Chalk Formations as Natural Barriers towards Radionuclide Migration

DEFF Research Database (Denmark)

Pedersen, Walther Batsberg; Carlsen, Lars; Jensen, Bror Skytte

1985-01-01

A series of chalk samples from the cretaceous formation overlying the Erslev salt dome have been studied in order to establish permeabilities, porosities, dispersion-, diffusion-, and sorption characteristics of the chalk. The chalk was found to be porous (∊≈0.4), however, of rather low...

Compaction of microfossil and clay-rich chalk sediments

DEFF Research Database (Denmark)

Fabricius, Ida Lykke

2001-01-01

The aim of this study was to evaluate the role of microfossils and clay in the compaction of chalk facies sediments. To meet this aim, chalk sediments with varying micro texture were studied. The sediments have been tested uniaxially confined in a stainless-steel compaction cell. The sediments are......: 1) Pure carbonate chalk with mudstone texture from Stevns Klint (Denmark), 2) Relatively pure chalk sediments with varying content of microfossils from the Ontong Java Plateau (Western Pacific), 3) Clay-rich chalk and mixed sediments from the Caribbean. The tested samples were characterised...

Nickel adsorption on chalk and calcite

DEFF Research Database (Denmark)

Belova, Dina Alexandrovna; Lakshtanov, Leonid; Carneiro, J.F.

2014-01-01

Nickel uptake from solution by two types of chalk and calcite was investigated in batch sorption studies. The goal was to understand the difference in sorption behavior between synthetic and biogenic calcite. Experiments at atmospheric partial pressure of CO2, in solutions equilibrated with calcite...... = - 1.12 on calcite and log KNi = - 0.43 and - 0.50 on the two chalk samples. The study confirms that synthetic calcite and chalk both take up nickel, but Ni binds more strongly on the biogenic calcite than on inorganically precipitated, synthetic powder, because of the presence of trace amounts...... of polysaccharides and clay nanoparticles on the chalk surface....

Productivity, facies and stable-isotope records of OAE2 (Cenomanian - Turonian) in the NW European epicontinental sea: from the English Chalk to North Sea black shales

Science.gov (United States)

Jarvis, Ian; Olde, Kate; Trabucho-Alexandre, João; Gröcke, Darren

2013-04-01

The Late Cretaceous (100.5 - 66.0 Ma) provides perhaps the best example of how the Earth System may function under long-term extreme greenhouse conditions. Rapidly rising global temperatures indicate that we are heading 'back to the Cretaceous' within a few hundred years, so a better understanding of this time interval is essential. The beginning of the Late Cretaceous was characterized by a period of rapidly rising eustatic sea level, the Cenomanian transgression, which flooded continental margins and established large areas of new epicontinental sea that accumulated thick sequences of pelagic and hemipelagic carbonate (chalk). Highest global temperatures were reached during the early part of the Turonian Stage (93.9 - 89.8 Ma). This period of dramatic palaeoenvironmental change was accompanied by one the largest perturbations of the global carbon cycle in the Mesozoic: Oceanic Anoxic Event 2 (OAE2), which was characterized by a 500 kyr episode of oceanic anoxia, widespread black shale deposition, biotic turnover, and a large global positive carbon stable-isotope excursion (2 - 6 ‰ ∂13C) recorded in marine carbonates and both marine and terrestrial organic matter. The Cenomanian-Turonian boundary interval exposed at Eastbourne, southern England, has become established as a European reference section for OAE2. Here, and elsewhere in Europe, the base of the ∂13C excursion is coincident with a marked facies change from rhythmically bedded grey chalks and marls, to a >8 m thick package of dark greenish-grey marl - the Plenus Marl. The termination of OAE2 occurs 6 m above, in a package of pale-yellow-weathering nodular chalks with prominent marl seams. Sediments are organic lean (10 wt%. The onshore equivalent in eastern England (the Black Band) is similarly organic-rich, as are comparable sections in northern Germany (e.g. Wunstorf), indicating likely fully anoxic episodes within some NW European basins. The exact stratigraphic equivalence between the onshore

Probing the intrinsically oil-wet surfaces of pores in North Sea chalk at subpore resolution

DEFF Research Database (Denmark)

Hassenkam, Tue; Skovbjerg, Lone Lindbæk; Stipp, Susan Louise Svane

2009-01-01

been drilled in a water-bearing formation. At this site, the chalk has never seen oil, though at other locations, the same stratigraphic horizon with the same rock properties is known to be a productive oil reservoir. Thus the properties of the investigated particle surfaces are inherent to the chalk......Ultimate Oil recovery from chalk reservoirs is limited by many factors - including the grain size and the surface properties of the small mainly biogenic calcite particles that chalk is made off . Wettability, the tendency for water or oil to spread over a surface, of the particle surfaces is one...... of the controlling factors for the effectiveness of water flooding, one of the most common methods to improve oil recovery in Chalk reservoirs. Understanding surface wetting and its variability at scales smaller than the pore dimension will potentially provide clues for more effective oil production methods. We used...

Water in chalk reservoirs: 'friend or foe?'

International Nuclear Information System (INIS)

Hjuler, Morten Leth

2004-01-01

Most of the petroleum fields in the Norwegian sector of the North Sea are sandstone reservoirs; the oil and gas are trapped in different species of sandstone. But the Ekofisk Field is a chalk reservoir, which really challenges the operator companies. When oil is produced from chalk reservoirs, water usually gets in and the reservoir subsides. The subsidence may be expensive for the oil companies or be used to advantage by increasing the recovery rate. Since 60 per cent of the world's petroleum reserves are located in carbonate reservoirs, it is important to understand what happens as oil and gas are pumped out. Comprehensive studies at the Department of Petroleum Technology and Applied Geophysics at Stavanger University College in Norway show that the mechanical properties of chalk are considerably altered when the pores in the rock become saturated with oil/gas or water under different stress conditions. The processes are extremely complex. The article also maintains that the effects of injecting carbon dioxide from gas power plants into petroleum reservoirs should be carefully studied before this is done extensively

Impact of supercritical CO2 injection on petrophysical and rock mechanics properties of chalk: an experimental study on chalk from South Arne field, North Sea

DEFF Research Database (Denmark)

Alam, Mohammad Monzurul; Hjuler, Morten Leth; Christensen, Helle Foged

2011-01-01

Changes in chalk due to EOR by injecting supercritical CO2 (CO2-EOR) can ideally be predicted by applying geophysical methods designed from laboratory-determined petrophysical and rock mechanics properties. A series of petrophysical and rock mechanics tests were performed on Ekofisk Formation...... and Tor Formation chalk of the South Arne field to reveal the changes in petrophysical and rock mechanics properties of chalk due to the injection of CO2 at supercritical state. An increase in porosity and decrease in specific surface was observed due to injection of supercritical CO2. This indicates...... as indicated by NMR T2 relaxation time was observed. Rock mechanics testing indicates that in 30% porosity chalk from the South Arne field, injection of supercritical CO2 has no significant effect on shear strength and compaction properties, while there is probably a slight decrease in stiffness properties...

Regional hardening of Upper Cretaceous Chalk in eastern England, UK: trace element and stable isotope patterns in the Upper Cenomanian and Turonian Chalk and their significance

Science.gov (United States)

Jeans, Christopher V.; Long, Dee; Hu, Xiu-Fang; Mortimore, Rory N.

2014-12-01

fluids, rich in sulphate and hydrocarbons, derived probably from the North Sea Basin. Microbial sulphate-reduction under anoxic conditions within these allochthonous fluids has been responsible for dissolving the fine-grained iron and manganese oxides within the chalk, locally enriching the Fe and Mn content of the calcite cement. The possibility is discussed that the pattern of cementation preserved in these regionally hard chalks of Late Cenomanian and Early Turonian age may be different from that preserved in the younger (late Turonian to Campanian) more basinal chalks of eastern England.

Waveform analysis of crosshole GPR data collected in heterogeneous chalk deposits

DEFF Research Database (Denmark)

Keskinen, Johanna; Nielsen, Lars; Zibar, Majken Caroline Looms

2014-01-01

Chalks are important reservoirs for groundwater production onshore Denmark and for hydrocarbons in the North Sea Basin. Therefore this rock type is studied extensively with geological and geophysical methods. Ground-penetrating radar (GPR) tomography is used to characterize fine-scale reservoir...

Rock physical aspects of CO{sub 2} injection in chalk

Energy Technology Data Exchange (ETDEWEB)

Alam, M.M.

2011-04-15

Impact of supercritical CO{sub 2} on the petrophysical and rock-mechanics properties of Ekofisk Formation and Tor Formation chalk from South Arne field, Danish North Sea, chalk was investigated. A series of laboratory experiments was performed on core material collected from the reservoir zone of the South Arne field in order to reveal the changes with respect to porosity, specific surface, pore stiffness, wettability, mineralogy and mechanical failure. In addition, a theoretical rock physical background was also established in order to be able to make sensible interpretation of laboratory data. Sound wave velocity was used as the central tool to study any change in petrophysical and rock mechanical properties. The main focus was to achieve a better understanding of effective stress coefficient (also known as Biot's coefficient); by means of which effective stress can be predicted more accurately. Independent theoretical studies were made on diagenesis, surface properties and stiffness of chalk and their relation with sonic velocity (or Biot's coefficient calculated from sonic velocity). The knowledge and experience from these studies was combined to achieve the main research objective of monitoring changes in hydrocarbon reservoirs in chalk due to CO{sub 2} injection. In order to understand the development of chalk from calcareous ooze and achieving pore stiffness, the diagenesis process of a sedimentary sequence from Kerguelen Plateau in the Indian Ocean was studied. The principal objective of the study was to explore how different porosity reduction mechanisms change the strength of these deep sea carbonate-rich sediments and how these mechanisms can be traced from the change in Biot's coefficient, alpha. In calcareous ooze, alpha was found close to one. Mechanical compaction reduces porosity, but only leads to a minor decrease in alpha. Recrystallization process renders particles smoother, but do not lead to reduction in alpha unless it gives

To What Degree Thermal Cycles Affect Chalk Strength

DEFF Research Database (Denmark)

Livada, Tijana; Nermoen, Anders; Korsnes, Reidar Inger

triaxial cell experiments. For dry rock, no significant effects of temperature cycling was found on average tensile strength, however the range of the tensile failure stress is doubled for the samples exposed to 50 temperature cycles, as opposed to those to none. For water saturated cores, the temperature......Chalk reservoirs could potentially undergo destabilization as the result of repeated cold water injection into a hot reservoir during water flooding. Preliminary results of an ongoing study are presented in this paper, which compare the impact of temperature cycling on mechanical behavior on dry...... and water saturated chalk. Sixty disks of dry Kansas chalk exposed to different number of temperature cycles were tested for tensile strength using a Brazilian test. Changes in elastic properties as function of number of temperature cycles of the same chalk, but now saturated in water, were studied using...

Stability analysis of chalk sea cliffs using UAV photogrammetry

Science.gov (United States)

Barlow, John; Gilham, Jamie

2017-04-01

Cliff erosion and instability poses a significant hazard to communities and infrastructure located is coastal areas. We use point cloud and spectral data derived from close range digital photogrammetry to assess the stability of chalk sea cliffs located at Telscombe, UK. Data captured from an unmanned aerial vehicle (UAV) were used to generate dense point clouds for a 712 m section of cliff face which ranges from 20 to 49 m in height. Generated models fitted our ground control network within a standard error of 0.03 m. Structural features such as joints, bedding planes, and faults were manually mapped and are consistent with results from other studies that have been conducted using direct measurement in the field. Kinematic analysis of these data was used to identify the primary modes of failure at the site. Our results indicate that wedge failure is by far the most likely mode of slope instability. An analysis of sequential surveys taken from the summer of 2016 to the winter of 2017 indicate several large failures have occurred at the site. We establish the volume of failure through change detection between sequential data sets and use back analysis to determine the strength of shear surfaces for each failure. Our results show that data capture through UAV photogrammetry can provide useful information for slope stability analysis over long sections of cliff. The use of this technology offers significant benefits in equipment costs and field time over existing methods.

Diagenetic Variations between Upper Cretaceous Outcrop and Deeply Buried Reservoir Chalks of the North Sea Area

DEFF Research Database (Denmark)

Hjuler, Morten Leth; Fabricius, Ida Lykke

2007-01-01

-particle connections and less altered particle shapes. The non-carbonate mineralogy of outcrop chalks is dominated by quartz, occasionally opal-CT and clinoptilolite, and the clay mineral smectite. In offshore chalks quartz still dominates, opal-CT has recrystallized into submicron-size quartz crystals and smectite...

New insight into the microtexture of chalks from NMR analysis

DEFF Research Database (Denmark)

Faÿ-Gomord, Ophélie; Soete, Jeroen; Katika, Konstantina

2016-01-01

An integrated petrographical and petrophysical study was carried out on a set of 35 outcrop chalk samples, covering a wide range of lithologies and textures. In this study various chalk rock-types have been characterized, in terms of microtextures and porous network, by integrating both geologica...

Trace elemental analysis of school chalk using energy dispersive X-ray florescence spectroscopy (ED-XRF)

International Nuclear Information System (INIS)

Maruthi, Y. A.; Das, N. Lakshmana; Ramprasad, S.; Ram, S. S.; Sudarshan, M.

2015-01-01

The present studies focus the quantitative analysis of elements in school chalk to ensure the safety of its use. The elements like Calcium (Ca), Aluminum (Al), Iron (Fe), Silicon (Si) and Chromium (Cr) were analyzed from settled chalk dust samples collected from five classrooms (CD-1) and also from another set of unused chalk samples collected from local market (CD-2) using Energy Dispersive X-Ray florescence(ED-XRF) spectroscopy. Presence of these elements in significant concentrations in school chalk confirmed that, it is an irritant and occupational hazard. It is suggested to use protective equipments like filtered mask for mouth, nose and chalk holders. This study also suggested using the advanced mode of techniques like Digital boards, marker boards and power point presentations to mitigate the occupational hazard for classroom chalk

Trace elemental analysis of school chalk using energy dispersive X-ray florescence spectroscopy (ED-XRF)

Energy Technology Data Exchange (ETDEWEB)

Maruthi, Y. A., E-mail: ymjournal2014@gmail.com [Associate professor, Dept of Environmental Studies, GITAM Institute of Science, GITAM University, Visakhapatnam, A.P (India); Das, N. Lakshmana, E-mail: nldas9@gmail.com [Professor, Dept of Physics, GITAM Institute of Science, GITAM University, Visakhapatnam, A.P (India); Ramprasad, S., E-mail: ramprasadsurakala@gmail.com [Research Scholar, Dept of Environmental science, GITAM Institute of Science, GITAM University, Visakhapatnam, A.P (India); Ram, S. S., E-mail: tracebio@gmail.com [Research Scholar, Dept of Trace element research, UGC-DAE Consortium Centre, Kolkata centre India (India); Sudarshan, M., E-mail: sude@alpha.iuc.res.in [Scientist-F, Dept of Trace element research, UGC-DAE Consortium Centre, Kolkata centre India (India)

2015-08-28

The present studies focus the quantitative analysis of elements in school chalk to ensure the safety of its use. The elements like Calcium (Ca), Aluminum (Al), Iron (Fe), Silicon (Si) and Chromium (Cr) were analyzed from settled chalk dust samples collected from five classrooms (CD-1) and also from another set of unused chalk samples collected from local market (CD-2) using Energy Dispersive X-Ray florescence(ED-XRF) spectroscopy. Presence of these elements in significant concentrations in school chalk confirmed that, it is an irritant and occupational hazard. It is suggested to use protective equipments like filtered mask for mouth, nose and chalk holders. This study also suggested using the advanced mode of techniques like Digital boards, marker boards and power point presentations to mitigate the occupational hazard for classroom chalk.

Full-waveform inversion of cross-hole GPR data collected in a strongly heterogeneous chalk reservoir analogue with sharp permittivity and conductivity contrasts

DEFF Research Database (Denmark)

Keskinen, Johanna; Zibar, Majken Caroline Looms; Moreau, Julien

2014-01-01

Chalk sediments form an important reservoir for groundwater onshore and for hydrocarbons in the Danish sector of the North Sea. Cross-hole Ground-penetrating radar (GPR) tomography is an efficient method to investigate subtle porosity variations in the chalk. Traditional ray-based inversion...

Delineating chalk sand distribution of Ekofisk formation using probabilistic neural network (PNN) and stepwise regression (SWR): Case study Danish North Sea field

Science.gov (United States)

Haris, A.; Nafian, M.; Riyanto, A.

2017-07-01

Danish North Sea Fields consist of several formations (Ekofisk, Tor, and Cromer Knoll) that was started from the age of Paleocene to Miocene. In this study, the integration of seismic and well log data set is carried out to determine the chalk sand distribution in the Danish North Sea field. The integration of seismic and well log data set is performed by using the seismic inversion analysis and seismic multi-attribute. The seismic inversion algorithm, which is used to derive acoustic impedance (AI), is model-based technique. The derived AI is then used as external attributes for the input of multi-attribute analysis. Moreover, the multi-attribute analysis is used to generate the linear and non-linear transformation of among well log properties. In the case of the linear model, selected transformation is conducted by weighting step-wise linear regression (SWR), while for the non-linear model is performed by using probabilistic neural networks (PNN). The estimated porosity, which is resulted by PNN shows better suited to the well log data compared with the results of SWR. This result can be understood since PNN perform non-linear regression so that the relationship between the attribute data and predicted log data can be optimized. The distribution of chalk sand has been successfully identified and characterized by porosity value ranging from 23% up to 30%.

Ekofisk chalk: core measurements, stochastic reconstruction, network modeling and simulation

Energy Technology Data Exchange (ETDEWEB)

Talukdar, Saifullah

2002-07-01

This dissertation deals with (1) experimental measurements on petrophysical, reservoir engineering and morphological properties of Ekofisk chalk, (2) numerical simulation of core flood experiments to analyze and improve relative permeability data, (3) stochastic reconstruction of chalk samples from limited morphological information, (4) extraction of pore space parameters from the reconstructed samples, development of network model using pore space information, and computation of petrophysical and reservoir engineering properties from network model, and (5) development of 2D and 3D idealized fractured reservoir models and verification of the applicability of several widely used conventional up scaling techniques in fractured reservoir simulation. Experiments have been conducted on eight Ekofisk chalk samples and porosity, absolute permeability, formation factor, and oil-water relative permeability, capillary pressure and resistivity index are measured at laboratory conditions. Mercury porosimetry data and backscatter scanning electron microscope images have also been acquired for the samples. A numerical simulation technique involving history matching of the production profiles is employed to improve the relative permeability curves and to analyze hysteresis of the Ekofisk chalk samples. The technique was found to be a powerful tool to supplement the uncertainties in experimental measurements. Porosity and correlation statistics obtained from backscatter scanning electron microscope images are used to reconstruct microstructures of chalk and particulate media. The reconstruction technique involves a simulated annealing algorithm, which can be constrained by an arbitrary number of morphological parameters. This flexibility of the algorithm is exploited to successfully reconstruct particulate media and chalk samples using more than one correlation functions. A technique based on conditional simulated annealing has been introduced for exact reproduction of vuggy

ChalkBoard: Mapping Functions to Polygons

Science.gov (United States)

Matlage, Kevin; Gill, Andy

ChalkBoard is a domain specific language for describing images. The ChalkBoard language is uncompromisingly functional and encourages the use of modern functional idioms. ChalkBoard uses off-the-shelf graphics cards to speed up rendering of functional descriptions. In this paper, we describe the design of the core ChalkBoard language, and the architecture of our static image generation accelerator.

Biot Critical Frequency Applied to Description of Failure and Yield of Highly Porous Chalk with Different Pore Fluids

DEFF Research Database (Denmark)

Andreassen, Katrine Alling; Fabricius, Ida Lykke

2010-01-01

Injection of water into chalk hydrocarbon reservoirs has led to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. In case of water-saturated samples, the concentration...... is controlled by solid-fluid friction. The reference frequency is thus a measure of this friction, and we propose that the fluid effect on mechanical properties of chalk may be the result of liquid-solid friction. We reviewed 622 published experiments on mechanical properties of porous chalk. The data include...... chalk samples that were tested at temperatures from 20 °C to 130 °C with the following pore fluids: fresh water, synthetic seawater, glycol, and oil of varying viscosity. The critical frequency is calculated for each experiment. For each specimen, we calculate the thickness to the slipping plane outside...

Potential for isoproturon, atrazine and mecoprop to be degraded within a chalk aquifer system

Science.gov (United States)

Johnson, Andrew C.; White, Craig; Lal Bhardwaj, C.

2000-06-01

The potential for herbicide degradation in an unconfined chalk aquifer was examined by collecting and spiking fresh samples and incubating them in the laboratory. The microcosms were incubated at 20°C under aerobic conditions and spiked with either isoproturon, atrazine or mecoprop at a concentration of 100 μg/l. The samples were obtained from a single fieldsite within the Upper Chalk aquifer in Hampshire, UK. Groundwater samples required the presence of sterile chalk in a ratio of at least 1:13 to promote isoproturon degradation. An isoproturon degradation potential existed in the soil, and the chalk unsaturated and saturated zones. However, no degradation of isoproturon in the unsaturated zone was observed when a more appropriate simulation of in-situ moisture conditions was carried out. Apart from the soil, no potential for atrazine or mecoprop degradation could be detected in the same samples over a 200-day incubation. In a series of groundwater samples taken from different boreholes, 10-300 m apart, large differences in isoproturon degradation potential were observed. Removal rates for 100 μg/l isoproturon varied from 83-425 ng/day, but in some samples no degradation potential could be detected. The primary metabolite which could be distinguished from isoproturon degradation in chalk and groundwater was monodesmethyl-isoproturon. When a chalk groundwater sample was spiked with isoproturon at 0.9 μg/l, this was not degraded over a 300-day incubation period. Further experiments with fresh groundwater from a Triassic Sandstone site illustrated that groundwater bacteria could degrade isoproturon at the more realistic temperature of 10°C as well as at 20°C.

Chalk as a reservoir

DEFF Research Database (Denmark)

Fabricius, Ida Lykke

, and the best reservoir properties are typically found in mudstone intervals. Chalk mudstones vary a lot though. The best mudstones are purely calcitic, well sorted and may have been redeposited by traction currents. Other mudstones are rich in very fine grained silica, which takes up pore space and thus...... basin, so stylolite formation in the chalk is controlled by effective burial stress. The stylolites are zones of calcite dissolution and probably are the source of calcite for porefilling cementation which is typical in water zone chalk and also affect the reservoirs to different extent. The relatively...... have hardly any stylolites and can have porosity above 40% or even 50% and thus also have relatively high permeability. Such intervals have the problem though, that increasing effective stress caused by hydrocarbon production results in mechanical compaction and overall subsidence. Most other chalk...

Seismic geomorphology and origin of diagenetic geobodies in the Upper Cretaceous Chalk of the North Sea Basin (Danish Central Graben)

DEFF Research Database (Denmark)

Smit, F. W. H.; van Buchem, F.S.P.; Holst, J.H.

2018-01-01

that the geobodies are of an open-system diagenetic origin caused by ascending basin fluids guided by faults and stratigraphic heterogeneities. Increased amounts of porosity-occluding cementation, contact cement and/or high-density/-velocity minerals caused an impedance contrast that can be mapped in seismic data...... failure, followed by local mechanical compaction of high-porous chalks, paired with 2) ascension of basinal diagenetic fluids along fault systems that locally triggered cementation of calcite and dolomite within the chalk, causing increased contact cements and/or reducing porosity. The migration pathway...... of the fluids is marked by the SCRs, which are the outlines of high-density bodies of chalk nested in highly porous chalks. This study thus provides new insights into the 3D relationship between fault systems, fluid migration and diagenesis in chalks, and has important applications for basin modeling...

Uranium traps in the phosphate bearing sudr chalk, in northeastern sinai, Egypt

International Nuclear Information System (INIS)

Hussein, H.A.; El-Aassy, I.E.; Mahdy, M.A.; Dabbour, G.A.; Mansour, M.Gh.; Morsy, A.M.

1998-01-01

The maastrichtian sudr formation in northeastern sinai is composed of three members, the lower chalk, the middle phosphate and chart-bearing and the upper chalk members. Lemon yellow secondary uranium mineralization, distributed in the lower chalk member and in some phosphate beds from the middle phosphate member are observed. The XRD analyses of some samples from the uranium bearing chalk and the phosphate beds showed the presence of the secondary uranium minerals carnotite, bergenite and upalite. The mode of uranium occurrences could be interpreted as a result of the phosphatic beds decomposition and their subjection to later diagenetic processes. Uranium leaching circulation from phosphate rocks led to the liberation of uranium from the phosphates, and vanadium from the bituminous material and clay minerals. These migrated and were deposited locally and within the underlying chalk beds which acted as a lithologic trap

Slope failure of chalk channel margins

DEFF Research Database (Denmark)

Gale, A.; Anderskouv, Kresten; Surlyk, Finn

2015-01-01

provide evidence for recurring margin collapse of a long-lived Campanian channel. Compressionally deformed and thrust chalk hardgrounds are correlated to thicker, non-cemented chalk beds that form a broad, gentle anticline. These chalks represent a slump complex with a roll-over anticline of expanded, non......-cemented chalk in the head region and a culmination of condensed hardgrounds in the toe region. Observations strongly suggest that the slumping represents collapse of a channel margin. Farther northwards, the contemporaneous succession shows evidence of small-scale penecontemporaneous normal faulting towards...

Trace elements in a North Sea drill core

DEFF Research Database (Denmark)

Kunzendorf, Helmar; Gwozdz, R.; Svendsen, N.

1986-01-01

, V, Sr, Dy, Mg, Ti, Ba and Eu. The major elements Ca and Al could be related to petrophysical parameters, particularly Al which shows a correlation with the silicification/argillaceous content. Na (and Cl) has a low content in the hydrocarbon-bearing section of the drill core suggesting that the pore......Chalk samples, systematically taken along a drill core from one of the hydrocarbon producing fields of the North Sea (Tyra field), were analysed by a neutron activation technique involving measurement of radioisotopes with relatively short half-lives. Elements determined include Na, Al, Cl, Ca, Mn...... space is filled mainly by hydrocarbons. A significant decrease of Mn with depth probably suggests diagenesis of chalk prior to, or with, hydrocarbon emplacement. Investigations of drilling fluids and cuttings reveal a strong contamination of the latter, mainly by Ba. Chalk data from comparable onshore...

Quick, Easy, and Economic Mineralogical Studies of Flooded Chalk for EOR Experiments Using Raman Spectroscopy

Directory of Open Access Journals (Sweden)

Laura Borromeo

2018-05-01

Full Text Available Understanding the chalk-fluid interactions and the associated mineralogical and mechanical alterations on a sub-micron scale are major goals in Enhanced Oil Recovery. Mechanical strength, porosity, and permeability of chalk are linked to mineral dissolution that occurs during brine injections, and affect the reservoir potential. This paper presents a novel “single grain” methodology to recognize the varieties of carbonates in rocks and loose sediments: Raman spectroscopy is a non-destructive, quick, and user-friendly technique representing a powerful tool to identify minerals down to 1 µm. An innovative working technique for oil exploration is proposed, as the mineralogy of micron-sized crystals grown in two flooded chalk samples (Liége, Belgium was successfully investigated by Raman spectroscopy. The drilled chalk cores were flooded with MgCl2 for ca. 1.5 (Long Term Test and 3 years (Ultra Long Term Test under North Sea reservoir conditions (Long Term Test: 130 °C, 1 PV/day, 9.3 MPa effective stress; Ultra Long Term Test: 130 °C, varying between 1–3 PV/day, 10.4 MPa effective stress. Raman spectroscopy was able to identify the presence of recrystallized magnesite along the core of the Long Term Test up to 4 cm from the injection surface, down to the crystal size of 1–2 µm. In the Ultra Long Term Test core, the growth of MgCO3 affected nearly the entire core (7 cm. In both samples, no dolomite or high-magnesium calcite secondary growth could be detected when analysing 557 and 90 Raman spectra on the Long and Ultra Long Term Test, respectively. This study can offer Raman spectroscopy as a breakthrough tool in petroleum exploration of unconventional reservoirs, due to its quickness, spatial resolution, and non-destructive acquisition of data. These characteristics would encourage its use coupled with electron microscopes and energy dispersive systems or even electron microprobe studies.

Impedance imaging in core analysis. Imaging of phase distributions in samples of natural cores of North Sea chalk containing conducting as well as non-conducting fluids. Part: 1-3

Energy Technology Data Exchange (ETDEWEB)

Laursen, S. [DTU, Inst. for Kemi (Denmark)] Moeller Nielsen, C. [DTU, Inst. for Energiteknik (Denmark)

1997-12-31

The present report documents the efforts to develop an impedance method for determining the distribution of the water saturation in a chalk core sample. Measurement of this distribution during a displacement process will make it possible to make numerical simulations of the process which may in turn reveal important rock parameters. The impedance method is one among other methods to determine saturation profiles in a research programme on rock parameters with participants from Danmarks Tekniske Universitet, DTU, and Danmarks og Groenlands Geologiske Undersoegelse, GEUS. The other methods investigated are nmr-scanning and {gamma}-logging. (au)

Quantitative NMR measurements on core samples

International Nuclear Information System (INIS)

Olsen, Dan

1997-01-01

Within the frame of an EFP-95 project NMR methods for porosity determination in 2D, and for fluid saturation determination in 1D and 2D have been developed. The three methods have been developed and tested on cleaned core samples of chalk from the Danish North Sea. The main restriction for the use of the methods is the inherently short T2 relaxation constants of rock samples. Referring to measurements conducted at 200 MHz, the 2D porosity determination method is applicable to sample material with T2 relaxation constants down to 5 ms. The 1D fluid saturation determination method is applicable to sample material with T2 relaxation constants down to 3 ms, while the 2D fluid saturation determination method is applicable to material with T2 relaxation constants down to 8 ms. In the case of the 2D methods these constraints as a minimum enables work on the majority of chalk samples of Maastrichtian age. The 1D fluid saturation determination method in addition is applicable to at least some chalk samples of Danian and pre-Maastrichtian age. The spatial resolution of the 2D porosity determination method, the 1D fluid saturation methods, and the 2D fluid saturation method is respectively 0.8 mm, 0.8 mm and 2 mm. Reproducibility of pixel values is for all three methods 2%- points. (au)

Quantitative 1D saturation profiles on chalk by NMR

DEFF Research Database (Denmark)

Olsen, Dan; Topp, Simon; Stensgaard, Anders

1996-01-01

Quantitative one-dimensional saturation profiles showing the distribution of water and oil in chalk core samples are calculated from NMR measurements utilizing a 1D CSI spectroscopy pulse sequence. Saturation profiles may be acquired under conditions of fluid flow through the sample. Results reveal...

Chalk effect on PVC cross-linking under irradiation

International Nuclear Information System (INIS)

Chudinova, V.V.; Guzeev, V.V.; Mozzhukhin, V.B.; Pomerantseva, Eh.G.; Nozrina, F.D.; Zhil'tsov, V.V.; Zubov, V.P.

1994-01-01

Effect of nonmodified and modified chalk on curing degree of polymer matrix was studied under-irradiation of PVC-compositions. Films of the compositions (100 mass part 7 PVC, 0-100 mas.part of chalk, 2.5 - lead sulfate, 1.5 - lead stearate and 0.3 - glycerin) were irradiated up to absorbed dose 0.1 MGy in an inert medium. Content of gel-fraction after boiling in THF was determined with use of IR spectroscopy. It was established, that intensive dehydrochlorination and polymer curing took place on chalk particle surface. Network fixed strongly chalk particles. However, chalk inhibited processes of dehydrochlorination and PVC curing, increasing amount of noncured PVC in polymer matrix

Influence of coal mine tips on the chalk aquifer. Sampling methods for three dimensional sulphate infiltration study

Energy Technology Data Exchange (ETDEWEB)

Barrez, F.; Mania, J. [Polytech' Lille, Dept. Genie Civil, UMR CNRS 8107 (LML), 59 - Villeneuve d' Ascq (France); Mansy, J.L. [Lille-1 Univ., Lab. de Sedimentologie et de Geodynamique, UMR CNRS 8110 (PBDS), 59 - Villeneuve d' Ascq (France); Piwakowski, B. [Ecole Centrale de Lille, Groupe Electronique Acoustique IEMN-DOAE, UMR CNRS 8520, 59 - Villeneuve d' Ascq (France)

2005-07-01

The coal basin of the Nord-Pas-de-Calais region (France) shows a very strong deterioration of the Chalk aquifer quality. In order to better model the hydro-dynamism and to improve knowledge on the chemical interactions, sampling according to depth of the groundwater is undertaken. The low-flow sampling and the profiles of the in-situ physicochemical parameters allow the observation of various vertical heterogeneities of the aquifer. The areas where the coal mine tips are localised appear very interesting to study. The sulphates released by the pyrite oxidation allow a 'artificial tracing' and give a visualization of the flow as well as information on the implied chemical processes between the oxidizing and reducing zones. (authors)

Influence of coal mine tips on the chalk aquifer. Sampling methods for three dimensional sulphate infiltration study

International Nuclear Information System (INIS)

Barrez, F.; Mania, J.; Mansy, J.L.; Piwakowski, B.

2005-01-01

The coal basin of the Nord-Pas-de-Calais region (France) shows a very strong deterioration of the Chalk aquifer quality. In order to better model the hydro-dynamism and to improve knowledge on the chemical interactions, sampling according to depth of the groundwater is undertaken. The low-flow sampling and the profiles of the in-situ physicochemical parameters allow the observation of various vertical heterogeneities of the aquifer. The areas where the coal mine tips are localised appear very interesting to study. The sulphates released by the pyrite oxidation allow a 'artificial tracing' and give a visualization of the flow as well as information on the implied chemical processes between the oxidizing and reducing zones. (authors)

Adsorption Properties of Chalk Reservoir Materials

DEFF Research Database (Denmark)

Okhrimenko, Denis

/gas adsorption properties of synthetic calcium carbonate phases (calcite, vaterite and aragonite) with chalk, which is composed of biogenic calcite (>98%). In combination with data from nanotechniques, the results demonstrate the complexity of chalk behavior and the role of nanoscale clay particles. The results...

Self Compacting Concrete with Chalk Filler

DEFF Research Database (Denmark)

Sørensen, Eigil V.

2007-01-01

Utilisation of Danish chalk filler has been investigated as a means to produce self compacting concrete (SCC) at lower strength levels for service in non aggressive environments. Stable SCC mixtures were prepared at chalk filler contents up to 60% by volume of binder to yield compressive strengths...

Tilting oil-water contact in the chalk of Tyra Field as interpreted from capillary pressure data

DEFF Research Database (Denmark)

Fabricius, Ida Lykke; Rana, M.A.

2010-01-01

The Tyra Field in the central North Sea is located in Palaeogene and Upper Cretaceous chalk. It contains a natural gas zone underlain by an oil leg. Based on analysis of logs and core data from ten wells drilled prior to the field being put into production, normalized water saturation depth-trend...... inequilibriumin the aquifer following tectonic tilting....

Field and numerical descriptions of fracture geometries and terminations in chalk containing chert layers and inclusions; implications for groundwater flow in Danish chalk aquifers

Science.gov (United States)

Seyum, S.

2017-12-01

This study is a description of the fracture distribution in laterally discontinuous chalk and chert layers, with an investigation on how fracture lengths and apertures vary as a function of applied stresses, material properties, and interface properties. Natural fractures intersect laterally extensive, discontinuous, chalk-chert material interfaces in 62 million-year old to 72 million-year old Chalk Group formations exposed at Stevns Klint, Denmark. Approximately one-third of Denmark's fresh water use is from chalk and limestone regional aquifers of the Chalk Group formations, where rock permeability is dominantly a function of open fracture connectivities. Fractured, centimeter- to decimeter-thick chert layers and inclusions (101 GPa elastic stiffness) are interlayered with fractured, meter-thick chalk layers (100 GPa elastic stiffness). Fractures are observed to terminate against and cross chalk-chert interfaces, affecting the vertical flow of water and pollutants between aquifers. The discontinuous and variably thin nature of chert layers at Stevns Klint effectively merges adjacent fracture-confining layers of chalk along discrete position intervals, resulting in lateral variability of fracture spacing. Finite element numerical models are designed to describe fracture interactions with stiff, chert inclusions of various shapes, thicknesses, widths, orientations, and interface friction and fracture toughness values. The models are two-dimensional with isotropic, continuous material in plane strain and uniformly applied remote principal stresses. These characteristics are chosen based on interpretations of the petrophysics of chalk and chert, the burial history of the rock, and the scale of investigation near fracture tips relative to grain sizes. The result are value ranges for relative stiffness contrasts, applied stresses, and material interface conditions that would cause fractures to cross, terminate at, or form along chalk-chert interfaces, with emphasis on

Adsorption of hydrocarbons in chalk reservoirs

Energy Technology Data Exchange (ETDEWEB)

Madsen, L.

1996-12-31

The present work is a study on the wettability of hydrocarbon bearing chalk reservoirs. Wettability is a major factor that influences flow, location and distribution of oil and water in the reservoir. The wettability of the hydrocarbon reservoirs depends on how and to what extent the organic compounds are adsorbed onto the surfaces of calcite, quartz and clay. Organic compounds such as carboxylic acids are found in formation waters from various hydrocarbon reservoirs and in crude oils. In the present investigation the wetting behaviour of chalk is studied by the adsorption of the carboxylic acids onto synthetic calcite, kaolinite, quartz, {alpha}-alumina, and chalk dispersed in an aqueous phase and an organic phase. In the aqueous phase the results clearly demonstrate the differences between the adsorption behaviour of benzoic acid and hexanoic acid onto the surfaces of oxide minerals and carbonates. With NaCl concentration of 0.1 M and with pH {approx_equal} 6 the maximum adsorption of benzoic acid decreases in the order: quartz, {alpha}-alumina, kaolinite. For synthetic calcite and chalk no detectable adsorption was obtaind. In the organic phase the order is reversed. The maximum adsorption of benzoic acid onto the different surfaces decreases in the order: synthetic calcite, chalk, kaolinite and quartz. Also a marked difference in adsorption behaviour between probes with different functional groups onto synthetic calcite from organic phase is observed. The maximum adsorption decreases in the order: benzoic acid, benzyl alcohol and benzylamine. (au) 54 refs.

Pitfalls in velocity analysis for strongly contrasting, layered media - Example from the Chalk Group, North Sea

Science.gov (United States)

Montazeri, Mahboubeh; Uldall, Anette; Moreau, Julien; Nielsen, Lars

2018-02-01

Knowledge about the velocity structure of the subsurface is critical in key seismic processing sequences, for instance, migration, depth conversion, and construction of initial P- and S-wave velocity models for full-waveform inversion. Therefore, the quality of subsurface imaging is highly dependent upon the quality of the seismic velocity analysis. Based on a case study from the Danish part of the North Sea, we show how interference caused by multiples, converted waves, and thin-layer effects may lead to incorrect velocity estimation, if such effects are not accounted for. Seismic wave propagation inside finely layered reservoir rocks dominated by chalk is described by two-dimensional finite-difference wave field simulation. The rock physical properties used for the modeling are based on an exploration well from the Halfdan field in the Danish sector of the North Sea. The modeling results are compared to seismic data from the study area. The modeling shows that interference of primaries with multiples, converted waves and thin-bed effects can give rise to strong anomalies in standard velocity analysis plots. Consequently, root-mean-square (RMS) velocity profiles may be erroneously picked. In our study area, such mis-picking can introduce errors in, for example, the thickness estimation of the layers near the base of the studied sedimentary strata by 11% to 26%. Tests show that front muting and bandpass filtering cannot significantly improve the quality of velocity analysis in our study. However, we notice that spiking deconvolution applied before velocity analysis may to some extent reduce the impact of interference and, therefore, reduce the risk of erroneous picking of the velocity function.

Use of X-ray computed tomography in core analysis of tight North Sea Chalk. Final report

Energy Technology Data Exchange (ETDEWEB)

Mogensen, K.; Stenby, E.H.

1997-12-01

This EFP-95 final report summarizes work performed at the Engineering Research Center (IVC-SEP) on the use of CT scanning in core analysis of tight core material from the North Sea. In this work, CT scanning has been applied to chalk material from Danish North Sea oil reservoirs. Results indicate that CT is fast and reliable for prediction of porosity. Typical errors lie within 2-3%. Calculation of fluid saturations requires considerable care from the experimentalists. Saturating a core ought to be performed by pulling vacuum to avoid trapped air bubbles. These bubbles may be produced after subsequent water and gas flooding, thereby ruining the mass balance calculations. Results performed at Stanford University show that if these simple precautions are taken, fluid saturations calculated from CT scanning are generally very accurate. Moreover, it appears that contrast agents need not be added to either phase. Regarding three-phase measurements the results are somewhat disappointing. Previous work using the dual-energy technique has indicated that the accuracy is less than satisfactory, due to an increased noise level at the low-energy setting. More work needs to be done in the future to develop the necessary expertise. The image analysis of the residual oil saturation after a gas flood can be simplified if water is assumed to be immobile during the injection. In that case, the resulting prediction of residual oil saturation is in excellent agreement with measured values. The general conclusion is that CT scanning holds a great potential as an assisting tool in modern core analysis, despite its limitations and the numerous implementation-related problems encountered during this work. (au) EFP-95. 57 refs.

Biot Critical Frequency Applied as Common Friction Factor for Chalk with Different Pore Fluids and Temperatures

DEFF Research Database (Denmark)

Andreassen, Katrine Alling; Fabricius, Ida Lykke

2010-01-01

Injection of water into chalk hydrocarbon reservoirs has lead to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. Water has a significant softening effect on elastic...... and we propose that the fluid effect on mechanical properties of highly porous chalk may be the result of liquid‐solid friction. Applying a different strain or stress rate is influencing the rock strength and needs to be included. The resulting function is shown to relate to the material dependent...... and rate independent b-factor used when describing the time dependent mechanical properties of soft rock or soils. As a consequence it is then possible to further characterize the material constant from the porosity and permeability of the rock as well as from pore fluid density and viscosity which...

Origin of channel systems in the Upper Cretaceous chalk group of the Paris Basin

DEFF Research Database (Denmark)

Esmerode, E. V.; Surlyk, Finn

2009-01-01

the presence of at least two distinct intra-chalk discordant reflections: a Top Santonian and a Mid-Campanian reflection. These reflections are in places associated with up to 120-m-deep channel-like structures trending preferentially N-S and NW-SE. The Mid-Campanian reflection is also sporadically associated...... with a massive secondary dolomite layer, the thicknesses of which may reach 110 m. Diagenesis does not seem to account for the formation of the discordant reflections, as there is neither a one-to-one relationship between the dolomite and discordant reflections, nor are there signs of systematic collapse...... is suggested due to the uninterrupted deep-marine chalk facies below and above both unconformities, and the unrealistically large sea-level drop of more than 200 m, which would be necessary for subaerial exposure of the central Paris Basin during the Campanian. The channels are oriented parallel to the margins...

Caoxite-hydroxyapatite composition as consolidating material for the chalk stone from Basarabi-Murfatlar churches ensemble

Science.gov (United States)

Ion, Rodica-Mariana; Turcanu-Caruţiu, Daniela; Fierăscu, Radu-Claudiu; Fierăscu, Irina; Bunghez, Ioana-Raluca; Ion, Mihaela-Lucia; Teodorescu, Sofia; Vasilievici, Gabriel; Rădiţoiu, Valentin

2015-12-01

The development of new composition for surface conservation of some architectural monuments represents now an important research topic. The Basarabi-Murfatlar Ensemble, recognized as the first religious monument from mediaeval Dobrogea (Romania) (from 9th to 11th century), is one of the most impressive archaeological sites of Europe. This ensemble is built from amorphous calcium carbonate, very sensitive to humidity, frost, salts, etc. The aim of this paper is to test on chalk stone samples a new consolidant - hydroxyapatite (HAp) mixed with calcium oxalate trihydrate (caoxite) (COT). Some specific techniques for evaluation its impact on chalk stone surface are used, as follows: petrographical and physical-chemical techniques: SEM, OM, ICP-AES, TGA, FTIR and Raman spectroscopy, chromatic parameters changes, the accelerated weathering tests: heating, freeze-thaw, and their effects on porosity and capillary water uptake by the chalk surface. All these have been evaluated before and after treatment with COT-HAp, putting into evidence the effect of the new composition on the chalk stone surface. HAp induces COT stabilization, and their joint composition can bind weathered stone blocks providing a substantial reinforcement of chalk surface.

Measurements with the Chalk River Calorimeters

International Nuclear Information System (INIS)

Boyd, A.W.

1970-01-01

The Chalk River calorimeters were designed to measure the absorbed dose rate in reactors in materials such as graphite, polyethylene and beryllium in the range 0.01-1 Wg -1 . To eliminate heaters in the sample they were made to operate adiabatically, or more accurately quasi-adiabatically since there is no heater on the jacket. Both the sample and jacket temperatures are recorded from the time of insertion in the reactor flux and the absorbed dose rate is calculated from these data. The advantages of this type of calorimeter are the ease of construction and the absence of a sample heater. The disadvantage is that dose rates below ~ 10 mWg -1 cannot be determined accurately

Investigation of spore forming bacterial flooding for enhanced oil recovery in a North Sea chalk Reservoir

DEFF Research Database (Denmark)

Halim, Amalia Yunita; Nielsen, Sidsel Marie; Eliasson Lantz, Anna

2015-01-01

Little has been done to study microbial enhanced oil recovery (MEOR) in chalk reservoirs. The present study focuses on core flooding experiments designed to see microbial plugging and its effect on oil recovery. A pressure tapped core holder was used for this purpose. A spore forming bacteria...... Bacillus licheniformis 421 was used as it was shown to be a good candidate in a previous study. Bacterial spore can penetrate deeper into the chalk rock, squeezing through the pore throats. Our results showed that injection of B. licheniformis 421 as a tertiary oil recovery method, in the residual oil...... saturation state, was able to produce additionally 1.0-2.3% original oil in place (OOIP) in homogeneous cores and 6.9-8.8% OOIP in heterogeneous cores. In addition, the pressure gradient was much higher in the heterogeneous cores, which confirms that bacterial selective plugging plays an important role...

Experimental study and mechanical modelling of the effects of water-driving in an oil saturated chalk. Application to the petroleum industry; Etude experimentale et modelisation mecanique des effets du balayage a l'eau dans une craie saturee d'huile. Application a l'industrie petroliere

Energy Technology Data Exchange (ETDEWEB)

Mata, C.

2001-01-01

The production of hydrocarbons may sometimes lead to compaction of the oil-reservoir layers with substantial collapse of the soil surface; this mechanism is usually mentioned as Subsidence. Classical remedy to this problem is to sustain the fluid pressure with the help of water injection. However, in presence of high porosity chalk (porosity > 30%), this technique does not give effective results: the subsidence rate at North Sea reservoirs (Ekofisk field), after injection, has remained unchanged. Some justify the subsistence in the chalk as caused by phenomena of dissolution of the carbonates; others think it is connected to the destruction of capillary menisci. In this research, we follow this second approach. This study is finalized to a better understanding of the compaction mechanisms in pure carbonates when water is injected. This is done by proposing -in micro-scale first and in macro-scale after- a physical model that agrees with empirical observations. In order to meet this target, IFP skills and experience in physical and chemical measurements (taken before, after and during mechanical tests) have proficiently joined ENPC laboratory (CERMMO) knowledge of micro and macro modelling. The soft rock studied is a Paris basin's white chalk (Craie de Guerville). Its physical and chemical characterisation (i.e.: silica content, porosity, permeability) is very similar to North Sea chalk, but Guerville chalk has never been in contact with oil and generally it crops out of the ground surface. Strength parameters of this rock have been first determined by standard triaxial tests. Three different saturation configurations have been examined: dry, fully oil-saturated and fully water-saturated. As literature clearly state, dry chalk is stronger than oil saturated chalk and the first two are largely stronger than water saturated chalk. Therefore uniaxial strain water injection tests have been performed on oil saturated samples. Results, coupled with previous physical

Seismic architecture of the Chalk Group from onshore reflection data in eastern Denmark

DEFF Research Database (Denmark)

Moreau, Julien; Anderskouv, Kresten; Boldreel, Lars Ole

with the seismic stratigraphy. Several seismic facies are identified in the Chalk Group: the 'transparent' (white chalk), the stratified (marl-chalk alternations), the crudely stratified (flint-rich chalk) and the hummocky (bryozoan mounds). The units notably vary in thickness at a relatively small scale...... of the deformations appear to be restricted to the white chalk, whereas the stratified seismic facies are comparatively less disturbed. The origin of the structures observed in the white chalk can either be associated with the regional stress field or with differential diagenetic evolution between strata inducing...

The fusion blanket program at Chalk River

International Nuclear Information System (INIS)

Hastings, I.J.

1986-03-01

Work on the Fusion Blanket Program commenced at Chalk River in 1984 June. Co-funded by Canadian Fusion Fuels Technology Project and Atomic Energy of Canada Limited, the Program utilizes Chalk River expertise in instrumented irradiation testing, ceramics, tritium technology, materials testing and compound chemistry. This paper gives highlights of studies to date on lithium-based ceramics, leading contenders for the fusion blanket

Controls on upper Campanian-Maastrichtian chalk deposition in the eastern Danish Basin

DEFF Research Database (Denmark)

Boussaha, Myriam; Thibault, Nicolas Rudolph; Anderskouv, Kresten

2017-01-01

% of the sediment. Sedimentation took place in deep water, below the photic zone and storm-wave base, and is characterized by decimetre to metre-scale variations in facies and trace fossil assemblages indicating repeated shifts in depositional environment. Integration of facies with published data on sea...... of accumulation rates and sea temperatures and is interpreted to represent a very broad set of deep water environmental conditions with an ample supply of calcareous nannofossil debris and intense bioturbation. Longer term shifts in deposition are best expressed by distribution of clay, flint and bioturbated...... micro-wackestone, bioturbated wackestone and laminated mudstone chalk facies, whereas the trace fossil assemblages appear less useful. The data set indicates overall shallowing over time with two distinctive events of clay influx to the basin during the late Campanian-earliest Maastrichtian and late...

Imaging the Danish Chalk Group with high resolution, 3-component seismics

Science.gov (United States)

Kammann, J.; Rasmussen, S. L.; Nielsen, L.; Malehmir, A.; Stemmerik, L.

2016-12-01

The Chalk Group in the Danish Basin forms important reservoirs to hydrocarbons as well as water resources, and it has been subject to several seismic studies to determine e.g. structural elements, deposition and burial history. This study focuses on the high quality seismic response of a survey acquired with an accelerated 45 kg weight drop and 3-component MEMS-based sensors and additional wireless vertical-type sensors. The 500 m long profile was acquired during one day close to a chalk quarry and chalk cliffs of the Stevns peninsula in eastern Denmark where the well-known K-T (Cretaceous-Tertiary) boundary and different chalk lithologies are well-exposed. With this simple and fast procedure we were able to achieve deep P-wave penetration to the base of the Chalk Group at about 900 m depth. Additionally, the CMP-processed seismic image of the vertical component stands out by its high resolution. Sedimentary features are imaged in the near-surface Danian, as well as in the deeper Maastrichtian and Upper Campanian parts of the Chalk Group. Integration with borehole data suggests that changes in composition, in particular clay content, correlate with changes in reflectivity of the seismic data set. While the pure chalk in the Maastrichtian deposits shows rather low reflectivity, succession enriched in clay appear to be more reflective. The integration of the mentioned methods gives the opportunity to connect changes in facies to the elastic response of the Chalk Group in its natural environmental conditions.

Chalk: composition, diagenesis and physical properties

DEFF Research Database (Denmark)

Fabricius, Ida Lykke

2007-01-01

Chalk is a sedimentary rock of unusually high homogeneity on the scale where physical properties are measured, but the properties fall in wide ranges. Chalk may thus be seen as the ideal starting point for a physical understanding of rocks in general. Properties as porosity, permeability, capillary...... involving clay, silica, and calcite are interlinked, but progress differently in different localities. This partly depends on primary sediment composition, including organic content, which may induce the formation of concretions by microbial action. The diagenetic processes also depend on water depth, rate...

Low field NMR surface relaxivity studies of chalk and argillaceous sandstones

DEFF Research Database (Denmark)

Katika, Konstantina; Fordsmand, Henrik; Fabricius, Ida Lykke

2017-01-01

the accuracy of predictions of petrophysical properties of various rocks with the use of NMR spectrometry. We perform laboratory transverse relaxation (T2) measurements on water saturated Gorm field chalk, Stevns Klint chalk, Solsort field greensand and Berea sandstone. These rocks are of particular interest...... field chalk and Solsort field greensand have higher ρ at higher Larmor frequency. By contrast, ρ of the purely calcitic Stevns chalk and quartzitic Berea sandstone proved not to be affected by the changes in frequency. T2 distributions at temperatures ranging from 10 °C to 60 °C provided comparison...

Elastic behaviour of North Sea chalk

DEFF Research Database (Denmark)

Gommesen, Lars; Fabricius, Ida Lykke; Mukerji, T.

2007-01-01

-consistent approximation, which here represents the unrelaxed scenario where the pore spaces of the rock are assumed to be isolated, and the Gassmann theory, which assumes that pore spaces are connected, as tools for predicting the effect of hydrocarbons from the elastic properties of brine-saturated North Sea reservoir...

