WorldWideScience

Sample records for sedimentation concentration technique

  1. Real-time measurements of suspended sediment concentration and particle size using five techniques

    Science.gov (United States)

    Felix, D.; Albayrak, I.; Abgottspon, A.; Boes, R. M.

    2016-11-01

    Fine sediments are important in the design and operation of hydropower plants (HPPs), in particular with respect to sediment management and hydro-abrasive erosion in hydraulic machines. Therefore, there is a need for reliable real-time measurements of suspended sediment mass concentration (SSC) and particle size distribution (PSD). The following instruments for SSC measurements were investigated in a field study during several years at the HPP Fieschertal in the Swiss Alps: (1) turbidimeters, (2) a Laser In-Situ Scattering and Trans- missometry instrument (LISST), (3) a Coriolis Flow and Density Meter (CFDM), (4) acoustic transducers, and (5) pressure sensors. LISST provided PSDs in addition to concentrations. Reference SSCs were obtained by gravimetrical analysis of automatically taken water samples. In contrast to widely used turbidimeters and the single-frequency acoustic method, SSCs obtained from LISST, the CFDM or the pressure sensors were less or not affected by particle size variations. The CFDM and the pressure sensors allowed measuring higher SSC than the optical or the acoustic techniques (without dilution). The CFDM and the pressure sensors were found to be suitable to measure SSC ≥ 2 g/l. In this paper, the measuring techniques, instruments, setup, methods for data treatment, and selected results are presented and discussed.

  2. Metallic Concentration in Karnaphuly Estuary Sediment Using Neutron Activation Analysis Technique

    International Nuclear Information System (INIS)

    Rahman, A.K.M.R.; Chakroborty, S.R.; Roy, P.K.; Dev, A.K.

    2013-01-01

    Thousands of tonnes of liquid waste, dirt and garbage from different mills and factories from Kaptai to Chittagong are dumped unhindered into the Karnaphuli River. Pollutants enter the river directly from urban sewerage and industrial waste discharges. Ships pollute waterways in many ways. All theses can contribute to the heavy and other metals of the water bodies. To find out concentration of different metallic elements and make a comparison with the world reference values twenty one surface sediment samples were collected from the different locations of Karnaphuly River near Chittagong city drainage outlet. Neutron Activation Analysis (NAA) technique was used for detecting the concentration qualitatively and quantitatively using the 3 MW TRIGA MARK II research reactor of Atomic Energy Research Establishment, Savar, Dhaka. Pearson correlation among the elements obtained using SPSS software. Three transitional metals Fe, Cr and Co, two alkali metals Rb and Na, two lanthanides La and Ce, and two metalloids As and Sb were determined. The concentrations of elements were compared with the world reference values. Some elements are found in elevated level. (author)

  3. Comparison of extraction techniques for isolation of steroid oestrogens in environmentally relevant concentrations from sediment

    Czech Academy of Sciences Publication Activity Database

    Sadílek, Jan; Spálovská, P.; Vrana, B.; Vávrová, M.; Maršálek, Blahoslav; Šimek, Z.

    2016-01-01

    Roč. 96, č. 11 (2016), s. 1022-1037 ISSN 0306-7319 Institutional support: RVO:67985939 Keywords : microwave - assisted extraction * estrogens * sediment Subject RIV: CB - Analytical Chemistry , Separation Impact factor: 1.208, year: 2016

  4. Estimation of suspended sediment concentration by acoustic ...

    African Journals Online (AJOL)

    concentration of sediments such as glass spheres or sand. However, the acoustic properties of natural sediments vary and depend on many parameters such as particle size, shape, mineralogy and distribution of those parameters in sample. Therefore, this study was conducted to determine the possibility of soil sediment ...

  5. Modeling sediment concentration of rill flow

    Science.gov (United States)

    Yang, Daming; Gao, Peiling; Zhao, Yadong; Zhang, Yuhang; Liu, Xiaoyuan; Zhang, Qingwen

    2018-06-01

    Accurate estimation of sediment concentration is essential to establish physically-based erosion models. The objectives of this study were to evaluate the effects of flow discharge (Q), slope gradient (S), flow velocity (V), shear stress (τ), stream power (ω) and unit stream power (U) on sediment concentration. Laboratory experiments were conducted using a 10 × 0.1 m rill flume under four flow discharges (2, 4, 8 and 16 L min-1), and five slope gradients (5°, 10°, 15°, 20° and 25°). The results showed that the measured sediment concentration varied from 87.08 to 620.80 kg m-3 with a mean value of 343.13 kg m-3. Sediment concentration increased as a power function with flow discharge and slope gradient, with R2 = 0.975 and NSE = 0.945. The sediment concentration was more sensitive to slope gradient than to flow discharge. The sediment concentration was well predicted by unit stream power (R2 = 0.937, NSE = 0.865), whereas less satisfactorily by flow velocity (R2 = 0.470, NSE = 0.539) and stream power (R2 = 0.773, NSE = 0.732). In addition, using the equations to simulate the measured sediment concentration of other studies, the result further indicated that slope gradient, flow discharge and unit stream power were good predictors of sediment concentration. In general, slope gradient, flow discharge and unit stream power seem to be the preferred predictors for estimating sediment concentration.

  6. Are conventional statistical techniques exhaustive for defining metal background concentrations in harbour sediments? A case study: The Coastal Area of Bari (Southeast Italy).

    Science.gov (United States)

    Mali, Matilda; Dell'Anna, Maria Michela; Mastrorilli, Piero; Damiani, Leonardo; Ungaro, Nicola; Belviso, Claudia; Fiore, Saverio

    2015-11-01

    Sediment contamination by metals poses significant risks to coastal ecosystems and is considered to be problematic for dredging operations. The determination of the background values of metal and metalloid distribution based on site-specific variability is fundamental in assessing pollution levels in harbour sediments. The novelty of the present work consists of addressing the scope and limitation of analysing port sediments through the use of conventional statistical techniques (such as: linear regression analysis, construction of cumulative frequency curves and the iterative 2σ technique), that are commonly employed for assessing Regional Geochemical Background (RGB) values in coastal sediments. This study ascertained that although the tout court use of such techniques in determining the RGB values in harbour sediments seems appropriate (the chemical-physical parameters of port sediments fit well with statistical equations), it should nevertheless be avoided because it may be misleading and can mask key aspects of the study area that can only be revealed by further investigations, such as mineralogical and multivariate statistical analyses. Copyright © 2015 Elsevier Ltd. All rights reserved.

  7. Heavy metal concentrations and toxicity in water and sediment from stormwater ponds and sedimentation tanks

    OpenAIRE

    Karlsson, Kristin; Viklander, Maria; Scholes, Lian N. L.; Revitt, D. Mike

    2010-01-01

    Sedimentation is a widely used technique in structural best management practices to remove pollutants from stormwater. However, concerns have been expressed about the environmental impacts that may be exerted by the trapped pollutants. This study has concentrated on stormwater ponds and sedimentation tanks and reports on the accumulated metal concentrations (Cd, Cr, Ni, Pb, and Zn) and the associated toxicity to the bacteria Vibrio fischeri. The metal concentrations are compared with guidelin...

  8. Metal and trace element concentration evaluation in sediment profiles of the TietÊ River, State Of SÃO Paulo, by INAA and ICP OES techniques

    Energy Technology Data Exchange (ETDEWEB)

    Soares, Josiane S., E-mail: josi.s@usp.br [Instituto de Pesquisas Tecnológicas do Estado de São Paulo (LAQ- CQuiM/IPT), São Paulo, SP (Brazil). Lab. de Análises Químicas; Rocha, Flavio R.; Fávaro, Déborah I. T., E-mail: defavaro@ipen.br [Instituto de Pesquisas Energéticas e Nucleares (LAN/IPEN/CNEN-SP), São Paulo, SP (Brazil). Lab. de Análise por Ativação Neutrônica

    2017-07-01

    The present study presents concentration results for heavy metals, major and trace elements, in two sediment cores collected along the Tietê River: Salto de Itu to Porto Feliz ( Core 4 at point T-5) and Laras to Anhembi (Core 6 at point T18). As, Ba, Br, Co, Cr, Cs, Hf, Rb, Sb, Sc, Ta, Th, U and Zn concentrations by Instrumental Neutron Activation Analysis (INAA) and Al, Ba, Cd, Co, Cr, Cu, Mn, Ni, Pb, Ti, V and Zn concentrations by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were determined. The enrichment factor (EF), to assess the presence of anthropogenic pollution sources, was calculated and showed FE > 1.5 values for As, Br, Cs, Hf, Rb, Ta, Th, U and Zn, confirming the anthropogenic contribution for these elements, in all fractions from both cores. As, Cd, Cr, Cu, Ni, Pb and Zn concentrations were compared to guideline values (TEL and PEL) from the Canadian Council of Ministers of the Environment (CCME) and adopted by the São Paulo State Environmental Company (CETESB) and concentration values between TEL and PEL were found, for all fractions from both cores, presenting good and or regular sediment quality classification, the worst being Core 6. (author)

  9. Metal and trace element concentration evaluation in sediment profiles of the TietÊ River, State Of SÃO Paulo, by INAA and ICP OES techniques

    International Nuclear Information System (INIS)

    Soares, Josiane S.; Rocha, Flavio R.; Fávaro, Déborah I. T.

    2017-01-01

    The present study presents concentration results for heavy metals, major and trace elements, in two sediment cores collected along the Tietê River: Salto de Itu to Porto Feliz ( Core 4 at point T-5) and Laras to Anhembi (Core 6 at point T18). As, Ba, Br, Co, Cr, Cs, Hf, Rb, Sb, Sc, Ta, Th, U and Zn concentrations by Instrumental Neutron Activation Analysis (INAA) and Al, Ba, Cd, Co, Cr, Cu, Mn, Ni, Pb, Ti, V and Zn concentrations by Inductively Coupled Plasma Optical Emission Spectrometry (ICP OES) were determined. The enrichment factor (EF), to assess the presence of anthropogenic pollution sources, was calculated and showed FE > 1.5 values for As, Br, Cs, Hf, Rb, Ta, Th, U and Zn, confirming the anthropogenic contribution for these elements, in all fractions from both cores. As, Cd, Cr, Cu, Ni, Pb and Zn concentrations were compared to guideline values (TEL and PEL) from the Canadian Council of Ministers of the Environment (CCME) and adopted by the São Paulo State Environmental Company (CETESB) and concentration values between TEL and PEL were found, for all fractions from both cores, presenting good and or regular sediment quality classification, the worst being Core 6. (author)

  10. Overflow Concentration and Sedimentation in Hoppers

    DEFF Research Database (Denmark)

    Hjelmager Jensen, Jacob; Saremi, Sina

    2014-01-01

    Sediment spillage from hopper overflow constitutes a source for sediment plumes and can also impact the turbidity of aquatic environments. The overflowing mixture is often different from the mixture pumped into the hopper (the inflow), because the mixture undergoes compositional transformation...... as a result of different timescales in the segregation of the various sediment fractions. The heavier constituents in a mixture will have had time to settle, and overflowing sediments are therefore primarily composed of the finer and lighter constituents, whose concentrations potentially exceed those...... sediment mixtures (i.e., polydispersions). Strictly speaking, these formulas have been validated for homogeneous and unenergetic mixtures only, but the hopper system fulfills these criteria reasonably well. A proper description of the compositional transformation during filling and subsequent overflow...

  11. Fluvial sediment transport: Analytical techniques for measuring sediment load

    International Nuclear Information System (INIS)

    2005-07-01

    Sediment transport data are often used for the evaluation of land surface erosion, reservoir sedimentation, ecological habitat quality and coastal sediment budgets. Sediment transport by rivers is usually considered to occur in two major ways: (1) in the flow as a suspended load and (2) along the bed as a bed load. This publication provides guidance on selected techniques for the measurement of particles moving in both modes in the fluvial environment. The relative importance of the transport mode is variable and depends on the hydraulic and sedimentary conditions. The potential user is directed in the selection of an appropriate technique through the presentation of operating principles, application guidelines and estimated costs. Techniques which require laboratory analysis are grab sample, pump sample, depth sample, point integrated and radioactive tracers. Techniques which will continuously record data are optical backscattering, nuclear transmission, single frequency acoustic and laser diffraction

  12. Heavy metal concentrations and toxicity in water and sediment from stormwater ponds and sedimentation tanks.

    Science.gov (United States)

    Karlsson, Kristin; Viklander, Maria; Scholes, Lian; Revitt, Mike

    2010-06-15

    Sedimentation is a widely used technique in structural best management practices to remove pollutants from stormwater. However, concerns have been expressed about the environmental impacts that may be exerted by the trapped pollutants. This study has concentrated on stormwater ponds and sedimentation tanks and reports on the accumulated metal concentrations (Cd, Cr, Ni, Pb, and Zn) and the associated toxicity to the bacteria Vibrio fischeri. The metal concentrations are compared with guidelines and the toxicity results are assessed in relation to samples for which metal concentrations either exceed or conform to these values. The water phase metal concentrations were highest in the ponds whereas the sedimentation tanks exhibited a distinct decrease towards the outlet. However, none of the water samples demonstrated toxicity even though the concentrations of Cu, Pb, and Zn exceeded the threshold values for the compared guidelines. The facilities with higher traffic intensities had elevated sediment concentrations of Cr, Cu, Ni, and Zn which increased towards the outlet for the sedimentation tanks in agreement with the highest percentage of fine particles. The sediments in both treatment facilities exhibited the expected toxic responses in line with their affinity for heavy metals but the role of organic carbon content is highlighted. Copyright 2010 Elsevier B.V. All rights reserved.

  13. Sediment acoustic index method for computing continuous suspended-sediment concentrations

    Science.gov (United States)

    Landers, Mark N.; Straub, Timothy D.; Wood, Molly S.; Domanski, Marian M.

    2016-07-11

    Suspended-sediment characteristics can be computed using acoustic indices derived from acoustic Doppler velocity meter (ADVM) backscatter data. The sediment acoustic index method applied in these types of studies can be used to more accurately and cost-effectively provide time-series estimates of suspended-sediment concentration and load, which is essential for informed solutions to many sediment-related environmental, engineering, and agricultural concerns. Advantages of this approach over other sediment surrogate methods include: (1) better representation of cross-sectional conditions from large measurement volumes, compared to other surrogate instruments that measure data at a single point; (2) high temporal resolution of collected data; (3) data integrity when biofouling is present; and (4) less rating curve hysteresis compared to streamflow as a surrogate. An additional advantage of this technique is the potential expansion of monitoring suspended-sediment concentrations at sites with existing ADVMs used in streamflow velocity monitoring. This report provides much-needed standard techniques for sediment acoustic index methods to help ensure accurate and comparable documented results.

  14. Review of sediment stabilisation techniques

    International Nuclear Information System (INIS)

    1992-01-01

    The best sites for tidal power schemes are found in estuaries with high tidal ranges which have complex ecosystems and include a wide and diverse range of habitats. If the tidal power is to be developed, therefore, it is important to determine the likely effect on the environment and any ameliorative measures which may be necessary. One possible change is likely to be the erosion of material from the bed or shoreline of the estuary, and possibly the adjacent coast. This is of particular concern if intertidal sandflats, mudflats and saltmarsh are affected, as these are important wildlife habitats. Moreover, largescale movement of sediments would be undesirable. Results of a desk study of methods of preventing the erosion of sediment deposits in or near an estuary in the conditions that may occur following the construction of a tidal power barrage are presented. (author)

  15. Lutz's spontaneous sedimentation technique and the paleoparasitological analysis of sambaqui (shell mound sediments

    Directory of Open Access Journals (Sweden)

    Morgana Camacho

    2013-04-01

    Full Text Available Parasite findings in sambaquis (shell mounds are scarce. Although the 121 shell mound samples were previously analysed in our laboratory, we only recently obtained the first positive results. In the sambaqui of Guapi, Rio de Janeiro, Brazil, paleoparasitological analysis was performed on sediment samples collected from various archaeological layers, including the superficial layer as a control. Eggs of Acanthocephala, Ascaridoidea and Heterakoidea were found in the archaeological layers. We applied various techniques and concluded that Lutz's spontaneous sedimentation technique is effective for concentrating parasite eggs in sambaqui soil for microscopic analysis.

  16. Lutz's spontaneous sedimentation technique and the paleoparasitological analysis of sambaqui (shell mound) sediments

    Science.gov (United States)

    Camacho, Morgana; Pessanha, Thaíla; Leles, Daniela; Dutra, Juliana MF; Silva, Rosângela; de Souza, Sheila Mendonça; Araujo, Adauto

    2013-01-01

    Parasite findings in sambaquis (shell mounds) are scarce. Although the 121 shell mound samples were previously analysed in our laboratory, we only recently obtained the first positive results. In the sambaqui of Guapi, Rio de Janeiro, Brazil, paleoparasitological analysis was performed on sediment samples collected from various archaeological layers, including the superficial layer as a control. Eggs of Acanthocephala, Ascaridoidea and Heterakoidea were found in the archaeological layers. We applied various techniques and concluded that Lutz's spontaneous sedimentation technique is effective for concentrating parasite eggs in sambaqui soil for microscopic analysis. PMID:23579793

  17. Entrainment at a sediment concentration interface in turbulent channel flow

    Science.gov (United States)

    Salinas, Jorge; Shringarpure, Mrugesh; Cantero, Mariano; Balachandar, S.

    2016-11-01

    In this work we address the role of turbulence on entrainment at a sediment concentration interface. This process can be conceived as the entrainment of sediment-free fluid into the bottom sediment-laden flow, or alternatively, as the entrainment of sediment into the top sediment-free flow. We have performed direct numerical simulations for fixed Reynolds and Schmidt numbers while varying the values of Richardson number and particle settling velocity. The analysis performed shows that the ability of the flow to pick up a given sediment size decreases with the distance from the bottom, and thus only fine enough sediment particles are entrained across the sediment concentration interface. For these cases, the concentration profiles evolve to a final steady state in good agreement with the well-known Rouse profile. The approach towards the Rouse profile happens through a transient self-similar state. Detailed analysis of the three dimensional structure of the sediment concentration interface shows the mechanisms by which sediment particles are lifted up by tongues of sediment-laden fluid with positive correlation between vertical velocity and sediment concentration. Finally, the mixing ability of the flow is addressed by monitoring the center of mass of the sediment-laden layer. With the support of ExxonMobil, NSF, ANPCyT, CONICET.

  18. Acoustic measuring techniques for suspended sediment

    Science.gov (United States)

    Gruber, P.; Felix, D.; Storti, G.; Lattuada, M.; Fleckenstein, P.; Deschwanden, F.

    2016-11-01

    Acoustic signals can be used in various ways for suspended sediment monitoring. One possibility which lends itself particularly well in the context of hydropower plants (HPPs), is to use installations for acoustic discharge measurement (ADM). Such installations already exist at waterways of many HPPs. Similar to certain turbidimeters, the attenuation of the forward scattered signal travelling through the water-sediment mixture is correlated with suspended sediment concentration (SSC). This correlation can be based on reference SSCs, e.g. from gravimetric analyses of bottle samples. Without the need of additional sensors and practically maintenance-free, this method is used successfully in the HPP Fieschertal to warn the HPP operator of high SSC to prevent excessive turbine abrasion. Acoustic methods and systems that allow for estimating both SSC and particle size distribution (PSD) are under development. The simultaneous determination of SSC and PSD is not possible using a single frequency. Therefore, multi-frequency approaches are investigated for generally scattered signals. When backscattered signals are used, a stronger frequency dependency can be exploited. However, the reliable simultaneous determination of particle size (and distribution) and concentration is still a major challenge due to a low signal-to-noise ratio and an ill- posed problem of estimating concentration and size from recorded signals. The optimal setup configuration (angles, frequencies) for such a system is not unique and further investigations are recommended.

  19. Influence of Temperature and Ion Concentration on Sedimentation ...

    African Journals Online (AJOL)

    ADOWIE PERE

    2017-12-16

    Dec 16, 2017 ... Rate data of sedimentation is useful in the design of sedimentation tanks and in modeling two-phase flow operations (Obunwo and Iboroma,. 2015). Mathematical models such as those by Stokes and. Vesilind respectively describe sedimentation of particles in dilute and concentrated suspension media.

  20. Metal concentrations in urban riparian sediments along an urbanization gradient

    Science.gov (United States)

    Daniel J. Bain; Ian D. Yesilonis; Richard V. Pouyat

    2012-01-01

    Urbanization impacts fluvial systems via a combination of changes in sediment chemistry and basin hydrology. While chemical changes in urban soils have been well characterized, similar surveys of riparian sediments in urbanized areas are rare. Metal concentrations were measured in sediments collected from riparian areas across the urbanization gradient in Baltimore, MD...

  1. Dynamics of suspended sediment concentration, flow discharge and sediment particle size interdependency to identify sediment source

    Science.gov (United States)

    Sadeghi, Seyed Hamidreza; Singh, Vijay P.

    2017-11-01

    Spatiotemporal behavior of sediment yield is a key for proper watershed management. This study analyzed statistical characteristics and trends of suspended sediment concentration (SCS), flow discharge (FD) and sediment particle sizes using data from 24 gage stations scattered throughout the United States. Analysis showed significant time- and location-specific differences of these variables. The median values of SSC, FD and percentage of particle sizes smaller than 63 μm (P63) for all 24 gage stations were found to be 510.236 mg l-1 (right skewed), 45.406 m3 s-1 (left skewed) and 78.648% (right skewed), respectively. Most of the stations exhibited significant trends (P practices which may call for local or regional planning based on natural (i.e., precipitation amount, type and erosivity, watershed area, and soil erodibility) and human-affected (i.e., land use and hydraulic structures and water resources management) factors governing the study variables.

  2. High concentration suspended sediment measurments using acontinuous fiber optic in-stream transmissometer

    Energy Technology Data Exchange (ETDEWEB)

    Campbell, Chris G.; Laycak, Danny T.; Hoppes, William; Tran,Nguyen T.; Shi, Frank G.

    2004-05-26

    Suspended sediment loads mobilized during high flow periods in rivers and streams are largely uncharacterized. In smaller and intermittent streams, a large storm may transport a majority of the annual sediment budget. Therefore monitoring techniques that can measure high suspended sediment concentrations at semi-continuous time intervals are needed. A Fiber optic In-stream Transmissometer (FIT) is presented for continuous measurement of high concentration suspended sediment in storm runoff. FIT performance and precision were demonstrated to be reasonably good for suspended sediment concentrations up to 10g/L. The FIT was compared to two commercially available turbidity devices and provided better precision and accuracy at both high and low concentrations. Both turbidity devices were unable to collect measurements at concentrations greater than 4 g/L. The FIT and turbidity measurements were sensitive to sediment particle size. Particle size dependence of transmittance and turbidity measurement poses the greatest problem for calibration to suspended sediment concentration. While the FIT was demonstrated to provide acceptable measurements of high suspended sediment concentrations, approaches to real-time suspended sediment detection need to address the particle size dependence in concentration measurements.

  3. Concentrations of metals in river sediment and wetland vegetations ...

    African Journals Online (AJOL)

    Levels of metals were determined in river sediment, rice and sugarcane juice from Lake Victoria basin where small-scale gold processing activities are carried out to assess levels of contamination. Concentrations of metals in river sediments were generally high in areas that were closest to gold ore processing sites.

  4. Trace elements in lake sediments measured by the PIXE technique

    International Nuclear Information System (INIS)

    Gatti, Luciana V.; Mozeto, Antonio A.; Artaxo, Paulo

    1999-01-01

    Lakes are ecosystems where there is a great potential of metal accumulation in sediments due to their depositional characteristics. Total concentration of trace elements was measured on a 50 cm long sediment core from the Infernao Lake, that is an oxbow lake of the Moji-Guacu River basin, in the state of Sao Paulo, Brazil. Dating of the core shows up to 180 yrs old sediment layers. The use of the PIXE technique for elemental analysis avoids the traditional acid digestion procedure common in other techniques. The multielemental characteristic of PIXE allows a simultaneous determination of about 20 elements in the sediment samples, such as, Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Rb, Sr, Zr, Ba, and Pb. Average values for the elemental composition were found to be similar to the bulk crustal composition. The lake flooding pattern strongly influences the time series of the elemental profiles. Factor analysis of the elemental variability shows five factors. Two of the factors represent the mineralogical matrix, and others represent the organic component, a factor with lead, and another loaded with chromium. The mineralogical component consists of elements such as, Fe, Al, V, Ti, Mn, Ni, K, Zr, Sr, Cu and Zn. The variability of Si is explained by two distinct factors, because it is influenced by two different sources, aluminum-silicates and quartz, and the effect of inundation are different for each other. The organic matter is strongly associated with calcium, and also bounded with S, Zn, Cu and P. Lead and chromium appears as separated factors, although it is not clear the evidences for their anthropogenic origin. The techniques developed for sample preparation and PIXE analysis was proven as advantageous and provided very good reproducibility and accuracy

  5. Application of multivariate techniques in the optimization of a procedure for the determination of bioavailable concentrations of Se and As in estuarine sediments by ICP OES using a concomitant metals analyzer as a hydride generator.

    Science.gov (United States)

    Lopes, Watson da Luz; Santelli, Ricardo Erthal; Oliveira, Eliane Padua; de Carvalho, Maria de Fátima Batista; Bezerra, Marcos Almeida

    2009-10-15

    A procedure has been developed for the determination of bioavailable concentrations of selenium and arsenic in estuarine sediments employing inductively coupled plasma optical emission spectrometry (ICP OES) using a concomitant metals analyzer device to perform hydride generation. The optimization of hydride generation was done in two steps: using a two-level factorial design for preliminary evaluation of studied factors and a Doehlert design to assess the optimal experimental conditions for analysis. Interferences of transition metallic ions (Cd(2+), Co(2+), Cu(2+), Fe(3+) and Ni(2+)) to selenium and arsenic signals were minimized by using higher hydrochloric acid concentrations. In this way, the procedure allowed the determination of selenium and arsenic in sediments with a detection limit of 25 and 30 microg kg(-1), respectively, assuming a 50-fold sample dilution (0.5 g sample extraction to 25 mL sample final volume). The precision, expressed as a relative standard deviation (% RSD, n=10), was 0.2% for both selenium and arsenic in 200 microg L(-1) solutions, which corresponds to 10 microg g(-1) in sediment samples after acid extraction. Applying the proposed procedure, a linear range of 0.08-10 and 0.10-10 microg g(-1) was obtained for selenium and arsenic, respectively. The developed procedure was validated by the analysis of two certified reference materials: industrial sludge (NIST 2782) and river sediment (NIST 8704). The results were in agreement with the certified values. The developed procedure was applied to evaluate the bioavailability of both elements in four sediment certified reference materials, in which there are not certified values for bioavailable fractions, and also in estuarine sediment samples collected in several sites of Guanabara Bay, an impacted environment in Rio de Janeiro, Brazil.

  6. Regional estimation of extreme suspended sediment concentrations using watershed characteristics

    Science.gov (United States)

    Tramblay, Yves; Ouarda, Taha B. M. J.; St-Hilaire, André; Poulin, Jimmy

    2010-01-01

    SummaryThe number of stations monitoring daily suspended sediment concentration (SSC) has been decreasing since the 1980s in North America while suspended sediment is considered as a key variable for water quality. The objective of this study is to test the feasibility of regionalising extreme SSC, i.e. estimating SSC extremes values for ungauged basins. Annual maximum SSC for 72 rivers in Canada and USA were modelled with probability distributions in order to estimate quantiles corresponding to different return periods. Regionalisation techniques, originally developed for flood prediction in ungauged basins, were tested using the climatic, topographic, land cover and soils attributes of the watersheds. Two approaches were compared, using either physiographic characteristics or seasonality of extreme SSC to delineate the regions. Multiple regression models to estimate SSC quantiles as a function of watershed characteristics were built in each region, and compared to a global model including all sites. Regional estimates of SSC quantiles were compared with the local values. Results show that regional estimation of extreme SSC is more efficient than a global regression model including all sites. Groups/regions of stations have been identified, using either the watershed characteristics or the seasonality of occurrence for extreme SSC values providing a method to better describe the extreme events of SSC. The most important variables for predicting extreme SSC are the percentage of clay in the soils, precipitation intensity and forest cover.

  7. Predicting pollutant concentrations in the water column during dredging operations: Implications for sediment quality criteria

    International Nuclear Information System (INIS)

    Wasserman, Julio Cesar; Wasserman, Maria Angélica V.; Barrocas, Paulo Rubens G.; Almeida, Aline Mansur

    2016-01-01

    The development of new dredging techniques that can reduce, or at least predict, the environmental impacts, is in high demand by governments in developing countries. In the present work, a new methodology was developed, to evaluate the level of metals contamination (i.e. cadmium, lead and zinc) of the water column, during a dredging operation. This methodology was used to evaluate the impacts of the construction of a new maritime terminal in Sepetiba Bay, Brazil. The methodology quantifies the amount of resuspended sediments and calculates the expected contaminants concentrations in the water column. The results indicated that sediment quality criteria were not compatible with water quality criteria, because the dredging of contaminated sediments does not necessarily yield contaminated water. It is suggested that the use of sediment quality criteria for dredging operations might be abandoned, and the methodology presented in this study applied to assess dredging's environmental impacts, predicting water contamination levels. - Graphical abstract: A graphic model showing transference of contaminants from the sediments to the water column. The dark sediment area represents the dredged sediments and the arrows emerging from them represent the resuspended sediments affecting the water column. - Highlights: •Developing countries demand for new dredging projects. •A new model evaluates concentrations of metals in the water, caused by dredging. •The model shows that water and sediment quality criteria are not compatible. •Local hydrodynamics have a strong influence on the contamination of the water. •Management of dredging operations reduces environmental contamination.

  8. Influence of temperature and ion concentration on sedimentation ...

    African Journals Online (AJOL)

    TSP sedimentation order also ranged between 0.58 and 1.31 at constant phosphate ions concentration and between 1.55 and 1.81 at constant strontium ions concentration. ... Data may be employed as additional design information for modeling physiochemical phosphate removal in water treatment technology. Keywords: ...

  9. Sediment tolerance mechanisms identified in sponges using advanced imaging techniques

    Directory of Open Access Journals (Sweden)

    Brian W. Strehlow

    2017-11-01

    Full Text Available Terrestrial runoff, resuspension events and dredging can affect filter-feeding sponges by elevating the concentration of suspended sediments, reducing light intensity, and smothering sponges with sediments. To investigate how sponges respond to pressures associated with increased sediment loads, the abundant and widely distributed Indo-Pacific species Ianthella basta was exposed to elevated suspended sediment concentrations, sediment deposition, and light attenuation for 48 h (acute exposure and 4 weeks (chronic exposure. In order to visualise the response mechanisms, sponge tissue was examined by 3D X-ray microscopy and scanning electron microscopy (SEM. Acute exposures resulted in sediment rapidly accumulating in the aquiferous system of I. basta, although this sediment was fully removed within three days. Sediment removal took longer (>2 weeks following chronic exposures, and I. basta also exhibited tissue regression and a smaller aquiferous system. The application of advanced imaging approaches revealed that I. basta employs a multilevel system for sediment rejection and elimination, containing both active and passive components. Sponges responded to sediment stress through (i mucus production, (ii exclusion of particles by incurrent pores, (iii closure of oscula and pumping cessation, (iv expulsion of particles from the aquiferous system, and (v tissue regression to reduce the volume of the aquiferous system, thereby entering a dormant state. These mechanisms would result in tolerance and resilience to exposure to variable and high sediment loads associated with both anthropogenic impacts like dredging programs and natural pressures like flood events.

  10. Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil

    International Nuclear Information System (INIS)

    Bostelmann, Eleine

    2006-01-01

    The present study chemically characterized sediment samples from the Billings reservoir, Rio Grande tributary, in the Metropolitan region of Sao Paulo, by determining metal concentration and other elements of interest. The chosen chemical parameters for this characterization were Aluminum, Arsenic, Barium, Cadmium, Copper, Chromium, Iron, Lead, Manganese, Mercury, Nickel, Selenium and Zinco. These parameters are also used in the water quality index, with the exception of Selenium. The concentrations were determined through different analytical techniques such as atomic absorption spectrometry (FAAS, GFAAS and CVAAS), optical emission spectrometry (ICP OES) and neutron activation analysis. These analytical methodologies were assessed for precision, accuracy and detection and/or quantification limits for the sediment elements in question. Advantages and disadvantages of each technique for each element and its concentration were also discussed. From these assessments the most adequate technique was selected for the routine analysis of sediment samples for each element concentration determination. This assessment verified also that digestion in a closed microwave system with nitric acid is efficient for the evaluation of extracted metals of environmental interest. The analytical techniques chosen were equally efficient for metals determination. In the case of Cd and Pb, the FAAS technique was selected due to better results than ICP OES, as it does not present matrix interference. The concentration values obtained for metals As, Cd, Cu, Cr, Hg, Ni, Pb and Zn in the sediment samples were compared to Canadian Council of Minister of the Environment (CCME) TEL and PEL values. (author)

  11. Assessment of metal concentrations in sediment samples from Billings reservoir, Rio Grande tributary, Sao Paulo, Brazil

    International Nuclear Information System (INIS)

    Bostelmann, Eleine

    2006-01-01

    The present study chemically characterized sediment samples from the Billings reservoir, Rio Grande tributary, in the Metropolitan region of Sao Paulo, by determining metal concentration and other elements of interest. The chosen chemical parameters for this characterization were Aluminum, Arsenic, Barium, Cadmium, Copper, Chromium, Iron, Lead, Manganese, Mercury, Nickel, Selenium and Zinc. These parameters are also used in the water quality index, with the exception of Selenium. The concentrations were determined through different analytical techniques such as atomic absorption spectrometry (FAAS, GFAAS and CVAAS), optical emission spectrometry (ICP OES) and neutron activation analysis. These analytical methodologies were assessed for precision, accuracy and detection and/or quantification limits for the sediment elements in question. Advantages and disadvantages of each technique for each element and its concentration were also discussed. From these assessment the most adequate technique was selected for the routine analysis of sediment samples for each element concentration determination. This assessment verified also that digestion in a closed microwave system with nitric acid is efficient for the evaluation of extracted metals of environmental interest. The analytical techniques chosen were equally efficient for metals determination. In the case of Cd and Pb, the FAAS technique was selected due to better results than ICP OES, as it does not present matrix interference. The concentration values obtained for metals As, Cd, Cu, Cr, Hg, Ni, Pb and Zn in the sediment samples were compared to Canadian Council of Minister of the Environment (CCME) TEL and PEL values. (author)

  12. Aromatic hydrocarbon concentrations in sediments of Placentia Bay, Newfoundland

    International Nuclear Information System (INIS)

    Kiceniuk, J.W.

    1992-01-01

    A study was conducted to examine the potential for contamination of recent sediments with polycyclic aromatic hydrocarbons due to tanker and refinery activity in Placentia Bay, Newfoundland, an area without large local anthropogenic sources of aromatics. Sediment samples were taken from the vicinity of the Come By Chance refinery, Woody Island, Wild Cove, and Port Royal Arm, all in the north end of the bay. The samples were extracted by two methods, dichloromethane extraction of dried sediment for determination of total aromatic hydrocarbon content and hexane extraction of wet sediment for estimation of the bioavailability of hydrocarbons and determination of more volatile compounds. Class analysis of aromatic hydrocarbons was conducted on a NH 2 column with detection at 255 nm. Total concentrations of di-tricyclic aromatics were highest at the Woody Island site (0.6 μg/g). The sediments from the Come By Chance site, Wild Cove, and Port Royal Arm sediments contained 0.3, 0.1, and 0.2 μg/g respectively. The hexane extracts from Come By Chance were lowest in di-tricyclic aromatics (0.007 μg/g), with the other sites being equal in concentration (0.01 μg/g). It is evident from the study that aromatic hydrocarbon concentrations in Placentia Bay are elevated in some parts of the bay in the absence of local combustion sources, and that the most likely source is petroleum. 12 refs., 5 figs., 2 tabs

  13. Sedimentation Characteristics of Kaolin and Bentonite in Concentrated Solutions

    Directory of Open Access Journals (Sweden)

    Abdulah Obut

    2005-11-01

    Full Text Available The sedimentation characteristics of two clays, namely kaolinite and bentonite, were determinated at high clay (5 % wt/vol and electrolyte (1 N concentrations using various inorganic-organic compounds. It was observed that the settling behaviour of kaolinite (1:1 clay and montmorillonite (2:1 clay is quite different due to the structural differences between these minerals. Although, similar initial settling rates and final sediment volumes were obtained after 24 hours of settling time for kaolin suspensions, the corresponding rates and volumes for bentonite suspensions varied greatly with the used chemical compound. According to the experimental results, a further intensive theoretical and experimental investigation is needed to reveal the mechanism underlying the sedimentation characteristics of clay minerals at high clay and electrolyte concentrations.

  14. Evaluating chemical extraction techniques for the determination of uranium oxidation state in reduced aquifer sediments

    Science.gov (United States)

    Stoliker, Deborah L.; Campbell, Kate M.; Fox, Patricia M.; Singer, David M.; Kaviani, Nazila; Carey, Minna; Peck, Nicole E.; Barger, John R.; Kent, Douglas B.; Davis, James A.

    2013-01-01

    Extraction techniques utilizing high pH and (bi)carbonate concentrations were evaluated for their efficacy in determining the oxidation state of uranium (U) in reduced sediments collected from Rifle, CO. Differences in dissolved concentrations between oxic and anoxic extractions have been proposed as a means to quantify the U(VI) and U(IV) content of sediments. An additional step was added to anoxic extractions using a strong anion exchange resin to separate dissolved U(IV) and U(VI). X-ray spectroscopy showed that U(IV) in the sediments was present as polymerized precipitates similar to uraninite and/or less ordered U(IV), referred to as non-uraninite U(IV) species associated with biomass (NUSAB). Extractions of sediment containing both uraninite and NUSAB displayed higher dissolved uranium concentrations under oxic than anoxic conditions while extractions of sediment dominated by NUSAB resulted in identical dissolved U concentrations. Dissolved U(IV) was rapidly oxidized under anoxic conditions in all experiments. Uraninite reacted minimally under anoxic conditions but thermodynamic calculations show that its propensity to oxidize is sensitive to solution chemistry and sediment mineralogy. A universal method for quantification of U(IV) and U(VI) in sediments has not yet been developed but the chemical extractions, when combined with solid-phase characterization, have a narrow range of applicability for sediments without U(VI).

  15. Metal concentrations in intertidal water and surface sediment along ...

    African Journals Online (AJOL)

    2017-01-01

    Jan 1, 2017 ... The higher metal concentrations reported in sediment suggested that both ... the condition of the water column and health of benthic marine ... and fish processing facilities are situated on the western side of ... ated approximately 20 km north of Cape Town. .... caused such levels of metal input to the system.

  16. Understanding coastal morphodynamic patterns from depth-averaged sediment concentration

    NARCIS (Netherlands)

    Ribas, F.; Falques, A.; de Swart, H. E.; Dodd, N.; Garnier, R.; Calvete, D.

    This review highlights the important role of the depth-averaged sediment concentration (DASC) to understand the formation of a number of coastal morphodynamic features that have an alongshore rhythmic pattern: beach cusps, surf zone transverse and crescentic bars, and shoreface-connected sand

  17. Review of sediment stabilisation techniques. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1992-12-31

    The best sites for tidal power schemes are found in estuaries with high tidal ranges which have complex ecosystems and include a wide and diverse range of habitats. If the tidal power is to be developed, therefore, it is important to determine the likely effect on the environment and any ameliorative measures which may be necessary. One possible change is likely to be the erosion of material from the bed or shoreline of the estuary, and possibly the adjacent coast. This is of particular concern if intertidal sandflats, mudflats and saltmarsh are affected, as these are important wildlife habitats. Moreover, largescale movement of sediments would be undesirable. Results of a desk study of methods of preventing the erosion of sediment deposits in or near an estuary in the conditions that may occur following the construction of a tidal power barrage are presented. (author).

  18. Characterization of marine sediments using analytical techniques

    International Nuclear Information System (INIS)

    Garcia-Rosales, G.; Longoria-Gandara, L.C.

    2011-01-01

    This study deals with the characterization of a marine sediments profile from the Gulf of Tehuantepec, Mexico. Ten sediment samples obtained from a core of 18.3 m of length were analysed. Although there have been numerous marine sediments studies carried out in Mexico, more are needed to better understand the sea floor formation. Crystallographic, morphologic, physical, chemical and gamma ray activity analysis were carried out on the samples. The analysis results showed a decrease in organic matter content as a function of sea depth; this value is related to the specific surface area. Some hazardous materials as Cr, Mn, Ni, Sr and Hg were also identified by PIXE in some samples, probably due to anthropogenic activity. The presence of uranium a naturally occurring element was found in all the samples, suggesting a migration through all materials of strata, radioactive elements such as 226 Ra, 235 U, 212 Pb, 214 Pb, 228 Ac, 208 Ti, 214 Bi, 228 Ac and 40 K were detected. (author)

  19. Trace metal concentrations in tropical mangrove sediments, NE Brazil.

    Science.gov (United States)

    Miola, Brígida; Morais, Jáder Onofre de; Pinheiro, Lidriana de Souza

    2016-01-15

    Sediment cores were taken from the mangroves of the Coreaú River estuary off the northeast coast of Brazil. They were analyzed for grain size, CaCO3, organic matter, and trace metal (Cd, Pb, Zn, Cu, Al, and Fe) contents. Mud texture was the predominant texture. Levels of trace metals in surface sediments indicated strong influence of anthropogenic processes, and diagenetic processes controlled the trace metal enrichment of core sediments of this estuary. The positive relationships between trace metals and Al and Fe indicate that Cu, Zn, Pb, and Cd concentrations are associated mainly with Al and Fe oxy-hydroxides and have natural sources. Copyright © 2015 Elsevier Ltd. All rights reserved.

  20. Groundwater arsenic concentrations in Vietnam controlled by sediment age

    DEFF Research Database (Denmark)

    Postma, Dieke; Larsen, Flemming; Thai, Nguyen Thi

    2012-01-01

    Arsenic contamination of groundwater continues to threaten the health of millions of people in southeast Asia. The oxidation of organic carbon, coupled to the reductive dissolution of arsenic-bearing iron oxides, is thought to control the release of sediment-bound arsenic into groundwater. However......, the cause of the high spatial variability in groundwater arsenic concentrations—which can range from 5 to 500 μg l−1 within distances of a few kilometres—has been uncertain. Here, we combine measurements of sediment age, organic-matter reactivity and water chemistry at four locations along a cross......-section of the arsenic-contaminated Red River floodplain in Vietnam to determine the origin of variations in groundwater arsenic concentrations. The burial age of the aquifer sediments, determined using optical stimulated luminescence, ranged from 460 years near the course of the present-day river to 5,900 years...

  1. Elevated in-home sediment contaminant concentrations - the consequence of a particle settling-winnowing process from Hurricane Katrina floodwaters.

    Science.gov (United States)

    Ashley, Nicholas A; Valsaraj, Kalliat T; Thibodeaux, Louis J

    2008-01-01

    Sediment samples were collected from two homes which were flooded in the wake of Hurricane Katrina in August 2005. The samples were analyzed for trace metals and semi-volatile organic compounds using techniques based on established EPA methods. The data showed higher concentrations of some metals and semi-volatile organic pollutants than reported in previous outdoor sampling events of soils and sediments. The Lake Pontchartrain sediments became resuspended during the hurricane, and this material subsequently was found in the residential areas of New Orleans following levee breaches. The clay and silt particles appear to be selectively deposited inside homes, and sediment contaminant concentrations are usually greatest within this fraction. Re-entry advisories based on outdoor sample concentration results may have under-predicted the exposure levels to homeowners and first responders. All contaminants found in the sediment sampled in this study have their origin in the sediments of Lake Pontchartrain and other localized sources.

  2. The 210Pb technique for dating sediments, and some applications

    International Nuclear Information System (INIS)

    Eakins, J.D.

    1983-01-01

    The use of 210 Pb for dating sediment in time scale 100-150 years is described. Various methods of determination of 210 Pb concentration are reviewed and the problem of the initial 210 Pb concentration using two models for interpretation of data is discussed. (author)

  3. Using artificial soil sediment mixtures for calibrating fingerprinting techniques at catchment scale

    International Nuclear Information System (INIS)

    Torres Astorga, Romina; Martin, Osvaldo A.; Velasco, Ricardo Hugo; Santos-Villalobos, Sergio de los; Mabit, Lionel; Dercon, Gerd

    2016-01-01

    Soil erosion and related sediment transportation and deposition are key environmental problems in Central Argentina. Certain land use practices, such as intensive grazing, are considered particularly harmful in causing erosion and sediment mobilization. In our studied catchment, Sub Catchment Estancia Grande (630 hectares), 23 km north east from San Luis, characterized by erosive loess soils, we tested sediment source fingerprinting techniques to identify critical hot spots of land degradation, based on the concentration of 43 elements determined by Energy Dispersive X Ray Fluorescence (EDXRF).

  4. Heavy metals concentrations in coal and sediments from River ...

    African Journals Online (AJOL)

    The levels of some heavy metals such as; Mn, Cr, Cd, As, Ni, and Pb were analysed in coal and sediment samples from River Ekulu in Enugu, Coal City using Atomic Absorption Spectrophotometer (AAS) model Spectra-AA-10 variant. Mean concentrations of Mn (0.256-0.389mg/kg) and Cr (0.214-0.267 mg/kg) are high ...

  5. Radioisotope Concentration in Lake Sediments of Maracaibo, Venezuela

    International Nuclear Information System (INIS)

    Salas, A. Rangel; Viloria, T.; Sajo-Bohus, L.; Barros, H.; Greaves, E. D.; Palacios, D.

    2007-01-01

    Maracaibo Lake is one of the most important water basing and oil producing regions in Venezuela. Changes in the local environment have been monitored for chemical pollution in the past. For this study we selected a set of sediment samples collected in the shore and analyzed for its radioisotope content. Results show the gamma emitting isotopes distribution. Isotopes concentrations have been determined within the natural K, Th and U families

  6. New Technique for Speciation of Uranium in Sediments Following Acetate-Stimulated Bioremediation

    Energy Technology Data Exchange (ETDEWEB)

    2011-06-22

    Acetate-stimulated bioremediation is a promising new technique for sequestering toxic uranium contamination from groundwater. The speciation of uranium in sediments after such bioremediation attempts remains unknown as a result of low uranium concentration, and is important to analyzing the stability of sequestered uranium. A new technique was developed for investigating the oxidation state and local molecular structure of uranium from field site sediments using X-Ray Absorption Spectroscopy (XAS), and was implemented at the site of a former uranium mill in Rifle, CO. Glass columns filled with bioactive Rifle sediments were deployed in wells in the contaminated Rifle aquifer and amended with a hexavalent uranium (U(VI)) stock solution to increase uranium concentration while maintaining field conditions. This sediment was harvested and XAS was utilized to analyze the oxidation state and local molecular structure of the uranium in sediment samples. Extended X-Ray Absorption Fine Structure (EXAFS) data was collected and compared to known uranium spectra to determine the local molecular structure of the uranium in the sediment. Fitting was used to determine that the field site sediments did not contain uraninite (UO{sub 2}), indicating that models based on bioreduction using pure bacterial cultures are not accurate for bioremediation in the field. Stability tests on the monomeric tetravalent uranium (U(IV)) produced by bioremediation are needed in order to assess the efficacy of acetate-stimulation bioremediation.

  7. Estimation of suspended sediment concentration in rivers using acoustic methods.

    Science.gov (United States)

    Elçi, Sebnem; Aydin, Ramazan; Work, Paul A

    2009-12-01

    Acoustic Doppler current meters (ADV, ADCP, and ADP) are widely used in water systems to measure flow velocities and velocity profiles. Although these meters are designed for flow velocity measurements, they can also provide information defining the quantity of particulate matter in the water, after appropriate calibration. When an acoustic instrument is calibrated for a water system, no additional sensor is needed to measure suspended sediment concentration (SSC). This provides the simultaneous measurements of velocity and concentration required for most sediment transport studies. The performance of acoustic Doppler current meters for measuring SSC was investigated in different studies where signal-to-noise ratio (SNR) and suspended sediment concentration were related using different formulations. However, these studies were each limited to a single study site where neither the effect of particle size nor the effect of temperature was investigated. In this study, different parameters that affect the performance of an ADV for the prediction of SSC are investigated. In order to investigate the reliability of an ADV for SSC measurements in different environments, flow and SSC measurements were made in different streams located in the Aegean region of Turkey having different soil types. Soil samples were collected from all measuring stations and particle size analysis was conducted by mechanical means. Multivariate analysis was utilized to investigate the effect of soil type and water temperature on the measurements. Statistical analysis indicates that SNR readings ob tained from the ADV are affected by water temperature and particle size distribution of the soil, as expected, and a prediction model is presented relating SNR readings to SSC mea surements where both water temperature and sediment characteristics type are incorporated into the model. The coefficients of the suggested model were obtained using the multivariate anal ysis. Effect of high turbidity

  8. Microplastics in sediments: A review of techniques, occurrence and effects.

    Science.gov (United States)

    Van Cauwenberghe, Lisbeth; Devriese, Lisa; Galgani, François; Robbens, Johan; Janssen, Colin R

    2015-10-01

    Microplastics are omnipresent in the marine environment and sediments are hypothesized to be major sinks of these plastics. Here, over 100 articles spanning the last 50 year are reviewed with following objectives: (i) to evaluate current microplastic extraction techniques, (ii) to discuss the occurrence and worldwide distribution of microplastics in sediments, and (iii) to make a comprehensive assessment of the possible adverse effects of this type of pollution to marine organisms. Based on this review we propose future research needs and conclude that there is a clear need for a standardized techniques, unified reporting units and more realistic effect assessments. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Quantitative research for pollution levels in marine sediments of Ha Long Bay by nuclear technique

    International Nuclear Information System (INIS)

    Nguyen Quang Long; Tran Thi Tuyet Mai; Pham Ngoc Khai; Nguyen Trung Thanh; Nguyen Van Phuc; Doan Thuy Hau; Duong Van Thang; Ha Lan Anh; Vo Thi Anh; Nguyen Thi Thu Ha

    2013-01-01

    Under the theme of Quantitative study of pollution levels in marine sediments of Halong bay by nuclear techniques conducted from June 2011 to June 2013, the authors conducted monitoring, sediment samples collected in the bay below the sediment column at 8 locations, in which 7 columns located at the estuary near Tuan Chau Island and 1 column at the area near the harbor of Cam Pha. The column samples were taken to the laboratory, cut slices with a distance of 2 cm in the form of frozen and conduct tests of radioactive Pb-210 to determine the rate of sediment in the survey area. Evaluation results based on the method by determining 210 Pb, the sediment rate showed speed in the survey area ranged from 0.3 cm.a -1 to 1.2 cm.a -1 and an average of 1.0 cm.a -1 . The slices of sediment samples (110 samples) were analyzed heavy metals (KLN) and As elemental by ICP-MS method. These sediment sample also were analyzed for simultaneous determination of N and P and total organic carbon (TOC). Results showed that heavy metal concentrations and As is smaller than the value specified in the National Technical Regulation on Sediment Quality of Vietnam (QCVN), phosphorus concentration less than that can cause harmful effects, but the concentration of total nitrogen and organic carbon that may exceed be harmful as directed by Canadian standards (Persuad et al. 1992). The concentration data in the Halong bay sediment were processed by statistical software SPSS-18, results showed high correlation between the quality TOC, N, P, K and correlation the majority of KLN, this proves the origin of sediments is part of the natural soil components and parts (TOC, N, P, K) is due to the activity of human activity as well as by agricultural fertilizers. The average content of elements in sediments Halong be compared with other data published works of sediment Quang Ninh area, the results show the correlation figures are also high. However, the results of the analysis of KLN and As in Halong

  10. Distinguishing between natural and aquaculture-derived sediment concentrations of heavy metals in the Broughton Archipelago, British Columbia

    International Nuclear Information System (INIS)

    Sutherland, T.F.; Petersen, S.A.; Levings, C.D.; Martin, A.J.

    2007-01-01

    Marine sediment samples were collected in the Broughton Archipelago, British Columbia, to assess the use of a geochemical normalization technique in the identification of a chemical tracer of aquaculture waste material. Zinc and copper were suggested as tracers of feed pellets, while copper was considered an indicator of anti-foulant agents used on netpen systems. The sediment samples were analyzed for carbon, nitrogen, organic matter, water, trace-element, and free sulfide concentrations, and sediment grain-size distribution. Sediment texture analysis revealed a wide range of substrate types from sand to silty loam categories. Strong relationships between sediment texture, sediment porosity, and organic content were observed across both near-field and far-field stations. Excess zinc and copper sediment concentrations, identified using a lithium-normalization technique, were restricted to near-field sampling stations (0 and 30 m from netpen systems). The relationships between these metal tracers and organic content and sulfur concentrations were explored to account for variations in sediment concentrations of zinc and copper

  11. USING TURBIDITY DATA TO PREDICT SUSPENDED SEDIMENT CONCENTRATIONS: POSSIBILITIES, LIMITATIONS, AND PITFALLS

    Science.gov (United States)

    This talk will look at the relationships between turbidity and suspended sediment concentrations in a variety of geographic areas, geomorphic river types, and river sizes; and attempt to give guidance on using existing turbidity data to predict suspended sediment concentrations.

  12. Concentration Factors of Norm in Sediment of Cisadane River

    International Nuclear Information System (INIS)

    Agus Gindo S; Lubis, Erwansyah

    2008-01-01

    The Concentration factor (Cf) in sediment of Cisadane river was investigated. The surface water and sediment was sampling at Gunung Sindur area (down stream) until Teluk Naga area (up stream). The results indicated that Cf values of gross-α, gross-β, gross-th, gross-U, 40 K, 226 Ra and 228 Th were 830 ± 87, 1800 ± 290, 2150 ± 50, 1415 ± 41, 37 ± 1, 22 ± 5 and 115 ± 56 respectively. With these Cf values, the radiological impact from liquid effluent release to Cisadane river that contains NORM from industrial activities for agriculture and fishery pathways are able to predicted. This investigation still has to be continued for other radionuclides. (author)

  13. Evolution of the sedimentation technique for particle size distribution analysis

    International Nuclear Information System (INIS)

    Maley, R.

    1998-01-01

    After an introduction on the significance of particle size measurements, sedimentation methods are described, with emphasis on the evolution of the gravitational approach. The gravitational technique based on mass determination by X-ray adsorption allows fast analysis by automation and easy data handling, in addition to providing the accuracy required by quality control and research applications [it

  14. Uranium concentrations in sediments of the Suez Canal

    International Nuclear Information System (INIS)

    Ibrahiem, N.M.; Pimpl, M.

    1994-01-01

    Suez Canal bottom sediment samples have been analyzed by alpha-spectrometry for the measurement of uranium. This method is based on the extraction of uranium with trioctylphosphine oxide/cyclohexane (TOPO) followed by reextraction and separation on anion exchange resins, and finally electrodeposition. The α-activity of 238 U and 234 U were measured by surface barrier detectors, in Bq/kg dry weight. The obtained results were compared with concentrations determined by γ measurements. The results point to a state of disequilibrium between 238 U and RaeU (radium equivalent uranium) which is attributed to the escape of radon. (author)

  15. Alternative procedure to determine radionuclide concentrations for marine sediment dating

    International Nuclear Information System (INIS)

    Palacios, D; Sajo-Bohus, L.; Alfonso, J.; Perez, K.; Trujillo, M.

    2006-01-01

    The development of an alternative method to prepare and to measure marine sediment samples for dating purpose using high resolution gamma spectrometry is given. To calculate the 137 Cs and the supported and unsupported 210 Pb concentrations, cylindrical tablets subjected to different pressures were analyzed. Mass attenuation coefficients (MAC) were determined by our variant of the transmission method, the Bragg law (using MACs provided by the web program XCOM) and the method of average composition of the analyzed sediment samples. The differences between obtained results are smaller than the experimental error (10%). The influence of pressure and sediment mass on the MAC, mechanical stability of the sample, and self-absorption corrections for different gamma energies is studied. Optimal dimensions of the tablets were determined from considerations on the infinite thickness, minimum detectable activity, precision of results, radiation self-absorption and geometric efficiency. Based on the differential peak absorption analysis, through a relative efficiency curve, a new method to evaluate the existence of radioactive equilibrium between 226 Ra, 222 Rn and its progeny is given. Experimental error of the proposed methodology is evaluated, as well as accuracy, precision and detection limit. With the use of developed methodology, the 210 Pb, 226 Ra and 137 Cs activities in recent sediment samples from near shore of the Orinoco River Delta were determined. The results were comparable with the obtained by two of the most used methods, while precision is improved and radiation self-absorption in sample container is avoided since sample encapsulation is not required. (Full Text)

  16. Concentration of 60Co by marine organisms through sediments

    International Nuclear Information System (INIS)

    Nakahara, Motokazu; Koyanagi, Taku; Saiki, Masamichi

    1976-01-01

    Uptake of 60 Co absorbed on sea sands by benthic marine organisms was observed in laboratory experiments, since the radioactive cobalt released from nuclear power plants or other establishments into coastal seawater trends to be absorbed on sea sediments and also various kinds of marine organisms live in bottom sediments. Few kinds of flatfishes (Limanda spp.) and shrimp (Trachypenaeus curvirostris) were reared in aquariums contained seawater and sea sands which were highly contaminated with 60 Co previously, and whole body retention and distribution of radioactivity were measured on the organisms taken up from the aquariums occasionally by a scintillation counter. Uptake of 60 Co from ingested sea sands was also observed on the flatfishes administrating the contaminated sands orally. Concentration of 60 Co by the flatfishes reared in the sands was not significant while the shrimp showed high retention of the radioactivity. The food habit of shrimp which usually feeds on organic detritus with other small benthic organisms is different from that of flatfishes, one of the carnivorous, and considered to bring the difference on the pathway of radionuclides concentration. Assimilation of 60 Co via the digestive tract of flatfishes through the sands was estimated as about 10 per cent of the administrated radioactivity. (auth.)

  17. Prediction and forecast of Suspended Sediment Concentration (SSC) on the Upper Yangtze basin

    Science.gov (United States)

    Matos, José Pedro; Hassan, Marwan; Lu, Xixi; Franca, Mário J.

    2017-04-01

    Sediment transport in suspension may represent 90% or more of the global annual flux of sediment. For instance, more than 99% of the sediment supplied to the sea by the Yangtze River is suspended load. Suspended load is an important component for understanding channel dynamics and landscape evolution. Sediments transported in suspension are a major source of nutrients for aquatic organisms in riparian and floodplain habitats, and play a beneficial role acting as a sink in the carbon cycle. Excess of fine sediments may also have adverse effects. It can impair fish spawning by riverbed clogging, disturb foraging efficiency of hunting of river fauna, cause algae and benthos scouring, reduce or inhibit exchanges through the hyporheic region. Accumulation of fine sediments in reservoirs reduces storage capacity. Although fine sediment dynamics has been the focus of many studies, the current knowledge of sediment sources, transfer, and storage is inadequate to address fine sediment dynamics in the landscape. The theoretical derivation of a complete model for suspended sediment transport at the basin scale, incorporating small scale processes of production and transport, is hindered because the underlying mechanisms are produced at different non-similar scales. Availability of long-term reliable data on suspended sediment dynamics is essential to improve our knowledge on transport processes and to develop reliable sediment prediction models. Over the last 60 years, the Yangtze River Commission has been measuring the daily Suspended Sediment Concentration (SSC) at the Pingshan station. This dataset provides a unique opportunity to examine temporal variability and controls of fine sediment dynamics in the Upper Yangtze basin. The objective of this study is to describe temporal variation of fine sediment dynamics at the Pingshan station making use of the extensive sediment monitoring program undertaken at that location. We test several strategies of prediction and forecast

  18. Sedimentation rate and chronology of As and Zn in sediment of a recent former tin mining lake estimated using Pb-210 dating technique

    International Nuclear Information System (INIS)

    Zaharidah Abu Bakar; Ahmad Saat; Zaini Hamzah; Abdul Khalik Wood; Zaharudin Ahmad

    2011-01-01

    Sedimentation in lake occurred through run-off from the land surface and settles on the bottom lake. Past mining activities might enhance sedimentation process in the former tin mining lakes either through natural or human activities. Former tin mining lakes were suspected to have high sedimentation rate due undisturbed environment for almost 50 years. To estimate sedimentation rate and metals contamination in this lake, Pb-210 dating technique was used. Two sediments cores were sampled using gravity corer from a former tin mining lake then analyzed using alpha-spectrometry and Neutron Activation Analysis (NAA). From this study, the results showed the sedimentation rate for sediment cores S1 and S2 are 0.26 cm y -1 and 0.23 cmy -1 respectively. According to sediment chronological sequences, high concentrations of As and Zn in the upper layer indicated that human activities contributed to these metals contamination in the lake sediment. Sedimentation rate and metals contamination possibly due to recent anthropogenic activities around the lake such as human settlement, farming and agricultures activities since the ceased of mining activities a few decades ago. (author)

  19. Comparison of test specific sediment effect concentrations with marine sediment quality assessment guidelines

    International Nuclear Information System (INIS)

    Carr, R.S.; Biedenbach, J.M.; MacDonald, D.D.

    1995-01-01

    As part of NOAA's National Status and Trends (NS and T) Bioeffects Assessment program and studies conducted by the National Biological Service, numerous sediment quality assessment surveys have recently been conducted along the Atlantic and Gulf coasts of the US using the sea urchin (Arbacia punctulata) fertilization and embryological development tests with pore water. Additional toxicity tests were also conducted in conjunction with most of these studies. The areas that have been sampled include Boston harbor, Massachusetts; Charleston Harbor, Winyah Bay, and Savannah River, South Carolina; St. Simon Sound, Georgia; Biscayne Bay, Tampa Bay, Choctawhatchee Bay, Apalachicola Bay, St. Andrew Bay, and Pensacola Bay, Florida; Galveston Bay, Lavaca Bay, and Sabine Lake, Texas, and 200 stations in the vicinity of offshore oil and gas production platforms in the Gulf of Mexico. Sufficient data are now available from this series of surveys to calculate test specific sediment effect concentrations (SECs). Based on these recent studies, SECs were developed for the sea urchin porewater and amphipod tests and compared with existing marine sediment quality assessment guidelines

  20. [Comparison of techniques for coliform bacteria extraction from sediment of Xochimilco Lake, Mexico].

    Science.gov (United States)

    Fernández-Rendón, Carlos L; Barrera-Escorcia, Guadalupe

    2013-01-01

    The need to separate bacteria from sediment in order to appropriately count them has led to test the efficacy of different techniques. In this research, traditional techniques such as manual shaking, homogenization, ultrasonication, and surfactant are compared. Moreover, the possibility of using a set of enzymes (pancreatine) and an antibiotic (ampicillin) for sediment coliform extraction is proposed. Samples were obtained from Xochimilco Lake in Mexico City. The most probable number of coliform bacteria was determined after applying the appropriate separation procedure. Most of the techniques tested led to numbers similar to those of the control (manual shaking). Only with the use of ampicillin, a greater total coliform concentration was observed (Mann-Whitney, z = 2.09; p = 0.03). It is possible to propose the use of ampicillin as a technique for total coliform extraction; however, it is necessary to consider sensitivity of bacteria to the antibiotic.

  1. The Effect of Source Suspended Sediment Concentration on the Sediment Dynamics of a Macrotidal Creek and Salt Marsh

    Science.gov (United States)

    Poirier, E.; van Proosdij, D.; Milligan, T. G.

    2017-12-01

    Seasonal variability in the sediment dynamics of a Bay of Fundy tidal creek and salt marsh system was analyzed to better understand the ecomorphodynamics of a high suspended sediment concentration intertidal habitat. Data were collected over 62 tides for velocity, suspended sediment concentration, deposition, and grain size at four stations from the creek thalweg to the marsh surface. Five topographic surveys were also conducted throughout the 14-month study. Deposition rates per tide varied spatially from 56.4 g·m-2 at the creek thalweg to 15.3 g·m-2 at the marsh surface. Seasonal variations in deposition in the creek and marsh surface were from 38.0 g·m-2 to 97.7 g·m-2 and from 12.2 g·m-2 to 19.6 g·m-2 respectively. Deposition and erosion were greatest in late fall and winter. This seasonal change, led by higher suspended sediment concentrations, was observed in the creek and at the marsh bank but notably absent from the marsh edge and marsh surface. Sediments were predominantly deposited in floc form (76-83%). Because of high floc content, higher suspended sediment concentrations led to more rapid loss of sediment from suspension. With increasing sediment concentration, deposition increased in the tidal creek and at the marsh bank but not at the marsh edge or marsh surface. This suggests that in highly flocculated environments the water column clears fast enough that very little sediment remains in suspension when the water reaches the marsh and that the sediment concentration during marsh inundation is independent of the initial concentration in the creek.

  2. Computing time-series suspended-sediment concentrations and loads from in-stream turbidity-sensor and streamflow data

    Science.gov (United States)

    Rasmussen, Patrick P.; Gray, John R.; Glysson, G. Doug; Ziegler, Andrew C.

    2010-01-01

    Over the last decade, use of a method for computing suspended-sediment concentration and loads using turbidity sensors—primarily nephelometry, but also optical backscatter—has proliferated. Because an in- itu turbidity sensor is capa le of measuring turbidity instantaneously, a turbidity time series can be recorded and related directly to time-varying suspended-sediment concentrations. Depending on the suspended-sediment characteristics of the measurement site, this method can be more reliable and, in many cases, a more accurate means for computing suspended-sediment concentrations and loads than traditional U.S. Geological Survey computational methods. Guidelines and procedures for estimating time s ries of suspended-sediment concentration and loading as a function of turbidity and streamflow data have been published in a U.S. Geological Survey Techniques and Methods Report, Book 3, Chapter C4. This paper is a summary of these guidelines and discusses some of the concepts, s atistical procedures, and techniques used to maintain a multiyear suspended sediment time series.

  3. Sampling method, storage and pretreatment of sediment affect AVS concentrations with consequences for bioassay responses.

    Science.gov (United States)

    De Lange, H J; Van Griethuysen, C; Koelmans, A A

    2008-01-01

    Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the disturbance of the sediment. AVS and Simultaneously Extracted Metal (SEM) concentrations were compared to bioassay responses with the freshwater benthic macroinvertebrate Asellus aquaticus. Storage conditions and sediment treatment affected AVS but not SEM levels. AVS can be used as a proxy for sediment disturbance. The best way to pretreat the sediment for use in a bioassay in order to maintain initial AVS conditions was to sample the sediment with an Ekman grab, immediately store it in a jar without headspace, and freeze it as soon as possible. In a survey using seven different sediments, bioassay responses of A. aquaticus were correlated with SEM and AVS characteristics.

  4. Application of dimensionless sediment rating curves to predict suspended-sediment concentrations, bedload, and annual sediment loads for rivers in Minnesota

    Science.gov (United States)

    Ellison, Christopher A.; Groten, Joel T.; Lorenz, David L.; Koller, Karl S.

    2016-10-27

    Consistent and reliable sediment data are needed by Federal, State, and local government agencies responsible for monitoring water quality, planning river restoration, quantifying sediment budgets, and evaluating the effectiveness of sediment reduction strategies. Heightened concerns about excessive sediment in rivers and the challenge to reduce costs and eliminate data gaps has guided Federal and State interests in pursuing alternative methods for measuring suspended and bedload sediment. Simple and dependable data collection and estimation techniques are needed to generate hydraulic and water-quality information for areas where data are unavailable or difficult to collect.The U.S. Geological Survey, in cooperation with the Minnesota Pollution Control Agency and the Minnesota Department of Natural Resources, completed a study to evaluate the use of dimensionless sediment rating curves (DSRCs) to accurately predict suspended-sediment concentrations (SSCs), bedload, and annual sediment loads for selected rivers and streams in Minnesota based on data collected during 2007 through 2013. This study included the application of DSRC models developed for a small group of streams located in the San Juan River Basin near Pagosa Springs in southwestern Colorado to rivers in Minnesota. Regionally based DSRC models for Minnesota also were developed and compared to DSRC models from Pagosa Springs, Colorado, to evaluate which model provided more accurate predictions of SSCs and bedload in Minnesota.Multiple measures of goodness-of-fit were developed to assess the effectiveness of DSRC models in predicting SSC and bedload for rivers in Minnesota. More than 600 dimensionless ratio values of SSC, bedload, and streamflow were evaluated and delineated according to Pfankuch stream stability categories of “good/fair” and “poor” to develop four Minnesota-based DSRC models. The basis for Pagosa Springs and Minnesota DSRC model effectiveness was founded on measures of goodness

  5. Sampling method, storage and pretreatment of sediment affect AVS concentrations with consequences for bioassay responses

    NARCIS (Netherlands)

    Lange, de H.J.; Griethuysen, van C.; Koelmans, A.A.

    2008-01-01

    Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the

  6. Influence of mineralogical and heavy metal composition on natural radionuclide concentrations in the river sediments

    Energy Technology Data Exchange (ETDEWEB)

    Suresh, G., E-mail: gsureshphy_1983@yahoo.co.in [Department of Physics Thiruvalluvar College of Engg and Tech, Ponnur hills, Vandavasi, Tamilnadu 604 505 (India); Ramasamy, V. [Department of Physics, Annamalai University, Tamilnadu (India); Meenakshisundaram, V. [Health and Safety Division, IGCAR, Kalpakkam, Tamilnadu (India); Venkatachalapathy, R. [CAS in Marine Biology, Faculty of Marine Sciences, Annamalai University, Tamilnadu (India); Ponnusamy, V. [Department of Physics, MIT Campus, Anna University Chennai, Tamilnadu (India)

    2011-10-15

    The natural radiation level has been determined for the sediment samples of the Ponnaiyar River with an aim of evaluating the radiation hazard. The mineralogical characterizations of the sediments have been carried out using the Fourier Transform Infrared (FTIR) spectroscopic technique. The relative distribution of major minerals is determined by calculating extinction coefficient. The concentration and spatial distribution of heavy metals (Pb, Cr, Cu, Zn and Ni) have been studied to understand the heavy metal contamination and its level of toxicity. To evaluate the potential toxicity, heavy metal concentrations are compared with different toxicological and geological reference values. The comparison results suggest that the present metals create an adverse effect on the aquatic ecosystems associated with this river. To assess the sediment contamination due to the studied heavy metals, the Pollution Load Index (PLI) is calculated. Multivariate Statistical analyses (Pearson Correlation, Cluster and Factor analysis) were carried out between the parameters obtained from radioactivity, mineralogical and geochemical analysis to know the existing relations. Obtained results showed that the effect of mineralogy on level of radioactivity should be significant. However, mineralogy effect on heavy metal composition in the sediments should be limited, indicating that other factors such as vicinity of the pollution sources are more important. Also, the influence of mineralogical characterization on level of radioactivity is significant, whereas the influence of the heavy metal composition on level of radioactivity should be limited. - Highlights: >Sediments radioactivity, mineralogical and heavy metal characterization have been analyzed. > Absorbed dose rate, PLI and kaolinite increase towards the river mouth. > Influence of minerals and heavy metals on level of radioactivity is assessed.

  7. Influence of mineralogical and heavy metal composition on natural radionuclide concentrations in the river sediments

    International Nuclear Information System (INIS)

    Suresh, G.; Ramasamy, V.; Meenakshisundaram, V.; Venkatachalapathy, R.; Ponnusamy, V.

