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Sample records for sea chalk samples

  1. Ultrasonic velocities of North Sea chalk samples: influence of porosity, fluid content and texture

    DEFF Research Database (Denmark)

    Rogen, B.; Fabricius, Ida Lykke; Japsen, P.

    2005-01-01

    a porosity-reducing effect and that samples rich in large grains have a relatively low porosity for a given P-wave modulus. The clay content in the samples is low and is mainly represented by either kaolinite or smectite; samples with smectite have a lower P-wave modulus than samples with kaolinite at equal...

  2. Geochemical criteria for reservoir quality variations in chalk from the North Sea

    International Nuclear Information System (INIS)

    Kunzendorf, H.; Soerensen, P.

    1989-12-01

    The influence of chalk geochemistry on petrophysical parameters determining porosity and permeability is investigated. The central well TWB-8 and eastern marginal well E-lx of the North Sea Tyra gas field were chosen. Drill core sections of Upper Maastrichtian and Danian chalk were selected. Chemical data on chalk samples were gathered by using X-ray fluorescence and instrumental neutron activation. Geochemical data are compared with the well-logging results. Geophysical logging suggests that there is reduced porosity in the Danian reservoir units LDP and UDT in both wells. The chalk drill core samples from the section with reduced porosity also show a lower Ca content. A high Si content is observed in these samples and a number of trace elements in chalk show a similar distribution with depth. Reservoir porosity may be estimated from the Si content of chalk. Chalk permeability may also be elements Al, Fe and Sc show the same trends as that for Si. Diagenetic changes in chalk also include clay minerals. The gas zone in TWB-8 is characterized by low contents of Na and Cl, i.e. lower water saturation is indicated. Low concentrations of rare earths in all chalk samples show a shale-normalized pattern that is characteristic of marine sediments laid down under oxic conditions. Some changes that occur with depth in the Ce anomaly may indicate a slight change in the depositional environment. The content of manganese continuously decreases with depth, from Danian (about 2000 ppm) to Maastrichtian strata (less than 200 ppm). In this respect, no other chemical element in chalk correlates with Mn. There is no indication as to which mineral or mineral phase one is likely to find in the element. (AB) 14 tabs., 49 ills., 147 refs

  3. Change of Static and Dynamic Elastic Properties due to CO² Injection in North Sea Chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, M.L.; Christensen, H.F.

    2012-01-01

    important in enhanced oil recovery by CO2 injection (CO2-EOR) in chalk as, chalk reservoirs are vulnerable to compaction under changed stress and pore fluid. From South Arne field, North Sea, we used Ekofisk Formation chalk having approximately 20% non-carbonate and Tor Formation chalk having less than 5...

  4. Dynamic and static elastic moduli of North Sea and deep sea chalk

    DEFF Research Database (Denmark)

    Gommesen, Lars; Fabricius, Ida Lykke

    2001-01-01

    We have established an empirical relationship between the dynamic and the static mechanical properties of North Sea and deep sea chalk for a large porosity interval with respect to porosity, effective stress history and textural composition. The chalk investigated is from the Tor and Hod Formatio...

  5. Influence of clay and silica on permeability and capillary entry pressure of chalk reservoirs in the North Sea

    DEFF Research Database (Denmark)

    Røgen, Birte; Fabricius, Ida Lykke

    2002-01-01

    specific surface area. Fifty-nine Tor and Ekofisk Formation chalk samples from five North Sea chalk reservoirs were investigated. All contain quartz and clay minerals, most commonly kaolinite and smectite, with trace amounts of illite. The contents of calcite and quartz are inversely correlated and both......)): calcite between 0.5 and 3.5, quartz about 5, kaolinite about 15, and smectite about 60....

  6. Elastic behaviour of North Sea chalk

    DEFF Research Database (Denmark)

    Gommesen, Lars; Fabricius, Ida Lykke; Mukerji, T.

    2007-01-01

    -consistent approximation, which here represents the unrelaxed scenario where the pore spaces of the rock are assumed to be isolated, and the Gassmann theory, which assumes that pore spaces are connected, as tools for predicting the effect of hydrocarbons from the elastic properties of brine-saturated North Sea reservoir...

  7. Burial diagenesis of deep sea chalk as reflected in Biot's coefficient

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Alam, Mohammad Monzurul

    2013-01-01

    to limestone as burial increases and porosity decreases. The porosity decrease is accompanied by an increasing velocity to elastic waves, and consequently a decreasing Biot's coefficient, as estimated from velocity and density of core samples. When the effective burial stress is normalized to total horizontal....... In the ooze, we find that the natural compaction causes an increasing stress on grain contact area, indicating that the ooze particles become strongly strained. In the chalk section, contact cement is probably the reason why particles become less strained as porosity declines. In the limestone, stress...... on particles apparently is low and not correlated with porosity, probably because the pore-filling cementation in this interval causes Biot's coefficient to decline as burial increases. Limestone from the water zone of the North sea Chalk Group follows the same stress trend as deep sea limestone. These results...

  8. Fluid substitution studies for North Sea chalk logging data

    DEFF Research Database (Denmark)

    Gommesen, Lars; Mavko, G.; Mukerji, T.

    2002-01-01

    We have tested the application of respectively the Kuster-Toksöz and the Gassmann theory as a tool for predicting pore fluid from the elastic properties of brine-saturated North Sea reservoir chalk. We confirm that the Kuster-Toksöz model predicts a larger fluid effect thant the Gassmann model......, and show that the Kuster-Toksöz model fails to predict the presence of hydrocarbons. The Gassmann prediction for the near and potentially invaded zone corresponds more closely to logging data, than the Gassmann prediction for the far, virgin zone. We hereby conclude that the Gassmann theory predicts...

  9. Dual hydraulic behaviour of the Chalk in the Netherlands North Sea

    NARCIS (Netherlands)

    Verweij, H.

    2006-01-01

    Information on the sedimentary development, seismic stratigraphy and burial compaction of the Chalk Group in the Netherlands North Sea was combined with pressure data and basin modelling to investigate the hydraulic behaviour of the Chalk Group in the Central Graben and Schill Grund High. The

  10. Stability analysis of chalk sea cliffs using UAV photogrammetry

    Science.gov (United States)

    Barlow, John; Gilham, Jamie

    2017-04-01

    Cliff erosion and instability poses a significant hazard to communities and infrastructure located is coastal areas. We use point cloud and spectral data derived from close range digital photogrammetry to assess the stability of chalk sea cliffs located at Telscombe, UK. Data captured from an unmanned aerial vehicle (UAV) were used to generate dense point clouds for a 712 m section of cliff face which ranges from 20 to 49 m in height. Generated models fitted our ground control network within a standard error of 0.03 m. Structural features such as joints, bedding planes, and faults were manually mapped and are consistent with results from other studies that have been conducted using direct measurement in the field. Kinematic analysis of these data was used to identify the primary modes of failure at the site. Our results indicate that wedge failure is by far the most likely mode of slope instability. An analysis of sequential surveys taken from the summer of 2016 to the winter of 2017 indicate several large failures have occurred at the site. We establish the volume of failure through change detection between sequential data sets and use back analysis to determine the strength of shear surfaces for each failure. Our results show that data capture through UAV photogrammetry can provide useful information for slope stability analysis over long sections of cliff. The use of this technology offers significant benefits in equipment costs and field time over existing methods.

  11. Impedance imaging in core analysis. Imaging of phase distributions in samples of natural cores of North Sea chalk containing conducting as well as non-conducting fluids. Part: 1-3

    Energy Technology Data Exchange (ETDEWEB)

    Laursen, S. [DTU, Inst. for Kemi (Denmark)] Moeller Nielsen, C. [DTU, Inst. for Energiteknik (Denmark)

    1997-12-31

    The present report documents the efforts to develop an impedance method for determining the distribution of the water saturation in a chalk core sample. Measurement of this distribution during a displacement process will make it possible to make numerical simulations of the process which may in turn reveal important rock parameters. The impedance method is one among other methods to determine saturation profiles in a research programme on rock parameters with participants from Danmarks Tekniske Universitet, DTU, and Danmarks og Groenlands Geologiske Undersoegelse, GEUS. The other methods investigated are nmr-scanning and {gamma}-logging. (au)

  12. The new Chalk River AMS ion source, sample changer and external sample magazine

    International Nuclear Information System (INIS)

    Koslowsky, V.T.; Bray, N.; Imahori, Y.; Andrews, H.R.; Davies, W.G.

    1997-01-01

    A new sample magazine, sample changer and ion source have been developed and are in routine use at Chalk River. The system features a readily accessible 40-sample magazine at ground potential that is external to the ion source and high-voltage cage. The samples are held in an inert atmosphere and can be individually examined or removed; they can be exchanged en masse as a complete magazine concurrent with an AMS measurement. On-line sample changing is done with a pneumatic rabbit transfer system employing two stages of differential pumping. At Chalk River this is routinely performed across a 200 kV potential. Sample positioning is precise, and hundreds of 36 Cl and 129 I samples have been measured over a period of several days without interruption or alteration of ion source operating conditions. (author)

  13. Microbial Fluid-Rock Interactions in Chalk Samples and Salinity Factor in Divalent Ca2+ ions Release for Microbial Enhanced Oil Recovery Purposes

    DEFF Research Database (Denmark)

    Jimoh, Ismaila Adetunji; Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen

    2011-01-01

    In this study, laboratory experiments were performed on chalk samples from Danish sector of the North Sea to study microbial fluid-rock interactions with carbonate rock and to evaluate the dissolution of rock matrix (CaCO3). Result showed that the average concentration of Ca2+ ions after microbia...

  14. Impedance imaging in core analysis. Imaging of phase distributions in samples of natural cores of North Sea chalk containing conducting as well as non-conducting fluids. Part 1: Development of prototype measurement cell

    Energy Technology Data Exchange (ETDEWEB)

    Moeller Nielsen, C. [DTU, Inst. for Kemi (Denmark); Lauersen, S. [DTU, Lab. for Energiteknik (Denmark)

    1996-12-31

    To make reservoir simulations it is necessary to know such parameter functions as the capillary pressure curve, relative permeabilities etc. These are difficult to measure in chalk by means of traditional techniques because of the low permeability. In the present approach a displacement process is studied in detail and computer simulation with reservoir simulators can be used to determine parameter functions. To do this, however, it is necessary to know the developments of saturation profiles during the experiment. Different methods are tested in the programme. NMR-scanning and {gamma}-logging are methods where straight rays penetrate the sample and are partly absorbed. In electric current imaging an electric field is induced in the sample and detected at the surface. There are several benefits of this method compared with the others: There are no special safety requirements in contrast to work with radiation; No expensive and limited available equipment is needed unlike NMR; There are no intrinsic procedures slowing the method. There are, however, also drawbacks: Making measurements on a core sample implies the application of a large number of minute electrodes. To do this an implementation has to be derived from scratch; The inverse problem, i.e. the determination of the field inside the sample from surface measurements, is more difficult than the inverse problem of straight ray absorption. In the present report the development of an experimental technique is described. In part II of the report the interpretation of the experimental results will be discussed. (EG) 21 refs.

  15. Stylolites, porosity, depositional texture, and silicates in chalk facies sediments:Ontong Java Plateau - Gorm and Tyra fields, North Sea

    OpenAIRE

    Fabricius, Ida Lykke; Borre, Mai K.

    2007-01-01

    Comparison of chalk on the Ontong Java Plateau and chalk in the Central North Sea indicates that, whereas pressure dissolution is controlled by effective burial stress, pore-filling cementation is controlled by temperature. Effective burial stress is caused by the weight of all overlying water and sediments as counteracted by the pressure in the pore fluid, so the regional overpressure in the Central North Sea is one reason why the two localities have different relationships between temperatu...

  16. Managing Injected Water Composition To Improve Oil Recovery: A Case Study of North Sea Chalk Reservoirs

    DEFF Research Database (Denmark)

    Zahid, Adeel; Shapiro, Alexander; Stenby, Erling Halfdan

    2012-01-01

    of the temperature dependence of the oil recovery indicated that the interaction of the ions contained in brine with the rock cannot be the only determining mechanism of enhanced recovery. We observed no substitution of Ca2+ ions with Mg2+ ions at high temperatures for both rocks. Not only the injection brine......In recent years, many core displacement experiments of oil by seawater performed on chalk rock samples have reported SO42–, Ca2+, and Mg2+ as potential determining ions for improving oil recovery. Most of these studies were carried out with outcrop chalk core plugs. The objective of this study...... is to investigate the potential of the advanced waterflooding process by carrying out experiments with reservoir chalk samples. The study results in a better understanding of the mechanisms involved in increasing the oil recovery with potential determining ions. We carried out waterflooding instead of spontaneous...

  17. Permeability, porosity, dispersion-, diffusion-, and sorption characteristics of chalk samples from Erslev, Mors, Denmark

    International Nuclear Information System (INIS)

    Carlsen, L.; Batsberg, W.; Skytte Jensen, B.; Bo, P.

    1981-08-01

    A series of chalk samples from the cretaceous formation overlying the Erslev salt dome have been studied in order to establish permeabilities, porosities, dispersion-, diffusion-, and sorption characteristics of the chalk, Predominantly the investigations have been carried out by application of a liquid chromatographic technique. The chalk was found to be porous (epsilon approximately 0.4), however, of rather low permeability (k approximately 10 -7 cm/sec). It was found that the material exhibits a retarding effect on the migration of cationic species as Cs + , Sr 2+ , Co 2+ , and Eu 3+ , whereas anionic species as Cl - and TcO - 4 move with the water front. The geochemical implications are discussed. (author)

  18. Towards an improved lithostratigraphic subdivision of the chalk group in the Netherlands North Sea area - A seismic stratigraphic approach

    NARCIS (Netherlands)

    Molen, A.S. van der; Wong, Th.E.

    2007-01-01

    In the Netherlands North Sea area, the Chalk Group has thus far been subdivided into the Cenomanian Texel Formation, the Turonian to Maastrichtian Ommelanden Formation and the Danian Ekofisk Formation. This paper describes the attempt to arrive at a more detailed lithostratigraphic subdivision for

  19. Towards an improved lithostratigraphic subdivision of the Chalk Group in the Netherlands North Sea area – A seismic stratigraphic approach

    NARCIS (Netherlands)

    Molen, A.S. van der; Wong, Th.E.

    In the Netherlands North Sea area, the Chalk Group has thus far been subdivided into the Cenomanian Texel Formation, the Turonian to MaastrichtianOmmelanden Formation and the Danian Ekofisk Formation. This paper describes the attempt to arrive at a more detailed lithostratigraphicsubdivision for

  20. Diagenetic Variations between Upper Cretaceous Outcrop and Deeply Buried Reservoir Chalks of the North Sea Area

    DEFF Research Database (Denmark)

    Hjuler, Morten Leth; Fabricius, Ida Lykke

    2007-01-01

    -particle connections and less altered particle shapes. The non-carbonate mineralogy of outcrop chalks is dominated by quartz, occasionally opal-CT and clinoptilolite, and the clay mineral smectite. In offshore chalks quartz still dominates, opal-CT has recrystallized into submicron-size quartz crystals and smectite...

  1. Probing the intrinsically oil-wet surfaces of pores in North Sea chalk at subpore resolution

    DEFF Research Database (Denmark)

    Hassenkam, Tue; Skovbjerg, Lone Lindbæk; Stipp, Susan Louise Svane

    2009-01-01

    been drilled in a water-bearing formation. At this site, the chalk has never seen oil, though at other locations, the same stratigraphic horizon with the same rock properties is known to be a productive oil reservoir. Thus the properties of the investigated particle surfaces are inherent to the chalk......Ultimate Oil recovery from chalk reservoirs is limited by many factors - including the grain size and the surface properties of the small mainly biogenic calcite particles that chalk is made off . Wettability, the tendency for water or oil to spread over a surface, of the particle surfaces is one...... of the controlling factors for the effectiveness of water flooding, one of the most common methods to improve oil recovery in Chalk reservoirs. Understanding surface wetting and its variability at scales smaller than the pore dimension will potentially provide clues for more effective oil production methods. We used...

  2. Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge, Danish North Sea

    Directory of Open Access Journals (Sweden)

    Finn Surlyk

    2011-12-01

    Full Text Available The 331 m long core from the Mona-1 well in the Danish North Sea spans almost the entire Upper Cretaceous Chalk Group but only about 10% of Late Cretaceous time is represented. The succession comprises 14 facies representing pelagic deposition, turbidity flow, and mass-transport processes, including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab¬sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites, and the resultant deposits were thoroughly bioturbated if deposited during normal oxygenation at the sea floor. Periodic benthic dysoxia resulted in the preservation of primary structures, as represented by laminated chalk which consists of thin pelagic laminae alternating with thin turbidites. In addition to the thin turbidites in the laminated chalk, four dif¬ferent turbidite facies are interpreted as representing high- to low-energy flows. Clast-supported chalk conglomerates have previously not been differentiated from other turbidites, but are here interpreted to be directly related to the down-slope evolution of debris flows. Debris flows are rep¬resented by matrix-supported conglomerates, which form one of the most common facies in the succession. High-concentration, gravity-driven suspension flows passed into dilute visco-plastic flows during the final stages of deposition and resulted in the deposition of structureless chalks. Limited shear deformation produced distinct quasi-facies from which the precursor facies can be deduced, whereas intense or continued shear deformation produced a shear-banded quasi-facies from which the precursor facies cannot be deduced in all cases. A series of major slump packages (14–18 in total are interpreted, forming over 40% of the succession; debrites appear to be the most common precursor facies involved in

  3. Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge, Danish North Sea: Plate 1

    Directory of Open Access Journals (Sweden)

    Surlyk, Finn

    2011-12-01

    Full Text Available The 331 m long core from the Mona-1 well in the Danish North Sea spans almost the entire Upper Cretaceous Chalk Group but only about 10% of Late Cretaceous time is represented. The succession comprises 14 facies representing pelagic deposition, turbidity flow, and mass-transport processes, including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab¬sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites, and the resultant deposits were thoroughly bioturbated if deposited during normal oxygenation at the sea floor. Periodic benthic dysoxia resulted in the preservation of primary structures, as represented by laminated chalk which consists of thin pelagic laminae alternating with thin turbidites. In addition to the thin turbidites in the laminated chalk, four dif¬ferent turbidite facies are interpreted as representing high- to low-energy flows. Clast-supported chalk conglomerates have previously not been differentiated from other turbidites, but are here interpreted to be directly related to the down-slope evolution of debris flows. Debris flows are rep¬resented by matrix-supported conglomerates, which form one of the most common facies in the succession. High-concentration, gravity-driven suspension flows passed into dilute visco-plastic flows during the final stages of deposition and resulted in the deposition of structureless chalks. Limited shear deformation produced distinct quasi-facies from which the precursor facies can be deduced, whereas intense or continued shear deformation produced a shear-banded quasi-facies from which the precursor facies cannot be deduced in all cases. A series of major slump packages (14–18 in total are interpreted, forming over 40% of the succession; debrites appear to be the most common precursor facies involved in

  4. Pitfalls in velocity analysis for strongly contrasting, layered media - Example from the Chalk Group, North Sea

    Science.gov (United States)

    Montazeri, Mahboubeh; Uldall, Anette; Moreau, Julien; Nielsen, Lars

    2018-02-01

    Knowledge about the velocity structure of the subsurface is critical in key seismic processing sequences, for instance, migration, depth conversion, and construction of initial P- and S-wave velocity models for full-waveform inversion. Therefore, the quality of subsurface imaging is highly dependent upon the quality of the seismic velocity analysis. Based on a case study from the Danish part of the North Sea, we show how interference caused by multiples, converted waves, and thin-layer effects may lead to incorrect velocity estimation, if such effects are not accounted for. Seismic wave propagation inside finely layered reservoir rocks dominated by chalk is described by two-dimensional finite-difference wave field simulation. The rock physical properties used for the modeling are based on an exploration well from the Halfdan field in the Danish sector of the North Sea. The modeling results are compared to seismic data from the study area. The modeling shows that interference of primaries with multiples, converted waves and thin-bed effects can give rise to strong anomalies in standard velocity analysis plots. Consequently, root-mean-square (RMS) velocity profiles may be erroneously picked. In our study area, such mis-picking can introduce errors in, for example, the thickness estimation of the layers near the base of the studied sedimentary strata by 11% to 26%. Tests show that front muting and bandpass filtering cannot significantly improve the quality of velocity analysis in our study. However, we notice that spiking deconvolution applied before velocity analysis may to some extent reduce the impact of interference and, therefore, reduce the risk of erroneous picking of the velocity function.

  5. Impact of supercritical CO2 injection on petrophysical and rock mechanics properties of chalk: an experimental study on chalk from South Arne field, North Sea

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Hjuler, Morten Leth; Christensen, Helle Foged

    2011-01-01

    Changes in chalk due to EOR by injecting supercritical CO2 (CO2-EOR) can ideally be predicted by applying geophysical methods designed from laboratory-determined petrophysical and rock mechanics properties. A series of petrophysical and rock mechanics tests were performed on Ekofisk Formation...... and Tor Formation chalk of the South Arne field to reveal the changes in petrophysical and rock mechanics properties of chalk due to the injection of CO2 at supercritical state. An increase in porosity and decrease in specific surface was observed due to injection of supercritical CO2. This indicates...... as indicated by NMR T2 relaxation time was observed. Rock mechanics testing indicates that in 30% porosity chalk from the South Arne field, injection of supercritical CO2 has no significant effect on shear strength and compaction properties, while there is probably a slight decrease in stiffness properties...

  6. Investigation of spore forming bacterial flooding for enhanced oil recovery in a North Sea chalk Reservoir

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Nielsen, Sidsel Marie; Eliasson Lantz, Anna

    2015-01-01

    Little has been done to study microbial enhanced oil recovery (MEOR) in chalk reservoirs. The present study focuses on core flooding experiments designed to see microbial plugging and its effect on oil recovery. A pressure tapped core holder was used for this purpose. A spore forming bacteria...... Bacillus licheniformis 421 was used as it was shown to be a good candidate in a previous study. Bacterial spore can penetrate deeper into the chalk rock, squeezing through the pore throats. Our results showed that injection of B. licheniformis 421 as a tertiary oil recovery method, in the residual oil...... saturation state, was able to produce additionally 1.0-2.3% original oil in place (OOIP) in homogeneous cores and 6.9-8.8% OOIP in heterogeneous cores. In addition, the pressure gradient was much higher in the heterogeneous cores, which confirms that bacterial selective plugging plays an important role...

  7. Optimization of Spore Forming Bacteria Flooding for Enhanced Oil Recovery in North Sea Chalk Reservoir

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Nielsen, Sidsel Marie; Eliasson Lantz, Anna

    2015-01-01

    .2-3.8 cm) during bacteria injection. Further seawater flooding after three days shut in period showed that permeability gradually increased in the first two sections of the core and started to decrease in the third section of the core (3.8-6.3 cm). Complete plugging was never observed in our experiments.......Little has been done to study microbial enhanced oil recovery (MEOR) in chalk reservoirs. The present study focused on core flooding experiments to see microbial plugging and its effect on oil recovery. A pressure tapped core holder with pressure ports at 1.2 cm, 3.8 cm, and 6.3 cm from the inlet...

  8. Productivity, facies and stable-isotope records of OAE2 (Cenomanian - Turonian) in the NW European epicontinental sea: from the English Chalk to North Sea black shales

    Science.gov (United States)

    Jarvis, Ian; Olde, Kate; Trabucho-Alexandre, João; Gröcke, Darren

    2013-04-01

    The Late Cretaceous (100.5 - 66.0 Ma) provides perhaps the best example of how the Earth System may function under long-term extreme greenhouse conditions. Rapidly rising global temperatures indicate that we are heading 'back to the Cretaceous' within a few hundred years, so a better understanding of this time interval is essential. The beginning of the Late Cretaceous was characterized by a period of rapidly rising eustatic sea level, the Cenomanian transgression, which flooded continental margins and established large areas of new epicontinental sea that accumulated thick sequences of pelagic and hemipelagic carbonate (chalk). Highest global temperatures were reached during the early part of the Turonian Stage (93.9 - 89.8 Ma). This period of dramatic palaeoenvironmental change was accompanied by one the largest perturbations of the global carbon cycle in the Mesozoic: Oceanic Anoxic Event 2 (OAE2), which was characterized by a 500 kyr episode of oceanic anoxia, widespread black shale deposition, biotic turnover, and a large global positive carbon stable-isotope excursion (2 - 6 ‰ ∂13C) recorded in marine carbonates and both marine and terrestrial organic matter. The Cenomanian-Turonian boundary interval exposed at Eastbourne, southern England, has become established as a European reference section for OAE2. Here, and elsewhere in Europe, the base of the ∂13C excursion is coincident with a marked facies change from rhythmically bedded grey chalks and marls, to a >8 m thick package of dark greenish-grey marl - the Plenus Marl. The termination of OAE2 occurs 6 m above, in a package of pale-yellow-weathering nodular chalks with prominent marl seams. Sediments are organic lean (10 wt%. The onshore equivalent in eastern England (the Black Band) is similarly organic-rich, as are comparable sections in northern Germany (e.g. Wunstorf), indicating likely fully anoxic episodes within some NW European basins. The exact stratigraphic equivalence between the onshore

  9. Seismic geomorphology and origin of diagenetic geobodies in the Upper Cretaceous Chalk of the North Sea Basin (Danish Central Graben)

    DEFF Research Database (Denmark)

    Smit, F. W. H.; van Buchem, F.S.P.; Holst, J.H.

    2018-01-01

    that the geobodies are of an open-system diagenetic origin caused by ascending basin fluids guided by faults and stratigraphic heterogeneities. Increased amounts of porosity-occluding cementation, contact cement and/or high-density/-velocity minerals caused an impedance contrast that can be mapped in seismic data...... failure, followed by local mechanical compaction of high-porous chalks, paired with 2) ascension of basinal diagenetic fluids along fault systems that locally triggered cementation of calcite and dolomite within the chalk, causing increased contact cements and/or reducing porosity. The migration pathway...... of the fluids is marked by the SCRs, which are the outlines of high-density bodies of chalk nested in highly porous chalks. This study thus provides new insights into the 3D relationship between fault systems, fluid migration and diagenesis in chalks, and has important applications for basin modeling...

  10. Influence of coal mine tips on the chalk aquifer. Sampling methods for three dimensional sulphate infiltration study

    International Nuclear Information System (INIS)

    Barrez, F.; Mania, J.; Mansy, J.L.; Piwakowski, B.

    2005-01-01

    The coal basin of the Nord-Pas-de-Calais region (France) shows a very strong deterioration of the Chalk aquifer quality. In order to better model the hydro-dynamism and to improve knowledge on the chemical interactions, sampling according to depth of the groundwater is undertaken. The low-flow sampling and the profiles of the in-situ physicochemical parameters allow the observation of various vertical heterogeneities of the aquifer. The areas where the coal mine tips are localised appear very interesting to study. The sulphates released by the pyrite oxidation allow a 'artificial tracing' and give a visualization of the flow as well as information on the implied chemical processes between the oxidizing and reducing zones. (authors)

  11. Influence of coal mine tips on the chalk aquifer. Sampling methods for three dimensional sulphate infiltration study

    Energy Technology Data Exchange (ETDEWEB)

    Barrez, F.; Mania, J. [Polytech' Lille, Dept. Genie Civil, UMR CNRS 8107 (LML), 59 - Villeneuve d' Ascq (France); Mansy, J.L. [Lille-1 Univ., Lab. de Sedimentologie et de Geodynamique, UMR CNRS 8110 (PBDS), 59 - Villeneuve d' Ascq (France); Piwakowski, B. [Ecole Centrale de Lille, Groupe Electronique Acoustique IEMN-DOAE, UMR CNRS 8520, 59 - Villeneuve d' Ascq (France)

    2005-07-01

    The coal basin of the Nord-Pas-de-Calais region (France) shows a very strong deterioration of the Chalk aquifer quality. In order to better model the hydro-dynamism and to improve knowledge on the chemical interactions, sampling according to depth of the groundwater is undertaken. The low-flow sampling and the profiles of the in-situ physicochemical parameters allow the observation of various vertical heterogeneities of the aquifer. The areas where the coal mine tips are localised appear very interesting to study. The sulphates released by the pyrite oxidation allow a 'artificial tracing' and give a visualization of the flow as well as information on the implied chemical processes between the oxidizing and reducing zones. (authors)

  12. Use of X-ray computed tomography in core analysis of tight North Sea Chalk. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Mogensen, K.; Stenby, E.H.

    1997-12-01

    This EFP-95 final report summarizes work performed at the Engineering Research Center (IVC-SEP) on the use of CT scanning in core analysis of tight core material from the North Sea. In this work, CT scanning has been applied to chalk material from Danish North Sea oil reservoirs. Results indicate that CT is fast and reliable for prediction of porosity. Typical errors lie within 2-3%. Calculation of fluid saturations requires considerable care from the experimentalists. Saturating a core ought to be performed by pulling vacuum to avoid trapped air bubbles. These bubbles may be produced after subsequent water and gas flooding, thereby ruining the mass balance calculations. Results performed at Stanford University show that if these simple precautions are taken, fluid saturations calculated from CT scanning are generally very accurate. Moreover, it appears that contrast agents need not be added to either phase. Regarding three-phase measurements the results are somewhat disappointing. Previous work using the dual-energy technique has indicated that the accuracy is less than satisfactory, due to an increased noise level at the low-energy setting. More work needs to be done in the future to develop the necessary expertise. The image analysis of the residual oil saturation after a gas flood can be simplified if water is assumed to be immobile during the injection. In that case, the resulting prediction of residual oil saturation is in excellent agreement with measured values. The general conclusion is that CT scanning holds a great potential as an assisting tool in modern core analysis, despite its limitations and the numerous implementation-related problems encountered during this work. (au) EFP-95. 57 refs.

  13. Delineating chalk sand distribution of Ekofisk formation using probabilistic neural network (PNN) and stepwise regression (SWR): Case study Danish North Sea field

    Science.gov (United States)

    Haris, A.; Nafian, M.; Riyanto, A.

    2017-07-01

    Danish North Sea Fields consist of several formations (Ekofisk, Tor, and Cromer Knoll) that was started from the age of Paleocene to Miocene. In this study, the integration of seismic and well log data set is carried out to determine the chalk sand distribution in the Danish North Sea field. The integration of seismic and well log data set is performed by using the seismic inversion analysis and seismic multi-attribute. The seismic inversion algorithm, which is used to derive acoustic impedance (AI), is model-based technique. The derived AI is then used as external attributes for the input of multi-attribute analysis. Moreover, the multi-attribute analysis is used to generate the linear and non-linear transformation of among well log properties. In the case of the linear model, selected transformation is conducted by weighting step-wise linear regression (SWR), while for the non-linear model is performed by using probabilistic neural networks (PNN). The estimated porosity, which is resulted by PNN shows better suited to the well log data compared with the results of SWR. This result can be understood since PNN perform non-linear regression so that the relationship between the attribute data and predicted log data can be optimized. The distribution of chalk sand has been successfully identified and characterized by porosity value ranging from 23% up to 30%.

  14. The sedimentology of redeposited chalk

    DEFF Research Database (Denmark)

    Anderskouv, Kresten; Surlyk, Finn; Gale, Andy

    Redeposited facies in the Upper Cretaceous Chalk Group constitute major hydrocarbon reservoirs in the North Sea Central Graben. Existing facies models are largely based on publications from the early 1980's dealing with core material from the Norwegian sector. However, the recognition, interpreta...

  15. Nickel adsorption on chalk and calcite

    DEFF Research Database (Denmark)

    Belova, Dina Alexandrovna; Lakshtanov, Leonid; Carneiro, J.F.

    2014-01-01

    Nickel uptake from solution by two types of chalk and calcite was investigated in batch sorption studies. The goal was to understand the difference in sorption behavior between synthetic and biogenic calcite. Experiments at atmospheric partial pressure of CO2, in solutions equilibrated with calcite...... = - 1.12 on calcite and log KNi = - 0.43 and - 0.50 on the two chalk samples. The study confirms that synthetic calcite and chalk both take up nickel, but Ni binds more strongly on the biogenic calcite than on inorganically precipitated, synthetic powder, because of the presence of trace amounts...... of polysaccharides and clay nanoparticles on the chalk surface....

  16. Chalk Formations as Natural Barriers towards Radionuclide Migration

    DEFF Research Database (Denmark)

    Pedersen, Walther Batsberg; Carlsen, Lars; Jensen, Bror Skytte

    1985-01-01

    A series of chalk samples from the cretaceous formation overlying the Erslev salt dome have been studied in order to establish permeabilities, porosities, dispersion-, diffusion-, and sorption characteristics of the chalk. The chalk was found to be porous (∊≈0.4), however, of rather low...

  17. Compaction of microfossil and clay-rich chalk sediments

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2001-01-01

    The aim of this study was to evaluate the role of microfossils and clay in the compaction of chalk facies sediments. To meet this aim, chalk sediments with varying micro texture were studied. The sediments have been tested uniaxially confined in a stainless-steel compaction cell. The sediments are......: 1) Pure carbonate chalk with mudstone texture from Stevns Klint (Denmark), 2) Relatively pure chalk sediments with varying content of microfossils from the Ontong Java Plateau (Western Pacific), 3) Clay-rich chalk and mixed sediments from the Caribbean. The tested samples were characterised...

  18. The surface reactivity of chalk (biogenic calcite) with hydrophilic and hydrophobic functional groups

    Science.gov (United States)

    Okhrimenko, D. V.; Dalby, K. N.; Skovbjerg, L. L.; Bovet, N.; Christensen, J. H.; Stipp, S. L. S.

    2014-03-01

    chalk surfaces and partly by adsorbed organic material. GS < GS after extraction < WS < WS after extraction < Ålborg after extraction ⩽ Ålborg. The increase of spreading work for WS chalk for ethanol is 21 mN/m and for water is 26 mN/m, a ratio of 21/26 = 0.81. The increase of spreading work for GS chalk for ethanol and water are 36 and 42 mN/m, a ratio of 36/42 = 0.86. The similarity between these ratios leads us to conclude, that the surface that was produced by extraction of the organic material is quite similar for these two samples.The total surface energy increase, after the extraction of organics, for GS and WS was 67 and 49 mJ/m2. Further separation of surface energy into polar and dispersive parts showed that, for both samples, removing organic matter by extraction preferably increases the dispersive component of the surface energy. The contribution from dispersive surface energy to the increase in total surface energy was 87% for GS and 73% for WS chalk. A high relative proportion of dispersive component in the total surface energy is also typical for clay minerals (Chassin et al., 1986; Jouany and Chassin, 1987; Kádár et al., 2006).This demonstrates that the additional adsorption sites that are exposed by the extraction procedure are less polar than the sites originally exposed. Based on these results, we can conclude that chalk particles have surface sites of different polarity and that organic compounds preferentially adsorb at the less polar sites. These additional sites have quite similar surface properties for both North Sea chalk samples with an energy distribution that is similar to clays, that are described in the literature (Chassin et al., 1986; Jouany and Chassin, 1987; Kádár et al., 2006).The Ålborg chalk initially has minimal adsorbed organic material and the work of wetting changes very little after the treatment for extracting organic material. Considering the lower reproducibility of the results on Ålborg chalk, the differences in

  19. Chalk as a reservoir

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    , and the best reservoir properties are typically found in mudstone intervals. Chalk mudstones vary a lot though. The best mudstones are purely calcitic, well sorted and may have been redeposited by traction currents. Other mudstones are rich in very fine grained silica, which takes up pore space and thus...... basin, so stylolite formation in the chalk is controlled by effective burial stress. The stylolites are zones of calcite dissolution and probably are the source of calcite for porefilling cementation which is typical in water zone chalk and also affect the reservoirs to different extent. The relatively...... have hardly any stylolites and can have porosity above 40% or even 50% and thus also have relatively high permeability. Such intervals have the problem though, that increasing effective stress caused by hydrocarbon production results in mechanical compaction and overall subsidence. Most other chalk...

  20. Chalk porosity and sonic velocity versus burial depth

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Gommesen, Lars; Krogsbøll, Anette Susanne

    2008-01-01

    Seventy chalk samples from four formations in the overpressured Danish central North Sea have been analyzed to investigate how correlations of porosity and sonic velocity with burial depth are affected by varying mineralogy, fluid pressure, and early introduction of petroleum. The results show th...... for fluid pressure because the cementing ions originate from stylolites, which are mechanically similar to fractures. We find that cementation occurs over a relatively short depth interval.......Seventy chalk samples from four formations in the overpressured Danish central North Sea have been analyzed to investigate how correlations of porosity and sonic velocity with burial depth are affected by varying mineralogy, fluid pressure, and early introduction of petroleum. The results show...... that porosity and sonic velocity follow the most consistent depth trends when fluid pressure and pore-volume compressibility are considered. Quartz content up to 10% has no marked effect, but more than 5% clay causes lower porosity and velocity. The mineralogical effect differs between P-wave and shear velocity...

  1. New insight into the microtexture of chalks from NMR analysis

    DEFF Research Database (Denmark)

    Faÿ-Gomord, Ophélie; Soete, Jeroen; Katika, Konstantina

    2016-01-01

    An integrated petrographical and petrophysical study was carried out on a set of 35 outcrop chalk samples, covering a wide range of lithologies and textures. In this study various chalk rock-types have been characterized, in terms of microtextures and porous network, by integrating both geologica...

  2. Microplastic sampling in the Mediterranean Sea

    DEFF Research Database (Denmark)

    Biginagwa, Fares; Sosthenes, Bahati; Syberg, Kristian

    The extent of microplastic pollution in the Southwestern Mediterranean Sea is not yet known, although on Northwestern part has been previously studied. Plastic samples were collected at 7 transects during a 10 day expedition from Sicily (Italy) to Malaga (Spain) in September 2014. A 330 µM mesh...... manta trawl was used for surface water sampling. Physical and chemical characterization of plastic particles was performed with regard to size (1-5mm), shape (fragment, line, thin film, foam and pellets), color (transparent, white, black and colored), density and chemical composition according...

  3. Water in chalk reservoirs: 'friend or foe?'

    International Nuclear Information System (INIS)

    Hjuler, Morten Leth

    2004-01-01

    Most of the petroleum fields in the Norwegian sector of the North Sea are sandstone reservoirs; the oil and gas are trapped in different species of sandstone. But the Ekofisk Field is a chalk reservoir, which really challenges the operator companies. When oil is produced from chalk reservoirs, water usually gets in and the reservoir subsides. The subsidence may be expensive for the oil companies or be used to advantage by increasing the recovery rate. Since 60 per cent of the world's petroleum reserves are located in carbonate reservoirs, it is important to understand what happens as oil and gas are pumped out. Comprehensive studies at the Department of Petroleum Technology and Applied Geophysics at Stavanger University College in Norway show that the mechanical properties of chalk are considerably altered when the pores in the rock become saturated with oil/gas or water under different stress conditions. The processes are extremely complex. The article also maintains that the effects of injecting carbon dioxide from gas power plants into petroleum reservoirs should be carefully studied before this is done extensively

  4. To What Degree Thermal Cycles Affect Chalk Strength

    DEFF Research Database (Denmark)

    Livada, Tijana; Nermoen, Anders; Korsnes, Reidar Inger

    triaxial cell experiments. For dry rock, no significant effects of temperature cycling was found on average tensile strength, however the range of the tensile failure stress is doubled for the samples exposed to 50 temperature cycles, as opposed to those to none. For water saturated cores, the temperature......Chalk reservoirs could potentially undergo destabilization as the result of repeated cold water injection into a hot reservoir during water flooding. Preliminary results of an ongoing study are presented in this paper, which compare the impact of temperature cycling on mechanical behavior on dry...... and water saturated chalk. Sixty disks of dry Kansas chalk exposed to different number of temperature cycles were tested for tensile strength using a Brazilian test. Changes in elastic properties as function of number of temperature cycles of the same chalk, but now saturated in water, were studied using...

  5. Biot Critical Frequency Applied to Description of Failure and Yield of Highly Porous Chalk with Different Pore Fluids

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke

    2010-01-01

    Injection of water into chalk hydrocarbon reservoirs has led to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. In case of water-saturated samples, the concentration...... is controlled by solid-fluid friction. The reference frequency is thus a measure of this friction, and we propose that the fluid effect on mechanical properties of chalk may be the result of liquid-solid friction. We reviewed 622 published experiments on mechanical properties of porous chalk. The data include...... chalk samples that were tested at temperatures from 20 °C to 130 °C with the following pore fluids: fresh water, synthetic seawater, glycol, and oil of varying viscosity. The critical frequency is calculated for each experiment. For each specimen, we calculate the thickness to the slipping plane outside...

  6. ChalkBoard: Mapping Functions to Polygons

    Science.gov (United States)

    Matlage, Kevin; Gill, Andy

    ChalkBoard is a domain specific language for describing images. The ChalkBoard language is uncompromisingly functional and encourages the use of modern functional idioms. ChalkBoard uses off-the-shelf graphics cards to speed up rendering of functional descriptions. In this paper, we describe the design of the core ChalkBoard language, and the architecture of our static image generation accelerator.

  7. Quantitative 1D saturation profiles on chalk by NMR

    DEFF Research Database (Denmark)

    Olsen, Dan; Topp, Simon; Stensgaard, Anders

    1996-01-01

    Quantitative one-dimensional saturation profiles showing the distribution of water and oil in chalk core samples are calculated from NMR measurements utilizing a 1D CSI spectroscopy pulse sequence. Saturation profiles may be acquired under conditions of fluid flow through the sample. Results reveal...

  8. Regional hardening of Upper Cretaceous Chalk in eastern England, UK: trace element and stable isotope patterns in the Upper Cenomanian and Turonian Chalk and their significance

    Science.gov (United States)

    Jeans, Christopher V.; Long, Dee; Hu, Xiu-Fang; Mortimore, Rory N.

    2014-12-01

    fluids, rich in sulphate and hydrocarbons, derived probably from the North Sea Basin. Microbial sulphate-reduction under anoxic conditions within these allochthonous fluids has been responsible for dissolving the fine-grained iron and manganese oxides within the chalk, locally enriching the Fe and Mn content of the calcite cement. The possibility is discussed that the pattern of cementation preserved in these regionally hard chalks of Late Cenomanian and Early Turonian age may be different from that preserved in the younger (late Turonian to Campanian) more basinal chalks of eastern England.

  9. Trace elemental analysis of school chalk using energy dispersive X-ray florescence spectroscopy (ED-XRF)

    International Nuclear Information System (INIS)

    Maruthi, Y. A.; Das, N. Lakshmana; Ramprasad, S.; Ram, S. S.; Sudarshan, M.

    2015-01-01

    The present studies focus the quantitative analysis of elements in school chalk to ensure the safety of its use. The elements like Calcium (Ca), Aluminum (Al), Iron (Fe), Silicon (Si) and Chromium (Cr) were analyzed from settled chalk dust samples collected from five classrooms (CD-1) and also from another set of unused chalk samples collected from local market (CD-2) using Energy Dispersive X-Ray florescence(ED-XRF) spectroscopy. Presence of these elements in significant concentrations in school chalk confirmed that, it is an irritant and occupational hazard. It is suggested to use protective equipments like filtered mask for mouth, nose and chalk holders. This study also suggested using the advanced mode of techniques like Digital boards, marker boards and power point presentations to mitigate the occupational hazard for classroom chalk

  10. Trace elemental analysis of school chalk using energy dispersive X-ray florescence spectroscopy (ED-XRF)

    Energy Technology Data Exchange (ETDEWEB)

    Maruthi, Y. A., E-mail: ymjournal2014@gmail.com [Associate professor, Dept of Environmental Studies, GITAM Institute of Science, GITAM University, Visakhapatnam, A.P (India); Das, N. Lakshmana, E-mail: nldas9@gmail.com [Professor, Dept of Physics, GITAM Institute of Science, GITAM University, Visakhapatnam, A.P (India); Ramprasad, S., E-mail: ramprasadsurakala@gmail.com [Research Scholar, Dept of Environmental science, GITAM Institute of Science, GITAM University, Visakhapatnam, A.P (India); Ram, S. S., E-mail: tracebio@gmail.com [Research Scholar, Dept of Trace element research, UGC-DAE Consortium Centre, Kolkata centre India (India); Sudarshan, M., E-mail: sude@alpha.iuc.res.in [Scientist-F, Dept of Trace element research, UGC-DAE Consortium Centre, Kolkata centre India (India)

    2015-08-28

    The present studies focus the quantitative analysis of elements in school chalk to ensure the safety of its use. The elements like Calcium (Ca), Aluminum (Al), Iron (Fe), Silicon (Si) and Chromium (Cr) were analyzed from settled chalk dust samples collected from five classrooms (CD-1) and also from another set of unused chalk samples collected from local market (CD-2) using Energy Dispersive X-Ray florescence(ED-XRF) spectroscopy. Presence of these elements in significant concentrations in school chalk confirmed that, it is an irritant and occupational hazard. It is suggested to use protective equipments like filtered mask for mouth, nose and chalk holders. This study also suggested using the advanced mode of techniques like Digital boards, marker boards and power point presentations to mitigate the occupational hazard for classroom chalk.

  11. Uranium traps in the phosphate bearing sudr chalk, in northeastern sinai, Egypt

    International Nuclear Information System (INIS)

    Hussein, H.A.; El-Aassy, I.E.; Mahdy, M.A.; Dabbour, G.A.; Mansour, M.Gh.; Morsy, A.M.

    1998-01-01

    The maastrichtian sudr formation in northeastern sinai is composed of three members, the lower chalk, the middle phosphate and chart-bearing and the upper chalk members. Lemon yellow secondary uranium mineralization, distributed in the lower chalk member and in some phosphate beds from the middle phosphate member are observed. The XRD analyses of some samples from the uranium bearing chalk and the phosphate beds showed the presence of the secondary uranium minerals carnotite, bergenite and upalite. The mode of uranium occurrences could be interpreted as a result of the phosphatic beds decomposition and their subjection to later diagenetic processes. Uranium leaching circulation from phosphate rocks led to the liberation of uranium from the phosphates, and vanadium from the bituminous material and clay minerals. These migrated and were deposited locally and within the underlying chalk beds which acted as a lithologic trap

  12. Full-waveform inversion of cross-hole GPR data collected in a strongly heterogeneous chalk reservoir analogue with sharp permittivity and conductivity contrasts

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Zibar, Majken Caroline Looms; Moreau, Julien

    2014-01-01

    Chalk sediments form an important reservoir for groundwater onshore and for hydrocarbons in the Danish sector of the North Sea. Cross-hole Ground-penetrating radar (GPR) tomography is an efficient method to investigate subtle porosity variations in the chalk. Traditional ray-based inversion...

