Large-scale ichthyoplankton and water mass distribution along the South Brazil Shelf.

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Luis Carlos Pinto de Macedo-Soares

Full Text Available Ichthyoplankton is an essential component of pelagic ecosystems, and environmental factors play an important role in determining its distribution. We have investigated simultaneous latitudinal and cross-shelf gradients in ichthyoplankton abundance to test the hypothesis that the large-scale distribution of fish larvae in the South Brazil Shelf is associated with water mass composition. Vertical plankton tows were collected between 21°27' and 34°51'S at 107 stations, in austral late spring and early summer seasons. Samples were taken with a conical-cylindrical plankton net from the depth of chlorophyll maxima to the surface in deep stations, or from 10 m from the bottom to the surface in shallow waters. Salinity and temperature were obtained with a CTD/rosette system, which provided seawater for chlorophyll-a and nutrient concentrations. The influence of water mass on larval fish species was studied using Indicator Species Analysis, whereas environmental effects on the distribution of larval fish species were analyzed by Distance-based Redundancy Analysis. Larval fish species were associated with specific water masses: in the north, Sardinella brasiliensis was found in Shelf Water; whereas in the south, Engraulis anchoita inhabited the Plata Plume Water. At the slope, Tropical Water was characterized by the bristlemouth Cyclothone acclinidens. The concurrent analysis showed the importance of both cross-shelf and latitudinal gradients on the large-scale distribution of larval fish species. Our findings reveal that ichthyoplankton composition and large-scale spatial distribution are determined by water mass composition in both latitudinal and cross-shelf gradients.

Large-scale ichthyoplankton and water mass distribution along the South Brazil Shelf.

Science.gov (United States)

de Macedo-Soares, Luis Carlos Pinto; Garcia, Carlos Alberto Eiras; Freire, Andrea Santarosa; Muelbert, José Henrique

2014-01-01

Ichthyoplankton is an essential component of pelagic ecosystems, and environmental factors play an important role in determining its distribution. We have investigated simultaneous latitudinal and cross-shelf gradients in ichthyoplankton abundance to test the hypothesis that the large-scale distribution of fish larvae in the South Brazil Shelf is associated with water mass composition. Vertical plankton tows were collected between 21°27' and 34°51'S at 107 stations, in austral late spring and early summer seasons. Samples were taken with a conical-cylindrical plankton net from the depth of chlorophyll maxima to the surface in deep stations, or from 10 m from the bottom to the surface in shallow waters. Salinity and temperature were obtained with a CTD/rosette system, which provided seawater for chlorophyll-a and nutrient concentrations. The influence of water mass on larval fish species was studied using Indicator Species Analysis, whereas environmental effects on the distribution of larval fish species were analyzed by Distance-based Redundancy Analysis. Larval fish species were associated with specific water masses: in the north, Sardinella brasiliensis was found in Shelf Water; whereas in the south, Engraulis anchoita inhabited the Plata Plume Water. At the slope, Tropical Water was characterized by the bristlemouth Cyclothone acclinidens. The concurrent analysis showed the importance of both cross-shelf and latitudinal gradients on the large-scale distribution of larval fish species. Our findings reveal that ichthyoplankton composition and large-scale spatial distribution are determined by water mass composition in both latitudinal and cross-shelf gradients.

Understanding Ice Shelf Basal Melting Using Convergent ICEPOD Data Sets: ROSETTA-Ice Study of Ross Ice Shelf

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Bell, R. E.; Frearson, N.; Tinto, K. J.; Das, I.; Fricker, H. A.; Siddoway, C. S.; Padman, L.

2017-12-01

The future stability of the ice shelves surrounding Antarctica will be susceptible to increases in both surface and basal melt as the atmosphere and ocean warm. The ROSETTA-Ice program is targeted at using the ICEPOD airborne technology to produce new constraints on Ross Ice Shelf, the underlying ocean, bathymetry, and geologic setting, using radar sounding, gravimetry and laser altimetry. This convergent approach to studying the ice-shelf and basal processes enables us to develop an understanding of the fundamental controls on ice-shelf evolution. This work leverages the stratigraphy of the ice shelf, which is detected as individual reflectors by the shallow-ice radar and is often associated with surface scour, form close to the grounding line or pinning points on the ice shelf. Surface accumulation on the ice shelf buries these reflectors as the ice flows towards the calving front. This distinctive stratigraphy can be traced across the ice shelf for the major East Antarctic outlet glaciers and West Antarctic ice streams. Changes in the ice thickness below these reflectors are a result of strain and basal melting and freezing. Correcting the estimated thickness changes for strain using RIGGS strain measurements, we can develop decadal-resolution flowline distributions of basal melt. Close to East Antarctica elevated melt-rates (>1 m/yr) are found 60-100 km from the calving front. On the West Antarctic side high melt rates primarily develop within 10 km of the calving front. The East Antarctic side of Ross Ice Shelf is dominated by melt driven by saline water masses that develop in Ross Sea polynyas, while the melting on the West Antarctic side next to Hayes Bank is associated with modified Continental Deep Water transported along the continental shelf. The two sides of Ross Ice Shelf experience differing basal melt in part due to the duality in the underlying geologic structure: the East Antarctic side consists of relatively dense crust, with low amplitude

On the dense water spreading off the Ross Sea shelf (Southern Ocean)

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Budillon, G.; Gremes Cordero, S.; Salusti, E.

2002-07-01

In this study, current meter and hydrological data obtained during the X Italian Expedition in the Ross Sea (CLIMA Project) are analyzed. Our data show a nice agreement with previous data referring to the water masses present in this area and their dynamics. Here, they are used to further analyze the mixing and deepening processes of Deep Ice Shelf Water (DISW) over the northern shelf break of the Ross Sea. In more detail, our work is focused on the elementary mechanisms that are the most efficient in removing dense water from the shelf: either classical mixing effects or density currents that interact with some topographic irregularity in order to drop to deeper levels, or also the variability of the Antarctic Circumpolar Current (ACC) which, in its meandering, can push the dense water off the shelf, thus interrupting its geostrophic flow. We also discuss in detail the (partial) evidence of dramatic interactions of the dense water with bottom particulate, of geological or biological origin, thus generating impulsive or quasi-steady density-turbidity currents. This complex interaction allows one to consider bottom particular and dense water as a unique self-interacting system. In synthesis, this is a first tentative analysis of the effect of bottom particulate on the dense water dynamics in the Ross Sea.

Environmental controls on micro fracture processes in shelf ice

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Sammonds, Peter

2013-04-01

The recent retreat and collapse of the ice shelves on the Antarctic Peninsula has been associated with regional atmospheric warming, oceanic warming, increased summer melt and shelf flexure. Although the cause of collapse is a matter of active discussion, the process is that of fracture of a creep-brittle material, close to its melting point. The environmental controls on how fracturing initiates, at a micro-scale, strongly determine the macroscopic disintegration of ice shelves. In particular the shelf temperature profile controls the plasticity of the ice shelf; the densification of shelf ice due to melting and re-freezing affects the crack tip stress intensity; the accretion of marine ice at the bottom of the shelf imposes a thermal/mechanical discontinuity; saline environments control crack tip stress corrosion; cyclic loading promotes sub-critical crack propagation. These strong environmental controls on shelf ice fracture means that assessing shelf stability is a non-deterministic problem. How these factors may be parameterized in ice shelf models, through the use of fracture mechanisms maps, is discussed. The findings are discussed in relation to the stability of Larsen C.

Transport and transfer rates in the waters of the continental shelf and slope: SEEP

International Nuclear Information System (INIS)

Biscaye, P.E.; Anderson, R.F.

1993-01-01

The overall Shelf Edge Exchange Processes (SEEP) Program, which began in 1980 or 1981, had as its goal the testing of a hypothesis with respect to the fate of particulate matter formed in and introduced into the waters of the continental shelf adjacent to the northern east coast of the US, i.e., the MAB. The original hypothesis was that a large proportion of the particles in general, and of the particulate organic carbon (POC) in particular, was exported from the shelf, across the shelf/slope break and front, into the waters of, and, to some degree, deposited in the sediments of the continental slope. This hypothesis was based on budgets of organic carbon and lead-210 that did not account for a large proportion of those species in the waters or sediments of the shelf, and on a carbon-rich band of sediments centered on the slope at ∼1,000 m water depth. The results of the first SEEP experiment, south of New England and Long Island (SEEP-1) suggested, but did not prove, that there was only a relatively small proportion of the carbon which was exported from the shelf to the slope. The objective of the second experiment -- SEEP-2 -- done under the subject grant, was to tighten the experiment in terms of the kinds of data collected, and to focus it more on the shelf and only the upper slope, where shelf-derived particles were thought to be deposited

Water Mass Classification on a Highly Variable Arctic Shelf Region: Origin of Laptev Sea Water Masses and Implications for the Nutrient Budget

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Bauch, D.; Cherniavskaia, E.

2018-03-01

Large gradients and inter annual variations on the Laptev Sea shelf prevent the use of uniform property ranges for a classification of major water masses. The central Laptev Sea is dominated by predominantly marine waters, locally formed polynya waters and riverine summer surface waters. Marine waters enter the central Laptev Sea from the northwestern Laptev Sea shelf and originate from the Kara Sea or the Arctic Ocean halocline. Local polynya waters are formed in the Laptev Sea coastal polynyas. Riverine summer surface waters are formed from Lena river discharge and local melt. We use a principal component analysis (PCA) in order to assess the distribution and importance of water masses within the Laptev Sea. This mathematical method is applied to hydro-chemical summer data sets from the Laptev Sea from five years and allows to define water types based on objective and statistically significant criteria. We argue that the PCA-derived water types are consistent with the Laptev Sea hydrography and indeed represent the major water masses on the central Laptev Sea shelf. Budgets estimated for the thus defined major Laptev Sea water masses indicate that freshwater inflow from the western Laptev Sea is about half or in the same order of magnitude as freshwater stored in locally formed polynya waters. Imported water dominates the nutrient budget in the central Laptev Sea; and only in years with enhanced local polynya activity is the nutrient budget of the locally formed water in the same order as imported nutrients.

Salt stabilizer for preventing chlorine depletion and increasing shelf-life of potable water - A concept

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Copeland, E. J.; Edgerley, R. H.

1971-01-01

Proposed concept, based on law of mass action uses addition of salt to increase chlorine ions produced in sodium hydrochlorite solutions, thereby increasing solution shelf-life. This technique is not costly. Usefulness will be determined by acceptability of salt in product undergoing long shelf-life.

Radon-222 and radium-226 in southeastern Bering Sea shelf waters and sediment

International Nuclear Information System (INIS)

Glover, D.M.; Reeburgh, W.S.

1987-01-01

Radon-222 and 226 Ra activities were measured in the waters and sediment of the southeastern Bering Sea shelf to evaluate the use of radon as a tracer of gas exchange, water column mixing and sediment-water exchange. Cross-shelf distributions of 222 Rn and 226 Ra are presented. Gas transfer coefficients were estimated using near-surface 222 Rn deficiency measurements. A statistically significant linear relationship between averaged wind speed and transfer coefficient was found. Vertical eddy diffusivities were evaluated by applying a one-dimensional model to near-bottom excess 222 Rn distributions; these diffusivities were compared to independently determined values. The one-dimensional model applied to the near-bottom 222 Rn data was found to be inadequate and a two-dimensional model was applied to improve the fit between model and data. Exchange across the sediment-water interface was computed from the deficiency of 222 Rn measured in sediment cores, standing crop estimates of excess 222 Rn in the water column and 222 Rn production rates of sediment surface grab samples. Biological irrigation of the sediments appeared to be the primary exchange mechanism between the sediment and water columns. Distributions in the water column showed finestructure reported previously and suggested biological removal of 226 Ra. (author)

Effects of electron beam irradiated natural casings on the quality properties and shelf stability of emulsion sausage

International Nuclear Information System (INIS)

Kim, Hyun-Wook; Choi, Ji-Hun; Choi, Yun-Sang; Kim, Hack-Youn; Hwang, Ko-Eun; Song, Dong-Heon; Lee, Ju-Woon; Kim, Cheon-Jei

2012-01-01

The effect of electron beam irradiated hog and sheep casings (1, 3, and 8 kGy) on the physicochemical properties and shelf stability of emulsion sausage was evaluated. There were no significant differences in pH, instrumental color, sensory properties (overall acceptability), and hardness between all the samples. The cooking yields for the irradiated treated samples were larger than that of the yields obtained for the non-irradiated samples for both the hog and sheep casing. The irradiated natural casings accelerated lipid oxidation, and inhibited the formation of volatile basic nitrogen and the increase in total aerobic bacteria. In conclusion, the natural casings irradiated below at a dose of 3 kGy had no effect on physicochemical and sensory properties of the emulsion sausages, however, that improved the shelf-stability over 5 weeks. Therefore, natural casings irradiated at moderate doses are suitable for sausage production. - Highlights: ► The effect of E-beam irradiated natural casings on sausage quality was evaluated. ► The use of irradiated casings improved shelf stability of sausage. ► Natural casings irradiated below 3 kGy are suitable for sausage production.

Cross-shelf transport into nearshore waters due to shoaling internal tides in San Pedro Bay, CA

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Noble, Marlene A.; Burt Jones,; Peter Hamilton,; Xu, Jingping; George Robertson,; Rosenfeld, Leslie; John Largier,

2009-01-01

In the summer of 2001, a coastal ocean measurement program in the southeastern portion of San Pedro Bay, CA, was designed and carried out. One aim of the program was to determine the strength and effectiveness of local cross-shelf transport processes. A particular objective was to assess the ability of semidiurnal internal tidal currents to move suspended material a net distance across the shelf. Hence, a dense array of moorings was deployed across the shelf to monitor the transport patterns associated with fluctuations in currents, temperature and salinity. An associated hydrographic program periodically monitored synoptic changes in the spatial patterns of temperature, salinity, nutrients and bacteria. This set of measurements show that a series of energetic internal tides can, but do not always, transport subthermocline water, dissolved and suspended material from the middle of the shelf into the surfzone. Effective cross-shelf transport occurs only when (1) internal tides at the shelf break are strong and (2) subtidal currents flow strongly downcoast. The subtidal downcoast flow causes isotherms to tilt upward toward the coast, which allows energetic, nonlinear internal tidal currents to carry subthermocline waters into the surfzone. During these events, which may last for several days, the transported water remains in the surfzone until the internal tidal current pulses and/or the downcoast subtidal currents disappear. This nonlinear internal tide cross-shelf transport process was capable of carrying water and the associated suspended or dissolved material from the mid-shelf into the surfzone, but there were no observation of transport from the shelf break into the surfzone. Dissolved nutrients and suspended particulates (such as phytoplankton) transported from the mid-shelf into the nearshore region by nonlinear internal tides may contribute to nearshore algal blooms, including harmful algal blooms that occur off local beaches.

Seasonal and inter-annual temperature variability in the bottom waters over the Black Sea shelf

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Shapiro, G. I.; Wobus, F.; Aleynik, D. L.

2011-02-01

Long-term changes in the state of the Bottom Shelf Water (BSW) on the Western shelf of the Black Sea are assessed using analysis of intra- and inter-annual variations of temperature as well as their relations to physical parameters of both shelf and deep-sea waters. First, large data sets of in-situ observations over the 20th century are compiled into high-resolution monthly climatology at different depth levels. Then, the temperature anomalies from the climatic mean are calculated and aggregated into spatial compartments and seasonal bins to reveal temporal evolution of the BSW. For the purpose of this study the BSW is defined as such shelf water body between the seabed and the upper mixed layer (bounded by the σθ = 14.2 isopycnal) which has limited ability to mix vertically with oxygen-rich surface waters during the warm season (May-November) due to the formation of a seasonal pycnocline. The effects of atmospheric processes at the surface on the BSW are hence suppressed as well as the action of the "biological pump". The vertical extent of the near- bottom waters is determined based on energy considerations and the structure of the seasonal pycnocline, whilst the horizontal extent is controlled by the shelf break, where strong along-slope currents hinder exchanges with the deep sea. The BSW is shown to occupy nearly half of the area of the shelf during the summer stratification period. The potential of the BSW to ventilate horizontally during the warm season with the deep-sea waters is assessed using isopycnic analysis of temperature variations. A long-term time series of temperature anomalies in the BSW is constructed from observations during the May-November period for the 2nd half of the 20th century. The results reveal a warm phase in the 1960s/70s, followed by cooling of the BSW during 1980-2001. The transition between the warm and cold periods coincides with a regime shift in the Black Sea ecosystem. While it was confirmed that the memory of winter

Formation waters of the Norwegian Continental Shelf

Energy Technology Data Exchange (ETDEWEB)

McCartney, R. A.; Rein, E.

2006-03-15

New and previously published analyses of formation waters for the Norwegian Continental Shelf (NCS) have been evaluated and interpreted to determine the compositional distribution of formation waters in the region and factors controlling their compositions, and also to obtain information on subsurface fluid flow. Formation waters in the region are Na-Cl and Na-Ca-Cl-type waters that display a wide range of salinity (2500-212000 mg/kg Cl). Generally, the concentrations of most dissolved constituents are positively correlated with Cl so that their distribution in formation waters largely reflects the variations shown by salinity. Exceptions are SO4 which is generally low (less than 40 mg/l) regardless of Cl, and HCO3 and in-situ pH which are negatively correlated with Cl. The main factors determining the compositions of the formation waters are mixing of meteoric water (probably late-Jurassic to Eocene), ancient seawater and primary brine together with diagenetic reactions that have affected each of these components individually as well as mixtures of them. Evaluation of the distribution of salinity has helped us identify where vertical and/or lateral migration of brine from the evaporites has occurred. This has in turn provided us with information on the presence of leak-points and vertical mixing, although further investigation of the location of evaporites and basin palaeohydrogeology are required to determine whether regional lateral advection has occurred in the past. The results of this study may benefit oil exploration and production activities in the NCS including constraint of hydrocarbon migration models, economic evaluation of undrilled prospects, scale management and compartmentalisation studies. (Author)

Trace metal fronts in European shelf waters

International Nuclear Information System (INIS)

Kremling, K.

1983-01-01

The Hebrides shelf edge area is characterized by strong horizontal salinity gradients (fronts) which mark the boundary between Scottish coastal and oceanic waters. The results presented here, obtained in summer 1981 on a transect between the open north Atlantic and the German Bight, confirm that the hydrographical front is accompanied by dramatic increases in inorganic nutrients (phosphate, silicate) and dissolved trace elements such as Cd, Cu, Mn, and 226 Ra. These data (together with measurements from North Sea regions) suggest that the trace metals are mobilized from partly reduced (organic-rich) sediments and vertically mixed into the surface waters. The regional variations evident from the transect are interpreted as being the result of the hydrography prevailing in waters around the British Isles. (author)

Hammerhead ribozyme activity and oligonucleotide duplex stability in mixed solutions of water and organic compounds

Directory of Open Access Journals (Sweden)

Shu-ichi Nakano

2014-01-01

Full Text Available Nucleic acids are useful for biomedical targeting and sensing applications in which the molecular environment is different from that of a dilute aqueous solution. In this study, the influence of various types of mixed solutions of water and water-soluble organic compounds on RNA was investigated by measuring the catalytic activity of the hammerhead ribozyme and the thermodynamic stability of an oligonucleotide duplex. The compounds with a net neutral charge, such as poly(ethylene glycol, small primary alcohols, amide compounds, and aprotic solvent molecules, added at high concentrations changed the ribozyme-catalyzed RNA cleavage rate, with the magnitude of the effect dependent on the NaCl concentration. These compounds also changed the thermodynamic stability of RNA base pairs of an oligonucleotide duplex and its dependence on the NaCl concentration. Specific interactions with RNA molecules and reduced water activity could account for the inhibiting effects on the ribozyme catalysis and destabilizing effects on the duplex stability. The salt concentration dependence data correlated with the dielectric constant, but not with water activity, viscosity, and the size of organic compounds. This observation suggests the significance of the dielectric constant effects on the RNA reactions under molecular crowding conditions created by organic compounds.

Stabilization and activation of alpha-chymotrypsin in water-organic solvent systems by complex formation with oligoamines.

Science.gov (United States)

Kudryashova, Elena V; Artemova, Tatiana M; Vinogradov, Alexei A; Gladilin, Alexander K; Mozhaev, Vadim V; Levashov, Andrey V

2003-04-01

Formation of enzyme-oligoamine complexes was suggested as an approach to obtain biocatalysts with enhanced resistance towards inactivation in water-organic media. Complex formation results in broadening (by 20-40% v/v ethanol) of the range of cosolvent concentrations where the enzyme retains its catalytic activity (stabilization effect). At moderate cosolvent concentrations (20-40% v/v) complex formation activates the enzyme (by 3-6 times). The magnitude of activation and stabilization effects increases with the number of possible electrostatic contacts between the protein surface and the molecules of oligoamines (OA). Circular dichroism spectra in the far-UV region show that complex formation stabilizes protein conformation and prevents aggregation in water-organic solvent mixtures. Two populations of the complexes with different thermodynamic stabilities were found in alpha-chymotrypsin (CT)-OA systems depending on the CT/OA ratio. The average dissociation constants and stoichiometries of both low- and high-affinity populations of the complexes were estimated. It appears that it is the low-affinity sites on the CT surface that are responsible for the activation effect.

Effects of energy-related activities on the Atlantic Continental Shelf

Energy Technology Data Exchange (ETDEWEB)

Manowitz, B [ed.

1975-01-01

Sixteen papers were presented and are announced separately. Coastal waters, continental shelf geology and aquatic ecosystems are studied for modelling basic data for assessment of possible environmental impacts from offshore energy development. Sediment transport and wave phenomena are modelled for understanding water pollution transport and diffusion. (PCS)

Shelf life prediction of apple brownies using accelerated method

Science.gov (United States)

Pulungan, M. H.; Sukmana, A. D.; Dewi, I. A.

2018-03-01

The aim of this research was to determine shelf life of apple brownies. Shelf life was determined with Accelerated Shelf Life Testing method and Arrhenius equation. Experiment was conducted at 25, 35, and 45°C for 30 days. Every five days, the sample was analysed for free fatty acid (FFA), water activity (Aw), and organoleptic acceptance (flavour, aroma, and texture). The shelf life of the apple brownies based on FFA were 110, 54, and 28 days at temperature of 25, 35, and 45°C, respectively.

Transport and transfer rates in the waters of the continental shelf. Annual report

International Nuclear Information System (INIS)

Biscaye, P.E.; Broecker, W.S.; Feely, H.W.; Gerard, R.D.

1976-04-01

The report is to the Energy Research and Development Administration on accomplishments of the Lamont-Doherty Geological Observatory geochemistry and physical oceanography groups during the 1975-1976 funding period on grant E(11-1)2185. Goals are to obtain detailed, quantitative knowledge of the rates of mixing within coastal waters of the New York Bight and across the continental slope and the exchange of water masses and species transported within them between shelf and Atlantic Ocean waters. The research is aimed at understanding the chemical, physical, and biological processes which control the origin, dispersal, and fate of particulate matter and trace metals, and to ultimately model the impact of energy related pollutants on the continental shelf

Distribution of Upper Circumpolar Deep Water on the warming continental shelf of the West Antarctic Peninsula

Science.gov (United States)

Couto, Nicole; Martinson, Douglas G.; Kohut, Josh; Schofield, Oscar

2017-07-01

We use autonomous underwater vehicles to characterize the spatial distribution of Upper Circumpolar Deep Water (UCDW) on the continental shelf of the West Antarctic Peninsula (WAP) and present the first near-synoptic measurements of mesoscale features (eddies) containing UCDW on the WAP. Thirty-three subsurface eddies with widths on the order of 10 km were detected during four glider deployments. Each eddy contributed an average of 5.8 × 1016 J to the subpycnocline waters, where a cross-shelf heat flux of 1.37 × 1019 J yr-1 is required to balance the diffusive loss of heat to overlying winter water and to the near-coastal waters. Approximately two-thirds of the heat coming onto the shelf diffuses across the pycnocline and one-third diffuses to the coastal waters; long-term warming of the subpycnocline waters is a small residual of this balance. Sixty percent of the profiles that contained UCDW were part of a coherent eddy. Between 20% and 53% of the lateral onshore heat flux to the WAP can be attributed to eddies entering Marguerite Trough, a feature in the southern part of the shelf which is known to be an important conduit for UCDW. A northern trough is identified as additional important location for eddy intrusion.

The nepheloid bottom layer and water masses at the shelf break of the western Ross Sea

Science.gov (United States)

Capello, Marco; Budillon, Giorgio; Cutroneo, Laura; Tucci, Sergio

2009-06-01

In the austral summers of 2000/2001 and 2002/2003 the Italian CLIMA Project carried out two oceanographic cruises along the northwestern margin of the Ross Sea, where the Antarctic Bottom Water forms. Here there is an interaction between the water masses on the sea floor of the outer shelf and slope with a consequent evolution of benthic nepheloid layers and an increase in total particulate matter. We observed three different situations: (a) the presence of triads (bottom structures characterized by a concomitant jump in turbidity, temperature, and salinity data) and high re-suspension phenomena related to the presence of the Circumpolar Deep Water and its mixing with cold, salty shelf waters associated with gravity currents; (b) the absence of triads with high re-suspension, implying that when the gravity currents are no longer active the benthic nepheloid layer may persist until the suspended particles settle to the sea floor, suggesting that the turbidity data can be used to study recent gravity current events; and (c) the absence of turbidity and sediment re-suspension phenomena supports the theory that a steady situation had been re-established and the current interaction no longer occurred or had finished sometime before.

Effects of electron beam irradiated natural casings on the quality properties and shelf stability of emulsion sausage

Science.gov (United States)

Kim, Hyun-Wook; Choi, Ji-Hun; Choi, Yun-Sang; Kim, Hack-Youn; Hwang, Ko-Eun; Song, Dong-Heon; Lee, Ju-Woon; Kim, Cheon-Jei

2012-05-01

The effect of electron beam irradiated hog and sheep casings (1, 3, and 8 kGy) on the physicochemical properties and shelf stability of emulsion sausage was evaluated. There were no significant differences in pH, instrumental color, sensory properties (overall acceptability), and hardness between all the samples. The cooking yields for the irradiated treated samples were larger than that of the yields obtained for the non-irradiated samples for both the hog and sheep casing. The irradiated natural casings accelerated lipid oxidation, and inhibited the formation of volatile basic nitrogen and the increase in total aerobic bacteria. In conclusion, the natural casings irradiated below at a dose of 3 kGy had no effect on physicochemical and sensory properties of the emulsion sausages, however, that improved the shelf-stability over 5 weeks. Therefore, natural casings irradiated at moderate doses are suitable for sausage production.

Observed vulnerability of Filchner-Ronne Ice Shelf to wind-driven inflow of warm deep water

Science.gov (United States)

Darelius, E.; Fer, I.; Nicholls, K. W.

2016-01-01

The average rate of melting at the base of the large Filchner-Ronne Ice Shelf in the southern Weddell Sea is currently low, but projected to increase dramatically within the next century. In a model study, melt rates increase as changing ice conditions cause a redirection of a coastal current, bringing warm water of open ocean origin through the Filchner Depression and into the Filchner Ice Shelf cavity. Here we present observations from near Filchner Ice Shelf and from the Filchner Depression, which show that pulses of warm water already arrive as far south as the ice front. This southward heat transport follows the eastern flank of the Filchner Depression and is found to be directly linked to the strength of a wind-driven coastal current. Our observations emphasize the potential sensitivity of Filchner-Ronne Ice Shelf melt rates to changes in wind forcing. PMID:27481659

Seasonal and inter-annual temperature variability in the bottom waters over the western Black Sea shelf

Directory of Open Access Journals (Sweden)

G. I. Shapiro

2011-09-01

Full Text Available Long-term changes in the state of the Bottom Shelf Water (BSW on the Western shelf of the Black Sea are assessed using analysis of intra-seasonal and inter-annual temperature variations. For the purpose of this study the BSW is defined as such shelf water mass between the seabed and the upper mixed layer (bounded by the σ_θ = 14.2 isopycnal which has limited ability to mix vertically with oxygen-rich surface waters during the warm season due to formation of a seasonal pycnocline. A long-term time series of temperature anomalies in the BSW is constructed from in-situ observations taken over the 2nd half of the 20th century. The BSW is shown to occupy nearly half of the shelf area during the summer stratification period (May–November.The results reveal a warm phase in the 1960s/70s, followed by a cold phase between 1985 and 1995 and a further warming after 1995. The transition between the warm and cold periods coincides with a regime shift in the Black Sea ecosystem. While it was confirmed that the memory of winter convection is well preserved over the following months in the deep sea, the signal of winter cooling in the BSW significantly reduces during the warm season. The potential of the BSW to ventilate horizontally during the warm season with the deep-sea waters is assessed using isopycnic analysis of temperature variations. It is shown that temperature in the BSW is stronger correlated with the temperature of Cold Intermediate Waters (CIW in the deep sea than with the severity of the previous winters, thus indicating that the isopycnal exchanges with the deep sea are more important for inter-annual/inter-decadal variability of the BSW on the western Black Sea shelf than effects of winter convection on the shelf itself.

Food supply mechanisms for cold-water corals along a continental shelf edge

Science.gov (United States)

Thiem, Øyvind; Ravagnan, Elisa; Fosså, Jan Helge; Berntsen, Jarle

2006-05-01

In recent years it has been documented that deep-water coral reefs of the species Lophelia pertusa are a major benthic habitat in Norwegian waters. However, basic information about the biology and ecology of this species is still unknown. Lophelia live and thrive under special environmental conditions of which factors such as temperature, water depth, water movement and food supply are important. The present work explores the hypothesis that Lophelia forms reefs in places where the encounter rate of food particles is sufficiently high and stable over long periods of time for continuous growth. This is done by relating the distribution of reefs with the results of numerical ocean modelling. Numerical simulations have been performed with an idealized bottom topography similar to what is found outside parts of the Norwegian coast. In the simulations the model is first forced with an along slope jet and then with an idealized atmospheric low pressure. The model results show that the encounter rates between the particles and the water layer near the seabed are particularly high close to the shelf break. This may indicate that many Lophelia reefs are located along the shelf edges because the supply of food is particularly good in these areas. A sensitivity study of the particle supply in the area close to the seabed for increasing latitude has also been done. This shows that the Ekman transport in the benthic layer tends to create a steady supply of food for benthic organisms near the shelf edge away from the equator.

Export of a Winter Shelf Phytoplankton Bloom at the Shelf Margin of Long Bay (South Atlantic Bight, USA)

Science.gov (United States)

Nelson, J.; Seim, H.; Edwards, C. R.; Lockhart, S.; Moore, T.; Robertson, C. Y.; Amft, J.

2016-02-01

A winter 2012 field study off Long Bay (seaward of Myrtle Beach, South Carolina) investigated exchange processes along the shelf margin. Topics addressed included mechanisms of nutrient input (upper slope to outer shelf), phytoplankton blooms and community characteristics (mid-to-outer shelf), and possible export of shelf bloom material (transport to and across the shelf break to the upper slope). Observations utilized three moorings (mid-shelf, shelf break, upper slope), two gliders and ship operations (repeat cruises with profiling, water sampling and towed body surveys) along with satellite SST and ocean color imagery and near-by NOAA buoy records. Here we focus on the late January to early February period, when a mid-shelf bloom of Phaeocystis globosa (which forms large gelatinous colonies) was transported to the shelf break. The presence of Phaeocystis colonies resulted in strong spiking in chlorophyll (chl) fluorescence profiles. A partitioning approach was adapted to estimate chl in colonies (spikes) and small forms (baseline signal) and to account for an apparent difference in measured in vivo fluorescence per unit chl (lower in colonies). Up to 40-50% of chl in the bloom (surface to bottom on the mid-shelf) was estimated to be in the colonies. In late January, there a pronounced seaward slumping of relatively dense mid-shelf water along the bottom under warmer surface water derived from the inshore edge of a broad jet of Gulf Stream water flowing southwestward along the upper slope. We describe the evolution of this event and the conditions which set up this mechanism for episodic near-bed transport of fresh bloom material produced on the shelf to the upper slope off Long Bay. Down-slope transport may have been enhanced in this case by the high phytoplankton biomass in gelatinous colonies, which appeared to be settling in the water column on the shelf prior to the transport event.

The European water framework directive: A challenge for nearshore, coastal and continental shelf research

Science.gov (United States)

Borja, Ángel

2005-09-01

The European Water Framework Directive (WFD) establishes a framework for the protection of groundwater, inland surface waters, estuarine waters, and coastal waters. The WFD constitutes a new view of the water resources management in Europe because, for the first time, water management is: (i) based mainly upon biological and ecological elements, with ecosystems being at the centre of the management decisions; (ii) applied to European water bodies, as a whole; and (iii) based upon the whole river basin, including also the adjacent coastal area. Although the marine water bodies affected by the WFD relate to only 19.8% of the whole of the European continental shelf, its application constitutes a challenge and an opportunity in nearshore, coastal and continental shelf research. This contribution highlights some of the main tasks and the research to be undertaken in the coming years, proposing investigations into: typologies; physico-chemical processes; indicator species; reference conditions; integration of the quality assessment; methodologies in determining ecological status, etc.

Surface and Subsurface Meltwater Ponding and Refreezing on the Bach Ice Shelf, Antarctic Peninsula

Science.gov (United States)

Willis, I.; Haggard, E.; Benedek, C. L.; MacAyeal, D. R.; Banwell, A. F.

2017-12-01

There is growing concern about the stability and fate of Antarctic ice shelves, as four major ice shelves on the Antarctic Peninsula have completely disintegrated since the 1950s. Their collapse has been linked to the southward movement of the -9 oC mean annual temperature isotherm. The proximal causes of ice shelf instability are not fully known, but an increase in surface melting leading to water ponding and ice flexure, fracture and calving has been implicated. Close to the recently collapsed Wilkins Ice Shelf, the Bach Ice Shelf (72°S 72°W) may be at risk from break up in the near future. Here, we document the changing surface hydrology of the Bach Ice Shelf between 2001 and 2017 using Landsat 7 & 8 imagery. Extensive surface water is identified across the Bach Ice Shelf and its tributary glaciers. Two types of drainage system are observed, drainage into firn via simple stream networks and drainage into the ocean via more complex networks. There are differences between the surface hydrology on the ice shelf and the tributary glaciers, as well as variations within and between summer seasons linked to surface air temperature fluctuations. We also document the changing subsurface hydrology of the ice shelf between 2014 and 2017 using Sentinel 1 A/B SAR imagery. Forty-five subsurface features are identified and analysed for their patterns and temporal evolution. Fourteen of the features show similar characteristics to previously-identified buried lakes and some occur in areas associated with surface lakes in previous years. The buried lakes show seasonal variability in area and surface backscatter, which varies with surface air temperature, and are consistent with the presence, enlargement and contraction of liquid water bodies. Buried lakes are an overlooked source of water loading on ice shelves, which may contribute to ice shelf flexure and potential fracture.

Ice-Shelf Tidal Flexure and Subglacial Pressure Variations

Science.gov (United States)

Walker, Ryan T.; Parizek, Byron R.; Alley, Richard B.; Anandakrishnan, Sridhar; Riverman, Kiya L.; Christianson, Knut

2013-01-01

We develop a model of an ice shelf-ice stream system as a viscoelastic beam partially supported by an elastic foundation. When bed rock near the grounding line acts as a fulcrum, leverage from the ice shelf dropping at low tide can cause significant (approx 1 cm) uplift in the first few kilometers of grounded ice.This uplift and the corresponding depression at high tide lead to basal pressure variations of sufficient magnitude to influence subglacial hydrology.Tidal flexure may thus affect basal lubrication, sediment flow, and till strength, all of which are significant factors in ice-stream dynamics and grounding-line stability. Under certain circumstances, our results suggest the possibility of seawater being drawn into the subglacial water system. The presence of sea water beneath grounded ice would significantly change the radar reflectivity of the grounding zone and complicate the interpretation of grounded versus floating ice based on ice-penetrating radar observations.

Atlantic water variability on the SE Greenland continental shelf and its relationship to SST

Science.gov (United States)

Sutherland, D. A.; Straneo, F.; Rosing-Asvid, A.; Stenson, G.; Davidson, F. J.; Hammill, M.

2012-12-01

Interaction of warm, Atlantic-origin water (AW) and colder, polar origin water (PW) advecting southward in the East Greenland Current (EGC) influences the heat content of water entering Greenland's outlet glacial fjords. Here we use depth and temperature data derived from deep-diving seals to map out water mass variability across the continental shelf and to augment existing bathymetric products. We find two dominant modes in the vertical temperature structure: a cold mode, with the typical AW/PW layering observed in the EGC, and a warm mode, where AW is present throughout the water column. The prevalence of these modes varies seasonally and spatially across the continental shelf, implying distinct AW pathways. In addition, we find that satellite sea surface temperatures (SST) correlate significantly with temperatures in the upper 50 m (R=0.54), but this correlation decreases with depth (R=0.22 at 200 m), and becomes insignificant below 250 m. Thus, care must be taken in using SST as a proxy for heat content, as AW mainly resides in these deeper layers. Regional map showing the location of all seal tracks originating from Canada and Greenland (stars). Tracks passing inside (red) or outside (blue) the SE Greenland region (black) were subdivided into continental shelf regions (green boxes) near Sermilik Fjord (SF), Cape Farewell (CF) and Kangerdlugssuaq Fjord (KG). GEBCO bathymetry is contoured at 200, 1000, 2000, and 3000 m.

Oxidative stability and estimate of the shelf life of sacha inchi (Plukenetia volubilis L. oil

Directory of Open Access Journals (Sweden)

Gilbert Rodríguez

2015-09-01

Full Text Available Sacha inchi oil is rich in polyunsaturated fatty acids that may rust, limiting their shel flife. The Rancimat method is official, for evaluations of oxidative stability accelerated in oils. Industrially conventional techniques based on physical and chemical indicators are used; there are no studies of correlation between them and Rancimat. This work has for objective correlate the oxidative stability index (OSI Sacha inchi oil obtained by Rancimat at temperatures of 80°, 90°, 100° and 110 °C under an air flow of 15 L/h, with the values of physic-chemical indicators such as Index peroxide, p-anisidine, totox and density. Also estimated by mathematical extrapolation, the shelf life of sacha inchi oil to usual storage temperatures. OSI values were: 0.493 ± 0.01 h at 110 ºC, 1.590 ± 0.06 h at 100 ºC, 4.645 ± 0.1 h at 90 ºC and 20.512 ± 0.02 h at 80 ºC. High correlation has been established between values of OSI vs physicochemical quality indices (0.9322 < r < 0.9965. The activation energy was found 137.90 kJ/mol, which explains the high oxidative stability for the oil, estimating a lifetime of 3.29, 1.79 and 0.79 years at 20, 25 and 30 °C respectively.

Uranium geochemistry on the Amazon shelf: Evidence for uranium release from bottom sediments

International Nuclear Information System (INIS)

McKee, B.A.; DeMaster, D.J.; Nittrouer, C.A.

1987-01-01

In Amazon-shelf waters, as salinity increases to 36.5 x 10 -3 , dissolved uranium activities increase to a maximum of 4.60 dpm 1 -1 . This value is much higher than the open-ocean value (2.50 dpm 1 -1 ), indicating a source of dissolved uranium to shelf waters in addition to that supplied from open-ocean and riverine waters. Uranium activities are much lower for surface sediments in the Amazon-shelf sea bed (mean: 0.69 ± .09 dpm g -1 ) than for suspended sediments in the Amazon river (1.82 dpm g -1 ). Data suggest that the loss of particulate uranium from riverine sediments is probably the result of uranium desorption from the ferric-oxyhydroxide coatings on sediment particles, and/or uranium release by mobilization of the ferric oxyhydroxides. The total flux of dissolved 238 U from the Amazon shelf (about 1.2 x 10 15 dpm yr -1 ) constitutes about 15% of uranium input to the world ocean, commensurate to the Amazon River's contribution to world river-water discharge. Measurement of only the riverine flux of dissolved 238 U underestimates, by a factor of about 5, the flux of dissolved 238 U from the Amazon shelf to the open ocean

Impacts of Sea-Level Rise and Human Activity on a Tropical Continental Shelf, RN State, NE Brazil

Science.gov (United States)

Vital, H.; Barros Pereira, T. R.; Lira, H. F.; Tabosa, W. F.; Eichler, P.; Stattegger, K.; Sen Gupta, B. K.; Gomes, M. P.; Nogueira, M. L. D. S.; Pierri, G. C. S.

2014-12-01

The northeastern Brazilian, tropical coast-shelf system along the Atlantic Ocean is a sediment-starved zone, because of low relief, small drainage basins, and a semiarid climate. This work presents the major results of a study of environmental changes, particularly those related to Holocene sea-level rise, affecting the coast and shallow waters of Rio Grande do Norte (RN) State, NE Brazil. The methods included bottom-sediment characterization, bioindicator tracking, and integrated shallow-water geophysical investigation. This coastline is marked by active sea cliffs carved into tablelands alternating with reef- or dune-barrier sections, beach rocks and lagoons, whereas the shelf is a narrow, very shallow, and highly energetic system. Overall, the area is under the natural influence of tides (with a semidiurnal mesotidal regime) and the anthropogenic influence of salt exploration, oil industry, shrimp farms, tourism, and wind-farms. Sedimentation during the Holocene has been controlled mainly by sea-level variation, longshore currents, and the advance and westward propagation of active dunes along the coast. As in other areas around the world, growing numbers of permanent and seasonal residents choose to live at or near the ocean. Coastal erosion is a cause for concern along many Brazilian beaches, and several erosion hot spots are already recognized in RN State. Curves of Holocene relative sea-level variation were established for RN State, but the absence of long-term oceanographic observations in the last centuries or that of detailed altimetry maps hinders the evaluation of different risk scenarios at the local level. Nevertheless, impacts of the current sea-level rise and human activity can be observed along the RN coastal-shelf system. Particular aspects of the study, such as oil-spill monitoring, coastal-water sewage contamination, and coastal erosion, will be highlighted.

Physico-chemical properties of ready to eat, shelf-stable pasta during storage.

Science.gov (United States)

Carini, E; Curti, E; Cassotta, F; Najm, N E O; Vittadini, E

2014-02-01

The changes in physico-chemical properties of RTE shelf stable pasta were studied during storage with a multianalytical and multidimensional approach (with special focus on water status) to understand the ageing process in this product. Pasta hardness and amylopectin recrystallisation increased, macroscopic water status indicators and proton molecular translational mobility remained constant, and significant changes were measured in the proton rotational molecular mobility indicators ((1)H FID, (1)H T2) during storage. Since the main changes observed in RTE pasta during storage were similar to those observed in other cereal-based products, it would be interesting to verify the effect of the anti-staling methods commonly used in the cereal processing industry in improving RTE pasta shelf-stability. Copyright © 2013 Elsevier Ltd. All rights reserved.

Effect of water and gluten on physico-chemical properties and stability of ready to eat shelf-stable pasta.

Science.gov (United States)

Diantom, Agoura; Carini, Eleonora; Curti, Elena; Cassotta, Fabrizio; D'Alessandro, Alessandro; Vittadini, Elena

2016-03-15

A multi-analytical and multi-dimensional approach was used to investigate the effect of moisture and gluten on physico-chemical properties of shelf-stable ready to eat (RTE) pasta. Moisture and frozen water contents were not affected by formulation nor storage time. Hardness and retrograded amylopectin significantly increased during storage in all samples, more markedly in pasta with the lowest moisture content. Higher amounts of water and gluten reduced pasta hardening and contributed to control RTE pasta quality. (1)H FID became steeper in all samples during storage, but no effect of high moisture and gluten levels was observed on the mobility of these protons. Three proton T2 populations were observed (population C, population D and population E). Population C and D were not resolved during all storage. (1)H T2 relaxation time of the most abundant population (population E) shifted to shorter times and the amount of protons increased during storage, more importantly in the samples with lower moisture and gluten content. Copyright © 2015 Elsevier Ltd. All rights reserved.

Arctic Ocean outflow and glacier-ocean interactions modify water over the Wandel Sea shelf (northeastern Greenland)

DEFF Research Database (Denmark)

Dmitrenko, Igor A.; Kirillov, Sergey A.; Rudels, Bert

2017-01-01

The first-ever conductivity-temperature-depth (CTD) observations on the Wandel Sea shelf in northeastern Greenland were collected in April-May 2015. They were complemented by CTDs taken along the continental slope during the Norwegian FRAM 2014-2015 drift. The CTD profiles are used to reveal...... the origin of water masses and interactions with ambient water from the continental slope and the tidewater glacier outlet. The subsurface water is associated with the Pacific water outflow from the Arctic Ocean. The underlying halocline separates the Pacific water from a deeper layer of polar water that has...... interacted with the warm Atlantic water outflow through the Fram Strait, recorded below 140 m. Over the outer shelf, the halocline shows numerous cold density-compensated intrusions indicating lateral interaction with an ambient polar water mass across the continental slope. At the front of the tidewater...

Amazon water lenses and the influence of the North Brazil Current on the continental shelf

Science.gov (United States)

Prestes, Yuri O.; Silva, Alex Costa da; Jeandel, Catherine

2018-05-01

The exchange processes on the Amazon continental shelf in northern Brazil are subject to complex interactions that involve forcings derived from distinct sources. The Amazon shelf is a unique and highly dynamic environment in which considerable discharge of freshwater enters the Atlantic Ocean, producing extensive Amazon Water Lenses (AWL). In addition to the presence of the AWL, the shelf is influenced by the semidiurnal oscillations of the tides and the strong North Brazil Current (NBC), a boundary current of the western Atlantic. The present study was based primarily on the influence of the freshwater input and the NBC on the shelf and the Amazon Shelf Break (ASB) off the mouth of the Pará River. For this purpose, hydrographic and hydrodynamic data were obtained by moorings of the AMANDES Project (April-July 2008), located on the Amazon shelf and the ASB. Spectral analysis and the continuous wavelet transform were applied to define tidal (high frequency/short period) and subtidal (low frequency/long period) signals. The results indicated that on both the shelf and the break, the semidiurnal tides are responsible for the residual landward transport and are predominantly across-shelf. Low-frequency motions in the synoptic bands and the AWL are related to spatial changes in the velocity field, mainly on the ASB in the along-shelf direction. The flow of the NBC can be interpreted as an along-shelf low-frequency oscillation capable of altering the spatial configuration of the velocity field, although its influence is perceived only in the absence of the AWL.

Radium variability produced by shelf-water transport and mixing in the western Gulf of Mexico

International Nuclear Information System (INIS)

Reid, D.F.

1984-01-01

226 Ra and 228 Ra exhibit significant temporal and spatial variability in the near-surface western Gulf of Mexico. Concentrations of both isotopes during March 1976 were approx. 22 to 26% greater than those observed during February 1973. It is shown that analytical differences cannot account for this increase. Consideration of radium levels in the western Caribbean Sea indicates that there must be an internal source of radium that has a significant but temporally variable influence on near-surface radium concentrations in the western Gulf. Comparisons of radium, salinity, and temperature data from 1973 and 1976 provide evidence that advective transport and mixing of radium-rich shelf water with the interior water column of the western basin is responsible for the variability. By plotting 228 Ra vs 226 Ra from this region, estimates of the apparent shelf-water component in the upper water column can be made. The results indicate 36% over the northern slope, 10 to 18% in the central western Gulf, and 3 to 7% over Campeche Bank. In addition to explaining observed short-term variations of radium in this region, this information should be useful for environmental impact assessments concerned with industrial discharges on the northern shelf. (author)

One- and two-stage Arrhenius models for pharmaceutical shelf life prediction.

Science.gov (United States)

Fan, Zhewen; Zhang, Lanju

2015-01-01

One of the most challenging aspects of the pharmaceutical development is the demonstration and estimation of chemical stability. It is imperative that pharmaceutical products be stable for two or more years. Long-term stability studies are required to support such shelf life claim at registration. However, during drug development to facilitate formulation and dosage form selection, an accelerated stability study with stressed storage condition is preferred to quickly obtain a good prediction of shelf life under ambient storage conditions. Such a prediction typically uses Arrhenius equation that describes relationship between degradation rate and temperature (and humidity). Existing methods usually rely on the assumption of normality of the errors. In addition, shelf life projection is usually based on confidence band of a regression line. However, the coverage probability of a method is often overlooked or under-reported. In this paper, we introduce two nonparametric bootstrap procedures for shelf life estimation based on accelerated stability testing, and compare them with a one-stage nonlinear Arrhenius prediction model. Our simulation results demonstrate that one-stage nonlinear Arrhenius method has significant lower coverage than nominal levels. Our bootstrap method gave better coverage and led to a shelf life prediction closer to that based on long-term stability data.

Trophic Ecology and Movement Patters of Tiger Sharks (Galeocerdo Cuvier) off the Western North Atlantic Coastal and Continental Shelf Waters

Science.gov (United States)

Sancho, G.; Edman, R.; Frazier, B.; Bubley, W.

2016-02-01

Understanding the trophic dynamics and habitat utilization of apex predators is central to inferring their influence on different marine landscapes and to help design effective management plans for these animals. Tiger sharks (Galeocerdo cuvier) are abundant in shelf and offshore Gulf Stream waters of the western North Atlantic Ocean, and based on movements from individuals captured in Florida and Bahamas, seem to avoid coastal and shelf waters off South Carolina and Georgia. This contradicts reports of tiger sharks regularly being caught nearshore by anglers in these states, indicating that separate sub-populations may exist in the western North Atlantic. In the present study we captured Tiger Sharks in coastal waters off South Carolina in 2014 and 2015 in order to describe their movement patterns through acoustic and satellite tagging, and trophic dynamics through stable isotope analyses. Movement data show that these tiger sharks repeatedly visit particular inshore areas and mainly travel over the continental shelf, but rarely venture offshore beyond the continental shelf edge. Ongoing C and N stable isotope analyses of muscle, blood and skin tissues from adult and juvenile tiger sharks, as well as from potential prey species and primary producers, will help determine if their diets are based on inshore, shelf or offshore based food webs. Tiger sharks exploiting nearshore environments and shelf waters have much higher probabilities of interacting with humans than individuals occupying far offshore Gulf Stream habitats.

Transport and transfer rates in the waters of the continental shelf. Annual report

International Nuclear Information System (INIS)

Biscaye, P.E.

1980-09-01

The goal of govern project is to understand and quantify the processes that the transport and dispersal of energy-related pollutants introduced to the waters of the continental shelf and slope. The report is divided into sections dealing with processes associated with suspended solids; processes associated with sediments sinks for radionuclides and other pollutants; and spreading of water characteristics and species in solution

Changes in water mass exchange between the NW shelf areas and the North Atlantic and their impact on nutrient/carbon cycling

Science.gov (United States)

Gröger, Matthias; Maier-Reimer, Ernst; Mikolajewicz, Uwe; Segschneider, Joachim; Sein, Dimitry

2010-05-01

Despite their comparatively small extension on a global scale, shelf areas are of interest for several economic reasons and climatic processes related to nutrient cycling, sea food supply, and biological productivity. Moreover, they constitute an important interface for nutrients, pollutants and freshwater on their pathway from the continents to the open ocean. This modelling study aims to investigate the spatial and temporal variability of water mass exchange between the North Atlantic and the NW European shelf and their impact on nutrient/carbon cycling and biological productivity. For this, a new modeling approach has been set up which bridges the gap between pure shelf models where water mass transports across the model domain too strongly depend on the formulation of open boundaries and global models suffering under their too coarse resolution in shelf regions. The new model consists of the global ocean and carbon cycle model MPIOM/HAMOCC with strongly increased resolution in the North Sea and the North Atlantic coupled to the regional atmosphere model REMO. The model takes the full luni-solar tides into account. It includes further a 12 layer sediment module with the relevant pore water chemistry. The main focus lies on the governing mechanisms of water mass exchange across the shelf break and the imprint on shelf biogeochemistry. For this, artificial tracers with a prescribed decay rate have been implemented to distinguish waters arriving from polar and shelf regions and those that originate from the tropics. Experiments were carried out for the years 1948 - 2007. The relationship to larger scale circulation patterns like the position and variability of the subtropical and subpolar gyres is analyzed. The water mass exchange is analyzed with respect to the nutrient concentration and productivity on the European shelf areas. The implementation of tides leads to an enhanced vertical mixing which causes lower sea surface temperatures compared to simulations

Oil, gas potential in shallow water: Peru`s continental shelf basins

Energy Technology Data Exchange (ETDEWEB)

Zuniga-Rivero, F.; Keeling, J.A.; Hay-Roe, H. [BPZ and Associates Inc., Houston, TX (United States)

1998-11-16

This third article of a series highlights the three sedimentary basins that underlie the 16 million acres of continental shelf adjacent to a 650-mile stretch of Peruvian coastline. This area lies roughly between the ports of Chiclayo and Pisco. These basins offer a variety of reservoirs, traps, and source-rock potential in water depths of less than 1,000 ft. They are characterized by a thick sequence of Neogene strata, underlain by Paleogene, Mesozoic, and Upper Paleozoic sediments down to as much as 7 sec two-way time on modern seismic records. In some places the sedimentary section may reach an aggregate thickness in excess of 50,000 ft. From north to south these contiguous shelf basins are the Sechura-Salaverry, Huacho, and Pisco basins. All three basins are described.

Temporal variability of the Circumpolar Deep Water inflow onto the Ross Sea continental shelf

Science.gov (United States)

Castagno, Pasquale; Falco, Pierpaolo; Dinniman, Michael S.; Spezie, Giancarlo; Budillon, Giorgio

2017-02-01

The intrusion of Circumpolar Deep Water (CDW) is the primary source of heat, salt and nutrients onto Antarctica's continental shelves and plays a major role in the shelf physical and biological processes. Different studies have analyzed the processes responsible for the transport of CDW across the Ross Sea shelf break, but until now, there are no continuous observations that investigate the timing of the intrusions. Also, few works have focused on the effect of the tides that control these intrusions. In the Ross Sea, the CDW intrudes onto the shelf in several locations, but mostly along the troughs. We use hydrographic observations and a mooring placed on the outer shelf in the middle of the Drygalski Trough in order to characterize the spatial and temporal variability of CDW inflow onto the shelf. Our data span from 2004 to the beginning of 2014. In the Drygalski Trough, the CDW enters as a 150 m thick layer between 250 and 400 m, and moves upward towards the south. At the mooring location, about 50 km from the shelf break, two main CDW cores can be observed: one on the east side of the trough spreading along the west slope of Mawson Bank from about 200 m to the bottom and the other one in the central-west side from 200 m to about 350 m depth. A signature of this lighter and relatively warm water is detected by the instruments on the mooring at bottom of the Drygalski Trough. High frequency periodic CDW intrusion at the bottom of the trough is related to the diurnal and spring/neap tidal cycles. At lower frequency, a seasonal variability of the CDW intrusion is noticed. A strong inflow of CDW is observed every year at the end of December, while the CDW inflow is at its seasonal minimum during the beginning of the austral fall. In addition an interannual variability is also evident. A change of the CDW intrusion before and after 2010 is observed.

Limited contribution of ancient methane to surface waters of the U.S. Beaufort Sea shelf

Science.gov (United States)

Sparrow, Katy J.; Kessler, John D.; Southon, John R.; Garcia-Tigreros, Fenix; Schreiner, Kathryn M.; Ruppel, Carolyn D.; Miller, John B.; Lehman, Scott J.; Xu, Xiaomei

2018-01-01

In response to warming climate, methane can be released to Arctic Ocean sediment and waters from thawing subsea permafrost and decomposing methane hydrates. However, it is unknown whether methane derived from this sediment storehouse of frozen ancient carbon reaches the atmosphere. We quantified the fraction of methane derived from ancient sources in shelf waters of the U.S. Beaufort Sea, a region that has both permafrost and methane hydrates and is experiencing significant warming. Although the radiocarbon-methane analyses indicate that ancient carbon is being mobilized and emitted as methane into shelf bottom waters, surprisingly, we find that methane in surface waters is principally derived from modern-aged carbon. We report that at and beyond approximately the 30-m isobath, ancient sources that dominate in deep waters contribute, at most, 10 ± 3% of the surface water methane. These results suggest that even if there is a heightened liberation of ancient carbon–sourced methane as climate change proceeds, oceanic oxidation and dispersion processes can strongly limit its emission to the atmosphere.

Effects of high hydrostatic pressure on the overall quality of Pêra-Rio orange juice during shelf life.

Science.gov (United States)

Spira, Paz; Bisconsin-Junior, Antonio; Rosenthal, Amauri; Monteiro, Magali

2018-01-01

The effect of high hydrostatic pressure on antioxidant activity, total phenolic compounds, physicochemical characteristics, color, pectin methylesterase activity, and microbiological count were evaluated during the shelf life of Pêra-Rio orange juice. Pressurized (520 MPa, 60 ℃, for 360 s), non-processed and pasteurized (95 ℃/30 s) orange juice were compared at zero time of storage. Pressurized and pasteurized juices were studied during a refrigerated 90-day shelf life. Pressurization did not cause expressive change in physicochemical characteristics of Pêra-Rio orange juice along shelf life, but significantly reduced pectin methylesterase residual activity to 13% and microbiological counts below detection levels up to 68 days of storage, with small counts (30.0 × 10 CFU/mL mesophilic aerobic bacteria and 20.7 × 10 CFU/mL yeast and mold) at 90 days, capable of ensuring the juice's stability along shelf life. Lightness ( L*) and b* values were significantly reduced by high hydrostatic pressure during shelf life, while a* values were significantly higher. Ascorbic acid decreased around 80% during shelf life. Antioxidant activity remained stable after processing and during storage.

Transport and transfer rates in the waters of the Continental Shelf. Annual report

International Nuclear Information System (INIS)

Biscaye, P.E.

1978-07-01

The present contract year has been one of transition from an emphasis on field work and sample gathering to the predominance of sample and data analysis and the formulation of testable hypotheses concerning specific processes in the New York Bight. We have begun to understand the seasonal transition in the role of phytoplankton vs. grazing zooplankton in forming the particles on which some reactive pollutants are removed. Using natural radioactive tracers we have estimated the removal rates of reactive metals from the surface waters and these range over an order of magnitude from most rapid nearshore to least rapid over the upper continental slope. Once removed nearshore, however, these tracers, and the pollutants for which they proxy, do not remain permanently in the sediments but appear to be remobilized (probably by oxidation) during the winter and are reintroduced into the water column. Work on transport and mixing processes of pollutants which are or behave like those in solution has continued along several fronts. Hydrographic data on the structure of the water column continues to give a description of the system that is crucial to understanding geochemical and biological processes which affect pollutants. Hydrographic characterization of water masses from the data sets of cruises has resulted in hypotheses concerning the renewal of shelf water by direct exchange between shelf and upper slope water

Short communication: Effect of active food packaging materials on fluid milk quality and shelf life.

Science.gov (United States)

Wong, Dana E; Goddard, Julie M

2014-01-01

Active packaging, in which active agents are embedded into or on the surface of food packaging materials, can enhance the nutritive value, economics, and stability of food, as well as enable in-package processing. In one embodiment of active food packaging, lactase was covalently immobilized onto packaging films for in-package lactose hydrolysis. In prior work, lactase was covalently bound to low-density polyethylene using polyethyleneimine and glutaraldehyde cross-linkers to form the packaging film. Because of the potential contaminants of proteases, lipases, and spoilage organisms in typical enzyme preparations, the goal of the current work was to determine the effect of immobilized-lactase active packaging technology on unanticipated side effects, such as shortened shelf-life and reduced product quality. Results suggested no evidence of lipase or protease activity on the active packaging films, indicating that such active packaging films could enable in-package lactose hydrolysis without adversely affecting product quality in terms of dairy protein or lipid stability. Storage stability studies indicated that lactase did not migrate from the film over a 49-d period, and that dry storage resulted in 13.41% retained activity, whereas wet storage conditions enabled retention of 62.52% activity. Results of a standard plate count indicated that the film modification reagents introduced minor microbial contamination; however, the microbial population remained under the 20,000 cfu/mL limit through the manufacturer's suggested 14-d storage period for all film samples. This suggests that commercially produced immobilized lactase active packaging should use purified cross-linkers and enzymes. Characterization of unanticipated effects of active packaging on food quality reported here is important in demonstrating the commercial potential of such technologies. Copyright © 2014 American Dairy Science Association. Published by Elsevier Inc. All rights reserved.