Effect of Fluid Dynamic Viscosity on the Strength of Chalk

DEFF Research Database (Denmark)

Hedegaard, K.; Fabricius, Ida Lykke

The mechanical strength of high porosity and weakly cemented chalk is affected by the fluid in the pores. In this study, the effect of the dynamic viscosity of non-polar fluids has been measured on outcrop chalk from Sigerslev Quarry, Stevns, Denmark. The outcome is that the measured strength...... of the chalk decreases with increasing dynamic viscosity. The proposed qualitative explanation is that pressure difference supports and enhances the generation of microscopic shear and tensile failures....

Influence of effective stress coefficient on mechanical failure of chalk

DEFF Research Database (Denmark)

Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Hjuler, M.L.

2012-01-01

The Effective stress coefficient is a measure of how chalk grains are connected with each other. The stiffness of chalk may decrease if the amount of contact cements between the grains decreases, which may lead to an increase of the effective stress coefficient. We performed CO2 injection in chal...... precise failure strength of chalk during changed stress state and under the influence of chemically reactive fluids during production of hydrocarbon and geological storage CO2....

Can we get a better knowledge on dissolution processes in chalk by using microfluidic chips?

Science.gov (United States)

Neuville, Amélie; Minde, Mona; Renaud, Louis; Vinningland, Jan Ludvig; Dysthe, Dag Kristian; Hiorth, Aksel

2017-04-01

This work has been initiated in the context of research on improving the oil recovery in chalk bedrocks. One of the methods to improve the oil recovery is to inject "smart water" (acidic water/brines). Experiments on core scale and field tests that have been carried out the last decade have clearly shown that water chemistry affects the final oil recovery. However, there is generally no consensus in the scientific community of why additional oil is released, and it is also still not understood what are the mineralogical and structural changes. Direct in situ observation of the structural changes that occur when chalk is flooded with brines could resolve many of the open questions that remain. One of the highlights of this work is thus the development of an innovative methodology where fluid/rock interactions are observed in-situ by microscopy. To do so, we create several types of custom-made microfluidic systems that embeds reactive materials like chalk and calcite. The methodology we develop can be applied to other reactive materials. We will present an experiment where a calcite window dissolves with a fluid, where we observe in-situ the topography features of the calcite window, as well as the dissolution rate [1]. The injected fluid circulates at controlled flowrates in a channel which is obtained by xurography: double sided tape is cut out with a cutter plotter and placed between the reactive window and a non-reactive support. While the calcite window reacts, its topography is measured in situ every 10 s using an interference microscope, with a pixel resolution of 4.9 μm and a vertical resolution of 50 nm. These experiments are also compared with reactive flow simulations done with Lattice Boltzmann methods. Then, we will present a dissolution experiment done with a microfluidic system that embeds chalk. In this experiment, the main flow takes place at the chalk surface, in contact with fluid flowing in a channel above the chalk sample. Thus the reaction

Wettability of Chalk and Argillaceous Sandstones Assessed from T1/T2 Ratio

DEFF Research Database (Denmark)

Katika, Konstantina; Saidian, M.; Fabricius, Ida Lykke

ratio can quantify the affinity between the rock and wetting pore fluid. The affinity is a measure directly linked to wettability. In order to investigate the T2-shortening, we performed T1-T2 NMR experiments on different samples of chalk, Berea sandstone, and chloritic greensand, saturated either...... with water, oil or oil/water at irreducible water saturation. The T1/T2 ratio obtained from T1-T2 maps reflects the T2-shortening. We compare the T1/T2 ratio for the same type of rock, saturated with different fluids. The chalk shows high affinity for water, Berea sandstone has no clear preference for oil...

Using Raman spectroscopic imaging for non-destructive analysis of filler distribution in chalk filled polypropylene

DEFF Research Database (Denmark)

Boros, Evelin; Porse, Peter Bak; Nielsen, Inga

2016-01-01

A feasibility study on using Raman spectral imaging for visualization and analysis of filler distribution in chalk filled poly-propylene samples has been carried out. The spectral images were acquired using a Raman spectrometer with 785 nm light source.Eight injection-molded samples with concentr...

Dissection of genetic architecture of grain chalk using NIR spectroscopy

Science.gov (United States)

Chalk is a major quality characteristic that causes grain breakage during milling and loss of crop value. In this study, we sought to elucidate the quantitatively inherited grain chalk trait in rice and to conduct genome-wide association mapping to identify SNPs and candidate genes associated with ...

Response of invertebrates from the hyporheic zone of chalk rivers to eutrophication and land use.

Science.gov (United States)

Pacioglu, Octavian; Moldovan, Oana Teodora

2016-03-01

Whereas the response of lotic benthic macroinvertebrates to different environmental stressors is a widespread practice nowadays in assessing the water and habitat quality, the use of hyporheic zone invertebrates is still in its infancy. In this study, classification and regression trees analysis were employed in order to assess the ecological requirements and the potential as bioindicators for the hyporheic zone invertebrates inhabiting four lowland chalk rivers (south England) with contrasting eutrophication levels (based on surface nitrate concentrations) and magnitude of land use (based on percentage of fine sediments load and median interstitial space). Samples of fauna, water and sediment were sampled twice, during low (summer) and high (winter) groundwater level, at depths of 20 and 35 cm. Certain groups of invertebrates (Glossosomatidae and Psychomyiidae caddisflies, and riffle beetles) proved to be good indicators of rural catchments, moderately eutrophic and with high fine sediment load. A diverse community dominated by microcrustaceans (copepods and ostracods) were found as good indicators of highly eutrophic urban streams, with moderate-high fine sediment load. However, the use of other taxonomic groups (e.g. chironomids, oligochaetes, nematodes, water mites and the amphipod Gammarus pulex), very widespread in the hyporheic zone of all sampled rivers, is of limited use because of their high tolerance to the analysed stressors. We recommend the use of certain taxonomic groups (comprising both meiofauna and macroinvertebrates) dwelling in the chalk hyporheic zone as indicators of eutrophication and colmation and, along with routine benthic sampling protocols, for a more comprehensive water and habitat quality assessment of chalk rivers.

Process for treating oil-chalk

Energy Technology Data Exchange (ETDEWEB)

1925-10-20

A process for treating oil-chalk or similar oil-containing minerals is characterized in that the material is treated in a stream of air diluted with indifferent gases at a temperature of about 150/sup 0/ to 160/sup 0/C.

Twelve tips for the production of digital chalk-talk videos.

Science.gov (United States)

Rana, Jasmine; Besche, Henrike; Cockrill, Barbara

2017-06-01

Increasingly over the past decade, faculty in medical and graduate schools have received requests from digital millennial learners for concise faculty-made educational videos. At our institution, over the past couple of years alone, several hundred educational videos have been created by faculty who teach in a flipped-classroom setting of the pre-clinical medical school curriculum. Despite the appeal and potential learning benefits of digital chalk-talk videos first popularized by Khan Academy, we have observed that the conceptual and technological barriers for creating chalk-talk videos can be high for faculty. To this end, this tips article offers an easy-to-follow 12-step conceptual framework to guide at-home production of chalk-talk educational videos.

Chalk effect on PVC cross-linking under irradiation; Vliyanie mela na sshivanie PVKh pri obluchenii

Energy Technology Data Exchange (ETDEWEB)

Chudinova, V V; Guzeev, V V; Mozzhukhin, V B; Pomerantseva, Eh G; Nozrina, F D; Zhil` tsov, V V; Zubov, V P

1994-12-31

Effect of nonmodified and modified chalk on curing degree of polymer matrix was studied under-irradiation of PVC-compositions. Films of the compositions (100 mass part 7 PVC, 0-100 mas.part of chalk, 2.5 - lead sulfate, 1.5 - lead stearate and 0.3 - glycerin) were irradiated up to absorbed dose 0.1 MGy in an inert medium. Content of gel-fraction after boiling in THF was determined with use of IR spectroscopy. It was established, that intensive dehydrochlorination and polymer curing took place on chalk particle surface. Network fixed strongly chalk particles. However, chalk inhibited processes of dehydrochlorination and PVC curing, increasing amount of noncured PVC in polymer matrix.

The effect of chalk on the finger-hold friction coefficient in rock climbing.

Science.gov (United States)

Amca, Arif Mithat; Vigouroux, Laurent; Aritan, Serdar; Berton, Eric

2012-11-01

The main purpose of this study was to examine the effect of chalk on the friction coefficient between climber's fingers and two different rock types (sandstone and limestone). The secondary purpose was to investigate the effects of humidity and temperature on the friction coefficient and on the influence of chalk. Eleven experienced climbers took part in this study and 42 test sessions were performed. Participants hung from holds which were fixed on a specially designed hang board. The inclination of the hang board was progressively increased until the climber's hand slipped from the holds. The angle of the hang board was simultaneously recorded by using a gyroscopic sensor and the friction coefficient was calculated at the moment of slip. The results showed that there was a significant positive effect of chalk on the coefficient of friction (+18.7% on limestone and +21.6% on sandstone). Moreover sandstone had a higher coefficient of friction than limestone (+15.6% without chalk, +18.4% with chalk). These results confirmed climbers' belief that chalk enhances friction. However, no correlation with humidity/temperature and friction coefficient was noted which suggested that additional parameters should be considered in order to understand the effects of climate on finger friction in rock climbing.

Advanced waterflooding in chalk reservoirs: Understanding of underlying mechanisms

DEFF Research Database (Denmark)

Zahid, Adeel; Sandersen, Sara Bülow; Stenby, Erling Halfdan

2011-01-01

Over the last decade, a number of studies have shown SO42−, Ca2+ and Mg2+ to be potential determining ions, which may be added to the injected brine for improving oil recovery during waterflooding in chalk reservoirs. However the understanding of the mechanism leading to an increase in oil recove...... of a microemulsion phase could be the possible reasons for the observed increase in oil recovery with sulfate ions at high temperature in chalk reservoirs besides the mechanism of the rock wettability alteration, which has been reported in most previous studies.......Over the last decade, a number of studies have shown SO42−, Ca2+ and Mg2+ to be potential determining ions, which may be added to the injected brine for improving oil recovery during waterflooding in chalk reservoirs. However the understanding of the mechanism leading to an increase in oil recovery...

Ultrasonic velocities of North Sea chalk samples: influence of porosity, fluid content and texture

DEFF Research Database (Denmark)

Rogen, B.; Fabricius, Ida Lykke; Japsen, P.

2005-01-01

a porosity-reducing effect and that samples rich in large grains have a relatively low porosity for a given P-wave modulus. The clay content in the samples is low and is mainly represented by either kaolinite or smectite; samples with smectite have a lower P-wave modulus than samples with kaolinite at equal...

Persistent and emerging micro-organic contaminants in Chalk groundwater of England and France

International Nuclear Information System (INIS)

Lapworth, D.J.; Baran, N.; Stuart, M.E.; Manamsa, K.; Talbot, J.

2015-01-01

The Chalk aquifer of Northern Europe is an internationally important source of drinking water and sustains baseflow for surface water ecosystems. The areal distribution of microorganic (MO) contaminants, particularly non-regulated emerging MOs, in this aquifer is poorly understood. This study presents results from a reconnaissance survey of MOs in Chalk groundwater, including pharmaceuticals, personal care products and pesticides and their transformation products, conducted across the major Chalk aquifers of England and France. Data from a total of 345 sites collected during 2011 were included in this study to provide a representative baseline assessment of MO occurrence in groundwater. A suite of 42 MOs were analysed for at each site including industrial compounds (n = 16), pesticides (n = 14) and pharmaceuticals, personal care and lifestyle products (n = 12). Occurrence data is evaluated in relation to land use, aquifer exposure, well depth and depth to groundwater to provide an understanding of vulnerable groundwater settings. - Highlights: • Broad range of microorganics detected in Chalk groundwater in England and France. • Plasticisers, pesticides, BPA and THM detected at the highest concentrations. • Pesticides higher in outcrop Chalk, caffeine and BPA at concealed sites. • Occurrences show some relationship to land use, borehole depth and water level. - Broad screening reveals for the first time the extent of emerging microorganic pollution in Chalk groundwater sources across England and France

Optimization of Spore Forming Bacteria Flooding for Enhanced Oil Recovery in North Sea Chalk Reservoir

DEFF Research Database (Denmark)

Halim, Amalia Yunita; Nielsen, Sidsel Marie; Eliasson Lantz, Anna

2015-01-01

.2-3.8 cm) during bacteria injection. Further seawater flooding after three days shut in period showed that permeability gradually increased in the first two sections of the core and started to decrease in the third section of the core (3.8-6.3 cm). Complete plugging was never observed in our experiments.......Little has been done to study microbial enhanced oil recovery (MEOR) in chalk reservoirs. The present study focused on core flooding experiments to see microbial plugging and its effect on oil recovery. A pressure tapped core holder with pressure ports at 1.2 cm, 3.8 cm, and 6.3 cm from the inlet...

Isotope hydrology of the Chalk River Laboratories site, Ontario, Canada

Science.gov (United States)

Peterman, Zell; Neymark, Leonid; King-Sharp, K.J.; Gascoyne, Mel

2016-01-01

This paper presents results of hydrochemical and isotopic analyses of groundwater (fracture water) and porewater, and physical property and water content measurements of bedrock core at the Chalk River Laboratories (CRL) site in Ontario. Density and water contents were determined and water-loss porosity values were calculated for core samples. Average and standard deviations of density and water-loss porosity of 50 core samples from four boreholes are 2.73 ± 12 g/cc and 1.32 ± 1.24 percent. Respective median values are 2.68 and 0.83 indicating a positive skewness in the distributions. Groundwater samples from four deep boreholes were analyzed for strontium (87Sr/86Sr) and uranium (234U/238U) isotope ratios. Oxygen and hydrogen isotope analyses and selected solute concentrations determined by CRL are included for comparison. Groundwater from borehole CRG-1 in a zone between approximately +60 and −240 m elevation is relatively depleted in δ18O and δ2H perhaps reflecting a slug of water recharged during colder climatic conditions. Porewater was extracted from core samples by centrifugation and analyzed for major dissolved ions and for strontium and uranium isotopes. On average, the extracted water contains 15 times larger concentration of solutes than the groundwater. 234U/238U and correlation of 87Sr/86Sr with Rb/Sr values indicate that the porewater may be substantially older than the groundwater. Results of this study show that the Precambrian gneisses at Chalk River are similar in physical properties and hydrochemical aspects to crystalline rocks being considered for the construction of nuclear waste repositories in other regions.

Radar sounding of bedrock and water table at Chalk River

International Nuclear Information System (INIS)

Annan, A.P.; Davis, J.L.

1979-01-01

When a spill of radioactive waste occurs, one of the main concerns is the flow pattern of ground water in the area of the spill. Ground probing radar is a relatively new geophysical technique which can provide high resolution data on the surficial geology and water distribution. The results of some preliminary radar experiments conducted at Chalk River Nuclear Laboratories (CRNL) of the Atomic Energy of Canada Limited (AECL), Chalk River, Ontario are presented. (auth)

Stylolites, porosity, depositional texture, and silicates in chalk facies sediments

DEFF Research Database (Denmark)

Fabricius, Ida Lykke; Borre, Mai K.

2007-01-01

dissolution around 490 m below sea floor (bsf) corresponds to an interval of waning porosity-decline, and even the occurrence of proper stylolites from 830 m bsf is accompanied by only minor porosity reduction. Because opal is present, the pore-water is relatively rich in Si which through the formation of Ca......-silica complexes causes an apparent super-saturation of Ca and retards cementation. The onset of massive pore-filling cementation at 1100 m bsf may be controlled by the temperature-dependent transition from opal-CT to quartz. In the stylolite-bearing chalk of two wells in the Gorm and Tyra fields, the nannofossil...... matrix shows recrystallization but only minor pore-filling cement, whereas microfossils are cemented. Cementation in Gorm and Tyra is thus partial and has apparently not been retarded by opal-controlled pore-water. A possible explanation is that, due to the relatively high temperature, silica has...

Improved Oil Recovery in Chalk. Spontaneous Imbibition affected by Wettability, Rock Framework and Interfacial Tension

Energy Technology Data Exchange (ETDEWEB)

Milter, J.

1996-12-31

The author of this doctoral thesis aims to improve the oil recovery from fractured chalk reservoirs, i.e., maximize the area of swept zones and their displacement efficiencies. In order to identify an improved oil recovery method in chalk, it is necessary to study wettability of calcium carbonate and spontaneous imbibition potential. The thesis contains an investigation of thin films and wettability of single calcite surfaces. The results of thin film experiments are used to evaluate spontaneous imbibition experiments in different chalk types. The chalk types were described detailed enough to permit considering the influence of texture, pore size and pore throat size distributions, pore geometry, and surface roughness on wettability and spontaneous imbibition. Finally, impacts of interfacial tension by adding anionic and cationic surfactants to the imbibing water phase are studied at different wettabilities of a well known chalk material. 232 refs., 97 figs., 13 tabs.

Diagenesis of silica-rich mounded chalk, the Coniacian Arnager Limestone, Denmark

DEFF Research Database (Denmark)

Buus Madsen, Heine; Stemmerik, Lars; Surlyk, Finn

2010-01-01

The Coniacian Arnager Limestone Formation is exposed on the Danish island of Bornholm in the Baltic Sea. It is composed of mound-bedded siliceous chalk, and X-ray diffraction and scanning electron microscopy indicate a content of 30-70% insoluble minerals, including authigenic opal-CT, quartz......, clinoptilolite, feldspars, calcite, dolomite, and barite. Opal-CT and clinoptilolite are the most common and constitute 16-53% and 2-9%, respectively. The content of insoluble minerals varies laterally bothwithinthemounds and inplanar beds, and the opal-CT content varies by up to 10% vertically. Themounds...... precipitation of opal-CT. The opal-CT formed at temperatures around 17°C, the precipitation lowered the silica activity and the Si/Al ratio of the pore water, resulting in precipitation of clinoptilolite, feldspar and smectite. Calcite formed synchronouslywith the latest clinoptilolite.Minoramounts of quartz...

Reactive transport modelling of groundwater chemistry in a chalk aquifer at the watershed scale.

Science.gov (United States)

Mangeret, A; De Windt, L; Crançon, P

2012-09-01

This study investigates thermodynamics and kinetics of water-rock interactions in a carbonate aquifer at the watershed scale. A reactive transport model is applied to the unconfined chalk aquifer of the Champagne Mounts (France), by considering both the chalk matrix and the interconnected fracture network. Major element concentrations and main chemical parameters calculated in groundwater and their evolution along flow lines are in fair agreement with field data. A relative homogeneity of the aquifer baseline chemistry is rapidly reached in terms of pH, alkalinity and Ca concentration since calcite equilibrium is achieved over the first metres of the vadose zone. However, incongruent chalk dissolution slowly releases Ba, Mg and Sr in groundwater. Introducing dilution effect by rainwater infiltration and a local occurrence of dolomite improves the agreement between modelling and field data. The dissolution of illite and opal-CT, controlling K and SiO(2) concentrations in the model, can be approximately tackled by classical kinetic rate laws, but not the incongruent chalk dissolution. An apparent kinetic rate has therefore been fitted on field data by inverse modelling: 1.5×10(-5) mol(chalk)L (-1) water year (-1). Sensitivity analysis indicates that the CO(2) partial pressure of the unsaturated zone is a critical parameter for modelling the baseline chemistry over the whole chalk aquifer. Copyright © 2012 Elsevier B.V. All rights reserved.

Reactor safety research and development in Chalk River Laboratories

Energy Technology Data Exchange (ETDEWEB)

Nitheanandan, T. [Atomic Energy of Canada Limited, Chalk River, ON (Canada)

2014-07-01

Atomic Energy of Canada Limited's Chalk River Laboratories provides three different services to stakeholders and customers. The first service provided by the laboratory is the implementation of Research and Development (R&D) programs to provide the underlying technological basis of safe nuclear power reactor designs. A significant portion of the Canadian R&D capability in reactor safety resides at Atomic Energy of Canada Limited's Chalk River Laboratories, and this capability was instrumental in providing the science and technology required to aid in the safety design of CANDU power reactors. The second role of the laboratory has been in supporting nuclear facility licensees to ensure the continued safe operation of nuclear facilities, and to develop safety cases to justify continued operation. The licensing of plant life extension is a key industry objective, requiring extensive research on degradation mechanisms, such that safety cases are based on the original safety design data and valid and realistic assumptions regarding the effect of ageing and management of plant life. Recently, Chalk River Laboratories has been engaged in a third role in research to provide the technical basis and improved understanding for decision making by regulatory bodies. The state-of-the-art test facilities in Chalk River Laboratories have been contributing to the R&D needs of all three roles, not only in Canada but also in the international community, thorough Canada's participation in cooperative programs lead by International Atomic Energy Agency and the OECD's Nuclear Energy Agency. (author)

Province of Ontario nuclear emergency plan part V - Chalk River

International Nuclear Information System (INIS)

1991-10-01

The aim of Part 5 of the Provincial Nuclear Emergency Plan is to describe the measures that shall be undertaken to deal with a nuclear emergency caused by the Chalk River Laboratories. This plan deals mainly with actions at the Provincial level and shall by supplemented by the appropriate Municipal Plan. The Townships of Rolph, Buchanan, Wylie, and McKay, the Town of Deep River and the Village of Chalk River are the designated municipalities with respect to CRL. 2 tabs., 5 figs

Province of Ontario nuclear emergency plan part V - Chalk River

Energy Technology Data Exchange (ETDEWEB)

NONE

1991-10-01

The aim of Part 5 of the Provincial Nuclear Emergency Plan is to describe the measures that shall be undertaken to deal with a nuclear emergency caused by the Chalk River Laboratories. This plan deals mainly with actions at the Provincial level and shall by supplemented by the appropriate Municipal Plan. The Townships of Rolph, Buchanan, Wylie, and McKay, the Town of Deep River and the Village of Chalk River are the designated municipalities with respect to CRL. 2 tabs., 5 figs.

THE STUDY OF TECHNOLOGICAL PROPERTIES OF PLASTISOLS BASED EMULSION PVC FILLED WITH CHALK GIDROFOBIZIROVANNYM

Directory of Open Access Journals (Sweden)

V. A. Sedykh

2014-01-01

Full Text Available Baby toys are made using the centrifugal molding plastisol based emulsion of polyvinyl chloride plasticized with dioctylphthalate. To reduce cost and decrease biotelemetry the dioctylphthalate on the surface of the product domestic toys than toys produced in China, there was a necessity of introduction of the filler is chalk from different manufacturers. By using a Brookfield vis-cometer PV-D was studied rheology of filled hydrophobized chalk PVC plastisols in storage conditions for up to 72 hours at temperatures of 14-20°C. It was found that the flow plastisols consistent with pseudo-plastic fluids. Given the flow rates of emulsion PVC plastisols filled to 35 % of the mass. hydrophobized chalk. The influence of the content of the plasticizer dioctylphthalate in a narrow interval (37,0 - 41,4 % of the mass. on the viscosity of polymer pastes and the kinetics of its changes during storage. Revealed a linear dependence of the viscosity of the filled hydrophobized chalk plastisols on the speed of rotation of the spindle of the viscometer and during storage. Given the rate of expansion changes the viscosity of the plastisols of the speed of rotation of the spindle of the viscometer, the rate of change in viscosity and calculation of the initial viscosity. Determined the stability of the dispersion hydrophobized chalk in a colloidal solution of PVC in dioctylphthalate during storage. We determined the variation of the content of chalk (ash with top and bottom layers plastisols height 8 cm after 24 hours storage. It is proved that the temperature of the preparation and storage of polymer pastes were determining factors in the regulation of such technological properties of PVC plastisols in the presence hydrophobized chalkas viscosity, stability of the dispersion of chalk and, consequently, the efficiency of distribution plastisols in the form of a centrifugal molding.

Elasticity and electrical resistivity of chalk and greensand during water flooding with selective ions

DEFF Research Database (Denmark)

Katika, Konstantina; Alam, Mohammad Monzurul; Alexeev, Artem

2018-01-01

is water-wet after flooding. Greensand remained mixed wet throughout the experiments. Electrical resistivity data are in agreement with this interpretation. The electrical resistivity data during flooding revealed that the formation brine is not fully replaced by the injected water in both chalk......Water flooding with selective ions has in some cases lead to increased oil recovery. We investigate the physical processes on a pore scale that are responsible for changes in petrophysical and mechanical properties of four oil-bearing chalk and four oil-bearing greensand samples caused by flooding...... with brines containing varying amounts of dissolved NaCl, Na2SO4, MgCl2 and MgSO4. Ultrasonic P-wave velocity and AC resistivity measurements were performed prior to, during and after flow through experiments in order to identify and quantify the processes related to water flooding with selective ions. Low...

Regional transport of radioxenon released from the Chalk River Laboratories medical isotope facility

International Nuclear Information System (INIS)

Christine Johnson; Steven Biegalski

2015-01-01

An examination of proposed sampling sites near Chalk River Laboratories in Ontario, Canada is performed by considering the regional transport of radioxenon using atmospheric dispersion modeling. The local geography is considered, as are the local meteorological conditions during the summer months. In particular the impacts of predicted conditions on the imprinting of atmospheric radioxenon into the subsurface are considered and weighed against site proximity, geography, and geology. (author)

Investigation of Lecturer's Chalk by x-ray Florescence and Fast Neutron Activation Techniques

International Nuclear Information System (INIS)

Hassan, M.F.

2011-01-01

Different samples of lecturer's chalk were studied, using X-ray florescence (XRF) and Fast Neutron Activation Analysis (FNAA) techniques to ensure the safety of its use. The K (X-rays) and the gamma-rays were measured, using Si(Li) and high-purity germanium (HPGe) spectrometers to detect and determine qualitatively and quantitatively the constituents of the studied samples. The concentrations of the elements (Ca and small traces of Al, Fe, Mg and Si) were measured and their presence was confirmed by gamma-ray, lifetime and/or XRF measurements.

From ooze to sedimentary rock, the first diagenetic processes affecting the chalk of eastern Denmark

DEFF Research Database (Denmark)

Moreau, Julien; Boussaha, Myriam; Nielsen, Lars

processes operating in the chalk sediments at widely different scales into a single diagenetic model: At Stevns the chalk is affected by an extensive polygonal fault system which is expressed in onshore and offshore seismic profiles. Smaller scale contractional features like deformation bands (hairline...... strongly affect reservoir properties of the chalk both by establishing compartments and vertical connections. A better understanding of these reservoir modifications will be critical for improving the predictive capability of models describing the behaviour of drinking water and hydrocarbons hosted...

Impedance imaging in core analysis. Imaging of phase distributions in samples of natural cores of North Sea chalk containing conducting as well as non-conducting fluids. Part 1: Development of prototype measurement cell

Energy Technology Data Exchange (ETDEWEB)

Moeller Nielsen, C. [DTU, Inst. for Kemi (Denmark); Lauersen, S. [DTU, Lab. for Energiteknik (Denmark)

1996-12-31

To make reservoir simulations it is necessary to know such parameter functions as the capillary pressure curve, relative permeabilities etc. These are difficult to measure in chalk by means of traditional techniques because of the low permeability. In the present approach a displacement process is studied in detail and computer simulation with reservoir simulators can be used to determine parameter functions. To do this, however, it is necessary to know the developments of saturation profiles during the experiment. Different methods are tested in the programme. NMR-scanning and {gamma}-logging are methods where straight rays penetrate the sample and are partly absorbed. In electric current imaging an electric field is induced in the sample and detected at the surface. There are several benefits of this method compared with the others: There are no special safety requirements in contrast to work with radiation; No expensive and limited available equipment is needed unlike NMR; There are no intrinsic procedures slowing the method. There are, however, also drawbacks: Making measurements on a core sample implies the application of a large number of minute electrodes. To do this an implementation has to be derived from scratch; The inverse problem, i.e. the determination of the field inside the sample from surface measurements, is more difficult than the inverse problem of straight ray absorption. In the present report the development of an experimental technique is described. In part II of the report the interpretation of the experimental results will be discussed. (EG) 21 refs.

Radiocarbon dating with the Chalk River MP Tandem accelerator

International Nuclear Information System (INIS)

Ball, G.C.; Andrews, H.R.; Brown, R.M.; Burn, N.; Davies, W.G.; Imahori, Y.; Milton, J.C.D.

1981-01-01

During the past three years an automated radiocarbon dating system based on the MP Tandem accelerator has been developed for the analysis of 14 C in groundwater samples from the nuclear waste disposal research program and other small samples of scientific interest. At the present time 14 C/ 12 C ratio measurements can be determined with an accuracy of about 5% and the system background levels (approx. 35000 to 45000 years) are totally determined by sample and/or ion source contamination. Our goal has been to develop a dedicated reliable system for routine analysis that will produce accurate results with a minimum expenditure of human resources and accelerator beam time. Improvements required to operate the tandem accelerator as a quantitative tool have also benefited the rest of the experimental nuclear physics program. The early evolution of the dating facility was described previously. This paper is a brief report of the current status at Chalk River

Porosity and sonic velocity depth trends of Eocene chalk in Atlantic Ocean: Influence of effective stress and temperature

DEFF Research Database (Denmark)

Awedalkarim, Ahmed; Fabricius, Ida Lykke

2014-01-01

We aimed to relate changes in porosity and sonic velocity data, measured on water-saturated Eocene chalks from 36 Ocean Drilling Program drill sites in the Atlantic Ocean, to vertical effective stress and thermal maturity. We considered only chalk of Eocene age to avoid possible influence...... not show or at least it is difficult to define a clear pore-stiffening contact cementation trend as the Ontong Java Plateau chalk. Mechanical compaction is the principal cause of porosity reduction (at shallow depths) in the studied Eocene chalk, at least down to about 5MPa Terzaghi׳s effective stress...

The End of "Chalk and Talk"

Science.gov (United States)

Barlow, Tim

2012-01-01

"Chalk and talk" had been the staple pedagogical approach of my Science teaching practice since entering the profession. I felt that there was a great deal of information that I must impart to my students. My tried and tested way to deliver information to my students had always been simply to stand in front of them and tell it to them... So what…

The Effect of Bacteria Penetration on Chalk Permeability

DEFF Research Database (Denmark)

Halim, Amalia Yunita; Shapiro, Alexander; Nielsen, Sidsel Marie

number of B. licheniformis was detected on the effluent compared with P. putida. However, in the experiment with B. licheniformis mainly spores were detected in the effluent. The core permeability decreased rapidly during injection of bacteria and a starvation period of 12 days did not allow......Bacteria selective plugging is one of the mechanisms through which microorganisms can be applied for enhanced oil recovery. Bacteria can plug the water-bearing zones of a reservoir, thus altering the flow paths and improving sweep efficiency. It is known that the bacteria can penetrate deeply...... into reservoirs, however, a complete understanding of the penetration behavior of bacteria is lacking, especially in chalk formations where the pore throat sizes are almost comparable with the sizes of bacteria vegetative cells. This study investigates the penetration of bacteria into chalk. Two bacteria types...

Analysis of fine-dispersed chalk usage as mineral additive in the composition of sand aggrerate concrete

Directory of Open Access Journals (Sweden)

Светлана Николаевна Чепурная

2016-12-01

Full Text Available The research results of fine-disperse chalk addition on physical and mechanical properties of the cement stone and concrete are shown. It is determined that fine-disperse chalk addition in the binder composition increases the content of ultrafine particles. The chalk particles fill the pore space between the cement particles, increasing the packing density, which leads to a density increase, which consequently leads to improved physical and mechanical properties of the concrete: water tightness, cold resistance, corrosion resistance, crack resistance and other properties

A summary of the Chalk River valve packing evaluation program 1985 - 1990

International Nuclear Information System (INIS)

Aikin, J.A.; Doubt, G.L.; Lade, C.R.

1990-12-01

The move away from asbestos-based valve packing products has generated concern among valve manufacturers, packing manufacturers and user groups about the reliability and safety of non-asbestos based products for long-term use. AECL Research, Chalk River, has been actively evaluating these new valve packing products since 1985. This report describes the work done at Chalk River from 1985 to 1990. The report includes both Electric Power Research Institute (EPRI) and CANDU Owners Group (COG) funded studies. A description of the test programs and a brief summary of the functional performance of the more successful materials (die-formed graphite, braided asbestos and braided non-asbestos) on friction, stem leakage and consolidation are provided. At this time, Chalk River and Ontario Hydro have approved the following packing arrangements: for non-live-loaded valves, the recommended replacements packing for braided asbestos is combination flexible graphite packing sets; and, for heavy water valves originally designed with JC187I, the recommended replacement packing is approved braided-asbestos products

Lithostratigraphy of the Palaeogene - Lower Neogene succession of the Danish North Sea

DEFF Research Database (Denmark)

Schiøler, Poul-Henrik; Andsbjerg, Jan; Clausen, Ole Rønø

2007-01-01

sediments of the Danish sector of the North Sea is revised. The sediment package from the top of the Chalk Group to the base of the Nordland Group is subdivided into seven formations containing eleven new members. The existing Våle, Lista, Sele, Fur, Balder, Horda and Lark Formations of previously...

Stochastic modelling of porosity using seismic impedances on a volume of chalk in the Dan Field

Energy Technology Data Exchange (ETDEWEB)

Vejbaek, O.V.

1995-12-31

Seismic impedances calculated from logs show very good correlation to log porosities in wells penetrating the chalk reservoir in the Dan Field, Danish North Sea. This is the basis for an attempt to use seismic impedances derived from inversion as soft data for geostatistical reservoir characterization. The study focusses on porosity description of the Maastrichtian chalk reservoir unit, laterally restricted to an area covered by a subset of a 3D seismic survey. This seismic volume was inverted using the ISIS software producing a volume of seismic impedances. Spatial porosity realizations are produced using a gaussian collocated co-simulation algorithm, where well log porosities constitute the hard data input and seismic impedances are the soft data input. The simulated volume measures 1400 m x 1525 m x 102 m and is oriented parallel to lines and cross lines in the seismic dataset. Simulated blocks measures 25 m x 25 m x 6 m equivalent to twice the line and trace spacing, and approximately equivalent to the seismic sample rate. The correlation coefficient between log porosities and impedances calculated from logs alone are shown to be misleading since they suggest unrealistic high coefficients. However, the actual data used, namely inversion derived impedances and log porosities, still show correlation coefficients in the order of -0,45, which is quite sufficient to make the inversion results very useful. It is remarkable that the calculated correlation coefficient is based on 15 wells, and the inversion is based on only one well. The negative correlation coefficient indicate that high impedances correspond to low porosities and vice-versa. The impedance data indicate the level of average porosities at locations between wells. The fine structure is produced by the geostatistic process, with averages constrained by seismic impedances. The seismic impedances derived from the inversion process are thus shown to constitute useful primary data to constrain reservoir

Nano sized clay detected on chalk particle surfaces

DEFF Research Database (Denmark)

Skovbjerg, Lone; Hassenkam, Tue; Makovicky, Emil

2012-01-01

that in calcite saturated water, both the polar and the nonpolar functional groups adhere to the nano sized clay particles but not to calcite. This is fundamentally important information for the development of conceptual and chemical models to explain wettability alterations in chalk reservoirs...

Marine macrofossil communities in the uppermost Maastrichtian chalk of Stevns Klint, Denmark

DEFF Research Database (Denmark)

Hansen, Thomas; Surlyk, Finn

2014-01-01

Three successive marine habitats and their benthic macrofossil communities have been recognised and assessed in the uppermost Maastrichtian chalk of Stevns Klint, Denmark. The mound-bedded lower Sigerslev Member was deposited below the photic zone under the influence of persistent, non-erosive bo......Three successive marine habitats and their benthic macrofossil communities have been recognised and assessed in the uppermost Maastrichtian chalk of Stevns Klint, Denmark. The mound-bedded lower Sigerslev Member was deposited below the photic zone under the influence of persistent, non...

Chalk Catchment Transit Time: Unresolved Issues

Energy Technology Data Exchange (ETDEWEB)

Darling, W. G.; Gooddy, D. C. [British Geological Survey, Crowmarsh Gifford, Wallingford, Oxfordshire (United Kingdom); Barker, J. A. [School of Civil Engineering and the Environment, University of Southampton, Southampton (United Kingdom); Robinson, M. [Centre for Ecology and Hydrology, Crowmarsh Gifford, Wallingford, Oxfordshire (United Kingdom)

2013-07-15

The mean transit time (MTT) of a catchment is the average residence time of water from rainfall to river outflow at the foot of the catchment. As such, MTT has important water quality as well as resource implications. Many catchments worldwide have been measured for MTT using environmental isotopes, yet the Chalk, an important aquifer in NW Europe, has received little attention in this regard. The catchment of the River Lambourn in southern England has been intermittently studied since the 1960s using isotopic methods. A tritium peak measured in the river during the 1970s indicates an apparent MTT of {approx}15 years, but the thick unsaturated zone (average {approx}50 m) of the catchment suggests that the MTT should be much greater because of the average downward movement through the Chalk of {approx}1 m/a consistently indicated by tritium and other tracers. Recent work in the catchment using SF{sub 6} as a residence time indicator has given groundwater ages in the narrow range 11-18 yrs, apparently supporting the river tritium data but in conflict with the unsaturated zone data even allowing for a moderate proportion of rapid bypass flow. The MTT of the catchment remains unresolved for the time being. (author)

Facilities for post-irradiation examination of experimental fuel elements at Chalk River Nuclear Laboratories

International Nuclear Information System (INIS)

Mizzan, E.; Chenier, R.J.

1979-10-01

Expansion of post-irradiation facilities at the Chalk River Nuclear Laboratories and steady improvement in hot-cell techniques and equipment are providing more support to Canada's reactor fuel development program. The hot-cell facility primarily used for examination of experimental fuels averages a quarterly throughput of 40 elements and 110 metallographic specimens. New developments in ultrasonic testing, metallographic sample preparation, active storage, active waste filtration, and fissile accountability are coming into use to increase the efficiency and safety of hot-cell operations. (author)

Structural and Lithological Controls upon Fluid Migration within the Chalk and Upper Greensand Aquifers in the Chilterns and Lambourn Downs

OpenAIRE

Thompson, Sally

2002-01-01

The influence of lithological heterogeneities, structural discontinuities and discontinuity surface mineralisation upon groundwater migration within the Chalk and the Upper Greensand of southern England has been investigated. Lithological heterogeneities in the Chalk succession include marl seams, hardgrounds, tabular flints and nodular flints. Each of these heterogeneities has a lower intrinsic porosity and permeability than in the calcite rich chalk. The influence that each of these ...

Kolmanda aastatuhande piraadid / kommenteerinud Peter Chalk ja Gordan Van Hook

Index Scriptorium Estoniae

2009-01-01

Piraatlusest Somaalia piirkonnas ja rahvusvahelistest dokumentidest piraatluse vastu võitlemiseks 21. sajandil. Kommenteerivad uurimiskeskuse RAND Corporation vanempoliitanalüütik Peter Chalk ja transpordikompanii Maersk Line innovatsiooni ja arenduse vanemdirektor Gordan Van Hook

The transport and behaviour of isoproturon in unsaturated chalk cores

Science.gov (United States)

Besien, T. J.; Williams, R. J.; Johnson, A. C.

2000-04-01

A batch sorption study, a microcosm degradation study, and two separate column leaching studies were used to investigate the transport and fate of isoproturon in unsaturated chalk. The column leaching studies used undisturbed core material obtained from the field by dry percussion drilling. Each column leaching study used 25 cm long, 10 cm wide unsaturated chalk cores through which a pulse of isoproturon and bromide was eluted. The cores were set-up to simulate conditions in the unsaturated zone of the UK Chalk aquifer by applying a suction of 1 kPa (0.1 m H 2O) to the base of each column, and eluting at a rate corresponding to an average recharge rate through the unsaturated Chalk. A dye tracer indicated that the flow was through the matrix under these conditions. The results from the first column study showed high recovery rates for both isoproturon (73-92%) and bromide (93-96%), and that isoproturon was retarded by a factor of about 1.23 relative to bromide. In the second column study, two of the four columns were eluted with non-sterile groundwater in place of the sterile groundwater used on all other columns, and this study showed high recovery rates for bromide (85-92%) and lower recovery rates for isoproturon (66-79% — sterile groundwater, 48-61% — non-sterile groundwater). The enhanced degradation in the columns eluted with non-sterile groundwater indicated that groundwater microorganisms had increased the degradation rate within these columns. Overall, the reduced isoproturon recovery in the second column study was attributed to increased microbial degradation as a result of the longer study duration (162 vs. 105 days). The breakthrough curves (BTCs) for bromide had a characteristic convection-dispersion shape and were accurately simulated with the minimum of calibration using a simple convection-dispersion model (LEACHP). However, the isoproturon BTCs had an unusual shape and could not be accurately simulated.

Fault zone processes in mechanically layered mudrock and chalk

Science.gov (United States)

Ferrill, David A.; Evans, Mark A.; McGinnis, Ronald N.; Morris, Alan P.; Smart, Kevin J.; Wigginton, Sarah S.; Gulliver, Kirk D. H.; Lehrmann, Daniel; de Zoeten, Erich; Sickmann, Zach

2017-04-01

A 1.5 km long natural cliff outcrop of nearly horizontal Eagle Ford Formation in south Texas exposes northwest and southeast dipping normal faults with displacements of 0.01-7 m cutting mudrock, chalk, limestone, and volcanic ash. These faults provide analogs for both natural and hydraulically-induced deformation in the productive Eagle Ford Formation - a major unconventional oil and gas reservoir in south Texas, U.S.A. - and other mechanically layered hydrocarbon reservoirs. Fault dips are steep to vertical through chalk and limestone beds, and moderate through mudrock and clay-rich ash, resulting in refracted fault profiles. Steeply dipping fault segments contain rhombohedral calcite veins that cross the fault zone obliquely, parallel to shear segments in mudrock. The vertical dimensions of the calcite veins correspond to the thickness of offset competent beds with which they are contiguous, and the slip parallel dimension is proportional to fault displacement. Failure surface characteristics, including mixed tensile and shear segments, indicate hybrid failure in chalk and limestone, whereas shear failure predominates in mudrock and ash beds - these changes in failure mode contribute to variation in fault dip. Slip on the shear segments caused dilation of the steeper hybrid segments. Tabular sheets of calcite grew by repeated fault slip, dilation, and cementation. Fluid inclusion and stable isotope geochemistry analyses of fault zone cements indicate episodic reactivation at 1.4-4.2 km depths. The results of these analyses document a dramatic bed-scale lithologic control on fault zone architecture that is directly relevant to the development of porosity and permeability anisotropy along faults.

Trial coring in LLRW trenches at Chalk River

International Nuclear Information System (INIS)

Donders, R.E.; Killey, R.W.D.; Franklin, K.J.; Strobel, G.S.

1996-11-01

As part of a program to better characterize the low-hazard radioactive waste managed by AECL at Chalk River Laboratories, coring techniques in waste trenches are being assessed. Trial coring has demonstrated that sampling in waste regions is possible, and that boreholes can be placed through the waste trenches. Such coring provides a valuable information-gathering technique. Information available from trench coring includes: trench cover depth, waste region depth, waste compaction level, and detailed stratigraphic data; soil moisture content and facility drainage performance; borehole gamma logs that indicate radiation levels in the region of the borehole; biochemical conditions in the waste regions, vadose zone, and groundwater; site specific information relevant to contaminant migration modelling or remedial actions; information on contaminant releases and inventories. Boreholes through the trenches can also provide a means for early detection of potential contaminant releases. (author). 4 refs., 4 tabs., 4 figs

Initial field measurements on the Chalk River superconducting cyclotron

International Nuclear Information System (INIS)

Ormrod, J.H.; Chan, K.C.; Hill, J.H.

1980-12-01

The midplane magnetic field of the Chalk River superconducting cyclotron has been mapped in detail over the full operating range of 2.5 to 5 tesla. The field measuring apparatus is described and results given include measurements of the field stability, reproducibility and harmonic content. (author)

Benthic macrofauna variations and community structure in Cenomanian cyclic chalk-marl from Southerham Grey Pit, SE England

DEFF Research Database (Denmark)

Lauridsen, Bodil Wesenberg; Gale, A. S.; Surlyk, Finn

2009-01-01

Cenomanian chalk-marl couplets from England represent the 20 ka Milankovitch precession cycle. Fossil communities from both chalk and marl are identified to test if the orbital fluctuations and the associated changes in substrate lithology and climate exerted any control on the benthic macrofauna...

Microplastic sampling in the Mediterranean Sea

DEFF Research Database (Denmark)

Biginagwa, Fares; Sosthenes, Bahati; Syberg, Kristian

The extent of microplastic pollution in the Southwestern Mediterranean Sea is not yet known, although on Northwestern part has been previously studied. Plastic samples were collected at 7 transects during a 10 day expedition from Sicily (Italy) to Malaga (Spain) in September 2014. A 330 µM mesh...... manta trawl was used for surface water sampling. Physical and chemical characterization of plastic particles was performed with regard to size (1-5mm), shape (fragment, line, thin film, foam and pellets), color (transparent, white, black and colored), density and chemical composition according...

Acidity of sphagnum and its relation to chalk and mineral salts

Energy Technology Data Exchange (ETDEWEB)

Skene, M

1915-01-01

In addition to the criticism and elucidation of various other points, the chief conclusions which may be drawn from the preceding pages are: (1) There is a variation in acidity and in sensitiveness to chalk between the different species of sphagnum. (2) There is a correlation between degree of acidity and degree of sensitiveness. (3) The connection between the two is indirect, not direct. (4) The sphagna thrive in acid solutions: the injurious effect of chalk, and of alkalies in general, is due to the substitution of an alkaline for an acid reaction. (5) Mineral solutions are generally physiologically harmless, but may be ecologically harmful. (6) The sphagna do actually utilize in growth bases held absorbed by the acid compounds of the cell-walls.

Nuclear magnetic resonance and sound velocity measurements of chalk saturated with magnesium rich brine

DEFF Research Database (Denmark)

Katika, Konstantina; Alam, Mohammad Monzurul; Fabricius, Ida Lykke

2013-01-01

The use of low field Nuclear Magnetic Resonance (NMR) to determine petrophysical properties of reservoirs has proved to be a good technique. Together with sonic and electrical resistivity measurements, NMR can contribute to illustrate the changes on chalk elasticity due to different pore water...... solutions of the same ionic strength. Saturation with a solution that contained divalent ions caused a major shift on the distribution of the relaxation time. The changes were probably due to precipitats forming extra internal surface in the sample. Sonic velocities were relatively low in the MgCl2 solution...

Process-based modelling to evaluate simulated groundwater levels and frequencies in a Chalk catchment in south-western England

Science.gov (United States)

Brenner, Simon; Coxon, Gemma; Howden, Nicholas J. K.; Freer, Jim; Hartmann, Andreas

2018-02-01

Chalk aquifers are an important source of drinking water in the UK. Due to their properties, they are particularly vulnerable to groundwater-related hazards like floods and droughts. Understanding and predicting groundwater levels is therefore important for effective and safe water management. Chalk is known for its high porosity and, due to its dissolvability, exposed to karstification and strong subsurface heterogeneity. To cope with the karstic heterogeneity and limited data availability, specialised modelling approaches are required that balance model complexity and data availability. In this study, we present a novel approach to evaluate simulated groundwater level frequencies derived from a semi-distributed karst model that represents subsurface heterogeneity by distribution functions. Simulated groundwater storages are transferred into groundwater levels using evidence from different observations wells. Using a percentile approach we can assess the number of days exceeding or falling below selected groundwater level percentiles. Firstly, we evaluate the performance of the model when simulating groundwater level time series using a spilt sample test and parameter identifiability analysis. Secondly, we apply a split sample test to the simulated groundwater level percentiles to explore the performance in predicting groundwater level exceedances. We show that the model provides robust simulations of discharge and groundwater levels at three observation wells at a test site in a chalk-dominated catchment in south-western England. The second split sample test also indicates that the percentile approach is able to reliably predict groundwater level exceedances across all considered timescales up to their 75th percentile. However, when looking at the 90th percentile, it only provides acceptable predictions for long time periods and it fails when the 95th percentile of groundwater exceedance levels is considered. By modifying the historic forcings of our model

Reservoir fracture mapping using microearthquakes: Austin chalk, Giddings field, TX and 76 field, Clinton Co., KY

Energy Technology Data Exchange (ETDEWEB)

Phillips, W.S.; Rutledge, J.T.; Gardner, T.L. [SPE, Richardson, TX (United States); Fairbanks, T.D.; Miller, M.E.; Schuessler, B.K. [Los Alamos National Lab., NM (United States)

1996-11-01

Patterns of microearthquakes detected downhole defined fracture orientation and extent in the Austin chalk, Giddings field, TX and the 76 field, Clinton Co., KY. We collected over 480 and 770 microearthquakes during hydraulic stimulation at two sites in the Austin chalk, and over 3200 during primary production in Clinton Co. Data were of high enough quality that 20%, 31% and 53% of the events could be located, respectively. Reflected waves constrained microearthquakes to the stimulated depths at the base of the Austin chalk. In plan view, microearthquakes defined elongate fracture zones extending from the stimulation wells parallel to the regional fracture trend. However, widths of the stimulated zones differed by a factor of five between the two Austin chalk sites, indicating a large difference in the population of ancillary fractures. Post-stimulation production was much higher from the wider zone. At Clinton Co., microearthquakes defined low-angle, reverse-fault fracture zones above and below a producing zone. Associations with depleted production intervals indicated the mapped fractures had been previously drained. Drilling showed that the fractures currently contain brine. The seismic behavior was consistent with poroelastic models that predicted slight increases in compressive stress above and below the drained volume.

Effect of fluid-solid friction on the stiffness of chalk

DEFF Research Database (Denmark)

Alam, Mohammad Monzurul; Nguh Akam, Hosea; Fabricius, Ida Lykke

2011-01-01

Chalks behave weaker at water saturated condition. We studied this softening effect as a function of Biot’s frequency ratio, which is a ratio between measured ultrasonic wave frequency and Biot critical frequency, fc. Kinematic viscosity of fluid and permeability of rock determines fc. We observe...

Vertical distribution of radioactive particles in Ottawa River sediment near the Chalk River Laboratories

International Nuclear Information System (INIS)

Lee, D.R.; Hartwig, D.S.

2011-01-01

Previously, we described an area of above-background levels of radioactivity in the bed of the Ottawa River near the Chalk River Laboratories. The area was about 200 m wide by 400 m long and in water 8 to 30 m deep. The source of the radioactivity was associated with the location of cooling-water discharge. Particles of radioactive material were later recovered from the upper 10-15 cm of sediment and were determined to be sand-sized grains of nuclear fuel and corrosion products. This report provides an examination of the vertical distribution of radioactive particles in the riverbed. Twenty-three dredge samples (representing 1.2 m 2 of riverbed) were collected near the Process Outfall. Each dredge sample was dissected in horizontal intervals 1-cm-thick. Each interval provided a 524 cm 3 sample of sediment that was carefully examined for particulate radioactivity. Approximately 80% of the radioactivity appeared to be associated with discrete particles. Although the natural sediment in the general area is cohesive, silty clay and contains less than 10% sand, the sediment near the Outfall was found to be rich in natural sand, presumably from sources such as winter sanding of roads at the laboratories. The radioactive particles were almost entirely contained in the top-most 10 cm of the river bed. The majority of the particles were found several centimetres beneath the sediment surface and the numbers of particles and the radioactivity of the particles peaked 3 to 7 cm below the sediment surface. Based on the sediment profile, there appeared to have been a marked decrease in the deposition of particulate radioactivity in recent decades. The vertical distribution of radioactive particles indicated that sedimentation is resulting in burial and that the deposition of most of the particulate radioactivity coincided with the operation of Chalk River's NRX reactor from 1947 to 1992. (author)

Capillary fringe and tritium and nitrogen tracing history in the Senonian chalk of Champagne

International Nuclear Information System (INIS)

Ballif, J.L.

1998-01-01

In the middle of Champagne-Ardenne area, a chalky zone is located, directly on top of which lies the soil and in which the water table is relatively close the soil; which allows for capillary direction to the surface horizons and the renewal of water reserve. After the presentation of the hydrological characteristics, the total porosity of chalk, the pores distribution, the capillary attraction is shown by the hydrological comportment of the soil and the upper part of the unsaturated zone of chalk. In the homogeneous rock, the tritium and nitrogen transfers reveal the historical tracks. (authors)

Geologic feasibility of selected chalk-bearing sequences within the conterminous United States with regard to siting of radioactive-waste repositories

International Nuclear Information System (INIS)

Gonzales, S.

