The Hygroscopicity Parameter of Marine Organics in Sea Spray Aerosols

Science.gov (United States)

Boyer, M.; Chang, R. Y. W.

2015-12-01

The effects of aerosols on climate are poorly understood, specifically with respect to their influence on cloud properties. Since oceans cover >70% of Earth's surface, sea spray aerosols (SSA), which act efficiently as cloud condensation nuclei (CCN), may have important implications on Earth's radiation budget. Surface active organic species readily accumulate in the sea surface microlayer (SML), located at the ocean-atmosphere interface, and transfer onto nascent SSA. While it is understood that SSA are commonly enriched with organics, the resulting effect of the organic content on CCN activation remains unresolved. The hygroscopicity parameter, kappa (k), allows for the cloud nucleating properties of individual components to be predicted in particles of mixed composition; however, most studies typically infer k from ambient measurements without assessing the contribution of the individual components to the overall k. In this study, a method for quantifying the cloud nucleating properties of the organic species in surface seawater using k-Kohler theory is proposed. Ambient SML and bulk water samples will be collected and atomized to generate particles such that the overall k can be inferred from CCN measurements. The inorganic and organic components will be quantified, and the organic component will be separated so that the hygroscopicity of only the organic constituents can be determined. By comparing the inferred k values for the samples before and after removal of the inorganic component, the hygroscopicity of the organic constituents alone can be calculated, providing insight on the effect of organic species on CCN activation in SSA.

Analysis of Organic Anionic Surfactants in Fine and Coarse Fractions of Freshly Emitted Sea Spray Aerosol

Energy Technology Data Exchange (ETDEWEB)

Cochran, Richard E.; Laskina, Olga; Jayarathne, Thilina; Laskin, Alexander; Laskin, Julia; Lin, Peng; Sultana, Camile M.; Lee, Christopher; Moore, Kathryn A.; Cappa, Christopher; Bertram, Timothy; Prather, Kimberly; Grassian, Vicki H.; Stone, Elizabeth

2016-02-01

The inclusion of organic compounds in freshly emitted sea spray aerosol (SSA) has been shown to be size-dependent, with an increasing organic fraction in smaller particles. Defining the molecular composition of sea spray aerosol has proven challenging, due to the mix of continental and background particles even in remote marine environments. Here we have used electrospray ionization-high resolution mass spectrometry in negative ion mode to identify organic compounds in nascent sea spray collected throughout a 25-day mesocosm experiment. Over 280 organic compounds from ten major homologous series were identified. These compounds were operationally defined as molecules containing a hydrophobic alkyl chain with a hydrophilic head group making them surface active. The most abundant class of molecules detected were saturated (C8–C24) and unsaturated (C12–C22) fatty acids. Fatty acid derivatives (including saturated oxo-fatty acids (C5–C18) and saturated hydroxy-fatty acids (C5–C18) were also identified. Interestingly, anthropogenic influences on SSA from the seawater were observed in the form of sulfate (C2–C7, C12–C17) and sulfonate (C16–C22) species. During the mesocosm, the distributions of molecules within each homologous series were observed to respond to variations among the levels of phytoplankton and bacteria in the seawater, indicating an important role of biological processes in determining the composition of SSA.

Micrometeorological measurements during the Blackmo 88 spray trials

Science.gov (United States)

D. E. Anderson; D. R. Miller; Y. S. Wang; W. E. Yendol; M. L. McManus

1991-01-01

Instrumentation was arrayed on a 120 foot tower to detail the local atmospheric conditions during the Blackmo 88 spray experiment. Measurements were continuous for 30 minute periods encompassing each spray pass.

Expanding Single Particle Mass Spectrometer Analyses for the Identification of Microbe Signatures in Sea Spray Aerosol.

Science.gov (United States)

Sultana, Camille M; Al-Mashat, Hashim; Prather, Kimberly A

2017-10-03

Ocean-derived microbes in sea spray aersosol (SSA) have the potential to influence climate and weather by acting as ice nucleating particles in clouds. Single particle mass spectrometers (SPMSs), which generate in situ single particle composition data, are excellent tools for characterizing aerosols under changing environmental conditions as they can provide high temporal resolution and require no sample preparation. While SPMSs have proven capable of detecting microbes, these instruments have never been utilized to definitively identify aerosolized microbes in ambient sea spray aersosol. In this study, an aerosol time-of-flight mass spectrometer was used to analyze laboratory generated SSA produced from natural seawater in a marine aerosol reference tank. We present the first description of a population of biological SSA mass spectra (BioSS), which closely match the ion signatures observed in previous terrestrial microbe studies. The fraction of BioSS dramatically increased in the largest supermicron particles, consistent with field and laboratory measurements of microbes ejected by bubble bursting, further supporting the assignment of BioSS mass spectra as microbes. Finally, as supported by analysis of inorganic ion signals, we propose that dry BioSS particles have heterogeneous structures, with microbes adhered to sodium chloride nodules surrounded by magnesium-enriched coatings. Consistent with this structure, chlorine-containing ion markers were ubiquitous in BioSS spectra and identified as possible tracers for distinguishing recently aerosolized marine from terrestrial microbes.

Measuring Spray Droplet Size from Agricultural Nozzles Using Laser Diffraction

Science.gov (United States)

Fritz, Bradley K.; Hoffmann, W. Clint

2016-01-01

When making an application of any crop protection material such as an herbicide or pesticide, the applicator uses a variety of skills and information to make an application so that the material reaches the target site (i.e., plant). Information critical in this process is the droplet size that a particular spray nozzle, spray pressure, and spray solution combination generates, as droplet size greatly influences product efficacy and how the spray moves through the environment. Researchers and product manufacturers commonly use laser diffraction equipment to measure the spray droplet size in laboratory wind tunnels. The work presented here describes methods used in making spray droplet size measurements with laser diffraction equipment for both ground and aerial application scenarios that can be used to ensure inter- and intra-laboratory precision while minimizing sampling bias associated with laser diffraction systems. Maintaining critical measurement distances and concurrent airflow throughout the testing process is key to this precision. Real time data quality analysis is also critical to preventing excess variation in the data or extraneous inclusion of erroneous data. Some limitations of this method include atypical spray nozzles, spray solutions or application conditions that result in spray streams that do not fully atomize within the measurement distances discussed. Successful adaption of this method can provide a highly efficient method for evaluation of the performance of agrochemical spray application nozzles under a variety of operational settings. Also discussed are potential experimental design considerations that can be included to enhance functionality of the data collected. PMID:27684589

PHYSICAL EXCHANGES AT THE AIR-SEA INTERFACE UK-SOLAS Field Measurements

NARCIS (Netherlands)

Brooks, Ian M.; Yelland, Margaret J.; Upstill-Goddard, Robert C.; Nightingale, Philip D.; Archer, Steve; d'Asaro, Ericic; Beale, Rachael; Beatty, Cory; Blomquist, Byron; Bloom, A. Anthony; Brooks, Barbara J.; Cluderay, John; Coles, David; Dacey, John; DeGrandpre, Michael; Dixon, Jo; Drennan, William M.; Gabriele, Joseph; Goldson, Laura; Hardman-Mountford, Nick; Hill, Martin K.; Horn, Matt; Hsueh, Ping-Chang; Huebert, Barry; de Leeuw, Gerrit; Leighton, Timothy G.; Liddicoat, Malcolm; Lingard, Justin J. N.; McNeil, Craig; McQuaid, James B.; Moat, Ben I.; Moore, Gerald; Neill, Craig; Norris, Sarah J.; O'Doherty, Simon; Pascal, Robin W.; Prytherch, John; Rebozo, Mike; Sahlee, Erik; Salter, Matt; Schuster, Ute; Skjelvan, Ingunn; Slagter, Hans; Smith, Michael H.; Smith, Paul D.; Srokosz, Meric; Stephens, John A.; Taylor, Peter K.; Telszewski, Maciej; Walsh, Roisin; Ward, Brian; Woolf, David K.; Young, Dickon; Zemmelink, Henk

As part of the U. K. contribution to the international Surface Ocean-Lower Atmosphere Study, a series of three related projects-DOGEE, SEASAW, and HiWASE-undertook experimental studies of the processes controlling the physical exchange of gases and sea spray aerosol at the sea surface. The studies

Sea spray production by bag breakup mode of fragmentation of the air-water interface at strong and hurricane wind

Science.gov (United States)

Troitskaya, Yuliya; Kandaurov, Alexander; Ermakova, Olga; Kozlov, Dmitry; Sergeev, Daniil; Zilitinkevich, Sergej

2016-04-01

Sea sprays is a typical element of the marine atmospheric boundary layer (MABL) of large importance for marine meteorology, atmospheric chemistry and climate studies. They are considered as a crucial factor in the development of hurricanes and severe extratropical storms, since they can significantly enhance exchange of mass, heat and momentum between the ocean and the atmosphere. This exchange is directly provided by spume droplets with the sizes from 10 microns to a few millimeters mechanically torn off the crests of a breaking waves and fall down to the ocean due to gravity. The fluxes associated with the spray are determined by the rate of droplet production at the surface quantified by the sea spray generation function (SSGF), defined as the number of spray particles of radius r produced from the unit area of water surface in unit time. However, the mechanism of spume droplets' formation is unknown and empirical estimates of SSGF varied over six orders of magnitude; therefore, the production rate of large sea spray droplets is not adequately described and there are significant uncertainties in estimations of exchange processes in hurricanes. Experimental core of our work comprise laboratory experiments employing high-speed video-filming, which have made it possible to disclose how water surface looks like at extremely strong winds and how exactly droplets are torn off wave crests. We classified events responsible for spume droplet, including bursting of submerged bubbles, generation and breakup of "projections" or liquid filaments (Koa, 1981) and "bag breakup", namely, inflating and consequent blowing of short-lived, sail-like pieces of the water-surface film, "bags". The process is similar to "bag-breakup" mode of fragmentation of liquid droplets and jets in gaseous flows. Basing on statistical analysis of results of these experiments we show that the main mechanism of spray-generation is attributed to "bag-breakup mechanism On the base of general principles

Measurement of Spray Drift with a Specifically Designed Lidar System.

Science.gov (United States)

Gregorio, Eduard; Torrent, Xavier; Planas de Martí, Santiago; Solanelles, Francesc; Sanz, Ricardo; Rocadenbosch, Francesc; Masip, Joan; Ribes-Dasi, Manel; Rosell-Polo, Joan R

2016-04-08

Field measurements of spray drift are usually carried out by passive collectors and tracers. However, these methods are labour- and time-intensive and only provide point- and time-integrated measurements. Unlike these methods, the light detection and ranging (lidar) technique allows real-time measurements, obtaining information with temporal and spatial resolution. Recently, the authors have developed the first eye-safe lidar system specifically designed for spray drift monitoring. This prototype is based on a 1534 nm erbium-doped glass laser and an 80 mm diameter telescope, has scanning capability, and is easily transportable. This paper presents the results of the first experimental campaign carried out with this instrument. High coefficients of determination (R² > 0.85) were observed by comparing lidar measurements of the spray drift with those obtained by horizontal collectors. Furthermore, the lidar system allowed an assessment of the drift reduction potential (DRP) when comparing low-drift nozzles with standard ones, resulting in a DRP of 57% (preliminary result) for the tested nozzles. The lidar system was also used for monitoring the evolution of the spray flux over the canopy and to generate 2-D images of these plumes. The developed instrument is an advantageous alternative to passive collectors and opens the possibility of new methods for field measurement of spray drift.

Sea water Corrosion of Nickel based Plasma Spray Coating

Science.gov (United States)

Parida, M.; Nanda, S. P.; Bhuyan, S. K.; Mishra, S. C.

2018-03-01

Different types of erosion resistant coatings are applied/deposited on aero components, depending on the operating/working temperatures. Nickel based coating are applied on the air craft (compressor) components, which can sustain up to working temperature of 650°C. In the present investigation, to improve the compatibility between substrate (i.e. the machine component) and the top coat, application of bond coat is there. The application of Nickel based coating by thermal plasma spray technique has proven to be a satisfactory means of producing acceptable sealing surface with excellent abradability. Before the corrosion study, coated sample is subjected to hardness, thickness and porosity testing. Hence the result is being evaluated. The corrosion behavior of coating was studied by sea water immersion with a time period of 16 weeks. It is observed that, up to 9 weeks increase in weight of coating occurs in a sharp trend and then takes a decreasing trend. The weight gain of the samples has varied from 37.23% (with one week immersion in sea water) to a maximum of about 64.36% for six weeks immersion. Coating morphology and composition analysis of the coatings are studied using SEM and EDS. This behavior shows adsorption/deposition of the foreign particles with polygonal shape on the coating surface by sea water interaction. Foreign particles with polygonal shape deposited on the coating and with increase in immersion/treatment time, washing out of the deposited materials starts, which reflects the decreasing trend of weight gain of the specimen.

Evaluation of StereoPIV Measurement of Droplet Velocity in an Effervescent Spray

Directory of Open Access Journals (Sweden)

Sina Ghaemi

2010-06-01

Full Text Available Particle image velocimetry (PIV is a well known technique for measuring the instantaneous velocity field of flows. However, error may be introduced when measuring the velocity field of sprays using this technique when the spray droplets are used as the seed particles. In this study, the effect of droplet number density, droplet velocity profile, and droplet size distribution of a spray produced by an effervescent atomizer on velocity measurement using a StereoPIV has been investigated. A shadowgraph-particle tracking velocimetry (S-PTV system provided measurement of droplet size and velocity for comparison. This investigation demonstrated that the StereoPIV under-estimates velocity at near-field dense spray region where measurement accuracy is limited by multi-scattering of the laser sheet. In the dilute far-field region of the spray, StereoPIV measurement is mostly in agreement with velocity of the droplet size-class which is close to the mean diameter based on droplet number frequency times droplet cross sectional area.

Measuring water ingestion from spray exposures.

Science.gov (United States)

Sinclair, Martha; Roddick, Felicity; Nguyen, Thang; O'Toole, Joanne; Leder, Karin

2016-08-01

Characterisation of exposure levels is an essential requirement of health risk assessment; however for water exposures other than drinking, few quantitative exposure data exist. Thus, regulatory agencies must use estimates to formulate policy on treatment requirements for non-potable recycled water. We adapted the use of the swimming pool chemical cyanuric acid as a tracer of recreational water ingestion to permit detection of small water volumes inadvertently ingested from spray exposures. By using solutions of 700-1000 mg/L cyanuric acid in an experimental spray exposure scenario, we were able to quantify inadvertent water ingestion in almost 70% of participants undertaking a 10 min car wash activity using a high pressure spray device. Skin absorption was demonstrated to be negligible under the experimental conditions, and the measured ingestion volumes ranged from 0.06 to 3.79 mL. This method could be applied to a range of non-potable water use activities to generate exposure data for risk assessment processes. The availability of such empirical measurements will provide greater assurance to regulatory agencies and industry that potential health risks from exposure to non-potable water supplies are well understood and adequately managed to protect public health. Copyright © 2016 Elsevier Ltd. All rights reserved.

Detailed assessment of diesel spray atomization models using visible and X-ray extinction measurements

Energy Technology Data Exchange (ETDEWEB)

Magnotti, G.M.; Genzale, C.L. (GIT)

2017-12-01

The physical mechanisms characterizing the breakup of a diesel spray into droplets are still unknown. This gap in knowledge has largely been due to the challenges of directly imaging this process or quantitatively measuring the outcomes of spray breakup, such as droplet size. Recent x-ray measurements by Argonne National Laboratory, utilized in this work, provide needed information about the spatial evolution of droplet sizes in selected regions of the spray under a range of injection pressures (50–150 MPa) and ambient densities (7.6–22.8 kg/m3) relevant for diesel operating conditions. Ultra-small angle x-ray scattering (USAXS) measurements performed at the Advanced Photon Source are presented, which quantify Sauter mean diameters (SMD) within optically thick regions of the spray that are inaccessible by conventional droplet sizing measurement techniques, namely in the near-nozzle region, along the spray centerline, and within the core of the spray. To quantify droplet sizes along the periphery of the spray, a complementary technique is proposed and introduced, which leverages the ratio of path-integrated x-ray and visible laser extinction (SAMR) measurements to quantify SMD. The SAMR and USAXS measurements are then utilized to evaluate current spray models used for engine computational fluid dynamic (CFD) simulations. We explore the ability of a carefully calibrated spray model, premised on aerodynamic wave growth theory, to capture the experimentally observed trends of SMD throughout the spray. The spray structure is best predicted with an aerodynamic primary and secondary breakup process that is represented with a slower time constant and larger formed droplet size than conventionally recommended for diesel spray models. Additionally, spray model predictions suggest that droplet collisions may not influence the resultant droplet size distribution along the spray centerline in downstream regions of the spray.

Ultrasonic technique for measuring porosity of plasma-sprayed alumina coatings

Science.gov (United States)

Parthasarathi, S.; Tittmann, B. R.; Onesto, E. J.

1997-12-01

Porosity is an important factor in plasma-sprayed coatings, especially ceramic coatings. Excessive poros-ity can adversely affect the performance of the coated component in various ways. An ultrasonic nonde-structive measurement technique has been developed to measure porosity in plasma-sprayed alumina coatings. The technique is generic and can be extended to other ceramic coating systems. To test the tech-nique, freestanding alumina coatings with varying levels of porosity were fabricated via plasma spray. Samples with varying porosity, obtained through innovative fabrication techniques, were used to gener-ate a calibration curve. The ultrasonic velocity in the low-frequency range was found to be dependent on the density of freestanding coatings (measured via Archimedian techniques). This dependence is the basis of the development of a technique to measure the density of coatings.

Structure of nonevaporating sprays - Measurements and predictions

Science.gov (United States)

Solomon, A. S. P.; Shuen, J.-S.; Zhang, Q.-F.; Faeth, G. M.

1984-01-01

Structure measurements were completed within the dilute portion of axisymmetric nonevaporating sprays (SMD of 30 and 87 microns) injected into a still air environment, including: mean and fluctuating gas velocities and Reynolds stress using laser-Doppler anemometry; mean liquid fluxes using isokinetic sampling; drop sizes using slide impaction; and drop sizes and velocities using multiflash photography. The new measurements were used to evaluate three representative models of sprays: (1) a locally homogeneous flow (LHF) model, where slip between the phases was neglected; (2) a deterministic separated flow (DSF) model, where slip was considered but effects of drop interaction with turbulent fluctuations were ignored; and (3) a stochastic separated flow (SSF) model, where effects of both interphase slip and turbulent fluctuations were considered using random sampling for turbulence properties in conjunction with random-walk computations for drop motion. The LHF and DSF models were unsatisfactory for present test conditions-both underestimating flow widths and the rate of spread of drops. In contrast, the SSF model provided reasonably accurate predictions, including effects of enhanced spreading rates of sprays due to drop dispersion by turbulence, with all empirical parameters fixed from earlier work.

The study of the effects of sea-spray drops on the marine atmospheric boundary layer by direct numerical simulation

Science.gov (United States)

Druzhinin, O.; Troitskaya, Yu; Zilitinkevich, S.

2018-01-01

The detailed knowledge of turbulent exchange processes occurring in the atmospheric marine boundary layer are of primary importance for their correct parameterization in large-scale prognostic models. These processes are complicated, especially at sufficiently strong wind forcing conditions, by the presence of sea-spray drops which are torn off the crests of sufficiently steep surface waves by the wind gusts. Natural observations indicate that mass fraction of sea-spray drops increases with wind speed and their impact on the dynamics of the air in the vicinity of the sea surface can become quite significant. Field experiments, however, are limited by insufficient accuracy of the acquired data and are in general costly and difficult. Laboratory modeling presents another route to investigate the spray-mediated exchange processes in much more detail as compared to the natural experiments. However, laboratory measurements, contact as well as Particle Image Velocimetry (PIV) methods, also suffer from inability to resolve the dynamics of the near-surface air-flow, especially in the surface wave troughs. In this report, we present a first attempt to use Direct Numerical Simulation (DNS) as tool for investigation of the drops-mediated momentum, heat and moisture transfer in a turbulent, droplet-laden air flow over a wavy water surface. DNS is capable of resolving the details of the transfer processes and do not involve any closure assumptions typical of Large-Eddy and Reynolds Averaged Navier-Stokes (LES and RANS) simulations. Thus DNS provides a basis for improving parameterizations in LES and RANS closure models and further development of large-scale prognostic models. In particular, we discuss numerical results showing the details of the modification of the air flow velocity, temperature and relative humidity fields by multidisperse, evaporating drops. We use Eulerian-Lagrangian approach where the equations for the air-flow fields are solved in a Eulerian frame whereas

Biofouling of Cr-Nickel Spray Coated Films on Steel Surfaces

International Nuclear Information System (INIS)

Yoshida, Kento; Kanematsu, Hideyuki; Kuroda, Daisuke; Ikigai, Hajime; Kogo, Takeshi; Yokoyama, Seiji

2012-01-01

Nowadays, corrosion of metals brings us serious economic loss and it often reaches several percentage of GNP. Particularly the marine corrosion was serious and the counter measure was very hard to be established, since the number of factors is huge and complicated. One of the complicated factors in marine corrosion is biofouling. Biofouling was classified into two main categories, microfouling and macrofouling. The former is composed of biofilm formation mainly. Marine bacteria are attached to material surfaces, seeking for nutrition in oligotrophic environment and they excrete polysaccharide to form biofilm on metal surfaces. Then larger living matters are attached on the biofilms to develop biofouling on metal surfaces, which often lead loss and failures of metals in marine environments. From the viewpoint of corrosion protection and maintenance of marine structures, biofouling should be mitigated as much as possible. In this study, we applied spray coating to steels and investigated if chromium-nickel spray coating could mitigate the biofouling, being compared with the conventional aluminium-zinc spray coating in marine environments. The specimens used for this investigation are aluminium, zinc, aluminium-zinc, stacked chromium/nickel and those films were formed on carbon steel (JIS SS400). And the pores formed by spray coating were sealed by a commercial reagent for some specimens. All of those specimens were immersed into sea water located at Marina Kawage (854-3, Chisato, Tsu, Mie Prefecture) in Ise Bay for two weeks. The depth of the specimen was two meter from sea water surface and the distance was always kept constant, since they were suspended from the floating pier. The temperature in sea water changed from 10 to 15 degrees Celsius during the immersion test. The biofouling behavior was investigated by low vacuum SEM (Hitachi Miniscope TM1000) and X-ray fluorescent analysis. When the spray coated specimens with and without sealing agents were compared

Enhancement of marine cloud albedo via controlled sea spray injections: a global model study of the influence of emission rates, microphysics and transport

Directory of Open Access Journals (Sweden)

H. Korhonen

2010-05-01

Full Text Available Modification of cloud albedo by controlled emission of sea spray particles into the atmosphere has been suggested as a possible geoengineering option to slow global warming. Previous global studies have imposed changes in cloud drop concentration in low level clouds to explore the radiative and climatic effects. Here, we use a global aerosol transport model to quantify how an imposed flux of sea spray particles affects the natural aerosol processes, the particle size distribution, and concentrations of cloud drops. We assume that the proposed fleet of vessels emits sea spray particles with a wind speed-dependent flux into four regions of persistent stratocumulus cloud off the western coasts of continents. The model results show that fractional changes in cloud drop number concentration (CDNC vary substantially between the four regions because of differences in wind speed (which affects the spray efficiency of the vessels, transport and particle deposition rates, and because of variations in aerosols from natural and anthropogenic sources. Using spray emission rates comparable to those implied by previous studies we find that the predicted CDNC changes are very small (maximum 20% and in one of the four regions even negative. The weak or negative effect is because the added particles suppress the in-cloud supersaturation and prevent existing aerosol particles from forming cloud drops. A scenario with five times higher emissions (considerably higher than previously assumed increases CDNC on average by 45–163%, but median concentrations are still below the 375 cm⁻³ assumed in previous studies. An inadvertent effect of the spray emissions is that sulphur dioxide concentrations are suppressed by 1–2% in the seeded regions and sulphuric acid vapour by 64–68% due to chemical reactions on the additional salt particles. The impact of this suppression on existing aerosol is negligible in the model, but should be investigated further in

Trajectory and velocity measurement of a particle in spray by digital holography

Energy Technology Data Exchange (ETDEWEB)

Lue Qieni; Chen Yiliang; Yuan Rui; Ge Baozhen; Gao Yan; Zhang Yimo

2009-12-20

We present a method for the trajectory and the velocity measurement of a particle in spray by digital holography. Based on multiple exposure digital in-line holography, a sequence of digital holograms of a dynamic spray particle field at different times are recorded with a CW laser and a high-speed CCD. The time evolution of the serial positions of particles, i.e., the motion trajectories of the particles, is obtained by numerically reconstructing the synthetic hologram of a sequence of digital holograms. The center coordinate (x,y) of each particle image can be extracted using a Hough transform and subpixel precision computing, and the velocity of an individual particle can also be obtained, which is then applied to measuring the velocity of diesel spray and alcohol spray. The research shows that the method presented in this paper for measuring spray field is feasible.

Quantification of sauter mean diameter in diesel sprays using scattering-absorption extinction measurements

Energy Technology Data Exchange (ETDEWEB)

Martinez, Gabrielle L; Magnotti, Gina M; Knox, Benjamin W; Genzale, Caroline L; Matusik, Katarzyna E; Duke, Daniel J; Powell, Christopher F; Kastengren, Alan L

2017-05-18

Quantitative measurements of the primary breakup process in diesel sprays are lacking due to a range of experimental and diagnostic challenges, including: high droplet number density environments, very small characteristic drop size scales (~1-10 μm), and high characteristic velocities in the primary breakup region (~600 m/s). Due to these challenges, existing measurement techniques have failed to resolve a sufficient range of the temporal and spatial scales involved and much remains unknown about the primary atomization process in practical diesel sprays. To gain a better insight into this process, we have developed a joint visible and x-ray extinction measurement technique to quantify axial and radial distributions of the path-integrated Sauter Mean Diameter (SMD) and Liquid Volume Fraction (LVF) for diesel-like sprays. This technique enables measurement of the SMD in regions of moderate droplet number density, enabling construction of the temporal history of drop size development within practical diesel sprays. The experimental campaign was conducted jointly at the Georgia Institute of Technology and Argonne National Laboratory using the Engine Combustion Network “Spray D” injector. X-ray radiography liquid absorption measurements, conducted at the Advanced Photon Source at Argonne, quantify the liquid-fuel mass and volume distribution in the spray. Diffused back-illumination liquid scattering measurements were conducted at Georgia Tech to quantify the optical thickness throughout the spray. By application of Mie-scatter equations, the ratio of the absorption and scattering extinction measurements is demonstrated to yield solutions for the SMD. This work introduces the newly developed scattering-absorption measurement technique and highlights the important considerations that must be taken into account when jointly processing these measurements to extract the SMD. These considerations include co-alignment of measurements taken at different institutions

Wind tunnel measurement of spray drift from on-off controlled sprayer nozzles

DEFF Research Database (Denmark)

Lund, Ivar; Jensen, Peter Kryger; Miller, Paul

wide surface area with a length of 200 mm. The test was conducted in the wind tunnel at Silsoe Spray Applications Unit in the UK. The measurements consisted of two test series; airborne drift was collected on polyethylene lines more than 375 mm away from the centerline of the nozzle and ground deposits...... and arranged to deliver a pulse of spray using the WeedSeeker valve. The tests were conducted to determine accumulated spray deposit at different crosswind and forward speeds. In general, the deposits, especially those measured downwind close to the target zone showed significant increase as the crosswind......Sensor-based precision weed control system at a high resolution requires a high spray application accuracy to keep the spray in a small target zone. The objective of this research was to investigate the target accuracy and spray drift from individual controlled sprayer nozzles targeting a 250 mm...

DepositScan, a Scanning Program to Measure Spray Deposition Distributions

Science.gov (United States)

DepositScan, a scanning program was developed to quickly measure spray deposit distributions on water sensitive papers or Kromekote cards which are widely used for determinations of pesticide spray deposition quality on target areas. The program is installed in a portable computer and works with a ...

Measurements and predictions for nonevaporating sprays in a quiescent environment

Science.gov (United States)

Solomon, A. S. P.; Shuen, J.-S.; Faeth, G. M.; Zhang, Q.-F.

1983-01-01

Yule et al. (1982) have conducted a study of vaporizing sprays with the aid of laser techniques. The present investigation has the objective to supplement the measurements performed by Yule et al., by considering the limiting case of a spray in a stagnant environment. Mean and fluctuating velocities of the continuous phase are measured by means of laser Doppler anemometry (LDA) techniques, while Fraunhofer diffraction and slide impaction methods are employed to determine drop sizes. Liquid fluxes in the spray are found by making use of an isokinetic sampling probe. The obtained data are used as a basis for the evaluation of three models of the process, including a locally homogeneous flow (LHF) model, a deterministic separated flow (DSF) model, and a stochastic separated flow (SSF) model. It is found that the LHF and DSF models do not provide very satisfactory predictions for the test sprays, while the SSF model does provide reasonably good predictions of the observed structure.

PIV measurements of flow structures in a spray dryer

DEFF Research Database (Denmark)

Meyer, Knud Erik; Velte, Clara Marika; Ullum, Thorvald

2011-01-01

Stereoscopic Particle Image Velocimetry (PIV) measurements are made in horizontal planes in a simplified scale model of a spray dryer using water as fluid. The sample rate was sufficient to resolve phenomena at lower frequencies. Data reveal asymmetric velocity fields in both mean fields and dyna......Stereoscopic Particle Image Velocimetry (PIV) measurements are made in horizontal planes in a simplified scale model of a spray dryer using water as fluid. The sample rate was sufficient to resolve phenomena at lower frequencies. Data reveal asymmetric velocity fields in both mean fields...

Planar measurements of spray-induced wall cooling using phosphor thermometry

Science.gov (United States)

Dragomirov, Plamen; Mendieta, Aldo; Abram, Christopher; Fond, Benoît; Beyrau, Frank

2018-03-01

The wall cooling induced by spray impingement is investigated using phosphor thermometry. Thin coatings of zinc oxide (ZnO) phosphor were applied with a transparent chemical binder onto a steel surface. Instantaneous spatially resolved temperatures were determined using the spectral intensity ratio method directly after the injection of UV-grade hexane onto the surface using a commercial gasoline injector. The investigations showed that 2D temperature measurements with high spatial and shot-to-shot precision of, respectively, 0.5 and 0.6 K can be achieved, allowing the accurate resolution of the cooling induced by the spray. The presence of a liquid film over the phosphor coating during measurements showed no noticeable influence on the measured temperatures. However, in some cases a change in the intensity ratio at the spray impingement area, in the form of a permanent "stain", could be observed after multiple injections. The formation of this stain was less likely with increasing annealing time of the coating as well as lower plate operating temperatures during the injection experiments. Finally, the experimental results indicate a noticeable influence of the thickness of the phosphor coating on the measured spray-induced wall cooling history. Hence, for quantitative analysis, a compromise between coating thickness and measurement accuracy needs to be considered for similar applications where the heat transfer rates are very high.

New tools and paradigms for the analysis of sea spray aerosols by single particle mass spectrometry

OpenAIRE

Sultana, Camille M.

2017-01-01

Aerosols can influence the chemistry of the atmosphere as well as also impact global climate by directly scattering light and modifying cloud properties. Sea spray aerosols (SSA) are the second most abundant natural aerosol globally and have the potential to strongly influence atmospheric chemistry and scattering of solar radiation in marine regions. In this dissertation, an ATOFMS was utilized to characterize the chemistry of SSA, focusing on describing the mixing state of the population an...

Mueller matrix polarimetry on plasma sprayed thermal barrier coatings for porosity measurement.

Science.gov (United States)

Luo, David A; Barraza, Enrique T; Kudenov, Michael W

2017-12-10

Yttria-stabilized zirconia (YSZ) is the most widely used material for thermal plasma sprayed thermal barrier coatings (TBCs) used to protect gas turbine engine parts in demanding operation environments. The superior material properties of YSZ coatings are related to their internal porosity level. By quantifying the porosity level, tighter control on the spraying process can be achieved to produce reliable coatings. Currently, destructive measurement methods are widely used to measure the porosity level. In this paper, we describe a novel nondestructive approach that is applicable to classify the porosity level of plasma sprayed YSZ TBCs via Mueller matrix polarimetry. A rotating retarder Mueller matrix polarimeter was used to measure the polarization properties of the plasma sprayed YSZ coatings with different porosity levels. From these measurements, it was determined that a sample's measured depolarization ratio is dependent on the sample's surface roughness and porosity level. To this end, we correlate the depolarization ratio with the samples' surface roughness, as measured by a contact profilometer, as well as the total porosity level, in percentage measured using a micrograph and stereological analysis. With the use of this technique, a full-field and rapid measurement of porosity level can be achieved.

Updating Sea Spray Aerosol Emissions in the Community Multiscale Air Quality Model

Science.gov (United States)

Gantt, B.; Bash, J. O.; Kelly, J.

2014-12-01

Sea spray aerosols (SSA) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. In this study, the Community Multiscale Air Quality (CMAQ) model is updated to enhance fine mode SSA emissions, include sea surface temperature (SST) dependency, and revise surf zone emissions. Based on evaluation with several regional and national observational datasets in the continental U.S., the updated emissions generally improve surface concentrations predictions of primary aerosols composed of sea-salt and secondary aerosols affected by sea-salt chemistry in coastal and near-coastal sites. Specifically, the updated emissions lead to better predictions of the magnitude and coastal-to-inland gradient of sodium, chloride, and nitrate concentrations at Bay Regional Atmospheric Chemistry Experiment (BRACE) sites near Tampa, FL. Including SST-dependency to the SSA emission parameterization leads to increased sodium concentrations in the southeast U.S. and decreased concentrations along the Pacific coast and northeastern U.S., bringing predictions into closer agreement with observations at most Interagency Monitoring of Protected Visual Environments (IMPROVE) and Chemical Speciation Network (CSN) sites. Model comparison with California Research at the Nexus of Air Quality and Climate Change (CalNex) observations will also be discussed, with particular focus on the South Coast Air Basin where clean marine air mixes with anthropogenic pollution in a complex environment. These SSA emission updates enable more realistic simulation of chemical processes in coastal environments, both in clean marine air masses and mixtures of clean marine and polluted conditions.

Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

OpenAIRE

Gantt, B.; Kelly, J. T.; Bash, J. O.

2015-01-01

Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are also important due to the localized impact of SSAs on atmospheric chemistry near the coast. In this study, SSA emissions in the Community Multiscale Air Quality (CMAQ) model were updated to enhance the...

PIV measurement of internal structure of diesel fuel spray

Energy Technology Data Exchange (ETDEWEB)

Cao, Z M [Ecotechnology System Lab., Yokohama National Univ. (Japan); Nishino, K [Div. of Artificial Environment and Systems, Yokohama National Univ. (Japan); Mizuno, S [Yokohama National Univ. (Japan); Torii, K [Dept. of Mechanical Engineering and Materials Science, Yokohama National Univ. (Japan)

2000-12-01

This paper reports particle image velocimetry (PIV) measurements of diesel fuel spray injected from a single-hole nozzle at injection pressures ranging from 30 to 70 MPa, which are comparable to partial-load operating conditions of commercial diesel engines. The fuel is injected into a non-combusting environment pressurized up to 2.0 MPa. A laser-induced fluorescent (LIF) technique is utilized to visualize internal structures of fuel sprays formed by densely-distributing droplets. A specially designed synchronization system is developed to acquire double-frame spray images at an arbitrary time delay after injection. A direct cross-correlation PIV technique is applied to measure instantaneous droplet velocity distribution. Unique large-scale structures in droplet concentration, called 'branch-like structures' by Azetsu et al. (1990), are observed and shown to be associated with active vortical motions, which appear to be responsible for the mixing between droplets and the surrounding gas. It is found that the droplets tend to move out of the vortical structures and accumulate in the regions of low vorticity. Some other interesting features concerning droplet velocity fields are also presented. (orig.)

Spray deposition and spray drift in orchard spraying by multiple row sprayers

NARCIS (Netherlands)

Wenneker, M.; Zande, van de J.C.; Michielsen, J.G.P.; Stallinga, H.; Velde, van P.

2016-01-01

The evaluation of the latest data on spray drift in orchard spraying in the Netherlands, and measurements of surface water quality parameters show that the current legislation and measures are insufficient to protect the surface water. To meet the national and European objectives regarding surface

Comparison of Global Sizing Velocimetry and Phase Doppler Anemometry measurements of alternative jet fuel sprays

Science.gov (United States)

Sadr, Reza; Kannaiyan, Kumaran

2013-11-01

Atomization plays a crucial precursor role in liquid fuel combustion that directly affects the evaporation, mixing, and emission levels. Laser diagnostic techniques are often used to study the spray characteristics of liquid fuels. The objective of this work is to compare the spray measurements of Gas-to Liquid (GTL) jet fuels obtained using Global Sizing Velocimetry (GSV) and Phase Doppler Anemometry (PDA) techniques at global and local levels, respectively. The chemical and physical properties of GTL fuels are different from conventional jet fuels, owing to the difference in their production methodology. In this work, the experimental facility, the measurement techniques, and spray characteristics of two different GTL fuels are discussed and compared with those of Jet A-1 fuel. Results clearly demonstrate that although the global measurement gives an overall picture of the spray, fine details are obtained only through local measurements and complement in gaining more inferences into the spray characteristics. The results also show a close similarity in spray characteristics between GTL and Jet A-1 fuels. Funded by Qatar Science and Technology Park.

Measurement of Ambient Air Motion of D. I. Gasoline Spray by LIF-PIV

Science.gov (United States)

Yamakawa, Masahisa; Isshiki, Seiji; Yoshizaki, Takuo; Nishida, Keiya

Ambient air velocity distributions in and around a D. I. gasoline spray were measured using a combination of LIF and PIV techniques. A rhodamine and water solution was injected into ambient air to disperse the fine fluorescent liquid particles used as tracers. A fuel spray was injected into the fluorescent tracer cloud and was illuminated by an Nd: YAG laser light sheet (532nm). The scattered light from the spray droplets and tracers was cut off by a high-pass filter (>560nm). As the fluorescence (>600nm) was transmitted through the high-pass filter, the tracer images were captured using a CCD camera and the ambient air velocity distribution could be obtained by PIV based on the images. This technique was applied to a D. I. gasoline spray. The ambient air flowed up around the spray and entered into the tail of the spray. Furthermore, the relative velocity between the spray and ambient air was investigated.

Modelling the Evolution of Sea Spray Droplets on a Global Scale

Science.gov (United States)

Staniec, A.; Vlahos, P.; Monahan, E. C.

2017-12-01

Sea spray droplets are an important mechanism for the transport of moisture, heat, and organic material between the ocean and the atmosphere. Spume droplets are the largest of the size spectrum and as such have the potential to transport significant amounts of energy and gases despite their generally short residence time in the atmosphere. A model is developed based on the physical parameterizations from Andreas et al. (1995, 2005)and a range of spume generation functions, coupled with a biogeochemical exchange model for gases developed here to examine the equilibrium temperature and gas exchange of spume droplets under representative open ocean conditions. The modelling approach uses micro-physics to simulate the expected changes to the droplet as it equilibrates with the atmospheric temperature and relative humidity. The effect of temperature differentials and relative humidity variations is explored. A global approach is simulated by using average summer and winter values for SST, salinity, and air temperature throughout the various ocean basins.

Indoor spray measurement of spray drift potential using a spray drift test bench : effect of drift-reducing nozzle types, spray boom height, nozzle spacing and forward speed

NARCIS (Netherlands)

Moreno Ruiz, J.R.

2014-01-01

In a series of indoor experiments spray drift potential was assessed when spraying over a spray drift testbench with two different driving speeds, 2m/s and 4m/s, two different spray boom heights, 30 cm and 50 cm, and two different nozzle spacing, 25 cm and 50 cm, for six different nozzle types. The

Characterizing Suspension Plasma Spray Coating Formation Dynamics through Curvature Measurements

Science.gov (United States)

Chidambaram Seshadri, Ramachandran; Dwivedi, Gopal; Viswanathan, Vaishak; Sampath, Sanjay

2016-12-01

Suspension plasma spraying (SPS) enables the production of variety of microstructures with unique mechanical and thermal properties. In SPS, a liquid carrier (ethanol/water) is used to transport the sub-micrometric feedstock into the plasma jet. Considering complex deposition dynamics of SPS technique, there is a need to better understand the relationships among spray conditions, ensuing particle behavior, deposition stress evolution and resultant properties. In this study, submicron yttria-stabilized zirconia particles suspended in ethanol were sprayed using a cascaded arc plasma torch. The stresses generated during the deposition of the layers (termed evolving stress) were monitored via the change in curvature of the substrate measured using an in situ measurement apparatus. Depending on the deposition conditions, coating microstructures ranged from feathery porous to dense/cracked deposits. The evolving stresses and modulus were correlated with the observed microstructures and visualized via process maps. Post-deposition bi-layer curvature measurement via low temperature thermal cycling was carried out to quantify the thermo-elastic response of different coatings. Lastly, preliminary data on furnace cycle durability of different coating microstructures were evaluated. This integrated study involving in situ diagnostics and ex situ characterization along with process maps provides a framework to describe coating formation mechanisms, process parametrics and microstructure description.

A Two-Continua Approach to Eulerian Simulation of Water Spray

DEFF Research Database (Denmark)

Nielsen, Michael Bang; Østerby, Ole

2013-01-01

Physics based simulation of the dynamics of water spray - water droplets dispersed in air - is a means to increase the visual plausibility of computer graphics modeled phenomena such as waterfalls, water jets and stormy seas. Spray phenomena are frequently encountered by the visual effects industry...

Linking variations in sea spray aerosol particle hygroscopicity to composition during two microcosm experiments

Directory of Open Access Journals (Sweden)

S. D. Forestieri

2016-07-01

Full Text Available The extent to which water uptake influences the light scattering ability of marine sea spray aerosol (SSA particles depends critically on SSA chemical composition. The organic fraction of SSA can increase during phytoplankton blooms, decreasing the salt content and therefore the hygroscopicity of the particles. In this study, subsaturated hygroscopic growth factors at 85 % relative humidity (GF(85 % of predominately submicron SSA particles were quantified during two induced phytoplankton blooms in marine aerosol reference tanks (MARTs. One MART was illuminated with fluorescent lights and the other was illuminated with sunlight, referred to as the "indoor" and "outdoor" MARTs, respectively. Optically weighted GF(85 % values for SSA particles were derived from measurements of light scattering and particle size distributions. The mean optically weighted SSA diameters were 530 and 570 nm for the indoor and outdoor MARTs, respectively. The GF(85 % measurements were made concurrently with online particle composition measurements, including bulk composition (using an Aerodyne high-resolution aerosol mass spectrometer and single particle (using an aerosol time-of-flight mass spectrometer measurement, and a variety of water-composition measurements. During both microcosm experiments, the observed optically weighted GF(85 % values were depressed substantially relative to pure inorganic sea salt by 5 to 15 %. There was also a time lag between GF(85 % depression and the peak chlorophyll a (Chl a concentrations by either 1 (indoor MART or 3-to-6 (outdoor MART days. The fraction of organic matter in the SSA particles generally increased after the Chl a peaked, also with a time lag, and ranged from about 0.25 to 0.5 by volume. The observed depression in the GF(85 % values (relative to pure sea salt is consistent with the large observed volume fractions of non-refractory organic matter (NR-OM comprising the SSA. The GF(85 % values

Quantitative X-ray measurements of high-pressure fuel sprays from a production heavy duty diesel injector

Energy Technology Data Exchange (ETDEWEB)

Ramirez, A.I.; Som, S.; Aggarwal, Suresh K. [University of Illinois at Chicago, Department of Mechanical and Industrial Engineering, Chicago, IL (United States); Kastengren, A.L.; El-Hannouny, E.M.; Longman, D.E.; Powell, C.F. [Argonne National Laboratory, Energy Systems Division, Argonne, IL (United States)

2009-07-15

A quantitative and time-resolved X-ray radiography technique has been used for detailed measurements of high-pressure fuel sprays in the near-nozzle region of a diesel engine injector. The technique provides high spatial and temporal resolution, especially in the relatively dense core region. A single spray plume from a hydraulically actuated electronically controlled unit injector model 315B injector with a 6-hole nozzle was isolated and studied at engine-like densities for two different injection pressures. Optical spray imaging was also employed to evaluate the effectiveness of the shield used to isolate a single spray plume. The steady state fuel distributions for both injection pressures are similar and show a dense spray region along the axis of the spray, with the on-axis spray density decreasing as the spray progresses downstream. The higher injection pressure case exhibits a larger cone angle and spray broadening at the exit of the nozzle. For some time periods, the near-nozzle penetration speed is lower for the high injection pressure case than the low injection pressure case, which is unexpected, but can be attributed to the needle and flow dynamics inside the injector causing slower pressure build-up for the former case. Rate of injection testing was performed to further understand near-nozzle behavior. Mass distribution data were obtained and used to find mass-averaged velocity of the spray. Comparisons of the radiography data with that from a common rail single-hole light duty injectors under similar injection conditions show several significant differences. The current data show a larger cone angle and lower penetration speed than that from the light-duty injector. Moreover, these data display a Gaussian mass distribution across the spray near the injector, whereas in previous light-duty injector measurements, the mass distribution had steeper sides and a flatter peak. Measurements are also used to examine the spray models in the STAR-CD software

Quantitative X-ray measurements of high-pressure fuel sprays from a production heavy duty diesel injector

Science.gov (United States)

Ramírez, A. I.; Som, S.; Aggarwal, Suresh K.; Kastengren, A. L.; El-Hannouny, E. M.; Longman, D. E.; Powell, C. F.

2009-07-01

A quantitative and time-resolved X-ray radiography technique has been used for detailed measurements of high-pressure fuel sprays in the near-nozzle region of a diesel engine injector. The technique provides high spatial and temporal resolution, especially in the relatively dense core region. A single spray plume from a hydraulically actuated electronically controlled unit injector model 315B injector with a 6-hole nozzle was isolated and studied at engine-like densities for two different injection pressures. Optical spray imaging was also employed to evaluate the effectiveness of the shield used to isolate a single spray plume. The steady state fuel distributions for both injection pressures are similar and show a dense spray region along the axis of the spray, with the on-axis spray density decreasing as the spray progresses downstream. The higher injection pressure case exhibits a larger cone angle and spray broadening at the exit of the nozzle. For some time periods, the near-nozzle penetration speed is lower for the high injection pressure case than the low injection pressure case, which is unexpected, but can be attributed to the needle and flow dynamics inside the injector causing slower pressure build-up for the former case. Rate of injection testing was performed to further understand near-nozzle behavior. Mass distribution data were obtained and used to find mass-averaged velocity of the spray. Comparisons of the radiography data with that from a common rail single-hole light duty injectors under similar injection conditions show several significant differences. The current data show a larger cone angle and lower penetration speed than that from the light-duty injector. Moreover, these data display a Gaussian mass distribution across the spray near the injector, whereas in previous light-duty injector measurements, the mass distribution had steeper sides and a flatter peak. Measurements are also used to examine the spray models in the STAR-CD software.

Temperature measurement in the sea

Digital Repository Service at National Institute of Oceanography (India)

Krishnamacharyulu, R.J.; Rao, L.V.G.

The importance of measuring sea temperature is explained and the various methods employed for this purpose are reviewed. Instruments used for spot measurement of water temperature at the sea surface and at discrete depths (bucket thermometer...

Feasibility Demonstration of Exciplex Fluorescence Measurements in Evaporating Laminar Sprays of Diesel Fuel

Science.gov (United States)

2011-05-15

code) 1 FEASIBILITY DEMONSTRATION OF EXCIPLEX FLUORESCENCE MEASUREMENTS IN EVAPORATING LAMINAR SPRAYS OF DIESEL FUEL Final Technical Report Grant...fluorescence is found to increase with temperature up to 538 K and then declines. Fluorescence from the liquid phase, i.e. the exciplex (Naphthalene+TMPD...to have as well characterized a description of the spray environment and assess conclusively the potential of the exciplex approach for more

The measurement of single particle temperature in plasma sprays

International Nuclear Information System (INIS)

Fincke, J.R.; Swank, W.D.; Bolsaitis, P.P.; Elliott, J.F.

1990-01-01

A measurement technique for simultaneously obtaining the size, velocity, temperature, and relative number density of particles entrained in high temperature flow fields is described. In determining the particle temperature from a two-color pyrometery technique, assumptions about the relative spectral emissivity of the particle are required. For situations in which the particle surface undergoes chemical reactions the assumption of grey body behavior is shown to introduce large Temperature measurement uncertainties. Results from isolated, laser heated, single particle measurements and in-flight data from the plasma spraying of WC-Co are presented. 10 refs., 5 figs

The origin of sea salt in snow on Arctic sea ice and in coastal regions

Directory of Open Access Journals (Sweden)

F. Domine

2004-01-01

Full Text Available Snow, through its trace constituents, can have a major impact on lower tropospheric chemistry, as evidenced by ozone depletion events (ODEs in oceanic polar areas. These ODEs are caused by the chemistry of bromine compounds that originate from sea salt bromide. Bromide may be supplied to the snow surface by upward migration from sea ice, by frost flowers being wind-blown to the snow surface, or by wind-transported aerosol generated by sea spray. We investigate here the relative importance of these processes by analyzing ions in snow near Alert and Ny-Ålesund (Canadian and European high Arctic in winter and spring. Vertical ionic profiles in the snowpack on sea ice are measured to test upward migration of sea salt ions and to seek evidence for ion fractionation processes. Time series of the ionic composition of surface snow layers are investigated to quantify wind-transported ions. Upward migration of unfractionated sea salt to heights of at least 17cm was observed in winter snow, leading to Cl- concentration of several hundred µM. Upward migration thus has the potential to supply ions to surface snow layers. Time series show that wind can deposit aerosols to the top few cm of the snow, leading also to Cl- concentrations of several hundred µM, so that both diffusion from sea ice and wind transport can significantly contribute ions to snow. At Ny-Ålesund, sea salt transported by wind was unfractionated, implying that it comes from sea spray rather than frost flowers. Estimations based on our results suggest that the marine snowpack contains about 10 times more Na+ than the frost flowers, so that both the marine snowpack and frost flowers need to be considered as sea salt sources. Our data suggest that ozone depletion chemistry can significantly enhance the Br- content of snow. We speculate that this can also take place in coastal regions and contribute to propagate ODEs inland. Finally, we stress the need to measure snow physical parameters

A two-wavelength imaging pyrometer for measuring particle temperature, velocity and size in thermal spray processes

International Nuclear Information System (INIS)

Craig, J.E.; Parker, R.A.; Lee, D.Y.; Biancaniello, F.; Ridder, S.

1999-01-01

An imaging pyrometer has been developed to measure the surface temperature of hot metal objects and to measure particle temperature, velocity and size in thermal spray, spray-fonning and atomization processes. The two-wavelength surface imaging pyrometer provides true temperature measurement with high resolution, even when the surface has emissivity variation caused by roughness or oxidation. The surface imaging pyrometer has been calibrated for use in a material processing lab calibration over the range of 1000 to 3000 deg K, and these results are described. The particle imaging pyrometer has a field of view that spans the entire particle stream in typical thermal spray devices, and provides continuous measurement of the entire particle stream. Particle temperature and velocity are critical parameters for producing high quality spray coatings efficiently and reliably. The software locates the particle streaks in the image, and determines the intensity ratio for each particle streak pair to obtain the temperature. The dimensions of the particle streak image are measured to determine the velocity and size. Because the vision-based sensor samples the entire particle stream in every video frame, the particle temperature, velocity and size data are updated at 30 Hz at all points in the particle stream. Particle measurements in a plasma spray at NIST are described. In this paper, we will describe our experiments with ceramic powders, in which measurements have been made at several positions along the particle stream. The particle data are represented as profiles across the particle stream, histograms of the full particle stream or time histories of the full-stream average. The results are compared and calibrated with other temperature and diagnostic measurement systems. (author)

Synchronized droplet size measurements for Coal-Water-Slurry (CWS) diesel sprays of an electronically-controlled fuel injection system

Science.gov (United States)

Kihm, K. D.; Terracina, D. P.; Payne, S. E.; Caton, J. A.

Experiments were completed to study intermittent coal-water slurry (CWS) fuel sprays injected from an electronically-controlled accumulator injector system. A laser diffraction particle analyzing (LDPA) technique was used to measure the spray diameters (Sauter mean diameter, SMD) assuming the Rosin-Rammler two parameter model. In order to ensure an accurate synchronization of the measurement with the intermittent sprays, a new synchronization technique was developed using the light extinction signal as a triggering source for the data taking initiation. This technique allowed measurement of SMD's near the spray tip where the light extinction was low and the data were free from the multiscattering bias. Coal-water slurry fuel with 50% coal loading in mass containing 5 (mu)m mass median diameter coal particulates was considered. Injection pressures ranging from 28 to 110 MPa, two different nozzle orifice diameters, 0.2 ad 0.4 mm, and four axial measurement locations from 60 to 120 mm from the nozzle orifice were studied. Measurements were made for pressurized (2.0 MPa in gauge) and for ambient chamber conditions. The spray SMD showed an increase with the distance of the axial measurement location and with the ambient gas density, and showed a decrease with increasing injection pressure. A correlation of the Sauter mean diameter with the injection conditions was determined. The results were also compared with previous SMD correlations that were available only for diesel fuel sprays.

Potential role of sea spray generation in the atmospheric transport of perfluorocarboxylic acids.

Science.gov (United States)

Webster, Eva; Ellis, David A

2010-08-01

The observed environmental concentrations of perfluorooctanoic acid (PFOA) and its conjugate base (PFO) in remote regions such as the Arctic have been primarily ascribed to the atmospheric transport and degradation of fluorotelomer alcohols (FTOHs) and to direct PFO transport in ocean currents. These mechanisms are each capable of only partially explaining observations. Transport within marine aerosols has been proposed and may explain transport over short distances but will contribute little over longer distances. However, PFO(A) has been shown to have a very short half-life in aqueous aerosols and thus sea spray was proposed as a mechanism for the generation of PFOA in the gas phase from PFO in a water body. Using the observed PFO concentrations in oceans of the Northern Hemisphere and estimated spray generation rates, this mechanism is shown to have the potential for contributing large amounts of PFOA to the atmosphere and may therefore contribute significantly to the concentrations observed in remote locations. Specifically, the rate of PFOA release into the gas phase from oceans in the Northern Hemisphere is calculated to be potentially comparable to global stack emissions to the atmosphere. The subsequent potential for atmospheric degradation of PFOA and its global warming potential are considered. Observed isomeric ratios and predicted atmospheric concentrations due to FTOH degradation are used to elucidate the likely relative importance of transport pathways. It is concluded that gas phase PFOA released from oceans may help to explain observed concentrations in remote regions. The model calculations performed in the present study strongly suggest that oceanic aerosol and gas phase field monitoring is of vital importance to obtain a complete understanding of the global dissemination of PFCAs. Copyright 2010 SETAC

Diesel spray characterization; Dieselmoottorin polttoainesuihkujen ominaisuudet

Energy Technology Data Exchange (ETDEWEB)

Pitkaenen, J.; Turunen, R.; Paloposki, T.; Rantanen, P.; Virolainen, T. [Helsinki Univ. of Technology, Otaniemi (Finland). Internal Combustion Engine Lab.