  13. Experimental study and mechanical modelling of the effects of water-driving in an oil saturated chalk. Application to the petroleum industry; Etude experimentale et modelisation mecanique des effets du balayage a l'eau dans une craie saturee d'huile. Application a l'industrie petroliere

    Energy Technology Data Exchange (ETDEWEB)

    Mata, C.

    2001-01-01

    The production of hydrocarbons may sometimes lead to compaction of the oil-reservoir layers with substantial collapse of the soil surface; this mechanism is usually mentioned as Subsidence. Classical remedy to this problem is to sustain the fluid pressure with the help of water injection. However, in presence of high porosity chalk (porosity > 30%), this technique does not give effective results: the subsidence rate at North Sea reservoirs (Ekofisk field), after injection, has remained unchanged. Some justify the subsistence in the chalk as caused by phenomena of dissolution of the carbonates; others think it is connected to the destruction of capillary menisci. In this research, we follow this second approach. This study is finalized to a better understanding of the compaction mechanisms in pure carbonates when water is injected. This is done by proposing -in micro-scale first and in macro-scale after- a physical model that agrees with empirical observations. In order to meet this target, IFP skills and experience in physical and chemical measurements (taken before, after and during mechanical tests) have proficiently joined ENPC laboratory (CERMMO) knowledge of micro and macro modelling. The soft rock studied is a Paris basin's white chalk (Craie de Guerville). Its physical and chemical characterisation (i.e.: silica content, porosity, permeability) is very similar to North Sea chalk, but Guerville chalk has never been in contact with oil and generally it crops out of the ground surface. Strength parameters of this rock have been first determined by standard triaxial tests. Three different saturation configurations have been examined: dry, fully oil-saturated and fully water-saturated. As literature clearly state, dry chalk is stronger than oil saturated chalk and the first two are largely stronger than water saturated chalk. Therefore uniaxial strain water injection tests have been performed on oil saturated samples. Results, coupled with previous physical

  14. Ekofisk chalk: core measurements, stochastic reconstruction, network modeling and simulation

    Energy Technology Data Exchange (ETDEWEB)

    Talukdar, Saifullah

    2002-07-01

    This dissertation deals with (1) experimental measurements on petrophysical, reservoir engineering and morphological properties of Ekofisk chalk, (2) numerical simulation of core flood experiments to analyze and improve relative permeability data, (3) stochastic reconstruction of chalk samples from limited morphological information, (4) extraction of pore space parameters from the reconstructed samples, development of network model using pore space information, and computation of petrophysical and reservoir engineering properties from network model, and (5) development of 2D and 3D idealized fractured reservoir models and verification of the applicability of several widely used conventional up scaling techniques in fractured reservoir simulation. Experiments have been conducted on eight Ekofisk chalk samples and porosity, absolute permeability, formation factor, and oil-water relative permeability, capillary pressure and resistivity index are measured at laboratory conditions. Mercury porosimetry data and backscatter scanning electron microscope images have also been acquired for the samples. A numerical simulation technique involving history matching of the production profiles is employed to improve the relative permeability curves and to analyze hysteresis of the Ekofisk chalk samples. The technique was found to be a powerful tool to supplement the uncertainties in experimental measurements. Porosity and correlation statistics obtained from backscatter scanning electron microscope images are used to reconstruct microstructures of chalk and particulate media. The reconstruction technique involves a simulated annealing algorithm, which can be constrained by an arbitrary number of morphological parameters. This flexibility of the algorithm is exploited to successfully reconstruct particulate media and chalk samples using more than one correlation functions. A technique based on conditional simulated annealing has been introduced for exact reproduction of vuggy

  15. Quick, Easy, and Economic Mineralogical Studies of Flooded Chalk for EOR Experiments Using Raman Spectroscopy

    Directory of Open Access Journals (Sweden)

    Laura Borromeo

    2018-05-01

    Full Text Available Understanding the chalk-fluid interactions and the associated mineralogical and mechanical alterations on a sub-micron scale are major goals in Enhanced Oil Recovery. Mechanical strength, porosity, and permeability of chalk are linked to mineral dissolution that occurs during brine injections, and affect the reservoir potential. This paper presents a novel “single grain” methodology to recognize the varieties of carbonates in rocks and loose sediments: Raman spectroscopy is a non-destructive, quick, and user-friendly technique representing a powerful tool to identify minerals down to 1 µm. An innovative working technique for oil exploration is proposed, as the mineralogy of micron-sized crystals grown in two flooded chalk samples (Liége, Belgium was successfully investigated by Raman spectroscopy. The drilled chalk cores were flooded with MgCl2 for ca. 1.5 (Long Term Test and 3 years (Ultra Long Term Test under North Sea reservoir conditions (Long Term Test: 130 °C, 1 PV/day, 9.3 MPa effective stress; Ultra Long Term Test: 130 °C, varying between 1–3 PV/day, 10.4 MPa effective stress. Raman spectroscopy was able to identify the presence of recrystallized magnesite along the core of the Long Term Test up to 4 cm from the injection surface, down to the crystal size of 1–2 µm. In the Ultra Long Term Test core, the growth of MgCO3 affected nearly the entire core (7 cm. In both samples, no dolomite or high-magnesium calcite secondary growth could be detected when analysing 557 and 90 Raman spectra on the Long and Ultra Long Term Test, respectively. This study can offer Raman spectroscopy as a breakthrough tool in petroleum exploration of unconventional reservoirs, due to its quickness, spatial resolution, and non-destructive acquisition of data. These characteristics would encourage its use coupled with electron microscopes and energy dispersive systems or even electron microprobe studies.

  16. Measurements with the Chalk River Calorimeters

    International Nuclear Information System (INIS)

    Boyd, A.W.

    1970-01-01

    The Chalk River calorimeters were designed to measure the absorbed dose rate in reactors in materials such as graphite, polyethylene and beryllium in the range 0.01-1 Wg -1 . To eliminate heaters in the sample they were made to operate adiabatically, or more accurately quasi-adiabatically since there is no heater on the jacket. Both the sample and jacket temperatures are recorded from the time of insertion in the reactor flux and the absorbed dose rate is calculated from these data. The advantages of this type of calorimeter are the ease of construction and the absence of a sample heater. The disadvantage is that dose rates below ~ 10 mWg -1 cannot be determined accurately

  17. Trace elements in a North Sea drill core

    DEFF Research Database (Denmark)

    Kunzendorf, Helmar; Gwozdz, R.; Svendsen, N.

    1986-01-01

    , V, Sr, Dy, Mg, Ti, Ba and Eu. The major elements Ca and Al could be related to petrophysical parameters, particularly Al which shows a correlation with the silicification/argillaceous content. Na (and Cl) has a low content in the hydrocarbon-bearing section of the drill core suggesting that the pore......Chalk samples, systematically taken along a drill core from one of the hydrocarbon producing fields of the North Sea (Tyra field), were analysed by a neutron activation technique involving measurement of radioisotopes with relatively short half-lives. Elements determined include Na, Al, Cl, Ca, Mn...... space is filled mainly by hydrocarbons. A significant decrease of Mn with depth probably suggests diagenesis of chalk prior to, or with, hydrocarbon emplacement. Investigations of drilling fluids and cuttings reveal a strong contamination of the latter, mainly by Ba. Chalk data from comparable onshore...

  18. Slope failure of chalk channel margins

    DEFF Research Database (Denmark)

    Gale, A.; Anderskouv, Kresten; Surlyk, Finn

    2015-01-01

    provide evidence for recurring margin collapse of a long-lived Campanian channel. Compressionally deformed and thrust chalk hardgrounds are correlated to thicker, non-cemented chalk beds that form a broad, gentle anticline. These chalks represent a slump complex with a roll-over anticline of expanded, non......-cemented chalk in the head region and a culmination of condensed hardgrounds in the toe region. Observations strongly suggest that the slumping represents collapse of a channel margin. Farther northwards, the contemporaneous succession shows evidence of small-scale penecontemporaneous normal faulting towards...

  19. Current oil and gas production from North American Upper Cretaceous chalks

    Science.gov (United States)

    Scholle, Peter A.

    1977-01-01

    Production of oil and natural gas from North American chalks has increased significantly during the past five years, spurred by the prolific production from North Sea chalks, as well as by higher prices and improved production technology. Chalk reservoirs have been discovered in the Gulf Coast in the Austin Group, Saratoga and Annona Chalks, Ozan Formation, Selma Group, Monroe gas rock (an informal unit of Navarro age), and other Upper Cretaceous units. In the Western Interior, production has been obtained from the Cretaceous Niobrara and Greenhorn Formations. Significant, though subcommercial, discoveries of natural gas and gas condensate also have been made in the Upper Cretaceous Wyandot Formation on the Scotian Shelf of eastern Canada. All North American chalk units share a similar depositional and diagenetic history. The chalks consist primarily of whole and fragmented coccoliths with subordinate planktonic and benthonic Foraminifera, inoceramid prisms, oysters, and other skeletal grains. Most have between 10 and 35 percent HCl-insoluble residue, predominantly clay. Deposition was principally below wave base in tens to hundreds of meters of water. The diagenetic history of a chalk is critical in determining its reservoir potential. All chalk has a stable composition (low-Mg calcite) and very high primary porosity. With subsequent burial, mechanical and chemical (solution-transfer) compaction can reduce or completely eliminate pore space. The degree of loss of primary porosity in chalk sections is normally a direct function of the maximum depth to which it has been buried. Pore-water chemistry, pore-fluid pressures, and tectonic stresses also influence rates of cementation. Oil or gas reservoirs of North American chalk fall into three main groups: 1. Areas with thin overburden and significant primary porosity retention (for example, Niobrara Formation of Kansas and eastern Colorado). 2. Areas with thicker overburden but considerable fracturing. Here primary

  20. Adsorption Properties of Chalk Reservoir Materials

    DEFF Research Database (Denmark)

    Okhrimenko, Denis

    /gas adsorption properties of synthetic calcium carbonate phases (calcite, vaterite and aragonite) with chalk, which is composed of biogenic calcite (>98%). In combination with data from nanotechniques, the results demonstrate the complexity of chalk behavior and the role of nanoscale clay particles. The results...

  1. Self Compacting Concrete with Chalk Filler

    DEFF Research Database (Denmark)

    Sørensen, Eigil V.

    2007-01-01

    Utilisation of Danish chalk filler has been investigated as a means to produce self compacting concrete (SCC) at lower strength levels for service in non aggressive environments. Stable SCC mixtures were prepared at chalk filler contents up to 60% by volume of binder to yield compressive strengths...

  2. Biot Critical Frequency Applied as Common Friction Factor for Chalk with Different Pore Fluids and Temperatures

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling; Fabricius, Ida Lykke

    2010-01-01

    Injection of water into chalk hydrocarbon reservoirs has lead to mechanical yield and failure. Laboratory experiments on chalk samples correspondingly show that the mechanical properties of porous chalk depend on pore fluid and temperature. Water has a significant softening effect on elastic...... and we propose that the fluid effect on mechanical properties of highly porous chalk may be the result of liquid‐solid friction. Applying a different strain or stress rate is influencing the rock strength and needs to be included. The resulting function is shown to relate to the material dependent...... and rate independent b-factor used when describing the time dependent mechanical properties of soft rock or soils. As a consequence it is then possible to further characterize the material constant from the porosity and permeability of the rock as well as from pore fluid density and viscosity which...

  3. Waveform analysis of crosshole GPR data collected in heterogeneous chalk deposits

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Nielsen, Lars; Zibar, Majken Caroline Looms

    2014-01-01

    Chalks are important reservoirs for groundwater production onshore Denmark and for hydrocarbons in the North Sea Basin. Therefore this rock type is studied extensively with geological and geophysical methods. Ground-penetrating radar (GPR) tomography is used to characterize fine-scale reservoir...

  4. Study of radioelements drained by Rhone stream to Mediterranean Sea: Strategy of sampling and methodology

    International Nuclear Information System (INIS)

    Arnaud, M.; Charmasson, S.; Calmet, D.; Fernandez, J.M.

    1992-01-01

    This paper describes the methods used for water and sediments sampling in rivers and sea. The purpose is the study of radionuclide migration (Cesium 134, Cesium 137) in Mediterranean Sea (Gulf of Lion). 20 refs., 11 figs., 1 tab

  5. Reactor loops at Chalk River

    International Nuclear Information System (INIS)

    Sochaski, R.O.

    1962-07-01

    This report describes broadly the nine in-reactor loops, and their components, located in and around the NRX and NRU reactors at Chalk River. First an introduction and general description is given of the loops and their function, supplemented with a table outlining some loop specifications and nine simplified flow sheets, one for each individual loop. The report then proceeds to classify each loop into two categories, the 'main loop circuit' and the 'auxiliary circuit', and descriptions are given of each circuit's components in turn. These components, in part, are comprised of the main loop pumps, the test section, loop heaters, loop coolers, delayed-neutron monitors, surge tank, Dowtherm coolers, loop piping. Here again photographs, drawings and tables are included to provide a clearer understanding of the descriptive literature and to include, in tables, some specifications of the more important components in each loop. (author)

  6. Protocol for Microplastics Sampling on the Sea Surface and Sample Analysis

    Science.gov (United States)

    Kovač Viršek, Manca; Palatinus, Andreja; Koren, Špela; Peterlin, Monika; Horvat, Petra; Kržan, Andrej

    2016-01-01

    Microplastic pollution in the marine environment is a scientific topic that has received increasing attention over the last decade. The majority of scientific publications address microplastic pollution of the sea surface. The protocol below describes the methodology for sampling, sample preparation, separation and chemical identification of microplastic particles. A manta net fixed on an »A frame« attached to the side of the vessel was used for sampling. Microplastic particles caught in the cod end of the net were separated from samples by visual identification and use of stereomicroscopes. Particles were analyzed for their size using an image analysis program and for their chemical structure using ATR-FTIR and micro FTIR spectroscopy. The described protocol is in line with recommendations for microplastics monitoring published by the Marine Strategy Framework Directive (MSFD) Technical Subgroup on Marine Litter. This written protocol with video guide will support the work of researchers that deal with microplastics monitoring all over the world. PMID:28060297

  7. The fusion blanket program at Chalk River

    International Nuclear Information System (INIS)

    Hastings, I.J.

    1986-03-01

    Work on the Fusion Blanket Program commenced at Chalk River in 1984 June. Co-funded by Canadian Fusion Fuels Technology Project and Atomic Energy of Canada Limited, the Program utilizes Chalk River expertise in instrumented irradiation testing, ceramics, tritium technology, materials testing and compound chemistry. This paper gives highlights of studies to date on lithium-based ceramics, leading contenders for the fusion blanket

  8. Stochastic modelling of porosity using seismic impedances on a volume of chalk in the Dan Field

    Energy Technology Data Exchange (ETDEWEB)

    Vejbaek, O.V.

    1995-12-31

    Seismic impedances calculated from logs show very good correlation to log porosities in wells penetrating the chalk reservoir in the Dan Field, Danish North Sea. This is the basis for an attempt to use seismic impedances derived from inversion as soft data for geostatistical reservoir characterization. The study focusses on porosity description of the Maastrichtian chalk reservoir unit, laterally restricted to an area covered by a subset of a 3D seismic survey. This seismic volume was inverted using the ISIS software producing a volume of seismic impedances. Spatial porosity realizations are produced using a gaussian collocated co-simulation algorithm, where well log porosities constitute the hard data input and seismic impedances are the soft data input. The simulated volume measures 1400 m x 1525 m x 102 m and is oriented parallel to lines and cross lines in the seismic dataset. Simulated blocks measures 25 m x 25 m x 6 m equivalent to twice the line and trace spacing, and approximately equivalent to the seismic sample rate. The correlation coefficient between log porosities and impedances calculated from logs alone are shown to be misleading since they suggest unrealistic high coefficients. However, the actual data used, namely inversion derived impedances and log porosities, still show correlation coefficients in the order of -0,45, which is quite sufficient to make the inversion results very useful. It is remarkable that the calculated correlation coefficient is based on 15 wells, and the inversion is based on only one well. The negative correlation coefficient indicate that high impedances correspond to low porosities and vice-versa. The impedance data indicate the level of average porosities at locations between wells. The fine structure is produced by the geostatistic process, with averages constrained by seismic impedances. The seismic impedances derived from the inversion process are thus shown to constitute useful primary data to constrain reservoir

  9. Potential for isoproturon, atrazine and mecoprop to be degraded within a chalk aquifer system

    Science.gov (United States)

    Johnson, Andrew C.; White, Craig; Lal Bhardwaj, C.

    2000-06-01

    The potential for herbicide degradation in an unconfined chalk aquifer was examined by collecting and spiking fresh samples and incubating them in the laboratory. The microcosms were incubated at 20°C under aerobic conditions and spiked with either isoproturon, atrazine or mecoprop at a concentration of 100 μg/l. The samples were obtained from a single fieldsite within the Upper Chalk aquifer in Hampshire, UK. Groundwater samples required the presence of sterile chalk in a ratio of at least 1:13 to promote isoproturon degradation. An isoproturon degradation potential existed in the soil, and the chalk unsaturated and saturated zones. However, no degradation of isoproturon in the unsaturated zone was observed when a more appropriate simulation of in-situ moisture conditions was carried out. Apart from the soil, no potential for atrazine or mecoprop degradation could be detected in the same samples over a 200-day incubation. In a series of groundwater samples taken from different boreholes, 10-300 m apart, large differences in isoproturon degradation potential were observed. Removal rates for 100 μg/l isoproturon varied from 83-425 ng/day, but in some samples no degradation potential could be detected. The primary metabolite which could be distinguished from isoproturon degradation in chalk and groundwater was monodesmethyl-isoproturon. When a chalk groundwater sample was spiked with isoproturon at 0.9 μg/l, this was not degraded over a 300-day incubation period. Further experiments with fresh groundwater from a Triassic Sandstone site illustrated that groundwater bacteria could degrade isoproturon at the more realistic temperature of 10°C as well as at 20°C.

  10. Adsorption of hydrocarbons in chalk reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Madsen, L.

    1996-12-31

    The present work is a study on the wettability of hydrocarbon bearing chalk reservoirs. Wettability is a major factor that influences flow, location and distribution of oil and water in the reservoir. The wettability of the hydrocarbon reservoirs depends on how and to what extent the organic compounds are adsorbed onto the surfaces of calcite, quartz and clay. Organic compounds such as carboxylic acids are found in formation waters from various hydrocarbon reservoirs and in crude oils. In the present investigation the wetting behaviour of chalk is studied by the adsorption of the carboxylic acids onto synthetic calcite, kaolinite, quartz, {alpha}-alumina, and chalk dispersed in an aqueous phase and an organic phase. In the aqueous phase the results clearly demonstrate the differences between the adsorption behaviour of benzoic acid and hexanoic acid onto the surfaces of oxide minerals and carbonates. With NaCl concentration of 0.1 M and with pH {approx_equal} 6 the maximum adsorption of benzoic acid decreases in the order: quartz, {alpha}-alumina, kaolinite. For synthetic calcite and chalk no detectable adsorption was obtaind. In the organic phase the order is reversed. The maximum adsorption of benzoic acid onto the different surfaces decreases in the order: synthetic calcite, chalk, kaolinite and quartz. Also a marked difference in adsorption behaviour between probes with different functional groups onto synthetic calcite from organic phase is observed. The maximum adsorption decreases in the order: benzoic acid, benzyl alcohol and benzylamine. (au) 54 refs.

  11. Using Raman spectroscopic imaging for non-destructive analysis of filler distribution in chalk filled polypropylene

    DEFF Research Database (Denmark)

    Boros, Evelin; Porse, Peter Bak; Nielsen, Inga

    2016-01-01

    A feasibility study on using Raman spectral imaging for visualization and analysis of filler distribution in chalk filled poly-propylene samples has been carried out. The spectral images were acquired using a Raman spectrometer with 785 nm light source.Eight injection-molded samples with concentr...

  12. Rock physical aspects of CO{sub 2} injection in chalk

    Energy Technology Data Exchange (ETDEWEB)

    Alam, M.M.

    2011-04-15

    Impact of supercritical CO{sub 2} on the petrophysical and rock-mechanics properties of Ekofisk Formation and Tor Formation chalk from South Arne field, Danish North Sea, chalk was investigated. A series of laboratory experiments was performed on core material collected from the reservoir zone of the South Arne field in order to reveal the changes with respect to porosity, specific surface, pore stiffness, wettability, mineralogy and mechanical failure. In addition, a theoretical rock physical background was also established in order to be able to make sensible interpretation of laboratory data. Sound wave velocity was used as the central tool to study any change in petrophysical and rock mechanical properties. The main focus was to achieve a better understanding of effective stress coefficient (also known as Biot's coefficient); by means of which effective stress can be predicted more accurately. Independent theoretical studies were made on diagenesis, surface properties and stiffness of chalk and their relation with sonic velocity (or Biot's coefficient calculated from sonic velocity). The knowledge and experience from these studies was combined to achieve the main research objective of monitoring changes in hydrocarbon reservoirs in chalk due to CO{sub 2} injection. In order to understand the development of chalk from calcareous ooze and achieving pore stiffness, the diagenesis process of a sedimentary sequence from Kerguelen Plateau in the Indian Ocean was studied. The principal objective of the study was to explore how different porosity reduction mechanisms change the strength of these deep sea carbonate-rich sediments and how these mechanisms can be traced from the change in Biot's coefficient, alpha. In calcareous ooze, alpha was found close to one. Mechanical compaction reduces porosity, but only leads to a minor decrease in alpha. Recrystallization process renders particles smoother, but do not lead to reduction in alpha unless it gives

  13. Tilting oil-water contact in the chalk of Tyra Field as interpreted from capillary pressure data

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Rana, M.A.

    2010-01-01

    The Tyra Field in the central North Sea is located in Palaeogene and Upper Cretaceous chalk. It contains a natural gas zone underlain by an oil leg. Based on analysis of logs and core data from ten wells drilled prior to the field being put into production, normalized water saturation depth-trend...... inequilibriumin the aquifer following tectonic tilting....

  14. Chalk: composition, diagenesis and physical properties

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2007-01-01

    Chalk is a sedimentary rock of unusually high homogeneity on the scale where physical properties are measured, but the properties fall in wide ranges. Chalk may thus be seen as the ideal starting point for a physical understanding of rocks in general. Properties as porosity, permeability, capillary...... involving clay, silica, and calcite are interlinked, but progress differently in different localities. This partly depends on primary sediment composition, including organic content, which may induce the formation of concretions by microbial action. The diagenetic processes also depend on water depth, rate...

  15. Wettability of Chalk and Argillaceous Sandstones Assessed from T1/T2 Ratio

    DEFF Research Database (Denmark)

    Katika, Konstantina; Saidian, M.; Fabricius, Ida Lykke

    ratio can quantify the affinity between the rock and wetting pore fluid. The affinity is a measure directly linked to wettability. In order to investigate the T2-shortening, we performed T1-T2 NMR experiments on different samples of chalk, Berea sandstone, and chloritic greensand, saturated either...... with water, oil or oil/water at irreducible water saturation. The T1/T2 ratio obtained from T1-T2 maps reflects the T2-shortening. We compare the T1/T2 ratio for the same type of rock, saturated with different fluids. The chalk shows high affinity for water, Berea sandstone has no clear preference for oil...

  16. Quantitative NMR measurements on core samples

    International Nuclear Information System (INIS)

    Olsen, Dan

    1997-01-01

    Within the frame of an EFP-95 project NMR methods for porosity determination in 2D, and for fluid saturation determination in 1D and 2D have been developed. The three methods have been developed and tested on cleaned core samples of chalk from the Danish North Sea. The main restriction for the use of the methods is the inherently short T2 relaxation constants of rock samples. Referring to measurements conducted at 200 MHz, the 2D porosity determination method is applicable to sample material with T2 relaxation constants down to 5 ms. The 1D fluid saturation determination method is applicable to sample material with T2 relaxation constants down to 3 ms, while the 2D fluid saturation determination method is applicable to material with T2 relaxation constants down to 8 ms. In the case of the 2D methods these constraints as a minimum enables work on the majority of chalk samples of Maastrichtian age. The 1D fluid saturation determination method in addition is applicable to at least some chalk samples of Danian and pre-Maastrichtian age. The spatial resolution of the 2D porosity determination method, the 1D fluid saturation methods, and the 2D fluid saturation method is respectively 0.8 mm, 0.8 mm and 2 mm. Reproducibility of pixel values is for all three methods 2%- points. (au)

  17. Certified reference material for radionuclides in fish flesh sample IAEA-414 (mixed fish from the Irish Sea and North Sea)

    DEFF Research Database (Denmark)

    Pham, M.K.; Sanchez-Cabeza, J.A.; Povinec, P.P.

    2006-01-01

    A certified reference material (CRM) for radionuclides in fish sample IAEA-414 (mixed fish from the Irish Sea and North Seas) is described and the results of the certification process are presented. Nine radionuclides (K-40, Cs-137, Th-232, U-234, U-235, U-238, Pu-238, Pu239+240 and Am-241) were...... ratios are also included. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in fish sample, for the development and validation of analytical methods and for training purposes. The material is available from IAEA, Vienna, in 100 g units. (c) 2006 Elsevier Ltd. All...

  18. Stylolites, porosity, depositional texture, and silicates in chalk facies sediments

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke; Borre, Mai K.

    2007-01-01

    dissolution around 490 m below sea floor (bsf) corresponds to an interval of waning porosity-decline, and even the occurrence of proper stylolites from 830 m bsf is accompanied by only minor porosity reduction. Because opal is present, the pore-water is relatively rich in Si which through the formation of Ca......-silica complexes causes an apparent super-saturation of Ca and retards cementation. The onset of massive pore-filling cementation at 1100 m bsf may be controlled by the temperature-dependent transition from opal-CT to quartz. In the stylolite-bearing chalk of two wells in the Gorm and Tyra fields, the nannofossil...... matrix shows recrystallization but only minor pore-filling cement, whereas microfossils are cemented. Cementation in Gorm and Tyra is thus partial and has apparently not been retarded by opal-controlled pore-water. A possible explanation is that, due to the relatively high temperature, silica has...

  19. The End of "Chalk and Talk"

    Science.gov (United States)

    Barlow, Tim

    2012-01-01

    "Chalk and talk" had been the staple pedagogical approach of my Science teaching practice since entering the profession. I felt that there was a great deal of information that I must impart to my students. My tried and tested way to deliver information to my students had always been simply to stand in front of them and tell it to them... So what…

  20. Process for treating oil-chalk

    Energy Technology Data Exchange (ETDEWEB)

    1925-10-20

    A process for treating oil-chalk or similar oil-containing minerals is characterized in that the material is treated in a stream of air diluted with indifferent gases at a temperature of about 150/sup 0/ to 160/sup 0/C.

  1. Stronger at Depth: Jamming Grippers as Deep Sea Sampling Tools.

    Science.gov (United States)

    Licht, Stephen; Collins, Everett; Mendes, Manuel Lopes; Baxter, Christopher

    2017-12-01

    In this work we experimentally demonstrate (a) that the holding strength of universal jamming grippers increases as a function of the jamming pressure to greater than three atmospheres, and (b) that jamming grippers can be operated in the deep sea in ambient pressures exceeding one hundred atmospheres, where such high jamming pressures can be readily achieved. Laboratory experiments in a pressurized, water-filled test cell are used to measure the holding force of a "universal" style jamming gripper as a function of the pressure difference between internal membrane pressure and ambient pressure. Experiments at sea are used to demonstrate that jamming grippers can be installed on, and operated from, remotely operated vehicles at depths in excess of 1200 m. In both experiments, the jamming gripper consists of a latex balloon filled with a mixture of fresh water and ∼200 μm glass beads, which are cheaply available in large quantities as sand blasting media. The use of a liquid, rather than a gas, as the fluid media allows operation of the gripper with a closed-loop fluid system; jamming pressure is controlled with an electrically driven water hydraulic cylinder in the laboratory and with an oil hydraulic-driven large-bore water hydraulic cylinder at sea.

  2. [Bacterial diversity within different sections of summer sea-ice samples from the Prydz Bay, Antarctica].

    Science.gov (United States)

    Ma, Jifei; Du, Zongjun; Luo, Wei; Yu, Yong; Zeng, Yixin; Chen, Bo; Li, Huirong

    2013-02-04

    In order to assess bacterial abundance and diversity within three different sections of summer sea-ice samples collected from the Prydz Bay, Antarctica. Fluorescence in situ hybridization was applied to determine the proportions of Bacteria in sea-ice. Bacterial community composition within sea ice was analyzed by 16S rRNA gene clone library construction. Correlation analysis was performed between the physicochemical parameters and the bacterial diversity and abundance within sea ice. The result of fluorescence in situ hybridization shows that bacteria were abundant in the bottom section, and the concentration of total organic carbon, total organic nitrogen and phosphate may be the main factors for bacterial abundance. In bacterial 16S rRNA gene libraries of sea-ice, nearly complete 16S rRNA gene sequences were grouped into three distinct lineages of Bacteria (gamma-Proteobacteria, alpha-Proteobacteria and Bacteroidetes). Most clone sequences were related to cultured bacterial isolates from the marine environment, arctic and Antarctic sea-ice with high similarity. The member of Bacteroidetes was not detected in the bottom section of sea-ice. The bacterial communities within sea-ice were little heterogeneous at the genus-level between different sections, and the concentration of NH4+ may cause this distribution. The number of bacteria was abundant in the bottom section of sea-ice. Gamma-proteobacteria was the dominant bacterial lineage in sea-ice.

  3. Assessing the sampling strategy in the Northwestern Mediterranean Sea

    Science.gov (United States)

    Margirier, Félix; Testor, Pierre; Bosse, Anthony; Heslop, Emma; L'Hévéder, Blandine; Arsouze, Thomas; Houpert, Loic; Mortier, Laurent

    2017-04-01

    The deployment of numerous autonomous platforms (gliders, argo floats, moorings) added to the repeated ship cruises in the Northwestern Mediterranean Sea account for a considerable data coverage of the area through the past 10 years. In this study, we analyse the in-situ observations' ability to assess for the changes in the Northwester Mediterranean basin water masses properties over time. Comparing the observed time series for the different regions and different water masses to that of a glider simulator in the NEMO-Med12 model, we estimate both the quality of the model and the skill of the in-situ observations in reproducing the evolution of the basin properties.

  4. AFSC/ABL: 2008 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2008 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

  5. AFSC/ABL: 2007 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2007 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

  6. AFSC/ABL: 2012 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch from the 2012 Bering Sea walleye pollock (Gadus chalcogrammus) trawl fishery was...

  7. AFSC/ABL: 2009 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2009 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

  8. AFSC/ABL: 2010 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2010 Bering Sea groundfish trawl fishery was undertaken to determine the...

  9. AFSC/ABL: 2011 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch from the 2011 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

  10. AFSC/ABL: 2005 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2005 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

  11. AFSC/ABL: 2006 Chum Salmon Bycatch Sample Analysis Bering Sea

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — A genetic analysis of samples from the chum salmon (Oncorhynchus keta) bycatch of the 2006 Bering Sea walleye pollock (Theragra chalcogramma) trawl fishery was...

  12. Radioactivity levels in some sediment samples from Red Sea and Baltic Sea

    International Nuclear Information System (INIS)

    Salahel Din, K.; Vesterbacka, P.

    2012-01-01

    Levels of 226, 228 Ra, 232 Th, 210 Pb, 210 Po and 40 K in sediments from four monitoring areas, El Hamraween and Ras El Behar (Red Sea (Egypt)) and LL3A and JML (Baltic Sea (Finland)), have been investigated using alpha and gamma spectrometry. The average activity concentrations were 238±4 Bq kg -1 ( 226 Ra), 215±11 Bq kg -1 ( 210 Pb) and 311±18 Bq kg -1 ( 210 Po) for El Hamraween area. In Ras El Behar area, the corresponding values were 16±0.4, 18±1 and 20±5 Bq kg -1 , respectively. The activity concentrations for 226 Ra, 210 Pb and 210 Po (uranium series) in El Hamraween bottom sediment are much high compared with those in Ras El Behar area, which indicates the enhanced levels due to the activities of phosphate mining and shipment operations in El Hamraween area. Excluding the influence of phosphate mining activities, it can be concluded that the levels of radioactivity in Baltic Sea sediments are higher than those in Red Sea sediments. (authors)

  13. Origin of channel systems in the Upper Cretaceous chalk group of the Paris Basin

    DEFF Research Database (Denmark)

    Esmerode, E. V.; Surlyk, Finn

    2009-01-01

    the presence of at least two distinct intra-chalk discordant reflections: a Top Santonian and a Mid-Campanian reflection. These reflections are in places associated with up to 120-m-deep channel-like structures trending preferentially N-S and NW-SE. The Mid-Campanian reflection is also sporadically associated...... with a massive secondary dolomite layer, the thicknesses of which may reach 110 m. Diagenesis does not seem to account for the formation of the discordant reflections, as there is neither a one-to-one relationship between the dolomite and discordant reflections, nor are there signs of systematic collapse...... is suggested due to the uninterrupted deep-marine chalk facies below and above both unconformities, and the unrealistically large sea-level drop of more than 200 m, which would be necessary for subaerial exposure of the central Paris Basin during the Campanian. The channels are oriented parallel to the margins...

  14. Radiocarbon dating with the Chalk River MP Tandem accelerator

    International Nuclear Information System (INIS)

    Ball, G.C.; Andrews, H.R.; Brown, R.M.; Burn, N.; Davies, W.G.; Imahori, Y.; Milton, J.C.D.

    1981-01-01

    During the past three years an automated radiocarbon dating system based on the MP Tandem accelerator has been developed for the analysis of 14 C in groundwater samples from the nuclear waste disposal research program and other small samples of scientific interest. At the present time 14 C/ 12 C ratio measurements can be determined with an accuracy of about 5% and the system background levels (approx. 35000 to 45000 years) are totally determined by sample and/or ion source contamination. Our goal has been to develop a dedicated reliable system for routine analysis that will produce accurate results with a minimum expenditure of human resources and accelerator beam time. Improvements required to operate the tandem accelerator as a quantitative tool have also benefited the rest of the experimental nuclear physics program. The early evolution of the dating facility was described previously. This paper is a brief report of the current status at Chalk River

  15. Influence of effective stress coefficient on mechanical failure of chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Fabricius, Ida Lykke; Hjuler, M.L.

    2012-01-01

    The Effective stress coefficient is a measure of how chalk grains are connected with each other. The stiffness of chalk may decrease if the amount of contact cements between the grains decreases, which may lead to an increase of the effective stress coefficient. We performed CO2 injection in chal...... precise failure strength of chalk during changed stress state and under the influence of chemically reactive fluids during production of hydrocarbon and geological storage CO2....

  16. Effect of Fluid Dynamic Viscosity on the Strength of Chalk

    DEFF Research Database (Denmark)

    Hedegaard, K.; Fabricius, Ida Lykke

    The mechanical strength of high porosity and weakly cemented chalk is affected by the fluid in the pores. In this study, the effect of the dynamic viscosity of non-polar fluids has been measured on outcrop chalk from Sigerslev Quarry, Stevns, Denmark. The outcome is that the measured strength...... of the chalk decreases with increasing dynamic viscosity. The proposed qualitative explanation is that pressure difference supports and enhances the generation of microscopic shear and tensile failures....

  17. Certified reference material for radionuclides in fish flesh sample IAEA-414 (mixed fish from the Irish Sea and North Sea)

    International Nuclear Information System (INIS)

    Pham, M.K.; Sanchez-Cabeza, J.A.; Povinec, P.P.; Arnold, D.; Benmansour, M.; Bojanowski, R.; Carvalho, F.P.; Kim, C.K.; Esposito, M.; Gastaud, J.; Gasco, C.L.; Ham, G.J.; Hegde, A.G.; Holm, E.; Jaskierowicz, D.; Kanisch, G.; Llaurado, M.; La Rosa, J.; Lee, S.-H.; Liong Wee Kwong, L.; Le Petit, G.; Maruo, Y.; Nielsen, S.P.; Oh, J.-S.; Oregioni, B.; Palomares, J.; Pettersson, H.B.L.; Rulik, P.; Ryan, T.P.; Sato, K.; Schikowski, J.; Skwarzec, B.; Smedley, P.A.; Tarjan, S.; Vajda, N.; Wyse, E.

    2006-01-01

    A certified reference material (CRM) for radionuclides in fish sample IAEA-414 (mixed fish from the Irish Sea and North Seas) is described and the results of the certification process are presented. Nine radionuclides ( 4 K, 137 Cs, 232 Th, 234 U, 235 U, 238 U, 238 Pu, 239+24 Pu and 241 Am) were certified for this material. Information on massic activities with 95% confidence intervals is given for six other radionuclides ( 9 Sr, 21 Pb( 21 Po), 226 Ra, 239 Pu, 24 Pu 241 Pu). Less frequently reported radionuclides ( 99 Tc, 129 I, 228 Th, 23 Th and 237 Np) and information on some activity and mass ratios are also included. The CRM can be used for quality assurance/quality control of the analysis of radionuclides in fish sample, for the development and validation of analytical methods and for training purposes. The material is available from IAEA, Vienna, in 100 g units

  18. Can we get a better knowledge on dissolution processes in chalk by using microfluidic chips?

    Science.gov (United States)

    Neuville, Amélie; Minde, Mona; Renaud, Louis; Vinningland, Jan Ludvig; Dysthe, Dag Kristian; Hiorth, Aksel

    2017-04-01

    This work has been initiated in the context of research on improving the oil recovery in chalk bedrocks. One of the methods to improve the oil recovery is to inject "smart water" (acidic water/brines). Experiments on core scale and field tests that have been carried out the last decade have clearly shown that water chemistry affects the final oil recovery. However, there is generally no consensus in the scientific community of why additional oil is released, and it is also still not understood what are the mineralogical and structural changes. Direct in situ observation of the structural changes that occur when chalk is flooded with brines could resolve many of the open questions that remain. One of the highlights of this work is thus the development of an innovative methodology where fluid/rock interactions are observed in-situ by microscopy. To do so, we create several types of custom-made microfluidic systems that embeds reactive materials like chalk and calcite. The methodology we develop can be applied to other reactive materials. We will present an experiment where a calcite window dissolves with a fluid, where we observe in-situ the topography features of the calcite window, as well as the dissolution rate [1]. The injected fluid circulates at controlled flowrates in a channel which is obtained by xurography: double sided tape is cut out with a cutter plotter and placed between the reactive window and a non-reactive support. While the calcite window reacts, its topography is measured in situ every 10 s using an interference microscope, with a pixel resolution of 4.9 μm and a vertical resolution of 50 nm. These experiments are also compared with reactive flow simulations done with Lattice Boltzmann methods. Then, we will present a dissolution experiment done with a microfluidic system that embeds chalk. In this experiment, the main flow takes place at the chalk surface, in contact with fluid flowing in a channel above the chalk sample. Thus the reaction

  19. Isotope hydrology of the Chalk River Laboratories site, Ontario, Canada

    Science.gov (United States)

    Peterman, Zell; Neymark, Leonid; King-Sharp, K.J.; Gascoyne, Mel

    2016-01-01

    This paper presents results of hydrochemical and isotopic analyses of groundwater (fracture water) and porewater, and physical property and water content measurements of bedrock core at the Chalk River Laboratories (CRL) site in Ontario. Density and water contents were determined and water-loss porosity values were calculated for core samples. Average and standard deviations of density and water-loss porosity of 50 core samples from four boreholes are 2.73 ± 12 g/cc and 1.32 ± 1.24 percent. Respective median values are 2.68 and 0.83 indicating a positive skewness in the distributions. Groundwater samples from four deep boreholes were analyzed for strontium (87Sr/86Sr) and uranium (234U/238U) isotope ratios. Oxygen and hydrogen isotope analyses and selected solute concentrations determined by CRL are included for comparison. Groundwater from borehole CRG-1 in a zone between approximately +60 and −240 m elevation is relatively depleted in δ18O and δ2H perhaps reflecting a slug of water recharged during colder climatic conditions. Porewater was extracted from core samples by centrifugation and analyzed for major dissolved ions and for strontium and uranium isotopes. On average, the extracted water contains 15 times larger concentration of solutes than the groundwater. 234U/238U and correlation of 87Sr/86Sr with Rb/Sr values indicate that the porewater may be substantially older than the groundwater. Results of this study show that the Precambrian gneisses at Chalk River are similar in physical properties and hydrochemical aspects to crystalline rocks being considered for the construction of nuclear waste repositories in other regions.

  20. Ion Chromatographic Analyses of Sea Waters, Brines and Related Samples

    OpenAIRE

    Nataša Gros

    2013-01-01

    This review focuses on the ion chromatographic methods for the analyses of natural waters with high ionic strength. At the beginning a natural diversity in ionic composition of waters is highlighted and terminology clarified. In continuation a brief overview of other review articles of potential interest is given. A review of ion chromatographic methods is organized in four sections. The first section comprises articles focused on the determination of ionic composition of water samples as com...

  1. Ion Chromatographic Analyses of Sea Waters, Brines and Related Samples

    Directory of Open Access Journals (Sweden)

    Nataša Gros

    2013-06-01

    Full Text Available This review focuses on the ion chromatographic methods for the analyses of natural waters with high ionic strength. At the beginning a natural diversity in ionic composition of waters is highlighted and terminology clarified. In continuation a brief overview of other review articles of potential interest is given. A review of ion chromatographic methods is organized in four sections. The first section comprises articles focused on the determination of ionic composition of water samples as completely as possible. The sections—Selected Anions, Selected Cations and Metals—follow. The most essential experimental conditions used in different methods are summarized in tables for a rapid comparison. Techniques encountered in the reviewed articles comprise: direct determinations of ions in untreated samples with ion- or ion-exclusion chromatography, or electrostatic ion chromatography; matrix elimination with column-switching; pre-concentration with a chelation ion chromatography and purge-and-trap pre-concentration. Different detection methods were used: non-suppressed conductometric or suppressed conductometric, direct spectrometric or spectrometric after a post-column derivetization, and inductively coupled plasma in combination with optical emission or mass spectrometry.

  2. Caoxite-hydroxyapatite composition as consolidating material for the chalk stone from Basarabi-Murfatlar churches ensemble

    Science.gov (United States)

    Ion, Rodica-Mariana; Turcanu-Caruţiu, Daniela; Fierăscu, Radu-Claudiu; Fierăscu, Irina; Bunghez, Ioana-Raluca; Ion, Mihaela-Lucia; Teodorescu, Sofia; Vasilievici, Gabriel; Rădiţoiu, Valentin

    2015-12-01

    The development of new composition for surface conservation of some architectural monuments represents now an important research topic. The Basarabi-Murfatlar Ensemble, recognized as the first religious monument from mediaeval Dobrogea (Romania) (from 9th to 11th century), is one of the most impressive archaeological sites of Europe. This ensemble is built from amorphous calcium carbonate, very sensitive to humidity, frost, salts, etc. The aim of this paper is to test on chalk stone samples a new consolidant - hydroxyapatite (HAp) mixed with calcium oxalate trihydrate (caoxite) (COT). Some specific techniques for evaluation its impact on chalk stone surface are used, as follows: petrographical and physical-chemical techniques: SEM, OM, ICP-AES, TGA, FTIR and Raman spectroscopy, chromatic parameters changes, the accelerated weathering tests: heating, freeze-thaw, and their effects on porosity and capillary water uptake by the chalk surface. All these have been evaluated before and after treatment with COT-HAp, putting into evidence the effect of the new composition on the chalk stone surface. HAp induces COT stabilization, and their joint composition can bind weathered stone blocks providing a substantial reinforcement of chalk surface.

  3. Dissection of genetic architecture of grain chalk using NIR spectroscopy

    Science.gov (United States)

    Chalk is a major quality characteristic that causes grain breakage during milling and loss of crop value. In this study, we sought to elucidate the quantitatively inherited grain chalk trait in rice and to conduct genome-wide association mapping to identify SNPs and candidate genes associated with ...

  4. Trial coring in LLRW trenches at Chalk River

    International Nuclear Information System (INIS)

    Donders, R.E.; Killey, R.W.D.; Franklin, K.J.; Strobel, G.S.

    1996-11-01

    As part of a program to better characterize the low-hazard radioactive waste managed by AECL at Chalk River Laboratories, coring techniques in waste trenches are being assessed. Trial coring has demonstrated that sampling in waste regions is possible, and that boreholes can be placed through the waste trenches. Such coring provides a valuable information-gathering technique. Information available from trench coring includes: trench cover depth, waste region depth, waste compaction level, and detailed stratigraphic data; soil moisture content and facility drainage performance; borehole gamma logs that indicate radiation levels in the region of the borehole; biochemical conditions in the waste regions, vadose zone, and groundwater; site specific information relevant to contaminant migration modelling or remedial actions; information on contaminant releases and inventories. Boreholes through the trenches can also provide a means for early detection of potential contaminant releases. (author). 4 refs., 4 tabs., 4 figs

  5. Chalk effect on PVC cross-linking under irradiation

    International Nuclear Information System (INIS)

    Chudinova, V.V.; Guzeev, V.V.; Mozzhukhin, V.B.; Pomerantseva, Eh.G.; Nozrina, F.D.; Zhil'tsov, V.V.; Zubov, V.P.

    1994-01-01

    Effect of nonmodified and modified chalk on curing degree of polymer matrix was studied under-irradiation of PVC-compositions. Films of the compositions (100 mass part 7 PVC, 0-100 mas.part of chalk, 2.5 - lead sulfate, 1.5 - lead stearate and 0.3 - glycerin) were irradiated up to absorbed dose 0.1 MGy in an inert medium. Content of gel-fraction after boiling in THF was determined with use of IR spectroscopy. It was established, that intensive dehydrochlorination and polymer curing took place on chalk particle surface. Network fixed strongly chalk particles. However, chalk inhibited processes of dehydrochlorination and PVC curing, increasing amount of noncured PVC in polymer matrix

  6. Controls on Cementation in a Chalk Reservoir

    DEFF Research Database (Denmark)

    Meireles, Leonardo Teixeira Pinto; Hussein, A.; Welch, M.J.

    In this study, we identify different controls on cementation in a chalk reservoir. Biot’s coefficient, a measure of cementation, stiffness and strength in porous rocks, is calculated from logging data (bulk density and sonic Pwave velocity). We show that Biot’s coefficient is correlated...... to the water saturation of the Kraka reservoir and is partly controlled by its stratigraphic sub-units. While the direct causal relationship between Biot’s coefficient and water saturation cannot be extended for Biot’s coefficient and porosity, a correlation is also identified between the two, implying...