1975-11-01

Various geologic and hydrologic parameters are evaluated in relation to assessing the potential for repository storage of high-level radioactive wastes within several stratigraphic sequences dominated by chalks and chalky limestones. The former lithology is defined as a carbonate rock consisting mainly of very fine-grained particles of micritic calcite. Although chalks also contain coarser-grained particles such as shells of fossil foraminifera and non-calcitic minerals like quartz, most contain more than 90 percent micritic material. The latter represents broken fossil coccolith plates. The chalk-dominated formations discussed are exposed and underlie two different physiographic provinces which nevertheless display a general similarity in both being regions of extensive plains. The Niobrara Formation occurs mainly within the Great Plains province, while the Austin Chalk of Texas and the Selma Group of Alabama and Mississippi are located in the western and eastern Gulf Coastal Plain, respectively. The preliminary assessment is that chalk-bearing sequences show some promise and are deserving of added consideration and evaluation. Containment for hundreds of thousands of years would seem possible given certain assumptions. The most promising units from the three studied are the Niobrara Formation and Selma Group. Regional and local conditions make the Austin more suspect

Electroosmotic dewatering of chalk sludge, iron hydroxide sludge, wet fly ash and biomass

Energy Technology Data Exchange (ETDEWEB)

Hansen, H.K.; Kristensen, I.V.; Ottosen, L.M.; Villumsen, A. [Dept. of Geology and Geotechnical Engineering, The Technical Univ. of Denmark, Lyngby (Denmark)

2001-07-01

Electroosmotic dewatering has been tested in laboratory cells for 4 different porous materials: chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge from enzyme production. In all cases it was possible to remove water when passing electric DC current through the material. Casagrande's coefficients for the three materials where determined at different water contents. In the electroosmotic experiments shown in this work chalk can be dewatered from 40% to 79% DM (dry matter), fly ash from 75 to 82% DM, iron hydroxide sludge from 2.7 to 19% DM and biomass from 3 to 33% DM. The process was not optimised indicating that higher dry matter contents could be achieved. (orig.)

The effect of divalent ions on the elasticity and pore collapse of chalk evaluated from compressional wave velocity and low-field Nuclear Magnetic Resonance (NMR)

DEFF Research Database (Denmark)

Katika, Konstantina; Addassi, Mouadh; Alam, Mohammad Monzurul

2015-01-01

The effects of divalent ions on the elasticity and the pore collapse of chalk were studied through rock-mechanical testing and low-field Nuclear Magnetic Resonance (NMR) measurements. Chalk samples saturated with deionized water and brines containing sodium, magnesium, calcium and sulfate ions were...... subjected to petrophysical experiments, rock mechanical testing and low-field NMR spectroscopy. Petrophysical characterization involving ultrasonic elastic wave velocities in unconfined conditions, porosity and permeability measurements, specific surface and carbonate content determination and backscatter...... electron microscopy of the materials were conducted prior to the experiments. The iso-frame model was used to predict the bulk moduli in dry and saturated conditions from the compressional modulus of water-saturated rocks. The effective stress coefficient, as introduced by Biot, was also determined from...

Groundwater conversion areas in chalk in the southern Frankish Alps

International Nuclear Information System (INIS)

Pfaff, T.

1987-01-01

In order to collect hydro-geological data, chalk water marking was done and/or interpreted, water balances were produced, the contents tritium, oxygen 18, calcium, magnesium and the groundwater temperatures and electrolytic conductivity of the groundwater were examined and the dry weather drainage of individual sources was analysed. (orig./PW) [de

High resolution microgravity investigations for the detection and characterisation of subsidence associated with abandoned, coal, chalk and salt mines

Energy Technology Data Exchange (ETDEWEB)

Styles, P.; Toon, S.; Branston, M.; England, R. [Keele Univ., Applied And Environmental Geophysics Group, School of Physical and Geographical Sciences (United Kingdom); Thomas, E.; Mcgrath, R. [Geotechnology, Neath (United Kingdom)

2005-07-01

The closure and decay of industrial activity involving mining has scarred the landscape of urban areas and geo-hazards posed by subsurface cavities are ubiquitous throughout Europe. Features of concern consist of natural solution cavities (e.g. swallow holes and sinkholes in limestone gypsum and chalk) and man-made cavities (mine workings, shafts) in a great variety of post mining environments, including coal, salt, gypsum, anhydrite, tin and chalk. These problems restrict land utilisation, hinder regeneration, pose a threat to life, seriously damage property and services and blight property values. This paper outlines the application of microgravity techniques to characterise abandoned mining hazard in case studies from Coal, Chalk and Salt Mining environments in the UK. (authors)

High resolution microgravity investigations for the detection and characterisation of subsidence associated with abandoned, coal, chalk and salt mines

International Nuclear Information System (INIS)

Styles, P.; Toon, S.; Branston, M.; England, R.; Thomas, E.; Mcgrath, R.

2005-01-01

The closure and decay of industrial activity involving mining has scarred the landscape of urban areas and geo-hazards posed by subsurface cavities are ubiquitous throughout Europe. Features of concern consist of natural solution cavities (e.g. swallow holes and sinkholes in limestone gypsum and chalk) and man-made cavities (mine workings, shafts) in a great variety of post mining environments, including coal, salt, gypsum, anhydrite, tin and chalk. These problems restrict land utilisation, hinder regeneration, pose a threat to life, seriously damage property and services and blight property values. This paper outlines the application of microgravity techniques to characterise abandoned mining hazard in case studies from Coal, Chalk and Salt Mining environments in the UK. (authors)

Controls on Cementation in a Chalk Reservoir

DEFF Research Database (Denmark)

Meireles, Leonardo Teixeira Pinto; Hussein, A.; Welch, M.J.

In this study, we identify different controls on cementation in a chalk reservoir. Biot’s coefficient, a measure of cementation, stiffness and strength in porous rocks, is calculated from logging data (bulk density and sonic Pwave velocity). We show that Biot’s coefficient is correlated...... to the water saturation of the Kraka reservoir and is partly controlled by its stratigraphic sub-units. While the direct causal relationship between Biot’s coefficient and water saturation cannot be extended for Biot’s coefficient and porosity, a correlation is also identified between the two, implying...

Groundwater recharge dynamics in unsaturated fractured chalk: a case study

Science.gov (United States)

Cherubini, Claudia; Pastore, Nicola; Giasi, Concetta I.; Allegretti, Nicolaetta M.

2016-04-01

The heterogeneity of the unsaturated zone controls its hydraulic response to rainfall and the extent to which pollutants are delayed or attenuated before reaching groundwater. It plays therefore a very important role in the recharge of aquifers and the transfer of pollutants because of the presence of temporary storage zones and preferential flows. A better knowledge of the physical processes in the unsaturated zone would allow an improved assessment of the natural recharge in a heterogeneous aquifer and of its vulnerability to surface-applied pollution. The case study regards the role of the thick unsaturated zone of the Cretaceous chalk aquifer in Picardy (North of France) that controls the hydraulic response to rainfall. In the North Paris Basin, much of the recharge must pass through a regional chalk bed that is composed of a porous matrix with embedded fractures. Different types of conceptual models have been formulated to explain infiltration and recharge processes in the unsaturated fractured rock. The present study analyses the episodic recharge in fractured Chalk aquifer using the kinematic diffusion theory to predict water table fluctuation in response to rainfall. From an analysis of the data, there is the evidence of 1) a seasonal behavior characterized by a constant increase in the water level during the winter/spring period and a recession period, 2) a series of episodic behaviors during the summer/autumn. Kinematic diffusion models are useful for predict preferential fluxes and dynamic conditions. The presented approach conceptualizes the unsaturated flow as a combination of 1) diffusive flow refers to the idealized portion of the pore space of the medium within the flow rate is driven essentially by local gradient of potential; 2) preferential flow by which water moves across macroscopic distances through conduits of macropore length.

Tracking selenium in the Chalk aquifer of northern France: Sr isotope constraints

International Nuclear Information System (INIS)

Cary, L.; Benabderraziq, H.; Elkhattabi, J.; Gourcy, L.; Parmentier, M.; Picot, J.; Khaska, M.; Laurent, A.; Négrel, Ph.

2014-01-01

Highlights: • We report the chemistry of the Chalk groundwater affected by Se contamination. • Strontium isotopes were used to identify the groundwater bodies and their mixings. • The spatial and temporal Se variability is mainly linked to the presence of Se-rich clays. • Saturation or desaturation of Se-rich clays control Se mobility. - Abstract: Groundwater at the southern and eastern edges of France’s Paris Basin has a selenium content that at times exceeds the European Framework Directive’s drinking-water limit value of 10 μg/L. To better understand the dynamics of the Chalk groundwater being tapped to supply the city of Lille and the Se origins, we used a combination of geochemical and isotopic tools. Strontium isotopes, coupled with Ca/Sr, Mg/Sr and Se/Sr ratios, were used to identify the main groundwater bodies and their mixings, with the Mg/Sr and Se/Sr ratios constraining a ternary system. Groundwater in the agricultural aquifer-recharge zone represents a first end-member and displays the youngest water ages of the catchment along with the highest Sr isotopic signature (0.70842) and low Se contents. Anaerobic groundwater constitutes a second major end-member affected by water-rock interactions over a long residence time, with the lowest Sr isotopic signature (0.70789) and the lowest Se content, its low SF6 content confirming the contribution of old water. Se-rich groundwater containing up to 30 μg/L of Se represents a third major end-member, with an intermediate Sr isotopic ratio (0.70826), and is mainly constrained by the clayey Se-rich formation overlying the Chalk aquifer. The spatial and temporal Se variability in the groundwater is clearly linked to the presence of this formation identified as Tertiary and also to the hydrological conditions; saturation of the Se-rich clays by oxygenated groundwater enhances Se mobility and also Sr adsorption onto the clays. This multi-tool study including Sr isotopes successfully identified the Se

Glaciotectonic deformations in the Jammerbugt and glaciodynamic development in the eastern North Sea

DEFF Research Database (Denmark)

Pedersen, Stig A. Schack; Boldreel, Lars Ole

2017-01-01

–Early Weichselian Skærumhede Group, indicating a Saalian age of the glaciotectonic deformation. The balancing of the thrust fault structures shows that the thrust sheets in the tailing end of the complex had their source in the Skagerrak sea. The hole caused by displacement contributed to formation of the Skagerrak......The Quaternary geology in the eastern part of the North Sea is characterized by large-scale glaciotectonic complexes. The northernmost complex is the Jammerbugt Glaciotectonic Complex here addressed, which occupies an area of more than 300km2. It was recently recognized during an investigation...... of conventional seismic profiles located about 10km offshore the west coast of northern Denmark. The deformed bedrock includes the main part of the Cretaceous Chalk Group in the North Sea. In the northern part of the complex the detachment surface is situated in Lower Cretaceous greensand about 400m below sea...

Full-waveform Inversion of Crosshole GPR Data Collected in Strongly Heterogeneous Chalk

DEFF Research Database (Denmark)

Keskinen, Johanna; Zibar, Majken Caroline Looms; Nielsen, Lars

2015-01-01

Chalk is an important reservoir rock for hydrocarbons and for groundwater resources for many major cities. Therefore, this rock type has been extensively investigated using both geological and geophysical methods. Many applications of crosshole GPR tomography rely on the ray approximation...... and corresponding inversions of first break traveltimes and/or maximum first-cycle amplitudes. Due to the inherent limitations associated with such approaches, the resulting models tend to be overly smooth and cannot adequately capture the small-scale heterogeneities. In contrast, the full-waveform inversion uses...... address the importance of (i) adequate starting models, both in terms of the dielectric permittivity and the electrical conductivity, (ii) the estimation of the source wavelet, (iii) and the effects of data sampling density when imaging this rock type. Moreover, we discuss the resolution of the bedding...

Mortality among long-term Chalk River employees

International Nuclear Information System (INIS)

Werner, M.M.; Myers, D.K.

1986-12-01

Mortality among Chalk River Nuclear Laboratory (CRNL) employees who died during employment or after retirement has been updated to 1985 December 31. Data in tabular form are presented for overall mortality for male and female employees, for the participants in the clean-up for the NRX and NRU reactor accidents and for a group of CRNL staff with lifetime accumulative doses in excess of 0.2 Sv. Data are also presented on the different types of cancer causing death among male employees. No statistically significant increases in cancer deaths were found in any of the groups analyzed. 25 refs

Strength and Biot's coefficient for high-porosity oil- or water-saturated chalk

DEFF Research Database (Denmark)

Andreassen, Katrine Alling

. The Biot coefficient states the degree of cementation or how the pore pressure contributes to the strain resulting from an external load for a porous material. It is here calculated from dynamic measurements and correlated with the strength of outcrop chalk characterized by the onset of pore collapse...... during hydrostatic loading. The hypothesis is that the Biot coefficient and the theory of poroelasticity may cover the fluid effect by including the increased fluid bulk modulus from oil to water. A high number of test results for both oil- and water-saturated high-porosity outcrop chalk show correlation......In the petroleum industry it is relevant to know the Biot coefficient for establishing the effective stresses present in both the overburden and for the reservoir interval. When depleting a reservoir it is important to estimate the settlement through the strain imposed by the effective stress. Also...

Protocol for Microplastics Sampling on the Sea Surface and Sample Analysis

Science.gov (United States)

Kovač Viršek, Manca; Palatinus, Andreja; Koren, Špela; Peterlin, Monika; Horvat, Petra; Kržan, Andrej

2016-01-01

Microplastic pollution in the marine environment is a scientific topic that has received increasing attention over the last decade. The majority of scientific publications address microplastic pollution of the sea surface. The protocol below describes the methodology for sampling, sample preparation, separation and chemical identification of microplastic particles. A manta net fixed on an »A frame« attached to the side of the vessel was used for sampling. Microplastic particles caught in the cod end of the net were separated from samples by visual identification and use of stereomicroscopes. Particles were analyzed for their size using an image analysis program and for their chemical structure using ATR-FTIR and micro FTIR spectroscopy. The described protocol is in line with recommendations for microplastics monitoring published by the Marine Strategy Framework Directive (MSFD) Technical Subgroup on Marine Litter. This written protocol with video guide will support the work of researchers that deal with microplastics monitoring all over the world. PMID:28060297

Experimental Study of Bacterial Penetration into Chalk Rock: Mechanisms and Effect on Permeability

DEFF Research Database (Denmark)

Halim, Amalia Yunita; Shapiro, Alexander; Eliasson Lantz, Anna

2014-01-01

Bacterial selective plugging is one of the mechanisms through which microorganisms can be applied for enhanced oil recovery, as bacteria can plug the water-swept zones of a reservoir, thus altering the flow paths and improving sweep efficiency. However, complete understanding of the penetration...... behavior of bacteria is lacking, especially in chalk formations where characteristic pore throat sizes are comparable with the sizes of bacterial cells. In this study, two bacterial strains, Bacillus licheniformis 421 (spore-forming) and Pseudomonas putida K12 (non-spore forming) were used to investigate...... the penetration of bacteria into chalk and its effect on permeability reduction. The core plugs were produced from Stevns Klint outcrop with low permeability (2–4 mD) and with pore sizes comparable to bacterial sizes. Both types of bacteria were able to penetrate and to be transported through the cores to some...

ACE - an algebraic compiler and encoder for the Chalk River datatron computer

International Nuclear Information System (INIS)

Kennedy, J.M.; Okazaki, E.A.; Millican, M.

1960-03-01

ACE is a program written for the Chalk River Datatron (Burroughs 205) Computer to enable the machine to compile a program for solving a problem from instructions supplied by the user in a notation related much more closely to algebra than to the machine's own code. (author)

WIMS-CRNL: A user's manual for the Chalk River version of WIMS

International Nuclear Information System (INIS)

Donnelly, J.V.

1986-01-01

This report describes the preparation of the input for WIMS-CRNL, the Chalk River version of the WIMS lattice code. Also included are notes on the operation of the code, contents of the associated libraries, and the relation of WIMS-CRNL to other versions of the code

Heating- and growing-degree days at Chalk River Nuclear Laboratories, 1976-1980

International Nuclear Information System (INIS)

Jay, P.C.; Wildsmith, D.P.

1981-05-01

An update of the report, Heating- and Growing-Degree-Days at Chalk River Nuclear Laboratories (AECL-5547) is presented along with various other meteorological variables which were not included in the previous publication. Also included, and shown in graph form, are the monthly degree-day frequencies. (author)

AFSC/ABL: 2008 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2008 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

AFSC/ABL: 2007 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2007 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

AFSC/ABL: 2012 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch from the 2012 Bering Sea walleye pollock (Gadus chalcogrammus) trawl fishery was...

AFSC/ABL: 2009 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2009 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

AFSC/ABL: 2011 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch from the 2011 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

AFSC/ABL: 2006 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2006 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

AFSC/ABL: 2005 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2005 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

Geologic models and evaluation of undiscovered conventional and continuous oil and gas resources: Upper Cretaceous Austin Chalk

Science.gov (United States)

Pearson, Krystal

2012-01-01

The Upper Cretaceous Austin Chalk forms a low-permeability, onshore Gulf of Mexico reservoir that produces oil and gas from major fractures oriented parallel to the underlying Lower Cretaceous shelf edge. Horizontal drilling links these fracture systems to create an interconnected network that drains the reservoir. Field and well locations along the production trend are controlled by fracture networks. Highly fractured chalk is present along both regional and local fault zones. Fractures are also genetically linked to movement of the underlying Jurassic Louann Salt with tensile fractures forming downdip of salt-related structures creating the most effective reservoirs. Undiscovered accumulations should also be associated with structure-controlled fracture systems because much of the Austin that overlies the Lower Cretaceous shelf edge remains unexplored. The Upper Cretaceous Eagle Ford Shale is the primary source rock for Austin Chalk hydrocarbons. This transgressive marine shale varies in thickness and lithology across the study area and contains both oil- and gas-prone kerogen. The Eagle Ford began generating oil and gas in the early Miocene, and vertical migration through fractures was sufficient to charge the Austin reservoirs.

AFSC/ABL: 2010 Chum Salmon Bycatch Sample Analysis Bering Sea

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2010 Bering Sea groundfish trawl fishery was undertaken to determine the...

Controls on Cementation in a Chalk Reservoir

DEFF Research Database (Denmark)

Meireles, Leonardo Teixeira Pinto; Hussein, A.; Welch, M.J.

2017-01-01

In this study, we identify different controls on cementation in a chalk reservoir. Biot’s coefficient, a measure of cementation, stiffness and strength in porous rocks, is calculated from logging data (bulk density and sonic Pwave velocity). We show that Biot’s coefficient is correlated...... that some degree of pore filling cementation occurred in Kraka (Alam, 2010). Lack of correlation between Biot’s coefficient and Gamma Ray (GR) indicates that the small amount of clay present is generally located in the pore space, thus not contributing to frame stiffness. While there was no compositional...... control on cementation via clay, we could infer that stratigraphy impacts on the diagenetic process....

Reactor loops at Chalk River

International Nuclear Information System (INIS)

Sochaski, R.O.

1962-07-01

This report describes broadly the nine in-reactor loops, and their components, located in and around the NRX and NRU reactors at Chalk River. First an introduction and general description is given of the loops and their function, supplemented with a table outlining some loop specifications and nine simplified flow sheets, one for each individual loop. The report then proceeds to classify each loop into two categories, the 'main loop circuit' and the 'auxiliary circuit', and descriptions are given of each circuit's components in turn. These components, in part, are comprised of the main loop pumps, the test section, loop heaters, loop coolers, delayed-neutron monitors, surge tank, Dowtherm coolers, loop piping. Here again photographs, drawings and tables are included to provide a clearer understanding of the descriptive literature and to include, in tables, some specifications of the more important components in each loop. (author)

Environmental isotope studies related to groundwater flow and saline encroachment in the chalk aquifer of Lincolnshire, England

International Nuclear Information System (INIS)

Lloyd, J.W.; Howard, K.W.F.

1978-01-01

The isotopes of tritium and carbon are used to study part of the North Lincolnshire Chalk aquifer in England. The tritium data support the view that the aquifer is a thin fissure system and indicate that some changes in flow direction have occurred due to recent abstraction. The data are also consistent with other chemical data in elucidating groundwater entering the Chalk from deeper aquifers. Carbon isotopes are used to distinguish between saline water bodies and suggest that saline water was entrapped within the aquifer in the Eemian and Flandrian stages of the Pleistocene. (orig.) [de

Investigated Miscible CO2 Flooding for Enhancing Oil Recovery in Wettability Altered Chalk and Sandstone Rocks

Energy Technology Data Exchange (ETDEWEB)

Tabrizy, Vahid Alipour

2012-07-01

The thesis addresses oil recovery by miscible CO2 flooding from modified sandstone and chalk rocks. Calcite mineral surface is modified with stearic acid (SA) and asphaltene, and the silicate mineral surfaces are modified with N,N-dimethyldodecylamine (NN-DMDA) and asphaltene. The stability of adsorbed polar components in presence of SO4 2- and Mg2 + ions is also investigated. Recovery from sandstone cores is consistently lower than that from chalk cores saturated with the same oil and flooded with CO2 at all miscible flooding conditions. This may be due to the larger permeability contrasts in sandstone cores, which promote the fingering phenomenon. Miscible CO2 flooding for chalk and sandstone cores with distilled water, as initial water saturation, shows also lower oil recovery than cores saturated with different ions. At higher miscible flooding conditions, higher oil recovery is obtained. However, presence of light components (such as C1 or C3) in oil reduced the recovery. Oil recovery in presence of methane (C1) is lower than that in presence of methane and propane (C1/C3). A ternary diagram was constructed in order to understand the CO2 flooding mechanism(s) at the different flooding conditions and in presence of light components. The side effect of the flooding with CO2 is the probability for asphaltene deposition. An approach based on solubility parameter in the liquid, is used to assess the risk for asphaltene deposition during CO2 miscible flooding. The light components (C1/C3) and higher flooding conditions enhanced the risk for asphaltene instability. It is also shown higher amount of asphaltene deposition in chalk cores than that in sandstone cores at similar miscibility conditions.(au)

Source and persistence of pesticides in a semi-confined chalk aquifer of southeast England

International Nuclear Information System (INIS)

Lapworth, D.J.; Gooddy, D.C.

2006-01-01

Pesticide contamination in groundwater is an increasing problem that poses a significant long-term threat to water quality. Following the detection of elevated concentrations of diuron in boreholes in a semi-confined chalk aquifer from southeast England, a sampling programme was undertaken. Between 2003 and 2004 diuron was observed in 90% of groundwaters analysed. In 60% of groundwater samples metabolites of diuron were more prevalent than the parent compound. Longer-term (1989-2005) monitoring shows that pollution of the aquifer by atrazine, simazine, and more recently diuron, shows a positive correlation with periods of high groundwater levels. Results from groundwater residence time indicators suggest that the highest diuron concentrations are associated with waters containing the greatest proportion of recent recharge. There is some evidence to indicate that diuron occurrence can be spatially related to areas of urban and industrial development and is probably correlated with amenity usage. - Pesticides and their metabolites from amenity use pose a long-term threat to groundwater quality

Source and persistence of pesticides in a semi-confined chalk aquifer of southeast England

Energy Technology Data Exchange (ETDEWEB)

Lapworth, D.J. [British Geological Survey, Maclean Building, Wallingford, Oxon OX10 8BB (United Kingdom); Gooddy, D.C. [British Geological Survey, Maclean Building, Wallingford, Oxon OX10 8BB (United Kingdom)]. E-mail: dcg@bgs.ac.uk

2006-12-15

Pesticide contamination in groundwater is an increasing problem that poses a significant long-term threat to water quality. Following the detection of elevated concentrations of diuron in boreholes in a semi-confined chalk aquifer from southeast England, a sampling programme was undertaken. Between 2003 and 2004 diuron was observed in 90% of groundwaters analysed. In 60% of groundwater samples metabolites of diuron were more prevalent than the parent compound. Longer-term (1989-2005) monitoring shows that pollution of the aquifer by atrazine, simazine, and more recently diuron, shows a positive correlation with periods of high groundwater levels. Results from groundwater residence time indicators suggest that the highest diuron concentrations are associated with waters containing the greatest proportion of recent recharge. There is some evidence to indicate that diuron occurrence can be spatially related to areas of urban and industrial development and is probably correlated with amenity usage. - Pesticides and their metabolites from amenity use pose a long-term threat to groundwater quality.

Edibility of sport fishes in the Ottawa River near Chalk River Laboratories

Energy Technology Data Exchange (ETDEWEB)

Lee, D.R.; Chaput, T.; Miller, A.; Wills, C.A., E-mail: leed@aecl.ca [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

2013-12-15

To address the question of edibility of fish in the Ottawa River near Chalk River Laboratories (CRL), 123 game fish were collected for analysis from four locations: Mackey and Rolphton (45 km and 35 km upstream of Chalk River Laboratories (CRL), respectively), the Sandspit (Pointe au Bapteme) and Cotnam Island (1.6 km and 45 km downstream of CRL, respectively). Twenty-six to thirty-six game fish were collected at each location in 2007 and samples of flesh or bone were analyzed. Trap nets were used to collect only the fish required, allowing release of management-sensitive species. The focus was on walleye (Sander vitreus) because they are abundant and popular among anglers. A few northern pike (Esox lucius) and a smaller number of smallmouth bass (Micropterus dolomieui) were also collected at three of the four sites. Samples of the fish were analyzed for cesium-137 ({sup 137}Cs), strontium-90 ({sup 90}Sr), mercury (Hg), and selected organo-chlorine compounds. Concentrations of {sup 137}Cs in the flesh and {sup 90}Sr in the bones of sport fish were low and similar at all four locations and appear to reflect the global residuals from nuclear weapons testing (primarily in the 1960's) as opposed to releases from CRL. Possible explanations are: 1) Reductions in radionuclide releases from CRL in recent decades and 2) Relatively large foraging ranges of sport fish. Mercury concentrations were elevated in fishes in the Ottawa River and were significantly higher at the Sandspit and Rolphton than at Mackey and Cotnam Island (p<0.001). Mercury concentrations from the four sites are comparable to concentrations in other Ontario and Quebec lakes. It is advisable therefore, that consumers follow the fish consumption guidelines issued by provincial authorities when eating fish from the Ottawa River. Organo-chlorine compounds were not detected in walleye; however, they were detected in all eight of the pike collected at Cotnam Island. The highest organo

Edibility of sport fishes in the Ottawa River near Chalk River Laboratories

International Nuclear Information System (INIS)

Lee, D.R.; Chaput, T.; Miller, A.; Wills, C.A.

2013-01-01

To address the question of edibility of fish in the Ottawa River near Chalk River Laboratories (CRL), 123 game fish were collected for analysis from four locations: Mackey and Rolphton (45 km and 35 km upstream of Chalk River Laboratories (CRL), respectively), the Sandspit (Pointe au Bapteme) and Cotnam Island (1.6 km and 45 km downstream of CRL, respectively). Twenty-six to thirty-six game fish were collected at each location in 2007 and samples of flesh or bone were analyzed. Trap nets were used to collect only the fish required, allowing release of management-sensitive species. The focus was on walleye (Sander vitreus) because they are abundant and popular among anglers. A few northern pike (Esox lucius) and a smaller number of smallmouth bass (Micropterus dolomieui) were also collected at three of the four sites. Samples of the fish were analyzed for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), mercury (Hg), and selected organo-chlorine compounds. Concentrations of 137 Cs in the flesh and 90 Sr in the bones of sport fish were low and similar at all four locations and appear to reflect the global residuals from nuclear weapons testing (primarily in the 1960's) as opposed to releases from CRL. Possible explanations are: 1) Reductions in radionuclide releases from CRL in recent decades and 2) Relatively large foraging ranges of sport fish. Mercury concentrations were elevated in fishes in the Ottawa River and were significantly higher at the Sandspit and Rolphton than at Mackey and Cotnam Island (p<0.001). Mercury concentrations from the four sites are comparable to concentrations in other Ontario and Quebec lakes. It is advisable therefore, that consumers follow the fish consumption guidelines issued by provincial authorities when eating fish from the Ottawa River. Organo-chlorine compounds were not detected in walleye; however, they were detected in all eight of the pike collected at Cotnam Island. The highest organo-chlorine concentrations were measured in two

How burial diagenesis of chalk sediments controls sonic velocity and porosity

DEFF Research Database (Denmark)

Fabricius, Ida Lykke

2003-01-01

Based on P-wave velocity and density data, a new elastic model for chalk sediments is established. The model allows the construction of a series of isoframe (IF) curves, each representing a constant part of the mineral phase contributing to the solid frame. The IF curves can be related to the pro......Based on P-wave velocity and density data, a new elastic model for chalk sediments is established. The model allows the construction of a series of isoframe (IF) curves, each representing a constant part of the mineral phase contributing to the solid frame. The IF curves can be related.......1 or higher. Upon burial, the sediments lose porosity by mechanical compaction, and concurrently, the calcite particles recrystallize into progressively more equant shapes. High compaction rates may keep the particles in relative motion, whereas low compaction rates allow the formation of contact cement...... this process testifies to the absence of chemical compaction by calcite-calcite pressure dissolution, as well as to the porosity-preserving effect of contact cementation. At sufficient burial stress, the presence of stylolites indicates that pressure dissolution takes place between calcite., and silicates...

Cancer and workers' compensation at Chalk River nuclear laboratories

International Nuclear Information System (INIS)

Evans, D.W.S.

1985-01-01

This paper describes the circumstances leading to the notification to the Worker's Compensation Board of Ontario of two cases of cancer, both involving the lymphatic and haematoporetic systems, in employees at Chalk River Nulcear Laboratories. Twenty of these neoplasms are known to have occurred in the CRNL population between 1966 and 1983. The leukemia/lymphoma ratio observed in the twenty neoplasms is similar to that found in populations not occupationally exposed to ionizing radiation. The possible relationship between asbestos exposure and lymphoid neoplasms was discussed. 5 refs

Temporal variability of micro-organic contaminants in lowland chalk catchments: New insights into contaminant sources and hydrological processes.

Science.gov (United States)

Manamsa, K; Lapworth, D J; Stuart, M E

2016-10-15

This paper explores the temporal variation of a broad suite of micro organic (MO) compounds within hydrologically linked compartments of a lowland Chalk catchment, the most important drinking water aquifer in the UK. It presents an assessment of results from relatively high frequency monitoring at a well-characterised site, including the type and concentrations of compounds detected and how they change under different hydrological conditions including exceptionally high groundwater levels and river flow conditions during 2014 and subsequent recovery. This study shows for the first time that within the Chalk groundwater there can be a greater diversity of the MOs compared to surface waters. Within the Chalk 26 different compounds were detected over the duration of the study compared to 17 in the surface water. Plasticisers (0.06-39μg/L) were found to dominate in the Chalk groundwater on 5 visits (38.4%) accounting for 14.5% of detections but contributing highest concentrations whilst other compounds dominated in the surface water. Trichloroethene and atrazine were among the most frequently detected compounds. The limit for the total pesticide concentration detected did not exceed EU/UK prescribed concentration values for drinking water. Emerging organic compounds such as caffeine, which currently do not have water quality limits, were also detected. The low numbers of compounds found within the hyporheic zone highlight the role of this transient interface in the attenuation and breakdown of the MOs, and provision of an important ecosystem service. Copyright © 2016 British Geological Survey, NERC. Published by Elsevier B.V. All rights reserved.

Mechanical and chemical processes affecting the chalk during burial, insights from combined reflection seismics, well data and field work

DEFF Research Database (Denmark)

Moreau, Julien; Boussaha, Myriam; Thibault, Nicolas Rudolph

2014-01-01

and cores analyses, respectively.However, few sites allow to combine all the different scale of observation for chalk diagenesis. Onshore and offshore high resolution seismics, two fully cored >350 m wells with wireline logging tools and very high quality exposures from a coastal cliff and a quarry form...... works have been performed with astronomical calibration based on stable isotope stratigraphy, wireline logs as well as several palaeontological proxies and detailed sedimentological analysis. Since a couple of decades, a specific kind of fractures has been described in the Chalk of Denmark, the so...

Integrated seismic analysis of the Chalk Group in eastern Denmark—Implications for estimates of maximum palaeo-burial in southwest Scandinavia

DEFF Research Database (Denmark)

Nielsen, Lars; Boldreel, Lars Ole; Hansen, Thomas Mejer

2011-01-01

Group. The sonic velocities are consistent with the overall seismic layering, although they show additional fine-scale layering. Integration of gamma and sonic log with porosity data shows that seismic velocity is sensitive to clay content. In intervals near boundaries of the refraction model, moderate......The origin of the topography of southwest Scandinavia is subject to discussion. Analysis of borehole seismic velocity has formed the basis for interpretation of several hundred metres of Neogene uplift in parts of Denmark.Here, refraction seismic data constrain a 7.5km long P-wave velocity model...... of the Chalk Group below the Stevns peninsula, eastern part of the Danish Basin. The model contains four layers in the ~860m thick Chalk Group with mean velocities of 2.2km/s, 2.4km/s, 3.1km/s, and 3.9–4.3km/s. Sonic and gamma wireline log data from two cored boreholes represent the upper ~450m of the Chalk...

A review of geophysical investigations at the site of Chalk River Nuclear Laboratories, Ontario

International Nuclear Information System (INIS)

Thomas, M.D.; Hayles, J.G.

1988-01-01

The site of the Chalk River Nuclear Laboratories was one of the first research areas located on crystalline rocks to be extensively investigated under the Canadian Nuclear Fuel Waste Management Program. A large contribution to meeting the geoscientific objectives of the program has been made using a suite of geophysical techniques. Many of them are standard, though sometimes modified in terms of instrumentation and/or experimental and/or analytical procedures, to meet the particular needs of the waste management program. Relatively new techniques have also been employed. Much of the early evaluation and development of the various techniques took place at the Chalk River site. Standard methods such as gravity, magnetics and seismic sounding have been used to investigate bedrock structure, and the seismic method has also been used to estimate overburden thickness. Standard geophysical borehole logging has been used to obtain in situ estimates of physical properties, to locate fracture zones and to make hole to hole correlations that have helped define local structure. Several standard electrical (e.g. resitivity) and electromagnetic (e.g. VLF-EM) techniques have proven successful in identifying water-filled fractures and faults. Relatively new techniques introduced into the geophysics at Chalk River were: ground probing radar; to investigate overburden; borehole TV and acoustic televiewer and VLF-EM, to locate fractures; studies of seismic tube-waves, well tides and temperature logs, to investigate fracture location and permeability. Most of these methods have been successful and are now routinely employed at other research sites

Cenozoic structures and the tectonic evolution of the eastern North Sea

DEFF Research Database (Denmark)

Clausen, O.R.; Nielsen, S.B.; Egholm, D.L.

2011-01-01

Abundant seismic sections and well data from the Cenozoic succession in the eastern North Sea area generally reveal normal faulting, salt tectonics and localized tectonic inversion. However, inferences on the Cenozoic dynamic evolution of the region require thorough analysis of interactions between...... or cover tectonism took place. Our objectives are thus 1) to analyze the interaction between basement and cover structures, and if possible 2) to relate the structures to the regional tectonic evolution. The Zechstein evaporites pinch out onto the Ringkøbing-Fyn High, which in the eastern North Sea...... influencede.g. Miocene deposition and controlled the generation of second order faults. The latter detached along the top Chalk Group due to the topography generated during faulting, i.e. they are second order detachment surfaces. We conclude that the regional tectonic significance of the Cenozoic structures...

Certified reference material for radionuclides in fish flesh sample IAEA-414 (mixed fish from the Irish Sea and North Sea)

DEFF Research Database (Denmark)

Pham, M.K.; Sanchez-Cabeza, J.A.; Povinec, P.P.

2006-01-01

A certified reference material (CRM) for radionuclides in fish sample IAEA-414 (mixed fish from the Irish Sea and North Seas) is described and the results of the certification process are presented. Nine radionuclides (K-40, Cs-137, Th-232, U-234, U-235, U-238, Pu-238, Pu239+240 and Am-241) were...... ratios are also included. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in fish sample, for the development and validation of analytical methods and for training purposes. The material is available from IAEA, Vienna, in 100 g units. (c) 2006 Elsevier Ltd. All...

Study of radioelements drained by Rhone stream to Mediterranean Sea: Strategy of sampling and methodology

International Nuclear Information System (INIS)

Arnaud, M.; Charmasson, S.; Calmet, D.; Fernandez, J.M.

1992-01-01

This paper describes the methods used for water and sediments sampling in rivers and sea. The purpose is the study of radionuclide migration (Cesium 134, Cesium 137) in Mediterranean Sea (Gulf of Lion). 20 refs., 11 figs., 1 tab

Sedimentology of the Upper Maastrichtian chalk, Danish Central Graben. M-10X (Dan Field), E-5X (Tyra SE Field) facies and core logs

Energy Technology Data Exchange (ETDEWEB)

Ineson, J.R.

2004-07-01

Based on detailed logs presented here at 1:10, the cored Upper Maastrichtian succession of the M-10X (Dan Field) and E-5X (Tyra SE Field) wells in the southern Danish Central Graben is subdivided into eight lithofacies and five ichnofabrics. The dominant bioturbated or laminated chalk mudstones and subordinate sparse skeletal wackestones are largely the result of pelagic carbonate production, sedimented by suspension settling and small volume, low density turbidity currents. Evidence of winnowing/reduced sedimentation rates is yielded by rare incipient hardgrounds; a well-developed mature hardground profile is developed at the Cretaceous-Danian boundary (the ''Maastrichtian hardground''). Rare marl laminae are recorded and a discrete marly chalk bed associated with an interval of finegrained skeletal chalk wackestones near the top of the Maastrichtian is recognised in both wells. Comparison between the two wells demonstrates that the m-scale laminated-bioturbated chalk cycles described from the Dan Field area are both stratigraphically and areally restricted; this has implications for both cyclostratigraphic correlation and reconstruction of depositional environments and Late Maastrichtian evolution of the Danish Central Graben. (au)

Technetium-99 in Fucus and seawater samples in the Finnish coastal area of the Baltic Sea, 1999

International Nuclear Information System (INIS)

Ikaeheimonen, T.K.; Vartti, V.P.; Ilus, E.; Mattila, J.

2002-01-01

Liquid discharges of 99 Tc from the Sellafield nuclear facilities increased largely in the mid 90's. These releases are transported to the Nordic sea areas by the ocean currents. Results of the 99 Tc activities along the Norwegian coastal areas and in the North Sea have been reported but then again, the spreading of 99 Tc into Baltic Sea has not been studied thoroughly. Fucus vesiculosus and seawater samples were collected in the summer 1999 from the Finnish coastal areas for measuring 99 Tc in the Baltic Sea area. A modified analytical method for measuring 99 Tc in the environmental samples was developed at that time. The method based on extraction chromatography and liquid scintillation measurement of 99 Tc. The 99 Tc concentration in the Fucus vesiculosus in the Finnish coast of the Baltic Sea varied from 1.6 to 11.6 Bq/kg (dry weight) being highest at the most northern sampling sites. These values were considerable lower than those in the Danish and Norwegian coasts. The variation in the concentrations observed are probably due to biological factors. The 99 Tc concentration in the Baltic Sea water studied was below 0.2 Bq/m 3 . (author)

The dynamic analysis facility at the Chalk River Nuclear Laboratories

International Nuclear Information System (INIS)

Argue, D.S.; Howatt, W.T.

1979-10-01

The Dynamic Analysis Facility at the Chalk River Nuclear Laboratories (CRNL) of Atomic Energy of Canada Limited (AECL) comprises a Hybrid Computer, consisting of two Applied Dynamic International AD/FIVE analog computers and a Digital Equipment Corporation (DEC) PDP-11/55 digital computer, and a Program Development System based on a DEC PDP-11/45 digital computer. This report describes the functions of the various hardware components of the Dynamic Analysis Facility and the interactions between them. A brief description of the software available to the user is also given. (auth)

Aerobic degradation potential of the herbicides mecoprop, dichlorprop and bentazone in groundwater from chalk aquifers

DEFF Research Database (Denmark)

Levi, Suzi; Hybel, Anne-Marie; Bjerg, Poul Løgstrup

2011-01-01

The aerobic degradation potential of mecoprop, dichlorprop and bentazone was studied at concentration of 1 μg/L in laboratory batch experiments with groundwater from chalk aquifers. Within the incubation period of 129 days, 14C-mecoprop concentration decreased to 60-80% in the microcosms with gro...

Determination of naturally radioactive elements in chalk sticks by means of gamma spectroscopy

Science.gov (United States)

Abd El-Wahab, Magda; Morsy, Zeinab; El-Faramawy, Nabil

2010-04-01

The radiation hazards due to ingestion of chalkboard dust were investigated. Sixteen samples from three different origin fabricates were used. The estimation of radiation hazard indices were based on the evaluation of the concentration activities of the natural radionuclides 238U, 232Th and 40K. The radium equivalent activity, external hazard index, internal hazard index and the annual dose equivalent associated with the radionuclides were calculated and compared with international recommended values to assess the radiation hazard. The values of internal and external radiation hazard indices were found to be less than unity. The annual effective dose rate obtained, E eff, and the annual gonadal dose equivalent (AGDE) are found to be less than the limit of the doses recommended by the International Commission on Radiological Protection for the general public. The analytical results show that besides the main calcium content, some toxic elements, S, Mo and Pb and Ni and Pb, in the Egyptian and imported chalk stocks, respectively, existed.

Water movements in the unsaturated zone and recharge of the aquifer in the Champagne Chalk (France): Isotopic and chemical approaches

International Nuclear Information System (INIS)

Vachier, P.; Dever, L.; Fontes, J.C.

1987-01-01

Water from the unsaturated zone in the chalk, obtained from porous plugs, was subjected to chemical and isotope analyses over a three-year period. Tensiometric and volumetric water content measurements were carried out at the same time. The results obtained make it possible to establish an outline of the hydrodynamics of this porous, fissured chalk medium. Matrix porosity was 0.42 while fissure porosity was in the region of 0.01. The tritium and nitrate concentrations in the water fix the mean residence time in the 20-metre unsaturated zone at about 30 years. The isotope profiles ( 18 O and 3 H) and their downward displacements make it possible to estimate the mean annual recharge into the unconfined groundwater in the chalk (200 to 300 mm, depending on plant cover). The vertical movement of the solution in the porous matrix is dominated by the piston effect. Variations in 18 O concentration can be correlated with local climatic fluctuations. The recharge period runs from November to March, with summer rainfall playing no part. A comparison of 2 H and 18 O concentrations shows that even winter rainfall is partially removed by evaporation. (author). 17 refs, 11 figs, 1 tab

COMPARISON OF THE TRADITIONAL CHALK AND BOARD LECTURE SYSTEM VERSUS POWER POINT PRESENTATION AS A TEACHING TECHNIQUE FOR TEACHING GROSS ANATOMY TO THE FIRST PROFESSIONAL MEDICAL STUDENTS

OpenAIRE

Nusrat; Abdul

2015-01-01

Traditionally and conventionally, gross anatomy is taught by lectures and cadaveric dissection and the lectures are taken with chalk and board (C&B) or chalk and talk method in, India. But there is always a debate over the most effective method of lecture delivery. AIM : The aim of this study was to compare the role and effecti...

Estimation of groundwater recharge to chalk and sandstone aquifers using simple soil models

Science.gov (United States)

Ragab, R.; Finch, J.; Harding, R.

1997-03-01

On the assumption that the water draining below the root zone is potentially available for groundwater recharge, two current UK methods for estimating annual groundwater recharge have been compared with a new soil model using data from four sites under permanent grass in the UK: two sites representative of the Chalk aquifer at Bridgest Farm (Hampshire) and Fleam Dyke (Cambridgeshire), and two sites on the Triassic sandstone at Bicton College (Devon) and Bacon Hall (Shropshire). A Four Root Layers Model (FRLM), the Penman-Grindley model and the UK Meteorological Office Rainfall and Evaporation Calculation System (MORECS) were used. The new soil model was run with potential evaporation as input both from the MORECS and from the Penman-Monteith equation. The models were run for the Chalk sites both with and without a bypass flow of 15% of rainfall. Bypass was not considered for the sandstone sites. The performance of the models was tested against neutron probes measurements of soil moisture deficits. In addition, the annual groundwater recharge estimated from the models was compared with the published values obtained from the 'zero flux plane' method. Generally, the Penman-Grindley model was more successful in predicting the time for soil to return to its field capacity than in predicting the magnitude of the soil moisture deficit. The annual groundwater recharge was predicted with reasonable accuracy. The MORECS relatively tended to overestimate the soil moisture deficits and to delay the time at which the soil returns to its field capacity. The consequences were underestimates of annual groundwater recharge, owing either to the higher values of potential evaporation calculated from the MORECS or tothe high available water capacity values associated with the soils under consideration. The new soil model (FRLM) predicts the soil moisture deficits successfully and hence is reliable in estimating the annual groundwater recharge. The model is capable of doing this with

Measuring and Modeling the Displacement of Connate Water in Chalk Core Plugs during Water Injection

DEFF Research Database (Denmark)

Korsbech, Uffe C C; Aage, Helle Karina; Andersen, Bertel Lohmann

2006-01-01

and forms a mixed water bank with almost 100% connate water in the front behind which a gradual transition to pure injection water occurs. This result underpins log interpretations from waterflooded chalk reservoirs. An ad hoc model was set up by use of the results, and the process was examined...

Field studies of radionuclide transport at the Chalk River Laboratories

International Nuclear Information System (INIS)

Champ, D.R.; Killey, R.W.D.; Moltyaner, G.L.

1991-01-01

In this paper the authors summarize the results of: in situ field column experiments to study the transport behaviour of several long-lived radionuclides, 4 natural gradient non-reactive radiotracer injection experiments at the Chalk River Laboratories (CRL) Twin Lake Tracer Test Site, and a model validation study that used data for 90 Sr from two well-defined contaminated groundwater flow systems at CRL. The paper also describes a current re-evaluation of radionuclide release and transport from a 1960 experimental burial (in a CRL sand aquifer) of glass blocks containing fission and activation products. (J.P.N.)

Elements of seismic imaging and velocity analysis – Forward modeling and diffraction analysis of conventional seismic data from the North Sea

DEFF Research Database (Denmark)

Montazeri, Mahboubeh

2018-01-01

comprises important oil and gas reservoirs. By application of well-established conventional velocity analysis methods and high-quality diffraction imaging techniques, this study aims to increase the resolution and the image quality of the seismic data. In order to analyze seismic wave propagation......-outs and salt delineations, which can be extracted from the diffractions. The potential of diffraction imaging techniques was studied for 2D seismic stacked data from the North Sea. In this approach, the applied plane-wave destruction method was successful in order to suppress the reflections from the stacked....... This improved seismic imaging is demonstrated for a salt structure as well as for Overpressured Shale structures and the Top Chalk of the North Sea....

Deep saltwater in Chalk of North-West Europe: origin, interface characteristics and development over geological time

DEFF Research Database (Denmark)

Bonnesen, Ellen Prip; Larsen, F.; Sonnenborg, T.O.

2009-01-01

High-concentration saltwaters occur in many places in the regional Chalk aquifers of North-West Europe; to investigate deep occurrences, profiles of interstitial porewater chemistry have been studied from three 250-450m deep cores drilled in the eastern parts of Zealand, Denmark. At the studied...

Distribution of 137Cs in samples of ocean bottom sediments of the baltic sea in 1982-1983

International Nuclear Information System (INIS)

Gedenov, L.I.; Flegontov, V.M.; Ivanova, L.M.; Kostandov, K.A.

1986-01-01

The concentration of Cs-137 in samples of ocean bottom sediments picked up in 1979 in the Gulf of Finland with a geological nozzle pipe varied within a wide interval of values. The results could indicate nonuniformity of the Cs-137 distribution in ocean bottom sediments as well as the penetration of significant amounts of Cs-137 to large depths. The main error resulted from the sampling technique employed because the upper part of the sediment could be lost. In 1982, a special ground-sampling device, with which the upper layer of sediments in the water layer close to the ocean bottom could be sampled, was tested in the Gulf of Finland and the Northeastern part of the Baltic Sea. The results of a layerwise determination of the Cs-137 concentration in samples of ocean bottom sediments of the Gulf of Finland and of the Baltic Sea are listed. The new soil-sampling device for picking samples of ocean sediments of undisturbed stratification will allow a correct determination of the radionuclide accumulation in the upper layers of ocean bottom sediments in the Baltic Sea

The Chalk River Tritium Extraction Plant

International Nuclear Information System (INIS)

Holtslander, W.J.; Harrison, T.E.; Spagnolo, D.A.

1990-01-01

The Chalk River Tritium Extraction Plant for removal of tritium from heavy water is described. Tritium is present in the heavy water from research reactors in the form of DTO at a concentration in the range of 1-35 Ci/kg. It is removed by a combination of catalytic exchange to transfer the tritium from DTO to DT, followed by cryogenic distillation to separate and concentrate the tritium to T 2 . The tritium product is reacted with titanium and packaged for transportation and storage as titanium tritide. The plant processes heavy water at a rate of 25 kg/h and removes 80% of the tritium and 90% of the protium per pass. Catalytic exchange is carried out in the liquid phase using a proprietary wetproofed catalyst. The plant serves two roles in the Canadian fusion program: it produces pure tritium for use in fusion research and development, and it demonstrates on an industrial scale many of the tritium technologies that are common to the tritium systems in fusion reactors (author)

The Chalk River Tritium Extraction Plant

Energy Technology Data Exchange (ETDEWEB)

Holtslander, W J; Harrison, T E; Spagnolo, D A

1990-07-01

The Chalk River Tritium Extraction Plant for removal of tritium from heavy water is described. Tritium is present in the heavy water from research reactors in the form of DTO at a concentration in the range of 1-35 Ci/kg. It is removed by a combination of catalytic exchange to transfer the tritium from DTO to DT, followed by cryogenic distillation to separate and concentrate the tritium to T{sub 2}. The tritium product is reacted with titanium and packaged for transportation and storage as titanium tritide. The plant processes heavy water at a rate of 25 kg/h and removes 80% of the tritium and 90% of the protium per pass. Catalytic exchange is carried out in the liquid phase using a proprietary wetproofed catalyst. The plant serves two roles in the Canadian fusion program: it produces pure tritium for use in fusion research and development, and it demonstrates on an industrial scale many of the tritium technologies that are common to the tritium systems in fusion reactors (author)

Understanding Fluid Flow during Tectonic Reactivation: An Example from the Flamborough Head Chalk Outcrop (UK

Directory of Open Access Journals (Sweden)

O. Faÿ-Gomord

2018-01-01

Full Text Available Flamborough Head chalks are located at the extremities of E-W and N-S trending fault systems along the Yorkshire coast (UK. Rock deformation is expressed in Selwicks Bay where a normal fault is exposed along with a high density of calcite veins. The fault mineralization is tested using geochemistry. Crosscutting relationships are used to differentiate between three vein generations: a network of parallel veins that are oriented perpendicular to stratigraphy (Group I, hydraulic breccia with typical jigsaw puzzle structure (Group II, and a third generation of calcite veins crosscutting the two previous generations (Group III. Geochemical analyses revealed that all three generations possess the same chemical signature and must reflect successive pulses from the same mineralizing fluid source. Strontium isotope analyses showed that the veins have elevated 87Sr/86Sr ratios, that is, up to 7.110, while ratios of the chalk matrix equal 7.707. The latter value is in agreement with the signature of Late Cretaceous seawater. Consequently, the source of the fluid is external, reflecting an open system. The radiogenic Sr-isotope ratios, combined with low iron concentration, suggest that fluids migrated through sandy deposits. Fluid inclusion salinities range from 0 to 12 eq. wt% NaCl equiv. with a dominance of very low salinity inclusions, reflecting a meteoric signal. This leads to a model where meteoric fluids stored in an underlying confined sandstone aquifer were remobilized. The wide range of salinities could result from mixing of the meteoric fluid with some more saline fluids present in the rock sequence or from the dissolution of salts in the subsurface. In addition to the understanding of the local paragenetic evolution of the veining in Flamborough Head chalks, this study offers an insight into the way how fluid flows and mineralizes along fault zones.

Effective stresses and shear failure pressure from in situ Biot's coefficient, Hejre Field, North Sea

DEFF Research Database (Denmark)

Regel, Jeppe Bendix; Orozova-Bekkevold, Ivanka; Andreassen, Katrine Alling

2017-01-01

, is significantly different from 1. The log-derived Biot's coefficient is above 0.8 in the Shetland Chalk Group and in the Tyne Group, and 0.6-0.8 in the Heno Sandstone Formation. We show that the effective vertical and horizontal stresses obtained using the log-derived Biot's coefficient result in a drilling......We propose a combination of Biot's equations for effective stress and the expression for shear failure in a rock to obtain an expression for minimum pore pressure in a stable vertical well bore. We show that a Biot's coefficient calculated from logging data in the Hejre Field, North Sea...

Intercomparison of radionuclide measurements in Baltic Sea water sample IAEA-299

International Nuclear Information System (INIS)

Ballestra, S.; Lopez, J.J.

1993-03-01

This report contains the results of the intercomparison exercise on IAEA-299 for the determination of 90 Sr, 134 Cs and 137 Cs concentration in Baltic Sea Water. The participants belong to 8 laboratories located in 6 countries, members of the Helsinki commission. Statistical evaluation of the data reported yields to recommended values for these elements. The elements, their recommended values and confidence intervals are listed here: 90 Sr: 13.6 Bq kg -1 (12.8-14.4); 134 Cs: 6.7 Bq kg -1 (5-8.3); 137 Cs: 70.9 Bq kg -1 (68-72.3). Reference date: 27 June 1991 (sampling date). The data reported by the laboratories of the Baltic Sea States are generally in very good agreement. (author)

Technical Note: Comparison of storage strategies of sea surface microlayer samples

Directory of Open Access Journals (Sweden)

K. Schneider-Zapp

2013-07-01

Full Text Available The sea surface microlayer (SML is an important biogeochemical system whose physico-chemical analysis often necessitates some degree of sample storage. However, many SML components degrade with time so the development of optimal storage protocols is paramount. We here briefly review some commonly used treatment and storage protocols. Using freshwater and saline SML samples from a river estuary, we investigated temporal changes in surfactant activity (SA and the absorbance and fluorescence of chromophoric dissolved organic matter (CDOM over four weeks, following selected sample treatment and storage protocols. Some variability in the effectiveness of individual protocols most likely reflects sample provenance. None of the various protocols examined performed any better than dark storage at 4 °C without pre-treatment. We therefore recommend storing samples refrigerated in the dark.