1997-10-01

Fuel injection of diesel engines will be studied using large-scale models of fuel injectors. The advantage of large-scale models is that the measurement of large-scale diesel sprays will be easier than the measurement of actual sprays. The objective is to study the break-up mechanism of diesel sprays and to measure drop size distributions in the inner part of the spray. The results will be used in the development of diesel engines and diesel fuels. (orig.)

Optical measurements in rocket engine liquid sprays

Science.gov (United States)

Feikema, Douglas A.

1994-01-01

The performance of liquid propellant rocket engines is dependent upon many elements of the entire system. One of the most fundamental and most critical is the performance of the injector elements. Their characterization is an important part of the development of combustion devices. Optical measurements within these environments have proven to be invaluable tools in quantifying the physical environment of two phase flows. The effort reported herein involves the measurement of drop velocity, drop size, and most importantly mass flux using Phase-Doppler Particle Anemometry within a spray generated by a single swirl injector element operating in atmospheric pressure conditions. The mass flux has been determined and validated by mechanical patternation methods and by profile integration of the mass flux.

A real-time assessment of measurement uncertainty in the experimental characterization of sprays

International Nuclear Information System (INIS)

Panão, M R O; Moreira, A L N

2008-01-01

This work addresses the estimation of the measurement uncertainty of discrete probability distributions used in the characterization of sprays. A real-time assessment of this measurement uncertainty is further investigated, particularly concerning the informative quality of the measured distribution and the influence of acquiring additional information on the knowledge retrieved from statistical analysis. The informative quality is associated with the entropy concept as understood in information theory (Shannon entropy), normalized by the entropy of the most informative experiment. A new empirical correlation is derived between the error accuracy of a discrete cumulative probability distribution and the normalized Shannon entropy. The results include case studies using: (i) spray impingement measurements to study the applicability of the real-time assessment of measurement uncertainty, and (ii) the simulation of discrete probability distributions of unknown shape or function to test the applicability of the new correlation

Measurement of the non-thermal properties of a low pressure spraying plasma by electric and spectroscopic methods

International Nuclear Information System (INIS)

Jung, Yong Ho

2003-02-01

For the case of an atmospheric plasma, the local thermodynamic equilibrium (LTE) model can be applied to plasmas at a nozzle entrance and to those on the axis of the plasma flame, but it is not easy to justify applying the LTE model to off-center plasma and to a low-pressure spraying plasma. Although the energy distribution of the electrons is assumed to be Maxwellian for the most of spraying plasmas, the non-Maxwellian distribution is possible for the case of low-pressure spaying plasma and edge plasma of atmospheric spraying plasma. In this work, the non-Maxwellian distribution of electrons was measured by using an electric probe installed on the fast scanning probe system, and non-LTE effects were measured by using the optical emission spectroscopy system. Distribution of the electrons of a low-pressure spraying plasma is observed not as Maxwellian but as bi-Maxwellian by the measurement of the single probe. Bi-Maxwellian distribution appears in the edge of a low pressure spraying plasma and seems to be due to the reduction of the collisonality by the drastic variation of the plasma density. Non-LTE characteristics of a low-pressure spraying plasma can be deuced from the measured results of the optical emission spectroscopy and is analyzed by the collisional radiative equilibrium (CRE) model, where the Maxwellian and the non-Maxwellian distributions are assumed for comparison. For the electron temperature, the results from optical emission spectroscopy were similar to the results from the single probe (3∼5 % in error)

In Situ Acoustic Monitoring of Thermal Spray Process Using High-Frequency Impulse Measurements

Science.gov (United States)

Tillmann, Wolfgang; Walther, Frank; Luo, Weifeng; Haack, Matthias; Nellesen, Jens; Knyazeva, Marina

2018-01-01

In order to guarantee their protective function, thermal spray coatings must be free from cracks, which expose the substrate surface to, e.g., corrosive media. Cracks in thermal spray coatings are usually formed because of tensile residual stresses. Most commonly, the crack occurrence is determined after the thermal spraying process by examination of metallographic cross sections of the coating. Recent efforts focus on in situ monitoring of crack formation by means of acoustic emission analysis. However, the acoustic signals related to crack propagation can be absorbed by the noise of the thermal spraying process. In this work, a high-frequency impulse measurement technique was applied to separate different acoustic sources by visualizing the characteristic signal of crack formation via quasi-real-time Fourier analysis. The investigations were carried out on a twin wire arc spraying process, utilizing FeCrBSi as a coating material. The impact of the process parameters on the acoustic emission spectrum was studied. Acoustic emission analysis enables to obtain global and integral information on the formed cracks. The coating morphology and coating defects were inspected using light microscopy on metallographic cross sections. Additionally, the resulting crack patterns were imaged in 3D by means of x-ray microtomography.

Characterization of sprayed CuInS2 films by XRD and Raman spectroscopy measurements

International Nuclear Information System (INIS)

Lee, Dong-Yeup; Kim, JunHo

2010-01-01

We studied CuInS 2 (CIS) film growth using two deposition methods, which were high electrostatic field assisted ultrasonic spray (HEFAUS) deposition and sulfurization of Cu-In metallic film. The sprayed-films were grown with chalcopyrite ordering and Cu-Au ordering mixed. In order to obtain higher quality CIS films, post-sulfurization was carried out for sprayed-films. The post-sulfurization induced improvement of crystallinity and enhancement of chalcopyrite ordering. However, it was observed that Cu-Au ordering still coexisted in the CIS film after post-sulfurization. With the same sulfurization condition, sulfurization was done to transform Cu-In metallic film into CIS film. The sulfurized metallic film was turned out to be formed as CIS film with higher crystallinity and better chalcopyrite ordering than sulfurized sprayed-films. All fabricated films were characterized by X-ray diffraction, Raman scattering, scanning electron microscope and energy dispersive X-ray analysis measurements.

The role of jet and film drops in controlling the mixing state of submicron sea spray aerosol particles

Energy Technology Data Exchange (ETDEWEB)

Wang, Xiaofei; Deane, Grant B.; Moore, Kathryn A.; Ryder, Olivia S.; Stokes, M. Dale; Beall, Charlotte M.; Collins, Douglas B.; Santander, Mitchell V.; Burrows, Susannah M.; Sultana, Camille M.; Prather, Kimberly A.

2017-06-19

Covering 71% of the Earth’s surface, oceans represent a significant global source of atmospheric aerosols. The size and composition of sea spray aerosols (SSA) affect their ability to serve as cloud seeds and thus understanding the factors controlling their composition is critical to predicting their impact on clouds and climate. SSA particles have been shown to be an external mixture of particles with different compositions. Film and jet drop production mechanisms ultimately determine the individual particle compositions which are comprised of an array of salt/organic mixtures ranging from pure sea salt to nearly pure organic particles. It is often assumed that the majority of submicron SSA are formed by film drops produced from bursting hydrophobic organic-rich bubble film caps at the sea surface, and in contrast, jet drops are postulated to produce larger supermicron particles from underlying seawater comprised largely of salts and water soluble organic species. However, here we show that jet drops produced by bursting sub-100 m bubbles account for up to 40 % of all submicron particles. They have distinct chemical compositions, organic volume fractions and ice nucleating activities from submicron film drops. Thus a substantial fraction of submicron particles will not necessarily be controlled by the composition of the sea surface microlayer as has been assumed in many studies. This finding has significant ramifications for the size-resolved mixing states of SSA particles which must be taken into consideration when accessing SSA impacts on clouds.

MEASUREMENTS IN A LIQUID ATOMISER SPRAY USING THE PHASE-DOPPLER PARTICLE ANALYSER

Directory of Open Access Journals (Sweden)

R HADEF

2000-12-01

Full Text Available Experiments have been carried out at atmospheric conditions using a water atomiser spray. A phase Doppler anemometry was used to perform the measurements of the droplets size, their velocity and concentration, and photographs were taken.  The results showed that the small particles with low turbulence occupied the central core of the jet displaying a Gaussian profile for the axial velocity component.  The large particles were defected towards the outer edges of the jet, due to their higher initial momentum, and displayed relatively high levels of turbulence. The variables measured show that their spatial distributions were nearly symmetrical about the x-axis and although the number density of the droplets is very high in the centred region, most of the pulverised liquid was present in the edges of the spray.

The organic fraction of bubble-generated, accumulation mode Sea Spray Aerosol (SSA

Directory of Open Access Journals (Sweden)

R. L. Modini

2010-03-01

Full Text Available Recent studies have detected a dominant accumulation mode (~100 nm in the Sea Spray Aerosol (SSA number distribution. There is evidence to suggest that particles in this mode are composed primarily of organics. To investigate this hypothesis we conducted experiments on NaCl, artificial SSA and natural SSA particles with a Volatility-Hygroscopicity-Tandem-Differential-Mobility-Analyser (VH-TDMA. NaCl particles were atomiser generated and a bubble generator was constructed to produce artificial and natural SSA particles. Natural seawater samples for use in the bubble generator were collected from biologically active, terrestrially-affected coastal water in Moreton Bay, Australia. Differences in the VH-TDMA-measured volatility curves of artificial and natural SSA particles were used to investigate and quantify the organic fraction of natural SSA particles. Hygroscopic Growth Factor (HGF data, also obtained by the VH-TDMA, were used to confirm the conclusions drawn from the volatility data. Both datasets indicated that the organic fraction of our natural SSA particles evaporated in the VH-TDMA over the temperature range 170–200 °C. The organic volume fraction for 71–77 nm natural SSA particles was 8±6%. Organic volume fraction did not vary significantly with varying water residence time (40 s to 24 h in the bubble generator or SSA particle diameter in the range 38–173 nm. At room temperature we measured shape- and Kelvin-corrected HGF at 90% RH of 2.46±0.02 for NaCl, 2.35±0.02 for artifical SSA and 2.26±0.02 for natural SSA particles. Overall, these results suggest that the natural accumulation mode SSA particles produced in these experiments contained only a minor organic fraction, which had little effect on hygroscopic growth. Our measurement of 8±6% is an order of magnitude below two previous measurements of the organic fraction in SSA particles of comparable sizes. We stress that our results were obtained using coastal seawater and

Wintertime Arctic Ocean sea water properties and primary marine aerosol concentrations

Directory of Open Access Journals (Sweden)

J. Zábori

2012-11-01

Full Text Available Sea spray aerosols are an important part of the climate system through their direct and indirect effects. Due to the diminishing sea ice, the Arctic Ocean is one of the most rapidly changing sea spray aerosol source areas. However, the influence of these changes on primary particle production is not known.

In laboratory experiments we examined the influence of Arctic Ocean water temperature, salinity, and oxygen saturation on primary particle concentration characteristics. Sea water temperature was identified as the most important of these parameters. A strong decrease in sea spray aerosol production with increasing water temperature was observed for water temperatures between −1°C and 9°C. Aerosol number concentrations decreased from at least 1400 cm⁻³ to 350 cm⁻³. In general, the aerosol number size distribution exhibited a robust shape with one mode close to dry diameter D_p 0.2 μm with approximately 45% of particles at smaller sizes. Changes in sea water temperature did not result in pronounced change of the shape of the aerosol size distribution, only in the magnitude of the concentrations. Our experiments indicate that changes in aerosol emissions are most likely linked to changes of the physical properties of sea water at low temperatures. The observed strong dependence of sea spray aerosol concentrations on sea water temperature, with a large fraction of the emitted particles in the typical cloud condensation nuclei size range, provide strong arguments for a more careful consideration of this effect in climate models.

Atmospheric Spray Freeze-Drying: Numerical Modeling and Comparison With Experimental Measurements.

Science.gov (United States)

Borges Sebastião, Israel; Robinson, Thomas D; Alexeenko, Alina

2017-01-01

Atmospheric spray freeze-drying (ASFD) represents a novel approach to dry thermosensitive solutions via sublimation. Tests conducted with a second-generation ASFD equipment, developed for pharmaceutical applications, have focused initially on producing a light, fine, high-grade powder consistently and reliably. To better understand the heat and mass transfer physics and drying dynamics taking place within the ASFD chamber, 3 analytical models describing the key processes are developed and validated. First, by coupling the dynamics and heat transfer of single droplets sprayed into the chamber, the velocity, temperature, and phase change evolutions of these droplets are estimated for actual operational conditions. This model reveals that, under typical operational conditions, the sprayed droplets require less than 100 ms to freeze. Second, because understanding the heat transfer throughout the entire freeze-drying process is so important, a theoretical model is proposed to predict the time evolution of the chamber gas temperature. Finally, a drying model, calibrated with hygrometer measurements, is used to estimate the total time required to achieve a predefined final moisture content. Results from these models are compared with experimental data. Copyright © 2016 American Pharmacists Association®. Published by Elsevier Inc. All rights reserved.

Direct aerosol chemical composition measurements to evaluate the physicochemical differences between controlled sea spray aerosol generation schemes

Directory of Open Access Journals (Sweden)

D. B. Collins

2014-11-01

Full Text Available Controlled laboratory studies of the physical and chemical properties of sea spray aerosol (SSA must be under-pinned by a physically and chemically accurate representation of the bubble-mediated production of nascent SSA particles. Bubble bursting is sensitive to the physico-chemical properties of seawater. For a sample of seawater, any important differences in the SSA production mechanism are projected into the composition of the aerosol particles produced. Using direct chemical measurements of SSA at the single-particle level, this study presents an intercomparison of three laboratory-based, bubble-mediated SSA production schemes: gas forced through submerged sintered glass filters ("frits", a pulsed plunging-waterfall apparatus, and breaking waves in a wave channel filled with natural seawater. The size-resolved chemical composition of SSA particles produced by breaking waves is more similar to particles produced by the plunging waterfall than those produced by sintered glass filters. Aerosol generated by disintegrating foam produced by sintered glass filters contained a larger fraction of organic-enriched particles and a different size-resolved elemental composition, especially in the 0.8–2 μm dry diameter range. Interestingly, chemical differences between the methods only emerged when the particles were chemically analyzed at the single-particle level as a function of size; averaging the elemental composition of all particles across all sizes masked the differences between the SSA samples. When dried, SSA generated by the sintered glass filters had the highest fraction of particles with spherical morphology compared to the more cubic structure expected for pure NaCl particles produced when the particle contains relatively little organic carbon. In addition to an intercomparison of three SSA production methods, the role of the episodic or "pulsed" nature of the waterfall method on SSA composition was under-taken. In organic

Simultaneous two-phase flow measurement of spray mixing process by means of high-speed two-color PIV

International Nuclear Information System (INIS)

Zhang, Ming; Xu, Min; Hung, David L S

2014-01-01

In this article, a novel high-speed two-color PIV optical diagnostic technique has been developed and applied to simultaneously measure the velocity flow-fields of a multi-hole spark-ignition direct injection (SIDI) fuel injector spray and its ambient gas in a high-pressure constant volume chamber. To allow for the phase discrimination between the fuel droplets and ambient gas, a special tracer-filter system was designed. Fluorescent seeding particles with Sauter mean diameter (SMD) of 4.8 µm were used to trace the gas inside the chamber. With a single high-speed Nd:YLF laser sheet (527 nm) as the incident light source, the Mie-scattering signal marked the phase of the fuel spray, while the fluorescent signal generated from the seeding particles tracked the phase of ambient gas. A high-speed camera, with an image-doubler (mounted in front of the camera lens) that divided the camera pixels into two parts focusing on the same field of view, was used to collect the Mie-scattering signal and LIF (laser induced fluorescence) signal simultaneously with two carefully selected optical filters. To accommodate the large dynamic range of velocities in the two phases (1–2 orders of magnitude difference), two separation times (dt) were introduced. This technique was successfully applied to the liquid spray and ambient gas two-phase flow measurement. The measurement accuracy was compared with those from LDV (laser Doppler velocimetry) measurement and good agreement was obtained. Ambient gas motion surrounding the fuel spray was investigated and characterized into three zones. The momentum transfer process between the fuel spray and ambient gas in each zone was analyzed. The two-phase flow interaction under various superheated conditions was investigated. A strengthened momentum transfer from the liquid spray to the ambient was observed with increased superheat degree. (paper)

Sea ice draft in the Weddell Sea, measured by upward looking sonars

Directory of Open Access Journals (Sweden)

A. Behrendt

2013-06-01

Full Text Available The presented database contains time-referenced sea ice draft values from upward looking sonar (ULS measurements in the Weddell Sea, Antarctica. The sea ice draft data can be used to infer the thickness of the ice. They were collected during the period 1990–2008. In total, the database includes measurements from 13 locations in the Weddell Sea and was generated from more than 3.7 million measurements of sea ice draft. The files contain uncorrected raw drafts, corrected drafts and the basic parameters measured by the ULS. The measurement principle, the data processing procedure and the quality control are described in detail. To account for the unknown speed of sound in the water column above the ULS, two correction methods were applied to the draft data. The first method is based on defining a reference level from the identification of open water leads. The second method uses a model of sound speed in the oceanic mixed layer and is applied to ice draft in austral winter. Both methods are discussed and their accuracy is estimated. Finally, selected results of the processing are presented. The data can be downloaded from doi:10.1594/PANGAEA.785565.

Water spray interaction with air-steam mixtures under containment spray conditions: experimental study in the TOSQAN facility

Energy Technology Data Exchange (ETDEWEB)

Porcheron, E.; Lemaitre, P.; Malet, J.; Nuboer, A.; Brun, P.; Bouilloux, L.; Vendel, J. [Institut de Radioprotection et de Surete Nucleaire (IRSN), Direction de la Surete des Usines, des laboratoires, des transports et des dechets, Saclay, BP 68 - 91192 Gif-sur-Yvette cedex (France)

2005-07-01

Full text of publication follows: During the course of an hypothetical severe accident in a Pressurized Water Reactor (PWR), hydrogen can be produced by the reactor core oxidation and distributed into the reactor containment according to convection flows and steam wall condensation. In order to assess the risk of detonation generated by a high local hydrogen concentration, hydrogen distribution in the containment has to be known. The TOSQAN experimental program has been created to simulate typical accidental thermal hydraulic flow conditions in the reactor containment. The present work is devoted to study the interaction of a water spray injection used as a mitigation mean in order to reduce containment pressure and to produce a mixing of air, steam and hydrogen induced by spray entrainment and condensation on droplet. In order to have a better understanding of physical phenomena, we need to make a detailed characterization of the spray and the gas. The TOSQAN facility that is highly instrumented with non-intrusive diagnostics consists in a closed cylindrical vessel (7 m{sup 3} volume, 4 m high, 1.5 m i.d.) into which steam is injected. Water droplets size is measured in the vessel by the Interferometric Laser Imaging for Droplet Sizing technique. Droplet velocity is obtained by Particle Image Velocimetry and Laser Doppler Velocimetry, and droplet temperature is measured by global rainbow refractometry. Gas concentration measurements are performed by Spontaneous Raman Scattering. The walls of the vessel are thermostatically controlled by heated oil circulation. Inner spray system that is located on the top of the enclosure on the vertical axis, is composed of a single nozzle producing a full cone water spray. Spray test scenario consists of water spray injection in TOSQAN that is first pressurized with a steam injection (steam injection is stopped before spray injection). Water spray falling into the sump is removed to avoid accumulation and evaporation

Time-resolved measurements of supersonic fuel sprays using synchrotron X-rays.

Science.gov (United States)

Powell, C F; Yue, Y; Poola, R; Wang, J

2000-11-01

A time-resolved radiographic technique has been developed for probing the fuel distribution close to the nozzle of a high-pressure single-hole diesel injector. The measurement was made using X-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution of better than 1 micros. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date.

First biological measurements of deep-sea corals from the Red Sea

OpenAIRE

C. Roder; M. L. Berumen; J. Bouwmeester; E. Papathanassiou; A. Al-Suwailem; C. R. Voolstra

2013-01-01

It is usually assumed that metabolic constraints restrict deep-sea corals to cold-water habitats, with ?deep-sea? and ?cold-water? corals often used as synonymous. Here we report on the first measurements of biological characters of deep-sea corals from the central Red Sea, where they occur at temperatures exceeding 20?C in highly oligotrophic and oxygen-limited waters. Low respiration rates, low calcification rates, and minimized tissue cover indicate that a reduced metabolism is one of the ...

Inland Sea Spray Aerosol Transport and Incomplete Chloride Depletion: Varying Degrees of Reactive Processing Observed during SOAS

Energy Technology Data Exchange (ETDEWEB)

Bondy, Amy L. [Department; Wang, Bingbing [Environmental; Laskin, Alexander [Environmental; Craig, Rebecca L. [Department; Nhliziyo, Manelisi V. [Department; Bertman, Steven B. [Department; Pratt, Kerri A. [Department; Shepson, Paul B. [Departments; Ault, Andrew P. [Department; Department

2017-08-08

Multiphase reactions involving sea spray aerosol (SSA) impact trace gases budgets in coastal regions by acting as a reservoir for oxidized nitrogen and sulfur species, as well as a source of halogen gases (HCl, ClNO2, etc.). While most studies of multiphase reactions on SSA have focused on marine environments, far less is known about SSA transported inland. Herein, single particle measurements of SSA are reported at a site > 320 km from the Gulf of Mexico, with transport times of 7-68 h. Samples were collected during the Southern Oxidant and Aerosol Study (SOAS) in June-July 2013 near Centreville, Alabama. SSA was observed in 93% of 42 time periods analyzed. During two marine air mass periods, SSA represented significant number fractions of particles in the accumulation (0.2-1.0 μm, 11%) and coarse (1.0-10.0 μm, 35%) modes. Chloride content of SSA particles ranged from full to partial depletion, with 24% of SSA particles containing chloride (mole fraction of Cl/Na > 0.1, 90% chloride depletion). Both the frequent observation of SSA at an inland site and the range of chloride depletion observed, suggest that SSA may represent an underappreciated inland sink for NOx/SO2 and source of halogen gases.

Three-dimensional measurement of the local extinction coefficient in a dense spray

International Nuclear Information System (INIS)

Wellander, Rikard; Berrocal, Edouard; Kristensson, Elias; Richter, Mattias; Aldén, Marcus

2011-01-01

Laser extinction, signal attenuation and multiple scattering are the three main phenomena limiting qualitative and quantitative measurements in planar laser imaging of sprays. In this paper, a method is presented where structured laser illumination planar imaging is used to remove the signal contribution from multiply scattered light. Based on this technique, data from side scattering and transmission measurements are obtained simultaneously. An algorithm, compensating for signal attenuation and laser extinction, is further applied to calculate the local extinction coefficient. The method is first demonstrated on a cuvette containing a homogeneous solution of scattering particles with an extinction coefficient μ-bar e = 0.13 mm −1 . Finally the procedure is applied on an air-assisted water spray with a maximum optical depth of OD ∼ 3, where the position-dependent extinction coefficient is extracted within the probed volume. To the best of our knowledge, this paper demonstrates for the first time a method to measure the local μ-bar e within the three dimensions of an inhomogeneous scattering medium using laser sheet illumination, after suppression of the multiple light scattering intensity

Residual stress measurements of 2-phase sprayed coating layer

International Nuclear Information System (INIS)

Nishida, Masayuki; Hanabusa, Takao

1997-01-01

In a series of the already reported single phase metal and ceramic melt sprayed films, on two phase melt sprayed films, their stress and thermal stress changes due to their bending load are tried to test. In order to prepare two phase state, austenitic stainless steel wire is used by a laser melt spraying method. In this method, CO 2 laser is used for a thermal source, and proceeding direction of its laser is selected to cross melt spraying direction. As a result, the following facts can be elucidated. The stress values at α- and γ-phase in the stainless steel film are linearly responsive to the bending load, and the stress change in α-phase is smaller than that in γ-phase. In a heat and cool cycle, α-phase shows a trend of extension with increasing temperature but γ-phase shows a trend of compression inversely. And, stress behavior at α- and γ-phases in the stainless steel film does not agree with a mixing rule in common two-phase materials. (G.K.)

Molecular Diversity of Sea Spray Aerosol Particles: Impact of Ocean Biology on Particle Composition and Hygroscopicity

Energy Technology Data Exchange (ETDEWEB)

Cochran, Richard E.; Laskina, Olga; Trueblood, Jonathan; Estillore, Armando D.; Morris, Holly S.; Jayarathne, Thilina; Sultana, Camile M.; Lee, Christopher; Lin, Peng; Laskin, Julia; Laskin, Alexander; Dowling, Jackie; Qin, Zhen; Cappa, Christopher; Bertram, Timothy; Tivanski, Alexei V.; Stone, Elizabeth; Prather, Kimberly; Grassian, Vicki H.

2017-05-01

The impact of sea spray aerosol (SSA) on climate depends on the size and chemical composition of individual particles that make-up the total SSA ensemble. While the organic fraction of SSA has been characterized from a bulk perspective, there remains a lack of understanding as to the composition of individual particles within the SSA ensemble. To better understand the molecular components within SSA particles and how SSA composition changes with ocean biology, simultaneous measurements of seawater and SSA were made during a month-long mesocosm experiment performed in an ocean-atmosphere facility. Herein, we deconvolute the composition of freshly emitted SSA devoid of anthropogenic and terrestrial influences by characterizing classes of organic compounds as well as specific molecules within individual SSA particles. Analysis of SSA particles show that the diversity of molecules within the organic fraction varies between two size fractions (submicron and supermicron) with contributions from fatty acids, monosaccharides, polysaccharides and siliceous material. Significant changes in the distribution of these compounds within individual particles are observed to coincide with the rise and fall of phytoplankton and bacterial populations within the seawater. Furthermore, water uptake is impacted as shown by hygroscopicity measurements of model systems composed of representative organic compounds. Thus, the how changes in the hygroscopic growth of SSA evolves with composition can be elucidated. Overall, this study provides an important connection between biological processes that control the composition of seawater and changes in single particle composition which will enhances our ability to predict the impact of SSA on climate.

Corrosion prevention of the rail by thermal spray coating of Zn-Al alloy; Zn-Al gokin yosha hifuku ni yoru reru no boshoku

Energy Technology Data Exchange (ETDEWEB)

Mizoguchi, S. [Nippon Steel Corp., Kitakyushu (Japan)] Urashima, C. [Kyushu Techno Research Corp., Fukuoka (Japan); Itai, K. [Nippon Steel Corp., Kitakyushu, Fukuoka (Japan). Technical Research Inst. of Yawata Works; Ichiriki, T.; Nishiki, M. [Kyushu Rail way comdany, Fukuoka (Japan)

1997-03-30

Replacement of the rail in under-sea tunnel such as the Kammon Tunnel is carried out very five years because of the severe corrosion caused by the humid state due to the leakage of sea water or the mist of sea water swept up by the passing trains. In this study, salt water spraying or sea water spraying test is carried out using Zn-Al alloy with the corrosion resistance and thermal spray efficiency even higher than those of Zn or Al. A rail coated by thermal spray of Zn-15mass%Al alloy has been laid by trial in the practical rail road of Kammon Tunnel for 5 years and 3 months, the deterioration degree of the coating, pitting depth, actual fatigue strength, etc. are evaluated. Further, these factors of a rail re-coated by Zincrich Primer+Tar Epoxy and a bare rail laid at the same time are evaluated for comparison. It is presumed by the results of the examination about the service life of a rail coated by the thermal spray of Zn-Al alloy based on the pitting depth in the rail base that the service life of such coated rail is more than twice as that of the bare rails used currently. 5 refs., 14 figs., 3 tabs.

Direct morphological comparison of vacuum plasma sprayed and detonation gun sprayed hydroxyapatite coatings for orthopaedic applications.

Science.gov (United States)

Gledhill, H C; Turner, I G; Doyle, C

1999-02-01

Hydroxyapatite coatings on titanium substrates were produced using two thermal spray techniques vacuum plasma spraying and detonation gun spraying. X-ray diffraction was used to compare crystallinity and residual stresses in the coatings. Porosity was measured using optical microscopy in conjunction with an image analysis system. Scanning electron microscopy and surface roughness measurements were used to characterise the surface morphologies of the coatings. The vacuum plasma sprayed coatings were found to have a lower residual stress, a higher crystallinity and a higher level of porosity than the detonation gun coatings. It is concluded that consideration needs to be given to the significance of such variations within the clinical context.

Time-resolved measurements of supersonic fuel sprays using synchrotron x-rays

International Nuclear Information System (INIS)

Powell, C.F.; Yue, Y.; Poola, R.; Wang, J.

2000-11-01

A time-resolved radiographic technique has been developed for probing the fuel distribution close to the nozzle of a high-pressure single-hole diesel injector. The measurement was made using X-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution of better than 1 μs. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date

Novel method for the measurement of liquid film thickness during fuel spray impingement on surfaces.

Science.gov (United States)

Henkel, S; Beyrau, F; Hardalupas, Y; Taylor, A M K P

2016-02-08

This paper describes the development and application of a novel optical technique for the measurement of liquid film thickness formed on surfaces during the impingement of automotive fuel sprays. The technique makes use of the change of the light scattering characteristics of a metal surface with known roughness, when liquid is deposited. Important advantages of the technique over previously established methods are the ability to measure the time-dependent spatial distribution of the liquid film without a need to add a fluorescent tracer to the liquid, while the measurement principle is not influenced by changes of the pressure and temperature of the liquid or the surrounding gas phase. Also, there is no need for non-fluorescing surrogate fuels. However, an in situ calibration of the dependence of signal intensity on liquid film thickness is required. The developed method can be applied to measure the time-dependent and two-dimensional distribution of the liquid fuel film thickness on the piston or the liner of gasoline direct injection (GDI) engines. The applicability of this technique was evaluated with impinging sprays of several linear alkanes and alcohols with different thermo-physical properties. The surface temperature of the impingement plate was controlled to simulate the range of piston surface temperatures inside a GDI engine. Two sets of liquid film thickness measurements were obtained. During the first set, the surface temperature of the plate was kept constant, while the spray of different fuels interacted with the surface. In the second set, the plate temperature was adjusted to match the boiling temperature of each fuel. In this way, the influence of the surface temperature on the liquid film created by the spray of different fuels and their evaporation characteristics could be demonstrated.

Development of nonintrusive, scatter-independent techniques for measurement of liquid density inside dense sprays

Science.gov (United States)

Hartfield, Roy

1994-01-01

A nonintrusive optical technique for measuring the liquid density in sprays used to simulate LOX injector flows is under development. This manuscript is a report on work toward that development which is currently in progress. The technique is a scatter-independent, absorption-based approach which depends on the numerical inversion of a collection of absorption profiles. For the case in which visible radiation passes through liquid-gas interfaces so numerous in sprays, substantial reductions and alterations in the signal result from scattering even in the absence of absorption. To avoid these problems, X-Rays will be used as the absorbed radiation. The experimental process is simulated by integrating the absorption spectrum for a known distribution, adding instrument noise to this 'measurement', creating a projection from the 'measurement', filtering the projection, inverting the projection, and comparing the results with the original prescribed distribution.

First biological measurements of deep-sea corals from the Red Sea.

Science.gov (United States)

Roder, C; Berumen, M L; Bouwmeester, J; Papathanassiou, E; Al-Suwailem, A; Voolstra, C R

2013-10-03

It is usually assumed that metabolic constraints restrict deep-sea corals to cold-water habitats, with 'deep-sea' and 'cold-water' corals often used as synonymous. Here we report on the first measurements of biological characters of deep-sea corals from the central Red Sea, where they occur at temperatures exceeding 20°C in highly oligotrophic and oxygen-limited waters. Low respiration rates, low calcification rates, and minimized tissue cover indicate that a reduced metabolism is one of the key adaptations to prevailing environmental conditions. We investigated four sites and encountered six species of which at least two appear to be undescribed. One species is previously reported from the Red Sea but occurs in deep cold waters outside the Red Sea raising interesting questions about presumed environmental constraints for other deep-sea corals. Our findings suggest that the present understanding of deep-sea coral persistence and resilience needs to be revisited.

First biological measurements of deep-sea corals from the Red Sea.

KAUST Repository

Roder, Cornelia

2013-10-03

It is usually assumed that metabolic constraints restrict deep-sea corals to cold-water habitats, with \\'deep-sea\\' and \\'cold-water\\' corals often used as synonymous. Here we report on the first measurements of biological characters of deep-sea corals from the central Red Sea, where they occur at temperatures exceeding 20°C in highly oligotrophic and oxygen-limited waters. Low respiration rates, low calcification rates, and minimized tissue cover indicate that a reduced metabolism is one of the key adaptations to prevailing environmental conditions. We investigated four sites and encountered six species of which at least two appear to be undescribed. One species is previously reported from the Red Sea but occurs in deep cold waters outside the Red Sea raising interesting questions about presumed environmental constraints for other deep-sea corals. Our findings suggest that the present understanding of deep-sea coral persistence and resilience needs to be revisited.

A multi-model assessment of the impact of sea spray geoengineering on cloud droplet number

Directory of Open Access Journals (Sweden)

K. J. Pringle

2012-12-01

Full Text Available Artificially increasing the albedo of marine boundary layer clouds by the mechanical emission of sea spray aerosol has been proposed as a geoengineering technique to slow the warming caused by anthropogenic greenhouse gases. A previous global model study (Korhonen et al., 2010 found that only modest increases (< 20% and sometimes even decreases in cloud drop number (CDN concentrations would result from emission scenarios calculated using a windspeed dependent geoengineering flux parameterisation. Here we extend that work to examine the conditions under which decreases in CDN can occur, and use three independent global models to quantify maximum achievable CDN changes. We find that decreases in CDN can occur when at least three of the following conditions are met: the injected particle number is < 100 cm⁻³, the injected diameter is > 250–300 nm, the background aerosol loading is large (≥ 150 cm⁻³ and the in-cloud updraught velocity is low (< 0.2 m s⁻¹. With lower background loadings and/or increased updraught velocity, significant increases in CDN can be achieved. None of the global models predict a decrease in CDN as a result of geoengineering, although there is considerable diversity in the calculated efficiency of geoengineering, which arises from the diversity in the simulated marine aerosol distributions. All three models show a small dependence of geoengineering efficiency on the injected particle size and the geometric standard deviation of the injected mode. However, the achievability of significant cloud drop enhancements is strongly dependent on the cloud updraught speed. With an updraught speed of 0.1 m s⁻¹ a global mean CDN of 375 cm⁻³ (previously estimated to cancel the forcing caused by CO₂ doubling is achievable in only about 50% of grid boxes which have > 50% cloud cover, irrespective of the amount of aerosol injected. But at stronger updraft speeds (0

Development of process data capturing, analysis and controlling for thermal spray techniques - SprayTracker

Science.gov (United States)

Kelber, C.; Marke, S.; Trommler, U.; Rupprecht, C.; Weis, S.

2017-03-01

Thermal spraying processes are becoming increasingly important in high-technology areas, such as automotive engineering and medical technology. The method offers the advantage of a local layer application with different materials and high deposition rates. Challenges in the application of thermal spraying result from the complex interaction of different influencing variables, which can be attributed to the properties of different materials, operating equipment supply, electrical parameters, flow mechanics, plasma physics and automation. In addition, spraying systems are subject to constant wear. Due to the process specification and the high demands on the produced coatings, innovative quality assurance tools are necessary. A central aspect, which has not yet been considered, is the data management in relation to the present measured variables, in particular the spraying system, the handling system, working safety devices and additional measuring sensors. Both the recording of all process-characterizing variables, their linking and evaluation as well as the use of the data for the active process control presuppose a novel, innovative control system (hardware and software) that was to be developed within the scope of the research project. In addition, new measurement methods and sensors are to be developed and qualified in order to improve the process reliability of thermal spraying.

A study on the macroscopic spray behavior and atomization characteristics of biodiesel and dimethyl ether sprays under increased ambient pressure

Energy Technology Data Exchange (ETDEWEB)

Kim, Hyung Jun; Park, Su Han [Graduate School of Hanyang University, 17 Haengdang-dong, Seoungdong-gu, Seoul 133-791 (Korea); Lee, Chang Sik [Department of Mechanical Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul 133-791 (Korea)

2010-03-15

The aim of this work is to investigate the spray behaviors of biodiesel and dimethyl ether (DME) fuels using image processing and atomization performance analysis of the two fuel sprays injected through a common-rail injection system under various ambient pressure conditions in a high pressure chamber. In order to observe the biodiesel and DME fuel spray behaviors under various ambient pressures, the spray images were analyzed at various times after the start of energization using a visualization system consisting of a high speed camera and two metal halide light sources. In addition, a high pressure chamber that can withstand a pressure of 4 MPa was used for adjusting the ambient pressure. From the spray images, spray characteristics such as the spray tip penetration, cone angle, area, and contour plot at various light intensity levels were analyzed using image conversion processing. Also, the local Sauter mean diameters (SMD) were measured at various axial/radial distances from the nozzle tip by a droplet measuring system to compare the atomization performances of the biodiesel and DME sprays. The results showed that the ambient pressure had a significant effect on the spray characteristics of the fuels at the various experimental conditions. The spray tip penetration and spray area decreased as the ambient pressure increased. The contour plot of the biodiesel and DME sprays showed a high light intensity level in the center regions of the sprays. In addition, it was revealed that the atomization performance of the biodiesel spray was inferior to that of the DME spray at the same injection and ambient conditions. (author)

An experimental methodology to quantify the spray cooling event at intermittent spray impact

International Nuclear Information System (INIS)

Moreira, Antonio L.N.; Carvalho, Joao; Panao, Miguel R.O.

2007-01-01

The present paper describes an experimental methodology devised to study spray cooling with multiple-intermittent sprays as those found in fuel injection systems of spark-ignition and diesel engines, or in dermatologic surgery applications. The spray characteristics and the surface thermal behaviour are measured by combining a two-component phase-Doppler anemometer with fast response surface thermocouples. The hardware allows simultaneous acquisition of Doppler and thermocouple signals which are processed in Matlab to estimate the time-varying heat flux and fluid-dynamic characteristics of the spray during impact. The time resolution of the acquisition system is limited by the data rate of validation of the phase-Doppler anemometer, but it has been shown to be accurate for the characterization of spray-cooling processes with short spurt durations for which the transient period of spray injection plays an important role. The measurements are processed in terms of the instantaneous heat fluxes, from which phase-average values of the boiling curves are obtained. Two of the characteristic parameters used in the thermal analysis of stationary spray cooling events, the critical heat flux (CHF) and Leidenfrost phenomenon, are then inferred in terms of operating conditions of the multiple-intermittent injections, such as the frequency, duration and pressure of injection. An integral method is suggested to describe the overall process of heat transfer, which accounts for the fluid-dynamic heterogeneities induced by multiple and successive droplet interactions within the area of spray impact. The method considers overall boiling curves dependant on the injection conditions and provides an empirical tool to characterize the heat transfer processes on the impact of multiple-intermittent sprays. The methodology is tested in a preliminary study of the effect of injection conditions on the heat removed by a fuel spray striking the back surface of the intake valve as in spark

Cold spray NDE for porosity and other process anomalies

Science.gov (United States)

Glass, S. W.; Larche, M. R.; Prowant, M. S.; Suter, J. D.; Lareau, J. P.; Jiang, X.; Ross, K. A.

2018-04-01

This paper describes a technology review of nondestructive evaluation (NDE) methods that can be applied to cold spray coatings. Cold spray is a process for depositing metal powder at high velocity so that it bonds to the substrate metal without significant heating that would be likely to cause additional residual tensile stresses. Coatings in the range from millimeters to centimeters are possible at relatively high deposition rates. Cold spray coatings that may be used for hydroelectric components that are subject to erosion, corrosion, wear, and cavitation damage are of interest. The topic of cold spray NDE is treated generally, however, but may be considered applicable to virtually any cold spray application except where there are constraints of the hydroelectric component application that bear special consideration. Optical profilometry, eddy current, ultrasound, and hardness tests are shown for one set of good, fair, and poor nickel-chrome (NiCr) on 304 stainless steel (304SS) cold spray samples to demonstrate inspection possibilities. The primary indicator of cold spray quality is the cold spray porosity that is most directly measured with witness-sample destructive examinations (DE)—mostly photo-micrographs. These DE-generated porosity values are correlated with optical profilometry, eddy current, ultrasound, and hardness test NDE methods to infer the porosity and other information of interest. These parameters of interest primarily include: • Porosity primarily caused by improper process conditions (temperature, gas velocity, spray standoff, spray angle, powder size, condition, surface cleanliness, surface oxide, etc.) • Presence/absence of the cold spray coating including possible over-sprayed voids • Coating thicknessOptical profilometry measurements of surface roughness trended with porosity plus, if compared with a reference measurement or reference drawing, would provide information on the coating thickness. Ultrasound could provide similar

Residual stresses in as-sprayed and heat treated TBCs : measurements and FEM calculations

NARCIS (Netherlands)

Koolloos, M.F.J.; Houben, J.M.

2000-01-01

The first part of this paper concerns measurement of through-thickness residual stresses in TBCs by the hole-drilling method. The influences of top coat thickness and different thermal histories (furnace and burner rig) were determined. Low tensile stresses prevailed in the as-sprayed state, and low

Sea-ice thickness from field measurements in the northwestern Barents Sea

Science.gov (United States)

King, Jennifer; Spreen, Gunnar; Gerland, Sebastian; Haas, Christian; Hendricks, Stefan; Kaleschke, Lars; Wang, Caixin

2017-02-01

The Barents Sea is one of the fastest changing regions of the Arctic, and has experienced the strongest decline in winter-time sea-ice area in the Arctic, at -23±4% decade-1. Sea-ice thickness in the Barents Sea is not well studied. We present two previously unpublished helicopter-borne electromagnetic (HEM) ice thickness measurements from the northwestern Barents Sea acquired in March 2003 and 2014. The HEM data are compared to ice thickness calculated from ice draft measured by ULS deployed between 1994 and 1996. These data show that ice thickness varies greatly from year to year; influenced by the thermodynamic and dynamic processes that govern local formation vs long-range advection. In a year with a large inflow of sea-ice from the Arctic Basin, the Barents Sea ice cover is dominated by thick multiyear ice; as was the case in 2003 and 1995. In a year with an ice cover that was mainly grown in situ, the ice will be thin and mechanically unstable; as was the case in 2014. The HEM data allow us to explore the spatial and temporal variability in ice thickness. In 2003 the dominant ice class was more than 2 years old; and modal sea-ice thickness varied regionally from 0.6 to 1.4 m, with the thinner ice being either first-year ice, or multiyear ice which had come into contact with warm Atlantic water. In 2014 the ice cover was predominantly locally grown ice less than 1 month old (regional modes of 0.5-0.8 m). These two situations represent two extremes of a range of possible ice thickness distributions that can present very different conditions for shipping traffic; or have a different impact on heat transport from ocean to atmosphere.

Characterization of the full cone pressure swirl spray nozzles for the nuclear reactor containment spray system

Energy Technology Data Exchange (ETDEWEB)

Jain, Manish [Department of Mechanical Engineering, I.I.T., Bombay, Powai, Mumbai (India); John, Benny [Nuclear Power Corporation of India Limited, Mumbai (India); Iyer, K.N. [Department of Mechanical Engineering, I.I.T., Bombay, Powai, Mumbai (India); Prabhu, S.V., E-mail: svprabhu@iitb.ac.in [Department of Mechanical Engineering, I.I.T., Bombay, Powai, Mumbai (India)

2014-07-01

Highlights: • Full cone spray pressure swirl nozzle with X-Vane is studied. • Laser illuminated imaging technique is used. • Correlations for coefficient of discharge, spray cone angle and SMD are suggested. • Droplet size and mass fraction distribution is measured. • Inviscid theory predicts the coefficient of discharge. - Abstract: The objective of the present study is to characterize a full cone pressure swirl nozzle for the Containment Spray System (CSS) of Indian Pressurized heavy Water reactors (IPHWR). The influence of Reynolds number and geometric parameters on the coefficient of discharge, spray cone angle, mass flux density distribution, droplet size distribution, Sauter mean diameter (SMD is studied for full cone pressure swirl full cone nozzles. The nozzles of orifice diameter range from 1.3 to 7.2 mm are studied. Experiments are conducted with water at room temperature as the working medium. The nozzles are operated with the pressure ranging from 1 to 8 bar. The measurements of the drop size distributions are performed with laser illuminated imaging technique. The spray cone-angle of the full cone nozzles is measured by the evaluation of images recorded with a camera using IMAGE J software. Correlations for coefficient of discharge, spray cone angle and Sauter mean diameter are suggested on the basis of the experimental results. Rosin–Rammler model and Nukiyama–Tanasawa distributions predict the mass fraction distribution reasonably well. However, the droplet size distribution is predicted by Nukiyama-Tanasawa model only.

Electrostatically atomised hydrocarbon sprays

Energy Technology Data Exchange (ETDEWEB)

Yule, A.J.; Shrimpton, J.S.; Watkins, A.P.; Balachandran, W.; Hu, D. [UMIST, Manchester (United Kingdom). Thermofluids Division, Dept. of Mechanical Engineering

1995-07-01

A burner using an electrostatic method to produce and control a fuel spray is investigated for non-burning sprays. The burner has a charge injection nozzle and the liquid flow rate and charge injection rate are varied using hydrocarbon liquids of differing viscosities, surface tensions and electrical conductivities (kerosene, white spirit and diesel oil). Droplet size distributions are measured and it is shown how the dropsize, spray pattern, breakup mechanism and breakup length depend on the above variables, and in particular on the specific charge achieved in the spray. The data are valuable for validating two computer models under development. One predicts the electric field and flow field inside the nozzle as a function of emitter potential, geometry and flow rate. The other predicts the effect of charge on spray dispersion, with a view to optimizing spray combustion. It is shown that electrostatic disruptive forces can be used to atomize oils at flow rates commensurate with practical combustion systems and that the charge injection technique is particularly suitable for highly resistive liquids. Possible limitations requiring further research include the need to control the wide spray angle, which may provide fuel-air mixtures too lean near the nozzle, and the need to design for maximum charge injection rate, which is thought to be limited by corona breakdown in the gas near the nozzle orifice. 30 refs., 15 figs., 1 tab.

Precise mean sea level measurements using the Global Positioning System

Science.gov (United States)

Kelecy, Thomas M.; Born, George H.; Parke, Michael E.; Rocken, Christian

1994-01-01

This paper describes the results of a sea level measurement test conducted off La Jolla, California, in November of 1991. The purpose of this test was to determine accurate sea level measurements using a Global Positioning System (GPS) equipped buoy. These measurements were intended to be used as the sea level component for calibration of the ERS 1 satellite altimeter. Measurements were collected on November 25 and 28 when the ERS 1 satellite overflew the calibration area. Two different types of buoys were used. A waverider design was used on November 25 and a spar design on November 28. This provided the opportunity to examine how dynamic effects of the measurement platform might affect the sea level accuracy. The two buoys were deployed at locations approximately 1.2 km apart and about 15 km west of a reference GPS receiver located on the rooftop of the Institute of Geophysics and Planetary Physics at the Scripps Institute of Oceanography. GPS solutions were computed for 45 minutes on each day and used to produce two sea level time series. An estimate of the mean sea level at both locations was computed by subtracting tide gage data collected at the Scripps Pier from the GPS-determined sea level measurements and then filtering out the high-frequency components due to waves and buoy dynamics. In both cases the GPS estimate differed from Rapp's mean altimetric surface by 0.06 m. Thus, the gradient in the GPS measurements matched the gradient in Rapp's surface. These results suggest that accurate sea level can be determined using GPS on widely differing platforms as long as care is taken to determine the height of the GPS antenna phase center above water level. Application areas include measurement of absolute sea level, of temporal variations in sea level, and of sea level gradients (dominantly the geoid). Specific applications would include ocean altimeter calibration, monitoring of sea level in remote regions, and regional experiments requiring spatial and

Research on the Fatigue Flexural Performance of RC Beams Attacked by Salt Spray

Science.gov (United States)

Mao, Jiang-hong; Xu, Fang-yuan; Jin, Wei-liang; Zhang, Jun; Wu, Xi-xi; Chen, Cai-sheng

2018-04-01

The fatigue flexural performance of RC beams attacked by salt spray was studied. A testing method involving electro osmosis, electrical accelerated corrosion and salt spray was proposed. This corrosion process method effectively simulates real-world salt spray and fatigue loading exerted by RC components on sea bridges. Four RC beams that have different stress amplitudes were tested. It is found that deterioration by corrosion and fatigue loading reduces the fatigue life of the RC and decreases the ability of deformation. The fatigue life and deflection ability could be reduced by increasing the stress amplitude and the corrosion duration time. The test result demonstrates that this experimental method can couple corrosion deterioration and fatigue loading reasonably. This procedure may be applied to evaluate the fatigue life and concrete durability of RC components located in a natural salt spray environment.

Secondary sulfate is internally mixed with sea spray aerosol and organic aerosol in the winter Arctic

Science.gov (United States)

Kirpes, Rachel M.; Bondy, Amy L.; Bonanno, Daniel; Moffet, Ryan C.; Wang, Bingbing; Laskin, Alexander; Ault, Andrew P.; Pratt, Kerri A.

2018-03-01

Few measurements of aerosol chemical composition have been made during the winter-spring transition (following polar sunrise) to constrain Arctic aerosol-cloud-climate feedbacks. Herein, we report the first measurements of individual particle chemical composition near Utqiaġvik (Barrow), Alaska, in winter (seven sample days in January and February 2014). Individual particles were analyzed by computer-controlled scanning electron microscopy with energy dispersive X-ray spectroscopy (CCSEM-EDX, 24 847 particles), Raman microspectroscopy (300 particles), and scanning transmission X-ray microscopy with near-edge X-ray absorption fine structure spectroscopy (STXM-NEXAFS, 290 particles). Sea spray aerosol (SSA) was observed in all samples, with fresh and aged SSA comprising 99 %, by number, of 2.5-7.5 µm diameter particles, 65-95 % from 0.5-2.5 µm, and 50-60 % from 0.1-0.5 µm, indicating SSA is the dominant contributor to accumulation and coarse-mode aerosol during the winter. The aged SSA particles were characterized by reduced chlorine content with 94 %, by number, internally mixed with secondary sulfate (39 %, by number, internally mixed with both nitrate and sulfate), indicative of multiphase aging reactions during transport. There was a large number fraction (40 % of 1.0-4.0 µm diameter particles) of aged SSA during periods when particles were transported from near Prudhoe Bay, consistent with pollutant emissions from the oil fields participating in atmospheric processing of aerosol particles. Organic carbon and sulfate particles were observed in all samples and comprised 40-50 %, by number, of 0.1-0.4 µm diameter particles, indicative of Arctic haze influence. Soot was internally mixed with organic and sulfate components. All sulfate was mixed with organic carbon or SSA particles. Therefore, aerosol sources in the Alaskan Arctic and resulting aerosol chemical mixing states need to be considered when predicting aerosol climate effects, particularly cloud

Cryogen spray cooling: Effects of droplet size and spray density on heat removal.

Science.gov (United States)

Pikkula, B M; Torres, J H; Tunnell, J W; Anvari, B

2001-01-01

Cryogen spray cooling (CSC) is an effective method to reduce or eliminate non-specific injury to the epidermis during laser treatment of various dermatological disorders. In previous CSC investigations, fuel injectors have been used to deliver the cryogen onto the skin surface. The objective of this study was to examine cryogen atomization and heat removal characteristics of various cryogen delivery devices. Various cryogen delivery device types including fuel injectors, atomizers, and a device currently used in clinical settings were investigated. Cryogen mass was measured at the delivery device output orifice. Cryogen droplet size profiling for various cryogen delivery devices was estimated by optically imaging the droplets in flight. Heat removal for various cryogen delivery devices was estimated over a range of spraying distances by temperature measurements in an skin phantom used in conjunction with an inverse heat conduction model. A substantial range of mass outputs were measured for the cryogen delivery devices while heat removal varied by less than a factor of two. Droplet profiling demonstrated differences in droplet size and spray density. Results of this study show that variation in heat removal by different cryogen delivery devices is modest despite the relatively large difference in cryogen mass output and droplet size. A non-linear relationship between heat removal by various devices and droplet size and spray density was observed. Copyright 2001 Wiley-Liss, Inc.

Characterization of Sodium Spray Aerosols

Energy Technology Data Exchange (ETDEWEB)

Nelson, C. T.; Koontz, R. L.; Silberberg, M. [Atomics International, North American Rockwell Corporation, Canoga Park, CA (United States)

1968-12-15

The consequences of pool and spray fires require evaluation in the safety analysis of liquid metal-cooled fast breeder reactors. Sodium spray fires are characterized by high temperature and pressure, produced during the rapid combustion of sodium in air. Following the initial energy release, some fraction of the reaction products are available as aerosols which follow the normal laws of agglomeration, growth, settling, and plating. An experimental study is underway at Atomics International to study the characteristics of high concentration sprays of liquid sodium in reduced oxygen atmospheres and in air. The experiments are conducted in a 31.5 ft{sup 3} (2 ft diam. by 10 ft high) vessel, certified for a pressure of 100 lb/in{sup 2} (gauge). The spray injection apparatus consists of a heated sodium supply pot and a spray nozzle through which liquid sodium is driven by nitrogen pressure. Spray rate and droplet size can be varied by the injection velocity (nozzle size, nitrogen pressure, and sodium temperature). Aerosols produced in 0, 4, and 10 vol. % oxygen environments have been studied. The concentration and particle size distribution of the material remaining in the air after the spray injection and reaction period are measured. Fallout rates are found to be proportional to the concentration of aerosol which remains airborne following the spray period. (author)

Ballistic Imaging and Scattering Measurements for Diesel Spray Combustion: Optical Development and Phenomenological Studies

Science.gov (United States)

2016-04-01

3mm) of diesel sprays from a high-pressure single-hole fuel injector . Ballistic imaging of dodecane and methyl oleate sprays are reported...Porter, Sean P. Duran, Terence E. Parker. Picosecond Ballistic Imaging of Ligament Structures in the Near- Nozzle Region of Diesel Sprays, ILASS...Experiments in Fluids (12 2014) Sean Duran, Jason Porter, Terence Parker. Ballistic Imaging of a Diesel Injector Spray at High Temperature and

Fuel concentration in isothermal Diesel sprays through structured planar laser imaging measurements

Energy Technology Data Exchange (ETDEWEB)

Payri, R.; Gimeno, J.; Marti, P. [CMT Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, 46022 Valencia (Spain); Manin, J., E-mail: jmanin@sandia.gov [Sandia National Laboratories, 7011 East Ave., 94551 Livermore, CA (United States)

2012-04-15

Highlights: Black-Right-Pointing-Pointer Structured illumination has been implemented to quantify mixing in isothermal sprays. Black-Right-Pointing-Pointer Comparison to a gas-jet model conducted to Schmidt number below the unity (Sc = 0.8). Black-Right-Pointing-Pointer Results showed incomplete momentum transfer due to velocity slip between droplets and ambient. Black-Right-Pointing-Pointer Higher injection pressures enhance momentum transfer and lead to better global mixing. - Abstract: The mixing of isothermal liquid sprays in engine-like conditions has been investigated by applying the structured planar laser imaging technique to remove multiple light scattering. The intensity of the illumination plane has been recovered by removing multiply scattered light and mapping the spray three-dimensionally via discrete tomography. Based on the extinction of light within the illumination plane, the number density has been extracted. Coupled with 2-D maps of droplet diameters obtained through LIF/Mie ratio, the number density allowed to calculate the fuel concentration in the sprays. The mixture fraction of DI Diesel sprays injected into an inert environment held at room temperature has been evaluated and compared to a 2-D model based on gas-jet theory. The experimental results showed good agreement with the predictions when a Gaussian radial distribution is assumed and the Schmidt number is correctly tuned. Differences in the radial distribution has been observed and related to incomplete momentum transfer between the liquid spray and the surrounding gases. For different testing conditions, while the influence of ambient density on mixing was expected, the effect of injection pressure has been found to provide additional information concerning the global mixing of liquid sprays.

