Core-shell structure of Miglyol/poly(D,L-lactide)/Poloxamer nanocapsules studied by small-angle neutron scattering.

Science.gov (United States)

Rübe, Andrea; Hause, Gerd; Mäder, Karsten; Kohlbrecher, Joachim

2005-10-03

The contrast variation technique in small angle neutron scattering (SANS) was used to investigate the inner structure of nanocapsules on the example of poly(D,L-lactide) (PLA) nanocapsules. The determination of the PLA and Poloxamer shell thickness was the focus of this study. Highest sensitivity on the inner structure of the nanocapsules was obtained when the scattering length density of the solvent was varied between the one of the Miglyol core and the PLA shell. According to the fit data the PLA shell thickness was 9.8 nm. The z-averaged radius determined by SANS experiments correlated well with dynamic light scattering (DLS) results, although DLS values were systematically slightly higher than the ones measured by SANS. This could be explained by taking into account the influence of Poloxamer attached to the nanocapsules surface. For a refined fit model with a second shell consisting of Poloxamer, SANS values and DLS values fitted well with each other. The characterization method presented here is significant because detailed insights into the nanocapsule and the Poloxamer shell were gained for the first time. This method could be used to develop strategies for the optimization of the shell properties concerning controlled release and to study changes in the shell structure during degradation processes.

DNA-magnetic Particle Binding Analysis by Dynamic and Electrophoretic Light Scattering.

Science.gov (United States)

Haddad, Yazan; Dostalova, Simona; Kudr, Jiri; Zitka, Ondrej; Heger, Zbynek; Adam, Vojtech

2017-11-09

Isolation of DNA using magnetic particles is a field of high importance in biotechnology and molecular biology research. This protocol describes the evaluation of DNA-magnetic particles binding via dynamic light scattering (DLS) and electrophoretic light scattering (ELS). Analysis by DLS provides valuable information on the physicochemical properties of particles including particle size, polydispersity, and zeta potential. The latter describes the surface charge of the particle which plays major role in electrostatic binding of materials such as DNA. Here, a comparative analysis exploits three chemical modifications of nanoparticles and microparticles and their effects on DNA binding and elution. Chemical modifications by branched polyethylenimine, tetraethyl orthosilicate and (3-aminopropyl)triethoxysilane are investigated. Since DNA exhibits a negative charge, it is expected that zeta potential of particle surface will decrease upon binding of DNA. Forming of clusters should also affect particle size. In order to investigate the efficiency of these particles in isolation and elution of DNA, the particles are mixed with DNA in low pH (~6), high ionic strength and dehydration environment. Particles are washed on magnet and then DNA is eluted by Tris-HCl buffer (pH = 8). DNA copy number is estimated using quantitative polymerase chain reaction (PCR). Zeta potential, particle size, polydispersity and quantitative PCR data are evaluated and compared. DLS is an insightful and supporting method of analysis that adds a new perspective to the process of screening of particles for DNA isolation.

Characterization of Nanocellulose Using Small-Angle Neutron, X-ray, and Dynamic Light Scattering Techniques.

Science.gov (United States)

Mao, Yimin; Liu, Kai; Zhan, Chengbo; Geng, Lihong; Chu, Benjamin; Hsiao, Benjamin S

2017-02-16

Nanocellulose extracted from wood pulps using TEMPO (2,2,6,6-tetramethylpiperidine-1-oxyl radical)-mediated oxidation and sulfuric acid hydrolysis methods was characterized by small-angle neutron scattering (SANS), small-angle X-ray scattering (SAXS), and dynamic light scattering (DLS) techniques. The dimensions of this nanocellulose (TEMPO-oxidized cellulose nanofiber (TOCN) and sulfuric acid hydrolyzed cellulose nanocrystal (SACN)) revealed by the different scattering methods were compared with those characterized by transmission electron microscopy (TEM). The SANS and SAXS data were analyzed using a parallelepiped-based form factor. The width and thickness of the nanocellulose cross section were ∼8 and ∼2 nm for TOCN and ∼20 and ∼3 nm for SACN, respectively, where the fitting results from SANS and SAXS profiles were consistent with each other. DLS was carried out under both the V V mode with the polarizer and analyzer parallel to each other and the H V mode having them perpendicular to each other. Using rotational and translational diffusion coefficients obtained under the H V mode yielded a nanocellulose length qualitatively consistent with that observed by TEM, whereas the length derived by the translational diffusion coefficient under the V V mode appeared to be overestimated.

Measurement of shear-induced diffusion of red blood cells using dynamic light scattering-optical coherence tomography

Science.gov (United States)

Tang, Jianbo; Erdener, Sefik Evren; Li, Baoqiang; Fu, Buyin; Sakadzic, Sava; Carp, Stefan A.; Lee, Jonghwan; Boas, David A.

2018-02-01

Dynamic Light Scattering-Optical Coherence Tomography (DLS-OCT) takes the advantages of using DLS to measure particle flow and diffusion within an OCT resolution-constrained 3D volume, enabling the simultaneous measurements of absolute RBC velocity and diffusion coefficient with high spatial resolution. In this work, we applied DLS-OCT to measure both RBC velocity and the shear-induced diffusion coefficient within penetrating venules of the somatosensory cortex of anesthetized mice. Blood flow laminar profile measurements indicate a blunted laminar flow profile, and the degree of blunting decreases with increasing vessel diameter. The measured shear-induced diffusion coefficient was proportional to the flow shear rate with a magnitude of 0.1 to 0.5 × 10-6 mm2 . These results provide important experimental support for the recent theoretical explanation for why DCS is dominantly sensitive to RBC diffusive motion.

Extinction, emission, and scattering spectroscopy of 5-50 nm citrate-coated gold nanoparticles: An argument for curvature effects on aggregation

Science.gov (United States)

Esfahani, Milad Rabbani; Pallem, Vasanta L.; Stretz, Holly A.; Wells, Martha J. M.