    2011-01-01

    The natural radiation level has been determined for the sediment samples of the Ponnaiyar River with an aim of evaluating the radiation hazard. The mineralogical characterizations of the sediments have been carried out using the Fourier Transform Infrared (FTIR) spectroscopic technique. The relative distribution of major minerals is determined by calculating extinction coefficient. The concentration and spatial distribution of heavy metals (Pb, Cr, Cu, Zn and Ni) have been studied to understand the heavy metal contamination and its level of toxicity. To evaluate the potential toxicity, heavy metal concentrations are compared with different toxicological and geological reference values. The comparison results suggest that the present metals create an adverse effect on the aquatic ecosystems associated with this river. To assess the sediment contamination due to the studied heavy metals, the Pollution Load Index (PLI) is calculated. Multivariate Statistical analyses (Pearson Correlation, Cluster and Factor analysis) were carried out between the parameters obtained from radioactivity, mineralogical and geochemical analysis to know the existing relations. Obtained results showed that the effect of mineralogy on level of radioactivity should be significant. However, mineralogy effect on heavy metal composition in the sediments should be limited, indicating that other factors such as vicinity of the pollution sources are more important. Also, the influence of mineralogical characterization on level of radioactivity is significant, whereas the influence of the heavy metal composition on level of radioactivity should be limited. - Highlights: →Sediments radioactivity, mineralogical and heavy metal characterization have been analyzed. → Absorbed dose rate, PLI and kaolinite increase towards the river mouth. → Influence of minerals and heavy metals on level of radioactivity is assessed.

  8. Prediction of suspended-sediment concentrations at selected sites in the Fountain Creek watershed, Colorado, 2008-09

    Science.gov (United States)

    Stogner, Sr., Robert W.; Nelson, Jonathan M.; McDonald, Richard R.; Kinzel, Paul J.; Mau, David P.

    2013-01-01

    In 2008, the U.S. Geological Survey (USGS), in cooperation with Pikes Peak Area Council of Governments, Colorado Water Conservation Board, Colorado Springs City Engineering, and the Lower Arkansas Valley Water Conservancy District, began a small-scale pilot study to evaluate the effectiveness of the use of a computational model of streamflow and suspended-sediment transport for predicting suspended-sediment concentrations and loads in the Fountain Creek watershed in Colorado. Increased erosion and sedimentation damage have been identified by the Fountain Creek Watershed Plan as key problems within the watershed. A recommendation in the Fountain Creek Watershed plan for management of the basin is to establish measurable criteria to determine if progress in reducing erosion and sedimentation damage is being made. The major objective of this study was to test a computational method to predict local suspended-sediment loads at two sites with different geomorphic characteristics in order to evaluate the feasibility of using such an approach to predict local suspended-sediment loads throughout the entire watershed. Detailed topographic surveys, particle-size data, and suspended-sediment samples were collected at two gaged sites: Monument Creek above Woodmen Road at Colorado Springs, Colorado (USGS gage 07103970), and Sand Creek above mouth at Colorado Springs, Colorado (USGS gage 07105600). These data were used to construct three-dimensional computational models of relatively short channel reaches at each site. The streamflow component of these models predicted a spatially distributed field of water-surface elevation, water velocity, and bed shear stress for a range of stream discharges. Using the model predictions, along with measured particle sizes, the sediment-transport component of the model predicted the suspended-sediment concentration throughout the reach of interest. These computed concentrations were used with predicted flow patterns and channel morphology to

  9. Biota sediment concentration ratio (CRs-b) for fishes of Rana Pratap Sagar Lake, Rawatbhata

    International Nuclear Information System (INIS)

    Goyal, S.K.; Srivastava, A.P.; Jain, A.K.; Meenal, Balram; Tiwari, S.N.; Ravi, P.M.; Tripathi, R.M.

    2018-01-01

    Radionuclides dissolved in water can be adsorbed by bottom/shore sediment transferring it to the deep sediment layers. These adsorbed radionuclides can be remobilized and be available again for uptake by freshwater biota. The biota sediment concentration ratio (CR s-b ) is the ratio of the concentration of a radionuclide in an organism (C b ) on a fresh weight basis to the radionuclide concentration measured in the sediment (C sediment ). Using the data of 137 Cs activity in fish and shore sediment, CR s-b was calculated for fish samples of Rana Pratap Sagar (RPS) Lake, Rawatbhata. This value can be applied in predictive models to calculate radionuclide concentration in fish samples

  10. Activity concentrations of 239+240 Pu in sediment at Sabah and Sarawak coastal areas

    International Nuclear Information System (INIS)

    Jalal Sharib; Zaharudin Ahmad; Yii Mei Wo; Hidayah Shahar

    2009-01-01

    The coastal sediment sampling was carried out in July 2004 as part of the Marine Radioactivity Database Development Project for Malaysia. The determination of plutonium, 239+240 Pu activity concentration and their distributions along the coastal areas of Sabah and Sarawak was by the alpha spectrometry counting system. Prior to counting, the radionuclides were isolated from the samples using radiochemical separation technique and mounted on a stainless steel disc by using electro-deposition. The results show that the distribution of 239+240 Pu activity concentration in coastal sediment is consistent, ranging from BDL - 1.83 Bq/kg and 0.11 - 0.84 Bq/kg dry weight, respectively. Lubok Sabanan, SB 15, in Sabah and Sungai Similajau, SR 13, in Sarawak were sampling stations that gave highest 239+240 Pu activity concentration. Overall, the 239+240 Pu activity concentration of Sabah and Sarawak are slightly higher in comparison the West Coast coastal stations of Peninsular Malaysia, and can be used as database. (Author)

  11. Assessment of the metals concentration in sediments of Chimaliapan Lagoon, Lerma, Mexico State

    International Nuclear Information System (INIS)

    Perez V, I. A.

    2015-01-01

    The San Pedro Tultepec Lagoon of Quiroga in Lerma, known as Chimaliapan Lagoon is one of the Cienegas of the high course of the Lerma river. Considering that the lagoon is adjacent to an industrial area, have been altered the natural conditions of the channels, degrading the water quality and affecting the systems with different pollution sources, among which are industrial and municipal discharges and runoff of farmland. For this reason was decided to conduct a study in order to assess the concentration of metals in sediments of 4 sites and 4 downloads of the Chimaliapan Lagoon in order to infer the possible natural contributions and/or anthropogenic metals and their impact on both flora and fauna and the population that is supplied with the same, while assessing levels of enrichment of Ti, Cr, Mn, Fe, Cu, Zn and Pb metals as a result of contributions previously mentioned applying the technique of Energy Dispersive X-ray Fluorescence (EDXRF). According to the results by EDXRF, the sediments of the Lagoon assessed with the criterion of the EPA for the disposal of dredged sediments at this site, Mn and Fe only slightly exceed this criterion, then considering the Canadian criteria for the protection of aquatic life OMe, might have slight effects of Cr, Mn, Fe and Cu. Sediment discharges, evaluated with the same criteria indicate that Cr and Pb exceed the limit recommended by the EPA for the disposal of dredged sediments and Cr, Cu and Zn exceed the limit recommended for the protection of aquatic life OMe, noting that these metals may cause slight effects on organisms living in the Lagoon, such as carp and other organisms that live there, causing potential effects on humans through the food chain. (Author)

  12. Differences in nutrient concentrations and resources between seagrass communities on carbonate and terrigenous sediments in South Sulawesi, Indonesia

    NARCIS (Netherlands)

    Erftemeijer, P.L.A.

    1994-01-01

    Water column, sediment and plant parameters were studied in six tropical seagrass beds in South Sulawesi, Indonesia, to evaluate the relation between seagrass bed nutrient concentrations and sediment type. Coastal seagrass beds on terrigenous sediments had considerably higher biomass of

  13. Assessment of heavy metals concentrations in coastal sediments in ...

    African Journals Online (AJOL)

    EJIRO

    Three kinds of analytical method were used for metals determination and quantification: ... such as copper, zinc, manganese, iron and chromium in Nosy Be sediments, were twice as .... Mean sewage of Mahajanga from Vallon de Meitzinger.

  14. Relationship between dioxin concentration and particle size for suspended sediment

    Energy Technology Data Exchange (ETDEWEB)

    Kitamura, K.; Sakurai, T.; Choi, J.W.; Suzuki, N.; Morita, M. [National Inst. for Environmental Studies, Tsukuba (Japan)

    2004-09-15

    The purpose of the present study was to find out how the amounts of adsorbed dioxins, i.e., polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/Fs), mono-ortho-polychlorinated biphenyls (PCBs) and non-ortho-PCBs, vary with the particle size of suspended sediment. As dioxins are hydrophobic, they tend to adsorb onto particles suspended in water, and the determination of which dioxin congeners readily dissolve in water or adsorb onto particles is central to the characterization of dioxin behavior in water/sediment systems. Presumably suspension of sediments and the size of the particles govern the transfer of dioxins to aquatic organisms. Therefore, in the present study, we investigated the relationship between the amount of dioxins and the particle-size distribution of resuspended, rather than settled, sediment.

  15. Characterization of sediments laid on Solimoes/Amazonas river flood plains, using energy dispersive X-ray fluorescence technique

    International Nuclear Information System (INIS)

    Carneiro, Ana E.V.; Nascimento Filho, Virgilio F. do

    1997-01-01

    This paper proposes sediment analysis with high light elements fraction using dispersive energy X-ray fluorescence technique with radioisotopic excitation, The proposed procedure is based on the Fundamental Parameters for analytical elements (Z ≥ 13) evaluation, and coherent and incoherent scattered radiation for quantification of the light fraction of the matrix (Z < 13). Laid sediments samples on Solimoes/Amazonas river flood plains were analyzed, determining simultaneously the Al, Si, K, Ca, Ti, Fe, Sc, V, Mn, Cu, Zn, Rb, Sr and Zr element concentrations, thus allowing chemical characterization and spatial variability, and some mineralogical and weathering sediments aspects. (author). 15 refs., 11 tabs

  16. Concentration-dependent sedimentation properties of ferritin: implications for estimation of iron contents of serum ferritins

    International Nuclear Information System (INIS)

    Niitsu, Y.; Adachi, C.; Takahashi, F.; Goto, Y.; Kohgo, Y.; Urushizaki, I.; Listowsky, I.

    1985-01-01

    Serum ferritins from various sources sedimented at lower densities than tissue ferritins in sucrose gradient centrifugation systems. The sedimentation patterns of ferritins, however, were shown to be dependent on the concentration of the protein; as the concentration decreased the protein appeared to sediment at lower densities. Thus, at the low concentration levels usually used for analysis of serum ferritin, tissue ferritins also sedimented in the same lower density regions. Iron labeling experiments indicated that the sedimentation changes upon dilution were not due to release of iron or was there any indication that the protein dissociated into subunits. The anomalous sedimentation behavior of serum ferritin should therefore not be interpreted in terms of its iron content. The disclosure that serum ferritins may have full complements of iron is counter to the prevalent view that serum ferritins are low iron forms and has potential implications with regard to the sources and possible function of this protein in the circulation

  17. Sampling method, storage and pretreatment of sediment affect AVS concentrations with consequences for bioassay responses

    Energy Technology Data Exchange (ETDEWEB)

    Lange, H.J. de [Aquatic Ecology and Water Quality Management Group, Wageningen University, Wageningen University and Research Centre, P.O. Box 8080, 6700 DD, Wageningen (Netherlands); Centre for Ecosystem Studies, Alterra, Wageningen University and Research Centre, P.O. Box 47, 6700 AA, Wageningen (Netherlands)], E-mail: marieke.delange@wur.nl; Griethuysen, C. van; Koelmans, A.A. [Aquatic Ecology and Water Quality Management Group, Wageningen University, Wageningen University and Research Centre, P.O. Box 8080, 6700 DD, Wageningen (Netherlands)

    2008-01-15

    Sediment treatment and sediment storage may alter sediment toxicity, and consequently biotic response. Purpose of our study was to combine these three aspects (treatment-toxicity-biotic response) in one integrated approach. We used Acid Volatile Sulfide (AVS) concentrations as a proxy of the disturbance of the sediment. AVS and Simultaneously Extracted Metal (SEM) concentrations were compared to bioassay responses with the freshwater benthic macroinvertebrate Asellus aquaticus. Storage conditions and sediment treatment affected AVS but not SEM levels. AVS can be used as a proxy for sediment disturbance. The best way to pretreat the sediment for use in a bioassay in order to maintain initial AVS conditions was to sample the sediment with an Ekman grab, immediately store it in a jar without headspace, and freeze it as soon as possible. In a survey using seven different sediments, bioassay responses of A. aquaticus were correlated with SEM and AVS characteristics. - Change in AVS is a good proxy for sediment disturbance and combined with SEM it can be used as a suitable predictor for biotic effects of sediment contamination.

  18. Trends in suspended-sediment loads and concentrations in the Mississippi River Basin, 1950–2009

    Science.gov (United States)

    Heimann, David C.; Sprague, Lori A.; Blevins, Dale W.

    2011-01-01

    Trends in loads and concentrations of suspended sediment and suspended sand generally were downward for stations within the Mississippi River Basin during the 60-, 34-, and 12-year periods analyzed. Sediment transport in the lower Mississippi River has historically been, and continues to be, most closely correlative to sediment contributions from the Missouri River, which generally carried the largest annual suspended-sediment load of the major Mississippi River subbasins. The closure of Fort Randall Dam in the upper Missouri River in 1952 was the single largest event in the recorded historical decline of suspended-sediment loads in the Mississippi River Basin. Impoundments on tributaries and sediment reductions as a result of implementation of agricultural conservation practices throughout the basin likely account for much of the remaining Mississippi River sediment transport decline. Scour of the main-stem channel downstream from the upper Missouri River impoundments is likely the largest source of suspended sand in the lower Missouri River. The Ohio River was second to the Missouri River in terms of sediment contributions, followed by the upper Mississippi and Arkansas Rivers. Declines in sediment loads and concentrations continued through the most recent analysis period (1998–2009) at available Mississippi River Basin stations. Analyses of flow-adjusted concentrations of suspended sediment indicate the recent downward temporal changes generally can be explained by corresponding decreases in streamflows.

  19. Radioactivity concentrations and their radiological significance in sediments of the Tema Harbour (Greater Accra, Ghana

    Directory of Open Access Journals (Sweden)

    Benjamin O. Botwe

    2017-01-01

    Full Text Available Studies on environmental radioactivity in tropical Africa are scarce. Therefore, a baseline study of natural (238U, 210Pb, 226Ra, 232Th, 228Ra, 228Th, 40K and anthropogenic (137Cs radionuclides was carried out on Tema Harbour (Greater Accra, Ghana surface sediments and on their radiological significance. Grab surface sediment samples were collected from 21 stations within the Tema Harbour and their radioactivity concentrations measured by gamma spectrometry. The mean sediment radioactivity concentrations (Bq kg−1 dw were 34 for 238U, 210 for 210Pb, 14 for 226Ra, 30 for 232Th, 29 for 228Ra, 31 for 228Th, 320 for 40K, and 1.5 for 137Cs. Large 238U/226Ra disequilibria were observed in the harbour sediments and a complex dynamics of several mixed sources of sediments within the Tema Harbour can be inferred from the spatial variations in the radioactivity concentrations. The estimated total absorbed dose rate in air (D, radium equivalent activity (Raeq, external hazard index (Hex, annual gonadal dose equivalent (AGDE and annual effective dose equivalent (AEDE indicated no significant radiological risks from the sediment radioactivity concentrations. Application of the Environmental Risk from Ionising Contaminants Assessment and Management tool (ERICA confirmed that the potential dose rates to biota from the sediment radioactivity concentrations are unlikely to pose appreciable ecological risks. The radioactivity levels are compared with levels reported in sediments from other coastal areas of the world.

  20. Radioactivity concentrations and their radiological significance in sediments of the Tema Harbour (Greater Accra, Ghana)

    OpenAIRE

    Benjamin O. Botwe; Antonio Schirone; Ivana Delbono; Mattia Barsanti; Roberta Delfanti; Peter Kelderman; Elvis Nyarko; Piet N.L. Lens

    2017-01-01

    Studies on environmental radioactivity in tropical Africa are scarce. Therefore, a baseline study of natural (238U, 210Pb, 226Ra, 232Th, 228Ra, 228Th, 40K) and anthropogenic (137Cs) radionuclides was carried out on Tema Harbour (Greater Accra, Ghana) surface sediments and on their radiological significance. Grab surface sediment samples were collected from 21 stations within the Tema Harbour and their radioactivity concentrations measured by gamma spectrometry. The mean sediment radioactivity...

  1. Heavy metal concentrations in Bottom Sediments of Ikpoba River ...

    African Journals Online (AJOL)

    MICHAEL HORSFALL

    2014-06-23

    Jun 23, 2014 ... macrophytes like salvinia sp and water hyacinth. (Eichornia crassipes). This station was the lowest in depth during the dry season. The water level however increased when it was heavily flooded during the rainy season. Activities here include making of sacrifices. Sediment Samples Collection, Preparation ...

  2. Sediment remediation treatment techniques for the Venice industrial canals

    Energy Technology Data Exchange (ETDEWEB)

    Pippa, R.; Scanferla, P.; Cammarata, F.; Zampieri, L.; Carlon, C. [Consorzio Venezia Ricerche (Italy); Pavoni, B. [Ca' Foscari University of Venice (Italy). Dept. of Environmental Sciences; Pannocchia, G. [Venezia Technologie SpA, Venice (Italy); Hreglich, S. [Stazione Sperimentale del Vetro, Venice (Italy); Avezzu, F. [Depuracque Impianti srl, Venice (Italy)

    2003-07-01

    The main objective of SeRTech project (Sediment Remediation Technologies) is to develop an integrated cost-effective treatment system to address heterogeneous contamination and matrixes, such as those of Venice lagoon dredged materials. Seven treatment techniques, selected over a large array, have been tested: Thermal Desorption. A preliminary set of isothermal treatments at different temperatures was performed to evaluated the losses of organic and the most volatile metals (such as Pb and As). An almost full volatilisation of organic compounds was observed at temperatures ranging between 200 and 300 C. Chemical stabilization-solidification. Depuracque Impianti srl process uses innovative patented additives (polimers and superplasticizers) to immobilize heavy metals into cement pellets. Solvent extraction. Organic contaminants such as PAHs and PCBs were extracted from sediments by using ethyl acetate. The results showed that solvent extraction obtained high efficiency in removal of PAHs and other organic contaminants. Immobilization of heavy metals employing sulfate-reducing bacteria. High Gradient Magnetic Separation (HGMS). Sulfate reducing bacteria (SBR) produce an iron sulfide containing biomass with a high capability to adsorbe hevy metals and some organic compounds. This biomass can be separated through a high gradient magnetic field removing a substantial fraction of contaminants. Vitrification. Sediment was mixed with other inorganic wastes (glass cullet, feldsphatic tailings) and low amounts of row material to obtain an inert glass, which in turn can be recycled into other useful products, for example glass fibres, foam glass and glass ceramics. Phytoremediation. Phragmites australis (Cav.), Trin; Juncus Iacustrus, Arthrocnmemum fruticosum, Spartina maritima, Helianthus annuus L., Zea mais L., Brassica napus L., Brassica juncea L. have been selected to verify limit and efficiency of phytoextraction for heavy metals (Zn, Pb, Hg, Cd, As, Ni). Not only

  3. Comparison of manufactured and black carbon nanoparticle concentrations in aquatic sediments

    NARCIS (Netherlands)

    Koelmans, A.A.; Nowack, B.; Wiesner, M.

    2009-01-01

    In this paper, we show that concentrations of manufactured carbon-based nanoparticles (MCNPs) in aquatic sediments will be negligible compared to levels of black carbon nanoparticles (BCNPs). This is concluded from model calculations accounting for MCNP sedimentation fluxes, removal rates due to

  4. Spatio-temporal Analysis of suspended sediment Concentration in the Yongjiang Estuary Based on GOCI

    Science.gov (United States)

    Kang, Yanyan; Dong, Chuan

    2018-01-01

    The concentration and spatio-temporal variation of suspended sediment concentration in the estuary area are of great significance to the nearshore engineering, port construction and coastal evolution. Based on multi-period GOCI images and corresponding measured suspended sediment concentration (SSC) data, three inversion models (the linear regression model, the power exponent model and the neural network model) were established after rapid atmospheric correction. The results show that the absolute error of the three models is 0.20, 0.16 and 0.10kg/m3 respectively, and the relative errors are 38%, 23% and 18% respectively. The accuracy of the neural network (8-17-17-1) is the best. The SSC distribution diagrams in an ebb and flow cycle are obtained using this ANN model. The results show that with Yongjiang estuary for segmentation, the high concentration area is located in the north and the lower is in the south around Jintang Island deeper water area. When the tide rises, the water flow disturbs a large amount of sediment, and then the sediment concentration increases and high area high concentrations water body moves along the SE-NW. When the tide falls, flow rate decreases and the sediment concentration decreases. However, with the falling tide, the concentration of suspended sediment in the northern sea areas gradually increases, and is higher than 1kg/m3, and gradually moves along the NW-SE until to the estuary.

  5. Effect of water-sediment regulation and its impact on coastline and suspended sediment concentration in Yellow River Estuary

    Directory of Open Access Journals (Sweden)

    Hai-bo Yang

    2017-10-01

    Full Text Available Implementation of the water-sediment regulation (WSR scheme, mainly focused on solving the sedimentation problems of reservoirs and the lower reaches of the Yellow River, has inevitably influenced the sediment distribution and coastal morphology of the Yellow River Estuary. Using coastline delineation and suspended sediment concentration (SSC retrieval methods, this study investigated water and sediment changes, identified detailed inter-annual and intra-annual variations of the coastline and SSC in the normal period (NP: 1986–2001, before and after the flood season and WSR period (WSRP: 2002–2013, before and after WSR. The results indicate that (1 the sedimentation in the low reaches of the Yellow River turned into erosion from 2002 onward; (2 the inter-annual coastline changes could be divided into an accretion stage (1986–1996, a slow erosion stage (1996–2002, and a slow accretion stage (2002–2013; (3 an intra-annual coastline extension occurred in the river mouth in most years of the WSRP; and (4 the mean intra-annual accretion area was 0.789 km2 in the NP and 4.73 km2 in the WSRP, and the mean SSC increased from 238 mg/L to 293 mg/L in the NP and from 192 mg/L to 264 mg/L in the WSRP.

  6. Zn, Pb, Cr and Cd concentrations in fish, water and sediment from ...

    African Journals Online (AJOL)

    ADOWIE PERE

    Zn, Pb, Cr and Cd concentrations in fish, water and sediment from the Azuabie Creek,. Port Harcourt. ... Heavy metal contamination in the aquatic ... Azuabie Creek and the associated water ..... Public in Tianjin, China via Consumption of.

  7. Passive sampling methods for contaminated sediments: Scientific rationale supporting use of freely dissolved concentrations

    DEFF Research Database (Denmark)

    Mayer, Philipp; Parkerton, Thomas F.; Adams, Rachel G.

    2014-01-01

    Passive sampling methods (PSMs) allow the quantification of the freely dissolved concentration (Cfree ) of an organic contaminant even in complex matrices such as sediments. Cfree is directly related to a contaminant's chemical activity, which drives spontaneous processes including diffusive upta...

  8. Comparison of polyvinyl alcohol- and formalin-preserved fecal specimens in the formalin-ether sedimentation technique for parasitological examination.

    OpenAIRE

    Carroll, M J; Cook, J; Turner, J A

    1983-01-01

    A total of 965 paired fecal specimens preserved in polyvinyl alcohol fixative and Formalin were processed by the Formalin-ether sedimentation technique. The effectiveness of the concentration procedures with material from each preservative was determined by comparing both diagnostic efficiency (percent identified) and quantitative egg and semiquantitative cyst counts. Of the 319 infections, 69.5% were detected in concentrates from both preservatives, 6.9% from polyvinyl alcohol only, and 23.5...

  9. Inorganic arsenic and iron(II) distributions in sediment porewaters investigated by a combined DGTcolourimetric DET technique

    DEFF Research Database (Denmark)

    Bennett, William W.; Teasdale, Peter R.; Welsh, David T.

    2012-01-01

    A new approach for investigating the biogeochemistry of inorganic arsenic and iron(II) in freshwater, estuarine and marine sediments is reported. The recently developed Metsorb diffusive gradients in thin films (DGT) technique for the measurement of total inorganic arsenic and the colourimetric d...... highly representative assessment of the biogeochemical status of arsenic and iron in a variety of natural sediments, including groundwater sediments where mobilised arsenic is responsible for significant human health risks.......A new approach for investigating the biogeochemistry of inorganic arsenic and iron(II) in freshwater, estuarine and marine sediments is reported. The recently developed Metsorb diffusive gradients in thin films (DGT) technique for the measurement of total inorganic arsenic and the colourimetric...... diffusive equilibration in thin films (DET) technique for the measurement of iron(II), were utilised in combination to determine co-located depth profiles of both solutes in sediment porewaters. DGT-measured porewater arsenic concentrations were typically less than 40nM, whereas iron(II) concentrations...

  10. Radiometric dating of sediment core from waterwork reservoir Rozgrund and analysis of mercury concentration depth profile

    International Nuclear Information System (INIS)

    Vanek, M.

    2005-01-01

    Radioisotope dating of lake sediments combined with analysis of chemical properties of the sediment layers allow us to study the history of the human impact on nature. Undisturbed sediment layers in the core samples serve as chronicle database with information about lake ecosystem and surrounding environment in the time of deposition. A sediment core sample from the bottom of the water-work reservoir Rozgrund was collected and separated into 2 cm thick layers. Samples were analysed by HPGe spectrometry for anthropogenous Cs-137 activity. From identified peaks corresponding to nuclear tests and Chernobyl accident the sedimentation rate was calculated and the chronology of layers established. Sub-samples from each layer were prepared separately for the analysis of the Hg concentration by atomic absorption spectrometry. The results show very small variations in Hg concentrations and there is no significant trend present in the profile. (author)

  11. Uranium concentrations in lake and stream waters and sediments from selected sites in the Susitna River Basin, Alaska

    International Nuclear Information System (INIS)

    Hill, D.E.

    1977-03-01

    During the summer of 1976, 141 water and 211 sediment samples were taken from 147 locations in the Susitna River basin in Alaska by the Geophysical Institute of the University of Alaska for the LASL. These samples were taken to provide preliminary information on the uranium concentrations in waters and sediments from the Susitna River basin and to test the analytical methods proposed for the NURE Hydrogeochemical and Stream Sediment Reconnaissance for uranium in Alaska. The uranium determinations resulting from the fluorometric analysis of the water samples and the delayed-neutron counting of the sediment samples are presented. The low levels of uranium in the water samples, many of which were below the detectable limit of the LASL fluorometric technique, indicate that a more sensitive analytical method is needed for the analysis of Alaskan water samples from this area. An overlay showing numbered sample locations and overlays graphically portraying the concentrations of uranium in the water and sediment samples, all at 1:250,000 scale for use with existing USGS topographic sheets, are also provided as plates

  12. Evaluation of suspended sediment concentrations, sediment fluxes and sediment depositions along a reservoir by using laser diffraction and acoustic backscatter data

    Science.gov (United States)

    Lizano, Laura; Haun, Stefan

    2015-04-01

    The construction of dams and reservoirs disturb the natural morphological behavior of rivers. A natural settling effect occurs due to the reduced turbulences and flow velocities. As a consequence, reservoirs fill up with sediments which results in a reduction of storage volume, influences the operation of hydropower plants and leads in several cases to flood protection problems. The sediment depositions in reservoirs are standardly evaluated by using bathymetric data, obtained by a single beam sonar from pre-defined cross sections or by an extensive evaluation of the reservoir bed by a side scan sonar. However, a disadvantage of this method is that it is not possible to evaluate the pore water content of the depositions, which may lead as consequence to an uncertainty in the measured amount of deposited sediments. Given that a major part of sediments entering reservoirs are transported in suspension, sediment flux measurements along defined transects could give more reliable information on the settled amount of sediments and additional information on the sediment transport mechanism within the reservoir. An evaluation of the sediment fluxes is in practice often conducted by a single suspended sediment concentration (SSC) measurement in combination with a cross sectional calibration factor to take changes in the SSC along the transect into account. However, these calibration factors are often developed only for one specific in-situ condition and may give unreliable results in case that the boundaries change e.g. the hydraulic conditions. Hence an evaluation of the sediment fluxes along the whole transect would give a more reliable number for the amount of transported sediments through the reservoir. This information can afterwards be used to calculate the amount of settled sediments in different sections of the reservoir and the amount of sediments which will enter the intake. For this study the suspended sediment transport within the Peñas Blancas reservoir in

  13. Concentration of arsenic in water, sediments and fish species from naturally contaminated rivers.

    Science.gov (United States)

    Rosso, Juan José; Schenone, Nahuel F; Pérez Carrera, Alejo; Fernández Cirelli, Alicia

    2013-04-01

    Arsenic (As) may occur in surface freshwater ecosystems as a consequence of both natural contamination and anthropogenic activities. In this paper, As concentrations in muscle samples of 10 fish species, sediments and surface water from three naturally contaminated rivers in a central region of Argentina are reported. The study area is one of the largest regions in the world with high As concentrations in groundwater. However, information of As in freshwater ecosystems and associated biota is scarce. An extensive spatial variability of As concentrations in water and sediments of sampled ecosystems was observed. Geochemical indices indicated that sediments ranged from mostly unpolluted to strongly polluted. The concentration of As in sediments averaged 6.58 μg/g ranging from 0.23 to 59.53 μg/g. Arsenic in sediments barely followed (r = 0.361; p = 0.118) the level of contamination of water. All rivers showed high concentrations of As in surface waters, ranging from 55 to 195 μg/L. The average concentration of As in fish was 1.76 μg/g. The level of contamination with As differed significantly between species. Moreover, the level of bioaccumulation of As in fish species related to the concentration of As in water and sediments also differed between species. Whilst some fish species seemed to be able to regulate the uptake of this metalloid, the concentration of As in the large catfish Rhamdia quelen mostly followed the concentration of As in abiotic compartments. The erratic pattern of As concentrations in fish and sediments regardless of the invariable high levels in surface waters suggests the existence of complex biogeochemical processes behind the distribution patterns of As in these naturally contaminated ecosystems.

  14. Anthropogenic lead concentrations and sources in Baltic Sea sediments based on lead isotopic composition

    International Nuclear Information System (INIS)

    Zaborska, Agata

    2014-01-01

    Highlights: • Pb concentrations reach even 147 μg/g at Gdansk Basin sediments. • Marine sediments deposited before 1860 are not contaminated by Pb. • Contemporary inventories of anthropogenic Pb in marine sediments was of 0.5–11 g for m 2 . • The lowest 206 Pb/ 207 Pb (1.165) were measured in sediments deposited between 1970s–90s. • Coal burning was always the most important Pb source in Poland. - Abstract: The Gulf of Gdańsk is influenced by heavy metals of anthropogenic origin. In this study, temporal concentration changes of Pb, Zn, Cd, and Cu were studied in six, 50 cm long sediment cores. The main aim of the study was to concentrate on the history of Pb fluxes and Pb isotopic composition ( 206 Pb/ 207 Pb and 208 Pb/ 206 Pb) to trace Pb sources. The lowest Pb concentrations (19 μg g −1 ) were measured in sediments deposited circa 1860, while the highest Pb concentrations (63–147 μg g −1 ) were measured in sediments deposited between 1960s and 70s. Pre-industrial Pb fluxes were 7 Pb m 2 year −1 , while after WWII they reached 199 Pb m 2 year −1 . Highest 206 Pb/ 207 Pb ratios (∼1.22) were measured in the oldest sediment layers, and the lowest 206 Pb/ 207 Pb ratios (∼1.165) were measured in the sediments deposited in 1970s–90s. During the period of highest Pb contamination, the anthropogenic Pb fraction reached up to 93%. A general discussion of the Pb sources, emissions, and loads for Poland is included

  15. Actual situation of concentration and inventory of radioactive cesium in Matsukawaura Lagoon sediment, Fukushima Prefecture

    International Nuclear Information System (INIS)

    Arita, Koichi; Yabe, Tohru; Hayashi, Seiji

    2014-01-01

    In order to qualitatively evaluate the current status of inventory of radioactive cesium in Matsukawaura Lagoon, profiles of radioactive cesium concentration in sediment cores and sediment characteristics were measured at 36 points. It was shown that sediment characteristics were different even at high concentration of radioactive cesium to the same extent. As a result, the inventory of radioactive cesium were also different. Even at high concentration of radioactive cesium, inventory in southwestern high mud content rate was less than the western. The total inventory of down to 20 cm of sediment throughout Matsukawaura Lagoon was estimated to be about 220 GBq, that more than 80% distributed to 15 cm shallower than has been revealed. (author)

  16. Water Quality and Heavy Metal Concentrations in Sediment of Sungai Kelantan, Kelantan, Malaysia: A Baseline Study

    International Nuclear Information System (INIS)

    Ahmad, A.K.; Mushrifah, I.; Mohamad Shuhaimi Othman

    2009-01-01

    A study on water quality and heavy metal concentration in sediment at selected sites of Sungai Kelantan was carried out. Ten water samples were collected along the river for physical and chemical analysis and twenty-six water and sediment samples were collected for heavy metal analysis. Water was sampled at three different dates throughout the study period whereas sediments were collected once. In addition to heavy metal analysis, sediment samples were also analysed for texture, ph and organic content. The physical and chemical water quality analyses were carried out according to the ALPHA procedures. Result of water quality analysis (physico-chemical) indicated that Sungai Kelantan is characterised by excellent water quality and comparable to pristine ecosystems such as the National Park and Kenyir Lake. This river was classified into class I - class III based on Malaysian interim water quality standard criteria (INWQS). Heavy metals Pb, Zn, Cu and Cd was detected at low concentration in sediment samples, except for Fe and Mn. The presence of Fe and Mn in sediment samples was though to be of natural origin from the soil. Anthropogenic metal concentrations in sediment were low indicating that Sungai Kelantan has not experienced extreme pollution. (author)

  17. Guidelines and Procedures for Computing Time-Series Suspended-Sediment Concentrations and Loads from In-Stream Turbidity-Sensor and Streamflow Data

    Science.gov (United States)

    Rasmussen, Patrick P.; Gray, John R.; Glysson, G. Douglas; Ziegler, Andrew C.

    2009-01-01

    In-stream continuous turbidity and streamflow data, calibrated with measured suspended-sediment concentration data, can be used to compute a time series of suspended-sediment concentration and load at a stream site. Development of a simple linear (ordinary least squares) regression model for computing suspended-sediment concentrations from instantaneous turbidity data is the first step in the computation process. If the model standard percentage error (MSPE) of the simple linear regression model meets a minimum criterion, this model should be used to compute a time series of suspended-sediment concentrations. Otherwise, a multiple linear regression model using paired instantaneous turbidity and streamflow data is developed and compared to the simple regression model. If the inclusion of the streamflow variable proves to be statistically significant and the uncertainty associated with the multiple regression model results in an improvement over that for the simple linear model, the turbidity-streamflow multiple linear regression model should be used to compute a suspended-sediment concentration time series. The computed concentration time series is subsequently used with its paired streamflow time series to compute suspended-sediment loads by standard U.S. Geological Survey techniques. Once an acceptable regression model is developed, it can be used to compute suspended-sediment concentration beyond the period of record used in model development with proper ongoing collection and analysis of calibration samples. Regression models to compute suspended-sediment concentrations are generally site specific and should never be considered static, but they represent a set period in a continually dynamic system in which additional data will help verify any change in sediment load, type, and source.

  18. Determination of sedimentation rates in Izmir Bay by 210Pb dating technique

    International Nuclear Information System (INIS)

    Ichedef, M.; Yener, G.; Ugur, A.; Oezden, B.; Goenuelalan, F.; Akoezcan, S.; Bueyuekisik, B.; Koeksal, E. Y.

    2006-01-01

    Environmental 2 10Pb (natural) dating technique was applied to determine sedimentation rates in Izmir Bay, near the heavily industrialized Turkish Coastal zone of the Aegean Sea. Core samples from different 20 stations in the inner bay were collected with core sampler and sedimentation rates were estimated from the vertical distribution of excess 2 10Pb. Core samples were stored for a period of 2-3 half-lives (9-14 months) of 2 10Po (t 1 /2=138 d) before analysis to allow build-up of 2 10Po from 2 10Pb. Po was collected on cupper disks by electrochemical deposition. Then, 2 10Pb activities were determined undirectly from 2 10Po activities. Measurement of 2 10Po were made through its 5.30 MeV alpha particle emission, using 2 09Po as the internal tracer. Measurements were made by PIPS (Passivated Implanted Planar Silicon) detector. The sedimentation rates for core samples analysed so far were calculated to vary from 0.198 cm y - 1 to 0.489 cm y - 1. The highest unsupported 2 10Pb concentrations (104 Bq kg - 1) were measured in the 8.station where the Ilica, Bayrakli and Bornova streams empty, and nearest to the harbour

  19. Technical note: False low turbidity readings from optical probes during high suspended-sediment concentrations

    Science.gov (United States)

    Voichick, Nicholas; Topping, David J.; Griffiths, Ronald E.

    2018-03-01

    Turbidity, a measure of water clarity, is monitored for a variety of purposes including (1) to help determine whether water is safe to drink, (2) to establish background conditions of lakes and rivers and detect pollution caused by construction projects and stormwater discharge, (3) to study sediment transport in rivers and erosion in catchments, (4) to manage siltation of water reservoirs, and (5) to establish connections with aquatic biological properties, such as primary production and predator-prey interactions. Turbidity is typically measured with an optical probe that detects light scattered from particles in the water. Probes have defined upper limits of the range of turbidity that they can measure. The general assumption is that when turbidity exceeds this upper limit, the values of turbidity will be constant, i.e., the probe is pegged; however, this assumption is not necessarily valid. In rivers with limited variation in the physical properties of the suspended sediment, at lower suspended-sediment concentrations, an increase in suspended-sediment concentration will cause a linear increase in turbidity. When the suspended-sediment concentration in these rivers is high, turbidity levels can exceed the upper measurement limit of an optical probe and record a constant pegged value. However, at extremely high suspended-sediment concentrations, optical turbidity probes do not necessarily stay pegged at a constant value. Data from the Colorado River in Grand Canyon, Arizona, USA, and a laboratory experiment both demonstrate that when turbidity exceeds instrument-pegged conditions, increasing suspended-sediment concentration (and thus increasing turbidity) may cause optical probes to record decreasing false turbidity values that appear to be within the valid measurement range of the probe. Therefore, under high-turbidity conditions, other surrogate measurements of turbidity (e.g., acoustic-attenuation measurements or suspended-sediment samples) are necessary to

  20. Influence of solids concentration on the sedimentation rate of the mud in the aggregate industry

    Directory of Open Access Journals (Sweden)

    Benigno Leyva-de la Cruz

    2016-12-01

    Full Text Available The objective of this investigation is to determine, for the mud resulting from the wash process in the Jobo community arid industry in Sagua de Tánamo, the impact of solids percent on the theoretical sedimentation velocity that is predicted by the Stokes velocity Law. Samples of the discharge pipeline and the mud sedimentation area were analyzed from granulometric, density and solids concentration points of view. The solids percentage variable (S was analyzed in four scenarios (4, 12, 20 and 28 % and time (t was evaluated at intervals of 20 minutes for 5 hours. The behavior of mud sedimentation was characterized through the sedimentation velocity. The results indicate that the Stokes velocity law does not apply for estimating the mud sedimentation velocity with a 95% confidence. Therefore, a correction function is obtained for the Stokes velocity law expressed through the polynomial mathematical model of second degree.

  1. Metal and trace element assessment of estuary sediments from Santos, Brazil, by neutron activation and atomic absorption techniques

    International Nuclear Information System (INIS)

    Amorim, Eduardo P.; Favaro, Deborah I.T.; Berbel, Glaucia B.B.; Braga, Elisabete S.

    2007-01-01

    In order to better understanding geochemical and environmental processes and their possible changes due to anthropogenic activities trace metal analyses and their distribution in marine sediments are commonly undertaken. The present study reports result concerning the distribution of some major, trace and rare earth elements in the Santos estuarine marine sediments. Thirteen bottom sediment samples (SV0501 to SV0513) were collected in this estuary, including regions of Sao Vicente, Santos, Cubatao, Vicente de Carvalho and Santos' Bay, in the summer of 2005. Multielemental analysis was carried out by instrumental neutron activation analysis (INAA). For total mercury determination cold vapor atomic absorption technique (CV AAS) was employed. In both cases methodology validation was performed by certified reference material analyses. The results obtained for multielemental concentrations in the sediment samples were compared with NASC (North American Shale Composite) values. The concentration values obtained for As and metals Cr, Hg and Zn in the sediment samples were compared to Canadian Council of Minister of the Environment (CCME) oriented values (TEL and PEL values). In general, the samples located near the Cubatao region showed higher concentrations for all elements analyzed probably due to the high impact of industrial activities. (author)

  2. Metal and trace element assessment of estuary sediments from Santos, Brazil, by neutron activation and atomic absorption techniques

    Energy Technology Data Exchange (ETDEWEB)

    Amorim, Eduardo P.; Favaro, Deborah I.T. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mails: ducamorim@yahoo.com.br; defavaro@ipen.br; Berbel, Glaucia B.B.; Braga, Elisabete S. [Universidade de Sao Paulo (USP), SP (Brazil). Inst. Oceanografico. Lab. de Nutrientes, Micronutrientes e Tracos nos Oceanos - LABNUT]. E-mail: edsbraga@usp.br

    2007-07-01

    In order to better understanding geochemical and environmental processes and their possible changes due to anthropogenic activities trace metal analyses and their distribution in marine sediments are commonly undertaken. The present study reports result concerning the distribution of some major, trace and rare earth elements in the Santos estuarine marine sediments. Thirteen bottom sediment samples (SV0501 to SV0513) were collected in this estuary, including regions of Sao Vicente, Santos, Cubatao, Vicente de Carvalho and Santos' Bay, in the summer of 2005. Multielemental analysis was carried out by instrumental neutron activation analysis (INAA). For total mercury determination cold vapor atomic absorption technique (CV AAS) was employed. In both cases methodology validation was performed by certified reference material analyses. The results obtained for multielemental concentrations in the sediment samples were compared with NASC (North American Shale Composite) values. The concentration values obtained for As and metals Cr, Hg and Zn in the sediment samples were compared to Canadian Council of Minister of the Environment (CCME) oriented values (TEL and PEL values). In general, the samples located near the Cubatao region showed higher concentrations for all elements analyzed probably due to the high impact of industrial activities. (author)

  3. Metal concentrations in water and sediments from tourist beaches of Acapulco, Mexico.

    Science.gov (United States)

    Jonathan, M P; Roy, P D; Thangadurai, N; Srinivasalu, S; Rodríguez-Espinosa, P F; Sarkar, S K; Lakshumanan, C; Navarrete-López, M; Muñoz-Sevilla, N P

    2011-04-01

    A survey on the metal concentrations (As, Ba, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V, Zn) in beach water and sediments is reported from the tourist destination of Acapulco city on the Pacific coast of Mexico. The concentration of dissolved trace metals (DTMs) in beach water and acid leachable trace metals (ALTMs) in sediments indicated that they are anthropogenic in nature due to the increased tourist activities in the crowded beach locations. The statistical analysis indicates Fe and Mn play a major role as metal scavengers in both the medium (water and sediment) and the higher value of other metals is site specific in the study area, indicating that they are transported from the local area. Comparison results suggest that the beach water quality has deteriorated more than the sediments and special care needs to be taken to restore the beach quality. Copyright © 2011 Elsevier Ltd. All rights reserved.

  4. Measurement of heavy metals concentrations of the sediment of Persian Gulf by Instrumental Neutron Activation Analysis (INAA)

    International Nuclear Information System (INIS)

    Athari Allaf, M.

    2002-01-01

    The Persian Gulf historically has been vulnerable to pollution, mainly because of its unique oceanographic characteristics. In the recent past, especially after Gulf war, regional countries including Iran began to investigate its environmental assessment. Because of mostly deposition of heavy metals in the sea sediment, one could use of concentration of trace elements as a contamination index. In this paper heavy metals concentrations of sediments were measured at seven stations in the Persian Gulf. Sampling was performed in six times during one year. Instrumental Neutron Activation Analysis technique (INAA) was used for measurement of Ce, Ca, Br. Al, Co, Cs, V, Ti, Na, Sc, K, Mn, Mg, and Zn in the all samples. In addition it was showed that using correlation factors calculations could search the sources of these elements

  5. The influence of grain size, grain color, and suspended-sediment concentration on light attenuation: why fine-grained terrestrial sediment is bad for coral reef ecosystems

    Science.gov (United States)

    Storlazzi, Curt; Norris, Benjamin; Rosenberger, Kurt

    2015-01-01

    Sediment has been shown to be a major stressor to coral reefs globally. Although many researchers have tested the impact of sedimentation on coral reef ecosystems in both the laboratory and the field and some have measured the impact of suspended sediment on the photosynthetic response of corals, there has yet to be a detailed investigation on how properties of the sediment itself can affect light availability for photosynthesis. We show that finer-grained and darker-colored sediment at higher suspended-sediment concentrations attenuates photosynthetically active radiation (PAR) significantly more than coarser, lighter-colored sediment at lower concentrations and provide PAR attenuation coefficients for various grain sizes, colors, and suspended-sediment concentrations that are needed for biophysical modeling. Because finer-grained sediment particles settle more slowly and are more susceptible to resuspension, they remain in the water column longer, thus causing greater net impact by reducing light essential for photosynthesis over a greater duration. This indicates that coral reef monitoring studies investigating sediment impacts should concentrate on measuring fine-grained lateritic and volcanic soils, as opposed to coarser-grained siliceous and carbonate sediment. Similarly, coastal restoration efforts and engineering solutions addressing long-term coral reef ecosystem health should focus on preferentially retaining those fine-grained soils rather than coarse silt and sand particles.

  6. PAHs concentration and toxicity in organic solvent extracts of atmospheric particulate matter and sea sediments.

    Science.gov (United States)

    Ozaki, Noriatsu; Takeuchi, Shin-ya; Kojima, Keisuke; Kindaichi, Tomonori; Komatsu, Toshiko; Fukushima, Takehiko

    2012-01-01

    The concentration of polycyclic aromatic hydrocarbons (PAHs) and the toxicity to marine bacteria (Vibrio fischeri) were measured for the organic solvent extracts of sea sediments collected from an urban watershed area (Hiroshima Bay) of Japan and compared with the concentrations and toxicity of atmospheric particulate matter (PM). In atmospheric PM, the PAHs concentration was highest in fine particulate matter (FPM) collected during cold seasons. The concentrations of sea sediments were 0.01-0.001 times those of atmospheric PM. 1/EC50 was 1-10 L g(-1) PM for atmospheric PM and 0.1-1 L g(-1) dry solids for sea sediments. These results imply that toxic substances from atmospheric PM are diluted several tens or hundreds of times in sea sediments. The ratio of the 1/EC50 to PAHs concentration ((1/EC50)/16PAHs) was stable for all sea sediments (0.1-1 L μg(-1) 16PAHs) and was the same order of magnitude as that of FPM and coarse particulate matter (CPM). The ratio of sediments collected from the west was more similar to that of CPM while that from the east was more similar to FPM, possibly because of hydraulic differences among water bodies. The PAHs concentration pattern analyses (principal component analysis and isomer ratio analysis) were conducted and the results showed that the PAHs pattern in sea sediments was quite different to that of FPM and CPM. Comparison with previously conducted PAHs analyses suggested that biomass burning residues comprised a major portion of these other sources.

  7. Impact of concentration and species of sulfamethoxazole and ofloxacin on their adsorption kinetics on sediments.

    Science.gov (United States)

    Wang, Peng; Zhang, Di; Zhang, Huang; Li, Hao; Ghosh, Saikat; Pan, Bo

    2017-05-01

    Antibiotics are used widely in human and veterinary medicine and are ubiquitous in environmental matrices worldwide. The influence of the concentration of antibiotics on adsorption kinetics is still unclear. This study used sulfamethoxazole (SMX) and ofloxacin (OFL) as adsorbates to investigate the adsorption kinetics on sediment affected by varying concentrations of antibiotics adsorbable species. At the experimental pH values, the major adsorbed species of SMX and OFL on sediment were SMX 0 and OFL + by hydrophobic interaction and electrostatic attraction, respectively. The apparent adsorption rate of SMX was not affected by the initial concentration and the pH values because the hydrophobic interactions were concentration-independent and charge-independent. However, the apparent adsorption rate of OFL significantly slowed down as the initial concentration increased. The adsorbed OFL + effectively neutralized the negative charges of the sediment, leading to a reduced adsorption rate of subsequent OFL + . The neutralization effect was greatly enhanced due to the increased OFL + with the increasing OFL concentration. Additionally, the apparent adsorption rate of OFL significantly increased at higher pH due to the reduced neutralization effect that resulted from the decreased OFL + and increased negative charges of the sediment surface. This study implied that the adsorption kinetics of antibiotics was greatly dominated by the concentration of adsorbable species rather than apparent overall concentration. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Mortandad Canyon: Elemental concentrations in vegetation, streambank soils, and stream sediments - 1979

    International Nuclear Information System (INIS)

    Ferenbaugh, R.W.; Gladney, E.S.

    1997-06-01

    In 1979, stream sediments, streambank soils, and streambank vegetation were sampled at 100 m intervals downstream of the outfall of the TA-50 radioactive liquid waste treatment facility in Mortandad Canyon. Sampling was discontinued at a distance of 3260 m at the location of the sediment traps in the canyon. The purpose of the sampling was to investigate the effect of the residual contaminants in the waste treatment facility effluent on elemental concentrations in various environmental media

  9. Assessment of heavy metals concentration in water, soil sediment ...

    African Journals Online (AJOL)

    22.81 ppb) and rivers to Lake Nakuru (1129±107 ppb) had the highest mean ± SD lead concentration. Arsenic, cadmium, chromium and lead were also observed in bird tissues. Metals in the Lesser Flamingo tissues were below the toxicological ...

  10. Metal concentrations in stream biofilm and sediments and their potential to explain biofilm microbial community structure

    International Nuclear Information System (INIS)

    Ancion, Pierre-Yves; Lear, Gavin; Dopheide, Andrew; Lewis, Gillian D.

    2013-01-01

    Concentrations of metals associated with sediments have traditionally been analysed to assess the extent of heavy metal contamination in freshwater environments. Stream biofilms present an alternative medium for this assessment which may be more relevant to the risk incurred by stream ecosystems as they are intensively grazed by aquatic organisms at a higher trophic level. Therefore, we investigated zinc, copper and lead concentrations in biofilms and sediments of 23 stream sites variously impacted by urbanisation. Simultaneously, biofilm bacterial and ciliate protozoan community structure was analysed by Automated Ribosomal Intergenic Spacer Analysis and Terminal Restriction Fragment Length Polymorphism, respectively. Statistical analysis revealed that biofilm associated metals explained a greater proportion of the variations observed in bacterial and ciliate communities than did sediment associated-metals. This study suggests that the analysis of metal concentrations in biofilms provide a good assessment of detrimental effects of metal contaminants on aquatic biota. - Highlights: ► Zn, Cu and Pb concentrations in biofilm and sediments from 23 streams were assessed. ► Bacteria and ciliate protozoa were simultaneously used as biological indicators. ► Zn and Cu were generally enriched in biofilm compared to sediments. ► Metals in biofilm provide a useful assessment of freshwater ecosystem contamination. ► Results highlight the likely ecological importance of biofilm associated metals. - Metal concentrations in stream biofilms provide a good assessment of the effects of trace metal contaminants on freshwater ecosystems.

  11. Estimation of suspended sediment concentration from Acoustic Doppler Current Profiler (ADCP) instrument: A case study of Lembeh Strait, North Sulawesi

    Science.gov (United States)

    Dwinovantyo, Angga; Manik, Henry M.; Prartono, Tri; Susilohadi; Ilahude, Delyuzar

    2017-01-01

    Measurement of suspended sediment concentration (SSC) is one of the parameters needed to determine the characteristics of sediment transport. However, the measurement of SSC nowadays still uses conventional technique and it has limitations; especially in temporal resolution. With advanced technology, the measurement can use hydroacoustic technology such as Acoustic Doppler Current Profiler (ADCP). ADCP measures the intensity of backscatter as echo intensity unit from sediment particles. The frequency of ADCP used in this study was 400 kHz. The samples were measured and collected from Lembeh Strait, North Sulawesi. The highest concentration of suspended sediment was 98.89 mg L-1 and the lowest was 45.20 mg L-1. Time series data showed the tidal condition affected the SSC. From the research, we also made correction from sound signal losses effect such as spherical spreading and sound absorption to get more accurate results by eliminating these parameters in echo intensity data. Simple linear regression analysis at echo intensity measured from ADCP to direct measurement of SSC was performed to obtain the estimation of the SSC. The comparison result of estimation of SSC from ADCP measurements and SSC from laboratory analyses was insignificantly different based on t-test statistical analysis with 95% confidence interval percentage.

  12. Investigation of sediment transport and optimization of dredging operations in Indian ports using radiotracer technique

    International Nuclear Information System (INIS)

    Pant, H.J.

    2012-01-01

    India has a long coastline of about 7,515 km and there are twelve major ports situated on the coastline. Out of them, six are situated on the West Coast whereas other six are situated on the East Coast. In addition to this, there are more than 140 minor ports and other marine establishments situated along the coastline. Each port and marine project has a navigation channel and depth of this navigation channel needs to be maintained to a level of at least 12-15 meters for smooth sailing of ships. Sediments continuously move along the coast due to alongshore currents generated by the waves and tides; and get deposited in navigation channels. For maintaining the required depth of the channels, the dredging operation is carried out. throughout the year or as and when required. Development of a new port or harbour also involves huge capital dredging. The dredged sediments generated during maintenance or capital dredging needs to be dumped at a suitable location, so that it does not find its way back to the channel and obstruct sailing of ships. Moreover the selected site should be such that the turn around time of the dredger is kept minimum to economize the dredging operation. In order to meet the above requirements, the knowledge of transport parameters such as the general direction of movement, extent of lateral and longitudinal movement, transport velocity, transport thickness and bed load movement rate is required. Radiotracer techniques are commonly used to investigate sediment transport on seabed and evaluate the suitability of the proposed dumping sites. Scandium-46 (half-life: 84 days, Gamma energies: 0.89 MeV (100%), 1.12 MeV (100%)) in the form of scandium glass powder is the most suitable radiotracer for tracing sediments on seabed. The activity used in an investigation ranges from 75-300 GBq (2-8 Ci). The suitably prepared particulate radiotracer is injected on seabed at the proposed site using a specially designed injection system and its movement is

  13. ANN modelling of sediment concentration in the dynamic glacial environment of Gangotri in Himalaya.

    Science.gov (United States)

    Singh, Nandita; Chakrapani, G J

    2015-08-01

    The present study explores for the first time the possibility of modelling sediment concentration with artificial neural networks (ANNs) at Gangotri, the source of Bhagirathi River in the Himalaya. Discharge, rainfall and temperature have been considered as the main controlling factors of variations in sediment concentration in the dynamic glacial environment of Gangotri. Fourteen feed forward neural networks with error back propagation algorithm have been created, trained and tested for prediction of sediment concentration. Seven models (T1-T7) have been trained and tested in the non-updating mode whereas remaining seven models (T1a-T7a) have been trained in the updating mode. The non-updating mode refers to the scenario where antecedent time (previous time step) values are not used as input to the model. In case of the updating mode, antecedent time values are used as network inputs. The inputs applied in the models are either the variables mentioned above as individual factors (single input networks) or a combination of them (multi-input networks). The suitability of employing antecedent time-step values as network inputs has hence been checked by comparative analysis of model performance in the two modes. The simple feed forward network has been improvised with a series parallel non-linear autoregressive with exogenous input (NARX) architecture wherein true values of sediment concentration have been fed as input during training. In the glacial scenario of Gangotri, maximum sediment movement takes place during the melt period (May-October). Hence, daily data of discharge, rainfall, temperature and sediment concentration for five consecutive melt periods (May-October, 2000-2004) have been used for modelling. High Coefficient of determination values [0.77-0.88] have been obtained between observed and ANN-predicted values of sediment concentration. The study has brought out relationships between variables that are not reflected in normal statistical analysis. A

  14. Use of the [(14)C]leucine incorporation technique to measure bacterial production in river sediments and the epiphyton.

    Science.gov (United States)

    Fischer, H; Pusch, M

    1999-10-01

    Bacterial production is a key parameter for the understanding of carbon cycling in aquatic ecosystems, yet it remains difficult to measure in many aquatic habitats. We therefore tested the applicability of the [(14)C]leucine incorporation technique for the measurement of bulk bacterial production in various habitats of a lowland river ecosystem. To evaluate the method, we determined (i) extraction efficiencies of bacterial protein from the sediments, (ii) substrate saturation of leucine in sediments, the biofilms on aquatic plants (epiphyton), and the pelagic zone, (iii) bacterial activities at different leucine concentrations, (iv) specificity of leucine uptake by bacteria, and (v) the effect of the incubation technique (perfused-core incubation versus slurry incubation) on leucine incorporation into protein. Bacterial protein was best extracted from sediments and precipitated by hot trichloroacetic acid treatment following ultrasonication. For epiphyton, an alkaline-extraction procedure was most efficient. Leucine incorporation saturation occurred at 1 microM in epiphyton and 100 nM in the pelagic zone. Saturation curves in sediments were difficult to model but showed the first level of leucine saturation at 50 microM. Increased uptake at higher leucine concentrations could be partly attributed to eukaryotes. Addition of micromolar concentrations of leucine did not enhance bacterial electron transport activity or DNA replication activity. Similar rates of leucine incorporation into protein calculated for whole sediment cores were observed after slurry and perfused-core incubations, but the rates exhibited strong vertical gradients after the core incubation. We conclude that the leucine incorporation method can measure bacterial production in a wide range of aquatic habitats, including fluvial sediments, if substrate saturation and isotope dilution are determined.

  15. Use of the [14C]Leucine Incorporation Technique To Measure Bacterial Production in River Sediments and the Epiphyton

    Science.gov (United States)

    Fischer, Helmut; Pusch, Martin

    1999-01-01

    Bacterial production is a key parameter for the understanding of carbon cycling in aquatic ecosystems, yet it remains difficult to measure in many aquatic habitats. We therefore tested the applicability of the [14C]leucine incorporation technique for the measurement of bulk bacterial production in various habitats of a lowland river ecosystem. To evaluate the method, we determined (i) extraction efficiencies of bacterial protein from the sediments, (ii) substrate saturation of leucine in sediments, the biofilms on aquatic plants (epiphyton), and the pelagic zone, (iii) bacterial activities at different leucine concentrations, (iv) specificity of leucine uptake by bacteria, and (v) the effect of the incubation technique (perfused-core incubation versus slurry incubation) on leucine incorporation into protein. Bacterial protein was best extracted from sediments and precipitated by hot trichloroacetic acid treatment following ultrasonication. For epiphyton, an alkaline-extraction procedure was most efficient. Leucine incorporation saturation occurred at 1 μM in epiphyton and 100 nM in the pelagic zone. Saturation curves in sediments were difficult to model but showed the first level of leucine saturation at 50 μM. Increased uptake at higher leucine concentrations could be partly attributed to eukaryotes. Addition of micromolar concentrations of leucine did not enhance bacterial electron transport activity or DNA replication activity. Similar rates of leucine incorporation into protein calculated for whole sediment cores were observed after slurry and perfused-core incubations, but the rates exhibited strong vertical gradients after the core incubation. We conclude that the leucine incorporation method can measure bacterial production in a wide range of aquatic habitats, including fluvial sediments, if substrate saturation and isotope dilution are determined. PMID:10508068

  16. Near-bed observations of high-concentration sediment transport in the Changjiang Estuary

    Science.gov (United States)

    Zhou, Z.; Ge, J.; Ding, P.

    2017-12-01

    The North Passage, the core of turbidity maximum in the Changjiang Estuary, is now under the strong sedimentation due to the abundant sediment supply from the upstream Changjiang River and the river-tide interacted dynamics. Recent studies suggested that strong siltation could be attributed to bottom high-concentration sediment transport, which however is very difficult to be detected and observed by vessel-anchored survey methods. To better understand the mechanisms of sediment transport and deposition in the channel region of the North Passage and its adjacent areas, we conducted continuous field observations which covered spring and neap tide period in the wintertime of 2016, the summertime of 2015 and 2017, focusing on near-bottom sediment transport. Tripods mounted with multiple instruments, including up-looking and down-looking Acoustic Doppler Current Profilers(ADCP), Vector Current Meter(ADV), Optical Backscatter Sensor(OBS), ASM, ALEC and RBR were used to observe the near-bottom physical process and its induced sediment dynamics. Results of these observations clearly described the current-wave-sediment interaction, which produced different patterns of bottom mud suspension at different tripods. Both hydrodynamic features and suspended sediment showed variations between spring and neap tide. Taking data of 2016 as an example, averaged suspended sediment concentration(SSC) at two tripods was 1.52 g/L and 2.13 g/L during the neap tide, 4.51 g/L and 5.75 g/L with the peak value reaching 25 g/L during the spring tide. At the tripod which was closer to the channel region, three peaks of SSC during the spring tide occurred near the flood slack with notable salinity increase, indicating the impact of saltwater intrusion on the bottom hydrodynamics. The results showed the occurrence of high-concentration suspended sediment was probably related to combined effects of bottom salinity intrusion, turbulent kinetic energy(TKE) and local stratification due to density

  17. Concentrations of organotin compounds in sediment and clams collected from coastal areas in Vietnam

    International Nuclear Information System (INIS)

    Midorikawa, Sayaka; Arai, Takaomi; Harino, Hiroya; Ohji, Madoka; Nguyen Duc Cu; Miyazaki, Nobuyuki

    2004-01-01

    Levels of butyltin (BT) and phenyltin (PT) compounds were determined in sediments and clam Meretrix spp. collected from north and central coastal areas in Vietnam. Concentrations of TBT in sediments ranged from 0.89 to 34 ng g -1 dry wt and those in clams ranged from 1.4 to 56 ng g -1 wet wt. The levels of TBT in sediments and clams from Vietnam were within limits reported from other countries. Further, the TBT level in clams was lower than the tolerable average residue level (TARL) estimated based on tolerable daily intake (TDI). Trace amounts of PTs were also found in both sediment and clam samples. In sediments from north and central Vietnam, the concentrations of TBT were highest in the order of Hue (28 ng g -1 dry wt), Cua Luc (15 ng g -1 dry wt), Sam Son (6.3 ng g -1 dry wt), and Tra Co (5.5 ng g -1 dry wt). Among the clams from north and central Vietnam, the levels of TBT in clams from Cua Luc were dramatically high at 47 ng g -1 wet wt. TBT formed the principal butyltin species in sediment at all sites studied. The ratios of TBT in sediment were higher among BT compounds at all study sites. Of total BTs, TBT was the dominant species in clams from almost all sites studied. In spatial distribution, TPT showed a pattern similar to TBT, suggesting the use of TPT as an antifouling paint. The partition coefficient between sediment and calms was calculated. The partition coefficients of TBT and TPT were 2.01 (0.56-5.5) and 9.23 (3.1-20), respectively. These results show that sediment-bound TBT is a source of contamination to clams in addition to dissolved TBT

  18. Magnitude and variability of methane production and concentration in tropical coastal lagoons sediments

    Directory of Open Access Journals (Sweden)

    Antonella Petruzzella

    Full Text Available AIM: Coastal wetlands are potential zones for methane (CH4 production. The present study aims to evaluate the spatial variation of CH4 production and concentration in ten tropical coastal lagoons, the influence of aquatic macrophytes on the sediment CH4 concentration and how the magnitude of these potential CH4 production rates compare to those in other ecosystems. METHODS: Sediments were sampled in ten coastal lagoons, with one site in the limnetic region and another site in aquatic macrophyte stands when they were present in the littoral region. We measured the CH4 production as a potential rate, and CH4 concentration was directly measured from sediment samples. RESULTS: The highest potential CH4 production (PMP rates were found in alkaline and hypersaline lagoons. However, Cabiúnas, which is a freshwater lagoon densely colonized by aquatic macrophytes, also exhibited a high PMP rate. We also observed that the sediment CH4 concentration in the littoral region was higher than in the limnetic region in all of the investigated lagoons except Paulista, which presented the opposite pattern. The PMP rates observed in the studied lagoons were low compared to other aquatic ecosystems. CONCLUSION: Our results suggest that the sediments of saline lagoons are important CH4 production sites, and in general, aquatic macrophytes have a positive influence on methanogenesis, which was evident based on the CH4 concentrations present in the sediments of these lagoons. Further studies should focus on the processes underlying the CH4 patterns observed in the tropical coastal lagoons, especially concerning the coupling between CH4 production and concentration.

  19. Antifoulant (butyltin and copper) concentrations in sediments from the Great Barrier Reef World Heritage Area, Australia

    International Nuclear Information System (INIS)

    Haynes, David; Loong, Dominica

    2002-01-01

    Antifoulant concentrations are generally low in the Great Barrier Reef, although ship grounding sites present a previously unidentified significant source of antifoulant pollutants in the Great Barrier Reef. - Antifoulant concentrations were determined in marine sediments collected from commercial harbours, marinas, mooring locations on mid-shelf continental islands, and outer reef sites in four regions within the Great Barrier Reef World Heritage Area in 1999. Highest copper concentrations were present in sediments collected from commercial harbour sampling sites (28-233 μg Cu g -1 dry wt.). In contrast, copper concentrations in sediments collected from boat mooring sites on mid-shelf continental islands and outer reef sites were at background concentrations (i.e. -1 dry wt.). Butyltin was only detectable in four of the 42 sediments sampled for analysis, and was only present in sediments collected from commercial harbours (18-1275 ng Sn g -1 dry wt.) and from marinas (4-5 ng Sn g -1 dry wt.). The detection of tributyltin at marina sites implies that this antifoulant may continue to be used illegally on the hulls of smaller recreational vessels. Sediment samples were also collected opportunistically from the site of a 22,000 t cargo ship grounding in May 1999 at Heath Reef, in the far northern Great Barrier Reef. Butyltin concentrations were grossly elevated (660-340,000 ng Sn g -1 dry wt.) at the grounding site. The impact of residual antifoulants at large ship grounding sites should be recognised as a significant, long-term environmental problem unless antfoulant clean-up strategies are undertaken

  20. Determination of multi-element in marine sediment samples collected in Angola by the k0-NAA technique

    International Nuclear Information System (INIS)

    Teixeira, M.C.P.; Ho Manh Dung; Cao Dong Vu; Nguyen Thi Sy; Nguyen Thanh Binh; Vuong Huu Tan

    2006-01-01

    The marine sediment samples were designed to collect in Angola for marine environmental pollution study. The k 0 -standardization method of neutron activation analysis (k 0 -NAA) on Dalat research reactor has been developed to determine of multi-element in the Angola marine sediment samples. The samples were irradiated in cell 7-1 for short- and middle-lived nuclides and rotary specimen rack for long-lived nuclides. The irradiation facilities were characterized for neutron spectrum parameters and post-activated samples were measured on the calibrated gamma-ray spectrometers using HPGe detectors. The analytical results for 9 marine sediment samples with 27 elements: Al, As, Br, Ca, Ce,Cl, Co, Cs, Dy, Fe, Hf, I, K, Mg, Mn, Na, Rb, Sb, Sc, Se, Sm, Th, Ti, U, V and Zn in term of mean concentration, standard deviation and their content range are shown in the report. The analytical quality assurance was done by analysis of a Japan's certified reference material namely marine sediment NMIJ-CRM-7302a. These preliminary results revealed that the k 0 -NAA technique on the Dalat research reactor is a good analytical technique for determination of multi-element in the marine sediment samples. Some heavy metals and trace elements determined in this work possibly connected to the human activities at the sampling region. (author)

  1. Sediment transport investigations in Hugli estuary using radiotracer technique

    International Nuclear Information System (INIS)

    Sharma, V.K.; Pant, H.J.; Kulkarni, U.P.; Pendharkar, A.S.; Chakraborty, Kalyan; Mukhopadhyay, Suman; Chaudhuri, Bikas

    2006-01-01

    This paper describes sediment transport investigations carried out at two different locations in Hugli estuary along the shipping channel leading to Haldia Dock Complex of the Kolkata Port Trust, Kolkata. The objectives of these investigations were to evaluate the suitability of the proposed dumping sites for optimizing the dredging operation and implementing the recommendations of the River Regulatory Measures, Kolkata Port Trust, Kolkata

  2. Seasonal variation of monomethylmercury concentrations in surface sediments of the Tagus Estuary (Portugal)

    International Nuclear Information System (INIS)

    Canario, Joao; Branco, Vasco; Vale, Carlos

    2007-01-01

    Surface sediments (0-2 cm) were collected at 40 sites along the Tagus Estuary in July and December 2004. The sediments were analysed for total mercury, monomethylmercury (MMHg) and interpretative parameters (e.g. redox potential, pH, C org ). No significant differences in total Hg, pH, Al, Fe, Mn and C org were found between sediments collected in the two periods, but MMHg concentrations were higher in July. On average sediments were warmer and more reducing in summer. On the basis of these results, an increase of 7 kg of MMHg (+37%) in surface sediments of the Tagus Estuary was estimated. Presumably higher temperatures in summer promote the increase of microbial activity and higher methylation rates. The alterations observed in this study point to the potential importance of seasonal changes in MMHg production at surface sediments with eventual changes in the MMHg uptake by benthic invertebrates and other organisms in the food web. - Seasonal changes in monomethylmercury production in sediments may increase its uptake by benthic invertebrates and other organisms in the food web

  3. Comparison of manufactured and black carbon nanoparticle concentrations in aquatic sediments

    International Nuclear Information System (INIS)

    Koelmans, A.A.; Nowack, B.; Wiesner, M.R.

    2009-01-01

    In this paper, we show that concentrations of manufactured carbon-based nanoparticles (MCNPs) in aquatic sediments will be negligible compared to levels of black carbon nanoparticles (BCNPs). This is concluded from model calculations accounting for MCNP sedimentation fluxes, removal rates due to aggregation or degradation, and MCNP burial in deeper sediment layers. The resultant steady state MCNP levels are compared with BCNP levels calculated from soot levels in sediments and weight fractions of nanosized fractions of these soot particles. MCNP/BCNP ratios range from 10 -7 to 10 -4 (w:w). This suggests that the often acclaimed effect of MCNPs on organic pollutant binding and bioavailability will likely be below the level of detection if natural BCNPs are present, even if binding to MCNP is one to two orders of magnitude stronger than to BCNPs. Furthermore, exposure and toxic effects of MCNPs in sediments and soils will be negligible compared to that of BCNPs. - Concentrations of manufactured carbon-based nanoparticles in sediments and soils will be negligible compared to levels of black carbon (soot) nanoparticles

  4. Estimated sedimentation rate by radionuclide techniques at Lam Phra Phloeng dam, Northeastern of Thailand

    International Nuclear Information System (INIS)

    Sasimonton Moungsrijun; Kanitha Srisuksawad; Kosit Lorsirirat; Tuangrak Nantawisarakul

    2009-01-01

    The Lam Phra Phloeng dam is located in Nakhon Ratchasima province, northeastern of Thailand. Since it was constructed in 1963, the dam is under severe reduction of its water storage capacity caused by deforestation to agricultural land at the upper catchment. Sediment cores were collected using a gravity corer. Sedimentation rates were estimated from the vertical distribution of unsupported Pb-210 in sediment cores. Total Pb-210 was determined by measuring Po-210 activities. The Po-210 and Ra-226 activities were used to determine the rate of sediment by using alpha and gamma spectrometry. The sedimentation rate was estimated using the Constant Initial Concentration model (CIC), the sedimentation rate crest dam 0.265 gcm -2 y -1 and the upstream 0.213 gcm -2 y -1 (Author)

  5. Intercomparison of techniques for estimation of sedimentation rate in the Sabah and Sarawak coastal waters

    International Nuclear Information System (INIS)

    Zal U'yun Wan Mahmood; Zaharudin Ahmad; Abdul Kadir Ishak; Che Abd Rahim Mohamed

    2011-01-01

    A total of eight sediment cores with 50 cm length were taken in the Sabah and Sarawak coastal waters using a gravity corer in 2004 to estimate sedimentation rates using four mathematical models of CIC, Shukla-CIC, CRS and ADE. The average of sedimentation rate ranged from 0.24 to 0.48 cm year -1 , which is calculated based on the vertical profile of 210 Pbex in sediment core. The finding also showed that the sedimentation rates derived from four models were generally shown in good agreement with similar or comparable value at some stations. However, based on statistical analysis of paired sample t-test indicated that CIC model was the most accurate, reliable and suitable technique to determine the sedimentation rate in the coastal area. (author)

  6. Concentrations of Mn and Fe in the Sediment Cores of Sarawak and Sabah Coastal Waters

    International Nuclear Information System (INIS)

    Zal Uyun Wan Mahmood; Zaharudin Ahmad; Che Abdul Rahim Mohamed

    2010-01-01

    Sediment cores were taken at eight stations along Sarawak and Sabah coastal waters using a gravity box corer on July 2004. The sediment cores were cut into 2 cm interval for measurement of Mn and Fe concentration using the Inductive Couple Plasma-Mass Spectrometer (ICP-MS). Overall, the sediment cores contained much mud which include a mixture of silt (46 - 67 %) and clay (18 - 53 %) compared to sand (0.4 - 16 %). The concentrations of Mn and Fe were in the range of 154 - 366 μg/ g and 0.9 - 3.4 %, respectively. The variation was studied by ANOVA, which showed a significant difference (p = 0.000) for both of Mn and Fe concentrations at all sampling stations. In those ranges, Fe concentration was higher compared to Mn. It is believed that dissolving and diluting process influenced the concentration of Mn in the water column and sediment. Fe showed a significant correlation (r > 0.5, p geo < 1 and classification 0 - 1. (author)

  7. Evaluation of instruments used in particle size analysis by using the sedimentation technique

    International Nuclear Information System (INIS)

    Elmasry, M.A.A.; Abdrahman, A.A.M.; Ahmed, A.Z.

