, Kakegawa district, Shizuoka prefecture. Shizuokaken Kakegawa chiiki no chushinto megamiso ni fukumareru ichisei sekkaigan gantai no kigen

Energy Technology Data Exchange (ETDEWEB)

Nakamori, T; Iryu, Y; Mori, K [Tohoku Univ., Sendai (Japan). Faculty of Science; Sasazawa, K [The Yomiuri Shimbun, Sendai (Japan). Tohoku General Bureau

1991-12-15

The Tertiary limestone bodies represented by Megami Hill and Ogami Hill are distributed in the Kakegawa district in the central portion of Shizuoka Prefecture, these limestone bodies are those originated from coral reefs and are contained in the Megami formation composed of sandstone, mudstone and tuff. However, concerning the limestone bodies of the Megami formation, there are, inter alia, the opinion that they are coral reef sediments on the spot and the opinion that they are foreign rocks, but neither has any firm concrete supporting evidence. In this paper, the sedimentation ages and the sedimentary locations of limestone and sandstone {center dot} mudstone composing the Megami formation were classified and the process, through which limestone was transformed up to its state now observed, was studied. The above study was done by a detailed survey of local rock facies, comparison of age of each rock facies through detection of reference fossils and other measures. A part of the conclusion is shown below: The limestone bodies of the Megami formation is discontinuous with the surrounding sandstone {center dot} mudstone and their strike dip is not harmonious. These limestone bodies are allochthonous rock blocks which collapsed after their sedimentation and mixed with the deep sea sediments (sandstone and mudstone). 37 refs., 4 figs., 4 tabs.

Butanol/Gasoline Test Plan

Science.gov (United States)

2012-03-01

authorities. METHODS FOR CLEANING UP: Contain spillage and then collect with non-combustible absorbent material, (e.g. sand, soil , diatomaceous earth...SARA 311/312 Hazards: Fire Hazard, Acute Health Hazard, and Chronic Health Hazard CERCLA SECTION 103 and SARA SECTION 304 (RELEASE TO THE ENVIROMENT

Volatile and Organic Compositions of Sedimentary Rocks in Yellowknife Bay, Gale Crater, Mars

Science.gov (United States)

Ming, D. W.; Archer, P. D.; Glavin, D. P.; Eigenbrode, J. L.; Franz, H. B.; Sutter, B.; Brunner, A. E.; Stern, J. C.; Freissinet, C.; McAdam, A. C.; Mahaffy, P. R.; Cabane, M.; Coll, P.; Campbell, J. L.; Atreya, S. K.; Niles, P. B.; Bell, J. F.; Bish, D. L.; Brinckerhoff, W. B.; Buch, A.; Conrad, P. G.; Des Marais, D. J.; Ehlmann, B. L.; Fairén, A. G.; Farley, K.; Flesch, G. J.; Francois, P.; Gellert, R.; Grant, J. A.; Grotzinger, J. P.; Gupta, S.; Herkenhoff, K. E.; Hurowitz, J. A.; Leshin, L. A.; Lewis, K. W.; McLennan, S. M.; Miller, K. E.; Moersch, J.; Morris, R. V.; Navarro-González, R.; Pavlov, A. A.; Perrett, G. M.; Pradler, I.; Squyres, S. W.; Summons, R. E.; Steele, A.; Stolper, E. M.; Sumner, D. Y.; Szopa, C.; Teinturier, S.; Trainer, M. G.; Treiman, A. H.; Vaniman, D. T.; Vasavada, A. R.; Webster, C. R.; Wray, J. J.; Yingst, R. A.; Kemppinen, Osku; Bridges, Nathan; Johnson, Jeffrey R.; Minitti, Michelle; Cremers, David; Edgar, Lauren; Farmer, Jack; Godber, Austin; Wadhwa, Meenakshi; Wellington, Danika; McEwan, Ian; Newman, Claire; Richardson, Mark; Charpentier, Antoine; Peret, Laurent; King, Penelope; Blank, Jennifer; Weigle, Gerald; Schmidt, Mariek; Li, Shuai; Milliken, Ralph; Robertson, Kevin; Sun, Vivian; Baker, Michael; Edwards, Christopher; Ehlmann, Bethany; Griffes, Jennifer; Newcombe, Megan; Pilorget, Cedric; Rice, Melissa; Siebach, Kirsten; Stack, Katie; Brunet, Claude; Hipkin, Victoria; Léveillé, Richard; Marchand, Geneviève; Sánchez, Pablo Sobrón; Favot, Laurent; Cody, George; Flückiger, Lorenzo; Lees, David; Nefian, Ara; Martin, Mildred; Gailhanou, Marc; Westall, Frances; Israël, Guy; Agard, Christophe; Baroukh, Julien; Donny, Christophe; Gaboriaud, Alain; Guillemot, Philippe; Lafaille, Vivian; Lorigny, Eric; Paillet, Alexis; Pérez, René; Saccoccio, Muriel; Yana, Charles; Armiens-Aparicio, Carlos; Rodríguez, Javier Caride; Blázquez, Isaías Carrasco; Gómez, Felipe Gómez; Gómez-Elvira, Javier; Hettrich, Sebastian; Malvitte, Alain Lepinette; Jiménez, Mercedes Marín; Martínez-Frías, Jesús; Martín-Soler, Javier; Martín-Torres, F. Javier; Jurado, Antonio Molina; Mora-Sotomayor, Luis; Caro, Guillermo Muñoz; López, Sara Navarro; Peinado-González, Verónica; Pla-García, Jorge; Manfredi, José Antonio Rodriguez; Romeral-Planelló, Julio José; Fuentes, Sara Alejandra Sans; Martinez, Eduardo Sebastian; Redondo, Josefina Torres; Urqui-O'Callaghan, Roser; Mier, María-Paz Zorzano; Chipera, Steve; Lacour, Jean-Luc; Mauchien, Patrick; Sirven, Jean-Baptiste; Manning, Heidi; Hayes, Alexander; Joseph, Jonathan; Sullivan, Robert; Thomas, Peter; Dupont, Audrey; Lundberg, Angela; Melikechi, Noureddine; Mezzacappa, Alissa; DeMarines, Julia; Grinspoon, David; Reitz, Günther; Prats, Benito; Atlaskin, Evgeny; Genzer, Maria; Harri, Ari-Matti; Haukka, Harri; Kahanpää, Henrik; Kauhanen, Janne; Kemppinen, Osku; Paton, Mark; Polkko, Jouni; Schmidt, Walter; Siili, Tero; Fabre, Cécile; Wilhelm, Mary Beth; Poitrasson, Franck; Patel, Kiran; Gorevan, Stephen; Indyk, Stephen; Paulsen, Gale; Schieber, Juergen; Gondet, Brigitte; Langevin, Yves; Geffroy, Claude; Baratoux, David; Berger, Gilles; Cros, Alain; d'Uston, Claude; Forni, Olivier; Gasnault, Olivier; Lasue, Jérémie; Lee, Qiu-Mei; Maurice, Sylvestre; Meslin, Pierre-Yves; Pallier, Etienne; Parot, Yann; Pinet, Patrick; Schröder, Susanne; Toplis, Mike; Lewin, Éric; Brunner, Will; Heydari, Ezat; Achilles, Cherie; Oehler, Dorothy; Coscia, David; Israël, Guy; Dromart, Gilles; Robert, François; Sautter, Violaine; Le Mouélic, Stéphane; Mangold, Nicolas; Nachon, Marion; Stalport, Fabien; Raulin, François; Cameron, James; Clegg, Sam; Cousin, Agnès; DeLapp, Dorothea; Dingler, Robert; Jackson, Ryan Steele; Johnstone, Stephen; Lanza, Nina; Little, Cynthia; Nelson, Tony; Wiens, Roger C.; Williams, Richard B.; Jones, Andrea; Kirkland, Laurel; Baker, Burt; Cantor, Bruce; Caplinger, Michael; Davis, Scott; Duston, Brian; Edgett, Kenneth; Fay, Donald; Hardgrove, Craig; Harker, David; Herrera, Paul; Jensen, Elsa; Kennedy, Megan R.; Krezoski, Gillian; Krysak, Daniel; Lipkaman, Leslie; Malin, Michael; McCartney, Elaina; McNair, Sean; Nixon, Brian; Posiolova, Liliya; Ravine, Michael; Salamon, Andrew; Saper, Lee; Stoiber, Kevin; Supulver, Kimberley; Van Beek, Jason; Van Beek, Tessa; Zimdar, Robert; French, Katherine Louise; Iagnemma, Karl; Miller, Kristen; Goesmann, Fred; Goetz, Walter; Hviid, Stubbe; Johnson, Micah; Lefavor, Matthew; Lyness, Eric; Breves, Elly; Dyar, M. Darby; Fassett, Caleb; Blake, David F.; Bristow, Thomas; Edwards, Laurence; Haberle, Robert; Hoehler, Tori; Hollingsworth, Jeff; Kahre, Melinda; Keely, Leslie; McKay, Christopher; Wilhelm, Mary Beth; Bleacher, Lora; Choi, David; Dworkin, Jason P.; Floyd, Melissa; Garvin, James; Harpold, Daniel; Jones, Andrea; Martin, David K.; Raaen, Eric; Smith, Michael D.; Tan, Florence; Meyer, Michael; Posner, Arik; Voytek, Mary; Anderson, Robert C.; Aubrey, Andrew; Beegle, Luther W.; Behar, Alberto; Blaney, Diana; Brinza, David; Calef, Fred; Christensen, Lance; Crisp, Joy A.; DeFlores, Lauren; Feldman, Jason; Feldman, Sabrina; Jun, Insoo; Keymeulen, Didier; Maki, Justin; Mischna, Michael; Morookian, John Michael; Parker, Timothy; Pavri, Betina; Schoppers, Marcel; Sengstacken, Aaron; Simmonds, John J.; Spanovich, Nicole; Juarez, Manuel de la Torre; Yen, Albert; Cucinotta, Francis; Jones, John H.; Rampe, Elizabeth; Nolan, Thomas; Fisk, Martin; Radziemski, Leon; Barraclough, Bruce; Bender, Steve; Berman, Daniel; Dobrea, Eldar Noe; Tokar, Robert; Williams, Rebecca M. E.; Cleghorn, Timothy; Huntress, Wesley; Manhès, Gérard; Hudgins, Judy; Olson, Timothy; Stewart, Noel; Sarrazin, Philippe; Vicenzi, Edward; Wilson, Sharon A.; Bullock, Mark; Ehresmann, Bent; Hamilton, Victoria; Hassler, Donald; Peterson, Joseph; Rafkin, Scot; Zeitlin, Cary; Fedosov, Fedor; Golovin, Dmitry; Karpushkina, Natalya; Kozyrev, Alexander; Litvak, Maxim; Malakhov, Alexey; Mitrofanov, Igor; Mokrousov, Maxim; Nikiforov, Sergey; Prokhorov, Vasily; Sanin, Anton; Tretyakov, Vladislav; Varenikov, Alexey; Vostrukhin, Andrey; Kuzmin, Ruslan; Clark, Benton; Wolff, Michael; Botta, Oliver; Drake, Darrell; Bean, Keri; Lemmon, Mark; Schwenzer, Susanne P.; Anderson, Ryan B.; Lee, Ella Mae; Sucharski, Robert; Hernández, Miguel Ángel de Pablo; Ávalos, Juan José Blanco; Ramos, Miguel; Kim, Myung-Hee; Malespin, Charles; Plante, Ianik; Muller, Jan-Peter; Ewing, Ryan; Boynton, William; Downs, Robert; Fitzgibbon, Mike; Harshman, Karl; Morrison, Shaunna; Dietrich, William; Kortmann, Onno; Palucis, Marisa; Williams, Amy; Lugmair, Günter; Wilson, Michael A.; Rubin, David; Jakosky, Bruce; Balic-Zunic, Tonci; Frydenvang, Jens; Jensen, Jaqueline Kløvgaard; Kinch, Kjartan; Koefoed, Asmus; Madsen, Morten Bo; Stipp, Susan Louise Svane; Boyd, Nick; VanBommel, Scott; Jacob, Samantha; Owen, Tobias; Rowland, Scott; Atlaskin, Evgeny; Savijärvi, Hannu; Boehm, Eckart; Böttcher, Stephan; Burmeister, Sönke; Guo, Jingnan; Köhler, Jan; García, César Martín; Mueller-Mellin, Reinhold; Wimmer-Schweingruber, Robert; Bridges, John C.; McConnochie, Timothy; Benna, Mehdi; Bower, Hannah; Blau, Hannah; Boucher, Thomas; Carmosino, Marco; Elliott, Harvey; Halleaux, Douglas; Rennó, Nilton; Wong, Michael; Pepin, Robert; Elliott, Beverley; Spray, John; Thompson, Lucy; Gordon, Suzanne; Newsom, Horton; Ollila, Ann; Williams, Joshua; Vasconcelos, Paulo; Bentz, Jennifer; Nealson, Kenneth; Popa, Radu; Kah, Linda C.; Tate, Christopher; Day, Mackenzie; Kocurek, Gary; Hallet, Bernard; Sletten, Ronald; Francis, Raymond; McCullough, Emily; Cloutis, Ed; ten Kate, Inge Loes; Kuzmin, Ruslan; Arvidson, Raymond; Fraeman, Abigail; Scholes, Daniel; Slavney, Susan; Stein, Thomas; Ward, Jennifer; Berger, Jeffrey; Moores, John E.

2014-01-01

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

In Situ Radiometric and Exposure Age Dating of the Martian Surface

Science.gov (United States)

Farley, K. A.; Malespin, C.; Mahaffy, P.; Grotzinger, J. P.; Vasconcelos, P. M.; Milliken, R. E.; Malin, M.; Edgett, K. S.; Pavlov, A. A.; Hurowitz, J. A.;

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale crater, Mars

Science.gov (United States)

Ming, D. W.; Archer, P.D.; Glavin, D.P.; Eigenbrode, J.L.; Franz, H.B.; Sutter, B.; Brunner, A.E.; Stern, J.C.; Freissinet, C.; McAdam, A.C.; Mahaffy, P.R.; Cabane, M.; Coll, P.; Campbell, J.L.; Atreya, S.K.; Niles, P.B.; Bell, J.F.; Bish, D.L.; Brinckerhoff, W.B.; Buch, A.; Conrad, P.G.; Des Marais, D.J.; Ehlmann, B.L.; Fairén, A.G.; Farley, K.; Flesch, G.J.; Francois, P.; Gellert, Ralf; Grant, J. A.; Grotzinger, J.P.; Gupta, S.; Herkenhoff, K. E.; Hurowitz, J.A.; Leshin, L.A.; Lewis, K.W.; McLennan, S.M.; Miller, Karl E.; Moersch, J.; Morris, R.V.; Navarro- González, R.; Pavlov, A.A.; Perrett, G.M.; Pradler, I.; Squyres, S. W.; Summons, Roger E.; Steele, A.; Stolper, E.M.; Sumner, D.Y.; Szopa, C.; Teinturier, S.; Trainer, M.G.; Treiman, A.H.; Vaniman, D.T.; Vasavada, A.R.; Webster, C.R.; Wray, J.J.; Yingst, R.A.

2014-01-01

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale crater, Mars.

Science.gov (United States)

Ming, D W; Archer, P D; Glavin, D P; Eigenbrode, J L; Franz, H B; Sutter, B; Brunner, A E; Stern, J C; Freissinet, C; McAdam, A C; Mahaffy, P R; Cabane, M; Coll, P; Campbell, J L; Atreya, S K; Niles, P B; Bell, J F; Bish, D L; Brinckerhoff, W B; Buch, A; Conrad, P G; Des Marais, D J; Ehlmann, B L; Fairén, A G; Farley, K; Flesch, G J; Francois, P; Gellert, R; Grant, J A; Grotzinger, J P; Gupta, S; Herkenhoff, K E; Hurowitz, J A; Leshin, L A; Lewis, K W; McLennan, S M; Miller, K E; Moersch, J; Morris, R V; Navarro-González, R; Pavlov, A A; Perrett, G M; Pradler, I; Squyres, S W; Summons, R E; Steele, A; Stolper, E M; Sumner, D Y; Szopa, C; Teinturier, S; Trainer, M G; Treiman, A H; Vaniman, D T; Vasavada, A R; Webster, C R; Wray, J J; Yingst, R A

2014-01-24

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and amorphous materials. Thermal decomposition of carbonates and combustion of organic materials are candidate sources for the CO2. Concurrent evolution of O2 and chlorinated hydrocarbons suggests the presence of oxychlorine phase(s). Sulfides are likely sources for sulfur-bearing species. Higher abundances of chlorinated hydrocarbons in the mudstone compared with Rocknest windblown materials previously analyzed by Curiosity suggest that indigenous martian or meteoritic organic carbon sources may be preserved in the mudstone; however, the carbon source for the chlorinated hydrocarbons is not definitively of martian origin.

Geomechanical and petrophysical properties of mudrocks: introduction

OpenAIRE

Rutter, Ernest

2017-01-01

Mudstones (shales) are of particular importance as the source rocks for oil and gas, and increasingly so as the reservoirs for unconventional hydrocarbons. They are also the most common sedimentary rocks on Earth, and, hence, are frequently encountered in excavations and foundations for buildings. These factors point to a pressing need to develop an increased fundamental understanding of their geomechanical and petrophysical properties. The mineral content of mudstones has a dominant effect o...

76 FR 64384 - Petitions for Modification of Application of Existing Mandatory Safety Standards

Science.gov (United States)

2011-10-18

..., commonly called ``beer'', to be used at the Lompoc Plant for use in chemical testing that is part of... agent utilized during the brewing process for beer. The finished diatomaceous earth products are... the brewing process, following fermentation, which results in the creation of the alcohol- containing...

40 CFR 141.173 - Filtration.

Science.gov (United States)

2010-07-01

... PRIMARY DRINKING WATER REGULATIONS Enhanced Filtration and Disinfection-Systems Serving 10,000 or More People § 141.173 Filtration. A public water system subject to the requirements of this subpart that does... treatment, direct filtration, slow sand filtration, or diatomaceous earth filtration. A public water system...

Detection of mineral impurities in diatomite ores

NARCIS (Netherlands)

Guatame Garcia, L.A.; Buxton, M.W.N.; Fiore, Saverio

2017-01-01

Diatomaceous Earth (DE) is commonly used in the industry for the manufacturing of filters, where diatomite is preferred due to its low chemical reactivity and high porosity. Diatomite deposits with major amounts of mineral impurities, such as carbonates, present a problem in the production DE. In

Particulate collection in a low level radioactive waste incinerator

International Nuclear Information System (INIS)

Rudnick, S.N.; Leith, D.; First, M.W.

1976-01-01

As designed, sintered stainless steel filters will clean the gas from the secondary cyclone at a low level radioactive waste incinerator. Using bench scale apparatus, asbestos floats and diatomaceous earth were evaluated as filter aids to prevent clogging of the sintered metal interstices and to decrease filter penetration. Both precoats prevented irreversible pressure drop increase, and decreased cold DOP penetration from 80% to less than 1%. To collect the same quantity of fly ash, less diatomaceous earth was needed than asbestos floats. A back-up study evaluated a moving bed of sodium carbonate pellets in lieu of the sintered metal filters. Since identical sodium carbonate pellets are used to neutralize hydrogen chloride in the incinerator, their use in a moving bed has the advantages of trouble free disposal and cost free replacement. Co, counter, and cross-current beds were studied and gave fly ash penetrations less than 0.1% at moderate pressure drop

Mineral composition and geochemistry of the Upper Cretaceous siliciclastics (Nubia Group), Aswan District, south Egypt: Implications for provenance and weathering

Science.gov (United States)

Hassan, Abdallah M.

2017-11-01

The Upper-Cretaceous clastic succession (Nubia Group) in the area northeast of Aswan includes three rock units, from base upwards: Abu Aggag Formation (Turonian), Timsah Formation (Coniacian -Santonian) and Um Barmil Formation (Santonian - Campanian). Quartz and clay minerals are the predominant phases throughout the whole succession while feldspars are very rare. Kaolinite is overwhelming among the clay minerals, in addition to less important amounts of illite and illite/smectite. The ultrastable heavy minerals are the prevailing non- opaque phases and they significantly change in relative abundance upsection. SiO2, Al2O3 and Fe2O3 are the dominant chemical components. The statistical examination had revealed that the chemical constituents are loaded on three main geochemical trends; the siliceous, the argillaceous and the ferruginous. The enrichment factor shows that the geochemical behavior of the major and trace elements is uniform throughout the sandstones and mudstones of the Abu Aggag Formation. A significant geochemical contrast is documented between the sandstones and mudstones of both the Timsah and the Um Barmil formations. The provenance - critical elemental ratios Ti/Nb and Ti/Y are nearly constant throughout the sandstones and mudstones of the Abu Aggag Formation, and they fall within the range of granitic-granodioritic composition. The Timsah sandstones have Ti/Nb and Ti/Y ratios that are consistent with those of the Abu Aggag rocks, suggesting a similar provenance. These elemental ratios are extremely higher in the Timsah mudstones, reflecting a great influx of mafic material. The Um Barmil sandstones exhibit exceedingly dispersed values of Ti/Nb and Ti/Y, reflecting their derivation from large catchment's areas of different rock types with the eroded products being mixed in various relative proportions. The Ti/Nb and Ti/Y of the Um Barmil mudstones are closely akin to those of the Timsah mudstones suggesting analogous source. The chemical index of

75 FR 28488 - Silver Nitrate; Exemption from the Requirement of a Tolerance

Science.gov (United States)

2010-05-21

... ( regulations.gov ) under the docket number EPA-HQ-OPP- 2009-0663. Silver nitrate is a water soluble inorganic... polymers and fatty acids; carriers such as clay and diatomaceous earth; thickeners such as carrageenan and... for which there is reliable information.'' This includes exposure through drinking water and in...

The Mineralogical and Chemical Case for Habitability at Yellowknife Bay, Gale Crater, Mars

Science.gov (United States)

Blake, David Frederick; Vaniman, David; Grotzinger, John P.; Conrad, Pamela Gales; Ming, Douglas W.; Bish, David L.; Farmer, Jack D.; Bristow, Thomas

2013-01-01

Sediments of the Yellowknife Bay formation (Gale crater) include the Sheepbed member, a mudstone cut by light-toned veins. Two drill samples, John Klein and Cumberland, were collected and analyzed by the CheMin XRD/XRF instrument and the Sample Analysis at Mars (SAM) evolved gas and isotopic analysis suite of instruments. Drill cuttings were also analyzed by the Alpha Particle X-ray Spectrometer (APXS) for bulk composition. The CheMin XRD analysis shows that the mudstone contains basaltic minerals (Fe-forsterite, augite, pigeonite, plagioclase), as well as Fe-oxide/hydroxides, Fe-sulfides, amorphous materials, and trioctahedral phyllosilicates. SAM evolved gas analysis of higher-temperature OH matches the CheMin XRD estimate of 20% clay minerals in the mudstone. The light-toned veins contain Ca-sulfates; anhydrite and bassanite are detected by XRD but gypsum is also indicated from Mastcam spectral mapping. These sulfates appear to be almost entirely restricted to late-diagenetic veins. The sulfate content of the mudstone matrix itself is lower than other sediments analyzed on Mars. The presence of phyllosilicates indicates that the activity of water was high during their formation and/or transport and deposition (should they have been detrital). Lack of chlorite places limits on the maximum temperature of alteration (likely habitable environment: Aqueous deposition at clement conditions of P, T, pH, Eh and ionic strength, plus the availability of sources of chemical energy.

Use of diatomaceous to liquid organic wastes adsorption

International Nuclear Information System (INIS)

Sanhueza M, Azucena; Padilla S, Ulises

1999-01-01

Background: One of the radioactive wastes that the Radioactive Wastes Management Unit must process are organic liquids from external generators and from sections of the Chilean Nuclear Energy Commission (CCHEN). The wastes from external generators contain H 3 and C 14; while the wastes from the CCHEN are contaminated with uranium. The total volume of liquid organic wastes that must be treated is 5 m3. The options recommended for processing these wastes are incineration or the adsorption of the organic liquid by some adsorbing medium and its subsequent immobilization in cement molds. Due to the cost of incineration, the adsorption method was chosen for study. Objective: To find the optimum amount of adsorbent to be saturated with radioactive organic liquid from liquid scintillation and to study immobilization in cement molds. Methodology: Adsorption granulated (1568 Merck) and diatom earth were tested as adsorbent mediums. The adsorbents were mixed in different ratios of volume with the organic liquid. Then the waste was mixed with different water/cement ratios to define the best immobilization conditions. Conclusions: The tests carried out with 2 adsorbents recommended in the literature and available in the CCHEN show that as adsorbent waste ratio decreases, the percentage of liquid adsorbed increases, as expected: a greater volume of adsorbent retains a greater quantity of liquid, with an increase in the final volume, depending on the adsorbent used. Of these adsorbents, the diatom earth was better for treating liquid organic wastes. It had 100% adsorption and an increased volume of 0%, which is more than enough from the volumetric point of view of waste management. The ratio 0.8 liquid/adsorbent also showed good characteristics, but more study is needed to decide on the above, since liquid remains to be adsorbed. This work must continue to study the repeatability of results, to obtain physical and radiological characteristics for the immobilized products and to carry out tests to scale, in order to contain the organic liquids that await treatment

Pest control in stored products using diatomaceous earth

Directory of Open Access Journals (Sweden)

Fetyukhina E.G.

2017-05-01

Full Text Available in the All-Russian Plant Quarantine Center the DEBUZZZER, dried diatomite powder of light beige color, has been presented by the Diamix Company for official testing in order to obtain the state registration of the Ministry of Agriculture. This article presents the results of laboratory studies of the DEBUZZZER preparation based on the diatomite against pests of stocks while processing wheat grain. It also shows the effectiveness of the DEBUZZZER against adult species of grain and rice weevils, their total death occurred on the 6th and 14th days accordingly, and the weight loss was up to 50%. The authors present the susceptibility to this drug by the imago of large and small meal worm, which was used to process the grain, and it caused 100% mortality on the 6th and 14th days and a decrease in the weight of test objects by 41.8 and 60.6%, accordingly. The vital activity of the larvae of the yellow mealworm beetle has decreased as a result of weight loss by 41.8%. However, the larvae remained viable and developed till pupal stage and imago despite weight loss, and death was indicated in only 6.7% of the species. The DEBUZZZER diatom powder implementation was not effective enough against the larvae of two species of Trogodermaspp.: khapra beetle and warehouse beetle, their mortality was 11.7 and 3.3% on the 20th day, accordingly. According to the authors, more frequent processing of the stored products is necessary for successful pest control.

Tratamento inseticida e qualidade de sementes de milho durante o armazenamento Insecticide treatment and seed quality of corn during storage

Directory of Open Access Journals (Sweden)

Oscar José Smiderle

1999-01-01

Full Text Available A presente pesquisa objetivou verificar os efeitos dos inseticidas deltametrina, clorpirifos, fosfina e da terra diatomácea no controle de insetos em sementes de milho, armazenadas durante 12 meses, visando oferecer alternativas de produtos inseticidas, utilizando delineamento inteiramente casualizado. As sementes do híbrido AG 303, tratadas com deltametrina e clorpirifos, aplicados na forma isolada ou em combinação, fosfina e terra diatomácea, foram acondicionadas em sacos de papel multifoliado e armazenadas por doze meses (maio/1997 a abril/1998 em condições normais de ambiente. Em intervalos bimestrais, sete épocas no total, as sementes foram submetidas às seguintes determinações: exame de sementes infestadas, massa de 100 sementes, teste de germinação, teste de frio, envelhecimento acelerado, condutividade elétrica, emergência de plântulas em campo e velocidade de emergência de plântulas. A análise dos dados e interpretação dos resultados permitiram concluir que: os inseticidas deltametrina e clorpirifos (isolados ou associados, a terra diatomácea e a fosfina promovem, de maneira similar, o controle de insetos-praga que ocorrem no armazenamento e não causam toxicidade às sementes; a qualidade fisiológica das sementes é efetivamente preservada pelos tratamentos com inseticidas químicos e terra diatomácea.To study the effects of insecticides (deltamethrin, chlorpyrifos, phosphin, and diatomaceous earth on the insect control of stored corn seeds during 12 months, this research was performed to find an alternative product, using a randomized design. Seeds of the hybrid AG 303 were treated with either isolated or combined deltamethrin and chlorpyrifos, phosphin and diatomaceous earth, and they were further arranged into multifoliated paper bags and stored for twelve months (May/1997 through April/1998 under normal environmental conditions. Seeds were submitted to an infested seed exam, mass of 100 seeds, germination

Concepts for backfilling and sealing of shafts

International Nuclear Information System (INIS)

Pierau, B.

1990-01-01

The disposal site is situated at a depth of 1000 to 1200 meters. It is covered by very thick cretatious mudstone layers forming the main barrier against the spread of radioactively contaminated water into the biosphere. Because of the excavation works and the resulting stress redistributions, the material surrounding the shafts is probably broken up, which leads to increased permeability in comparison with the intact rock. It is planned to backfill the shafts with an insoluble mineral mixture including a fine fraction necessary to achieve the sealing required. The joints and cracks in the brocken-up surrounding material are believed to be sealed by themselves due to swelling of the mudstone. Some strata of the mudstone contain more than 20% of smektite, a swelling clay mineral. Those regions, where the broken-up zone cannot be considered sure to self-seal due to swelling, are planned to be sealed by pressure grouting using clay suspension. (orig./HP) [de

High Solids Consolidated Incinerator Facility (CIF) Wastes Stabilization with Ceramicrete and Super Cement

International Nuclear Information System (INIS)

Walker, B.W.

1999-01-01

High Solids ash and scrubber solution waste streams were generated at the incinerator facility at SRS by burning radioactive diatomaceous filter rolls which contained small amounts of uranium, and listed solvents (F and U). This report details solidification activities using selected Mixed Waste Focus Area (MWFA) technologies with the High Solids waste streams

EFFECT OF DIATOMEAOUS EARTH TREATMENT USING HYDROGEN CHLORIDE AND SULFURIC ACID ON KINETICS OF CADMIUM(II ADSORPTION

Directory of Open Access Journals (Sweden)

Nuryono Nuryono

2010-06-01

Full Text Available In this research, treatment of diatomaceous earth, Sangiran, Central Java using hydrogen chloride (HCl and sulfuric acid (H2SO4 on kinetics of Cd(II adsorption in aqueous solution has been carried out. The work was conducted by mixing an amount of grounded diatomaceous earth (200 mesh in size with HCl or H2SO4 solution in various concentrations for two hours at temperature range of 100 - 150oC. The mixture was then filtered and washed with water until the filtrate pH is approximately 7 and then the residue was dried for four hours at a temperature of 70oC. The product was used as an adsorbent to adsorb Cd(II in aqueous solution with various concentrations. The Cd(II adsorbed was determined by analyzing the rest of Cd(II in the solution using atomic absorption spectrophotometry. The effect of treatment was evaluated from kinetic parameter of adsorption rate constant calculated based on the simple kinetic model. Results showed  that before equilibrium condition reached, adsorpstion of Cd(II occurred through two steps, i.e. a step tends to follow a reaction of irreversible first order  (step I followed by reaction of reversible first order (step II. Treatment with acids, either hydrogen chloride or sulfuric acid, decreased adsorption rate constant for the step I from 15.2/min to a range of 6.4 - 9.4/min.  However, increasing concentration of acid (in a range of concentration investigated did not give significant and constant change of adsorption rate constant. For step II process,  adsorption involved physical interaction with the sufficient low adsorption energy (in a range of 311.3 - 1001 J/mol.     Keywords: adsorption, cdmium, diatomaceous earth, kinetics.

Removal of hydrogen sulfide (H2S) from biogas for the community in the province of Maha Sarakham

Science.gov (United States)

Pinate, W.; Dangphonthong, D.; Sirirach, S.; Sukkhon, S.

2017-09-01

Biogas produced from the fermentation in the province of Maha Sarakham of excreta from cow dung, fattening pigs and buffalo dung in small scale farms contained hydrogen sulfide (H2S) at 764, 926 and 1,103 ppm, respectively. This gas has offensive smell and is corrosive to motor and metal stove of farmers, thus needs to be eliminated. The adsorbent granules soaking in FeCl3 and NaOH made from grey cement mixed with diatomaceous earth or fine sand. The experiment cow dung, fattening pigs and buffalo dung farms revealed that the adsorbent granules made from fine sand mixed with grey cement had better efficiency in reducing H2S than diatomaceous earth plus grey cement or scrap iron (97.1-91.4 vs. 86.0-64.3 and 77.9-89.4%, Pbiogas from 3,141 to 0 ppm in the first day and to 6 ppm on day 25 of using period, during which the colour of adsorbent granules changed from red brown to dark brown.

Particulate collection in a low level radioactive waste incinerator

International Nuclear Information System (INIS)

Rudnick, S.N.; Leith, D.; First, M.W.

1976-01-01

As designed, sintered stainless steel filters will clean the gas from the secondary cyclone at a low level radioactive waste incinerator. Bench-scale apparatus was used to evaluate asbestos floats and diatomaceous earth as filter aids to prevent clogging of the sintered metal interstices and to decrease filter penetration. Both precoats prevented irreversible pressure drop increase, and decreased cold DOP penetration from 80 percent to less than 1 percent. Less diatomaceous earth was needed than asbestos floats, to collect the same quantity of fly ash. A back-up study evaluated a moving bed of sodium carbonate pellets in lieu of the sintered metal filters. Since identical sodium carbonate pellets are used to neutralize hydrogen chloride in the incinerator, their use in a moving bed has the advantages of trouble free disposal and cost free replacement. Co - , counter, and cross-current beds were studied and gave fly ash penetrations less than 0.1 percent at moderate pressure drop. The filter cake which forms on the pellet surfaces decreases penetration greatly

Facies architecture of basin-margin units in time and space: Lower to Middle Miocene Sivas Basin, Turkey

Science.gov (United States)

Çiner, A.; Kosun, E.

2003-04-01

The Miocene Sivas Basin is located within a collision zone, forming one of the largest basins in Central Turkey that developed unconformably on a foundered Paleozoic-Mesozoic basement and Eocene-Oligocene deposits. The time and space relationships of sedimentary environments and depositional evolution of Lower to Middle Miocene rocks exposed between Zara and Hafik towns is studied. A 4 km thick continuous section is subdivided into the Agilkaya and Egribucak Formations. Each formation shows an overall fining upward trend and contains three members. Although a complete section is present at the western part (near Hafik) of the basin, to the east the uppermost two members (near Zara) are absent. The lower members of both formations are composed of fluvial sheet-sandstone and red mudstone that migrate laterally on a flood basin within a semi-arid fan system. In the Agilkaya Formation that crops out near Zara, alluvial fans composed of red-pink volcanic pebbles are also present. The middle members are composed of bedded to massive gypsum and red-green mudstone of a coastal and/or continental sabkha environment. While the massive gypsum beds reach several 10’s of m in Hafik area, near Zara, they are only few m thick and alternate with green mudstones. In Hafik, bedded gypsums are intercalated with lagoonal dolomitic limestone and bituminous shale in the Agilkaya Formation and with fluvial red-pink sandstone-red mudstone in the Egribucak Formation. The upper members are made up of fossiliferous mudstone and discontinuous sandy limestone beds with gutter casts, HCS, and 3-D ripples. They indicate storm-induced sedimentation in a shallow marine setting. The disorganized accumulations of ostreid and cerithiid shells, interpreted as coquina bars, are the products of storm generated reworking processes in brackish environments. Rapid vertical and horizontal facies changes and the facies associations in both formations reflect the locally subsiding nature of this molassic

Gas storage in the Upper Devonian-Lower Mississippian Woodford Shale, Arbuckle Mountains, Oklahoma: how much of a role do the cherts play?

Science.gov (United States)

Fishman, Neil S.; Ellis, Geoffrey S.; Paxton, Stanley T.; Abbott, Marvin M.; Boehlke, Adam

2010-01-01

How gas is stored in shale-gas systems is a critical element in characterizing these potentially prolific, low-porosity/permeability reservoirs. An integrated mineralogic, geochemical, and porosity/permeability study is of the Upper Devonian-Lower Mississippian Woodford Shale, Arbuckle Mountains, southern Oklahoma, at locations previously described through detailed stratigraphic and spectral gamma surveys, was undertaken to provide insights into possible mechanisms by which natural gas might be stored in Woodford reservoirs in the adjacent Anadarko Basin. The outcrops in the Arbuckle Mountains are an ideal location to study the Woodford because here the formation is immature or marginally mature for oil generation (Comer and Hinch, 1987; Lewan, 1987), so deep burial and thermal maturation are much less pronounced than is the case for the Woodford in the basin, and as such the samples we studied are not overprinted by possible alterations resulting from deep burial and heating. Rock types studied in the Woodford Shale are broadly divided into chert (n = 8) and mudstone (n = 10) lithologies that display different characteristics from the outcrop to thin section scales. Woodford cherts, based on quantitative X-ray diffraction (XRD), contain >85 weight (wt) % quartz, green algae). Quartz in mudstones is both detrital and authigenic, with unequivocal authigenic quartz occurring as monocrystalline “grains” that can partly or even completely infill Tasmanites; as in the case of the cherts, authigenic quartz in mudstones must have precipitated soon after deposition before significant burial and collapse of the soft, delicate Tasmanites cysts. MICP analyses (at 50% Hg saturation) reveal that, with one exception, mudstones have (1) porosities ranging from 1.97-6.31%, (2) low calculated permeabilities (0.011-0.089 D), and (3) small mean pore apertures (6.2-17.8 nm). Porosity in the mudstones occurs as (1) “slots” between clay mineral grains or plates, (2) micropores

Radiation effects on Fischer-Tropsch syntheses

International Nuclear Information System (INIS)

Hatada, M.; Matsuda, K.

1977-01-01

Radiation effects on Fischer-Tropsch synthesis has been examined using high dose rate electron beams and Fe-Cu-diatomaceous earth catalyst. Yields of saturated hydrocarbons were found to increase by irradiation, but the yields of these compounds were decreased by raising reaction temperature without irradiation, suggesting the presence of radiation chemical process in catalytic reactions. (author)

Application of integrated vitrinite reflectance and FAMM analyses for thermal maturity assessment of the northeastern Malay Basin, offshore Vietnam: Implications for petroleum prospectivity evaluation

DEFF Research Database (Denmark)

Petersen, H. I.; Sherwood, N.; Mathiesen, A.

2008-01-01

Several exploration wells have intersected a Cenozoic coal-bearing, fluvial-deltaic mudstone and sandstone succession in the northeastern Vietnamese part of the Malay Basin, and have successfully tested seismically identified direct hydrocarbon indicators (DHIs). The oil and gas/condensate discov......Several exploration wells have intersected a Cenozoic coal-bearing, fluvial-deltaic mudstone and sandstone succession in the northeastern Vietnamese part of the Malay Basin, and have successfully tested seismically identified direct hydrocarbon indicators (DHIs). The oil and gas...... for the uppermost Oligocene source rocks between 2Ma and present-day, which post-dates trap formation. Seismic facies patterns suggest that lacustrine oil-prone units are in he oil window in the same graben complex a few km NW of the investigated well, and these rocks are likely to be the source of the hydrocarbons....../condensate discovery ell 46-CN-1x encountered a _55m thick section of lacustrine mudstones having considerable potential as an oil source. Vitrinite reflectance (VR) measurements from these alginite-bearing rocks introduce several problems in thermal maturity evaluation, including associated VR suppression...

Hydrocarbon Source Rock Potential of the Sinamar Formation, Muara Bungo, Jambi

Directory of Open Access Journals (Sweden)

Moh. Heri Hermiyanto Zajuli

2014-07-01

Full Text Available DOI: 10.17014/ijog.v1i1.175The Oligocene Sinamar Formation consists of shale, claystone, mudstone, sandstone, conglomeratic sandstone, and intercalation of coal seams. The objective of study was to identify the hydrocarbon source rock potential of the Sinamar Formation based on geochemichal characteristics. The analyses were focused on fine sediments of the Sinamar Formation comprising shale, claystone, and mudstone. Primary data collected from the Sinamar Formation well and outcrops were analyzed according to TOC, pyrolisis analysis, and gas chromatography - mass spectometry of normal alkanes that include isoprenoids and sterane. The TOC value indicates a very well category. Based on TOC versus Pyrolysis Yields (PY diagram, the shales of Sinamar Formation are included into oil prone source rock potential with good to excellent categories. Fine sediments of the Sinamar Formation tend to produce oil and gas originated from kerogen types I and III. The shales tend to generate oil than claystone and mudstone and therefore they are included into a potential source rock. 

Morphology of channels and channel-sand bodies in the Glauconitic sandstone member (Upper Mannville), Little Bow area, Alberta

Energy Technology Data Exchange (ETDEWEB)

Hopkins, J.C.; Hermanson, S.W.; Lawton, D.C.

1982-12-01

Large channels in the Glauconitic sandstone member of southern Alberta have proved to be difficult exploration targets because of an irregular distribution of reservoir sands within the channels. In the Little Bow area, two channels are present in the lower part of the Glauconitic member and have cut into the underlying Calcareous member. The channels can be recognized where they truncate regional markers of the Calcareous member -- the Bantry shale and Ostracod limestone, and where channel-fill deposits exhibit uniform geophysical log characters, indicating sandstone- or mudstone-filled reaches. Sediments of the Glauconitic member adjacent to the channels comprise a series of splay sandstones and mudstones that prograded into interdistributary bays of the lower delta plain. The two channels associated with these deposits are interpreted as distributary channels. Sand bodies within the channels formed as lateral bars and are isolated by mudstones which mark the abandoned stream course. Geological exploration for these discontinuous channel sandstones is difficult, and high-resolutio seismic data integrated with sound geologic modelling are critical for successful prospect delineation.

Deposition and diagenesis of the Brushy Basin Member and upper part of the Westwater Canyon member of the Morrison Formation, San Juan Basin, New Mexico

International Nuclear Information System (INIS)

Bell, T.E.

1986-01-01

The Brushy Basin Member and the upper part of the Westwater Canyon Member of the Morrison Formation in northwest New Mexico are nonmarine sedimentary rocks of Late Jurassic age. This stratigraphic interval consists of as many as four lithofacies deposited in fluvial and playa-lake environments. Lithofacies A is composed of crossbed feldspathic sandstone and was deposited by braided streams on an alluvial plain. Lithofacies B is composed of crossbedded feldspathic sandstone and tuffaceous mudstone, and was deposited by braided and anastomosing streams at the distal end of the alluvial plain. Lithofacies C is composed of calcareous, tuffaceous mudstone and was deposited on a mudflat between the alluvial plain and a playa lake. Lithofacies D is composed of zeolitic, tuffaceous mudstone and was deposited in a playa lake. The distribution of diagenetic facies in mudstones and tuffs in the Brushy Basin Member and upper part of the Westwater Canyon Member reflects the pH and salinity gradients common to fluvial/playa-lake systems. The abundant vitric ash in the sediments reacted to form montmorillonite in the fluvial facies. Calcite and montmorillonite were the reaction products where the fluvial and outermost playa facies met. Vitric ash reacted to form clinoptilolite and heulandite along the playa margins. In the center of the playa facies, analcime replaced clinoptilolite, an early zeolite. These early diagenetic minerals were replaced by albite, quartz, and mixed-layer illitemontmorillonite where the Brushy Basin Member and upper part of the Westwater Canyon Member have been deeply buried in the San Juan basin

Diatomaceous Fungal and Bacterial Building Blocks for Material Synthesis

Science.gov (United States)

2008-04-08

Thalassiosira-templated metallic microshells. Thalassiosira, only 1mM rhodamine 6G (d) lmM, (e) I piM ,(f 100 nM R6G. 4 concentrations gave detectable...hybridized with a 27-mer 7 oligonucleotide containing a 7-mer TAG GAA TAG TTA TA AT OTT ATT AGO complementary region 2, which produces TAIOATCCTTA TACAATAATCC

29 CFR 1915.1000 - Air contaminants.

Science.gov (United States)

2010-07-01

... Limit calculated from the formula 250 (k) %SiO2+5 Cristobalite Amorphous, including natural diatomaceous...) 50 (or 15 mg/m3 whichever is the smaller) of total dust SiO2 Conversion factors mppcf × 35.3... 94 X Ferbam 14484-64-1 Total dust — 15 — Ferrovanadium dust 12604-58-9 — 1 — Fibrous Glass Total dust...

29 CFR 1926.55 - Gases, vapors, fumes, dusts, and mists.

Science.gov (United States)

2010-07-01

... Limit calculated from the formula 250 (k) %SiO2+5 Cristobalite Amorphous, including natural diatomaceous...) 50 (or 15 mg/m3 whichever is the smaller) of total dust SiO2 [Inert or Nuisance Dusts includes... 94 X Ferbam 14484-64-1 Total dust — 15 — Ferrovanadium dust 12604-58-9 — 1 — Fibrous Glass Total dust...

Mechanical behavior in the Nankai inner accretionary prism, IODP Site C0002

Science.gov (United States)

Valdez, R. D., II; Saffer, D. M.

2017-12-01

Understanding the processes that control seismogenesis and stress state at subduction zones requires knowledge of fault zone and sediment physical and mechanical properties. As part of the International Ocean Discovery Program (IODP) Nankai Trough Seismogenic Zone Experiment (NanTroSEIZE), Expedition 348 drilled into the Kumano forearc basin and underlying inner accretionary prism at Site C0002, located 35 km landward of the trench. One primary objective was to sample and characterize the mechanical behavior of the inner accretionary prism. Here we report on the frictional and unconfined compressive strength (UCS) of mudstone samples and a clay-rich shear zone recovered from 2182-2209 meters below sea floor (mbsf), determined from triaxial deformation tests at confining pressures from 1 to 7 MPa (UCS measurements on mudstones) and 36 MPa (strength of fault zone). Our results show that at a confining pressure of 1 MPa, the wall rock sediments fail at a peak differential stress of 9.1 MPa with a residual stress of 2.8 MPa. A clear peak and evolution to residual strength remains present at 7 MPa, and both the peak and residual strengths of the mudstones increases systematically with confining pressure. At a confining pressure of 36 MPa, the shear zone sediment yields at a differential stress of 25.2 MPa followed by strain-hardening to a maximum stress of 33.1 MPa. The shear zone is frictionally weaker than the surrounding mudstones, with a friction coefficient (μ) of 0.26-0.31, versus µ = 0.45 for the wall rock. The suite of tests defines a UCS for the mudstone of 7.9 MPa. Our friction data suggest that the inner wedge may be weaker than commonly assumed in applications of critical wedge theory to estimate the properties and conditions in accretionary prisms. One key implication is that for a given basal detachment friction coefficient, higher basal pore pressures (or lower wedge pore pressures) would be required to sustain observed taper angles. Additionally, the

Geochemical characteristics of crude oil from a tight oil reservoir in the Lucaogou Formation, Jimusar Sag, Junggar Basin

Science.gov (United States)

Cao, Z.

2015-12-01

Jimusar Sag, which lies in the Junggar Basin,is one of the most typical tight oil study areas in China. However, the properties and origin of the crude oil and the geochemical characteristics of the tight oil from the Lucaogou Formation have not yet been studied. In the present study, 23 crude oilsfrom the Lucaogou Formation were collected for analysis, such as physical properties, bulk composition, saturated hydrocarbon gas chromatography-mass spectrometry (GC-MS), and the calculation of various biomarker parameters. In addition,source rock evaluation and porosity permeability analysis were applied to the mudstones and siltstones. Biomarkers of suitable source rocks (TOC>1, S1+S2>6mg/g, 0.7%mudstones within the Lucaogou Formation contributed to oil accumulation.Crude oil from the upper and lower sections originated from thin-bedded mudstones interbedded within sweet spot sand bodies. A good coincidence of filling history and hydrocarbon generation history indicated that the Lucaogou reservoir is a typical in situ reservoir. The mudstones over or beneath the sweet spot bodies consisted of natural caprocks and prevented the vertical movement of oil by capillary forces. Despite being thicker, the thick-bedded mudstone between the upper and lower sweet spots had no obvious contribution to

Mechanical-Stratigraphic Characterization of the Eagle Ford Formation in Outcrop and Core, McMullen and Terrell Counties, Texas

Science.gov (United States)

Xu, G.; Chester, J. S.; Chester, F. M.

2017-12-01

The objective of this project is to characterize the geomechanical properties of individual and composite lithologic units over length scales of decimeter to tens of meters. We have characterized the stratigraphy and lithology of the Eagle Ford Formation in outcrops at Lozier and Antonio Canyons of West TX, and in core taken at 3.2 km depth in McMullen County, TX. Dominant lithologies examined include reworked ash layers, argillaceous mudstone, organic-rich mudstone, foraminifera wackestone, packstone, pyritic packstone, and foraminifera/dolomitic packstone-grainstone. Samples of these units are deformed in triaxial compression at 1- 40 MPa confining pressure (Pc), and room temperature and humidity. The elastic properties, pre-fracture yielding (ductility), and fracture strength are primarily a function of particle size, texture (degree of mud versus grain support), and composition. Young's Modulus (YM) and Poison's Ratio (PR) increase similarly with an increase in grain-support and carbonate content, and a decrease in organic matter and clay. The greatest change occurs at the transition from mud-supported to grain-supported textures where YM and PR increase by a factor of 3 and 1.5, respectively. Both YM and PR can display anisotropy with directional variation of 30%, most notably in micro-laminated units, but also in the more massive pyritic packstones. Overall, pre-fracture ductility decreases with an increase in carbonate content; ductile strain in the argillaceous- and organic-rich-mudstones is 1.4%, 3-4 times greater than that in the packstone/grainstone. Fracture strength increases with an increase in carbonate content and a decrease in clay content. The organic rich mudstone fails at 130 MPa, is nearly 2 times stronger than argillaceous mudstones, and 50% weaker than packstone/grainstones at 1 MPa Pc. The angle of internal friction is 45 degrees for all lithologies, consistent with a transition in fracture from opening- to shear-mode between 1 to 15 MPa Pc

Efficiency of inert mineral dusts in the control of corn weevil

Directory of Open Access Journals (Sweden)

Carlos F. Jairoce

2016-02-01

Full Text Available ABSTRACT Corn weevil (Sitophilus zeamais may cause great losses in the crop and in stored corn grains. This insect is controlled with the use of chemical insecticides, which may cause serious damage to human health. One alternative of control is the use of inert dusts. The objective of this study was to evaluate the efficiency of inert dusts in the control of S. zeamais under laboratory conditions. The experiment was conducted in 2014, in a completely randomized design, and the treatments consisted of basalt dust with three different granulometries (A, B and C and diatomaceous earth, each of which at the doses of 2 and 4 kg t-1 and a control (no application. Each treatment had four replicates, and the sample unit consisted of 20 g of corn grains infected with 10 adults of S. zeamais kept in temperature-controlled chamber at 25 °C, 70% RH and photophase of 12 h. The dust efficiency was calculated using the equation of Abbott. The mortality rate was higher with the use of diatomaceous earth, reaching 100% after 5 days of exposure and the percentage of control for basalt dusts, 29 days after treatment, was above 80%.

Geology of the Carnegie museum dinosaur quarry site of Diplodocus carnegii, Sheep Creek, Wyoming

Science.gov (United States)

Brezinski, D.K.; Kollar, A.D.

2008-01-01

The holotype of Diplodocus carnegii Hatcher, 1901, consists of a partial skeleton (CM 84) that was recovered, along with a second partial skeleton of the same species (CM 94), from the upper 10 m of the Talking Rock facies of the Brushy Basin Member of the Morrison Formation exposed along Bone Quarry Draw, a tributary of Sheep Creek in Albany County, Wyoming. A composite measured section of the stratigraphic interval exposed adjacent to the quarry indicates that the Brushy Basin Member in this area is a stacked succession of lithofacies consisting of hackly, greenish gray, calcareous mudstone and greenish brown, dense, fine-grained limestone. The more erosion resistant limestone layers can be traced over many hundreds of meters. Thus, these strata do not appear to represent a highly localized deposit such as a stream channel, oxbow lake, or backwater pond. The Sheep Creek succession is interpreted as representing a clastic-dominated lake where high turbidity and sediment influx produced deposition of calcareous mudstone. During drier periods the lake's turbidity decreased and limestone and dolomite precipitation replaced mud deposition. Microkarsting at the top of some limestone/ dolomite layers suggests subaerial deposition may have prevailed during these dry episodes. The quarry of D. carnegii was excavated within the top strata of one of the numerous intervals of hackly, greenish gray, calcareous mudstone that represent an ephemeral freshwater lake. The quarry strata are directly overlain by 0.3 m of dolomite-capped limestone that was deposited shortly after interment of D. carnegii in the lake mudstones. The close vertical proximity of the overlying limestone to the skeleton's stratigraphic: level suggests that the animal's carcass may have been buried beneath the drying lake deposits during a period of decreased rainfall.

Lithologic Controls on Structure Highlight the Role of Fluids in Failure of a Franciscan Complex Accretionary Prism Thrust Fault

Science.gov (United States)

Bartram, H.; Tobin, H. J.; Goodwin, L. B.

2015-12-01

Plate-bounding subduction zone thrust systems are the source of major earthquakes and tsunamis, but their mechanics and internal structure remain poorly understood and relatively little-studied compared to faults in continental crust. Exposures in exhumed accretionary wedges present an opportunity to study seismogenic subduction thrusts in detail. In the Marin Headlands, a series of thrusts imbricates mechanically distinct lithologic units of the Mesozoic Franciscan Complex including pillow basalt, radiolarian chert, black mudstone, and turbidites. We examine variations in distribution and character of structure and vein occurrence in two exposures of the Rodeo Cove thrust, a fossil plate boundary exposed in the Marin Headlands. We observe a lithologic control on the degree and nature of fault localization. At Black Sand Beach, deformation is localized in broad fault cores of sheared black mudstone. Altered basalts, thrust over greywacke, mudstone, and chert, retain their coherence and pillow structures. Veins are only locally present. In contrast, mudstone is virtually absent from the exposure 2 km away at Rodeo Beach. At this location, deformation is concentrated in the altered basalts, which display evidence of extensive vein-rock interaction. Altered basalts exhibit a pervasive foliation, which is locally disrupted by both foliation-parallel and cross-cutting carbonate-filled veins and carbonate cemented breccia. Veins are voluminous (~50%) at this location. All the structures are cut by anastomosing brittle shear zones of foliated cataclasite or gouge. Analyses of vein chemistry will allow us to compare the sources of fluids that precipitated the common vein sets at Rodeo Beach to the locally developed veins at Black Sand Beach. These observations lead us to hypothesize that in the absence of a mechanically weak lithology, elevated pore fluid pressure is required for shear failure. If so, the vein-rich altered basalt at Rodeo Beach may record failure of an

Development of a Field Laundry Wastewater Recycling System

Science.gov (United States)

1986-04-01

its physical , chemical, and toxicological properties . Chemical interactions may also occur in laundry water that may result in additional compounds of...was used to prepare a diatomite slurry needed to precoat the septums in the diatomaceous earth filter. II 6 If Sx COLLECTION TANK (CT) Figure 3...biochemical oxygen demand (BOD) bottles were then taken. The samples were divided into fractions for replicate testing of chemical and physical

In-situ Substrate Addition to Create Reactive Zones for Treatment of Chlorinated Aliphatic Hydrocarbons: Vandenberg Air Force Base

Science.gov (United States)

2004-12-17

the diatomite and diatomaceous siltstone of the Sisquoc formation. This aquifer configuration affords an effective bottom to the unconfined aquifer and...dissolved phase (Suthersan 2002). Given the low TOC of the soils , this effect would be expected to be slight. The rise was approximately concurrent with... effects of molasses are not largely a “ soil washing” effect ? A mass balance approach seems essential. Please discuss this general concern, and

National Uranium Resource Evaluation: Salina Quadrangle, Utah

International Nuclear Information System (INIS)

Lupe, R.D.; Campbell, J.A.; Franczyk, K.J.; Luft, S.J.; Peterson, F.; Robinson, K.

1982-09-01

Two stratigraphic units, the Late Jurassic Salt Wash Member of the Morrison Formation and the Triassic Chinle Formation, were determined to be favorable for the occurrence of uranium deposits that meet the minimum size and grade requirements of the US Department of Energy in the Salina 1 x 2 0 Quadrangle, Utah. Three areas judged favorable for the Salt Wash Member are the Tidwell and Notom districts, and the Henry Mountains mineral belt. The criteria used to establish favorability were the presence of: (1) fluvial sandstone beds deposited by low-energy streams; (2) actively moving major and minor structures such as the Paradox basin and the many folds within it; (3) paleostream transport directions approximately perpendicular to the trend of many of the paleofolds; (4) presence of favorable gray lacustrine mudstone beds; and (5) known uranium occurrences associated with the favorable gray mudstones. Four favorable areas have been outlined for the Chinle Formation. These are the San Rafael Swell, Inter River, and the Orange Cliffs subareas and the Capitol Reef area. The criteria used to establish these areas are: the sandstone-to-mudstone ratios and the geographic distribution of the Petrified Forest Member of the Chinle Formation which is considered as the probable source for the uranium

Upper Silurian reef mounds on a shallowing carbonate ramp, Devon Island, Arctic Canada

Energy Technology Data Exchange (ETDEWEB)

Dixon, O A [Ottawa Univ., ON (Canada); Graf, G C [Chevron Canada Resources, Calgary, AB (Canada)

1992-03-01

Near Gascoyne Inlet, the topmost Douro and lowermost Barlow Inlet formations record overall upward shallowing from ramp to shallow shelf conditions. This transitional sequence contains bioherms of various sizes, from small isolated reef mounds 1-2 m across to larger, compound reef mounds over 50 m thick and 60 m across, as well as distictive inter- and pre-reef mound facies. The larger reef mounds show stages intermediate in character between those in sponge-dominated reef mounds of the Douro Formation and in larger stromatoporoid-crinoid dominated reefs in the Barlow Inlet Formation. Three principal reef mounds developed in turn. An initial partly lithified lime mudstone, containing scattered corals and apparently relict sponge-cryptomicrobial fabrics, developed on sheets of oncolitic storm debris in mainly low energy conditions between storm and fairweather wave bases. With gradual shallowing and progressively higher energy conditions above fairweather wave base, a middle facies of coral- and crinoid-rich mudstone developed. An abrupt deepening restored conditions of low energy, and the ensuing upper facies of the reef mounds is more varied, comprising sparsely fossiliferous and locally fenestral lime mudstones, patchy coral bafflestone and bindstone, coarse encrinites and substantially culminating stromatoporoid bindstone. 36 refs., 14 figs., 5 tabs.

Mechanical Aqueous Alteration Dominates Textures of Gale Crater Rocks: Mars Hand Lens Imager (MAHLI) Results

Science.gov (United States)

Aileen Yingst, R.; Minitti, Michelle; Edgett, Kenneth; McBride, Marie; Stack, Kathryn

2015-04-01

The Mars Hand Lens Imager (MAHLI) acquired sub-mm/pixel scale color images of over 70 individual rocks and outcrops during Curiosity's first year on Mars, permitting the study of textures down to the distinction between silt and very fine sand. We group imaged rock textures into classes based on their grain size, sorting, matrix characteristics, and abundance of pores. Because the recent campaign at Pahrump Hills acquired many more MAHLI images than elsewhere along the rover traverse [6], textural analysis there is more detailed and thus types observed there are sub-divided. Mudstones: These rocks contain framework grains smaller than the highest resolution MAHLI images (16 μm/pixel), and thus are interpreted to consist of grains that are silt-sized or smaller. Some rocks contain nodules, sulfate veins, and Mg-enriched erosionally-resistant ridges. The Pahrump Hills region contains mudstones of at least four different sub-textures: recessive massive, recessive parallel-laminated, resistant laminated-to-massive, and resistant cross-stratified. Recessive mudstones are slope-forming; parallel-laminated recessive mudstones display mm-scale parallel (and in some cases rhythmic) lamination that extends laterally for many meters, and are interbedded with recessive massive mudstones. Coarse cm- to mm-scale laminae appear within resistant mudstones though some portions are more massive; laminae tend to be traceable for cm to meters. Well-sorted sandstones: Rocks in this class are made of gray, fine-to-medium sand and exhibit little to no porosity. Two examples of this class show fine lineations with sub-mm spacing. Aillik, a target in the Shaler outcrop, shows abundant cross-lamination. The Pahrump Hills region contains a sub-texture of well-sorted, very fine to fine-grained cross-stratified sandstone at the dune and ripple-scale. Poorly-sorted sandstones. This class is subdivided into two sub-classes: rounded, coarse-to-very coarse sand grains of variable colors and

Consolidation properties of the mudstones from the Harwell boreholes

International Nuclear Information System (INIS)

McEwen, T.J.; Hobbs, P.; Horseman, S.T.

1983-03-01

Long term high stress consolidation tests have been performed on samples of Oxford Clay, Gault clay, Kimmeridge clay and Lower Lias clay from beneath the Atomic Energy Research Establishment, Harwell, Oxfordshire. In addition to calculating the modulus of volume change and the coefficient of consolidation for each sample, reconstruction of the true one-dimensional consolidation behaviour has been attempted. One dimensional vertical permeabilities have been calculated for samples of Oxford Clay and are compared with those measured by hydraulic testing. Tests were performed in a specially modified oedometer cell using an adapted Denison dead weight loading system in order to produce the required high consolidation stresses. Only one sample, that of Kimmeridge Clay, gave a classical and easily interpretable, consolidation curve, and because of this the OCR (Overconsolidation Ratio) values from other curves have been corrected with respect to this one. This discrepancy between laboratory derived OCRs (OCRLAB) and those calculated from geological information (OCRGEOL) is interesting and is ascribed in this report to apparent overconsolidation caused by secondary compression. Hydraulic conductivities calculated from the oedometer tests at the in situ stresses expected in the Oxford Clay at 273 m depth lie in the range from 4.6 to 5.4 x 10 -12 ms -1 . (author)

Organic molecules in the Sheepbed Mudstone, Gale Crater, Mars

NARCIS (Netherlands)

Freissinet, C.; Glavin, D. P.; Mahaffy, P. R.; Miller, K. E.; Eigenbrode, J. L.; Summons, R. E.; Brunner, A. E.; Buch, A.; Szopa, C.; Archer, P. D.; Franz, H. B.; Atreya, S. K.; Brinckerhoff, W. B.; Cabane, M.; Coll, P.; Conrad, P. G.; Des Marais, D. J.; Dworkin, J. P.; Fairén, A. G.; François, P.; Grotzinger, J. P.; Kashyap, S.; ten Kate, I. L.; Leshin, L. A.; Malespin, C. A.; Martin, M. G.; Martin-Torres, F. J.; Mcadam, A. C.; Ming, D. W.; Navarro-González, R.; Pavlov, A. A.; Prats, B. D.; Squyres, S. W.; Steele, A.; Stern, J. C.; Sumner, D. Y.; Sutter, B.; Zorzano, M. P.