Sea Ice as a Sink for CO2 and Biogeochemical Material: a Novel Sampling Method and Astrobiological Applications

Science.gov (United States)

Wilner, J.; Hofmann, A.; Hand, K. P.

2017-12-01

Accurately modelling the intensification of greenhouse gas effects in the polar regions ("polar amplification") necessitates a thorough understanding of the geochemical balance between atmospheric, sea ice, and oceanic layers. Sea ice is highly permeable to CO2 and therefore represents a major sink of oceanic CO2 in winter and of atmospheric CO2 in summer, sinks that are typically either poorly constrained in or fully absent from global climate models. We present a novel method for sampling both trapped and dissolved gases (CO2, CH4 and δ13CH4) in sea ice with a Picarro 2132-i Methane Analyzer, taking the following sampling considerations into account: minimization of water and air contamination, full headspace sampling, prevention of inadvertent sample bag double-puncturing, and ease of use. This method involves melting of vacuum-sealed ice cores to evacuate trapped gases to the headspace and sampling the headspace gas with a blunt needle sheathed by a beveled puncturing needle. A gravity catchment tube prevents input of dangerous levels of liquid water to the Picarro cavity. Subsequent ultrasonic degassing allows for dissolved gas measurement. We are in the process of using this method to sample gases trapped and dissolved in Arctic autumn sea ice cores and atmospheric samples collected during the 2016 Polarstern Expedition and during a May 2017 field campaign north of Barrow, Alaska. We additionally employ this method, together with inductively coupled plasma mass spectrometry (ICP-MS), to analyze the transfer of potential biogeochemical signatures of underlying hydrothermal plumes to sea ice. This has particular relevance to Europa and Enceladus, where hypothetical hydrothermal plumes may deliver seafloor chemicals to the overlying ice shell. Hence, we are presently investigating the entrainment of methane and other hydrothermal material in sea ice cores collected along the Gakkel Ridge that may serve as biosignatures of methanogenic organisms in seafloor

[Bacterial diversity within different sections of summer sea-ice samples from the Prydz Bay, Antarctica].

Science.gov (United States)

Ma, Jifei; Du, Zongjun; Luo, Wei; Yu, Yong; Zeng, Yixin; Chen, Bo; Li, Huirong

2013-02-04

In order to assess bacterial abundance and diversity within three different sections of summer sea-ice samples collected from the Prydz Bay, Antarctica. Fluorescence in situ hybridization was applied to determine the proportions of Bacteria in sea-ice. Bacterial community composition within sea ice was analyzed by 16S rRNA gene clone library construction. Correlation analysis was performed between the physicochemical parameters and the bacterial diversity and abundance within sea ice. The result of fluorescence in situ hybridization shows that bacteria were abundant in the bottom section, and the concentration of total organic carbon, total organic nitrogen and phosphate may be the main factors for bacterial abundance. In bacterial 16S rRNA gene libraries of sea-ice, nearly complete 16S rRNA gene sequences were grouped into three distinct lineages of Bacteria (gamma-Proteobacteria, alpha-Proteobacteria and Bacteroidetes). Most clone sequences were related to cultured bacterial isolates from the marine environment, arctic and Antarctic sea-ice with high similarity. The member of Bacteroidetes was not detected in the bottom section of sea-ice. The bacterial communities within sea-ice were little heterogeneous at the genus-level between different sections, and the concentration of NH4+ may cause this distribution. The number of bacteria was abundant in the bottom section of sea-ice. Gamma-proteobacteria was the dominant bacterial lineage in sea-ice.

Modelling flow and heat transfer through unsaturated chalk - Validation with experimental data from the ground surface to the aquifer

Science.gov (United States)

Thiéry, Dominique; Amraoui, Nadia; Noyer, Marie-Luce

2018-01-01

During the winter and spring of 2000-2001, large floods occurred in northern France (Somme River Basin) and southern England (Patcham area of Brighton) in valleys that are developed on Chalk outcrops. The floods durations were particularly long (more than 3 months in the Somme Basin) and caused significant damage in both countries. To improve the understanding of groundwater flooding in Chalk catchments, an experimental site was set up in the Hallue basin, which is located in the Somme River Basin (France). Unsaturated fractured chalk formation overlying the Chalk aquifer was monitored to understand its reaction to long and heavy rainfall events when it reaches a near saturation state. The water content and soil temperature were monitored to a depth of 8 m, and the matrix pressure was monitored down to the water table, 26.5 m below ground level. The monitoring extended over a 2.5-year period (2006-2008) under natural conditions and during two periods when heavy, artificial infiltration was induced. The objective of the paper is to describe a vertical numerical flow model based on Richards' equation using these data that was developed to simulate infiltrating rainwater flow from the ground surface to the saturated aquifer. The MARTHE computer code, which models the unsaturated-saturated continuum, was adapted to reproduce the monitored high saturation periods. Composite constitutive functions (hydraulic conductivity-saturation and pressure-saturation) that integrate the increase in hydraulic conductivity near saturation and extra available porosity resulting from fractures were introduced into the code. Using these composite constitutive functions, the model was able to accurately simulate the water contents and pressures at all depths over the entire monitored period, including the infiltration tests. The soil temperature was also accurately simulated at all depths, except during the infiltrations tests, which contributes to the model validation. The model was used

A review of analytical techniques for the determination of carbon-14 in environmental samples

International Nuclear Information System (INIS)

Milton, G.M.; Brown, R.M.

1993-11-01

This report contains a brief summary of analytical techniques commonly used for the determination of radiocarbon in a variety of environmental samples. Details of the applicable procedures developed and tested in the Environmental Research Branch at Chalk River Laboratories are appended

Effluent and environmental monitoring of Chalk River Laboratories

Energy Technology Data Exchange (ETDEWEB)

Pilgrim, T.; De Waele, C.; Gallagher, C. [Atomic Energy of Canada Limited, Chalk River, ON (Canada)

2014-07-01

Atomic Energy of Canada Limited's (AECL's) Environmental Protection Program has been gathering environmental monitoring data at its Chalk River Laboratories (CRL) for over 60 years. The comprehensive effluent and environmental monitoring program at CRL consists of more than 600 sampling locations, including the Ottawa River, with approximately 60,000 analyses performed on air and liquid effluent parameters each year. Monitoring for a variety of radiological and non-radiological parameters is regularly conducted on various media, including ambient air, foodstuff (e.g. milk, fish, garden produce, large game, and farm animals), groundwater, Ottawa River water and other surface water on and off-site. The purpose of the monitoring program is to verify that past and current radiological and non-radiological emissions derived from AECL operations and activities, such as process water effluent into the Ottawa River, are below regulatory limits and demonstrate that CRL operations do not negatively affect the quality of water on or leaving the site. In fact, ongoing program reports demonstrate that radiological emissions are well below regulatory limits and have been declining for the past five years, and that non-radiological contaminants do not negatively affect the quality of water on and off the site. Two updated Canadian Standards Association (CSA) standards for Effluent and Environmental monitoring have come into effect and have resulted in some changes to the AECL Program. This presentation will discuss effluent and surface water monitoring results, the observed trends, the changes triggered by the CSA standards, and a path forward for the future. (author)

Certified reference material for radionuclides in fish flesh sample IAEA-414 (mixed fish from the Irish Sea and North Sea)

International Nuclear Information System (INIS)

Pham, M.K.; Sanchez-Cabeza, J.A.; Povinec, P.P.; Arnold, D.; Benmansour, M.; Bojanowski, R.; Carvalho, F.P.; Kim, C.K.; Esposito, M.; Gastaud, J.; Gasco, C.L.; Ham, G.J.; Hegde, A.G.; Holm, E.; Jaskierowicz, D.; Kanisch, G.; Llaurado, M.; La Rosa, J.; Lee, S.-H.; Liong Wee Kwong, L.; Le Petit, G.; Maruo, Y.; Nielsen, S.P.; Oh, J.-S.; Oregioni, B.; Palomares, J.; Pettersson, H.B.L.; Rulik, P.; Ryan, T.P.; Sato, K.; Schikowski, J.; Skwarzec, B.; Smedley, P.A.; Tarjan, S.; Vajda, N.; Wyse, E.

2006-01-01

A certified reference material (CRM) for radionuclides in fish sample IAEA-414 (mixed fish from the Irish Sea and North Seas) is described and the results of the certification process are presented. Nine radionuclides ( 4 K, 137 Cs, 232 Th, 234 U, 235 U, 238 U, 238 Pu, 239+24 Pu and 241 Am) were certified for this material. Information on massic activities with 95% confidence intervals is given for six other radionuclides ( 9 Sr, 21 Pb( 21 Po), 226 Ra, 239 Pu, 24 Pu 241 Pu). Less frequently reported radionuclides ( 99 Tc, 129 I, 228 Th, 23 Th and 237 Np) and information on some activity and mass ratios are also included. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in fish sample, for the development and validation of analytical methods and for training purposes. The material is available from IAEA, Vienna, in 100 g units

Life-history strategies as a tool to identify conservation constraints: A case-study on ants in chalk grasslands

NARCIS (Netherlands)

Noordwijk, C.G.E.; Boer, P.; Mabelis, A.A.; Verberk, W.C.E.P.; Siepel, H.

2012-01-01

Species’ life-history traits underlie species–environment relationships. Therefore, analysis of species traits, combined into life-history strategies, can be used to identify key factors shaping the local species composition. This is demonstrated in a case-study on ants in chalk grasslands. We

Radioactivity levels in some sediment samples from Red Sea and Baltic Sea

International Nuclear Information System (INIS)

Salahel Din, K.; Vesterbacka, P.

2012-01-01

Levels of 226, 228 Ra, 232 Th, 210 Pb, 210 Po and 40 K in sediments from four monitoring areas, El Hamraween and Ras El Behar (Red Sea (Egypt)) and LL3A and JML (Baltic Sea (Finland)), have been investigated using alpha and gamma spectrometry. The average activity concentrations were 238±4 Bq kg -1 ( 226 Ra), 215±11 Bq kg -1 ( 210 Pb) and 311±18 Bq kg -1 ( 210 Po) for El Hamraween area. In Ras El Behar area, the corresponding values were 16±0.4, 18±1 and 20±5 Bq kg -1 , respectively. The activity concentrations for 226 Ra, 210 Pb and 210 Po (uranium series) in El Hamraween bottom sediment are much high compared with those in Ras El Behar area, which indicates the enhanced levels due to the activities of phosphate mining and shipment operations in El Hamraween area. Excluding the influence of phosphate mining activities, it can be concluded that the levels of radioactivity in Baltic Sea sediments are higher than those in Red Sea sediments. (authors)

Derived release limits (DRL's) for airborne and liquid effluents from the Chalk River Nuclear Laboratories during normal operations

International Nuclear Information System (INIS)

Palmer, J.F.

1981-02-01

Derived release limits (DRL's), based on regulatory dose limits, have been calculated for routine discharges of radioactivity in airborne and liquid effluents from the Chalk River Nuclear Laboratories. Three types of sources of airborne effluents were considered: the NRX/NRU stack, the 61 m stack connected to the 99 Mo production facility, and a roof vent typical of those installed on several buildings on the site. Sources of liquid effluents to the Ottawa River were treated as a single source from the site as a whole. Various exposure pathways to workers on the site and to members of the public outside the site boundary were considered in the calculations. The DRL's represent upper limits for routine emissions of radioactivity from the Chalk River Nuclear Laboratories to the surrounding environment. Actual releases are regulated by Administrative Levels, set lower than the DRL's, and are confirmed by monitoring. (author)

Uranium-phosphate relationship in phosphated chalks of the Mons and Picardie Bassins

Energy Technology Data Exchange (ETDEWEB)

Quinif, Y; Charlet, J M; Dupuis, C; Robaszynski, F [Faculte Polytechnique de Mons (Belgium)

1981-11-30

The lithological and geochemical conditions relative to the ''Senonian'' phosphatic chalks are relatively simple in the Basins of Mons (Belgium) and of Picardy (France). Their characteristics permit us to study chiefly the uranium-phosphate relation. It appears a very good linear correlation between the phosphate and the uranium. The coefficient U/P/sub 2/O/sub 5/ remains a constant from the bottom to the top of the same section, but changes in space for synchronic formations (lateral variation of geochemical facies) and in time for two separated basins.

Uranium and plutonium containing particles in a sea sediment sample from Thule, Greenland

DEFF Research Database (Denmark)

Moring, M.; Ikäheimonen, T.K.; Pöllänen, R.

2001-01-01

Particles composed of radioactive materials and probably originating from US nuclear weapons were identified in sea sediment samples collected from Thule, Greenland in 1997. The weapons were destroyed close to the Thule Air Base in 1968 in an aeroplane crash, which dispersed radioactive materials...

Proceedings of a workshop on geophysical and related geoscientific research at Chalk River, Ontario

International Nuclear Information System (INIS)

Thomas, M.D.; Dixon, D.F.

1989-10-01

A large part of the Canadian Nuclear Fuel Waste Management Program is geoscience research and development aimed at obtaining information to quantify the transport of radionuclides through the geosphere and at determining the geotechnical properties required for disposal vault design. The geosphere at potential disposal sites is characterized in part by the use of remote sensing (geophysical) methods. In 1977 public concern about the disposal of radioactive waste resulted in field work being restricted to the site of Chalk River Nuclear Laboratories, which was used to develop, evaluate and compare various techniques in order to optimize the methods for obtaining geoscience information. Methods tested at Chalk River are to be applied at other research sites. Most investigations have been carried out around Maskinonge Lake, using about thirty boreholes sink into bedrock. The boreholes provide subsurface geological information that can be used as a reference to compare the responses of various geophysical methods and equipment. Regional studies, including airborne geophysical surveys, have also been conducted. The 25 papers presented at this workshop provide comprehensive documentation of the most significant results of geophysical studies. The workshop also provided an evaluation of geophysical techniques and their utility to the Nuclear Fuel Waste Management Program

The Use of Hydrograph Analysis and Impulse Response Functions to Improve Understanding of Groundwater Flooding: A Case Study from the Chalk Aquifer, United Kingdom.

Science.gov (United States)

Ascott, M.; Bloomfield, J.; Macdonald, D.; Marchant, B.; McKenzie, A.

2017-12-01

The Cretaceous Chalk, the most important aquifer in the United Kingdom (UK) for public water supply, underlies many large cities in southern and eastern England including parts of London, however, it is prone to groundwater flooding. We have developed a new approach to analyse the spatio-temporal extent of groundwater flooding using statistical analysis of groundwater level hydrographs and impulse response functions (IRFs) applied to a major Chalk groundwater flooding event in the UK during winter 2013/14. Using monthly groundwater levels for 26 boreholes in the Chalk and a new standardised index for groundwater flooding, we have: estimated standardised series; grouped them using k-means cluster analysis; and, cross-correlated the cluster centroids with the Standardised Precipitation Index accumulated over time intervals between 1 and 60 months. This analysis reveals two spatially coherent groups of standardised hydrographs which respond to precipitation over different timescales. We estimate IRF models of the groundwater level response to effective precipitation for three boreholes in each group. The IRF models support the SPI analysis showing different response functions between the two groups. If we apply identical effective precipitation inputs to each of the IRF models we see differences between the hydrographs from each group. It is proposed that these differences are due to the intrinsic, hydrogeological properties of the Chalk and of overlying relatively low permeability superficial deposits. Consequently, it is concluded that the overarching controls on groundwater flood response are a complex combination of antecedent conditions, rainfall and catchment hydrogeological properties. These controls should be taken into consideration when anticipating and managing future groundwater flood events.

Atmospherically dispersed radiocarbon at the Chalk River Laboratories

International Nuclear Information System (INIS)

Milton, G.M.; Brown, R.M.; Repta, C.J.W.; Selkirk, C.J.

1996-01-01

A small percentage of the total radiocarbon produced by the NRX and NRU experimental reactors at the Chalk River Laboratories has been vented from the main reactor stack and atmospherically dispersed across the site. Surveys conducted in 1982-83 and 1993-94 have shown that atmospheric levels more than 50 m from the stack are never greater than 600 Bq.kg -1 carbon above the natural background level, falling to near-global atmospheric levels at the site boundaries roughly 7 km away. A dispersion factor > 1.2 x 10 6 m 3 .s -1 at ∼ 0.75 km distance from the point of emission is calculated on the basis of recent in-stack monitoring. Analysis of growth rings in on-site trees has provided an opportunity to search for correlations of 14 C output summer power production and/or moderator losses. (author). 16 refs., 14 tabs., 11 figs

Observing System Simulation Experiments for the assessment of temperature sampling strategies in the Mediterranean Sea

Directory of Open Access Journals (Sweden)

F. Raicich

2003-01-01

Full Text Available For the first time in the Mediterranean Sea various temperature sampling strategies are studied and compared to each other by means of the Observing System Simulation Experiment technique. Their usefulness in the framework of the Mediterranean Forecasting System (MFS is assessed by quantifying their impact in a Mediterranean General Circulation Model in numerical twin experiments via univariate data assimilation of temperature profiles in summer and winter conditions. Data assimilation is performed by means of the optimal interpolation algorithm implemented in the SOFA (System for Ocean Forecasting and Analysis code. The sampling strategies studied here include various combinations of eXpendable BathyThermograph (XBT profiles collected along Volunteer Observing Ship (VOS tracks, Airborne XBTs (AXBTs and sea surface temperatures. The actual sampling strategy adopted in the MFS Pilot Project during the Targeted Operational Period (TOP, winter-spring 2000 is also studied. The data impact is quantified by the error reduction relative to the free run. The most effective sampling strategies determine 25–40% error reduction, depending on the season, the geographic area and the depth range. A qualitative relationship can be recognized in terms of the spread of information from the data positions, between basin circulation features and spatial patterns of the error reduction fields, as a function of different spatial and seasonal characteristics of the dynamics. The largest error reductions are observed when samplings are characterized by extensive spatial coverages, as in the cases of AXBTs and the combination of XBTs and surface temperatures. The sampling strategy adopted during the TOP is characterized by little impact, as a consequence of a sampling frequency that is too low. Key words. Oceanography: general (marginal and semi-enclosed seas; numerical modelling

Observing System Simulation Experiments for the assessment of temperature sampling strategies in the Mediterranean Sea

Directory of Open Access Journals (Sweden)

F. Raicich

Full Text Available For the first time in the Mediterranean Sea various temperature sampling strategies are studied and compared to each other by means of the Observing System Simulation Experiment technique. Their usefulness in the framework of the Mediterranean Forecasting System (MFS is assessed by quantifying their impact in a Mediterranean General Circulation Model in numerical twin experiments via univariate data assimilation of temperature profiles in summer and winter conditions. Data assimilation is performed by means of the optimal interpolation algorithm implemented in the SOFA (System for Ocean Forecasting and Analysis code. The sampling strategies studied here include various combinations of eXpendable BathyThermograph (XBT profiles collected along Volunteer Observing Ship (VOS tracks, Airborne XBTs (AXBTs and sea surface temperatures. The actual sampling strategy adopted in the MFS Pilot Project during the Targeted Operational Period (TOP, winter-spring 2000 is also studied.

The data impact is quantified by the error reduction relative to the free run. The most effective sampling strategies determine 25–40% error reduction, depending on the season, the geographic area and the depth range. A qualitative relationship can be recognized in terms of the spread of information from the data positions, between basin circulation features and spatial patterns of the error reduction fields, as a function of different spatial and seasonal characteristics of the dynamics. The largest error reductions are observed when samplings are characterized by extensive spatial coverages, as in the cases of AXBTs and the combination of XBTs and surface temperatures. The sampling strategy adopted during the TOP is characterized by little impact, as a consequence of a sampling frequency that is too low.

Key words. Oceanography: general (marginal and semi-enclosed seas; numerical modelling

A comparative study of the adsorption of uranium on commercial and natural (Cypriot) sea sand samples

International Nuclear Information System (INIS)

Maria Efstathiou; Ioannis Pashalidis

2013-01-01

The adsorption of hexavalent uranium on two different types of sea sand [e.g. a local, Cypriot (N S S) and a commercially available marine sediment (C S S)] has been investigated as a function of pH, initial metal concentration, ionic strength and contact time under normal atmospheric conditions. Before carrying out the adsorption experiments, the sea sand samples have been characterized by XRD, XRF, N 2 -adsorption, acid/base titrations and FTIR spectroscopy. Sample characterization showed clearly that the two sea sand types differ significantly in their composition, particularly in their calcite and FeOOH content. According to experimental data obtained from acid/base titrations and adsorption batch experiments sea sand composition affects the acid/base and the adsorption properties of the adsorbents. The extraordinary high affinity of N S S for hexavalent uranium in the alkaline pH region can be attributed to the formation of mixed U(VI)-carbonato surface species on the FeOOH crystal phases present in N S S, which effectively compete the formation of U(VI)-carbonato complexes in solution. On the other hand, data obtained by adsorption experiments carried out in solution of different ionic strengths don't differ significantly from one another indicating the formation of inner-sphere complexes. Finally, the adsorption on sea sands is a relatively fast two-step process. (author)

Spreading Design of Radioactivity in Sea Water, Algae and Fish Samples inthe Coastal of Muria Peninsula Area

International Nuclear Information System (INIS)

Sutjipto; Muryono; Sumining

2000-01-01

Spreading design of radioactivity in sea water, brown algae (phaeopyceae)and kerapu fish (epeniphelus) samples in the coastal of Muria peninsula areahas been studied. This research was carried out with designed beside to knowspreading each radioactivity but also spreading design in relation to thecontent of Pu-239 and Cs-137. Samples taken, preparation and analysis basedon the procedures of environmental radioactivity analysis. The instrumentused for the analysis radioactivity were alpha counter with detector ZnS, lowlevel beta counter modified P3TM-BATAN with detector GM and spectrometergamma with detector Ge(Li). Alpha radioactivity obtained of sea water, algaeand fish were the fluctuation form of the natural background. Radionuclide ofPu-239 in samples not detect, because its concentration/radioactivity stillbelow the maximum concentration detection value of Pu-239 for algae and fishwas that 1.10 Bq/g, whereas for sea water was that 0.07 Bq/mL. Result for theradioactivity which give the highest alpha radioactivity obtained on thekerapu fish was that 1.56 x 10 -3 Bq/g, beta radioactivity on sea water wasthat 1.75 x 10 2 mBq/L, gamma radioactivity of K-40 on brown algae was that3.72 x 10 -2 Bq/g and gamma radioactivity of Tl-208 on fish as mentionedabove was that 1.35 x 10 -2 Bq/g. All the peak spectrum gamma energy ofCs-137 do not detect with gamma counter, so there are not the radionuclide ofCs-137 in the samples. Spreading design of radioactivity which occur in thecoastal of Muria peninsula area for alpha radioactivity was found on kerapufish, beta radioactivities on sea water and gamma radioactivity on brownalgae and kerapu fish. (author)

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea and others from 1998-02-19 to 1998-03-05 (NCEI Accession 0157460)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157460 includes chemical, discrete sample, physical and profile data collected from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea, Flores...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea and others from 1996-11-21 to 1996-12-13 (NCEI Accession 0157473)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157473 includes chemical, discrete sample, physical and profile data collected from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea, Flores...

Analysis of the Pelletron charging chain break in the Chalk River MP tandem accelerator

International Nuclear Information System (INIS)

Burn, N.; Greiner, B.F.; Coleman, C.E.

1980-11-01

On February 7, 1980 one of the three Pelletron charging chains in the Low Energy end of the Chalk River MP Tandem Accelerator broke during normal operation. The chains had been in use for 38 000 h at the time of the break. Tensile tests were carried out on pieces of the broken chain as well as unused pieces of chain. Several possible reasons for the chain break are suggested; ways of improving performance and reliability are proposed. (auth)

Field burial results and SIMS analysis of the Chalk River glass blocks

International Nuclear Information System (INIS)

Tait, J.C.; Hocking, W.H.; Betteridge, J.S.; Bart, G.

1986-01-01

In 1959, 25 2-kg hemispherical blocks of aluminosilicate glass, each containing ∼90 MBq/g of mixed fission products, were buried in a sandy soil aquifer in the waste management area at the Chalk River Nuclear Laboratories. A second set of blocks, containing ∼260 MBq/g mixed fission products, was buried in 1960. One block from each test was retrieved in 1978 to undergo chemical and surface analysis. This report reviews the migration of the 90 Sr and 137 Cs plume in the soil and presents the results of SIMS depth profiling of the surface of a glass block. (author)

Status of the Chalk River superconducting heavy-ion cyclotron

International Nuclear Information System (INIS)

Ormrod, J.H.; Bigham, C.B.; Heighway, E.A.; Hoffmann, C.R.; Hulbert, J.A.; Schneider, H.R.

1982-01-01

The Chalk River four-sector K=520 superconducting cyclotron is designed to accelerate all ions from lithium (to 50 MeV/u) to uranium (to 10 MeV/u) using a 13 MV tandem Van de Graaff as injector. After an extended shutdown the magnet has been reassembled and field measurements resumed. During the shutdown a ground fault between the superconducting coil and its container was removed, the flutter poles were shimmed and the remaining trim rod holes were bored in them, the 104 trim rods with their holders were installed and the cryostat inner wall was modified to accept the radiofrequency accelerating structure. Experiments on the radiofrequency accelerating system, cryopumps, electrostatic deflector and superconducting windings for the magnetic channel are done in separate test chambers. Recent results and the status of all subsystems are given

Programme of research into the management and storage of radioactive waste. Single fracture experiment at Chalk River

International Nuclear Information System (INIS)

Bourke, P.J.

1984-01-01

A field experiment was carried out at Chalk river to measure the transport of bromine and strontium through a fracture in granite. Retardation of strontium transport by sorption onto the rock was also measured. Data was obtained for bromine but no useful data was obtained for strontium due to failure of the hydraulic equipment. (U.K.)

Application of the spectrometric and radiochemical techniques in analyzing environmental samples from the Bulgarian Black Sea region

International Nuclear Information System (INIS)

Veleva, B.S.; Mungov, G.; Galabov, N.; Kolarova, M.; Guenchev, T.

1999-01-01

Development of the appropriate methods and techniques for marine and atmospheric radioactivity measurements in the NIMH-BAS during the last 5 years is presented. Approaches for pre-concentration of the radionuclides from the atmosphere and sea water samples followed with reliable radiochemical methods for radionuclides separation and low level counting are discussed. Dissolved radiocesium concentrations measured in a period of time starting in 1993 show some decrease with years and spatial variations probably due to the hydrophysical features of the sampling sides - the lower measured concentrations during 1995 and 1998 correspond to the lower salinity. Application of the radiochemical separation of Plutonium, Thorium, 90 Sr and Americium on the samples from the Bulgarian Black Sea coastal region is reported. (author)

Overview of research in physics and health sciences at the Chalk River Nuclear Laboratories

International Nuclear Information System (INIS)

Milton, J.C.D.

1988-01-01

Toxicology research was a logical extension of existing program at Chalk River. Research in radiotoxicology has been going on there since the early forties. An overview of the existing physics and health sciences research programs operating at the Research Company of Atomic Energy of Canada Limited was presented. Programs in nuclear physics, heavy ion nuclear physics, astrophysical neutrino physics, condensed matter physics, fusion, biology, dosimetry, and environmental sciences were briefly described. In addition, a description of the research company organization was provided

Statistical analysis of temperature data sampled at Station-M in the Norwegian Sea

Science.gov (United States)

Lorentzen, Torbjørn

2014-02-01

The paper analyzes sea temperature data sampled at Station-M in the Norwegian Sea. The data cover the period 1948-2010. The following questions are addressed: What type of stochastic process characterizes the temperature series? Are there any changes or patterns which indicate climate change? Are there any characteristics in the data which can be linked to the shrinking sea-ice in the Arctic area? Can the series be modeled consistently and applied in forecasting of the future sea temperature? The paper applies the following methods: Augmented Dickey-Fuller tests for testing of unit-root and stationarity, ARIMA-models in univariate modeling, cointegration and error-correcting models are applied in estimating short- and long-term dynamics of non-stationary series, Granger-causality tests in analyzing the interaction pattern between the deep and upper layer temperatures, and simultaneous equation systems are applied in forecasting future temperature. The paper shows that temperature at 2000 m Granger-causes temperature at 150 m, and that the 2000 m series can represent an important information carrier of the long-term development of the sea temperature in the geographical area. Descriptive statistics shows that the temperature level has been on a positive trend since the beginning of the 1980s which is also measured in most of the oceans in the North Atlantic. The analysis shows that the temperature series are cointegrated which means they share the same long-term stochastic trend and they do not diverge too far from each other. The measured long-term temperature increase is one of the factors that can explain the shrinking summer sea-ice in the Arctic region. The analysis shows that there is a significant negative correlation between the shrinking sea ice and the sea temperature at Station-M. The paper shows that the temperature forecasts are conditioned on the properties of the stochastic processes, causality pattern between the variables and specification of model

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian Sea from 2000-05-27 to 2000-06-20 (NODC Accession 0115683)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115683 includes biological, chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the Barents Sea, North Greenland Sea...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian Sea from 1999-06-15 to 1999-07-07 (NODC Accession 0115678)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115678 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian...

Electroosmotic dewatering of chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge

DEFF Research Database (Denmark)

Hansen, H.K.; Christensen, Iben Vernegren; Ottosen, Lisbeth M.

2003-01-01

. Casagrande's coefficients were determined for the four materials at different water contents. The experiments in this work showed that chalk could be dewatered from 40% to 79% DM (dry matter), fly ash from 75 to 82% DM, iron hydroxide sludge from 2.7 to 19% DM and biomass from 3 to 33% DM by electroosmosis....... The process was not optimised indicating that higher dry matter contents could be achieved by electroosmosis. It was possible to relate Casagrande's coefficient directly to the electroosmotic coefficient obtained by dewatering experiments....

An overview of the waste characterization program at Chalk River Nuclear Laboratories

International Nuclear Information System (INIS)

Csullog, G.W.; Hardy, D.G.

1990-05-01

A comprehensive Waste Characterization Program (WCP) is in place at Chalk River Laboratories to support disposal projects. The WCP is responsible for: 1) specifying the manifests for waste shipments; 2) developing and maintaining central databases for waste inventories and analytical data; and 3) developing the technologies and procedures to characterize the radiological and the physical/chemical properties of wastes. WCP work is being performed under the umbrella of a newly developed waste management Quality Assurance (QA) program. This paper gives an overview of the WCP with an emphasis on the requirements for determining radionuclide inventories in wastes, for implementing record-keeping systems, and for maintaining a QA program for disposal operations

Precise Th/U-dating of small and heavily coated samples of deep sea corals

Science.gov (United States)

Lomitschka, Michael; Mangini, Augusto

1999-07-01

Marine carbonate skeletons like deep-sea corals are frequently coated with iron and manganese oxides/hydroxides which adsorb additional thorium and uranium out of the sea water. A new cleaning procedure has been developed to reduce this contamination. In this further cleaning step a solution of Na 2EDTA (Na 2H 2T B) and ascorbic acid is used which composition is optimised especially for samples of 20 mg of weight. It was first tested on aliquots of a reef-building coral which had been artificially contaminated with powdered ferromanganese nodule. Applied on heavily contaminated deep-sea corals (scleractinia), it reduced excess 230Th by another order of magnitude in addition to usual cleaning procedures. The measurement of at least three fractions of different contamination, together with an additional standard correction for contaminated carbonates results in Th/U-ages corrected for the authigenic component. A good agreement between Th/U- and 14C-ages can be achieved even for extremely coated corals.

Evaluation of the toxicological properties of ground- and surface-water samples from the Aral Sea Basin

International Nuclear Information System (INIS)

Bosch, K.; Erdinger, L.; Ingel, F.; Khussainova, S.; Utegenova, E.; Bresgen, N.; Eckl, P.M.

2007-01-01

In order to determine whether there is a potential health risk associated with the water supply in the Aral Sea Basin, ground- and surface-water samples were collected in and around Aralsk and from the Aral Sea in 2002. Water samples from Akchi, a small town close to Almaty, served as controls. Bioassays with different toxicological endpoints were employed to assess the general toxicological status. Additionally, the samples were analysed for microbial contamination. The samples were tested in the primary hepatocyte assay for their potential to induce micronuclei and chromosomal aberrations as cumulative indicators for genotoxicity. In parallel, the effects on cell proliferation evidenced by mitotic index and cytotoxicity such as the appearance of necrotic and apoptotic cells, were determined. Furthermore, samples were examined using the Microtox assay for general toxicity. Chemical analysis according to European regulations was performed and soil and water samples were analysed for DDT and DDE. The results obtained indicated no increased cyto- or genotoxic potential of the water samples, nor levels of DDT or DDE exceeding the thresholds levels suggested by WHO. Our data therefore do not support the hypothesis that the contamination of the drinking water in and around Aralsk is responsible for the health effects previously described such as increased rates of liver disease and in particular liver cancer. Microbiological analysis, however, revealed the presence of contamination in most samples analysed

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA I in the Bali Sea, Banda Sea and others from 1994-01-28 to 1994-02-25 (NCEI Accession 0144624)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144624 includes discrete sample and profile data collected from BARUNA JAYA I in the Bali Sea, Banda Sea, Celebes Sea, Ceram Sea or Seram Sea, Flores...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA I in the Bali Sea, Banda Sea and others from 1993-08-08 to 1993-09-09 (NCEI Accession 0144623)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144623 includes discrete sample and profile data collected from BARUNA JAYA I in the Bali Sea, Banda Sea, Celebes Sea, Ceram Sea or Seram Sea, Flores...

Foil changer for the Chalk River superconducting cyclotron

International Nuclear Information System (INIS)

Hoffmann, C.R.; Kilborn, R.I.; Mouris, J.E.; Proulx, D.R.; Weaver, J.F.

1985-01-01

Capture of an injected beam in the Chalk River superconducting cyclotron requires that a carbon stripping foil be accurately placed in a dee to intercept the incoming beam. Foil radial position must be precisely adjustable and foils must be easily replaced. A foil changing apparatus has been designed, built and tested to meet these requirements. The main components are a supply magazine, a transport system, and unloading and loading mechanisms. The magazine is on top of the cyclotron. It holds 300 foils and can be isolated from machine vacuum for refilling. Each foil is mounted on a stainless steel frame. A stainless steel roller chain fitted with 33 copper sleeves (shrouds) carries foils, one per shroud, down a dee stem to the midplane. A 12-bit absolute optical shaft encoder senses foil position. To replace a foil a shroud is positioned at the top of the cyclotron, a foil is removed, and another is transferred from the magazine to the empty shroud. Three stepping motors and associated electronics provide mechanical drive and are interfaced with a CAMAC control system

The Chalk River helium jet and skimmer system

International Nuclear Information System (INIS)

Schmeing, H.; Koslowsky, V.; Wightman, M.; Hardy, J.C.; MacDonald, J.A.; Faestermann, T.; Andrews, H.R.; Geiger, J.S.; Graham, R.L.

1976-01-01

A helium jet and skimmer system intended as an interface between a target location at the Chalk River tandem accelerator and the ion source of an on-line separator presently under construction has been developed. The system consists of a target chamber, a 125 cm long capillary, and a one stage skimmer chamber. The designs of the target and skimmer chambers allow one to vary a large number of independent flow and geometrical parameters with accurate reproducibility. Experiments with the β-delayed proton emitter 25 Si (tsub(1/2)=218 ms) produced in the reaction 24 Mg( 3 He,2n) 25 Si show that under optimized conditions about 75% of the reaction products leaving the target are transported to the skimmer. Of those, more than 90% pass through the skimmer orifice, which separates off 97.5% of the transport gas, helium. By introducing an additional helium flow across the skimming orifice the amount of helium separated off the transport jet can be increased to beyond 99.85%, leaving the high throughput of recoils unaffected. (Auth.)

Compaction monitoring in the Ekofisk area Chalk Fields

International Nuclear Information System (INIS)

Menghini, M.L.

1989-01-01

In late Nov. 1984, the subsidence phenomenon was recognized in the Ekofisk field. To determine the magnitude and areal extent of the formation compaction, a program for measuring compaction with electric logging tools was initiated. Initial time-lapse surveys performed with cased-hole neutron tools indicated that reservoir compaction was occurring, but the accuracy of the determination of compaction rate was low. In addition to the cased-hole neutron survey, radioactive markers and a gamma ray (GR) detection tool were used to determine compaction rate in the reservoir more accurately and to determine whether compaction was occurring in the overburden. A program for implanting radioactive-marker bullets and subsequent monitoring with a four-detector GR tool was implemented. There are currently 13 wells equipped with radioactive markers in the compaction monitoring program. Compaction monitoring accuracy using the four-detector GR tool was found to depend on wellbore geometry, completion design, and radioactive-marker placement. This paper gives the results of the program to date and describes the operational procedures and analysis techniques used for compaction monitoring in the greater Ekofisk area chalk fields

Combining Chalk Talk with PowerPoint to Increase In-class Student Engagement

Directory of Open Access Journals (Sweden)

Swati Betharia

2016-11-01

Full Text Available In striving to attain a higher degree of in-class student engagement, and target a larger number of preferred student-learning styles, this case study describes a multimodal teaching approach. PowerPoint slides have gradually gained popularity over the more traditional chalk and talk lecture design. The student population in today’s age seeks more non-passive modes of information delivery. Numerous novel approaches to enhance active learning, such as flipped classroom and problem-based learning, have recently been explored. While working well for therapeutic and lab-based courses, these formats may not be best-suited for all basic science topics. The importance of basic science in a pharmacy curriculum is well emphasized in the 2016 ACPE Standards. To actively involve students in a pharmacology lecture on diuretics, a session was designed to combine the PowerPoint and chalk talk approaches. Students created 10 concept diagrams following an instructor, who explained each step in the process using a document camera. For visual learners, these diagrams provided a layered representation of the information, gradually increasing in complexity. For learners with a preference for the reading learning style, the information was also available in corresponding PowerPoint slides. Scores from pre- and post-session quizzes indicated a high level of concept understanding and recall (median 1 [IQR 0 – 2] vs 4 [IQR 3 – 5]; p<0.001. The student perception survey data reported higher in-class attention levels (76%, an appreciation for the utility of self-created concept diagrams (88%, and a call for additional sessions being presented in this format (73%. Targeting a variety of student learning styles by using the active development of concept diagrams, in addition to traditional PowerPoint slides, can promote student engagement and enhance content understanding.   Type: Case Study

Agricultural diffuse pollution in a chalk aquifer (Trois Fontaines, France): Influence of pesticide properties and hydrodynamic constraints

Science.gov (United States)

Baran, N.; Lepiller, M.; Mouvet, C.

2008-08-01

SummaryThe characterization of the transfer of pesticides to and in groundwater is essential for effective water resource management. Intensive monitoring, from October 1989 to May 2006, of a weakly karstified chalk aquifer system in a 50 km 2 agricultural catchment, enabled the characterization of the temporal variability of pesticide concentrations in the groundwater of the main outlet. Atrazine and its metabolite deethylatrazine were quantified 394 and 393 times in 476 samples with concentrations ranging from the quantification limit (0.025 μg L -1) to 5.3 and 1.86 μg L -1, respectively. This common presence, compared to the rare detections of isoproturon (in 108 of 476 samples), the pesticide most widely used in the catchment during at least the past decade, highlighted the significant effect of pesticide properties in the time series of concentrations observed in the groundwater. The use of geochemical tracers (nitrate, chloride) analysed in the groundwater and the hydrodynamic monitoring of the system (discharge, water levels) enabled identification of various infiltration mechanisms governing the functioning of the system. The hydrodynamic study showing that the relative contribution of the infiltration mechanisms varies with time, made it possible to explain major variations observed in the pesticide-concentration time series recorded at the spring.

Potentiometric surface of the Upper Patapsco aquifer in southern Maryland, September 2009

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2010-01-01

This report presents a map showing the potentiometric surface of the upper Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland during September 2009. The map is based on water-level measurements in 65 wells. The highest measured water level was 118 feet above sea level near the northern boundary and outcrop area of the aquifer in northern Anne Arundel County. From this area, the potentiometric surface declined to the south toward a well field in the Annapolis-Arnold area, and from all directions toward three additional cones of depression. These cones are located in the Waldorf-La Plata area, Chalk Point, and the Leonardtown-Lexington Park area. The lowest measured groundwater levels were 26 feet below sea level at Annapolis, 108 feet below sea level south of Waldorf, 60 feet below sea level at Chalk Point, and 83 feet below sea level at Leonardtown. The map also shows well yield in gallons per day for 2008 at wells or well fields.

Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge

DEFF Research Database (Denmark)

Anderskouv, Kresten; Surlyk, Finn

2011-01-01

, including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab­sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites...... slump packages (14–18 in total) are interpreted, forming over 40% of the succession; debrites appear to be the most common precursor facies involved in slumping. The vertical succession of facies records an earliest Cenomanian facies shift from dominantly siliciclastic to chalk deposition...

Trace fossils of a cyclic chalk-marl succession; the upper Maastrichtian Rørdal Member, Denmark

DEFF Research Database (Denmark)

Lauridsen, Bodil Wesenberg; Surlyk, Finn; Bromley, Richard Granville

2011-01-01

Trace fossils from an upper Maastrichtian cyclic chalk–marl succession, the Rørdal Member, exposed in the Rørdal quarry, Denmark, are analysed in order to test whether the changes in substrate lithology exerted any control over the ichnodiversity, tiering complexity, and density of the infauna...... in the visibility of traces between chalk and marl and not due to differences in ecological stress upon the endobenthic community of the two lithologies. The study thus provides an excellent example of how the effect of taphonomic factors may give a misleading and biased impression of apparent differences...

Identifying evidence of climate change impact on extreme events in permeable chalk catchments

Science.gov (United States)

Butler, A. P.; Nubert, S.

2009-12-01

The permeable chalk catchments of southern England are vital for the economy and well being of the UK. Not only important as a water resource, their freely draining soils support intensive agricultural production, and the rolling downs and chalk streams provide important habitants for many protected plant and animal species. Consequently, there are concerns about the potential impact of climate change on such catchments, particularly in relation to groundwater recharge. Of major concern are possible changes in extreme events, such as groundwater floods and droughts, as any increase in the frequency and/or severity of these has important consequences for water resources, ecological systems and local infrastructure. Studies of climate change impact on extreme events for such catchments have indicated that, under medium and high emissions scenarios, droughts are likely to become more severe whilst floods less so. However, given the uncertainties in such predictions and the inherent variability in historic data, producing definitive evidence of changes in flood/drought frequency/severity poses a significant challenge. Thus, there is a need for specific extreme event statistics that can be used as indicators of actual climate change in streamflow and groundwater level observations. Identifying such indicators that are sufficiently robust requires catchments with long historic time series data. One such catchment is the River Lavant, an intermittent chalk stream in West Sussex, UK. Located within this catchment is Chilgrove House, the site of the UK’s longest groundwater monitoring well (with a continuous record of water level observations of varying frequency dating back to 1836). Using a variety of meteorological datasets, the behaviour of the catchment has been modelled, from 1855 to present, using a 'leaky aquifer' conceptual model. Model calibration was based on observed daily streamflow, at a gauging station just outside the town of Chichester, from 1970. Long

Foil changer for the Chalk River superconducting cyclotron

International Nuclear Information System (INIS)

Hoffmann, C.R.; Kilborn, R.I.; Mouris, J.F.; Proulx, D.R.; Weaver, J.F.

1985-01-01

Capture of an injected beam in the Chalk River superconducting cyclotron requires that a carbon stripping foil be accurately placed in a dee to intercept the incoming beam. Foil radial position must be precisely adjustable and foils must be easily replaced. A foil changing apparatus has been designed, built and tested to meet these requirements. The main components are a supply magazine, a transport system, and unloading and loading mechanisms. The magazine is on top of the loading mechanisms. The magazine is on top of the cyclotron. It holds 300 foils and can be isolated from machine vacuum for refilling. Each foil is mounted on a stainless steel frame. A stainless steel roller chain fitted with 33 copper sleeves (shrouds) carries foils, one per shroud, down a dee stem to the midplane. A 12-bit absolute optical shaft encoder senses foil position. To replace a foil a shroud is positioned at the top of the cyclotron, a foil is removed, and another is transferred from the magazine to the empty shroud. Three stepping motors and associated electronics provide mechanical drive and are interfaced with a CAMAC control system

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the Barents Sea, North Greenland Sea and Norwegian Sea from 1999-10-03 to 1999-10-11 (NODC Accession 0113888)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113888 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the Barents Sea, North Greenland Sea and Norwegian...

Taxonomic analysis of extremely halophilic archaea isolated from 56-years-old dead sea brine samples.

Science.gov (United States)

Arahal, D R; Gutiérrez, M C; Volcani, B E; Ventosa, A

2000-10-01

A taxonomic study comprising both phenotypic and genotypic characterization, has been carried out on a total of 158 extremely halophilic aerobic archaeal strains. These strains were isolated from enrichments prepared from Dead Sea water samples dating from 1936 that were collected by B. E. Volcani for the demonstration of microbial life in the Dead Sea. The isolates were examined for 126 morphological, physiological, biochemical and nutritional tests. Numerical analysis of the data, by using the S(J) coefficient and UPGMA clustering method, showed that the isolates clustered into six phenons. Twenty-two out of the 158 strains used in this study were characterized previously (ARAHAL et al., 1996) and were placed into five phenotypic groups. The genotypic study included both the determination of the guanineplus-cytosine content of the DNA and DNA-DNA hybridization studies. For this purpose, representative strains from the six phenons were chosen. These groups were found to represent some members of three different genera - Haloarcula (phenons A, B, and C), Haloferax (phenons D and E) and Halobacterium (phenon F) - of the family Halobacteriaceae, some of them never reported to occur in the Dead Sea, such as Haloarcula hispanica, while Haloferax volcanii (phenons D and E) was described in the Dead Sea by studies carried out several decades later than Volcani's work.

Correlation of Heavy Element in Sea Water and Sediment Samples from Peninsula of Muria

International Nuclear Information System (INIS)

Rosidi; Sukirno

2007-01-01

The analysis of heavy metals in marine environmental samples peninsula of Muria in the year 2004 has been carried out by using neutron activation analysis (NAA) method. The objective of this analysis is to know the distribution of heavy metals in the sea water and sediment, which accommodate the recent environmental data in supporting the license of site for the nuclear power plants (NPP). The result of the analysis show that there were only 5 observed elements found in sea water and sediment were Cd, Co, Cr, Sb and Sc. All of heavy metals from sea water (0.002 mg/l) are obviously lower than the threshold value established by environmental minister Act; Kep LH No 51/2004. From the observed data to use software of SPSS version 10, application of the Pearson correlation (r) shows that between Co with Sc was indicator show a highly positive significant correlation (r=0.928), between Cr with Sc was sufficiently positive high (r=0.756), between Cr with Cd was precisely (r=0.611) while Co with Sb shows the significantly low (r=0.429). (author)

Electrostatic deflector development at the Chalk River superconducting cyclotron

International Nuclear Information System (INIS)

Diamond, W.T.; Mitchel, G.R.; Almeida, J.; Schmeing, H.

1991-01-01

An electrostatic deflector is used to extract heavy-ion beans from the Chalk River superconducting cyclotron. Deflector voltages up to 100 kV across a 7 m gap (143 kV/cm) are needed to extract the full range of beams that the cyclotron is designed to accelerate. This goal remains a challenge, but substantial progress has been made over the past year. Voltages over 90 kV have been reliably maintained over a 7.5 mm gap with a magnetic field of 3 T. Voltages of 74 kV have been used with a reduced gap of 4.75 mm (corresponding to a field greater than 150 kV/cm) to extract beams with magnetic fields up to 4.25 T. Major progress was achieved when the authors introduced a water-cooled, negative high-voltage electrode, and changed the sparking plates and the thin septum from molybdenum to stainless steel. Efforts are continuing to attain a field of at least 143 kV/cm over a gap of at least 6 mm width

Importance of small fishes and invasive crayfish in otter Lutra lutra diet in an English chalk stream

OpenAIRE

Britton, J.R.; Berry, M.; Sewell, S.; Lees, C.; Reading, P.

2017-01-01

The diet composition of the European otter Lutra lutra was assessed using spraint analysis in the Hampshire Avon, a lowland chalk stream in Southern England, over an 18-month period. Small cyprinid fishes were the main prey item taken in all seasons, with bullhead Cottus gobio and stone loach Barbatula barbatula also important; there were relatively few larger fishes of interest to fisheries found. There were significant seasonal differences in diet composition by season, with signal crayfish...

Formulation and Implementation of a Constitutive Model for Soft Rock

OpenAIRE

Hickman, Randall John

2004-01-01

Petroleum reservoirs located in the Norwegian sector of the North Sea have undergone unexpected subsidence of great magnitude (> 10 m) during more than 30 years of petroleum recovery operations. Historical laboratory investigations have shown that the subsidence is due to the mechanical behavior and mechanical properties of chalk. Chalk behavior is characterized by elastoplasticity, including pore collapse, shear failure, and tensile failure mechanisms; rate-dependence; and pore fluid depende...

Experience with radioactive waste incineration at Chalk River Nuclear Laboratories

International Nuclear Information System (INIS)

Le, V.T.; Beamer, N.V.; Buckley, L.P.

1988-06-01

Chalk River Nuclear Laboratories is a nuclear research centre operated by Atomic Energy of Canada Limited. A full-scale waste treatment centre has been constructed to process low- and intermediate-level radioactive wastes generated on-site. A batch-loaded, two-stage, starved-air incinerator for solid combustible waste is one of the processes installed in this facility. The incinerator has been operating since 1982. It has consistently reduced combustible wastes to an inert ash product, with an average volume reduction factor of about 150:1. The incinerator ash is stored in 200 L drums awaiting solidification in bitumen. The incinerator and a 50-ton hydraulic baler have provided treatment for a combined volume of about 1300 m 3 /a of solid low-level radioactive waste. This paper presents a review of the performance of the incinerator during its six years of operation. In addition to presenting operational experience, an assessment of the starved-air incineration technique will also be discussed

Assessment of the National Research Universal Reactor Proposed New Stack Sampling Probe Location for Compliance with ANSI/HPS N13.1-1999

Energy Technology Data Exchange (ETDEWEB)

Glissmeyer, John A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Antonio, Ernest J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Flaherty, Julia E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2016-02-29

This document reports on a series of tests conducted to assess the proposed air sampling location for the National Research Universal reactor (NRU) complex exhaust stack, located in Chalk River, Ontario, Canada, with respect to the applicable criteria regarding the placement of an air sampling probe. Due to the age of the equipment in the existing monitoring system, and the increasing difficulty in acquiring replacement parts to maintain this equipment, a more up-to-date system is planned to replace the current effluent monitoring system, and a new monitoring location has been proposed. The new sampling probe should be located within the exhaust stack according to the criteria established by the American National Standards Institute/Health Physics Society (ANSI/HPS) N13.1-1999, Sampling and Monitoring Releases of Airborne Radioactive Substances from the Stack and Ducts of Nuclear Facilities. These criteria address the capability of the sampling probe to extract a sample that represents the effluent stream. The internal Pacific Northwest National Laboratory (PNNL) project for this task was 65167, Atomic Energy Canada Ltd. Chalk River Effluent Duct Flow Qualification. The testing described in this document was guided by the Test Plan: Testing of the NRU Stack Air Sampling Position (TP-STMON-032).

Metagenomic covariation along densely sampled environmental gradients in the Red Sea

Science.gov (United States)

Thompson, Luke R; Williams, Gareth J; Haroon, Mohamed F; Shibl, Ahmed; Larsen, Peter; Shorenstein, Joshua; Knight, Rob; Stingl, Ulrich

2017-01-01

Oceanic microbial diversity covaries with physicochemical parameters. Temperature, for example, explains approximately half of global variation in surface taxonomic abundance. It is unknown, however, whether covariation patterns hold over narrower parameter gradients and spatial scales, and extending to mesopelagic depths. We collected and sequenced 45 epipelagic and mesopelagic microbial metagenomes on a meridional transect through the eastern Red Sea. We asked which environmental parameters explain the most variation in relative abundances of taxonomic groups, gene ortholog groups, and pathways—at a spatial scale of water mass with different physicochemical properties. Temperature explained the most variation in each metric, followed by nitrate, chlorophyll, phosphate, and salinity. That nitrate explained more variation than phosphate suggested nitrogen limitation, consistent with low surface N:P ratios. Covariation of gene ortholog groups with environmental parameters revealed patterns of functional adaptation to the challenging Red Sea environment: high irradiance, temperature, salinity, and low nutrients. Nutrient-acquisition gene ortholog groups were anti-correlated with concentrations of their respective nutrient species, recapturing trends previously observed across much larger distances and environmental gradients. This dataset of metagenomic covariation along densely sampled environmental gradients includes online data exploration supplements, serving as a community resource for marine microbial ecology. PMID:27420030

Potentiometric Surface of the Upper Patapsco Aquifer in Southern Maryland, September 2007

Science.gov (United States)

Curtin, Stephen E.; Andreasen, David C.; Staley, Andrew W.