Atmospheric dry deposition in the vicinity of the Salton Sea, California - II: Measurement and effects of an enhanced evaporation system

Science.gov (United States)

Alonso, R.; Bytnerowicz, A.; Yee, J.L.; Boarman, W.I.

2005-01-01

A study was conducted to determine the effects of salt spray drift from pilot technologies employed by the US Bureau of Reclamation on deposition rates of various air-born ions. An enhanced evaporation system (EES) was tested in the field at the Salton Sea, California. Dry deposition of NO3-, NH4+, SO42-, Cl-, Ca2+, Na+, K+ and Se was assessed by using nylon filters and branches of natural vegetation exposed for one-week long periods. The simultaneous exposure of both lyophilized branches and branches of live plants offered important information highlighting the dynamics of deposited ions on vegetation. The EES significantly increased the deposition rates of Cl-, SO42- and Na+ in an area of about 639-1062 m surrounding the sprayers. Similarly, higher deposition of Ca 2+ and K+ caused by the EES was detected only when deposition was assessed using nylon filters or lyophilized branches. Deposition fluxes of NO3-, NH4+ and Se were not affected by the spraying system. Techniques for measuring dry deposition and calculating landscape-level depositional loads in non-forested systems need further development. ?? 2005 Elsevier Ltd. All rights reserved.

Single nozzle spray drift measurements of drift reducing nozzles at two forward speeds

NARCIS (Netherlands)

Stallinga, H.; Zande, van de J.C.; Michielsen, J.G.P.; Velde, van P.

2016-01-01

In 2011‒2012 single nozzle field experiments were carried out to determine the effect of different flat fan spray nozzles of the spray drift reduction classes 50, 75, 90 and 95% on spray drift at two different forward speeds (7.2 km h-1 and 14.4 km h-1). Experiments were performed with a single

Investigation of the physical scaling of sea spray spume droplet production

Science.gov (United States)

Fairall, C. W.; Banner, M. L.; Peirson, W. L.; Asher, W.; Morison, R. P.

2009-10-01

In this paper we report on a laboratory study, the Spray Production and Dynamics Experiment (SPANDEX), conducted at the University of New South Wales Water Research Laboratory in Australia. The goals of SPANDEX were to illuminate physical aspects of spume droplet production and dispersion; verify theoretical simplifications used to estimate the source function from ambient droplet concentration measurements; and examine the relationship between the implied source strength and forcing parameters such as wind speed, surface turbulent stress, and wave properties. Observations of droplet profiles give reasonable confirmation of the basic power law profile relationship that is commonly used to relate droplet concentrations to the surface source strength. This essentially confirms that, even in a wind tunnel, there is a near balance between droplet production and removal by gravitational settling. The observations also indicate considerable droplet mass may be present for sizes larger than 1.5 mm diameter. Phase Doppler Anemometry observations revealed significant mean horizontal and vertical slip velocities that were larger closer to the surface. The magnitude seems too large to be an acceleration time scale effect. Scaling of the droplet production surface source strength proved to be difficult. The wind speed forcing varied only 23% and the stress increased a factor of 2.2. Yet, the source strength increased by about a factor of 7. We related this to an estimate of surface wave energy flux through calculations of the standard deviation of small-scale water surface disturbance, a wave-stress parameterization, and numerical wave model simulations. This energy index only increased by a factor of 2.3 with the wind forcing. Nonetheless, a graph of spray mass surface flux versus surface disturbance energy is quasi-linear with a substantial threshold.

SPRAY CASTING

OpenAIRE

SALAMCI, Elmas

2010-01-01

ABSTRACT This paper is designed to provide a basic review of spray casting. A brief overview of the historical development of spray  casting and the description of plant and equipment have been given. Following metallurgical characteristics of spray formed alloys, process parameters and solidification mechanism of spray deposition have been discussed in detail. Finally, microstructure and mechanical properties of the selected spray cast Al-Zn-Mg-Cu alloys have been presented and comp...

Quality characteristic of spray-drying egg white powders.

Science.gov (United States)

Ma, Shuang; Zhao, Songning; Zhang, Yan; Yu, Yiding; Liu, Jingbo; Xu, Menglei

2013-10-01

Spray drying is a useful method for developing egg process and utilization. The objective of this study was to evaluate effects on spray drying condition of egg white. The optimized conditions were spraying flow 22 mL/min, feeding temperature 39.8 °C and inlet-air temperature 178.2 °C. Results of sulfydryl (SH) groups measurement indicated conformation structure have changed resulting in protein molecule occur S-S crosslinking phenomenon when heating. It led to free SH content decreased during spray drying process. There was almost no change of differential scanning calorimetry between fresh egg white and spray-drying egg white powder (EWP). For a given protein, the apparent SH reactivity is in turn influenced by the physico-chemical characteristics of the reactant. The phenomenon illustrated the thermal denaturation of these proteins was unrelated to their free SH contents. Color measurement was used to study browning level. EWP in optimized conditions revealed insignificant brown stain. Swelling capacity and scanning electron micrograph both proved well quality characteristic of spray-drying EWP. Results suggested spray drying under the optimized conditions present suitable and alternative method for egg processing industrial implementation. Egg food industrialization needs new drying method to extend shelf-life. The purpose of the study was to provide optimal process of healthy and nutritional instant spray-drying EWP and study quality characteristic of spray-drying EWP.

Modeling the influence of nozzle-generated turbulence on diesel sprays

Energy Technology Data Exchange (ETDEWEB)

Magnotti, G M; Matusik, K E; Duke, D J; Knox, B W; Martinez, G L; Powell, C F; Kastengren, A L; Genzale, C L

2017-05-18

The physical mechanisms governing spray breakup in direct injection engines, such as aerodynamic induced instabilities and nozzle-generated cavitation and turbulence, are not well understood due to the experimental and computational limitations in resolving these processes. Recent x-ray and visible extinction measurements have been con-ducted with a targeted interest in the spray formation region in order to characterize the distribution of droplet sizes throughout the spray. Detailed analysis of these measurements shows promise of yielding insight into likely mechanisms governing atomization, which can inform the improvement of spray models for engine computational fluid dynamic (CFD) codes. In order to investigate potential atomization mechanisms, we employ a joint experimental and computational approach to characterize the structure of the spray formation region using the Engine Combustion Network Spray D injector. X-ray tomography, radiography and ultra-small angle x-ray scattering measurements conducted at the Advanced Photon Source at Argonne National Laboratory quantify the injector geometry, liquid fuel mass and Sauter mean diameter (SMD) distributions under non-vaporizing conditions. Diffused back-illumination imaging measurements, conducted at the Georgia Institute of Technology, characterize the asymmetry of the spray structure. The selected range of injection pressures (50 – 150 MPa) and ambient densities (1.2 – 22.8 kg/m3) allow for the influence of aerodynamic forces on the spray to be studied in a controlled and systematic manner, while isolating the atomization process from the effects of vaporization. In comparison to high ambient density conditions, the spray is observed to be more asymmetric at low ambient density conditions. Although several mechanisms may cause asymmetries in the nozzle exit flow conditions and ultimately the spray distribution, irregularities in the internal nozzle geometry were identified, suggesting an increased

Inhalational and dermal exposures during spray application of biocides.

Science.gov (United States)

Berger-Preiss, Edith; Boehncke, Andrea; Könnecker, Gustav; Mangelsdorf, Inge; Holthenrich, Dagmar; Koch, Wolfgang

2005-01-01

Data on inhalational and potential dermal exposures during spray application of liquid biocidal products were generated. On the one hand, model experiments with different spraying devices using fluorescent tracers were carried out to investigate the influence of parameters relevant to the exposure (e.g. spraying equipment, nozzle size, direction of application). On the other hand, measurements were performed at selected workplaces (during disinfection operations in food and feed areas; pest control operations for private, public and veterinary hygiene; wood protection and antifouling applications) after application of biocidal products such as Empire 20, Responsar SC, Omexan-forte, Actellic, Perma-forte; Fendona SC, Pyrethrum mist; CBM 8, Aldekol Des 03, TAD CID, Basileum, Basilit. The measurements taken in the model rooms demonstrated dependence of the inhalation exposure on the type of spraying device used, in the following order: "spraying with low pressure" < "airless spraying" < "fogging" indicating that the particle diameter of the released spray droplets is the most important parameter. In addition inhalation exposure was lowest when the spraying direction was downward. Also for the potential dermal exposure, the spraying direction was of particular importance: overhead spraying caused the highest contamination of body surfaces. The data of inhalational and potential dermal exposures gained through workplace measurements showed considerable variation. During spraying procedures with low-pressure equipments, dose rates of active substances inhaled by the operators ranged from 7 to 230 microg active substance (a.s.)/h. An increase in inhaled dose rates (6-33 mg a.s./h) was observed after use of high application volumes/time unit during wood protection applications indoors. Spraying in the veterinary sector using medium-pressure sprayers led to inhaled dose rates between 2 and 24mga.s./h. The highest inhaled dose rates were measured during fogging (114 mg a

Evaporation of boric acid from sea water

Energy Technology Data Exchange (ETDEWEB)

Gast, J A; Thompson, T G

1959-01-01

Previous investigators have shown that the boron-chlorinity ratios of rain waters are many times greater than the boron-chlorinity ratio of sea water. The presence of boron in the atmosphere has been attributed to sea spray, volcanic activity, accumulation in dust, evaporation from plants, and industrial pollution. In this paper data are presented to demonstrate that boric acid in sea water has a vapor pressure at ordinary temperatures of the sea and, when sea water evaporates, boric acid occurs in the condensate of the water vapor. It is postulated that, while some of the boron in the atmosphere can be attributed to the sources mentioned above, most of the boric acid results from evaporation from the sea.

Study of mass and momentum transfer in diesel sprays based on X-ray mass distribution measurements and on a theoretical derivation

Energy Technology Data Exchange (ETDEWEB)

Desantes, J.M.; Salvador, F.J.; Lopez, J.J.; Morena, J. de la [Universidad Politecnica de Valencia, CMT-Motores Termicos, Valencia (Spain)

2011-02-15

In this paper, a research aimed at quantifying mass and momentum transfer in the near-nozzle field of diesel sprays injected into stagnant ambient air is reported. The study combines X-ray measurements for two different nozzles and axial positions, which provide mass distributions in the spray, with a theoretical model based on momentum flux conservation, which was previously validated. This investigation has allowed the validation of Gaussian profiles for local fuel concentration and velocity near the nozzle exit, as well as the determination of Schmidt number at realistic diesel spray conditions. This information could be very useful for those who are interested in spray modeling, especially at high-pressure injection conditions. (orig.)

Measurement of electro-sprayed 238 and 239+240 plutonium isotopes using 4π-alpha spectrometry. Application to environmental samples

International Nuclear Information System (INIS)

Charmoille-Roblot, M.

1999-01-01

A new protocol for plutonium deposition using the electro-spray technique coupled with 4π-α spectrometry is proposed to improve the detection limit, shorten the counting time. In order to increase the detection efficiency, it was proposed to measure 238 and 239+240 plutonium isotopes electro-sprayed deposit simultaneously on both sides of the source support, that must be as transparent as possible to alpha-emissions, in a two-alpha detectors chamber. A radiochemical protocol was adapted to electro-spray constraints and a very thin carbon foil was selected for 4π -alpha spectrometry. The method was applied to a batch of sediment samples and gave the same results as an electrodeposited source measured using conventional alpha spectrometry with a 25 % gain on counting time and 10 % on plutonium 238 detection limit. Validation and application of the technique have been made on reference samples. (author)

Determination of the Territorial Sea Baseline - Measurement Aspect

Science.gov (United States)

Specht, Cezary; Weintrit, Adam; Specht, Mariusz; Dabrowski, Pawel

2017-12-01

Determining the course of the territorial sea baseline (TSB) of the coastal state is the basis for establishing its maritime boundaries, thus becoming indirect part of maritime policy of the state. Besides the following aspects: legal and methodological as described in the conventions, acts, standards and regulations, equally important is the issue of measurement methodology with respect to the boundaries of the territorial sea. The publication discussed accuracy requirements of the TSB measurement implementation, the relationship of sea level with a choice of the method of its determination, and discussed the implementation of such a measurement on a selected example. As the test reservoir was used the 400-meter stretch of the public beach in Gdynia. During the measurements they used the GNSS geodetic receiver operating in real time based on the geodetic network - VRSnet.pl. Additionally, a comparison was made of the applied method with analogous measurements of the TSB performed in 1999.

Understanding the Impact of Model Surfactants on Cloud Condensation Nuclei Activity of Sea Spray Aerosols

Science.gov (United States)

Forestieri, S.; Cappa, C. D.; Ruehl, C. R.; Bertram, T. H.; Staudt, S.; Kuborn, T.

2017-12-01

Aerosol impacts on cloud properties, also known as indirect effects, remain a major source of uncertainty in modeling global radiative forcing. Reducing this uncertainty necessitates better understanding of how aerosol chemical composition impacts the cloud-forming ability of aerosols. The presence of surfactants in aerosols can decrease the surface tension of activating droplets relative to water and lead to more efficient activation. The importance of this effect has been debated, but recent surface tension measurements of microscopic droplets indicate that surface tension is substantially depressed relative to water for lab-generated particles consisting of salt and a single organic species and for complex mixtures of organic matter. However, little work has been done on understanding how chemical complexity (i.e. interaction between different surfactant species) impacts surface tension for particles containing mixtures of surfactants. In this work, we quantified the surface tension of lab-generated aerosols containing surfactants that are commonly found in nascent sea spray aerosol (SSA) at humidities close to activation using a continuous flow stream-wise thermal gradient chamber (CFSTGC). Surface tension was quantified for particles containing single surfactant species and mixtures of these surfactants to investigate the role of chemical complexity on surface tension and molecular packing at the air-water interface. For all surfactants tested in this study, substantial surface tension depression (20-40 mN/m) relative to water was observed for particles containing large fractions of organic matter at humidities just below activation. However, the presence of these surfactants only weakly depressed surface tension at activation. Kinetic limitations were observed for particles coated with just palmitic acid, since palmitic acid molecules inhibit water uptake through their ability to pack tightly at the surface. However, these kinetic limitations disappeared when

The Irminger Sea and the Iceland Sea time series measurements of sea water carbon and nutrient chemistry 1983–2008

Directory of Open Access Journals (Sweden)

J. Olafsson

2010-03-01

Full Text Available This paper describes the ways and means of assembling and quality controling the Irminger Sea and Iceland Sea time-series biogeochemical data which are included in the CARINA data set. The Irminger Sea and the Iceland Sea are hydrographically different regions where measurements of sea water carbon and nutrient chemistry were started in 1983. The sampling is seasonal, four times a year. The carbon chemistry is studied with measurements of the partial pressure of carbon dioxide in seawater, pCO₂, and total dissolved inorganic carbon, TCO₂. The carbon chemistry data are for surface waters only until 1991 when water column sampling was initiated. Other measured parameters are salinity, dissolved oxygen and the inorganic nutrients nitrate, phosphate and silicate. Because of the CARINA criteria for secondary quality control, depth >1500 m, the IRM-TS could not be included in the routine QC and the IS-TS only in a limited way. However, with the information provided here, the quality of the data can be assessed, e.g. on the basis of the results obtained with the use of reference materials.

Quantitative Assessment of Spray Deposition with Water-Sensitive Paper

Science.gov (United States)

Spray droplets, discharged from the lower six nozzles of an airblast sprayer, were sampled on pairs of absorbent filter and water-sensitive papers at nine distances from sprayer. Spray deposition on filter targets were measured by fluorometry and spray distribution on WSP targets were assessed by t...

Multiphysics modelling of the spray forming process

International Nuclear Information System (INIS)

Mi, J.; Grant, P.S.; Fritsching, U.; Belkessam, O.; Garmendia, I.; Landaberea, A.

2008-01-01

An integrated, multiphysics numerical model has been developed through the joint efforts of the University of Oxford (UK), University of Bremen (Germany) and Inasmet (Spain) to simulate the spray forming process. The integrated model consisted of four sub-models: (1) an atomization model simulating the fragmentation of a continuous liquid metal stream into droplet spray during gas atomization; (2) a droplet spray model simulating the droplet spray mass and enthalpy evolution in the gas flow field prior to deposition; (3) a droplet deposition model simulating droplet deposition, splashing and re-deposition behavior and the resulting preform shape and heat flow; and (4) a porosity model simulating the porosity distribution inside a spray formed ring preform. The model has been validated against experiments of the spray forming of large diameter IN718 Ni superalloy rings. The modelled preform shape, surface temperature and final porosity distribution showed good agreement with experimental measurements

Cancer in US Air Force veterans not involved with spraying herbicides during the Vietnam War

Energy Technology Data Exchange (ETDEWEB)

Pavuk, M. [SpecPro, Inc. (United States); Michalek, J.; Ketchum, N. [Air Force Research Laboratory, San Antonio, TX (United States); Akhtar, F. [The START Center, San Antonio, TX (United States)

2004-09-15

The Air Force Health Study is a 20-year prospective study examining the health, mortality and reproductive outcomes in US Air Force veterans of Operation Ranch Hand who sprayed herbicides in Vietnam from 1962 to 1971. Comparison veterans flew or serviced C-130 transport aircraft in Southeast Asia (SEA) during the same time period but did not spray herbicides. They were stationed mostly in Taiwan, the Philippines, Guam, Japan, and Thailand and spent on average less than 30% of their SEA service in Vietnam. Comparison veterans also spent approximately 30% more time in SEA than Ranch Hand veterans. No increases in Ranch Hand cancer mortality and morbidity were found in earlier investigations, but a recent study contrasting cancer rates in Air Force veterans and in the general US (white male) population reported increases in cancer at all SEER sites, prostate cancer and melanoma in Ranch Hand veterans and cancer at all SEER sites and prostate cancer in Comparison veterans. Associations between dioxin exposure category and cancer were found after restriction to Ranch Hand veterans who served in SEA no more than 2 years and to those who spent all of their SEA service in Vietnam. Overall cancer incidence in the general population in countries of SEA is about half of that in the United States, but cancers of the oral cavity/nasopharynx and liver are more prevalent in this region. Here we examine in more detail whether years served in SEA had any effect on the risk of cancer among Comparison veterans.

Sea Spray Generation at a Rocky Shoreline

Science.gov (United States)

2015-07-01

Tanya Lubansky, and Lindsey Nielsen for logistics support and company on the 541 “Rock”; and Chris Fairall, Dan Wolfe , and Sergio Pezoa of NOAA/ESRL...the turbulent air-sea heat fluxes. J. Geophys. Res., 97, 603 11429–11441. 604 , 2002a: Parameterizing scalar transfer over snow and ice

X-ray vision of fuel sprays

International Nuclear Information System (INIS)

Wang, J.

2005-01-01

With brilliant synchrotron X-ray sources, microsecond time-resolved synchrotron X-ray radiography and tomography have been used to elucidate the detailed three-dimensional structure and dynamics of high-pressure high-speed fuel sprays in the near-nozzle region. The measurement allows quantitative determination of the fuel distribution in the optically impenetrable region owing to the multiple scattering of visible light by small atomized fuel droplets surrounding the jet. X-radiographs of the jet-induced shock waves prove that the fuel jets become supersonic under appropriate injection conditions and that the quantitative analysis of the thermodynamic properties of the shock waves can also be derived from the most direct measurement. In other situations where extremely axial-asymmetric sprays are encountered, mass deconvolution and cross-sectional fuel distribution models can be computed based on the monochromatic and time-resolved X-radiographic images collected from various rotational orientations of the sprays. Such quantitative analysis reveals the never-before-reported characteristics and most detailed near-nozzle mass distribution of highly transient fuel sprays

Plasma-sprayed tantalum/alumina cermets

International Nuclear Information System (INIS)

Kramer, C.M.

1977-12-01

Cermets of tantalum and alumina were fabricated by plasma spraying, with the amount of alumina varied from 0 to 65 percent (by volume). Each of four compositions was then measured for tensile strength, elastic modulus, and coefficient of thermal expansion. In general, strength and strain to failure decreased with increasing alumina content: 62 MPa for 100 percent Ta to 19 MPa for 35 v percent Ta. A maximum of 0.1 percent strain was observed for the sprayed 100 percent Ta specimens. The coefficient of thermal expansion measured for the pure Ta was 6.2 (10 -6 )/K

Global change and the measurement of absolute sea-level

Science.gov (United States)

Diamante, John M.; Pyle, Thomas E.; Carter, William E.; Scherer, Wolfgang

To quantify properly the long-term response of sea-level to climate change, land motions must be separated from the apparent or relative sea-level change recorded by conventional tide/sea-level gauges. Here we present a concept for global measurement of the true or “absolute” sea-level change, which combines recent advances in space-based geodetic techniques with plans for a global sea-level network under the World Climate Research Programme (WCRP). Data from initial feasibility tests show that land motion, due to global (plate tectonic), regional (glacial rebound), or local (fluid withdrawal) effects, can probably be measured to ±1cm (on a single measurement basis) by an innovative combination of Very Long Baseline Interferometry (VLBI) and Global Positioning System (GPS) tevhniques. By making repeated observations of position at a number of tide gauges using portable, economical GPS receivers in a differential mode relative to the fewer, more stable, but more expensive VLBI observatories, it will be possible to subtract land motion from the relative sea-level signal. Decadal to century scale trends at the 1-2mm y -1 level will be resolvable in the sea-level and vertical land motion time series within about a decade. Detection of subsidence or uplift at specific gauges will allow correction for land motion or deletion of bad data when computing regional or global, i.e. eustatic, sea-level changes. In addition to their applications in oceanography and climate studies, such data will test models by Peltier and other that relate mantle viscosity and deglaciation history to present rates of crustal subsidence or uplift. If the predicted crustal motions are confirmed, we can also have more confidence in the use of historical tide/sea-level gauge records in retrospective studies of sea-level change related to climate variability on decadal or longer time scales. It is concluded that as few as one-third (about 100) of the total number of tide/sea-level gauges (250

The Influence of Air-Sea Fluxes on Atmospheric Aerosols During the Summer Monsoon Over the Tropical Indian Ocean

Science.gov (United States)

Zavarsky, Alex; Booge, Dennis; Fiehn, Alina; Krüger, Kirstin; Atlas, Elliot; Marandino, Christa

2018-01-01

During the summer monsoon, the western tropical Indian Ocean is predicted to be a hot spot for dimethylsulfide emissions, the major marine sulfur source to the atmosphere, and an important aerosol precursor. Other aerosol relevant fluxes, such as isoprene and sea spray, should also be enhanced, due to the steady strong winds during the monsoon. Marine air masses dominate the area during the summer monsoon, excluding the influence of continentally derived pollutants. During the SO234-2/235 cruise in the western tropical Indian Ocean from July to August 2014, directly measured eddy covariance DMS fluxes confirm that the area is a large source of sulfur to the atmosphere (cruise average 9.1 μmol m-2 d-1). The directly measured fluxes, as well as computed isoprene and sea spray fluxes, were combined with FLEXPART backward and forward trajectories to track the emissions in space and time. The fluxes show a significant positive correlation with aerosol data from the Terra and Suomi-NPP satellites, indicating a local influence of marine emissions on atmospheric aerosol numbers.

High quality ceramic coatings sprayed by high efficiency hypersonic plasma spraying gun

International Nuclear Information System (INIS)

Zhu Sheng; Xu Binshi; Yao JiuKun

2005-01-01

This paper introduced the structure of the high efficiency hypersonic plasma spraying gun and the effects of hypersonic plasma jet on the sprayed particles. The optimised spraying process parameters for several ceramic powders such as Al 2 O 3 , Cr 2 O 3 , ZrO 2 , Cr 3 C 2 and Co-WC were listed. The properties and microstructure of the sprayed ceramic coatings were investigated. Nano Al 2 O 3 -TiO 2 ceramic coating sprayed by using the high efficiency hypersonic plasma spraying was also studied. Compared with the conventional air plasma spraying, high efficiency hypersonic plasma spraying improves greatly the ceramic coatings quality but at low cost. (orig.)

Effect of spray angle and spray volume on deposition of a medium droplet spray with air support in ivy pot plants.

Science.gov (United States)

Foqué, Dieter; Pieters, Jan G; Nuyttens, David

2014-03-01

Spray boom systems, an alternative to the predominantly-used spray guns, have the potential to considerably improve crop protection management in glasshouses. Based on earlier experiments, the further optimization of the deposits of a medium spray quality extended range flat fan nozzle type using easy adjustable spray boom settings was examined. Using mineral chelate tracers and water sensitive papers, the spray results were monitored at three plant levels, on the upper side and the underside of the leaves, and on some off-target collectors. In addition, the deposition datasets of all tree experiments were compared. The data showed that the most efficient spray distribution with the medium spray quality flat fan nozzles was found with a 30° forward angled spray combined with air support and an application rate of 1000 L ha(-1) . This technique resulted in a more uniform deposition in the dense canopy and increased spray deposition on the lower side of the leaves compared with the a standard spray boom application. Applying 1000 L ha(-1) in two subsequent runs instead of one did not seem to show any added value. Spray deposition can be improved hugely simply by changing some spray boom settings like nozzle type, angling the spray, using air support and adjusting the spray volume to the crop. © 2013 Society of Chemical Industry.

Fluctuations of a spray generated by an airblast atomizer

Energy Technology Data Exchange (ETDEWEB)

Batarseh, Feras Z.; Gnirss, Markus; Roisman, Ilia V.; Tropea, Cameron [Technische Universitaet Darmstadt (Germany). Chair of Fluid Mechanics and Aerodynamics

2009-06-15

This paper is devoted to the study of the aerodynamic instability of the spray generated by an airblast atomizer. As a result of this instability the spray shape and its velocity fluctuate with a certain frequency, which depends on the operational parameters of the atomizer. The effect of three parameters, namely; chamber pressure, liquid phase flow rate and the gas phase flow rate on the spray fluctuating frequency are investigated. The velocity vector of the drops in the spray and the arrival times to the detection volume are measured using the laser Doppler instrument. The slotting technique is applied to the data of axial velocity and arrival times of the drops in order to estimate the dominating spray frequencies. Additionally, the shape of the spray has been observed using the high-speed video system. The frequencies of the shape fluctuations are estimated using proper orthogonal decomposition of the time-resolved images of the spray. We show that the frequencies of the spray velocity and those exhibited by spray shape coincide over a wide range of spray parameters. Finally, a simple scaling for the spray frequency is proposed and validated by the experimental data. (orig.)

Sea spray as a source of ice nucleating particles - results from the AIDA Ocean03 campaign

Science.gov (United States)

Salter, M. E.; Ickes, L.; Adams, M.; Bierbauer, S.; Bilde, M.; Christiansen, S.; Ekman, A.; Gorokhova, E.; Höhler, K.; Kiselev, A. A.; Leck, C.; Mohr, C.; Mohler, O.; Murray, B. J.; Porter, G.; Ullrich, R.; Wagner, R.

2017-12-01

Clouds and their radiative effects are one of the major influences on the radiative fluxes in the atmosphere, but at the same time they remain the largest uncertainty in climate models. This lack of understanding is especially pronounced in the high Arctic. Summertime clouds can persist over long periods in this region, which is difficult to replicate in models based on our current understanding. The clouds most often encountered in the summertime high Arctic consist of a mixture of ice crystals and super-cooled water droplets, so-called mixed-phase clouds. This cloud type is sensitive to the availability of aerosol particles, which can act as cloud condensation nuclei and ice nuclei. However, since the high Arctic is a pristine region, aerosol particles are not very abundant, and the hypothesis of open leads in the Arctic as a potentially important source of cloud and ice nucleating particles via bubble bursting has emerged. In this context, we have conducted a series of experiments at the AIDA chamber at KIT, designed to investigate the mechanisms linking marine biology, seawater chemistry and aerosol physics/potential cloud impacts. During this campaign, two marine diatom species (Melosira arctica and Skeletonema marinoi) as well as sea surface microlayer samples collected during several Arctic Ocean research cruises were investigated. To aerosolize the samples, a variety of methods were used including a sea spray simulation chamber to mimic the process of bubble-bursting. The ice nucleating efficiency (mixed-phase cloud regime) of the samples was determined either directly in the AIDA chamber during adiabatic expansions, or using the INKA continuous flow diffusion chamber, or a cold stage. Results from the campaign along with the potential implications are presented.

Spray characteristics and spray cooling heat transfer in the non-boiling regime

International Nuclear Information System (INIS)

Cheng, Wen-Long; Han, Feng-Yun; Liu, Qi-Nie; Fan, Han-Lin

2011-01-01

Spray cooling is an effective method for dissipating high heat fluxes in the field of electronics thermal control. In this study, experiments were performed with distilled water as a test liquid to study the spray cooling heat transfer in non-boiling regime. A Phase Doppler Anemometry (PDA) was used to study the spray characteristics. The effects of spray flow rate, spray height, and inlet temperature on spray cooling heat transfer were investigated. It was found that the parameters affect heat transfer of spray cooling in non-boiling regime by the spray characteristics and working fluid thermophysical properties. Then the corresponding droplet axial velocity and Sauter mean diameter (SMD) were successfully correlated with mean absolute error of 15%, which were based upon the orifice diameter, the Weber and Reynolds numbers of the orifice flow prior to liquid breakup, dimensionless spray height and spray cross-section radius. The heat transfer in non-boiling regime was correlated with a mean absolute error of 7%, which was mainly associated with the working fluid thermophysical properties, the Weber and Reynolds numbers hitting the heating surface, dimensionless heating surface temperature and diameter. -- Highlights: → The spray flow rate, spray height, and inlet temperature affect heat transfer of spray cooling in non-boiling regime by the spray characteristics and the working fluid thermophysical properties. → Then the corresponding droplet axial velocity and Sauer mean diameter (SMD) were successfully correlated with mean absolute error of 15%. → The heat transfer in non-boiling regime was correlated with a mean absolute error of 7%.

Water transparency measurements in the deep Ionian Sea

CERN Document Server

Anassontzis, E G; Belias, A; Fotiou, A; Grammatikakis, G; Kontogiannis, H; Koske, P; Koutsoukos, S; Lykoussis, V; Markopoulos, E; Psallidas, A; Resvanis, L K; Siotis, I; Stavrakakis, S; Stavropoulos, G; Zhukov, V A

2010-01-01

A long optical base line spectrophotometer designed to measure light transmission in deep sea waters is described. The variable optical path length allows measurements without the need for absolute or external calibration. The spectrophotometer uses eight groups of uncollimated light sources emitting in the range 370–530 nm and was deployed at various depths at two locations in the Ionian Sea that are candidate sites for a future underwater neutrino telescope. Light transmission spectra at the two locations are presented and compared.

Sensors Based Measurement Techniques of Fuel Injection and Ignition Characteristics of Diesel Sprays in DI Combustion System

Directory of Open Access Journals (Sweden)

S. Rehman

2016-09-01

Full Text Available Innovative sensor based measurement techniques like needle lift sensor, photo (optical sensor and piezoresistive pressure transmitter are introduced and used to measure the injection and combustion characteristics in direct injection combustion system. Present experimental study is carried out in the constant volume combustion chamber to study the ignition, combustion and injection characteristics of the solid cone diesel fuel sprays impinging on the hot surface. Hot surface ignition approach has been used to create variety of advanced combustion systems. In the present study, the hot surface temperatures were varied from 623 K to 723 K. The cylinder air pressures were 20, 30 and 40 bar and fuel injection pressures were 100, 200 and 300 bar. It is found that ignition delay of fuel sprays get reduced with the rise in injection pressure. The ignition characteristics of sprays much less affected at high fuel injection pressures and high surface temperatures. The fuel injection duration reduces with the increase in fuel injection pressures. The rate of heat release becomes high at high injection pressures and it decreases with the increase in injection duration. It is found that duration of burn/combustion decrease with the increase in injection pressure. The use of various sensors is quite effective, reliable and accurate in measuring the various fuel injection and combustion characteristics. The study simulates the effect of fuel injection system parameters on combustion performance in large heavy duty engines.

Measurement of spectral sea ice albedo at Qaanaaq fjord in northwest Greenland

Science.gov (United States)

Tanikawa, T.

2017-12-01

The spectral albedos of sea ice were measured at Qaanaaq fjord in northwest Greenland. Spectral measurements were conducted for sea ice covered with snow and sea ice without snow where snow was artificially removed around measurement point. Thickness of the sea ice was approximately 1.3 m with 5 cm of snow over the sea ice. The measurements show that the spectral albedos of the sea ice with snow were lower than those of natural pure snow especially in the visible regions though the spectral shapes were similar to each other. This is because the spectral albedos in the visible region have information of not only the snow but also the sea ice under the snow. The spectral albedos of the sea ice without the snow were approximately 0.4 - 0.5 in the visible region, 0.05-0.25 in the near-infrared region and almost constant of approximately 0.05 in the region of 1500 - 2500 nm. In the visible region, it would be due to multiple scattering by an air bubble within the sea ice. In contrast, in the near-infrared and shortwave infrared wavelengths, surface reflection at the sea ice surface would be dominant. Since a light absorption by the ice in these regions is relatively strong comparing to the visible region, the light could not be penetrated deeply within the sea ice, resulting that surface reflection based on Fresnel reflection would be dominant. In this presentation we also show the results of comparison between the radiative transfer calculation and spectral measurement data.

Agricultural sprays in cross-flow and drift

DEFF Research Database (Denmark)

Farooq, M.; Balachandar, R.; Wulfsohn, Dvoralai

2001-01-01

The droplet size and velocity characteristics of an agricultural spray were studied in a wind tunnel in the presence of a non-uniform cross-flow. The spray was generated at three nozzle-operating pressures. The droplet size and velocity was measured in both the cross-flow direction and the vertical...

Advanced Research in Diesel Fuel Sprays Using X-rays From The Advanced Photon Source

International Nuclear Information System (INIS)

Powell, C.

2003-01-01

The fuel distribution and degree of atomization in the combustion chamber is a primary factor in the formation of emissions in diesel engines. A number of diagnostics to study sprays have been developed over the last twenty years; these are primarily based on visible light measurement techniques. However, visible light scatters strongly from fuel droplets surrounding the spray, which prevents penetration of the light. This has made quantitative measurements of the spray core very difficult, particularly in the relatively dense near- nozzle region [1-3]. For this reason we developed the x-ray technique to study the properties of fuel sprays in a quantitative way [4]. The x-ray technique is not limited by scattering, which allows it to be used to make quantitative measurements of the fuel distribution. These measurements are particularly effective in the region near the nozzle where other techniques fail. This technique has led to a number of new insights into the structure of fuel sprays, including the discovery and quantitative measurement of shock waves generated under some conditions by high-pressure diesel sprays [5]. We also performed the first-ever quantitative measurements of the time-resolved mass distribution in the near-nozzle region, which demonstrated that the spray is atomized only a few nozzle diameters from the orifice [6]. Our recent work has focused on efforts to make measurements under pressurized ambient conditions. We have recently completed a series of measurements at pressures up to 5 bar and are looking at the effect of ambient pressure on the structure of the spray. The enclosed figure shows the mass distributions measured for 1,2, and 5 bar ambient pressures. As expected, the penetration decreases as the pressure increases. This leads to changes in the measured mass distribution, including an increase in the density at the leading edge of the spray. We have also observed a narrowing in the cone angle of the spray core as the pressure

Layered growth with bottom-spray granulation for spray deposition of drug.

Science.gov (United States)

Er, Dawn Z L; Liew, Celine V; Heng, Paul W S

2009-07-30

The gap in scientific knowledge on bottom-spray fluidized bed granulation has emphasized the need for more studies in this area. This paper comparatively studied the applicability of a modified bottom-spray process and the conventional top-spray process for the spray deposition of a micronized drug during granulation. The differences in circulation pattern, mode of growth and resultant granule properties between the two processes were highlighted. The more ordered and consistent circulation pattern of particles in a bottom-spray fluidized bed was observed to give rise to layered granule growth. This resulted in better drug content uniformity among the granule batches and within a granule batch. The processes' sensitivities to wetting and feed material characteristics were also compared and found to differ markedly. Less robustness to differing process conditions was observed for the top-spray process. The resultant bottom-spray granules formed were observed to be less porous, more spherical and had good flow properties. The bottom-spray technique can thus be potentially applied for the spray deposition of drug during granulation and was observed to be a good alternative to the conventional technique for preparing granules.

Development of cold sprayed Cu coating for canister

International Nuclear Information System (INIS)

Kim, Hyung Jun; Kang, Yoon Ha

2010-01-01

Cold sprayed Cu deposition was studied for the application of outer part of canister for high level nuclear waste. Five commercially available pure Cu powders were analyzed and sprayed by high pressure cold spray system. Electrochemical corrosion test using potentiostat in 3.5% NaCl solution was conducted as well as microstructural analysis including hardness and oxygen content measurements. Overall evaluation of corrosion performance of cold sprayed Cu deposition is inferior to forged and extruded Cu plates, but some of Cu depositions are comparable to Cu plates. The simulated corrosion test in 200m underground cave is still in progress. The effect of cold spray process parameters was also studied and the results show that the type of nozzle is the most important other than powder feed rate, spray distance, and scan speed. 1/10 scale miniature of canister was manufactured confirming that the production of full scale canister is possible

Investigation of Water-spray Cooling of Turbine Blades in a Turbojet Engine

Science.gov (United States)

Freche, John C; Stelpflug, William J

1953-01-01

An analytical and experimental investigation was made with a J33-A-9 engine to determine the effectiveness of spray cooling as a means of increasing thrust by permitting engine operation at inlet-gas temperatures and speeds above rated. With the assumption of adequate spray cooling at a coolant-to-gas flow ratio of 3 percent, calculations for the sea-level static condition indicated a thrust may be achieved by engine operation at an inlet-gas temperature of 2000 degrees F and an overspeed of 10 percent. Of the water-injection configurations investigated experimentally, those located in the inner ring of the stator diaphragm provided the best cooling at rated engine speed.

Spray droplet velocity characterization for convergent nozzles with three different diameters

Energy Technology Data Exchange (ETDEWEB)

R. Payri; B. Tormos; F.J. Salvador; L. Araneo [Universidad Politecnica de Valencia, Valencia (Spain). CMT-Motores Termicos

2008-11-15

The core of the present work consists of the phase-Doppler anemometry non-intrusive measurements performed at various points of diesel direct injection sprays in order to obtain the local speed of fuel droplets. The main objective was to perform extensive sets of measurements on convergent nozzles with various orifices diameters, observe and justify the differences and compare the experimental data with a theoretical approach derived by the authors in a previous work which takes into account the spray momentum flux. Experimental axial velocity profiles in different sections of the spray showed a radial distribution that was fitted with a high level of agreement to a Gaussian profile and so proving that this type of profile is a reasonable approach for the type of sprays within the scope of the present work. The experimental results showed that the velocity in the spray's axis inversely depends on axial position and that for a given axial position; higher axial velocity has been measured for the nozzles with higher spray momentum. 16 refs., 5 figs., 5 tabs.

Effect of spray application technique on spray deposition in greenhouse strawberries and tomatoes.

Science.gov (United States)

Braekman, Pascal; Foque, Dieter; Messens, Winy; Van Labeke, Marie-Christine; Pieters, Jan G; Nuyttens, David

2010-02-01

Increasingly, Flemish greenhouse growers are using spray booms instead of spray guns to apply plant protection products. Although the advantages of spray booms are well known, growers still have many questions concerning nozzle choice and settings. Spray deposition using a vertical spray boom in tomatoes and strawberries was compared with reference spray equipment. Five different settings of nozzle type, size and pressure were tested with the spray boom. In general, the standard vertical spray boom performed better than the reference spray equipment in strawberries (spray gun) and in tomatoes (air-assisted sprayer). Nozzle type and settings significantly affected spray deposition and crop penetration. Highest overall deposits in strawberries were achieved using air-inclusion or extended-range nozzles. In tomatoes, the extended-range nozzles and the twin air-inclusion nozzles performed best. Using smaller-size extended-range nozzles above the recommended pressure range resulted in lower deposits, especially inside the crop canopy. The use of a vertical spray boom is a promising technique for applying plant protection products in a safe and efficient way in tomatoes and strawberries, and nozzle choice and setting should be carefully considered.

Research Into Ni-Cr-Si-B Coating Sprayed Onto Aluminium Substrate Using the Method of Plasma Spray

Directory of Open Access Journals (Sweden)

Raimonda Lukauskaitė

2013-02-01

Full Text Available The article deals with Ni base coatings deposited on aluminium substrate applying the method of plasma spray. The purpose of the conducted research is to improve the physical and mechanical properties of coatings on the surface of aluminium alloy work pieces. Spraying on aluminium alloys encounters serious problems, and therefore this work analyses the ways to make the situation more favourable. Before spraying, the surfaces of substrates were modified employing chemical and mechanical pre-treatment methods. The aim of pre-treating aluminium alloys was to remove oxide layers from the aluminium surface. Coating microstructures and porosity were characterised applying optical microscopy. Differences in the roughness of pre-treated surfaces have been determined referring to profilometry. The paper investigates the influence of the adhesion of plasma spray coatings on aluminium surface pretreatment. Microhardness technique was applied for measuring the hardness of coatings. The study also describes and compares the mechanical properties of Ni base coatings deposited on different pre-treated aluminium substrates using plasma spray.Article in Lithuanian

Research Into Ni-Cr-Si-B Coating Sprayed Onto Aluminium Substrate Using the Method of Plasma Spray

Directory of Open Access Journals (Sweden)

Raimonda Lukauskaitė

2012-12-01

Full Text Available The article deals with Ni base coatings deposited on aluminium substrate applying the method of plasma spray. The purpose of the conducted research is to improve the physical and mechanical properties of coatings on the surface of aluminium alloy work pieces. Spraying on aluminium alloys encounters serious problems, and therefore this work analyses the ways to make the situation more favourable. Before spraying, the surfaces of substrates were modified employing chemical and mechanical pre-treatment methods. The aim of pre-treating aluminium alloys was to remove oxide layers from the aluminium surface. Coating microstructures and porosity were characterised applying optical microscopy. Differences in the roughness of pre-treated surfaces have been determined referring to profilometry. The paper investigates the influence of the adhesion of plasma spray coatings on aluminium surface pretreatment. Microhardness technique was applied for measuring the hardness of coatings. The study also describes and compares the mechanical properties of Ni base coatings deposited on different pre-treated aluminium substrates using plasma spray.Article in Lithuanian

Influence of fuel temperature on dispersion and decay of BDE sprays; Einfluss der Kraftstofftemperatur auf die Ausbreitung und den Zerfall von BDE-Sprays

Energy Technology Data Exchange (ETDEWEB)

Schmitz, I.; Beyrau, F.; Leipertz, A. [Erlangen-Nuernberg Univ., Erlangen (Germany). Lehrstuhl fuer Technische Thermodynamik

2007-07-01

As an example for a highly - developed technical spray system, the spray vaporization of a multi - hole injector used for the gasoline direct injection (GDI) has been investigated. Experiments were conducted in a heated injection chamber for different chamber pressures, fuels and fuel temperatures. In this investigation pure rotational coherent anti-Stokes Raman spectroscopy (RCARS) has been applied to the study of vaporizing sprays in combination with other laser techniques. Gas phase temperatures inside the sprays have been determined with high spatial and temporal resolution. A temperature drop of about 30 K was measured for all fuel temperatures studied. Droplet sizes and number densities have been measured using phase Doppler anemometry, and the correlation of these results with two - dimensional laser sheet Mie scattering images and laser-induced exciplex fluorescence allows an improved interpretation of the spray vaporization process. Furthermore under the influence of flash boiling a reduction of the mean drop size D10 up to 30% could be observed. (orig.)

A Planar-Fluorescence Imaging Technique for Studying Droplet-Turbulence Interactions in Vaporizing Sprays

Science.gov (United States)

Santavicca, Dom A.; Coy, E.

1990-01-01

Droplet turbulence interactions directly affect the vaporization and dispersion of droplets in liquid sprays and therefore play a major role in fuel oxidizer mixing in liquid fueled combustion systems. Proper characterization of droplet turbulence interactions in vaporizing sprays require measurement of droplet size velocity and size temperature correlations. A planar, fluorescence imaging technique is described which is being developed for simultaneously measuring the size, velocity, and temperature of individual droplets in vaporizing sprays. Preliminary droplet size velocity correlation measurements made with this technique are presented. These measurements are also compared to and show very good agreement with measurements made in the same spray using a phase Doppler particle analyzer.

Structure of steam water mixture spray

International Nuclear Information System (INIS)

Mitsuhashi, Yuki; Mizutani, Hiroya; Sanada, Toshiyuki; Saito, Takayuki

2008-01-01

The flow structure of steam and water mixture spray is studied both numerically and experimentally. The velocity and pressure profiles of the single phase flow are calculated using numerical methods. Using calculated flow fields, the droplet behavior is predicted by the one-way interaction model. This numerical analysis clarifies that the droplets are still accelerated after they are sprayed from the nozzle. In the experiments, the spray of the mixture is observed by using ultra high-speed video camera, and the velocity field is measured by using PIV technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, mixing process of steam and water, and atomization process of liquid film are observed through the transparent nozzle. The high-speed photography observation reveals that the flow inside the nozzle forms the annular flow and the most of the liquid film is atomized at the nozzle outlet. Finally, the optimum method of processing mixture of steam and water is proposed. (author)

Evaluation of mechanical properties of Aluminum-Copper cold sprayed and alloy 625 wire arc sprayed coatings

Science.gov (United States)

Bashirzadeh, Milad

This study examines microstructural-based mechanical properties of Al-Cu composite deposited by cold spraying and wire arc sprayed nickel-based alloy 625 coating using numerical modeling and experimental techniques. The microhardness and elastic modulus of samples were determined using the Knoop hardness technique. Hardness in both transverse and longitudinal directions on the sample cross-sections has been measured. An image-based finite element simulation algorithm was employed to determine the mechanical properties through an inverse analysis. In addition mechanical tests including, tensile, bending, and nano-indentation tests were performed on alloy 625 wire arc sprayed samples. Overall, results from the experimental tests are in relatively good agreement for deposited Al-Cu composites and alloy 625 coating. However, results obtained from numerical simulation are significantly higher in value than experimentally obtained results. Examination and comparison of the results are strong indications of the influence of microstructure characteristics on the mechanical properties of thermally spray deposited coatings.

High-Performance Molybdenum Coating by Wire–HVOF Thermal Spray Process

Science.gov (United States)

Tailor, Satish; Modi, Ankur; Modi, S. C.

2018-04-01

Coating deposition on many industrial components with good microstructural, mechanical properties, and better wear resistance is always a challenge for the thermal spray community. A number of thermal spray methods are used to develop such promising coatings for many industrial applications, viz. arc spray, flame spray, plasma, and HVOF. All these processes have their own limitations to achieve porous free, very dense, high-performance wear-resistant coatings. In this work, an attempt has been made to overcome this limitation. Molybdenum coatings were deposited on low-carbon steel substrates using wire-high-velocity oxy-fuel (W-HVOF; WH) thermal spray system (trade name HIJET 9610®). For a comparison, Mo coatings were also fabricated by arc spray, flame spray, plasma spray, and powder-HVOF processes. As-sprayed coatings were analyzed using x-ray diffraction, scanning electron microscopy for phase, and microstructural analysis, respectively. Coating microhardness, surface roughness, and porosity were also measured. Adhesion strength and wear tests were conducted to determine the mechanical and wear properties of the as-sprayed coatings. Results show that the coatings deposited by W-HVOF have better performance in terms of microstructural, mechanical, and wear resistance properties, in comparison with available thermal spray process (flame spray and plasma spray).

Measurement of Critical Heat Flux Using the Transient Inverse Heat Conduction Method in Spray cooling

Energy Technology Data Exchange (ETDEWEB)

Kim, Yeung Chan [Andong Nat’l Univ., Andong (Korea, Republic of)

2016-10-15

A study on the measurement of critical heat flux using the transient inverse heat conduction method in spray cooling was performed. The inverse heat conduction method estimates the surface heat flux or temperature using a measured interior temperature history. The effects of the measuring time interval and location of temperature measurement on the measurement of critical heat flux were primarily investigated. The following results were obtained. The estimated critical heat flux decreased as the time interval of temperature measurement increased. Meanwhile, the effect of measurement location on critical heat flux was not significant. It was also found, from the experimental results, that the critical superheat increased as the measurement location of thermocouple neared the heat transfer surface.

Measurement of Critical Heat Flux Using the Transient Inverse Heat Conduction Method in Spray cooling

International Nuclear Information System (INIS)

Kim, Yeung Chan

2016-01-01

A study on the measurement of critical heat flux using the transient inverse heat conduction method in spray cooling was performed. The inverse heat conduction method estimates the surface heat flux or temperature using a measured interior temperature history. The effects of the measuring time interval and location of temperature measurement on the measurement of critical heat flux were primarily investigated. The following results were obtained. The estimated critical heat flux decreased as the time interval of temperature measurement increased. Meanwhile, the effect of measurement location on critical heat flux was not significant. It was also found, from the experimental results, that the critical superheat increased as the measurement location of thermocouple neared the heat transfer surface.

Droplets Behavior of Hollow-Cone Spray in a Non-Condensable Environment

International Nuclear Information System (INIS)

Minoru Takahashi; Shin-ichi Kitagawa; Suizheng Qiu

2002-01-01

The characteristics of droplets in a water hollow-cone spray from nozzles 1.1 mm and 3.6 mm in diameter in an air environment have been investigated experimentally. The dual phase Doppler anemometry (PDA) system was used to measure the size and two velocity components of individual spherical particles. The liquid spray geometry, including spray breakup length and spray angle were also obtained experimentally. The mechanism and the influence of these parameters on a hollow cone spray flow were described. (authors)

Summary of the Blackmo 88 spray experiment

Science.gov (United States)

D. R. Miller; W. E. Yendol; M. L. McManus; D. E. Anderson; K. Mierzejewski

1991-01-01

The Blackmo 88 spray trial experiment was conducted for two primary purposes: To quantify the effects of local micrometeorological processes, in and near the canopy, on the deposition patterns of aerially applied BT in a mature oak forest; To generate a data set containing simultaneous measurements of spray deposition and detailed micrometeorology, in a canopy of known...

Measurement of the non-thermal properties in a low-pressure spraying plasma

International Nuclear Information System (INIS)

Jung, Yong Ho; Chung, Kyu Sun

2002-01-01

The non-thermal properties of a low-pressure spraying plasma have been characterized by using optical emission spectroscopy and single probes installed in a fast scanning probe system. A two-temperature model of the electrons is introduced to explain their non-isothermal properties, which are measured using single probes. The excitation temperatures of the atomic and the ionic lines are calculated from measurements of the emission intensities of Ar (I) and Ar (II), and those temperatures can be explained by using a local thermodynamic equilibrium (LTE) or a non-local thermodynamic equilibrium (non-LTE) model. In order to deduce more reasonable values (excitation temperatures), we introduce a multi-thermodynamic equilibrium (MTE) model, which gives different temperatures, depending upon the atomic excitation states

Spray cooling

International Nuclear Information System (INIS)

Rollin, Philippe.