The Sample Analysis at Mars (SAM) instrument on board the Mars Science Laboratory Curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of Mars at Gale Crater.

comparison of authigenic minerals in sandstones and interbedded

African Journals Online (AJOL)

a

Mechanically compacted mudstones, siltstones and shales expelled large ... quartz, and (16) hydrocarbon migration; pyrite and apatite precipitation [1, 7, 12]. ... relationship of the authigenic minerals, burial history and fluid inclusions studies.

Chemical variations in Yellowknife Bay formation sedimentary rocks analyzed by ChemCam on board the Curiosity rover on Mars

Science.gov (United States)

Mangold, Nicolas; Forni, Olivier; Dromart, G.; Stack, K.M.; Wiens, Roger C.; Gasnault, Olivier; Sumner, Dawn Y.; Nachon, Marion; Meslin, Pierre-Yves; Anderson, Ryan B.; Barraclough, Bruce; Bell, J.F.; Berger, G.; Blaney, D.L.; Bridges, J.C.; Calef, F.; Clark, Brian R.; Clegg, Samuel M.; Cousin, Agnes; Edgar, L.; Edgett, Kenneth S.; Ehlmann, B.L.; Fabre, Cecile; Fisk, M.; Grotzinger, John P.; Gupta, S.C.; Herkenhoff, Kenneth E.; Hurowitz, J.A.; Johnson, J. R.; Kah, Linda C.; Lanza, Nina L.; Lasue, Jeremie; Le Mouélic, S.; Lewin, Eric; Malin, Michael; McLennan, Scott M.; Maurice, S.; Melikechi, Noureddine; Mezzacappa, Alissa; Milliken, Ralph E.; Newsome, H.L.; Ollila, A.; Rowland, Scott K.; Sautter, Violaine; Schmidt, M.E.; Schroder, S.; D'Uston, C.; Vaniman, Dave; Williams, R.A.

2015-01-01

The Yellowknife Bay formation represents a ~5 m thick stratigraphic section of lithified fluvial and lacustrine sediments analyzed by the Curiosity rover in Gale crater, Mars. Previous works have mainly focused on the mudstones that were drilled by the rover at two locations. The present study focuses on the sedimentary rocks stratigraphically above the mudstones by studying their chemical variations in parallel with rock textures. Results show that differences in composition correlate with textures and both manifest subtle but significant variations through the stratigraphic column. Though the chemistry of the sediments does not vary much in the lower part of the stratigraphy, the variations in alkali elements indicate variations in the source material and/or physical sorting, as shown by the identification of alkali feldspars. The sandstones contain similar relative proportions of hydrogen to the mudstones below, suggesting the presence of hydrous minerals that may have contributed to their cementation. Slight variations in magnesium correlate with changes in textures suggesting that diagenesis through cementation and dissolution modified the initial rock composition and texture simultaneously. The upper part of the stratigraphy (~1 m thick) displays rocks with different compositions suggesting a strong change in the depositional system. The presence of float rocks with similar compositions found along the rover traverse suggests that some of these outcrops extend further away in the nearby hummocky plains.

Geology of the Cannonball Formation (Paleocene) in the Williston basin, with reference to uranium potential. Report of investigation No. 57

International Nuclear Information System (INIS)

Cvancara, A.M.

1976-01-01

The Paleocene Cannonball Formation is a marine, non-lignitic-bearing clastic sequence in the lower part of the Fort Union Group. It is overlain by the lignite-bearing Tongue River Formation in places and both overlain and underlain by the lignite-bearing Ludlow Formation in places. The Cannonball crops out primarily in southwest-central North Dakota and probably occurs throughout the western one-half of the state. It occurs also in northwestern South Dakota and may extend into parts of Saskatchewan and Manitoba. Poorly consolidated, very fine- to fine-grained, light to medium brownish yellow-weathering sandstone and light gray-weathering, sandy mudstone are the principal types of lithology. Mudstone generally predominates in North Dakota whereas sandstone seems to predominate in South Dakota. Although uranium in the Williston basin has been found almost entirely in lignite and nonmarine carbonaceous rocks, its occurrence in the marine Cannonball Formation is possible. If the Cannonball, Ludlow, Tongue River, and Sentinel Butte Formations are at least partly penecontemporaneous, a variety of depositional environments were in areal juxtaposition during the Paleocene. Streams originating or passing through coastal plain bogs could have carried uranium ions (derived from volcanic materials) to the Cannonball sea where they were deposited syngenetically. Epigenetic uranium may occur in Cannonball mudstones or sandstones that directly underlie the Ludlow Formation, which is known to contain volcanic materials

Detection of mineral impurities in diatomite ores

OpenAIRE

Guatame Garcia, L.A.; Buxton, M.W.N.; Fiore, Saverio

2017-01-01

Diatomaceous Earth (DE) is commonly used in the industry for the manufacturing of filters, where diatomite is preferred due to its low chemical reactivity and high porosity. Diatomite deposits with major amounts of mineral impurities, such as carbonates, present a problem in the production DE. In this study, samples from a diatomite deposit with known presence of carbonate were analysed. With the aim of estimating the carbonate content, the samples were analysed with infrared (IR) spectroscop...

ChemCam at Gale Crater: Highlights and Discoveries from Three Years of Chemical Measurements on Mars

Science.gov (United States)

Blaney, Diana L.; Wiens, Roger; Maurice, Sylvestre; Gasnault, Olivier; Anderson, Ryan; Bridges, John; Bridges, Nathan; Clegg, Samuel; Clark, Benton; Ehlmann, Bethany; Dyar, Melinda D.; Fisk, Martin; Francis, Raymond; Fabre, Cecile; Forni, Olivier; Frydenvang, Jens; Johnson, Jeffery; Lanza, Nina; Leveille, Richard; Lasue, Jeremie; Le Deit, Laetitia; Mangold, Nicholas; Melikechi, Noureddine; Nachon, Marion; Newsom, Horton; Payre, Valerie; Rapin, William; Sautter, Violane; Vaniman, David; Grotzinger, John; Vasavad, Ashwin; Crisp, Joy

2015-11-01

ChemCam has undertaken a detailed chemical investigation of the rocks and soils at Gale crater over the last three years with over six thousand separate geochemical measurements. Recent recalibration of the ChemCam data using a new library of >350 geochemical standards has enabled increased elemental accuracies over a wider compositional range. The increased accuracy combined with ChemCam’s small spot size allows for the chemistry of mineral end members including feldspars, high silica, oxide rich grains to be identified. ChemCam has observed both sedimentary and igneous compositions. Igneous compositions are generally present in conglomerates and in float rocks. Compositions show a wide range of igneous chemistry ranging from basaltic to feldspar rich assemblages.Sedimentary rocks have a wide range of compositions reflecting both differences in chemical source regions and in depositional and diagenetic histories. The “Sheepbed” mudstones cluster around Martian average crustal compositions. The “Kimberley” outcrop showed enhanced potassium reaching concentrations up to ~6 wt% K2O. More recent observations in the Murray Formation at the base of Mt. Sharp reveal mudstones that are lower in magnesium and higher in silica and aluminum than the more basaltic mudstones previously investigated. Extremely high silica (75-85 wt%) deposits have also been identified. The high silica observations were associated with increased TiO2, While the Murray mudstones are generally low in magnesium, local enhancements in magnesium have also been noted associated with resistant facies in the outcrop. Chemical trends also indicate that iron oxide phases may also be present as cements. Sandstone facies with a mafic composition are also present. Veins in the unit also show a wide range of compositions indicating fluid chemistries rich in calcium sulfate, fluorine, magnesium and iron were present. Vein chemistry could be the result of distinct fluids migrating through from a

Paleomagnetic results from Late Pennsylvanian marls and Early Permian red paleosols of the Dunkard group, Ohio and West Virginia, U.S.A.

Science.gov (United States)

Abrajevitch, A.; Oliva, B.; Peters, S.; Beehr, A.; van der Voo, R.

2006-12-01

Sediments of the Dunkard Gr. were deposited in the Appalachian foreland basin during the Pennsylvanian and Early Permian, an interval encompassing the long reverse polarity Kiaman chron. Lithofacies in the Dunkard Gr. in eastern Ohio and western West Virginia include lenticular and sheet-form cross-bedded micaceous sandstones, coal, mottled red and purple mudstones, gray laminated mudstones and argillaceous lime mudstones. They are indicative of deposition on a low-gradient, tropical wet-dry fluvial plain. Few lithofacies are laterally persistent over sufficiently long distances, so that correlation schemes are based largely on coal horizons, partly for historical economic reasons and partly because coal beds appear to be more laterally persistent than most other lithofacies. Magnetostratigraphy would therefore provide a powerful additional correlation tool in the Dunkard Gr, A short normal polarity interval has been reported in the Dunkard Gr. (Helsley, 1965), but to date such a change in magnetic field polarity has not been confirmed by later studies. To confirm the presence of the normal polarity subchron and to explore the possibility of using it as a correlation tool in the Dunkard Gr., we sampled 5 sections thought to straddle the Late Pennyslvanian-Early Permian boundary. Sampled lithofacies include red and mottled red-purple paleosols, grey mudstones containing siderite concretions, micaceous sandstones, and dark gray argillaceous limestones. Samples were demagnetized thermally and by AF. The remanent magnetic directions agree with those expected for the Early Permian. A change in polarity was detected in three of the studied sections. Magnetization is carried by several different magnetic minerals, mostly hematite in paleosols and iron sulfides in combination with magnetite in sandstones, marls and limestones. Although we have found good evidence for the normal polarity interval within Kiaman age rocks of the Dunkard Gr., additional magnetostratigraphic

Late Miocene radiolarian biostratigraphy and paleoceanography of Sawai Bay formation, Neill Island, Andamans, India

Digital Repository Service at National Institute of Oceanography (India)

Gupta, S.M.; Srinivasan, M.S.

Late Miocene radiolarian zones are encountered from mudstone strata of Sawai Bay Formation, Neill Island, Andamans. Percentage data of forty-five coarser taxonomic groups of radiolarians were subjected to Q-mode cluster analysis. Based...

Mineralogy of Rocks and Sediments at Gale Crater, Mars

Science.gov (United States)

Achilles, Cherie; Downs, Robert; Blake, David; Vaniman, David; Ming, Doug; Rampe, Elizabeth; Morris, Dick; Morrison, Shaunna; Treiman, Allan; Chipera, Steve; Yen, Albert; Bristow, Thomas; Craig, Patricia; Hazen, Robert; Crisp, Joy; Grotzinger, John; Des Marias, David; Farmer, Jack; Sarrazin, Philippe; Morookian, John Michael

2017-04-01

The Mars Science Laboratory rover, Curiosity, is providing in situ mineralogical, geochemical, and sedimentological assessments of rocks and soils in Gale crater. Since landing in 2012, Curiosity has traveled over 15 km, providing analyses of mudstones and sandstones to build a stratigraphic history of the region. The CheMin X-ray diffraction (XRD) instrument is the first instrument on Mars to provide quantitative mineralogical analyses of drilled powders and scooped sediment based on X-ray crystallography. CheMin identifies and determines mineral abundances and unit-cell parameters of major crystalline phases, and identifies minor phases at abundances >1 wt%. In conjunction with elemental analyses, CheMin-derived crystal chemistry allows for the first calculations of crystalline and amorphous material compositions. These mineralogy, crystal chemistry, and amorphous chemistry datasets are playing central roles in the characterization of Gale crater paleoenvironments. CheMin has analyzed 17 rock and sediment samples. In the first phase of the mission, Curiosity explored the sedimentary units of Aeolis Palus (Bradbury group), including two mudstones from Yellowknife Bay. CheMin analyses of the Yellowknife Bay mudstones identified clay minerals among an overall basaltic mineral assemblage. These mineralogical results, along with imaging and geochemical analyses, were used to characterize an ancient lacustrine setting that is thought to have once been a habitable environment. Following the investigations of the Bradbury group, Curiosity arrived at the lower reaches of Aeolis Mons, commonly called Mt. Sharp. A strategic sample campaign was initiated, drilling bedrock at X-ray amorphous phases. Adjacent to fractures, light-toned, halo-like zones are thought to result from significant aqueous alteration of the primary sandstone and show decreased abundances of feldspar and pyroxene, and an increase in the amorphous component, specifically high-silica phases. The Murray

The organic carbon isotope of lacustrine sediments of the Upper Shahejie formation in Huanghua Depression: a record of sedimentary environment and productivity of an ancient lake

International Nuclear Information System (INIS)

Fei, Weiwei; Huang, Xiaoyan; Dai, Na; Zhong, Ningning

2013-01-01

Huanghua depression was one of the largest Paleogene rift lakes in Bohai Bay basin, eastern China. The lake had broad area and deep water in the period of development peak—Oligocene 36~38Ma B.C., when organic-rich mudstones of upper Shahejie Formation formed. Twenty eight distal lake facie samples of the upper Shahejie Formation from Well GS35 were analyzed for organic carbon isotope, TOC, hydrogen index and trace elements in order to investigate the controls of organic carbon accumulation in the lake. The results show that lacustrine mudstones in the middile member of the upper Shahejie Formation have a heavy organic carbon isotope (-28.6 ‰ to -21.1 ‰) and a intense fractionation which is more than 7‰. In addition, it shows a good positive correlation with the total organic carbon (TOC) (Figure 1). Organic petrographic and organic geochemical analysis indicate that the biological inputs of the mudstone is dominated by algae and other aquatic organisms, and a low content of gammacerane prove the water is freshwater-brackish, so terrigenous organic matter and water salinity have little effect on its organic carbon isotope composition (δ"1"3C_o_r_g). It has well been documented that the climate in Bohai Bay basin was warm and humid during deposition of the upper Shahejie Formation, and the temperature did not change dramatically at that time (TaoZ et al., 2005). Ultimately, the heavy carbon isotope values of lacustrine organic matter may indicate the high productivity of ancient lakes. The good correlation between total organic carbon (TOC) and organic carbon isotope (δ"1"3C_o_r_g) as well as the widely existed organic-rich lamellae of the mudstone are the strong evidence for high paleoproductivity of the upper Shahejie Formation in Huanghua Depression during the deposition period. (1) Organic-rich lamellae of the mudstone formed in anoxia and stable environment have been recognized as the best evidence of high paleoproductivity. The presence of organic

Uraniferous surficial deposits in Southern Africa

International Nuclear Information System (INIS)

Hambleton-Jones, B.B.; Levin, M.; Wagener, G.F.

1986-01-01

Surficial uranium deposits are located in the north-western Cape Province of South Africa, in the Namib Desert east of Walvis Bay in South West Africa/Namibia and in the Serule Block of Botswana. They have been classified into the valley-fill, lacustrine, and pedogenic types. Carnotite is the main uranium-bearing mineral in the larger surficial deposits, with other minerals such as soddyite and phosphuranylite occurring locally. Uraninite or urano-organic complexes occur in the reducing environments of the diatomaceous earth, peat-rich deposits. Economically, the valley-fill type is the most important, with the largest deposits occurring in South West Africa/Namibia. In South West Africa/Namibia the valley-fill surficial uranium deposits occur in the Tumas and Langer Heinrich formations of the Teriary to Recent Namib Group. The Tubas, Langer Heinrich, and Welwitchia deposits are discussed: in them, carnotite occurs in calcareous and gypsiferous fluvial gravels. The pedogenic deposit at Mile 72 occurs in weathered granite and overlying gypcrete and has little economic potential. The economic potential of the surficial deposits in the north-western Cape Province is very limited in comparison with their South West African/Namibian counterparts, but the most important deposits are the lacustrine type, in particular those containing peat and diatomaceous earth. The mechanisms for the precipitation and preservation of the uranium are discussed

ON THE PALEOFAUNA INVERTEBRATES (MOLLUSCA, ARTROPODA; INSECTA OF DIATOMITE DEPOSITS OF SHAMB–1 LOCALITY (SISIAN SUITE, EARLY PLEISTOCENE, ARMENIA

Directory of Open Access Journals (Sweden)

М. A. Маrjanyan

2016-01-01

Full Text Available Aim. The study of fossil insects from diatomaceous sediments of Shamb-1 locality of Sisian Suite (Early Pleistocene. The collection of fossils plants and animals of Institute of Botany of NAS RA and authors' findings served as material for study.Methods. The material is processed and prepared for study by conventional methods in paleontology for prints and fossils of insects from diatomaceous sediments. There are 654 samples studied: 2 samples were with mollusks’ imprints and 652 samples with imprints of insects, from which preserved marks on 291samples allowed to identify them up to order, family, genus and species.Results. The studied material refers to the Mollusca and Arthropoda (Insecta types. Insects are represented by species of orders Orthoptera (2 fam., Homoptera (1 fam., Heteroptera (2 fam., Coleoptera (15 fam., Hymenoptera (2 fam., Diptera (1 fam.. Coleopteras dominate among them and are presented with following species of the family – Carabidae, Dytiscidae, Hydrophilidae, Histeridae, Staphylinidae, Silphidae, Elateridae, Buprestidae, Lampyridae, Scarabaeidae, Chrysomelidae, Tenebrionidae, Coccinellidae, Cerambycidae, Curculionidae.Main conclusions. An analysis of the taxonomic composition of paleofauna was done, which corresponds to the recent fauna and with considering modern ecological characteristics of systematical groups and species. In the investigated location of Shamb-1 a version is suggested about the palaeolandscapes and palaeoclimate in the Early Pleistocene.

Inert powders alone or in combination with neem oil for controlling Spodoptera eridania and Spodoptera frugiperda (Lepidoptera: Noctuidae) larvae

OpenAIRE

Kelly Christiane Constanski Silva; Janaina Zorzetti; Patricia Helena Santoro; Adriano Thibes Hoshino; Pedro Manuel Oliveira Janeiro Neves

2016-01-01

Laboratory studies was carry out to evaluated the potential of inert powders: bentonite, kaolin and diatomaceous earth (DE) applied as dust and aqueous suspension alone and associated with neem oil to the control Spodoptera eridania and Spodoptera frugiperda second instar larvae. In dust applications, 100% mortality of S. eridania, at the concentrations of 1.5 and 2.0 grams of bentonite, and 93.3% of S. frugiperda, at the concentration of 2.0 g were observed. DE at the height concentration (2...

Radiometric measurements on the fabrication of non-destructive assay standards for WIPP-Performance Demonstration Program

International Nuclear Information System (INIS)

Wong, A.S.; Marshall, R.S.

1997-04-01

The Inorganic Elemental Analysis Group of LANL has prepared several different sets of working reference materials (WRMs). These WRMs are prepared by blending quantities of nuclear materials (plutonium, americium, and enriched uranium) with diatomaceous earth. The blends are encapsulated in stainless steel cylinders. These WRMs are being measured as blind controls in neutron and gamma based non-destructive assay (NDA) instruments. Radiometric measurements on the blending homogeneity and verification on a set of sixty three plutonium based WRMs are discussed in this paper

Valorization of beer brewing wastes by composting

OpenAIRE

Silva, Maria Elisabete; Brás, Isabel

2017-01-01

The aim of this work was to study the viability of recycling the residual yeast and diatomaceous earth (RYDE) slurry generated by the beer brewing industry by composting with animal manures, as well as to evaluate the quality of the composts obtained. Two pilot composting trials were carried out with different mixes: cow manure/RYDE slurry (Pile CM) and sheep manure/RYDE slurry (Pile SM). For all piles, wood chips were applied as bulking agent. The process was monitored b...

Mineralogical Results from the Mars Science Laboratory Rover Curiosity

Science.gov (United States)

Blake, David Frederick.

2017-01-01

NASA's CheMin instrument, the first X-ray Diffractometer flown in space, has been operating on Mars for nearly five years. CheMin was first to establish the quantitative mineralogy of the Mars global soil (1). The instrument was next used to determine the mineralogy of a 3.7 billion year old lacustrine mudstone, a result that, together with findings from other instruments on the MSL Curiosity rover, documented the first habitable environment found on another planet (2). The mineralogy of this mudstone from an ancient playa lake was also used to derive the maximum concentration of CO2 in the early Mars atmosphere, a surprisingly low value that calls into question the current theory that CO2 greenhouse warming was responsible for the warm and wet environment of early Mars. CheMin later identified the mineral tridymite, indicative of silica-rich volcanism, in mudstones of the Murray formation on Mt. Sharp. This discovery challenges the paradigm of Mars as a basaltic planet and ushers in a new chapter of comparative terrestrial planetology (3). CheMin is now being used to systematically sample the sedimentary layers that comprise the lower strata of Mt. Sharp, a 5,000 meter sequence of sedimentary rock laid down in what was once a crater lake, characterizing isochemical sediments that through their changing mineralogy, document the oxidation and drying out of the Mars in early Hesperian time.

Amount and nature of occluded water in bedded salt, Palo Duro Basin, Texas

International Nuclear Information System (INIS)

Fisher, R.S.

1987-01-01

The quantity and types of fluids within bedded salt cores from the Permian San Andres Formation, Palo Duro, Texas, were evaluated at the Texas Bureau of Economic Geology. Bedded halite from the San Andres Formation and other salt-bearing units were selected to represent the variety of salt types present, and were then analyzed. The mean water content of ''pure'' samples (more than 90% halite) is 0.4 weight percent, with none observed greater than 1.0 weight percent. Samples that contain more than 10 weight percent clay or mudstone display a trend of increasing water content with increasing clastic material. Chaotic mudstone-halite samples have as much as 5 weight percent water; halite-cemented mudstone interlayers, common throughout the bedded salts, may have water content values as high as 10 to 15 weight percent based on extrapolation of existing data that range from 0 to about 6%. No significant difference exists between the mean water content values of ''pure salt'' from the upper San Andres, lower San Andres Cycle 5, and lower San Andres Cycle 4 salt units. The fraction of total water present as mobile intergranular water is highly variable and not readily predicted from observed properties of the salt sample. The amount of water that would be affected by a high-level nuclear waste repository can be estimated if the volume of halite, the volume of clastic interlayers, and the amount and type of impurity in halite are known. Appendix contains seven vugraphs

Thermal conductivity of sedimentary rocks - selected methodological, mineralogical and textural studies

Energy Technology Data Exchange (ETDEWEB)

Midttoemme, Kirsti

1997-12-31

The thermal conductivity of sedimentary rocks is an important parameter in basin modelling as the main parameter controlling the temperature within a sedimentary basin. This thesis presents measured thermal conductivities, mainly on clay- and mudstone. The measured values are compared with values obtained by using thermal conductivity models. Some new thermal conductivity models are developed based on the measured values. The values obtained are less than most previously published values. In a study of unconsolidated sediments a constant deviation was found between thermal conductivities measured with a needle probe and a divided bas apparatus. Accepted thermal conductivity models based on the geometric mean model fail to predict the thermal conductivity of clay- and mudstone. Despite this, models based on the geometric mean model, where the effect of porosity is taken account of by the geometric mean equation, seem to be the best. Existing models underestimate the textural influence on the thermal conductivity of clay- and mudstone. The grain size was found to influence the thermal conductivity of artificial quartz samples. The clay mineral content seems to be a point of uncertainty in both measuring and modelling thermal conductivity. A good universal thermal conductivity model must include many mineralogical and textural factors. Since this is difficult, different models restricted to specific sediment types and textures are suggested to be the best solution to obtain realistic estimates applicable in basin modelling. 243 refs., 64 figs., 31 tabs.

Analysis of Deformation Characteristics and Stability Mechanisms of ...

Indian Academy of Sciences (India)

21

analysis of landslide mass under the similar engineering geological ... The bedrock mainly consists of the green-gray marlite of the thin layer, the interbedded dolomitic limestone and the purple-red mudstone of the Badong Formation from the ...

A preliminary report on coprolites from the Late Triassic part of the Kap Stewart Formation, Jameson Land, East Greenland

DEFF Research Database (Denmark)

Milàn, Jesper; Clemmensen, Lars B; Adolphsen, Jan Schulz

2012-01-01

The basal part of the Triassic-Jurassic (Rhaetian-Sinemurian) Kap Stewart Formation, exposed at Jameson Land, East Greenland, yields an extensive coprolite collection from black, parallel-laminated mudstone (“paper shale”), representing an open lacustrine system. Preliminary investigations show t...

An attempt to prepare and characterize a soil reference material for Cr(VI) and Cr(III)

International Nuclear Information System (INIS)

Solano, G.; Katz, S.A.; Holzbecher, J.; Chatt, A.

1994-01-01

Reference materials for the speciation and quantification of chromium in contaminated soils were prepared by impregnating diatomaceous earth with BaCrO 4 and Cr 2 O 3 . The chromium concentrations of these materials were confirmed to be 200 mg/kg both by atomic absorption spectrometry and by instrumental neutron activation analysis, but monthly assays over two calendar quarters of the reference material impregnated with BaCrO 4 revealed the hexavalent chromium was not stable in this matrix. (author) 6 refs,; 2 tabs

The Search for Organic Compounds of Martian Origin in Gale Crater by the Sample Analysis at Mars (SAM) Instrument on Curiosity

Science.gov (United States)

Glavin, Daniel; Freissinet, Caroline; Mahaffy, Paul; Miller, Kristen; Eigenbrode, Jennifer; Summons, Roger; Archer, Douglas, Jr.; Brunner, Anna; Martin, Mildred; Buch, Arrnaud;

Study of Sedimentary Outcrop of Semanggol Formation with the Correlation of Geology, Geotechnical and Geophysics Technique

Science.gov (United States)

Nordiana, A. N.; Nordiana, M. M.; Jia, Teoh Ying; Hisham, Hazrul; Sulaiman, Nabila; Maslinda, Umi; Taqiuddin, Z. M.; Nur Amalina, M. K. A.; Afiq Saharudin, Muhamad

2017-04-01

The study location was at Bukit Kukus, Kuala Ketil, Kedah, Malaysia where the geological outcrop of this Semanggol Formation comprises of chert, mudstone, and volcanic tuff. The study was conducted using two geophysical methods, which are 2-D Resistivity and Ground Penetrating Radar (GPR). The objectives of the study are to correlate both of the geophysical methods through the value of conductivity and to identify the physical properties of rocks through the value of porosity and permeability. The data acquisition for both methods was conducted on the same line. For 2-D Resistivity method, the length of the line is 60 m with 1.5 m electrode spacing and the array used was Wenner-Schlumberger. For GPR method, the survey line was on top of the resistivity line, and the frequency of the antenna used is 250 MHz. A good correlation exists between both of the GPR signature and contour maps for resistivity from the surfer 10 software with the outcrop feature. Conductivity value from both GPR and Resistivity method was compared and the range value of conductivity obtained from GPR method almost equivalent with Resistivity method based on derivation and calculation for the sedimentary rocks, which are 0.037 to 0.574 miliSiemens per metre (mS/m) for chert and 0.186 to 10.142 miliSiemens per metre (mS/m) for mudstone. Two types of rock samples were taken, and several geotechnical tests were conducted, but only the value of permeability, K and porosity, ɸ of chert can be calculated, which are 1.95E-22 m2 (original condition) and 2.27E-22 m2 (dry condition) and 3 percent respectively as the sample of mudstone was damaged. The parameter of the 2-D resistivity method derived from Archie’s law was used to calculate the porosity, ɸf value using the Formation Factor equation. The range values of porosity, ɸf for chert mostly in the range of 5 to 25 percent, which is 6.26 to 13.36 percent but slightly out of range for mudstone, which is 14.12 to 36.02 percent.

Evidence of lacustrine sedimentation in the Upper Permian Bijori

Indian Academy of Sciences (India)

The Upper Permian Bijori Formation of the Satpura Gondwana basin comprising fine- to coarsegrained sandstone, carbonaceous shale/mudstone and thin coal bands was previously interpreted as the deposits of meandering rivers. The present study documents abundance of wave ripples, hummocky and swaley ...

Alteration of uraniferous and native copper concretions in the Permian mudrocks of south Devon, United Kingdom

International Nuclear Information System (INIS)

Milodowski, A.E.; Styles, M.T.; Horstwood, M.S.A.; Kemp, S.J.

2002-03-01

This report presents the results of a study of the mineralogy and alteration characteristics of unusual concretions containing sheets of native copper, and uranium-vanadium mineralised concretions, in mudstones and siltstones of the Pennian Littleham Mudstone Formation, at Littleham Cove, south Devon, England. The main objectives of the study were: 1. To investigate the corrosion characteristics of the native copper as a natural analogue for the long-term behaviour of copper canisters, sealed in a compacted clay (bentonite) backfill, that will be used for the deep geological disposal of spent fuel and high-level radioactive waste (HLW). This study developed from an earlier pilot study, which demonstrated that the alteration of the native copper in the concretions from Littleham Cove was mineralogically and chemically complex. 2. To investigate the alteration and oxidation of minerals containing reduced species (e.g. ferrous iron) within the uranium-rich concretions as a natural analogue for the potential effects of oxidation induced by alpha-radiolysis of water in a HLW repository environment. Native copper-bearing concretions in the Littleham Mudstone Formation are very rare. They occur, as thin lenticular disks developed largely along bedding lamina and thin low-angle fractures cutting the bedding laminae the upper part of the formation, about 10 m below the top of the formation. This part of the sequence comprises laterally discontinuous, fine-grained sheet-flood and channel sandstones and siltstones. Some of these sandstones, are more extensively-cemented by copper sulphides (mainly chalcocite), copper arsenides, cobalt-nickel arsenides, and uranium silicate. The thin permeable sandstones and siltstones, and fractures zones around small faults appear to have acted as the conduits for the movement of mineralising fluids through the mudstones. The native copper sheets all show a similar pattern of corrosion and alteration. However, the intensity of alteration is

Lawrence Livermore National Laboratory Working Reference Material Production Pla

Energy Technology Data Exchange (ETDEWEB)

Wong, Amy; Thronas, Denise; Marshall, Robert

1998-11-04

This Lawrence Livermore National Laboratory (LLNL) Working Reference Material Production Plan was written for LLNL by the Los Alamos National Laboratory to address key elements of producing seven Pu-diatomaceous earth NDA Working Reference Materials (WRMS). These WRMS contain low burnup Pu ranging in mass from 0.1 grams to 68 grams. The composite Pu mass of the seven WRMS was designed to approximate the maximum TRU allowable loading of 200 grams Pu. This document serves two purposes: first, it defines all the operations required to meet the LLNL Statement of Work quality objectives, and second, it provides a record of the production and certification of the WRMS. Guidance provided in ASTM Standard Guide C1128-89 was used to ensure that this Plan addressed all the required elements for producing and certifying Working Reference Materials. The Production Plan was written to provide a general description of the processes, steps, files, quality control, and certification measures that were taken to produce the WRMS. The Plan identifies the files where detailed procedures, data, quality control, and certification documentation and forms are retained. The Production Plan is organized into three parts: a) an initial section describing the preparation and characterization of the Pu02 and diatomaceous earth materials, b) middle sections describing the loading, encapsulation, and measurement on the encapsulated WRMS, and c) final sections describing the calculations of the Pu, Am, and alpha activity for the WRMS and the uncertainties associated with these quantities.

Conductividad térmica efectiva en cerámicas porosas

Directory of Open Access Journals (Sweden)

Gabriel Peña Rodríguez

2016-07-01

Full Text Available The effective thermal conductivity at room temperature of porous ceramics that were produced by the method of casting in plaster molds from mixtures of kaolin clay, diatomaceous earth and calcium carbonate (CaCO3 is reported. To produce samples, the diatomite concentration was changed between 30 and 90%, maintaining the percentage of CaCO3 in 10 % percent. Sodium silicate was used as deflocculant, ranging from 0.5% to 2.1%, increasing along with the concentration of diatomite. The process of homogenization of the slip was performed using a reference flocculator F6 E & Q 300T at 200 rpm. The drying was carried out at room temperature for 24 hours and later in a Memmert D-91126 forced circulation oven, at 110 ± 5 ° C for the same period. The sintering was performed in a Terrigeno MM80 muffle, with a heating ramp of 5 ° C by minute at maximum temperature of 950 °C for two hours. The determination of bulk density and percentage of water absorption was made according to the NTC 4321-3 standard. While the effective thermal conductivity (ke of the samples was measured using the TPS 2500 system, which uses the physical principle of the flat transient heat source (TPS, and the hot disk sensor. The results show that as the concentration diatomaceous earth increases, the density and the effective thermal conductivity decreases while the percentage of water absorption increases.

Local controls on sediment accumulation and distribution in a fjord in the West Antarctic Peninsula: implications for palaeoenvironmental interpretations

Directory of Open Access Journals (Sweden)

Yuribia P. Munoz

2016-08-01

Full Text Available We analyse surface sediment and its distribution in Flandres Bay, West Antarctic Peninsula, in order to understand modern day sediment dispersal patterns in a fjord with retreating, tidewater glaciers. The surface sediment descriptions of 41 cores are included in this study. The sediment facies described include muddy diatomaceous ooze, diatomaceous mud, pebbly mud, sandy mud and mud, with scattered pebbles present in most samples. In contrast to a traditional conceptual model of glacial sediment distribution in fjords, grain size in Flandres Bay generally coarsens from the inner to outer bay. The smallest grain size sediments were found in the bay head and are interpreted as fine-grained deposits resulting from meltwater plumes and sediment gravity flows occurring close to the glacier front. The middle of the bay is characterized by a high silt percentage, which correlates to diatom-rich sediments. Sediments in the outer bay have a high component of coarse material, which is interpreted as being the result of winnowing from currents moving from the Bellingshausen Sea into the Gerlache Strait. Palaeoenvironmental reconstructions of glacial environments often use grain size as an indicator of proximity to the ice margin. After a detailed analysis of a large number of cores collected in the study area, our findings highlight the variability in sedimentation patterns within a fjord and provide a valuable evidence of the complexity that may occur in the sedimentary record.

Radiostratigraphy and heavy mineral content of the Weches Formation (Eocene), Nacogdoches County, Texas

International Nuclear Information System (INIS)

Jobe, K.; Ledger, E.B.; Sharp, P.; Crocker, M.C.

1993-01-01

The Weches Formation of eastern Texas is a mudstone containing green sand-size clay aggregates. A vertical sequence of 43 samples was analyzed along an excavated cliff to determine radionuclide content. Samples average 5 ppm uranium and range from 2 to about 7 ppm. Thorium averages 20 ppm and ranges from 13 to almost 36 ppm. the gamma-ray spectrometer employed exhibits a certainty of about ±10% (one standard deviation) at the levels measured. Heavy mineral studies of mudstones are few, so one sample of the Weches mudstone was selected for heavy mineral separation and point counting of grain mounts. A total of 2606 grains were counted giving mineral percentages of zircon (28.8%), garnet (17.9%), tourmaline (10.5%), titanite (8.7%), apatite (7.6%), staurolite (6.4%), green hornblende (5.2%), epidote (5.1%), sillimanite (2.8%), monatite (2.2%), kyanite (1.9%), basaltic hornblende (1.5%), and biotite (1.3%). In addition, actinolite, spinel, rutile, and collophane were observed but not counted. Previous studies found a similar heavy mineral suite in the underlying Queen City Formation, but in different proportions. Differences in heavy mineral percentages probably reflect different water-flow regimes at the time of deposition. Heavy minerals in the Weches and Queen City formations are from the same general source area Measured radionuclide ratios are similar to granitic ratios and suggest that detrital heavy minerals, particularly zircon and monazite, are the main site of uranium and thorium and their decay products in the Weches Formation

Petrology and geochemistry of the Miocene-Pliocene fluvial succession, Katawaz Basin, Western Pakistan: Implications on provenance and source area weathering

DEFF Research Database (Denmark)

Kasi, Aimal K.; Kassi, Aktar Muhammad; Friis, Henrik

Petrology and geochemistry of sandstones and mudstones of the Miocene Dasht Murgha Group (DMG) and Pliocene Malthanai Formation (MF) of the Pishin Belt (Katawaz Basin), northwestern Pakistan have been carried out to find out their provenance and source area weathering. Sandstones of the Dasht...

Trophic structure and community stability in an overfished ecosystem

KAUST Repository

Utne-Palm, Anne Christine

2010-07-15

Since the collapse of the pelagic fisheries off southwest Africa in the late 1960s, jellyfish biomass has increased and the structure of the Benguelan fish community has shifted, making the bearded goby (Sufflogobius bibarbatus) the new predominant prey species. Despite increased prédation pressure and a harsh environment, the gobies are thriving. Here we show that physiological adaptations and antipredator and foraging behaviors underpin the success of these fish. In particular, body-tissue isotope signatures reveal that gobies consume jellyfish and sulphidic diatomaceous mud, transferring "dead-end" resources back into the food chain.

Geohydrological investigation of an uranium anomaly near Vanzylsrus in the Northern Cape Province

International Nuclear Information System (INIS)

Levin, M.; Talma, A.S.; Vogel, J.C.

1982-01-01

An anomaly, caused by low-grade uranium accumulations in organic-rich diatomaceous earth deposits, was located by an airborne radiometric survey near Vanzylsrus in the Northern Cape. Low-grade uraniferous calcrete also occurs in the vicinity of the anomaly. A significant uranium anomaly was found along the whole course of the palaeodrainage with the highest values occuring behind a dolerite dyke a few kilometres south of the confluence. A multidisciplinary approach in corporating geohydrology, water geochemistry, isotopic data and radiometric borehole logging studies was used to evaluate its potential

Trophic structure and community stability in an overfished ecosystem

KAUST Repository

Utne-Palm, Anne Christine; Salvanes, Anne Gro Vea; Currie, Bronwen; Kaartvedt, Stein; Nilsson, Gö ran E.; Braithwaite, Victoria A.; Stecyk, Jonathan A W; Hundt, Matthias; Van Der Bank, Megan G.; Flynn, Bradley A.; Sandvik, Guro Katrine; Klevjer, Thor Aleksander; Sweetman, Andrew K.; Brü chert, Volker; Pittman, Karin A.; Peard, Kathleen R.; Lunde, Ida Gjervold; Strandaba, R. A U; Gibbons, Mark J.

2010-01-01

Since the collapse of the pelagic fisheries off southwest Africa in the late 1960s, jellyfish biomass has increased and the structure of the Benguelan fish community has shifted, making the bearded goby (Sufflogobius bibarbatus) the new predominant prey species. Despite increased prédation pressure and a harsh environment, the gobies are thriving. Here we show that physiological adaptations and antipredator and foraging behaviors underpin the success of these fish. In particular, body-tissue isotope signatures reveal that gobies consume jellyfish and sulphidic diatomaceous mud, transferring "dead-end" resources back into the food chain.

La chaux et la diatomite comme moyens de lutte alternatifs contre Aethina tumida Murray (Coleoptera: Nitidulidae)

OpenAIRE

Buchholz , Sven; Merkel , Katharina; Spiewok , Sebastian; Pettis , Jeff S.; Duncan , Michael; Spooner-Hart , Robert; Ulrichs , Christian; RITTER , Wolfgang; Neumann , P.

2009-01-01

International audience; Aiming at alternative small hive beetle control, slaked lime, powdered limestone and diatomaceous earth (Fossil Shield® FS 95, FS 90.0 and FS 90.0s) were evaluated for their effects on pupation and adult emergence in the laboratory. Limestone, FS 90.0 and FS 95 showed no significant effect. Slaked lime in autoclaved soil prevented pupation, but was lethal only in high dosages of 10 and 15 g per 100 g soil. In non-autoclaved soil, low slaked lime dosages of 0.5 and 5 g ...

Fossil Scenedesmus (Chlorococcales) from the Raton Formation, Colorado and New Mexico, U.S.A.

Science.gov (United States)

Farley, Fleming R.

1989-01-01

Fossilized coenobia of the alga Scenedesmus (Chlorococcales) were recovered in palynomorph assemblages from a lower Paleocene mudstone in the Upper Cretaceous and Paleocene Raton Formation of Colorado and New Mexico. This is the first description of fossil Scenedesmus from Tertiary rocks. Two species, Scenedesmus tschudyi sp. nov. and Scenedesmus hanleyi sp. nov., are present in the assemblages. Coenobia of S. tschudyi sp. nov. are characterized by lunate terminal cells and fusiform median cells. As in species of modern Scenedesmus, coenobia of S. tschudyi sp. nov. occur with four or eight cells. Coenobia of S. hanleyi sp. nov. have four oval cells and are smaller than coenobia of S. tschudyi sp. nov. Fossil coenobia of Scenedesmus co-occur with the fossil alga Pediastrum in Raton Formation mudstones. Because these genera co-occur in modern lakes and ponds, the co-occurrence of fossil Scenedesmus and Pediastrum in ancient nonmarine rocks is interpreted to indicate deposition of sediment in freshwater lakes and ponds. ?? 1989.

A geological reconnaissance study of the Dyfi Valley region, Gwynedd/Powys, Wales

International Nuclear Information System (INIS)

Martin, B.A.; Howells, M.F.; Reedman, A.J.

1981-01-01

A collation of existing maps and data backed up by localised checking, reinterpretation and modification, employing sampling, structural measurements and aerial photograph interpretation, have updated the geological information available on the Dyfi Valley region. The region comprises an argillaceous-dominated Ordovician and Silurian sedimentary pile of approximately 4 km thickness. Thick formations of mudstones and silty mudstones with thin intercalations of silty sandstone and fine-grained sandstone predominate and exhibit fewer variations in thickness and extent than the subordinate formations with a higher proportion of sand-grade material. Three periods of deformation (D 1 -D 3 ) are distinguished, with the D 1 phase dominating the structure of the region by forming upright, asymmetrical, large (km) scale folds (F 1 ) of a NNE-SSW to NE-SW trend and producing an almost ubiquitous slaty cleavage (S 1 ). The succeeding deformations produced localised crenulation cleavages, kink bands and box folds. Data on the faulting and jointing associated with this deformation history are also presented. (author)

Application of base-level cycles to sandstone-type uranium deposit: taking Dongsheng uranium deposits as an example

International Nuclear Information System (INIS)

Yang Renchao; Han Zuozhen; Fan Aiping; Chang Xiangchun

2006-01-01

High-resolution sequence stratigraphy taking base-level cycles as interface of reference was developed rapidly in recent years. Its greatest predominance lies in that it can be applied to multi-controled continental sedimentary basins and can effectively improve accuracy and distinguishability of sequence stratigraphy analysis. Principles of base-level cycles can also be applied to the research and practice of the exploration and exploitation of sandstone-type uranium deposits as they control the spatial distribution, porosity, the permeability and the sealing ability of sandstone and mudstone, and stacking patterns of strata configuration. Taking Dongsheng uranium deposits as an example, the application of base-level cycles to exploration and exploitation of sandstone uranium deposits was analyzed. It is suggested that favorable strata framework of sandstone and mudstone was developed very well in the fluctuation of base-level cycles. Sand bodies were provided with good connectedness, coarse granularity, high debris content, low matrix content and good porosity-permeability becoming the most important uranium hosted strata. (authors)

Natural radiogenic heat production in the northeastern part of the North German Basin; Natuerliche radiogene Waermeproduktion im Nordostdeutschen Becken

Energy Technology Data Exchange (ETDEWEB)

Ullner, H A [GeoForschungsZentrum Potsdam (Germany)

1997-12-01

The radiogenic heat-production rate is a parameter that affects the thermal structure in the sedimentary cover. The parameter is important to warrant an extensive study. The first results gained in the northeastern part of the North German Basin show values in the range between 2.2 and 2.6 {mu}W/m{sup 3} in Permian mudstones in the Peckensen borehole and in the Bonese borehole (Altmark area). Comparable results were obtained in mudstones from a {gamma}-ray log measured in the Rheinsberg borehole (Brandenburg area). (orig.) [Deutsch] Die Untersuchung der thermischen Struktur des nordostdeutschen Beckens erfordert Kenntnisse ueber die radiogene Waermeproduktion der in zahlreichen Bohrungen aufgeschlossenen Sedimente. Die erste Ergebnisse eines am GFZ Postdam begonnenen Messprogrammes zeigen Waermeproduktionsraten im Bereich 2,2 bis 2,6 {mu}W/m{sup 3} in Tonsteinen des Perm in den Bohrungen Peckensen und Bonese (Altmark). Eine vergleichbare Waermeproduktion wurde anhand eines {gamma}-ray-Logs in Tonsteinen in der Bohrung Rheinsberg (Brandenburg) ermittelt. (orig.)

Water extraction of coals - potential for estimating low molecular weight organic acids as carbon feedstock for the deep terrestrial biosphere

Energy Technology Data Exchange (ETDEWEB)

Vieth, A.; Mangelsdorf, K.; Sykes, R.; Horsfield, B. [Geoforschungszentrum Potsdam, Potsdam (Germany)

2008-08-15

With the recent increasing interest in the deep biosphere, the question arises as to where the carbon sources that support deep microbial communities are derived from. Our research was focussed on the water-soluble, low molecular weight (LMW) organic acids that are potentially available from different sedimentary lithologies to serve as a carbon source to feed the deep biosphere. A series of Eocene-Pleistocene coals, mudstones and sandstones of varying rank (maturity) and total organic carbon (TOC) content from the Waikato Basin, New Zealand, has been Soxhlet-extracted using water. The combined concentration of recovered formate, acetate and oxalate range from 366 to 2499 {mu} g/g sediment and appear to be dependent on rank, organofacies and TOC. The yields indicate the potential of carbonaceous sediments to feed the local deep terrestrial biosphere over geological periods of time. The existence of living microbial organisms in the mudstones and sandstones was proved by the identification of intact phospholipids (PLs).

Development of swelling strain in smectite clays through exposure to carbon dioxide

NARCIS (Netherlands)

de Jong, S.M.; Spiers, C.J.; Busch, A.

2014-01-01

Smectites are common constituents of claystones, mudstones and shales and are often present in the caprocks and faults that seal potential CO2 storage reservoirs at depths up to 2 or even 3 km. Whilst the marked swelling behaviour of smectites caused by hydration through interlayer sorption of water

Probable late Messinian tsunamiites near Monte Dei Corvi, Italy, and the Nijar Basin, Spain: expected architecture of offshore tsunami deposits

NARCIS (Netherlands)

Smit, J.; Laffra, C.; Meulenaars, K.; Montanari, A.

2011-01-01

Three distinct, 30- to 80-cm-thick, graded, multilayered, coarse-grained sandstone layers, intercalated in the late Messinian mudstones of the Colombacci formation in Lago Mare facies of the Trave section are interpreted as tsunamiites (Ts1-Ts3). Each of these layers is sheet-like and could be

Journal of Earth System Science | Indian Academy of Sciences

Indian Academy of Sciences (India)

The presence of rill marks, flat-topped ripples, wrinkle marks, desiccation cracks and adhesion warts point to intertidal conditions with intermittent exposure. The high energy sandstone bars overlie a thick mudstone-dominated shelf sequence across a sharp interface indicating rapid change in the sea-level, provenance, rate ...

Research Article

African Journals Online (AJOL)

2016-06-18

Jun 18, 2016 ... Journal of Fundamental and Applied Sciences is licensed under a ... extraordinary wide and long region along the north–northeast edge of the Arabian plate. ..... within muddy carbonate sediments or as surface crusts on supratidal flats. ... Interbedded lime mudstones and layers with anhydrite or gypsum ...

Sedimentology and uranium prospecting of the Siwaliks in Western Nepal

International Nuclear Information System (INIS)

Nakajima, Terumasa

1982-01-01

The Siwaliks (Miocene to Pleistocene) distributed along the southern side of the Main Boundary Thrust in Nepal are composed of conglomerates, sandstones, mudstones and lignites. The lower and Middle Siwaliks show various kinds of cyclic repetition in their lithofacies and sedimentary structures. A generalized unit of the cycles consists of sandstones, mudstones and lignites from bottom to top. The sandstones are well-stratified and frequently cross-bedded while the mudstones exhibit massive aspect occasionally with lenticular bedding. In the unit, each lithofacies gradually change into overlying one whereas the boundaries between units are mostly discontinuous and erosional. These cyclic sedimentation, sedimentary structures and fossil evidence suggest the Siwaliks to have been deposited in coastal environments of a fresh water basin. The conglomerates of the Middle and Upper Siwaliks of the investigated area do not contain any High Himalayan rocks such as gneisses and granites. The composition of the conglomerates combined with the palaeocurrent data reveals the sediments to be derived mainly from the Lesser Himalayas just north of the Main Boundary Thrust. As in Pakistan, uranium deposits are expected to occur in the Siwalik sandstones in Nepal. In most places, however, the Siwaliks would have less possibility of uranium occurrence because the Lesser Himalayas do not contain big granite bodies from which uranium minerals are supposed to be originated. In the High Himalayas, granitic rocks are widely distributed, and three big rivers of Nepal have percolated through them and transported the sediments into the Siwalik basin from the ancient time. It seems to be more effective to concentrate our uranium prospecting to the area where these rivers have descended into the Siwalik basin. (author)

Th and U in the Paleozoic and Mesozoic systems of Kitakami range (preliminary report)

International Nuclear Information System (INIS)

Katada, Masato; Kanaya, Hiroshi; Sato, Choji.

1984-01-01

The research of Th and U in Kitakami range was commenced during the period of late 1950s and early 1960s. Following the exploration, the studies on Th and U in sedimentary rocks in Kitakami have been continued systematically. The data of Th and U covered whole Kitakami range by the addition of the newly obtained analytical data of northern part. The behaviors of Th and U during deposition and their contents in source rocks were studied by the analytical data. 75 samples of mudstone, sandstone, the matrix of conglomerate and limestone from south Kitakami, and 180 samples of mudstone, cherty clay stone, limestone, chert and green rock from northern part of Kitakami were analyzed. U/K 2 O ratio was constant regardless of the stratigraphy in the samples of southern Kitakami. This suggests that the major portion of U was initially dissolved in seawater, adsorbed by sericite, which is the only K 2 O -bearing mineral of sediment, and deposited. The values of Th and U in the sedimentary rocks in southern Kitakami were nearly the same as those of common sedimentary rocks in the world. It is supposed that the formation of K 2 O-bearing mineral was small, and the contents in source rocks affected. On the contrary, the Th values of sedimentary rocks in northern Kitakami, were higher than those of south, and it is supposed that this is attributable to the felsitic nature of source rocks. The mudstone of Matsumae, Hokkaido, differed from that of Kitakami, which means that they were not in same sedimentary basin. (Ishimitsu, A.)

The Shale Gas potential of Lower Carboniferous Sediments in Germany

Science.gov (United States)

Kerschke, D.; Mihailovic, A.; Schulz, H., -M.; Horsfield, B.

2012-04-01

Organic-rich Carboniferous sediments are proven source rocks for conventional gas systems in NW Europe and are likely gas shale candidates. Within the framework of GeoEnergie, an initiative to strengthen scientific excellence, funded by the German Ministry of Education and Research (BMBF), the influence of palaeogeography and basin dynamics on sedimentology and diagenesis is being investigated. Our aim is to unravel the evolution of shale gas-relevant properties which control gas prospectivity and production parameters like porosity, brittleness, etc. for the Lower Carboniferous in Germany. Northern Germany is underlain by thick, mudstone-bearing Carboniferous successions with a wide range of thermal maturities. Some of these mudstone horizons are rich in organic carbon which is either of marine and/or terrigenous origin. During the Carboniferous deposition of fine-grained, TOC-rich basinal sediments changed into shallow marine to paralic siliciclastic sediments (carbonates during the Lower Carboniferous) in the north, and grade into coarse-grained sediments close to the uprising Variscan mountains in the south. As a result different architectural elements including TOC-rich fine-grained sediments like basinal shales, fine-grained parts of turbidites, and shallow marine mudstones occur in both the Lower and the Upper Carboniferous section. A high shale gas potential occurs in basinal shales of Namurian age with marine organic material and TOC contents of up to 8 % (Rhenish Alum Shales). Such sediments with thermal maturities between 1.3 to 3.0 % vitrinite reflectance and sufficient quartz contents occur in wide areas of present-day Central European Basins System (CEBS), and are at favourable depth for shale gas exploration predominantly along the southern CEBS margin.

Arsenic species determination in human scalp hair by pressurized hot water extraction and high performance liquid chromatography-inductively coupled plasma-mass spectrometry.

Science.gov (United States)

Morado Piñeiro, Andrés; Moreda-Piñeiro, Jorge; Alonso-Rodríguez, Elia; López-Mahía, Purificación; Muniategui-Lorenzo, Soledad; Prada-Rodríguez, Darío

2013-02-15

Analytical methods for the determination of total arsenic and arsenic species (mainly As(III) and As(V)) in human scalp hair have been developed. Inductively coupled plasma-mass spectrometry (ICP-MS) and high performance liquid chromatography (HPLC) coupled to ICP-MS have been used for total arsenic and arsenic species determination, respectively. The proposed methods include a "green", fast, high efficient and automated species leaching procedure by pressurized hot water extraction (PHWE). The operating parameters for PHWE including modifier concentration, extraction temperature, static time, extraction steps, pressure, mean particle size, diatomaceous earth (DE) mass/sample mass ratio and flush volume were studied using design of experiments (Plackett-Burman design PBD). Optimum condition implies a modifier concentration (acetic acid) of 150 mM and powdered hair samples fully mixed with diatomaceous earth (DE) as a dispersing agent at a DE mass/sample mass ratio of 5. The extraction has been carried out at 100°C and at an extraction pressure of 1500 psi for 5 min in four extraction step. Under optimised conditions, limits of quantification of 7.0, 6.3 and 50.3 ng g(-1) for total As, As(III) and As(V), respectively were achieved. Repeatability of the overall procedure (4.4, 7.2 and 2.1% for total As, As(III) and As(V), respectively) was achieved. The analysis of GBW-07601 (human hair) certified reference material was used for validation. The optimised method has been finally applied to several human scalp hair samples. Copyright © 2012 Elsevier B.V. All rights reserved.

Source-to-Sink System Evolution as Recorded in Clastic Facies in Two New Zealand Examples: the Bounty System of South Island and the Waipaoa System of North Island

Science.gov (United States)

Marsaglia, K. M.

2010-12-01

New Zealand river sources and their submarine sinks are excellent examples for modeling source-to-sink systems. In particular, the sand fractions of these systems can be used as tracers to document links and/or disconnects between fluvial, shelf, slope, and bathyal components. Within any given system, the ability to use sand as a tracer depends on the nature of the rocks exposed in source river drainage basins. In evolving systems, the potential for erosional unroofing, change of outcrop lithology through time, can be important. Additionally, the ability of a given lithology to generate sediment of a certain size may also vary. For example in the New Zealand examples, Cenozoic mudstones generate mostly mud but can liberate recycled sand grains (if present), as well as a smaller proportion of mudstone lithic fragments depending on degree of mudstone induration; schist generates copious sand and quartz-vein pebbles; and thin-bedded sandy turbidites can generate significant gravel, as well as mud and sand. Sediment production mode also comes into play with glacial processes (South Island) generating rock flour, as well as coarser debris. The major outcropping unit across both islands is a sedimentary to metasedimentary forearc succession, the Torlesse Terrane. It served as the protolith of the Otago schist (South Island) and the source of detritus for Cretaceous and Cenozoic sedimentary units on both islands. Local magmatism also supplied sand-sized material: intraplate (South Island) volcanism produced intrabasinal epiclastic debris and magmatic arc (North Island) volcanism produced extrabasinal pyroclastic debris. Various lithologies have characteristic detrital signatures. For example, in the Cenozoic units of the Waipaoa system, Pliocene calcareous mudstone fragments are key lithic components in tracing sediment transport from source-to sink, whereas the major fingerprint of Otago schist input into the Bounty System of South Island is mica. Critical to defining

Diffusion and retention of organic anions in Callovian-Oxfordian clay rock

International Nuclear Information System (INIS)

Rasamimanana, Sabrina

2016-01-01

The Callovo-Oxfordian mud-stone (CO_x) is studied as a possible host rock for a deep disposal of radioactive waste (Cigeo project). Indeed, besides being very weakly permeable, it presents a high content of clayey minerals, capable of retaining radionuclides under cationic form and to delay strongly their transport. Nevertheless, some waste packages may release a significant amount of organic molecules, capable of complexing these radionuclides and drastically increase their mobility. So, the objective of this work was to better understand the diffusive behavior of several organic molecules of interest in this mudstone, by investigating at first their affinity with the host rock. The retention of organic molecules under anionic form (acetate, phthalate, adipate, benzoate, and citrate) was quantified on to the dispersed CO_x mudstone using adsorption/desorption batch experiments. Experiments on de-carbonated rock and clay fraction only (≤ 2μm) were also performed to identify solid phases and chemical functions responsible for the retention. a correlation of the intensity of retention, R_d, was pointed out whit the dipole moment μ(Orga.), providing a qualitative estimate of retention capacity for polar hydrophilic organic molecules. So, phthalate, slightly polar, displays a reversible retention (R_d ≅1,6 L.kg"-"1), mainly on clayey phases. Citrate, very polar and strongly adsorbed (R_d ≅ 40 L.kg"-"1), displays a persistent desorption hysteresis and an affinity to different solid phases (clayey minerals and minor oxides). Lastly, acetate, adipate and benzoate, weakly polar, display a lower affinity with rock (R_d ≤ 0,2 L.kg"-"1). The diffusive behavior in compact rock of these organic anions was then studied. The effective diffusion coefficient and retardation factor values were quantified. The low diffusivity, [D_e/D_0](Organic Anions) ≅ 0,1 a0,25 * [D_e/D_0](Water) evidences an effect of anionic exclusion, with a same intensity as that observed for

Laboratory measurements of the solute transport properties of samples from the Bradwell, Elstow, Fulbeck and Killingholme site investigations

International Nuclear Information System (INIS)

Gilling, D.; Jefferies, N.L.; Lineham, T.R.

1987-12-01

The diffusivity and hydraulic conductivity of geological samples collected during the site investigations at Bradwell, Elstow, Fulbeck and Killingholme have been determined. Comparison between laboratory permeability measurements and in-situ permeability measurements for the mudstone units may give some indication of the importance of fissure flow at the sites. (author)

The Tournemire industrial analogue: reactive-transport modelling of cement-clay interfaces

International Nuclear Information System (INIS)

Watson, C.; Wilson, J.; Benbow, S.; Savage, D.; Walker, C.; Norris, S.

2012-01-01

, which remained in contact with the natural mud-stone for 15-20 years. Subsequently the boreholes have been over-cored, extracted and mineralogical characterisation has been performed. A reactive transport model of the Tournemire system has been set up using the general-purpose modelling tool QPAC (developed by Quintessa). Both the cement and mud-stone regions were represented in the model, which included aqueous speciation, kinetic models of mineral precipitation and dissolution and full coupling between porosity changes and transport of aqueous species. A solid solution model was used to represent the C-S-H gel in the cement section, with (tobermorite-like and jennite-like) C-S-H phases allowed to precipitate in the mud-stone. Full details can be found in Watson et al. (NDA RWMD Report QRS-1523A-1 v1.1, 2011). The main features observed at Tournemire were replicated by the model, including porosity variations and precipitation of carbonates, K-feldspar, ettringite and calcite. It was found that ion exchange needed to be included in order for C-S-H minerals to precipitate in the mud-stone, providing a better match with the mineralogical investigations. The inclusion of surface complexation processes on the montmorillonite present in the mud-stone, however, led to limited calcite growth at the cement-mud-stone interface; unlike samples taken from the Tournemire site that have a visible line of crusty carbonates along the interface. This perhaps indicates that surface complexation has not played an important role in the mineralogical evolution to date at Tournemire. This may be due to smectite (montmorillonite) not being the principal clay mineral in the mud-stone. This study was carried out as part of the Long-Term Cement Studies (LCS) project, an international collaboration between Posiva (Finland), JAEA (Japan), NDA (UK), SKB (Sweden) and Nagra (Switzerland) aimed at furthering the understanding of cement-rock interactions. (authors)

Lithostratigraphy of Upper Ordovician strata exposed in Kentucky

Science.gov (United States)

Weir, Gordon Whitney; Peterson, Warren Lee; Swadley, W.C.

1984-01-01

Creek Limestone in the western and central parts. In east-central Kentucky, the Grant Lake is classified as a member of the Ashlock Formation, an assemblage of lithologically distinct units that were combined to facilitate mapping in the southeastern and southern part of the region. The Ashlock consists of the following members, in ascending order: The Tate (calcitic and dolomitic mudstone), the Grant Lake, the Gilbert (micrograined limestone and shale), the Stingy Creek (nodular-bedded mudstone and limestone), the Terrill (dolomitic and calcitic mudstone), the Sunset (micrograined limestone), and the Reba (nodular-bedded limestone and shale). The Bull Fork Formation, which overlies the Grant Lake Limestone, is made up of subequal amounts of thin-bedded highly fossiliferous limestone and shale; limestone makes up about 80 percent of the basal part of the formation and decreases in abundance irregularly upward to only 20 percent of the top part. On the east side of the Blue Grass region, the Bull Fork grades into the Reba Member of the Ashlock Formation; on the west side, it grades into the Grant Lake. The uppermost formation in the region is the Drakes Formation, which in east-central Kentucky consists of the Rowland Member (calcitic to dolomitic mudstone) overlain by the Preachersville Member (dolomitic to calcitic mudstone and dolomite and dolomitic siltstone). In northeast Kentucky, the Drakes is represented by only the Preachersville Member. In most of central and north-central Kentucky, the formation consists of three members: the Rowland at the base (dolomitic mudstone to muddy limestone), the Bardstown (fossiliferous limestone and shale), and the Saluda Dolomite (dolomite, in part calcitic and muddy). In northern north-central Kentucky, the Drakes is represented by only the Saluda Dolomite Member. The top of the Ordovician sequence in the Blue Grass region is generally formed by members of the Drakes Formation, which are overlain by str

Remoção dos corantes azul brilhante, amarelo crepúsculo e amarelo tartrazina de soluções aquosas utilizando carvão ativado, terra ativada, terra diatomácea, quitina e quitosana: estudos de equilíbrio e termodinâmica

Directory of Open Access Journals (Sweden)

Guilherme Luiz Dotto

2011-01-01

Full Text Available This work compared activated carbon, activated earth, diatomaceous earth, chitin and chitosan to removal acid blue 9, food yellow 3 and FD&C yellow nº 5 dyes from aqueous solutions with different pH values (2-10. In the best process condition for each dye, equilibrium studies were carried out at different temperatures (from 298 to 328 K and Langmuir, Freundlich, Redlich-Peterson, Temkin and Dubinin-Radushkevich models were fitted with experimental data. In addition, entropy change, Gibbs free energy change and enthalpy change were obtained in order to verify the thermodynamic adsorption behavior.