2009-01-01

This report presents a map showing the potentiometric surface of the upper Patapsco aquifer in the Patapsco Formation of Early Cretaceous age in Southern Maryland during September 2007. The map is based on water-level measurements in 50 wells. The highest measured water level was 120 feet above sea level near the northern boundary and outcrop area of the aquifer in northern Anne Arundel County. From this area, the potentiometric surface declined to the south toward a well field in the Annapolis-Arnold area, and from all directions toward four cones of depression. These cones are located in the Waldorf-La Plata area, Chalk Point-Prince Frederick area, Swan Point subdivision in southern Charles County, and the Lexington Park-St. Inigoes area. The lowest measured ground-water level was 44 feet below sea level at Arnold, 106 feet below sea level south of Waldorf, 54 feet below sea level at Swan Point, 59 feet below sea level at Chalk Point, and 58 feet below sea level at Lexington Park.

Natural radioactivity in environmental samples from an island of volcanic origin (Milos, Aegean Sea)

International Nuclear Information System (INIS)

Florou, H.; Kritidis, P.

1991-01-01

Enhanced concentrations of natural radionuclides occur in volcanic islands such as Milos in the Aegean Sea. The natural gamma radiation status of the entire environment in Milos were studied using gamma radiometry. Gamma spectrometry was used to analyse ore samples, sediments and marine biota. While non-living materials showed enhanced levels of natural radioactivity, most of the marine organisms examined did not seem to reflect this radiological status. (UK)

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian Sea from 1993-07-30 to 1993-08-15 (NODC Accession 0113559)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113559 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian...

SeaWiFS technical report series. Volume 4: An analysis of GAC sampling algorithms. A case study

Science.gov (United States)

Yeh, Eueng-Nan (Editor); Hooker, Stanford B. (Editor); Hooker, Stanford B. (Editor); Mccain, Charles R. (Editor); Fu, Gary (Editor)

1992-01-01

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) instrument will sample at approximately a 1 km resolution at nadir which will be broadcast for reception by realtime ground stations. However, the global data set will be comprised of coarser four kilometer data which will be recorded and broadcast to the SeaWiFS Project for processing. Several algorithms for degrading the one kilometer data to four kilometer data are examined using imagery from the Coastal Zone Color Scanner (CZCS) in an effort to determine which algorithm would best preserve the statistical characteristics of the derived products generated from the one kilometer data. Of the algorithms tested, subsampling based on a fixed pixel within a 4 x 4 pixel array is judged to yield the most consistent results when compared to the one kilometer data products.

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from METEOR in the Adriatic Sea, Aegean Sea and others from 2011-04-05 to 2011-04-28 (NODC Accession 0108079)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108079 includes discrete sample and profile data collected from METEOR in the Adriatic Sea, Aegean Sea, Alboran Sea, Ionian Sea, Mediterranean Sea,...

Radiochemical data obtained by α spectrometry on unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea

International Nuclear Information System (INIS)

Choukri, A.; Hakam, O.K.; Reyss, J.L.; Plaziat, J.C.

2007-01-01

In this work, radiochemical results obtained by α spectrometry on 80 unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea are presented and discussed. The coral samples were collected in Egypt from the emerged 5e coral reef terraces over 500km from The Ras Gharib-Ras Shukeir depression (28 deg. 10 ' ) in the north to Wadi Lahami (north of Ras Banas, 24 deg. 10 ' ) in the south. The statistical description of radiochemical results (concentrations of U and Th radioisotopes, 234 U/ 238 U activity ratios and ages) obtained on a great number of coral samples showed that it is possible to establish methodological criterions which could be used to validate the measured ages before confronting them to the geological context of sampling sites. The obtained results confirm that the unrecrystallized corals ( 232 Th 238 U varies between 2.2 and 4.9ppm around an average of 3.18+/-0.65ppm. 234 U/ 238 U activity ratios are between 1.08 and 1.28 with an averaged value of 1.164+/-0.016 which exceeds that of present day sea water but which is in agreement with the ratio of 1.16 measured by a precise mass spectrometry in many Pleistocene coral samples. Except three samples dated at least 100ka, the radiochemical age of 5e coral samples vary between 108 and 131ka with an average value of 122.2ka and a standard deviation of 4.3ka. Except for samples from the Zeit area, the reef terrace is between 2 and 6m above the present sea level. This position is similar to the highest sea level from the last interglacial according to the glacio-isostatic rebound calculated for stable regions. This work proves that the large tectonic motions which affected the studied area after the Oligocene ceased after at least the last interglacial period

Radiochemical data obtained by {alpha} spectrometry on unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea

Energy Technology Data Exchange (ETDEWEB)

Choukri, A. [Laboratoire de Physique de la Matiere et Rayonnement, Equipe de Physique et Techniques Nucleaires, UFR ' Faibles Radioactivites, Mathematiques physiques et environnement' Universite Ibn Tofail, Faculte des Sciences, Departement de Physique, P.B. 133, 14 000 Kenitra (Morocco)]. E-mail: choukrimajid@yahoo.com; Hakam, O.K. [Laboratoire de Physique de la Matiere et Rayonnement, Equipe de Physique et Techniques Nucleaires, UFR ' Faibles Radioactivites, Mathematiques physiques et environnement' Universite Ibn Tofail, Faculte des Sciences, Departement de Physique, P.B. 133, 14 000 Kenitra (Morocco); Reyss, J.L. [Laboratoire des Sciences de Climat et de l' Environnement, Domaine du CNRS, Avenue de la Terrasse 91 1958, Gif sur Yvette (France); Plaziat, J.C. [Universite de Paris-Sud, Departement des Sciences de la Terre, URA 723, Batiment 504, F-91405 Orsay, Cedex (France)

2007-02-15

In this work, radiochemical results obtained by {alpha} spectrometry on 80 unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea are presented and discussed. The coral samples were collected in Egypt from the emerged 5e coral reef terraces over 500km from The Ras Gharib-Ras Shukeir depression (28 deg. 10{sup '}) in the north to Wadi Lahami (north of Ras Banas, 24 deg. 10{sup '}) in the south. The statistical description of radiochemical results (concentrations of U and Th radioisotopes, {sup 234}U/{sup 238}U activity ratios and ages) obtained on a great number of coral samples showed that it is possible to establish methodological criterions which could be used to validate the measured ages before confronting them to the geological context of sampling sites. The obtained results confirm that the unrecrystallized corals ({sup 232}Th<3%) constitute the reliable means of determining the timing of Pleistocene sea-level fluctuations in the past. A few number of measured younger ages could be explain as a result of a rejuvenation due to latter addition of a ''younger'' uranium to the initial stock entered just after coral death. The obvious rejuvenation observed and confirmed is due to a recent cementation of aragonitic deposit on the fossil coral. {sup 238}U varies between 2.2 and 4.9ppm around an average of 3.18+/-0.65ppm. {sup 234}U/ {sup 238}U activity ratios are between 1.08 and 1.28 with an averaged value of 1.164+/-0.016 which exceeds that of present day sea water but which is in agreement with the ratio of 1.16 measured by a precise mass spectrometry in many Pleistocene coral samples. Except three samples dated at least 100ka, the radiochemical age of 5e coral samples vary between 108 and 131ka with an average value of 122.2ka and a standard deviation of 4.3ka. Except for samples from the Zeit area, the reef terrace is between 2 and 6m above the present sea level. This position is similar to

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from METEOR in the Aegean Sea, Mediterranean Sea and others from 2001-10-18 to 2001-11-11 (NODC Accession 0084620)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0084620 includes discrete sample and profile data collected from METEOR in the Aegean Sea, Mediterranean Sea, Mediterranean Sea - Eastern Basin,...

PH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from PROFESSOR SIEDLECKI in the Adriatic Sea, Aegean Sea and others from 1988-11-17 to 1988-11-26 (NCEI Accession 0144306)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144306 includes discrete sample and profile data collected from PROFESSOR SIEDLECKI in the Adriatic Sea, Aegean Sea, Mediterranean Sea, Mediterranean...

Development of an Integrated Waste Plan for Chalk River Laboratories - 13376

International Nuclear Information System (INIS)

Jones, L.

2013-01-01

To further its Strategic Planning, the Atomic Energy of Canada Limited (AECL) required an effective approach to developing a fully integrated waste plan for its Chalk River Laboratories (CRL) site. Production of the first Integrated Waste Plan (IWP) for Chalk River was a substantial task involving representatives from each of the major internal stakeholders. Since then, a second revision has been produced and a third is underway. The IWP remains an Interim IWP until all gaps have been resolved and all pathways are at an acceptable level of detail. Full completion will involve a number of iterations, typically annually for up to six years. The end result of completing this process is a comprehensive document and supporting information that includes: - An Integrated Waste Plan document summarizing the entire waste management picture in one place; - Details of all the wastes required to be managed, including volume and timings by waste stream; - Detailed waste stream pathway maps for the whole life-cycle for each waste stream to be managed from pre-generation planning through to final disposition; and - Critical decision points, i.e. decisions that need to be made and timings by when they need to be made. A waste inventory has been constructed that serves as the master reference inventory of all waste that has been or is committed to be managed at CRL. In the past, only the waste that is in storage has been effectively captured, and future predictions of wastes requiring to be managed were not available in one place. The IWP has also provided a detailed baseline plan at the current level of refinement. Waste flow maps for all identified waste streams, for the full waste life cycle complete to disposition have been constructed. The maps identify areas requiring further development, and show the complexities and inter-relationships between waste streams. Knowledge of these inter-dependencies is necessary in order to perform effective options studies for enabling

Change in Biot's effective stress coefficient of chalk during pore collapse

DEFF Research Database (Denmark)

Alam, M. Monzurul; Fabricius, Ida Lykke

2013-01-01

the grains could also change during elastic deformation of the grains in a rock mechanics test. Diagenetic change in grain contact cement of chalk can be compared with stress-induced change in the laboratory. The change in porosity is studied with reference to the change in effective stress on grain contacts...... and porosity reduces at a slower rate. We noticed that presence of non carbonates and hydrocarbon could increase σ'm. During rock mechanics test in the lab, with increased applied stress, σ'm increases, Biot's effective stress coefficient shows a decreasing trend, while a minor porosity reduction was observed......Biot's effective stress coefficient (α) is a measure of how well grains in the rocks are connected with each other. The amount of contact cements between the grains determines the stiffness of rocks. Change in grain contact occurs during natural diagenesis of sedimentary rock. Contact between...

Contaminated groundwater characterization at the Chalk River Laboratories, Ontario, Canada

Energy Technology Data Exchange (ETDEWEB)

Schilk, A.J.; Robertson, D.E.; Thomas, C.W.; Lepel, E.A. [Pacific Northwest National Lab., Richland, WA (United States); Champ, D.R.; Killey, R.W.D.; Young, J.L.; Cooper, E.L. [Chalk River Labs., Chalk River, Ontario (Canada)

1993-03-01

The licensing requirements for the disposal of low-level radioactive waste (10 CFR 61) specify the performance objectives and technical requisites for federal and commercial land disposal facilities, the ultimate goal of which is to contain the buried wastes so that the general population is adequately protected from harmful exposure to any released radioactive materials. A major concern in the operation of existing and projected waste disposal sites is subterranean radionuclide transport by saturated or unsaturated flow, which could lead to the contamination of groundwater systems as well as uptake by the surrounding biosphere, thereby directly exposing the general public to such materials. Radionuclide transport in groundwater has been observed at numerous commercial and federal waste disposal sites [including several locations within the waste management area of Chalk River Laboratories (CRL)], yet the physico-chemical processes that lead to such migration are still not completely understood. In an attempt to assist in the characterization of these processes, an intensive study was initiated at CRL to identify and quantify the mobile radionuclide species originating from three separate disposal sites: (a) the Chemical Pit, which has received aqueous wastes containing various radioisotopes, acids, alkalis, complexing agents and salts since 1956, (b) the Reactor Pit, which has received low-level aqueous wastes from a reactor rod storage bay since 1956, and (c) the Waste Management Area C, a thirty-year-old series of trenches that contains contaminated solid wastes from CRL and various regional medical facilities. Water samples were drawn downgradient from each of the above sites and passed through a series of filters and ion-exchange resins to retain any particulate and dissolved or colloidal radionuclide species, which were subsequently identified and quantified via radiochemical separations and gamma spectroscopy. These groundwaters were also analyzed for anions

The distribution and diversity of sea cucumbers in the coral reefs of the South China Sea, Sulu Sea and Sulawesi Sea

Science.gov (United States)

Woo, Sau Pinn; Yasin, Zulfigar; Ismail, Siti Hasmah; Tan, Shau Hwai

2013-11-01

A study on the distribution and diversity of sea cucumbers in the coral reefs of the South China Sea, Sulu Sea and Sulawesi Sea was carried out in July 2009. The survey was done using wandering transect underwater with SCUBA. Twelve species of sea cucumber were found from four different families and nine genera. The most dominant family was Holothuriidae (five species), followed by Stichopodidae (three species), Synaptidae (three species) and Cucumariidae with only one species. The most dominant species found around the island was Pearsonothuria graffei, which can be found abundantly on substrate of dead corals in a wide range of depth (6-15 m). The Sulawesi Sea showed a higher diversity of sea cucumber with seven different species compared to the South China Sea with only six different species and Sulu Sea with only two species. Ordination by multidimensional scaling of Bray-Curtis similarities clustered the sampling locations to three main clusters with two outgroups. Previous studies done indicated a higher diversity of sea cucumber as compared to this study. This can be indication that the population and diversity of sea cucumbers in the reef is under threat.

Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Final report, March 1996--September 1998

Energy Technology Data Exchange (ETDEWEB)

Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Carroll, R.E.; Groshong, R.H.; Jin, G.

1998-12-01

This project was designed to analyze the structure of Mesozoic and Tertiary strata in Gilbertown Field and adjacent areas to suggest ways in which oil recovery can be improved. The Eutaw Formation comprises 7 major flow units and is dominated by low-resistivity, low-contrast play that is difficult to characterize quantitatively. Selma chalk produces strictly from fault-related fractures that were mineralized as warm fluid migrated from deep sources. Resistivity, dipmeter, and fracture identification logs corroborate that deformation is concentrated in the hanging-wall drag zones. New area balancing techniques were developed to characterize growth strata and confirm that strain is concentrated in hanging-wall drag zones. Curvature analysis indicates that the faults contain numerous fault bends that influence fracture distribution. Eutaw oil is produced strictly from footwall uplifts, whereas Selma oil is produced from fault-related fractures. Clay smear and mineralization may be significant trapping mechanisms in the Eutaw Formation. The critical seal for Selma reservoirs, by contrast, is where Tertiary clay in the hanging wall is juxtaposed with poorly fractured Selma chalk in the footwall. Gilbertown Field can be revitalized by infill drilling and recompletion of existing wells. Directional drilling may be a viable technique for recovering untapped oil from Selma chalk. Revitalization is now underway, and the first new production wells since 1985 are being drilled in the western part of the field.

Magnetic field related mechanical tolerances for the proposed Chalk River superconducting heavy-ion cyclotron

International Nuclear Information System (INIS)

Heighway, E.A.; Chaplin, K.R.

1977-11-01

A four sector azimuthally varying field cyclotron with superconducting main coils has been proposed as a heavy-ion post-accelerator for the Chalk River MP Tandem van de Graaff. The radial profile of the average axial field will be variable using movable steel trim rods. The field errors due to coil, trim rod and flutter pole imperfections are calculated. Those considered are errors in the axial field, first and second azimuthal harmonic axial fields, transverse field and first azimuthal harmonic transverse field. Such fields induce phase slip, axial or radial coherent oscillations and can result in axial or radial beam instability. The allowed imperfections (tolerances) required to retain stability and maintain acceptably small coherent oscillation amplitudes are calculated. (author)

Study on the application of electrothermal atomization atomic absorption spectrometry for the determination of metallic Cu, Pb, Zn, Cd traces in sea water samples

International Nuclear Information System (INIS)

Nguyen Thi Kim Dung; Doan Thanh Son; Tran Thi Ngoc Diep

2004-01-01

The trace amount of some heavy metallic elements (Cu, Zn, Pb, Cd) in sea water samples were determined directly (without separation) and quantitatively by using Electro-Thermal Atomization Atomic Absorption Spectrometry (ETA-AAS). The effect of mainly major constituents such as Na, Mg, Ca, K, and the mutual effect of the trace elements, which were present in the matrix on the absorption intensity of each analyzed element was studied. The adding of a certain chemical modification for each trace element was also investigated in order to eliminate the overall effect of the background during the pyrolysis and atomization. The sea water sample after fitrating through a membrane with 0.45 μm-hole size was injected in to the graphite tube via an autosampler (MPE50). The absorption intensity of each element was then measured on the VARIO-6 under the optimum parameters for spectrometer such as: maximum wavelength, current of hollow cathode lamp, and that for graphite furnace such as dry temperature, pyrolysis temperature, atomization temperature, ect. The analytical procedures were set-up and applied for the determination of these above mentioned elements in the synthesized sea water sample and in the real sea water samples with high precision and accuracy. (author)

Equilibrium passive sampling as a tool to study polycyclic aromatic hydrocarbons in Baltic Sea sediment pore-water systems

DEFF Research Database (Denmark)

Lang, Susann-Cathrin; Hursthouse, Andrew; Mayer, Philipp

2015-01-01

Solid Phase Microextraction (SPME) was applied to provide the first large scale dataset of freely dissolved concentrations for 9 polycyclic aromatic hydrocarbons (PAHs) in Baltic Sea sediment cores. Polydimethylsiloxane (PDMS) coated glass fibers were used for ex-situ equilibrium sampling followed...

Integrating geophysical and hydrochemical borehole-log measurements to characterize the Chalk aquifer, Berkshire, United Kingdom

Science.gov (United States)

Schürch, Marc; Buckley, David

2002-09-01

Geophysical and hydrochemical borehole-logging techniques were integrated to characterize hydraulic and hydrogeochemical properties of the Chalk aquifer at boreholes in Berkshire, UK. The down-hole measurements were made to locate fissures in the chalk, their spatial extent between boreholes, and to determine the groundwater chemical quality of the water-bearing layers. The geophysical borehole logging methods used were caliper, focused resistivity, induction resistivity, gamma ray, fluid temperature, fluid electrical conductivity, impeller and heat-pulse flowmeter, together with borehole wall optical-imaging. A multiparameter data transmitter was used to measure groundwater temperature, electrical conductivity, dissolved oxygen, pH, and redox potential of the borehole fluid down-hole. High permeability developed at the Chalk Rock by groundwater circulation provides the major flow horizon at the Banterwick Barn study site and represents a conduit system that serves as an effective local hydraulic connection between the boreholes. The Chalk Rock includes several lithified solution-ridden layers, hardgrounds, which imply a gap in sedimentation possibly representing an unconformity. Lower groundwater temperature, high dissolved-oxygen content, and flowmeter evidence of preferential groundwater flow in the Chalk Rock indicated rapid groundwater circulation along this horizon. By repeating the logging at different times of the year under changing hydraulic conditions, other water-inflow horizons within the Chalk aquifer were recognized. Résumé. Des techniques géophysiques et hydrochimiques de diagraphies en forage ont été mises en oeuvre pour caractériser les propriétés hydrauliques et hydrogéochimiques de l'aquifère de la craie dans des forages du Berkshire (Grande-Bretagne). Les mesures en descente ont été faites pour localiser les fissures dans la craie et leur développement spatial entre forages, et pour déterminer la qualité de l'eau souterraine des

Other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from unknown platforms in the North Atlantic Ocean, North Sea and Norwegian Sea from 1874-01-01 to 2005-12-31 (NCEI Accession 0144342)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144342 includes discrete sample and profile data collected from unknown platforms in the North Atlantic Ocean, North Sea and Norwegian Sea from...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the FRANKLIN in the Coral Sea and Tasman Sea from 1993-06-24 to 1993-07-17 (NODC Accession 0116409)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116409 includes chemical, discrete sample, physical and profile data collected from FRANKLIN in the Coral Sea and Tasman Sea from 1993-06-24 to...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1993-11-06 to 1993-12-02 (NODC Accession 0115679)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115679 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1992-11-05 to 1992-12-01 (NODC Accession 0115403)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115403 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1991-11-05 to 1991-11-27 (NODC Accession 0115685)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115685 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1996-10-30 to 1996-11-10 (NODC Accession 0115680)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115680 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Two-Year Monitoring of Water Samples from Dam of Iskar and the Black Sea, Bulgaria, by Molecular Analysis: Focus on Mycobacterium spp.

Directory of Open Access Journals (Sweden)

Stefan Panaiotov

2015-06-01

Full Text Available The coast of the Bulgarian Black Sea is a popular summer holiday destination. The Dam of Iskar is the largest artificial dam in Bulgaria, with a capacity of 675 million m3. It is the main source of tap water for the capital Sofia and for irrigating the surrounding valley. There is a close relationship between the quality of aquatic ecosystems and human health as many infections are waterborne. Rapid molecular methods for the analysis of highly pathogenic bacteria have been developed for monitoring quality. Mycobacterial species can be isolated from waste, surface, recreational, ground and tap waters and human pathogenicity of nontuberculose mycobacteria (NTM is well recognized. The objective of our study was to perform molecular analysis for key-pathogens, with a focus on mycobacteria, in water samples collected from the Black Sea and the Dam of Iskar. In a two year period, 38 water samples were collected—24 from the Dam of Iskar and 14 from the Black Sea coastal zone. Fifty liter water samples were concentrated by ultrafiltration. Molecular analysis for 15 pathogens, including all species of genus Mycobacterium was performed. Our results showed presence of Vibrio spp. in the Black Sea. Rotavirus A was also identified in four samples from the Dam of Iskar. Toxigenic Escherichia coli was present in both locations, based on markers for stx1 and stx2 genes. No detectable amounts of Cryptosporidium were detected in either location using immunomagnetic separation and fluorescence microscopy. Furthermore, mass spectrometry analyses did not detect key cyanobacterial toxins. On the basis of the results obtained we can conclude that for the period 2012–2014 no Mycobacterium species were present in the water samples. During the study period no cases of waterborne infections were reported.

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from OCEAN RESEARCHER I in the Philippine Sea and South China Sea from 1991-07-08 to 1991-07-12 (NCEI Accession 0143948)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143948 includes discrete sample and profile data collected from OCEAN RESEARCHER I in the Philippine Sea and South China Sea (Nan Hai) from...

US team measurements during the June 1987 experimental HT release at the Chalk River Nuclear Laboratories, Ontario, Canada

International Nuclear Information System (INIS)

Jalbert, R.A.; Murphy, C.E.

1988-01-01

In June 1987, an experiment was performed at the Chalk River Nuclear Laboratories in Ontario, Canada, to study the oxidation of HT in the environment. The experiment involved a 30-minute release of 100 Ci of HT to the atmosphere at an elevation of one meter. The HTOHT ratios were shown to slowly increase downwind (/approximately/4 /times/ 10/sup /minus/5/ at 50 meters to almost 10/sup /minus/3 at 400 meters) as conversion of HT takes place. For several days after the release, HTO concentrations in the atmosphere remained elevated. Freeze-dried water from vegetation samples was found to be very low in HTO immediately after the release suggesting a very low direct uptake of HTO in air by vegetation. The tritiated water concentration increased during the first day, peaking during the second day (about 400 to 600 pCiml of water at 50 meters from the source) and decreasing by the end of the second day. The organically bound tritium continued to accumulate during the period following exposure (about 10 pCigm dry weight at 50 meters after two days). 4 refs., 6 figs., 2 tabs

Dissolved inorganic carbon, alkalinity, temperature, salinity and OXYGEN - APPARENT UTILIZATION (AOU) collected from discrete sample and profile observations using CTD, bottle and other instruments from UNKNOWN PLATFORMS in the Adriatic Sea, Aegean Sea and others from 1874-10-11 to 2000-04-26 (NODC Accession 0117350)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0117350 includes chemical, discrete sample, physical and profile data collected from UNKNOWN PLATFORMS in the Adriatic Sea, Aegean Sea, Alboran Sea,...

Paleoenvironments of the Jurassic and Cretaceous Oceans: Selected Highlights

Science.gov (United States)

Ogg, J. G.

2007-12-01

There are many themes contributing to the sedimentation history of the Mesozoic oceans. This overview briefly examines the roles of the carbonate compensation depth (CCD) and the associated levels of atmospheric carbon dioxide, of the evolution of marine calcareous microplankton, of major transgressive and regressive trends, and of super-plume eruptions. Initiation of Atlantic seafloor spreading in the Middle Jurassic coincided with an elevated carbonate compensation depth (CCD) in the Pacific-Tethys mega-ocean. Organic-rich sediments that would become the oil wealth of regions from Saudi Arabia to the North Sea were deposited during a continued rise in CCD during the Oxfordian-early Kimmeridgian, which suggests a possible increase in carbon dioxide release by oceanic volcanic activity. Deep-sea deposits in near-equatorial settings are dominated by siliceous shales or cherts, which reflect the productivity of siliceous microfossils in the tropical surface waters. The end-Jurassic explosion in productivity by calcareous microplankton contributed to the lowering of the CCD and onset of the chalk ("creta") deposits that characterize the Tithonian and lower Cretaceous in all ocean basins. During the mid-Cretaceous, the eruption of enormous Pacific igneous provinces (Ontong Java Plateau and coeval edifices) increased carbon dioxide levels. The resulting rise in CCD terminated chalk deposition in the deep sea. The excess carbon was progressively removed in widespread black-shale deposits in the Atlantic basins and other regions - another major episode of oil source rock. A major long-term transgression during middle and late Cretaceous was accompanied by extensive chalk deposition on continental shelves and seaways while the oceanic CCD remained elevated. Pacific guyots document major oscillations (sequences) of global sea level superimposed on this broad highstand. The Cretaceous closed with a progressive sea-level regression and lowering of the CCD that again enabled

Changes in Specific Surface as observed by NMR, caused by saturation of Chalk with porewater bearing divalent Ions

DEFF Research Database (Denmark)

Katika, Konstantina; Addassi, Mouadh; Alam, Mohammad Monzurul

2014-01-01

Nuclear Magnetic Resonance (NMR) spectrometry has proved to be a good technique for determining the petrophysical properties of reservoir rocks; such as porosity and pore size distribution. We investigated how pore water rich in divalent ions affect the NMR signal from chalk with two different de......-to-volume ratio of the pore space. The results of this work could benefit the ongoing study on the optimization of the water composition for Enhanced Oil Recovery (EOR) methods and shed light on how it can affect the mechanical and physical properties of the rock....

Occurrence of microplastics in the beach sand of the Chinese inner sea: the Bohai Sea.

Science.gov (United States)

Yu, Xubiao; Peng, Jinping; Wang, Jundong; Wang, Kan; Bao, Shaowu

2016-07-01

The occurrence of microplastics in the beach sand of the Bohai Sea was investigated for the first time. The Bohai Sea is the largest Chinese inner sea and its coastal region is one of the most densely urbanized and industrialized zones of China. Samples from three costal sites (i.e., Bijianshan, Xingcheng and Dongdaihe) were collected, quantified and identified for microplastic analysis. Effects of sample depth and tourism activity were investigated. Surface samples (2 cm) contained higher microplastic concentrations than deep samples (20 cm). Samples from the bathing beach exhibited higher microplastic concentrations than the non-bathing beach, suggesting the direct contribution of microplastics from tourism activity. Of eight types of microplastics that were found, PEVA (polyethylene vinyl acetate), LDPE (light density polyethylene) and PS (polystyrene) were the largest in abundances. Moreover, the non-plastic items from samples were analyzed and results revealed that the majority abundance of the observed non-plastics were viscose cellulose fibers. Further studies are required to evaluate the environmental hazards of microplastics, especially as they may "act as a contaminant transporter" to the Bohai Sea ecosystem. Copyright © 2016 Elsevier Ltd. All rights reserved.

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the USCGC POLAR SEA in the North Greenland Sea from 1992-07-15 to 1992-08-14 (NODC Accession 0115687)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115687 includes biological, chemical, discrete sample, physical and profile data collected from USCGC POLAR SEA in the North Greenland Sea from...

Ultralow-level measurement of organically-bound tritium in bioassay samples

International Nuclear Information System (INIS)

Kotzer, T.; Trivedi, A.; Waito, G.; Workman, W.

1998-12-01

An intercomparison study of urine samples having high levels (5 Bq·L -1 ) of organically-bound tritium (OBT) was conducted, in conjunction with the oxygen combustion-liquid scintillation counting (LSC) method, to evaluate the suitability and sensitivity of the 3 He-ingrowth mass spectrometry (MS) technique for OBT in bioassay samples. The study established that 3 He ingrowth-MS has the required sensitivity to measure ultralow levels of OBT-in-urine (∼0.1 Bq·L -1 ). Cumulative 24 h urine samples from a few members of the general population, living in the vicinity of the heavy-water research reactor facility at Chalk River Laboratories (CRL) at Chalk River, were collected and analyzed for tritiated water (HTO) and OBT. The participants were from Ottawa (200 km east), Deep River (10 km west) and an occasionally occupationally HTO-exposed worker at CRL. HTO-in-urine values were 6.5 Bq·L -1 for the Ottawa resident, 15.8 Bq·L -1 for the Deep River resident, and 1260 Bq·L -1 for the exposed worker. OBT-in-urine levels from these same individuals were 0.06 Bq·L -1 (Ottawa), 0.29 Bq·L -1 (Deep River), and 2.2 Bq·L -1 (exposed worker). With a model developed for calculating OBT dose fraction from the measured ratio of HTO to OBT in urine, we estimated that the dose arising from OBT in the body was about 26% of the total tritium dose for the Ottawa resident and 50% for the Deep River resident. The CRL individual had a 5% dose contribution from OBT, but had higher overall tritium dose due to frequent intakes of HTO. The study indicates that the bulk of the tritium dose to the population is the result of HTO intakes and not due to dietary intake of OBT. (author)

Dissolved inorganic carbon, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from SAGAR SAMPADA in the Arabian Sea, Indian Ocean and Laccadive Sea from 1994-03-01 to 1995-05-03 (NODC Accession 0117387)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0117387 includes chemical, discrete sample, physical and profile data collected from SAGAR SAMPADA in the Arabian Sea, Indian Ocean and Laccadive Sea...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the YMER in the Arctic Ocean, Barents Sea and North Greenland Sea from 1980-08-11 to 1980-09-19 (NODC Accession 0113607)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113607 includes chemical, discrete sample, physical and profile data collected from YMER in the Arctic Ocean, Barents Sea and North Greenland Sea...

Low incidence of clonality in cold water corals revealed through the novel use of a standardized protocol adapted to deep sea sampling

Science.gov (United States)

Becheler, Ronan; Cassone, Anne-Laure; Noël, Philippe; Mouchel, Olivier; Morrison, Cheryl L.; Arnaud-Haond, Sophie

2017-11-01

Sampling in the deep sea is a technical challenge, which has hindered the acquisition of robust datasets that are necessary to determine the fine-grained biological patterns and processes that may shape genetic diversity. Estimates of the extent of clonality in deep-sea species, despite the importance of clonality in shaping the local dynamics and evolutionary trajectories, have been largely obscured by such limitations. Cold-water coral reefs along European margins are formed mainly by two reef-building species, Lophelia pertusa and Madrepora oculata. Here we present a fine-grained analysis of the genotypic and genetic composition of reefs occurring in the Bay of Biscay, based on an innovative deep-sea sampling protocol. This strategy was designed to be standardized, random, and allowed the georeferencing of all sampled colonies. Clonal lineages discriminated through their Multi-Locus Genotypes (MLG) at 6-7 microsatellite markers could thus be mapped to assess the level of clonality and the spatial spread of clonal lineages. High values of clonal richness were observed for both species across all sites suggesting a limited occurrence of clonality, which likely originated through fragmentation. Additionally, spatial autocorrelation analysis underlined the possible occurrence of fine-grained genetic structure in several populations of both L. pertusa and M. oculata. The two cold-water coral species examined had contrasting patterns of connectivity among canyons, with among-canyon genetic structuring detected in M. oculata, whereas L. pertusa was panmictic at the canyon scale. This study exemplifies that a standardized, random and georeferenced sampling strategy, while challenging, can be applied in the deep sea, and associated benefits outlined here include improved estimates of fine grained patterns of clonality and dispersal that are comparable across sites and among species.

U.S. team measurements during the June 1987 experimental HT release at the Chalk River Nuclear Laboratories, Ontario, Canada

International Nuclear Information System (INIS)

Jalbert, R.A.; Murphy, C.E.

1988-01-01

In June 1987, an experiment was performed at the Chalk River Nuclear Laboratories in Ontario, Canada, to study the oxidation of HT in the environment. The experiment involved a 30-minute release of 3.54 TBq (95.7 Ci) of HT to the atmosphere at an elevation of one meter. The HTO/HT ratios were shown to slowly increase downwind (-- 4 x 10/sup -5/ at 50 meters to almost 10/sup -3/ at 400 meters) as conversion of HT takes place. For several days after the release, HTO concentrations in the atmosphere remained elevated. Freeze-dried water from vegetation samples was found to be very low in HTO immediately after the release suggesting a very low direct uptake of HTO in air by vegetation. The free-HTO concentration in vegetation increased during the first day, peaking during the second day (about 1.5 - 3.0 x 10/sup 4/ Bq/L at 50 meters from the source) and decreasing by the end of the second day. The organically bound tritium continued to accumulate during the period following exposure (about 400 Bq/kg dry weight at 50 meters after two days)

The Barbados Sea Level Record

Science.gov (United States)

Fairbanks, R. G.; Mortlock, R. A.; Abdul, N. A.; Wright, J. D.; Cao, L.; Mey, J. L.

2013-12-01

Additional offshore drill cores, nearly 100 new radiometric dates, and more than 1000 kilometers of Multibeam mapping greatly enhance the Barbados Sea Level record. Extensive Multibeam mapping around the entire island covers approximately 2650 km2 of the sea bottom and now integrates the offshore reef topography and Barbados Sea Level Record with the unparalleled onshore core collection, digital elevation maps, and Pleistocene sea level record spanning the past one million years. The reef crest coral, Acropora palmata, remains the stalwart indicator of sea level for many reasons that are validated by our redundant sea level records and redundant dating via Th/U and Pa/U analyses. Microanalysis and densitometry studies better explain why Acropora palmata is so well preserved in the Pleistocene reef records and therefore why it is the species of choice for sea level reconstructions and radiometric dating. New drill cores into reefs that formed during Marine Isotope Stage 3 lead us to a model of diagenesis that allows us to better prospect for unaltered coral samples in older reefs that may be suitable for Th/U dating. Equally important, our diagenesis model reinforces our rigorous sample quality criteria in a more quantitative manner. The Barbados Sea Level record has a sampling resolution of better than 100 years throughout much of the last deglaciation showing unprecedented detail in redundant drill cores. The Melt Water Pulses (MWP1A and MWP1B) are well resolved and the intervening interval that includes the Younger Dryas reveals sea level changes in new detail that are consistent with the terrestrial records of ice margins (see Abdul et al., this section). More than 100 paired Th/U and radiocarbon ages place the Barbados Sea Level Record unambiguously on the radiocarbon time scale for direct comparisons with the terrestrial records of ice margin changes.

Causes of death among long-term employees of Chalk River Laboratories, 1966-1989

International Nuclear Information System (INIS)

Werner, M.M.; Myers, D.K.

1990-11-01

Data on mortality among long-term employees of Chalk River Laboratories to 1989 December 31 are reported. The 1988 Hare report, entitled The Safety of Ontario's Nuclear Power Reactors, noted that there had been a steady rise in standardized mortality ratios (SMR) for cancer among these employees in the last three successive five-year periods from 1971-75 to 1981-85. None of the SMRs was significantly different from unity; however, the apparent trend could be indicative of the development of latent cancers. The present report was prepared to see if that increasing trend in cancer SMRs continued. In the years 1986-89, the SMR for cancer among long-term male employees was exceptionally low. The wide fluctuations seen in our data over time are likely anomalies arising from the small size of the study group rather than problems arising from radiation exposures on site

Chemometrics methods for the investigation of methylmercury and total mercury contamination in mollusks samples collected from coastal sites along the Chinese Bohai Sea

International Nuclear Information System (INIS)

Wang Yawei; Liang Lina; Shi Jianbo; Jiang Guibin

2005-01-01

The development and application of chemometrics methods, principal component analysis (PCA), cluster analysis and correlation analysis for the determination of methylmercury (MeHg) and total mercury (HgT) in gastropod and bivalve species collected from eight coastal sites along the Chinese Bohai Sea are described. HgT is directly determined by atomic fluorescence spectrometry (AFS), while MeHg is measured by a laboratory established high performance liquid chromatography-atomic fluorescence spectrometry system (HPLC-AFS). One-way ANOVA and cluster analysis indicated that the bioaccumulation of Rap to accumulate Hg was significantly (P<0.05) different from other mollusks. Correlation analysis shows that there is linear relationship between MeHg and HgT in mollusks samples collected from coastal sites along the Chinese Bohai Sea, while in mollusks samples collected from Hongqiao market in Beijing City, there is not any linear relationship. - Rapana venosa might be used as a potential biomonitor for Hg pollution in the Bohai Sea, China

U–Pb, Rb–Sr, and U-series isotope geochemistry of rocks and fracture minerals from the Chalk River Laboratories site, Grenville Province, Ontario, Canada

International Nuclear Information System (INIS)

Neymark, L.A.; Peterman, Z.E.; Moscati, R.J.; Thivierge, R.H.

2013-01-01

Highlights: • AECL evaluates Chalk River Laboratories site as potential nuclear waste repository. • Isotope-geochemical data for rocks and fracture minerals at CRL site are reported. • Zircons from gneiss and granite yielded U–Pb ages of 1472 ± 14 and 1045 ± 6 Ma. • WR Rb–Sr and Pb–Pb systems do not show substantial large-scale isotopic mobility. • U-series and REE data do not support oxidizing conditions at depth in the past 1 Ma. - Abstract: As part of the Geologic Waste Management Facility feasibility study, Atomic Energy of Canada Ltd. (AECL) is evaluating the suitability of the Chalk River Laboratories (CRL) site in Ontario, situated in crystalline rock of the southwestern Grenville Province, for the possible development of an underground repository for low- and intermediate-level nuclear waste. This paper presents petrographic and trace element analyses, U–Pb zircon dating results, and Rb–Sr, U–Pb and U-series isotopic analyses of gneissic drill core samples from the deep CRG-series characterization boreholes at the CRL site. The main rock types intersected in the boreholes include hornblende–biotite (±pyroxene) gneisses of granitic to granodioritic composition, leucocratic granitic gneisses with sparse mafic minerals, and garnet-bearing gneisses with variable amounts of biotite and/or hornblende. The trace element data for whole-rock samples plot in the fields of within-plate, syn-collision, and volcanic arc-type granites in discrimination diagrams used for the tectonic interpretation of granitic rocks. Zircons separated from biotite gneiss and metagranite samples yielded SHRIMP-RG U–Pb ages of 1472 ± 14 (2σ) and 1045 ± 6 Ma, respectively, in very good agreement with widespread Early Mesoproterozoic plutonic ages and Ottawan orogeny ages in the Central Gneiss Belt. The Rb–Sr, U–Pb, and Pb–Pb whole-rock errorchron apparent ages of most of the CRL gneiss samples are consistent with zircon U–Pb age and do not indicate

Sample size matters in dietary gene expression studies—A case study in the gilthead sea bream (Sparus aurata L.

Directory of Open Access Journals (Sweden)

Fotini Kokou

2016-05-01

Full Text Available One of the main concerns in gene expression studies is the calculation of statistical significance which in most cases remains low due to limited sample size. Increasing biological replicates translates into more effective gains in power which, especially in nutritional experiments, is of great importance as individual variation of growth performance parameters and feed conversion is high. The present study investigates in the gilthead sea bream Sparus aurata, one of the most important Mediterranean aquaculture species. For 24 gilthead sea bream individuals (biological replicates the effects of gradual substitution of fish meal by plant ingredients (0% (control, 25%, 50% and 75% in the diets were studied by looking at expression levels of four immune-and stress-related genes in intestine, head kidney and liver. The present results showed that only the lowest substitution percentage is tolerated and that liver is the most sensitive tissue to detect gene expression variations in relation to fish meal substituted diets. Additionally the usage of three independent biological replicates were evaluated by calculating the averages of all possible triplets in order to assess the suitability of selected genes for stress indication as well as the impact of the experimental set up, thus in the present work the impact of FM substitution. Gene expression was altered depending of the selected biological triplicate. Only for two genes in liver (hsp70 and tgf significant differential expression was assured independently of the triplicates used. These results underlined the importance of choosing the adequate sample number especially when significant, but minor differences in gene expression levels are observed. Keywords: Sample size, Gene expression, Fish meal replacement, Immune response, Gilthead sea bream

Production of Calcareous Nannofossil Ooze for Sedimentological Experiments

DEFF Research Database (Denmark)

Buls, Toms; Anderskouv, Kresten; Fabricius, Ida Lykke

2015-01-01

by an abundance of sedimentary structures, such as drifts, moats, sediment waves, and channels documented in the Upper Cretaceous Chalk Group of NW Europe. Despite chalk being a major hydrocarbon reservoir rock of the North Sea, surprisingly little is known about the physical behavior of the pelagic carbonate......The notion of fine-grained pelagic carbonates as uniform, monotonous sequences of sediments settled in a quiescent environment has been challenged over the past few decades. Fine-grained pelagic carbonates can undergo substantial reworking after their first deposition, as illustrated...... sediment from which the chalk formed-calcareous nannofossil ooze. This poses a serious challenge to the understanding of the depositional system and the properties of facies distribution. Experimental tests, such as those performed in laboratory flumes, are necessary to provide empirical data...

Ross Sea Mollusca from the Latitudinal Gradient Program: R/V Italica 2004 Rauschert dredge samples

Directory of Open Access Journals (Sweden)

Claudio Ghiglione

2013-10-01

Full Text Available Information regarding the molluscs in this dataset is based on the Rauschert dredge samples collected during the Latitudinal Gradient Program (LGP on board the R/V “Italica” in the Ross Sea (Antarctica in the austral summer 2004. A total of 18 epibenthic dredge deployments/samplings have been performed at four different locations at depths ranging from 84 to 515m by using a Rauschert dredge with a mesh size of 500µm. In total 8,359 specimens have been collected belonging to a total of 161 species. Considering this dataset in terms of occurrences, it corresponds to 505 discrete distributional records (incidence data. Of these, in order of abundance, 5,965 specimens were Gastropoda (accounting for 113 species, 1,323 were Bivalvia (accounting for 36 species, 949 were Aplacophora (accounting for 7 species, 74 specimens were Scaphopoda (3 species, 38 were Monoplacophora (1 species and, finally, 10 specimens were Polyplacophora (1 species. This data set represents the first large-scale survey of benthic micro-molluscs for the area and provides important information about the distribution of several species, which have been seldom or never recorded before in the Ross Sea. All vouchers are permanently stored at the Italian National Antarctic Museum (MNA, Section of Genoa, enabling future comparison and crosschecking. This material is also currently under study, from a molecular point of view, by the barcoding project “BAMBi” (PNRA 2010/A1.10.

Occurrence of marine algal toxins in oyster and phytoplankton samples in Daya Bay, South China Sea.

Science.gov (United States)

Jiang, Tao; Liu, Lei; Li, Yang; Zhang, Jing; Tan, Zhijun; Wu, Haiyan; Jiang, Tianjiu; Lu, Songhui

2017-09-01

The occurrence and seasonal variations of marine algal toxins in phytoplankton and oyster samples in Daya Bay (DYB), South China Sea were investigated. Two Dinophysis species, namely, D. caudata and D. acuminata complex, were identified as Okadaic acid (OA)/pectenotoxin (PTX) related species. Liquid chromatography with tandem mass spectrometry (LC-MS/MS) analysis demonstrated that 2.04-14.47 pg PTX2 per cell was the predominant toxin in single-cell isolates of D. caudata. D. acuminata was not subjected to toxin analysis. The occurrence of OAs in phytoplankton concentrates of net-haul sample coincided with the presence of D. accuminata complex, suggesting that this species is most likely an OA producer in this sea area. OA, dinophysistoxins-1 (DTX1), PTX2, PTX2sa, gymnodimine (GYM), homoyessotoxin (homoYTX), and domoic acid (DA) demonstrated positive results in net haul samples. To our best knowledge, this paper is the first to report the detection of GYM, DA, and homoYTX in phytoplankton samples in Chinese coastal waters. Among the algal toxins, GYM demonstrated the highest frequency of positive detections in phytoplankton concentrates (13/17). Five compounds of algal toxins, including OA, DTX1, PTX2, PTX2sa, and GYM, were detected in oyster samples. DA and homoYTX were not detected in oysters despite of positive detections for both in the phytoplankton concentrates. However, neither the presence nor absence of DA in oysters can be determined because extraction conditions with 100% methanol used to isolate toxins from oysters (recommended by the EU-Harmonised Standard Operating Procedure, 2015) would likely be unsuitable for this water-soluble toxin. In addition, transformation of DA during the digestion process of oysters may also be involved in the negative detections of this toxin. GYM exhibited the highest frequency of positive results in oysters (14/17). OAs were only detected in the hydrolyzed oyster samples. The detection rates of PTX and PTX2sa in

The Irminger Sea and the Iceland Sea time series measurements of sea water carbon and nutrient chemistry 1983–2008

Directory of Open Access Journals (Sweden)

J. Olafsson

2010-03-01

Full Text Available This paper describes the ways and means of assembling and quality controling the Irminger Sea and Iceland Sea time-series biogeochemical data which are included in the CARINA data set. The Irminger Sea and the Iceland Sea are hydrographically different regions where measurements of sea water carbon and nutrient chemistry were started in 1983. The sampling is seasonal, four times a year. The carbon chemistry is studied with measurements of the partial pressure of carbon dioxide in seawater, pCO₂, and total dissolved inorganic carbon, TCO₂. The carbon chemistry data are for surface waters only until 1991 when water column sampling was initiated. Other measured parameters are salinity, dissolved oxygen and the inorganic nutrients nitrate, phosphate and silicate. Because of the CARINA criteria for secondary quality control, depth >1500 m, the IRM-TS could not be included in the routine QC and the IS-TS only in a limited way. However, with the information provided here, the quality of the data can be assessed, e.g. on the basis of the results obtained with the use of reference materials.

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1994-05-25 to 1994-06-06 (NODC Accession 0113954)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113954 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1998-03-08 to 1998-03-24 (NODC Accession 0113546)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113546 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1997-02-25 to 1997-03-24 (NODC Accession 0113545)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113545 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1994-02-24 to 1994-03-17 (NODC Accession 0113541)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113541 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1994-08-26 to 1994-09-10 (NODC Accession 0113542)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113542 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1995-04-27 to 1995-05-23 (NODC Accession 0113561)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113561 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1995-11-08 to 1995-11-26 (NODC Accession 0113562)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113562 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Chemical composition of aerosol, sea fog, and rainwater in the marine boundary layer of the northwestern North Pacific and its marginal seas

Science.gov (United States)

Sasakawa, Motoki; Uematsu, Mitsuo

2002-12-01

Samples of aerosol, sea fog, and rainwater were collected during a research cruise in the northwestern North Pacific, the Sea of Okhotsk, and the Sea of Japan in the summer of 1998. High concentrations of NO3-, nss-SO42- and NH4+ in aerosol over the Sea of Japan suggest that anthropogenic substances were transported to this region. Although the Sea of Okhotsk was covered with a clean marine air mass, the concentration of nss-SO42- was comparatively high in the aerosol samples. This nss-SO42- is probably of marine biogenic origin. The pH values of fogwater samples were measured to be fogwater collected over the Sea of Japan were higher than those in the other regions, suggesting that the sea fog scavenged anthropogenic substances. The concentration of nss-SO42- in fogwater over the Sea of Okhotsk was equivalent to that over the Sea of Japan, probably because nss-SO42- and SO2 of marine biogenic origin were scavenged by the sea fog over the Sea of Okhotsk. The pH values of rainwater samples ranged from 6.1 to 7.2 during the cruise, and acidification of the rain was not significant. The concentrations of nss-Ca2+ in the rainwater were higher than those of the fogwater. This suggests that the rain-scavenged continental CaCO3 may have existed above the lower marine boundary layer, where sea fog appeared. Comparisons of the composition of aerosol and fogwater indicated that coarse particles, such as sea salts predominantly act as condensation nuclei of sea fog droplets rather than fine particles such as (NH4)2SO4.

RADIOECOLOGICAL STUDIES IN MARINE ENVIRONMENT. A STUDY ON THE CONCENTRATION OF MIXED FISSION PRODUCTS IN GREEK SEA WATERS AND OF 137CS IN FISH AND SEA PLANTS

International Nuclear Information System (INIS)

DANALI-KOTSAKI, S.; FLOROU-GAZI, H.

1982-12-01

Full text: The concentrations of mixed fission products in sea water and of 137 Cs in fish and sea plants are different for samples collected from different sampling areas. This difference is more remarkable the year where the level of the world wide fall-out is higher, especially with regards to M. F. P. concentrations in sea water samples. Increases or decreases to M.F.P. concentrations in sea water samples result to increases or decreases of 137 Cs in fish and sea plants. (author)

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the Barents Sea and Norwegian Sea from 2001-08-22 to 2001-08-29 (NODC Accession 0113887)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113887 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the Barents Sea and Norwegian Sea from 2001-08-22...

Proposed approach for bedrock characterization at Chalk River Nuclear Laboratories for waste disposal

International Nuclear Information System (INIS)

Heystee, R.J.; Dixon, D.F.

1985-07-01

Low- and intermediate-level wastes (L AND ILW) are produced at the Chalk River Nuclear Laboratories (CRNL) by the operation of reactors for nuclear research and development and by the production of radioisotopes. CRNL also manages L and ILW produced by Canadian research laboratories, universities, hospitals and some industries. An option that is being considered for the disposal of some of these wastes is to emplace them in a shallow rock cavity in fractured crystalline bedrock on the CRNL property. To design such a disposal facility and to evalute its long-term performance, data must be obtained on the geologic and hydrogeologic characteristics of the site. Over the past several years, a variety of airborne, ground surface and borehole geological, geophysical and/or hydrogeological methods have been used to acquire data on some rock mass discontinuities at CRNL. The techniques which are apparently more useful for acquiring these data are described and a proposed approach to site characterization for a shallow rock cavity at CRNL is outlined

Metagenomic covariation along densely sampled environmental gradients in the Red Sea

KAUST Repository

Thompson, Luke R

2016-07-15

Oceanic microbial diversity covaries with physicochemical parameters. Temperature, for example, explains approximately half of global variation in surface taxonomic abundance. It is unknown, however, whether covariation patterns hold over narrower parameter gradients and spatial scales, and extending to mesopelagic depths. We collected and sequenced 45 epipelagic and mesopelagic microbial metagenomes on a meridional transect through the eastern Red Sea. We asked which environmental parameters explain the most variation in relative abundances of taxonomic groups, gene ortholog groups, and pathways—at a spatial scale of <2000 km, along narrow but well-defined latitudinal and depth-dependent gradients. We also asked how microbes are adapted to gradients and extremes in irradiance, temperature, salinity, and nutrients, examining the responses of individual gene ortholog groups to these parameters. Functional and taxonomic metrics were equally well explained (75–79%) by environmental parameters. However, only functional and not taxonomic covariation patterns were conserved when comparing with an intruding water mass with different physicochemical properties. Temperature explained the most variation in each metric, followed by nitrate, chlorophyll, phosphate, and salinity. That nitrate explained more variation than phosphate suggested nitrogen limitation, consistent with low surface N:P ratios. Covariation of gene ortholog groups with environmental parameters revealed patterns of functional adaptation to the challenging Red Sea environment: high irradiance, temperature, salinity, and low nutrients. Nutrient-acquisition gene ortholog groups were anti-correlated with concentrations of their respective nutrient species, recapturing trends previously observed across much larger distances and environmental gradients. This dataset of metagenomic covariation along densely sampled environmental gradients includes online data exploration supplements, serving as a community

Dissolved inorganic carbon, alkalinity, temperature, salinity and DISSOLVED OXYGEN collected from profile and discrete sample observations using Alkalinity titrator, CTD and other instruments from the Pacific Celebes in the Alboran Sea, Arabian Sea and others from 2007-06-11 to 2012-03-18 (NODC Accession 0081040)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0081040 includes chemical, discrete sample, physical and underway - surface data collected from Pacific Celebes in the Alboran Sea, Arabian Sea,...

Stronger at Depth: Jamming Grippers as Deep Sea Sampling Tools.

Science.gov (United States)

Licht, Stephen; Collins, Everett; Mendes, Manuel Lopes; Baxter, Christopher

2017-12-01

In this work we experimentally demonstrate (a) that the holding strength of universal jamming grippers increases as a function of the jamming pressure to greater than three atmospheres, and (b) that jamming grippers can be operated in the deep sea in ambient pressures exceeding one hundred atmospheres, where such high jamming pressures can be readily achieved. Laboratory experiments in a pressurized, water-filled test cell are used to measure the holding force of a "universal" style jamming gripper as a function of the pressure difference between internal membrane pressure and ambient pressure. Experiments at sea are used to demonstrate that jamming grippers can be installed on, and operated from, remotely operated vehicles at depths in excess of 1200 m. In both experiments, the jamming gripper consists of a latex balloon filled with a mixture of fresh water and ∼200 μm glass beads, which are cheaply available in large quantities as sand blasting media. The use of a liquid, rather than a gas, as the fluid media allows operation of the gripper with a closed-loop fluid system; jamming pressure is controlled with an electrically driven water hydraulic cylinder in the laboratory and with an oil hydraulic-driven large-bore water hydraulic cylinder at sea.