    2007-01-01

    This study is carried out to evaluate the performance of some instruments in which the sedimentation technique is used for the determination of particle size distribution using Stoke's law. A mathematical formula has been developed to calculate the particle size distribution for different cases and the results were compared to the real ones. The results revealed unsatisfactory agreement between the calculated and the measured values. In addition, illogic results were obtained indicating that the instruments in which the sedimentation technique is used are not the proper ones to provide accurate measurements except for mono particle size cases. More above, the results obtained represent the sedimentation rate but not the particle size distribution.

  8. Estimation of suspended sediment flux in streams using continuous turbidity and flow data coupled with laboratory concentrations

    Science.gov (United States)

    Jack Lewis

    2002-01-01

    The widening use of sediment surrogate measurements such as turbidity necessitates consideration of new methods for estimating sediment flux. Generally, existing methods can be simply be used in new ways. The effectiveness of a method varies according to the quality of the surrogate data and its relation to suspended sediment concentration (SSC). For this discussion,...

  9. Field calibration of optical sensors for measuring suspended sediment concentration in the western Mediterranean

    Directory of Open Access Journals (Sweden)

    J. Guillén

    2000-12-01

    Full Text Available The water turbidity measured with optical methods (transmittance and backscattering is usually expressed as beam attenuation coefficient (BAC or formazin turbidity units (FTU. The transformation of these units to volumetric suspended sediment concentration (SSC units is not straightforward, and accurate calibrations are required in order to obtain valuable information on suspended sediment distributions and fluxes. In this paper, data from field calibrations between BAC, FTU and SSC are presented and best-fit calibration curves are shown. These calibrations represent an average from different marine environments of the western Mediterranean (from estuary to continental slope. However, the general curves can only be applied for descriptive or semi-quantitative purposes. Comparison of turbidity measurements using the same sensor with different calibration ranges shows the advantage of simultaneously combining two instruments calibrated in different ranges when significant changes in suspended sediment concentrations are expected.

  10. Effects of must concentration techniques on wine isotopic parameters.

    Science.gov (United States)

    Guyon, Francois; Douet, Christine; Colas, Sebastien; Salagoïty, Marie-Hélène; Medina, Bernard

    2006-12-27

    Despite the robustness of isotopic methods applied in the field of wine control, isotopic values can be slightly influenced by enological practices. For this reason, must concentration technique effects on wine isotopic parameters were studied. The two studied concentration techniques were reverse osmosis (RO) and high-vacuum evaporation (HVE). Samples (must and extracted water) have been collected in various French vineyards. Musts were microfermented at the laboratory, and isotope parameters were determined on the obtained wine. Deuterium and carbon-13 isotope ratios were studied on distilled ethanol by nuclear magnetic resonance (NMR) and isotope ratio mass spectrometry (IRMS), respectively. The oxygen-18 ratio was determined on extracted and wine water using IRMS apparatus. The study showed that the RO technique has a very low effect on isotopic parameters, indicating that this concentration technique does not create any isotopic fractionation, neither at sugar level nor at water level. The effect is notable for must submitted to HVE concentration: water evaporation leads to a modification of the oxygen-18 ratio of the must and, as a consequence, ethanol deuterium concentration is also modified.

  11. River suspended sediment estimation by climatic variables implication: Comparative study among soft computing techniques

    Science.gov (United States)

    Kisi, Ozgur; Shiri, Jalal

    2012-06-01

    Estimating sediment volume carried by a river is an important issue in water resources engineering. This paper compares the accuracy of three different soft computing methods, Artificial Neural Networks (ANNs), Adaptive Neuro-Fuzzy Inference System (ANFIS), and Gene Expression Programming (GEP), in estimating daily suspended sediment concentration on rivers by using hydro-meteorological data. The daily rainfall, streamflow and suspended sediment concentration data from Eel River near Dos Rios, at California, USA are used as a case study. The comparison results indicate that the GEP model performs better than the other models in daily suspended sediment concentration estimation for the particular data sets used in this study. Levenberg-Marquardt, conjugate gradient and gradient descent training algorithms were used for the ANN models. Out of three algorithms, the Conjugate gradient algorithm was found to be better than the others.

  12. Rehabilitation of river sediments contaminated by heavy metals from tanning industries using the phytoextraction technique

    Science.gov (United States)

    Beltrá Castillo, Juan Carlos; García Orenes, Fuensanta; Mora Navarro, José; Murcia Navarro, Francisco Jose; Zornoza Belmonte, Raúl; Faz Cano, Ángel; Gómez-Garrido, Melisa

    2017-04-01

    Leather tanning is an industrial sector of great tradition in Spain that has progressively evolved until it has reached a high degree of technification in the present. However, in its early days, the leather tanning industry has always been considered a dirty and polluting activity, mainly due to the water spills that ended up in the river channels. The Guadalentin Valley between Lorca and Murcia (SE Spain) is characterised by intensive crop and pig production, and an extensive agroalimentary and leather tannery industry. These anthropogenic sources have released salts and metals such as copper (Cu), zinc (Zn) and chromium (Cr) into Guadalentin river. Up to 2003, wastewater was discharged directly to the dry river, immediately upstream of the urban nucleus of Lorca, without any previous treatment. It contained high concentrations of inorganic salts and heavy metals (Cu, Zn and Cr). Spills, in some events, had a flow of 10 000 m3 d-1, with concentration of Cr over 500 mg L-1. Phytoremediation is a sustainable alternative that allows the environmental rehabilitation of fluvial dry sediments through the transfer of heavy metals from the contaminated soils to the native vegetation present. Atriplex halimus, salsola oppositifolia, suaeda vera and tamarix africana were the most representative autochthonous phytoextractor species that were planted to study the degree of decontamination of dry river sediments before planting and 12 months after planting. The sediments characterization was done by a sampling grid of 40 000 m2 (500 m x 8 m) where samples were taken at 3 depths (0-20 cm, 20-50 cm and 5-100 cm) every 50 m. A vegetation study was carried out by random plots of 10 m x 10 m. The results indicated that after 12 months the vegetation cover increased between 35% and 70%. The degree of contamination of Cu, Zn and Cr of the river dry sediments decreased slightly, being the atriplex halimus the plant specie that presented the highest value of the bioaccumulation factor

  13. Interannual heavy element and nutrient concentration trends in the top sediments of Venice Lagoon (Italy)

    International Nuclear Information System (INIS)

    Masiol, Mauro; Facca, Chiara; Visin, Flavia; Sfriso, Adriano; Pavoni, Bruno

    2014-01-01

    Highlights: • Heavy element concentrations in sediments of a transitional system were studied. • Element contamination in the recent years has generally declined. • Mercury and cadmium contamination still remain above the limits in hot spots. • The role of sediment resuspension due to anthropogenic activity is discussed. • A basic knowledge to assess the impact of the MOSE construction is provided. - Abstract: The elemental composition of surficial sediments of Venice Lagoon (Italy) in 1987, 1993, 1998 and 2003 were investigated. Zn and Cr concentrations resulted in higher than background levels, but only Cd and Hg were higher than legal quality standards (Italian Decree 2010/260 and Water Framework Directive 2000/60/EC). Contaminants with similar spatial distribution are sorted into three groups by means of correlation analysis: (i) As, Co, Cd, Cu, Fe, Pb, Zn; (ii) Ni, Cr; (iii) Hg. Interannual concentrations are compared by applying a factor analysis to the matrix of differences between subsequent samplings. A general decrease of heavy metal levels is observed from 1987 to 1993, whereas particularly high concentrations of Ni and Cr are recorded in 1998 as a consequence of intense clam fishing, subsequently mitigated by better prevention of illegal harvesting. Due to the major role played by anthropogenic sediment resuspension, bathymetric variations are also considered

  14. Testing of a uranium downhole logging system to measure in-situ plutonium concentrations in sediments

    International Nuclear Information System (INIS)

    Kasper, R.B.; Kay, M.A.; Bruns, L.E.; Stokes, J.A.; Steinman, D.K.; Adams, J.

    1980-11-01

    A prototype urainium borehole logging system, developed for uranium exploration, was modified for Pu assay and testing at the site. It uses the delayed fission neutron (DFN) method. It was tested in a retired Pu facility, the 216-Z-1A Crib. General agreement between laboratory determined Pu concentrations in sediment samples and neutron flux measurements was found for the relative distribution with depth

  15. Petroleum hydrocarbon concentrations in marine sediments along Chennai Coast, Bay of Bengal, India.

    Science.gov (United States)

    Venkatachalapathy, R; Veerasingam, S; Ramkumar, T

    2010-10-01

    The spatial and temporal distribution of petroleum hydrocarbons (PHC) in marine sediments along the Chennai coast, Bay of Bengal was quantified by Ultra-Violet Fluorescence (UVF) Spectroscopy. The concentration of PHC in surface sediments varied from 1.88 to 39.76 ppm. The highest values obtained in the northern part of the study area, where shipping activities and land-based waste waters disposed into sea through the rivers like Kuvam and Adayar. The Adayar (7.26-16.83 ppm) and Kuvam (5.5-39.72 ppm) cores reveal a clear horizon of increase in PHC above 50 and 35 cm respectively. PHC values showed a decreasing pattern with depth in all sediment cores suggesting the excess anthropogenic loading occurring in the recent past. The present study revealed that the PHC values of Chennai coastal sediments are lower than the values reported from selected costal areas including the sediment of the Mumbai coast (7.6-42.8 ppm), Arabian Sea. The results will be useful for pollution monitoring program along the coastal region and also to check the level of petroleum hydrocarbons in marine sediments.

  16. Technical note: False low turbidity readings from optical probes during high suspended-sediment concentrations

    Science.gov (United States)

    Voichick, Nicholas; Topping, David; Griffiths, Ronald

    2018-01-01

    Turbidity, a measure of water clarity, is monitored for a variety of purposes including (1) to help determine whether water is safe to drink, (2) to establish background conditions of lakes and rivers and detect pollution caused by construction projects and stormwater discharge, (3) to study sediment transport in rivers and erosion in catchments, (4) to manage siltation of water reservoirs, and (5) to establish connections with aquatic biological properties, such as primary production and predator–prey interactions. Turbidity is typically measured with an optical probe that detects light scattered from particles in the water. Probes have defined upper limits of the range of turbidity that they can measure. The general assumption is that when turbidity exceeds this upper limit, the values of turbidity will be constant, i.e., the probe is pegged; however, this assumption is not necessarily valid. In rivers with limited variation in the physical properties of the suspended sediment, at lower suspended-sediment concentrations, an increase in suspended-sediment concentration will cause a linear increase in turbidity. When the suspended-sediment concentration in these rivers is high, turbidity levels can exceed the upper measurement limit of an optical probe and record a constant pegged value. However, at extremely high suspended-sediment concentrations, optical turbidity probes do not necessarily stay pegged at a constant value. Data from the Colorado River in Grand Canyon, Arizona, USA, and a laboratory experiment both demonstrate that when turbidity exceeds instrument-pegged conditions, increasing suspended-sediment concentration (and thus increasing turbidity) may cause optical probes to record decreasing false turbidity values that appear to be within the valid measurement range of the probe. Therefore, under high-turbidity conditions, other surrogate measurements of turbidity (e.g., acoustic-attenuation measurements or suspended-sediment samples

  17. Link between concentrations of sediment flux and deep crustal processes beneath the European Alps.

    Science.gov (United States)

    Garefalakis, Philippos; Schlunegger, Fritz

    2018-01-09

    Large sediment fluxes from mountain belts have the potential to cause megafans to prograde into the neighbouring sedimentary basins. These mechanisms have been documented based from numerical modelling and stratigraphic records. However, little attention has been focused on inferring temporal changes in the concentrations of supplied sediment from coarse-grained deposits. Here, we extract changes of this variable in the field from a Late Oligocene, c. 4 km-thick suite of fluvial conglomerates situated in the North Alpine foreland basin, which evolved in response to the tectonic and erosional history of the Alps. We measure a decrease in channel depths from >2 m to 20 cm from the base to the top of the suite. These constraints are used to calculate an increase in fan surface slopes from 1.0° based on the Shields criteria for sediment entrainment. We combine slope and bulk grain size data with the Bagnold equation for sediment transport to infer higher concentrations of the supplied sediment. We use these shifts to propose a change towards faster erosion and a steeper landscape in the Alpine hinterland, driven by mantle-scale processes beneath the Alps.

  18. Analysis of heavy metals concentration in water and sediment in the Hara biosphere reserve, southern Iran.

    Science.gov (United States)

    Nowrouzi, Mohsen; Mansouri, Borhan; Nabizadeh, Sahar; Pourkhabbaz, Alireza

    2014-02-01

    This study determined the concentration of heavy metals (Al, Cr, Cu, and Zn) in water and sediments at nine sites in the Hara biosphere reserve of southern Iran during the summer and winter 2010. Determination of Al, Cr, Cu, and Zn in water was carried out by graphite furnace atomic absorption spectrometer (Shimadzu, AA 610s) and in sediment by flame atomic absorption spectrometer (Perkin Elmer, AA3030). Results showed that the heavy metal concentrations in the water samples decreased in the sequence of Zn > Al > Cu > Cr, while in sediment samples were Cr > Zn > Cu > Al. Data analysis indicated that with the exception of Al, there was a Pearson's correlation coefficient between pH and Cu, Zn, and Cr at α = 0.01, 0.05, and 0.001 in sediment (in winter), respectively. There were also significant differences between heavy metals of Cr, Cu, and Zn during the two seasons (p < 0.001) in the water and sediment.

  19. Investigation on concentration of elements in wetland sediments and aquatic plants

    Directory of Open Access Journals (Sweden)

    H. Janadeleh

    2016-01-01

    Full Text Available The major aim of the present study was to investigate element (Fe, Ni, Pb, V, Zn concentrations in sediment and different tissues of Phragmities australis and Typha latifolia in Hor al-Azim Wetland Southwest Iran. Sampling of sediments and aquatic plants was carried out during spring and summer 2014. Results showed that the mean  concentrations of elements in Phragmities australis  in root and stem-leaf were as follows: Iron:4448 mg/kg, Nickel: 28 mg/kg, Lead:8 mg/kg, Vanadium:10 mg/kg  and Zinc 15.5 mg/kg in root and: Fe:645 mg/kg, Ni:15 mg/kg, Pb:4 mg/kg, V:4 mg/kg and Zinc 16 mg/kg respectively. Also, the mean concentrations of Fe, Ni, Pb, V and Zn in roots of Typha latifolia were 8696 mg/kg, 34 mg/kg, 5 mg/kg, 19 mg/kg and 27 mg/kg respectively. The mean concentrations of Fe, Ni, V, Pb, Zn in stem-leaves of Typha latifolia were as follows: 321 mg/kg, 3 mg/kg, 7 mg/kg, 2 mg/kg and 14 mg/kg respectively. The mean concentrations of Fe, Ni, V, Pb and zinc were as: 40991 mg/kg, 65 mg/kg, 60 mg/kg, 31 mg/kg, 60 mg/kg respectively in surface sediment of study area. Concentration pattern of elements in sediment were as: Fe>Ni>Zn>V>Pb. The highest concentration of elements in the plant was seen in the roots. Also, Typha latifolia can uptake more concentration of elements than Phragmities australis. Based on the enrichment factor, Ni in summer had the highest EF values among the elements studied and it has a moderate enrichment.

  20. Increasing precision of turbidity-based suspended sediment concentration and load estimates.

    Science.gov (United States)

    Jastram, John D; Zipper, Carl E; Zelazny, Lucian W; Hyer, Kenneth E

    2010-01-01

    Turbidity is an effective tool for estimating and monitoring suspended sediments in aquatic systems. Turbidity can be measured in situ remotely and at fine temporal scales as a surrogate for suspended sediment concentration (SSC), providing opportunity for a more complete record of SSC than is possible with physical sampling approaches. However, there is variability in turbidity-based SSC estimates and in sediment loadings calculated from those estimates. This study investigated the potential to improve turbidity-based SSC, and by extension the resulting sediment loading estimates, by incorporating hydrologic variables that can be monitored remotely and continuously (typically 15-min intervals) into the SSC estimation procedure. On the Roanoke River in southwestern Virginia, hydrologic stage, turbidity, and other water-quality parameters were monitored with in situ instrumentation; suspended sediments were sampled manually during elevated turbidity events; samples were analyzed for SSC and physical properties including particle-size distribution and organic C content; and rainfall was quantified by geologic source area. The study identified physical properties of the suspended-sediment samples that contribute to SSC estimation variance and hydrologic variables that explained variability of those physical properties. Results indicated that the inclusion of any of the measured physical properties in turbidity-based SSC estimation models reduces unexplained variance. Further, the use of hydrologic variables to represent these physical properties, along with turbidity, resulted in a model, relying solely on data collected remotely and continuously, that estimated SSC with less variance than a conventional turbidity-based univariate model, allowing a more precise estimate of sediment loading, Modeling results are consistent with known mechanisms governing sediment transport in hydrologic systems.

  1. Trace contaminant concentration affects mineral transformation and pollutant fate in hydroxide-weathered Hanford sediments

    International Nuclear Information System (INIS)

    Perdrial, Nicolas; Rivera, Nelson; Thompson, Aaron; O’Day, Peggy A.; Chorover, Jon

    2011-01-01

    Highlights: ► Fate of Sr, Cs and I tracked during hydroxide-weathering of sediments. ► pCO 2 and contaminant concentration affected mineral transformation. ► Sodalite/cancrinite formed at μM levels, chabazite at mM levels. ► Absence of CO 2 resulted in calcite dissolution and strätlingite formation. ► Trace contaminant concentrations modified their own sequestration path. - Abstract: Prior work has shown that when silicaceous sediments are infused with caustic radioactive waste, contaminant fate is tightly coupled to ensuing mineral weathering reactions. However, the effects of local aqueous geochemical conditions on these reactions are poorly studied. Thus, we varied contaminant concentration and pCO 2 during the weathering of previously uncontaminated Hanford sediments over 6 months and 1 year in a solution of caustic waste (pH 13, high ionic strength). Co-contaminants Sr, Cs and I were added at “low” (Cs/Sr: 10 −5 m; I: 10 −7 m) and “high” (Cs/Sr: 10 −3 m; I: 10 −5 m) concentrations, and headspace was held at atmospheric or undetectable ( 2 partial pressure. Solid phase characterization revealed the formation of the zeolite chabazite in “high” samples, whereas feldspathoids, sodalite and cancrinite, were formed preferentially in “low” samples. Sr, Cs and I were sequestered in all reacted sediments. Native calcite dissolution in the CO 2 -free treatment drove the formation of strätlingite (Ca 2 Al 2 SiO 7 ·8H 2 O) and diminished availability of Si and Al for feldspathoid formation. Results indicate that pCO 2 and contaminant concentrations strongly affect contaminant speciation in waste-weathered sediments, and are therefore likely to impact reaction product stability under any remediation scenario.

  2. Nutrient and sediment concentrations and loads in the Steele Bayou Basin, northwestern Mississippi, 2010–14

    Science.gov (United States)

    Hicks, Matthew B.; Murphy, Jennifer C.; Stocks, Shane J.

    2017-06-01

    The U.S. Geological Survey, in cooperation with the U.S. Army Corps of Engineers-Vicksburg District, monitored streamflow, water quality, and sediment at two stations on the Steele Bayou in northwestern Mississippi from October 2010 through September 2014 to characterize nutrient and sediment concentrations and loads in areas where substantial implementation of conservation efforts have been implemented. The motivation for this effort was to quantify improvements, or lack thereof, in water quality in the Steele Bayou watershed as a result of implementing large- and small-scale best-management practices aimed at reducing nutrient and sediment concentrations and loads. The results of this study document the hydrologic, water-quality, and sedimentation status of these basins following over two decades of ongoing implementation of conservation practices.Results from this study indicate the two Steele Bayou stations have comparable loads and yields of total nitrogen, phosphorus, and suspended sediment when compared to other agricultural basins in the southeastern and central United States. However, nitrate plus nitrite yields from basins in the Mississippi River alluvial plain, including the Steele Bayou Basin, are generally lower than other agricultural basins in the southeastern and central United States.Seasonal variation in nutrient and sediment loads was observed at both stations and for most constituents. About 50 percent of the total annual nutrient and sediment load was observed during the spring (February through May) and between 25 and 50 percent was observed during late fall and winter (October through January). These seasonal patterns probably reflect a combination of seasonal patterns in precipitation, runoff, streamflow, and in the timing of fertilizer application.Median concentrations of total nitrogen, nitrate plus nitrite, total phosphorus, orthophosphate, and suspended sediment were slightly higher at the upstream station, Steele Bayou near Glen Allan

  3. Sediment movement along the U.S. east coast continental shelf—II. Modelling suspended sediment concentration and transport rate during storms

    Science.gov (United States)

    Lyne, Vincent D.; Butman, Bradford; Grant, William D.

    1990-05-01

    Long-term near-bottom wave and current observations and a one-dimensional sediment transport model are used to calculate the concentration and transport of sediment during winter storms at 60-80 m water depth along the southern flank of Georges Bank and in the Mid-Atlantic Bight. Calculations are presented for five stations, separated by more than 600 km alongshelf, that have different bottom sediment texture, bedforms and current conditions. A modified version of the sediment transport model presented by GRANT and GLENN (1983, Technical Report to the American Gas Association), GLENN (1983, D.Sc. Thesis, M.I.T.), and GLENN and GRANT (1987, Journal of Geophysical Research, 92, 8244-8264) is used to examine the influence of wave-current interaction, sediment stratification, and limitations on the erodibility of the bottom sediments on the concentration of sediment in the water column and on transport. Predicted suspended sediment concentrations are higher than observed, based on beam transmissometer measurements, unless an erosion limit of order a few millimeters for sediments finer than 94 μm is imposed. The agreement between predicted and measured beam attenuation is better at stations that have significant amounts of silt plus clay in the surficial sediments than for stations with sandy sediments. Sediment concentrations during storms estimated by MOODYet al. (1987, Continental Shelf Research, 7, 609-628) are within 50% of the model predictions. Sediment transport rates for sediments 94 μm and finer are determined largely by the concentrations in the surficial sediment and the erosion depth limit. Large alongshelf transports in the direction of storm-driven currents are inferred for stations in the Mid-Atlantic Bight. During a 115-day period in winter 1979-1980, the net transport of sediment along the shelf was westward; benthic storms (defined as periods when the bottom wave stress exceeded the current stress by 2 dyn cm -2) occurred between 23 and 73% of the

  4. Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

    Science.gov (United States)

    Méndez-García, C.; Renteria-Villalobos, M.; García-Tenorio, R.; Montero-Cabrera, M. E.

    2014-07-01

    Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232Th-series, 238U-series, 40K and 137Cs activity concentrations (AC, Bq kg-1) were determined by gamma spectrometry with a high purity Ge detector. 238U and 234U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210Pb activities. Results were verified by 137Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento - Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234U/overflow="scroll">238U and 238U/overflow="scroll">226Ra in sediments have values between 0.9-1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232Th/overflow="scroll">238U, 228Ra/overflow="scroll">226Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.

  5. Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Méndez-García, C.; Montero-Cabrera, M. E., E-mail: elena.montero@cimav.edu.mx [Centro de Investigación en Materiales Avanzados, CIMAV, Miguel de Cervantes 120, 31109, Chihuahua, Chihuahua (Mexico); Renteria-Villalobos, M. [Facultad de Zootecnia y Ecología Universidad Autónoma de Chihuahua, Periferico Francisco R. Almada Km 1, 31410, Chihuahua (Mexico); García-Tenorio, R. [Applied Nuclear Physics Group, University of Seville, ETS Arquitectura, Avda. Reina Mercedes s/n, 41012 Seville (Spain)

    2008-01-01

    Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. ²³²Th-series, ²³⁸U-series, ⁴⁰K and ¹³⁷Cs activity concentrations (AC, Bq kg⁻¹) were determined by gamma spectrometry with a high purity Ge detector. ²³⁸U and ²³⁴U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to ²¹⁰Pb activities. Results were verified by ¹³⁷Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High ²³⁸U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) ²³⁴U/²³⁸U and ²³⁸U/²²⁶Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. ²³²Th/²³⁸U, ²²⁸Ra/²²⁶Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs.

  6. Uranium series isotopes concentration in sediments at San Marcos and Luis L. Leon reservoirs, Chihuahua, Mexico

    International Nuclear Information System (INIS)

    Méndez-García, C.; Montero-Cabrera, M. E.; Renteria-Villalobos, M.; García-Tenorio, R.

    2014-01-01

    Spatial and temporal distribution of the radioisotopes concentrations were determined in sediments near the surface and core samples extracted from two reservoirs located in an arid region close to Chihuahua City, Mexico. At San Marcos reservoir one core was studied, while from Luis L. Leon reservoir one core from the entrance and another one close to the wall were investigated. 232 Th-series, 238 U-series, 40 K and 137 Cs activity concentrations (AC, Bq kg −1 ) were determined by gamma spectrometry with a high purity Ge detector. 238 U and 234 U ACs were obtained by liquid scintillation and alpha spectrometry with a surface barrier detector. Dating of core sediments was performed applying CRS method to 210 Pb activities. Results were verified by 137 Cs AC. Resulting activity concentrations were compared among corresponding surface and core sediments. High 238 U-series AC values were found in sediments from San Marcos reservoir, because this site is located close to the Victorino uranium deposit. Low AC values found in Luis L. Leon reservoir suggest that the uranium present in the source of the Sacramento – Chuviscar Rivers is not transported up to the Conchos River. Activity ratios (AR) 234 U/ 238 U and 238 U/ 226 Ra in sediments have values between 0.9–1.2, showing a behavior close to radioactive equilibrium in the entire basin. 232 Th/ 238 U, 228 Ra/ 226 Ra ARs are witnesses of the different geological origin of sediments from San Marcos and Luis L. Leon reservoirs

  7. Reaching ultra low phosphorus concentrations by filtration techniques

    NARCIS (Netherlands)

    Scherrenberg, S.M.

    2011-01-01

    This research deals with tertiary treatment techniques used for the removal of phosphorus from wastewater treatment plant (WWTP) effluent. The main objective of this research is to obtain ultra low total phosphorus (<0.15 mg total phosphorus/L) concentrations by coagulation, flocculation and

  8. Geospatial approach towards enumerative analysis of suspended sediment concentration for Ganges-Brahmaputra Bay

    Digital Repository Service at National Institute of Oceanography (India)

    Pandey, P.; Kunte, P.D.

    , it can be used for a better output. The month of November also has a good amount of sediments. The study of Landsat 7 could not be done for monsoon and post-monsoon season due to non-availability of cloud-free data. The software package is developed... concentration and transport has been made much easier using the satellite imagery due to continuous and synoptic view. Temporal satellites monitoring of the area offers a better opportunity for the monthly, seasonal and yearly study of the suspended sediments...

  9. Sediment Ksub(d)s and concentration factors for radionuclides in the marine environment

    International Nuclear Information System (INIS)

    1985-01-01

    Both the biological and geochemical processes, which are dependent on the chemical form of the element in question, and the radioactive decay of the nuclide are important parameters in the models used for the calculation of dumping limits for radioactive wastes disposed of in the deep sea. The geochemical processes were not adequately represented in earlier models and only rough approximations of parameters were used in the calculations. This report provides an approach for the calculation of deep-sea sediment distribution coefficients and coastal sediment concentration factors for radionuclides in marine biological materials based, whenever possible, on field data

  10. A Preliminary Study on the Measurement of Sediment Concentration in Hill-Slope Runoff with an Electrolyte Tracer

    Directory of Open Access Journals (Sweden)

    Xiaonan Shi Fan Zhang

    2012-01-01

    Full Text Available Sediment concentration in hill-slope runoff is an important index for soil erosion. Developing a reliable and portable measuring system of sediment concentration is a core issue for soil and water conservation study, especially for the Tibetan Plateau under unfavorable climate and terrain conditions for field investigation. Challenges include uneven distribution of sediment across a runoff section as well as difficulty in detecting a wide range of particle sizes. An electrolyte tracer, with the advantage of uniform distribution and its widely used electric-conductivity sensor, can avoid the problems of direct measurement of sediment. A new measurement method of sediment concentration in runoff with an electrolyte tracer is proposed based on a premise that sediment concentration is closely correlated with hydrodynamic dispersion coefficient of solute in runoff. In this study, an experiment system of hill-slope runoff with an electrolyte tracer and sediments is first designed. Second, two model parameters in the advective-dispersive equation of solute transport, flow velocity and diffusion coefficient, are inversely estimated by calibrating the observed concentrations of an electrolyte tracer. And third, the relationship between sediment concentrations and hydrodynamic dispersion coefficients are defined through specified regression. As a result, a measurement system of sediment concentration in hill-slope runoff with an electrolyte tracer is primarily established by integrating the relationship of variables, experiment system, and model theory.

  11. Sediment concentrations, flow conditions, and downstream evolution of two turbidity currents, Monterey Canyon, USA

    Science.gov (United States)

    Xu, Jingping; Octavio E. Sequeiros,; Noble, Marlene A.

    2014-01-01

    The capacity of turbidity currents to carry sand and coarser sediment from shallow to deep regions in the submarine environment has attracted the attention of researchers from different disciplines. Yet not only are field measurements of oceanic turbidity currents a rare achievement, but also the data that have been collected consist mostly of velocity records with very limited or no suspended sediment concentration or grain size distribution data. This work focuses on two turbidity currents measured in Monterey Canyon in 2002 with emphasis on suspended sediment from unique samples collected within the body of these currents. It is shown that concentration and grain size of the suspended material, primarily controlled by the source of the gravity flows and their interaction with bed material, play a significant role in shaping the characteristics of the turbidity currents as they travel down the canyon. Before the flows reach their normal or quasi-steady state, which is defined by bed slope, bed roughness, and suspended grain size, they might pass through a preliminary adjustment stage where they are subject to capacity-driven deposition, and release heavy material in excess. Flows composed of fine (silt/clay) sediments tend to be thicker than those with sands. The measured velocity and concentration data confirm that flow patterns differ between the front and body of turbidity currents and that, even after reaching normal state, the flow regime can be radically disrupted by abrupt changes in canyon morphology.

  12. Toxic effects of zinc from trout farm sediments on ATP, protein, and hemoglobin concentrations of Limnodrilus hoffmeisteri.

    Science.gov (United States)

    Martinez-Tabche, L; Gutiérrez Cabrera, I; Gómez Oliván, L; Galar Martinez, M; Germán Faz, C

    2000-04-14

    Zinc (Zn) is a nutritionally essential metal, and deficiency results in severe health consequences to aquatic organisms. In this study toxicity data for Limnodrilus hoffmeisteri produced by Zn in systems using three natural sediments (trout farms: El Oyamel, El Truchón, and El Potrero) are presented. Hemoglobin, adenosine triphosphate (ATP), and protein concentrations were measured in L. hoffmeisteri exposed to spiked sediments, as indicators of exposure. Physicochemical characteristics of water and sediments were also considered. Zn concentrations were measured in water and sediment. El Oyamel, El Truchón, and El Potrero pond sediments did not have similar physicochemical characteristics. Zn concentrations of water obtained from the rustic ponds were near 0.4575 mg/L; however, this metal was always found to be higher in the sediments (0.0271-0.9754 mg/kg). The bioassay with worms demonstrated that pond sediments from El Oyamel, El Potrero, and El Truchón produced toxicity since ATP and protein concentrations were low compared to controls (organisms without metal). All spiked sediments had a significant reduction effect on ATP, protein, and hemoglobin concentrations. This investigation clearly shows that sediments of El Truchón, El Oyamel, and El Potrero possess toxicity potential. These results suggest the usefulness of these bioassays to evaluate the toxicity of sediments polluted with heavy metals.

  13. Concentrations and sources of polycyclic aromatic hydrocarbons in surface coastal sediments of the northern Gulf of Mexico

    Science.gov (United States)

    2014-01-01

    Background Coastal sediments in the northern Gulf of Mexico have a high potential of being contaminated by petroleum hydrocarbons, such as polycyclic aromatic hydrocarbons (PAHs), due to extensive petroleum exploration and transportation activities. In this study we evaluated the spatial distribution and contamination sources of PAHs, as well as the bioavailable fraction in the bulk PAH pool, in surface marsh and shelf sediments (top 5 cm) of the northern Gulf of Mexico. Results PAH concentrations in this region ranged from 100 to 856 ng g−1, with the highest concentrations in Mississippi River mouth sediments followed by marsh sediments and then the lowest concentrations in shelf sediments. The PAH concentrations correlated positively with atomic C/N ratios of sedimentary organic matter (OM), suggesting that terrestrial OM preferentially sorbs PAHs relative to marine OM. PAHs with 2 rings were more abundant than those with 5–6 rings in continental shelf sediments, while the opposite was found in marsh sediments. This distribution pattern suggests different contamination sources between shelf and marsh sediments. Based on diagnostic ratios of PAH isomers and principal component analysis, shelf sediment PAHs were petrogenic and those from marsh sediments were pyrogenic. The proportions of bioavailable PAHs in total PAHs were low, ranging from 0.02% to 0.06%, with higher fractions found in marsh than shelf sediments. Conclusion PAH distribution and composition differences between marsh and shelf sediments were influenced by grain size, contamination sources, and the types of organic matter associated with PAHs. Concentrations of PAHs in the study area were below effects low-range, suggesting a low risk to organisms and limited transfer of PAHs into food web. From the source analysis, PAHs in shelf sediments mainly originated from direct petroleum contamination, while those in marsh sediments were from combustion of fossil fuels. PMID:24641695

  14. Interannual heavy element and nutrient concentration trends in the top sediments of Venice Lagoon (Italy).

    Science.gov (United States)

    Masiol, Mauro; Facca, Chiara; Visin, Flavia; Sfriso, Adriano; Pavoni, Bruno

    2014-12-15

    The elemental composition of surficial sediments of Venice Lagoon (Italy) in 1987, 1993, 1998 and 2003 were investigated. Zn and Cr concentrations resulted in higher than background levels, but only Cd and Hg were higher than legal quality standards (Italian Decree 2010/260 and Water Framework Directive 2000/60/EC). Contaminants with similar spatial distribution are sorted into three groups by means of correlation analysis: (i) As, Co, Cd, Cu, Fe, Pb, Zn; (ii) Ni, Cr; (iii) Hg. Interannual concentrations are compared by applying a factor analysis to the matrix of differences between subsequent samplings. A general decrease of heavy metal levels is observed from 1987 to 1993, whereas particularly high concentrations of Ni and Cr are recorded in 1998 as a consequence of intense clam fishing, subsequently mitigated by better prevention of illegal harvesting. Due to the major role played by anthropogenic sediment resuspension, bathymetric variations are also considered. Copyright © 2014 Elsevier Ltd. All rights reserved.

  15. Geospatial approach towards enumerative analysis of suspended sediment concentration for Ganges-Brahmaputra Bay

    Science.gov (United States)

    Pandey, Palak; Kunte, Pravin D.

    2016-10-01

    This study presents an easy, modular, user-friendly, and flexible software package for processing of Landsat 7 ETM and Landsat 8 OLI-TIRS data for estimating suspended particulate matter concentrations in the coastal waters. This package includes 1) algorithm developed using freely downloadable SCILAB package, 2) ERDAS Models for iterative processing of Landsat images and 3) ArcMAP tool for plotting and map making. Utilizing SCILAB package, a module is written for geometric corrections, radiometric corrections and obtaining normalized water-leaving reflectance by incorporating Landsat 8 OLI-TIRS and Landsat 7 ETM+ data. Using ERDAS models, a sequence of modules are developed for iterative processing of Landsat images and estimating suspended particulate matter concentrations. Processed images are used for preparing suspended sediment concentration maps. The applicability of this software package is demonstrated by estimating and plotting seasonal suspended sediment concentration maps off the Bengal delta. The software is flexible enough to accommodate other remotely sensed data like Ocean Color monitor (OCM) data, Indian Remote Sensing data (IRS), MODIS data etc. by replacing a few parameters in the algorithm, for estimating suspended sediment concentration in coastal waters.

  16. The attenuation of concentrations model: a new method for assessing mercury mobility in sediments

    Directory of Open Access Journals (Sweden)

    Julio C. Wasserman

    2004-02-01

    Full Text Available In this work we propose a new approach for the determination of the mobility of mercury in sediments based on spatial distribution of concentrations. We chose the Tainheiros Cove, located in the Todos os Santos Bay, Brazil, as the study area, for it has a history of mercury contamination due to a chloro-alkali plant that was active during 12 years. Twenty-six surface sediment samples were collected from the area and mercury concentrations were measured by cold vapour atomic absorption spectrophotometry. A contour map was constructed from the results, indicating that mercury accumulated in a "hot spot" where concentrations reach more than 1 µg g-1. The model is able to estimate mobility of mercury in the sediments based on the distances between iso-concentration contours that determines an attenuation of concentrations factor. Values of attenuation ranged between 0.0729 (East of the hot spot, indicating higher mobility to 0.7727 (North of the hot spot, indicating lower mobility.

  17. Heavy metal concentration in mangrove surface sediments from the north-west coast of South America.

    Science.gov (United States)

    Fernández-Cadena, J C; Andrade, S; Silva-Coello, C L; De la Iglesia, R

    2014-05-15

    Mangrove ecosystems are coastal estuarine systems confined to the tropical and subtropical regions. The Estero Salado mangrove located in Guayaquil, Ecuador, has suffered constant disturbances during the past 20 years, due to industrial wastewater release. However, there are no published data for heavy metals present in its sediments and the relationship with anthropogenic disturbance. In the present study, metal concentrations were evaluated in surface sediment samples of the mangrove, showing that B, Cd, Cu, Pb, Se, V, and Zn levels exceeded those declared in international environmental quality standards. Moreover, several metals (Pb, Sn, Cd, Ag, Mo, Zn and Ni) could be linked to the industrial wastewater present in the studied area. In addition, heavy metal levels detected in this mangrove are higher than previous reports on mangrove sediments worldwide, indicating that this mangrove ecosystem is one of the most disrupted on earth. Copyright © 2014 Elsevier Ltd. All rights reserved.

  18. Concentrations of some elements in the coastal sea sediments. Bays with marinas

    International Nuclear Information System (INIS)

    Obhodas, J.; Kutle, A.; Valkovic, V.

    2006-01-01

    Surface sediments and sediment cores from two bays in the Adriatic sea (Punat Bay and Soline Bay, Croatia) have been analyzed for a number of elements, in particular: Ti, V, Mn, Fe, Cu, Zn, As and Pb, by using XRF. Maps of elemental distribution in surface sediments show increased concentrations for some elements present in antifouling paints (Cu, Zn, Pb) near the service areas in the villages or marinas. Core profiles for these elements were used to evaluate the environmental impact of newly constructed marinas. Source partition indicates the influence of other sources located in near by villages. The critical factor in these considerations was shown to be water exchange with the open sea. (author)

  19. Study of techniques applicable for monitoring MIC in soil or sediment

    DEFF Research Database (Denmark)

    Hilbert, Lisbeth Rischel

    1999-01-01

    technique have been evaluated including field tests in soil and marine sediment. The conclusions are that EIS can detect combined biofilm and corrosion product film formation, but corrosion rate is overestimated. The ER technique seems to give a correct and sensitive corrosion rate measurement within...

  20. Reopening abandoned forest roads in northern Idaho, USA: Quantification of runoff, sediment concentration, infiltration, and interrill erosion parameters

    Science.gov (United States)

    R. B. Foltz; N. S. Copeland; W. J. Elliot

    2009-01-01

    This study measured runoff and sediment concentration from the tire track and from the non-tire track to determine infiltration, interrill erodibility, and vegetative cover impacts of reopening an abandoned forest road. Runoff was lowest on the non-track portion of the abandoned road and highest on the reopened road. Sediment concentrations were significantly higher on...

  1. Optimization of colorimetric DET technique for the in situ, two-dimensional measurement of iron(II) distributions in sediment porewaters

    DEFF Research Database (Denmark)

    Bennett, William W.; Teasdale, Peter R.; Welsh, David T.

    2012-01-01

    The recently developed colorimetric diffusive equilibration in thin films (DET) technique for the in situ, high-resolution measurement of iron(II) in marine sediments is optimized to allow measurement of the higher iron concentrations typical of freshwater sediment porewaters. Computer imaging...... the sensitivity of the assay as required; by processing the image with different color channel filters, the sensitivity of the assay can be optimized for lower concentrations (up to 100 μmol L -1) or higher concentrations (up to 2000 μmol L -1) of iron(II), depending on the specific site characteristics......(II) in sediment porewaters. The detection limit of the optimized technique was 4.1 ± 0.3 μmol L -1 iron(II) and relative standard deviations were less than 6%....

  2. Influence of hydrological regime on pore water metal concentrations in a contaminated sediment-derived soil

    International Nuclear Information System (INIS)

    Du Laing, G.; Vanthuyne, D.R.J.; Vandecasteele, B.; Tack, F.M.G.; Verloo, M.G.

    2007-01-01

    Options for wetland creation or restoration might be limited because of the presence of contaminants in the soil. The influence of hydrological management on the pore water concentrations of Cd, Cr, Cu, Fe, Mn, Ni and Zn in the upper soil layer of a contaminated overbank sedimentation zone was investigated in a greenhouse experiment. Flooding conditions led to increased Fe, Mn, Ni and Cr concentrations and decreased Cd, Cu and Zn concentrations in the pore water of the upper soil layer. Keeping the soil at field capacity resulted in a low pore water concentration of Fe, Mn and Ni while the Cd, Cu, Cr and Zn concentrations increased. Alternating hydrological conditions caused metal concentrations in the pore water to fluctuate. Formation and re-oxidation of small amounts of sulphides appeared dominant in determining the mobility of Cd, Cu, and to a lesser extent Zn, while Ni behaviour was consistent with Fe/Mn oxidation and reduction. These effects were strongly dependent on the duration of the flooded periods. The shorter the flooded periods, the better the metal concentrations could be linked to the mobility of Ca in the pore water, which is attributed to a fluctuating CO 2 pressure. - The hydrological regime is a key factor in determining the metal concentration in the pore water of a contaminated sediment-derived soil

  3. Concentrations and carbon isotope compositions of methane in the cored sediments from offshore SW Taiwan

    Energy Technology Data Exchange (ETDEWEB)

    Chuang, P.C.; Yang, T.F.; Hong, W.L. [National Taiwan Univ., Taipei, Taiwan (China). Dept. of Geosciences; Lin, S.; Chen, J.C. [National Taiwan Univ., Taipei, Taiwan (China). Inst. of Oceanography; Sun, C.H. [CPC Corp., Wen Shan, Miaoli, Taiwan (China). Exploration and Development Research Inst.; Wang, Y. [Central Geological Survey, MOEA, Taipei, Taiwan (China)

    2008-07-01

    Gas hydrates are natural occurring solids that contain natural gases, mainly methane, within a rigid lattice of water molecules. They are a type of non-stoichiometric clathrates and metastable crystal products in low temperature and high pressure conditions and are widely distributed in oceans and in permafrost regions around the world. Gas hydrates have been considered as potential energy resources for the future since methane is the major gas inside gas hydrates. Methane is also a greenhouse gas that might affect the global climates from the dissociations of gas hydrates. Bottom simulating reflections (BSRs) have been found to be widely distributed in offshore southwestern Taiwan therefore, inferring the existence of potential gas hydrates underneath the seafloor sediments. This paper presented a study that involved the systematic collection of sea waters and cored sediments as well as the analysis of the gas composition of pore-space of sediments through ten cruises from 2003 to 2006. The paper discussed the results in terms of the distribution of methane concentrations in bottom waters and cored sediments; methane fluxes in offshore southwestern Taiwan; and isotopic compositions of methane in pore spaces of cored sediments. It was concluded that the carbon isotopic compositions of methane demonstrated that biogenic gas source was dominated at shallower depth. However, some thermogenic gases might be introduced from deeper source in this region. 15 refs., 5 figs.

  4. Concentrations and annual fluxes of sediment-associated chemical constituents from conterminous US coastal rivers using bed sediment data

    Science.gov (United States)

    Horowitz, Arthur J.; Stephens, Verlin C.; Elrick, Kent A.; Smith, James J.

    2012-01-01

    Coastal rivers represent a significant pathway for the delivery of natural and anthropogenic sediment-associated chemical constituents to the Atlantic, Pacific and Gulf of Mexico coasts of the conterminous USA. This study entails an accounting segment using published average annual suspended sediment fluxes with published sediment-associated chemical constituent concentrations for (1) baseline, (2) land-use distributions, (3) population density, and (4) worldwide means to estimate concentrations/annual fluxes for trace/major elements and total phosphorus, total organic and inorganic carbon, total nitrogen, and sulphur, for 131 coastal river basins. In addition, it entails a sampling and subsequent chemical analysis segment that provides a level of ‘ground truth’ for the calculated values, as well as generating baselines for sediment-associated concentrations/fluxes against which future changes can be evaluated. Currently, between 260 and 270 Mt of suspended sediment are discharged annually from the conterminous USA; about 69% is discharged from Gulf rivers (n = 36), about 24% from Pacific rivers (n = 42), and about 7% from Atlantic rivers (n = 54). Elevated sediment-associated chemical concentrations relative to baseline levels occur in the reverse order of sediment discharges:Atlantic rivers (49%)>Pacific rivers (40%)>Gulf rivers (23%). Elevated trace element concentrations (e.g. Cu, Hg, Pb, Zn) frequently occur in association with present/former industrial areas and/or urban centres, particularly along the northeast Atlantic coast. Elevated carbon and nutrient concentrations occur along both the Atlantic and Gulf coasts but are dominated by rivers in the urban northeast and by southeastern and Gulf coast (Florida) ‘blackwater’ streams. Elevated Ca, Mg, K, and Na distributions tend to reflect local petrology, whereas elevated Ti, S, Fe, and Al concentrations are ubiquitous, possibly because they have substantial natural as well as anthropogenic sources

  5. Characterization of arsenic-contaminated aquifer sediments from eastern Croatia by ion microbeam, PIXE and ICP-OES techniques

    International Nuclear Information System (INIS)

    Ujević Bošnjak, M.; Fazinić, S.; Duić, Ž.

    2013-01-01

    Highlights: •ICP-OES and PIXE used in the characterization of As-contaminated sediments. •Observed high correlations between the results obtained by those techniques. •Discrepancies observed for Mn, and for the highest As concentrations. •Microbeam analyses showed As association with sulphides and iron. -- Abstract: Groundwater arsenic contamination has been evidenced in eastern Croatia and hydrochemical results suggest that the occurrence of arsenic in the groundwater depends on the local geology, hydrogeology, and geochemical characteristics of the aquifer. In order to perform the sediment characterization and to investigate arsenic association with the other elements in the sediments, 10 samples from two boreholes (PVc-3 and Gundinci 1) in eastern Croatia were analyzed using two techniques: PIXE (without sample pre-treatment) and ICP-OES (after digestion), as well by ion microbeam analyses. The results of the PIXE and ICP-OES techniques showed quite good agreement; however, greater discrepancies were observed at the higher arsenic and manganese mass ratios. According to both techniques, higher As mass ratios were observed in the sediments from the PVc-3 core (up to 651 mg/kg and 491 mg/kg using PIXE and ICP-OES analyses respectively) than from the Gundinci 1 core (up to 60 mg/kg using both techniques). Although arsenic association with Fe is expected, no correlation was observed. The microbeam analyses demonstrated that arsenic is associated with sulphides and iron in the most As-contaminated sample from the PVc-3 core, while this relationship was not evident in the most As-contaminated sample from the Gundinci 1 borehole

  6. Characterization of arsenic-contaminated aquifer sediments from eastern Croatia by ion microbeam, PIXE and ICP-OES techniques

    Energy Technology Data Exchange (ETDEWEB)

    Ujević Bošnjak, M., E-mail: magdalena.ujevic@hzjz.hr [Croatian National Institute of Public Health, Rockefelerova 7, 10000 Zagreb (Croatia); Fazinić, S. [Institute Ruđer Bošković, Bijenička cesta, 10000 Zagreb (Croatia); Duić, Ž. [University of Zagreb, Faculty of Mining, Geology and Petroleum Engineering, Pierottijeva 6, Zagreb (Croatia)

    2013-10-01

    Highlights: •ICP-OES and PIXE used in the characterization of As-contaminated sediments. •Observed high correlations between the results obtained by those techniques. •Discrepancies observed for Mn, and for the highest As concentrations. •Microbeam analyses showed As association with sulphides and iron. -- Abstract: Groundwater arsenic contamination has been evidenced in eastern Croatia and hydrochemical results suggest that the occurrence of arsenic in the groundwater depends on the local geology, hydrogeology, and geochemical characteristics of the aquifer. In order to perform the sediment characterization and to investigate arsenic association with the other elements in the sediments, 10 samples from two boreholes (PVc-3 and Gundinci 1) in eastern Croatia were analyzed using two techniques: PIXE (without sample pre-treatment) and ICP-OES (after digestion), as well by ion microbeam analyses. The results of the PIXE and ICP-OES techniques showed quite good agreement; however, greater discrepancies were observed at the higher arsenic and manganese mass ratios. According to both techniques, higher As mass ratios were observed in the sediments from the PVc-3 core (up to 651 mg/kg and 491 mg/kg using PIXE and ICP-OES analyses respectively) than from the Gundinci 1 core (up to 60 mg/kg using both techniques). Although arsenic association with Fe is expected, no correlation was observed. The microbeam analyses demonstrated that arsenic is associated with sulphides and iron in the most As-contaminated sample from the PVc-3 core, while this relationship was not evident in the most As-contaminated sample from the Gundinci 1 borehole.

  7. Application of PAH concentration profiles in lake sediments as indicators for smelting activity.

    Science.gov (United States)

    Warner, Wiebke; Ruppert, Hans; Licha, Tobias

    2016-09-01

    The ability of lake sediment cores to store long-term anthropogenic pollution establishes them as natural archives. In this study, we focus on the influence of copper shale mining and smelting in the Mansfeld area of Germany, using the depth profiles of two sediment cores from Lake Süßer See. The sediment cores provide a detailed chronological deposition history of polycyclic aromatic hydrocarbons (PAHs) and heavy metals in the studied area. Theisen sludge, a fine-grained residue from copper shale smelting, reaches the lake via deflation by wind or through riverine input; it is assumed to be the main source of pollution. To achieve the comparability of absolute contaminant concentrations, we calculated the influx of contaminants based on the sedimentation rate. Compared to the natural background concentrations, PAHs are significantly more enriched than heavy metals. They are therefore more sensitive and selective for source apportionment. We suggest two diagnostic ratios of PAHs to distinguish between Theisen sludge and its leachate: the ratio fluoranthene to pyrene ~2 and the ratio of PAH with logKOW5.7 converging to an even lower value than 2.3 (the characteristic of Theisen sludge) to identify the particulate input in lake environments. Copyright © 2016 Elsevier B.V. All rights reserved.

  8. Radiotracer and sealed source techniques for sediment management. Report of the consultants meeting

    International Nuclear Information System (INIS)

    2008-01-01

    Radioisotopes as tracers and sealed sources have been a useful and often irreplaceable tool for sediment transport studies. Gamma scattering and transmission gauges are used for sediment monitoring. Computational fluid dynamics (CFD) modelling is now an essential tool for the management of the natural systems and are increasingly used to study the fate and behaviour of particulates and contaminants. Radiotracer techniques are often employed to validate CFD models to enhance confidence in the predictive value of the models. Experimental tracing and numerical modelling are complementary methods of studying complex systems. During the last few decades, many radiotracer studies for the investigation of sediment transport in natural systems have been conducted worldwide, and various techniques for tracing and monitoring sediment have been developed by individual tracer groups. However, the developed techniques and methods for sediment tracing have not been compiled yet as a technical document, which is essential for the preservation of the knowledge and transfer of the technology to developing countries. Standard procedures or guidelines for the tracer experiments, which are vital for the reliability of the experiments and the acceptance of end-users, have not been established by the international tracer community either. The use of radiotracers in sediment transport studies demands the additional attention of the community to further develop these techniques and to ensure their transfer to developing countries. The Consultants' Meeting on 'Radiotracer and sealed source techniques for sediment management' was convened at the headquarters of the International Atomic Energy Agency (IAEA) in Vienna, Austria, from 21 to 25 April 2008. Experts from Argentina, Brazil, France, India, Republic of Korea and United Kingdom have been invited to discuss the current status of the tracer and nucleonic gauge technologies as applied for sediment transport investigations and to evaluate

  9. Radiotracer and sealed source techniques for sediment management. Report of the consultants meeting

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    Radioisotopes as tracers and sealed sources have been a useful and often irreplaceable tool for sediment transport studies. Gamma scattering and transmission gauges are used for sediment monitoring. Computational fluid dynamics (CFD) modelling is now an essential tool for the management of the natural systems and are increasingly used to study the fate and behaviour of particulates and contaminants. Radiotracer techniques are often employed to validate CFD models to enhance confidence in the predictive value of the models. Experimental tracing and numerical modelling are complementary methods of studying complex systems. During the last few decades, many radiotracer studies for the investigation of sediment transport in natural systems have been conducted worldwide, and various techniques for tracing and monitoring sediment have been developed by individual tracer groups. However, the developed techniques and methods for sediment tracing have not been compiled yet as a technical document, which is essential for the preservation of the knowledge and transfer of the technology to developing countries. Standard procedures or guidelines for the tracer experiments, which are vital for the reliability of the experiments and the acceptance of end-users, have not been established by the international tracer community either. The use of radiotracers in sediment transport studies demands the additional attention of the community to further develop these techniques and to ensure their transfer to developing countries. The Consultants' Meeting on 'Radiotracer and sealed source techniques for sediment management' was convened at the headquarters of the International Atomic Energy Agency (IAEA) in Vienna, Austria, from 21 to 25 April 2008. Experts from Argentina, Brazil, France, India, Republic of Korea and United Kingdom have been invited to discuss the current status of the tracer and nucleonic gauge technologies as applied for sediment transport investigations and to evaluate

  10. Investigation of suspended sediment transport using ultrasonic techniques

    DEFF Research Database (Denmark)

    Bjørnø, Irina; Jensen, Leif Bjørnø

    1994-01-01

    The results of the initial experimental studies involving the scattering of ultrasonic signals from canonical and non-canonical shaped suspended particles with known elastical qualities are reported. These results have formed the basis for the development of a numerical model for ultrasound...... propagation through low-concentration suspensions of sand particles...

  11. Correlations of turbidity to suspended-sediment concentration in the Toutle River Basin, near Mount St. Helens, Washington, 2010-11

    Science.gov (United States)

    Uhrich, Mark A.; Kolasinac, Jasna; Booth, Pamela L.; Fountain, Robert L.; Spicer, Kurt R.; Mosbrucker, Adam R.

    2014-01-01

    Researchers at the U.S. Geological Survey, Cascades Volcano Observatory, investigated alternative methods for the traditional sample-based sediment record procedure in determining suspended-sediment concentration (SSC) and discharge. One such sediment-surrogate technique was developed using turbidity and discharge to estimate SSC for two gaging stations in the Toutle River Basin near Mount St. Helens, Washington. To provide context for the study, methods for collecting sediment data and monitoring turbidity are discussed. Statistical methods used include the development of ordinary least squares regression models for each gaging station. Issues of time-related autocorrelation also are evaluated. Addition of lagged explanatory variables was used to account for autocorrelation in the turbidity, discharge, and SSC data. Final regression model equations and plots are presented for the two gaging stations. The regression models support near-real-time estimates of SSC and improved suspended-sediment discharge records by incorporating continuous instream turbidity. Future use of such models may potentially lower the costs of sediment monitoring by reducing time it takes to collect and process samples and to derive a sediment-discharge record.

  12. Determination of the Relative Sediment Concentration in Water Bodies Using Remote Sensing Methodology

    Directory of Open Access Journals (Sweden)

    Germán Vargas Cuervo

    2017-01-01

    Full Text Available Studies for the determination of the relative concentration of sediments (RCS in bodies of water such as rivers, marshes and river deltas require specialized equipment, field work and laboratory analyses of samples, all with high economic costs. Remote sensing, in regions of the optical electromagnetic spectrum, particularly in the visible range between 0.4 and 0.6 µm, shows radiometric contrasts associated with the relative concentration of sediments in water bodies. This work presents an analysis of the principal spectral, spatial and radiometric properties or characteristics of remote sensors for the determination of the relative concentration of sediments in bodies of water, a methodological process for its cartography at a given time or an established period of time. This cartography is based on digital processing of images rather than direct measurements in the field. Lastly, applications are presented for the delta coast of the southwestern area of the Colombian Caribbean between Barranquilla and Punta Piedra and in the lacustrine area of the Guajaro Reservoir and the Jobo and Capote Wetlands in the upper Canal del Dique, Colombia.

  13. Trace metal concentrations in sediments from the southwest of the Iberian Peninsula

    Directory of Open Access Journals (Sweden)

    Julián Blasco

    2010-11-01

    Full Text Available Metal sediment concentrations (As, Cd, Cu, Hg, Ni, Pb and Zn in surface sediments (0 to 5 cm from 11 sampling stations in the southwest of the Iberian Peninsula (the Ria Formosa and the Guadiana River, the Ría de Huelva and the Bay of Cadiz were determined in two seasonal periods (autumn 2006 and spring 2007. No seasonal metal concentration pattern was identified, as similar values were found in both periods. The highest concentrations of copper, zinc, lead and cadmium were reported in the Ria of Huelva area, and those of mercury and nickel in the Bay of Cadiz. The hazard potential index (HPiM was determined to assess the potential risk associated with metal contamination (Cu, Cd, Pb and Zn, taking into account extractable (presumed bioavailable fractions of these metals and site-specific sediment quality values. When the HPiM is > 1 there is risk, and according to this index Ría de Huelva is polluted whereas the Bay of Cadiz is not.

  14. Adapting SWAT hillslope erosion model to predict sediment concentrations and yields in large Basins.

    Science.gov (United States)

    Vigiak, Olga; Malagó, Anna; Bouraoui, Fayçal; Vanmaercke, Matthias; Poesen, Jean

    2015-12-15

    The Soil and Water Assessment Tool (SWAT) is used worldwide for water quality assessment and planning. This paper aimed to assess and adapt SWAT hillslope sediment yield model (Modified Universal Soil Loss Equation, MUSLE) for applications in large basins, i.e. when spatial data is coarse and model units are large; and to develop a robust sediment calibration method for large regions. The Upper Danube Basin (132,000km(2)) was used as case study representative of large European Basins. The MUSLE was modified to reduce sensitivity of sediment yields to the Hydrologic Response Unit (HRU) size, and to identify appropriate algorithms for estimating hillslope length (L) and slope-length factor (LS). HRUs gross erosion was broadly calibrated against plot data and soil erosion map estimates. Next, mean annual SWAT suspended sediment concentrations (SSC, mg/L) were calibrated and validated against SSC data at 55 gauging stations (622 station-years). SWAT annual specific sediment yields in subbasin reaches (RSSY, t/km(2)/year) were compared to yields measured at 33 gauging stations (87station-years). The best SWAT configuration combined a MUSLE equation modified by the introduction of a threshold area of 0.01km(2) where L and LS were estimated with flow accumulation algorithms. For this configuration, the SSC residual interquartile was less than +/-15mg/L both for the calibration (1995-2004) and the validation (2005-2009) periods. The mean SSC percent bias for 1995-2009 was 24%. RSSY residual interquartile was within +/-10t/km(2)/year, with a mean RSSY percent bias of 12%. Residuals showed no bias with respect to drainage area, slope, or spatial distribution. The use of multiple data types at multiple sites enabled robust simulation of sediment concentrations and yields of the region. The MUSLE modifications are recommended for use in large basins. Based on SWAT simulations, we present a sediment budget for the Upper Danube Basin. Copyright © 2015. Published by Elsevier B.V.

  15. Heavy Metal Concentration in the Surface Sediment of Tanjung Lumpur Mangrove Forest, Kuantan, Malaysia

    International Nuclear Information System (INIS)

    Kamaruzzaman Yunus; Shahbudin Saad; Ahmed Jalal Khan Chowdhury; Nurulnadia Mohd Yusuf; Noor Azhar Mohd Shazili; Chuan, O.M.; Bidai, J.

    2011-01-01

    Surface sediment samples from 2 transect (20 sampling points) of Tanjung Lumpur mangrove forest were analyzed for the concentrations of Pb, Cu, Co and Mn. In this study, the average concentrations of Pb, Cu, Co and Mn were 44.41 μg/g dry weight, 32.79 μg/g dry weight, 5.79 μg/g dry weight and 117.73 μg/g dry weight, respectively. The calculated enrichment factors (EF) obtained for Co and Mn can be considered to have the terigeneous in sources while Pb and Cu are considered to have anthropogenic input. (author)

  16. Concentrations of PAHs (Polycyclicaromatic Hydrocarbons Pollutant in Sediment of The Banten Bay

    Directory of Open Access Journals (Sweden)

    Khozanah Munawir

    2018-02-01

    Full Text Available Banten Bay is end of stream for a few rivers from Banten mainland where many manufactures and petrochemical industries are built. This may give environmental pressure of water quality of the bay due to pollutant input, such as Polycyclic Aromatic Hydrocarbons (PAHs. This study is to identify those pollutants and determine their total concentration and distribution in sediments. Surface sediment samples were collected in four zones: inner coastline within the bay, middle bay, coastline off the bay and outer of the Bay in April 2016. PAH components were extracted and measured using a gas chromatography-mass spectrometry. Levels of total PAHs in sediments in inner coastline within the bay ranged between 0.381-2.654 ppm with an average of 1.288 ppm, middle of the bay ranged between 0.747-1.762 ppm with an average of 1.198 ppm, outer of the bay ranged between 0.192-1.394 ppm with an average of 0.921 ppm, and east coast of the bay ranged between 0.191-1.394 ppm and an average of 0.778 ppm. The levels of total PAH contamination is apparently lower than those of PAH threshold in sediments (i.e. 4.5 ppm. Keywords: PAHs (Polycyclic Aromatic Hydrocarbons, Banten Bay

  17. Parameterization of Time-Averaged Suspended Sediment Concentration in the Nearshore

    Directory of Open Access Journals (Sweden)

    Hyun-Doug Yoon

    2015-11-01

    Full Text Available To quantify the effect of wave breaking turbulence on sediment transport in the nearshore, the vertical distribution of time-averaged suspended sediment concentration (SSC in the surf zone was parameterized in terms of the turbulent kinetic energy (TKE at different cross-shore locations, including the bar crest, bar trough, and inner surf zone. Using data from a large-scale laboratory experiment, a simple relationship was developed between the time-averaged SSC and the time-averaged TKE. The vertical variation of the time-averaged SSC was fitted to an equation analogous to the turbulent dissipation rate term. At the bar crest, the proposed equation was slightly modified to incorporate the effect of near-bed sediment processes and yielded reasonable agreement. This parameterization yielded the best agreement at the bar trough, with a coefficient of determination R2 ≥ 0.72 above the bottom boundary layer. The time-averaged SSC in the inner surf zone showed good agreement near the bed but poor agreement near the water surface, suggesting that there is a different sedimentation mechanism that controls the SSC in the inner surf zone.

  18. Preliminary Experimental Results on the Technique of Artificial River Replenishment to Mitigate Sediment Loss Downstream Dams

    Science.gov (United States)

    Franca, M. J.; Battisacco, E.; Schleiss, A. J.

    2014-12-01

    The transport of sediments by water throughout the river basins, from the steep slopes of the upstream regions to the sea level, is recognizable important to keep the natural conditions of rivers with a role on their ecology processes. Over the last decades, a reduction on the supply of sand and gravel has been observed downstream dams existing in several alpine rivers. Many studies highlight that the presence of a dam strongly modifies the river behavior in the downstream reach, in terms of morphology and hydrodynamics, with consequences on local ecology. Sediment deficit, bed armoring, river incision and bank instability are the main effects which affect negatively the aquatic habitats and the water quality. One of the proposed techniques to solve the problem of sediment deficit downstream dams, already adopted in few Japanese and German rivers although on an unsatisfactory fashion, is the artificial replenishment of these. Generally, it was verified that the erosion of the replenishments was not satisfactory and the transport rate was not enough to move the sediments to sufficient downstream distances. In order to improve and to provide an engineering answer to make this technique more applicable, a series of laboratory tests are ran as preparatory study to understand the hydrodynamics of the river flow when the replenishment technique is applied. Erodible volumes, with different lengths and submergence conditions, reproducing sediment replenishments volumes, are positioned along a channel bank. Different geometrical combinations of erodible sediment volumes are tested as well on the experimental flume. The first results of the experimental research, concerning erosion time evolution, the influence of discharge and the distance travelled by the eroded sediments, will be presented and discussed.

  19. The use of modeling and suspended sediment concentration measurements for quantifying net suspended sediment transport through a large tidally dominated inlet

    Science.gov (United States)

    Erikson, Li H.; Wright, Scott A.; Elias, Edwin; Hanes, Daniel M.; Schoellhamer, David H.; Largier, John; Barnard, P.L.; Jaffee, B.E.; Schoellhamer, D.H.

    2013-01-01

    Sediment exchange at large energetic inlets is often difficult to quantify due complex flows, massive amounts of water and sediment exchange, and environmental conditions limiting long-term data collection. In an effort to better quantify such exchange this study investigated the use of suspended sediment concentrations (SSC) measured at an offsite location as a surrogate for sediment exchange at the tidally dominated Golden Gate inlet in San Francisco, CA. A numerical model was calibrated and validated against water and suspended sediment flux measured during a spring–neap tide cycle across the Golden Gate. The model was then run for five months and net exchange was calculated on a tidal time-scale and compared to SSC measurements at the Alcatraz monitoring site located in Central San Francisco Bay ~ 5 km from the Golden Gate. Numerically modeled tide averaged flux across the Golden Gate compared well (r2 = 0.86, p-value

  20. Fourier transform infrared spectroscopy, a new method for rapid determination of total organic and inorganic carbon and biogenic silica concentration in lake sediments

    DEFF Research Database (Denmark)

    Rosén, Peter; Vogel, Hendrik; Cunningham, Laura

    2010-01-01

    We demonstrate the use of Fourier transform infrared spectroscopy (FTIRS) to make quantitative measures of total organic carbon (TOC), total inorganic carbon (TIC) and biogenic silica (BSi) concentrations in sediment. FTIRS is a fast and cost-effective technique and only small sediment samples...... varied between r = 0.84-0.99 for TOC, r = 0.85-0.99 for TIC, and r = 0.68-0.94 for BSi. Because FTIR spectra contain information on a large number of both inorganic and organic components, there is great potential for FTIRS to become an important tool in paleolimnology....

  1. Using disposable solid-phase microextraction (SPME) to determine the freely dissolved concentration of polybrominated diphenyl ethers (PBDEs) in sediments

    International Nuclear Information System (INIS)

    Jia Fang; Cui Xinyi; Wang Wei; Delgado-Moreno, Laura; Gan, Jay

    2012-01-01

    Polybrominated diphenyl ethers (PBDEs) are brominated flame retardants (BFRs). The ubiquity and persistence of PBDEs in sediment have raised concerns over their environmental fate and ecological risks. Due to strong affinity for sediment organic matter, environmental fate and bioavailability of PBDEs closely depend on their phase distribution. In this study, disposable polydimethylsiloxane (PDMS) fiber was used to derive the freely dissolved concentration (C free ) of PBDEs in sediment porewater as a measurement of bioavailability. The PDMS-to-water partition coefficient (log K PDMS ) was 5.46–5.83 for BDE 47, 99, and 153. In sediments, PBDEs were predominantly sorbed to the sediment phase, with C free accounting for free of PBDEs decreased as their bromination or sediment organic carbon content increased. The strong association with dissolved organic matter (DOM) implies a potential for facilitated offsite transport and dispersion in the environment that depends closely on the stability of sediment aggregates. - Highlights: ► A disposable SPME method was developed for measuring C free of PBDEs in sediment. ► C free decreased with increasing congener bromination or sediment OC content. ► C free of PBDEs accounted for DOC values suggest a high probability for DOM-facilitated offsite transport. - A SPME method based on disposable PDMS fibers was developed for measuring the freely dissolved concentration of PBDEs (C free ) in sediment porewater.

  2. Aerobic Biofilms Grown from Athabasca Watershed Sediments Are Inhibited by Increasing Concentrations of Bituminous Compounds

    Science.gov (United States)

    Lawrence, John R.; Sanschagrin, Sylvie; Roy, Julie L.; Swerhone, George D. W.; Korber, Darren R.; Greer, Charles W.

    2013-01-01

    Sediments from the Athabasca River and its tributaries naturally contain bitumen at various concentrations, but the impacts of this variation on the ecology of the river are unknown. Here, we used controlled rotating biofilm reactors in which we recirculated diluted sediments containing various concentrations of bituminous compounds taken from the Athabasca River and three tributaries. Biofilms exposed to sediments having low and high concentrations of bituminous compounds were compared. The latter were 29% thinner, had a different extracellular polysaccharide composition, 67% less bacterial biomass per μm2, 68% less cyanobacterial biomass per μm2, 64% less algal biomass per μm2, 13% fewer protozoa per cm2, were 21% less productive, and had a 33% reduced content in chlorophyll a per mm2 and a 20% reduction in the expression of photosynthetic genes, but they had a 23% increase in the expression of aromatic hydrocarbon degradation genes. Within the Bacteria, differences in community composition were also observed, with relatively more Alphaproteobacteria and Betaproteobacteria and less Cyanobacteria, Bacteroidetes, and Firmicutes in biofilms exposed to high concentrations of bituminous compounds. Altogether, our results suggest that biofilms that develop in the presence of higher concentrations of bituminous compounds are less productive and have lower biomass, linked to a decrease in the activities and abundance of photosynthetic organisms likely due to inhibitory effects. However, within this general inhibition, some specific microbial taxa and functional genes are stimulated because they are less sensitive to the inhibitory effects of bituminous compounds or can degrade and utilize some bitumen-associated compounds. PMID:24056457

  3. Determination of 210Pb in marine sediment core- A comparison between alpha and gamma techniques

    International Nuclear Information System (INIS)

    Zal Uyun Wan Mahmood; Yii Mei Wo; Zaharudin Ahmad

    2010-01-01

    The most commonly used techniques of alpha and gamma spectrometry were performed to measure 210 Pb activity in marine sediment core as a comparison. Alpha analytical technique measured the activity of 210 Pb from its in-grow grand-daughter 210 Po after a chemical separation, assuming radioactive equilibrium between the two radionuclides. Meanwhile, gamma analysis technique allows direct measurement, non-destructive and no preliminary chemical separation. Through the comparison, it is found that both alpha and gamma analysis techniques were slightly difference. Overall, the results from alpha analytical technique were basically higher than those from the gamma analytical techniques. Some logical argument had been discussed to explain this situation. In routine analysis, the analytical technique used should be chosen carefully based on advantages and disadvantages of the each technique and analysis requirements. Therefore, it is recommended to determine exactly the needs and purpose of analysis and to know the sample history before decide the appropriate analytical technique. (author)

  4. Remote Sensing Analysis of Temperature and Suspended Sediment Concentration in Ayeyarwady River in Myanmar

    Science.gov (United States)

    Thanda Ko, Nyein; Rutten, Martine

    2017-04-01

    Detailed spatial coverage of water quality parameters are crucial to better manage rivers. However, collection of water quality parameters is both time consuming and costly for large rivers. This study demonstrates that Operational Land Image (OLI) Sensor on board of Landsat 8 can be successfully applied for the detection of spatial patterns of water temperature as well as suspended sediment concentration (SSC) using the Ayeyarwady river, Myanmar as a case study. Water temperature estimation was obtained from the brightness thermal Band 10 by using the Split-Window algorithm. The study finds that there is a close agreement between the remote sensing temperature and in-situ temperature with relative error in the range from 4.5% to 8.2%. The sediment load of Ayeyarwady river is ranked as the third-largest sediment load among the world's rivers but there is very little known about this important parameter, due to a lack of adequate gauge data. The single band reflectance of Landsat image (Band 5) seems a good indicator for the estimation of SSC with relative error in the range of less than 10% but the developed empirical formula by the power relation with the only seven ground reference points is uncertain to apply for the entire river basin. It is to note that an important constraint for the sediment analysis is the availability of spatial and temporal ground reference data. Future studies should also focus on the improvement of ground reference data points to become more reliable, because most of the river in Asia, especially in Myanmar, don't have readily available continuous ground sediment data points due to lack of measurement gauge stations through the river.