1975-01-01

Spray cooling - using water spraying in air - is surveyed as a possible system for make-up (peak clipping in open circuit) or major cooling (in closed circuit) of the cooling water of the condensers in thermal power plants. Indications are given on the experiments made in France and the systems recently developed in USA, questions relating to performance, cost and environmental effects of spray devices are then dealt with [fr

Experiments on aerosol removal by high-pressure water spray

Energy Technology Data Exchange (ETDEWEB)

Corno, Ada del, E-mail: delcorno@rse-web.it [RSE, Power Generation Technologies and Materials Dept, via Rubattino 54, I-20134 Milano (Italy); Morandi, Sonia, E-mail: morandi@rse-web.it [RSE, Power Generation Technologies and Materials Dept, via Rubattino 54, I-20134 Milano (Italy); Parozzi, Flavio, E-mail: parozzi@rse-web.it [RSE, Power Generation Technologies and Materials Dept, via Rubattino 54, I-20134 Milano (Italy); Araneo, Lucio, E-mail: lucio.araneo@polimi.it [Politecnico di Milano, Department of Energy, via Lambruschini 4A, I-20156 Milano (Italy); CNR-IENI, via Cozzi 53, I-20125 Milano (Italy); Casella, Francesco, E-mail: francesco2.casella@mail.polimi.it [Politecnico di Milano, Department of Energy, via Lambruschini 4A, I-20156 Milano (Italy)

2017-01-15

Highlights: • Experimental research to measure the efficiency of high-pressure sprays in capturing aerosols if applied to a filtered containment venting system in case of severe accident. • Cloud of monodispersed SiO{sub 2} particles with sizes 0.5 or 1.0 μm and initial concentration in the range 2–90 mg/m{sup 3}. • Carried out in a chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls equipped with a high pressure water spray with single nozzle. • Respect to low-pressure sprays, removal efficiency turned out significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure sprays system. - Abstract: An experimental research was managed in the framework of the PASSAM European Project to measure the efficiency of high-pressure sprays in capturing aerosols when applied to a filtered containment venting system in case of severe accident. The campaign was carried out in a purposely built facility composed by a scrubbing chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls to permit the complete view of the aerosol removal process, where the aerosol was injected to form a cloud of specific particle concentration. The chamber was equipped with a high pressure water spray system with a single nozzle placed on its top. The test matrix consisted in the combination of water pressure injections, in the range 50–130 bar, on a cloud of monodispersed SiO{sub 2} particles with sizes 0.5 or 1.0 μm and initial concentration ranging between 2 and 99 mg/m{sup 3}. The spray was kept running for 2 min and the efficiency of the removal was evaluated, along the test time, using an optical particle sizer. With respect to low-pressure sprays, the removal efficiency turned out much more significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure spray system. The highest removal rate was

Experiments on aerosol removal by high-pressure water spray

International Nuclear Information System (INIS)

Corno, Ada del; Morandi, Sonia; Parozzi, Flavio; Araneo, Lucio; Casella, Francesco

2017-01-01

Highlights: • Experimental research to measure the efficiency of high-pressure sprays in capturing aerosols if applied to a filtered containment venting system in case of severe accident. • Cloud of monodispersed SiO_2 particles with sizes 0.5 or 1.0 μm and initial concentration in the range 2–90 mg/m"3. • Carried out in a chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls equipped with a high pressure water spray with single nozzle. • Respect to low-pressure sprays, removal efficiency turned out significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure sprays system. - Abstract: An experimental research was managed in the framework of the PASSAM European Project to measure the efficiency of high-pressure sprays in capturing aerosols when applied to a filtered containment venting system in case of severe accident. The campaign was carried out in a purposely built facility composed by a scrubbing chamber 0.5 × 1.0 m and 1.5 m high, with transparent walls to permit the complete view of the aerosol removal process, where the aerosol was injected to form a cloud of specific particle concentration. The chamber was equipped with a high pressure water spray system with a single nozzle placed on its top. The test matrix consisted in the combination of water pressure injections, in the range 50–130 bar, on a cloud of monodispersed SiO_2 particles with sizes 0.5 or 1.0 μm and initial concentration ranging between 2 and 99 mg/m"3. The spray was kept running for 2 min and the efficiency of the removal was evaluated, along the test time, using an optical particle sizer. With respect to low-pressure sprays, the removal efficiency turned out much more significant: the half-life for 1 μm particles with a removal high-pressure spray system is orders of magnitude shorter than that with a low-pressure spray system. The highest removal rate was detected with 1 �

Spray boom for selectively spraying a herbicidal composition onto dicots

DEFF Research Database (Denmark)

2012-01-01

There is provided a method and spray boom for discriminating cereal crop (monocot) and weeds (dicots). The spray boom includes means for digitally recording an image of a selected area to be treated by a nozzle on the spray boom, whereby a plant material is identified based on a segmentation proc...

Updating sea spray aerosol emissions in the Community Multiscale Air Quality (CMAQ) model version 5.0.2

Science.gov (United States)

Gantt, B.; Kelly, J. T.; Bash, J. O.

2015-11-01

Sea spray aerosols (SSAs) impact the particle mass concentration and gas-particle partitioning in coastal environments, with implications for human and ecosystem health. Model evaluations of SSA emissions have mainly focused on the global scale, but regional-scale evaluations are also important due to the localized impact of SSAs on atmospheric chemistry near the coast. In this study, SSA emissions in the Community Multiscale Air Quality (CMAQ) model were updated to enhance the fine-mode size distribution, include sea surface temperature (SST) dependency, and reduce surf-enhanced emissions. Predictions from the updated CMAQ model and those of the previous release version, CMAQv5.0.2, were evaluated using several coastal and national observational data sets in the continental US. The updated emissions generally reduced model underestimates of sodium, chloride, and nitrate surface concentrations for coastal sites in the Bay Regional Atmospheric Chemistry Experiment (BRACE) near Tampa, Florida. Including SST dependency to the SSA emission parameterization led to increased sodium concentrations in the southeastern US and decreased concentrations along parts of the Pacific coast and northeastern US. The influence of sodium on the gas-particle partitioning of nitrate resulted in higher nitrate particle concentrations in many coastal urban areas due to increased condensation of nitric acid in the updated simulations, potentially affecting the predicted nitrogen deposition in sensitive ecosystems. Application of the updated SSA emissions to the California Research at the Nexus of Air Quality and Climate Change (CalNex) study period resulted in a modest improvement in the predicted surface concentration of sodium and nitrate at several central and southern California coastal sites. This update of SSA emissions enabled a more realistic simulation of the atmospheric chemistry in coastal environments where marine air mixes with urban pollution.

Sea ice thickness measurements collected during the LOMROG 2007 and 2009 expeditions

DEFF Research Database (Denmark)

Skourup, Henriette; Forsberg, René; Hanson, Susanne

and 2009 we have collected a unique data set of late summer sea ice thickness, freeboard height and snow depth from the high Arctic Ocean during the time of the annual minimum sea ice extent. The data were collected by on-the-ground drilling and EM measurements. Here we give a brief overview of the data......According to scientific measurements, the Arctic sea ice extent has declined dramatically over the past thirty years, with the most extreme decline seen in the summer melt season. Other observations indicate that the sea ice has become thinner and perennial ice less widely distributed...... collection, as well as the results including the freeboard-to-sea-ice thickness conversion factor, which is used when interpreting freeboard heights measured by remote sensing....

Reduction of spray pressure leads to less emission and better deposition of spray liquid at high-volume spraying in greenhouse tomato

NARCIS (Netherlands)

Os, van E.A.; Michielsen, J.M.G.P.; Corver, F.J.M.; Berg, van den J.V.; Bruins, M.A.; Porskamp, H.A.J.; Zande, van de J.C.

2005-01-01

In an experimental greenhouse, growing a tomato crop, it was investigated if a reduction in spray pressure could improve the spray result, while, simultaneously, emission to the ground could be reduced. Spray deposition on the leaves and the emission to the ground was evaluated at different spray

Experimental characterisation of sprays resulting from impacts of liquid-containing projectiles

Energy Technology Data Exchange (ETDEWEB)

Hostikka, Simo, E-mail: simo.hostikka@aalto.fi [Aalto University, Espoo (Finland); Silde, Ari; Sikanen, Topi; Vepsä, Ari; Paajanen, Antti [VTT Technical Research Centre of Finland Ltd, Espoo (Finland); Honkanen, Markus [Pixact Oy, Tampere (Finland)

2015-12-15

Highlights: • Detailed characterisation of sprays resulting from the impacts of water-filled metal projectiles on a hard wall. • Experimental measurements of spray speed, direction and droplet size. • Detailed analysis of overall spray evolution. • The spray characterisation information can be used in CFD analyses of aircraft impact fires. - Abstract: Modelling and analysing fires following aircraft impacts requires information about the behaviour of liquid fuel. In this study, we investigated sprays resulting from the impacts of water-filled metal projectiles on a hard wall. The weights of the projectiles were in the range of 38–110 kg, with 8.6–68 kg water, and the impact speeds varied between 96 and 169 m/s. The overall spray behaviour was observed with high-speed video cameras. Ultra-high-speed cameras were used in backlight configuration for measuring the droplet size and velocity distributions. The results indicate that the liquid leaves the impact position as a thin sheet of spray in a direction perpendicular to the projectile velocity. The initial spray speeds were 1.5–2.5 times the impact speed, and the Sauter mean diameters were in the 147–344 μm range. This data can be used as boundary conditions in CFD fire analyses, considering the two-phase fuel flow. The overall spray observations, including the spray deceleration rate, can be used for validating the model.

Airborne Spectral Measurements of Surface-Atmosphere Anisotropy for Arctic Sea Ice and Tundra

Science.gov (United States)

Arnold, G. Thomas; Tsay, Si-Chee; King, Michael D.; Li, Jason Y.; Soulen, Peter F.

1999-01-01

Angular distributions of spectral reflectance for four common arctic surfaces: snow-covered sea ice, melt-season sea ice, snow-covered tundra, and tundra shortly after snowmelt were measured using an aircraft based, high angular resolution (1-degree) multispectral radiometer. Results indicate bidirectional reflectance is higher for snow-covered sea ice than melt-season sea ice at all wavelengths between 0.47 and 2.3 pm, with the difference increasing with wavelength. Bidirectional reflectance of snow-covered tundra is higher than for snow-free tundra for measurements less than 1.64 pm, with the difference decreasing with wavelength. Bidirectional reflectance patterns of all measured surfaces show maximum reflectance in the forward scattering direction of the principal plane, with identifiable specular reflection for the melt-season sea ice and snow-free tundra cases. The snow-free tundra had the most significant backscatter, and the melt-season sea ice the least. For sea ice, bidirectional reflectance changes due to snowmelt were more significant than differences among the different types of melt-season sea ice. Also the spectral-hemispherical (plane) albedo of each measured arctic surface was computed. Comparing measured nadir reflectance to albedo for sea ice and snow-covered tundra shows albedo underestimated 5-40%, with the largest bias at wavelengths beyond 1 pm. For snow-free tundra, nadir reflectance underestimates plane albedo by about 30-50%.

Study of Heterogeneous Structure in Diesel Fuel Spray by Using Micro-Probe L2F

Science.gov (United States)

Sakaguchi, Daisaku; Yamamoto, Shohei; Ueki, Hironobu; Ishdia, Masahiro

A L2F (Laser 2-Focus velocimeter) was applied for the measurements of the velocity and size of droplets in diesel fuel sprays. The micro-scale probe of the L2F has an advantage in avoiding the multiple scattering from droplets in a dense region of fuel sprays. A data sampling rate of 15MHz has been achieved in the L2F system for detecting almost all of the droplets which passed through the measurement probe. Diesel fuel was injected into the atmosphere by using a common rail injector. Measurement positions were located along the spray axis at 10, 15, 20, 25, and 30 mm from the nozzle exit. Measurement result showed that the velocity and size of droplets decreased and the number density of droplets increased along the spray axis. It was clearly shown that the mass flow rate in the spray was highest near the spray tip and was lower inside the spray.

Application of High Performance Computing for Simulations of N-Dodecane Jet Spray with Evaporation

Science.gov (United States)

2016-11-01

is unlimited. 10 6. References 1. Malbec L-M, Egúsquiza J, Bruneaux G, Meijer M. Characterization of a set of ECN spray A injectors : nozzle to...sprays and develop a predictive theory for comparison to measurements in the laboratory of turbulent diesel sprays. 15. SUBJECT TERMS high...models into future simulations of turbulent jet sprays and develop a predictive theory for comparison to measurements in the lab of turbulent diesel

Effects of nozzle type and spray angle on spray deposition in ivy pot plants.

Science.gov (United States)

Foqué, Dieter; Nuyttens, David

2011-02-01

Fewer plant protection products are now authorised for use in ornamental growings. Frequent spraying with the same product or a suboptimal technique can lead to resistance in pests and diseases. Better application techniques could improve the sustainable use of the plant protection products still available. Spray boom systems--instead of the still predominantly used spray guns--might improve crop protection management in greenhouses considerably. The effect of nozzle type, spray pressure and spray angle on spray deposition and coverage in ivy pot plants was studied, with a focus on crop penetration and spraying the bottom side of the leaves in this dense crop. The experiments showed a significant and important effect of collector position on deposition and coverage in the plant. Although spray deposition and coverage on the bottom side of the leaves are generally low, they could be improved 3.0-4.9-fold using the appropriate application technique. When using a spray boom in a dense crop, the nozzle choice, spray pressure and spray angle should be well considered. The hollow-cone, the air-inclusion flat-fan and the standard flat-fan nozzle with an inclined spray angle performed best because of the effect of swirling droplets, droplets with a high momentum and droplet direction respectively. Copyright © 2010 Society of Chemical Industry.

Lanthanide-based laser-induced phosphorescence for spray diagnostics

Energy Technology Data Exchange (ETDEWEB)

Voort, D. D. van der, E-mail: d.d.v.d.voort@tue.nl; Water, W. van de; Kunnen, R. P. J.; Clercx, H. J. H.; Heijst, G. J. F. van [Applied Physics Department, Eindhoven University of Technology, 5612 AZ Eindhoven (Netherlands); Maes, N. C. J.; Sweep, A. M.; Dam, N. J. [Mechanical Engineering Department, Eindhoven University of Technology, 5612 AZ Eindhoven (Netherlands); Lamberts, T. [Institute of Theoretical Chemistry, University of Stuttgart, D-70569 Stuttgart (Germany)

2016-03-15

Laser-induced phosphorescence (LIP) is a relatively recent and versatile development for studying flow dynamics. This work investigates certain lanthanide-based molecular complexes for their use in LIP for high-speed sprays. Lanthanide complexes in solutions have been shown to possess long phosphorescence lifetimes (∼1-2 ms) and to emit light in the visible wavelength range. In particular, europium and terbium complexes are investigated using fluorescence/phosphorescence spectrometry, showing that europium-thenoyltrifluoracetone-trioctylphosphineoxide (Eu-TTA-TOPO) can be easily and efficiently excited using a standard frequency-tripled Nd:YAG laser. The emitted spectrum, with maximum intensity at a wavelength of 614 nm, is shown not to vary strongly with temperature (293-383 K). The decay constant of the phosphorescence, while independent of ambient pressure, decreases by approximately 12 μs/K between 323 and 373 K, with the base level of the decay constant dependent on the used solvent. The complex does not luminesce in the gas or solid state, meaning only the liquid phase is visualized, even in an evaporating spray. By using an internally excited spray containing the phosphorescent complex, the effect of vaporization is shown through the decrease in measured intensity over the length of the spray, together with droplet size measurements using interferometric particle imaging. This study shows that LIP, using the Eu-TTA-TOPO complex, can be used with different solvents, including diesel surrogates. Furthermore, it can be easily handled and used in sprays to investigate spray breakup and evaporation.

Measurements of sea level off Tikkavanipalem - Coast India

Digital Repository Service at National Institute of Oceanography (India)

Joseph, A.; Desai, R.G.P.; Peshwe, V.B.; Desa, E.; VijayKumar, K.; Desa, E.S.; Mehra, P.; Nagvekar, S.

, and meteorological measurements were also made during this one-year period. These measurements have indicated that the sea level along this coast contains contributions from several classes of motions, principally tidal motions and set-up/set-down motions...

Investigation and evaluation of airborne pollution in the framework of PARCOM (North Sea) and HELCOM (Baltic Sea) - subproject: Measurements of trace metals

International Nuclear Information System (INIS)

Schneider, B.

1993-01-01

On the basis of measurements of the deposition and concentrations of atmospheric trace metals the annual input of some selected elements (Pb, Zn, Cd, Ni, V) into the North Sea and the Baltic Sea was estimated. For the Baltic Sea, deposition measurements with a buoy system in the Kiel Bight and data from the EGAP(HELCOM)-monitoring network were used. Data from the measurement stations were extrapolated to related sub-basins according to the deposition fields obtained from model calculations (EMEP). For the North Sea, a mean atmospheric trace metal distribution was determined from numerous measurements at a coastal site and over the central North Sea and the annual input was calculated by multiplication with corresponding deposition velocities and scavenging ratios. A comparison of the deposition data based on measurements with those from model calculations show good agreement in the case of Pb in the Baltic Sea as well as in the North Sea. However, for Zn and Cd large discrepancies are observed. Additionally, deposition processes were studied. Scavenging ratios were determined and dry deposition velocities were estimated by the use of a new method for high time resolution measurements of atmospheric trace metal concentrations (impactor/TXRF). (orig.). 9 figs., 14 tabs [de

Characterization of the spray velocities from a pressurized metered-dose inhaler.

Science.gov (United States)

Crosland, Brian Michael; Johnson, Matthew Ronald; Matida, Edgar Akio

2009-06-01

Pressurized metered dose inhalers (pMDIs) are widely used to deliver aerosolized medications to the lungs, most often to relieve the symptoms of asthma. Over the past decade, pMDIs have been modified in several ways to eliminate the use of chlorofluorocarbons in their manufacture while increasing efficacy. Numerical simulations are being used more frequently to predict the flow and deposition of particles at various locations, both inside the respiratory tract as well as in pMDIs and add-on devices. These simulations require detailed information about the spray generated by a pMDI to ensure the validity of their results. This paper presents detailed, spatially resolved velocity measurements of the spray emitted from salbutamol sulfate pMDIs obtained using optically triggered particle image velocimetry (PIV). Instantaneous planar velocity measurements were taken and ensemble-averaged at nine different times during the spray event ranging from 1.3 to 100 msec after a pneumatically controlled actuation. The mean spray velocities were shown to be bimodal in time, with two velocity peaks and velocity magnitudes found to be much lower than published data from instantaneous single point measurements. Planar velocity data at each time step were analyzed to produce prescriptive velocity profiles suitable for use in numerical simulations. Spray geometry data are also reported. Statistical comparisons from several thousand individual spray events indicate that there is no significant difference in measured velocity among (1) two brands of pMDI canisters, (2) two pMDIs of the same brand but having different lot numbers, and (3) a full pMDI versus an almost empty pMDI. The addition of a secondary air flow of 30 SLPM (to represent simultaneous inhalation and spray actuation) deflected the spray downward but did not have a significant effect on flow velocity. Further experiments with an added cylindrical spacer revealed that within the spacer, the spray direction and cone angle

Novel Online Diagnostic Analysis for In-Flight Particle Properties in Cold Spraying

Science.gov (United States)

Koivuluoto, Heli; Matikainen, Ville; Larjo, Jussi; Vuoristo, Petri

2018-02-01

In cold spraying, powder particles are accelerated by preheated supersonic gas stream to high velocities and sprayed on a substrate. The particle velocities depend on the equipment design and process parameters, e.g., on the type of the process gas and its pressure and temperature. These, in turn, affect the coating structure and the properties. The particle velocities in cold spraying are high, and the particle temperatures are low, which can, therefore, be a challenge for the diagnostic methods. A novel optical online diagnostic system, HiWatch HR, will open new possibilities for measuring particle in-flight properties in cold spray processes. The system employs an imaging measurement technique called S-PTV (sizing-particle tracking velocimetry), first introduced in this research. This technique enables an accurate particle size measurement also for small diameter particles with a large powder volume. The aim of this study was to evaluate the velocities of metallic particles sprayed with HPCS and LPCS systems and with varying process parameters. The measured in-flight particle properties were further linked to the resulting coating properties. Furthermore, the camera was able to provide information about variations during the spraying, e.g., fluctuating powder feeding, which is important from the process control and quality control point of view.

Containment atmosphere response to external sprays

International Nuclear Information System (INIS)

Green, J.; Almenas, K.

1995-01-01

The application of external sprays to a containment steel shell can be an effective energy removal method and has been proposed in the passive AP-600 design. Reduction of the steel shell temperature in contact with the containment atmosphere enhances both heat and mass transfer driving forces. Large scale experimental data in this area is scarce, therefore the measurements obtained from the E series tests conducted at the German HDR facility deserve special attention. These long term tests simulated various severe accident conditions, including external spraying of the hemispherical steel shell. This investigation focuses upon the integral response of the HDR containment atmosphere during spray periods and upon methods by which lumped parameter system codes, like CONTAIN, model the underlying condensation phenomena. Increases in spray water flowrates above a minimum value were ineffective at improving containment pressure reduction since the limiting resistance for energy transfer lies in the noncondensable-vapor boundary layer at the inner condensing surface. The spray created an unstable condition by cooling the upper layers of a heated atmosphere and thus inducing global natural circulation flows in the facility and subsequently, abrupt changes in lighter-than-air noncondensable (J 2 /He) concentrations. Modeling results using the CONTAIN code are outlined and code limitations are delineated

Containment atmosphere response to external sprays

Energy Technology Data Exchange (ETDEWEB)

Green, J.; Almenas, K. [Univ. of Maryland, College Park, MD (United States)

1995-09-01

The application of external sprays to a containment steel shell can be an effective energy removal method and has been proposed in the passive AP-600 design. Reduction of the steel shell temperature in contact with the containment atmosphere enhances both heat and mass transfer driving forces. Large scale experimental data in this area is scarce, therefore the measurements obtained from the E series tests conducted at the German HDR facility deserve special attention. These long term tests simulated various severe accident conditions, including external spraying of the hemispherical steel shell. This investigation focuses upon the integral response of the HDR containment atmosphere during spray periods and upon methods by which lumped parameter system codes, like CONTAIN, model the underlying condensation phenomena. Increases in spray water flowrates above a minimum value were ineffective at improving containment pressure reduction since the limiting resistance for energy transfer lies in the noncondensable-vapor boundary layer at the inner condensing surface. The spray created an unstable condition by cooling the upper layers of a heated atmosphere and thus inducing global natural circulation flows in the facility and subsequently, abrupt changes in lighter-than-air noncondensable (J{sub 2}/He) concentrations. Modeling results using the CONTAIN code are outlined and code limitations are delineated.

Flow structure of steam-water mixed spray

International Nuclear Information System (INIS)

Sanada, Toshiyuki; Mitsuhashi, Yuki; Mizutani, Hiroya; Saito, Takayuki

2010-01-01

In this study, the flow structure of a steam-water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.

Flow structure of steam-water mixed spray

Energy Technology Data Exchange (ETDEWEB)

Sanada, Toshiyuki, E-mail: ttsanad@ipc.shizuoka.ac.j [Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Shizuoka (Japan); Mitsuhashi, Yuki; Mizutani, Hiroya; Saito, Takayuki [Department of Mechanical Engineering, Shizuoka University, 3-5-1 Johoku, Naka-ku, Hamamatsu 432-8561, Shizuoka (Japan)

2010-12-15

In this study, the flow structure of a steam-water mixed spray is studied both numerically and experimentally. The velocity and pressure profiles of single-phase flow are calculated using numerical methods. On the basis of the calculated flow fields, the droplet behavior is predicted by a one-way interaction model. This numerical analysis reveals that the droplets are accelerated even after they are sprayed from the nozzle. Experimentally, the mixed spray is observed using an ultra-high-speed video camera, and the velocity field is measured by using the oarticle image velocimetry (PIV) technique. Along with this PIV velocity field measurement, the velocities and diameters of droplets are measured by phase Doppler anemometry. Furthermore, the mixing process of steam and water and the atomization process of a liquid film are observed using a transparent nozzle. High-speed photography observations reveal that the flow inside the nozzle is annular flow and that most of the liquid film is atomized at the nozzle throat and nozzle outlet. Finally, the optimum mixing method for steam and water is determined.

The influence of spray properties on intranasal deposition.

Science.gov (United States)

Foo, Mow Yee; Cheng, Yung-Sung; Su, Wei-Chung; Donovan, Maureen D

2007-01-01

While numerous devices, formulations, and spray characteristics have been shown to influence nasal deposition efficiency, few studies have attempted to identify which of these interacting factors plays the greatest role in nasal spray deposition. The deposition patterns of solutions with a wide range of surface tensions and viscosities were measured using an MRI-derived nasal cavity replica. The resulting spray plumes had angles between 29 degrees and 80 degrees and contained droplet sizes (D(v50)) from 37-157 microm. Each formulation contained rhodamine 590 as a fluorescent marker for detection. Administration angles of 30 degrees , 40 degrees , or 50 degrees above horizontal were tested to investigate the role of user technique on nasal deposition. The amount of spray deposited within specific regions of the nasal cavity was determined by disassembling the replica and measuring the amount of rhodamine retained in each section. Most of the spray droplets were deposited onto the anterior region of the model, but sprays with small plume angles were capable of reaching the turbinate region with deposition efficiencies approaching 90%. Minimal dependence on droplet size, viscosity, or device was observed. Changes in inspiratory flow rate (0-60 L/min) had no significant effect on turbinate deposition efficiency. Both plume angle and administration angle were found to be important factors in determining deposition efficiency. For administration angles of 40 degrees or 50 degrees , maximal turbinate deposition efficiency (30-50%) occurred with plume angles of 55-65 degrees , whereas a 30 degrees administration angle gave an approximately 75% deposition efficiency for similar plume angles. Deposition efficiencies of approximately 90% could be achieved with plume angles deposition efficiency, while many other spray parameters, including particle size, have relatively minor influences on deposition within the nasal cavity.

Measurement of sea ice thickness using electromagnetic sounding; Denji tansaho wo mochiita kaihyoatsu no keisoku

Energy Technology Data Exchange (ETDEWEB)

Kawauchi, K; Suzuki, I; Goto, N [Muroran Institute of Technology, Hokkaido (Japan); Hoshiyama, K

1997-10-22

Thickness of sea ice is measured by an electromagnetic method making use of the peculiarities of sea ice. Sea ice floats on the seawater (saline water), and the result is two horizontal layers greatly different from each other in conductivity, with seawater being highly conductive and ice being non-conductive. A study is conducted on Lake Kumatori, a saline lake in Abashiri City, in which effort a board of naturally frozen sea ice and a board of sea ice allowed to form on the sea surface at a spot from which ice has been removed are examined. A portable electromagnetic probe EM38 of GEONICS Company is employed to perform measurement in a horizontal dipole mode. To determine the relationship between the obtained conductivity measurements and sea ice thickness, holes are bored in the sea ice boards for the measurement of their thickness for the formulation of an experimental regression equation. Measurements along the traverse line 1 and traverse line 3 are converted into sea ice thickness by use of the experimental regression equation, and the result is that ice thickness is the greatest near the quay growing thinner away from the shore. The study shows that sea ice thickness may be measured accurately by electromagnetic probing. 3 refs., 10 figs.

Spinning projectile's attitude measurement with LW infrared radiation under sea-sky background

Science.gov (United States)

Xu, Miaomiao; Bu, Xiongzhu; Yu, Jing; He, Zilu

2018-05-01

With the further development of infrared radiation research in sea-sky background and the requirement of spinning projectile's attitude measurement, the sea-sky infrared radiation field is used to carry out spinning projectile's attitude angle instead of inertial sensors. Firstly, the generation mechanism of sea-sky infrared radiation is analysed. The mathematical model of sea-sky infrared radiation is deduced in LW (long wave) infrared 8 ∼ 14 μm band by calculating the sea surface and sky infrared radiation. Secondly, according to the movement characteristics of spinning projectile, the attitude measurement model of infrared sensors on projectile's three axis is established. And the feasibility of the model is analysed by simulation. Finally, the projectile's attitude calculation algorithm is designed to improve the attitude angle estimation accuracy. The results of semi-physical experiments show that the segmented interactive algorithm estimation error of pitch and roll angle is within ±1.5°. The attitude measurement method is effective and feasible, and provides accurate measurement basis for the guidance of spinning projectile.

Field experiment on spray drift: deposition and airborne drift during application to a winter wheat crop.

Science.gov (United States)

Wolters, André; Linnemann, Volker; van de Zande, Jan C; Vereecken, Harry

2008-11-01

A field experiment was performed to evaluate various techniques for measuring spray deposition and airborne drift during spray application to a winter wheat crop. The application of a spraying agent containing the fluorescent dye Brilliant Sulfo Flavine by a conventional boom sprayer was done according to good agricultural practice. Deposition was measured by horizontal collectors in various arrangements in and outside the treated area. Airborne spray drift was measured both with a passive and an active air collecting system. Spray deposits on top of the treated canopy ranged between 68 and 71% of the applied dose and showed only small differences for various arrangements of the collectors. Furthermore, only small variations were measured within the various groups of collectors used for these arrangements. Generally, the highest spray deposition outside the treated area was measured close to the sprayed plot and was accompanied by a high variability of values, while a rapid decline of deposits was detected in more remote areas. Estimations of spray deposits with the IMAG Drift Calculator were in accordance with experimental findings only for areas located at a distance of 0.5-4.5 m from the last nozzle, while there was an overestimation of a factor of 4 at a distance of 2.0-3.0 m, thus revealing a high level of uncertainty of the estimation of deposition for short distances. Airborne spray drift measured by passive and active air collecting systems was approximately at the same level, when taking into consideration the collector efficiency of the woven nylon wire used as sampling material for the passive collecting system. The maximum value of total airborne spray drift for both spray applications (0.79% of the applied dose) was determined by the active collecting system. However, the comparatively high variability of measurements at various heights above the soil by active and passive collecting systems revealed need for further studies to elucidate the spatial

A theoretical model for prediction of deposition efficiency in cold spraying

International Nuclear Information System (INIS)

Li Changjiu; Li Wenya; Wang Yuyue; Yang Guanjun; Fukanuma, H.

2005-01-01

The deposition behavior of a spray particle stream with a particle size distribution was theoretically examined for cold spraying in terms of deposition efficiency as a function of particle parameters and spray angle. The theoretical relation was established between the deposition efficiency and spray angle. The experiments were conducted by measuring deposition efficiency at different driving gas conditions and different spray angles using gas-atomized copper powder. It was found that the theoretically estimated results agreed reasonably well with the experimental ones. Based on the theoretical model and experimental results, it was revealed that the distribution of particle velocity resulting from particle size distribution influences significantly the deposition efficiency in cold spraying. It was necessary for the majority of particles to achieve a velocity higher than the critical velocity in order to improve the deposition efficiency. The normal component of particle velocity contributed to the deposition of the particle under the off-nomal spray condition. The deposition efficiency of sprayed particles decreased owing to the decrease of the normal velocity component as spray was performed at off-normal angle

In situ Measurements of Residual Stresses and Elelastic Moduli in Thermal Sprayed Coatings. Part 1: Apparatus and Analysis

Czech Academy of Sciences Publication Activity Database

Matějíček, Jiří; Sampath, S.

2003-01-01

Roč. 51, č. 3 (2003), s. 863-872 ISSN 1359-6454 Grant - others:NSF(US) DMR9632570 Institutional research plan: CEZ:AV0Z2043910 Keywords : coatings plasma spraying, mechanical properties testing, elastic modulus Subject RIV: JB - Sensors, Measurment, Regulation Impact factor: 3.059, year: 2003

Elastic response of thermal spray deposits under indentation tests

International Nuclear Information System (INIS)

Leigh, S.H.; Lin, C.K.; Berndt, C.C.

1997-01-01

The elastic response behavior of thermal spray deposits at Knoop indentations has been investigated using indentation techniques. The ration of hardness to elastic modulus, which is an important prerequisite for the evaluation of indentation fracture toughness, is determined by measuring the elastic recovery of the in-surface dimensions of Knoop indentations. The elastic moduli of thermal spray deposits are in the range of 12%--78% of the comparable bulk materials and reveal the anisotropic behavior of thermal spray deposits. A variety of thermal spray deposits has been examined, including Al 2 O 3 , yttria-stabilized ZrO 2 (YSZ), and NiAl. Statistical tools have been used to evaluate the error estimates of the data

Radiometric investigation of factors, influencing the spray characteristics of aerosol flasks filled with propellants

International Nuclear Information System (INIS)

Benkoe, Gy.; Stampf, Gy.; Csontos, A.; Gyarmati, L.

1976-01-01

The role of 16 sprayheads, 5 valve systems and 3 propellant mixtures has been investigated in influencing the spray characteristics of pharmaceuticals. The distribution of matter has been determined with the aid of radiometry. The 14 C activity of spray spots has been measured in a mosaic-like way determining the activity of each area of 1 cm 2 in the right-angles spot-coordinate system. A Frieseke-Hoepfner type, PB gas current scaler has been used for measuring activity. According to the results spray heads play a decisive role in influencing the spray characteristics of aerosol flasks filled with propellants. The different propellant mixtures and valve systems influence the spray characteristics only in a small degree and only when adjusted to a given spray head. The method is well applicable for qualification of spray heads in practice of both factories and hospitals. (K.A.)

Emulsions from Aerosol Sprays

Science.gov (United States)

Hengelmolen; Vincent; Hassall

1997-12-01

An electrostatic emulsification apparatus has been designed for the purpose of studying diffusion from oil droplets which have a mean size in the range of approximately 1.5-3.5 &mgr;m, with standard deviations of 40-50%. The emulsification technique involves the collection of a spray of electrically charged oil droplets onto a rotating water film which is sustained from a reservoir. In this way, emulsions with volume fractions of approximately 10(-3) are produced within several minutes at oil flow rates of around 10(-2) ml min-1. Phase-Doppler anemometry (PDA) was used to assess droplet size distributions for the sprays and emulsions. Results show that the mean emulsion droplet size was smaller than the mean spray droplet size by several orders of magnitude. At flow rates around 10(-2) ml min-1, the spray droplet size distribution was little affected by the applied potential between about -4.20 and -4.65 kV (mean droplet size between approximately 7.6 and 7.8 &mgr;m, with standard deviations of approximately 20%), whereas the mean droplet size of the corresponding emulsion decreased more rapidly with applied potential. Above an applied potential of approximately -4.30 kV, which corresponded to an emulsion droplet size below approximately 2 &mgr;m, the measured volume fraction of the emulsion decreased with respect to the volume fraction as calculated on the basis of total amount of injected oil. Copyright 1997 Academic Press. Copyright 1997Academic Press

Current implications of past DDT indoor spraying in Oman.

Science.gov (United States)

Booij, Petra; Holoubek, Ivan; Klánová, Jana; Kohoutek, Jiří; Dvorská, Alice; Magulová, Katarína; Al-Zadjali, Said; Čupr, Pavel

2016-04-15

In Oman, DDT was sprayed indoors during an intensive malaria eradication program between 1976 and 1992. DDT can remain for years after spraying and is associated with potential health risk. This raises the concern for human exposure in areas where DDT was used for indoor spraying. Twelve houses in three regions with a different history of DDT indoor spraying were chosen for a sampling campaign in 2005 to determine p,p'-dichlorodiphenyltrichloroethane (p,p'-DDT), p,p'-dichlorodiphenyldichloroethylene (p,p'-DDE) and p,p'-dichlorodiphenyldichloroethane (p,p'-DDD) levels in indoor air, dust, and outdoor soil. Although DDT was only sprayed indoor, p,p'-DDT, p,p'-DDE and p,p'-DDD were also found in outdoor soil. The results indicate that release and exposure continue for years after cessation of spraying. The predicted cancer risk based on concentrations determined in 2005, indicate that there was still a significant cancer risk up to 13 to 16years after indoor DDT spraying. A novel approach, based on region-specific half-lives, was used to predict concentrations in 2015 and showed that more than 21years after spraying, cancer risk for exposure to indoor air, dust, and outdoor soil are acceptable in Oman for adults and young children. The model can be used for other locations and countries to predict prospective exposure of contaminants based on indoor experimental measurements and knowledge about the spraying time-schedule to extrapolate region-specific half-lives and predict effects on the human population years after spraying. Copyright © 2015 Elsevier B.V. All rights reserved.

Modelling of fuel spray and combustion in diesel engines

Energy Technology Data Exchange (ETDEWEB)

Huttunen, M T; Kaario, O T [VTT Energy, Espoo (Finland)

1998-12-31

Fuel spray and air motion characteristics and combustion in direct injection (DI) diesel engines was studied using computational models of the commercial CFD-code FIRE. Physical subprocesses modelled included Lagrangian spray droplet movement and behaviour (atomisation, evaporation and interaction of spray droplets) and combustion of evaporated liquid spray in the gas phase. Fuel vapour combustion rate was described by the model of Magnussen and Hjertager. The standard k,{epsilon}-model was used for turbulence. In order to be able to predict combustion accurately, the fuel spray penetration should be predicted with reasonable accuracy. In this study, the standard drag coefficient had to be reduced in order to match the computed penetration to the measured one. In addition, the constants in the submodel describing droplet breakup also needed to be adjusted for closer agreement with the measurements. The characteristic time scale of fuel consumption rate k/C{sub R} {epsilon} strongly influenced the heat release and in-cylinder pressure. With a value around 2.0 to 5.0 for C{sub R}, the computed in-cylinder pressure during the compression stroke agreed quite well with the measurements. On the other hand, the in-cylinder pressure was underpredicted during the expansion stroke. This is partly due to the fact that hydrocarbon fuel combustion was modelled as a one-step reaction reading to CO{sub 2} and H{sub 2}O and inadequate description of the mixing of reactants and combustion products. (author) 16 refs.

Modelling of fuel spray and combustion in diesel engines

Energy Technology Data Exchange (ETDEWEB)

Huttunen, M.T.; Kaario, O.T. [VTT Energy, Espoo (Finland)

1997-12-31

Fuel spray and air motion characteristics and combustion in direct injection (DI) diesel engines was studied using computational models of the commercial CFD-code FIRE. Physical subprocesses modelled included Lagrangian spray droplet movement and behaviour (atomisation, evaporation and interaction of spray droplets) and combustion of evaporated liquid spray in the gas phase. Fuel vapour combustion rate was described by the model of Magnussen and Hjertager. The standard k,{epsilon}-model was used for turbulence. In order to be able to predict combustion accurately, the fuel spray penetration should be predicted with reasonable accuracy. In this study, the standard drag coefficient had to be reduced in order to match the computed penetration to the measured one. In addition, the constants in the submodel describing droplet breakup also needed to be adjusted for closer agreement with the measurements. The characteristic time scale of fuel consumption rate k/C{sub R} {epsilon} strongly influenced the heat release and in-cylinder pressure. With a value around 2.0 to 5.0 for C{sub R}, the computed in-cylinder pressure during the compression stroke agreed quite well with the measurements. On the other hand, the in-cylinder pressure was underpredicted during the expansion stroke. This is partly due to the fact that hydrocarbon fuel combustion was modelled as a one-step reaction reading to CO{sub 2} and H{sub 2}O and inadequate description of the mixing of reactants and combustion products. (author) 16 refs.

Reactor container spray device

International Nuclear Information System (INIS)

Yanai, Ryoichi.

1980-01-01

Purpose: To enable decrease in the heat and the concentration of radioactive iodine released from the reactor vessel into the reactor container in the spray device of BWR type reactors. Constitution: A plurality of water receiving trays are disposed below the spray nozzle in the dry well and communicated to a pressure suppression chamber by way of drain pipeways passing through a diaphragm floor. When the recycling system is ruptured and coolants in the reactor vessel and radioactive iodine in the reactor core are released into the dry well, spray water is discharged from the spray nozzle to eliminate the heat and the radioactive iodine in the dry well. In this case, the receiving trays collect the portions of spray water whose absorption power for the heat and radioactive iodine is nearly saturated and falls them into the pool water of the pressure suppression chamber. Consequently, other portions of the spray water that still possess absorption power can be jetted with no hindrance, to increase the efficiency for the removal of the heat and iodine of the spray droplets. (Horiuchi, T.)

Systematic Investigation on the Influence of Spray Parameters on the Mechanical Properties of Atmospheric Plasma-Sprayed YSZ Coatings

Science.gov (United States)

Mutter, Markus; Mauer, Georg; Mücke, Robert; Guillon, Olivier; Vaßen, Robert

2018-04-01

In the atmospheric plasma spray (APS) process, micro-sized ceramic powder is injected into a thermal plasma where it is rapidly heated and propelled toward the substrate. The coating formation is characterized by the subsequent impingement of a large number of more or less molten particles forming the so-called splats and eventually the coating. In this study, a systematic investigation on the influence of selected spray parameters on the coating microstructure and the coating properties was conducted. The investigation thereby comprised the coating porosity, the elastic modulus, and the residual stress evolution within the coating. The melting status of the particles at the impingement on the substrate in combination with the substrate surface condition is crucial for the coating formation. Single splats were collected on mirror-polished substrates for selected spray conditions and evaluated by identifying different types of splats (ideal, distorted, weakly bonded, and partially molten) and their relative fractions. In a previous study, these splat types were evaluated in terms of their effect on the above-mentioned coating properties. The particle melting status, which serves as a measure for the particle spreading behavior, was determined by in-flight particle temperature measurements and correlated to the coating properties. It was found that the gun power and the spray distance have a strong effect on the investigated coating properties, whereas the feed rate and the cooling show minor influence.

Slurry spray distribution within a simulated laboratory scale spray dryer

International Nuclear Information System (INIS)

Bertone, P.C.

1979-01-01

It was found that the distribution of liquid striking the sides of a simulated room temperature spray dryer was not significantly altered by the choice of nozles, nor by a variation in nozzle operating conditions. Instead, it was found to be a function of the spray dryer's configuration. A cocurrent flow of air down the drying cylinder, not possible with PNL's closed top, favorably altered the spray distribution by both decreasing the amount of liquid striking the interior of the cylinder from 72 to 26% of the feed supplied, and by shifting the zone of maximum impact from 1.0 to 1.7 feet from the nozzle. These findings led to the redesign of the laboratory scale spray dryer to be tested at the Savannah River Plant. The diameter of the drying chamber was increased from 5 to 8 inches, and a cocurrent flow of air was established with a closed recycle. Finally, this investigation suggested a drying scheme which offers all the advantages of spray drying without many of its limitations

Plasma Sprayed Hydroxyapatite Coatings: Influence of Spraying Power on Microstructure

International Nuclear Information System (INIS)

Mohd, S. M.; Abd, M. Z.; Abd, A. N.

2010-01-01

The plasma sprayed hydroxyapatite (HA) coatings are used on metallic implants to enhance the bonding between the implant and bone in human body. The coating process was implemented at different spraying power for each spraying condition. The coatings formed from a rapid solidification of molten and partly molten particles that impact on the surface of substrate at high velocity and high temperature. The study was concentrated on different spraying power that is between 23 to 31 kW. The effect of different power on the coatings microstructure was investigated using scanning electron microscope (SEM) and phase composition was evaluated using X-ray diffraction (XRD) analysis. The coatings surface morphology showed distribution of molten, partially melted particles and some micro-cracks. The produced coatings were found to be porous as observed from the cross-sectional morphology. The coatings XRD results indicated the presence of crystalline phase of HA and each of the patterns was similar to the initial powder. Regardless of different spraying power, all the coatings were having similar XRD patterns.

Resistance and Spray Characteristics of a 1/13-Scale Model of the Consolidated Vultee Skate 7 Seaplane, TED No. NACA DE 338

Science.gov (United States)

McKann, Robert E.; Coffee, Claude W.; Arabian, Donald D.

1949-01-01

A model of a Consolidated Vultee Aircraft Corporation Skate 7 sea-plane:was tested in Langley tank no= 2. Resistance data, 'spray photographs, and underwater photographs,are given in this report without discussion.

Drop formation of black liquor spraying; Mustalipeaen pisaroituminen

Energy Technology Data Exchange (ETDEWEB)

Fogelholm, C J; Kankkunen, A; Nieminen, K; Laine, J; Miikkulainen, P [Helsinki Univ. of Technology, Otaniemi (Finland): Lab. of Energy Technology and Environmental Protection

1997-10-01

Black liquor is a spent liquor of the pulp and paper industry. It is burned in kraft recovery boilers for chemical and energy recovery. The high dry solids content and viscosity of black liquor require a high spraying temperature. This affects the performance of the boiler. Kraft recovery boiler deposit formation, emissions and chemical recovery are strongly affected by the drop size and the velocity of the black liquor spray formed by a splashplate nozzle. The sheet breakup mechanism is studied with a system based on a video and image-analysis. The drop size of mill-scale nozzles was measured also with an image-analysis-system. Measurements were carried out in a spray test chamber. The sheet breakup mechanism and drop size tests were carried out both below and over the boiling point of black liquor. Special attention was paid to the effect of flashing on drop formation. Temperature increase normally decreases drop size. In the temperature where the wavy-sheet disintegration changes to perforated-sheet disintegration the drop size increases. Spray velocity rises when the temperature is increased above the boiling point. (orig.)

Effects of Compound K-Distributed Sea Clutter on Angle Measurement of Wideband Monopulse Radar

Directory of Open Access Journals (Sweden)

Hong Zhu

2017-01-01

Full Text Available The effects of compound K-distributed sea clutter on angle measurement of wideband monopulse radar are investigated in this paper. We apply the conditional probability density function (pdf of monopulse ratio (MR error to analyze these effects. Based on the angle measurement procedure of the wideband monopulse radar, this conditional pdf is first deduced in detail for the case of compound K-distributed sea clutter plus noise. Herein, the spatial correlation of the texture components for each channel clutter and the correlation of the texture components between the sum and difference channel clutters are considered, and two extreme situations for each of them are tackled. Referring to the measured sea clutter data, angle measurement performances in various K-distributed sea clutter plus noise circumstances are simulated, and the effects of compound K-distributed sea clutter on angle measurement are discussed.

Evaluation of Steadiness and Drop Size Distribution in Sprays Generated by Different Twin-Fluid Atomizers

Directory of Open Access Journals (Sweden)

Zaremba Matouš

2015-01-01

Full Text Available Twin-fluid atomizers underwent a significant development during the last few decades. They are common in many industrial applications such as fuel spraying, melt atomization and food processing. This paper is focused on the evaluation of four different twin-fluid atomizers. The aim is to compare the quality of sprays generated by various atomizers with similar dimensions and in the same operating regimes. A phase- Doppler anemometry (PDA and particle image velocimetry (PIV were used to measure spray characteristics such as velocity and size of the droplets. Measured data were used to compare droplet size distribution and to evaluate steadiness of the spray. Visualisations were made to support measured data and to clarify the principles of primary atomization and its influence on the spray.

Evaluation of Steadiness and Drop Size Distribution in Sprays Generated by Different Twin-Fluid Atomizers

Science.gov (United States)

Zaremba, Matouš; Mlkvik, Marek; Malý, Milan; Jedelský, Jan; Jícha, Miroslav

2015-05-01

Twin-fluid atomizers underwent a significant development during the last few decades. They are common in many industrial applications such as fuel spraying, melt atomization and food processing. This paper is focused on the evaluation of four different twin-fluid atomizers. The aim is to compare the quality of sprays generated by various atomizers with similar dimensions and in the same operating regimes. A phase- Doppler anemometry (PDA) and particle image velocimetry (PIV) were used to measure spray characteristics such as velocity and size of the droplets. Measured data were used to compare droplet size distribution and to evaluate steadiness of the spray. Visualisations were made to support measured data and to clarify the principles of primary atomization and its influence on the spray.

Laboratory modeling of air-sea interaction under severe wind conditions

Science.gov (United States)

Troitskaya, Yuliya; Vasiliy, Kazakov; Nicolay, Bogatov; Olga, Ermakova; Mikhail, Salin; Daniil, Sergeev; Maxim, Vdovin

2010-05-01

Wind-wave interaction at extreme wind speed is of special interest now in connection with the problem of explanation of the sea surface drag saturation at the wind speed exceeding 30 m/s. The idea on saturation (and even reduction) of the coefficient of aerodynamic resistance of the sea surface at hurricane wind speed was first suggested by Emanuel (1995) on the basis of theoretical analysis of sensitivity of maximum wind speed in a hurricane to the ratio of the enthalpy and momentum exchange coefficients. Both field (Powell, Vickery, Reinhold, 2003, French et al, 2007, Black, et al, 2007) and laboratory (Donelan et al, 2004) experiments confirmed that at hurricane wind speed the sea surface drag coefficient is significantly reduced in comparison with the parameterization obtained at moderate to strong wind conditions. Two groups of possible theoretical mechanisms for explanation of the effect of the sea surface drag reduction can be specified. In the first group of models developed by Kudryavtsev & Makin (2007) and Kukulka,Hara Belcher (2007), the sea surface drag reduction is explained by peculiarities of the air flow over breaking waves. Another approach more appropriate for the conditions of developed sea exploits the effect of sea drops and sprays on the wind-wave momentum exchange (Andreas, 2004; Makin, 2005; Kudryavtsev, 2006). The main objective of this work is investigation of factors determining momentum exchange under high wind speeds basing on the laboratory experiment in a well controlled environment. The experiments were carried out in the Thermo-Stratified WInd-WAve Tank (TSWIWAT) of the Institute of Applied Physics. The parameters of the facility are as follows: airflow 0 - 25 m/s (equivalent 10-m neutral wind speed U10 up to 60 m/s), dimensions 10m x 0.4m x 0.7 m, temperature stratification of the water layer. Simultaneous measurements of the airflow velocity profiles and wind waves were carried out in the wide range of wind velocities. Airflow

CONCHAS-SPRAY, Reactive Flows with Fuel Sprays

International Nuclear Information System (INIS)

Cloutman, L.D.; Dukowicz, J.K.; Ramshaw, J.D.; Amsden, A.A.

2001-01-01

Description of program or function: CONCHAS-SPRAY solves the equations of transient, multicomponent, chemically reactive fluid dynamics, together with those for the dynamics of an evaporating liquid spray. The program was developed with applications to internal combustion engines in mind. The formulation is spatially two-dimensional, and encompasses both planar and axisymmetric geometries. In the latter case, the flow is permitted to swirl about the axis of symmetry. CONCHAS-SPRAY is a time-marching, finite- difference program that uses a partially implicit numerical scheme. Spatial differences are formed with respect to a generalized two- dimensional mesh of arbitrary quadrilaterals whose corner locations are specified functions of time. This feature allows a Lagrangian, Eulerian, or mixed description, and is particularly useful for representing curved or moving boundary surfaces. Arbitrary numbers of species and chemical reactions are allowed. The latter are subdivided into kinetic and equilibrium reactions, which are treated by different algorithms. A turbulent law-of-the-wall boundary layer option is provided. CONCHAS-SPRAY calls a number of LANL system subroutines to display graphic or numerical information on microfiche. These routines are not included, but are described in the reference report. Several routines called from LINPACK and SLATEC1.0 are included

Spray structure of a pressure-swirl atomizer for combustion applications

Directory of Open Access Journals (Sweden)

Jicha Miroslav

2012-04-01

Full Text Available In the present work, global as well as spatially resolved parameters of a spray produced by a pressure-swirl atomizer are obtained. Small pressure-swirl atomizer for aircraft combustion chambers was run on a newly designed test bench with Jet A-1 kerosene type aviation fuel. The atomizer was tested in four regimes based on typical operation conditions of the engine. Spray characteristics were studied using two optical measurement systems, Particle Image velocimetry (PIV and Phase-Doppler Particle Analyzer (P/DPA. The results obtained with P/DPA include information about Sauter Mean Diameter of droplets and spray velocity profiles in one plane perpendicular to the spray axis. Velocity magnitudes of droplets in an axial section of the spray were obtained using PIV. The experimental outputs also show a good confirmation of velocity profiles obtained with both instruments in the test plane. These data together will elucidate impact of the spray quality on the whole combustion process, its efficiency and exhaust gas emissions.

Spray structure of a pressure-swirl atomizer for combustion applications

Science.gov (United States)

Durdina, Lukas; Jedelsky, Jan; Jicha, Miroslav

2012-04-01

In the present work, global as well as spatially resolved parameters of a spray produced by a pressure-swirl atomizer are obtained. Small pressure-swirl atomizer for aircraft combustion chambers was run on a newly designed test bench with Jet A-1 kerosene type aviation fuel. The atomizer was tested in four regimes based on typical operation conditions of the engine. Spray characteristics were studied using two optical measurement systems, Particle Image velocimetry (PIV) and Phase-Doppler Particle Analyzer (P/DPA). The results obtained with P/DPA include information about Sauter Mean Diameter of droplets and spray velocity profiles in one plane perpendicular to the spray axis. Velocity magnitudes of droplets in an axial section of the spray were obtained using PIV. The experimental outputs also show a good confirmation of velocity profiles obtained with both instruments in the test plane. These data together will elucidate impact of the spray quality on the whole combustion process, its efficiency and exhaust gas emissions.

Numerical modelling of fuel sprays

Energy Technology Data Exchange (ETDEWEB)

Bergstroem, C.

1999-06-01

The way the fuel is introduced into the combustion chamber is one of the most important parameters for the power output and the generation of emissions in the combustion of liquid fuels. The interaction between the turbulent gas flow field and the liquid fuel droplets, the vaporisation of them and the mixing of the gaseous fuel with the ambient air that are vital parameters in the combustion process. The use of numerical calculations is an important tool to better understand these complex interacting phenomena. This thesis reports on the numerical modelling of fuel sprays in non-reacting cases using an own developed spray module. The spray module uses the stochastic parcel method to represent the spray. The module was made in such manner that it could by coupled with different gas flow solver. Results obtained from four different gas flow solvers are presented in the thesis, including the use of two different kinds of turbulence models. In the first part the spray module is coupled with a k-{eta} based 2-D cylindrical gas flow solver. A thorough sensitivity analysis was performed on the spray and gas flow solver parameters, such as grid size dependence and sensitivity to initial values of k-{eta}. The results of the spray module were also compared to results from other spray codes, e.g. the well known KIVA code. In the second part of this thesis the spray was injected into a turbulent and fully developed crossflow studied. The spray module was attached to a LES (Large Eddy Simulation) based flow solvers enabling the study of the complex structures and time dependent phenomena involved in spray in crossflows. It was found that the spray performs an oscillatory motion and that the Strouhal number in the wake was about 0.1. Different spray breakup models were evaluated by comparing with experimental results 66 refs, 56 figs

The erosive potential of candy sprays

NARCIS (Netherlands)

Gambon, D.L.; Brand, H.S.; Nieuw Amerongen, A.V.

2009-01-01

Objective To determine the erosive potential of seven different commercially available candy sprays in vitro and in vivo. Material and methods The erosive potential was determined in vitro by measuring the pH and neutralisable acidity. The salivary pH and flow rate were measured in healthy

Thermal Arc Spray Overview

Science.gov (United States)

Hafiz Abd Malek, Muhamad; Hayati Saad, Nor; Kiyai Abas, Sunhaji; Mohd Shah, Noriyati

2013-06-01

Usage of protective coating for corrosion protection was on highly demand during the past decade; and thermal spray coating played a major part during that time. In recent years, the thermal arc spray coating becomes a popular coating. Many big players in oil and gas such as PETRONAS, EXXON MOBIL and SHELL in Malaysia tend to use the coating on steel structure as a corrosion protection. Further developments in coating processes, the devices, and raw materials have led to expansion of functional coatings and applications scope from conventional coating to specialized industries. It is widely used because of its ability to withstand high process temperature, offer advantages in efficiency, lower cost and acts as a corrosion protection. Previous research also indicated that the thermal arc spray offers better coating properties compared to other methods of spray. This paper reviews some critical area of thermal spray coating by discussing the process/parameter of thermal arc spray technology and quality control of coating. Coating performance against corrosion, wear and special characteristic of coating are also described. The field application of arc spray technology are demonstrated and reviewed.