Determination of arsenic species in seafood samples from the Aegean Sea by liquid chromatography-(photo-oxidation)-hydride generation-atomic fluorescence spectrometry

Energy Technology Data Exchange (ETDEWEB)

Schaeffer, Richard [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Soeroes, Csilla [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Ipolyi, Ildiko [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Fodor, Peter [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Thomaidis, Nikolaos S. [Laboratory of Analytical Chemistry, Department of Chemistry, University of Athens, Panepistiomopolis Zografou, 15776 Athens (Greece)]. E-mail: ntho@chem.uoa.gr

2005-08-15

In this study arsenic compounds were determined in mussels (Mytulis galloprovincialis), anchovies (Engraulis encrasicholus), sea-breams (Sparus aurata), sea bass (Dicentrarchus labrax) and sardines (Sardina pilchardus) collected from Aegean Sea using liquid chromatography-photo-oxidation-hydride generation-atomic fluorescence spectrometry [LC-(PO)-HG-AFS] system. Twelve arsenicals were separated and determined on the basis of their difference in two properties: (i) the pK {sub a} values and (ii) hydride generation capacity. The separation was carried out both with an anion- and a cation-exchange column, with and without photo-oxidation. In all the samples arsenobetaine, AB was detected as the major compound (concentrations ranging between 2.7 and 23.1 {mu}g g{sup -1} dry weight), with trace amounts of arsenite, As(III), dimethylarsinic acid, DMA and arsenocholine, AC, also present. Arsenosugars were detected only in the mussel samples (in concentrations of 0.9-3.6 {mu}g g{sup -1} dry weight), along with the presence of an unknown compound, which, based on its retention time on the anion-exchange column Hamilton PRP-X100 and a recent communication [E. Schmeisser, R. Raml, K.A. Francesconi, D. Kuehnelt, A. Lindberg, Cs. Soeroes, W. Goessler, Chem. Commun. 16 (2004) 1824], is supposed to be a thio-arsenic analogue.

Frost flowers and sea-salt aerosols over seasonal sea-ice areas in northwestern Greenland during winter–spring

Directory of Open Access Journals (Sweden)

K. Hara

2017-07-01

Full Text Available Sea salts and halogens in aerosols, frost flowers, and brine play an important role in atmospheric chemistry in polar regions. Simultaneous sampling and observations of frost flowers, brine, and aerosol particles were conducted around Siorapaluk in northwestern Greenland during December 2013 to March 2014. Results show that water-soluble frost flower and brine components are sea-salt components (e.g., Na+, Cl−, Mg2+, K+, Ca2+, Br−, and iodine. Concentration factors of sea-salt components of frost flowers and brine relative to seawater were 1.14–3.67. Sea-salt enrichment of Mg2+, K+, Ca2+, and halogens (Cl−, Br−, and iodine in frost flowers is associated with sea-salt fractionation by precipitation of mirabilite and hydrohalite. High aerosol number concentrations correspond to the occurrence of higher abundance of sea-salt particles in both coarse and fine modes, and blowing snow and strong winds. Aerosol number concentrations, particularly in coarse mode, are increased considerably by release from the sea-ice surface under strong wind conditions. Sulfate depletion by sea-salt fractionation was found to be limited in sea-salt aerosols because of the presence of non-sea-salt (NSS SO42−. However, coarse and fine sea-salt particles were found to be rich in Mg. Strong Mg enrichment might be more likely to proceed in fine sea-salt particles. Magnesium-rich sea-salt particles might be released from the surface of snow and slush layer (brine on sea ice and frost flowers. Mirabilite-like and ikaite-like particles were identified only in aerosol samples collected near new sea-ice areas. From the field evidence and results from earlier studies, we propose and describe sea-salt cycles in seasonal sea-ice areas.

Frost flowers and sea-salt aerosols over seasonal sea-ice areas in northwestern Greenland during winter-spring

Science.gov (United States)

Hara, Keiichiro; Matoba, Sumito; Hirabayashi, Motohiro; Yamasaki, Tetsuhide

2017-07-01

Sea salts and halogens in aerosols, frost flowers, and brine play an important role in atmospheric chemistry in polar regions. Simultaneous sampling and observations of frost flowers, brine, and aerosol particles were conducted around Siorapaluk in northwestern Greenland during December 2013 to March 2014. Results show that water-soluble frost flower and brine components are sea-salt components (e.g., Na+, Cl-, Mg2+, K+, Ca2+, Br-, and iodine). Concentration factors of sea-salt components of frost flowers and brine relative to seawater were 1.14-3.67. Sea-salt enrichment of Mg2+, K+, Ca2+, and halogens (Cl-, Br-, and iodine) in frost flowers is associated with sea-salt fractionation by precipitation of mirabilite and hydrohalite. High aerosol number concentrations correspond to the occurrence of higher abundance of sea-salt particles in both coarse and fine modes, and blowing snow and strong winds. Aerosol number concentrations, particularly in coarse mode, are increased considerably by release from the sea-ice surface under strong wind conditions. Sulfate depletion by sea-salt fractionation was found to be limited in sea-salt aerosols because of the presence of non-sea-salt (NSS) SO42-. However, coarse and fine sea-salt particles were found to be rich in Mg. Strong Mg enrichment might be more likely to proceed in fine sea-salt particles. Magnesium-rich sea-salt particles might be released from the surface of snow and slush layer (brine) on sea ice and frost flowers. Mirabilite-like and ikaite-like particles were identified only in aerosol samples collected near new sea-ice areas. From the field evidence and results from earlier studies, we propose and describe sea-salt cycles in seasonal sea-ice areas.

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1997-04-14 to 1997-05-22 (NODC Accession 0113563)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113563 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1995-02-17 to 1995-03-18 (NODC Accession 0113543)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113543 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JAMES CLARK ROSS in the North Greenland Sea and Norwegian Sea from 1996-07-20 to 1996-08-22 (NODC Accession 0113757)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113757 includes chemical, discrete sample, physical and profile data collected from JAMES CLARK ROSS in the North Greenland Sea and Norwegian Sea...

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1998-08-01 to 1998-08-23 (NODC Accession 0113758)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113758 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MIRAI in the East China Sea, Japan Sea and others from 2005-10-31 to 2006-01-30 (NODC Accession 0109919)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109919 includes chemical, discrete sample, physical and profile data collected from MIRAI in the East China Sea (Tung Hai), Japan Sea, North Pacific...

Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KAIYO-MARU in the East China Sea (Tung Hai) and Philippine Sea from 1996-06-20 to 1996-07-15 (NODC Accession 0115023)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115023 includes chemical, discrete sample, physical and profile data collected from KAIYO-MARU in the East China Sea (Tung Hai) and Philippine Sea...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the G.O. SARS in the North Greenland Sea and Norwegian Sea from 2006-07-21 to 2006-08-05 (NODC Accession 0105859)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0105859 includes chemical, discrete sample, physical and profile data collected from G.O. SARS in the North Greenland Sea and Norwegian Sea from...

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the Beaufort Sea and Bering Sea from 2006-08-21 to 2006-09-29 (NODC Accession 0112268)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112268 includes chemical, discrete sample, optical, physical and profile data collected from MIRAI in the Beaufort Sea and Bering Sea from 2006-08-21...

The use of at-sea-sampling data to dissociate environmental variability in Norway lobster (Nephrops norvegicus) catches to improve resource efficiency

DEFF Research Database (Denmark)

Feekings, Jordan P.; Christensen, Asbjørn; Jonsson, Patrik

2014-01-01

The primary aim of this study was to determine whether the information collected as part of the at-sea-sampling program could be used to identify hydrographical and environmental variables that are influential on catch rates of Norway lobster. Ultimately, we wanted to know whether environmental...

Black Sea aerosols

International Nuclear Information System (INIS)

Hacisalihoglu, G.; Eliyakut, F.; Anwari, M.A.; Ataman, O.Y.; Balkas, T.I.; Tuncel, G.; Olmez, I.

1991-01-01

Shipboard, high volume air particulate samples were collected from the Black Sea atmosphere and analyzed by instrumental neutron activation analysis, atomic absorption spectrophotometry and ion chromatography for about 40 elements and ions. Concentrations of elements in the eastern and western parts of the Black Sea are different at the 95% confidence level, with lower concentrations in the eastern Black Sea. Back-trajectories and concentrations of elements in trajectory groups show that Europe accounts for more than 70% of the anthropogenic elements in the atmosphere. The average sulfate concentration was 7 μg/m 3 , which is comparable with rural sulfate levels in western Europe. Fluxes of elements from the atmosphere to the Black Sea are in good agreement with the results of similar flux calculations for other regions

Distribution and activity of petroleum hydrocarbon degrading bacteria in the North Sea and Baltic Sea

International Nuclear Information System (INIS)

Bruns, K.; Dahlmann, G.; Gunkel, W.

1993-01-01

Data were collected in 1988 and 1989 on the distribution and activity of petroleum hydrocarbon degrading bacteria in the North Sea and Baltic Sea. Crude oil degrading bacteria and the number of bacteria which in particular degrade naphthalene were quantified using a modified dilution method (MPN). Crude oil degrading bacteria were present in all of about 100 water samples, with as many as 10 3 ml -1 in some samples. Numbers of naphthalene degrading bacteria were at least tenfold lower. There is obviously a greater connection between this bacteria group and petroleum hydrocarbon (PHC) contamination than between the more nonspecific group of crude oil degrading bacteria and PHC contamination. Data from the North Sea show an extremely high abundance of hydrocarbon degrading bacteria, even in winter, while in the southern Baltic Sea low numbers of bacteria were found and slower crude oil degradation was observed. (orig.)

Environmental assessment of rosetta area,mediterranean sea coast - egypt

International Nuclear Information System (INIS)

Aly, A.M.A.

2013-01-01

This study is titled (Environmental Assessment of Rosetta Area,Mediterranean Sea Coast, Egypt). The environmental assessment can be defined here as the process of assessing the potential impacts (positive or negative) of the presence of certain influential on a particular ecosystem. Samples were collected from Abu Khashaba beach area, Rosetta on the Mediterranean Sea coast. Samples of the beach sediments, sea-water and the scattered shells in this coastal region were collected. Sediments in this region are characterized by its large content of heavy metals, which added to these sediments its black color. It is known that these black sands occurred along the Mediterranean Sea coast from Alexandria to Rafah. The advantage of these black sand deposits is their contents from multiple economic metals which have important industrial uses, such as magnetite, ilmenite, rutile, monazite, zircon, garnet and other important minerals. Ten sampling profiles spaced in-between by about 600 m distance, and extending into the land from the shoreline for about 50 m or less. Along each profile, three sediment samples were collected; the first sample from the surface at the beach line, the second sample from the end of the foreshore area at a depth of about 50 cm and the third sample was taken from the backshore area at a depth of about 1 m. Extending from each profile into the sea, marine-water samples were taken at a distance of about 3 m from the beach line, and from a depth of about 1 m below the sea surface. The shells samples were collected from the scattered shells on the beach. By examination of these samples a 15 different shells types were defined.

Upper Campanian−Maastrichtian holostratigraphy of the eastern Danish Basin

DEFF Research Database (Denmark)

Surlyk, Finn; Rasmussen, Susanne Lil; Boussaha, Myriam

2013-01-01

of changes in chalk facies, water depths and sea-water temperatures. Combined lithological data, a suite of petrophysical logs including gamma ray (GR) logs, nannofossil and dinoflagellate palaeontology, stable carbon isotopes, seismic reflection and refraction sections form the basis for the definition...

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from JAKOV SMIRNITSKIY in the Beaufort Sea, East Siberian Sea and others from 2008-08-15 to 2008-09-16 (NODC Accession 0108368)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108368 includes chemical, discrete sample, physical and profile data collected from JAKOV SMIRNITSKIY in the Beaufort Sea, East Siberian Sea, Kara...

Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the USCGC POLAR SEA in the North Greenland Sea from 1993-07-18 to 1993-08-20 (NODC Accession 0114447)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0114447 includes biological, chemical, discrete sample, physical and profile data collected from USCGC POLAR SEA in the North Greenland Sea from...

The Fourth SeaWiFS HPLC Analysis Round-Robin Experiment (SeaHARRE-4)

Science.gov (United States)

Hooker, Stanford B.; Thomas, Crystal S.; van Heukelem, Laurie; Schlueter, louise; Russ, Mary E.; Ras, Josephine; Claustre, Herve; Clementson, Lesley; Canuti, Elisabetta; Berthon, Jean-Francois;

A sterol and spiroditerpenoids from a Penicillium sp. isolated from a deep sea sediment sample.

Science.gov (United States)

Li, Yan; Ye, Dezan; Shao, Zongze; Cui, Chengbin; Che, Yongsheng

2012-02-01

A new polyoxygenated sterol, sterolic acid (1), three new breviane spiroditerpenoids, breviones I-K (2-4), and the known breviones (5-8), were isolated from the crude extract of a Penicillium sp. obtained from a deep sea sediment sample that was collected at a depth of 5115 m. The structures of 1-4 were elucidated primarily by NMR experiments, and 1 was further confirmed by X-ray crystallography. The absolute configurations of 2 and 3 were deduced by comparison of their CD spectra with those of the model compounds. Compounds 2 and 5 showed significant cytotoxicity against MCF-7 cells, which is comparable to the positive control cisplatin.

Petrophysical and rock-mechanics effects of CO2 injection for enhanced oil recovery

DEFF Research Database (Denmark)

Alam, Mohammad Monzurul; Hjuler, Morten Leth; Christensen, Helle Foged

2014-01-01

this issue we studied two types of chalk from South Arne field, North Sea: (1) Ekofisk Formation having >12% non-carbonate and (2) Tor Formation, which has less than 5% non-carbonate. We performed a series of laboratory experiments to reveal the changes in petrophysical and rock-mechanics properties due...... reservoirs. North Sea chalk is characterized by high porosity but also high specific surface causing low permeability. A high porosity provides room for CO2 storage, while a high specific surface causes a high risk for chemical reaction and consequently for mechanical weakening. In order to address...... to the injection of CO2 at supercritical state. We analyzed these changes with respect to the differences in porosity, specific surface, pore stiffness, wettability, mineralogy and mechanical strength. We observed a 2–3% increase in porosity, a minor decrease of specific surface and consequently a small increase...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Arctic Ocean, Beaufort Sea and Bering Sea from 2000-08-03 to 2000-10-13 (NODC Accession 0112352)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112352 includes chemical, discrete sample, physical and profile data collected from MIRAI in the Arctic Ocean, Beaufort Sea and Bering Sea from...

Technogenic and natural radionuclides in Black Sea sediments and algae

International Nuclear Information System (INIS)

Strezov, A.; Stoilova, T.; Petkov, N.; Hristoskova, M.

1999-01-01

Technogenic and natural emitters have been monitored since 1991 in marine samples from the Bulgarian Black Sea coast by low level gamma and alpha spectroscopy. The radionuclide content was determined in bottom sediment samples from 35 reference locations in the spring, summer and autumn during six consecutive years. Samples were collected and data obtained for the main Black Sea resorts and the main dwelling places along the Bulgarian Black Sea shore

First Insights into the Viral Communities of the Deep-sea Anoxic Brines of the Red Sea

KAUST Repository

Antunes, Andre

2015-10-31

The deep-sea brines of the Red Sea include some of the most extreme and unique environments on Earth. They combine high salinities with increases in temperature, heavy metals, hydrostatic pressure, and anoxic conditions, creating unique settings for thriving populations of novel extremophiles. Despite a recent increase of studies focusing on these unusual biotopes, their viral communities remain unexplored. The current survey explores four metagenomic datasets obtained from different brine-seawater interface samples, focusing specifically on the diversity of their viral communities. Data analysis confirmed that the particle-attached viral communities present in the brine-seawater interfaces were diverse and generally dominated by Caudovirales, yet appearing distinct from sample to sample. With a level of caution, we report the unexpected finding of Phycodnaviridae, which infects algae and plants, and trace amounts of insect-infecting Iridoviridae. Results from Kebrit Deep revealed stratification in the viral communities present in the interface: the upper-interface was enriched with viruses associated with typical marine bacteria, while the lower-interface was enriched with haloviruses and halophages. These results provide first insights into the unexplored viral communities present in deep-sea brines of the Red Sea, representing one of the first steps for ongoing and future sampling efforts and studies.

First Insights into the Viral Communities of the Deep-sea Anoxic Brines of the Red Sea

KAUST Repository

Antunes, Andre; Alam, Intikhab; Simoes, Marta; Daniels, Camille Arian; Ferreira, Ari J.S.; Siam, Rania; El-Dorry, Hamza; Bajic, Vladimir B.

2015-01-01

The deep-sea brines of the Red Sea include some of the most extreme and unique environments on Earth. They combine high salinities with increases in temperature, heavy metals, hydrostatic pressure, and anoxic conditions, creating unique settings for thriving populations of novel extremophiles. Despite a recent increase of studies focusing on these unusual biotopes, their viral communities remain unexplored. The current survey explores four metagenomic datasets obtained from different brine-seawater interface samples, focusing specifically on the diversity of their viral communities. Data analysis confirmed that the particle-attached viral communities present in the brine-seawater interfaces were diverse and generally dominated by Caudovirales, yet appearing distinct from sample to sample. With a level of caution, we report the unexpected finding of Phycodnaviridae, which infects algae and plants, and trace amounts of insect-infecting Iridoviridae. Results from Kebrit Deep revealed stratification in the viral communities present in the interface: the upper-interface was enriched with viruses associated with typical marine bacteria, while the lower-interface was enriched with haloviruses and halophages. These results provide first insights into the unexplored viral communities present in deep-sea brines of the Red Sea, representing one of the first steps for ongoing and future sampling efforts and studies.

Taxonomic research on deep-sea macrofauna in the South China Sea using the Chinese deep-sea submersible Jiaolong.

Science.gov (United States)

Li, Xinzheng

2017-07-01

This paper reviews the taxonomic and biodiversity studies of deep-sea invertebrates in the South China Sea based on the samples collected by the Chinese manned deep-sea submersible Jiaolong. To date, 6 new species have been described, including the sponges Lophophysema eversa, Saccocalyx microhexactin and Semperella jiaolongae as well as the crustaceans Uroptychus jiaolongae, Uroptychus spinulosus and Globospongicola jiaolongi; some newly recorded species from the South China Sea have also been reported. The Bathymodiolus platifrons-Shinkaia crosnieri deep-sea cold seep community has been reported by Li (2015), as has the mitochondrial genome of the glass sponge L. eversa by Zhang et al. (2016). The population structures of two dominant species, the shrimp Shinkaia crosnieri and the mussel Bathymodiolus platifrons, from the cold seep Bathymodiolus platifrons-Shinkaia crosnieri community in the South China Sea and the hydrothermal vents in the Okinawa Trough, were compared using molecular analysis. The systematic position of the shrimp genus Globospongicola was discussed based on 16S rRNA gene sequences. © 2017 International Society of Zoological Sciences, Institute of Zoology/Chinese Academy of Sciences and John Wiley & Sons Australia, Ltd.

Deep sea radionuclides

International Nuclear Information System (INIS)

Kanisch, G.; Vobach, M.

1993-01-01

Every year since 1979, either in sping or in summer, the fishing research vessel 'Walther Herwig' goes to the North Atlantic disposal areas of solid radioactive wastes, and, for comparative purposes, to other areas, in order to collect water samples, plankton and nekton, and, from the deep sea bed, sediment samples and benthos organisms. In addition to data on the radionuclide contents of various media, information about the plankton, nekton and benthos organisms living in those areas and about their biomasses could be gathered. The investigations are aimed at acquiring scientifically founded knowledge of the uptake of radioactive substances by microorganisms, and their migration from the sea bottom to the areas used by man. (orig.) [de

An overview of the waste characterization program at Chalk River Nuclear Laboratories

International Nuclear Information System (INIS)

Csullog, G.W.; Hardy, D.G.

1988-01-01

In the last five years, Chalk River Nuclear Laboratories (CRNL) placed 17,000 m 3 of wastes into storage (excluding contaminated soil and fill). Almost half of the waste was generated off-site. CRNL is now developing IRUS, an Intrusion Resistant Underground Structure, and the IST, an Improved Sand Trench, to replace storage with safe, permanent disposal. IRUS will be used to dispose of wastes with radiologically hazardous lifetimes between 150 and 500 years duration and the IST will be used for wastes with radiologically hazardous lifetimes of less than 150 years. A comprehensive Waste Characterization Program (WCP) is in place to support disposal projects. The WCP is responsible for (1) specifying the manifests for waste shipments; (2) developing and maintaining central databases for waste inventories and analytical data; and (3) developing the technologies and procedures to characterize the radiological and the physical/chemical properties of wastes. WCP work is being performed under the umbrella of a newly developed waste management quality assurance (QA) program. This paper gives an overview of the WCP with an emphasis on the requirements for determining radionuclide inventories in wastes, for implementing record-keeping systems and for maintaining a QA program for disposal operations

Trace determination of heavy metal concentrations in fauna, flora and salt samples from Black Sea waters by charged particles - induced X-rays

International Nuclear Information System (INIS)

Badica, T.; Ciortea, C.; Dima, S.; Petrovici, A.; Popescu, I.; Serbanescu, O.

1977-01-01

Studies were performed on Black Sea pollution by charged particles induced X-rays spectra analysis, using alpha and 16 O beams. Fauna, flora and salt samples were analysed. We found some of the concentrations of pollutant elements to be below the accepted levels. (author)

Chemometrics methods for the investigation of methylmercury and total mercury contamination in mollusks samples collected from coastal sites along the Chinese Bohai Sea.

Science.gov (United States)

Yawei, Wang; Lina, Liang; Jianbo, Shi; Guibin, Jiang

2005-06-01

The development and application of chemometrics methods, principal component analysis (PCA), cluster analysis and correlation analysis for the determination of methylmercury (MeHg) and total mecury (HgT) in gastropod and bivalve species collected from eight coastal sites along the Chinese Bohai Sea are described. HgT is directly determined by atomic fluorescence spectrometry (AFS), while MeHg is measured by a laboratory established high performance liquid chromatography-atomic fluorescence spectrometry system (HPLC-AFS). One-way ANOVA and cluster analysis indicated that the bioaccumulation of Rap to accumulate Hg was significantly (P<0.05) different from other mollusks. Correlation analysis shows that there is linear relationship between MeHg and HgT in mollusks samples collected from coastal sites along the Chinese Bohai Sea, while in mollusks samples collected from Hongqiao market in Beijing City, there is not any linear relationship.

Comparative metagenomics of the Red Sea

KAUST Repository

Mineta, Katsuhiko

2016-01-01

started monthly samplings of the metagenomes in the Red Sea under KAUST-CCF project. In collaboration with Kitasato University, we also collected the metagenome data from the ocean in Japan, which shows contrasting features to the Red Sea. Therefore

Non-destructive identification of micrometer-scale minerals and their position within a bulk sample

DEFF Research Database (Denmark)

Sørensen, Henning O.; Hakim, Sepide S.; Pedersen, Stefan

2012-01-01

. Crushing or disintegrating a sample annihilates any possibility for gathering information from the texture of the porous media or the mineral assemblage close to the grains in question. A new method using three-dimensional X-ray diffraction (3DXRD) microscopy can be successfully applied to natural...... materials. We combined X-ray microtomography (XMT) and 3DXRD to investigate a sample of very fine-grained chalk containing fracture minerals. The XMT technique provides three-dimensional images of the particles and pore structure at very high resolution (350 nm voxel dimension) on samples less than 500 μm......Using the conventional techniques of mineralogy, it has been a challenge to determine mineral identity, crystal orientation and spatial position of micrometer-sized crystals that are embedded in a rock, sediment or soil. Traditionally, the individual grains must be extracted and analyzed separately...

Towards a representative periphytic diatom sample

Directory of Open Access Journals (Sweden)

2007-01-01

Full Text Available The need to acquire a representative periphytic diatom sample for river water quality monitoring has been recognised in the development of existing diatom indices, important in the development and employment of diatom monitoring tools for the Water Framework Directive. In this study, a nested design with replication is employed to investigate the magnitude of variation in diatom biomass, composition and Trophic Diatom Index at varying scales within a small chalk river. The study shows that the use of artificial substrates may not result in diatom communities that are typical of the surrounding natural substrates. Periphytic diatom biomass and composition varies between artificial and natural substrates, riffles and glides and between two stretches of the river channel. The study also highlights the existence of high variation in diatom frustule frequency and biovolume at the individual replicate scale which may have implications for the use of diatoms in routine monitoring.

Transcriptomes and expression profiling of deep-sea corals from the Red Sea provide insight into the biology of azooxanthellate corals

OpenAIRE

Yum, L. K.; Baumgarten, S.; Röthig, T.; Roder, C.; Roik, Anna; Michell, C.; Voolstra, C. R.

2017-01-01

Despite the importance of deep-sea corals, our current understanding of their ecology and evolution is limited due to difficulties in sampling and studying deep-sea environments. Moreover, a recent re-evaluation of habitat limitations has been suggested after characterization of deep-sea corals in the Red Sea, where they live at temperatures of above 20??C at low oxygen concentrations. To gain further insight into the biology of deep-sea corals, we produced reference transcriptomes and studie...

Quarterly Fishery Surveys - Salton Sea [ds428

Data.gov (United States)

California Natural Resource Agency — In the spring of 2003, California Department of Fish and Game (CDFG) personnel began quarterly sampling of Salton Sea fish at fourteen stations around the sea, as...

First report of the planktonic copepod Oithona davisae in the northern Wadden Sea (North Sea): Evidence for recent invasion?

Science.gov (United States)

Cornils, Astrid; Wend-Heckmann, Britta

2015-06-01

In October 2010, specimens of Oithona were taken from the List Tidal Basin in the northern Wadden Sea (North Sea) for a biogeographic study on Oithona similis. These specimens could not be assigned to O. similis or any of the other Oithona species known from the North Sea genetically. These specimens were identified as Oithona davisae Ferrari and Orsi 1984, a Northwest Pacific species, known as an invasive species from the Black Sea and the northwestern Mediterranean Sea. Recent sampling provided evidence that O. davisae is still present in the northern Wadden Sea and may thus now be a permanent plankton species.

First Insights into the Viral Communities of the Deep-sea Anoxic Brines of the Red Sea.

Science.gov (United States)

Antunes, André; Alam, Intikhab; Simões, Marta Filipa; Daniels, Camille; Ferreira, Ari J S; Siam, Rania; El-Dorry, Hamza; Bajic, Vladimir B

2015-10-01

The deep-sea brines of the Red Sea include some of the most extreme and unique environments on Earth. They combine high salinities with increases in temperature, heavy metals, hydrostatic pressure, and anoxic conditions, creating unique settings for thriving populations of novel extremophiles. Despite a recent increase of studies focusing on these unusual biotopes, their viral communities remain unexplored. The current survey explores four metagenomic datasets obtained from different brine-seawater interface samples, focusing specifically on the diversity of their viral communities. Data analysis confirmed that the particle-attached viral communities present in the brine-seawater interfaces were diverse and generally dominated by Caudovirales, yet appearing distinct from sample to sample. With a level of caution, we report the unexpected finding of Phycodnaviridae, which infects algae and plants, and trace amounts of insect-infecting Iridoviridae. Results from Kebrit Deep revealed stratification in the viral communities present in the interface: the upper-interface was enriched with viruses associated with typical marine bacteria, while the lower-interface was enriched with haloviruses and halophages. These results provide first insights into the unexplored viral communities present in deep-sea brines of the Red Sea, representing one of the first steps for ongoing and future sampling efforts and studies. Copyright © 2015 The Authors. Production and hosting by Elsevier Ltd.. All rights reserved.

Elastic and electric properties of North Sea Chalk

DEFF Research Database (Denmark)

Olsen, Casper

bjergartsfysiske modeller til forudsigelse af Biot’s koefficient ud fra porøsitet og én lydhastighed og hans resultater tyder på at Berryman’s udbredte ”Selfconsistent Model” er mindre velegnet til det formål, mens at de simplere Isoframe og Bound-averaging metoder giver bedre resultater. Dvorkin’s partikel...

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the ODEN in the Arctic Ocean, Beaufort Sea and Bering Sea from 2005-08-19 to 2005-09-25 (NODC Accession 0108129)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108129 includes chemical, discrete sample, physical and profile data collected from ODEN in the Arctic Ocean, Beaufort Sea and Bering Sea from...

Uranium series geochemistry in aquifers: quantification of transport mechanisms of uranium and daughter products: the chalk aquifer (Champagne, France)

International Nuclear Information System (INIS)

Hubert, A.

2005-09-01

With the increase of contaminant flux of radionuclides in surface environment (soil, river, aquifer...), there is a need to understand and model the processes that control the distribution of uranium and its daughter products during transport within aquifers. We have used U-series disequilibria as an analogue for the transport of uranium and its daughter products in aquifer to understand such mechanisms. The measurements of uranium ( 234 U et 238 U), thorium ( 230 Th et 232 Th), 226 Ra and 222 Rn isotopes in the solid and liquid phases of the chalk aquifer in Champagne (East of France) allows us to understand the processes responsible for fractionation within the uranium decay chain. Fractionations are induced by physical and chemical properties of the elements (leaching, adsorption) but also by radioactive properties (recoil effect during α-decay). For the first time a comprehensive sampling of the solid phase has been performed, allowing quantifying mechanisms responsible for the long term evolution of the aquifer. A non steady state 1D model has been developed which takes into account leaching, adsorption processes as well as radioactive filiation and α-recoil effect. Retardation coefficients have been calculated for uranium, thorium and radium. The aquifer is characterised by a double porosity, and the contribution of fracture and matrix porosity on the water/rock interaction processes has been estimated. (author)

Coccolithophore assemblage response to Black Sea Water inflow into the North Aegean Sea (NE Mediterranean)

Science.gov (United States)

Karatsolis, B.-Th.; Triantaphyllou, M. V.; Dimiza, M. D.; Malinverno, E.; Lagaria, A.; Mara, P.; Archontikis, O.; Psarra, S.

2017-10-01

This study aims to presents the species composition of living coccolithophore communities in the NE Aegean Sea, investigating their spatial and temporal variations along a north-south transect in the area receiving the inflowing surface Black Sea Water (BSW) over the deeper Levantine Water (LW) layer. Coccolithophores in the area were relatively diverse and a total of 95 species over 3 sampling periods studied were recognized using Scanning Electron Microscope (SEM) techniques. R-mode hierarchical cluster analysis distinguished two coccolithophore Groups (I, IIa, IIb, IIc) with different ecological preferences. Emiliania huxleyi was the most abundant species of Group I, whereas Syracosphaera spp., Rhabdosphaera spp. and holococcolithophores were prevailing in the highly diversified Group II assemblages. Biometric analysis conducted on E. huxleyi coccoliths from Aegean water column and Black Sea sediment trap samples, indicated that during autumn, NE Aegean specimens in samples under BSW influence were featured by unimodal distribution concerning the coccolith relative tube width, with values similar to those provided by the Black Sea specimens. In early spring, coccoliths in the stations with increased BSW influx displayed a bimodal pattern of relative tube width with smaller values found mostly in the surface layers, while the distribution became again unimodal and dominated by larger values within the deeper LW layers. In the summer period, the typical LW holococcolithophore species (Group II) presented low cell numbers in the surface layer (huxleyi was almost absent in the NE Aegean during the summer sampling period.

Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the Japan Sea, North Pacific Ocean and Sea of Okhotsk from 2006-08-01 to 2006-08-20 (NODC Accession 0112267)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112267 includes chemical, discrete sample, optical, physical and profile data collected from MIRAI in the Japan Sea, North Pacific Ocean and Sea of...

Acoustic and Petrophysical Evolution of Organic-Rich Chalk Following Maturation Induced by Unconfined Pyrolysis

Science.gov (United States)

Shitrit, Omri; Hatzor, Yossef H.; Feinstein, Shimon; Vinegar, Harold J.

2017-12-01

Thermal maturation is known to influence the rock physics of organic-rich rocks. While most studies were performed on low-porosity organic-rich shales, here we examine the effect of thermal maturation on a high-porosity organic-rich chalk. We compare the physical properties of native state immature rock with the properties at two pyrolysis-simulated maturity levels: early-mature and over-mature. We further evaluate the applicability of results from unconfined pyrolysis experiments to naturally matured rock properties. Special attention is dedicated to the elastic properties of the organic phase and the influence of bitumen and kerogen contents. Rock physics is studied based on confined petrophysical measurements of porosity, density and permeability, and measurements of bedding-normal acoustic velocities at estimated field stresses. Geochemical parameters like total organic carbon (TOC), bitumen content and thermal maturation indicators are used to monitor variations in density and volume fraction of each phase. We find that porosity increases significantly upon pyrolysis and that P wave velocity decreases in accordance. Solids density versus TOC relationships indicate that the kerogen increases its density from 1.43 to 1.49 g/cc at the immature and early-mature stages to 2.98 g/cc at the over-mature stage. This density value is unusually high, although increase in S wave velocity and backscatter SEM images of the over-mature samples verify that the over-mature kerogen is significantly denser and stiffer. Using the petrophysical and acoustic properties, the elastic moduli of the rock are estimated by two Hashin-Shtrikman (HS)-based models: "HS + BAM" and "HS kerogen." The "HS + BAM" model is calibrated to the post-pyrolysis measurements to describe the mechanical effect of the unconfined pyrolysis on the rock. The absence of compaction in the pyrolysis process causes the post-pyrolysis samples to be extremely porous. The "HS kerogen" model, which simulates a

Spatial sea-level reconstruction in the Baltic Sea and in the Pacific Ocean from tide gauges observations

Directory of Open Access Journals (Sweden)

Marco Olivieri

2016-07-01

Full Text Available Exploiting the Delaunay interpolation, we present a newly implemented 2-D sea-level reconstruction from coastal sea-level observations to open seas, with the aim of characterizing the spatial variability of the rate of sea-level change. To test the strengths and weaknesses of this method and to determine its usefulness in sea-level interpolation, we consider the case studies of the Baltic Sea and of the Pacific Ocean. In the Baltic Sea, a small basin well sampled by tide gauges, our reconstructions are successfully compared with absolute sea-level observations from altimetry during 1993-2011. The regional variability of absolute sea level observed across the Pacific Ocean, however, cannot be reproduced. We interpret this result as the effect of the uneven and sparse tide gauge data set and of the composite vertical land movements in and around the region. Useful considerations arise that can serve as a basis for developing sophisticated approaches.

Extending the Instrumental Record of Sea-Level Change: A 1300-Year Sea-Level Record From Eastern Connecticut

Science.gov (United States)

Donnelly, J. P.; Cleary, P.

2002-12-01

The instrumental record of sea-level change in the northeastern United States extends back to the early 20th century and at New York City (NYC) extends back to 1856. These tide gauge records indicate that sea level has risen at a rate of 2.5 to 4 mm/year over the last 100-150 years. Geologic evidence of sea-level change in the region over the last 2,000 years indicates rates of sea-level rise of about 1 mm/year or less. The discordance between the instrumental and geologic records is frequently cited as potentially providing evidence that anthropogenic warming of the climate system has resulted in an increase in the rate of sea-level rise. In order to begin to test the hypothesis that acceleration in the rate of sea-level rise has occurred in the last 150 years due to anthropogenic climate warming, accurate and precise information on the timing of the apparent acceleration in sea-level rise are needed. Here we construct a high-resolution relative sea-level record for the past 1350 years by dating basal salt marsh peat samples above a glacial erratic in a western Connecticut salt marsh. Preservation of marsh vegetation remains in the sediment record that has a narrow vertical habitat range at the upper end of the tidal range provides information on past sea levels. { \\it Spartina patens} (marsh hay) and { \\it Juncus gerardi} (black rush) dominate both the modern marsh and their remains are the major constituent of the marsh sediments and occur in the modern marsh between mean high water (MHW) and mean highest high water. We use the elevation distribution of modern plant communities to estimate the relationship of sediment samples to paleo-mean high water. The chronology is based on 15 radiocarbon ages, supplemented by age estimates derived from the horizons of industrial Pb pollution and pollen indicative of European land clearance. Thirteen of the radiocarbon ages and the Pb and pollen data come from samples taken along a contact between marsh peat and a glacial

Cliff stability assessment using electrical resistivity tomography at the historic WWII D-Day invasion site, Pointe du Hoc, France

Science.gov (United States)

Everett, M. E.; Udphuay, S.; Warden, R.

2007-05-01

The 1944 D-Day invasion site at Pointe du Hoc, Normandy, France is an important WWII battlefield and cultural resource but is at risk from chalk cliff collapse. The American Battle Monuments Commission tasked us to evaluate the geohazard to the observation post and other cliff-side buildings of historical significance. Geophysical multi-electrode resistivity profiling is used to study cliff stability and the condition of the observation- post foundations. Preliminary 2-D geological interpretations are provided of individual profiles. The copious steel, concrete and void spaces at the site renders hydrogeological interpretation challenging but tractable. The cliff face appears to be relatively intact and well-drained. Several routes taken by groundwater into fractures within the chalk were identified mainly on the western side of the site. The eastern side is drier and somewhat sheltered from the Atlantic storms but may contain large void spaces that could efficiently transmit groundwater flow during heavy precipitation events, thereby imperiling the major antiaircraft gun emplacement occupied by Col. Rudder in the early days of the Allied invasion. The forward German observation post perched close to the sea stack, which now hosts the U.S. Ranger memorial, may be moving with the soil and not securely anchored to bedrock. A complex failure mechanism is identified as a combination of groundwater dissolution of the fractured chalk and sea wave attack at the cliff base.

Sea level trends in South East Asian Seas (SEAS)

Science.gov (United States)

Strassburg, M. W.; Hamlington, B. D.; Leben, R. R.; Manurung, P.; Lumban Gaol, J.; Nababan, B.; Vignudelli, S.; Kim, K.-Y.

2014-10-01

Southeast Asian Seas (SEAS) span the largest archipelago in the global ocean and provide a complex oceanic pathway connecting the Pacific and Indian Oceans. The SEAS regional sea level trends are some of the highest observed in the modern satellite altimeter record that now spans almost two decades. Initial comparisons of global sea level reconstructions find that 17 year sea level trends over the past 60 years exhibit good agreement in areas and at times of strong signal to noise associated decadal variability forced by low frequency variations in Pacific trade winds. The SEAS region exhibits sea level trends that vary dramatically over the studied time period. This historical variation suggests that the strong regional sea level trends observed during the modern satellite altimeter record will abate as trade winds fluctuate on decadal and longer time scales. Furthermore, after removing the contribution of the Pacific Decadal Oscillation (PDO) to sea level trends in the past twenty years, the rate of sea level rise is greatly reduced in the SEAS region. As a result of the influence of the PDO, the SEAS regional sea level trends during 2010s and 2020s are likely to be less than the global mean sea level (GMSL) trend if the observed oscillations in wind forcing and sea level persist. Nevertheless, long-term sea level trends in the SEAS will continue to be affected by GMSL rise occurring now and in the future.

Organic Matter Contents and Paleoproductivity Variation Within Late Pleistocene Japan Sea/East Sea Sediments: Results from IODP Expedition 346

Science.gov (United States)

Black, H. D.; Anderson, W. T., Jr.

2017-12-01

Inorganic and organic matter concentrations as well as the stable isotopes of nitrogen and organic carbon are presented for continuous sedimentary sequences collected during Integrated Ocean Drilling Program (IODP) Expedition 346 in the Japan Sea/East Sea in 2013. During major glacioeustatic sea level changes, the paleoceanographic conditions within the Japan Sea/East Sea widely vary due to the shallow, narrow straights connecting the sea to surrounding waters limiting an influx of oceanic currents. During glacial sea level low-stands the sea can be nearly isolated, creating a highly-stratified water column and hypoxic to anoxic bottom water conditions. Meanwhile during sea level high-stands, the Tsushima Warm Current (TWC) flows into the sea bringing warmer, nutrient-rich inputs, leading to vertical mixing and oxic conditions. This study aims to better understand the role of orbital cycling within the organic matter and stable isotope contents of these Late Pleistocene sediments. A total of 192 samples were analyzed each for %CaCO3, %TOC, δ13C, %N, and δ15N from two Expedition 346 sampling sites (U1426 and U1427) during the last 430,000 years and statistical analyses were completed using wavelet and time series analyses. Carbonate concentration ranges from 0-44.3%, total organic carbon 0.2 to 6.4%, δ13C -25.8 to -19.6‰, %N 0.04 to 0.4%, and δ15N 3.8 to 13.1‰. These results are well correlated with b* color values of the sediment and generally show increased productivity during interglacial periods, likely through increased vertical mixing and deepwater ventilation, when compared to glacial periods within the Japan Sea/East Sea when the sea may be partially isolated.

Correlation of Element Concentration of Cd, Cr, Co and Sc in Sea Water, Fish and Algae Samples from Beach of Lemahabang Muria

International Nuclear Information System (INIS)

Sukirno; Rosidi; Agus Taftazani

2007-01-01

The analysis of Cd, Cr, Co, Sb and Sc element in beach environmental samples Lemahabang Muria in the year 2004 has been carried out by using neutron activation analysis (NAA) method. All of heavy metals from sea water (2.0 μg/l) are obviously lower than the threshold value established by SKRI No 51/2004. From the observed data by Excel application of the correlation value (r) shows that between Cd, Cr, Co, Sb and Sc concentrations from dependent variable of sea water about tree independent variable of kerapu fish, green and brown algae shows a highly positive significant correlation (r > 0.92) except element of Sb was sufficiently positive high (r = 0.66). (author)

Sea level hazards: Altimetric monitoring of tsunamis and sea level rise

Science.gov (United States)

Hamlington, Benjamin Dillon

Whether on the short timescale of an impending tsunami or the much longer timescale of climate change-driven sea level rise, the threat stemming from rising and inundating ocean waters is a great concern to coastal populations. Timely and accurate observations of potentially dangerous changes in sea level are vital in determining the precautionary steps that need to be taken in order to protect coastal communities. While instruments from the past have provided in situ measurements of sea level at specific locations across the globe, satellites can be used to provide improved spatial and temporal sampling of the ocean in addition to producing more accurate measurements. Since 1993, satellite altimetry has provided accurate measurements of sea surface height (SSH) with near-global coverage. Not only have these measurements led to the first definitive estimates of global mean sea level rise, satellite altimetry observations have also been used to detect tsunami waves in the open ocean where wave amplitudes are relatively small, a vital step in providing early warning to those potentially affected by the impending tsunami. The use of satellite altimetry to monitor two specific sea level hazards is examined in this thesis. The first section will focus on the detection of tsunamis in the open ocean for the purpose of providing early warning to coastal inhabitants. The second section will focus on estimating secular trends using satellite altimetry data with the hope of improving our understanding of future sea level change. Results presented here will show the utility of satellite altimetry for sea level monitoring and will lay the foundation for further advancement in the detection of the two sea level hazards considered.

Exploring the utility of quantitative network design in evaluating Arctic sea ice thickness sampling strategies

OpenAIRE

Kaminski, T.; Kauker, F.; Eicken, H.; Karcher, M.

2015-01-01

We present a quantitative network design (QND) study of the Arctic sea ice-ocean system using a software tool that can evaluate hypothetical observational networks in a variational data assimilation system. For a demonstration, we evaluate two idealised flight transects derived from NASA's Operation IceBridge airborne ice surveys in terms of their potential to improve ten-day to five-month sea-ice forecasts. As target regions for the forecasts we select the Chukchi Sea, a...

Radioactivity levels in Barents, Petshora, Kara, Laptev and White Seas

International Nuclear Information System (INIS)

Rissanen, K.; Matishov, D.; Matishov, G.G.

1995-01-01

The samples collected and analysed during joint work between the Finnish Centre for Radiation and Nuclear Safety and the Murmansk Marine Biological Institute cover a rather large area of the arctic in north west Russia. All the analysed sediments, algae, benthic and fish samples, have shown surprisingly low radionuclide concentrations and indicate that the open sea areas are almost uncontaminated. But the most interesting locations with potential risk sources are closed areas. 134 Cs isotope originating from the fallout of the Chernobyl accident was measured only in terrestrial samples collected on the Kola peninsula and around the White Sea. Small amounts of this isotope with only 2 years half-life was also noticed in some sediment samples from White Sea. 134 Cs isotopes was not noticed in any terrestrial sample collected from the coastal area between the Kanin peninsula and the Jenisey river. The very low concentrations of 134 Cs isotope measured in Kara Sea sediment samples were usually in association with an outlet of a river and were obviously transported by river water from the central parts of Russia. The measured low concentrations of the antropogenic radionuclides in the Barents and Petshora Sea originate obviously from the global fallout. The higher White Sea concentrations contain also additional fallout from the Chernobyl accident and probably also some terrestrial runoff. Low concentration of 60 Co isotopes in some sediment, algae and benthic fauna samples, reveals, however, slight fresh contamination, as were concentrations also at the outlet of Jenisey river. The results on well documented sampling locations represent also background data for possible leakage or other accidents. 5 refs., 3 figs, 3 tabs

Sea Cucumber (Holothuroidea Species of Turkey

Directory of Open Access Journals (Sweden)

Mehmet AYDIN

2016-11-01

Full Text Available There are nearly 1200 sea cucumber species in the world oceans, while only 37 species from Holothuroidea class lives in the Mediterranean Sea. This preliminary study aims identification sea cucumbers species of the Turkish waters. The sea cucumber samples used in this study were obtained from a series of different studies between the years of 2008 and 2014. Identification of the species are mainly based on the morphometric characteristics while some of species are determined from their calcareous spicules. Eight sea species were identified in this research which are; Holothuria tubulosa, Holothuria polii, Holothuria mammata, Holothuria (Platyperona sanctori, Holothuria forskali, Stichopus regalis, Synaptula reciprocans and Stereoderma kirschbergi. There are limited number of studies in the literature focusing on the identification of the sea cucumber species spread in our seas. Therefore, this study is believed to play an important role in guiding future researches.

Tritium concentration in fresh, brackish and sea-water samples in Rokkasho-Village, Japan, bordered by nuclear fuel cycle facilities

International Nuclear Information System (INIS)

Ueda, S.; Kakiuchi, H.; Kondo, K.; Inaba, J.

2006-01-01

In order to identify the concentration of tritium ( 3 H) in areas of fresh, brackish and sea water, bordered by nuclear fuel facilities at Rokkasho-Village, Aomori, Japan, water samples were collected from 2001 to 2004 at six points in those areas. Concentration ranges of tritium in fresh river water, brackish lake and seawater samples were 0.60 to 1.1 Bq x l -1 (mean value 0.79 Bq x l -1 ), 0.20 to 0.87 Bq x l -1 (mean value 0.41 Bq x l -1 ), and 0.08 to 0.25 Bq x l -1 (mean value 0.15 Bq x l -1 ), respectively. Relationships between tritium concentrations and salinity in the samples showed a clear negative correlation. Moreover, the seasonal variation of tritium in water from Rokkasho-Village was high in spring and low in fall. (author)

Area balance and strain in an extensional fault system: Strategies for improved oil recovery in fractured chalk, Gilbertown Field, southwestern Alabama. Annual report, March 1996--March 1997

Energy Technology Data Exchange (ETDEWEB)

Pashin, J.C.; Raymond, D.E.; Rindsberg, A.K.; Alabi, G.G.; Groshong, R.H.

1997-08-01

Gilbertown Field is the oldest oil field in Alabama and produces oil from chalk of the Upper Cretaceous Selma Group and from sandstone of the Eutaw Formation along the southern margin of the Gilbertown fault system. Most of the field has been in primary recovery since establishment, but production has declined to marginally economic levels. This investigation applies advanced geologic concepts designed to aid implementation of improved recovery programs. The Gilbertown fault system is detached at the base of Jurassic salt. The fault system began forming as a half graben and evolved in to a full graben by the Late Cretaceous. Conventional trapping mechanisms are effective in Eutaw sandstone, whereas oil in Selma chalk is trapped in faults and fault-related fractures. Burial modeling establishes that the subsidence history of the Gilbertown area is typical of extensional basins and includes a major component of sediment loading and compaction. Surface mapping and fracture analysis indicate that faults offset strata as young as Miocene and that joints may be related to regional uplift postdating fault movement. Preliminary balanced structural models of the Gilbertown fault system indicate that synsedimentary growth factors need to be incorporated into the basic equations of area balance to model strain and predict fractures in Selma and Eutaw reservoirs.

Importance of small fishes and invasive crayfish in otter Lutra lutra diet in an English chalk stream

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Britton J. Robert

2017-01-01

Full Text Available The diet composition of the European otter Lutra lutra was assessed using spraint analysis in the Hampshire Avon, a lowland chalk stream in Southern England, over an 18-month period. Small cyprinid fishes were the main prey item taken in all seasons, with bullhead Cottus gobio and stone loach Barbatula barbatula also important; there were relatively few larger fishes of interest to fisheries found. There were significant seasonal differences in diet composition by season, with signal crayfish Pacifastacus leniusculus only being prominent prey items in warmer months and amphibians in winter, revealing that non-fish resources were seasonally important dietary components. Reconstructed body lengths of prey revealed the only species present in diet >350 mm was pike Esox lucius. These dietary data thus provide important information for informing conservation conflicts between otters and fishery interests.

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1996-07-20 to 1996-08-05 (NODC Accession 0115688)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115688 includes biological, chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian...

Quarterly Water Quality Surveys - Salton Sea [ds429

Data.gov (United States)

California Natural Resource Agency — In the spring of 2003, California Department of Fish and Game (CDFG) personnel began quarterly sampling of Salton Sea fish at fourteen stations around the sea, as...

USE OF SEA BUCKTHORN FRUITS IN THE PASTRY MANUFACTURING

Directory of Open Access Journals (Sweden)

RODICA A. STURZA

2016-04-01

Full Text Available Different researches on optimizing the shelf life of pastries (gingerbread, sponge cakes that are produced by adding sea buckthorn flour (2 - 4 % by weight of the flour used are presented in this study. This study shows the impact of biologically active substances on structural and mechanical, physicochemical, microbiological properties as well as the antioxidant activity of products under the conditions of in vitro gastric digestion. It has been demonstrated that the sea buckthorn flour increases the porosity of pastries, reduces the wet gluten amount and this contributes to moisture loss. The organoleptic assessment indicates that the addition of 2 % sea buckthorn flour improves the appearance, the color and the consistency of pastries. Microbiological analysis showed that samples with added sea buckthorn flour exhibit microbiological stability due to the sea buckthorn chemical composition. The antiradical activity DPPH• in conditions of in vitro gastric digestion of the samples with added sea buckthorn flour increases in a positive way, indicating a clearly positive effect on health.

Natural radioactivity of beach sand samples in Port Sudan, red sea state

International Nuclear Information System (INIS)

Kambal, Wala Haider Hussein

2015-01-01

Natural radioactivity is a source of continuous exposure to human beings. In Port Sudan city, the main port of Sudan, data on the levels of natural radioactivity in soil is required. The aim of this study was to measure the activity concentration as well as the absorbed dose and annual effective dose of the naturally occurring radionuclides 238 U, 232 Th, and 40 K in soil samples collected from different locations around Red Sea costa areas in Port Sudan city. Activity concentrations were measured using gamma ray spectrometry (Nal) detector. Results showed that the average activity concentration of 238 U, 232 Th and 40 K were found to be 21.86, 17.55, 85.50 Bqkg 1 , respectively, with an average absorbed dose of 10.42, 9.40 and 3.57 nGyh 1 , respectively. The average annual effective dose values were found to be 11.89, 11.54 and 4.37 μSvy 1 for 238 U, 232 Th and 40 K, respectively. The measured values were comparable with other global radioactivity measurements and found to be safe for public and environment.(Author)

Study of radioactivity among te Bulgarian Black Sea coastal zone - results from the NIMH monitoring program

Energy Technology Data Exchange (ETDEWEB)

Veleva, B.; Kolarova, M.; Mungov, G. [National Institute of Meteorology and Hydrology, Bulgarian Academy of Sciences, Sofia (Bulgaria)

2011-07-01

In the frame of the NIMH at BAS investigations of the Black sea radioactivity were initiated in 1978 with a development of a monitoring campaign. Samples of sea waters, sediments and algae were collected from several sampling sites along the coastal zone and measured by gamma-spectrometry. Results on gamma-emitting radio-nuclide's measurements in the Black sea coastal waters were published in the 80's. After the Chernobyl accident during the period between 1986-1989 seasonal-fields sampling campaigns were organised and radioactivity of algae and bottom sediments was estimated. Harmonized sampling strategies, analytical procedures and related data information exchange for radioactivity of seawater, sediment and biota in coastal areas of Black Sea countries were developed under the IAEA TCP Black Sea Project. The present work reports results of the monitoring programme of the NIMH of Bulgaria developed in the frame of the IAEA projects for the Black Sea basin. From 1993 to 2005 regular seasonal sampling was performed in 5 sampling sites along the Bulgarian Black Sea shore. Results of the dissolved '1'3'7Cs concentrations in sea water, sand, algae, and fish samples are discussed. The data for the different radio-isotopes measured in algae, fish and sea sediment samples are given in comparison with other investigations. A complex assessment of Cs-137 concentrations as important tracer and indicator of the marine processes is made on a long-term basis. (author)

Study of radioactivity among te Bulgarian Black Sea coastal zone - results from the NIMH monitoring program

International Nuclear Information System (INIS)

Veleva, B.; Kolarova, M.; Mungov, G.