Retrofitting and operation solid radwaste system Dresden Station, Units 2 and 3

International Nuclear Information System (INIS)

Testa, J.; Homer, J.C.

1982-01-01

Units 2 and 3 at Dresden Station are twin 794 MW (net) BWR units that became operational in 1970 and 1971. The waste streams are typical of BWR stations, namely, bead resin and filter sludge (powdered resins and diatomaceous earth), evaporator concentrate containing approximately 25% dissolved solids and dry active waste. The original solid radwaste system utilized cement for solidification in open top 55 gallon drums. Remote handling was provided by means of a monorail with moving platforms supporting the drums. A relatively light-weight compactor was used to compact DAW into 55 gallon drums. Difficulties were experienced with this system

Combination of diatomaceous earth and powder deltamethrin for insect control in stored corn Combinação de terra de diatomácea e deltametrina em pó para o controle de insetos em milho armazenado

Directory of Open Access Journals (Sweden)

Fabiane Cristina Ceruti

2005-12-01

Full Text Available The use of diatomaceous earth (DE is a very efficient insect control measure in stored grain IPM due to its low cost, easy application, reduction of active ingredient residues, lower environmental contamination and operator safety. The objective of this research was to evaluate the efficacy of different dosages of DE mixed with powder deltamethrin for controlling Sitophilus zeamais in stored corn. Samples of 100 g of clean and dry corn, in three replicates, were submitted to the following treatments: DE (Keepdry®, at the dosages of 500, 750 and 1000 g/t; powder deltamethrin (K-Obiol® at 0,5 g a.i. /t and 1,0 g a.i. /t; and combinations of the lowest and highest DE dosages with the two dosages of deltamethrin. Thirty adults of S. zeamais were placed in each vial with the treated grains and kept in environment chambers at 25ºC. Mortality was evaluated from the 1st to the 28th day. In the treatments mixing DE with deltamethrin or deltamethrin alone, the mortalyti was registered since the first day. In the treatments using only DE, the first dead insects were recorded after the 3rd day, especially in the highest dosages. After the 7th day, however, there was no statistical difference among all treatments, except for the lowest dosage of DE which reached a satisfactory control level only by the 14th day. It was concluded that treatments using DE combined with low dosages of powder deltamethrin represent an efficient control measure against S. zeamais in stored corn because insect mortality is faster than in treatments using DE alone and residues of active ingredients are much lower than using the insecticide in high dosages.O uso de terra de diatomácea (TD representa uma medida de controle importante em programas de MIP de armazenamento devido ao baixo custo, facilidade de aplicação, redução do nível de resíduos de ingrediente ativo e da contaminação ambiental e maior segurança para o operador. O objetivo desta pesquisa foi avaliar a

A natural analogue for copper waste canisters: The copper-uranium mineralised concretions in the Permian mudrocks of south Devon, United Kingdom

International Nuclear Information System (INIS)

Milodowski, A.E.; Styles, M.T.; Hards, V.L.

2000-08-01

This report presents the results of a small-scale pilot study of the mineralogy and alteration characteristics of unusual sheet-like native copper occurring together with uraniferous and vanadiferous concretions in mudstones and siltstones of the Permian Littleham Mudstone Formation, at Littleham Cove, south Devon, England. The host mudstones and siltstones are smectitic and have been compacted through deep Mesozoic burial. The occurrence of native copper within these rocks represents a natural analogue for the long-term behaviour of copper canisters, sealed in a compacted clay (bentonite) backfill, that will be used for the deep geological disposal of high-level radioactive waste by the SKB. The study was undertaken by the British Geological Survey (BGS) on behalf of SKB between November 1999 and June 2000. The study was based primarily on archived reference material collected by the BGS during regional geological and mineralogical surveys of the area in the 1970's and 1980's. However, a brief visit was made to Littleham Cove in January 2000 to try to examine the native copper in situ and to collect additional material. Unfortunately, recent landslips and mudflows obscured much of the outcrop, and only one new sample of native copper could be collected. The native copper occurs as thin plates, up to 160 mm in diameter, which occur parallel to bedding in the Permian Littleham Mudstone Formation at Littleham Cove (near Budleigh Salterton) in south Devon. Each plate is made up of composite stacks of individual thin copper sheets each 1-2 mm thick. The copper is very pure (>99.4% Cu) but is accompanied by minor amounts of native silver (also pure - >99%) which occurs as small inclusions within the native copper. Detailed mineralogical and petrological studies of the native copper sheets, using optical petrography, backscattered scanning electron microscopy, X-ray diffraction analysis and electron probe microanalytical techniques, reveal a complex history of

A natural analogue for copper waste canisters: The copper-uranium mineralised concretions in the Permian mudrocks of south Devon, United Kingdom

Energy Technology Data Exchange (ETDEWEB)

Milodowski, A.E.; Styles, M.T.; Hards, V.L. [Natural Environment Research Council (United Kingdom). British Geological Survey

2000-08-01

This report presents the results of a small-scale pilot study of the mineralogy and alteration characteristics of unusual sheet-like native copper occurring together with uraniferous and vanadiferous concretions in mudstones and siltstones of the Permian Littleham Mudstone Formation, at Littleham Cove, south Devon, England. The host mudstones and siltstones are smectitic and have been compacted through deep Mesozoic burial. The occurrence of native copper within these rocks represents a natural analogue for the long-term behaviour of copper canisters, sealed in a compacted clay (bentonite) backfill, that will be used for the deep geological disposal of high-level radioactive waste by the SKB. The study was undertaken by the British Geological Survey (BGS) on behalf of SKB between November 1999 and June 2000. The study was based primarily on archived reference material collected by the BGS during regional geological and mineralogical surveys of the area in the 1970's and 1980's. However, a brief visit was made to Littleham Cove in January 2000 to try to examine the native copper in situ and to collect additional material. Unfortunately, recent landslips and mudflows obscured much of the outcrop, and only one new sample of native copper could be collected. The native copper occurs as thin plates, up to 160 mm in diameter, which occur parallel to bedding in the Permian Littleham Mudstone Formation at Littleham Cove (near Budleigh Salterton) in south Devon. Each plate is made up of composite stacks of individual thin copper sheets each 1-2 mm thick. The copper is very pure (>99.4% Cu) but is accompanied by minor amounts of native silver (also pure - >99%) which occurs as small inclusions within the native copper. Detailed mineralogical and petrological studies of the native copper sheets, using optical petrography, backscattered scanning electron microscopy, X-ray diffraction analysis and electron probe microanalytical techniques, reveal a complex history of

Alteration of uraniferous and native copper concretions in the Permian mudrocks of south Devon, United Kingdom

Energy Technology Data Exchange (ETDEWEB)

Milodowski, A.E.; Styles, M.T.; Horstwood, M.S.A.; Kemp, S.J. [British Geological Survey, Nottingham (United Kingdom)

2002-03-01

This report presents the results of a study of the mineralogy and alteration characteristics of unusual concretions containing sheets of native copper, and uranium-vanadium mineralised concretions, in mudstones and siltstones of the Pennian Littleham Mudstone Formation, at Littleham Cove, south Devon, England. The main objectives of the study were: 1. To investigate the corrosion characteristics of the native copper as a natural analogue for the long-term behaviour of copper canisters, sealed in a compacted clay (bentonite) backfill, that will be used for the deep geological disposal of spent fuel and high-level radioactive waste (HLW). This study developed from an earlier pilot study, which demonstrated that the alteration of the native copper in the concretions from Littleham Cove was mineralogically and chemically complex. 2. To investigate the alteration and oxidation of minerals containing reduced species (e.g. ferrous iron) within the uranium-rich concretions as a natural analogue for the potential effects of oxidation induced by alpha-radiolysis of water in a HLW repository environment. Native copper-bearing concretions in the Littleham Mudstone Formation are very rare. They occur, as thin lenticular disks developed largely along bedding lamina and thin low-angle fractures cutting the bedding laminae the upper part of the formation, about 10 m below the top of the formation. This part of the sequence comprises laterally discontinuous, fine-grained sheet-flood and channel sandstones and siltstones. Some of these sandstones, are more extensively-cemented by copper sulphides (mainly chalcocite), copper arsenides, cobalt-nickel arsenides, and uranium silicate. The thin permeable sandstones and siltstones, and fractures zones around small faults appear to have acted as the conduits for the movement of mineralising fluids through the mudstones. The native copper sheets all show a similar pattern of corrosion and alteration. However, the intensity of alteration is

National Uranium Resource Evaluation: Cortez quadrangle, Colorado and Utah

Energy Technology Data Exchange (ETDEWEB)

Campbell, J A

1982-09-01

Six stratigraphic units are recognized as favorable for the occurrence of uranium deposits that meet the minimum size and grade requirements of the U.S. Department of Energy in the Cortez 1/sup 0/ x 2/sup 0/ Quadrangle, Utah and Colorado. These units include the Jurassic Salt Wash, Recapture, and Brushy Basin Members of the Morrison Formation and the Entrada Sandstone, the Late Triassic Chinle Formation, and the Permian Cutler Formation. Four areas are judged favorable for the Morrison members which include the Slick Rock, Montezuma Canyon, Cottonwood Wash and Hatch districts. The criteria used to determine favorability include the presence of the following (1) fluvial sandstone beds deposited by low-energy streams; (2) actively moving major and minor structures such as the Paradox Basin and the many folds within it; (3) paleostream transport directions approximately perpendicular to the trend of many of the paleofolds; (4) presence of favorable gray lacustrine mudstone beds; and (5) known uranium occurrences associated with the favorable gray mudstones. Two areas of favorability are recognized for the Chinle Formation. These areas include the Abajo Mountain and Aneth-Ute Mountain areas. The criteria used to determine favorability include the sandstone-to-mudstone ratio for the Chinle Formation and the geographic distribution of the Petrified Forest Member of the Chinle Formation. Two favorable areas are recognized for the Cutler Formation. Both of these areas are along the northern border of the quadrangle between the Abajo Mountains and the Dolores River Canyon area. Two areas are judged favorable for the Entrada Sandstone. One area is in the northeast corner of the quadrangle in the Placerville district and the second is along the eastern border of the quadrangle on the southeast flank of the La Plata Mountains.

Characterization and quantification of suspended sediment sources to the Manawatu River, New Zealand.

Science.gov (United States)

Vale, S S; Fuller, I C; Procter, J N; Basher, L R; Smith, I E

2016-02-01

Knowledge of sediment movement throughout a catchment environment is essential due to its influence on the character and form of our landscape relating to agricultural productivity and ecological health. Sediment fingerprinting is a well-used tool for evaluating sediment sources within a fluvial catchment but still faces areas of uncertainty for applications to large catchments that have a complex arrangement of sources. Sediment fingerprinting was applied to the Manawatu River Catchment to differentiate 8 geological and geomorphological sources. The source categories were Mudstone, Hill Subsurface, Hill Surface, Channel Bank, Mountain Range, Gravel Terrace, Loess and Limestone. Geochemical analysis was conducted using XRF and LA-ICP-MS. Geochemical concentrations were analysed using Discriminant Function Analysis and sediment un-mixing models. Two mixing models were used in conjunction with GRG non-linear and Evolutionary optimization methods for comparison. Discriminant Function Analysis required 16 variables to correctly classify 92.6% of sediment sources. Geological explanations were achieved for some of the variables selected, although there is a need for mineralogical information to confirm causes for the geochemical signatures. Consistent source estimates were achieved between models with optimization techniques providing globally optimal solutions for sediment quantification. Sediment sources was attributed primarily to Mudstone, ≈38-46%; followed by the Mountain Range, ≈15-18%; Hill Surface, ≈12-16%; Hill Subsurface, ≈9-11%; Loess, ≈9-15%; Gravel Terrace, ≈0-4%; Channel Bank, ≈0-5%; and Limestone, ≈0%. Sediment source apportionment fits with the conceptual understanding of the catchment which has recognized soft sedimentary mudstone to be highly susceptible to erosion. Inference of the processes responsible for sediment generation can be made for processes where there is a clear relationship with the geomorphology, but is problematic for

National Uranium Resource Evaluation: Cortez quadrangle, Colorado and Utah

International Nuclear Information System (INIS)

Campbell, J.A.

1982-09-01

Six stratigraphic units are recognized as favorable for the occurrence of uranium deposits that meet the minimum size and grade requirements of the U.S. Department of Energy in the Cortez 1 0 x 2 0 Quadrangle, Utah and Colorado. These units include the Jurassic Salt Wash, Recapture, and Brushy Basin Members of the Morrison Formation and the Entrada Sandstone, the Late Triassic Chinle Formation, and the Permian Cutler Formation. Four areas are judged favorable for the Morrison members which include the Slick Rock, Montezuma Canyon, Cottonwood Wash and Hatch districts. The criteria used to determine favorability include the presence of the following (1) fluvial sandstone beds deposited by low-energy streams; (2) actively moving major and minor structures such as the Paradox Basin and the many folds within it; (3) paleostream transport directions approximately perpendicular to the trend of many of the paleofolds; (4) presence of favorable gray lacustrine mudstone beds; and (5) known uranium occurrences associated with the favorable gray mudstones. Two areas of favorability are recognized for the Chinle Formation. These areas include the Abajo Mountain and Aneth-Ute Mountain areas. The criteria used to determine favorability include the sandstone-to-mudstone ratio for the Chinle Formation and the geographic distribution of the Petrified Forest Member of the Chinle Formation. Two favorable areas are recognized for the Cutler Formation. Both of these areas are along the northern border of the quadrangle between the Abajo Mountains and the Dolores River Canyon area. Two areas are judged favorable for the Entrada Sandstone. One area is in the northeast corner of the quadrangle in the Placerville district and the second is along the eastern border of the quadrangle on the southeast flank of the La Plata Mountains

Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity During the Prime Mission: Implications for Diagenesis

Science.gov (United States)

Rampe, Elizabeth B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T. F.; Chipera, S. J.; Blake, D. F.; Ming, D. W.; Farmer, J. D.; Morrison, S. M.;

Study of flux and mud stone with potential for using in porcelainized stoneware tile compositions; Estudo de fundente e argilito com potencial para uso em formulacoes de porcelanato

Energy Technology Data Exchange (ETDEWEB)

Hoffmann, F.S.; Santos, G. dos; Morelli, M.R., E-mail: felipesh@gmail.com [Departamento de Engenharia de Materiais, Universidade Federal de S. Carlos - UFSCar, S. Carlos, SP (Brazil)

2012-04-15

The porcelain tile is distinguished in the current market for ceramic tiles, with excellent technical and esthetic characteristics. In the present study traditional ceramic raw materials were selected and a standard formulation conventionally reported in the literature was adopted aiming to replace the melting phase (feldspar) of the composition for a raw material that forms liquid phase at high temperature, and replacement of the clay fraction by a mudstone of lower refractoriness. The aim of this study was to evaluate the use of these materials as alternative techniques and lower cost, since, in a mass of porcelain tile, the amount of flux is very large (representing approximately 50% of total raw materials used). The nepheline syenite was the natural raw material selected to replace the feldspar due to the fact that it belongs to the family of feldspathoids, and has similar physicochemical characteristics, therefore, a high fluxing efficiency. To replace the clay fraction was chosen a mudstone naturally occurring, abundant in the region of Santa Gertrudes, SP. Substitutions to the feldspar and clay fraction were completely and/or partially by means of combinations between the flux and mud stones. The masses were processed from the mixing of powders, wet milling, drying, disagglomeration, compaction and firing. In addition to the vitrification curves, techniques such as dilatometry, measurements of porosity, flexure strength test, electron microscopy and X-ray diffraction were used to characterize the material after firing at various temperatures. The results showed that, in principle, it is possible the combination of raw materials such as nepheline and mudstone to replace potassium feldspar and S. Simao clay, as they provide the vitrification at lower temperatures. Compositions with both materials showed lower values of water absorption (<0.1%) and high mechanical strength (> 45 MPa), despite higher pyroplastic strain at 1150 deg C (author)

Sedimentology and ichnology of Neogene Coastal Swamp deposits in the Niger Delta Basin, Nigeria

Directory of Open Access Journals (Sweden)

Ezeh Sunny C.

2016-09-01

Full Text Available Often analyses of depositional environments from sparse data result in poor interpretation, especially in multipartite depositional settings such as the Niger Delta. For instance, differentiating channel sandstones, heteroliths and mudstones within proximal environments from those of distal facies is difficult if interpretations rely solely on well log signatures. Therefore, in order to achieve an effective and efficient interpretation of the depositional conditions of a given unit, integrated tools must be applied such as matching core descriptions with wireline log signature. In the present paper cores of three wells from the Coastal Swamp depositional belt of the Niger Delta are examined in order to achieve full understanding of the depositional environments. The well sections comprise cross-bedded sandstones, heteroliths (coastal and lower shoreface and mudstones that were laid down in wave, river and tidal processes. Interpretations were made from each data set comprising gamma ray logs, described sedimentological cores showing sedimentary features and ichnological characteristics; these were integrated to define the depositional settings. Some portions from one of the well sections reveal a blocky gamma ray well log signature instead of a coarsening-upward trend that characterises a shoreface setting while in other wells the signatures for heteroliths at some sections are bell blocky in shaped rather than serrated. Besides, heteroliths and mudstones within the proximal facies and those of distal facies were difficult to distinguish solely on well log signatures. However, interpretation based on sedimentology and ichnology of cores from these facies was used to correct these inconsistencies. It follows that depositional environment interpretation (especially in multifarious depositional environments such as the Niger Delta should ideally be made together with other raw data for accuracy and those based solely on well log signatures should

Sedimentology of Hirnantian glaciomarine deposits in the Balkan Terrane, western Bulgaria: Fixing a piece of the north peri-Gondwana jigsaw puzzle

Science.gov (United States)

Chatalov, Athanas

2017-04-01

Glaciomarine deposits of late Hirnantian age in the western part of the Palaeozoic Balkan Terrane have persistent thickness ( 7 m) and lateral uniformity in rock colour, bedding pattern, lithology, and sedimentary structures. Four lithofacies are distinguished from base to top: lonestone-bearing diamictites, interbedded structureless mudstones, crudely laminated diamictites, and finely laminated mudstones. The diamictites are clast-poor to clast-rich comprising muddy to sandy varieties. Their compositional maturity is evidenced by the very high amount of detrital quartz compared to the paucity of feldspar and unstable lithic grains. Other textural components include extraclasts derived from the local Ordovician basement, mudstone intraclasts, and sediment aggregates. Turbate structures, grain lineations, and soft sediment deformation of the matrix below larger grains are locally observed. Sedimentological analysis reveals that deposition occurred in an ice-intermediate to ice-distal, poorly agitated shelf environment by material supplied from meltwater buoyant plumes and rain-out from ice-rafted debris. Remobilization by mass-flow processes (cohesive debris flows and slumps) was an important mechanism particularly for the formation of massive diamictites. The glaciomarine deposits represent a typical deglaciation sequence reflecting retreat of the ice front (grounded or floating ice sheet), relative sea-level rise and gradually reduced sedimentation rate with increasing contribution from suspension fallout. This sequence was deposited on the non-glaciated shelf of the intracratonic North Gondwana platform along the southern margin of the Rheic Ocean. The Hirnantian strata of the Balkan Terrane can be correlated with similar glaciomarine deposits known from peri-Gondwana terranes elsewhere in Europe showing clear 'Armorican affinity'. Several lines of evidence suggest that the provenance of siliciclastic material was associated mainly with sedimentary recycling of

A lithology identification method for continental shale oil reservoir based on BP neural network

Science.gov (United States)

Han, Luo; Fuqiang, Lai; Zheng, Dong; Weixu, Xia

2018-06-01

The Dongying Depression and Jiyang Depression of the Bohai Bay Basin consist of continental sedimentary facies with a variable sedimentary environment and the shale layer system has a variety of lithologies and strong heterogeneity. It is difficult to accurately identify the lithologies with traditional lithology identification methods. The back propagation (BP) neural network was used to predict the lithology of continental shale oil reservoirs. Based on the rock slice identification, x-ray diffraction bulk rock mineral analysis, scanning electron microscope analysis, and the data of well logging and logging, the lithology was divided with carbonate, clay and felsic as end-member minerals. According to the core-electrical relationship, the frequency histogram was then used to calculate the logging response range of each lithology. The lithology-sensitive curves selected from 23 logging curves (GR, AC, CNL, DEN, etc) were chosen as the input variables. Finally, the BP neural network training model was established to predict the lithology. The lithology in the study area can be divided into four types: mudstone, lime mudstone, lime oil-mudstone, and lime argillaceous oil-shale. The logging responses of lithology were complicated and characterized by the low values of four indicators and medium values of two indicators. By comparing the number of hidden nodes and the number of training times, we found that the number of 15 hidden nodes and 1000 times of training yielded the best training results. The optimal neural network training model was established based on the above results. The lithology prediction results of BP neural network of well XX-1 showed that the accuracy rate was over 80%, indicating that the method was suitable for lithology identification of continental shale stratigraphy. The study provided the basis for the reservoir quality and oily evaluation of continental shale reservoirs and was of great significance to shale oil and gas exploration.

Influence of lithological characters of coal bearing formation on stability of roof of coal seams

Energy Technology Data Exchange (ETDEWEB)

Meng Zhao-ping; Peng Su-ping; Li Guo-qing; Huang Wei; Lu Jun; Lei Zhi-yong [CUMT, Beijing (China). School of Resources and Safety Engineering

2003-07-01

Lithology is one of the important factors influencing the stability of roof of coal seams. In order to investigate this, the phenomenon of underground pressure and distribution of pressure were studied by using the local observation and simulation test with similar materials. The observation results show that the distance of initial weighting and periodic weighting of the mudstone roof is shorter than that of sandstone roofs. The sandstone roof with a high strength has a longer distance of initial weighting and periodic weighting, the abutment stress on the working face is big and the height of caving and fracture zone is high. The peak point of abutment stress in the sandstone roof is near to the working face and the pressure bump is inclined to occur. The result is contrary to that in case of the mudstone roof with a low strength. While in the transition zone of nipped sandstone, roof rock-mass is broken and is poor in stability, therefore, it is difficult to hold the roof.

The sedimentology of uranium-bearing sandstones on the Waterval portion of the farm Brandewyns Gat 214, Beaufort West area

International Nuclear Information System (INIS)

Cole, D.I.

1980-08-01

The sedimentology of two uranium-bearing sandstones on the Waterval portion of the farm Brandewyns Gat 214 was studied by means of 36 vertical profiles measured across, through and adjacent to 4 mineralised deposits. The vertical profiles basically consist of a succession of sedimentary facies. A total of 19 facies was recognised within the fluvial sandstone sequence according to the criteria of grain-size and sedimentary structure. Transitions between the facies were subjected to a Markov chain analysis in order to delineate Markov-dependent transitions. Uranium mineralisation occurs mostly within the lower half of the fluvial sandstone sequence and is confined to the coarser-grained sedimentary facies. These facies probably acted as suitable aquifers for the transport of uraniferous solutions and permeability differences between the sandstone and the underlying mudstone and siltstone must have restricted these solutions to the lower half of the channel sandstone. The massive mudstone facies contains 13 per cent of the total cumulative thickness of mineralisation. This mineralisation probably originated from synchronously deposited tuffaceous material. Subsequent migration of uraniferous solutions may have concentrated the uranium

Synthesis of Akaganeite in the Presence of Sulfate: Implications for Akaganeite Formation in Yellowknife Bay, Gale Crater, Mars

Science.gov (United States)

Peretyazhko, T. S.; Fox, A.; Sutter, B.; Niles, P. B.; Adams, M.; Morris, R. V.; Ming, D. W.

2016-01-01

Akaganeite (beta-FeOOH) is an Fe(III) (hydr)oxide with a tunnel structure usually occupied by chloride. Akaganeite has been recently discovered in a mudstone on the surface of Mars by the Chemistry and Mineralogy (CheMin) and Sample Analysis at Mars (SAM) instruments onboard the Mars Science Laboratory (MSL) Curiosity Rover in Gale crater [1, 2]. Akaganeite was detected together with sulfate minerals [anhydrite (CaSO4) and basanite (2CaSO4·2H2O)] in the drilled Cumberland and John Clein mudstone samples at Yellowknife Bay [2]. Discovery of akaganeite and sulfates in the same samples suggests that sulfate ions could be present in aqueous solution during akaganeite formation. However, mechanism and aqueous environmental conditions of akaganeite formation (e.g., pH and range of sulfate concentration) in Yellowknife Bay remain unknown. The objective of our work was to perform synthesis of akaganeite without or with sulfate addition at variable pHs in order to constrain formation conditions of akaganeite in Yellowknife Bay, Gale crater on Mars.

Expressway construction in landslide areas. ; Construction work between Fujioka interchange and Saku interchange of Joshin'etsu expressway. Ugoku yama wo tsuranuku. ; Joshin'etsu Jidoshado Fujioka IC/Saku IC kan kensetsu koji

Energy Technology Data Exchange (ETDEWEB)

Togo, Y [Japan Highway Public Corp., Tokyo (Japan)

1993-03-15

The Joshin'etsu motorway is a 204km expressway. Various technological studies have been made for the remediation work for the 69.5km section which is opened to traffic this spring, because not only a series of tunnels, bridges, long cut and fill soil particular to mountain roads are included but also the section has many landslide areas. The length of the Higureyama tunnel is 2,314m. Although strong andesite is prevailing as the nature of the soil, the central area of the tunnel is consisted of brittle mudstone and self-crushing andesite with faults because the tunnel runs through the lower portion of a landslide zone. The mudstone is a squeezing ground, and buckling of H supporting, breakage of lock bolts, and damage of sprayed concrete occurred in many places. 2 years and 10 months are required for the construction of the tunnel. The average monthly drilling is only 10m/month which is an unprecedented case in tunnel excavation. Even limited to large-scale landslides, 13 occurrences are experienced. 10 figs., 1 tab.

Braidplain, floodplain and playa lake, alluvial-fan, aeolian and palaeosol facies composing a diversified lithogenetical sequence in the permian and triassic of South Devon (England)

Science.gov (United States)

Mader, Detlef

The Permian and Triassic of South Devon (England) are a continental red bed sequence of very diversified lithogenetical composition. Within the thick series, the distribution of the main depositional environments being fluvial braidplain, fluvial floodplain and playa lake, alluvial fan, aeolian dune and calcrete palaeosol changes repeatedly in both horizontal and vertical direction. Significant sedimentary milieus such as aeolian dunes and calcrete palaeosols occur repeatedly within the succession, but are also lacking in several parts of the sequence. Fluvial braidplain deposits comprise conglomerates, sandstones, intraformational reworking horizons and mudstones and originate in channels and overbank plains of a braided river system. Conglomerates and sandstones are formed by migration of bars and spreading out of sheets during infilling of streams and aggradation of flats. Gravel is often enriched as lag pockets or veneers within steeper scour holes and kolk pots or on the plane floor of the watercourse. Finer-grained sandstones and mudstones are laid down by suspension settling in stagnant water bodies such as small lakes in the overbank area and residual pools in interbar depressions during low-stage or waning-flow in active channels or in abandoned streams. Spectacular bioturbation features in some sandstones with both horizontal tubes and vertical burrows testify to the colonization of the sediments at the bottom of the rivers with declining discharge and transport capacity. Intraformational reworking horizons with ghost-like remnants of degraded sandstones, mudstones and pedogenic carbonates document partially severe condensation of the sequence by removal of some facies elements from the depositional record. The occasionally occurring gravel-bearing mudstones or silty-clayey sandstones represent products of high-energy water surges overspilling the channel banks and transporting sandy and gravelly bed-load in limited amounts beyond the levee wall. The

Volatile and organic compositions of sedimentary rocks in Yellowknife Bay, Gale Crater, Mars

NARCIS (Netherlands)

Ming, D.W.; Archer Jr., P.D.; Glavin, D.P.; Eigenbrode, J.L.; Franz, H.B.; Sutter, B.; Brunner, A.E.; Stern, J.C.; Freissinet, C.; McAdam, A.C.; Mahaffy, P.R.; Cabane, M.; Coll, P.; Campbell, J.L.; Atreya, S.K.; Niles, P.B.; Bell III, J.F.; Bish, D.L.; Brinckerhoff, W.B.; Buch, A.; Conrad, P.G.; Des Marais, D.J.; Ehlmann, B.L.; Fairén, A.G.; Farley, K.; Flesch, G.J.; Francois, P.; Gellert, R.; Grant, J.A.; Grotzinger, J.P.; Gupta, S.; Herkenhoff, K.E.; Hurowitz, J.A.; Leshin, L.A.; Lewis, K.W.; McLennan, S.M.; Miller, K.E.; Moersch, J.; Morris, R.V.; Navarro-González, R.; Pavlov, A.A.; Perrett, G.M.; Pradler, I.; Squyres, S.W.; Summons, R.E.; Steele, A.; Stolper, E.M.; Sumner, D.Y.; Szopa, C.; Teinturier, S.; Trainer, M.G.; Treiman, A.H.; Vaniman, D.T.; Vasavada, A.R.; Webster, C.R.; Wray, J.J.; Yingst, R.A.; MSL Science Team, the|info:eu-repo/dai/nl/292012217

2014-01-01

H2O, CO2, SO2, O2, H2, H2S, HCl, chlorinated hydrocarbons, NO, and other trace gases were evolved during pyrolysis of two mudstone samples acquired by the Curiosity rover at Yellowknife Bay within Gale crater, Mars. H2O/OH-bearing phases included 2:1 phyllosilicate(s), bassanite, akaganeite, and

Use of geophysical methods for determination of physico-mechanical properties of coal-bearing rocks in wells of the Vorkutskoye field

International Nuclear Information System (INIS)

Grechukhin, V.V.; Iokhin, S.B.; Baklanov, V.G.; Chernikov, A.G.

1974-01-01

The total porosity (P), electric resistivity (Er), density, bulk density, water content, velocity of longitudinal elastic waves (Vl), intensity of natural γ-radiation, and polarization self-potential (Ps) are determined of the lithol. different interlayered sandstones, argillites, mudstones, siltstones, and concretions. A direct linear correlation exists between these parameters and the mineralogical composition, coefficient of sorting, and sedimentation conditions

On-capillary sample cleanup method for the electrophoretic determination of carbohydrates in juice samples.

Science.gov (United States)

Morales-Cid, Gabriel; Simonet, Bartolomé M; Cárdenas, Soledad; Valcárcel, Miguel

2007-05-01

On many occasions, sample treatment is a critical step in electrophoretic analysis. As an alternative to batch procedures, in this work, a new strategy is presented with a view to develop an on-capillary sample cleanup method. This strategy is based on the partial filling of the capillary with carboxylated single-walled carbon nanotube (c-SWNT). The nanoparticles retain interferences from the matrix allowing the determination and quantification of carbohydrates (viz glucose, maltose and fructose). The precision of the method for the analysis of real samples ranged from 5.3 to 6.4%. The proposed method was compared with a method based on a batch filtration of the juice sample through diatomaceous earth and further electrophoretic determination. This method was also validated in this work. The RSD for this other method ranged from 5.1 to 6%. The results obtained by both methods were statistically comparable demonstrating the accuracy of the proposed methods and their effectiveness. Electrophoretic separation of carbohydrates was achieved using 200 mM borate solution as a buffer at pH 9.5 and applying 15 kV. During separation, the capillary temperature was kept constant at 40 degrees C. For the on-capillary cleanup method, a solution containing 50 mg/L of c-SWNTs prepared in 300 mM borate solution at pH 9.5 was introduced for 60 s into the capillary just before sample introduction. For the electrophoretic analysis of samples cleaned in batch with diatomaceous earth, it is also recommended to introduce into the capillary, just before the sample, a 300 mM borate solution as it enhances the sensitivity and electrophoretic resolution.

RESFRIAMENTO ARTIFICIAL E USO DE TERRA DE DIATOMÁCEA PARA O CONTROLE DE INSETOS EM GRÃOS DE TRIGO ARMAZENADOS EM SILOS DE CONCRETO

Directory of Open Access Journals (Sweden)

Marcus Bochi da Silva Volk

2009-01-01

Full Text Available The objective of this study was to evaluate the effectiveness of artificial cooling associated with the use of diatomaceous earth to control insects in grains of wheat stored in concrete silos. We used two concrete silos, with a static capacity of 2.500 t (Silo A and the other with static capacity of 5.000 t (Silo B. The surface of the grain silos were treated with diatom earth with a commercial assay (1.0 kg / t of product. For the cooling of the grains, cold air was blown through the aeration system silos until the grains reach a temperature of 17 ° C between the layers. After cooling, it is the retention period of five months. The monitoring of insects in the Silo A was accomplished by collecting infested grain and / or insects with probes. In Silo B, the monitoring was done through the capture of insects with traps of the type calador. In The Silo, were not detected representative quantities of insects in grain up to 120 days, when the collections were made with probes in the layer below the grain treated with diatomaceous earth. In Silo B, where the collection of insects was performed with traps of the type calador, increased population of insects of the species O. surinamensis and R. dominica with the extension of storage. This increase in the number of insects was greater after 60 days of the early experiments. This is happening due to the presence of insects in grain mass before cooling. The use of cooling associated with the inert powder has an effective control of insects in grain mass.

Micropore-free surface-activated carbon for the analysis of polychlorinated dibenzo-p-dioxins-dibenzofurans and non-ortho-substituted polychlorinated biphenyls in environmental samples.

Science.gov (United States)

Kemmochi, Yukio; Tsutsumi, Kaori; Arikawa, Akihiro; Nakazawa, Hiroyuki

2002-11-22

2,3,7,8-Substituted polychlorinated dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDD/Fs) and non-ortho-substituted polychlorinated biphenyls (PCBs) account for almost all of the total toxic equivalents (TEQ) in environmental samples. Activated carbon columns are used to fractionate the samples for GC-MS analysis or bioassay. Micropore-free surface-activated carbon is highly selective for PCDD/Fs and non-ortho-PCBs and can improve the conventional activated carbon column clean-up. Along with sulfuric acid-coated diatomaceous earth columns, micropore-free surface-activated carbon provides a rapid, robust, and high-throughput sample preparation method for PCDD/Fs and non-ortho-PCBs analysis.

Effects of Wastes from the Brewing Industry in Lightweight Aggregates Manufactured with Clay for Green Roofs

Directory of Open Access Journals (Sweden)

Romina D. Farías

2017-05-01

Full Text Available This study investigates the effects of sieved wastes generated from the brewing industry on lightweight aggregates manufactured with clay. Sludge from a wastewater treatment plant, bagasse and diatomaceous earth were used to obtain the samples. These wastes are usually dumped in landfills, but the current increase in restrictions on dumping and interest in improving the environment make our proposal for gaining value from these wastes a significant contribution. Laboratory tests show that the new aggregate has low bulk density and increased water absorption and porosity. The thermographic camera results provide evidence that new aggregates have significant insulating properties and are suitable for use on green roofs.

Effects of Wastes from the Brewing Industry in Lightweight Aggregates Manufactured with Clay for Green Roofs

Science.gov (United States)

Farías, Romina D.; Martínez García, Carmen; Cotes Palomino, Teresa; Martínez Arellano, Myriam

2017-01-01

This study investigates the effects of sieved wastes generated from the brewing industry on lightweight aggregates manufactured with clay. Sludge from a wastewater treatment plant, bagasse and diatomaceous earth were used to obtain the samples. These wastes are usually dumped in landfills, but the current increase in restrictions on dumping and interest in improving the environment make our proposal for gaining value from these wastes a significant contribution. Laboratory tests show that the new aggregate has low bulk density and increased water absorption and porosity. The thermographic camera results provide evidence that new aggregates have significant insulating properties and are suitable for use on green roofs. PMID:28772892

Army Programmatic Environmental Assessment of the Mine Resistant Ambush Protected (MRAP) Vehicle Program

Science.gov (United States)

2010-12-01

Petroleum distillates  Powertrain  Pro Lock Pipe Sealant  Polyfunctional Dimethyacrylate esters  Mechanical  TT‐E‐529G Yellow  Enamel   Petroleum...907E)  Petroleum oil, Copper powder   Mechanical  White  Enamel   Toluene, Acetone, Xylene, Propane, Isobutane, n‐ Butane, Ethylbenzene, Petroleum...Diatomaceous earth, Yellow Iron   Oxide Pigment   External finish paint  Penetrant, Liquid    Surface  Crack  detector  Penetrant, Liquid    Used to

Fracture-fault network characterization of pavement imagery of the Whitby Mudstone, Yorkshire

Science.gov (United States)

Boersma, Quinten; Hardebol, Nico; Houben, Maartje; Barnhoorn, Auke; Drury, Martyn

2015-04-01

Natural fractures play an important role in the hydrocarbon production from tight reservoirs. The need for fracture network pathways by fraccing matters particularly for shale gas prospects, due to their micro- to nano-darcies matrix permeabilities. The study of natural fractures from outcrops helps to better understand network connectivity and possibility of reactivating pre-existing planes of weakness, induced by hydraulic stimulation. Microseismicity also show that natural fractures are reactivated during fraccing in tight gas reservoirs and influence the success of the stimulation. An accurate understanding of natural fracture networks can help in predicting the development of fracture networks. In this research we analyze an outcrop analogue, the Whitby Mustone Formation (WMF), in terms of its horizontal fracture network. The WMF is the time equivalent of the Posidonia Shale Formation (PSF), which on itself is the main shale gas prospect in the Dutch subsurface. The fracture network of the WMF is characterized by a system of steep dipping joints with two dominant directions with N-S and E-W strike. The network was digitized from bird-view imagery of the pavement with a spatial extent of ~100 m at sub-cm resolution. The imagery is interpreted in terms of orientation and length distributions, intensity and fractal dimensions. Samples from the field were analyzed for rock strength and sample mineralogy. The results indicate that the fracture networks greatly differ per bed. Observed differences are for example; the geometry of the fracture network, its cumulative length distribution law, the fracture intensity, the fracture length vs its orientation and the fractal dimension. All these parameters greatly influence fracture network connectivity, the probability that longer fractures exist within the pavement and whether the network is more prone to clustering or scattering. Apart from the differences, the networks display a fairly similar orthogonal arrangement with dominant large (> 5-10 m) N-S striking fractures and smaller E-W striking cross-joints (< 2-3 m). A nested network arrangement is indicated by some smaller-scale N-S fractures abutting against the E-W striking ones. Furthermore, abutment relations provide some constraints on relative time. Timing indications with respect to burial-exhumation are difficult to establish. Some joints are cemented and measurable from the high-resolution imagery. The vein measurements helped establishing a first order relation between the fracture aperture with respect to their length and confirm that longer fractures have a wider aperture. The above stated parameters and results all prove to be very valuable information which can help predict the geometries of the different fracture networks present within the PSF. It is important to understand the possible mechanisms which can cause these differences in fracture network characteristics. Bulk lithological variations between beds are minor, mainly consisting of clay minerals. Furthermore, some quartz and pyrite is present in all samples and TOC is present in variable amounts. However, the occurrence of concretions up to 0.5m in size correlates with notable differences in distinct network arrangement. Therefore it appears that the presence of these concretions greatly alters the overall strength of the rock, hence the fracture network geometry.

Frasnian-Famennian boundary near Jasper, Alberta, Canada

Energy Technology Data Exchange (ETDEWEB)

Geldsetzer, H.; Goodfellow, W.D.; McLaren, D.; Orchard, M.J.

1985-01-01

The extinction event at the Frasnian-Famennian boundary cannot be associated with a first-order event, whether impact, volcanic or other. However, data from Alberta and western Australia suggest a sudden flooding of cratonic areas by anoxic water as the immediate or second-order cause. In the Rocky Mountains near Jasper, Alberta abrupt sedimentological, geochemical and faunal changes occur between bioturbated dolomitic siltstones below and thinly laminated, very pyritic, argillaceous lime mudstones above. The siltstones which overlie thick subtidal sediments that infilled Middle Frasnian reef topography, were deposited in shallow, well oxygenated water and contain a Frasnian gigas Zone conodont fauna. In contrast, the overlying lime mudstones which pass upward into beds with Famennian triangularis Zone conodonts, represent deposition under strongly anoxic conditions; the contained pyrite has anomalously high delta/sup 34/S values suggesting prolonged bacterial reduction of sulfate to sulfide. The abrupt change to anoxic conditions could have been triggered by an ocean turn-over event as a result of which cratonic areas were flooded with anoxic water. This in turn would have caused a sharp reduction of the biomass and large-scale faunal extinctions.

Evidence for indigenous nitrogen in sedimentary and aeolian deposits from the Curiosity rover investigations at Gale crater, Mars

Science.gov (United States)

Stern, Jennifer C.; Sutter, Brad; Freissinet, Caroline; Navarro-González, Rafael; McKay, Christopher P.; Archer, P. Douglas; Buch, Arnaud; Brunner, Anna E.; Coll, Patrice; Eigenbrode, Jennifer L.; Fairen, Alberto G.; Franz, Heather B.; Glavin, Daniel P.; Kashyap, Srishti; McAdam, Amy C.; Ming, Douglas W.; Steele, Andrew; Szopa, Cyril; Wray, James J.; Martín-Torres, F. Javier; Zorzano, Maria-Paz; Conrad, Pamela G.; Mahaffy, Paul R.; Kemppinen, Osku; Bridges, Nathan; Johnson, Jeffrey R.; Minitti, Michelle; Cremers, David; Bell, James F.; Edgar, Lauren; Farmer, Jack; Godber, Austin; Wadhwa, Meenakshi; Wellington, Danika; McEwan, Ian; Newman, Claire; Richardson, Mark; Charpentier, Antoine; Peret, Laurent; King, Penelope; Blank, Jennifer; Weigle, Gerald; Schmidt, Mariek; Li, Shuai; Milliken, Ralph; Robertson, Kevin; Sun, Vivian; Baker, Michael; Edwards, Christopher; Ehlmann, Bethany; Farley, Kenneth; Griffes, Jennifer; Grotzinger, John; Miller, Hayden; Newcombe, Megan; Pilorget, Cedric; Rice, Melissa; Siebach, Kirsten; Stack, Katie; Stolper, Edward; Brunet, Claude; Hipkin, Victoria; Léveillé, Richard; Marchand, Geneviève; Sánchez, Pablo Sobrón; Favot, Laurent; Cody, George; Steele, Andrew; Flückiger, Lorenzo; Lees, David; Nefian, Ara; Martin, Mildred; Gailhanou, Marc; Westall, Frances; Israël, Guy; Agard, Christophe; Baroukh, Julien; Donny, Christophe; Gaboriaud, Alain; Guillemot, Philippe; Lafaille, Vivian; Lorigny, Eric; Paillet, Alexis; Pérez, René; Saccoccio, Muriel; Yana, Charles; Armiens-Aparicio, Carlos; Rodríguez, Javier Caride; Blázquez, Isaías Carrasco; Gómez, Felipe Gómez; Gómez-Elvira, Javier; Hettrich, Sebastian; Malvitte, Alain Lepinette; Jiménez, Mercedes Marín; Martínez-Frías, Jesús; Martín-Soler, Javier; - Torres, F. Javier Martín; Jurado, Antonio Molina; Mora-Sotomayor, Luis; Caro, Guillermo Muñoz; López, Sara Navarro; Peinado-González, Verónica; Pla-García, Jorge; Manfredi, José Antonio Rodriguez; Romeral-Planelló, Julio José; Fuentes, Sara Alejandra Sans; Martinez, Eduardo Sebastian; Redondo, Josefina Torres; Urqui-O'Callaghan, Roser; Mier, María-Paz Zorzano; Chipera, Steve; Lacour, Jean-Luc; Mauchien, Patrick; Sirven, Jean-Baptiste; Manning, Heidi; Fairén, Alberto; Hayes, Alexander; Joseph, Jonathan; Squyres, Steven; Sullivan, Robert; Thomas, Peter; Dupont, Audrey; Lundberg, Angela; Melikechi, Noureddine; Mezzacappa, Alissa; DeMarines, Julia; Grinspoon, David; Reitz, Günther; Prats, Benito; Atlaskin, Evgeny; Genzer, Maria; Harri, Ari-Matti; Haukka, Harri; Kahanpää, Henrik; Kauhanen, Janne; Kemppinen, Osku; Paton, Mark; Polkko, Jouni; Schmidt, Walter; Siili, Tero; Fabre, Cécile; Wray, James; Wilhelm, Mary Beth; Poitrasson, Franck; Patel, Kiran; Gorevan, Stephen; Indyk, Stephen; Paulsen, Gale; Gupta, Sanjeev; Bish, David; Schieber, Juergen; Gondet, Brigitte; Langevin, Yves; Geffroy, Claude; Baratoux, David; Berger, Gilles; Cros, Alain; d’Uston, Claude; Forni, Olivier; Gasnault, Olivier; Lasue, Jérémie; Lee, Qiu-Mei; Maurice, Sylvestre; Meslin, Pierre-Yves; Pallier, Etienne; Parot, Yann; Pinet, Patrick; Schröder, Susanne; Toplis, Mike; Lewin, Éric; Brunner, Will; Heydari, Ezat; Achilles, Cherie; Oehler, Dorothy; Sutter, Brad; Cabane, Michel; Coscia, David; Israël, Guy; Szopa, Cyril; Dromart, Gilles; Robert, François; Sautter, Violaine; Le Mouélic, Stéphane; Mangold, Nicolas; Nachon, Marion; Buch, Arnaud; Stalport, Fabien; Coll, Patrice; François, Pascaline; Raulin, François; Teinturier, Samuel; Cameron, James; Clegg, Sam; Cousin, Agnès; DeLapp, Dorothea; Dingler, Robert; Jackson, Ryan Steele; Johnstone, Stephen; Lanza, Nina; Little, Cynthia; Nelson, Tony; Wiens, Roger C.; Williams, Richard B.; Jones, Andrea; Kirkland, Laurel; Treiman, Allan; Baker, Burt; Cantor, Bruce; Caplinger, Michael; Davis, Scott; Duston, Brian; Edgett, Kenneth; Fay, Donald; Hardgrove, Craig; Harker, David; Herrera, Paul; Jensen, Elsa; Kennedy, Megan R.; Krezoski, Gillian; Krysak, Daniel; Lipkaman, Leslie; Malin, Michael; McCartney, Elaina; McNair, Sean; Nixon, Brian; Posiolova, Liliya; Ravine, Michael; Salamon, Andrew; Saper, Lee; Stoiber, Kevin; Supulver, Kimberley; Van Beek, Jason; Van Beek, Tessa; Zimdar, Robert; French, Katherine Louise; Iagnemma, Karl; Miller, Kristen; Summons, Roger; Goesmann, Fred; Goetz, Walter; Hviid, Stubbe; Johnson, Micah; Lefavor, Matthew; Lyness, Eric; Breves, Elly; Dyar, M. Darby; Fassett, Caleb; Blake, David F.; Bristow, Thomas; DesMarais, David; Edwards, Laurence; Haberle, Robert; Hoehler, Tori; Hollingsworth, Jeff; Kahre, Melinda; Keely, Leslie; McKay, Christopher; Wilhelm, Mary Beth; Bleacher, Lora; Brinckerhoff, William; Choi, David; Conrad, Pamela; Dworkin, Jason P.; Eigenbrode, Jennifer; Floyd, Melissa; Freissinet, Caroline; Garvin, James; Glavin, Daniel; Harpold, Daniel; Jones, Andrea; Mahaffy, Paul; Martin, David K.; McAdam, Amy; Pavlov, Alexander; Raaen, Eric; Smith, Michael D.; Stern, Jennifer; Tan, Florence; Trainer, Melissa; Meyer, Michael; Posner, Arik; Voytek, Mary; Anderson, Robert C; Aubrey, Andrew; Beegle, Luther W.; Behar, Alberto; Blaney, Diana; Brinza, David; Calef, Fred; Christensen, Lance; Crisp, Joy A.; DeFlores, Lauren; Ehlmann, Bethany; Feldman, Jason; Feldman, Sabrina; Flesch, Gregory; Hurowitz, Joel; Jun, Insoo; Keymeulen, Didier; Maki, Justin; Mischna, Michael; Morookian, John Michael; Parker, Timothy; Pavri, Betina; Schoppers, Marcel; Sengstacken, Aaron; Simmonds, John J.; Spanovich, Nicole; Juarez, Manuel de la Torre; Vasavada, Ashwin R.; Webster, Christopher R.; Yen, Albert; Archer, Paul Douglas; Cucinotta, Francis; Jones, John H.; Ming, Douglas; Morris, Richard V.; Niles, Paul; Rampe, Elizabeth; Nolan, Thomas; Fisk, Martin; Radziemski, Leon; Barraclough, Bruce; Bender, Steve; Berman, Daniel; Dobrea, Eldar Noe; Tokar, Robert; Vaniman, David; Williams, Rebecca M. E.; Yingst, Aileen; Lewis, Kevin; Leshin, Laurie; Cleghorn, Timothy; Huntress, Wesley; Manhès, Gérard; Hudgins, Judy; Olson, Timothy; Stewart, Noel; Sarrazin, Philippe; Grant, John; Vicenzi, Edward; Wilson, Sharon A.; Bullock, Mark; Ehresmann, Bent; Hamilton, Victoria; Hassler, Donald; Peterson, Joseph; Rafkin, Scot; Zeitlin, Cary; Fedosov, Fedor; Golovin, Dmitry; Karpushkina, Natalya; Kozyrev, Alexander; Litvak, Maxim; Malakhov, Alexey; Mitrofanov, Igor; Mokrousov, Maxim; Nikiforov, Sergey; Prokhorov, Vasily; Sanin, Anton; Tretyakov, Vladislav; Varenikov, Alexey; Vostrukhin, Andrey; Kuzmin, Ruslan; Clark, Benton; Wolff, Michael; McLennan, Scott; Botta, Oliver; Drake, Darrell; Bean, Keri; Lemmon, Mark; Schwenzer, Susanne P.; Anderson, Ryan B.; Herkenhoff, Kenneth; Lee, Ella Mae; Sucharski, Robert; Hernández, Miguel Ángel de Pablo; Ávalos, Juan José Blanco; Ramos, Miguel; Kim, Myung-Hee; Malespin, Charles; Plante, Ianik; Muller, Jan-Peter; Navarro-González, Rafael; Ewing, Ryan; Boynton, William; Downs, Robert; Fitzgibbon, Mike; Harshman, Karl; Morrison, Shaunna; Dietrich, William; Kortmann, Onno; Palucis, Marisa; Sumner, Dawn Y.; Williams, Amy; Lugmair, Günter; Wilson, Michael A.; Rubin, David; Jakosky, Bruce; Balic-Zunic, Tonci; Frydenvang, Jens; Jensen, Jaqueline Kløvgaard; Kinch, Kjartan; Koefoed, Asmus; Madsen, Morten Bo; Stipp, Susan Louise Svane; Boyd, Nick; Campbell, John L.; Gellert, Ralf; Perrett, Glynis; Pradler, Irina; VanBommel, Scott; Jacob, Samantha; Owen, Tobias; Rowland, Scott; Atlaskin, Evgeny; Savijärvi, Hannu; Boehm, Eckart; Böttcher, Stephan; Burmeister, Sönke; Guo, Jingnan; Köhler, Jan; García, César Martín; Mueller-Mellin, Reinhold; Wimmer-Schweingruber, Robert; Bridges, John C.; McConnochie, Timothy; Benna, Mehdi; Franz, Heather; Bower, Hannah; Brunner, Anna; Blau, Hannah; Boucher, Thomas; Carmosino, Marco; Atreya, Sushil; Elliott, Harvey; Halleaux, Douglas; Rennó, Nilton; Wong, Michael; Pepin, Robert; Elliott, Beverley; Spray, John; Thompson, Lucy; Gordon, Suzanne; Newsom, Horton; Ollila, Ann; Williams, Joshua; Vasconcelos, Paulo; Bentz, Jennifer; Nealson, Kenneth; Popa, Radu; Kah, Linda C.; Moersch, Jeffrey; Tate, Christopher; Day, Mackenzie; Kocurek, Gary; Hallet, Bernard; Sletten, Ronald; Francis, Raymond; McCullough, Emily; Cloutis, Ed; ten Kate, Inge Loes; Kuzmin, Ruslan; Arvidson, Raymond; Fraeman, Abigail; Scholes, Daniel; Slavney, Susan; Stein, Thomas; Ward, Jennifer; Berger, Jeffrey; Moores, John E.

2015-01-01

The Sample Analysis at Mars (SAM) investigation on the Mars Science Laboratory (MSL) Curiosity rover has detected oxidized nitrogen-bearing compounds during pyrolysis of scooped aeolian sediments and drilled sedimentary deposits within Gale crater. Total N concentrations ranged from 20 to 250 nmol N per sample. After subtraction of known N sources in SAM, our results support the equivalent of 110–300 ppm of nitrate in the Rocknest (RN) aeolian samples, and 70–260 and 330–1,100 ppm nitrate in John Klein (JK) and Cumberland (CB) mudstone deposits, respectively. Discovery of indigenous martian nitrogen in Mars surface materials has important implications for habitability and, specifically, for the potential evolution of a nitrogen cycle at some point in martian history. The detection of nitrate in both wind-drifted fines (RN) and in mudstone (JK, CB) is likely a result of N2 fixation to nitrate generated by thermal shock from impact or volcanic plume lightning on ancient Mars. Fixed nitrogen could have facilitated the development of a primitive nitrogen cycle on the surface of ancient Mars, potentially providing a biochemically accessible source of nitrogen. PMID:25831544

Evidence for indigenous nitrogen in sedimentary and aeolian deposits from the Curiosity rover investigations at Gale crater, Mars.

Science.gov (United States)

Stern, Jennifer C; Sutter, Brad; Freissinet, Caroline; Navarro-González, Rafael; McKay, Christopher P; Archer, P Douglas; Buch, Arnaud; Brunner, Anna E; Coll, Patrice; Eigenbrode, Jennifer L; Fairen, Alberto G; Franz, Heather B; Glavin, Daniel P; Kashyap, Srishti; McAdam, Amy C; Ming, Douglas W; Steele, Andrew; Szopa, Cyril; Wray, James J; Martín-Torres, F Javier; Zorzano, Maria-Paz; Conrad, Pamela G; Mahaffy, Paul R

2015-04-07

The Sample Analysis at Mars (SAM) investigation on the Mars Science Laboratory (MSL) Curiosity rover has detected oxidized nitrogen-bearing compounds during pyrolysis of scooped aeolian sediments and drilled sedimentary deposits within Gale crater. Total N concentrations ranged from 20 to 250 nmol N per sample. After subtraction of known N sources in SAM, our results support the equivalent of 110-300 ppm of nitrate in the Rocknest (RN) aeolian samples, and 70-260 and 330-1,100 ppm nitrate in John Klein (JK) and Cumberland (CB) mudstone deposits, respectively. Discovery of indigenous martian nitrogen in Mars surface materials has important implications for habitability and, specifically, for the potential evolution of a nitrogen cycle at some point in martian history. The detection of nitrate in both wind-drifted fines (RN) and in mudstone (JK, CB) is likely a result of N2 fixation to nitrate generated by thermal shock from impact or volcanic plume lightning on ancient Mars. Fixed nitrogen could have facilitated the development of a primitive nitrogen cycle on the surface of ancient Mars, potentially providing a biochemically accessible source of nitrogen.

A study on a instability slope in Taiwan subjected to rainfalls

Science.gov (United States)

Hsiao, D. H.; Hsieh, C. S.; Yeh, L. C.; Lin, D. Y.; T-A Phan, V.

2018-04-01

After the long-term monitoring on the Chaishan area in Taiwan from 2005 to 2012 by Kaohsiung City Government, the obtained results showed that annual lateral displacements in the region are about 7-8cm to the Taiwan Strait. The geological surface profiles of Chaishan area are in sequence weathered limestone, clay layer, limestone and mudstone layer, respectively. Thus the frictional resistance between weathered soils and rock layer could decrease after infiltration of rainwater due to impervious to water of the lowest mudstone layer. Typhoon invades often Taiwan each year, resulting in rainfall infiltration and rising groundwater level, as well as increased pore water pressure within the soil mass, causing the earth movements in some parts of Chaishan, especially in the Temple A (Shan Hai Temple) accompanied with cracking phenomenon. In this paper, limit equilibrium (LE) and finite element method (FEM) are used for slope analysis, in which the slope is considered as unsaturated soil. Results showed groundwater amounts are easy to accumulate and increasing pore water pressure give resulting in decreased safety factor. Both of groundwater level and rain durations were also considered in this study.

Development of artificial soft rock

International Nuclear Information System (INIS)

Kishi, Kiyoshi

1995-01-01

When foundation base rocks are deeper than the level of installing structures or there exist weathered rocks and crushed rocks in a part of base rocks, often sound artificial base rocks are made by substituting the part with concrete. But in the construction of Kashiwazaki Kariwa Nuclear Power Station of Tokyo Electric Power Co., Inc., the foundation base rocks consist of mudstone, and the stiffness of concrete is large as compared with the surrounding base rocks. As the quality of the substituting material, the nearly same stiffness as that of the surrounding soft rocks and long term stability are suitable, and the excellent workability and economical efficiency are required, therefore, artificial soft rocks were developed. As the substituting material, the soil mortar that can obtain the physical property values in stable form, which are similar to those of Nishiyama mudstone, was selected. The mechanism of its hardening and the long term stability, and the manufacturing plant are reported. As for its application to the base rocks of Kashiwazaki Kariwa Nuclear Power Station, the verification test at the site and the application to the base rocks for No. 7 plant reactor building and other places are described. (K.I.)

Analysis of cyclical sedimentation in the lower Permian Mchuchuma coalfield (South-West-Tanzania)

Energy Technology Data Exchange (ETDEWEB)

Casshyap, S M; Kreuser, T; Wopfner, H

1987-01-01

A statistical approach by a modified Markov process model was used to prove that the lower Permian coal measures of the Tanzanian Mchuchuma basin developed distinct cyclicities during deposition. From results the transition path of lithologic states typical for this coal sequence is as follows: (A) coarse sandstone, (B) medium sandstone, (C) fine-very fine sandstone, (D) shale, (E) mudstone, (F) coal or (E+F) and again (A) coarse sandstone. The majority of cycles is asymmetric (ABCDEF-ABC..) but symmetrical cycles are present as well (ABCDEFED). The statistical results concur with observed sedimentological evidence of depositional environment. Fining upward cycles correspond to the development of basal channel bars, changing into levees, then into back swamps which are topped by coal swamps. Frequent interbedding of coal and mudstone in the upper part of the coal measures calls for periodic flooding and flushing of fine clastics into coal-forming swamps causing interruption of peat formation. Cyclical deposition is explained by wandering channels in response to varying discharge and rate of deposition, their lateral frequent shifting caused the formation of asymmetrical cycles in this fluviodeltaic depositional model. 33 refs., 7 figs., 1 tab.

ANALISIS PENGENDALIAN KUALITAS MEMBRAN DALAM PERVAPORASI ETANOL-AIR DENGAN MENGGUNAKAN METODE STATISTICAL QUALITY CONTROL

Directory of Open Access Journals (Sweden)

Miftahul Djana

2018-01-01

Full Text Available Pervaporation is an alternative separation process using membrane which allows separations of organic mixtures and dehydrates organic solvents with low energy consumption. The purpose of this experiment is to analyze the influence of operating parameters such as feed temperature, times, variation of feed ethanol water mixtures, variation of membranes on pervaporation performance shown by the flux and selectivity by using ceramic membranes with variation of diatomaceous earth and clay as separation. Pervaporation process performance is determined from permeate selectivity and flux. Increase of permeate selectivity and flux means also increasing performace of pervaporation. However, increasing product flux may contribute on decreasing selectivity. The research consists of membrane preparation, pervaporation process, and optimization. Feed of this research are ethanol-water mixture with temperature varying between 40-60oC and downstream pressure 0.5 mbar. Ceramic membrane is used and modification with 30,60,90% of diatomaceous earth. From the results, the membranes have successfully improved the flux of this research..The results showed that the operating conditions of 0,5mbar pressure of permeate, the variation in temperatures of 40ºC, 50ºC and º, th variation of membranes and times produces the flux increases and selectivity decreases.In these conditions the maximum temperature, 60ºC gives the flux of 0,1945 l/m2.hr and the selectivity of 1,7198. In these conditions produce fuel grade ethanol with purity levels reached 98% from 95% ethanol feed.The test results indicated the mean value of t = 31.400> t table = 2.00 and sig. =0,000 <α = 0.05, thus the average (mean of 1.806 issignificant. Thus the hypothesis that the level of damage membrane of the product significantly affect the processproduction is not proven.

As, Cd, Cr, Ni and Pb pressurized liquid extraction with acetic acid from marine sediment and soil samples

International Nuclear Information System (INIS)

Moreda-Pineiro, Jorge; Alonso-Rodriguez, Elia; Lopez-Mahia, Purificacion; Muniategui-Lorenzo, Soledad; Prada-Rodriguez, Dario; Moreda-Pineiro, Antonio; Bermejo-Barrera, Adela; Bermejo-Barrera, Pilar

2006-01-01

Rapid leaching procedures by Pressurized Liquid Extraction (PLE) have been developed for As, Cd, Cr, Ni and Pb leaching from environmental matrices (marine sediment and soil samples). The Pressurized Liquid Extraction is completed after 16 min. The released elements by acetic acid Pressurized Liquid Extraction have been evaluated by inductively coupled plasma-optical emission spectrometry. The optimum multi-element leaching conditions when using 5.0 ml stainless steel extraction cells, were: acetic acid concentration 8.0 M, extraction temperature 100 deg. C, pressure 1500 psi, static time 5 min, flush solvent 60%, two extraction steps and 0.50 g of diatomaceous earth as dispersing agent (diatomaceous earth mass/sample mass ratio of 2). Results have showed that high acetic acid concentrations and high extraction temperatures increase the metal leaching efficiency. Limits of detection (between 0.12 and 0.5 μg g -1 ) and repeatability of the over-all procedure (around 6.0%) were assessed. Finally, accuracy was studied by analyzing PACS-2 (marine sediment), GBW-07409 (soil), IRANT-12-1-07 (cambisol soil) and IRANT-12-1-08 (luvisol soil) certified reference materials (CRMs). These certified reference materials offer certified concentrations ranges between 2.9 and 26.2 μg g -1 for As, from 0.068 to 2.85 μg g -1 for Cd, between 26.4 and 90.7 μg g -1 for Cr, from 9.3 to 40.0 μg g -1 for Ni and between 16.3 and 183.0 μg g -1 for Pb. Recoveries after analysis were between 95.7 and 105.1% for As, 96.2% for Cd, 95.2 and 100.6% for Cr, 95.7 and 103% for Ni and 94.2 and 105.5% for Pb

Taphonomy of the fossil insects of the middle Eocene Kishenehn Formation

Directory of Open Access Journals (Sweden)

Dale E. Greenwalt

2015-12-01

Full Text Available The lacustrine oil shales of the Coal Creek Member of the Kishenehn Formation in northwestern Montana comprise a relatively unstudied middle Eocene fossil insect locality. Herein, we detail the stratigraphic position of the fossiliferous unit, describe the insect fauna of the Coal Creek locality and document its bias towards very small but remarkably pre-served insects. In addition, the depositional environment is examined and the mineral constituents of the laminations that comprise the varves of the Kishenehn oil shale are defined. Fifteen orders of insects have been recorded with the majority of all insects identified as aquatic with the families Chironomidae (Diptera and Corixidae (Hemiptera dominant. The presence of small aquatic insects, many of which are immature, the intact nature of >90% of the fossil insects and the presence of Daphnia ephippia, all indicate that the depositional environment was the shallow margin of a large freshwater lake. The fossil insects occur within fossilized microbial mat layers that comprise the bedding planes of the oil shale. Unlike the fossiliferous shales of the Florissant and Okanagan Highlands, the mats are not a product of diatomaceous algae nor are diatom frustules a component of the sediments or the varve structure. Instead, the varves are composed of very fine eolian siliciclastic silt grains overlaid with non-diatomaceous, possibly cyanobacteria-derived microbial mats which contain distinct traces of polyaromatic hydrocarbons. A distinct third layer composed of essentially pure calcite is present in the shale of some exposures and is presumably derived from the seasonal warming-induced precipitation of carbonate from the lake’s waters. The Coal Creek locality presents a unique opportunity to study both very small middle Eocene insects not often preserved as compression fossils in most Konservat-Lagerstätte and the processes that led to their preservation.