2017-03-01

The interaction of macromolecules with gold nanoparticles (GNPs) is of interest in the emerging field of biomedical and environmental detection devices. However, the physicochemical properties, including spectra, of GNPs in aqueous solution in the absence of metal-macromolecular interactions must first be considered before their activity in biological and environmental systems can be understood. The specific objective of this research was to experimentally illuminate the role of nanoparticle core size on the spectral (simultaneous consideration of extinction, emission, and scattering) versus aggregation behaviors of citrate-coated GNPs (CT-GNPs). It is difficult to find in the literature systematic simultaneous presentation of scattering, emission, and extinction spectra, including the UV range, and thus the present work will aid those who would use such particles for spectroscopic related separations or sensors. The spectroscopic behavior of CT-GNPs with different core sizes (5, 10, 30, and 50 nm) was studied in ultra-pure water at pH 6.0-6.5 employing UV-visible extinction, excitation-emission matrix (EEM), resonance Rayleigh scattering, and dynamic light scattering (DLS) spectroscopies. The CT-GNP-5 and CT-GNP-10 samples aggregated, absorbed light, and emitted light. In contrast, the CT-GNP-30 and CT-GNP-50 samples did not aggregate and did not emit light, but scattered light intensely. Multimodal peaks were observed in the intensity-based DLS spectra of CT-GNP-5 and CT-GNP-10 samples. Monomodal peaks in the volume-based DLS spectra overestimated particle diameters by 60% and 30% for the CT-GNP-5 and CT-GNP-10 samples, respectively, but underestimated diameters by 10% and 4% for the CT-GNP-30 and CT-GNP-50 samples. The volume-based DLS spectra indicated that dimer and trimer aggregates contributed most to the overall volume of particles in the 5- and 10-nm CT-GNPs, whereas the CT-GNP-30 and CT-GNP-50 samples did not aggregate. Here, we discuss the potential

Monomeric Amyloid Beta Peptide in Hexafluoroisopropanol Detected by Small Angle Neutron Scattering.

Directory of Open Access Journals (Sweden)

Bo Zhang-Haagen

Full Text Available Small proteins like amyloid beta (Aβ monomers are related to neurodegenerative disorders by aggregation to insoluble fibrils. Small angle neutron scattering (SANS is a nondestructive method to observe the aggregation process in solution. We show that SANS is able to resolve monomers of small molecular weight like Aβ for aggregation studies. We examine Aβ monomers after prolonged storing in d-hexafluoroisopropanol (dHFIP by using SANS and dynamic light scattering (DLS. We determined the radius of gyration from SANS as 1.0±0.1 nm for Aβ1-40 and 1.6±0.1 nm for Aβ1-42 in agreement with 3D NMR structures in similar solvents suggesting a solvent surface layer with 5% increased density. After initial dissolution in dHFIP Aβ aggregates sediment with a major component of pure monomers showing a hydrodynamic radius of 1.8±0.3 nm for Aβ1-40 and 3.2±0.4 nm for Aβ1-42 including a surface layer of dHFIP solvent molecules.

Effect of solvent and temperature on the size distribution of casein micelles measured by dynamic light scattering.

Science.gov (United States)

Beliciu, C M; Moraru, C I

2009-05-01

The objectives of this study were to investigate the effect of the solvent on the accuracy of casein micelle particle size determination by dynamic light scattering (DLS) at different temperatures and to establish a clear protocol for these measurements. Dynamic light scattering analyses were performed at 6, 20, and 50 degrees C using a 90Plus Nanoparticle Size Analyzer (Brookhaven Instruments, Holtsville, NY). Raw and pasteurized skim milk were used as sources of casein micelles. Simulated milk ultrafiltrate, ultrafiltered water, and permeate obtained by ultrafiltration of skim milk using a 10-kDa cutoff membrane were used as solvents. The pH, ionic concentration, refractive index, and viscosity of all solvents were determined. The solvents were evaluated by DLS to ensure that they did not have a significant influence on the results of the particle size measurements. Experimental protocols were developed for accurate measurement of particle sizes in all solvents and experimental conditions. All measurements had good reproducibility, with coefficients of variation below 5%. Both the solvent and the temperature had a significant effect on the measured effective diameter of the casein micelles. When ultrafiltered permeate was used as a solvent, the particle size and polydispersity of casein micelles decreased as temperature increased. The effective diameter of casein micelles from raw skim milk diluted with ultrafiltered permeate was 176.4 +/- 5.3 nm at 6 degrees C, 177.4 +/- 1.9 nm at 20 degrees C, and 137.3 +/- 2.7 nm at 50 degrees C. This trend was justified by the increased strength of hydrophobic bonds with increasing temperature. Overall, the results of this study suggest that the most suitable solvent for the DLS analyses of casein micelles was casein-depleted ultrafiltered permeate. Dilution with water led to micelle dissociation, which significantly affected the DLS measurements, especially at 6 and 20 degrees C. Simulated milk ultrafiltrate seemed to give

Amphiphilic copolymers based on polyoxazoline and grape seed vegetable oil derivatives: self-assemblies and dynamic light scattering

Energy Technology Data Exchange (ETDEWEB)

Travelet, Christophe, E-mail: Christophe.Travelet@cermav.cnrs.fr [Universite Joseph Fourier (UJF), Institut de Chimie Moleculaire de Grenoble (ICMG-FR 2607 CNRS), PolyNat Carnot institute, Arcane LabEx, domaine universitaire de Grenoble, Centre de Recherches sur les Macromolecules Vegetales - CERMAV-UPR 5301 CNRS (France); Stemmelen, Mylene; Lapinte, Vincent [Universite de Montpellier II, Institut Charles Gerhardt Montpellier (UMR 5253 CNRS-UM2-UM1-ENSCM), equipe ingenierie et architectures macromoleculaires (France); Dubreuil, Frederic [Universite Joseph Fourier (UJF), Institut de Chimie Moleculaire de Grenoble (ICMG-FR 2607 CNRS), PolyNat Carnot institute, Arcane LabEx, domaine universitaire de Grenoble, Centre de Recherches sur les Macromolecules Vegetales - CERMAV-UPR 5301 CNRS (France); Robin, Jean-Jacques [Universite de Montpellier II, Institut Charles Gerhardt Montpellier (UMR 5253 CNRS-UM2-UM1-ENSCM), equipe ingenierie et architectures macromoleculaires (France); and others