  7. Controls on Cementation in a Chalk Reservoir

    DEFF Research Database (Denmark)

    Meireles, Leonardo Teixeira Pinto; Hussein, A.; Welch, M.J.

    2017-01-01

    In this study, we identify different controls on cementation in a chalk reservoir. Biot’s coefficient, a measure of cementation, stiffness and strength in porous rocks, is calculated from logging data (bulk density and sonic Pwave velocity). We show that Biot’s coefficient is correlated...... that some degree of pore filling cementation occurred in Kraka (Alam, 2010). Lack of correlation between Biot’s coefficient and Gamma Ray (GR) indicates that the small amount of clay present is generally located in the pore space, thus not contributing to frame stiffness. While there was no compositional...... control on cementation via clay, we could infer that stratigraphy impacts on the diagenetic process....

  8. A comparative study of the adsorption of uranium on commercial and natural (Cypriot) sea sand samples

    International Nuclear Information System (INIS)

    Maria Efstathiou; Ioannis Pashalidis

    2013-01-01

    The adsorption of hexavalent uranium on two different types of sea sand [e.g. a local, Cypriot (N S S) and a commercially available marine sediment (C S S)] has been investigated as a function of pH, initial metal concentration, ionic strength and contact time under normal atmospheric conditions. Before carrying out the adsorption experiments, the sea sand samples have been characterized by XRD, XRF, N 2 -adsorption, acid/base titrations and FTIR spectroscopy. Sample characterization showed clearly that the two sea sand types differ significantly in their composition, particularly in their calcite and FeOOH content. According to experimental data obtained from acid/base titrations and adsorption batch experiments sea sand composition affects the acid/base and the adsorption properties of the adsorbents. The extraordinary high affinity of N S S for hexavalent uranium in the alkaline pH region can be attributed to the formation of mixed U(VI)-carbonato surface species on the FeOOH crystal phases present in N S S, which effectively compete the formation of U(VI)-carbonato complexes in solution. On the other hand, data obtained by adsorption experiments carried out in solution of different ionic strengths don't differ significantly from one another indicating the formation of inner-sphere complexes. Finally, the adsorption on sea sands is a relatively fast two-step process. (author)

  9. Uranium and plutonium containing particles in a sea sediment sample from Thule, Greenland

    DEFF Research Database (Denmark)

    Moring, M.; Ikäheimonen, T.K.; Pöllänen, R.

    2001-01-01

    Particles composed of radioactive materials and probably originating from US nuclear weapons were identified in sea sediment samples collected from Thule, Greenland in 1997. The weapons were destroyed close to the Thule Air Base in 1968 in an aeroplane crash, which dispersed radioactive materials...

  10. Regional transport of radioxenon released from the Chalk River Laboratories medical isotope facility

    International Nuclear Information System (INIS)

    Christine Johnson; Steven Biegalski

    2015-01-01

    An examination of proposed sampling sites near Chalk River Laboratories in Ontario, Canada is performed by considering the regional transport of radioxenon using atmospheric dispersion modeling. The local geography is considered, as are the local meteorological conditions during the summer months. In particular the impacts of predicted conditions on the imprinting of atmospheric radioxenon into the subsurface are considered and weighed against site proximity, geography, and geology. (author)

  11. Chalk Catchment Transit Time: Unresolved Issues

    Energy Technology Data Exchange (ETDEWEB)

    Darling, W. G.; Gooddy, D. C. [British Geological Survey, Crowmarsh Gifford, Wallingford, Oxfordshire (United Kingdom); Barker, J. A. [School of Civil Engineering and the Environment, University of Southampton, Southampton (United Kingdom); Robinson, M. [Centre for Ecology and Hydrology, Crowmarsh Gifford, Wallingford, Oxfordshire (United Kingdom)

    2013-07-15

    The mean transit time (MTT) of a catchment is the average residence time of water from rainfall to river outflow at the foot of the catchment. As such, MTT has important water quality as well as resource implications. Many catchments worldwide have been measured for MTT using environmental isotopes, yet the Chalk, an important aquifer in NW Europe, has received little attention in this regard. The catchment of the River Lambourn in southern England has been intermittently studied since the 1960s using isotopic methods. A tritium peak measured in the river during the 1970s indicates an apparent MTT of {approx}15 years, but the thick unsaturated zone (average {approx}50 m) of the catchment suggests that the MTT should be much greater because of the average downward movement through the Chalk of {approx}1 m/a consistently indicated by tritium and other tracers. Recent work in the catchment using SF{sub 6} as a residence time indicator has given groundwater ages in the narrow range 11-18 yrs, apparently supporting the river tritium data but in conflict with the unsaturated zone data even allowing for a moderate proportion of rapid bypass flow. The MTT of the catchment remains unresolved for the time being. (author)

  12. Elasticity and electrical resistivity of chalk and greensand during water flooding with selective ions

    DEFF Research Database (Denmark)

    Katika, Konstantina; Alam, Mohammad Monzurul; Alexeev, Artem

    2018-01-01

    is water-wet after flooding. Greensand remained mixed wet throughout the experiments. Electrical resistivity data are in agreement with this interpretation. The electrical resistivity data during flooding revealed that the formation brine is not fully replaced by the injected water in both chalk......Water flooding with selective ions has in some cases lead to increased oil recovery. We investigate the physical processes on a pore scale that are responsible for changes in petrophysical and mechanical properties of four oil-bearing chalk and four oil-bearing greensand samples caused by flooding...... with brines containing varying amounts of dissolved NaCl, Na2SO4, MgCl2 and MgSO4. Ultrasonic P-wave velocity and AC resistivity measurements were performed prior to, during and after flow through experiments in order to identify and quantify the processes related to water flooding with selective ions. Low...

  13. Kolmanda aastatuhande piraadid / kommenteerinud Peter Chalk ja Gordan Van Hook

    Index Scriptorium Estoniae

    2009-01-01

    Piraatlusest Somaalia piirkonnas ja rahvusvahelistest dokumentidest piraatluse vastu võitlemiseks 21. sajandil. Kommenteerivad uurimiskeskuse RAND Corporation vanempoliitanalüütik Peter Chalk ja transpordikompanii Maersk Line innovatsiooni ja arenduse vanemdirektor Gordan Van Hook

  14. Natural radioactivity in environmental samples from an island of volcanic origin (Milos, Aegean Sea)

    International Nuclear Information System (INIS)

    Florou, H.; Kritidis, P.

    1991-01-01

    Enhanced concentrations of natural radionuclides occur in volcanic islands such as Milos in the Aegean Sea. The natural gamma radiation status of the entire environment in Milos were studied using gamma radiometry. Gamma spectrometry was used to analyse ore samples, sediments and marine biota. While non-living materials showed enhanced levels of natural radioactivity, most of the marine organisms examined did not seem to reflect this radiological status. (UK)

  15. Observing System Simulation Experiments for the assessment of temperature sampling strategies in the Mediterranean Sea

    Directory of Open Access Journals (Sweden)

    F. Raicich

    2003-01-01

    Full Text Available For the first time in the Mediterranean Sea various temperature sampling strategies are studied and compared to each other by means of the Observing System Simulation Experiment technique. Their usefulness in the framework of the Mediterranean Forecasting System (MFS is assessed by quantifying their impact in a Mediterranean General Circulation Model in numerical twin experiments via univariate data assimilation of temperature profiles in summer and winter conditions. Data assimilation is performed by means of the optimal interpolation algorithm implemented in the SOFA (System for Ocean Forecasting and Analysis code. The sampling strategies studied here include various combinations of eXpendable BathyThermograph (XBT profiles collected along Volunteer Observing Ship (VOS tracks, Airborne XBTs (AXBTs and sea surface temperatures. The actual sampling strategy adopted in the MFS Pilot Project during the Targeted Operational Period (TOP, winter-spring 2000 is also studied. The data impact is quantified by the error reduction relative to the free run. The most effective sampling strategies determine 25–40% error reduction, depending on the season, the geographic area and the depth range. A qualitative relationship can be recognized in terms of the spread of information from the data positions, between basin circulation features and spatial patterns of the error reduction fields, as a function of different spatial and seasonal characteristics of the dynamics. The largest error reductions are observed when samplings are characterized by extensive spatial coverages, as in the cases of AXBTs and the combination of XBTs and surface temperatures. The sampling strategy adopted during the TOP is characterized by little impact, as a consequence of a sampling frequency that is too low. Key words. Oceanography: general (marginal and semi-enclosed seas; numerical modelling

  16. Observing System Simulation Experiments for the assessment of temperature sampling strategies in the Mediterranean Sea

    Directory of Open Access Journals (Sweden)

    F. Raicich

    Full Text Available For the first time in the Mediterranean Sea various temperature sampling strategies are studied and compared to each other by means of the Observing System Simulation Experiment technique. Their usefulness in the framework of the Mediterranean Forecasting System (MFS is assessed by quantifying their impact in a Mediterranean General Circulation Model in numerical twin experiments via univariate data assimilation of temperature profiles in summer and winter conditions. Data assimilation is performed by means of the optimal interpolation algorithm implemented in the SOFA (System for Ocean Forecasting and Analysis code. The sampling strategies studied here include various combinations of eXpendable BathyThermograph (XBT profiles collected along Volunteer Observing Ship (VOS tracks, Airborne XBTs (AXBTs and sea surface temperatures. The actual sampling strategy adopted in the MFS Pilot Project during the Targeted Operational Period (TOP, winter-spring 2000 is also studied.

    The data impact is quantified by the error reduction relative to the free run. The most effective sampling strategies determine 25–40% error reduction, depending on the season, the geographic area and the depth range. A qualitative relationship can be recognized in terms of the spread of information from the data positions, between basin circulation features and spatial patterns of the error reduction fields, as a function of different spatial and seasonal characteristics of the dynamics. The largest error reductions are observed when samplings are characterized by extensive spatial coverages, as in the cases of AXBTs and the combination of XBTs and surface temperatures. The sampling strategy adopted during the TOP is characterized by little impact, as a consequence of a sampling frequency that is too low.

    Key words. Oceanography: general (marginal and semi-enclosed seas; numerical modelling

  17. Radar sounding of bedrock and water table at Chalk River

    International Nuclear Information System (INIS)

    Annan, A.P.; Davis, J.L.

    1979-01-01

    When a spill of radioactive waste occurs, one of the main concerns is the flow pattern of ground water in the area of the spill. Ground probing radar is a relatively new geophysical technique which can provide high resolution data on the surficial geology and water distribution. The results of some preliminary radar experiments conducted at Chalk River Nuclear Laboratories (CRNL) of the Atomic Energy of Canada Limited (AECL), Chalk River, Ontario are presented. (auth)

  18. Statistical analysis of temperature data sampled at Station-M in the Norwegian Sea

    Science.gov (United States)

    Lorentzen, Torbjørn

    2014-02-01

    The paper analyzes sea temperature data sampled at Station-M in the Norwegian Sea. The data cover the period 1948-2010. The following questions are addressed: What type of stochastic process characterizes the temperature series? Are there any changes or patterns which indicate climate change? Are there any characteristics in the data which can be linked to the shrinking sea-ice in the Arctic area? Can the series be modeled consistently and applied in forecasting of the future sea temperature? The paper applies the following methods: Augmented Dickey-Fuller tests for testing of unit-root and stationarity, ARIMA-models in univariate modeling, cointegration and error-correcting models are applied in estimating short- and long-term dynamics of non-stationary series, Granger-causality tests in analyzing the interaction pattern between the deep and upper layer temperatures, and simultaneous equation systems are applied in forecasting future temperature. The paper shows that temperature at 2000 m Granger-causes temperature at 150 m, and that the 2000 m series can represent an important information carrier of the long-term development of the sea temperature in the geographical area. Descriptive statistics shows that the temperature level has been on a positive trend since the beginning of the 1980s which is also measured in most of the oceans in the North Atlantic. The analysis shows that the temperature series are cointegrated which means they share the same long-term stochastic trend and they do not diverge too far from each other. The measured long-term temperature increase is one of the factors that can explain the shrinking summer sea-ice in the Arctic region. The analysis shows that there is a significant negative correlation between the shrinking sea ice and the sea temperature at Station-M. The paper shows that the temperature forecasts are conditioned on the properties of the stochastic processes, causality pattern between the variables and specification of model

  19. Taxonomic analysis of extremely halophilic archaea isolated from 56-years-old dead sea brine samples.

    Science.gov (United States)

    Arahal, D R; Gutiérrez, M C; Volcani, B E; Ventosa, A

    2000-10-01

    A taxonomic study comprising both phenotypic and genotypic characterization, has been carried out on a total of 158 extremely halophilic aerobic archaeal strains. These strains were isolated from enrichments prepared from Dead Sea water samples dating from 1936 that were collected by B. E. Volcani for the demonstration of microbial life in the Dead Sea. The isolates were examined for 126 morphological, physiological, biochemical and nutritional tests. Numerical analysis of the data, by using the S(J) coefficient and UPGMA clustering method, showed that the isolates clustered into six phenons. Twenty-two out of the 158 strains used in this study were characterized previously (ARAHAL et al., 1996) and were placed into five phenotypic groups. The genotypic study included both the determination of the guanineplus-cytosine content of the DNA and DNA-DNA hybridization studies. For this purpose, representative strains from the six phenons were chosen. These groups were found to represent some members of three different genera - Haloarcula (phenons A, B, and C), Haloferax (phenons D and E) and Halobacterium (phenon F) - of the family Halobacteriaceae, some of them never reported to occur in the Dead Sea, such as Haloarcula hispanica, while Haloferax volcanii (phenons D and E) was described in the Dead Sea by studies carried out several decades later than Volcani's work.

  20. Technical Note: Comparison of storage strategies of sea surface microlayer samples

    Directory of Open Access Journals (Sweden)

    K. Schneider-Zapp

    2013-07-01

    Full Text Available The sea surface microlayer (SML is an important biogeochemical system whose physico-chemical analysis often necessitates some degree of sample storage. However, many SML components degrade with time so the development of optimal storage protocols is paramount. We here briefly review some commonly used treatment and storage protocols. Using freshwater and saline SML samples from a river estuary, we investigated temporal changes in surfactant activity (SA and the absorbance and fluorescence of chromophoric dissolved organic matter (CDOM over four weeks, following selected sample treatment and storage protocols. Some variability in the effectiveness of individual protocols most likely reflects sample provenance. None of the various protocols examined performed any better than dark storage at 4 °C without pre-treatment. We therefore recommend storing samples refrigerated in the dark.

  1. Seismic architecture of the Chalk Group from onshore reflection data in eastern Denmark

    DEFF Research Database (Denmark)

    Moreau, Julien; Anderskouv, Kresten; Boldreel, Lars Ole

    with the seismic stratigraphy. Several seismic facies are identified in the Chalk Group: the 'transparent' (white chalk), the stratified (marl-chalk alternations), the crudely stratified (flint-rich chalk) and the hummocky (bryozoan mounds). The units notably vary in thickness at a relatively small scale...... of the deformations appear to be restricted to the white chalk, whereas the stratified seismic facies are comparatively less disturbed. The origin of the structures observed in the white chalk can either be associated with the regional stress field or with differential diagenetic evolution between strata inducing...

  2. Elastic and electric properties of North Sea Chalk

    DEFF Research Database (Denmark)

    Olsen, Casper

    bjergartsfysiske modeller til forudsigelse af Biot’s koefficient ud fra porøsitet og én lydhastighed og hans resultater tyder på at Berryman’s udbredte ”Selfconsistent Model” er mindre velegnet til det formål, mens at de simplere Isoframe og Bound-averaging metoder giver bedre resultater. Dvorkin’s partikel...

  3. Controls on upper Campanian-Maastrichtian chalk deposition in the eastern Danish Basin

    DEFF Research Database (Denmark)

    Boussaha, Myriam; Thibault, Nicolas Rudolph; Anderskouv, Kresten

    2017-01-01

    % of the sediment. Sedimentation took place in deep water, below the photic zone and storm-wave base, and is characterized by decimetre to metre-scale variations in facies and trace fossil assemblages indicating repeated shifts in depositional environment. Integration of facies with published data on sea...... of accumulation rates and sea temperatures and is interpreted to represent a very broad set of deep water environmental conditions with an ample supply of calcareous nannofossil debris and intense bioturbation. Longer term shifts in deposition are best expressed by distribution of clay, flint and bioturbated...... micro-wackestone, bioturbated wackestone and laminated mudstone chalk facies, whereas the trace fossil assemblages appear less useful. The data set indicates overall shallowing over time with two distinctive events of clay influx to the basin during the late Campanian-earliest Maastrichtian and late...

  4. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from METEOR in the Adriatic Sea, Aegean Sea and others from 2011-04-05 to 2011-04-28 (NODC Accession 0108079)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108079 includes discrete sample and profile data collected from METEOR in the Adriatic Sea, Aegean Sea, Alboran Sea, Ionian Sea, Mediterranean Sea,...

  5. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA I in the Bali Sea, Banda Sea and others from 1994-01-28 to 1994-02-25 (NCEI Accession 0144624)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144624 includes discrete sample and profile data collected from BARUNA JAYA I in the Bali Sea, Banda Sea, Celebes Sea, Ceram Sea or Seram Sea, Flores...

  6. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA I in the Bali Sea, Banda Sea and others from 1993-08-08 to 1993-09-09 (NCEI Accession 0144623)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144623 includes discrete sample and profile data collected from BARUNA JAYA I in the Bali Sea, Banda Sea, Celebes Sea, Ceram Sea or Seram Sea, Flores...

  7. Intercomparison of radionuclide measurements in Baltic Sea water sample IAEA-299

    International Nuclear Information System (INIS)

    Ballestra, S.; Lopez, J.J.

    1993-03-01

    This report contains the results of the intercomparison exercise on IAEA-299 for the determination of 90 Sr, 134 Cs and 137 Cs concentration in Baltic Sea Water. The participants belong to 8 laboratories located in 6 countries, members of the Helsinki commission. Statistical evaluation of the data reported yields to recommended values for these elements. The elements, their recommended values and confidence intervals are listed here: 90 Sr: 13.6 Bq kg -1 (12.8-14.4); 134 Cs: 6.7 Bq kg -1 (5-8.3); 137 Cs: 70.9 Bq kg -1 (68-72.3). Reference date: 27 June 1991 (sampling date). The data reported by the laboratories of the Baltic Sea States are generally in very good agreement. (author)

  8. Investigation of Lecturer's Chalk by x-ray Florescence and Fast Neutron Activation Techniques

    International Nuclear Information System (INIS)

    Hassan, M.F.

    2011-01-01

    Different samples of lecturer's chalk were studied, using X-ray florescence (XRF) and Fast Neutron Activation Analysis (FNAA) techniques to ensure the safety of its use. The K (X-rays) and the gamma-rays were measured, using Si(Li) and high-purity germanium (HPGe) spectrometers to detect and determine qualitatively and quantitatively the constituents of the studied samples. The concentrations of the elements (Ca and small traces of Al, Fe, Mg and Si) were measured and their presence was confirmed by gamma-ray, lifetime and/or XRF measurements.

  9. Precise Th/U-dating of small and heavily coated samples of deep sea corals

    Science.gov (United States)

    Lomitschka, Michael; Mangini, Augusto

    1999-07-01

    Marine carbonate skeletons like deep-sea corals are frequently coated with iron and manganese oxides/hydroxides which adsorb additional thorium and uranium out of the sea water. A new cleaning procedure has been developed to reduce this contamination. In this further cleaning step a solution of Na 2EDTA (Na 2H 2T B) and ascorbic acid is used which composition is optimised especially for samples of 20 mg of weight. It was first tested on aliquots of a reef-building coral which had been artificially contaminated with powdered ferromanganese nodule. Applied on heavily contaminated deep-sea corals (scleractinia), it reduced excess 230Th by another order of magnitude in addition to usual cleaning procedures. The measurement of at least three fractions of different contamination, together with an additional standard correction for contaminated carbonates results in Th/U-ages corrected for the authigenic component. A good agreement between Th/U- and 14C-ages can be achieved even for extremely coated corals.

  10. Correlation of Heavy Element in Sea Water and Sediment Samples from Peninsula of Muria

    International Nuclear Information System (INIS)

    Rosidi; Sukirno

    2007-01-01

    The analysis of heavy metals in marine environmental samples peninsula of Muria in the year 2004 has been carried out by using neutron activation analysis (NAA) method. The objective of this analysis is to know the distribution of heavy metals in the sea water and sediment, which accommodate the recent environmental data in supporting the license of site for the nuclear power plants (NPP). The result of the analysis show that there were only 5 observed elements found in sea water and sediment were Cd, Co, Cr, Sb and Sc. All of heavy metals from sea water (0.002 mg/l) are obviously lower than the threshold value established by environmental minister Act; Kep LH No 51/2004. From the observed data to use software of SPSS version 10, application of the Pearson correlation (r) shows that between Co with Sc was indicator show a highly positive significant correlation (r=0.928), between Cr with Sc was sufficiently positive high (r=0.756), between Cr with Cd was precisely (r=0.611) while Co with Sb shows the significantly low (r=0.429). (author)

  11. A sterol and spiroditerpenoids from a Penicillium sp. isolated from a deep sea sediment sample.

    Science.gov (United States)

    Li, Yan; Ye, Dezan; Shao, Zongze; Cui, Chengbin; Che, Yongsheng

    2012-02-01

    A new polyoxygenated sterol, sterolic acid (1), three new breviane spiroditerpenoids, breviones I-K (2-4), and the known breviones (5-8), were isolated from the crude extract of a Penicillium sp. obtained from a deep sea sediment sample that was collected at a depth of 5115 m. The structures of 1-4 were elucidated primarily by NMR experiments, and 1 was further confirmed by X-ray crystallography. The absolute configurations of 2 and 3 were deduced by comparison of their CD spectra with those of the model compounds. Compounds 2 and 5 showed significant cytotoxicity against MCF-7 cells, which is comparable to the positive control cisplatin.

  12. The Chalk River Tritium Extraction Plant

    International Nuclear Information System (INIS)

    Holtslander, W.J.; Harrison, T.E.; Spagnolo, D.A.

    1990-01-01

    The Chalk River Tritium Extraction Plant for removal of tritium from heavy water is described. Tritium is present in the heavy water from research reactors in the form of DTO at a concentration in the range of 1-35 Ci/kg. It is removed by a combination of catalytic exchange to transfer the tritium from DTO to DT, followed by cryogenic distillation to separate and concentrate the tritium to T 2 . The tritium product is reacted with titanium and packaged for transportation and storage as titanium tritide. The plant processes heavy water at a rate of 25 kg/h and removes 80% of the tritium and 90% of the protium per pass. Catalytic exchange is carried out in the liquid phase using a proprietary wetproofed catalyst. The plant serves two roles in the Canadian fusion program: it produces pure tritium for use in fusion research and development, and it demonstrates on an industrial scale many of the tritium technologies that are common to the tritium systems in fusion reactors (author)

  13. The Chalk River Tritium Extraction Plant

    Energy Technology Data Exchange (ETDEWEB)

    Holtslander, W J; Harrison, T E; Spagnolo, D A

    1990-07-01

    The Chalk River Tritium Extraction Plant for removal of tritium from heavy water is described. Tritium is present in the heavy water from research reactors in the form of DTO at a concentration in the range of 1-35 Ci/kg. It is removed by a combination of catalytic exchange to transfer the tritium from DTO to DT, followed by cryogenic distillation to separate and concentrate the tritium to T{sub 2}. The tritium product is reacted with titanium and packaged for transportation and storage as titanium tritide. The plant processes heavy water at a rate of 25 kg/h and removes 80% of the tritium and 90% of the protium per pass. Catalytic exchange is carried out in the liquid phase using a proprietary wetproofed catalyst. The plant serves two roles in the Canadian fusion program: it produces pure tritium for use in fusion research and development, and it demonstrates on an industrial scale many of the tritium technologies that are common to the tritium systems in fusion reactors (author)

  14. Response of invertebrates from the hyporheic zone of chalk rivers to eutrophication and land use.

    Science.gov (United States)

    Pacioglu, Octavian; Moldovan, Oana Teodora

    2016-03-01

    Whereas the response of lotic benthic macroinvertebrates to different environmental stressors is a widespread practice nowadays in assessing the water and habitat quality, the use of hyporheic zone invertebrates is still in its infancy. In this study, classification and regression trees analysis were employed in order to assess the ecological requirements and the potential as bioindicators for the hyporheic zone invertebrates inhabiting four lowland chalk rivers (south England) with contrasting eutrophication levels (based on surface nitrate concentrations) and magnitude of land use (based on percentage of fine sediments load and median interstitial space). Samples of fauna, water and sediment were sampled twice, during low (summer) and high (winter) groundwater level, at depths of 20 and 35 cm. Certain groups of invertebrates (Glossosomatidae and Psychomyiidae caddisflies, and riffle beetles) proved to be good indicators of rural catchments, moderately eutrophic and with high fine sediment load. A diverse community dominated by microcrustaceans (copepods and ostracods) were found as good indicators of highly eutrophic urban streams, with moderate-high fine sediment load. However, the use of other taxonomic groups (e.g. chironomids, oligochaetes, nematodes, water mites and the amphipod Gammarus pulex), very widespread in the hyporheic zone of all sampled rivers, is of limited use because of their high tolerance to the analysed stressors. We recommend the use of certain taxonomic groups (comprising both meiofauna and macroinvertebrates) dwelling in the chalk hyporheic zone as indicators of eutrophication and colmation and, along with routine benthic sampling protocols, for a more comprehensive water and habitat quality assessment of chalk rivers.

  15. Ross Sea Mollusca from the Latitudinal Gradient Program: R/V Italica 2004 Rauschert dredge samples

    Directory of Open Access Journals (Sweden)

    Claudio Ghiglione

    2013-10-01

    Full Text Available Information regarding the molluscs in this dataset is based on the Rauschert dredge samples collected during the Latitudinal Gradient Program (LGP on board the R/V “Italica” in the Ross Sea (Antarctica in the austral summer 2004. A total of 18 epibenthic dredge deployments/samplings have been performed at four different locations at depths ranging from 84 to 515m by using a Rauschert dredge with a mesh size of 500µm. In total 8,359 specimens have been collected belonging to a total of 161 species. Considering this dataset in terms of occurrences, it corresponds to 505 discrete distributional records (incidence data. Of these, in order of abundance, 5,965 specimens were Gastropoda (accounting for 113 species, 1,323 were Bivalvia (accounting for 36 species, 949 were Aplacophora (accounting for 7 species, 74 specimens were Scaphopoda (3 species, 38 were Monoplacophora (1 species and, finally, 10 specimens were Polyplacophora (1 species. This data set represents the first large-scale survey of benthic micro-molluscs for the area and provides important information about the distribution of several species, which have been seldom or never recorded before in the Ross Sea. All vouchers are permanently stored at the Italian National Antarctic Museum (MNA, Section of Genoa, enabling future comparison and crosschecking. This material is also currently under study, from a molecular point of view, by the barcoding project “BAMBi” (PNRA 2010/A1.10.

  16. Advanced waterflooding in chalk reservoirs: Understanding of underlying mechanisms

    DEFF Research Database (Denmark)

    Zahid, Adeel; Sandersen, Sara Bülow; Stenby, Erling Halfdan

    2011-01-01

    Over the last decade, a number of studies have shown SO42−, Ca2+ and Mg2+ to be potential determining ions, which may be added to the injected brine for improving oil recovery during waterflooding in chalk reservoirs. However the understanding of the mechanism leading to an increase in oil recove...... of a microemulsion phase could be the possible reasons for the observed increase in oil recovery with sulfate ions at high temperature in chalk reservoirs besides the mechanism of the rock wettability alteration, which has been reported in most previous studies.......Over the last decade, a number of studies have shown SO42−, Ca2+ and Mg2+ to be potential determining ions, which may be added to the injected brine for improving oil recovery during waterflooding in chalk reservoirs. However the understanding of the mechanism leading to an increase in oil recovery...

  17. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea and others from 1998-02-19 to 1998-03-05 (NCEI Accession 0157460)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157460 includes chemical, discrete sample, physical and profile data collected from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea, Flores...

  18. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea and others from 1996-11-21 to 1996-12-13 (NCEI Accession 0157473)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157473 includes chemical, discrete sample, physical and profile data collected from BARUNA JAYA IV in the Banda Sea, Ceram Sea or Seram Sea, Flores...

  19. Nuclear magnetic resonance and sound velocity measurements of chalk saturated with magnesium rich brine

    DEFF Research Database (Denmark)

    Katika, Konstantina; Alam, Mohammad Monzurul; Fabricius, Ida Lykke

    2013-01-01

    The use of low field Nuclear Magnetic Resonance (NMR) to determine petrophysical properties of reservoirs has proved to be a good technique. Together with sonic and electrical resistivity measurements, NMR can contribute to illustrate the changes on chalk elasticity due to different pore water...... solutions of the same ionic strength. Saturation with a solution that contained divalent ions caused a major shift on the distribution of the relaxation time. The changes were probably due to precipitats forming extra internal surface in the sample. Sonic velocities were relatively low in the MgCl2 solution...

  20. Facilities for post-irradiation examination of experimental fuel elements at Chalk River Nuclear Laboratories

    International Nuclear Information System (INIS)

    Mizzan, E.; Chenier, R.J.

    1979-10-01

    Expansion of post-irradiation facilities at the Chalk River Nuclear Laboratories and steady improvement in hot-cell techniques and equipment are providing more support to Canada's reactor fuel development program. The hot-cell facility primarily used for examination of experimental fuels averages a quarterly throughput of 40 elements and 110 metallographic specimens. New developments in ultrasonic testing, metallographic sample preparation, active storage, active waste filtration, and fissile accountability are coming into use to increase the efficiency and safety of hot-cell operations. (author)

  1. Province of Ontario nuclear emergency plan part V - Chalk River

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1991-10-01

    The aim of Part 5 of the Provincial Nuclear Emergency Plan is to describe the measures that shall be undertaken to deal with a nuclear emergency caused by the Chalk River Laboratories. This plan deals mainly with actions at the Provincial level and shall by supplemented by the appropriate Municipal Plan. The Townships of Rolph, Buchanan, Wylie, and McKay, the Town of Deep River and the Village of Chalk River are the designated municipalities with respect to CRL. 2 tabs., 5 figs.

  2. Province of Ontario nuclear emergency plan part V - Chalk River

    International Nuclear Information System (INIS)

    1991-10-01

    The aim of Part 5 of the Provincial Nuclear Emergency Plan is to describe the measures that shall be undertaken to deal with a nuclear emergency caused by the Chalk River Laboratories. This plan deals mainly with actions at the Provincial level and shall by supplemented by the appropriate Municipal Plan. The Townships of Rolph, Buchanan, Wylie, and McKay, the Town of Deep River and the Village of Chalk River are the designated municipalities with respect to CRL. 2 tabs., 5 figs

  3. Occurrence of marine algal toxins in oyster and phytoplankton samples in Daya Bay, South China Sea.

    Science.gov (United States)

    Jiang, Tao; Liu, Lei; Li, Yang; Zhang, Jing; Tan, Zhijun; Wu, Haiyan; Jiang, Tianjiu; Lu, Songhui

    2017-09-01

    The occurrence and seasonal variations of marine algal toxins in phytoplankton and oyster samples in Daya Bay (DYB), South China Sea were investigated. Two Dinophysis species, namely, D. caudata and D. acuminata complex, were identified as Okadaic acid (OA)/pectenotoxin (PTX) related species. Liquid chromatography with tandem mass spectrometry (LC-MS/MS) analysis demonstrated that 2.04-14.47 pg PTX2 per cell was the predominant toxin in single-cell isolates of D. caudata. D. acuminata was not subjected to toxin analysis. The occurrence of OAs in phytoplankton concentrates of net-haul sample coincided with the presence of D. accuminata complex, suggesting that this species is most likely an OA producer in this sea area. OA, dinophysistoxins-1 (DTX1), PTX2, PTX2sa, gymnodimine (GYM), homoyessotoxin (homoYTX), and domoic acid (DA) demonstrated positive results in net haul samples. To our best knowledge, this paper is the first to report the detection of GYM, DA, and homoYTX in phytoplankton samples in Chinese coastal waters. Among the algal toxins, GYM demonstrated the highest frequency of positive detections in phytoplankton concentrates (13/17). Five compounds of algal toxins, including OA, DTX1, PTX2, PTX2sa, and GYM, were detected in oyster samples. DA and homoYTX were not detected in oysters despite of positive detections for both in the phytoplankton concentrates. However, neither the presence nor absence of DA in oysters can be determined because extraction conditions with 100% methanol used to isolate toxins from oysters (recommended by the EU-Harmonised Standard Operating Procedure, 2015) would likely be unsuitable for this water-soluble toxin. In addition, transformation of DA during the digestion process of oysters may also be involved in the negative detections of this toxin. GYM exhibited the highest frequency of positive results in oysters (14/17). OAs were only detected in the hydrolyzed oyster samples. The detection rates of PTX and PTX2sa in

  4. Metagenomic covariation along densely sampled environmental gradients in the Red Sea

    Science.gov (United States)

    Thompson, Luke R; Williams, Gareth J; Haroon, Mohamed F; Shibl, Ahmed; Larsen, Peter; Shorenstein, Joshua; Knight, Rob; Stingl, Ulrich

    2017-01-01

    Oceanic microbial diversity covaries with physicochemical parameters. Temperature, for example, explains approximately half of global variation in surface taxonomic abundance. It is unknown, however, whether covariation patterns hold over narrower parameter gradients and spatial scales, and extending to mesopelagic depths. We collected and sequenced 45 epipelagic and mesopelagic microbial metagenomes on a meridional transect through the eastern Red Sea. We asked which environmental parameters explain the most variation in relative abundances of taxonomic groups, gene ortholog groups, and pathways—at a spatial scale of water mass with different physicochemical properties. Temperature explained the most variation in each metric, followed by nitrate, chlorophyll, phosphate, and salinity. That nitrate explained more variation than phosphate suggested nitrogen limitation, consistent with low surface N:P ratios. Covariation of gene ortholog groups with environmental parameters revealed patterns of functional adaptation to the challenging Red Sea environment: high irradiance, temperature, salinity, and low nutrients. Nutrient-acquisition gene ortholog groups were anti-correlated with concentrations of their respective nutrient species, recapturing trends previously observed across much larger distances and environmental gradients. This dataset of metagenomic covariation along densely sampled environmental gradients includes online data exploration supplements, serving as a community resource for marine microbial ecology. PMID:27420030

  5. Diagenesis of silica-rich mounded chalk, the Coniacian Arnager Limestone, Denmark

    DEFF Research Database (Denmark)

    Buus Madsen, Heine; Stemmerik, Lars; Surlyk, Finn

    2010-01-01

    The Coniacian Arnager Limestone Formation is exposed on the Danish island of Bornholm in the Baltic Sea. It is composed of mound-bedded siliceous chalk, and X-ray diffraction and scanning electron microscopy indicate a content of 30-70% insoluble minerals, including authigenic opal-CT, quartz......, clinoptilolite, feldspars, calcite, dolomite, and barite. Opal-CT and clinoptilolite are the most common and constitute 16-53% and 2-9%, respectively. The content of insoluble minerals varies laterally bothwithinthemounds and inplanar beds, and the opal-CT content varies by up to 10% vertically. Themounds...... precipitation of opal-CT. The opal-CT formed at temperatures around 17°C, the precipitation lowered the silica activity and the Si/Al ratio of the pore water, resulting in precipitation of clinoptilolite, feldspar and smectite. Calcite formed synchronouslywith the latest clinoptilolite.Minoramounts of quartz...

  6. Technetium-99 in Fucus and seawater samples in the Finnish coastal area of the Baltic Sea, 1999

    International Nuclear Information System (INIS)

    Ikaeheimonen, T.K.; Vartti, V.P.; Ilus, E.; Mattila, J.

    2002-01-01

    Liquid discharges of 99 Tc from the Sellafield nuclear facilities increased largely in the mid 90's. These releases are transported to the Nordic sea areas by the ocean currents. Results of the 99 Tc activities along the Norwegian coastal areas and in the North Sea have been reported but then again, the spreading of 99 Tc into Baltic Sea has not been studied thoroughly. Fucus vesiculosus and seawater samples were collected in the summer 1999 from the Finnish coastal areas for measuring 99 Tc in the Baltic Sea area. A modified analytical method for measuring 99 Tc in the environmental samples was developed at that time. The method based on extraction chromatography and liquid scintillation measurement of 99 Tc. The 99 Tc concentration in the Fucus vesiculosus in the Finnish coast of the Baltic Sea varied from 1.6 to 11.6 Bq/kg (dry weight) being highest at the most northern sampling sites. These values were considerable lower than those in the Danish and Norwegian coasts. The variation in the concentrations observed are probably due to biological factors. The 99 Tc concentration in the Baltic Sea water studied was below 0.2 Bq/m 3 . (author)

  7. Initial field measurements on the Chalk River superconducting cyclotron

    International Nuclear Information System (INIS)

    Ormrod, J.H.; Chan, K.C.; Hill, J.H.

    1980-12-01

    The midplane magnetic field of the Chalk River superconducting cyclotron has been mapped in detail over the full operating range of 2.5 to 5 tesla. The field measuring apparatus is described and results given include measurements of the field stability, reproducibility and harmonic content. (author)

  8. Nano sized clay detected on chalk particle surfaces

    DEFF Research Database (Denmark)

    Skovbjerg, Lone; Hassenkam, Tue; Makovicky, Emil

    2012-01-01

    that in calcite saturated water, both the polar and the nonpolar functional groups adhere to the nano sized clay particles but not to calcite. This is fundamentally important information for the development of conceptual and chemical models to explain wettability alterations in chalk reservoirs...

  9. Groundwater conversion areas in chalk in the southern Frankish Alps

    International Nuclear Information System (INIS)

    Pfaff, T.

    1987-01-01

    In order to collect hydro-geological data, chalk water marking was done and/or interpreted, water balances were produced, the contents tritium, oxygen 18, calcium, magnesium and the groundwater temperatures and electrolytic conductivity of the groundwater were examined and the dry weather drainage of individual sources was analysed. (orig./PW) [de

  10. Sea Ice as a Sink for CO2 and Biogeochemical Material: a Novel Sampling Method and Astrobiological Applications

    Science.gov (United States)

    Wilner, J.; Hofmann, A.; Hand, K. P.

    2017-12-01

    Accurately modelling the intensification of greenhouse gas effects in the polar regions ("polar amplification") necessitates a thorough understanding of the geochemical balance between atmospheric, sea ice, and oceanic layers. Sea ice is highly permeable to CO2 and therefore represents a major sink of oceanic CO2 in winter and of atmospheric CO2 in summer, sinks that are typically either poorly constrained in or fully absent from global climate models. We present a novel method for sampling both trapped and dissolved gases (CO2, CH4 and δ13CH4) in sea ice with a Picarro 2132-i Methane Analyzer, taking the following sampling considerations into account: minimization of water and air contamination, full headspace sampling, prevention of inadvertent sample bag double-puncturing, and ease of use. This method involves melting of vacuum-sealed ice cores to evacuate trapped gases to the headspace and sampling the headspace gas with a blunt needle sheathed by a beveled puncturing needle. A gravity catchment tube prevents input of dangerous levels of liquid water to the Picarro cavity. Subsequent ultrasonic degassing allows for dissolved gas measurement. We are in the process of using this method to sample gases trapped and dissolved in Arctic autumn sea ice cores and atmospheric samples collected during the 2016 Polarstern Expedition and during a May 2017 field campaign north of Barrow, Alaska. We additionally employ this method, together with inductively coupled plasma mass spectrometry (ICP-MS), to analyze the transfer of potential biogeochemical signatures of underlying hydrothermal plumes to sea ice. This has particular relevance to Europa and Enceladus, where hypothetical hydrothermal plumes may deliver seafloor chemicals to the overlying ice shell. Hence, we are presently investigating the entrainment of methane and other hydrothermal material in sea ice cores collected along the Gakkel Ridge that may serve as biosignatures of methanogenic organisms in seafloor

  11. Effluent and environmental monitoring of Chalk River Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Pilgrim, T.; De Waele, C.; Gallagher, C. [Atomic Energy of Canada Limited, Chalk River, ON (Canada)

    2014-07-01

    Atomic Energy of Canada Limited's (AECL's) Environmental Protection Program has been gathering environmental monitoring data at its Chalk River Laboratories (CRL) for over 60 years. The comprehensive effluent and environmental monitoring program at CRL consists of more than 600 sampling locations, including the Ottawa River, with approximately 60,000 analyses performed on air and liquid effluent parameters each year. Monitoring for a variety of radiological and non-radiological parameters is regularly conducted on various media, including ambient air, foodstuff (e.g. milk, fish, garden produce, large game, and farm animals), groundwater, Ottawa River water and other surface water on and off-site. The purpose of the monitoring program is to verify that past and current radiological and non-radiological emissions derived from AECL operations and activities, such as process water effluent into the Ottawa River, are below regulatory limits and demonstrate that CRL operations do not negatively affect the quality of water on or leaving the site. In fact, ongoing program reports demonstrate that radiological emissions are well below regulatory limits and have been declining for the past five years, and that non-radiological contaminants do not negatively affect the quality of water on and off the site. Two updated Canadian Standards Association (CSA) standards for Effluent and Environmental monitoring have come into effect and have resulted in some changes to the AECL Program. This presentation will discuss effluent and surface water monitoring results, the observed trends, the changes triggered by the CSA standards, and a path forward for the future. (author)

  12. Contaminated groundwater characterization at the Chalk River Laboratories, Ontario, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Schilk, A.J.; Robertson, D.E.; Thomas, C.W.; Lepel, E.A. [Pacific Northwest National Lab., Richland, WA (United States); Champ, D.R.; Killey, R.W.D.; Young, J.L.; Cooper, E.L. [Chalk River Labs., Chalk River, Ontario (Canada)

    1993-03-01

    The licensing requirements for the disposal of low-level radioactive waste (10 CFR 61) specify the performance objectives and technical requisites for federal and commercial land disposal facilities, the ultimate goal of which is to contain the buried wastes so that the general population is adequately protected from harmful exposure to any released radioactive materials. A major concern in the operation of existing and projected waste disposal sites is subterranean radionuclide transport by saturated or unsaturated flow, which could lead to the contamination of groundwater systems as well as uptake by the surrounding biosphere, thereby directly exposing the general public to such materials. Radionuclide transport in groundwater has been observed at numerous commercial and federal waste disposal sites [including several locations within the waste management area of Chalk River Laboratories (CRL)], yet the physico-chemical processes that lead to such migration are still not completely understood. In an attempt to assist in the characterization of these processes, an intensive study was initiated at CRL to identify and quantify the mobile radionuclide species originating from three separate disposal sites: (a) the Chemical Pit, which has received aqueous wastes containing various radioisotopes, acids, alkalis, complexing agents and salts since 1956, (b) the Reactor Pit, which has received low-level aqueous wastes from a reactor rod storage bay since 1956, and (c) the Waste Management Area C, a thirty-year-old series of trenches that contains contaminated solid wastes from CRL and various regional medical facilities. Water samples were drawn downgradient from each of the above sites and passed through a series of filters and ion-exchange resins to retain any particulate and dissolved or colloidal radionuclide species, which were subsequently identified and quantified via radiochemical separations and gamma spectroscopy. These groundwaters were also analyzed for anions

  13. Field and numerical descriptions of fracture geometries and terminations in chalk containing chert layers and inclusions; implications for groundwater flow in Danish chalk aquifers

    Science.gov (United States)

    Seyum, S.

    2017-12-01

    This study is a description of the fracture distribution in laterally discontinuous chalk and chert layers, with an investigation on how fracture lengths and apertures vary as a function of applied stresses, material properties, and interface properties. Natural fractures intersect laterally extensive, discontinuous, chalk-chert material interfaces in 62 million-year old to 72 million-year old Chalk Group formations exposed at Stevns Klint, Denmark. Approximately one-third of Denmark's fresh water use is from chalk and limestone regional aquifers of the Chalk Group formations, where rock permeability is dominantly a function of open fracture connectivities. Fractured, centimeter- to decimeter-thick chert layers and inclusions (101 GPa elastic stiffness) are interlayered with fractured, meter-thick chalk layers (100 GPa elastic stiffness). Fractures are observed to terminate against and cross chalk-chert interfaces, affecting the vertical flow of water and pollutants between aquifers. The discontinuous and variably thin nature of chert layers at Stevns Klint effectively merges adjacent fracture-confining layers of chalk along discrete position intervals, resulting in lateral variability of fracture spacing. Finite element numerical models are designed to describe fracture interactions with stiff, chert inclusions of various shapes, thicknesses, widths, orientations, and interface friction and fracture toughness values. The models are two-dimensional with isotropic, continuous material in plane strain and uniformly applied remote principal stresses. These characteristics are chosen based on interpretations of the petrophysics of chalk and chert, the burial history of the rock, and the scale of investigation near fracture tips relative to grain sizes. The result are value ranges for relative stiffness contrasts, applied stresses, and material interface conditions that would cause fractures to cross, terminate at, or form along chalk-chert interfaces, with emphasis on

  14. Metagenomic covariation along densely sampled environmental gradients in the Red Sea

    KAUST Repository

    Thompson, Luke R

    2016-07-15

    Oceanic microbial diversity covaries with physicochemical parameters. Temperature, for example, explains approximately half of global variation in surface taxonomic abundance. It is unknown, however, whether covariation patterns hold over narrower parameter gradients and spatial scales, and extending to mesopelagic depths. We collected and sequenced 45 epipelagic and mesopelagic microbial metagenomes on a meridional transect through the eastern Red Sea. We asked which environmental parameters explain the most variation in relative abundances of taxonomic groups, gene ortholog groups, and pathways—at a spatial scale of <2000 km, along narrow but well-defined latitudinal and depth-dependent gradients. We also asked how microbes are adapted to gradients and extremes in irradiance, temperature, salinity, and nutrients, examining the responses of individual gene ortholog groups to these parameters. Functional and taxonomic metrics were equally well explained (75–79%) by environmental parameters. However, only functional and not taxonomic covariation patterns were conserved when comparing with an intruding water mass with different physicochemical properties. Temperature explained the most variation in each metric, followed by nitrate, chlorophyll, phosphate, and salinity. That nitrate explained more variation than phosphate suggested nitrogen limitation, consistent with low surface N:P ratios. Covariation of gene ortholog groups with environmental parameters revealed patterns of functional adaptation to the challenging Red Sea environment: high irradiance, temperature, salinity, and low nutrients. Nutrient-acquisition gene ortholog groups were anti-correlated with concentrations of their respective nutrient species, recapturing trends previously observed across much larger distances and environmental gradients. This dataset of metagenomic covariation along densely sampled environmental gradients includes online data exploration supplements, serving as a community

  15. Integrated waste plan for Chalk River Laboratories

    International Nuclear Information System (INIS)

    McClelland, P.; Bainbridge, I.