Hydrography and chlorophyll a in a transect from the coast to the shelf-break in the Argentinian Sea

Science.gov (United States)

Carreto, JoséI.; Lutz, Vivian A.; Carignan, Marco O.; Cucchi Colleoni, Angel D.; De Marco, Silvia G.

1995-03-01

On the basis of data obtained during eight research cruises from a section of the Buenos Aires province shelf, three systems are characterized: (1) coastal system; (2) subantarctic shelf waters system; and (3) Malvinas system. These domains are frequently separated by two quasipermanent fronts: (1) the coastal front; and (2) the shelf-break front. The patterns of seasonal variation of phytoplankton biomass in these systems are strongly related to changes in vertical stability, that controls the availability of nutrients and light energy. In the coastal system, the mixing produced by winds and tides gives homogenenous waters all year round, having the lowest nitrate concentration and the lowest N:P ratio. The amplitude of the seasonal variation of chlorophyll was relatively small, although the highest concetrations were detected in spring and autumn. The subantarctic shelf waters system is characterized by the typical development and breakdown cycle of the seasonal thermocline. Two well defined chlorophyll a maxima are observed: the main peak during spring and the secondary one during autumn. Geographical differences occur in the timing of the development and breakdown of the thermocline. Another factor of variability is the advection of low salinity waters from the coastal region of the Rio de la Plata during spring. During winter, when nutrient concentration is the highest, an increasing nitrate gradient from the coastal front to the shelf-break region is observed. During summer, surface nitrate concentration is low over the whole continental shelf, and the highest chlorophyll a concentrations are associated with the depth of the pycnocline. However, associated with the surface nitrate maximum, chlorophyll a values higher than 2 mg m -3 are recorded at the shelf-break front. The observed surface maxima are thought to be related to physical processes associated with the slope, where the enhanced mixing results in nutrient renewal and subsequent phytoplankton growth

Downslope flow across the Ross Sea shelf break (Antarctica)

Science.gov (United States)

Bergamasco, A.; Budillon, G.; Carniel, S.; Defendi, V.; Meloni, R.; Paschini, E.; Sclavo, M.; Spezie, G.

2003-12-01

The analysis of some high-resolution hydrological data sets acquired during the 1997, 1998, 2001 and 2003 austral summers across the Ross Sea continental shelf break are here presented. The main focus of these cruises carried out in the framework of the Italian National Antarctic Program was the investigation of the downslope flow of the dense waters originated inside the Ross Sea. Such dense waters, flow near the bottom and, reaching the continental shelf break, ventilate the deep ocean. Two Antarctic continental shelf mechanisms can originate dense and deep waters. The former mechanism involves the formation, along the Victoria Land coasts, of a dense and saline water mass, the High Salinity Shelf Water (HSSW). The HSSW formation is linked to the rejection of salt into the water column as sea ice freezes, especially during winter, in the polynya areas, where the ice is continuously pushed offshore by the strong katabatic winds. The latter one is responsible of the formation of a supercold water mass, the Ice Shelf Water (ISW). The salt supplied by the HSSW recirculated below the Ross Ice Shelf, the latent heat of melting and the heat sink provided by the Ross Ice Shelf give rise to plumes of ISW, characterized by temperatures below the sea-surface freezing point. The dense shelf waters migrate to the continental shelf-break, spill over the shelf edge and descend the continental slope as a shelf-break gravity current, subject to friction and possibly enhanced by topographic channelling. Friction, in particular, breaks the constraint of potential vorticity conservation, counteracting the geostrophic tendency for along slope flow. The density-driven downslope motion or cascading entrains ambient water, namely the lower layer of the CDW, reaches a depth where density is the same and spreads off-slope. In fact, the cascading event is inhibited by friction without entrainment. The downslope processes are important for the ocean and climate system because they play a

Microbiological quality of soft, semi-hard and hard cheeses during the shelf-life

Directory of Open Access Journals (Sweden)

Josip Vrdoljak

2016-03-01

Full Text Available Cheeses as ready-to-eat food should be considered as a potential source of foodborne pathogens, primarily Listeria monocytogenes. The aim of present study was to determine the microbiological quality of soft, semi-hard and hard cheeses during the shelf-life, with particular reference to L. monocytogenes. Five types of cheeses were sampled at different timepoints during the cold storage and analyzed for presence of Salmonella and L. monocytogenes, as well as lactic acid bacteria, Escherichia coli, coagulase-positive staphylococci, yeasts, molds, sulfite-reducing clostridia and L. monocytogenes counts. Water activity, pH and NaCl content were monitored in order to evaluate the possibility of L. monocytogenes growth. Challenge test for L. monocytogenes was performed in soft whey cheese, to determine the growth potential of pathogen during the shelf-life of product. All analyzed cheeses were compliant with microbiological criteria during the shelf-life. In soft cheeses, lactic acid bacteria increased in the course of the shelf-life period (1.2-2.6 log increase, while in semi-hard and hard cheeses it decreased (1.6 and 5.2 log decrease, respectively. Soft cheeses support the growth of L. monocytogenes according to determined pH values (5.8-6.5, water activity (0.99-0.94, and NaCl content (0.3-1.2%. Challenge test showed that L. monocytogenes growth potential in selected soft cheese was 0.43 log10 cfu/g during 8 days at 4°C. Water activity in semi-hard and hard cheeses was a limiting factor for Listeria growth during the shelf-life. Soft, semi-hard and hard cheeses were microbiologically stable during their defined shelf-life. Good manufacturing and hygienic practices must be strictly followed in the production of soft cheeses as Listeria-supporting food and be focused on preventing (recontamination.

Cold shock treatment extends shelf life of naturally ripened or ethylene-ripened avocado fruits.

Science.gov (United States)

Chen, Jiao; Liu, Xixia; Li, Fenfang; Li, Yixing; Yuan, Debao

2017-01-01

Avocado is an important tropical fruit with high commercial value, but has a relatively short storage life. In this study, the effects of cold shock treatment (CST) on shelf life of naturally ripened and ethylene-ripened avocado fruits were investigated. Fruits were immersed in ice water for 30 min, then subjected to natural or ethylene-induced ripening. Fruit color; firmness; respiration rate; ethylene production; and the activities of polygalacturonase (PG), pectin methylesterase (PME), and endo-β-1,4-glucanase were measured. Immersion in ice water for 30 min effectively delayed ripening-associated processes, including peel discoloration, pulp softening, respiration rate, and ethylene production during shelf life. The delay in fruit softening by CST was associated with decreased PG and endo-β-1,4-glucanase activities, but not PME activity. This method could potentially be a useful postharvest technology to extend shelf life of avocado fruits.

Biological, physical and chemical properties at the Subtropical Shelf Front Zone in the SW Atlantic Continental Shelf

Science.gov (United States)

Muelbert, José H.; Acha, Marcelo; Mianzan, Hermes; Guerrero, Raúl; Reta, Raúl; Braga, Elisabete S.; Garcia, Virginia M. T.; Berasategui, Alejandro; Gomez-Erache, Mónica; Ramírez, Fernando

2008-07-01

The physical aspects of the Subtropical Shelf Front (STSF) for the Southwest Atlantic Continental Shelf were previously described. However, only scarce data on the biology of the front is available in the literature. The main goal of this paper is to describe the physical, chemical and biological properties of the STSF found in winter 2003 and summer 2004. A cross-section was established at the historically determined location of the STSF. Nine stations were sampled in winter and seven in summer. Each section included a series of conductivity-temperature-depth (CTD) stations where water samples from selected depths were filtered for nutrient determination. Surface samples were taken for chlorophyll a (Chl- a) determination and plankton net tows carried out above and below the pycnocline. Results revealed that winter was marked by an inner-shelf salinity front and that the STSF was located on the mid-shelf. The low salinity waters in the inner-shelf indicated a strong influence of freshwater, with high silicate (72 μM), suspended matter (45 mg l -1), phosphate (2.70 μM) and low nitrate (1.0 μM) levels. Total dissolved nitrogen was relatively high (22.98 μM), probably due to the elevated levels of organic compound contribution close to the continental margin. Surface Chl -a concentration decreased from coastal well-mixed waters, where values up to 8.0 mg m -3 were registered, to offshore waters. Towards the open ocean, high subsurface nutrients values were observed, probably associated to South Atlantic Central Waters (SACW). Zooplankton and ichthyoplankton abundance followed the same trend; three different groups associated to the inner-, mid- and outer-shelf region were identified. During summer, diluted waters extended over the shelf to join the STSF in the upper layer; the concentration of inorganic nutrients decreased in shallow waters; however, high values were observed between 40 and 60 m and in deep offshore waters. Surface Chl -a ranged 0.07-1.5 mg m -3

Stability of people exposed to water flows

Directory of Open Access Journals (Sweden)

E. Martínez-Gomariz

2016-01-01

Full Text Available Our cities are formed by several elements which are exposed to floods of a magnitude according to the importance of the rainfall event and the design of the urban drainage system. The most important components in the cities are the pedestrians who develop various activities during rain events. Focusing on pedestrians, the research on their stability when they are exposed to water flows provides the necessary knowledge to understand and manage the associated hazard for them. In this research, several experiments with humans were carried out in order to determine the stability limits to pedestrians crossing through a water flow in a real scale platform. The results obtained and by comparing those with human stability criteria proposed by other authors and guidelines provide a more restrictive criterion.

Carbon Monoxide Modified Atmosphere Packaging Beef Shelf Life Studies

Directory of Open Access Journals (Sweden)

Rini Ariani Basyamfar

2014-02-01

Full Text Available The combination of O2, CO2, and low concentrations of CO in CO-MAP has repeatedly been shown to increase the shelf-life of red meat products. Concentrations of CO2 of 30% has been shown to slow microbial growth while O2 preserves the natural color of red meat. The addition of low concentrations of CO (<0.4% preserves the color stability of the meat while allowing for lower levels of O2 which reduces the oxidative spoilage of the product. Shelf-life extension of 5 to 10 days above traditional MAP has been seen with CO-MAP technologies. The addition of active/smart films such as antimicrobial films and/or the combination of irradiation further extends the shelf-life of red meat. Undetectable levels of E. coli at storage temperatures as high as 10oC at 28 days have been shown with CO-MAP and irradiation.

Porosity and water activity effects on stability of crystalline β-carotene in freeze-dried solids.

Science.gov (United States)

Harnkarnsujarit, Nathdanai; Charoenrein, Sanguansri; Roos, Yrjö H

2012-11-01

Stability of entrapped crystalline β-carotene as affected by water activity, solids microstructure, and composition of freeze-dried systems was investigated. Aliquots (1000 mm(3) , 20% w/w solids) of solutions of maltodextrins of various dextrose equivalents (M040:DE6, M100:DE11, and M250:DE25.5), M100-sugars (1:1 glucose, fructose and sucrose), and agar for gelation with dispersed β-carotene were frozen at -20, -40, or -80 °C and freeze-dried. Glass transition and α-relaxation temperatures were determined with differential scanning calorimetry and dynamic mechanical analysis, respectively. β-Carotene contents were monitored spectrophotometrically. In the glassy solids, pore microstructure had a major effect on β-carotene stability. Small pores with thin walls and large surface area allowed β-carotene exposure to oxygen which led to a higher loss, whereas structural collapse enhanced stability of β-carotene by decreasing exposure to oxygen. As water plasticized matrices, an increase in molecular mobility in the matrix enhanced β-carotene degradation. Stability of dispersed β-carotene was highest at around 0.2 a(w) , but decreasing structural relaxation times above the glass transition correlated well with the rate of β-carotene degradation at higher a(w) . Microstructure, a(w) , and component mobility are important factors in the control of stability of β-carotene in freeze-dried solids. β-Carotene expresses various nutritional benefits; however, it is sensitive to oxygen and the degradation contributes to loss of nutritional values as well as product color. To increase stability of β-carotene in freeze-dried foods, the amount of oxygen penetration need to be limited. The modification of freeze-dried food structures, for example, porosity and structural collapse, components, and humidity effectively enhance the stability of dispersed β-carotene in freeze-dried solids. © 2012 Institute of Food Technologists®

Multi-Tracer Approach for Shelf Water Mixing Studies in Brazilian Regions under Different Climates

Energy Technology Data Exchange (ETDEWEB)

Lacerda, L. D.; Marins, R. V.; Dias, F. J.S. [Instituto de Ciencias do Mar, Universidate Federal do Ceara, Fortaleza, CE (Brazil); Godoy, M. L.D.P. [Instituto de Radioprotecao e Dosimetria, Comissao Nacional de Energia Nuclear, Rio de Janeiro, RJ (Brazil); Godoy, J. M.; Souza, T. A. [Departamento de Quimica, Pontificia Universidade Catolica, Rio de Janeiro, RJ (Brazil); Rezende, C. E. [Centro de Biociencias e Biotecnologia, Universidade Estadual do Norte Fluminense, Campos dos Goytacazes, RJ (Brazil)

2013-07-15

Fresh water and sediment supply at estuary and plume regions has dramatically changed due to land use changes, mostly damming, in river basins. The resulting impact, however, may vary significantly depending on climate and hydrology. The seasonal differences in shelf, plume, estuarine and river waters of two watersheds located under contrasting climates in the Brazilian coast are reported using a multi-tracer approach (salinity, barium, silica, uranium, deuterium and {sup 18}O) to characterize the mixing processes. At the Paraiba do Sul River, SE Brazil, in a wet tropical coast, all results showed similarity between dry and wet seasons; at the Jaguaribe river under semi arid climate in NE Brazil, the results showed a moving freshwater plume depending on season, with freshwater at the estuary in the rainy season and shelf water intrusion upstream in the estuary in the dry season. Most tracers used were able to consistently characterize water masses even in the wide range of latitudes studied, confirming their importance as a tool for modelling mixing processes at the continent-ocean boundary. Barium, however, still needs better studies on its seashore chemistry, since in the semi arid site, Ba distribution could not be directly related to conservative mixing behaviour, at least during the rainy season. (author)

Summertime calcium carbonate undersaturation in shelf waters of the western Arctic Ocean – how biological processes exacerbate the impact of ocean acidification

OpenAIRE

N. R. Bates; M. I. Orchowska; R. Garley; J. T. Mathis

2013-01-01

The Arctic Ocean accounts for only 4% of the global ocean area, but it contributes significantly to the global carbon cycle. Recent observations of seawater CO2-carbonate chemistry in shelf waters of the western Arctic Ocean, primarily in the Chukchi Sea, from 2009 to 2011 indicate that bottom waters are seasonally undersaturated with respect to calcium carbonate (CaCO3) minerals, particularly aragonite. Nearly 40% of sampled bottom waters on the shelf have saturation states...

Size-dependent photoacclimation of the phytoplankton community in temperate shelf waters (southern Bay of Biscay)

KAUST Repository

Á lvarez, E; Moran, Xose Anxelu G.; Ló pez-Urrutia, Á ; Nogueira, E

2015-01-01

© Inter-Research 2016. Shelf waters of the Cantabrian Sea (southern Bay of Biscay) are productive ecosystems with a marked seasonality. We present the results from 1 yr of monthly monitoring of the phytoplankton community together with an intensive sampling carried out in 2 contrasting scenarios during the summer and autumn in a mid-shelf area. Stratification was apparent on the shelf in summer, while the water column was comparatively well mixed in autumn. The size structure of the photoautotrophic community, from pico-to micro-phytoplankton, was tightly coupled with the meteo-climatic and hydrographical conditions. Over the short term, variations in the size structure and chlorophyll content of phytoplankton cells were related to changes in the physico-chemical environment, through changes in the availability of nutrients and light. Uncoupling between the dynamics of carbon biomass and chlorophyll resulted in chlorophyll to carbon ratios dependent on body size. The slope of the size dependence of chlorophyll content increased with increasing irradiance, reflecting different photoacclimation plasticity from pico-to micro-phytoplankton. The results have important implications for the productivity and the fate of biogenic carbon in this region, since the size dependence of photosynthetic rates is directly related to the size scaling of chlorophyll content.

Size-dependent photoacclimation of the phytoplankton community in temperate shelf waters (southern Bay of Biscay)

KAUST Repository

Álvarez, E

2015-12-09

© Inter-Research 2016. Shelf waters of the Cantabrian Sea (southern Bay of Biscay) are productive ecosystems with a marked seasonality. We present the results from 1 yr of monthly monitoring of the phytoplankton community together with an intensive sampling carried out in 2 contrasting scenarios during the summer and autumn in a mid-shelf area. Stratification was apparent on the shelf in summer, while the water column was comparatively well mixed in autumn. The size structure of the photoautotrophic community, from pico-to micro-phytoplankton, was tightly coupled with the meteo-climatic and hydrographical conditions. Over the short term, variations in the size structure and chlorophyll content of phytoplankton cells were related to changes in the physico-chemical environment, through changes in the availability of nutrients and light. Uncoupling between the dynamics of carbon biomass and chlorophyll resulted in chlorophyll to carbon ratios dependent on body size. The slope of the size dependence of chlorophyll content increased with increasing irradiance, reflecting different photoacclimation plasticity from pico-to micro-phytoplankton. The results have important implications for the productivity and the fate of biogenic carbon in this region, since the size dependence of photosynthetic rates is directly related to the size scaling of chlorophyll content.

On the shelf life of pharmaceutical products.

Science.gov (United States)

Capen, Robert; Christopher, David; Forenzo, Patrick; Ireland, Charles; Liu, Oscar; Lyapustina, Svetlana; O'Neill, John; Patterson, Nate; Quinlan, Michelle; Sandell, Dennis; Schwenke, James; Stroup, Walter; Tougas, Terrence

2012-09-01

This article proposes new terminology that distinguishes between different concepts involved in the discussion of the shelf life of pharmaceutical products. Such comprehensive and common language is currently lacking from various guidelines, which confuses implementation and impedes comparisons of different methodologies. The five new terms that are necessary for a coherent discussion of shelf life are: true shelf life, estimated shelf life, supported shelf life, maximum shelf life, and labeled shelf life. These concepts are already in use, but not named as such. The article discusses various levels of "product" on which different stakeholders tend to focus (e.g., a single-dosage unit, a batch, a production process, etc.). The article also highlights a key missing element in the discussion of shelf life-a Quality Statement, which defines the quality standard for all key stakeholders. Arguments are presented that for regulatory and statistical reasons the true product shelf life should be defined in terms of a suitably small quantile (e.g., fifth) of the distribution of batch shelf lives. The choice of quantile translates to an upper bound on the probability that a randomly selected batch will be nonconforming when tested at the storage time defined by the labeled shelf life. For this strategy, a random-batch model is required. This approach, unlike a fixed-batch model, allows estimation of both within- and between-batch variability, and allows inferences to be made about the entire production process. This work was conducted by the Stability Shelf Life Working Group of the Product Quality Research Institute.

Evolution of Meltwater on the McMurdo Ice Shelf, Antarctica During Two Summer Melt Seasons

Science.gov (United States)

Macdonald, G. J.; Banwell, A. F.; Willis, I.; Mayer, D. P.; Hansen, E. K.; MacAyeal, D. R.

2017-12-01

Ice shelves surround > 50% of Antarctica's coast and their response to climate change is key to the ice sheet's future and global sea-level rise. Observations of the development and drainage of 2750 lakes prior to the collapse of the Larsen B Ice Shelf, combined with our understanding of ice-shelf flexure/fracture, suggest that surface meltwater plays a key role in ice-shelf stability, although the present state of knowledge remains limited. Here, we report results of an investigation into the seasonal evolution of meltwater on the McMurdo Ice Shelf (MIS) during the 2015/16 and 2016/17 austral summers using satellite remote sensing, complemented by ground survey. Although the MIS is relatively far south (78° S), it experiences relatively high ablation rates in the west due to adiabatically warmed winds, making it a useful example of how meltwater could evolve on more southerly ice shelves in a warming climate. We calculate the areas and depths of ponded surface meltwater on the ice shelf at different stages of the two melt seasons using a modified NDWI approach and water-depth algorithm applied to both Landsat 8 and Worldview imagery. Data from two automatic weather stations on the ice shelf are used to drive a positive degree-day model to compare our observations of surface water volumes with modelled meltwater production. Results suggest that the spatial and temporal variations in surface meltwater coverage on the ice shelf vary not only with climatic conditions but also in response to other important processes. First, a rift that widens and propagates between the two melt seasons intercepts meltwater streams, redirecting flow and facilitating ponding elsewhere. Second, some lakes from previous years remain frozen over and become pedestalled, causing streams to divert around their perimeter. Third, surface debris conditions also cause large-scale spatial variation in melt rates and the flow and storage of water.

Sup(210)Pb and 210Po distributions and disequilibrium in the coastal and shelf waters of the southern North Sea

International Nuclear Information System (INIS)

Zhizheng, Zuo; Eisma, Doeke

1993-01-01

Concentration profiles of 210 Pb and 210 Po were measured at 10 stations in the coastal and shelf areas of the southern North Sea. Scavenging processes in this study area are revealed by 210 Po/ 210 Pb disequilibrium and their distributions in the water column. Results for 210 Po show strong excess, relative to 210 Pb, in both dissolved and particulate forms, indicating an additional flux of 210 Po from the coastal and shelf sediment. A significant maximum of the dissolved 210 Po and 210 Pb over the fine grained depositional area (Oyster Ground) was observed to correspond with resuspension of the underlying muddy sediments. A comparison of the data between the water and sediment columns shows that the excess of 210 Po found in the water body could be balanced by only a small amount of deficit of 210 Po in the sediment, due to the characteristics of this continental shelf area. (author)

The Effect of Alongcoast Advection on Pacific Northwest Shelf and Slope Water Properties in Relation to Upwelling Variability

Science.gov (United States)

Stone, Hally B.; Banas, Neil S.; MacCready, Parker

2018-01-01

The Northern California Current System experiences highly variable seasonal upwelling in addition to larger basin-scale variability, both of which can significantly affect its water chemistry. Salinity and temperature fields from a 7 year ROMS hindcast model of this region (43°N-50°N), along with extensive particle tracking, were used to study interannual variability in water properties over both the upper slope and the midshelf bottom. Variation in slope water properties was an order of magnitude smaller than on the shelf. Furthermore, the primary relationship between temperature and salinity anomalies in midshelf bottom water consisted of variation in density (cold/salty versus warm/fresh), nearly orthogonal to the anomalies along density levels (cold/fresh versus warm/salty) observed on the upper slope. These midshelf anomalies were well-explained (R2 = 0.6) by the combination of interannual variability in local and remote alongshore wind stress, and depth of the California Undercurrent (CUC) core. Lagrangian analysis of upper slope and midshelf bottom water shows that both are affected simultaneously by large-scale alongcoast advection of water through the northern and southern boundaries. The amplitude of anomalies in bottom oxygen and dissolved inorganic carbon (DIC) on the shelf associated with upwelling variability are larger than those associated with typical variation in alongcoast advection, and are comparable to observed anomalies in this region. However, a large northern intrusion event in 2004 illustrates that particular, large-scale alongcoast advection anomalies can be just as effective as upwelling variability in changing shelf water properties on the interannual scale.

Stability and activity of lysozyme in stoichiometric and non-stoichiometric protic ionic liquid (PIL)-water systems

Science.gov (United States)

Wijaya, Emmy C.; Separovic, Frances; Drummond, Calum J.; Greaves, Tamar L.

2018-05-01

There has been a substantial increase in enzyme applications within the biochemical and pharmaceutical industries, for example, as industrial biocatalysts. However, enzymes have narrow marginal stability which makes them prone to become inactive and/or denature with a slight change in the solvent environment. Typically industrial applications require harsher solvent environments than enzyme native environments, and hence there is a need to understand solvent-protein interactions in order to develop strategies to maintain, or enhance, the enzymatic activity under industrially relevant solvent conditions. Previously we have shown that protic ionic liquids (PILs) with water can have a stabilising effect on lysozyme, with a large variation dependent on which PIL ions are present, and the water concentration [E. C. Wijaya et al., Phys. Chem. Chem. Phys. 18(37), 25926-25936 (2016)]. Here we extend on this work using non-stoichiometric aqueous PIL solvents to investigate, and isolate, the role of pH and ionicity on enzymes. We have used the PILs ethylammonium nitrate (EAN) and ethanolammonium formate (EOAF) since our previous work has identified these as good solvents for lysozyme. Solvent libraries were made from these two PILs with an additional precursor acid or base to modify the acidity/basicity of the neutral stoichiometric PIL, and with water added, to have solutions with 4-17 mol. % of the PIL ions in water. Molar ratios of base:acid were varied between 1:1.05 and 2:1 for EAN and 1:1.25 and 2:1 for EOAF, which enabled from highly basic to highly acidic solutions to be obtained. This was to modify the acidity/basicity of the neutral stoichiometric PILs, without the addition of buffers. The structure and stability of hen egg white lysozyme (HEWL) were explored under these solvent conditions using synchrotron small angle X-ray scattering (SAXS), Fourier transform infrared (FTIR), and activity assays. The radius of gyration and Kratky plots obtained from the SAXS data

Exchanges between the open Black Sea and its North West shelf

Science.gov (United States)

Shapiro, Georgy; Wobus, Fred; Zhou, Feng

2014-05-01

Exchanges between the vast NW shelf and the deep basin of the Black Sea play a significant role in maintaining the balance of nutrients, heat content and salinity of the shelf waters. Nearly 87 % of the Black Sea is entirely anoxic below 70 to 200m and contains high levels of hydrogen sulphide (Zaitsev et al, 2001), and this makes the shelf waters particularly valuable for maintaining the Black Sea ecosystem in good health. The increase in salinity of shelf waters occurs partially due to exchanges with more saline open sea waters and represents a threat to relics and endemic species. The shelf-break is commonly considered the bottle-neck of the shelf-deep sea exchanges (e.g. (Huthnance, 1995, Ivanov et al, 1997). Due to conservation of potential vorticity, the geostrophic currents flow along the contours of constant depth. However the ageostrophic flows (Ekman drift, mesoscale eddies, filaments, internal waves) are not subject to the same constraints. It has been shown that during the winter well mixed cold waters formed on the North West shelf propagate into the deep sea, providing an important mechanism for the replenishment of the Cold Intermediate Layer ( Staneva and Stanev, 1997). However, much less is known about exchanges in the warm season. In this study, the transports of water, heat and salt between the northwestern shelf and the adjacent deep basin of the Black Sea are investigated using a high-resolution three-dimensional primitive equation model, NEMO-SHELF-BLS (Shapiro et al, 2013). It is shown that during the period from April to August, 2005, both onshore and offshore cross-shelf break transports in the top 20 m were as high as 0.24 Sv on average, which was equivalent to the replacement of 60% of the volume of surface shelf waters (0 - 20 m) per month. Two main exchange mechanisms are studied: (i) Ekman transport, and (ii) transport by mesoscale eddies and associated meanders of the Rim Current. The Ekman drift causes nearly uniform onshore or

Fun at Antarctic grounding lines: Ice-shelf channels and sediment transport

Science.gov (United States)

Drews, Reinhard; Mayer, Christoph; Eisen, Olaf; Helm, Veit; Ehlers, Todd A.; Pattyn, Frank; Berger, Sophie; Favier, Lionel; Hewitt, Ian H.; Ng, Felix; Fürst, Johannes J.; Gillet-Chaulet, Fabien; Bergeot, Nicolas; Matsuoka, Kenichi

2017-04-01

Meltwater beneath the polar ice sheets drains, in part, through subglacial conduits. Landforms created by such drainages are abundant in areas formerly covered by ice sheets during the last glacial maximum. However, observations of subglacial conduit dynamics under a contemporary ice sheet are lacking. We present results from ice-penetrating radar to infer the existence of subglacial conduits upstream of the grounding line of Roi Baudouin Ice Shelf, Antarctica. The conduits are aligned with ice-shelf channels, and underlain by esker ridges formed from sediment deposition due to reduced water outflow speed near the grounding line. In turn, the eskers modify local ice flow to initiate the bottom topography of the ice-shelf channels, and create small surface ridges extending onto the shelf. Relict features on the shelf are interpreted to indicate a history of these interactions and variability of past subglacial drainages. Because ice-shelf channels are loci where intense melting occurs to thin an ice shelf, these findings expose a novel link between subglacial drainage, sedimentation, and ice-shelf stability. To investigate the role of sediment transport beneath ice sheets further, we model the sheet-shelf system of the Ekstömisen catchment, Antarctica. A 3D finite element model (Elmer/ICE) is used to solve the transients full Stokes equation for isotropic, isothermal ice with a dynamic grounding line. We initialize the model with surface topography from the TanDEM-X satellites and by inverting simultaneously for ice viscosity and basal drag using present-day surface velocities. Results produce a flow field which is consitent with sattelite and on-site observations. Solving the age-depth relationship allows comparison with radar isochrones from airborne data, and gives information about the atmospheric/dynamic history of this sector. The flow field will eventually be used to identify potential sediment sources and sinks which we compare with more than 400 km of

Inorganic carbon fluxes on the Mackenzie Shelf of the Beaufort Sea

Science.gov (United States)

Mol, Jacoba; Thomas, Helmuth; Myers, Paul G.; Hu, Xianmin; Mucci, Alfonso

2018-02-01

The Mackenzie Shelf in the southeastern Beaufort Sea is a region that has experienced large changes in the past several decades as warming, sea-ice loss, and increased river discharge have altered carbon cycling. Upwelling and downwelling events are common on the shelf, caused by strong, fluctuating along-shore winds, resulting in cross-shelf Ekman transport, and an alternating estuarine and anti-estuarine circulation. Downwelling carries dissolved inorganic carbon (DIC) and other remineralization products off the shelf and into the deep basin for possible long-term storage in the world's oceans. Upwelling carries DIC and nutrient-rich waters from the Pacific-origin upper halocline layer (UHL) onto the shelf. Profiles of DIC and total alkalinity (TA) taken in August and September of 2014 are used to investigate the cycling of carbon on the Mackenzie Shelf. The along-shore transport of water and the cross-shelf transport of DIC are quantified using velocity field output from a simulation of the Arctic and Northern Hemisphere Atlantic (ANHA4) configuration of the Nucleus of European Modelling of the Ocean (NEMO) framework. A strong upwelling event prior to sampling on the Mackenzie Shelf took place, bringing CO2-rich (elevated pCO2) water from the UHL onto the shelf bottom. The maximum on-shelf DIC flux was estimated at 16.9×103 mol C d-1 m-2 during the event. The maximum on-shelf transport of DIC through the upwelling event was found to be 65±15×10-3 Tg C d-1. TA and the oxygen isotope ratio of water (δ18O-H2O) are used to examine water-mass distributions in the study area and to investigate the influence of Pacific Water, Mackenzie River freshwater, and sea-ice melt on carbon dynamics and air-sea fluxes of carbon dioxide (CO2) in the surface mixed layer. Understanding carbon transfer in this seasonally dynamic environment is key to quantify the importance of Arctic shelf regions to the global carbon cycle and provide a basis for understanding how it will

Inorganic carbon fluxes on the Mackenzie Shelf of the Beaufort Sea

Directory of Open Access Journals (Sweden)

J. Mol

2018-02-01

Full Text Available The Mackenzie Shelf in the southeastern Beaufort Sea is a region that has experienced large changes in the past several decades as warming, sea-ice loss, and increased river discharge have altered carbon cycling. Upwelling and downwelling events are common on the shelf, caused by strong, fluctuating along-shore winds, resulting in cross-shelf Ekman transport, and an alternating estuarine and anti-estuarine circulation. Downwelling carries dissolved inorganic carbon (DIC and other remineralization products off the shelf and into the deep basin for possible long-term storage in the world's oceans. Upwelling carries DIC and nutrient-rich waters from the Pacific-origin upper halocline layer (UHL onto the shelf. Profiles of DIC and total alkalinity (TA taken in August and September of 2014 are used to investigate the cycling of carbon on the Mackenzie Shelf. The along-shore transport of water and the cross-shelf transport of DIC are quantified using velocity field output from a simulation of the Arctic and Northern Hemisphere Atlantic (ANHA4 configuration of the Nucleus of European Modelling of the Ocean (NEMO framework. A strong upwelling event prior to sampling on the Mackenzie Shelf took place, bringing CO2-rich (elevated pCO2 water from the UHL onto the shelf bottom. The maximum on-shelf DIC flux was estimated at 16.9×103 mol C d−1 m−2 during the event. The maximum on-shelf transport of DIC through the upwelling event was found to be 65±15×10−3 Tg C d−1. TA and the oxygen isotope ratio of water (δ18O-H2O are used to examine water-mass distributions in the study area and to investigate the influence of Pacific Water, Mackenzie River freshwater, and sea-ice melt on carbon dynamics and air–sea fluxes of carbon dioxide (CO2 in the surface mixed layer. Understanding carbon transfer in this seasonally dynamic environment is key to quantify the importance of Arctic shelf regions to the global carbon cycle and provide a basis

Arctic Ocean outflow and glacier-ocean interactions modify water over the Wandel Sea shelf (northeastern Greenland)

Science.gov (United States)

Dmitrenko, Igor A.; Kirillov, Sergey A.; Rudels, Bert; Babb, David G.; Toudal Pedersen, Leif; Rysgaard, Søren; Kristoffersen, Yngve; Barber, David G.

2017-12-01

The first-ever conductivity-temperature-depth (CTD) observations on the Wandel Sea shelf in northeastern Greenland were collected in April-May 2015. They were complemented by CTDs taken along the continental slope during the Norwegian FRAM 2014-2015 drift. The CTD profiles are used to reveal the origin of water masses and interactions with ambient water from the continental slope and the tidewater glacier outlet. The subsurface water is associated with the Pacific water outflow from the Arctic Ocean. The underlying halocline separates the Pacific water from a deeper layer of polar water that has interacted with the warm Atlantic water outflow through the Fram Strait, recorded below 140 m. Over the outer shelf, the halocline shows numerous cold density-compensated intrusions indicating lateral interaction with an ambient polar water mass across the continental slope. At the front of the tidewater glacier outlet, colder and turbid water intrusions were observed at the base of the halocline. On the temperature-salinity plots these stations indicate a mixing line that is different from the ambient water and seems to be conditioned by the ocean-glacier interaction. Our observations of Pacific water are set within the context of upstream observations in the Beaufort Sea and downstream observations from the Northeast Water Polynya, and clearly show the modification of Pacific water during its advection across the Arctic Ocean. Moreover, ambient water over the Wandel Sea slope shows different thermohaline structures indicating the different origin and pathways of the on-shore and off-shore branches of the Arctic Ocean outflow through the western Fram Strait.

The Faroe shelf circulation and its potential impact on the primary production

Science.gov (United States)

Rasmussen, Till A. S.; Olsen, Steffen M.; Hansen, Bogi; Hátún, Hjálmar; Larsen, Karin M. H.

2014-10-01

The ecosystem on the Faroe shelf has been shown to be tightly controlled by the primary production. It has been suggested that the primary production is governed by the physical processes controlling this water mass. The objective of this study is to identify the physical control mechanisms that control this water mass, link these to the interannual variability of the chlorophyll content on the Faroe shelf and through this discuss the influence on the primary production. In order to achieve this, a 10 year hindcast (2000-2009) with a regional ocean circulation model has been set up for the focus area. Results are compared with measurements on the Faroe shelf. The model reproduces the clockwise residual circulation around the Faroe Islands. The vertical velocity profile is validated using observations at a location west of the Islands. Observations show a logarithmic profile in the entire water column indicating a fully developed boundary layer. The modeled profile matches the observations in the bottom part of the water column, however the thickness of the bottom boundary layer is underestimated, which results in a constant profile in the upper part of the water column. As a consequence, the modeled velocity in the upper part of the water column is up to 20% lower than the observed velocity. The direction of the modeled velocity profile compares well with observations. The model realistically forms the partly isolated unique shelf water mass. Years with anomalously early and persistent modeled spring stratification correspond with years with a high on-shelf chlorophyll concentration. An integration of the exchange across the 120 m isobath shows intense water mass exchange across this depth contour. The major part of this includes tidal shifting of the front between on-shelf and off-shelf waters and is associated with little effective water mass exchange. The result is a shelf water mass that is relatively isolated. The modeled net exchange is constituted by an on-shelf

Ethylene Control Technologies in Extending Postharvest Shelf Life of Climacteric Fruit.

Science.gov (United States)

Zhang, Junhua; Cheng, Dong; Wang, Baobin; Khan, Iqbal; Ni, Yonghao

2017-08-30

Fresh fruit is important for a healthy diet. However, because of their seasonal production, regional specific cultivation, and perishable nature, it is essential to develop preservation technologies to extend the postharvest shelf life of fresh fruits. Climacteric fruit adopt spoilage because of ethylene, a key hormone associated with the ripening process. Therefore, controlling ethylene activity by following safe and effective approaches is a key to extend the postharvest shelf life of fruit. In this review, ethylene control technologies will be discussed aiming for the need of developing more innovative and effective approaches. The biosynthesis pathway will be given first. Then, the technologies determining the postharvest shelf life of climacteric fruit will be described with special attention to the latest and significant published works in this field. Special attention is given to 1-methylcyclopropene (1-MCP), which is effective in fruit preservation technologies. Finally, the encapsulation technology to improve the stability of 1-MCP will be proposed, using a potential encapsulation agent of 1-MCP, calixarene.

Short term variation in particulate matter in the shelf waters of the Princess Astrid Coast, Antarctica

Digital Repository Service at National Institute of Oceanography (India)

Dhargalkar, V.K.; Bhosle, N.B.

Particulate matter collected at a single station in the shelf waters of Princess Astrid coast (70 degrees S, 11 degrees E) Antarctica, during the austral summer (Jan.-Feb. 1986) was analysed for phytoplankton biomass (Chl @ia@@), living carbon (ATP...

Paleocene Wilcox cross-shelf channel-belt history and shelf-margin growth: Key to Gulf of Mexico sediment delivery

Science.gov (United States)

Zhang, Jinyu; Steel, Ronald; Ambrose, William

2017-12-01

Shelf margins prograde and aggrade by the incremental addition of deltaic sediments supplied from river channel belts and by stored shoreline sediment. This paper documents the shelf-edge trajectory and coeval channel belts for a segment of Paleocene Lower Wilcox Group in the northern Gulf of Mexico based on 400 wireline logs and 300 m of whole cores. By quantitatively analyzing these data and comparing them with global databases, we demonstrate how varying sediment supply impacted the Wilcox shelf-margin growth and deep-water sediment dispersal under greenhouse eustatic conditions. The coastal plain to marine topset and uppermost continental slope succession of the Lower Wilcox shelf-margin sediment prism is divided into eighteen high-frequency ( 300 ky duration) stratigraphic sequences, and further grouped into 5 sequence sets (labeled as A-E from bottom to top). Sequence Set A is dominantly muddy slope deposits. The shelf edge of Sequence Sets B and C prograded rapidly (> 10 km/Ma) and aggraded modestly ( 80 m/Ma) characterizes Sequence Sets D and E, which is associated with smaller (9-10 m thick on average) and isolated channel belts. This stratigraphic trend is likely due to an upward decreasing sediment supply indicated by the shelf-edge progradation rate and channel size, as well as an upward increasing shelf accommodation indicated by the shelf-edge aggradation rate. The rapid shelf-edge progradation and large rivers in Sequence Sets B and C confirm earlier suggestions that it was the early phase of Lower Wilcox dispersal that brought the largest deep-water sediment volumes into the Gulf of Mexico. Key factors in this Lower Wilcox stratigraphic trend are likely to have been a very high initial sediment flux to the Gulf because of the high initial release of sediment from Laramide catchments to the north and northwest, possibly aided by modest eustatic sea-level fall on the Texas shelf, which is suggested by the early, flat shelf-edge trajectory, high

Duality of Ross Ice Shelf systems: crustal boundary, ice sheet processes and ocean circulation from ROSETTA-Ice surveys

Science.gov (United States)

Tinto, K. J.; Siddoway, C. S.; Padman, L.; Fricker, H. A.; Das, I.; Porter, D. F.; Springer, S. R.; Siegfried, M. R.; Caratori Tontini, F.; Bell, R. E.

2017-12-01

Bathymetry beneath Antarctic ice shelves controls sub-ice-shelf ocean circulation and has a major influence on the stability and dynamics of the ice sheets. Beneath the Ross Ice Shelf, the sea-floor bathymetry is a product of both tectonics and glacial processes, and is influenced by the processes it controls. New aerogeophysical surveys have revealed a fundamental crustal boundary bisecting the Ross Ice Shelf and imparting a duality to the Ross Ice Shelf systems, encompassing bathymetry, ocean circulation and ice flow history. The ROSETTA-Ice surveys were designed to increase the resolution of Ross Ice Shelf mapping from the 55 km RIGGS survey of the 1970s to a 10 km survey grid, flown over three years from New York Air National Guard LC130s. Radar, LiDAR, gravity and magnetic instruments provide a top to bottom profile of the ice shelf and the underlying seafloor, with 20 km resolution achieved in the first two survey seasons (2015 and 2016). ALAMO ocean-profiling floats deployed in the 2016 season are measuring the temperature and salinity of water entering and exiting the sub-ice water cavity. A significant east-west contrast in the character of the magnetic and gravity fields reveals that the lithospheric boundary between East and West Antarctica exists not at the base of the Transantarctic Mountains (TAM), as previously thought, but 300 km further east. The newly-identified boundary spatially coincides with the southward extension of the Central High, a rib of shallow basement identified in the Ross Sea. The East Antarctic side is characterized by lower amplitude magnetic anomalies and denser TAM-type lithosphere compared to the West Antarctic side. The crustal structure imparts a fundamental duality on the overlying ice and ocean, with deeper bathymetry and thinner ice on the East Antarctic side creating a larger sub-ice cavity for ocean circulation. The West Antarctic side has a shallower seabed, more restricted ocean access and a more complex history of

Carbon and oxygen dynamics on the Louisiana continental shelf: role of water column primary production and respiration

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We conducted a multi-year study of the Louisiana continental shelf (LCS) to better understand the linkages between water column net metabolism and the formation of hypoxia (dissolved oxygen respiration (R) and primary p...

The Sinking and Spreading of The Antarctic Deep Ice Shelf Water In The Ross Sea Studied By In Situ Observaions and Numerical Modeling

Science.gov (United States)

Rubino, A.; Budillon, G.; Pierini, S.; Spezie, G.

The sinking and spreading of the Deep Ice Shelf Water (DISW) in the Ross Sea are analyzed using in situ observations and the results of a nonlinear, reduced-gravity, frontal layered numerical "plume" model which is able to simulate the motion of a bottom-arrested current over realistic topography. The model is forced by prescribing the thickness of the DISW vein as well as its density structure at the southern model boundary. The ambient temperature and salinity are imposed using hydrographic data acquired by the Italian PNRA-CLIMA project. In the model water of the quiescent ambient ocean is allowed to entrain in the active deep layer due to a simple param- eterization of turbulent mixing. The importance of forcing the model with a realistic ambient density is demonstrated by carrying out a numerical simulation in which the bottom active layer is forced using an idealized ambient density. In a more realis- tic simulation the path and the density structure of the DISW vein flowing over the Challenger Basin are obtained and are found to be in good agreement with data. The evolution of the deep current beyond the continental shelf is also simulated. It provides useful information on the water flow and mixing in a region of the Ross Sea where the paucity of experimental data does not allow for a detailed description of the deep ocean dynamics.

Impacts of a weather event on shelf circulation and CO2 and O2 dynamics on the Louisiana shelf during summer 2009

Science.gov (United States)

Huang, W.-J.; Cai, W.-J.; Wang, Y.; Hopkinson, C. S.

2013-12-01

While much is known about the physics of coastal currents, much less is known about the biogeochemical effects of surface currents on shelf carbon dioxide (CO2) and oxygen distribution and dynamics. The Mississippi and Atchafalaya River plume is usually observed along the Louisiana shelf with easterly winds. Such a typical pattern was observed in August 2007, i.e. a plume of low salinity and low partial pressure of CO2 (pCO2), indicating high biological production on the inner shelf; and higher salinity and pCO2 on the outer shelf. This high biological production induced by riverine nitrogen flux thus provided major organic matter sources for the shelf-wide hypoxia (dissolved oxygen [DO] hypoxic area. Furthermore, DIC concentration in bottom waters was higher than those predicted by the Redfield ratio, most likely because of much rapid O2 compensation than CO2 loss during air-sea exchange. Numerical models indicate such relocation of plume was mostly affected by the shelf circulation dominated by southerly and southwesterly winds. Consequently, we conclude that wind-forcing and shelf circulation are critical factors that influence the plume trajectories and the associated biogeochemical properties in coastal waters.

A laboratory scale model of abrupt ice-shelf disintegration

Science.gov (United States)

Macayeal, D. R.; Boghosian, A.; Styron, D. D.; Burton, J. C.; Amundson, J. M.; Cathles, L. M.; Abbot, D. S.

2010-12-01

An important mode of Earth’s disappearing cryosphere is the abrupt disintegration of ice shelves along the Peninsula of Antarctica. This disintegration process may be triggered by climate change, however the work needed to produce the spectacular, explosive results witnessed with the Larsen B and Wilkins ice-shelf events of the last decade comes from the large potential energy release associated with iceberg capsize and fragmentation. To gain further insight into the underlying exchanges of energy involved in massed iceberg movements, we have constructed a laboratory-scale model designed to explore the physical and hydrodynamic interactions between icebergs in a confined channel of water. The experimental apparatus consists of a 2-meter water tank that is 30 cm wide. Within the tank, we introduce fresh water and approximately 20-100 rectangular plastic ‘icebergs’ having the appropriate density contrast with water to mimic ice. The blocks are initially deployed in a tight pack, with all blocks arranged in a manner to represent the initial state of an integrated ice shelf or ice tongue. The system is allowed to evolve through time under the driving forces associated with iceberg hydrodynamics. Digitized videography is used to quantify how the system of plastic icebergs evolves between states of quiescence to states of mobilization. Initial experiments show that, after a single ‘agitator’ iceberg begins to capsize, an ‘avalanche’ of capsizing icebergs ensues which drives horizontal expansion of the massed icebergs across the water surface, and which stimulates other icebergs to capsize. A surprise initially evident in the experiments is the fact that the kinetic energy of the expanding mass of icebergs is only a small fraction of the net potential energy released by the rearrangement of mass via capsize. Approximately 85 - 90 % of the energy released by the system goes into water motion modes, including a pervasive, easily observed seich mode of the tank

How fast is the Patagonian shelf-break acidifying?

Science.gov (United States)

Orselli, Iole B. M.; Kerr, Rodrigo; Ito, Rosane G.; Tavano, Virginia M.; Mendes, Carlos Rafael B.; Garcia, Carlos A. E.

2018-02-01

Anthropogenic carbon (Cant) concentration is determined according to the TrOCA method, from carbonate system data and hydrographic parameters collected during two consecutive spring cruises (2007 and 2008) in the Argentinean Patagonian shelf-break zone between 36°S and 50°S. Cant has intruded the water column until intermediate depths, with no Cant below 1000 m, in the deeper waters (i.e., North Atlantic Deep Water and Antarctic Bottom Water) of the Northern sector of the study area (i.e., North of 38°S). The higher Cant concentration is observed in Subantarctic Shelf Water in the Southern region, whereas in the Northern sector both Tropical Water and South Atlantic Central Water are equally affected by Cant intrusion. The Antarctic Intermediate Water represents the depth-limit achieved by Cant penetration, reinforcing the role that this water mass plays as an important vehicle to transport Cant to the oceans interior. The estimated Cant average (± method precision) is 46.6 ± 5.3 μmol kg- 1, considering the full depth of the water column. The ocean acidification state (ΔpH) shows an average (± standard deviation) of - 0.11 ± 0.05, thus, indicating an annual pH reduction of - 0.0010 yr- 1 since the Industrial Revolution (c.a. 1750). The degree of aragonite saturation is lowered towards undersaturation levels of calcite. The Patagonian shelf and shelf-break zones-a strong CO2 sink region in the global ocean-are likely a key area for Cant intrusion in the southwestern South Atlantic Ocean.

Eddy-induced cross-shelf export of high Chl-a coastal waters in the SE Bay of Biscay

KAUST Repository

Rubio, Anna

2017-12-08

Different remote sensing data were combined to characterise a winter anticyclonic eddy in the southeastern Bay of Biscay and to infer its effects on cross-shelf exchanges, in a period when typical along shelf-slope currents depict a cyclonic pattern. While the joint analysis of available satellite data (infrared, visible and altimetry) permitted the characterisation and tracking of the anticyclone properties and path, data from a coastal high-frequency radar system enabled a quantitative analysis of the surface cross-shelf transports associated with this anticyclone. The warm core anticyclone had a diameter of around 50km, maximum azimuthal velocities near 50cms−1 and a relative vorticity of up to −0.45f. The eddy generation occurred after the relaxation of a cyclonic wind-driven current regime over the shelf-slope; then, the eddy remained stationary for several weeks until it started to drift northwards along the shelf break. The surface signature of this eddy was observed by means of high-frequency radar data for 20 consecutive days, providing a unique opportunity to characterise and quantify, from a Lagrangian perspective, the associated transport and its effect on the Chl-a surface distribution. We observed the presence of mesoscale structures with similar characteristics in the area during different winters within the period 2011–2014. Our results suggest that the eddy-induced recurrent cross-shelf export is an effective mechanism for the expansion of coastal productive waters into the adjacent oligotrophic ocean basin.

Intrusions of Kuroshio and Shelf Waters on Northern Slope of South China Sea in Summer 2015

Science.gov (United States)

Li, Denghui; Zhou, Meng; Zhang, Zhaoru; Zhong, Yisen; Zhu, Yiwu; Yang, Chenghao; Xu, Mingquan; Xu, Dongfeng; Hu, Ziyuan

2018-06-01

The northern slope region of the South China Sea (SCS) is a biological hot spot characterized by high primary productivity and biomasses transported by cross-shelf currents, which support the spawning and growth of commercially and ecologically important fish species. To understand the physical and biogeochemical processes that promote the high primary production of this region, we conducted a cruise from June 10 and July 2, 2015. In this study, we used fuzzy cluster analysis and optimum multiparameter analysis methods to analyze the hydrographic data collected during the cruise to determine the compositions of the upper 55-m water masses on the SCS northern slope and thereby elucidate the cross-slope transport of shelf water (SHW) and the intrusions of Kuroshio water (KW). We also analyzed the geostrophic currents derived from acoustic Doppler current profiler measurements and satellite data. The results reveal the surface waters on the northern slope of the SCS to be primarily composed of waters originating from South China Sea water (SCSW), KW, and SHW. The SCSW dominated a majority of the study region at percentages ranging between 60% and 100%. We found a strong cross-slope current with speeds greater than 50 cm s-1 to have carried SHW into and through the surveyed slope area, and KW to have intruded onto the slope via mesoscale eddies, thereby dominating the southwestern section of the study area.

Arctic Ocean outflow and glacier–ocean interactions modify water over the Wandel Sea shelf (northeastern Greenland

Directory of Open Access Journals (Sweden)

I. A. Dmitrenko

2017-12-01

Full Text Available The first-ever conductivity–temperature–depth (CTD observations on the Wandel Sea shelf in northeastern Greenland were collected in April–May 2015. They were complemented by CTDs taken along the continental slope during the Norwegian FRAM 2014–2015 drift. The CTD profiles are used to reveal the origin of water masses and interactions with ambient water from the continental slope and the tidewater glacier outlet. The subsurface water is associated with the Pacific water outflow from the Arctic Ocean. The underlying halocline separates the Pacific water from a deeper layer of polar water that has interacted with the warm Atlantic water outflow through the Fram Strait, recorded below 140 m. Over the outer shelf, the halocline shows numerous cold density-compensated intrusions indicating lateral interaction with an ambient polar water mass across the continental slope. At the front of the tidewater glacier outlet, colder and turbid water intrusions were observed at the base of the halocline. On the temperature–salinity plots these stations indicate a mixing line that is different from the ambient water and seems to be conditioned by the ocean–glacier interaction. Our observations of Pacific water are set within the context of upstream observations in the Beaufort Sea and downstream observations from the Northeast Water Polynya, and clearly show the modification of Pacific water during its advection across the Arctic Ocean. Moreover, ambient water over the Wandel Sea slope shows different thermohaline structures indicating the different origin and pathways of the on-shore and off-shore branches of the Arctic Ocean outflow through the western Fram Strait.

Exchange across the shelf break at high southern latitudes

Directory of Open Access Journals (Sweden)

J. M. Klinck

2010-05-01

Full Text Available Exchange of water across the Antarctic shelf break has considerable scientific and societal importance due to its effects on circulation and biology of the region, conversion of water masses as part of the global overturning circulation and basal melt of glacial ice and the consequent effect on sea level rise. The focus in this paper is the onshore transport of warm, oceanic Circumpolar Deep Water (CDW; export of dense water from these shelves is equally important, but has been the focus of other recent papers and will not be considered here. A variety of physical mechanisms are described which could play a role in this onshore flux. The relative importance of some processes are evaluated by simple calculations. A numerical model for the Ross Sea continental shelf is used as an example of a more comprehensive evaluation of the details of cross-shelf break exchange. In order for an ocean circulation model to simulate these processes at high southern latitudes, it needs to have high spatial resolution, realistic geometry and bathymetry. Grid spacing smaller than the first baroclinic radius of deformation (a few km is required to adequately represent the circulation. Because of flow-topography interactions, bathymetry needs to be represented at these same small scales. Atmospheric conditions used to force these circulation models also need to be known at a similar small spatial resolution (a few km in order to represent orographically controlled winds (coastal jets and katabatic winds. Significantly, time variability of surface winds strongly influences the structure of the mixed layer. Daily, if not more frequent, surface fluxes must be imposed for a realistic surface mixed layer. Sea ice and ice shelves are important components of the coastal circulation. Ice isolates the ocean from exchange with the atmosphere, especially in the winter. Melting and freezing of both sea ice and glacial ice influence salinity and thereby the character of shelf

Nutrient Dynamics in the Northern South China Sea Shelf-sea (NoSoCS)

Science.gov (United States)

Wong, G. T.; Guo, X.

2011-12-01

The Northern South China Sea Shelf-sea (NoSoCS) is situated in the sub-tropics along the southern Chinese coast between the southern end of the Taiwan Strait and the Hainan Island. Samples were collected in four cross-shelf transects in summer, 2010 and two cross-shelf transects in winter, 2011 in this Shelf-sea. The shelf may be sub-divided into the inner shelf (1 μM in NO3- and >0.1 μM in soluble reactive phosphate) stretched across the shelf at least to the middle shelf. Thus, vertical mixing, even to relatively shallow depths, on the shelf may supply nutrients to and play a critical role in determining the primary production in the mixed layer. At least three such processes were observed. Through the year, internal waves of various strengths generated at the Luzon Strait propagated westward along the bottom of the mixed layer and dissipated along the middle and outer shelf. The effects of these waves were especially conspicuous north of the Dongsha Atoll and their action enhances vertical mixing. In the summer, upwelling occurred in the inner/middle shelf off Dongshan in response to the along shore southwest monsoon and the topographic forcing by the ridge extending offshore from Dongshan to the Taiwan Bank. In the winter, surface cooling and the strong northeast monsoon led to complete overturn in the shelf. The maximum density, reaching 24.6, in the surface waters was found offshore in the inner and middle shelf. This density was equivalent to the density of the water at >100 m offshore. As a result, this dense water also appeared as a layer of bottom water that extended across the shelf to the shelf edge.

Investigation on flow stability of supercritical water cooled systems

International Nuclear Information System (INIS)

Cheng, X.; Kuang, B.

2006-01-01

Research activities are ongoing worldwide to develop nuclear power plants with supercritical water cooled reactor (SCWR) with the purpose to achieve a high thermal efficiency and to improve their economical competitiveness. However, the strong variation of the thermal-physical properties of water in the vicinity of the pseudo-critical line results in challenging tasks in various fields, e.g. thermal-hydraulic design of a SCWR. One of the challenging tasks is to understand and to predict the dynamic behavior of supercritical water cooled systems. Although many thermal-hydraulic research activities were carried out worldwide in the past as well as in the near present, studies on dynamic behavior and flow stability of SC water cooled systems are scare. Due to the strong density variation, flow stability is expected to be one of the key items which need to be taken into account in the design of a SCWR. In the present work, the dynamic behavior and flow stability of SC water cooled systems are investigated using both numerical and theoretical approaches. For this purpose a new computer code SASC was developed, which can be applied to analysis the dynamic behavior of systems cooled by supercritical fluids. In addition, based on the assumptions of a simplified system, a theoretical model was derived for the prediction of the onset of flow instability. A comparison was made between the results obtained using the theoretical model and those from the SASC code. A good agreement was achieved. This gives the first evidence of the reliability of both the SASC code and the theoretical model

Distribution of nutrients in the shelf waters of the Arabian sea along the west coast of India

Digital Repository Service at National Institute of Oceanography (India)

Reddy, C.V.G.; Sankaranarayanan, V.N.

The paper presents a descriptive account of the distribution of phosphates, silicates and nitrates in the shelf waters of Arabian Sea along the West Coast of India including a brief mention about the hydrographical features and their relationship...

Inter-annual variability of exchange processes at the outer Black Sea shelf

Science.gov (United States)

Shapiro, Georgy; Wobus, Fred; Yuan, Dongliang; Wang, Zheng

2014-05-01

averaged over the warm periods of each year. Over the 34 year time span, the on-shelf and off-shelf transports between the CIL and BSW fluctuate in the range of 0.22 to 0.45 Sv, with the maximum values in 1996 and the minimum in 1990. The net cross-shelf transport is small, approximately 0.03 Sv, due to volume conservation, and is directed off-shore due to river discharges. The years with high values of transport correspond to the situation when a 'channel' of constant PV connecting the BSW and CIL exists, forming a conduit for the waters to move across the shelf break. In the years of reduced transport, there was a PV 'barrier', i.e. a band of significant PV gradient along the shelf break, which inhibits exchanges. The efficiency of the exchange can be represented by the average renewal time of BSW, which is defined as the ratio of BSW volume to the onshore transport. This value, as well as the volumes and the transports vary over the 34 years. The renewal time is within the range between 18 to 42 days. The short renewal time (31 days on average) compared to the seasonal time scales, suggests an efficient exchange between bottom waters on the outer shelf and the CIL in the deep sea during the warm season. This study was partially supported by the EU (via PERSEUS grant FP7-OCEAN-2011-287600 and MyOcean SPA.2011.1.5-01 grant 283367), Institute of Oceanology, Chinese Academy of Sciences and the University of Plymouth Marine Institute Innovation Fund. References Brodeau L., B. Barnier, A.-M. Treguier, T.Penduff, S.Gulev, 2010. An ERA40-based atmospheric forcing for global ocean circulation models, Ocean Modelling, 31 (3-4), 88-104. Kolesnikov, A.G., 1953. Intra-annual variability of temperature, stability and vertical turbulent exchange of heat in the open area of the Black Sea. In: Proceedings of the Marine Hydrophysical Institute, issue 3. Filippov D.M., 1968. Water Circulation and Structure of the Black Sea. Nauka, Moscow, 136 pp. Ivanov, L. I., Besiktepe, S. and E. �

The shelf life of dyed polymethylmethacrylate dosimeters

International Nuclear Information System (INIS)

Bett, R.; Watts, M.F.; Plested, M.E.