2013-06-15

The self-assembly in solution of original structures of amphiphilic partially natural copolymers based on polyoxazoline [more precisely poly(2-methyl-2-oxazoline) (POx)] and grape seed vegetable oil derivatives (linear, T-, and trident-structure) is investigated. The results show that such systems are found, using dynamic light scattering (DLS), to spontaneously self-organize into monomodal, narrow-size, and stable nanoparticles in aqueous medium. The obtained hydrodynamic diameters (D{sub h}) range from 8.6 to 32.5 nm. Specifically, such size increases strongly with increasing natural block (i.e., lipophilic species) length due to higher hydrophobic interactions (from 10.1 nm for C{sub 19} to 19.2 nm for C{sub 57}). Furthermore, increasing the polyoxazoline (i.e., hydrophilic block) length leads to a moderate linear increase of the D{sub h}-values. Therefore, the first-order size effect comes from the natural lipophilic block, whereas the characteristic size can be tuned more finely (i.e., in a second-order) by choosing appropriately the polyoxazoline length. The DLS results in terms of characteristic size are corroborated using nanoparticle tracking analysis (NTA), and also by atomic force microscopy (AFM) and transmission electron microscopy (TEM) imaging where well-defined spherical and individual nanoparticles exhibit a very good mechanical resistance upon drying. Moreover, changing the lipophilic block architecture from linear to T-shape, while keeping the same molar mass, generates a branching and thus a shrinking by a factor of 2 of the nanoparticle volume, as observed by DLS. In this paper, it is clearly shown that the self-assemblies of amphiphilic block copolymer obtained from grape seed vegetable oil derivatives (sustainable renewable resources) as well as their tunability are of great interest for biomass valorization at the nanoscale level [continuation of the article by Stemmelen et al. (Polym Chem 4:1445-1458, 2013)].Graphical Abstract

Amphiphilic copolymers based on polyoxazoline and grape seed vegetable oil derivatives: self-assemblies and dynamic light scattering

International Nuclear Information System (INIS)

Travelet, Christophe; Stemmelen, Mylène; Lapinte, Vincent; Dubreuil, Frédéric; Robin, Jean-Jacques

2013-01-01

The self-assembly in solution of original structures of amphiphilic partially natural copolymers based on polyoxazoline [more precisely poly(2-methyl-2-oxazoline) (POx)] and grape seed vegetable oil derivatives (linear, T-, and trident-structure) is investigated. The results show that such systems are found, using dynamic light scattering (DLS), to spontaneously self-organize into monomodal, narrow-size, and stable nanoparticles in aqueous medium. The obtained hydrodynamic diameters (D h ) range from 8.6 to 32.5 nm. Specifically, such size increases strongly with increasing natural block (i.e., lipophilic species) length due to higher hydrophobic interactions (from 10.1 nm for C 19 to 19.2 nm for C 57 ). Furthermore, increasing the polyoxazoline (i.e., hydrophilic block) length leads to a moderate linear increase of the D h -values. Therefore, the first-order size effect comes from the natural lipophilic block, whereas the characteristic size can be tuned more finely (i.e., in a second-order) by choosing appropriately the polyoxazoline length. The DLS results in terms of characteristic size are corroborated using nanoparticle tracking analysis (NTA), and also by atomic force microscopy (AFM) and transmission electron microscopy (TEM) imaging where well-defined spherical and individual nanoparticles exhibit a very good mechanical resistance upon drying. Moreover, changing the lipophilic block architecture from linear to T-shape, while keeping the same molar mass, generates a branching and thus a shrinking by a factor of 2 of the nanoparticle volume, as observed by DLS. In this paper, it is clearly shown that the self-assemblies of amphiphilic block copolymer obtained from grape seed vegetable oil derivatives (sustainable renewable resources) as well as their tunability are of great interest for biomass valorization at the nanoscale level [continuation of the article by Stemmelen et al. (Polym Chem 4:1445–1458, 2013)].Graphical AbstractAmphiphilic copolymers based

Characterization of Comb-Shaped Copolymers by Multidetection SEC, DLS and SANS

Directory of Open Access Journals (Sweden)

Giulia Gelardi

2017-02-01

Full Text Available PolyCarboxylate ether-based superplasticizers (PCEs are a type of comb-shaped copolymers used as polymeric dispersants in cementitious materials. PCEs have a high degree of dispersity, which limits the suitability of conventional characterization techniques, such as Size Exclusion Chromatography (SEC. Properties of PCEs strongly depend on their molecular structure and a comprehensive characterization is needed to fully understand the structure–property relationships. PCEs with well-defined molecular structures were synthesized to study their solution conformation by SEC and scattering techniques. The combined use of SEC, dynamic light scattering and small-angle neutron scattering allowed us to demonstrate the validity of a scaling law describing the radius of gyration of comb-shaped copolymers as a function of their molecular structure. Moreover, we show that the use of SEC with standard calibration, although widely spread, is not adequate for PCEs.

Dynamic light scattering for the characterization and counting of extracellular vesicles: a powerful noninvasive tool

Science.gov (United States)

Palmieri, Valentina; Lucchetti, Donatella; Gatto, Ilaria; Maiorana, Alessandro; Marcantoni, Margherita; Maulucci, Giuseppe; Papi, Massimiliano; Pola, Roberto; De Spirito, Marco; Sgambato, Alessandro

2014-09-01

Extracellular vesicles (EVs) are cell-to-cell shuttles that have recently drawn interest both as drug delivery platforms and disease biomarkers. Despite the increasingly recognized relevance of these vesicles, their detection, and characterization still have several technical drawbacks. In this paper, we accurately assess the size distribution and concentration of EVs by using a high-throughput non-perturbative technique such as Dynamic Light Scattering (DLS). The vesicle radii distribution, as further confirmed by Atomic Force Microscopy experiments, ranges from 10 to 80 nm and appears very asymmetric towards larger radii with a main peak at roughly 30 nm. By combining DLS and Bradford assay, we also demonstrate the feasibility of recovering the concentration and its distribution of proteins contained inside vesicles. The sensitivity of our approach allows to detect protein concentrations as low as 0.01 mg/ml.