  5. Chemometric techniques in distribution, characterisation and source apportionment of polycyclic aromatic hydrocarbons (PAHS) in aquaculture sediments in Malaysia.

    Science.gov (United States)

    Retnam, Ananthy; Zakaria, Mohamad Pauzi; Juahir, Hafizan; Aris, Ahmad Zaharin; Zali, Munirah Abdul; Kasim, Mohd Fadhil

    2013-04-15

    This study investigated polycyclic aromatic hydrocarbons (PAHs) pollution in surface sediments within aquaculture areas in Peninsular Malaysia using chemometric techniques, forensics and univariate methods. The samples were analysed using soxhlet extraction, silica gel column clean-up and gas chromatography mass spectrometry. The total PAH concentrations ranged from 20 to 1841 ng/g with a mean of 363 ng/g dw. The application of chemometric techniques enabled clustering and discrimination of the aquaculture sediments into four groups according to the contamination levels. A combination of chemometric and molecular indices was used to identify the sources of PAHs, which could be attributed to vehicle emissions, oil combustion and biomass combustion. Source apportionment using absolute principle component scores-multiple linear regression showed that the main sources of PAHs are vehicle emissions 54%, oil 37% and biomass combustion 9%. Land-based pollution from vehicle emissions is the predominant contributor of PAHs in the aquaculture sediments of Peninsular Malaysia. Copyright © 2013 Elsevier Ltd. All rights reserved.

  6. Sensing dissolved sediment porewater concentrations of persistent and bioaccumulative poolutants using disposable solid-phase microextraction fibers

    NARCIS (Netherlands)

    Mayer, P.; Vaes, W.H.J.; Wijnker, F.; Legierse, K.C.H.M.; Kraaij, R.H.; Tolls, J.; Hermens, J.L.M.

    2000-01-01

    Polymer coated glass fibers were applied as disposable samplers to measure dissolved concentrations of persistent and bioaccumulative pollutants (PBPs) in sediment porewater. The method is called matrix solid-phase microextraction (matrix-SPME), because it utilizes the entire sediment matrix as a

  7. Metals concentrations in sediments and oyster Crassostrea gigas from La Pitahaya lagoon, Sinaloa, NW Mexico

    Science.gov (United States)

    Luna Varela, R.; Muñoz Sevilla, N.; Campos Villegas, L.; Rodriguez Espinosa, P.; Gongora Gomez, A.; MP, J.

    2013-05-01

    This present study was performed in a culture of Crassostrea gigas in La Pitahaya, Sinaloa, México. The main objective is to identify the enrichment pattern of trace elements (Cu, Cd, Cr, Ni, Pb, Zn, Hg, As, V) also was determine concentrations thereof in oyster. Four sampling sites were selected, two smaller channels which connect the lagoon directly , the region of culture and connection with the sea ; and each sampling consisted of 4 sample sediments and 50 oysters of commercial size per mounth . Concentrations of trace metals were determined using atomic absorption spectrophotometry (AAS). The higher concentration of elements in certain samples clearly suggests that they are directly fed by the smaller channels which connect the lagoon directly. These small channels often carry the contaminants which are absorbed and deposited in the sediments. The results were also compared with the Effect Range Low (ERL) and Effect Range Medium (ERM) of NOAA and it indicates that Ni is above the ERL values. Cadmium, lead, chrome and copper concentrations exceeded the limits permissible of bivalbe mollusks established by the sanitary regulations

  8. Sedimentation

    Science.gov (United States)

    Cliff R. Hupp; Michael R. Schening

    2000-01-01

    Sedimentation is arguably the most important water-quality concern in the United States. Sediment trapping is cited frequently as a major function of riverine-forested wetlands, yet little is known about sedimcntation rates at the landscape scale in relation to site parameters, including woody vegetation type, elevation, velocity, and hydraulic connection to the river...

  9. Determination of Heavy and Toxic Trace Elements in Sediments of Qarun Lake Using Instrumental Neutron Activation Analysis Technique

    International Nuclear Information System (INIS)

    Hamed, A.; Abd EI-Samad, M.; Soliman, N.F.

    2011-01-01

    An investigation of certain heavy and toxic trace elements in 15 sediment samples from different areas at Qarun Lake was performed by a neutron activation technique using the neutron irradiation facilities of the Second Egyptian Research Reactor (ETRR-2). The samples together with two sets of gold foils (one bare and the other covered with cadmium) and two Standard Reference Materials IAEA (Soil-7) were irradiated at the core of the reactor in two capsules for 8520 seconds, another two capsules each has two sets of gold foils (one bare and the other covered with cadmium) are used to determine the neutron fluxes around the sediment samples. The gamma-rays of nuclides from the irradiated samples were carried out by means of a well calibrated high resolution HPGe detection system. The concentrations of product nuclides containing in the irradiated samples were determined from the peak counting-rates of the prominent gamma-ray lines for the corresponding nuclides using Single External Comparator Method (k 0 -Standardization Method) which called k 0 -NAA technique. The neutron flux ratios (f) in the same radiation sites of the sediment samples bottles were calculated as well as the cadmium ratios (R e d). MS Excel work books were constructed and used in our calculation. The total contents of As , Ba , Ca ,Co, Cr ,Cs, Eu ,Hf ,Hg,Na ,Ru ,Sc ,Se ,Sm ,Sn ,Sr ,Th ,Rb ,Zn ,and Zr in these samples were measured. The objectives .of this study were evaluated to identify the variations of concentration of some elements that have an impact on environmental pollutions. The results indicated that the concentrations of toxic trace elements of Ba, Cr, Se, Sn, Hg, Sin and Zn may represent pollutions problem

  10. Electron spin resonance as a high sensitivity technique for environmental magnetism: determination of contamination in carbonate sediments

    Science.gov (United States)

    Crook, Nigel P.; Hoon, Stephen R.; Taylor, Kevin G.; Perry, Chris T.

    2002-05-01

    This study investigates the application of high sensitivity electron spin resonance (ESR) to environmental magnetism in conjunction with the more conventional techniques of magnetic susceptibility, vibrating sample magnetometry (VSM) and chemical compositional analysis. Using these techniques we have studied carbonate sediment samples from Discovery Bay, Jamaica, which has been impacted to varying degrees by a bauxite loading facility. The carbonate sediment samples contain magnetic minerals ranging from moderate to low concentrations. The ESR spectra for all sites essentially contain three components. First, a six-line spectra centred around g = 2 resulting from Mn2+ ions within a carbonate matrix; second a g = 4.3 signal from isolated Fe3+ ions incorporated as impurities within minerals such as gibbsite, kaolinite or quartz; third a ferrimagnetic resonance with a maxima at 230 mT resulting from the ferrimagnetic minerals present within the bauxite contamination. Depending upon the location of the sites within the embayment these signals vary in their relative amplitude in a systematic manner related to the degree of bauxite input. Analysis of the ESR spectral components reveals linear relationships between the amplitude of the Mn2+ and ferrimagnetic signals and total Mn and Fe concentrations. To assist in determining the origin of the ESR signals coral and bauxite reference samples were employed. Coral representative of the matrix of the sediment was taken remote from the bauxite loading facility whilst pure bauxite was collected from nearby mining facilities. We find ESR to be a very sensitive technique particularly appropriate to magnetic analysis of ferri- and para-magnetic components within environmental samples otherwise dominated by diamagnetic (carbonate) minerals. When employing typical sample masses of 200 mg the practical detection limit of ESR to ferri- and para-magnetic minerals within a diamagnetic carbonate matrix is of the order of 1 ppm and 1 ppb

  11. Phosphorus availability from bottom sediments of lakes using a nuclear technique

    International Nuclear Information System (INIS)

    Flores, F.; Facetti, J.F.

    1991-01-01

    Availability of phosphorus from the bottom sediments of a lake plays an import role in the development of aquatic biota and in the enhancement of eutrophication process. In this work the 31 P↔ 32 P isotopic exchange (E values) technique was applied to assess the potential influence of this phosphorus reservoir on the water quality of Acaray and Yguazu Dams, at the Eastern Region of Paraguay. Samples analyzed were taken from the bottom sediments of the water bodies at different sites as well as from the shores. The method is reliable and yields information of ecological significance

  12. Phosphorus availability from bottom sediments of lakes using a nuclear technique

    International Nuclear Information System (INIS)

    Flores, F.; Facetti, J.F.

    1992-01-01

    Availability of phosphorus from the bottom sediments of a lake plays an import role in the development of aquatic biota and in the enhancement of the eutrophication process. In this work, the 31 P- 32 P isotopic exchange (E values) technique was applied to assess the potential influence of this phosphorus 'reservoir' on the water quality of the Acaray and Yguazu Dams in the Easter Region of Paraguay. Samples analyzed were taken from the bottom sediments of the water body at different sites as well as from the shores. The method is reliable and yields information of potential ecological significance. (author) 14 refs.; 2 tabs

  13. Suspended sediment concentration and optical property observations of mixed-turbidity, coastal waters through multispectral ocean color inversion

    Science.gov (United States)

    Multispectral satellite ocean color data from high-turbidity areas of the coastal ocean contain information about the surface concentrations and optical properties of suspended sediments and colored dissolved organic matter (CDOM). Empirical and semi-analytical inversion algorit...

  14. Modeling the Impacts of Suspended Sediment Concentration and Current Velocity on Submersed Vegetation in an Illinois River Pool, USA

    National Research Council Canada - National Science Library

    Best, Elly

    2004-01-01

    This technical note uses a modeling approach to examine the impacts of suspended sediment concentrations and current velocity on the persistence of submersed macrophytes in a shallow aquatic system...

  15. Metal toxicity in a sediment-dwelling polychaete: Threshold body concentrations or overwhelming accumulation rates?

    International Nuclear Information System (INIS)

    Carmen Casado-Martinez, M.; Smith, Brian D.; Luoma, Samuel N.; Rainbow, Philip S.

    2010-01-01

    We followed the net accumulation of As, Cu and Zn in the deposit-feeding polychaete Arenicola marina exposed in the laboratory to natural metal-contaminated sediments, one exposure leading to mass mortality between day 10 and 20, and the other not causing lethality over a period of 60 days of exposure. The worms showed lower total accumulated metal concentrations just before mortality occurred (<20 days) at the lethal exposure, than after 30 days of exposure to sediments not causing mortality. Moreover rates of accumulation of As, Cu and Zn were significantly higher in the lethal exposure than in the sublethal exposure. Our results show that it is not possible to link mortality to a critical total body concentration, and we add to a growing body of literature indicating that metal toxicity occurs when organisms cannot cope with overwhelming influx and subsequent accumulation rates. - Laboratory exposures with the deposit-feeding polychaete Arenicola marina suggest that toxicity is not caused by the accumulated concentration of toxic metals in the body of the animal, but by the rate at which the toxic metal is accumulated.

  16. Water erosion in surface soil conditions: runoff velocity, concentration and D50 index of sediments in runoff

    OpenAIRE

    Ramos,Júlio César; Bertol,Ildegardis; Barbosa,Fabrício Tondello; Bertól,Camilo; Mafra,Álvaro Luiz; Miquelluti,David José; Mecabô Júnior,José

    2016-01-01

    ABSTRACT Water erosion and contamination of water resources are influenced by concentration and diameter of sediments in runoff. This study aimed to quantify runoff velocity and concentration and the D50 index of sediments in runoff under different soil surface managements, in the following treatments: i) cropped systems: no-tilled soil covered by ryegrass (Lolium multiflorum Lam.) residue, with high soil cover and minimal roughness (HCR); no tilled soil covered by vetch (Vicia sativa L.) res...

  17. Metal concentrations in sediments from tourist beaches of Miri City, Sarawak, Malaysia (Borneo Island).

    Science.gov (United States)

    Nagarajan, R; Jonathan, M P; Roy, Priyadarsi D; Wai-Hwa, L; Prasanna, M V; Sarkar, S K; Navarrete-López, M

    2013-08-15

    Forty-three sediment samples were collected from the beaches of Miri City, Sarawak, Malaysia to identify the enrichment of partially leached trace metals (PLTMs) from six different tourist beaches. The samples were analyzed for PLTMs Fe, Mn, Cr, Co, Cu, Ni, Pb, Sr and Zn. The concentration pattern suggest that the southern side of the study area is enriched with Fe (1821-6097 μg g(-1)), Mn (11.57-90.22 μg g(-1)), Cr (51.50-311 μg g(-1)), Ni (18-51 μg g(-1)), Pb (8.81-84.05 μg g(-1)), Sr (25.95-140.49 μg g(-1)) and Zn (12.46-35.04 μg g(-1)). Compared to the eco-toxicological values, Cr>Effects range low (ERL), Lowest effect level (LEL), Severe effect level (SEL); Cu>Unpolluted sediments, ERL, LEL; Pb>Unpolluted sediments and Ni>ERL and LEL. Comparative results with other regions indicate that Co, Cr, Cu, Ni and Zn are higher, indicating an external input rather than natural process. Copyright © 2013 Elsevier Ltd. All rights reserved.

  18. The Concentration Levels Of Some Isotopic Radionuclides In The Coastal Sediments Of The Red Sea, Egypt

    International Nuclear Information System (INIS)

    EL SAHARTY, A.A.; DAR, M.A.

    2010-01-01

    The radionuclide activities of 238 U, 232 Th, 40 K and 137 Cs were measured using high resolution gamma spectrometry system. The total organic matter (TOM) and carbonate contents were also measured in the surface sediments of three valleys downstream at the southern Egyptian Red Sea coast. These localities are characterized by the presence of mangrove swamps with dense aerobic roots that provide calm conditions for particulate and fine sediments settlement. 238 U and 232 Th recorded almost equal activity values in the studied localities and their occurrence in the localities indicated that the metal accumulation are due to the complex and multiple processes that characterize the mangrove environments including accumulation in particulate form with the fine sediments, absorption on iron and manganese oxides and hydroxides from the sea water, incorporation inside the carbonate frameworks and as detrital phase. 40 K showed obvious radioactivity in the three localities indicating the presence of terrestrial radionuclide. 137 Cs concentrations were not evident in the studied localities which may indicate non-significant artificial source of radionuclide activity.

  19. Activities concentration of 239+240Pu in sediment in Sabah and Sarawak coastal area

    International Nuclear Information System (INIS)

    Jalal Sharib; Zaharudin Ahmad; Yii Mei Wo; Ahmad Sanadi Abu Bakar; Norfaizal Mohamed; Kamarozaman Ishak; Zulkifli Daud

    2008-08-01

    The determination of plutonium, 239+240 Pu activity concentration and their distributions along the coastal area of the Sabah and Sarawak have been performed using alpha spectrometry counting system. The sampling coastal sediment for this study was carried out in July 2004 as part of the Marine Radioactivity Database Development Project for Malaysia. This results show that the distribution of Plutonium, 239+240 Pu radionuclides in coastal sediment is consistent, their activities are depending on the sampling locations. Generally, the 239+240 Pu activities measured in Sabah and Sarawak coastal sediment are in the range of BDL - 1.83 Bq/kg and 0.11 - 0.841 Bq/kg dry weights, respectively. The sampling stations, Persisiran Lubok Sabanan, SB 15 and Sungai Similajau, SR 13 showed the highest plutonium, 239+240 Pu radionuclides isotopes activity in Sabah and Sarawak. Meanwhile, these two stations shows higher activity compare to West Coast of Peninsular of Malaysia station for the Marine Radioactivity Database Development Project for Malaysia. (Author)

  20. Effects of salinity and particle concentration on sediment hydrodynamics and critical bed-shear-stress for erosion of fine grained sediments used in wetland restoration projects

    Science.gov (United States)

    Ghose-Hajra, M.; McCorquodale, A.; Mattson, G.; Jerolleman, D.; Filostrat, J.

    2015-03-01

    Sea-level rise, the increasing number and intensity of storms, oil and groundwater extraction, and coastal land subsidence are putting people and property at risk along Louisiana's coast, with major implications for human safety and economic health of coastal areas. A major goal towards re-establishing a healthy and sustainable coastal ecosystem has been to rebuild Louisiana's disappearing wetlands with fine grained sediments that are dredged or diverted from nearby rivers, channels and lakes to build land in open water areas. A thorough geo-hydrodynamic characterization of the deposited sediments is important in the correct design and a more realistic outcome assessment of the long-term performance measures for ongoing coastal restoration projects. This paper evaluates the effects of salinity and solid particle concentration on the re-suspension characteristics of fine-grained dredged sediments obtained from multiple geographic locations along the Gulf coast. The critical bed-shear-stress for erosion has been evaluated as a function of sedimentation time. The sediment hydrodynamic properties obtained from the laboratory testing were used in a numerical coastal sediment distribution model to aid in evaluating sediment diversions from the Mississippi River into Breton Sound and Barataria Bay.

  1. Effects of salinity and particle concentration on sediment hydrodynamics and critical bed-shear-stress for erosion of fine grained sediments used in wetland restoration projects

    Directory of Open Access Journals (Sweden)

    M. Ghose-Hajra

    2015-03-01

    Full Text Available Sea-level rise, the increasing number and intensity of storms, oil and groundwater extraction, and coastal land subsidence are putting people and property at risk along Louisiana’s coast, with major implications for human safety and economic health of coastal areas. A major goal towards re-establishing a healthy and sustainable coastal ecosystem has been to rebuild Louisiana’s disappearing wetlands with fine grained sediments that are dredged or diverted from nearby rivers, channels and lakes to build land in open water areas. A thorough geo-hydrodynamic characterization of the deposited sediments is important in the correct design and a more realistic outcome assessment of the long-term performance measures for ongoing coastal restoration projects. This paper evaluates the effects of salinity and solid particle concentration on the re-suspension characteristics of fine-grained dredged sediments obtained from multiple geographic locations along the Gulf coast. The critical bed-shear-stress for erosion has been evaluated as a function of sedimentation time. The sediment hydrodynamic properties obtained from the laboratory testing were used in a numerical coastal sediment distribution model to aid in evaluating sediment diversions from the Mississippi River into Breton Sound and Barataria Bay.

  2. The adsorption/desorption of phosphorus in freshwater sediments from buffer zones: the effects of sediment concentration and pH.

    Science.gov (United States)

    Zhang, Liang; Du, Yun; Du, Chao; Xu, Meng; Loáiciga, Hugo A

    2016-01-01

    Riparian buffer zones adjacent to reservoirs and lakes protect aquatic ecosystems from polluted surface runoff. Sediments, collected from the buffer zones of Danjiangkou Reservoir (SR) and Honghu Lake (SL) in an ecologically fragile region in central China, were evaluated to reveal their phosphorus-adsorbing/desorbing properties and storage capacities. A nonlinear regression method was used to fit the pseudo-second-order kinetic and the modified crossover-type Langmuir isotherm models to the experimental data. It is shown that the adsorption of phosphorus onto the studied sediments followed the pseudo-second-order kinetic expression. The modified crossover-type Langmuir isotherm model was found to be a suitable method for describing adsorption/desorption processes in the experimental sediments. The maximum adsorption capacities (Q m), partitioning coefficients (K p), native adsorbed exchangeable phosphorus (NAP), and equilibrium phosphorus concentration (EPC0) were subsequently obtained for the experimental sediments. The effects of sediment concentration and pH were also investigated by batch experiments and Fourier transformation infrared and scanning electron microscopy analyses. The adsorption/desorption characteristics of different phosphate species on the sediments from reservoir and lake buffer zones were identified.

  3. Assessment of Marine Pollution in İzmir Bay: Heavy Metal and Organic Compound Concentrations in Surficial Sediments

    OpenAIRE

    AKSU, Ali Engin

    2014-01-01

    The extent of marine pollution in İzmir Bay is investigated using inorganic and organic geochemical data from surface sediments. The concentrations of 42 elements in 84 samples established that surface sediments in Inner İzmir Bay display significant enrichments in Ag, As, Cd, Cr, Cu, Hg, Mo, P, Pb, Sb, Sn, V, and Zn, associated with notably high concentrations of total organic carbon and sulphur. Organic geochemical data in 14 samples from Inner İzmir Bay showed that these sediments...

  4. A preliminary study on sedimentation rate in Tasek Bera Lake estimated using Pb-210 dating technique

    International Nuclear Information System (INIS)

    Wan Zakaria Wan Muhamad Tahir; Johari Abdul Latif; Juhari Mohd Yusof; Kamaruzaman Mamat; Gharibreza, M.R.

    2010-01-01

    Tasek Bera is the largest natural lake system (60 ha) in Malaysia located in southwest Pahang. The lake is a complex dendritic system consisting of extensive peat-swamp forests. The catchment was originally lowland dipterocarp forest, but this has nearly over the past four decades been largely replaced with oil palm and rubber plantations developed by the Federal Land Development Authority (FELDA). Besides the environmentally importance of Tasek Bera, it is seriously subjected to erosion, sedimentation and morphological changes. Knowledge and information of accurate sedimentation rate and its causes are of utmost importance for appropriate management of lakes and future planning. In the present study, environmental 210 Pb (natural) dating technique was applied to determine sedimentation rate and pattern as well as the chronology of sediment deposit in Tasek Bera Lake. Three undisturbed core samples from different locations at the main entry and exit points of river mouth and in open water within the lake were collected during a field sampling campaign in October 2009 and analyzed for 210 Pb using gamma spectrometry method. Undisturbed sediments are classified as organic soils to peat with clayey texture that composed of 93 % clay, 5 % silt, and 2 % very fine sand. Comparatively higher sedimentation rates in the entry (0.06-1.58 cm/ yr) and exit (0.05-1.55 cm/ yr) points of the main river mouth as compared to the lakes open water (0.02- 0.74 cm/ yr) were noticed. Reasons for the different pattern of sedimentation rates in this lake and conclusion are discussed in this paper. (author)

  5. Secondary poisoning of cadmium, copper and mercury: implications for the Maximum Permissible Concentrations and Negligible Concentrations in water, sediment and soil

    NARCIS (Netherlands)

    Smit CE; Wezel AP van; Jager T; Traas TP; CSR

    2000-01-01

    The impact of secondary poisoning on the Maximum Permissible Concentrations (MPCs) and Negligible Concentrations (NCs) of cadmium, copper and mercury in water, sediment and soil have been evaluated. Field data on accumulation of these elements by fish, mussels and earthworms were used to derive

  6. Concentrations of heavy metals in sediment and organisms during a harmful algal bloom (HAB) at Kun Kaak Bay, Sonora, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Hernandez, Jaqueline [Centro de investigacion en Alimentacion y Desarrollo AC (CIAD) Guaymas Unit, Carretera al Varadero Nal. Km 6.6, Apdo. Postal 284, CP 85480 Guaymas, Sonora (Mexico)]. E-mail: jaqueline@cascabel.ciad.mx; Garcia-Rico, Leticia [Centro de investigacion en Alimentacion y Desarrollo AC (CIAD), Carretera a la Victoria Km 0.6, Apdo. Postal 1735, CP 83000 Hermosillo, Sonora (Mexico)]. E-mail: lgarciar@cascabel.ciad.mx; Jara-Marini, Martin E. [Centro de investigacion en Alimentacion y Desarrollo AC (CIAD), Carretera a la Victoria Km 0.6, Apdo. Postal 1735, CP 83000 Hermosillo, Sonora (Mexico)]. E-mail: mjara@cascabel.ciad.mx; Barraza-Guardado, Ramon [Departamento de Investigaciones Cientificas y Tecnologicas de la Universidad de Sonora (DICTUS), Rosales y Ninos Heroes s/n Col. Centro, CP 83000 Hermosillo, Sonora (Mexico)]. E-mail: rbarraza@rtn.uson.mx; Hudson Weaver, Amy [Comunidad y Biodiversidad AC - COBI, Terminacion Bahia de Bacochibampo s/m, Fraccionamiento Lomas de Cortes, CP 85450 Guaymas, Sonora (Mexico)]. E-mail: ahw@cobi.org.mx

    2005-07-01

    In early April 2003, fishermen from Kino Bay Sonora alerted us about a massive die-off of fish and mollusks occurring at Kun Kaak Bay. Phytoplankton samples taken on 17 May 2003 reported the presence of a harmful algal bloom composed of Chatonella marina, Chatonella cf. ovata, Gymnodinium catenatum and Gymnodinium sanguineum. On 22 of May, we collected samples of water, sediment and organisms at the affected area. Physicochemical parameters and nutrients were measured in water samples from different depths. Sediment and benthic organisms were analyzed for Cd, Cu, Zn, Pb and Hg. We found concentrations of heavy metals higher than background levels for this area. Cadmium and Lead concentrations in sediment from the HAB area were up to 6x greater than background levels and Cd in mollusks was 8x greater than regulations allow. A relationship between elevated Cd and Pb concentrations in sediment and the survival of toxic dinoflagellates is suspected.

  7. Concentrations of heavy metals in sediment and organisms during a harmful algal bloom (HAB) at Kun Kaak Bay, Sonora, Mexico

    International Nuclear Information System (INIS)

    Garcia-Hernandez, Jaqueline; Garcia-Rico, Leticia; Jara-Marini, Martin E.; Barraza-Guardado, Ramon; Hudson Weaver, Amy

    2005-01-01

    In early April 2003, fishermen from Kino Bay Sonora alerted us about a massive die-off of fish and mollusks occurring at Kun Kaak Bay. Phytoplankton samples taken on 17 May 2003 reported the presence of a harmful algal bloom composed of Chatonella marina, Chatonella cf. ovata, Gymnodinium catenatum and Gymnodinium sanguineum. On 22 of May, we collected samples of water, sediment and organisms at the affected area. Physicochemical parameters and nutrients were measured in water samples from different depths. Sediment and benthic organisms were analyzed for Cd, Cu, Zn, Pb and Hg. We found concentrations of heavy metals higher than background levels for this area. Cadmium and Lead concentrations in sediment from the HAB area were up to 6x greater than background levels and Cd in mollusks was 8x greater than regulations allow. A relationship between elevated Cd and Pb concentrations in sediment and the survival of toxic dinoflagellates is suspected

  8. Concentrations of heavy metals in sediment and organisms during a harmful algal bloom (HAB) at Kun Kaak Bay, Sonora, Mexico.

    Science.gov (United States)

    García-Hernández, Jaqueline; García-Rico, Leticia; Jara-Marini, Martin E; Barraza-Guardado, Ramón; Hudson Weaver, Amy

    2005-07-01

    In early April 2003, fishermen from Kino Bay Sonora alerted us about a massive die-off of fish and mollusks occurring at Kun Kaak Bay. Phytoplankton samples taken on 17 May 2003 reported the presence of a harmful algal bloom composed of Chatonella marina, Chatonella cf. ovata, Gymnodinium catenatum and Gymnodinium sanguineum. On 22 of May, we collected samples of water, sediment and organisms at the affected area. Physicochemical parameters and nutrients were measured in water samples from different depths. Sediment and benthic organisms were analyzed for Cd, Cu, Zn, Pb and Hg. We found concentrations of heavy metals higher than background levels for this area. Cadmium and Lead concentrations in sediment from the HAB area were up to 6x greater than background levels and Cd in mollusks was 8x greater than regulations allow. A relationship between elevated Cd and Pb concentrations in sediment and the survival of toxic dinoflagellates is suspected.

  9. Assessment of sediment quality based on toxic equivalent benzo[a]Pyrene concentration

    International Nuclear Information System (INIS)

    King, T.L.; Lee, K.

    2004-01-01

    This study examined benzo[a]pyrene (B[a]P) as an indicator and its thresholds for polycyclic aromatic hydrocarbons (PAH) in sediments. The indicator, based on toxicity and carcinogenic effects, was selected to assess the marine environment and changes in marine environmental quality (MEQ) in Sydney Harbour, Nova Scotia. It was shown that the bioavailability of B[a]P and other PAHs is greatly affected by the quality and quantity of dissolved organic matter and organic carbon content. Two coal coke facilities were constructed on the shore of Sydney Harbour in the 19th century. For many years, the coke-ovens discharged toxic liquid effluent through the Tar Ponds into the harbour, contaminating the ground and surface water with arsenic, lead and other toxins. It also led to the accumulation of PAHs and polychlorinated biphenyls. A recent assessment of PAH contamination of Sydney Harbour has focused on the exposure of organisms to contaminants as well as the biological effects on the organisms. All samples collected from the South Arm of Sydney Harbour exceeded the upper threshold of established regulatory guidelines. Samples from the Northwest Arm were within regulatory limits, suggesting that industrial and municipal sources were the primary sources of pollution. PAH concentrations were used to identify sediments that exceed effects thresholds based on MEQ guidelines. The results were compared to actual observations of biological effects. Toxic equivalency factors were established for B[a]P and other PAHs in order to estimate cumulative exposure levels. The concentrations can be compared to regulatory sediment quality guidelines established in Canada and the United States for the protection of marine life. 34 refs., 6 tabs., 2 figs

  10. Analysis of heavy metals (Pb and Zn) concentration in sediment of Blanakan fish ponds, Subang, West Java

    Science.gov (United States)

    Wiriawan, A.; Takarina, N. D.; Pin, T. G.

    2017-07-01

    Blanakan fish ponds receive water resource from Kali Malang and Blanakan rivers. Industrial and domestic activities along the river can cause pollution, especially heavy metals. Zinc (Zn) is an essential element that needed by an organism, while Lead (Pb) is a nonessential element that is not needed. Discharge of waste water from industries and anthropogenic activities continuously not only pollute the water but also the sediment and biota live on it. This research was aimed to know the heavy metals content in the sediment of Blanakan fish ponds. Sediment samples were taken on July and August 2016 at three locations. Heavy metals were analyzed using Atomic Absorption Spectrophotometry (AAS) Shimadzu 6300. The result of Lead (Pb) measurement showed that Fish Pond 1 had higher average concentration compared Fish Pond 2 and Fish Pond 3 which was 0.55 ppm. Standard for Lead (Pb) in sediment according to Ontario Sediment Standards (2008) is 31 ppm. Based on Zinc (Zn) measurement, it was known that average of Zinc (Zn) concentration also higher on Fish Pond 1 compared to Fish Pond 2 and 3 which was 1.93 ppm. According to Ontario Sediment Standards (2008), a standard for Zinc (Zn) in sediment is 120 ppm. This indicated that heavy metals in the sediment of fish ponds were below standards. Statistical analysis using t-test showed that there was no significant difference of heavy metals content among fish ponds.

  11. Concentration levels and spatial distribution of sulphur and metals in fine-grained sediments in western Finland

    Directory of Open Access Journals (Sweden)

    M. ÅSTRÖM

    2008-12-01

    Full Text Available On the coastal plains of Finland, widespread Holocene marine and lacustrine sediments have developed into acid sulphate soil as a result of extensive artificial drainage for agricultural purposes. This has caused a variety of environmental problems. The aim of this study was to determine the concentration levels and spatial distribution of sulphur, carbon and metals [titanium, vanadium, chromium, manganese (Mn, iron, cobalt (Co, nickel (Ni, copper (Cu, zinc (Zn] in these sediments, in order to increase the geochemical understanding of the parent materials from which acid sulphate soil develops. Sediment samples were collected at 317 sites from a depth of 1.5–3 m. While the sediments have high S (sulphide concentrations (median = 0.54% and thus a strong acidification potential, they carry transition metals mainly in smallsized silicates close to “background concentrations” far below contamination limits. The previously documented extensive release of Co, Cu, Mn, Ni and Zn from oxidised and acidified layers of these sediments (i.e. acid sulphate soil is thus not explained by anomalously high natural or anthropogenic metal concentrations of the soils/sediments, but by an inherent highly mobile metal pool. Spatial-distribution maps highlight areas of elevated S and Mn concentrations, where it is likely that ditching and subsequent oxidation will result in an exceptionally large release of protons and Mn respectively.;

  12. Quantification of Fine-grained Sediment Concentration in the Aquatic Environment Using Optical and Acoustic Sensors: Insight from Lab Experiments

    Science.gov (United States)

    Xu, K.; Champagne, B. N.

    2017-12-01

    The transport of sediment in the coastal zone and continental shelf is highly impacted by fluvial and oceanographic dynamics. In Louisiana, the Mississippi River delivers a bulk of water, sediment, and nutrients to the coast. However, coastal land loss highlights the importance of the sediment deposited at the mouth of the river. Sediment is the foundation to build land and suspended sediment concentration (SSC) tracks the delivery, deposition, and erosion of sediment. On a more applicable scale, variables such as SSC can be used to calculate sediment transport flux, an important parameter for projects such as sediment diversions and barrier island restoration. In order to rely on suspended sediment concentration (SSC) as continuous data, lab experiments are needed to establish the relationship between turbidity and SSC. Factors such as sensor type (optical or acoustic) and grain size (coarse or fine) can greatly impact the estimated SSC. In this study, fine-grained sediment was collected from multiple sites in coastal Louisiana and used to calibrate both optical backscatter (OBS) and acoustic backscatter (ABS) sensors to establish the relationship between sensor type and accuracy of the SSC estimation. Multiple grain-size analyses using a Laser Diffraction Particle Size Analyzer helped determine the effects of sensor accuracy regarding grain size. The results of these experiments were combined in order to establish the calibration curves of SSC. Our results indicated that the OBS-3A sensor's turbidity data were more correlated with the SSC than the OBS-5+'s data. Possible explanations for this could be due to differences between the instruments' measuring ranges and their sensitivity to various grain sizes. This technology development has a broad impact to the studies of sediment delivery, transport, and deposition in multiple types of coastal protection and restoration projects.

  13. A MATHEMATICAL MODEL TO PREDICT NICKEL CONCENTRATION IN KARAJ RIVER SEDIMENTS

    Directory of Open Access Journals (Sweden)

    R. Ramezankhani, A. A. M. Sharif, M. T. Sadatipour, R.Abdolahzadeh

    2008-04-01

    Full Text Available The contamination of surface waters through human activities has been intensified over the past years as population density has increased. Nickel is a metallic element and fuel combustion, nickel mining, refining waste, sewage sludge, and incineration are the major sources of nickel propagation. Nickel from various industrial wastewaters and other sources finally are disposed into water bodies. In this work, Karaj river was considered from 50º to 50º 14´longitudes and 35º 45´ to 35º 58´ latitudes and the presence of nickel was also assessed in this area. Sixteen stations were randomly selected and sediment samples were collected in polyethylene containers. Some water quality parameters such as pH, temperature, dissolved oxygen, electrical conductivity, were determind by direct on-site measurements. To measure COD, 16 water samples were collected in dark bottles and transferred to laboratory spatial parameters such as slope and distance from start point were also calculated by ARCGIS 9.2. The relation between Ni concentration with spatial parameters and water quality parameters were obtained by multivariate analysis. Results showed that there was a significant relation between Ni concentration in sediments and distance from start point and electrical conductivity.

  14. In-Stream Sediment Dynamics for predicted environmental concentration calculations of plant protection products in the FOCUSSW Scenarios

    Science.gov (United States)

    Strehmel, Alexander; Erzgräber, Beate; Gottesbüren, Bernhard

    2016-04-01

    The exposure assessment for the EU registration procedure of plant protection products (PPP), which is based on the 'Forum for the co-ordination of pesticide fate models and their use' (FOCUS), currently considers only periods of 12-16 months for the exposure assessment in surface water bodies. However, in a recent scientific opinion of the European Food Safety Authority (EFSA) it is argued that in a multi-year exposure assessment, the accumulation of PPP substances in river sediment may be a relevant process. Therefore, the EFSA proposed to introduce a sediment accumulation factor in order to account for enrichment of PPP substances over several years in the sediment. The calculation of this accumulation factor, however, would consider degradation in sediment as the only dissipation path, and does not take into account riverine sediment dynamics. In order to assess the influence of deposition and the possible extent of substance accumulation in the sediment phase, the hydraulic model HEC-RAS was employed for an assessment of in-stream sediment dynamics of the FOCUS stream scenarios. The model was parameterized according to the stream characteristics of the FOCUS scenarios and was run over a period of 20 years. The results show that with the distribution of grain sizes and the ranges of flow velocity in the FOCUS streams the main sediment process in the streams is transport. First modeling results suggest that about 80% of the eroded sediment mass from the adjacent field are transported to the downstream end of the stream and out of the system, while only about 20% are deposited in the river bed. At the same time, only about 30% of in-stream sediment mass stems from the adjacent field and is associated with PPP substance, while the remaining sediment consists of the substance-free base sediment concentration regarded in the scenarios. With this, the hydraulic modelling approach is able to support the development of a meaningful sediment accumulation factor by

  15. Characterization of sediments in the Clinch River, Tennessee, using remote sensing and multi-dimensional GIS techniques

    International Nuclear Information System (INIS)

    Levine, D.A.; Hargrove, W.W.; Hoffman, F.

    1995-01-01

    Remotely-sensed hydro-acoustic data were used as input to spatial extrapolation tools in a GIS to develop two- and three-dimensional models of sediment densities in the Clinch River arm of Watts Bar Reservoir, Tennessee. This work delineated sediment deposition zones to streamline sediment sampling and to provide a tool for estimating sediment volumes and extrapolating contaminant concentrations throughout the system. The Clinch River arm of Watts Bar Reservoir has been accumulating sediment-bound contaminants from three Department of Energy (DOE) facilities on the Oak Ridge Reservation, Tennessee. Public concern regarding human and ecological health resulted in Watts Bar Reservoir being placed on the National Priorities List for SUPERFUND. As a result, DOE initiated and is funding the Clinch River Environmental Restoration Program (CR-ERP) to perform a remedial investigation to determine the nature and extent of sediment contamination in the Watts Bar Reservoir and the Clinch River and to quantify any human or ecological health risks. The first step in characterizing Clinch River sediments was to determine the locations of deposition zones. It was also important to know the sediment type distribution within deposition zones because most sediment-bound contaminants are preferentially associated to fine particles. A dual-frequency hydro-acoustic survey was performed to determine: (1) depth to the sediment water interface, (2) depth of the sediment layer, and (3) sediment characteristics (density) with depth (approximately 0.5-foot intervals). An array of geophysical instruments was used to meet the objectives of this investigation

  16. High arsenic (As concentrations in the shallow groundwaters of southern Louisiana: Evidence of microbial controls on As mobilization from sediments

    Directory of Open Access Journals (Sweden)

    Ningfang Yang

    2016-03-01

    Full Text Available Study region: The Mississippi Delta in southern Louisiana, United States. Study focus: The probable role that microbial respiration plays in As release from the shallow aquifer sediments. New hydrological insights for the region: Shallow groundwaters in southern Louisiana have been reported to contain elevated As concentrations, whereas mechanisms responsible for As release from sediments have rarely been studied in this region. Microbial respiration is generally considered the main mechanism controlling As release in reducing anoxic aquifers such as the shallow aquifers in southern Louisiana and those of the Bengal basin. This study investigates the role microbial respiration plays in As release from shallow aquifer sediments in southern Louisiana through sediment incubation experiments and porewater analysis. Arsenic concentrations were the lowest in the sterilized control experiments, slightly higher in the un-amended experiments, and the highest in the experiments amended with acetate, and especially those amended with both acetate and AQDS (9,10-anthraquinone-2,6-disulfonic acid. Although Fe and Mn generally decreased at the beginning of all the experiments, they did follow a similar trend to As after the decrease. Porewater analysis showed that As and Fe concentrations were generally positively correlated and were higher in the coarse-grained sediments than in the fine-grained sediments. Results of the investigation are consistent with microbial respiration playing a key role in As release from the shallow aquifers sediments in southern Louisiana. Keywords: Groundwater, Arsenic, Microbial respiration

  17. Concentration of Antifouling Biocides and Metals in Sediment Core Samples in the Northern Part of Hiroshima Bay

    Directory of Open Access Journals (Sweden)

    Noritaka Tsunemasa

    2014-06-01

    Full Text Available Accumulation of Ot alternative antifoulants in sediment is the focus of this research. Much research had been done on surface sediment, but in this report, the accumulation in the sediment core was studied. The Ot alternative antifoulants, Diuron, Sea-Nine211, and Irgarol 1051, and the latter’s degradation product, M1, were investigated in five samples from the northern part of Hiroshima Bay. Ot compounds (tributyltin (TBT and triphenyltin (TPT were also investigated for comparison. In addition, metal (Pb, Cu, Zn, Fe and Mn levels and chronology were measured to better understand what happens after accumulation on the sea floor. It was discovered that Ot alternative antifoulant accumulation characteristics in sediment were like Ot compounds, with the concentration in the sediment core being much higher than surface sediment. The concentration in sediment seems to have been affected by the regulation of Ot compounds in 1990, due to the concentration of Ot alternative antifoulants and Ot compounds at the survey point in front of the dock, showing an increase from almost the same layer after the regulation.

  18. PCB concentrations in sediments from the Gulf of Nicoya estuary, Pacific coast of Costa Rica

    Directory of Open Access Journals (Sweden)

    Alison L Spongberg

    2004-12-01

    Full Text Available Thirty-one sediment samples collected from 1996-2003 from the Gulf of Nicoya estuary on the north- western coast of Costa Rica, have been obtained for PCB analyses. This is part of the first study to evaluate the PCB contamination in coastal Costa Rica.Overall, the concentrations are low, especially when compared to sediments from more temperate climates and/or sediments from more heavily industrialized areas. Values average less than 3 ng/g dw sediment, however, a few samples contained up to 7 ng/g dw sediment. Sediments with the highest concentrations were located in the Punta Morales area, where muds were sampled from among mangrove roots. The Puntarenas samples had surprisingly low PCB concentrations, likely due to their sandy lithology. The congener distribution within the majority of the samples showed signs of either recent sources or lack of degradation. However, a few sites, specifically some of the inter-gulf islands and more remote samples had congener distributions indicative of airborne contaminants and/or degradation. Considering the presence of air-borne PCBs in the Gulf of Papagayo to the north, the lack of airborne PCBs and more varied congener distribution in the Gulf of Nicoya estuary was surprisingSe analizó los bifenilos policlorados (PCB en 31 muestras de sedimentos colectadas entre 1996 -2003 en el estuario del Golfo de Nicoya, costa noroeste de Costa Rica. Esto es parte de un primer estudio para evaluar la contaminación por PCB en aguas costeras de Costa Rica. En general, las concentraciones fueron bajas especialmente cuando se les compara con sedimentos de climas templados y / o sedimentos de areas altamente industrializadas. Los valores promedio son inferiores a 3 ng / dw (peso seco de sedimento. Sin embargo, unas pocas muestras contienen hasta 7 ng/ g dw de sedimento. Los sedimentos con las concentraciones más altas están localizados en el area de Punta Morales, en cienos de entre raíces de mangle. Las

  19. Source Evaluation and Trace Metal Contamination in Benthic Sediments from Equatorial Ecosystems Using Multivariate Statistical Techniques.

    Directory of Open Access Journals (Sweden)

    Nsikak U Benson

    Full Text Available Trace metals (Cd, Cr, Cu, Ni and Pb concentrations in benthic sediments were analyzed through multi-step fractionation scheme to assess the levels and sources of contamination in estuarine, riverine and freshwater ecosystems in Niger Delta (Nigeria. The degree of contamination was assessed using the individual contamination factors (ICF and global contamination factor (GCF. Multivariate statistical approaches including principal component analysis (PCA, cluster analysis and correlation test were employed to evaluate the interrelationships and associated sources of contamination. The spatial distribution of metal concentrations followed the pattern Pb>Cu>Cr>Cd>Ni. Ecological risk index by ICF showed significant potential mobility and bioavailability for Cu, Cu and Ni. The ICF contamination trend in the benthic sediments at all studied sites was Cu>Cr>Ni>Cd>Pb. The principal component and agglomerative clustering analyses indicate that trace metals contamination in the ecosystems was influenced by multiple pollution sources.

  20. The use of nuclear muprobe techniques to study the chemistry of lacustrine sediments and particles

    Science.gov (United States)

    Grime, G. W.; Davison, W.

    1993-05-01

    The Oxford SPM has been used in two novel studies of lake chemistry: (a) The distribution of dissolved iron in sediment pore waters close to the sediment/water interface has been measured using the novel technique of diffusive equilibration in a thin film (DET). In this technique, which has a spatial resolution of O stoichiometry of single particles. The particles were filtered from a depth of 14 m in Esthwaite Water in the English Lake District and handled in anoxic conditions until evacuation in the SPM sample chamber. Two distinct compositions of iron oxide were determined in clusters of about 5 μm diameter. Analysis by PIXE revealed that FeS was uniformly distributed in the particulate material and that it also contained elevated levels of Cu and Zn. This study was the first to demonstrate directly that discrete clusters of iron oxides are present in black particulate material which is commonly considered to comprise iron sulphides.

  1. Comparison of five bioassay techniques for assessing sediment-bound contaminants

    OpenAIRE

    Ahlf, Wolfgang; Calmano, Wolfgang; Erhard, Judith; Förstner, Ulrich

    1989-01-01

    Biological response could not be predicted based on chemical concentration of the sediment contaminants. Bioassays integrate the response of test organisms to contaminants and nutrients. Comparative results of five acute bioassays indicated that Neubauer phytoassay was the most sensitive. The mircobial biomass and algal growth tests indicated a response to the availability of contaminants and nutrients. These results suggest the usefulness of a diversity of bioassays in toxicity testing of se...

  2. Determination of solid flow for bottom sediment drag of Parana river using tracer techniques

    International Nuclear Information System (INIS)

    Aoki, Pedro E.; Enokihara, Cyro T.; Rocca, Hector C.C.; Bittencourt, Andre V.L.

    1997-01-01

    Radioactive tracing technique with labeled sand was employed to evaluate the bottom sediment drag of Parana River, near Guaira City, State of Parana. 198 Au radioisotope was used and measurements have been performed for a period of fifteen days. A bed load rate of 914,8 t/day was obtained for a laminar layer of 0,33 mean thickness and 1,65 m/day mean velocity. (author). 5 refs., 7 figs., 3 tabs

  3. Testing a laser-induced breakdown spectroscopy technique on the Arctic sediments

    Science.gov (United States)

    Han, D.; Nam, S. I.

    2017-12-01

    Physical and geochemical investigations coupled with the Laser-induced Breakdown Spectroscopy (LIBS) were performed on three surface sediment cores (ARA03B/24BOX, ARA02B/01(A)MUC, ARA02B/02MUC and ARA02B/03(A)MUC) recovered from the western Arctic Ocean (Chukchi Sea) during IBRV ARON expeditions in 2012. The LIBS technique was applied to carry out elemental chemical analysis of the Arctic sediments and compared with that measured by ITRAX X-ray fuorescence (XRF) core scanning. LIBS and XRF have shown similar elemental composition within each sediment core. In this study, mineral composition (XRD), grain size distribution and organic carbon content as well as elemental composition (LIBS) were all considered to understand paleoenvironmental changes (ocean circulation, sea-ice drift, iceberg discharge, and etc.) recorded in the Arctic Holocene sediment. Quantitative LIBS analysis shows a gradually varying distribution of the elements along the sampled core and clear separation between the cores. The cores are geochemically characterized by elevated Mn profile. The gradient of mineral composition and grain sizes among the cores shows regional distribution and variation in sedimentary condition due to geological distance between East Siberian and North America. The present study reveals that a LIBS technique can be employed for in-situ sediment analyses for the Arctic Ocean. Furthermore, LIBS does not require costly equipment, trained operators, and complicated sample pre-treatment processes compared to Atomic absorption spectroscopy (AAS) and inductively coupled plasma emission spectroscopy (ICP), and also known to show relatively high levels of sensitivity, precision, and distinction than XRF analysis, scanning electron microscopy-energy dispersive spectrometry (SEM-EDS), and electron probe X-ray microanalysis (EPMA).

  4. Metal concentrations and mobility in marine sediment and groundwater in coastal reclamation areas: A case study in Shenzhen, China

    International Nuclear Information System (INIS)

    Chen Kouping; Jiao, Jiu J.

    2008-01-01

    The concentrations of metals in the buried marine sediment and groundwater were differently affected by land reclamation. Nine metals (V, Cr, Mn, Co, Ni, Cu, Zn, Cd and Pb) in sediment and coastal groundwater from reclamation areas in Shenzhen were examined. The gradually decreased concentrations (V, Cr, Mn, Ni, Cu, Zn) in sediment and relatively higher concentrations (V, Cr, Mn, Co, Ni, Cu and Cd) in groundwater within reclamation areas were observed. The increase of V, Cr, Mn, Ni, Cu and Cd concentrations in groundwater within reclamation areas subsequently after land reclamation should be resulted from the mobilization of these metals accumulated in the sediment. These metals appear to be easily mobilized from solid phase to solution phase after reclamation. The physico-chemical changes such as reduction in pH and salinity in water environment induced by land reclamation appear to be responsible for metal mobility in the sediment-groundwater system. - Metals in coastal groundwater and marine sediment are affected by land reclamation

  5. Concentrations of chlorinated organic compounds in biota and bed sediment in streams of the San Joaquin Valley, California

    Science.gov (United States)

    Brown, L.R.

    1997-01-01

    Samples of resident biota and bed sediments were collected in 1992 from 18 sites on or near the floor of the San Joaquin Valley, California, for analysis of 33 organochlorine compounds. The sites were divided into five groups on the basis of physiographic region and land use. Ten compounds were detected in tissue, and 15 compounds were detected in bed sediment. The most frequently detected compound in both media was p,p'-DDE. Concentrations of ??DDT (sum of o,p'- and p, p' forms of DDD, DDE, and DDT) were statistically different among groups of sites for both tissue and sediment (Kruskal- Wallis, p TOC) normalized concentrations were significantly correlated with specific conductance and pH (p TOC in sediment. The results of this study did not indicate any clear advantage to using either bed sediment or tissues in studies of organochlorine chemicals in the environment. Some guidelines for protection of fish and wildlife were exceeded. Concentrations of organochlorine chemicals in biota, and perhaps sediment, have declined from concentrations measured in the 1970s and 1980s, but remain high compared to other regions of the United States.

  6. Observations on the redistribution of plutonium and americium in the Irish Sea sediments, 1978 to 1996: concentrations and inventories

    International Nuclear Information System (INIS)

    Kershaw, P.J.; Denoon, D.C.; Woodhead, D.S.

    1999-01-01

    The distribution of plutonium and americium in the sub-tidal sediments of the Irish Sea is described following major surveys in 1978, 1983, 1988 and 1995. Concentrations in surface sediments have declined near the source at Sellafield since 1988. Time-series of inter-tidal surface sediment concentrations are presented from 1977 onwards, revealing the importance of sediment reworking and transport in controlling the evolution of the environmental signal. The surface and near-surface sediments, in the eastern Irish Sea 'mud-patch', are generally well mixed with respect to Pu (α) and 241 Am distributions but show increasing variability with depth - up to 4 orders of magnitude in concentration. The inventories of 239,240 Pu and 241 Am in the sub-tidal sediments have been estimated and compared with the reported decay-corrected discharges. These amounted to 360 and 545 TBq respectively, in 1995, about 60% of the total decay-corrected discharge. Part of the unaccounted fraction may be due to unrepresentative sampling of the seabed. It is speculated that some tens of TBq of plutonium and 241 Am reside undetected in the large volumes of coarse-grained, sub-tidal and inter-tidal sediment which characterise much of the Irish Sea. This has been due to the inability of the available corers to penetrate to the base of contamination in these mobile sediments. Further observations are needed to verify and quantify the missing amount. A budget of plutonium-α and 241 Am has been estimated based on published observations in the three main compartments: water column, sub-tidal and inter-tidal sediments. This amounts to 460-540 TBq and 575-586 TBq respectively, or 64-75% and 60-61%, of the decay-corrected reported discharge. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

  7. Central Colorado Assessment Project (CCAP)-Geochemical data for rock, sediment, soil, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; DeWitt, Ed H.; Klein, Terry L.

    2010-01-01

    This database was initiated, designed, and populated to collect and integrate geochemical data from central Colorado in order to facilitate geologic mapping, petrologic studies, mineral resource assessment, definition of geochemical baseline values and statistics, environmental impact assessment, and medical geology. The Microsoft Access database serves as a geochemical data warehouse in support of the Central Colorado Assessment Project (CCAP) and contains data tables describing historical and new quantitative and qualitative geochemical analyses determined by 70 analytical laboratory and field methods for 47,478 rock, sediment, soil, and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed either in the analytical laboratories of the USGS or by contract with commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects. In addition, geochemical data from 7,470 sediment and soil samples collected and analyzed under the Atomic Energy Commission National Uranium Resource Evaluation (NURE) Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) program (henceforth called NURE) have been included in this database. In addition to data from 2,377 samples collected and analyzed under CCAP, this dataset includes archived geochemical data originally entered into the in-house Rock Analysis Storage System (RASS) database (used by the USGS from the mid-1960s through the late 1980s) and the in-house PLUTO database (used by the USGS from the mid-1970s through the mid-1990s). All of these data are maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB and from the NURE database were used to generate most of this dataset. In addition, USGS data that have been excluded previously from the NGDB because the data predate earliest USGS geochemical databases, or were once excluded for programmatic reasons

  8. Responses in sediment phosphorus and lanthanum concentrations and composition across 10 lakes following applications of lanthanum modified bentonite

    DEFF Research Database (Denmark)

    Dithmer, Line; Nielsen, Ulla Gro; Lürling, Miquel

    2016-01-01

    and binding forms, P adsorption capacity of discrete sediment layers, and pore water P concentrations. Lanthanum phosphate mineral phases were confirmed by solid state (31)P MAS NMR and LIII EXAFS spectroscopy. Rhabdophane (LaPO4 · nH2O) was the major phase although indications of monazite (LaPO4) formation...... conditions of P retention (with the exception of two lakes) by sediments, indicating effective control of sediment P release, i.e. between two and nine years after treatment....

  9. On the anomalous concentrations of uranium in sediments from hydrothermal mounds. A geochemical roll-type mechanism

    International Nuclear Information System (INIS)

    Bernat, M.; Benhassaine, A.

    1987-01-01

    Sediments close to the nontronite formations of hydrothermal mounds often show anomalously high concentrations of uranium. This is frequently interpreted as being due to seeping of low temperature U bearing hydrothermal water through the basal basalt and into the overlying sediments. But we think that this phenomenon is the consequence of leaching of the sediment by hydrothermal water initially depleted in uranium. The migration of U is favoured by the pH of these water which dissolve the iron oxides and hydroxides giving Fe +++ ions in solution. The location and strength of the formed U anomalies are controlled by geochemical and hydrodynamicals factors. 22 refs [fr

  10. Uranium hydrogeochemical and stream sediment reconnaissance of the Newcastle NTMS Quadrangle, Wyoming, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Goff, S.J.; Sandoval, W.F.; Gallimore, D.L.; Talcott, C.L.; Martinez, R.G.; Minor, M.E.; Mills, C.F.

    1980-06-01

    Water and sediment samples were collected and each water sample was analyzed for U, and each sediment sample was analyzed for 43 elements, including U and Th. Uranium concentrations in water samples range from below the detection limit of 0.02 ppB to 702.26 ppB and have a median of 1.73 ppB and a mean of 11.76 ppB. Water samples containing high uranium concentrations generally are associated with known uranium mining activity or units known to be uranium bearing. About one-third of the water samples containing high uranium concentrations were collected from locations within the Pumpkin Buttes and Turnercrest-Ross Districts. Nearly half of the water samples containing high uranium concentrations were collected from locations just west of the Monument Hill and Highland Flats-Box Creek Districts. Similar anomalous uranium concentrations in this region have been reported updip from Exxon's Highland uranium deposits. High uranium concentrations were also found associated with the Lance Creek-Old Woman Anticline District. Uranium concentrations in sediment samples range from 1.14 to 220.70 ppM and have a median of 3.37 ppM and a mean of 4.03 ppM. Throughout the major uranium mining districts of the Powder River Basin, sediment samples with high uranium concentrations were collected from dry streams located near wells producing water samples with high uranium concentrations. High uranium concentrations were also found associated with the Lance Creek oil field where uranium mineralization is known in the White River formation. High uranium concentrations were also found in sediment samples in areas where uranium mineralization is not known. These samples are from dry streams in areas underlain by the White River formation, the Niobrara formation, and the Pierre, Carlisle, Belle Fourche, and Mowry shales

  11. Equilibrium Partitioning Sediment Benchmarks (ESBs) for the Protection of Benthic Organisms: Procedures for the Determination of the Freely Dissolved Interstitial Water Concentrations of Nonionic Organics

    Science.gov (United States)

    This document describes procedures to determine the concentrations of nonionic organic chemicals in sediment interstitial waters. In previous ESB documents, the general equilibrium partitioning (EqP) approach was chosen for the derivation of sediment benchmarks because it account...

  12. Uranium hydrogeochemical and stream sediment reconnaissance of the Pueblo NTMS quadrangel, Colorado, including concentrations of forty-three additional elements

    International Nuclear Information System (INIS)

    Shannon, S.S. Jr.

    1978-12-01

    This report is a supplement to the HSSR uranium evaluation report for the Pueblo quadrangle (Shannon, 1978), which presented the field and uranium data for the 861 water and 1060 sediment samples collected from 1402 locations in the quadrangle. This supplement presents those data again and the results of subsequent multielement analyses of those HSSR samples. In addition to uranium, the concentrations of 12 elements are presented for the waters and 42 elements for the sediments

  13. Retrieval of suspended sediment concentrations using Landsat-8 OLI satellite images in the Orinoco River (Venezuela)

    Science.gov (United States)

    Yepez, Santiago; Laraque, Alain; Martinez, Jean-Michel; De Sa, Jose; Carrera, Juan Manuel; Castellanos, Bartolo; Gallay, Marjorie; Lopez, Jose L.

    2018-01-01

    In this study, 81 Landsat-8 scenes acquired from 2013 to 2015 were used to estimate the suspended sediment concentration (SSC) in the Orinoco River at its main hydrological station at Ciudad Bolivar, Venezuela. This gauging station monitors an upstream area corresponding to 89% of the total catchment area where the mean discharge is of 33,000 m3·s-1. SSC spatial and temporal variabilities were analyzed in relation to the hydrological cycle and to local geomorphological characteristics of the river mainstream. Three types of atmospheric correction models were evaluated to correct the Landsat-8 images: DOS, FLAASH, and L8SR. Surface reflectance was compared with monthly water sampling to calibrate a SSC retrieval model using a bootstrapping resampling. A regression model based on surface reflectance at the Near-Infrared wavelengths showed the best performance: R2 = 0.92 (N = 27) for the whole range of SSC (18 to 203 mg·l-1) measured at this station during the studied period. The method offers a simple new approach to estimate the SSC along the lower Orinoco River and demonstrates the feasibility and reliability of remote sensing images to map the spatiotemporal variability in sediment transport over large rivers.

  14. Acoustic Doppler velocimeter backscatter for quantification of suspended sediment concentration in South San Francisco Bay, USA

    Science.gov (United States)

    Öztürk, Mehmet; Work, Paul A.

    2016-01-01

    A data set was acquired on a shallow mudflat in south San Francisco Bay that featured simultaneous, co-located optical and acoustic sensors for subsequent estimation of suspended sediment concentrations (SSC). The optical turbidity sensor output was converted to SSC via an empirical relation derived at a nearby site using bottle sample estimates of SSC. The acoustic data was obtained using an acoustic Doppler velocimeter. Backscatter and noise were combined to develop another empirical relation between the optical estimates of SSC and the relative backscatter from the acoustic velocimeter. The optical and acoustic approaches both reproduced similar general trends in the data and have merit. Some seasonal variation in the dataset was evident, with the two methods differing by greater or lesser amounts depending on which portion of the record was examined. It is hypothesized that this is the result of flocculation, affecting the two signals by different degrees, and that the significance or mechanism of the flocculation has some seasonal variability. In the earlier portion of the record (March), there is a clear difference that appears in the acoustic approach between ebb and flood periods, and this is not evident later in the record (May). The acoustic method has promise but it appears that characteristics of flocs that form and break apart may need to be accounted for to improve the power of the method. This may also be true of the optical method: both methods involve assuming that the sediment characteristics (size, size distribution, and shape) are constant.

  15. Quantification and Analysis of Suspended Sediments Concentration Using Mobile and Static Acoustic Doppler Current Profiler Instruments

    Directory of Open Access Journals (Sweden)

    Angga Dwinovantyo

    2017-01-01

    Full Text Available The application of Acoustic Doppler Current Profiler (ADCP can be used not only for measuring ocean currents, but also for quantifying suspended sediment concentrations (SSC from acoustic backscatter strength based on sonar principle. Suspended sediment has long been recognized as the largest sources of sea contaminant and must be considered as one of the important parameters in water quality of seawater. This research was to determine SSC from measured acoustic backscattered intensity of static and mobile ADCP. In this study, vertically mounted 400 kHz and 750 kHz static ADCP were deployed in Lembeh Strait, North Sulawesi. A mobile ADCP 307.2 kHz was also mounted on the boat and moved to the predefined cross-section, accordingly. The linear regression analysis of echo intensity measured by ADCP and by direct measurement methods showed that ADCP is a reliable method to measure SSC with correlation coefficient (r 0.92. Higher SSC was observed in low water compared to that in high water and near port area compared to those in observed areas. All of this analysis showed that the combination of static and mobile ADCP methods produces reasonably good spatial and temporal data of SSC.

  16. Evaluating suitability of MODIS-Terra images for reproducing historic sediment concentrations in water bodies: Lake Tana, Ethiopia

    Science.gov (United States)

    Kaba, Essayas; Philpot, William; Steenhuis, Tammo

    2014-02-01

    Government and NGO funded conservation programs are being implemented in developing countries with the potential benefit of reduced sediment inflow into fresh water lakes. However, these claims are difficult to verify due to limited historical sediment concentration data in lakes and rivers. Remote sensing can potentially aid in monitoring sediment concentration. With almost daily availability over the past ten years and consistent atmospheric correction applied to the images, Moderate Resolution Imaging Spectroradiometer (MODIS) 250 meter images are potential resources capable of monitoring future concentrations and reconstructing historical sediment concentration records. In this paper, site-specific relationships are developed between reflectance in near-infrared (NIR) images and three factors: total suspended solids (TSS), turbidity and Secchi depth for Lake Tana near the mouth of the Gumara River. The first two sampling campaigns on November 27, 2010 and May 13, 2011 are used in calibration. Reflectance in the NIR varies linearly with turbidity (R2 = 0.89) and TSS (R2 = 0.95). Secchi depth fit best to an exponential relation with R2 of 0.74. The relationships are validated using a third sample set collected on November 7, 2011 with RMSE of 11 Nephelometric Turbidity Units (NTU) for Turbidity, 16.5 mg l-1 for TSS and 0.12 meters for Secchi depth. The MAE was 10% for TSS, 14% for turbidity and 0.1% for Secchi depth. Using the relationship for TSS, a 10-year time series of sediment concentration in Lake Tana near the Gumara River was plotted. It was found that after the severe drought of 2002 and 2003 the concentration in the lake increased significantly. The results showed that MODIS images are potential cost effective tools to monitor suspended sediment concentration and obtain a past history of concentration for evaluating the effect of best management practices.

  17. Calculation and evaluation of sediment effect concentrations for the amphipod Hyalella azteca and the midge Chironomus riparius

    Science.gov (United States)

    Ingersoll, Christopher G.; Haverland, Pamela S.; Brunson, Eric L.; Canfield, Timothy J.; Dwyer, F. James; Henke, Chris; Kemble, Nile E.; Mount, David R.; Fox, Richard G.

    1996-01-01

    Procedures are described for calculating and evaluating sediment effect concentrations (SECs) using laboratory data on the toxicity of contaminants associated with field-collected sediment to the amphipod Hyalella azteca and the midge Chironomus riparius. SECs are defined as the concentrations of individual contaminants in sediment below which toxicity is rarely observed and above which toxicity is frequently observed. The objective of the present study was to develop SECs to classify toxicity data for Great Lake sediment samples tested with Hyalella azteca and Chironomus riparius. This SEC database included samples from additional sites across the United States in order to make the database as robust as possible. Three types of SECs were calculated from these data: (1) Effect Range Low (ERL) and Effect Range Median (ERM), (2) Threshold Effect Level (TEL) and Probable Effect Level (PEL), and (3) No Effect Concentration (NEC). We were able to calculate SECs primarily for total metals, simultaneously extracted metals, polychlorinated biphenyls (PCBs), and polycyclic aromatic hydrocarbons (PAHs). The ranges of concentrations in sediment were too narrow in our database to adequately evaluate SECs for butyltins, methyl mercury, polychlorinated dioxins and furans, or chlorinated pesticides. About 60 to 80% of the sediment samples in the database are correctly classified as toxic or not toxic depending on type of SEC evaluated. ERMs and ERLs are generally as reliable as paired PELs and TELs at classifying both toxic and non-toxic samples in our database. Reliability of the SECs in terms of correctly classifying sediment samples is similar between ERMs and NECs; however, ERMs minimize Type I error (false positives) relative to ERLs and minimize Type II error (false negatives) relative to NECs. Correct classification of samples can be improved by using only the most reliable individual SECs for chemicals (i.e., those with a higher percentage of correct classification). SECs

  18. Assessment of metal concentrations in sediment samples from Billings Reservoir, Rio Grande tributary, Sao Paulo, Brazil; Avaliacao da concentracao de metais em amostras de sedimento do Reservatorio Billings, Braco Rio Grande, Sao Paulo, Brasil

    Energy Technology Data Exchange (ETDEWEB)

    Bostelmann, Eleine

    2006-07-01

    The present study chemically characterized sediment samples from the Billings reservoir, Rio Grande tributary, in the Metropolitan region of Sao Paulo, by determining metal concentration and other elements of interest. The chosen chemical parameters for this characterization were Aluminum, Arsenic, Barium, Cadmium, Copper, Chromium, Iron, Lead, Manganese, Mercury, Nickel, Selenium and Zinco. These parameters are also used in the water quality index, with the exception of Selenium. The concentrations were determined through different analytical techniques such as atomic absorption spectrometry (FAAS, GFAAS and CVAAS), optical emission spectrometry (ICP OES) and neutron activation analysis. These analytical methodologies were assessed for precision, accuracy and detection and/or quantification limits for the sediment elements in question. Advantages and disadvantages of each technique for each element and its concentration were also discussed. From these assessments the most adequate technique was selected for the routine analysis of sediment samples for each element concentration determination. This assessment verified also that digestion in a closed microwave system with nitric acid is efficient for the evaluation of extracted metals of environmental interest. The analytical techniques chosen were equally efficient for metals determination. In the case of Cd and Pb, the FAAS technique was selected due to better results than ICP OES, as it does not present matrix interference. The concentration values obtained for metals As, Cd, Cu, Cr, Hg, Ni, Pb and Zn in the sediment samples were compared to Canadian Council of Minister of the Environment (CCME) TEL and PEL values. (author)

  19. The Effect of Water Harvesting Techniques on Runoff, Sedimentation, and Soil Properties

    Science.gov (United States)

    Al-Seekh, Saleh H.; Mohammad, Ayed G.

    2009-07-01

    This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that runoff is reduced by 65-85% and sedimentation by 58-69% in stone terraces and semi-circle bunds compared to the control at the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80% and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques compared to the control in all treatments at the three study sites. In addition, the difference between the control and the water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation, via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the amount of supplemental irrigation required for growing fruit trees.

  20. The effect of water harvesting techniques on runoff, sedimentation, and soil properties.

    Science.gov (United States)

    Al-Seekh, Saleh H; Mohammad, Ayed G

    2009-07-01

    This study addressed the hydrological processes of runoff and sedimentation, soil moisture content, and properties under the effect of different water harvesting techniques (treatments). The study was conducted at three sites, representing environmental condition gradients, located in the southern part of the West Bank. For each treatment, the study evaluated soil chemical and physical properties, soil moisture at 30 cm depth, surface runoff and sedimentation at each site. Results showed that runoff is reduced by 65-85% and sedimentation by 58-69% in stone terraces and semi-circle bunds compared to the control at the semi-humid site. In addition, stone terraces and contour ridges significantly reduced the amount of total runoff by 80% and 73%, respectively, at the arid site. Soil moisture content was significantly increased by water harvesting techniques compared to the control in all treatments at the three study sites. In addition, the difference between the control and the water harvesting structures were higher in the arid and semi-arid areas than in the semi-humid area. Soil and water conservation, via utilization of water harvesting structures, is an effective principle for reducing the negative impact of high runoff intensity and subsequently increasing soil moisture storage from rainfall. Jessour systems in the valley and stone terraces were effective in increasing soil moisture storage, prolonging the growing season for natural vegetation, and decreasing the amount of supplemental irrigation required for growing fruit trees.

  1. Investigating high zircon concentrations in the fine fraction of stream sediments draining the Pan-African Dahomeyan Terrane in Nigeria

    International Nuclear Information System (INIS)

    Key, Roger M.; Johnson, Christopher C.; Horstwood, Matthew S.A.; Lapworth, Dan J.; Knights, Katherine V.; Kemp, Simon J.; Watts, Michael; Gillespie, Martin; Adekanmi, Michael; Arisekola, Tunde

    2012-01-01

    Sixteen hundred stream sediments (<150 μm fraction) collected during regional geochemical surveys in central and SW Nigeria have high median and maximum concentrations of Zr that exceed corresponding Zr concentrations found in stream sediments collected from elsewhere in the World with similar bedrock geology. X-ray diffraction studies on a sub-set of the analysed stream sediments showed that Zr is predominantly found in detrital zircon grains. However, the main proximal source rocks (Pan-African ‘Older Granites’ of Nigeria and their Proterozoic migmatitic gneiss country rocks) are not enriched in zircon (or Zr). Nevertheless, U–Pb LA-ICP-MS dating with cathodoluminescence imaging on detrital zircons, both from stream sediment samples and underlying Pan-African ‘Older Granites’ confirms a local bedrock source for the stream sediment zircons. A combination of tropical/chemical weathering and continuous physical weathering, both by ‘wet season’ flash flooding and ‘dry season’ unidirectional winds are interpreted to have effectively broken down bedrock silicate minerals and removed much of the resultant clay phases, thereby increasing the Zr contents in stream sediments. The strong correlation between winnowing index (Th/Al) and Zr concentration across the study area support this interpretation. Therefore, ‘anomalous’ high values of Zr, as well as other elements concentrated in resistant ‘heavy’ minerals in Nigeria’s streams may not reflect proximal bedrock concentrations of these elements. This conclusion has important implications for using stream sediment chemistry as an exploration tool in Nigeria for primary metal deposits associated with heavy minerals.