2002-01-01

The long-term stability of the radiation response of Harwell Red 4034 and Amber 3042 Perspex Dosimeters has been monitored for more than 15 years, and the resulting data used in the justification of their shelf-life specifications

Stability of niclosamide in water under local conditions

International Nuclear Information System (INIS)

El Hindi, A.M.; Sidra, M.S.

1986-01-01

The stability of 14 C-labelled niclosamide was studied in distilled water at two different pH values and in canal water. 2 mg/1 niclosamide solutions were exposed to direct atmospheric conditions. The activity was followed by radioassay and the concentration of niclosamide was determined by GLC. The total activity was found to decrease to 46.0% in weakly acidic solution (pH 6.5), 45% in neutral solution (pH 7.0) and 16.7% in filtered canal water after three weeks. GLC analysis showed that niclosamide concentration had dropped to 0.05, 0.06 and 0.03 mg/1 in weakly acidic, neutral medium and canal water after the same period. GLC analysis as compared to radioassay indicated the presence of increasing amounts of degradation product(s), in the chloroform extracts of water with time, which were not detected by GLC

Eddy-induced cross-shelf export of high Chl-a coastal waters in the SE Bay of Biscay

KAUST Repository

Rubio, Anna; Caballero, Ainhoa; Orfila, Alejandro; Herná ndez-Carrasco, Ismael; Ferrer, Luis; Gonzá lez, Manuel; Solabarrieta, Lohitzune; Mader, Julien

2017-01-01

with similar characteristics in the area during different winters within the period 2011–2014. Our results suggest that the eddy-induced recurrent cross-shelf export is an effective mechanism for the expansion of coastal productive waters into the adjacent

Influence of cross-shelf water transport on nutrients and phytoplankton in the East China Sea: a model study

Directory of Open Access Journals (Sweden)

L. Zhao

2011-01-01

Full Text Available A three dimensional coupled biophysical model was used to examine the supply of oceanic nutrients to the shelf of the East China Sea (ECS and its role in primary production over the shelf. The model consisted of two parts: the hydrodynamic module was based on a nested model with a horizontal resolution of 1/18 degree, whereas the biological module was a lower trophic level ecosystem model including two types of phytoplankton, three elements of nutrients, and biogenic organic material. The model results suggested that seasonal variations occurred in the distribution of nutrients and chlorophyll a over the shelf of the ECS. After comparison with available observed nutrients and chlorophyll a data, the model results were used to calculate volume and nutrients fluxes across the shelf break. The annual mean total fluxes were 1.53 Sv for volume, 9.4 kmol s⁻¹ for DIN, 0.7 kmol s⁻¹ for DIP, and 18.2 kmol s⁻¹ for silicate. Two areas, northeast of Taiwan and southwest of Kyushu, were found to be major source regions of oceanic nutrients to the shelf. Although the onshore fluxes of nutrients and volume both had apparent seasonal variations, the seasonal variation of the onshore nutrient flux did not exactly follow that of the onshore volume flux. Additional calculations in which the concentration of nutrients in Kuroshio water was artificially increased suggested that the oceanic nutrients were distributed in the bottom layer from the shelf break to the region offshore of the Changjiang estuary from spring to summer and appeared in the surface layer from autumn to winter. The calculations also implied that the supply of oceanic nutrients to the shelf can change the consumption of pre-existing nutrients from rivers. The response of primary production over the shelf to the oceanic nutrients was confirmed not only in the surface layer (mainly at the outer shelf and shelf break in winter and in the region

Semi-analytical Model for Estimating Absorption Coefficients of Optically Active Constituents in Coastal Waters

Science.gov (United States)

Wang, D.; Cui, Y.

2015-12-01

The objectives of this paper are to validate the applicability of a multi-band quasi-analytical algorithm (QAA) in retrieval absorption coefficients of optically active constituents in turbid coastal waters, and to further improve the model using a proposed semi-analytical model (SAA). The ap(531) and ag(531) semi-analytically derived using SAA model are quite different from the retrievals procedures of QAA model that ap(531) and ag(531) are semi-analytically derived from the empirical retrievals results of a(531) and a(551). The two models are calibrated and evaluated against datasets taken from 19 independent cruises in West Florida Shelf in 1999-2003, provided by SeaBASS. The results indicate that the SAA model produces a superior performance to QAA model in absorption retrieval. Using of the SAA model in retrieving absorption coefficients of optically active constituents from West Florida Shelf decreases the random uncertainty of estimation by >23.05% from the QAA model. This study demonstrates the potential of the SAA model in absorption coefficients of optically active constituents estimating even in turbid coastal waters. Keywords: Remote sensing; Coastal Water; Absorption Coefficient; Semi-analytical Model

Complex vertical migration of larvae of the ghost shrimp, Nihonotrypaea harmandi, in inner shelf waters of western Kyushu, Japan

Science.gov (United States)

Tamaki, Akio; Mandal, Sumit; Agata, Yoshihiro; Aoki, Ikumi; Suzuki, Toshikazu; Kanehara, Hisao; Aoshima, Takashi; Fukuda, Yasushi; Tsukamoto, Hideshi; Yanagi, Tetsuo

2010-01-01

The position of meroplanktonic larvae in the water column with depth-dependent current velocities determines horizontal transport trajectories. For those larvae occurring in inner shelf waters, little is known about how combined diel and tidally-synchronized vertical migration patterns shift ontogenetically. The vertical migration of larvae of Nihonotrypaea harmandi (Decapoda: Thalassinidea: Callianassidae) was investigated in mesotidal, inner shelf waters of western Kyushu, Japan in July-August 2006. The larval sampling at seven depth layers down to 60 m was conducted every 3 h for 36 h in a 68.5-m deep area 10 km off a major coastal adult habitat. Within a 61-65-m deep area 5-7.5 km off the adult habitat, water temperature, salinity, chlorophyll a concentration, and photon flux density were measured, and water currents there were characterized from harmonic analysis of current meter data collected in 2008. The water column was stratified, with pycnocline, chlorophyll a concentration maximum, and 2% of photon flux density at 2 m, recorded at around 22-24 m. The stratified residual currents were detected in their north component, directed offshore and onshore in the upper and lower mixed layers, respectively. More than 87% of larvae occurred between 20 m and 60 m, producing a net onshore transport of approximately 1.3 km d -1. At the sunset flooding tide, all zoeal-stage larvae ascended, which could further promote retention (1.4-km potential onshore transport in 3 h). The actual onshore transport of larvae was detected by observing their occurrence pattern in a shallow embayment area with the adult habitat for 24 h in October 1994. However, ontogenetic differences in the vertical migration pattern in inner shelf waters were also apparent, with the maximum mean positions of zoeae deepening with increasing stages. Zoeae I and II performed a reverse diel migration, with their minimum and maximum depths being reached around noon and midnight, respectively. Zoeae IV

The exchange of inorganic carbon on the Canadian Beaufort Shelf

Science.gov (United States)

Mol, Jacoba; Thomas, Helmuth; Hu, Xianmin; Myers, Paul G.

2017-04-01

The Mackenzie Shelf in the southeastern Beaufort Sea is an area that has experienced large changes in the past several decades as warming, sea-ice loss, and increased river discharge have altered carbon cycling. Upwelling and downwelling events are common on the shelf, caused by strong, fluctuating along-shore winds and resulting cross-shelf Ekman transport. Downwelling carries inorganic carbon and other remineralization products off the shelf and into the deep basin for possible long-term storage in the world oceans. Upwelling carries water high in dissolved inorganic carbon (DIC) and nutrients from the Pacific-origin upper halocline layer (UHL) onto the shelf. Profiles of DIC and total alkalinity (TA) taken in August and September of 2014 are used to investigate the cycling of inorganic carbon on the Mackenzie Shelf. The along-shore and cross-shelf transport of inorganic carbon is quantified using velocity field output from a simulation of the Arctic and Northern Hemisphere Atlantic (ANHA4) configuration of the Nucleus of European Modelling of the Ocean (NEMO) model. A strong upwelling event prior to sampling on the Mackenzie Shelf is analyzed and the resulting influence on the carbonate system, including the saturation state of aragonite and pH levels, is investigated. TA and δ18O are used to examine water mass distributions in the study area and analyze the influence of Pacific Water, Mackenzie River freshwater, and sea-ice melt on carbon dynamics and air-sea fluxes of CO2 in the surface mixed layer. Understanding carbon transfer in this seasonally dynamic environment is key in order to quantify the importance of Arctic shelf regions to the global carbon cycle and to provide a basis for understanding how its role will respond to the aforementioned changes in the regional marine system.

Integration of airborne altimetry and in situ radar measurements to estimate marine ice thickness beneath the Larsen C ice shelf, Antarctic Peninsula

Science.gov (United States)

McGrath, D.; Steffen, K.; Rodriguez Lagos, J.

2010-12-01

Observed atmospheric and oceanic warming is driving significant retreat and / or collapse of ice shelves along the Antarctic Peninsula totaling over 25,000 km2 in the past five decades. Basal melting of meteoric ice can occur near the grounding line of deep glacier inflows if the ocean water is above the pressure melting point. Buoyant meltwater will develop thermohaline circulation, rising beneath the ice shelf, where it may become supercooled and subsequently refreeze in ice draft minima. Marine ice, due to its warm and thus relatively viscous nature, is hypothesized to suture parallel flow bands, increasing ice shelf stability by arresting fracture propagation and controlling iceberg calving dimensions. Thus efforts to model ice shelf stability require accurate estimates of marine ice location and thickness. Ice thickness of a floating ice shelf can be determined in two manners: (1) from measurements of ice elevation above sea level and the calculation of ice thickness from assumptions of hydrostatic equilibrium, and (2) from radar echo measurements of the ice-water interface. Marine ice can confound the latter because its high dielectric constant and strong absorptive properties attenuate the radar energy, often preventing a return signal from the bottom of the ice shelf. These two methods are complementary for determining the marine ice component though because positive anomalies in (1) relative to (2) suggest regions of marine ice accretion. Nearly 350 km of ice penetrating radar (25 MHz) surveys were collected on the Larsen C ice shelf, in conjunction with kinematic GPS measurements and collocated with surface elevation data from the NASA Airborne Topographic Mapper (ATM) as part of the ICE Bridge mission in 2009. Basal ice topography and total ice thickness is accurately mapped along the survey lines and compared with calculated ice thickness from both the kinematic GPS and ATM elevation data. Positive anomalies are discussed in light of visible imagery and

Phytoplankton Distribution in Relation to Environmental Drivers on the North West European Shelf Sea.

Science.gov (United States)

Siemering, Beatrix; Bresnan, Eileen; Painter, Stuart C; Daniels, Chris J; Inall, Mark; Davidson, Keith

2016-01-01

The edge of the North West European Shelf (NWES) is characterised by a steep continental slope and a northward flowing slope current. These topographic/hydrographic features separate oceanic water and shelf water masses hence potentially separate phytoplankton communities. The slope current may facilitate the advective transport of phytoplankton, with mixing at the shelf edge supporting nutrient supply and therefore phytoplankton production. On the west Scottish shelf in particular, little is known about the phytoplankton communities in and around the shelf break and adjacent waters. Hence, to improve our understanding of environmental drivers of phytoplankton communities, biological and environmental data were collected on seven cross-shelf transects across the Malin and Hebridean Shelves during autumn 2014. Density profiles indicated that shelf break and oceanic stations had a 100 m deep mixed surface layer while stations on the shelf were generally well mixed. Analysis of similarity and multidimensional scaling of phytoplankton counts revealed that phytoplankton communities on the shelf were significantly different to those found at the shelf break and at oceanic stations. Shelf stations were dominated by dinoflagellates, with diatoms contributing a maximum of 37% of cells. Shelf break and oceanic stations were also dinoflagellate dominated but displayed a lower species diversity. Significant difference between shelf and shelf break stations suggested that the continental slope limited cross shelf phytoplankton exchange. Northern and southern phytoplankton communities on the shelf were approximately 15% dissimilar while there was no latitudinal gradient for stations along the slope current, suggesting this current provided south to north connectivity. Fitting environmental data to phytoplankton ordination showed a significant relationship between phytoplankton community dissimilarities and nutrient concentrations and light availability on the shelf compared to

Shelf life extension of whole-wheat breadsticks: Formulation and packaging strategies.

Science.gov (United States)

Alamprese, Cristina; Cappa, Carola; Ratti, Simona; Limbo, Sara; Signorelli, Marco; Fessas, Dimitrios; Lucisano, Mara

2017-09-01

The aim of this study was the shelf life extension of whole-wheat breadsticks through the addition of a rosemary extract and packaging under nitrogen. Shelf life was studied at four temperatures (20, 27, 35, 48°C) for up to 200 storage days. The minimal changes observed in moisture, water activity and texture of the samples, coupled with the high peroxide values (13-539meqO 2 /kg fat ) measured at the end of storage, and the exponential increase of hexanal concentrations (up to 13-34mg/kg) confirmed that quality decay of whole-wheat breadsticks is mainly associated to lipid oxidation. The kinetic study of oxidation development and the consumer sensory acceptance determined by the survival analysis demonstrated that the rosemary extract addition yields a 42% shelf life extension, higher than that observed using nitrogen in the package (24-29%). The combination of the formulation and packaging strategies gave the best result (83% shelf life extension at 25°C). Copyright © 2017 Elsevier Ltd. All rights reserved.

Oxidative stability of refined olive and sunflower oils supplemented with lycopene-rich oleoresin from tomato peels industrial by-product, during accelerated shelf-life storage.

Science.gov (United States)

Kehili, Mouna; Choura, Sirine; Zammel, Ayachi; Allouche, Noureddine; Sayadi, Sami

2018-04-25

Tomato peels by-product from a Tunisian industry was used for the extraction of lycopene-rich oleoresin using hexane solvent maceration. Tomato peels oleoresin, TPO, exhibited competitive free radicals scavenging activity with synthetic antioxidants. The efficacy of TPO in stabilizing refined olive (ROO) and sunflower (RSO) oils was investigated for five months, under accelerated shelf-life, compared to the synthetic antioxidant, butylated hydroxytoluene (BHT). TPO was added to ROO and RSO at four different concentrations, namely 250, 500, 1000 and 2000 µg/g and BHT standard at 200 µg/g. Lipid oxidation was tracked by measuring the peroxide value, acidity, conjugated dienes and trienes. Results suggested the highest efficiency of 250 µg/g and 2000 µg/g of TPO, referring to 5 µg/g and 40 µg/g of lycopene, for the oxidative stabilization of ROO and RSO, respectively. The protective effect of TPO against the primary oxidation of these refined oils was significantly correlated to their lycopene contents. Copyright © 2017 Elsevier Ltd. All rights reserved.

Refrigerated Shelf Life of a Coconut Water-Oatmeal Mix and the Viability of Lactobacillus Plantarum Lp 115-400B.

Science.gov (United States)

Dharmasena, Muthu; Barron, Felix; Fraser, Angela; Jiang, Xiuping

2015-08-10

Non-dairy probiotic products have the advantage of being lactose-free and can be manufactured to sustain the growth of probiotics. In this study, coconut water and oatmeal were used with the probiotic, Lactobacillus plantarum Lp 115-400B ( L. plantarum ) as a starter culture. Two separate treatments were carried out probiotic (P) and probiotic and prebiotic (PP) added. In both treatments, oatmeal-coconut water matrix was inoculated with 7 log CFU/g of L. plantarum and fermented at 27 °C for 10 h. For the PP treatment, 1 g of inulin/100 mL of the product was added additionally. The fermented products were then refrigerated (4 °C) and the viability of L. plantarum , pH, total acidity, and apparent viscosity of the matrix were monitored at selected time intervals. The shelf life to reach was defined by maintenance of L. plantarum count of 7 log CFU/g product. Refrigerated shelf life was determined to be seven-weeks for the P treatment and five-weeks for PP treatment. A significant reduction of pH was observed at the end of the considered shelf life; conversely, the apparent viscosity of the product did not change significantly.

Active packaging using ethylene absorber to extend shelf-life

Energy Technology Data Exchange (ETDEWEB)

Ponce, Patricia; Carbonari, Guilherme L.R.; Lugao, Ademar B. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)], e-mail: patponce@iq.usp.br, e-mail: guilacaz@uol.com.br, e-mail: ablugao@ipen.br

2009-07-01

Ethylene gas is a plant hormone which is produced by fruits and vegetables during ripening and it is also found in the environment. It plays an essential role in normal ripening, but excessive exposure can radically reduce the shelf-life of the product, in some cases inducing undesirable reactions such as development of bitter flavors and loss of chlorophyll (yellowing of greens). The objectives of our work were: to test an active packaging of polyvinyl alcohol (PVA) for apple stored; to test the effect of ethylene absorber agent, impregnated in plastic film, to reduce decay of fresh apple; to study the influence of radiation on the barrier properties, mechanical properties and biodegradability of PVA films. This study evaluated the effect of coating produced from PVA and polyol (glycerol and sorbitol) as plasticizer on apple conservation (75 deg F (24 deg C); 70%RH). The coated product was analyzed for mass loss, color alterations and fungi. The PVA films were produced by casting process (dehydration of a filmogenic solution on Petriplastic dishes) and were irradiated at low doses of 2, 5 and 10 kGy, commonly used in food irradiation. The resulting films were transparent and homogeneous. The active packaged fruits presented higher acceptance, lower microbiological growth, less alterations in acidity, lower weight loss rate during the storage time and an extended shelf-life as compared to the control fruits (without plastic films). (author)

Active packaging using ethylene absorber to extend shelf-life

International Nuclear Information System (INIS)

Ponce, Patricia; Carbonari, Guilherme L.R.; Lugao, Ademar B.

2009-01-01

Ethylene gas is a plant hormone which is produced by fruits and vegetables during ripening and it is also found in the environment. It plays an essential role in normal ripening, but excessive exposure can radically reduce the shelf-life of the product, in some cases inducing undesirable reactions such as development of bitter flavors and loss of chlorophyll (yellowing of greens). The objectives of our work were: to test an active packaging of polyvinyl alcohol (PVA) for apple stored; to test the effect of ethylene absorber agent, impregnated in plastic film, to reduce decay of fresh apple; to study the influence of radiation on the barrier properties, mechanical properties and biodegradability of PVA films. This study evaluated the effect of coating produced from PVA and polyol (glycerol and sorbitol) as plasticizer on apple conservation (75 deg F (24 deg C); 70%RH). The coated product was analyzed for mass loss, color alterations and fungi. The PVA films were produced by casting process (dehydration of a filmogenic solution on Petriplastic dishes) and were irradiated at low doses of 2, 5 and 10 kGy, commonly used in food irradiation. The resulting films were transparent and homogeneous. The active packaged fruits presented higher acceptance, lower microbiological growth, less alterations in acidity, lower weight loss rate during the storage time and an extended shelf-life as compared to the control fruits (without plastic films). (author)

Sediment transport processes at the head of Halibut Canyon, Eastern Canada margin: An interplay between internal tides and dense shelf water cascading.

Science.gov (United States)

Puig, Pere; Greenan, Blair J. W.; Li, Michael Z.; Prescott, Robert H.; Piper, David J. W.

2013-04-01

To investigate the processes by which sediment is transported through a submarine canyon incised in a glaciated margin, the bottom boundary layer quadrapod RALPH was deployed at 276-m depth in the West Halibut Canyon (off Newfoundland) during winter 2008-2009. Two main sediment transport processes were identified throughout the deployment. Firstly, periodic increases of near-bottom suspended-sediment concentrations (SSC) were recorded associated with the up-canyon propagation of the semidiurnal internal tidal bore along the canyon axis, carrying fine sediment particles resuspended from deeper canyon regions. The recorded SSC peaks, lasting less than one hour, were observed sporadically and were linked to bottom intensified up-canyon flows concomitant with sharp drops in temperature. Secondly, sediment transport was also observed during events of intensified down-canyon current velocities that occurred during periods of sustained heat loss from surface waters, but were not associated with large storms. High-resolution velocity profiles throughout the water column during these events revealed that the highest current speeds (~1 m s-1) were centered several meters above the sea floor and corresponded to the region of maximum velocities of a gravity flow. Such flows had associated low SSC and cold water temperatures and have been interpreted as dense shelf water cascading events channelized along the canyon axis. Sediment transport during these events was largely restricted to bedload and saltation, producing winnowing of sands and fine sediments around larger gravel particles. Analysis of historical hydrographic data suggests that the origin of such gravity flows is not related to the formation of coastal dense waters advected towards the canyon head. Rather, the dense shelf waters appear to be generated around the outer shelf, where convection during winter is able to reach the sea floor and generate a pool of near-bottom dense water that cascades into the canyon

Benthic iron and phosphorus release from river dominated shelf sediments under varying bottom water O2 concentrations.

Science.gov (United States)

Ghaisas, N. A.; Maiti, K.; White, J. R.

2017-12-01

Phosphorus (P) cycling in coastal ocean is predominantly controlled by river discharge and biogeochemistry of the sediments. In coastal Louisiana, sediment biogeochemistry is strongly influenced by seasonally fluctuating bottom water O2, which, in turn transitions the shelf sediments from being a sink to source of P. Sediment P-fluxes were 9.73 ± 0.76 mg / m2 /d and 0.67±0.16 mg/m2/d under anaerobic and aerobic conditions respectively, indicating a 14 times higher P-efflux from oxygen deprived sediments. A high sedimentary oxygen consumption rate of 889 ± 33.6 mg/m2/d was due to organic matter re-mineralization and resulted in progressively decreasing the water column dissolved O2 , coincident with a P-flux of 7.2 ± 5.5 mg/m2/d from the sediment. Corresponding water column flux of Fe total was 19.7 ± 7.80 mg/m2/d and the sediment-TP decreased from 545 mg/Kg to 513 mg/Kg. A simultaneous increase in pore water Fe and P concentrations in tandem with a 34.6% loss in sedimentary Fe-bound P underscores the importance of O2 on coupled Fe- P biogeochemistry. This study suggests that from a 14,025 sq. km hypoxia area, Louisiana shelf sediments can supply 1.33x105 kg P/day into the water column compared to 0.094 x 105 kg P/day during the fully aerobic water column conditions.

Dissolved iron in the Arctic shelf seas and surface waters of the central Arctic Ocean : Impact of Arctic river water and ice-melt

NARCIS (Netherlands)

Klunder, M. B.; Bauch, D.; Laan, P.; de Baar, H. J. W.; van Heuven, S.; Ober, S.

2012-01-01

Concentrations of dissolved (10 nM) in the bottom waters of the Laptev Sea shelf may be attributed to either sediment resuspension, sinking of brine or regeneration of DFe in the lower layers. A significant correlation (R-2 = 0.60) between salinity and DFe is observed. Using delta O-18, salinity,

EFFECT OF PASTEURIZATION TEMPERATURE AND ASEPTIC FILLING ON THE SHELF-LIFE OF MILK

Directory of Open Access Journals (Sweden)

Rodrigo Rodrigues PETRUS

2011-12-01

Full Text Available Aseptic filling process can contribute to extend the shelf-life of pasteurized milk. However, this technology is not still commercially practiced in Brazil for this product. The aim of this study was to evaluate the effect of the pasteurization temperature and aseptic filling on the stability of milk packaged in high density polyethylene bottle (HDPE. Three batches of one hundred bottles each were processed at 72, 83, and 94ºC/15s, followed by aseptic packaging and storage at 9ºC, simulating a deficient cold chain scenario as found in the Brazilian market. Microbiological stability evaluation was based on mesophilic and psychrotrophic counts. Sensory shelf-life was estimated according to the ratings assigned to the attributes appearance, aroma, flavor and overall appreciation of milk samples. The pasteurization temperature, in the range investigated, did not affect the shelf-life of milk, which lasted up to 11 days for the three processed batches. The aseptic filling, associated to the employed thermal treatments, did not extend the shelf-life of milk stored under the abuse condition of 9°C, considering that the commercial product shelf-life in Brazil is of about 10 days.

The effectiveness of various Rhizobacteria carriers to improve the shelf life and the stability of Rhizobacteria as Bioherbicide

Science.gov (United States)

Rakian, T. C.; Karimuna, L.; Taufik, M.; Sutariati, G. A. K.; Muhidin; Fermin, U.

2018-02-01

Deleterius Rhizobacteria (DRB) has a potential to control of weed and act as a bioherbicide. Developing a method to weed control that environmentally sound friendly has been increasingly studied. Rhizobacteria can form colonies on weed rooting and synthesize the secondary metabolite compounds. The effectiveness of rhizobacteria as bioherbicide is determined by its survival to be stored for a long time. The objective of this study is to obtain the type of carrier which effectively maintains the life and stability of DRB. Therefore it is necessary to do in vivo and in-vitro research. This study consists of two stages of testing the effectiveness of the carrier in increasing the shelf life of rhizobacteria and testing the effectiveness stability as a bioherbicide on Ageratum conyzoides weed after storage for 20 weeks. Research was conducted in Agronomy Lab, Agriculture Faculty, Halu Oleo University Kendari, Since August to December 2016. Research found that the talc powder and chaff charcoal powder were effective as a carrier of rhizobacteria and able to maintain the viability of rhizobacteria Bacillus lentus A05 and Pseudomonas aeruginosa A08 for five months and also able to maintain the stability of rhizobacteria as bioherbicide.

Sonograph patterns of the central western continental shelf of India

Digital Repository Service at National Institute of Oceanography (India)

Rao, P.S.

knolls. A transition zone with tonal variations is present between 40 and 60 m water depth. Ground-truth data sediment and rock distribution maps indicate depositional (inner shelf), nondepositional or erosional (outer shelf) environments and a...

Dynamics of internal waves on the Southeast Florida shelf: Implications for cross-shelf exchange and turbulent mixing on a barrier reef system

Science.gov (United States)

Davis, Kristen Alexis

The dynamics of internal waves shoaling on the Southeast Florida shelf and the resulting stratified turbulence in the shelf bottom boundary layer are investigated using observational studies completed during the summers of 2003-2005. This work is driven by a desire to understand the effects of internal wave-driven flow and the shoreward transport of cool, nutrient-rich water masses on cross-shelf exchange, vertical mixing, and mass transfer to benthic reef organisms. Shelf sea internal wave fields are typically highly variable and dominated by wind and tidal forces. However, this is not necessarily true for outer shelf regions or very narrow shelves where remote physical processes originating over the slope or deep ocean may exert a strong influence on the internal wave climate. During the summers of 2003 and 2004 observational studies were conducted to examine the effects of a western boundary current (the Florida Current), tides, and wind on the mean currents and internal wave field on the outer Southeast Florida shelf. We present evidence that suggests that the Florida Current plays as large a role in the determination of the high frequency internal wave field as tidal forces. These observations and analyses show that it is necessary to include the forcing from the Florida Current meanders and instabilities in order to predict accurately the episodic nature of the internal wave field on the Southeast Florida shelf. Deep ocean and continental shelf processes intersect at the shelf edge and influence the exchange of water masses and their associated characteristics including heat, nutrients, sediment, and larvae across the shelf. Thus, the dynamics of cross-shelf circulation have important consequences for organisms living on the shelf. In the second phase of this work, we investigate physical mechanisms controlling the exchange of water masses during the summer season across the Southeast Florida shelf. A time series of cross-shelf transport from May to August

Atlantic update, July 1986--June 1990: Outer Continental Shelf oil and gas activities

Energy Technology Data Exchange (ETDEWEB)

Karpas, R.M.; Gould, G.J.

1990-10-01

This report describes outer continental shelf oil and gas activities in the Atlantic Region. This edition of the Atlantic Update includes an overview of the Mid-Atlantic Planning Area and a summary of the Manteo Prospect off-shore North Carolina. 6 figs., 8 tabs.

FEBEX bentonite colloid stability in ground water

Energy Technology Data Exchange (ETDEWEB)

Seher, H.; Schaefer, T.; Geckeis, H. [Inst. fuer Nukleare Entsorgung (INE), Forschungszentrum Karlsruhe, 76021 Karlsruhe (Germany)]. e-mail: holger.seher@ine.fzk .de; Fanghaenel, T. [Ruprecht-Karls-Univ. Heidelberg, Physikalisch-Chemisches In st., D-69120 Heidelberg (Germany)

2007-06-15

Coagulation experiments are accomplished to identify the geochemical conditions for the stability of Febex bentonite colloids in granite ground water. The experiments are carried out by varying pH, ionic strength and type of electrolyte. The dynamic light scattering technique (photon correlation spectroscopy) is used to measure the size evolution of the colloids with time. Agglomeration rates are higher in MgCl{sub 2} and CaCl{sub 2} than in NaCl solution. Relative agglomeration rates follow approximately the Schulze-Hardy rule. Increasing agglomeration rates at pH>8 are observed in experiments with MgCl{sub 2} and CaCl{sub 2} which are, however, caused by coprecipitation phenomena. Bentonite colloid stability fields derived from the colloid agglomeration experiments predict low colloid stabilization in granite ground water taken from Aespoe, Sweden, and relatively high colloid stability in Grimsel ground water (Switzerland)

Variability of Basal Melt Beneath the Pine Island Glacier Ice Shelf, West Antarctica

Science.gov (United States)

Bindschadler, Robert; Vaughan, David G.; Vornberger, Patricia

2011-01-01

Observations from satellite and airborne platforms are combined with model calculations to infer the nature and efficiency of basal melting of the Pine Island Glacier ice shelf, West Antarctica, by ocean waters. Satellite imagery shows surface features that suggest ice-shelf-wide changes to the ocean s influence on the ice shelf as the grounding line retreated. Longitudinal profiles of ice surface and bottom elevations are analyzed to reveal a spatially dependent pattern of basal melt with an annual melt flux of 40.5 Gt/a. One profile captures a persistent set of surface waves that correlates with quasi-annual variations of atmospheric forcing of Amundsen Sea circulation patterns, establishing a direct connection between atmospheric variability and sub-ice-shelf melting. Ice surface troughs are hydrostatically compensated by ice-bottom voids up to 150m deep. Voids form dynamically at the grounding line, triggered by enhanced melting when warmer-than-average water arrives. Subsequent enlargement of the voids is thermally inefficient (4% or less) compared with an overall melting efficiency beneath the ice shelf of 22%. Residual warm water is believed to cause three persistent polynyas at the ice-shelf front seen in Landsat imagery. Landsat thermal imagery confirms the occurrence of warm water at the same locations.

Modified, Packaged Tortillas Have Long Shelf Life

Science.gov (United States)

Bourland, Charles; Glaus-Late, Kimberly

1995-01-01

Tortillas made from modified recipe and sealed in low-pressure nitrogen in foil pouches in effort to increase their shelf life at room temperature. Preliminary tests show that shelf life of these tortillas at least five months; in contrast, commercial tortillas last only few days. Part of water in recipe replaced with glycerin. Particularly necessary to avoid Clostridium botulinum, which grows in anaerobic environments and produces deadly toxin that causes botulism.

Refrigerated Shelf Life of a Coconut Water-Oatmeal Mix and the Viability of Lactobacillus Plantarum Lp 115-400B

Directory of Open Access Journals (Sweden)

Muthu Dharmasena

2015-08-01

Full Text Available Non-dairy probiotic products have the advantage of being lactose-free and can be manufactured to sustain the growth of probiotics. In this study, coconut water and oatmeal were used with the probiotic, Lactobacillus plantarum Lp 115-400B (L. plantarum as a starter culture. Two separate treatments were carried out probiotic (P and probiotic and prebiotic (PP added. In both treatments, oatmeal-coconut water matrix was inoculated with 7 log CFU/g of L. plantarum and fermented at 27 °C for 10 h. For the PP treatment, 1 g of inulin/100 mL of the product was added additionally. The fermented products were then refrigerated (4 °C and the viability of L. plantarum, pH, total acidity, and apparent viscosity of the matrix were monitored at selected time intervals. The shelf life to reach was defined by maintenance of L. plantarum count of 7 log CFU/g product. Refrigerated shelf life was determined to be seven-weeks for the P treatment and five-weeks for PP treatment. A significant reduction of pH was observed at the end of the considered shelf life; conversely, the apparent viscosity of the product did not change significantly.

Controls on reef development and the terrigenous-carbonate interface on a shallow shelf, Nicaragua (Central America)

Science.gov (United States)

Roberts, H. H.; Murray, S. P.

1983-06-01

Marine geology and physical oceanographic data collected during two field projects (˜4 months) on the Caribbean shelf of Nicaragua indicate a surprising dominance of carbonate deposition and reef growth on a shelf that is receiving an abnormally large volume of terrigenous sediments. High rainfall rates (˜400 500 cm/year), coupled with a warm tropical climate, encourage rapid denudation of the country's central volcanic highland and transport of large volumes of terrigenous sediment and fresh water to the coast. Estimates suggest that three times more fresh water and fifteen times more sediment are introduced per unit length of coastline than on the east coast of the United States. Distribution of the terrigenous facies, development of carbonate sediment suites, and the location and quality of viable reefs are strongly controlled by the dynamic interaction near the coasts of highly turbid fresh to brackish water effluents from thirteen rivers with clear marine waters of the shelf. Oceanic water from the central Caribbean drift current intersects the shelf and moves slowely in a dominant northwest direction toward the Yucatan Channel. A sluggish secondary gyre moves to the south toward Costa Rica. In contrast, the turbid coastal water is deflected to the south in response to density gradients, surface water slopes, and momentum supplied by the steady northeast trade winds. A distinct two-layered flow is commonly present in the sediment-rich coastal boundary zone, which is typically 10 20 km wide. The low-salinity upper layer is frictionally uncoupled from the ambient shelf water and therefore can expand out of the normally coherent coastal boundary zone during periods of abnormal flooding or times when instability is introduced into the northeast trades. Reef distribution, abruptness of the terrigenous-carbonate interface, and general shelf morphology reflect the long-term dynamic structure of the shelf waters. A smooth-bottomed ramp of siliciclastic sands to

Assessment of MODIS-Aqua chlorophyll-a algorithms in coastal and shelf waters of the eastern Arabian Sea

Science.gov (United States)

Tilstone, Gavin H.; Lotliker, Aneesh A.; Miller, Peter I.; Ashraf, P. Muhamed; Kumar, T. Srinivasa; Suresh, T.; Ragavan, B. R.; Menon, Harilal B.

2013-08-01

The use of ocean colour remote sensing to facilitate the monitoring of phytoplankton biomass in coastal waters is hampered by the high variability in absorption and scattering from substances other than phytoplankton. The eastern Arabian Sea coastal shelf is influenced by river run-off, winter convection and monsoon upwelling. Bio-optical parameters were measured along this coast from March 2009 to June 2011, to characterise the optical water type and validate three Chlorophyll-a (Chla) algorithms applied to Moderate Resolution Imaging Spectroradiometer on Aqua (MODIS-Aqua) data against in situ measurements. Ocean Colour 3 band ratio (OC3M), Garver-Siegel-Maritorena Model (GSM) and Generalized Inherent Optical Property (GIOP) Chla algorithms were evaluated. OC3M performed better than GSM and GIOP in all regions and overall, was within 11% of in situ Chla. GSM was within 24% of in situ Chla and GIOP on average was 55% lower. OC3M was less affected by errors in remote sensing reflectance Rrs(λ) and by spectral variations in absorption coefficient (aCDOM(λ)) of coloured dissolved organic material (CDOM) and total suspended matter (TSM) compared to the other algorithms. A nine year Chla time series from 2002 to 2011 was generated to assess regional differences between OC3M and GSM. This showed that in the north eastern shelf, maximum Chla occurred during the winter monsoon from December to February, where GSM consistently gave higher Chla compared to OC3M. In the south eastern shelf, maximum Chla occurred in June to July during the summer monsoon upwelling, and OC3M yielded higher Chla compared to GSM. OC3M currently provides the most accurate Chla estimates for the eastern Arabian Sea coastal waters.

Evaluating Current Practices in Shelf Life Estimation.

Science.gov (United States)

Capen, Robert; Christopher, David; Forenzo, Patrick; Huynh-Ba, Kim; LeBlond, David; Liu, Oscar; O'Neill, John; Patterson, Nate; Quinlan, Michelle; Rajagopalan, Radhika; Schwenke, James; Stroup, Walter

2018-02-01

The current International Council for Harmonisation of Technical Requirements for Pharmaceuticals for Human Use (ICH) methods for determining the supported shelf life of a drug product, described in ICH guidance documents Q1A and Q1E, are evaluated in this paper. To support this evaluation, an industry data set is used which is comprised of 26 individual stability batches of a common drug product where most batches are measured over a 24 month storage period. Using randomly sampled sets of 3 or 6 batches from the industry data set, the current ICH methods are assessed from three perspectives. First, the distributional properties of the supported shelf lives are summarized and compared to the distributional properties of the true shelf lives associated with the industry data set, assuming the industry data set represents a finite population of drug product batches for discussion purposes. Second, the results of the ICH "poolability" tests for model selection are summarized and the separate shelf life distributions from the possible alternative models are compared. Finally, the ICH methods are evaluated in terms of their ability to manage risk. Shelf life estimates that are too long result in an unacceptable percentage of nonconforming batches at expiry while those that are too short put the manufacturer at risk of possibly having to prematurely discard safe and efficacious drug product. Based on the analysis of the industry data set, the ICH-recommended approach did not produce supported shelf lives that effectively managed risk. Alternative approaches are required.

Hydrocarbon production forecast for committed assets in the shallow water Outer Continental Shelf of the Gulf of Mexico

International Nuclear Information System (INIS)

Kaiser, Mark J.

2009-01-01

In 2007, the federal waters of the Gulf of Mexico averaged daily production of 1.3 million barrels of oil and 7.6 billion cubic feet of natural gas. The majority of oil is produced from deepwater fields in water depth greater than 1000 ft, while most gas production is extracted from the shelf. The Outer Continental Shelf is a mature province with over 3800 fixed structures and 6500 producing wells connected into an integrated pipeline network more than 30,000 miles in length. The purpose of this paper is to develop a methodology to forecast oil and gas production in the shallow water Gulf of Mexico. Structures are categorized according to age and production characteristics, and forecast procedures for each asset class are described and illustrated. The methodology is implemented using the inventory of committed assets circa December 2006. The expected amount of hydrocarbon production arising from the inventory of committed assets under stable reservoir and investment conditions is estimated to be 1056 MMbbl oil and 13.3 Tcf gas valued between $85 and 150 billion. The results of generalized regression models are presented with a discussion of the limitations of analysis. (author)

Exchanges between the shelf and the deep Black Sea: an integrated analysis of physical mechanisms

Science.gov (United States)

Shapiro, Georgy; Wobus, Fred; Zatsepin, Andrei; Akivis, Tatiana; Zhou, Feng

2017-04-01

the analysis of propagation of cold waters formed on the NW Black Sea shelf we use a passive tracer method. The tracer is treated as an artificial dye that "stains" a water parcel within the defined area as soon as it cooled below a 7°C temperature. To quantify the shelf-deep sea exchange, the transport of water, salt and heat between the NW shelf and deep-sea regions is calculated across an enclosed boundary (a "fence") approximating the 200 m isobath on the NW shelf plus two short segments connected to the coast. Partial transports are also calculated for the surface layer (top 20 m) and the under-surface layer (from 20 m to the bottom). The 20 m level is approximately equal to the Ekman depth in summer. It is also close to the depth of the biologically active euphotic layer. For validation of the NEMO-BLS24 configuration we present comparisons of the model with satellite-derived sea surface temperature measurements and with ship-derived cross-sections that show the vertical structure. We also compare the model to observations carried out during Black Sea cruises in 2004, 2007 and 2008. The model represents well the sea surface temperature, the depth of the upper mixed layer and the depth of the CIL, while overestimating the temperature in the core of the CIL by approx. 0.5 °C. Mechanism 1: exchanges due to a frontal eddy. Numerical simulations for the year 2005 (for which comprehensive remote sensed data is available) shows that a significant cross-shelf transport was generated by a long-lived anticyclonic eddy impinging on the shelf, sometimes assisted by a cyclonic meander of the Rim Current. Over 69 days between April 23 and June 30, 2005, a volume of 2.84×10^12 m3 of water (102% of the entire volume of the shelf waters) was transported out of the shelf and a similar amount onto the shelf (see details in Zhou et al. 2014). Mechanism 2: exchanges due to Ekman drift. During the short but intensive wind events of April 15 - 22 and July 1 - 4, 2005, 23% and 16

Climatology of the oceanography in the northern South China Sea Shelf-sea (NoSoCS) and adjacent waters: Observations from satellite remote sensing

Science.gov (United States)

Pan, X.; Wong, G. T.; Tai, J.; Ho, T.

2013-12-01

By using the observations from multiple satellite sensors, the climatology of the oceanography, including the surface wind vector, sea surface temperature (SST), surface chlorophyll a concentration (Chl_a), and vertically integrated net primary production (PPeu), in the northern South China Sea Shelf-sea (NoSoCS) and adjacent waters is evaluated. Regional and sub-regional mechanisms in driving the coastal processes, which influence the spatial and temporal distributional patterns in water component, are assessed. Seasonal vertical convective mixing by wind and surface heating/cooling is the primary force in driving the annual changes in SST and Chl_a in the open South China Sea (SCS), in which highly negative correlation coefficients between Chl_a and SST and moderately positive correlation coefficients between Chl_a and wind speed are found. Together, the seasonal variations in SST and wind speed account for about 80% of the seasonal variation in Chl_a. In the NoSoCS as a whole, however, the contribution is reduced to about 40%, primarily due to the effect of the Pearl River plume. A tongue of water extending eastward from the mouth of the River into the middle shelf with positive correlation coefficients between Chl_a and SST and around zero or slightly negative correlation coefficients between Chl_a and wind is the most striking feature in the NoSoCS. The westward and eastward propagations of the Pearl River plume are both very small during the northeast monsoonal season, driven primarily by the Coriolis effect. The abrupt increase in the areal coverage of the River plume, which is much more pronounced in the eastward propagation, between June and August can be attributed to the prevailing southwest monsoon as well as the annual peak of the river flow. Coastal upwelling is another sub-regional phenomenon in the NoSoCS. The upwelling at the shelf edge off the Taiwan Bank may be characterized by its elevated Chl_a. Its areal coverage and average Chl_a do not vary

Radioimmunoassay procedure using a stabilized complex

International Nuclear Information System (INIS)

Sultanian, I.V.; Irani, J.H.

1978-01-01

An improved radioimmunoassay procedure involves the use of a stabilized complex of labelled antigen and antibody which has an extended shelf life as compared to the same complex absent the stabilizers. Since the time needed to incubate the mixture of labelled antigen and antibody is eliminated, the time for completing the assay is considerably shortened and simplified. The components for carrying out the procedure are packaged in a kit basically including standard antigen for generation of a standard curve, a stabilized labelled antigen-antibody complex and reference serum, if used. A plurality of stabilizers are used in the complex to provide a shelf life of six weeks or more. 10 claims

Mean Lagrangian drift in continental shelf waves

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Drivdal, M.; Weber, J. E. H.

2012-04-01

The time- and depth-averaged mean drift induced by barotropic continental shelf waves (CSW's) is studied theoretically for idealized shelf topography by calculating the mean volume fluxes to second order in wave amplitude. The waves suffer weak spatial damping due to bottom friction, which leads to radiation stress forcing of the mean fluxes. In terms of the total wave energy density E¯ over the shelf region, the radiation stress tensor component S¯11 for CSW's is found to be different from that of shallow water surface waves in a non-rotating ocean. For CSW's, the ratio ¯S11/¯E depends strongly on the wave number. The mean Lagrangian flow forced by the radiation stress can be subdivided into a Stokes drift and a mean Eulerian drift current. The magnitude of the latter depends on the ratio between the radiation stress and the bottom stress acting on the mean flow. When the effect of bottom friction acts equally strong on the waves and the mean current, calculations for short CSW's show that the Stokes drift and the friction-dependent wave-induced mean Eulerian current varies approximately in anti-phase over the shelf, and that the latter is numerically the largest. For long CSW's they are approximately in phase. In both cases the mean Lagrangian current, which is responsible for the net particle drift, has its largest numerical value at the coast on the shallow part of the shelf. Enhancing the effect of bottom friction on the Eulerian mean flow, results in a general current speed reduction, as well as a change in spatial structure for long waves. Applying realistic physical parameters for the continental shelf west of Norway, calculations yield along-shelf mean drift velocities for short CSW's that may be important for the transport of biological material, neutral tracers, and underwater plumes of dissolved oil from deep water drilling accidents.

ANALISIS KADAR AIR DAN AKTIFITAS AIR KRITIKAL PRODUK SATA DARI MALAYSIA DAN IMPLIKASINYA PADA SIFAT-SIFAT PRODUK DAN UMUR SIMPANNYA [Analysis of Critical Moisture and Water Activity of Malaysian Sata and Its Implication to Product Characteristics and Shelf Life

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Rita Hayati1

2005-12-01

Full Text Available Critical moisture and water activity of Sata. a Malaysian traditional food made of fish and young coconut meats, were analyzed for the first and second critical points of transition among the primary, secondary and tertiary bound water fractions in the Sata. It was found out that the first critical points of moisture content and water activity were M, of 5.09 % db (4.73 % wb and ar of 0.44 respectively. The second critical points were water content M5 of 19.38 % db(15.2 % wb and water activity as of 79 % respectively. The upper limit of he tertiary bound water (Mt was 75.3 % db (43.0 % wb. Sate sample in the primary bound water fraction (represented by moisture content at 5.0 % rib / 4.73 % wb, was stable in color and appearance, but slightly rancid due to molecular mobility of the liquid oil content The sample in the secondary bound water fraction (represented by moisture content of 15.0% db / 13.0% wb, has a color change to darker brown: and in the tertiary bound water fraction (represented by moisture of 30.5 % db / 23.4 % wb, mold growth appeared on the 10th day storage. The characteristics of the Malaysian Sate indicated an intermediate moisture food (IMF with water content of 37.5% wb, water activity of 0.9 and limited shelf tile to, few days at room temperature.

Effect of buffer and antioxidant on stability of a mercaptopurine suspension.

Science.gov (United States)

Aliabadi, Hamidreza Montazeri; Romanick, Marcel; Desai, Sunil; Lavasanifar, Afsaneh

2008-03-01

The stability of standard and modified mercaptopurine suspensions when stored at room temperature and under refrigerated conditions to test the feasibility of increasing shelf life was studied. A 50-mg/mL mercaptopurine suspension was compounded by adding simple syrup, cherry syrup, and sterile water for irrigation to triturated mercaptopurine tablets for the initial reference formulation. Three additional formulations were prepared by adding an antioxidant (ascorbic acid 10 mg), a buffer (sodium phosphate monobasic monohydrate 500 mg), and a combination of antioxidant and buffer to the reference formulation. Each compounded batch was divided into two parts and stored in amber bottles at room temperature (19-23 degrees C) or under refrigerated conditions (4-8 degrees C). Analysis through high-performance liquid chromatography determined mercaptopurine levels after three and seven days and weekly thereafter for at least two weeks after shelf life was reached under specified storage conditions. Solutions with at least 93% of the original mercaptopurine concentration and with no observable sign of aggregation or cake formation were considered stable. The reference suspension of mercaptopurine showed an acceptable physical and chemical stability of up to 5 weeks when stored at room temperature. The addition of ascorbic acid extended the shelf life of the compounded suspension to 11 weeks. However, the addition of sodium phosphate monobasic did not improve the stability of mercaptopurine in the suspension. The results showed a higher stability for all formulations after storage at room temperature compared with those stored in a refrigerator. A standard oral suspension of mercaptopurine contained an acceptable drug concentration for up to 5 weeks when stored at room temperature. The addition of ascorbic acid at a concentration of 0.1% w/v to the standard formulation increased the suspension's shelf life at room temperature to 11 weeks.

Seabed geology of the Canadian eastern continental shelf

Science.gov (United States)

Piper, David J. W.

1991-08-01

The physiography of the continental shelf off eastern Canada is irregular, developed by glacial erosion of a previously fluvially-dominated landscape. Northern shelves are deeper than southern shelves. Most surficial sediments on the shelf are relict or palimpsest. The principal modern source of sediment to the northern shelves is ice rafting and iceberg scour reworking of Quaternary sediments. Southern shelves receive sediment through erosion of Quaternary sediments; only small amounts of fine-grained sediment derived from coastal erosion and rivers escape from the coastal zone. Regional maps of sediment texture, carbonate content and heavy mineralogy consequently show differences between the northern and southern shelves. Large areas of the shelf show little net deposition. On the northern shelves, there is a surface veneer up to 0.5 m thick derived from ice rafting and iceberg turbation of underlying Quaternary sediment, modified by south-flowing currents [ WOODWORTH-LYNASet al. (this issue) Continental Shelf Research, 11, 939-961]. The overall effects of former iceberg turbation may extend to a depth of 10 m sub-bottom. On the southern shelves, bioturbation and perhaps storm-related currents rework exposed Quaternary sediments more slowly. Muds accumulate in deep basins on the shelves at rates of about 0.5 m per 1000 years; this accumulation is probably episodic and related to major storms reworking sediment from the surface sediment veneer in shallower areas of little net deposition. In water depths less than 110 m sand and gravel have formed as a result of reworking in the coastal zone during the post-glacial transgression. Over large areas of Georges Bank, the eastern Scotian Shelf and the Grand Banks of Newfoundland, such sands are mobilized during storms to form a wide suite of bedforms [ AMOS and JUDGE (this issue) Continental Shelf Research, 11, 1037-1068]. Elsewhere, particularly in deeper water, sandy surfaces appear moribund or inactive and large

Infaunal macrobenthic community of soft bottom sediment in a tropical shelf

Digital Repository Service at National Institute of Oceanography (India)

Jayaraj, K.A.; Jacob, J.; DineshKumar, P.K.

Studies of benthic communities in tropical shelf waters are limited. In this study, we deal with the infaunal benthic community of soft bottom sediment of the tropical eastern Arabian Sea shelf. Benthic macroinfauna was sampled with a Smith...

Mixing processes at the subsurface layer in the Amundsen Sea shelf region

Science.gov (United States)

Mojica, J.; Djoumna, G.; Francis, D. K.; Holland, D.

2017-12-01

In the Amundsen Sea shelf region, mixing processes promote an upward transport of diapycnal fluxes of heat and salt from the subsurface to the surface mixing layer. Here we estimate the diapycnal mixing rates on the Amundsen shelf from a multi-year mooring cluster and five research cruises. By applying fine-scale parameterizations, the mixing rates obtained were higher near the southern end of Pine Island glacier front and exceeded 10-2 m2s-1. The eddy diffusivity increased near the critical latitude (74o 28' S) for semi-diurnal M2 tides, which coincided with near-critical topography on the shelf. This condition favored the generation of internal waves of M2 frequency. The semi-diurnal dynamic enhanced the mixing that potentially affected the heat budget and the circulation of the modified Circumpolar Deep Water. This can be observed in the characteristics of water exchange both below the ice shelves and between the continental shelf and the ice shelf cavities. The location of the critical latitude and critical topography provided favorable conditions for the generation of internal waves. KEYWORDS: Mixing processes, diapycnal fluxes, critical latitude, Circumpolar Deep Water.

Improved protocol and data analysis for accelerated shelf-life estimation of solid dosage forms.

Science.gov (United States)

Waterman, Kenneth C; Carella, Anthony J; Gumkowski, Michael J; Lukulay, Patrick; MacDonald, Bruce C; Roy, Michael C; Shamblin, Sheri L

2007-04-01

To propose and test a new accelerated aging protocol for solid-state, small molecule pharmaceuticals which provides faster predictions for drug substance and drug product shelf-life. The concept of an isoconversion paradigm, where times in different temperature and humidity-controlled stability chambers are set to provide a critical degradant level, is introduced for solid-state pharmaceuticals. Reliable estimates for temperature and relative humidity effects are handled using a humidity-corrected Arrhenius equation, where temperature and relative humidity are assumed to be orthogonal. Imprecision is incorporated into a Monte-Carlo simulation to propagate the variations inherent in the experiment. In early development phases, greater imprecision in predictions is tolerated to allow faster screening with reduced sampling. Early development data are then used to design appropriate test conditions for more reliable later stability estimations. Examples are reported showing that predicted shelf-life values for lower temperatures and different relative humidities are consistent with the measured shelf-life values at those conditions. The new protocols and analyses provide accurate and precise shelf-life estimations in a reduced time from current state of the art.

Seabed fluid expulsion along the upper slope and outer shelf of the U.S. Atlantic continental margin

Science.gov (United States)

Brothers, D.S.; Ruppel, C.; Kluesner, J.W.; ten Brink, Uri S.; Chaytor, J.D.; Hill, J.C.; Andrews, B.D.; Flores, C.

2014-01-01

Identifying the spatial distribution of seabed fluid expulsion features is crucial for understanding the substrate plumbing system of any continental margin. A 1100 km stretch of the U.S. Atlantic margin contains more than 5000 pockmarks at water depths of 120 m (shelf edge) to 700 m (upper slope), mostly updip of the contemporary gas hydrate stability zone (GHSZ). Advanced attribute analyses of high-resolution multichannel seismic reflection data reveal gas-charged sediment and probable fluid chimneys beneath pockmark fields. A series of enhanced reflectors, inferred to represent hydrate-bearing sediments, occur within the GHSZ. Differential sediment loading at the shelf edge and warming-induced gas hydrate dissociation along the upper slope are the proposed mechanisms that led to transient changes in substrate pore fluid overpressure, vertical fluid/gas migration, and pockmark formation.

Transport of plutonium in surface and sub-surface waters from the Arctic shelf to the North Pole via the Lomonosov Ridge

International Nuclear Information System (INIS)

Leon Vintro, L.; McMahon, C.A.; Mitchell, P.I.; Josefsson, D.; Holm, E.; Roos, P.

2002-01-01

New data on the levels and long-range transport of plutonium in the Arctic Ocean, recorded in the course of two expeditions to this zone in 1994 and 1996, are discussed in this paper. Specifically, approximately 100 plutonium measurements in surface and sub-surface water sampled at 58 separate stations throughout the Kara, Laptev and East Siberian Seas, as well as along latitudinal transects across the Lomonosov Ridge, are reported and interpreted in terms of the circulation pathways responsible for the transport of this element from the North Atlantic to the Arctic Shelf and into the Arctic interior. In addition, the behaviour of plutonium in its transit through the vast Arctic shelf seas to open waters under extreme environmental conditions is discussed in terms of the partitioning of plutonium between filtered (<0.45 μm) seawater and suspended particulate, and its association with colloidal matter. Finally, limited evidence of the presence of a colloidal plutonium component in Arctic waters subject to direct riverine input is adduced

Using aerogravity and seismic data to model the bathymetry and upper crustal structure beneath the Pine Island Glacier ice shelf, West Antarctica

Science.gov (United States)

Muto, A.; Peters, L. E.; Anandakrishnan, S.; Alley, R. B.; Riverman, K. L.

2013-12-01

Recent estimates indicate that ice shelves along the Amundsen Sea coast in West Antarctica are losing substantial mass through sub-ice-shelf melting and contributing to the accelerating mass loss of the grounded ice buttressed by them. For Pine Island Glacier (PIG), relatively warm Circumpolar Deep Water has been identified as the key driver of the sub-ice-shelf melting although poor constraints on PIG sub-ice shelf have restricted thorough understanding of these ice-ocean interactions. Aerogravity data from NASA's Operation IceBridge (OIB) have been useful in identifying large-scale (on the order of ten kilometers) features but the results have relatively large uncertainties due to the inherent non-uniqueness of the gravity inversion. Seismic methods offer the most direct means of providing water thickness and upper crustal geological constraints, but availability of such data sets over the PIG ice shelf has been limited due to logistical constraints. Here we present a comparative analysis of the bathymetry and upper crustal structure beneath the ice shelf of PIG through joint inversion of OIB aerogravity data and in situ active-source seismic measurements collected in the 2012-13 austral summer. Preliminary results indicate improved resolution of the ocean cavity, particularly in the interior and sides of the PIG ice shelf, and sedimentary drape across the region. Seismically derived variations in ice and ocean water densities are also applied to the gravity inversion to produce a more robust model of PIG sub-ice shelf structure, as opposed to commonly used single ice and water densities across the entire study region. Misfits between the seismically-constrained gravity inversion and that estimated previously from aerogravity alone provide insights on the sensitivity of gravity measurements to model perturbations and highlight the limitations of employing gravity data to model ice shelf environments when no other sub-ice constraints are available.

Signatures of Late Quaternary sea-level changes and Neo-tectonic activity over Visakhapatnam - Gopalpur shelf, east coast of India

Digital Repository Service at National Institute of Oceanography (India)

Rao, K.M.; Reddy, N.P.C; PremKumar, M.K.; Raju, Y.S.N.; Venkateswarlu, K.; Murthy, K.S.R.

High-resolution shallow seismic and echo sounding profiles of the continental shelf between Visakhapatnam and Gopalpur reveal prominent morphological features like terraces, reefs and pinnacles at different water depths of 80-100 m, 50-30 m...

Long-Term Stability of New Co-Amorphous Drug Binary Systems: Study of Glass Transitions as a Function of Composition and Shelf Time

Directory of Open Access Journals (Sweden)

Luz María Martínez

2016-12-01

Full Text Available The amorphous state is of particular interest in the pharmaceutical industry due to the higher solubility that amorphous active pharmaceutical ingredients show compared to their respective crystalline forms. Due to their thermodynamic instability, drugs in the amorphous state tend to recrystallize; in order to avoid crystallization, it has been a common strategy to add a second component to hinder the crystalline state and form a thermally stable co-amorphous system, that is to say, an amorphous binary system which retains its amorphous structure. The second component can be a small molecule excipient (such as a sugar or an aminoacid or a second drug, with the advantage that a second active pharmaceutical ingredient could be used for complementary or combined therapeutic purposes. In most cases, the compositions studied are limited to 1:1, 2:1 and 1:2 molar ratios, leaving a gap of information about phase transitions and stability on the amorphous state in a wider range of compositions. In the present work, a study of novel co–amorphous formulations in which the selection of the active pharmaceutical ingredients was made according to the therapeutic effect is presented. Resistance against crystallization and behavior of glass transition temperature ( T g were studied through calorimetric measurements as a function of composition and shelf time. It was found that binary formulations with T g temperatures higher than those of pure components presented long-term thermal stability. In addition, significant increments of T g values, of as much as 15 ∘ C, were detected as a result of glass relaxation at room temperature during storage time; this behavior of glass transition has not been previously reported for co-amorphous drugs. Based on these results, it can be concluded that monitoring behavior of T g and relaxation processes during the first weeks of storage leads to a more objective evaluation of the thermomechanical stability of an amorphous

Decadal variability on the Northwest European continental shelf

Science.gov (United States)

Jones, Sam; Cottier, Finlo; Inall, Mark; Griffiths, Colin

2018-02-01

Decadal scale time series of the shelf seas are important for understanding both climate and process studies. Despite numerous investigations of long-term temperature variability in the shelf seas, studies of salinity variability are few. Salt is a more conservative tracer than temperature in shallow seas, and it can reveal changes in local hydrographic conditions as well as transmitted basin-scale changes. Here, new inter-annual salinity time series on the northwest European shelf are developed and a 13 year high resolution salinity record from a coastal mooring in western Scotland is presented and analysed. We find strong temporal variability in coastal salinity on timescales ranging from tidal to inter-annual, with the magnitude of variability greatest during winter months. There is little seasonality and no significant decadal trend in the coastal time series of salinity. We propose 4 hydrographic states to explain salinity variance in the shelf area west of Scotland based on the interaction between a baroclinic coastal current and wind-forced barotropic flow: while wind forcing is important, we find that changes in the buoyancy-driven flow are more likely to influence long-term salinity observations. We calculate that during prevailing westerly wind conditions, surface waters in the Sea of the Hebrides receive a mix of 62% Atlantic origin water to 38% coastal sources. This contrasts with easterly wind conditions, during which the mix is 6% Atlantic to 94% coastal sources on average. This 'switching' between hydrographic states is expected to impact nutrient transport and therefore modify the level of primary productivity on the shelf. This strong local variability in salinity is roughly an order of magnitude greater than changes in the adjacent ocean basin, and we infer from this that Scottish coastal waters are likely to be resilient to decadal changes in ocean climate.