Thermal Arc Spray Overview

International Nuclear Information System (INIS)

Malek, Muhamad Hafiz Abd; Saad, Nor Hayati; Abas, Sunhaji Kiyai; Shah, Noriyati Mohd

2013-01-01

Usage of protective coating for corrosion protection was on highly demand during the past decade; and thermal spray coating played a major part during that time. In recent years, the thermal arc spray coating becomes a popular coating. Many big players in oil and gas such as PETRONAS, EXXON MOBIL and SHELL in Malaysia tend to use the coating on steel structure as a corrosion protection. Further developments in coating processes, the devices, and raw materials have led to expansion of functional coatings and applications scope from conventional coating to specialized industries. It is widely used because of its ability to withstand high process temperature, offer advantages in efficiency, lower cost and acts as a corrosion protection. Previous research also indicated that the thermal arc spray offers better coating properties compared to other methods of spray. This paper reviews some critical area of thermal spray coating by discussing the process/parameter of thermal arc spray technology and quality control of coating. Coating performance against corrosion, wear and special characteristic of coating are also described. The field application of arc spray technology are demonstrated and reviewed.

Hair spray poisoning

Science.gov (United States)

... this page: //medlineplus.gov/ency/article/002705.htm Hair spray poisoning To use the sharing features on this page, please enable JavaScript. Hair spray poisoning occurs when someone breathes in (inhales) ...

Effect of ambient gas density for diesel spray; Diesel funmu ni taisuru fun`iki mitsudo no eikyo

Energy Technology Data Exchange (ETDEWEB)

Yokohashi, M; Suzuki, T; Oshima, R [Tohokugakuin University, Sendai (Japan); Ono, A [Shinryo Corp., Tokyo (Japan)

1997-10-01

Effect of ambient gas density for fuel spray are measured to investigate the Diesel spray behavior. The change of ambient gas density has been given by pressuring N2 gas and using a high density atmospheric pressure SF6 gas. The measurement are performed for the spray penetration and angle. As a result, the spray penetration is confirmed same tendency at the change of density by pressuring N2 and using SF6. Though spray angle is required modification with viscosity. 2 refs., 11 figs.

Spray rolling aluminum alloy strip

Energy Technology Data Exchange (ETDEWEB)

McHugh, Kevin M.; Delplanque, J.-P.; Johnson, S.B.; Lavernia, E.J.; Zhou, Y.; Lin, Y

2004-10-10

Spray rolling combines spray forming with twin-roll casting to process metal flat products. It consists of atomizing molten metal with a high velocity inert gas, cooling the resultant droplets in flight and directing the spray between mill rolls. In-flight convection heat transfer from atomized droplets teams with conductive cooling at the rolls to rapidly remove the alloy's latent heat. Hot deformation of the semi-solid material in the rolls results in fully consolidated, rapidly solidified product. While similar in some ways to twin-roll casting, spray rolling has the advantage of being able to process alloys with broad freezing ranges at high production rates. This paper describes the process and summarizes microstructure and tensile properties of spray-rolled 2124 and 7050 aluminum alloy strips. A Lagrangian/Eulerian poly-dispersed spray flight and deposition model is described that provides some insight into the development of the spray rolling process. This spray model follows droplets during flight toward the rolls, through impact and spreading, and includes oxide film formation and breakup when relevant.

Hydrogen permeation properties of plasma-sprayed tungsten

International Nuclear Information System (INIS)

Anderl, R.A.; Pawelko, R.J.; Hankins, M.R.; Longhurst, G.R.; Neiser, R.A.

1994-01-01

Tungsten has been proposed as a plasma-facing component material for advanced fusion facilities. This paper reports on laboratory-scale studies that were done to assess the hydrogen permeation properties of plasma-sprayed tungsten for such applications. The work entailed deuterium permeation measurements for plasma-sprayed (PS) tungsten coatings, sputter-deposited (SP) tungsten coatings, and steel substrate material using a mass-analyzed, 3 keV D + 3 ion beam with fluxes of similar 6.5x10 19 D/m 2 s. Extensive characterization analyses for the plasma-sprayed tungsten coatings were made using Auger spectrometry and scanning electron microscopy (SEM). Observed permeation rates through composite PS-tungsten/steel specimens were several orders of magnitude below the permeation levels observed for SP-tungsten/steel composite specimens and pure steel specimens. Characterization analyses indicated that the plasma-sprayed tungsten coating had a nonhomogeneous microstructure that consisted of splats with columnar solidification, partially-melted particles with grain boundaries, and void regions. Reduced permeation levels can be attributed to the complex microstructure and a substantial surface-connected porosity. ((orig.))

Hydrogen permeation properties of plasma-sprayed tungsten

Energy Technology Data Exchange (ETDEWEB)

Anderl, R.A. (Idaho National Engineering Lab., EG and G Idaho Inc., Idaho Falls, ID (United States)); Pawelko, R.J. (Idaho National Engineering Lab., EG and G Idaho Inc., Idaho Falls, ID (United States)); Hankins, M.R. (Idaho National Engineering Lab., EG and G Idaho Inc., Idaho Falls, ID (United States)); Longhurst, G.R. (Idaho National Engineering Lab., EG and G Idaho Inc., Idaho Falls, ID (United States)); Neiser, R.A. (Sandia National Laboratories, Albuquerque, NM 87185 (United States))

1994-09-01

Tungsten has been proposed as a plasma-facing component material for advanced fusion facilities. This paper reports on laboratory-scale studies that were done to assess the hydrogen permeation properties of plasma-sprayed tungsten for such applications. The work entailed deuterium permeation measurements for plasma-sprayed (PS) tungsten coatings, sputter-deposited (SP) tungsten coatings, and steel substrate material using a mass-analyzed, 3 keV D[sup +][sub 3] ion beam with fluxes of similar 6.5x10[sup 19] D/m[sup 2] s. Extensive characterization analyses for the plasma-sprayed tungsten coatings were made using Auger spectrometry and scanning electron microscopy (SEM). Observed permeation rates through composite PS-tungsten/steel specimens were several orders of magnitude below the permeation levels observed for SP-tungsten/steel composite specimens and pure steel specimens. Characterization analyses indicated that the plasma-sprayed tungsten coating had a nonhomogeneous microstructure that consisted of splats with columnar solidification, partially-melted particles with grain boundaries, and void regions. Reduced permeation levels can be attributed to the complex microstructure and a substantial surface-connected porosity. ((orig.))

Remotely controlled spray gun

Science.gov (United States)

Cunningham, William C. (Inventor)

1987-01-01

A remotely controlled spray gun is described in which a nozzle and orifice plate are held in precise axial alignment by an alignment member, which in turn is held in alignment with the general outlet of the spray gun by insert. By this arrangement, the precise repeatability of spray patterns is insured.

Effects of spray parameters on the microstructure and property of Al2O3 coatings sprayed by a low power plasma torch with a novel hollow cathode

International Nuclear Information System (INIS)

Li Changjiu; Sun Bo

2004-01-01

Al 2 O 3 coating is deposited using a low power plasma torch with a novel hollow cathode through axial powder injection under a plasma power up to several kilowatts. The effects of the main processing parameters including plasma arc power, operating gas flow and spray distance on particle velocity during spraying, and the microstructure and property of the coating are investigated. The microstructure of the Al 2 O 3 coating is examined using optical microscopy and X-ray diffraction analysis. The property of the coating is characterized by dry rubber wheel abrasive wear test. The velocity of in-flight particle is measured using a velocity/temperature measurement system for spray particle based on thermal radiation from the particle. The dependency of the microstructure and property of the coating on spray particle conditions are examined by comparing the particle velocity, and microstructure and abrasive wear weight loss of subsequent coating deposited by low power plasma spray with those of the coating by conventional plasma spray at a power one order higher. X-ray diffraction analysis of the coating revealed that Al 2 O 3 particles during low power plasma spraying reach to sufficiently melting state prior to impact on the substrate with a velocity comparable to that in conventional plasma spraying. The experiment results have shown that processing parameters have significant influence on the particle conditions and performance of deposited Al 2 O 3 coating. The coating of comparable microstructure and properties to that deposited by conventional plasma spray can be produced under a power one order lower. From the present study, it can be suggested that a comparable coating can be produced despite plasma power level if the comparable particle velocity and molten state are achieved

Comparision on dynamic behavior of diesel spray and rapeseed oil spray in diesel engine

Science.gov (United States)

Sapit, Azwan; Azahari Razali, Mohd; Faisal Hushim, Mohd; Jaat, Norrizam; Nizam Mohammad, Akmal; Khalid, Amir

2017-04-01

Fuel-air mixing is important process in diesel combustion. It significantly affects the combustion and emission of diesel engine. Biomass fuel has high viscosity and high distillation temperature and may negatively affect the fuel-air mixing process. Thus, study on the spray development and atomization of this type of fuel is important. This study investigates the atomization characteristics and droplet dynamic behaviors of diesel engine spray fuelled by rapeseed oil (RO) and comparison to diesel fuel (GO). Optical observation of RO spray was carried out using shadowgraph photography technique. Single nano-spark photography technique was used to study the characteristics of the spray while dual nano-spark shadowgraph technique was used to study the spray droplet behavior. Using in-house image processing algorithm, the images were processed and the boundary condition of each spray was also studied. The results show that RO has very poor atomization due to the high viscosity nature of the fuel when compared to GO. This is in agreement with the results from spray droplet dynamic behavior studies that shows due to the high viscosity, the RO spray droplets are large in size and travel downward, with very little influence of entrainment effect due to its large kinematic energy.

A theoretical model of the influence of spray on the exchange of momentum, with storm and hurricane winds

Science.gov (United States)

Troitskaya, Yuliya; Ezhova, Ekaterina; Soustova, Irina

2013-04-01

A stochastic model of the "life cycle" of a droplet, the torn off the crest of a steep surface wave and then falling down to the water is constructed. The model includes the following constituents: i) a model of motion of a heavy particle in the forcing air flow (equation of motion), ii) a model of the wind flow (wind velocity, wave-induced disturbances, turbulent fluctuations), iii) a model of spray injection, iiii) the droplet statistics (size distribution, wind-speed dependence) The interaction of water droplets in the atmospheric boundary layer with turbulent fluctuations is described in terms of the Markovian chain. The mean wind field in the marine atmospheric boundary layer is determined by the momentum exchange associated with the turbulent and wave momentum transfer and by sprays. The wave and turbulent momentum exchange is parameterized by the Charnok expression for the roughness parameter. Wave disturbances induced in the air flow by waves at the surface, were calculated within the model of the marine atmospheric boundary suggested in [1]. The greatest uncertainty in this model is the mechanism of droplets injection. We consider two models for the injection of droplets in the air flow. In the first model the droplets formed by the development of the Kelvin-Helmholtz instability, are entered in the flow with the orbital velocity of the wave (Koga's model [2]), The second mechanism, investigated in many papers, considers droplets from the breakdown of a jet which rises at high speeds from the bottom of the collapsing air bubble cavity [3]. To determine the number of drops injected to the atmospheric boundary layer from the sea surface, the Spray generation function proposed in [4] was in use. Within the model the momentum acquired by every droplet in the interaction with the air flow was calculated. Depending on the particular field of air velocity, wave parameters and the radius of the droplet, it can both get and deliver momentum give impetus to the air

Experimental investigation of spray characteristics of alternative aviation fuels

International Nuclear Information System (INIS)

Kannaiyan, Kumaran; Sadr, Reza

2014-01-01

Highlights: • Physical properties of GTL fuel are different from those of conventional jet fuels. • Spray characteristics of GTL and Jet A-1 fuels are experimentally investigated using phase Doppler anemometry. • Regions near the nozzle are influenced by differences in fuel physical properties. • Spray characteristics of GTL can be predicted by empirical relations developed for conventional jet fuels. - Abstract: Synthetic fuels derived from non-oil feedstock are gaining importance due to their cleaner combustion characteristics. This work investigates spray characteristics of two Gas-to-Liquid (GTL) synthetic jet fuels from a pilot-scale pressure swirl nozzle and compares them with those of the conventional Jet A-1 fuel. The microscopic spray parameters are measured at 0.3 and 0.9 MPa injection pressures at several points in the spray using phase Doppler anemometry. The results show that the effect of fuel physical properties on the spray characteristics is predominantly evident in the regions close to the nozzle exit at the higher injection pressure. The lower viscosity and surface tension of GTL fuel seems to lead to faster disintegration and dispersion of the droplets when compared to those of Jet A-1 fuel under atmospheric conditions. Although the global characteristics of the fuels are similar, the effects of fuel properties are evident on the local spray characteristics at the higher injection pressure

Marine Emissions and Atmospheric Processing Influence Aerosol Mixing States in the Bering Strait and Chukchi Sea

Science.gov (United States)

Kirpes, R.; Rodriguez, B.; Kim, S.; Park, K.; China, S.; Laskin, A.; Pratt, K.

2017-12-01

The Arctic region is rapidly changing due to sea ice loss and increasing oil/gas development and shipping activity. These changes influence aerosol sources and composition, resulting in complex aerosol-cloud-climate feedbacks. Atmospheric particles were collected aboard the R/V Araon in July-August 2016 in the Alaskan Arctic along the Bering Strait and Chukchi Sea. Offline analysis of individual particles by microscopic and spectroscopic techniques provided information on particle size, morphology, and chemical composition. Sea spray aerosol (SSA) and organic aerosol (OA) particles were the most commonly observed particle types, and sulfate was internally mixed with both SSA and OA. Evidence of multiphase sea spray aerosol reactions was observed, with varying degrees of chlorine depletion observed along the cruise. Notably, atmospherically processed SSA, completely depleted in chlorine, and internally mixed organic and sulfate particles, were observed in samples influenced by the central Arctic Ocean. Changes in particle composition due to fog processing were also investigated. Due to the changing aerosol sources and atmospheric processes in the Arctic region, it is crucial to understand aerosol composition in order to predict climate impacts.

Thermal spray for commercial shipbuilding

Science.gov (United States)

Rogers, F. S.

1997-09-01

Thermal spraying of steel with aluminum to protect it from corrosion is a technology that has been proven to work in the marine environment. The thermal spray coating system includes a paint sealer that is applied over the thermally sprayed aluminum. This extends the service life of the coating and provides color to the end product. The thermal spray system protects steel both through the principle of isolation (as in painting) and galvanizing. With this dual protection mechanism, steel is protected from corrosion even when the coating is damaged. The thermal- sprayed aluminum coating system has proved the most cost- effective corrosion protection system for the marine environment. Until recently, however, the initial cost of application has limited its use for general application. Arc spray technology has reduced the application cost of thermal spraying of aluminum to below that of painting. Commercial shipbuilders could use this technology to enhance their market position in the marine industry.

Inside versus Outside: Ion Redistribution in Nitric Acid Reacted Sea Spray Aerosol Particles as Determined by Single Particle Analysis (Invited)

Science.gov (United States)

Ault, A. P.; Guasco, T.; Ryder, O. S.; Baltrusaitis, J.; Cuadra-Rodriguez, L. A.; Collins, D. B.; Ruppel, M. J.; Bertram, T. H.; Prather, K. A.; Grassian, V. H.

2013-12-01

Sea spray aerosol (SSA) particles were generated under real-world conditions using natural seawater and a unique ocean-atmosphere facility equipped with actual breaking waves or a marine aerosol reference tank (MART) that replicates those conditions. The SSA particles were exposed to nitric acid in situ in a flow tube and the well-known chloride displacement and nitrate formation reaction was observed. However, as discussed here, little is known about how this anion displacement reaction affects the distribution of cations and other chemical constituents within and phase state of individual SSA particles. Single particle analysis of individual SSA particles shows that cations (Na+, K+, Mg2+ and Ca2+) within individual particles undergo a spatial redistribution after heterogeneous reaction with nitric acid, along with a more concentrated layer of organic matter at the surface of the particle. These data suggest that specific ion and aerosol pH effects play an important role in aerosol particle structure in ways that have not been previously recognized. The ordering of organic coatings can impact trace gas uptake, and subsequently impact trace gas budgets of O3 and NOx.

Influence of the spray characteristics of a piezo-A-nozzle on the inflammation at spray guided combustion processes; Einfluss der Spraycharakteristik einer Piezo-A-Duese auf die Entflammung beim strahlgefuehrten Brennverfahren

Energy Technology Data Exchange (ETDEWEB)

Breuninger, Tobias; Schmidt, Juergen [Magdeburg Univ. (DE). Inst. fuer Stroemungstechnik und Thermodynamik (ISUT); Hese, Martin; Tschoeke, Helmut [Magdeburg Univ. (DE). Inst. fuer Mobile Systeme (IMS); Kufferath, Andreas [Robert Bosch GmbH, Schwieberdingen (Germany); Altenschmidt, Frank [Daimler AG, Stuttgart (Germany)

2011-07-01

The spray-guided combustion process offers a significant potential for improvement on the fuel consumption in partial-load engine operation. Due to the very close positioning of the injector to the spark plug, there is only very little time for the fuel mixture generation which leads to the presence of still liquid fuel particles next to already evaporized one. Furthermore the fuel-mixture generation is primarily driven by the dynamics of the fuel spray. In this article the spray characteristics of a Piezo-A-injector under pressure-chamber conditions as well as the combustion behavior on a one-cylinder test motor are analyzed. The global spray dispersion is analyzed using high-speed visualization while laser-optical measurements are used to observe the ignition-area. The mean diameter as well as the velocity of fuel droplets are determined using the phase-doppler-anemometry (PDA). An extinction-measuring methodology is used to quantify the liquid fuel particles. Analyzing the evaluated misfire-rate as a function of the spray-attributes allows for rating the spray-sections according to their ignition behavior. (orig.)

Silver nasal sprays: misleading Internet marketing.

Science.gov (United States)

Gaslin, Michael T; Rubin, Cory; Pribitkin, Edmund A

2008-04-01

Long-term use of silver-containing products is associated with a permanent bluish-gray discoloration of the skin known as argyria, but they remain widely available despite several measures by the FDA to regulate them. Several recent case reports have described the occurrence of argyria as a result of using these "natural" products. We used the five most common Internet search engines to find Web sites providing information on silver-containing nasal sprays. Of 49 Web sites analyzed, only 2 (4%) mentioned argyria as a possible complication, although 30 (61%) did caution against long-term use. Eight sites (16%) made specific claims about the health benefits of the product. All 49 sites (100%) provided direct or indirect links to buy silver-containing nasal sprays. We conclude that information about silver-containing nasal sprays on the Internet is misleading and inaccurate. Therefore, otolaryngologists should be aware of the misinformation their patients may be receiving about these products.

Evaluation of droplet velocity and size from nasal spray devices using phase Doppler anemometry (PDA).

Science.gov (United States)

Liu, Xiaofei; Doub, William H; Guo, Changning

2010-03-30

To determine aerosol deposition during the inhalation drug delivery, it is important to understand the combination of velocity and droplet size together. In this study, phase Doppler anemometry (PDA) was used to simultaneously characterize the aerosol velocity and droplet size distribution (DSD) of three nasal spray pumps filled with water. Thirteen sampling positions were located in the horizontal cross-sectional area of the nasal spray plumes at a distance of 3cm from the pump orifice. The results showed droplet velocities near the center of the spray plume were higher and more consistent than those near the edge. The pumps examined showed significant differences in their aerosol velocity at the center of the spray plume, which suggest that this metric might be used as a discriminating parameter for in vitro testing of nasal sprays. Droplet size measurements performed using PDA were compared with results from laser light scattering measurements. The ability of PDA to provide simultaneous measurements of aerosol velocity and size makes it a powerful tool for the detailed investigation of nasal spray plume characteristics. Published by Elsevier B.V.

Microwave emission measurements of sea surface roughness, soil moisture, and sea ice structure

Science.gov (United States)

Gloersen, P.; Wilheit, T. T.; Schmugge, T. J.

1972-01-01

In order to demonstrate the feasibility of the microwave radiometers to be carried aboard the Nimbus 5 and 6 satellites and proposed for one of the earth observatory satellites, remote measurements of microwave radiation at wavelengths ranging from 0.8 to 21 cm have been made of a variety of the earth's surfaces from the NASA CV-990 A/C. Brightness temperatures of sea water surfaces of varying roughness, of terrain with varying soil moisture, and of sea ice of varying structure were observed. In each case, around truth information was available for correlation with the microwave brightness temperature. The utility of passive microwave radiometry in determining ocean surface wind speeds, at least for values higher than 7 meters/second has been demonstrated. In addition, it was shown that radiometric signatures can be used to determine soil moisture in unvegetated terrain to within five percentage points by weight. Finally, it was demonstrated that first year thick, multi-year, and first year thin sea ice can be distinguished by observing their differing microwave emissivities at various wavelengths.

A user-friendly model for spray drying to aid pharmaceutical product development.

Science.gov (United States)

Grasmeijer, Niels; de Waard, Hans; Hinrichs, Wouter L J; Frijlink, Henderik W

2013-01-01

The aim of this study was to develop a user-friendly model for spray drying that can aid in the development of a pharmaceutical product, by shifting from a trial-and-error towards a quality-by-design approach. To achieve this, a spray dryer model was developed in commercial and open source spreadsheet software. The output of the model was first fitted to the experimental output of a Büchi B-290 spray dryer and subsequently validated. The predicted outlet temperatures of the spray dryer model matched the experimental values very well over the entire range of spray dryer settings that were tested. Finally, the model was applied to produce glassy sugars by spray drying, an often used excipient in formulations of biopharmaceuticals. For the production of glassy sugars, the model was extended to predict the relative humidity at the outlet, which is not measured in the spray dryer by default. This extended model was then successfully used to predict whether specific settings were suitable for producing glassy trehalose and inulin by spray drying. In conclusion, a spray dryer model was developed that is able to predict the output parameters of the spray drying process. The model can aid the development of spray dried pharmaceutical products by shifting from a trial-and-error towards a quality-by-design approach.

Demonstration of measuring sea fog with an SNSPD-based Lidar system.

Science.gov (United States)

Zhu, Jiang; Chen, Yajun; Zhang, Labao; Jia, Xiaoqing; Feng, Zhijun; Wu, Ganhua; Yan, Xiachao; Zhai, Jiquan; Wu, Yang; Chen, Qi; Zhou, Xiaoying; Wang, Zhizhong; Zhang, Chi; Kang, Lin; Chen, Jian; Wu, Peiheng

2017-11-08

The monitor of sea fogs become more important with the rapid development of marine activities. Remote sensing through laser is an effective tool for monitoring sea fogs, but still challengeable for large distance. We demonstrated a Long-distance Lidar for sea fog with superconducting nanowire single-photon detector (SNSPD), which extended the ranging area to a 180-km diameter area. The system, which was verified by using a benchmark distance measurement of a known island, is applied to the Mie scattering weather prediction Lidar system. The fog echo signal distribution in the range of 42.3∼63.5 km and 53.2∼74.2 km was obtained by the Lidar system. Then the fog concentration and the velocity of the fog were deduced from the distribution, which is consistent with the weather prediction. The height of the sea fog is about two hundred meter while the visibility at this height is about 90 km due to the Earth's radius of curvature. Therefore, the capability of this SNSPD-based Lidar was close to the theoretical limit for sea fog measurements for extremely high signal-to-noise ratio of SNSPD.

Influence of spray parameters on the microstructure and mechanical properties of gas-tunnel plasma sprayed hydroxyapatite coatings

International Nuclear Information System (INIS)

Morks, M.F.; Kobayashi, Akira

2007-01-01

For biomedical applications, hydroxyapatite (HA) coatings were deposited on 304 stainless steel substrate by using a gas tunnel type plasma spraying process. The influences of spraying distances and plasma arc currents on the microstructure, hardness and adhesion properties of HA coatings were investigated. Microstructure observation by SEM showed that HA coatings sprayed at low plasma power have a porous structure and poor hardness. HA coatings sprayed at high plasma power and short spraying distance are characterized by good adhesion and low porosity with dense structure. Hardness increased for HA coatings sprayed at shorter spraying distance and higher plasma power, mainly due to the formation of dense coatings

Particle size distribution of aerosols sprayed from household hand-pump sprays containing fluorine-based and silicone-based compounds.

Science.gov (United States)

Kawakami, Tsuyoshi; Isama, Kazuo; Ikarashi, Yoshiaki

2015-01-01

Japan has published safety guideline on waterproof aerosol sprays. Furthermore, the Aerosol Industry Association of Japan has adopted voluntary regulations on waterproof aerosol sprays. Aerosol particles of diameter less than 10 µm are considered as "fine particles". In order to avoid acute lung injury, this size fraction should account for less than 0.6% of the sprayed aerosol particles. In contrast, the particle size distribution of aerosols released by hand-pump sprays containing fluorine-based or silicone-based compounds have not been investigated in Japan. Thus, the present study investigated the aerosol particle size distribution of 16 household hand-pump sprays. In 4 samples, the ratio of fine particles in aerosols exceeded 0.6%. This study confirmed that several hand-pump sprays available in the Japanese market can spray fine particles. Since the hand-pump sprays use water as a solvent and their ingredients may be more hydrophilic than those of aerosol sprays, the concepts related to the safety of aerosol-sprays do not apply to the hand pump sprays. Therefore, it may be required for the hand-pump spray to develop a suitable method for evaluating the toxicity and to establish the safety guideline.

Hard tissue ablation with a spray-assisted mid-IR laser

International Nuclear Information System (INIS)

Kang, H W; Rizoiu, I; Welch, A J

2007-01-01

The objective of this study was to understand the dominant mechanism(s) for dental enamel ablation with the application of water spray. A free-running Er,Cr:YSGG (yttrium, scandium, gallium, garnet) laser was used to ablate human enamel tissue at various radiant exposures. During dental ablation, distilled water was sprayed on the sample surface, and these results were compared to ablation without a spray (dry ablation). In order to identify dominant ablation mechanisms, transient acoustic waves were compared to ablation thresholds and the volume of material removed. The ablation profile and depth were measured using optical coherence tomography (OCT). Irregular surface modification, charring and peripheral cracks were associated with dry ablation, whereas craters for spray samples were relatively clean without thermal damage. In spite of a 60% higher ablation threshold for spray associated irradiations owing to water absorption, acoustic peak pressures were six times higher and ablation volume was up to a factor of 2 larger compared to dry ablation. The enhanced pressure and ablation performance of the spray-assisted process was the result of rapid water vaporization, material ejection with recoil stress, interstitial water explosion and possibly liquid-jet formation. With water cooling and abrasive/disruptive mechanical effects, the spray ablation can be a safe and efficient modality for dental treatment

Hard tissue ablation with a spray-assisted mid-IR laser

Science.gov (United States)

Kang, H. W.; Rizoiu, I.; Welch, A. J.

2007-12-01

The objective of this study was to understand the dominant mechanism(s) for dental enamel ablation with the application of water spray. A free-running Er,Cr:YSGG (yttrium, scandium, gallium, garnet) laser was used to ablate human enamel tissue at various radiant exposures. During dental ablation, distilled water was sprayed on the sample surface, and these results were compared to ablation without a spray (dry ablation). In order to identify dominant ablation mechanisms, transient acoustic waves were compared to ablation thresholds and the volume of material removed. The ablation profile and depth were measured using optical coherence tomography (OCT). Irregular surface modification, charring and peripheral cracks were associated with dry ablation, whereas craters for spray samples were relatively clean without thermal damage. In spite of a 60% higher ablation threshold for spray associated irradiations owing to water absorption, acoustic peak pressures were six times higher and ablation volume was up to a factor of 2 larger compared to dry ablation. The enhanced pressure and ablation performance of the spray-assisted process was the result of rapid water vaporization, material ejection with recoil stress, interstitial water explosion and possibly liquid-jet formation. With water cooling and abrasive/disruptive mechanical effects, the spray ablation can be a safe and efficient modality for dental treatment.

Release mitigation spray safety systems for chemical demilitarization applications.

Energy Technology Data Exchange (ETDEWEB)

Leonard, Jonathan; Tezak, Matthew Stephen; Brockmann, John E.; Servantes, Brandon; Sanchez, Andres L.; Tucker, Mark David; Allen, Ashley N.; Wilson, Mollye C.; Lucero, Daniel A.; Betty, Rita G.

2010-06-01

Sandia National Laboratories has conducted proof-of-concept experiments demonstrating effective knockdown and neutralization of aerosolized CBW simulants using charged DF-200 decontaminant sprays. DF-200 is an aqueous decontaminant, developed by Sandia National Laboratories, and procured and fielded by the US Military. Of significance is the potential application of this fundamental technology to numerous applications including mitigation and neutralization of releases arising during chemical demilitarization operations. A release mitigation spray safety system will remove airborne contaminants from an accidental release during operations, to protect personnel and limit contamination. Sandia National Laboratories recently (November, 2008) secured funding from the US Army's Program Manager for Non-Stockpile Chemical Materials Agency (PMNSCMA) to investigate use of mitigation spray systems for chemical demilitarization applications. For non-stockpile processes, mitigation spray systems co-located with the current Explosive Destruction System (EDS) will provide security both as an operational protective measure and in the event of an accidental release. Additionally, 'tented' mitigation spray systems for native or foreign remediation and recovery operations will contain accidental releases arising from removal of underground, unstable CBW munitions. A mitigation spray system for highly controlled stockpile operations will provide defense from accidental spills or leaks during routine procedures.

Seawater movement in the Japan Sea inferred from 14C measurement in seawater

International Nuclear Information System (INIS)

Otosaka, Shigeyoshi; Tanaka, Takayuki; Togawa, Orihiko; Amano, Hikaru; Aramaki, Takafumi

2008-01-01

Research Group for Environmental Science, JAEA has carried out oceanographic observations in the Japan Sea since 1997 to clarify the biogeochemical cycle in the Japan Sea. More than 3,000 seawater samples for measurement of radiocarbon were collected during the observations, and radiocarbon in the seawater samples was measured at AMS facility in JAEA Mutsu. In this paper, formation and circulation of water mass in the northern Japan Sea were discussed using analysis of radiocarbon and hydrographic data (e.g. salinity, temperature, nutrients). (author)

Modifications Of A Commercial Spray Gun

Science.gov (United States)

Allen, Peter B.

1993-01-01

Commercial spray gun modified to increase spray rate and make sprayed coats more nearly uniform. Consists of gun head and pneumatic actuator. Actuator opens valves for two chemical components, called "A" and "B," that react to produce foam. Components flow through orifices, into mixing chamber in head. Mixture then flows through control orifice to spray tip. New spray tip tapered to reduce area available for accumulation of foam and makes tip easier to clean.

Implementation and Development of the Incremental Hole Drilling Method for the Measurement of Residual Stress in Thermal Spray Coatings

Science.gov (United States)

Valente, T.; Bartuli, C.; Sebastiani, M.; Loreto, A.

2005-12-01

The experimental measurement of residual stresses originating within thick coatings deposited by thermal spray on solid substrates plays a role of fundamental relevance in the preliminary stages of coating design and process parameters optimization. The hole-drilling method is a versatile and widely used technique for the experimental determination of residual stress in the most superficial layers of a solid body. The consolidated procedure, however, can only be implemented for metallic bulk materials or for homogeneous, linear elastic, and isotropic materials. The main objective of the present investigation was to adapt the experimental method to the measurement of stress fields built up in ceramic coatings/metallic bonding layers structures manufactured by plasma spray deposition. A finite element calculation procedure was implemented to identify the calibration coefficients necessary to take into account the elastic modulus discontinuities that characterize the layered structure through its thickness. Experimental adjustments were then proposed to overcome problems related to the low thermal conductivity of the coatings. The number of calculation steps and experimental drilling steps were finally optimized.

Ensemble Diffraction Measurements of Spray Combustion in a Novel Vitiated Coflow Turbulent Jet Flame Burner

Science.gov (United States)

Cabra, R.; Hamano, Y.; Chen, J. Y.; Dibble, R. W.; Acosta, F.; Holve, D.

2000-01-01

An experimental investigation is presented of a novel vitiated coflow spray flame burner. The vitiated coflow emulates the recirculation region of most combustors, such as gas turbines or furnaces; additionally, since the vitiated gases are coflowing, the burner allows exploration of the chemistry of recirculation without the corresponding fluid mechanics of recirculation. As such, this burner allows for chemical kinetic model development without obscurations caused by fluid mechanics. The burner consists of a central fuel jet (droplet or gaseous) surrounded by the oxygen rich combustion products of a lean premixed flame that is stabilized on a perforated, brass plate. The design presented allows for the reacting coflow to span a large range of temperatures and oxygen concentrations. Several experiments measuring the relationships between mixture stoichiometry and flame temperature are used to map out the operating ranges of the coflow burner. These include temperatures as low 300 C to stoichiometric and oxygen concentrations from 18 percent to zero. This is achieved by stabilizing hydrogen-air premixed flames on a perforated plate. Furthermore, all of the CO2 generated is from the jet combustion. Thus, a probe sample of NO(sub X) and CO2 yields uniquely an emission index, as is commonly done in gas turbine engine exhaust research. The ability to adjust the oxygen content of the coflow allows us to steadily increase the coflow temperature surrounding the jet. At some temperature, the jet ignites far downstream from the injector tube. Further increases in the coflow temperature results in autoignition occurring closer to the nozzle. Examples are given of methane jetting into a coflow that is lean, stoichiometric, and even rich. Furthermore, an air jet with a rich coflow produced a normal looking flame that is actually 'inverted' (air on the inside, surrounded by fuel). In the special case of spray injection, we demonstrate the efficacy of this novel burner with a

Substrate system for spray forming

Energy Technology Data Exchange (ETDEWEB)

Chu, Men G. (Export, PA); Chernicoff, William P. (Harrisburg, PA)

2002-01-01

A substrate system for receiving a deposit of sprayed metal droplets including a movable outer substrate on which the sprayed metal droplets are deposited. The substrate system also includes an inner substrate disposed adjacent the outer substrate where the sprayed metal droplets are deposited on the outer substrate. The inner substrate includes zones of differing thermal conductivity to resist substrate layer porosity and to resist formation of large grains and coarse constituent particles in a bulk layer of the metal droplets which have accumulated on the outer substrate. A spray forming apparatus and associated method of spray forming a molten metal to form a metal product using the substrate system of the invention is also provided.

Seasonal variability of the Red Sea, from GRACE time-variable gravity and altimeter sea surface height measurements

Science.gov (United States)

Wahr, John; Smeed, David; Leuliette, Eric; Swenson, Sean

2014-05-01

Seasonal variability of sea surface height and mass within the Red Sea, occurs mostly through the exchange of heat with the atmosphere and wind-driven inflow and outflow of water through the strait of Bab el Mandab that opens into the Gulf of Aden to the south. The seasonal effects of precipitation and evaporation, of water exchange through the Suez Canal to the north, and of runoff from the adjacent land, are all small. The flow through the Bab el Mandab involves a net mass transfer into the Red Sea during the winter and a net transfer out during the summer. But that flow has a multi-layer pattern, so that in the summer there is actually an influx of cool water at intermediate (~100 m) depths. Thus, summer water in the southern Red Sea is warmer near the surface due to higher air temperatures, but cooler at intermediate depths (especially in the far south). Summer water in the northern Red Sea experiences warming by air-sea exchange only. The temperature profile affects the water density, which impacts the sea surface height but has no effect on vertically integrated mass. Here, we study this seasonal cycle by combining GRACE time-variable mass estimates, altimeter (Jason-1, Jason-2, and Envisat) measurements of sea surface height, and steric sea surface height contributions derived from depth-dependent, climatological values of temperature and salinity obtained from the World Ocean Atlas. We find good consistency, particularly in the northern Red Sea, between these three data types. Among the general characteristics of our results are: (1) the mass contributions to seasonal SSHT variations are much larger than the steric contributions; (2) the mass signal is largest in winter, consistent with winds pushing water into the Red Sea through the Strait of Bab el Mandab in winter, and out during the summer; and (3) the steric signal is largest in summer, consistent with summer sea surface warming.

Spray drift of pesticides and stream macroinvertebrates: Experimental evidence of impacts and effectiveness of mitigation measures

Energy Technology Data Exchange (ETDEWEB)

Maltby, Lorraine [Department of Animal and Plant Sciences, University of Sheffield, Western Bank, Sheffield S10 2TN (United Kingdom)], E-mail: l.maltby@sheffield.ac.uk; Hills, Louise [Department of Animal and Plant Sciences, University of Sheffield, Western Bank, Sheffield S10 2TN (United Kingdom)

2008-12-15

Impoverished stream communities in agricultural landscapes have been associated with pesticide contamination, but conclusive evidence of causality is rare. We address this deficiency by adopting an experimental approach to investigate the effects of the insecticides cypermethrin and chlorpyrifos on benthic macroinvertebrates. Three treatments were established and a combination of biomarker, bioassay and biomonitoring approaches was employed to investigate, individual, population and community-level effects. Animals deployed during pesticide application had altered enzyme activity, depressed feeding rate and reduced survival, but these effects were only observed where pesticide was sprayed to the stream edge. There were no clear pesticide-related effects on macroinvertebrate community structure or on the population densities of individual species. Hence, short-term pesticide exposure did cause individual-level effects in stream macroinvertebrates, but these were not translated to effects at the population or community-level and were effectively mitigated by the adoption of a no-spray buffer zone. - Pulsed pesticide exposures via spray drift adversely affected stream invertebrates but did not cause population or community-level effects and were mitigated by no-spray buffer zones.

Effects of self-pulsation on the spray characteristics of gas-liquid swirl coaxial injector

Science.gov (United States)

Kang, Zhongtao; Li, Qinglian; Cheng, Peng; Zhang, Xinqiao; Wang, Zhen-guo

2016-10-01

To understand the influence of self-pulsation on the spray characteristics of gas-liquid swirl coaxial injector, a back-lighting photography technique has been employed to capture the instantaneous self-pulsated spray and stable spray images with a high speed camera. The diameter and velocity of the droplets in the spray have been characterized with a Dantec Phase Doppler Anemometry (PDA) system. The effects of self-pulsation on the spray pattern, primary breakup, spray angle, diameter and velocity distribution and mass flow rate distribution are analyzed and discussed. The results show that the spray morphology is greatly influenced by self-pulsation. The stable spray has a cone shape, while the self-pulsated spray looks like a Christmas tree. The main difference of these two sprays is the primary breakup. The liquid film of stable spray keeps stable while that of self-pulsated spray oscillates periodically. The film width of self-pulsated spray varies in a large range with 'neck' and 'shoulder' features existing. The liquid film of self-pulsated spray breaks up at the second neck, and then the second shoulder begins to breakup into ligaments. The self-pulsated spray produces droplet clusters periodically, varies horizontal spray width and mass flux periodically. From the point of spatial distribution, self-pulsation is good for the spray, it uniformizes the mass flux along radius and increases the spray angle. However, when self-pulsation occurs, the SMD distribution varies from an inverted V shape to a hollow cone shape, and SMD increases at all the measuring points. Namely, from the point of atomization performance, self-pulsation has negative effects even when the breakup length is smaller. The effects of self-pulsation on the diameter and velocity distributions of the spray are mainly in the center part of the spray. The periphery of stable and self-pulsated spray has similar diameter and velocity distribution.

A spray flamelet/progress variable approach combined with a transported joint PDF model for turbulent spray flames

Science.gov (United States)

Hu, Yong; Olguin, Hernan; Gutheil, Eva

2017-05-01

A spray flamelet/progress variable approach is developed for use in spray combustion with partly pre-vaporised liquid fuel, where a laminar spray flamelet library accounts for evaporation within the laminar flame structures. For this purpose, the standard spray flamelet formulation for pure evaporating liquid fuel and oxidiser is extended by a chemical reaction progress variable in both the turbulent spray flame model and the laminar spray flame structures, in order to account for the effect of pre-vaporised liquid fuel for instance through use of a pilot flame. This new approach is combined with a transported joint probability density function (PDF) method for the simulation of a turbulent piloted ethanol/air spray flame, and the extension requires the formulation of a joint three-variate PDF depending on the gas phase mixture fraction, the chemical reaction progress variable, and gas enthalpy. The molecular mixing is modelled with the extended interaction-by-exchange-with-the-mean (IEM) model, where source terms account for spray evaporation and heat exchange due to evaporation as well as the chemical reaction rate for the chemical reaction progress variable. This is the first formulation using a spray flamelet model considering both evaporation and partly pre-vaporised liquid fuel within the laminar spray flamelets. Results with this new formulation show good agreement with the experimental data provided by A.R. Masri, Sydney, Australia. The analysis of the Lagrangian statistics of the gas temperature and the OH mass fraction indicates that partially premixed combustion prevails near the nozzle exit of the spray, whereas further downstream, the non-premixed flame is promoted towards the inner rich-side of the spray jet since the pilot flame heats up the premixed inner spray zone. In summary, the simulation with the new formulation considering the reaction progress variable shows good performance, greatly improving the standard formulation, and it provides new

Hydrogen permeation properties of plasma-sprayed tungsten*1

Science.gov (United States)

Anderl, R. A.; Pawelko, R. J.; Hankins, M. R.; Longhurst, G. R.; Neiser, R. A.

1994-09-01

Tungsten has been proposed as a plasma-facing component material for advanced fusion facilities. This paper reports on laboratory-scale studies that were done to assess the hydrogen permeation properties of plasma-sprayed tungsten for such applications. The work entailed deuterium permeation measurements for plasma-sprayed (PS) tungsten coatings, sputter-deposited (SP) tungsten coatings, and steel substrate material using a mass-analyzed, 3 keV D 3+ ion beam with fluxes of ˜6.5 × 10 19 D/m 2 s. Extensive characterization analyses for the plasma-sprayed tungsten coatings were made using Auger spectrometry and scanning electron microscopy (SEM). Observed permeation rates through composite PS-tungsten/steel specimens were several orders of magnitude below the permeation levels observed for SP-tungsten/steel composite specimens and pure steel specimens. Characterization analyses indicated that the plasma-sprayed tungsten coating had a nonhomogeneous microstructure that consisted of splats with columnar solidification, partially-melted particles with grain boundaries, and void regions. Reduced permeation levels can be attributed to the complex microstructure and a substantial surface-connected porosity.

Flow regime effects on non-cavitating injection nozzles over spray behavior

Energy Technology Data Exchange (ETDEWEB)

Payri, R., E-mail: rpayri@mot.upv.e [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, Valencia E-46022 (Spain); Salvador, F.J.; Gimeno, J.; Novella, R. [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, Valencia E-46022 (Spain)

2011-02-15

This paper deals with the influence of flow regime (laminar, transition or turbulent) on the internal flow behavior, and how it affects the spray development in diesel nozzles. In particular, the research described here aims at studying and quantifying the internal flow regime effects on the spray behavior. With this purpose, internal flow results, based on mass flow rate and momentum flux measurements performed on three different tapered nozzles and which helped to determine the flow regime, has been taken into account as a point of departure for the spray behavior analysis. Thus, in this work, spray macroscopic visualization tests have been performed and analyzed which clearly revealed a change in the behavior of the angle and penetration of the spray related to the change of the flow nature. Moreover, with all the experimental data available, it has been possible to relate macroscopic parameters of the spray with those describing the internal flow (momentum and effective velocity) or the geometry of the nozzle (length or diameter) through correlations.

Particle emission rates during electrostatic spray deposition of TiO2 nanoparticle-based photoactive coating

DEFF Research Database (Denmark)

Koivisto, Antti J.; Jensen, Alexander C. Ø.; Kling, Kirsten I.

2017-01-01

Here, we studied the particle release rate during Electrostatic spray deposition of anatase-(TiO2)-based photoactive coating onto tiles and wallpaper using a commercially available electrostatic spray device. Spraying was performed in a 20.3m3 test chamber while measuring concentrations of 5.6nm ...

Comparison of measured and satellite-derived spectral diffuse attenuation coefficients for the Arabian Sea

Digital Repository Service at National Institute of Oceanography (India)

Suresh, T.; Talaulikar, M.; Desa, E.; Matondkar, S.G.P.; Mascarenhas, A.

The results of study comparing the spectral diffuse attenuation coefficients Kd(Lambda) measured in the Arabian Sea with those derived from the Sea-Viewing Wide Field-of-View Sensor (SeaWiFS) using three algorithms, of which two are empirical...

Experimental and analytical study on biodiesel and diesel spray characteristics under ultra-high injection pressure

International Nuclear Information System (INIS)

Wang Xiangang; Huang Zuohua; Kuti, Olawole Abiola; Zhang Wu; Nishida, Keiya

2010-01-01

Spray characteristics of biodiesels (from palm and cooked oil) and diesel under ultra-high injection pressures up to 300 MPa were studied experimentally and analytically. Injection delay, spray penetration, spray angle, spray projected area and spray volume were measured in a spray vessel using a high speed video camera. Air entrainment and atomization characteristics were analyzed with the quasi-steady jet theory and an atomization model respectively. The study shows that biodiesels give longer injection delay and spray tip penetration. Spray angle, projected area and volume of biodiesels are smaller than those of diesel fuel. The approximately linear relationship of non-dimensional spray tip penetration versus time suggests that the behavior of biodiesel and diesel sprays is similar to that of gaseous turbulent jets. Calculation from the quasi-steady jet theory shows that the air entrainment of palm oil is worse than that of diesel, while the cooked oil and diesel present comparable air entrainment characteristics. The estimation on spray droplet size shows that biodiesels generate larger Sauter mean diameter due to higher viscosity and surface tension.

Characterization of viscous biofuel sprays using digital imaging in the near field region

International Nuclear Information System (INIS)

Sallevelt, J.L.H.P.; Pozarlik, A.K.; Brem, G.

2015-01-01

Highlights: • Biodiesel, vegetable oil and glycerin sprays have been studied using PDIA. • The study is focused on the effect of fuel viscosity on the spray characteristics. • Viscosity has a strong effect on the breakup length in pressure-swirl atomization. • The results are compared to combustion experiments with a micro gas turbine. • The penetration depth of ligaments can be a critical factor in burning viscous fuel. - Abstract: The atomization of biodiesel, vegetable oil and glycerin has been studied in an atmospheric spray rig by using digital imaging (PDIA). Images of the spray were captured in the near field, just 18 mm downstream of the atomizer, and processed to automatically determine the size of both ligaments and droplets. The effect of the spray structure in this region is of major interest for the combustion of biofuels in gas turbines. The sprays were produced by a pressure-swirl atomizer that originates from the multifuel micro gas turbine (MMGT) setup. Various injection conditions have been tested to investigate the influence of viscosity on the spray characteristics and to assess the overall performance of the atomizer. The spray measurements have been compared to combustion experiments with biodiesel and vegetable oil in the micro gas turbine at similar injection conditions. The results show that the primary breakup process rapidly deteriorates when the viscosity is increased. A higher viscosity increases the breakup length, which becomes visible at the measurement location in the form of ligaments. This effect leads to an unacceptable spray quality once the viscosity slightly exceeds the typical range for conventional gas turbine fuels. The SMD in the investigated spray region was not significantly affected by viscosity, but mainly influenced by injection pressure. The data furthermore indicate an increase in SMD with surface tension. It was found that the penetration depth of ligaments can have major impact on the combustion process

Dynamics of flare sprays

International Nuclear Information System (INIS)

Tandberg-Hanssen, E.; Hansen, R.T.

1980-01-01

During solar cycle No. 20 new insight into the flare-spray phenomenon has been attained due to several innovations in solar optical-observing techniques (higher spatial resolution cinema-photography, tunable pass-band filters, multi-slit spectroscopy and extended angular field coronographs). From combined analysis of 13 well-observed sprays which occured between 1969-1974 we conclude that (i) the spray material originates from a preexisting active region filament which undergoes increased absorption some tens of minutes prior to the abrupt chromospheric brightening at the 'flare-start', and (ii) the spray material is confined within a steadily expanding, loop-shaped (presumably magnetically controlled) envelope with part of the material draining back down along one or both legs of the loop. (orig.)

Absorption/desorption in sprays

International Nuclear Information System (INIS)

Naimpally, A.

1987-01-01

This survey paper shall seek to present the present state of knowledge concerning absorption and desorption in spray chambers. The first part of the paper presents the theories and formulas for the atomization and break-up of sprays in nozzles. Formulas for the average (sauter-mean) diameters are then presented. For the case of absorption processes, the formulas for the dimensionless mass transfer coefficients is in drops. The total; mass transfer is the total of the transfer in individual drops. For the case of desorption of sparingly soluble gases from liquids in a spray chamber, the mass transfer occurs in the spray just at the point of break-up of the jet. Formulas for the desorption of gases are presented

Dissolved organic matter in sea spray: a transfer study from marine surface water to aerosols

Science.gov (United States)

Schmitt-Kopplin, P.; Liger-Belair, G.; Koch, B. P.; Flerus, R.; Kattner, G.; Harir, M.; Kanawati, B.; Lucio, M.; Tziotis, D.; Hertkorn, N.; Gebefügi, I.

2012-04-01

Atmospheric aerosols impose direct and indirect effects on the climate system, for example, by absorption of radiation in relation to cloud droplets size, on chemical and organic composition and cloud dynamics. The first step in the formation of Organic primary aerosols, i.e. the transfer of dissolved organic matter from the marine surface into the atmosphere, was studied. We present a molecular level description of this phenomenon using the high resolution analytical tools of Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) and nuclear magnetic resonance spectroscopy (NMR). Our experiments confirm the chemoselective transfer of natural organic molecules, especially of aliphatic compounds from the surface water into the atmosphere via bubble bursting processes. Transfer from marine surface water to the atmosphere involves a chemical gradient governed by the physicochemical properties of the involved molecules when comparing elemental compositions and differentiating CHO, CHNO, CHOS and CHNOS bearing compounds. Typical chemical fingerprints of compounds enriched in the aerosol phase were CHO and CHOS molecular series, smaller molecules of higher aliphaticity and lower oxygen content, and typical surfactants. A non-targeted metabolomics analysis demonstrated that many of these molecules corresponded to homologous series of oxo-, hydroxy-, methoxy-, branched fatty acids and mono-, di- and tricarboxylic acids as well as monoterpenes and sugars. These surface active biomolecules were preferentially transferred from surface water into the atmosphere via bubble bursting processes to form a significant fraction of primary organic aerosols. This way of sea spray production leaves a selective biological signature of the surface water in the corresponding aerosol that may be transported into higher altitudes up to the lower atmosphere, thus contributing to the formation of secondary organic aerosol on a global scale or transported laterally with

Spatial and temporal distribution of airborne Bacillus thuringiensis var. kurstaki during an aerial spray program for gypsy moth eradication.

OpenAIRE

Teschke, K; Chow, Y; Bartlett, K; Ross, A; van Netten, C

2001-01-01

We measured airborne exposures to the biological insecticide Bacillus thuringiensis var. kurstaki (Btk) during an aerial spray program to eradicate gypsy moths on the west coast of Canada. We aimed to determine whether staying indoors during spraying reduced exposures, to determine the rate of temporal decay of airborne concentrations, and to determine whether drift occurred outside the spray zone. During spraying, the average culturable airborne Btk concentration measured outdoors within the...

Research on electrostatic electrification during jet kerosene spraying

International Nuclear Information System (INIS)

Liu, Quanzhen; Li, Yipeng; Zhang, Wentian; Sun, Keping

2013-01-01

Multiple electrostatic electrifications during aircraft fuelling process may cause a fire disaster or explosion, so study on the protection measure for electrostatic electrification is very important for the security of aircraft fuelling. This paper investigated the electrostatic voltage and charge of the fuel nozzle and metal parts during the fuel spraying by self-designed jet kerosene spraying electrostatic electrification test system. The experimental results indicate that the voltage on the fuel nozzle and metal parts is very dangerous for electrostatic safety if they are not reliably grounded.

Pretreatment Prediction of the Outcomes of Intranasal Steroid Sprays in Cases with Inferior Turbinate Hypertrophy.

Science.gov (United States)

Karataş, Abdullah

2017-09-01

Intranasal steroid sprays (INSS) are frequently prescribed for treating inferior turbinate hypertrophy (ITH). Complications due to the long-term application of INSS such as crusting, epistaxis, nasal mucosa dryness, and septal perforation may occur. Predicting patients who would benefit from INSS early might lower treatment costs and complication rates. We examined the predictive value of nasal decongestant response rates for the outcomes of INSS in ITH. Fifty patients with bilateral ITH were included in two groups: patients benefiting from INSS and those not benefiting. Nasal airflow was assessed by peak nasal inspiratory flow (PNIF) measurement in all cases. Measurements were taken three times: before and after the application of nasal decongestant sprays and after the application of INSS. In both groups, the nasal air flow rates significantly increased after the application of nasal decongestant sprays; however, the nasal decongestant response rates were higher in the group with patients benefiting from INSS. There was a strong correlation between the nasal air flow rates measured after the application of nasal decongestant sprays and after the application of INSS. The cut-off value for the relationship between increased nasal air flow rates after the application of nasal decongestant sprays and outcomes of INSS was 23%. Measurement of nasal airflow increase rate after the application of nasal decongestant sprays is a simple and easy method for the early prediction of the outcomes of INSS in ITH. A higher than 23% increase in nasal air flow rates after the application of nasal decongestant sprays indicates much better outcomes of INSS for patients.

Crop adapted spray application (CASA) - precise and safe plant protection in fruit growing

NARCIS (Netherlands)

Doruchowski, G.; Balsari, P.; Marucco, P.; Zande, van de J.C.; Wenneker, M.

2012-01-01

The Crop Adapted Spray Application (CASA) system for orchards integrates disease detection based on reflectance imaging, crop identification with ultrasonic sensors, wind measurement and DGPS navigation. Through the automatic adjustment of spray application parameters according to the crop

Spray characterization of a piezo pintle-type injector for gasoline direct injection engines

Science.gov (United States)

Nouri, J. M.; Hamid, M. A.; Yan, Y.; Arcoumanis, C.

2007-10-01

The sprays from a pintle-type nozzle injected into a constant volume chamber have been visualised by a high resolution CCD camera and quantified in terms of droplet velocity and diameter with a 2-D phase Doppler anemometry (PDA) system at an injection pressure of 200 bar and back-pressures varying from atmospheric to 12 bar. Spray visualization illustrated that the spray was string-structured, that the location of the strings remained constant from one injection to the next and that the spray structure was unaffected by back pressure. The overall spray cone angle was also stable and independent of back pressure whose effect was to reduce the spray tip penetration so that the averaged vertical spray tip velocity was reduced by 37% when the back-pressure increased from 1 to 12 bar. Detailed PDA measurements were carried out under atmospheric conditions at 2.5 and 10 mm from the injector exit with the results providing both the temporal and the spatial velocity and size distributions of the spray droplets. The maximum axial mean droplet velocity was 155 m/s at 2.5 mm from the injector which was reduced to 140 m/s at z = 10 mm. The string spacing determined from PDA measurements was around 0.375 mm and 0.6 mm at z=2.5 and 10 mm, respectively. The maximum mean droplet diameter was found to be in the core of the strings with values up to 40 μm at z=2.5 mm reducing to 20 μm at z=10 mm.