  2. Scaling-up watershed discharge and sediment concentrations to regional scale: The Blue Nile Basin

    Science.gov (United States)

    Steenhuis, T. S.; Tilahun, S. A.; MacAlister, C.; Ayana, E. K.; Tebebu, T. Y.; Bayabil, H. K.; Zegeye, A. D.; Worqlul, A. W.

    2012-12-01

    Since Hewlet and Hibbert's publication there is recognition that saturated excess overland land flow is one of the main runoff mechanisms in vegetated watersheds. Predicting discharge in these watersheds can be accomplished by use of simplified models where the landscape features are grouped in potentially runoff contributing zones and permeable hillsides where the water infiltrates (and become the source of interflow and base flow). In this way each watershed can be described with nine parameters: fractional area and available water content for each of the three zones and three parameters describing subsurface flow. The information parameter values can be derived directly from the outflow hydrograph. We show that this model performs well for discharge and sediment concentration (with three additional parameters) on a 1 to 10 day time scale in the Blue Nile Basin for watersheds ranging in in size from 100 ha to 170,000 km2. Thus scaling up from watershed to regional scale can be accomplished with nine parameters for the hydrology and three additional parameters for sediment concentrations. Our hypothesis, that the model works so well, is that after the watershed wets up it drains to a characteristic moisture content distribution that is invariant in time. Wetting up is similar each time and is as a function of effective rainfall. This gives rise to a unique relationship between total storm runoff and total precipitation and surprisingly can be described by a modified form of the well-known SCS runoff equation. This approach has a direct parallel with Darcy's law in that although the average flow over several pores is described well, flow in individual pores cannot predicted. In our case the discharge can be simulated by averaging over the different runoff source area and permeable hillside in the watersheds, but processes within the zones cannot be described. This is not to say that information within the various zones cannot be simulated, but will require detailed

  3. Metal concentrations in surface water and sediments from Pardo River, Brazil: human health risks.

    Science.gov (United States)

    Alves, Renato I S; Sampaio, Carolina F; Nadal, Martí; Schuhmacher, Marta; Domingo, José L; Segura-Muñoz, Susana I

    2014-08-01

    Pardo River (Brazil) is suffering from an important anthropogenic impact due to the pressure of highly populated areas and the influence of sugarcane cultivation. The objective of the present study was to determine the levels of 13 trace elements (As, Be, Cd, Cr, Cu, Pb, Mn, Hg, Ni, Tl, Sn, V and Zn) in samples of surface water and sediments from the Pardo River. Furthermore, the human health risks associated with exposure to those metals through oral intake and dermal absorption were also evaluated. Spatial and seasonal trends of the data were closely analyzed from a probabilistic approach. Manganese showed the highest mean concentrations in both water and sediments, remarking the incidence of the agricultural activity and the geological characteristics within the basin. Thallium and arsenic were identified as two priority pollutants, being the most important contributors to the Hazard Index (HI). Since non-carcinogenic risks due to thallium exposure slightly exceeded international guidelines (HI>1), a special effort should be made on this trace element. However, the current concentrations of arsenic, a carcinogenic element, were in accordance to acceptable lifetime risks. Nowadays, there is a clear increasing growth in human population and economic activities in the Pardo River, whose waters have become a serious strategic alternative for the potential supply of drinking water. Therefore, environmental monitoring studies are required not only to assure that the current state of pollution of Pardo River does not mean a risk for the riverside population, but also to assess the potential trends in the environmental levels of those elements. Copyright © 2014 Elsevier Inc. All rights reserved.

  4. Different techniques of excess 210Pb for sedimentation rate estimation in the Sarawak and Sabah coastal waters

    International Nuclear Information System (INIS)

    Zal Uyun Wan Mahmood; Zaharudin Ahmad; Abdul Kadir Ishak; Che Abdul Rahim Mohamed

    2010-01-01

    Sediment core samples were collected at eight stations in the Sarawak and Sabah coastal waters using a gravity box corer to estimate sedimentation rates based on the activity of excess 210 Pb. The sedimentation rates derived from four mathematical models of CIC, Shukla-CIC, CRS and ADE were generally shown in good agreement with similar or comparable value at all stations. However, based on statistical analysis of independent sample t-test indicated that Shukla-CIC model was the most accurate, reliable and suitable technique to determine the sedimentation rate in the study area. (author)

  5. Sediment concentration and bed form structures of Gulf of Cambay from remote sensing

    Digital Repository Service at National Institute of Oceanography (India)

    Kunte, P.D.

    period, the bottom currents pull sediment (sand) particles supplied by major and minor rivers, rolling along the Gulf bed. These sediments perhaps participate in the formation of bed form structures. The topography of the Gulf bottom comprises of numerous...

  6. Larval Fish Feeding Responses to Variable Suspended Sediment and Planktonic Prey Concentrations

    National Research Council Canada - National Science Library

    Colby, D

    2004-01-01

    ... impacts from dredging projects. For example, in the context of nearshore placement of mixed sediments, concerns have been raised that winnowing of fine sediments from deposited dredged material may elevate turbidity and have a...

  7. Natural and man-made radionuclide concentrations in marine sediments of Gokova Bay, Aegean Turkish coast

    International Nuclear Information System (INIS)

    Tanbay, A.U.; Yener, G.; Mulsow, S.; Fowler, S.W.; Duman, M.

    1999-01-01

    The purpose of this research is to define a baseline study of selected radionuclides (natural and man made) on sediments collected along Goekova Bay. A total of six sediment cores (gravity corer) were collected, each sediment core was sliced in sections and 210 Po, 210 Pb, 226 Ra, 232 Th and 40 K and 137 Cs, 239,240 Pu, 238 Pu and 241 Am were determined for each layer of sediment

  8. Distribution of naturally occurring radionuclides activity concentration in East Malaysian marine sediment

    Energy Technology Data Exchange (ETDEWEB)

    Yii, M.W. [Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang (Malaysia)], E-mail: yii@nuclearmalaysia.gov.my; Zaharudin, A.; Abdul-Kadir, I. [Malaysian Nuclear Agency (Nuclear Malaysia), Bangi, 43000 Kajang (Malaysia)

    2009-04-15

    Studies of naturally occurring radioactive materials (NORM) distribution of {sup 226}Ra, {sup 228}Ra and {sup 40}K in East Malaysia were carried out as part of a marine coastal environment project. The results of measurements will serve as baseline data and background reference level for Malaysia coastlines. Sediments from 21 coastal locations and 10 near shore locations were collected for analyses. The samples were dried, finely ground, sealed in a container and stored for a minimum of 30 days to establish secular equilibrium between {sup 226}Ra and {sup 228}Ra and their respective radioactive progenies. They were counted using a high-purity germanium (HPGe) spectrometer covering the respective progeny energy peak. For {sup 40}K, the presence of this was measured directly via its 1460 keV energy peak. The concentration of {sup 226}Ra, {sup 228}Ra and {sup 40}K in samples obtained from coastal Sarawak ranged between 23 and 41 (mean 30{+-}2) Bq/kg, 27 and 45 (mean 39{+-}4) Bq/kg and 142 and 680 (mean 462{+-}59) Bq/kg, respectively. Meanwhile, the concentration of {sup 226}Ra, {sup 228}Ra and {sup 40}K for samples obtained from coastal Sabah ranged between 16 and 30 (mean 23{+-}2) Bq/kg, 23 and 45 (mean 35{+-}4) Bq/kg and 402 and 842 (mean 577{+-}75) Bq/kg, respectively. For the Sarawak near shore stations, the concentration of {sup 226}Ra, {sup 228}Ra and {sup 40}K ranged between 11 and 36 (mean 22{+-}2) Bq/kg, 21 and 65 (mean 39{+-}5) Bq/kg and 149 and 517 (mean 309{+-}41) Bq/kg, respectively. Meanwhile, the concentration of {sup 226}Ra, {sup 228}Ra and {sup 40}K for samples obtained from Sabah ranged between 9 and 31 (mean 14{+-}2) Bq/kg, 10 and 48 (mean 21{+-}3) Bq/kg and 140 and 580 (mean 269{+-}36) Bq/kg, respectively. The calculated external hazard values of between 0.17 and 0.33 (less than unity) showed that there is little risk of external hazard to the workers handling the sediments.

  9. Novel Quantification of Sediment Concentration in Turbidity Currents Through in-situ Measurements of Conductivity and Temperature

    Science.gov (United States)

    Xu, J.; Wang, Z.; Gwiazda, R.; Paull, C. K.; Talling, P.; Parsons, D. R.; Maier, K. L.; Simmons, S.; Cartigny, M.

    2017-12-01

    During a large turbidity current event observed by seven moorings placed along Monterey Canyon, offshore central California, in the axial channel between 300 and 1900 meters water depth, a conductivity/temperature sensor placed 11 meters above canyon floor on the mooring at 1500 meters water depth recorded a rapid decrease of conductivity and increase of temperature during the passage of a large turbidity current. The conductivity decline is unlikely caused by fresh water input owing to lack of precipitation in the region prior to the event. We investigated the mechanisms of turbidity currents' high sediment concentration reducing the measured conductivity. By conducting a series of laboratory experiments with a range of different concentrations, grain size, and water temperature combinations, we quantified a relationship between reduced conductivity and the elevated sediment concentration. This relationship can be used for estimating the very high sediment concentrations in a turbidity current with a condition of assuming constant salinity of the ambient seawater. The empirical relationship was then applied to the in-situ time-series of temperature and conductivity measured during this turbidity current. The highest sediment concentration, in the head of the flow, reached nearly 400 g/L (volume concentration 17%). Such a high value, which has yet been reported in literature for an oceanic turbidity current, will have significant implications for the dynamics and deposits of such flows.

  10. Fundamentals and techniques of nonimaging optics for solar energy concentration

    Science.gov (United States)

    Winston, R.; Ogallaher, J. J.

    1980-09-01

    Recent progress in basic research into the theoretical understanding of nonimaging optical systems and their application to the design of practical solar concentration was reviewed. Work was done to extend the previously developed geometrical vector flux formalism with the goal of applying it to the analysis of nonideal concentrators. Both phase space and vector flux representation for traditional concentrators were generated. Understanding of the thermodynamically derived relationship between concentration and cavity effects led to the design of new lossless and low loss concentrators for absorbers with gaps. Quantitative measurements of the response of real collector systems and the distribution of diffuse insolation shows that in most cases performance exceeds predictions in solar applications. These developments led to improved nonimaging solar concentrator designs and applications.

  11. Hydrocarbon composition and concentrations in the Gulf of Mexico sediments in the 3 years following the Macondo well blowout.

    Science.gov (United States)

    Babcock-Adams, Lydia; Chanton, Jeffrey P; Joye, Samantha B; Medeiros, Patricia M

    2017-10-01

    In April of 2010, the Macondo well blowout in the northern Gulf of Mexico resulted in an unprecedented release of oil into the water column at a depth of approximately 1500 m. A time series of surface and subsurface sediment samples were collected to the northwest of the well from 2010 to 2013 for molecular biomarker and bulk carbon isotopic analyses. While no clear trend was observed in subsurface sediments, surface sediments (0-3 cm) showed a clear pattern with total concentrations of n-alkanes, unresolved complex mixture (UCM), and petroleum biomarkers (terpanes, hopanes, steranes) increasing from May to September 2010, peaking in late November 2010, and strongly decreasing in the subsequent years. The peak in hydrocarbon concentrations were corroborated by higher organic carbon contents, more depleted Δ 14 C values and biomarker ratios similar to those of the initial MC252 crude oil reported in the literature. These results indicate that at least part of oil discharged from the accident sedimented to the seafloor in subsequent months, resulting in an apparent accumulation of hydrocarbons on the seabed by the end of 2010. Sediment resuspension and transport or biodegradation may account for the decrease in sedimented oil quantities in the years following the Macondo well spill. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Comparison of techniques for pre-concentrating radium from seawater

    International Nuclear Information System (INIS)

    Bourquin, M.; Van Beek, P.; Souhaut, M.; Jeandel, C.; Reyss, J.L.; Charette, M.A.

    2008-01-01

    In the framework of the KEOPS project (Kerguelen: compared study of the Ocean and the Plateau in Surface water), we aimed to provide information on the water mass pathways and vertical mixing on the Kerguelen Plateau, Southern Ocean, based on 228 Ra profiles. Because 228 Ra activities are extremely low in this area (∼ 0.1 dpm/100 kg or ∼ 2.10 -18 g kg -1 ), the filtration of large volumes of seawater was required in order to be able to detect it with minimal uncertainty. This challenging study was an opportunity for us to test and compare methods aimed at removing efficiently radium isotopes from seawater. We used Mn-fiber that retains radium and that allows the measurement of all four radium isotopes ( 226 Ra, 228 Ra, 223 Ra, 224 Ra). First, we used Niskin bottles or the ship's seawater intake to collect large volumes of seawater that were passed onto Mn-fiber in the laboratory. Second, we filled cartridges with Mn-fiber that we placed in tandem on in situ pumps. Finally, we fixed nylon nets filled with Mn-fiber on the frame of in situ pumps to allow the passive filtration of seawater during the pump deployment. Yields of radium fixation on the cartridges filled with Mn-fiber and placed on in situ pumps are ca. 30% when combining the two cartridges. Because large volumes of seawater can be filtered with these pumps, this yields to effective volumes of 177-280 kg (that is, higher than that recovered from fourteen 12-1 Niskin bottles). Finally, the effective volume of seawater that passed through Mn-fiber placed in nylon nets and deployed during 4 h ranged between 125 and 364 kg. Consequently, the two techniques that separate Ra isotopes in situ are good alternatives for pre-concentrating radium from seawater. They can save ship-time by avoiding repeated CTD casts to obtain the large volumes of seawater. This is especially true when in situ pumps are deployed to collect suspended particles. However, both methods only provide 228 Ra/ 226 Ra ratios. The

  13. Bioavailability assessment of toxic metals using the technique "acid-volatile sulfide (AVS)-simultaneously extracted metals (SEM)" in marine sediments collected in Todos os Santos Bay, Brazil.

    Science.gov (United States)

    Silva, Jucelino B; Nascimento, Rodrigo A; de Oliva, Sergio T; de Oliveira, Olívia M C; Ferreira, Sergio L C

    2015-10-01

    This paper reports the bioavailability of the metals (cadmium, copper, zinc, lead, and nickel) in sediment samples collected in seven stations from the São Paulo Estuary, Todos os Santos Bay, Brazil. The bioavailability was determined by employing the technique "acid-volatile sulfide (AVS) and simultaneously extracted metal (SEM)". The elements cadmium, copper, lead, and zinc were determined using differential pulse anodic stripping voltammetry (DPASV), while nickel was quantified utilizing electrothermal atomic absorption spectrometry (ET AAS). The accuracy of these methods was confirmed using a certified reference material of estuarine sediment (NIST 1646). The sulfide was quantified using potentiometry with selective electrode and the organic matter determination employing an indirect volumetric method using potassium dichromate and iron(II) sulfate solutions. The bioavailability of the metals was estimated by relationship between the concentration of AVS and the sum of the concentrations of the simultaneously extracted metals (ΣSEM), considering a significant toxicity when (ΣSEM)/(AVS) is higher than 1. The bioavailability values in the seven stations studied varied from 0.93 to 1.31 (June, 2014) and from 0.34 to 0.58 (September, 2014). These results demonstrated a critical condition of toxicity (bioavailability >1) in six of the seven sediment samples collected during the rainy season (June, 2014). In the other period (September, 2014), the bioavailability was always lower than 1 for all sediment samples collected in the seven stations. The individual values of the concentrations of the five metals were compared with the parameters PEL (probable effects level) and TEL (threshold effects level), which are commonly employed for characterization of ecological risk in environmental systems. This comparison revealed that all metals have concentrations lower than the PEL and only zinc and lead in some stations have contents higher than the TEL. The

  14. Cytotoxicity of TiO{sub 2} nanoparticles towards freshwater sediment microorganisms at low exposure concentrations

    Energy Technology Data Exchange (ETDEWEB)

    Kumari, Jyoti; Kumar, Deepak; Mathur, Ankita; Naseer, Arif; Kumar, Ravi Ranjan [Centre for Nanobiotechnology, VIT University, Vellore 632014 (India); Thanjavur Chandrasekaran, Prathna [Department of Materials Engineering, Indian Institute of Science, Bangalore (India); Chaudhuri, Gouri; Pulimi, Mrudula [Centre for Nanobiotechnology, VIT University, Vellore 632014 (India); Raichur, Ashok M. [Department of Materials Engineering, Indian Institute of Science, Bangalore (India); Department of Chemical Technology, University of Johannesburg (South Africa); Babu, S. [School of Bio Sciences and Technology, VIT University, Vellore (India); Chandrasekaran, Natarajan [Centre for Nanobiotechnology, VIT University, Vellore 632014 (India); Nagarajan, R. [Department of Chemical Engineering, IIT Madras, Chennai (India); Mukherjee, Amitava, E-mail: amit.mookerjea@gmail.com [Centre for Nanobiotechnology, VIT University, Vellore 632014 (India)

    2014-11-15

    There is a persistent need to assess the effects of TiO{sub 2} nanoparticles on the aquatic ecosystem owing to their increasing usage in consumer products and risk of environmental release. The current study is focused on TiO{sub 2} nanoparticle-induced acute toxicity at sub-ppm level (≤1 ppm) on the three different freshwater sediment bacterial isolates and their consortium under two different irradiation (visible light and dark) conditions. The consortium of the bacterial isolates was found to be less affected by the exposure to the nanoparticles compared to the individual cells. The oxidative stress contributed considerably towards the cytotoxicity under both light and dark conditions. A statistically significant increase in membrane permeability was noted under the dark conditions as compared to the light conditions. The optical and fluorescence microscopic images showed aggregation and chain formation of the bacterial cells, when exposed to the nanoparticles. The electron microscopic (SEM, TEM) observations suggested considerable damage of cells and bio-uptake of nanoparticles. The exopolysaccrides (EPS) production and biofilm formation were noted to increase in the presence of the nanoparticles, and expression of the key genes involved in biofilm formation was studied by RT-PCR. - Highlights: • Toxicity of NPs towards freshwater sediment bacteria at sub-ppm concentrations. • Decreased toxicity of the nanoparticles in the consortium of microorganisms. • Enhanced bacterial resistance through EPS and biofilm formation in the presence of NPs. • Considerable surface damage of cells and internalization of NPs. • Gene expression analyses related to biofilm formation in the presence of NPs.

  15. Cytotoxicity of TiO2 nanoparticles towards freshwater sediment microorganisms at low exposure concentrations

    International Nuclear Information System (INIS)

    Kumari, Jyoti; Kumar, Deepak; Mathur, Ankita; Naseer, Arif; Kumar, Ravi Ranjan; Thanjavur Chandrasekaran, Prathna; Chaudhuri, Gouri; Pulimi, Mrudula; Raichur, Ashok M.; Babu, S.; Chandrasekaran, Natarajan; Nagarajan, R.; Mukherjee, Amitava

    2014-01-01

    There is a persistent need to assess the effects of TiO 2 nanoparticles on the aquatic ecosystem owing to their increasing usage in consumer products and risk of environmental release. The current study is focused on TiO 2 nanoparticle-induced acute toxicity at sub-ppm level (≤1 ppm) on the three different freshwater sediment bacterial isolates and their consortium under two different irradiation (visible light and dark) conditions. The consortium of the bacterial isolates was found to be less affected by the exposure to the nanoparticles compared to the individual cells. The oxidative stress contributed considerably towards the cytotoxicity under both light and dark conditions. A statistically significant increase in membrane permeability was noted under the dark conditions as compared to the light conditions. The optical and fluorescence microscopic images showed aggregation and chain formation of the bacterial cells, when exposed to the nanoparticles. The electron microscopic (SEM, TEM) observations suggested considerable damage of cells and bio-uptake of nanoparticles. The exopolysaccrides (EPS) production and biofilm formation were noted to increase in the presence of the nanoparticles, and expression of the key genes involved in biofilm formation was studied by RT-PCR. - Highlights: • Toxicity of NPs towards freshwater sediment bacteria at sub-ppm concentrations. • Decreased toxicity of the nanoparticles in the consortium of microorganisms. • Enhanced bacterial resistance through EPS and biofilm formation in the presence of NPs. • Considerable surface damage of cells and internalization of NPs. • Gene expression analyses related to biofilm formation in the presence of NPs

  16. Mapping sediment deposite on tank FB-901 using neutron back scattering technique

    International Nuclear Information System (INIS)

    Wibisono; Sugiharto; Zulkifli Lubis; Phyu Phyu Aung Myint; Thin Moe Hlaing

    2016-01-01

    Tank FB-901 is storage tank for temporary material production with a diameter 11 m and a high 12 m. This tank has been use about 10 years so it is suspected there is sediment in it. Neutron back scattering technique has been used to detected the level of sediment inside so it can be seen the volume of liquid properly and avoid problem in the nozzle outlet. AmBe neutron source with activity one Curie shoot into the tank to enable back scattering intensity from material. Measurement using He-3 detector, radiation counter Ludlum model 2200 scaler ratemeter and mechanical motor controlled by computer. Investigation were taken at around the tank from the bottom to the top on each step 50 mm height 8000 mm. Scan determined the distance between 500 mm and measurement time 3 seconds to each sample point. Investigation found the sediment level average 1000 mm by 1500 mm highest and lowest level 100 mm. Fluctuating liquid level observed maximum of 7800 mm and average of 7000 mm. Cleaning tank advised to avoid blockage of the nozzle and material volume is measured accurately. (author)

  17. Distribution of 210Pb activity concentrations in marine surface sediments within East Coast Peninsula Malaysia Exclusive Economic Zone (EEZ)

    International Nuclear Information System (INIS)

    Ahmad Sanadi Abu Bakar; Zaharudin Ahmad

    2010-01-01

    A sampling expedition into the East Coast Peninsula Malaysia Exclusive Economic Zone (EEZ) was carried in June 2008. Marine surface sediment samples were taken and the activity concentrations of 210 Pb have been determined. Its distribution was plotted and the findings show that the activity concentrations decline from north to south. On the other hand, the activity concentrations are increasing from west to east right to the edge of the EEZ. The highest activity concentrations were found to be near offshore oil platforms. The 210 Pb activity concentrations were found to be in the range of 18.3 - 123.1 Bq/ kg. (author)

  18. Application of tracer techniques in studies of sediment transport in Vietnam

    International Nuclear Information System (INIS)

    Hai, P.S.; Quang, N.H.; Xuan, N.M.; Chuong, P.N.; Hien, P.Z.

    1997-01-01

    As a consequence of intensive erosion processes typical of the humid tropical one, as well as of human activities destroying tropical forests, grasslands and protective mangrove swamps, etc, most navigable estuaries in Vietnam suffer seriously from sedimentation. In order to maintain the necessary depth for the 7.000 ton vessels entering and leaving ports, a large amount of money is spent annually on dredging operation. A lot of hydraulic and sedimentary surveys were carried out in the past by different groups of researchers. However, owing to the complexity of sediment processes in estuarine areas under the hydrometeorological conditions typical of the southwest Pacific, the use of just any modelling approach is not suitable. In many cases, the conclusions inferred from mathematical models have been the controversial matter. The tracer techniques, which have been employed in the country since 1991, have provided a very efficient tool to obtain a dynamic idea of sediment transport. Many investigations of bedload transport using Sc-46 labelled glass and Ir-192 glass as radioactive tracers were carried out from 1992 to 1996 at Haiphong harbour area. Bedload transport rates under effect of northeast monsoon and southeast monsoon at 5 zones located on both sides of the navigation channel were estimated. In bedload transport studies, apart from conventional methods for assessment of transport thickness, a new method using the ratio of photoelectric peak to Compton region of spectra acquired directly on the sea bed was put forward and applied. The influence of dredging materials at two dumping sites under different tidal phases on in fill rate in the access channel was assessed by radioactive tracers. The qualitative and quantitative information on sediment transport at some experimental sites given by tracers was used by modelling specialists who have undertaken hydraulic and sedimentary surveys in this region

  19. Concentration of heavy metals in brook trout in comparison to aquatic plants and sediments

    Energy Technology Data Exchange (ETDEWEB)

    Abo-Rady, M.D.

    1983-01-01

    From 1974 to 1977 the heavy metal content of river water, fishes (Salmo trutta fario), three aquatic plants (Cladophora glomerata, Potamogeton pectinatus, Zannichellia palustris), one river-bank plant (Phalaris arundinacea), and sediments (clay fraction) taken from the River Leine, up and downstream of Goettingen, were determined. Galvanic-bath sewage containing heavy metals caused an increase (11-60%) in the concentration of nine elements in the water. The average level of heavy metals in the river water corresponded to that of the Ems, Elbe and Weser, but was lower than that of the Neckar, Rhine and Danube. It was also below the European Community Guidelines (1975) on the quality of water used for the artificial recharging of ground water. River water upstream of the city has been used for this recharging for many years. There is a good correlation between the metal content in the investigated samples and in the water. In the muscles, only Cd, Co and Mn, in the liver Cd, Co, Cr. Hg, Mn and Zn, and in the total fish Cd, Co, Cr, Cu and Zn had increased significantly. In contrast to all other elements, Cr shows the highest concentration in the muscles. A previous accumulation of Cr in the liver is not a prerequisite for the accumulation in the muscles. Mercury shows the highest accumulation in the muscles, apparently because of the high retention rate of this element. Muscles also are a good monitor for this element. The impact of heavy metals on the Leine water was reflected in aquatic plants, which showed an increase in concentration up to 95-fold (according to metal or plant) - but not in river-bank plants. C. glomerata has the remarkable capability of accumulating all ten elements. Since P. arundinacea cannot reflect the different load of heavy metals it is therefore less suitable as a biological monitor for these metals.

  20. Identification of metals in bordering soils and sediments of Lake Ipe (Mato Grosso do Sul State), Brazil, by EDXRF technique

    International Nuclear Information System (INIS)

    Barreto, Sonia Regina G.; Barreto, Wagner J.; Nozaki, Jorge; Nascimento Filho, Virgilio F. do; Aragao, Pedro Henrique A.

    2002-01-01

    Lake Ipe, located in a floodplain area of Parana River, is an ecosystem that apparently does not show signs of pollution. The samplings of sediments in this lake, with a surface area of approximately 10,700 m 2 , were taken at the central point. The soil samples were gathered in a terrestrial area close to the lake not exposed to inundation by overflowing. The qualitative determinations of the main metals, Mg to Pb in soils and sediments were performed by EDXRF. The comparative study among peaks areas analysis of metals by EDXRF in soils and sediments indicated that the concentration of Fe, Zn, and Ga in sediments were respectively 3.29, 4.32, and 7.04 times higher than the soils. On the other hand, the concentrations of Rb and Pb were 100 and 1,552 times higher in sediments. The peak areas of K, Co, Ni, and Cu in sediments were practically twice in the soil samples. The peak areas of Ca, Ti, Cr, and Mn were equivalents in both compartments. The absence of Pb in soils, and the high concentrations observed in sediments, indicated that Pb came from allochthonous sources carried by water of Parana River and not by lixiviation of adjacent soils. (author)

  1. Dredging effects on selected nutrient concentrations and ecoenzymatic activity in two drainage ditch sediments in the lower Mississippi River Valley

    Directory of Open Access Journals (Sweden)

    Matt Moore

    2017-09-01

    Full Text Available Agricultural drainage ditches are conduits between production acreage and receiving aquatic systems. Often overlooked for their mitigation capabilities, agricultural drainage ditches provide an important role for nutrient transformation via microbial metabolism. Variations in ecoenzyme activities have been used to elucidate microbial metabolism and resource demand of microbial communities to better understand the relationship between altered nutrient ratios and microbial activity in aquatic ecosystems. Two agricultural drainage ditches, one in the northeast portion of the Arkansas Delta and the other in the lower Mississippi Delta, were monitored for a year. Sediment samples were collected prior to each ditch being dredged (cleaned, and subsequent post-dredging samples occurred as soon as access was available. Seasonal samples were then collected throughout a year to examine effects of dredging on selected nutrient concentrations and ecoenzymatic activity recovery in drainage ditch sediments. Phosphorus concentrations in sediments after dredging decreased 33–66%, depending on ditch and phosphorus extraction methodology. Additionally, ecoenzymatic activity was significantly decreased in most sediment samples after dredging. Fluorescein diacetate hydrolysis activity, an estimate of total microbial activity, decreased 56–67% after dredging in one of the two ditches. Many sample sites also had significant phosphorus and ecoenzymatic activity differences between the post-dredge samples and the year-long follow-up samples. Results indicate microbial metabolism in dredged drainage ditches may take up to a year or more to recover to pre-dredged levels. Likewise, while sediment nutrient concentrations may be decreased through dredging and removal, runoff and erosion events over time tend to quickly replenish nutrient concentrations in replaced sediments. Understanding nutrient dynamics and microbial metabolism within agricultural drainage ditches is

  2. Uranium hydrogeochemical and stream sediment reconnaissance of the Gillette NTMS quadrangle, Wyoming, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Warren, R.G.; George, W.E.; Minor, M.M.; Simi, O.R.; Talcott, C.L.; Hensley, W.K.; Cheadle, J.M. III.

    1980-08-01

    During 1976 and 1977, 752 water and 843 sediment samples were collected from 1419 locations within the 17 700-km 2 area of the Gillette quadrangle, Wyoming. Water samples were collected primarily from wells, and also from springs, ponds, and streams; sediment samples were collected primarily from stream channels, and also from springs and ponds. Each water sample was analyzed for uranium and each sediment sample was analyzed for 43 elements, including uranium and thorium. Uranium concentrations in water samples range from below the detection limit of 0.02 to 212.20 ppB and have a median of 1.10 ppB. The highest background uranium concentrations, as well as the highest individual uranium values, are in areas where favorable host units for uranium mineralization crop out. These units are the Wasatch and Fort Union formations in the Powder River Basin and the Inyan Kara group in the Black Hills. Uranium concentrations in sediment samples range from 0.64 to 29.83 ppM and have a median of 3.24 ppM. Background uranium concentrations are strongly controlled by the exposed geologic unit, and range from 4 to 8 ppM for the Cretaceous Colorado group to 1 to 3 ppM for the Triassic and Paleozoic units exposed in the Black Hills. Several areas where the Wasatch and Fort Union formations are exposed exhibit uranium concentrations in sediment samples that are slightly, but distinctly, above background values for these units. All of these areas are also associated with notably high uranium concentrations in water samples. Because epigenetic uranium mineralization in economically important areas can exhibit a similar geochemical signature, these areas within the Gillette quadrangle should be further examined for the possible presence of uranium mineralization

  3. Suppression of local haze variations in MERIS images over turbid coastal waters for retrieval of suspended sediment concentration

    NARCIS (Netherlands)

    Shen, F.; Verhoef, W.

    2010-01-01

    Atmospheric correction over turbid waters can be problematic if atmospheric haze is spatially variable. In this case the retrieval of water quality is hampered by the fact that haze variations could be partly mistaken for variations in suspended sediment concentration (SSC). In this study we propose

  4. Uranium hydrogeochemical and stream sediment reconnaissance of the Bozeman NTMS quadrangle, Montana, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Bolivar, S.L.; Hensley, W.K.; Van Haaften, I.J.; Pirtle, J.; George, W.E.; Gallimore, D.; Apel, C.; Hansel, J.

    1980-07-01

    This report contains uranium analyses for 1251 water samples and multielement analyses for 1536 sediment samples. Sediments were analyzed for uranium and thorium as well as aluminum, antimony, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chlorine, chromium, cobalt, copper, dysprosium, europium, gold, hafnium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, nickel, niobium, potassium, rubidium, samarium, scandium, silver, sodium, strontium, tantalum, terbium, tin, titanium, tungsten, vanadium, ytterbium, and zinc. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than 40 ppB uranium were reanalyzed by delayed-neutron counting (DNC). All sediments were analyzed for uranium by DNC. Other elemental concentrations in sediments were determined by neutron activation analysis for 31 elements, by x-ray fluorescence for 9 elements, and by arc-source emission spectrography for 2 elements. Analytical results for sediments are reported as parts per million. Descriptions of procedures used for analysis of water and sediment samples as well as analytical precisions and detection limits are given

  5. The concentration of "1"3"7Cs and organic carbon on sediment at Rat island in Indian ocean

    International Nuclear Information System (INIS)

    Muslim; Reza Agung Arjana; Wahyu Retno Prihatiningsih

    2016-01-01

    Rat Island is one of the islands in Indonesia, located in the Indian Ocean, about 10 kilometers west of Bengkulu, which has a beautiful scenery both on its land and on the seabed, making it a favorite tourist in Bengkulu. The purpose of this study was to determine the condition of "1"3"7Cs in sediments and its relation to the total carbon and sediment texture. Sediment sampling carried out on 17 September 2014 at six stations where three stations are still relatively close to The Rat island with water depth of ≤ 1 m and 3 others are far from Rat Island waters with a depth of 14-18 meters. Sediment texture and TOC content at waters depth of ≤ 1 m is sand and its TOC contents were <5.5%. On other hand at water depth of 14-18 meters sediment texture are silt sand mixture and the TOC content were ≥6%. The concentration of "1"3"7Cs in sediment were influenced by texture characteristic and TOC content. (author)

  6. Uranium hydrogeochemical and stream sediment reconnasissance of the Trinidad NTMS Quadrangle, Colorado, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Shannon, S.S. Jr.

    1980-05-01

    Uranium and other elemental data resulting from the Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) of the Trinidad National Topographic Map Series (NTMS) quadrangle, Colorado, by the Los Alamos Scientific Laboratory (LASL) are reported herein. This study was conducted as part of the United States Department of Energy's National Uranium Resource Evaluation (NURE), which is designed to provide improved estimates of the availability and economics of nuclear fuel resources and to make available to industry information for use in exploration and development of uranium resources. The HSSR data will ultimately be integrated with other NURE data (e.g., airborne radiometric surveys and geological investigations) to complete the entire NURE program. This report is a supplement to the HSSR uranium evaluation report for the Trinidad quadrange (Morris et al, 1978), which presented the field and uranium data for the 1060 water and 1240 sediment samples collected from 1768 locations in the quadrangle. The earlier report contains an evaluation of the uranium concentrations of the samples as well as descriptions of the geology, hydrology, climate, and uranium occurrences of the quadrange. This supplement presents the sediment field and uranium data again and the analyses of 42 other elements in the sediments. All uranium samples were redetermined by delayed-neutron counting (DNC) when the sediment samples were analyzed for 31 elements by neutron activation. For 99.6% of the sediment samples analyzed, the differences between the uranium contents first determined (Morris et al, 1978) and the analyses reported herein are less than 10%

  7. Concentration, composition and sources of PAHs in the coastal sediments of the exclusive economic zone (EEZ) of Qatar, Arabian Gulf.

    Science.gov (United States)

    Soliman, Y S; Al Ansari, E M S; Wade, T L

    2014-08-30

    Surface sediments were collected from sixteen locations in order to assess levels and sources of polycyclic aromatic hydrocarbons (PAHs) in sediments of Qatar exclusive economic zone (EEZ). Samples were analyzed for 16 parent PAHs, 18 alkyl homologs and for dibenzothiophenes. Total PAHs concentration (∑PAHs) ranged from 2.6 ng g(-1) to 1025 ng g(-1). The highest PAHs concentrations were in sediments in and adjacent to harbors. Alkylated PAHs predominated most of the sampling locations reaching up to 80% in offshore locations. Parent PAHs and parent high molecular weight PAHs dominated location adjacent to industrial activities and urban areas. The origin of PAHs sources to the sediments was elucidated using ternary plot, indices, and molecular ratios of specific compounds such as (Ant/Phe+Ant), (Flt/Flt+Pyr). PAHs inputs to most coastal sites consisted of mixture of petroleum and combustion derived sources. However, inputs to the offshore sediments were mainly of petroleum origin. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. Delineation of heavy metal contamination pathways (seawater, food and sediment) in tropical oysters from New Caledonia using radiotracer techniques

    International Nuclear Information System (INIS)

    Hedouin, Laetitia; Metian, Marc; Teyssie, Jean-Louis; Fichez, Renaud; Warnau, Michel

    2010-01-01

    Bioaccumulation of Ag, Cd, Co, Cr and Zn was studied in the oysters Isognomon isognomon and Malleus regula, using highly sensitive radiotracer techniques. Metals were readily bioconcentrated from the dissolved phase. Sediment exposures indicated a low bioavailability of sediment-bound metals (3-5 orders of magnitude lower than dissolved metals). In both seawater and sediment experiments, the two oysters displayed similar bioaccumulation behaviour towards all metals but Ag. Indeed, Ag was much more efficiently incorporated and retained in I. isognomon. Metals ingested with food (phytoplankton) were efficiently assimilated (34-77%) and strongly retained in oyster tissues (T b1/2 ≥ 20 d). Estimation of the relative contribution of each exposure pathway indicated that for both species sediment was the dominant pathway for Co and Cd, whereas food was the major source of Zn. Regarding Ag, seawater was the main source for I. isognomon (86%), whereas sediment was the predominant route for M. regula (92%).

  9. Activity concentration of some anthropogenic radionuclides in the surface marine sediments near the Saudi coast of the Arabian (Persian) Gulf

    International Nuclear Information System (INIS)

    Al-Kheliewi, A.S.; Shabana, E.I.

    2007-01-01

    Activity concentrations of some anthropogenic radionuclides ( 90 Sr, 137 Cs, 238 Pu, 239+240 Pu and 241 Am) have been measured in the surface of marine sediments along the Saudi coast of the Arabian (Persian) Gulf. The samples were collected at different locations and water depths. The spatial distribution of the concentrations of the measured radionuclides showed a heterogeneous pattern and is independent of location or water depth. The obtained results are discussed and some conclusions are drawn. (author)

  10. Benthic iron and phosphorus release from river dominated shelf sediments under varying bottom water O2 concentrations.

    Science.gov (United States)

    Ghaisas, N. A.; Maiti, K.; White, J. R.

    2017-12-01

    Phosphorus (P) cycling in coastal ocean is predominantly controlled by river discharge and biogeochemistry of the sediments. In coastal Louisiana, sediment biogeochemistry is strongly influenced by seasonally fluctuating bottom water O2, which, in turn transitions the shelf sediments from being a sink to source of P. Sediment P-fluxes were 9.73 ± 0.76 mg / m2 /d and 0.67±0.16 mg/m2/d under anaerobic and aerobic conditions respectively, indicating a 14 times higher P-efflux from oxygen deprived sediments. A high sedimentary oxygen consumption rate of 889 ± 33.6 mg/m2/d was due to organic matter re-mineralization and resulted in progressively decreasing the water column dissolved O2 , coincident with a P-flux of 7.2 ± 5.5 mg/m2/d from the sediment. Corresponding water column flux of Fe total was 19.7 ± 7.80 mg/m2/d and the sediment-TP decreased from 545 mg/Kg to 513 mg/Kg. A simultaneous increase in pore water Fe and P concentrations in tandem with a 34.6% loss in sedimentary Fe-bound P underscores the importance of O2 on coupled Fe- P biogeochemistry. This study suggests that from a 14,025 sq. km hypoxia area, Louisiana shelf sediments can supply 1.33x105 kg P/day into the water column compared to 0.094 x 105 kg P/day during the fully aerobic water column conditions.

  11. Uranium hydrogeochemical and stream sediment reconnaissance of the Arminto NTMS quadrangle, Wyoming, including concentrations of forty-three additional elements

    International Nuclear Information System (INIS)

    Morgan, T.L.

    1979-11-01

    During the summers of 1976 and 1977, 570 water and 1249 sediment samples were collected from 1517 locations within the 18,000-km 2 area of the Arminto NTMS quadrangle of central Wyoming. Water samples were collected from wells, springs, streams, and artifical ponds; sediment samples were collected from wet and dry streams, springs, and wet and dry ponds. All water samples were analyzed for 13 elements, including uranium, and each sediment sample was analyzed for 43 elements, including uranium and thorium. Uranium concentrations in water samples range from below the detection limit to 84.60 parts per billion (ppb) with a mean of 4.32 ppb. All water sample types except pond water samples were considered as a single population in interpreting the data. Pond water samples were excluded due to possible concentration of uranium by evaporation. Most of the water samples containing greater than 20 ppb uranium grouped into six clusters that indicate possible areas of interest for further investigation. One cluster is associated with the Pumpkin Buttes District, and two others are near the Kaycee and Mayoworth areas of uranium mineralization. The largest cluster is located on the west side of the Powder River Basin. One cluster is located in the central Big Horn Basin and another is in the Wind River Basin; both are in areas underlain by favorable host units. Uranium concentrations in sediment samples range from 0.08 parts per million (ppm) to 115.50 ppm with a mean of 3.50 ppm. Two clusters of sediment samples over 7 ppm were delineated. The first, containing the two highest-concentration samples, corresponds with the Copper Mountain District. Many of the high uranium concentrations in samples in this cluster may be due to contamination from mining or prospecting activity upstream from the sample sites. The second cluster encompasses a wide area in the Wind River Basin along the southern boundary of the quadrangle

  12. Uranium hydrogeochemical and stream sediment reconnaissance of the Arminto NTMS quadrangle, Wyoming, including concentrations of forty-three additional elements

    Energy Technology Data Exchange (ETDEWEB)

    Morgan, T.L.

    1979-11-01

    During the summers of 1976 and 1977, 570 water and 1249 sediment samples were collected from 1517 locations within the 18,000-km/sup 2/ area of the Arminto NTMS quadrangle of central Wyoming. Water samples were collected from wells, springs, streams, and artifical ponds; sediment samples were collected from wet and dry streams, springs, and wet and dry ponds. All water samples were analyzed for 13 elements, including uranium, and each sediment sample was analyzed for 43 elements, including uranium and thorium. Uranium concentrations in water samples range from below the detection limit to 84.60 parts per billion (ppb) with a mean of 4.32 ppb. All water sample types except pond water samples were considered as a single population in interpreting the data. Pond water samples were excluded due to possible concentration of uranium by evaporation. Most of the water samples containing greater than 20 ppb uranium grouped into six clusters that indicate possible areas of interest for further investigation. One cluster is associated with the Pumpkin Buttes District, and two others are near the Kaycee and Mayoworth areas of uranium mineralization. The largest cluster is located on the west side of the Powder River Basin. One cluster is located in the central Big Horn Basin and another is in the Wind River Basin; both are in areas underlain by favorable host units. Uranium concentrations in sediment samples range from 0.08 parts per million (ppm) to 115.50 ppm with a mean of 3.50 ppm. Two clusters of sediment samples over 7 ppm were delineated. The first, containing the two highest-concentration samples, corresponds with the Copper Mountain District. Many of the high uranium concentrations in samples in this cluster may be due to contamination from mining or prospecting activity upstream from the sample sites. The second cluster encompasses a wide area in the Wind River Basin along the southern boundary of the quadrangle.

  13. Senegalese artisanal gold mining leads to elevated total mercury and methylmercury concentrations in soils, sediments, and rivers

    Directory of Open Access Journals (Sweden)

    Jacqueline R. Gerson

    2018-01-01

    Full Text Available The largest source of global mercury (Hg anthropogenic inputs to the environment is derived from artisanal and small-scale gold mining (ASGM activities in developing countries. While our understanding of global Hg emissions from ASGM is growing, there is limited empirical documentation about the levels of total mercury (THg and methylmercury (MeHg contamination near ASGM sites. We measured THg and MeHg concentrations in soil (n = 119, sediment (n = 22, and water (n = 25 from four active ASGM villages and one non-ASGM reference village in Senegal, West Africa. Nearly all samples had THg and MeHg concentrations that exceeded the reference village concentrations and USEPA regulatory standards. The highest median THg concentrations were found in huts where mercury-gold amalgams were burned (7.5 μg/g, while the highest median MeHg concentrations and percent Hg as MeHg were found in river sediments (4.2 ng/g, 0.41%. Median river water concentrations of THg and MeHg were also elevated compared to values at the reference site (22 ng THg/L, 0.037 ng MeHg/L in ASGM sites. This study provides direct evidence that Hg from ASGM is entering both the terrestrial and aquatic ecosystems where it is converted in soils, sediment, and water to the neurotoxic and bioavailable form of MeHg.

  14. Sedimentation

    Digital Repository Service at National Institute of Oceanography (India)

    Rixen, T.; Guptha, M.V.S.; Ittekkot, V.

    opal ratios. Such changes are assumed to have lowered the atmospheric CO sub(2) concentration significantly during glacial times. The differences between estimated deep ocean fluxes derived from satellite data and measured deep fluxes are lower than...

  15. Impact of seasonal variation on Escherichia coli concentrations in the riverbed sediments in the Apies River, South Africa.

    Science.gov (United States)

    Abia, Akebe Luther King; Ubomba-Jaswa, Eunice; Momba, Maggy Ndombo Benteke

    2015-12-15

    Many South Africans living in resource-poor settings with little or no access to pipe-borne water still rely on rivers as alternative water sources for drinking and other purposes. The poor microbial quality of such water bodies calls for appropriate monitoring. However, routine monitoring only takes into consideration the microbial quality of the water column, and does not include monitoring of the riverbed sediments for microbial pollution. This study sought to investigate the microbial quality of riverbed sediments in the Apies River, Gauteng Province, South Africa, using Escherichia coli as a faecal indicator organism and to investigate the impact of seasonal variation on its abundance. Weekly samples were collected at 10 sampling sites on the Apies River between May and August 2013 (dry season) and between January and February 2014 (wet season). E. coli was enumerated using the Colilert®-18 Quanti-Tray® 2000 system. All sites tested positive for E. coli. Wastewater treatment work effluents had the highest negative impact on the river water quality. Seasonal variations had an impact on the concentration of E. coli both in water and sediments with concentrations increasing during the wet season. A strong positive correlation was observed between temperature and the E. coli concentrations. We therefore conclude that the sediments of the Apies River are heavily polluted with faecal indicator bacteria and could also harbour other microorganisms including pathogens. The release of such pathogens into the water column as a result of the resuspension of sediments due to extreme events like floods or human activities could increase the health risk of the populations using the untreated river water for recreation and other household purposes. There is therefore an urgent need to reconsider and review the current South African guidelines for water quality monitoring to include sediments, so as to protect human health and other aquatic lives. Copyright © 2015 Elsevier

  16. Assessment of the concentration of Cr, Mn and Fe in sediment using ...

    African Journals Online (AJOL)

    In the present study, laser-induced breakdown spectroscopy (LIBS) has been applied for the determination of levels of Cr, Mn and Fe in sediment samples and the results have been compared with that of flame-atomic absorption spectroscopy (F-AAS). Fourteen sediment samples were collected from Tinishu Akaki River ...

  17. Effect of high flow events on spatiotemporal variation of E. coli concentrations in creek sediments

    Science.gov (United States)

    Sediments can harbor large populations of Escherichia coli often times in greater amounts than the overlying water column. Resuspension of sediments during storm events causes the release of E. coli which drastically changes microbial water quality metrics. It is not well known how populations of E....

  18. A geological interpretation of heavy metal concentrations in soils and sediments in the southern Netherlands

    NARCIS (Netherlands)

    Huisman, D.J.; Vermeulen, F.J.H.; Baker, J.; Veldkamp, A.; Kroonenberg, S.B.; Klaver, G.Th.

    1997-01-01

    The natural variation in heavy metal contents of subsurface sediments in the southern Netherlands is described, based on a series of 820 bulk geochemical analyses. The detrital heavy metal contents of these sediments show linear correlations with Al as a result of their joint occurrence in

  19. Prediction of toxic metals concentration using artificial intelligence techniques

    Science.gov (United States)

    Gholami, R.; Kamkar-Rouhani, A.; Doulati Ardejani, F.; Maleki, Sh.

    2011-12-01

    Groundwater and soil pollution are noted to be the worst environmental problem related to the mining industry because of the pyrite oxidation, and hence acid mine drainage generation, release and transport of the toxic metals. The aim of this paper is to predict the concentration of Ni and Fe using a robust algorithm named support vector machine (SVM). Comparison of the obtained results of SVM with those of the back-propagation neural network (BPNN) indicates that the SVM can be regarded as a proper algorithm for the prediction of toxic metals concentration due to its relative high correlation coefficient and the associated running time. As a matter of fact, the SVM method has provided a better prediction of the toxic metals Fe and Ni and resulted the running time faster compared with that of the BPNN.

  20. Temporal variation of persistent organic pollutant (POP) residue concentrations in sediments from the bay of Chetumal, Mexico.

    Science.gov (United States)

    Noreña-Barroso, E; Gold-Bouchot, G; Ceja-Moreno, V

    2007-08-01

    Bay of Chetumal is a transboundary priority area for the Mesoamerican Barrier Reef Systems project, which has been studied because it is the receiving body of pollutants from a large agricultural area and the city of Chetumal. Levels of persistent organic pollutants in sediments from the Bay were assessed a few years after a mass mortality event of Mayan catfish (Ariopsis assimilis) occurred in 1996. Recent sediments were collected in the rainy season (1999) and dry season (2000); results show concentrations in general lower than those reported after the fish kill, and a change of chemical profiles in chemical pollution.

  1. Comparison of depth-averaged concentration and bed load flux sediment transport models of dam-break flow

    Directory of Open Access Journals (Sweden)

    Jia-heng Zhao

    2017-10-01

    Full Text Available This paper presents numerical simulations of dam-break flow over a movable bed. Two different mathematical models were compared: a fully coupled formulation of shallow water equations with erosion and deposition terms (a depth-averaged concentration flux model, and shallow water equations with a fully coupled Exner equation (a bed load flux model. Both models were discretized using the cell-centered finite volume method, and a second-order Godunov-type scheme was used to solve the equations. The numerical flux was calculated using a Harten, Lax, and van Leer approximate Riemann solver with the contact wave restored (HLLC. A novel slope source term treatment that considers the density change was introduced to the depth-averaged concentration flux model to obtain higher-order accuracy. A source term that accounts for the sediment flux was added to the bed load flux model to reflect the influence of sediment movement on the momentum of the water. In a one-dimensional test case, a sensitivity study on different model parameters was carried out. For the depth-averaged concentration flux model, Manning's coefficient and sediment porosity values showed an almost linear relationship with the bottom change, and for the bed load flux model, the sediment porosity was identified as the most sensitive parameter. The capabilities and limitations of both model concepts are demonstrated in a benchmark experimental test case dealing with dam-break flow over variable bed topography.

  2. Discriminating sediment and clear water over coastal water using GD technique

    Directory of Open Access Journals (Sweden)

    Amin Abd Rahman Mat

    2017-03-01

    Full Text Available Currently two algorithms are being used routinely by the MODIS Atmosphere and Ocean Team in order to distinguish sediment influence and clear water pixels over turbid water area. These two algorithms require complicated computational analyses. In this paper, a simple algorithm based on empirical technique to detect the sediment-influenced pixels over coastal waters is proposed as an alternative to these two algorithms. This study used apparent reflectance acquired from MODIS L1B product. This algorithm is based on the gradient difference of the line connecting the 0.47- and 1.24-μm channels and 0.47- and 0.66-μm channels of a log-log graph of the apparent reflectance values against MODIS wavelengths. Over clear-water areas (deep blue sea, the 0.47-, 0.66- and 1.24-μm channels fitted very well in line with correlation R > 0.99. Over turbid waters, a substantial increase of 0.66 μm in the reflectance leads to a low correlation value. By computing the difference between the gradient of the line connecting 0.47 and 0.66 μm and the gradient of the line connecting 0.47 and 1.24 μm, the threshold to discriminate turbid and shallow coastal waters from clear-water pixels can be obtained. If the gradient difference is greater than 0, the pixels were then marked as sediment-influenced pixels. This proposed algorithm works well for MODIS Terra and Aqua sensor. The comparison of this algorithm with an established algorithm also showed a good agreement.

  3. Concentrations of inorganic arsenic in groundwater, agricultural soils and subsurface sediments from the middle Gangetic plain of Bihar, India.

    Science.gov (United States)

    Kumar, Manoj; Ramanathan, A L; Rahman, Mohammad Mahmudur; Naidu, Ravi

    2016-12-15

    Concentrations of inorganic forms [arsenite, As(III) and arsenate, As(V) of arsenic (As) present in groundwater, agricultural soils and subsurface sediments located in the middle Gangetic plain of Bihar, India were determined. Approximately 73% of the groundwater samples (n=19) show As(III) as the dominant species while 27% reveals As(V) was the dominant species. The concentration of As(III) in agricultural soil samples varies from not detectable to 40μg/kg and As(V) was observed as the major species (ranging from 1050 to 6835μg/kg) while the total As concentration varied from 3528 to 14,690μg/kg. Total extracted concentration of As was higher in the subsurface sediments (range 9119-20,056μg/kg in Methrapur and 4788-19,681μg/kg in Harail Chapar) than the agricultural soil, indicating the subsurface sediment as a source of As. Results of X-ray diffraction (XRD) and environmental scanning electron microscope (ESEM) revealed the presence of hematite and goethite throughout the vertical section below while magnetite was observed only in the upper oxidized layer at Methrapur and Harail Chapar. Alteration of Fe-oxides and presence of fibrous goethite indicating presence of diagenetic sediment. Siderite plays a crucial role as sinks to the As in subsurface sediments. The study also concluded that decomposition of organic matter present in dark and grey sections promote the redox conditions and trigger mobilization of As into groundwater. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Influence of land use on metal concentrations in playa sediments and amphibians in the Southern High Plains

    Energy Technology Data Exchange (ETDEWEB)

    Venne, Louise S. [Department of Environmental Toxicology, Institute of Environmental and Human Health, Texas Tech University, MS 1163, Lubbock, TX 79409 (United States)]. E-mail: louise.venne@tiehh.ttu.edu; Cobb, George P. [Department of Environmental Toxicology, Institute of Environmental and Human Health, Texas Tech University, MS 1163, Lubbock, TX 79409 (United States); Coimbatore, Gopal [Department of Environmental Toxicology, Institute of Environmental and Human Health, Texas Tech University, MS 1163, Lubbock, TX 79409 (United States); Smith, Loren M. [Wildlife and Fisheries Management Institute, Texas Tech University, MS 2125, Lubbock, TX 79409 (United States); McMurry, Scott T. [Department of Environmental Toxicology, Institute of Environmental and Human Health, Texas Tech University, MS 1163, Lubbock, TX 79409 (United States)

    2006-11-15

    The Southern High Plains (SHP) is a semi-arid region in which playa wetlands are the focal points of biodiversity. Playas are highly influenced by surrounding land use. Most of the SHP is in agricultural production (primarily cotton) with a history of arsenic-containing herbicide use. Metals influence reproduction and development in amphibians. We analyzed metal residues in playa sediment and whole body tissue of Spea spp. and Bufo cognatus metamorphs from two land uses: cropland and native grassland. Cd and Ni concentrations in B. cognatus tissues differed between land uses. Metal concentrations in Spea spp. tissues did not differ between land uses. Ba was higher in Spea spp. than B. cognatus collected from the same grassland playas, indicating differential habitat use. No correlations between sediment and tissue concentrations were found. Land use appeared to have little influence on metal concentrations and levels were below those known to cause effects in amphibians. - Land use surrounding playas has little effect on metal concentrations in sediments.

  5. A comparative study of seasonal variation of 137CS concentration in mangroves and sediment around Mumbai Harbour Bay

    International Nuclear Information System (INIS)

    Dutta, Madhuparna; Raj, Sanu S.; Jha, S.K.; Tripathi, R.M.

    2016-01-01

    Mangroves are various large and extensive types of trees up to medium height and also shrubs, which belong to the genus Rhizophora, that grow in saline coastal sediment habitats in the tropics and subtropics mainly between latitudes 25 ° N and 25° S. Mangrove ecosystems play a key role in nutrient and metal cycling. Because of their variable physical and chemical properties. Mangroves can act as a sink or a source of heavy metals in coastal environments. The level of trace metal which accumulate in mangroves differ seasonally and spatially varying with saline environment that may affect uptake and distribution of metals in the plants. Hence the estimation of 137 Cs activity in samples of mangrove and the surrounding sediment collected round the year will give us pattern of seasonal uptake. The study was carried out in Mumbai Harbour Bay (MHB), to estimate the 137 Cs activity concentration in mangrove leaves and the surrounding sediment and to compare the two

  6. Chemical concentrations in water and suspended sediment, Green River to Lower Duwamish Waterway near Seattle, Washington, 2016–17

    Science.gov (United States)

    Conn, Kathleen E.; Black, Robert W.; Peterson, Norman T.; Senter, Craig A.; Chapman, Elena A.

    2018-01-05

    From August 2016 to March 2017, the U.S. Geological Survey (USGS) collected representative samples of filtered and unfiltered water and suspended sediment (including the colloidal fraction) at USGS streamgage 12113390 (Duwamish River at Golf Course, at Tukwila, Washington) during 13 periods of differing flow conditions. Samples were analyzed by Washington-State-accredited laboratories for a large suite of compounds, including metals, dioxins/furans, semivolatile compounds including polycyclic aromatic hydrocarbons, butyltins, the 209 polychlorinated biphenyl (PCB) congeners, and total and dissolved organic carbon. Concurrent with the chemistry sampling, water-quality field parameters were measured, and representative water samples were collected and analyzed for river suspended-sediment concentration and particle-size distribution. The results provide new data that can be used to estimate sediment and chemical loads transported by the Green River to the Lower Duwamish Waterway.

  7. Quantitative interpretation of Cl, Br and I porewater concentration profiles in lake sediments of Loch Lomond, Scotland

    International Nuclear Information System (INIS)

    Falck, W.E.; Hooker, P.J.

    1991-01-01

    One of the four natural analogue sites being investigated by the British Geological Survey is Loch Lomond, Scotland. Naturally occurring halogen elements (Cl, Br and I) have been migrating from a thin marine horizon into overlying freshwater deposits by a diffusion process which has been occurring for at least 5 400 years. This report summarizes the main findings accumulated since 1983 when the work was first begun, and provides a modelling interpretation of the measured concentration-depth profiles using a new numerical code called Diagen. The release rates of I and Br from the organic matter association in the shallow buried marine layer are very slow; subsequent anion movement by diffusion is affected by tortuosity differences in the sediments rather than by chemical reaction with the sediments. The bulk of the evidence supports conservative transport of iodide, bromide and chloride anions towards the sediment/loch interface. The report discusses some implications of the findings

  8. Technique for Outdoor Test on Concentrating Photovoltaic Cells

    Directory of Open Access Journals (Sweden)

    Paola Sansoni

    2015-01-01

    Full Text Available Outdoor experimentation of solar cells is essential to maximize their performance and to assess utilization requirements and limits. More generally tests with direct exposure to the sun are useful to understand the behavior of components and new materials for solar applications in real working conditions. Insolation and ambient factors are uncontrollable but can be monitored to know the environmental situation of the solar exposure experiment. A parallel characterization of the photocells can be performed in laboratory under controllable and reproducible conditions. A methodology to execute solar exposure tests is proposed and practically applied on photovoltaic cells for a solar cogeneration system. The cells are measured with concentrated solar light obtained utilizing a large Fresnel lens mounted on a sun tracker. Outdoor measurements monitor the effects of the exposure of two multijunction photovoltaic cells to focused sunlight. The main result is the continuous acquisition of the V-I (voltage-current curve for the cells in different conditions of solar concentration and temperature of exercise to assess their behavior. The research investigates electrical power extracted, efficiency, temperatures reached, and possible damages of the photovoltaic cell.

  9. Distribution of the dominant microbial communities in marine sediments containing high concentrations of gas hydrates

    Energy Technology Data Exchange (ETDEWEB)

    Briggs, B.; Colwell, F.; Carini, P.; Torres, M. [Oregon State Univ., Corvallis, OR (United States); Hangsterfer, A.; Kastner, M. [California Univ., San Diego, CA (United States). Scripps Inst. of Oceanography; Brodie, E. [Lawrence Berkeley National Laboratory, Berkeley, CA (United States). Center for Environmental Biotechnology; Daly, R. [California Univ., Berkeley, CA (United States); Holland, M. [GeoTek, Daventry, Northants (United Kingdom); Long, P.; Schaef, H. [Pacific Northwest National Laboratory, Richland, WA (United States). Environmental Technology; Delwiche, M. [Idaho National Laboratory, Idaho Falls, ID (United States). Biotechnology; Winters, W. [United States Geological Survey, Woods Hole, MA (United States). Woods Hole Science Center; Riedel, M. [McGill Univ., Montreal, PQ (Canada). Dept. of Earth and Planetary Sciences

    2008-07-01

    Methane produced by microorganisms represents a large portion of the methane that occurs in marine sediments where gas hydrates are present. The diverse communities that populate these formations have been documented by cultures or through molecular traces. Previous studies have explored the biogeography of hydrate-bearing systems by comparing clone libraries developed from sediments where hydrates are abundant with those developed from sediments that lack hydrates. There is a distinct microbial community present in sediments that have methane hydrates. This paper presented an investigation into finer-scale biogeography, in order to determine how factors such as the presence or absence of hydrates, grain size, and the depositional environment in marine sediments may control the number, type and distribution of microbial communities in sediments. The purpose of the study was to understand the controls on the distribution and activity of all microbes that contribute to the conversion of organic matter to methane. To this aim, DNA was extracted from deep marine sediments cored from continental slope locations including offshore India and the Cascadia Margin. The data from the study was used to refine computational models that require biological rate terms that are consistent with sediment conditions in order to accurately describe the dynamics of this large methane reservoir. The paper discussed the materials and methods used for the study, including the sample site, sample collection and microbiological analysis. Results were presented in terms of DNA extractions; microbial diversity; and biofilm analyses. It was concluded that the findings from the study complemented previously reported studies which indicated the presence of diverse microbial communities in sediments containing methane hydrates. 9 refs., 5 figs.

  10. How do changes in suspended sediment concentration alone influence the size of mud flocs under steady turbulent shearing?

    Science.gov (United States)

    Tran, Duc; Kuprenas, Rachel; Strom, Kyle

    2018-04-01

    Modeling the size and settling velocity of sediment under the influence of flocculation is crucial for the accurate prediction of mud movement and deposition in sediment transport modeling of environments such as agricultural streams, large coastal rivers, estuaries, river plumes, and turbidity currents. Yet, collecting accurate and high resolution data on mud flocs is difficult. As a result, models that account for the influence of flocculation on mud settling velocity are based on sparse data that often present non-congruent relationship in floc properties with basic influencers of flocculations such as suspended sediment concentration. This study examines the influence of suspended sediment concentration on floc size populations within a turbulent suspension. Specifically, the work investigates: (1) the relationship between the equilibrium floc size and suspended sediment concentration under conditions of steady concentration and turbulent shearing; and (2) the speed at which mature flocs adapt to an unsteady drop in the concentration when turbulent shear is constant. Two sets of experiments were used to investigate the target processes. All work was conducted in laboratory mixing tanks using a floc camera and a newly developed image acquisition method. The new method allows for direct imaging and sizing of flocs within turbulent suspensions of clay in concentrations ranging from 15 to 400 mg/L, so that no transfer of the sample to another settling column or imaging tank is needed. The primary conclusions from the two sets of experiments are: (1) that the equilibrium floc size in an energetic turbulent suspension is linearly and positively related to concentration over the range of C = 50 to 400 mg/L, yet with a smaller-than-expected slope based on previous data and models from low-energy environments; and (2) that floc sizes decrease quickly (with a time lag on the order of 1-15 min) to time-varying decreases in concentration at turbulent shearing of G = 50s-1

  11. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Lewistown NTMS Quadrangle, Montana, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Shannon, S.S. Jr.

    1980-08-01

    Totals of 758 water and 1170 sediment samples were collected from 1649 locations in the Levistown quadrangle. Water samples were collected at streams, springs, wells, ponds, and marshes; sediment samples were obtained from streams, springs, and ponds. Histograms and statistical data for uranium concentrations in water and sediment samples and thorium concentrations in sediment samples are given. All samples were collected at the nominal reconnaissance density of one sample location per 10 km 2 . Elemental concentration, field measurement, weather, geologic, and geographic data for each sample location are listed for waters and for sediments. Uranium to thorium (U/Th) ratios for sediment samples are included. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than 40 ppB U were reanalyzed by delayed-neutron counting. Sediments were analyzed for U and Th as well as Al, Sb, Ba, Be, Bi, Cd, Ca, Ce, Cs, Cl, Cr, Co, Cu, Dy, Eu, Au, Hf, Fe, La, Pb, Li, Lu, Mg, Mn, Ni, Nb, K, Rb, Sa, Sc, Ag, Na, Sr, Ta, Tb, Sn, Ti, W, V, Yb, and Zn. All sediments were analyzed for U by delayed neutron counting. Other elemental concentrations in sediments were determined by neutron activation analysis for 31 elements, by x-ray fluorescence for 9 elements, and by arc-source emission spectrography for 2 elements. Analytical results are reported as parts per million. Descriptions of procedures used for analysis of water and sediments samples as well as analytical precisions and detection limits are given

  12. Uranium and coexisting element behaviour in surface waters and associated sediments with varied sampling techniques used for uranium exploration

    International Nuclear Information System (INIS)

    Wenrich-Verbeek, K.J.

    1977-01-01

    Optimum sampling methods in surface water and associated sediments for use in uranium exploration are being studied at thirty sites in Colorado, New Mexico, Arizona and Utah. For water samples, filtering is recommended to increase sample homogeneity and reproducibility because for most elements studied water samples which were allowed to remain unfiltered until time of analysis contained higher concentrations than field-filtered samples of the same waters. Acidification of unfiltered samples resulted in still higher concentrations. This is predominantly because of leaching of the elements from the suspended fraction. U in water correslates directly with Ca, Mg, Na, K, Ba, B, Li and As. In stream sediments, U and other trace elements are concentrated in the finer size fractions. Accordingly, in prospecting, grain size fractions less than 90 μm (170 mesh) should be analyzed for U. A greater number of elements (21) show a significant positive correlation with U in stream sediments than in water. Results have revealed that anomalous concentrations of U found in water may not be detected in associated sediments and vice versa. Hence, sampling of both surface water and coexisting sediment is strongly recommended

  13. The use of dispersive X-ray fluorescence technique for pollution evaluation of heavy metals in water samples and lake sediments

    International Nuclear Information System (INIS)

    Vives, Ana Elisa Sirito de; Brienza, Sandra Maria Boscolo

    2002-01-01

    The energy dispersive X-ray fluorescence technique (EDXRF) was used to determine metals concentration in water and bottom sediments samples in lakes at Santa Gertrudes region, Sao Paulo state, Brazil. The studied area is about 12 ha, with several lakes formed by argil extraction and present high volume of waste which can be dangerous and cause risks to water flora and fauna and also to human health by direct or indirect contact with the residues. To evaluate contamination degree by heavy metals water samples were collected in three lakes, in 2000 July and November, corresponding to the dry and rainy season. In two lakes the sampling procedure were superficial, and in the third lake, sampling was done at central region and in different deepness. Sediment samples were collected at two lakes, in 2000, July (dry) and November (rainy). To determine biologically available metals concentration (no-residual fraction) in the sediment, an acid extraction procedure was used. To quantitative analysis of both samples, metals were pre concentrated by complexation with ammonium pyrrolidine dithiocarbamate. Samples were excited with a X-ray tube with Mo target and Zr filter, operated at 25 kV/10 mA, and X-ray characteristics measure were done with a Si(Li) semi conductor detector. In water samples, were determined the elements Fe, Cu, Zn and Pb. Among the analyzed elements, Fe presented the highest concentration, independent of the sampling local. Was verified that all the analyzed elements presented concentrations below the maximum limit allowed to waters class 2, which may be distributed to domestic provisioning, to primary contact recreation, to vegetables and fruitier plants irrigation and to the natural and/or intensive breeding (agriculture) of species destined to the alimentation. In the sediment samples were determined Fe, Co, Ni, Cu, Zn and Pb, and was observed high contents to the elements Fe, Zn and Pb and relatively low concentrations of Co, Ni and Cu. It was verified

  14. Petroleum hydrocarbon concentration in sediments along northern west coast of India

    Digital Repository Service at National Institute of Oceanography (India)

    Ram, A.; Kadam, A.N.

    Gas chromatography revealed that nonpolar material extracted from surface sediments collected along the northern west coast of India was originated from petroleum hydrocarbon residue. Petroleum hydrocarbon levels as determinEd. by fluorescence...

  15. PAH concentrations in lake sediment decline following ban on coal-tar-based pavement sealants in Austin, Texas

    Science.gov (United States)

    Van Metre, Peter C.; Mahler, Barbara J.

    2013-01-01

    Recent studies have concluded that coal-tar-based pavement sealants are a major source of polycyclic aromatic hydrocarbons (PAHs) in urban settings in large parts of the United States. In 2006, Austin, TX, became the first jurisdiction in the U.S. to ban the use of coal-tar sealants. We evaluated the effect of Austin’s ban by analyzing PAHs in sediment cores and bottom-sediment samples collected in 1998, 2000, 2001, 2012, and 2014 from Lady Bird Lake, the principal receiving water body for Austin urban runoff. The sum concentration of the 16 EPA Priority Pollutant PAHs (∑PAH16) in dated core intervals and surficial bottom-sediment samples collected from sites in the lower lake declined about 44% from 1998–2005 to 2006–2014 (means of 7980 and 4500 μg kg–1, respectively), and by 2012–2014, the decline was about 58% (mean of 3320 μg kg–1). Concentrations of ∑PAH16 in bottom sediment from two of three mid-lake sites decreased by about 71 and 35% from 2001 to 2014. Concentrations at a third site increased by about 14% from 2001 to 2014. The decreases since 2006 reverse a 40-year (1959–1998) upward trend. Despite declines in PAH concentrations, PAH profiles and source-receptor modeling results indicate that coal-tar sealants remain the largest PAH source to the lake, implying that PAH concentrations likely will continue to decline as stocks of previously applied sealant gradually become depleted.

  16. Total mercury concentrations in surface water and sediments from Danube Delta lakes

    Directory of Open Access Journals (Sweden)

    TEODOROF Liliana

    2007-10-01

    Full Text Available The samples were collected from surface water and sediments of Danube Delta lakes, during april and may 2006. The sediments were digested with nitric acid, and the surface water with real aqua, at Microwave Oven Anton Paar and analised at FIMS 400 Perkin Elmer. The results show that the total mercury is compared with the maximum allowed limits according with Normative 161/2006.

  17. Alaska Geochemical Database (AGDB)-Geochemical data for rock, sediment, soil, mineral, and concentrate sample media

    Science.gov (United States)

    Granitto, Matthew; Bailey, Elizabeth A.; Schmidt, Jeanine M.; Shew, Nora B.; Gamble, Bruce M.; Labay, Keith A.