Phase behavior of fluorocarbon and hydrocarbon double-chain hydroxylated and galactosylated amphiphiles and bolaamphiphiles. Long-term shelf-stability of their liposomes.

Science.gov (United States)

Clary, L; Gadras, C; Greiner, J; Rolland, J P; Santaella, C; Vierling, P; Gulik, A

1999-06-01

This paper describes the morphological characterization, by freeze-fracture electron microscopy, and the thermotropic phase behavior, by differential scanning calorimetry and/or X-ray scattering, of aqueous dispersions of various hydroxylated and galactosylated double-chain amphiphiles and bolaamphiphiles, several of them containing one or two hydrophobic fluorocarbon chains. Colloidal systems are observed in water with the hydroxylated hydrocarbon or fluorocarbon bolaamphiphiles only when they are dispersed with a co-amphiphile such as rac-1,2-dimyristoylphosphatidylcholine (DMPC) or rac-1,2-distearoylphosphatidylcholine (DSPC). Liposomes are formed providing the relative content of bolaamphiphiles does not exceed 20% mol. Most of these liposomes can be thermally sterilized and stored at room temperature for several months without any significant modification of their size and size distribution. The hydrocarbon galactosylated bolaamphiphile HO[C24][C12]Gal forms in water a lamellar phase (the gel to liquid-crystal phase transition is complete at 45 degrees C) and a Im3m cubic phase above 47 degrees C. The fluorocarbon HO[C24][F6C5]Gal analog displays a more complex and metastable phase behavior. The fluorinated non-bolaform galactosylated [F8C7][C16]AEGal and SerGal amphiphiles form lamellar phases in water. Low amounts (10% molar ratio) of the HO[C24][F6C5]Gal or HO[C24][C12]Gal bolaamphiphiles or of the single-headed [F8C7][C16]AEGal improve substantially the shelf-stability of reference phospholipon/cholesterol 2/1 liposomes. These liposomes when co-formulated with a single-headed amphiphile from the SerGal series are by far less stable.

The salinity signature of the cross-shelf exchanges in the Southwestern Atlantic Ocean: Satellite observations.

Science.gov (United States)

Guerrero, Raul A; Piola, Alberto R; Fenco, Harold; Matano, Ricardo P; Combes, Vincent; Chao, Yi; James, Corinne; Palma, Elbio D; Saraceno, Martin; Strub, P Ted

2014-11-01

Satellite-derived sea surface salinity (SSS) data from Aquarius and SMOS are used to study the shelf-open ocean exchanges in the western South Atlantic near 35°S. Away from the tropics, these exchanges cause the largest SSS variability throughout the South Atlantic. The data reveal a well-defined seasonal pattern of SSS during the analyzed period and of the location of the export of low-salinity shelf waters. In spring and summer, low-salinity waters over the shelf expand offshore and are transferred to the open ocean primarily southeast of the river mouth (from 36°S to 37°30'S). In contrast, in fall and winter, low-salinity waters extend along a coastal plume and the export path to the open ocean distributes along the offshore edge of the plume. The strong seasonal SSS pattern is modulated by the seasonality of the along-shelf component of the wind stress over the shelf. However, the combined analysis of SSS, satellite-derived sea surface elevation and surface velocity data suggest that the precise location of the export of shelf waters depends on offshore circulation patterns, such as the location of the Brazil Malvinas Confluence and mesoscale eddies and meanders of the Brazil Current. The satellite data indicate that in summer, mixtures of low-salinity shelf waters are swiftly driven toward the ocean interior along the axis of the Brazil/Malvinas Confluence. In winter, episodic wind reversals force the low-salinity coastal plume offshore where they mix with tropical waters within the Brazil Current and create a warmer variety of low-salinity waters in the open ocean. Satellite salinity sensors capture low-salinity detrainment events from shelves SW Atlantic low-salinity detrainments cause highest basin-scale variability In summer low-salinity detrainments cause extended low-salinity anomalies.

Intense Undular Bores on the Autumn Pycnocline of Shelf Waters of the Peter the Great Bay (Sea of Japan)

Science.gov (United States)

Dolgikh, G. I.; Novotryasov, V. V.; Yaroshchuk, I. O.; Permyakov, M. S.

2018-03-01

The results of field observations of an internal undular bore that were performed in a coastal zone of constant depth in the Sea of Japan are presented. A hydrodynamic model of undular bores is discussed according to which the recorded disturbances of the water medium are an experimental prototype of strongly nonlinear (intense) internal undular bores on the pycnocline of shelf waters of Peter the Great Bay with an intensity close to the limit.

Freeze Drying Improves the Shelf-Life of Conductive Polymer Modified Neural Electrodes

Directory of Open Access Journals (Sweden)

Himadri S. Mandal

2015-08-01

Full Text Available Coating microelectrodes with conductive polymer is widely recognized to decrease impedance and improve performance of implantable neural devices during recording and stimulation. A concern for wide-spread use of this approach is shelf-life, i.e., the electrochemical stability of the coated microelectrodes prior to use. In this work, we investigated the possibility of using the freeze-drying process in order to retain the native low impedance state and, thereby, improve the shelf-life of conductive polymer poly(3,4-ethylenedioxythiophene (PEDOT-PSS modified neural electrodes. Control PEDOT-PSS coated microelectrodes demonstrated a significant increase in impedance at 1 kHz after 41–50 days of room temperature storage. Based on equivalent circuit modeling derived from electrochemical impedance spectroscopy, this increase in impedance could be largely attributed to a decrease in the interfacial capacitance consistent with a collapse and closing of the porous structure of the polymeric coating. Time-dependent electrochemical impedance measurements revealed higher stability of the freeze-dried coated microelectrodes compared to the controls, such that impedance values after 41–50 days appeared to be indistinguishable from the initial levels. This suggests that freeze drying PEDOT-PSS coated microelectrodes correlates with enhanced electrochemical stability during shelf storage.

Synchronous response of sedimentary organic carbon accumulation on the inner shelf of the East China Sea to the water impoundment of Three Gorges and Gezhouba Dams

Science.gov (United States)

Lin, Jia; Zhu, Qing; Hong, Yuehui; Yuan, Lirong; Liu, Jinzhong; Xu, Xiaoming; Wang, Jianghai

2018-01-01

Coastal seas, located between continents and the open ocean, are an important active carbon pool. The sedimentary total organic carbon (TOC) in these areas is a mixture of terrestrial and marine sources, and can be a powerful proxy for tracing natural processes and human activities. In this study, one fine-grained sediment core (DH5-1) from the inner shelf of the East China Sea was systematically analyzed for TOC and black carbon (BC) contents and TOC stable carbon isotope ratios (δ13C). By combining these data with 210Pb dating, an improved carbon correction model and a two end-member mixing model, we reconstructed century-scale high-resolution sequences of corrected TOC, terrestrial TOC and marine TOC contents and identified two carbon depletion events in the DH5-1 record. The two events, shown as two minima in the TOC profiles, correspond temporally to 1985-1987 AD and 2003-2006 AD, which exactly matches the water impoundment of the Gezhouba Dam and Three Gorges Dam, respectively. In addition, the variations in TOC contents and δ13C values before, during or after the minima demonstrate a relationship between the depletion events and water impoundment of the dams on the Changjiang River. The TOC reductions may represent synchronous responses of sedimentary TOC and resultant ecological effects on the inner shelf of the East China Sea to the water impoundment of the dams. These new TOC records reflect the interaction between natural and anthropogenic processes and, accordingly, provide a deep insight and important references for assessing marine ecological effects resulting from water impoundment of largescale dams.

Phytoplankton community structure in relation to hydrographic features along a coast-to-offshore transect on the SW Atlantic Continental Shelf

Science.gov (United States)

Islabão, C. A.; Mendes, C. R. B.; Detoni, A. M. S.; Odebrecht, C.

2017-12-01

The continental shelf in Southern Brazil is characterized by high biological productivity associated with horizontal and vertical density gradients due to the mixing of distinct water masses. Phytoplankton biomass and composition were evaluated in summer 2013 along an on-offshore transect off the mouth of the Patos Lagoon (Lat. 32°12S). Photosynthetic active radiation, temperature, salinity and fluorescence vertical profiles were carried out and Brünt-Väisäla frequency was estimated. Three water bodies were identified: the Subtropical Shelf Water along the entire transect, the Plata Plume Water on the middle shelf surface and the Tropical Water farther offshore. The water was sampled (N = 40) for the analyses of dissolved inorganic nutrients, phytoplankton cell density and composition. Phytoplankton present in the water was identified and quantified by the classical microscope sedimentation technique, complemented with CHEMTAX analysis of high-performance liquid chromatography (HPLC) pigment data. From the results obtained, chlorophyll a concentration was higher at both coastal stations (1.6-2.0 mg m-3) where the water column was homogeneous and diatoms dominated the stations. This group was replaced by dinoflagellates in stratified conditions on the shelf and farther offshore. Along the onshore-offshore gradient, two types of dinoflagellates were found: the peridinin-containing dinoflagellates Prorocentrum and Scrippsiella with a small contribution at the coastal stations, and the fucoxantin-containing small Gymnodiniales cells (< 15 μm) with more than 50% of the total chlorophyll a at the stations on the continental shelf, especially associated with the chlorophyll maximum at the base of the euphotic zone. The positive (negative) relationship between the biomass of dinoflagellates (diatoms) with the Brünt-Väisäla frequency, respectively, support the hypothesis that stratification is the most important environmental factor that determines the biomass of

The effect of irradiation temperature on the quality improvement of Kimchi, Korean fermented vegetables, for its shelf stability

Energy Technology Data Exchange (ETDEWEB)

Park, Jin-Gyu [Team for Radiation Food Science and Biotechnology, Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup 580-185 (Korea, Republic of); Department of Food and Biotechnology, Korea University, Chungnam 339-700 (Korea, Republic of); Kim, Jae-Hun; Park, Jae-Nam [Team for Radiation Food Science and Biotechnology, Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup 580-185 (Korea, Republic of); Kim, Young-Duk [CJ Food Research and Development, CJ Corp., Seoul 152-050 (Korea, Republic of); Kim, Wang-Geun [Department of Application Science and Technology, Chosun University, Gwangju 501-759 (Korea, Republic of); Lee, Ju-Woon [Team for Radiation Food Science and Biotechnology, Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup 580-185 (Korea, Republic of); Hwang, Han-Joon [Department of Food and Biotechnology, Korea University, Chungnam 339-700 (Korea, Republic of); Byun, Myung-Woo [Team for Radiation Food Science and Biotechnology, Advanced Radiation Technology Institute, Korea Atomic Energy Research Institute, Jeongeup 580-185 (Korea, Republic of)], E-mail: mwbyun@kaeri.re.kr

2008-04-15

The present study was conducted to evaluate the effect of irradiation temperature on the shelf stability and quality of Kimchi during storage at 35 deg. C for 30 days. Kimchi samples were N{sub 2}-packaged and heated at 60 deg. C and then gamma irradiated at 20 kGy under various temperatures (room temperature, ice, dry ice, and liquid nitrogen). In the results of microbial, pH, and acidity analysis, combination treatment of heating and irradiation was able to sterilize microbes in Kimchi regardless of irradiation temperature. When Kimchi was irradiated under frozen temperatures, especially dry ice, the softening of texture and the deterioration of sensory quality of Kimchi were reduced. Also, ESR signal intensities were weakened due to the decrease of irradiation dose and temperature.

The effect of irradiation temperature on the quality improvement of Kimchi, Korean fermented vegetables, for its shelf stability

International Nuclear Information System (INIS)

Park, Jin-Gyu; Kim, Jae-Hun; Park, Jae-Nam; Kim, Young-Duk; Kim, Wang-Geun; Lee, Ju-Woon; Hwang, Han-Joon; Byun, Myung-Woo

2008-01-01

The present study was conducted to evaluate the effect of irradiation temperature on the shelf stability and quality of Kimchi during storage at 35 deg. C for 30 days. Kimchi samples were N 2 -packaged and heated at 60 deg. C and then gamma irradiated at 20 kGy under various temperatures (room temperature, ice, dry ice, and liquid nitrogen). In the results of microbial, pH, and acidity analysis, combination treatment of heating and irradiation was able to sterilize microbes in Kimchi regardless of irradiation temperature. When Kimchi was irradiated under frozen temperatures, especially dry ice, the softening of texture and the deterioration of sensory quality of Kimchi were reduced. Also, ESR signal intensities were weakened due to the decrease of irradiation dose and temperature

The effect of a novel photodynamic activation method mediated by curcumin on oyster shelf life and quality.

Science.gov (United States)

Liu, Fang; Li, Zhaojie; Cao, Binbin; Wu, Juan; Wang, Yuming; Xue, Yong; Xu, Jie; Xue, Changhu; Tang, Qing Juan

2016-09-01

In this paper, the effect of photodynamic method mediated by curcumin (PDT) on the shelf life and quality of pacific oysters during storage at 5±1°C were analyzed. In our previous study we investigated the optimal treatment conditions of photodynamic method mediated by curcumin to sterilization were 10uM photosensitizer concentration and 5.4J/cm 2 light energy density. Under these conditions, the effect of a novel photodynamic activation method mediated by curcumin on oyster shelf life and quality was researched. The total bacterial counts, TVB-N content and sensory analysis were used to evaluate the effects on oyster shelf life. The oyster shelf life was prolonged from 8days to 12days after photodynamic treatment and the oysters in the treatment group displayed notable odor retention, produced fewer odor corrupting substances when the control group oysters reached the end of their shelf life (day 8). Texture, free amino acid contents and fatty acid levels were applied to estimate the quality of the treated oysters. The texture had no significant change after treated with PDT. At the end of oyster shelf life, compared PDT group (PDT) with control group (control), total free amino acid contents (control: 234.30mg/100g, PDT: 813.02mg/100g) was higher and free fatty acid levels (control: 0.071mEq/L, PDT: 0.0455mEq/L) displayed lower in PDT group. This indicated that the treated oysters oxidized minimally, decayed slowly, decomposed fewer nutrients and had lower metabolic levels of spoilage microorganisms. PDT has a positive effect on prolonging oyster shelf life and its quality. Copyright © 2016 Elsevier Ltd. All rights reserved.

Efficacy evaluation of a new water sanitizer for increasing the shelf life of Southern Australian King George Whiting and Tasmanian Atlantic Salmon fillets.

Science.gov (United States)

Khazandi, Manouchehr; Deo, Permal; Ferro, Sergio; Venter, Henrietta; Pi, Hongfei; Crabb, Simon; Amorico, Tony; Ogunniyi, Abiodun D; Trott, Darren J

2017-12-01

The bacterial species and specific spoilage organisms associated with the Southern Australian King George Whiting (KGW) and Tasmanian Atlantic Salmon (TAS), and the efficacy of a HOCl-containing water-based sanitization product (Electro-Chemically Activated Solution, by ECAS4) in extending the shelf life of KGW and TAS fillets were evaluated. Fillets were washed with an ECAS4 solution containing either 45 ppm or 150 ppm of free chlorine and bacterial species enumerated on selective and non-selective media, followed by identification of pure isolates by 16 S rRNA gene sequencing. The dominant spoilage microbiota in KGW and TAS fillets stored at 4 ± 1 °C were Pseudomonas spp. and Shewanella spp. At either concentration, ECAS4 significantly reduced total bacterial load and specific spoilage organisms on KGW and TAS fillets (approx. 1-2 log colony-forming units) during storage and significantly extended the shelf life of the fillets by 2 and 4 days, respectively. The significant increase in shelf life and quality of fillets was corroborated by raw and cooked sensory evaluation. ECAS4 sanitization could have a significant impact on the overall food industry, translating into health and economic benefits through reduction of food spoilage bacteria and potentially, foodborne pathogens without many of the disadvantages of currently approved biocides. Copyright © 2017 Elsevier Ltd. All rights reserved.

Macronutrient and carbon supply, uptake and cycling across the Antarctic Peninsula shelf during summer.

Science.gov (United States)

Henley, Sian F; Jones, Elizabeth M; Venables, Hugh J; Meredith, Michael P; Firing, Yvonne L; Dittrich, Ribanna; Heiser, Sabrina; Stefels, Jacqueline; Dougans, Julie

2018-06-28

The West Antarctic Peninsula shelf is a region of high seasonal primary production which supports a large and productive food web, where macronutrients and inorganic carbon are sourced primarily from intrusions of warm saline Circumpolar Deep Water. We examined the cross-shelf modification of this water mass during mid-summer 2015 to understand the supply of nutrients and carbon to the productive surface ocean, and their subsequent uptake and cycling. We show that nitrate, phosphate, silicic acid and inorganic carbon are progressively enriched in subsurface waters across the shelf, contrary to cross-shelf reductions in heat, salinity and density. We use nutrient stoichiometric and isotopic approaches to invoke remineralization of organic matter, including nitrification below the euphotic surface layer, and dissolution of biogenic silica in deeper waters and potentially shelf sediment porewaters, as the primary drivers of cross-shelf enrichments. Regenerated nitrate and phosphate account for a significant proportion of the total pools of these nutrients in the upper ocean, with implications for the seasonal carbon sink. Understanding nutrient and carbon dynamics in this region now will inform predictions of future biogeochemical changes in the context of substantial variability and ongoing changes in the physical environment.This article is part of the theme issue 'The marine system of the West Antarctic Peninsula: status and strategy for progress in a region of rapid change'. © 2018 The Authors.

The assessment of optimal MERIS ocean colour products in the shelf waters of the KwaZulu-Natal Bight, South Africa

CSIR Research Space (South Africa)

Smith, ME

2013-10-01

Full Text Available The KwaZulu-Natal Bight is a highly variable bio-optical environment, where waters over the shelf can change from the oligotrophic case 1 conditions of the Agulhas Current to the case 2 inshore environment influenced by upwelling and riverine influx...

Front-Eddy Influence on Water Column Properties, Phytoplankton Community Structure, and Cross-Shelf Exchange of Diatom Taxa in the Shelf-Slope Area off Concepción (˜36-37°S)

Science.gov (United States)

Morales, Carmen E.; Anabalón, Valeria; Bento, Joaquim P.; Hormazabal, Samuel; Cornejo, Marcela; Correa-Ramírez, Marco A.; Silva, Nelson

2017-11-01

In eastern boundary current systems (EBCSs), submesoscale to mesocale variability contributes to cross-shore exchanges of water properties, nutrients, and plankton. Data from a short-term summer survey and satellite time series (January-February 2014) were used to characterize submesoscale variability in oceanographic conditions and phytoplankton distribution across the coastal upwelling and coastal transition zones north of Punta Lavapié, and to explore cross-shelf exchanges of diatom taxa. A thermohaline front (FRN-1) flanked by a mesoscale anticyclonic intrathermocline eddy (ITE-1), or mode-water eddy, persisted during the time series and the survey was undertaken during a wind relaxation event. At the survey time, ITE-1 contributed to an onshore intrusion of warm oceanic waters (southern section) and an offshore advection of cold coastal waters (northern section), with the latter forming a cold, high chlorophyll-a filament. In situ phytoplankton and diatom biomasses were highest at the surface in FRN-1 and at the subsurface in ITE-1, whereas values in the coastal zone were lower and dominated by smaller cells. Diatom species typical of the coastal zone and species dominant in oceanic waters were both found in the FRN-1 and ITE-1 interaction area, suggesting that this mixture was the result of both offshore and onshore advection. Overall, front-eddy interactions in EBCSs could enhance cross-shelf exchanges of coastal and oceanic plankton, as well as sustain phytoplankton growth in the slope area through localized upward injections of nutrients in the frontal zone, combined with ITE-induced advection and vertical nutrient inputs to the surface layer.

Interannual variability of surface and bottom sediment transport on the Laptev Sea shelf during summer

Directory of Open Access Journals (Sweden)

C. Wegner

2013-02-01

Full Text Available Sediment transport dynamics were studied during ice-free conditions under different atmospheric circulation regimes on the Laptev Sea shelf (Siberian Arctic. To study the interannual variability of suspended particulate matter (SPM dynamics and their coupling with the variability in surface river water distribution on the Laptev Sea shelf, detailed oceanographic, optical (turbidity and Ocean Color satellite data, and hydrochemical (nutrients, SPM, stable oxygen isotopes process studies were carried out continuously during the summers of 2007 and 2008. Thus, for the first time SPM and nutrient variations on the Laptev Sea shelf under different atmospheric forcing and the implications for the turbidity and transparency of the water column can be presented.

The data indicate a clear link between different surface distributions of riverine waters and the SPM transport dynamics within the entire water column. The summer of 2007 was dominated by shoreward winds and an eastward transport of riverine surface waters. The surface SPM concentration on the southeastern inner shelf was elevated, which led to decreased transmissivity and increased light absorption. Surface SPM concentrations in the central and northern Laptev Sea were comparatively low. However, the SPM transport and concentration within the bottom nepheloid layer increased considerably on the entire eastern shelf. The summer of 2008 was dominated by offshore winds and northward transport of the river plume. The surface SPM transport was enhanced and extended onto the mid-shelf, whereas the bottom SPM transport and concentration was diminished. This study suggests that the SPM concentration and transport, in both the surface and bottom nepheloid layers, are associated with the distribution of riverine surface waters which are linked to the atmospheric circulation patterns over the Laptev Sea and the adjacent Arctic Ocean during the open water season. A continuing trend toward

Surficial sediments of the continental shelf off Karnataka

Digital Repository Service at National Institute of Oceanography (India)

Hashimi, N.H.; Nair, R.R.

sediments occur betweenthe water depths of 15 to 50m corresponding to a distance of about 40 km from the coast. Beyond 50 m to the shelf edge are calcareous sands. Non-carbonate components of these deep water sands are essentially quartz, many of which...

Dissolved inorganic nutrients and chlorophyll on the narrow continental shelf of Eastern Brazil

Directory of Open Access Journals (Sweden)

Gilmara Fernandes Eça

2014-03-01

Full Text Available The eastern Brazilian continental shelf is narrow and subject to the influence of a western boundary current system, presenting lower biological productivity than other regions. In this study, the distribution of water masses, dissolved inorganic nutrients, chlorophyll-a and total suspended solids (TSS on the inner shelf (< 35 m depth, between Itacaré and Canavieiras, eastern Brazil, is presented. Sampling surveys were carried out in March and August 2006 and March 2007. Tropical water (TW prevailed during March 2006 and August 2007 with the lower salinity waters (< 36 found in most samples taken in March 2007, reflecting the influence of continental outflow and rain in coastal waters. Low concentrations of dissolved inorganic nutrients and Chl-a found were typical of TW and results suggested that the inner shelf waters were depleted in dissolved inorganic nitrogen in August 2006 and March 2007, and in phosphate in March 2006, potentially affecting phytoplankton growth. Stratification of the water column was observed due to differences in dissolved nutrient concentrations, chlorophyll-a and TSS when comparing surface and bottom samples, possibly the result of a colder water intrusion and mixing on the bottom shelf and a deep chlorophyll maximum and/or sediment resuspension effect. Despite this stratification, oceanographic processes such as lateral mixing driven by the Brazil Current as well as a northward alongshore drift driven by winds and tides transporting Coastal Water can lead to an enhanced mixing of these waters promoting some heterogeneity in this oligotrophic environment.

Study of sorption behavior, shelf life and colour kinetics of vacuum puffed honey powder at accelerated storage conditions.

Science.gov (United States)

Devi, K Deepika; Paul, Sanjib Kr; Sahu, Jatindra K

2016-05-01

In the study, the storage life of vacuum puffed honey powder at accelerated storage environment (90 % relative humidity and 36 °C) was computed by determining the sticky-point moisture content as the critical parameter of the honey powder. The value of monolayer moisture content in the GAB model was calculated to be 0.081 kg water/kg dry solids by fitting water activity and moisture sorption data. Shelf life of the honey powder was predicted to be 222 days when the powder was packaged in aluminum foil-laminated polyethylene pouches with permeability value of 5.427X10(-8) kg/m(2)//day/Pa. Actual shelf life of honey powder was experimentally determined as 189 days and analysis of mean relative percent derivation modulus (Rd) and root mean square (RMS) established the accuracy and acceptability of the technique for the prediction of shelf life of honey powder. Overall colour deviation pattern followed first order reaction kinetics with rate constant (k1) as 0.037 day(-1). This study revealed overall colour difference of 18.1 till the end of shelf life with drastic change during initial storage period.

Retaining Oxidative Stability of Emulsified Foods by Novel Nonmigratory Polyphenol Coated Active Packaging.

Science.gov (United States)

Roman, Maxine J; Decker, Eric A; Goddard, Julie M

2016-07-13

Oxidation causes lipid rancidity, discoloration, and nutrient degradation that decrease shelf life of packaged foods. Synthetic additives are effective oxidation inhibitors, but are undesirable to consumers who prefer "clean" label products. The aim of this study was to improve oxidative stability of emulsified foods by a novel nonmigratory polyphenol coated active packaging. Polyphenol coatings were applied to chitosan functionalized polypropylene (PP) by laccase assisted polymerization of catechol and catechin. Polyphenol coated PP exhibited both metal chelating (39.3 ± 2.5 nmol Fe(3+) cm(-2), pH 4.0) and radical scavenging (up to 52.9 ± 1.8 nmol Trolox eq cm(-2)) capacity, resulting in dual antioxidant functionality to inhibit lipid oxidation and lycopene degradation in emulsions. Nonmigratory polyphenol coated PP inhibited ferric iron promoted degradation better than soluble chelators, potentially by partitioning iron from the emulsion droplet interface. This work demonstrates that polyphenol coatings can be designed for advanced material chemistry solutions in active food packaging.

Statistical evaluation of accelerated stability data obtained at a single temperature. I. Effect of experimental errors in evaluation of stability data obtained.

Science.gov (United States)

Yoshioka, S; Aso, Y; Takeda, Y

1990-06-01

Accelerated stability data obtained at a single temperature is statistically evaluated, and the utility of such data for assessment of stability is discussed focussing on the chemical stability of solution-state dosage forms. The probability that the drug content of a product is observed to be within the lower specification limit in the accelerated test is interpreted graphically. This probability depends on experimental errors in the assay and temperature control, as well as the true degradation rate and activation energy. Therefore, the observation that the drug content meets the specification in the accelerated testing can provide only limited information on the shelf-life of the drug, without the knowledge of the activation energy and the accuracy and precision of the assay and temperature control.

A summary of the low upper shelf toughness safety margin issue

International Nuclear Information System (INIS)

Merkle, J.G.

1991-01-01

The low upper shelf toughness issue has a long history, beginning with the choice of materials for the submerged arc welding process, but also potentially involving the use of A302-B plate. Criteria for vessels containing low upper shelf materials have usually been expressed in terms of the Charpy upper shelf impact energy. Although these criteria have had several different bases, the range of limiting values for wall thicknesses approaching 229 mm (9 in.) has remained between 54 to 68J (40 to 50 ft lbs). Allowable values for vessels with thinner walls and/or only circumferential low upper shelf welds might conceivably be less. A decision on criteria to be incorporated into the ASME Code is now being made. Choices to be made concern the method for estimating the decrease in upper shelf impact energy, flaw geometry for circumferential welds, statistical significance of toughness values, the choice between J D and J M , reference pressure, safety factors and the inclusion of tearing stability calculations by means of R curve extrapolation. NRC research programs have contributed significantly to the resolution of the low upper shelf issue. These programs embrace all aspects of the issue, including material characterization, large scale testing, analysis and criteria development. 52 refs., 5 figs

Nutrient regeneration and oxygen demand in Bering Sea continental shelf sediments

Science.gov (United States)

Rowe, Gilbert T.; Phoel, William C.

1992-04-01

Measurements of seabed oxygen demand and nutrient regeneration were made on continental shelf sediments in the southeast Bering Sea from 1 to 15 June 1981. The mean seabed oxygen demand was relatively modest (267 μM O 2 m -2 h -1), equivalent to a utilization of 60 mg organic carbon m -2 day -1. The seasonal build up of ammonium over the mid-shelf domain was generated at least in part by the bottom biota, as previously suggested ( WHITLEDGEet al., 1986 , Continental Shelf Research, 5, 109-132), but on the outer shelf nitrate replaced ammonium as the dominant inorganic nitrogen compound that was regenerated from the sediments. Comparison of oxygen consumption with the organic matter in sedimenting particulate matter (sampled with sediment traps) could imply that benthic processes were not accounting for the fate of considerable quantities of organic matter. Benthic oxygen demand rates, however, probably lag behind the input of the spring bloom to the bottom, thus extending the remineralization process out over time. Consumption by small microheterotrophs in the water column was also a likely sink, although shelf export and advective transport north were possible as well. Estimated nitrification rates in surface sediments could account for only a small fraction of the abrupt increase in nitrate observed in the water column over the shelf just prior to the spring bloom.

Effects of electron beam irradiation combined with hot water immersion treatment for shelf life extension of bananas

International Nuclear Information System (INIS)

Russly Abdul Rahman

1996-01-01

A study of the effects of minimal processing treatments, both individually or in combinations, was carried out in order to extend the shelf life and to improve the quality of bananas. Pre climacteric bananas at light full three-quarter grade, were either treated with hot water immersion for 1-30 min at 45-55 degree C, or irradiated with electron beams (2.0 MeV, Van de Graaff accelerator), to a dose of 0.1-1.5 kGy. All fruit was stored at 21 ± 1 degree C and relative humidity of 85-95 %. There was no significant delay in ripening of fruit treated with hot water immersion at the above temperatures. Some damage to fruit particularly peel scalding at ends occurred at the higher temperatures (>50 degree C). The 50 degree C, 5 minutes immersion was selected for further study. Irradiation to 0.1-0.3 kGy delayed the ripening (up to 3 days) without affecting fruit quality. Doses greater than 0.4 kGy resulted in extensive discoloration and fruit splitting. No significant differences could be detected organoleptically between bananas irradiated at 0.15 kGy and the control. Results of the physico-chemical attributes of the bananas were reported for fruits at colour stage 5 and after 10 and 15 days of storage. The combination treatment of hot water immersion and irradiation at the above settings further extended the shelf life of the banana fruits

Shelf-Life of Chlorine Solutions Recommended in Ebola Virus Disease Response.

Science.gov (United States)

Iqbal, Qais; Lubeck-Schricker, Maya; Wells, Emma; Wolfe, Marlene K; Lantagne, Daniele

2016-01-01

In Ebola Virus Disease (EVD) outbreaks, it is widely recommended to wash living things (handwashing) with 0.05% (500 mg/L) chlorine solution and non-living things (surfaces, personal protective equipment, dead bodies) with 0.5% (5,000 mg/L) chlorine solution. Chlorine solutions used in EVD response are primarily made from powdered calcium hypochlorite (HTH), granular sodium dichloroisocyanurate (NaDCC), and liquid sodium hypochlorite (NaOCl), and have a pH range of 5-11. Chlorine solutions degrade following a reaction highly dependent on, and unusually sensitive to, pH, temperature, and concentration. We determined the shelf-life of 0.05% and 0.5% chlorine solutions used in EVD response, including HTH, NaDCC, stabilized NaOCl, generated NaOCl, and neutralized NaOCl solutions. Solutions were stored for 30 days at 25, 30, and 35°C, and tested daily for chlorine concentration and pH. Maximum shelf-life was defined as days until initial concentration fell to pH = 7) had a maximum shelf-life of a few hours, NaDCC solutions (pH = 6) 2 days, generated NaOCl solutions (pH = 9) 6 days, and HTH and stabilized NaOCl solutions (pH 9-11) >30 days. Models were developed for solutions with maximum shelf-lives between 1-30 days. Extrapolating to 40°C, the maximum predicted shelf-life for 0.05% and 0.5% NaDCC solutions were 0.38 and 0.82 hours, respectively; predicted shelf-life for 0.05% and 0.5% generated NaOCl solutions were >30 and 5.4 days, respectively. Each chlorine solution type offers advantages and disadvantages to responders, as: NaDCC is an easy-to-import high-concentration effervescent powder; HTH is similar, but forms a precipitate that may clog pipes; and, NaOCl solutions can be made locally, but are difficult to transport. We recommend responders chose the most appropriate source chlorine compound for their use, and ensure solutions are stored at appropriate temperatures and used or replaced before expiring.

Water-stabilized plasma generators

Czech Academy of Sciences Publication Activity Database

Hrabovský, Milan

1998-01-01

Roč. 70, č. 6 (1998), s. 1157-1162 ISSN 0033-4545 R&D Projects: GA ČR GA102/95/0592; GA ČR GV106/96/K245 Institutional research plan: CEZ:AV0Z2043910 Keywords : thermal plasma, plasma torch, water-stabilized plasma Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 1.677, year: 1998

The yogurt amino acid profile's variation during the shelf-life.

Science.gov (United States)

Germani, A; Luneia, R; Nigro, F; Vitiello, V; Donini, L M; del Balzo, V

2014-01-01

To analyze the yogurt amino acid profile starting from marketing through the whole shelf-life. The evaluation of the proteolytic activity of Lactobacillus delbrueckii subsp. bulgaricus and Streptococcus salivarius subsp. thermophilus, allows to deduce their vitality during the shelf-life period and within 45 days. Three types of full fats yogurts have been analyzed (a) natural white (b) sweet white and (c) whole fruit - in two stages: t0 (first day of shelf-life) and t1 (end of shelf-life). The proteins have been analyzed by the Kjeldahl method and the amino acid profile by HPLC. In natural yogurt a significant increase of the amount of free amino acids has been observed during the period of shelf-life (97%). In the sweetened full fats and fruit yogurt, instead, there is a lower increase of respectively 33% and 39% In whole milk natural yogurt, based on our data, the proteolytic activity seems to persist during the entire period of the shelf-life and this can be considered an index of bacterial survival, especially of Lactobacillus delbrueckii subsp. bulgaricus during the marketing process.

Zooplankton and ichthyoplankton distribution on the southern Brazilian shelf: an overview

Directory of Open Access Journals (Sweden)

Rubens M. Lopes

2006-06-01

Full Text Available The southern Brazilian coast is the major fishery ground for the Brazilian sardine (Sardinella brasiliensis, a species responsible for up to 40% of marine fish catches in the region. Fish spawning and recruitment are locally influenced by seasonal advection of nutrient-rich waters from both inshore and offshore sources. Plankton communities are otherwise controlled by regenerative processes related to the oligotrophic nature of the Tropical Water from the Brazil Current. As recorded in other continental margins, zooplankton species diversity increases towards outer shelf and open ocean waters. Peaks of zooplankton biomass and ichthyoplankton abundance are frequent on the inner shelf, either at upwelling sites or off large estuarine systems. However, meandering features of the Brazil Current provide an additional mechanism of upward motion of the cold and nutrient-rich South Atlantic Central Water, increasing phyto- and zooplankton biomass and production on mid- and outer shelves. Cold neritic waters originating off Argentina, and subtropical waters from the Subtropical Convergence exert a strong seasonal influence on zooplankton and ichthyoplankton distribution towards more southern areas. This brief review highlights the need for further experimental studies on zooplankton life cycle strategies in order to understand the major processes controlling food web dynamics in this shelf ecosystem.

A stability identification system for boiling water nuclear reactors

International Nuclear Information System (INIS)

Belblidia, L.A.; Chevrier, A.

1994-01-01

Boiling water reactors are subject to instabilities under low-flow, high-power operating conditions. These instabilities are a safety concern and it is therefore important to determine stability margins. This paper describes a method to estimate a measure of stability margin, called the decay ratio, from autoregressive modelling of time series data. A phenomenological model of a boiling water reactor with known stability characteristics is used to generate time series to validate the program. The program is then applied to signals from local power range monitors from the cycle 7 stability tests at the Leibstadt plant. (author) 7 figs., 2 tabs., 12 refs

Chronicling ice shelf history in the sediments left behind

Science.gov (United States)

Rosenheim, B. E.; Subt, C.; Shevenell, A.; Guitard, M.; Vadman, K. J.; DeCesare, M.; Wellner, J. S.; Bart, P. J.; Lee, J. I.; Domack, E. W.; Yoo, K. C.; Hayes, J. M.

2017-12-01

Collapsing and retreating ice shelves leave unmistakable sediment sequences on the Antarctic margin. These sequences tell unequivocal stories of collapse or retreat through a typical progression of sub-ice shelf diamicton (marking the past positions of grounding lines), sequentially overlain by a granulated facies from beneath the ice shelf, ice rafted debris from the calving line, and finally open marine sediment. The timelines to these stories, however, are troublesome. Difficulties in chronicling these stories recorded in sediment have betrayed their importance to our understanding of a warming world in many cases. The difficulties involve the concerted lack of preservation/production of calcium carbonate tests from the water column above and admixture of relict organic material from older sources of carbon. Here, we summarize our advances in the last decade of overcoming difficulties associated with the paucity of carbonate and creating chronologies of ice shelf retreat into the deglacial history of Antarctica by exploiting the range of thermochemical stability in organic matter (Ramped PyrOx) from these sediment sequences. We describe our success in comparing Ramped PyrOx 14C dates with foraminiferal dates, the relationship between sediment facies and radiocarbon age spectrum, and our ability to push limits of dating sediments deposited underneath ice shelves. With attention to the caveats of recent dating developments, we summarize expectations that geologist should have when coring the Antarctic margins to discern deglacial history. Perhaps most important among these expectations is the ability to design coring expeditions without regard to our ability to date calcium carbonate microfossils within the cores, in essence removing suspense of knowing whether cores taken from crucial paleo ice channels and other bathymetric features will ultimately yield a robust chronology for its sedimentary sequence.

Does Arctic sea ice reduction foster shelf-basin exchange?

Science.gov (United States)

Ivanov, Vladimir; Watanabe, Eiji

2013-12-01

The recent shift in Arctic ice conditions from prevailing multi-year ice to first-year ice will presumably intensify fall-winter sea ice freezing and the associated salt flux to the underlying water column. Here, we conduct a dual modeling study whose results suggest that the predicted catastrophic consequences for the global thermohaline circulation (THC), as a result of the disappearance of Arctic sea ice, may not necessarily occur. In a warmer climate, the substantial fraction of dense water feeding the Greenland-Scotland overflow may form on Arctic shelves and cascade to the deep basin, thus replenishing dense water, which currently forms through open ocean convection in the sub-Arctic seas. We have used a simplified model for estimating how increased ice production influences shelf-basin exchange associated with dense water cascading. We have carried out case studies in two regions of the Arctic Ocean where cascading was observed in the past. The baseline range of buoyancy-forcing derived from the columnar ice formation was calculated as part of a 30-year experiment of the pan-Arctic coupled ice-ocean general circulation model (GCM). The GCM results indicate that mechanical sea ice divergence associated with lateral advection accounts for a significant part of the interannual variations in sea ice thermal production in the coastal polynya regions. This forcing was then rectified by taking into account sub-grid processes and used in a regional model with analytically prescribed bottom topography and vertical stratification in order to examine specific cascading conditions in the Pacific and Atlantic sectors of the Arctic Ocean. Our results demonstrate that the consequences of enhanced ice formation depend on geographical location and shelf-basin bathymetry. In the Pacific sector, strong density stratification in slope waters impedes noticeable deepening of shelf-origin water, even for the strongest forcing applied. In the Atlantic sector, a 1.5x increase of

Preparation and Application of LDPE/ZnO Nanocomposites for Extending Shelf Life of Fresh Strawberries.

Science.gov (United States)

Emamifar, Aryou; Mohammadizadeh, Mehri

2015-12-01

Strawberries have a very short post-harvest life mostly due to their relatively high water content, intense metabolic activity and susceptibility to microbial rot. Antimicrobial low-density polyethylene nanocomposite films containing ZnO nanoparticles at different mass fractions were prepared by melt mixing and followed by compression moulding using a hot press machine. Fresh strawberries were packed in nanocomposite films and stored at 4 °C. Their microbial stability, ascorbic acid content and titratable acidity were evaluated after 0, 4, 8, 12 and 16 days of storage. Microbial growth rate was significantly reduced up to 16 days as a result of the use of nanocomposite packaging material containing ZnO nanoparticles. By increasing the ZnO nanoparticle mass fraction to 5%, the antimicrobial activity of the film increased. All packages containing the ZnO nanoparticles kept the microbial load of fresh strawberries below the level that affects shelf life (5 log CFU/g) up to 16 days. The lowest degradation of ascorbic acid content (6.55 mg per 100 g), and loss of acidity (0.68%) were observed in packages containing 3% of ZnO nanoparticles with 10% polyethylene-grafted maleic anhydride.

Preparation and Application of LDPE/ZnO Nanocomposites for Extending Shelf Life of Fresh Strawberries

Directory of Open Access Journals (Sweden)

Mehri Mohammadizadeh

2015-01-01

Full Text Available Strawberries have a very short post-harvest life mostly due to their relatively high water content, intense metabolic activity and susceptibility to microbial rot. Antimicrobial low-density polyethylene nanocomposite films containing ZnO nanoparticles at different mass fractions were prepared by melt mixing and followed by compression moulding using a hot press machine. Fresh strawberries were packed in nanocomposite films and stored at 4 °C. Their microbial stability, ascorbic acid content and titratable acidity were evaluated after 0, 4, 8, 12 and 16 days of storage. Microbial growth rate was significantly reduced up to 16 days as a result of the use of nanocomposite packaging material containing ZnO nanoparticles. By increasing the ZnO nanoparticle mass fraction to 5 %, the antimicrobial activity of the film increased. All packages containing the ZnO nanoparticles kept the microbial load of fresh strawberries below the level that affects shelf life (5 log CFU/g up to 16 days. The lowest degradation of ascorbic acid content (6.55 mg per 100 g, and loss of acidity (0.68 % were observed in packages containing 3 % of ZnO nanoparticles with 10 % polyethylene-grafted maleic anhydride.

Geometric controls of the flexural gravity waves on the Ross Ice Shelf

Science.gov (United States)

Sergienko, O. V.

2017-12-01

Long-period ocean waves, formed locally or at distant sources, can reach sub-ice-shelf cavities and excite coupled motion in the cavity and the ice shelf - flexural gravity waves. Three-dimensional numerical simulations of the flexural gravity waves on the Ross Ice Shelf show that propagation of these waves is strongly controlled by the geometry of the system - the cavity shape, its water-column thickness and the ice-shelf thickness. The results of numerical simulations demonstrate that propagation of the waves is spatially organized in beams, whose orientation is determined by the direction of the of the open ocean waves incident on the ice-shelf front. As a result, depending on the beams orientation, parts of the Ross Ice Shelf experience significantly larger flexural stresses compared to other parts where the flexural gravity beams do not propagate. Very long-period waves can propagate farther away from the ice-shelf front exciting flexural stresses in the vicinity of the grounding line.

Connections between the growth of Arctica islandica and phytoplankton dynamics on the Faroe Shelf

Science.gov (United States)

Bonitz, Fabian; Andersson, Carin; Trofimova, Tamara

2017-04-01

In this study we use molluscan sclerochronological techniques in order to obtain closer insights into environmental and ecological dynamics of Faroe Shelf waters. The Faroe Shelf represents a special ecosystem with rich benthic and neritic communities, which also have great importance for many economically relevant fish stocks. Thus, a better understanding of seasonal and year-to-year phytoplankton and stratification dynamics would be useful because they also have implications for higher trophic levels. The water masses of the Faroe Shelf are fairly homogenous and isolated from off-shelf waters but at a certain depth, which is referred to as transition zone, seasonal stratification and horizontal exchange occur. Systematic observations and phytoplankton dynamic investigations have only been performed during the last 29 years but longer records are missing. Thus, we use the growth increment variability in long-lived Arctica islandica shells from the transition zone of the eastern Faroe Shelf to evaluate its potential to estimate on-shelf phytoplankton and stratification dynamics since previous studies have shown that the growth of A. islandica is highly dependent on food availability. We have built a shell-based master-chronology reaching back to the 17th century. Comparisons between the growth indices of our chronology and fluorescence data reveal significant positive relationships. In combination with an index that accounts for stratification even stronger correlations are obtained. This indicates that the growth of A. islandica is largely influenced by a combination of how much phytoplankton is produced and how much actually reaches the bottom, i.e. how well-mixed the water column is. Further significant positive correlations can also be found between the growth indices and other primary productivity data from the Faroe Shelf. In conclusion, our results suggest that the growth indices can be related to year-to-year changes in phytoplankton production and

Physical stability, microstructure and micro-rheological properties of water-in-oil-in-water (W/O/W) emulsions stabilized by porcine gelatin.

Science.gov (United States)

Zhu, Qiaomei; Qiu, Shuang; Zhang, Hongwei; Cheng, Yongqiang; Yin, Lijun

2018-07-01

Water-in-oil-in-water (W/O/W) emulsions could be utilized for fat-reduced food formulation and delivery of bioactive nutrients. However, due to thermodynamic instability, it is difficult to prepare stable double emulsions. The purpose of this study was to improve the stability of W/O/W double emulsions containing 2.0 M MgCl 2 by adding porcine gelatin in the inner water phase. The impact of gelatin on the physical stability, microstructure and micro-rheological properties of W/O/W emulsions was investigated. It was found that, when the concentration of porcine gelatin exceeded 4.0 wt%, the stability of emulsions was improved, due to increased viscoelasticity of emulsion droplets. When MgCl 2 concentration increased to 2.0 M, the particle size of emulsions increased, due to the osmotic pressure gradient, and the presence of gelatin further increased the droplet size. Confocal microscopy results showed that the presence of gelatin could improve the stability of W/O/W emulsions against coalescence。. Copyright © 2018. Published by Elsevier Ltd.

Dense shelf water cascading in the northwestern Mediterranean during the cold winter 2005: Quantification of the export through the Gulf of Lion and the Catalan margin

NARCIS (Netherlands)

Ulses, C.; Estournel, C.; Puig, P.; Durrieu de Madron, X.; Marsaleix, P.

2008-01-01

Dense shelf water cascading in the northwestern Mediterranean Sea during winter 2005, which was shown to cause large erosion in the canyons and to influence deep benthic ecosystem, was investigated using numerical modeling validated with temperature and current observations. Intense dense water

Acoustic Estimates of Distribution and Biomass of Different Acoustic Scattering Types Between the New England Shelf Break and Slope Waters

KAUST Repository

McLaren, Alexander

2011-11-01

Due to their great ecological significance, mesopelagic fishes are attracting a wider audience on account of the large biomass they represent. Data from the National Marine Fisheries Service (NMFS) provided the opportunity to explore an unknown region of the North-West Atlantic, adjacent to one of the most productive fisheries in the world. Acoustic data collected during the cruise required the identification of acoustically distinct scattering types to make inferences on the migrations, distributions and biomass of mesopelagic scattering layers. Six scattering types were identified by the proposed method in our data and traces their migrations and distributions in the top 200m of the water column. This method was able to detect and trace the movements of three scattering types to 1000m depth, two of which can be further subdivided. This process of identification enabled the development of three physically-derived target-strength models adapted to traceable acoustic scattering types for the analysis of biomass and length distribution to 1000m depth. The abundance and distribution of acoustic targets varied closely in relation to varying physical environments associated with a warm core ring in the New England continental Shelf break region. The continental shelf break produces biomass density estimates that are twice as high as the warm core ring and the surrounding continental slope waters are an order of magnitude lower than either estimate. Biomass associated with distinct layers is assessed and any benefits brought about by upwelling at the edge of the warm core ring are shown not to result in higher abundance of deepwater species. Finally, asymmetric diurnal migrations in shelf break waters contrasts markedly with the symmetry of migrating layers within the warm ring, both in structure and density estimates, supporting a theory of predatorial and nutritional constraints to migrating pelagic species.

The application of the Accelerated Stability Assessment Program (ASAP) to quality by design (QbD) for drug product stability.

Science.gov (United States)

Waterman, Kenneth Craig

2011-09-01

An isoconversion paradigm, where times in different temperature and humidity-controlled stability chambers are set to provide a fixed degradant level, is shown to compensate for the complex, non-single order kinetics of solid drug products. A humidity-corrected Arrhenius equation provides reliable estimates for temperature and relative humidity effects on degradation rates. A statistical protocol is employed to determine best fits for chemical stability data, which in turn allows for accurate estimations of shelf life (with appropriate confidence intervals) at any storage condition including inside packaging (based on the moisture vapor transmission rate of the packaging and moisture sorption isotherms of the internal components). These methodologies provide both faster results and far better predictions of chemical stability limited shelf life (expiry) than previously possible. Precise shelf-life estimations are generally determined using a 2-week, product-specific protocol. Once the model for a product is developed, it can play a critical role in providing the product understanding necessary for a quality by design (QbD) filing for product approval and enable rational control strategies to assure product stability. Moreover, this Accelerated Stability Assessment Program (ASAP) enables the coupling of product attributes (e.g., moisture content, packaging options) to allow for flexibility in how control strategies are implemented to provide a balance of cost, speed, and other factors while maintaining adequate stability.

Evaluation of the organophosphorus hydrolase enzyme activity in creams and investigation of its stability

Directory of Open Access Journals (Sweden)

Mariye Rajaie

2016-06-01

Full Text Available The main purpose of this project is investigation of the organophosphorus hydrolase (OPH enzyme activity in water in oil (w/o and oil in water (o/w creams and investigation of the OPH enzyme stability in formulated creams. OPH enzyme was extracted and purified from strain flavobacterium. The w/o and o/w creams were prepared using different formulations. In order to achieve an emulsion with maximum stability, appropriate percentage of the cream components was selected by studying different formulations and the physical and chemical stability of the produced cream were considered. 5Uenzyme/90gcream enzyme was used for each formulation. To measure the enzyme activity in creams, extraction method was used and enzyme activity was determined based on parathion hydrolysis. The thermal stability of OPH in both types of w/o and o/w creams was studied at 4 and 30  °C for various time periods. The average enzyme activity was about 0.0065 U/gcream and 0.018 U/gcream for w/o and o/w creams respectivly. According to the results, the relative activity at 4 °C was reduced to 50% after 26 and 45 days in w/o and o/w creams, respectivly. The results showed that the OPH enzyme activity in o/w cream was 2.6 times more than that of w/o cream, because of the higher hydrophobicity of o/w cream compared to w/o. The OPH enzyme stability in o/w cream was greater in comparison to w/o cream. The OPH enzyme was active for nearly 2 months on o/w creams at 4 °C .

Enzyme Stability and Activity in Non-Aqueous Reaction Systems: A Mini Review

Directory of Open Access Journals (Sweden)

Shihui Wang

2016-02-01

Full Text Available Enormous interest in biocatalysis in non-aqueous phase has recently been triggered due to the merits of good enantioselectivity, reverse thermodynamic equilibrium, and no water-dependent side reactions. It has been demonstrated that enzyme has high activity and stability in non-aqueous media, and the variation of enzyme activity is attributed to its conformational modifications. This review comprehensively addresses the stability and activity of the intact enzymes in various non-aqueous systems, such as organic solvents, ionic liquids, sub-/super-critical fluids and their combined mixtures. It has been revealed that critical factors such as Log P, functional groups and the molecular structures of the solvents define the microenvironment surrounding the enzyme molecule and affect enzyme tertiary and secondary structure, influencing enzyme catalytic properties. Therefore, it is of high importance for biocatalysis in non-aqueous media to elucidate the links between the microenvironment surrounding enzyme surface and its stability and activity. In fact, a better understanding of the correlation between different non-aqueous environments and enzyme structure, stability and activity can contribute to identifying the most suitable reaction medium for a given biotransformation.

Ocean stratification reduces melt rates at the grounding zone of the Ross Ice Shelf

Science.gov (United States)

Begeman, C. B.; Tulaczyk, S. M.; Marsh, O.; Mikucki, J.; Stanton, T. P.; Hodson, T. O.; Siegfried, M. R.; Powell, R. D.; Christianson, K. A.; King, M. A.

2017-12-01

Ocean-driven melting of ice shelves is often invoked as the primary mechanism for triggering ice loss from Antarctica. However, due to the difficulty in accessing the sub-ice-shelf ocean cavity, the relationship between ice-shelf melt rates and ocean conditions is poorly understood, particularly near the transition from grounded to floating ice, known as the grounding zone. Here we present the first borehole oceanographic observations from the grounding zone of Antarctica's largest ice shelf. Contrary to predictions that tidal currents near grounding zones should mix the water column, driving high ice-shelf melt rates, we find a stratified sub-ice-shelf water column. The vertical salinity gradient dominates stratification over a weakly unstable vertical temperature gradient; thus, stratification takes the form of a double-diffusive staircase. These conditions limit vertical heat fluxes and lead to low melt rates in the ice-shelf grounding zone. While modern grounding zone melt rates may presently be overestimated in models that assume efficient tidal mixing, the high sensitivity of double-diffusive staircases to ocean freshening and warming suggests future melt rates may be underestimated, biasing projections of global sea-level rise.

Conditions Affecting Shelf-Life of Inoculated Legume Seed

Directory of Open Access Journals (Sweden)

Greg Gemell

2012-02-01

Full Text Available Microbial inoculants are becoming more available as sustainable alternatives to fertilizers and other agrichemicals in broad-acre cropping. However, with the exception of legume inoculants little is understood about effective delivery and survival of the inoculum. Legume inoculants are applied to both seed and soil but seed inoculation is the most economical technique. Large quantities of pasture seed in Australia are inoculated by commercial seed coating companies, but the long-term survival of seed-applied inoculum is variable and monitoring of viability requires specialist microbiology skills and facilities. The aim of our research was to define optimum storage conditions for survival of rhizobia on legume seed and evaluate water activity as a means of monitoring shelf-life. The relationship between survival and water activity varied according to seed species, inoculum preparation, coating ingredients, initial water activity and time suggesting that storage conditions would need to be defined for each different combination. Although drying seeds after coating significantly reduced viable numbers of rhizobia, survival of rhizobia on dried commercially coated lucerne seed after 11 weeks was less variable than seeds that had not been dried. The highest numbers were maintained when seeds remained dry with water activities of between 0.47 and 0.38. The quality of inoculated seed could be improved by reducing the death rate of inoculum during preparation and providing optimum storage conditions for long-term survival.

The Deposition and Accumulation of Microplastics in Marine Sediments and Bottom Water from the Irish Continental Shelf.

Science.gov (United States)

Martin, Jake; Lusher, Amy; Thompson, Richard C; Morley, Audrey

2017-09-07

Microplastics are widely dispersed throughout the marine environment. An understanding of the distribution and accumulation of this form of pollution is crucial for gauging environmental risk. Presented here is the first record of plastic contamination, in the 5 mm-250 μm size range, of Irish continental shelf sediments. Sixty-two microplastics were recovered from 10 of 11 stations using box cores. 97% of recovered microplastics were found to reside shallower than 2.5 cm sediment depth, with the area of highest microplastic concentration being the water-sediment interface and top 0.5 cm of sediments (66%). Microplastics were not found deeper than 3.5 ± 0.5 cm. These findings demonstrate that microplastic contamination is ubiquitous within superficial sediments and bottom water along the western Irish continental shelf. Results highlight that cores need to be at least 4-5 cm deep to quantify the standing stock of microplastics within marine sediments. All recovered microplastics were classified as secondary microplastics as they appear to be remnants of larger items; fibres being the principal form of microplastic pollution (85%), followed by broken fragments (15%). The range of polymer types, colours and physical forms recovered suggests a variety of sources. Further research is needed to understand the mechanisms influencing microplastic transport, deposition, resuspension and subsequent interactions with biota.

SmartShelf trademark: Report of activities for fiscal year 1996

International Nuclear Information System (INIS)

Bell, Z.W.; Lawson, R.L.; Long, C.D.

1996-01-01

The SmartShelf trademark system is designated to maintain an up-to-the-minute inventory of containers or other assets. Through the use of Dallas Semiconductor touch memory devices affixed to containers and entrusted to authorized operators, the system can determine which operator added or removed which container and when the transaction occurred. Through the use of a PC-based data base system, reports of the current status of all containers and nodes can be generated in minutes. This report covers activities on the SmartShelf trademark project for the period 1 October 1995 through 30 September 1996. During this year, project team members have advanced the state of the hardware and software from rough prototypes to a working system ready for field trials.The project team has developed an intimate working knowledge of the hardware and software, and has become expert at implementations of Dallas Semiconductor touch memory devices. System hardware includes a desktop PC running LabView and Microsoft Access, and an STD-bus 8086 computer to monitor container storage locations (nodes). The STD-bus computer monitors up to 128 nodes, and responds to operator actions (adding or removing containers) within 10 seconds. The PC uses LabView software to query the STD-bus machine to obtain records of transactions, and to download configuration information. Microsoft Access is used to store the transactions and configuration data in a user-accessible form

A Hydrodynamic and Sediment Transport Model for the Waipaoa Shelf, New Zealand: Sensitivity of Fluxes to Spatially-Varying Erodibility and Model Nesting

Directory of Open Access Journals (Sweden)

Julia M. Moriarty

2014-04-01

Full Text Available Numerical models can complement observations in investigations of marine sediment transport and depositional processes. A coupled hydrodynamic and sediment transport model was implemented for the Waipaoa River continental shelf offshore of the North Island of New Zealand, to complement a 13-month field campaign that collected seabed and hydrodynamic measurements. This paper described the formulations used within the model, and analyzed the sensitivity of sediment flux estimates to model nesting and seabed erodibility. Calculations were based on the Regional Ocean Modeling System—Community Sediment Transport Modeling System (ROMS-CSTMS, a primitive equation model using a finite difference solution to the equations for momentum and water mass conservation, and transport of salinity, temperature, and multiple classes of suspended sediment. The three-dimensional model resolved the complex bathymetry, bottom boundary layer, and river plume that impact sediment dispersal on this shelf, and accounted for processes including fluvial input, winds, waves, tides, and sediment resuspension. Nesting within a larger-scale, lower resolution hydrodynamic model stabilized model behavior during river floods and allowed large-scale shelf currents to impact sediment dispersal. To better represent observations showing that sediment erodibility decreased away from the river mouth, the seabed erosion rate parameter was reduced with water depth. This allowed the model to account for the observed spatial pattern of erodibility, though the model held the critical shear stress for erosion constant. Although the model neglected consolidation and swelling processes, use of a spatially-varying erodibility parameter significantly increased export of fluvial sediment from Poverty Bay to deeper areas of the shelf.

The Columbia River plume as cross-shelf exporter and along-coast barrier

Science.gov (United States)

Banas, N. S.; MacCready, P.; Hickey, B. M.