Spray characterization of a piezo pintle-type injector for gasoline direct injection engines

International Nuclear Information System (INIS)

Nouri, J M; Hamid, M A; Yan, Y; Arcoumanis, C

2007-01-01

The sprays from a pintle-type nozzle injected into a constant volume chamber have been visualised by a high resolution CCD camera and quantified in terms of droplet velocity and diameter with a 2-D phase Doppler anemometry (PDA) system at an injection pressure of 200 bar and back-pressures varying from atmospheric to 12 bar. Spray visualization illustrated that the spray was string-structured, that the location of the strings remained constant from one injection to the next and that the spray structure was unaffected by back pressure. The overall spray cone angle was also stable and independent of back pressure whose effect was to reduce the spray tip penetration so that the averaged vertical spray tip velocity was reduced by 37% when the back-pressure increased from 1 to 12 bar. Detailed PDA measurements were carried out under atmospheric conditions at 2.5 and 10 mm from the injector exit with the results providing both the temporal and the spatial velocity and size distributions of the spray droplets. The maximum axial mean droplet velocity was 155 m/s at 2.5 mm from the injector which was reduced to 140 m/s at z = 10 mm. The string spacing determined from PDA measurements was around 0.375 mm and 0.6 mm at z=2.5 and 10 mm, respectively. The maximum mean droplet diameter was found to be in the core of the strings with values up to 40 μm at z=2.5 mm reducing to 20 μm at z=10 mm

Effects of ambient pressure on dynamics of near-nozzle diesel sprays studied by ultrafast x-radiography

International Nuclear Information System (INIS)

Cheong, S. K.; Liu, J.; Shu, D.; Wang, J.; Powell, C. F.; Experimental Facilities Division

2004-01-01

A time-resolved x-radiographic technique has been employed for measuring the fuel distribution close to a single-hole nozzle fitted in a high-pressure diesel injector. Using a monochromatic synchrotron x-ray beam, it is possible to perform quantitative x-ray absorption measurements and obtain two-dimensional projections of the mass of the fuel spray. We have completed a series of spray measurements in the optically dense, near-nozzle region (ml 15 mm from the nozzle orifice) under ambient pressures of 1, 2, and 5.2 bar Nd2 and 1 bar SFd6 at room temperature with injection pressures of 500 and 1000 bar. The focus of the measurements is on the dynamical behaviors of the fuel jets with an emphasis on their penetration in the near-nozzle region. Careful analysis of the time-resolved, x-radiographic data revealed that the spray penetration in this near-nozzle region was not significantly affected by the limited change of the ambient pressure. In addition, well-defined features of the spray, such as the leading and trailing edges, and fluctuations of fuel mass density in the spray body, allowed us to calculate the leading, trailing, and internal speeds of the sprays

Field experiment on spray drift: Deposition and airborne drift during application to a winter wheat crop

NARCIS (Netherlands)

Wolters, A.; Linnemann, V.; Zande, van de J.C.; Vereecken, H.

2008-01-01

A field experiment was performed to evaluate various techniques for measuring spray deposition and airborne drift during spray application to a winter wheat crop. The application of a spraying agent containing the fluorescent dye Brilliant Sulfo Flavine by a conventional boom sprayer was done

Development of spraying methods for high density bentonite barriers. Part 3. Field investigation of spraying methods

International Nuclear Information System (INIS)

Tanaka, Toshiyuki; Nakajima, Makoto; Kobayashi, Ichizo; Toida, Masaru; Fukuda, Katsumi; Sato, Tatsuro; Nonaka, Katsumi; Gozu, Keisuke

2007-01-01

The authors have developed a new method of constructing high density bentonite barriers by means of a wet spraying method. Using this method, backfill material can be placed in narrow upper and side parts in a low-level radioactive waste disposal facility. Using a new supplying machine for bentonite, spraying tests were conducted to investigate the conditions during construction. On the basis of the test results, the various parameters for the spraying method were investigated. The test results are summarized as follows: 1. The new machine supplied about twice the weight of material supplied by a screw conveyor. A dry density of spraying bentonite 0.05 Mg/m 3 higher than that of a screw conveyor with the same water content could be achieved. 2. The dry density of sprayed bentonite at a boundary with concrete was the same as that at the center of the cross section. 3. The variation in densities of bentonite sprayed in the vertical downward and horizontal directions was small. Also, density reduction due to rebound during spraying was not seen. 4. Bentonite controlled by water content could be sprayed smoothly in the horizontal direction by a small machine. Also rebound could be collected by a machine conveying air. (author)

Stoichiometry and superconductive properties of YBaCuO films deposited by spray pyrolysis

International Nuclear Information System (INIS)

Conde-Gallardo, A.; Falcony, C.; Ortiz, A.

1994-01-01

The dependence of the stoichiometry and the superconducting characteristics of YBaCuO films deposited by spray pyrolysis on the spraying solution composition and the deposition conditions is reported. It has been found that a proper optimization of the starting materials concentration in the spraying solution results in superconducting films with zero resistance temperature of 91 K and a transition to superconducting state within a 3 K range. X-ray diffraction and resistance vs temperature measurements have been used to monitor the crystal composition and the conductive characteristics of the films as a function of the spraying solution composition and the deposition parameters

1994 Thermal spray industrial applications: Proceedings

International Nuclear Information System (INIS)

Berndt, C.C.; Sampath, S.

1994-01-01

The 7th National Thermal Spray Conference met on June 20--24, 1994, in Boston, Massachusetts. The conference was sponsored by the Thermal Spray Division of ASM International and co-sponsored by the American Welding Society, Deutscher Verband fur Schweisstechnik e.V., High Temperature Society of Japan, International Thermal Spray Association, and Japanese Thermal Spraying Society. The conference covered applications for automobiles, aerospace, petrochemicals, power generation, and biomedical needs. Materials included metals, ceramics, and composites with a broad range of process developments and diagnostics. Other sections included modeling and systems control; spray forming and reactive spraying; post treatment; process, structure and property relationships; mechanical properties; and testing, characterization and wear. One hundred and seventeen papers have been processed separately for inclusion on the data base

Plasma sprayed samarium--cobalt permanent magnets

International Nuclear Information System (INIS)

Willson, M.C.; Janowiecki, R.J.

1975-01-01

Samarium--cobalt permanent magnets were fabricated by arc plasma spraying. This process involves the injection of relatively coarse powder particles into a high-temperature gas for melting and spraying onto a substrate. The technique is being investigated as an economical method for fabricating cobalt--rare earth magnets for advanced traveling wave tubes and cross-field amplifiers. Plasma spraying permits deposition of material at high rates over large areas with optional direct bonding to the substrate, and offers the ability to fabricate magnets in a variety of shapes and sizes. Isotropic magnets were produced with high coercivity and good reproducibility in magnetic properties. Post-spray thermal treatments were used to enhance the magnetic properties of sprayed deposits. Samarium--cobalt magnets, sprayed from samarium-rich powder and subjected to post-spray heat treatment, displayed energy products in excess of 9 million gauss-oersteds and coercive forces of approximately 6000 oersteds. Bar magnet arrays were constructed by depositing magnets on ceramic substrates. (auth)

Plasma sprayed samarium--cobalt permanent magnets

International Nuclear Information System (INIS)

Willson, M.C.; Janowiecki, R.J.

1975-01-01

Samarium--Co permanent magnets were fabricated by arc plasma spraying. This process involves the injection of relatively coarse powder particles into a high temperature gas for melting and spraying onto a substrate. The technique is being investigated as an economical method for fabricating Co--rare earth magnets for advanced traveling wave tubes and cross-field amplifiers. Plasma spraying permits deposition of material at high rates over large areas with optional direct bonding to the substrate, and offers the ability to fabricate magnets in a variety of shapes and sizes. Isotropic magnets were produced with high coercivity and good reproducibility in magnetic properties. Post-spray thermal treatments were used to enhance the magnetic properties of sprayed deposits. Samarium--Co magnets, sprayed from Sm-rich powder and subjected to post-spray heat treatment, displayed energy products in excess of 9 million G-Oe and coercive forces of approximately 6000 Oe. Bar magnet arrays were constructed by depositing magnets on ceramic substrates

Measuring the sea quark polarization

International Nuclear Information System (INIS)

Makdisi, Y.

1993-01-01

Spin is a fundamental degree of freedom and measuring the spin structure functions of the nucleon should be a basic endeavor for hadron physics. Polarization experiments have been the domain of fixed target experiments. Over the years large transverse asymmetries have been observed where the prevailing QCD theories predicted little or no asymmetries, and conversely the latest deep inelastic scattering experiments of polarized leptons from polarized targets point to the possibility that little of the nucleon spin is carried by the valence quarks. The possibility of colliding high luminosity polarized proton beams in the Brookhaven Relativistic Heavy Ion Collider (RHIC) provides a great opportunity to extend these studies and systematically probe the spin dependent parton distributions specially to those reactions that are inaccessible to current experiments. This presentation focuses on the measurement of sea quark and possibly the strange quark polarization utilizing the approved RHIC detectors

Spray Drift Reduction Evaluations of Spray Nozzles Using a Standardized Testing Protocol

Science.gov (United States)

2010-07-01

Drop Size Characteristics in a Spray Using Optical Nonimaging Light-Scattering Instruments,” Annual Book of ASTM Standards, Vol. 14-02, ASTM...Test Method for Determining Liquid Drop Size Characteristics in a Spray Using Optical Non- imaging Light-Scattering Instruments 22. AGDISP Model

Spatial and temporal distribution of airborne Bacillus thuringiensis var. kurstaki during an aerial spray program for gypsy moth eradication.

Science.gov (United States)

Teschke, K; Chow, Y; Bartlett, K; Ross, A; van Netten, C

2001-01-01

We measured airborne exposures to the biological insecticide Bacillus thuringiensis var. kurstaki (Btk) during an aerial spray program to eradicate gypsy moths on the west coast of Canada. We aimed to determine whether staying indoors during spraying reduced exposures, to determine the rate of temporal decay of airborne concentrations, and to determine whether drift occurred outside the spray zone. During spraying, the average culturable airborne Btk concentration measured outdoors within the spray zone was 739 colony-forming units (CFU)/m3 of air. Outdoor air concentrations decreased over time, quickly in an initial phase with a half time of 3.3 hr, and then more slowly over the following 9 days, with an overall half-time of about 2.4 days. Inside residences during spraying, average concentrations were initially 2-5 times lower than outdoors, but at 5-6 hr after spraying began, indoor concentrations exceeded those outdoors, with an average of 244 CFU/m3 vs. 77 CFU/m3 outdoors, suggesting that the initial benefits of remaining indoors during spraying may not persist as outside air moves indoors with normal daily activities. There was drift of culturable Btk throughout a 125- to 1,000-meter band outside the spray zone where measurements were made, a consequence of the fine aerosol sizes that remained airborne (count median diameters of 4.3 to 7.2 microm). Btk concentrations outside the spray zone were related to wind speed and direction, but not to distance from the spray zone.

Effects of spray axis incident angle on heat transfer performance of rhombus-pitch shell-and-tube interior spray evaporator

International Nuclear Information System (INIS)

Lin, Ru-Li; Chang, Tong-Bou; Liang, Chih-Chang

2012-01-01

An interior spray method is proposed for enhancing the heat transfer performance of a compact rhombus-pitch shell-and-tube spray evaporator. The experimental results show that the shell-side heat transfer coefficient obtained using the proposed spray method is significantly higher than that achieved in a conventional flooded-type evaporator. Four different spray axis incident angles (0 .deg., 45 .deg., 60 .deg. and 75 .deg.) are tested in order to investigate the effect of the spray inclination angle on the heat transfer performance of the spray evaporator system. It is shown that the optimal heat transfer performance is obtained using a spray axis incident angle of 60 .deg.

Radiolysis of spray solutions

International Nuclear Information System (INIS)

Habersbergerova, A.; Janovsky, I.

1985-01-01

The factors were studied affecting thiosulfate radiolysis in the so-called spray solution for nuclear power plant containments. The reaction mechanism of primary radiolytic reactions leading to thiosulfate decomposition was studied using pulse radiolysis. Also measured was hydrazine loss in the irradiation of the bubbling solution intended for the capture of volatile chemical forms of radioiodine. Pulse radiolysis was used to study the kinetics of hydrazine reaction with elemental iodine. (author)

Fixed automated spray technology.

Science.gov (United States)

2011-04-19

This research project evaluated the construction and performance of Boschungs Fixed Automated : Spray Technology (FAST) system. The FAST system automatically sprays de-icing material on : the bridge when icing conditions are about to occur. The FA...

Measurement of inherent optical properties in the Arabian Sea

Digital Repository Service at National Institute of Oceanography (India)

Suresh, T.; Desa, E.; Kurian, J.; Mascarenhas, A.A.M.Q.

Inherent optical properties, absorption and began attenuation were measured in situ using a reflective tube absorption meter at nint wavelength, 412, 440, 488, 510, 555, 630, 650, 676 and 715 nm, in the Arabian Sea during March. Since inherent...

Vision-aided Monitoring and Control of Thermal Spray, Spray Forming, and Welding Processes

Science.gov (United States)

Agapakis, John E.; Bolstad, Jon

1993-01-01

Vision is one of the most powerful forms of non-contact sensing for monitoring and control of manufacturing processes. However, processes involving an arc plasma or flame such as welding or thermal spraying pose particularly challenging problems to conventional vision sensing and processing techniques. The arc or plasma is not typically limited to a single spectral region and thus cannot be easily filtered out optically. This paper presents an innovative vision sensing system that uses intense stroboscopic illumination to overpower the arc light and produce a video image that is free of arc light or glare and dedicated image processing and analysis schemes that can enhance the video images or extract features of interest and produce quantitative process measures which can be used for process monitoring and control. Results of two SBIR programs sponsored by NASA and DOE and focusing on the application of this innovative vision sensing and processing technology to thermal spraying and welding process monitoring and control are discussed.

Characterization of fully functional spray-on antibody thin films

Energy Technology Data Exchange (ETDEWEB)

Figueroa, Jhon [Department of Chemistry, University of South Florida, 4202 E. Fowler Ave., Tampa, FL 33620-5250 (United States); Magaña, Sonia; Lim, Daniel V. [Department of Cell Biology, Microbiology and Molecular Biology, University of South Florida, 4202 E. Fowler Ave., Tampa, FL 33620-7115 (United States); Schlaf, Rudy, E-mail: schlaf@eng.usf.edu [Department of Electrical Engineering, University of South Florida, 4202 E. Fowler Ave., Tampa, FL 33620-5101 (United States)

2014-02-15

The authors recently demonstrated that fully functional Escherichia coli O157:H7 antibody thin films can be prepared using a simple pneumatic nebulizer on glass surface [1]. This paper focuses on the investigation of the morphology and physical properties of these films with the aim to better understand their performance. A series of E. coli O157:H7 antibody spray-on thin films were investigated by ellipsometry, X-ray photoelectron spectroscopy (XPS), immunoassays, attenuated total reflectance-Fourier transform infrared spectroscopy (ATR-FTIR), fluorescence microscopy, atomic force microscope (AFM) and contact angle analysis. These data were compared to measurements on films prepared with the biotin–avidin covalent bonding scheme. The investigation showed that films created by a 2 min pneumatic spray deposition time can capture antigens similar as the avidin–biotin wet-chemical method. The results also suggests that an influential factor for the comparable capture cell ability between sprayed and covalent films is an increased antibody surface coverage for the sprayed films (non-equilibrium technique), which compensates for the lack of its antibody orientation. There was no significant antibody denaturation detected on any of the sprayed films. Both techniques led to the formation of cluster-aggregates, a factor that seems unavoidable due to the natural tendency of protein to cluster. The avidin–biotin bridge films generally had a higher roughness, which manifested itself in a higher wettability compared to the sprayed films.

Standard practice for modified salt spray (fog) testing

CERN Document Server

American Society for Testing and Materials. Philadelphia

2009-01-01

1.1 This practice covers and sets forth conditions for five modifications in salt spray (fog) testing for specification purposes. These are in chronological order of their development: 1.1.1 Annex A1, acetic acid-salt spray test, continuous. 1.1.2 Annex A2, cyclic acidified salt spray test. 1.1.3 Annex A3, seawater acidified test, cyclic (SWAAT). 1.1.4 Annex A4, SO2 salt spray test, cyclic. 1.1.5 Annex A5, dilute electrolyte cyclic fog dry test. 1.2 This practice does not prescribe the type of modification, test specimen or exposure periods to be used for a specific product, nor the interpretation to be given to the results. 1.3 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to consult and establish appropriate safety and health practices and determine the applicabilit...

Estimation of the diameter-charge distribution in polydisperse electrically charged sprays of electrically insulating liquids

Energy Technology Data Exchange (ETDEWEB)

Rigit, A.R.H. [University of Sarawak, Faculty of Engineering, Kota Samarahan, Sarawak (Malaysia); Shrimpton, John S. [University of Southampton, Energy Technology Research Group, School of Engineering Sciences, Southampton (United Kingdom)

2009-06-15

The majority of scientific and industrial electrical spray applications make use of sprays that contain a range of drop diameters. Indirect evidence suggests the mean drop diameter and the mean drop charge level are usually correlated. In addition, within each drop diameter class there is every reason to suspect a distribution of charge levels exist for a particular drop diameter class. This paper presents an experimental method that uses the joint PDF of drop velocity and diameter, obtained from phase Doppler anemometry measurements, and directly obtained spatially resolved distributions of the mass and charge flux to obtain a drop diameter and charge frequency distribution. The method is demonstrated using several data-sets obtained from experimental measurements of steady poly-disperse sprays of an electrically insulating liquid produced with the charge injection technique. The space charge repulsion in the spray plume produces a hollow cone spray structure. In addition an approximate self-similarity is observed, with the maximum radial mass and charge flow occurring at r/d{proportional_to}200. The charge flux profile is slightly offset from the mass flux profile, and this gives direct evidence that the spray specific charge increases from approximately 20% of the bulk mean spray specific charge on the spray axis to approximately 200% of the bulk mean specific charge in the periphery of the spray. The results from the drop charge estimation model suggest a complex picture of the correlation between drop charge and drop diameter, with spray specific charge, injection velocity and orifice diameter all contributing to the shape of the drop diameter-charge distribution. Mean drop charge as a function of the Rayleigh limit is approximately 0.2, and is invariant with drop diameter and also across the spray cases tested. (orig.)

Estimation of the diameter-charge distribution in polydisperse electrically charged sprays of electrically insulating liquids

Science.gov (United States)

Rigit, A. R. H.; Shrimpton, John S.

2009-06-01

The majority of scientific and industrial electrical spray applications make use of sprays that contain a range of drop diameters. Indirect evidence suggests the mean drop diameter and the mean drop charge level are usually correlated. In addition, within each drop diameter class there is every reason to suspect a distribution of charge levels exist for a particular drop diameter class. This paper presents an experimental method that uses the joint PDF of drop velocity and diameter, obtained from phase Doppler anemometry measurements, and directly obtained spatially resolved distributions of the mass and charge flux to obtain a drop diameter and charge frequency distribution. The method is demonstrated using several data-sets obtained from experimental measurements of steady poly-disperse sprays of an electrically insulating liquid produced with the charge injection technique. The space charge repulsion in the spray plume produces a hollow cone spray structure. In addition an approximate self-similarity is observed, with the maximum radial mass and charge flow occurring at r/ d ~ 200. The charge flux profile is slightly offset from the mass flux profile, and this gives direct evidence that the spray specific charge increases from approximately 20% of the bulk mean spray specific charge on the spray axis to approximately 200% of the bulk mean specific charge in the periphery of the spray. The results from the drop charge estimation model suggest a complex picture of the correlation between drop charge and drop diameter, with spray specific charge, injection velocity and orifice diameter all contributing to the shape of the drop diameter-charge distribution. Mean drop charge as a function of the Rayleigh limit is approximately 0.2, and is invariant with drop diameter and also across the spray cases tested.

Production of cocrystals in an excipient matrix by spray drying.

Science.gov (United States)

Walsh, David; Serrano, Dolores R; Worku, Zelalem Ayenew; Norris, Brid A; Healy, Anne Marie

2018-01-30

Spray drying is a well-established scale-up technique for the production of cocrystals. However, to the best of our knowledge, the effect of introducing a third component into the feed solution during the spray drying process has never been investigated. Cocrystal formation in the presence of a third component by a one-step spray drying process has the potential to reduce the number of unit operations which are required to produce a final pharmaceutical product (e.g. by eliminating blending with excipient). Sulfadimidine (SDM), a poorly water soluble active pharmaceutical ingredient (API), and 4-aminosalicylic acid (4ASA), a hydrophilic molecule, were used as model drug and coformer respectively to form cocrystals by spray drying in the presence of a third component (excipient). The solubility of the cocrystal in the excipient was measured using a thermal analysis approach. Trends in measured solubility were in agreement with those determined by calculated Hansen Solubility Parameter (HSP) values. The ratio of cocrystal components to excipient was altered and cocrystal formation at different weight ratios was assessed. Cocrystal integrity was preserved when the cocrystal components were immiscible with the excipient, based on the difference in Hansen Solubility Parameters (HSP). For immiscible systems (difference in HSP > 9.6 MPa 0.5 ), cocrystal formation occurred even when the proportion of excipient was high (90% w/w). When the excipient was partly miscible with the cocrystal components, cocrystal formation was observed post spray drying, but crystalline API and coformer were also recovered in the processed powder. An amorphous dispersion was formed when the excipient was miscible with the cocrystal components even when the proportion of excipient used as low (10% w/w excipient). For selected spray dried cocrystal-excipient systems an improvement in tableting characteristics was observed, relative to equivalent physical mixtures. Copyright © 2017 Elsevier

LSPRAY-IV: A Lagrangian Spray Module

Science.gov (United States)

Raju, M. S.

2012-01-01

LSPRAY-IV is a Lagrangian spray solver developed for application with parallel computing and unstructured grids. It is designed to be massively parallel and could easily be coupled with any existing gas-phase flow and/or Monte Carlo Probability Density Function (PDF) solvers. The solver accommodates the use of an unstructured mesh with mixed elements of either triangular, quadrilateral, and/or tetrahedral type for the gas flow grid representation. It is mainly designed to predict the flow, thermal and transport properties of a rapidly vaporizing spray. Some important research areas covered as a part of the code development are: (1) the extension of combined CFD/scalar-Monte- Carlo-PDF method to spray modeling, (2) the multi-component liquid spray modeling, and (3) the assessment of various atomization models used in spray calculations. The current version contains the extension to the modeling of superheated sprays. The manual provides the user with an understanding of various models involved in the spray formulation, its code structure and solution algorithm, and various other issues related to parallelization and its coupling with other solvers.

Experimental and numerical investigations on spray characteristics of fatty acid methyl esters.

Science.gov (United States)

Lanjekar, R D; Deshmukh, D

2018-02-01

A comparative experimental and numerical study is conducted to establish the significance of the use of single-component over multi-component representatives of biodiesel, diesel and their blend for predicting spray tip penetration. Methyl oleate and methyl laurate are used as single-component representative fuels for biodiesel. The pure components n -heptane, n -dodecane and n -tetradecane are used as single-component representative fuels for diesel. Methyl laurate is found to represent biodiesel of coconut, whereas methyl oleate is found to represent biodiesel having high percentage of long-chain fatty acid esters. The spray tip penetration of methyl oleate is found to be in good agreement with the measured spray tip penetration of karanja biodiesel. The spray tip penetration prediction of n -heptane fuel is closely following diesel spray tip penetration along with that of n -tetradecane and n -dodecane. The study suggests that the knowledge of the single-component representatives of biodiesel, diesel and their blend is sufficient to predict the spray tip penetration of the corresponding biodiesel, diesel and their blend under non-evaporating environment.

Experimental and numerical investigations on spray characteristics of fatty acid methyl esters

Science.gov (United States)

Lanjekar, R. D.; Deshmukh, D.

2018-02-01

A comparative experimental and numerical study is conducted to establish the significance of the use of single-component over multi-component representatives of biodiesel, diesel and their blend for predicting spray tip penetration. Methyl oleate and methyl laurate are used as single-component representative fuels for biodiesel. The pure components n-heptane, n-dodecane and n-tetradecane are used as single-component representative fuels for diesel. Methyl laurate is found to represent biodiesel of coconut, whereas methyl oleate is found to represent biodiesel having high percentage of long-chain fatty acid esters. The spray tip penetration of methyl oleate is found to be in good agreement with the measured spray tip penetration of karanja biodiesel. The spray tip penetration prediction of n-heptane fuel is closely following diesel spray tip penetration along with that of n-tetradecane and n-dodecane. The study suggests that the knowledge of the single-component representatives of biodiesel, diesel and their blend is sufficient to predict the spray tip penetration of the corresponding biodiesel, diesel and their blend under non-evaporating environment.

Droplets and sprays

CERN Document Server

Sazhin, Sergei

2014-01-01

Providing a clear and systematic description of droplets and spray dynamic models, this book maximises reader insight into the underlying physics of the processes involved, outlines the development of new physical and mathematical models, and broadens understanding of interactions between the complex physical processes which take place in sprays. Complementing approaches based on the direct application of computational fluid dynamics (CFD), Droplets and Sprays treats both theoretical and practical aspects of internal combustion engine process such as the direct injection of liquid fuel, subcritical heating and evaporation. Includes case studies that illustrate the approaches relevance to automotive applications,  it is also anticipated that the described models can find use in other areas such as in medicine and environmental science.

Preparation and Characterization of Plasma-Sprayed Ultrafine Chromium Oxide Coatings

International Nuclear Information System (INIS)

Lin Feng; Jiang Xianliang; Yu Yueguang; Zeng Keli; Ren Xianjing; Li Zhenduo

2007-01-01

Ultrafine chromium oxide coatings were prepared by plasma spraying with ultrafine feedstock. Processing parameters of plasma spraying were optimized. Optical microscope (OM) was used to observe the microstructure of the ultrafine chromium oxide coatings. Scanning electron microscopy (SEM) was used to observe the morphology and particle size of ultrafine powder feedstock as well as to examine the microstructure of the chromium oxide coating. In addition, hardness and bonding strength of the ultrafine chromium oxide coatings were measured. The results showed that the optimized plasma spraying parameters were suitable for ultrafine chromium oxide coating and the properties and microstructure of the optimized ultrafine chromium oxide coating were superior compared to conventional chromium oxide wear resistant coatings

COUPLED ATOMIZATION AND SPRAY MODELLING IN THE SPRAY FORMING PROCESS USING OPENFOAM

DEFF Research Database (Denmark)

Gjesing, Rasmus; Hattel, Jesper Henri; Fritsching, Udo

2009-01-01

The paper presents a numerical model capable of simulating the atomization, break-up and in-flight spray phenomena in the spray forming process. The model is developed and implemented in the freeware code openFOAM. The focus is on studying the coupling effect of the melt break-up phenomena...

Investigation on the suitability of plasma sprayed Fe-Cr-Al coatings as tritium permeation barrier

International Nuclear Information System (INIS)

Fazio, C.; Serra, E.; Benamati, G.

1999-01-01

Results on the fabrication of a tritium permeation barrier by spraying Fe-Cr-Al powders are described. The sprayed coatings were deposited at temperatures below the A c1 temperature of the ferritic-martensitic steel substrate and no post-deposition heat treatment was applied. The aim of the investigation was the determination of the efficiency of the coatings to act as tritium permeation barrier. Metallurgical investigations as well as hydrogen isotope permeation measurements were carried out onto the produced coatings. The depositions were performed on ferritic-martensitic steels by means of three types of spray techniques: high velocity oxy fuel, air plasma spray and vacuum plasma spray. (orig.)

Head spray nozzle in reactor pressure vessel

International Nuclear Information System (INIS)

Hatano, Shun-ichi.

1990-01-01

In a reactor pressure vessel of a BWR type reactor, a head spray nozzle is used for cooling the head of the pressure vessel and, in view of the thermal stresses, it is desirable that cooling is applied as uniformly as possible. A conventional head spray is constituted by combining full cone type nozzles. Since the sprayed water is flown down upon water spraying and the sprayed water in the vertical direction is overlapped, the flow rate distribution has a high sharpness to form a shape as having a maximum value near the center and it is difficult to obtain a uniform flow rate distribution in the circumferential direction. Then, in the present invention, flat nozzles each having a spray water cross section of laterally long shape, having less sharpness in the circumferential distribution upon spraying water to the inner wall of the pressure vessel and having a wide angle of water spray are combined, to make the flow rate distribution of spray water uniform in the inner wall of the pressure vessel. Accordingly, the pressure vessel can be cooled uniformly and thermal stresses upon cooling can be decreased. (N.H.)

Droplet size measurement of diesel fuel spray particles using a planar laser-induced fluorescence method; Nijigen laser yuki keikoho wo mochiita diesel funmu ryushi no ryukei keisoku ni kansuru kenkyu

Energy Technology Data Exchange (ETDEWEB)

Ishikawa, N. [Isuzu Motors Ltd., Tokyo (Japan); Niimura, K. [Nissan Diesel Motor Co. Ltd., Saitama (Japan); Tsujimura, K.

1997-11-25

In this study, the planar laser-induced fluorescence (PLIF) technique was used to measure the mean size and size distribution of diesel spray particles. The fuel used was n-tridecane mixed with 1 wt% N, N, Nprime, Nprime-tetramethylparaphenyenediamine (TMPD). The light source used to excite the TMPD in the fuel was a secondary harmonic of a ruby laser-light sheet. A highly magnified image of the fluorescence from TMPD was taken by a 35 mm still camera with magnified optics, and the mean particle size and particle size distribution of the fuel spray were determined by processing the images of fuel particles printed on paper. First, the accuracy of this method was confirmed by comparison with results of Phase Doppler Anemometry for fuel spray of an air-assisted gasoline injector. Then, for the diesel spray, the effects of injection velocity, ambient pressure, geometric configuration of nozzle hole (i.e., nozzle hole diameter and nozzle hole L/D) and of measurement points on the fuel particle mean size and size distribution in a high-pressure vessel at atmospheric temperature were investigated. The results showed that the small size particles increase in number with increasing injection velocity. At higher injection velocity, seem to atomize more actively. With increasing ambient pressure, the mean particle size increases. A reduction in nozzle diameter resulted in no improvement of atomization in this study. Also, the mean particle size in the downstream region of the spray is larger than that in the upstream region of the spray. 16 refs., 19 figs., 3 tabs.

Multiple-Nozzle Spray Head Applies Foam Insulation

Science.gov (United States)

Walls, Joe T.

1993-01-01

Spray head equipped with four-nozzle turret mixes two reactive components of polyurethane and polyisocyanurate foam insulating material and sprays reacting mixture onto surface to be insulated. If nozzle in use becomes clogged, fresh one automatically rotated into position, with minimal interruption of spraying process. Incorporates features recirculating and controlling pressures of reactive components to maintain quality of foam by ensuring proper blend at outset. Also used to spray protective coats on or in ships, aircraft, and pipelines. Sprays such reactive adhesives as epoxy/polyurethane mixtures. Components of spray contain solid-particle fillers for strength, fire retardance, toughness, resistance to abrasion, or radar absorption.

Gas entrainment by one single French PWR spray, SARNET-2 spray benchmark

Energy Technology Data Exchange (ETDEWEB)

Malet, J., E-mail: jeanne.malet@irsn.fr [Institut de Radioprotection et de Sûreté Nucléaire, Saclay (France); Mimouni, S., E-mail: stephane.mimouni@edf.fr [Electricité de France, EDF MF2E, Chatou (France); Manzini, G., E-mail: giovanni.manzini@rse-web.it [RSE, Milano (Italy); Xiao, J., E-mail: jianjun.xiao@kit.edu [IKET, KIT, Karlsruhe (Germany); Vyskocil, L., E-mail: vyl@ujv.cz [UJV Rez (Czech Republic); Siccama, N.B., E-mail: siccama@nrg.eu [NRG, Safety and Power (Netherlands); Huhtanen, R., E-mail: risto.huhtanen@vtt.fi [VTT, PO Box 1000, FI-02044 VTT (Finland)

2015-02-15

Highlights: • This paper presents a benchmark performed in the frame of the SARNET-2 EU project. • It concerns momentum transfer between a PWR spray and the surrounding gas. • The entrained gas velocities can vary up to 100% from one code to another. • Simplified boundary conditions for sprays are generally used by the code users. • It is shown how these simplified conditions impact the gas entrainment. - Abstract: This paper presents a benchmark performed in the frame of the SARNET-2 EU project, dealing with momentum transfer between a real-scale PWR spray and the surrounding gas. It presents a description of the IRSN tests on the CALIST facility, the participating codes (8 contributions), code-experiment and code-to-code comparisons. It is found that droplet velocities are almost well calculated one meter below the spray nozzle, even if the spread of the spray is not recovered and the values of the entrained gas velocity vary up to 100% from one code to another. Concerning sensitivity analysis, several ‘simplifications’ have been made by the contributors, especially based on the boundary conditions applied at the location where droplets are injected. It is shown here that such simplifications influence droplet and entrained gas characteristics. The next step will be to translate these conclusions in terms of variables representative of interesting parameters for nuclear safety.

Gas entrainment by one single French PWR spray, SARNET-2 spray benchmark

International Nuclear Information System (INIS)

Malet, J.; Mimouni, S.; Manzini, G.; Xiao, J.; Vyskocil, L.; Siccama, N.B.; Huhtanen, R.

2015-01-01

Highlights: • This paper presents a benchmark performed in the frame of the SARNET-2 EU project. • It concerns momentum transfer between a PWR spray and the surrounding gas. • The entrained gas velocities can vary up to 100% from one code to another. • Simplified boundary conditions for sprays are generally used by the code users. • It is shown how these simplified conditions impact the gas entrainment. - Abstract: This paper presents a benchmark performed in the frame of the SARNET-2 EU project, dealing with momentum transfer between a real-scale PWR spray and the surrounding gas. It presents a description of the IRSN tests on the CALIST facility, the participating codes (8 contributions), code-experiment and code-to-code comparisons. It is found that droplet velocities are almost well calculated one meter below the spray nozzle, even if the spread of the spray is not recovered and the values of the entrained gas velocity vary up to 100% from one code to another. Concerning sensitivity analysis, several ‘simplifications’ have been made by the contributors, especially based on the boundary conditions applied at the location where droplets are injected. It is shown here that such simplifications influence droplet and entrained gas characteristics. The next step will be to translate these conclusions in terms of variables representative of interesting parameters for nuclear safety

14 CFR 23.239 - Spray characteristics.

Science.gov (United States)

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Spray characteristics. 23.239 Section 23.239 Aeronautics and Space FEDERAL AVIATION ADMINISTRATION, DEPARTMENT OF TRANSPORTATION AIRCRAFT... Handling Characteristics § 23.239 Spray characteristics. Spray may not dangerously obscure the vision of...

14 CFR 29.239 - Spray characteristics.

Science.gov (United States)

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Spray characteristics. 29.239 Section 29... AIRWORTHINESS STANDARDS: TRANSPORT CATEGORY ROTORCRAFT Flight Ground and Water Handling Characteristics § 29.239 Spray characteristics. If certification for water operation is requested, no spray characteristics...

14 CFR 27.239 - Spray characteristics.

Science.gov (United States)

2010-01-01

... 14 Aeronautics and Space 1 2010-01-01 2010-01-01 false Spray characteristics. 27.239 Section 27... AIRWORTHINESS STANDARDS: NORMAL CATEGORY ROTORCRAFT Flight Ground and Water Handling Characteristics § 27.239 Spray characteristics. If certification for water operation is requested, no spray characteristics...

A comparison of biological effect and spray liquid distribution and deposition for different spray application techniques in different crops

OpenAIRE

Larsolle, Anders; Wretblad, Per; Westberg, Carl

2002-01-01

The objective of this study was to compare a selection of spray application techniques with different application volumes, with respect to the spray liquid distribution on flat surfaces, the deposition in fully developed crops and the biological effect. The spray application techniques in this study were conventional spray technique with three different nozzles: Teelet XR, Lechler ID and Lurmark DriftBeta, and also AirTec, Danfoil, Hardi Twin, Kyndestoit and Släpduk. The dynamic spray liquid ...

Transient analysis of intermittent multijet sprays

Energy Technology Data Exchange (ETDEWEB)

Panao, Miguel R.O.; Moreira, Antonio Luis N. [Universidade Tecnica de Lisboa, IN, Center for Innovation, Technology and Policy Research, Instituto Superior Tecnico, Lisboa (Portugal); Durao, Diamantino G. [Universidade Lusiada, Lisboa (Portugal)

2012-07-15

This paper analyzes the transient characteristics of intermittent sprays produced by the single-point impact of multiple cylindrical jets. The aim is to perform a transient analysis of the intermittent atomization process to study the effect of varying the number of impinging jets in the hydrodynamic mechanisms of droplet formation. The results evidence that hydrodynamic mechanisms underlying the physics of ligament fragmentation in 2-impinging jets sprays also apply to sprays produced with more than 2 jets during the main period of injection. Ligaments detaching from the liquid sheet, as well as from its bounding rim, have been identified and associated with distinct droplet clusters, which become more evident as the number of impinging jets increases. Droplets produced by detached ligaments constitute the main spray, and their axial velocity becomes more uniformly distributed with 4-impinging jets because of a delayed ligament fragmentation. Multijet spray dispersion patterns are geometric depending on the number of impinging jets. Finally, an analysis on the Weber number of droplets suggests that multijet sprays are more likely to deposit on interposed surfaces, thus becoming a promising and competitive atomization solution for improving spray cooling. (orig.)

Sprayed films of europium complexes toward light conversion devices

Energy Technology Data Exchange (ETDEWEB)

Camacho, Sabrina A.; Aoki, Pedro H.B.; Constantino, Carlos J.L.; Pires, Ana Maria, E-mail: anapires@fct.unesp.br

2014-09-15

Rare-earth complexes have become subject of intensive research due to the high quantum efficiency of their emission, very narrow bands, and excellent fluorescence monochromaticity. The chemical design and characterization of Eu complexes based on β-diketone ligands hexafluoroacetylacetate (hfac) and dibenzoylmetanate (dbm) is reported here. K[Eu(dbm){sub 4}] and K[Eu(hfac){sub 4}] complexes were immobilized as thin films by using the spray technique, a promising methodology for practical applications. The latter provides not only a faster layer deposition but also larger coated areas compared to conventional methods, such as layer-by-layer (LbL) and Langmuir–Blodgett (LB). The growth of the sprayed films was monitored through microbalance (QCM) and ultraviolet–visible (UV–Vis) absorption spectroscopy, which reveal a higher mass and absorbance per deposited layer of K[Eu(dbm){sub 4}] film. Micro-Raman images display a more homogeneous spatial distribution of the K[Eu(dbm){sub 4}] complex throughout the film, when compared to K[Eu(hfac){sub 4}] film. At nanometer scale, atomic force microscopy (AFM) images indicate that the roughness of the K[Eu(hfac){sub 4}] film is approximately one order of magnitude higher than that for the K[Eu(dbm){sub 4}] film, which pattern is kept at micrometer scale according to micro-Raman measurements. The photoluminescence data show that the complexes remain as pure red emitters upon spray immobilization. Besides, the quantum efficiency for the sprayed films are found equivalent to the values achieved for the powders, highlighting the potential of the films for application in light conversion devices. - Highlights: • Rare earth complexes thin films based on β-diketone ligands. • Spraying procedures to fabricate layer-by-layer (LbL) luminescent thin films. • Chemical design of Eu complexes based on hfac and dbm β-diketones ligands immobilized as sprayed films. • Pure red emitters upon spray immobilization. • Sprayed

Macro controlling of copper oxide deposition processes and spray mode by using home-made fully computerized spray pyrolysis system

Science.gov (United States)

Essa, Mohammed Sh.; Chiad, Bahaa T.; Shafeeq, Omer Sh.

2017-09-01

Thin Films of Copper Oxide (CuO) absorption layer have been deposited using home-made Fully Computerized Spray Pyrolysis Deposition system FCSPD on glass substrates, at the nozzle to substrate distance equal to 20,35 cm, and computerized spray mode (continues spray, macro-control spray). The substrate temperature has been kept at 450 °c with the optional user can enter temperature tolerance values ± 5 °C. Also that fixed molar concentration of 0.1 M, and 2D platform speed or deposition platform speed of 4mm/s. more than 1000 instruction program code, and specific design of graphical user interface GUI to fully control the deposition process and real-time monitoring and controlling the deposition temperature at every 200 ms. The changing in the temperature has been recorded during deposition processes, in addition to all deposition parameters. The films have been characterized to evaluate the thermal distribution over the X, Y movable hot plate, the structure and optical energy gap, thermal and temperature distribution exhibited a good and uniform distribution over 20 cm2 hot plate area, X-ray diffraction (XRD) measurement revealed that the films are polycrystalline in nature and can be assigned to monoclinic CuO structure. Optical band gap varies from 1.5-1.66 eV depending on deposition parameter.

Effectiveness of containment sprays in containment management

International Nuclear Information System (INIS)

Nourbakhsh, H.P.; Perez, S.E.; Lehner, J.R.

1993-05-01

A limited study has been performed assessing the effectiveness of containment sprays-to mitigate particular challenges which may occur during a severe accident. Certain aspects of three specific topics related to using sprays under severe accident conditions were investigated. The first was the effectiveness of sprays connected to an alternate water supple and pumping source because the actual containment spray pumps are inoperable. This situation could occur during a station blackout. The second topic concerned the adverse as well as beneficial effects of using containment sprays during severe accident scenario where the containment atmosphere contains substantial quantities of hydrogen along with steam. The third topic was the feasibility of using containment sprays to moderate the consequences of DCH

Spray-on polyvinyl alcohol separators and impact on power production in air-cathode microbial fuel cells with different solution conductivities

KAUST Repository

Hoskins, Daniel L.

2014-11-01

© 2014 Elsevier Ltd. Separators are used to protect cathodes from biofouling and to avoid electrode short-circuiting, but they can adversely affect microbial fuel cell (MFC) performance. A spray method was used to apply a polyvinyl alcohol (PVA) separator to the cathode. Power densities were unaffected by the PVA separator (339 ± 29 mW/m2), compared to a control lacking a separator in a low conductivity solution (1mS/cm) similar to wastewater. Power was reduced with separators in solutions typical of laboratory tests (7-13 mS/cm), compared to separatorless controls. The PVA separator produced more power in a separator assembly (SEA) configuration (444 ± 8 mW/m2) in the 1mS/cm solution, but power was reduced if a PVA or wipe separator was used in higher conductivity solutions with either Pt or activated carbon catalysts. Spray and cast PVA separators performed similarly, but the spray method is preferred as it was easier to apply and use.

Preparation of cellulose based microspheres by combining spray coagulating with spray drying.

Science.gov (United States)

Wang, Qiao; Fu, Aiping; Li, Hongliang; Liu, Jingquan; Guo, Peizhi; Zhao, Xiu Song; Xia, Lin Hua

2014-10-13

Porous microspheres of regenerated cellulose with size in range of 1-2 μm and composite microspheres of chitosan coated cellulose with size of 1-3 μm were obtained through a two-step spray-assisted approach. The spray coagulating process must combine with a spray drying step to guarantee the formation of stable microspheres of cellulose. This approach exhibits the following two main virtues. First, the preparation was performed using aqueous solution of cellulose as precursor in the absence of organic solvent and surfactant; Second, neither crosslinking agent nor separated crosslinking process was required for formation of stable microspheres. Moreover, the spray drying step also provided us with the chance to encapsulate guests into the resultant cellulose microspheres. The potential application of the cellulose microspheres acting as drug delivery vector has been studied in two PBS (phosphate-buffered saline) solution with pH values at 4.0 and 7.4 to mimic the environments of stomach and intestine, respectively. Copyright © 2014 Elsevier Ltd. All rights reserved.

Measurement of the sea surface wind speed and direction by an airborne microwave radar altimeter

Energy Technology Data Exchange (ETDEWEB)

Nekrassov, A. [GKSS-Forschungszentrum Geesthacht GmbH (Germany). Inst. fuer Hydrophysik

2001-07-01

A pilot needs operational information about wind over sea as well as wave height to provide safety of a hydroplane landing on water. Near-surface wind speed and direction can be obtained with an airborne microwave scatterometer, radar designed for measuring the scatter characteristics of a surface. Mostly narrow-beam antennas are applied for such wind measurement. Unfortunately, a microwave narrow-beam antenna has considerable size that hampers its placing on flying apparatus. In this connection, a possibility to apply a conventional airborne radar altimeter as a scatterometer with a nadir-looking wide-beam antenna in conjunction with Doppler filtering for recovering the wind vector over sea is discussed, and measuring algorithms of sea surface wind speed and direction are proposed. The obtained results can be used for creation of an airborne radar system for operational measurement of the sea roughness characteristics and for safe landing of a hydroplane on water. (orig.)

Spray structure of a pressure-swirl atomizer for combustion applications

OpenAIRE

Jicha Miroslav; Jedelsky Jan; Durdina Lukas

2012-01-01

In the present work, global as well as spatially resolved parameters of a spray produced by a pressure-swirl atomizer are obtained. Small pressure-swirl atomizer for aircraft combustion chambers was run on a newly designed test bench with Jet A-1 kerosene type aviation fuel. The atomizer was tested in four regimes based on typical operation conditions of the engine. Spray characteristics were studied using two optical measurement systems, Particle Image velocimetry (PIV) and Phase-Doppler Par...

Photoluminescence of spray pyrolysis deposited ZnO nanorods

Directory of Open Access Journals (Sweden)

Mikli Valdek

2011-01-01

Full Text Available Abstract Photoluminescence of highly structured ZnO layers comprising well-shaped hexagonal rods is presented. The ZnO rods (length 500-1,000 nm, diameter 100-300 nm were grown in air onto a preheated soda-lime glass (SGL or ITO/SGL substrate by low-cost chemical spray pyrolysis method using zinc chloride precursor solutions and growth temperatures in the range of 450-550°C. We report the effect of the variation in deposition parameters (substrate type, growth temperature, spray rate, solvent type on the photoluminescence properties of the spray-deposited ZnO nanorods. A dominant near band edge (NBE emission is observed at 300 K and at 10 K. High-resolution photoluminescence measurements at 10 K reveal fine structure of the NBE band with the dominant peaks related to the bound exciton transitions. It is found that all studied technological parameters affect the excitonic photoluminescence in ZnO nanorods. PACS: 78.55.Et, 81.15.Rs, 61.46.Km

An evaluation of the electric arc spray and (HPPS) processes for the manufacturing of high power plasma spraying MCrAIY coatings

Science.gov (United States)

Sacriste, D.; Goubot, N.; Dhers, J.; Ducos, M.; Vardelle, A.

2001-06-01

The high power plasma torch (PlazJet) can be used to spray refractory ceramics with high spray rates and deposition efficiency. It can provide dense and hard coating with high bond strengths. When manufacturing thermal barrier coatings, the PlazJet gun is well adapted to spraying the ceramic top coat but not the MCrAIY materials that are used as bond coat. Arc spraying can compete with plasma spraying for metallic coatings since cored wires can be used to spray alloys and composites. In addition, the high production rate of arc spraying enables a significant decrease in coating cost. This paper discusses the performances of the PlazJet gun, and a twin-wire are spray system, and compares the properties and cost of MCrAIY coatings made with these two processes. For arc spraying, the use of air or nitrogen as atomizing gas is also investigated.

Arctic ice island and sea ice movements and mechanical properties. First quarterly report, October 1-December 31, 1983

Energy Technology Data Exchange (ETDEWEB)

Sackinger, W.M.; Stringer, W.J.

1984-01-01

Research activities for the first quarter are presented for the following tasks: (1) ice island; (2) intrusion of the pack ice edge in the Chukchi Sea; and (3) spray ice adhesion to offshore structure coatings. With respect to the ice island portion of this project the following activities are planned for the year: (1) use aerial photography, satellite imagery, and all available historical records to establish a time history of all of the ice shelves of Ellesmere Island; (2) establish positioning buoys on the existing ice islands to track their trajectories daily and to telemeter daily barometric pressure and temperature, via System Argos; (3) relate geostrophic winds to the observed trajectories; (4) begin to build a pseudo-random model for ice island motion over the long term which would enable a determination of the probability of interaction between ice islands and offshore structures. The overall objective of task 2 is to investigate and analyze the causes and extent of summer time pace ice intrusions into the Chukchi Sea, which would interfere with exploration drilling and emplacement of permanent production structures. For task three a method for evaluating shear and tensile strengths of the interface bond between the sea spray ice layer and the structure or ship surface will be developed. A second more detailed task is to then measure the mechanical properties of this bonded layer for a variety of candidate coatings, as functions of temperature, loading rate, strain rate, salinity, and ice type. 25 references, 92 figures.

Thermal spray deposition and evaluation of low-Z coatings

International Nuclear Information System (INIS)

Seals, R.D.; Swindeman, C.J.; White, R.L.

1996-01-01

Thermally sprayed low-Z coatings of B 4 C on Al substrates were investigated as candidate materials for first-wall reactor protective surfaces. Comparisons were made to thermally sprayed coatings of B, MgAl 2 O 4 , Al 2 O 3 , and composites. Graded bond layers were applied to mitigate coefficient of thermal expansion mismatch. Microstructures, thermal diffusivity before and after thermal shock loading, steel ball impact resistance, CO 2 pellet cleaning and erosion tolerance, phase content, stoichiometry by Rutherford backscattering spectroscopy, and relative tensile strengths were measured

ROTARY SPRAY DUSTER

Directory of Open Access Journals (Sweden)

E. S. Nechaeva

2013-01-01

Full Text Available Results of researches of hydraulic resistance, ablation of splashes and efficiency of dedusting in the rotor spray dust collector are given. Influence of frequency of rotation of the spray, the specified speed of gas and diameter of spattering holes on hydraulic resistance, size ablation of splashes and efficiency of a dedusting the device by diameter 0,25 m is investigated. As model liquid water is used. Results of mathematical processing are presented.

Studies on Microscopic Structure of Diesel Sprays under Atmospheric and High Gas Pressures

Directory of Open Access Journals (Sweden)

D. Deshmukh

2014-06-01

Full Text Available In the present work, the spray structure of diesel from a 200-μm, single-hole solenoid injector is studied using microscopic imaging at injection pressures of 700, 1000 and 1400 bar for various gas pressures. A long-distance microscope with a high resolution camera is used for spray visualization with a direct imaging technique. This study shows that even at very high injection pressures, the spray structure in an ambient environment of atmospheric pressure reveals presence of entangled ligaments and non-spherical droplets during the injection period. With increase in the injection pressure, the ligaments tend to get smaller and spread radially. The spray structure studies are also conducted at high gas pressures in a specially designed high pressure chamber with optical access. The near nozzle spray structure at the end of the injection shows that the liquid jet breakup is improved with increase in gas density. The droplet size measurement is possible only late in the injection duration when the breakup appears to be complete and mostly spherical droplets are observed. Hence, droplet size measurements are performed after 1.3 ms from start of the injection pulse. Spatial and temporal variation in Sauter Mean Diameter (SMD is observed and reported for the case corresponding to an injection pressure of 700 bar. Overall, this study has highlighted the importance of verifying the extentof atomization and droplet shape even in dense sprays before using conventional dropsizing methods such as PDPA.

Characteristics of spray from a GDI fuel injector for naphtha and surrogate fuels

KAUST Repository

Wang, Libing

2016-11-18

Characterization of the spray angle, penetration, and droplet size distribution is important to analyze the spray and atomization quality. In this paper, the spray structure development and atomization characterization of two naphtha fuels, namely light naphtha (LN) and whole naphtha (WN) and two reference fuel surrogates, i.e. toluene primary reference fuel (TPRF) and primary reference fuel (PRF) were investigated using a gasoline direct injection (GDI) fuel injector. The experimental setup included a fuel injection system, a high-speed imaging system, and a droplet size measurement system. Spray images were taken by using a high-speed camera for spray angle and penetration analysis. Sauter mean diameter, Dv(10), Dv(50), Dv(90), and particle size distribution were measured using a laser diffraction technique. Results show that the injection process is very consistent for different runs and the time averaged spray angles during the measuring period are 103.45°, 102.84°, 102.46° and 107.61° for LN, WN, TPRF and PRF, respectively. The spray front remains relatively flat during the early stage of the fuel injection process. The peak penetration velocities are 80 m/s, 75 m/s, 75 m/s and 79 m/s for LN, WN, TPRF and PRF, respectively. Then velocities decrease until the end of the injection and stay relatively stable. The transient particle size and the time-averaged particle size were also analyzed and discussed. The concentration weighted average value generally shows higher values than the arithmetic average results. The average data for WN is usually the second smallest except for Dv90, of which WN is the biggest. Generally the arithmetic average particle sizes of PRF are usually the smallest, and the sizes does not change much with the measuring locations. For droplet size distribution results, LN and WN show bimodal distributions for all the locations while TPRF and PRF shows both bimodal and single peak distribution patterns. The results imply that droplet size

On the modeling of fuel sprays

Energy Technology Data Exchange (ETDEWEB)

Bergstroem, Christer

1997-12-01

This report concerns on the modelling of fuel sprays in a non-combustible case using an own developed fuel spray code module. The spray code is made as an independent module to simplify the use of different gas flow solvers together with the spray module. This enables the possibility to use different turbulence models. In the report two turbulence models has been used, the standard k-{epsilon} and the LES (Large Eddy Simulation) model. The report presents results obtained from a sensitivity study of both numerical and physical parameters on an evaporating spray under diesel like conditions (light duty diesel engine) with the spray code module attached to a cylindrical gas phase flow solver. The results from the sensitivity analysis showed that these effects were not so pronounced as has been reported. It was suggested that this was due to the `easy` nature of the investigated case, where the flow field could be sufficiently resolved without violating the droplet void fraction criteria and break-up, collision and combustion that may increase the grid spacing sensitivity were not modelled. An investigation was performed to valuate the feasibility of using LES as turbulence model. Calculations of the initial phase of a developing jet were made and it was found that in the initial phase of the spray and the flow structure were similar to that of a spatially developing jet flow, which is in agreement with experimental observations. Results from LES calculations on a developing spray jet was also compared with k-{epsilon} based ones. This result showed that the spray-LES approach captured the transition from a laminar to a turbulent flow field with an increase in turbulent kinetic energy k along the injection direction 45 refs, 37 figs, 2 tabs

Radio-frequency plasma spraying of ceramics

International Nuclear Information System (INIS)

Okada, T.; Hamatani, H.; Yoshida, T.