    2011-01-01

    The core missions for Chalk River Laboratories (CRL) will involve a complex suite of activities for decades to come, many of these activities resulting in production of some amount of wastes. In order to support the business of the Nuclear Laboratories there is a requirement to responsibly manage the wastes arising from these activities. Capability to develop waste stream pathway scenarios and be able to make informed strategic decisions regarding the various options for waste processing, storage and long-term management (i.e. e nabling facilities ) is necessary to discharge this responsibility in the most cost effective and sustainable manner. A holistic waste management plan integrated with the decommissioning, environmental remediation and operations programs is the desired result such that: - Waste inputs and timings are identified; - Timing of key decisions regarding enabling facilities is clearly identified; and - A defensible decision-making framework for enabling facilities is established, thereby ensuring value for Canadians. The quantities of wastes that require managing as part of the Nuclear Legacy Liabilities Program and AECL operations activities is in the range of 200,000 to 300,000 m 3 , with a yearly increase of several thousand m 3 . This volume can be classified into over thirty distinct waste streams having differing life cycle waste management pathways from generation to disposition. The time phasing of the waste management activities required for these wastes spans several decades and involves a complex array of processes and facilities. Several factors typical of wastes from the development of nuclear technology further complicate the situation. For example, there is considerable variation in the level of detail and format of waste records generated over several decades. Also, wastes were put into storage over several decades without knowledge or consideration of what the final disposition path will be. Prior to proceeding with any major new

  16. Exploring the utility of quantitative network design in evaluating Arctic sea ice thickness sampling strategies

    OpenAIRE

    Kaminski, T.; Kauker, F.; Eicken, H.; Karcher, M.

    2015-01-01

    We present a quantitative network design (QND) study of the Arctic sea ice-ocean system using a software tool that can evaluate hypothetical observational networks in a variational data assimilation system. For a demonstration, we evaluate two idealised flight transects derived from NASA's Operation IceBridge airborne ice surveys in terms of their potential to improve ten-day to five-month sea-ice forecasts. As target regions for the forecasts we select the Chukchi Sea, a...

  17. Equilibrium passive sampling as a tool to study polycyclic aromatic hydrocarbons in Baltic Sea sediment pore-water systems

    DEFF Research Database (Denmark)

    Lang, Susann-Cathrin; Hursthouse, Andrew; Mayer, Philipp

    2015-01-01

    Solid Phase Microextraction (SPME) was applied to provide the first large scale dataset of freely dissolved concentrations for 9 polycyclic aromatic hydrocarbons (PAHs) in Baltic Sea sediment cores. Polydimethylsiloxane (PDMS) coated glass fibers were used for ex-situ equilibrium sampling followed...

  18. Distribution of 137Cs in samples of ocean bottom sediments of the baltic sea in 1982-1983

    International Nuclear Information System (INIS)

    Gedenov, L.I.; Flegontov, V.M.; Ivanova, L.M.; Kostandov, K.A.

    1986-01-01

    The concentration of Cs-137 in samples of ocean bottom sediments picked up in 1979 in the Gulf of Finland with a geological nozzle pipe varied within a wide interval of values. The results could indicate nonuniformity of the Cs-137 distribution in ocean bottom sediments as well as the penetration of significant amounts of Cs-137 to large depths. The main error resulted from the sampling technique employed because the upper part of the sediment could be lost. In 1982, a special ground-sampling device, with which the upper layer of sediments in the water layer close to the ocean bottom could be sampled, was tested in the Gulf of Finland and the Northeastern part of the Baltic Sea. The results of a layerwise determination of the Cs-137 concentration in samples of ocean bottom sediments of the Gulf of Finland and of the Baltic Sea are listed. The new soil-sampling device for picking samples of ocean sediments of undisturbed stratification will allow a correct determination of the radionuclide accumulation in the upper layers of ocean bottom sediments in the Baltic Sea

  19. Spectroscopic studies of humic acids from subsurface sediment samples collected across the Aegean Sea

    Directory of Open Access Journals (Sweden)

    F. SAKELLARIADOU

    2006-12-01

    Full Text Available Natural humic acids are biogenic, structurally complex and heterogeneous, refractory, acidic, yellow-to black-coloured organic polyelectrolytes of relatively high molecular weight. They occur in all soils, sediments, fresh waters, and seawaters. Humic acids represent the largest portion of nonliving soil organic matter. In the present paper, humic substances were isolated from marine subsurface sediment samples collected across the Aegean sea (in Greece and especially from a marine area extending northwards of the Samothraki plateau towards the north-eastern part of the island of Crete. In a following step, humic preparations were studied using infrared and fluorescence spectroscopy (emission, excitation and synchronous-scan excitation spectra were obtained. The infrared spectra suggested functional chemical groups such as as OH-, C-H aliphatic, C=C, C=O/COO-, salts of carboxylic acids, and also, in some cases, silicate anions or C-O from alcohols, esters and ethers. Fluorescence emission, excitation and synchronous scan excitation provided some valuable information concerning a probable origin (marine and/or terrestrial for the isolated humics.

  20. Natural radioactivity of beach sand samples in Port Sudan, red sea state

    International Nuclear Information System (INIS)

    Kambal, Wala Haider Hussein

    2015-01-01

    Natural radioactivity is a source of continuous exposure to human beings. In Port Sudan city, the main port of Sudan, data on the levels of natural radioactivity in soil is required. The aim of this study was to measure the activity concentration as well as the absorbed dose and annual effective dose of the naturally occurring radionuclides 238 U, 232 Th, and 40 K in soil samples collected from different locations around Red Sea costa areas in Port Sudan city. Activity concentrations were measured using gamma ray spectrometry (Nal) detector. Results showed that the average activity concentration of 238 U, 232 Th and 40 K were found to be 21.86, 17.55, 85.50 Bqkg 1 , respectively, with an average absorbed dose of 10.42, 9.40 and 3.57 nGyh 1 , respectively. The average annual effective dose values were found to be 11.89, 11.54 and 4.37 μSvy 1 for 238 U, 232 Th and 40 K, respectively. The measured values were comparable with other global radioactivity measurements and found to be safe for public and environment.(Author)

  1. The Effect of Bacteria Penetration on Chalk Permeability

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Shapiro, Alexander; Nielsen, Sidsel Marie

    number of B. licheniformis was detected on the effluent compared with P. putida. However, in the experiment with B. licheniformis mainly spores were detected in the effluent. The core permeability decreased rapidly during injection of bacteria and a starvation period of 12 days did not allow......Bacteria selective plugging is one of the mechanisms through which microorganisms can be applied for enhanced oil recovery. Bacteria can plug the water-bearing zones of a reservoir, thus altering the flow paths and improving sweep efficiency. It is known that the bacteria can penetrate deeply...... into reservoirs, however, a complete understanding of the penetration behavior of bacteria is lacking, especially in chalk formations where the pore throat sizes are almost comparable with the sizes of bacteria vegetative cells. This study investigates the penetration of bacteria into chalk. Two bacteria types...

  2. Reactor safety research and development in Chalk River Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Nitheanandan, T. [Atomic Energy of Canada Limited, Chalk River, ON (Canada)

    2014-07-01

    Atomic Energy of Canada Limited's Chalk River Laboratories provides three different services to stakeholders and customers. The first service provided by the laboratory is the implementation of Research and Development (R&D) programs to provide the underlying technological basis of safe nuclear power reactor designs. A significant portion of the Canadian R&D capability in reactor safety resides at Atomic Energy of Canada Limited's Chalk River Laboratories, and this capability was instrumental in providing the science and technology required to aid in the safety design of CANDU power reactors. The second role of the laboratory has been in supporting nuclear facility licensees to ensure the continued safe operation of nuclear facilities, and to develop safety cases to justify continued operation. The licensing of plant life extension is a key industry objective, requiring extensive research on degradation mechanisms, such that safety cases are based on the original safety design data and valid and realistic assumptions regarding the effect of ageing and management of plant life. Recently, Chalk River Laboratories has been engaged in a third role in research to provide the technical basis and improved understanding for decision making by regulatory bodies. The state-of-the-art test facilities in Chalk River Laboratories have been contributing to the R&D needs of all three roles, not only in Canada but also in the international community, thorough Canada's participation in cooperative programs lead by International Atomic Energy Agency and the OECD's Nuclear Energy Agency. (author)

  3. The transport and behaviour of isoproturon in unsaturated chalk cores

    Science.gov (United States)

    Besien, T. J.; Williams, R. J.; Johnson, A. C.

    2000-04-01

    A batch sorption study, a microcosm degradation study, and two separate column leaching studies were used to investigate the transport and fate of isoproturon in unsaturated chalk. The column leaching studies used undisturbed core material obtained from the field by dry percussion drilling. Each column leaching study used 25 cm long, 10 cm wide unsaturated chalk cores through which a pulse of isoproturon and bromide was eluted. The cores were set-up to simulate conditions in the unsaturated zone of the UK Chalk aquifer by applying a suction of 1 kPa (0.1 m H 2O) to the base of each column, and eluting at a rate corresponding to an average recharge rate through the unsaturated Chalk. A dye tracer indicated that the flow was through the matrix under these conditions. The results from the first column study showed high recovery rates for both isoproturon (73-92%) and bromide (93-96%), and that isoproturon was retarded by a factor of about 1.23 relative to bromide. In the second column study, two of the four columns were eluted with non-sterile groundwater in place of the sterile groundwater used on all other columns, and this study showed high recovery rates for bromide (85-92%) and lower recovery rates for isoproturon (66-79% — sterile groundwater, 48-61% — non-sterile groundwater). The enhanced degradation in the columns eluted with non-sterile groundwater indicated that groundwater microorganisms had increased the degradation rate within these columns. Overall, the reduced isoproturon recovery in the second column study was attributed to increased microbial degradation as a result of the longer study duration (162 vs. 105 days). The breakthrough curves (BTCs) for bromide had a characteristic convection-dispersion shape and were accurately simulated with the minimum of calibration using a simple convection-dispersion model (LEACHP). However, the isoproturon BTCs had an unusual shape and could not be accurately simulated.

  4. Low field NMR surface relaxivity studies of chalk and argillaceous sandstones

    DEFF Research Database (Denmark)

    Katika, Konstantina; Fordsmand, Henrik; Fabricius, Ida Lykke

    2017-01-01

    the accuracy of predictions of petrophysical properties of various rocks with the use of NMR spectrometry. We perform laboratory transverse relaxation (T2) measurements on water saturated Gorm field chalk, Stevns Klint chalk, Solsort field greensand and Berea sandstone. These rocks are of particular interest...... field chalk and Solsort field greensand have higher ρ at higher Larmor frequency. By contrast, ρ of the purely calcitic Stevns chalk and quartzitic Berea sandstone proved not to be affected by the changes in frequency. T2 distributions at temperatures ranging from 10 °C to 60 °C provided comparison...

  5. SeaWiFS technical report series. Volume 4: An analysis of GAC sampling algorithms. A case study

    Science.gov (United States)

    Yeh, Eueng-Nan (Editor); Hooker, Stanford B. (Editor); Hooker, Stanford B. (Editor); Mccain, Charles R. (Editor); Fu, Gary (Editor)

    1992-01-01

    The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) instrument will sample at approximately a 1 km resolution at nadir which will be broadcast for reception by realtime ground stations. However, the global data set will be comprised of coarser four kilometer data which will be recorded and broadcast to the SeaWiFS Project for processing. Several algorithms for degrading the one kilometer data to four kilometer data are examined using imagery from the Coastal Zone Color Scanner (CZCS) in an effort to determine which algorithm would best preserve the statistical characteristics of the derived products generated from the one kilometer data. Of the algorithms tested, subsampling based on a fixed pixel within a 4 x 4 pixel array is judged to yield the most consistent results when compared to the one kilometer data products.

  6. Spreading Design of Radioactivity in Sea Water, Algae and Fish Samples inthe Coastal of Muria Peninsula Area

    International Nuclear Information System (INIS)

    Sutjipto; Muryono; Sumining

    2000-01-01

    Spreading design of radioactivity in sea water, brown algae (phaeopyceae)and kerapu fish (epeniphelus) samples in the coastal of Muria peninsula areahas been studied. This research was carried out with designed beside to knowspreading each radioactivity but also spreading design in relation to thecontent of Pu-239 and Cs-137. Samples taken, preparation and analysis basedon the procedures of environmental radioactivity analysis. The instrumentused for the analysis radioactivity were alpha counter with detector ZnS, lowlevel beta counter modified P3TM-BATAN with detector GM and spectrometergamma with detector Ge(Li). Alpha radioactivity obtained of sea water, algaeand fish were the fluctuation form of the natural background. Radionuclide ofPu-239 in samples not detect, because its concentration/radioactivity stillbelow the maximum concentration detection value of Pu-239 for algae and fishwas that 1.10 Bq/g, whereas for sea water was that 0.07 Bq/mL. Result for theradioactivity which give the highest alpha radioactivity obtained on thekerapu fish was that 1.56 x 10 -3 Bq/g, beta radioactivity on sea water wasthat 1.75 x 10 2 mBq/L, gamma radioactivity of K-40 on brown algae was that3.72 x 10 -2 Bq/g and gamma radioactivity of Tl-208 on fish as mentionedabove was that 1.35 x 10 -2 Bq/g. All the peak spectrum gamma energy ofCs-137 do not detect with gamma counter, so there are not the radionuclide ofCs-137 in the samples. Spreading design of radioactivity which occur in thecoastal of Muria peninsula area for alpha radioactivity was found on kerapufish, beta radioactivities on sea water and gamma radioactivity on brownalgae and kerapu fish. (author)

  7. Application of the spectrometric and radiochemical techniques in analyzing environmental samples from the Bulgarian Black Sea region

    International Nuclear Information System (INIS)

    Veleva, B.S.; Mungov, G.; Galabov, N.; Kolarova, M.; Guenchev, T.

    1999-01-01

    Development of the appropriate methods and techniques for marine and atmospheric radioactivity measurements in the NIMH-BAS during the last 5 years is presented. Approaches for pre-concentration of the radionuclides from the atmosphere and sea water samples followed with reliable radiochemical methods for radionuclides separation and low level counting are discussed. Dissolved radiocesium concentrations measured in a period of time starting in 1993 show some decrease with years and spatial variations probably due to the hydrophysical features of the sampling sides - the lower measured concentrations during 1995 and 1998 correspond to the lower salinity. Application of the radiochemical separation of Plutonium, Thorium, 90 Sr and Americium on the samples from the Bulgarian Black Sea coastal region is reported. (author)

  8. Evaluation of the toxicological properties of ground- and surface-water samples from the Aral Sea Basin

    International Nuclear Information System (INIS)

    Bosch, K.; Erdinger, L.; Ingel, F.; Khussainova, S.; Utegenova, E.; Bresgen, N.; Eckl, P.M.

    2007-01-01

    In order to determine whether there is a potential health risk associated with the water supply in the Aral Sea Basin, ground- and surface-water samples were collected in and around Aralsk and from the Aral Sea in 2002. Water samples from Akchi, a small town close to Almaty, served as controls. Bioassays with different toxicological endpoints were employed to assess the general toxicological status. Additionally, the samples were analysed for microbial contamination. The samples were tested in the primary hepatocyte assay for their potential to induce micronuclei and chromosomal aberrations as cumulative indicators for genotoxicity. In parallel, the effects on cell proliferation evidenced by mitotic index and cytotoxicity such as the appearance of necrotic and apoptotic cells, were determined. Furthermore, samples were examined using the Microtox assay for general toxicity. Chemical analysis according to European regulations was performed and soil and water samples were analysed for DDT and DDE. The results obtained indicated no increased cyto- or genotoxic potential of the water samples, nor levels of DDT or DDE exceeding the thresholds levels suggested by WHO. Our data therefore do not support the hypothesis that the contamination of the drinking water in and around Aralsk is responsible for the health effects previously described such as increased rates of liver disease and in particular liver cancer. Microbiological analysis, however, revealed the presence of contamination in most samples analysed

  9. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian Sea from 1993-07-30 to 1993-08-15 (NODC Accession 0113559)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113559 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian...

  10. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the Barents Sea, North Greenland Sea and Norwegian Sea from 1999-10-03 to 1999-10-11 (NODC Accession 0113888)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113888 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the Barents Sea, North Greenland Sea and Norwegian...

  11. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian Sea from 2000-05-27 to 2000-06-20 (NODC Accession 0115683)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115683 includes biological, chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the Barents Sea, North Greenland Sea...

  12. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian Sea from 1999-06-15 to 1999-07-07 (NODC Accession 0115678)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115678 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the Barents Sea, North Greenland Sea and Norwegian...

  13. Vertical distribution of radioactive particles in Ottawa River sediment near the Chalk River Laboratories

    International Nuclear Information System (INIS)

    Lee, D.R.; Hartwig, D.S.

    2011-01-01

    Previously, we described an area of above-background levels of radioactivity in the bed of the Ottawa River near the Chalk River Laboratories. The area was about 200 m wide by 400 m long and in water 8 to 30 m deep. The source of the radioactivity was associated with the location of cooling-water discharge. Particles of radioactive material were later recovered from the upper 10-15 cm of sediment and were determined to be sand-sized grains of nuclear fuel and corrosion products. This report provides an examination of the vertical distribution of radioactive particles in the riverbed. Twenty-three dredge samples (representing 1.2 m 2 of riverbed) were collected near the Process Outfall. Each dredge sample was dissected in horizontal intervals 1-cm-thick. Each interval provided a 524 cm 3 sample of sediment that was carefully examined for particulate radioactivity. Approximately 80% of the radioactivity appeared to be associated with discrete particles. Although the natural sediment in the general area is cohesive, silty clay and contains less than 10% sand, the sediment near the Outfall was found to be rich in natural sand, presumably from sources such as winter sanding of roads at the laboratories. The radioactive particles were almost entirely contained in the top-most 10 cm of the river bed. The majority of the particles were found several centimetres beneath the sediment surface and the numbers of particles and the radioactivity of the particles peaked 3 to 7 cm below the sediment surface. Based on the sediment profile, there appeared to have been a marked decrease in the deposition of particulate radioactivity in recent decades. The vertical distribution of radioactive particles indicated that sedimentation is resulting in burial and that the deposition of most of the particulate radioactivity coincided with the operation of Chalk River's NRX reactor from 1947 to 1992. (author)

  14. A certified reference material for radionuclides in the water sample from Irish Sea (IAEA-443)

    DEFF Research Database (Denmark)

    Pham, M.K.; Betti, M.; Povinec, P.P.

    2011-01-01

    A new certified reference material (CRM) for radionuclides in sea water from the Irish sea (IAEA-443) is described and the results of the certification process are presented. Ten radionuclides (3H, 40K, 90Sr, 137Cs, 234U, 235U, 238U, 238Pu, 239+240Pu and 241Am) have been certified, and information...... values on massic activities with 95% confidence intervals are given for four radionuclides (230Th, 232Th, 239Pu and 240Pu). Results for less frequently reported radionuclides (99Tc, 228Th, 237Np and 241Pu) are also reported. The CRM can be used for quality assurance/quality control of the analysis...

  15. Determination of naturally radioactive elements in chalk sticks by means of gamma spectroscopy

    Science.gov (United States)

    Abd El-Wahab, Magda; Morsy, Zeinab; El-Faramawy, Nabil

    2010-04-01

    The radiation hazards due to ingestion of chalkboard dust were investigated. Sixteen samples from three different origin fabricates were used. The estimation of radiation hazard indices were based on the evaluation of the concentration activities of the natural radionuclides 238U, 232Th and 40K. The radium equivalent activity, external hazard index, internal hazard index and the annual dose equivalent associated with the radionuclides were calculated and compared with international recommended values to assess the radiation hazard. The values of internal and external radiation hazard indices were found to be less than unity. The annual effective dose rate obtained, E eff, and the annual gonadal dose equivalent (AGDE) are found to be less than the limit of the doses recommended by the International Commission on Radiological Protection for the general public. The analytical results show that besides the main calcium content, some toxic elements, S, Mo and Pb and Ni and Pb, in the Egyptian and imported chalk stocks, respectively, existed.

  16. Full-waveform Inversion of Crosshole GPR Data Collected in Strongly Heterogeneous Chalk

    DEFF Research Database (Denmark)

    Keskinen, Johanna; Zibar, Majken Caroline Looms; Nielsen, Lars

    2015-01-01

    Chalk is an important reservoir rock for hydrocarbons and for groundwater resources for many major cities. Therefore, this rock type has been extensively investigated using both geological and geophysical methods. Many applications of crosshole GPR tomography rely on the ray approximation...... and corresponding inversions of first break traveltimes and/or maximum first-cycle amplitudes. Due to the inherent limitations associated with such approaches, the resulting models tend to be overly smooth and cannot adequately capture the small-scale heterogeneities. In contrast, the full-waveform inversion uses...... address the importance of (i) adequate starting models, both in terms of the dielectric permittivity and the electrical conductivity, (ii) the estimation of the source wavelet, (iii) and the effects of data sampling density when imaging this rock type. Moreover, we discuss the resolution of the bedding...

  17. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from METEOR in the Aegean Sea, Mediterranean Sea and others from 2001-10-18 to 2001-11-11 (NODC Accession 0084620)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0084620 includes discrete sample and profile data collected from METEOR in the Aegean Sea, Mediterranean Sea, Mediterranean Sea - Eastern Basin,...

  18. PH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from PROFESSOR SIEDLECKI in the Adriatic Sea, Aegean Sea and others from 1988-11-17 to 1988-11-26 (NCEI Accession 0144306)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144306 includes discrete sample and profile data collected from PROFESSOR SIEDLECKI in the Adriatic Sea, Aegean Sea, Mediterranean Sea, Mediterranean...

  19. Dissolved inorganic carbon, alkalinity, temperature, salinity and OXYGEN - APPARENT UTILIZATION (AOU) collected from discrete sample and profile observations using CTD, bottle and other instruments from UNKNOWN PLATFORMS in the Adriatic Sea, Aegean Sea and others from 1874-10-11 to 2000-04-26 (NODC Accession 0117350)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0117350 includes chemical, discrete sample, physical and profile data collected from UNKNOWN PLATFORMS in the Adriatic Sea, Aegean Sea, Alboran Sea,...

  20. Process-based modelling to evaluate simulated groundwater levels and frequencies in a Chalk catchment in south-western England

    Science.gov (United States)

    Brenner, Simon; Coxon, Gemma; Howden, Nicholas J. K.; Freer, Jim; Hartmann, Andreas

    2018-02-01

    Chalk aquifers are an important source of drinking water in the UK. Due to their properties, they are particularly vulnerable to groundwater-related hazards like floods and droughts. Understanding and predicting groundwater levels is therefore important for effective and safe water management. Chalk is known for its high porosity and, due to its dissolvability, exposed to karstification and strong subsurface heterogeneity. To cope with the karstic heterogeneity and limited data availability, specialised modelling approaches are required that balance model complexity and data availability. In this study, we present a novel approach to evaluate simulated groundwater level frequencies derived from a semi-distributed karst model that represents subsurface heterogeneity by distribution functions. Simulated groundwater storages are transferred into groundwater levels using evidence from different observations wells. Using a percentile approach we can assess the number of days exceeding or falling below selected groundwater level percentiles. Firstly, we evaluate the performance of the model when simulating groundwater level time series using a spilt sample test and parameter identifiability analysis. Secondly, we apply a split sample test to the simulated groundwater level percentiles to explore the performance in predicting groundwater level exceedances. We show that the model provides robust simulations of discharge and groundwater levels at three observation wells at a test site in a chalk-dominated catchment in south-western England. The second split sample test also indicates that the percentile approach is able to reliably predict groundwater level exceedances across all considered timescales up to their 75th percentile. However, when looking at the 90th percentile, it only provides acceptable predictions for long time periods and it fails when the 95th percentile of groundwater exceedance levels is considered. By modifying the historic forcings of our model

  1. Improved Oil Recovery in Chalk. Spontaneous Imbibition affected by Wettability, Rock Framework and Interfacial Tension

    Energy Technology Data Exchange (ETDEWEB)

    Milter, J.

    1996-12-31

    The author of this doctoral thesis aims to improve the oil recovery from fractured chalk reservoirs, i.e., maximize the area of swept zones and their displacement efficiencies. In order to identify an improved oil recovery method in chalk, it is necessary to study wettability of calcium carbonate and spontaneous imbibition potential. The thesis contains an investigation of thin films and wettability of single calcite surfaces. The results of thin film experiments are used to evaluate spontaneous imbibition experiments in different chalk types. The chalk types were described detailed enough to permit considering the influence of texture, pore size and pore throat size distributions, pore geometry, and surface roughness on wettability and spontaneous imbibition. Finally, impacts of interfacial tension by adding anionic and cationic surfactants to the imbibing water phase are studied at different wettabilities of a well known chalk material. 232 refs., 97 figs., 13 tabs.

  2. Chalk effect on PVC cross-linking under irradiation; Vliyanie mela na sshivanie PVKh pri obluchenii

    Energy Technology Data Exchange (ETDEWEB)

    Chudinova, V V; Guzeev, V V; Mozzhukhin, V B; Pomerantseva, Eh G; Nozrina, F D; Zhil` tsov, V V; Zubov, V P

    1994-12-31

    Effect of nonmodified and modified chalk on curing degree of polymer matrix was studied under-irradiation of PVC-compositions. Films of the compositions (100 mass part 7 PVC, 0-100 mas.part of chalk, 2.5 - lead sulfate, 1.5 - lead stearate and 0.3 - glycerin) were irradiated up to absorbed dose 0.1 MGy in an inert medium. Content of gel-fraction after boiling in THF was determined with use of IR spectroscopy. It was established, that intensive dehydrochlorination and polymer curing took place on chalk particle surface. Network fixed strongly chalk particles. However, chalk inhibited processes of dehydrochlorination and PVC curing, increasing amount of noncured PVC in polymer matrix.

  3. Fault zone processes in mechanically layered mudrock and chalk

    Science.gov (United States)

    Ferrill, David A.; Evans, Mark A.; McGinnis, Ronald N.; Morris, Alan P.; Smart, Kevin J.; Wigginton, Sarah S.; Gulliver, Kirk D. H.; Lehrmann, Daniel; de Zoeten, Erich; Sickmann, Zach

    2017-04-01

    A 1.5 km long natural cliff outcrop of nearly horizontal Eagle Ford Formation in south Texas exposes northwest and southeast dipping normal faults with displacements of 0.01-7 m cutting mudrock, chalk, limestone, and volcanic ash. These faults provide analogs for both natural and hydraulically-induced deformation in the productive Eagle Ford Formation - a major unconventional oil and gas reservoir in south Texas, U.S.A. - and other mechanically layered hydrocarbon reservoirs. Fault dips are steep to vertical through chalk and limestone beds, and moderate through mudrock and clay-rich ash, resulting in refracted fault profiles. Steeply dipping fault segments contain rhombohedral calcite veins that cross the fault zone obliquely, parallel to shear segments in mudrock. The vertical dimensions of the calcite veins correspond to the thickness of offset competent beds with which they are contiguous, and the slip parallel dimension is proportional to fault displacement. Failure surface characteristics, including mixed tensile and shear segments, indicate hybrid failure in chalk and limestone, whereas shear failure predominates in mudrock and ash beds - these changes in failure mode contribute to variation in fault dip. Slip on the shear segments caused dilation of the steeper hybrid segments. Tabular sheets of calcite grew by repeated fault slip, dilation, and cementation. Fluid inclusion and stable isotope geochemistry analyses of fault zone cements indicate episodic reactivation at 1.4-4.2 km depths. The results of these analyses document a dramatic bed-scale lithologic control on fault zone architecture that is directly relevant to the development of porosity and permeability anisotropy along faults.

  4. Groundwater recharge dynamics in unsaturated fractured chalk: a case study

    Science.gov (United States)

    Cherubini, Claudia; Pastore, Nicola; Giasi, Concetta I.; Allegretti, Nicolaetta M.

    2016-04-01

    The heterogeneity of the unsaturated zone controls its hydraulic response to rainfall and the extent to which pollutants are delayed or attenuated before reaching groundwater. It plays therefore a very important role in the recharge of aquifers and the transfer of pollutants because of the presence of temporary storage zones and preferential flows. A better knowledge of the physical processes in the unsaturated zone would allow an improved assessment of the natural recharge in a heterogeneous aquifer and of its vulnerability to surface-applied pollution. The case study regards the role of the thick unsaturated zone of the Cretaceous chalk aquifer in Picardy (North of France) that controls the hydraulic response to rainfall. In the North Paris Basin, much of the recharge must pass through a regional chalk bed that is composed of a porous matrix with embedded fractures. Different types of conceptual models have been formulated to explain infiltration and recharge processes in the unsaturated fractured rock. The present study analyses the episodic recharge in fractured Chalk aquifer using the kinematic diffusion theory to predict water table fluctuation in response to rainfall. From an analysis of the data, there is the evidence of 1) a seasonal behavior characterized by a constant increase in the water level during the winter/spring period and a recession period, 2) a series of episodic behaviors during the summer/autumn. Kinematic diffusion models are useful for predict preferential fluxes and dynamic conditions. The presented approach conceptualizes the unsaturated flow as a combination of 1) diffusive flow refers to the idealized portion of the pore space of the medium within the flow rate is driven essentially by local gradient of potential; 2) preferential flow by which water moves across macroscopic distances through conduits of macropore length.

  5. Cancer and workers' compensation at Chalk River nuclear laboratories

    International Nuclear Information System (INIS)

    Evans, D.W.S.

    1985-01-01

    This paper describes the circumstances leading to the notification to the Worker's Compensation Board of Ontario of two cases of cancer, both involving the lymphatic and haematoporetic systems, in employees at Chalk River Nulcear Laboratories. Twenty of these neoplasms are known to have occurred in the CRNL population between 1966 and 1983. The leukemia/lymphoma ratio observed in the twenty neoplasms is similar to that found in populations not occupationally exposed to ionizing radiation. The possible relationship between asbestos exposure and lymphoid neoplasms was discussed. 5 refs

  6. The dynamic analysis facility at the Chalk River Nuclear Laboratories

    International Nuclear Information System (INIS)

    Argue, D.S.; Howatt, W.T.

    1979-10-01

    The Dynamic Analysis Facility at the Chalk River Nuclear Laboratories (CRNL) of Atomic Energy of Canada Limited (AECL) comprises a Hybrid Computer, consisting of two Applied Dynamic International AD/FIVE analog computers and a Digital Equipment Corporation (DEC) PDP-11/55 digital computer, and a Program Development System based on a DEC PDP-11/45 digital computer. This report describes the functions of the various hardware components of the Dynamic Analysis Facility and the interactions between them. A brief description of the software available to the user is also given. (auth)

  7. Mortality among long-term Chalk River employees

    International Nuclear Information System (INIS)

    Werner, M.M.; Myers, D.K.

    1986-12-01

    Mortality among Chalk River Nuclear Laboratory (CRNL) employees who died during employment or after retirement has been updated to 1985 December 31. Data in tabular form are presented for overall mortality for male and female employees, for the participants in the clean-up for the NRX and NRU reactor accidents and for a group of CRNL staff with lifetime accumulative doses in excess of 0.2 Sv. Data are also presented on the different types of cancer causing death among male employees. No statistically significant increases in cancer deaths were found in any of the groups analyzed. 25 refs

  8. Field studies of radionuclide transport at the Chalk River Laboratories

    International Nuclear Information System (INIS)

    Champ, D.R.; Killey, R.W.D.; Moltyaner, G.L.

    1991-01-01

    In this paper the authors summarize the results of: in situ field column experiments to study the transport behaviour of several long-lived radionuclides, 4 natural gradient non-reactive radiotracer injection experiments at the Chalk River Laboratories (CRL) Twin Lake Tracer Test Site, and a model validation study that used data for 90 Sr from two well-defined contaminated groundwater flow systems at CRL. The paper also describes a current re-evaluation of radionuclide release and transport from a 1960 experimental burial (in a CRL sand aquifer) of glass blocks containing fission and activation products. (J.P.N.)

  9. Sample size matters in dietary gene expression studies—A case study in the gilthead sea bream (Sparus aurata L.

    Directory of Open Access Journals (Sweden)

    Fotini Kokou

    2016-05-01

    Full Text Available One of the main concerns in gene expression studies is the calculation of statistical significance which in most cases remains low due to limited sample size. Increasing biological replicates translates into more effective gains in power which, especially in nutritional experiments, is of great importance as individual variation of growth performance parameters and feed conversion is high. The present study investigates in the gilthead sea bream Sparus aurata, one of the most important Mediterranean aquaculture species. For 24 gilthead sea bream individuals (biological replicates the effects of gradual substitution of fish meal by plant ingredients (0% (control, 25%, 50% and 75% in the diets were studied by looking at expression levels of four immune-and stress-related genes in intestine, head kidney and liver. The present results showed that only the lowest substitution percentage is tolerated and that liver is the most sensitive tissue to detect gene expression variations in relation to fish meal substituted diets. Additionally the usage of three independent biological replicates were evaluated by calculating the averages of all possible triplets in order to assess the suitability of selected genes for stress indication as well as the impact of the experimental set up, thus in the present work the impact of FM substitution. Gene expression was altered depending of the selected biological triplicate. Only for two genes in liver (hsp70 and tgf significant differential expression was assured independently of the triplicates used. These results underlined the importance of choosing the adequate sample number especially when significant, but minor differences in gene expression levels are observed. Keywords: Sample size, Gene expression, Fish meal replacement, Immune response, Gilthead sea bream

  10. The effect of divalent ions on the elasticity and pore collapse of chalk evaluated from compressional wave velocity and low-field Nuclear Magnetic Resonance (NMR)

    DEFF Research Database (Denmark)

    Katika, Konstantina; Addassi, Mouadh; Alam, Mohammad Monzurul

    2015-01-01

    The effects of divalent ions on the elasticity and the pore collapse of chalk were studied through rock-mechanical testing and low-field Nuclear Magnetic Resonance (NMR) measurements. Chalk samples saturated with deionized water and brines containing sodium, magnesium, calcium and sulfate ions were...... subjected to petrophysical experiments, rock mechanical testing and low-field NMR spectroscopy. Petrophysical characterization involving ultrasonic elastic wave velocities in unconfined conditions, porosity and permeability measurements, specific surface and carbonate content determination and backscatter...... electron microscopy of the materials were conducted prior to the experiments. The iso-frame model was used to predict the bulk moduli in dry and saturated conditions from the compressional modulus of water-saturated rocks. The effective stress coefficient, as introduced by Biot, was also determined from...

  11. From ooze to sedimentary rock, the first diagenetic processes affecting the chalk of eastern Denmark

    DEFF Research Database (Denmark)

    Moreau, Julien; Boussaha, Myriam; Nielsen, Lars

    processes operating in the chalk sediments at widely different scales into a single diagenetic model: At Stevns the chalk is affected by an extensive polygonal fault system which is expressed in onshore and offshore seismic profiles. Smaller scale contractional features like deformation bands (hairline...... strongly affect reservoir properties of the chalk both by establishing compartments and vertical connections. A better understanding of these reservoir modifications will be critical for improving the predictive capability of models describing the behaviour of drinking water and hydrocarbons hosted...

  12. Atmospherically dispersed radiocarbon at the Chalk River Laboratories

    International Nuclear Information System (INIS)

    Milton, G.M.; Brown, R.M.; Repta, C.J.W.; Selkirk, C.J.

    1996-01-01

    A small percentage of the total radiocarbon produced by the NRX and NRU experimental reactors at the Chalk River Laboratories has been vented from the main reactor stack and atmospherically dispersed across the site. Surveys conducted in 1982-83 and 1993-94 have shown that atmospheric levels more than 50 m from the stack are never greater than 600 Bq.kg -1 carbon above the natural background level, falling to near-global atmospheric levels at the site boundaries roughly 7 km away. A dispersion factor > 1.2 x 10 6 m 3 .s -1 at ∼ 0.75 km distance from the point of emission is calculated on the basis of recent in-stack monitoring. Analysis of growth rings in on-site trees has provided an opportunity to search for correlations of 14 C output summer power production and/or moderator losses. (author). 16 refs., 14 tabs., 11 figs

  13. Status of the Chalk River superconducting heavy-ion cyclotron

    International Nuclear Information System (INIS)

    Ormrod, J.H.; Bigham, C.B.; Heighway, E.A.; Hoffmann, C.R.; Hulbert, J.A.; Schneider, H.R.

    1982-01-01

    The Chalk River four-sector K=520 superconducting cyclotron is designed to accelerate all ions from lithium (to 50 MeV/u) to uranium (to 10 MeV/u) using a 13 MV tandem Van de Graaff as injector. After an extended shutdown the magnet has been reassembled and field measurements resumed. During the shutdown a ground fault between the superconducting coil and its container was removed, the flutter poles were shimmed and the remaining trim rod holes were bored in them, the 104 trim rods with their holders were installed and the cryostat inner wall was modified to accept the radiofrequency accelerating structure. Experiments on the radiofrequency accelerating system, cryopumps, electrostatic deflector and superconducting windings for the magnetic channel are done in separate test chambers. Recent results and the status of all subsystems are given

  14. Relative contributions of sampling effort, measuring, and weighing to precision of larval sea lamprey biomass estimates

    Science.gov (United States)

    Slade, Jeffrey W.; Adams, Jean V.; Cuddy, Douglas W.; Neave, Fraser B.; Sullivan, W. Paul; Young, Robert J.; Fodale, Michael F.; Jones, Michael L.

    2003-01-01

    We developed two weight-length models from 231 populations of larval sea lampreys (Petromyzon marinus) collected from tributaries of the Great Lakes: Lake Ontario (21), Lake Erie (6), Lake Huron (67), Lake Michigan (76), and Lake Superior (61). Both models were mixed models, which used population as a random effect and additional environmental factors as fixed effects. We resampled weights and lengths 1,000 times from data collected in each of 14 other populations not used to develop the models, obtaining a weight and length distribution from reach resampling. To test model performance, we applied the two weight-length models to the resampled length distributions and calculated the predicted mean weights. We also calculated the observed mean weight for each resampling and for each of the original 14 data sets. When the average of predicted means was compared to means from the original data in each stream, inclusion of environmental factors did not consistently improve the performance of the weight-length model. We estimated the variance associated with measures of abundance and mean weight for each of the 14 selected populations and determined that a conservative estimate of the proportional contribution to variance associated with estimating abundance accounted for 32% to 95% of the variance (mean = 66%). Variability in the biomass estimate appears more affected by variability in estimating abundance than in converting length to weight. Hence, efforts to improve the precision of biomass estimates would be aided most by reducing the variability associated with estimating abundance.

  15. Revised South China Sea spreading history based on macrostructure analysis of IODP Expedition 349 core samples and geophysical data

    Science.gov (United States)

    Sun, Z.; Ding, W.; Zhao, X.; Qiu, N.; Lin, J.; Li, C.

    2017-12-01

    In Internaltional Ocean Discovery Program (IODP) Expedition 349, four sites were drilled and cored successfully in the South China Sea (SCS). Three of them are close to the central spreading ridge (Sites U1431, U1433 and U1434), and one (Site U1435) is located on an outer rise,,providingsignificant information on the spreading history of the SCS.In order to constrain the spreading historymore accurately with the core results, we analyzed the identifiable macrostructures (over 300 fractures, veins and slickensides)from all the consolidated samples of these four drill sites. Then we made a retrograde reconstruction of the SCS spreading history with the constraints of the estimated fractures and veins, post-spreading volcanism,seismic interpretation, as well as free-air gravity and magnetic anomaly and topography analysis. Our study indicates that the spreading of the SCS experienced at least one ridge jump event and two events of ridge orientation and spreading direction adjustment, which mademagnetic anomaly orientation, ridge positionand facture zone directionskeep changing in the South China Sea. During the last spreading stage, the spreading direction was north-southward but lasted for a very short time period. The oceanic crust is wider in the eastern SCS and tapers out toward west.Due to the subductionof SCS beneath the Philippine Sea plate, the seafloor began to develop new fractures:the NWW-to EW-trending R' shear faults and the NE-trending P faultsbecame dominant faults and controlled the eruption of post-drift volcanism.

  16. Imaging the Danish Chalk Group with high resolution, 3-component seismics

    Science.gov (United States)

    Kammann, J.; Rasmussen, S. L.; Nielsen, L.; Malehmir, A.; Stemmerik, L.

    2016-12-01

    The Chalk Group in the Danish Basin forms important reservoirs to hydrocarbons as well as water resources, and it has been subject to several seismic studies to determine e.g. structural elements, deposition and burial history. This study focuses on the high quality seismic response of a survey acquired with an accelerated 45 kg weight drop and 3-component MEMS-based sensors and additional wireless vertical-type sensors. The 500 m long profile was acquired during one day close to a chalk quarry and chalk cliffs of the Stevns peninsula in eastern Denmark where the well-known K-T (Cretaceous-Tertiary) boundary and different chalk lithologies are well-exposed. With this simple and fast procedure we were able to achieve deep P-wave penetration to the base of the Chalk Group at about 900 m depth. Additionally, the CMP-processed seismic image of the vertical component stands out by its high resolution. Sedimentary features are imaged in the near-surface Danian, as well as in the deeper Maastrichtian and Upper Campanian parts of the Chalk Group. Integration with borehole data suggests that changes in composition, in particular clay content, correlate with changes in reflectivity of the seismic data set. While the pure chalk in the Maastrichtian deposits shows rather low reflectivity, succession enriched in clay appear to be more reflective. The integration of the mentioned methods gives the opportunity to connect changes in facies to the elastic response of the Chalk Group in its natural environmental conditions.

  17. The effect of chalk on the finger-hold friction coefficient in rock climbing.

    Science.gov (United States)

    Amca, Arif Mithat; Vigouroux, Laurent; Aritan, Serdar; Berton, Eric

    2012-11-01

    The main purpose of this study was to examine the effect of chalk on the friction coefficient between climber's fingers and two different rock types (sandstone and limestone). The secondary purpose was to investigate the effects of humidity and temperature on the friction coefficient and on the influence of chalk. Eleven experienced climbers took part in this study and 42 test sessions were performed. Participants hung from holds which were fixed on a specially designed hang board. The inclination of the hang board was progressively increased until the climber's hand slipped from the holds. The angle of the hang board was simultaneously recorded by using a gyroscopic sensor and the friction coefficient was calculated at the moment of slip. The results showed that there was a significant positive effect of chalk on the coefficient of friction (+18.7% on limestone and +21.6% on sandstone). Moreover sandstone had a higher coefficient of friction than limestone (+15.6% without chalk, +18.4% with chalk). These results confirmed climbers' belief that chalk enhances friction. However, no correlation with humidity/temperature and friction coefficient was noted which suggested that additional parameters should be considered in order to understand the effects of climate on finger friction in rock climbing.

  18. Reactive transport modelling of groundwater chemistry in a chalk aquifer at the watershed scale.

    Science.gov (United States)

    Mangeret, A; De Windt, L; Crançon, P

    2012-09-01

    This study investigates thermodynamics and kinetics of water-rock interactions in a carbonate aquifer at the watershed scale. A reactive transport model is applied to the unconfined chalk aquifer of the Champagne Mounts (France), by considering both the chalk matrix and the interconnected fracture network. Major element concentrations and main chemical parameters calculated in groundwater and their evolution along flow lines are in fair agreement with field data. A relative homogeneity of the aquifer baseline chemistry is rapidly reached in terms of pH, alkalinity and Ca concentration since calcite equilibrium is achieved over the first metres of the vadose zone. However, incongruent chalk dissolution slowly releases Ba, Mg and Sr in groundwater. Introducing dilution effect by rainwater infiltration and a local occurrence of dolomite improves the agreement between modelling and field data. The dissolution of illite and opal-CT, controlling K and SiO(2) concentrations in the model, can be approximately tackled by classical kinetic rate laws, but not the incongruent chalk dissolution. An apparent kinetic rate has therefore been fitted on field data by inverse modelling: 1.5×10(-5) mol(chalk)L (-1) water year (-1). Sensitivity analysis indicates that the CO(2) partial pressure of the unsaturated zone is a critical parameter for modelling the baseline chemistry over the whole chalk aquifer. Copyright © 2012 Elsevier B.V. All rights reserved.

  19. Persistent and emerging micro-organic contaminants in Chalk groundwater of England and France

    International Nuclear Information System (INIS)

    Lapworth, D.J.; Baran, N.; Stuart, M.E.; Manamsa, K.; Talbot, J.

    2015-01-01

    The Chalk aquifer of Northern Europe is an internationally important source of drinking water and sustains baseflow for surface water ecosystems. The areal distribution of microorganic (MO) contaminants, particularly non-regulated emerging MOs, in this aquifer is poorly understood. This study presents results from a reconnaissance survey of MOs in Chalk groundwater, including pharmaceuticals, personal care products and pesticides and their transformation products, conducted across the major Chalk aquifers of England and France. Data from a total of 345 sites collected during 2011 were included in this study to provide a representative baseline assessment of MO occurrence in groundwater. A suite of 42 MOs were analysed for at each site including industrial compounds (n = 16), pesticides (n = 14) and pharmaceuticals, personal care and lifestyle products (n = 12). Occurrence data is evaluated in relation to land use, aquifer exposure, well depth and depth to groundwater to provide an understanding of vulnerable groundwater settings. - Highlights: • Broad range of microorganics detected in Chalk groundwater in England and France. • Plasticisers, pesticides, BPA and THM detected at the highest concentrations. • Pesticides higher in outcrop Chalk, caffeine and BPA at concealed sites. • Occurrences show some relationship to land use, borehole depth and water level. - Broad screening reveals for the first time the extent of emerging microorganic pollution in Chalk groundwater sources across England and France

  20. A new cytotoxic sesquiterpene quinone produced by Penicillium sp. F00120 isolated from a deep sea sediment sample.

    Science.gov (United States)

    Lin, Xiuping; Zhou, Xuefeng; Wang, Fazuo; Liu, Kaisheng; Yang, Bin; Yang, Xianwen; Peng, Yan; Liu, Juan; Ren, Zhe; Liu, Yonghong

    2012-01-01

    A new fungal strain, displaying strong toxic activity against brine shrimp larvae, was isolated from a deep sea sediment sample collected at a depth of 1300 m. The strain, designated as F00120, was identified as a member of the genus Penicillium on the basis of morphology and ITS sequence analysis. One new sesquiterpene quinone, named penicilliumin A (1), along with two known compounds ergosterol (2) and ergosterol peroxide (3), were isolated and purified from the cultures of F00120 by silica gel column, Sephadex LH-20 column, and preparative thin layer chromatography. Their structures were elucidated by detailed nuclear magnetic resonance (NMR) and mass spectroscopic (MS) analysis as well as comparison with literature data. The new compound penicilliumin A inhibited in vitro proliferation of mouse melanoma (B16), human melanoma (A375), and human cervical carcinoma (Hela) cell lines moderately.