Lithofacies palaeogeography of the Carboniferous and Permian in the Qinshui Basin, Shanxi Province, China

Directory of Open Access Journals (Sweden)

Long-Yi Shao

2015-10-01

The Xiashihezi, Shangshihezi, and Shiqianfeng Formations consist mainly of red mudstones with thick-interbedded sandstones. During the deposition of these formations, most areas of the basin were occupied by a fluvial channel, resulting in palaeogeographic units that include fluvial channel zones and flood basins. The fluvial channel deposits consist mainly of relatively-thick sandstones, which could have potential for exploration of tight sandstone gas.

An analysis of natural gas exploration potential in the Qiongdongnan Basin by use of the theory of “joint control of source rocks and geothermal heat”

Directory of Open Access Journals (Sweden)

Zhang Gongcheng

2014-10-01

Full Text Available The Oligocene Yacheng Fm contains the most important source rocks that have been confirmed by exploratory wells in the Qiongdongnan Basin. The efficiency of these source rocks is the key to the breakthrough in natural gas exploration in the study area. This paper analyzes the hydrocarbon potential of each sag in this basin from the perspective of control of both source rocks and geothermal heat. Two types of source rocks occur in the Yacheng Fm, namely mudstone of transitional facies and mudstone of neritic facies. Both of them are dominated by a kerogen of type-III, followed by type-II. Their organic matter abundances are controlled by the amount of continental clastic input. The mudstone of transitional facies is commonly higher in organic matter abundance, while that of neritic facies is lower. The coal-measure source rocks of transitional facies were mainly formed in such environments as delta plains, coastal plains and barrier tidal flat-marshes. Due to the control of Cenozoic lithosphere extension and influence of neotectonism, the geothermal gradient, terrestrial heat flow value (HFV and level of thermal evolution are generally high in deep water. The hot setting not only determines the predominance of gas generation in the deep-water sags, but can promote the shallow-buried source rocks in shallow water into oil window to generate oil. In addition to promoting the hydrocarbon generation of source rocks, the high geothermal and high heat flow value can also speed up the cracking of residual hydrocarbons, thus enhancing hydrocarbon generation efficiency and capacity. According to the theory of joint control of source quality and geothermal heat on hydrocarbon generation, we comprehensively evaluate and rank the exploration potentials of major sags in the Qiongdongnan Basin. These sags are divided into 3 types, of which type-I sags including Yanan, Lingshui, Baodao, Ledong and Huaguang are the highest in hydrocarbon exploration potential.

Sedimentation in a Submarine Seamount Apron at Site U1431, International Ocean Discovery Program Expedition 349, South China Sea

Science.gov (United States)

Dadd, K. A.; Clift, P. D.; Hyun, S.; Jiang, T.; Liu, Z.

2014-12-01

International Ocean Discovery Program (IODP) Expedition 349 Site U1431 is located near the relict spreading ridge in the East Subbasin of the South China Sea. Holes at this site were drilled close to seamounts and intersected the volcaniclastic apron. Volcaniclastic breccia and sandstone at Site U1431 are dated as late middle Miocene to early late Miocene (~8-13 Ma), suggesting a 5 m.y. duration of seamount volcanism. The apron is approximately 200 m thick and is sandwiched between non-volcaniclastic units that represent the background sedimentation. These comprise dark greenish gray clay, silt, and nannofossil ooze interpreted as turbidite and hemipelagic deposits that accumulated at abyssal water depths. At its base, the seamount sequence begins with dark greenish gray sandstone, siltstone, and claystone in upward fining sequences interpreted as turbidites intercalated with minor intervals of volcaniclastic breccia. Upsection the number and thickness of breccia layers increases with some beds up to 4.8 m and possibly 14.5 m thick. The breccia is typically massive, ungraded, and poorly sorted with angular to subangular basaltic clasts, as well as minor reworked subrounded calcareous mudstone, mudstone, and sandstone clasts. Basaltic clasts include nonvesicular aphyric basalt, sparsely vesicular aphyric basalt, highly vesicular aphyric basalt, and nonvesicular glassy basalt. Mudstone clasts are clay rich and contain foraminifer fossils. The matrix comprises up to 40% of the breccia beds and is a mix of clay, finer grained altered basalt clasts, and mafic vitroclasts with rare foraminifer fossils. Some layers have calcite cement between clasts. Volcaniclastic sandstone and claystone cycles interbedded with the breccia layers have current ripples and parallel laminations indicative of high-energy flow conditions during sedimentation. The breccia beds were most likely deposited as a series of debris flows or grain flows. This interpretation is supported by their

Physical Property Changes During CO2 Injection into Sandstone from Pukpyeong Formation, South Korea: Pore-scale Approach

Science.gov (United States)

Han, J.; Keehm, Y.

2010-12-01

Carbon dioxide is believed to be responsible for global warming and climate change, and Korea government puts a great effort in CCS (Carbon Capture and Storage). The geological sequestration is regarded as one viable option and we are looking for prospecting formations for carbon storage. In this paper, we present a new approach to determine physical property changes during CO2 injection and preliminary results from applying the method to one of prospective Tertiary formation in South Korea. The so-called computational rock physics method is composed of three steps: 1) acquisition of high-resolution pore microstructures by X-ray micro-tomography; 2) CO2 injection simulation using lattice-Boltzmann (LB) two-phase flow simulation; and 3) FEM property simulations (electrical and elastic) at different CO2 saturations during the injection. We have been shown the viability of the method last year. This year we applied this method to one of CS (carbon storage) target area, Pukpyeong formation located in north-eastern part of South Korea. From thin section analysis, we found that the formation is composed of mudstone, sandstone and conglomerate, and most of them are poorly consolidated. The mudstone and poorly-sorted conglomerate are believed to have very low permeability, and the effect of CO2 injection would be significant. Thus we focus on sandstone units and get pore microstructure of those units. We then performed the computational rock physics analysis, and present the relations of Vp - CO2 saturation, and electrical conductivity - CO2 saturation for a few sand units. We also present the preliminary upscaling results by putting combined sandstone and mudstone units into FEM modeling. The modeling results implies that the new computational approach can be very useful to characterizing the CS sites especially in early stage. Acknowledgement: This work was supported by the Energy R&D program of the Korea Institute of Energy Technology Evaluation and Planning (KETEP

Five Years of Analyses of Volatiles, Isotopes and Organics in Gale Crater Materials

Science.gov (United States)

McAdam, A.; Mahaffy, P. R.; Andrejkovicova, S. C.; Archer, P. D., Jr.; Atreya, S. K.; Buch, A.; Coll, P. J.; Conrad, P. G.; Eigenbrode, J. L.; Farley, K. A.; Flesch, G.; Franz, H. B.; Freissinet, C.; Glavin, D. P.; Hogancamp, J. V.; House, C. H.; Knudson, C. A.; Lewis, J. M.; Malespin, C.; Martin, P. M.; Millan, M.; Ming, D. W.; Morris, R. V.; Navarro-Gonzalez, R.; Steele, A.; Stern, J. C.; Summons, R. E.; Sutter, B.; Szopa, C.; Teinturier, S.; Trainer, M. G.; Webster, C. R.; Wong, G. M.

2017-12-01

Over the last five years, the Curiosity rover has explored a variety of fluvial, lacustrine and aeolian sedimentary rocks, and soils. The Sample Analysis at Mars (SAM) instrument has analysed 3 soil and 12 rock samples, which exhibit significant chemical and mineralogical diversity in over 200 meters of vertical section. Here we will highlight several key insights enabled by recent measurements of the chemical and isotopic composition of inorganic volatiles and organic compounds detected in Gale Crater materials. Until recently samples have evolved O2 during SAM evolved gas analyses (EGA), attributed to the thermal decomposition of oxychlorine phases. A lack of O2 evolution from recent mudstone samples may indicate a difference in the composition of depositional or diagenetic fluids, and can also have implications for the detection of organic compounds since O2 can combust organics to CO2 in the SAM ovens. Recent mudstone samples have also shown little or no evolution of NO attributable to nitrate salts, possibly also as a result of changes in the chemical composition of fluids [1]. Measurements of the isotopic composition of sulfur, hydrogen, nitrogen, chlorine, and carbon in methane evolved during SAM pyrolysis are providing constraints on the conditions of possible paleoenvironments [e.g., 2, 3]. There is evidence of organic C from both EGA and GCMS measurements of Gale samples [e.g., 4, 5]. Organic sulfur volatiles have been detected in several samples, and the first opportunistic derivatization experiment produced a rich dataset indicating the presence of several organic compounds [6, 7]. A K-Ar age has been obtained from the Mojave mudstone, and the age of secondary materials formed by aqueous alteration is likely history and habitability. [1] Sutter et al. (2017) LPSC 3009. [2] Franz et al., this mtg. [3] Stern et al., this mtg. [4] Ming et al. (2014) Science 343. [5] Freissinet et al. (2015) JGR 120. [6] Eigenbrode et al. (2016) AGU P21D-08. [7] Freissinet

Repairing the deteriorated thermal insulation in the serpentine - moderator tank - SLCD assemblies

International Nuclear Information System (INIS)

Gyongyosi, Tiberiu

2004-01-01

Deterioration during operation of the thermal insulation at the upper serpentines in the serpentine assembly in the moderator tank of SLCD (the system of localising the failed fuel) can create problems when one scans the fuel channels in case of failure of one of the ventilated air refrigerator in the rooms of the LAC 10 reactor. Recovering the thermal insulation is absolutely necessary but it is difficult to execute because the loading operation with the granulated layer of diatomaceous filtering agent must be effected directly on the moderator tank after some 24 h from the reactor shut down. The paper presents two possible methods of repairing together with the necessary technological facilities

Primary screen for potential sheep scab control agents.

Science.gov (United States)

Dunn, J A; Prickett, J C; Collins, D A; Weaver, R J

2016-07-15

The efficacy of potential acaricidal agents were assessed against the sheep scab mite Psoroptes ovis using a series of in vitro assays in modified test arenas designed initially to maintain P. ovis off-host. The mortality effects of 45 control agents, including essential oils, detergents, desiccants, growth regulators, lipid synthesis inhibitors, nerve action/energy metabolism disruptors and ecdysteroids were assessed against adults and nymphs. The most effective candidates were the desiccants (diatomaceous earth, nanoclay and sorex), the growth regulators (buprofezin, hexythiazox and teflubenzuron), the lipid synthesis inhibitors (spirodiclofen, spirotetramat and spiromesifen) and the nerve action and energy metabolism inhibitors (fenpyroximate, spinosad, tolfenpyrad, and chlorantraniliprole). Crown Copyright © 2016. Published by Elsevier B.V. All rights reserved.

Paleoenvironmental Implications of Clay Minerals at Yellowknife Bay, Gale Crater, Mars

Science.gov (United States)

Bristow, Thomas F.; Blake, David F.

2014-01-01

The Mars Science Laboratory (MSL) Rover, Curiosity spent approx 150 sols at Yellowknife Bay (YKB) studying a section of fluvio-lacustrine sedimentary rocks (with potential indications of volcanic influence), informally known as the Yellowknife Bay formation. YKB lies in a distal region of the Peace Vallis alluvial fan, which extends from the northern rim of Gale Crater toward the dune field at the base of Mt Sharp. Sedimentological and stratigraphic observations are consistent with the Yellowknife Bay formation being part of a distal fan deposit, which could be as young as middle Hesperian to even early Amazonian in age (approx. 3.5 to 2.5 Ga). The Yellowknife Bay formation hosts a unit of mudstone called the Sheepbed member. Curiosity obtained powdered rock samples from two drill holes in the Sheepbed Member, named John Klein and Cumberland, and delivered them to instruments in Curiosity. Data from CheMin, a combined X-ray diffraction (XRD)/X-ray fluorescence instrument (XRF), has allowed detailed mineralogical analysis of mudstone powders revealing a clay mineral component of approx. 20 wt.% in each sample. The clay minerals are important indicators of paleoenvironmental conditions and sensitive recorders of post-depositional alteration processes. The XRD pattern of John Klein reveals a 02l band consistent with a trioctahedral phyllosilicate. A broad peak at approx. 10A with a slight inflexion at approx. 12A indicates the presence of 2:1 type clay minerals in the John Klein sample. The trioctahedral nature of the clay minerals, breadth of the basal reflection, and presence of a minor component with larger basal spacing suggests that John Klein contains a trioctahedral smectite (probably saponite), whose interlayer is largely collapsed because of the low-humidity conditions. The XRD patterns show no evidence of corrensite (mixed-layer chlorite/smectite) or chlorite, which are typical diagenetic products of trioctahedral smectites when subjected to burial and

The First X-ray Diffraction Patterns of Clay Minerals from Gale Crater

Science.gov (United States)

Bristow, Thomas; Blake, David; Bish, David L.; Vaniman, David; Ming, Douglas W.; Morris, Richard V.; Chipera, Steve; Rampe, Elizabeth B.; Farmer, Jack, D.; Treiman, Allan H;

Demonstration of a Fractured Rock Geophysical Toolbox (FRGT) for Characterization and Monitoring of DNAPL Biodegradation in Fractured Rock Aquifers

Science.gov (United States)

2015-09-29

is characterized by dark gray slate or phyllite, alternating with thin layers of light gray siltstone or sandstone . Table 1 summarizes the primary...sedimentary rocks of the Newark Basin. Competent rocks are primarily mudstones and sandstones of the Lockatong and Stockton Formations. Fill, weathered silt... sandstone , and characterized by water bearing bedding plane fractures. An array of open boreholes in the source area that were drilled for the 2002

Petrography and geochemistry of iron formations of the Paleoproterozoic Koegas Subgroup, Transvaal Supergroup, Griqualand West, South Africa

OpenAIRE

2013-01-01

M.Sc. (Geology) Nel, B.P. (2013). Petrography and geochemistry of iron formations of the Paleoproterozoic Koegas Subgroup, Transvaal Supergroup, Griqualand West, South Africa. MSc thesis (unpublished), University of Johannesburg, Aucklandpark, pp. 133. The Early Paleoproterozoic Koegas Subgroup comprises a succession of siltstone, mudstone, iron-­‐formation, chert and carbonate rocks that overlies the iron-­‐formations of the Asbestos Hills Subgroup with sharp contact. It is overlain with ...

Distribution and behavior of major and trace elements in Tokyo Bay, Mutsu Bay and Funka Bay marine sediments

International Nuclear Information System (INIS)

Honda, Teruyuki; Kimura, Ken-ichiro

2003-01-01

Fourteen major and trace elements in marine sediment core samples collected from the coasts along eastern Japan, i.e. Tokyo Bay (II) (the recess), Tokyo Bay (IV) (the mouth), Mutsu Bay and Funka Bay and the Northwest Pacific basin as a comparative subject were determined by the instrumental neutron activation analysis (INAA). The sedimentation rates and sedimentary ages were calculated for the coastal sediment cores by the 210 Pb method. The results obtained in this study are summarized as follows: (1) Lanthanoid abundance patterns suggested that the major origin of the sediments was terrigenous material. La*/Lu* and Ce*/La* ratios revealed that the sediments from Tokyo Bay (II) and Mutsu Bay more directly reflected the contribution from river than those of other regions. In addition, the Th/Sc ratio indicated that the coastal sediments mainly originated in the materials from the volcanic island-arcs, Japanese islands, whereas those from the Northwest Pacific mainly from the continent. (2) The correlation between the Ce/U and Th/U ratios with high correlation coefficients of 0.920 to 0.991 indicated that all the sediments from Tokyo Bay (II) and Funka Bay were in reducing conditions while at least the upper sediments from Tokyo Bay (IV) and Mutsu Bay were in oxidizing conditions. (3) It became quite obvious that the sedimentation mechanism and the sedimentation environment at Tokyo Bay (II) was different from those at Tokyo Bay (IV), since the sedimentation rate at Tokyo Bay (II) was approximately twice as large as that at Tokyo Bay (IV). The sedimentary age of the 5th layer (8∼10 cm in depth) from Funka Bay was calculated at approximately 1940∼50, which agreed with the time, 1943∼45 when Showa-shinzan was formed by the eruption of the Usu volcano. (author)

Development of artificial soft rock. Jinko nangan zairyo no kaihatsu

Energy Technology Data Exchange (ETDEWEB)

Kishi, K.; Nishioka, T. (The Tokyo Electric Power Co. Inc., Tokyo (Japan)); Nojiri, Y.; Kurihara, H.; Fukazawa, E. (Kajima Corp., Tokyo (Japan))

1990-09-15

When a part of the ground is replaced with artificial materials in the construction of important structures on soft rock foundations, it is desirable for the artificial materials to have the rigidity equivalent to that of the surrounding ground and to be stable in the long term. The article reports a success in the development and utilization of artificial soft rocks satisfying the above conditions by using a raw material produced locally at the construction site. The soft rock aimed at was mudstone belonging to the Neocene period, and the artificial material of soil-mortal system is selected as the equivalent having the same physical properties. Improvements in selection of solidification agents and cohesive soil were especially contrived: taht is, a new material for solidification was developed by mixing blast-furnace cement and gypsum; and the mudstone on the site was used as the cohesive soil by slurrying it to adjust its grain size to homogeneous composition. The artificial soft rock resulting from the above contrivance showed excellent flow, self-leveling, and filling properties at the stage of fresh mortar, and the physical properties after hardning was very similar to those of the natural ground. The long-term stability was also confirmed by the tests on hydration reaction and environmental factors. 2 figs., 1 tab.

Lithology and uranium potential of Jurassic formations in the San Ysidro--Cuba and majors ranch areas, northwestern New Mexico

International Nuclear Information System (INIS)

Santos, E.S.

1975-01-01

The aggregate thickness of sedimentary rocks of Jurassic age near the eastern and southeastern margin of the San Juan Basin in Sandoval County, N. Mex., is about 1150 feet (350 metres). The Entrada Sandstone is the base. The Entrada Sandstone, 97 to 227 feet (30 to 69 m) thick, consists of red and brown siltstone and fine-grained sandstone and brown and white sandstone. The Todilto Formation, 5 to 125 feet (1.5 to 38 m) thick, consists of a limestone unit and a massive white gypsum unit. The Summerville Formation, 0 to 50 feet (0 to 15 m) thick, consists of variegated, interstratified mudstone, claystone, siltstone, and sandstone. The Morrison Formation, 750 to 870 feet (229 to 265 m) thick, is divided into three members. The Recapture Member consists mainly of red and white color-banded fine-grained sandstone. The Westwater Canyon and Brushy Basin Members consist mainly of red and green mudstone interstratified with grayish-orange arkosic sandstone. The upper unit of the Brushy Basin Member is called the Jackpile sandstone, a name of economic usage. Most of the sandstone in the Morrison Formation above the Recapture Member in the area studied is considered to be a potential host for uranium ore deposits. (auth)

Reservoir architecture patterns of sandy gravel braided distributary channel

Directory of Open Access Journals (Sweden)

Senlin Yin

2016-06-01

Full Text Available The purpose of this study was to discuss shape, scale and superimposed types of sandy gravel bodies in sandy-gravel braided distributary channel. Lithofacies analysis, hierarchy bounding surface analysis and subsurface dense well pattern combining with outcrops method were used to examine reservoir architecture patterns of sandy gravel braided distributary channel based on cores, well logging, and outcrops data, and the reservoir architecture patterns of sandy gravel braided distributary channels in different grades have been established. The study shows: (1 The main reservoir architecture elements for sandy gravel braided channel delta are distributary channel and overbank sand, while reservoir flow barrier elements are interchannel and lacustrine mudstone. (2 The compound sand bodies in the sandy gravel braided delta distributary channel take on three shapes: sheet-like distributary channel sand body, interweave strip distributary channel sand body, single strip distributary channel sand body. (3 Identification marks of single distributary channel include: elevation of sand body top, lateral overlaying, “thick-thin-thick” feature of sand bodies, interchannel mudstone and overbank sand between distributary channels and the differences in well log curve shape of sand bodies. (4 Nine lithofacies types were distinguished in distributary channel unit interior, different channel units have different lithofacies association sequence.

Fasies dan lingkungan pengendapan Formasi Bobong berumur Jura sebagai pembawa lapisan batubara di Taliabu, Kepulauan Sanana-Sula, Maluku Utara

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Kusnama Kusnama

2014-06-01

Full Text Available http://dx.doi.org/10.17014/ijog.vol3no3.20085The Bobong Formation is a coarse clastic sedimentary rock succession. In the lower part, it consists of breccia and conglomerate facies, then followed by quartz sandstone with intercalations of claystone facies. Upwards, the rock succession is gradually changed to become alternating shale, claystone and mudstone. In the upper section the rock unit is well exposed in the western and northern parts of the Taliabu Island. The formation is Jurassic in age and it was deposited within a fluvial-transition to shallow marine environ- ment. The coal bed found within quartz sandstone and shale and claystone-mudstone facies ocupies the upper part succession of the Bobong Formation. The coal in the Taliabu Island has two seams having a thickness of 30 - 40 cm and 100 - 120 cm, respectively. The geochemical analysis result indicates that the calorific value ranges from 6,186 to 7,350 cal/g, the sulphur content is from 3% to 4.65% , fixed carbon ranges from 45.69 to 53,96%, and ash content from 7.86 - 16.37%. On the basis of those parameter, the coal within the Bobong Formation is categorized as subbituminous to high volatile bituminous rank.    

Electric and VLF-MT survey of Tegatayama tunnel; Tegatayama tunnel no denki tansa oyobi VLF tansa

Energy Technology Data Exchange (ETDEWEB)

Nishitani, T [Akita University, Akita (Japan). Mining College

1997-05-27

To survey the structure at the depth between 20 and 30 m, field tests were conducted by means of vertical electric and VFL-MT (magnetotelluric) survey. Tegatayama tunnel has a total length of 276 m, width of 7.5 m, and height of 4.7 m, and the depth from the surface is about 28 m near the top of mountain. Near the tunnel, the thickness of surface soil is about 60 cm, which consists of clay soil including soft mudstone gravel. It was found that terrace deposit is distributed up to the depth of 8 m, and that mudstone is distributed below the depth of 8 m. Weighted four-electrode method was adopted for the vertical electrical survey. Measurements were conducted at the immediately above the tunnel, 10 m apart from the center of tunnel in the right and left, and 20 m apart from the center in the east. For the VLF-MT method, component of frequency 22.2 kHz was used. As a result of the tests, it was difficult to illustrate the existence of tunnel from the vertical electrical survey only at one point. Feature of the tunnel could be well illustrated by means of the VLF-MT method. 3 refs., 9 figs.

Anatomy of biocalcarenitic units in the Plio-Pleistocene record of the Northern Apennines (Italy)

Science.gov (United States)

Cau, Simone; Roveri, Marco; Taviani, Marco

2017-04-01

The Castell'Arquato Basin (CAB) in the foothills of the thrust-belt Northern Apennines is a foreland basin infilled by Plio-Quaternary sediments and a reference area for Plio-Pleistocene biostratigraphy. The CAB exposes plurimetric biodetrital carbonate units at discrete temporal intervals. Such shell-rich units are at places lithified, turning into conspicuous biodetritral carbonate rocks (biocalcarenites) that display a cyclical stacking motif highlighted by the regular alternation with finer-grained marine deposits. The cyclical nature of thick biocalcarenites has been hypothesized to be orbitally-controlled by obliquity and/or precession cyclicity. Furthermore, biocalcarenite-mudstone couplets form distinct clusters governed by 100-400 ka eccentricity maxima starting from 3.1 Ma at the inception of the Northern Hemisphere glaciation. They correlate with sapropels cycles formed at times of maximum insolation (precession minima). The CAB calcarenites are poorly known with respect to their environmental genetic context what motivated a detailed paleoecological analysis to unravel at best their formative context. Five distinct biofacies arranged in stacking patterns are identified through two-way cluster analysis based on the macrofossil content. Our quantitative and qualitative results suggest that these polytaxic shell concentrations and their bracketing marine mudstones developed in middle shelf settings being sensitive to climatically-driven changes.

Preliminary study on features of mineralogical zoning of epigenetic alteration at sandstone-type uranium deposit, Dongsheng area, Ordos basin

International Nuclear Information System (INIS)

Xiao Xinjian; Li Ziying; Chen Anping

2004-01-01

Sandstone-type uranium deposits located in Dongsheng area, northern Ordos basin, occur in Zhiluo Formation, Middle Jurassic. The Zhiluo Formation is divided into two members. The lower member is further divided into two submembers. The lower submember is dominantly composed of grey sandstone being the ore-hosting horizon; the upper submember consists of grey-green sandstone and mudstone. The upper member of Zhiluo Formation is made of mottled medium-fine grained sandstone and mudstone. Through the microscopic observation and study on sandstones of Zhiluo Formation, authors have established a vertical zonation of epigenetic alteration (from the top to the bottom): the limonitization + clayization + carbonation in the mottled fine-grained sandstone of the upper member of Zhiluo Formation; the green alteration (II) (mainly the chloritization of biotite, as well as the chloritization and epidotization of feldspar) + clayization + carbonation in the grey-green sandstone of the upper submember of the lower member of Zhiluo Formation; and the green alteration (I) (mainly the epidotization of feldspar) + carbonation in grey, grey-white sandstone of the lower submember. The epigenetic alteration basically occurs in grey-green sandstone. The sandstone shows grey-green color because it contains much green biotite (not chlorite). The epigenetic alteration in sandstone layer is closely associated with the uranium ore-formation

Characterization of Rock Mechanical Properties Using Lab Tests and Numerical Interpretation Model of Well Logs

Directory of Open Access Journals (Sweden)

Hao Xu

2016-01-01

Full Text Available The tight gas reservoir in the fifth member of the Xujiahe formation contains heterogeneous interlayers of sandstone and shale that are low in both porosity and permeability. Elastic characteristics of sandstone and shale are analyzed in this study based on petrophysics tests. The tests indicate that sandstone and mudstone samples have different stress-strain relationships. The rock tends to exhibit elastic-plastic deformation. The compressive strength correlates with confinement pressure and elastic modulus. The results based on thin-bed log interpretation match dynamic Young’s modulus and Poisson’s ratio predicted by theory. The compressive strength is calculated from density, elastic impedance, and clay contents. The tensile strength is calibrated using compressive strength. Shear strength is calculated with an empirical formula. Finally, log interpretation of rock mechanical properties is performed on the fifth member of the Xujiahe formation. Natural fractures in downhole cores and rock microscopic failure in the samples in the cross section demonstrate that tensile fractures were primarily observed in sandstone, and shear fractures can be observed in both mudstone and sandstone. Based on different elasticity and plasticity of different rocks, as well as the characteristics of natural fractures, a fracture propagation model was built.

Article coated with flash bonded superhydrophobic particles

Science.gov (United States)

Simpson, John T [Clinton, TN; Blue, Craig A [Knoxville, TN; Kiggans, Jr., James O [Oak Ridge, TN

2010-07-13

A method of making article having a superhydrophobic surface includes: providing a solid body defining at least one surface; applying to the surface a plurality of diatomaceous earth particles and/or particles characterized by particle sizes ranging from at least 100 nm to about 10 .mu.m, the particles being further characterized by a plurality of nanopores, wherein at least some of the nanopores provide flow through porosity, the particles being further characterized by a plurality of spaced apart nanostructured features that include a contiguous, protrusive material; flash bonding the particles to the surface so that the particles are adherently bonded to the surface; and applying a hydrophobic coating layer to the surface and the particles so that the hydrophobic coating layer conforms to the nanostructured features.

Uranium occurrences in the surficial deposits of Southern Africa

International Nuclear Information System (INIS)

Hambleton-Jones, B.B.

1982-01-01

This paper outlines the geology of the Tertiary to Recent(10 to 0,1 Ma) surficial uranium deposits in South West Africa/Namibia and South Africa. They occur mainly in the Namib Desert to the east of Walvis Bay in South West Africa/Namibia and in the north-western Cape Province of South Africa. All the deposits can be classified as fluviatile, lacustrine/pan, or pedogenic types. The economic potential of the surficial uranium deposits in the north-western Cape is insignificant compared with their South West African/Namibian counterparts. Most of the deposits occur in gypsiferous fluviatile gravels and lacustrine/pan sediments. The largest of the deposits is a lacustrinal, peat-rich, diatomaceous earth type. The mechanisms for the precipitation of the uranium are discussed

Examining Local Climate Variability in the Late Pennsylvanian Through Paleosols: An Example from the Lower Conemaugh Group of Southeastern Ohio, USA

OpenAIRE

Dzenowski, Nicole; Hembree, Daniel

2012-01-01

Three temporally close stratigraphic sections were excavated in Glenshaw Formation of Athens County, Ohio. The described units are Upper Pennsylvanian (Gzhelian, 305–302 Ma) and located in the distal portion of the Appalachian foreland basin. Mudstone units interpreted as paleosols were identified across all three sections. Detailed field and micromorphological studies lead to the recognition of two separate paleosols within the profile. The profile consists of a composite paleosol composed o...

Archaeological Test Excavations at CA-LAn-105, -291, and -1269, Palos Verdes Peninsula, Los Angeles County, California.

Science.gov (United States)

1986-08-01

averages 51 percent. The average yearly temperature in the hills is approximately 67 degrees (Woodring et al. k 1946:8-9). In general, the native...as early as 1835, and, because of the soil and climatic conditions, may not have been present in any quantity in the hills even during late prehistoric...and upper parts, labeled the Valmonte Diatomite and the Malaga Mudstone members, respectively, consist of organic siliceous shale, silty shale, chert

Microfacies, Sedimentary Environment and Relative Sea Level Changes of the Ruteh Formation, Sangsar and Makaroud Sections, Central Alborz

Directory of Open Access Journals (Sweden)

Leili Bastami

2016-12-01

-red S solution according to Dickson (1965 method. The grain and matrix percentages were estimated using visual percentage charts of Bacelle and Bosellini (1965. Dunham (1962 classification were used for carbonate facies nomenclature. Based on lithological and textural characteristics, fossil content, abiotic allochems, facies succession and their comparision with well studied environments by Flugel (2010, microfacies and their subenvironments have been identified. In this study investigation of relative sea level changes is on the basis of field observations and facies analysis. Based on the vertical succession of microfacies and sedimentary paleoenvironmental features, Systems tracts and sedimentary sequences have been recognized. Discussion of Results & Conclusions Field and petrographic studies at the Sangsar and Makaroud sections, indicate that the Ruteh Formation sediments consist of 19 carbonate microfacies and one siliciclastic petrofacies that during the Middle Permian times deposited in tidal flat to open marine facies belts of a bioclastic homoclinal carbonate ramp on the southern passive margin of the Paleotethys located on the northern Gondwana Supercontinent in a tropical region. Tidal flat facies belt includes: Dolomitic mudstone, lime mudstone to sandy lime mudstone, pelloid intraclast packstone and one quartzarenite siliciclastic petrofacies. Lagoon facies belt includes: bioclast mudstone, dasycladacea wackestone, foraminifera pelloid wackestone, bioclast pelloid wackestone,  bioclast tubiphytes wackestone, bioclast algal wackestone/packstone. Shoal facies belt includes: ooid pelloid packstone/grainstone, bioclast pelloid packstone/grainstone, pelloid bioclast grainstone and algal packstone/grainstone. Open marine facies belt includes: tubiphytes gymnocodiacea wackestone, gymnocodiacea packstone, bioclast gymnocodiacea wackestone, sponge spicule bioclast wackestone, crinoid mudstone/wackestone and bioclast mudstone.  The Ruteh Formation at both

Underground openings in clay formations - Technical requirements on drifting technology and support systems for underground openings and their impact on retreat systems for the installation of engineered barriers

International Nuclear Information System (INIS)

Mischo, Helmut

2012-01-01

Document available in extended abstract form only. Several countries are currently investigating the possibility of long-term storage of nuclear waste in clay formations, with a special focus on mud-stone formations. During the last decades extensive research has been conducted on the suitability of mud-stone as repository and the related special requirements of the clay matrix - with significant success. The knowledge base on the behaviour of the host formations during the mining phase of the excavations on the other hand is relatively limited compared to that of other investigated host rock formations, e.g. salt. With the low value of mud-stone and its relatively limited industrial application range, there have not been any large scale commercial underground mining activities in recent years to provide a significant and independent database on the behaviour of the selected mud-stone formations or their geological analogue during mining activities. Most information currently used for the assessment of this type of sediment and the planning of the mining activities has been gathered either during the execution of logistics and tunneling projects or during the excavation of today's underground laboratories. There is, however, a database on a vast variety of clay deposit types and morphologies available from commercial underground clay mining activities worldwide. The data available on commercial clay mining shows significant differences for each and every technological stage of clay mining as compared to the stages of any other mining operation. This is, amongst other things, due to the high and partly extreme ductility and creeping properties of typical clay formations, especially when considering their sensitiveness to a changing water content. In general the technical and technological differences include the applicable mining technology for the excavation of underground openings, the need for an advancement of any available technology to waterless variants as

ARGAZ: a new device for experimental study of the coupling between hydrogen production and hydrogen transfer through saturated Callovian-Oxfordian argillite

International Nuclear Information System (INIS)

Imbert, C.; Bataillon, C.; Touze, G.; Vigier, P.; Talandier, J.

2010-01-01

Document available in extended abstract form only. A specific experimental device has been designed to produce hydrogen at the metal-argillite interface by electrochemistry. The target is for one hand to reproduce the production of hydrogen occurring when a metal is corroded by the water contained in the porosity of the mud-stone. On the other hand, the transfer of the hydrogen through the mud-stone can be studied. The specific features of the experiment are the following: - Hydrogen is generated inside a cell by electrochemistry, at the interface between the argillite and a metallic surface; no gas injection is required; - Electrochemistry gives the possibility to control the hydrogen production rate; - Hydrogen generation implies water consumption: the water comes from the porosity of the bulk argillite, near the interface; - That one-dimensional experiment has been built around a cylindrical sample of bulk and undamaged argillite coming from the Callovian-Oxfordian formation. Inside the device a cylindrical sample of argillite is placed above a nickel plate. Around the argillite, a ring of compacted bentonite ensures a mechanical confinement. When saturated, the bentonite will apply a swelling pressure close to the total pressure encountered by the sample in the geological formation. The hydrogen is generated at the interface nickel-argillite. The nickel plate is one of the two electrodes required for electrochemistry. At the top face of bentonite, iron electrode is used to close the electrical circuit. The hydrogen produced at the bottom face of the mud-stone is expected to go across the argillite towards the top face. A porous plate connected with a sampling bottle allows the capture of hydrogen. The argillite sample has a diameter of 50 mm, and a height of 50 mm. It is obtained by over-coring a core sample, and by a careful machining leading to a perfect geometry and surface quality. The production rate of hydrogen can be calculated from the current intensity

Death in Guizhou — Late Triassic drowning of the Yangtze carbonate platform

Science.gov (United States)

Enos, Paul; Wei Jiayong; Lehrmann, Daniel J.

1998-06-01

The Yangtze platform in south China formed a stable palaeogeographic element from the Late Proterozoic to the end of the Middle Triassic with deposition of shallow-water carbonates during much of this time. A portion of the Yangtze platform in south-central Guizhou drowned at the transition from Permian to Triassic, as the south-adjacent Nanpanjiang basin encroached about 100 km northward, but a new, stable platform margin was established that persisted through the Early and Middle Triassic. This long history as a stable carbonate platform ended at the transition from the Ladinian to the Carnian. The latest Ladinian rocks, the Yangliujing Formation, are 490 m of shoaling-upward carbonate cycles of grapestone and bioclastic grainstone, fenestral limestone, and stromatolitic dolomudstone, commonly overprinted by extensive subaerial diagenesis. The beginning of the Carnian is marked by a rapid transition to medium-dark-grey, nodular lime mudstones containing ammonoids, conodonts and thin-shelled bivalves, the Zhuganpo Formation. The upper part of this thin pelagic limestone contains many muddy intraclasts, some slightly bored and encrusted, indicating incipient cementation. The overlying Wayao Formation is a condensed black shale with thin interbeds of dark-grey, manganiferous lime mudstone near the base. Ammonoids, conodonts, thin-shelled bivalves, and articulated crinoid stems are abundant. Fine-grained greywacke with sole marks forms prominent bundles within grey, calcareous shale in the overlying Laishike Formation. Ammonoids and thin-shelled bivalves occur sporadically in this 810-m-thick unit. Calcareous shale with thicker-shelled bivalves and packages of cleaner, coarser-grained sandstone characterize the Banan Formation, 460 m thick. The sandstone units generally coarsen and thicken upward, with ripples, medium-scale trough cross-beds, and rare U-tube burrows. Quartzose, coal-bearing siliciclastics 690 m thick form the overlying Huobachong Formation. Thick

Regional paleohydrologic and paleoclimatic settings of wetland/lacustrine depositional systems in the Morrison Formation (Upper Jurassic), Western Interior, USA

Science.gov (United States)

Dunagan, S.P.; Turner, C.E.

2004-01-01

During deposition of the Upper Jurassic Morrison Formation, water that originated as precipitation in uplands to the west of the Western Interior depositional basin infiltrated regional aquifers that underlay the basin. This regional groundwater system delivered water into the otherwise dry continental interior basin where it discharged to form two major wetland/lacustrine successions. A freshwater carbonate wetland/lacustrine succession formed in the distal reaches of the basin, where regional groundwater discharged into the Denver-Julesburg Basin, which was a smaller structural basin within the more extensive Western Interior depositional basin. An alkaline-saline wetland/lacustrine complex (Lake T'oo'dichi') formed farther upstream, where shallower aquifers discharged into the San Juan/Paradox Basin, which was another small structural basin in the Western Interior depositional basin. These were both wetlands in the sense that groundwater was the major source of water. Input from surface and meteoric water was limited. In both basins, lacustrine conditions developed during episodes of increased input of surface water. Inclusion of wetlands in our interpretation of what had previously been considered largely lacustrine systems has important implications for paleohydrology and paleoclimatology. The distal carbonate wetland/lacustrine deposits are well developed in the Morrison Formation of east-central Colorado, occupying a stratigraphic interval that is equivalent to the "lower" Morrison but extends into the "upper" Morrison Formation. Sedimentologic, paleontologic, and isotopic evidence indicate that regional groundwater discharge maintained shallow, hydrologically open, well oxygenated, perennial carbonate wetlands and lakes despite the semi-arid climate. Wetland deposits include charophyte-rich wackestone and green mudstone. Lacustrine episodes, in which surface water input was significant, were times of carbonate and siliciclastic deposition in scarce deltaic

Shallow marine event sedimentation in a volcanic arc-related setting: The Ordovician Suri Formation, Famatina range, northwest Argentina

Science.gov (United States)

Mangano, M.G.; Buatois, L.A.

1996-01-01

The Loma del Kilome??tro Member of the Lower Ordovician Suri Formation records arc-related shelf sedimentation in the Famatina Basin of northwest Argentina. Nine facies, grouped into three facies assemblages, are recognized. Facies assemblage 1 [massive and parallel-laminated mudstones (facies A) locally punctuated by normally graded or parallel-laminated silty sandstones (facies B] records deposition from suspension fall-out and episodic storm-induced turbidity currents in an outer shelf setting. Facies assemblage 2 [massive and parallel-laminated mudstones (facies A) interbedded with rippled-top very fine-grained sandstones (facies D)] is interpreted as the product of background sedimentation alternating with distal storm events in a middle shelf environment. Facies assemblage 3 [normally graded coarse to fine-grained sandstones (facies C); parallel-laminated to low angle cross-stratified sandstones (facies E); hummocky cross-stratified sandstones and siltstones (facies F); interstratified fine-grained sandstones and mudstones (facies G); massive muddy siltstones and sandstones (facies H); tuffaceous sandstones (facies I); and interbedded thin units of massive and parallel-laminated mudstones (facies A)] is thought to represent volcaniclastic mass flow and storm deposition coupled with subordinated suspension fall-out in an inner-shelf to lower-shoreface setting. The Loma del Kilo??metro Member records regressive-transgressive sedimentation in a storm- and mass flow-dominated high-gradient shelf. Volcano-tectonic activity was the important control on shelf morphology, while relative sea-level change influenced sedimentation. The lower part of the succession is attributed to mud blanketing during high stand and volcanic quiescence. Progradation of the inner shelf to lower shoreface facies assemblage in the middle part represents an abrupt basinward shoreline migration. An erosive-based, non-volcaniclastic, turbidite unit at the base of this package suggests a sea

Cavola experiment site: geophysical investigations and deployment of a dense seismic array on a landslide

OpenAIRE

L. Martelli; M. Cercato; P. Augliera; G. Di Giulio; G. Milana; J. Haines; P. Bordoni; F. Cara; undefined Cavola Experiment Team

2007-01-01

Geophysical site investigations have been performed in association with deployment of a dense array of 95 3-component seismometers on the Cavola landslide in the Northern Apennines. The aim of the array is to study propagation of seismic waves in the heterogeneous medium through comparison of observation and modelling. The small-aperture array (130 m×56 m) operated continuously for three months in 2004. Cavola landslide consists of a clay body sliding over mudstone-shale b...

砒素を溶出する泥岩のモエジマシダによるファイトレメディエーションに関するポット実験

OpenAIRE

渡邉, 彩; 榊原, 正幸; 佐野, 栄; 近藤, 敏仁; 井上, 雅裕; 堀, 利栄; 鈴木, 哲也; 竹花, 大介

2005-01-01

Phytoremediation is the use of plants for the in situ cleanup of contaminated soils, sediments, and ground water. Pot-scale experiment evaluated phytoremediation by Pteris vittata L. (Chinese brake fern) for mudstone containing arsenic (12.3 mg/kg-DW) of the Hakobuchi Group in the Yubari City, central Hokkaido, Japan. In this experiment, fronds of Pteris vittata L. were taken after 18 weeks growth in soil. The following properties became clear after examining the experimental results. (1) The...

Application of clay minerals from Cayo Guan, Cuba, as sorbents of heavy metals and ceramic raw materials; Aplicaciones de los minerales arcillosos de Cayo Guan, Cuba, como adsorbentes de metales pesados y materia prima ceramica

Energy Technology Data Exchange (ETDEWEB)

Fonseca, D.; Barba, F.; Callejas, P.; Recio, P.

2012-11-01

It has been studied by Analysis Heating Microscope Optical the behaviour of some kaolinitic clays from a reservoir of Cayo Guan rich in iron oxides and low silica content proving to be a refractory materials whose softening appears after 1500 degree centigrade. It has obtained the workability diagram of the different clay minerals calculating the plasticity by the method of Casagrande spoon; only one of the samples is in the area suitable for extrusion. Vitrification diagrams report that the capacity of water absorption is <0.6 % when the temperature of 1400 degree centigrade is achieved. We have designed a program to calculate compositions of porcelain stoneware prepared from these modified clays adding low-cost raw materials that facilitate the formation of glassy phase ((potassium feldspar and glass cullet) and/or increase the silica (sand and diatomaceous earth used as filters in the brewing industry). With one of these compositions, prepared in the laboratory (60 % of clay, 30 % feldspar and 10 % of diatomaceous earth), calcined at 1250 degree centigrade with a heating rate of 15 degree centigrade/min, the results were: water absorption 0.8 %, and linear shrinkage 21 % without any deformation observed. These clays have been treated with acid to eliminate its high iron content and study its application as an sorbent of heavy metals as Cd{sup 2}+, Cr{sup 3}+. The results of the immobilization of these elements have been compared with those obtained with thermally activated vermiculite at 800 degree centigrade, showing that the treated samples show sorption of both cadmium and chromium below the vermiculite, but the non-treated ones are suitable to remove chromium; this is because these clays do not contain in its composition exchangeable ions (Ca{sup {sub 2}} +, Mg{sup 2} +, Na{sup +}, K{sup +}), and even if they are chemically activated only the presence of Fe ions is which produces form bindings (Cr{sub x}.Fe{sub 1}-x) (OH){sub 3} which favor Cr sorption

Armoured mud balls as a result of ephemeral fluvial flood in a humid climate: Modern example from Guizhou Province, South China

Directory of Open Access Journals (Sweden)

Gerhard H. Bachmann

2014-10-01

Full Text Available Armoured mud balls were observed after rainfall and a short flood in the otherwise dry Xiaohe (small river valley of Guanling County, Guizhou Province, South China, approximately 30 km southwest of Guanling City. Armoured mud balls are most common in semiarid climates, but rather unusual in a humid climate as in Guizhou. A number of well-rounded mud balls, 2–20 cm in diameter, were found lying on the gravel of the Xiaohe gully floor. The mud balls consist of sticky, light brown and slightly mottled clay without carbonate content. The surfaces of the mud balls were studded with rims of sand- or gravel-size limestone clasts, collected during bedload transport, as is typical for armoured mud balls. The mud balls originated from alluvial mudstone deposits of the valley floor and cliff that are most likely derived from the weathering and karstification of bedrock limestones. Such mudstones with high clay content seem to be especially well suited for forming armoured mud balls. As flood events are rather common in the area, the formation of armoured mud balls should be very frequent in the Xiaohe valley and similar valleys nearby, giving the possibility for further and more detailed studies. To the best of our knowledge this is the first description of armoured mud balls in China.

Lacustrine-humate model for primary uranium ore deposits, Grants Uranium Region, New Mexico

International Nuclear Information System (INIS)

Turner-Peterson, C.E.

1985-01-01

Two generations of uranium ore, primary and redistributed, occur in fluvial sandstones of the Upper Jurassic Morrison Formation in the San Juan basin; the two stages of ore formation can be related to the hydrologic history of the basin. Primary ore formed soon after Morrison deposition, in the Late Jurassic to Early Cretaceous, and a model, the lacustrine-humate model, is offered that views primary mineralization as a diagenetic event related to early pore fluid evolution. The basic premise is that the humate, a pore-filling organic material closely associated with primary ore, originated as humic acids dissolved in pore waters of greenish-gray lacustrine mudstones deposited in the mud-flat facies of the Brushy Basin Member and similar K shale beds in the Westwater Canyon Member. During compaction associated with early burial, formation water expelled from lacustrine mudstone units carried these humic acids into adjacent sandstone beds where the organics precipitated, forming the humate deposits that concentrated uranium. During the Tertiary, much later in the hydrologic history of the basin, when Jurassic sediments were largely compacted, oxygenated ground water flowed basinward from uplifted basin margins. This invasion of Morrison sandstone beds by oxidizing ground waters redistributed uranium from primary ores along redox boundaries, forming ore deposits that resemble roll-front-type uranium ores. 11 figures

On the Validity of the “Thin” and “Thick” Double-Layer Assumptions When Calculating Streaming Currents in Porous Media

Directory of Open Access Journals (Sweden)

Matthew D. Jackson

2012-01-01

Full Text Available We find that the thin double layer assumption, in which the thickness of the electrical diffuse layer is assumed small compared to the radius of curvature of a pore or throat, is valid in a capillary tubes model so long as the capillary radius is >200 times the double layer thickness, while the thick double layer assumption, in which the diffuse layer is assumed to extend across the entire pore or throat, is valid so long as the capillary radius is >6 times smaller than the double layer thickness. At low surface charge density (0.5 M the validity criteria are less stringent. Our results suggest that the thin double layer assumption is valid in sandstones at low specific surface charge (<10 mC⋅m−2, but may not be valid in sandstones of moderate- to small pore-throat size at higher surface charge if the brine concentration is low (<0.001 M. The thick double layer assumption is likely to be valid in mudstones at low brine concentration (<0.1 M and surface charge (<10 mC⋅m−2, but at higher surface charge, it is likely to be valid only at low brine concentration (<0.003 M. Consequently, neither assumption may be valid in mudstones saturated with natural brines.

Continental Environment of Triassic Alluvial Beds in the Northern North Sea Area: Core Examples from the Lunde Formation, Snorre Field

Energy Technology Data Exchange (ETDEWEB)

Nystuen, Johan Petter; Bergan, Morten

1999-07-01

Alluvial processes transport and deposit gravel, sand and mud in a series of depositional systems such as alluvial fans, fluvial channels, floodplain and lacustrine basins. In the northernmost part of the North Sea alluvial sandstones form major reservoir rocks in several oil fields in the Tampen Spur area. In the Snorre Field, the Norian- Early Rhaetian Lunde Formation has given a great database from exploration and production wells, seismic studies, reservoir modelling, production experience and comparative analogue studies on facies distribution, alluvial architecture, heterogeneities and reservoir properties of alluvial successions. The Lunde Formation is subdivided in three members, the lower, middle and upper Lunde members, with the upper member being the main part of the Lunde reservoir rocks. The scope of presenting core samples from the upper Lunde member is to demonstrate main alluvial facies and facies associations, how facies analysis proceeds into construction of conceptual fluvial models that in turn are fundamental in evaluation of reservoir heterogeneities and reservoir modelling. The upper Lunde member consists of repeated units of red and grey sandstone and mudstone. Sandstones are dominantly medium-grained with common range from coarse- to very fine-grained. A basic building stone of the alluvial succession consists of a thick single- or multi-storey sandstone body overlain by a thick mudstone unit. Such couplets form allostratigraphic units and define the main reservoir zones.

Selected trace elements in Stockton, New Zealand, waters

International Nuclear Information System (INIS)

Alarcon Leon, E.; Anstiss, R.G.

2002-01-01

Ni, Mn, As, Pb, Cd, Cr, Cu, Hg, Se, Al, Zn, Fe, SO 4 2- , hardness (calc.) in addition to pH, total dissolved solids (TDS), and total suspended solids (TSS) were measured at 18 (11 surface and 7 subsurface) sampling sites (which were each assigned a semi-quantitative Mudstone Index (MI)) from 20 days over 9 months in the waters which drain the Stockton coal mine area on the Stockton Plateau, New Zealand. Trace element, TDS and TSS concentrations were found to be elevated and pH depressed consistent with acid mine drainage (AMD) and were characterised by significant variability due to environmental processes. Frequent concentration spikes in surface and subsurface waters occurred which sometimes exceeded maximum acceptable values (MAV) and/or aesthetic guideline values (GV) including a number of toxic trace elements. Mean concentrations of Ni and Mn in both surface and subsurface waters and As and Cd in subsurface waters exceeded MAVs. Mean concentrations of Mn, Al, Fe, SO 4 2- , and pH in both surface and subsurface waters exceeded GVs. There tends to be higher trace element and TDS concentrations where there are more mudstones (higher MI) with lower pHs. It is recommended that any further studies focus on geographic distribution, concentration fluctuation factors, movement, and possible exposure issues. (author). 7 refs., 1 fig., 3 tabs

Resource Assessment of the In-Place and Potentially Recoverable Deep Natural Gas Resource of the Onshore Interior Salt Basins, North Central and Northeastern Gulf of Mexico

Energy Technology Data Exchange (ETDEWEB)

Ernest A. Mancini; Paul Aharon; Donald A. Goddard; Roger Barnaby

2005-10-28

The principal research effort for Year 2 of the project has been petroleum system characterization and modeling. Understanding the burial, thermal maturation, and hydrocarbon expulsion histories of the strata in the onshore interior salt basins of the North Central and Northeastern Gulf of Mexico areas is important in hydrocarbon resource assessment. The underburden and overburden rocks in these basins and subbasins are a product of their rift-related geohistory. Petroleum source rock analysis and initial thermal maturation and hydrocarbon expulsion modeling indicated that an effective regional petroleum source rock in the onshore interior salt basins and subbasins, the North Louisiana Salt Basin, Mississippi Interior Salt Basin, Manila Subbasin and Conecuh Subbasin, was Upper Jurassic Smackover lime mudstone. The initial modeling also indicated that hydrocarbon generation and expulsion were initiated in the Early Cretaceous and continued into the Tertiary in the North Louisiana Salt Basin and the Mississippi Interior Salt Basin and that hydrocarbon generation and expulsion were initiated in the Late Cretaceous and continued into the Tertiary in the Manila Subbasin and Conecuh Subbasin. Refined thermal maturation and hydrocarbon expulsion modeling and additional petroleum source rock analysis have confirmed that the major source rock in the onshore interior salt basins and subbasins is Upper Jurassic Smackover lime mudstone. Hydrocarbon generation and expulsion were initiated in the Early to Late Cretaceous and continued into the Tertiary.

[Study on rapid analysis method of pesticide contamination in processed foods by GC-MS and GC-FPD].

Science.gov (United States)

Kobayashi, Maki; Otsuka, Kenji; Tamura, Yasuhiro; Tomizawa, Sanae; Kamijo, Kyoko; Iwakoshi, Keiko; Sato, Chizuko; Nagayama, Toshihiro; Takano, Ichiro

2011-01-01

A simple and rapid method using GC-MS and GC-FPD for the determination of pesticide contamination in processed food has been developed. Pesticides were extracted from a sample with ethyl acetate in the presence of anhydrous sodium sulfate, then cleaned up with a combination of mini-columns, such as macroporous diatomaceous earth, C18, GCB (graphite carbon black) and PSA. Recovery tests of 57 pesticides (known to be toxic or harmful) from ten kinds of processed foods (butter, cheese, corned beef, dried shrimp, frozen Chinese dumplings, grilled eels, instant noodles, kimchi, retort-packed curry and wine) were performed, and the recovery rates were mostly between 70% and 120%. This method can be used to judge whether or not processed foods are contaminated with pesticides at potentially harmful levels.

Carrier effect on separation efficiency of the column in reversed-phase partition chromatography

International Nuclear Information System (INIS)

Pszonicka, M.; Siekierski, S.

1972-01-01

Chromatographic columns were filled with carriers of diatomaceous earth type (Hyflo Super Cell, and Celite 545) of large pores, and two microporous silica gels respectively. These columns were used for the separation of europium and gadolinium by reversed-phase partition chromatography in the system: stationary phase-diethylhexylphosphoric acid (HDEHP) mobile phase-0.4 N nitric acid. In each case the separation of the above mentioned elements was achieved. The plate height that characterizes separation efficiency of the column, decreases with the decrease of particle diameter of the carrier. Best columns were obtained from carriers of large pores (Hyflo Super Cell and Celite 545) for which plate hights below 0.1 mm could be achieved. Columns filled with microporous silica gels showed plate heights of 0.2-0.3 mm. (author)

Systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies

Science.gov (United States)

Fliermans,; Carl, B [Augusta, GA

2012-08-07

Some or all of the needs above can be addressed by embodiments of the invention. According to embodiments of the invention, systems and methods for facilitating hydrogen storage using naturally occurring nanostructure assemblies can be implemented. In one embodiment, a method for storing hydrogen can be provided. The method can include providing diatoms comprising diatomaceous earth or diatoms from a predefined culture. In addition, the method can include heating the diatoms in a sealed environment in the presence of at least one of titanium, a transition metal, or a noble metal to provide a porous hydrogen storage medium. Furthermore, the method can include exposing the porous hydrogen storage medium to hydrogen. In addition, the method can include storing at least a portion of the hydrogen in the porous hydrogen storage medium.

Prokaryotic communities differ along a geothermal soil photic gradient.

Science.gov (United States)

Meadow, James F; Zabinski, Catherine A

2013-01-01

Geothermal influenced soils exert unique physical and chemical limitations on resident microbial communities but have received little attention in microbial ecology research. These environments offer a model system in which to investigate microbial community heterogeneity and a range of soil ecological concepts. We conducted a 16S bar-coded pyrosequencing survey of the prokaryotic communities in a diatomaceous geothermal soil system and compared communities across soil types and along a conspicuous photic depth gradient. We found significant differences between the communities of the two different soils and also predictable differences between samples taken at different depths. Additionally, we targeted three ecologically relevant bacterial phyla, Cyanobacteria, Planctomycetes, and Verrucomicrobia, for clade-wise comparisons with these variables and found strong differences in their abundances, consistent with the autecology of these groups.

Evaluation of the Efficiency of Clay Pots in Removal of Water Impurities

Directory of Open Access Journals (Sweden)

K Naddafi , AH Mahvi, S Nasseri, M Mokhtari, H Zeraati

2005-04-01

Full Text Available Recently, inexpensive technologies for drinking water supply in small communities are highly considered in developing countries. One of these technologies is the application of ceramic filters that are usually made of diatomaceous earth or clay soil. This research was carried out to determine the efficiency of clay pots (as a filter in removing water impurities. Pilot and the related clay parts were manufactured and its efficiency in removing TDS, hardness, NO3-, color and turbidity was measured by passing water through the clay pipes. The results showed that the clay filters had not the potential to remove hardness, EC, TDS and nitrate of water. However, they showed excellent efficiency in turbidity removal (≥ 90% and could significantly decrease the color of the water (≥ 60%.

Mixed waste: The treatment of organic radioactive waste by means of adsorbents

International Nuclear Information System (INIS)

Sanhueza-Mir, A.; Morales-Galarce, T.

2001-01-01

Full text: The work described in this paper has been carried in the radioactive waste treatment facilities of the Nuclear Research Center Lo Aguirre, CEN LA, which are operated by Radioactive Waste Management Unit, UGDR. This last, centralizes its activities in order to manage all radioactive waste generated in the country due to the nuclear development. Features of danger and risks presented by organic radioactive liquid waste, make the need to develop a practicable alternative for its treatment and to allow the conditioning towards a suitable final disposal The raw material for this work, is an organic liquid waste arising from scintillation techniques, contaminated with Tritium. This mixed waste has to be treated and then conditioned in a solid form within a 200 I container, according with actual acceptance criteria for our temporary store for radioactive waste. The best formulation which allows to immobilize the liquid waste was determined. The first step consists in the adsorption treatment that waste is humbled. From the available adsorbents, two types were studied: adsorption granulat and diatomaceous earth. From the waste management standpoint, results with diatomaceous earth present physical characteristics better than the other Following, the second stage is the immobilization, which is achieved in a cement matrix made with puzzolanic cement (Polpaico 400) made in Chile. Later, due to cost and availability in the country, the diatomaceous earth is selected for the study, in the form of celite which is comparatively economic. The best mixture, with regard to physical feature, has the following composition: a 0.35 (w/w) water/cement ratio, which represents the needed quantity to obtain workability in the mixture, and it is the minimum amount of water to hydrating the cement; a waste/adsorbent ratio of 0.5 (v/v), in which the organic liquid is completely adsorbed and it is incorporated into the crystalline system of the solid form; and an adsorbed waste

Water resources (Chapter 5)

CSIR Research Space (South Africa)

Hobbs, Philip

2016-01-01

Full Text Available and relationships that inform the association between geology, shale gas and groundwater that is discussed in this Chapter. The mudstones and sandstones of the Adelaide Subgroup at the base of the Beaufort Group succession of sedimentary strata represent... migration to surface. The sedimentary rocks of the Ecca Group cover a further ~6% of the study area. In agreement with Rosewarne et al. (2013), who recognise a western, a central and an eastern subarea; this study recognises an additional southern subarea...

Sedimentary features of the Mercedes formation (upper Cretaceous ) between Mercedes and Fray Bentos cities, Rca. O del Uruguay

International Nuclear Information System (INIS)

Tofalo, O.; Pazos, P.

1998-01-01

A new locality by the Mercedes formation is analyzed close to route 2, near at the Mercedes City. The stratigraphic assignment is proposed after the examination of the sedimentary features that include geometry, composition and sedimentary structures. The section that reach 10 meters in thickness contains conglomerates, pebbly sandstones, sandstones and scare mudstones with a finning upward arrangement. All of features are indicative of a alluvial origin. This locality is the first mention of the Mercedes formation in the south section of the Department Rio Negro. (author)

The XRD Amorphous Component in John Klein Drill Fines at Yellowknife Bay, Gale Crater, Mars

Science.gov (United States)

Morris, Richard V.; Ming,, Douglas W.; Blake, David; Vaniman, David; Bish, David L; Chipera, Steve; Downs, Robert; Morrison, Shaunna; Gellert, Ralf; Campbell, Iain;

Eocene bituminous coal deposits of the Claiborne group, Webb County, Texas

Science.gov (United States)

Hook, Robert W.; Warwick, Peter D.; Warwick, Peter D.; Karlsen, Alexander K.; Merrill, Matthew D.; Valentine, Brett J.