2009-01-01

An intensive Lagrangian particle-tracking analysis of the July 2004 upwelling period was conducted in a hindcast model of the US Pacific Northwest coast, in order to determine the effect of the Columbia River plume on the fate of upwelled water. The model, implemented using Regional Ocean Modeling System (ROMS), includes variable wind and atmospheric forcing, variable Columbia river flow, realistic boundary conditions from Navy Coastal Ocean Model (NCOM), and 10 tidal constituents. Model skill has been demonstrated in detail elsewhere [MacCready, P., Banas, N.S., Hickey, B.M., Dever, E.P., Liu, Y., 2008. A model study of tide- and wind-induced mixing in the Columbia River estuary and plume. Continental Shelf Research, this issue, doi:10.1016/j.csr.2008.03.015]. Particles were released in the Columbia estuary, along the Washington coastal wall, and along the model's northern boundary at 48°N. Particles were tracked in three dimensions, using both velocities from ROMS and a vertical random displacement representing turbulent mixing. When 25 h of upwelling flow is looped and particles tracked for 12 d, their trajectories highlight a field of transient eddies and recirculations on scales from 5 to 50 km both north and south of the Columbia. Not all of these features are caused by plume dynamics, but the presence of the plume increases the entrainment of inner-shelf water into them. The cumulative effect of the plume's interaction with these transient features is to increase cross-shelf dispersion: 25% more water is transported laterally past the 100 m isobath when river and estuarine effects are included than when they are omitted. This cross-shelf dispersion also disrupts the southward transport of water along the inner shelf that occurs in the model when the Columbia River is omitted. This second effect—increased retention of upwelled water on the Washington shelf—may be partly responsible for the regional-scale alongcoast gradient in chlorophyll biomass

Long-term stability study of Prussian blue - a quality assessment of water content and thallium binding.

Science.gov (United States)

Mohammad, Adil; Faustino, Patrick J; Khan, Mansoor A; Yang, Yongsheng

2014-12-30

The purpose of this study is to assess the long-term stability of Prussian blue (PB) drug product (DP) and active pharmaceutical ingredient (API) under laboratory storage conditions by monitoring the loss in water content and the corresponding change of the in vitro thallium binding capacity that represents product performance. The bound water content and the in vitro thallium binding capacity of PB DPs and APIs were measured in 2003 and 2013, respectively. Water content, a critical quality attribute that directly correlates to the thallium (Tl) binding capacity was measured by thermal gravimetric analysis (TGA). The thallium binding study was conducted by testing PB in buffered solutions over the human gastrointestinal pH range with thallium concentrations ranging from 600 to 1,500 ppm. Samples were incubated at physiological temperature of 37°C in a shaking water bath to mimic gastric flux and intestinal transport. The binding equilibrium was reached at 24h. Following incubation, each sample was filtered and the free thallium was analyzed using a validated inductively coupled plasma spectroscopic method (ICP). The Langmuir isotherm was plotted to calculate maximum binding capacity (MBC). Compared with 2003, the water content of DP-1 decreased by about 14.1% (from 15.6 to 13.4 mol), and the MBC of DP-1 decreased by about 12.5% (from 714 to 625 mg/g) at pH 7.5. When low concentration of thallium (600 ppm) was used at pH 7.5, the Tl binding remained comparable for both API-1 (286 vs 276 mg/g) and DP-1 (286 vs 268 mg/g). Similarly, the Tl binding remained unchanged for both API-1 (237 vs 255 mg/g) and DP-1 (234 vs 236 mg/g) at pH 5.0. However, at pH 1.0 the binding was reduced 32.3% and 25.9% for API-1 and DP-1, respectively. Since the majority of binding takes place in the upper GI tract where pH around 5 can be expected, and therefore, the Tl binding capacity of PB should be comparable for new and aged samples. The findings that Tl binding changes with the water

Plankton community respiration, net ecosystem metabolism, and oxygen dynamics on the Louisiana continental shelf: Implications for hypoxia

Science.gov (United States)

Murrell, Michael C.; Stanley, Roman S.; Lehrter, John C.; Hagy, James D.

2013-01-01

We conducted a multi-year study of the Louisiana continental shelf (LCS) to better understand the linkages between water column metabolism and the formation of hypoxia (dissolved oxygen Continental Shelf Research, 29: 1861-1872) to estimate net water column metabolism. There was consistent evidence of net heterotrophy, particularly in western transects, and in deeper waters (>40 m depth), indicating a net organic carbon deficit on the LCS. We offer a simple scale argument to suggest that riverine and inshore coastal waters may be significant sources of organic carbon to account for this deficit. This study provided unprecedented, continental shelf scale coverage of heterotrophic metabolism, which is useful for constraining models of oxygen, carbon, and nutrient dynamics along the LCS.

Dynamics of tidal and non-tidal currents along the southwest continental shelf of India

Digital Repository Service at National Institute of Oceanography (India)

Aruna, C.; Ravichandran, C.; Srinivas, K.; Rasheed, P.A.A.; Lekshmi, S.

are predominantly mixed, semidiurnal in nature. Motion over any continental shelf is governed by the tide-driven oscillatory flow. In this paper, tidal and non-tidal characteristics of the waters of Southwest continental shelf of India are assessed using...

Soil-Water Characteristic Curves of Red Clay treated by Ionic Soil Stabilizer

Science.gov (United States)

Cui, D.; Xiang, W.

2009-12-01

The relationship of red clay particle with water is an important factor to produce geological disaster and environmental damage. In order to reduce the role of adsorbed water of red clay in WuHan, Ionic Soil Stabilizer (ISS) was used to treat the red clay. Soil Moisture Equipment made in U.S.A was used to measure soil-water characteristic curve of red clay both in natural and stabilized conditions in the suction range of 0-500kPa. The SWCC results were used to interpret the red clay behavior due to stabilizer treatment. In addition, relationship were compared between the basic soil and stabilizer properties such as water content, dry density, liquid limit, plastic limit, moisture absorption rate and stabilizer dosages. The analysis showed that the particle density and specific surface area increase, the dehydration rate slows and the thickness of water film thins after treatment with Ionic Soil Stabilizer. After treatment with the ISS, the geological disasters caused by the adsorbed water of red clay can be effectively inhibited.

Evaluation of pulsed light treatments on inactivation of Salmonella on blueberries and its impact on shelf-life and quality attributes.

Science.gov (United States)

Cao, Xinang; Huang, Runze; Chen, Haiqiang

2017-11-02

Blueberry have a short shelf life when fully ripe and susceptible to contamination of various pathogens. Our study investigated the effect of pulsed light (PL) on inactivation of Salmonella on blueberries and its impact on shelf-life, quality attributes and health-benefit compounds of blueberries. Dry PL (6J/cm 2 ) and water-assisted PL (samples were agitated in water during PL treatment; 9J/cm 2 ) along with two controls, dry control (untreated) and water-assisted control (water washing without PL), were applied to blueberries with subsequent storages at room temperature (3days) or 5°C (7days). For Salmonella inactivation, dry PL treatment achieved 0.9 and 0.6 log reduction of Salmonella for spot and dip inoculation, respectively; while the water-assisted PL treatment reduced Salmonella by 4.4 log and 0.8 log for spot and dip inoculation, respectively. The water-assisted PL treatment resulted in Salmonella populations significantly lower than the dry control after storage regardless of the storage temperature and inoculation method. Neither dry nor water-assisted PL treatments improved the shelf life of blueberries even though direct inactivation of natural yeasts and molds were achieved. Surface lightness was instantly reduced after both dry and water-assisted PL treatments. Compared with the dry control, the two PL treatments did not reduce the firmness of blueberries. Weight loss was increased for the dry PL treated samples, but not for the water-assisted PL treatment for both storage conditions. Delayed anthocyanins accumulation and reduced total antioxidant activity were induced by both PL treatments at the end of storage at room temperature, while slight enhancement in total phenolics content was achieved by water-assisted PL treatment. In conclusion, the water-assisted PL treatment could effectively decontaminate Salmonella on blueberries while showed minimal or no impact on the shelf-life, quality attributes and health-benefit compounds of blueberries. PL

Modeling, Stability Analysis and Active Stabilization of Multiple DC-Microgrids Clusters

DEFF Research Database (Denmark)

Shafiee, Qobad; Dragicevic, Tomislav; Vasquez, Juan Carlos

2014-01-01

), and more especially during interconnection with other MGs, creating dc MG clusters. This paper develops a small signal model for dc MGs from the control point of view, in order to study stability analysis and investigate effects of CPLs and line impedances between the MGs on stability of these systems....... This model can be also used to synthesis and study dynamics of control loops in dc MGs and also dc MG clusters. An active stabilization method is proposed to be implemented as a dc active power filter (APF) inside the MGs in order to not only increase damping of dc MGs at the presence of CPLs but also...... to improve their stability while connecting to the other MGs. Simulation results are provided to evaluate the developed models and demonstrate the effectiveness of proposed active stabilization technique....

The seasonal evolution of shelf water masses around Bouvetøya, a sub-Antarctic island in the mid-Atlantic sector of the Southern Ocean, determined from an instrumented southern elephant seal

Directory of Open Access Journals (Sweden)

Andrew D. Lowther

2016-10-01

Full Text Available Our study makes use of a fortuitous oceanographic data set collected around the remote sub-Antarctic island of Bouvetøya by a conductivity–temperature–depth recorder (CTD integrated with a satellite-relayed data logger deployed on an adult female southern elephant seal (Mirounga leonina to describe the seasonal evolution of the western shelf waters. The instrumented seal remained in waters over the shelf for 259 days, collecting an average of 2.6 (±0.06 CTD profiles per day, providing hydrographic data encompassing the late austral summer and the entire winter. These data document the thermal stratification of the upper water layer due to summer surface heating of the previous year's Antarctic Surface Water, giving way to a cold subsurface layer at about 100 m as the austral winter progressed, with a concomitant increase in salinity of the upper layer. Upper Circumpolar Deep Water was detected at a depth of approximately 200 m along the western shelf of Bouvetøya throughout the year. These oceanographic data represent the only seasonal time series for this region and the second such animal–instrument oceanographic time series in the sub-Antarctic domain of the Southern Ocean.

Preparing for chemical terrorism: a study of the stability of expired pralidoxime (2-PAM).

Science.gov (United States)

Hoffman, Robert S; Mercurio-Zappala, Maria; Bouchard, Nicole; Ravikumar, Padinjarekuttu; Goldfrank, Lewis

2012-03-01

Oximes such as pralidoxime (2-PAM) are essential antidotes for life-threatening organophosphate poisoning. Unfortunately, oximes are expensive, have limited use, and have short shelf lives. As such, maintaining large stockpiles in preparation for terrorist activity is not always possible. We have demonstrated that atropine is stable well beyond its labeled shelf life and that recently expired 2-PAM was clinically efficacious in a series of poisoned patients. Because 2-PAM is often dosed empirically, clinical improvement does not guarantee pharmacological stability. We therefore chose to analyze the chemical stability of expired 2-PAM. Samples of lyophylized 2-PAM were maintained according to the manufacturer's recommendations for 20 years beyond the published shelf life. We studied 2-PAM contained in a MARK I autoinjector that was stored properly for 3 years beyond its expiration date. An Agilent LC/MSD 1100 with diode-array detector and an Agilent Sorbax SB-C-18, 4.6 × 150-mm, 5-μm column were used with the following solvent systems: water with 0.01% trifluoroacetic acid and methanol with 0.01% trifluoroacetic acid. Fresh reagent grade 2-PAM was used as a standard. Results were repeated for consistency. Lyophylized 2-PAM was a white powder that was clear and colorless in solution. Liquid chromatography was identical to the standard and resulted in 2 isolated peaks with identical mass spectra, suggesting that they are stereoisomers. The autoinjector discharged a clear, yellowish solution. In addition to the 2 peaks identified for lyophylized 2-PAM, a small third peak was identified with a mass spectra corresponding to the reported N -methyl pyridinium carboxaldehyde degradation product. When properly stored, lyophylized 2-PAM appears to be chemically stable well beyond its expiration date. Although the relative amount of degradation product found in solubilized (autoinjector) 2-PAM was small, it is unclear whether this may be toxic and therefore is of concern

West Florida shelf circulation and temperature budget for the 1998 fall transition

Science.gov (United States)

He, Ruoying; Weisberg, Robert H.

2003-05-01

Mid-latitude continental shelves undergo a fall transition as the net heat flux changes from warming to cooling. Using in situ data and a numerical model we investigate the circulation on the west Florida shelf (WFS) for the fall transition of 1998. The model is a regional adaptation of the primitive equation, Princeton Ocean Model forced by NCEP reanalysis wind, air pressure, and heat flux fields, plus river inflows. After comparison with observations the model is used to draw inferences on the seasonal and synoptic scale features of the shelf circulation. By running twin experiments, one without and the other with an idealized Loop Current (LC), we explore the relative importance of local versus deep-ocean forcing. We find that local forcing largely controls the inner-shelf circulation, including changes from the Florida Panhandle in the north to regions farther south. The effects of the LC in fall 1998 are to reinforce the mid-shelf currents and to increase the across-shelf transports in the bottom Ekman layer, thereby accentuating the shoreward transport of cold, nutrient rich water of deep-ocean origin. A three-dimensional analysis of the temperature budget reveals that surface heat flux largely controls both the seasonal and synoptic scale temperature variations. Surface cooling leads to convective mixing that rapidly alters temperature gradients. One interesting consequence is that upwelling can result in near-shore warming as warmer offshore waters are advected landward. The temperature balances on the shelf are complex and fully three-dimensional.

Improvement of shelf stability and processing properties of meat products by gamma irradiation

International Nuclear Information System (INIS)

Byun, M.-W.; Lee, J.-W.; Yook, H.-S.; Lee, K.-H.; Kim, H.-Y.

2002-01-01

To evaluate the effects of gamma irradiation on the processing properties of meat products, emulsion-type sausage, beef patties and pork loin ham were manufactured. Most contaminated bacteria were killed by 3 kGy-irradiation to raw ground beef, and sausage can be manufactured with desirable flavor, a reduction of NaCl and phosphate, and extension of shelf life using gamma irradiation on the raw meat. The beef patties were manufactured with the addition of antioxidants (200 ppm), BHA, ascorbyl palmitate, α-tocopherol, or β-carotene, and gamma-irradiation. Retardation of lipid oxidation appeared at the patties with an antioxidant. A dose of 5 kGy was observed to be as effective as the use of 200 ppm NaNO 2 to provide and maintain the desired color of the product during storage. After curing, irradiation, heating and smoking could extensively prolong the shelf life of the hams

Improvement of shelf stability and processing properties of meat products by gamma irradiation

Science.gov (United States)

Byun, Myung-Woo; Lee, Ju-Woon; Yook, Hong-Sun; Lee, Kyong-Haeng; Kim, Hee-Yun

2002-03-01

To evaluate the effects of gamma irradiation on the processing properties of meat products, emulsion-type sausage, beef patties and pork loin ham were manufactured. Most contaminated bacteria were killed by 3 kGy-irradiation to raw ground beef, and sausage can be manufactured with desirable flavor, a reduction of NaCl and phosphate, and extension of shelf life using gamma irradiation on the raw meat. The beef patties were manufactured with the addition of antioxidants (200 ppm), BHA, ascorbyl palmitate, α-tocopherol, or β-carotene, and gamma-irradiation. Retardation of lipid oxidation appeared at the patties with an antioxidant. A dose of 5 kGy was observed to be as effective as the use of 200 ppm NaNO 2 to provide and maintain the desired color of the product during storage. After curing, irradiation, heating and smoking could extensively prolong the shelf life of the hams.

Collisional stabilization efficiencies that control condensation flux rates in supersaturated vapors of n-alcohols and water

International Nuclear Information System (INIS)

Bauer, S.H.; Wilcox, C.F. Jr.

1994-01-01

Using J(S;T) values, magnitudes for a temperature-dependent stabilization factor, the size-dependent activation energy for evaporation from stabilized clusters, and the size-dependent heats of evaporation are derived. This kinetic derivation is carried out using data from supersaturated water and six n-alcohols obtained with the double-piston expansion technique. 30 refs., 5 figs., 1 tab

Oxidative changes in lipids, proteins, and antioxidants in yogurt during the shelf life.

Science.gov (United States)

Citta, Anna; Folda, Alessandra; Scalcon, Valeria; Scutari, Guido; Bindoli, Alberto; Bellamio, Marco; Feller, Emiliano; Rigobello, Maria Pia

2017-11-01

Oxidation processes in milk and yogurt during the shelf life can result in an alteration of protein and lipid constituents. Therefore, the antioxidant properties of yogurt in standard conditions of preservation were evaluated. Total phenols, free radical scavenger activity, degree of lipid peroxidation, and protein oxidation were determined in plain and skim yogurts with or without fruit puree. After production, plain, skim, plain berries, and skim berries yogurts were compared during the shelf life up to 9 weeks. All types of yogurts revealed a basal antioxidant activity that was higher when a fruit puree was present but gradually decreased during the shelf life. However, after 5-8 weeks, antioxidant activity increased again. Both in plain and berries yogurts lipid peroxidation increased until the seventh week of shelf life and after decreased, whereas protein oxidation of all yogurts was similar either in the absence or presence of berries and increased during shelf life. During the shelf life, a different behavior between lipid and protein oxidation takes place and the presence of berries determines a protection only against lipid peroxidation.

Selective and reactive hydration of nitriles to amides in water using silver nanoparticles stabilized by organic ligands

International Nuclear Information System (INIS)

Kawai, Koji; Kawakami, Hayato; Narushima, Takashi; Yonezawa, Tetsu

2015-01-01

Water-dispersible silver nanoparticles stabilized by silver–carbon covalent bonds were prepared. They exhibited high catalytic activities for the selective hydration of nitriles to amides in water. The activation of a nitrile group by the functional groups of the substrates and the hydrophobic layer on the nanoparticles influenced the catalyzed reaction were confirmed. Alkyl nitriles could also be selectively hydrated

Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts

Energy Technology Data Exchange (ETDEWEB)

Kim, Yong-Tae; Lopes, Pietro Papa; Park, Shin-Ae; Lee, A-Yeong; Lim, Jinkyu; Lee, Hyunjoo; Back, Seoin; Jung, Yousung; Danilovic, Nemanja; Stamenkovic, Vojislav; Erlebacher, Jonah; Snyder, Joshua; Markovic, Nenad M.

2017-11-13

The selection of oxide materials for catalyzing the Oxygen Evolution Reaction in acid-based electrolyzers must be guided by the proper balance between activity, stability and conductivity – a challenging mission of great importance for delivering affordable and environmentally friendly hydrogen. Here we report that the highly conductive nanoporous architecture of an iridium oxide shell on a metallic iridium core, formed through the fast dealloying of osmium from an Ir25Os75 alloy, exhibits an exceptional balance between oxygen evolution activity and stability as quantified by the Activity-Stability FactorASF. Based on this metric, the nanoporous Ir/IrO2 morphology of dealloyed Ir25Os75 shows a factor of ~30 improvement ASFrelative to conventional Ir-based oxide materials and a ~8 times improvement over dealloyed Ir25Os75 nanoparticles due to optimized stability and conductivity, respectively. We propose that the Activity-Stability FactorASF is the key “metric” for determining the technological relevance of oxide-based anodic water electrolyzer catalysts.

Carbon mineralization in Laptev and East Siberian sea shelf and slope sediment

Directory of Open Access Journals (Sweden)

V. Brüchert

2018-01-01

Full Text Available The Siberian Arctic Sea shelf and slope is a key region for the degradation of terrestrial organic material transported from the organic-carbon-rich permafrost regions of Siberia. We report on sediment carbon mineralization rates based on O2 microelectrode profiling; intact sediment core incubations; 35S-sulfate tracer experiments; pore-water dissolved inorganic carbon (DIC; δ13CDIC; and iron, manganese, and ammonium concentrations from 20 shelf and slope stations. This data set provides a spatial overview of sediment carbon mineralization rates and pathways over large parts of the outer Laptev and East Siberian Arctic shelf and slope and allows us to assess degradation rates and efficiency of carbon burial in these sediments. Rates of oxygen uptake and iron and manganese reduction were comparable to temperate shelf and slope environments, but bacterial sulfate reduction rates were comparatively low. In the topmost 50 cm of sediment, aerobic carbon mineralization dominated degradation and comprised on average 84 % of the depth-integrated carbon mineralization. Oxygen uptake rates and anaerobic carbon mineralization rates were higher in the eastern East Siberian Sea shelf compared to the Laptev Sea shelf. DIC ∕ NH4+ ratios in pore waters and the stable carbon isotope composition of remineralized DIC indicated that the degraded organic matter on the Siberian shelf and slope was a mixture of marine and terrestrial organic matter. Based on dual end-member calculations, the terrestrial organic carbon contribution varied between 32 and 36 %, with a higher contribution in the Laptev Sea than in the East Siberian Sea. Extrapolation of the measured degradation rates using isotope end-member apportionment over the outer shelf of the Laptev and East Siberian seas suggests that about 16 Tg C yr−1 is respired in the outer shelf seafloor sediment. Of the organic matter buried below the oxygen penetration depth, between 0.6 and 1.3�

Antioxidant activity of hydrated carboxylated nanodiamonds and its influence on water γ-radiolysis

Science.gov (United States)

Santacruz-Gomez, Karla; Sarabia-Sainz, A.; Acosta-Elias, M.; Sarabia-Sainz, M.; Janetanakit, Woraphong; Khosla, Nathan; Melendrez, R.; Pedroza Montero, Martin; Lal, Ratnesh

2018-03-01

Water radiolysis involves chemical decomposition of the water molecule into free radicals after exposure to ionizing radiation. These free radicals have deleterious effects on normal cell physiology. Carboxylated nanodiamonds (cNDs) appear to modulate the deleterious effects of γ-irradiation on the pathophysiology of red blood cells (RBCs). In the present work, the antioxidant activity of hydrated cNDs (h-cNDs) on limiting oxidative damage (the water radiolysis effect) by γ-irradiation was confirmed. Our results show that h-cNDs have remarkable free radical scavenging ability and preserve the enzymatic activity of catalase after γ-irradiation. The underlying mechanism through which nanodiamonds exhibit antioxidant activity appears to depend on their colloidal stability. This property of detonation synthesized nanodiamonds is improved after carboxylation, which in turn influences changes in the hydrogen bond strength in water. The observed stability of h-cNDs in water and their antioxidant activity correlates with their protective effect on RBCs against γ-irradiation.

Uncovering the glacial history of the Irish continental shelf (Invited)

Science.gov (United States)

Dunlop, P.; Benetti, S.; OCofaigh, C.

2013-12-01

In 1999 the Irish Government initiated a €32 million survey of its territorial waters known as the Irish National Seabed Survey (INSS). The INSS is amongst the largest marine mapping programmes ever undertaken anywhere in the world and provides high-resolution multibeam, backscatter and seismic data of the seabed around Ireland. These data have been used to provide the first clear evidence for extensive glaciation of the continental shelf west and northwest of Ireland. Streamlined drumlins on the mid to outer shelf record former offshore-directed ice flow towards the shelf edge and show that the ice sheet was grounded in a zone of confluence where ice flowing onto the shelf from northwest Ireland merged with ice flowing across the Malin Shelf from southwest Scotland. The major glacial features on the shelf are well developed nested arcuate moraine systems that mark the position of the ice sheet margin and confirm that the former British Irish Ice Sheet was grounded as far as the shelf edge around 100 km offshore of west Donegal at the last glacial maximum. Distal to the moraines, on the outermost shelf, prominent zones of iceberg plough marks give way to the Barra/Donegal fan and a well developed system of gullies and canyons which incise the continental slope. Since 2008 several scientific cruises have retrieved cores from the shelf and slope to help build a more detailed understanding of glacial events in this region. This presentation will provide an overview of the glacial history of the Irish shelf and will discuss ongoing research programmes that are building on the initial research findings to produce a better understanding of the nature and timing of ice sheet events in this region.

Biological stability of drinking water: controlling factors, methods and challenges

Directory of Open Access Journals (Sweden)

Emmanuelle ePrest

2016-02-01

Full Text Available Biological stability of drinking water refers to the concept of providing consumers with drinking water of same microbial quality at the tap as produced at the water treatment facility. However, uncontrolled growth of bacteria can occur during distribution in water mains and premise plumbing, and can lead to hygienic (e.g. development of opportunistic pathogens, aesthetic (e.g. deterioration of taste, odour, colour or operational (e.g. fouling or biocorrosion of pipes problems. Drinking water contains diverse microorganisms competing for limited available nutrients for growth. Bacterial growth and interactions are regulated by factors such as (i type and concentration of available organic and inorganic nutrients, (ii type and concentration of residual disinfectant, (iii presence of predators such as protozoa and invertebrates, (iv environmental conditions such as water temperature, and (v spatial location of microorganisms (bulk water, sediment or biofilm. Water treatment and distribution conditions in water mains and premise plumbing affect each of these factors and shape bacterial community characteristics (abundance, composition, viability in distribution systems. Improved understanding of bacterial interactions in distribution systems and of environmental conditions impact is needed for better control of bacterial communities during drinking water production and distribution. This article reviews (i existing knowledge on biological stability controlling factors and (ii how these factors are affected by drinking water production and distribution conditions. In addition, (iii the concept of biological stability is discussed in light of experience with well-established and new analytical methods, enabling high throughput analysis and in-depth characterization of bacterial communities in drinking water. We discuss how knowledge gained from novel techniques will improve design and monitoring of water treatment and distribution systems in order to

Biological Stability of Drinking Water: Controlling Factors, Methods, and Challenges

Science.gov (United States)

Prest, Emmanuelle I.; Hammes, Frederik; van Loosdrecht, Mark C. M.; Vrouwenvelder, Johannes S.

2016-01-01

Biological stability of drinking water refers to the concept of providing consumers with drinking water of same microbial quality at the tap as produced at the water treatment facility. However, uncontrolled growth of bacteria can occur during distribution in water mains and premise plumbing, and can lead to hygienic (e.g., development of opportunistic pathogens), aesthetic (e.g., deterioration of taste, odor, color) or operational (e.g., fouling or biocorrosion of pipes) problems. Drinking water contains diverse microorganisms competing for limited available nutrients for growth. Bacterial growth and interactions are regulated by factors, such as (i) type and concentration of available organic and inorganic nutrients, (ii) type and concentration of residual disinfectant, (iii) presence of predators, such as protozoa and invertebrates, (iv) environmental conditions, such as water temperature, and (v) spatial location of microorganisms (bulk water, sediment, or biofilm). Water treatment and distribution conditions in water mains and premise plumbing affect each of these factors and shape bacterial community characteristics (abundance, composition, viability) in distribution systems. Improved understanding of bacterial interactions in distribution systems and of environmental conditions impact is needed for better control of bacterial communities during drinking water production and distribution. This article reviews (i) existing knowledge on biological stability controlling factors and (ii) how these factors are affected by drinking water production and distribution conditions. In addition, (iii) the concept of biological stability is discussed in light of experience with well-established and new analytical methods, enabling high throughput analysis and in-depth characterization of bacterial communities in drinking water. We discussed, how knowledge gained from novel techniques will improve design and monitoring of water treatment and distribution systems in order

Biological Stability of Drinking Water: Controlling Factors, Methods, and Challenges

KAUST Repository

Prest, Emmanuelle I.

2016-02-01

Biological stability of drinking water refers to the concept of providing consumers with drinking water of same microbial quality at the tap as produced at the water treatment facility. However, uncontrolled growth of bacteria can occur during distribution in water mains and premise plumbing, and can lead to hygienic (e.g., development of opportunistic pathogens), aesthetic (e.g., deterioration of taste, odor, color) or operational (e.g., fouling or biocorrosion of pipes) problems. Drinking water contains diverse microorganisms competing for limited available nutrients for growth. Bacterial growth and interactions are regulated by factors, such as (i) type and concentration of available organic and inorganic nutrients, (ii) type and concentration of residual disinfectant, (iii) presence of predators, such as protozoa and invertebrates, (iv) environmental conditions, such as water temperature, and (v) spatial location of microorganisms (bulk water, sediment, or biofilm). Water treatment and distribution conditions in water mains and premise plumbing affect each of these factors and shape bacterial community characteristics (abundance, composition, viability) in distribution systems. Improved understanding of bacterial interactions in distribution systems and of environmental conditions impact is needed for better control of bacterial communities during drinking water production and distribution. This article reviews (i) existing knowledge on biological stability controlling factors and (ii) how these factors are affected by drinking water production and distribution conditions. In addition, (iii) the concept of biological stability is discussed in light of experience with well-established and new analytical methods, enabling high throughput analysis and in-depth characterization of bacterial communities in drinking water. We discussed, how knowledge gained from novel techniques will improve design and monitoring of water treatment and distribution systems in order

Shelf life extension of minimally processed ready-to-cook (RTC) cabbage by gamma irradiation

International Nuclear Information System (INIS)

Banerjee, Aparajita; Chatterjee, Suchandra; Variyar, Prasad S.; Sharma, Arun

2016-01-01

Gamma irradiation (0.5-2.5 kGy) in combination with low temperature (4-15 °C) storage was attempted to increase shelf life of ready-to-cook shredded cabbage wrapped in cling films. A maximum extension in shelf life of 8 days, while retaining the microbial and sensory quality, was obtained with an irradiation dose of 2 kGy and storage at 10 °C. Gamma irradiation also inhibited browning of shredded cabbage at their cut edges resulting in enhanced visual appeal. An increase in total antioxidant activity was observed with respect to DPPH and hydroxyl radical scavenging ability while the nitric oxide radical scavenging activity and ferric reducing property remained unaffected with irradiation. Total phenolic, flavonoid and vitamin C content remained unchanged due to irradiation. No significant migration of additives from cling films into stimulant water was observed up to a radiation dose of 2 kGy thus demonstrating the feasibility of such films for above applications. (author)

Shelf life extension of minimally processed ready-to-cook (RTC) cabbage by gamma irradiation.

Science.gov (United States)

Banerjee, Aparajita; Chatterjee, Suchandra; Variyar, Prasad S; Sharma, Arun

2016-01-01

Gamma irradiation (0.5-2.5 kGy) in combination with low temperature (4-15 °C) storage was attempted to increase shelf life of ready-to-cook shredded cabbage wrapped in cling films. A maximum extension in shelf life of 8 days, while retaining the microbial and sensory quality, was obtained with an irradiation dose of 2 kGy and storage at 10 °C. Gamma irradiation also inhibited browning of shredded cabbage at their cut edges resulting in enhanced visual appeal. An increase in total antioxidant activity was observed with respect to DPPH and hydroxyl radical scavenging ability while the nitric oxide radical scavenging activity and ferric reducing property remained unaffected with irradiation. Total phenolic, flavonoid and vitamin C content remained unchanged due to irradiation. No significant migration of additives from cling films into stimulant water was observed up to a radiation dose of 2 kGy thus demonstrating the feasibility of such films for above applications.

Stability monitoring of a natural-circulation-cooled boiling water reactor

International Nuclear Information System (INIS)

Hagen, T.H.J.J. van der.

1989-01-01

Methods for monitoring the stability of a boiling water reactor (BWR) are discussed. Surveillance of BWR stability is of importance as problems were encountered in several large reactors. Moreover, surveying stability allows plant owners to operate at high power with acceptable stability margins. The results of experiments performed on the Dodewaard BWR (the Netherlands) are reported. This type reactor is cooled by natural circulation, a cooling principle that is also being considered for new reactor designs. The stability of this reactor was studied both with deterministic methods and by noise analysis. Three types of stability are distinguished and were investigated separately: reactor-kinetic stability, thermal-hydraulic stability and total-plant stability. It is shown that the Dodewaard reactor has very large stability margins. A simple yet reliable stability criterion is introduced. It can be derived on-line from thhe noise signal of ex-vessel neutron detectors during normal operation. The sensitivity of neutron detectors to in-core flux perturbations - reflected in the field-of-view of the detector - was calculated in order to insure proper stability surveillance. A novel technique is presented which enables the determination of variations of the in-core coolant velocity by noise correlation. The velocity measured was interpreted on the basis of experiments performed on the air/water flow in a model of a BWR coolant channel. It appeared from this analysis that the velocity measured was much higher than the volume-averaged water and air velocities and the volumetric flux. The applicability of the above-mentioned technique to monitoring of local channel-flow stability was tested. It was observed that stability effects on the coolant velocity are masked by other effects originating from the local flow pattern. Experimental and theoretical studies show a shorter effective fuel time constant in a BWR than was assumed. (author). 118 refs.; 73 figs.; 21 tabs

Moisture adsorption properties and shelf-life estimation of dried and pulverised edible house cricket Acheta domesticus (L.) and black soldier fly larvae Hermetia illucens (L.).

Science.gov (United States)

Kamau, E; Mutungi, C; Kinyuru, J; Imathiu, S; Tanga, C; Affognon, H; Ekesi, S; Nakimbugwe, D; Fiaboe, K K M

2018-04-01

Edible insects are part of the diets of a significant proportion of rural populations in the tropics especially Africa and Asia, and their use as source of key nutrients for better nutrition is re-emerging. Indigenously, elemental methods are used to process the insects before they are consumed or sold in retail outlets. In recent years, better knowledge of processing, packaging and storage has become necessary because of commercialisation needs. A common processing approach involves drying after a brief heat-treatment step, and then milling into a powdered product which is sold to manufacturers or consumers as ingredient for processing final products. The hydration properties of dried powders of edible house cricket and black soldier fly larvae (BSFL) were studied with the aim of predicting shelf-life stability under typical packaging and storage temperatures experienced in the tropics. Moisture adsorption isotherms were determined gravimetrically at 25, 30 and 35 °C, over 0.11-0.97 water activity (a W ) range, and the data fitted to various models. Sorption isotherms were of type II according to Brunauer classification indicating monolayer-multilayer sorption behaviour. Cricket powder exhibited higher hydration capacity, and a W of this product was less sensitive to temperature variation as compared to BSFL powder. In the two products, water exhibited transitions from bound- to free- state at ~5 g/100 g moisture content. Based on Heiss-Eichner model, a shelf-life of 7 months at 25 °C can be achieved if the cricket and BSFL powders are dried to ca. 5 g/100 g moisture content and packaged in 80 μm thick polyethylene films. At 35 °C the shelf-life of the cricket product is shortened three- to four-fold whereas the BSFL powder is unable to store. Copyright © 2018 Elsevier Ltd. All rights reserved.

Laser frequency stabilization using a transfer interferometer

Science.gov (United States)

Jackson, Shira; Sawaoka, Hiromitsu; Bhatt, Nishant; Potnis, Shreyas; Vutha, Amar C.

2018-03-01

We present a laser frequency stabilization system that uses a transfer interferometer to stabilize slave lasers to a reference laser. Our implementation uses off-the-shelf optical components along with microcontroller-based digital feedback, and offers a simple, flexible, and robust way to stabilize multiple laser frequencies to better than 1 MHz.

Speedup and fracturing of George VI Ice Shelf, Antarctic Peninsula

Directory of Open Access Journals (Sweden)

T. O. Holt

2013-05-01

Full Text Available George VI Ice Shelf (GVIIS is located on the Antarctic Peninsula, a region where several ice shelves have undergone rapid breakup in response to atmospheric and oceanic warming. We use a combination of optical (Landsat, radar (ERS 1/2 SAR and laser altimetry (GLAS datasets to examine the response of GVIIS to environmental change and to offer an assessment on its future stability. The spatial and structural changes of GVIIS (ca. 1973 to ca. 2010 are mapped and surface velocities are calculated at different time periods (InSAR and optical feature tracking from 1989 to 2009 to document changes in the ice shelf's flow regime. Surface elevation changes are recorded between 2003 and 2008 using repeat track ICESat acquisitions. We note an increase in fracture extent and distribution at the south ice front, ice-shelf acceleration towards both the north and south ice fronts and spatially varied negative surface elevation change throughout, with greater variations observed towards the central and southern regions of the ice shelf. We propose that whilst GVIIS is in no imminent danger of collapse, it is vulnerable to ongoing atmospheric and oceanic warming and is more susceptible to breakup along its southern margin in ice preconditioned for further retreat.

Impacts of Suspended Sediment and Estuarine - Shelf Exchange Pathways on Shelf Ecosystem Dynamics in the Northern Gulf of Mexico

Science.gov (United States)

Wiggert, J. D.; Pan, C.; Dinniman, M. S.; Lau, Y.; Fitzpatrick, P. J.; O'Brien, S. J.; Bouchard, C.; Quas, L. M.; Miles, T. N.; Cambazoglu, M. K.; Dykstra, S. L.; Dzwonkowski, B.; Jacobs, G. A.; Church, I.; Hofmann, E. E.

2017-12-01

A circulation model based on the Coupled-Ocean-Atmosphere-Wave-Sediment Transport (COAWST) Modeling System, with coupled biogeochemical and sediment transport modules, has been implemented for Mississippi Sound and the adjacent continental shelf region. The model has 400-m horizontal resolution, 24 vertical layers, and includes wetting/drying capability to resolve shallow inshore regions. The circulation model was spun-up using oceanographic initial and lateral boundary conditions provided by a 1-km resolution regional implementation of the Navy Coastal Ocean Model (NCOM) in the Gulf of Mexico. The biogeochemical module includes multiple size classes of phytoplankton, zooplankton and detritus, a fish larvae compartment, and explicitly tracks dissolved oxygen with benthic cycling interaction. The sediment transport model is implemented based on benthic mapping data that provides bottom sediment type distributions and spatio-temporal validation. A regionally specific atmospheric forcing product that provides improved spatial and temporal resolution, including diurnal sea breeze impacts, has been developed and applied. Model experiments focus on periods when comprehensive ship-based sampling was deployed by the CONCORDE (Consortium for Coastal River-Dominated Ecosystems) research program, which was established to investigate the complex fine-scale biological, chemical and physical interactions in a marine system controlled by pulsed-river plume dynamics. Biophysical interactions and biogeochemical variability associated with estuarine - shelf exchanges between nearshore lagoonal estuarine waters and the continental shelf revealed by the model provide new insight into how seasonal variation of hydrological forcing conditions influence ecological and biogeochemical processes in the highly productive Northern Gulf region. Application of the COAWST-based model system with and without inclusion of the sediment transport module demonstrates how suspended sediment in the

The Statoil/Hydro fusion in a continental shelf perspective

International Nuclear Information System (INIS)

Osmundsen, Petter

2007-01-01

The article analysis the consequences of the Statoil/Hydro merger on the development on the Norwegian continental shelf. Various indicators of results of the market power the merger are presented and the effects of reduced competition on the markets are discussed. The advantages of the merger on the activities on the shelf are analyzed. (tk)

Mean hydrography on the continental shelf from 26 repeat glider deployments along Southeastern Australia

Science.gov (United States)

Schaeffer, Amandine; Roughan, Moninya; Austin, Tim; Everett, Jason D.; Griffin, David; Hollings, Ben; King, Edward; Mantovanelli, Alessandra; Milburn, Stuart; Pasquer, Benedicte; Pattiaratchi, Charitha; Robertson, Robin; Stanley, Dennis; Suthers, Iain; White, Dana

2016-08-01

Since 2008, 26 glider missions have been undertaken along the continental shelf of southeastern Australia. Typically these missions have spanned the continental shelf on the inshore edge of the East Australian Current from 29.5-33.5°S. This comprehensive dataset of over 33,600 CTD profiles from the surface to within 10 m of the bottom in water depths ranging 25-200 m provides new and unprecedented high resolution observations of the properties of the continental shelf waters adjacent to a western boundary current, straddling the region where it separates from the coast. The region is both physically and biologically significant, and is also in a hotspot of ocean warming. We present gridded mean fields for temperature, salinity and density, but also dissolved oxygen and chlorophyll-a fluorescence indicative of phytoplankton biomass. This data will be invaluable for understanding shelf stratification, circulation, biophysical and bio-geochemical interactions, as well as for the validation of high-resolution ocean models or serving as teaching material.

Cascading off the West Greenland Shelf: A numerical perspective

Science.gov (United States)

Marson, Juliana M.; Myers, Paul G.; Hu, Xianmin; Petrie, Brian; Azetsu-Scott, Kumiko; Lee, Craig M.

2017-07-01

Cascading of dense water from the shelf to deeper layers of the adjacent ocean basin has been observed in several locations around the world. The West Greenland Shelf (WGS), however, is a region where this process has never been documented. In this study, we use a numerical model with a 1/4° resolution to determine (i) if cascading could happen from the WGS; (ii) where and when it could take place; (iii) the forcings that induce or halt this process; and (iv) the path of the dense plume. Results show cascading happening off the WGS at Davis Strait. Dense waters form there due to brine rejection and slide down the slope during spring. Once the dense plume leaves the shelf, it gradually mixes with waters of similar density and moves northward into Baffin Bay. Our simulation showed events happening between 2003-2006 and during 2014; but no plume was observed in the simulation between 2007 and 2013. We suggest that the reason why cascading was halted in this period is related to: the increased freshwater transport from the Arctic Ocean through Fram Strait; the additional sea ice melting in the region; and the reduced presence of Irminger Water at Davis Strait during fall/early winter. Although observations at Davis Strait show that our simulation usually overestimates the seasonal range of temperature and salinity, they agree with the overall variability captured by the model. This suggests that cascades have the potential to develop on the WGS, albeit less dense than the ones estimated by the simulation.

Reconstructing the trophic history of the Black Sea shelf

Science.gov (United States)

Yunev, Oleg; Velikova, Violeta; Carstensen, Jacob

2017-11-01

In the last 50 years the Black Sea has undergone large changes driven by increasing anthropogenic pressures. We estimated the integrated annual primary production (APP) for different shelf regions during the early eutrophication phase (1963-1976) using chlorophyll a and winter nitrate concentrations as proxy observations of primary production to describe its seasonal variation. For comparison, APP was estimated during the period when eutrophication peaked (1985-1992). In the early eutrophication period APP was estimated at 64-89 g C m-2 yr-1 for most part of the shelf, except the shelf part influenced by the Danube River (the shallow waters off the Romanian and Bulgarian coasts) where APP was ∼126 g C m-2 yr-1. In these two different shelf parts, APP increased to 138-190 and 266-318 g C m-2 yr-1 during the peak eutrophication period. These spatial differences are attributed to the large nutrient inputs from the Danube River. The APP estimates provide new insight into the eutrophication history of the Black Sea shelf, documenting stronger signs of eutrophiction than observed in other enclosed seas such as the Baltic Sea. Since the peak eutrophication period APP is estimated to have decreased by approximately 15-20%.

High stability of benzotriazole and benzodithiophene containing medium band-gap polymer solar cell

DEFF Research Database (Denmark)

Unay, Hande; dos Reis Benatto, Gisele A.; Beliatis, Michail J.

2018-01-01

The improvement of polymer solar cell stability is a challenge for the scientists and has significant implications commercially. In this study, we investigated the stability of a novel P-SBTBDT active material applied in an inverted type solar cell. Detailed stability experiments comprising shelf......-in phase with T50 from 700 to 840 h, with some P-SBTBDT solar cells did not reach T50 in the time span of the test. Degradation tests on the P-SBTBDT solar cells which were carried out under natural solar light indicated that T40 was reached after 840 h. The results of dark, light, damp and dry stability...

The potential for satellite and marginal field developments on the Norwegian continental shelf

International Nuclear Information System (INIS)

Raustein, O.; Abrahamsen, L.E.; Einang, G.

1994-01-01

Norway is faced with decreasing field sizes in hostile waters. On the other hand, approximately 620 billion 1993-NOK have been invested in field installations and transport systems. These installations will have significant available processing and transport capacity in the future, and thus represent a valuable infrastructure. This paper describes the resource situation and the installed infrastructure on the Norwegian Continental Shelf. Then the potential of still maintaining a high activity level in field developments is outlined

Geochemistry of sediments of the western Canadian continental shelf

Science.gov (United States)

Macdonald, R. W.; Pedersen, T. F.

1991-08-01

Few chemical data exist for the sedimentary environment off the Canadian west coast. Here we define the chemical nature of the shelf sediments by examining the important sources of material (natural and anthropogenic) to the region and processes relevant to diagenesis. Slightly more data exist for the continental shelf to the south (Washington) and north (Alaska), however it is clear that the sedimentary environment of these neighbouring shelves differs importantly from the Canadian portion. The British Columbia shelf receives little modern terrigenous detritus due mainly to isolation from terrestrial sediment sources by fiords, inland seas, or bypassing by shelf canyons. The chemical state of the sediments depends on the rate of supply of material, the energy of the depositional or erosional environment and the organic and inorganic composition of the material. These features in concert with bottom water characteristics control the redox state. Although no basins hosting continuous depositional records for the Holocene on the open British Columbia shelf have been identified or studied in a manner described by BUCKLEY ( Continental Shelf Research, 11, 1099-1122), some coastal embayments and fiords provide valuable historical records of post-glacial sedimentation. Such environments will prove to be increasingly useful in future studies of changes in regional climate and in establishing the chronology of natural disasters and anthropogenic impacts. Recommendations are given for a variety of research projects that would help us to understand better both chemical interactions at the seabed and Late Quaternary depositional history.

Effect of incorporation of natural chemicals in water ice-glazing on freshness and shelf-life of Pacific saury (Cololabis saira) during -18 °C frozen storage.

Science.gov (United States)

Luo, Haibo; Wang, Weihua; Chen, Wei; Tang, Haiqing; Jiang, Li; Yu, Zhifang

2017-12-14

Microbial spoilage and lipid oxidation are two major factors causing freshness deterioration of Pacific saury (Cololabis saira) during frozen storage. To provide a remedy, the effects of several natural chemicals incorporated alone or in combination in traditional water ice-glazing on the freshness and shelf-life of Pacific saury during frozen storage at -18 °C were investigated. Pacific sauries were subjected to individual quick freezing followed immediately by dipping into cold tap water (control) or solutions containing nisin, chitosan, phytic acid (single-factor experiment) or their combinations ((L 9 (3 4 ) orthogonal experiment) for 10 s at 1 °C and then packaged in polypropylene bags before frozen storage at -18 °C. The storage duration tested was up to 12 months. All ice-glazing treatments with individual chemicals could significantly (P shelf-life of Pacific saury could be extended up to 12 months at -18 °C. The study indicated that the combination treatment with natural chemicals could be commercially utilized to maintain the freshness and prolong the shelf-life of Pacific saury. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Physical and oxidative stability of fish oil-in-water emulsions stabilized with beta-lactoglobulin and pectin.

Science.gov (United States)

Katsuda, Marly S; McClements, D J; Miglioranza, Lucia H S; Decker, Eric A

2008-07-23

The oxidation of fatty acids can be inhibited by engineering the surface of oil-in-water emulsion droplets to decrease interactions between aqueous phase prooxidants and lipids. The objective of this research was to evaluate whether emulsions stabilized by a multilayer emulsifier systems consisting of beta-lactoglobulin and citrus or sugar beet pectin could produce fish oil-in-water emulsions that had good physical and oxidative stability. Sugar beet pectin was compared to citrus pectin because the sugar beet pectin contains the known antioxidant, ferulic acid. A primary Menhaden oil-in-water emulsion was prepared with beta-lactoglobulin upon which the pectins were electrostatically deposited at pH 3.5. Emulsions prepared with 1% oil, 0.05% beta-lactoglobulin, and 0.06% pectins were physically stable for up to 16 days. As determined by monitoring lipid hydroperoxide and headspace propanal formation, emulsions prepared with the multilayer system of beta-lactoglobulin and citrus pectin were more stable than emulsions stabilized with beta-lactoglobulin alone. Emulsions prepared with the multilayer system of beta-lactoglobulin and sugar beet pectin were less stable than emulsions stabilized with beta-lactoglobulin alone despite the presence of ferulic acid in the sugar beet pectin. The lower oxidative stability of the emulsions with the sugar beet pectin could be due to its higher iron and copper concentrations which would produce oxidative stress that would overcome the antioxidant capacity of ferulic acid. These data suggest that the oxidative stability of oil-in-water emulsions containing omega-3 fatty acids could be improved by the use of multilayer emulsion systems containing pectins with low metal concentrations.

Structure and stability of spiro-cyclic water clusters

Indian Academy of Sciences (India)

Administrator

Abstract. The structure and stability of spiro-cyclic water clusters containing up to 32 water molecules have been ... due to its importance in various real life systems. 1–8. High level ... It is well-known from the crystal structure data- base that the ...

Contribution to atmospheric methane by natural seepages on the Bulgarian continental shelf

Energy Technology Data Exchange (ETDEWEB)

Dimitrov, L. [Bulgarian Academy of Science, Varna (Bulgaria). Inst. of Oceanology

2002-07-01

This paper provides an estimation of the atmospheric methane flux from Bulgarian Black Sea continental shelf. Potential gas source rocks include Holocene gas-charged sediments, Quaternary peats and sapropels, and deep-lying Palaeocene and Neogene clays, Cretaceous coals, and other sediments of late Jurassic to early Cretaceous age. These cover almost the whole continental shelf and slope and, together with irregularly developed seal rocks and widespread active and conducting faults, provide good conditions for upward gas migration. A total of 5 100 line kilometers of shallow seismic (boomer) and echo-sounder records acquired during the Institute of Oceanology's regional surveys, and several detailed side-scan sonar lines, have been reviewed for water column targets. Four hundred and eighty-two targets were assigned as gas seepage plumes. It is estimated that a total of 19,735 individual seeps exists on the open shelf. The number of seeps in coastal waters was estimated to be 6020; this is based on available public-domain data, specific research, and results of a specially made questionnaire which was distributed to a range of 'seamen'. More than 150 measurements of the seabed flux rates were made in the 'Golden sands' and 'Zelenka' seepage areas between 1976 and 1991. Indirect estimations of flux rates from video and photo materials, and a review of published data have also been undertaken. Based on these data, three types of seepages were identified as the most representative of Bulgarian coastal waters. These have flux rates of 0.4, 1.8, and 3.51/min. The contribution to atmospheric methane is calculated by multiplying the flux rates with the number of seepages, and entering corrections for methane concentration and the survival of gas bubbles as they ascend through seawater of the corresponding water depth. The estimation indicates that between 45,100,000 (0.03 Tg) and 210,650,000 m{sup 3} (0. 15 Tg) methane yr{sup -1} come

Power distribution effects on boiling water reactor stability

International Nuclear Information System (INIS)

Damiano, B.; March-Leuba, J.

1989-01-01

The work presented in this paper deals with the effects of spatial power distributions on the stability of boiling water reactors (BWRs). It is shown that a conservative power distribution exists for which the stability is minimal. These results are relevant because they imply that bounding stability calculations are possible and, thus, a worst-possible scenario may be defined for a particular BWR geometry. These bounding calculations may, then, be used to determine the maximum expected limit-cycle peak powers

Accelerated Stability Testing of a Clobetasol Propionate-Loaded Nanoemulsion as per ICH Guidelines.

Science.gov (United States)

Ali, Mohammad Sajid; Alam, Mohammad Sarfaraz; Alam, Nawazish; Anwer, Tarique; Safhi, Mohammed Mohsen A

2013-01-01

The physical and chemical degradation of drugs may result in altered therapeutic efficacy and even toxic effects. Therefore, the objective of this work was to study the stability of clobetasol propionate (CP) in a nanoemulsion. The nanoemulsion formulation containing CP was prepared by the spontaneous emulsification method. For the formulation of the nanoemulsion, Safsol, Tween 20, ethanol, and distilled water were used. The drug was incorporated into an oil phase in 0.05% w/v. The lipophilic nature of the drug led to the O/W nanoemulsion formulation. This was characterized by droplet size, pH, viscosity, conductivity, and refractive index. Stability studies were performed as per ICH guidelines for a period of three months. The shelf life of the nanoemulsion formulation was also determined after performing accelerated stability testing (40°C ± 2°C and 75% ± 5% RH). We also performed an intermediate stability study (30°C ± 2°C/65% RH ± 5% RH). It was found that the droplet size, conductivity, and refractive index were slightly increased, while the viscosity and pH slightly decreased at all storage conditions during the 3-month period. However, the changes in these parameters were not statistically significant (p≥0.05). The degradation (%) of the optimized nanoemulsion of CP was determined and the shelf life was found to be 2.18 years at room temperature. These studies confirmed that the physical and chemical stability of CP were enhanced in the nanoemulsion formulation.

Shallow-water vortex equilibria and their stability

Energy Technology Data Exchange (ETDEWEB)

Plotka, H; Dritschel, D G, E-mail: hanna@mcs.st-andrews.ac.uk, E-mail: dgd@mcs.st-andrews.ac.uk [School of Mathematics and Statistics, University of St Andrews, North Haugh, St. Andrews KY16 9SS (United Kingdom)

2011-12-22

We first describe the equilibrium form and stability of steadily-rotating simply-connected vortex patches in the single-layer quasi-geostrophic model of geophysical fluid dynamics. This model, valid for rotating shallow-water flow in the limit of small Rossby and Froude numbers, has an intrinsic length scale L{sub D} called the 'Rossby deformation length' relating the strength of stratification to that of the background rotation rate. Specifically, L{sub D} = c/f where c={radical}gH is a characteristic gravity-wave speed, g is gravity (or 'reduced' gravity in a two-layer context where one layer is infinitely deep), H is the mean active layer depth, and f is the Coriolis frequency (here constant). We next introduce ageostrophic effects by using the full shallow-water model to generate what we call 'quasi-equilibria'. These equilibria are not strictly steady, but radiate such weak gravity waves that they are steady for all practical purposes. Through an artificial ramping procedure, we ramp up the potential vorticity anomaly of the fluid particles in our quasi-geostrophic equilibria to obtain shallow-water quasi-equilibria at finite Rossby number. We show a few examples of these states in this paper.

Tides, the PIG, and 'warm' water

International Nuclear Information System (INIS)

Robertson, Robin

2010-01-01

The present rapid melting of the Pine Island Glacier (PIG) has been attributed to basal melting driven by the ocean. Specifically, this ocean melting is attributed to currents and tides pumping 'warm' Circumpolar Deep Water (CDW) into the ice shelf cavity. To identify tidal activity in the region, an observational time series of yo-yo CTD (Conductivity, Temperature, and Depth) data collected in the PIG outflow region was analyzed. The water column in front of the PIG consisted of two primary layers, a meltwater layer exiting the ice shelf cavity over a layer of CDW. Semidiurnal tides were present in both layers, with both the strength and direction of the tides differing between the two layers. The upper layer tides were stronger and directed in and out of the cavity, while the lower layer tides were primarily directed along the front of the cavity. Energy was found to be transferred from the semidiurnal tide to other frequencies and to be reflected by the ice shelf front. These mechanisms were most prominent at the interfaces between layers and indicate potential mixing between the layers. In conclusion, tides were found to contribute to the circulation into the ice shelf cavity and also to mixing of the exiting water, which influences pumping of the CDW into the ice shelf cavity and melting of the PIG.

Shelf life determinants and enzyme activities of pearl millet: a comparison of changes in stored flour of hybrids, CMS lines, inbreds and composites.

Science.gov (United States)

Goyal, Preeti; Chugh, L K

2017-09-01

Shelf life of pearl millet flour is very short because of rapid development of rancidity. This investigation was carried out in view of generating breeding material for development of low rancid pearl millet hybrids/varieties. Flour of twenty-one genotypes; seven hybrids, seven CMS lines, five inbreds and two composites stored in covered aluminium boxes at 37 °C for 30 days along with respective fresh flour was analysed for shelf life indicators/determinants. Crude fat content and fat acidity (FA) of fresh flour of the genotypes varied from 3.8 to 7.2% and 11 to 75 mg KOH/100 g d.m., respectively. FA in stored flour ranged between 180 and 330 mg KOH/100 g d.m. After storage, magnitude of decrease in pH of water extract of flour of the genotypes varied from 0.15 to 0.44. Activity of peroxidase (POX) varied from 378 to 588 units in control flour and irrespective of the genotypes decreased upon storage. Increase in FA (difference between FA of fresh and stored flour) rather total build up of FA was positively associated with crude fat content (r = 0.440*) indicated comparatively more prominent role of lipolytic enzymes. Chemical changes taking place in water soluble fraction of flour were independent of fat content as no correlation was discerned between fat content and decrease in pH. Among the hybrids, HHB 197 had lowest crude fat content (4.7%), lowest total build up FA (212 mg KOH/100 g d.m.), slowest increase in FA (191 mg KOH/100 g d.m.), least decrease in pH (0.31) of water soluble fraction flour during storage and lowest activity of POX in fresh flour (377 units/g d.m). Among all the tested CMS lines, inbreds and composites, HBL 11 showed pattern of quantitative changes in FA, pH and POX activity similar to the hybrid HHB 197 and was identified a promising inbred for developing low-rancid pearl millet variety or hybrid.

Thermostable Shelf Life Study

Science.gov (United States)

Perchonok, M. H.; Antonini, D. K.

2008-01-01

The objective of this project is to determine the shelf life end-point of various food items by means of actual measurement or mathematical projection. The primary goal of the Advanced Food Technology Project in these long duration exploratory missions is to provide the crew with a palatable, nutritious and safe food system while minimizing volume, mass, and waste. The Mars missions could be as long as 2.5 years with the potential of the food being positioned prior to the crew arrival. Therefore, it is anticipated that foods that are used during the Mars missions will require a 5 year shelf life. Shelf life criteria are safety, nutrition, and acceptability. Any of these criteria can be the limiting factor in determining the food's shelf life. Due to the heat sterilization process used for the thermostabilized food items, safety will be preserved as long as the integrity of the package is maintained. Nutrition and acceptability will change over time. Since the food can be the sole source of nutrition to the crew, a significant loss in nutrition may determine when the shelf life endpoint has occurred. Shelf life can be defined when the food item is no longer acceptable. Acceptability can be defined in terms of appearance, flavor, texture, or aroma. Results from shelf life studies of the thermostabilized food items suggest that the shelf life of the foods range from 0 months to 8 years, depending on formulation.

Thermostabilized Shelf Life Study

Science.gov (United States)

Perchonok, Michele H.; Catauro, Patricia M.

2009-01-01

The objective of this project is to determine the shelf life end-point of various food items by means of actual measurement or mathematical projection. The primary goal of the Advanced Food Technology Project in these long duration exploratory missions is to provide the crew with a palatable, nutritious and safe food system while minimizing volume, mass, and waste. The Mars missions could be as long as 2.5 years with the potential of the food being positioned prior to the crew arrival. Therefore, it is anticipated that foods that are used during the Mars missions will require a 5 year shelf life. Shelf life criteria are safety, nutrition, and acceptability. Any of these criteria can be the limiting factor in determining the food's shelf life. Due to the heat sterilization process used for the thermostabilized food items, safety will be preserved as long as the integrity of the package is maintained. Nutrition and acceptability will change over time. Since the food can be the sole source of nutrition to the crew, a significant loss in nutrition may determine when the shelf life endpoint has occurred. Shelf life can be defined when the food item is no longer acceptable. Acceptability can be defined in terms of appearance, flavor, texture, or aroma. Results from shelf life studies of the thermostabilized food items suggest that the shelf life of the foods range from 0 months to 8 years, depending on formulation.

Summertime calcium carbonate undersaturation in shelf waters of the western Arctic Ocean – how biological processes exacerbate the impact of ocean acidification

Directory of Open Access Journals (Sweden)

N. R. Bates

2013-08-01

Full Text Available The Arctic Ocean accounts for only 4% of the global ocean area, but it contributes significantly to the global carbon cycle. Recent observations of seawater CO2-carbonate chemistry in shelf waters of the western Arctic Ocean, primarily in the Chukchi Sea, from 2009 to 2011 indicate that bottom waters are seasonally undersaturated with respect to calcium carbonate (CaCO3 minerals, particularly aragonite. Nearly 40% of sampled bottom waters on the shelf have saturation states less than one for aragonite (i.e., Ωaragonite 3-secreting organisms, while 80% of bottom waters present had Ωaragonite values less than 1.5. Our observations indicate seasonal reduction of saturation states (Ω for calcite (Ωcalcite and aragonite (Ωaragonite in the subsurface in the western Arctic by as much as 0.8 and 0.5, respectively. Such data indicate that bottom waters of the western Arctic shelves were already potentially corrosive for biogenic and sedimentary CaCO3 for several months each year. Seasonal changes in Ω are imparted by a variety of factors such as phytoplankton photosynthesis, respiration/remineralization of organic matter and air–sea gas exchange of CO2. Combined, these processes either increase or enhance in surface and subsurface waters, respectively. These seasonal physical and biological processes also act to mitigate or enhance the impact of Anthropocene ocean acidification (OA on Ω in surface and subsurface waters, respectively. Future monitoring of the western Arctic shelves is warranted to assess the present and future impact of ocean acidification and seasonal physico-biogeochemical processes on Ω values and Arctic marine ecosystems.