  1. Edibility of sport fishes in the Ottawa River near Chalk River Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Lee, D.R.; Chaput, T.; Miller, A.; Wills, C.A., E-mail: leed@aecl.ca [Atomic Energy of Canada Limited, Chalk River, Ontario (Canada)

    2013-12-15

    To address the question of edibility of fish in the Ottawa River near Chalk River Laboratories (CRL), 123 game fish were collected for analysis from four locations: Mackey and Rolphton (45 km and 35 km upstream of Chalk River Laboratories (CRL), respectively), the Sandspit (Pointe au Bapteme) and Cotnam Island (1.6 km and 45 km downstream of CRL, respectively). Twenty-six to thirty-six game fish were collected at each location in 2007 and samples of flesh or bone were analyzed. Trap nets were used to collect only the fish required, allowing release of management-sensitive species. The focus was on walleye (Sander vitreus) because they are abundant and popular among anglers. A few northern pike (Esox lucius) and a smaller number of smallmouth bass (Micropterus dolomieui) were also collected at three of the four sites. Samples of the fish were analyzed for cesium-137 ({sup 137}Cs), strontium-90 ({sup 90}Sr), mercury (Hg), and selected organo-chlorine compounds. Concentrations of {sup 137}Cs in the flesh and {sup 90}Sr in the bones of sport fish were low and similar at all four locations and appear to reflect the global residuals from nuclear weapons testing (primarily in the 1960's) as opposed to releases from CRL. Possible explanations are: 1) Reductions in radionuclide releases from CRL in recent decades and 2) Relatively large foraging ranges of sport fish. Mercury concentrations were elevated in fishes in the Ottawa River and were significantly higher at the Sandspit and Rolphton than at Mackey and Cotnam Island (p<0.001). Mercury concentrations from the four sites are comparable to concentrations in other Ontario and Quebec lakes. It is advisable therefore, that consumers follow the fish consumption guidelines issued by provincial authorities when eating fish from the Ottawa River. Organo-chlorine compounds were not detected in walleye; however, they were detected in all eight of the pike collected at Cotnam Island. The highest organo

  2. Edibility of sport fishes in the Ottawa River near Chalk River Laboratories

    International Nuclear Information System (INIS)

    Lee, D.R.; Chaput, T.; Miller, A.; Wills, C.A.

    2013-01-01

    To address the question of edibility of fish in the Ottawa River near Chalk River Laboratories (CRL), 123 game fish were collected for analysis from four locations: Mackey and Rolphton (45 km and 35 km upstream of Chalk River Laboratories (CRL), respectively), the Sandspit (Pointe au Bapteme) and Cotnam Island (1.6 km and 45 km downstream of CRL, respectively). Twenty-six to thirty-six game fish were collected at each location in 2007 and samples of flesh or bone were analyzed. Trap nets were used to collect only the fish required, allowing release of management-sensitive species. The focus was on walleye (Sander vitreus) because they are abundant and popular among anglers. A few northern pike (Esox lucius) and a smaller number of smallmouth bass (Micropterus dolomieui) were also collected at three of the four sites. Samples of the fish were analyzed for cesium-137 ( 137 Cs), strontium-90 ( 90 Sr), mercury (Hg), and selected organo-chlorine compounds. Concentrations of 137 Cs in the flesh and 90 Sr in the bones of sport fish were low and similar at all four locations and appear to reflect the global residuals from nuclear weapons testing (primarily in the 1960's) as opposed to releases from CRL. Possible explanations are: 1) Reductions in radionuclide releases from CRL in recent decades and 2) Relatively large foraging ranges of sport fish. Mercury concentrations were elevated in fishes in the Ottawa River and were significantly higher at the Sandspit and Rolphton than at Mackey and Cotnam Island (p<0.001). Mercury concentrations from the four sites are comparable to concentrations in other Ontario and Quebec lakes. It is advisable therefore, that consumers follow the fish consumption guidelines issued by provincial authorities when eating fish from the Ottawa River. Organo-chlorine compounds were not detected in walleye; however, they were detected in all eight of the pike collected at Cotnam Island. The highest organo-chlorine concentrations were measured in two

  3. Structural and Lithological Controls upon Fluid Migration within the Chalk and Upper Greensand Aquifers in the Chilterns and Lambourn Downs

    OpenAIRE

    Thompson, Sally

    2002-01-01

    The influence of lithological heterogeneities, structural discontinuities and discontinuity surface mineralisation upon groundwater migration within the Chalk and the Upper Greensand of southern England has been investigated. Lithological heterogeneities in the Chalk succession include marl seams, hardgrounds, tabular flints and nodular flints. Each of these heterogeneities has a lower intrinsic porosity and permeability than in the calcite rich chalk. The influence that each of these ...

  4. Source and persistence of pesticides in a semi-confined chalk aquifer of southeast England

    International Nuclear Information System (INIS)

    Lapworth, D.J.; Gooddy, D.C.

    2006-01-01

    Pesticide contamination in groundwater is an increasing problem that poses a significant long-term threat to water quality. Following the detection of elevated concentrations of diuron in boreholes in a semi-confined chalk aquifer from southeast England, a sampling programme was undertaken. Between 2003 and 2004 diuron was observed in 90% of groundwaters analysed. In 60% of groundwater samples metabolites of diuron were more prevalent than the parent compound. Longer-term (1989-2005) monitoring shows that pollution of the aquifer by atrazine, simazine, and more recently diuron, shows a positive correlation with periods of high groundwater levels. Results from groundwater residence time indicators suggest that the highest diuron concentrations are associated with waters containing the greatest proportion of recent recharge. There is some evidence to indicate that diuron occurrence can be spatially related to areas of urban and industrial development and is probably correlated with amenity usage. - Pesticides and their metabolites from amenity use pose a long-term threat to groundwater quality

  5. Source and persistence of pesticides in a semi-confined chalk aquifer of southeast England

    Energy Technology Data Exchange (ETDEWEB)

    Lapworth, D.J. [British Geological Survey, Maclean Building, Wallingford, Oxon OX10 8BB (United Kingdom); Gooddy, D.C. [British Geological Survey, Maclean Building, Wallingford, Oxon OX10 8BB (United Kingdom)]. E-mail: dcg@bgs.ac.uk

    2006-12-15

    Pesticide contamination in groundwater is an increasing problem that poses a significant long-term threat to water quality. Following the detection of elevated concentrations of diuron in boreholes in a semi-confined chalk aquifer from southeast England, a sampling programme was undertaken. Between 2003 and 2004 diuron was observed in 90% of groundwaters analysed. In 60% of groundwater samples metabolites of diuron were more prevalent than the parent compound. Longer-term (1989-2005) monitoring shows that pollution of the aquifer by atrazine, simazine, and more recently diuron, shows a positive correlation with periods of high groundwater levels. Results from groundwater residence time indicators suggest that the highest diuron concentrations are associated with waters containing the greatest proportion of recent recharge. There is some evidence to indicate that diuron occurrence can be spatially related to areas of urban and industrial development and is probably correlated with amenity usage. - Pesticides and their metabolites from amenity use pose a long-term threat to groundwater quality.

  6. Porosity and sonic velocity depth trends of Eocene chalk in Atlantic Ocean: Influence of effective stress and temperature

    DEFF Research Database (Denmark)

    Awedalkarim, Ahmed; Fabricius, Ida Lykke

    2014-01-01

    We aimed to relate changes in porosity and sonic velocity data, measured on water-saturated Eocene chalks from 36 Ocean Drilling Program drill sites in the Atlantic Ocean, to vertical effective stress and thermal maturity. We considered only chalk of Eocene age to avoid possible influence...... not show or at least it is difficult to define a clear pore-stiffening contact cementation trend as the Ontong Java Plateau chalk. Mechanical compaction is the principal cause of porosity reduction (at shallow depths) in the studied Eocene chalk, at least down to about 5MPa Terzaghi׳s effective stress...

  7. Application of PIXE analysis to environmental samples stable element distribution in sea algae by scanning microprobe analysis

    International Nuclear Information System (INIS)

    Ishikawa, M.; Kitao, K.; Imaseki, H.; Ishii, T.; Uchida, S.

    1984-01-01

    The resolution of a 33+-3 μm microprobe focussed with quadrupole doublet installed at the 3 MV Van de Graaff of the National Institute of Radiological Sciences, Japan, was used for the present analysis. Brown algae, Hizikia fusiforme was the sample target bombarded with a 2 MeV proton beam collimated mechanically into a rectangular image of 100 μm x 700 μm. Scanning across the sample target prepared into a longitudinal section from the caulis of the algae provided the following observations. More than 12 elements such as Al, Si, P, Cl, Ca, Mn, Fe, Cu, Zn, As, Br and Sr were determined simultaneously, together with their distributional information across the diameter. In the medullary layer, Mn and Zn were specific in their accumulation, while the deposition of Fe, Cu, As and Br were observed to be high in the epithelial layer, especially Fe and Cu which were found on the surface, where they contacted ambient sea water, but no significant change in pattern was indicated for such elements as Al, P and Cl. The PIXE microprobe analysis was, therefore, effective in its detectability for elements below a few ppm level, resultantly providing further possibilities for collecting information from bio-medical and environmental samples on trace characterization of elements. (author)

  8. Interstitial water studies on small core samples, Deep Sea Drilling Project, Leg 5

    Science.gov (United States)

    Manheim, F. T.; Chan, K.M.; Sayles, F.L.

    1970-01-01

    Leg 5 samples fall into two categories with respect to interstitial water composition: 1) rapidly deposited terrigenous or appreciably terrigenous deposits, such as in Hole 35 (western Escanaba trough, off Cape Mendocino, California); and, 2) slowly deposited pelagic clays and biogenic muds and oozes. Interstitial waters in the former show modest to slight variations in chloride and sodium, but drastic changes in non-conservative ions such as magnesium and sulfate. The pelagic deposits show only relatively minor changes in both conservative and non-conservative pore fluid constituents. As was pointed out in earlier Leg Reports, it is believed that much of the variation in chloride in pore fluids within individual holes is attributable to the manipulation of samples on board ship and in the laboratory. On the other hand, the scatter in sodium is due in part to analytical error (on the order of 2 to 3 per cent, in terms of a standard deviation), and it probably accounts for most of the discrepancies in total anion and cation balance. All constituents reported here, with the exception of bulk water content, were analyzed on water samples which were sealed in plastic tubes aboard ship and were subsequently opened and divided into weighed aliquots in the laboratory. Analytical methods follow the atomic absorption, wet chemical and emission spectrochemical techniques briefly summarized in previous reports, e.g. Manheim et al., 1969, and Chan and Manheim, 1970. The authors acknowledge assistance from W. Sunda, D. Kerr, C. Lawson and H. Richards, and thank D. Spencer, P. Brewer and E. Degens for allowing the use of equipment and laboratory facilities.

  9. Determination of environmental levels of 239240Pu, 241Am, 137Cs, and 90Sr in large volume sea water samples

    International Nuclear Information System (INIS)

    Sutton, D.C.; Calderon, G.; Rosa, W.

    1976-06-01

    A method is reported for the determination of environmental levels of 239 240 Pu and 241 Am in approximately 60-liter size samples of seawater. 137 Cs and 90 Sr were also separated and determined from the same samples. The samples were collected at the sea surface and at various depths in the oceans through the facilities of the Woods Hole Oceanographic Institution. Plutonium and americium were separated from the seawater by iron hydroxide scavenging then treated with a mixture of nitric, hydrochloric, and perchloric acids. A series of anion exchange separations were used to remove interferences and purify plutonium and americium; then each was electroplated on platinum disks and measured by solid state alpha particle spectrometry. The overall chemical yields averaged 62 +- 9 and 69 +- 14 percent for 236 Pu, and 243 Am tracers, respectively. Following the iron hydroxide scavenge of the transuranics, cesium was removed from the acidified seawater matrix by adsorption onto ammonium phosphomolybdate. Cesium carrier and 137 Cs isolation was effected by ion exchange and precipitations were made using chloroplatinic acid. The samples were weighed to determine overall chemical yield then beta counted. Cesium recoveries averaged 75 +- 5 percent. After cesium was removed from the seawater matrix, the samples were neutralized with sodium hydroxide and ammonium carbonate was added to precipitate 85 Sr tracer and the mixed alkaline earth carbonates. Strontium was separated as the nitrate and scavenged by chromate and hydroxide precipitations. Yttrium-90 was allowed to build up for two weeks, then milked and precipitated as the oxalate, weighed, and beta counted. The overall chemical yields of 85 Sr tracer averaged 84 +- 16 percent. The recovery of the yttrium oxalate precipitates averaged 96 +- 3 percent

  10. THE STUDY OF TECHNOLOGICAL PROPERTIES OF PLASTISOLS BASED EMULSION PVC FILLED WITH CHALK GIDROFOBIZIROVANNYM

    Directory of Open Access Journals (Sweden)

    V. A. Sedykh

    2014-01-01

    Full Text Available Baby toys are made using the centrifugal molding plastisol based emulsion of polyvinyl chloride plasticized with dioctylphthalate. To reduce cost and decrease biotelemetry the dioctylphthalate on the surface of the product domestic toys than toys produced in China, there was a necessity of introduction of the filler is chalk from different manufacturers. By using a Brookfield vis-cometer PV-D was studied rheology of filled hydrophobized chalk PVC plastisols in storage conditions for up to 72 hours at temperatures of 14-20°C. It was found that the flow plastisols consistent with pseudo-plastic fluids. Given the flow rates of emulsion PVC plastisols filled to 35 % of the mass. hydrophobized chalk. The influence of the content of the plasticizer dioctylphthalate in a narrow interval (37,0 - 41,4 % of the mass. on the viscosity of polymer pastes and the kinetics of its changes during storage. Revealed a linear dependence of the viscosity of the filled hydrophobized chalk plastisols on the speed of rotation of the spindle of the viscometer and during storage. Given the rate of expansion changes the viscosity of the plastisols of the speed of rotation of the spindle of the viscometer, the rate of change in viscosity and calculation of the initial viscosity. Determined the stability of the dispersion hydrophobized chalk in a colloidal solution of PVC in dioctylphthalate during storage. We determined the variation of the content of chalk (ash with top and bottom layers plastisols height 8 cm after 24 hours storage. It is proved that the temperature of the preparation and storage of polymer pastes were determining factors in the regulation of such technological properties of PVC plastisols in the presence hydrophobized chalkas viscosity, stability of the dispersion of chalk and, consequently, the efficiency of distribution plastisols in the form of a centrifugal molding.

  11. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the ODEN in the Arctic Ocean, Beaufort Sea and Bering Sea from 2005-08-19 to 2005-09-25 (NODC Accession 0108129)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108129 includes chemical, discrete sample, physical and profile data collected from ODEN in the Arctic Ocean, Beaufort Sea and Bering Sea from...

  12. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from JAKOV SMIRNITSKIY in the Beaufort Sea, East Siberian Sea and others from 2008-08-15 to 2008-09-16 (NODC Accession 0108368)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108368 includes chemical, discrete sample, physical and profile data collected from JAKOV SMIRNITSKIY in the Beaufort Sea, East Siberian Sea, Kara...

  13. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MIRAI in the East China Sea, Japan Sea and others from 2005-10-31 to 2006-01-30 (NODC Accession 0109919)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109919 includes chemical, discrete sample, physical and profile data collected from MIRAI in the East China Sea (Tung Hai), Japan Sea, North Pacific...

  14. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the G.O. SARS in the North Greenland Sea and Norwegian Sea from 2006-07-21 to 2006-08-05 (NODC Accession 0105859)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0105859 includes chemical, discrete sample, physical and profile data collected from G.O. SARS in the North Greenland Sea and Norwegian Sea from...

  15. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the Barents Sea and Norwegian Sea from 2001-08-22 to 2001-08-29 (NODC Accession 0113887)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113887 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the Barents Sea and Norwegian Sea from 2001-08-22...

  16. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the Beaufort Sea and Bering Sea from 2006-08-21 to 2006-09-29 (NODC Accession 0112268)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112268 includes chemical, discrete sample, optical, physical and profile data collected from MIRAI in the Beaufort Sea and Bering Sea from 2006-08-21...

  17. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the FRANKLIN in the Coral Sea and Tasman Sea from 1993-06-24 to 1993-07-17 (NODC Accession 0116409)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116409 includes chemical, discrete sample, physical and profile data collected from FRANKLIN in the Coral Sea and Tasman Sea from 1993-06-24 to...

  18. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1997-04-14 to 1997-05-22 (NODC Accession 0113563)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113563 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  19. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1995-02-17 to 1995-03-18 (NODC Accession 0113543)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113543 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

  20. Other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from unknown platforms in the North Atlantic Ocean, North Sea and Norwegian Sea from 1874-01-01 to 2005-12-31 (NCEI Accession 0144342)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144342 includes discrete sample and profile data collected from unknown platforms in the North Atlantic Ocean, North Sea and Norwegian Sea from...

  1. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1998-03-08 to 1998-03-24 (NODC Accession 0113546)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113546 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

  2. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1997-02-25 to 1997-03-24 (NODC Accession 0113545)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113545 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

  3. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1994-02-24 to 1994-03-17 (NODC Accession 0113541)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113541 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

  4. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea and Norwegian Sea from 1994-08-26 to 1994-09-10 (NODC Accession 0113542)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113542 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea and Norwegian Sea from...

  5. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1995-04-27 to 1995-05-23 (NODC Accession 0113561)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113561 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  6. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JAMES CLARK ROSS in the North Greenland Sea and Norwegian Sea from 1996-07-20 to 1996-08-22 (NODC Accession 0113757)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113757 includes chemical, discrete sample, physical and profile data collected from JAMES CLARK ROSS in the North Greenland Sea and Norwegian Sea...

  7. Dissolved inorganic carbon, alkalinity, temperature, salinity and DISSOLVED OXYGEN collected from profile and discrete sample observations using Alkalinity titrator, CTD and other instruments from the Pacific Celebes in the Alboran Sea, Arabian Sea and others from 2007-06-11 to 2012-03-18 (NODC Accession 0081040)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0081040 includes chemical, discrete sample, physical and underway - surface data collected from Pacific Celebes in the Alboran Sea, Arabian Sea,...

  8. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KAIYO-MARU in the East China Sea (Tung Hai) and Philippine Sea from 1996-06-20 to 1996-07-15 (NODC Accession 0115023)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115023 includes chemical, discrete sample, physical and profile data collected from KAIYO-MARU in the East China Sea (Tung Hai) and Philippine Sea...

  9. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from OCEAN RESEARCHER I in the Philippine Sea and South China Sea from 1991-07-08 to 1991-07-12 (NCEI Accession 0143948)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143948 includes discrete sample and profile data collected from OCEAN RESEARCHER I in the Philippine Sea and South China Sea (Nan Hai) from...

  10. Dissolved inorganic carbon, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from SAGAR SAMPADA in the Arabian Sea, Indian Ocean and Laccadive Sea from 1994-03-01 to 1995-05-03 (NODC Accession 0117387)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0117387 includes chemical, discrete sample, physical and profile data collected from SAGAR SAMPADA in the Arabian Sea, Indian Ocean and Laccadive Sea...

  11. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1993-11-06 to 1993-12-02 (NODC Accession 0115679)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115679 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  12. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1992-11-05 to 1992-12-01 (NODC Accession 0115403)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115403 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  13. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1991-11-05 to 1991-11-27 (NODC Accession 0115685)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115685 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  14. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1994-05-25 to 1994-06-06 (NODC Accession 0113954)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113954 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  15. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the Japan Sea, North Pacific Ocean and Sea of Okhotsk from 2006-08-01 to 2006-08-20 (NODC Accession 0112267)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112267 includes chemical, discrete sample, optical, physical and profile data collected from MIRAI in the Japan Sea, North Pacific Ocean and Sea of...

  16. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1996-10-30 to 1996-11-10 (NODC Accession 0115680)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115680 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  17. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the YMER in the Arctic Ocean, Barents Sea and North Greenland Sea from 1980-08-11 to 1980-09-19 (NODC Accession 0113607)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113607 includes chemical, discrete sample, physical and profile data collected from YMER in the Arctic Ocean, Barents Sea and North Greenland Sea...

  18. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Arctic Ocean, Beaufort Sea and Bering Sea from 2000-08-03 to 2000-10-13 (NODC Accession 0112352)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112352 includes chemical, discrete sample, physical and profile data collected from MIRAI in the Arctic Ocean, Beaufort Sea and Bering Sea from...

  19. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1995-11-08 to 1995-11-26 (NODC Accession 0113562)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113562 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  20. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1998-08-01 to 1998-08-23 (NODC Accession 0113758)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113758 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian Sea from...

  1. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the USCGC POLAR SEA in the North Greenland Sea from 1992-07-15 to 1992-08-14 (NODC Accession 0115687)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115687 includes biological, chemical, discrete sample, physical and profile data collected from USCGC POLAR SEA in the North Greenland Sea from...

  2. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the USCGC POLAR SEA in the North Greenland Sea from 1993-07-18 to 1993-08-20 (NODC Accession 0114447)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0114447 includes biological, chemical, discrete sample, physical and profile data collected from USCGC POLAR SEA in the North Greenland Sea from...

  3. Three-dimensional temperature fields of the North Patagonian Sea recorded by Magellanic penguins as biological sampling platforms

    Science.gov (United States)

    Sala, Juan E.; Pisoni, Juan P.; Quintana, Flavio

    2017-04-01

    Temperature is a primary determinant of biogeographic patterns and ecosystem processes. Standard techniques to study the ocean temperature in situ are, however, particularly limited by their time and spatial coverage, problems which might be partially mitigated by using marine top predators as biological platforms for oceanographic sampling. We used small archival tags deployed on 33 Magellanic penguins (Spheniscus magellanicus), and obtained 21,070 geo-localized profiles of water temperature, during late spring of 2008, 2011, 2012 and 2013; in a region of the North Patagonian Sea with limited oceanographic records in situ. We compared our in situ data of sea surface temperature (SST) with those available from satellite remote sensing; to describe the three-dimensional temperature fields around the area of influence of two important tidal frontal systems; and to study the inter-annual variation in the three-dimensional temperature fields. There was a strong positive relationship between satellite- and animal-derived SST data although there was an overestimation by remote-sensing by a maximum difference of +2 °C. Little inter-annual variability in the 3-dimensional temperature fields was found, with the exception of 2012 (and to a lesser extent in 2013) where the SST was significantly higher. In 2013, we found weak stratification in a region which was unexpected. In addition, during the same year, a warm small-scale vortex is indicated by the animal-derived temperature data. This allowed us to describe and better understand the dynamics of the water masses, which, so far, have been mainly studied by remote sensors and numerical models. Our results highlight again the potential of using marine top predators as biological platforms to collect oceanographic data, which will enhance and accelerate studies on the Southwest Atlantic Ocean. In a changing world, threatened by climate change, it is urgent to fill information gaps on the coupled ocean-atmosphere system

  4. Experience with radioactive waste incineration at Chalk River Nuclear Laboratories

    International Nuclear Information System (INIS)

    Le, V.T.; Beamer, N.V.; Buckley, L.P.

    1988-06-01

    Chalk River Nuclear Laboratories is a nuclear research centre operated by Atomic Energy of Canada Limited. A full-scale waste treatment centre has been constructed to process low- and intermediate-level radioactive wastes generated on-site. A batch-loaded, two-stage, starved-air incinerator for solid combustible waste is one of the processes installed in this facility. The incinerator has been operating since 1982. It has consistently reduced combustible wastes to an inert ash product, with an average volume reduction factor of about 150:1. The incinerator ash is stored in 200 L drums awaiting solidification in bitumen. The incinerator and a 50-ton hydraulic baler have provided treatment for a combined volume of about 1300 m 3 /a of solid low-level radioactive waste. This paper presents a review of the performance of the incinerator during its six years of operation. In addition to presenting operational experience, an assessment of the starved-air incineration technique will also be discussed

  5. Foil changer for the Chalk River superconducting cyclotron

    International Nuclear Information System (INIS)

    Hoffmann, C.R.; Kilborn, R.I.; Mouris, J.E.; Proulx, D.R.; Weaver, J.F.

    1985-01-01

    Capture of an injected beam in the Chalk River superconducting cyclotron requires that a carbon stripping foil be accurately placed in a dee to intercept the incoming beam. Foil radial position must be precisely adjustable and foils must be easily replaced. A foil changing apparatus has been designed, built and tested to meet these requirements. The main components are a supply magazine, a transport system, and unloading and loading mechanisms. The magazine is on top of the cyclotron. It holds 300 foils and can be isolated from machine vacuum for refilling. Each foil is mounted on a stainless steel frame. A stainless steel roller chain fitted with 33 copper sleeves (shrouds) carries foils, one per shroud, down a dee stem to the midplane. A 12-bit absolute optical shaft encoder senses foil position. To replace a foil a shroud is positioned at the top of the cyclotron, a foil is removed, and another is transferred from the magazine to the empty shroud. Three stepping motors and associated electronics provide mechanical drive and are interfaced with a CAMAC control system

  6. Electrostatic deflector development at the Chalk River superconducting cyclotron

    International Nuclear Information System (INIS)

    Diamond, W.T.; Mitchel, G.R.; Almeida, J.; Schmeing, H.

    1991-01-01

    An electrostatic deflector is used to extract heavy-ion beans from the Chalk River superconducting cyclotron. Deflector voltages up to 100 kV across a 7 m gap (143 kV/cm) are needed to extract the full range of beams that the cyclotron is designed to accelerate. This goal remains a challenge, but substantial progress has been made over the past year. Voltages over 90 kV have been reliably maintained over a 7.5 mm gap with a magnetic field of 3 T. Voltages of 74 kV have been used with a reduced gap of 4.75 mm (corresponding to a field greater than 150 kV/cm) to extract beams with magnetic fields up to 4.25 T. Major progress was achieved when the authors introduced a water-cooled, negative high-voltage electrode, and changed the sparking plates and the thin septum from molybdenum to stainless steel. Efforts are continuing to attain a field of at least 143 kV/cm over a gap of at least 6 mm width

  7. Foil changer for the Chalk River superconducting cyclotron

    International Nuclear Information System (INIS)

    Hoffmann, C.R.; Kilborn, R.I.; Mouris, J.F.; Proulx, D.R.; Weaver, J.F.

    1985-01-01

    Capture of an injected beam in the Chalk River superconducting cyclotron requires that a carbon stripping foil be accurately placed in a dee to intercept the incoming beam. Foil radial position must be precisely adjustable and foils must be easily replaced. A foil changing apparatus has been designed, built and tested to meet these requirements. The main components are a supply magazine, a transport system, and unloading and loading mechanisms. The magazine is on top of the loading mechanisms. The magazine is on top of the cyclotron. It holds 300 foils and can be isolated from machine vacuum for refilling. Each foil is mounted on a stainless steel frame. A stainless steel roller chain fitted with 33 copper sleeves (shrouds) carries foils, one per shroud, down a dee stem to the midplane. A 12-bit absolute optical shaft encoder senses foil position. To replace a foil a shroud is positioned at the top of the cyclotron, a foil is removed, and another is transferred from the magazine to the empty shroud. Three stepping motors and associated electronics provide mechanical drive and are interfaced with a CAMAC control system

  8. The Chalk River helium jet and skimmer system

    International Nuclear Information System (INIS)

    Schmeing, H.; Koslowsky, V.; Wightman, M.; Hardy, J.C.; MacDonald, J.A.; Faestermann, T.; Andrews, H.R.; Geiger, J.S.; Graham, R.L.

    1976-01-01

    A helium jet and skimmer system intended as an interface between a target location at the Chalk River tandem accelerator and the ion source of an on-line separator presently under construction has been developed. The system consists of a target chamber, a 125 cm long capillary, and a one stage skimmer chamber. The designs of the target and skimmer chambers allow one to vary a large number of independent flow and geometrical parameters with accurate reproducibility. Experiments with the β-delayed proton emitter 25 Si (tsub(1/2)=218 ms) produced in the reaction 24 Mg( 3 He,2n) 25 Si show that under optimized conditions about 75% of the reaction products leaving the target are transported to the skimmer. Of those, more than 90% pass through the skimmer orifice, which separates off 97.5% of the transport gas, helium. By introducing an additional helium flow across the skimming orifice the amount of helium separated off the transport jet can be increased to beyond 99.85%, leaving the high throughput of recoils unaffected. (Auth.)

  9. Compaction monitoring in the Ekofisk area Chalk Fields

    International Nuclear Information System (INIS)

    Menghini, M.L.

    1989-01-01

    In late Nov. 1984, the subsidence phenomenon was recognized in the Ekofisk field. To determine the magnitude and areal extent of the formation compaction, a program for measuring compaction with electric logging tools was initiated. Initial time-lapse surveys performed with cased-hole neutron tools indicated that reservoir compaction was occurring, but the accuracy of the determination of compaction rate was low. In addition to the cased-hole neutron survey, radioactive markers and a gamma ray (GR) detection tool were used to determine compaction rate in the reservoir more accurately and to determine whether compaction was occurring in the overburden. A program for implanting radioactive-marker bullets and subsequent monitoring with a four-detector GR tool was implemented. There are currently 13 wells equipped with radioactive markers in the compaction monitoring program. Compaction monitoring accuracy using the four-detector GR tool was found to depend on wellbore geometry, completion design, and radioactive-marker placement. This paper gives the results of the program to date and describes the operational procedures and analysis techniques used for compaction monitoring in the greater Ekofisk area chalk fields

  10. Benthic macrofauna variations and community structure in Cenomanian cyclic chalk-marl from Southerham Grey Pit, SE England

    DEFF Research Database (Denmark)

    Lauridsen, Bodil Wesenberg; Gale, A. S.; Surlyk, Finn

    2009-01-01

    Cenomanian chalk-marl couplets from England represent the 20 ka Milankovitch precession cycle. Fossil communities from both chalk and marl are identified to test if the orbital fluctuations and the associated changes in substrate lithology and climate exerted any control on the benthic macrofauna...

  11. Trace determination of heavy metal concentrations in fauna, flora and salt samples from Black Sea waters by charged particles - induced X-rays

    International Nuclear Information System (INIS)

    Badica, T.; Ciortea, C.; Dima, S.; Petrovici, A.; Popescu, I.; Serbanescu, O.

    1977-01-01

    Studies were performed on Black Sea pollution by charged particles induced X-rays spectra analysis, using alpha and 16 O beams. Fauna, flora and salt samples were analysed. We found some of the concentrations of pollutant elements to be below the accepted levels. (author)

  12. The use of at-sea-sampling data to dissociate environmental variability in Norway lobster (Nephrops norvegicus) catches to improve resource efficiency

    DEFF Research Database (Denmark)

    Feekings, Jordan P.; Christensen, Asbjørn; Jonsson, Patrik

    2014-01-01

    The primary aim of this study was to determine whether the information collected as part of the at-sea-sampling program could be used to identify hydrographical and environmental variables that are influential on catch rates of Norway lobster. Ultimately, we wanted to know whether environmental...

  13. Study on the application of electrothermal atomization atomic absorption spectrometry for the determination of metallic Cu, Pb, Zn, Cd traces in sea water samples

    International Nuclear Information System (INIS)

    Nguyen Thi Kim Dung; Doan Thanh Son; Tran Thi Ngoc Diep

    2004-01-01

    The trace amount of some heavy metallic elements (Cu, Zn, Pb, Cd) in sea water samples were determined directly (without separation) and quantitatively by using Electro-Thermal Atomization Atomic Absorption Spectrometry (ETA-AAS). The effect of mainly major constituents such as Na, Mg, Ca, K, and the mutual effect of the trace elements, which were present in the matrix on the absorption intensity of each analyzed element was studied. The adding of a certain chemical modification for each trace element was also investigated in order to eliminate the overall effect of the background during the pyrolysis and atomization. The sea water sample after fitrating through a membrane with 0.45 μm-hole size was injected in to the graphite tube via an autosampler (MPE50). The absorption intensity of each element was then measured on the VARIO-6 under the optimum parameters for spectrometer such as: maximum wavelength, current of hollow cathode lamp, and that for graphite furnace such as dry temperature, pyrolysis temperature, atomization temperature, ect. The analytical procedures were set-up and applied for the determination of these above mentioned elements in the synthesized sea water sample and in the real sea water samples with high precision and accuracy. (author)

  14. Twelve tips for the production of digital chalk-talk videos.

    Science.gov (United States)

    Rana, Jasmine; Besche, Henrike; Cockrill, Barbara

    2017-06-01

    Increasingly over the past decade, faculty in medical and graduate schools have received requests from digital millennial learners for concise faculty-made educational videos. At our institution, over the past couple of years alone, several hundred educational videos have been created by faculty who teach in a flipped-classroom setting of the pre-clinical medical school curriculum. Despite the appeal and potential learning benefits of digital chalk-talk videos first popularized by Khan Academy, we have observed that the conceptual and technological barriers for creating chalk-talk videos can be high for faculty. To this end, this tips article offers an easy-to-follow 12-step conceptual framework to guide at-home production of chalk-talk educational videos.

  15. Lithostratigraphy of the Palaeogene - Lower Neogene succession of the Danish North Sea

    DEFF Research Database (Denmark)

    Schiøler, Poul-Henrik; Andsbjerg, Jan; Clausen, Ole Rønø

    2007-01-01

    sediments of the Danish sector of the North Sea is revised. The sediment package from the top of the Chalk Group to the base of the Nordland Group is subdivided into seven formations containing eleven new members. The existing Våle, Lista, Sele, Fur, Balder, Horda and Lark Formations of previously...

  16. Radiochemical data obtained by α spectrometry on unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea

    International Nuclear Information System (INIS)

    Choukri, A.; Hakam, O.K.; Reyss, J.L.; Plaziat, J.C.

    2007-01-01

    In this work, radiochemical results obtained by α spectrometry on 80 unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea are presented and discussed. The coral samples were collected in Egypt from the emerged 5e coral reef terraces over 500km from The Ras Gharib-Ras Shukeir depression (28 deg. 10 ' ) in the north to Wadi Lahami (north of Ras Banas, 24 deg. 10 ' ) in the south. The statistical description of radiochemical results (concentrations of U and Th radioisotopes, 234 U/ 238 U activity ratios and ages) obtained on a great number of coral samples showed that it is possible to establish methodological criterions which could be used to validate the measured ages before confronting them to the geological context of sampling sites. The obtained results confirm that the unrecrystallized corals ( 232 Th 238 U varies between 2.2 and 4.9ppm around an average of 3.18+/-0.65ppm. 234 U/ 238 U activity ratios are between 1.08 and 1.28 with an averaged value of 1.164+/-0.016 which exceeds that of present day sea water but which is in agreement with the ratio of 1.16 measured by a precise mass spectrometry in many Pleistocene coral samples. Except three samples dated at least 100ka, the radiochemical age of 5e coral samples vary between 108 and 131ka with an average value of 122.2ka and a standard deviation of 4.3ka. Except for samples from the Zeit area, the reef terrace is between 2 and 6m above the present sea level. This position is similar to the highest sea level from the last interglacial according to the glacio-isostatic rebound calculated for stable regions. This work proves that the large tectonic motions which affected the studied area after the Oligocene ceased after at least the last interglacial period

  17. Marine macrofossil communities in the uppermost Maastrichtian chalk of Stevns Klint, Denmark

    DEFF Research Database (Denmark)

    Hansen, Thomas; Surlyk, Finn

    2014-01-01

    Three successive marine habitats and their benthic macrofossil communities have been recognised and assessed in the uppermost Maastrichtian chalk of Stevns Klint, Denmark. The mound-bedded lower Sigerslev Member was deposited below the photic zone under the influence of persistent, non-erosive bo......Three successive marine habitats and their benthic macrofossil communities have been recognised and assessed in the uppermost Maastrichtian chalk of Stevns Klint, Denmark. The mound-bedded lower Sigerslev Member was deposited below the photic zone under the influence of persistent, non...

  18. Capillary fringe and tritium and nitrogen tracing history in the Senonian chalk of Champagne

    International Nuclear Information System (INIS)

    Ballif, J.L.

    1998-01-01

    In the middle of Champagne-Ardenne area, a chalky zone is located, directly on top of which lies the soil and in which the water table is relatively close the soil; which allows for capillary direction to the surface horizons and the renewal of water reserve. After the presentation of the hydrological characteristics, the total porosity of chalk, the pores distribution, the capillary attraction is shown by the hydrological comportment of the soil and the upper part of the unsaturated zone of chalk. In the homogeneous rock, the tritium and nitrogen transfers reveal the historical tracks. (authors)

  19. Sampling

    CERN Document Server

    Thompson, Steven K

    2012-01-01

    Praise for the Second Edition "This book has never had a competitor. It is the only book that takes a broad approach to sampling . . . any good personal statistics library should include a copy of this book." —Technometrics "Well-written . . . an excellent book on an important subject. Highly recommended." —Choice "An ideal reference for scientific researchers and other professionals who use sampling." —Zentralblatt Math Features new developments in the field combined with all aspects of obtaining, interpreting, and using sample data Sampling provides an up-to-date treat

  20. Two-Year Monitoring of Water Samples from Dam of Iskar and the Black Sea, Bulgaria, by Molecular Analysis: Focus on Mycobacterium spp.

    Directory of Open Access Journals (Sweden)

    Stefan Panaiotov

    2015-06-01

    Full Text Available The coast of the Bulgarian Black Sea is a popular summer holiday destination. The Dam of Iskar is the largest artificial dam in Bulgaria, with a capacity of 675 million m3. It is the main source of tap water for the capital Sofia and for irrigating the surrounding valley. There is a close relationship between the quality of aquatic ecosystems and human health as many infections are waterborne. Rapid molecular methods for the analysis of highly pathogenic bacteria have been developed for monitoring quality. Mycobacterial species can be isolated from waste, surface, recreational, ground and tap waters and human pathogenicity of nontuberculose mycobacteria (NTM is well recognized. The objective of our study was to perform molecular analysis for key-pathogens, with a focus on mycobacteria, in water samples collected from the Black Sea and the Dam of Iskar. In a two year period, 38 water samples were collected—24 from the Dam of Iskar and 14 from the Black Sea coastal zone. Fifty liter water samples were concentrated by ultrafiltration. Molecular analysis for 15 pathogens, including all species of genus Mycobacterium was performed. Our results showed presence of Vibrio spp. in the Black Sea. Rotavirus A was also identified in four samples from the Dam of Iskar. Toxigenic Escherichia coli was present in both locations, based on markers for stx1 and stx2 genes. No detectable amounts of Cryptosporidium were detected in either location using immunomagnetic separation and fluorescence microscopy. Furthermore, mass spectrometry analyses did not detect key cyanobacterial toxins. On the basis of the results obtained we can conclude that for the period 2012–2014 no Mycobacterium species were present in the water samples. During the study period no cases of waterborne infections were reported.

  1. Radiochemical data obtained by {alpha} spectrometry on unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea

    Energy Technology Data Exchange (ETDEWEB)

    Choukri, A. [Laboratoire de Physique de la Matiere et Rayonnement, Equipe de Physique et Techniques Nucleaires, UFR ' Faibles Radioactivites, Mathematiques physiques et environnement' Universite Ibn Tofail, Faculte des Sciences, Departement de Physique, P.B. 133, 14 000 Kenitra (Morocco)]. E-mail: choukrimajid@yahoo.com; Hakam, O.K. [Laboratoire de Physique de la Matiere et Rayonnement, Equipe de Physique et Techniques Nucleaires, UFR ' Faibles Radioactivites, Mathematiques physiques et environnement' Universite Ibn Tofail, Faculte des Sciences, Departement de Physique, P.B. 133, 14 000 Kenitra (Morocco); Reyss, J.L. [Laboratoire des Sciences de Climat et de l' Environnement, Domaine du CNRS, Avenue de la Terrasse 91 1958, Gif sur Yvette (France); Plaziat, J.C. [Universite de Paris-Sud, Departement des Sciences de la Terre, URA 723, Batiment 504, F-91405 Orsay, Cedex (France)

    2007-02-15

    In this work, radiochemical results obtained by {alpha} spectrometry on 80 unrecrystallized fossil coral samples from the Egyptian shoreline of the north-western Red Sea are presented and discussed. The coral samples were collected in Egypt from the emerged 5e coral reef terraces over 500km from The Ras Gharib-Ras Shukeir depression (28 deg. 10{sup '}) in the north to Wadi Lahami (north of Ras Banas, 24 deg. 10{sup '}) in the south. The statistical description of radiochemical results (concentrations of U and Th radioisotopes, {sup 234}U/{sup 238}U activity ratios and ages) obtained on a great number of coral samples showed that it is possible to establish methodological criterions which could be used to validate the measured ages before confronting them to the geological context of sampling sites. The obtained results confirm that the unrecrystallized corals ({sup 232}Th<3%) constitute the reliable means of determining the timing of Pleistocene sea-level fluctuations in the past. A few number of measured younger ages could be explain as a result of a rejuvenation due to latter addition of a ''younger'' uranium to the initial stock entered just after coral death. The obvious rejuvenation observed and confirmed is due to a recent cementation of aragonitic deposit on the fossil coral. {sup 238}U varies between 2.2 and 4.9ppm around an average of 3.18+/-0.65ppm. {sup 234}U/ {sup 238}U activity ratios are between 1.08 and 1.28 with an averaged value of 1.164+/-0.016 which exceeds that of present day sea water but which is in agreement with the ratio of 1.16 measured by a precise mass spectrometry in many Pleistocene coral samples. Except three samples dated at least 100ka, the radiochemical age of 5e coral samples vary between 108 and 131ka with an average value of 122.2ka and a standard deviation of 4.3ka. Except for samples from the Zeit area, the reef terrace is between 2 and 6m above the present sea level. This position is similar to

  2. Effect of fluid-solid friction on the stiffness of chalk

    DEFF Research Database (Denmark)

    Alam, Mohammad Monzurul; Nguh Akam, Hosea; Fabricius, Ida Lykke

    2011-01-01

    Chalks behave weaker at water saturated condition. We studied this softening effect as a function of Biot’s frequency ratio, which is a ratio between measured ultrasonic wave frequency and Biot critical frequency, fc. Kinematic viscosity of fluid and permeability of rock determines fc. We observe...

  3. Aerobic degradation potential of the herbicides mecoprop, dichlorprop and bentazone in groundwater from chalk aquifers

    DEFF Research Database (Denmark)

    Levi, Suzi; Hybel, Anne-Marie; Bjerg, Poul Løgstrup

    2011-01-01

    The aerobic degradation potential of mecoprop, dichlorprop and bentazone was studied at concentration of 1 μg/L in laboratory batch experiments with groundwater from chalk aquifers. Within the incubation period of 129 days, 14C-mecoprop concentration decreased to 60-80% in the microcosms with gro...

  4. WIMS-CRNL: A user's manual for the Chalk River version of WIMS

    International Nuclear Information System (INIS)

    Donnelly, J.V.

    1986-01-01

    This report describes the preparation of the input for WIMS-CRNL, the Chalk River version of the WIMS lattice code. Also included are notes on the operation of the code, contents of the associated libraries, and the relation of WIMS-CRNL to other versions of the code

  5. Measuring and Modeling the Displacement of Connate Water in Chalk Core Plugs during Water Injection

    DEFF Research Database (Denmark)

    Korsbech, Uffe C C; Aage, Helle Karina; Andersen, Bertel Lohmann

    2006-01-01

    and forms a mixed water bank with almost 100% connate water in the front behind which a gradual transition to pure injection water occurs. This result underpins log interpretations from waterflooded chalk reservoirs. An ad hoc model was set up by use of the results, and the process was examined...

  6. ACE - an algebraic compiler and encoder for the Chalk River datatron computer

    International Nuclear Information System (INIS)

    Kennedy, J.M.; Okazaki, E.A.; Millican, M.

    1960-03-01

    ACE is a program written for the Chalk River Datatron (Burroughs 205) Computer to enable the machine to compile a program for solving a problem from instructions supplied by the user in a notation related much more closely to algebra than to the machine's own code. (author)

  7. Reservoir fracture mapping using microearthquakes: Austin chalk, Giddings field, TX and 76 field, Clinton Co., KY

    Energy Technology Data Exchange (ETDEWEB)

    Phillips, W.S.; Rutledge, J.T.; Gardner, T.L. [SPE, Richardson, TX (United States); Fairbanks, T.D.; Miller, M.E.; Schuessler, B.K. [Los Alamos National Lab., NM (United States)

    1996-11-01

    Patterns of microearthquakes detected downhole defined fracture orientation and extent in the Austin chalk, Giddings field, TX and the 76 field, Clinton Co., KY. We collected over 480 and 770 microearthquakes during hydraulic stimulation at two sites in the Austin chalk, and over 3200 during primary production in Clinton Co. Data were of high enough quality that 20%, 31% and 53% of the events could be located, respectively. Reflected waves constrained microearthquakes to the stimulated depths at the base of the Austin chalk. In plan view, microearthquakes defined elongate fracture zones extending from the stimulation wells parallel to the regional fracture trend. However, widths of the stimulated zones differed by a factor of five between the two Austin chalk sites, indicating a large difference in the population of ancillary fractures. Post-stimulation production was much higher from the wider zone. At Clinton Co., microearthquakes defined low-angle, reverse-fault fracture zones above and below a producing zone. Associations with depleted production intervals indicated the mapped fractures had been previously drained. Drilling showed that the fractures currently contain brine. The seismic behavior was consistent with poroelastic models that predicted slight increases in compressive stress above and below the drained volume.

  8. Heating- and growing-degree days at Chalk River Nuclear Laboratories, 1976-1980

    International Nuclear Information System (INIS)

    Jay, P.C.; Wildsmith, D.P.

    1981-05-01

    An update of the report, Heating- and Growing-Degree-Days at Chalk River Nuclear Laboratories (AECL-5547) is presented along with various other meteorological variables which were not included in the previous publication. Also included, and shown in graph form, are the monthly degree-day frequencies. (author)

  9. Chemometrics methods for the investigation of methylmercury and total mercury contamination in mollusks samples collected from coastal sites along the Chinese Bohai Sea.