Scattering Studies of Hydrophobic Monomers in Liposomal Bilayers: An Expanding Shell Model of Monomer Distribution

International Nuclear Information System (INIS)

Richter, Andrew; Dergunov, Sergey; Ganus, Bill; Thomas, Zachary; Pingali, Sai Venkatesh; Urban, Volker S.; Liu, Yun; Porcar, Lionel; Pinkhassik, Eugene

2011-01-01

Hydrophobic monomers partially phase separate from saturated lipids when loaded into lipid bilayers in amounts exceeding a 1:1 monomer/lipid molar ratio. This conclusion is based on the agreement between two independent methods of examining the structure of monomer-loaded bilayers. Complete phase separation of monomers from lipids would result in an increase in bilayer thickness and a slight increase in the diameter of liposomes. A homogeneous distribution of monomers within the bilayer would not change the bilayer thickness and would lead to an increase in the liposome diameter. The increase in bilayer thickness, measured by the combination of small-angle neutron scattering (SANS) and small-angle X-ray scattering (SAXS), was approximately half of what was predicted for complete phase separation. The increase in liposome diameter, measured by dynamic light scattering (DLS), was intermediate between values predicted for a homogeneous distribution and complete phase separation. Combined SANS, SAXS, and DLS data suggest that at a 1.2 monomer/lipid ratio approximately half of the monomers are located in an interstitial layer sandwiched between lipid sheets. These results expand our understanding of using self-assembled bilayers as scaffolds for the directed covalent assembly of organic nanomaterials. In particular, the partial phase separation of monomers from lipids corroborates the successful creation of nanothin polymer materials with uniform imprinted nanopores. Pore-forming templates do not need to span the lipid bilayer to create a pore in the bilayer-templated films.

Shear-induced diffusion of red blood cells measured with dynamic light scattering-optical coherence tomography.

Science.gov (United States)

Tang, Jianbo; Erdener, Sefik Evren; Li, Baoqiang; Fu, Buyin; Sakadzic, Sava; Carp, Stefan A; Lee, Jonghwan; Boas, David A

2018-02-01

Quantitative measurements of intravascular microscopic dynamics, such as absolute blood flow velocity, shear stress and the diffusion coefficient of red blood cells (RBCs), are fundamental in understanding the blood flow behavior within the microcirculation, and for understanding why diffuse correlation spectroscopy (DCS) measurements of blood flow are dominantly sensitive to the diffusive motion of RBCs. Dynamic light scattering-optical coherence tomography (DLS-OCT) takes the advantages of using DLS to measure particle flow and diffusion within an OCT resolution-constrained three-dimensional volume, enabling the simultaneous measurements of absolute RBC velocity and diffusion coefficient with high spatial resolution. In this work, we applied DLS-OCT to measure both RBC velocity and the shear-induced diffusion coefficient within penetrating venules of the somatosensory cortex of anesthetized mice. Blood flow laminar profile measurements indicate a blunted laminar flow profile and the degree of blunting decreases with increasing vessel diameter. The measured shear-induced diffusion coefficient was proportional to the flow shear rate with a magnitude of ~0.1 to 0.5 × 10 -6  mm 2 . These results provide important experimental support for the recent theoretical explanation for why DCS is dominantly sensitive to RBC diffusive motion. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Hydrogen-bonding recognition-induced aggregation of gold nanoparticles for the determination of the migration of melamine monomers using dynamic light scattering.

Science.gov (United States)

Wu, Long; Chen, Kun; Lu, Zhicheng; Li, Tingting; Shao, Kang; Shao, Feng; Han, Heyou

2014-10-03

The migration of melamine monomers from food contact materials has aroused particular attention since the 2008 melamine-tainted milk scandal in China. However, the determination of melamine monomer's migratory quantity (MMMQ) has remained an open question because of the complex sample pretreatment and the low sensitivity. Based on the hydrogen bonding interaction between DNA thymine and melamine, this paper described a simple and rapid method focusing on the measurement of MMMQ from melamine tableware by gold nanoparticles (GNPs) and dynamic light scattering (DLS). With the presence of probe DNA (p-DNA), the GNPs were stable in NaCl solution (0.06 M), whereas they became aggregated when the p-DNA hybridized with melamine. The change in the hydrodynamic diameter of GNPs could be detected by DLS technology. Under the optimal conditions, the average diameter increased linearly with the concentration of melamine over the range from 5.0 to 320.0 μg L(-1), and showed a detection limit of 2.0 μg L(-1) (3σ/slope). The MMMQ was investigated within a range from 6.00×10(-4) to 2.58×10(-1) mg dm(-2) (n≥3) in four different food simulants at different temperatures and time points. The results suggest that the DLS method has great potential in the analysis of the migration of melamine monomers. Copyright © 2014 Elsevier B.V. All rights reserved.

Colorimetric and dynamic light scattering detection of DNA sequences by using positively charged gold nanospheres: a comparative study with gold nanorods

Science.gov (United States)

Pylaev, T. E.; Khanadeev, V. A.; Khlebtsov, B. N.; Dykman, L. A.; Bogatyrev, V. A.; Khlebtsov, N. G.