    2011-01-01

    The Alaska Geochemical Database (AGDB) was created and designed to compile and integrate geochemical data from Alaska in order to facilitate geologic mapping, petrologic studies, mineral resource assessments, definition of geochemical baseline values and statistics, environmental impact assessments, and studies in medical geology. This Microsoft Access database serves as a data archive in support of present and future Alaskan geologic and geochemical projects, and contains data tables describing historical and new quantitative and qualitative geochemical analyses. The analytical results were determined by 85 laboratory and field analytical methods on 264,095 rock, sediment, soil, mineral and heavy-mineral concentrate samples. Most samples were collected by U.S. Geological Survey (USGS) personnel and analyzed in USGS laboratories or, under contracts, in commercial analytical laboratories. These data represent analyses of samples collected as part of various USGS programs and projects from 1962 to 2009. In addition, mineralogical data from 18,138 nonmagnetic heavy mineral concentrate samples are included in this database. The AGDB includes historical geochemical data originally archived in the USGS Rock Analysis Storage System (RASS) database, used from the mid-1960s through the late 1980s and the USGS PLUTO database used from the mid-1970s through the mid-1990s. All of these data are currently maintained in the Oracle-based National Geochemical Database (NGDB). Retrievals from the NGDB were used to generate most of the AGDB data set. These data were checked for accuracy regarding sample location, sample media type, and analytical methods used. This arduous process of reviewing, verifying and, where necessary, editing all USGS geochemical data resulted in a significantly improved Alaska geochemical dataset. USGS data that were not previously in the NGDB because the data predate the earliest USGS geochemical databases, or were once excluded for programmatic reasons

  18. Abundance and δ13C values of fatty acids in lacustrine surface sediments: Relationships with in-lake methane concentrations

    Science.gov (United States)

    Stötter, Tabea; Bastviken, David; Bodelier, Paul L. E.; van Hardenbroek, Maarten; Rinta, Päivi; Schilder, Jos; Schubert, Carsten J.; Heiri, Oliver

    2018-07-01

    Proxy-indicators in lake sediments provide the only approach by which the dynamics of in-lake methane cycling can be examined on multi-decadal to centennial time scales. This information is necessary to constrain how lacustrine methane production, oxidation and emissions are expected to respond to global change drivers. Several of the available proxies for reconstructing methane cycle changes of lakes rely on interpreting past changes in the abundance or relevance of methane oxidizing bacteria (MOB), either directly (e.g. via analysis of bacterial lipids) or indirectly (e.g. via reconstructions of the past relevance of MOB in invertebrate diet). However, only limited information is available about the extent to which, at the ecosystem scale, variations in abundance and availability of MOB reflect past changes in in-lake methane concentrations. We present a study examining the abundances of fatty acids (FAs), particularly of 13C-depleted FAs known to be produced by MOB, relative to methane concentrations in 29 small European lakes. 39 surface sediment samples were obtained from these lakes and FA abundances were compared with methane concentrations measured at the lake surface, 10 cm above the sediments and 10 cm within the sediments. Three of the FAs in the surface sediment samples, C16:1ω7c, C16:1ω5c/t, and C18:1ω7c were characterized by lower δ13C values than the remaining FAs. We show that abundances of these FAs, relative to other short-chain FAs produced in lake ecosystems, are related with sedimentary MOB concentrations assessed by quantitative polymerase chain reaction (qPCR). We observed positive relationships between methane concentrations and relative abundances of C16:1ω7c, C16:1ω5c/t, and C18:1ω7c and the sum of these FAs. For the full dataset these relationships were relatively weak (Spearman's rank correlation (rs) of 0.34-0.43) and not significant if corrected for multiple testing. However, noticeably stronger and statistically significant

  19. Assessing metal contamination in recent creek sediments using fractionation technique along Mumbai coast, India

    Digital Repository Service at National Institute of Oceanography (India)

    Fernandes, L.L.; Nayak, G.N.

    nitrogen) and sediment components (sand, silt, clay). A sequential extraction procedure was also applied to understand the partitioning of trace metals among the different fractions of the sediment. Together with this data, pollution indices were also...

  20. A Novel Technique for Assessing Antioxidant Concentration in Retrieved UHMWPE.

    Science.gov (United States)

    Currier, Barbara H; Van Citters, Douglas W

    2017-05-01

    identification of antioxidant content. Paired Student's t-tests were used to compare as-retrieved articular antioxidant index with expected antioxidant index (the bulk value for blended antioxidants where constant antioxidant content is expected throughout and the extrapolated original vitamin E concentration at the articular surface based on the as-manufactured vitamin E concentration gradient). Linear regression was used for each of the retrievals to evaluate the correlation of antioxidant index to ester content with the goal of extrapolation to the antioxidant index at zero ester content. On average, vitamin E index at the articular surface (0.04 ± 0.03) was reduced compared with expected vitamin E index (0.09 ± 0.04; 95% confidence interval [CI] of the difference, 0.04-0.07; p antioxidant indices at zero absorbed ester index. Absorbed esters from time in vivo caused erroneous values of antioxidant index to be calculated. However, hexane extraction to remove absorbed species also removed diffused vitamin E. Correlating antioxidant indices with ester content, measured by FTIR in unextracted antioxidant retrievals, provides a nonaltered method for estimating actual articular surface vitamin E index and demonstrates that there was no measurable elution in these short-term retrievals. Assessing antioxidant content in retrieved polyethylene inserts is important to determine how much of the antioxidant remains in place to prevent oxidation of the polyethylene over time in vivo. Retrieval analyses reporting antioxidant content must account for absorbed species to be valid. Because standard hexane extraction removes both absorbed species and vitamin E from diffused vitamin E retrievals, the correlation method presented in this study is the recommended analysis alternative.

  1. Polycyclic aromatic hydrocarbons and black carbon in intertidal sediments of China coastal zones: Concentration, ecological risk, source and their relationship

    Energy Technology Data Exchange (ETDEWEB)

    Li, Xiaofei [School of Geographical Sciences, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China); Hou, Lijun [State Key Laboratory of Estuarine and Coastal Research, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China); Li, Ye [School of Geographical Sciences, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China); Liu, Min, E-mail: mliu@geo.ecnu.edu.cn [School of Geographical Sciences, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China); Key Laboratory of Geographic Information Science, Ministry of Education, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China); Lin, Xianbiao; Cheng, Lv [School of Geographical Sciences, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062 (China)

    2016-10-01

    Polycyclic aromatic hydrocarbons (PAHs) and black carbon (BC) have attracted many attentions, especially in the coastal environments. In this study, spatiotemporal distributions of PAHs and BC, and the correlations between BC and PAHs were investigated in the intertidal sediments of China coastal zones. BC in sediments was measured through dichromate oxidation (BC{sub Cr}) and thermal oxidation (BC{sub CTO}). The concentrations of BC{sub Cr} in the intertidal sediments ranged between 0.61 and 6.32 mg g{sup −1}, while BC{sub CTO} ranged between 0.57 and 4.76 mg g{sup −1}. Spatial variations of δ{sup 13}C signatures in TOC and BC were observed, varying from − 21.13‰ to − 24.87‰ and from − 23.53‰ to − 16.78‰, respectively. PAH contents of sediments ranged from 195.9 to 4610.2 ng g{sup −1} in winter and 98.2 to 2796.5 ng g{sup −1} in summer, and significantly seasonal variations were observed at most sampling sites. However, the results of potential toxicity assessment indicated low ecological risk in the intertidal sediments of China coastal zones. Greater concentrations of PAHs measured in the sediments of estuarine environments indicated that rivers runoff may have been responsible for the higher PAH pollution levels in the intertidal sediments of China coastal zones. Pearson's correlation analysis suggested that pyrogenic compounds of PAH were significantly related to BC, due to that both BC and these compounds derived mainly from the combustion process of fossil fuels and biomass. Overall, increasing energy consumptions caused by anthropogenic activities can contribute more emissions of BC as well as PAHs and thus improve the importance of BC in indicating pyrogenic compounds of PAHs in the intertidal sediments of China coastal zones. - Highlights: • River runoffs were responsible for the high PAH pollution levels in the study area. • BC and PAHs derived mainly from the combustion process of fossil fuels. • BC was associated

  2. Comparison of infrared spectroscopy techniques: developing an efficient method for high resolution analysis of sediment properties from long records

    Science.gov (United States)

    Hahn, Annette; Rosén, Peter; Kliem, Pierre; Ohlendorf, Christian; Persson, Per; Zolitschka, Bernd; Pasado Science Team

    2010-05-01

    The analysis of sediment samples in visible to mid-infrared spectra is ideal for high-resolution records. It requires only small amounts (0.01-0.1g dry weight) of sample material and facilitates rapid and cost efficient analysis of a wide variety of biogeochemical properties on minerogenic and organic substances (Kellner et al. 1998). One of these techniques, the Diffuse Reflectance Fourier Transform Infrared Spectrometry (DRIFTS), has already been successfully applied to lake sediment from very different settings and has shown to be a promising technique for high resolution analyses of long sedimentary records on glacial-interglacial timescales (Rosén et al. 2009). However, the DRIFTS technique includes a time-consuming step where sediment samples are mixed with KBr. To assess if alternative and more rapid infrared (IR) techniques can be used, four different IR spectroscopy techniques are compared for core catcher sediment samples from Laguna Potrok Aike - an ICDP site located in southernmost South America. Partial least square (PLS) calibration models were developed using the DRIFTS technique. The correlation coefficients (R) for correlations between DRIFTS-inferred and conventionally measured biogeochemical properties show values of 0.80 for biogenic silica (BSi), 0.95 for total organic carbon (TOC), 0.91 for total nitrogen (TN), and 0.92 for total inorganic carbon (TIC). Good statistical performance was also obtained by using the Attenuated Total Reflectance Fourier Transform Infrared Spectroscopy ATR-FTIRS technique which requires less sample preparation. Two devices were used, the full-sized Bruker Equinox 252 and the smaller and less expensive Bruker Alpha. R for ATR-FTIRS-inferred and conventionally measured biogeochemical properties were 0.87 (BSi), 0.93 (TOC), 0.90 (TN), and 0.91 (TIC) for the Alpha, and 0.78 (TOC), 0.85 (TN), 0.79 (TIC) for the Equinox 252 device. As the penetration depth of the IR beam is frequency dependent, a firm surface contact of

  3. Relations between continuous real-time turbidity data and discrete suspended-sediment concentration samples in the Neosho and Cottonwood Rivers, east-central Kansas, 2009-2012

    Science.gov (United States)

    Foster, Guy M.

    2014-01-01

    The Neosho River and its primary tributary, the Cottonwood River, are the primary sources of inflow to the John Redmond Reservoir in east-central Kansas. Sedimentation rate in the John Redmond Reservoir was estimated as 743 acre-feet per year for 1964–2006. This estimated sedimentation rate is more than 80 percent larger than the projected design sedimentation rate of 404 acre-feet per year, and resulted in a loss of 40 percent of the conservation pool since its construction in 1964. To reduce sediment input into the reservoir, the Kansas Water Office implemented stream bank stabilization techniques along an 8.3 mile reach of the Neosho River during 2010 through 2011. The U.S. Geological Survey, in cooperation with the Kansas Water Office and funded in part through the Kansas State Water Plan Fund, operated continuous real-time water-quality monitors upstream and downstream from stream bank stabilization efforts before, during, and after construction. Continuously measured water-quality properties include streamflow, specific conductance, water temperature, and turbidity. Discrete sediment samples were collected from June 2009 through September 2012 and analyzed for suspended-sediment concentration (SSC), percentage of sediments less than 63 micrometers (sand-fine break), and loss of material on ignition (analogous to amount of organic matter). Regression models were developed to establish relations between discretely measured SSC samples, and turbidity or streamflow to estimate continuously SSC. Continuous water-quality monitors represented between 96 and 99 percent of the cross-sectional variability for turbidity, and had slopes between 0.91 and 0.98. Because consistent bias was not observed, values from continuous water-quality monitors were considered representative of stream conditions. On average, turbidity-based SSC models explained 96 percent of the variance in SSC. Streamflow-based regressions explained 53 to 60 percent of the variance. Mean squared

  4. Relationship of bifenthrin sediment concentrations to grain size and total organic carbon in California waterbodies: implications for ecological risk.

    Science.gov (United States)

    Hall, Lenwood W; Anderson, Ronald D

    2014-12-01

    A summary analysis of data sets from six California waterbodies was conducted to determine the relationship of bifenthrin sediment concentrations to: % sand/gravel; % silt; % clay; % silt/clay and % total organic carbon (TOC). The relationship of TOC to % sand/gravel, % silt, % clay, and % silt/clay was also analyzed. Statistically significant and meaningful direct relationships were reported between bifenthrin and % TOC, % silt, % clay and % silt/clay while a significant and meaningful inverse relationship was reported between bifenthrin and % sand/gravel. A significant and meaningful inverse relationship was reported between % TOC and % sand/gravel, while a significant and meaningful direct relationship was reported between % TOC and % silt, % clay and % silt/clay. Significant bifenthrin sediment concentrations would not be expected in non-depositional (sand/gravel) areas which have been reported to be dominant in various streams in California's Central Valley and are also the preferred habitat for many benthic macroinvertebrate taxa.

  5. Radioactivity and metal concentrations in marine sediments associated with mining activities in Ierissos Gulf, North Aegean Sea, Greece

    International Nuclear Information System (INIS)

    Pappa, F.K.; Tsabaris, C.; Ioannidou, A.; Patiris, D.L.; Kaberi, H.; Pashalidis, I.; Eleftheriou, G.; Androulakaki, E.G.; Vlastou, R.

    2016-01-01

    Marine sediment samples were collected from Ierissos Gulf, N Aegean Sea, close to the coastal mining facilities. Measurements of radionuclide and metal concentrations, mineral composition and grain size distribution were performed. The concentrations of "2"2"6Ra, "2"3"5U and trace metals showed enhanced values in the port of Stratoni compared with those obtained near to Ierissos port. The dose rates received by marine biota were also calculated by the ERICA Assessment Tool and the results indicated no significant radiological risk. - Highlights: • Baseline information of radionuclides in a coastal area near a mining site. • Trace metals measurements in marine sediment. • Dose rates assessment for marine biota using ERICA Assessment Tool.

  6. Response of suspended sediment concentration to tidal dynamics at a site inside the mouth of an inlet: Jiaozhou Bay (China

    Directory of Open Access Journals (Sweden)

    S. L. Yang

    2004-01-01

    Full Text Available Observations of fair weather currents and suspended sediment concentrations (SSC were made using an acoustic Doppler current profiler and two YSI turbidity sensors over a neap to spring time cycle at a site near the inner mouth of a semi-enclosed mesotidal-macrotidal embayment (Jiaozhou Bay to examine the influence of tidal dynamics on concentration and transport of suspended sediment. During the investigation, SSC varied from about 3 to 16 mg L–1 at the surface and about 6 to 40 mg L–1 close to the bed, while the current velocity reached 79 cm s–1 at the surface and 61 cm s–1 near the bed. SSC was tidally cyclic. The near-bed instantaneous SSC was closely related to current velocity with almost no time lag, indicating that the variability of SSC was governed by current-induced settling/resuspension. At the surface, however, instantaneous SSC was poorly related to instantaneous current velocity because the peak SSC tended to occur around ebb slack water. This suggests that the surface SSC was controlled by horizontal advection from landward higher concentration areas. Both at the surface and near the bed, on the other hand, tidally-averaged SSC was well correlated to tidal range and current speed. Current velocity and SSC were flood-dominated for all the tides investigated, which resulted in significant landward residual suspended sediment transport at the study site. The observed flood dominance was mainly attributed to the location of the study site on the landward side of the bay’s inlet where flow separation is favoured during flood tide. It was concluded that tides are the dominant hydrodynamic component controlling the variability of SSC during fair weather at the study area. Keywords: sediment, concentration, suspension, advection, currents, shoalling effect, Jiaozhou Bay, China

  7. Uranium hydrogeochemical and stream sediment reconnaissance of the thermopolis NTMS Quadrangle, Wyoming, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Maassen, L.W.

    1980-08-01

    The Los Alamos Scientific Laboratory conducted a hydrogeochemical and stream sediment reconnaissance for uranium in the Thermopolis National Topographic Map Series quadrangle, Wyoming. Totals of 920 water and 1821 sediment samples were collected from 1977 locations at an average density of one sample location per 9 km 2 over an 18,000-km 2 area. Water samples were collected from streams, springs, and wells; sediment samples were collected from streams and springs. The uranium contents of water samples range from below the detection limit of 0.02 ppB to 307.98 ppB with a median of 0.56 ppB. Six clusters of anomalous water samples were delineated within the Wind River Basin and are associated predominantly with the Wind River formation. Two clusters of anomalous waters were collected on the southern margin of the Bighorn Basin and are associated with sandstone and shales of Permian through Cretaceous age. The uranium contents of sediment samples range from 0.43 to 94.65 ppM with a median of 2.90 ppM. Most sediment samples with uranium concentrations of greater than 12 ppM are underlain by Precambrian crystalline rocks of the Wind River Range; this area contains the highest uranium values found in sediments from the Thermopolis quadrangle. Other samples containing greater than 12 ppM uranium are found associated with the Wind River and Aycross formations along the northern margin of the Wind River Basin, and one sample was collected from Precambrian granitic terrain of the Owl Creek Mountains

  8. Combined SEM/AVS and attenuation of concentration models for the assessment of bioavailability and mobility of metals in sediments of Sepetiba Bay (SE Brazil).

    Science.gov (United States)

    Ribeiro, Andreza Portella; Figueiredo, Ana Maria Graciano; dos Santos, José Osman; Dantas, Elizabeth; Cotrim, Marycel Elena Barboza; Figueira, Rubens Cesar Lopes; Silva Filho, Emmanoel V; Wasserman, Julio Cesar

    2013-03-15

    This study proposes a new methodology to study contamination, bioavailability and mobility of metals (Cd, Cu, Ni, Pb, and Zn) using chemical and geostatistics approaches in marine sediments of Sepetiba Bay (SE Brazil). The chemical model of SEM (simultaneously extracted metals)/AVS (acid volatile sulfides) ratio uses a technique of cold acid extraction of metals to evaluate their bioavailability, and the geostatistical model of attenuation of concentrations estimates the mobility of metals. By coupling the two it was observed that Sepetiba Port, the urban area of Sepetiba and the riverine discharges may constitute potential sources of metals to Sepetiba Bay. The metals are concentrated in the NE area of the bay, where they tend to have their lowest mobility, as shown by the attenuation model, and are not bioavailable, as they tend to associate with sulfide and organic matter originated in the mangrove forests of nearby Guaratiba area. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Polychlorinated biphenyl (PCB) contamination in Galveston Bay, Texas: Comparing concentrations and profiles in sediments, passive samplers, and fish.

    Science.gov (United States)

    Oziolor, Elias M; Apell, Jennifer N; Winfield, Zach C; Back, Jeffrey A; Usenko, Sascha; Matson, Cole W

    2018-05-01

    The industrialized portion of the Houston Ship Channel (HSC) is heavily contaminated with anthropogenic contaminants, most prominent of which are the polychlorinated biphenyls (PCBs). This contamination has driven adaptive evolution in a keystone species for Galveston Bay, the Gulf killifish (Fundulus grandis). We investigated the geographical extent of PCB impacts by sampling 12 sites, ranging from the heavily industrialized upper portion of the HSC to Galveston Island. At each site, PCB concentrations and profiles were determined in three environmental compartments: sediment, water (polyethylene passive samplers), and fish tissue (resident Gulf killifish). We observed a steep gradient of PCB contamination, ranging from 4.00 to 100,000 ng/g organic carbon in sediment, 290-110,000 ng/g lipid in fish, and 4.5-2300 ng/g polyethylene in passive samplers. The PCB congener profiles in Gulf killifish at the most heavily contaminated sites were shifted toward the higher chlorinated PCBs and were highly similar to the sediment contamination profiles. In addition, while magnitude of total PCB concentrations in sediment and total fish contamination levels were highly correlated between sites, the relative PCB congener profiles in fish and passive samplers were more alike. This strong correlation, along with a lack of dependency of biota-sediment accumulation factors with total contamination rates, confirm the likely non-migratory nature of Gulf killifish and suggest their contamination levels are a good site-specific indicator of contamination in the Galveston Bay area. The spatial gradient of PCB contamination in Galveston Bay was evident in all three matrices studied and was observed effectively using Gulf killifish contamination as an environmentally relevant bioindicator of localized contamination in this environment. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. A PTV method based on ultrasound imaging and feature tracking in a low-concentration sediment-laden flow

    Science.gov (United States)

    Ma, Zhimin; Hu, Wenbin; Zhao, Xiaohong; Tao, Weiliang

    2018-02-01

    This study aims to provide a particle tracking velocimetry (PTV) method based on ultrasound imaging and feature-tracking in a low-concentration sediment-laden flow. A phased array probe is used to generate a 2D ultrasound image at different times. Then, the feature points are extracted to be tracked instead of the centroids of the particle image. In order to better identify the corresponding feature point, each feature is described by an oriented angle and its location. Then, a statistical interpolation procedure is used to yield the displacement vector on the desired grid point. Finally a correction procedure is adopted because the ultrasound image is sequentially acquired line by line through the field of view. A simple test experiment was carried out to evaluate the performance. The ultrasound PTV system was applied to a sediment-laden flow with a low concentration of 1‰, and the speed was up to 10 cm s-1. In comparison to optical particle image velocimetry (PIV), ultrasound imaging does not have a limitation in optical access. The feature-tracking method does not have a binarisation and segmentation procedure, which can result in overlapping particles or a serious loss of particle data. The feature-tracking algorithm improves the peak locking effect and measurement accuracy. Thus, the ultrasound PTV algorithm is a feasible alternative and is significantly more robust against gradients than the correlation-based PIV algorithms in a low-concentration sediment-laden fluid.

  11. A data reconnaissance on the effect of suspended-sediment concentrations on dissolved-solids concentrations in rivers and tributaries in the Upper Colorado River Basin

    Science.gov (United States)

    Tillman, Fred D.; Anning, David W.

    2014-01-01

    The Colorado River is one of the most important sources of water in the western United States, supplying water to over 35 million people in the U.S. and 3 million people in Mexico. High dissolved-solids loading to the River and tributaries are derived primarily from geologic material deposited in inland seas in the mid-to-late Cretaceous Period, but this loading may be increased by human activities. High dissolved solids in the River causes substantial damages to users, primarily in reduced agricultural crop yields and corrosion. The Colorado River Basin Salinity Control Program was created to manage dissolved-solids loading to the River and has focused primarily on reducing irrigation-related loading from agricultural areas. This work presents a reconnaissance of existing data from sites in the Upper Colorado River Basin (UCRB) in order to highlight areas where suspended-sediment control measures may be useful in reducing dissolved-solids concentrations. Multiple linear regression was used on data from 164 sites in the UCRB to develop dissolved-solids models that include combinations of explanatory variables of suspended sediment, flow, and time. Results from the partial t-test, overall likelihood ratio, and partial likelihood ratio on the models were used to group the sites into categories of strong, moderate, weak, and no-evidence of a relation between suspended-sediment and dissolved-solids concentrations. Results show 68 sites have strong or moderate evidence of a relation, with drainage areas for many of these sites composed of a large percentage of clastic sedimentary rocks. These results could assist water managers in the region in directing field-scale evaluation of suspended-sediment control measures to reduce UCRB dissolved-solids loading.

  12. A sedimentation study in the Muda catchment area using nuclear techniques

    International Nuclear Information System (INIS)

    Kamarudin Samuding; Wan Zakaria Wan Muhamad Tahir; Roslan Mohd Ali; Juhari Yusuf

    2002-01-01

    A study on the sediment size distribution and determination of sediment density profile was conducted in a selected area of the Muda Dam catchment area, Kedah. The objective of the study was to establish baseline data of the input sedimentation with regard to the effects of development within the catchment in the future. Three main sampling locations were identified, namely at Sungai Teliang, Sungai Muda and the Muda Reservoir. Results showed that the grain size distribution of sediment generally ranged from clay to gravel size. In the reservoir and downstream the river, most of the samples studied consisted of fine sediment Le, silt and clay (< 63 μm). However, sediment distribution in the upstream section of Sungai Teliang mainly consisted of fine to coarse sand. Based on the sediment distribution profile analysis, the study site could be divided into two parts comprising the dynamic area (region) covering selected locations along the river and the deposited sediment in the reservoir. Measurement of sediment thickness was performed using nuclear gauges, i.e. direct transmission and backscattering methods. The result also showed that the thickness of bed sediment varied from one location to another, whereby the thickness variation could reach up to 0.75 metre in some areas. This study could assist local authorities (AMDA) in identifying the rates and sources of accumulated sediment as well as quality and quantity of water in the study area in order to sustain distribution of good quality water to the farmers. (Author)

  13. Evaluation of ultrasonic technique to characterize the concentration of boric acid in liquid medium

    International Nuclear Information System (INIS)

    Kohara, Richard Yuzo Ramida

    2015-01-01

    This dissertation is to analyze the viability of using ultrasonic technique to characterize the concentration of boric acid in liquid medium non-invasively, therefore, ultrasonic tests were performed relating different boric acid concentrations with the travel time of the ultrasonic wave, also were evaluated factors able to mask the characterization of these concentrations by ultrasonic technique. The results showed that the ultrasonic technique allows the characterization of boric acid concentrations in liquid medium in very simple terms by the ultrasonic wave travel time, requiring further studies in complex conditions. (author)

  14. Biodiversity effects of benthic ecosystem engineers on the spatial patterns of sediment CH4 concentration in an urban Neotropical coastal lagoon

    Directory of Open Access Journals (Sweden)

    Adriano Caliman

    Full Text Available AIM: Biodiversity of sediment bioturbators has been shown to be important for to the magnitude and stability of benthic-pelagic processes. However, no study to date has evaluated the importance of the biodiversity of benthic invertebrate bioturbators to the spatial patterns of sediment CH4 concentration ([CH4]. Here we conducted a laboratorial experiment to test the following predictions: (1 Bioturbator species richness will reduce the sediment [CH4]; (2 individual bioturbator species (i.e. species composition will have different effects on sediment [CH4]; (3 and both the effects of bioturbator species richness and composition on sediment [CH4] will be dependent on sediment depth. METHODS: We manipulated the number and composition of three functional divergent benthic invertebrate bioturbators species that are widespread in South Atlantic coastal lagoons, in laboratorial sediment chambers containing the sediment and water of an urban impacted coastal lagoon RESULTS: Bioturbator species richness had no overall significant effect on sediment [CH4] when comparisons of sediment [CH4] were made among species richness levels. However, bioturbator species richness significantly reduced sediment [CH4] when species richness levels were compared to the control (defaunated treatments, but this effect was significant only at the deepest sediment layer. Furthermore, bioturbator species composition had significant, but distinct effects on the patterns of reduction in sediment [CH4], depending on the sediment depth and the bioturbator species. CONCLUSIONS: We conclude that both the number and composition of bioturbator species are important to determine the effects of benthic bioturbators on spatial patterns of sediment [CH4], but the strength of these effects depend on species traits that determine interspecific interactions strength across the sediment vertical niche space.

  15. Metal concentrations in zebra mussels and sediments from embayments and riverine environments of eastern Lake Erie, southern Lake Ontario, and the Niagara River.

    Science.gov (United States)

    Lowe, T P; Day, D D

    2002-10-01

    Concentrations of 14 metals were studied in the soft tissues of zebra mussels ( Dreissena polymorpha) and sediments from 16 Great Lakes embayments and riverine environments. Samples were collected in 1993 and 1994 during the early and late autumn period when the body mass of mussels is least affected by reproductive activities. There was a significant difference in geometric mean concentrations of all metals except Cu in mussels sampled from different sites, and there was a significant difference in the geometric mean concentrations of all metals but Cd, Mn, and Zn between years. The higher metal concentrations in mussels from this study were generally similar to those in mussels from contaminated European and U.S. locations, and those with lower concentrations were similar to those from uncontaminated European and U.S. locations. Geometric mean sediment concentrations of all metals differed significantly among sites. Sediment concentrations of metals from some sites were above EPA guidelines for moderately polluted harbor sediments. Sites where zebra mussels had higher concentrations of Al, Cr, and V tended to be the same sites as those where sediment concentrations of these metals were also higher. However, there was not a significant statistical relationship between concentrations of metals in zebra mussels and sediments, except for Mg.

  16. Petroleum hydrocarbon concentrations in marine sediments along Nagapattinam - Pondicherry coastal waters, Southeast coast of India.

    Science.gov (United States)

    Kamalakannan, K; Balakrishnan, S; Sampathkumar, P

    2017-04-15

    In this present study, petroleum hydrocarbons were statistically analyzed in three different coastal sediment cores viz., (N1, P1 and P2) from the Southeast coast of Tamil Nadu, India to examine the viability of PHCs. The significant positive relationship between mud (silt+clay+sand) and PHC unveiled that high specific surface of area of mud content raise the level of PHCs. Cluster analysis was used to discriminate the sediment samples based on their degree of contamination. The present study shows that instead of expensive and destructive PHC chemical methods, magnetic susceptibility is found to be a suitable, cheap and rapid method for detailed study of PHC in marine sediments. This baseline PHCs data can be used for regular ecological monitoring and effective management for the mining and tourism related activities in the coastal ecosystem. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

  17. Assessment of soil erosion and sedimentation through the use of the 137Cs and related techniques

    International Nuclear Information System (INIS)

    Queralt, I.; Zapata, F.; Garcia Agudo, E.

    2000-01-01

    During the last decades the international scientific community has been increasingly aware of both the risk and the effects of soil erosion and sedimentation processes cause to sustainable agricultural activities and the quality of the superficial environment. Soil erosion is a major environmental worldwide concern of our time. Over the past thirty years two main streams of thought have developed about the effects of soil erosion. The first one, mainly based on ecologist and environmentalist criteria, believes that soil erosion is a true disease on the land that quickly depletes the soil production capacity with some additional subsequent effects such as eutrophication of water reservoirs and pollution of natural waters. The second one supports that soil erosion is a natural process shaping the overall landscape. Development of fertile soils on river valleys can be attributed to erosion processes in the upper reaches of catchment. Loss of productivity due to soil erosion on agricultural lands can be easily compensated by small addition of fertilisers . W h a t ever position we adopt a development of methods offering reliable data is needed. The use of models based on radiogenic isotopes distribution in soil profiles can offer valuable data set both in soil erosion and deposition. In addition, soil redistribution can be effectively assessed. These methods can be applied in a huge range of soil conditions in different geographic zones and the results are comparable at global scale. The International Atomic Energy Agency (IAEA) sponsored since 1995, the implementation of two co-ordinated research projects (CRP's) dealing with the application of the 137 Cs technique in soil erosion and sedimentation studies respectively. A joint Meeting of both CRP's was organised by the Land and Water Conservation Group of the Institute of Earth Sciences 'Jaume Almera', CSIC, in Barcelona, Spain, from 4 to 8 October 1999. This Special Issue of Acta Geologica Hispanica contains a

  18. Estimating concentrations of fine-grained and total suspended sediment from close-range remote sensing imagery

    Science.gov (United States)

    Mosbrucker, Adam; Spicer, Kurt R.; Christianson, Tami; Uhrich, Mark A.

    2015-01-01

    Fluvial sediment, a vital surface water resource, is hazardous in excess. Suspended sediment, the most prevalent source of impairment of river systems, can adversely affect flood control, navigation, fisheries and aquatic ecosystems, recreation, and water supply (e.g., Rasmussen et al., 2009; Qu, 2014). Monitoring programs typically focus on suspended-sediment concentration (SSC) and discharge (SSQ). These time-series data are used to study changes to basin hydrology, geomorphology, and ecology caused by disturbances. The U.S. Geological Survey (USGS) has traditionally used physical sediment sample-based methods (Edwards and Glysson, 1999; Nolan et al., 2005; Gray et al., 2008) to compute SSC and SSQ from continuous streamflow data using a sediment transport-curve (e.g., Walling, 1977) or hydrologic interpretation (Porterfield, 1972). Accuracy of these data is typically constrained by the resources required to collect and analyze intermittent physical samples. Quantifying SSC using continuous instream turbidity is rapidly becoming common practice among sediment monitoring programs. Estimations of SSC and SSQ are modeled from linear regression analysis of concurrent turbidity and physical samples. Sediment-surrogate technologies such as turbidity promise near real-time information, increased accuracy, and reduced cost compared to traditional physical sample-based methods (Walling, 1977; Uhrich and Bragg, 2003; Gray and Gartner, 2009; Rasmussen et al., 2009; Landers et al., 2012; Landers and Sturm, 2013; Uhrich et al., 2014). Statistical comparisons among SSQ computation methods show that turbidity-SSC regression models can have much less uncertainty than streamflow-based sediment transport-curves or hydrologic interpretation (Walling, 1977; Lewis, 1996; Glysson et al., 2001; Lee et al., 2008). However, computation of SSC and SSQ records from continuous instream turbidity data is not without challenges; some of these include environmental fouling, calibration, and

  19. Radioactivity and metal concentrations in marine sediments associated with mining activities in Ierissos Gulf, North Aegean Sea, Greece.

    Science.gov (United States)

    Pappa, F K; Tsabaris, C; Ioannidou, A; Patiris, D L; Kaberi, H; Pashalidis, I; Eleftheriou, G; Androulakaki, E G; Vlastou, R

    2016-10-01

    Marine sediment samples were collected from Ierissos Gulf, N Aegean Sea, close to the coastal mining facilities. Measurements of radionuclide and metal concentrations, mineral composition and grain size distribution were performed. The concentrations of (226)Ra, (235)U and trace metals showed enhanced values in the port of Stratoni compared with those obtained near to Ierissos port. The dose rates received by marine biota were also calculated by the ERICA Assessment Tool and the results indicated no significant radiological risk. Copyright © 2016 Elsevier Ltd. All rights reserved.

  20. Impacts of anthropic pressures on soil phosphorus availability, concentration, and phosphorus forms in sediments in a Southern Brazilian watershed

    Energy Technology Data Exchange (ETDEWEB)

    Pellegrini, Joao Batista Rossetto; Rheinheimer dos Santos, Danilo; Goncalves, Celso Santos; Copetti, Andre Carlos Cruz [Dept. de Solos, Univ. Federal de Santa Maria, Centro de Ciencias Rurais, Santa Maria, RS (Brazil); Bortoluzzi, Edson Campanhola [Faculdade de Agronomia e Medicina Veterinaria da Univ. de Passo Fundo, RS (Brazil); Tessier, Daniel [Inst. National de la Recherche Agronomique, Versailles (France)

    2010-04-15

    Purpose: The transfer of soil sediments and phosphorus from terrestrial to aquatic systems is a common process in agricultural lands. The aims of this paper are to quantify the soil phosphorus availability and to characterize phosphorus forms in soil sediments as contaminant agents of waters as a function of anthropic pressures. Materials and methods On three subwatersheds with different anthropic pressure, water and sediment samples were collected automatically in upstream and downstream discharge points in six rainfall events during the tobacco growing season. Phosphorus desorption capacity from soil sediments was estimated by successive extractions with anion exchange resins. First-order kinetic models were adjusted to desorption curves for estimating potentially bioavailable particulate phosphorus, desorption rate constant, and bioavailable particulate phosphorus. Results and discussion The amount of bioavailable particulate phosphorus was directly correlated with the iron oxide content. The value of desorption rate constant was directly related with the total organic carbon and inversely with the iron oxide contents. Phosphate ions were released to solution, on average, twice as rapidly from sediments collected in subwatersheds with low anthropic activity than from those ones of highly anthropic subwatersheds. Anthropic pressure on watershed can engender high sediment discharge, but these solid particles seem to present low phosphorus-releasing capacity to water during transport due to the evidenced high affinity between phosphorus and iron oxide from sediments. Conclusions Anthropic pressure was related with sediment concentration and phosphorus release to aquatic systems. While natural vegetation along streams plays a role on soil and water depuration, it is unable to eliminate the phosphorus inputs intrinsic to the agricultural-intensive systems. Recommendations and perspectives The contamination of water in watershed by phosphates is facilitated by the

  1. Estimation of carbonate concentration and characterization of marine sediments by Fourier transform infrared spectroscopy.

    Digital Repository Service at National Institute of Oceanography (India)

    Veerasingam, S.; Venkatachalapathy, R.

    its saturation horizon is shallower than that calcite [1]. Elements such as Ca2+ and Mg2+, in addition to their substantial contribution to marine sediments, are used biologically in vital cellular processes and in the mineralization of skeletons... such as ocean acidification on ecosystems. Thus, a rapid, cheap and non-destructive tool is required to investigate the distribution of CaCO3 in sediments for the understanding of the fate of biologically produced carbonate. 3    FTIR spectroscopy is one...

  2. Comparison of 210Pb level in Kuala Muda tsunami affected marine sediment core measured using two different techniques

    International Nuclear Information System (INIS)

    Yii Mei Wo; Zal Uyun Wan Mahmood; Jalal Sharib; Zaharudin Ahmad

    2010-01-01

    The most commonly used techniques of alpha and gamma spectrometry were compared to measure 210 Pb activity in marine sediment core. Alpha analytical technique measured the activity of 210 Pb from its in-grow grand-daughter 210 Po after a chemical separation by assuming that there is radioactive equilibrium between the two radionuclides. Meanwhile, gamma analysis technique allows direct measurement, non-destructive and no preliminary chemical separation. Through the comparison, it was found that both alpha and gamma analysis techniques were slightly different. Overall, the results from gamma analytical technique were higher than those from the alpha analytical techniques. Some logical argument had been discussed to explain this situation. In routine analysis, the analytical technique used should be chosen carefully based on advantages and disadvantages of the each technique and analysis requirements. Therefore, it is recommended to determine the exact needs and purpose of analysis and to know the sample history before deciding the appropriate analytical technique. (author)

  3. Reprint of Mechanisms of maintaining high suspended sediment concentration over tide-dominated offshore shoals in the southern Yellow Sea

    Science.gov (United States)

    Xiong, Jilian; Wang, Xiao Hua; Wang, Ya Ping; Chen, Jingdong; Shi, Benwei; Gao, Jianhua; Yang, Yang; Yu, Qian; Li, Mingliang; Yang, Lei; Gong, Xulong

    2018-06-01

    An understanding of the dynamics and behaviors of suspended sediments is vital in analysis of morphological, environmental, and ecological processes occurring in coastal marine environments. To study the mechanisms of maintaining high suspended sediment concentrations (SSCs) on a tide-dominated offshore shoal, we measured water depths, current velocities, SSCs, wave parameters and bottom sediment compositions in the southern Yellow Sea. These data were then used to calculate bottom shear stresses generated by currents (τc), waves (τw), and wave-current interactions (τcw). SSCs time series exhibited strong quarter-diurnal peaks during spring tides, in contrast to the semidiurnal signal during neap tides. A Fourier analysis showed that suspended sediment variations within tidal cycles was mainly controlled by resuspension in most stations. There existed relatively stable background SSCs (maintaining high SSCs among tidal cycles) values at all four stations during both windy (wind speed > 9.0 m/s) and normal weather conditions (wind speed value of 0.21 N/m2. On account of the strong tidal currents, background SSCs of spring tides were greater than that of neap tides. In addition, on the base of wavelet, statistics analyses and turbulence dissipation parameter, background SSCs during slack tide in the study area may be maintained by intermittent turbulence events induced by a combined tidal current and wave action.

  4. Evaluation of the concentration of toxic metals and rare ground elements in samples of sediments of the Billings and Guarapiranga systems reservoirs

    International Nuclear Information System (INIS)

    Silva, Larissa de Souza

    2017-01-01

    The excessive urbanization process of the Sao Paulo Metropolitan Region resulted in the loss of the natural characteristics of its water courses causing serious changes in flow and quality regimes. The objective of this study was evaluate the concentration of toxic metals, semi metals As, Sb and Se, and rare earth elements present in surface sediment samples collected at the Billings, Guarapiranga and Rio Grande Reservoirs. The Ag, Al, As, Ba, Ca, Cd, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Na, Ni, Pb, Sb, Se and Zn elements were analyzed using Optical Emission Spectrometry With Inductively Coupled Plasma (ICP OES). Some major, trace and rare earth elements (Ce, Eu, La, Lu, Nd, Sm, Tb and Yb) were analyzed by the Instrumental Neutron Activation Analysis (INAA) technique. The total Hg concentration was determined by Cold Vapor Atomic Absorption Spectrometry technique (CVAAS). The validation of the methodologies was performed by means of the certified reference material analyses. To assess the sources of anthropogenic contamination, the enrichment factor (EF) and the geoaccumulation index (IGeo) were calculated. The results obtained for both techniques were compared with TEL and PEL oriented values established by CCME (Canadian Council of Ministers of the Environment) and adopted by CETESB (Environmental Company of the Sao Paulo State). All sampling points showed concentration values for toxic metals >TEL and 2 points at Billings Reservoir (BILL02030 and 02100), values > PEL for As, Cr, Cu, Hg, Ni, Pb and Zn, probably due to the entrance of the Pinheiros River waters and drainage basins of the Cocaia and Borore streams. The calculated EF and IGeo values indicated possible anthropogenic contamination for Sb and Se for the elements determined by ICP OES and As, Cr, Sb and Zn, obtained by INAA. The Billings reservoir presented, in general, the highest concentrations for the analyzed elements, indicating a poor quality of its sediments. This study confirms the need of a frequent

  5. Uranium hydrogeochemical and stream sediment reconnaissance of the Dixon Entrance NTMS and Prince Rupert D-6 quadrangles, Alaska, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Warren, R.G.; Hensley, W.K.; Hanks, D.E.

    1980-09-01

    During August 1978, sediment and water samples were collected from 203 lakes, streams, and springs in the Dixon Entrance and Prince Rupert D-6 quadrangles, Alaska. Variations in concentrations of all 43 elements among the five sieve fractions at each location are generally less than analytical uncertainty. Therefore, elemental analyses are generally comparable for a wide range in sieve fractions for sediment sample locations in southeastern Alaska. However, at some few locations, several elemental concentrations increase with finer mesh size; for uranium, such an increase may be associated with mineralization. Waterborne sediment samples collected from the center of a stream yield analyses essentially identical to those collected from the adjacent bank for most elements. Chlorine concentrations are generally higher in bank sediments, probably as a result of concentration of halogens in the vegetation that stabilizes the bank. At a few locations, concentrations of the ferrous elements, particularly Mn and Co, differ notably between the stream center and bank: such behavior is characteristic of mineralized areas. Concentrations of the ferrous elements, particularly Mn and Co, are strikingly enriched in the stream sediments compared either to lake sediments or to crustal abundances. This suggests that this area might be a favorable location for strategic resources of these elements. Uranium concentrations in all 950 sediment samples of all sieve fractions range from 0.54 to 22.80 ppM, with a median of 2.70 ppM

  6. Total and methyl mercury concentrations in sediment and water of a constructed wetland in the Athabasca Oil Sands Region

    International Nuclear Information System (INIS)

    Oswald, Claire J.; Carey, Sean K.

    2016-01-01

    In the Athabasca Oil Sands Region in northeastern Alberta, Canada, oil sands operators are testing the feasibility of peatland construction on the post-mining landscape. In 2009, Syncrude Canada Ltd. began construction of the 52 ha Sandhill Fen pilot watershed, including a 15 ha, hydrologically managed fen peatland built on sand-capped soft oil sands tailings. An integral component of fen reclamation is post-construction monitoring of water quality, including salinity, fluvial carbon, and priority pollutant elements. In this study, the effects of fen reclamation and elevated sulfate levels on mercury (Hg) fate and transport in the constructed system were assessed. Total mercury (THg) and methylmercury (MeHg) concentrations in the fen sediment were lower than in two nearby natural fens, which may be due to the higher mineral content of the Sandhill Fen peat mix and/or a loss of Hg through evasion during the peat harvesting, stockpiling and placement processes. Porewater MeHg concentrations in the Sandhill Fen typically did not exceed 1.0 ng L −1 . The low MeHg concentrations may be a result of elevated porewater sulfate concentrations (mean 346 mg L −1 ) and an increase in sulphide concentrations with depth in the peat, which are known to suppress MeHg production. Total Hg and MeHg concentrations increased during a controlled mid-summer flooding event where the water table rose above the ground surface in most of the fen. The Hg dynamics during this event showed that hydrologic fluctuations in this system exacerbate the release of THg and MeHg downstream. In addition, the elevated SO 4 2− concentrations in the peat porewaters may become a problem with respect to downstream MeHg production once the fen is hydrologically connected to a larger wetland network that is currently being constructed. - Highlights: • A constructed fen peatland in the Athabasca Oil Sands Region was studied. • Total and methyl mercury concentrations in fen sediment and waters

  7. Assessment of heavy metal concentrations in water, sediment and biota (fish and crabs) samples from the Densu Delta

    International Nuclear Information System (INIS)

    Kudu, I.B.

    2010-01-01

    The aim of the study was assess the concentration of some selected heavy metals in water, sediments and biota (fish and crab) sampled from the Densu Delta. In situ and laboratory based analysis were carried out to measure the following physicochemical properties of surface water from the delta; temperature, pH, electrical conductivity (EC), salinity, total dissolved solids (TDS), alkalinity, sodium ion concentration (Na+), potassium ion concentration (K+), chloride ion concentration (Cl), bicarbonate concentration, phosphate concentration, nitrate concentration, sulphate concentration and biochemical oxygen demand (BOD). Heavy metal (Fe, Zn, Cu, Ni, Cd, Cr, Pb and Hg) concentrations in water, sediments, fish and crab sampled at six sites from the Densu Delta wetland in the month of December, 2009 were analysed using VARIAN Fast Sequential Atomic Absorption Spectrophotometer (AAS) model AA240 FS. Two fish species; Blackchin tilapia (Sarotherodon melanotheron), White mullet (Mugil curema) and one species of crab; Blue swimming crab (Callinectes amnicola) were collected from the Densu Delta wetland and analysed. Heavy metal contents in the fish were higher in gill tissue than muscle tissue while in crabs concentrations were higher in the soft tissue than the shell. Levels of Fe, Zn and Cu in the muscle tissue of S. melanotheron were greater than the levels detected in the muscle tissue of M. curema. Cd, Ni and Hg were detected in gill tissue but not in the muscle tissue of S. melanotheron, M. curema on the other hand contained these metals in both gill and muscle tissue. The maximum level of Fe (34.98 mg/L), Zn (25.08 mg/L) in the muscle of S. melanotheron was observed at Bortianor and Zn (2.70 mg/L) was observed at Tetegu. In the M. curema, the maximum level of Fe (34.66 mg/L), Zn (15.9 mg/L) and Cu (1.43 mg/L) was detected at Aplaku, Tetegu and Faana respectively. Heavy metal concentrations were higher in sediment than water. The presence of elevated levels of Cd

  8. Distribution study of fatty acids (FAs) in sediments of Al-Kabeer Al-Shemali river estuary area using (HPLC) technique

    International Nuclear Information System (INIS)

    Nasser, M.; Ali, B.; Ali, A.

    2010-01-01

    Samples of sediments from fife sites of Al-kabeer Al-shemali river estuary area were collected during the period (22/2/2007-7/11/2007). The samples were extracted to determine their content of Fatty acids qualitatively and quantitatively by using ( HPLC) technique for determination resources of organic matter in studied sediments . The total concentrations of (FAs) varied from (0.36-1245.5μg/g dry weight).The saturated fatty acids were dominated in all samples (12.1 - 100 %) of total fatty acids. The levels of polyunsaturated fatty acids (PUFAs) were tested percent (0-18 %) of total fatty acids except one sample from surficial sediments in St 3 during 8/8/2007 .while the concentrations of monounsaturated fatty acids (MUFAs) were low (0 -21.6 %) of total fatty acids . We can use the saturated long chain fatty acid (C-22) as terrestrial biomarker. poly unsaturated fatty acid (C 1 8: 2ω6) as plankton biomarker and the Mono unsaturated fatty acid (C 1 8 : 1ω7) as bacterial biomarker.(author)

  9. A colorimetric DET technique for the high-resolution measurement of two-dimensional alkalinity distributions in sediment porewaters

    DEFF Research Database (Denmark)

    Bennett, William W.; Welsh, David T.; Serriere, Antoine

    2015-01-01

    Measurements of porewater alkalinity are fundamental to the study of organic matter mineralization in sediments, which plays an essential role in the global cycles of carbon and nutrients. A new colorimetric diffusive equilibration in thin film (DET) technique is described for measuring two-dimen...

  10. Assessment of the concentration of Cr, Mn and Fe in sediment using ...

    African Journals Online (AJOL)

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    determination of levels of Cr, Mn and Fe in sediment samples and the results have ... produced within the plasma emit radiation over a broad spectral range, from UV ... intake [36] and their oxides play important role in the soil for fixing trace ...

  11. Revisiting geochemical methods of distinguishing natural concentrations and pollution by risk elements in fluvial sediments

    Czech Academy of Sciences Publication Activity Database

    Matys Grygar, Tomáš; Popelka, J.

    2016-01-01

    Roč. 170, NOV (2016), s. 39-57 ISSN 0375-6742 R&D Projects: GA ČR(CZ) GA15-00340S Institutional support: RVO:61388980 Keywords : Enrichment * Fluvial sediments * Heavy metals Subject RIV: DD - Geochemistry Impact factor: 2.464, year: 2016

  12. Detailed uranium hydrogeochemical and stream sediment reconnaissance data release for the eastern portion of the Montrose NTMS Quadrangle, Colorado, including concentrations of forty-five additional elements

    International Nuclear Information System (INIS)

    Maassen, L.W.

    1981-01-01

    In September and October 1979, the Los Alamos Scientific Laboratory (LASL) conducted a detailed geochemical survey for uranium primarily in the Sawatch Range in the eastern part of the Montrose National Topographic Map Series (NTMS) quadrangle, Colorado, as part of the National Hydrogeochemical and Stream Sediment Reconnaissance (HSSR). Totals of 1034 water and 2087 sediment samples were collected from streams and springs from 2088 locations within a 5420-km 2 area. Statistical data for uranium concentrations in water and sediment samples are presented. Elemental concentration, field measurement, weather, geologic, and geographic data for each sample location are listed for waters and for sediments in appendices. Uranium/thorium ratios for sediment samples are also included. This report contains uranium analyses for water samples and multielement analyses for sediment samples. Sediments were analyzed for uranium and thorium as well as Al, Sb, As, Ba, Be, Bi, Cd, Ca, Ce, Cs, Cl, Cr, Co, Cu, Dy, Eu, Au, Hf, Fe, La, Pb, Li, Lu, Mg, Mn, Ni, Nb, K, Rb, Sm, Sc, Se, Ag, Na, Sr, Ta, Tb, Sn, Ti, W, V, Yb, Zn, and Zr. All elemental analyses were performed at the LASL. Water samples were analyzed for uranium by fluorometry. Sediments were analyzed for uranium by delayed neutron counting. Other elemental concentrations in sediments were determined by neutron activation analysis for 31 elements, by x-ray fluorescence for 12 elements, and by arc-source emission spectrography for 2 elements. Descriptions of procedures as analytical precisions and detection limits are given in the appendix

  13. Evaluation of the boundary condition influence on PAH concentrations in the water column during the sediment dredging of a port.

    Science.gov (United States)

    Cutroneo, L; Castellano, M; Carbone, C; Consani, S; Gaino, F; Tucci, S; Magrì, S; Povero, P; Bertolotto, R M; Canepa, G; Capello, M

    2015-12-30

    The mobilisation of sediments and related contaminants connected to dredging activities is one of the most critical issues to the environmental risk and exposure assessment of a dredging project. The aim of this paper was an investigation of the mobilisation of polycyclic aromatic hydrocarbons (PAHs) due to the dredging of the Port of Genoa (Italy) to identify the temporal and spatial extent of the contaminant transport, and the influence of the dredging and the boundary conditions on it. The results showed relatively low background PAH concentrations in the water column and confirmed the dredging as the primary rising factor of concentrations in the water column, but also showed a complex scenario in which the different environmental and dredging factors forced the concentrations at different levels and moments. The post dredging phase showed PAH values close to the background conditions and the concentrations remained relatively high only for a few PAHs.

  14. High resolution characterization of uranium in sediments by DGT and DET techniques ACA-S-12-2197

    Czech Academy of Sciences Publication Activity Database

    Gregušová, Michaela; Dočekal, Bohumil

    2013-01-01

    Roč. 763, FEB 6 (2013), s. 50-56 ISSN 0003-2670 R&D Projects: GA ČR GAP503/10/2002 Institutional support: RVO:68081715 Keywords : Diffusive gradient in thin films technique * Diffusive equilibrium technique * Uranium * Sediment Subject RIV: CB - Analytical Chemistry , Separation Impact factor: 4.517, year: 2013 http://www.scopus.com/record/display.url?fedsrfIntegrator=COSMADRALI-SCOCIT&origin=fedsrf&view=basic&eid=2-s2.0-84872594514

  15. Effect of Hydrograph Separation on Suspended Sediment Concentration Predictions in a Forested Headwater with Thick Soil and Weathered Gneiss Layers

    Directory of Open Access Journals (Sweden)

    Naoki Kabeya

    2014-06-01

    Full Text Available Two-component hydrograph separation using oxygen-18 concentrations was conducted at a sediment runoff observation weir installed in a small subcatchment of a forested gneiss catchment in Japan. The mean soil thickness of this catchment is 7.27 m, which comprises 3.29 m of brown forest soil (A and B layers and a 3.98-m layer of heavily weathered gneiss. Data were collected for a storm on 20–21 May 2003, and the percentage of event water separated by the stable isotope ratio in comparison with the total rainfall amount was about 1%. This value is within the ratio of a riparian zone in a drainage area. Temporal variation of suspended sediment concentration exhibited higher correlation with the event water component than with the total runoff or pre-event water component. This shows that the riparian zone causes rainwater to flow out quickly during a rain event, and that this is an important area of sediment production and transportation in a forested headwater with thick soil and weathered gneiss layers.

  16. Metals and trace elements concentration in water and sediments of the hydrographic basins from Mogi-Guacu and Pardo rivers in the State of Sao Paulo, Brazil

    International Nuclear Information System (INIS)

    Lemes, Marcos Jose de Lima

    2001-01-01

    The present work aimed to evaluate the environmental water and sediment quality in Mogi-Guacu and Pardo Rivers Basins (Sao Paulo State), in the localities of water supply intake for the 13 cities in the basins. Metals and ions analysis of the water and sediment were performed according methods to procedures described in Standard Methods for Examinations of Water and Wastewater, 17th. edition. The hydrographic basins from Mogi-Guacu and Pardo Rivers have a large agriculture influence on limnologic, physical and chemical characteristics and this area is unique in the State of Sao Paulo that the water catchment for supply is only surface and used for water supply agriculture, public and industrial as well as far other uses, and it is also the recharge of Guarani's aquifer and it is one of huge aquifers of the world. On this study sampling was carried out at in a hydrological period, they were sampled bimonthly for 12 months (April 98/April 99) and analyzed: ions (F - , Cl - , SO 4 2- , Na + , K + and NH 4 + ), nutrients (NO 3 - and PO 4 3- ) using the Ion Chromatographic technique, metals (Ag, Al, Ba, Ca, Cd, Co, Cr, Cu, Fe, Mg, Mn, Ni, P, Pb and Zn) using the Inductively Coupled Plasma Atomic Emission Spectrometric technique, organic carbon, using the Volumetric technique, for characterization of the sediments was used X Ray Fluorescence Spectrometric and X Ray Diffraction Spectrometric techniques in the 13 communities. During the catchment's period was gotten a large number of results. For it was used a computer software program for descriptive, correlation and principal components analysis. The descriptive analyze was written Fe, Mn and Al getting down concentration after treatment water, the Mg, Co, P, Cu, Na and K elements still at same concentration after treatment concentration and, the Ca, F - , Cl - and SO 4 2- elements getting upper concentration after treatment water. The interstitial phase showed 2 to 30 fold values than natural water. For supernatant and

  17. Evaluation of the concentrations of rare earth elements, metals and traces in sediments of the Graminha Reservoir, São Paulo, SP, Brazil by Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Junqueira, Lucas S.; Fávaro, Déborah I.T.; Silva, Sharlleny A.

    2017-01-01

    Sediment profiles were collected in the Graminha (Caconde) supply reservoir, SP, in Aug / 2014 (points 1 and 4). The analytical technique of Neutral Activation with Instrumental Neutrons (INAA) was used and the determined elements were: As, Ba, Br, Ca, Co, Cr, Cs, Fe, Hf, K, Na, Rb, Sb, Ta, Th, U and Zn and the rare earth elements (ETRs) (Ce, Eu, La, Lu, Nd, Sm, Sc, Tb and Yb). The concentration values for the elements As, Cr and Zn were compared to the concentration guideline values (TEL and PEL) established by CCME (Canada) and adopted by CETESB. The sediments were classified as of good or optimal quality, for these 3 elements. The values found in the last slices of profile 1 (depth 90 cm) were taken as baseline values and from these values, the enrichment factors (FE) and the Geoacumulation Index (IGeo) were calculated. Values of FE> 1.5 were found, mainly, for the ETRs, U and Th, in both points, indicative of presence of anthropic contribution. The IGeo values confirmed FE values, with values of 1

  18. Environmentally relevant concentrations of polyethylene microplastics negatively impact the survival, growth and emergence of sediment-dwelling invertebrates.

    Science.gov (United States)

    Ziajahromi, Shima; Kumar, Anupama; Neale, Peta A; Leusch, Frederic D L

    2018-05-01

    Microplastics are a widespread environmental pollutant in aquatic ecosystems and have the potential to eventually sink to the sediment, where they may pose a risk to sediment-dwelling organisms. While the impacts of exposure to microplastics have been widely reported for marine biota, the effects of microplastics on freshwater organisms at environmentally realistic concentrations are largely unknown, especially for benthic organisms. Here we examined the effects of a realistic concentration of polyethylene microplastics in sediment on the growth and emergence of a freshwater organism Chironomus tepperi. We also assessed the influence of microplastic size by exposing C. tepperi larvae to four different size ranges of polyethylene microplastics (1-4, 10-27, 43-54 and 100-126 μm). Exposure to an environmentally relevant concentration of microplastics, 500 particles/kg sediment , negatively affected the survival, growth (i.e. body length and head capsule) and emergence of C. tepperi. The observed effects were strongly dependent on microplastic size with exposure to particles in the size range of 10-27 μm inducing more pronounced effects. While growth and survival of C. tepperi were not affected by the larger microplastics (100-126 μm), a significant reduction in the number of emerged adults was observed after exposure to the largest microplastics, with the delayed emergence attributed to exposure to a stressor. While scanning electron microscopy showed a significant reduction in the size of the head capsule and antenna of C. tepperi exposed to microplastics in the 10-27 μm size range, no deformities to the external structure of the antenna and mouth parts in organisms exposed to the same size range of microplastics were observed. These results indicate that environmentally relevant concentrations of microplastics in sediment induce harmful effects on the development and emergence of C. tepperi, with effects greatly dependent on particle size. Copyright

  19. Age determination of sediments by Pb-210 using a plastic detector technique

    International Nuclear Information System (INIS)

    Jensen, J.M.; Enge, W.; Erlenkeuser, H.; Willkomm, H.

    1976-01-01

    For age determination of sediments up to 150 years Pb-210 is suitable on grounds of its half life of 22.3 years. By a nitric acid disintegration lead is extracted out ot the sediment and subsequently precipitated electrolytically on Pt-electrodes. The activity of the sample resp. Pb-210 is measured via the alpha-activity of its granddaughter Po-210. As detector a plastic sheet (Cellulose nitrate, CA 80-15, made by Kodak) is used. Investigated was a sediment core from the Kieler Bucht, western Baltic Sea. The results let it appear possible, that the sediment is mixed up by shellfishes (cyprina islandica). (orig.) [de

  20. Age determination of sediments by 210Pb using a plastic detector technique

    International Nuclear Information System (INIS)

    Jensen, J.M.; Enge, W.; Erlenkeuser, H.; Willkomm, A.

    1977-01-01

    For age determination of sediments up to 150y 210 Pb is suitable on grounds of its half-life of 22.3y. By a nitric acid disintegration lead is extracted out of the sediment and subsequently precipitated electrolytically on Pt-electrodes. The activity of the sample resp. 210 Pb is measured via the alpha-activity of its granddaughter 210 Po. As detector a plastic sheet (cellulose nitrate, CA 80-15, made by Kodak) is used. Investigated was a sediment core from the Kieler Bucht, western Baltic Sea. The results make it appear possible, that the sediment is mixed up by shellfish (cyprina islandica). (Auth.)

  1. AMS measurement of {sup 10}Be concentrations in marine sediments from Chile Trench at the TANDAR laboratory

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, D., E-mail: darodrig@tandar.cnea.gov.ar [Departamento de Física Experimental, Laboratorio TANDAR, GIyA, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA San Martín (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Arazi, A. [Departamento de Física Experimental, Laboratorio TANDAR, GIyA, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA San Martín (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Fernández Niello, J.O. [Departamento de Física Experimental, Laboratorio TANDAR, GIyA, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA San Martín (Argentina); CONICET, Av. Rivadavia 1917, C1033AAJ Buenos Aires (Argentina); Instituto de Investigación e Ingeniería Ambiental, Universidad Nacional de San Martín, 25 de Mayo y Francia, B1650BWA San Martín, Buenos Aires (Argentina); Martí, G.V. [Departamento de Física Experimental, Laboratorio TANDAR, GIyA, Comisión Nacional de Energía Atómica, Av. Gral. Paz 1499, B1650KNA San Martín (Argentina); and others

    2017-03-15

    The {sup 10}Be/{sup 9}Be ratios in marine sediments samples from the Southern Chile Trench have been measured using accelerator mass spectrometry (AMS). The samples were measured at the TANDAR accelerator, where the discrimination of the {sup 10}Be radionuclides was achieved by means of a passive absorber in front of an ionization chamber. This setup along with the high voltage available, provided a complete suppression of the {sup 10}B isobar interference. The obtained values for the {sup 10}Be concentrations, of the order of 10{sup 9} atoms/g, are the first {sup 10}Be measurements from the Southern Chile Trench and offer an excellent tracer to quantitatively study the recycling of sediments in Andean magmas.

  2. The use of x-ray fluorescence technique (XRF) in the determination of trace elements in environmental study: a case study for sediments and soils

    International Nuclear Information System (INIS)

    Hamzah Mohamad

    1997-01-01

    A specific X-ray fluorescence technique (XRF) was developed to determine the concentrations of nine common and significant trace elements in sediments and soils, i.e. two of the common materials used in environmental studies. The elements are Ba, Cr, Cu, Fe, Mn, Ni, Pb, V and Zn. A total of 22 international reference materials of rocks, soils, minerals, ores and sediments were employed to construct nine calibration curves, all of which depict linear correlation of concentration-intensity, with correlation coefficients of 0.9 or better. The accuracy of determination is implied from the relative differences between the observed and suggested values in four reference materials: USGS SCO-1, shale; CCRMP SO-1, soil; CCRMP CO-2, soil; and SARM 42, soil. The determinations of four elements are considered as accurate, with relative errors of smaller than 10%; they are Fe (5%), Mn (6%), Cr (8%), and Cu (9%). Only a moderate accuracy has been achieved in the determinations of Ba (13%), Zn (18%) and V (21 %). Ni and Ph results are associated with larger errors. The developed technique is considered rapid, whereby nine elements in 30 samples in the form of pressed powder briquettes can be analysed in 8 hours. Without extrapolating the calibration curves, the method is suitable to analyse elements in soils and sediments in the following ranges of concentrations: Ba, 0-1500 ppm; Cr, 0-3000 ppm; Cu, 0-300 ppm; Fe, 0.7%; Mn, 0-1000 ppm; Ni, 0-300 ppm; Pb, 0-70 ppm; V, 0-300 ppm and Zn, 0-270 ppm

  3. Gastrointestinal parasites of cats in Denmark assessed by necropsy and concentration McMaster technique.

    Science.gov (United States)

    Takeuchi-Storm, N; Mejer, H; Al-Sabi, M N S; Olsen, C S; Thamsborg, S M; Enemark, H L

    2015-12-15

    The large population of feral cats in Denmark may potentially transmit pathogens to household cats and zoonotic parasites to humans. A total of 99 euthanized cats; feral cats (n=92) and household cats with outdoor access (n=7), were collected from March to May 2014 from the Zealand region, Denmark. The sedimentation and counting technique (SCT) was used to isolate helminths and coproscopy was done by concentration McMaster technique (c-McMaster). Overall, 90.1% of the cats were infected and a total of 10 species were recorded by SCT: 5 nematode species: Toxocara cati (84.8%), Ollulanus tricuspis (13.1%), Aonchotheca putorii (7.1%), Paersonema spp. (3.0%), Strongyloides spp. (1.0%); 3 cestodes: Hydatigera taeniaeformis (36.4%), Mesocestoides sp. (3.0%), Dipylidium caninum (1.0%); and 2 trematodes: Cryptocotyle spp. (5.1%) and Pseudamphistomum truncatum (1.0%). O. tricuspis was the second most common gastrointestinal nematode of cats but had the highest intensity of infection. For T. cati, prevalence and worm burden were significantly higher in feral than household cats. No juvenile cats were infected with H. taeniaeformis, and age thus had a significant effect on prevalence and worm burdens of this species. Rural cats had a higher prevalence and worm burden of A. putorii than urban cats. By c-McMaster, ascarid, capillarid, strongylid or taeniid type eggs were found in 77.9% of the cats while Cystoisospora felis was found in 2.1%. The sensitivity of the c-McMaster was 82.5% for T. cati but 26.5% for taeniid eggs, using the SCT as gold standard. A positive correlation between faecal egg counts and worm burdens was seen for T. cati, but not for taeniid eggs (assumed to be H. taeniaeformis). Coprological examination also detected the eggs of extraintestinal Capillariidae species including Eucoleus aerophilus and Eucoleus boehmi, but further necropsy studies are needed to confirm these findings. Copyright © 2015 Elsevier B.V. All rights reserved.

  4. Stress Concentration and Its Mitigation Techniques in Flat Plate with Singularities - A Critical Review

    Directory of Open Access Journals (Sweden)

    Shubhashish Sanyal

    2012-01-01

    Full Text Available A number of analytical, numerical & experimental techniques are available for the reduction of stress concentration factor around discontinuities. Using various techniques the SCF around different discontinuities in a rectangular plate made up of different materials under different loading conditions have been reported in literature. Mitigation of stress concentration around different types of discontinuity is also reported in literature. This paper is to present an analysis and overview of emerging techniques developed for analysis as well as mitigation of stress concentration. The proposed methods in literature are compared.

  5. Evaluating Spatial Variability in Sediment and Phosphorus Concentration-Discharge Relationships Using Bayesian Inference and Self-Organizing Maps

    Science.gov (United States)

    Underwood, Kristen L.; Rizzo, Donna M.; Schroth, Andrew W.; Dewoolkar, Mandar M.

    2017-12-01

    Given the variable biogeochemical, physical, and hydrological processes driving fluvial sediment and nutrient export, the water science and management communities need data-driven methods to identify regions prone to production and transport under variable hydrometeorological conditions. We use Bayesian analysis to segment concentration-discharge linear regression models for total suspended solids (TSS) and particulate and dissolved phosphorus (PP, DP) using 22 years of monitoring data from 18 Lake Champlain watersheds. Bayesian inference was leveraged to estimate segmented regression model parameters and identify threshold position. The identified threshold positions demonstrated a considerable range below and above the median discharge—which has been used previously as the default breakpoint in segmented regression models to discern differences between pre and post-threshold export regimes. We then applied a Self-Organizing Map (SOM), which partitioned the watersheds into clusters of TSS, PP, and DP export regimes using watershed characteristics, as well as Bayesian regression intercepts and slopes. A SOM defined two clusters of high-flux basins, one where PP flux was predominantly episodic and hydrologically driven; and another in which the sediment and nutrient sourcing and mobilization were more bimodal, resulting from both hydrologic processes at post-threshold discharges and reactive processes (e.g., nutrient cycling or lateral/vertical exchanges of fine sediment) at prethreshold discharges. A separate DP SOM defined two high-flux clusters exhibiting a bimodal concentration-discharge response, but driven by differing land use. Our novel framework shows promise as a tool with broad management application that provides insights into landscape drivers of riverine solute and sediment export.

  6. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments. Final report

    International Nuclear Information System (INIS)

    Lloyd, Jonathan R.

    2009-01-01

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low 99 Tc) and Area 3 (pH 3.5, high nitrate, relatively high 99 Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with 99 Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate 99 Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter 99m Tc (50-200 MBq; half life 6 hours) and its

  7. Novel imaging techniques, integrated with mineralogical, geochemical and microbiological characterizations to determine the biogeochemical controls on technetium mobility in FRC sediments

    Energy Technology Data Exchange (ETDEWEB)

    Jonathan R. Lloyd

    2009-02-03

    The objective of this research program was to take a highly multidisciplinary approach to define the biogeochemical factors that control technetium (Tc) mobility in FRC sediments. The aim was to use batch and column studies to probe the biogeochemical conditions that control the mobility of Tc at the FRC. Background sediment samples from Area 2 (pH 6.5, low nitrate, low {sup 99}Tc) and Area 3 (pH 3.5, high nitrate, relatively high {sup 99}Tc) of the FRC were selected (http://www.esd.ornl.gov/nabirfrc). For the batch experiments, sediments were mixed with simulated groundwater, modeled on chemical constituents of FRC waters and supplemented with {sup 99}Tc(VII), both with and without added electron donor (acetate). The solubility of the Tc was monitored, alongside other biogeochemical markers (nitrate, nitrite, Fe(II), sulfate, acetate, pH, Eh) as the 'microcosms' aged. At key points, the microbial communities were also profiled using both cultivation-dependent and molecular techniques, and results correlated with the geochemical conditions in the sediments. The mineral phases present in the sediments were also characterized, and the solid phase associations of the Tc determined using sequential extraction and synchrotron techniques. In addition to the batch sediment experiments, where discrete microbial communities with the potential to reduce and precipitate {sup 99}Tc will be separated in time, we also developed column experiments where biogeochemical processes were spatially separated. Experiments were conducted both with and without amendments proposed to stimulate radionuclide immobilization (e.g. the addition of acetate as an electron donor for metal reduction), and were also planned with and without competing anions at high concentration (e.g. nitrate, with columns containing Area 3 sediments). When the columns had stabilized, as determined by chemical analysis of the effluents, we used a spike of the short-lived gamma emitter {sup 99m}Tc (50

  8. Exploring the uncertainty in attributing sediment contributions in fingerprinting studies due to uncertainty in determining element concentrations in source areas.

    Science.gov (United States)

    Gomez, Jose Alfonso; Owens, Phillip N.; Koiter, Alex J.; Lobb, David

    2016-04-01

    One of the major sources of uncertainty in attributing sediment sources in fingerprinting studies is the uncertainty in determining the concentrations of the elements used in the mixing model due to the variability of the concentrations of these elements in the source materials (e.g., Kraushaar et al., 2015). The uncertainty in determining the "true" concentration of a given element in each one of the source areas depends on several factors, among them the spatial variability of that element, the sampling procedure and sampling density. Researchers have limited control over these factors, and usually sampling density tends to be sparse, limited by time and the resources available. Monte Carlo analysis has been used regularly in fingerprinting studies to explore the probable solutions within the measured variability of the elements in the source areas, providing an appraisal of the probability of the different solutions (e.g., Collins et al., 2012). This problem can be considered analogous to the propagation of uncertainty in hydrologic models due to uncertainty in the determination of the values of the model parameters, and there are many examples of Monte Carlo analysis of this uncertainty (e.g., Freeze, 1980; Gómez et al., 2001). Some of these model analyses rely on the simulation of "virtual" situations that were calibrated from parameter values found in the literature, with the purpose of providing insight about the response of the model to different configurations of input parameters. This approach - evaluating the answer for a "virtual" problem whose solution could be known in advance - might be useful in evaluating the propagation of uncertainty in mixing models in sediment fingerprinting studies. In this communication, we present the preliminary results of an on-going study evaluating the effect of variability of element concentrations in source materials, sampling density, and the number of elements included in the mixing models. For this study a virtual

  9. Monitoring the effectiveness of remediation techniques using sediment toxicity tests with the amphipod Eohaustorius estuarius

    International Nuclear Information System (INIS)

    Doe, K.G.; Jackman, P.M.; Lee, K.