    Science.gov (United States)

    Yawei, Wang; Lina, Liang; Jianbo, Shi; Guibin, Jiang

    2005-06-01

    The development and application of chemometrics methods, principal component analysis (PCA), cluster analysis and correlation analysis for the determination of methylmercury (MeHg) and total mecury (HgT) in gastropod and bivalve species collected from eight coastal sites along the Chinese Bohai Sea are described. HgT is directly determined by atomic fluorescence spectrometry (AFS), while MeHg is measured by a laboratory established high performance liquid chromatography-atomic fluorescence spectrometry system (HPLC-AFS). One-way ANOVA and cluster analysis indicated that the bioaccumulation of Rap to accumulate Hg was significantly (P<0.05) different from other mollusks. Correlation analysis shows that there is linear relationship between MeHg and HgT in mollusks samples collected from coastal sites along the Chinese Bohai Sea, while in mollusks samples collected from Hongqiao market in Beijing City, there is not any linear relationship.

  10. Analysis of fine-dispersed chalk usage as mineral additive in the composition of sand aggrerate concrete

    Directory of Open Access Journals (Sweden)

    Светлана Николаевна Чепурная

    2016-12-01

    Full Text Available The research results of fine-disperse chalk addition on physical and mechanical properties of the cement stone and concrete are shown. It is determined that fine-disperse chalk addition in the binder composition increases the content of ultrafine particles. The chalk particles fill the pore space between the cement particles, increasing the packing density, which leads to a density increase, which consequently leads to improved physical and mechanical properties of the concrete: water tightness, cold resistance, corrosion resistance, crack resistance and other properties

  11. Low incidence of clonality in cold water corals revealed through the novel use of a standardized protocol adapted to deep sea sampling

    Science.gov (United States)

    Becheler, Ronan; Cassone, Anne-Laure; Noël, Philippe; Mouchel, Olivier; Morrison, Cheryl L.; Arnaud-Haond, Sophie

    2017-11-01

    Sampling in the deep sea is a technical challenge, which has hindered the acquisition of robust datasets that are necessary to determine the fine-grained biological patterns and processes that may shape genetic diversity. Estimates of the extent of clonality in deep-sea species, despite the importance of clonality in shaping the local dynamics and evolutionary trajectories, have been largely obscured by such limitations. Cold-water coral reefs along European margins are formed mainly by two reef-building species, Lophelia pertusa and Madrepora oculata. Here we present a fine-grained analysis of the genotypic and genetic composition of reefs occurring in the Bay of Biscay, based on an innovative deep-sea sampling protocol. This strategy was designed to be standardized, random, and allowed the georeferencing of all sampled colonies. Clonal lineages discriminated through their Multi-Locus Genotypes (MLG) at 6-7 microsatellite markers could thus be mapped to assess the level of clonality and the spatial spread of clonal lineages. High values of clonal richness were observed for both species across all sites suggesting a limited occurrence of clonality, which likely originated through fragmentation. Additionally, spatial autocorrelation analysis underlined the possible occurrence of fine-grained genetic structure in several populations of both L. pertusa and M. oculata. The two cold-water coral species examined had contrasting patterns of connectivity among canyons, with among-canyon genetic structuring detected in M. oculata, whereas L. pertusa was panmictic at the canyon scale. This study exemplifies that a standardized, random and georeferenced sampling strategy, while challenging, can be applied in the deep sea, and associated benefits outlined here include improved estimates of fine grained patterns of clonality and dispersal that are comparable across sites and among species.

  12. Differences between Whole Otolith and Broken-Burnt Otolith Ages of Red Mullet (Mullus barbatus ponticus Essipov, 1927) Sampled from the Black Sea (Samsun, Turkey)

    OpenAIRE

    POLAT, Nazmi; BOSTANCI, Derya; YILMAZ, Savaş

    2005-01-01

    Different bony structures as scales, vertebrae, otoliths, opercles and subopercles of 156 red mullet (Mullus barbatus ponticus Essipov, 1927) sampled from the Black Sea were removed for age determination. Otoliths were read once by two experienced readers. However, due to the difficulty of interpretation of annuli on the otolith edge, the broken-burnt method was applied to the 61 otoliths. Broken-burnt otoliths were also read once by the same two experienced readers. When whole otolith and br...

  13. Using high sampling rate (10/20 Hz) altimeter data for the observation of coastal surface currents: A case study over the northwestern Mediterranean Sea

    Science.gov (United States)

    Birol, Florence; Delebecque, Caroline

    2014-01-01

    Satellite altimetry, measuring sea surface heights (SSHs), has unique capabilities to provide information about the ocean dynamics. In this paper, the skill of the original full rate (10/20 Hz) measurements, relative to conventional 1-Hz data, is evaluated in the context of coastal studies in the Northwestern Mediterranean Sea. The performance and the question of the measurement noise are quantified through a comparison with different tide gauge sea level time series. By applying a specific processing, closer than 30 km to the land, the number of valid data is higher for the 10/20-Hz than for the 1-Hz observations: + 4.5% for T/P, + 10.3 for Jason-1 and + 13% for Jason-2. By filtering higher sampling rate measurements (using a 30-km cut-off low-pass Lanczos filter), we can obtain the same level of sea level accuracy as we would using the classical 1-Hz altimeter data. The gain in near-shore data results in a better observation of the Liguro-Provençal-Catalan Current. The seasonal evolution of the currents derived from 20-Hz data is globally consistent with patterns derived from the corresponding 1-Hz observations. But the use of higher frequency altimeter measurements allows us to observe the variability of the regional flow closer to the coast (~ 10-15 km from land).

  14. Diagenesis of upper cretaceous onshore and offshore chalk from the North Sea area

    DEFF Research Database (Denmark)

    Hjuler, Morten Leth

    grund af det høje poretryk i den centrale del af Nordsøen og på trods af dyb begravelse er meget porøs. Kalken fra Valhall lader dog til at være påvirket af den højere temperatur og er mere kemisk omdannet og formentlig stivere. Et andet problem er indholdet af opal og kvarts, som påvirker...... permeabiliteten. I Nørrejylland er kalken forholdsvis rig på opal, men i det dybere begravede Valhall-felt er opalen øjensynligt omdannet til kvarts. På Stevns derimod, er opalen øjensynlig forholdsvis kort efter aflejringen opløst og genudfældet i flintlag, muligvis hjulpet af mikroorganismer. Dette giver en...

  15. Likely-clean concrete disposition at Chalk River Laboratories

    Energy Technology Data Exchange (ETDEWEB)

    Betts, J.A. [Atomic Energy of Canada Limited, Chalk River, ON (Canada)

    2011-07-01

    The vast majority of wastes produced at nuclear licensed sites are no different from wastes produced from other traditional industrial activities. Radiation and contamination control practices ensure that the small amounts of waste materials that contain a radiation and or contamination hazard are segregated and managed appropriately according to the level of hazard. Part of the segregation process involves additional clearance checks of wastes generated in areas where the potential to become radioactively contaminated exists, but is very small and contamination control practices are such that the wastes are believed to be 'likely-clean'. This important clearance step helps to ensure that radioactive contamination is not inadvertently released during disposition of inactive waste materials. Clearance methods for bagged likely-clean wastes (i.e. small volumes of low density wastes) or discreet non-bagged items are well advanced. Clearance of bagged likely-clean wastes involves measuring small volumes of bagged material within purpose built highly sensitive bag monitors. For non-bagged items the outer surfaces are scanned to check for surface contamination using traditional hand-held contamination instrumentation. For certain very bulky and porous materials (such as waste concrete), these traditional clearance methods are impractical or not fully effective. As a somewhat porous (and dense) material, surface scanning cannot always be demonstrated to be conclusive. In order to effectively disposition likely-clean concrete, both the method of clearance (i.e. conversion from likely-clean to clean) and method of disposition have to be considered. Likely-clean concrete wastes have been produced at Chalk River Laboratories (CRL) from demolitions of buildings and structures, as well as small amounts from site maintenance activities. A final disposition method for this material that includes the secondary clearance check that changes the classification of this

  16. Likely-clean concrete disposition at Chalk River Laboratories

    International Nuclear Information System (INIS)

    Betts, J.A.

    2011-01-01

    The vast majority of wastes produced at nuclear licensed sites are no different from wastes produced from other traditional industrial activities. Radiation and contamination control practices ensure that the small amounts of waste materials that contain a radiation and or contamination hazard are segregated and managed appropriately according to the level of hazard. Part of the segregation process involves additional clearance checks of wastes generated in areas where the potential to become radioactively contaminated exists, but is very small and contamination control practices are such that the wastes are believed to be 'likely-clean'. This important clearance step helps to ensure that radioactive contamination is not inadvertently released during disposition of inactive waste materials. Clearance methods for bagged likely-clean wastes (i.e. small volumes of low density wastes) or discreet non-bagged items are well advanced. Clearance of bagged likely-clean wastes involves measuring small volumes of bagged material within purpose built highly sensitive bag monitors. For non-bagged items the outer surfaces are scanned to check for surface contamination using traditional hand-held contamination instrumentation. For certain very bulky and porous materials (such as waste concrete), these traditional clearance methods are impractical or not fully effective. As a somewhat porous (and dense) material, surface scanning cannot always be demonstrated to be conclusive. In order to effectively disposition likely-clean concrete, both the method of clearance (i.e. conversion from likely-clean to clean) and method of disposition have to be considered. Likely-clean concrete wastes have been produced at Chalk River Laboratories (CRL) from demolitions of buildings and structures, as well as small amounts from site maintenance activities. A final disposition method for this material that includes the secondary clearance check that changes the classification of this

  17. Determination of arsenic species in seafood samples from the Aegean Sea by liquid chromatography-(photo-oxidation)-hydride generation-atomic fluorescence spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Schaeffer, Richard [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Soeroes, Csilla [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Ipolyi, Ildiko [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Fodor, Peter [Department of Applied Chemistry, Corvinus University, Villanyi ut 29-35, 1118 Budapest (Hungary); Thomaidis, Nikolaos S. [Laboratory of Analytical Chemistry, Department of Chemistry, University of Athens, Panepistiomopolis Zografou, 15776 Athens (Greece)]. E-mail: ntho@chem.uoa.gr

    2005-08-15

    In this study arsenic compounds were determined in mussels (Mytulis galloprovincialis), anchovies (Engraulis encrasicholus), sea-breams (Sparus aurata), sea bass (Dicentrarchus labrax) and sardines (Sardina pilchardus) collected from Aegean Sea using liquid chromatography-photo-oxidation-hydride generation-atomic fluorescence spectrometry [LC-(PO)-HG-AFS] system. Twelve arsenicals were separated and determined on the basis of their difference in two properties: (i) the pK {sub a} values and (ii) hydride generation capacity. The separation was carried out both with an anion- and a cation-exchange column, with and without photo-oxidation. In all the samples arsenobetaine, AB was detected as the major compound (concentrations ranging between 2.7 and 23.1 {mu}g g{sup -1} dry weight), with trace amounts of arsenite, As(III), dimethylarsinic acid, DMA and arsenocholine, AC, also present. Arsenosugars were detected only in the mussel samples (in concentrations of 0.9-3.6 {mu}g g{sup -1} dry weight), along with the presence of an unknown compound, which, based on its retention time on the anion-exchange column Hamilton PRP-X100 and a recent communication [E. Schmeisser, R. Raml, K.A. Francesconi, D. Kuehnelt, A. Lindberg, Cs. Soeroes, W. Goessler, Chem. Commun. 16 (2004) 1824], is supposed to be a thio-arsenic analogue.

  18. Chemometrics methods for the investigation of methylmercury and total mercury contamination in mollusks samples collected from coastal sites along the Chinese Bohai Sea

    International Nuclear Information System (INIS)

    Wang Yawei; Liang Lina; Shi Jianbo; Jiang Guibin

    2005-01-01

    The development and application of chemometrics methods, principal component analysis (PCA), cluster analysis and correlation analysis for the determination of methylmercury (MeHg) and total mercury (HgT) in gastropod and bivalve species collected from eight coastal sites along the Chinese Bohai Sea are described. HgT is directly determined by atomic fluorescence spectrometry (AFS), while MeHg is measured by a laboratory established high performance liquid chromatography-atomic fluorescence spectrometry system (HPLC-AFS). One-way ANOVA and cluster analysis indicated that the bioaccumulation of Rap to accumulate Hg was significantly (P<0.05) different from other mollusks. Correlation analysis shows that there is linear relationship between MeHg and HgT in mollusks samples collected from coastal sites along the Chinese Bohai Sea, while in mollusks samples collected from Hongqiao market in Beijing City, there is not any linear relationship. - Rapana venosa might be used as a potential biomonitor for Hg pollution in the Bohai Sea, China

  19. Correlation of Element Concentration of Cd, Cr, Co and Sc in Sea Water, Fish and Algae Samples from Beach of Lemahabang Muria

    International Nuclear Information System (INIS)

    Sukirno; Rosidi; Agus Taftazani

    2007-01-01

    The analysis of Cd, Cr, Co, Sb and Sc element in beach environmental samples Lemahabang Muria in the year 2004 has been carried out by using neutron activation analysis (NAA) method. All of heavy metals from sea water (2.0 μg/l) are obviously lower than the threshold value established by SKRI No 51/2004. From the observed data by Excel application of the correlation value (r) shows that between Cd, Cr, Co, Sb and Sc concentrations from dependent variable of sea water about tree independent variable of kerapu fish, green and brown algae shows a highly positive significant correlation (r > 0.92) except element of Sb was sufficiently positive high (r = 0.66). (author)

  20. Acoustic and Petrophysical Evolution of Organic-Rich Chalk Following Maturation Induced by Unconfined Pyrolysis

    Science.gov (United States)

    Shitrit, Omri; Hatzor, Yossef H.; Feinstein, Shimon; Vinegar, Harold J.

    2017-12-01

    Thermal maturation is known to influence the rock physics of organic-rich rocks. While most studies were performed on low-porosity organic-rich shales, here we examine the effect of thermal maturation on a high-porosity organic-rich chalk. We compare the physical properties of native state immature rock with the properties at two pyrolysis-simulated maturity levels: early-mature and over-mature. We further evaluate the applicability of results from unconfined pyrolysis experiments to naturally matured rock properties. Special attention is dedicated to the elastic properties of the organic phase and the influence of bitumen and kerogen contents. Rock physics is studied based on confined petrophysical measurements of porosity, density and permeability, and measurements of bedding-normal acoustic velocities at estimated field stresses. Geochemical parameters like total organic carbon (TOC), bitumen content and thermal maturation indicators are used to monitor variations in density and volume fraction of each phase. We find that porosity increases significantly upon pyrolysis and that P wave velocity decreases in accordance. Solids density versus TOC relationships indicate that the kerogen increases its density from 1.43 to 1.49 g/cc at the immature and early-mature stages to 2.98 g/cc at the over-mature stage. This density value is unusually high, although increase in S wave velocity and backscatter SEM images of the over-mature samples verify that the over-mature kerogen is significantly denser and stiffer. Using the petrophysical and acoustic properties, the elastic moduli of the rock are estimated by two Hashin-Shtrikman (HS)-based models: "HS + BAM" and "HS kerogen." The "HS + BAM" model is calibrated to the post-pyrolysis measurements to describe the mechanical effect of the unconfined pyrolysis on the rock. The absence of compaction in the pyrolysis process causes the post-pyrolysis samples to be extremely porous. The "HS kerogen" model, which simulates a

  1. Ammonia and ammonium over the southern Baltic Sea. Part 1. Preparation of aerosol and air samples for the determination of ammonia by the indophenol method

    Directory of Open Access Journals (Sweden)

    Lucyna Falkowska

    2004-06-01

    Full Text Available 1997 saw the start of a study into the spatial and temporal changes in the chemical composition of the atmosphere over the littoral and offshore waters of the Baltic Sea. Collection of samples and their subsequent chemical analysis was preceded by meticulous laboratory experiments concerning the validation and adaptation of the analytical procedures. The colorimetric indophenol blue technique was used to analyse the aerosol samples for the concentration of ammonium ions and the air samples for their gaseous ammonia. The samples were collected with PTFE-filters and Whatman 41 filters coated with 5% orthophosphoric acid. This acid enhances the aerosol sampling efficacy but reduces the pH of the reaction in which indophenol is formed. The pH of the aerosol samples thus had to be raised, and this in turn required an alteration to the original procedure prior to ammonia determination. It was demonstrated that the addition of 0.1 N KOH to the filters coated with H3PO4 increases the pH of the reaction medium to the required level of pH = 8-11.5 and does not substantially influence the precision of the determination; the error of the modified procedure was of the order of 5.2%.      Air samples for the determination of gaseous ammonia were collected with annular denuders. Oxalic acid and citric acid are the usual impregnating agents. In the present experiments oxalic acid was used for denuder impregnation; it turned out to be more effective than citric acid under the conditions of the southern Baltic Sea.      The detection limit of the indophenol blue method in these laboratory experiments was 0.045 mmol dm-3. The respective relative standard deviations (RSD within the range of higher and lower concentrations were 0.64% and 4.53%.

  2. Experimental Study of Bacterial Penetration into Chalk Rock: Mechanisms and Effect on Permeability

    DEFF Research Database (Denmark)

    Halim, Amalia Yunita; Shapiro, Alexander; Eliasson Lantz, Anna

    2014-01-01

    Bacterial selective plugging is one of the mechanisms through which microorganisms can be applied for enhanced oil recovery, as bacteria can plug the water-swept zones of a reservoir, thus altering the flow paths and improving sweep efficiency. However, complete understanding of the penetration...... behavior of bacteria is lacking, especially in chalk formations where characteristic pore throat sizes are comparable with the sizes of bacterial cells. In this study, two bacterial strains, Bacillus licheniformis 421 (spore-forming) and Pseudomonas putida K12 (non-spore forming) were used to investigate...... the penetration of bacteria into chalk and its effect on permeability reduction. The core plugs were produced from Stevns Klint outcrop with low permeability (2–4 mD) and with pore sizes comparable to bacterial sizes. Both types of bacteria were able to penetrate and to be transported through the cores to some...

  3. Electroosmotic dewatering of chalk sludge, iron hydroxide sludge, wet fly ash and biomass

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, H.K.; Kristensen, I.V.; Ottosen, L.M.; Villumsen, A. [Dept. of Geology and Geotechnical Engineering, The Technical Univ. of Denmark, Lyngby (Denmark)

    2001-07-01

    Electroosmotic dewatering has been tested in laboratory cells for 4 different porous materials: chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge from enzyme production. In all cases it was possible to remove water when passing electric DC current through the material. Casagrande's coefficients for the three materials where determined at different water contents. In the electroosmotic experiments shown in this work chalk can be dewatered from 40% to 79% DM (dry matter), fly ash from 75 to 82% DM, iron hydroxide sludge from 2.7 to 19% DM and biomass from 3 to 33% DM. The process was not optimised indicating that higher dry matter contents could be achieved. (orig.)

  4. Acidity of sphagnum and its relation to chalk and mineral salts

    Energy Technology Data Exchange (ETDEWEB)

    Skene, M

    1915-01-01

    In addition to the criticism and elucidation of various other points, the chief conclusions which may be drawn from the preceding pages are: (1) There is a variation in acidity and in sensitiveness to chalk between the different species of sphagnum. (2) There is a correlation between degree of acidity and degree of sensitiveness. (3) The connection between the two is indirect, not direct. (4) The sphagna thrive in acid solutions: the injurious effect of chalk, and of alkalies in general, is due to the substitution of an alkaline for an acid reaction. (5) Mineral solutions are generally physiologically harmless, but may be ecologically harmful. (6) The sphagna do actually utilize in growth bases held absorbed by the acid compounds of the cell-walls.

  5. Strength and Biot's coefficient for high-porosity oil- or water-saturated chalk

    DEFF Research Database (Denmark)

    Andreassen, Katrine Alling

    . The Biot coefficient states the degree of cementation or how the pore pressure contributes to the strain resulting from an external load for a porous material. It is here calculated from dynamic measurements and correlated with the strength of outcrop chalk characterized by the onset of pore collapse...... during hydrostatic loading. The hypothesis is that the Biot coefficient and the theory of poroelasticity may cover the fluid effect by including the increased fluid bulk modulus from oil to water. A high number of test results for both oil- and water-saturated high-porosity outcrop chalk show correlation......In the petroleum industry it is relevant to know the Biot coefficient for establishing the effective stresses present in both the overburden and for the reservoir interval. When depleting a reservoir it is important to estimate the settlement through the strain imposed by the effective stress. Also...

  6. Investigated Miscible CO2 Flooding for Enhancing Oil Recovery in Wettability Altered Chalk and Sandstone Rocks

    Energy Technology Data Exchange (ETDEWEB)

    Tabrizy, Vahid Alipour

    2012-07-01

    The thesis addresses oil recovery by miscible CO2 flooding from modified sandstone and chalk rocks. Calcite mineral surface is modified with stearic acid (SA) and asphaltene, and the silicate mineral surfaces are modified with N,N-dimethyldodecylamine (NN-DMDA) and asphaltene. The stability of adsorbed polar components in presence of SO4 2- and Mg2 + ions is also investigated. Recovery from sandstone cores is consistently lower than that from chalk cores saturated with the same oil and flooded with CO2 at all miscible flooding conditions. This may be due to the larger permeability contrasts in sandstone cores, which promote the fingering phenomenon. Miscible CO2 flooding for chalk and sandstone cores with distilled water, as initial water saturation, shows also lower oil recovery than cores saturated with different ions. At higher miscible flooding conditions, higher oil recovery is obtained. However, presence of light components (such as C1 or C3) in oil reduced the recovery. Oil recovery in presence of methane (C1) is lower than that in presence of methane and propane (C1/C3). A ternary diagram was constructed in order to understand the CO2 flooding mechanism(s) at the different flooding conditions and in presence of light components. The side effect of the flooding with CO2 is the probability for asphaltene deposition. An approach based on solubility parameter in the liquid, is used to assess the risk for asphaltene deposition during CO2 miscible flooding. The light components (C1/C3) and higher flooding conditions enhanced the risk for asphaltene instability. It is also shown higher amount of asphaltene deposition in chalk cores than that in sandstone cores at similar miscibility conditions.(au)

  7. Overview of research in physics and health sciences at the Chalk River Nuclear Laboratories

    International Nuclear Information System (INIS)

    Milton, J.C.D.

    1988-01-01

    Toxicology research was a logical extension of existing program at Chalk River. Research in radiotoxicology has been going on there since the early forties. An overview of the existing physics and health sciences research programs operating at the Research Company of Atomic Energy of Canada Limited was presented. Programs in nuclear physics, heavy ion nuclear physics, astrophysical neutrino physics, condensed matter physics, fusion, biology, dosimetry, and environmental sciences were briefly described. In addition, a description of the research company organization was provided

  8. Analysis of the Pelletron charging chain break in the Chalk River MP tandem accelerator

    International Nuclear Information System (INIS)

    Burn, N.; Greiner, B.F.; Coleman, C.E.

    1980-11-01

    On February 7, 1980 one of the three Pelletron charging chains in the Low Energy end of the Chalk River MP Tandem Accelerator broke during normal operation. The chains had been in use for 38 000 h at the time of the break. Tensile tests were carried out on pieces of the broken chain as well as unused pieces of chain. Several possible reasons for the chain break are suggested; ways of improving performance and reliability are proposed. (auth)

  9. Agricultural diffuse pollution in a chalk aquifer (Trois Fontaines, France): Influence of pesticide properties and hydrodynamic constraints

    Science.gov (United States)

    Baran, N.; Lepiller, M.; Mouvet, C.

    2008-08-01

    SummaryThe characterization of the transfer of pesticides to and in groundwater is essential for effective water resource management. Intensive monitoring, from October 1989 to May 2006, of a weakly karstified chalk aquifer system in a 50 km 2 agricultural catchment, enabled the characterization of the temporal variability of pesticide concentrations in the groundwater of the main outlet. Atrazine and its metabolite deethylatrazine were quantified 394 and 393 times in 476 samples with concentrations ranging from the quantification limit (0.025 μg L -1) to 5.3 and 1.86 μg L -1, respectively. This common presence, compared to the rare detections of isoproturon (in 108 of 476 samples), the pesticide most widely used in the catchment during at least the past decade, highlighted the significant effect of pesticide properties in the time series of concentrations observed in the groundwater. The use of geochemical tracers (nitrate, chloride) analysed in the groundwater and the hydrodynamic monitoring of the system (discharge, water levels) enabled identification of various infiltration mechanisms governing the functioning of the system. The hydrodynamic study showing that the relative contribution of the infiltration mechanisms varies with time, made it possible to explain major variations observed in the pesticide-concentration time series recorded at the spring.

  10. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from Kaiyo in the Philippine Sea from 1994-02-12 to 1994-02-16 (NCEI Accession 0143635)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143635 includes discrete sample and profile data collected from Kaiyo in the Philippine Sea from 1994-02-12 to 1994-02-16. These data include DELTA...

  11. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from RYOFU MARU in the Philippine Sea from 1992-02-10 to 1992-02-17 (NCEI Accession 0143943)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143943 includes discrete sample and profile data collected from RYOFU MARU in the Philippine Sea from 1992-02-10 to 1992-02-17. These data include...

  12. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HEALY in the Arctic Ocean and Beaufort Sea from 2003-09-11 to 2003-10-18 (NODC Accession 0115676)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115676 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean and Beaufort Sea...

  13. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the OCEAN RESEARCHER I in the Philippine Sea from 1991-06-26 to 1991-07-04 (NODC Accession 0115598)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115598 includes chemical, discrete sample, physical and profile data collected from OCEAN RESEARCHER I in the Philippine Sea from 1991-06-26 to...

  14. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from OCEAN RESEARCHER I in the Philippine Sea from 1990-10-11 to 1990-10-15 (NODC Accession 0115600)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115600 includes chemical, discrete sample, physical and profile data collected from OCEAN RESEARCHER I in the Philippine Sea from 1990-10-11 to...

  15. PH, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from SHUMPU MARU in the Philippine Sea from 1992-02-25 to 1992-02-29 (NODC Accession 0115709)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115709 includes chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1992-02-25 to 1992-02-29....

  16. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HEALY in the Arctic Ocean and Beaufort Sea from 2004-07-18 to 2004-08-26 (NODC Accession 0113548)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113548 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean and Beaufort Sea...

  17. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JAN MAYEN in the Norwegian Sea from 1993-04-01 to 1995-11-01 (NODC Accession 0115677)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115677 includes chemical, discrete sample, physical and profile data collected from JAN MAYEN in the Norwegian Sea from 1993-04-01 to 1995-11-01 and...

  18. Tritium concentration in fresh, brackish and sea-water samples in Rokkasho-Village, Japan, bordered by nuclear fuel cycle facilities

    International Nuclear Information System (INIS)

    Ueda, S.; Kakiuchi, H.; Kondo, K.; Inaba, J.

    2006-01-01

    In order to identify the concentration of tritium ( 3 H) in areas of fresh, brackish and sea water, bordered by nuclear fuel facilities at Rokkasho-Village, Aomori, Japan, water samples were collected from 2001 to 2004 at six points in those areas. Concentration ranges of tritium in fresh river water, brackish lake and seawater samples were 0.60 to 1.1 Bq x l -1 (mean value 0.79 Bq x l -1 ), 0.20 to 0.87 Bq x l -1 (mean value 0.41 Bq x l -1 ), and 0.08 to 0.25 Bq x l -1 (mean value 0.15 Bq x l -1 ), respectively. Relationships between tritium concentrations and salinity in the samples showed a clear negative correlation. Moreover, the seasonal variation of tritium in water from Rokkasho-Village was high in spring and low in fall. (author)

  19. Sample-size dependence of diversity indices and the determination of sufficient sample size in a high-diversity deep-sea environment

    OpenAIRE

    Soetaert, K.; Heip, C.H.R.

    1990-01-01

    Diversity indices, although designed for comparative purposes, often cannot be used as such, due to their sample-size dependence. It is argued here that this dependence is more pronounced in high diversity than in low diversity assemblages and that indices more sensitive to rarer species require larger sample sizes to estimate diversity with reasonable precision than indices which put more weight on commoner species. This was tested for Hill's diversity number N sub(0) to N sub( proportional ...

  20. A review of geophysical investigations at the site of Chalk River Nuclear Laboratories, Ontario

    International Nuclear Information System (INIS)

    Thomas, M.D.; Hayles, J.G.

    1988-01-01

    The site of the Chalk River Nuclear Laboratories was one of the first research areas located on crystalline rocks to be extensively investigated under the Canadian Nuclear Fuel Waste Management Program. A large contribution to meeting the geoscientific objectives of the program has been made using a suite of geophysical techniques. Many of them are standard, though sometimes modified in terms of instrumentation and/or experimental and/or analytical procedures, to meet the particular needs of the waste management program. Relatively new techniques have also been employed. Much of the early evaluation and development of the various techniques took place at the Chalk River site. Standard methods such as gravity, magnetics and seismic sounding have been used to investigate bedrock structure, and the seismic method has also been used to estimate overburden thickness. Standard geophysical borehole logging has been used to obtain in situ estimates of physical properties, to locate fracture zones and to make hole to hole correlations that have helped define local structure. Several standard electrical (e.g. resitivity) and electromagnetic (e.g. VLF-EM) techniques have proven successful in identifying water-filled fractures and faults. Relatively new techniques introduced into the geophysics at Chalk River were: ground probing radar; to investigate overburden; borehole TV and acoustic televiewer and VLF-EM, to locate fractures; studies of seismic tube-waves, well tides and temperature logs, to investigate fracture location and permeability. Most of these methods have been successful and are now routinely employed at other research sites

  1. A summary of the Chalk River valve packing evaluation program 1985 - 1990

    International Nuclear Information System (INIS)

    Aikin, J.A.; Doubt, G.L.; Lade, C.R.

    1990-12-01

    The move away from asbestos-based valve packing products has generated concern among valve manufacturers, packing manufacturers and user groups about the reliability and safety of non-asbestos based products for long-term use. AECL Research, Chalk River, has been actively evaluating these new valve packing products since 1985. This report describes the work done at Chalk River from 1985 to 1990. The report includes both Electric Power Research Institute (EPRI) and CANDU Owners Group (COG) funded studies. A description of the test programs and a brief summary of the functional performance of the more successful materials (die-formed graphite, braided asbestos and braided non-asbestos) on friction, stem leakage and consolidation are provided. At this time, Chalk River and Ontario Hydro have approved the following packing arrangements: for non-live-loaded valves, the recommended replacements packing for braided asbestos is combination flexible graphite packing sets; and, for heavy water valves originally designed with JC187I, the recommended replacement packing is approved braided-asbestos products

  2. Spatial analysis of Carbon-14 dynamics in a wetland ecosystem (Duke Swamp, Chalk River Laboratories, Canada)

    International Nuclear Information System (INIS)

    Yankovich, T.L.; King-Sharp, K.J.; Carr, J.; Robertson, E.; Killey, R.W.D.; Beresford, N.A.; Wood, M.D.

    2014-01-01

    A detailed survey was conducted to quantify the spatial distribution of 14 C in Sphagnum moss and underlying soil collected in Duke Swamp. This wetland environment receives 14 C via groundwater pathways from a historic radioactive Waste Management Area (WMA) on Atomic Energy Canada Limited (AECL)'s Chalk River Laboratories (CRL) site. Trends in 14 C specific activities were evaluated with distance from the sampling location with the maximum 14 C specific activity (DSS-35), which was situated adjacent to the WMA and close to an area of groundwater discharge. Based on a spatial evaluation of the data, an east-to-west 14 C gradient was found, due to the influence of the WMA on 14 C specific activities in the swamp. In addition, it was possible to identify two groups of sites, each showing significant exponential declines with distance from the groundwater source area. One of the groups showed relatively more elevated 14 C specific activities at a given distance from source, likely due to their proximity to the WMA, the location of the sub-surface plume originating from the WMA, the presence of marsh and swamp habitat types, which facilitated 14 C transport to the atmosphere, and possibly, 14 C air dispersion patterns along the eastern edge of the swamp. The other group, which had lower 14 C specific activities at a given distance from the groundwater source area, included locations that were more distant from the WMA and the sub-surface plume, and contained fen habitat, which is known to act as barrier to groundwater flow. The findings suggest that proximity to source, groundwater flow patterns and habitat physical characteristics can play an important role in the dynamics of 14 C being carried by discharging groundwater into terrestrial and wetland environments. - Highlights: • Groundwater represents an important source of volatile radionuclides to wetlands. • Habitat type influenced 14 C transport from sub-surface to surface environments. • C-14 specific

  3. US team measurements during the June 1987 experimental HT release at the Chalk River Nuclear Laboratories, Ontario, Canada

    International Nuclear Information System (INIS)

    Jalbert, R.A.; Murphy, C.E.

    1988-01-01

    In June 1987, an experiment was performed at the Chalk River Nuclear Laboratories in Ontario, Canada, to study the oxidation of HT in the environment. The experiment involved a 30-minute release of 100 Ci of HT to the atmosphere at an elevation of one meter. The HTOHT ratios were shown to slowly increase downwind (/approximately/4 /times/ 10/sup /minus/5/ at 50 meters to almost 10/sup /minus/3 at 400 meters) as conversion of HT takes place. For several days after the release, HTO concentrations in the atmosphere remained elevated. Freeze-dried water from vegetation samples was found to be very low in HTO immediately after the release suggesting a very low direct uptake of HTO in air by vegetation. The tritiated water concentration increased during the first day, peaking during the second day (about 400 to 600 pCiml of water at 50 meters from the source) and decreasing by the end of the second day. The organically bound tritium continued to accumulate during the period following exposure (about 10 pCigm dry weight at 50 meters after two days). 4 refs., 6 figs., 2 tabs

  4. U.S. team measurements during the June 1987 experimental HT release at the Chalk River Nuclear Laboratories, Ontario, Canada

    International Nuclear Information System (INIS)

    Jalbert, R.A.; Murphy, C.E.

    1988-01-01

    In June 1987, an experiment was performed at the Chalk River Nuclear Laboratories in Ontario, Canada, to study the oxidation of HT in the environment. The experiment involved a 30-minute release of 3.54 TBq (95.7 Ci) of HT to the atmosphere at an elevation of one meter. The HTO/HT ratios were shown to slowly increase downwind (-- 4 x 10/sup -5/ at 50 meters to almost 10/sup -3/ at 400 meters) as conversion of HT takes place. For several days after the release, HTO concentrations in the atmosphere remained elevated. Freeze-dried water from vegetation samples was found to be very low in HTO immediately after the release suggesting a very low direct uptake of HTO in air by vegetation. The free-HTO concentration in vegetation increased during the first day, peaking during the second day (about 1.5 - 3.0 x 10/sup 4/ Bq/L at 50 meters from the source) and decreasing by the end of the second day. The organically bound tritium continued to accumulate during the period following exposure (about 400 Bq/kg dry weight at 50 meters after two days)

  5. Uranium series geochemistry in aquifers: quantification of transport mechanisms of uranium and daughter products: the chalk aquifer (Champagne, France)

    International Nuclear Information System (INIS)

    Hubert, A.

    2005-09-01

    With the increase of contaminant flux of radionuclides in surface environment (soil, river, aquifer...), there is a need to understand and model the processes that control the distribution of uranium and its daughter products during transport within aquifers. We have used U-series disequilibria as an analogue for the transport of uranium and its daughter products in aquifer to understand such mechanisms. The measurements of uranium ( 234 U et 238 U), thorium ( 230 Th et 232 Th), 226 Ra and 222 Rn isotopes in the solid and liquid phases of the chalk aquifer in Champagne (East of France) allows us to understand the processes responsible for fractionation within the uranium decay chain. Fractionations are induced by physical and chemical properties of the elements (leaching, adsorption) but also by radioactive properties (recoil effect during α-decay). For the first time a comprehensive sampling of the solid phase has been performed, allowing quantifying mechanisms responsible for the long term evolution of the aquifer. A non steady state 1D model has been developed which takes into account leaching, adsorption processes as well as radioactive filiation and α-recoil effect. Retardation coefficients have been calculated for uranium, thorium and radium. The aquifer is characterised by a double porosity, and the contribution of fracture and matrix porosity on the water/rock interaction processes has been estimated. (author)

  6. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HUDSON in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 1982-02-28 to 1982-04-04 (NODC Accession 0113889)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113889 includes chemical, discrete sample, physical and profile data collected from HUDSON in the North Atlantic Ocean, North Greenland Sea and...

  7. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2002-05-05 to 2002-06-15 (NODC Accession 0113952)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113952 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and...

  8. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2004-05-15 to 2004-06-23 (NODC Accession 0115592)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115592 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and...

  9. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from the NATHANIEL B. PALMER in the Arctic Ocean, Beaufort Sea and Bering Sea from 2003-07-05 to 2003-08-20 (NODC Accession 0116064)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116064 includes biological, chemical, discrete sample, physical and profile data collected from NATHANIEL B. PALMER in the Arctic Ocean, Beaufort Sea...

  10. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2004-07-18 to 2004-08-26 (NODC Accession 0115707)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115707 includes biological, chemical, discrete sample, optical, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and...

  11. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the Ryofu Maru II in the East China Sea (Tung Hai), North Pacific Ocean and Philippine Sea from 2004-10-21 to 2004-11-09 (NODC Accession 0112286)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112286 includes biological, chemical, discrete sample, physical and profile data collected from Ryofu Maru II in the East China Sea (Tung Hai), North...

  12. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from HEALY in the Arctic Ocean, Beaufort Sea and Bering Sea from 2002-07-18 to 2002-08-21 (NODC Accession 0113953)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113953 includes biological, chemical, discrete sample, physical and profile data collected from HEALY in the Arctic Ocean, Beaufort Sea and Bering...

  13. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the LOUIS S. ST. LAURENT in the Arctic Ocean, Beaufort Sea and North Greenland Sea from 1994-07-24 to 1994-09-01 (NODC Accession 0113983)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113983 includes chemical, discrete sample, physical and profile data collected from LOUIS S. ST. LAURENT in the Arctic Ocean, Beaufort Sea and North...

  14. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 1992-07-12 to 1992-07-28 (NODC Accession 0113558)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113558 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and...

  15. PH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from POLARSTERN in the Arctic Ocean, Kara Sea and Laptev Sea from 1995-07-07 to 1995-09-20 (NODC Accession 0116408)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0116408 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean, Kara Sea and Laptev (or...

  16. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 2001-05-27 to 2001-06-19 (NODC Accession 0113754)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113754 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Atlantic Ocean, North Greenland Sea and...

  17. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the G.O. SARS in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 2003-09-22 to 2003-10-13 (NODC Accession 0113752)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113752 includes chemical, discrete sample, physical and profile data collected from G.O. SARS in the North Atlantic Ocean, North Greenland Sea and...

  18. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JAN MAYEN in the Arctic Ocean, Barents Sea and North Greenland Sea from 2005-05-20 to 2005-06-02 (NODC Accession 0113564)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113564 includes chemical, discrete sample, physical and profile data collected from JAN MAYEN in the Arctic Ocean, Barents Sea and North Greenland...

  19. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the POLARSTERN in the Arctic Ocean, Barents Sea and Laptev (or Nordenskjold) Sea from 2007-07-28 to 2007-10-10 (NODC Accession 0109899)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0109899 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean, Barents Sea and Laptev (or...

  20. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Greenland Sea and Norwegian Sea from 1996-07-20 to 1996-08-05 (NODC Accession 0115688)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115688 includes biological, chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Greenland Sea and Norwegian...

  1. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 1994-10-29 to 1994-11-23 (NODC Accession 0115681)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115681 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and...

  2. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and Norwegian Sea from 1994-07-23 to 1994-08-16 (NODC Accession 0113560)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113560 includes chemical, discrete sample, physical and profile data collected from JOHAN HJORT in the North Atlantic Ocean, North Greenland Sea and...

  3. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from THOMAS G. THOMPSON in the East China Sea, North Pacific Ocean and Philippine Sea from 1985-05-04 to 1985-06-03 (NCEI Accession 0156918)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0156918 includes chemical, discrete sample, physical and profile data collected from THOMAS G. THOMPSON in the East China Sea (Tung Hai), North...

  4. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the RYOFU MARU in the East China Sea (Tung Hai), North Pacific Ocean and Philippine Sea from 1997-06-23 to 1997-07-22 (NODC Accession 0115597)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115597 includes biological, chemical, discrete sample, physical and profile data collected from RYOFU MARU in the East China Sea (Tung Hai), North...

  5. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the AKADEMIK FYODOROV in the East Siberia Sea and Laptev (or Nordenskjold) Sea from 1994-07-05 to 1994-08-08 (NODC Accession 0113884)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113884 includes chemical, discrete sample, physical and profile data collected from AKADEMIK FYODOROV in the East Siberia Sea and Laptev (or...

  6. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the POLARSTERN in the Arctic Ocean, Kara Sea and Laptev (or Nordenskjold) Sea from 1993-08-06 to 1993-10-05 (NODC Accession 0113593)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113593 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean, Kara Sea and Laptev (or...

  7. Independent Subspace Analysis of the Sea Surface Temperature Variability: Non-Gaussian Sources and Sensitivity to Sampling and Dimensionality

    Directory of Open Access Journals (Sweden)

    Carlos A. L. Pires

    2017-01-01

    Full Text Available We propose an expansion of multivariate time-series data into maximally independent source subspaces. The search is made among rotations of prewhitened data which maximize non-Gaussianity of candidate sources. We use a tensorial invariant approximation of the multivariate negentropy in terms of a linear combination of squared coskewness and cokurtosis. By solving a high-order singular value decomposition problem, we extract the axes associated with most non-Gaussianity. Moreover, an estimate of the Gaussian subspace is provided by the trailing singular vectors. The independent subspaces are obtained through the search of “quasi-independent” components within the estimated non-Gaussian subspace, followed by the identification of groups with significant joint negentropies. Sources result essentially from the coherency of extremes of the data components. The method is then applied to the global sea surface temperature anomalies, equatorward of 65°, after being tested with non-Gaussian surrogates consistent with the data anomalies. The main emerging independent components and subspaces, supposedly generated by independent forcing, include different variability modes, namely, The East-Pacific, the Central Pacific, and the Atlantic Niños, the Atlantic Multidecadal Oscillation, along with the subtropical dipoles in the Indian, South Pacific, and South-Atlantic oceans. Benefits and usefulness of independent subspaces are then discussed.

  8. COMPARISON OF THE TRADITIONAL CHALK AND BOARD LECTURE SYSTEM VERSUS POWER POINT PRESENTATION AS A TEACHING TECHNIQUE FOR TEACHING GROSS ANATOMY TO THE FIRST PROFESSIONAL MEDICAL STUDENTS

    OpenAIRE

    Nusrat; Abdul

    2015-01-01

    Traditionally and conventionally, gross anatomy is taught by lectures and cadaveric dissection and the lectures are taken with chalk and board (C&B) or chalk and talk method in, India. But there is always a debate over the most effective method of lecture delivery. AIM : The aim of this study was to compare the role and effecti...

  9. Optimization of sample preparation and chromatography for the determination of perfluoroalkyl acids in sediments from the Yangtze Estuary and East China Sea.

    Science.gov (United States)

    Wang, Qian-Wen; Yang, Gui-Peng; Zhang, Ze-Ming; Zhang, Jing

    2018-08-01

    Perfluoroalkyl acids (PFAAs) are ubiquitous pollutants present in various environmental media, including marine sediments. A method was proposed for the determination of 17 target PFAA analytes in marine sediment samples (n = 49) collected from the Yangtze Estuary and East China Sea. The proposed method involves the use of an optimized pretreatment procedure and ultrahigh-performance liquid chromatography electrospray ionization-tandem mass spectrometry in dynamic multiple reaction monitoring mode. The method relied on extraction cycles using methanol followed by concentration, filtration, and small volume injection to UHPLC-MS/MS. The recovery, time efficiency, and detection limit of the proposed method are improved relative to those of traditional methods. Limits of detection varied from 0.003 to 0.045 ng/g, and spike recoveries to sediment ranged from 90% to 110% with suitable precisions (1.7%-14.6%). PFAAs were widely present in the samples, and ΣPFAAs ranged from 0.67 ng/g dw to 36.75 ng/g dw. Results indicated that terrigenous input strongly influences PFAA distribution in sediments from the study areas. Perfluorooctanoic acid (PFOA) and perfluorooctanesulfonate (PFOS) were identified as the dominant perfluorocarboxylic acid (PFCA) and perfluoroalkylsulfonate (PFSA) in sediment samples from the Yangtze Estuary and the East China Sea. Preliminary environmental risk assessment indicated that PFOS may pose a higher environmental risk than PFOA. Furthermore, risk quotient values indicated that PFOS poses a significant risk to the aquatic ecosystem of the study areas. Copyright © 2018 Elsevier Ltd. All rights reserved.

  10. Enhanced bacterial affinity of PVDF membrane: its application as improved sea water sampling tool for environmental monitoring.

    Science.gov (United States)

    Kumar, Sweta Binod; Sharnagat, Preeti; Manna, Paramita; Bhattacharya, Amit; Haldar, Soumya

    2017-02-01

    Isolation of diversified bacteria from seawater is a major challenge in the field of environmental microbiology. In the present study, an attempt has been made to select specific membrane with improved property of attaching diversified bacteria. Initially, different concentrations (15, 18, and 20% W/W) of polysulfone (PSF) were used to check their affinity for the attachment of selected gram-positive (Bacillus subtilis) and gram-negative (Escherichia coli) bacteria. Among these, 20% W/W PSF showed maximum attachment. Therefore, membrane prepared with other materials such as polyvinylidene fluoride (PVDF) and polyether sulfone (PES) were used with the same concentration (20% W/W) to check their improved bacterial attachment property. Comparative study of bacterial attachment on three different membranes revealed that PVDF possessed the highest affinity towards both the groups of bacteria. This property was confirmed by different analytical methods viz. contact angle, atomic force microscopy, zeta potential, and flux study and further validated with seawater samples collected from seven sites of western coast and Lakshadweep island of India, using Biolog EcoPlate™. All the samples showed that bacterial richness and diversity was high in PVDF membrane in comparison to surrounding seawater samples. Interestingly, affinity for more diversified bacteria was reported to be higher in water sample with less turbidity and low bacteria load. This finding can facilitate the development of PVDF (20% W/W) membrane as a simple, cheap, and less labor intensive environmental sampling tool for the isolation of diversified bacteria from seawater sample wih different physiochemical properties. Graphical abstract ᅟ.