2011-01-01

In the frame of the NIMH at BAS investigations of the Black sea radioactivity were initiated in 1978 with a development of a monitoring campaign. Samples of sea waters, sediments and algae were collected from several sampling sites along the coastal zone and measured by gamma-spectrometry. Results on gamma-emitting radio-nuclide's measurements in the Black sea coastal waters were published in the 80's. After the Chernobyl accident during the period between 1986-1989 seasonal-fields sampling campaigns were organised and radioactivity of algae and bottom sediments was estimated. Harmonized sampling strategies, analytical procedures and related data information exchange for radioactivity of seawater, sediment and biota in coastal areas of Black Sea countries were developed under the IAEA TCP Black Sea Project. The present work reports results of the monitoring programme of the NIMH of Bulgaria developed in the frame of the IAEA projects for the Black Sea basin. From 1993 to 2005 regular seasonal sampling was performed in 5 sampling sites along the Bulgarian Black Sea shore. Results of the dissolved '1'3'7Cs concentrations in sea water, sand, algae, and fish samples are discussed. The data for the different radio-isotopes measured in algae, fish and sea sediment samples are given in comparison with other investigations. A complex assessment of Cs-137 concentrations as important tracer and indicator of the marine processes is made on a long-term basis. (author)

Revealing Holobiont Structure and Function of Three Red Sea Deep-Sea Corals

KAUST Repository

Yum, Lauren

2014-12-01

Deep-sea corals have long been regarded as cold-water coral; however a reevaluation of their habitat limitations has been suggested after the discovery of deep-sea coral in the Red Sea where temperatures exceed 20˚C. To gain further insight into the biology of deep-sea corals at these temperatures, the work in this PhD employed a holotranscriptomic approach, looking at coral animal host and bacterial symbiont gene expression in Dendrophyllia sp., Eguchipsammia fistula, and Rhizotrochus sp. sampled from the deep Red Sea. Bacterial community composition was analyzed via amplicon-based 16S surveys and cultured bacterial strains were subjected to bioprospecting in order to gauge the pharmaceutical potential of coralassociated microbes. Coral host transcriptome data suggest that coral can employ mitochondrial hypometabolism, anaerobic glycolysis, and surface cilia to enhance mass transport rates to manage the low oxygen and highly oligotrophic Red Sea waters. In the microbial community associated with these corals, ribokinases and retron-type reverse transcriptases are abundantly expressed. In its first application to deep-sea coral associated microbial communities, 16S-based next-generation sequencing found that a single operational taxonomic unit can comprise the majority of sequence reads and that a large number of low abundance populations are present, which cannot be visualized with first generation sequencing. Bioactivity testing of selected bacterial isolates was surveyed over 100 cytological parameters with high content screening, covering several major organelles and key proteins involved in a variety of signaling cascades. Some of these cytological profiles were similar to those of several reference pharmacologically active compounds, which suggest that the bacteria isolates produce compounds with similar mechanisms of action as the reference compounds. The sum of this work offers several mechanisms by which Red Sea deep-sea corals cope with environmental

Do pelagic grazers benefit from sea ice? Insights from the Antarctic sea ice proxy IPSO25

Directory of Open Access Journals (Sweden)

K. Schmidt

2018-04-01

Full Text Available Sea ice affects primary production in polar regions in multiple ways. It can dampen water column productivity by reducing light or nutrient supply, provide a habitat for ice algae and condition the marginal ice zone (MIZ for phytoplankton blooms on its seasonal retreat. The relative importance of three different carbon sources (sea ice derived, sea ice conditioned, non-sea-ice associated for the polar food web is not well understood, partly due to the lack of methods that enable their unambiguous distinction. Here we analysed two highly branched isoprenoid (HBI biomarkers to trace sea-ice-derived and sea-ice-conditioned carbon in Antarctic krill (Euphausia superba and relate their concentrations to the grazers' body reserves, growth and recruitment. During our sampling in January–February 2003, the proxy for sea ice diatoms (a di-unsaturated HBI termed IPSO25, δ13C  =  −12.5 ± 3.3 ‰ occurred in open waters of the western Scotia Sea, where seasonal ice retreat was slow. In suspended matter from surface waters, IPSO25 was present at a few stations close to the ice edge, but in krill the marker was widespread. Even at stations that had been ice-free for several weeks, IPSO25 was found in krill stomachs, suggesting that they gathered the ice-derived algae from below the upper mixed layer. Peak abundances of the proxy for MIZ diatoms (a tri-unsaturated HBI termed HBI III, δ13C  =  −42.2 ± 2.4 ‰ occurred in regions of fast sea ice retreat and persistent salinity-driven stratification in the eastern Scotia Sea. Krill sampled in the area defined by the ice edge bloom likewise contained high amounts of HBI III. As indicators for the grazer's performance we used the mass–length ratio, size of digestive gland and growth rate for krill, and recruitment for the biomass-dominant calanoid copepods Calanoides acutus and Calanus propinquus. These indices consistently point to blooms in the MIZ as an important feeding

Do pelagic grazers benefit from sea ice? Insights from the Antarctic sea ice proxy IPSO25

Science.gov (United States)

Schmidt, Katrin; Brown, Thomas A.; Belt, Simon T.; Ireland, Louise C.; Taylor, Kyle W. R.; Thorpe, Sally E.; Ward, Peter; Atkinson, Angus

2018-04-01

Sea ice affects primary production in polar regions in multiple ways. It can dampen water column productivity by reducing light or nutrient supply, provide a habitat for ice algae and condition the marginal ice zone (MIZ) for phytoplankton blooms on its seasonal retreat. The relative importance of three different carbon sources (sea ice derived, sea ice conditioned, non-sea-ice associated) for the polar food web is not well understood, partly due to the lack of methods that enable their unambiguous distinction. Here we analysed two highly branched isoprenoid (HBI) biomarkers to trace sea-ice-derived and sea-ice-conditioned carbon in Antarctic krill (Euphausia superba) and relate their concentrations to the grazers' body reserves, growth and recruitment. During our sampling in January-February 2003, the proxy for sea ice diatoms (a di-unsaturated HBI termed IPSO25, δ13C = -12.5 ± 3.3 ‰) occurred in open waters of the western Scotia Sea, where seasonal ice retreat was slow. In suspended matter from surface waters, IPSO25 was present at a few stations close to the ice edge, but in krill the marker was widespread. Even at stations that had been ice-free for several weeks, IPSO25 was found in krill stomachs, suggesting that they gathered the ice-derived algae from below the upper mixed layer. Peak abundances of the proxy for MIZ diatoms (a tri-unsaturated HBI termed HBI III, δ13C = -42.2 ± 2.4 ‰) occurred in regions of fast sea ice retreat and persistent salinity-driven stratification in the eastern Scotia Sea. Krill sampled in the area defined by the ice edge bloom likewise contained high amounts of HBI III. As indicators for the grazer's performance we used the mass-length ratio, size of digestive gland and growth rate for krill, and recruitment for the biomass-dominant calanoid copepods Calanoides acutus and Calanus propinquus. These indices consistently point to blooms in the MIZ as an important feeding ground for pelagic grazers. Even though ice

Arsenic in sediments from the southeastern Baltic Sea

International Nuclear Information System (INIS)

Garnaga, Galina; Wyse, Eric; Azemard, Sabine; Stankevicius, Algirdas; Mora, Stephen de

2006-01-01

Arsenic occurs as a persistent constituent in many of the chemical weapons dumped into the Baltic Sea; it can be used as an indicator of leakage and dispersal of released munitions to the marine environment. Total arsenic was analysed in sediment samples taken from the Lithuanian economic zone in the Baltic Sea, which included samples from the chemical munitions dumpsite in the Gotland Basin and national monitoring stations in the southeastern Baltic Sea. Arsenic concentrations in sediments ranged from 1.1 to 19.0 mg kg -1 , with an average of 3.4 mg kg -1 . Although there was evidence of slightly elevated arsenic content in sediments near the weapons dumpsite, arsenic concentrations were nevertheless quite low relative to other investigations in the Baltic and North Seas. - Arsenic concentrations in sediments near chemical weapons dumpsites were only slightly elevated

Concentration of mercury in wheat samples stored with mercury tablets as preservative

International Nuclear Information System (INIS)

Lalit, B.Y.; Ramachandran, T.V.

1977-01-01

Tablets consisting of mercury in the form of a dull grey powder made by triturating mercury with chalk and sugar are used in Indian household for storing food-grains. The contamination of wheat samples by mercury, when stored with mercury tablets for period of upto four years has been assessed by using non-destructive neutron activation analysis. The details of the analytical procedure used have also been briefly described. The concentration of mercury in wheat increases with storage period. Loss of weight of mercury tablet is proportional to the storage period to a first approximation. In the present experiment, the average weight loss at the and end of first year was 0.009716 g corresponding to 6 ppm in wheat. (T.G.)

The dynamics of biogeographic ranges in the deep sea.

Science.gov (United States)

McClain, Craig R; Hardy, Sarah Mincks

2010-12-07

Anthropogenic disturbances such as fishing, mining, oil drilling, bioprospecting, warming, and acidification in the deep sea are increasing, yet generalities about deep-sea biogeography remain elusive. Owing to the lack of perceived environmental variability and geographical barriers, ranges of deep-sea species were traditionally assumed to be exceedingly large. In contrast, seamount and chemosynthetic habitats with reported high endemicity challenge the broad applicability of a single biogeographic paradigm for the deep sea. New research benefiting from higher resolution sampling, molecular methods and public databases can now more rigorously examine dispersal distances and species ranges on the vast ocean floor. Here, we explore the major outstanding questions in deep-sea biogeography. Based on current evidence, many taxa appear broadly distributed across the deep sea, a pattern replicated in both the abyssal plains and specialized environments such as hydrothermal vents. Cold waters may slow larval metabolism and development augmenting the great intrinsic ability for dispersal among many deep-sea species. Currents, environmental shifts, and topography can prove to be dispersal barriers but are often semipermeable. Evidence of historical events such as points of faunal origin and climatic fluctuations are also evident in contemporary biogeographic ranges. Continued synthetic analysis, database construction, theoretical advancement and field sampling will be required to further refine hypotheses regarding deep-sea biogeography.

PH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from POLARSTERN in the Arctic Ocean, Kara Sea and Laptev Sea from 1995-07-07 to 1995-09-20 (NODC Accession 0116408)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0116408 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean, Kara Sea and Laptev (or...

Revised South China Sea spreading history based on macrostructure analysis of IODP Expedition 349 core samples and geophysical data

Science.gov (United States)

Sun, Z.; Ding, W.; Zhao, X.; Qiu, N.; Lin, J.; Li, C.

2017-12-01

In Internaltional Ocean Discovery Program (IODP) Expedition 349, four sites were drilled and cored successfully in the South China Sea (SCS). Three of them are close to the central spreading ridge (Sites U1431, U1433 and U1434), and one (Site U1435) is located on an outer rise,,providingsignificant information on the spreading history of the SCS.In order to constrain the spreading historymore accurately with the core results, we analyzed the identifiable macrostructures (over 300 fractures, veins and slickensides)from all the consolidated samples of these four drill sites. Then we made a retrograde reconstruction of the SCS spreading history with the constraints of the estimated fractures and veins, post-spreading volcanism,seismic interpretation, as well as free-air gravity and magnetic anomaly and topography analysis. Our study indicates that the spreading of the SCS experienced at least one ridge jump event and two events of ridge orientation and spreading direction adjustment, which mademagnetic anomaly orientation, ridge positionand facture zone directionskeep changing in the South China Sea. During the last spreading stage, the spreading direction was north-southward but lasted for a very short time period. The oceanic crust is wider in the eastern SCS and tapers out toward west.Due to the subductionof SCS beneath the Philippine Sea plate, the seafloor began to develop new fractures:the NWW-to EW-trending R' shear faults and the NE-trending P faultsbecame dominant faults and controlled the eruption of post-drift volcanism.

AECL'S approach to managing long term liabilities at Chalk River Laboratories. Annex II

International Nuclear Information System (INIS)

Audet, M.C.

2006-01-01

Chalk River Laboratories (CRL) is a large nuclear research and development/ industrial site operated by Atomic Energy of Canada Limited (AECL). Construction of the site started in 1944, and it now includes over 100 buildings/facilities operating in various nuclear fields. A well developed decommissioning programme exists at CRL, with progress being made on decommissioning older redundant buildings, in parallel with ongoing site operations and development. The decommissioning programme is predicated on the assumption that the current nuclear operations will continue over a 100 year operating period, but with a decline towards the end of the period. Although decommissioning and remediation work will be carried out throughout the operational period, residual levels of activity remaining in a few areas will require institutional control (IC) for an assumed period of 300 years. The intention is to complete all necessary active remediation work before the start of the IC period and thereafter rely only on passive means to reduce residual contamination to levels that do not require IC measures. The latter include environmental monitoring, active and passive controls to prevent intrusion, and management controls to prohibit access or development. A formal information and records management programme at CRL has been initiated. (author)

Grain-size based sea-level reconstruction in the south Bohai Sea during the past 135 kyr

Science.gov (United States)

Yi, Liang; Chen, Yanping

2013-04-01

Future anthropogenic sea-level rise and its impact on coastal regions is an important issue facing human civilizations. Due to the short nature of the instrumental record of sea-level change, development of proxies for sea-level change prior to the advent of instrumental records is essential to reconstruct long-term background sea-level changes on local, regional and global scales. Two of the most widely used approaches for past sea-level changes are: (1) exploitation of dated geomorphologic features such as coastal sands (e.g. Mauz and Hassler, 2000), salt marsh (e.g. Madsen et al., 2007), terraces (e.g. Chappell et al., 1996), and other coastal sediments (e.g. Zong et al., 2003); and (2) sea-level transfer functions based on faunal assemblages such as testate amoebae (e.g. Charman et al., 2002), foraminifera (e.g. Chappell and Shackleton, 1986; Horton, 1997), and diatoms (e.g. Horton et al., 2006). While a variety of methods has been developed to reconstruct palaeo-changes in sea level, many regions, including the Bohai Sea, China, still lack detailed relative sea-level curves extending back to the Pleistocene (Yi et al., 2012). For example, coral terraces are absent in the Bohai Sea, and the poor preservation of faunal assemblages makes development of a transfer function for a relative sea-level reconstruction unfeasible. In contrast, frequent alternations between transgression and regression has presumably imprinted sea-level change on the grain size distribution of Bohai Sea sediments, which varies from medium silt to coarse sand during the late Quaternary (IOCAS, 1985). Advantages of grainsize-based relative sea-level transfer function approaches are that they require smaller sample sizes, allowing for replication, faster measurement and higher spatial or temporal resolution at a fraction of the cost of detail micro-palaeontological analysis (Yi et al., 2012). Here, we employ numerical methods to partition sediment grain size using a combined database of

Fin whales and microplastics: The Mediterranean Sea and the Sea of Cortez scenarios

International Nuclear Information System (INIS)

Fossi, Maria Cristina; Marsili, Letizia; Baini, Matteo; Giannetti, Matteo; Coppola, Daniele; Guerranti, Cristiana; Caliani, Ilaria; Minutoli, Roberta; Lauriano, Giancarlo; Finoia, Maria Grazia; Rubegni, Fabrizio; Panigada, Simone; Bérubé, Martine; Urbán Ramírez, Jorge; Panti, Cristina

2016-01-01

The impact that microplastics have on baleen whales is a question that remains largely unexplored. This study examined the interaction between free-ranging fin whales (Balaenoptera physalus) and microplastics by comparing populations living in two semi-enclosed basins, the Mediterranean Sea and the Sea of Cortez (Gulf of California, Mexico). The results indicate that a considerable abundance of microplastics and plastic additives exists in the neustonic samples from Pelagos Sanctuary of the Mediterranean Sea, and that pelagic areas containing high densities of microplastics overlap with whale feeding grounds, suggesting that whales are exposed to microplastics during foraging; this was confirmed by the observation of a temporal increase in toxicological stress in whales. Given the abundance of microplastics in the Mediterranean environment, along with the high concentrations of Persistent Bioaccumulative and Toxic (PBT) chemicals, plastic additives and biomarker responses detected in the biopsies of Mediterranean whales as compared to those in whales inhabiting the Sea of Cortez, we believe that exposure to microplastics because of direct ingestion and consumption of contaminated prey poses a major threat to the health of fin whales in the Mediterranean Sea. - Highlights: • Microplastics and phthalates were higher in the Mediterranean Sea than in the Sea of Cortez. • The overlap between the whale feeding areas and high microplastic density shows the risk of interaction. • Data suggest an increasing risk of chemical transfer from microplastic to whales during the foraging. • Mediterranean whales are exposed to higher ecotoxicological threat of than Sea of Cortez whales. - This study identified temporal and regional ecotoxicological variations in free-ranging fin whales inhabiting two seas different characterized by different microplastic abundance.

Transcriptomes and expression profiling of deep-sea corals from the Red Sea provide insight into the biology of azooxanthellate corals.

Science.gov (United States)

Yum, Lauren K; Baumgarten, Sebastian; Röthig, Till; Roder, Cornelia; Roik, Anna; Michell, Craig; Voolstra, Christian R

2017-07-25

Despite the importance of deep-sea corals, our current understanding of their ecology and evolution is limited due to difficulties in sampling and studying deep-sea environments. Moreover, a recent re-evaluation of habitat limitations has been suggested after characterization of deep-sea corals in the Red Sea, where they live at temperatures of above 20 °C at low oxygen concentrations. To gain further insight into the biology of deep-sea corals, we produced reference transcriptomes and studied gene expression of three deep-sea coral species from the Red Sea, i.e. Dendrophyllia sp., Eguchipsammia fistula, and Rhizotrochus typus. Our analyses suggest that deep-sea coral employ mitochondrial hypometabolism and anaerobic glycolysis to manage low oxygen conditions present in the Red Sea. Notably, we found expression of genes related to surface cilia motion that presumably enhance small particle transport rates in the oligotrophic deep-sea environment. This is the first study to characterize transcriptomes and in situ gene expression for deep-sea corals. Our work offers several mechanisms by which deep-sea corals might cope with the distinct environmental conditions present in the Red Sea As such, our data provide direction for future research and further insight to organismal response of deep-sea coral to environmental change and ocean warming.

Transcriptomes and expression profiling of deep-sea corals from the Red Sea provide insight into the biology of azooxanthellate corals

KAUST Repository

Yum, Lauren

2017-07-19

Despite the importance of deep-sea corals, our current understanding of their ecology and evolution is limited due to difficulties in sampling and studying deep-sea environments. Moreover, a recent re-evaluation of habitat limitations has been suggested after characterization of deep-sea corals in the Red Sea, where they live at temperatures of above 20 °C at low oxygen concentrations. To gain further insight into the biology of deep-sea corals, we produced reference transcriptomes and studied gene expression of three deep-sea coral species from the Red Sea, i.e. Dendrophyllia sp., Eguchipsammia fistula, and Rhizotrochus typus. Our analyses suggest that deep-sea coral employ mitochondrial hypometabolism and anaerobic glycolysis to manage low oxygen conditions present in the Red Sea. Notably, we found expression of genes related to surface cilia motion that presumably enhance small particle transport rates in the oligotrophic deep-sea environment. This is the first study to characterize transcriptomes and in situ gene expression for deep-sea corals. Our work offers several mechanisms by which deep-sea corals might cope with the distinct environmental conditions present in the Red Sea As such, our data provide direction for future research and further insight to organismal response of deep-sea coral to environmental change and ocean warming.

Transcriptomes and expression profiling of deep-sea corals from the Red Sea provide insight into the biology of azooxanthellate corals

KAUST Repository

Yum, Lauren; Baumgarten, Sebastian; Rö thig, Till; Roder, Cornelia; Roik, Anna Krystyna; Michell, Craig; Voolstra, Christian R.

2017-01-01

Despite the importance of deep-sea corals, our current understanding of their ecology and evolution is limited due to difficulties in sampling and studying deep-sea environments. Moreover, a recent re-evaluation of habitat limitations has been suggested after characterization of deep-sea corals in the Red Sea, where they live at temperatures of above 20 °C at low oxygen concentrations. To gain further insight into the biology of deep-sea corals, we produced reference transcriptomes and studied gene expression of three deep-sea coral species from the Red Sea, i.e. Dendrophyllia sp., Eguchipsammia fistula, and Rhizotrochus typus. Our analyses suggest that deep-sea coral employ mitochondrial hypometabolism and anaerobic glycolysis to manage low oxygen conditions present in the Red Sea. Notably, we found expression of genes related to surface cilia motion that presumably enhance small particle transport rates in the oligotrophic deep-sea environment. This is the first study to characterize transcriptomes and in situ gene expression for deep-sea corals. Our work offers several mechanisms by which deep-sea corals might cope with the distinct environmental conditions present in the Red Sea As such, our data provide direction for future research and further insight to organismal response of deep-sea coral to environmental change and ocean warming.

Elemental composition of commercial sea cucumbers (holothurians).

Science.gov (United States)

Wen, J; Hu, C

2010-01-01

Toxic and essential elements in 11 different sea cucumber species were determined and compared with daily intake recommendations and maximum allowed levels. The contents of macro-elements contents in dried sea cucumber samples were found to be 25,000-152,000 mg kg(-1) for Na, 4000-8600 mg kg(-1) for Mg, 1100-5200 mg kg(-1) for K, 15,000-68,000 mg kg(-1) and 36,300-251,000 mg kg(-1) for Cl. Trace element concentrations in dried sea cucumber samples were found to be 11-100 mg kg(-1) for Zn, 41-660 mg kg(-1) for Fe, 3-74 mg kg(-1) for Cu, 1.1-16 mg kg(-1) for Mn, 1.4-3.7 mg kg(-1) for Se, 1.1-9.6 mg kg(-1) for Cr, and 0.3-5.1 mg kg(-1) for Ni. All sea cucumber species were rich sources of Na, Cl, Mg, Ca, Fe, Cu, Se and Cr for human consumption. Regarding contaminants, As, Cd and Pb concentrations in dried sea cucumbers were in the ranges of 1.1-6.1, 0.03-0.06 and 0.11-0.69 mg kg(-1), respectively. Moreover, Hg values of 11 sea cucumbers were below the detection limit (0.01 mg kg(-1)).

The biomass of the deep-sea benthopelagic plankton

Science.gov (United States)

Wishner, K. F.

1980-04-01

Deep-sea benthopelagic plankton samples were collected with a specially designed opening-closing net system 10 to 100 m above the bottom in five different oceanic regions at depths from 1000 to 4700 m. Benthopelagic plankton biomasses decrease exponentially with depth. At 1000 m the biomass is about 1% that of the surface zooplankton, at 5000 m about 0.1%. Effects of differences in surface primary productivity on deep-sea plankton biomass are much less than the effect of depth and are detectable only in a few comparisons of extreme oceanic regions. The biomass at 10 m above the bottom is greater than that at 100 m above the bottom (in a three-sample comparison), which could be a consequence of an enriched near-bottom environment. The deep-sea plankton biomass in the Red Sea is anomalously low. This may be due to increased decomposition rates in the warm (22°C) deep Red Sea water, which prevent much detritus from reaching the deep sea. A model of organic carbon utilization in the benthic boundary layer (bottom 100 m), incorporating results from deep-sea sediment trap and respiration studies, indicates that the benthopelagic plankton use only a small amount of the organic carbon flux. A large fraction of the flux is unaccounted for by present estimates of benthic and benthopelagic respiration.

Fin whales and microplastics: The Mediterranean Sea and the Sea of Cortez scenarios.

Science.gov (United States)

Fossi, Maria Cristina; Marsili, Letizia; Baini, Matteo; Giannetti, Matteo; Coppola, Daniele; Guerranti, Cristiana; Caliani, Ilaria; Minutoli, Roberta; Lauriano, Giancarlo; Finoia, Maria Grazia; Rubegni, Fabrizio; Panigada, Simone; Bérubé, Martine; Urbán Ramírez, Jorge; Panti, Cristina

2016-02-01

The impact that microplastics have on baleen whales is a question that remains largely unexplored. This study examined the interaction between free-ranging fin whales (Balaenoptera physalus) and microplastics by comparing populations living in two semi-enclosed basins, the Mediterranean Sea and the Sea of Cortez (Gulf of California, Mexico). The results indicate that a considerable abundance of microplastics and plastic additives exists in the neustonic samples from Pelagos Sanctuary of the Mediterranean Sea, and that pelagic areas containing high densities of microplastics overlap with whale feeding grounds, suggesting that whales are exposed to microplastics during foraging; this was confirmed by the observation of a temporal increase in toxicological stress in whales. Given the abundance of microplastics in the Mediterranean environment, along with the high concentrations of Persistent Bioaccumulative and Toxic (PBT) chemicals, plastic additives and biomarker responses detected in the biopsies of Mediterranean whales as compared to those in whales inhabiting the Sea of Cortez, we believe that exposure to microplastics because of direct ingestion and consumption of contaminated prey poses a major threat to the health of fin whales in the Mediterranean Sea. Copyright © 2015 Elsevier Ltd. All rights reserved.

Phenolic compounds in Ross Sea water

Science.gov (United States)

Zangrando, Roberta; Barbaro, Elena; Gambaro, Andrea; Barbante, Carlo; Corami, Fabiana; Kehrwald, Natalie; Capodaglio, Gabriele

2016-04-01

Phenolic compounds are semi-volatile organic compounds produced during biomass burning and lignin degradation in water. In atmospheric and paleoclimatic ice cores studies, these compounds are used as biomarkers of wood combustion and supply information on the type of combusted biomass. Phenolic compounds are therefore indicators of paleoclimatic interest. Recent studies of Antarctic aerosols highlighted that phenolic compounds in Antarctica are not exclusively attributable to biomass burning but also derive from marine sources. In order to study the marine contribution to aerosols we developed an analytical method to determine the concentration of vanillic acid, vanillin, p-coumaric acid, syringic acid, isovanillic acid, homovanillic acid, syringaldehyde, acetosyringone and acetovanillone present in dissolved and particle phases in Sea Ross waters using HPLC-MS/MS. The analytical method was validated and used to quantify phenolic compounds in 28 sea water samples collected during a 2012 Ross Sea R/V cruise. The observed compounds were vanillic acid, vanillin, acetovanillone and p-coumaric acid with concentrations in the ng/L range. Higher concentrations of analytes were present in the dissolved phase than in the particle phase. Sample concentrations were greatest in the coastal, surficial and less saline Ross Sea waters near Victoria Land.

Diverse deep-sea fungi from the South China Sea and their antimicrobial activity.

Science.gov (United States)

Zhang, Xiao-Yong; Zhang, Yun; Xu, Xin-Ya; Qi, Shu-Hua

2013-11-01

We investigated the diversity of fungal communities in nine different deep-sea sediment samples of the South China Sea by culture-dependent methods followed by analysis of fungal internal transcribed spacer (ITS) sequences. Although 14 out of 27 identified species were reported in a previous study, 13 species were isolated from sediments of deep-sea environments for the first report. Moreover, these ITS sequences of six isolates shared 84-92 % similarity with their closest matches in GenBank, which suggested that they might be novel phylotypes of genera Ajellomyces, Podosordaria, Torula, and Xylaria. The antimicrobial activities of these fungal isolates were explored using a double-layer technique. A relatively high proportion (56 %) of fungal isolates exhibited antimicrobial activity against at least one pathogenic bacterium or fungus among four marine pathogenic microbes (Micrococcus luteus, Pseudoaltermonas piscida, Aspergerillus versicolor, and A. sydowii). Out of these antimicrobial fungi, the genera Arthrinium, Aspergillus, and Penicillium exhibited antibacterial and antifungal activities, while genus Aureobasidium displayed only antibacterial activity, and genera Acremonium, Cladosporium, Geomyces, and Phaeosphaeriopsis displayed only antifungal activity. To our knowledge, this is the first report to investigate the diversity and antimicrobial activity of culturable deep-sea-derived fungi in the South China Sea. These results suggest that diverse deep-sea fungi from the South China Sea are a potential source for antibiotics' discovery and further increase the pool of fungi available for natural bioactive product screening.

Late Holocene sea ice conditions in Herald Canyon, Chukchi Sea

Science.gov (United States)

Pearce, C.; O'Regan, M.; Rattray, J. E.; Hutchinson, D. K.; Cronin, T. M.; Gemery, L.; Barrientos, N.; Coxall, H.; Smittenberg, R.; Semiletov, I. P.; Jakobsson, M.

2017-12-01

Sea ice in the Arctic Ocean has been in steady decline in recent decades and, based on satellite data, the retreat is most pronounced in the Chukchi and Beaufort seas. Historical observations suggest that the recent changes were unprecedented during the last 150 years, but for a longer time perspective, we rely on the geological record. For this study, we analyzed sediment samples from two piston cores from Herald Canyon in the Chukchi Sea, collected during the 2014 SWERUS-C3 Arctic Ocean Expedition. The Herald Canyon is a local depression across the Chukchi Shelf, and acts as one of the main pathways for Pacific Water to the Arctic Ocean after entering through the narrow and shallow Bering Strait. The study site lies at the modern-day seasonal sea ice minimum edge, and is thus an ideal location for the reconstruction of past sea ice variability. Both sediment cores contain late Holocene deposits characterized by high sediment accumulation rates (100-300 cm/kyr). Core 2-PC1 from the shallow canyon flank (57 m water depth) is 8 meter long and extends back to 4200 cal yrs BP, while the upper 3 meters of Core 4-PC1 from the central canyon (120 mwd) cover the last 3000 years. The chronologies of the cores are based on radiocarbon dates and the 3.6 ka Aniakchak CFE II tephra, which is used as an absolute age marker to calculate the marine radiocarbon reservoir age. Analysis of biomarkers for sea ice and surface water productivity indicate stable sea ice conditions throughout the entire late Holocene, ending with an abrupt increase of phytoplankton sterols in the very top of both sediment sequences. The shift is accompanied by a sudden increase in coarse sediments (> 125 µm) and a minor change in δ13Corg. We interpret this transition in the top sediments as a community turnover in primary producers from sea ice to open water biota. Most importantly, our results indicate that the ongoing rapid ice retreat in the Chukchi Sea of recent decades was unprecedented during the

[Principal component analysis and cluster analysis of inorganic elements in sea cucumber Apostichopus japonicus].

Science.gov (United States)

Liu, Xiao-Fang; Xue, Chang-Hu; Wang, Yu-Ming; Li, Zhao-Jie; Xue, Yong; Xu, Jie

2011-11-01

The present study is to investigate the feasibility of multi-elements analysis in determination of the geographical origin of sea cucumber Apostichopus japonicus, and to make choice of the effective tracers in sea cucumber Apostichopus japonicus geographical origin assessment. The content of the elements such as Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Mo, Cd, Hg and Pb in sea cucumber Apostichopus japonicus samples from seven places of geographical origin were determined by means of ICP-MS. The results were used for the development of elements database. Cluster analysis(CA) and principal component analysis (PCA) were applied to differentiate the sea cucumber Apostichopus japonicus geographical origin. Three principal components which accounted for over 89% of the total variance were extracted from the standardized data. The results of Q-type cluster analysis showed that the 26 samples could be clustered reasonably into five groups, the classification results were significantly associated with the marine distribution of the sea cucumber Apostichopus japonicus samples. The CA and PCA were the effective methods for elements analysis of sea cucumber Apostichopus japonicus samples. The content of the mineral elements in sea cucumber Apostichopus japonicus samples was good chemical descriptors for differentiating their geographical origins.

Monitoring of radionuclides in the Baltic Sea in 1989-1990

International Nuclear Information System (INIS)

Ilus, E.; Sjoeblom, K.L.; Ikaeheimonen, T.; Saxen, R.; Klemola, S.

1993-02-01

Monitoring of radioactive substances in the Baltic Sea continued within the framework of the Finnish national monitoring programme. Samples of sea water, bottom sediment and fish were collected for radionuclide analyses. All samples were analysed for gamma-emitting radionuclides and some also for 90 Sr and transuranic elements. The general levelling of Chernobyl derived 137 Cs and 134 Cs in the water mass of the Baltic Sea, which had started soon after the fallout situation, continued in 1989. The activity concentration of 137 Cs was about the same level (120-160 Bq/m 3 ) in surface water throughout the Baltic Sea area except in some coastal areas. The cesium concentrations had levelled vertically as well as horizontally. In 1990, the cesium concentrations of surface water decreased further in other sea areas, but not in the Bothnian Sea, where somewhat higher values were detected once more. In bottom sediments the total amounts of 137 Cs had clearly increased between 1988 and 1990 which indicates that fresh fallout was still settling on the bottom. No increase was found in the total amounts of 239 , 240 Pu. Small amounts of 60 Co were detected in the surface sediment of our sampling station in the Northern Baltic proper. 137 Cs concentrations in Baltic herring ranged from 17 to 32 Bq/kg fresh weight and pike from 22 to 290 Bq/kg fresh weight, the maximum values being in the samples supplied from the Vaasa archipelago. The internal radiation dose received by Finns from eating Baltic Sea fish was 0.01mSv both in 1989 and in 1990. (orig.)

Drivers of abundance and community composition of benthic macroinvertebrates in Ottawa River sediment near Chalk River Laboratories

Energy Technology Data Exchange (ETDEWEB)

Bond, M.J.; Rowan, D.; Silke, R.; Carr, J., E-mail: bondm@aecl.ca [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

2013-12-15

The Ottawa River has received effluent from Chalk River Laboratories (CRL) for more than 60 years. Some radionuclides and contaminants released in effluents are bound rapidly to particles and deposited in bottom sediments where they may be biologically available to benthic invertebrates and other aquatic biota. As part of a larger ecological assessment, we assess the potential impact of contaminated sediments in the vicinity of CRL on local benthic community structure. Using bivariate and multivariate approaches, we demonstrate that CRL operations have had little impact on the local benthic community. Despite elevated anthropogenic radionuclide activity concentrations in sediment near CRL's process outfall, the benthic community is no less abundant or diverse than what is observed upstream at background levels. The Ottawa River benthic invertebrate community is structured predominantly by natural physical and biological conditions in the sediment, specifically sediment water content and organic content. These natural habitat conditions have a stronger influence on macroinvertebrate communities than sediment contamination. (author)

Seasonal signatures in SFG vibrational spectra of the sea surface nanolayer at Boknis Eck Time Series Station (SW Baltic Sea

Directory of Open Access Journals (Sweden)

K. Laß

2013-08-01

Full Text Available The very thin sea surface nanolayer on top of the sea surface microlayer, sometimes just one monomolecular layer thick, forms the interface between ocean and atmosphere. Due to the small dimension and tiny amount of substance, knowledge about the development of the layer in the course of the year is scarce. In this work, the sea surface nanolayer at Boknis Eck Time Series Station (BE, southwestern Baltic Sea, has been investigated over a period of three and a half years. Surface water samples were taken monthly by screen sampling and were analyzed in terms of organic content and composition by sum frequency generation spectroscopy, which is specifically sensitive to interfacial layers. A yearly periodicity has been observed with a pronounced abundance of sea surface nanolayer material (such as carbohydrate-rich material during the summer months. On the basis of our results we conclude that the abundance of organic material in the nanolayer at Boknis Eck is not directly related to phytoplankton abundance alone. We speculate that indeed sloppy feeding of zooplankton together with photochemical and/or microbial processing of organic precursor compounds is responsible for the pronounced seasonality.

Seasonal signatures in SFG vibrational spectra of the sea surface nanolayer at Boknis Eck Time Series Station (SW Baltic Sea)

Science.gov (United States)

Laß, K.; Bange, H. W.; Friedrichs, G.

2013-08-01

The very thin sea surface nanolayer on top of the sea surface microlayer, sometimes just one monomolecular layer thick, forms the interface between ocean and atmosphere. Due to the small dimension and tiny amount of substance, knowledge about the development of the layer in the course of the year is scarce. In this work, the sea surface nanolayer at Boknis Eck Time Series Station (BE), southwestern Baltic Sea, has been investigated over a period of three and a half years. Surface water samples were taken monthly by screen sampling and were analyzed in terms of organic content and composition by sum frequency generation spectroscopy, which is specifically sensitive to interfacial layers. A yearly periodicity has been observed with a pronounced abundance of sea surface nanolayer material (such as carbohydrate-rich material) during the summer months. On the basis of our results we conclude that the abundance of organic material in the nanolayer at Boknis Eck is not directly related to phytoplankton abundance alone. We speculate that indeed sloppy feeding of zooplankton together with photochemical and/or microbial processing of organic precursor compounds is responsible for the pronounced seasonality.

Cyanobacteria toxins in the Salton Sea.

Science.gov (United States)

Carmichael, Wayne W; Li, RenHui

2006-04-19

The Salton Sea (SS) is the largest inland body of water in California: surface area 980 km2, volume 7.3 million acre-feet, 58 km long, 14-22 km wide, maximum depth 15 m. Located in the southeastern Sonoran desert of California, it is 85 m below sea level at its lowest point. It was formed between 1905 and 1907 from heavy river flows of the Colorado River. Since its formation, it has attracted both people and wildlife, including flocks of migratory birds that have made the Salton Sea a critical stopover on the Pacific flyway. Over the past 15 years wintering populations of eared grebe (Podiceps nigricollis) at the Salton Sea, have experienced over 200,000 mortalities. The cause of these large die-offs remains unknown. The unique environmental conditions of the Salton Sea, including salinities from brackish freshwater at river inlets to hypersaline conditions, extreme daily summer temperatures (>38 degrees C), and high nutrient loading from rivers and agricultural drainage favor eutrophic conditions that encourage algal blooms throughout the year. A significant component of these algal blooms are the prokaryotic group - the Cyanophyta or blue-green algae (also called Cyanobacteria). Since many Cyanobacteria produce toxins (the cyanotoxins) it became important to evaluate their presence and to determine if they are a contributing factor in eared-grebe mortalities at the Salton Sea. From November 1999 to April 2001, 247 water and sediment samples were received for phytoplankton identification and cyanotoxin analyses. Immunoassay (ELISA) screening of these samples found that eighty five percent of all water samples contained low but detectable levels of the potent cyclic peptide liver toxin called microcystins. Isolation and identification of cyanobacteria isolates showed that the picoplanktonic Synechococcus and the benthic filamentous Oscillatoria were dominant. Both organisms were found to produce microcystins dominated by microcystin-LR and YR. A laboratory strain

Concentration of mercury in wheat samples stored with mercury tablets as preservative. [Neutrons

Energy Technology Data Exchange (ETDEWEB)

Lalit, B Y; Ramachandran, T V [Bhabha Atomic Research Centre, Bombay (India). Air Monitoring Section

1977-01-01

Tablets consisting of mercury in the form of a dull grey powder made by triturating mercury with chalk and sugar are used in Indian household for storing food-grains. The contamination of wheat samples by mercury, when stored with mercury tablets for period of upto four years has been assessed by using non-destructive neutron activation analysis. The details of the analytical procedure used have also been briefly described. The concentration of mercury in wheat increases with storage period. Loss of weight of mercury tablet is proportional to the storage period to a first approximation. In the present experiment, the average weight loss at the and end of first year was 0.009716 g corresponding to 6 ppm in wheat.

Assessing the sampling strategy in the Northwestern Mediterranean Sea

Science.gov (United States)

Margirier, Félix; Testor, Pierre; Bosse, Anthony; Heslop, Emma; L'Hévéder, Blandine; Arsouze, Thomas; Houpert, Loic; Mortier, Laurent

2017-04-01

The deployment of numerous autonomous platforms (gliders, argo floats, moorings) added to the repeated ship cruises in the Northwestern Mediterranean Sea account for a considerable data coverage of the area through the past 10 years. In this study, we analyse the in-situ observations' ability to assess for the changes in the Northwester Mediterranean basin water masses properties over time. Comparing the observed time series for the different regions and different water masses to that of a glider simulator in the NEMO-Med12 model, we estimate both the quality of the model and the skill of the in-situ observations in reproducing the evolution of the basin properties.

Characterization of the lipid fraction of wild sea urchin from the Sardinian Sea (western Mediterranean).

Science.gov (United States)

Angioni, Alberto; Addis, Pierantonio

2014-02-01

The fatty acid (FA) composition of Spatangus purpureus, Echinus melo, Sphaerechinus granularis, and Paracentrotus lividus, sea urchins, has been studied. Sea urchins were collected at different depth along Sardinia coast in the Mediterranean sea, and their gonad was measured, separated, and analyzed for FA composition by gas chromatography-mass spectrometry. A total of 53 FAs were detected, 16 saturated (SFA), 10 monounsaturated (MUFA), 9 polyunsaturated (PUFA), and 13 highly unsaturated (HUFA). Moreover, 5 furan FAs (FFAs) were revealed for the first time in sea urchin. The HUFA and PUFA classes were the most represented accounting for almost 80% of total FAs. Among these compounds, C20:4 n6 (19.64, 20.52, 23.37, and 8.48 mg/g, respectively) and C22:6 n3 (19.68, 20.05, 3.83, and 1.78 mg/g, respectively) were the most abundant. The results of principal component analysis indicated that the sea urchin samples could be clearly discriminated with respect to their FAs composition. © 2014 Institute of Food Technologists®

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2002-07-18 to 2002-08-21 (NODC Accession 0113953)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113953 includes biological, chemical, discrete sample, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and Bering...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2002-05-05 to 2002-06-15 (NODC Accession 0113952)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113952 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2004-05-15 to 2004-06-23 (NODC Accession 0115592)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115592 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from the NATHANIEL B. PALMER in the Arctic Ocean, Beaufort Sea and Bering Sea from 2003-07-05 to 2003-08-20 (NODC Accession 0116064)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116064 includes biological, chemical, discrete sample, physical and profile data collected from NATHANIEL B. PALMER in the Arctic Ocean, Beaufort Sea...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2004-07-18 to 2004-08-26 (NODC Accession 0115707)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115707 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and...

Tritium behavior on a cultivated plot in the 1994 chronic HT release experiment at Chalk River

International Nuclear Information System (INIS)

Noguchi, H.; Yokoyama, S.; Kinouchi, N.; Murata, M.; Amano, H.; Atarashi, M.; Ichimasa, Y.; Ichimasa, M.

1995-01-01

The behavior of HT and HTO in air and surface soil has been studied extensively in the chronic HT release experiment carried out at Chalk River during the summer of 1994. HTO concentrations in air moisture and soil water collected in a cultivated plot showed similar time-variations, increasing rapidly during the first and second days and becoming gradual after the first 3-4 days. The air HTO concentration decreased during and following rainfall but recovered within a day. The rainfall reduced the HTO concentrations in ridge soil water but little in furrows. Time histories of HTO concentrations in air moisture and soil water suggest that the system was near steady-state within a continuous HT release period of 12 days, in spite of the presence of rain during the period. The air HTO concentrations on clear days showed diurnal cycles that were higher during daytime than at night. The experimental field had a very complex soil regime with respect to HT deposits. The deposits to soil surface varied depending on soil conditions. 12 refs., 5 figs

Pre-operational HTO/HT surveys in the vicinity of the Chalk River Laboratories tritium extraction plant

International Nuclear Information System (INIS)

Workman, W.J.G.; Brown, R.M.

1993-08-01

Surveys of the concentrations of HT and HTO in the atmosphere downwind of the Chalk River Laboratories reactor facilities were carried out in 1986 November, and in 1989 March, April and September under different conditions of air temperature, wind direction, and snow or vegetative cover. HT usually amounted to 1-5% of total tritium, but values up to 20% were observed, probably resulting from preferential removal of HTO. In all of the surveys, the greater persistence in the atmosphere of HT than of HTO was evident. The existing levels of HT are such that they will not be augmented significantly by chronic releases from the Tritium Extraction Plant (TEP) when it comes into operation. Hence, operation of the TEP will not facilitate studies of the environmental behaviour of chronically released HT. However, longer term studies of the distribution of HT from the existing facilities would be worthwhile. Soil and vegetation HTO levels in the study area are reported. Further studies of the distribution of tritium between the air, soil and vegetation in areas subjected to chronic exposure would be valuable

Impact of microstructure evolution on the difference between geometric and reactive surface areas in natural chalk

Science.gov (United States)

Yang, Y.; Bruns, S.; Stipp, S. L. S.; Sørensen, H. O.

2018-05-01

The coupling between flow and mineral dissolution drives the evolution of many natural and engineered flow systems. Pore surface changes as microstructure evolves but this transient behaviour has traditionally been difficult to model. We combined a reactor network model with experimental, greyscale tomography data to establish the morphological grounds for differences among geometric, reactive and apparent surface areas in dissolving chalk. This approach allowed us to study the effects of initial geometry and macroscopic flow rate independently. The simulations showed that geometric surface, which represents a form of local transport heterogeneity, increases in an imposed flow field, even when the porous structure is chemically homogeneous. Hence, the fluid-reaction coupling leads to solid channelisation, which further results in fluid focusing and an increase in geometric surface area. Fluid focusing decreases the area of reactive surface and the residence time of reactant, both contribute to the over-normalisation of reaction rate. In addition, the growing and merging of microchannels, near the fluid entrance, contribute to the macroscopic, fast initial dissolution rate of rocks.

Mortality study of Canadian military personnel exposed to radiation: atomic test blasts and Chalk River nuclear reactor clean-ups, 1950's

International Nuclear Information System (INIS)

Raman, S.; Dulberg, C.S.; Spasoff, R.A.

1984-08-01

This report describes a historical cohort study of the group of Canadian military personnel exposed to radiation in the 1950s at atomic bomb test blasts in the U.S. and Australia, and at clean-up operations at the Chalk River Nuclear Laboratories. Overall and cause-specific mortality in the exposed group was compared to that of the control cohort of unexposed military personnel, matched on age, service, rank and trade. Analyses indicated no elevation in the exposed cohort, in overall or cause-specific mortality due to diseases associated with radiation. Since this study was restricted to an investigation of mortality, we must stress that we cannot generalize these results or conclusions to current morbidity experienced by the exposed cohort

Air-sea gas exchange of HCHs and PCBs and enantiomers of α-HCH in the Kattegat Sea region

International Nuclear Information System (INIS)

Sundqvist, Kristina L.; Wingfors, Haakan; Brorstoem-Lunden, Eva; Wiberg, Karin

2004-01-01

Concentrations and air-water gas exchange of polychlorinated biphenyls (PCBs) and hexachlorocyclohexanes (HCHs) were determined in nine paired air and water samples. The samples were collected monthly in the Kattegat Sea between December 1998 and November 1999. Average fugacity and flux values indicated that PCBs were oversaturated in the water, while HCHs were net deposited. Variations were large over the year, especially during spring and summer. Air parcel back trajectories suggested that air concentrations over the Kattegat Sea are largely dependent of air mass origin. Seasonal trends were detected for airborne HCHs and for PCBs in water. The air and water enantiomeric compositions of α-HCH indicated that a larger portion of α-HCH in air originated from the underlying water during summer than during winter. - Air-water exchange of PCBs and HCHs is studied in the Kattegat Sea and shows to vary seasonally

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 1994-10-29 to 1994-11-23 (NODC Accession 0115681)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115681 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and...

Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from THOMAS G. THOMPSON in the East China Sea, North Pacific Ocean and Philippine Sea from 1985-05-04 to 1985-06-03 (NCEI Accession 0156918)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0156918 includes chemical, discrete sample, physical and profile data collected from THOMAS G. THOMPSON in the East China Sea (Tung Hai), North...

The Skælskør structure in eastern Denmark – wrench-related anticline or primary Late Cretaceous sea-floor topography?

DEFF Research Database (Denmark)

Surlyk, Finn; Boldreel, Lars Ole; Lykke-Andersen, Holger

2010-01-01

seismic studies of the Chalk Group in Øresund and Kattegat have shown that similar highs actually represent topographic highs on the Late Cretaceous – Danian seafloor formed by strong contourparallel bottom currents. Reflection seismic data collected over the Skælskør structure in order to test...... the Ringkøbing Fyn High into the Danish Basin. The elevated position is maintained due to reduced subsidence as compared with the Danish Basin north of the high. The hypothesis of wrench tectonics as origin can be refuted. The seismic data show that the upper part of the Chalk Group is characterised by irregular...

Application of PIXE analysis to environmental samples stable element distribution in sea algae by scanning microprobe analysis

International Nuclear Information System (INIS)

Ishikawa, M.; Kitao, K.; Imaseki, H.; Ishii, T.; Uchida, S.

1984-01-01

The resolution of a 33+-3 μm microprobe focussed with quadrupole doublet installed at the 3 MV Van de Graaff of the National Institute of Radiological Sciences, Japan, was used for the present analysis. Brown algae, Hizikia fusiforme was the sample target bombarded with a 2 MeV proton beam collimated mechanically into a rectangular image of 100 μm x 700 μm. Scanning across the sample target prepared into a longitudinal section from the caulis of the algae provided the following observations. More than 12 elements such as Al, Si, P, Cl, Ca, Mn, Fe, Cu, Zn, As, Br and Sr were determined simultaneously, together with their distributional information across the diameter. In the medullary layer, Mn and Zn were specific in their accumulation, while the deposition of Fe, Cu, As and Br were observed to be high in the epithelial layer, especially Fe and Cu which were found on the surface, where they contacted ambient sea water, but no significant change in pattern was indicated for such elements as Al, P and Cl. The PIXE microprobe analysis was, therefore, effective in its detectability for elements below a few ppm level, resultantly providing further possibilities for collecting information from bio-medical and environmental samples on trace characterization of elements. (author)

Sea level trends in Southeast Asian seas

Science.gov (United States)

Strassburg, M. W.; Hamlington, B. D.; Leben, R. R.; Manurung, P.; Lumban Gaol, J.; Nababan, B.; Vignudelli, S.; Kim, K.-Y.

2015-05-01

Southeast Asian seas span the largest archipelago in the global ocean and provide a complex oceanic pathway connecting the Pacific and Indian oceans. The Southeast Asian sea regional sea level trends are some of the highest observed in the modern satellite altimeter record that now spans almost 2 decades. Initial comparisons of global sea level reconstructions find that 17-year sea level trends over the past 60 years exhibit good agreement with decadal variability associated with the Pacific Decadal Oscillation and related fluctuations of trade winds in the region. The Southeast Asian sea region exhibits sea level trends that vary dramatically over the studied time period. This historical variation suggests that the strong regional sea level trends observed during the modern satellite altimeter record will abate as trade winds fluctuate on decadal and longer timescales. Furthermore, after removing the contribution of the Pacific Decadal Oscillation (PDO) to sea level trends in the past 20 years, the rate of sea level rise is greatly reduced in the Southeast Asian sea region. As a result of the influence of the PDO, the Southeast Asian sea regional sea level trends during the 2010s and 2020s are likely to be less than the global mean sea level (GMSL) trend if the observed oscillations in wind forcing and sea level persist. Nevertheless, long-term sea level trends in the Southeast Asian seas will continue to be affected by GMSL rise occurring now and in the future.

Southern Dobrogea coastal potable water sources and Upper Quaternary Black Sea level changes

Science.gov (United States)

Caraivan, Glicherie; Stefanescu, Diana

2013-04-01

Southern Dobrogea is a typical geologic platform unit, placed in the south-eastern part of Romania, with a Pre-Cambrian crystalline basement and a Paleozoic - Quaternary sedimentary cover. It is bordered to the north by the Capidava - Ovidiu fault and by the Black Sea to the east. A regional WNW - ESE and NNE - SSW fault system divides the Southern Dobrogea structure in several tectonic blocks. Four drinking water sources have been identified: surface water, phreatic water, medium depth Sarmatian aquifer, and deep Upper Jurassic - Lower Cretaceous aquifer. Surface water sources are represented by several springs emerged from the base of the loess cliff, and a few small rivers, barred by coastal beaches. The phreatic aquifer develops at the base of the loess deposits, on the impervious red clay, overlapping the Sarmatian limestones. The medium depth aquifer is located in the altered and karstified Sarmatian limestones, and discharges into the Black Sea. The Sarmatian aquifer is unconfined where covered by silty loess deposits, and locally confined, where capped by clayey loess deposits. The aquifer is supplied from the Pre-Balkan Plateau. The Deep Upper Jurassic - Lower Cretaceous aquifer, located in the limestone and dolomite deposits, is generally confined and affected by the regional WNW - ESE and NNE - SSW fault system. In the south-eastern Dobrogea, the deep aquifer complex is separated from the Sarmatian aquifer by a Senonian aquitard (chalk and marls). The natural boundary of the Upper Jurassic - Lower Cretaceous aquifer is the Capidava - Ovidiu Fault. The piezometric heads show that the Upper Jurassic - Lower Cretaceous aquifer is supplied from the Bulgarian territory, where the Upper Jurassic deposits crop out. The aquifer discharges into the Black Sea to the east and into Lake Siutghiol to the northeast. The cyclic Upper Quaternary climate changes induced drastic remodeling of the Black Sea level and the corresponding shorelines. During the Last Glacial

Using high sampling rate (10/20 Hz) altimeter data for the observation of coastal surface currents: A case study over the northwestern Mediterranean Sea

Science.gov (United States)

Birol, Florence; Delebecque, Caroline

2014-01-01

Satellite altimetry, measuring sea surface heights (SSHs), has unique capabilities to provide information about the ocean dynamics. In this paper, the skill of the original full rate (10/20 Hz) measurements, relative to conventional 1-Hz data, is evaluated in the context of coastal studies in the Northwestern Mediterranean Sea. The performance and the question of the measurement noise are quantified through a comparison with different tide gauge sea level time series. By applying a specific processing, closer than 30 km to the land, the number of valid data is higher for the 10/20-Hz than for the 1-Hz observations: + 4.5% for T/P, + 10.3 for Jason-1 and + 13% for Jason-2. By filtering higher sampling rate measurements (using a 30-km cut-off low-pass Lanczos filter), we can obtain the same level of sea level accuracy as we would using the classical 1-Hz altimeter data. The gain in near-shore data results in a better observation of the Liguro-Provençal-Catalan Current. The seasonal evolution of the currents derived from 20-Hz data is globally consistent with patterns derived from the corresponding 1-Hz observations. But the use of higher frequency altimeter measurements allows us to observe the variability of the regional flow closer to the coast (~ 10-15 km from land).