    2002-01-01

    The results of a controlled oil release experiment of weathered crude oil was presented. The released oil was applied to a tidal saltwater marsh at Conrod's Beach, Nova Scotia, Canada. The study included 3 replicate blocks which included 2 unoiled treatments and 4 oiled treatments for each block. One unoiled site had no treatment, the second unoiled site had nutrient addition to examine the effect of nutrients. The oiled treatments included natural attenuation, nutrient addition, nutrient addition with plants, and nutrient addition with a garden aerator to introduce oxygen. A standard lab procedure was used to analyze the sediments to determine the effectiveness of the technique as well as the toxic effects on the survival of the amphipod Eohaustorius estuarius. Test results indicated that the unoiled sites were non-toxic, with a slight decrease in survival in the treatment with nutrient addition. All the oiled sites were very toxic at first, but toxicity decreased gradually with time. Treatment with nutrient addition with a garden aerator proved to be the most complete and fastest detoxification method. 8 refs., 4 tabs., 2 figs

  10. Metal concentrations of river water and sediments in West Java, Indonesia.

    Science.gov (United States)

    Yasuda, Masaomi; Yustiawati; Syawal, M Suhaemi; Sikder, Md Tajuddin; Hosokawa, Toshiyuki; Saito, Takeshi; Tanaka, Shunitz; Kurasaki, Masaaki

    2011-12-01

    To determine the water environment and pollutants in West Java, the contents of metals and general water quality of the Ciliwung River in the Jakarta area were measured. High Escherichia coli number (116-149/mL) was detected downstream in the Ciliwung River. In addition to evaluate mercury pollution caused by gold mining, mercury contents of water and sediment samples from the Cikaniki River, and from paddy samples were determined. The water was not badly polluted. However, toxic metals such as mercury were detected at levels close to the baseline environmental standard of Indonesia (0.83-1.07 μg/g of sediments in the Cikaniki River). From analyses of the paddy samples (0.08 μg/g), it is considered that there is a health risk caused by mercury.

  11. Age of a prehistoric "Rodedian" cult site constrained by sediment and rock surface luminescence dating techniques

    DEFF Research Database (Denmark)

    Sohbati, Reza; Murray, Andrew; Porat, N.

    2015-01-01

    The construction age of a pavement in a “Rodedian” prehistoric cult site in Negev desert, Israel, is established by determining the burial age of (i) a cobble used in the pavement, and (ii) the underlying sediment. The quartz OSL age and the K-feldspar corrected IR50 age from the sediment...

  12. Ripening of clayey dredged sediments during temporary upland disposal, A Bioremediation technique.

    NARCIS (Netherlands)

    Vermeulen, J.; Grotenhuis, J.T.C.; Joziasse, J.; Rulkens, W.H.

    2003-01-01

    Background and Goal. In the Netherlands about 40 million m3 of sediment has to be dredged annually for both maintenance and environmental reasons. Temporary upland disposal is the most widely adopted alternative for dredged sediments worldwide. For good management of temporary disposal sites,

  13. The geostatistics of the metal concentrations in sediments from the eastern Brazilian continental shelf in areas of gas and oil production

    Science.gov (United States)

    Aguiar, Jose Edvar; de Lacerda, Luiz Drude; Miguens, Flavio Costa; Marins, Rozane Valente

    2014-04-01

    Geostatistical techniques were used to evaluate the differences in the geochemistry of metals in the marine sediments along the Eastern Brazilian continental margin along the states of Ceará and Rio Grande do Norte (Northeastern sector) and Espírito Santo (Southeastern sector). The concentrations of Al, Fe, Mn, Ba, Cd, Cu, Cr, Ni, Pb, V, Hg, and Zn were obtained from acid digestion and quantified using flame atomic absorption spectrometry (AAS), inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma atomic emission spectrometry (ICP-AES). The metals showed a similar order of concentration: Al > Fe > Ba > Mn > V > Ni > Pb > Cr > Zn > Cu, in both the Ceará; and Rio Grande do Norte shelf regions but different in the Espírito Santo shelf (Fe > Al > Mn > Ba > Zn > V > Cr > Ni > Pb > Cu. The concentrations of Hg and Cd were below the detection limit in all areas. A multivariate analysis revealed that the metals of siliciclastic origin on the continental shelf of Ceará are carried by Al. In addition, a large portion of metal deposits is connected to the iron and manganese oxides on the continental margin of Rio Grande do Norte. The metals from the continental supply on the coast of Espírito Santo (Cu, Ni, Ba, and Mn) are associated with Al; whereas Cr, Pb, V, and Zn are associated with iron in this southern area. Geochemical evaluations are needed to distinguish the origin and mineralogical differences of marine sediments within the regions. Scanning electron microscopy/energy dispersive spectrometry (SEM/EDS) applied to the sediments from the coast of Ceará showed the morphological diversity of sediment grains: biological fragments, multifaceted particles, aggregates, and crystals occurred in the three regions analyzed. Among these grains, calcite, Mg-calcite, and aragonite were predominant in the northeastern sector, whereas silicates and other minerals were predominant the southeastern sector. Mg, K, Ti, and Zr as well as the

  14. SIMPLE METHOD FOR ESTIMATING POLYCHLORINATED BIPHENYL CONCENTRATIONS ON SOILS AND SEDIMENTS USING SUBCRITICAL WATER EXTRACTION COUPLED WITH SOLID-PHASE MICROEXTRACTION. (R825368)

    Science.gov (United States)

    A rapid method for estimating polychlorinated biphenyl (PCB) concentrations in contaminated soils and sediments has been developed by coupling static subcritical water extraction with solid-phase microextraction (SPME). Soil, water, and internal standards are placed in a seale...

  15. 226Ra concentrations in crayfish tissues, water, and sediments from the Serpent River Basin in Northeastern Ontario, Canada

    International Nuclear Information System (INIS)

    Alikhan, M.A.

    1996-01-01

    Lower Serpent River, as well as Elliot, McCarthy and McCabe lakes had highest 226 Ra contamination, Chrisman, Quirke and Whiskey lakes a moderate one, Flack and Semiwhite lakes and the 'distant' control, Lake Wanapitei, the lowest. 226 Ra activity in Cambarus robustus tissues was directly related to their background levels. Thus, concentration coefficient (tissue/sediment concentrations) for 226 Ra ranged from 0.53 to 0.74 in highly contaminated Elliot and McCarthy lakes, 0.28 to 0.59 in moderately contaminated Quirke and Whiskey lakes, and from 0.27 to 3.44 in least contaminated Semiwhite and Flack lakes. Among various organs analysed, exoskeleton showed the highest (43.04 - 90.69%) and the tail muscles the lowest (2.95 -17.14%) 226 Ra activity. 226 Ra concentrations in the alimentary canal were considered a part of the ambient environment as they had not been absorbed

  16. Erosion and sediment deposition evaluation on a slope under pasture in Jandaia-GO using the '137Cs fallout' technique

    International Nuclear Information System (INIS)

    Arthur, Robson C.J.; Bacchi, Osny O.S.; Reichardt, Klaus; Oliveira, Carloeme Alves de; Correchel, Vladia

    2009-01-01

    Water erosion is one of the main forms of soil degradation and among the diverse factors that affect it, two of great importance are the soil cover and slope. Estimates of sediment distribution rates associated to the different uses and soil management practices are scarce and the employed methods in these determinations are in general costly and time consuming. Rates of sediment redistribution evaluated by means of the 137 Cs technique are based on the comparison of inventories of individual points of a given position and an inventory of reference, whose value represents the amount of 137 Cs of 'fallout' origin that was added to the local site. This allows evaluating situations of losses and accumulations of sediments by the erosive process. The objective of the present work was to analyze the sediment production in a pasture area and to measure the efficiency of riparian forests in trapping the erosion sediments coming from pasture, through the ' 137 Cs fallout' redistribution analysis. The study was carried out in Jandaia/GO, Brazil, in two dowslope transects located in a pasture area. Samples were taken from seven points of two 140 m long transects, as well as from three soil profiles of a 15 m transect in the downstream riparian forests of each transect. Soil profiles were sampled in three layers of 20 cm (0-20, 20-40 and 40-60). The soil samples were air dried, sieved and then analyzed for 137 Cs activity by a gamma ray detector (GEM-20180P, EG and ORTEC) coupled to a multichannel analyzer at CENA/USP. The results indicate variations of 137 Cs activity in soil profiles and high erosion rates to the riparian forest to the pasture areas of the two transects, showing sediment movement from the pasture area to the riparian forest, which suggests that the current width of the forest is not wide enough to trap the sediments produced upslope in the pasture area. (author)

  17. Comparison of methods for conducting marine and estuarine sediment porewater toxicity tests—extraction, storage, and handling techniques

    Science.gov (United States)

    Carr, R.S.; Chapman, D.C.

    1995-01-01

    A series of studies was conducted to compare different porewater extraction techniques and to evaluate the effects of sediment and porewater storage conditions on the toxicity of pore water, using assays with the sea urchin Arbacia punctulata. If care is taken in the selection of materials, several different porewater extraction techniques (pressurized squeezing, centrifugation, vacuum) yield samples with similar toxicity. Where the primary contaminants of concern are highly hydrophobic organic compounds, centrifugation is the method of choice for minimizing the loss of contaminants during the extraction procedure. No difference was found in the toxicity of pore water obtained with the Teflon® and polyvinyl chloride pressurized extraction devices. Different types of filters in the squeeze extraction devices apparently adsorbed soluble contaminants to varying degrees. The amount of fine suspended particulate material remaining in the pore water after the initial extraction varied among the methods. For most of the sediments tested, freezing and thawing did not affect the toxicity of porewater samples obtained by the pressurized squeeze extraction method. Pore water obtained by other methods (centrifugation, vacuum) and frozen without additional removal of suspended particulates by centrifugation may exhibit increased toxicity compared with the unfrozen sample.The toxicity of pore water extracted from refrigerated (4°C) sediments exhibited substantial short-term (days, weeks) changes. Similarly, sediment pore water extracted over time from a simulated amphipod solid-phase toxicity test changed substantially in toxicity. For the sediments tested, the direction and magnitude of change in toxicity of pore water extracted from both refrigerated and solid-phase test sediments was unpredictable.

  18. Analysis of antibody aggregate content at extremely high concentrations using sedimentation velocity with a novel interference optics.

    Science.gov (United States)

    Schilling, Kristian; Krause, Frank

    2015-01-01

    Monoclonal antibodies represent the most important group of protein-based biopharmaceuticals. During formulation, manufacturing, or storage, antibodies may suffer post-translational modifications altering their physical and chemical properties. Such induced conformational changes may lead to the formation of aggregates, which can not only reduce their efficiency but also be immunogenic. Therefore, it is essential to monitor the amount of size variants to ensure consistency and quality of pharmaceutical antibodies. In many cases, antibodies are formulated at very high concentrations > 50 g/L, mostly along with high amounts of sugar-based excipients. As a consequence, all routine aggregation analysis methods, such as size-exclusion chromatography, cannot monitor the size distribution at those original conditions, but only after dilution and usually under completely different solvent conditions. In contrast, sedimentation velocity (SV) allows to analyze samples directly in the product formulation, both with limited sample-matrix interactions and minimal dilution. One prerequisite for the analysis of highly concentrated samples is the detection of steep concentration gradients with sufficient resolution: Commercially available ultracentrifuges are not able to resolve such steep interference profiles. With the development of our Advanced Interference Detection Array (AIDA), it has become possible to register interferograms of solutions as highly concentrated as 150 g/L. The other major difficulty encountered at high protein concentrations is the pronounced non-ideal sedimentation behavior resulting from repulsive intermolecular interactions, for which a comprehensive theoretical modelling has not yet been achieved. Here, we report the first SV analysis of highly concentrated antibodies up to 147 g/L employing the unique AIDA ultracentrifuge. By developing a consistent experimental design and data fit approach, we were able to provide a reliable estimation of the minimum

  19. Determination Of Natural Boron Concentration In Coffee Leaves, Using de Autobiography by Neutron Capture Technique

    International Nuclear Information System (INIS)

    Loria, L. G.; Jimenez, R.; Thellier, M.

    1999-01-01

    Determination of natural boron concentration in coffee leaves, using the autoradiography, by neutron capture technique. The boron absorption coefficient in young coffee leaves was measured using autoradiography by neutron capture. In two experiments carried out in April and November, 1996, it was found that the coefficient varies between 0.9 and 5.3 nmol/h. the concentration of natural boron in coffee leaves in regard to age, symptoms and treatment received was also studied, using the same technique. (Author) [es

  20. Distribution and concentration evaluation of trace and rare earth elements in sediment samples of the Billings and Guarapiranga reservoir systems

    Energy Technology Data Exchange (ETDEWEB)

    Silva, Larissa S.; Fávaro, Déborah I.T., E-mail: defavaro@ipen.br [Instituto de Pesquisas Energéticas e Nucleares (LAN-CRPq/IPEN/CNEN-SP), São Paulo(Brazil). Lab. de Análise por Ativação Neutrônica; Ferreira, Francisco J. [Companhia Ambiental do Estado de São Paulo (ELAI/CETESB), Sao Paulo, SP (Brazil). Setor de Química Inorgânica

    2017-07-01

    Concentration and distribution of trace and rare earth elements in bottom sediment samples collected in the Billings System (including Rio Grande and Guarapiranga Reservoirs) were assessed by using Instrumental Neutron Activation (INAA). To evaluate the sources of anthropogenic contamination the enrichment factor (FE) and the geoacumulation index (IGeo) were calculated using NASC and Guarapiranga Park Soil as Reference Values. Results were compared to the concentration guideline values established by CCME (Canadian Council of Ministers of the Environment) environmental agency for As, Cr and Zn, and values in other published studies. Most points exceeded TEL values and, in some points, PEL values for these elements, indicating poor sediment quality in these reservoirs. In general terms, the elements As, Cr, Sb and Zn through EF and IGeo calculations present enrichment at all points analyzed, in both collection campaigns, except for the Rio Grande Reservoir points. The region where the reservoirs are located receive untreated sewage as well as pollution from urban occupation, industrial and mining activities, making it difficult to accurately identify the pollution sources. This study found higher concentrations of the elements analyzed in the Billings Reservoir, indicating a greater contamination level in relation to the other reservoirs. (author)

  1. Distribution and concentration evaluation of trace and rare earth elements in sediment samples of the Billings and Guarapiranga reservoir systems

    International Nuclear Information System (INIS)

    Silva, Larissa S.; Fávaro, Déborah I.T.; Ferreira, Francisco J.

    2017-01-01

    Concentration and distribution of trace and rare earth elements in bottom sediment samples collected in the Billings System (including Rio Grande and Guarapiranga Reservoirs) were assessed by using Instrumental Neutron Activation (INAA). To evaluate the sources of anthropogenic contamination the enrichment factor (FE) and the geoacumulation index (IGeo) were calculated using NASC and Guarapiranga Park Soil as Reference Values. Results were compared to the concentration guideline values established by CCME (Canadian Council of Ministers of the Environment) environmental agency for As, Cr and Zn, and values in other published studies. Most points exceeded TEL values and, in some points, PEL values for these elements, indicating poor sediment quality in these reservoirs. In general terms, the elements As, Cr, Sb and Zn through EF and IGeo calculations present enrichment at all points analyzed, in both collection campaigns, except for the Rio Grande Reservoir points. The region where the reservoirs are located receive untreated sewage as well as pollution from urban occupation, industrial and mining activities, making it difficult to accurately identify the pollution sources. This study found higher concentrations of the elements analyzed in the Billings Reservoir, indicating a greater contamination level in relation to the other reservoirs. (author)

  2. Use of pre-industrial floodplain lake sediments to establish baseline river metal concentrations downstream of Alberta oil sands: a new approach for detecting pollution of rivers

    International Nuclear Information System (INIS)

    Wiklund, Johan A; Hall, Roland I; Farwell, Andrea J; George Dixon, D; Wolfe, Brent B; Edwards, Thomas WD

    2014-01-01

    In the Alberta oil sands region, insufficient knowledge of pre-disturbance reference conditions has undermined the ability of the Regional Aquatics Monitoring Program (RAMP) to detect pollution of the Athabasca River, because sampling began three decades after the industry started and the river naturally erodes oil-bearing strata. Here, we apply a novel approach to characterize pre-industrial reference metal concentrations in river sediment downstream of Alberta oil sands development by analyzing metal concentrations in sediments deposited in floodplain lakes of the Athabasca Delta during 1700–1916, when they were strongly influenced by Athabasca River floodwaters. We compared results to metal concentrations in surficial bottom sediments sampled by RAMP (2010–2013) at downstream sites of the Athabasca River and distributaries. When normalized to lithium content, concentrations of vanadium (a metal of concern in the oil sands region) and other priority pollutants (Be, Cd, Cr, Cu, Pb, Ni, Zn) in nearly all of the RAMP river sediment samples lie below the upper 95% prediction interval linearly extrapolated from the river-derived lake sediments. Assuming the RAMP protocols obtained recently deposited sediment, this indicates that the metal concentrations in downstream Athabasca River sediment have not increased above pre-disturbance levels. Reference conditions derived from the lake sediment data were used to develop profiles of metal residual concentrations versus time for the RAMP river sediment data, which provides an excellent tool for decision-makers to identify and quantify levels of metal pollution for any given sample, and to monitor for future trends. We recommend that the approach be applied to resurrect the utility of RAMP data at other river sampling locations closer to the development, and for ongoing risk assessment. The approach is also readily transferable to other rivers where insufficient pre-disturbance reference data impairs an ability to

  3. Elemental concentration and potential ecological risk assessment of reef associated surface sediments of Appa Island, Gulf of Mannar Biosphere Reserve, Southeast coast of India.

    Science.gov (United States)

    Saravanan, P; Krishnakumar, S; Silva, Judith D; Pradhap, D; Vidyasakar, A; Radhakrishnan, K; Godson, Prince S; Arumugam, K; Magesh, N S

    2018-03-01

    Thirty three surface sediments were collected for the present study to assess the elemental concentration and its associated ecological risk in the reef associated surface sediments, Appa Island, Gulf of Mannar Biosphere Reserve, South east coast of India. The distribution of calcium carbonate in the reef sediments is controlled by coral debris and shell fragments whereas the Organic matter (OM) content are chiefly derived from mangroves and sea grasses. The circulation of trace elements and Fe, Mn are controlled by the fluvial process and re-suspended sediments. The concentration of Pb was primarily controlled by migration of pollutants through long shore sediment transport process. The main source of Pb in the study area is from coal incinerating power plants and coal handling operations from harbors. Copyright © 2018 Elsevier Ltd. All rights reserved.

  4. Improving the reliability of open-cycle water systems: Application of biofouling surveillance and control techniques to sediment and corrosion fouling at nuclear power plants

    International Nuclear Information System (INIS)

    Johnson, K.I.; Neitzel, D.A.

    1987-03-01

    Biofouling surveillance and control techniques are evaluated for their applicability to sediment and corrosion fouling and suggestions are given to improve their effectiveness. Alternate techniques to better detect and control sedimentation and corrosion are also evaluated. Environmental conditions that allow biofouling, sedimentation, and corrosion to occur are summarized. A correlation between sediment and corrosion is identified and the causes are described. Environmental regulations, especially those in the Clean Water Act of 1977, are reviewed to identify those that may limit or prevent the use of surveillance and control techniques described in this report. Flow velocity is the major design factor that determines whether or not biofouling, sedimentation, and corrosion will occur. Monitoring flow conditions can provide early warning of conditions that will allow fouling to occur. Visual inspection is the most common and most effective technique for identifying the cause and extent of fouling in the open-cycle water system. Most biofouling control techniques in current use are not effective against sediment and corrosion. Frequent, high-velocity flushing of cooling loops may effectively remove sediment and reduce under-sediment corrosion. Alternate biocide treatments such as targeted chlorination or the use of ozone or 2,2-dibromo-3-nitrilo propionamide (DBNPA) may also be effective in reducing under-sediment corrosion

  5. A new XRF probe for in-situ determining concentration of multi-elements in ocean sediments

    CERN Document Server

    Ge Liang Quan; Zhou Si Chun; Lin Ling; Lin Yan Chang; Ren Jia Fu

    2001-01-01

    The author introduces a new X-ray fluorescence probe for in-situ determining the concentration of multi-elements in ocean sediments. The probe consists of Si-Pin X-ray detector with an electro-thermal colder, two isotope sources, essential electrical signal processing units and a notebook computer. More than 10 elements can be simultaneously determined at a detection limit of (10-200) x 10 sup - sup 6 and precision of 5%-30% without liquid Nitrogen supply. tests show that the probe can perform the analytical tasks under the water at the depth of less than 1000 meters

  6. A new XRF probe for in-situ determining concentration of multi-elements in ocean sediments

    International Nuclear Information System (INIS)

    Ge Liangquan; Lai Wanchang; Zhou Sichun; Lin Ling; Lin Yanchang; Ren Jiafu

    2001-01-01

    The author introduces a new X-ray fluorescence probe for in-situ determining the concentration of multi-elements in ocean sediments. The probe consists of Si-Pin X-ray detector with an electro-thermal colder, two isotope sources, essential electrical signal processing units and a notebook computer. More than 10 elements can be simultaneously determined at a detection limit of (10-200) x 10 -6 and precision of 5%-30% without liquid Nitrogen supply. tests show that the probe can perform the analytical tasks under the water at the depth of less than 1000 meters

  7. Characterization of heavy-metal-contaminated sediment by using unsupervised multivariate techniques and health risk assessment.

    Science.gov (United States)

    Wang, Yeuh-Bin; Liu, Chen-Wuing; Wang, Sheng-Wei

    2015-03-01

    This study characterized the sediment quality of the severely contaminated Erjen River in Taiwan by using multivariate analysis methods-including factor analysis (FA), self-organizing maps (SOMs), and positive matrix factorization (PMF)-and health risk assessment. The SOMs classified the dataset with similar heavy-metal-contaminated sediment into five groups. FA extracted three major factors-traditional electroplating and metal-surface processing factor, nontraditional heavy-metal-industry factor, and natural geological factor-which accounted for 80.8% of the variance. The SOMs and FA revealed the heavy-metal-contaminated-sediment hotspots in the middle and upper reaches of the major tributary in the dry season. The hazardous index value for health risk via ingestion was 0.302. PMF further qualified the source apportionment, indicating that traditional electroplating and metal-surface-processing industries comprised 47% of the health risk posed by heavy-metal-contaminated sediment. Contaminants discharged from traditional electroplating and metal-surface-processing industries in the middle and upper reaches of the major tributary must be eliminated first to improve the sediment quality in Erjen River. The proposed assessment framework for heavy-metal-contaminated sediment can be applied to contaminated-sediment river sites in other regions. Copyright © 2014 Elsevier Inc. All rights reserved.

  8. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Butte NTMS Quadrangle, Montana, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Broxton, D.E.; George, W.E.; Montoya, J.V.; Martell, C.J.; Hensley, W.K.; Hanks, D.

    1980-05-01

    This report contains data collected during a geochemical survey for uranium in the Butte National Topographic Map Series (NTMS) quadrangle of west-central Montana. Histograms and statistical data for uranium concentrations in water and sediment samples and thorium concentrations in sediment samples are given. Elemental concentration, field measurement, weather, geologic, and geographic data for each sample location are listed for waters and for sediments. Uranium/thorium ratios for sediment samples are also included. This report contains uranium analyses for water samples and multielement analyses for sediment samples. A supplemental report containing the results of multielement analyses of water samples will be open filed in the near future. Sediments were analyzed for uranium and thorium as well as aluminum, antimony, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chlorine, chromium, cobalt, copper, dysprosium, europium, gold, hafnium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, nickel, niobium, potassium, rubidium, samarium, scandium, silver, sodium, strontium, tantalum, terbium, tin, titanium, tungsten, vanadium, ytterbium, and zinc. All elemental analyses were performed at the LASL. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than 40 ppB uranium were reanalyzed by delayed-neutron counting (DNC). All sediments were analyzed for uranium by DNC. Other elemental concentrations in sediments were determined by neutron activation analysis for 31 elements, by x-ray fluorescence for 9 elements, and by arc-source emission spectrography for 2 elements. Analytical results for sediments are reported as parts per million. Descriptions of procedures used for analysis of water and sediment samples as well as analytical precisions and detection limits are given

  9. Technical note: False low turbidity readings from optical probes during high suspended-sediment concentrations

    OpenAIRE

    N. Voichick; D. J. Topping; R. E. Griffiths

    2018-01-01

    Turbidity, a measure of water clarity, is monitored for a variety of purposes including (1) to help determine whether water is safe to drink, (2) to establish background conditions of lakes and rivers and detect pollution caused by construction projects and stormwater discharge, (3) to study sediment transport in rivers and erosion in catchments, (4) to manage siltation of water reservoirs, and (5) to establish connections with aquatic biological properties, such as primary ...

  10. Metal concentrations in surface sediments of Paraiba do Sul River (Brazil)

    International Nuclear Information System (INIS)

    Pereira, M.O.; Calza, C.; Lopes, R.T.; Anjos, M.J.; UERJ, Rio de Janeiro; Araujo, F.G.

    2006-01-01

    The Paraiba do Sul River is located in a strategic region between the most important urban and industrial centers of Brazil. In the last years, an increase in the water pollution has been reported, caused by the untreated domestic sewerage of the inhabitants, effluents discharged by various industries, mining activities and sand extraction from the riverbed. This work used total reflection X-ray fluorescence with synchrotron radiation (SRTXRF) to determine metals in the bioavailable and residual fractions from the surface sediments. The metals identified were Ti, Cr, Mn, Fe, Cu, Zn, Rb, Sr, Ba and Pb. (author)

  11. [Concentrations and Distribution of Metals in the Core Sediments from Estuary and City Section of Liaohe River].

    Science.gov (United States)

    Wang, Wei-jie; Zhou, Jun-li; Pei, Shu-wei; Liu, Zheng-tao

    2016-01-15

    The particle size, total organic carbon (TOC), total nitrogen (TN), C/N ratio and metal concentrations as well as activities of 210Pb were determined in Liaohe River estuary area (LN-2) and Shenyang area (LN-5), and the organic matter resources were discussed in two core sediments. Also the index of geoaccumulation (Igeo) and enrichment factors (EFs) methods were applied to evaluate the state of heavy metal contamination in the studied sties. The study showed that both sediment cores LN-2 and LN-5 were dominated by silts, and the vertical variations of grain-size composition and organic matter were well distributed in LN- 2 while fluctuated in LN-5. According to the organic matter source analysis through C/N ratio, C/N ratio varied in the scale of 5. 24-7.93 in LN-2 which was dominated by river source, and 9.94-14.21 in LN-5 which was dominated by terrestrial input. Al, Ca, Fe, Mn, Ni, Cu, Zn, Cd, Pb and Cr in two sediment cores had different vertical changing rules, Ni and Zn in LN-2 as well as Pb and Zn in LN-5 were affected by both natural and human factors, other elements had similar distributions to those of organic matters, which showed that these elements were mainly affected by the natural activities. Based on Igeo and EFs, both sediment cores were more severely polluted with Ni, Zn and Pb than other metals. The effects of human activities on the environment were also discussed in this study, combined with the economical development of Liaoning Province and the studied sites in the past 20 years.

  12. Evaluation of the anthropogenic radionuclide concentrations in sediments and fauna collected in the Beaufort Sea and northern Alaska

    International Nuclear Information System (INIS)

    Efurd, D.W.; Miller, G.G.; Rokop, D.J.

    1997-07-01

    This study was performed to establish a quality controlled data set about the levels of radio nuclide activity in the environment and in selected biota in the U.S. Arctic. Sediment and biota samples were collected by the National Oceanic and Atmospheric Administration (NOAA), the National Biological Service, and the North Slope Borough's Department of Wildlife Management to determine the impact of anthropogenic radionuclides in the Arctic. The results summarized in this report are derived from samples collected in northwest Alaska with emphasis on species harvested for subsistence in Barrow, Alaska. Samples were analyzed for the anthropogenic radionuclides 90 Sr, 137 Cs, 238 Pu, 239 Pu, 240 Pu and 241 Am. The naturally occurring radionuclides 40 K, 212 Pb and 214 Pb were also measured. One goal of this study was to determine the amounts of anthropogenic radionuclides present in the Beaufort Sea. Sediment samples were isotopically fingerprinted to determine the sources of radio nuclide activities. Biota samples of subsistence and ecological value were analyzed to search for evidence of bio-accumulation of radionuclides and to determine the radiation exposures associated with subsistence living in northern Alaska. The anthropogenic radio nuclide content of sediments collected in the Beaufort Sea was predominantly the result of the deposition of global fallout. No other sources of anthropogenic radionuclides could be conclusively identified in the sediments. The anthropogenic radio nuclide concentrations in fish, birds and mammals were very low. Assuming that ingestion of food is an important pathway leading to human contact with radioactive contaminants and given the dietary patterns in coastal Arctic communities, it can be surmised that marine food chains are presently not significantly affected

  13. Importance of Dissolved Neutral Hg-Sulfides, Energy Rich Organic Matter and total Hg Concentrations for Methyl Mercury Production in Sediments

    Science.gov (United States)

    Drott, A.; Skyllberg, U.

    2007-12-01

    Methyl mercury (MeHg) is the mercury form that biomagnifies to the greatest extent in aquatic food webs. Therefore information about factors determining MeHg concentrations is critical for accurate risk assessment of contaminated environments. The concentration of MeHg in wetlands and sediments is the net result of: 1) methylation rates, 2) demethylation rates, and 3) input/output processes. In this study, the main controls on Hg methylation rates and total concentrations of MeHg, were investigated at eight sites in Sweden with sediments that had been subjected to local Hg contamination either as Hg(0), or as phenyl-Hg. Sediments were selected to represent a gradient in total Hg concentration, temperature climate, salinity, primary productivity, and organic C content and quality. Most sediments were high in organic matter content due to wood fibre efflux from pulp and paper industry. The pore water was analysed for total Hg, MeHg, DOC, H2S(aq), pH, DOC, Cl and Br. The chemical speciation of Hg(II) and MeHg in pore water was calculated using equilibrium models. Potential methylation and demethylation rates in sediments were determined in incubation experiments at 23° C under N2(g) for 48 h, after addition of isotopically enriched 201Hg(II) and Me204Hg. In all surface (0-20 cm) sediments there was a significant (pdetermined specific potential methylation rate constant (Km, day-1) and % MeHg (concentrations of MeHg normalized to total Hg) in the sediment. This indicates that MeHg production overruled degradation and input/output processes of MeHg in surface sediments, and that % MeHg in surface sediments may be used as a proxy for net production of MeHg. To our knowledge, these are the first data showing significant positive relationships between short term (48 h) MeHg production and longer term accumulation of MeHg, across a range of sites with different properties (1). If MeHg was not normalized to total Hg, the relationship was not significant. For sub-sets of

  14. The Role of Sedimentation on Waters Edge and Analysis Pb and Zn Concentration in Water from Sentani Lake, Jayapura-Papua

    Directory of Open Access Journals (Sweden)

    Frans Deminggus

    2015-05-01

    Full Text Available We have conducted research on the role of sediment on the waters edge and content analysis of metal concentrations of lead (Pb, zinc (Zn in the water of Sentani Lake in Jayapura, Papua Province. The experiment was conducted in April 2013. The study was conducted to determine the role of lake sediments on water quality, sediment characteristics and metal analysis has been analyzed in the laboratory to determine the concentration of Pb and Zn in the sediment. Metal analysis using Atomic Absorption Spectrophotometry (AAS instrumentation. Sediment characteristics that have analysis, namely physical and chemical parameters are bulk density, density, porosity, water content, texture, pH, DO, colors and others. Sediment sampling locations are Ifale, estuary, Yahim beach and Yoboy with each location in depth of 0-5 cm, 5-10 cm and 10-15 cm vertically. The results showed that at each sampling site and every sediment depths showed highly significant influence on the metal content of Pb and Zn. In general, the deeper the sediment content of Pb and Zn showed different results. Average content of heavy metals (Pb and Zn in sediments at each location that are Ifale at 27.37 mg/Kg and 35.04 mg/Kg, estuary of 15.37 mg/Kg and Pb is 28.01 mg/Kg, Yahim beach of 3.83 mg/Kg and 33.50 mg/Kg, while the location of Yoboy of 6.69 mg/Kg and 34.60 mg/Kg. Concentration of Pb (3.83 to 27.37 mg/Kg and Zn (6.69 to 35.04 mg/Kg in sediments is lower than the standard quality of heavy metals in sediments (EPA Region Va is 40 mg/Kg for Pb and 90 mg/Kg for Zn metals, therefore concentrations of Pb and Zn in sediments at four locations of Sentani lake is still below the quality standard so that the levels of Pb and Zn in the sediment is not contaminated. The existence of Sentani lake sediments act as a reservoir heavy metal and not as a source of pollutants to the water quality in the Sentani lake.

  15. Combining X-Ray Fluorescence and Magnetic Techniques to Quantify Elemental Concentrations in Coral Cores from Belize

    Science.gov (United States)

    Goldfarb, L. A.; Kingsley, C.; Urbalejo, A. A.; Hangsterfer, A.; Gee, J. S.; Carilli, J.; Feinberg, J. M.; Mitra, R.; Bhattacharya, A.; Field, D.

    2017-12-01

    Caribbean coral reefs are some of the most threatened marine ecosystems in the world. Research suggest that environmental stressors of local origin, such as sediment run off, can reduce the resilience of these reefs to global threats such as ocean warming. Material trapped in coral skeletons can provide information on the sources of particulate matter in the ocean ecosystem. Despite the importance of quantifying sources and types of materials trapped in corals, the research community is yet to fully develop techniques that allow accurate representation of trapped matter, which is potentially a major source of metal content in reef building coral skeletons. The dataset presented here is a progress and combination of two works presented at American Geophysical Union 2016 Fall Meeting; In this research, we explore the efficacy of X-Ray Fluorescence (XRF), a widely used tool in environmental studies (but generally not in corals), to estimate detrital metal content in coral cores collected from four locations near Belize, with varying degrees of impact from coastal processes. Four coral cores together cover a period of 1862-2006. Trace, major and minor metal content from these cores have been well-studied using solution-based ICP-MS, providing us with the unique opportunity to test the efficacy of XRF technique in characterizing metal content in these coral cores. We have measured more than 50 metals using XRF every two millimeters along slabs removed from the middle of a coral core spanning to characterize materials present in coral skeletons. We compare the results from XRF to elemental concentrations reported from solution-based ICP-MS. Furthermore, we also compare our XRF data to magnetic measurements we have made in these same coral cores. Overall, it appears that the non-destructive XRF technique is a viable supplement to the ICP-MS in determining sediment and metal content in coral cores, and may be particularly helpful for assessing resistant phases such as

  16. Bottom sediment transport by radioactive tracer techniques off a stretch of the southern coast from Sao Paulo State - Brazil

    International Nuclear Information System (INIS)

    Bomtempo, V.L.

    1995-01-01

    This paper presents the methodology and results obtained with radioactive tracer techniques as applied to study sea-bottom sediments movements off a stretch of the southern coast of Sao Paulo State, Brazil, namely Praia do Una. Three injections of ground glass containing Iridium-192 were made and the behaviour of this material was tracked by special detection techniques, as it was acted upon by hydrodynamic agents, in two distinct periods of the year of 1982 (summer and winter). Measurement of hydrodynamic parameters was conducted simultaneously with tracer experiments. From the experiments with radioactive tracers, combined with other conventional studies, qualitative and quantitative conclusions could be drawn, as follows: waves are the prevailing agents in moving bottom sediments; during summer time, onshore and alongshore transport can be identified; during winter time, offshore and alongshore transport are present; for summer conditions, Massif transport rate was estimated to be 150 kg m -1 day -1 . (author). 2 refs, 3 figs

  17. Wave-induced Maintenance of Suspended Sediment Concentration during Slack in a Tidal Channel on a Sheltered Macro-tidal Flat, Gangwha Island, Korea

    Science.gov (United States)

    Lee, Guan-hong; Kang, KiRyong

    2018-05-01

    A field campaign was conducted to better understand the influence of wave action, in terms of turbulence and bed shear stress, on sediment resuspension and transport processes on a protected tidal flat. An H-frame was deployed in a tidal channel south of Gangwha Island for 6 tidal cycles during November 2006 with instrumentation including an Acoustic Doppler Velocimeter, an Acoustic Backscatter System, and an Optical Backscatter Sensor. During calm conditions, the current-induced shear was dominant and responsible for suspending sediments during the accelerating phases of flood and ebb. During the high-tide slack, both bed shear stress and suspended sediment concentration were reduced. The sediment flux was directed landward due to the scour-lag effect over a tidal cycle. On the other hand, when waves were stronger, the wave-induced turbulence appeared to keep sediments in suspension even during the high-tide slack, while the current-induced shear remained dominant during the accelerating phases of flood and ebb. The sediment flux under strong waves was directed offshore due to the sustained high suspended sediment concentration during the high-tide slack. Although strong waves can induce offshore sediment flux, infrequent events with strong waves are unlikely to alter the long-term accretion of the protected southern Gangwha tidal flats.

  18. Automatic classification techniques for type of sediment map from multibeam sonar data

    Science.gov (United States)

    Zakariya, R.; Abdullah, M. A.; Che Hasan, R.; Khalil, I.

    2018-02-01

    Sediment map can be important information for various applications such as oil drilling, environmental and pollution study. A study on sediment mapping was conducted at a natural reef (rock) in Pulau Payar using Sound Navigation and Ranging (SONAR) technology which is Multibeam Echosounder R2-Sonic. This study aims to determine sediment type by obtaining backscatter and bathymetry data from multibeam echosounder. Ground truth data were used to verify the classification produced. The method used to analyze ground truth samples consists of particle size analysis (PSA) and dry sieving methods. Different analysis being carried out due to different sizes of sediment sample obtained. The smaller size was analyzed using PSA with the brand CILAS while bigger size sediment was analyzed using sieve. For multibeam, data acquisition includes backscatter strength and bathymetry data were processed using QINSy, Qimera, and ArcGIS. This study shows the capability of multibeam data to differentiate the four types of sediments which are i) very coarse sand, ii) coarse sand, iii) very coarse silt and coarse silt. The accuracy was reported as 92.31% overall accuracy and 0.88 kappa coefficient.

  19. Using X-Ray Fluorescence Technique to Quantify Metal Concentration in Coral Cores from Belize

    Science.gov (United States)

    Kingsley, C.; Bhattacharya, A.; Hangsterfer, A.; Carilli, J.; Field, D. B.

    2016-12-01

    Caribbean coral reefs are some of the most threatened marine ecosystems in the world. Research appears to suggest that environmental stressors of local origin, such as sediment run off, can reduce the resilience of these reefs to global threats such as ocean warming. Sedimentation can stunt coral growth, reduce its resilience, and it is possible that trapped material could render coral skeletons brittle (personal discussions). Material trapped in coral skeletons can provide information on the sources of particulate matter in the ocean ecosystem. Despite the importance of quantifying sources and types of materials trapped in corals, the research community is yet to fully develop techniques that allow accurate representation of trapped matter, which is potentially a major source of metal content in reef building coral skeletons. The dataset presented here explores the usefulness of X-Ray Fluorescence (XRF), a widely used tool in environmental studies (but generally not in corals), to estimate metal content in coral cores collected from four locations near Belize, with varying degrees of impact from coastal processes. The coral cores together cover a period of 1862-2006. Trace, major, and minor metal content from these cores have been well-studied using solution-based ICP-MS, providing us with the unique opportunity to test the efficacy of XRF technique in characterizing metal content in these coral cores. We have measured more than 50 metals using XRF every two millimeters along slabs removed from the middle of a coral core to characterize materials present in coral skeletons. We compared the results from XRF to solution-based ICP-MS - that involves dissolving subsamples of coral skeleton to measure metal content. Overall, it appears that the non-destructive XRF technique is a viable supplement in determining sediment and metal content in coral cores, and may be particularly helpful for assessing resistant phases such as grains of sediment that are not fully

  20. Activity concentrations of primordial radionuclides in sediments of surface - water dams in southwest Nigeria - a baseline survey

    International Nuclear Information System (INIS)

    Isinkaye, M.O.; Farai, I.P.

    2008-01-01

    The radionuclide contents of sediment samples collected from 20 surface-water dams in southwestern Nigeria have been determined by low-level gamma-spectroscopy. The average concentration of 40 K in each of the dams varied between 110.9±11.9 Bq kg-1 and 1025.9±36.8 Bq kg -1 with an overall mean (±SD) of 549.3 ± 247.6 Bq kg -1 while that of 238 U varied from 17.1±3.6 to 51.9±8.7 Bq kg -1 with an overall mean (±SD) of 27.6±8.5 Bq kg -1 and that of 232 Th varied from 26.2 ±3.6 Bq kg -1 to 130.1±23.7 Bq kg -1 with overall mean (±SD) of 62.0±26.1 Bq kg -1 . The variability of the values shows the wide disparity in the measured activity concentrations. The mean radium equivalent of 158.9 Bq kg -1 was calculated for the sediments in the dams. No artificial gamma emitting radionuclide was detected in the samples. (authors)

  1. Spatiotemporal trend analysis of metal concentrations in sediments of a residential California stream with toxicity and regulatory implications.

    Science.gov (United States)

    Hall, Lenwood W; Anderson, Ronald D; Killen, William D

    2017-06-07

    The objective of this study was to determine if concentrations of arsenic, cadmium, chromium, copper, lead, nickel and zinc measured in the sediments of a residential stream in California (Pleasant Grove Creek) have changed temporally or spatially from 2006 to 2016. Threshold Effect Levels (TELs), conservative ecological effects benchmarks, and exceedances for the seven metals were also evaluated over the 11-year time period to provide insight into potential metal toxicity to resident benthic communities. In addition, the bioavailability of metals in sediments was also determined by calculating Simultaneous Extracted Metal/Acid Volatle Sulfide (SEM/AVS) ratios to allow an additional assessment of toxicity. Regulatory implications of this data set and the role of metal toxicity are also discussed. Stream-wide temporal trend analysis showed no statistically significant trends for any of the metals. However, spatial analysis for several sites located near storm drains did show a significant increase for most metals over the 11-year period. TEL exceedances during the 7 years of sampling, spanning 2006-2016, were reported for all metals with the number of exceedances ranging from 47 for copper and zinc to 1 for lead. A spatial analysis showed that the highest number of TEL exceedances and the highest number of SEM/AVS ratios greater than one with at least one metal exceeding a TEL occurred at upstream sites. The potentially toxic metal concentrations reported in Pleasant Grove Creek should be used in the 303 (d) listing process for impaired water bodies in California.

  2. A new estimate of detrital redox-sensitive metal concentrations and variability in fluxes to marine sediments

    Science.gov (United States)

    Cole, Devon B.; Zhang, Shuang; Planavsky, Noah J.

    2017-10-01

    The enrichment and depletion of redox sensitive trace metals in marine sediments have been used extensively as paleoredox proxies. The trace metals in shale are comprised of both detrital (transported or particulate) and authigenic (precipitated, redox-driven) constituents, potentially complicating the use of this suite of proxies. Untangling the influence of these components is vital for the interpretation of enrichments, depletions, and isotopic signals of iron (Fe), chromium (Cr), uranium (U), and vanadium (V) observed in the rock record. Traditionally, a single crustal average is used as a cutoff for detrital input, and concentrations above or below this value are interpreted as redox derived authigenic enrichment or depletion, while authigenic isotopic signals are frequently corrected for an assumed detrital contribution. Building from an extensive study of soils across the continental United States - which upon transport will become marine sediments - and their elemental concentrations, we find large deviations from accepted crustal averages in redox-sensitive metals (Fe, Cr, U, V) compared to typical detrital tracers (Al, Ti, Sc, Th) and provide new estimates for detrital contributions to the ocean. The variability in these elemental ratios is present over large areas, comparable to the catchment-size of major rivers around the globe. This heterogeneity in detrital flux highlights the need for a reevaluation of how the detrital contribution is assessed in trace metal studies, and the use of confidence intervals rather than single average values, especially in local studies or in the case of small authigenic enrichments.

  3. Use of the [14C]Leucine Incorporation Technique To Measure Bacterial Production in River Sediments and the Epiphyton

    OpenAIRE

    Fischer, Helmut; Pusch, Martin

    1999-01-01

    Bacterial production is a key parameter for the understanding of carbon cycling in aquatic ecosystems, yet it remains difficult to measure in many aquatic habitats. We therefore tested the applicability of the [14C]leucine incorporation technique for the measurement of bulk bacterial production in various habitats of a lowland river ecosystem. To evaluate the method, we determined (i) extraction efficiencies of bacterial protein from the sediments, (ii) substrate saturation of leucine in sedi...

  4. Assessment of metal and trace element concentrations in the Cananeia estuary, Brazil, by neutron activation and atomic absorption techniques

    International Nuclear Information System (INIS)

    Amorim, E.P.; Favaro, D.I.T.; Berbel, G.B.B.; Braga, E.S.

    2008-01-01

    Twenty six bottom sediment samples were collected from the Cananeia estuary in summer and winter of 2005. Multielemental analysis was carried out by instrumental neutron activation analysis. Total mercury was determined by cold vapor atomic absorption. As, Cr, Hg and Zn concentrations were compared to the Canadian oriented values (TEL and PEL). Sample points 4 and 9 presented higher concentration for most elements and As and Cr exceeded the TEL values. Organic matter (>10%) associated with siltic and clay sediments was observed. Climatic conditions, hydrodynamic and biogeochemical processes promote differences in seasonal concentrations of elements at some points, which contribute to special distributions. (author)

  5. Temporal fluctuations in grain size, organic materials and iron concentrations in intertidal surface sediment of San Francisco Bay

    Science.gov (United States)

    Thomson-Becker, E. A.; Luoma, S.N.

    1985-01-01

    The physical and chemical characteristics of the oxidized surface sediment in an estuary fluctuate temporally in response to physical forces and apparently-fluctuating inputs. These characteristics, which include grain size and concentrations of organic materials and iron, will influence both trace-metal geochemistry and bioavailability. Temporal trends in the abundance of fine particles, total organic carbon content (TOC), absorbance of extractable organic material (EOM), and concentration of extractable iron in the sediment of San Francisco Bay were assessed using data sets containing approximately monthly samples for periods of two to seven years. Changes in wind velocity and runoff result in monthly changes in the abundance of fine particles in the intertidal zone. Fine-grained particles are most abundant in the late fall/early winter when runoff is elevated and wind velocities are low; particles are coarser in the summer when runoff is low and wind velocities are consistently high. Throughout the bay, TOC is linearly related to fine particle abundance (r = 0.61). Temporal variability occurs in this relationship, as particles are poor in TOC relative to percent of fine particles in the early rainy season. Iron-poor particles also appear to enter the estuary during high runoff periods; while iron is enriched on particle surfaces in the summer. Concentrations of extractable iron and absorbance of EOM vary strongly from year to year. Highest absorbances of EOM occurred in the first year following the drought in 1976-77, and in 1982 and 1983 when river discharge was unusually high. Extractable-iron concentrations were also highest in 1976-77, but were very low in 1982 and 1983. ?? 1985 Dr W. Junk Publishers.

  6. Siderophile element concentrations in magnetic spherules from deep sea sediments revealed by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Nogami, Ken-ichi; Shimamura, Tadashi; Tazawa, Yuji; Yamakoshi, Kazuo.

    1980-01-01

    For the purpose of deciding the extraterrestrial origin of the magnetic spherules found in deep sea sediments, the siderophile elements Co, Ni, Ir and/or Au etc., were measured by instrumental neutron activation analysis. Spherules were collected from red clay samples which were dredged from Mid Pacific Ocean. Only spherules which had smooth surfaces and relatively high specific gravities were chosen for analysis. Existence of Co, Ni and Ir in most spherules suggests the possibility of an extraterrestrial origin for these spherules. It is not clear whether these spherules are droplets ablated from iron meteorites entering into the Earth's atmosphere or they are cosmic iron grains themselves. X-ray diffraction analysis suggested that these spherules are the products of rapid cooling materials. (author)

  7. Trace element, semivolatile organic, and chlorinated organic compound concentrations in bed sediments of selected streams at Fort Gordon, Georgia, February-April 2010

    Science.gov (United States)

    Thomas, Lashun K.; Journey, Celeste A.; Stringfield, Whitney J.; Clark, Jimmy M.; Bradley, Paul M.; Wellborn, John B.; Ratliff, Hagan; Abrahamsen, Thomas A.

    2011-01-01

    A spatial survey of streams was conducted from February to April 2010 to assess the concentrations of major ions, selected trace elements, semivolatile organic compounds, organochlorine pesticides, and polychlorinated biphenyls associated with the bed sediments of surface waters at Fort Gordon military installation near Augusta, Georgia. This investigation expanded a previous study conducted in May 1998 by the U.S. Geological Survey, in cooperation with the U.S. Department of the Army Environmental and Natural Resources Management Office of the U.S. Army Signal Center and Fort Gordon, that evaluated the streambed sediment quality of selected surface waters at Fort Gordon. The data presented in this report are intended to help evaluate bed sediment quality in relation to guidelines for the protection of aquatic life, and identify temporal trends in trace elements and semivolatile organic compound concentrations at streambed sites previously sampled. Concentrations of 34 major ions and trace elements and 102 semivolatile organic, organochlorine pesticide, and polychlorinated biphenyl compounds were determined in the fine-grained fraction of bed sediment samples collected from 13 of the original 29 sites in the previous study, and 22 additional sites at Fort Gordon. Three of the sites were considered reference sites as they were presumed to be located away from potential sources of contaminants and were selected to represent surface waters flowing onto the fort, and the remaining 32 nonreference sites were presumed to be located within the contamination area at the fort. Temporal trends in trace elements and semivolatile organic compound concentrations also were evaluated at 13 of the 32 nonreference sites to provide an assessment of the variability in the number of detections and concentrations of constituents in bed sediment associated with potential sources, accumulation, and attenuation processes. Major ion and trace element concentrations in fine-grained bed

  8. Study of radionuclide and element characterization of Angola marine sediment using low background gamma spectrometry and instrumental neutron activation analysis techniques

    International Nuclear Information System (INIS)

    Teixeira, M.C.P.; Vuong Huu Tan; Truong Y; Ho Manh Dung; Le Nhu Sieu; Cao Dong Vu; Nguyen Thanh Binh

    2007-01-01

    The concentrations of radionuclides and chemical elements in Angola marine sediment samples were determined by using low background gamma (LBG) spectrometry and instrumental neutron activation analysis (INAA). The combination of radionuclide and elemental concentration values yielded synergy in the validation of analytical data and identification of sediment sources modeled by multivariate factor analysis. Varimax rotation factor analysis based on the elemental concentrations revealed five sources contributed to the sediment composition, i.e. crustal, sea-salt, industrial, coal-related and Se-related sources. (author)

  9. Identification of crystaline sediments in apple juice concentrate with the method of structural rentgenography

    International Nuclear Information System (INIS)

    Pogorzelski, E.; Wieczorek, M.; Lubecka, I.

    2001-01-01

    The juice before concentrating was exposed to the pectinolysis and ultrafiltration. The researches to find the causes of coming to being the connection of the calcium with the malic acid are performing. It's supposed that raised quantity of calcium ions in the juice designed to concentration is the effect of pectinolysis. The preparations with low contents of pectinoestherase don't initiate the reaction of calcium precipitation with pectin acid after demethylation

  10. Fundamentals and techniques of nonimaging optics for solar energy concentration. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Winston, R.

    1980-05-20

    Nonimaging optics is a new discipline with techniques, formalism and objectives quite distinct from the traditional methods of focusing optics. These new systems achieve or closely approach the maximum concentration permitted by the Second Law of Thermodynamics for a given angular acceptance and are often called ideal. Application of these new principles to solar energy over the past seven years has led to the invention of a new class of solar concentrators, the most well known version of which is the Compound Parabolic Concentrator or CPC. A new formalism for analyzing nonimaging systems in terms of a quantity called the geometrical vector flux has been developed. This has led not only to a better understanding of the properties of ideal concentrators but to the discovery of several new concentrator designs. One of these new designs referred to as the trumpet concentrator has several advantageous features when used as a secondary concentrator for a point focusing dish concentrator. A new concentrator solution for absorbers which must be separated from the reflector by a gap has been invented. The properties of a variety of new and previously known nonimaging optical configurations have been investigated: for example, Compound Elliptical Concentrators (CEC's) as secondary concentrators and asymmetric ideal concentrators. A thermodynamic model which explains quantitatively the enhancement of effective absorptance of gray body receivers through cavity effects has been developed. The classic method of Liu and Jordan, which allows one to predict the diffuse sunlight levels through correlation with the total and direct fraction was revised and updated and applied to predict the performance of nonimaging solar collectors. The conceptual design for an optimized solar collector which integrates the techniques of nonimaging concentration with evacuated tube collector technology was carried out.

  11. Exploring innovative techniques for identifying geochemical elements as fingerprints of sediment sources in an agricultural catchment of Argentina affected by soil erosion.

    Science.gov (United States)

    Torres Astorga, Romina; de Los Santos Villalobos, Sergio; Velasco, Hugo; Domínguez-Quintero, Olgioly; Pereira Cardoso, Renan; Meigikos Dos Anjos, Roberto; Diawara, Yacouba; Dercon, Gerd; Mabit, Lionel

    2018-05-15

    Identification of hot spots of land degradation is strongly related with the selection of soil tracers for sediment pathways. This research proposes the complementary and integrated application of two analytical techniques to select the most suitable fingerprint tracers for identifying the main sources of sediments in an agricultural catchment located in Central Argentina with erosive loess soils. Diffuse reflectance Fourier transformed in the mid-infrared range (DRIFT-MIR) spectroscopy and energy-dispersive X-ray fluorescence (EDXRF) were used for a suitable fingerprint selection. For using DRIFT-MIR spectroscopy as fingerprinting technique, calibration through quantitative parameters is needed to link and correlate DRIFT-MIR spectra with soil tracers. EDXRF was used in this context for determining the concentrations of geochemical elements in soil samples. The selected tracers were confirmed using two artificial mixtures composed of known proportions of soil collected in different sites with distinctive soil uses. These fingerprint elements were used as parameters to build a predictive model with the whole set of DRIFT-MIR spectra. Fingerprint elements such as phosphorus, iron, calcium, barium, and titanium were identified for obtaining a suitable reconstruction of the source proportions in the artificial mixtures. Mid-infrared spectra produced successful prediction models (R 2  = 0.91) for Fe content and moderate useful prediction (R 2  = 0.72) for Ti content. For Ca, P, and Ba, the R 2 were 0.44, 0.58, and 0.59 respectively.

  12. Potential Release Site Sediment Concentrations Correlated to Storm Water Station Runoff through GIS Modeling

    International Nuclear Information System (INIS)

    McLean, C.T.

    2005-01-01

    This research examined the relationship between sediment sample data taken at Potential Release Sites (PRSs) and storm water samples taken at selected sites in and around Los Alamos National Laboratory (LANL). The PRSs had been evaluated for erosion potential and a matrix scoring system implemented. It was assumed that there would be a stronger relationship between the high erosion PRSs and the storm water samples. To establish the relationship, the research was broken into two areas. The first area was raster-based modeling, and the second area was data analysis utilizing the raster based modeling results and the sediment and storm water sample results. Two geodatabases were created utilizing raster modeling functions and the Arc Hydro program. The geodatabase created using only Arc Hydro functions contains very fine catchment drainage areas in association with the geometric network and can be used for future contaminant tracking. The second geodatabase contains sub-watersheds for all storm water stations used in the study along with a geometric network. The second area of the study focused on data analysis. The analytical sediment data table was joined to the PRSs spatial data in ArcMap. All PRSs and PRSs with high erosion potential were joined separately to create two datasets for each of 14 analytes. Only the PRSs above the background value were retained. The storm water station spatial data were joined to the table of analyte values that were either greater than the National Pollutant Discharge Elimination System (NPDES) Multi-Sector General Permit (MSGP) benchmark value, or the Department of Energy (DOE) Drinking Water Defined Contribution Guideline (DWDCG). Only the storm water stations were retained that had sample values greater than the NPDES MSGP benchmark value or the DOE DWDCG. Separate maps were created for each analyte showing the sub-watersheds, the PRSs over background, and the storm water stations greater than the NPDES MSGP benchmark value or the

  13. Assessment of sedimentation rate and hydrodynamics of Vembanad lagoon, Southern India, using isotope techniques

    International Nuclear Information System (INIS)

    Jacob, Noble; Joseph, T.B.; Hari Kumar, P.S.

    2012-01-01

    Wetlands are natural ecosystems that contribute to flood mitigation, fish and wildlife habitat protection and natural retention of pollutants and nutrients. Despite the importance, wetlands all over the world are undergoing severe degradation in the recent years, because of pollution and human interventions. Hydrology and water quality are the important factors controlling the ecological processes of wetlands and their understanding is essential for the wetlands restoration and management. Vembanad Lagoon, a major component of the Vembanad wetland system, is one of the largest coastal ecosystems in the southwestern part of India. Currently, it is facing numerous problems such as water quality deterioration due to ingression of saltwater, heavy metal contamination, weed infestation etc. and sedimentation due to large scale reclamation, intensive agriculture practices together with deforestation in its catchments. Hence, an isotope investigation was carried out to assess the sedimentation rate, pollution levels in sediments and hydrodynamics of Vembanad Lagoon

  14. Total and methyl mercury concentrations in sediment and water of a constructed wetland in the Athabasca Oil Sands Region.

    Science.gov (United States)

    Oswald, Claire J; Carey, Sean K

    2016-06-01

    In the Athabasca Oil Sands Region in northeastern Alberta, Canada, oil sands operators are testing the feasibility of peatland construction on the post-mining landscape. In 2009, Syncrude Canada Ltd. began construction of the 52 ha Sandhill Fen pilot watershed, including a 15 ha, hydrologically managed fen peatland built on sand-capped soft oil sands tailings. An integral component of fen reclamation is post-construction monitoring of water quality, including salinity, fluvial carbon, and priority pollutant elements. In this study, the effects of fen reclamation and elevated sulfate levels on mercury (Hg) fate and transport in the constructed system were assessed. Total mercury (THg) and methylmercury (MeHg) concentrations in the fen sediment were lower than in two nearby natural fens, which may be due to the higher mineral content of the Sandhill Fen peat mix and/or a loss of Hg through evasion during the peat harvesting, stockpiling and placement processes. Porewater MeHg concentrations in the Sandhill Fen typically did not exceed 1.0 ng L(-1). The low MeHg concentrations may be a result of elevated porewater sulfate concentrations (mean 346 mg L(-1)) and an increase in sulphide concentrations with depth in the peat, which are known to suppress MeHg production. Total Hg and MeHg concentrations increased during a controlled mid-summer flooding event where the water table rose above the ground surface in most of the fen. The Hg dynamics during this event showed that hydrologic fluctuations in this system exacerbate the release of THg and MeHg downstream. In addition, the elevated SO4(2-) concentrations in the peat porewaters may become a problem with respect to downstream MeHg production once the fen is hydrologically connected to a larger wetland network that is currently being constructed. Copyright © 2016 Elsevier Ltd. All rights reserved.

  15. Effect of flexibility on the growth of concentration fluctuations in a suspension of sedimenting fibers: Particle simulations

    Energy Technology Data Exchange (ETDEWEB)

    Manikantan, Harishankar; Saintillan, David [Department of Mechanical and Aerospace Engineering, University of California San Diego, La Jolla, California 92093 (United States)

    2016-01-15

    Three-dimensional numerical simulations are performed to study the stability of a sedimenting suspension of weakly flexible fibers. It is well known that a suspension of rigid rods sedimenting under gravity at low Reynolds number is unstable to concentration fluctuations owing to hydrodynamic interactions. Flexible fibers, however, reorient while settling and even weak flexibility can alter their collective dynamics. In our recent work [Manikantan et al., “The instability of a sedimenting suspension of weakly flexible fibres,” J. Fluid Mech. 756, 935–964 (2014)], we developed a mean-field theory to predict the linear stability of such a system. Here, we verify these predictions using accurate and efficient particle simulations based on a slender-body model. We also demonstrate the mechanisms by which flexibility-induced reorientation alters suspension microstructure, and through it, its stability. Specifically, we first show that the anisotropy of the base state in the case of a suspension of flexible fibers has a destabilizing effect compared to a suspension of rigid rods. Second, a conflicting effect of flexibility is also shown to suppress particle clustering and slow down the growth of the instability. The relative magnitude of filament flexibility and rotational Brownian motion dictates which effect dominates, and our simulations qualitatively follow theoretically predicted trends. The mechanism for either effects is tied to the flexibility-induced reorientation of particles, which we illustrate using velocity and orientation statistics from our simulations. Finally, we also show that, in the case of an initially homogeneous and isotropic suspension, flexibility always acts to suppress the growth of the instability.

  16. Effect of flexibility on the growth of concentration fluctuations in a suspension of sedimenting fibers: Particle simulations

    International Nuclear Information System (INIS)

    Manikantan, Harishankar; Saintillan, David

    2016-01-01

    Three-dimensional numerical simulations are performed to study the stability of a sedimenting suspension of weakly flexible fibers. It is well known that a suspension of rigid rods sedimenting under gravity at low Reynolds number is unstable to concentration fluctuations owing to hydrodynamic interactions. Flexible fibers, however, reorient while settling and even weak flexibility can alter their collective dynamics. In our recent work [Manikantan et al., “The instability of a sedimenting suspension of weakly flexible fibres,” J. Fluid Mech. 756, 935–964 (2014)], we developed a mean-field theory to predict the linear stability of such a system. Here, we verify these predictions using accurate and efficient particle simulations based on a slender-body model. We also demonstrate the mechanisms by which flexibility-induced reorientation alters suspension microstructure, and through it, its stability. Specifically, we first show that the anisotropy of the base state in the case of a suspension of flexible fibers has a destabilizing effect compared to a suspension of rigid rods. Second, a conflicting effect of flexibility is also shown to suppress particle clustering and slow down the growth of the instability. The relative magnitude of filament flexibility and rotational Brownian motion dictates which effect dominates, and our simulations qualitatively follow theoretically predicted trends. The mechanism for either effects is tied to the flexibility-induced reorientation of particles, which we illustrate using velocity and orientation statistics from our simulations. Finally, we also show that, in the case of an initially homogeneous and isotropic suspension, flexibility always acts to suppress the growth of the instability

  17. Spartial and seasonal variations in concentrations of polycyclic aromatic hydrocarbons in water and sediment of Kisumu City bay of Winam Gulf, Lake Victoria-Kenya.

    Science.gov (United States)

    Kwach, Bowa O; Lalah, Joseph O; Shem, Wandiga O

    2009-11-01

    Seasonal and offshore concentration variations for selected sixteen priority pollutant polycyclic aromatic hydrocarbons (PAHs) in surface sediments and water of Car Wash and Kisat areas of Winam Gulf, Lake Victoria, have been investigated. PAHs concentrations in sediments and water range from 0.4 to 31.95 microg/g dry weight and 3.32 to 55.8 microg/L, respectively. Statistical analysis of the PAHs concentrations showed that the most contaminated samples are found during rainy season (April, 2006), 5 m offshore for sediments and 10 m offshore for water. Dry season (October, 2005) generally recorded lower concentrations. The variations showed significant difference (p < or = 0.05) with season and distance of sampling from the shore.

  18. Elemental concentration variations in Plio-Pleistocene sediments from ODP Site 1143 (southern South China Sea) obtained by XRF analyses

    Science.gov (United States)

    Tian, J.; Xie, X.; Jin, H.; Wang, P.; Jian, Z.

    2009-12-01

    Energy dispersive X-ray fluorescence (XRF) scanning technology provides the most accurate and most economic analytical methods for the determination of major and minor elements of the deep-sea sediment ranging from sodium (11) to uranium (92). Scanning on the smooth core surface by XRF Core scanner is reliable and non-destructive to the sediment, requiring little or no time to prepare the core. This method overcomes the drawback of the traditional analytical method by ICP-AES or ICP-MS which requires long time for sample preparation. Thus, it makes it viable to reconstruct long and high-resolution elemental time series from sediment cores. We have performed relatively elemental concentration analyses on the deep sea sediment cores from ODP site 1143 (southern SCS) down to 190.77 mcd (meters composite depth) by XRF core scanner. The depth resolution of the scanning is 1 cm, equivalent to a time resolution of ~250 years. The age model is based on tuning the benthic foraminiferal d18O at Site 1143 to obliquity and precession (Tian et al., 2002) which indicates that the 190.77 meters long sediment spans the past 5 Myr. We compared the records between 99.5 and 136.46 mcd with the elemental records from the same site obtained by Philips PW 2400 X-ray spectrometer (Wehausen et al., online publication). Comparison reveals, regardless of the absolute changes of the elements, that the elemental records (Si, Ti, Al, Fe, Mn, Ca, K, P, Ba, Rb, Sr) obtained by two methods are nearly the same. Results show that the relative concentration variations of the productivity related elements such as Ba and Ca display distinctive glacial-interglacial cycles for the past 5 Myr. These productivity cycles recorded show one-on-one relationship with the glacial-interglacial cycles of the global ice volume change recorded in the benthic foraminiferal d18O. The glacial-interglacial cycles in productivity and global ice volume changes are consistent with each other not only in amplitude but also

  19. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Elk City NTMS Quadrangle, Idaho/Montana, including concentrations of forty-five additional elements

    Energy Technology Data Exchange (ETDEWEB)

    Broxton, D.E.; Beyth, M.

    1980-07-01

    Totals of 1580 water and 1720 sediment samples were collected from 1754 locations in the quadrangle. Elemental concentration, field measurement, weather, geologic, and geographic data for each sample location are listed for waters in Appendix I-A and for sediments in Appendix I-B. Uranium/thorium ratios for sediment samples are also included in Appendix I-B. All elemental analyses were performed at the LASL. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than 40 parts per billion (ppB) uranium were reanalyzed by delayed-neutron counting (DNC). A supplemental report containing the multielement analyses of water samples will be open filed in the near future. Sediments were analyzed for uranium and thorium as well as aluminum, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chlorine, chromium, cobalt, copper, dysprosium, europium, gold, hafnium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, nickel, niobium, potassium, rubidium, samarium, selenium, scandium, silver, sodium, strontium, tantalum, terbium, tin, titanium, tungsten, vanadium, ytterbium, zinc, and zirconium. Basic statistics for 40 of these elements are presented. All sediments were analyzed for uranium by delayed-neutron counting. Other elemental concentrations in sediments were determined by neutron-activation analysis for 30 elements, by x-ray fluorescence for 12 elements, and by arc-source emission spectrography for 2 elements. Analytical results for sediments are reported as parts per million.

  20. Fate of polychlorinated biphenyls in a contaminated lake ecosystem: combining equilibrium passive sampling of sediment and water with total concentration measurements of biota.

    Science.gov (United States)

    Mäenpää, Kimmo; Leppänen, Matti T; Figueiredo, Kaisa; Mayer, Philipp; Gilbert, Dorothea; Jahnke, Annika; Gil-Allué, Carmen; Akkanen, Jarkko; Nybom, Inna; Herve, Sirpa

    2015-11-01

    Equilibrium sampling devices can be applied to study and monitor the exposure and fate of hydrophobic organic chemicals on a thermodynamic basis. They can be used to determine freely dissolved concentrations and chemical activity ratios and to predict equilibrium partitioning concentrations of hydrophobic organic chemicals in biota lipids. The authors' aim was to assess the equilibrium status of polychlorinated biphenyls (PCBs) in a contaminated lake ecosystem and along its discharge course using equilibrium sampling devices for measurements in sediment and water and by also analyzing biota. The authors used equilibrium sampling devices (silicone rubber and polyethylene [PE]) to determine freely dissolved concentrations and chemical activities of PCBs in the water column and sediment porewater and calculated for both phases the corresponding equilibrium concentrations and chemical activities in model lipids. Overall, the studied ecosystem appeared to be in disequilibrium for the studied phases: sediment, water, and biota. Chemical activities of PCBs were higher in sediment than in water, which implies that the sediment functioned as a partitioning source of PCBs and that net diffusion occurred from the sediment to the water column. Measured lipid-normalized PCB concentrations in biota were generally below equilibrium lipid concentrations relative to the sediment (CLip ⇌Sed ) or water (CLip ⇌W ), indicating that PCB levels in the organisms were below the maximum partitioning levels. The present study shows the application versatility of equilibrium sampling devices in the field and facilitates a thermodynamic understanding of exposure and fate of PCBs in a contaminated lake and its discharge course. © 2015 SETAC.

  1. The natural radioactivity measurements in coastal sediment samples along the East Coast of Tamilnadu using gamma spectrometry technique

    Energy Technology Data Exchange (ETDEWEB)

    Chandramohan, J. [E.G.S Pillay Engineering College, Nagapattinam, 611002, Tamilnadu (India); Tholkappian, M. [Sri Vari College of Education, Then Arasampattu, Tiruvannamalai, 606611, Tamilnadu (India); Harikrishnan, N.; Ravisankar, R., E-mail: ravisankarphysics@gmail.com [Post Graduate and Research Department of Physics, Government Arts College, Tiruvannamalai 606603, Tamilnadu (India)

    2015-08-28

    The natural radioactivity concentration in beach sediment samples collected from Pattipulam to Devanampattinam of East Coast of Tamilnadu have been determined by NaI (TI) gamma ray spectrometer. The specific activity concentrations range from ≤ 2.21 (BDL) to 37.02 Bq kg{sup −1} with a mean of 3.79 Bqkg{sup −1} for {sup 238}U, ≤ 2.11 (BDL) to 643.77 Bqkg{sup −1} with a mean of 49.60 Bqkg{sup −1} for {sup 232}Th and 300.34 Bqkg{sup −1} to 449.08 Bqkg{sup −1} with a mean of 360.23 Bqkg{sup −1} for {sup 40}K. The potential radiological hazards due to natural radionuclides content such as Radium Equivalent activity (Ra{sub eq}), Representative level index (RLI), External hazard index (H{sub ex}), absorbed gamma does rate (D{sub R}), and Annual effective dose rate (AEDR) are estimated to assess the radiation hazard associated with the sediments. The obtained data are compared with the recommended safety limits and international approved values. All the values are well below the recommended safety limits indicating that radiation levels do not poses any significant health hazard to the public in the area as a result of the natural radioactivity of beach sediments. This study may help the baseline data for more extensive works in the same subjects of future studies.

  2. Influence of three different concentration techniques on evaporation rate, color and phenolics content of blueberry juice.

    Science.gov (United States)

    Elik, Aysel; Yanık, Derya Koçak; Maskan, Medeni; Göğüş, Fahrettin

    2016-05-01

    The present study was undertaken to assess the effects of three different concentration processes open-pan, rotary vacuum evaporator and microwave heating on evaporation rate, the color and phenolics content of blueberry juice. Kinetics model study for changes in soluble solids content (°Brix), color parameters and phenolics content during evaporation was also performed. The final juice concentration of 65° Brix was achieved in 12, 15, 45 and 77 min, for microwave at 250 and 200 W, rotary vacuum and open-pan evaporation processes, respectively. Color changes associated with heat treatment were monitored using Hunter colorimeter (L*, a* and b*). All Hunter color parameters decreased with time and dependently studied concentration techniques caused color degradation. It was observed that the severity of color loss was higher in open-pan technique than the others. Evaporation also affected total phenolics content in blueberry juice. Total phenolics loss during concentration was highest in open-pan technique (36.54 %) and lowest in microwave heating at 200 W (34.20 %). So, the use of microwave technique could be advantageous in food industry because of production of blueberry juice concentrate with a better quality and short time of operation. A first-order kinetics model was applied to modeling changes in soluble solids content. A zero-order kinetics model was used to modeling changes in color parameters and phenolics content.

  3. Concentration of "1"3"4Cs + "1"3"7Cs bonded to the organic fraction of sediments offshore Fukushima, Japan

    International Nuclear Information System (INIS)

    Ono, Tsuneo; Ambe, Daisuke; Kaeriyama, Hideki

    2015-01-01

    We conducted a sequential chemical extraction experiment for radiocesium ("1"3"4Cs + "1"3"7Cs) using 21 surface sediment samples and two sets of size-fractionated surface sediment samples collected offshore Fukushima. Our results support earlier reports in this area that organic substances in marine sediments have an apparently higher preference for radiocesium than mineral substances. Observations suggest that mineral and organic substances in the marine sediments offshore Fukushima have the same order of preference for radiocesium, primarily because of the existence of ionic competitors in seawater. The apparent preference of radiocesium for organic material is greater because of the partial coverage of sediment mineral surfaces by organic substances. By using these relationships, we created a 2-D map of radiocesium concentration in sediment organic fraction in offshore-Fukushima region. Combining our results with existing monitoring data of marine benthos in offshore-Fukushima sediments, we estimated a transfer coefficient of radiocesium from sediment organic materials to benthic polychaetes as less than 0.03-0.008. (author)

  4. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Rock Springs NTMS Quadrangle, Wyoming, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Morgan, T.L.