  11. High resolution microgravity investigations for the detection and characterisation of subsidence associated with abandoned, coal, chalk and salt mines

    Energy Technology Data Exchange (ETDEWEB)

    Styles, P.; Toon, S.; Branston, M.; England, R. [Keele Univ., Applied And Environmental Geophysics Group, School of Physical and Geographical Sciences (United Kingdom); Thomas, E.; Mcgrath, R. [Geotechnology, Neath (United Kingdom)

    2005-07-01

    The closure and decay of industrial activity involving mining has scarred the landscape of urban areas and geo-hazards posed by subsurface cavities are ubiquitous throughout Europe. Features of concern consist of natural solution cavities (e.g. swallow holes and sinkholes in limestone gypsum and chalk) and man-made cavities (mine workings, shafts) in a great variety of post mining environments, including coal, salt, gypsum, anhydrite, tin and chalk. These problems restrict land utilisation, hinder regeneration, pose a threat to life, seriously damage property and services and blight property values. This paper outlines the application of microgravity techniques to characterise abandoned mining hazard in case studies from Coal, Chalk and Salt Mining environments in the UK. (authors)

  12. High resolution microgravity investigations for the detection and characterisation of subsidence associated with abandoned, coal, chalk and salt mines

    International Nuclear Information System (INIS)

    Styles, P.; Toon, S.; Branston, M.; England, R.; Thomas, E.; Mcgrath, R.

    2005-01-01

    The closure and decay of industrial activity involving mining has scarred the landscape of urban areas and geo-hazards posed by subsurface cavities are ubiquitous throughout Europe. Features of concern consist of natural solution cavities (e.g. swallow holes and sinkholes in limestone gypsum and chalk) and man-made cavities (mine workings, shafts) in a great variety of post mining environments, including coal, salt, gypsum, anhydrite, tin and chalk. These problems restrict land utilisation, hinder regeneration, pose a threat to life, seriously damage property and services and blight property values. This paper outlines the application of microgravity techniques to characterise abandoned mining hazard in case studies from Coal, Chalk and Salt Mining environments in the UK. (authors)

  13. Understanding Fluid Flow during Tectonic Reactivation: An Example from the Flamborough Head Chalk Outcrop (UK

    Directory of Open Access Journals (Sweden)

    O. Faÿ-Gomord

    2018-01-01

    Full Text Available Flamborough Head chalks are located at the extremities of E-W and N-S trending fault systems along the Yorkshire coast (UK. Rock deformation is expressed in Selwicks Bay where a normal fault is exposed along with a high density of calcite veins. The fault mineralization is tested using geochemistry. Crosscutting relationships are used to differentiate between three vein generations: a network of parallel veins that are oriented perpendicular to stratigraphy (Group I, hydraulic breccia with typical jigsaw puzzle structure (Group II, and a third generation of calcite veins crosscutting the two previous generations (Group III. Geochemical analyses revealed that all three generations possess the same chemical signature and must reflect successive pulses from the same mineralizing fluid source. Strontium isotope analyses showed that the veins have elevated 87Sr/86Sr ratios, that is, up to 7.110, while ratios of the chalk matrix equal 7.707. The latter value is in agreement with the signature of Late Cretaceous seawater. Consequently, the source of the fluid is external, reflecting an open system. The radiogenic Sr-isotope ratios, combined with low iron concentration, suggest that fluids migrated through sandy deposits. Fluid inclusion salinities range from 0 to 12 eq. wt% NaCl equiv. with a dominance of very low salinity inclusions, reflecting a meteoric signal. This leads to a model where meteoric fluids stored in an underlying confined sandstone aquifer were remobilized. The wide range of salinities could result from mixing of the meteoric fluid with some more saline fluids present in the rock sequence or from the dissolution of salts in the subsurface. In addition to the understanding of the local paragenetic evolution of the veining in Flamborough Head chalks, this study offers an insight into the way how fluid flows and mineralizes along fault zones.

  14. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from KNORR in the Davis Strait, Labrador Sea and others from 1981-04-01 to 1981-10-19 (NODC Accession 0000733)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0000733 includes discrete sample and profile data collected from KNORR in the Davis Strait, Labrador Sea, North Atlantic Ocean, North Greenland Sea...

  15. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Arctic Ocean, Beaufort Sea and others from 2002-08-22 to 2002-10-10 (NODC Accession 0112355)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112355 includes biological, chemical, discrete sample, physical and profile data collected from MIRAI in the Arctic Ocean, Beaufort Sea, Bering Sea...

  16. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the MELVILLE in the Arabian Sea, Bay of Bengal and others from 1972-07-18 to 1978-04-28 (NODC Accession 0117677)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0117677 includes chemical, discrete sample, physical and profile data collected from MELVILLE in the Arabian Sea, Bay of Bengal, Bering Sea, Gulf of...

  17. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from KNORR in the North Atlantic Ocean, North Greenland Sea and others from 1972-07-18 to 1973-04-01 (NCEI Accession 0143398)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143398 includes discrete sample and profile data collected from KNORR in the North Atlantic Ocean, North Greenland Sea, Norwegian Sea, South Atlantic...

  18. Tracking selenium in the Chalk aquifer of northern France: Sr isotope constraints

    International Nuclear Information System (INIS)

    Cary, L.; Benabderraziq, H.; Elkhattabi, J.; Gourcy, L.; Parmentier, M.; Picot, J.; Khaska, M.; Laurent, A.; Négrel, Ph.

    2014-01-01

    Highlights: • We report the chemistry of the Chalk groundwater affected by Se contamination. • Strontium isotopes were used to identify the groundwater bodies and their mixings. • The spatial and temporal Se variability is mainly linked to the presence of Se-rich clays. • Saturation or desaturation of Se-rich clays control Se mobility. - Abstract: Groundwater at the southern and eastern edges of France’s Paris Basin has a selenium content that at times exceeds the European Framework Directive’s drinking-water limit value of 10 μg/L. To better understand the dynamics of the Chalk groundwater being tapped to supply the city of Lille and the Se origins, we used a combination of geochemical and isotopic tools. Strontium isotopes, coupled with Ca/Sr, Mg/Sr and Se/Sr ratios, were used to identify the main groundwater bodies and their mixings, with the Mg/Sr and Se/Sr ratios constraining a ternary system. Groundwater in the agricultural aquifer-recharge zone represents a first end-member and displays the youngest water ages of the catchment along with the highest Sr isotopic signature (0.70842) and low Se contents. Anaerobic groundwater constitutes a second major end-member affected by water-rock interactions over a long residence time, with the lowest Sr isotopic signature (0.70789) and the lowest Se content, its low SF6 content confirming the contribution of old water. Se-rich groundwater containing up to 30 μg/L of Se represents a third major end-member, with an intermediate Sr isotopic ratio (0.70826), and is mainly constrained by the clayey Se-rich formation overlying the Chalk aquifer. The spatial and temporal Se variability in the groundwater is clearly linked to the presence of this formation identified as Tertiary and also to the hydrological conditions; saturation of the Se-rich clays by oxygenated groundwater enhances Se mobility and also Sr adsorption onto the clays. This multi-tool study including Sr isotopes successfully identified the Se

  19. Electroosmotic dewatering of chalk sludge, iron hydroxide sludge, wet fly ash and biomass sludge

    DEFF Research Database (Denmark)

    Hansen, H.K.; Christensen, Iben Vernegren; Ottosen, Lisbeth M.

    2003-01-01

    . Casagrande's coefficients were determined for the four materials at different water contents. The experiments in this work showed that chalk could be dewatered from 40% to 79% DM (dry matter), fly ash from 75 to 82% DM, iron hydroxide sludge from 2.7 to 19% DM and biomass from 3 to 33% DM by electroosmosis....... The process was not optimised indicating that higher dry matter contents could be achieved by electroosmosis. It was possible to relate Casagrande's coefficient directly to the electroosmotic coefficient obtained by dewatering experiments....

  20. Field burial results and SIMS analysis of the Chalk River glass blocks

    International Nuclear Information System (INIS)

    Tait, J.C.; Hocking, W.H.; Betteridge, J.S.; Bart, G.

    1986-01-01

    In 1959, 25 2-kg hemispherical blocks of aluminosilicate glass, each containing ∼90 MBq/g of mixed fission products, were buried in a sandy soil aquifer in the waste management area at the Chalk River Nuclear Laboratories. A second set of blocks, containing ∼260 MBq/g mixed fission products, was buried in 1960. One block from each test was retrieved in 1978 to undergo chemical and surface analysis. This report reviews the migration of the 90 Sr and 137 Cs plume in the soil and presents the results of SIMS depth profiling of the surface of a glass block. (author)

  1. An overview of the waste characterization program at Chalk River Nuclear Laboratories

    International Nuclear Information System (INIS)

    Csullog, G.W.; Hardy, D.G.

    1990-05-01

    A comprehensive Waste Characterization Program (WCP) is in place at Chalk River Laboratories to support disposal projects. The WCP is responsible for: 1) specifying the manifests for waste shipments; 2) developing and maintaining central databases for waste inventories and analytical data; and 3) developing the technologies and procedures to characterize the radiological and the physical/chemical properties of wastes. WCP work is being performed under the umbrella of a newly developed waste management Quality Assurance (QA) program. This paper gives an overview of the WCP with an emphasis on the requirements for determining radionuclide inventories in wastes, for implementing record-keeping systems, and for maintaining a QA program for disposal operations

  2. Uranium-phosphate relationship in phosphated chalks of the Mons and Picardie Bassins

    Energy Technology Data Exchange (ETDEWEB)

    Quinif, Y; Charlet, J M; Dupuis, C; Robaszynski, F [Faculte Polytechnique de Mons (Belgium)

    1981-11-30

    The lithological and geochemical conditions relative to the ''Senonian'' phosphatic chalks are relatively simple in the Basins of Mons (Belgium) and of Picardy (France). Their characteristics permit us to study chiefly the uranium-phosphate relation. It appears a very good linear correlation between the phosphate and the uranium. The coefficient U/P/sub 2/O/sub 5/ remains a constant from the bottom to the top of the same section, but changes in space for synchronic formations (lateral variation of geochemical facies) and in time for two separated basins.

  3. Upper Cretaceous chalk facies and depositional history recorded in the Mona-1 core, Mona Ridge

    DEFF Research Database (Denmark)

    Anderskouv, Kresten; Surlyk, Finn

    2011-01-01

    , including mudflow, debris flow, and slumping. Pelagic deposits vary mainly in terms of the concentration of siliciclastic material, the trace-fossil assemblage, and the presence or ab­sence of primary sedimentary structures. Pelagic sedimentation was probably punctuated by the deposition of thin turbidites...... slump packages (14–18 in total) are interpreted, forming over 40% of the succession; debrites appear to be the most common precursor facies involved in slumping. The vertical succession of facies records an earliest Cenomanian facies shift from dominantly siliciclastic to chalk deposition...

  4. A method for the measurement of 99Tc by quadrupole ICP-MS in dry fallout and sea grass samples

    International Nuclear Information System (INIS)

    Mas, Jose Luis; Bolivar, Juan Pedro; Garcia-Leon, Manuel

    2003-01-01

    A method for the detection of 99 Tc by ICP-MS in environmental samples is proposed and explained in detail. This method combines the capabilities of anion exchange chromatographic TEVA·Spec TM resin with prior isotope concentration using solvent extraction to Tributylphosphate. The problem that the excess of Mo in the solution analyzed by ICP-MS causes in the instrumental response at m/z ratio 99 is described in detail, and the proposed solution takes the form of the referred radiochemical method. The realistic limits of detection of this technique (bearing in mind the particular methodology here applied) are in the range of 20-70 mBq/kg when treating mass amounts in the range of 20-125 g dry weight. A few environmental samples proceeding from a region unaffected by any closer nuclear industry (the Southwest of Spain) are analyzed for checking 99 Tc concentration. (author)

  5. Mechanical and chemical processes affecting the chalk during burial, insights from combined reflection seismics, well data and field work

    DEFF Research Database (Denmark)

    Moreau, Julien; Boussaha, Myriam; Thibault, Nicolas Rudolph

    2014-01-01

    and cores analyses, respectively.However, few sites allow to combine all the different scale of observation for chalk diagenesis. Onshore and offshore high resolution seismics, two fully cored >350 m wells with wireline logging tools and very high quality exposures from a coastal cliff and a quarry form...... works have been performed with astronomical calibration based on stable isotope stratigraphy, wireline logs as well as several palaeontological proxies and detailed sedimentological analysis. Since a couple of decades, a specific kind of fractures has been described in the Chalk of Denmark, the so...

  6. Environmental isotope studies related to groundwater flow and saline encroachment in the chalk aquifer of Lincolnshire, England

    International Nuclear Information System (INIS)

    Lloyd, J.W.; Howard, K.W.F.

    1978-01-01

    The isotopes of tritium and carbon are used to study part of the North Lincolnshire Chalk aquifer in England. The tritium data support the view that the aquifer is a thin fissure system and indicate that some changes in flow direction have occurred due to recent abstraction. The data are also consistent with other chemical data in elucidating groundwater entering the Chalk from deeper aquifers. Carbon isotopes are used to distinguish between saline water bodies and suggest that saline water was entrapped within the aquifer in the Eemian and Flandrian stages of the Pleistocene. (orig.) [de

  7. A high-pressure thermal gradient block for investigating microbial activity in multiple deep-sea samples

    DEFF Research Database (Denmark)

    Kallmeyer, J.; Ferdelman, TG; Jansen, KH

    2003-01-01

    Details about the construction and use of a high-pressure thermal gradient block for the simultaneous incubation of multiple samples are presented. Most parts used are moderately priced off-the-shelf components that easily obtainable. In order to keep the pressure independent of thermal expansion....... Sulfate reduction rates increase with increasing pressure and show maximum values at pressures higher than in situ. (C) 2003 Elsevier Science B.V. All rights reserved....

  8. A high-pressure thermal gradient block for investigating microbial activity in multiple deep-sea samples

    DEFF Research Database (Denmark)

    Kallmeyer, J.; Ferdelman, TG; Jansen, KH

    2003-01-01

    Details about the construction and use of a high-pressure thermal gradient block for the simultaneous incubation of multiple samples are presented. Most parts used are moderately priced off-the-shelf components that easily obtainable. In order to keep the pressure independent of thermal expansion...... range of temperatures and pressures and can easily be modified to accommodate different experiments, either biological or chemical. As an application, we present measurements of bacterial sulfate reduction rates in hydrothermal sediments from Guyamas Basin over a wide range of temperatures and pressures...

  9. Proceedings of a workshop on geophysical and related geoscientific research at Chalk River, Ontario

    International Nuclear Information System (INIS)

    Thomas, M.D.; Dixon, D.F.

    1989-10-01

    A large part of the Canadian Nuclear Fuel Waste Management Program is geoscience research and development aimed at obtaining information to quantify the transport of radionuclides through the geosphere and at determining the geotechnical properties required for disposal vault design. The geosphere at potential disposal sites is characterized in part by the use of remote sensing (geophysical) methods. In 1977 public concern about the disposal of radioactive waste resulted in field work being restricted to the site of Chalk River Nuclear Laboratories, which was used to develop, evaluate and compare various techniques in order to optimize the methods for obtaining geoscience information. Methods tested at Chalk River are to be applied at other research sites. Most investigations have been carried out around Maskinonge Lake, using about thirty boreholes sink into bedrock. The boreholes provide subsurface geological information that can be used as a reference to compare the responses of various geophysical methods and equipment. Regional studies, including airborne geophysical surveys, have also been conducted. The 25 papers presented at this workshop provide comprehensive documentation of the most significant results of geophysical studies. The workshop also provided an evaluation of geophysical techniques and their utility to the Nuclear Fuel Waste Management Program

  10. How burial diagenesis of chalk sediments controls sonic velocity and porosity

    DEFF Research Database (Denmark)

    Fabricius, Ida Lykke

    2003-01-01

    Based on P-wave velocity and density data, a new elastic model for chalk sediments is established. The model allows the construction of a series of isoframe (IF) curves, each representing a constant part of the mineral phase contributing to the solid frame. The IF curves can be related to the pro......Based on P-wave velocity and density data, a new elastic model for chalk sediments is established. The model allows the construction of a series of isoframe (IF) curves, each representing a constant part of the mineral phase contributing to the solid frame. The IF curves can be related.......1 or higher. Upon burial, the sediments lose porosity by mechanical compaction, and concurrently, the calcite particles recrystallize into progressively more equant shapes. High compaction rates may keep the particles in relative motion, whereas low compaction rates allow the formation of contact cement...... this process testifies to the absence of chemical compaction by calcite-calcite pressure dissolution, as well as to the porosity-preserving effect of contact cementation. At sufficient burial stress, the presence of stylolites indicates that pressure dissolution takes place between calcite., and silicates...

  11. The Congolobe project, a multidisciplinary study of Congo deep-sea fan lobe complex: Overview of methods, strategies, observations and sampling

    Science.gov (United States)

    Rabouille, C.; Olu, K.; Baudin, F.; Khripounoff, A.; Dennielou, B.; Arnaud-Haond, S.; Babonneau, N.; Bayle, C.; Beckler, J.; Bessette, S.; Bombled, B.; Bourgeois, S.; Brandily, C.; Caprais, J. C.; Cathalot, C.; Charlier, K.; Corvaisier, R.; Croguennec, C.; Cruaud, P.; Decker, C.; Droz, L.; Gayet, N.; Godfroy, A.; Hourdez, S.; Le Bruchec, J.; Saout, J.; Le Saout, M.; Lesongeur, F.; Martinez, P.; Mejanelle, L.; Michalopoulos, P.; Mouchel, O.; Noel, P.; Pastor, L.; Picot, M.; Pignet, P.; Pozzato, L.; Pruski, A. M.; Rabiller, M.; Raimonet, M.; Ragueneau, O.; Reyss, J. L.; Rodier, P.; Ruesch, B.; Ruffine, L.; Savignac, F.; Senyarich, C.; Schnyder, J.; Sen, A.; Stetten, E.; Sun, Ming Yi; Taillefert, M.; Teixeira, S.; Tisnerat-Laborde, N.; Toffin, L.; Tourolle, J.; Toussaint, F.; Vétion, G.; Jouanneau, J. M.; Bez, M.; Congolobe Group:

    2017-08-01

    The presently active region of the Congo deep-sea fan (around 330,000 km2), called the terminal lobes or lobe complex, covers an area of 2500 km2 at 4700-5100 m water depth and 750-800 km offshore. It is a unique sedimentary area in the world ocean fed by a submarine canyon and a channel-levee system which presently deliver large amounts of organic carbon originating from the Congo River by turbidity currents. This particularity is due to the deep incision of the shelf by the Congo canyon, up to 30 km into the estuary, which funnels the Congo River sediments into the deep-sea. The connection between the river and the canyon is unique for major world rivers. In 2011, two cruises (WACS leg 2 and Congolobe) were conducted to simultaneously investigate the geology, organic and inorganic geochemistry, and micro- and macro-biology of the terminal lobes of the Congo deep-sea fan. Using this multidisciplinary approach, the morpho-sedimentary features of the lobes were characterized along with the origin and reactivity of organic matter, the recycling and burial of biogenic compounds, the diversity and function of bacterial and archaeal communities within the sediment, and the biodiversity and functioning of the faunal assemblages on the seafloor. Six different sites were selected for this study: Four distributed along the active channel from the lobe complex entrance to the outer rim of the sediment deposition zone, and two positioned cross-axis and at increasing distance from the active channel, thus providing a gradient in turbidite particle delivery and sediment age. This paper aims to provide the general context of this multidisciplinary study. It describes the general features of the site and the overall sampling strategy and provides the initial habitat observations to guide the other in-depth investigations presented in this special issue. Detailed bathymetry of each sampling site using 0.1-1 m resolution multibeam obtained with a remotely operated vehicle (ROV

  12. Diffusive parameters of tritiated water (HTO) and U in chalk

    International Nuclear Information System (INIS)

    Descostes, M.; Gandois, O.; Frasca, B.; Radwan, J.; Juery, A.; Descostes, M.; Pili, E.

    2009-01-01

    Complete text of publication follows: The feasibility of aquifer storage and recovery systems (ASR) to counteract short and long term imbalances between freshwater supply and demand is currently investigated for the metropolitan area of Perth, Western Australia. During the planned injection of oxic excess water into a deep anoxic aquifer the water quality evolution will depend on the extent and structure of the physical and geochemical heterogeneity and reactivity of the aquifer. A detailed geochemical characterisation was undertaken to determine amount and type of sedimentary reductants within different lithological facies. The incubation of sediment samples from the target aquifer for ∼ 52 days enabled quantification of their oxygen (O 2 ) consumption and CO 2 production [1]. Data analysis, in particular the identification of key redox and acid buffering processes, was under-pinned by hydrogeochemical modelling. Results showed that the average measured reductive capacities (MRC) towards O 2 consumption increased from the sand facies, followed by the siltstone facies, and the mud-stone/shale facies. This approach identified pyrite (20 - 100%), sedimentary organic matter (SOM; 3 - 56%), siderite (3 - 28%) and Fe(II)- aluminosilicates (8 - 55%) as the main O 2 reductants. Minute amounts of carbonate acted as buffering minerals, while a bounding pH of 3 indicated acid buffering by K-feldspar dissolution. The supernatants showed elevated aqueous concentrations of Ni, Cd and Pb to be a potential risk for the quality of the recovered water. [1] Hartog, Griffioen and Van der Weijden (2002) Environmental Science and Technology 36(11), 2338-2344

  13. Life-history strategies as a tool to identify conservation constraints: A case-study on ants in chalk grasslands

    NARCIS (Netherlands)

    Noordwijk, C.G.E.; Boer, P.; Mabelis, A.A.; Verberk, W.C.E.P.; Siepel, H.

    2012-01-01

    Species’ life-history traits underlie species–environment relationships. Therefore, analysis of species traits, combined into life-history strategies, can be used to identify key factors shaping the local species composition. This is demonstrated in a case-study on ants in chalk grasslands. We

  14. Deep saltwater in Chalk of North-West Europe: origin, interface characteristics and development over geological time

    DEFF Research Database (Denmark)

    Bonnesen, Ellen Prip; Larsen, F.; Sonnenborg, T.O.

    2009-01-01

    High-concentration saltwaters occur in many places in the regional Chalk aquifers of North-West Europe; to investigate deep occurrences, profiles of interstitial porewater chemistry have been studied from three 250-450m deep cores drilled in the eastern parts of Zealand, Denmark. At the studied...

  15. Programme of research into the management and storage of radioactive waste. Single fracture experiment at Chalk River

    International Nuclear Information System (INIS)

    Bourke, P.J.

    1984-01-01

    A field experiment was carried out at Chalk river to measure the transport of bromine and strontium through a fracture in granite. Retardation of strontium transport by sorption onto the rock was also measured. Data was obtained for bromine but no useful data was obtained for strontium due to failure of the hydraulic equipment. (U.K.)

  16. Estimation of groundwater recharge to chalk and sandstone aquifers using simple soil models

    Science.gov (United States)

    Ragab, R.; Finch, J.; Harding, R.

    1997-03-01

    On the assumption that the water draining below the root zone is potentially available for groundwater recharge, two current UK methods for estimating annual groundwater recharge have been compared with a new soil model using data from four sites under permanent grass in the UK: two sites representative of the Chalk aquifer at Bridgest Farm (Hampshire) and Fleam Dyke (Cambridgeshire), and two sites on the Triassic sandstone at Bicton College (Devon) and Bacon Hall (Shropshire). A Four Root Layers Model (FRLM), the Penman-Grindley model and the UK Meteorological Office Rainfall and Evaporation Calculation System (MORECS) were used. The new soil model was run with potential evaporation as input both from the MORECS and from the Penman-Monteith equation. The models were run for the Chalk sites both with and without a bypass flow of 15% of rainfall. Bypass was not considered for the sandstone sites. The performance of the models was tested against neutron probes measurements of soil moisture deficits. In addition, the annual groundwater recharge estimated from the models was compared with the published values obtained from the 'zero flux plane' method. Generally, the Penman-Grindley model was more successful in predicting the time for soil to return to its field capacity than in predicting the magnitude of the soil moisture deficit. The annual groundwater recharge was predicted with reasonable accuracy. The MORECS relatively tended to overestimate the soil moisture deficits and to delay the time at which the soil returns to its field capacity. The consequences were underestimates of annual groundwater recharge, owing either to the higher values of potential evaporation calculated from the MORECS or tothe high available water capacity values associated with the soils under consideration. The new soil model (FRLM) predicts the soil moisture deficits successfully and hence is reliable in estimating the annual groundwater recharge. The model is capable of doing this with

  17. Genotypic Characterization of Streptococcus infantarius subsp. coli Isolates from Sea Otters with Infective Endocarditis and/or Septicemia and from Environmental Mussel Samples

    Science.gov (United States)

    Counihan-Edgar, Katrina L.; Gill, Verena A.; Doroff, Angela M.; Burek, Kathleen A.; Miller, Woutrina A.; Shewmaker, Patricia L.; Jang, Spencer; Goertz, Caroline E. C.; Tuomi, Pamela A.; Miller, Melissa A.; Jessup, David A.

    2012-01-01

    Pulsed-field gel electrophoresis (PFGE) was used to type 128 Streptococcus infantarius subsp. coli isolates from sea otters and mussels. Six SmaI PFGE groups were detected, with one predominant group representing 57% of the isolates collected over a wide geographic region. Several sea otter and mussel isolates were highly related, suggesting that an environmental infection source is possible. PMID:23052307

  18. Isolation, partial purification, biochemical characterization and detergent compatibility of alkaline protease produced by Bacillus subtilis, Alcaligenes faecalis and Pseudomonas aeruginosa obtained from sea water samples

    Directory of Open Access Journals (Sweden)

    Sarika Kedar Marathe

    2018-06-01

    Full Text Available In the current study, bacteria isolated from sea water samples of Murdeshwar, Karnataka, were screened for the production of alkaline protease by culturing them onto skim milk agar media. Of the isolated bacteria, Bacillus subtilis, Pseudomonas aeruginosa and Alcaligenes faecalis showed distinct zones of hydrolysis due to enzyme production. They were each inoculated into enzyme production media under submerged fermentation conditions at 37 °C for 48 h with a constant agitation of 120 rpm. Partial purification of alkaline protease was carried out by isoelectric precipitation. Enzyme activity was determined under varying conditions of pH, incubation temperature, different substrates, carbon and nitrogen sources and salt concentrations using sigma’s universal protease activity assay. Enzyme immobilization was carried out using 2% Sodium alginate and 0.1 M ice cold CaCl2 and its activity under varying pH, temperature conditions and detergent compatibility was assayed. Efficacy of enzyme in stain removal was tested and haemolysis was observed within of 60 s which resulted in removal of the stain. Among the three organisms, enzyme from Bacillus subtilis showed highest activity in all cases indicating that it was the most ideal organism for enzyme production. Keywords: Alkaline protease, Skim milk agar, Bacillus, Alcaligenes, Pseudomonas, Isoelectric precipitation, Protease activity, Enzyme immobilization, Detergent compatibility

  19. Potential Physiologies of Deep Branches on the Tree of Life with Deep Subsurface Samples from IODP Leg 347: Baltic Sea Paleoenvironment

    Science.gov (United States)

    Lloyd, K. G.; Bird, J. T.; Shumaker, A.

    2014-12-01

    Very little is known about how evolutionary branches that are distantly related to cultured microorganisms make a living in the deep subsurface marine environment. Here, sediments are cut-off from surface inputs of organic substrates for tens of thousands of years; yet somehow support a diverse population of microorganisms. We examined the potential metabolic and ecological roles of uncultured archaea and bacteria in IODP Leg 347: Baltic Sea Paleoenvironment samples, using quantitative PCR holes 60B, 63E, 65C, and 59C and single cell genomic analysis for hole 60B. We quantified changes in total archaea and bacteria, as well as deeply-branching archaeal taxa with depth. These sediment cores alternate between high and low salinities, following a glacial cycle. This allows changes in the quantities of these groups to be placed in the context of potentially vastly different organic matter sources. In addition, single cells were isolated, and their genomes were amplified and sequenced to allow a deeper look into potential physiologies of uncultured deeply-branching organisms found up to 86 meters deep in marine sediments. Together, these data provide deeper insight into the relationship between microorganisms and their organic matter substrates in this extreme environments.

  20. Change in Biot's effective stress coefficient of chalk during pore collapse

    DEFF Research Database (Denmark)

    Alam, M. Monzurul; Fabricius, Ida Lykke

    2013-01-01

    the grains could also change during elastic deformation of the grains in a rock mechanics test. Diagenetic change in grain contact cement of chalk can be compared with stress-induced change in the laboratory. The change in porosity is studied with reference to the change in effective stress on grain contacts...... and porosity reduces at a slower rate. We noticed that presence of non carbonates and hydrocarbon could increase σ'm. During rock mechanics test in the lab, with increased applied stress, σ'm increases, Biot's effective stress coefficient shows a decreasing trend, while a minor porosity reduction was observed......Biot's effective stress coefficient (α) is a measure of how well grains in the rocks are connected with each other. The amount of contact cements between the grains determines the stiffness of rocks. Change in grain contact occurs during natural diagenesis of sedimentary rock. Contact between...

  1. Causes of death among long-term employees of Chalk River Laboratories, 1966-1989

    International Nuclear Information System (INIS)

    Werner, M.M.; Myers, D.K.

    1990-11-01

    Data on mortality among long-term employees of Chalk River Laboratories to 1989 December 31 are reported. The 1988 Hare report, entitled The Safety of Ontario's Nuclear Power Reactors, noted that there had been a steady rise in standardized mortality ratios (SMR) for cancer among these employees in the last three successive five-year periods from 1971-75 to 1981-85. None of the SMRs was significantly different from unity; however, the apparent trend could be indicative of the development of latent cancers. The present report was prepared to see if that increasing trend in cancer SMRs continued. In the years 1986-89, the SMR for cancer among long-term male employees was exceptionally low. The wide fluctuations seen in our data over time are likely anomalies arising from the small size of the study group rather than problems arising from radiation exposures on site

  2. Magnetic field related mechanical tolerances for the proposed Chalk River superconducting heavy-ion cyclotron

    International Nuclear Information System (INIS)

    Heighway, E.A.; Chaplin, K.R.

    1977-11-01

    A four sector azimuthally varying field cyclotron with superconducting main coils has been proposed as a heavy-ion post-accelerator for the Chalk River MP Tandem van de Graaff. The radial profile of the average axial field will be variable using movable steel trim rods. The field errors due to coil, trim rod and flutter pole imperfections are calculated. Those considered are errors in the axial field, first and second azimuthal harmonic axial fields, transverse field and first azimuthal harmonic transverse field. Such fields induce phase slip, axial or radial coherent oscillations and can result in axial or radial beam instability. The allowed imperfections (tolerances) required to retain stability and maintain acceptably small coherent oscillation amplitudes are calculated. (author)

  3. Combining Chalk Talk with PowerPoint to Increase In-class Student Engagement

    Directory of Open Access Journals (Sweden)

    Swati Betharia

    2016-11-01

    Full Text Available In striving to attain a higher degree of in-class student engagement, and target a larger number of preferred student-learning styles, this case study describes a multimodal teaching approach. PowerPoint slides have gradually gained popularity over the more traditional chalk and talk lecture design. The student population in today’s age seeks more non-passive modes of information delivery. Numerous novel approaches to enhance active learning, such as flipped classroom and problem-based learning, have recently been explored. While working well for therapeutic and lab-based courses, these formats may not be best-suited for all basic science topics. The importance of basic science in a pharmacy curriculum is well emphasized in the 2016 ACPE Standards. To actively involve students in a pharmacology lecture on diuretics, a session was designed to combine the PowerPoint and chalk talk approaches. Students created 10 concept diagrams following an instructor, who explained each step in the process using a document camera. For visual learners, these diagrams provided a layered representation of the information, gradually increasing in complexity. For learners with a preference for the reading learning style, the information was also available in corresponding PowerPoint slides. Scores from pre- and post-session quizzes indicated a high level of concept understanding and recall (median 1 [IQR 0 – 2] vs 4 [IQR 3 – 5]; p<0.001. The student perception survey data reported higher in-class attention levels (76%, an appreciation for the utility of self-created concept diagrams (88%, and a call for additional sessions being presented in this format (73%. Targeting a variety of student learning styles by using the active development of concept diagrams, in addition to traditional PowerPoint slides, can promote student engagement and enhance content understanding.   Type: Case Study

  4. Total- and monomethyl-mercury and major ions in coastal California fog water: Results from two years of sampling on land and at sea

    Directory of Open Access Journals (Sweden)

    Peter Weiss-Penzias

    2016-04-01

    Full Text Available Abstract Marine fog water samples were collected over two summers (2014–2015 with active strand collectors (CASCC at eight coastal sites from Humboldt to Monterey counties in California, USA, and on four ocean cruises along the California coastline in order to investigate mercury (Hg cycling at the ocean-atmosphere-land interface. The mean concentration of monomethylmercury (MMHg in fog water across terrestrial sites for both years was 1.6 ± 1.9 ng L-1 (<0.01–10.4 ng L-1, N = 149, which corresponds to 5.7% (2.0–10.8% of total Hg (HgT in fog. Rain water samples from three sites had mean MMHg concentrations of 0.20 ± 0.12 ng L-1 (N = 5 corresponding to 1.4% of HgT. Fog water samples collected at sea had MMHg concentrations of 0.08 ± 0.15 ng L-1 (N = 14 corresponding to 0.4% of HgT. Significantly higher MMHg concentrations in fog were observed at terrestrial sites next to the ocean relative to a site 40 kilometers inland, and the mean difference was 1.6 ng L-1. Using a rate constant for photo-demethylation of MMHg of -0.022 h-1 based on previous demethylation experiments and a coastal-inland fog transport time of 12 hours, a mean difference of only 0.5 ng L-1 of MMHg was predicted between coastal and inland sites, indicating other unknown source and/or sink pathways are important for MMHg in fog. Fog water deposition to a standard passive 1.00 m2 fog collector at six terrestrial sites averaged 0.10 ± 0.07 L m-2 d-1, which was ∼2% of typical rainwater deposition in this area. Mean air-surface fog water fluxes of MMHg and HgT were then calculated to be 34 ± 40 ng m-2 y-1 and 546 ± 581 ng m-2 y-1, respectively. These correspond to 33% and 13% of the rain fluxes, respectively.

  5. Late Quaternary paleoceanographic features as deduced from calcium carbonate and faunal changes of planktonic foraminifers in core samples from northeastern Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, K.K.; Jayalakshmy, K.V.; Singh, A.D.

    carbonate and planktonic foraminifers, with implications on paleoceanography of the Arabian Sea during late Quaternary. Paleoclimatic curve based on per cent variations of carbonate is substantiated by the faunal characteristics. Low value of cold...

  6. A review of analytical techniques for the determination of carbon-14 in environmental samples

    International Nuclear Information System (INIS)

    Milton, G.M.; Brown, R.M.

    1993-11-01

    This report contains a brief summary of analytical techniques commonly used for the determination of radiocarbon in a variety of environmental samples. Details of the applicable procedures developed and tested in the Environmental Research Branch at Chalk River Laboratories are appended

  7. Derived release limits (DRL's) for airborne and liquid effluents from the Chalk River Nuclear Laboratories during normal operations

    International Nuclear Information System (INIS)

    Palmer, J.F.

    1981-02-01

    Derived release limits (DRL's), based on regulatory dose limits, have been calculated for routine discharges of radioactivity in airborne and liquid effluents from the Chalk River Nuclear Laboratories. Three types of sources of airborne effluents were considered: the NRX/NRU stack, the 61 m stack connected to the 99 Mo production facility, and a roof vent typical of those installed on several buildings on the site. Sources of liquid effluents to the Ottawa River were treated as a single source from the site as a whole. Various exposure pathways to workers on the site and to members of the public outside the site boundary were considered in the calculations. The DRL's represent upper limits for routine emissions of radioactivity from the Chalk River Nuclear Laboratories to the surrounding environment. Actual releases are regulated by Administrative Levels, set lower than the DRL's, and are confirmed by monitoring. (author)

  8. Temporal variability of micro-organic contaminants in lowland chalk catchments: New insights into contaminant sources and hydrological processes.

    Science.gov (United States)

    Manamsa, K; Lapworth, D J; Stuart, M E

    2016-10-15

    This paper explores the temporal variation of a broad suite of micro organic (MO) compounds within hydrologically linked compartments of a lowland Chalk catchment, the most important drinking water aquifer in the UK. It presents an assessment of results from relatively high frequency monitoring at a well-characterised site, including the type and concentrations of compounds detected and how they change under different hydrological conditions including exceptionally high groundwater levels and river flow conditions during 2014 and subsequent recovery. This study shows for the first time that within the Chalk groundwater there can be a greater diversity of the MOs compared to surface waters. Within the Chalk 26 different compounds were detected over the duration of the study compared to 17 in the surface water. Plasticisers (0.06-39μg/L) were found to dominate in the Chalk groundwater on 5 visits (38.4%) accounting for 14.5% of detections but contributing highest concentrations whilst other compounds dominated in the surface water. Trichloroethene and atrazine were among the most frequently detected compounds. The limit for the total pesticide concentration detected did not exceed EU/UK prescribed concentration values for drinking water. Emerging organic compounds such as caffeine, which currently do not have water quality limits, were also detected. The low numbers of compounds found within the hyporheic zone highlight the role of this transient interface in the attenuation and breakdown of the MOs, and provision of an important ecosystem service. Copyright © 2016 British Geological Survey, NERC. Published by Elsevier B.V. All rights reserved.

  9. Importance of small fishes and invasive crayfish in otter Lutra lutra diet in an English chalk stream

    OpenAIRE

    Britton, J.R.; Berry, M.; Sewell, S.; Lees, C.; Reading, P.

    2017-01-01

    The diet composition of the European otter Lutra lutra was assessed using spraint analysis in the Hampshire Avon, a lowland chalk stream in Southern England, over an 18-month period. Small cyprinid fishes were the main prey item taken in all seasons, with bullhead Cottus gobio and stone loach Barbatula barbatula also important; there were relatively few larger fishes of interest to fisheries found. There were significant seasonal differences in diet composition by season, with signal crayfish...

  10. Geologic models and evaluation of undiscovered conventional and continuous oil and gas resources: Upper Cretaceous Austin Chalk

    Science.gov (United States)

    Pearson, Krystal

    2012-01-01

    The Upper Cretaceous Austin Chalk forms a low-permeability, onshore Gulf of Mexico reservoir that produces oil and gas from major fractures oriented parallel to the underlying Lower Cretaceous shelf edge. Horizontal drilling links these fracture systems to create an interconnected network that drains the reservoir. Field and well locations along the production trend are controlled by fracture networks. Highly fractured chalk is present along both regional and local fault zones. Fractures are also genetically linked to movement of the underlying Jurassic Louann Salt with tensile fractures forming downdip of salt-related structures creating the most effective reservoirs. Undiscovered accumulations should also be associated with structure-controlled fracture systems because much of the Austin that overlies the Lower Cretaceous shelf edge remains unexplored. The Upper Cretaceous Eagle Ford Shale is the primary source rock for Austin Chalk hydrocarbons. This transgressive marine shale varies in thickness and lithology across the study area and contains both oil- and gas-prone kerogen. The Eagle Ford began generating oil and gas in the early Miocene, and vertical migration through fractures was sufficient to charge the Austin reservoirs.

  11. Water movements in the unsaturated zone and recharge of the aquifer in the Champagne Chalk (France): Isotopic and chemical approaches

    International Nuclear Information System (INIS)

    Vachier, P.; Dever, L.; Fontes, J.C.

    1987-01-01

    Water from the unsaturated zone in the chalk, obtained from porous plugs, was subjected to chemical and isotope analyses over a three-year period. Tensiometric and volumetric water content measurements were carried out at the same time. The results obtained make it possible to establish an outline of the hydrodynamics of this porous, fissured chalk medium. Matrix porosity was 0.42 while fissure porosity was in the region of 0.01. The tritium and nitrate concentrations in the water fix the mean residence time in the 20-metre unsaturated zone at about 30 years. The isotope profiles ( 18 O and 3 H) and their downward displacements make it possible to estimate the mean annual recharge into the unconfined groundwater in the chalk (200 to 300 mm, depending on plant cover). The vertical movement of the solution in the porous matrix is dominated by the piston effect. Variations in 18 O concentration can be correlated with local climatic fluctuations. The recharge period runs from November to March, with summer rainfall playing no part. A comparison of 2 H and 18 O concentrations shows that even winter rainfall is partially removed by evaporation. (author). 17 refs, 11 figs, 1 tab

  12. Assessment of contaminant concentrations in sediments, fish and mussels sampled from the North Atlantic and European regional seas within the ICON project.

    Science.gov (United States)

    Robinson, Craig D; Webster, Lynda; Martínez-Gómez, Concepción; Burgeot, Thierry; Gubbins, Matthew J; Thain, John E; Vethaak, A Dick; McIntosh, Alistair D; Hylland, Ketil

    2017-03-01

    Understanding the status of contaminants in the marine environment is a requirement of European Union Directives and the Regional Seas Conventions, so that measures to reduce pollution can be identified and their efficacy assessed. The international ICON workshop (Hylland et al., in this issue) was developed in order to test an integrated approach to assessing both contaminant concentrations and their effects. This paper describes and assesses the concentrations of trace metals, polycyclic aromatic hydrocarbons, and polychlorinated biphenyls in sediments, mussels, and fish collected from estuarine, coastal and offshore waters from Iceland to the Mediterranean Sea. For organic contaminants, concentrations progressively increased from Iceland, to the offshore North Sea, to the coastal seas, and were highest in estuaries. Metals had a more complex distribution, reflecting local anthropogenic inputs, natural sources and hydrological conditions. Use of internationally recognised assessment criteria indicated that at no site were concentrations of all contaminants at background and that concentrations of some contaminants were of significant concern in all areas, except the central North Sea. Crown Copyright © 2016. Published by Elsevier Ltd. All rights reserved.

  13. Identifying evidence of climate change impact on extreme events in permeable chalk catchments

    Science.gov (United States)

    Butler, A. P.; Nubert, S.

    2009-12-01

    The permeable chalk catchments of southern England are vital for the economy and well being of the UK. Not only important as a water resource, their freely draining soils support intensive agricultural production, and the rolling downs and chalk streams provide important habitants for many protected plant and animal species. Consequently, there are concerns about the potential impact of climate change on such catchments, particularly in relation to groundwater recharge. Of major concern are possible changes in extreme events, such as groundwater floods and droughts, as any increase in the frequency and/or severity of these has important consequences for water resources, ecological systems and local infrastructure. Studies of climate change impact on extreme events for such catchments have indicated that, under medium and high emissions scenarios, droughts are likely to become more severe whilst floods less so. However, given the uncertainties in such predictions and the inherent variability in historic data, producing definitive evidence of changes in flood/drought frequency/severity poses a significant challenge. Thus, there is a need for specific extreme event statistics that can be used as indicators of actual climate change in streamflow and groundwater level observations. Identifying such indicators that are sufficiently robust requires catchments with long historic time series data. One such catchment is the River Lavant, an intermittent chalk stream in West Sussex, UK. Located within this catchment is Chilgrove House, the site of the UK’s longest groundwater monitoring well (with a continuous record of water level observations of varying frequency dating back to 1836). Using a variety of meteorological datasets, the behaviour of the catchment has been modelled, from 1855 to present, using a 'leaky aquifer' conceptual model. Model calibration was based on observed daily streamflow, at a gauging station just outside the town of Chichester, from 1970. Long

  14. Integrating geophysical and hydrochemical borehole-log measurements to characterize the Chalk aquifer, Berkshire, United Kingdom

    Science.gov (United States)

    Schürch, Marc; Buckley, David

    2002-09-01

    Geophysical and hydrochemical borehole-logging techniques were integrated to characterize hydraulic and hydrogeochemical properties of the Chalk aquifer at boreholes in Berkshire, UK. The down-hole measurements were made to locate fissures in the chalk, their spatial extent between boreholes, and to determine the groundwater chemical quality of the water-bearing layers. The geophysical borehole logging methods used were caliper, focused resistivity, induction resistivity, gamma ray, fluid temperature, fluid electrical conductivity, impeller and heat-pulse flowmeter, together with borehole wall optical-imaging. A multiparameter data transmitter was used to measure groundwater temperature, electrical conductivity, dissolved oxygen, pH, and redox potential of the borehole fluid down-hole. High permeability developed at the Chalk Rock by groundwater circulation provides the major flow horizon at the Banterwick Barn study site and represents a conduit system that serves as an effective local hydraulic connection between the boreholes. The Chalk Rock includes several lithified solution-ridden layers, hardgrounds, which imply a gap in sedimentation possibly representing an unconformity. Lower groundwater temperature, high dissolved-oxygen content, and flowmeter evidence of preferential groundwater flow in the Chalk Rock indicated rapid groundwater circulation along this horizon. By repeating the logging at different times of the year under changing hydraulic conditions, other water-inflow horizons within the Chalk aquifer were recognized. Résumé. Des techniques géophysiques et hydrochimiques de diagraphies en forage ont été mises en oeuvre pour caractériser les propriétés hydrauliques et hydrogéochimiques de l'aquifère de la craie dans des forages du Berkshire (Grande-Bretagne). Les mesures en descente ont été faites pour localiser les fissures dans la craie et leur développement spatial entre forages, et pour déterminer la qualité de l'eau souterraine des

  15. Development of an Integrated Waste Plan for Chalk River Laboratories - 13376

    International Nuclear Information System (INIS)

    Jones, L.

    2013-01-01

    To further its Strategic Planning, the Atomic Energy of Canada Limited (AECL) required an effective approach to developing a fully integrated waste plan for its Chalk River Laboratories (CRL) site. Production of the first Integrated Waste Plan (IWP) for Chalk River was a substantial task involving representatives from each of the major internal stakeholders. Since then, a second revision has been produced and a third is underway. The IWP remains an Interim IWP until all gaps have been resolved and all pathways are at an acceptable level of detail. Full completion will involve a number of iterations, typically annually for up to six years. The end result of completing this process is a comprehensive document and supporting information that includes: - An Integrated Waste Plan document summarizing the entire waste management picture in one place; - Details of all the wastes required to be managed, including volume and timings by waste stream; - Detailed waste stream pathway maps for the whole life-cycle for each waste stream to be managed from pre-generation planning through to final disposition; and - Critical decision points, i.e. decisions that need to be made and timings by when they need to be made. A waste inventory has been constructed that serves as the master reference inventory of all waste that has been or is committed to be managed at CRL. In the past, only the waste that is in storage has been effectively captured, and future predictions of wastes requiring to be managed were not available in one place. The IWP has also provided a detailed baseline plan at the current level of refinement. Waste flow maps for all identified waste streams, for the full waste life cycle complete to disposition have been constructed. The maps identify areas requiring further development, and show the complexities and inter-relationships between waste streams. Knowledge of these inter-dependencies is necessary in order to perform effective options studies for enabling

  16. Assessment of contaminant concentrations in sediments, fish and mussels sampled from the North Atlantic and European regional seas within the ICON project

    NARCIS (Netherlands)

    Robinson, Craig D.; Webster, Lynda; Martínez-Gómez, Concepción; Burgeot, Thierry; Gubbins, Matthew J.; Thain, John E.; Vethaak, A. Dick; McIntosh, Alistair D.; Hylland, Ketil

    Understanding the status of contaminants in the marine environment is a requirement of European Union Directives and the Regional Seas Conventions, so that measures to reduce pollution can be identified and their efficacy assessed. The international ICON workshop (Hylland et al., in this issue) was

  17. Assessing coastal wetland vulnerability to sea-level rise along the northern Gulf of Mexico coast: Gaps and opportunities for developing a coordinated regional sampling network.