2011-07-01

We introduce a new genosensing approach employing CTAB (cetyltrimethylammonium bromide)-coated positively charged colloidal gold nanoparticles (GNPs) to detect target DNA sequences by using absorption spectroscopy and dynamic light scattering. The approach is compared with a previously reported method employing unmodified CTAB-coated gold nanorods (GNRs). Both approaches are based on the observation that whereas the addition of probe and target ssDNA to CTAB-coated particles results in particle aggregation, no aggregation is observed after addition of probe and nontarget DNA sequences. Our goal was to compare the feasibility and sensitivity of both methods. A 21-mer ssDNA from the human immunodeficiency virus type 1 HIV-1 U5 long terminal repeat (LTR) sequence and a 23-mer ssDNA from the Bacillus anthracis cryptic protein and protective antigen precursor (pagA) genes were used as ssDNA models. In the case of GNRs, unexpectedly, the colorimetric test failed with perfect cigar-like particles but could be performed with dumbbell and dog-bone rods. By contrast, our approach with cationic CTAB-coated GNPs is easy to implement and possesses excellent feasibility with retention of comparable sensitivity—a 0.1 nM concentration of target cDNA can be detected with the naked eye and 10 pM by dynamic light scattering (DLS) measurements. The specificity of our method is illustrated by successful DLS detection of one-three base mismatches in cDNA sequences for both DNA models. These results suggest that the cationic GNPs and DLS can be used for genosensing under optimal DNA hybridization conditions without any chemical modifications of the particle surface with ssDNA molecules and signal amplification. Finally, we discuss a more than two-three-order difference in the reported estimations of the detection sensitivity of colorimetric methods (0.1 to 10-100 pM) to show that the existing aggregation models are inconsistent with the detection limits of about 0.1-1 pM DNA and that

CONTIN XPCS: Software for Inverse Transform Analysis of X-Ray Photon Correlation Spectroscopy Dynamics.

Science.gov (United States)

Andrews, Ross N; Narayanan, Suresh; Zhang, Fan; Kuzmenko, Ivan; Ilavsky, Jan

2018-02-01

X-ray photon correlation spectroscopy (XPCS) and dynamic light scattering (DLS) both reveal dynamics using coherent scattering, but X-rays permit investigating of dynamics in a much more diverse array of materials. Heterogeneous dynamics occur in many such materials, and we showed how classic tools employed in analysis of heterogeneous DLS dynamics extend to XPCS, revealing additional information that conventional Kohlrausch exponential fitting obscures. This work presents the software implementation of inverse transform analysis of XPCS data called CONTIN XPCS, an extension of traditional CONTIN that accommodates dynamics encountered in equilibrium XPCS measurements.

Quantitative imaging of cerebral blood flow velocity and intracellular motility using dynamic light scattering-optical coherence tomography.

Science.gov (United States)

Lee, Jonghwan; Radhakrishnan, Harsha; Wu, Weicheng; Daneshmand, Ali; Climov, Mihail; Ayata, Cenk; Boas, David A

2013-06-01

This paper describes a novel optical method for label-free quantitative imaging of cerebral blood flow (CBF) and intracellular motility (IM) in the rodent cerebral cortex. This method is based on a technique that integrates dynamic light scattering (DLS) and optical coherence tomography (OCT), named DLS-OCT. The technique measures both the axial and transverse velocities of CBF, whereas conventional Doppler OCT measures only the axial one. In addition, the technique produces a three-dimensional map of the diffusion coefficient quantifying nontranslational motions. In the DLS-OCT diffusion map, we observed high-diffusion spots, whose locations highly correspond to neuronal cell bodies and whose diffusion coefficient agreed with that of the motion of intracellular organelles reported in vitro in the literature. Therefore, the present method has enabled, for the first time to our knowledge, label-free imaging of the diffusion-like motion of intracellular organelles in vivo. As an example application, we used the method to monitor CBF and IM during a brief ischemic stroke, where we observed an induced persistent reduction in IM despite the recovery of CBF after stroke. This result supports that the IM measured in this study represent the cellular energy metabolism-related active motion of intracellular organelles rather than free diffusion of intracellular macromolecules.

Total internal reflection and dynamic light scattering microscopy of gels

Science.gov (United States)

Gregor, Brian F.

Two different techniques which apply optical microscopy in novel ways to the study of biological systems and materials were built and applied to several samples. The first is a system for adapting the well-known technique of dynamic light scattering (DLS) to an optical microscope. This can detect and scatter light from very small volumes, as compared to standard DLS which studies light scattering from volumes 1000x larger. The small scattering volume also allows for the observation of nonergodic dynamics in appropriate samples. Porcine gastric mucin (PGM) forms a gel at low pH which lines the epithelial cell layer and acts as a protective barrier against the acidic stomach environment. The dynamics and microscopic viscosity of PGM at different pH levels is studied using polystyrene microspheres as tracer particles. The microscopic viscosity and microrheological properties of the commercial basement membrane Matrigel are also studied with this instrument. Matrigel is frequently used to culture cells and its properties remain poorly determined. Well-characterized and purely synthetic Matrigel substitutes will need to have the correct rheological and morphological characteristics. The second instrument designed and built is a microscope which uses an interferometry technique to achieve an improvement in resolution 2.5x better in one dimension than the Abbe diffraction limit. The technique is based upon the interference of the evanescent field generated on the surface of a prism by a laser in a total internal reflection geometry. The enhanced resolution is demonstrated with fluorescent samples. Additionally. Raman imaging microscopy is demonstrated using the evanescent field in resonant and non-resonant samples, although attempts at applying the enhanced resolution technique to the Raman images were ultimately unsuccessful. Applications of this instrument include high resolution imaging of cell membranes and macroscopic structures in gels and proteins. Finally, a third

Dynamic light scattering of nano-gels of xanthan gum biopolymer in colloidal dispersion

Directory of Open Access Journals (Sweden)

Abbas Rahdar

2016-09-01

Full Text Available The dynamical properties of nanogels of xanthan gum (XG with hydrodynamic radius controlled in a size range from 5 nm to 35 nm, were studied at the different XG concentrations in water/sodium bis-2-ethylhexyl-sulfosuccinate (AOT/decane reverse micelles (RMs vs. mass fraction of nano-droplet (MFD at W = 40, using dynamic light scattering (DLS. The diffusion study of nanometer-sized droplets by DLS technique indicated that enhancing concentration of the XG polysaccharide resulted in exchanging the attractive interaction between nano-gels to repulsive interaction, as the mass fraction of nano-droplets increased. The reorientation time (τr of water nanodroplets decreased with MFD for water-in-oil AOT micro-emulsion comprising high concentration (0.0000625 of XG. On the other hand, decreasing concentration of biopolymer led to increasing the rotational correlation time of water nanodroplets with MFD. In conclusion, a single relaxation curve was observed for AOT inverse microemulsions containing different XG concentrations. Furthermore, the interaction between nanogels was changed from attractive to repulsive versus concentration of XG in the AOT RMs.