1989-01-01

This study was aimed at developing a novel spraying process using a radio-frequency (rf) plasma. Experiments of Al 2 O 3 and ZrO 2 - 8 wt% Y 2 O 3 spraying showed that the initial powder size was the most important parameter for depositing dense coatings. The optimum powder sizes of Al 2 O 3 and ZrO 2 - 8 wt% Y 2 O 3 were considered to be around 100 and 80 μm, respectively. The use of such large-size powders compared with those used by conventional dc plasma spraying made it possible to deposit adherent ceramics coatings of 150 to 300 μm on as-rolled SS304 substrates. It was also shown that low particle velocity of about 10 m/s, which is peculiar to rf plasma spraying, was sufficient for particle deformation, though it imposed a severe limitation on the substrate position. These experimental results prove that rf plasma spraying is an effective process and a strong candidate to open new fields of spraying applications

The influence of spill-line geometry on a spray generated by a pressure-swirl atomizer

Directory of Open Access Journals (Sweden)

Malý Milan

2016-01-01

Full Text Available An experimental investigation of characteristics of spray generated by a pressure-swirl atomizer (spill-return type was performed using shadowgraphy and Phase-Doppler Anemometry (PDA. Several different geometries of the spill-return orifice were tested in terms of a spray stability and quality on a cold test bench. PDA measurement yields a drop-size distribution and velocity data while the shadowgraphy unveils a break-up process in detail. Performed measurements reveal significant differences in spray characteristics as well as differences in spray stability. The results suggest that the air core, formed inside the swirl chamber, passes through the spill orifice, which causes instability of the inner flow. These instabilities lead to a chaotic state of sheet breakup resulting in shortening of breakup distance. Obtained findings are used to propose possible changes in the atomizer design for improvement of its performance.

The influence of spill-line geometry on a spray generated by a pressure-swirl atomizer

Science.gov (United States)

Malý, Milan; Janáčková, Lada; Jedelský, Jan; Jícha, Miroslav

2016-03-01

An experimental investigation of characteristics of spray generated by a pressure-swirl atomizer (spill-return type) was performed using shadowgraphy and Phase-Doppler Anemometry (PDA). Several different geometries of the spill-return orifice were tested in terms of a spray stability and quality on a cold test bench. PDA measurement yields a drop-size distribution and velocity data while the shadowgraphy unveils a break-up process in detail. Performed measurements reveal significant differences in spray characteristics as well as differences in spray stability. The results suggest that the air core, formed inside the swirl chamber, passes through the spill orifice, which causes instability of the inner flow. These instabilities lead to a chaotic state of sheet breakup resulting in shortening of breakup distance. Obtained findings are used to propose possible changes in the atomizer design for improvement of its performance.

Large Eddy Simulation of the spray formation in confinements

International Nuclear Information System (INIS)

Lampa, A.; Fritsching, U.

2013-01-01

Highlights: • Process stability of confined spray processes is affected by the geometric design of the spray confinement. • LES simulations of confined spray flow have been performed successfully. • Clustering processes of droplets is predicted in simulations and validated with experiments. • Criteria for specific coherent gas flow patterns and droplet clustering behaviour are found. -- Abstract: The particle and powder properties produced within spray drying processes are influenced by various unsteady transport phenomena in the dispersed multiphase spray flow in a confined spray chamber. In this context differently scaled spray structures in a confined spray environment have been analyzed in experiments and numerical simulations. The experimental investigations have been carried out with Particle-Image-Velocimetry to determine the velocity of the gas and the discrete phase. Large-Eddy-Simulations have been set up to predict the transient behaviour of the spray process and have given more insight into the sensitivity of the spray flow structures in dependency from the spray chamber design

Measuring sea surface height with a GNSS-Wave Glider

Science.gov (United States)

Morales Maqueda, Miguel Angel; Penna, Nigel T.; Foden, Peter R.; Martin, Ian; Cipollini, Paolo; Williams, Simon D.; Pugh, Jeff P.

2017-04-01

A GNSS-Wave Glider is a novel technique to measure sea surface height autonomously using the Global Navigation Satellite System (GNSS). It consists of an unmanned surface vehicle manufactured by Liquid Robotics, a Wave Glider, and a geodetic-grade GNSS antenna-receiver system, with the antenna installed on a mast on the vehicle's deck. The Wave Glider uses the differential wave motion through the water column for propulsion, thus guaranteeing an, in principle, indefinite autonomy. Solar energy is collected to power all on-board instrumentation, including the GNSS system. The GNSS-Wave Glider was first tested in Loch Ness in 2013, demonstrating that the technology is capable of mapping geoid heights within the loch with an accuracy of a few centimetres. The trial in Loch Ness did not conclusively confirm the reliability of the technique because, during the tests, the state of the water surface was much more benign than would normally be expect in the open ocean. We now report on a first deployment of a GNSS-Wave Glider in the North Sea. The deployment took place in August 2016 and lasted thirteen days, during which the vehicle covered a distance of about 350 nautical miles in the north western North Sea off Great Britain. During the experiment, the GNSS-Wave Glider experienced sea states between 1 (0-0.1 m wave heights) and 5 (2.5-4 m wave heights). The GNSS-Wave Glider data, recorded at 5 Hz frequency, were analysed using a post-processed kinematic GPS-GLONASS precise point positioning (PPP) approach, which were quality controlled using double difference GPS kinematic processing with respect to onshore reference stations. Filtered with a 900 s moving-average window, the PPP heights reveal geoid patterns in the survey area that are very similar to the EGM2008 geoid model, thus demonstrating the potential use of a GNSS-Wave Glider for marine geoid determination. The residual of subtracting the modelled or measured marine geoid from the PPP signal combines information

Spray Formation of Herschel-Bulkley Fluids using Impinging Jets

Science.gov (United States)

Rodrigues, Neil; Gao, Jian; Chen, Jun; Sojka, Paul E.

2015-11-01

The impinging jet spray formation of two non-Newtonian, shear-thinning, Herschel-Bulkley fluids was investigated in this work. The water-based gelled solutions used were 1.0 wt.-% agar and 1.0 wt.-% kappa carrageenan. A rotational rheometer and a capillary viscometer were used to measure the strain-rate dependency of viscosity and the Herschel-Bulkley Extended (HBE) rheological model was used to characterize the shear-thinning behavior. A generalized HBE jet Reynolds number Rej , gen - HBE was used as the primary parameter to characterize the spray formation. A like-on-like impinging jet doublet was used to produce atomization. Shadowgraphs were captured in the plane of the sheet formed by the two jets using a CCD camera with an Nd:YAG laser beam providing the back-illumination. Typical behavior for impinging jet atomization using Newtonian liquids was not generally observed due to the non-Newtonian, viscous properties of the agar and kappa carrageenan gels. Instead various spray patterns were observed depending on Rej , gen - HBE. Spray characteristics of maximum instability wavelength and sheet breakup length were extracted from the shadowgraphs. Multi-University Research Initiative Grant Number W911NF-08-1-0171.

Characterization of Liquid Fuel Evaporation of a Lifted Methanol Spray Flame in a Vitiated Coflow Burner

Science.gov (United States)

Cabra, Ricardo; Dibble, Robert W.; Chen, Jyh-Yuan

2002-01-01

An experimental investigation of lifted spray flames in a coflow of hot, vitiated gases is presented. The vitiated coflow burner is a spray flame that issues into a coaxial flow of hot combustion products from a lean, premixed H2/Air flame. The spray flame in a vitiated coflow emulates the combustion that occurs in many advanced combustors without the detailed fluid mechanics. Two commercially available laser diagnostic systems are used to characterize the spray flame and to demonstrate the vitiated coflow burner's amenability to optical investigation. The Ensemble Particle Concentration and Size (EPCS) system is used to measure the path-average droplet size distribution and liquid volume fraction at several axial locations while an extractive probe instrument named the Real-time Fuel-air Analyzer (RFA) is used to measure the air to fuel ratio downstream of the spray nozzle with high temporal and spatial resolution. The effect of coflow conditions (stoichiometry) and dilution of the fuel with water was studied with the EPCS optical system. As expected, results show that water retards the evaporation and combustion of fuels. Measurements obtained by the RFA extractive probe show that while the Delavan manufactured nozzle does distribute the fuel over the manufacturer specified spray angle, it unfortunately does not distribute the fuel uniformly, providing conditions that may result in the production of unwanted NOx. Despite some limitations due to the inherent nature of the experimental techniques, the two diagnostics can be readily applied to spray flames in the vitiated coflow environment.

Optical measurements in the North Sea-Baltic Sea transition zone. I. On the origin of the deep water in the Kattegat

Science.gov (United States)

Højerslev, N. K.; Holt, N.; Aarup, T.

1996-08-01

In the North Sea-Baltic Sea region, several studies have shown that yellow substance can be treated as a quasi-conservative parameter that is negatively correlated with salinity. A review of more than 5000 historic and recently gathered yellow substance absorption and salinity measurements from the transition zone between the North Sea and the Baltic Sea have been analyzed for the purpose of water mass identification. Salinity-yellow substance scatter plots show that three water masses can be identified in the area: (1) North Sea water (high salinity, low yellow substance content); (2) Baltic Sea water (low salinity, intermediate-high yellow substance content); and (3) German Bight/Southern North Sea water (intermediate-high salinity, high yellow substance content). Based on the volume flow estimates used in a two-layer box-model of the Kattegat (Jørgensen, Continental Shelf Research, 12, 103-114, 1992) and conservation of yellow substance, it is argued that the long-term average composition of the bottom layer inflow to the Kattegat from the Skagerrak consists of about 90% North Sea/Atlantic water and 10% German Bight/Southern North Sea water. The German Bight content estimate is substantially lower than the ones given in earlier studies (50-67%) and implies that the Jutland Coastal Current only has a small impact on the water quality of the Kattegat.

Experimental characterization of gasoline sprays under highly evaporating conditions

Science.gov (United States)

Khan, Muhammad Mahabat; Sheikh, Nadeem Ahmed; Khalid, Azfar; Lughmani, Waqas Akbar

2018-05-01

An experimental investigation of multistream gasoline sprays under highly evaporating conditions is carried out in this paper. Temperature increase of fuel and low engine pressure could lead to flash boiling. The spray shape is normally modified significantly under flash boiling conditions. The spray plumes expansion along with reduction in the axial momentum causes the jets to merge and creates a low-pressure area below the injector's nozzle. These effects initiate the collapse of spray cone and lead to the formation of a single jet plume or a big cluster like structure. The collapsing sprays reduces exposed surface and therefore they last longer and subsequently penetrate more. Spray plume momentum increase, jet plume reduction and spray target widening could delay or prevent the closure condition and limit the penetration (delayed formation of the cluster promotes evaporation). These spray characteristics are investigated experimentally using shadowgraphy, for five and six hole injectors, under various boundary conditions. Six hole injectors produce more collapsing sprays in comparison to five hole injector due to enhanced jet to jet interactions. The spray collapse tendency reduces with increase in injection pressure due high axial momentum of spray plumes. The spray evaporation rates of five hole injector are observed to be higher than six hole injectors. Larger spray cone angles of the six hole injectors promote less penetrating and less collapsing sprays.

Calcium titanate (CaTiO{sub 3}) dielectrics prepared by plasma spray and post-deposition thermal treatment

Energy Technology Data Exchange (ETDEWEB)

Ctibor, Pavel [Materials Engineering Department, Institute of Plasma Physics ASCR, v.v.i., Za Slovankou 3, Prague 8 (Czech Republic); Kotlan, Jiri, E-mail: kotlan@ipp.cas.cz [Materials Engineering Department, Institute of Plasma Physics ASCR, v.v.i., Za Slovankou 3, Prague 8 (Czech Republic); Department of Electrotechnology, Faculty of Electrical Engineering, Czech Technical University in Prague, Technicka 2, Prague 6 (Czech Republic); Pala, Zdenek [Materials Engineering Department, Institute of Plasma Physics ASCR, v.v.i., Za Slovankou 3, Prague 8 (Czech Republic); Sedlacek, Josef [Department of Electrotechnology, Faculty of Electrical Engineering, Czech Technical University in Prague, Technicka 2, Prague 6 (Czech Republic); Hajkova, Zuzana; Grygar, Tomas Matys [Institute of Inorganic Chemistry ASCR, v.v.i., Husinec-Rez 1001, Rez (Czech Republic)

2015-12-15

Highlights: • Calcium titanate was sprayed by two different plasma spray systems. • Significant improvement of dielectric properties after annealing was observed. • Calcium titanate self-supporting parts can be fabricated by plasma spraying. - Abstract: This paper studies calcium titanate (CaTiO{sub 3}) dielectrics prepared by plasma spray technology. A water stabilized plasma gun (WSP) as well as a widely used gas stabilized plasma gun (GSP) were employed in this study to deposit three sample sets at different spray conditions. Prepared specimens were annealed in air at atmospheric pressure for 2 h at various temperatures from 530 to 1170 °C. X-ray diffraction (XRD), Raman spectroscopy and porosity measurements were used for sample characterization. Dielectric spectroscopy was applied to obtain relative permittivity, conductivity and loss factor frequency dependence. Band gap energy was estimated from reflectance measurements. The work is focused on the explanation of changes in microstructure and properties of a plasma sprayed deposit after thermal annealing. Obtained results show significant improvement of dielectric properties after thermal annealing.

Fully-flexible supercapacitors using spray-deposited carbon-nanotube films as electrodes

Science.gov (United States)

Lee, Churl Seung; Bae, Joonho

2013-12-01

Fully-flexible carbon-nanotube-based supercapacitors were successfully fabricated using a spray method. For electrodes, multiwalled carbon-nanotube films sprayed on polyethylene terephthalate (PET) substrates were employed. Thin Al films on PET were used as current collectors. The electrolyte was 1 M KNO3. Cyclic voltammetry and galvanostatic charge-discharge measurements on the flexible supercapacitors revealed that the area-specific capacitance was 0.11 mF/cm2. Electrochemical impedance spectroscopy of the supercapacitors resulted in a low internal resistance (3.7 Ω). The energy density and the power density of the flexible supercapacitor were measured to be 3.06 × 10-8 Wh/cm2 and 2.65 × 10-7 W/cm2, respectively. The Bode | z| and phase-angle plots showed that the supercapacitors functioned close to ideal capacitors at the frequencies near 2 kHz. These results indicate that the spray deposition method of carbon nanotubes could be promising for fabricating flexible energy devices or electronics.

Spray characteristics and liquid distribution of multi-hole effervescent atomisers for industrial burners

International Nuclear Information System (INIS)

Jedelský, Jan; Jícha, Miroslav

2016-01-01

Highlights: • The multi-hole (mh) spray morphology is very similar to that of single-hole nozzles. • Unsteady spray was found at low pressure and low gas-to-liquid-ratio (GLR) values. • Cone angle variation in mh spray with pressure and GLR depends on the exit nozzles angle. • A liquid–gas gravitational separation in horizontal atomiser operation was observed. • It causes up to 70% fuel supply variance into exit holes depending on design and regime. - Graphical Abstract: - Abstract: The present paper provides an experimental study and optimisation of multi-hole effervescent atomisers for industrial burners using oil-based fossil, bio- or waste fuels with prospects of emission reduction. Several multi-hole nozzles were designed based on our previous work. We probed the spray quality by phase-Doppler anemometry. 3-D plots of Sauter mean diameter and mean droplet velocity demonstrate their spatial distribution within the spray. The effect of geometrical and operational factors on the spray is discussed. Droplet size–velocity correlations as well as the size and velocity distributions are presented, and differences are found against other investigations. A spray macrostructure is photographically observed and spray cone angles of the multi-hole nozzles are analysed. An internal two-phase flow is estimated using the Baker's map for horizontal two-phase flow. Our previous two-phase flow visualisations suggested a liquid–gas gravitational separation when the multi-hole atomiser operated horizontally. This issue is addressed here; the results of spray heterogeneity measurements document that fuel flow rates through individual exit holes differ significantly. This difference spans between 0 and 70% depending on the nozzle design and flow regime. Effervescent sprays are unsteady under some operating conditions; spray unsteadiness was detected at low pressure and low gas-to-liquid-ratios.

Cold spray nozzle design

Science.gov (United States)

Haynes, Jeffrey D [Stuart, FL; Sanders, Stuart A [Palm Beach Gardens, FL

2009-06-09

A nozzle for use in a cold spray technique is described. The nozzle has a passageway for spraying a powder material, the passageway having a converging section and a diverging section, and at least the diverging section being formed from polybenzimidazole. In one embodiment of the nozzle, the converging section is also formed from polybenzimidazole.

Checking technical measurements on climatic data during sand blasting and spraying work in the condensation chamber of the boiling water reactor Gundremmingen

International Nuclear Information System (INIS)

Rausch, D.; Unte, U.

1986-01-01

During sand blasting and spraying work in the condensation chambers of boiling water reactors prescribed climatic data must be adhered to. For this purpose temporary air conditioners are used. The technical measurement examination here should provide information as to whether the air conditioners used were to fulfill the parameter curve specifications. (orig.) [de

CFD simulation of pesticide spray from air-assisted sprayers in an apple orchard: Tree deposition and off-target losses

Science.gov (United States)

Hong, Se-Woon; Zhao, Lingying; Zhu, Heping

2018-02-01

The ultimate goal of a pesticide spraying system is to provide adequate coverage on intended canopies with a minimum amount of spray materials and off-target waste. Better spray coverage requires an understanding of the fate and transport of spray droplets carried by turbulent airflows in orchards. In this study, an integrated computational fluid dynamics (CFD) model was developed to predict displacement of pesticide spray droplets discharged from an air-assisted sprayer, depositions onto tree canopies, and off-target deposition and airborne drift in an apple orchard. Pesticide droplets discharged from a moving sprayer were tracked using the Lagrangian particle transport model, and the deposition model was applied to droplets entering porous canopy zones. Measurements of the droplet deposition and drift in the same orchard were used to validate the model simulations. Good agreement was found between the measured and simulated spray concentrations inside tree canopies and off-target losses (ground deposition and airborne drifts) with the overall relative errors of 22.1% and 40.6%, respectively, under three growth stages. The CFD model was able to estimate the mass balance of pesticide droplets in the orchard, which was practically difficult to investigate by measurements in field conditions. As the foliage of trees became denser, spray deposition inside canopies increased from 8.5% to 65.8% and airborne drift and ground deposition decreased from 25.8% to 7.0% and 47.8% to 21.2%, respectively. Higher wind speed also increased the spray airborne drift downwind of the orchard. This study demonstrates that CFD model can be used to evaluate spray application performance and design and operate sprayers with increased spray efficiencies and reduced drift potentials.

Spatio-temporal droplet size statistics in developing spray of starchy solution

Science.gov (United States)

Naz, Muhammad Yasin; Sulaiman, Shaharin Anwar; Ariwahjoedi, Bambang

2015-07-01

In the given research, the spray jet breakup of a modified starch solution was studied as a function of jet injection time and nozzle orifice diameter. The starch-urea-borax solution was prepared and tested with three axisymmetric full cone nozzles at service temperature of 80°C and the injection pressure of 5 bar. It is worth mentioning that no jet breakup was seen below these temperature and pressure values. The imaging studies on the time based spray evolution revealed monotonic increase in both; spray cone angle and tip penetration with an increase in injection time form 0-300 mm. Hereinafter, both parameters exhibited constants value over injection time. Phase Doppler Anemometry (PDA) measurements of the droplet size revealed significant decrease in the Sauter Mean Diameter (SMD) along the spray centerline. However, a steady decrease in SMD was seen towards the spray boundary. For fixed injection time of 300 ms, the overall SMD was decreased from 112 to 71 µm at 60 mm downstream, from 102 to 64 µm at 100 mm downstream and from 85 to 61 µm at 140 mm downstream with an increase in orifice diameter from 1.19 to 1.59 mm.

Quantitative liquid and vapor distribution measurements in evaporating fuel sprays using laser-induced exciplex fluorescence

International Nuclear Information System (INIS)

Fansler, Todd D; Drake, Michael C; Gajdeczko, Boguslaw; Düwel, Isabell; Koban, Wieland; Zimmermann, Frank P; Schulz, Christof

2009-01-01

Fully quantitative two-dimensional measurements of liquid- and vapor-phase fuel distributions (mass per unit volume) from high-pressure direct-injection gasoline injectors are reported for conditions of both slow and rapid vaporization in a heated, high-pressure spray chamber. The measurements employ the coevaporative gasoline-like fluorobenzene (FB)/diethylmethylamine (DEMA)/hexane exciplex tracer/fuel system. In contrast to most previous laser-induced exciplex-fluorescence (LIEF) experiments, the quantitative results here include regions in which liquid and vapor fuel coexist (e.g. near the injector exit). A unique aspect is evaluation of both vapor- and liquid-phase distributions at varying temperature and pressure using only in situ vapor-phase fluorescence calibration measurements at room temperature and atmospheric pressure. This approach draws on recent extensive measurements of the temperature-dependent spectroscopic properties of the FB–DEMA exciplex system, in particular on knowledge of the quantum efficiencies of the vapor-phase and liquid-phase (exciplex) fluorescence. In addition to procedures necessary for quantitative measurements, we discuss corrections for liquid–vapor crosstalk (liquid fluorescence that overlaps the vapor-fluorescence bandpass), the unknown local temperature due to vaporization-induced cooling, and laser-sheet attenuation by scattering and absorption

Study of Multi-Function Micro-Plasma Spraying Technology

International Nuclear Information System (INIS)

Wang Liuying; Wang Hangong; Hua Shaochun; Cao Xiaoping

2007-01-01

A multi-functional micro-arc plasma spraying system was developed according to aerodynamics and plasma spray theory. The soft switch IGBT (Insulated Gate Bipolar Transistor) invert technique, micro-computer control technique, convergent-divergent nozzle structure and axial powder feeding techniques have been adopted in the design of the micro-arc plasma spraying system. It is not only characterized by a small volume, a light weight, highly accurate control, high deposition efficiency and high reliability, but also has multi-functions in plasma spraying, welding and quenching. The experimental results showed that the system can produce a supersonic flame at a low power, spray Al 2 O 3 particles at an average speed up to 430 m/s, and make nanostructured AT13 coatings with an average bonding strength of 42.7 MPa. Compared to conventional 9M plasma spraying with a higher power, the coatings with almost the same properties as those by conventional plasma spray can be deposited by multi-functional micro-arc plasma spraying with a lower power plasma arc due to an improved power supply design, spray gun structure and powder feeding method. Moreover, this system is suitable for working with thin parts and undertaking on site repairs, and as a result, the application of plasma spraying will be greatly extended

Study on Spray Characteristics and Spray Droplets Dynamic Behavior of Diesel Engine Fueled by Rapeseed Oil

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Sapit Azwan

2014-07-01

Full Text Available Fuel-air mixing is important process in diesel combustion. It directly affects the combustion and emission of diesel engine. Biomass fuel needs great help to atomize because the fuel has high viscosity and high distillation temperature. This study investigates the atomization characteristics and droplet dynamic behaviors of diesel engine spray fueled by rapeseed oil (RO. Optical observation of RO spray was carried out using shadowgraph photography technique. Single nano-spark photography technique was used to study the characteristics of the rapeseed oil spray while dual nano-spark shadowgraph technique was used to study the spray droplet behavior. The results show that RO has very poor atomization due to the high viscosity nature of the fuel. This is in agreement with the results from spray droplet dynamic behavior studies that shows due to the high viscosity, the droplets are large in size and travel downward, with very little influence of entrainment effect due to its large kinematic energy.

Optical and electrical characteristics of zirconium oxide thin films deposited on silicon substrates by spray pyrolysis

International Nuclear Information System (INIS)

Aguilar-Frutis, M.; Araiza, J.J.; Falcony, C.; Garcia, M.

2002-01-01

The optical and electrical characteristics of zirconium oxide thin films deposited by spray pyrolysis on silicon substrates are reported. The films were deposited from a spraying solution of zirconium acetylacetonate in N,N-dimethylformamide using an ultrasonic mist generator on (100) Si substrates. The substrate temperature during deposition was in the range of 400 to 600 grad C. Deposition rates up to 16 A/sec were obtained depending on the spraying solution concentration and on the substrate temperature. A refraction index of the order of 2.0 was measured on these films by ellipsometry. The electrical characteristics of the films were determined from the capacitance and current versus voltage measurements. The addition of water mist during the spraying deposition process was also studied in the characteristics of the films. (Authors)

Intermittent cryogen spray cooling for optimal heat extraction during dermatologic laser treatment

Science.gov (United States)

Majaron, Boris; Svaasand, Lars O.; Aguilar, Guillermo; Nelson, J. Stuart

2002-09-01

Fast heat extraction is critically important to obtain the maximal benefit of cryogen spray cooling (CSC) during laser therapy of shallow skin lesions, such as port wine stain birthmarks. However, a film of liquid cryogen can build up on the skin surface, impairing heat transfer due to the relatively low thermal conductivity and higher temperature of the film as compared to the impinging spray droplets. In an attempt to optimize the cryogen mass flux, while minimally affecting other spray characteristics, we apply a series of 10 ms spurts with variable duty cycles. Heat extraction dynamics during such intermittent cryogen sprays were measured using a custom-made metal-disc detector. The highest cooling rates were observed at moderate duty cycle levels. This confirms the presence, and offers a practical way to eliminate the adverse effect of liquid cryogen build-up on the sprayed surface. On the other hand, lower duty cycles allow a substantial reduction in the average rate of heat extraction, enabling less aggressive and more efficient CSC for treatment of deeper targets, such as hair follicles.

Characteristics of combustion flame sprayed nickel aluminum using a Coanda Assisted Spray Manipulation collar for off-normal deposits

Science.gov (United States)

Archibald, Reid S.

A novel flame spray collar called the Coanda Assisted Spray Manipulation collar (CSM) has been tested for use on the Sulzer Metco 5P II combustion flame spray gun. A comparison study of the stock nozzle and the CSM has been performed by evaluating the porosity, surface roughness, microhardness, tensile strength and microscopy of normal and off-normal sprayed NiAl deposits. The use of the CSM collar resulted in the need to position the sprayed coupons closer to the gun, which in turn affected the particle impact energy and particle temperatures of the NiAl powder. For the CSM, porosities had a larger scatterband, surface roughness was comparably the same, microhardness was lower, and tensile strength was higher. The microscopy analysis revealed a greater presence of unmelted particles and steeper intersplat boundaries for the CSM. For both processes, the porosity and surface roughness increased and the microhardness decreased as the spray angle decreased.

Using complexation for the microencapsulation of nisin in biopolymer matrices by spray-drying.

Science.gov (United States)

Ben Amara, Chedia; Kim, Lanhee; Oulahal, Nadia; Degraeve, Pascal; Gharsallaoui, Adem

2017-12-01

The aim of this study is to investigate the potential of complexation to encapsulate nisin (5g/L concentration) using spray-drying technique and to evaluate how complexation with pectin or alginate (2g/L concentration) can preserve nisin structure and antimicrobial activity. Spray-drying of nisin-low methoxyl pectin or nisin-alginate electrostatic complexes has led to the microencapsulation of the peptide in different networks that were highly influenced by the polysaccharide type. Turbidity and particle size measurements indicated that while spray-drying promoted the aggregation of nisin-pectin complexes, it favored the dissociation of nisin-alginate aggregates to form individual complexes. Structural changes of nisin induced by complexation with pectin or alginate and spray-drying were studied by using UV-Vis absorption and fluorescence spectroscopy. The results showed that complexation with pectin or alginate preserved nisin structure as well as its antimicrobial activity during spray-drying. Copyright © 2017 Elsevier Ltd. All rights reserved.

Resilience of Infrastructure Systems to Sea-Level Rise in Coastal Areas: Impacts, Adaptation Measures, and Implementation Challenges

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Beatriz Azevedo de Almeida

2016-11-01

Full Text Available Expansive areas of low elevation in many densely populated coastal areas are at elevated risk of storm surges and flooding due to torrential precipitation, as a result of sea level rise. These phenomena could have catastrophic impacts on coastal communities and result in the destruction of critical infrastructure, disruption of economic activities and salt water contamination of the water supply. The objective of the study presented in this paper was to identify various impacts of sea level rise on civil infrastructures in coastal areas and examine the adaptation measures suggested in the existing literature. To this end, a systemic review of the existing literature was conducted in order to identify a repository of studies addressing sea level rise impacts and adaptation measures in the context of infrastructure systems. The study focused on three infrastructure sectors: water and wastewater, energy, and road transportation. The collected information was then analyzed in order to identify different categories of sea level rise impacts and corresponding adaptation measures. The findings of the study are threefold: (1 the major categories of sea level rise impacts on different infrastructure systems; (2 measures for protection, accommodation, and retreat in response to sea level rise impacts; and (3 challenges related to implementing adaptation measures.

Visualization, granulometry and evaporation of drops and sprays - Study in close and pressurized atmosphere

International Nuclear Information System (INIS)

Lassauce, Aurelia

2011-01-01

The objective of this thesis is to determine the influence of ambient pressure between 100 and 600 KPa on the evaporation of a drop, and on the evaporation of a spray in the same conditions. The first step is to study the influence of ambient pressure on the evolution of the shape, the diameter, the speed and the evaporation rate of a drop of liquid in free fall. Then, an optical measurement technique has been used and a methodology was developed to calibrate this measurement technique and minimize measurement errors on the particle size. In parallel, an analytical model of evaporation of falling drops has been developed: a particular attention was paid to the determination of an appropriate correlation for the drag coefficient to take into account changes in the shape of drops during their fall. This model of evaporation of drop is compared with a spray evaporation model (taking into account the training of air, the vapor concentration away from the drop and the influence of the pressure to show the limits of this drop evaporation model when applied to the evaporation of a spray. The second phase of the study was to apply the measurement techniques and analysis developed previously to study the drop size of a spray to characterize the influence of three parameters: ambient pressure, injection pressure of the liquid and nature of the liquid. The analysis of the results allowed developing a statistical model to determine the size of the drops of these sprays [fr

Discriminating Sea Spikes in Incoherent Radar Measurements of Sea Clutter

Science.gov (United States)

2008-03-01

het detecteren echter niet te verwachten dat bet gebruik van sea spikes te onderzoeken. Een van deze modellen zal leiden tot een Auteur (s) dergelijk...report I TNO-DV 2008 A067 6/33 Abbreviations CFAR Constant False-Alarm Rate CST Composite Surface Theory FFT Fast Fourier Transform PDF Probability Density...described by the composite surface theory (CST). This theory describes the sea surface as small Bragg-resonant capillary waves riding on top of

A study on the effect of heat treatment on electrical properties of plasma sprayed YSZ

International Nuclear Information System (INIS)

Elshikh, S.S.M.

2012-01-01

Free standing samples of plasma sprayed (PS) zirconia partially stabilized with yettria (YSZ) were prepared with two machines of plasma spray deposition (Triplex gun- 100 kw, F-4 gun 64 kw) have different electrical power and spraying parameters, which produced different microstructures; contain different amounts and varieties of pores and micro-cracks.The study included heat treatment of samples at 1200 degree C for 1 h, 5 h, 10 h, 100 h and 500 h, to study the changes in macrostructure (pores and micro-cracks) which affect the electrical conductivity.The electrical properties (resistively, electrical conductivity) of plasma sprayed ZrO 2 stabilized by 8 wt. % Y 2 O 3 samples were determined by using electrical impedance spectroscopy (IS). Specimen's microstructure was examined by optical microscopy. By measuring electrical properties and connected porosity percent of the coatings obtained under various spraying conditions, it would be possible to select the optimum spraying condition to spray coatings which have high efficiency at high temperature.The results showed that the electrical conductivity of (YSZ) samples after heat treatment increased by a rate of (20%-30%) as compared to that of as sprayed.

Supernova-produced radionuclides in deep-sea sediments measured with AMS

International Nuclear Information System (INIS)

Feige, J.

2014-01-01

This thesis is dedicated to computational micromagnetics, where several new numerical methods are In this work a set of long-lived radionuclides is measured to detect supernova-traces presumably deposited on Earth 2-3 Myr ago. Approximately 100 samples of four deep-sea sediment cores (Indian Ocean) were analyzed for 26 Al, 53Mn, and 60 Fe with accelerator mass spectrometry (AMS). Additionally, 10 Be was measured to confirm the existing paleomagnetic chronology of the sediments. A signal of extraterrestrial 60 Fe, which is not produced in-situ on Earth, was detected in a time period of 1.7-3.2 Myr in the sediments used for this work. 60 Fe/ 26 Al ratios were used to calculate limits on theoretical nucleosynthesis models. A supernova-signature of 26 Al is hidden behind a terrestrial background. The measured 26 Al/ 10 Be ratios indicate, that the major source of 26 Al detected in the sediments is of atmospheric origin. Because of the extraordinarily good depth profile for the deep-sea sediments from the measured 26 Al data, this radionuclide was used for dating. (author) [de

Fundamental Study on the Effect of Spray Parameters on Characteristics of P3HT:PCBM Active Layers Made by Spray Coating

Directory of Open Access Journals (Sweden)

Yu Xie

2015-08-01

Full Text Available This paper is an attempt to elucidate the effects of the important spray characteristics on the surface morphology and light absorbance of spray-on P3HT:PCBM thin-films, used as an active layer in polymer solar cells (PSCs. Spray coating or deposition is a viable scalable technique for the large-scale, fast, and low-cost fabrication of solution-processed solar cells, and has been widely used for device fabrication, although the fundamental understanding of the underlying and controlling parameters, such as spray characteristics, droplet dynamics, and surface wettability, is still limited, making the results on device fabrication not reproducible and unreliable. In this paper, following the conventional PSC architecture, a PEDOT:PSS layer is first spin-coated on glass substrates, followed by the deposition of P3HT:PCBM using an automatic ultrasonic spray coating system, with a movable nozzle tip, to mimic an industrial manufacturing process. To gain insight, the effects of the spray carrier air pressure, the number of spray passes, the precursor flow rate, and precursor concentration are studied on the surface topography and light absorbance spectra of the spray-on films. Among the results, it is found that despite the high roughness of spray-on films, the light absorbance of the film is satisfactory. It is also found that the absorbance of spray-on films is a linear function of the number of spray passes or deposition layers, based on which an effective film thickness is defined for rough spray-on films. The effective thickness of a rough spray-on P3HT:PCBM film was found to be one-quarter of that of a flat film predicted by a simple mass balance.

Fine Sprays for Disinfection within Healthcare

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G Nasr

2016-09-01

Full Text Available Problems exist worldwide with Hospital Acquired Infections (HAI's. The Spray Research Group (SRG have been working with relevant industries in developing a product which can provide a delivery system for treatment chemicals for surfaces, including the design and testing of a novel Spill-Return Atomiser (SRA for this purpose. A comprehensive description of this atomiser has already been given. This paper reports on a new application of this atomiser and discusses the problem of spray coating for disinfection that has been considered very little in previous work. The related spray coating performance tests in developing the product are thus provided. The experimental work includes determining the required spray duration and the coverage area produced by different sprays, including the analysis of the effects of atomiser positions, configurations, and the required number of atomisers. Comparison is made with the efficacy of an ultrasonic gas atomiser that is currently used for this purpose. The investigation has found that the utilisation of fine sprays (10μm>D32>25μm at high liquid pressure (<12MPa and low flow rates (<0.3 l/min is suitable for surface disinfection in healthcare applications (i.e. MRSA, VRSA etc.

Comparison of SeaWiFS measurements of the Moon with the U.S. Geological Survey lunar model.

Science.gov (United States)

Barnes, Robert A; Eplee, Robert E; Patt, Frederick S; Kieffer, Hugh H; Stone, Thomas C; Meister, Gerhard; Butler, James J; McClain, Charles R

2004-11-01

The Sea-Viewing Wide-Field-of-View Sensor (SeaWiFS) has made monthly observations of the Moon since 1997. Using 66 monthly measurements, the SeaWiFS calibration team has developed a correction for the instrument's on-orbit response changes. Concurrently, a lunar irradiance model has been developed by the U.S. Geological Survey (USGS) from extensive Earth-based observations of the Moon. The lunar irradiances measured by SeaWiFS are compared with the USGS model. The comparison shows essentially identical response histories for SeaWiFS, with differences from the model of less than 0.05% per thousand days in the long-term trends. From the SeaWiFS experience we have learned that it is important to view the entire lunar image at a constant phase angle from measurement to measurement and to understand, as best as possible, the size of each lunar image. However, a constant phase angle is not required for using the USGS model. With a long-term satellite lunar data set it is possible to determine instrument changes at a quality level approximating that from the USGS lunar model. However, early in a mission, when the dependence on factors such as phase and libration cannot be adequately determined from satellite measurements alone, the USGS model is critical to an understanding of trends in instruments that use the Moon for calibration. This is the case for SeaWiFS.

Simulated wind-generated inertial oscillations compared to current measurements in the northern North Sea

Science.gov (United States)

Bruserud, Kjersti; Haver, Sverre; Myrhaug, Dag

2018-04-01

Measured current speed data show that episodes of wind-generated inertial oscillations dominate the current conditions in parts of the northern North Sea. In order to acquire current data of sufficient duration for robust estimation of joint metocean design conditions, such as wind, waves, and currents, a simple model for episodes of wind-generated inertial oscillations is adapted for the northern North Sea. The model is validated with and compared against measured current data at one location in the northern North Sea and found to reproduce the measured maximum current speed in each episode with considerable accuracy. The comparison is further improved when a small general background current is added to the simulated maximum current speeds. Extreme values of measured and simulated current speed are estimated and found to compare well. To assess the robustness of the model and the sensitivity of current conditions from location to location, the validated model is applied at three other locations in the northern North Sea. In general, the simulated maximum current speeds are smaller than the measured, suggesting that wind-generated inertial oscillations are not as prominent at these locations and that other current conditions may be governing. Further analysis of the simulated current speed and joint distribution of wind, waves, and currents for design of offshore structures will be presented in a separate paper.

Digital image processing techniques for the analysis of fuel sprays global pattern

Science.gov (United States)

Zakaria, Rami; Bryanston-Cross, Peter; Timmerman, Brenda

2017-12-01

We studied the fuel atomization process of two fuel injectors to be fitted in a new small rotary engine design. The aim was to improve the efficiency of the engine by optimizing the fuel injection system. Fuel sprays were visualised by an optical diagnostic system. Images of fuel sprays were produced under various testing conditions, by changing the line pressure, nozzle size, injection frequency, etc. The atomisers were a high-frequency microfluidic dispensing system and a standard low flow-rate fuel injector. A series of image processing procedures were developed in order to acquire information from the laser-scattering images. This paper presents the macroscopic characterisation of Jet fuel (JP8) sprays. We observed the droplet density distribution, tip velocity, and spray-cone angle against line-pressure and nozzle-size. The analysis was performed for low line-pressure (up to 10 bar) and short injection period (1-2 ms). Local velocity components were measured by applying particle image velocimetry (PIV) on double-exposure images. The discharge velocity was lower in the micro dispensing nozzle sprays and the tip penetration slowed down at higher rates compared to the gasoline injector. The PIV test confirmed that the gasoline injector produced sprays with higher velocity elements at the centre and the tip regions.

Measurement of residual stress in plasma-sprayed composite coatings with graded and uniform compositions

Energy Technology Data Exchange (ETDEWEB)

Kesler, O.; Suresh, S. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Matejicek, J.; Sampath, S.

1999-10-01

Residual stresses in plasma sprayed composite coatings were studied experimentally by both curvature and neutron diffraction measurements. Graded and uniform composite coatings, consisting of nickel + alumina and NiCrAlY + yttria-stabilized zirconia, were investigated. This paper briefly summarizes our recent work dealing with the effects of coating thickness, composition, and material properties on the evolution of residual stresses in coatings. Analysis of the results allowed in some cases the separation of the quenching stress and thermal stress contributions to the final residual stress, as well as the determination of the through-thickness stress profile from measurements of different thickness specimens. In the ceramic-metal composites, it was found that the thermal mismatch stress plays a dominant role in the ceramic phase, whereas the stress in the metallic phase is mostly dominated by quenching stress. The residual stress measurement methods employed here were found to be complementary, in that each can provide unique information about the stress state. Through-thickness stress profiles in graded coatings were determined with high spatial resolution by the curvature method, and determination of the stress in each separate phase of a composite was made by neutron diffraction. (orig.) 14 refs.

Water spray interaction with air-steam mixtures under containment spray conditions: comparison of heat and mass transfer modelling with the TOSQAN spray tests

International Nuclear Information System (INIS)

Malet, J.; Lemaitre, P.; Porcheron, E.; Vendel, J.

2005-01-01

Full text of publication follows: During the course of a hypothetical severe accident in a Pressurized Water Reactor (PWR), hydrogen can be produced by the reactor core oxidation and distributed into the reactor containment according to convection flows and water steam wall condensation. In order to mitigate the risk of detonation generated by a high local hydrogen concentration, spray systems are used in the containment. The TOSQAN programme has been created to simulate separate-effect tests representative of typical accidental thermal-hydraulic flow conditions in the reactor containment. The present work concerns the interaction of a water spray, used at the top of the containment in order to reduce the steam partial pressure, with air-steam mixtures. The main phenomena occurring when water spray is used are the mixing induced by spray entrainment and the condensation on droplets. In order to improve the latter phenomena, different levels of modelling can be used. The objective of this paper is to analyze experimental results obtained for water spray interaction with air-steam mixtures using different heat and mass transfer modelling. For this purpose, two modelling issues have been used: the first one is devoted for the determination of the gas thermodynamical properties, and the second one concerns the droplets characterization. In the first one, the gas thermodynamical analysis is performed using depressurization, gas temperature variation and humidity decrease during the spray injection. In this modelling, heat and mass transfer between the spray and the surrounding gas is treated in a global way by energy balance between the total amount of water and the gas. In the second one, droplets characterization is obtained by means of droplet size, temperature and velocities evolutions. In this modelling, the spray is considered as a single droplet falling with an initial velocity. Droplet interactions are neglected. Assessment of these two modelling is performed

The interaction of trace heavy metal with lipid monolayer in the sea surface microlayer.

Science.gov (United States)

Li, Siyang; Du, Lin; Tsona, Narcisse T; Wang, Wenxing

2018-04-01

Lipid molecules and trace heavy metals are enriched in sea surface microlayer and can be transferred into the sea spray aerosol. To better understand their impact on marine aerosol generation and evolution, we investigated the interaction of trace heavy metals including Fe 3+ , Pb 2+ , Zn 2+ , Cu 2+ , Ni 2+ , Cr 3+ , Cd 2+ , and Co 2+ , with dipalmitoylphosphatidylcholine (DPPC) monolayers at the air-water interface. Phase behavior of the DPPC monolayer on heavy metal solutions was probed with surface pressure-area (π-A) isotherms. The conformation order and orientation of DPPC alkyl chains were characterized by infrared reflection-absorption spectroscopy (IRRAS). The π-A isotherms show that Zn 2+ and Fe 3+ strongly interact with DPPC molecules, and induce condensation of the monolayers in a concentration-dependent manner. IRRAS spectra show that the formation of cation-DPPC complex gives rise to conformational changes and immobilization of the headgroups. The current results suggest that the enrichment of Zn 2+ in sea spray aerosols is due to strong binding to the DPPC film. The interaction of Fe 3+ with DPPC monolayers can significantly influence their surface organizations through the formation of lipid-coated particles. These results suggest that the sea surface microlayer is capable of accumulating much higher amounts of these metals than the subsurface water. The organic and metal pollutants may transfer into the atmosphere by this interaction. Copyright © 2017 Elsevier Ltd. All rights reserved.

Sea and swell along west coast of India: Study based on measured data

Digital Repository Service at National Institute of Oceanography (India)

SanilKumar, V.; AshokKumar, K.; Pednekar, P.; Gowthaman, R.

Conference on Harbour and Ocean Engineering 12-14, Dec. 2007, at NITK, Surathkal 736 SEA AND SWELL...@nio.org pprem@nio.org rgowtham@nio.org Ocean Engineering Division National Institute of Oceanography Dona Paula, Goa 403 004 India ABSTRACT Separation of sea and swell from the measured data is important for studying the wind wave dynamics...

Underwater Acoustic Measurements to Estimate Wind and Rainfall in the Mediterranean Sea

Directory of Open Access Journals (Sweden)

Sara Pensieri

2015-01-01

Full Text Available Oceanic ambient noise measurements can be analyzed to obtain qualitative and quantitative information about wind and rainfall phenomena over the ocean filling the existing gap of reliable meteorological observations at sea. The Ligurian Sea Acoustic Experiment was designed to collect long-term synergistic observations from a passive acoustic recorder and surface sensors (i.e., buoy mounted rain gauge and anemometer and weather radar to support error analysis of rainfall rate and wind speed quantification techniques developed in past studies. The study period included combination of high and low wind and rainfall episodes and two storm events that caused two floods in the vicinity of La Spezia and in the city of Genoa in 2011. The availability of high resolution in situ meteorological data allows improving data processing technique to detect and especially to provide effective estimates of wind and rainfall at sea. Results show a very good correspondence between estimates provided by passive acoustic recorder algorithm and in situ observations for both rainfall and wind phenomena and demonstrate the potential of using measurements provided by passive acoustic instruments in open sea for early warning of approaching coastal storms, which for the Mediterranean coastal areas constitutes one of the main causes of recurrent floods.

Measurement of residual stress in plasma-sprayed metallic, ceramic and composite coatings

Energy Technology Data Exchange (ETDEWEB)

Kesler, O.; Suresh, S. [Massachusetts Inst. of Tech., Cambridge, MA (United States); Matejicek, J.; Sampath, S. [State Univ. of New York, Stony Brook, NY (United States). Inst. for Mathematical Sciences; Gnaeupel-Herold, T.; Brand, P.C.; Prask, H.J. [National Institute of Standards and Technology, Gaithersburg, MD (United States)

1998-12-15

Residual stresses in plasma-sprayed coatings were studied by three experimental techniques: curvature measurements, neutron diffraction and X-ray diffraction. Two distinct material classes were investigated: (1) single-material coatings (molybdenum) and (2) bi-material composites (nickel+alumina and NiCrAlY+yttria-stabilized zirconia), with and without graded layers. This paper deals with the effects of coating thickness and material properties on the evolution of residual stresses as a function of composition and thickness in both homogeneous and graded coatings. Mathematical analysis of the results allowed in some cases the separation of the quenching stress and thermal stress contributions to the final residual stress, as well as the determination of the through-thickness stress profile from measurements of different thickness specimens. In the ceramic-metal composites, it was found that the quenching stress plays a dominant role in the metallic phase, whereas the stress in the ceramic phase is mostly dominated by thermal mismatch. The respective thermal expansion coefficients and mechanical properties are the most important factors determining the stress sign and magnitude. The three residual stress measurement methods employed here were found to be complementary, in that each can provide unique information about the stress state. The most noteworthy outcomes are the determination of the through-thickness stress profile in graded coatings with high spatial resolution (curvature method) and determination of stress in each phase of a composite separately (neutron diffraction). (orig.) 25 refs.

The influence of pore formers on the microstructure of plasma-sprayed NiO-YSZ anodes

Science.gov (United States)

Poon, Michael; Kesler, Olivera

2012-07-01

Four types of pore formers: high-density polyethylene (HDPE), polyether-ether-ketone (PEEK), mesocarbon-microbead (MCMB) carbon powder, and baking flour, are processed and characterized, then incorporated with NiO-YSZ nano-agglomerate powder to produce plasma sprayed SOFC anode coatings. Scanning electron microscopy (SEM) of the coating microstructure, gas permeability measurements, and porosity determinations by image analysis are used to evaluate the effectiveness of each potential pore former powder. Under the spray conditions studied, the flour and MCMB pore former powders are effective as plasma sprayed pore formers, increasing the permeability of the coatings by factors of four and two, respectively, compared to a similarly sprayed NiO-YSZ coating without pore formers. The HDPE powder is unable to survive the plasma spray process and does not contribute to the final coating porosity. The PEEK pore former, though ineffective with the current powder characteristics and spray parameters, exhibits the highest relative deposition efficiency and the most favorable thermal characteristics.

Treatment Satisfaction, Product Perception, and Quality of Life in Plaque Psoriasis Patients Using Betamethasone Dipropionate Spray 0.05.

Science.gov (United States)

Fowler, Joseph F; Del Rosso, James Q; Pakunlu, Refika I; Sidgiddi, Srinivas

2017-11-01

Objective: To assess patient-reported satisfaction, efficacy, and tolerability associated with the use of betamethasone dipropionate spray 0.05% when applied twice daily in subjects with moderate plaque psoriasis. Design: This was an open-label, multicenter study involving 45 patients with moderate plaque psoriasis, with the aim of evaluating patient-reported outcomes with betamethasone dipropionate spray 0.05%. Patients treated all affected areas twice daily with betamethasone dipropionate (BD) spray 0.05% for 28 days per label instructions. Measurements: Outcome measures included the Treatment Satisfaction Questionnaire for Medication (TSQM), Dermatology Life Quality Index (DLQI), Investigators Global Assessment (IGA), and Total Sign Score (TSS). In addition, the lesions were photographed at baseline (Day 1) and on Day 8, Day 14, and Day 29. Results: The results indicated that BD spray 0.05% treatment is associated with improved quality of life. BD spray 0.05% also led to improved IGA and TSS values and a reduction in the percentage of body surface area affected. Conclusion: In subjects with moderate plaque psoriasis, BD spray 0.05% demonstrated good levels of patient satisfaction and quality of life measures, in combination with improvements in the global assessment of disease and the level of itching experienced by subjects.

Investigation of discharged aerosol nanoparticles during chemical precipitation and spray pyrolysis for developing safety measures in the nano research laboratory.

Science.gov (United States)

Kolesnikov, Еvgeny; Karunakaran, Gopalu; Godymchuk, Anna; Vera, Levina; Yudin, Andrey Grigorjevich; Gusev, Alexander; Kuznetsov, Denis

2017-05-01

Nowadays, the demands for the nanoparticles are increasing due to their tremendous applications in various fields. As a consequence, the discharge of nanoparticles into the atmosphere and environment is also increasing, posing a health threat and environmental damage in terms of pollution. Thus, an extensive research is essential to evaluate the discharge of these nanoparticles into the environment. Keeping this in mind, the present investigation aimed to analyze the discharge of aerosol nanoparticles that are synthesized in the laboratory via chemical precipitation and spray pyrolysis methods. The results indicated that the chemical precipitation method discharges a higher concentration of nanoparticles in the work site when compared to the spray pyrolysis method. The aerosol concentration also varied with the different steps involved during the synthesis of nanoparticles. The average particle's concentration in air for chemical precipitation and spray pyrolysis methods was around 1,037,476 and 883,421particles/cm 3 . In addition, the average total discharge of nanoparticles in the entire laboratory was also examined. A significant variation in the concentration of nanoparticles was noticed, during the processing of materials and the concentration of particles (14-723nm) exceeding the daily allowed concentration to about 70-170 times was observed over a period of 6 months. Thus, the results of the present study will be very useful in developing safety measures and would help in organizing the rules for people working in nanotechnology laboratories to minimize the hazardous effects. Copyright © 2017 Elsevier Inc. All rights reserved.

Thermodynamic versus non-equilibrium stability of palmitic acid monolayers in calcium-enriched sea spray aerosol proxy systems.

Science.gov (United States)

Wellen Rudd, Bethany A; Vidalis, Andrew S; Allen, Heather C

2018-04-16

Of the major cations in seawater (Na+, Mg2+, Ca2+, K+), Ca2+ is found to be the most enriched in fine sea spray aerosols (SSA). In this work, we investigate the binding of Ca2+ to the carboxylic acid headgroup of palmitic acid (PA), a marine-abundant fatty acid, and the impact such binding has on the stability of PA monolayers in both equilibrium and non-equilibrium systems. A range of Ca2+ conditions from 10 μM to 300 mM was utilized to represent the relative concentration of Ca2+ in high and low relative humidity aerosol environments. The CO2- stretching modes of PA detected by surface-sensitive infrared reflection-absorption spectroscopy (IRRAS) reveal ionic binding motifs of the Ca2+ ion to the carboxylate group with varying degrees of hydration. Surface tensiometry was used to determine the thermodynamic equilibrium spreading pressure (ESP) of PA on the various aqueous CaCl2 subphases. Up to concentrations of 1 mM Ca2+, each system reached equilibrium, and Ca2+:PA surface complexation gave rise to a lower energy state revealed by elevated surface pressures relative to water. We show that PA films are not thermodynamically stable at marine aerosol-relevant Ca2+ concentrations ([Ca2+] ≥ 10 mM). IRRAS and vibrational sum frequency generation (VSFG) spectroscopy were used to investigate the surface presence of PA on high concentration Ca2+ aqueous subphases. Non-equilibrium relaxation (NER) experiments were also conducted and monitored by Brewster angle microscopy (BAM) to determine the effect of the Ca2+ ions on PA stability. At high surface pressures, the relaxation mechanisms of PA varied among the systems and were dependent on Ca2+ concentration.

Spray casting project final report

International Nuclear Information System (INIS)

Churnetski, S.R.; Thompson, J.E.

1996-08-01

Lockheed Martin Energy Systems, Inc. (Energy Systems), along with other participating organizations, has been exploring the feasibility of spray casting depleted uranium (DU) to near-net shape as a waste minimization effort. Although this technology would be useful in a variety of applications where DU was the material of choice, this effort was aimed primarily at gamma-shielding components for use in storage and transportation canisters for high-level radioactive waste, particularly in the Multipurpose Canister (MPC) application. In addition to the waste-minimization benefits, spray casting would simplify the manufacturing process by allowing the shielding components for MPC to be produced as a single component, as opposed to multiple components with many fabrication and assembly steps. In earlier experiments, surrogate materials were used to simulate the properties (specifically reactivity and density) of DU. Based on the positive results from those studies, the project participants decided that further evaluation of the issues and concerns that would accompany spraying DU was warranted. That evaluation occupied substantially all of Fiscal Year 1995, yielding conceptual designs for both an intermediate facility and a production facility and their associated engineering estimates. An intermediate facility was included in this study to allow further technology development in spraying DU. Although spraying DU to near-net shape seems to be feasible, a number of technical, engineering, and safety issues would need to be evaluated before proceeding with a production facility. This report is intended to document the results from the spray-casting project and to provide information needed by anyone interested in proceeding to the next step

Thermally sprayed coatings: Aluminum on lead

International Nuclear Information System (INIS)

Usmani, S.; Czajkowski, C.J.; Zatorski, R.

1999-01-01

An experimental program to determine the feasibility of thermally spraying aluminum on a lead substrate was initiated in support of the accelerator production of tritium (APT) Project for the US Department of Energy. The program consisted of two distinct parts: (1) the characterization of the thermally sprayed coatings, including microhardness testing, effects of heating, and microstructure and porosity determinations, and (2) effects of mercury doping and heat treatments on the thermally sprayed composite. The project determined that aluminum could successfully be thermally sprayed onto the lead. The coatings had a dense microstructure, with a Vicker's Pyramid Hardness (VPH) of about 60, and a maximum porosity (found in strips on the samples) of 12%

Structure of Non-evaporating diesel sprays

International Nuclear Information System (INIS)

Mirza, M.R.; Baluch, A.H.; Tahir, Z.R.