Stability analysis of supercritical-pressure light water-cooled reactor in constant pressure operation

International Nuclear Information System (INIS)

Suhwan, JI; Shirahama, H.; Koshizuka, S.; Oka, Y.

2001-01-01

The purpose of this study is to evaluate the thermal-hydraulic and the thermal-nuclear coupled stabilities of a supercritical pressure light water-cooled reactor. A stability analysis code at supercritical pressure is developed. Using this code, stabilities of full and partial-power reactor operating at supercritical pressure are investigated by the frequency-domain analysis. Two types of SCRs are analyzed; a supercritical light water reactor (SCLWR) and a supercritical water-cooled fast reactor (SCFR). The same stability criteria as Boiling Water Reactor are applied. The thermal-hydraulic stability of SCLWR and SCFR satisfies the criteria with a reasonable orifice loss coefficient. The decay ratio of the thermal-nuclear coupled stability in SCFR is almost zero because of a small coolant density coefficient of the fast reactor. The evaluated decay ratio of the thermal-nuclear coupled stability is 3,41 ∼ 10 -V at 100% power in SCFR and 0,028 at 100% power in SCLWR. The sensitivity is investigated. It is found that the thermal-hydraulic stability is sensitive to the mass flow rate strongly and the thermal-nuclear coupled stability to the coolant density coefficient. The bottom power peak distribution makes the thermal-nuclear stability worse and the thermal-nuclear stability better. (author)

Sources, extent and history of methane seepage on the continental shelf off northern Norway

Science.gov (United States)

Sauer, Simone; Lepland, Aivo; Chand, Shyam; Schubert, Carsten J.; Eichinger, Florian; Knies, Jochen

2014-05-01

Active natural hydrocarbon gas seepage was recently discovered in the Hola area on the continental shelf off Vesterålen, northern Norway. We conducted acoustic and geochemical investigations to assess the modern and past extent, source and pathways of the gas seepage . Water column echosounder surveys showed bubble plumes up to several tens of metres above the seafloor. Analyses of dissolved methane in the water column indicated slightly elevated concentrations (50 nM) close to the seafloor. To identify fluxes and origin of methane in the sediments we analysed sediment pore water chemistry, the isotopic composition of methane and of dissolved inorganic carbon (d13CCH4, d2HCH4, d13CDIC) in three closely spaced (

Water permeation through the internal water pathway in activated GPCR rhodopsin.

Directory of Open Access Journals (Sweden)

Katsufumi Tomobe

Full Text Available Rhodopsin is a light-driven G-protein-coupled receptor that mediates signal transduction in eyes. Internal water molecules mediate activation of the receptor in a rhodopsin cascade reaction and contribute to conformational stability of the receptor. However, it remains unclear how internal water molecules exchange between the bulk and protein inside, in particular through a putative solvent pore on the cytoplasmic. Using all-atom molecular dynamics simulations, we identified the solvent pore on cytoplasmic side in both the Meta II state and the Opsin. On the other hand, the solvent pore does not exist in the dark-adapted rhodopsin. We revealed two characteristic narrow regions located within the solvent pore in the Meta II state. The narrow regions distinguish bulk and the internal hydration sites, one of which is adjacent to the conserved structural motif "NPxxY". Water molecules in the solvent pore diffuse by pushing or sometimes jumping a preceding water molecule due to the geometry of the solvent pore. These findings revealed a total water flux between the bulk and the protein inside in the Meta II state, and suggested that these pathways provide water molecules to the crucial sites of the activated rhodopsin.

PENGARUH ISOTERM SORPSI AIR TERHADAP STABILITAS BERAS UBI [Effect of Moisture Sorption Isotherm to Stability of “Sweet Potato Rice”

Directory of Open Access Journals (Sweden)

Sri Widowati1*

2010-12-01

Full Text Available “Sweet Potato Rice” stability as a dry food product was determined by water activity (aw and equilibrium moisture content (Me. This relationship is known as moisture sorption isotherm. This research were aimed 1 to study moisture sorption isotherm of “Sweet Potato Rice” from sweet potato flour (Cangkuang variety and native/heat moisture treatment (HMT starch which was stored at the range of aw:0.06 - 0.96 and 28oC; 2 to determine an appropriate model for describing product moisture sorption isotherm and 3 to predict “Sweet Potato Rice” shelf of life. Experimental design used was a random complete design with two factor, namely: 1 sweet potato starch: native and HMT, and 2 packaging material: polyethylene (PE and polypropylene (PP.The result showed that the moisture sorption isotherm profiles were sigmoid. Smith equation was the best model which described moisture sorption isotherm with R2= 0,991-0,993 for adsorption and R2= 0,964-0,971 for desorption. Shelf life test showed that “Sweet Potato Rice” from Cangkuang flour and modified starch had longer shelf life (5.67 months when packed in PP bag and 2.3 months when packed in PE bag; while shelf life artificial sweet potato made from Cangkuang flour and native starch was 4.24 months when packed in PP bag and 1.72 months when packed in PE bag.

Influence of oceanographic features on the spatial and seasonal patterns of mesozooplankton in the southern Patagonian shelf (Argentina, SW Atlantic)

Science.gov (United States)

Sabatini, M. E.; Reta, R.; Lutz, V. A.; Segura, V.; Daponte, C.

2016-05-01

Surveys conducted during spring, summer and late winter in 2005-2006 over the southern Patagonian shelf have allowed the seasonal distribution of mesozooplankton communities in relation to water masses and circulation to be investigated. In this system, most of the shelf is dominated by a distinct low salinity plume that is related to the runoff from the Magellan Strait (MSW), while the outer shelf is highly influenced by the cold and salty Subantarctic water (SAW) of the boundary Malvinas Current. Separating these two, the Subantarctic Shelf water mass (SASW) extends over the middle shelf. Correspondingly, the structure of the MSW and SAW mesozooplankton communities was found to be clearly different, while the former and the SASW assemblages were barely separable. This relatively fresh water mass is actually a variant of Subantarctic water that enters into the region from the south and the shelf-break, and hence its mesozooplankton community was not significantly different from that of the SAW water mass. Dissimilar species abundance, in turn associated with different life histories and population development, was more important than species composition in defining the assemblages. Total mesozooplankton abundance increased about 2.5-fold from the beginning of spring to late summer, and then decreased at least two orders of magnitude in winter. Across all seasons copepods represented > 70-80% of total mesozooplankton over most of the shelf. Copepod species best represented through all seasons, in terms of both relative abundance and occurrence, were Drepanopus forcipatus and Oithona helgolandica. Although seasonal differences in abundance were striking, the spatial distribution of mesozooplankton was largely similar across seasons, with relatively higher concentrations occurring mainly in Grande Bay and surroundings. The well defined spatial patterns of mesozooplankton that appear from our results in conjunction with the southward wide extension of the shelf and

Seismic stratigraphy and late Quaternary shelf history, south-central Monterey Bay, California

Science.gov (United States)

Chin, J.L.; Clifton, H.E.; Mullins, H.T.

1988-01-01

The south-central Monterey Bay shelf is a high-energy, wave-dominated, tectonically active coastal region on the central California continental margin. A prominent feature of this shelf is a sediment lobe off the mouth of the Salinas River that has surface expression. High-resolution seismic-reflection profiles reveal that an angular unconformity (Quaternary?) underlies the entire shelf and separates undeformed strata above it from deformed strata below it. The Salinas River lobe is a convex bulge on the shelf covering an area of approximately 72 km2 in water depths from 10 to 90 m. It reaches a maximum thickness of 35 m about 2.5 km seaward of the river mouth and thins in all directions away from this point. Adjacent shelf areas are characterized by only a thin (2 to 5 m thick) and uniform veneer of sediment. Acoustic stratigraphy of the lobe is complex and is characterized by at least three unconformity-bounded depositional sequences. Acoustically, these sequences are relatively well bedded. Acoustic foresets occur within the intermediate sequence and dip seaward at 0.7?? to 2.0??. Comparison with sedimentary sequences in uplifted onshore Pleistocene marine-terrace deposits of the Monterey Bay area, which were presumably formed in a similar setting under similar processes, suggests that a general interpretation can be formulated for seismic stratigraphic patterns. Depositional sequences are interpreted to represent shallowing-upwards progradational sequences of marine to nonmarine coastal deposits formed during interglacial highstands and/or during early stages of falling sea level. Acoustic foresets within the intermediate sequence are evidence of seaward progradation. Acoustic unconformities that separate depositional sequences are interpreted as having formed largely by shoreface planation and may be the only record of the intervening transgressions. The internal stratigraphy of the Salinas River lobe thus suggests that at least several late Quaternary

Suspended particulate layers and internal waves over the southern Monterey Bay continental shelf: an important control on shelf mud belts?

Science.gov (United States)

Cheriton, Olivia M.; McPhee-Shaw, Erika E.; Shaw, William J.; Stanton, Timothy P.; Bellingham, James G.; Storlazzi, Curt D.

2014-01-01

Physical and optical measurements taken over the mud belt on the southern continental shelf of Monterey Bay, California documented the frequent occurrence of suspended particulate matter features, the majority of which were detached from the seafloor, centered 9–33 m above the bed. In fall 2011, an automated profiling mooring and fixed instrumentation, including a thermistor chain and upward-looking acoustic Doppler current profiler, were deployed at 70 m depth for 5 weeks, and from 12 to 16 October a long-range autonomous underwater vehicle performed across-shelf transects. Individual SPM events were uncorrelated with local bed shear stress caused by surface waves and bottom currents. Nearly half of all observed SPM layers occurred during 1 week of the study, 9–16 October 2011, and were advected past the fixed profiling mooring by the onshore phase of semidiurnal internal tide bottom currents. At the start of the 9–16 October period, we observed intense near-bed vertical velocities capable of lifting particulates into the middle of the water column. This “updraft” event appears to have been associated with nonlinear adjustment of high-amplitude internal tides over the mid and outer shelf. These findings suggest that nonlinear internal tidal motions can erode material over the outer shelf and that, once suspended, this SPM can then be transported shoreward to the middle and shallow sections of the mud belt. This represents a fundamental broadening of our understanding of how shelf mud belts may be built up and sustained.

Geochemistry of Precambrian carbonates - 3-shelf seas and non-marine environments of the Archean

Science.gov (United States)

Veizer, Jan; Clayton, R. N.; Hinton, R. W.; Von Brunn, Victor; Mason, T. R.

1990-01-01

Samples from the Pangola and Ventersdorp Supergroups (Kaapvaal Craton, South Africa) and from the Fortescue and Hamersley Groups (Pilbara Block, Australia) were analyzed, using XRF, AAS, and isotope-analysis techniques to investigate the mineralogical, chemical, and isotopic features of these representatives of contemporary shelf carbonates (Pangola and Hamersley samples) and nonmarine carbonates (the Ventersdorp and Fortescue samples). Results show that, mineralogically, the shelf carbonates are almost exclusively dolostones, while the lacustrine facies are predominantly limestones. Geological, trace-element, and oxygen-isotope results of the shelf carbonates suggest that their original mineralogy may have been aragonite, and that the Pangola dolostones may represent a direct dolomitization product of this precursor. By contrast, the stabilization of the Hamersley carbonates may have involved an additional step of transformation of a metastable precursor into limestone.

Seasonal and interannual cross-shelf transport over the Texas and Louisiana continental shelf

Science.gov (United States)

Thyng, Kristen M.; Hetland, Robert D.

2018-05-01

Numerical drifters are tracked in a hydrodynamic simulation of circulation over the Texas-Louisiana shelf to analyze patterns in cross-shelf transport of materials. While the important forcing mechanisms in the region (wind, river, and deep eddies) and associated flow patterns are known, the resultant material transport is less well understood. The primary metric used in the calculations is the percent of drifters released within a region that cross the 100 m isobath. Results of the analysis indicate that, averaged over the eleven years of the simulation, there are two regions on the shelf - over the Texas shelf during winter, and over the Louisiana shelf in summer - with increased seasonal probability for offshore transport. Among the two other distinct regions, the big bend region in Texas has increased probability for onshore transport, and the Mississippi Delta region has an increase in offshore transport, for both seasons. Some of these regions of offshore transport have marked interannual variability. This interannual variability is correlated to interannual changes in forcing conditions. Winter transport off of the Texas shelf is correlated with winter mean wind direction, with more northerly winds enhancing offshore transport; summer transport off the Louisiana shelf is correlated with Mississippi River discharge.

Morphology and sediment dynamics of the northern Catalan continental shelf, northwestern Mediterranean Sea

Science.gov (United States)

Durán, Ruth; Canals, Miquel; Sanz, José Luis; Lastras, Galderic; Amblas, David; Micallef, Aaron

2014-01-01

The northern Catalan continental shelf, in the northwestern Mediterranean Sea, extends along 200 km from the Cap de Creus submarine canyon to the Llobregat Delta, in the vicinity of the city of Barcelona. In this paper we present the results of a systematic investigation of this area by means of very high-resolution multibeam bathymetry to fully assess its morphological variability. The causative factors and processes determining such variability are subsequently interpreted. The shelf is divided in three segments by two prominent submarine canyons: the northernmost Roses Shelf is separated from the intermediate La Planassa Shelf by the La Fonera Canyon, while the boundary between the La Planassa Shelf and the southernmost Barcelona Shelf is marked by the Blanes Canyon. These two canyons are deeply incised in the continental margin, with their heads located at only 0.8 and 5 km from the shore, respectively. The seafloor character reflects the influence of external controlling factors on the geomorphology and sediment dynamics of the northern continental shelf of Catalonia. These factors are the geological setting, the volume and nature of sediment input, and the type and characteristics of processes leading to sediment redistribution, such as dense shelf water cascading (DSWC) and eastern storms. The interaction of all these factors determines sediment dynamics and allows subdividing the northern Catalan continental shelf into three segments: the erosional-depositional Roses Shelf to the north, the non-depositional La Planassa Shelf in the middle, and the depositional Barcelona Shelf to the south. Erosional features off the Cap de Creus Peninsula and an along-shelf subdued channel in the outer shelf illustrate prevailing sediment dynamics in the Roses segment, which is dominated by erosional processes, local sediment accumulations and the southward bypass of sediment. The rocky character of the seafloor immediately north of the Blanes Canyon head demonstrates that

Radiation stress and mean drift in continental shelf waves

Science.gov (United States)

Weber, Jan Erik H.; Drivdal, Magnus

2012-03-01

The time- and depth-averaged mean drift induced by barotropic continental shelf waves (CSW's) is studied theoretically for idealized shelf topography by calculating the mean volume fluxes to second order in wave amplitude. The waves suffer weak spatial damping due to bottom friction, which leads to radiation stress forcing of the mean fluxes. In terms of the total wave energy density E̅̅ over the shelf region, the radiation stress tensor component S̅11 for CSW's is found to be different from that of shallow water surface waves in a non-rotating ocean. For CSW's, the ratio S̅11/E̅ depends strongly on the wave number. The mean Lagrangian flow forced by the radiation stress can be subdivided into a Stokes drift and a mean Eulerian drift current. The magnitude of latter depends on ratio between the radiation stress and the bottom stress acting on the mean flow. When the effect of bottom friction acts equally strong on the waves and the mean current, calculations for short CSW's show that the Stokes drift and the friction-dependent wave-induced mean Eulerian current varies approximately in anti-phase over the shelf, and that the latter is numerically the largest. For long CSW's they are approximately in phase. In both cases the mean Lagrangian current, which is responsible for the net particle drift, has its largest numerical value at the coast on the shallow part of the shelf. Enhancing the effect of bottom friction on the Eulerian mean flow, results in a general current speed reduction, as well as a change in spatial structure for long waves. Applying realistic physical parameters for the continental shelf west of Norway, calculations yield along-shelf mean drift velocities for short CSW's that may be important for the transport of biological material, neutral tracers, and underwater plumes of dissolved oil from deepwater drilling accidents.

Habitat characteristics of the shelf distribution of the harbour porpoise (Phocoena phocoena in the waters around the Faroe Islands during summer

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Henrik Skov

2003-07-01

Full Text Available Observations from a large number of seabird line-transect surveys conducted in Faroese waters are used to derive some general conclusions regarding the distribution of harbour porpoises (Phocoena phocoena in the region using estimates of encounter rates (no./km-1 in different meso-scale habitats around the Faroes during the breeding season (May-September. Based on a sub-set of the data collected during calm conditions (sea states below Beaufort 3 we analysed the distribution of harbour porpoises in relation to 5 potentially important physical parameters: water depth, distance to shore, slope of the ocean floor, distance to tidal front and Beaufort sea state. These parameters were determined from data collected during the surveys, the literature as well as from the new bathymetry established for the Faroese shelf. In order to link the differently scaled physical parameters with the encounter rates and sea states recorded during the surveys we used a suite of geo-statistical and raster-based GIS techniques based on a uniform grid resolution of 1 km in UTM zone 29 N projection. After removing parameters with insignificant effects a model of main effects was produced with sea state and distance to the tidal front having a significant negative effect on the rate of encountering harbour porpoises during both sets of cruises analysed (August 1997 and other surveys. During both sets of cruises the distance to the tidal front had a larger effect on the distribution of the animals than sea state. The strong relationship between harbour porpoise distribution and the average position of the tidal front around the Faroes strongly suggests that the species concentrates near the quasi-stationary circular shelf front separating mixed from stratified waters around the Faroes. However, the importance of shelf fronts for the distribution of harbour porpoises needs to be studied in detail in order to establish the proportionof the populations associated with these

Assessing the quality of bottom water temperatures from the Finite-Volume Community Ocean Model (FVCOM) in the Northwest Atlantic Shelf region

Science.gov (United States)

Li, Bai; Tanaka, Kisei R.; Chen, Yong; Brady, Damian C.; Thomas, Andrew C.

2017-09-01

The Finite-Volume Community Ocean Model (FVCOM) is an advanced coastal circulation model widely utilized for its ability to simulate spatially and temporally evolving three-dimensional geophysical conditions of complex and dynamic coastal regions. While a body of literature evaluates model skill in surface fields, independent studies validating model skill in bottom fields over large spatial and temporal scales are scarce because these fields cannot be remotely sensed. In this study, an evaluation of FVCOM skill in modeling bottom water temperature was conducted by comparison to hourly in situ observed bottom temperatures recorded by the Environmental Monitors on Lobster Traps (eMOLT), a program that attached thermistors to commercial lobster traps from 2001 to 2013. Over 2 × 106 pairs of FVCOM-eMOLT records were evaluated by a series of statistical measures to quantify accuracy and precision of the modeled data across the Northwest Atlantic Shelf region. The overall comparison between modeled and observed data indicates reliable skill of FVCOM (r2 = 0.72; root mean squared error = 2.28 °C). Seasonally, the average absolute errors show higher model skill in spring, fall and winter than summer. We speculate that this is due to the increased difficulty of modeling high frequency variability in the exact position of the thermocline and frontal zones. The spatial patterns of the residuals suggest that there is improved similarity between modeled and observed data at higher latitudes. We speculate that this is due to increased tidal mixing at higher latitudes in our study area that reduces stratification in winter, allowing improved model accuracy. Modeled bottom water temperatures around Cape Cod, the continental shelf edges, and at one location at the entrance to Penobscot Bay were characterized by relatively high errors. Constraints for future uses of FVCOM bottom water temperature are provided based on the uncertainties in temporal-spatial patterns. This study is

Biological stability of drinking water : Controlling factors, methods, and challenges

NARCIS (Netherlands)

Prest, E.I.E.D.; Hammes, F.; Van Loosdrecht, M.C.M.; Vrouwenvelder, J.S.

2016-01-01

Biological stability of drinking water refers to the concept of providing consumers with drinking water of same microbial quality at the tap as produced at the water treatment facility. However, uncontrolled growth of bacteria can occur during distribution in water mains and premise plumbing, and

Preparation and Application of Water-in-Oil Emulsions Stabilized by Modified Graphene Oxide

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Xiaoma Fei

2016-08-01

Full Text Available A series of alkyl chain modified graphene oxides (AmGO with different alkyl chain length and content was fabricated using a reducing reaction between graphene oxide (GO and alkyl amine. Then AmGO was used as a graphene-based particle emulsifier to stabilize Pickering emulsion. Compared with the emulsion stabilized by GO, which was oil-in-water type, all the emulsions stabilized by AmGO were water-in-oil type. The effects of alkyl chain length and alkyl chain content on the emulsion properties of AmGO were investigated. The emulsions stabilized by AmGO showed good stability within a wide range of pH (from pH = 1 to pH = 13 and salt concentrations (from 0.1 to 1000 mM. In addition, the application of water-in-oil emulsions stabilized by AmGO was investigated. AmGO/polyaniline nanocomposite (AmGO/PANi was prepared through an emulsion approach, and its supercapacitor performance was investigated. This research broadens the application of AmGO as a water-in-oil type emulsion stabilizer and in preparing graphene-based functional materials.

Experiences in stability testing of boiling water reactors

International Nuclear Information System (INIS)

March-Leuba, J.; Otaduy, P.J.

1986-01-01

The purpose of this paper is to summarize experiences with boiling water reactor (BWR) stability testing using noise analysis techniques. These techniques have been studied over an extended period of time, but it has been only recently that they have been well established and generally accepted. This paper contains first a review of the problem of BWR neutronic stability, focusing on its physical causes and its effects on reactor operation. The paper also describes the main techniques used to quantify, from noise measurements, the reactor's stability in terms of a decay ratio. Finally, the main results and experiences obtained from the stability tests performed at the Dresden and the Browns Ferry reactors using noise analysis techniques are summarized

Rate of antioxidant degradation and color variations in dehydrated apples as related to water activity.

Science.gov (United States)

Lavelli, Vera; Vantaggi, Claudia

2009-06-10

Dehydrated apples were studied to evaluate the effects of water activity on the stability of their antioxidants and color. Apples were freeze-dried, ground, then equilibrated, and stored at eight water activity levels, ranging from 0.058 to 0.747, at 40 degrees C. Their contents of hydroxycinnamic acids, dihydrochalcones, catechin, epicatechin, polymeric flavan-3-ols, and hydroxymethylfurfural, their antioxidant activity values, and their Hunter colorimetric parameters were analyzed at different storage times. Antioxidant degradation followed pseudo-first-order kinetics and was accelerated by increasing the water activity. The order of antioxidant stability in the products at water activity levels below 0.316 was catechin, epicatechin, and ascorbic acid acid acid; however, in the products at water activity levels above 0.316, the degradation of all antioxidants was very fast. The hydroxymethylfurfural formation rate increased exponentially during storage, especially at high water activity levels. The antioxidant activity of the dehydrated apples decreased during storage, consistent with antioxidant loss. The variations of the colorimetric parameters, namely, lightness (L*), redness (a*), and yellowness (b*), followed pseudo-zero-order kinetics and were accelerated by increasing water activity. All analytical indices indicated that the dehydrated apples were stable at water activity levels below 0.316, with the degradation rate accelerating upon exposure to higher relative humidities. Above 0.316, a small increase in water activity of the product would sharply increase the degradation rate constants for both antioxidant and color variations.

Shelf-life dating of shelf-stable strawberry juice based on survival analysis of consumer acceptance information.

Science.gov (United States)

Buvé, Carolien; Van Bedts, Tine; Haenen, Annelien; Kebede, Biniam; Braekers, Roel; Hendrickx, Marc; Van Loey, Ann; Grauwet, Tara

2018-07-01

Accurate shelf-life dating of food products is crucial for consumers and industries. Therefore, in this study we applied a science-based approach for shelf-life assessment, including accelerated shelf-life testing (ASLT), acceptability testing and the screening of analytical attributes for fast shelf-life predictions. Shelf-stable strawberry juice was selected as a case study. Ambient storage (20 °C) had no effect on the aroma-based acceptance of strawberry juice. The colour-based acceptability decreased during storage under ambient and accelerated (28-42 °C) conditions. The application of survival analysis showed that the colour-based shelf-life was reached in the early stages of storage (≤11 weeks) and that the shelf-life was shortened at higher temperatures. None of the selected attributes (a * and ΔE * value, anthocyanin and ascorbic acid content) is an ideal analytical marker for shelf-life predictions in the investigated temperature range (20-42 °C). Nevertheless, an overall analytical cut-off value over the whole temperature range can be selected. Colour changes of strawberry juice during storage are shelf-life limiting. Combining ASLT with acceptability testing allowed to gain faster insight into the change in colour-based acceptability and to perform shelf-life predictions relying on scientific data. An analytical marker is a convenient tool for shelf-life predictions in the context of ASLT. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Parameterization of light scattering for solving the inverse problem of determining the concentrations of the principal light scattering and absorbing admixtures in shelf waters

Directory of Open Access Journals (Sweden)

Vadim N. Pelevin

2001-12-01

Full Text Available A method for estimating the water backscattering coefficient was put forward on the basis of experimental data of diffuse attenuation coefficient for downwelling irradiance and irradiance reflectance. Calculations were carried out for open sea waters of different types and the spectral dependencies were found ("anomalous" spectra and explained. On this basis, a new model of light backscattering on particles in the sea is proposed. This model may be useful for modelling remote sensing reflectance spectra in order to solve the inverse problems of estimating the concentration of natural admixtures in shelf waters.

Experimental investigation of the stability of the floating water bridge

Science.gov (United States)

Montazeri Namin, Reza; Azizpour Lindi, Shiva; Amjadi, Ahmad; Jafari, Nima; Irajizad, Peyman

2013-09-01

When a high voltage is applied between two beakers filled with deionized water, a floating bridge of water is formed in between exceeding the length of 2 cm when the beakers are pulled apart. Currently two theories regarding the stability of the floating water bridge exist, one suggesting that the tension caused by electric field in the dielectric medium is holding the bridge and the other suggesting surface tension to be responsible for the vertical equilibrium. We construct experiments in which the electric field and the geometry of the bridge are measured and compared with predictions of theories of the floating water bridge stability. We use a numerical simulation for estimation of the electric field. Our results indicate that the two forces of dielectric and surface tensions hold the bridge against gravity simultaneously and, having the same order of magnitude, neither of the two forces are negligible. In bridges with larger diameters, the effect of dielectric tension is slightly more in the vertical equilibrium than surface tension. Results show that the stability can be explained by macroscopic forces, regardless of the microscopic changes in the water structure.

Effects of self-carbon dioxide-generation material for active packaging on pH, water-holding capacity, meat color, lipid oxidation and microbial growth in beef during cold storage.

Science.gov (United States)

Lee, Seung-Jae; Lee, Seung Yun; Kim, Gap-Don; Kim, Geun-Bae; Jin, Sang Keun; Hur, Sun Jin

2017-08-01

Active packaging refers to the mixing of additive agents into packaging materials with the purpose of maintaining or extending food product quality and shelf life. The aim of this study was to develop an easy and cheap active packaging for beef. Beef loin samples were divided into three packaging groups (C, ziplock bag packaging; T1, vacuum packaging; T2, active packaging) and stored at 4 °C for 21 days. The water-holding capacity was significantly (P packaging using self-CO 2 -generation materials can extend the shelf life similarly to that observed with vacuum packaging, and that the active packaging method can improve the quality characteristics of beef during cold storage. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

Biological stability in drinking water distribution systems : A novel approach for systematic microbial water quality monitoring

NARCIS (Netherlands)

Prest, E.I.E.D.

2015-01-01

Challenges to achieve biological stability in drinking water distribution systems Drinking water is distributed from the treatment facility to consumers through extended man-made piping systems. The World Health Organization drinking water guidelines (2006) stated that “Water entering the

Outlet Glacier-Ice Shelf-Ocean Interactions: Is the Tail Wagging the Dog?

Science.gov (United States)

Parizek, B. R.; Walker, R. T.; Rinehart, S. K.

2009-12-01

While the massive interior regions of the Antarctic and Greenland Ice Sheets are presently ``resting quietly", the lower elevations of many outlet glaciers are experiencing dramatic adjustments due to changes in ice dynamics and/or surface mass balance. Oceanic and/or atmospheric forcing in these marginal regions often leads to mass deficits for entire outlet basins. Therefore, coupling the wagging tail of ice-ocean interactions with the vast ice-sheet reservoirs is imperative for accurate assessments of future sea-level rise. To study ice-ocean dynamic processes, we couple an ocean-plume model that simulates ice-shelf basal melting rates based on temperature and salinity profiles combined with plume dynamics associated with the geometry of the ice-shelf cavity (following Jenkins, 1991 and Holland and Jenkins, 1999) with a two-dimensional, isothermal model of outlet glacier-ice shelf flow (as used in Alley et al., 2007; Walker et al., 2008; Parizek et al., in review). Depending on the assigned temperature and salinity profiles, the ocean model can simulate both water-mass end-members: either cold High Salinity Shelf Water (HSSW) or relatively warm Circumpolar Deep Water (CDW), as well as between-member conditions. Notably, the coupled system exhibits sensitivity to the initial conditions. In particular, melting concentrated near the grounding line has the greatest effect in forcing grounding-line retreat. Retreat is further enhanced by a positive feedback between the ocean and ice, as the focused melt near the grounding line leads to an increase in the local slope of the basal ice, thereby enhancing buoyancy-driven plume flow and subsequent melt rates.

Seasonal distribution of dissolved inorganic carbon and net community production on the Bering Sea shelf

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J. T. Mathis

2010-05-01

Full Text Available In order to assess the current state of net community production (NCP in the southeastern Bering Sea, we measured the spatio-temporal distribution and controls on dissolved inorganic carbon (DIC concentrations in spring and summer of 2008 across six shelf domains defined by differing biogeochemical characteristics. DIC concentrations were tightly coupled to salinity in spring and ranged from ~1900 μmoles kg⁻¹ over the inner shelf to ~2400 μmoles kg⁻¹ in the deeper waters of the Bering Sea. In summer, DIC concentrations were lower due to dilution from sea ice melt, terrestrial inputs, and primary production. Concentrations were found to be as low ~1800 μmoles kg⁻¹ over the inner shelf. We found that DIC concentrations were drawn down 30–150 μmoles kg⁻¹ in the upper 30 m of the water column due to primary production and calcium carbonate formation between the spring and summer occupations. Using the seasonal drawdown of DIC, estimated rates of NCP on the inner, middle, and outer shelf averaged 28 ± 9 mmoles C m⁻² d⁻¹. However, higher rates of NCP (40–47 mmoles C m⁻² d⁻¹ were observed in the "Green Belt" where the greatest confluence of nutrient-rich basin water and iron-rich shelf water occurs. We estimated that in 2008, total NCP across the shelf was on the order of ~96 Tg C yr⁻¹. Due to the paucity of consistent, comparable productivity data, it is impossible at this time to quantify whether the system is becoming more or less productive. However, as changing climate continues to modify the character of the Bering Sea, we have shown that NCP can be an important indicator of how the ecosystem is functioning.

Strategies to Extend Bread and GF Bread Shelf-Life: From Sourdough to Antimicrobial Active Packaging and Nanotechnology

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Valentina Melini

2018-02-01

Full Text Available Bread is a staple food worldwide. It commonly undergoes physico-chemical and microbiological changes which impair its quality and shelf-life. Staling determines organoleptic impairment, whereas microbiological spoilage causes visible mould growth and invisible production of mycotoxins. To tackle this economic and safety issue, the bakery industry has been working to identify treatments which allow bread safety and extended shelf-life. Physical methods and chemical preservatives have long been used. However, new frontiers have been recently explored. Sourdough turned out an ancient but novel technology to preserve standard and gluten-free bread. Promising results have also been obtained by application of alternative bio-preservation techniques, including antifungal peptides and plant extracts. Active packaging, with absorbing and/or releasing compounds effective against bread staling and/or with antimicrobials preventing growth of undesirable microorganisms, showed up an emerging area of food technology which can confer many preservation benefits. Nanotechnologies are also opening up a whole universe of new possibilities for the food industry and the consumers. This work thus aims to provide an overview of opportunities and challenges that traditional and innovative anti-staling and anti-spoilage methods can offer to extend bread shelf-life and to provide a basis for driving further research on nanotechnology applications into the bakery industry.

Ice shelf fracture parameterization in an ice sheet model

Science.gov (United States)

Sun, Sainan; Cornford, Stephen L.; Moore, John C.; Gladstone, Rupert; Zhao, Liyun

2017-11-01

Floating ice shelves exert a stabilizing force onto the inland ice sheet. However, this buttressing effect is diminished by the fracture process, which on large scales effectively softens the ice, accelerating its flow, increasing calving, and potentially leading to ice shelf breakup. We add a continuum damage model (CDM) to the BISICLES ice sheet model, which is intended to model the localized opening of crevasses under stress, the transport of those crevasses through the ice sheet, and the coupling between crevasse depth and the ice flow field and to carry out idealized numerical experiments examining the broad impact on large-scale ice sheet and shelf dynamics. In each case we see a complex pattern of damage evolve over time, with an eventual loss of buttressing approximately equivalent to halving the thickness of the ice shelf. We find that it is possible to achieve a similar ice flow pattern using a simple rule of thumb: introducing an enhancement factor ˜ 10 everywhere in the model domain. However, spatially varying damage (or equivalently, enhancement factor) fields set at the start of prognostic calculations to match velocity observations, as is widely done in ice sheet simulations, ought to evolve in time, or grounding line retreat can be slowed by an order of magnitude.

P-wave velocity models of continental shelf of East Siberian Sea using the Laplace-domain full waveform inversion

Science.gov (United States)

Kang, S. G.; Hong, J. K.; Jin, Y. K.; Jang, U.; Niessen, F.; Baranov, B.

2017-12-01

2016 IBRV ARAON Arctic Cruise Leg-2, Expedition ARA07C was a multidisciplinary undertaking carried out in the East Siberian Sea (ESS) from August 25 to September 10, 2016. The program was conducted as a collaboration between the Korea Polar Research Institute (KOPRI), P.P. Shirshov Institute of Oceanology (IORAS), and Alfred Wegener Institute (AWI). During this expedition, the multi-channel seismic (MCS) data were acquired on the continental shelf and the upper slope of the ESS, totaling 3 lines with 660 line-kilometers. The continental shelf of ESS is one of the widest shelf seas in the world and it is believed to cover the largest area of sub-sea permafrost in the Arctic. According to the present knowledge of the glacial history of the western Arctic Ocean, it is likely that during the LGM with a sea level approximately 120 m below present, the entire shelf area of the ESS was exposed to very cold air temperatures so that thick permafrost should have formed. Indeed, in water depths shallower than 80 m, sub-bottom profiles in the ESS recorded from the shelf edge to a latitude of 74°30' N in 60 m water depth exhibited acoustic facies, suggesting that at least relicts of submarine permafrost are present. In order to identify the existence and/or non-existence of subsea permafrost in our study area, we analyze the MCS data using the Laplace domain full waveform inversion (FWI). In case of the Canadian continental shelf of the Beaufort Sea, subsea permafrost has high seismic velocity values (over 2.6 km/sec) and strong refraction events were found in the MCS shotgathers. However, in the EES our proposed P-wave velocity models derived from FWI have neither found high velocity structures (over 2.6 km/sec) nor indicate strong refraction events by subsea permafrost. Instead, in 300 m depth below sea floor higher P-wave velocity structures (1.8 2.2 km/s) than normal subsea sediment layers were found, which are interpreted as cemented strata by glaciation activities.

Storage Stability and Improvement of Intermediate Moisture Foods, Phase 3

Science.gov (United States)

Labuza, T. P.

1975-01-01

Methods were determined for the improvement of shelf-life stability of intermediate moisture foods (IMF). Microbial challenge studies showed that protection against molds and Staphylococcus aureus could be achieved by a combination of antimicrobial agents, humectants and food acids. Potassium sorbate and propylene glycol gave the best results. It was also confirmed that the maximum in heat resistance shown by vegetative pathogens at intermediate water activities also occurred in a solid food. Glycols and sorbitol both achieve browning inhibition because of their action as a medium for reaction and effect on viscosity of the adsorbed phase. Chemical availability results showed rapid lysine loss before visual discoloration occurred. This is being confirmed with a biological test using Tetrahymena pyriformis W. Accelerated temperature tests show that effectiveness of food antioxidants against rancidity development can be predicted; however, the protection factor changes with temperature. BHA was found to be the best antioxidant for iron catalyzed oxidation.

Combined effects of thermosonication and slightly acidic electrolyzed water on the microbial quality and shelf life extension of fresh-cut kale during refrigeration storage.

Science.gov (United States)

Mansur, Ahmad Rois; Oh, Deog-Hwan

2015-10-01

This study evaluated the efficacy of thermosonication combined with slightly acidic electrolyzed water (SAcEW) on the shelf life extension of fresh-cut kale during storage at 4 and 7 °C. Each kale (10 ± 0.2 g) was inoculated to contain approximately 6 log CFU/g of Listeria monocytogenes. Each inoculated or uninoculated samples was dip treated at 40 °C for 3 min with deionized water, thermosonication (400 W/L), SAcEW (5 mg/L), sodium chlorite (SC; 100 mg/L), sodium hypochlorite (SH; 100 mg/L), and thermosonication combined with SAcEW, SC, and SH (TS + SAcEW, TS + SC, and TS + SH, respectively). Growths of L. monocytogenes and spoilage microorganisms and changes in sensory (overall visual quality, browning, and off-odour) were evaluated. The results show that lag time and specific growth rate of each microorganism were not significantly (P > 0.05) affected by treatment and storage temperature. Exceeding the unacceptable counts of spoilage microorganisms did not always result in adverse effects on sensory attributes. This study suggests that TS + SAcEW was the most effective method to prolong the shelf life of kale with an extension of around 4 and 6 days at 4 and 7 °C, respectively, and seems to be a promising method for the shelf life extension of fresh produce. Copyright © 2015 Elsevier Ltd. All rights reserved.

Evaluation of the stability of linezolid in aqueous solution and commonly used intravenous fluids

Directory of Open Access Journals (Sweden)

Taylor R

2017-07-01

Full Text Available Rachel Taylor, Bruce Sunderland, Giuseppe Luna, Petra Czarniak School of Pharmacy, Faculty of Health Sciences, Curtin University, Bentley, WA, Australia Purpose: The aim was to evaluate the stability of linezolid in commonly used intravenous fluids and in aqueous solution to determine the kinetics of degradation and shelf-life values at alkaline pH values. Methods: Forced degradation studies were performed on linezolid in solution to develop a validated high-performance liquid chromatography analysis. Sodium chloride 0.9%, sodium lactate, and glucose 5% and glucose 10% solution containing 2.0 mg/mL linezolid were stored at 25.0°C (±0.1°C for 34 days. The effect of temperature on the stability of linezolid in 0.1 M sodium hydroxide solution was investigated to determine the activation energy. The degradation rates of linezolid at selected pH values at 70.0°C and the influence of ionic strength were also examined. Activation energy data were applied to determine the shelf-life values at selected pH values, and a pH rate profile was constructed over the pH range of 8.7–11.4. The stability of intravenous linezolid (Zyvox® solution was evaluated by storing at 70.0°C for 72 hours. Results: Linezolid was found to maintain >95.0% of its initial concentration after storage at 25.0°C for 34 days in sodium lactate, 0.9% in sodium chloride, and 5% and 10% in glucose solutions. Linezolid was degraded at alkaline pH values by first-order kinetics. Activation energy data showed that temperature, but not ionic strength, influenced the degradation rate significantly. An activation energy of 58.22 kJ/mol was determined for linezolid in 0.1 M sodium hydroxide solution. Linezolid was least stable at high pH values and at elevated temperatures. It was determined that linezolid has adequate stability for the preparation of intravenous fluids for clinical administration. Conclusion: Linezolid was found to have a shelf life of 34 days at 25°C when added to

Shelf-life evaluation of Kaṃsaharītakī avaleha and its granules: A preliminary study.

Science.gov (United States)

Khemuka, Nidhi; Galib, R; Patgiri, B J; Prajapati, Pradeep Kumar

2015-01-01

Savīryatā-avadhi (shelf life) of different Ayurvedic dosage forms is described in Śārṅgadharasaṃhitā. Though the concepts have a strong background, we seek to re-evaluate the age old concepts by following current norms. An attempt has been made in the present study to evaluate shelf-life of Kaṃsaharītakī avaleha and its granules. Raw materials were procured from Pharmacy, Gujarat Ayurved University, Jamnagar and utilized after proper authentication in pharmacognosy lab. The avaleha and its granules were prepared in the departmental laboratory following classical guidelines and subjected to accelerated stability studies. Both the products were found to be free from microbial contamination. Heavy metals were within the prescribed limit. Changes in physico-chemical profiles at different intervals are insignificant. On extrapolation of the observations, the shelf life of avaleha was found to be18 months and 27 months to the granules. Stability of granules was found to be comparatively higher than the avaleha. This observation may be exclusive to Kaṃsaharītakī avaleha. Studies on other avalehas and their granules need to be carried out to confirm this preliminary observation.

Modeling the nitrogen fluxes in the Black Sea using a 3D coupledhydrodynamical-biogeochemical model: transport versus biogeochemicalprocesses, exchanges across the shelf break and comparison of the shelf anddeep sea ecodynamics

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M. Grégoire

2004-01-01

Full Text Available A 6-compartment biogeochemical model of nitrogen cycling and plankton productivity has been coupled with a 3D general circulation model in an enclosed environment (the Black Sea so as to quantify and compare, on a seasonal and annual scale, the typical internal biogeochemical functioning of the shelf and of the deep sea as well as to estimate the nitrogen and water exchanges at the shelf break. Model results indicate that the annual nitrogen net export to the deep sea roughly corresponds to the annual load of nitrogen discharged by the rivers on the shelf. The model estimated vertically integrated gross annual primary production is 130gCm-2yr-1 for the whole basin, 220gCm-2yr-1 for the shelf and 40gCm-2yr-1 for the central basin. In agreement with sediment trap observations, model results indicate a rapid and efficient recycling of particulate organic matter in the sub-oxic portion of the water column (60-80m of the open sea. More than 95% of the PON produced in the euphotic layer is recycled in the upper 100m of the water column, 87% in the upper 80 m and 67% in the euphotic layer. The model estimates the annual export of POC towards the anoxic layer to 4 1010molyr-1. This POC is definitely lost for the system and represents 2% of the annual primary production of the open sea.

46 CFR 178.340 - Stability standards for pontoon vessels on protected waters.

Science.gov (United States)

2010-10-01

... 46 Shipping 7 2010-10-01 2010-10-01 false Stability standards for pontoon vessels on protected waters. 178.340 Section 178.340 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) SMALL....340 Stability standards for pontoon vessels on protected waters. (a) The portion of the deck...

QUALIY PARAMETERS AND SHELF LIFE OF GAME MEAT DURING FROZEN STORAGE

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M. Spaziani

2011-01-01

Full Text Available This study examined the effect of the duration of frozen storage at –20°C on the game meat quality parameters, namely the pH, colour, thawing and cooking losses. The oxidative stability of game meat was evaluated by the production of thiobarbituric acid reactive substances (TBARS. Frozen storage duration did not extensively influence either the quality properties, or the oxidative stability of game meat. Therefore, it was hypothesized that the higher amount of a- tocopherol in the muscles of game compared to pellet-fed animals could be mainly responsible for the lower lipid oxidation and longer shelf life.

Discovery of Widespread Biogenic Methane Emissions and Authigenic Carbonate Mound-like Structures at the Aquitaine Shelf (Bay of Biscay)

Science.gov (United States)

Dupré, S.; Loubrieu, B.; Scalabrin, C.; Ehrhold, A.; Gautier, E.; Ruffine, L.; Pierre, C.; Battani, A.; Le Bouffant, N.; Berger, L.

2014-12-01

Fishery acoustic surveys conducted in the Bay of Biscay (1998-2012) and dedicated to monitoring and predicting pelagic ecosystem evolution reveal numerous active seeps on the Aquitaine Shelf, east of the shelf break (Dupré et al. 2014). Seafloor and water column acoustic investigation with the use of ship-borne multibeam echosounder in 2013 (Gazcogne1 marine expedition) confirmed the presence of numerous (> 3000) persistent and widespread gas emission sites at water depths ranging from ~140 to 180 m. These fluid emissions are associated at the seafloor with high backscatter subcircular small-scale mounds, on average less than 2 m high and a few meters in diameter. Near-bottom visual observations and samplings were conducted with the ROV (Remotely Operated Vehicle) Victor (Gazcogne2 expedition). The whole mounds cover an area of ~200 km2 of the seabed, and are by-products of gas seepage, i.e. methane-derived authigenic carbonates. The spatial distribution of the seeps and related structures, based on water column acoustic gas flares and high backscatter seabed patches, appears to be relatively broad, with a North-South extension of ~80 km across the Parentis Basin and the Landes High, and a West-East extension along a few kilometers wide on the shelf, up to 8 km. Gas bubbles sampled at in situ conditions are principally composed of biogenic methane, possibly originated from Late Pleistocene deposits. The volume of methane emitted into the water column is abundant i) with an average gas flux varying locally from 0.035 to 0.37 Ln/min and ii) with regard to the time needed for the precipitation of the authigenic carbonates identified both at the seabed and in the upper most sedimentary column. The GAZCOGNE study is co-funded by TOTAL and IFREMER as part of the PAMELA (Passive Margin Exploration Laboratories) scientific project. ReferenceDupré, S., Berger, L., Le Bouffant, N., Scalabrin, C., and Bourillet, J.-F., 2014. Fluid emissions at the Aquitaine Shelf (Bay of

Nano-silver in drinking water and drinking water sources: stability and influences on disinfection by-product formation.

Science.gov (United States)

Tugulea, A-M; Bérubé, D; Giddings, M; Lemieux, F; Hnatiw, J; Priem, J; Avramescu, M-L

2014-10-01

Nano-silver is increasingly used in consumer products from washing machines and refrigerators to devices marketed for the disinfection of drinking water or recreational water. The nano-silver in these products may be released, ending up in surface water bodies which may be used as drinking water sources. Little information is available about the stability of the nano-silver in sources of drinking water, its fate during drinking water disinfection processes, and its interaction with disinfection agents and disinfection by-products (DBPs). This study aims to investigate the stability of nano-silver in drinking water sources and in the finished drinking water when chlorine and chloramines are used for disinfection and to observe changes in the composition of DBPs formed when nano-silver is present in the source water. A dispersion of nano-silver particles (10 nm; PVP-coated) was used to spike untreated Ottawa River water, treated Ottawa River water, organic-free water, and a groundwater at concentrations of 5 mg/L. The diluted dispersions were kept under stirred and non-stirred conditions for up to 9 months and analyzed weekly using UV absorption to assess the stability of the nano-silver particles. In a separate experiment, Ottawa River water containing nano-silver particles (at 0.1 and 1 mg/L concentration, respectively) was disinfected by adding sodium hypochlorite (a chlorinating agent) in sufficient amounts to maintain a free chlorine residual of approximately 0.4 mg/L after 24 h. The disinfected drinking water was then quenched with ascorbic acid and analyzed for 34 neutral DBPs (trihalomethanes, haloacetonitriles, haloacetaldehydes, 1,1 dichloro-2-propanone, 1,1,1 trichloro-2-propanone, chloropicrin, and cyanogen chloride). The results were compared to the profile of DBPs obtained under the same conditions in the absence of nano-silver and in the presence of an equivalent concentration of Ag(+) ions (as AgNO3). The stability of the nano-silver dispersions in

An improved 99mTc-Aprotinin kit formulation: quality control analysis of cold kit shelf life and radiotracer stability

International Nuclear Information System (INIS)

Smyth, D.R.; Tsopelas, C.

2005-01-01

Aprotinin is a small protein that inhibits serine proteases and has been shown to bind to amyloid fibrils of varying chemical composition in-vitro. 99 mTc-aprotinin has demonstrated potential for imaging cardiac and pleuropulmonary AL amyloidosis and other forms of amyloidosis present as deposits in joints, the tongue or intestines and other sites excluding the kidneys and liver. Radiolabelling of aprotinin was previously achieved by addition of 99 mTc-pertech-netate to an alkaline mixture of Trasylol (aprotinin injection) and stannous chloride, followed by a necessary filtration step after 20-30 minutes. We have developed a modified cold kit formulation, utilising pharmaceutical starting materials, that provides a more convenient and efficient radiolabelling procedure where filtration is not required prior to injection. The shelf life of the cold kits was validated after storage in a freezer. The reducing agent used was stannous-pyrophosphate (PYP) and the alkaline buffer was a phosphate-glycine mixture (pH 10.5). Quality control testing of the cold kits was performed after 0, 1, 2, 3 and 6 months storage by assessing the % RCP of 99 mTc-apro-tinin by ITLC-SG. Radiotracer stability was examined in the same way 25, 85 and 265 minutes post reconstitution (pr) via a three strip system employing acetone, saline and ammonia:ethanol:water mixture (1:2:5). A rapid quality control cartridge method was also investigated. Radiolabelling of the cold kits yielded RCP > 95% at 25 mins pr and all other time points, from a formulation that avoided a filtration step. The impurities were quantified as TcO., ( 99 mTc-PYP (< 0.7%) by paper methods. The improved Tc-aprotinin kit formulation has greater convenience and efficiency in the clinical setting

Coupling a thermodynamically active ice shelf to a regional simulation of the Weddell Sea

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V. Meccia

2013-08-01

Full Text Available A thermodynamically interactive ice shelf cavity parameterization is coupled to the Regional Ocean Model System (ROMS and is applied to the Southern Ocean domain with enhanced resolution in the Weddell Sea. This implementation is tested in order to assess its degree of improvement to the hydrography (and circulation of the Weddell Sea. Results show that the inclusion of ice shelf cavities in the model is feasible and somewhat realistic (considering the lack of under-ice observations for validation. Ice shelf–ocean interactions are an important process to be considered in order to obtain realistic hydrographic values under the ice shelf. The model framework presented in this work is a promising tool for analyzing the Southern Ocean's response to future climate change scenarios.

Uranium geochemistry on the Amazon shelf: Chemical phase partitioning and cycling across a salinity gradient

International Nuclear Information System (INIS)

Swarzenski, P.W.; McKee, B.A.; Booth, J.G.

1995-01-01

The size distribution of U was examined in surface waters of the Amazon shelf. Water samples were collected during a low discharge river stage across a broad salinity gradient (0.3-35.4%) and fractionated by planar filtration and tangential-flow ultrafiltration into (1) solution (U s , c , 10,000 MW-0.4 μm), (3) dissolved (U d p >0.4 μm) phases. Concentrations of colloidal U comprise up to 92% of the dissolved U fraction at the river mouth and attain highest values (∼0.45 μg/L) in the productive, biogenic region of the Amazon shelf (salinities above ∼20%). U d and U c distributions are highly nonconservative relative to ideal dilution of river water and seawater, indicating extensive removal at salinities below ∼10%. The distribution of U s also shows some nonconservative behavior, yet removal, if any, is minimal. Saltwater-induced precipitation and aggregation of riverine colloidal material is most likely the dominant mechanism of U removal in the low salinity, terrigenous region of the Amazon shelf. There is evident of a substantial colloidal U input (∼245% of the riverine U c flux) into surface waters above 5%. Such U c enrichment most likely is the result of colloidal U-rich porewater diffusion/advection from the seabed and fluid muds or shelf-wide particle-colloid disaggregation. Removal of solution and dissolved phase U via a colloidal intermediate and U c aggregation in terms of coagulation phase U via a colloidal intermediate and U c aggregation was examined in terms of coagulation theory. The high reactive nature of all U phases on the Amazon shelf suggests that remobilization and fractionation of U may also occur in other river-influenced coastal environments

Stability of fruit bases and chocolate fillings

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Joice Natali Miquelim

2011-03-01

Full Text Available Syrups with high sugar content and dehydrated fruits in its composition can be added to chocolate fillings to reduce the need of artificial flavor and dyes attributing a natural appeal to the product. Fruit bases were produced with lyophilized strawberry, passion fruit, and sliced orange peel. Rheological dynamic oscillatory tests were applied to determine the products stability and tendency of shelf life. Values of G´ G´´ were found for orange flavor during the 90 days of storage. It was observed that shear stress values did not vary significantly suggesting product stability during the studied period. For all fillings, it was found a behavior similar to the fruit base indicating that it has great influence on the filling behavior and its stability. The use of a sugar matrix in fillings provided good shelf life for the fruit base, which could be kept under room temperature conditions for a period as long as one year. The good stability and storage conditions allow the use of fruit base for handmade products as well as for industrialized products.

The Myanmar continental shelf

Digital Repository Service at National Institute of Oceanography (India)

Ramaswamy, V.; Rao, P.S.

reveal a minimum of 18 m thick strata of modern muds (Fig. 2g). At the outer boundary of the Gulf of Myanmar Continental Shelf 8 Martaban (15oN Latitude), brown muds overlie coarse sands indicating that modern deltaic sediments... on the Myeik Bank (Rodolfo, 1969a). Modern sediments on the Ayeyarwady shelf General composition, Texture and Grain-size: The distribution and sediment texture on the Ayeyarwady shelf shows fine-grained sediments comprising silty-clay and clayey...

Hydrography, phytoplankton biomass and photosynthesis in shelf and oceanic waters off southeastern Brazil during autumn (may/june, 1983

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Frederico Pereira Brandini

1988-01-01

Full Text Available Spatial distribution of chlorophyll-a, phytoplankton photosynthesis and nutrients were studied in relation to the hydrographic environment of the southeastern Brazil from May 3 to June 31 of 1983 during an oceanographia cruise conducted by the R/V "Almirante Saldanha" of the Brazilian Navy. Temperature and salinity at 5 meters depth ranged from 21 to 25º C and from 33.00 to 37.11, respectively. The concentration of nutrients varied, nitrate + nitrite-N from 1.0-3.0 µg-at/l, phosphate-P 0.1-0.9 µg-at/l and silicate-Si 5-25 µg-at/l. The chlorophyll-a concentrations along the coast varied from 0.35 to 1.48 mg/m³ with maxima in front of Paranaguá Bay (PR and over the southern shelf of Santa Catarina State. Low concentrations around 0.20 mg/m³ of uniform distribution were observed in shelf and off-shelf areas. Comparatively high concentrations were measured over the shelf break zone in front of Paranaguá Bay indicationg the occurrence of shelf break upwelling of deep nutrient rich waters. The pattern of vertical distribution was stratified and irregular in coastal stations and uniform in shelf and oceanic waters although some subsurface peaks were sometimes detected. The integrated chlorophyll values within the euphotic layer varied between 2.70 and 28.06 mg/m². The surface photo synthetic capacity varied from 0.4 to 7.7 mgC/mgChl.a/hr with higher values obtained in coastal areas.. The vertical distributions were variable in coastal areas and more uniform in mid-shelf stations. Sub-surface maxima of photosynthesis were detected in both nearshore and off-shore stations, and surface inhibition was not observed.Os padrões de distribuição espacial de parâmetros hidrográficos, clorofila-a e fotossíntese do fitoplancton são estudados em relação ao regime oceanográfico da região sueste do Brasil nos meses de maio e junho de 1983. A região oceânica foi totalmente dominada pela Agua Tropical da Corrente do Brasil (AT com caracter

Tidal Modulation of Ice-shelf Flow: a Viscous Model of the Ross Ice Shelf

Science.gov (United States)

Brunt, Kelly M.; MacAyeal, Douglas R.

2014-01-01

Three stations near the calving front of the Ross Ice Shelf, Antarctica, recorded GPS data through a full spring-neap tidal cycle in November 2005. The data revealed a diurnal horizontal motion that varied both along and transverse to the long-term average velocity direction, similar to tidal signals observed in other ice shelves and ice streams. Based on its periodicity, it was hypothesized that the signal represents a flow response of the Ross Ice Shelf to the diurnal tides of the Ross Sea. To assess the influence of the tide on the ice-shelf motion, two hypotheses were developed. The first addressed the direct response of the ice shelf to tidal forcing, such as forces due to sea-surface slopes or forces due to sub-ice-shelf currents. The second involved the indirect response of ice-shelf flow to the tidal signals observed in the ice streams that source the ice shelf. A finite-element model, based on viscous creep flow, was developed to test these hypotheses, but succeeded only in falsifying both hypotheses, i.e. showing that direct tidal effects produce too small a response, and indirect tidal effects produce a response that is not smooth in time. This nullification suggests that a combination of viscous and elastic deformation is required to explain the observations.

Performance on Water Stability of Cement-Foamed Asphalt Cold Recycled Mixture

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Li Junxiao

2018-01-01

Full Text Available Through designing the mixture proportion of foamed asphalt cold in-place recycled mixture combined with the water stability experiment, it shows that the addition of cement can obviously improve foamed asphalt mixture’s water stability and the best cement admixture is between 1% ~ 2%; Using digital imaging microscope and SEM technology, the mechanism of increasing on the intensity of foamed asphalt mixture resulted by adding cement was analyzed. It revealed that the cement hydration products contained in the foamed asphalt mixture hydrolyzed into space mesh structure and wrapped up the aggregate particle, this is the main reason that the cement can enhance the mixture’s intensity as well as the water stability. This research provides reference for cement admixture’s formulation in the designing of foamed asphalt cold in-place recycled mixture.

Cruise report; RV Coastal Surveyor Cruise C1-99; multibeam mapping of the Long Beach, California continental shelf; April 12 through May 19, 1999

Science.gov (United States)

Gardner, James V.; Hughes-Clarke, John E.; Mayer, Larry A.

1999-01-01

The greater Los Angeles area of California is home to more than 10 million people. This large population puts increased pressure on the adjacent offshore continental shelf and margin with activities such as ocean disposal for dredged spoils, explosive disposal, waste-water outfall, and commercial fishing. The increased utilization of the shelf and margin in this area has generated accelerated multi-disciplinary research efforts in all aspects of the environment of the coastal zone. Prior to 1996 there were no highly accurate base maps of the continental shelf and slope upon which the research activities could be located and monitored. In 1996, the United States Geological Survey (USGS) Pacific Seafloor Mapping Project began to address this problem by mapping the Santa Monica shelf and margin (Fig. 1) using a state-of-the-art, high-resolution multibeam sonar system (Gardner, et al., 1996; 1999). Additional seafloor mapping in 1998 provided coverage of the continental margin from south of Newport to the proximal San Pedro Basin northwest of Palos Verdes Peninsula (Gardner, et al., 1998) (Fig. 1). The mapping of the seafloor in the greater Los Angeles continental shelf and margin was completed with a 30-day mapping of the Long Beach shelf in April and May 1999, the subject of this report. The objective of Cruise C-1-99-SC was to completely map the broad continental shelf from the eastern end of the Palos Verdes Peninsula to the narrow shelf south of Newport Beach, from the break in slope at about 120-m isobath to the inner shelf at about the 10-m isobath. Mapping the Long Beach shelf was jointly funded by the U.S. Geological Survey and the County of Orange (CA) Sanitation District and was conducted under a Cooperative Agreement with the Ocean Mapping Group from the University of New Brunswick (OMG/UNB). The OMG/UNB contracted with C&C Technologies, Inc. of Lafayette, LA for use of the RV Coastal Surveyor and the latest evolution of high-resolution multibeam sonars, a

Hydraulic loading, stability and water quality of Nakivubo wetland ...

African Journals Online (AJOL)

Nakivubo wetland, which has performed tertiary water treatment for Kampala city for the past 40 years, is ecologically stressed by agricultural and infrastructural developments. Field studies were carried out to assess the hydraulic loading, pollution profile, stability and water quality of this wetland. The upper and lower ...