Spin-Echo Small Angle Neutron Scattering analysis of liposomes and bacteria

Science.gov (United States)

van Heijkamp, Léon F.; Sevcenco, Ana-Maria; Abou, Diane; van Luik, Remko; Krijger, Gerard C.; Hagedoorn, Peter-Leon; de Schepper, Ignatz M.; Wolterbeek, Bert; Koning, Gerben A.; Bouwman, Wim G.

2010-10-01

Two types of liposomes, commonly used in drug delivery studies, and E. coli bacteria, all prepared in H2O, were resuspended in D2O and measured with Small Angle Spin-Echo Neutron Scattering (SESANS). Modeling was performed using correlation functions for solid spheres and hollow spheres. The signal strength and curve shape were more indicative of hollow particles, indicating that the H2O-D2O exchange occurred too fast to be observed with the available time resolution. Fitting the particle diameter and membrane thickness of the hollow sphere model to the data, gave results which were in good agreement with Dynamic Light Scattering (DLS) data and literature, showing as a proof-of-principle that SESANS is able to investigate such systems. SESANS may become a good alternative to conventional tritium studies or a tool with which to study intracellular vesicle transport phenomena, with possible in vivo applications. Calculations show that a substantial change in numbers of a mixed system of small and large biological particles should be observable. A possible application is the destruction by external means of great numbers of liposomes in the presence of tumor cells for triggered drug release in cancer treatment. Since SESANS is both non-invasive and non-destructive and can handle relatively thick samples, it could be a useful addition to more conventional techniques.

Structural evaluation of an amyloid fibril model using small-angle x-ray scattering

Science.gov (United States)

Dahal, Eshan; Choi, Mina; Alam, Nadia; Bhirde, Ashwinkumar A.; Beaucage, Serge L.; Badano, Aldo

2017-08-01

Amyloid fibrils are highly structured protein aggregates associated with a wide range of diseases including Alzheimer’s and Parkinson’s. We report a structural investigation of an amyloid fibril model prepared from a commonly used plasma protein (bovine serum albumin (BSA)) using small-angle x-ray scattering (SAXS) technique. As a reference, the size estimates from SAXS are compared to dynamic light scattering (DLS) data and the presence of amyloid-like fibrils is confirmed using Congo red absorbance assay. Our SAXS results consistently show the structural transformation of BSA from spheroid to rod-like elongated structures during the fibril formation process. We observe the elongation of fibrils over two months with fibril length growing from 35.9  ±  3.0 nm to 51.5  ±  2.1 nm. Structurally metastable fibrils with distinct SAXS profiles have been identified. As proof of concept, we demonstrate the use of such distinct SAXS profiles to detect fibrils in the mixture solutions of two species by estimating their volume fractions. This easily detectable and well-characterized amyloid fibril model from BSA can be readily used as a control or standard reference to further investigate SAXS applications in the detection of structurally diverse amyloid fibrils associated with protein aggregation diseases.

Combined scanning probe and light scattering characterization of multi-stage self-assembly of targeted liposome-based delivery systems

International Nuclear Information System (INIS)

Farkas, N; Dagata, J A; Yang, C; Rait, A; Pirollo, K F; Chang, E H

2011-01-01

The mean size and size distribution of a targeted nanoparticle delivery system (NDS) strongly influences the intrinsic stability and functionality of this molecular complex, affects its performance as a systemic drug delivery platform and ultimately determines its efficacy toward early detection and treatment of cancer. Since its components undergo significant reorganization during multiple stages of self-assembly, it is essential to monitor the size and stability of the complex throughout the NDS formulation in order to ensure its potency and manufacturability prior to entering clinical trials. This work combines scanning probe microscopy (SPM) and dynamic light scattering (DLS) techniques to obtain quantitative and reliable size measurements of the NDS, and to investigate how variations in the NDS formulation or self-assembly process impact the size, structure and functionality of the complex with various therapeutic and diagnostic agent payloads. These combined SPM and DLS methods, when implemented at an early stage of the NDS formulation, present a potential measurement approach to facilitate drug discovery and development, optimization and quality control during manufacturing of the NDS

New Programs Utilizing Light Scattering and Flow Imaging Techniques for Macromolecular Crystal Growth and Fluid Dynamics Studies

Science.gov (United States)

2003-01-01

Dr. Phil Segre, a physicist by training, is a recent addition to the Biotech group, SD46, having joined NASA in August of 2000. Over the past two years he has been developing a laboratory for the study of macromolecular and protein crystal growth. The main apparatus for this work is a Dynamic Light Scattering apparatus, DLS, which is capable of making highly precise measurements of size distributions of both protein solutions and protein crystals. With Drs. Chernov and Thomas (USRA), he has begun a collaboration studying the affects of protein impurities on protein crystal growth and subsequent crystal quality. One of the hypotheses behind the differences between Earth and space grown protein crystals is that the absorption of harmful impurities is reduced in space due to the absence of convective flows. Using DLS measurements we are examining crystal growth with varying amounts of impurities and testing whether there is a strong physical basis behind this hypothesis. With Dr. Joe Ng of UAH he has been collaborating on a project to examine the folding/unfolding dynamics of large RNA complexes. A detailed understanding of this process is necessary for the handling of RNA in biotech applications, and the DLS instrument gives details and results beyond that of other instruments. With Prof. Jim McClymer of the University of Maine (summer faculty visitor to NASA in 2001, 2002), we have been studying the crystallization process in model colloidal suspensions whose behavior in some cases can mimic that of much smaller protein solutions. An understanding of the self-assembly of colloids is the first step in the process of engineering novel materials for photonic and light switching applications. Finally, he has begun an investigation into the physics of particle sedimentation. In addition to the DLS instrument he also has an instrument (called PIV) that can measure flow fields of fluids. The applications are to the dynamics of protein crystal motions both on earth and in

Core-size regulated aggregation/disaggregation of citrate-coated gold nanoparticles (5-50 nm) and dissolved organic matter: Extinction, emission, and scattering evidence

Science.gov (United States)

Esfahani, Milad Rabbani; Pallem, Vasanta L.; Stretz, Holly A.; Wells, Martha J. M.