2011-01-01

Two bituminous coal zones, the San Pedro and the Santo Tomas, in the middle Eocene Claiborne Group of Webb County, south Texas (Figure 1), are among the coal resources that are not evaluated quantitatively as part of the current Gulf Coastal Plain coal resource assessment. Coal beds within these zones were mined by underground methods northwest of Laredo until 1939 and have been intermittently mined at the surface since 1979. These coals have long been regarded as unique within the Gulf Coast Tertiary coal-bearing section because they are high-volatile C bituminous in rank and because their physical characteristics resemble upper Carboniferous cannel coals of the Appalachians and Europe.Discontinuous exposures of the Santo Tomas and the underlying San Pedro coal zone extend northwestward from Dolores for approximately 15 to 21 mi along the breaks of the Rio Grande and its tributaries in Webb County (Figure 1). This part of south Texas lies along the southwestern flank of the Rio Grande Embayment, which extends south and southeastwardly through the Mexican States of Coahuila, Nuevo León, and Tamaulipas (Figure 1). Within the embayment, the lower to middle part of the Claiborne Group consists of marine mudstones (Reklaw Formation) in the east and northeast and sandstones and mudstones (Bigford Formation) in the south and southwest (Figure 2). The marine mudstones coarsen upward into fluvial-deltaic sandstones (Queen City Sand) that prograded gulfward across eastern and central Texas (Guevara and Garcia, 1972). To the west and southwest, the interval overlying the Bigford Formation becomes less sandy, and claystones (El Pico Clay) predominate. Although the San Pedro coal zone has been placed traditionally near the top of the Bigford Formation and the Santo Tomas coal zone near the base of the El Pico Clay, recent work has failed to validate a mappable contact between these formations (Warwick and Hook, 1995). The coal beds dip northeast at less than 2 degrees towards

Sedimentary processes and depositional environments of the Horn River Shale in British Columbia, Canada

Science.gov (United States)

Yoon, Seok-Hoon; Koh, Chang-Seong; Joe, Young-Jin; Woo, Ju-Hwan; Lee, Hyun-Suk

2017-04-01

The Horn River Basin in the northeastern British Columbia, Canada, is one of the largest unconventional gas accumulations in North America. It consists mainly of Devonian shales (Horn River Formation) and is stratigraphically divided into three members, the Muskwa, Otterpark and Evie in descending order. This study focuses on sedimentary processes and depositional environments of the Horn River shale based on sedimentary facies analysis aided by well-log mineralogy (ECS) and total organic carbon (TOC) data. The shale formation consists dominantly of siliceous minerals (quartz, feldspar and mica) and subordinate clay mineral and carbonate materials, and TOC ranging from 1.0 to 7.6%. Based on sedimentary structures and micro texture, three sedimentary facies were classified: homogeneous mudstone (HM), indistinctly laminated mudstone (ILM), and planar laminated mudstone (PLM). Integrated interpretation of the sedimentary facies, lithology and TOC suggests that depositional environment of the Horn River shale was an anoxic quiescent basin plain and base-of-slope off carbonate platform or reef. In this deeper marine setting, organic-rich facies HM and ILM, dominant in the Muskwa (the upper part of the Horn River Formation) and Evie (the lower part of the Horn River Formation) members, may have been emplaced by pelagic to hemipelagic sedimentation on the anoxic sea floor with infrequent effects of low-density gravity flows (turbidity currents or nepheloid flows). In the other hand, facies PLM typifying the Otterpark Member (the middle part of the Horn River Formation) suggests more frequent inflow of bottom-hugging turbidity currents punctuating the hemipelagic settling of the background sedimentation process. The stratigraphic change of sedimentary facies and TOC content in the Horn River Formation is most appropriately interpreted to have been caused by the relative sea-level change, that is, lower TOC and frequent signal of turbidity current during the sea

Subaqueous early eruptive phase of the late Aptian Rajmahal volcanism, India: Evidence from volcaniclastic rocks, bentonite, black shales, and oolite

Directory of Open Access Journals (Sweden)

Naresh C. Ghose

2017-07-01

Full Text Available The late Aptian (118–115 Ma continental flood basalts of the Rajmahal Volcanic Province (RVP are part of the Kerguelen Large Igneous Province, and constitute the uppermost part of the Gondwana Supergroup on the eastern Indian shield margin. The lower one-third of the Rajmahal volcanic succession contains thin layers of plant fossil-rich inter-trappean sedimentary rocks with pyroclasts, bentonite, grey and black shale/mudstone and oolite, whereas the upper two-thirds consist of sub-aerial fine-grained aphyric basalts with no inter-trappean material. At the eastern margin and the north-central sector of the RVP, the volcanics in the lower part include rhyolites and dacites overlain by enstatite-bearing basalts and enstatite-andesites. The pyroclastic rocks are largely felsic in composition, and comprise ignimbrite as well as coarse-grained tuff with lithic clasts, and tuff breccia with bombs, lapilli and ash that indicate explosive eruption of viscous rhyolitic magma. The rhyolites/dacites (>68 wt.% are separated from the andesites (<60 wt.% by a gap in silica content indicating their formation through upper crustal anatexis with only heat supplied by the basaltic magma. On the other hand, partially melted siltstone xenoliths in enstatite-bearing basalts suggest that the enstatite-andesites originated through mixing of the upper crust with basaltic magma, crystallizing orthopyroxene at a pressure-temperature of ∼3 kb/1150 °C. In contrast, the northwestern sector of the RVP is devoid of felsic-intermediate rocks, and the volcaniclastic rocks are predominantly mafic (basaltic in composition. Here, the presence of fine-grained tuffs, tuff breccia containing sideromelane shards and quenched texture, welded tuff breccia, peperite, shale/mudstone and oolite substantiates a subaqueous environment. Based on these observations, we conclude that the early phase of Rajmahal volcanism occurred under predominantly subaqueous conditions. The presence

Depositional controls on coal distribution and quality in the Eocene Brunner Coal Measures, Buller Coalfield, South Island, New Zealand

Science.gov (United States)

Flores, R.M.; Sykes, R.

1996-01-01

The Buller Coalfield on the West Coast of the South Island, New Zealand, contains the Eocene Brunner Coal Measures. The coal measures unconformably overlie Paleozoic-Cretaceous basement rocks and are conformably overlain by, and laterally interfinger with, the Eocene marine Kaiata Formation. This study examines the lithofacies frameworks of the coal measures in order to interpret their depositional environments. The lower part of the coal measures is dominated by conglomeratic lithofacies that rest on a basal erosional surface and thicken in paleovalleys incised into an undulating peneplain surface. These lithofacies are overlain by sandstone, mudstone and organic-rich lithofacies of the upper part of the coal measures. The main coal seam of the organic-rich lithofacies is thick (10-20 m), extensive, locally split, and locally absent. This seam and associated coal seams in the Buller Coalfield are of low- to high-volatile bituminous rank (vitrinite reflectance between 0.65% and 1.75%). The main seam contains a variable percentage of ash and sulphur. These values are related to the thickening and areal distribution of the seam, which in turn, were controlled by the nature of clastic deposition and peat-forming mire systems, marine transgression and local tidal incursion. The conglomeratic lithofacies represent deposits of trunk and tributary braided streams that rapidly aggraded incised paleovalleys during sea-level stillstands. The main seam represents a deposit of raised mires that initially developed as topogenous mires on abandoned margins of inactive braidbelts. Peat accumulated in mires as a response to a rise in the water table, probably initially due to gradual sea-level rise and climate, and the resulting raised topography served as protection from floods. The upper part of the coal measures consists of sandstone lithofacies of flu vial origin and bioturbated sandstone, mudstone and organic-rich lithofacies, which represent deposits of paralic (deltaic

Depositional environments and porosity distribution in regressive limestone reservoirs of the Mishrif Formation, Southern Iraq

International Nuclear Information System (INIS)

AlDabbas, Moutaz; AlJassim Jassim; AlJumaily Saad

2010-01-01

Eight subsurface sections and a large number of thin sections of the Mishrif Limestone were studied to unravel the depositional facies and environments. The allochems in the Mishrif Formation are dominated by bioclasts, whereas peloids, ooids, and intraclasts are less abundant. The sedimentary microfacies of the Mishrif Formation includes mudstone, wackestone, packstone, grainstone, floatstone, and rudstone, which have been deposited in basinal, outer shelf, slop followed by shoal reef and lagoonal environments. The formation displays various extents of dolomitization and is cemented by calcite and dolomite. The formation has gradational contact with the underlying Rumaila Formation but is unconformably overlain by the Khasib Formation. The unconformity is recognized because the skeletal grains are dominated by Chaophyta (algae), which denotes the change of environment from fully marine to lacustrine environment. Thus, the vertical bioclast analysis indicates that the Mishrif Formation is characterized by two regressive cycles, which control the distribution of reservoir quality as well as the patterns of calcite and dolomite cement distribution. Mishrif Formation gradationally overlies Rumaila Formation. This was indicated by the presence of the green parts of Chaophyta (algae) as main skeletal grains at the uppermost part of well Zb-47, which refer to lacustrine or fresh water environment. Petrographical study shows that the fossils, peloids, oolitis, and intraclasts represent the main allochem. Calcite and dolomite (as diagenetic products) are the predominant mineral components of Mishrif Formation. Fossils were studied as an environmental age and facial boundaries indicators, which are located in a chart using personal computer programs depending on their distributions on the first appearance of species. Fifteen principal sedimentary microfacies have been identified in the Mishrif Formation, which includes lime mudstone, mudstone-wackestone, wackestone

Textural evidence for jamming and dewatering of a sub-surface, fluid-saturated granular flow

Science.gov (United States)

Sherry, T. J.; Rowe, C. D.; Kirkpatrick, J. D.; Brodsky, E. E.

2011-12-01

Sand injectites are spectacular examples of large-scale granular flows involving migration of hundreds of cubic meters of sand slurry over hundreds of meters to kilometers in the sub-surface. By studying the macro- and microstructural textures of a kilometer-scale sand injectite, we interpret the fluid flow regimes during emplacement and define the timing of formation of specific textures in the injected material. Fluidized sand sourced from the Santa Margarita Fm., was injected upward into the Santa Cruz Mudstone, Santa Cruz County, California. The sand injectite exposed at Yellow Bank Beach records emplacement of both hydrocarbon and aqueous sand slurries. Elongate, angular mudstone clasts were ripped from the wall rock during sand migration, providing evidence for high velocity, turbid flow. However, clast long axis orientations are consistently sub-horizontal suggesting the slurry transitioned to a laminar flow as the flow velocity decreased in the sill-like intrusion. Millimeter to centimeter scale laminations are ubiquitous throughout the sand body and are locally parallel to the mudstone clast long axes. The laminations are distinct in exposure because alternating layers are preferentially cemented with limonite sourced from later groundwater infiltration. Quantitative microstructural analyses show that the laminations are defined by subtle oscillations in grain alignment between limonite and non-limonite stained layers. Grain packing, size and shape distributions do not vary. The presence of limonite in alternating layers results from differential infiltration of groundwater, indicating permeability changes between the layers despite minimal grain scale differences. Convolute dewatering structures deform the laminations. Dolomite-cemented sand, a signature of hydrocarbon saturation, forms irregular bodies that cross-cut the laminations and dewatering structures. Laminations are not formed in the dolomite-cemented sand. The relative viscosity difference

Slope-apron deposition in an ordovician arc-related setting: The Vuelta de Las Tolas Member (Suri Formation), Famatina Basin, northwest Argentina

Science.gov (United States)

Mangano, M.G.; Buatois, L.A.

1997-01-01

The Ordovician Suri Formation is part of the infill of the Famatina Basin of northwest Argentina, which formed in an active setting along the western margin of early Paleozoic Gondwana. The lower part of this formation, the Vuelta de Las Tolas Member, records sedimentation on a slope apron formed in an intra-arc basin situated on a flooded continental arc platform. The coincidence of a thick Arenig-Llanvirn sedimentary succession and volcanic-plutonic arc rocks suggests an extensional or transtensional arc setting, and is consistent with evidence of an extensional regime within the volcanic arc in the northern Puna region. The studied stratigraphic sections consist of volcanic rocks and six sedimentary facies. The facies can be clustered into four facies associations. Association 1, composed of facies A (laminated siltstones and mudstones) and B (massive mudstones and siltstones), is interpreted to have accumulated from silty-muddy high-and low-density turbidity currents and highly fluid, silty debris flows, with subsequent reworking by bottom currents, and to a lesser extent, hemipelagic suspension in an open-slope setting. Facies association 2 is dominated by facies C (current-rippled siltstones) strata. These deposits are interpreted to record overbank sedimentation from fine-grained turbidity currents. Facies E (matrix-supported volcanic breccias) interbedded with andesitic lava units comprises facies association 3. Deposition was contemporaneous with subaqueous volcanic activity, and accumulated from cohesive debris flows in a coarse-grained wedge at the base of slope. Facies association 4 is typified by facies D (vitric fine-grained sandstones and siltstones) and F (channelized and graded volcanic conglomerates and breccias) deposits. These strata commonly display thinning-and fining-upward trends, indicating sedimentation from highly-concentrated volcaniclastic turbidity currents in a channelized system. The general characteristics of these deposits of fresh

Capacity and degree of iodine absorbed and enriched by vegetable from soil.

Science.gov (United States)

Weng, Huan-Xin; Weng, Jing-Ke; Yong, Wen-Bin; Sun, Xiang-Wu; Zhong, Hang

2003-01-01

To understand the biogeochemical transfer of iodine, the absorbability and bioaccumulation of iodine in tested vegetables (radish, spinach and Chinese cabbage) are examined by applying iodic fertilizer composed of kelp and diatomaceous earth. The experimental results show that when iodine in soil is not excessive, the concentrations of iodine in tested vegetables increase as the content of iodine in soil increases. The absorbability and enrichment degree of iodine in various vegetables and in various parts of the same vegetable a redifferent, which explains that the concentration of iodine in plant is determined by the plant type and the physiological action of plant. The patience order of tested vegetables to excessive iodine is Chinese cabbage > spinach > radish. These results have theoretical and practical significance in opening up a new way for ameliorating poor iodine environment with artificial means.

Growth, Failure, and Erosion of Submarine Channel Levees on the Upper Mississippi Fan, Gulf of Mexico

Science.gov (United States)

Sawyer, D. E.; Flemings, P. B.; Nikolinakou, M. A.

2011-12-01

Late Pleistocene channel levees on the Mississippi Fan failed repeatedly along deep-seated listric faults. These growth faults begin at the top of the levee, as much as a kilometer away from the channel axis. They plunge 150-200 meters downward reaching their deepest point halfway towards the channel axis (0.5 km) along the base of a regional sand unit. They then rise toward the channel axis where they emerge. The erosion of toe-thrust material coupled with levee growth, promoted a dynamic equilibrium: turbidity currents flushed the channel axis and deposited new levee on the margins, which induced further displacement into the channel. With a geomechanical model we show that deep-seated failure occurred by undrained loading of an underlying low permeability mudstone. Excess pore pressure formed a low-strength layer that localized the detachment at the base of a regional sand. Our results show that deep-seated failure is expected when levee systems form above regional sand bodies that were deposited rapidly above low permeability mudstone. Furthermore, the presence of this failure style in channel-levee systems is a strong indicator that overpressures and low effective stresses were present during formation and thus record paleo-pressures. Understanding these systems is critical for the design of safe well penetrations, predicting hydraulic connectivity of deepwater channel sands, and the growth of submarine channel-levee systems. This study illuminates the linkages between sedimentation, erosion, and the mechanical stability of levees in submarine channel systems.

Marine Jurassic lithostratigraphy of Thailand

Science.gov (United States)

Meesook, A.; Grant-Mackie, J. A.

Marine Jurassic rocks of Thailand are well-exposed in the Mae Sot and Umphang areas and less extensively near Mae Hong Son, Kanchanaburi, Chumphon and Nakhon Si Thammarat, in the north, west, and south respectively. They are generally underlain unconformably by Triassic and overlain by Quaternary strata. Based mainly on five measured sections, fourteen new lithostratigraphic units are established: (in ascending order) Pa Lan, Mai Hung and Kong Mu Formations of the Huai Pong Group in the Mae Hong Son area; Khun Huai, Doi Yot and Pha De Formations of the Hua Fai Group in the Mae Sot area; Klo Tho, Ta Sue Kho, Pu Khloe Khi and Lu Kloc Tu Formations of the Umphang Group in the Umphang area; and the Khao Lak Formation in the Chumphon area. Mudstone, siltstone, sandstone, limestone and marl are the dominant lithologies. Mudstones, siltstones and sandstones are widespread; limestones are confined to the Mae Sot, Umphang, Kanchanaburi and Mae Hong Son areas; marls are found only in Mae Sot. The sequences are approximately 900 m thick in Mae Sot and 450 m thick in Umphang and are rather thinner in the other areas, particularly in the south. Based on ammonites, with additional data from bivalves and foraminifera, the marine Jurassic is largely Toarcian-Aalenian plus some Bajocian. Late Jurassic ages given previously for strata in the Mae Sot and Umphang areas have not been confirmed.

Applying and improving a sedimentary facies model for exploration of stratigraphic traps in the Austrian Molasse basin

Energy Technology Data Exchange (ETDEWEB)

Hinsch, R.; Kofler, N. [Rohoel-Aufsuchungs AG (RAG), Vienna (Austria); Hubbard, S. [Calgary Univ., Calgary (Canada). Dept. of Geology and Geophysics

2007-09-13

In the Molasse foreland basin of Upper Austria gas is produced from deep-water sandstones and conglomerates of the Puchkirchen and basal Hall formations (Oligocene-Lower Miocene). The basin is mature, with >750 wells drilled by RAG to date. An extensive 3-D seismic reflection dataset that covers much of the paleo-basin foredeep has been acquired in the study area over the last 15 years. Seismic stratigraphic analysis has revealed that deepwater sedimentation in the basin was dominated by a channel belt up to 5 km wide that transported sediment derived from the Central and Eastern Alps eastward along the basin axis (Linzer, 2001; de Ruig, 2003). Based on these findings, a detailed sedimentary facies model has been developed, outlining several distinct depositional elements that reveal numerous possible stratigraphic trap types (de Ruig and Hubbard, 2006). This depositional model is currently being applied and tested in exploration and refined by ongoing research. Channel abandonment and migration are important processes that resulted in stratigraphic configurations consisting of coarse-grained sandstones and conglomerates overlain by channel and overbank mudstones. This represents ideal reservoir architecture, including porous reservoir facies sealed by impermeable deposits. Additional stratigraphic trapping conditions can result from special spatial arrangements of depositional elements, for example a sandstone-filled tributary channel that is sealed by an overlying mudstone-filled abandonment channel. Recognizing and further improving such stratigraphic trapping configurations are important for future exploration in Upper Austria, where most of the structural traps have been drilled. (orig.)

Facies architecture of the Bluejacket Sandstone in the Eufaula Lake area, Oklahoma: Implications for the reservoir characterization of the Bartlesville Sandstone

Energy Technology Data Exchange (ETDEWEB)

Ye, Liangmiao; Yang, Kexian [Univ. of Tulsa, OK (United States)

1997-08-01

Outcrop studies of the Bluejacket Sandstone (Middle Pennsylvanian) provide significant insights to reservoir architecture of the subsurface equivalent Bartlesville Sandstone. Quarry walls and road cuts in the Lake Eufaula area offer excellent exposures for detailed facies architectural investigations using high-precision surveying, photo mosaics. Directional minipermeameter measurements are being conducted. Subsurface studies include conventional logs, borehole image log, and core data. Reservoir architectures are reconstructed in four hierarchical levels: multi-storey sandstone, i.e. discrete genetic intervals; individual discrete genetic interval; facies within a discrete genetic interval; and lateral accretion bar deposits. In both outcrop and subsurface, the Bluejacket (Bartlesville) Sandstone comprises two distinctive architectures: a lower braided fluvial and an upper meandering fluvial. Braided fluvial deposits are typically 30 to 80 ft thick, and are laterally persistent filling an incised valley wider than the largest producing fields. The lower contact is irregular with local relief of 50 ft. The braided-fluvial deposits consist of 100-400-ft wide, 5-15-ft thick channel-fill elements. Each channel-fill interval is limited laterally by an erosional contact or overbank deposits, and is separated vertically by discontinuous mudstones or highly concentrated mudstone interclast lag conglomerates. Low-angle parallel-stratified or trough cross-stratified medium- to coarse-grained sandstones volumetrically dominate. This section has a blocky well log profile. Meandering fluvial deposits are typically 100 to 150 ft thick and comprise multiple discrete genetic intervals.

Fluvial sedimentology of a major uranium-bearing sandstone - A study of the Westwater Canyon member of the Morrison Formation, San Juan Basin, New Mexico

International Nuclear Information System (INIS)

Turner-Peterson, C.E.

1986-01-01

The Westwater Canyon Member of the Morrison Formation, the main ore-bearing sandstone in the San Juan basin, consists of a sequence of vertically stacked braided stream deposits. Three fluvial units within the sequence can be delineated in the basin. Volcanic pebbles are abundant in the middle fluvial unit, in a zone that forms a crude time line. A pronounced thickening of sandstone in the Westwater Canyon Member north of Gallup, once believed to be the apex of a large alluvial fan, is now thought to merely reflect a greater accumulation of sediment in response to downwarping of the basin in that area. Provenance studies suggest that highlands that contributed detritus to Westwater Canyon streams were located several hundred kilometers to the west and southwest of the San Juan basin, and thus fan apices would also have been several hundred kilometers upstream. The fluvial units recognized in the basin may well be coalesced distal fan deposits, but are probably best interpreted as vertically stacked braided steam sequences. Facies changes in fine-grained interbeds of the Westwater Canyon probably have greater significance in terms of localizing ore than any special attribute of the fluvial sandstones themselves. Uranium ore generally occurs in sandstones that are interbedded with greenish-gray lacustrine mudstones. Pore waters that were expelled from these mudstones are thought to have been the source of the pore-filling organic matter (humate) associated with primary uranium ore in nearby sandstones

Geologic-seismic models, prediction of shallow-water lacustrine delta sandbody and hydrocarbon potential in the Late Miocene, Huanghekou Sag, Bohai Bay Basin, northern China

Directory of Open Access Journals (Sweden)

Hao Liu

2018-01-01

Full Text Available The Huanghekou Sag is located at the southeast part of the Bohai Bay Basin, northern China. Large-scale shallow lake delta developed in the Neogene provided suitable geological conditions for the formation of a subtle oil-gas reservoir in this area. The key for analyzing sandstone reservoir and sedimentary facies is by using seismic attributes (amplitude to establish the relationship between lithology combination and seismic attributes. The lower unit of Late Miocene Minghuazhen Formation at the BZ34 block in the Huanghekou Sag was subdivided into 10 parasequence sets (PSS. Thicker sandstones mainly occurred in PSS1 and PSS10, whereas thin sandstones are mostly observed within other parasequence sets. This study presents statistics and analyses of lithology, i.e., statistics of root-mean-square (RMS amplitude and lithology of well locations in different parasequence sets of the study area, as well as 1-D forward seismic models of 7 types of lithology combinations, the establishment of a spatial distribution of 2-D sandbody, forward seismic models etc. Our study indicates that high amplitude peaks correspond to thicker sandbodies, while low amplitude indicates non-development of sandbodies (generally less than 2 m, and medium amplitude agrees well with large sets of mudstones interbedded with medium and thinner sandstones. Different sand–mudstone combinations genetically reflect a combination of multiple micro-facies, therefore, amplitude features can predict sandbodies as well as facies characteristics.

Integrated ground-based hyperspectral imaging and geochemical study of the Eagle Ford Group in West Texas

Science.gov (United States)

Sun, Lei; Khan, Shuhab; Godet, Alexis

2018-01-01

This study used ground-based hyperspectral imaging to map an outcrop of the Eagle Ford Group in west Texas. The Eagle Ford Group consists of alternating layers of mudstone - wackestone, grainstone - packstone facies and volcanic ash deposits with high total organic content deposited during the Cenomanian - Turonian time period. It is one of the few unconventional source rock and reservoirs that have surface representations. Ground-based hyperspectral imaging scanned an outcrop and hand samples at close ranges with very fine spatial resolution (centimeter to sub-millimeter). Spectral absorption modeling of clay minerals and calcite with the modified Gaussian model (MGM) allowed quantification of variations of mineral abundances. Petrographic analysis confirmed mineral identifications and shed light on sedimentary textures, and major element geochemistry supported the mineral quantification. Mineral quantification resulted in mapping of mudstone - wackestone, grainstone - packstone facies and bentonites (volcanic ash beds). The lack of spatial associations between the grainstones and bentonites on the outcrop calls into question the hypothesis that the primary productivity is controlled by iron availability from volcanic ash beds. Enrichment of molybdenum (Mo) and uranium (U) indicated "unrestricted marine" paleo-hydrogeology and anoxic to euxinic paleo-redox bottom water conditions. Hyperspectral remote sensing data also helped in creating a virtual outcrop model with detailed mineralogical compositions, and provided reservoir analog to extract compositional and geo-mechanical characteristics and variations. The utilization of these new techniques in geo-statistical analysis provides a workflow for employing remote sensing in resource exploration and exploitation.

Lower Cretaceous paleo-Vertisols and sedimentary interrelationships in stacked alluvial sequences, Utah, USA

Science.gov (United States)

Joeckel, R. M.; Ludvigson, G. A.; Kirkland, J. I.

2017-11-01

The Yellow Cat Member of the Cedar Mountain Formation in Poison Strip, Utah, USA, consists of stacked, erosionally bounded alluvial sequences dominated by massive mudstones (lithofacies Fm) with paleo-Vertisols. Sediment bodies within these sequences grade vertically and laterally into each other at pedogenic boundaries, across which color, texture, and structures (sedimentary vs. pedogenic) change. Slickensides, unfilled (sealed) cracks, carbonate-filled cracks, and deeper cracks filled with sandstone; the latter features suggest thorough desiccation during aridification. Thin sandstones (Sms) in some sequences, typically as well as laminated to massive mudstones (Flm) with which they are interbedded in some cases, are interpreted as avulsion deposits. The termini of many beds of these lithofacies curve upward, parallel to nearby pedogenic slickensides, as the features we call ;turnups.; Turnups are overlain or surrounded by paleosols, but strata sheltered underneath beds with turnups retain primary sedimentary fabrics. Turnups were produced by movement along slickensides during pedogenesis, by differential compaction alongside pre-existing gilgai microhighs, or by a combination of both. Palustrine carbonates (lithofacies C) appear only in the highest or next-highest alluvial sequences, along with a deep paleo-Vertisol that exhibits partially preserved microrelief at the base of the overlying Poison Strip Member. The attributes of the Yellow Cat Member suggest comparatively low accommodation, slow accumulation, long hiatuses in clastic sedimentation, and substantial time intervals of subaerial exposure and pedogenesis; it appears to be distinct among the members of the Cedar Mountain Formation in these respects.

The source rock characters of U-rich granite

Energy Technology Data Exchange (ETDEWEB)

Mingyue, Feng; Debao, He [CNNC Key Laboratory of Uranium Resources Exploration and Evaluation Technology, Beijing Research Institute of Uranium Geology (China)

2012-03-15

This paper discusses the stratum composition, lithological association, uranium content of crust and the activation, migration, concentration of uranium at each tectonic cycle in South China. The authors point out that the source rock of U-rich granite is U-rich continental crust which is rich in Si, Al and K. The lithological association is mainly composed of terrestrial clastic rocks formation of mudstone and sandstone, mingled with intermediate-acidic, mafic pyroclastic rocks and carbonate rocks formation. During tectonic movements, the rocks had undergone regional metamorphism, migmatitization, granitization, and formed U-rich granites finally. (authors)

The source rock characters of U-rich granite

International Nuclear Information System (INIS)

Feng Mingyue; He Debao

2012-01-01

This paper discusses the stratum composition, lithological association, uranium content of crust and the activation, migration, concentration of uranium at each tectonic cycle in South China. The authors point out that the source rock of U-rich granite is U-rich continental crust which is rich in Si, Al and K. The lithological association is mainly composed of terrestrial clastic rocks formation of mudstone and sandstone, mingled with intermediate-acidic, mafic pyroclastic rocks and carbonate rocks formation. During tectonic movements, the rocks had undergone regional metamorphism, migmatitization, granitization, and formed U-rich granites finally. (authors)

Rare earth phosphate occurrence in Resende formation, paleogene of continental rift in Southeast Brazil; Ocorrencia de fosfato de terras raras na formacao Resende, paleogeno do rift continental do Sudeste do Brasil

Energy Technology Data Exchange (ETDEWEB)

Sant' Anna, Lucy Gomes; Riccomini, Claudio; Valarelli, Jose Vicente [Sao Paulo Univ., SP (Brazil). Inst. de Geociencias]. E-mail: lsantann@hotmail.com; comin@usp.br

1999-12-01

Petrographic studies and SEM/EDS and XRD analyses revealed the presence of a phosphate with Ca and REE (La, Nd) in a mudstone deposit of the Resende Formation, located on the northern border of the Resende Basin. The morphological characteristics (prismatic hexagonal habit) and chemical composition of the phosphate allow including this mineral in the rhabdophane group. This phosphate is authigenic and its origin is related to the dissolution of detritic apatite grains, probably by alkaline hydrothermal solutions. These solutions also provided some of the elements involved in the rhabdophane crystallization. (author)

Clay minerals assemblage in the Neogene fluvial succession of the Pishin Belt, Pakistan

DEFF Research Database (Denmark)

Kasi, Aimal Khan; Kassi, Akhtar Muhammad; Friis, Henrik

2014-01-01

indicate derivation of material from the Pre-Miocene sedimentary and meta-sedimentary terrains of the Pishin Belt. X-ray diffraction (XRD) analyses indicate that clay minerals in various mudstones and sandstone samples are identical and detrital in nature and include smectite, chlorite, illite, serpentine...... and kaolinite. Smectite and chlorite are most probably derived from the metavolcanic and mafic volcanic rocks, respectively. Presence of serpentine in samples of the Bostan Formation indicates altered ultramafic rocks as one of the source terrains. Illite is probably recycled from the older sedimentary...

Early Cambrian wave-formed shoreline deposits

DEFF Research Database (Denmark)

Clemmensen, Lars B; Glad, Aslaug Clemmensen; Pedersen, Gunver Krarup

2017-01-01

-preserved subaqueous dunes and wave ripples indicates deposition in a wave-dominated upper shoreface (littoral zone) environment, and the presence of interference ripples indicates that the littoral zone environment experienced water level fluctuations due to tides and/or changing meteorological conditions. Discoidal....... During this period, wave-formed shoreline sediments (the Vik Member, Hardeberga Formation) were deposited on Bornholm and are presently exposed at Strøby quarry. The sediments consist of fine- and medium-grained quartz-cemented arenites in association with a few silt-rich mudstones. The presence of well...

Self-healing of Fractures in Argillaceous Media from the Geomechanical Point of View

International Nuclear Information System (INIS)

Horseman, Steve

2001-01-01

Presently, there is no established theory describing fracture self-healing and self-sealing processes in mud-rocks (clays, mud-stones and shales) and no methodology to assess the conditions under which these processes might be important. The author suggests that the modified Cam-Clay approach provides a useful conceptual and theoretical framework for the analysis of the largely hydro-mechanical process of self-sealing. Three basic hypotheses are proposed and applied to the problem of fracture self-sealing in the repository EDZ and to the more general question of fault sealing. (author)

The genesis of Kurišková U-Mo ore deposit

International Nuclear Information System (INIS)

Demko, R.; Biroň, A.; Novotný, L.; Bartalský, B.

2014-01-01

The U-Mo ores of the known uranium deposit Kurišková located in the Huta volcano-sedimentary complex (HVC) of lower Permian age belongs to the Petrova Hora Formation of the North-Gemeric tectonic unit (Western Carpathians). The HVC is built up by volcanic rocks of bimodal basalt-rhyolite association, intercalated with sandstones, mudstones and claystones. Based on the sedimentary facies reconstruction, it is supposed paleoenvironment of seasonally flooded shallow lakes of continental fluvial plain with transition to estuaries and shallow marine facies of continental shelf in the upper part of HVC.

Compaction of microfossil and clay-rich chalk sediments

DEFF Research Database (Denmark)

Fabricius, Ida Lykke

2001-01-01

The aim of this study was to evaluate the role of microfossils and clay in the compaction of chalk facies sediments. To meet this aim, chalk sediments with varying micro texture were studied. The sediments have been tested uniaxially confined in a stainless-steel compaction cell. The sediments are......: 1) Pure carbonate chalk with mudstone texture from Stevns Klint (Denmark), 2) Relatively pure chalk sediments with varying content of microfossils from the Ontong Java Plateau (Western Pacific), 3) Clay-rich chalk and mixed sediments from the Caribbean. The tested samples were characterised...

Rare earth, major and trace element composition of Leg 127 sediments

Science.gov (United States)

Murray, R.W.; Buchholtz ten Brink, Marilyn R.; Brumsack, Hans-Juergen; Gerlach, David C.; Russ III, G. Price

1992-01-01

The relative effects of paleoceanographic and paleogeographic variations, sediment lithology, and diagenetic processes on the final preserved chemistry of Japan Sea sediments are evaluated by investigating the rare earth element (REE), major element, and trace element concentrations in 59 squeeze-cake whole-round and 27 physical-property sample residues from Sites 794, 795, and 797, cored during ODP Leg 127. The most important variation in sedimentary chemical composition is the increase in SiO2 concentration through the Pliocene diatomaceous sequences, which dilutes most other major and trace element components by various degrees. This biogenic input is largest at Site 794 (Yamato Basin), moderately developed at Site 797 (Yamato Basin), and of only minor importance at Site 795 (Japan Basin), potentially reflecting basinal contrasts in productivity with the Yamato Basin recording greater biogenic input than the Japan Basin and with the easternmost sequence of Site 794 lying beneath the most productive waters. There are few systematic changes in solid-phase chemistry resulting from the opal-A/opal-CT or opal-CT/quartz silica phase transformations. Most major and trace element concentrations are controlled by the aluminosilicate fraction of the sediment, although the effects of diagenetic silica phases and manganese carbonates are of localized importance. REE total abundances (IREE) in the Japan Sea are strongly dependent upon the paleoceanographic position of a given site with respect to terrigenous and biogenic sources. REE concentrations at Site 794 overall correspond well to aluminosilicate chemical indices and are strongly diluted by SiO2 within the upper Miocene-Pliocene diatomaceous sequence. Eu/Eu* values at Site 794 reach a maximum through the diatomaceous interval as well, most likely suggesting an association of Eu/Eu* with the siliceous component, or reflecting slight incorporation of a detrital feldspar phase. XREE at Site 795 also is affiliated strongly

The lower Darriwilian (Middle Ordovician) at the northern extreme of the Mendoza Precordillera, Argentina: stratigraphic and biostratigraphic implications; El Darriwiliense inferior (Ordovícico Medio) en el extremo norte de la Precordillera de Mendoza, Argentina: implicaciones estratigráficas y bioestratigráficas

Energy Technology Data Exchange (ETDEWEB)

Beresi, M.S.; Bordonaro, O.L.; Heredia, S.E.; Mestre, A.; Toro, B.A.

2017-09-01

A tectonically affected Middle Ordovician succession crops out at the Los Guanacos quarry in the sierra de Las Higueras, in the Precordillera of Mendoza, western Argentina. This is represented by the San Juan Formation which is transitionally covered by a mixed carbonate-shaly unit of dark colours, 1.5 metres thick (transfacies) which can be interpreted as the base of the Los Azules Formation. A 5-cm thick intra-bioclastic pack/grainstone bed interbedded in the lower part of this unit has been interpreted as a tempestite. It is characterized both by a millimetre-thick erosional boundary, just above the dark mudstone layer and strong mechanical distribution of bioclasts and intraclasts, suggesting sedimentary structures associated with a storm event of high energy possibly occurring in the middle part of the platform. Towards the bottom, a hummocky structure thin interval, under the dark mudstone, is interpreted as the record of another tempestite event. The mudstone represents the post-storm event reflecting the low energy of the marine water environment. The lenticular layer contains predominantly lingulid shells, trilobites and graptolites, all highly fragmented, which suggests they have been reworked and subsequently mixed and quickly redeposited during a storm event that caused the mortality of these faunas. The trilobites Mendolaspis salagastensis and indeterminate species of Matagnostidae, Illaenidae, Leiostegiidae, Encrinuridae, Telephinidae and Trinucleidae have been recorded for the first time at this locality. The conodont fauna allows the identification of the Yangtzeplacognathus crassus Zone, which indicates the lower Darriwilian (Middle Ordovician). Graptolites assignable to evisograptus cf. Levisograptus austrodentatus and Levisograptus sp. are described for the first time in the studied area and biostratigraphic implications validate the early Darriwilian age for the bearing levels. Finally, based on the studied records, correlation with different

Grainstones and cementstone mounds: The Trogkofel summit section (Lower Permian, Carnic Alps, Austria).

Science.gov (United States)

Schaffhauser, M.; Sanders, D.; Krainer, K.

2009-04-01

In the Carnic Alps, Austria, an Artinskian succession 400 m thick of shallow-water bioclastic limestones and of mounds composed of ?Archaeolithophyllum, Archaeolithoporella and abundant fibrous cementstone (after former aragonite) records deposition along a "grainstone-dominated" platform margin. The section was taken along the route through the east-facing cliff of Trogkofel. The Trogkofel Limestone (Artinskian pro parte) is excellently exposed and preserved the most complete along this route, but no section has hitherto been logged. The total thickness of the Trogkofel Limestone probably is about 550 meters; the summit section comprises its upper 400 meters. The section consists mainly of shallow-water bioclastic limestones (grainstones, packstones, rudstones) intercalated with cementstone mounds. Both the bioclastic limestones and the mounds typically are thick-bedded to, more commonly, unbedded. Throughout the section, intervals a few tens of meters in thickness dominated by bioclastic limestones change vertically with intervals dominated by cementstone mounds. Up-section, no clear-cut trend with respect to prevalent facies, mean depositional water depth, and energy index is obvious. Furthermore, no lime-muddy, meter-scale peritidal cycles, and no teepee structures and no pisolite levels were identified; thin intervals of fenestral lime mudstones and/or of cryptmicrobially-laminated limestones are very rare. The bioclastic limestones commonly weather out unstratified, or show subhorizontal stratification or, more rarely, low-angle cross-stratification. In the upper 100 meters of section, grainstones to fine-grained rudstones rich in keystone vugs are prevalent. The cementstone mounds comprise intervals up to a few meters in thickness; the biogenic component is characterized by foliose crusts pertaining to ?Archaeolithophyllum hidensis and Archaeolithoporella, overgrown by Tubiphytes and fenestrate bryozoans. The ?Archaeolithophyllum-Archaeolithoporella crusts

Natural diatomite process for removal of radioactivity from liquid waste

Energy Technology Data Exchange (ETDEWEB)

Osmanlioglu, Ahmet Erdal [Radioactive Waste Management Unit (RWMU), Turkish Atomic Energy Authority, Cekmece Nuclear Research and Training Center, Altinsehir Yolu 5 km. Halkali, 34303K Cekmece, Istanbul (Turkey)]. E-mail: Erdal.Osmanlioglu@taek.gov.tr

2007-01-15

Diatomite has a number of unique physical properties and has found diversified industrial utilization. The filtration characteristics are particularly significant in the purification of liquids. The purpose of this study was to test natural diatomaceous earth (diatomite) as an alternative material that could be used for removal of radioactivity from liquid waste. A pilot-scale column-type device was designed. Natural diatomite samples were ground, sieved and prepared to use as sorption media. In this study, real waste liquid was used as radioactive liquid having special conditions. The liquid waste contained three radionuclides (Cs-137, Cs-134 and Co-60). Following the treatment by diatomite, the radioactivity of liquid waste was reduced from the initial 2.60 Bq/ml to less than 0.40 Bq/ml. The results of this study show that most of the radioactivity was removed from the solution by processing with diatomite.

Natural diatomite process for removal of radioactivity from liquid waste

International Nuclear Information System (INIS)

Osmanlioglu, Ahmet Erdal

2007-01-01

Diatomite has a number of unique physical properties and has found diversified industrial utilization. The filtration characteristics are particularly significant in the purification of liquids. The purpose of this study was to test natural diatomaceous earth (diatomite) as an alternative material that could be used for removal of radioactivity from liquid waste. A pilot-scale column-type device was designed. Natural diatomite samples were ground, sieved and prepared to use as sorption media. In this study, real waste liquid was used as radioactive liquid having special conditions. The liquid waste contained three radionuclides (Cs-137, Cs-134 and Co-60). Following the treatment by diatomite, the radioactivity of liquid waste was reduced from the initial 2.60 Bq/ml to less than 0.40 Bq/ml. The results of this study show that most of the radioactivity was removed from the solution by processing with diatomite

Natural diatomite process for removal of radioactivity from liquid waste.

Science.gov (United States)

Osmanlioglu, Ahmet Erdal

2007-01-01

Diatomite has a number of unique physical properties and has found diversified industrial utilization. The filtration characteristics are particularly significant in the purification of liquids. The purpose of this study was to test natural diatomaceous earth (diatomite) as an alternative material that could be used for removal of radioactivity from liquid waste. A pilot-scale column-type device was designed. Natural diatomite samples were ground, sieved and prepared to use as sorption media. In this study, real waste liquid was used as radioactive liquid having special conditions. The liquid waste contained three radionuclides (Cs-137, Cs-134 and Co-60). Following the treatment by diatomite, the radioactivity of liquid waste was reduced from the initial 2.60 Bq/ml to less than 0.40 Bq/ml. The results of this study show that most of the radioactivity was removed from the solution by processing with diatomite.

Late Holocene climate variability from Lake Pupuke maar, Auckland, New Zealand

Science.gov (United States)

Striewski, B.; Shulmeister, J.; Augustinus, P. C.; Soderholm, J.

2013-10-01

Spectral analyses of quasi-annual organo-diatomaceous laminae couplets in an Auckland maar lake indicate brief (sub-decadal scale) episodes with strong spectral power and long periods of weak to no spectral power between c. 1700 to c. 550 cal. yr BP. Laminae couplet thickness appears to be a function of changes in wind flow over the basin, with enhanced wind flow deepening the mixing zone and providing additional nutrients for laminae formation. Aeolian dust from Australia amplifies the wind signal. Spectral signals in the high power episodes are focused in Auckland climate whereby strongly negative (positive) ENSO are associated with enhanced (diminished) SW airflow over Auckland. ENSO events interact in the modern climate and the spectral results indicate that this is the case when spectral power is strong in the laminae. These results highlight strong but intermittent ENSO activity between 600 and 1400 cal. yr BP.

Control of poultry red mites

DEFF Research Database (Denmark)

Kilpinen, Ole; Steenberg, Tove

2008-01-01

The poultry red mite (PRM), Dermanyssus gallinae, is the most important ectoparasite in European egg production. The mites hide in cracks and crevices in the near vicinity of the resting places of the birds, coming out to feed mainly during the night. Under favourable conditions the population can...... grow rapidly, leading to serious problems. Large mite populations may cause anaemia or even death to the poultry, but also in lower numbers mites may be a nuisance to the birds causing decreased egg production and egg quality. Furthermore, they may have the potential of acting as reservoir......-pathogenic fungi and desiccant dust. The dust is diatomaceous earth (of natural origin), synthetic silica products or combinations of the two. The progress of the work with desiccant dusts will be reported. So far, 7 different products have been tested in the laboratory with regard to their efficacy, speed...

Diatoms - nature materials with great potential for bioapplications

Directory of Open Access Journals (Sweden)

Medarević Đorđe P.

2016-01-01

Full Text Available Diatoms are widespread unicellular photosynthetic algae that produce unique highly ordered siliceous cell wall, called frustule. Micro- to nanoporous structure with high surface area that can be easily modified, high mechanical resistance, unique optical features (light focusing and luminescence and biocompatibility make diatom frustule as a suitable raw material for the development of devices such as bio- and gas sensors, microfluidic particle sorting devices, supercapacitors, batteries, solar cells, electroluminescent devices and drug delivery systems. Their wide availability in the form of fossil remains (diatomite or diatomaceous earth as well as easy cultivation in the artificial conditions further supports use of diatoms in many different fields of application. This review focused on the recent achievements in the diatom bioapplications such as drug delivery, biomolecules immobilization, bio- and gas sensing, since great progress was made in this field over the last several years.

Permanganate diffusion and reaction in sedimentary rocks.

Science.gov (United States)

Huang, Qiuyuan; Dong, Hailiang; Towne, Rachael M; Fischer, Timothy B; Schaefer, Charles E

2014-04-01

In situ chemical oxidation using permanganate has frequently been used to treat chlorinated solvents in fractured bedrock aquifers. However, in systems where matrix back-diffusion is an important process, the ability of the oxidant to migrate and treat target contaminants within the rock matrix will likely determine the overall effectiveness of this remedial approach. In this study, a series of diffusion experiments were performed to measure the permanganate diffusion and reaction in four different types of sedimentary rocks (dark gray mudstone, light gray mudstone, red sandstone, and tan sandstone). Results showed that, within the experimental time frame (~2 months), oxidant migration into the rock was limited to distances less than 500 μm. The observed diffusivities for permanganate into the rock matrices ranged from 5.3 × 10(-13) to 1.3 × 10(-11) cm(2)/s. These values were reasonably predicted by accounting for both the rock oxidant demand and the effective diffusivity of the rock. Various Mn minerals formed as surface coatings from reduction of permanganate coupled with oxidation of total organic carbon (TOC), and the nature of the formed Mn minerals was dependent upon the rock type. Post-treatment tracer testing showed that these Mn mineral coatings had a negligible impact on diffusion through the rock. Overall, our results showed that the extent of permanganate diffusion and reaction depended on rock properties, including porosity, mineralogy, and organic carbon. These results have important implications for our understanding of long-term organic contaminant remediation in sedimentary rocks using permanganate. Copyright © 2014 Elsevier B.V. All rights reserved.

Imaging Pathways in Fractured Rock Using Three-Dimensional Electrical Resistivity Tomography.

Science.gov (United States)

Robinson, Judith; Slater, Lee; Johnson, Timothy; Shapiro, Allen; Tiedeman, Claire; Ntarlagiannis, Dimitrios; Johnson, Carole; Day-Lewis, Frederick; Lacombe, Pierre; Imbrigiotta, Thomas; Lane, John

2016-03-01

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three-dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high-resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time-lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone. © 2015, National Ground Water Association.

Mineralogy, geochemistry, and palynology of modern and late Tertiary mangrove deposits in the Barreiras Formation of Mosqueiro Island, northeastern Pará state, eastern Amazonia

Science.gov (United States)

Behling, Hermann; da Costa, Marcondes Lima

2004-12-01

A coastal environment has been interpreted from 110 cm thick mudstone deposits found at the base of a 10 m immature laterite profile, which forms the modern coastal cliff on Mosqueiro Island in northeastern Pará state, northern Brazil. The late Tertiary sediment deposits of the Barreiras Formation are studied by multi-element geochemistry and pollen analyses. The mineralogical and geochemical results show that the gray, organic-rich deposits are composed of kaolinite, quartz, and illite/muscovite, as well as pyrite and anatase. They are rich in SiO 2, Al 2O 3, and some FeO. The composition is homogenous, indicating that the detritus source area is formed of lateritic soils derived from acid rock composition. Their chemical composition, including trace elements, is somewhat comparable to continental shale, and the values are below the upper continental Earth crust composition. The pollen analytical data document that the mudstone deposits were formed by an ancient mangrove ecosystem. Mineralogical, geochemical, and pollen analytical data obtained from late Tertiary mangrove deposits are compared with modern mangrove deposits from the Bragança Peninsula of the northeastern coast of Pará state. Although the pollen composition of the deposits is very similar to the modern one, the geochemical and mineralogical composition is different. Smectite was only found in the modern deposit; illite/mica occurs in the ancient deposit, along with Mg, K, and Na. The pollen signature and detrital minerals (kaolinite, quartz and anatase) found in both mangrove deposits show that during the Miocene, a humid tropical climate condition prevailed, similar to modern conditions.

Palynological and bulk geochemical constraints on the paleoceanographic conditions across the Frasnian-Famennian boundary, New Albany Shale, Indiana

Energy Technology Data Exchange (ETDEWEB)

Rue, Sarah R. de la [Department of Geology and Geophysics, Louisiana State University, Baton Rouge, Louisiana 70803-4101 (United States); Rowe, Harold D.; Rimmer, Susan M. [Department of Earth and Environmental Sciences, Slone Research Building, University of Kentucky, Lexington KY 40506-0053 (United States)

2007-06-01

A down-core record of stable isotope and geochemical results is integrated with palynofacies (kerogen) data from the New Albany Shale (Indiana) to reconstruct environmental changes that occurred across the Frasnian-Famennian boundary. Preliminary interpretations are focused on developing several multiproxy linkages that will potentially lead toward a more robust understanding of the occurrence and significance of phytoplankton assemblage variations during the Late Devonian, a time of widespread black shale formation. Development of such linkages will potentially provide a more comprehensive assessment of the various controls on 1) primary production, and 2) carbon sequestration in a large, low-paleolatitude intracratonic basin. An abrupt change in the geochemical and biotic proxies for particulate organic matter across the Frasnian-Famennian boundary coincides with a distinct lithological change, characterized by laminated, brownish-black Famennian mudstones unconformably overlying alternating bioturbated, greenish-gray and non-bioturbated, dark-gray Frasnian mudstones. Elemental and isotopic profiles reflect different patterns of production, degradation, and removal of organic carbon in the two shale facies. A shift from acritarch- to prasinophyte-dominated waters across the boundary indicates the overall importance of bathymetric fluctuations, chemico-physical conditions, and nutrient availability related to eustatic sea-level change. A positive {delta}{sup 13}C{sub V-PDB} shift of 1.1 permille across the boundary is interpreted to be correlative with the global Upper Kellwasser Event. A preliminary model is proposed to explain the sustainable primary production during times of maximum flooding, thereby enhancing organic preservation during black shale formation. (author)

Evidence of orbital forcing in lake-level fluctuations in the Middle Eocene oil shale-bearing lacustrine successions in the Mudurnu-Göynük Basin, NW Anatolia (Turkey)

Science.gov (United States)

Ocakoğlu, F.; Açıkalın, S.; Yılmaz, İ. Ö.; Şafak, Ü.; Gökçeoğlu, C.

2012-08-01

Mudurnu-Göynük basin of the Sakarya Zone in NW Anatolia comprises ca. 1500 m thick Paleocene-Eocene terrestrial to shallow marine succession overlying the Late Cretaceous deeper marine progradational fore-arc sediments. Formed in a foreland setting in relation to southerly situated İzmir-Ankara suture zone, this terrestrial succession (regionally known as Kızılçay group) comprises a thin (nalysis on three correlative measured sections showed that mudstone, oil shale and thinner limestone alternations characterize the relatively deeper part of the Eocene lake with probable marine intervention, while thicker limestone, coal, marl and occasional oil shale alternations typify the southern relatively freshwater shoal areas. These facies are frequently organized as meter-scale symmetric to asymmetric transgressive-regressive cycles. Spectral analysis of the mudstone beds and the cycles within the lacustrine succession strongly indicates the occurrence of full bands of Milankovitch with the shortest precession cycle (19 ka) at ca. 2.30 m. Our observations further revealed quite rhythmic thin couplets with estimated durations of 365-730 yr that might represent abrupt climatic changes during deposition. On the other hand, longer duration (ca. 1 Ma) of shoaling and deepening trends in the studied sections were attributed basically to varying subsidence due to tectonic loading in the southerly suture zone. Lastly, regarding the distribution of depositional environments we propose that the oil shale exploration activities should be carried out within a 20 km wide E-W running belt while the southern limits of this belt is more prolific for coal resources.

Thermophysical Properties Along Curiosity's Traverse in Gale Crater, Mars, Derived from the REMS Ground Temperature Sensor

Science.gov (United States)

Vasavada, Ashwin R.; Piqueux, Sylvain; Lewis, Kevin W.; Lemmon, Mark T.; Smith, Michael Doyle

2016-01-01

The REMS instrument onboard the Mars Science Laboratory rover, Curiosity, has measured ground temperature nearly continuously at hourly intervals for two Mars years. Coverage of the entire diurnal cycle at 1 Hz is available every few martian days. We compare these measurements with predictions of surface atmosphere thermal models to derive the apparent thermal inertia and thermally derived albedo along the rovers traverse after accounting for the radiative effects of atmospheric water ice during fall and winter, as is necessary to match the measured seasonal trend. The REMS measurements can distinguish between active sand, other loose materials, mudstone, and sandstone based on their thermophysical properties. However, the apparent thermal inertias of bedrock dominated surfaces [approx. 350-550 J m(exp. -2) K(exp. -1 s(exp. -1/2 )] are lower than expected. We use rover imagery and the detailed shape of the diurnal ground temperature curve to explore whether lateral or vertical heterogeneity in the surface materials within the sensor footprint might explain the low inertias. We find that the bedrock component of the surface can have a thermal inertia as high as 650-1700 J m(exp. -2) K(exp. -1) s(exp. -1/2) for mudstone sites and approx. 700 J m(exp. -2) K(exp. -1) s(exp. - 1/2) for sandstone sites in models runs that include lateral and vertical mixing. Although the results of our forward modeling approach may be non-unique, they demonstrate the potential to extract information about lateral and vertical variations in thermophysical properties from temporally resolved measurements of ground temperature.

IODP Expedition 351 Lithostratigraphy: Volcaniclastic Record of Izu-Bonin-Mariana (IBM) Arc Initiation

Science.gov (United States)

Barth, A. P.; Brandl, P. A.; Li, H.; Hickey-Vargas, R.; Jiang, F.; Kanayama, K.; Kusano, Y.; Marsaglia, K. M.; McCarthy, A.; Meffre, S.; Savov, I. P.; Tepley, F. J., III; Yogodzinski, G. M.

2014-12-01

The destruction of lithospheric plates by subduction is a fundamentally important process leading to arc magmatism and the creation of continental crust, yet subduction initiation and early magmatic arc evolution remain poorly understood. For many arc systems, onset of arc volcanism and early evolution are obscured by metamorphism or the record is deeply buried; however, initial products of arc systems may be preserved in forearc and backarc sedimentary records. IODP Expedition 351 recovered this history from the dispersed ash and pyroclast record in the proximal rear-arc of the northern IBM system west of the Kyushu-Palau Ridge. Drilling at Site U1438 in the Amami Sankaku Basin recovered a thick volcaniclastic record of subduction initiation and the early evolution of the Izu-Bonin Arc. A 160-m thick section of Neogene sediment overlies 1.3 kilometers of Paleogene volcaniclastic rocks with andesitic average composition; this volcaniclastic section was deposited on mafic volcanic basement rocks. The thin upper sediment layer is primarily terrigenous, biogenic and volcaniclastic mud and ooze with interspersed ash layers. The underlying Eocene to Oligocene volcaniclastic rocks are 33% tuffaceous mudstone, 61% tuffaceous sandstone, and 6% conglomerate with volcanic and rare sedimentary clasts commonly up to pebble and rarely to cobble size. The clastic section is characterized by repetitive conglomerate and sandstone-dominated intervals with intervening mudstone-dominated intervals, reflecting waxing and waning of coarse arc-derived sediment inputs through time. Volcanic lithic clasts in sandstones and conglomerates range from basalt to rhyolite in composition and include well-preserved pumice, reflecting a lithologically diverse and compositionally variable arc volcanic source.

Combined tide and storm influence on facies sedimentation of miocene Miri Formation, Sarawak

International Nuclear Information System (INIS)

Yuniarta Ulfa; Nasiman Sapari; Zuhar Zahir Tuan Harith

2011-01-01

This study was conducted on the sedimentary rocks belonging to the Miri Formation (Middle - Late Miocene). The primary objective of the present study is to provide additional interpretation on the stratigraphy of the Miri Formation in the Miri Field based on the new information gathered from new outcrops in the area. Five outcrops were examined in detail on sedimentology and stratigraphy. Based on lithology, sedimentary structures, bedding geometry and traces fossil, the sediments of the Miri Formation were grouped into fourteen lithofacies. Influence of tide and storm during the depositional processes of the formation were indicated by the group of two main facies associations which are: (i) tide-dominated estuary; and (ii) wave-and-storm dominated facies associations. The tide-dominated estuary system of the Miri Formation are includes variety of sub environments: estuary mouth or tidal channel and sand bars (characterized by trough cross-stratified sandstone with mud drapes facies), estuary channel or upper flow regime of sand flat (characterized by parallel stratified sandstone with mud-laminas facies), mixed-tidal flat (characterized by wavy and flaser bedded sandstone facies), and mud-tidal flat (characterized by rhythmic stratified sandstone-mudstone and lenticular bedding facies). The wave-and-storm dominated varied from lower to middle shore face (characterized by hummocky cross-stratified sandstone and rhythmic parallel stratified sandstone and laminated siltstone facies), upper shore face (characterized by swaley cross-stratified sandstone), lower shore face inter bedded to bioturbated sandstone and siltstone facies), and offshore transitional (characterized by bioturbated sandstone and mudstone inter bedding with parallel to hummocky cross-stratified sandstone facies). (author)

Stratigraphic and structural data for the Conasauga Group and the Rome Formation on the Copper Creek fault block near Oak Ridge, Tennessee: preliminary results from test borehole ORNL-JOY No. 2

International Nuclear Information System (INIS)

Haase, C.S.; Walls, E.C.; Farmer, C.D.

1985-06-01

To resolve long-standing problems with the stratigraphy of the Conasauga Group and the Rome Formation on the Copper Creek fault block near Oak Ridge National Laboratory (ORNL), an 828.5-m-deep test borehole was drilled. Continuous rock core was recovered from the 17.7- to 828.5-m-deep interval; temperature, caliper, neutron, gamma-ray, and acoustic (velocity and televiewer) logs were obtained. The Conasauga Group at the study site is 572.4 m thick and comprises six formations that are - in descending stratigraphic order - Maynardville Limestone (98.8 m), Nolichucky Shale (167.9 m), Maryville Limestone (141.1 m), Rogersville Shale (39.6 m), Rutledge Limestone (30.8 m), and Pumpkin Valley Shale (94.2 m). The formations are lithologically complex, ranging from clastics that consist of shales, mudstones, and siltstones to carbonates that consist of micrites, wackestones, packstones, and conglomerates. The Rome Formation is 188.1 m thick and consists of variably bedded mudstones, siltstones, and sandstones. The Rome Formation thickness represents 88.1 m of relatively undeformed section and 100.0 m of highly deformed, jumbled, and partially repeated section. The bottom of the Rome Formation is marked by a tectonic disconformity that occurs within a 46-m-thick, intensely deformed interval caused by motion along the Copper Creek fault. Results from this study establish the stratigraphy and the lithology of the Conasauga Group and the Rome Formation near ORNL and, for the first time, allow for the unambiguous correlation of cores and geophysical logs from boreholes elsewhere in the ORNL vicinity. 45 refs., 26 figs., 2 tabs

Sedimentology of middle ordovician carbonates in the Argentine precordillera: evidence of regional relative sea-level changes

Science.gov (United States)

Keller, M.; Eberlein, S.; Lehnert, O.

1993-07-01

The Las Aguaditas Formation in the Argentine Precordillera of San Juan is the only Ordovician carbonate sequence deposited on a slope. Spiculites, mudstones and calcisiltites represent the autochthonous sediments, characterized by a fine lamination, rare fossils and their dark colour. The pelagic fauna consists of rare radiolarians/calcispheres, trinucleid trilobites, graptolites and conodonts. The latter are typical of an open marine environment and proved a Llanvirn—Llandeilo age for the Las Aguaditas Formation. In the upper part of the succession there are several intercalations of megabreccias. Their thickness decreases from about 20 to 4 m towards the top of the formation, accompanied by an increasing amount of carbonate turbidites. The clasts of the breccias are derived from the slope as well as the platform. Each of the megabreccia horizons represents a system of channels, lobes and interchannel deposits, which together form a slope apron. On top of the lower breccia a small biostrome developed, where bryozoans and crinoids are preserved in an autochthonous position. Sedimentation of the Las Aguaditas Formation started with the drowning of the underlying carbonate platform (San Juan limestones). Near the Arenig-Llanvirn boundary, a rapid ecstatic sea-level rise led to the deposition of graptolitic black shales and mudstones. Upwards, allochthonous carbonates become increasingly abundant. The onset of megabreccia deposition coincides with a major relative sea-level fall, caused by block movements in connection with rifting. The subsequent transition from breccia formation towards turbiditic sedimentation corresponds to an environmental shift from the slope towards the toe of slope and basin and marks a renewed moderate sea-level rise.

Imaging pathways in fractured rock using three-dimensional electrical resistivity tomography

Science.gov (United States)

Robinson, Judith; Slater, Lee; Johnson, Timothy B.; Shapiro, Allen M.; Tiedeman, Claire; Ntlargiannis, Dimitrios; Johnson, Carole D.; Day-Lewis, Frederick D.; Lacombe, Pierre; Imbrigiotta, Thomas; Lane, John W.

2016-01-01

Major challenges exist in delineating bedrock fracture zones because these cause abrupt changes in geological and hydrogeological properties over small distances. Borehole observations cannot sufficiently capture heterogeneity in these systems. Geophysical techniques offer the potential to image properties and processes in between boreholes. We used three-dimensional cross borehole electrical resistivity tomography (ERT) in a 9 m (diameter) × 15 m well field to capture high-resolution flow and transport processes in a fractured mudstone contaminated by chlorinated solvents, primarily trichloroethylene. Conductive (sodium bromide) and resistive (deionized water) injections were monitored in seven boreholes. Electrode arrays with isolation packers and fluid sampling ports were designed to enable acquisition of ERT measurements during pulsed tracer injections. Fracture zone locations and hydraulic pathways inferred from hydraulic head drawdown data were compared with electrical conductivity distributions from ERT measurements. Static ERT imaging has limited resolution to decipher individual fractures; however, these images showed alternating conductive and resistive zones, consistent with alternating laminated and massive mudstone units at the site. Tracer evolution and migration was clearly revealed in time-lapse ERT images and supported by in situ borehole vertical apparent conductivity profiles collected during the pulsed tracer test. While water samples provided important local information at the extraction borehole, ERT delineated tracer migration over spatial scales capturing the primary hydrogeological heterogeneity controlling flow and transport. The fate of these tracer injections at this scale could not have been quantified using borehole logging and/or borehole sampling methods alone.

Block Slides on Extremely Weak Tectonic Clay Seams in Openly Folded Tertiary Mud-Rocks at Auckland and the Rangitikei Valley, North Island, New Zealand

Science.gov (United States)

Prebble, Warwick M.; Williams, Ann L.

2016-06-01

Block slides have developed on extremely weak, thin clay seams of tectonic origin, parallel to bedding in gently dipping sandstones and mudstones of Tertiary age. Two areas of noted instability are investigated at Auckland and the Rangitikei valley. Dimensions range from 100 m across × 100 m long for short displacement block slides up to 4 km across × 3 km long for large landslide complexes in which block slides are a major component. Displacements of blocks range from incipient (cm) through short (30 m) to 2 or 3 km for large slides. Many of the Auckland slides are dormant but likely to move in a 2000 year return period earthquake or 100 year high intensity rain storm. At Rangitikei there are many active, younger slides. Sliding rates for active failures vary from a few cm/year to 50 m in 30 min. Host rocks are weak to very weak clayey sandstones and sandy mudstones. The seams are rich in smectite. They have polished and crushed walls, may have slickensides and some contain rounded rock fragments. Laboratory shear strength of the seams is 13 kPa cohesion and 13° friction, with a lower bound of 8° at zero cohesion. Strength is increased at the field scale by waviness, steps and splays. Continuity can be demonstrated over distances of hundreds of metres. Key investigation methods were mapping, shafts and trenches. Tectonic uplift, folding and faulting of the weak Tertiary strata and river down-cutting are perpetuating block slide development.