    1981-01-01

    This report contains data collected by the Los Alamos Scientific Laboratory (LASL) during a regional geochemical survey for uranium in the Rock Springs National Topographic Map Series (NTMS) quadrangle, southwestern Wyoming, as part of the nationwide hydrogeochemical and Stream Sediment Reconnaissance (HSSR). Totals of 397 water and 1794 sediment samples were collected from 1830 locations in the Rock Springs quadrangle of southern Wyoming during the summer of 1976. The average uranium concentration of all water samples is 6.57 ppb and the average sediment uranium concentration is 3.64 ppM. Elemental concentration, field measurement, weather, geologic, and geographic data for each sample location are listed for waters and for sediments in the appendices. Uranium/thorium ratios for sediment samples are also included. A sample location overlay (Plate I) at 1:250 000 scale for use in conjunction with the Rock Springs NTMS quadrangle sheet (US Geological Survey, 1954) is provided. All elemental analyses were performed at the LASL. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than 40 ppB uranium were reanalyzed by delayed-neutron counting. Sediments were analyzed for uranium and thorium as well as Al, Sb, Ba, Be, Bi, Cd, Ca, Ce, Cs, Cl, Cr, Co, Cu, Dy, Eu, Au, Hf, Fe, La, Pb, Li, Lu, Mg, Mn, Ni, Nb, K, Rb, Sm, Sc, Ag, Na, Sr, Ta, Tb, Sn, T, W, V, Yb, and Zn. All sediments were analyzed for uranium by delayed-neutron counting. Other elemental concentrations in sediments were determined by neutron-activation analysis for 30 elements, by x-ray fluorescence for 12 elements, and by arc-source emission spectrography for 2 elements. These analytical methods are described briefly in the appendix. This report is simply a data release and is intended to make the data available to the DOE and to the public as quickly as possible

  5. Denitrification activity is closely linked to the total ambient Fe concentration in mangrove sediments of Goa, India

    Science.gov (United States)

    Fernandes, Sheryl Oliveira; Gonsalves, Maria-Judith; Michotey, Valérie D.; Bonin, Patricia C.; Loka, A.; Bharathi, P.

    2013-10-01

    Denitrification activity (DNT) and associated environmental parameters were examined in two mangrove ecosystems of Goa, India - the relatively unimpacted Tuvem and the anthropogenically-influenced Divar. Sampling was carried out at every 2 cm interval within the 0-10 cm depth range to determine (1) seasonal (pre-monsoon, monsoon and post-monsoon) down-core variation in DNT (2) assess the environmental factors influencing the DNT and (3) to build predictive models for benthic DNT. Denitrification generally decreased with depth and showed marked seasonal variation at both the locations. Denitrification peaked during the pre-monsoon occurring at a rate of up to 21.00 ± 12.84 nmol N2O g-1 h-1 within 0-4 cm at both the locations. Further, DNT at pre-monsoon was significantly influenced by Fe content at Tuvem and Divar suggesting Fe-mediated nitrate respiration. The influence of other limiting substrates such as NO3- and NO2- was most important during the monsoon and post-monsoon especially at Divar. The multiple regression models developed could predict 67-98% of the observed variability in DNT through the seasons. About 6-9 environmental variables were required to relatively well-predict DNT in these sediments with the complexity governing DNT decreasing from pre-monsoon to post-monsoon. Our results reveal that seasonal dynamics of DNT in tropical mangrove sediments are closely linked to the total Fe at the prevailing ambient concentration in both the systems.

  6. An exploratory study of using external fluid loading on a vibrating tube for measuring suspended sediment concentration in water

    International Nuclear Information System (INIS)

    Hsu, Y-S; Hwang, Y-F; Huang, J H

    2008-01-01

    This paper presents an exploratory study of using external fluid loading on a vibrating tube for measuring the suspended sediment concentration (SSC) in bodies of water such as rivers and reservoirs. This new measuring concept provides an opportunity for an automated on-site monitoring of the conditions in a body of water by taking the fluid sample instantaneously in the area surrounding the vibrating tube. The physical properties of the fluid sample are those of the fluid that naturally flows around the tube, and are more representative of those of the water with SSC to be measured. The theoretical analysis presented in this paper shows that the resonance frequencies of an immersed vibrating tube change significantly with mass density variations that normally occur in bodies of water with suspended sediment. These changes are sensitive enough to have a possible 1% resolution of the measured fluid density. The signal processing issues are discussed, and a schematic of a conceptual measuring setup is proposed. Based on the theoretical analyses and other measurement issues presented in the paper, using the loading by external fluid on a vibrating tube is feasible for measuring the SSC in water bodies

  7. Developing Sediment Remediation Goals at Superfund Sites Based on Pore Water for the Protection of Benthic Organisms from Direct Toxicity to Non-ionic Organic Contaminants

    Science.gov (United States)

    A methodology for developing remediation goals for sites with contaminated sediments is provided. The remediation goals are based upon the concentrations of chemicals in the sediment interstitial water measured using the passive sampling technique. The passive sampling technique ...

  8. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Socorro NRMS Quadrangle, New Mexico, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Planner, H.N.; Fuka, M.A.; Hanks, D.E.; Hansel, J.M.; Minor, M.M.; Montoya, J.D.; Sandoval, W.F.

    1980-10-01

    Results for uranium in water samples and uranium and 42 additional elements in sediment samples are given. A total of 650 water samples was collected from wells (525), springs (99), streams (25), and one pond. Uranium concentrations for all water samples range from below the detection limit to 157.20 parts per billion (ppB). Mean concentrations in springs and well waters are 4.91 ppB and 5.04 ppB, respectively, compared to a value of 2.78 ppB in stream waters. Of the 1384 sediment samples collected, 1246 are from dry stream beds. The remaining 138 samples are from springs (68), ponds (50), and flowing streams (20). Uranium concentrations in sediments range from 0.84 to 13.40 parts per million (ppM) with the exception of a single 445.10-ppM concentration. The mean uranium content of all sediments is 3.12 ppM. Field data, recorded at the collection site, are reported with the elemental concentrations for each water and sediment sample listed in Appendixes I-A and I-B. These data include a scintillometer determination of the equivalent uranium, pH and conductivity measurements, and geographic and weather information. Appendix II explains the codes used in Appendix I and describes the standard field and analytical procedures used by the LASL in the HSSR program

  9. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Leadville NTMS Quadrangle, Colorado, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Planner, H.N.

    1980-10-01

    A total of 1797 locations was sampled over a 19 330-km 2 area, providing an average density of one sample location per 11 km 2 . This report contains results for uranium in water samples and uranium and 42 additional elements in sediment samples. A total of 1279 water samples was collected from streams (1125) and springs (154). Uranium concentrations for all water samples range from below the detection limit of 0.02 ppB to 37.56 ppB. Mean concentrations in streams and springs are 1.05 ppB and 1.19 ppB, respectively. A total of 1784 sediment samples was collected from streams (1590), springs (193), and one pond. Uranium concentrations in sediments range from 1.27 to 223.80 ppM. Statistical mean uranium concentrations for wet stream (8.55 ppM) and spring (7.51 ppM) sediments are found to be greater than their dry counterparts (5.13 ppM and 4.96 ppM, respectively). Field data, recorded at the collection site, are reported with the elemental concentrations for each water and sediment sample listed. These data include a scintillometer determination of the equivalent uranium, pH and conductivity measurements, and geographic and weather information

  10. Speciation of Fe(II) and Fe(III) in Contaminated Aquifer Sediments Using Chemical Extraction Techniques

    DEFF Research Database (Denmark)

    Heron, Gorm; Crouzet, Catherine.; Bourg, Alain C. M.

    1994-01-01

    The iron mineralogy of aquifer sediments was described by chemical extraction techniques. Single-step extractions including 1 M CaC12, NaAc, oxalate, dithionite, Ti(II1)- EDTA, 0.5 M HC1,5 M HC1, hot 6 M HC1, and a sequential extraction by HI and CrIIHC1 were tested on standard iron minerals...... species are distinguished as AVS (acid volatile sulfide, hot 6 M HC1 extraction) and pyrite (sequential HI and CrIIHC1 extraction). By including a cold 5 M HC1 extraction, the total distribution of the major reactive Fe(I1) and Fe(II1) fractions in aquifer sediments can be assessed....

  11. ACOUSTIC TECHNIQUES FOR THE MAPPING OF THE DISTRIBUTION OF CONTAMINATED SEDIMENTS

    Science.gov (United States)

    An overview of the last 30 years of analytical research into the acoustic properties of harbor marine sediments has allowed the extension of the original work of Hamilton (1970) into a production system for classifying the density and bulk physical properties of standard marine s...

  12. Reduction of metal exposure of Daubenton's bats (Myotis daubentonii) following remediation of pond sediment as evidenced by metal concentrations in hair.

    Science.gov (United States)

    Flache, Lucie; Ekschmitt, Klemens; Kierdorf, Uwe; Czarnecki, Sezin; Düring, Rolf-Alexander; Encarnação, Jorge A

    2016-03-15

    Transfer of contaminants from freshwater sediments via aquatic insects to terrestrial predators is well documented in spiders and birds. Here, we analyzed the metal exposure of Myotis daubentonii using an urban pond as their preferred foraging area before and after a remediation measure (sediment dredging) at this pond. Six metal elements (Zn, Cu, Cr, Cd, Pb and Ni) were measured in the sediment of the pond, in EDTA extracts of the sediment and in hair samples of M. daubentonii foraging at the pond. Samples were taken before remediation in 2011 and after remediation in 2013. Metal concentrations were quantified by ICP-OES after miniaturized microwave assisted extraction. In 2011, the pond sediment exhibited a high contamination with nickel, a moderate contamination with copper and chromium and low contents of zinc, cadmium and lead. While sediment metal contents declined only weakly after remediation, a much more pronounced reduction in the concentrations of zinc, copper, chromium and lead concentrations was observed in bat hair. Our results suggest a marked decline in metal exposure of the bats foraging at the pond as a consequence of the remediation measure. It is concluded that Daubenton's bats are suitable bioindicators of metal contamination in aquatic environments, integrating metal exposure via prey insects over their entire foraging area. We further suggest that bat hair is a useful monitoring unit, allowing a non-destructive and non-invasive assessment of metal exposure in bats. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Vertical distribution of trace-element concentrations and occurrence of metallurgical slag particles in accumulated bed sediments of Lake Roosevelt, Washington, September 2002

    Science.gov (United States)

    Cox, S.E.; Bell, P.R.; Lowther, J.S.; Van Metre, P.C.

    2005-01-01

    Sediment cores were collected from six locations in Lake Roosevelt to determine the vertical distributions of trace-element concentrations in the accumulated sediments of Lake Roosevelt. Elevated concentrations of arsenic, cadmium, copper, lead, mercury, and zinc occurred throughout much of the accumulated sediments. Concentrations varied greatly within the sediment core profiles, often covering a range of 5 to 10 fold. Trace-element concentrations typically were largest below the surficial sediments in the lower one-half of each profile, with generally decreasing concentrations from the 1964 horizon to the surface of the core. The trace-element profiles reflect changes in historical discharges of trace elements to the Columbia River by an upstream smelter. All samples analyzed exceeded clean-up guidelines adopted by the Confederated Tribes of the Colville Reservation for cadmium, lead, and zinc and more than 70 percent of the samples exceeded cleanup guidelines for mercury, arsenic, and copper. Although 100 percent of the samples exceeded sediment guidelines for cadmium, lead, and zinc, surficial concentrations of arsenic, copper, and mercury in some cores were less than the sediment-quality guidelines. With the exception of copper, the trace-element profiles of the five cores collected along the pre-reservoir Columbia River channel typically showed trends of decreasing concentrations in sediments deposited after the 1964 time horizon. The decreasing concentrations of trace elements in the upper half of cores from along the pre-reservoir Columbia River showed a pattern of decreasing concentrations similar to reductions in trace-element loading in liquid effluent from an upstream smelter. Except for arsenic, trace-element concentrations typically were smaller at downstream reservoir locations along the pre-reservoir Columbia River. Trace-element concentration in sediments from the Spokane Arm of the reservoir showed distinct differences compared to the similarities

  14. Differential Mueller matrix polarimetry technique for non-invasive measurement of glucose concentration on human fingertip.

    Science.gov (United States)

    Phan, Quoc-Hung; Lo, Yu-Lung

    2017-06-26

    A differential Mueller matrix polarimetry technique is proposed for obtaining non-invasive (NI) measurements of the glucose concentration on the human fingertip. The feasibility of the proposed method is demonstrated by detecting the optical rotation angle and depolarization index of tissue phantom samples containing de-ionized water (DI), glucose solutions with concentrations ranging from 0~500 mg/dL and 2% lipofundin. The results show that the extracted optical rotation angle increases linearly with an increasing glucose concentration, while the depolarization index decreases. The practical applicability of the proposed method is demonstrated by measuring the optical rotation angle and depolarization index properties of the human fingertips of healthy volunteers.

  15. Rapid Late Holocene glacier fluctuations reconstructed from South Georgia lake sediments using novel analytical and numerical techniques

    Science.gov (United States)

    van der Bilt, Willem; Bakke, Jostein; Werner, Johannes; Paasche, Øyvind; Rosqvist, Gunhild

    2016-04-01

    The collapse of ice shelves, rapidly retreating glaciers and a dramatic recent temperature increase show that Southern Ocean climate is rapidly shifting. Also, instrumental and modelling data demonstrate transient interactions between oceanic and atmospheric forcings as well as climatic teleconnections with lower-latitude regions. Yet beyond the instrumental period, a lack of proxy climate timeseries impedes our understanding of Southern Ocean climate. Also, available records often lack the resolution and chronological control required to resolve rapid climate shifts like those observed at present. Alpine glaciers are found on most Southern Ocean islands and quickly respond to shifts in climate through changes in mass balance. Attendant changes in glacier size drive variations in the production of rock flour, the suspended product of glacial erosion. This climate response may be captured by downstream distal glacier-fed lakes, continuously recording glacier history. Sediment records from such lakes are considered prime sources for paleoclimate reconstructions. Here, we present the first reconstruction of Late Holocene glacier variability from the island of South Georgia. Using a toolbox of advanced physical, geochemical (XRF) and magnetic proxies, in combination with state-of-the-art numerical techniques, we fingerprinted a glacier signal from glacier-fed lake sediments. This lacustrine sediment signal was subsequently calibrated against mapped glacier extent with the help of geomorphological moraine evidence and remote sensing techniques. The outlined approach enabled us to robustly resolve variations of a complex glacier at sub-centennial timescales, while constraining the sedimentological imprint of other geomorphic catchment processes. From a paleoclimate perspective, our reconstruction reveals a dynamic Late Holocene climate, modulated by long-term shifts in regional circulation patterns. We also find evidence for rapid medieval glacier retreat as well as a

  16. Identification of metal elements by time-resolved LIBS technique in sediments lake the “Cisne”

    Science.gov (United States)

    Pacheco, P.; Arregui, E.; Álvarez, J.; Rangel, N.; Sarmiento, R.

    2017-01-01

    Laser induced breakdown spectroscopy (LIBS), is a kind of spectral method of atomic emission that uses pulses of radiation high energy laser as excitation source. One of the advantages of technical LIBS lies in the possibility of analyse the substances in any State of aggregation, already is solid, liquid or gaseous, even in colloids as aerosols, gels and others. Another advantage over other conventional techniques is the simultaneous analysis of elements present in a sample of multielement. This work is made in the use of this technique for the identification of metal pollutants in the Swan Lake sediment samples, collected by drilling cores. Plasmas were generated by focusing the radiation of Nd: YAG laser with an energy per pulse 13mJ and 4ns duration, wavelength of 532nm. The spectra of radiation from the plasmas of sediment were recorded with an Echelle spectrograph type coupled to an ICCD camera. The delay times were between 0.5μs and 7μs, while the gate width was of 2μs. To ensure the homogeneity of the plasmas, the sediment sample was placed in a positioning system of linear and rotary adjustment of smooth step synchronized with the trigger of the laser pulse. The registration of the spectra of the sediment to different times of delay, allowed to identify the lines prominent of the different elements present in the sample. The analysis of the Spectra allowed the identification of some elements in the sample as if, Ca, Na, Mg, and Al through the measurement of wavelengths of the prominent peaks.

  17. Identification of metal elements by time-resolved LIBS technique in sediments lake the “Cisne”

    International Nuclear Information System (INIS)

    Pacheco, P; Arregui, E; Álvarez, J; Rangel, N; Sarmiento, R

    2017-01-01

    Laser induced breakdown spectroscopy (LIBS), is a kind of spectral method of atomic emission that uses pulses of radiation high energy laser as excitation source. One of the advantages of technical LIBS lies in the possibility of analyse the substances in any State of aggregation, already is solid, liquid or gaseous, even in colloids as aerosols, gels and others. Another advantage over other conventional techniques is the simultaneous analysis of elements present in a sample of multielement. This work is made in the use of this technique for the identification of metal pollutants in the Swan Lake sediment samples, collected by drilling cores. Plasmas were generated by focusing the radiation of Nd: YAG laser with an energy per pulse 13mJ and 4ns duration, wavelength of 532nm. The spectra of radiation from the plasmas of sediment were recorded with an Echelle spectrograph type coupled to an ICCD camera. The delay times were between 0.5μs and 7μs, while the gate width was of 2μs. To ensure the homogeneity of the plasmas, the sediment sample was placed in a positioning system of linear and rotary adjustment of smooth step synchronized with the trigger of the laser pulse. The registration of the spectra of the sediment to different times of delay, allowed to identify the lines prominent of the different elements present in the sample. The analysis of the Spectra allowed the identification of some elements in the sample as if, Ca, Na, Mg, and Al through the measurement of wavelengths of the prominent peaks. (paper)

  18. The effects of wind and rainfall on suspended sediment concentration related to the 2004 Indian Ocean tsunami

    International Nuclear Information System (INIS)

    Zhang Xinfeng; Tang Danling; Li Zizhen; Zhang Fengpan

    2009-01-01

    The effects of rainfall and wind speed on the dynamics of suspended sediment concentration (SSC), during the 2004 Indian Ocean tsunami, were analyzed using spatial statistical models. The results showed a positive effect of wind speed on SSC, and inconsistent effects (positive and negative) of rainfall on SSC. The effects of wind speed and rainfall on SSC weakened immediately around the tsunami, indicating tsunami-caused floods and earthquake-induced shaking may have suddenly disturbed the ocean-atmosphere interaction processes, and thus weakened the effects of wind speed and rainfall on SSC. Wind speed and rainfall increased markedly, and reached their maximum values immediately after the tsunami week. Rainfall at this particular week exceeded twice the average for the same period over the previous 4 years. The tsunami-affected air-sea interactions may have increased both wind speed and rainfall immediately after the tsunami week, which directly lead to the variations in SSC.

  19. Quantifying the Effects of Near-Bed Concentration on the Sediment Flux after the Operation of the Three Gorges Dam, Yangtze River

    Directory of Open Access Journals (Sweden)

    Li He

    2017-12-01

    Full Text Available The regime of sediment transport in the Jingjiang Reach has significantly changed from quasi-equilibrium to sub-saturation since the impoundment of the Three Gorges Dam (TGD, and vertical profiles of suspended sediment concentration (SSC have changed accordingly. Vertical profiles of SSC data measured at three hydrological stations in the Jingjiang Reach (Zhicheng, Shaishi, and Jianli, before and after the impoundment of TGD, were collected and analyzed. Analytic results indicate a remarkably large concentration in the near-bed zone (within 10% of water depth from the river-bed in a sub-saturated channel. The maximum measured concentration was up to 15 times the vertical average concentration, while the ratio in quasi-equilibrium channel was less than four times that. Concentrations normalized with reference concentration at the same height, and may decrease with increasing values of suspension index (settling velocity over shear velocity. In addition, concentration near the water surface may be larger than concentration in the near-bed region when the suspension index is smaller than 0.01. Sediment flux transported in the near-bed zone may be up to 35% of the total sediment flux in unsaturated flows. The relationship between deviations of estimating sediment flux when ignoring the near-bed concentration and discharge in flood season and non-flood season are different in unsaturated and quasi-equilibrium channels. Analysis indicates that, in the quasi-equilibrium channel, more attention should be paid to near-bed concentration during non-flood season, the same as measurements during flood season with larger discharge.

  20. {sup 226}Ra concentrations in crayfish tissues, water, and sediments from the Serpent River Basin in Northeastern Ontario, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Alikhan, M.A. [Laurentian Univ., Sudbury, ON (Canada). Dept of Biology

    1996-12-31

    Lower Serpent River, as well as Elliot, McCarthy and McCabe lakes had highest {sup 226}Ra contamination, Chrisman, Quirke and Whiskey lakes a moderate one, Flack and Semiwhite lakes and the `distant` control, Lake Wanapitei, the lowest. {sup 226}Ra activity in Cambarus robustus tissues was directly related to their background levels. Thus, concentration coefficient (tissue/sediment concentrations) for {sup 226}Ra ranged from 0.53 to 0.74 in highly contaminated Elliot and McCarthy lakes, 0.28 to 0.59 in moderately contaminated Quirke and Whiskey lakes, and from 0.27 to 3.44 in least contaminated Semiwhite and Flack lakes. Among various organs analysed, exoskeleton showed the highest (43.04 - 90.69%) and the tail muscles the lowest (2.95 -17.14%) {sup 226}Ra activity. {sup 226}Ra concentrations in the alimentary canal were considered a part of the ambient environment as they had not been absorbed. 12 refs, 1 fig, 1 tab.

  1. Automated urinalysis technique determines concentration of creatine and creatinine by colorimetry

    Science.gov (United States)

    Rho, J. H.

    1967-01-01

    Continuous urinalysis technique is useful in the study of muscle wastage in primates. Creatinine concentration in urine is determined in an aliquot mixture by a color reaction. Creatine is determined in a second aliquot by converting it to creatinine and measuring the difference in color intensity between the two aliquots.

  2. A Photometric Technique for Determining Fluid Concentration using Consumer-Grade Hardware

    Science.gov (United States)

    Leslie, F.; Ramachandran, N.

    1999-01-01

    In support of a separate study to produce an exponential concentration gradient in a magnetic fluid, a noninvasive technique for determining, species concentration from off-the-shelf hardware has been developed. The approach uses a backlighted fluid test cell photographed with a commercial digital camcorder. Because the light extinction coefficient is wavelength dependent, tests were conducted to determine the best filter color to use, although some guidance was also provided using an absorption spectrophotometer. With the appropriate filter in place, the provide attenuation of the light passing, through the test cell was captured by the camcorder. The digital image was analyzed for intensity using, software from Scion Image Corp. downloaded from the Internet. The analysis provides a two-dimensional array of concentration with an average error of 0.0095 ml/ml. This technique is superior to invasive techniques, which require extraction of a sample that disturbs the concentration distribution in the test cell. Refinements of this technique using a true monochromatic laser light Source are also discussed.

  3. 238U And 232Th Concentration In Rock Samples using Alpha Autoradiography and Gamma Spectroscopy Techniques

    International Nuclear Information System (INIS)

    Hafez, A.F.; El-Farrash, A.H.; Yousef, H.A.

    2009-01-01

    The activity concentrations of uranium and thorium were measured for some rock samples selected from Dahab region in the south tip of Sinai. In order to detect any harmful radiation that would affect on the tourists and is becoming economic resource because Dahab have open fields of tourism in Egypt. The activity concentration of uranium and thorium in rocks samples was measured using two techniques. The first is .-autoradiography technique with LR-115 and CR-39 detectors and the second is gamma spectroscopic technique with NaI(Tl) detector. It was found that the average activity concentrations of uranium and thorium using .-autoradiography technique ranged from 6.41-49.31 Bqkg-1, 4.86- 40.87 Bqkg-1 respectively and by gamma detector are ranged from 6.70- 49.50 Bqkg-1, 4.47- 42.33 Bqkg-1 respectively. From the obtained data we can conclude that there is no radioactive healthy hazard for human and living beings in the area under investigation. It was found that there are no big differences between the calculated thorium to uranium ratios in both techniques

  4. A novel technique to determine concentration-dependent solvent dispersion in Vapex

    Energy Technology Data Exchange (ETDEWEB)

    Abukhalifeh, H.; Lohi, A.; Upreti, S. R. [Department of Chemical Engineering, Ryerson University, 350 Victoria Street, Toronto, Ontario, M5B 2K3 (Canada)

    2009-07-01

    Vapex (vapor extraction of heavy oil and bitumen) is a promising recovery technology because it consumes low energy, and is very environmentally-friendly. The dispersion of solvents into heavy oil and bitumen is a crucial transport property governing Vapex. The accurate determination of solvent dispersion in Vapex is essential to effectively predict the amount and time scale of oil recovery as well to optimize the field operations. In this work, a novel technique is developed to experimentally determine the concentration-dependent dispersion coefficient of a solvent in Vapex process. The principles of variational calculus are utilized in conjunction with a mass transfer model of the experimental Vapex process. A computational algorithm is developed to optimally compute solvent dispersion as a function of its concentration in heavy oil. The developed technique is applied to Vapex utilizing propane as a solvent. The results show that dispersion of propane is a unimodal function of its concentration in bitumen. (author)

  5. A Novel Technique to Determine Concentration-Dependent Solvent Dispersion in Vapex

    Directory of Open Access Journals (Sweden)

    Hadil Abukhalifeh

    2009-10-01

    Full Text Available Vapex (vapor extraction of heavy oil and bitumen is a promising recovery technology because it consumes low energy, and is very environmentally-friendly. The dispersion of solvents into heavy oil and bitumen is a crucial transport property governing Vapex. The accurate determination of solvent dispersion in Vapex is essential to effectively predict the amount and time scale of oil recovery as well to optimize the field operations. In this work, a novel technique is developed to experimentally determine the concentration-dependent dispersion coefficient of a solvent in Vapex process. The principles of variational calculus are utilized in conjunction with a mass transfer model of the experimental Vapex process. A computational algorithm is developed to optimally compute solvent dispersion as a function of its concentration in heavy oil. The developed technique is applied to Vapex utilizing propane as a solvent. The results show that dispersion of propane is a unimodal function of its concentration in bitumen.

  6. Determination of the uranium concentration in soil solutions by the fission track registration technique

    International Nuclear Information System (INIS)

    Fernandes, G.P.

    1980-02-01

    The fission tracks registration technique was used to determine the uranium concentration in soil solutions. The Makrofol KG, a synthetic plastic manufactured by Bayer, was used as a detector and the wet method was applied. From the calibration curves obtained, it was possible to determine uranium concentrations in soil solutions, from 90 to 320 μg U/l, with an error between 9.4% and 4.0%, respectively. The method was applied to a few soil samples from Pocos de Caldas, Minas Gerais in Brazil. The uranium concentrations in the sample and residues were also determined by other methods to compare the results obtained; only one sample showed deviation from the results obtained by the fission tracks method. And this discrepancy was explained in a reasonable way. It was shown that the fission tracks technique can be used with sucess for application in soil solutions. (Author) [pt

  7. Effect of sediment composition on methane concentration and production in the transition zone of a mangrove (Sepetiba Bay, Rio de Janeiro, Brazil).

    Science.gov (United States)

    Marinho, C C; Campos, E A; Guimarães, J R D; Esteves, F A

    2012-08-01

    The aim of this research was to evaluate the effect of sediment composition on methane (CH4) dynamics in sediments of different areas in the transition zone between a mangrove and the sea. This research was conducted in a mangrove at Coroa Grande, on the southern coast of Rio de Janeiro. Samples were collected at three stations: (1) region colonised by Rhizophora mangle L. on the edge of the mangrove, (2) region colonised by seagrasses and (3) infra-littoral region without vegetation. Samples were collected from the surface layer of the sediment to determine the concentrations of nutrients (C, N and P) and CH4 concentration and production. We observed that concentrations of CH4 and carbon (C) were significantly higher (p Mangrove Coroa Grande is a function of available OM suggesting a possible inhibition of methanotrophy by intense oxygen consumption in the soil surface covered by detritus of Rhizophora mangle vegetation.

  8. High concentrations of polycyclic aromatic hydrocarbons found in water and sediments of car wash and Kisat areas of Winam Gulf, Lake Victoria-Kenya.

    Science.gov (United States)

    Kwach, B O; Lalah, J O

    2009-11-01

    Mean concentrations of selected USEPA priority polycyclic aromatic hydrocarbons (PAHs) in surface sediments and water samples from Car Wash and Kisat areas of Winam Gulf, Lake Victoria in Kenya have been determined using GC-FID and GC-MS. Sampling was done during the rainy season in April 2006. The PAH concentrations in sediment and water ranged from 0.04 to 31.95 microg/g dry weight and 3.32 to 55.8 microg/L, respectively, depending upon the sampling location. The total concentration levels of PAHs in both the sediment and water phase in this study were found to be much higher compared with those reported from other regions worldwide, revealing significant PAH pollution of Car Wash and Kisat areas of Kisumu city bay as a consequent of anthropogenic activities as described in the text. The GC-detected PAHs were confirmed by GC-MS.

  9. Evaluation of the effect of temperature, pH, and bioproduction on Hg concentration in sediments, water, molluscs and algae of the delta of the Ebro river.

    Science.gov (United States)

    Schuhmacher, M; Domingo, J L; Llobet, J M; Corbella, J

    1993-01-01

    The effects of temperature, pH, and bioproduction on mercury levels in sediments, water, molluscs and algae from the delta of the Ebro river (NE Spain) were determined in this study. Mercury concentrations were measured in a cold-vapor atomic absorption spectrophotometer. The ranges of mercury concentrations were the following: sediments, 0.014-0.185 microgram g-1; water, 0.001-0.018 microgram g-1; molluscs, 0.118-0.861 microgram g-1; and algae 0.008-0.026 microgram g-1. Although not statistically significant, a decrease in the pH of the water corresponded with a diminution in the content of mercury in sediments and molluscs, while the mercury levels in water and algae were lower in the areas with high levels of bioproduction. The concentrations of mercury in water significantly decreased with temperature. However, the differences with temperature of the mercury concentrations in sediments did not reach the level of significance. Consequently, water would not be an adequate indicator to determine the levels of mercury contamination, although both sediments and molluscs can be used for this purpose.

  10. Suspended-sediment concentrations, loads, total suspended solids, turbidity, and particle-size fractions for selected rivers in Minnesota, 2007 through 2011

    Science.gov (United States)

    Ellison, Christopher A.; Savage, Brett E.; Johnson, Gregory D.

    2014-01-01

    Sediment-laden rivers and streams pose substantial environmental and economic challenges. Excessive sediment transport in rivers causes problems for flood control, soil conservation, irrigation, aquatic health, and navigation, and transports harmful contaminants like organic chemicals and eutrophication-causing nutrients. In Minnesota, more than 5,800 miles of streams are identified as impaired by the Minnesota Pollution Control Agency (MPCA) due to elevated levels of suspended sediment. The U.S. Geological Survey, in cooperation with the MPCA, established a sediment monitoring network in 2007 and began systematic sampling of suspended-sediment concentrations (SSC), total suspended solids (TSS), and turbidity in rivers across Minnesota to improve the understanding of fluvial sediment transport relations. Suspended-sediment samples collected from 14 sites from 2007 through 2011 indicated that the Zumbro River at Kellogg in the driftless region of southeast Minnesota had the highest mean SSC of 226 milligrams per liter (mg/L) followed by the Minnesota River at Mankato with a mean SSC of 193 mg/L. During the 2011 spring runoff, the single highest SSC of 1,250 mg/L was measured at the Zumbro River. The lowest mean SSC of 21 mg/L was measured at Rice Creek in the northern Minneapolis- St. Paul metropolitan area. Total suspended solids (TSS) have been used as a measure of fluvial sediment by the MPCA since the early 1970s; however, TSS concentrations have been determined to underrepresent the amount of suspended sediment. Because of this, the MPCA was interested in quantifying the differences between SSC and TSS in different parts of the State. Comparisons between concurrently sampled SSC and TSS indicated significant differences at every site, with SSC on average two times larger than TSS concentrations. The largest percent difference between SSC and TSS was measured at the South Branch Buffalo River at Sabin, and the smallest difference was observed at the Des Moines

  11. Comparison of Low Concentration and High Concentration Arsenic Removal Techniques and Evaluation of Concentration of Arsenic in Ground Water: A Case Study of Lahore, Pakistan

    International Nuclear Information System (INIS)

    Yasar, Abdullah; Tabinda, Amtul Bari; Shahzadi, Uzma; Saleem, Pakeeza

    2014-01-01

    The main focus of this study was the evaluation of arsenic concentration in the ground water of Lahore at different depth and application of different mitigation techniques for arsenic removal. Twenty four hours of solar oxidation gives 90% of arsenic removal as compared to 8 hr. or 16 hr. Among oxides, calcium oxide gives 96% of As removal as compared to 93% by lanthanum oxide. Arsenic removal efficiency was up to 97% by ferric chloride, whereas 95% by alum. Activated alumina showed 99% removal as compared to 97% and 95% removal with bauxite and charcoal, respectively. Elemental analysis of adsorbents showed that the presence of phosphate and silica can cause a reduction of arsenic removal efficiency by activated alumina, bauxite and charcoal. This study has laid a foundation for further research on arsenic in the city of Lahore and has also provided suitable techniques for arsenic removal

  12. Comparison of Low Concentration and High Concentration Arsenic Removal Techniques and Evaluation of Concentration of Arsenic in Ground Water: A Case Study of Lahore, Pakistan

    Energy Technology Data Exchange (ETDEWEB)

    Yasar, Abdullah; Tabinda, Amtul Bari; Shahzadi, Uzma; Saleem, Pakeeza [GC University, Lahore (Pakistan)

    2014-10-15

    The main focus of this study was the evaluation of arsenic concentration in the ground water of Lahore at different depth and application of different mitigation techniques for arsenic removal. Twenty four hours of solar oxidation gives 90% of arsenic removal as compared to 8 hr. or 16 hr. Among oxides, calcium oxide gives 96% of As removal as compared to 93% by lanthanum oxide. Arsenic removal efficiency was up to 97% by ferric chloride, whereas 95% by alum. Activated alumina showed 99% removal as compared to 97% and 95% removal with bauxite and charcoal, respectively. Elemental analysis of adsorbents showed that the presence of phosphate and silica can cause a reduction of arsenic removal efficiency by activated alumina, bauxite and charcoal. This study has laid a foundation for further research on arsenic in the city of Lahore and has also provided suitable techniques for arsenic removal.

  13. Organic matter in uranium concentration during ancient bed oxidation of carboniferons sediments

    International Nuclear Information System (INIS)

    Kruglova, V.G.; Uspenskij, V.A.; Dement'ev, P.K.; Kochenov, A.V.

    1984-01-01

    Changes in the organic matter accompanying the process of epigenetic ore formation are studied using the example of a deposit localized in carboniferous molasse strata of the Cretaceous period. Peculiarities of the organic matter as the main mineralization agent are studied by a complex of physical and themical methods. A distinct relationship between the uranium concentration and the degree of organic matter oxigenation is a most characteristic feature of the ore localization, however, there is no direct correlation between the contents of uranium and organic matter in ores. Uranium minerallzation was accumulated during infiltration of acid uraniferous.waters into grey stratum in the process of the bed oxidation zone formation oxidizing. Brown coal matter possessing a maximum adsorbability, as compared to other sedimentary rocks, apprared to be the uranium precipitator. The adsorption was accompanie by the formation of proper uranium minerals (coffinite, pitchblende) due to uranium reduction by oxidizing organic matter. Thus, the oxidative epigenesis was an are-forming process with the uranium concentration on organic matter proportionally to oxidation of the latter

  14. Uranium hydrogeochemical and stream sediment reconnaissance of the Lime Hills and Tyonek NTMS Quadrangles, Alaska, including concentrations of forty-three additional elements

    International Nuclear Information System (INIS)

    Jacobsen, S.I.; Aamodt, P.L.; Sharp, R.R. Jr.

    1979-01-01

    The U contents of the 671 waters from the Lime Hills quadrangle range from below 0.02 ppB to a high of 11.29 ppB. U contents of the 667 sediments from this quadrangle range from a low of 0.1 ppM to a high of 94.9 ppM. Both waters and sediments containing relatively high U concentrations are found to cluster in association with plutonic rocks in the Alaska Range, and particularly so in the vicinity of the Tired Pup batholith and Mount Estelle pluton. The U contents of 575 waters from the Tyonek quadrangle range from below the detection limit to 13.13 ppB. Relatively high U concentrations in waters were found to cluster near the Mount Estelle pluton and undifferentiated igneous, metasedimentary, and volcanic rocks in the Alaska Range and in Pleistocene deposits along the Castle Mountain fault. Uranium contents in 502 sediments from the Tyonek quadrangle range from 0.1 to 58 ppM. Most sediment samples having high U concentrations are from locations near the Mount Estelle pluton and Styx River batholith in the Alaska Range. Data for samples collected in the Alaska Range and the two flanking lowlands were also examined separately. Water samples from all source types in the Alaska Range had a higher mean U concentration (0.85 ppB) than those from the Western Lowland (0.34 ppB) or the Susitna Lowland (0.51 ppB). The mean U concentrations for lake water samples from the Alaska Range and the lowland areas are similar. Sediment samples from streams and lakes in the Alaska Range have a markedly higher mean U concentration (7.00 ppM) than sediment samples from either the Western Lowland (2.46 ppM) or the Susitna Lowland area

  15. Effects of mine drainage on the River Hayle, Cornwall. Factors affecting concentrations of copper, zinc, and iron in water, sediments and dominant invertebrate fauna

    Energy Technology Data Exchange (ETDEWEB)

    Brown, B.E.

    1977-02-15

    Concentrations of copper, zinc and iron were measured in waters, sediments and invertebrates collected from the River Hayle. In river water at least 70% of copper and iron was associated with the ''particulate'' fraction whereas 80% of zinc was in the ''soluble'' form. Although total concentrations of zinc in water exceeded those of copper approximately ten fold, copper predominated over zinc in the sediments by a factor of approximately three. Iron was the most abundant metal recorded in both water and sediments. Seasonal differences in ''total'' metal content of waters suggested that concentrations of copper, zinc and iron increased during periods of high flow and decreased during lower flows. Copper concentrations in the sediment, unlike zinc and iron, showed markedly higher values during the summer sampling period when flows were minimal. In the ''free-living'' Trichoptera larvae, concentrations of copper and zinc in the tissue appeared to follow copper and zinc levels in the water. Similar relationships in Odonata and Plecoptera larvae were not obtained. Factors affecting animal/metal relationships are discussed with particular reference to adaptation shown by organisms exposed to high concentrations of heavy metals in their environment.

  16. Krypton-enhanced ventilation CT with dual energy technique: experimental study for optimal krypton concentration.

    Science.gov (United States)

    Chung, Yong Eun; Hong, Sae Rom; Lee, Mi-Jung; Lee, Myungsu; Lee, Hye-Jeong

    2014-11-01

    To assess the feasibility of krypton-enhanced ventilation CT using dual energy (DE) technique for various krypton concentrations and to determine the appropriate krypton concentration for DE ventilation CT through an animal study. Baseline DECT was first performed on seven New Zealand white rabbits. The animals were then ventilated using 20%, 30%, 40%, 50%, 60%, to 70% krypton concentration, and DECT was performed for each concentration. Krypton extraction was performed through a workstation, and results were displayed on a color map. Overlay Hounsfield unit (HU) values were obtained by two observers in consensus readings. A linear mixed model was used to correlate overlay HU values and krypton concentrations. Visual assessments of the homogeneity of krypton maps were also performed. Mean overlay HU values according to krypton concentration were as follows; 20% krypton, 1.68 ± 5.15; 30% krypton, 3.73 ± 5.93; 40% krypton, 6.92 ± 5.51; 50% krypton, 10.88 ± 5.17; 60% krypton, 14.54 ± 4.23; and 70% krypton, 18.79 ± 3.63. We observed a significant correlation between overlay HU values on krypton maps and krypton concentrations (P krypton color maps, all observers determined universal enhancement on the 70% krypton map for all animals. It is feasible to evaluate lung ventilation function using DECT with a krypton concentration of at least 70%.

  17. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Dubois NTMS Quadrangle, Idaho/Montana, including concentrations of forty-five additional elements

    International Nuclear Information System (INIS)

    LaDelfe, C.M.

    1980-08-01

    Totals of 1024 water samples and 1600 sediment samples were collected from 1669 locations in the Dubois quadrangle. Water samples were taken at streams, springs, and wells; sediment samples were collected from streams and springs. All field and analytical data are presented for waters in Appendix I-A and for sediments in I-B. All elemental analyses were performed at the LASL. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than the upper detection limit of uranium were reanalyzed by delayed neutron counting. Sediments were analyzed for uranium and thorium as well as aluminum, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chlorine, chromium, cobalt, copper, dysprosium, europium, gold, hafnium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, nickel, niobium, potassium rubidium, samarium, scandium, selenium, silver, sodium, strontium, tantalum, terbium, tin, titanium, tungsten, vanadium, ytterbium, zinc and zirconium. All sediments were analyzed for uranium by delayed-neutron counting. Other elemental concentrations in sediments were determined by neutron-activation analysis for 30 elements, by x-ray fluorescence for 12 elements, and by arc-source emission spectrography for 2 elements. Analytical results for sediments are reported as parts per million

  18. Geospatial risk assessment and trace element concentration in reef associated sediments, northern part of Gulf of Mannar biosphere reserve, Southeast Coast of India.

    Science.gov (United States)

    Krishnakumar, S; Ramasamy, S; Simon Peter, T; Godson, Prince S; Chandrasekar, N; Magesh, N S

    2017-12-15

    Fifty two surface sediments were collected from the northern part of the Gulf of Mannar biosphere reserve to assess the geospatial risk of sediments. We found that distribution of organic matter and CaCO 3 distributions were locally controlled by the mangrove litters and fragmented coral debris. In addition, Fe and Mn concentrations in the marine sediments were probably supplied through the riverine input and natural processes. The Geo-accumulation of elements fall under the uncontaminated category except Pb. Lead show a wide range of contamination from uncontaminated-moderately contaminated to extremely contaminated category. The sediment toxicity level of the elements revealed that the majority of the sediments fall under moderately to highly polluted sediments (23.07-28.84%). The grades of potential ecological risk suggest that predominant sediments fall under low to moderate risk category (55.7-32.7%). The accumulation level of trace elements clearly suggests that the coral reef ecosystem is under low to moderate risk. Copyright © 2017 Elsevier Ltd. All rights reserved.

  19. Uranium hydrogeochemical and stream sediment reconnaissance data release for the Dubois NTMS Quadrangle, Idaho/Montana, including concentrations of forty-five additional elements

    Energy Technology Data Exchange (ETDEWEB)

    LaDelfe, C.M.

    1980-08-01

    Totals of 1024 water samples and 1600 sediment samples were collected from 1669 locations in the Dubois quadrangle. Water samples were taken at streams, springs, and wells; sediment samples were collected from streams and springs. All field and analytical data are presented for waters in Appendix I-A and for sediments in I-B. All elemental analyses were performed at the LASL. Water samples were initially analyzed for uranium by fluorometry. All water samples containing more than the upper detection limit of uranium were reanalyzed by delayed neutron counting. Sediments were analyzed for uranium and thorium as well as aluminum, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chlorine, chromium, cobalt, copper, dysprosium, europium, gold, hafnium, iron, lanthanum, lead, lithium, lutetium, magnesium, manganese, nickel, niobium, potassium rubidium, samarium, scandium, selenium, silver, sodium, strontium, tantalum, terbium, tin, titanium, tungsten, vanadium, ytterbium, zinc and zirconium. All sediments were analyzed for uranium by delayed-neutron counting. Other elemental concentrations in sediments were determined by neutron-activation analysis for 30 elements, by x-ray fluorescence for 12 elements, and by arc-source emission spectrography for 2 elements. Analytical results for sediments are reported as parts per million.

  20. Trace metal enrichments in core sediments in Muthupet mangroves, SE coast of India: Application of acid leachable technique

    International Nuclear Information System (INIS)

    Janaki-Raman, D.; Jonathan, M.P.; Srinivasalu, S.; Armstrong-Altrin, J.S.; Mohan, S.P.; Ram-Mohan, V.

    2007-01-01

    Core sediments from Mullipallam Creek of Muthupet mangroves on the southeast coast of India were analyzed for texture, CaCO 3 , organic carbon, sulfur and acid leachable trace metals (Fe, Mn, Cr, Cu, Ni, Co, Pb, Zn and Cd). Textural analysis reveals a predominance of mud while CaCO 3 indicates dissolution in the upper half of the core, and reprecipitation of carbonates in reduction zones. Trace metals are diagenetically modified and anthropogenic processes control Pb and, to some extent, Ni, Zn and Fe. A distinct event is identified at 90 cm suggesting a change in deposition. Strong relationship of trace metals with Fe indicates that they are associated with Fe-oxyhydroxides. The role of carbonates in absorbing trace metals is evident from their positive relationship with trace metals. Comparison of acid leachable trace metals indicates increase in concentrations in the study area and the sediments act as a sink for trace metals contributed from multiple sources. - Natural and anthropogenic trace metals afeecting mangrove sediments

  1. Uranium concentrations in stream waters and sediments from selected sites in the eastern Seward Peninsula, Koyukuk, and Charley River areas, and across South-Central Alaska

    International Nuclear Information System (INIS)

    Sharp, R.R. Jr.; Hill, D.E.

    1978-04-01

    During the summer of 1975, a 6-week reconnaissance was conducted in widespread areas of Alaska as part of the National Uranium Resource Evaluation (NURE) program; Water, stream sediment, and bedrock samples were taken from the eastern Seward Peninsula, from north of Koyukuk River, from the Charley River area, and from across south central Alaska. This report contains the LASL uranium determinations resulting from fluorometric analysis of the water samples and delayed-neutron counting of the stream sediment samples. Results of total uranium for 611 water and 641 sediment samples, from 691 stream locations, are presented. Overlays showing the numbered sample locations and graphically portraying the concentrations of uranium in water and stream sediment samples, at 1:250,000 scale for use with existing National Topographic Map Series (NTMS) sheets and published geologic maps, are provided as plates. The main purposes of this work are to make the uranium data available to the public in the standard computer format used in the NURE Hydrogeochemical and Stream Sediment Reconnaissance (i.e., with a DOE sample number giving the latitude and longitude of each sample location) and to provide uranium concentration overlays at the standard scale of 1:250,000 adopted by the DOE for the NURE program. It also allows a plausible explanation of differences between the uranium values for sediment as determined by acid dissolution/extraction/fluorometry and by delayed-neutron counting that were noted in the earlier report

  2. Impact of Hurricane Irene on Vibrio vulnificus and Vibrio parahaemolyticus concentrations in surface water, sediment and cultured oysters in the Chesapeake Bay, Maryland, USA

    Directory of Open Access Journals (Sweden)

    Kristi S Shaw

    2014-05-01

    Full Text Available To determine if a storm event (i.e., high winds, large volumes of precipitation could alter concentrations of Vibrio vulnificus and Vibrio parahaemolyticus in aquacultured oysters (Crassostrea virginica and associated surface water and sediment, this study followed a sampling timeline before and after Hurricane Irene impacted the Chesapeake Bay estuary in late August 2011. Aquacultured oysters were sampled from two levels in the water column: surface 0.3 m and near-bottom just above the sediment. Concentrations of each Vibrio spp. and associated virulence genes were measured in oysters with a combination of real-time PCR and most probable number enrichment methods, and in sediment and surface water with real-time PCR. While concentration shifts of each Vibrio species were apparent post-storm, statistical tests indicated no significant change in concentration change for either Vibrio species by location (surface or near bottom oysters or date sampled (oyster tissue, surface water and sediment concentrations. V. vulnificus in oyster tissue was correlated with total suspended solids (r=0.41, p=0.04, and V. vulnificus in sediment was correlated with secchi depth (r=-0.93, p< 0.01, salinity (r=-0.46, p=0.02, tidal height (r=-0.45, p=0.03, and surface water V. vulnificus (r=0.98, p< 0.01. V. parahaemolyticus in oyster tissue did not correlate with environmental measurements, but V. parahaemolyticus in sediment and surface water correlated with several measurements including secchi depth (r=-0.48, p=0.02[sediment]; r=-0.97 p< 0.01[surface water] and tidal height (r=-0.96. p< 0.01[sediment], r=-0.59,p< 0.01 [surface water]. The concentrations of Vibrio spp. were higher in oysters relative to other studies (average V. vulnificus 4x105 MPN g-1, V. parahaemolyticus 1x105 MPN g-1, and virulence-associated genes were detected in most oyster samples. This study provides a first estimate of storm-related Vibrio density changes in oyster tissues, sediment and

  3. Regional geochemical maps of the Tonopah 1 degree by 2 degrees Quadrangle, Nevada, based on samples of stream sediment and nonmagnetic heavy-mineral concentrate

    Science.gov (United States)

    Nash, J.T.; Siems, D.F.

    1988-01-01

    This report is part of a series of geologic, geochemical, and geophysical maps of the Tonopah 1° x 2° quadrangle, Nevada, prepared during studies of the area for the Conterminous United States Mineral Assessment Program (CUSMAP). Included here are 21 maps showing the distributions of selected elements or combinations of elements. These regional geochemical maps are based on chemical analyses of the minus-60 mesh (0.25 mm) fraction of stream-sediment samples and the nonmagnetic heavy-mineral concentrate derived from stream sediment. Stream sediments were collected at 1,217 sites. Our geochemical studies of mineralized rock samples provide a framework for evaluating the results from stream sediments.

  4. Applicability of a numerical model to predict vertical distribution of suspended sediment concentration along the depth in Dithmarschen Bight

    Science.gov (United States)

    Rahbani, M.

    2012-04-01

    A three dimensional numerical model of Delft3d-flow was developed to simulate the current velocity and sediment transport of Piep tidal channel system. This channel system is part of Dithmarschen Bight located in the German North Sea coast. It consists of two main channel namely Norderpiep, and Süderpiep. These two channels conjunct together to form Piep channel near the land on tidal flat. The source of the required field data for this study was those collected under "Prediction of Medium Term Coastal Morphodynamics", known as the PROMORPH project. It was executed during the period May 1999 to June 2002. Those measured data used for calibration and validation of the model were current velocity and suspended sediment concentration (SSC). Current velocities were collected using ADCP devise. Suspended sediment concentration data was prepared by converting the measured values of light transmission. These data was collected using transmissometer. On the basis of some in situ mechanical sampler data an equation was developed to convert light transmission to the SSC. Field data were carried out at several stations along the width of three cross sections from the surface to the bottom, taking into account the limitations. To verify the performance of the calibrated model, its results were compared with the field data. The comparison between the modeled and measured current velocity shows an accuracy of about 0.2 m/s. Factor of two of measured SSC were used to evaluate the performance of the model regarding these values. Some dissimilarity was found between the modeled SSC and those of the field data.To verify the cause of this dissimilarity, two comparing procedures were carried out. First the evolution of the vertical profile of the SSC from the model and those from the field were prepared and compared. In another procedure the snapshot of distribution of SSC at each cross section during different phases of a tidal cycle were prepared using the model results and

  5. Optimal Electromagnetic (EM) Geophysical Techniques to Map the Concentration of Subsurface Ice and Adsorbed Water on Mars and the Moon

    Science.gov (United States)

    Stillman, D. E.; Grimm, R. E.

    2013-12-01

    Water ice is ubiquitous in our Solar System and is a probable target for planetary exploration. Mapping the lateral and vertical concentration of subsurface ice from or near the surface could determine the origin of lunar and martian ice and quantify a much-needed resource for human exploration. Determining subsurface ice concentration on Earth is not trivial and has been attempted previously with electrical resistivity tomography (ERT), ground penetrating radar (GPR), airborne EM (AEM), and nuclear magnetic resonance (NMR). These EM geophysical techniques do not actually detect ice, but rather the absence of unfrozen water. This causes a non-unique interpretation of frozen and dry subsurface sediments. This works well in the arctic because most locations are not dry. However, for planetary exploration, liquid water is exceedingly rare and subsurface mapping must discriminate between an ice-rich and a dry subsurface. Luckily, nature has provided a unique electrical signature of ice: its dielectric relaxation. The dielectric relaxation of ice creates a temperature and frequency dependence of the electrical properties and varies the relative dielectric permittivity from ~3.1 at radar frequencies to >100 at low frequencies. On Mars, sediments smaller than silt size can hold enough adsorbed unfrozen water to complicate the measurement. This is because the presence of absorbed water also creates frequency-dependent electrical properties. The dielectric relaxation of adsorbed water and ice can be separated as they have different shapes and frequency ranges as long as a spectrum spanning the two relaxations is measured. The volume concentration of ice and adsorbed water is a function of the strength of their relaxations. Therefore, we suggest that capacitively-coupled dielectric spectroscopy (a.k.a. spectral induced polarization or complex resistivity) can detect the concentration of both ice and adsorbed water in the subsurface. To prove this concept we have collected

  6. Concentrations and loads of suspended sediment-associated pesticides in the San Joaquin River, California and tributaries during storm events

    Science.gov (United States)

    Hladik, M.L.; Domagalski, Joseph L.; Kuivila, K.M.

    2009-01-01

    Current-use pesticides associated with suspended sediments were measured in the San Joaquin River, California and its tributaries during two storm events in 2008. Nineteen pesticides were detected: eight herbicides, nine insecticides, one fungicide and one insecticide synergist. Concentrations for the herbicides (0.1 to 3000 ng/g; median of 6.1 ng/g) were generally greater than those for the insecticides (0.2 to 51 ng/g; median of 1.5 ng/g). Concentrations in the tributaries were usually greater than in the mainstem San Joaquin River and the west side tributaries were higher than the east side tributaries. Estimated instantaneous loads ranged from 1.3 to 320 g/day for herbicides and 0.03 to 53 g/day for insecticides. The greatest instantaneous loads came from the Merced River on the east side. Instantaneous loads were greater for the first storm of 2008 than the second storm in the tributaries while the instantaneous loads within the San Joaquin River were greater during the second storm. Pesticide detections generally reflected pesticide application, but other factors such as physical-chemical properties and timing of application were also important to pesticide loads.

  7. Concentrations of heavy metals in river sediments of the Canes River Basin, the state of Rio de Janeiro, Brazil

    International Nuclear Information System (INIS)

    De Meneses Silva, M.; Teixeira de Andrade, G.

    2010-01-01

    Research about chimism in the Bengalas river basin was performed as a part of the environmental study project developed in the area, encompassing several knowledge fields. Among these, Environmental Geochemistry played an important role. This work presents the results related to heavy metals in stream sediments, indicating its origins (natural or anthropic) and its availability for aquatic biota. The basin under study has 135.07 Km2, laying in the oriental portion of the Teresópolis country, 100 Km far from the of Rio de Janeiro city. The rivers forming the Bengalas basin cut Pre-Cambrian terrain, formed by Orthognaiss takes 70% of the area, post-tectonic granite(20%), migmatite gneiss (10%) and gabro dikes. The methodology used was the determination of the content of heavy metals through sequencial extraction technique, consisting in the selective remove of metals in the geochemical fractions found in the sediments, cation exchange (bioavailable), carbonaceous, reducible and organic (potentially bioavailable) and residual (non available).The analyze of the results showed that iron was present in all sequential phases and predominated in the residual phase The same behavior was verified for zinc and copper. Manganese had the best distribution through the fractions due to its redox character, allowing bigger solubility and transportation; it appeared in the exchange, residual, organic and carbonaceous phases. Cadmium was found only in the carbonaceous phase, confirming its geochemical tendency. Chrome, on the other hand, was present in the residual and organic phase, while lead was found in the residual and carbonaceous phase

  8. Development of automatic high-concentration boron measurement technique; Konodo hoso jido sokutei gijutsu no kaihatsu

    Energy Technology Data Exchange (ETDEWEB)

    Maeda, T.; Honda, S.; Ito, A. [Kyushu Electric Power Co. Inc., Fukuoka (Japan)

    1997-03-01

    The technology that can automatically measure the boron concentration in boric acid water was developed. A high-concentration boric acid solution must be held at a high temperature to prevent the deposition. Skill and precision ({plus_minus}0.2 to 0.3% for 10 to 2500 ppm as boron concentration, and {plus_minus}2 to 3% for 2500 to 25,000 ppm) are required to analyze the boric acid solution manually. In theory, the boron concentration in a wide range can be measured, and boron has a constant-temperature function. A density hydrometer method that facilitates the treatment and calibration in high precision and at low cost was chosen. The vibration period generated when vibration is given to the solution specimen put in a U-tube is higher as the density is lower. On the basis of this theory, the density of a specimen can be obtained according to the relation with the same data of the known-concentration boric acid water. The high-concentration boric acid water that cannot be measured by the existing boron densitometer can be measured directly. It can also be measured in a low-concentration area. The technique can be used in a laboratory as the simplified method that is replaced by the current manual analysis. The reduction effect of analytical chemical`s waste liquid can also be expected. In the electric power industry, automated equipment is required for high efficiency and labor saving. 13 figs., 3 tabs.

  9. Analysis of atmospheric concentrations of radon and thoron using beta counting technique

    International Nuclear Information System (INIS)

    Islam, G.S.; Basunia, S.M.

    1995-05-01

    This paper presents a detailed theory and experimental procedure for measurement and analysis of mixed radon and thoron in the environment. The technique has been successfully applied to the study of seasonal variations of radon and thoron in Rajshahi atmosphere during the years 1989-1991. The maximum radon concentration in outdoor air was observed in the winter from December to January while the indoor radon concentration was found to be maximum during the monsoon months of July and August. The implication of results is briefly discussed in the paper. (author). 4 refs, 6 figs, 2 tabs

  10. Comparability of data for natural radionuclides in marine sediment obtained by different analytical techniques

    International Nuclear Information System (INIS)

    Bojanowski, R.; Fukai, R.; Holm, E.

    1987-01-01

    The results of postassium, uranium, thorium and radium measurements performed on the natural marine sediment sample SD-N-1/2 in the framework of the IAEA-organized worldwide intercomparison excercise are presented. Analytical methods applied in this excercise were evaluated for performance, and significance of the observed discrepancies are discussed in the light of statistical and operative criteria. Possible sources of error were identified in alpha and gamma spectrometric measurements and suggestions are given about how to avoid them. Well characterized reference materials based on natural matrices are shown to be helpful in achieving better data comparability in low level measurements of environmental radioactivity. (author)

  11. Comparison of sediment pollution in the rivers of the Hungarian Upper Tisza Region using non-destructive analytical techniques

    International Nuclear Information System (INIS)

    Osan, Janos; Toeroek, Szabina; Alfoeldy, Balint; Alsecz, Anita; Falkenberg, Gerald; Baik, Soo Yeun; Van Grieken, Rene

    2007-01-01

    The rivers in the Hungarian Upper Tisza Region are frequently polluted mainly due to mining activities in the catchment area. At the beginning of 2000, two major mining accidents occurred in the Romanian part of the catchment area due to the failure of a tailings dam releasing huge amounts of cyanide and heavy metals to the rivers. Surface sediment as well as water samples were collected at six sites in the years 2000-2003, from the northeast-Hungarian section of the Tisza, Szamos and Tur rivers. The sediment pollution of the rivers was compared based on measurements of bulk material and selected single particles, in order to relate the observed compositions and chemical states of metals to the possible sources and weathering of pollution. Non-destructive X-ray analytical methods were applied in order to obtain different kinds of information from the same samples or particles. In order to identify the pollution sources, their magnitude and fate, complementary analyses were carried out. Heterogeneous particulate samples were analyzed from a large geographical territory and a 4-year time period. Individual particles were analyzed only from the 'hot' samples that showed elevated concentrations of heavy metals. Particles that were classified as anthropogenic were finally analyzed to identify trace concentrations and chemical states of heavy metals. Although the Tisza river was affected by water pollution due to the two major mining accidents at the beginning of 2000, the concentration of heavy metals in sediments decreased to the mineral background level 1 year after the pollution event. In the tributaries Szamos and Tur, however, no significant decrease of the heavy metal concentrations was observed in the recent years, indicating a continuous pollution. Among the water suspended particles collected from river Tur, fibers of unknown origin were observed by electron microscopy; these particles were aluminosilicates enriched in Zn and Mn. Cd was also concentrated in

  12. Areal distribution and concentration of contaminants of concern in surficial streambed and lakebed sediments, Lake St. Clair and tributaries, Michigan, 1990-2003

    Science.gov (United States)

    Rachol, Cynthia M.; Button, Daniel T.

    2006-01-01

    As part of the Lake St. Clair Regional Monitoring Project, the U.S. Geological Survey evaluated data collected from surficial streambed and lakebed sediments in the Lake Erie-Lake St. Clair drainages. This study incorporates data collected from 1990 through 2003 and focuses primarily on the U.S. part of the Lake St. Clair Basin, including Lake St. Clair, the St. Clair River, and tributaries to Lake St. Clair. Comparable data from the Canadian part of the study area are included where available. The data are compiled into 4 chemical classes and consist of 21 compounds. The data are compared to effects-based sediment-quality guidelines, where the Threshold Effect Level and Lowest Effect Level represent concentrations below which adverse effects on biota are not expected and the Probable Effect Level and Severe Effect Level represent concentrations above which adverse effects on biota are expected to be frequent.Maps in the report show the spatial distribution of the sampling locations and illustrate the concentrations relative to the selected sediment-quality guidelines. These maps indicate that sediment samples from certain areas routinely had contaminant concentrations greater than the Threshold Effect Concentration or Lowest Effect Level. These locations are the upper reach of the St. Clair River, the main stem and mouth of the Clinton River, Big Beaver Creek, Red Run, and Paint Creek. Maps also indicated areas that routinely contained sediment contaminant concentrations that were greater than the Probable Effect Concentration or Severe Effect Level. These locations include the upper reach of the St. Clair River, the main stem and mouth of the Clinton River, Red Run, within direct tributaries along Lake St. Clair and in marinas within the lake, and within the Clinton River headwaters in Oakland County.Although most samples collected within Lake St. Clair were from sites adjacent to the mouths of its tributaries, samples analyzed for trace-element concentrations

  13. Application of fission track technique for estimation of uranium concentration in drinking waters of Punjab

    International Nuclear Information System (INIS)

    Prabhu, S.P.; Sawant, P.D.; Raj, S.S.; Kumar, A.; Sarkar, P.K.; Tripathi, R.M.

    2012-01-01

    Drinking water samples were collected from four different districts, namely Bhatinda, Mansa, Faridkot and Firozpur, of Punjab for ascertaining the U(nat.) concentrations. All samples were preserved, processed and analyzed by laser fluorimetry (LF). To ensure accuracy of the data obtained by LF, few samples (10 nos) from each district were analyzed by alpha spectrometry as well as by fission track analysis (FTA) technique. For FTA technique few μl of water sample was transferred to polythene tube, lexan detector was immersed in it and the other end of the tube was also heat-sealed. Two samples and one uranium standard were irradiated in DHRUVA reactor. Irradiated detectors were chemically etched and tracks counted using an optical microscope. Uranium concentrations in samples ranged from 3.2 to 60.5 ppb and were comparable with those observed by LF. (author)

  14. Application of the wavelet image analysis technique to monitor cell concentration in bioprocesses

    Directory of Open Access Journals (Sweden)

    G. J. R. Garófano

    2005-12-01

    Full Text Available The growth of cells of great practical interest, such as, the filamentous cells of bacterium Streptomyces clavuligerus, the yeast Saccharomyces cerevisiae and the insect Spodoptera frugiperda (Sf9 cell, cultivated in shaking flasks with complex media at appropriate temperatures and pHs, was quantified by the new wavelet transform technique. This image analysis tool was implemented using Matlab 5.2 software to process digital images acquired of samples taken of these three types of cells throughoot their cultivation. The values of the average wavelet coefficients (AWCs of simplified images were compared with experimental measurements of cell concentration and with computer-based densitometric measurements. AWCs were shown to be directly proportional to measurements of cell concentration and to densitometric measurements, making evident the great potential of the wavelet transform technique to quantitatively estimate the growth of several types of cells.

  15. PRODUCTION OF INDUSTRY SALT WITH SEDIMENTATION – MICROFILTRATION PROCESS: OPTIMAZATION OF TEMPERATURE AND CONCENTRATION BY USING SURFACE RESPONSE METHODOLOGY

    Directory of Open Access Journals (Sweden)

    Widayat Widayat

    2012-02-01

    Full Text Available The salt of sodium chloride commonly used consumption in house , so as a raw material in industry. Thequality of salt depends on sodium chloride concentration. The objective of this research is obtained ofoptimum condition in production of salt industry by using sedimentation and microfiltration process. Theoptimization used surface response methodology and analysis by Statistica 6 software. The responseperceived is NaCl concentration in product. The experiments do by mixing stearic acid with NaOH solutionto product stearic sodium. Then, the solution mixed with sea water, so the white solid will be emerge, thereare stearic calcium and stearic magnesium. And so filtrate evaporated until to obtain salt. TheMathematical model for reduction of Ca2+ and Mg2+ are1 222 221 1 Y = 93,3185 + 1,0967 X + 0,1909 X +1,0682 X - 0,2333 X - 0,3376 X X , with maximum conversion is94,46% at temperature 82,42oC and stearic sodium concentration 14,16%(v/v. The maximum of NaClconcentration is 96,19% at temperature 81,54oC and stearic sodium concetration 13,11 %(v/v. Themathematical model for NaCl production is1 222 221 1 Y = 92,7596 − 0,3443 X − 3,3706 X + 2,9553 X - 0,9562 X - 1,9272 X X . The results of NaCl not yetfulfilled with SNI industry salt. The NaCl concetration in SNI is 98,5%. So, this process is nt aplicable forproductiob salt industry in Indonesia.

  16. Simultaneous demonstration of UV-type and ionizing radiation-type DNA repair by the nucleoid sedimentation technique

    International Nuclear Information System (INIS)

    Aldenhoff, P.; Sperling, K.

    1984-01-01

    The nucleoid sedimentation technique is one of the most sensitive methods for measuring DNA excision repair. With this technique, it is shown that both UV- and ionizing radiation-type repair (the latter induced by bleomycin) can be discriminated in HeLa and normal diploid cells using 1-β-D-arabinofuranosylcytosine. The latter compound inhibits UV-type repair synthesis, and thus causes DNA breaks due to enzymic incision to persist, but has no effect on rejoining DNA after ionizing radiation-type damage. It was then possible to prove that 4-nitroquinoline-1-oxide induces both types of lesions which are repaired simultaneously. This effect could be demonstrated in HeLa and normal human diploid cells in a single experimental set-up. (Auth.)

  17. Can groundwater sampling techniques used in monitoring wells influence methane concentrations and isotopes?

    Science.gov (United States)

    Rivard, Christine; Bordeleau, Geneviève; Lavoie, Denis; Lefebvre, René; Malet, Xavier

    2018-03-06

    Methane concentrations and isotopic composition in groundwater are the focus of a growing number of studies. However, concerns are often expressed regarding the integrity of samples, as methane is very volatile and may partially exsolve during sample lifting in the well and transfer to sampling containers. While issues concerning bottle-filling techniques have already been documented, this paper documents a comparison of methane concentration and isotopic composition obtained with three devices commonly used to retrieve water samples from dedicated observation wells. This work lies within the framework of a larger project carried out in the Saint-Édouard area (southern Québec, Canada), whose objective was to assess the risk to shallow groundwater quality related to potential shale gas exploitation. The selected sampling devices, which were tested on ten wells during three sampling campaigns, consist of an impeller pump, a bladder pump, and disposable sampling bags (HydraSleeve). The sampling bags were used both before and after pumping, to verify the appropriateness of a no-purge approach, compared to the low-flow approach involving pumping until stabilization of field physicochemical parameters. Results show that methane concentrations obtained with the selected sampling techniques are usually similar and that there is no systematic bias related to a specific technique. Nonetheless, concentrations can sometimes vary quite significantly (up to 3.5 times) for a given well and sampling event. Methane isotopic composition obtained with all sampling techniques is very similar, except in some cases where sampling bags were used before pumping (no-purge approach), in wells where multiple groundwater sources enter the borehole.

  18. Elemental Characterization of Soil and Sediment Using NAA Technique for BATAN Inter Laboratory Comparison

    International Nuclear Information System (INIS)

    Syukria Kurniawati; Diah Dwiana Lestiani; Natalia Adventini

    2009-01-01

    Elemental characterization of soil and sediment samples using neutron activation analysis (NAA) for BATAN inter laboratory comparison have been conducted. TAR laboratory have been accredited by KAN since 2006, participating the test to evaluate and maintain its capability as testing laboratory that implemented ISO/IEC 17025. Samples from PTBIN were dried at 110°C for 2 hours and homogenized. The samples were irradiated at rabbit system of Multi-Purpose Reactor G.A Siwabessy for 1, 2, 10 and 60 minutes, then counted using HPGe gamma spectrometer. Several statistical test were applied such as μ-test, relative deviation, acceptance criteria for accuracy and precision. The result showed that soil contains V, Al, Ca, Mn, Na, K, As, Fe, Zn and Hg. From accuracy and precision, final status for 9 elements were passed but Ca was rejected, while V, Al, Mn, Cr, Fe, Zn and Co were detected in sediment samples. Final status for V, Al, Mn, Cr, Fe and Co elements were passed but Zn was rejected. (author)

  19. Uranium hydrogeochemical and stream sediment reconnaissance of the Dalhart NTMS quadrangle, New Mexico/Texas/Oklahoma, including concentrations of forty-two additional elements

    International Nuclear Information System (INIS)

    Morgan, T.L.

    1980-08-01

    Totals of 1583 water samples and 503 sediment samples were collected from 2028 locations within the 20 000-km 2 area of the quadrangle at an average density of one location per 9.86 km 2 . Water samples were collected from wells, springs, and streams and were analyzed for uranium. Sediment samples were collected from streams and springs and were analyzed for uranium, thorium, and 41 additional elements. All field and analytical data are listed in the appendixes of this report. Discussion is limited to anomalous samples, which are considered to be those containing over 20 ppB uranium for waters and over 5 ppM uranium for sediments. Uranium concentrations in water samples range from below the detection limit of 0.2 ppB to 1457.65 ppB and average 7.41 ppB. Most of the seventy anomalous water samples (4.4% of all water samples) are grouped spatially into five clusters or areas of interest. Samples in three of the clusters were collected along the north edge of the quadrangle where Mesozoic strata are exposed. The other two clusters are from the central and southern portions where the Quaternary Ogallala formation is exposed. Sediment samples from the quadrangle have uranium concentrations that range from 0.90 ppM to 27.20 ppM and average 3.27 ppM. Fourteen samples (2.8% of all sediment samples) contain over 5 ppM uranium and are considered anomalous. The five samples with the highest concentrations occur where downcutting streams expose Cretaceous units beneath the Quaternary surficial deposits. The remaining anomalous sediment samples were collected from scattered locations and do not indicate any single formation or unit as a potential source for the anomalous concentrations

  20. Pu abundances, concentrations, and isotopics by x- and gamma-ray spectrometry assay techniques

    International Nuclear Information System (INIS)

    Camp, D.C.; Gunnink, R.; Ruhter, W.D.; Prindle, A.L.; Gomes, R.J.

    1986-01-01

    Two x- and gamma-ray systems were recently installed at-line in gloveboxes and will measure Pu solution concentrations from 5 to 105 g/L. These NDA technique, developed and refined over the past decade, are now used domestically and internationally for nuclear material process monitoring and accountability needs. In off- and at-line installations, they can measure solution concentrations to 0.2%. The K-XRFA systems use a transmission source to correct for solution density. The gamma-ray systems use peaks from 59- to 208-keV to determine solution concentrations and relative isotopics. A Pu check source monitors system stability. These two NDA techniques can be combined to form a new, NDA measurement methodology. With the instrument located outside of a glovebox, both relative Pu isotopics and absolute Pu abundances of a sample located inside a glovebox can be measured. The new technique works with either single or dual source excitation; the former for a detector 6 to 20 cm away with no geometric corrections needed; t