2018-01-01

Knowledge of the interactions between gold nanoparticles (GNPs) and dissolved organic matter (DOM) is significant in the development of detection devices for environmental sensing, studies of environmental fate and transport, and advances in antifouling water treatment membranes. The specific objective of this research was to spectroscopically investigate the fundamental interactions between citrate-stabilized gold nanoparticles (CT-GNPs) and DOM. Studies indicated that 30 and 50 nm diameter GNPs promoted disaggregation of the DOM. This result-disaggregation of an environmentally important polyelectrolyte-will be quite useful regarding antifouling properties in water treatment and water-based sensing applications. Furthermore, resonance Rayleigh scattering results showed significant enhancement in the UV range which can be useful to characterize DOM and can be exploited as an analytical tool to better sense and improve our comprehension of nanomaterial interactions with environmental systems. CT-GNPs having core size diameters of 5, 10, 30, and 50 nm were studied in the absence and presence of added DOM at 2 and 8 ppm at low ionic strength and near neutral pH (6.0-6.5) approximating surface water conditions. Interactions were monitored by cross-interpretation among ultraviolet (UV)-visible extinction spectroscopy, excitation-emission matrix (EEM) spectroscopy (emission and Rayleigh scattering), and dynamic light scattering (DLS). This comprehensive combination of spectroscopic analyses lends new insights into the antifouling behavior of GNPs. The CT-GNP-5 and -10 controls emitted light and aggregated. In contrast, the CT-GNP-30 and CT-GNP-50 controls scattered light intensely, but did not aggregate and did not emit light. The presence of any CT-GNP did not affect the extinction spectra of DOM, and the presence of DOM did not affect the extinction spectra of the CT-GNPs. The emission spectra (visible range) differed only slightly between calculated and actual

Core–Shell Structure and Aggregation Number of Micelles Composed of Amphiphilic Block Copolymers and Amphiphilic Heterografted Polymer Brushes Determined by Small-Angle X-ray Scattering

Energy Technology Data Exchange (ETDEWEB)

Szymusiak, Magdalena; Kalkowski, Joseph; Luo, Hanying; Donovan, Alexander J.; Zhang, Pin; Liu, Chang; Shang, Weifeng; Irving, Thomas; Herrera-Alonso, Margarita; Liu, Ying (JHU); (IIT); (UIC)

2017-08-31

A large group of functional nanomaterials employed in biomedical applications, including targeted drug delivery, relies on amphiphilic polymers to encapsulate therapeutic payloads via self-assembly processes. Knowledge of the micelle structures will provide critical insights into design of polymeric drug delivery systems. Core–shell micelles composed of linear diblock copolymers poly(ethylene glycol)-b-poly(caprolactone) (PEG-b-PCL), poly(ethylene oxide)-b-poly(lactic acid) (PEG-b-PLA), as well as a heterografted brush consisting of a poly(glycidyl methacrylate) backbone with PEG and PLA branches (PGMA-g-PEG/PLA) were characterized by dynamic light scattering (DLS) and small-angle X-ray scattering (SAXS) measurements to gain structural information regarding the particle morphology, core–shell size, and aggregation number. The structural information at this quasi-equilibrium state can also be used as a reference when studying the kinetics of polymer micellization.

Core–Shell Structure and Aggregation Number of Micelles Composed of Amphiphilic Block Copolymers and Amphiphilic Heterografted Polymer Brushes Determined by Small-Angle X-ray Scattering

Energy Technology Data Exchange (ETDEWEB)

Szymusiak, Magdalena [Department; Kalkowski, Joseph [Department; Luo, Hanying [Department; Donovan, Alexander J. [Department; Zhang, Pin [Department; Liu, Chang [Department; Shang, Weifeng [Department; Irving, Thomas [Department; Herrera-Alonso, Margarita [Department; Liu, Ying [Department; Department

2017-08-16

A large group of functional nanomaterials employed in biomedical applications, including targeted drug delivery, relies on amphiphilic polymers to encapsulate therapeutic payloads via self-assembly processes. Knowledge of the micelle structures will provide critical insights into design of polymeric drug delivery systems. Core–shell micelles composed of linear diblock copolymers poly(ethylene glycol)-b-poly(caprolactone) (PEG-b-PCL), poly(ethylene oxide)-b-poly(lactic acid) (PEG-b-PLA), as well as a heterografted brush consisting of a poly(glycidyl methacrylate) backbone with PEG and PLA branches (PGMA-g-PEG/PLA) were characterized by dynamic light scattering (DLS) and small-angle X-ray scattering (SAXS) measurements to gain structural information regarding the particle morphology, core–shell size, and aggregation number. The structural information at this quasi-equilibrium state can also be used as a reference when studying the kinetics of polymer micellization.

Amorphous Calcium Phosphate Formation and Aggregation Process Revealed by Light Scattering Techniques

Directory of Open Access Journals (Sweden)

Vida Čadež

2018-06-01

Full Text Available Amorphous calcium phosphate (ACP attracts attention as a precursor of crystalline calcium phosphates (CaPs formation in vitro and in vivo as well as due to its excellent biological properties. Its formation can be considered to be an aggregation process. Although aggregation of ACP is of interest for both gaining a fundamental understanding of biominerals formation and in the synthesis of novel materials, it has still not been investigated in detail. In this work, the ACP aggregation was followed by two widely applied techniques suitable for following nanoparticles aggregation in general: dynamic light scattering (DLS and laser diffraction (LD. In addition, the ACP formation was followed by potentiometric measurements and formed precipitates were characterized by Fourier transform infrared spectroscopy (FTIR, powder X-ray diffraction (PXRD, transmission electron microscopy (TEM, and atomic force microscopy (AFM. The results showed that aggregation of ACP particles is a process which from the earliest stages simultaneously takes place at wide length scales, from nanometers to micrometers, leading to a highly polydisperse precipitation system, with polydispersity and vol. % of larger aggregates increasing with concentration. Obtained results provide insight into developing a way of regulating ACP and consequently CaP formation by controlling aggregation on the scale of interest.