Helium measurements of pore fluids obtained from the San Andreas Fault Observatory at Depth (SAFOD, USA) drill cores

Science.gov (United States)

Ali, S.; Stute, M.; Torgersen, T.; Winckler, G.; Kennedy, B. M.

2011-02-01

4He accumulated in fluids is a well established geochemical tracer used to study crustal fluid dynamics. Direct fluid samples are not always collectable; therefore, a method to extract rare gases from matrix fluids of whole rocks by diffusion has been adapted. Helium was measured on matrix fluids extracted from sandstones and mudstones recovered during the San Andreas Fault Observatory at Depth (SAFOD) drilling in California, USA. Samples were typically collected as subcores or from drillcore fragments. Helium concentration and isotope ratios were measured 4-6 times on each sample, and indicate a bulk 4He diffusion coefficient of 3.5 ± 1.3 × 10-8 cm2 s-1 at 21°C, compared to previously published diffusion coefficients of 1.2 × 10-18 cm2 s-1 (21°C) to 3.0 × 10-15 cm2 s-1 (150°C) in the sands and clays. Correcting the diffusion coefficient of 4Hewater for matrix porosity (˜3%) and tortuosity (˜6-13) produces effective diffusion coefficients of 1 × 10-8 cm2 s-1 (21°C) and 1 × 10-7 (120°C), effectively isolating pore fluid 4He from the 4He contained in the rock matrix. Model calculations indicate that <6% of helium initially dissolved in pore fluids was lost during the sampling process. Complete and quantitative extraction of the pore fluids provide minimum in situ porosity values for sandstones 2.8 ± 0.4% (SD, n = 4) and mudstones 3.1 ± 0.8% (SD, n = 4).

Development of early diagenetic silica and quartz morphologies — Examples from the Siri Canyon, Danish North Sea

DEFF Research Database (Denmark)

Weibel, Rikke; Friis, Henrik; Kazerouni, Afsoon Moatari

2010-01-01

in the following way: 1. Opal rims; characteristic of the initial phase of the silica diagenesis in most sandstone units in the Siri Canyon. Thick opal rims characterise the sandstone parts adjacent to the mudstone units in the Stine segment of the Siri Field. 2. Microquartz (quartz crystals with a size of 1–5 μm......); seen as coatings on the opal rims, both ordered and random. 3. Cavity overgrowth; found as quartz outgrowths in circular and angular cavities formed by dissolution of early authigenic phases. Angular cavities in the microquartz coatings origin from dissolution of clinoptilolite, possibly with a source...

Hydrogeology of an ancient arid closed basin: Implications for tabular sandstone-hosted uranium deposits

International Nuclear Information System (INIS)

Sanford, R.F.

1990-01-01

Hydrogeologic modeling shows that tabular-type uranium deposits in the grants uranium region of the San Juan basin, New Mexico, formed in zones of ascending and discharging regional ground-water flow. The association of either lacustrine mudstone or actively subsiding structures and uranium deposits can best be explained by the occurrence of lakes at topographic depressions where ground water having different sources and compositions is likely to converge, mix, and discharge. Ascending and discharging flow also explains the association of uranium deposits with underlying evaporites and suggests a brine interface. The simulations contradict previous suggestions that ground water moved downward in the mudflat

The effect of sedimentation background of depression target stratum containing mineral in Erlian basin, Ulanqab to uranium mineralization type

International Nuclear Information System (INIS)

Kang Shihu; Jiao Yangquan; Men Hong; Kuang Wenzhan

2012-01-01

The ore bearing stratum in depression of Ulanqab contains target stratum of lower cretaceous Saihan formation, upper cretaceous Erlian formation, paleogene system etc. The uranium mineralization type which have found by now contains sandstone type, mudstone type and coal petrography. The genetic type of mineral deposit contains paleovalley-type, reformed type after superposition with sedimentation and diagenesis by sedimentation. Uranium mineralization of both the natural type and genetic type have close relationship with its ore bearing stratum. Different geological background forms different sedimentary system combination, and different sedimentary system combination forms different uranium mineralization type. (authors)

Palynology and stratigraphy preliminary study and the perforation 313/1, lower Permian. Uruguay

International Nuclear Information System (INIS)

Beri, A; Daners, G.; Spoturno, J.

1998-01-01

The palynomorphs in the bore 313/1 of the Direccion Nacional de Mineria y Geologia are analyzed. Twenty three samples were processed, and only 9 were fertile. The lithologies correspond to sandstones of variable grain size, to mudstone and to diamictite, all of them assigned to the San Gregorio and Tres Islas Fms. The most abundant genera of sporare are essentially represented by monosaccate grains. Bisaccate and striated grains are very scare. The palynoflora is comparable with those studied in Brazil in the Fm Rio Bonito. Therefore, it is proposed that the sediments studied were deposited in the early Permian. (author)

Sampling and treatment of rock cores and groundwater under reducing environments of deep underground

International Nuclear Information System (INIS)

Ebashi, Katsuhiro; Yamaguchi, Tetsuji; Tanaka, Tadao

2005-01-01

A method of sampling and treatment of undisturbed rock cores and groundwater under maintained reducing environments of deep underground was developed and demonstrated in a Neogene's sandy mudstone layer at depth of GL-100 to -200 m. Undisturbed rock cores and groundwater were sampled and transferred into an Ar gas atmospheric glove box with minimized exposure to the atmosphere. The reducing conditions of the sampled groundwater and rock cores were examined in the Ar atmospheric glove box by measuring pH and Eh of the sampled groundwater and sampled groundwater contacting with disk type rock samples, respectively. (author)

Evolution of the east-central San Jose del Cabo basin, Baja California Sur, Mexico

Science.gov (United States)

McTeague, M. S.; Umhoefer, P. J.; Schwennicke, T.; Ingle, J. C.; Cortes Martinez, M.

2006-12-01

The San Jose del Cabo basin at the southern tip of the Baja California peninsula records the early tectonic evolution of the west side of the Gulf of California. This study focused on the east central margin of the basin. The basal La Calera Formation unconformably overlies Cretaceous granite and consists of conglomerate, pebbly sandstone and conglomerate, and sandstone deposited in alluvial fans and fan-deltas. Deposition of the La Calera Formation was from ca. 9-14 Ma. The lower member of the Trinidad Formation was deposited beginning ca. 9-13 Ma and consists of sandstone, mudstone, and shelly mudstone deposited in nearshore and estuarine environments. These age estimates are based on sedimentation rates and foraminifera and coccoliths from the NN 11A nannozone (7.4 8.6 Ma, GTS 2004). The middle member of the Trinidad Formation consists of deeper water mudstones deposited by turbidity currents and suspension settling in a shelf to slope and conglomerates deposited by submarine debris flows on the shelf. The basin began earlier than previously thought. The oldest marine rocks are ca.9-13 Ma, while sedimentation on the east side began at ca. 9-14 Ma, synchronous with estimates of initiation of offset on the San Jose del Cabo fault. The Zapote fault is a down-to-the-east normal and sinistral-oblique fault that exposes a wedge of granite and older strata in the footwall to the west. The fault was active during sedimentation in the late Miocene and possibly later. The fault divides the study area into an eastern hanging wall subbasin and western footwall subbasin. The eastern subbasin formed an embayment in the eastern margin of the Cabo basin. A regional flooding surface (ca. 8 Ma) can be correlated across the fault that marks a major marine incursion. Depositional systems evolved rapidly from coarse-grained terrestrial systems to fine-grained marine and estuarine systems. The Cabo basin provides an excellent analogue for comparison with offshore basins, which are

The Jurassic of Denmark and Greenland: Sedimentology and sequence stratigraphy of the Bryne and Lulu Formations, Middle Jurassic, northern Danish Central Graben

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Andsbjerg, Jan

2003-10-01

Full Text Available The Middle Jurassic Bryne and Lulu Formations of the Søgne Basin (northern part of the Danish Central Graben consist of fluvially-dominated coastal plain deposits, overlain by interfingering shoreface and back-barrier deposits. Laterally continuous, mainly fining-upwards fluvial channel sandstones that locally show evidence for tidal influence dominate the alluvial/coastal plain deposits of the lower Bryne Formation. The sandstones are separated by units of fine-grained floodplain sediments that show a fining-upwards - coarsening-upwards pattern and locally grade into lacustrine mudstones. A regional unconformity that separates the lower Bryne Formation from the mainly estuarine upper Bryne Formation is defined by the strongly erosional base of a succession of stacked channel sandstones, interpreted as the fill of a system of incised valleys. Most of the stacked channel sandstones show abundant mud laminae and flasers, and rare herringbone structures, suggesting that they were deposited in a tidal environment, probably an estuary. Several tens of metres of the lower Bryne Formation may have been removed by erosion at this unconformity. The estuarine channel sandstone succession is capped by coal beds that attain a thickness of several metres in the western part of the Søgne Basin, but are thin and poorly developed in the central part of the basin. Above the coal beds, the Lulu Formation is dominated by various types of tidally influenced paralic deposits in the western part of the basin and by coarsening-upwards shoreface and beach deposits in central parts. Westwards-thickening wedges of paralic deposits interfinger with eastwards-thickening wedges of shallow marine deposits. The Middle Jurassic succession is subdivided into nine sequences. In the lower Bryne Formation, sequence boundaries are situated at the base of laterally continuous fluvial channel sandstones whereas maximum flooding surfaces are placed in laterally extensive floodplain

Lithofacies, age, depositional setting, and geochemistry of the Otuk Formation in the Red Dog District, northwestern Alaska

Science.gov (United States)

Dumoulin, Julie A.; Burruss, Robert A.; Blome, Charles D.

2013-01-01

Complete penetration of the Otuk Formation in a continuous drill core (diamond-drill hole, DDH 927) from the Red Dog District illuminates the facies, age, depositional environment, source rock potential, and isotope stratigraphy of this unit in northwestern Alaska. The section, in the Wolverine Creek plate of the Endicott Mountains Allochthon (EMA), is ~82 meters (m) thick and appears structurally uncomplicated. Bedding dips are generally low and thicknesses recorded are close to true thicknesses. Preliminary synthesis of sedimentologic, paleontologic, and isotopic data suggests that the Otuk succession in DDH 927 is a largely complete, albeit condensed, marine Triassic section in conformable contact with marine Permian and Jurassic strata. The Otuk Formation in DDH 927 gradationally overlies gray siliceous mudstone of the Siksikpuk Formation (Permian, based on regional correlations) and underlies black organic-rich mudstone of the Kingak(?) Shale (Jurassic?, based on regional correlations). The informal shale, chert, and limestone members of the Otuk are recognized in DDH 927, but the Jurassic Blankenship Member is absent. The lower (shale) member consists of 28 m of black to light gray, silty shale with as much as 6.9 weight percent total organic carbon (TOC). Thin limy layers near the base of this member contain bivalve fragments (Claraia sp.?) consistent with an Early Triassic (Griesbachian-early Smithian) age. Gray radiolarian chert dominates the middle member (25 m thick) and yields radiolarians of Middle Triassic (Anisian and Ladinian) and Late Triassic (Carnian-late middle Norian) ages. Black to light gray silty shale, like that in the lower member, forms interbeds that range from a few millimeters to 7 centimeters in thickness through much of the middle member. A distinctive, 2.4-m-thick interval of black shale and calcareous radiolarite ~17 m above the base of the member has as much as 9.8 weight percent TOC, and a 1.9-m-thick interval of limy to cherty

Synthesis of Nd-doped ZSM-5 and its application to treating slightly polluted water

Directory of Open Access Journals (Sweden)

Mang Lu

2018-03-01

Full Text Available In this study, ZSM-5 zeolite was synthesized using diatomaceous mud as the raw material, and then doped with different amounts of Nd2O3. The orthogonal experiments were performed to investigate the influence of Nd:Si molar ratio, zeolite dosage, contact time, solution pH and temperature on the removal of humic acid (HA. The removal of HA was comprehensively evaluated by chemical oxygen demand (COD, UV254 and UV410 of the solution. The results demonstrate that solution pH and zeolite dosage are the two most important factors influencing HA adsorption. The optimum experimental conditions were determined to be: 35 °C, Nd:Si molar ratio of 1:100, 2.0 g/L zeolite, pH 4 and 50 min contact time. Under these conditions, the removal efficiencies of UV254, UV410 and COD are 82.70%, 76.00% and 82.10%, respectively, corresponding to a comprehensive removal of 81.02%.

Decontamination and decommissioning of TAN radioactive liquid-waste-evaporator system (PM-2A). Final report

International Nuclear Information System (INIS)

Smith, D.L.

1983-03-01

This report describes the decontamination and decommissioning of the Test Area North (TAN) liquid waste evaporator (PM-2A). The PM-2A facility included the aboveground evaporator system, two underground holding tanks and feedlines, an electrical distribution subsystem, and one above ground concrete tank. Much surface soil of the PM-2A area was also radioactively contaminated. Stabilization of the liquid and sludge in the holding tanks, a major task, was achieved by pumping most of the liquid into 55-gal drums and mixing it with cement. The drums were buried in the Radioactive Waste Management Complex (RWMC). The remaining liquid and sludge were dried in place by layers of diatomaceous earth. The most contaminated surface soil was removed, and the area backfilled with clean topsoil and graded, reducing the surface radiation field to background. A 6-ft-high chain link fence now surrounds the area. Most of the area was seeded to crested wheatgrass. 46 figures, 9 tables

Kieselgur - mining, processing and use

Energy Technology Data Exchange (ETDEWEB)

Paschen, S.

1986-04-01

Kieselgur, also known as diatomite or diatomaceous earth is a soft rocklike material consisting of skeletal remains of microscopic unicellular algea of the diatom family. Smaller or larger deposits are known all over the world, of fresh-water or marine origin, fomed in the tertiary or quaternary period of earth's history. - Kieselgur is a predominantly amorphous opaline silica (silicon dioxide). The crude ore contains impurities such as organic matter, clay, sand and metal salts. - Following processing in shelf furnaces or rotary tube furnaces, milling and air separation the Kieselgur is obtained as a fine powder of brown, punk or white color. The finished product mainly consists of silica and varying amounts of water-insoluble oxides of iron, calcium, aluminium and traces of other oxides. - Kieselgur is chemically inert, highly porous and has a large surface area. It is suited for applications in filtration as filter aid for alluvial filters, and also as special filler and carrier in various branches in industry.

The hydroxyl species and acid sites on diatomite surface: a combined IR and Raman study

Science.gov (United States)

Yuan, P.; Wu, D. Q.; He, H. P.; Lin, Z. Y.

2004-04-01

Diffuse reflectance infrared Fourier transform spectroscopy (DRIFT), Raman spectroscopy of adsorbed pyridine molecules (Py-Raman) and in situ Py-IR have been used to investigate the hydroxyl species and acid sites on diatomite surfaces. The Lewis (L) and Brønsted (B) acid sites, and various hydroxyl species, including isolated hydroxyl groups, H-bonded hydroxyl groups and physically adsorbed water, are identified. The L acid sites in diatomite samples are resulted from the clay impurities, and the B acid sites are resulted from some moderate strength H-bonded hydroxyl groups. At room temperature, both of the isolated and H-bonded silanols associate with the physically adsorbed water by hydrogen bond. After calcination treatment, physically adsorbed water will be desorbed from the silanols, and the silanols will condense with the increase of temperature. Generally, the H-bonded silanols condense more easily than the isolated ones. The properties of surface hydroxyl species of diatomaceous silica are more similar to precipitated silica rather than fumed silica.

APPLICATION OF DIATOMS TO ASSESS THE QUALITY OF THE WATERS OF THE BARYCZKA STREAM, LEFT-SIDE TRIBUTARY OF THE RIVER SAN

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Teresa Noga

2013-07-01

Full Text Available The Baryczka stream is a small (about 20 km long, left bank tributary of the River San (Podkarpackie Voivodeship. Studies on diversity of diatom communities using OMNIDIA software were conducted in 2010 and 2011. Diatomaceous indices IPS, GDI and TDI and Van Dam et al. classification system were used for water quality assessment. Planothidium lanceolatum, Cocconeis placentula var. lineata, Achnanthidium minutissimum var. minutissimum, Nitzschia linearis, Rhoicosphenia abbreviata, Navicula lanceolata and Naicula gregaria were the most numerous. Values of the IPS index indicate good water quality (II–III class. Based on the GDI index, waters of the Baryczka stream were classified to III class water quality. The TDI index indicated poor and bad ecological state on the most sampling sites. On all sampling sites alaliphilous (pH>7 diatoms taxa predominated. The most common were eutraphentic and hypereutraphentic diatoms. With respect to trophy, it was shown that α- and β-mesosaprobous diatoms were the most common (III and II class water quality.

Caldera formation and varied eruption styles on North Pacific seamounts: the clastic lithofacies record

Science.gov (United States)

Portner, Ryan A.; Clague, Dave A.; Paduan, Jennifer B.

2014-08-01

Detailed examination of volcaniclastic and sedimentary rocks collected from the Taney (30 Ma), President Jackson (4 Ma), Vance (3 Ma) and Alarcon (2 Ma) near-ridge seamount chains of the North Pacific reveals seven clastic lithofacies that record various modes of eruption, magma fragmentation, and particle dispersal. Lithofacies are distinguished by differences in lithology, bedding habit, compositional heterogeneity, and relationship to volcanic landforms. Breccia lithofacies were produced through mechanical fragmentation during caldera collapse (polymict) or effusive eruptions onto steep slopes (monomict). Rare globular lapilli mudstone lithofacies contain clasts with morphologies formed by magma-sediment mingling processes (peperite). Seamount summit pyroclastic deposits include proximal lapilli tuff with vesicular pyroclasts, and more distal limu o Pele tuff lithofacies. Much finer-grained hydrothermal mudstone/tuff lithofacies occurs around caldera rims and contains greenschist minerals, hydrothermal clays and basaltic ash that record subsurface phreatomagmatic fragmentation processes. Very fine-grained ash is transported to distal regions by oceanic currents and hydrothermal plumes, and is a component of the regional pelagic sediment budget. Pyroclastic lithofacies only occur on seamount summits suggesting formation during the latter stages of seamount evolution. As a seamount drifts away from an adjacent ridge axis and associated heat source, its magma supply is reduced allowing for magmatic gas buildup and mild explosive eruptions. During this stage, the diminished melt supply under the seamount is unable to fully compensate for extension along the ridge axis and vertical seamount growth. Lateral intrusion into spreading-related structures in this stage causes magma withdrawal and caldera formation. Formation of caldera ring faults also promotes seawater ingress into subseafloor hydrothermal cells, which interact with magma conduits causing phreatomagmatic

Structural control and correlation of uranium distribution and mineralogy of meta-pelites in Ogcheon terrain, Korea

International Nuclear Information System (INIS)

Park, B.S.; So, C.S.

1980-01-01

The rock units of Goesan area in the Ogcheon metamorphic terrain established on the basis of field criteria should be redefined into following sequence. Based on shear senses in secondary small structures which are usually observable in the investigated area, the stratigraphy can be lithologically divided into the lower pelite, pebbly mudstone, upper pelite, quartzite and psammite unit in ascending order. This conclusion is in discordance with a previous opinion; Munjuri formation and Guryongsan formation may be equivalent to upper pelite unit, Iwonri formation and Hwanggangri formation to pebbly mudstone. From this, it may be inferred that isoclinal overtuned folds repeatedly occur in the area. The uranium bearing coaly thin layers in upper pelite unit have relatively broad exposures in Deogpyeongri block of Goesan area along culmination zone in the central part of the investigated area. It is believed that structural feature in the block recognized complexly refolded synform plunging to southwest. Mineralogical and radiometric studies were made on 135 representative samples from the Ogcheon Group of Korea. The mineralogy of all black slate samples is qualitatively similar but quantitatively different. The uranium distribution in the studied area show approximately log normal. Uranium in the black slates of the Ogcheon Group was deposited together under same physico-chemical environmental conditions. The chemical and geological factors that controlled the abundance of organic carbon and iron oxides also controlled the uranium content. The relationship of the major components to uranium can be expressed by the following regression equation: Log(Ux10 4 +1)=1.70999-0.00367(quartz)-0.00512(micas)-0.00930(other silicates)+0.01911(iron oxides)-0.03389(other opaques)+0.02062(organic carbon). (author)

Geology of the Golden Gate Highlands National Park

Directory of Open Access Journals (Sweden)

G.H. Groenewald

1986-11-01

Full Text Available The Golden Gate Highlands National Park is underlain by stratigraphic units belonging to the upper part of the Karoo Sequence. These units include part of the Beaufort Group and the Molteno, Elliot, Clarens and Drakensberg Formations. Dolerite dykes and sills are intruded into the succession while recent alluvium and scree cover the valley floors and mountain slopes. The Beaufort Group is represented by red mudstone and light brown fine-grained feldspathic sandstone of the Tarkastad Subgroup. The Molteno Formation consists of medium- to coarse-grained trough cross-bedded sandstone, while the Elliot Formation comprises a thick succession of red mudstone, siltstone and interlayered fine- to medium-grained, light yellow-brown sandstone. The most characteristic feature of the park is the yellowish sandstone cliffs of the Clarens Formation. Cave formation is caused by exudation, differential weathering due to different degrees of carbonate cementation and undercutting of the sandstone. The highest peaks are capped by numerous layers of amygdaloidal and massive varieties of basaltic lava of the Drakensberg Formation. A possible volcanic pipe occurs in the eastern part of the park. The Elliot and Clarens Formations are rich in vertebrate fossil remains, especially Massospondylus sp. Remains of Notochampsa sp., Pachygenelus monus, Clarencea gracilis, Lanasaurus scalpridens and a cluster of unidentified dinosaur eggs have also been found. The formations underlying the Golden Gate Highlands National Park were formed during the Late Triassic Epoch and the Jurassic Period (roughly 150 to 230 million years ago. The strata in the park show very little structural deformation and the only obvious structures are faults which are intruded by dolerite.

Incipiently drowned platform deposit in cyclic Ordovician shelf sequence: Lower Ordovician Chepultepec Formation, Virginia

Energy Technology Data Exchange (ETDEWEB)

Bova, J.A.; Read, J.F.

1983-03-01

The Chepultepec interval, 145 to 260 m (476 to 853 ft) thick, in Virginia contains the Lower Member up to 150 m (492 ft) thick, and the Upper Member, up to 85 m (279 ft) thick, of peritidal cyclic limestone and dolomite, and a Middle Member, up to 110 m (360 ft) thick, of subtidal limestone and bioherms, passing northwestward into cyclic facies. Calculated long term subsidence rates were 4 to 5 cm/1000 yr (mature passive margin rates), shelf gradients were 6 cm/km, and average duration of cycles was 140,00 years. Peritidal cyclic sequences are upward shallowing sequences of pellet-skeletal limestone, thrombolites, rippled calcisiltites and intraclast grainstone, and laminite caps. They formed by rapid transgression with apparent submergence increments averaging approximately 2 m (6.5 ft) in Lower Member and 3.5 m (11.4 ft), Upper Member. Deposition during Middle Member time was dominated by skeletal limestone-mudstone, calcisiltite with storm generated fining-upward sequences, and burrow-mixed units that were formed near fair-weather wave base, along with thrombolite bioherms. Locally, there are upward shallowing sequences, of basal wackestone/mudstone to calcisiltite to bioherm complexes (locally with erosional scalloped tops). Following each submergence, carbonate sedimentation was able to build to sea level prior to renewed submergence. Large submergence events caused tidal flats to be shifted far to the west, and they were unable to prograde out onto the open shelf because of insufficient time before subsidence was renewed, and because the open shelf setting inhibited tidal flat deposition. The Middle Member represents an incipiently drowned sequence that developed by repeated submergence events.

National Uranium Resource Evaluation: Moab Quadrangle, Colorado and Utah

International Nuclear Information System (INIS)

Campbell, J.A.; Franczyk, K.J.; Lupe, R.D.; Peterson, F.

1982-09-01

Portions of the Salt Wash Member of the Morrison, the Chinle, the Rico, the Cutler, and the Entrada Formations are favorable for uranium deposits that meet the minimum size and grade requirements of the US Department of Energy within the Moab 1' x 2' Quadrangle, Utah and Colorado. Nine areas are judged favorable for the Late Jurassic Salt Wash Member. The criteria used to evaluate these areas as favorable include the presence of (1) fluvial sandstone beds deposited by low-energy streams; (2) actively moving major and minor structures such as the Paradox basin and the many folds within it; (3) paleostream transport directions approximately perpendicular to the trend of many of the paleofolds; (4) presence of favorable gray lacustrine mudstone beds; and (5) known uranium occurrences associated with the favorable gray mudstones. Three favorable areas have been outlined for the Late Triassic Chinle Formation. The criteria used to evaluate these areas are the sandstone-to-shale ratios for the Chinle Formation and the distribution of the Petrified Forest Member of the Chinle, which is considered the source for the uranium. Two favorable areas have been delineated for the Permian Cutler Formation, and one for the Permian Rico Formation. The criteria used to outline favorable areas are the distribution of favorable facies within each formation. Favorable facies are those that are a result of deposition in environments that are transitional between fluvial and marine. One favorable area is outlined in the Jurassic Entrada Sandstone in the southeastern corner of the quadrangle in the Placerville district. Boundaries for this area were established by geologic mapping

Paleocene-middle Miocene flexural-margin migration of the non marine llanos Foreland basin of Colombia

International Nuclear Information System (INIS)

Bayona, German; Jaramillo, Carlos; Rueda, Milton; Reyes Harker, Andres; Torres, Vladimir

2007-01-01

A foreland basin is a dynamic system whose depositional systems migrate in response to changes in tectonic uplift patterns, sedimentary filling processes and isostatic rebound of the lithosphere. The Paleocene-middle Miocene foreland system of the llanos foothills and llanos basin of Colombia includes regional unconformities, abrupt changes in lithology/stacking patterns and flooding surfaces bounding reservoir and seal units. Here we integrate a systematic biostratigraphic study, strata architecture and tectonic subsidence analyses, regional seismic profiles, and provenance data to define the diachronism of such surfaces and to document the direction of migration of foreland depozones. Line a flexural-deformed basin, sandstone composition, rates of accommodation and sediment supply vary across and along the basin. we show how a coeval depositional profile in the llanos foothills-llanos foreland basin consists of lithoranites inter b edded with mudstones (seal rock, supplied from the orogenic front to the west) that correlate craton ward with organic-rich mudstones and coal (source rock), and to amalgamated fluvial-estuarine quartzarenites (reservoir rock, supplied from the craton to the east) adjacent to a sub-aerial fore-bulge (unconformity). This system migrated northward and eastward during the Paleocene, westward during the early-middle Eocene, and eastward during the Oligocene. In the lower-middle Miocene succession of the llanos basin, identification of flooding events indicates a westward encroaching of a shallow-water lacustrine system that covered an eastward-directed fluvial-deltaic system. A similar process has been documented in other basins in Venezuela and Bolivia, indicating the regional extent of such flooding event may be related to the onset of Andean-scale mountain-building processes

Métallogénie du gîte à PB-ZN-AG de Nicholas-Denys, Nouveau-Brunswick

OpenAIRE

Deakin, Michelle Kyle

2011-01-01

Le gîte à Pb–Zn–Ag de Nicholas-Denys, dans le camp minier de Bathurst (Nouveau-Brunswick), est constitué de plusieurs lentilles à pyrrhotite–sphalérite–galène, encaissées par le mudstone de la Formation de Millstream du Groupe de Fournier, déposé dans un bassin d’arrière-arc ordovicien. Les lentilles de sulfures sont concordantes avec la foliation régional S1, et sont boudinées parallèlement à la faille de Rocky-Brook Millstream, indiquant que les sulfures prédatent la déformation décrochante...

The geology of Burnsville Cove, Bath and Highland Counties, Virginia

Science.gov (United States)

Swezey, Christopher; Haynes, John T.; Lambert, Richard A.; White, William B.; Lucas, Philip C.; Garrity, Christopher P.

2015-01-01

Burnsville Cove is a karst region in Bath and Highland Counties of Virginia. A new geologic map of the area reveals various units of limestone, sandstone, and siliciclastic mudstone (shale) of Silurian through Devonian age, as well as structural features such as northeast-trending anticlines and synclines, minor thrust faults, and prominent joints. Quaternary features include erosional (strath) terraces and accumulations of mud, sand, and gravel. The caves of Burnsville Cove are located within predominantly carbonate strata above the Silurian Williamsport Sandstone and below the Devonian Oriskany Sandstone. Most of the caves are located within the Silurian Tonoloway Limestone, rather than the Silurian-Devonian Keyser Limestone as reported previously.

Evolved Gas Analyses of the Murray Formation in Gale Crater, Mars: Results of the Curiosity Rover's Sample Analysis at Mars (SAM) Instrument

Science.gov (United States)

Sutter, B.; McAdam, A. C.; Rampe, E. B.; Thompson, L. M.; Ming, D. W.; Mahaffy, P. R.; Navarro-Gonzalez, R.; Stern, J. C.; Eigenbrode, J. L.; Archer, P. D.

2017-01-01

The Sample Analysis at Mars (SAM) instrument aboard the Mars Science Laboratory rover has analyzed 13 samples from Gale Crater. All SAM-evolved gas analyses have yielded a multitude of volatiles (e.g., H2O, SO2, H2S, CO2, CO, NO, O2, HCl) [1- 6]. The objectives of this work are to 1) Characterize recent evolved SO2, CO2, O2, and NO gas traces of the Murray formation mudstone, 2) Constrain sediment mineralogy/composition based on SAM evolved gas analysis (SAM-EGA), and 3) Discuss the implications of these results relative to understanding the geological history of Gale Crater.

Brushy Basin drilling project, Cedar Mountain, Emergy County, Utah

International Nuclear Information System (INIS)

Kiloh, K.D.; McNeil, M.; Vizcaino, H.

1980-03-01

A 12-hole drilling program was conducted on the northwestern flank of the San Rafael swell of eastern Utah to obtain subsurface geologic data to evaluate the uranium resource potential of the Brushy Basin Member of the Morrison Formation (Jurassic). In the Cedar Mountain-Castle Valley area, the Brushy Basin Member consists primarily of tuffaceous and carbonaceous mudstones. Known uranium mineralization is thin, spotty, very low grade, and occurs in small lenticular pods. Four of the 12 drill holes penetrated thin intervals of intermediate-grade uranium mineralization in the Brushy Basin. The study confirmed that the unit does not contain significant deposits of intermediate-grade uranium

Humic acid provenance influence to the adsorption capacity in uranium and thorium removal

Science.gov (United States)

Prasetyo, E.

2018-01-01

It is common knowledge that humic acid is organic compound without certain chemical composition since it is derived from different organic materials. Further this raises question whether the different humic acid sample used could lead to different adsorbent properties e.g. adsorption capacity. To address the problem, this paper is aimed to clarify the relation between the provenances of humic acid and synthesized adsorbent properties especially adsorption capacities by quantitative and qualitative functional groups determination including discussion on their effect to the metal ion adsorption mechanism using three humic acid samples. Two commercial samples were derived from recent compost while the other extracted from tertiary carbonaceous mudstone strata.

Clay club catalogue of characteristics of argillaceous rocks

International Nuclear Information System (INIS)

2005-01-01

The OECD/NEA Working Group on the Characterisation, the Understanding and the Performance of Argillaceous Rocks as Repository Host Formations, namely the Clay Club, examines the various argillaceous rocks that are being considered for the deep geological disposal of radioactive waste, i.e. from plastic, soft, poorly indurated clays to brittle, hard mud-stones or shales. The Clay Club considered it necessary and timely to provide a catalogue to gather in a structured way the key geo-scientific characteristics of the various argillaceous formations that are - or were - studied in NEA member countries with regard to radioactive waste disposal. The present catalogue represents the outcomes of this Clay Club initiative. (author)

Soft-sediment deformation structures from an ice-marginal storm-tide interactive system, Permo-Carboniferous Talchir Formation, Talchir Coalbasin, India

Science.gov (United States)

Bhattacharya, H. N.; Bhattacharya, Biplab

2010-01-01

Permo-Carboniferous Talchir Formation, Talchir Coalbasin, India, records sedimentation during a phase of climatic amelioration in an ice-marginal storm-affected shelf. Evidences of subtidal processes are preserved only under thick mud drapes deposited during waning storm phases. Various soft-sediment deformation structures in some sandstone/siltstone-mudstone interbeds, like syn-sedimentary faults, deformed laminations, sand-silt flows, convolute laminations and various flame structures, suggest liquefaction and fluidization of the beds due to passage of syn-depositional seismic shocks. In the Late Paleozoic ice-marginal shelf, such earthquake tremors could be generated by crustal movements in response to glacioisostatic adjustments of the basin floor.

The volcanic-sedimentary sequence of the Lousal deposit, Iberian Pyrite Belt (Portugal)

Science.gov (United States)

Rosa, Carlos; Rosa, Diogo; Matos, Joao; Relvas, Jorge

2010-05-01

The Iberian Pyrite Belt (IPB) is a massive sulfide province that is located in the south of Portugal and Spain, and hosts more than 90 massive sulfide deposits that amount to more than 1850 million metric tonnes of sulfide ore (Tornos, 2006). The ore deposits size, vary from ~1Mt to >100Mt (e.g. Neves Corvo and Aljustrel in Portugal, and Rio Tinto and Tharsis in Spain). The ore deposits are hosted by a submarine sedimentary and volcanic, felsic dominated, succession that constitutes the Upper Devonian to Lower Carboniferous Volcanic and Sedimentary Complex (VSC). The VSC ranges in thickness from approximately 600 to 1300 m (Tornos 2006). The VSC overlies the Phyllite-Quartzite Group (PQ) (Upper Devonian, base unknown) and is overlain by the Baixo Alentejo Flysch Group (Lower to Upper Carboniferous). The Lousal massive sulfide deposit is located in the western part of the IPB and occurs mostly interbedded with black mudstone. The VSC sequence at Lousal mine consists of a mudstone and quartzite sequence (PQ Group) in the lower part of the succession, over which a thick sequence of rhyolitic lavas (>300 m) occurs. Above the rhyolitic lavas there is a thick sequence of black and grey mudstone that hosts the massive sulfide ore bodies, and a rhyolitic sill. The upper part of the VSC sequence consists of a thick mudstone interval that hosts two thick basaltic units, locally with pillows. The rhyolites have small coherent cores, locally with flow bands, that grade to surrounding massive clastic intervals, with large lateral extent. The clasts show jigsaw-fit arrangement in many places and have planar or curviplanar margins and locally are perlitic at the margin. The top contact of these units is in most locations not exposed, which makes difficult to interpret the mode of emplacement. However, the thick clastic intervals, above described, are in accordance with quenching of volcanic glass with abundant water and therefore indicate that quenching of the rhyolites was the

The Deuterium to Hydrogen Ratio in the Water that Formed the Yellowknife Bay Mudstones in Gale Crater

Science.gov (United States)

Mahaffy, Paul R.; Brunner, Anna E.; Webster, Chris R.; Atreya, Sushil K.; Mcadam, Amy Catherine; Stern, Jennifer Claire; Leshin, Laurie Ann; Navarro-Gonzales, Rafael; Jones, J.; Kashyap, Srishti

2014-01-01

A suite of isotope ratios of light elements in the present martian atmosphere (13C/12C, 15N/14N, 18O/16O, 38Ar/36Ar, and D/H) are all substantially enriched in the heavy element suggesting atmospheric loss to space over the past billions of years with preferential loss of the lighter isotope from each pair. In situ measurements from MSL's Sample Analysis at Mars (SAM) instrument [e.g. 1,2,3] have considerably refined previous measurements from the Viking mass spectrometers [e.g. 4], from remote spectroscopic observations [e.g. 5,6], and from martian meteorite studies [e.g. 7,8]. The persistence of habitable environments such as the ancient Yellowknife Bay lake recently revealed by measurements from the Curiosity rover [9] depends on the surface temperatures and the duration of an atmosphere thicker than that at present. Current and planned measurements from orbit with the Mars Express and MAVEN missions respectively intend to study the processes of atmospheric escape including solar wind interaction, sputtering, thermal escape, and dissociative recombination, and determine or refine the current rate of atmospheric loss caused by these and other mechanisms. The goal of these programs is to understand the physical processes sufficiently well so that robust extrapolations over the past billions of years can be made D/H is measured by both the Tunable Laser Spectrometer (TLS) and the Quadrupole Mass Spectrometer (QMS) of the SAM suite. to predict the atmospheric and surface conditions on early Mars. However, the study of the history of martian atmospheric evolution will be greatly facilitated if we are able to also directly measure the isotopic composition of volatiles captured in rocks that are representative of the ancient atmosphere. To date, D/H is one of the most promising candidates for this study since water is the most abundant volatile thermally released from the Yellowknife Bay phylosilicates discovered by the SAM and CheMin experiments of MSL and its

The thermal and chemical evolution of hydrothermal vent fluids in shale hosted massive sulphide (SHMS) systems from the MacMillan Pass district (Yukon, Canada)

Science.gov (United States)

Magnall, J. M.; Gleeson, S. A.; Blamey, N. J. F.; Paradis, S.; Luo, Y.

2016-11-01

At Macmillan Pass (YT, Canada), the hydrothermal vent complexes beneath two shale-hosted massive sulphide (SHMS) deposits (Tom, Jason) are well preserved within Late Devonian strata. These deposits provide a unique opportunity to constrain key geochemical parameters (temperature, salinity, pH, fO2, ΣS) that are critical for metal transport and deposition in SHMS systems, and to evaluate the interaction between hydrothermal fluids and the mudstone host rock. This has been achieved using a combination of detailed petrography, isotopic techniques (δ34S, δ13C and δ18O values), carbonate rare earth element analysis (LA-ICP-MS), fluid inclusion analysis (microthermometry, gas analysis via incremental crush fast scan mass spectrometry), and thermodynamic modelling. Two main paragenetic stages are preserved in both vent complexes: Stage 1 comprises pervasive ankerite alteration of the organic-rich mudstone host rock and crosscutting stockwork ankerite veining (±pyrobitumen, pyrite and quartz) and; Stage 2 consists of main stage massive sulphide (galena-pyrrhotite-pyrite ± chalcopyrite-sphalerite) and siderite (±quartz and barytocalcite) mineralisation. Co-variation of δ18O and δ13C values in ankerite can be described by temperature dependent fractionation and fluid rock interaction. Together with fluid inclusion microthermometry, this provides evidence of a steep thermal gradient (from 300 to ∼100 °C) over approximately 15 m stratigraphic depth, temporally and spatially constrained within the paragenesis of both vent complexes and developed under shallow lithostatic (28), characteristic of diagenetic fluids, are coupled with positive europium anomalies and variable light REE depletion, which are more consistent with chloride complexation in hot (>250 °C) hydrothermal fluids. In this shallow sub-seafloor setting, thermal alteration of organic carbon in the immature, chemically reactive mudstones also had an important role in the evolution of fluid chemistry

Revised stratigraphy and reinterpretation of the Miocene Pohang basinfill, SE Korea: sequence development in response to tectonism and eustasy in a back-arc basin margin

Science.gov (United States)

Sohn, Y. K.; Rhee, C. W.; Shon, H.

2001-09-01

The Miocene Pohang Basin is a pull-apart basin formed along the eastern continental margin of Korea (ECMK) during the back-arc opening of the East Sea (Sea of Japan). The basin is filled by more than 1 km thick, nonmarine to deep-marine strata. These strata show extreme vertical and lateral lithofacies changes and have caused decades-long controversies on their nature and stratigraphy. Previous sedimentological studies suggest that the basinfill was deposited by a series of contemporaneously developed depositional systems, including fan delta, prodelta, slope apron, and basin plain. Detailed mapping and magnetotelluric surveying show, however, that the basinfill is composed of several packages of strata (sequences) that are bounded by distinct and laterally persistent stratigraphic discontinuities (sequence boundaries). This suggests that the depositional systems in the Pohang Basin developed sequentially rather than contemporaneously. Six packages of strata are identified in the basin: a nonmarine to shallow marine (transgressive) sequence (Sequence 1), a Gilbert-type-delta conglomerate (Sequence 2), and alternations of submarine conglomerates and hemipelagic mudstones (Sequences 3-6). The conglomerates and hemipelagic mudstones of the latter four sequences are interpreted to represent lowstand depositional systems (slope apron, submarine fan, and high-gradient delta) and condensed intervals, respectively. Compilation of geochronologic, paleomagnetic, and biostratigraphic data suggests that Sequence 1 formed during the gradual subsidence of the ECMK prior to 17 Ma, whereas Sequence 2 formed in response to abrupt downfaulting of the Pohang Basin at about 17 Ma. Both sequences are interpreted to have developed in response to the early Miocene back-arc-opening tectonism of the East Sea. On the other hand, Sequences 3-6 formed between 17 and about 10.5 Ma. The Pohang Basin was subject to only minor tectonism during this period and could record global sea

Bioerosion by pit-forming, temperate-reef sea urchins: History, rates and broader implications.

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Michael P Russell

Full Text Available Sea urchins are dominant members of rocky temperate reefs around the world. They often occur in cavities within the rock, and fit so tightly, it is natural to assume they sculpted these "pits." However, there are no experimental data demonstrating they bore pits. If they do, what are the rates and consequences of bioerosion to nearshore systems? We sampled purple sea urchins, Strongylocentrotus purpuratus, from sites with four rock types, three sedimentary (two sandstones and one mudstone and one metamorphic (granite. A year-long experiment showed urchins excavated depressions on sedimentary rocks in just months. The rate of pit formation varied with rock type and ranged from 100 yr for granite. In the field, there were differences in pit size and shapes of the urchins (height:diameter ratio. The pits were shallow and urchins flatter at the granite site, and the pits were deeper and urchins taller at the sedimentary sites. Although overall pit sizes were larger on mudstone than on sandstone, urchin size accounted for this difference. A second, short-term experiment, showed the primary mechanism for bioerosion was ingestion of the substratum. This experiment eliminated potential confounding factors of the year-long experiment and yielded higher bioerosion rates. Given the high densities of urchins, large amounts of rock can be converted to sediment over short time periods. Urchins on sandstone can excavate as much as 11.4 kg m-2 yr-1. On a broader geographic scale, sediment production can exceed 100 t ha-1 yr-1, and across their range, their combined bioerosion is comparable to the sediment load of many rivers. The phase shift between urchin barrens and kelp bed habitats in the North Pacific is controlled by the trophic cascade of sea otters. By limiting urchin populations, these apex predators also may indirectly control a substantial component of coastal rates of bioerosion.

Overburden characterization and post-burn study of the Hanna IV, underground coal gasification site, Wyoming, and comparison to other Wyoming UCG sites

Energy Technology Data Exchange (ETDEWEB)

Marcouiller, B.A.; Burns, L.K.; Ethridge, F.G.

1984-11-01

Analysis of 21 post-burn cores taken from the Hanna IV UCG site allows 96 m (315 ft) of overburden to be subdivided into four local stratigraphic units. The 7.6 m (25 ft) thick Hanna No. 1 coal seam is overlain by a laterally discontinuous, 3.3 m (11 ft) thick shaley mudstone (Unit A') in part of the Hanna IV site. A more widespread, 30 m (90 ft) thick well-indurated sandstone (Unit A) overlies the A' unit. Unit A is the roof rock for both of the Hanna IV cavities. Overlying Unit A is a 33 m (108 ft) thick sequence of mudstone and claystone (Unit B), and the uppermost unit at the Hanna IV site (Unit C) is a coarse-grained sandstone that ranges in thickness from 40 to 67 m (131 to 220 ft). Two elliptical cavities were formed during the two phases of the Hanna IV experiment. The larger cavity, Hanna IVa, is 45 x 15 m in plan and has a maximum height of 18 m (59 ft) from the base of the coal seam to the top of the cavity; the Hanna IVb cavity is 40 x 15 m in plan and has a maximum height of 11 m (36 ft) from the base of the coal seam to the top of the cavity. Geotechnical tests indicated that the Hanna IV overburden rocks were moderately strong to strong, based on the empirical classification of Broch and Franklin (1972), and a positive, linear correlation exists between rock strength and volume percent calcite cement. There is an inverse linear correlation between rock strength and porosity for the Hanna IV overburden rocks. 28 refs., 34 figs., 13 tabs..

Relationship between Mineral and Organic Matter in Shales: The Case of Shahejie Formation, Dongying Sag, China

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Xiang Zeng

2018-05-01

Full Text Available Types of organic matter and mineral associations and microstructures of shales can reflect the depositional mechanism and sedimentary environment. Therefore, analysis of organic matter and mineral associations is a prerequisite for research on fine-grained sedimentary rocks. Shales from the Eocene Shahejie Formation in the Dongying Sag of China were selected to classify their lithofacies and to investigate the characteristics of their organic matter and mineral associations. This analysis identified six lithofacies (e.g., laminated shales and massive mudstones; in all the lithofacies, clay minerals exhibit a positive correlation with detrital minerals, thus indicating that they were derived from the same source. The comprehensive analysis of mineral and organic matter associations reveals that detrital minerals were deposited with low-hydrogen index (HI OM. The deposition of detrital minerals was mainly a physical process. Clay minerals can undergo deposition in one of two ways due to their surface charge: they can either aggregate with high-HI OM via chemical deposition, thus forming organic-rich laminae, or they can be deposited together with low-HI OM via physical deposition, thus forming clay-rich laminae or a massive matrix. Carbonate minerals, which often coexist with high-HI OM, are biological sediments. The analysis of the sedimentary characteristics of these organic matter and mineral associations indicates that the sedimentary processes differ between various lithofacies: e.g., the discontinuous laminated shale represents the product of biophysical processes. Differences in depositional mechanisms are also present in each sub-member. Therefore, it is important to analyze the properties of minerals and organic matter, as well as their associations, to more deeply understand the classification of lithofacies and the depositional processes of shales and mudstones.

Cenozoic Methane-Seep Faunas of the Caribbean Region.

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Steffen Kiel

Full Text Available We report new examples of Cenozoic cold-seep communities from Colombia, Cuba, the Dominican Republic, Trinidad, and Venezuela, and attempt to improve the stratigraphic dating of Cenozoic Caribbean seep communities using strontium isotope stratigraphy. Two seep faunas are distinguished in Barbados: the late Eocene mudstone-hosted 'Joes River fauna' consists mainly of large lucinid bivalves and tall abyssochrysoid gastropods, and the early Miocene carbonate-hosted 'Bath Cliffs fauna' containing the vesicomyid Pleurophopsis, the mytilid Bathymodiolus and small gastropods. Two new Oligocene seep communities from the Sinú River basin in Colombia consist of lucinid bivalves including Elongatolucina, thyasirid and solemyid bivalves, and Pleurophopsis. A new early Miocene seep community from Cuba includes Pleurophopsis and the large lucinid Meganodontia. Strontium isotope stratigraphy suggests an Eocene age for the Cuban Elmira asphalt mine seep community, making it the oldest in the Caribbean region. A new basal Pliocene seep fauna from the Dominican Republic is characterized by the large lucinid Anodontia (Pegophysema. In Trinidad we distinguish two types of seep faunas: the mudstone-hosted Godineau River fauna consisting mainly of lucinid bivalves, and the limestone-hosted Freeman's Bay fauna consisting chiefly of Pleurophopsis, Bathymodiolus, and small gastropods; they are all dated as late Miocene. Four new seep communities of Oligocene to Miocene age are reported from Venezuela. They consist mainly of large globular lucinid bivalves including Meganodontia, and moderately sized vesicomyid bivalves. After the late Miocene many large and typical 'Cenozoic' lucinid genera disappeared from the Caribbean seeps and are today known only from the central Indo-Pacific Ocean. We speculate that the increasingly oligotrophic conditions in the Caribbean Sea after the closure of the Isthmus of Panama in the Pliocene may have been unfavorable for such large

BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

Energy Technology Data Exchange (ETDEWEB)

Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

2005-05-10

The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structure and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary

Organic Geochemistry and Rock-Eval Pyrolysis of Eocene fine Sediments, East Ketungau Basin, West Kalimantan

Directory of Open Access Journals (Sweden)

M.H. Hermiyanto Zajuli

2014-06-01

Full Text Available DOI: 10.17014/ijog.v6i2.119Indonesia contains many Paleogene and Neogene basins which some of them have been proven to be a very prolific producer of oil and gas. A study on the result of Rock-Eval pyrolysis and biomarker undertaken on the Eocene Mandai Group was able to assess hydrocarbon potential of the Paleogene fine sediments in the frontier basin, especially West Kalimantan area. East Ketungau Basin is located in the western Kalimantan, bounded with Melawi Basin by the Semitau High in the south and West Ketungau Basin in the west. The Mandai Group was deposited in the East Ketungau Basin during Eocene, consisting of sandstone and mudstone facies. Mudstone facies comprises shale, claystone, and coal. Seven samples of Eocene fine sediments collected from East Ketungau Basin were analyzed by Rock-Eval pyrolisis and three samples for biomarker to evaluate their hydrocarbon potential. The Rock-Eval pyrolisis result of Mandai Group shows that TOC value of this facies ranges from 0.34 % to 5.16 %, Potential Yield (PY between 0.06 and 4.78 mg HC/g rock, and Hydrogen Index (HI from 12 to 89. Based on that result, the fine sediments of Mandai Group are included into a gas prone source rock potential with poor to fair categories. Moreover Tmax values vary from 426o C to 451o C. The Eocene fine sediments of Mandai Group fall under kerogen type III. Based on Tmax and biomarker analyses, the maturity of the sediments is situated within immature to mature level. The fine sediments of Mandai Group were deposited in a terrestrial to marine environment under anoxic to sub-oxic condition.

Preferred-rupture propagation to the hangingwall of the shallow part of the out-of-sequence thrust: Ishido Fault in Boso Peninsula, central Japan

Science.gov (United States)

Yamamoto, Y.; Fukuyama, M.; Ujiie, K.; Hirose, T.; Hamada, Y.; Kitamura, M.; Kamiya, N.

2016-12-01

Although earthquake ruptures in shallow portion of plate boundary have recently been identified (e.g. Tohoku, Nankai, etc.), their mechanisms why the shallow portion of plate boundary composed mainly of clay minerals can accumulate strain and make seismic slip are under controversial. An ancient out-of-sequence thrust which divided the early and late Miocene accretionary complexes in the Boso Peninsula, central Japan records rupture propagation to the shallow portion of accretionary prism (The fault core is composed of black-colored thin (The former is characterized by homogeneous glassy matrix including fragments of quartz/feldspar, submicron-sized Fe-rich spherules, and vesicles. Based on the mineralogy of the host rock and EDS analyses of matrices, origin of the pseudotachylite was apparently frictional melting of smectite containing Fe. Fe-rich spherules formed by rapid cooling of pseudotachylite. On the other hand, overturned fault-related drag fold developed in the footwall, within about 30 m. Although some Riedel sheared normal faults developed in the overturned footwall, no other brittle deformations were identified. These occurrences imply coexistence of low- and high-speed slips along the same thrust fault. The whole-rock major and trace elemental analyses using XRF and ICP-MS show that mudstone in the hangingwall has similar chemical composition to those of pseudotachylite and fluidized fault gouge with REE enriched patterns, whereas the footwall has different chemical characteristics with relatively flat REE pattern and low LOI. Therefore, the protolith of pseudotachylite and fluidized fault gouge is mudstone in the hangingwall. These data imply that rupture propagation preferably occurred in the hangingwall along the fault zone. The footwall was also deformed apparently during slow-slip deformation leading to formation of the overturn, whereas only the hangingwall, just side of the fault zone, slipped under high-speed shear.

Griffith Saponite as an Analog for Clay Minerals at Yellowknife Bay in Gale Crater, Mars: A Marker for Low-temperature Hydrothermal Processes

Science.gov (United States)

Morris, R.V.; Treiman, A. H.; Agresti, D. G.; Graff, T. G.; Achilles, C. N.; Rampe, E. B.; Bristow, T. F.; Ming, D. W.; Blake, D. F.; Vaniman, D. T.;

Stratigraphy and structure of the Miners Mountain area, Wayne County, Utah

Science.gov (United States)

Luedke, Robert G.

1953-01-01

The Miners Mountain area includes about 85 square miles in Wayne County, south-central Utah. The area is semiarid and characterized by cliffs and deep canyons. Formations range in age from Permian to Upper Jurassic and have an aggregate thickness of about 3,500 feet. Permian formations are the buff Coconino sandstone and the overlying white, limy, shert-containing Kaibab limestone. Unconformably overlying the Kaihab is the lower Triassic Moenkopi formation of reddish-brown and yellow mudstone, siltstone, and sandstone; it contains the Sinbad limestone member (?) in the lower part. Thin, lenticular Shinarump conglomerate unconformably overlies the Moenkopi, but grades upward into the Upper Triassic Chinle formation of variegated mudstone with some interbedded sandstone and limestone lenses. Uncomformably overlying the Chinle are the Wingate sandstone, Kayenta formation, and Navajo sandstone of the Jurassic (?) Glen Canyon group, which consist of red to white sandstone. Only the lower part of the Carmel formation of the Upper Jurassic San Rafael group is exposed in the area; it consists of variegated siltstone, sandstone, limestone, and gypsum. The conspicuous structural feature in the area is the Teasdale anticline which trends northwest, is about 14 miles long, and is asymmetric with a steeper west flank. Bounding the anticline on the northeast and east is the Capitol Reef monocline, the northern part of the Waterpocket Fold. Strata in the area are broken by steeply-dipping normal faults with small displacements, except for the Teasdale fault which has a maximum displacement of over 1,000 feet. Jointing is prominent in some formations. The major orogenic movement in the area is believed to be late Upper Cretaceous to early Tertiary. Epeirogenic uplift occurred intermittently throughout Tertiary and perhaps Quaternary time.

Searching for Ancient Lakebeds in Ladon Basin, Mars and Implications for Future Exploration

Science.gov (United States)

Colón, A. M.; Miranda, C.; Milliken, R.

2017-12-01

It is well known from terrestrial studies that clay-rich rocks, and lacustrine mudstones in particular, are efficient at trapping, binding, and preserving organic matter through geologic time. This has also been demonstrated on Mars, where the Curiosity rover has detected organics in ancient mudstones in Gale crater. A number of other potential ancient lake sites have been proposed as landing sties for the Mars 2020 rover, including regions within the Ladon Basin and Valles system. In this study we map of the distribution of clay deposits in the Uzboi-Morava-Ladon (ULM) System, a system thought to have been a series of lakes interconnected by channels, and assess how these hydrous minerals relate to topography, adjacent fluvial networks, and the overall stratigraphy of basin deposits. We use CTX images and near-IR spectral reflectance data from the Mars Reconnaissance Orbiter CRISM instrument to independently map morphological and mineralogical features within Ladon. We find a number of occurrences of stratified, light-toned outcrops within the basin, but individual outcrops are small even at the scale of CTX images and are concentrated in several locations in the basin. Some light-toned outcrops are associated with clay minerals, but in general the light-toned appearance appears to be a poor proxy for clay distribution. CRISM data reveal that some clay-bearing regions are visually indistinct from adjacent clay-poor terrains. Some of the best examples of stratified, clay-bearing rocks are found in Ladon Valles, where they occur in terraces. In general, the stratigraphic, topographic, and morphologic evidence do not preclude a lacustrine origin, but there is no diagnostic evidence to support this interpretation either. The clay-bearing and light-toned deposits within Ladon basin may instead reflect deposition in an alluvial/fluvial system that post-dates the peak period of inferred lacustrine activity in the ULM system.

Provenance and tectonic setting of the Neoproterozoic clastic rocks hosting the Banana Zone Cu-Ag mineralisation, northwest Botswana

Science.gov (United States)

Kelepile, Tebogo; Bineli Betsi, Thierry; Franchi, Fulvio; Shemang, Elisha; Suh, Cheo Emmanuel

2017-05-01

Petrographic and geochemical data were combined in order to decipher the petrogenesis of the Neoproterozoic sedimentary succession associated with the Banana Zone Cu-Ag mineralisation (northwest Botswana), in the Kalahari Copperbelt. The investigated Neoproterozoic sedimentary succession is composed of two formations including the Ngwako Pan and the D'kar Formations. The Ngwako Pan Formation is made up of continental siliciclastic sediments, mainly sandstones interbedded with siltstones and mudstones, whereas the D'kar Formation is comprised of shallow marine laminated siltstones, sandstones and mudstones, with subordinate limestone. Copper-Ag mineralisation is essentially confined at the base of the D'kar Formation, which bears reduced organic components, likely to have controlled Cu-Ag precipitation. Sandstones of both the Ngwako Pan and the D'kar Formations are arkoses and subarkoses, composed of quartz (Q), feldspars (F) and lithic fragments (L). Moreover, geochemically the sandstones are considered as potassic and classified as arkoses. On the other hand, mudrocks of the D'kar Formation are finely laminated and are dominated by muscovite, sericite, chlorite and quartz. The modified chemical index of weathering (CIW‧) values indicated an intense chemical weathering of the source rock. The dominance of detrital quartz and feldspar grains coupled with Al2O3/TiO2 ratios (average 29.67 and 24.52 for Ngwako Pan and D'kar Formations, respectively) and Ni and Cr depletion in the sandstones, suggest a dominant felsic source. However, high concentrations of Ni and Cr and a low Al2O3/TiO2 ratio (block and deposited in a continental rift setting (passive margin) in a humid environment. The source rocks might have been the Palaeoproterozoic basement rocks (granitoids and granitic gneiss) and the Mesoproterozoic Kgwebe volcanic rocks exposed north of the study area.

Stratigraphy of the Kapalga Formation north of Pine Creek and its relationship to base metal mineralization

International Nuclear Information System (INIS)

Goulevitch, J.

1980-01-01

The lithology, stratigraphy and mineralization of the Kapalga Formation (South Alligator Group) is described from the Margaret Syncline in the Pine Creek area of the Northern Territory of Australia. An interdigitation of carbonaceous siltstones and mudstones, chert, ashstones and tuffaceous chert, greywacke, siltstone, mudstone and minor banded iron formation (b.i.f.) characterises the Formation. These rocks define a vertical facies transition between low energy sediments of the underlying Koolpin Formation, and high energy sediments of the overlying Burrell Creek Formation. This transition is interlayered with numerous ashstone-tuffaceous chert horizons which were deposited during the waning stage of Gerowie Tuff sedimentation. The boundary between the Kapalga Formation of the South Alligator Group and the Burrell Creek Formation of the Finniss River Group is strictly conformable in this part of the Pine Creek 'Geosyncline'. Relict devitrified shards have been recognised in the Gerowie Tuff in the Margaret Syncline and these observations along with whole-rock chemical analyses conclusively support claims by previous investigators that these rocks are volcanic derivatives. Base metal mineralization at Iron Blow and Mt. Bonnie occurs as massive, stratiform, sulphide-silicate-carbonate lodes. The deposits are at the same stratigraphic level towards the base of the Kapalga Formation and minor stratification parallel with bedding has been observed. These features, and the association of the lodes with mud-flow breccias, lead to the conclusion that the lodes are syngenetic in origin. Thermochemical consideration of the sulphide assemblages together with the temporal relationship between the mineralization and Gerowie Tuff point to diagenetic devitrification of the underlying tuffaceous rocks as the source of the mineralization. Recent publications of experimental data from reaction of seawater and volcanic glass provide information which supports this thesis, and

Electrical Conductive Mechanism of Gas Hydrate-Bearing Reservoirs in the Permafrost Region of Qilian Mountain

Science.gov (United States)

Peng, C.; Zou, C.; Tang, Y.; Liu, A.; Hu, X.

2017-12-01

In the Qilian Mountain, gas hydrates not only occur in pore spaces of sandstones, but also fill in fractures of mudstones. This leads to the difficulty in identification and evaluation of gas hydrate reservoir from resistivity and velocity logs. Understanding electrical conductive mechanism is the basis for log interpretation. However, the research is insufficient in this area. We have collected well logs from 30 wells in this area. Well logs and rock samples from DK-9, DK-11 and DK-12 wells were used in this study. The experiments including SEM, thin section, NMR, XRD, synthesis of gas hydrate in consolidated rock cores under low temperature and measurement of their resistivity and others were performed for understanding the effects of pore structure, rock composition, temperature and gas hydrate on conductivity. The results show that the porosity of reservoir of pore filling type is less than 10% and its clay mineral content is high. As good conductive passages, fractures can reduce resistivity of water-saturated rock. If fractures in the mudstone are filled by calcite, resistivity increases significantly. The resistivity of water-saturated rock at 2°C is twice of that at 18°C. The gas hydrate formation process in the sandstone was studied by resistivity recorded in real time. In the early stage of gas hydrate formation, the increase of residual water salinity may lead to the decrease of resistivity. In the late stage of gas hydrate formation, the continuity decrease of water leads to continuity increase of resistivity. In summary, fractures, rock composition, temperature and gas hydrate are important factors influencing resistivity of formation. This study is helpful for more accurate evaluation of gas hydrate from resistivity log. Acknowledgment: We acknowledge the financial support of the National Special Program for Gas Hydrate Exploration and Test-production (GZH201400302).

Genesis of natural hydraulic fractures as an indicator of basin inversion

Science.gov (United States)

Meng, Qingfeng; Hooker, John; Cartwright, Joe

2017-09-01

Satin spar (fibrous gypsum) veins, which occur in evaporite basins worldwide, provide significant insights into host rock deformation and fluid flow, although the genetic mechanism remains obscure. Satin spar veins in the red marls of the Triassic Mercia Mudstone of the Bristol Channel Basin were characterized in the context of regional and local setting. The vein network in the Keuper Marl (lower Mercia) exhibits a lack of systematic cross-cutting between three distinct vein sets. Two sets of veins are observed in the overlying Tea Green Marl, with one set clearly crossing the other. The gypsum veins commonly contain a blocky median zone of multiple thin bands of host-rock inclusions and alabastrine gypsum crystals, exhibiting crack-seal patterns. Fibrous zones on either side of the median zone consist of pure parallel-aligned gypsum fibres that are oblique to vein walls, indicating a hybrid shear-extensional mode of vein widening. Veins developed within reverse-reactivated faults contain fibre lineations in the median zones and also on vein surfaces, suggesting a minimum of two phases of fault slip. The veins are interpreted to have formed as a result of overpressure in the low-permeability mudstones by tectonic compression during basin inversion, giving rise to the median zone. Growth of gypsum fibres commenced when the initial fractures were completely sealed. The timing of vein formation is suggested to be Miocene, based on cross-cutting relationships with folds formed during the latest phase of basin inversion. Because the fractures initiated in response to fluid overpressures, they provide a useful analog to subsurface hydraulic fracture systems in low-permeability rocks subjected to tectonic compression. The fibrous widening of the veins post-dates their initiation and led to continued propagation and increased connectivity.