Chitosan extends the shelf-life of filleted tilapia ( Oreochromis niloticus) during refrigerated storage

Science.gov (United States)

Cao, Rong; Liu, Qi; Yin, Bangzhong; Wu, Biao

2012-09-01

Shelf-life extension of aquatic products is of significant economical importance. To determine the potential effect of chitosan on the shelf-life of filleted tilapia, this study analyzed the bacterial community diversity in fresh and spoiled tilapia fillets stored at (4 ± 1)°C and examined the antimicrobial activity of chitosan against relevant bacteria isolates. Results showed that Pseudomonas (20%) and Aeromonas (16%) were abundant in fresh tilapia fillets, whereas Pseudomonas (52%), Aeromonas (32%) and Staphylococcus (12%) were dominant in the spoiled samples. Chitosan showed wide-spectrum antibacterial activity against bacteria isolated from tilapia and 5.0 g L-1 chitosan was selected for application in preservation. We further determined the shelf-life of chitosan-treated, filleted tilapia stored at (4 ± 1)°C based on microbiological, biochemical and sensory analyses. Results showed that the shelf-life of chitosan-treated, filleted tilapia was extended to 12 d, whereas that of untreated, control samples was 6 d. These indicate that chitosan, as a natural preservative, has great application potential in the shelf-life extension of tilapia fillets.

Morphologic and seismic evidence of rapid submergence offshore Cide-Sinop in the southern Black Sea shelf

Science.gov (United States)

Ocakoğlu, Neslihan; İşcan, Yeliz; Kılıç, Fatmagül; Özel, Oğuz

2018-06-01

Multi-beam bathymetric and multi-channel seismic reflection data obtained offshore Cide-Sinop have revealed important records on the latest transgression of the Black Sea for the first time. A relatively large shelf plain within the narrow southern continental shelf characterized by a flat seafloor morphology at -100 water depth followed by a steep continental slope leading to -500 m depth. This area is widely covered by submerged morphological features such as dunes, lagoons, possible aeolianites, an eroded anticline and small channels that developed by aeolian and fluvial processes. These morphological features sit upon an erosional surface that truncates the top of all seismic units and constitutes the seafloor over the whole shelf. The recent prograded delta deposits around the shelf break are also truncated by the similar erosional surface. These results indicate that offshore Cide-Sinop was once a terrestrial landscape that was then submerged. The interpreted paleoshoreline varies from -100 to -120 m. This variation can be explained by not only sea level changes but also the active faults observed on the seismic section. The effective protection of morphological features on the seafloor is the evidence of abrupt submergence rather than gradual. In addition, the absence of coastal onlaps suggests that these morphological features should have developed at low sea level before the latest sea level rise in the Black Sea.

Phytoplankton absorption predicts patterns in primary productivity in Australian coastal shelf waters

Science.gov (United States)

Robinson, C. M.; Cherukuru, N.; Hardman-Mountford, N. J.; Everett, J. D.; McLaughlin, M. J.; Davies, K. P.; Van Dongen-Vogels, V.; Ralph, P. J.; Doblin, M. A.

2017-06-01

The phytoplankton absorption coefficient (aPHY) has been suggested as a suitable alternate first order predictor of net primary productivity (NPP). We compiled a dataset of surface bio-optical properties and phytoplankton NPP measurements in coastal waters around Australia to examine the utility of an in-situ absorption model to estimate NPP. The magnitude of surface NPP (0.20-19.3 mmol C m-3 d-1) across sites was largely driven by phytoplankton biomass, with higher rates being attributed to the microplankton (>20 μm) size class. The phytoplankton absorption coefficient aPHY for PAR (photosynthetically active radiation; āPHY)) ranged from 0.003 to 0.073 m-1, influenced by changes in phytoplankton community composition, physiology and environmental conditions. The aPHY coefficient also reflected changes in NPP and the absorption model-derived NPP could explain 73% of the variability in measured surface NPP (n = 41; RMSE = 2.49). The absorption model was applied to two contrasting coastal locations to examine NPP dynamics: a high chlorophyll-high variation (HCHV; Port Hacking National Reference Station) and moderate chlorophyll-low variation (MCLV; Yongala National Reference Station) location in eastern Australia using the GIOP-DC satellite aPHY product. Mean daily NPP rates between 2003 and 2015 were higher at the HCHV site (1.71 ± 0.03 mmol C m-3 d-1) with the annual maximum NPP occurring during the austral winter. In contrast, the MCLV site annual NPP peak occurred during the austral wet season and had lower mean daily NPP (1.43 ± 0.03 mmol C m-3 d-1) across the time-series. An absorption-based model to estimate NPP is a promising approach for exploring the spatio-temporal dynamics in phytoplankton NPP around the Australian continental shelf.

Stability and activity of doped transition metal zeolites in the hydrothermal processing

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Thomas François Robin

2015-12-01

Full Text Available This study investigates the stability and activity of HZSM-5 doped with metals such as molybdenum, nickel, copper and iron in under hydrothermal conditions used for the direct liquefaction of microalgae. Catalysts have been prepared by ion exchange techniques, and MoZSM-5 was also prepared by wet incipient impregnation for comparison. Hydrothermal liquefaction is considered as a potential route to convert microalgae into a sustainable fuel. One of the drawbacks of this process is that the bio-crude produced contains significant levels of nitrogen and oxygen compounds which have an impact on the physical and chemical propriety of the fuel. Heterogeneous catalysts have been shown to improve the quality of the bio-crude by reducing nitrogen and oxygen contents. Zeolites, such as HZSM-5, are strong candidates due to their low cost compared to noble metal catalysts but their stability and activity under hydrothermal conditions is not well understood. The stability of the catalysts has been determined under hydrothermal conditions at 350 °C. Catalysts have been characterised before and after treatment using XRD, BET physisorption and STEM microscopy. Metal leaching was determined by analysis of the water phase following hydrothermal treatment. The inserted cation following ion-exchange can influence the physical properties of HZSM-5 for example molybdenum improves the crystallinity of the zeolite. In general, metal doped zeolites were relatively stable under subcritical water. Activity of the catalysts for processing lipids, protein and microalgae has been assessed. Four feedstocks were selected: sunflower oil, soya proteins, Chlorella and P. ellipsoidea. The catalysts exhibited greater activity towards converting lipids for example MoZSM-5 enhanced the formation of aromatic compounds. NiZSM-5 and CuZSM-5 were observed to be more efficient for deoxygenation.

Stability and Activity of Doped Transition Metal Zeolites in the Hydrothermal Processing

International Nuclear Information System (INIS)

Robin, Thomas François; Ross, Andrew B.; Lea-Langton, Amanda R.; Jones, Jenny M.

2015-01-01

This study investigates the stability and activity of HZSM-5 doped with metals such as molybdenum, nickel, copper, and iron under hydrothermal conditions used for the direct liquefaction of microalgae. Catalysts have been prepared by ion-exchange techniques, and MoZSM-5 was also prepared by wet incipient impregnation for comparison. Hydrothermal liquefaction is considered a potential route to convert microalgae into a sustainable fuel. One of the drawbacks of this process is that the bio-crude produced contains significant levels of nitrogen and oxygen compounds that have an impact on the physical and chemical properties of the fuel. Heterogeneous catalysts have been shown to improve the quality of the bio-crude by reducing nitrogen and oxygen contents. Zeolites, such as HZSM-5, are strong candidates due to their low cost compared to noble metal catalysts, but their stability and activity under hydrothermal conditions are not well understood. The stability of the catalysts has been determined under hydrothermal conditions at 350°C. Catalysts have been characterized before and after treatment using X-ray diffraction, BET physisorption, and scanning transmission electronic microscopy. Metal leaching was determined by the analysis of the water phase following the hydrothermal treatment. The inserted cation following ion-exchange can influence the physical properties of HZSM-5, for example, molybdenum improves the crystallinity of the zeolite. In general, metal-doped zeolites were relatively stable in subcritical water. The activity of the catalysts for processing lipids, protein, and microalgae has been assessed. Four feedstocks were selected: sunflower oil, soya proteins, Chlorella, and Pseudochoricystis ellipsoidea. The catalysts exhibited greater activity toward converting lipids, for example, MoZSM-5 enhanced the formation of aromatic compounds. NiZSM-5 and CuZSM-5 were observed to be more efficient for deoxygenation.

Stability and Activity of Doped Transition Metal Zeolites in the Hydrothermal Processing

Energy Technology Data Exchange (ETDEWEB)

Robin, Thomas François, E-mail: thomas.cognac@gmail.com; Ross, Andrew B.; Lea-Langton, Amanda R.; Jones, Jenny M. [School of Chemical and Process Engineering, University of Leeds, Leeds (United Kingdom)

2015-12-14

This study investigates the stability and activity of HZSM-5 doped with metals such as molybdenum, nickel, copper, and iron under hydrothermal conditions used for the direct liquefaction of microalgae. Catalysts have been prepared by ion-exchange techniques, and MoZSM-5 was also prepared by wet incipient impregnation for comparison. Hydrothermal liquefaction is considered a potential route to convert microalgae into a sustainable fuel. One of the drawbacks of this process is that the bio-crude produced contains significant levels of nitrogen and oxygen compounds that have an impact on the physical and chemical properties of the fuel. Heterogeneous catalysts have been shown to improve the quality of the bio-crude by reducing nitrogen and oxygen contents. Zeolites, such as HZSM-5, are strong candidates due to their low cost compared to noble metal catalysts, but their stability and activity under hydrothermal conditions are not well understood. The stability of the catalysts has been determined under hydrothermal conditions at 350°C. Catalysts have been characterized before and after treatment using X-ray diffraction, BET physisorption, and scanning transmission electronic microscopy. Metal leaching was determined by the analysis of the water phase following the hydrothermal treatment. The inserted cation following ion-exchange can influence the physical properties of HZSM-5, for example, molybdenum improves the crystallinity of the zeolite. In general, metal-doped zeolites were relatively stable in subcritical water. The activity of the catalysts for processing lipids, protein, and microalgae has been assessed. Four feedstocks were selected: sunflower oil, soya proteins, Chlorella, and Pseudochoricystis ellipsoidea. The catalysts exhibited greater activity toward converting lipids, for example, MoZSM-5 enhanced the formation of aromatic compounds. NiZSM-5 and CuZSM-5 were observed to be more efficient for deoxygenation.

Examining the mean vertical attenuation of scalar quantum irradiance (PAR) over the Louisiana-Texas shelf (northern Gulf of Mexico)

Science.gov (United States)

Lugo-Fernández, A.; Gravois, M.; Green, R. E.; Montgomery, T.

2012-04-01

We examined freshwater and ocean circulation effects on the distribution of vertical quantum diffuse attenuation coefficients (Kq0) of photosyntheticaly available radiation (PAR) in waters of the northern Gulf of Mexico's Louisiana-Texas shelf. Mean Kq0 coefficients were estimated from 509 vertical profiles of PAR collected during 10 cruises spanning 30 months (1992-1994). Vertical profiles of density revealed that the shelf waters are divided into two periods: a stratified period with an upper layer 10 m thick of turbid waters (0.06≤Kq0≤1.18 m-1) and a lower layer of more transparent waters (0.01≤Kq0≤0.49 m-1). The second or non-stratified period consists of a homogenous layer ˜55 m thick and less turbid waters (0.03≤Kq0≤1.00 m-1). Horizontally, the distribution of Kq0 reveals nearshore coastal or case 2 waters followed by offshore oceanic or case 1 waters that separate near the 70-m isobath regardless of time and place. The Kq0 distribution reflects the freshwater influx from the Mississippi and Atchafalaya Rivers which causes a turbid surface trapped river plume, the shelf wind-driven circulation, and ensuing mixing. To investigate Kq0 we used two regression models involving salinity, suspended particulate matter (SPM), chlorophyll-a (Chl), and water depth. The best statistical model explained 57% to 85% of the observed Kq0 variability and involved the reciprocal of water depth, salinity, and SPM. However, a more bio-optically relevant model involving salinity, SPM, and Chl, explained only 32% to 64% of the observed Kq0 variability. Estimates of Kq0 for the upper layer indicate compensation depths of 30-92 m in waters deeper than 70 m which help account for the presence of coral communities on submerged banks near the shelf edge. The observed temporal and spatial distribution of Kq0 agrees qualitatively with that of satellite-derived values of the diffuse attenuation coefficient, Kd(4 9 0) over this shelf.

Extension of shelf-life of Chickoo slices using hurdle technology

International Nuclear Information System (INIS)

Shirodkar, S.; Behere, A.G.; Padwal-Desai, S.R.; Lele, S.S.; Pai, J.S.

2001-01-01

An attempt has been made to evolve a protocol to prepare shelf-stable high moisture chickoo slices using Hurdle Technology. The process is based on a slight reduction of water activity (0.98?0.94) by osmosis with a 70 deg Brix sucrose syrup, lowering of pH (5.75 to 4.46) by addition of citric acid, addition of KMS and then subjecting the resulting slices to different doses of gamma radiation ranging from 0.25-1 kGy. Radiation processed chickoo slices remained acceptable for 8 weeks at sub-room temperature (10 ± 2 degC) and for 3 weeks at ambient temperature (28 ± 2 degC) when evaluated by a taste-test panel. (author)

Characterisation of the nematode community of a low-activity cold seep in the recently ice-shelf free Larsen B area, Eastern Antarctic Peninsula.

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Freija Hauquier

Full Text Available BACKGROUND: Recent climate-induced ice-shelf disintegration in the Larsen A (1995 and B (2002 areas along the Eastern Antarctic Peninsula formed a unique opportunity to assess sub-ice-shelf benthic community structure and led to the discovery of unexplored habitats, including a low-activity methane seep beneath the former Larsen B ice shelf. Since both limited particle sedimentation under previously permanent ice coverage and reduced cold-seep activity are likely to influence benthic meiofauna communities, we characterised the nematode assemblage of this low-activity cold seep and compared it with other, now seasonally ice-free, Larsen A and B stations and other Antarctic shelf areas (Weddell Sea and Drake Passage, as well as cold-seep ecosystems world-wide. PRINCIPAL FINDINGS: The nematode community at the Larsen B seep site differed significantly from other Antarctic sites in terms of dominant genera, diversity and abundance. Densities in the seep samples were high (>2000 individuals per 10 cm(2 and showed below-surface maxima at a sediment depth of 2-3 cm in three out of four replicates. All samples were dominated by one species of the family Monhysteridae, which was identified as a Halomonhystera species that comprised between 80 and 86% of the total community. The combination of high densities, deeper density maxima and dominance of one species is shared by many cold-seep ecosystems world-wide and suggested a possible dependence upon a chemosynthetic food source. Yet stable (13C isotopic signals (ranging between -21.97±0.86‰ and -24.85±1.89‰ were indicative of a phytoplankton-derived food source. CONCLUSION: The recent ice-shelf collapse and enhanced food input from surface phytoplankton blooms were responsible for the shift from oligotrophic pre-collapse conditions to a phytodetritus-based community with high densities and low diversity. The parthenogenetic reproduction of the highly dominant Halomonhystera species is rather unusual

Effect of insulin phase state in water on its radiation stability

Energy Technology Data Exchange (ETDEWEB)

Soboleva, N N; Ivanova, A I; Tal' roze, V L; Trofimov, V I; Fedotov, V P [Nauchno-Issledovatel' skij Inst. po Biologicheskim Ispytaniyam Khimicheskikh Soedinenij (USSR); AN SSSR, Moscow. Inst. Khimicheskoj Fiziki; Akademiya Meditsinskikh Nauk SSSR, Moscow. Inst. Ehksperimental' noj Ehndokrinologii i Khimii Gormonov)

1980-01-01

Radiation stability of the aqueous solution and the insulin suspension is investigated. The degree of radiation transformations is determined by means of chromatography on paper and with the method of cramp reaction in mice. ..gamma..-irradiation is carried out at room temperature, at dose rate of 0.75 M rad/h. The data obtained prove the earlier suggested hypothesis of a phase division of a biologically active compound, personally medicinal substance and water (for example, in the case of which permits to prolong the preservation of medicine in the case of irradiation.

Shelf spawning habitat of Emmelichthys nitidus in south-eastern Australia - Implications and suitability for egg-based biomass estimation

Science.gov (United States)

Neira, Francisco J.; Lyle, Jeremy M.; Keane, John P.

2009-03-01

The spawning habitat of Emmelichthys nitidus (Emmelichthyidae) in south-eastern Australia is described from vertical ichthyoplankton samples collected along the shelf region off eastern through to south-western Tasmania during peak spawning in October 2005-06. Surveys covered eastern waters in 2005 (38.8-43.5°S), and both eastern and southern waters in 2006 (40.5°S around to 43.5°S off the south-west). Eggs ( n = 10,393) and larvae ( n = 378) occurred along eastern Tasmania in both years but were rare along southern waters south and westwards of 43.5°S in 2006. Peak egg abundances (1950-2640 per m -2) were obtained off north-eastern Tasmania (40.5-41.5°S) between the shelf break and 2.5 nm inshore from the break. Eggs were up to 5-days old, while nearly 95% of larvae were at the early preflexion stage, i.e. close to newly emerged. Average abundances of aged eggs pooled across each survey declined steadily from day-1 to day-5 eggs both in 2005 (97-18) and 2006 (175-34). Moreover, day-1 egg abundances were significantly greater 2.5 nm at either side of the break, including at the break, than in waters ≥5 nm both inshore and offshore from the break. These results, complemented with egg and larval data obtained in shelf waters off New South Wales (NSW; 35.0-37.7°S) in October 2002-03, indicate that the main spawning area of E. nitidus in south-eastern Australia lies between 35.5°S off southern NSW and 43.5°S off south-eastern Tasmania, and that spawning activity declines abruptly south and westwards of 43.5°S around to the south-west coast. In addition, quotient analyses of day-1 egg abundances point to a preferred spawning habitat contained predominantly within a 5 nm corridor along the shelf break, where waters are 125-325 m deep and median temperatures 13.5-14.0 °C. Spawning off eastern Tasmania is timed with the productivity outburst typical of the region during the austral spring, and the temperature increase from the mixing between the southwards

Tracing river runoff and DOC over the East Siberian Shelf using in situ CDOM measurements

Science.gov (United States)

Pugach, Svetlana; Semiletov, Igor; Pipko, Irina

2010-05-01

The Great Siberian Rivers integrate meteorological and hydrological changes in their watersheds and play a significant role in the physical and biogeochemical regime of the Arctic Ocean through transport of fresh water (FW) and carbon into the sea. Since 1994, the Laboratory of Arctic Research POI in cooperation with the IARC UAF investigate the fresh water and carbon fluxes in the Siberian Arctic land-shelf system with the special emphasize in the East Siberian Arctic shelf (ESAS) which represents the widest and shallowest continental shelf in the World Ocean, yet it is still poorly explored. The East Siberian Sea is influenced by water exchange from the eastern Laptev Sea (where local shelf waters are diluted mostly by Lena River discharge) and by inflow of Pacific waters from the Chukchi Sea. This region is characterized by the highest rate of coastal erosion and significant volume of the riverine discharge and exhibits the largest gradients in all oceanographic parameters observed for the entire Arctic Ocean. Here we demonstrate a connection among Chromophoric (or Colored) Dissolved Organic Matter (CDOM) which represents the colored fraction of Dissolved Organic Carbon (DOC), salinity, and pCO2. Our data have documented strong linear correlations between salinity and CDOM in the near shore zone strongly influenced by riverine runoff. Correlation coefficient between CDOM and salinity in surface waters was equal to -0.94, -0.94 and -0.95 for surface water stations in September of 2003, 2004, and 2005, respectively. Combined analysis of CDOM and DOC data demonstrated a high degree of correlation between these parameters (r=0.96). Such close connection between these characteristics of waters in this region makes it possible to restore the distribution of DOC according to our original CDOM data of the profiling systems, such as CTD-Seabird equipped by WETStar CDOM fluorimeter. It is shown that the CDOM can be used as a conservative tracer to follow the transport and

Shelf life stability comparison in air for solution processed pristine PDPP3T polymer and doped spiro-OMeTAD as hole transport layer for perovskite solar cell

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Ashish Dubey

2016-06-01

Full Text Available This data in brief includes forward and reverse scanned current density–voltage (J–V characteristics of perovskite solar cells with PDPP3T and spiro-OMeTAD as HTL, stability testing conditions of perovskite solar cell shelf life in air for both PDPP3T and spiro-OMeTAD as HTL as per the description in Ref. [1], and individual J–V performance parameters acquired with increasing time exposed in ambient air are shown for both type of devices using PDPP3T and spiro-OMeTAD as HTL. The data collected in this study compares the device stability with time for both PDPP3T and spiro-OMeTAD based perovskite solar cells and is directly related to our research article “solution processed pristine PDPP3T polymer as hole transport layer for efficient perovskite solar cells with slower degradation” [2].

Development of Low-Toxicity Wastewater Stabilization for Spacecraft Water Recovery Systems

Science.gov (United States)

Adam, Niklas; Mitchell, Julie; Pickering, Karen; Carrier, Chris; Vega, Letty; Muirhead, Dean

2014-01-01

Wastewater stabilization was an essential component of the spacecraft water cycle. The purpose of stabilizing wastewater was two-fold. First, stabilization prevents the breakdown of urea into ammonia, a toxic gas at high concentrations. Second, it prevents the growth of microorganisms, thereby mitigating hardware and water quality issues due to due biofilm and planktonic growth. Current stabilization techniques involve oxidizers and strong acids (pH=2) such as chromic and sulfuric acid, which are highly toxic and pose a risk to crew health. The purpose of this effort was to explore less toxic stabilization techniques, such as food-grade and commercial care preservatives. Additionally, certain preservatives were tested in the presence of a low-toxicity organic acid. Triplicate 300-mL volumes of urine were dosed with a predetermined quantity of stabilizer and stored for two weeks. During that time, pH, total organic carbon (TOC), ammonia, and turbidity were monitored. Those preservatives that showed the lowest visible microbial growth and stable pH were further tested in a six-month stability study. The results of the six-month study are also included in this paper.

Performance on Water Stability of Cement-Foamed Asphalt Cold Recycled Mixture

OpenAIRE

Li Junxiao; Fu Wei; Zang Hechao

2018-01-01

Through designing the mixture proportion of foamed asphalt cold in-place recycled mixture combined with the water stability experiment, it shows that the addition of cement can obviously improve foamed asphalt mixture’s water stability and the best cement admixture is between 1% ~ 2%; Using digital imaging microscope and SEM technology, the mechanism of increasing on the intensity of foamed asphalt mixture resulted by adding cement was analyzed. It revealed that the cement hydration products ...

Enzyme-polyelectrolyte complexes in water-ethanol mixtures: negatively charged groups artificially introduced into alpha-chymotrypsin provide additional activation and stabilization effects.

Science.gov (United States)

Kudryashova, E V; Gladilin, A K; Vakurov, A V; Heitz, F; Levashov, A V; Mozhaev, V V

1997-07-20

Formation of noncovalent complexes between alpha-chymotrypsin (CT) and a polyelectrolyte, polybrene (PB), has been shown to produce two major effects on enzymatic reactions in binary mixtures of polar organic cosolvents with water. (i) At moderate concentrations of organic cosolvents (10% to 30% v/v), enzymatic activity of CT is higher than in aqueous solutions, and this activation effect is more significant for CT in complex with PB (5- to 7-fold) than for free enzyme (1.5- to 2.5-fold). (ii) The range of cosolvent concentrations that the enzyme tolerates without complete loss of catalytic activity is much broader. For enhancement of enzyme stability in the complex with the polycation, the number of negatively charged groups in the protein has been artificially increased by using chemical modification with pyromellitic and succinic anhydrides. Additional activation effect at moderate concentrations of ethanol and enhanced resistance of the enzyme toward inactivation at high concentrations of the organic solvent have been observed for the modified preparations of CT in the complex with PB as compared with an analogous complex of the native enzyme. Structural changes behind alterations in enzyme activity in water-ethanol mixtures have been studied by the method of circular dichroism (CD). Protein conformation of all CT preparations has not changed significantly up to 30% v/v of ethanol where activation effects in enzymatic catalysis were most pronounced. At higher concentrations of ethanol, structural changes in the protein have been observed for different forms of CT that were well correlated with a decrease in enzymatic activity. (c) 1997 John Wiley & Sons, Inc. Biotechnol Bioeng 55: 267-277, 1997.

Ice shelf fracture parameterization in an ice sheet model

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S. Sun

2017-11-01

Full Text Available Floating ice shelves exert a stabilizing force onto the inland ice sheet. However, this buttressing effect is diminished by the fracture process, which on large scales effectively softens the ice, accelerating its flow, increasing calving, and potentially leading to ice shelf breakup. We add a continuum damage model (CDM to the BISICLES ice sheet model, which is intended to model the localized opening of crevasses under stress, the transport of those crevasses through the ice sheet, and the coupling between crevasse depth and the ice flow field and to carry out idealized numerical experiments examining the broad impact on large-scale ice sheet and shelf dynamics. In each case we see a complex pattern of damage evolve over time, with an eventual loss of buttressing approximately equivalent to halving the thickness of the ice shelf. We find that it is possible to achieve a similar ice flow pattern using a simple rule of thumb: introducing an enhancement factor ∼ 10 everywhere in the model domain. However, spatially varying damage (or equivalently, enhancement factor fields set at the start of prognostic calculations to match velocity observations, as is widely done in ice sheet simulations, ought to evolve in time, or grounding line retreat can be slowed by an order of magnitude.

Bacterial biomass and heterotrophic potential in the waters of the Chesapeake Bay plume and contiguous continental shelf

Science.gov (United States)

Kator, H. I.; Zubkoff, P. L.

1981-01-01

Seasonal baseline data on bacterial biomass and heterotrophic uptake in the Chesapeake Bay plume and contiguous Atlantic Ocean shelf waters are discussed. Viable count bacterial numbers in surface water samples collected during June 1980 ranged from a maximum of 190,000 MPN (most probable number)/ml at the Bay mouth to a minimum of 7900 MPN/ml offshore. Similarly, direct count densities ranged from 1,800,000 BU (bacterial units)/ml to 24,000 BU/ml. Heterotrophic potential (V max) was largest at the Bay mouth and lowest offshore. Biomass and V max values usually decreased with depth although subsurface maxima were occasionally observed at inshore stations. Correlation of biomass and heterotrophic potential data with selected hydrographic variables was determind with a nonparametric statistic. Results indicate viable counts are positively and significantly correlated with total chlorophyll, temperature, direct count and V max during June 1980; significant negative correlations are obtained with salinity and depth. Calculations of bacterial standing crop are discussed.

Arctic continental shelf morphology related to sea-ice zonation, Beaufort Sea, Alaska

Science.gov (United States)

Reimnitz, E.; Toimil, L.; Barnes, P.

1978-01-01

Landsat-1 and NOAA satellite imagery for the winter 1972-1973, and a variety of ice and sea-floor data were used to study sea-ice zonation and dynamics and their relation to bottom morphology and geology on the Beaufort Sea continental shelf of arctic Alaska. In early winter the location of the boundary between undeformed fast ice and westward-drifting pack ice of the Pacific Gyre is controlled by major coastal promontories. Pronounced linear pressure- and shear-ridges, as well as hummock fields, form along this boundary and are stabilized by grounding, generally between the 10- and 20-m isobaths. Slippage along this boundary occurs intermittently at or seaward of the grounded ridges, forming new grounded ridges in a widening zone, the stamukhi zone, which by late winter extends out to the 40-m isobath. Between intermittent events along the stamukhi zone, pack-ice drift and slippage is continuous along the shelf edge, at average rates of 3-10 km/day. Whether slippage occurs along the stamukhi zone or along the shelf edge, it is restricted to a zone several hundred meters wide, and ice seaward of the slip face moves at uniform rates without discernible drag effects. A causal relationship is seen between the spatial distribution of major ice-ridge systems and offshore shoals downdrift of major coastal promontories. The shoals appear to have migrated shoreward under the influence of ice up to 400 m in the last 25 years. The sea floor seaward of these shoals within the stamukhi zone shows high ice-gouge density, large incision depths, and a high degree of disruption of internal sedimentary structures. The concentration of large ice ridges and our sea floor data in the stamukhi zone indicate that much of the available marine energy is expended here, while the inner shelf and coast, where the relatively undeformed fast ice grows, are sheltered. There is evidence that anomalies in the overall arctic shelf profile are related to sea-ice zonation, ice dynamics, and bottom

Thermal stability of butter oils produced from sheep’s non-pasteurized and pasteurized milk

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FLAVIA POP

Full Text Available The physical and chemical characteristics and thermal stability of butter oil produced from non-pasteurized and pasteurized sheep’s milk were studied. Thermal stability of samples was estimated by using the accelerated shelf-life testing method. Samples were stored at 50, 60 and 70oC in the dark and the reaction was monitored by measuring peroxide, thiobarbituric acid and free fatty acid values. The peroxide and thiobarbituric acid values increased as the temperature increased. The increase of acid values of the two samples was not significant. A slight increase in free fatty acid value showed that hydrolytic reactions were not responsible for the deterioration of butter oil samples in thermal stability studies. When compared, butter oil produced from pasteurized sheep’s milk has higher thermal stability than butter oil produced from non-pasteurized sheep’s milk. Although butter oil produced from non-pasteurized milk was not exposed to any heat treatment, the shelf-life of this product was lower than the shelf-life of butter oil produced from pasteurized sheep’s milk. Therefore, heat treatment for pasteurization did not affect the thermal stability of butter oil.

Relationships between Charpy impact shelf energies and upper shelf Ksub(IC) values for reactor pressure vessel steels

International Nuclear Information System (INIS)

Witt, F.J.

1983-01-01

Charpy shelf data and lower bound estimates of Ksub(IC) shelf data for the same steels and test temperatures are given. Included are some typical reactor pressure vessel steels as well as some less tough or degraded steels. The data were evaluated with shelf estimates of Ksub(IC) up to and exceeding 550 MPa√m. It is shown that the high shelf fracture toughness representative of tough reactor pressure vessel steels may be obtained from a knowledge of the Charpy shelf energies. The toughness transition may be obtained either by testing small fracture toughness specimens or by Charpy energy indexing. (U.K.)

Stability studies of silymarin nanoemulsion containing Tween 80 as a surfactant

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Rabea Parveen

2015-01-01

Full Text Available Background: Silymarin, a flavonolignan from "milk thistle" (Silybum marianum plant is used almost exclusively for hepatoprotection. Because of its low bioavailability, it was incorporated into a nanoemulsion formulation. The aim of the present study was to check the stability of silymarin nanoemulsion at different temperatures for 3 months. Materials and Methods: The oil-in-water based nanoemulsion formulation was prepared by titration method. Silymarin nanoemulsion was characterized by droplet size, viscosity, and refractive index. Droplet size, viscosity, and refractive index were determined every month. The shelf-life of silymarin nanoemulsion was determined by accelerated stability testing. Results: It was found that there was no significant change in the droplet size, viscosity, and refractive index at refrigerator and room temperature during the period of 3 months. The half-life of the optimized nanoemulsion formulation was found to be 4.74 years at room temperature. Conclusion: These results indicated that stability of silymarin can be enhanced in nanoemulsion formulation using Tween 80 as a surfactant.

Ross Ice Shelf airstream driven by polar vortex cyclone

Science.gov (United States)

Schultz, Colin

2012-07-01

The powerful air and ocean currents that flow in and above the Southern Ocean, circling in the Southern Hemisphere's high latitudes, form a barrier to mixing between Antarctica and the rest of the planet. Particularly during the austral winter, strong westerly winds isolate the Antarctic continent from heat, energy, and mass exchange, bolstering the scale of the annual polar ozone depletion and driving the continent's record-breaking low temperatures. Pushing through this wall of high winds, the Ross Ice Shelf airstream (RAS) is responsible for a sizable amount of mass and energy exchange from the Antarctic inland areas to lower latitudes. Sitting due south of New Zealand, the roughly 470,000-square-kilometer Ross Ice Shelf is the continent's largest ice shelf and a hub of activity for Antarctic research. A highly variable lower atmospheric air current, RAS draws air from the inland Antarctic Plateau over the Ross Ice Shelf and past the Ross Sea. Drawing on modeled wind patterns for 2001-2005, Seefeldt and Cassano identify the primary drivers of RAS.

Study on shelf life extension of papayas irradiated by /sup 60/Co gamma-rays

Energy Technology Data Exchange (ETDEWEB)

Chang, M.S.; Chen, M.D.; Lin, C.T.; Fu, Y.K.

1984-11-01

Papayas are one of the main fresh fruits in Taiwan area. Papaya fruits were treated with hot water to pasteurize peels followed by /sup 60/Co gamma-ray irradiation to extend the ripening time. The purpose of synergetic methods is to extend the shelf life of papaya fruits. This experiment was carried out by seven treatments, which were: (1) control group, (2) hot water treatment only, (3) hot water treatment with a 25 krad ..gamma..-irradiation, (4) hot water treatment with a 50 krad ..gamma..-irradiation, (5) hot water treatment with a 75 krad ..gamma..-irradiation, (6) 75 krad ..gamma..-irradiation only, and (7) hot water treatment with a 100 krad ..gamma..-irradiation. The items of observation were: surface yellowing, surface decaying, quality of texture, and length of period lasted after irradiation for 50% marketable papayas. The results of this study showed that a shelf-life extension of six days could be obtained for papayas subjected to hot water (50 to 55/sup 0/C) treatment and a 100 krad irradiation. 3 refs., 2 figs., 2 tabs.

Abundant plankton-sized microplastic particles in shelf waters of the northern Gulf of Mexico.

Science.gov (United States)

Di Mauro, Rosana; Kupchik, Matthew J; Benfield, Mark C

2017-11-01

Accumulation of marine debris is a global problem that affects the oceans on multiple scales. The majority of floating marine debris is composed of microplastics: plastic particles up to 5 mm in diameter. With similar sizes and appearances to natural food items, these small fragments pose potential risks to many marine organisms including zooplankton and zooplanktivores. Semi-enclosed seas are reported to have high concentrations of microplastics, however, the distribution and concentration of microplastics in one such system, the Gulf of Mexico, remains unknown. Our study documented and characterized microplastics in continental shelf waters off the Louisiana coast in the northern Gulf of Mexico, using bongo nets, neuston nets, and Niskin bottles. Additionally, we compared the size distributions of microplastics and zooplankton collected using the nets. Plastics were manually sorted from the samples, documented, and measured using digital microscopy. Confirmation of putative plastics was carried out by hydrofluoric acid digestion and a subsample was analyzed using FTIR microscopy. Estimated concentrations of microplastics collected on the inner continental shelf during this study are among the highest reported globally. Total microplastic concentrations ranged from 4.8 to 8.2 particles m -3 and 5.0-18.4 particles m -3 for the bongo and neuston samples, respectively. Niskin bottles collected smaller plastic particles than the nets and indicated total microplastic concentrations (primarily fibers) from 6.0E4 - 15.7E4 particles m -3 . Microplastic concentrations were greater than the abundances of all but four of the five most abundant taxa from bongo nets and were not statistically different from the abundances of any of the most numerous taxa from neuston nets. Sizes of microplastics and zooplankton partially or completely overlapped, suggesting the potential for confusion with natural prey. Copyright © 2017 Elsevier Ltd. All rights reserved.

The Asymmetric Continental Shelf Wave in Response to the Synoptic Wind Burst in a Semienclosed Double-Shelf Basin

Science.gov (United States)

Qu, Lixin; Lin, Xiaopei; Hetland, Robert D.; Guo, Jingsong

2018-01-01

The primary goal of this study is to investigate the asymmetric structure of continental shelf wave in a semienclosed double-shelf basin, such as the Yellow Sea. Supported by in situ observations and realistic numerical simulations, it is found that in the Yellow Sea, the shelf wave response to the synoptic wind forcing does not match the mathematically symmetric solution of classic double-shelf wave theory, but rather exhibits a westward shift. To study the formation mechanism of this asymmetric structure, an idealized model was used and two sets of experiments were conducted. The results confirm that the asymmetric structure is due to the existence of a topographic waveguide connecting both shelves. For a semienclosed basin, such as the Yellow Sea, a connection at the end of the basin eliminates the potential vorticity barrier between the two shelves and hence plays a role as a connecting waveguide for shelf waves. This waveguide enables the shelf wave to propagate from one shelf to the other shelf and produces the asymmetric response in sea level and upwind flow evolutions.

The Stability, Sustained Release and Cellular Antioxidant Activity of Curcumin Nanoliposomes

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Xing Chen

2015-08-01

Full Text Available Curcumin is a multifunctional and natural agent considered to be pharmacologically safe. However, its application in the food and medical industry is greatly limited by its poor water solubility, physicochemical instability and inadequate bioavailability. Nanoliposome encapsulation could significantly enhance the solubility and stability of curcumin. Curcumin nanoliposomes exhibited good physicochemical properties (entrapment efficiency = 57.1, particle size = 68.1 nm, polydispersity index = 0.246, and zeta potential = −3.16 mV. Compared with free curcumin, curcumin nanoliposomes exhibited good stability against alkaline pH and metal ions as well as good storage stability at 4 °C. Curcumin nanoliposomes also showed good sustained release properties. Compared with free curcumin, curcumin nanoliposomes presented an equal cellular antioxidant activity, which is mainly attributed to its lower cellular uptake as detected by fluorescence microscopy and flow cytometry. This study provide theoretical and practical guides for the further application of curcumin nanoliposomes.

Shelf life extension and sensory evaluation of birch tree sap using chemical preservatives

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Maciej Bilek

2016-10-01

Full Text Available The aim of this study was to assess the stability of the birch tree sap, depending on the addition and concentration of two chemical factors, ie. potassium sorbate and acids: malic, citric or lactic. As in our previous studies we found that the optimal physical parameter to assess the stability of birch sap is turbidity measurement, we used turbidimeter for estimate the effectiveness of shelf life extending. Sensory evaluation was carried out by university sensory panel with 8 skilled people (students and teachers with pre-selection and basic training of sensory methodology. On the other hand artificial perception measurements were realized by electronic nose. Birch tree sap stability without addition of preservatives, both room temperature and refrigerated, is less than three days. The effectiveness of preservation of birch tree sap depends on the concentration of acids. Independently of storage temperature, samples that received stability during the whole one-month storage period, were those with potassium sorbate and three acids in the highest concentrations, ie. malic acid at 0.3%, citric acid at 0.5% and lactic acid at 0.5%. Unfortunately, concentrations of acids, which allow extension of shelf life at least for one month in a room temperature, are characterized by the worst sensory evaluation rating. Thus, they should be corrected by the use of additives for improving the flavor, such as fruit syrups or herbal extracts. On the other hand, additionally storage in a refrigerated conditions allows one-month-stability for the sample with the highest sensory evaluation rating, ie. with the addition of lactic acid at 0.1% and potassium sorbate, which taste not need to be corrected.

Microfluidic preparation and self diffusion PFG-NMR analysis of monodisperse water-in-oil-in-water double emulsions.

Science.gov (United States)

Hughes, Eric; Maan, Abid Aslam; Acquistapace, Simone; Burbidge, Adam; Johns, Michael L; Gunes, Deniz Z; Clausen, Pascal; Syrbe, Axel; Hugo, Julien; Schroen, Karin; Miralles, Vincent; Atkins, Tim; Gray, Richard; Homewood, Philip; Zick, Klaus

2013-01-01

Monodisperse water-in-oil-in-water (WOW) double emulsions have been prepared using microfluidic glass devices designed and built primarily from off the shelf components. The systems were easy to assemble and use. They were capable of producing double emulsions with an outer droplet size from 100 to 40 μm. Depending on how the devices were operated, double emulsions containing either single or multiple water droplets could be produced. Pulsed-field gradient self-diffusion NMR experiments have been performed on the monodisperse water-in-oil-in-water double emulsions to obtain information on the inner water droplet diameter and the distribution of the water in the different phases of the double emulsion. This has been achieved by applying regularization methods to the self-diffusion data. Using these methods the stability of the double emulsions to osmotic pressure imbalance has been followed by observing the change in the size of the inner water droplets over time. Copyright © 2012 Elsevier Inc. All rights reserved.

The Cross Surfzone/Inner-shelf Dye Exchange (CSIDE) Experiment Overview: Binational Dye Tracer Releases to Study Pollution Transport and Dilution.

Science.gov (United States)

Feddersen, F.; Giddings, S. N.; Kumar, N.; Grimes, D. J.; Pawlak, G. R.; Rivas, D.; Diaz, M.

2016-02-01

Per square km, the surfzone and inner-shelf are by far the most economically and ecologically important ocean regions, vital for recreation, food, and ecosystem services. Despite the importance of clean coastal waters to our economy and well-being, declining water quality threatens coastal ecosystem and human health worldwide. Healthy coasts are a significant priority to federal agencies, local government, and NGOs. In particular the San Diego US and Tijuana Mexico border region have unique and persistent water quality issues due to a range of pollution sources. Cross-shore exchange of tracers (e.g., pathogens, anthropogenic nutrients, harmful algal blooms - HABs, larvae) between the well-mixed surfzone and stratified inner-shelf is poorly understood. The surfzone, inner- and mid-shelf span drastically different dynamical regimes, with varying cross-shelf exchange mechanisms due to wave, wind, buoyancy, and tidal processes and intrinsic variability. The NSF funded CSIDE (Cross Surfzone/Inner-shelf Dye Exchange) experiment (Sept & Oct 2015) aims to increase our understanding of cross-shelf material exchange by performing 3 shoreline dye release experiments that are tracked for up to 20 km alongshore and over 48+ hrs. One dye release will be performed in Mexico and the dye transport tracked across the border. The dye will be tracked via a broad range of binational instrumentation. In this presentation, we present an overview of the CSIDE experiment, in particular the binational aspects of the study,

Flexural-response of the McMurdo Ice Shelf to surface lake filling and drainage

Science.gov (United States)

Banwell, A. F.; MacAyeal, D. R.; Willis, I.; Macdonald, G. J.; Goodsell, B.

2017-12-01

Antarctic ice-shelf instability and break-up, as exhibited by the Larsen B ice shelf in 2002, remains one of the most difficult glaciological processes to observe directly. It is, however, vital to do so because ice-shelf breakup has the potential to influence the buttressing controls on inland ice discharge, and thus to affect sea level. Several mechanisms enabling Larsen B style breakup have previously been proposed, including the ability of surface lakes to introduce ice-shelf fractures when they fill and drain. During the austral summer of 2016/2017, we monitored the filling and draining of four surface lakes on the McMurdo Ice Shelf, Antarctica, and the effect of these processes on ice-shelf flexure. Water-depth data from pressure sensors reveal that two lakes filled to >2 m in depth and subsequently drained over multiple week timescales, which had a simultaneous effect on vertical ice deflection in the area. Differential GPS data from 12 receivers over three months show that vertical deflection varies as a function of distance from the maximum load change (i.e. at the lake centre). Using remote sensing techniques applied to both Landsat 8 and Worldview imagery, we also quantify the meltwater volume in these two lakes through the melt season, which, together with the vertical deflection data, are used to constrain key flexural parameter values in numerical models of ice-shelf flexure.

Tunable Enzymatic Activity and Enhanced Stability of Cellulase Immobilized in Biohybrid Nanogels.

Science.gov (United States)

Peng, Huan; Rübsam, Kristin; Jakob, Felix; Schwaneberg, Ulrich; Pich, Andrij

2016-11-14

This paper reports a facile approach for encapsulation of enzymes in nanogels. Our approach is based on the use of reactive copolymers able to get conjugated with enzyme and build 3D colloidal networks or biohybrid nanogels. In a systematic study, we address the following question: how the chemical structure of nanogel network influences the biocatalytic activity of entrapped enzyme? The developed method allows precise control of the enzyme activity and improvement of enzyme resistance against harsh store conditions, chaotropic agents, and organic solvents. The nanogels were constructed via direct chemical cross-linking of water-soluble reactive copolymers poly(N-vinylpyrrolidone-co-N-methacryloxysuccinimide) with proteins such as enhanced green fluorescent protein (EGFP) and cellulase in water-in-oil emulsion. The water-soluble reactive copolymers with controlled amount of reactive succinimide groups and narrow dispersity were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization. Poly(ethylene glycol) bis(3-aminopropyl) and branched polyethylenimine were utilized as model cross-linkers to optimize synthesis of nanogels with different architectures in the preliminary experiments. Biofluorescent nanogels with different loading amount of EGFP and varying cross-linking densities were obtained. We demonstrate that the biocatalytic activity of cellulase-conjugated nanogels (CNG) can be elegantly tuned by control of their cross-linking degrees. Circular dichroism (CD) spectra demonstrated that the secondary structures of the immobilized cellulase were changed in the aspect of α-helix contents. The secondary structures of cellulase in highly cross-linked nanogels were strongly altered compared with loosely cross-linked nanogels. The fluorescence resonance energy transfer (FRET) based study further revealed that nanogels with lower cross-linking degree enable higher substrate transport rate, providing easier access to the active site of

Eddy-resolving simulations of the Fimbul Ice Shelf cavity circulation: Basal melting and exchange with open ocean

Science.gov (United States)

Hattermann, T.; Smedsrud, L. H.; Nøst, O. A.; Lilly, J. M.; Galton-Fenzi, B. K.

2014-10-01

Melting at the base of floating ice shelves is a dominant term in the overall Antarctic mass budget. This study applies a high-resolution regional ice shelf/ocean model, constrained by observations, to (i) quantify present basal mass loss at the Fimbul Ice Shelf (FIS); and (ii) investigate the oceanic mechanisms that govern the heat supply to ice shelves in the Eastern Weddell Sea. The simulations confirm the low melt rates suggested by observations and show that melting is primarily determined by the depth of the coastal thermocline, regulating deep ocean heat fluxes towards the ice. Furthermore, the uneven distribution of ice shelf area at different depths modulates the melting response to oceanic forcing, causing the existence of two distinct states of melting at the FIS. In the simulated present-day state, only small amounts of Modified Warm Deep Water enter the continental shelf, and ocean temperatures beneath the ice are close to the surface freezing point. The basal mass loss in this so-called state of "shallow melting" is mainly controlled by the seasonal inflow of solar-heated surface water affecting large areas of shallow ice in the upper part of the cavity. This is in contrast to a state of "deep melting", in which the thermocline rises above the shelf break depth, establishing a continuous inflow of Warm Deep Water towards the deep ice. The transition between the two states is found to be determined by a complex response of the Antarctic Slope Front overturning circulation to varying climate forcings. A proper representation of these frontal dynamics in climate models will therefore be crucial when assessing the evolution of ice shelf basal melting along this sector of Antarctica.

Adequacy of environmental information for outer continental shelf oil and gas decisions: Georges Bank. Final report

International Nuclear Information System (INIS)

1991-01-01

Georges Bank, a large, shallow marine bank with important fishery resources and possibly important oil and gas resources, lies east of Massachusetts in the territorial waters of both the United States and Canada. The Department of the Interior has planned since 1974 to lease parts of the north Atlantic outer continental shelf (OCS)--including part of Georges Bank--for oil and gas exploration. As a result of public concern about the environmental impacts of oil and gas production on the U.S. OCS, Congress declared a moratorium on drilling on Georges Bank and an area to the southwest. The report--by the NRC's Committee to Review the Outer Continental Shelf Environmental Studies Program and its panels on physical oceanography, ecology, and socioeconomics--reviews the adequacy of information bearing on the potential environmental impacts of OCS oil and gas activities for the Georges Bank sale area

Flux of energy and essential elements through the continental shelf ecosystem. Progress report

Energy Technology Data Exchange (ETDEWEB)

Pomeroy, L.R.

1981-11-30

There are three distinct but not mutually exclusive areas of research in this contract, studies of intrusions of the west wall of the Gulf Stream onto the outer continental shelf, studies of the flux of materials across nearshore density fronts, and advances in understanding of the planktonic food web of the continental shelf. Studies of frontal events on the outer and inner continental shelf involve distinctive physical and chemical regimes and have proven to require distinctive biological approaches. The studies of the food web run through our work on both of the frontal regimes, but certain aspects have become subjects in their own right. We have developed a simulation model of the flux of energy through the continental shelf food web which we believe to be more realistic than previous ones of its type. We have examined several of the many roles of dissolved organic compounds in sea water which originate either from release by phytoplankton, digestive processes or metabolites of zooplankton, or extracellular digestion of microorganisms. Methods have been developed under this contract to measure both the chelating capacity of naturally occurring organic materials and the copper concentration in the water. It has been possible to characterize the effects, both toxic and stimulatory, of copper on photosynthesis of naturally occurring phytoplankton populations. It is possible to characterize in considerable detail the course of biological events associated with meanders of the Gulf Stream. We are now in a position to explain the limits to biological productivity of the outer continental shelf of the southeastern US and the reasons why that biological production moves through the food web in the characteristic way that it does.

Shelf-Life of Chlorine Solutions Recommended in Ebola Virus Disease Response.

Directory of Open Access Journals (Sweden)

Qais Iqbal

Full Text Available In Ebola Virus Disease (EVD outbreaks, it is widely recommended to wash living things (handwashing with 0.05% (500 mg/L chlorine solution and non-living things (surfaces, personal protective equipment, dead bodies with 0.5% (5,000 mg/L chlorine solution. Chlorine solutions used in EVD response are primarily made from powdered calcium hypochlorite (HTH, granular sodium dichloroisocyanurate (NaDCC, and liquid sodium hypochlorite (NaOCl, and have a pH range of 5-11. Chlorine solutions degrade following a reaction highly dependent on, and unusually sensitive to, pH, temperature, and concentration. We determined the shelf-life of 0.05% and 0.5% chlorine solutions used in EVD response, including HTH, NaDCC, stabilized NaOCl, generated NaOCl, and neutralized NaOCl solutions. Solutions were stored for 30 days at 25, 30, and 35°C, and tested daily for chlorine concentration and pH. Maximum shelf-life was defined as days until initial concentration fell to 30 days. Models were developed for solutions with maximum shelf-lives between 1-30 days. Extrapolating to 40°C, the maximum predicted shelf-life for 0.05% and 0.5% NaDCC solutions were 0.38 and 0.82 hours, respectively; predicted shelf-life for 0.05% and 0.5% generated NaOCl solutions were >30 and 5.4 days, respectively. Each chlorine solution type offers advantages and disadvantages to responders, as: NaDCC is an easy-to-import high-concentration effervescent powder; HTH is similar, but forms a precipitate that may clog pipes; and, NaOCl solutions can be made locally, but are difficult to transport. We recommend responders chose the most appropriate source chlorine compound for their use, and ensure solutions are stored at appropriate temperatures and used or replaced before expiring.

Hydraulic modelling for analysis of the hot water layer stability in research reactor

International Nuclear Information System (INIS)

Ribeiro, Rogerio; Yanagihara, Jurandir Itizo

1995-01-01

Pool reactors are research reactors, which allow easy access to the core and are simple to operate. Reactors of this kind operating at power levels higher than about one megawatt need a hot water layer at the surface of the pool, in order to keep surface activity below acceptable levels and enable free access to the upper part of the reactor. This work presents similitude criteria derived by dimensional analysis and by non dimensioning the basic equations to analyze this layer's stability in a reduced scale model. The flow in the reactor is complex. It is impossible to consider all the phenomena with a single similitude criterion. The best would be to construct several models considering all the similitude criteria and then combine the results. Economical reasons and available time in the majority of the cases are a restrain to this procedure. Then, the most important criteria to the considered phenomenon must be chosen in order to give the best results. This work identifies three similitude criteria that were considered important to analyze the pool reactor's hot water layer stability. (author)

Sedimentation on the Valencia Continental Shelf: Preliminary results

Science.gov (United States)

Maldonado, Andres; Swift, Donald J. P.; Young, Robert A.; Han, Gregory; Nittrouer, Charles A.; DeMaster, David J.; Rey, Jorge; Palomo, Carlos; Acosta, Juan; Ballester, A.; Castellvi, J.

1983-10-01

Preliminary analysis of data collected during the course of a cooperative Spanish-United States investigation of the Valencia Shelf (western Mediterranean) reveals a storm-dominated, mud-accumulating sedimentary regime. Calcareous mud is accumulating seaward of a narrow band of shoreface sand and gravel. On the outer shelf the mud is enriched by a pelagic calcareous component. Preliminary 210Pb data from vertical profiles of box cores yield nominal accumulation rates from 2.6 mm y -1 near the Ebro Delta to 1.3 mm y -1 on the southern portion of the Valencia Shelf. Storm-current winnowing has resulted in the development of a biogenic lag sand over the mid-shelf mud in the northern part of the study area. Piston cores reveal a basal Holocene sand and gravel facies similar to that presently seen on the inner shelf. Upward-fining sequences on the central and outer shelf are inferred to result from the landward shift of lithotopes during the course of the Holocene transgression. These sequences are locally repeated, perhaps as the consequence of brief, local interludes of coastal progradation. Application of a diagnostic circulation model suggests that intense, downwelling coastal flows occur during winter northeastern storms. Storm activity has induced erosional shoreface retreat during the course of the Holocene transgression and has generated by this means the basal coarse facies observed in the piston cores. In the central part of the study area seaward of the Albufera Lagoon, the mud blanket thins to a layer several centimeters thick which is draped over a thickened (10 m) basal sand. The basal sand is molded into northwest trending ridges. The data are not sufficient to determine whether these are overstepped barriers, or submarine sand ridges formed by storm flows during the shoreface retreat process.

Circulation in the SAV, Shelf of Veracruz, Mexico

Science.gov (United States)

Zavala-Hidalgo, J.; Martinez-Lopez, B.; Fernandez-Eguiarte, A.; de Buen, R.; Rojas, J.

2007-05-01

Data from current meter, hydrographic measurements, and numerical modeling are analyzed to determine the circulation patterns in the Sistema Arrecifal Veracruzano (SAV), Veracruz, Mexico, region. Results show that the main forcing in the region is the along-coast wind stress component. Tides contribute with one order of magnitude less energy, during the fall-winter period. Two main regimes are identified: one between the coast and the 20 m isobath, with waters of large turbidity and small influence from rivers, and the other between the 20 m isobath and the external shelf, with clearer waters. Stratified water column with low temperature upwelled waters near the bottom are observed when southeasterly winds are present. Downwelling and southeastward currents are associated with northerly winds linked with northers.

Shelf erosion and submarine river canyons: implications for deep-sea oxygenation and ocean productivity during glaciation

Directory of Open Access Journals (Sweden)

I. Tsandev

2010-06-01

Full Text Available The areal exposure of continental shelves during glacial sea level lowering enhanced the transfer of erodible reactive organic matter to the open ocean. Sea level fall also activated submarine canyons thereby allowing large rivers to deposit their particulate load, via gravity flows, directly in the deep-sea. Here, we analyze the effects of shelf erosion and particulate matter re-routing to the open ocean during interglacial to glacial transitions, using a coupled model of the marine phosphorus, organic carbon and oxygen cycles. The results indicate that shelf erosion and submarine canyon formation may significantly lower deep-sea oxygen levels, by up to 25%, during sea level low stands, mainly due to the supply of new material from the shelves, and to a lesser extent due to particulate organic matter bypassing the coastal zone. Our simulations imply that deep-sea oxygen levels can drop significantly if eroded shelf material is deposited to the seafloor. Thus the glacial ocean's oxygen content could have been significantly lower than during interglacial stages. Primary production, organic carbon burial and dissolved phosphorus inventories are all affected by the erosion and rerouting mechanisms. However, re-routing of the continental and eroded shelf material to the deep-sea has the effect of decoupling deep-sea oxygen demand from primary productivity in the open ocean. P burial is also not affected showing a disconnection between the biogeochemical cycles in the water column and the P burial record.

Intercomparison of Antarctic ice-shelf, ocean, and sea-ice interactions simulated by MetROMS-iceshelf and FESOM 1.4

Science.gov (United States)

Naughten, Kaitlin A.; Meissner, Katrin J.; Galton-Fenzi, Benjamin K.; England, Matthew H.; Timmermann, Ralph; Hellmer, Hartmut H.; Hattermann, Tore; Debernard, Jens B.

2018-04-01

An increasing number of Southern Ocean models now include Antarctic ice-shelf cavities, and simulate thermodynamics at the ice-shelf/ocean interface. This adds another level of complexity to Southern Ocean simulations, as ice shelves interact directly with the ocean and indirectly with sea ice. Here, we present the first model intercomparison and evaluation of present-day ocean/sea-ice/ice-shelf interactions, as simulated by two models: a circumpolar Antarctic configuration of MetROMS (ROMS: Regional Ocean Modelling System coupled to CICE: Community Ice CodE) and the global model FESOM (Finite Element Sea-ice Ocean Model), where the latter is run at two different levels of horizontal resolution. From a circumpolar Antarctic perspective, we compare and evaluate simulated ice-shelf basal melting and sub-ice-shelf circulation, as well as sea-ice properties and Southern Ocean water mass characteristics as they influence the sub-ice-shelf processes. Despite their differing numerical methods, the two models produce broadly similar results and share similar biases in many cases. Both models reproduce many key features of observations but struggle to reproduce others, such as the high melt rates observed in the small warm-cavity ice shelves of the Amundsen and Bellingshausen seas. Several differences in model design show a particular influence on the simulations. For example, FESOM's greater topographic smoothing can alter the geometry of some ice-shelf cavities enough to affect their melt rates; this improves at higher resolution, since less smoothing is required. In the interior Southern Ocean, the vertical coordinate system affects the degree of water mass erosion due to spurious diapycnal mixing, with MetROMS' terrain-following coordinate leading to more erosion than FESOM's z coordinate. Finally, increased horizontal resolution in FESOM leads to higher basal melt rates for small ice shelves, through a combination of stronger circulation and small-scale intrusions of

Multi-Decadal Averages of Basal Melt for Ross Ice Shelf, Antarctica Using Airborne Observations

Science.gov (United States)

Das, I.; Bell, R. E.; Tinto, K. J.; Frearson, N.; Kingslake, J.; Padman, L.; Siddoway, C. S.; Fricker, H. A.

2017-12-01

Changes in ice shelf mass balance are key to the long term stability of the Antarctic Ice Sheet. Although the most extensive ice shelf mass loss currently is occurring in the Amundsen Sea sector of West Antarctica, many other ice shelves experience changes in thickness on time scales from annual to ice age cycles. Here, we focus on the Ross Ice Shelf. An 18-year record (1994-2012) of satellite radar altimetry shows substantial variability in Ross Ice Shelf height on interannual time scales, complicating detection of potential long-term climate-change signals in the mass budget of this ice shelf. Variability of radar signal penetration into the ice-shelf surface snow and firn layers further complicates assessment of mass changes. We investigate Ross Ice Shelf mass balance using aerogeophysical data from the ROSETTA-Ice surveys using IcePod. We use two ice-penetrating radars; a 2 GHz unit that images fine-structure in the upper 400 m of the ice surface and a 360 MHz radar to identify the ice shelf base. We have identified internal layers that are continuous along flow from the grounding line to the ice shelf front. Based on layer continuity, we conclude that these layers must be the horizons between the continental ice of the outlet glaciers and snow accumulation once the ice is afloat. We use the Lagrangian change in thickness of these layers, after correcting for strain rates derived using modern day InSAR velocities, to estimate multidecadal averaged basal melt rates. This method provides a novel way to quantify basal melt, avoiding the confounding impacts of spatial and short-timescale variability in surface accumulation and firn densification processes. Our estimates show elevated basal melt rates (> -1m/yr) around Byrd and Mullock glaciers within 100 km from the ice shelf front. We also compare modern InSAR velocity derived strain rates with estimates from the comprehensive ground-based RIGGS observations during 1973-1978 to estimate the potential magnitude of

Protein Stabilization and Enzyme Activation in Ionic Liquids: Specific Ion Effects

Science.gov (United States)

Zhao, Hua

2015-01-01

There are still debates on whether the hydration of ions perturbs the water structure, and what is the degree of such disturbance; therefore, the origin of Hofmeister effect on protein stabilization continues being questioned. For this reason, it is suggested to use the ‘specific ion effect’ instead of other misleading terms such as Hofmeister effect, Hofmeister series, lyotropic effect, and lyotropic series. In this review, we firstly discuss the controversial aspect of inorganic ion effects on water structures, and several possible contributors to the specific ion effect of protein stability. Due to recent overwhelming attraction of ionic liquids (ILs) as benign solvents in many enzymatic reactions, we further evaluate the structural properties and molecular-level interactions in neat ILs and their aqueous solutions. Next, we systematically compare the specific ion effects of ILs on enzyme stability and activity, and conclude that (a) the specificity of many enzymatic systems in diluted aqueous IL solutions is roughly in line with the traditional Hofmeister series albeit some exceptions; (b) however, the specificity follows a different track in concentrated or neat ILs because other factors (such as hydrogen-bond basicity, nucelophilicity, and hydrophobicity, etc) are playing leading roles. In addition, we demonstrate some examples of biocatalytic reactions in IL systems that are guided by the empirical specificity rule. PMID:26949281

Zooplankton from the shelf watrs off the west coast of India

Digital Repository Service at National Institute of Oceanography (India)

Nair, V.R.; Peter, G.