    Science.gov (United States)

    Osland, Michael J; Griffith, Kereen T; Larriviere, Jack C; Feher, Laura C; Cahoon, Donald R; Enwright, Nicholas M; Oster, David A; Tirpak, John M; Woodrey, Mark S; Collini, Renee C; Baustian, Joseph J; Breithaupt, Joshua L; Cherry, Julia A; Conrad, Jeremy R; Cormier, Nicole; Coronado-Molina, Carlos A; Donoghue, Joseph F; Graham, Sean A; Harper, Jennifer W; Hester, Mark W; Howard, Rebecca J; Krauss, Ken W; Kroes, Daniel E; Lane, Robert R; McKee, Karen L; Mendelssohn, Irving A; Middleton, Beth A; Moon, Jena A; Piazza, Sarai C; Rankin, Nicole M; Sklar, Fred H; Steyer, Greg D; Swanson, Kathleen M; Swarzenski, Christopher M; Vervaeke, William C; Willis, Jonathan M; Wilson, K Van

    2017-01-01

    Coastal wetland responses to sea-level rise are greatly influenced by biogeomorphic processes that affect wetland surface elevation. Small changes in elevation relative to sea level can lead to comparatively large changes in ecosystem structure, function, and stability. The surface elevation table-marker horizon (SET-MH) approach is being used globally to quantify the relative contributions of processes affecting wetland elevation change. Historically, SET-MH measurements have been obtained at local scales to address site-specific research questions. However, in the face of accelerated sea-level rise, there is an increasing need for elevation change network data that can be incorporated into regional ecological models and vulnerability assessments. In particular, there is a need for long-term, high-temporal resolution data that are strategically distributed across ecologically-relevant abiotic gradients. Here, we quantify the distribution of SET-MH stations along the northern Gulf of Mexico coast (USA) across political boundaries (states), wetland habitats, and ecologically-relevant abiotic gradients (i.e., gradients in temperature, precipitation, elevation, and relative sea-level rise). Our analyses identify areas with high SET-MH station densities as well as areas with notable gaps. Salt marshes, intermediate elevations, and colder areas with high rainfall have a high number of stations, while salt flat ecosystems, certain elevation zones, the mangrove-marsh ecotone, and hypersaline coastal areas with low rainfall have fewer stations. Due to rapid rates of wetland loss and relative sea-level rise, the state of Louisiana has the most extensive SET-MH station network in the region, and we provide several recent examples where data from Louisiana's network have been used to assess and compare wetland vulnerability to sea-level rise. Our findings represent the first attempt to examine spatial gaps in SET-MH coverage across abiotic gradients. Our analyses can be used

  18. Assessing coastal wetland vulnerability to sea-level rise along the northern Gulf of Mexico coast: Gaps and opportunities for developing a coordinated regional sampling network.

    Directory of Open Access Journals (Sweden)

    Michael J Osland

    Full Text Available Coastal wetland responses to sea-level rise are greatly influenced by biogeomorphic processes that affect wetland surface elevation. Small changes in elevation relative to sea level can lead to comparatively large changes in ecosystem structure, function, and stability. The surface elevation table-marker horizon (SET-MH approach is being used globally to quantify the relative contributions of processes affecting wetland elevation change. Historically, SET-MH measurements have been obtained at local scales to address site-specific research questions. However, in the face of accelerated sea-level rise, there is an increasing need for elevation change network data that can be incorporated into regional ecological models and vulnerability assessments. In particular, there is a need for long-term, high-temporal resolution data that are strategically distributed across ecologically-relevant abiotic gradients. Here, we quantify the distribution of SET-MH stations along the northern Gulf of Mexico coast (USA across political boundaries (states, wetland habitats, and ecologically-relevant abiotic gradients (i.e., gradients in temperature, precipitation, elevation, and relative sea-level rise. Our analyses identify areas with high SET-MH station densities as well as areas with notable gaps. Salt marshes, intermediate elevations, and colder areas with high rainfall have a high number of stations, while salt flat ecosystems, certain elevation zones, the mangrove-marsh ecotone, and hypersaline coastal areas with low rainfall have fewer stations. Due to rapid rates of wetland loss and relative sea-level rise, the state of Louisiana has the most extensive SET-MH station network in the region, and we provide several recent examples where data from Louisiana's network have been used to assess and compare wetland vulnerability to sea-level rise. Our findings represent the first attempt to examine spatial gaps in SET-MH coverage across abiotic gradients. Our

  19. Proposed approach for bedrock characterization at Chalk River Nuclear Laboratories for waste disposal

    International Nuclear Information System (INIS)

    Heystee, R.J.; Dixon, D.F.

    1985-07-01

    Low- and intermediate-level wastes (L AND ILW) are produced at the Chalk River Nuclear Laboratories (CRNL) by the operation of reactors for nuclear research and development and by the production of radioisotopes. CRNL also manages L and ILW produced by Canadian research laboratories, universities, hospitals and some industries. An option that is being considered for the disposal of some of these wastes is to emplace them in a shallow rock cavity in fractured crystalline bedrock on the CRNL property. To design such a disposal facility and to evalute its long-term performance, data must be obtained on the geologic and hydrogeologic characteristics of the site. Over the past several years, a variety of airborne, ground surface and borehole geological, geophysical and/or hydrogeological methods have been used to acquire data on some rock mass discontinuities at CRNL. The techniques which are apparently more useful for acquiring these data are described and a proposed approach to site characterization for a shallow rock cavity at CRNL is outlined

  20. AECL'S approach to managing long term liabilities at Chalk River Laboratories. Annex II

    International Nuclear Information System (INIS)

    Audet, M.C.

    2006-01-01

    Chalk River Laboratories (CRL) is a large nuclear research and development/ industrial site operated by Atomic Energy of Canada Limited (AECL). Construction of the site started in 1944, and it now includes over 100 buildings/facilities operating in various nuclear fields. A well developed decommissioning programme exists at CRL, with progress being made on decommissioning older redundant buildings, in parallel with ongoing site operations and development. The decommissioning programme is predicated on the assumption that the current nuclear operations will continue over a 100 year operating period, but with a decline towards the end of the period. Although decommissioning and remediation work will be carried out throughout the operational period, residual levels of activity remaining in a few areas will require institutional control (IC) for an assumed period of 300 years. The intention is to complete all necessary active remediation work before the start of the IC period and thereafter rely only on passive means to reduce residual contamination to levels that do not require IC measures. The latter include environmental monitoring, active and passive controls to prevent intrusion, and management controls to prohibit access or development. A formal information and records management programme at CRL has been initiated. (author)

  1. Tritium behavior on a cultivated plot in the 1994 chronic HT release experiment at Chalk River

    International Nuclear Information System (INIS)

    Noguchi, H.; Yokoyama, S.; Kinouchi, N.; Murata, M.; Amano, H.; Atarashi, M.; Ichimasa, Y.; Ichimasa, M.

    1995-01-01

    The behavior of HT and HTO in air and surface soil has been studied extensively in the chronic HT release experiment carried out at Chalk River during the summer of 1994. HTO concentrations in air moisture and soil water collected in a cultivated plot showed similar time-variations, increasing rapidly during the first and second days and becoming gradual after the first 3-4 days. The air HTO concentration decreased during and following rainfall but recovered within a day. The rainfall reduced the HTO concentrations in ridge soil water but little in furrows. Time histories of HTO concentrations in air moisture and soil water suggest that the system was near steady-state within a continuous HT release period of 12 days, in spite of the presence of rain during the period. The air HTO concentrations on clear days showed diurnal cycles that were higher during daytime than at night. The experimental field had a very complex soil regime with respect to HT deposits. The deposits to soil surface varied depending on soil conditions. 12 refs., 5 figs

  2. An overview of the waste characterization program at Chalk River Nuclear Laboratories

    International Nuclear Information System (INIS)

    Csullog, G.W.; Hardy, D.G.

    1988-01-01

    In the last five years, Chalk River Nuclear Laboratories (CRNL) placed 17,000 m 3 of wastes into storage (excluding contaminated soil and fill). Almost half of the waste was generated off-site. CRNL is now developing IRUS, an Intrusion Resistant Underground Structure, and the IST, an Improved Sand Trench, to replace storage with safe, permanent disposal. IRUS will be used to dispose of wastes with radiologically hazardous lifetimes between 150 and 500 years duration and the IST will be used for wastes with radiologically hazardous lifetimes of less than 150 years. A comprehensive Waste Characterization Program (WCP) is in place to support disposal projects. The WCP is responsible for (1) specifying the manifests for waste shipments; (2) developing and maintaining central databases for waste inventories and analytical data; and (3) developing the technologies and procedures to characterize the radiological and the physical/chemical properties of wastes. WCP work is being performed under the umbrella of a newly developed waste management quality assurance (QA) program. This paper gives an overview of the WCP with an emphasis on the requirements for determining radionuclide inventories in wastes, for implementing record-keeping systems and for maintaining a QA program for disposal operations

  3. Impact of microstructure evolution on the difference between geometric and reactive surface areas in natural chalk

    Science.gov (United States)

    Yang, Y.; Bruns, S.; Stipp, S. L. S.; Sørensen, H. O.

    2018-05-01

    The coupling between flow and mineral dissolution drives the evolution of many natural and engineered flow systems. Pore surface changes as microstructure evolves but this transient behaviour has traditionally been difficult to model. We combined a reactor network model with experimental, greyscale tomography data to establish the morphological grounds for differences among geometric, reactive and apparent surface areas in dissolving chalk. This approach allowed us to study the effects of initial geometry and macroscopic flow rate independently. The simulations showed that geometric surface, which represents a form of local transport heterogeneity, increases in an imposed flow field, even when the porous structure is chemically homogeneous. Hence, the fluid-reaction coupling leads to solid channelisation, which further results in fluid focusing and an increase in geometric surface area. Fluid focusing decreases the area of reactive surface and the residence time of reactant, both contribute to the over-normalisation of reaction rate. In addition, the growing and merging of microchannels, near the fluid entrance, contribute to the macroscopic, fast initial dissolution rate of rocks.

  4. Glaciotectonic deformations in the Jammerbugt and glaciodynamic development in the eastern North Sea

    DEFF Research Database (Denmark)

    Pedersen, Stig A. Schack; Boldreel, Lars Ole

    2017-01-01

    –Early Weichselian Skærumhede Group, indicating a Saalian age of the glaciotectonic deformation. The balancing of the thrust fault structures shows that the thrust sheets in the tailing end of the complex had their source in the Skagerrak sea. The hole caused by displacement contributed to formation of the Skagerrak......The Quaternary geology in the eastern part of the North Sea is characterized by large-scale glaciotectonic complexes. The northernmost complex is the Jammerbugt Glaciotectonic Complex here addressed, which occupies an area of more than 300km2. It was recently recognized during an investigation...... of conventional seismic profiles located about 10km offshore the west coast of northern Denmark. The deformed bedrock includes the main part of the Cretaceous Chalk Group in the North Sea. In the northern part of the complex the detachment surface is situated in Lower Cretaceous greensand about 400m below sea...

  5. Geologic feasibility of selected chalk-bearing sequences within the conterminous United States with regard to siting of radioactive-waste repositories

    International Nuclear Information System (INIS)

    Gonzales, S.

    1975-11-01

    Various geologic and hydrologic parameters are evaluated in relation to assessing the potential for repository storage of high-level radioactive wastes within several stratigraphic sequences dominated by chalks and chalky limestones. The former lithology is defined as a carbonate rock consisting mainly of very fine-grained particles of micritic calcite. Although chalks also contain coarser-grained particles such as shells of fossil foraminifera and non-calcitic minerals like quartz, most contain more than 90 percent micritic material. The latter represents broken fossil coccolith plates. The chalk-dominated formations discussed are exposed and underlie two different physiographic provinces which nevertheless display a general similarity in both being regions of extensive plains. The Niobrara Formation occurs mainly within the Great Plains province, while the Austin Chalk of Texas and the Selma Group of Alabama and Mississippi are located in the western and eastern Gulf Coastal Plain, respectively. The preliminary assessment is that chalk-bearing sequences show some promise and are deserving of added consideration and evaluation. Containment for hundreds of thousands of years would seem possible given certain assumptions. The most promising units from the three studied are the Niobrara Formation and Selma Group. Regional and local conditions make the Austin more suspect

  6. U–Pb, Rb–Sr, and U-series isotope geochemistry of rocks and fracture minerals from the Chalk River Laboratories site, Grenville Province, Ontario, Canada

    International Nuclear Information System (INIS)

    Neymark, L.A.; Peterman, Z.E.; Moscati, R.J.; Thivierge, R.H.

    2013-01-01

    Highlights: • AECL evaluates Chalk River Laboratories site as potential nuclear waste repository. • Isotope-geochemical data for rocks and fracture minerals at CRL site are reported. • Zircons from gneiss and granite yielded U–Pb ages of 1472 ± 14 and 1045 ± 6 Ma. • WR Rb–Sr and Pb–Pb systems do not show substantial large-scale isotopic mobility. • U-series and REE data do not support oxidizing conditions at depth in the past 1 Ma. - Abstract: As part of the Geologic Waste Management Facility feasibility study, Atomic Energy of Canada Ltd. (AECL) is evaluating the suitability of the Chalk River Laboratories (CRL) site in Ontario, situated in crystalline rock of the southwestern Grenville Province, for the possible development of an underground repository for low- and intermediate-level nuclear waste. This paper presents petrographic and trace element analyses, U–Pb zircon dating results, and Rb–Sr, U–Pb and U-series isotopic analyses of gneissic drill core samples from the deep CRG-series characterization boreholes at the CRL site. The main rock types intersected in the boreholes include hornblende–biotite (±pyroxene) gneisses of granitic to granodioritic composition, leucocratic granitic gneisses with sparse mafic minerals, and garnet-bearing gneisses with variable amounts of biotite and/or hornblende. The trace element data for whole-rock samples plot in the fields of within-plate, syn-collision, and volcanic arc-type granites in discrimination diagrams used for the tectonic interpretation of granitic rocks. Zircons separated from biotite gneiss and metagranite samples yielded SHRIMP-RG U–Pb ages of 1472 ± 14 (2σ) and 1045 ± 6 Ma, respectively, in very good agreement with widespread Early Mesoproterozoic plutonic ages and Ottawan orogeny ages in the Central Gneiss Belt. The Rb–Sr, U–Pb, and Pb–Pb whole-rock errorchron apparent ages of most of the CRL gneiss samples are consistent with zircon U–Pb age and do not indicate

  7. An overview of the ecological half-life of the 137Cs radioisotope and a determination of radioactivity levels in sediment samples after Chernobyl in the Eastern Black Sea, Turkey

    Science.gov (United States)

    Baltas, Hasan; Sirin, Murat; Dalgic, Goktug; Cevik, Ugur

    2018-01-01

    A study which determined the activity concentration of 137Cs in sediments contaminated by effluents from the Chernobyl accident which had collected along the coast of the Eastern Black Sea region in Turkey was carried out in 1993. Marine sediment samples were collected in 2015 from the same fifteen sampling points, and the activity concentrations of 226Ra, 232Th, 40K and 137Cs were determined for the sediment samples. The activity concentrations ranged from 10.94-25.95, 12.14-33.05, 265.74-459.89 and 2.08-37.45 Bq kg- 1 for 226Ra, 232Th, 40K and 137Cs respectively. The results showed that there was a steep decline in 137Cs within the sediment at most of the sampling sites from the Eastern Black Sea region during the 22-year period, except for two sites at which the measured levels were much higher. This may be the result of the combined effects of radioactive contaminant entry into this area from rivers, environmental changes and nuclear testing between 1993 and 2015. Furthermore, the ecological half-life (EHL) of the 137Cs radionuclide was estimated for the sediment samples, and radiological hazard parameters such as the absorbed dose rate in air (D), the annual effective dose equivalent (AEDE) and the excess lifetime cancer risk (ELCR) were calculated and compared with the international recommended values. It was shown that these sediments do not present any significant health risk for humans in this area.

  8. Current status of the waste identification program at AECL's Chalk River Laboratories

    International Nuclear Information System (INIS)

    Csullog, G.W.; Edwards, N.W.; TerHuurne, M.A.

    1998-01-01

    The management of routine operating waste by Waste Management and Decommissioning (WM and D) at Atomic Energy of Canada Limited's (AECL) Chalk River Laboratories (CRL) is supported by the Waste Identification (WI) Program. The principal purpose of the WI Program is to minimize the cost and the effort associated with waste characterization and waste tracking, which are needed to optimize waste handling, storage and disposal. The major steps in the WI Program are: (1) identify and characterize the processes that generate the routine radioactive wastes accepted by WM and D - radioisotope production, radioisotope use, reactor operation, fuel fabrication, et cetera (2) identify and characterize the routine blocks of waste generated by each process or activity - the initial characterization is based on inference (process knowledge) (3) prepare customized, template data sheets for each routine waste block - templates contain information such as package type, waste material, waste type, solidifying agent, the average non-radiological contaminant inventory, the average radiological contaminant inventory, and the waste class (4) ensure generators 'use the right piece of paper with the right waste' when they transfer waste to WM and D - that is they use the correct template data sheets to transfer routine wastes, by: identifying and marking waste collection points in the generator's facility; ensuring that generators implement effective waste collection/segregation procedures; implementing standard procedures to transfer waste to WM and D; and, auditing waste collection and segregation within a generator's facility (5) determine any additional waste block characterization requirements (is anything needed beyond the original characterization by process knowledge?) This paper describes the WI Program, it provides an example of its implementation, and it summarizes the current status of its implementation for both CRL and non-CRL waste generators. (author)

  9. Modelling flow and heat transfer through unsaturated chalk - Validation with experimental data from the ground surface to the aquifer

    Science.gov (United States)

    Thiéry, Dominique; Amraoui, Nadia; Noyer, Marie-Luce

    2018-01-01

    During the winter and spring of 2000-2001, large floods occurred in northern France (Somme River Basin) and southern England (Patcham area of Brighton) in valleys that are developed on Chalk outcrops. The floods durations were particularly long (more than 3 months in the Somme Basin) and caused significant damage in both countries. To improve the understanding of groundwater flooding in Chalk catchments, an experimental site was set up in the Hallue basin, which is located in the Somme River Basin (France). Unsaturated fractured chalk formation overlying the Chalk aquifer was monitored to understand its reaction to long and heavy rainfall events when it reaches a near saturation state. The water content and soil temperature were monitored to a depth of 8 m, and the matrix pressure was monitored down to the water table, 26.5 m below ground level. The monitoring extended over a 2.5-year period (2006-2008) under natural conditions and during two periods when heavy, artificial infiltration was induced. The objective of the paper is to describe a vertical numerical flow model based on Richards' equation using these data that was developed to simulate infiltrating rainwater flow from the ground surface to the saturated aquifer. The MARTHE computer code, which models the unsaturated-saturated continuum, was adapted to reproduce the monitored high saturation periods. Composite constitutive functions (hydraulic conductivity-saturation and pressure-saturation) that integrate the increase in hydraulic conductivity near saturation and extra available porosity resulting from fractures were introduced into the code. Using these composite constitutive functions, the model was able to accurately simulate the water contents and pressures at all depths over the entire monitored period, including the infiltration tests. The soil temperature was also accurately simulated at all depths, except during the infiltrations tests, which contributes to the model validation. The model was used

  10. Changes in Specific Surface as observed by NMR, caused by saturation of Chalk with porewater bearing divalent Ions

    DEFF Research Database (Denmark)

    Katika, Konstantina; Addassi, Mouadh; Alam, Mohammad Monzurul

    2014-01-01

    Nuclear Magnetic Resonance (NMR) spectrometry has proved to be a good technique for determining the petrophysical properties of reservoir rocks; such as porosity and pore size distribution. We investigated how pore water rich in divalent ions affect the NMR signal from chalk with two different de......-to-volume ratio of the pore space. The results of this work could benefit the ongoing study on the optimization of the water composition for Enhanced Oil Recovery (EOR) methods and shed light on how it can affect the mechanical and physical properties of the rock....

  11. Trace fossils of a cyclic chalk-marl succession; the upper Maastrichtian Rørdal Member, Denmark

    DEFF Research Database (Denmark)

    Lauridsen, Bodil Wesenberg; Surlyk, Finn; Bromley, Richard Granville

    2011-01-01

    Trace fossils from an upper Maastrichtian cyclic chalk–marl succession, the Rørdal Member, exposed in the Rørdal quarry, Denmark, are analysed in order to test whether the changes in substrate lithology exerted any control over the ichnodiversity, tiering complexity, and density of the infauna...... in the visibility of traces between chalk and marl and not due to differences in ecological stress upon the endobenthic community of the two lithologies. The study thus provides an excellent example of how the effect of taphonomic factors may give a misleading and biased impression of apparent differences...

  12. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from USCGC POLAR SEA in the South Pacific Ocean and Southern Oceans from 1994-02-04 to 1994-02-10 (NODC Accession 0116062)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0116062 includes chemical, discrete sample, physical and profile data collected from USCGC POLAR SEA in the South Pacific Ocean and Southern Oceans...

  13. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the G.O. SARS in the Barents Sea, North Atlantic Ocean and others from 2009-05-28 to 2009-08-11 (NODC Accession 0114433)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0114433 includes biological, chemical, discrete sample, physical and profile data collected from G.O. SARS in the Barents Sea, North Atlantic Ocean,...

  14. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HUDSON in the Labrador Sea and North Atlantic Ocean from 1992-05-27 to 1992-06-15 (NODC Accession 0113550)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113550 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Labrador Sea and North Atlantic Ocean from...

  15. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MARTHA L. BLACK in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2012-06-01 to 2012-06-17 (NCEI Accession 0144337)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144337 includes discrete sample and profile data collected from MARTHA L. BLACK in the Davis Strait, Labrador Sea and North Atlantic Ocean from...

  16. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2015-05-04 to 2015-05-24 (NCEI Accession 0160487)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0160487 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  17. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2009-05-17 to 2009-06-01 (NODC Accession 0108073)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108073 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  18. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2003-07-13 to 2003-08-04 (NODC Accession 0108219)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108219 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  19. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2014-05-02 to 2014-05-24 (NCEI Accession 0157623)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157623 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  20. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and underway - surface observations using Alkalinity titrator, CTD and other instruments from the MIRAI in the Coral Sea, North Pacific Ocean and others from 2009-04-10 to 2009-07-03 (NODC Accession 0108084)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108084 includes chemical, discrete sample, meteorological, physical, profile and underway - surface data collected from MIRAI in the Coral Sea, North...

  1. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from Surface underway, discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MIRAI in the Bering Sea, North Pacific Ocean and South Pacific Ocean from 2007-10-08 to 2007-12-26 (NODC Accession 0108123)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108123 includes Surface underway, discrete sample and profile data collected from MIRAI in the Bering Sea, North Pacific Ocean and South Pacific...

  2. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2007-01-17 to 2007-02-26 (NODC Accession 0112331)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112331 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  3. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 2000-10-11 to 2000-10-19 (NODC Accession 0112315)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112315 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 2000-10-11 to...

  4. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from PROFESSOR KHROMOV in the North Pacific Ocean and Sea of Okhotsk from 2000-06-02 to 2000-07-05 (NCEI Accession 0157453)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157453 includes chemical, discrete sample, physical and profile data collected from PROFESSOR KHROMOV in the North Pacific Ocean and Sea of Okhotsk...

  5. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from PROFESSOR KHROMOV in the North Pacific Ocean and Sea of Okhotsk from 1999-08-27 to 1999-09-28 (NCEI Accession 0157466)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157466 includes chemical, discrete sample, physical and profile data collected from PROFESSOR KHROMOV in the North Pacific Ocean and Sea of Okhotsk...

  6. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JAN MAYEN in the Arctic Ocean and Barents Sea from 2004-07-24 to 2004-07-31 (NODC Accession 0113566)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113566 includes chemical, discrete sample, physical and profile data collected from JAN MAYEN in the Arctic Ocean and Barents Sea from 2004-07-24 to...

  7. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the Davis Strait, Labrador Sea and North Atlantic Ocean from 1997-07-07 to 1997-08-09 (NODC Accession 0113913)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113913 includes chemical, discrete sample, physical and profile data collected from METEOR in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  8. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MELVILLE in the South Pacific Ocean and Tasman Sea from 2009-11-21 to 2010-02-11 (NODC Accession 0109920)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109920 includes discrete sample and profile data collected from MELVILLE in the South Pacific Ocean and Tasman Sea from 2009-11-21 to 2010-02-11 and...

  9. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HEALY in the Bering Sea from 2008-03-29 to 2008-05-06 (NCEI Accession 0144549)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144549 includes discrete sample and profile data collected from HEALY in the Bering Sea from 2008-03-29 to 2008-05-06. These data include AMMONIUM...

  10. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the LANCE in the Barents Sea from 1986-07-19 to 1986-07-26 (NODC Accession 0113910)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113910 includes chemical, discrete sample, physical and profile data collected from LANCE in the Barents Sea from 1986-07-19 to 1986-07-26 and...

  11. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the Caribbean Sea and North Atlantic Ocean from 2005-08-13 to 2005-09-19 (NODC Accession 0116566)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116566 includes chemical, discrete sample, physical and profile data collected from METEOR in the Caribbean Sea and North Atlantic Ocean from...

  12. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KNORR in the Caribbean Sea and North Atlantic Ocean from 1996-11-02 to 1997-09-03 (NODC Accession 0115005)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115005 includes chemical, discrete sample, physical and profile data collected from KNORR in the Caribbean Sea and North Atlantic Ocean from...

  13. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the MELVILLE in the North Pacific Ocean and Philippine Sea from 2004-06-15 to 2004-08-27 (NODC Accession 0108080)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108080 includes chemical, discrete sample, physical and profile data collected from MELVILLE in the North Pacific Ocean and Philippine Sea from...

  14. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2008-05-20 to 2008-06-04 (NODC Accession 0108224)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108224 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  15. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2004-01-20 to 2004-02-06 (NODC Accession 0112210)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112210 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  16. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from MIRAI in the South Pacific Ocean and Tasman Sea from 2003-08-03 to 2003-10-16 (NODC Accession 0108122)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108122 includes chemical, discrete sample, physical and profile data collected from MIRAI in the South Pacific Ocean and Tasman Sea from 2003-08-03...

  17. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and underway - surface observations using Alkalinity titrator, CTD and other instruments from the MIRAI in the Bismarck Sea, North Pacific Ocean and South Pacific Ocean from 2005-05-25 to 2005-07-02 (NODC Accession 0108081)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108081 includes chemical, discrete sample, physical, profile and underway - surface data collected from MIRAI in the Bismarck Sea, North Pacific...

  18. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2004-06-16 to 2004-08-13 (NODC Accession 0112212)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112212 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  19. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 1997-05-09 to 1997-06-11 (NODC Accession 0113557)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113557 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  20. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 1994-05-24 to 1994-06-12 (NODC Accession 0113554)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113554 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  1. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the LOUIS S. ST. LAURENT in the Beaufort Sea and Northwest Passage from 1997-08-31 to 1997-09-16 (NODC Accession 0116061)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116061 includes chemical, discrete sample, physical and profile data collected from LOUIS S. ST. LAURENT in the Beaufort Sea and Northwest Passage...

  2. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from unknown platforms in the North Greenland Sea from 2014-03-17 to 2014-03-19 (NCEI Accession 0160541)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0160541 includes chemical, discrete sample, physical and profile data collected from unknown platforms in the North Greenland Sea from 2014-03-17 to...

  3. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the LOUIS S. ST. LAURENT in the Arctic Ocean and Beaufort Sea from 1997-09-24 to 1997-10-15 (NODC Accession 0113984)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113984 includes chemical, discrete sample, physical and profile data collected from LOUIS S. ST. LAURENT in the Arctic Ocean and Beaufort Sea from...

  4. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HUDSON in the Gulf of St. Lawrence, Labrador Sea and North Atlantic Ocean from 1998-06-22 to 1998-07-09 (NODC Accession 0113610)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113610 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Gulf of St. Lawrence, Labrador Sea and North...

  5. Dissolved inorganic carbon, pH, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from METEOR in the Labrador Sea and North Atlantic Ocean from 1999-07-11 to 1999-08-10 (NODC Accession 0113585)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113585 includes chemical, discrete sample, physical and profile data collected from METEOR in the Labrador Sea and North Atlantic Ocean from...

  6. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the Davis Strait, Labrador Sea and North Atlantic Ocean from 1994-11-15 to 1994-12-19 (NODC Accession 0113581)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113581 includes chemical, discrete sample, physical and profile data collected from METEOR in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  7. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the Labrador Sea and North Atlantic Ocean from 2003-08-31 to 2003-10-05 (NODC Accession 0115587)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115587 includes chemical, discrete sample, physical and profile data collected from METEOR in the Labrador Sea and North Atlantic Ocean from...

  8. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the Caribbean Sea, North Atlantic Ocean and South Atlantic Ocean from 2002-06-07 to 2002-07-04 (NODC Accession 0115586)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115586 includes chemical, discrete sample, physical and profile data collected from METEOR in the Caribbean Sea, North Atlantic Ocean and South...

  9. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the METEOR in the Labrador Sea and North Atlantic Ocean from 2003-07-23 to 2003-08-29 (NODC Accession 0113891)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113891 includes chemical, discrete sample, physical and profile data collected from METEOR in the Labrador Sea and North Atlantic Ocean from...

  10. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HEALY in the Baffin Bay and Lincoln Sea from 2003-07-21 to 2003-08-16 (NODC Accession 0113909)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113909 includes chemical, discrete sample, physical and profile data collected from HEALY in the Baffin Bay and Lincoln Sea from 2003-07-21 to...

  11. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Bering Sea and North Pacific Ocean from 2002-10-11 to 2002-11-06 (NODC Accession 0112258)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112258 includes chemical, discrete sample, physical and profile data collected from MIRAI in the Bering Sea and North Pacific Ocean from 2002-10-11...

  12. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and time series profile observations using Alkalinity titrator, CTD and other instruments from HERMANO GINES in the Caribbean Sea from 1995-11-08 to 2015-07-29 (NODC Accession 0112926)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112926 includes discrete sample, profile and time series profile data collected from HERMANO GINES in the Caribbean Sea from 1995-11-08 to...

  13. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from METEOR in the Caribbean Sea and North Atlantic Ocean from 2004-07-10 to 2004-08-07 (NODC Accession 0116644)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0116644 includes chemical, discrete sample, physical and profile data collected from METEOR in the Caribbean Sea and North Atlantic Ocean from...

  14. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the RYOFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2001-10-10 to 2001-12-06 (NODC Accession 0115281)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115281 includes biological, chemical, discrete sample, physical and profile data collected from RYOFU MARU in the North Pacific Ocean, Philippine Sea...

  15. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2011-05-06 to 2011-05-28 (NODC Accession 0108124)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0108124 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  16. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Bering Sea and North Pacific Ocean from 2008-10-11 to 2008-11-07 (NODC Accession 0112271)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112271 includes chemical, discrete sample, physical and profile data collected from MIRAI in the Bering Sea and North Pacific Ocean from 2008-10-11...

  17. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from MARION DUFRESNE in the Indian Ocean and Savu Sea from 1992-02-17 to 1992-03-23 (NCEI Accession 0143946)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0143946 includes discrete sample and profile data collected from MARION DUFRESNE in the Indian Ocean and Savu Sea from 1992-02-17 to 1992-03-23. These...

  18. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the MARION DUFRESNE in the Indian Ocean and Savu Sea from 1989-07-30 to 1989-09-09 (NODC Accession 0117679)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0117679 includes chemical, discrete sample, physical and profile data collected from MARION DUFRESNE in the Indian Ocean and Savu Sea from 1989-07-30...

  19. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the TYRO in the Arctic Ocean and Beaufort Sea from 1996-09-13 to 1996-10-28 (NODC Accession 0116717)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116717 includes chemical, discrete sample, physical and profile data collected from TYRO in the Arctic Ocean and Beaufort Sea from 1996-09-13 to...

  20. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Arctic Ocean and Beaufort Sea from 1999-09-11 to 1999-10-05 (NODC Accession 0112350)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112350 includes chemical, discrete sample, physical and profile data collected from MIRAI in the Arctic Ocean and Beaufort Sea from 1999-09-11 to...

  1. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from KNORR in the Caribbean Sea and North Atlantic Ocean from 2003-09-22 to 2003-11-13 (NODC Accession 0108060)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108060 includes chemical, discrete sample, physical and profile data collected from KNORR in the Caribbean Sea and North Atlantic Ocean from...

  2. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from DISCOVERY in the Inner Sea - West Coast Scotland and North Atlantic Ocean from 2012-08-02 to 2012-08-15 (NCEI Accession 0157313)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157313 includes chemical, discrete sample, physical and profile data collected from DISCOVERY in the Inner Sea - West Coast Scotland and North...

  3. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from RYOFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2010-07-06 to 2010-08-22 (NODC Accession 0109921)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109921 includes biological, chemical, discrete sample, physical and profile data collected from RYOFU MARU in the North Pacific Ocean, Philippine Sea...

  4. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from OCEAN RESEARCHER I in the East China Sea from 2008-01-02 to 2008-01-09 (NODC Accession 0109902)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109902 includes biological, chemical, discrete sample, physical and profile data collected from OCEAN RESEARCHER I in the East China Sea (Tung Hai)...

  5. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, PAR Sensor and other instruments from MIRAI in the Bismarck Sea, North Pacific Ocean and South Pacific Ocean from 2011-01-12 to 2012-02-09 (NCEI Accession 0157014)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157014 includes biological, chemical, discrete sample, optical, physical and profile data collected from MIRAI in the Bismarck Sea, North Pacific...

  6. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the Barents Sea from 2000-09-23 to 2000-10-03 (NODC Accession 0113886)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113886 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the Barents Sea from 2000-09-23 to 2000-10-03 and...

  7. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea from 1996-11-21 to 1996-11-30 (NODC Accession 0113544)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113544 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea from 1996-11-21 to...

  8. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 2000-05-07 to 2000-05-15 (NODC Accession 0112312)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112312 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 2000-05-07 to...

  9. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1998-07-09 to 1998-07-17 (NODC Accession 0112303)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112303 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1998-07-09 to...

  10. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1999-10-06 to 1999-10-14 (NODC Accession 0112310)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112310 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1999-10-06 to...

  11. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1999-08-30 to 1999-09-06 (NODC Accession 0112309)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112309 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1999-08-30 to...

  12. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1999-04-28 to 1999-05-06 (NODC Accession 0112307)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112307 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1999-04-28 to...

  13. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 2000-01-21 to 2000-01-28 (NODC Accession 0112311)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112311 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 2000-01-21 to...

  14. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from RRS JAMES COOK in the Inner Sea - West Coast Scotland and North Atlantic Ocean from 2013-05-10 to 2013-05-24 (NCEI Accession 0157282)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157282 includes chemical, discrete sample, optical, physical and profile data collected from RRS JAMES COOK in the Inner Sea - West Coast Scotland...

  15. pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from the BELGICA in the North Sea from 2006-04-25 to 2006-05-11 (NODC Accession 0112762)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112762 includes chemical, discrete sample, physical and profile data collected from BELGICA in the North Sea from 2006-04-25 to 2006-05-11. These...

  16. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from THOMAS G. THOMPSON in the Bering Sea, North Pacific Ocean and South Pacific Ocean from 1993-07-05 to 1993-09-02 (NODC Accession 0115008)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0115008 includes chemical, discrete sample, physical and profile data collected from THOMAS G. THOMPSON in the Bering Sea, North Pacific Ocean and...

  17. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the MELVILLE in the Coral Sea and South Pacific Ocean from 1994-03-27 to 1994-06-25 (NODC Accession 0115761)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115761 includes chemical, discrete sample, physical and profile data collected from MELVILLE in the Coral Sea and South Pacific Ocean from 1994-03-27...

  18. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HEALY in the Bering Sea from 2008-07-03 to 2008-07-31 (NCEI Accession 0144981)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0144981 includes discrete sample and profile data collected from HEALY in the Bering Sea from 2008-07-03 to 2008-07-31. These data include AMMONIUM...

  19. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the MIRAI in the Bering Sea and North Pacific Ocean from 2004-08-07 to 2004-08-30 (NODC Accession 0113609)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113609 includes chemical, discrete sample, physical and profile data collected from MIRAI in the Bering Sea and North Pacific Ocean from 2004-08-07...

  20. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample, profile and time series profile observations using Alkalinity titrator, CTD and other instruments from POLARFRONT in the Norwegian Sea from 2001-10-31 to 2007-11-29 (NODC Accession 0112884)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112884 includes chemical, discrete sample, physical, profile and time series profile data collected from POLARFRONT in the Norwegian Sea from...

  1. Dissolved inorganic carbon, alkalinity, temperature and salinity collected from discrete sample and profile observations using CTD, bottle and other instruments from G.O. SARS in the Norwegian Sea from 2012-03-20 to 2012-03-22 (NCEI Accession 0156922)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0156922 includes chemical, discrete sample, physical and profile data collected from G.O. SARS in the Norwegian Sea from 2012-03-20 to 2012-03-22....

  2. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2005-05-26 to 2005-06-17 (NODC Accession 0108221)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108221 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  3. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2010-05-13 to 2010-05-30 (NODC Accession 0108225)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108225 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  4. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2002-06-23 to 2002-07-19 (NODC Accession 0108218)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108218 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  5. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2007-05-10 to 2007-05-27 (NODC Accession 0108223)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108223 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait, Labrador Sea and North Atlantic Ocean...

  6. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1998-08-19 to 1998-08-27 (NODC Accession 0112304)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112304 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1998-08-19 to...

  7. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the ARANDA in the North Atlantic Ocean and North Greenland Sea from 1997-08-05 to 1997-09-25 (NODC Accession 0115602)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115602 includes chemical, discrete sample, physical and profile data collected from ARANDA in the North Atlantic Ocean and North Greenland Sea from...

  8. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HUDSON in the Davis Strait and Labrador Sea from 1993-06-17 to 1993-06-29 (NODC Accession 0113552)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113552 includes chemical, discrete sample, physical and profile data collected from HUDSON in the Davis Strait and Labrador Sea from 1993-06-17 to...

  9. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from ATLANTIS in the Caribbean Sea and North Atlantic Ocean from 2012-03-24 to 2012-04-17 (NODC Accession 0109915)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0109915 includes discrete sample and profile data collected from ATLANTIS in the Caribbean Sea and North Atlantic Ocean from 2012-03-24 to 2012-04-17...

  10. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the Ryofu Maru II in the Bismarck Sea, North Pacific Ocean and others from 1994-07-07 to 1994-08-25 (NODC Accession 0115017)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115017 includes chemical, discrete sample, physical and profile data collected from Ryofu Maru II in the Bismarck Sea, North Pacific Ocean,...

  11. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KAIYO-MARU in the North Pacific Ocean and Philippine Sea from 1994-01-07 to 1994-02-10 (NODC Accession 0115007)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115007 includes chemical, discrete sample, physical and profile data collected from KAIYO-MARU in the North Pacific Ocean and Philippine Sea from...

  12. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the L'ATALANTE in the Caribbean Sea and North Atlantic Ocean from 2003-04-12 to 2003-04-25 (NODC Accession 0117494)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0117494 includes chemical, discrete sample, physical and profile data collected from L'ATALANTE in the Caribbean Sea and North Atlantic Ocean from...

  13. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KNORR in the Barents Sea, North Atlantic Ocean and others from 2002-05-30 to 2002-07-01 (NODC Accession 0113569)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113569 includes chemical, discrete sample, physical and profile data collected from KNORR in the Barents Sea, North Atlantic Ocean, North Greenland...

  14. Alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the Arctic Ocean and Beaufort Sea from 2004-09-01 to 2004-10-13 (NODC Accession 0112357)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112357 includes biological, chemical, discrete sample, physical and profile data collected from MIRAI in the Arctic Ocean and Beaufort Sea from...

  15. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2005-06-15 to 2005-08-12 (NODC Accession 0112215)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112215 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  16. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the HAKON MOSBY in the North Greenland Sea from 1994-02-03 to 1994-02-23 (NODC Accession 0117371)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0117371 includes chemical, discrete sample, physical and profile data collected from HAKON MOSBY in the North Greenland Sea from 1994-02-03 to...

  17. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from METEOR in the Labrador Sea and North Atlantic Ocean from 2001-05-07 to 2001-05-31 (NODC Accession 0113586)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0113586 includes chemical, discrete sample, physical and profile data collected from METEOR in the Labrador Sea and North Atlantic Ocean from...

  18. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2001-01-19 to 2001-03-09 (NODC Accession 0115321)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115321 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  19. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from MIRAI in the North Pacific Ocean and Philippine Sea from 2002-11-13 to 2002-12-16 (NODC Accession 0112356)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0112356 includes chemical, discrete sample, physical and profile data collected from MIRAI in the North Pacific Ocean and Philippine Sea from...

  20. Partial pressure (or fugacity) of carbon dioxide, dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KNORR in the South Pacific Ocean and Tasman Sea from 1992-05-02 to 1992-07-30 (NODC Accession 0115018)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115018 includes chemical, discrete sample, physical and profile data collected from KNORR in the South Pacific Ocean and Tasman Sea from 1992-05-02...

  1. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 2000-06-28 to 2000-07-06 (NODC Accession 0112313)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112313 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 2000-06-28 to...

  2. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from MELVILLE in the North Pacific Ocean and Philippine Sea from 2013-03-21 to 2013-05-01 (NODC Accession 0117338)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0117338 includes chemical, discrete sample, physical and profile data collected from MELVILLE in the North Pacific Ocean and Philippine Sea from...

  3. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KNORR in the Caribbean Sea, North Atlantic Ocean and South Atlantic Ocean from 1982-12-01 to 1983-02-18 (NODC Accession 0116706)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0116706 includes chemical, discrete sample, physical and profile data collected from KNORR in the Caribbean Sea, North Atlantic Ocean and South...

  4. Dissolved inorganic carbon, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the POLARSTERN in the Arctic Ocean and North Greenland Sea from 1987-07-04 to 1987-09-02 (NODC Accession 0113916)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0113916 includes chemical, discrete sample, physical and profile data collected from POLARSTERN in the Arctic Ocean and North Greenland Sea from...

  5. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using Alkalinity titrator, CTD and other instruments from DISCOVERY in the English Channel, Inner Sea - West Coast Scotland and others from 2011-06-06 to 2011-07-09 (NCEI Accession 0157451)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0157451 includes chemical, discrete sample, physical and profile data collected from DISCOVERY in the English Channel, Inner Sea - West Coast...

  6. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1998-10-07 to 1998-10-15 (NODC Accession 0112305)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112305 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1998-10-07 to...

  7. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from DISCOVERY in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2008-08-20 to 2008-09-25 (NODC Accession 0108367)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0108367 includes discrete sample and profile data collected from DISCOVERY in the Davis Strait, Labrador Sea and North Atlantic Ocean from 2008-08-20...

  8. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the JOHN V. VICKERS in the Bering Sea, North Pacific Ocean and South Pacific Ocean from 1992-08-16 to 1992-10-21 (NODC Accession 0115003)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115003 includes chemical, discrete sample, physical and profile data collected from JOHN V. VICKERS in the Bering Sea, North Pacific Ocean and South...

  9. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2008-01-17 to 2008-02-28 (NODC Accession 0112334)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112334 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  10. Temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from NOAA Ship OCEANOGRAPHER in the Coral Sea, North Pacific Ocean and others from 1987-06-06 to 1987-07-05 (NCEI Accession 0160542)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0160542 includes chemical, discrete sample, physical and profile data collected from NOAA Ship OCEANOGRAPHER in the Coral Sea, North Pacific Ocean,...

  11. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1999-07-09 to 1999-07-17 (NODC Accession 0112308)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112308 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1999-07-09 to...

  12. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2002-06-25 to 2002-08-01 (NODC Accession 0112204)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112204 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  13. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2003-06-25 to 2003-08-07 (NODC Accession 0112208)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112208 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...

  14. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1999-01-21 to 1999-01-28 (NODC Accession 0112306)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112306 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1999-01-21 to...

  15. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from MELVILLE in the Bering Sea, North Pacific Ocean and others from 1973-08-22 to 1974-06-09 (NCEI Accession 0163184)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0163184 includes chemical, discrete sample, physical and profile data collected from MELVILLE in the Bering Sea, North Pacific Ocean,...

  16. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from MELVILLE in the Arabian Sea, Bay of Bengal and others from 1977-12-04 to 1978-04-28 (NCEI Accession 0163183)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NCEI Accession 0163183 includes chemical, discrete sample, physical and profile data collected from MELVILLE in the Arabian Sea, Bay of Bengal, Gulf of Aden, Indian...

  17. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 2000-08-17 to 2000-08-25 (NODC Accession 0112314)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112314 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 2000-08-17 to...

  18. Dissolved inorganic carbon, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the L'ATALANTE in the Coral Sea, North Pacific Ocean and South Pacific Ocean from 1994-09-23 to 1994-10-29 (NODC Accession 0111870)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0111870 includes chemical, discrete sample, physical and profile data collected from L'ATALANTE in the Coral Sea, North Pacific Ocean and South...

  19. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, Coulometer for DIC measurement and other instruments from the SHUMPU MARU in the Philippine Sea from 1998-04-22 to 1998-04-30 (NODC Accession 0112302)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0112302 includes biological, chemical, discrete sample, physical and profile data collected from SHUMPU MARU in the Philippine Sea from 1998-04-22 to...

  20. Dissolved inorganic carbon, pH, alkalinity, temperature, salinity and other variables collected from discrete sample and profile observations using CTD, bottle and other instruments from the KEIFU MARU in the North Pacific Ocean, Philippine Sea and South Pacific Ocean from 2002-01-17 to 2002-03-06 (NODC Accession 0115278)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — NODC Accession 0115278 includes biological, chemical, discrete sample, physical and profile data collected from KEIFU MARU in the North Pacific Ocean, Philippine Sea...