Bioerosion by pit-forming, temperate-reef sea urchins: History, rates and broader implications

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Gibbs, Victoria K.; Duwan, Emily

2018-01-01

Sea urchins are dominant members of rocky temperate reefs around the world. They often occur in cavities within the rock, and fit so tightly, it is natural to assume they sculpted these “pits.” However, there are no experimental data demonstrating they bore pits. If they do, what are the rates and consequences of bioerosion to nearshore systems? We sampled purple sea urchins, Strongylocentrotus purpuratus, from sites with four rock types, three sedimentary (two sandstones and one mudstone) and one metamorphic (granite). A year-long experiment showed urchins excavated depressions on sedimentary rocks in just months. The rate of pit formation varied with rock type and ranged from 100 yr for granite. In the field, there were differences in pit size and shapes of the urchins (height:diameter ratio). The pits were shallow and urchins flatter at the granite site, and the pits were deeper and urchins taller at the sedimentary sites. Although overall pit sizes were larger on mudstone than on sandstone, urchin size accounted for this difference. A second, short-term experiment, showed the primary mechanism for bioerosion was ingestion of the substratum. This experiment eliminated potential confounding factors of the year-long experiment and yielded higher bioerosion rates. Given the high densities of urchins, large amounts of rock can be converted to sediment over short time periods. Urchins on sandstone can excavate as much as 11.4 kg m-2 yr-1. On a broader geographic scale, sediment production can exceed 100 t ha-1 yr-1, and across their range, their combined bioerosion is comparable to the sediment load of many rivers. The phase shift between urchin barrens and kelp bed habitats in the North Pacific is controlled by the trophic cascade of sea otters. By limiting urchin populations, these apex predators also may indirectly control a substantial component of coastal rates of bioerosion. PMID:29466357

Evolution of pores and fractures in an unconventional Upper Carboniferous reservoir analogue, Westphalian D, W-Germany

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Hoehne, M.; Schurk, K.; Hilgers, C. [RWTH Aachen Univ. (Germany). Reservoir-Petrology, Energy and Mineral Resources Group (EMR); Koehrer, B. [Wintershall Holding GmbH, Barnstorf (Germany); Bertier, P. [RWTH Aachen Univ. (Germany). Inst. of Clay and Interface Mineralogy

2013-08-01

Uncertainties in reservoir characterization of tight gas sandstones can be significantly reduced by using quantitative data from outcrops. The active Piesberg quarry near Osnabrueck exposes Upper Carboniferous strata and therefore provides a reservoir outcrop analog to the gas-bearing tight gas fields in NW-Germany. This study focused on variations of sedimentary facies, porosity, diagenesis and structural inventory in the quarry. The Westphalian D strata at Piesberg consist of siliciclastic, coarse- to fine-grained sandstones with a strong cementation, intercalated with coal seams, siltstones and mudstones. Petrography shows shale-, mudstone and clay rip-up fragments squeezed into primary porosity during eodiagenesis. Sandstone types commonly show low porosities (<10 %) and very low permeabilities (<0.01 mD) mainly due to intense quartz cementation. Scarce authigenic carbonates are euhedral ankerites formed during burial. Secondary porosity resulted mostly from detrital carbonate leaching and limited dissolution of feldspars. Within a zone of up to several meters around faults, porosity is much higher. Feldspars are almost completely altered to illite and locally to kaolinite. Partly dissolved detrital carbonates show Fe-oxide margins around intragranular pores, indicative of Fe-rich compositions formed during telo-diagenesis. Both joints and faults were mapped throughout the quarry and strike, slip and throw of the latter were documented. Cemented fractures prevail around faults and may thus be associated with the structural and diagenetic evolution of the Upper Carboniferous of the Piesberg area. This study is embedded into a larger outcrop analog study of RWTH Aachen in cooperation with Wintershall. Its aim is to unravel the impact of structural diagenesis on the alteration and evolution of pore space and thus reservoir quality. Results can be used to develop datadriven exploration strategies and improved development options for analogous subsurface tight gas

Formation of fine crystalline dolomites in lacustrine carbonates of the Eocene Sikou Depression, Bohai Bay Basin, East China

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Yong-Qiang Yang

2016-11-01

Full Text Available Abstract The genesis of the fine crystalline dolomites that exhibit good to excellent reservoir properties in the upper fourth member of the Eocene Shahejie Formation (Es 4 s around the Sikou Sag, Bohai Bay Basin, is uncertain. This paper investigates the formation mechanisms of this fine crystalline dolomite using XRD, SEM, thin section analysis and geochemical data. The stratigraphy of the Sikou lacustrine carbonate is dominated by the repetition of metre-scale, high-frequency deposition cycles, and the amount of dolomite within a cycle increases upward from the cycle bottom. These dolomite crystals are 2–30 μm in length, subhedral to anhedral in shape and typically replace both grains and matrix. They also occur as rim cement and have thin lamellae within ooid cortices. Textural relations indicate that the dolomite predates equant sparry calcite cement and coarse calcite cement. The Sr concentrations of dolomites range from 900 to 1200 ppm. Dolomite δ18O values (−11.3 to −8.2 ‰ PDB are depleted relative to calcite mudstone (−8.3 to −5.4 ‰ PDB that precipitated from lake water, while δ13C values (0.06–1.74 ‰ PDB are within the normal range of calcite mudstone values (−2.13 to 1.99 ‰ PDB. High 87Sr/86Sr values (0.710210–0.710844 indicate that amounts of Ca2+ and Mg2+ have been derived from the chemical weathering of Palaeozoic carbonate bedrocks. The high strontium concentration indicates that hypersaline conditions were maintained during the formation of the dolomites and that the dolomites were formed by the replacement of precursor calcite or by direct precipitation.

Physical data of soil profiles formed on late Quaternary marine terraces near Santa Cruz, California

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Munster, Jennie; Harden, Jennifer W.

2002-01-01

The marine terraces in and around Santa Cruz, California, represent a set of well-preserved terraces formed as a product of geology, sea level, and climate. A marine terrace begins as a wave cut platform. Eustatic sea level changes, seacliff erosion, and tectonic uplift work together to generate marine terraces. "When a wave-cut platform is raised (due to tectonic activity) above sea level and cliffed by wave action it becomes a marine terrace" (Bradley, 1957, p. 424). During glacial periods, eustatic sea level is estimated to have dropped by 150 meters (Fairbanks, 1989). Cliff retreat measured from aerial photographs between 1930 and 1980 vary from 0.0 to 0.2 m yr–1 (Best and Griggs, 1991). Estimates of uplift rates along the Santa Cruz coastline vary from 0.10 to 0.48 m kyr–1 (Bradley and Griggs, 1976; Weber and others, 1999). Uplift mechanisms include coseismic uplift associated both with a reverse component of slip on the steeply SW dipping Loma Prieta fault in the restraining bend of the San Andreas Fault and a small component of reverse slip on the steeply SE dipping San Gregorio fault (Anderson and Menking 1994). Previous work studying physical properties on these terraces include Pinney and others (in press) and Aniku (1986) and Bowman and Estrada (1980). Sedimentary deposits of the marine terraces are a mixture of terrestrial and marine sediments but generally consist of a sheet of marine deposits overlying the old platform and a wedge of nonmarine deposits banked against the old sea cliff (Bradley, 1957). Bedrock underlying the terraces in the Santa Cruz area is generally either Santa Margarita Sandstone or Santa Cruz Mudstone. The Santa Margarita Sandstone represents an upper Miocene, transgressive, tidally dominated marine-shelf deposit with crossbedded sets of sand and gravel and horizontally stratified and bioturbated invertebrate-fossils beds (Phillips, 1990). The siliceous Santa Cruz Mudstone, of late Miocene age, conformably overlies the Santa

Formation conditions and prospecting criteria for sandstone uranium deposit of interlayer oxidation type

International Nuclear Information System (INIS)

Huang Shijie

1994-01-01

This paper comprehensively analyses the geotectonic setting and favourable conditions, such as structure of the basin, sedimentary facies and paleogeography, geomorphology and climate, hydrodynamics and hydrogeochemistry, the development of interlayered oxidation etc, necessary for the formation of sandstone uranium deposit of interlayered oxidation type. The following prospecting criteria is proposed, namely: abundant uranium source, arid climate, stable big basin, flat-lying sandstone bed, big alluvial fan, little change in sedimentary facies, intercalation of sandstone and mudstone beds, shallow burying of sandstone bed, well-aquiferous sandstone bed, high permeability of sandstone bed, development of interlayered oxidation, and high content of reductant in sandstone. In addition, the 6 in 1 hydrogenic genetic model is proposed

The Nitrate/Perchlorate Ratio on Mars as an Indicator for Habitability

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Stern, J. C.; Sutter, B.; McKay, C. P.; Navarro-Gonzalex, R.; Freissinet, C.; Conrad, P. G.; Mahaffy, P. R.; Archer, P. D., Jr.; Ming, D. W.; Niles, P. B.;

Lower Oligocene non-geniculate coralline red algal (Corallinales, Rhodophyta assemblage from Poljšica pri Podnartu (Upper Carniola, Slovenia

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Luka Gale

2008-12-01

Full Text Available The Lower Oligocene Gornji Grad beds from Polj{ica pri Podnartu consist of marly limestone, mudstone, several layers of limestones and two layers of sandstones, and were deposited on a mixed carbonate-siliciclastic ramp.Especially the limestones contain rich fossil fauna and non-geniculate coralline red algae. These were systematicallycollected from four horizons and researched in thin sections under an optical microscope. Genera Lithoporella,Neogoniolithon, Spongites, Lithothamnion, Mesophyllum and Spongites were recognized. Surface area for each genus was calculated and the differences in the coralline assemblages in the four horizons were analysed. Thecorallines originate from two source areas: sandy-muddy bottom of a shallow marine environment, and small coral bioherms with its encrusters.

Positively charged microporous ceramic membrane for the removal of Titan Yellow through electrostatic adsorption.

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Cheng, Xiuting; Li, Na; Zhu, Mengfu; Zhang, Lili; Deng, Yu; Deng, Cheng

2016-06-01

To develop a depth filter based on the electrostatic adsorption principle, positively charged microporous ceramic membrane was prepared from a diatomaceous earth ceramic membrane. The internal surface of the highly porous ceramic membrane was coated with uniformly distributed electropositive nano-Y2O3 coating. The dye removal performance was evaluated through pressurized filtration tests using Titan Yellow aqueous solution. It showed that positively charged microporous ceramic membrane exhibited a flow rate of 421L/(m(2)·hr) under the trans-membrane pressure of 0.03bar. Moreover it could effectively remove Titan Yellow with feed concentration of 10mg/L between pH3 to 8. The removal rate increased with the enhancement of the surface charge properties with a maximum rejection of 99.6%. This study provides a new and feasible method of removing organic dyes in wastewater. It is convinced that there will be a broad market for the application of charged ceramic membrane in the field of dye removal or recovery from industry wastewater. Copyright © 2016. Published by Elsevier B.V.

Application of Principal Component Analysis in Assessment of Relation Between the Parameters of Technological Quality of Wheat Grains Treated with Inert Dusts Against Rice Weevil (Sitophilus oryzae L.

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Marija Bodroža-Solarov

2011-01-01

Full Text Available Quality parameters of several wheat grain lots (low vitreous and high vitreous grains,non-infested and infested with rice weevils, (Sitophilus oryzae L. treated with inert dusts(natural zeolite, two diatomaceous earths originating from Serbia and a commercial productProtect-It® were investigated. Principal component analysis (PCA was used to investigatethe classification of treated grain lots and to assess how attributes of technological qualitycontribute to this classification. This research showed that vitreousness (0.95 and test weight(0.93 contributed most to the first principal component whereas extensigraph area (-0.76contributed to the second component. The determined accountability of the total variabilityby the first component was around 55%, while with the second it was 18%, which meansthat those two dimensions together account for around 70% of total variability of the observedset of variables. Principal component analysis (PCA of data set was able to distinguishamong the various treatments of wheat lots. It was revealed that inert dust treatments producedifferent effects depending on the degree of endosperm vitreousness.

Control of the phytoplankton response during the SAGE experiment: A synthesis

Science.gov (United States)

Peloquin, Jill; Hall, Julie; Safi, Karl; Ellwood, Michael; Law, Cliff S.; Thompson, Karen; Kuparinen, Jorma; Harvey, Michael; Pickmere, Stuart

2011-03-01

The SOLAS Air-Sea Gas Exchange (SAGE) experiment was conducted in Sub-Antarctic waters off the east coast of the South Island of New Zealand in the late summer of 2004. This mesoscale iron enrichment experiment was unique in that chlorophyll a (chl a) and primary productivity were only 2× OUT stations values toward the end of the experiment and this enhancement was due to increased activity of non-diatomaceous species. In addition, this enhancement in activity appeared to occur without a significant build up of particulate organic carbon. Picoeukaryotes (statistically significant increase, a doubling in biomass. To better understand the controls of phytoplankton growth and biomass, we present results from a series of on-deck perturbation experiments conducted during SAGE. Results suggest that the pico-dominated phytoplankton assemblage was only weakly inhibited by iron. Diatoms with high growth rates comprised a small (food web. A primary implication of this study is that any iron-mediated gain in fixed carbon with this set of environmental conditions has a high probability of being recycled in surface waters.

Polymerase Chain Reaction (Pcr) Assay to Detect Hepatitis C Virus

International Nuclear Information System (INIS)

Lina MR; Dadang S; Budiman Bela

2004-01-01

Research on the detection of hepatitis C virus in blood serum using PCR technique has been carried out. Amount of 50 blood serum from laboratory of Indonesia Red Cross (Palang Merah Indonesia = PMI) and RSCM hospital as samples, were used in this research. Lysis of virus cell and extraction of RNA virus as a preliminary treatment of the sample, was done with BOOM method using guanidine thiocyanate and diatomaceous earth, respectively. Synthesis of cDNA from RNA as an extraction product mentioned above, was carried out by means of reverse-transcriptase and RNA-se inhibitor. Amplification of cDNA was done with nested PCR technique that was performed with two times PCR processes using two pairs of oligonucleotide primers for each process. The amplified DNA was detected by agarose gel electrophoresis and ethidium bromide staining. Subsequently, the DNA was visualized with UV transilluminator. Result shows that of 50 blood serum samples, 13 serum were positive for RNA HCV that were performed with the present of specific DNA band on agarose gel. (author)

Bioluminescent bacteria have potential as a marker of drowning in seawater: two immersed cadavers retrieved near estuaries.

Science.gov (United States)

Kakizaki, Eiji; Kozawa, Shuji; Sakai, Masahiro; Yukawa, Nobuhiro

2009-03-01

We detected numerous bioluminescent bacteria in blood samples from two cadavers that had been immersed in estuarine environments. Autopsy, diatomaceous and toxicological findings indicated death by drowning, which agreed with environmental aspects and the findings of police investigations. Bioluminescent bacteria appeared in blood samples cultured on selective agar containing 2%, 3% and 4% NaCl after about 18h. Blood from the left side of the heart, the right side of the heart and the femoral vein generated 7.0 x 10(2), 2.0 x 10(4) and 8.0 x 10(2) cfu/ml of blood (case 1), and 1.8 x 10(4), 1.1 x 10(3) and 2.5 x 10(1) cfu/ml (case 2) of bioluminescent colonies, respectively, in agar containing 4% NaCl. Homologous analysis based on the 16S rRNA gene also identified the bioluminescent colonies as Vibrio fischeri and V. harveyi, which normally inhabit seawater. This simple assay might serve as an additional indicator to support a conclusion of death by drowning together with the diatom test.

Study on the immobilization of alpha-amylase by radiation-induced polymerization at low-temperature, (1)

International Nuclear Information System (INIS)

Yoshida, Masaru; Kumakura, Minoru; Kaetsu, Isao

1975-07-01

The immobilization of enzymes by radiation-induced polymerization at low temperatures has been studied. It is important to know how the enzymes are affected by irradiation. The radiation effect of enzyme itself before immobilization must thus be investigated. In radiation effect on α-amylase from Bacillus subtilis, interesting results were obtained, as follows. The enzyme is very stable for irradiation in the total dose range of 1 x 10 4 to 1 x 10 7 R, and the activity is hardly affected. And further, the relative activity increases by irradiation, when the α-amylase is of high purity or contains some appropriate additive. A certain substance such as diatomaceous earth or CaCl 2 thus decreases the activity, while the addition of DRIERITE composed mainly of CaSO 4 increases the activity. α-Amylase is then more stable and higher in activity in the irradiation at lower temperatures. The activity is independent of presence or absence of the ambient air. In conclusion, α-amylase is very stable for irradiation at low temperatures; therefore, its immobilization by polymerization at low temperature is recommended. (auth.)

Alternatives for clarifying glucose syrup obtained by enzymatic hydrolysis of starch

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Gloria Teresa Cruz Guerrero

2004-05-01

Full Text Available The present paper studies some routes for separating and purifying glucose syrup obtained by enzymatic hydrolysis of potato starch. The clarifying process is done in three stages. The first one (solids remotion is done by applying conventional solid-liquid separation techniiques such as sedimentation, centrifugation and filtration, as well as studying the effect of using flocculant and coagulant agents, prior to the already mentioned operations. Purification is done by adding decolouring agents, followed by ultrafiltration of the syrup. The last step (concentration is done by vacuum evaporation. The results showed that separation, centrifuging and sedimation reached 50% yield whilst filtration and ultrafiltration achieved 78% and 98% respectively. It was found that adsorbent agents such as activated carbon and diatomaceous earth were effective in removing colour during the purification stage. The most suitable alternative for separation can be suggested from the foregoing, allowing a syrup to be obtained having similar characteristics and propierties to the commercial product. The most appropriate technological module for carrying out the operation is also represented.

Further studies of the nature, composition and ages of contemporary phosphorite from the Namibian Shelf

International Nuclear Information System (INIS)

Thomson, J.; Calvert, S.E.; Mukherjee, S.; Burnett, W.C.; Bremner, J.M.

1984-01-01

Major and minor element and radiochemical data are examined for a set of phosphorite concretions and other phosphatic material from the Namibian Shelf. The concretions were separated on a morphological basis from grab samples taken in a transect of shallowing depth over the diatomaceous ooze belt. Compositional data indicate that the samples are fairly pure carbonate-fluorapatite, and trend towards a maximum 32% P 2 O 5 content. A range of compositional variability similar to other samples from the Namibian Shelf is observed. Radiochemical systematics confirm that pelletal phosphorite and glauconitized pelletal phosphorite from depths > 170 m are at radioactive equilibrium, and are therefore old and reworked. The concretions, collected from depths shallower than 78 m, are entirely Recent, with maximum ages in the range 500-3800 years. They may be much younger. Despite distinct textural and small compositional differences, similar are found for separates from the same grab. Samples of fish scales and an unidentified high-magnesian phosphate mineral are also shown to have incorporated uranium recently. (orig.)

Summarized report on research cooperation promotion project in fiscal 2000. Research cooperation on developing high-efficiency mineral resource extracting and processing technology of environment harmonizing type; 2000 nendo kenkyu kyoryoku suishin jigyo sokatsu hokokusho. Kankyo chowagata kokoritsu kobutsushigen chushutsu shori gijutsu no kaihatsu ni kansuru kenkyu kyoryoku

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NONE

2001-03-01

A joint research with the Republic of Kazakhstan has been carried out on developing a technology to extract and recover efficiently the valuable metals (copper, gold, silver and others) contained in ore wastes in large quantity produced in association with mine operation, with considerations given to the environment. This paper summarizes the achievements in fiscal 2000. The joint research has performed site survey for existence of ore wastes in the Republic of Kazakhstan, domestic research for discussing the disposal systems, design, fabrication, installation, adjustment and operation of a pilot plant. Process researches included ore flotation test, leaching test on Zhezkent ore wastes in chemical leaching and low-grade Nikolayevska ores, Cu leaching acceleration effect in bacteria leaching, utilization of activated carbon, fundamental test on solvent extraction, reverse extraction test, test using iron oxidizing bacteria in waste water treatment, Fe{sup 2}+ oxidation in waste water due to waste water bacteria concentrated by diatomaceous earth, Au and Ag leaching test, and column leaching test. This paper summarizes the results thereof. (NEDO)

Development of high sensitivity gamma and beta sensors for in situ diffusion tests in the mudstone in France

International Nuclear Information System (INIS)

Lin, Zhenhua

2017-01-01

The precise monitoring of radiotracers, for example used for medical imaging, for the storage of ultimate waste, or for certain industrial applications can be a very complex subject. The development of low-noise sensors with long-term stability and high geometric flexibility were engaged by the AXINT company. (Hautefeuille, et al., 2006). My PhD thesis was focused on experiments in the diffusion of radiotracers, typically to monitor the possible leakage of radioactive products from the geological repositories. We focuses on the study of the "2"2Na and "3"6Cl ion diffusion, which is one of the highest cation and anions diffusion rate in geological medium, as well as actinides, which represent the majority of the radioactive elements of Stored nuclear waste. This thesis is in continuity with the research carried out by ANDRA (National Agency for Radioactive Waste), under contract with the laboratory ILM (Institute Light Matter), of which AXINT is the main subcontractor. The present project describes the research work that foreseen the radiation impact on the environment for the coming years during the deep disposal of nuclear waste. Our work focus on the investigation and quantification of the radionuclide diffusion through the geological clay barriers. A new in situ experiment was considered by Andra for the study of the radionuclide migration. Compared to previous experiments, this new in situ diffusion test required longer distance (hundreds of mm), longer time-scale (over 10 years), and real time in situ monitoring of radionuclides migration. To fulfill these conditions, the work was organized as following: 1: Conception and dimensional design of the Diffusion of Radio Nuclide (DRN) experiments in solving emission of beta and gamma radiations 2: Development of corresponding beta and gamma monitoring systems by means of sensors located in peripheral boreholes. (author) [fr

Surveying Clay Mineral Diversity in the Murray Formation, Gale Crater, Mars

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Bristow, T.F.; Blake, D. F..; Vaniman, D. T.; Chipera, S. J.; Rampe, E. B.; Grotzinger, J. P.; McAdam, A. C.; Ming, D. W..; Morrison, S. M.; Yen, A. S.;

Control of the Mexican bean weevil Zabrotes subfasciatus with kaolin Controle do caruncho-do-feijão Zabrotes subfasciatus com caulim

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Adriana Yatie Mikami

2010-07-01

Full Text Available The Mexican bean weevil Zabrotes subfasciatus (Coleoptera: Chrysomelidae: Bruchinae is an important pest of stored beans in tropical regions. The efficiency of kaolin [with or without neem (Azadirachta indica oil] and diatomaceous earth (DE (standard treatment was studied in laboratory aiming to obtain alternatives for chemical control of this insect. Insects were confined in plastic vials containing beans treated with kaolin (2, 4 and 8g kg-1, kaolin + neem [2g kg-1(5% neem oil], diatomaceous earth (1g kg-1 and control. Mortality of adult insects, number of eggs and F1generation beetles emergency were assessed. Kaolin caused mortality of Z. subfasciatus, however higher periods and doses than DE were necessary to promote high mortality (100% or close. Kaolin treatments also affected female behavior because many eggs were placed in the vials walls. Number of emerged adults (F1 was similar between DE and kaolin; hence, kaolin constitutes a promising tool to the management of Z. subfasciatus. The mixture of kaolin and neem oil was not efficient in the control of Z. subfasciatus.O caruncho-do-feijão Zabrotes subfasciatus (Coleoptera: Chrysomelidae: Bruchinae é uma importante praga de grãos de feijão armazenado nas regiões tropicais. A eficiência do caulim [com ou sem óleo de nim (Azadirachta indica] e terra diatomácea (TD (tratamento padrão foi estudada em laboratório com o intuito de obter alternativas para o controle químico deste inseto. Insetos foram confinados em frascos de plástico com feijão tratado com caulim (2, 4 e 8g kg-1, caulim + nim [2g kg-1(5% óleo de nim], terra diatomácea (1g kg-1 e controle. Mortalidade de insetos adultos, número de ovos e emergência da geração F1 foram avaliados. Caulim causou a mortalidade de Z. subfasciatus, porém foram necessários maiores períodos e doses que a TD para promover elevada mortalidade (100% ou aproximadamente. Os tratamentos com caulim também afetaram o comportamento da f

Preliminary mineralogical and paleoenvironmental study of the diatomites from Adamclisi, South Dobrogea, Romania

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Dumitras, Delia-Georgeta; Sebe-Radoi, Oana-Gabriela; Marincea, Stefan; Costea, Constantin

2017-04-01

Diatomite samples taken from the Urluia - Adamclisi localities, South Dobrogea region (Romania) have been studied by X-ray fluorescence, wet-chemical analysis, scanning electron microscopy (SEM), FTIR and X-ray powder diffraction. The diatomaceous earth from Adamclisi occurs as beds and lenses in alternance with bentonitic clays and limestones. The diatomite levels are chalk-like, soft, friable, earthy, very fine-grained, and have a white - yellow color. The mineralogy of all but one sample is characterized by the presence of quartz, amorphous silica, feldspars and clay minerals. Based on the broad hump registered between 15 and 20° 2 theta on XRD patterns and on the characters and intensities of the bands centered around 3350 and 1630 cm-1 in the FTIR spectra, the amorphous silica from the diagenesis-affected diatom frustules was identified as opal-A. The associated mineral species are quartz (up to 5 wt.%), opal-Ct (up to 15 wt%), clay minerals (up to 60 wt.%), and minor feldspar (up to 20 wt.%). The micro-paleontological study shows that benthic pennate diatoms prevail (more than 60%), with a low rate of species diversity. Large chain-forming centric diatoms also occur together with other microfossils (dinoflagellates, phytolites, sponge spicules, different types of fish teeth) assemblages common for the Sarmatian (middle Miocene) marine deposits of Eastern Paratethys. The diatomaceous formation afforded exceptional fossilization. The diatom assemblages characterize a shallow marine basin environment, with littoral or freshwater contributions. Both at the basis and on the top of the profile, the marine diatoms prevail. At the basis of profile, the marine species (e.g., Actinocyclus ehrenbergii, Amphora crassa, Amphora crassa-punctata, Caloneis liber, Camylodiscus kutzingii, Grammatophora stricta, etc.) form up to 80 % of the rock volume, being associated with marine-brackish species such as Achnanthes brevipes and Cocconeis scutelum (up to 25 %) and with

Discussion of “Geology and diamond distribution of the 140/141 kimberlite, Fort à la Corne, central Saskatchewan, Canada”, by A. Berryman, B.H. Scott-Smith and B.C. Jellicoe (Lithos v. 76, p. 99 114)

Science.gov (United States)

Kjarsgaard, Bruce A.; Leckie, Dale A.; Zonneveld, John-Paul

2007-09-01

A wide variety of geological data and geological observations by numerous geoscientists do not support a two-stage crater excavation and in-fill model, or a champagne glass-shaped geometry for the 169 or 140/141 kimberlite bodies in the Fort à la Corne kimberlite field, Saskatchewan as described by Berryman, A., Scott Smith, B.H., Jellicoe, B., (2004). Rather, these kimberlite bodies are best described as polygenetic kimberlite tephra cones and tuff rings with associated feeder vents of variable geometry as shown by previous workers for the 169 kimberlite, the 140/141 kimberlite and the Star kimberlite. The domal tephra cone geometry is preserved due to burial by conformable Cretaceous marine mudstones and siltstones and is not an artifact of Quaternary glacial processes.

A desk study of surface diffusion and mass transport in clay

International Nuclear Information System (INIS)

Cook, A.J.

1988-09-01

The concept of a geological barrier to radionuclide migration from theoretical radioactive waste repositories has drawn attention to the physico-chemical properties of clays, which are traditionally regarded as retarding media. This report addresses the different mechanisms of transport of radionuclides through clay and in particular focuses on the surface diffusion movement of sorbed cations. The relative contributory importance of the different transport mechanisms is governed by the pore size distributions and interconnections within the clay fabric. Surface diffusion data in the literature have been from experiments using compacted montmorillonite and biotite gneiss. A possible programme of laboratory work is outlined, based on diffusion experiments, which describes the way of measuring the effect of surface diffusion more accurately in clays, mudstones and shales. (author)

El neopaleozoico de la Sierra de Castaño (Cordillera Frontal andina, San Juan, Argentina: Reconstrucción tectónica y paleoambiental The neopaleozoic of the Sierra de Castaño (Andean Cordillera Frontal, San Juan, Argentina: Tectonic and paleoenviromental reconstruction

Directory of Open Access Journals (Sweden)

Pedro Busquets

2013-01-01

ón andina. El más antiguo tuvo lugar próximo al límite Carbonífero-Pérmico, o durante el Pérmico más temprano. El segundo evento de deformación ocurrió hacia fines del Pérmico temprano y se correlaciona con la Fase Tectónica San Rafael, la que señala el inicio del importante volcanismo permotriásico (Grupo Choiyoi extensamente desarrollado a lo largo de la región andina.This paper addresses the stratigraphic analysis of the Late Paleozoic sequence outcroping in the Sierra de Castaño area (Cordillera Frontal, San Juan Province, Argentina. In this region three major stratigraphic units have been recognized. The lower one corresponds to the Cerro Agua Negra Formation (Late Carboniferous-Early Permian? composed of sandstones and mudstones, mainly deposited in shallow marine environments. The San Ignacio Formation (Early Permian covers unconformably the Cerro Agua Negra Formation and it is formed by conglomerates, breccias, sandstones, mudstones, stromatolitic limestones, volcanic and pyroclastic rocks. Three facies associations were recognized in the San Ignacio Formation. The lower (AFa is composed of breccias, conglomerates and lithic sandstones which were very probably deposited in alluvial and fluvial (braided systems that filled the irregular topography carved into the Cerro Agua Negra Formation. The facies association AFb, formed by conglomerates, sandstones and mudstones, characteristically develops metric-scale finning-upward cycles probably formed in high-sinuosity fluvial systems. Regarding the facies association AFc comprises stromatolitic limestones, mudstones, volcanics and pyroclastic rocks which are interpreted as deposited in shallow water bodies under recurrent volcanic activity. The San Ignacio Formation allows characterizing the transition from the prevolcanic sequences belonging to the Cerro Agua Negra Formation to the large volcanic activity represented in the Choiyoi Group (Middle Permian-Early Triassic. Moreover the analyzed sequence

On the water saturation calculation in hydrocarbon sandstone reservoirs

Energy Technology Data Exchange (ETDEWEB)

Stalheim, Stein Ottar

2002-07-01

The main goal of this work was to identify the most important uncertainty sources in water saturation calculation and examine the possibility for developing new S{sub w} - equations or possibility to develop methods to remove weaknesses and uncertainties in existing S{sub w} - equations. Due to the need for industrial applicability of the equations we aimed for results with the following properties: The accuracy in S{sub w} should increase compared with existing S{sub w} - equations. The equations should be simple to use in petrophysical evaluations. The equations should be based on conventional logs and use as few as possible input parameters. The equations should be numerical stable. This thesis includes an uncertainty and sensitivity analysis of the most common S{sub w} equations. The results are addressed in chapter 3 and were intended to find the most important uncertainty sources in water saturation calculation. To increase the knowledge of the relationship between R{sub t} and S{sub w} in hydrocarbon sandstone reservoirs and to understand how the pore geometry affects the conductivity (n and m) of the rock a theoretical study was done. It was also an aim to examine the possibility for developing new S{sub w} - equations (or investigation an effective medium model) valid inhydrocarbon sandstone reservoirs. The results are presented in paper 1. A new equation for water saturation calculation in clean sandstone oil reservoirs is addressed in paper 2. A recommendation for best practice of water saturation calculation in non water wet formation is addressed in paper 3. Finally a new equation for water saturation calculation in thinly interbedded sandstone/mudstone reservoirs is presented in paper 4. The papers are titled: 1) Is the saturation exponent n a constant. 2) A New Model for Calculating Water Saturation In 3) Influence of wettability on water saturation modeling. 4) Water Saturation Calculations in Thinly Interbedded Sandstone/mudstone Reservoirs. A

Structural Evolution of Kerogen and Bitumen during Thermal Maturation examined by Fourier-Transform Infrared Spectroscopy

Science.gov (United States)

Craddock, P. R.; Le Doan, T. V.; Pomerantz, A.

2014-12-01

Kerogen—the organic matter that is solid and insoluble in organic solvents—is a key component of organic-rich mudstones. The composition of kerogen affects the storage and transport of hydrocarbons in these unconventional resources and is known to change with thermal maturity. We report here using FTIR spectroscopy, the compositional characteristics of kerogen as a function of thermal maturity, together with the compositional characteristics of the organic phase, bitumen—the organic matter that is solid, but soluble in organic solvents. Kerogen is consumed during thermal maturation, whereas bitumen is an intermediary formed at low maturity from kerogen and consumed at higher maturities in formation of oil and gas. Bitumen relative to kerogen has higher aliphatic content, lower aromatic content, and lower abundance of oxygenated functions. At low maturity (vitrinite reflectance equivalent VRe ~ 0.5-0.9 %), the average length of aliphatic chains in bitumen increases during bitumen formation. At higher thermal maturities (VRe > 1.0-1.3 %), average aliphatic chain length decreases as bitumen is consumed. This evolution contrasts to that in kerogen, where aliphatic chain lengths shorten during all stages of maturation. Breakdown of kerogen appears to be driven by cleavage of oxygen functions at low maturity and removal of aliphatic carbons at higher maturities. These aliphatic-rich fragments may comprise the bitumen, and may in part explain the solubility of bitumen in organic solvents. Bitumen shows evidence of oxidation at low thermal maturity, a phenonemom not documented for kerogen. Bitumen maturation and degradation at higher thermal maturity is driven by cleavage and loss of aliphatic carbons, and is coincident with the maximum generation of oil and gas. The aromatic content of bitumen and of kerogen both increase during maturation as a consequence of the loss of aliphatic carbon. The oil and gas generation potential of the residual organic matter thus

Mineral Fractionation during Sediment Comminution and Transport in Fluvio-Deltaic and Lacustrine Rocks of the Bradbury Group, Gale Crater, Mars

Science.gov (United States)

Siebach, K. L.; Baker, M. B.; Grotzinger, J. P.; McLennan, S. M.; Gellert, R.; Thompson, L. M.; Hurowitz, J.

2017-12-01

Mineral distribution patterns in sediments of the Bradbury group in Gale crater, interpreted from observations by the Mars Science Laboratory rover Curiosity, show the importance of transport mechanics in source-to-sink processes on Mars. The Bradbury group is comprised of basalt-derived mudstones to conglomerates exposed along the modern floor of Gale crater and analyzed along a 9-km traverse of the Curiosity rover. Over 110 bulk chemistry analyses of the rocks were acquired, along with two XRD mineralogical analyses of the mudstone. These rocks are uniquely suited for analysis of source-to-sink processes because they exhibit a wide range of compositions, but (based on multiple chemical weathering proxies) they appear to have experienced negligible cation-loss during weathering and erosion. Chemical variations between analyses correlate with sediment grain sizes, with coarser-grained rocks enriched in plagioclase components SiO2, Al2O3, and Na2O, and finer-grained rocks enriched in components of mafic minerals, consistent with grain-size sorting of mineral fractions during sediment transport. Further geochemical and mineralogical modeling supports the importance of mineral fractionation: even though the limited XRD data suggests that some fraction (if not all) of the rocks contain clays and an amorphous component, models show that 90% of the compositions measured are consistent with sorting of primary igneous minerals from a plagioclase-phyric subalkaline basalt (i.e., no corrections for cation-loss are required). The distribution of K2O, modeled as a potassium feldspar component, is an exception to the major-element trends because it does not correlate with grain size, but has an elevation-dependent signal likely correlated with the introduction of a second source material. However, the dominant compositional trends within the Bradbury group sedimentary rocks are correlated with grain size and consistent with mineral fractionation of minimally

Stratigraphy and Folding in the Cenozoic Cover of a Fold-Thrust Belt in the Nallıhan Region (Ankara, Central Turkey)

Science.gov (United States)

Karaaǧaç, Serdal; Koral, Hayrettin

2017-04-01

This study investigates stratigraphy and structural features in the Cenozoic sedimentary sequence of the fold-thrust belt of the Nallıhan-Ankara region, located to the north of the İzmir-Ankara-Erzincan Suture Zone. Permian-Triassic age marble intercalated with schist-phyllites, the upper Jurassic-lower Cretaceous age limestone and the upper Cretaceous age sandstone-shale alternation compose the basement in the study area. These rocks are unconformably overlain by the Cenozoic age terrestrial sedimentary and volcanic units. The Cenozoic stratigraphy begins with the Paleocene-Eocene age coal-bearing, at times, volcanic intercalated conglomerate-sandstone-mudstone alternation of alluvial-fluvial origins (Aksaklar Formation) and the tuff intercalated with lacustrine limestone, bituminous limestone (Kabalar Formation). These units are conformably overlain by the Eocene age basalt-andesite and pyroclastic rocks (Meyildere volcanics). The Paleocene-Eocene aged units are unconformably overlain by the conglomerate-sandstone-mudstone-marl of a lower-middle Miocene lacustrine environment (Hançili Formation). The terrestrial conglomerate-sandstone alternation (Örencik Formation) is the youngest unit in the Cenozoic stratigraphy, and is assumed to be of Pliocene age based its stratigraphic position on older units. Field study shows existence of both folds and faults in the sedimentary cover. Stereographic projections of bedding measured in the field shows N25W/45NW and N60W/4SE-oriented fold axes in the Paleocene-Eocene age units. There are also N76W/12SE and N88E/8NE-oriented folds. The difference in fold-axis orientations suggests that some folds may have been rotated in blocks bound by faults during the post-Paleocene/Eocene period. Whereas, the lower-middle Miocene units manifest N88W/13SE-oriented fold axes. It is thus proposed that the observed difference in the azimuth of fold axes represent two different folding phases, one with NE-SW and the other with N

Cover sequences at the northern margin of the Antongil Craton, NE Madagascar

Science.gov (United States)

Bauer, W.; Walsh, G.J.; De Waele, B.; Thomas, Ronald J.; Horstwood, M.S.A.; Bracciali, L.; Schofield, D.I.; Wollenberg, U.; Lidke, D.J.; Rasaona, I.T.; Rabarimanana, M.H.

2011-01-01

The island of Madagascar is a collage of Precambrian, generally high-grade metamorphic basement domains, that are locally overlain by unmetamorphosed sedimentary rocks and poorly understood low-grade metasediments. In the Antalaha area of NE Madagascar, two distinct cover sequences rest on high-grade metamorphic and igneous basement rocks of the Archaean Antongil craton and the Neoproterozoic Bemarivo belt. The older of these two cover sequences, the Andrarona Group, consists of low-grade metasedimentary rocks. The younger sequence, the newly defined Ampohafana Formation, consists of unmetamorphosed sedimentary rocks. The Andrarona Group rests on Neoarchaean granites and monzogranites of the Antongil craton and consists of a basal metagreywacke, thick quartzites and an upper sequence of sericite-chlorite meta-mudstones, meta-sandstones and a volcaniclastic meta-sandstone. The depositional age of the volcaniclastic meta-sandstone is constrained in age by U–Pb laser-ablation ICP-MS analyses of euhedral zircons to 1875 ± 8 Ma (2σ). Detrital zircons of Archaean and Palaeoproterozoic age represent an input from the Antongil craton and a newly defined Palaeoproterozoic igneous unit, the Masindray tonalite, which underlies the Andrarona Group, and yielded a U–Pb zircon age of 2355 ± 11 Ma (2σ), thus constraining the maximum age of deposition of the basal part of the Andrarona Group. The Andrarona Group shows a low-grade metamorphic overprint in the area near Antalaha; illite crystallinity values scatter around 0.17°Δ2Θ CuKα, which is within the epizone. The Ampohafana Formation consists of undeformed, polymict conglomerate, cross-bedded sandstone, and red mudstone. An illite crystallinity value of >0.25°Δ2Θ CuKα obtained from the rocks is typical of the diagenetic zone. Occurrences of rhyodacite pebbles in the Ampohafana Formation and the intrusion of a basaltic dyke suggest a deposition in a WSW-ENE-trending graben system during the opening of the Indian

Stratigraphy and paleontology of Lower Permian rocks north of Cananea, northern Sonora, Mexico

Science.gov (United States)

Blodgett, R.B.; Moore, T.E.; Gray, F.

2002-01-01

Lower Permian carbonate and overlying red bed clastic rocks are present in a 2 km2 stratigraphic window in the vicinity of Rancho La Cueva, Santa Cruz sheet (scale 1:50,000), northern Sonora, Mexico. This exposure lies unconformably beneath predominantly intermediate Upper Cretaceous volcanics yielding 40Ar/39Ar ages of 73.4?? 0.18 and 71.1 ?? 0.35 Ma. The lower part of the Permian succession consists of light- to medium-gray colored limestones of the Colina Limestone, with a minimum thickness of 235 m. Sedimentary features suggest shallow water, slightly restricted depositional environments. Although lacking observable fossils for the most part, two intervals of richly fossiliferous, silicified shell beds are present near the base and top of the Colina Limestone. The lower fauna consist mostly of gastropods and bivalves. The presence of a new microdomatid gastropod species. Glyptospira sonorensis n. sp., close to Glytospira arelela Plas, suggests a late Wolfcampian age for this horizon. The upper fauna are predominantly molluscan dominated (gastropods and bivalves), but some brachiopods (productids and the rhynchonellid genus Pontisia) are also present. Gastropod genera include Bellerophon, Warthia, Euomphalus (represented by the species, Euomphalus kaibabensis Chronic), Baylea, Worthenia, Naticopsis, Goniasma, Kinishbia, Cibecuia, and Glyptospira. The gastropods suggest a Leonardian (late Early Permian) age for this horizon, and many of the species have previously been recorded from the Supai Group and Kaibab Formation of northern and central Arizona. The Colina Limestone is conformably overlain by 11.2 m of light-gray lime mudstone and dolostone, assigned here to the Epitaph Dolomite, which in turn is succeeded by 58.8 m of red-colored sandstone and gray lime mudstone, assigned here to the Scherrer Formation. This Lower Permian succession is significant because it further strengthens the stratigraphic ties of southeastern Arizona rocks with those of northern

Three-dimensional characterization of microporosity and permeability in fault zones hosted in heterolithic succession

Science.gov (United States)

Riegel, H. B.; Zambrano, M.; Jablonska, D.; Emanuele, T.; Agosta, F.; Mattioni, L.; Rustichelli, A.

2017-12-01

The hydraulic properties of fault zones depend upon the individual contributions of the damage zone and the fault core. In the case of the damage zone, it is generally characterized by means of fracture analysis and modelling implementing multiple approaches, for instance the discrete fracture network model, the continuum model, and the channel network model. Conversely, the fault core is more difficult to characterize because it is normally composed of fine grain material generated by friction and wear. If the dimensions of the fault core allows it, the porosity and permeability are normally studied by means of laboratory analysis or in the other case by two dimensional microporosity analysis and in situ measurements of permeability (e.g. micro-permeameter). In this study, a combined approach consisting of fracture modeling, three-dimensional microporosity analysis, and computational fluid dynamics was applied to characterize the hydraulic properties of fault zones. The studied fault zones crosscut a well-cemented heterolithic succession (sandstone and mudstones) and may vary in terms of fault core thickness and composition, fracture properties, kinematics (normal or strike-slip), and displacement. These characteristics produce various splay and fault core behavior. The alternation of sandstone and mudstone layers is responsible for the concurrent occurrence of brittle (fractures) and ductile (clay smearing) deformation. When these alternating layers are faulted, they produce corresponding fault cores which act as conduits or barriers for fluid migration. When analyzing damage zones, accurate field and data acquisition and stochastic modeling was used to determine the hydraulic properties of the rock volume, in relation to the surrounding, undamaged host rock. In the fault cores, the three-dimensional pore network quantitative analysis based on X-ray microtomography images includes porosity, pore connectivity, and specific surface area. In addition, images were

Deposition of Boron in Possible Evaporite Deposits in Gale Crate

Science.gov (United States)

Gasda, P. J.; Peets, E.; Lamm, S. N.; Rapin, W.; Lanza, N.; Frydenvang, J.; Clark, B. C.; Herkenhoff, K. E.; Bridges, J.; Schwenzer, S. P.; Haldeman, E. B.; Wiens, R. C.; Maurice, S.; Clegg, S. M.; Delapp, D.; Sanford, V.; Bodine, M. R.; McInroy, R.

2017-12-01

Boron has been previously detected in Gale crater using the ChemCam instrument on board the NASA Curiosity rover within calcium sulfate fracture fill hosted by lacustrine mudstone and eolian sandstone units. Recent results show that up to 300 ppm B is present in the upper sections of the lacustrine unit. Boron has been detected in both the groundwater-emplaced calcium sulfate fracture fill materials and bedding-parallel calcium sulfate layers. The widespread bedding-parallel calcium sulfate layers within the upper strata of the lacustrine bedrock that Curiosity has encountered recently could be interpreted as primary evaporite deposits. We have two hypotheses for the history of boron in Gale crater. In both hypotheses, borates were first deposited as lake water evaporated, depositing primary evaporates that were later re-dissolved by groundwater, which redistributed the boron into secondary evaporitic calcium sulfate fracture fill deposits. In the first scenario, Gale crater may have undergone a period of perennial lake formation during a drier period of martian history, depositing layers of evaporitic minerals (including borates) among lacustrine mudstone layers. In the second scenario, lake margins could have become periodically exposed during cyclic drops in lake level and subsequently desiccated. Evaporites were deposited and desiccation features were formed in lowstand deposits. Either hypothetical scenario of evaporite deposition would promote prebiotic chemical reactions via wet-dry cycles. Boron may be an important prebiotic element, and as such, its presence in ancient martian surface and groundwater provides evidence that important prebiotic chemical reactions could occur on Mars if organics were present. The presence of boron in ancient Gale crater groundwater also provides additional evidence that a habitable environment existed in the martian subsurface well after the expected disappearance of liquid water on the surface of Mars. We will report on the

Herbicide residues in grapes and wine.

Science.gov (United States)

Ying, G G; Williams, B

1999-05-01

The persistence of several common herbicides from grapes to wine has been studied. Shiraz, Tarrango and Doradillo grapes were separately sprayed with either norflurazon, oxyfluorfen, oxadiazon or trifluralin-persistent herbicides commonly used for weed control in vineyards. The dissipation of the herbicides from the grapes was followed for 28 days following treatment. Results showed that norflurazon was the most persist herbicide although there were detectable residues of all the herbicides on both red and white grapes at the end of the study period. The penetration of herbicides into the flesh of the grapes was found to be significantly greater for white grapes than for red grapes. Small-lot winemaking experiments showed that norflurazon persisted at levels close to the initial concentration through vinification and into the finished wine. The other herbicides degraded, essentially via first-order kinetics, within the period of "first fermentation" and had largely disappeared after 28 days. The use of charcoal together with filter pads, or with diatomaceous earth was shown to be very effective in removing herbicide residues from the wine. A 5% charcoal filter removed more than 96% of the norflurazon persisting in the treated wine.

131I levels in cow's milk following ingestion of contaminated alfalfa or sudan grass

International Nuclear Information System (INIS)

Black, S.C.; Stanley, R.E.; Barth, D.S.

1975-08-01

A dry aerosol, consisting of submicrometer diatomaceous earth particles tagged with 131 I, was released over two different types of growing forage (alfalfa and Sudan grass) at the Experimental Dairy Farm on the Nevada Test Site. Following deposition of the aerosol, the two forage types were chopped and fed to different groups of lactating dairy cows. The dual objectives of the study were to evaluate the relationship of 131 I secretion in milk to the ingestion of different types of contaminated forage and to obtain a further indication of the possible influence on milk radioiodine levels of changing the particle size of the contaminant. The ratios of the peak activity concentrations measured in the milk to the peak activity concentrations in the forage were computed to be 0.0145 for the cows fed contaminated alfalfa and 0.0082 for those fed contaminated Sudan grass. Comparison of the results from this study with those from earlier studies indicates the major effect on activity levels in the milk can be related to forage type. Ingestion of Sudan grass by the cow reduces the transfer of radioiodine to milk by one half compared to ingestion of alfalfa. (U.S.)

Analysis of azaarenes in pan fried meat and its gravy by liquid chromatography with fluorescence detection.

Science.gov (United States)

Błaszczyk, Urszula; Janoszka, Beata

2008-07-01

A method for analysis of six azaarenes (benzo[h]quinoline, benzo[a]acridine, benzo[c]acridine, dibenzo[a,c]acridine, dibenzo[a,j]acridine and dibenzo[a,h]acridine) in thermally treated high-protein food has been described. The clean-up procedure used based on alkaline hydrolysis, tandem solid phase extraction on columns filled with Extrelut - diatomaceous earth and cation exchanger (propyl sulfonic acid), enabled a selective isolation of carcinogenic compounds belonging to benzoacridines and dibenzoacridines from samples of cooked meat and its gravy. The isolated fractions of aza-PAHs were analysed by high-performance liquid chromatography with fluorescence detection. The detection limits for the azaarenes were between 0.0001ng and 0.005ng loaded on column. The recoveries for the four-ring and five-ring azaarenes were from 55% to 67%. Two types of dishes prepared from pork by pan-frying were investigated. Total contents of the benzoacridines and dibenzoacridines determined in cooked meat were 1.57 and 2.50ng/g in collar and chop samples, respectively; their gravies contained 0.34 and 0.59ng of these azaarenes per g of cooked meat. Copyright © 2007 Elsevier Ltd. All rights reserved.

Solidification of oils and organic liquids

International Nuclear Information System (INIS)

Clark, D.E.; Colombo, P.; Neilson, R.M. Jr.

1982-07-01

The suitability of selected solidification media for application in the disposal of low-level oil and other organic liquid wastes has been investigated. In the past, these low-level wastes (LLWs) have commonly been immobilized by sorption onto solid absorbents such as vermiculite or diatomaceous earth. Evolving regulations regarding the disposal of these materials encourage solidification. Solidification media which were studied include Portland type I cement; vermiculite plus Portland type I cement; Nuclear Technology Corporation's Nutek 380-cement process; emulsifier, Portland type I cement-sodium silicate; Delaware Custom Materiel's cement process; and the US Gypsum Company's Envirostone process. Waste forms have been evaluated as to their ability to reliably produce free standing monolithic solids which are homogeneous (macroscopically), contain < 1% free standing liquids by volume and pass a water immersion test. Solidified waste form specimens were also subjected to vibratory shock testing and flame testing. Simulated oil wastes can be solidified to acceptable solid specimens having volumetric waste loadings of less than 40 volume-%. However, simulated organic liquid wastes could not be solidified into acceptable waste forms above a volumetric loading factor of about 10 volume-% using the solidification agents studied

Clean-up of aqueous acetone vegetable extracts by solid-matrix partition for pyrethroid residue determination by gas chromatography-electron-capture detection.

Science.gov (United States)

Di Muccio, A; Barbini, D A; Generali, T; Pelosi, P; Ausili, A; Vergori, F; Camoni, I

1997-03-21

Disposable, ready-to-use cartridges filled with macroporous diatomaceous material are used to carry out a partition clean-up that, in a single step, is capable of transferring pesticide residues from aqueous acetone extracts into light petroleum-dichloromethane (75:25, v/v). This procedure takes the place of some functions (such as separatory-funnel partition, drying over anhydrous sodium sulphate and partial adsorption clean-up) usually performed by separate steps in classical schemes. Fourteen pyrethroid pesticides, including tefluthrin, tetramethrin, cyphenothrin, cyfluthrin, flucythrinate, tau-fluvalinate, deltamethrin, bioallethrin, fenpropathrin, lambda-cyhalothrin, permethrin, alpha-cypermethrin, esfenvalerate and tralomethrin were determined using the described procedure with satisfactory recoveries for most of them, at spiking levels ranging from 0.08 to 0.82 mg/kg for the different compounds. Crops subjected to the described procedure included strawberry, apple, and orange gave extracts containing a mass of co-extractives that was between 5 and 30 mg. Compared with classical schemes, the described procedure is simple, less labour intensive, allows parallel handling of several extracts and does not require the preparation and maintenance of equipment. Troublesome emulsions such as those frequently observed in separation funnel partitioning do not occur.

Cationic amino acids specific biomimetic silicification in ionic liquid: a quest to understand the formation of 3-D structures in diatoms.

Directory of Open Access Journals (Sweden)

Rajesh Ramanathan

Full Text Available The intricate, hierarchical, highly reproducible, and exquisite biosilica structures formed by diatoms have generated great interest to understand biosilicification processes in nature. This curiosity is driven by the quest of researchers to understand nature's complexity, which might enable reproducing these elegant natural diatomaceous structures in our laboratories via biomimetics, which is currently beyond the capabilities of material scientists. To this end, significant understanding of the biomolecules involved in biosilicification has been gained, wherein cationic peptides and proteins are found to play a key role in the formation of these exquisite structures. Although biochemical factors responsible for silica formation in diatoms have been studied for decades, the challenge to mimic biosilica structures similar to those synthesized by diatoms in their natural habitats has not hitherto been successful. This has led to an increasingly interesting debate that physico-chemical environment surrounding diatoms might play an additional critical role towards the control of diatom morphologies. The current study demonstrates this proof of concept by using cationic amino acids as catalyst/template/scaffold towards attaining diatom-like silica morphologies under biomimetic conditions in ionic liquids.

Egyptian diatomite as high fluid loss squeeze slurry in sealing fractures and

Directory of Open Access Journals (Sweden)

A.M. Al-Sabagh

2016-09-01

Full Text Available Lost circulation is the most costly mud related drilling problem, and induced fracture. Water slurry of diatomite is used as the high fluid loss squeeze slurry in the treatment of lost circulation and in decreasing fluid loss. Egypt has diatomite deposits, especially in El-Fayuom Depression. Fourteen samples were collected from Qasr El-Sagha at the northern shore of Birket Qarun. Samples were examined to identify the diatom species then subjected to X-ray fluorescence, XRD and grain size distribution tests. A total of 38 species related to 13 diatom genera were identified. Cocconeis, Epithemia and Rhopalodia were the predominant genera. The diatomaceous earth which acts as a filter aid material was tested with different additives; bentonite, lime, finely divided paper, polymer, barite and different concentrations with different types of lost circulation materials (LCM to form a high fluid loss squeeze slurry. As a result the required time for collecting the filtrate was decreased to be in the range of 50 s to 1 min and 49 s comparing with the international standard which recommended the filtrate should be collected maximum within 2–3 min.

Diatomite Photonic Crystals for Facile On-Chip Chromatography and Sensing of Harmful Ingredients from Food

Directory of Open Access Journals (Sweden)

Xianming Kong

2018-03-01

Full Text Available Diatomaceous earth—otherwise called diatomite—is essentially composed of hydrated biosilica with periodic nanopores. Diatomite is derived from fossilized remains of diatom frustules and possesses photonic-crystal features. In this paper, diatomite simultaneously functions as the matrix of the chromatography plate and the substrate for surface-enhanced Raman scattering (SERS, by which the photonic crystal-features could enhance the optical field intensity. The on-chip separation performance of the device was confirmed by separating and detecting industrial dye (Sudan I in an artificial aqueous mixture containing 4-mercaptobenzoic acid (MBA, where concentrated plasmonic Au colloid was casted onto the analyte spot for SERS measurement. The plasmonic-photonic hybrid mode between the Au nanoparticles (NP and the diatomite layer could supply nearly 10 times the increment of SERS signal (MBA intensity compared to the common silica gel chromatography plate. Furthermore, this lab-on-a-chip photonic crystal device was employed for food safety sensing in real samples and successfully monitored histamine in salmon and tuna. This on-chip food sensor can be used as a cheap, robust, and portable sensing platform for monitoring for histamine or other harmful ingredients at trace levels in food products.

Facile Preparation of Nano-Bi₂MoO₆/Diatomite Composite for Enhancing Photocatalytic Performance under Visible Light Irradiation.

Science.gov (United States)

Cai, Lu; Gong, Jiuyan; Liu, Jianshe; Zhang, Hailong; Song, Wendong; Ji, Lili

2018-02-09

In this work, a new nano-Bi₂MoO₆/diatomite composite photocatalyst was successfully synthesized by a facile solvothermal method. Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and UV-vis diffuse reflection spectroscopy (DRS) were employed to investigate the morphology, crystal structure, and optical properties. It was shown that nanometer-scaled Bi₂MoO₆ crystals were well-deposited on the surface of Bi₂MoO₆/diatomite. The photocatalytic activity of the obtained samples was evaluated by the degradation of rhodamine B (RhB) under the visible light (λ > 420 nm) irradiation. Moreover, trapping experiments were performed to investigate the possible photocatalytic reaction mechanism. The results showed that the nano-Bi₂MoO₆/diatomite composite with the mass ratio of Bi₂MoO₆ to diatomaceous earth of 70% exhibited the highest activity, and the RhB degradation efficiency reached 97.6% within 60 min. The main active species were revealed to be h⁺ and•O 2- . As a photocatalytic reactor, its recycling performance showed a good stability and reusability. This new composite photocatalyst material holds great promise in the engineering field for the environmental remediation.

Diatomite Photonic Crystals for Facile On-Chip Chromatography and Sensing of Harmful Ingredients from Food.

Science.gov (United States)

Kong, Xianming; Yu, Qian; Li, Erwen; Wang, Rui; Liu, Qing; Wang, Alan X

2018-03-31

Diatomaceous earth-otherwise called diatomite-is essentially composed of hydrated biosilica with periodic nanopores. Diatomite is derived from fossilized remains of diatom frustules and possesses photonic-crystal features. In this paper, diatomite simultaneously functions as the matrix of the chromatography plate and the substrate for surface-enhanced Raman scattering (SERS), by which the photonic crystal-features could enhance the optical field intensity. The on-chip separation performance of the device was confirmed by separating and detecting industrial dye (Sudan I) in an artificial aqueous mixture containing 4-mercaptobenzoic acid (MBA), where concentrated plasmonic Au colloid was casted onto the analyte spot for SERS measurement. The plasmonic-photonic hybrid mode between the Au nanoparticles (NP) and the diatomite layer could supply nearly 10 times the increment of SERS signal (MBA) intensity compared to the common silica gel chromatography plate. Furthermore, this lab-on-a-chip photonic crystal device was employed for food safety sensing in real samples and successfully monitored histamine in salmon and tuna. This on-chip food sensor can be used as a cheap, robust, and portable sensing platform for monitoring for histamine or other harmful ingredients at trace levels in food products.

Modeling Permeability Alteration in Diatomite Reservoirs During Steam Drive, SUPRI TR-113

Energy Technology Data Exchange (ETDEWEB)

Bhat, Suniti Kumar; Kovscek, Anthony R.

1999-08-09

There is an estimated 10 billion barrels of original oil in place (OOIP) in diatomaceous reservoirs in Kern County, California. These reservoirs have low permeability ranging from 0.1 to 10 mD. Injection pressure controlled steam drive has been found to be an effective way to recover oil from these reservoir. However, steam drive in these reservoirs has its own complications. The rock matrix is primarily silica (SiO2). It is a known fact that silica is soluble in hot water and its solubility varies with temperature and pH. Due to this fact, the rock matrix in diatomite may dissolve into the aqueous phase as the temperature at a location increases or it may precipitate from the aqueous phase onto the rock grains as the temperature decreases. Thus, during steam drive silica redistribution will occur in the reservoir along with oil recovery. This silica redistribution causes the permeability and porosity of the reservoir to change. Understanding and quantifying these silica redistribution effects on the reservoir permeability might prove to be a key aspect of designing a steam drive project in these formations.

Preliminary environmental analysis of Gondwana in Candiota Region, Rio Grande do Sul

International Nuclear Information System (INIS)

Silveira Fontes, L.C. da; Cava, L.T.

1980-10-01

The geological results obtained in the Candiota Region by NUCLEBRAS, during the evaluation of the uranium economic potential from basal Gondwana Sequence - Itarare Group and Rio Bonito Formation - at South-East of the Parana Sedimentary Basin, are studied. The analysis of 18 geologic sections (scales 1:5.000 x 1:500), 21 drill holes and fotogeologic interpretation in the scale 1:50.000, are included. The Itarare Group sedimentation was conditioned by paleo - relief with valleys formed from differential erosion on 'horst - graben' structures. The deposition of its rhythmites, diamictites and siltstones was made in periglacial and marine environments. The sedimentation of the Rio Bonito Formation is related to the main Itarare Group depositional axes. The typical lithologies are: sandstones, siltstones, mudstones and coals, representing progradational fluvial sediments over coastal - plain areas. (Author) [pt

The Imprint of Atmospheric Evolution in the D/H of Hesperian Clay Minerals on Mars

Science.gov (United States)

Mahaffy, P. R.; Webster, C. R.; Stern, J. C.; Brunner, A. E.; Atreya, S. K.; Conrad, P. G.; Domagal-Goldman, S.; Eigenbrode, J. L.; Flesch, G. J.; Christensen, L. E.;

Controls on upper Campanian-Maastrichtian chalk deposition in the eastern Danish Basin

DEFF Research Database (Denmark)

Boussaha, Myriam; Thibault, Nicolas Rudolph; Anderskouv, Kresten

2017-01-01

% of the sediment. Sedimentation took place in deep water, below the photic zone and storm-wave base, and is characterized by decimetre to metre-scale variations in facies and trace fossil assemblages indicating repeated shifts in depositional environment. Integration of facies with published data on sea...... of accumulation rates and sea temperatures and is interpreted to represent a very broad set of deep water environmental conditions with an ample supply of calcareous nannofossil debris and intense bioturbation. Longer term shifts in deposition are best expressed by distribution of clay, flint and bioturbated...... micro-wackestone, bioturbated wackestone and laminated mudstone chalk facies, whereas the trace fossil assemblages appear less useful. The data set indicates overall shallowing over time with two distinctive events of clay influx to the basin during the late Campanian-earliest Maastrichtian and late...

Terahertz lens made out of natural stone.