Zooplankton in the shelf waters of India from Dabhol to Tuticorin was studied during the 17th cruise of R.V. Gaveshani in March 1977. Biomass values were relatively high in the central zone between Mangalore and Alleppey. In the region between...

The petroleum resources on the Norwegian Continental Shelf. 2009

Energy Technology Data Exchange (ETDEWEB)

2009-07-01

Exploration activity has reached record-breaking levels in the last couple of years, which has led to many, but small, discoveries. The NPD believes that large discoveries can still be made in areas of the shelf that have not been extensively explored. Content: Challenges on the Norwegian continental shelf; Value creation in fields; 40 years of oil and gas production; Resource management; Still many possibilities; Energy consumption and the environment; Exploration; Access to acreage; Awards of new licenses; Exploration in frontier areas; Exploration history and statistics; Resources and forecasts; Undiscovered resources; Proven recoverable resources; Forecasts; Short-term petroleum production forecast (2009-2013); Investments- and operating costs forecasts; Long-term forecast for the petroleum production; Emissions from the petroleum activity. (AG)

Landscape stability and water management around the ancient city Jerash, Jordan

DEFF Research Database (Denmark)

Holdridge, Genevieve; Kristiansen, Søren Munch; Raja, Rubina

2017-01-01

paleoenvironmental and landscape studies have provided much needed insight into the changes of a city0 s surroundings. However, more in-depth urban archaeological studies of soils and sediments on-site, and the interaction of processes on- and off-site are needed to provide new information on human impact...... Dayr, which feeds into the Zarqa River, and the area is affected by the tectonic activity of the Dead Sea Rift zone. Since the Roman period, various structures were built to manage surface water including rock-cut and plastered channels, water reservoirs and cisterns. Also, during the city’s long......, and are currently analyzing sediments and soils at both landscape and intra-site scales. Profiles in key locations of the wadi offer insight into slope stability (upstream), site land use (midstream) and overall impacts on the wadi system (downstream). Analyses include soil geochemistry, micromorphology...

Modelling shelf-ocean exchange and its biogeochemical consequences in coastal upwelling systems

DEFF Research Database (Denmark)

Muchamad, Al Azhar

margin bathymetry, and 3) what processes determine the observed variability of total organic carbon (TOC) content in shelf sediments underlying the upwelling system, with implications for the formation of petroleum source rocks. Here, a numerical ocean modeling approach is used in this thesis to explore...... processes and the development of anoxia/euxinia under the present day or past geological conditions. Thirdly and last, processes controlling distribution of total organic carbon (TOC) content in sediments across the continental margin is evaluated by application of the model to the Benguela upwelling system....... In the model, biological primary production and shelf bottom-water anoxia result in enhanced sedimentary TOC concentrations on the mid shelf and upper slope. The simulated TOCs implicate that bottom lateral transport only has a significant effect on increasing the deposition of the organic carbon on the mid...

Ice-Shelf Melt Response to Changing Winds and Glacier Dynamics in the Amundsen Sea Sector, Antarctica

Science.gov (United States)

Donat-Magnin, Marion; Jourdain, Nicolas C.; Spence, Paul; Le Sommer, Julien; Gallée, Hubert; Durand, Gaël.

2017-12-01

It has been suggested that the coastal Southern Ocean subsurface may warm over the 21st century in response to strengthening and poleward shifting winds, with potential adverse effects on West Antarctic glaciers. However, using a 1/12° ocean regional model that includes ice-shelf cavities, we find a more complex response to changing winds in the Amundsen Sea. Simulated offshore subsurface waters get colder under strengthened and poleward shifted winds representative of the SAM projected trend. The buoyancy-driven circulation induced by ice-shelf melt transports this cold offshore anomaly onto the continental shelf, leading to cooling and decreased melt below 450 m. In the vicinity of ice-shelf fronts, Ekman pumping contributes to raise the isotherms in response to changing winds. This effect overwhelms the horizontal transport of colder offshore waters at intermediate depths (between 200 and 450 m), and therefore increases melt rates in the upper part of the ice-shelf cavities, which reinforces the buoyancy-driven circulation and further contributes to raise the isotherms. Then, prescribing an extreme grounding line retreat projected for 2100, the total melt rates simulated underneath Thwaites and Pine Island are multiplied by 2.5. Such increase is explained by a larger ocean/ice interface exposed to CDW, which is then amplified by a stronger melt-induced circulation along the ice draft. Our main conclusions are that (1) outputs from ocean models that do not represent ice shelf cavities (e.g., CMIP5 models) should not be directly used to predict the thermal forcing of future ice shelf cavities; (2) coupled ocean/ice sheet models with a velocity-dependent melt formulation are needed for future projections of glaciers experiencing a significant grounding line retreat.

Oceanic hydraulic structures for developing a shelf. Issledovaniye morskikh gidrotekhnicheskikh sooruzheniy dlya osvoyenia sel'fa

Energy Technology Data Exchange (ETDEWEB)

Simakov, G.B.

1980-01-01

The anthology is devoted to practical problems of oceanic hydraulic engineering which arise during design and construction of specialized oceanic hydraulic structures to be erected and used in the shelf zones of seas and oceans. Most of the articles deal with studying the external effect of rough waters, impacts from ships and ice floes on floating and stationary hydraulic structures for developing a shelf. A great deal of attention is also given to the hydrodynamic and anchoring of floating hydraulic structures. The information reflects the current status of the problems of designing and building production facilities for developing a continental shelf.

Modeling Nitrogen Decrease in Water Lettuce Ponds from Waste Stabilization Ponds

Science.gov (United States)

Putri, Gitta Agnes; Sunarsih

2018-02-01

This paper presents about the dynamic modeling of the Water Lettuce ponds as a form of improvement from the Water Hyacinth ponds. The purpose of this paper is to predict nitrogen decrease and nitrogen transformation in Water Lettuce ponds integrated with Waste Stabilization Ponds. The model consists of 4 mass balances, namely Dissolved Organic Nitrogen (DON), Particulate Organic Nitrogen (PON), ammonium (NH4+), Nitrate and Nitrite (NOx). The process of nitrogen transformation which considered in a Water Lettuce ponds, namely hydrolysis, mineralization, nitrification, denitrification, plant and bacterial uptake processes. Numerical simulations are performed by giving the values of parameters and the initial values of nitrogen compounds based on a review of previous studies. Numerical results show that the rate of change in the concentration of nitrogen compounds in the integration ponds of waste stabilization and water lettuce decreases and reaches stable at different times.

Stabilizing local boundary conditions for two-dimensional shallow water equations

KAUST Repository

Dia, Ben Mansour

2018-03-27

In this article, we present a sub-critical two-dimensional shallow water flow regulation. From the energy estimate of a set of one-dimensional boundary stabilization problems, we obtain a set of polynomial equations with respect to the boundary values as a requirement for the energy decrease. Using the Riemann invariant analysis, we build stabilizing local boundary conditions that guarantee the stability of the hydrodynamical state around a given steady state. Numerical results for the controller applied to the nonlinear problem demonstrate the performance of the method.

Transformation of internal solitary waves at the "deep" and "shallow" shelf: satellite observations and laboratory experiment

Directory of Open Access Journals (Sweden)

O. D. Shishkina

2013-10-01

Full Text Available An interaction of internal solitary waves with the shelf edge in the time periods related to the presence of a pronounced seasonal pycnocline in the Red Sea and in the Alboran Sea is analysed via satellite photos and SAR images. Laboratory data on transformation of a solitary wave of depression while passing along the transverse bottom step were obtained in a tank with a two-layer stratified fluid. The certain difference between two characteristic types of hydrophysical phenomena was revealed both in the field observations and in experiments. The hydrological conditions for these two processes were named the "deep" and the "shallow" shelf respectively. The first one provides the generation of the secondary periodic short internal waves – "runaway" edge waves – due to change in the polarity of a part of a soliton approaching the shelf normally. Another one causes a periodic shear flow in the upper quasi-homogeneous water layer with the period of incident solitary wave. The strength of the revealed mechanisms depends on the thickness of the water layer between the pycnocline and the shelf bottom as well as on the amplitude of the incident solitary wave.

Experiment for water-flow measurement by pulsed-neutron activation

International Nuclear Information System (INIS)

Drozdowicz, K.

1994-08-01

An experiment is presented which constitutes a feasibility study for applying the neutron activation method for measurement of the water mass transport in pipings, e.g. in nuclear power stations. The fast neutron generator has been used as a pulsed-neutron activation source for oxygen in water which circulated in a closed system. The γ radiation of the nitrogen product isotope has been measured by the scintillation detectors placed in two positions at the piping. The two time distributions of the pulses have been recorded by a multiscaler (a software design based on CAMAC). The water flow velocity has been estimated from the peak-to-peak time distance. The tests have been performed under different experimental conditions (the neutron pulse duration, the time channel width, the water flow velocity) to define the stability, reproducibility and reliability of the measurement. The detailed results are presented in tables and in time distribution plots. The method has been found useful for the application considered. 4 refs, 17 figs, 5 tabs

Stability of a1 mg/mL oral solution zidovudine

International Nuclear Information System (INIS)

Garcia Penna, Caridad Margarita; Morales Lacarrere, Ivan; Martinez Espinosa, Vivian

2011-01-01

The carrying out of a high-performance liquid chromatography analytical method was assessed; applicable to stability study of oral solution zidovudine (1 mg/mL) was made. The analytical method was linear, precise, specific and exact in the study concentrations. The stability study of oral solution zidovudine (1 mg/mL) was conducted determining expiring date. The shelf life study was conducted over 24 months at room temperature; whereas that of accelerated stability was conducted with the product under wet and temperature conditions; analysis was carried out over three months. Formula met quality specifications described in Pharmacopeia. Results from the shelf life study demonstrated that product keeps the parameters determining its quality during that time and in accelerated studies there was not significant product degradation. Under above mentioned conditions two years were established as expiring date

Conductometric method for determining water stability and nutrient leaching of extruded fish feed

Directory of Open Access Journals (Sweden)

Banjac Vojislav V.

2017-01-01

Full Text Available Water stability of eight samples of extruded salmon feeds was first determined by applying two gravimetric methods developed by the authors: gravimetric static and wet sieving method. Then, the conductometric method, primarily developed for investigation of nutrient leaching of feed into the water by the authors, was used for each sample. The aim of this study was to evaluate the potential of the conductometric measurement as a technique for determining water stability of extruded fish feed. In order to find any correlation between the results of two gravimetric tests and conductometric method, correlation analysis was employed. The results of static and wet sieving method were expressed as water stability index, which was expressed as the percent of remained dry matter of sample after being disintegrated in the water. The results of conductometric method were shown as conductivity curves for each sample, giving the insight in rate of nutrient leaching during the time. The obtained values of water conductivity showed no significant (p < 0.05 correlation with the results of static water method, while there was a negative significant (p < 0.05 correlation with the results of wet sieving method during first four hours of pellets soaking in water. The highest correlation coefficients were obtained within the first hour of conductivity measurement, demonstrating that proposed conductometric method had a potential to be applied as a rapid and simple method for determination and relative comparison of salmon feed water stability.[ Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. III46012 and Grant no. TR31011

Steady state and linear stability analysis of a supercritical water natural circulation loop

International Nuclear Information System (INIS)

Sharma, Manish; Pilkhwal, D.S.; Vijayan, P.K.; Saha, D.; Sinha, R.K.

2010-01-01

Supercritical water (SCW) has excellent heat transfer characteristics as a coolant for nuclear reactors. Besides it results in high thermal efficiency of the plant. However, the flow can experience instabilities in supercritical water reactors, as the density change is very large for the supercritical fluids. A computer code SUCLIN using supercritical water properties has been developed to carry out the steady state and linear stability analysis of a SCW natural circulation loop. The conservation equations of mass, momentum and energy have been linearized by imposing small perturbation in flow rate, enthalpy, pressure and specific volume. The equations have been solved analytically to generate the characteristic equation. The roots of the equation determine the stability of the system. The code has been qualitatively assessed with published results and has been extensively used for studying the effect of diameter, height, heater inlet temperature, pressure and local loss coefficients on steady state and stability behavior of a Supercritical Water Natural Circulation Loop (SCWNCL). The present paper describes the linear stability analysis model and the results obtained in detail.

Development of safe and shelf-stable Intermediate Moisture (IM) convenience meat products through radiation processing

International Nuclear Information System (INIS)

Ramesh Chander; Kanatt, S.R.; Chawla, S.P.; Bongirwar, D.R.

2001-01-01

Ready-to-use shelf stable mutton and chicken sheek kababs, and chicken chilly were developed by reducing the water activity either by grilling or by hot air drying, vacuum packing and irradiation. Microbiological analysis revealed a dose dependent reduction in total viable count and in Staphylococcus species on irradiation treatment ( 2.5, 5.0 and 10.0 kGy). The products subjected to irradiation at 10 kGy showed absence of viable micro-organisms and also had high sensory acceptability up to 9 months at ambient temperature. (author)

Combined Statistical Analyses for Long-Term Stability Data with Multiple Storage Conditions : A Simulation Study

NARCIS (Netherlands)

Almalik, Osama; Nijhuis, Michiel B.; van den Heuvel, Edwin R.

2014-01-01

Shelf-life estimation usually requires that at least three registration batches are tested for stability at multiple storage conditions. The shelf-life estimates are often obtained by linear regression analysis per storage condition, an approach implicitly suggested by ICH guideline Q1E. A linear

Membrane Stabilizing Activity And Phytochemistry Of Hibiscus rosa ...

African Journals Online (AJOL)

The human erythrocyte membrane stabilizing activity of saline extract of Hibiscus rosa-sinensis leaves was investigated as part of efforts at validating its use as anti-arthritic and anti-inflammatory agent. The results of the membrane stabilizing activity of the extract, when compared to two non-steroidal anti-inflammatory drugs ...

Chemotrophic Ecosystem Beneath the Larsen Ice Shelf, Antarctica

Science.gov (United States)

Leventer, A.; Domack, E.; Ishman, S.; Sylva, S.; Willmott, V.; Huber, B.; Padman, L.

2005-12-01

The first living chemotrophic ecosystem in the Southern Ocean was discovered in a region of the seafloor previously occupied by the Larsen-B Ice Shelf. A towed video survey documents an ecosystem characterized by a bottom-draping white mat that appears similar to mats of Begiattoa, hydrogen sulfide oxidizing bacteria, and bivalves, 20-30 cm large, similar to vesicomyid clams commonly found at cold seeps. The carbon source is unknown; three potential sources are hypothesized. First, thermogenically-produced methane may occur as the marine shales of this region are similar to hydrocarbon-bearing rocks to the north in Patagonia. The site occurs in an 850 m deep glacially eroded trough located along the contact between Mesozoic-Tertiary crystalline basement and Cretaceous-Tertiary marine rocks; decreased overburden could have induced upward fluid flow. Also possible is the dissociation of methane hydrates, a process that might have occurred as a result of warming oceanic bottom waters. This possibility will be discussed in light of the distribution of early diagenetic ikaite in the region. Third, the possibility of a biogenic methane source will be discussed. A microstratigraphic model for the features observed at the vent sites will be presented; the system is comprised of mud mounds with central vents and surrounding mud flow channels. A series of still image mosaics record the dynamic behavior of the system, which appears to demonstrate episodic venting. These images show the spatial relationship between more and less active sites, as reflected in the superposition of several episodes of mud flow activity and the formation of mud channels. In addition, detailed microscale features of the bathymetry of the site will be presented, placing the community within the context of glacial geomorphologic features. The Larsen-B Ice Shelf persisted through the entire Holocene, limiting carbon influx from a photosynthetic source. Tidal modeling of both pre and post breakup

41 CFR 101-27.205 - Shelf-life codes.

Science.gov (United States)

2010-07-01

... 41 Public Contracts and Property Management 2 2010-07-01 2010-07-01 true Shelf-life codes. 101-27...-Management of Shelf-Life Materials § 101-27.205 Shelf-life codes. Shelf-life items shall be identified by use of a one-digit code to provide for uniform coding of shelf-life materials by all agencies. (a) The...

Arrhenius equation modeling for the shelf life prediction of tomato paste containing a natural preservative.

Science.gov (United States)

Jafari, Seid Mahdi; Ganje, Mohammad; Dehnad, Danial; Ghanbari, Vahid; Hajitabar, Javad

2017-12-01

The shelf life of tomato paste with microencapsulated olive leaf extract was compared with that of samples containing a commercial preservative by accelerated shelf life testing. Based on previous studies showing that olive leaf extract as a rich source of phenolic compounds can have antimicrobial properties, application of its encapsulated form to improve the storage stability of tomato paste is proposed here. Regarding total soluble solids, the control and the sample containing 1000 µg g -1 sodium benzoate had the lowest (Q 10  = 1.63) and highest (Q 10  = 1.88) sensitivity to temperature changes respectively; also, the microencapsulated sample containing 1000 µg g -1 encapsulated olive leaf extract (Q 10  = 1.83) followed the sample containing 1000 µg g -1 sodium benzoate in terms of the highest kinetic rates. In the case of consistency, the lowest and highest activation energies (E a ) corresponded to samples containing 1000 µg g -1 non-encapsulated olive leaf extract and 1000 µg g -1 microencapsulated olive leaf extract respectively. Interestingly, samples containing microencapsulated olive leaf extract could maintain the original quality of the tomato paste very well, while those with non-encapsulated olive leaf extract rated the worst performance (among all specimens) in terms of maintaining their quality indices for a long time period. Overall, the shelf life equation was able to predict the consistency index of all tomato paste samples during long-time storage with high precision. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

An appraisal of the enzyme stability-activity trade-off.

Science.gov (United States)

Miller, Scott R

2017-07-01

A longstanding idea in evolutionary physiology is that an enzyme cannot jointly optimize performance at both high and low temperatures due to a trade-off between stability and activity. Although a stability-activity trade-off has been observed for well-characterized examples, such a trade-off is not imposed by any physical chemical constraint. To better understand the pervasiveness of this trade-off, I investigated the stability-activity relationship for comparative biochemical studies of purified orthologous enzymes identified by a literature search. The nature of this relationship varied greatly among studies. Notably, studies of enzymes with low mean synonymous nucleotide sequence divergence were less likely to exhibit the predicted negative correlation between stability and activity. Similarly, a survey of directed evolution investigations of the stability-activity relationship indicated that these traits are often uncoupled among nearly identical yet phenotypically divergent enzymes. This suggests that the presumptive trade-off often reported for investigations of enzymes with high mean sequence divergence may in some cases instead be a consequence of the degeneration over time of enzyme function in unselected environments, rather than a direct effect of thermal adaptation. The results caution against the general assertion of a stability-activity trade-off during enzyme adaptation. © 2017 The Author(s). Evolution © 2017 The Society for the Study of Evolution.

Active water exchange and life near the grounding line of an Antarctic outlet glacier

Science.gov (United States)

Sugiyama, Shin; Sawagaki, Takanobu; Fukuda, Takehiro; Aoki, Shigeru

2014-08-01

The grounding line (GL) of the Antarctic ice sheet forms the boundary between grounded and floating ice along the coast. Near this line, warm oceanic water contacts the ice shelf, producing the ice sheet's highest basal-melt rate. Despite the importance of this region, water properties and circulations near the GL are largely unexplored because in-situ observations are difficult. Here we present direct evidence of warm ocean-water transport to the innermost part of the subshelf cavity (several hundred meters seaward from the GL) of Langhovde Glacier, an outlet glacier in East Antarctica. Our measurements come from boreholes drilled through the glacier's ∼400-m-thick grounding zone. Beneath the grounding zone, we find a 10-24-m-deep water layer of uniform temperature and salinity (-1.45 °C; 34.25 PSU), values that roughly equal those measured in the ocean in front of the glacier. Moreover, living organisms are found in the thin subglacial water layer. These findings indicate active transport of water and nutrients from the adjacent ocean, meaning that the subshelf environment interacts directly and rapidly with the ocean.

Export of Dissolved Lignin from Coastal Wetlands to the Louisiana Shelf

Science.gov (United States)

Bianchi, T. S.; Dimarco, S. F.; Smith, R. W.; Schreiner, K. M.

2008-12-01

Here we report on spatial and temporal changes in the concentration and composition of dissolved lignin- phenols in surface and bottom waters off the Louisiana coast (USA). Samples were collected at 7 stations on 2 cruises (April, and July, 2008) along a transect that spanned from inside Terrebonne Bay, Louisiana (12 m water depth) to the outer-most station on the inner Louisiana shelf (21 m water depth). The highest average concentration of dissolved organic carbon (DOC) and dissolved lignin, during both cruises, occurred at the interface between Terrebonne Bay and the inner shelf. Average DOC and dissolved lignin concentrations were significantly higher in April than in July across most stations. Based on hydrologic data, these higher concentrations clearly reflect a combined mixing of DOM from plume waters to the west and local marsh inputs. The cinnamyl/vanillyl (C/V) and syringyl/vanillyl (S/V) ratios indicated that the predominant source of lignin was from non-woody angiosperms - likely the dominant species of wetland plants Spartina alterniflora and S. patens (Spartina spp.) that border the entire bay. The high vanillic acid to vanillin (Ad/Al)v ratios for all stations were typical of that found near estuarine boundaries, where biologically- and photochemically-mediated lignin decay processes are important. This preliminary data indicates that wetlands provide another source of dissolved organic matter (DOM) to the Louisiana shelf that likely contributes to microbial food resources and hence hypoxia, especially in the context of the instability and extensive erosion of these marshes over the past ca. 50 years. This has important implications for the current management plan to reduce hypoxia in the GOM, particularly in those regions that extend west of the nutrient-rich highly productive near-field zones of Atchafalaya-Mississippi river plumes.

Morphodynamics and stratigraphic architecture of shelf-edge deltas subject to constant vs. dynamic environmental forcings

Science.gov (United States)

Straub, K. M.

2017-12-01

When deltas dock at the edge of continental margins they generally construct thick stratigraphic intervals and activate channelized continental slope systems. Deposits of shelf-edge deltas have the capacity to store detailed paleo-environmental records, given their location in the source to sink system. However, present day highstand sea-level conditions have pushed most deltaic systems well inbound of their shelf-edges, making it difficult to study their space-time dynamics and resulting stratigraphic products. Several competing theories describe how deltas and their downslope environments respond to sea-level cycles of varying magnitude and periodicity. We explore these hypotheses in a physical experiment where the topographic evolution of a coupled delta and downdip slope system was monitored at high temporal and spatial resolution. The experiment had three stages. In the first stage a delta aggraded at the shelf-edge under constant water and sediment supply, in addition to a constant generation of accommodation through a sea-level rise. In the second stage the sediment transport system responded to low magnitude and high frequency sea-level cycles. Finally, in the third stage the transport system responded to a high magnitude and long period sea-level cycle. In each stage, fine sediment from the input grain size distribution and dissolved salt in the input water supply promoted plunging hyperpycnal flows. Specifically, we compare the mean and temporal variability of the sediment delivered to the slope system between stages. In addition, we compare stratigraphic architecture and sediment sizes delivered to the slope system in each stage. These results are used to improve inversion of slope deposits for paleo-environmental forcings.

Formulation and stability of topical water in oil emulsion containing ...

African Journals Online (AJOL)

Purpose: To formulate the water in oil (W/O) emulsion of corn silk (CS) extract and to evaluate its stability at various storage conditions. Methods: Ethanol CS extract was prepared using maceration (cold) technique. A 4 % CS emulsion was prepared using varying concentrations of liquid paraffin, ABIL EM90 and water.

Sub-ice-shelf sediments record history of twentieth-century retreat of Pine Island Glacier.

Science.gov (United States)

Smith, J A; Andersen, T J; Shortt, M; Gaffney, A M; Truffer, M; Stanton, T P; Bindschadler, R; Dutrieux, P; Jenkins, A; Hillenbrand, C-D; Ehrmann, W; Corr, H F J; Farley, N; Crowhurst, S; Vaughan, D G

2017-01-05

The West Antarctic Ice Sheet is one of the largest potential sources of rising sea levels. Over the past 40 years, glaciers flowing into the Amundsen Sea sector of the ice sheet have thinned at an accelerating rate, and several numerical models suggest that unstable and irreversible retreat of the grounding line-which marks the boundary between grounded ice and floating ice shelf-is underway. Understanding this recent retreat requires a detailed knowledge of grounding-line history, but the locations of the grounding line before the advent of satellite monitoring in the 1990s are poorly dated. In particular, a history of grounding-line retreat is required to understand the relative roles of contemporaneous ocean-forced change and of ongoing glacier response to an earlier perturbation in driving ice-sheet loss. Here we show that the present thinning and retreat of Pine Island Glacier in West Antarctica is part of a climatically forced trend that was triggered in the 1940s. Our conclusions arise from analysis of sediment cores recovered beneath the floating Pine Island Glacier ice shelf, and constrain the date at which the grounding line retreated from a prominent seafloor ridge. We find that incursion of marine water beyond the crest of this ridge, forming an ocean cavity beneath the ice shelf, occurred in 1945 (±12 years); final ungrounding of the ice shelf from the ridge occurred in 1970 (±4 years). The initial opening of this ocean cavity followed a period of strong warming of West Antarctica, associated with El Niño activity. Thus our results suggest that, even when climate forcing weakened, ice-sheet retreat continued.

Mesoporous templated silicas: stability, pore size engineering and catalytic activation

International Nuclear Information System (INIS)

Vansant, Etienne

2003-01-01

structural characterization techniques (XRD and N2-adsorption-desorption) to insure that the crystallinity and the porosity of the structure are still intact. Also the catalytic evaluation of the synthesized materials is an essential part of the characterization. The activity and product selectivity are compared with commercial and conventional catalysts, initially by using a simple probe reaction. Hereby the characteristics of the catalyst, such as leaching, hydrothermal stability, regeneration and mechanical strength are evaluated. Most MTS materials exhibit a rather poor mechanical and hydrothermal stability. The intrinsic stability of these materials can be improved by either optimizing the synthesis conditions, yielding more stable structures, or by introducing a post-synthesis modification step with a stabilizing reagent. This post synthesis modification step consists of silylation procedures, that are either aiming at a thickening of the pore wall (mechanical stability) or at a partial hydrophobization of the surface (improving both mechanical and hydrothermal stability). Hereby, secondary anchoring groups are created which are interesting for catalytic activation. Furthermore, with this treatment the leaching of the active centers (metal oxides) is reduced to almost zero, even in liquid water. Recently, we have developed an entirely new material, called PHMTS (Plugged Hexagonal Mesoporous Templated Silica). The material consists of hexagonally packed cylindrical pores, with large pore widths (6-8 nm) and thick pore walls (3-4 nm). The pore walls themselves are perforated with micropores. Moreover, microporous silica plugs exist inside the mesopores, resulting in a unique nitrogen desorption isotherm and unprecedented possibilities for adsorption (controlled desorption), encapsulation and catalysis. (author)

Isolated Pt Atoms Stabilized by Amorphous Tungstenic Acid for Metal-Support Synergistic Oxygen Activation.

Science.gov (United States)

Zhang, Qian; Qin, Xixi; Duanmu, Fanpeng; Ji, Huiming; Shen, Zhurui; Han, Xiaopeng; Hu, Wenbin

2018-06-05

Oxygen activation plays a crucial role in many important chemical reactions such as organics oxidation and oxygen reduction. For developing highly active materials for oxygen activation, herein, we report an atomically dispersed Pt on WO3 nanoplates stabilized by in-situ formed amorphous H2WO4 out-layer and the mechanism for activating molecular oxygen. Experimental and theoretical studies demonstrate that the isolated Pt atoms coordinated with oxygen atoms from [WO6] and water of H2WO4, consequently leading to optimized surface electronic configuration and strong metal support interaction (SMSI). In exemplified reactions of butanone oxidation sensing and oxygen reduction, the atomic Pt/WO3 hybrid exhibits superior activity than those of Pt nanoclusters/WO3 and bare WO3 as well as enhanced long-term durability. This work will provide insight on the origin of activity and stability for atomically dispersed materials, thus promoting the development of highly efficient and durable single atom-based catalysts. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Behavior of tungsten carbide in water stabilized plasma

Czech Academy of Sciences Publication Activity Database

Brožek, Vlastimil; Matějíček, Jiří; Neufuss, Karel

2007-01-01

Roč. 7, č. 4 (2007), s. 213-220 ISSN 1335-8987 R&D Projects: GA ČR(CZ) GA104/05/0540 Institutional research plan: CEZ:AV0Z20430508 Keywords : water stabilized plasma * tungsten carbide * tungsten hemicarbide * decarburization Subject RIV: BL - Plasma and Gas Discharge Physics

Particle residence times in waters of the Yangtze and Amazon continental shelves

International Nuclear Information System (INIS)

McKee, B.A.; Nittrouer, C.A.; DeMaster, D.J.

1986-01-01

Water column and seabed samples were analyzed for naturally occurring Th-234 to determine particle residence times in Yangtze and Amazon continental-shelf waters. On the Yangtze shelf, the water column was vertically well-mixed and suspended-sediment concentrations decreased offshore (from 230 mg/l near the river mouth to 2 mg/l in mid-shelf waters). Particle residence times increased offshore and ranged from 3.2 hours (12 m water depth) to 7.3 days (60 m water depth). Particle residence times ranged from 3 to 30 times shorter than values predicted by settling of discrete (4-8 micron) particles, suggesting that particles were settling in aggregate form. On the Amazon shelf, a two-layer estuarine flow dominated shelf circulation. Suspended-sediment concentrations on the inner shelf (10-12 m water depth) were much greater in bottom waters (range: 100-880 mg/l) than in surface waters (range 5-60 mg/l) as a result of resuspension. Particle residence times ranged from 1.1 days in surface waters to 2.5 days in bottom waters. Particles probably underwent several cycles of resuspension before permanent removal from the water column

SOFT COMPUTING SINGLE HIDDEN LAYER MODELS FOR SHELF LIFE PREDICTION OF BURFI

Directory of Open Access Journals (Sweden)

Sumit Goyal

2012-05-01

Full Text Available Burfi is an extremely popular sweetmeat, which is prepared by desiccating the standardized water buffalo milk. Soft computing feedforward single layer models were developed for predicting the shelf life of burfi stored at 30g.C. The data of the product relating to moisture, titratable acidity, free fatty acids, tyrosine, and peroxide value were used as input variables, and the overall acceptability score as output variable. The results showed excellent agreement between the experimental and the predicted data, suggesting that the developed soft computing model can alternatively be used for predicting the shelf life of burfi.

Outer Continental Shelf Lands Act

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This data represents geographic terms used within the Outer Continental Shelf Lands Act (OCSLA or Act). The Act defines the United States outer continental shelf...

21 CFR 211.166 - Stability testing.

Science.gov (United States)

2010-04-01

... record of such data shall be maintained. Accelerated studies, combined with basic stability information on the components, drug products, and container-closure system, may be used to support tentative expiration dates provided full shelf life studies are not available and are being conducted. Where data from...

Time Series of Transport and Currents on the Chukchi Shelf: 2010 - 2015

Science.gov (United States)

Stabeno, P. J.; Ladd, C. A.; Mordy, C. W.; Sullivan, M. E.

2016-02-01

Starting in 2010, NOAA/EcoFOCI in partnership with BOEM, has measured currents and water properties at multiple mooring sites on the Chukchi shelf and slope. Observations began at three sites (C1, C2, C3) off Icy Cape in 2010 and expanded in 2013 to include three sites around Barrow Canyon and two sites northeast of Hanna Shoal. In 2014, a mooring was deployed on the slope (1000 m) northeast of Hanna Shoal. A near-continuous velocity record exists at C2 from August 2010 - September 2015. These velocity data are combined with 40 satellite-tracked drifter trajectories (drogue depth 30 m) and hydrographic transects (2010 - 2015) to examine flow patterns and transport on the eastern Chukchi shelf. Six primary hydrographic transects extending from Pt. Hope (DBO3) to Barrow Canyon (DBO5) were occupied most years. Transport past Icy Cape accounts for 40% of the transport through Bering Strait. Maximum monthly-mean transport (>0.8 Sv) is in July with low interannual variability, while the lowest monthly transports are in December - April with high interannual variability. Currents are significantly correlated with alongshore winds. Satellite-tracked drifters deployed near Bering Strait show onshelf flow at Central Channel. Drifters deployed along the Icy Cape line are transported northeastward, converging to a narrow flow, and mainly exit the shelf through Barrow Canyon. The drifters then travel westward along the slope. In summer, drifters and hydrographic sections delineate the pathways of the nutrient-poor Alaska Coastal Current, and the nutrient-rich water to the west (Bering Sea water and Anadyr water). These data were collected mainly as part of three BOEM funded projects (CHAOZ, CHAOZ-Extension and ArcWEST).

Spoilage and shelf-life extension of fresh fish and shellfish.

Science.gov (United States)

Ashie, I N; Smith, J P; Simpson, B K

1996-01-01

Fresh fish and shellfish are highly perishable products due to their biological composition. Under normal refrigerated storage conditions, the shelf life of these products is limited by enzymatic and microbiological spoilage. However, with increasing consumer demands for fresh products with extended shelf life and increasing energy costs associated with freezing and frozen storage, the fish-processing industry is actively seeking alternative methods of shelf life preservation and marketability of fresh, refrigerated fish and at the same time economizing on energy costs. Additional methods that could fulfill these objectives include chemical decontamination, low-dose irradiation, ultra-high pressure, and modified atmosphere packaging (MAP). This review focuses on the biochemical and microbiological composition of fresh fish/shellfish, the spoilage patterns in these products, factors influencing spoilage, and the combination treatments that can be used in conjunction with refrigeration to extend the shelf life and keeping quality of fresh fish/shellfish. The safety concerns of minimally processed/MAP fish, specifically with respect to the growth of Clostridium botulinum type E, is also addressed.

Dynamic Stabilization of Metal Oxide–Water Interfaces

Energy Technology Data Exchange (ETDEWEB)

McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne E.; Eng, Peter J.; Blumberger, Jochen; Rosso, Kevin M.

2017-02-08

The interaction of water with metal oxide surfaces plays a crucial role in the catalytic and geochemical behavior of metal oxides. In a vast majority of studies, the interfacial structure is assumed to arise from a relatively static lowest energy configuration of atoms, even at room temperature. Using hematite (α-Fe2O3) as a model oxide, we show through a direct comparison of in situ synchrotron X-ray scattering with density functional theory-based molecular dynamics simulations that the structure of the (1102) termination is dynamically stabilized by picosecond water exchange. Simulations show frequent exchanges between terminal aquo groups and adsorbed water in locations and with partial residence times consistent with experimentally determined atomic sites and fractional occupancies. Frequent water exchange occurs even for an ultrathin adsorbed water film persisting on the surface under a dry atmosphere. The resulting time-averaged interfacial structure consists of a ridged lateral arrangement of adsorbed water molecules hydrogen bonded to terminal aquo groups. Surface pKa prediction based on bond valence analysis suggests that water exchange will influence the proton-transfer reactions underlying the acid/base reactivity at the interface. Our findings provide important new insights for understanding complex interfacial chemical processes at metal oxide–water interfaces.

Hydraulic Properties of Porous Media Saturated with Nanoparticle-Stabilized Air-Water Foam

Directory of Open Access Journals (Sweden)

Xianglei Zheng

2016-12-01

Full Text Available The foam generated by the mixture of air and water has a much higher viscosity and lower mobility than those of pure water or gas that constitutes the air-water foam. The possibility of using the air-water foam as a flow barrier for the purpose of groundwater and soil remediation is explored in this paper. A nanoparticle-stabilized air-water foam was fabricated by vigorously stirring the nano-fluid in pressurized condition. The foam bubble size distribution was analyzed with a microscope. The viscosities of foams generated with the solutions with several nanoparticle concentrations were measured as a function of time. The breakthrough pressure of foam-saturated microfluidic chips and sand columns were obtained. The hydraulic conductivity of a foam-filled sand column was measured after foam breakthrough. The results show that: (1 bubble coalescence and the Ostwald ripening are believed to be the reason of bubble size distribution change; (2 the viscosity of nanoparticle-stabilized foam and the breakthrough pressures decreased with time once the foam was generated; (3 the hydraulic conductivity of the foam-filled sand column was almost two orders of magnitude lower than that of a water-saturated sand column even after the foam-breakthrough. Based on the results in this study, the nanoparticle-stabilized air-water foam could be injected into contaminated soils to generate vertical barriers for temporary hydraulic conductivity reduction.

Reaction of PFCs in water stabilized plasma

Czech Academy of Sciences Publication Activity Database

Mastný, L.; Horníček, J.; Živný, Oldřich; Brožek, Vlastimil; Sember, Viktor

2017-01-01

Roč. 13, č. 1 (2017), s. 161 ISSN 1336-7242. [Zjazd chemikov /69./. 11.09.2017-15.09.2017, Horný Smokovec] R&D Projects: GA ČR(CZ) GC17-10246J Institutional support: RVO:61389021 Keywords : Water stabilized plasma * tetrafluoromethane * corrosion resistance * boron nitride * titanium nitride Subject RIV: BL - Plasma and Gas Discharge Physics OBOR OECD: Fluids and plasma physics (including surface physics)

Atomically Monodisperse Nickel Nanoclusters as Highly Active Electrocatalysts for Water Oxidation

KAUST Repository

Joya, Khurram

2016-04-08

Achieving water splitting at low overpotential with high oxygen evolution efficiency and stability is important for realizing solar to chemical energy conversion devices. Herein we report the synthesis, characterization and electrochemical evaluation of highly active nickel nanoclusters (Ni NCs) for water oxidation at low overpotential. These atomically precise and monodisperse Ni NCs are characterized by using UV-visible absorption spectroscopy, single crystal X-ray diffraction and mass spectrometry. The molecular formulae of these Ni NCs are found to be Ni4(PET)8 and Ni6(PET)12 and are highly active electrocatalysts for oxygen evolution without any pre-conditioning. Ni4(PET)8 are slightly better catalysts than Ni6(PET)12 and initiate the oxygen evolution at an amazingly low overpotential of ~1.51 V (vs RHE; η ≈ 280 mV). The peak oxygen evolution current density (J) of ~150 mA cm–2 at 2.0 V (vs. RHE) with a Tafel slope of 38 mV dec–1 is observed using Ni4(PET)8. These results are comparable to the state-of-the art RuO2 electrocatalyst, which is highly expensive and rare compared to Ni-based materials. Sustained oxygen generation for several hours with an applied current density of 20 mA cm–2 demonstrates the long-term stability and activity of these Ni NCs towards electrocatalytic water oxidation. This unique approach provides a facile method to prepare cost-effective, nanoscale and highly efficient electrocatalysts for water oxidation.

Dynamic Stabilization of Metal Oxide–Water Interfaces

Energy Technology Data Exchange (ETDEWEB)

McBriarty, Martin E.; von Rudorff, Guido Falk; Stubbs, Joanne; Eng, Peter; Blumberger, Jochen; Rosso, Kevin M.

2017-02-08

Metal oxide growth, dissolution, and redox reactivity depend on the structure and dynamics at the interface with aqueous solution. We present the most definitive analysis to date of the hydrated naturally abundant r-cut (11$\\bar{0}$2) termination of the iron oxide hematite (α-Fe₂O₃). In situ synchrotron X-ray scattering analysis reveals a ridged lateral arrangement of adsorbed water molecules hydrogen bonded to terminal aquo groups. Large-scale hybrid-functional density functional theory-based molecular dynamics (DFT-MD) simulations show how this structure is dynamically stabilized by picosecond exchange between aquo groups and adsorbed water, even under nominally dry conditions. Surface pKa prediction based on bond valence analysis suggests that water exchange may influence the proton transfer reactions associated with acid/base reactivity at the interface. Our findings rectify inconsistencies between existing models and may be extended to resolving more complex electrochemical phenomena at metal oxide-water interfaces.

Shelf Life Prediction for Canned Gudeg using Accelerated Shelf Life Testing (ASLT) Based on Arrhenius Method

Science.gov (United States)

Nurhayati, R.; Rahayu NH, E.; Susanto, A.; Khasanah, Y.

2017-04-01

Gudeg is traditional food from Yogyakarta. It is consist of jackfruit, chicken, egg and coconut milk. Gudeg generally have a short shelf life. Canning or commercial sterilization is one way to extend the shelf life of gudeg. This aims of this research is to predict the shelf life of Andrawinaloka canned gudeg with Accelerated Shelf Life Test methods, Arrhenius model. Canned gudeg stored at three different temperature, there are 37, 50 and 60°C for two months. Measuring the number of Thio Barbituric Acid (TBA), as a critical aspect, were tested every 7 days. Arrhenius model approach is done with the equation order 0 and order 1. The analysis showed that the equation of order 0 can be used as an approach to estimating the shelf life of canned gudeg. The storage of Andrawinaloka canned gudeg at 30°C is predicted untill 21 months and 24 months for 25°C.

Development of the Technologies for Stabilization Treatment of the Water of the Recycling Cooling Systems at Thermal Power Plants

Science.gov (United States)

Vlasov, S. M.; Chichirova, N. D.; Chichirov, A. A.; Vlasova, A. Yu.; Filimonova, A. A.; Prosvirnina, D. V.

2018-02-01

A turbine-condensate cooling system is one of the less stable and most hard-to-control systems of maintaining optimal water chemistry. A laboratory recycling cooling water test facility, UVO-0.3, was developed for physical simulation of innovative zero-discharge water chemistry conditions and improvement of technological flowcharts of stabilization treatment of the initial and circulating water of the recycling cooling systems at thermal power plants. Experiments were conducted in the UVO-0.3 facility to investigate the processes that occur in the recycling water supply system and master new technologies of stabilization of the initial and circulating water. It is shown that, when using untreated initial water, scaling cannot be prevented even under low concentration levels. The main reason for the activation of scale depositing is the desorption of carbon dioxide that results in alkalization of the circulating water and, as a consequence, a displacement of the chemical reaction equilibrium towards the formation of slightly soluble hardness ions. Some techniques, viz., liming and alkalization of the initial water and the by-pass treatment of the circulating water, are considered. New engineering solutions have been developed for reducing the amount of scale-forming substances in the initial and circulating water. The best results were obtained by pretreating the initial water with alkalizing agents and simultaneously bypassing and treating part of the circulating water. The obtained experimental data underlie the process flowcharts of stabilization treatment of the initial and circulating TPP water that ensure scale-free and noncorrosive operation and meet the corresponding environmental requirements. Under the bypassing, the specific rates of the agents and the residual hardness are reduced compared with the conventional pretreatment.

The study of stability, combustion characteristics and performance of water in diesel emulsion fuel

Directory of Open Access Journals (Sweden)

Syafiq Zulkifli

2017-01-01

Full Text Available A single cylinder diesel engine study of water in diesel emulsions was conducted to investigate the stability effect of emulsion fuel on three different fuel blends and the water emulsification effect on the engine performance. Emulsified fuels contained 2% of surfactant including Span 80 Tween 80 and tested 10 HLB number. The blends also varied of 5%, 10% and 15% of water in diesel ratios namely as BSW5, BSW10 and BSW15. The fuel blends performance was tested using a single cylinder, direct injection diesel engine, operating at 1860 rpm. The results on stability reveal that high shear homogenizer yields more stability on emulsion fuel than mechanical stirrer and ultrasonic water bath. The engine performance results show that the ignition delay and peak pressure increase with the increment of water percentage up to 15%. However, the results indicate the increment of water percentage is also shows a significant decrease in engine power.

Accumulation of 210Po by spiny dogfish (Squalus acanthias), elephant fish (Callorhinchus milii) and red gurnard (Chelodonichthys kumu) in New Zealand shelf waters

International Nuclear Information System (INIS)

Bellamy, P.; Hunter, K.A.

1997-01-01

Concentrations of the natural radionuclide 210 Po in the livers of 81 individual specimens of three fish species collected from waters of the Otago continental shelf, New Zealand, have been measured: spiny dogfish (Squalus acanthias), 4.2 ± 1.8 Bq kg -1 wet weight (mean ± standard deviation, n=48); elephant fish (Callorhinchus milii), 136 ± 39 Bq kg -1 (n = 7); and red gurnard (Chelodonichthys kumu), 38 ± 13 Bq kg -1 (n = 26). Separate measurements showed that only a negligible fraction of the 210 Po was supported by decay of the 210 Pb parent ( 210 Po/ 210 Pb activity ratios were 15, 134 and 5.9 respectively for the three species), indicating that direct uptake of 210 Po into the liver balances losses from excretion and radioactive decay. The radiation dose from 210 Po in the livers accounted for between 88% and 99% of the total internal absorbed dose received by the fish species. The activity of 210 Po in sea water from the study area was 0.9-2.2 mBq L -1 , yielding concentration factors for 210 Po in liver tissue in the range 3 x 103 to 100 x 103. No significant monophasic relationships were observed between the 210 Po results and the measured concentrations of the elements Cd, Cu, Fe, Mn, Zn and Pb, except that Pb and 210 Po were correlated (r = 0.511 ) in C. kumu. Copyright (1997) CSIRO Publishing

Accumulation of 210 Po by spiny dogfish (Squalus acanthias), elephant fish (Callorhinchus milii) and red gurnard (Chelodonichthys kumu) in New Zealand shelf waters

International Nuclear Information System (INIS)

Peter Bellamy, P.; Hunter, K.A.

1997-01-01

Concentrations of the natural radionuclide 210 Po in the livers of 81 individual specimens of three fish species collected from waters of the Otago continental shelf, New Zealand, have been measured: spiny dogfish (Squalus acanthias), 4.2 ± 1.8 Bq kg -1 wet weight (mean ± standard deviation, n = 48); elephant fish (Callorhinchus milii), 136 ± 39 Bq kg -1 (n = 7); and red gurnard (Chelodonichthys kumu), 38 ± 13 Bq kg -1 (n = 26). Separate measurements showed that only a negligible fraction of the 210 Po was supported by decay of the 210 Pb parent ( 210 Po/ 210 Pb activity ratios were 15, 134 and 5.9 respectively for the three species), indicating that direct uptake of 210 Po into the liver balances losses from excretion and radioactive decay. The radiation dose from 210 Po in the livers accounted for between 88% and 99% of the total internal absorbed dose received by the fish species. The activity of 210 Po in sea water from the study area was 0.9-2.2 mBq L -1 , yielding concentration factors for 210 Po in liver tissue in the range 3 x 103 to 100 x 103. No significant monophasic relationships were observed between the 210 Po results and the measured concentrations of the elements Cd, Cu, Fe, Mn, Zn and Pb, except that Pb and 210 Po were correlated (r = 0.511) in C. kumu. 33 refs., 4 tabs., 1 fig

Interaction Between Shelf Layout and Marketing Effectiveness and Its Impact on Optimizing Shelf Arrangements

NARCIS (Netherlands)

van Nierop, Erjen; Fok, Dennis; Franses, Philip Hans

2008-01-01

In this paper, we propose and operationalize a new method for optimizing shelf arrangements. We show that there are important dependencies between the layout of the shelf and stock-keeping unit (SKU) sales and marketing effectiveness. The importance of these dependencies is further shown by the

The evolution of a coupled ice shelf-ocean system under different climate states

Science.gov (United States)

Grosfeld, Klaus; Sandhäger, Henner

2004-07-01

Based on a new approach for coupled applications of an ice shelf model and an ocean general circulation model, we investigate the evolution of an ice shelf-ocean system and its sensitivity to changed climatic boundary conditions. Combining established 3D models into a coupled model system enabled us to study the reaction and feedbacks of each component to changes at their interface, the ice shelf base. After calculating the dynamics for prescribed initial ice shelf and bathymetric geometries, the basal mass balance determines the system evolution. In order to explore possible developments for given boundary conditions, an idealized geometry has been chosen, reflecting basic features of the Filchner-Ronne Ice Shelf, Antarctica. The model system is found to be especially sensitive in regions where high ablation or accretion rates occur. Ice Shelf Water formation as well as the build up of a marine ice body, resulting from accretion of marine ice, is simulated, indicating strong interaction processes. To improve consistency between modeled and observed ice shelf behavior, we incorporate the typical cycle of steady ice front advance and sudden retreat due to tabular iceberg calving in our time-dependent simulations. Our basic hypothesis is that iceberg break off is associated with abrupt crack propagation along elongated anomalies of the inherent stress field of the ice body. This new concept yields glaciologically plausible results and represents an auspicious basis for the development of a thorough calving criterion. Experiments under different climatic conditions (ocean warming of 0.2 and 0.5 °C and doubled surface accumulation rates) show the coupled model system to be sensitive especially to ocean warming. Increased basal melt rates of 100% for the 0.5 °C ocean warming scenario and an asymmetric development of ice shelf thicknesses suggest a high vulnerability of ice shelf regions, which represent pivotal areas between the Antarctic Ice Sheet and the Southern

Coordination: southeast continental shelf studies. Progress report

Energy Technology Data Exchange (ETDEWEB)

Menzel, D.W.

1981-02-01

The objectives are to identify important physical, chemical and biological processes which affect the transfer of materials on the southeast continental shelf, determine important parameters which govern observed temporal and spatial varibility on the continental shelf, determine the extent and modes of coupling between events at the shelf break and nearshore, and determine physical, chemical and biological exchange rates on the inner shelf. Progress in meeting these research objectives is presented. (ACR)

Water-stability of soil aggregates in relation to selected properties

International Nuclear Information System (INIS)

Mbagwu, J.S.C.; Bazzoffi, P.; Unamba Oparah, I.

1995-03-01

The stability of soil aggregates in water is an important soil physical property for evaluating the potential of agricultural soils to erode and elucidating the mechanisms of soil erosion. In this study we used aggregates from 15 surface soil samples in Italy to evaluate the influence of intrinsic soil physical, chemical and mineralogical properties on aggregates stability (AS). The aim was to develop a model for predicting AS from a subset of these soil properties. The index of stability used is the mean-weight diameter of water-stable aggregates (MWD). The model developed with soil physical properties alone explained just 42% of variance in MWD and predicted AS in only 20% of test soils. The model developed with mineralogical properties alone explained 70% of variance in MWD and predicted AS in 60% of the test soils. The chemical properties - based model explained 90% of variance in MWD and predicted AS in 80% of the test soils. The best-fit model was developed with soil properties from the physical, chemical and mineralogical subsets. It explained 98% of variance in MWD and predicted AS in 100% of the test soils. This model shows that the most important soil properties which influence the AS of these soils include ratio of total sand to clay, concentrations of iron oxide, magnesium oxide, organic matter, silica/alumina ratio, chlorite, feldspar and muscovite. This indicates that fairly good estimates of the relative stability of these aggregates in water and hence of their potential to erode, requires a knowledge of the physico-chemical and mineralogical properties. (author). 40 refs, 4 tabs

Active Risk Management and Banking Stability

NARCIS (Netherlands)

Silva Buston, C.F.

2013-01-01

Abstract: This paper analyzes the net impact of two opposing effects of active risk management at banks on their stability: higher risk-taking incentives and better isolation of credit supply from varying economic conditions. We present a model where banks actively manage their portfolio risk by

Shelf life of electronic/electrical devices

International Nuclear Information System (INIS)

Polanco, S.; Behera, A.K.

1993-01-01

This paper discusses inconsistencies which exist between various industry practices regarding the determination of shelf life for electrical and electronic components. New methodologies developed to evaluate the shelf life of electrical and electronic components are described and numerous tests performed at Commonwealth Edison Company's Central Receiving Inspection and Testing (CRIT) Facility are presented. Based upon testing and analysis using the Arrhenius methodology and typical materials used in the manufacturing of electrical and electronic components, shelf life of these devices was determined to be indefinite. Various recommendations to achieve an indefinite. Various recommendations to achieve an indefinite shelf life are presented to ultimately reduce inventory and operating costs at nuclear power plants

Hurricane Arthur and its effect on the short-term variability of pCO2 on the Scotian Shelf, NW Atlantic

Science.gov (United States)

Lemay, Jonathan; Thomas, Helmuth; Craig, Susanne E.; Burt, William J.; Fennel, Katja; Greenan, Blair J. W.

2018-04-01

The understanding of the seasonal variability of carbon cycling on the Scotian Shelf in the NW Atlantic Ocean has improved in recent years; however, very little information is available regarding its short-term variability. In order to shed light on this aspect of carbon cycling on the Scotian Shelf we investigate the effects of Hurricane Arthur, which passed the region on 5 July 2014. The hurricane caused a substantial decline in the surface water partial pressure of CO2 (pCO2), even though the Scotian Shelf possesses CO2-rich deep waters. High-temporal-resolution data of moored autonomous instruments demonstrate that there is a distinct layer of relatively cold water with low dissolved inorganic carbon (DIC) slightly above the thermocline, presumably due to a sustained population of phytoplankton. Strong storm-related wind mixing caused this cold intermediate layer with high phytoplankton biomass to be entrained into the surface mixed layer. At the surface, phytoplankton begin to grow more rapidly due to increased light. The combination of growth and the mixing of low DIC water led to a short-term reduction in the partial pressure of CO2 until wind speeds relaxed and allowed for the restratification of the upper water column. These hurricane-related processes caused a (net) CO2 uptake by the Scotian Shelf region that is comparable to the spring bloom, thus exerting a major impact on the annual CO2 flux budget.

Shelf life prediction of canned fried-rice using accelerated shelf life testing (ASLT) arrhenius method

Science.gov (United States)

Kurniadi, M.; Bintang, R.; Kusumaningrum, A.; Nursiwi, A.; Nurhikmat, A.; Susanto, A.; Angwar, M.; Triwiyono; Frediansyah, A.

2017-12-01

Research on shelf-life prediction of canned fried rice using Accelerated Shelf-life Test (ASLT) of Arrhenius model has been conducted. The aim of this research to predict shelf life of canned-fried rice products. Lethality value of 121°C for 15 and 20 minutes and Total Plate count methods are used to determine time and temperatures of sterilization process.Various storage temperatures of ASLT Arrhenius method were 35, 45 and 55°C during 35days. Rancidity is one of the derivation quality of canned fried rice. In this research, sample of canned fried rice is tested using rancidity value (TBA). TBA value was used as parameter which be measured once a week periodically. The use of can for fried rice without any chemical preservative is one of the advantage of the product, additionaly the use of physicalproperties such as temperature and pressure during its process can extend the shelf life and reduce the microbial contamination. The same research has never done before for fried rice as ready to eat meal. The result showed that the optimum conditions of sterilization process were 121°C,15 minutes with total plate count number of 9,3 × 101 CFU/ml. Lethality value of canned fried rice at 121°C,15 minutes was 3.63 minutes. The calculated Shelf-life of canned fried rice using Accelerated Shelf-life Test (ASLT) of Arrhenius method was 10.3 months.

Observations and a model of undertow over the inner continental shelf

Science.gov (United States)

Lentz, Steven J.; Fewings, Melanie; Howd, Peter; Fredericks, Janet; Hathaway, Kent

2008-01-01

Onshore volume transport (Stokes drift) due to surface gravity waves propagating toward the beach can result in a compensating Eulerian offshore flow in the surf zone referred to as undertow. Observed offshore flows indicate that wave-driven undertow extends well offshore of the surf zone, over the inner shelves of Martha’s Vineyard, Massachusetts, and North Carolina. Theoretical estimates of the wave-driven offshore transport from linear wave theory and observed wave characteristics account for 50% or more of the observed offshore transport variance in water depths between 5 and 12 m, and reproduce the observed dependence on wave height and water depth.During weak winds, wave-driven cross-shelf velocity profiles over the inner shelf have maximum offshore flow (1–6 cm s−1) and vertical shear near the surface and weak flow and shear in the lower half of the water column. The observed offshore flow profiles do not resemble the parabolic profiles with maximum flow at middepth observed within the surf zone. Instead, the vertical structure is similar to the Stokes drift velocity profile but with the opposite direction. This vertical structure is consistent with a dynamical balance between the Coriolis force associated with the offshore flow and an along-shelf “Hasselmann wave stress” due to the influence of the earth’s rotation on surface gravity waves. The close agreement between the observed and modeled profiles provides compelling evidence for the importance of the Hasselmann wave stress in forcing oceanic flows. Summer profiles are more vertically sheared than either winter profiles or model profiles, for reasons that remain unclear.

Interaction Between Shelf Layout and Marketing Effectiveness and Its Impact On Optimizing Shelf Arrangements

NARCIS (Netherlands)

J.E.M. van Nierop; D. Fok (Dennis); Ph.H.B.F. Franses (Philip Hans)

2006-01-01

textabstractAllocating the proper amount of shelf space to stock keeping units [SKUs] is an increasingly relevant and difficult topic for managers. Shelf space is a scarce resource and it has to be distributed across a larger and larger number of items. It is in particular important because the

Shelf life and safety concerns of bakery products--a review.

Science.gov (United States)

Smith, James P; Daifas, Daphne Phillips; El-Khoury, Wassim; Koukoutsis, John; El-Khoury, Anis

2004-01-01

Bakery products are an important part of a balanced diet and, today, a wide variety of such products can be found on supermarket shelves. This includes unsweetened goods (bread, rolls, buns, crumpets, muffins and bagels), sweet goods (pancakes, doughnuts, waffles and cookies) and filled goods (fruit and meat pies, sausage rolls, pastries, sandwiches, cream cakes, pizza and quiche). However, bakery products, like many processed foods, are subject to physical, chemical and microbiological spoilage. While physical and chemical spoilage limits the shelf life of low and intermediate moisture bakery products, microbiological spoilage by bacteria, yeast and molds is the concern in high moisture products i.e., products with a water activity (a(w)) > 0.85. Furthermore, several bakery products also have been implicated infoodborne illnesses involving Salmonella spp., Listeria monoctyogenes and Bacillus cereus, while Clostridium botulinum is a concern in high moisture bakery products packaged under modified atmospheres. This extensive review is divided into two parts. Part I focuses on the spoilage concerns of low, intermediate and high moisture bakery products while Part II focuses on the safety concerns of high moisture bakery products only. In both parts, traditional and novel methods of food preservation that can be used by the bakery industry to extend the shelf life and enhance the safety of products are discussed in detail.

Physico-chemical shelf-life indicators of meat from broilers given ...

African Journals Online (AJOL)

The objective of the study was to determine the effect of using Moringa oleifera leaf meal (MOLM) as an additive on physico-chemical shelf life indicators of meat from broilers. A total of 432 1-day-old chicks were randomly allocated to four treatments (TRT's). Water and feed was provided ad libitum. The feeding phases were ...