2008-01-01

Need is always felt of some rational experimental information on fuel spray jet formation, its development and dispersion in the combustion chamber of an internal combustion engine. The latest study uses computational fluid dynamics for the modeling of engine flows. The original experimental work of the present author on non-evaporating sprays produced by a single-hole orifice type nozzle using a distribution type commercial fuel injection pump forms the basis to derive correlations for penetration rates, break up times and lengths of non-evaporating diesel sprays. The correlations derived can be used to do CFD modeling of sprays under variable conditions of injector nozzle hole diameter, fuel injection pressure and combustion chamber pressure. (author)

Advanced Diagnostics for High Pressure Spray Combustion.

Energy Technology Data Exchange (ETDEWEB)

Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

2014-06-01

The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

Water spray ventilator system for continuous mining machines

Science.gov (United States)

Page, Steven J.; Mal, Thomas

1995-01-01

The invention relates to a water spray ventilator system mounted on a continuous mining machine to streamline airflow and provide effective face ventilation of both respirable dust and methane in underground coal mines. This system has two side spray nozzles mounted one on each side of the mining machine and six spray nozzles disposed on a manifold mounted to the underside of the machine boom. The six spray nozzles are angularly and laterally oriented on the manifold so as to provide non-overlapping spray patterns along the length of the cutter drum.

Assessment of the Influence Factors on Nasal Spray Droplet Velocity Using Phase-Doppler Anemometry (PDA)

OpenAIRE

Liu, Xiaofei; Doub, William H.; Guo, Changning

2011-01-01

Droplet velocity is an important parameter that can be used to characterize nasal spray products. In this study, a phase-Doppler anemometry (PDA) system was used to measure the droplet velocities of nasal sprays. A survey of seven commercial nasal spray products showed a range of droplet velocities from 6.7 to 19.2 m/s, all significantly different from each other. A three-level, four-factor Box–Behnken design of experiments (DOE) methodology were applied to investigate the influences of actua...

Atomization and spray characteristics of bioethanol and bioethanol blended gasoline fuel injected through a direct injection gasoline injector

International Nuclear Information System (INIS)

Park, Su Han; Kim, Hyung Jun; Suh, Hyun Kyu; Lee, Chang Sik

2009-01-01

The focus of this study was to investigate the spray characteristics and atomization performance of gasoline fuel (G100), bioethanol fuel (E100), and bioethanol blended gasoline fuel (E85) in a direct injection gasoline injector in a gasoline engine. The overall spray and atomization characteristics such as an axial spray tip penetration, spray width, and overall SMD were measured experimentally and predicted by using KIVA-3V code. The development process and the appearance timing of the vortices in the test fuels were very similar. In addition, the numerical results accurately described the experimentally observed spray development pattern and shape, the beginning position of the vortex, and the spray breakup on the spray surface. Moreover, the increased injection pressure induced the occurrence of a clear circular shape in the downstream spray and a uniform mixture between the injected spray droplets and ambient air. The axial spray tip penetrations of the test fuels were similar, while the spray width and spray cone angle of E100 were slightly larger than the other fuels. In terms of atomization performance, the E100 fuel among the tested fuels had the largest droplet size because E100 has a high kinematic viscosity and surface tension.

A new method for spray deposit assessment

Science.gov (United States)

Chester M. Himel; Leland Vaughn; Raymond P. Miskus; Arthur D. Moore

1965-01-01

Solid fluorescent particles suspended in a spray liquid are distributed in direct proportion to the size of the spray droplets. Use of solid fluorescent particles is the basis of a new method for visual recognition of the size and number of droplets impinging on target and nontarget portions of sprayed areas.

A simplified model of aerosol removal by containment sprays

Energy Technology Data Exchange (ETDEWEB)

Powers, D.A. (Sandia National Labs., Albuquerque, NM (United States)); Burson, S.B. (Nuclear Regulatory Commission, Washington, DC (United States). Div. of Safety Issue Resolution)

1993-06-01

Spray systems in nuclear reactor containments are described. The scrubbing of aerosols from containment atmospheres by spray droplets is discussed. Uncertainties are identified in the prediction of spray performance when the sprays are used as a means for decontaminating containment atmospheres. A mechanistic model based on current knowledge of the physical phenomena involved in spray performance is developed. With this model, a quantitative uncertainty analysis of spray performance is conducted using a Monte Carlo method to sample 20 uncertain quantities related to phenomena of spray droplet behavior as well as the initial and boundary conditions expected to be associated with severe reactor accidents. Results of the uncertainty analysis are used to construct simplified expressions for spray decontamination coefficients. Two variables that affect aerosol capture by water droplets are not treated as uncertain; they are (1) [open quote]Q[close quote], spray water flux into the containment, and (2) [open quote]H[close quote], the total fall distance of spray droplets. The choice of values of these variables is left to the user since they are plant and accident specific. Also, they can usually be ascertained with some degree of certainty. The spray decontamination coefficients are found to be sufficiently dependent on the extent of decontamination that the fraction of the initial aerosol remaining in the atmosphere, m[sub f], is explicitly treated in the simplified expressions. The simplified expressions for the spray decontamination coefficient are given. Parametric values for these expressions are found for median, 10 percentile, and 90 percentile values in the uncertainty distribution for the spray decontamination coefficient. Examples are given to illustrate the utility of the simplified expressions to predict spray decontamination of an aerosol-laden atmosphere.

Visualization research on spray atomization, evaporation and combustion processes of ethanol–diesel blend under LTC conditions

International Nuclear Information System (INIS)

Huang, Sheng; Deng, Peng; Huang, Ronghua; Wang, Zhaowen; Ma, Yinjie; Dai, Hui

2015-01-01

Highlights: • Spray combustion of E20 diesel in LTC condition shows a U-shape flame structure. • The chasing behavior of fuel spray exists near the spray axis. • Fuel ignition doesn’t initiate at the spray tip but in peripheral regions behind it. • An improper chamber structure may lead to a long post-combustion duration. - Abstract: Utilization of ethanol in diesel engines has been widely studied by means of engine experiments and emission detection. However, pertinent studies on the spray combustion process of ethanol–diesel blends are scarce. In order to verify the effect of ethanol in modern diesel engines, an experiment is conducted to visualize the spray combustion process of ethanol–diesel blend under LTC conditions. Stages including atomization, evaporation and combustion, are investigated individually to realize synergistic analysis. Meanwhile, considering the long time scale of combustion after fuel injection finishes, characteristics during and after injection period are both targeted in this paper. Moreover, measurement of macroscopic characteristics, such as spray tip penetration, spray spreading cone angle and flame lift off length, provides a quantitative profile of the spray structure. Results show that, evaporation, different from atomization, has little influence on spray penetration, but promotes the spray spreading angle and spray projected area. So does combustion, which enlarges the spray projected area further. Ignition takes place on the periphery behind the spray tip, then quickly extends to the whole head of the spray and forms a U-shape diffusion structure. After the injection period, the residual spray tail develops into wavelike structures due to absence of subsequent entrainment force. Also, the penetration speed falls greatly to an extent much slower than flame propagation, which frees the flame from the lift-off effect. Subsequently, the flame propagates upstream towards the nozzle orifice. After consumed all fuel in

Quantifying Seasonal Skill In Coupled Sea Ice Models Using Freeboard Measurements From Spaceborne Laser Altimeters

Science.gov (United States)

2016-06-01

Data collection periods during the ICESat mission were influenced by the presence of atmospheric clouds and aerosols, and also LASER malfunctions. Upon...measurements after that satellite is launched next year. 14. subject terms Arctic, climate change, Regional Arctic System Model, altimetry...measurements, sea ice, sea ice thickness, freeboard, ICESat, ICESat-2, climate model, coupled model, Operation IceBridge 15. NUMBER OF PAGES 147 16

Effect of spray volume on the deposition, viability and infectivity of entomopathogenic nematodes in a foliar spray on vegetables.

Science.gov (United States)

Brusselman, Eva; Beck, Bert; Pollet, Sabien; Temmerman, Femke; Spanoghe, Pieter; Moens, Maurice; Nuyttens, David

2012-10-01

Spray volume can influence the amount of free water on the leaf surface and subsequently the ability of entomopathogenic nematodes (EPNs) to move. In this study, an investigation was made of the effect of spray volume (548, 730 and 1095 L ha(-1) ) on the deposition, viability and infectivity of EPNs against Galleria mellonella on savoy cabbage, cauliflower and leek. Increasing spray volume decreased nematode deposition on 7.1 cm2 leek leaf discs at a 15° angle with the spray nozzle. Although the number of living nematodes observed on leek after 240 min of exposure was not significantly different between the low-volume application (548 L ha(-1) ) and the high-volume application (1095 L ha(-1) ), a greater infectivity was obtained in the latter application. The higher number of droplets deposited on the leek discs in the high-volume application may have stimulated nematode movement. No significant effect of spray volume was observed on the relative deposition of Steinernema carpocapsae on the bottom side of cauliflower and savoy cabbage leaf discs. In spite of the low S. carpocapsae deposition on the bottom side of the savoy cabbage discs, high infectivity was obtained against G. mellonella. Using the lowest spray volume on savoy cabbage, infectivity decreased with increasing exposure time, while infectivity was not affected by exposure time when a spray volume of 730 L ha(-1) or more was used. Spray volume is an important application parameter, as it affects nematode infectivity. Future research should investigate the effect of spray volume in the field and its influence on the effect of adjuvants. Copyright © 2012 Society of Chemical Industry.

Albendazole Microparticles Prepared by Spray Drying Technique ...

African Journals Online (AJOL)

Purpose: To enhance the dissolution of albendazole (ABZ) using spray-drying technique. Method: ABZ binary mixtures with Kollicoat IR® (KL) and polyvinyl pyrrolidone (PVP) in various drug to polymer ratios (1: 1, 1: 2 and 1; 4) were prepared by spray-drying. The spray-dried particles were characterized for particle shape, ...

CHARACTERIZATION OF DIESEL SPRAY IMAGES USING A SHAPE PROCESSING METHODOLOGY

Directory of Open Access Journals (Sweden)

Cecile Petit

2011-05-01

Full Text Available In Diesel engines, a key element in achieving a clean and efficient combustion process is a proper fuel-air mixing, which is a consequence of the fuel spray development and fuel-air interaction inside the engine combustion chamber. The spray structure and behavior are classically described by the length (penetration and width (angle of the spray plume but these parameters do not give any clue on the geometrical injection center and on the spray symmetry. The purpose of this paper is to find out original tools to characterize the Diesel spray: the virtual spray origin is the geometrical injection center, which may (or may not coincide with the injector axis. Another interesting point is the description of the Diesel spray in terms of symmetry: the spray plume internal and external symmetry characterize the spray and the injector performance. Our approach is first to find out the virtual spray origin: after the image segmentation, the spray is coded with the Freeman code and with an original shape coding from which the moments are derived. The symmetry axes are then computed and the spray plumes are discarded (or not for the virtual spray origin computation, which is derived from a Voronoi diagram. The last step is the internal and external spray plume symmetry characterization thanks to correlation and mathematical distances.

Ultrafast X-ray Imaging of Fuel Sprays

Science.gov (United States)

Wang, Jin

2007-01-01

Detailed analysis of fuel sprays has been well recognized as an important step for optimizing the operation of internal combustion engines to improve efficiency and reduce emissions. Ultrafast radiographic and tomographic techniques have been developed for probing the fuel distribution close to the nozzles of direct-injection diesel and gasoline injectors. The measurement was made using x-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution on the order of 1 μs. Furthermore, an accurate 3-dimensional fuel-density distribution, in the form of fuel volume fraction, was obtained by the time-resolved computed tomography. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date. With high-energy and high-brilliance x-ray beams available at the Advanced Photon Source, propagation-based phase-enhanced imaging was developed as a unique metrology technique to visualize the interior of an injection nozzle through a 3-mm-thick steel with a 10-μs temporal resolution, which is virtually impossible by any other means.

Ultrafast X-ray Imaging of Fuel Sprays

International Nuclear Information System (INIS)

Wang Jin

2007-01-01

Detailed analysis of fuel sprays has been well recognized as an important step for optimizing the operation of internal combustion engines to improve efficiency and reduce emissions. Ultrafast radiographic and tomographic techniques have been developed for probing the fuel distribution close to the nozzles of direct-injection diesel and gasoline injectors. The measurement was made using x-ray absorption of monochromatic synchrotron-generated radiation, allowing quantitative determination of the fuel distribution in this optically impenetrable region with a time resolution on the order of 1 μs. Furthermore, an accurate 3-dimensional fuel-density distribution, in the form of fuel volume fraction, was obtained by the time-resolved computed tomography. These quantitative measurements constitute the most detailed near-nozzle study of a fuel spray to date. With high-energy and high-brilliance x-ray beams available at the Advanced Photon Source, propagation-based phase-enhanced imaging was developed as a unique metrology technique to visualize the interior of an injection nozzle through a 3-mm-thick steel with a 10-μs temporal resolution, which is virtually impossible by any other means

Spray drying of beryllium oxide powder

International Nuclear Information System (INIS)

Sepulveda, J.L.; Kahler, D.A.

1991-01-01

Forming of beryllia ceramics through dry pressing requires the agglomeration of the powder through spray drying. To produce high quality fired ceramics it is necessary to disperse/grind the primary powder prior to binder addition. Size reduction of the powder is accomplished using an aqueous system in Vibro-Energy mills (VEM) charged with beryllia media to minimize contamination. Two VEM mills of different size were used to characterize the grinding operation. Details of the grinding kinetics are described within the context of the Macroscopic Population Balance Model approach. Spray drying of the ceramic slurry was accomplished with both a centrifugal atomizer and a two fluid nozzle atomizer. Two different spray dryers were used. Important operating parameters affecting the size distribution of the spray dried powder are discussed

LSPRAY-V: A Lagrangian Spray Module

Science.gov (United States)

Raju, M. S.

2015-01-01

LSPRAY-V is a Lagrangian spray solver developed for application with unstructured grids and massively parallel computers. It is mainly designed to predict the flow, thermal and transport properties of a rapidly vaporizing spray encountered over a wide range of operating conditions in modern aircraft engine development. It could easily be coupled with any existing gas-phase flow and/or Monte Carlo Probability Density Function (PDF) solvers. The manual provides the user with an understanding of various models involved in the spray formulation, its code structure and solution algorithm, and various other issues related to parallelization and its coupling with other solvers. With the development of LSPRAY-V, we have advanced the state-of-the-art in spray computations in several important ways.

Vacuum-plasma-sprayed silicon coatings

International Nuclear Information System (INIS)

Varacalle, D.J. Jr.; Herman, H.; Bancke, G.A.; Burchell, T.D.; Romanoski, G.R.

1991-01-01

Vacuum plasma spraying produces well-bonded dense stress-free coatings for a variety of materials on a wide range of substrates. The process is used in many industries for the excellent wear, corrosion resistance and high temperature behavior of the fabricated coatings. In this study, silicon metal was deposited on graphite to study the feasibility of preventing corrosion and oxidation of graphite components for nuclear reactors. Operating parameters were varied in a Taguchi design of experiments to display the range of the plasma processing conditions and their effect on the measured coating characteristics. The coating attributes evaluated were thickness, porosity, microhardness and phase content. This paper discusses the influence of the processing parameters on as-sprayed coating qualities. The paper also discusses the effect of thermal cycling on silicon samples in an inert helium atmosphere. The diffraction spectrum for a sample that experienced a 1600degC temperature cycle indicated that more than 99% of the coating transformed to β-SiC. The silicon coatings protected the graphite substrates from oxidation in one experiment. (orig.)

Comparisons of some scattering theories with recent scatterometer measurements. [sea roughness radar model

Science.gov (United States)

Fung, A. K.; Dome, G.; Moore, R. K.

1977-01-01

The paper compares the predictions of two different types of sea scatter theories with recent scatterometer measurements which indicate the variations of the backscattering coefficient with polarization, incident angle, wind speed, and azimuth angle. Wright's theory (1968) differs from that of Chan and Fung (1977) in two major aspects: (1) Wright uses Phillips' sea spectrum (1966) while Chan and Fung use that of Mitsuyasu and Honda, and (2) Wright uses a modified slick sea slope distribution by Cox and Munk (1954) while Chan and Fung use the slick sea slope distribution of Cox and Munk defined with respect to the plane perpendicular to the look direction. Satisfactory agreements between theory and experimental data are obtained when Chan and Fung's model is used to explain the wind and azimuthal dependence of the scattering coefficient.

Meteorological buoy measurements in the Iceland Sea, 2007-2009

Science.gov (United States)

Nína Petersen, Guðrún

2017-10-01

The Icelandic Meteorological Office (IMO) conducted meteorological buoy measurements in the central Iceland Sea in the time period 2007-2009, specifically in the northern Dreki area on the southern segment of the Jan Mayen Ridge. Due to difficulties in deployment and operations, in situ measurements in this region are sparse. Here the buoy, deployment and measurements are described with the aim of giving a future user of the data set information that is as comprehensive as possible. The data set has been quality-checked, suspect data removed and the data set made publicly available from PANGAEA Data Publisher (PANGAEA.876206" target="_blank">https://doi.org/10.1594/PANGAEA.876206).

Ocean Color Measurements from Landsat-8 OLI using SeaDAS

Science.gov (United States)

Franz, Bryan Alden; Bailey, Sean W.; Kuring, Norman; Werdell, P. Jeremy

2014-01-01

The Operational Land Imager (OLI) is a multi-spectral radiometer hosted on the recently launched Landsat-8 satellite. OLI includes a suite of relatively narrow spectral bands at 30-meter spatial resolution in the visible to shortwave infrared that make it a potential tool for ocean color radiometry: measurement of the reflected spectral radiance upwelling from beneath the ocean surface that carries information on the biogeochemical constituents of the upper ocean euphotic zone. To evaluate the potential of OLI to measure ocean color, processing support was implemented in SeaDAS, which is an open-source software package distributed by NASA for processing, analysis, and display of ocean remote sensing measurements from a variety of satellite-based multi-spectral radiometers. Here we describe the implementation of OLI processing capabilities within SeaDAS, including support for various methods of atmospheric correction to remove the effects of atmospheric scattering and absorption and retrieve the spectral remote-sensing reflectance (Rrs; sr exp 1). The quality of the retrieved Rrs imagery will be assessed, as will the derived water column constituents such as the concentration of the phytoplankton pigment chlorophyll a.

Plasma spraying process of disperse carbides for spraying and facing

International Nuclear Information System (INIS)

Blinkov, I.V.; Vishnevetskaya, I.A.; Kostyukovich, T.G.; Ostapovich, A.O.

1989-01-01

A possibility to metallize carbides in plasma of impulsing capacitor discharge is considered. Powders granulation occurs during plasma spraying process, ceramic core being completely capped. X-ray phase and chemical analyses of coatings did not show considerable changes of carbon content in carbides before and after plasma processing. This distinguishes the process of carbides metallization in impulsing plasma from the similar processing in arc and high-frequency plasma generator. Use of powder composites produced in the impulsing capacitor discharge, for plasma spraying and laser facing permits 2-3 times increasing wear resistance of the surface layer as against the coatings produced from mechanical powders mixtures

Alignment Fixtures For Vacuum-Plasma-Spray Gun

Science.gov (United States)

Woodford, William H.; Mckechnie, Timothy N.; Power, Christopher A.; Daniel, Ronald L., Jr.

1993-01-01

Fixtures for alignment of vacuum-plasma-spray guns built. Each fixture designed to fit specific gun and holds small, battery-powered laser on centerline of gun. Laser beam projects small red dot where centerline intersects surface of workpiece to be sprayed. After laser beam positioned on surface of workpiece, fixture removed from gun and spraying proceeds.

Fractal analysis of agricultural nozzles spray

Directory of Open Access Journals (Sweden)

Francisco Agüera

2012-02-01

Full Text Available Fractal scaling of the exponential type is used to establish the cumulative volume (V distribution applied through agricultural spray nozzles in size x droplets, smaller than the characteristic size X. From exponent d, we deduced the fractal dimension (Df which measures the degree of irregularity of the medium. This property is known as 'self-similarity'. Assuming that the droplet set from a spray nozzle is self-similar, the objectives of this study were to develop a methodology for calculating a Df factor associated with a given nozzle and to determine regression coefficients in order to predict droplet spectra factors from a nozzle, taking into account its own Df and pressure operating. Based on the iterated function system, we developed an algorithm to relate nozzle types to a particular value of Df. Four nozzles and five operating pressure droplet size characteristics were measured using a Phase Doppler Particle Analyser (PDPA. The data input consisted of droplet size spectra factors derived from these measurements. Estimated Df values showed dependence on nozzle type and independence of operating pressure. We developed an exponential model based on the Df to enable us to predict droplet size spectra factors. Significant coefficients of determination were found for the fitted model. This model could prove useful as a means of comparing the behavior of nozzles which only differ in not measurable geometric parameters and it can predict droplet spectra factors of a nozzle operating under different pressures from data measured only in extreme work pressures.

Characteristics of wetting temperature during spray cooling

International Nuclear Information System (INIS)

Mitsutake, Yuichi; Monde, Masanori; Hidaka, Shinichirou

2006-01-01

An experimental study has been done to elucidate the effects of mass flux and subcooling of liquid and thermal properties of solid on the wetting temperature during cooling of a hot block with spray. A water spray was impinged at one of the end surfaces of a cylindrical block initially heated at 400 or 500degC. The experimental condition was mass fluxes G=1-9 kg/m 2 s and degrees of subcooling ΔT sub =20, 50, 80 K. Three blocks of copper, brass and carbon steel were prepared. During spray cooling internal block temperature distribution and sputtering sound pressure level were recorded and the surface temperature and heat flux were evaluated with 2D inverse heat conducting analysis. Cooling process on cooling curves is divided into four regimes categorized by change in a flow situation and the sound level. The wetting temperature defined as the wall temperature at a minimum heat flux point was measured over an extensive experimental range. The wetting wall temperature was correlated well with the parameter of GΔT sub . The wetting wall temperature increases as GΔT sub increases and reaches a constant value depending on the material of the surface at higher region of GΔT sub . (author)

Development and Preliminary Evaluation of a Spray Deposition Sensing System for Improving Pesticide Application.

Science.gov (United States)

Kesterson, Melissa A; Luck, Joe D; Sama, Michael P

2015-12-17

An electronic, resistance-based sensor array and data acquisition system was developed to measure spray deposition from hydraulic nozzles. The sensor surface consisted of several parallel tin plated copper traces of varying widths with varying gap widths. The system contained an embedded microprocessor to monitor output voltage corresponding to spray deposition every second. In addition, a wireless module was used to transmit the voltage values to a remote laptop. Tests were conducted in two stages to evaluate the performance of the sensor array in an attempt to quantify the spray deposition. Initial tests utilized manual droplet placement on the sensor surface to determine the effects of temperature and droplet size on voltage output. Secondary testing utilized a spray chamber to pass nozzles at different speeds above the sensor surface to determine if output varied based on different application rates or spray droplet classification. Results from this preliminary analysis indicated that manual droplets of 5 and 10 μL resulted in significantly different values from the sensors while temperature did not consistently affect output. Spray chamber test results indicated that different application rates and droplet sizes could be determined using the sensor array.

Tungsten/copper composite deposits produced by a cold spray

International Nuclear Information System (INIS)

Kang, Hyun-Ki; Kang, Suk Bong

2003-01-01

An agglomerated tungsten/copper composite powder was both cold sprayed and plasma sprayed onto a mild steel substrate for electronic package applications. Most pores resulting from the spraying were found in the vicinity of the tungsten-rich regions of the final product. The levels of porosity varied with the amount of tungsten present. No copper oxidation was found at the cold-sprayed deposit, but relatively high copper oxidation was observed at the plasma-sprayed deposit

New trends in the kitchen: propellants assessment of edible food aerosol sprays used on food.

Science.gov (United States)

Varlet, V; Smith, F; Augsburger, M

2014-01-01

New products available for food creations include a wide variety of "supposed" food grade aerosol sprays. However, the gas propellants used cannot be considered as safe. The different legislations available did not rule any maximum residue limits, even though these compounds have some limits when used for other food purposes. This study shows a preliminary monitoring of propane, butane and dimethyl ether residues, in cakes and chocolate after spraying, when these gases are used as propellants in food aerosol sprays. Release kinetics of propane, butane and dimethyl ether were measured over one day with sprayed food, left at room temperature or in the fridge after spraying. The alkanes and dimethyl ether analyses were performed by headspace-gas chromatography-mass spectrometry/thermal conductivity detection, using monodeuterated propane and butane generated in situ as internal standards. According to the obtained results and regardingthe extrapolations of the maximum residue limits existing for these substances, different delays should be respected according to the storage conditions and the gas propellant to consume safely the sprayed food. Copyright © 2013 Elsevier Ltd. All rights reserved.

76 FR 2027 - Fisheries of the Exclusive Economic Zone Off Alaska; Steller Sea Lion Protection Measures for the...

Science.gov (United States)

2011-01-12

.... 101006495-0498-01] RIN 0648-BA31 Fisheries of the Exclusive Economic Zone Off Alaska; Steller Sea Lion... 13, 2010, to implement Steller sea lion protection measures to ensure that the Bering Sea and... existence of the western distinct population segment of Steller sea lions or adversely modify its designated...

75 FR 77535 - Fisheries of the Exclusive Economic Zone Off Alaska; Steller Sea Lion Protection Measures for the...

Science.gov (United States)

2010-12-13

... (Steller sea lion sites). A lottery system assigned vessels to platoons that were allowed to fish inside.... 101006495-0498-01] RIN 0648-BA31 Fisheries of the Exclusive Economic Zone Off Alaska; Steller Sea Lion... sea lion protection measures to insure that the Bering Sea and Aleutian Islands management area (BSAI...

Sprayed concrete linings

Energy Technology Data Exchange (ETDEWEB)

Hindle, D.

1999-12-01

Sprayed concrete, or shotcrete, was invented in the 1920s for preserving dinosaur skeletons and was used underground initially in coalmines for the preservation and fine proofing of timber supports. Its use as a support lining in rock tunnelling was developed in the 1950s and 60s. The article surveys equipment available from major manufacturers and suppliers of concrete spraying equipment (Aliva, Cifa, GIA, Industri, Ingersoll Rand, etc.), specialist cement and additive manufacturers (Castle, Cement, Moria Carbotech). manufacturers of lattice girders and fibre reinforcement, and manufacturers of instrumentation for tunnel linings. 5 tabs., 9 photos.

Thermal Diffusivity Measurement for Thermal Spray Coating Attached to Substrate Using Laser Flash Method

Science.gov (United States)

Akoshima, Megumi; Tanaka, Takashi; Endo, Satoshi; Baba, Tetsuya; Harada, Yoshio; Kojima, Yoshitaka; Kawasaki, Akira; Ono, Fumio

2011-11-01

Ceramic-based thermal barrier coatings are used as heat and wear shields of gas turbine blades. There is a strong need to evaluate the thermal conductivity of coating for thermal design and use. The thermal conductivity of a bulk material is obtained as the product of thermal diffusivity, specific heat capacity, and density above room temperature in many cases. Thermal diffusivity and thermal conductivity are unique for a given material because they are sensitive to the structure of the material. Therefore, it is important to measure them in each sample. However it is difficult to measure the thermal diffusivity and thermal conductivity of coatings because coatings are attached to substrates. In order to evaluate the thermal diffusivity of a coating attached to the substrate, we have examined the laser flash method with the multilayer model on the basis of the response function method. We carried out laser flash measurements in layered samples composed of a CoNiCrAlY bond coating and a 8YSZ top coating by thermal spraying on a Ni-based superalloy substrate. It was found that the procedure using laser flash method with the multilayer model is useful for the thermal diffusivity evaluation of a coating attached to a substrate.

Computational Analysis of Spray Jet Flames

Science.gov (United States)

Jain, Utsav

There is a boost in the utilization of renewable sources of energy but because of high energy density applications, combustion will never be obsolete. Spray combustion is a type of multiphase combustion which has tremendous engineering applications in different fields, varying from energy conversion devices to rocket propulsion system. Developing accurate computational models for turbulent spray combustion is vital for improving the design of combustors and making them energy efficient. Flamelet models have been extensively used for gas phase combustion because of their relatively low computational cost to model the turbulence-chemistry interaction using a low dimensional manifold approach. This framework is designed for gas phase non-premixed combustion and its implementation is not very straight forward for multiphase and multi-regime combustion such as spray combustion. This is because of the use of a conserved scalar and various flamelet related assumptions. Mixture fraction has been popularly employed as a conserved scalar and hence used to parameterize the characteristics of gaseous flamelets. However, for spray combustion, the mixture fraction is not monotonic and does not give a unique mapping in order to parameterize the structure of spray flames. In order to develop a flamelet type model for spray flames, a new variable called the mixing variable is introduced which acts as an ideal conserved scalar and takes into account the convection and evaporation of fuel droplets. In addition to the conserved scalar, it has been observed that though gaseous flamelets can be characterized by the conserved scalar and its dissipation, this might not be true for spray flamelets. Droplet dynamics has a significant influence on the spray flamelet and because of effects such as flame penetration of droplets and oscillation of droplets across the stagnation plane, it becomes important to accommodate their influence in the flamelet formulation. In order to recognize the

Imaging diagnostics of ethanol port fuel injection sprays for automobile engine applications

International Nuclear Information System (INIS)

Padala, Srinivas; Le, Minh Khoi; Kook, Sanghoon; Hawkes, Evatt R.

2013-01-01

This paper presents characteristics of ethanol sprays at port fuel injection (PFI) conditions with variations in injection and ambient parameters. Details of temporal and spatial development of ethanol PFI sprays are studied using Mie-scattering and high-speed shadowgraph imaging techniques. Momentum flux-based injection rate measurement is also performed. The influences of fuel flow-rate, injection duration, and ambient air cross-flow are of particular interest in an effort to understand ethanol PFI spray characteristics that are relevant to automobile engines. For comparison purposes, the results from gasoline fuel are also presented. Ethanol flow-rate effects are studied using two injectors with different nozzle-hole sizes at a fixed injection pressure. From the experiments, it was found that the actual injection duration was longer for the higher flow-rate injector although an electronic pulse width was fixed. This was due to an extended delay in the injector needle closing as the flow resistance against the needle was increased for the high flow-rate injector. For liquid droplets, the larger hole size of the higher flow-rate injector caused a higher mean droplet diameter and higher number of droplets. Injection duration was also varied to study transient spray behaviour: short-injection sprays with the end-of-injection transient dominating the overall spray development were compared to long, steady-injection sprays. From Mie-scattering images, the number of droplets and mean droplet diameter were found to be less for the short injection sprays. Detailed analysis using an axial profile of the number of droplets and mean droplet diameter suggested that the observed trends were a result of increased evaporation rate near the nozzle after the end of injection. This was consistent with shadowgraph images showing no liquid regions but only the vapour-phase fuel near the nozzle. Under the influence of ambient air cross-flow, both mean droplet diameter and number of

Stresses in plasma-sprayed Cr2O3 coatings measured by neutron diffraction

Czech Academy of Sciences Publication Activity Database

Dubský, Jiří; Prask, H. J.; Matějíček, Jiří; Gnäupel-Herold, T.

2002-01-01

Roč. 75, - (2002), s. 1-3 ISSN 0947-8396. [International Conference on Neutron Scattreing. Munich, 09.08.2001-13.08.2002] R&D Projects: GA ČR GA106/01/0094 Institutional research plan: CEZ:AV0Z2043910 Keywords : plasma sprayed, diffraction Subject RIV: JK - Corrosion ; Surface Treatment of Materials Impact factor: 2.231, year: 2002

Optimization of the spray application technology in bay laurel (Laurus nobilis).

Science.gov (United States)

Nuyttens, D; Braekman, P; Foque, D

2009-01-01

Bay laurel is an evergreen, commercially grown and expensive ornamental pot plant, which is susceptible to different pests like aphids, scale and lerp insects, thrips, caterpillars of codling moth and sooty moulds. Recently, caterpillars of the Mediterranean carnation leafroller (Cacoecimorpha pronubana) cause more and more problems. These pests can lead to important financial losses for the growers. During summer the individual pot plants are placed on a field-container in a fairly dense configuration. Crop protection is traditionally done by moving with a spray lance between the rows of pot plants and treating each individual plant from bottom to top. Good penetration is clearly an important advantages of this spray technique but it is very time-consuming, unhealthy and laborious. Some other growers use a 'spray platform' on a high-clearance tractor. Plants sprayed from this platform are exclusively approached from above resulting in an inferior spray deposition on the lower parts of the plants. To overcome the disadvantages of both available techniques, the potential of an automated tunnel sprayer was investigated. Five different nozzle types were evaluated under laboratory conditions i.e. hollow cone, standard flat fan, air inclusion flat fan, deflector flat fan and twin air inclusion flat fan at spray pressures varying from 3.0 to 7.0 bar depending on the type of nozzle. For each nozzle type, three nozzle sizes were included in the experiments which resulted in 15 different spray application techniques. All experiments were done at a speed of 2.5 km x h(-1). This resulted in three different application volumes: 2450, 4900 and 7300 l x ha(-1). After optimizing the nozzle configuration (distance and orientation) using water-sensitive paper, deposition tests with five different mineral chelates as tracer elements were performed. Filter papers were used as collectors at 20 different positions to measure spray deposition, distribution and penetration in the canopy

PTV analysis of the entrained air into the diesel spray at high-pressure injection

Science.gov (United States)

Toda, Naoki; Yamashita, Hayato; Mashida, Makoto

2014-08-01

In order to clarify the effect of high-pressure injection on soot reduction in terms of the air entrainment into spray, the air flow surrounding the spray and set-off length indicating the distance from the nozzle tip to the flame region in diffusion diesel combustion were investigated using 300MPa injection of a multi-hole injector. The measurement of the air entrainment flow was carried out at non-evaporating condition using consecutive PTV (particle tracking velocimetry) method with a high-speed camera and a high-frequency pulse YAG laser. The set-off length was measured at highpressure and high-temperature using the combustion bomb of constant volume and optical system of shadow graph method. And the amount of air entrainment into spray until reaching set-off length in diffusion combustion was studied as a factor of soot formation.

Plasma sprayed coatings on crankshaft used steels

Science.gov (United States)

Mahu, G.; Munteanu, C.; Istrate, B.; Benchea, M.

2017-08-01

Plasma spray coatings may be an alternative to conventional heat treatment of main journals and crankpins of the crankshaft. The applications of plasma coatings are various and present multiple advantages compared to electric arc wire spraying or flame spraying. The study examines the layers sprayed with the following powders: Cr3C2- 25(Ni 20Cr), Al2O3- 13TiO2, Cr2O3-SiO2- TiO2 on the surface of steels used in the construction of a crankshaft (C45). The plasma spray coatings were made with the Spray wizard 9MCE facility at atmospheric pressure. The samples were analyzed in terms of micro and morphological using optical microscopy, scanning electron microscopy and X-ray diffraction. Wear tests on samples that have undergone simulates extreme working conditions of the crankshafts. In order to emphasize adherence to the base material sprayed layer, were carried out tests of microscratches and micro-indentation. Results have showed a relatively compact morphological aspect given by the successive coatings with splat-like specific structures. Following the microscratch analysis it can be concluded that Al2O3-13TiO2 coating has a higher purpose in terms of hardness compared to Cr3C2-(Ni 20Cr) and Cr2O3-SiO2- TiO2 powders. Thermal coatings of the deposited powders have increased the mechanical properties of the material. The results stand to confirm that plasma sprayed Al2O3-13TiO2 powder is in fact a efficient solution for preventing mechanical wear, even with a faulty lubrication system.

To spray or not to spray? Understanding participation in an indoor residual spray campaign in Arequipa, Peru.

Science.gov (United States)

Paz-Soldán, Valerie A; Bauer, Karin M; Hunter, Gabrielle C; Castillo-Neyra, Ricardo; Arriola, Vanessa D; Rivera-Lanas, Daniel; Rodriguez, Geoffrey H; Toledo Vizcarra, Amparo M; Mollesaca Riveros, Lina M; Levy, Michael Z; Buttenheim, Alison M

2018-01-01

Current low participation rates in vector control programmes in Arequipa, Peru complicate the control of Chagas disease. Using focus groups (n = 17 participants) and semi-structured interviews (n = 71) conducted in March and May 2013, respectively, we examined barriers to and motivators of household participation in an indoor residual spray (IRS) campaign that had taken place one year prior in Arequipa. The most common reported barriers to participation were inconvenient spray times due to work obligations, not considering the campaign to be necessary, concerns about secondary health impacts (e.g. allergic reactions to insecticides), and difficulties preparing the home for spraying (e.g. moving heavy furniture). There was also a low perception of risk for contracting Chagas disease that might affect participation. The main motivator to participate was to ensure personal health and well-being. Future IRS campaigns should incorporate more flexible hours, including weekends; provide appropriate educational messages to counter concerns about secondary health effects; incorporate peer educators to increase perceived risk to Chagas in community; obtain support from community members and leaders to build community trust and support for the campaign; and assist individuals in preparing their homes. Enhancing community trust in both the need for the campaign and its operations is key.

Injector spray characterization of methanol in reciprocating engines

Science.gov (United States)

Dodge, L.; Naegeli, D.

1994-06-01

This report covers a study that addressed cold-starting problems in alcohol-fueled, spark-ignition engines by using fine-spray port-fuel injectors to inject fuel directly into the cylinder. This task included development and characterization of some very fine-spray, port-fuel injectors for a methanol-fueled spark-ignition engine. After determining the spray characteristics, a computational study was performed to estimate the evaporation rate of the methanol fuel spray under cold-starting and steady-state conditions.

Spatially-resolved, three-dimensional spray characterization of impinging jets by digital in-line holography

Science.gov (United States)

Gao, Jian; Rodrigues, Neil; Sojka, Paul; Chen, Jun

2014-11-01

The impinging jet injector is a preferred method for the atomization of liquid rocket propellants. The majority of experimental studies in literature are not spatially-resolved due to the limitations of widely available point-wise and two-dimensional (2D) diagnostic techniques such as phase Doppler anemometry (PDA), which requires significant experimental repetitions to give spatially-resolved measurements. In the present study, digital in-line holography (DIH) is used to provide spatially-resolved, three-dimensional (3D) characteristics of impinging jet sprays. A double-exposure DIH setup is configured to measure droplet 3D, three-component velocity as well as the size distribution. The particle information is extracted by the hybrid method, which is recently proposed as a particle detection method. To enlarge the detection volume, two parallel, collimated laser beams are used to simultaneously probe the spray at two locations, and two identical cameras are used to record the corresponding holograms. Such a setup has a detection volume of approximately 20 cm by 3.6 cm by 4.8 cm. Sprays of both Newtonian and non-Newtonian liquids corresponding to regimes at relatively lower jet Reynolds and Weber numbers are investigated. Measurements from DIH are further verified by comparison with experimental data obtained from shadowgraph and PDA. It is revealed that DIH is particularly suitable to provide spatially-resolved, 3D measurements of impinging jet sprays that are not particularly dense.

A three-color absorption/scattering imaging technique for simultaneous measurements on distributions of temperature and fuel concentration in a spray

Science.gov (United States)

Qi, Wenyuan; Zhang, Yuyin

2018-04-01

A three-color imaging technique was proposed for simultaneous measurements on distributions of fuel/air mixture temperature and fuel vapor/liquid concentrations in evaporating sprays. The idea is based on that the vapor concentration is proportional to the absorption of vapor to UV light, the liquid-phase concentration is related to the light extinction due to scattering of droplet to visible light, and the mixture temperature can be correlated to the absorbance ratio at two absorbing wavelengths or narrow bands. For verifying the imaging system, the molar absorption coefficients of p-xylene at the three narrow bands, which were centered respectively at 265, 289, and 532 nm with FWHM of 10 nm, were measured in a specially designed calibration chamber at different temperatures (423-606 K) and pressure of 3.6 bar. It was found that the ratio of the molar absorption coefficients of p-xylene at the two narrow bands centered at the two UV wavelengths is sensitive to the mixture temperature. On the other hand, the distributions of fuel vapor/liquid concentrations can be obtained by use of absorbance due to ultraviolet absorption of vapor and visible light scattering of droplets. Combining these two methods, a simultaneous measurement on distributions of mixture temperature and fuel vapor/liquid concentrations can be realized. In addition, the temperature field obtained from the ratio of the two absorbing narrow bands can be further used to improve the measurement accuracy of vapor/liquid concentrations, because the absorption coefficients depend on temperature. This diagnostic was applied to an evaporating spray inside a high-temperature and high-pressure constant volume chamber.

Impact of organic fertilizer, humic acid and sea weed extract on wheat production in pothowar region of pakistan

International Nuclear Information System (INIS)

Muhammad, S.; Anjum, A.S.; Kasana, M.I.

2013-01-01

Wheat (Triticum aestivum L) crop production was evaluated under organic conditions during the year 2008-09 and 2009-2010 at National Agricultural Research Center (NARC), Pakistan Agricultural Research council (PARC) Islamabad. The study includes four treatments with four replications. The treatments includes; (1) Organic fertilizer 625 Kg ha/sup -1/, (2) Organic fertilizer 625 and Humic Acid 10 Kg ha/sup -1/ (3) Humic Acid and Sea weed extract 625 ml ha/sup -1/ and (4) Control. Organic amendments were incorporated during land preparation and seaweed extract as foliar spray. The basal dose of organic fertilizer and humic acid (granule) were added at the time of sowing of wheat during 2008-2009 and 2009-2010.Humic acid solution 1% and sea weed extract were applied as foliar spray at 6 inches of wheat crop. The second foliar spray was done at tillering while third and forth sprays at heading and milking stage respectively. The crop conditions, color, shoot length and spike and yield parameters were recorded at different stages of the organic fertilizer application. The soils and crops managed organically are sustainable. Similarly, biological and chemical properties of soil also improved significantly. The compost enriched with different organic waste increased all physico-chemical and biological properties of the soil as well as yield of the crop. The wheat crop morphological and agronomical parameters also increase significantly. Moreover, nutrients supply and other soil properties like pH, CEC, ECe and plant nutrients including microbial community structure influence positively. (author)

Spray Modeling for Outwardly-Opening Hollow-Cone Injector

KAUST Repository

Sim, Jaeheon

2016-04-05

The outwardly-opening piezoelectric injector is gaining popularity as a high efficient spray injector due to its precise control of the spray. However, few modeling studies have been reported on these promising injectors. Furthermore, traditional linear instability sheet atomization (LISA) model was originally developed for pressure swirl hollow-cone injectors with moderate spray angle and toroidal ligament breakups. Therefore, it is not appropriate for the outwardly-opening injectors having wide spray angles and string-like film structures. In this study, a new spray injection modeling was proposed for outwardly-opening hollow-cone injector. The injection velocities are computed from the given mass flow rate and injection pressure instead of ambiguous annular nozzle geometry. The modified Kelvin-Helmholtz and Rayleigh-Taylor (KH-RT) breakup model is used with adjusted initial Sauter mean diameter (SMD) for modeling breakup of string-like structure. Spray injection was modeled using a Lagrangian discrete parcel method within the framework of commercial CFD software CONVERGE, and the new model was implemented through the user-defined functions. A Siemens outwardly-opening hollow-cone spray injector was characterized and validated with existing experimental data at the injection pressure of 100 bar. It was found that the collision modeling becomes important in the current injector because of dense spray near nozzle. The injection distribution model showed insignificant effects on spray due to small initial droplets. It was demonstrated that the new model can predict the liquid penetration length and local SMD with improved accuracy for the injector under study.

UNA REVISIÓN DEL SPRAY TÉRMICO COMO TÉCNICA DE DEPOSICIÓN PARA CAPAS DE BARRERAS TÉRMICAS // THE THERMAL SPRAY AS A DEPOSITION TECHNIQUE FOR THERMAL BARRIER COATING: A REVIEW

Directory of Open Access Journals (Sweden)

Eduardo Rondón Briceño

2015-06-01

Full Text Available It is important to know the thermal barrier deposition techniques since materials with low thermal conductivity in the barrier can be obtained from them. The dependence of the thermal conductivity with the temperature can be divided into four regions. In this work, we were interested in the study of used techniques for the manufacture of materials with a desirable low thermal conductivity that will be exposed to high temperatures that is to say, materials found in the III and IV region. In these regions the thermal conductivity can be reduced increasing the porosity of the material. Through the study of the thermal barrier deposition techniques we found that the thermal spray produces a coat with high porosity, being the low velocity flame spray technique the best to produce coat of La2Zr2O7 with a minimal thermal conductivity. The thermal spray technique is low cost and almost any material can be thermally sprayed, so this can be considered a very attractive technique for industrial applications. // RESUMEN Es importante conocer las técnicas de deposición de barreras térmicas ya que de ellas depende la obtención de materiales con baja conductividad térmica en la barrera. La dependencia de la conductividad térmica con la temperatura puede dividirse en cuatro regiones. En este trabajo estuvimos interesados en el estudio de las técnicas que se utilizan para la fabricación de materiales sometidos a muy altas temperaturas y donde se desea que su conductividad térmica sea baja, es decir, materiales que se encuentran en la región III y IV. En estas regiones se puede disminuir la conductividad térmica aumentando la porosidad del material. A través del estudio de las técnicas de deposición de barreras térmica, hemos encontrado que la técnica del spray térmico produce una alta porosidad en el recubrimiento, siendo el método de rociado con baja velocidad el mejor método para producir capas de La2Zr2O7 con mínima conductividad t

Sea ice local surface topography from single-pass satellite InSAR measurements: a feasibility study

Directory of Open Access Journals (Sweden)

W. Dierking

2017-08-01

Full Text Available Quantitative parameters characterizing the sea ice surface topography are needed in geophysical investigations such as studies on atmosphere–ice interactions or sea ice mechanics. Recently, the use of space-borne single-pass interferometric synthetic aperture radar (InSAR for retrieving the ice surface topography has attracted notice among geophysicists. In this paper the potential of InSAR measurements is examined for several satellite configurations and radar frequencies, considering statistics of heights and widths of ice ridges as well as possible magnitudes of ice drift. It is shown that, theoretically, surface height variations can be retrieved with relative errors  ≤  0.5 m. In practice, however, the sea ice drift and open water leads may contribute significantly to the measured interferometric phase. Another essential factor is the dependence of the achievable interferometric baseline on the satellite orbit configurations. Possibilities to assess the influence of different factors on the measurement accuracy are demonstrated: signal-to-noise ratio, presence of a snow layer, and the penetration depth into the ice. Practical examples of sea surface height retrievals from bistatic SAR images collected during the TanDEM-X Science Phase are presented.

Process-based quality for thermal spray via feedback control

Science.gov (United States)

Dykhuizen, R. C.; Neiser, R. A.

2006-09-01

Quality control of a thermal spray system manufacturing process is difficult due to the many input variables that need to be controlled. Great care must be taken to ensure that the process remains constant to obtain a consistent quality of the parts. Control is greatly complicated by the fact that measurement of particle velocities and temperatures is a noisy stochastic process. This article illustrates the application of quality control concepts to a wire flame spray process. A central feature of the real-time control system is an automatic feedback control scheme that provides fine adjustments to ensure that uncontrolled variations are accommodated. It is shown how the control vectors can be constructed from simple process maps to independently control particle velocity and temperature. This control scheme is shown to perform well in a real production environment. We also demonstrate that slight variations in the feed wire curvature can greatly influence the process. Finally, the geometry of the spray system and sensor must remain constant for the best reproducibility.

The feasibility study of hot cell decontamination by the PFC spray method

International Nuclear Information System (INIS)

Hui-Jun Won; Chong-Hun Jung; Jei-Kwon Moon

2008-01-01

module. A performance test on each module was executed and the results have been reported. A combined test of the four modules, however, has not been performed as yet. The main objective of the present study is to demonstrate the feasibility of the full PFC spray decontamination process. Decontamination of the inside of the IMEF hot cell by the PFC spray method was also performed. PFC spray decontamination process was demonstrated by using a surrogate wall contaminated with Eu 2 O 3 powder. The spray pressure was 41 kgf/cm 2 , the orifice diameter was 0.2 mm and the spray velocity was 0.2 L/min. And, the decontaminated area was 100 cm 2 . From previous test results, we found that the decontamination factor of the PFC spray method was in the range from 9.6 to 62.4. When the decontamination efficiency of Co-60 was high, then the decontamination efficiency of Cs-137 was also high. As the surface roughness of the specimen increased, the PFC spray decontamination efficiency decreased. Inferring from the previous results, the surface of the surrogate wall was cleaned by the PFC spray method. The vacuum cup of the collection module operated well and gathered more than 99 % of the PFC solution. Also, filtration and distillation modules operated well. All the filtered PFC solution flowed to the storage chamber where some of the PFC solution was distilled. The coolant of the distillation module was a dry ice. And, the recycled solution was transferred to the spray module by a high pressure pump. To evaluate the PFC spray decontamination efficiency, a smear device was fabricated and operated by a manipulator. Before and after decontamination, a smear test was performed. The tested area was 100 cm 2 and the radioactivity was estimated indirectly by measuring the radioactivity of the filter paper. The average decontamination factor was in the range between 10 and 15. One application time was 2 minutes. The sprayed PFC solution was collected by the vacuum cup and it was stored in the

Ketorolac Tromethamine Spray Prevents Postendotracheal-Intubation-Induced Sore Throat after General Anesthesia

Directory of Open Access Journals (Sweden)

H. L. Yang

2016-01-01

Full Text Available Background. Postoperative sore throat is one of the major complaints of general anesthesia in the postanesthesia care unit. This prospective study investigated the preventive effect of ketorolac tromethamine spray in postendotracheal-intubation-induced sore throat after general anesthesia. Methods. Surgical patients undergoing general anesthesia with endotracheal intubation were recruited from a medical center. Patients were randomly assigned to group K (treated with 5% ketorolac tromethamine spray or group D (treated with distilled water spray. Before intubation, each endotracheal tube was sprayed with the appropriate solution by physicians over the 20 cm length of the cuff. Each group comprised 95 patients fitting the inclusion and exclusion criteria for whom complete data sets were collected. The intensity of the sore throat was measured at 1, 3, 6, and 24 h after surgery, and data were compared. Results. The two groups had similar characteristics. Postoperative sore throat was significantly less frequent in group K than in group D (p<0.001 and the pain intensity was significantly lower in group K than in group D at each time point (all p<0.001. Conclusions. This study demonstrated that preanesthesia 5% ketorolac tromethamine spray could effectively decrease postendotracheal-intubation-induced sore throat in patients undergoing general anesthesia.

Water Spray Flow Characteristics Under Synthetic Jet Driven By a Piezoelectric Actuator

Science.gov (United States)

Marchitto, L.; Valentino, G.; Chiatto, M.; de Luca, L.

2017-01-01

Particle Image Velocimetry (PIV) and Phase Doppler Anemometry (PDA) have been applied to investigate the droplets size and velocity distribution of a water spray, under the control of a piezo-element driven synthetic jet (SJ). Tests were carried out under atmospheric conditions within a chamber test rig equipped with optical accesses at two injection pressures, namely 5 and 10 MPa, exploring the variation of the main spray parameters caused by the synthetic jet perturbations. The SJ orifice has been placed at 45° with respect to the water spray axis; the nozzle body has been moved on its own axis and three different nozzle quotes were tested. PIV measurements have been averaged on 300 trials whereas about 105 samples have been acquired for the PDA tests. For each operative condition, the influence region of the SJ device on the spray has been computed through a T-Test algorithm. The synthetic jet locally interacts with the spray, energizing the region downstream the impact. The effect of the actuator decreases at higher injection pressures and moving the impact region upwards. Droplets coalescence can be detected along the synthetic jet axis, while no significant variations are observed along a direction orthogonal to it.

Experimental investigation of water sprayed finned heat exchanger tube bundles

International Nuclear Information System (INIS)

Sommer, A.

1987-07-01

Experimental investigations have been made to study the performance of two finned tube-bundle heat exchangers (FORGO type) when wetted by water sprays. The heat exchangers are designed to cool water in a dry cooling tower. The test-elements had a frontal area of 1 m 2 . The water sprays were created by 20 nozzles, 200 mm in front of the heat exchangers. Air velocities at the inlet of the coolers were in the range 0,8 m/s to 12 m/s and initial temperature differences ITD reached 45 degrees C. The test facility was designed to determine the combined latent and sensible heat fluxes in the wetted heat exchanger, the airside pressure drop and the air humidity and temperature at the exchanger inlet and outlet, and to measure the weight of the water wetting the cooler's surface. The sprayed test elements were investigated in different positions, but most of the experiments were carried out in the position with the fins horizontal

Research of Plasma Spraying Process on Aluminum-Magnesium Alloy

Directory of Open Access Journals (Sweden)

Patricija Kavaliauskaitė

2016-04-01

Full Text Available The article examines plasma sprayed 95Ni-5Al coatings on alu-minum-magnesium (Mg ≈ 2,6‒3,6 % alloy substrate. Alumi-num-magnesium samples prior spraying were prepared with mechanical treatment (blasting with Al2O3. 95Ni-5Al coatings on aluminum-magnesium alloys were sprayed with different parameters of process and coating‘s thickness, porosity, micro-hardness and microstructure were evaluated. Also numerical simulations in electric and magnetic phenomena of plasma spray-ing were carried out.

Technology development of p-type microstrip detectors with radiation hard p-spray isolation

International Nuclear Information System (INIS)

Pellegrini, G.; Fleta, C.; Campabadal, F.; Diez, S.; Lozano, M.; Rafi, J.M.; Ullan, M.

2006-01-01

A technology for the fabrication of p-type microstrip silicon radiation detectors using p-spray implant isolation has been developed at CNM-IMB. The p-spray isolation has been optimized in order to withstand a gamma irradiation dose up to 50 Mrad (Si), which represents the ionization radiation dose expected in the middle region of the SCT-Atlas detector of the future Super-LHC during 10 years of operation. The best technological options for the p-spray implant were found by using a simulation software package and dedicated calibration runs. Using the optimized technology, detectors have been fabricated in the Clean Room facility of CNM-IMB, and characterized by reverse current and capacitance measurements before and after irradiation. The average full depletion voltage measured on the non-irradiated detectors was V FD =41±3 V, while the leakage current density for the microstrip devices at V FD +20 V was 400 nA/cm 2