Science.gov (United States)

Han, Daehoon; Lee, Kanghee; Lim, Jongseok; Hong, Sei Sun; Kim, Young Kie; Ahn, Jaewook

2013-12-20

Terahertz (THz) time-domain spectroscopy probes the optical properties of naturally occurring solid aggregates of minerals, or stones, in the THz frequency range. Refractive index and extinction coefficient measurement reveals that most natural stones, including mudstone, sandstone, granite, tuff, gneiss, diorite, slate, marble, and dolomite, are fairly transparent for THz frequency waves. Dolomite in particular exhibits a nearly uniform refractive index of 2.7 over the broad frequency range from 0.1 to 1 THz. The high index of refraction allows flexibility in lens designing with a shorter accessible focal length or a thinner lens with a given focal length. Good agreement between the experiment and calculation for the THz beam profile confirms that dolomite has high homogeneity as a lens material, suggesting the possibility of using natural stones for THz optical elements.

Preliminary data on dinosaurs habitat during the Upper Maastrichtian, Hateg Basin, Romania

International Nuclear Information System (INIS)

Grigorescu, D.; Klarik, L.; Bojar, A.-V.

2002-01-01

The Hateg basin is located in the south-western part of the Transylvanian Depression and it is filled with sediments that overly the crystalline rocks of the Getic nappe. The basin show multiple stage of Mesozoic evolution. The Latest Cretaceous (Middle and Upper Maastrichtian) with continuous transition to Paleocene is represented by two continental lithostratigraphic units: the Densus-Ciula and the Sinpetru Formations. The Upper Maastrichtian of Densus-Ciula Formation at Tustea Quarry is represented by a pebbly alluvium with massive, matrix supported conglomerates, cross bedded sandstones and mudstones, the last one containing calcretes and dinosaur remains, including eggs and hatchlings of the hadrosaurid Telmatosaurus transsylvanicus. In order to constrain the paleoenvironment in which dinosaurs lived, calcretes and dinosaur eggshells were analyzed for carbon and oxygen isotopic composition

Geology and ground water in north-central Santa Cruz County, California

Science.gov (United States)

Johnson, Michael J.

1980-01-01

North-central Santa Cruz County is underlain mainly by folded sedimentary rocks of Tertiary and Cretaceous age that have been highly fractured by movements in the San Andreas fault system. Ground water is stored in fractures within shale and mudstone formations and in intergranular pore spaces within fine- to very fine-grained sandstone and siltstone formations. Fewer than 10% of the wells yield more than 15 gallons of water per minute. The water in most wells is moderately hard to very hard, is generally of a sodium bicarbonate or calcium bicarbonate type, and commonly has excessive concentrations of iron or manganese. Of the many geologic units in the study area, only the Purisima Formation of Pliocene age has the potential to sustain well yields greater than 100 gallons per minute. (USGS)

Uranium in the Bunter sediments of the Polish area

International Nuclear Information System (INIS)

Saldan, M.; Strzelecki, R.

1980-01-01

Uranium mineralization occurring in the Triassic sediments in the Polish area is discussed. Systematic work conducted for over ten years revealed the presence of uranium mineralization in the following geological units: Peribaltic syneclize, Fore-Sudetic monocline, Zary pericline and Pomerania trough. Out of three uranium-bearing horizons which can be correlated with each other two (the lower and the middle) are connected with the Middle Bunter, while the upper horizon is related to the Upper Bunter. Mineralization was found in sandstones, conglomerates, mudstones and claystones and, in the Fore-Sudetic monocline, also in carbonates. Among uranium minerals uranium black and coffinite were identified. In addition to uranium, increased vanadium, selenium and molybdenum contents were found in the sandstones. Some of the uranium-bearing horizons are of economic value. (author)

Differential early diagenetic low-Mg calcite cementation and rhythmic hardground development in Campanian-Maastrichtian chalk

DEFF Research Database (Denmark)

Molenaar, Nicolaas; J.J.P., Zijlstra

1997-01-01

and differences in the degree of early diagenesis. Cemented layers and hardgrounds are the result of differential early marine calcite cementation. In these limestones early calcite cementation cannot be explained by the supply of cementing materials from saturated seawater, An alternative model for early marine......The Campanian-Maastrichtian limestones in the south of the Netherlands are well-sorted fine-grained mudstones and silt- to fine sand-sized bioclastic grainstones. These limestones show a distinct lithological cyclicity manifested by fining-upward grain-size cycles with calcite-cemented layers...... calcite cementation is proposed, in which early calcite cementation occurred within the sediment at some distance below the seafloor as a result of organic matter degradation and internal redistribution of bioclastic carbonate. Bacterial organic matter degradation caused dissolution of relatively unstable...

Paleogene Vertebrate Paleontology, Geology and Remote Sensing in the Wind River Basin

Science.gov (United States)

Stucky, R. K.; Krishtalka, L.

1985-01-01

Biostratigraphic and lithostratigraphic studies were used to correlate different events in the geologic evolution of the northeastern part of the Wind River Basin and have suggested several conclusions. Laterally equivalent exposures of the Lysite member from Cedar Ridge to Bridger Creek show a gradation in lithology from interbedded boulder conglomerates and sandstones to interbedded lenticular sandstones and mudstones to interbedded carbonaceous shales, coals and tabular sandstones. This gradation suggests a shift from alluvial fan to braided stream to paludal or lacustrine sedimentary environments during the late early Eocene. The Lysite and Lost Cabin members of the Wind River Formation are in fault contact in the Bridger Creek area and may intertongue to the east along Cedar Ridge. Ways in which remote sensing could be used in these studies are discussed.

The Paleoecology of Vegetation on Pennsylvanian Basin Margins

DEFF Research Database (Denmark)

Bashforth, Arden Roy

deposits are capped by log accumulations, many of which are overlain by abandoned channel mudstones.  It is proposed that flood sediment buildup and log jam development prompted avulsion and channel abandonment, thus providing some of the earliest evidence for the effects of large woody debris on fluvial...... settings.  Such landscapes were characterized by steep gradients and high-energy regimes due to their proximity to uplands, and the prevalence of coarse-grained sediment enhanced soil drainage and hindered peat accumulation. To help resolve the full spectrum of vegetation cover in tropical Euramerica...... on a fluvial megafan under strongly seasonal conditions, gigantic cordaitalean forests dominated the landscape, particularly alongside ephemeral channels.  Floodplains were largely dry and degraded, although pteridosperms, ferns, and lycopsids persisted around poorly drained depressions.  On the Nýrany Member...

Geologic History of Eocene Stonerose Fossil Beds, Republic, Washington, USA

Directory of Open Access Journals (Sweden)

George E. Mustoe

2015-07-01

Full Text Available Eocene lakebed sediments at Stonerose Interpretive Center in Republic, Washington, USA are one of the most important Cenozoic fossil sites in North America, having gained international attention because of the abundance and diversity of plant, insect, and fish fossils. This report describes the first detailed geologic investigation of this unusual lagerstätten. Strata are gradationally divided into three units: Siliceous shale that originated as diatomite, overlain by laminated mudstone, which is in turn overlain by massive beds of lithic sandstone. The sedimentary sequence records topographic and hydrologic changes that caused a deep lake to become progressively filled with volcaniclastic detritus from earlier volcanic episodes. The location of the ancient lake within an active graben suggests that displacements along the boundary faults were the most likely trigger for changes in depositional processes.

A model for Cryogenian iron formation

Science.gov (United States)

Cox, Grant M.; Halverson, Galen P.; Poirier, André; Le Heron, Daniel; Strauss, Justin V.; Stevenson, Ross

2016-01-01

The Neoproterozoic Tatonduk (Alaska) and Holowilena (South Australia) iron formations share many characteristics including their broadly coeval (Sturtian) ages, intimate association with glaciogenic sediments, and mineralogy. We show that these shared characteristics extend to their neodymium (εNd) and iron isotope (δ56Fe) systematics. In both regions δ56Fe values display a distinct up-section trend to isotopically heavier values, while εNd values are primitive and similar to non-ferruginous mudstones within these successions. The δ56Fe profiles are consistent with oxidation of ferruginous waters during marine transgression, and the εNd values imply that much of this iron was sourced from the leaching of continental margin sediments largely derived from continental flood basalts. Rare earth element data indicate a secondary hydrothermal source for this iron.

Preliminary data on dinosaurs habitat during the Upper Maastrichtian, Hateg Basin, Romania

Energy Technology Data Exchange (ETDEWEB)

Grigorescu, D; Klarik, L [University of Bucharest, Faculty of Geology and Geophysics (Romania); Bojar, A -V [Department of Geology and Paleontology, Graz (Austria)

2002-10-01

The Hateg basin is located in the south-western part of the Transylvanian Depression and it is filled with sediments that overly the crystalline rocks of the Getic nappe. The basin show multiple stage of Mesozoic evolution. The Latest Cretaceous (Middle and Upper Maastrichtian) with continuous transition to Paleocene is represented by two continental lithostratigraphic units: the Densus-Ciula and the Sinpetru Formations. The Upper Maastrichtian of Densus-Ciula Formation at Tustea Quarry is represented by a pebbly alluvium with massive, matrix supported conglomerates, cross bedded sandstones and mudstones, the last one containing calcretes and dinosaur remains, including eggs and hatchlings of the hadrosaurid Telmatosaurus transsylvanicus. In order to constrain the paleoenvironment in which dinosaurs lived, calcretes and dinosaur eggshells were analyzed for carbon and oxygen isotopic composition.

Characterization of the mechanical and hydraulic damage in the excavation damaged zone of MHM with gas permeability measurement

International Nuclear Information System (INIS)

Yang, D.

2008-09-01

On the feasibility evaluation of nuclear waste storage in deep formations, the essential issues are as follows: the stability of underground structures over the reversible period, the influence of cavity excavation on geomechanical properties of the wall rock and the variation of those properties during the different phases while storage realization. The work presented here covers the investigations on the variation of geomechanical properties of the approximately 500 m deep MHM in France (mudstone in the departments of Meuse/Haute-Marne), chosen as a potential medium for nuclear waste disposal by ANDRA. In order to measure the very low permeability of mudstone and to observe the dependency on saturation, a special test scheme on measurement of gas permeability has been developed. In the scheme, in situ referenced stresses have been chosen as the stresses acting on the solid matrix. The gas permeability has been determined with both analytical and numerical methods. To estimate the mechanical damage of storage induced by the excavation, laboratory tests on gas permeability have been conducted on samples recovered from different locations situated at different distances from the wall of the main access shaft of the MHM (from 0,1 m to 12,5 m). Results of gas permeability obtained under an isotropic stress of 11 MPa vary between 10 -21 and 10 -22 m 2 and do not show significant variations between damaged zones (near the wall) and intact zones (sample located 12 m from the wall). The observations in laboratory tests coincide with in situ damage characterizations. The variation of gas permeability under the cycle of loading and unloading is an order less than the initial value under the isotropic stress. Taking into account the precision of the testing system, this variation is not significant. The oviparous intact samples have been imposed different saturations by salt solutions (with a relative humidity from 25 % to 98 %) to form a cycle of de- and re-saturation. The

Diagenetic evolution and stable isotopes of Lower Permian platform marginal carbonates (Trogkofel Limestone, Carnic Alps, Austria)

Science.gov (United States)

Schaffhauser, Maria; Krainer, Karl; Sanders, Diethard Gerald; Spötl, Christoph

2010-05-01

The Trogkofel massif in the Carnic Alps, Austria/Italy, consists of a succession up to 400 m thick of limestones deposited along a platform margin (Trogkofel Limestone; Artinskian). The top of the Trogkofel Limestone is erosively overlain by the Tarvis Breccia. Up-section, the Trogkofel Limestone consists of well-bedded shallow-water bioclastic limestones with intercalated mud mounds, overlain by thick-bedded to unbedded limestones (bioclastic grainstones, packstones, rudstones) and cementstone mounds rich in phylloid algae, Tubiphytes, bryozoans and Archaeolithoporella. In the cementstone mounds, bioclasts are coated by thick fringes and botryoids of fibrous calcite, and of calcite spar that probably represents calcitized aragonite. Primary and intrinsic pores are filled by microbialite, and/or by mudstone to bioclastic wackestone. Shallow-water bioclastic grainstones are cemented by isopachous fringes of fibrous calcite, or by sparry calcite. Throughout the succession, evidence for meteoric-vadose dissolution is present. The Trogkofel Limestone is riddled by palaeokarstic dykes and caverns filled by (a) isopachous cement fringes up to a few decimetres thick, and/or (b) by red, geopetally-laminated lime mudstone to bio-lithoclastic wackestone; geopetal laminasets locally display convolute bedding. Small dissolution cavities are filled by grey internal sediment, or by crystal silt. Brecciated internal sediments overlain by unbrecciated, geopetally-laminated infillings record deformation during or after deposition of the Trogkofel Limestone. Polyphase fractures cemented by calcite may cross-cut both internal sediments and host rock. In the Trogkofel Limestone, local dolomitization is common. Replacement dolomites show a wide range of shapes and fabrics, including: (a) fine-crystalline anhedral xenotopic fabric, (b) coarse-crystalline subhedral to euhedral, hypidiotopic to idiotopic fabric of turbid or optically zoned crystals, and (c) saddle dolomite as replacement

Collision of the Tacheng block with the Mayile-Barleik-Tangbale accretionary complex in Western Junggar, NW China: Implication for Early-Middle Paleozoic architecture of the western Altaids

Science.gov (United States)

Zhang, Ji'en; Xiao, Wenjiao; Luo, Jun; Chen, Yichao; Windley, Brian F.; Song, Dongfang; Han, Chunming; Safonova, Inna

2018-06-01

Western Junggar in NW China, located to the southeast of the Boshchekul-Chingiz (BC) Range and to the north of the Chu-Balkhash-Yili microcontinent (CBY), played a key role in the architectural development of the western Altaids. However, the mutual tectonic relationships have been poorly constrained. In this paper, we present detailed mapping, field structural geology, and geochemical data from the Barleik-Mayile-Tangbale Complex (BMTC) in Western Junggar. The Complex is divisible into Zones I, II and III, which are mainly composed of Cambrian-Silurian rocks. Zone I contains pillow lava, siliceous shale, chert, coral-bearing limestone, sandstone and purple mudstone. Zone II consists of basaltic lava, siliceous shale, chert, sandstone and mudstone. Zone III is characterized by basalt, chert, sandstone and mudstone. These rocks represent imbricated ocean plate stratigraphy, which have been either tectonically juxtaposed by thrusting or form a mélange with a block-in-matrix structure. All these relationships suggest that the BMTC is an Early-Middle Paleozoic accretionary complex in the eastern extension of the BC Range. These Early Paleozoic oceanic rocks were thrust onto Silurian sediments forming imbricate thrust stacks that are unconformably overlain by Devonian limestone, conglomerate and sandstone containing fossils of brachiopoda, crinoidea, bryozoa, and plant stems and leaves. The tectonic vergence of overturned folds in cherts, drag-related curved cleavages and σ-type structures on the main thrust surface suggests top-to-the-NW transport. Moreover, the positive εNd(t) values of volcanic rocks from the Tacan-1 drill-core, and the positive εHf(t) values and post-Cambrian ages of detrital zircons from Silurian and Devonian strata to the south of the Tacheng block indicate that its basement is a depleted and juvenile lithosphere. And there was a radial outward transition from coral-bearing shallow marine (shelf) to deep ocean (pelagic) environments, and from

Investigation of the potential for concealed base-metal mineralization at the Drenchwater Creek Zn-Pb-Ag occurrence, northern Alaska, using geology, reconnaissance geochemistry, and airborne electromagnetic geophysics

Science.gov (United States)

Graham, Garth E.; Deszcz-Pan, Maria; Abraham, Jared E.; Kelley, Karen D.

2011-01-01

In 2005, the U.S. Geological Survey, Bureau of Land Management, and State of Alaska cooperated on an investigation of the mineral potential of a southern part of the National Petroleum Reserve in Alaska, Howard Pass quadrangle, to provide background information for future land-use decisions. The investigation incorporated an airborne electromagnetic (EM) survey covering 1,500 mi2 (~3,900 km2), including flight lines directly over the Drenchwater Creek sediment-hosted Zn-Pb-Ag occurrence, the largest known base-metal occurrence in the survey area. Samples from the mineralized outcrop and rubblecrop contain metal concentrations that can exceed 11 percent Zn+Pb, with appreciable amounts of Ag. Soil samples with anomalous Pb concentrations are distributed near the sulfide-bearing outcrops and along a >2.5 km zone comprising mudstone, shale, and volcanic rocks of the Kuna Formation.

Organic geochemistry and petrology of oil source rocks, Carpathian Overthrust region, southeastern Poland - Implications for petroleum generation

Science.gov (United States)

Kruge, M.A.; Mastalerz, Maria; Solecki, A.; Stankiewicz, B.A.

1996-01-01

The organic mailer rich Oligocene Menilite black shales and mudstones are widely distributed in the Carpathian Overthrust region of southeastern Poland and have excellent hydrocarbon generation potential, according to TOC, Rock-Eval, and petrographic data. Extractable organic matter was characterized by an equable distribution of steranes by carbon number, by varying amounts of 28,30-dinor-hopane, 18??(H)-oleanane and by a distinctive group of C24 ring-A degraded triterpanes. The Menilite samples ranged in maturity from pre-generative to mid-oil window levels, with the most mature in the southeastern portion of the study area. Carpathian petroleum samples from Campanian Oligocene sandstone reservoirs were similar in biomarker composition to the Menilite rock extracts. Similarities in aliphatic and aromatic hydrocarbon distributions between petroleum asphaltene and source rock pyrolyzates provided further evidence genetically linking Menilite kerogens with Carpathian oils.

Redox stratification of an ancient lake in Gale crater, Mars.

Science.gov (United States)

Hurowitz, J A; Grotzinger, J P; Fischer, W W; McLennan, S M; Milliken, R E; Stein, N; Vasavada, A R; Blake, D F; Dehouck, E; Eigenbrode, J L; Fairén, A G; Frydenvang, J; Gellert, R; Grant, J A; Gupta, S; Herkenhoff, K E; Ming, D W; Rampe, E B; Schmidt, M E; Siebach, K L; Stack-Morgan, K; Sumner, D Y; Wiens, R C

2017-06-02

In 2012, NASA's Curiosity rover landed on Mars to assess its potential as a habitat for past life and investigate the paleoclimate record preserved by sedimentary rocks inside the ~150-kilometer-diameter Gale impact crater. Geological reconstructions from Curiosity rover data have revealed an ancient, habitable lake environment fed by rivers draining into the crater. We synthesize geochemical and mineralogical data from lake-bed mudstones collected during the first 1300 martian solar days of rover operations in Gale. We present evidence for lake redox stratification, established by depth-dependent variations in atmospheric oxidant and dissolved-solute concentrations. Paleoclimate proxy data indicate that a transition from colder to warmer climate conditions is preserved in the stratigraphy. Finally, a late phase of geochemical modification by saline fluids is recognized. Copyright © 2017, American Association for the Advancement of Science.

Carbonate rock classification applied to brazilian sedimentary basins; Classificacao de rochas carbonaticas aplicavel as bacias sedimentares brasileiras

Energy Technology Data Exchange (ETDEWEB)

Terra, Gerson Jose Salamoni [Universidade Petrobras, Rio de Janeiro, RJ (Brazil). Escola de Ciencias e Tecnologias de Exploracao e Producao], E-mail: gersonterra@petrobras.com.br; Spadini, Adali Ricardo [Petrobras E e P, Rio de Janeiro, RJ (Brazil). Exploracao], E-mail: spadini@petrobras.com.br; Franca, Almerio Barros [Centro de Pesquisa e Desenvolvimento Leopoldo A. Miguez de Mello (CENPES), Rio de Janeiro, RJ (Brazil). Sedimentologia e Petrologia] (and others)

2009-11-15

A new classification of carbonate rocks is proposed seeking to cover the entire spectrum of their occurrence in Brazilian basins. Emphasis is given to those in oil exploration and production locations, especially since the discovery of giant oil fields in the so called Pre-Salt section. This classification is a synergy between the various existing classifications adapting or modifying some terms and introducing new names. The carbonate rocks were divided into four groups according to their depositional texture: 1) elements not bound during deposition (mudstone, wackestone, packstone, grainstone, floatstone, rudstone, bioaccumulated, breccia), 2) elements bound during deposition, or in situ (boundstone, stromatolite, arborescent stromatolite, arbustiform stromatolite, dendriform stromatolite, thrombolite, dendrolite, leiolite, spherulitite, travertine and tufa), 3) elements bound or not bound during deposition (laminite, smooth laminite, crenulated laminite); 4) unrecognized depositional texture (crystalline limestone, dolomite). (author)

Characterization of a lime-pozzolan plaster containing phase change material

International Nuclear Information System (INIS)

Pavlíková, Milena; Pavlík, Zbyšek; Trník, Anton; Pokorný, Jaroslav; Černý, Robert

2015-01-01

A PCM (Phase Change Material) modified lime-pozzolan plaster for improvement of thermal energy storage of building envelopes is studied in the paper. The investigated plaster is composed of lime hydrate, pozzolan admixture based on metakaolin and mudstone, silica sand, water and paraffin wax encapsulated in polymer capsule. The reference plaster without PCM application is studied as well. The analyzed materials are characterized by bulk density, matrix density, total open porosity, compressive strength and pore size distribution. The temperature of phase change, heat of fusion and crystallization are studied using DSC (Difference Scanning Calorimetry) analysis performed in air atmosphere. In order to get information on materials hygrothermal performance, determination of thermal and hygric properties is done in laboratory conditions. Experimental data reveal a substantial improvement of heat storage capacity of PCM-modified plaster as compared to the reference material without PCM

Sedimentary Facies of the West Crocker Formation North Kota Kinabalu-Tuaran Area, Sabah, Malaysia

Science.gov (United States)

Mohamed, Azfar; Hadi Abd Rahman, Abdul; Suhaili Ismail, Mohd

2016-02-01

Newly outcrops exposed in the West Crocker Formation have led to the detail sedimentolgical analysis of the formation. Eight sedimentary facies have been recognised in which it was divided into three main groups: (1) sand-dominated facies (F1-F2), (2) poorly- sorted unit mixed sand and mud-dominated facies (F3), and (3) mud-dominated facies (F4-F5). These are: F1- graded sandstone (massive to planar laminated), F2-ripple-cross laminated, wavy and convolute lamination sandstone, F3-chaotic beds of mixed sandstone and mudstone blocks and clasts, F4-lenticular bedded of sandstone, and F5-shale. The studies of the formation has come out that it was deposited in a sand-rich submarine fan with specific location located at (1) inner fan channel-levee complex; (2) mid-fan channelised lobes, and (3) outer fan.

Iron speciation and mineral characterization of upper Jurassic reservoir rocks in the Minhe Basin, NW China

Energy Technology Data Exchange (ETDEWEB)

Ma, Xiangxian; Zheng, Guodong, E-mail: gdzhbj@mail.iggcas.ac.cn; Xu, Wang [Chinese Academy of Sciences, Key Laboratory of Petroleum Resources, Gansu Province / Key Laboratory of Petroleum Resources Research, Institute of Geology and Geophysics (China); Liang, Minliang [Chinese Academy of Geological Sciences, Institute of Geomechanics, Key Lab of Shale Oil and Gas Geological Survey (China); Fan, Qiaohui; Wu, Yingzhong; Ye, Conglin [Chinese Academy of Sciences, Key Laboratory of Petroleum Resources, Gansu Province / Key Laboratory of Petroleum Resources Research, Institute of Geology and Geophysics (China); Shozugawa, Katsumi; Matsuo, Motoyuki [The University of Tokyo, Graduate School of Arts and Sciences (Japan)

2016-12-15

Six samples from a natural outcrop of reservoir rocks with oil seepage and two control samples from surrounding area in the Minhe Basin, northwestern China were selectively collected and analyzed for mineralogical composition as well as iron speciation using X-ray powder diffraction (XRD) and Mössbauer spectroscopy, respectively. Iron species revealed that: (1) the oil-bearing reservoir rocks were changed by water-rock-oil interactions; (2) even in the same site, there was a different performance between sandstone and mudstone during the oil and gas infusion to the reservoirs; and (3) this was evidence indicating the selective channels of hydrocarbon migration. In addition, these studies showed that the iron speciation by Mössbauer spectroscopy could be useful for the study of oil and gas reservoirs, especially the processes of the water-rock interactions within petroleum reservoirs.

Active silica sources in the Sele formation and quartz cementation in mudstone-Examples from the Siri Canyon, Danish North Sea

DEFF Research Database (Denmark)

Kazerouni, Afsoon Moatari; Friis, Henrik; Svendsen, Johan B.

shale to document the diagenetic steps which releases silica and to evaluate the possible timing of the silica export from the shale into neighbouring sandstones. The major silica mobilization occur at shallow depths, related to the transformation of biogenic opal and volcanic ash, and at intermediate...... depths, related to the dissolution of opal-CT and zeolite.  At these processes, the shale may have been active silica exported.  Reported sandstone cementation patterns indicate the earlier phase is related to major export of silica, whereas the shale itself was the major consumer during the intermediate...

Spatial Variability of Organic Carbon in a Fractured Mudstone and Its Effect on the Retention and Release of Trichloroethene (TCE)

Science.gov (United States)

Sole-Mari, G.; Fernandez-Garcia, D.

2016-12-01

Random Walk Particle Tracking (RWPT) coupled with Kernel Density Estimation (KDE) has been recently proposed to simulate reactive transport in porous media. KDE provides an optimal estimation of the area of influence of particles which is a key element to simulate nonlinear chemical reactions. However, several important drawbacks can be identified: (1) the optimal KDE method is computationally intensive and thereby cannot be used at each time step of the simulation; (2) it does not take advantage of the prior information about the physical system and the previous history of the solute plume; (3) even if the kernel is optimal, the relative error in RWPT simulations typically increases over time as the particle density diminishes by dilution. To overcome these problems, we propose an adaptive branching random walk methodology that incorporates the physics, the particle history and maintains accuracy with time. The method allows particles to efficiently split and merge when necessary as well as to optimally adapt their local kernel shape without having to recalculate the kernel size. We illustrate the advantage of the method by simulating complex reactive transport problems in randomly heterogeneous porous media.

Mineralogía de arcillas y nanofósiles calcáreos de las formaciones Jagüel y Roca en el sector oriental del lago Pellegrini, Cuenca Neuquina, República Argentina Clay mineralogy and calcareous nannofossils from Jagüel and Roca formations in the eastern sector of Pellegrini Lake, Neuquen Basin, República Argentina

Directory of Open Access Journals (Sweden)

Telma Musso

2012-09-01

hacia posiciones más altas del Daniano, lo cual podría indicar un clima cálido y más húmedo en este intervalo, que tendería a condiciones menos húmedas y estacionales hacia el Daniano tardío. Las asociaciones de nanofósiles calcáreos maastrichtianos sugerirían la existencia de ambientes oligotróficos con buena estratificación de la capa fótica, aunque en algunos niveles la nanoflora es abundante y con menor riqueza específica, lo que indica condiciones marinas más restringidas.This study presents new mineralogical, sedimentologi-cal, and micropaleontological data from the Jagüel (Late Maastrichtian-Early Danian and Roca (Danian formations, located in the eastern sector of Pellegrini Lake, Río Negro province, República Argentina. According to the physical characteristics and the age of the sediments that conform these formations, two siliciclastic lithofacies and a carbonate one were recognized, they are named: Maastrichtian grayish yellow calcareous mudstones, Danian olive gray calcareous mudstones, and Danian carbonates. The rocks which constitutes siliciclastic lithofacies were classified as allochemical mudstones and the mineralogy is characterized by high proportions of clay minerals and, to a lesser extent, calcite. The clay mineral association is dominated by a random (R0 I/S mixed-layers (70-90% Sm accompanied by lower proportions of illite and kaolinite. The mineralogy and the microfabric of the mudstones reflect that these sediments have not been affected significantly by diagenesis. Clay minerals would be of detrital origin and the predominance of the highly smectitic I/S along all sections would be associated with an active volcanism coming from the western magmatic arc, located in the Neuquén Basin during the Late Cretaceous and Paleocene. Micropalaeontological analyses confirmed the presence of Cretaceous-Paleogene transition in the Jagüel Formation beds. The calcareous nannofossils allowed to relate changes in the the mineralogical

Trace fossils and sedimentary facies from a Late Cambrian‐Early Ordovician tide‐dominated shelf (Santa Rosita Formation, northwest Argentina): Implications for ichnofacies models of shallow marine successions

Science.gov (United States)

Mángano, M. Gabriela; Buatois, Luis A.; Aceñolaza, Guillermo F.

1996-01-01

The Santa Rosita Formation is one the most widely distributed lower Paleozoic units of northwest Argentina. At the Quebrada del Salto Alto section, east of Purmamarca, Jujuy Province, it is represented by four sedimentary facies: thick‐bedded planar cross‐stratified quartzose sandstones (A), thin‐bedded planar cross‐stratified quartzose sandstones and mudstones (B), wave‐rippled sandstones and bioturbated mudstones (C), and black and greenish gray shales (D). Paleocurrent data, sandstone architecture, and sedimentary structures from faciès A and B indicate bipolar/bimodal paleoflows, suggesting the action of tidal currents. The succession is interpreted as that of a tide‐dominated shelf, with only secondary influence of wave processes. Trace fossils are restricted to facies B and C.The Cruziana ichnocoenosis is preserved on the soles of thin‐bedded planar cross‐stratified quartzose sandstones (faciès B). This ichnocoenosis consists of Conostichus isp., Cruziana omanica, C. semiplicata, C. cf. tortworthi, Cruziana isp. Helminthopsis abeli, Monomorphichnus bilinearis, M. multilineatus, Palaeophycus tubularis, Rusophycus carbonarias, R. latus, and R. isp. The occurrence of Cruziana semiplicata, C. omanica, C. cf. tortworthi, and Rusophycus latus supports a Late Cambrian‐Tremadoc age. Slabbing of Cruziana shows complex interactions between biologic and sedimentologic processes, and suggests a predominance of exhumed traces, washed out and recast by tractive sand deposition. Sandstone soles are densely packed with biogenic structures and exhibit distinctive clusters of Rusophycus isp. that most likely represent trilobite nesting burrows. The Cruziana ichnocoenosis records the resident fauna of a protected, lower intertidal to subtidal interbar setting.The Skolithos ichnocoenosis is represented by high to low density vertical burrows of Skolithos linearis, which extend downwards to the quartzose sandstone soles of faciès B and

Carbon isotope ratios of organic matter in Bering Sea settling particles. Extremely high remineralization of organic carbon derived from diatoms

International Nuclear Information System (INIS)

Yasuda, Saki; Akagi, Tasuku; Naraoka, Hiroshi; Kitajima, Fumio; Takahashi, Kozo

2016-01-01

The carbon isotope ratios of organic carbon in settling particles collected in the highly-diatom-productive Bering Sea were determined. Wet decomposition was employed to oxidize relatively fresh organic matter. The amount of unoxidised organic carbon in the residue following wet decomposition was negligible. The δ 13 C of organic carbon in the settling particles showed a clear relationship against SiO 2 /CaCO 3 ratio of settling particles: approximately -26‰ and -19‰ at lower and higher SiO 2 /CaCO 3 ratios, respectively. The δ 13 C values were largely interpreted in terms of mixing of two major plankton sources. Both δ 13 C and compositional data can be explained consistently only by assuming that more than 98% of diatomaceous organic matter decays and that organic matter derived from carbonate-shelled plankton may remain much less remineralized. A greater amount of diatom-derived organic matter is discovered to be trapped with the increase of SiO 2 /CaCO 3 ratio of the settling particles. The ratio of organic carbon to inorganic carbon, known as the rain ratio, therefore, tends to increase proportionally with the SiO 2 /CaCO 3 ratio under an extremely diatom-productive condition. (author)

Polyacrylamide-based inorganic hybrid flocculants with self-degradable property

Energy Technology Data Exchange (ETDEWEB)

Wei, Xinfang [Materials and Metallurgical College, Northeastern University, Shenyang 110819 (China); Hebei Provincial Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004 (China); Tao, Junshi; Li, Mingzhi; Zhu, Bishan; Li, Xuan; Ma, Zhiyu; Zhao, Tingjie; Wang, Bingzhu; Suo, Biao [Hebei Provincial Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004 (China); Wang, Haiwang, E-mail: whwdbdx@126.com [Materials and Metallurgical College, Northeastern University, Shenyang 110819 (China); State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Hebei Provincial Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004 (China); Yang, Jun, E-mail: jyang@ipe.ac.cn [State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190 (China); Ye, Li, E-mail: yeli@iccas.ac.cn [Beijing National Laboratory for Molecular Sciences, Institute of Chemistry Chinese Academy of Sciences, Beijing 100190 (China); Qi, Xiwei, E-mail: qxw@mail.neuq.edu.cn [Materials and Metallurgical College, Northeastern University, Shenyang 110819 (China); Hebei Provincial Laboratory for Dielectric and Electrolyte Materials, Northeastern University at Qinhuangdao, Qinhuangdao 066004 (China)

2017-05-01

Polyacrylamide (PAM)-based inorganic hybrid materials are of great potential as flocculants in soil-liquid separation. Herein, we reported the design of inorganic soil-TiO{sub 2}-PAM hybrid materials using a unique process, which involved coating of titanium dioxide (TiO{sub 2}) nanoparticles on the surface of inorganic soils and subsequent polymerization of acrylamide (AM) on these nanoparticles under visible light. Inorganic soils including kaolin, bentonite, montmorillonite and diatomaceous earth were used to control the volume and to reduce the cost, and the TiO{sub 2} nanoparticles accelerated PAM degradation. The nanoparticles initiated AM polymerization directly under visible light, thus providing a facile strategy for the synthesis of new organic-inorganic hybrid flocculants. The obtained hybrid materials were characterized using Fourier transform infrared spectroscopy and transmission electron microscopy. The degradation of PAM initiated by UV irradiation exceeded 24% in 2 h, depending on its initial concentration. - Highlights: • A new polyacrylamide (PAM)-based inorganic hybrid flocculants with self-degradable property was developed. • TiO{sub 2} nanoparticles show a unique surface-initiated property under the condition of visible light. • We designed a facile strategy for the synthesis of inorganic soil@TiO{sub 2}@PAM hybrid materials.

Joule-heated glass-furnace system for the incineration of low-level radioactive wastes

International Nuclear Information System (INIS)

Armstrong, K.M.; Klingler, L.M.; Doty, J.W.; Kramer, D.P.

1982-01-01

For the past 1-1/2 years, Mound has been preparing and evaluating a commercially available joule-heated glass furnace unit, coupled with a wet scrubbing system. The purpose of the glass furnace evaluation is to advance and document incinerator technology for such combustibles as solids, resins, and sludges, and to develop a stable waste form for subsequent disposal. Four (4) waste nonradioactive types were selected to determine the combustion efficiency of the furnace unit: (1) dry solid waste composed of paper, plastics, rubber, and cloth, (2) ion exchange resin of both the anionic and cationic type, (3) filter sludge composed of diatomaceous earth, organic cellulosic filter aid, and powdered ion exchange resin, and (4) cartridge filters having glass and plastic filter surfaces and nonmetallic cores. When completed, the combustion efficiency experiments for the proposed nonradioactive waste-types revealed the ability of the furnace to easily incinerate waste at feedrates of up to 150 lb/hr. During the course of the experiments, combustibles in the offgas remained consistently low, suggesting excellent combustion efficiency. Furthermore, ash produced by the combustion process was effectively incorporated into the melt by convective currents in the glass. Future work on the glass furnace incinerator will include spiking the waste to determine radioisotope behavior in the furnace

Optimization of Saccharification Conditions of Lignocellulosic Biomass under Alkaline Pre-Treatment and Enzymatic Hydrolysis

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Rafał Łukajtis

2018-04-01

Full Text Available Pre-treatment is a significant step in the production of second-generation biofuels from waste lignocellulosic materials. Obtaining biofuels as a result of fermentation processes requires appropriate pre-treatment conditions ensuring the highest possible degree of saccharification of the feed material. An influence of the following process parameters were investigated for alkaline pre-treatment of Salix viminalis L.: catalyst concentration (NaOH, temperature, pre-treatment time and granulation. For this purpose, experiments were carried out in accordance to the Box-Behnken design for four factors. In the saccharification process of the pre-treated biomass, cellulolytic enzymes immobilized on diatomaceous earth were used. Based on the obtained results, a mathematical model for the optimal conditions of alkaline pre-treatment prediction is proposed. The optimal conditions of alkaline pre-treatment are established as follows: granulation 0.75 mm, catalyst concentration 7%, pre-treatment time 6 h and temperature 65 °C if the saccharification efficiency and cost analysis are considered. An influence of the optimized pre-treatment on both the chemical composition and structural changes for six various lignocellulosic materials (energetic willow, energetic poplar, beech, triticale, meadow grass, corncobs was investigated. SEM images of raw and pre-treated biomass samples are included in order to follow the changes in the biomass structure during hydrolysis.

Reconstruction of postglacial landscape evolution within the eastern periphery of Chuya depression on the basis of multidisciplinary analysis of peats in Boguty river basin, SE Altai, Russia

Science.gov (United States)

Agatova, A. R.; Khazina, I. V.; Bronnikova, M. A.; Uspenskaya, O. N.; Nepop, R. K.

2018-03-01

This paper presents the results of multidisciplinary investigations of the peat-bed under hummocky permafrosted boggy meadow within the Boguty basin. For the last 7600 years 4 evolutionary phases of peatbog formation within the drained part of Low Boguty Lake bottom were established and corresponding 4 pollen complexes were described. 18 radiocarbon dates suggest some chronological bench marks of postglacial landscape evolution in the region. After degradation of Sartan glaciation about 14000 BP, trees grew in now forestless areas at 11000 BP and 8500-7800 BP. The climate in the first half of the Holocene was warmer and more humid. Accumulation of lacustrine loams within the studied peatbog occurred before 7600 BP with predominated algae Pediastrum, Zygnemataceae and Botryococcus. After the lake level lowered in the result of destructing moraine dam, two lower peat horizons were developed about 7600 – 7200 BP. An episode of significant lake desiccation (later than 7200 BP) was recorded in all proxy archives. Further rise of water supply led to increasing the number of water-bog plants, diatomaceous, euglenic and green algae. At the same time, the pollen of xerophytes began to predominate in the pollen complexes, indicating aridization. The final stage reflects stable peatbog drying and its transformation into boggy meadow, decomposition and mineralization of peat.

Determination of benzoylurea insecticides in food by pressurized liquid extraction and LC-MS.

Science.gov (United States)

Brutti, Monia; Blasco, Cristina; Picó, Yolanda

2010-01-01

A method based on pressurized liquid extraction and LC-MS/MS has been developed for determining nine benzoylureas (BUs) in fruit, vegetable, cereals, and animal products. Samples (5 g) were homogenized with diatomaceous earth and extracted in a 22 mL cell with 22 mL of ethyl acetate at 80 degrees C and 1500 psi. After solvent concentration and exchange to methanol, BUs were analyzed by LC-MS/MS using an IT mass analyzer, which achieved several transitions of precursor ions that increase selectivity providing identification. LOQs were between 0.002 and 0.01 mg/kg, which are equal or lower than maximum residue limits established by the Codex Alimentarius. Excellent linearity was achieved over a range of concentrations from 0.01 to 1 mg/kg with correlation coefficients 0.995-0.999 (n=7). Validation of the total method was performed by analyzing in quintuplicate seven different commodities (milk, eggs, meat, rice, lettuce, avocado, and lemon) at three concentration levels (0.01, 0.1, and 1 mg/kg). The recoveries ranged from 58 to 97% and the RSDs from 5 to 19% depending on the compound and the commodity. The combination of pressurized liquid extraction with LC-MS/MS provides a sensitive and selective method for the determination of BUs in food.

Diffusion and reaction within porous packing media: a phenomenological model.

Science.gov (United States)

Jones, W L; Dockery, J D; Vogel, C R; Sturman, P J

1993-04-25

A phenomenological model has been developed to describe biomass distribution and substrate depletion in porous diatomaceous earth (DE) pellets colonized by Pseudomonas aeruginosa. The essential features of the model are diffusion, attachment and detachment to/from pore walls of the biomass, diffusion of substrate within the pellet, and external mass transfer of both substrate and biomass in the bulk fluid of a packed bed containing the pellets. A bench-scale reactor filled with DE pellets was inoculated with P. aeruginosa and operated in plug flow without recycle using a feed containing glucose as the limiting nutrient. Steady-state effluent glucose concentrations were measured at various residence times, and biomass distribution within the pellet was measured at the lowest residence time. In the model, microorganism/substrate kinetics and mass transfer characteristics were predicted from the literature. Only the attachment and detachment parameters were treated as unknowns, and were determined by fitting biomass distribution data within the pellets to the mathematical model. The rate-limiting step in substrate conversion was determined to be internal mass transfer resistance; external mass transfer resistance and microbial kinetic limitations were found to be nearly negligible. Only the outer 5% of the pellets contributed to substrate conversion.

[Determination of fatty acid esters of chloropropanediols in diet samples by gas chromatography-mass spectrometry coupled with solid-supported liquid-liquid extraction].

Science.gov (United States)

Gao, Jie; Liu, Qing; Han, Feng; Miao, Hong; Zhao, Yunfeng; Wu, Yongning

2014-05-01

To establish a method for the determination of fatty acid esters of 3-monochloropropane-1, 2-diol (3-MCPD) and 2-monochloropropane-1, 3-diol (2-MCPD) in diet samples by gas chromatography-mass spectrometry (GC-MS) with solid-supported liquid-liquid extraction (SLE). Diet samples were ultrasonically extracted by hexane, followed by ester cleavage reaction with sodium methylate in methanol, and then purified by solid-supported liquid-liquid extraction. (SLE) using diatomaceous earth as the sorbent. After derivatization with heptafluorobutyrylimidazole, the analytes were detected by GC-MS and quantified by the deuterated internal standards. The limits of detection (LODs) of 3-MCPD esters and 2-MCPD esters in different diet samples were 0.002 - 0.005 mg/kg and 0.002 - 0.006 mg/kg. The average recoveries of 3-MCPD esters and 2-MCPD esters at the spiking levels of 0.05 and 0.1 mg/kg in the diet samples were in the range of 65.9% - 104.2% and 75.4% - 118.0%, respectively, with the relative standard deviations in the range of 2.2% - 14.2% and 0.8% - .13.9%. The method is simple, accurate and rugged for the determination of fatty acid esters of 3-MCPD and 2-MCPD in diet samples.

Diatomite as a novel composite ingredient for chitosan film with enhanced physicochemical properties.

Science.gov (United States)

Akyuz, Lalehan; Kaya, Murat; Koc, Behlul; Mujtaba, Muhammad; Ilk, Sedef; Labidi, Jalel; Salaberria, Asier M; Cakmak, Yavuz Selim; Yildiz, Aysegul

2017-12-01

Practical applications of biopolymers in different industries are gaining considerable increase day by day. But still, these biopolymers lack important properties in order to meet the industrial demands. In the same regard, in the current study, chitosan composite films are produced by incorporating diatomite soil at two different concentrations. In order to obtain a homogeneous film, glutaraldehyde was supplemented to chitosan solution as a cross-linker. Compositing diatomaceous earth to chitosan film resulted in improvement of various important physicochemical properties compared to control such as; enhanced film wettability, increase elongation at break and improved thermal stability (264-277°C). The microstructure of the film was observed to haveconsisted of homogeneously distributed blister-shaped structures arised due to the incorporation of diatomite. The incorporation of diatomite did not influence the overall antioxidant activity of the composite films, which can be ascribe to the difficulty radicals formation. Chitosan film incorporated with increasing fraction of diatomite revealed a notable enhancement in the antimicrobial activity. Additionally with the present study, for the first time possible interactions between chitosan/diatomite were determined via quantum chemical calculations. Current study will be helpful in giving a new biotechnological perspective to diatom in terms of its successful application in hydrophobic composite film production. Copyright © 2017 Elsevier B.V. All rights reserved.

Insights into the diagenetic environment of fossil marine vertebrates of the Pisco Formation (late Miocene, Peru) from mineralogical and Sr-isotope data

Science.gov (United States)

Gioncada, A.; Petrini, R.; Bosio, G.; Gariboldi, K.; Collareta, A.; Malinverno, E.; Bonaccorsi, E.; Di Celma, C.; Pasero, M.; Urbina, M.; Bianucci, G.

2018-01-01

The late Miocene Pisco Formation of Peru is an outstanding example of richness and high-quality preservation of fossil marine vertebrates. In order to reconstruct the fossilization path, we present new textural, mineralogical and Sr-isotope data of diagenetic minerals formed in correspondence of fossil specimens such as marine vertebrates and mollusks. These fossil specimens were found at Cerro los Quesos, in the Ica Desert, within the diatomaceous strata of the Pisco Formation. Dolomite, gypsum, anhydrite and Mn minerals are the main phases found, while the calcium carbonate originally forming the mollusk valves is replaced by gypsum. An early formation of dolomite and of Mn minerals, triggered by the modifications of the geochemical environment due to organic matter degradation, is suggested by the textural relationships and is confirmed by the Sr isotopic ratio of dolomite, which agrees with that of seawater at the time of sedimentation. Instead, gypsum Sr isotopic ratios indicate a pre-Miocene seawater-derived brine circulating within the sedimentary sequence as a source for Sr. Oxidation of diagenetic sulfide causing a lowering of the pH of porewater is proposed as an explanation for Ca-carbonate dissolution. The diagenetic chemical environment was, nevertheless, favorable to bone preservation.

Robust Superhydrophobic Graphene-Based Composite Coatings with Self-Cleaning and Corrosion Barrier Properties.

Science.gov (United States)

Nine, Md J; Cole, Martin A; Johnson, Lucas; Tran, Diana N H; Losic, Dusan

2015-12-30

Superhydrophobic surfaces for self-cleaning applications often suffer from mechanical instability and do not function well after abrasion/scratching. To address this problem, we present a method to prepare graphene-based superhydrophobic composite coatings with robust mechanical strength, self-cleaning, and barrier properties. A suspension has been formulated that contains a mixture of reduced graphene oxide (rGO) and diatomaceous earth (DE) modified with polydimethylsiloxane (PDMS) that can be applied on any surface using common coating methods such as spraying, brush painting, and dip coating. Inclusion of TiO2 nanoparticles to the formulation shows further increase in water contact angle (WCA) from 159 ± 2° to 170 ± 2° due to the structural improvement with hierarchical surface roughness. Mechanical stability and durability of the coatings has been achieved by using a commercial adhesive to bond the superhydrophobic "paint" to various substrates. Excellent retention of superhydrophobicity was observed even after sandpaper abrasion and crosscut scratching. A potentiodynamic polarization study revealed excellent corrosion resistance (96.78%) properties, and an acid was used to provide further insight into coating barrier properties. The ease of application and remarkable properties of this graphene-based composite coating show considerable potential for broad application as a self-cleaning and protective layer.

Longitudinal study of parasite-induced mortality of a long-lived host: the importance of exposure to non-parasitic stressors.

Science.gov (United States)

Chin, Hilary M-H; Luong, Lien T; Shostak, Allen W

2017-12-01

Hosts face mortality from parasitic and environmental stressors, but interactions of parasitism with other stressors are not well understood, particularly for long-lived hosts. We monitored survival of flour beetles (Tribolium confusum) in a longitudinal design incorporating cestode (Hymenolepis diminuta) infection, starvation and exposure to the pesticide diatomaceous earth (DE). We found that cestode cysticercoids exhibit increasing morphological damage and decreasing ability to excyst over time, but were never eliminated from the host. In the presence of even mild environmental stressors, host lifespan was reduced sufficiently that extensive degradation of cysticercoids was never realized. Median host lifespan was 200 days in the absence of stressors, and 3-197 days with parasitism, starvation and/or DE. Early survival of parasitized hosts was higher relative to controls in the presence of intermediate concentrations of DE, but reduced under all other conditions tested. Parasitism increased host mortality in the presence of other stressors at times when parasitism alone did not cause mortality, consistent with an interpretation of synergy. Environmental stressors modified the parasite numbers needed to reveal intensity-dependent host mortality, but only rarely masked intensity dependence. The longitudinal approach produced observations that would have been overlooked or misinterpreted if survival had only been monitored at a single time point.

Misconceptions regarding the pathogenicity of silicas and silicates.

Science.gov (United States)

Feigin, D S

1989-01-01

Several inhaled substances, from occupational or other environmental exposure, produce significant pulmonary disease and abnormalities demonstrated by pulmonary imaging. Areas of controversy and misconception relate principally to the extent and nature of both the clinical disease and the imaging abnormalities specific to each substance. The size and shape of the inhaled particles is an important determinant of the nature and severity of the disease produced, with fibrous shapes usually being the most pathogenetic. Fibrogenicity is another important pathogenetic characteristic of talc and kaolin, as well as asbestos. Talc produces four distinct forms of pulmonary disease, depending not only on the other substances with which it is inhaled, but also whether it is inhaled or injected intravenously. When inhaled alone, talc does not appear to produce significant pulmonary fibrosis or malignancy. Kaolin, mica, fuller's earth, zeolite, and fiberglass all vary in disease production according to their shape and fibrogenicity. Silica, diatomaceous earth, and other forms of silica are all highly fibrogenic and thus produce clinically obvious disease with sufficient inhalation. The largest particles usually produce nodular patterns in the upper pulmonary fields, as is typical of silicosis. The fibrous particles are more likely to manifest themselves as interstitial patterns in the lower pulmonary fields.

Eco-sustainable systems based on poly(lactic acid), diatomite and coffee grounds extract for food packaging.

Science.gov (United States)

Cacciotti, Ilaria; Mori, Stefano; Cherubini, Valeria; Nanni, Francesca

2018-06-01

In the food packaging sector many efforts have been (and are) devoted to the development of new materials in order to reply to an urgent market demand for green and eco-sustainable products. Particularly a lot of attention is currently devoted both to the use of compostable and biobased polymers as innovative and promising alternative to the currently used petrochemical derived polymers, and to the re-use of waste materials coming from agriculture and food industry. In this work, multifunctional eco-sustainable systems, based on poly(lactic acid) (PLA) as biopolymeric matrix, diatomaceous earth as reinforcing filler and spent coffee grounds extract as oxygen scavenger, were produced for the first time, in order to provide a simultaneous improvement of mechanical and gas barrier properties. The influence of the diatomite and the spent coffee grounds extract on the microstructural, mechanical and oxygen barrier properties of the produced films was deeply investigated by means of X-Ray diffraction (XRD), infrared spectroscopy (FT-IR, ATR), scanning electron microscopy (SEM), uniaxial tensile tests, O 2 permeabilimetry measurements. An improvement of both mechanical and oxygen barrier properties was recorded for systems characterised by the co-presence of diatomite and coffee grounds extract, suggesting a possible synergic effect of the two additives. Copyright © 2018 Elsevier B.V. All rights reserved.

Facile Preparation of Nano-Bi2MoO6/Diatomite Composite for Enhancing Photocatalytic Performance under Visible Light Irradiation

Directory of Open Access Journals (Sweden)

Lu Cai

2018-02-01

Full Text Available In this work, a new nano-Bi2MoO6/diatomite composite photocatalyst was successfully synthesized by a facile solvothermal method. Scanning electron microscopy (SEM, Fourier transform infrared spectroscopy (FTIR, X-ray diffraction (XRD, and UV-vis diffuse reflection spectroscopy (DRS were employed to investigate the morphology, crystal structure, and optical properties. It was shown that nanometer-scaled Bi2MoO6 crystals were well-deposited on the surface of Bi2MoO6/diatomite. The photocatalytic activity of the obtained samples was evaluated by the degradation of rhodamine B (RhB under the visible light (λ > 420 nm irradiation. Moreover, trapping experiments were performed to investigate the possible photocatalytic reaction mechanism. The results showed that the nano-Bi2MoO6/diatomite composite with the mass ratio of Bi2MoO6 to diatomaceous earth of 70% exhibited the highest activity, and the RhB degradation efficiency reached 97.6% within 60 min. The main active species were revealed to be h+ and•O2−. As a photocatalytic reactor, its recycling performance showed a good stability and reusability. This new composite photocatalyst material holds great promise in the engineering field for the environmental remediation.

Microfluidic Diatomite Analytical Devices for Illicit Drug Sensing with ppb-Level Sensitivity.

Science.gov (United States)

Kong, Xianming; Chong, Xinyuan; Squire, Kenny; Wang, Alan X

2018-04-15

The escalating research interests in porous media microfluidics, such as microfluidic paper-based analytical devices, have fostered a new spectrum of biomedical devices for point-of-care (POC) diagnosis and biosensing. In this paper, we report microfluidic diatomite analytical devices (μDADs), which consist of highly porous photonic crystal biosilica channels, as an innovative lab-on-a-chip platform to detect illicit drugs. The μDADs in this work are fabricated by spin-coating and tape-stripping diatomaceous earth on regular glass slides with cross section of 400×30µm 2 . As the most unique feature, our μDADs can simultaneously perform on-chip chromatography to separate small molecules from complex biofluidic samples and acquire the surface-enhanced Raman scattering spectra of the target chemicals with high specificity. Owing to the ultra-small dimension of the diatomite microfluidic channels and the photonic crystal effect from the fossilized diatom frustules, we demonstrate unprecedented sensitivity down to part-per-billion (ppb) level when detecting pyrene (1ppb) from mixed sample with Raman dye and cocaine (10 ppb) from human plasma. This pioneering work proves the exclusive advantage of μDADs as emerging microfluidic devices for chemical and biomedical sensing, especially for POC drug screening.

Facile Preparation of Nano-Bi2MoO6/Diatomite Composite for Enhancing Photocatalytic Performance under Visible Light Irradiation

Science.gov (United States)

Gong, Jiuyan; Liu, Jianshe; Song, Wendong; Ji, Lili

2018-01-01

In this work, a new nano-Bi2MoO6/diatomite composite photocatalyst was successfully synthesized by a facile solvothermal method. Scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), and UV-vis diffuse reflection spectroscopy (DRS) were employed to investigate the morphology, crystal structure, and optical properties. It was shown that nanometer-scaled Bi2MoO6 crystals were well-deposited on the surface of Bi2MoO6/diatomite. The photocatalytic activity of the obtained samples was evaluated by the degradation of rhodamine B (RhB) under the visible light (λ > 420 nm) irradiation. Moreover, trapping experiments were performed to investigate the possible photocatalytic reaction mechanism. The results showed that the nano-Bi2MoO6/diatomite composite with the mass ratio of Bi2MoO6 to diatomaceous earth of 70% exhibited the highest activity, and the RhB degradation efficiency reached 97.6% within 60 min. The main active species were revealed to be h+ and•O2−. As a photocatalytic reactor, its recycling performance showed a good stability and reusability. This new composite photocatalyst material holds great promise in the engineering field for the environmental remediation. PMID:29425138

Magnetic Polarity Stratigraphy and Rock Magnetic Data From the Continuous Cored Record of Triassic Continental Environmental Change, the Colorado Plateau Coring Project

Science.gov (United States)

Geissman, J. W.; McIntosh, J.; Buhedma, H. M. A.

2017-12-01

Despite the fact that the Triassic Period (ca. 251.9-201.3 Ma) is bound by two of Earth's largest mass extinctions, experienced giant bolide impacts and eruption of three large igneous provinces, and witnessed evolution of the main components of modern tetrapod communities, the time interval has sparse geochronologic calibration. The US NSF- and ICDP-funded coring of Phase 1 of the CPCP was completed in 2013, with the recovery of two major cores (6.35 cm diameter: 1A, 518m length and 2B, 253m; 31km apart) from the Petrified Forest National Park spanning the Chinle and Moenkopi fms. Core 1A has been fully sampled, with specimens obtained either by drilling or by extraction of core fragments and packing in ceramic boxes. Specimens are subjected to progressive thermal demagnetization or a combination of alternating field (AF) followed by thermal treatment. In several cases, specimens were extracted from each core segment to test for internal consistency. Chinle hematitic mudstones and siltstones have NRM intensities between 130 to 0.5 mA/m, with bulk susceptibilities from 2 x 10-2 to 5 x 10-5 SI units. More indurated hematitic siltstones/ medium sandstones of the Moenkopi Fm have NRM intensities and bulk susceptibilities that are far less variable (NRM: 9.0 to 1.2 mA/m, MS: 3.0 X 10-4 and 0.5 x 10-5 SI vol). Thermal demagnetization typically isolates magnetizations of N declination and shallow inclination (interpreted as normal polarity) and antipodes (reverse) (image), a polarity stratigraphy is being compiled for much of the section. Response is typically more interpretable for very hematitic Chinle mudstone sections and most Moenkopi rocks. Coarser grained, less hematitic Chinle strata rarely yield interpretable results, likely due to coarse-grained detrital magnetite, and it is likely that these intervals will not yield robust polarity information. Some core segments yield well-resolved magnetizations that are inconsistent with a Triassic field and we suspect

Stratigraphic distribution, taphonomy and paleoenvironments of Spinicaudata in the Triassic and Jurassic of the Paraná Basin

Science.gov (United States)

Jenisch, Alan Gregory; Lehn, Ilana; Gallego, Oscar Florencio; Monferran, Mateo Daniel; Horodyski, Rodrigo Scalise; Faccini, Ubiratan Ferrucio

2017-12-01

Due to the chitino-phosphatic nature of Spinicaudata conchostracan exoskeletons, their carapaces exhibit a low preservational potential compared to other bivalve groups. However, the recent studies point towards the increased tolerance of the carapace against the physical processes. Due to this peculiar characteristic, conchostracan carapace have been utilized as precise temporal markers in estimating stratigraphic and taphonomic parameters. The same characteristic also makes the spinicaudatans useful in evaluating the depositional processes and environments. The present work aims at providing a paleoenvironmental and stratigraphic analysis of conchostracans (Spinicaudata) from the Triassic-Jurassic of the Paraná Basin (Santa Maria and Caturrita formations) in terms of the sedimentary facies analysis, depositional system characterization, and analysis of the taphonomic signatures of the fossiliferous horizons within these formations. The results from the taphonomic study delineates the presence of 4 distinct fossil assemblages based on the causative mechanism and fundamental characteristics of the fossil concentrations: two taphonomic assemblages in the laminated mudstone beds deposited from the decanting fine-grained sediments in floodplains; the sandstone beds with plane parallel laminations and dune- and ripple-cross-stratifications deposited from the flooding-related overflow in the floodplains; and the association of laminated mudstone and massive sandstone beds deposited as the river mouth bars. The results show that the taphonomic signatures, e.g., closed valves, may indicate the various patterns of autochthony and allochthony. In the fine-grained floodplain assemblages, the high degree of preservation can be attributed to autochthony in the conchostracans, whereas the preservational condition of floodplain sandstone sheet and mouth bar assemblages point toward parautochthony and even allochthony. Therefore, the preservational quality of conchostracan

Eo-Oligocene Oil Shales of the Talawi, Lubuktaruk, and Kiliranjao Areas, West Sumatra: Are they potential source rocks?

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M. Iqbal

2014-12-01

Full Text Available DOI:10.17014/ijog.v1i3.198To anticipate the increasing energy demand, additional data and information covering unconventional fossil fuels such as oil shale must be acquired to promote the usage of alternative energy sources to crude oil. The Talawi and Lubuktaruk regions situated within intra-montane Ombilin Basin, and the Kiliranjao assumed to be a small intra montane basin are occupied by Eo-Oligocene sediments of Sangkarewang and Kiliran Formations, respectively. Field activity, geochemical screening techniques, and organic petrographic analysis, supported by SEM mode, are methods used. Most of the oil shale sequence is typically of an organically rich-succession comprising predominantly well-bedded, laminated and fissile, brownish to dark grey organic-rich shale and mudstone rocks. The exinite macerals within oil shale comprise mainly Pediastrum-lamalginite with minor cutinite, resinite, liptodetrinite, sporinite, bituminite, and rare Botryococcus-telalginite. Therefore; the oil shale deposits can be described as “lamosites”. Minor vitrinite maceral is also recognized. TOC analysis on selected shale samples corresponds to a fair up to excellent category of source rock characterization. The hydrogen index (HI for all samples shows a range of values from 207 - 864, and pyrolysis yield (PY ranges from 2.67 to 79.72 mg HC/g rock. The kerogen is suggested to be of mixed Type II and Type I autochthonous materials such as alginite, with minor allochthonous substances. Oil samples collected appear to be positioned within more oil prone rather than gas prone. Thermal maturity of the oil shales gained from Tmax value and production index (PI tends to show immature to marginally/early mature stage. A consistency in the thermal maturity level results by using both Tmax and vitrinite reflectance value is recognized. On the basis of  SEM analysis, the oil shale has undergone a late eodiagenetic process. Thereby, overall, vitrinite reflectance

Bedrock cores from 89° North: Implications for the geologic framework and Neogene paleoceanography of Lomonosov Ridge and a tie to the Barents shelf

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Grantz, Arthur; Pease, Victoria L.; Willard, Debra A.; Phillips, R.L.; Clark, David L.

2001-01-01

Two piston cores from the Eurasian flank of Lomonosov Ridge near lat 88.9°N, long 140°E provide the first samples of bedrock from this high-standing trans-Arctic ridge. Core 94-PC27 sampled nonmarine siltstone similar in facies and age to uppermost Triassic to lower Lower Jurassic and mid– Lower Cretaceous beds in the 4 to > 5 km Mesozoic section on Franz Josef Land, on the outer Barents shelf. A ca. 250 Ma peak in the cumulative frequency curve of detrital zircons from the siltstone, dated by U- Th-Pb analysis, suggests a source in the post-tectonic syenites of northern Taymyr and nearby islands in the Kara Sea. Textural trends reported in the literature indicate that the Lower Jurassic nonmarine strata of Franz Josef Land coarsen to the southeast; this suggests the existence of a sedimentary system in which detrital zircons could be transported from the northern Taymyr Peninsula to the outer Barents shelf near the position of core 94-PC27 prior to opening of the Eurasia Basin. Correlation of the coaly siltstone in core 94-PC27 with part of the Mesozoic section on Franz Josef Land is compatible with the strong evidence from seafloor magnetic anomalies and bathymetry that Lomonosov Ridge is a continental fragment rifted from the Barents shelf during the Cenozoic. It also suggests that Lomonosov Ridge near the North Pole is underlain by a substantial section of unmetamorphosed Mesozoic marine and nonmarine sedimentary strata. Core 94-PC29 sampled cyclical deposits containing ice-rafted debris (IRD) overlying weakly consolidated laminated olive-black anoxic Neogene siltstone and mudstone with an average total organic carbon (TOC) of 4.1 wt%. The high TOC content of the mudstone indicates that during the Neogene, prior to the introduction of IRD into the Arctic seas about 3.3 Ma (early late Pliocene), the shallow waters of the central Arctic Ocean supported significant primary photosynthetic organic production near the North Pole. These deposits also contain fine