Studies on determination of stable elements in sea water and organisms

International Nuclear Information System (INIS)

Anon.

1974-01-01

The existing conditions of stable elements including Co, Zn, Cs, Ce and Eu in sea water were determined by adding radioactive tracers, and determination methods were discussed. 60 Co added to sea water revealed to be kept in solution in 93 per cent of non-filtrated sea water, and in 98 per cent of filtrated sea water. 65 Zn also added to sea water showed to be kept in solution in 97 per cent of both non-filtrated and filtrated sea water. Both elements seemed to exist as particle or ion smaller than 0.45 μ, which solved in sea water. On the other hand, in both Ce and Eu of rare earth elements, about 80 per cent of them presented in the residue, but the treatment of sea water by hydrochroric acid solubilized 80 to 90 per cent of them in filtrated sea water. One of the instrumental analysis, irradiation analysis by nuclear reactor, was applied: each of preconcentration procedure by ion exchange method for Co and Zn in sea water and drying up sample marine organisms to ash content combined with irradiation analysis. Chemical recovery of both 60 Co and 65 Zn in sea water by preconcentration procedure reached more than 95 per cent. As to marine organisms, Co, Zn, and Cs could be determined with only 100 to 200 mg. of ash content obtained from sample marine organisms showing 80 per cent of chemical yield of the carrier through whole the procedure of analysis in almost all the samples. The chemical recovery of Ce and Eu in sea water and marine organisms by the preconcentration procedure reached about 85 per cent, and chemical yield through whole the procedure of analysis was more than 60 per cent. Concentration factor of Co and Zn in fishes and shells, especially that of muscles, obtained by stable elements determination method was almost 10 times that by RI tracer method. The difference of chemical forms between RI tracer and stable isotope affected not only to physiological metabolism but also to food chains. (Kanao, K.)

Spectroscopic studies of humic acids from subsurface sediment samples collected across the Aegean Sea

Directory of Open Access Journals (Sweden)

F. SAKELLARIADOU

2006-12-01

Full Text Available Natural humic acids are biogenic, structurally complex and heterogeneous, refractory, acidic, yellow-to black-coloured organic polyelectrolytes of relatively high molecular weight. They occur in all soils, sediments, fresh waters, and seawaters. Humic acids represent the largest portion of nonliving soil organic matter. In the present paper, humic substances were isolated from marine subsurface sediment samples collected across the Aegean sea (in Greece and especially from a marine area extending northwards of the Samothraki plateau towards the north-eastern part of the island of Crete. In a following step, humic preparations were studied using infrared and fluorescence spectroscopy (emission, excitation and synchronous-scan excitation spectra were obtained. The infrared spectra suggested functional chemical groups such as as OH-, C-H aliphatic, C=C, C=O/COO-, salts of carboxylic acids, and also, in some cases, silicate anions or C-O from alcohols, esters and ethers. Fluorescence emission, excitation and synchronous scan excitation provided some valuable information concerning a probable origin (marine and/or terrestrial for the isolated humics.

Illicit drugs and their metabolites in 36 rivers that drain into the Bohai Sea and north Yellow Sea, north China.

Science.gov (United States)

Wang, De-Gao; Zheng, Qiu-Da; Wang, Xiao-Ping; Du, Juan; Tian, Chong-Guo; Wang, Zhuang; Ge, Lin-Ke

2016-08-01

Illicit drugs and their metabolites have recently been recognized as an emerging group of contaminants due to their potential ecotoxicological impact in aquatic ecosystems. To date, information on the occurrence of these compounds in the aquatic environment of China remains limited. In this study, we collected surface water samples from 36 rivers in north China that discharge into the Bohai Sea and north Yellow Sea and measured the concentrations of amphetamine-like compounds, ketamines, cocainics, and opioids. The occurrence and spatial patterns of these substances show significant differences between the rivers and regions. Two designer drugs, methamphetamine (METH) and ketamine (KET), were the most abundant compounds detected in the entire set of samples (detection frequency of 92 and 69 %). The concentrations of METH and KET ranged from illicit drugs consumed in China. The high concentrations of these illicit drugs and their metabolites were found in areas that have a high population density. The riverine input of total illicit drugs into the Bohai Sea and north Yellow Sea was estimated to be in the range of 684 to 1160 kg per year.

Three-dimensional temperature fields of the North Patagonian Sea recorded by Magellanic penguins as biological sampling platforms

Science.gov (United States)

Sala, Juan E.; Pisoni, Juan P.; Quintana, Flavio

2017-04-01

Temperature is a primary determinant of biogeographic patterns and ecosystem processes. Standard techniques to study the ocean temperature in situ are, however, particularly limited by their time and spatial coverage, problems which might be partially mitigated by using marine top predators as biological platforms for oceanographic sampling. We used small archival tags deployed on 33 Magellanic penguins (Spheniscus magellanicus), and obtained 21,070 geo-localized profiles of water temperature, during late spring of 2008, 2011, 2012 and 2013; in a region of the North Patagonian Sea with limited oceanographic records in situ. We compared our in situ data of sea surface temperature (SST) with those available from satellite remote sensing; to describe the three-dimensional temperature fields around the area of influence of two important tidal frontal systems; and to study the inter-annual variation in the three-dimensional temperature fields. There was a strong positive relationship between satellite- and animal-derived SST data although there was an overestimation by remote-sensing by a maximum difference of +2 °C. Little inter-annual variability in the 3-dimensional temperature fields was found, with the exception of 2012 (and to a lesser extent in 2013) where the SST was significantly higher. In 2013, we found weak stratification in a region which was unexpected. In addition, during the same year, a warm small-scale vortex is indicated by the animal-derived temperature data. This allowed us to describe and better understand the dynamics of the water masses, which, so far, have been mainly studied by remote sensors and numerical models. Our results highlight again the potential of using marine top predators as biological platforms to collect oceanographic data, which will enhance and accelerate studies on the Southwest Atlantic Ocean. In a changing world, threatened by climate change, it is urgent to fill information gaps on the coupled ocean-atmosphere system

Comparative metagenomics of the Red Sea

KAUST Repository

Mineta, Katsuhiko

2016-01-26

Metagenome produces a tremendous amount of data that comes from the organisms living in the environments. This big data enables us to examine not only microbial genes but also the community structure, interaction and adaptation mechanisms at the specific location and condition. The Red Sea has several unique characteristics such as high salinity, high temperature and low nutrition. These features must contribute to form the unique microbial community during the evolutionary process. Since 2014, we started monthly samplings of the metagenomes in the Red Sea under KAUST-CCF project. In collaboration with Kitasato University, we also collected the metagenome data from the ocean in Japan, which shows contrasting features to the Red Sea. Therefore, the comparative metagenomics of those data provides a comprehensive view of the Red Sea microbes, leading to identify key microbes, genes and networks related to those environmental differences.

Optimization of sample preparation and chromatography for the determination of perfluoroalkyl acids in sediments from the Yangtze Estuary and East China Sea.

Science.gov (United States)

Wang, Qian-Wen; Yang, Gui-Peng; Zhang, Ze-Ming; Zhang, Jing

2018-08-01

Perfluoroalkyl acids (PFAAs) are ubiquitous pollutants present in various environmental media, including marine sediments. A method was proposed for the determination of 17 target PFAA analytes in marine sediment samples (n = 49) collected from the Yangtze Estuary and East China Sea. The proposed method involves the use of an optimized pretreatment procedure and ultrahigh-performance liquid chromatography electrospray ionization-tandem mass spectrometry in dynamic multiple reaction monitoring mode. The method relied on extraction cycles using methanol followed by concentration, filtration, and small volume injection to UHPLC-MS/MS. The recovery, time efficiency, and detection limit of the proposed method are improved relative to those of traditional methods. Limits of detection varied from 0.003 to 0.045 ng/g, and spike recoveries to sediment ranged from 90% to 110% with suitable precisions (1.7%-14.6%). PFAAs were widely present in the samples, and ΣPFAAs ranged from 0.67 ng/g dw to 36.75 ng/g dw. Results indicated that terrigenous input strongly influences PFAA distribution in sediments from the study areas. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) were identified as the dominant perfluorocarboxylic acid (PFCA) and perfluoroalkylsulfonate (PFSA) in sediment samples from the Yangtze Estuary and the East China Sea. Preliminary environmental risk assessment indicated that PFOS may pose a higher environmental risk than PFOA. Furthermore, risk quotient values indicated that PFOS poses a significant risk to the aquatic ecosystem of the study areas. Copyright © 2018 Elsevier Ltd. All rights reserved.

How Much Are Floridians Willing to Pay for Protecting Sea Turtles from Sea Level Rise?

Science.gov (United States)

Hamed, Ahmed; Madani, Kaveh; Von Holle, Betsy; Wright, James; Milon, J Walter; Bossick, Matthew

2016-01-01

Sea level rise (SLR) is posing a great inundation risk to coastal areas. Some coastal nesting species, including sea turtle species, have experienced diminished habitat from SLR. Contingent valuation method (CVM) was used in an effort to assess the economic loss impacts of SLR on sea turtle nesting habitats for Florida coasts; and to elicit values of willingness to pay (WTP) of Central Florida residents to implement certain mitigation strategies, which would protect Florida's east coast sea turtle nesting areas. Using the open-ended and dichotomous choice CVM, we sampled residents of two Florida communities: Cocoa Beach and Oviedo. We estimated the WTP of households from these two cities to protect sea turtle habitat to be between $42 and $57 per year for 5 years. Additionally, we attempted to assess the impact of the both the respondents' demographics and their perception toward various situations on their WTP value. Findings include a negative correlation between the age of a respondent and the probability of an individual willing to pay the hypothetical WTP amount. We found that WTP of an individual was not dependent on prior knowledge of the effects of SLR on sea turtle habitat. The greatest indicators of whether or not an individual was willing to pay to protect sea turtle habitat were the respondents' perception regarding the trustworthiness and efficiency of the party which will implement the conservation measures and their confidence in the conservation methods used. Respondents who perceive sea turtles having an effect on their life were also more likely to pay.

Radioactivity contamination of the Russian Arctic Seas

Energy Technology Data Exchange (ETDEWEB)

Rissanen, K. [STUK Radiation and Nuclear Safety Authority, Rovaniemi (Finland); Ikaeheimonen, T.K. [STUK Radiation and Nuclear Safety Authority, Helsinki (Finland); Matishov, D.; Matishov, G.G. [Murmansk Marine Biological Inst., Murmansk (Russian Federation)

2001-04-01

The levels of the anthropogenic radionuclides in the Russian Arctic Seas are low compared to the potential sources of pollution and originata mainly from the global fallout, Chernobyl fallout and from the western nuclear fuel reprocessing plants. Fresh release of radioactivity was noticed in this study only in the Kola Bay and in two sampling locations in the White Sea. The increased {sup 137}Cs concentrations measured in the estuaries of River Dvina and River Yenisey are caused by the riverine transport from the large catchment area. The sediments of the Russian Arctic Seas are hard. Good and enough long cores for sedimentation rate determination were obtained only in two locations in the White Sea. All the cores from river estuaries were badly mixed. (EHS)

Surfactant control of air-sea gas exchange from North Sea coastal waters and the Atlantic Meridional Transect

Science.gov (United States)

Pereira, R.

2016-02-01

Suppression of gas transfer velocity (kw) by surfactants are well established, both in laboratory wind flumes and purposeful oceanic releases. However, the effects on kw of time and space varying concentrations of natural surfactant are inadequately studied. We have developed an automated gas exchange tank for simultaneous high precision measurement of kw in unmodified seawater samples. Here we present data from two studies along a coastal North Sea transect during 2012-2013 and the Atlantic Meridional Transect (AMT) 24 from September to November 2014. Measurements of surfactant activity (SA), CDOM absorbance and chlorophyll-a have enabled us to characterize the effects of variable amounts of natural surfactant on kw. North Sea coastal waters range in k660 (kw normalized to the value for CO2 in freshwater at 20oC) was 6.8-24.5 cm hr-1 (n=20), with the ranges of SA, total CDOM absorbance (200-450 nm) and chlorophyll-a measured in the surface microlayer (SML) of our seawater samples were 0.08-0.38 mg l-1 T-X-100, 0.13-4.7 and 0.09-1.54 µg l-1, respectively. The AMT k660 ranged from 7.0-23.9 cm hr-1 (n=22), with SA measured in the SML and subsurface water (SSW) of our seawater samples ranging from 0.15-1.08 mg l-1 T-X-100 and 0.07-0.43 mg l-1 T-X-100, respectively. Importantly, we found 12-45% (North Sea) and 1-43% (AMT) k660 suppression relative to Milli-Q water that relate to seasonal and spatial differences in SA. The North Sea demonstrated notable seasonal influences on k660 suppression that were related to CDOM absorbance and chlorophyll-a. The degree of k660 suppression was highest in summer consistent with k660 control by natural surfactant. The degree of k660 suppression decreased with distance offshore in the North Sea and displayed a strong relationship with SA (r2 = 0.51-0.64, p = 0.02, n = 20). The AMT demonstrated notable differences in k660 suppression between hemispheres and across the Longhurst Provinces but the overall relationship between k660

Accumulation and maternal transfer of polychlorinated biphenyls in Steller Sea Lions (Eumetopias jubatus) from Prince William Sound and the Bering Sea, Alaska

International Nuclear Information System (INIS)

Wang Jun; Huelck, Kathrin; Hong, Su-Myeong; Atkinson, Shannon; Li, Qing X.

2011-01-01

The western stock of the Steller sea lion (Eumetopias jubatus) in the northern Pacific Ocean has declined by approximately 80% over the past 30 years. This led to the listing of this sea lion population as an endangered species in 1997. Chemical pollution is a one of several contributing causes. In the present study, 145 individual PCBs were determined in tissues of male sea lions from Tatitlek (Prince William Sound) and St. Paul Island (Bering Sea), and placentae from the Aleutian Islands. PCBs 90/101, 118, and 153 were abundant in all the samples. The mean toxic equivalents (TEQ) were 2.6, 4.7 and 7.4 pg/g lw in the kidney, liver, and blubber samples, respectively. The mean TEQ in placentae was 8 pg/g lw. Total PCBs concentrations (2.6-7.9 μg/g lw) in livers of some males were within a range known to cause physiological effects. Further suggesting the possibility of adverse effects on this stock. - PCBs at median concentrations of 1.2-3.7 μg/g lipid weight in different tissues of the western stock of Steller sea lions have physiological effects.

Occurrence of organohalogens at the Dead Sea Basin

Science.gov (United States)

Tubbesing, Christoph; Kotte, Karsten; Keppler, Frank; Krause, Torsten; Bahlmann, Enno; Schöler, Heinfried

2013-04-01

Most arid and semi-arid regions are characterized by evaporites, which are assured sources for volatile organohalogens (VOX) [1]. These compounds play an important role in tropospheric and stratospheric chemistry. The Dead Sea between Israel and Jordan is the world's most famous and biggest all-season water covered salt lake. In both countries chemical plants like the Dead Sea Works and the Arab Potash Company are located at the southern part of the Dead Sea and mine various elements such as bromine and magnesium. Conveying sea water through constructed evaporation pans multifarious salts are enriched and precipitated. In contrast, the Northern basin and main part of the Dead Sea has remained almost untouched by industrial salt production. Its fresh water supply from the Jordan River is constantly decreasing, leading to further increased salinity. During a HALOPROC campaign (Natural Halogenation Processes in the Environment) we collected various samples including air, soils, sediments, halophytic plants, ground- and seawater from the Northern and Southern basin of the Israeli side of the Dead Sea. These samples were investigated for the occurrence of halocarbons using different analytical techniques. Most samples were analyzed for volatile organohalogens such as haloalkanes using gas chromatography- mass spectrometry (GC-MS). Interestingly, there is a strong enrichment of trihalomethanes (THM), especially all chlorinated and brominated ones and also the iodinated compound dichloroiodomethane were found in the Southern basin. In addition, volatile organic carbons (VOC) such as ethene and some other alkenes were analyzed by a gas chromatography-flame ionisation detector (GC-FID) to obtain further information about potential precursors of halogenated compounds. Halophytic plants were investigated for their potential to release chloromethane and bromomethane but also for their stable carbon and hydrogen isotope composition. For this purpose, a plant chamber was

Ammonia and ammonium over the southern Baltic Sea. Part 1. Preparation of aerosol and air samples for the determination of ammonia by the indophenol method

Directory of Open Access Journals (Sweden)

Lucyna Falkowska

2004-06-01

Full Text Available 1997 saw the start of a study into the spatial and temporal changes in the chemical composition of the atmosphere over the littoral and offshore waters of the Baltic Sea. Collection of samples and their subsequent chemical analysis was preceded by meticulous laboratory experiments concerning the validation and adaptation of the analytical procedures. The colorimetric indophenol blue technique was used to analyse the aerosol samples for the concentration of ammonium ions and the air samples for their gaseous ammonia. The samples were collected with PTFE-filters and Whatman 41 filters coated with 5% orthophosphoric acid. This acid enhances the aerosol sampling efficacy but reduces the pH of the reaction in which indophenol is formed. The pH of the aerosol samples thus had to be raised, and this in turn required an alteration to the original procedure prior to ammonia determination. It was demonstrated that the addition of 0.1 N KOH to the filters coated with H3PO4 increases the pH of the reaction medium to the required level of pH = 8-11.5 and does not substantially influence the precision of the determination; the error of the modified procedure was of the order of 5.2%.      Air samples for the determination of gaseous ammonia were collected with annular denuders. Oxalic acid and citric acid are the usual impregnating agents. In the present experiments oxalic acid was used for denuder impregnation; it turned out to be more effective than citric acid under the conditions of the southern Baltic Sea.      The detection limit of the indophenol blue method in these laboratory experiments was 0.045 mmol dm-3. The respective relative standard deviations (RSD within the range of higher and lower concentrations were 0.64% and 4.53%.

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HUDSON in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 1982-02-28 to 1982-04-04 (NODC Accession 0113889)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113889 includes chemical, discrete sample, physical and profile data collected from HUDSON in the North Atlantic Ocean, North Greenland Sea and...

Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the POLARSTERN in the Arctic Ocean, Kara Sea and Laptev (or Nordenskjold) Sea from 1993-08-06 to 1993-10-05 (NODC Accession 0113593)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113593 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean, Kara Sea and Laptev (or...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the AKADEMIK FYODOROV in the East Siberia Sea and Laptev (or Nordenskjold) Sea from 1994-07-05 to 1994-08-08 (NODC Accession 0113884)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113884 includes chemical, discrete sample, physical and profile data collected from AKADEMIK FYODOROV in the East Siberia Sea and Laptev (or...

Change of MMP dependent on temperature

DEFF Research Database (Denmark)

Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen; Akwansa, Eugene

2008-01-01

   The experiment was conducted with the purpose to investigate how Minimum Miscibility Pressure (MMP) changes at different temperatures. MMP was measured in a high pressure unit. An original oil saturated chalk core plug from the Danish oil field in North Sea was under investigation. The plug...... underestimation of MMP values which can lead to the loss of efficiency of oil extraction....

A success story of regional projects implemented for the management of marine environment. Turkish experience related to the black sea and the mediterranean sea

International Nuclear Information System (INIS)

Goktepe, B.G.; Gungor, N.; Gungor, E.; Karakelle, B.

2004-01-01

Full text: A wide scope Regional Technical Co-operation Project RER/2/003 'Marine Environmental Assessment of the Black Sea Region' is implemented by the International Atomic Energy Agency (IAEA) in the period 1995-2001. This project was initiated in response to the needs of participating Member States - the six Black Sea coastal countries (Bulgaria, Romania, Ukraine, Russian Federation, Georgia and Turkey) to establish capabilities for reliably assessing radionuclides in the Black Sea environment and applying tracer techniques to marine pollution studies The project has various important aspects: Scientifically; one of the major environmental issue radioactivity pollution is addressed. Technically; laboratory capability for transuranic analysis is being developed. Economically; the reversing the ecological deterioration and developing sustainable uses of the Black Sea and its natural resources is one of the major interests. Politically; responsibility of pollution control and rehabilitation plans of six Black Sea countries are addressed through various convention and declarations. Socio-economically, fisheries and tourism sectors are expected to benefit. Highlights from the joint radioactivity-monitoring program of the project among six Black Sea countries are outlined. Examples from the Turkish monitoring work consist of the routine sampling of seawater, algae, mussels, fish samples and beach sand from the selected stations along the Black Sea coast are presented for illustration. The success of the Black Sea regional project has given rise to a new regional project 'Marine Environmental Assessment of the Mediterranean Region' based on the request of the member countries, which will be initiated in 2005 by the IAEA. The initial phase the project, its objectives and the schedule will be summarized. Key words: marine radioactivity, environmental management, Black Sea, Mediterranean Sea, regional cooperation

Nematode assemblages in the deep-sea benthos of the Norwegian Sea

Science.gov (United States)

Jensen, Preben

1988-07-01

The deep-sea benthos of the Norwegian Sea contains 20-204 nematodes per 10 cm 2 down to 3 cm depth at seven stations sampled between 970 and 3294 m water depth. The majority of nematodes occur in the uppermost cm. Biomass varies from 3 to 73 μg C per 10 cm 2. Individual adult weight of the most dominant species differs by a factor of almost 1000, i.e. from 3-4 ng C to 3400 ng C; however, the majority of the nematodes is small-sized. Species diversity and evenness are high at all stations and each station harbours its specific fauna with little overlap between stations. Analysis of trophic group composition suggests that microbial feeding types (deposit and epistrate feeders) prevail in the deep-sea benthos; predators and scavengers are scarce. It is concluded that the nematode assemblage at each station consists of a mosaic of many microhabitats. The small nematode body weight probably results from limited food supply and/or poor food quality.

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JAN MAYEN in the Arctic Ocean, Barents Sea and North Greenland Sea from 2005-05-20 to 2005-06-02 (NODC Accession 0113564)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113564 includes chemical, discrete sample, physical and profile data collected from JAN MAYEN in the Arctic Ocean, Barents Sea and North Greenland...

Sea Cucumber Resources At Tanjung Pai Waters Padaido Biak Numfor Papua

Directory of Open Access Journals (Sweden)

Eddy Yusron

2004-12-01

Full Text Available Observation on sea cucumber diversity was carried out at coastal waters of Pai and Imbeyomi Islands in the Padaido Island Biak Numfor. Sampling was done by using a transect quadrant of 1 m x 1 m. This sampling and observation on its microhabitat were conducted by snorkling. Analyses on the sea cucumber community structure were based on its frequency of occurance, diversity, and density. The results showed that at both locations 10 species of sea cucumber were found where Holothuria edulis, H. atra, and H. nobilis were predominant common and more evenly distributed than the other species.

Bacterial communities from Arctic seasonal sea ice are more compositionally variable than those from multi-year sea ice.

Science.gov (United States)

Hatam, Ido; Lange, Benjamin; Beckers, Justin; Haas, Christian; Lanoil, Brian

2016-10-01

Arctic sea ice can be classified into two types: seasonal ice (first-year ice, FYI) and multi-year ice (MYI). Despite striking differences in the physical and chemical characteristics of FYI and MYI, and the key role sea ice bacteria play in biogeochemical cycles of the Arctic Ocean, there are a limited number of studies comparing the bacterial communities from these two ice types. Here, we compare the membership and composition of bacterial communities from FYI and MYI sampled north of Ellesmere Island, Canada. Our results show that communities from both ice types were dominated by similar class-level phylogenetic groups. However, at the operational taxonomic unit (OTU) level, communities from MYI and FYI differed in both membership and composition. Communities from MYI sites had consistent structure, with similar membership (presence/absence) and composition (OTU abundance) independent of location and year of sample. By contrast, communities from FYI were more variable. Although FYI bacterial communities from different locations and different years shared similar membership, they varied significantly in composition. Should these findings apply to sea ice across the Arctic, we predict increased compositional variability in sea ice bacterial communities resulting from the ongoing transition from predominantly MYI to FYI, which may impact nutrient dynamics in the Arctic Ocean.

First evaluation of neustonic microplastics in Black Sea waters.

Science.gov (United States)

Aytan, Ulgen; Valente, Andre; Senturk, Yasemen; Usta, Riza; Esensoy Sahin, Fatma Basak; Mazlum, Rahsan Evren; Agirbas, Ertugrul

2016-08-01

The Black Sea has a high risk of plastic pollution given the high river discharge of several industrialized countries into this semi-enclosed sea. Here, for the first time, the occurrence and distribution of microplastics are reported for the Black Sea. Microplastics were assessed from zooplankton samples taken during two cruises along the south eastern coast of the Black Sea in the November of 2014 and February of 2015. In each cruise neuston samples were collected at 12 stations using a WP2 net with 200 μm mesh. Microplastics (0.2-5 mm) were found in 92% of the samples. The primary shapes were fibres (49.4%) followed by plastic films (30.6%) and fragments (20%), and no micro beads were found. Average microplastic concentration in November (1.2 ± 1.1 × 10(3) par. m(-3)) was higher than in February (0.6 ± 0.55 × 10(3) par. m(-3)). Reduced concentrations in February were possibly caused by increased mixing. The highest concentrations of microplastics were observed in offshore stations during November sampling. The heterogeneous spatial distribution (0.2 × 10(3)-3.3 × 10(3) par. m(-3) for all samples) and accumulation in some stations could be associated to transport and retention mechanisms linked with wind and the dynamics of the rim current, as well by different sources of plastic. There were no statistically significant differences in MP concentration between sampling stations and sampling periods (t-test, p pollution and there is an urgency to understand their origins, transportation and effects on marine life. Copyright © 2016 Elsevier Ltd. All rights reserved.

Monitoring of radionuclides in the Baltic Sea in 1988

International Nuclear Information System (INIS)

Saxen, R.; Ikaeheimonen, T.K.; Ilus, E.

1989-12-01

Monitoring of radioactive substances in the Baltic Sea was continued within the framework of the Finnish national monitoring programme. Samples of sea water, bottom sediment and fish were collected for radionuclide analyses. All samples were analysed for gamma-emitting radionuclides and partly also for 90 Sr and transuranic elements. The activity concentrations of 137 Cs were about 120 Bq/m 3 in the surface water of the Bothnian Bay, 220-320 Bq/m 3 in the Bothnian Sea, 120-230 Bq/m 3 in the Gulf of Finland and 150-170 Bq/m 3 in the Baltic Proper. In the open Gulf of Finland and Bothnian Sea the 137 Cs concentrations of surface water were about 20 and 55 % of the maximum values in 1986. The total amounts of 137 Cs in bottom sediments ranged from 1700 to 16000 Bq/m 2 . In the Gulf of Bothnia and Gulf of Finland the total amounts of 137 Cs were about 5-6 times higher in 1988 than before the Chernobyl accident and 3 times higher in the northern Baltic Proper. The 137 Cs concentrations in Baltic herring ranged from 20 to 37 Bq/kg fresh weight and in pike from 38 to 160 Bq/kg fresh weight, the maximum values being in samples supplied from the Vaasa archipelago. The internal radiation dose to Finnish people caused by the consumption of Baltic Sea fish in 1988 was about 0.009mSv. (orig.)

Ecologically least vulnerable sites for exploration drilling in the Wadden Sea and the North Sea coastal area

International Nuclear Information System (INIS)

Lindeboom, H.J.; Bergman, M.J.N.; De Gee, A.

1996-01-01

The Dutch Oil Company (NAM, abbreviated in Dutch) applied for a number of exploration drilling in the Dutch part of the Wadden Sea and the North Sea coastal area. NAM is obliged to draft a so-called MER (environmental impact report) to indicate the most environment-friendly alternative for the test drilling. By order of NAM, NIOZ and the IBN-DLO (Institute for Research on Forests and Nature) analyzed samples of the animal life in all the potential sites. Based on the results of the analyses, literature and expert knowledge the ecologically least vulnerable sites and the ecologically least vulnerable season were selected during a workshop. In this report the results are given of the workshop, the field sample analyses and a sailing trip along the sites

Phylogenetic relationships of Scomberomorus commerson using sequence analysis of the mtDNA D-loop region in the Persian Gulf, Oman Sea and Arabian Sea

Directory of Open Access Journals (Sweden)

Ana Mansourkiaei

2016-04-01

Full Text Available Abstract Narrow-barred Spanish mackerel, Scomberomorus commerson, is an epipelagic and migratory species of family Scombridae which have a significant role in terms of ecology and fishery. 100 samples were collected from the Persian Gulf, Oman Sea and Arabian Sea. Part of their dorsal fins was snipped and transferred to micro-tubes containing ethanol; then, DNAs were extracted and HRM-Real Time PCR was performed to designate representative specimens for sequencing. Phylogenetic relationships of S. commerson from Persian Gulf, Oman Sea and Arabian Sea were investigated using sequence data of mitochondrial DNA D-loop region. None clustered Neighbor Joining tree indicated the proximity amid S. commerson in four sites. As numbers demonstrated in sequence analyses of mitochondrial DNA D-Loop region a sublimely high degree of genetic similarity among S. commerson from the Persian Gulf and Oman Sea were perceived, thereafter, having one stock structure of S. commerson in four regions were proved, and this approximation can be merely justified by their migration process along the coasts of Oman Sea and Persian Gulf. Therefore, the assessment of distribution patterns of 20 haplotypes in the constructed phylogenetic tree using mtDNA D-Loop sequences ascertained that no significant clustering according to the sampling sites was concluded.

New approaches for air-sea fluxes in the Southern Ocean

CSIR Research Space (South Africa)

Gille, S

2016-05-01

Full Text Available Air-sea exchanges in the Southern Ocean of momentum, heat, freshwater, carbon dioxide, and other gases are not well documented because fluxes are sparsely sampled (see Figure 1) and because high winds, high sea state, and lack of calibration...

IODP expedition 347: Baltic Sea basin paleoenvironment and biosphere

DEFF Research Database (Denmark)

Andrén, T; Jørgensen, Bo Barker; Cotterill, Carol

2015-01-01

-rich clay. Due to the stratified water column of the brackish Baltic Sea and the recurrent and widespread anoxia, the deeper basins harbor laminated sediments that provide a unique opportunity for high-resolution chronological studies. The Baltic Sea is a eutrophic intra-continental sea that is strongly...... degassing upon core recovery. The depth distributions of conservative sea water ions still reflected the transition at the end of the last glaciation from fresh-water clays to Holocene brackish mud. High-resolution sampling and analyses of interstitial water chemistry revealed the intensive mineralization......The Integrated Ocean Drilling Program (IODP) expedition 347 cored sediments from different set- tings of the Baltic Sea covering the last glacial–interglacial cycle. The main aim was to study the geological development of the Baltic Sea in relation to the extreme climate variability of the region...

Sea surface temperatures and salinities from platforms in the Barents Sea, Sea of Japan, North Atlantic Ocean, Philippine Sea, Red Sea, and the South China Sea (Nan Hai) from 1896-1950 (NODC Accession 0000506)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — Surface temperatures and salinities were collected in the Barents Sea, Sea of Japan, North Atlantic Ocean, Philippine Sea, Red Sea, and South China Sea (Nan Hai)...

Detection of Total and Pathogenic Vibrio parahaemolyticus in Shellfish Growing along the South Yellow Sea and the East China Sea.

Science.gov (United States)

Han, Feng; Gu, Run-Run; Shen, Xiao-Sheng; Chen, Yuan-Ge; Tian, Liang-Liang; Zhou, Wei-Feng; Cai, You-Qiong

2017-10-17

This study was conducted to monitor the densities of total and pathogenic Vibrio parahaemolyticus in 300 samples of nine shellfish species harvested from the coasts of the South Yellow Sea and the East China Sea (N 23° to 34°, E 116° to 124°), People's Republic of China, between May and October 2015. Total V. parahaemolyticus densities were measured, and V. parahaemolyticus isolates were biochemically identified with probes for the thermostable direct hemolysin gene (tdh) and the thermostable direct hemolysin-related hemolysin gene (trh). We found that 202 of the 300 samples were positive for V. parahaemolyticus from all the sites: 58 of the 100 samples from the Fujian province, 71 of the 100 samples from the Zhejiang province, and 73 of the 100 samples from the Jiangsu province. In most (170) of the 300 samples, V. parahaemolyticus densities were 0.3 to 10 most probable number (MPN)/g; five lots exceeded 110 MPN/g, and two lots were estimated at 110 MPN/g. Among the 202 V. parahaemolyticus strains, only one was trh positive. Densities of V. parahaemolyticus in these shellfish were temperature dependent, with highest densities in June and July. Among the nine mollusk species, V. parahaemolyticus was most abundant in the agemaki clam (Sinonovacula constricta). The highest and lowest V. parahaemolyticus prevalences were found in oriental cyclina (Cyclina sinensis, 93.8%) and mussels (Mytilus edulis, 28.1%), respectively. Overall, although V. parahaemolyticus is widely distributed in marine environments, the density of V. parahaemolyticus was low and the prevalence of the main virulence factor was very low in shellfish along the coasts of the South Yellow Sea and East China Sea, which is important from a public health perspective. Data presented here will be useful for correlational research and can be utilized for developing risk management plans that establish food safety guidelines for V. parahaemolyticus in Chinese shellfish.

Spatial analysis of Carbon-14 dynamics in a wetland ecosystem (Duke Swamp, Chalk River Laboratories, Canada)

International Nuclear Information System (INIS)

Yankovich, T.L.; King-Sharp, K.J.; Carr, J.; Robertson, E.; Killey, R.W.D.; Beresford, N.A.; Wood, M.D.

2014-01-01

A detailed survey was conducted to quantify the spatial distribution of 14 C in Sphagnum moss and underlying soil collected in Duke Swamp. This wetland environment receives 14 C via groundwater pathways from a historic radioactive Waste Management Area (WMA) on Atomic Energy Canada Limited (AECL)'s Chalk River Laboratories (CRL) site. Trends in 14 C specific activities were evaluated with distance from the sampling location with the maximum 14 C specific activity (DSS-35), which was situated adjacent to the WMA and close to an area of groundwater discharge. Based on a spatial evaluation of the data, an east-to-west 14 C gradient was found, due to the influence of the WMA on 14 C specific activities in the swamp. In addition, it was possible to identify two groups of sites, each showing significant exponential declines with distance from the groundwater source area. One of the groups showed relatively more elevated 14 C specific activities at a given distance from source, likely due to their proximity to the WMA, the location of the sub-surface plume originating from the WMA, the presence of marsh and swamp habitat types, which facilitated 14 C transport to the atmosphere, and possibly, 14 C air dispersion patterns along the eastern edge of the swamp. The other group, which had lower 14 C specific activities at a given distance from the groundwater source area, included locations that were more distant from the WMA and the sub-surface plume, and contained fen habitat, which is known to act as barrier to groundwater flow. The findings suggest that proximity to source, groundwater flow patterns and habitat physical characteristics can play an important role in the dynamics of 14 C being carried by discharging groundwater into terrestrial and wetland environments. - Highlights: • Groundwater represents an important source of volatile radionuclides to wetlands. • Habitat type influenced 14 C transport from sub-surface to surface environments. • C-14 specific

Observational analysis of air-sea fluxes and sea water temperature offshore South China Sea

Science.gov (United States)

Bi, X.; Huang, J.; Gao, Z.; Liu, Y.

2017-12-01

This paper investigates the air-sea fluxes (momentum flux, sensible heat flux and latent heat flux) from eddy covariance method based on data collected at an offshore observation tower in the South China Sea from January 2009 to December 2016 and sea water temperature (SWT) on six different levels based on data collected from November 2011 to June 2013. The depth of water at the tower over the sea averages about 15 m. This study presents the in-situ measurements of continuous air-sea fluxes and SWT at different depths. Seasonal and diurnal variations in air-sea fluxes and SWT on different depths are examined. Results show that air-sea fluxes and all SWT changed seasonally; sea-land breeze circulation appears all the year round. Unlike winters where SWT on different depths are fairly consistent, the difference between sea surface temperature (SST) and sea temperature at 10 m water depth fluctuates dramatically and the maximum value reaches 7 °C during summer.

Arabian Red Sea coastal soils as potential mineral dust sources

KAUST Repository

Prakash, P. Jish

2016-09-26

Both Moderate Resolution Imaging Spectroradiometer (MODIS) and Spinning Enhanced Visible and InfraRed Imager (SEVIRI) satellite observations suggest that the narrow heterogeneous Red Sea coastal region is a frequent source of airborne dust that, because of its proximity, directly affects the Red Sea and coastal urban centers. The potential of soils to be suspended as airborne mineral dust depends largely on soil texture, moisture content and particle size distributions. Airborne dust inevitably carries the mineralogical and chemical signature of a parent soil. The existing soil databases are too coarse to resolve the small but important coastal region. The purpose of this study is to better characterize the mineralogical, chemical and physical properties of soils from the Arabian Red Sea coastal plain, which in turn will help to improve assessment of dust effects on the Red Sea, land environmental systems and urban centers. Thirteen surface soils from the hot-spot areas of windblown mineral dust along the Red Sea coastal plain were sampled for analysis. Analytical methods included optical microscopy, X-ray diffraction (XRD), inductively coupled plasma optical emission spectrometry (ICP-OES), ion chromatography (IC), scanning electron microscopy (SEM) and laser particle size analysis (LPSA). We found that the Red Sea coastal soils contain major components of quartz and feldspar, as well as lesser but variable amounts of amphibole, pyroxene, carbonate, clays and micas, with traces of gypsum, halite, chlorite, epidote and oxides. The range of minerals in the soil samples was ascribed to the variety of igneous and metamorphic provenance rocks of the Arabian Shield forming the escarpment to the east of the Red Sea coastal plain. The analysis revealed that the samples contain compounds of nitrogen, phosphorus and iron that are essential nutrients to marine life. The analytical results from this study will provide a valuable input into dust emission models used in climate

Exploring Archaeal Communities And Genomes Across Five Deep-Sea Brine Lakes Of The Red Sea With A Focus On Methanogens

KAUST Repository

Guan, Yue

2015-12-15

The deep-sea hypersaline lakes in the Red Sea are among the most challenging, extreme, and unusual environments on the planet Earth. Despite their harshness to life, they are inhabited by diverse and novel members of prokaryotes. Methanogenesis was proposed as one of the main metabolic pathways that drive microbial colonization in similar habitats. However, not much is known about the identities of the methane-producing microbes in the Red Sea, let alone the way in which they could adapt to such poly extreme environments. Combining a range of microbial community assessment, cultivation and omics (genomics, transcriptomics, and single amplified genomics) approaches, this dissertation seeks to fill these gaps in our knowledge by studying archaeal composition, particularly methanogens, their genomic capacities and transcriptomic characteristics in order to elucidate their diversity, function, and adaptation to the deep-sea brines of the Red Sea. Although typical methanogens are not abundant in the samples collected from brine pool habitats of the Red Sea, the pilot cultivation experiment has revealed novel halophilic methanogenic species of the domain Archaea. Their physiological traits as well as their genomic and transcriptomic features unveil an interesting genetic and functional adaptive capacity that allows them to thrive in the unique deep-sea hypersaline environments in the Red Sea.

Metagenomic survey of the taxonomic and functional microbial communities of seawater and sea ice from the Canadian Arctic.

Science.gov (United States)

Yergeau, Etienne; Michel, Christine; Tremblay, Julien; Niemi, Andrea; King, Thomas L; Wyglinski, Joanne; Lee, Kenneth; Greer, Charles W

2017-02-08

Climate change has resulted in an accelerated decline of Arctic sea ice since 2001 resulting in primary production increases and prolongation of the ice-free season within the Northwest Passage. The taxonomic and functional microbial community composition of the seawater and sea ice of the Canadian Arctic is not very well known. Bacterial communities from the bottom layer of sea ice cores and surface water from 23 locations around Cornwallis Island, NU, Canada, were extensively screened. The bacterial 16S rRNA gene was sequenced for all samples while shotgun metagenomics was performed on selected samples. Bacterial community composition showed large variation throughout the sampling area both for sea ice and seawater. Seawater and sea ice samples harbored significantly distinct microbial communities, both at different taxonomic levels and at the functional level. A key difference between the two sample types was the dominance of algae in sea ice samples, as visualized by the higher relative abundance of algae and photosynthesis-related genes in the metagenomic datasets and the higher chl a concentrations. The relative abundance of various OTUs and functional genes were significantly correlated with multiple environmental parameters, highlighting many potential environmental drivers and ecological strategies.

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the POLARSTERN in the Arctic Ocean, Barents Sea and Laptev (or Nordenskjold) Sea from 2007-07-28 to 2007-10-10 (NODC Accession 0109899)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0109899 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean, Barents Sea and Laptev (or...

Seawater movement in the Japan Sea inferred from 14C measurement in seawater

International Nuclear Information System (INIS)

Otosaka, Shigeyoshi; Tanaka, Takayuki; Togawa, Orihiko; Amano, Hikaru; Aramaki, Takafumi

2008-01-01

Research Group for Environmental Science, JAEA has carried out oceanographic observations in the Japan Sea since 1997 to clarify the biogeochemical cycle in the Japan Sea. More than 3,000 seawater samples for measurement of radiocarbon were collected during the observations, and radiocarbon in the seawater samples was measured at AMS facility in JAEA Mutsu. In this paper, formation and circulation of water mass in the northern Japan Sea were discussed using analysis of radiocarbon and hydrographic data (e.g. salinity, temperature, nutrients). (author)

Sea-floor morphology and sedimentary environments in southern Narragansett Bay, Rhode Island

Science.gov (United States)

McMullen, Katherine Y.; Poppe, Lawrence J.; Blackwood, Dann S.; Nardi, Matthew J.; Andring, Matthew A.

2015-09-09

Multibeam echosounder data collected by the National Oceanic and Atmospheric Administration along with sediment samples and still and video photography of the sea floor collected by the U.S. Geological Survey were used to interpret sea-floor features and sedimentary environments in southern Narragansett Bay, Rhode Island, as part of a long-term effort to map the sea floor along the northeastern coast of the United States. Sea-floor features include rocky areas and scour depressions in high-energy environments characterized by erosion or nondeposition, and sand waves and megaripples in environments characterized by coarse-grained bedload transport. Two shipwrecks are also located in the study area. Much of the sea floor is relatively featureless within the resolution of the multibeam data; sedimentary environments in these areas are characterized by processes associated with sorting and reworking. This report releases bathymetric data from the multibeam echosounder, grain-size analyses of sediment samples, and photographs of the sea floor and interpretations of the sea-floor features and sedimentary environments. It provides base maps that can be used for resource management and studies of topics such as benthic ecology, contaminant inventories, and sediment transport.

Accumulation of technetium-99 in the Irish Sea?

International Nuclear Information System (INIS)

Leonard, Kinson S.; McCubbin, David; Bonfield, Rachel; McDonald, Paul; Service, Matthew; Conney, Stuart

2004-01-01

An assessment has been carried out to determine the impact of continued 99 Tc discharges into the Irish Sea from the nuclear fuels reprocessing plant at Sellafield. Samples of surface and bottom seawater and sediment have been collected from the Irish Sea and analysed for 99 Tc. The information has been used, together with supporting data, to determine the effect of summer stratification upon the seawater concentrations and to evaluate whether sediments provide a sink for 99 Tc. Hydrographic data provide clear evidence of thermal stratification of waters above the muddy sediment in the western Irish Sea. Surface water contained higher 99 Tc concentrations than bottom water, and concentrations were inversely related to water salinity. This inverse relationship was not observed in the eastern Irish Sea close to Sellafield. 99 Tc activities in surficial sediments were greatest (>20 Bq/kg) at sites closest to the Cumbrian coastline. Activity, from equivalent sampling sites, remained similar between surveys carried out in 1995 and 1998. The muted response of the seabed sediments, to fluctuations in the Sellafield discharges, compared with the water column is to be expected given that they reflect the integrated radionuclide discharge history

Deep-sea coral research and technology program: Alaska deep-sea coral and sponge initiative final report

Science.gov (United States)

Rooper, Chris; Stone, Robert P.; Etnoyer, Peter; Conrath, Christina; Reynolds, Jennifer; Greene, H. Gary; Williams, Branwen; Salgado, Enrique; Morrison, Cheryl L.; Waller, Rhian G.; Demopoulos, Amanda W.J.

2017-01-01

Deep-sea coral and sponge ecosystems are widespread throughout most of Alaska’s marine waters. In some places, such as the central and western Aleutian Islands, deep-sea coral and sponge resources can be extremely diverse and may rank among the most abundant deep-sea coral and sponge communities in the world. Many different species of fishes and invertebrates are associated with deep-sea coral and sponge communities in Alaska. Because of their biology, these benthic invertebrates are potentially impacted by climate change and ocean acidification. Deepsea coral and sponge ecosystems are also vulnerable to the effects of commercial fishing activities. Because of the size and scope of Alaska’s continental shelf and slope, the vast majority of the area has not been visually surveyed for deep-sea corals and sponges. NOAA’s Deep Sea Coral Research and Technology Program (DSCRTP) sponsored a field research program in the Alaska region between 2012–2015, referred to hereafter as the Alaska Initiative. The priorities for Alaska were derived from ongoing data needs and objectives identified by the DSCRTP, the North Pacific Fishery Management Council (NPFMC), and Essential Fish Habitat-Environmental Impact Statement (EFH-EIS) process.This report presents the results of 15 projects conducted using DSCRTP funds from 2012-2015. Three of the projects conducted as part of the Alaska deep-sea coral and sponge initiative included dedicated at-sea cruises and fieldwork spread across multiple years. These projects were the eastern Gulf of Alaska Primnoa pacifica study, the Aleutian Islands mapping study, and the Gulf of Alaska fish productivity study. In all, there were nine separate research cruises carried out with a total of 109 at-sea days conducting research. The remaining projects either used data and samples collected by the three major fieldwork projects or were piggy-backed onto existing research programs at the Alaska Fisheries Science Center (AFSC).

Epibiotic Diatoms Are Universally Present on All Sea Turtle Species

OpenAIRE

Robinson, Nathan J.; Majewska, Roksana; Lazo-Wasem, Eric A.; Nel, Ronel; Paladino, Frank V.; Rojas, Lourdes; Zardus, John D.; Pinou, Theodora

2016-01-01

The macro-epibiotic communities of sea turtles have been subject to growing interest in recent years, yet their micro-epibiotic counterparts are almost entirely unknown. Here, we provide the first evidence that diatoms are epibionts for all seven extant species of sea turtle. Using Scanning Electron Microscopy, we inspected superficial carapace or skin samples from a single representative of each turtle species. We distinguished 18 diatom taxa from these seven individuals, with each sea turtl...

The sea ice in Young Sound: Implications for carbon cycling

DEFF Research Database (Denmark)

Glud, Ronnie Nøhr; Rysgaard, Søren; Kühl, Michael

2007-01-01

on the available nutrients. The sea-ice algal community adapts effi ciently to the local light environment, and in areas with natural (or man-made) holes and cracks sea-ice algae bloom. However, despite ample nutrients, the overall phototrophic biomass in Young Sound remains very low, with maximum values of c. 15......–30 μg Chl a l-1 sea ice at the underside of the ice and with maximum area integrated values of c. 3 mg Chl a m-2. We speculate that the extreme dynamics in sea-ice appearance, structure and brine percolation, which is driven primarily by large but variable freshwater inputs during snow melt...... the sea-ice matrix were extremely dynamic and strongly regulated by physical processes related to freezing and thawing of sea water rather than biological activity. Enclosure experiments on sea-ice samples performed in June 2002 revealed a high heterotrophic potential causing the sea-ice environment...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 2001-05-27 to 2001-06-19 (NODC Accession 0113754)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113754 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Atlantic Ocean, North Greenland Sea and...

Population genetic structure of the mantis shrimp Oratosquilla oratoria (Crustacea: Squillidae) in the Yellow Sea and East China Sea

Science.gov (United States)

Yang, Mei; Li, Xinzheng

2017-09-01

The mantis shrimp Oratosquilla oratoria is an ecologically and economically important species in the Western Pacific. In present study, the population genetic structure of Oratosquilla oratoria from the Yellow Sea and East China Sea was examined with mitochondrial DNA control region sequences. In total, 394 samples were collected from 18 locations and 102 haplotypes were obtained. For the Yellow Sea, the overall nucleotide diversity and haplotype diversity were 0.006 9 and 0.946 8, respectively; while across all the East China Sea locations, the overall nucleotide diversity and haplotype diversity were 0.027 94 and 0.979 0, respectively. The results of AMOVA and pairwise F ST (0.145 2, P China Sea populations of O. oratoria. However, neither the neighbor-joining tree nor haplotype network showed clades with geographic pattern, which indicated considerable gene flow was existed between the Yellow Sea and East China Sea, and supporting the high larval dispersal ability in this species. Mismatch distribution analysis and neutrality tests suggested that O. oratoria has undergone population expansion event, and the Pleistocene glacial cycles might have an impact on the historical demography of O. oratoria. The genetic information obtained in this study can provide useful information for sustainable improvements for capture fisheries management strategies.

Comparison of modern pollen distribution between the northern and southern parts of the South China Sea.

Science.gov (United States)

Luo, Chuanxiu; Chen, Muhong; Xiang, Rong; Liu, Jianguo; Zhang, Lanlan; Lu, Jun

2015-04-01

The authors conducted a palynological analysis based on different number of air pollen samples for the northern and southern parts of the South China Sea, respectively, in order to give a reference to reconstruct the paleoclimate of the area. (1) Fifteen air pollen samples were collected from the northern part of the South China Sea from August to September 2011, and 13 air pollen samples were collected from the southern part of the South China Sea in December 2011. The pollen types were more abundant in the north than in the south. The total pollen number and concentration in the north was 10 times more than that in the south, which may be because of the sampling season. Airborne pollen types and concentrations have a close relationship with wind direction and distance from the sampling point to the continent. (2) Seventy-four samples were collected from surface sediments in the northern part of the South China Sea in the autumn. Thirty-three samples were collected from surface sediments in the southern part of the South China Sea in the winter. Pollen concentrations in the north were nearly 10 times higher than that in the south. This is because trilete spores are transported by rivers from Hainan Island to the sea and also by the summer monsoon-forced marine current. (3) Ten air pollen samples and 10 surface sediments samples were selected for comparison. The pollen and spores in the air were mainly herbaceous and woody pollen, excluding fern spores, having seasonal pollen characteristics. Pollen in the surface sediments were mainly trilete, Pinus, and herbaceous, and may also show a combination of annual pollen characteristics.

Stable isotope geochemistry of deep sea cherts

Energy Technology Data Exchange (ETDEWEB)

Kolodny, Y; Epstein, S [California Inst. of Tech., Pasadena (USA). Div. of Geological Sciences

1976-10-01

Seventy four samples of DSDP (Deep Sea Drilling Project) recovered cherts of Jurassic to Miocene age from varying locations, and 27 samples of on-land exposed cherts were analyzed for the isotopic composition of their oxygen and hydrogen. These studies were accompanied by mineralogical analyses and some isotopic analyses of the coexisting carbonates. delta/sup 18/0 of chert ranges between 27 and 39 parts per thousand relative to SMOW, delta/sup 18/0 of porcellanite - between 30 and 42 parts per thousand. The consistent enrichment of opal-CT in porcellanites in /sup 18/0 with respect to coexisting microcrystalline quartz in chert is probably a reflection of a different temperature (depth) of diagenesis of the two phases. delta/sup 18/0 of deep sea cherts generally decrease with increasing age, indicating an overall cooling of the ocean bottom during the last 150 m.y. A comparison of this trend with that recorded by benthonic foraminifera (Douglas et al., Initial Reports of the Deep Sea Drilling Project; 32:509(1975)) indicates the possibility of delta/sup 18/0 in deep sea cherts not being frozen in until several tens of millions of years after deposition. Cherts of any Age show a spread of delta/sup 18/0 values, increasing diagenesis being reflected in a lowering of delta/sup 18/0. Drusy quartz has the lowest delta/sup 18/0 values. On land exposed cherts are consistently depleted in /sup 18/0 in comparison to their deep sea time equivalent cherts. Water extracted from deep sea cherts ranges between 0.5 and 1.4 wt%. deltaD of this water ranges between -78 and -95 parts per thousand and is not a function of delta/sup 18/0 of the cherts (or the temperature of their formation).

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the LOUIS S. ST. LAURENT in the Arctic Ocean, Beaufort Sea and North Greenland Sea from 1994-07-24 to 1994-09-01 (NODC Accession 0113983)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113983 includes chemical, discrete sample, physical and profile data collected from LOUIS S. ST. LAURENT in the Arctic Ocean, Beaufort Sea and North...

Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the G.O. SARS in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 2003-09-22 to 2003-10-13 (NODC Accession 0113752)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113752 includes chemical, discrete sample, physical and profile data collected from G.O. SARS in the North Atlantic Ocean, North Greenland Sea and...

IMPROVEMENT OF METHODS FOR HYDROBIOLOGICAL RESEARCH AND MODIFICATION OF STANDARD TOOLS FOR SAMPLE COLLECTION