Scattering and multiple scattering in disordered materials

International Nuclear Information System (INIS)

Weaver, R.L.; Butler, W.H.

1992-01-01

The papers in this section were presented at a joint session of symposium V on Applications of Multiple Scattering Theory and of Symposium P on Disordered Systems. They show that the ideas of scattering theory can help us to understand a very broad class of phenomena

Quantitative characterization of gold nanoparticles by field-flow fractionation coupled online with light scattering detection and inductively coupled plasma mass spectrometry.

Science.gov (United States)

Schmidt, Bjørn; Loeschner, Katrin; Hadrup, Niels; Mortensen, Alicja; Sloth, Jens J; Koch, Christian Bender; Larsen, Erik H

2011-04-01

An analytical platform coupling asymmetric flow field-flow fractionation (AF(4)) with multiangle light scattering (MALS), dynamic light scattering (DLS), and inductively coupled plasma mass spectrometry (ICPMS) was established and used for separation and quantitative determination of size and mass concentration of nanoparticles (NPs) in aqueous suspension. Mixtures of three polystyrene (PS) NPs between 20 and 100 nm in diameter and mixtures of three gold (Au) NPs between 10 and 60 nm in diameter were separated by AF(4). The geometric diameters of the separated PS NPs and the hydrodynamic diameters of the Au and PS NPs were determined online by MALS and DLS, respectively. The three separated Au NPs were quantified by ICPMS and recovered at 50-95% of the injected masses, which ranged between approximately 8-80 ng of each nanoparticle size. Au NPs adhering to the membrane in the separation channel was found to be a major cause for incomplete recoveries. The lower limit of detection (LOD) ranged between 0.02 ng Au and 0.4 ng Au, with increasing LOD by increasing nanoparticle diameter. The analytical platform was applied to characterization of Au NPs in livers of rats, which were dosed with 10 nm, 60 nm, or a mixture of 10 and 60 nm nanoparticles by intravenous injection. The homogenized livers were solubilized in tetramethylammonium hydroxide (TMAH), and the recovery of Au NPs from the livers amounted to 86-123% of their total Au content. In spite of successful stabilization with bovine serum albumin even in alkaline medium, separation of the Au NPs by AF(4) was not possible due to association with undissolved remains of the alkali-treated liver tissues as demonstrated by electron microscopy images.

Validity of Dynamic Light Scattering Method to Analyze a Range of Gold and Copper Nanoparticle Sizes Attained by Solids Laser Ablation in Liquid

Directory of Open Access Journals (Sweden)

Yu. V. Golubenko

2014-01-01

Full Text Available Nanoparticles of metals possess a whole series of features, concerned with it’s sizes, this leads to appearing or unusual electromagnetic and optical properties, which are untypical for particulates.An extended method of receiving nanoparticles by means of laser radiation is pulse laser ablation of hard targets in liquid medium.Varying the parameters of laser radiation, such as wavelength of laser radiation, energy density, etc., we can operate the size and shape of the resultant particles.The greatest trend of application in medicine have the nanoparticles of iron, copper, silver, silicon, magnesium, gold and zinc.The subject matter in this work is nanoparticles of copper and gold, received by means of laser ablation of hard targets in liquid medium.The aim of exploration, represented in the article, is the estimation of application of the dynamic light scattering method for determination of the range of nanoparticles sizes in the colloidal solution.For studying of the laser ablation process was chosen the second harmonic of Nd:YAG laser with the wavelength of 532 nm. Special attention was spared for the description of the experiment technique of receiving of nanoparticles.As the liquid medium ethanol and distillation water were used.For exploration of the received colloidal system have been used the next methods: DLS, transmission electron microscopy (TEM and scanning electron microscopy (SEM.The results of measuring by DLS method showed that colloidal solution of the copper in the ethanol is the steady system. Copper nanoparticle’s size reaches 200 nm and is staying in the same size for some time.Received system from the gold’s nanoparticles is polydisperse, unsteady and has a big range of the nanoparticle’s sizes. This fact was confirmed by means of photos, got from the TEM FEI Tecnai G2F20 + GIF and SEM Helios NanoLab 660. The range of the gold nanoparticle’s sizes is from 5 to 60 nm. So, it has been proved that the DLS method is

Micellar aggregates of amylose-block-polystyrene rod-coil block copolymers in water and THF

NARCIS (Netherlands)

Loos, Katja; Böker, Alexander; Zettl, Heiko; Zhang, Mingfu; Krausch, Georg; Müller, Axel H.E.; Boker, A.; Zhang, A.F.

2005-01-01

Amylose-block-polystyrenes with various block copolymer compositions were investigated in water and in THF solution. Fluorescence correlation spectroscopy, dynamic light, scattering (DLS), and asymmetric flow field-flow fractionation with multiangle light scattering detection indicate the presence

Gelation mechanism of poly(N-isopropylacrylamide)-clay nanocomposite hydrogels synthesized by photopolymerization.

Science.gov (United States)

Ferse, Bernhard; Richter, Sven; Eckert, Franziska; Kulkarni, Amit; Papadakis, Christine M; Arndt, Karl-Friedrich

2008-11-04

The gelation process of poly-(N-isopropylacrylamide)-clay nanocomposite hydrogels (PNIPAAm-clay NC gels) was investigated by dynamic and static light scattering (DLS and SLS), as well as by fluorescence correlation spectroscopy (FCS). The photopolymerization method chosen for the radical polymerizing system ensured that, when the irradiation is removed, the reaction stopped immediately. Experiments showed that shortly before the gelation threshold is reached, no changes in the DLS autocorrelation functions appear, while the monomer conversion can be observed by 1H NMR spectroscopy. These results correspond to the formation of microparticles, in which the PNIPAAm chains are closely attached to the clay platelets. During the further polymerization process, clay clusters are developed before the sol-gel threshold is reached. FCS measurements were performed to obtain information on the motion of the clay platelets inside the NC gel. The DLS method gives only an average of the motions in the gel. In a time window between 10 micros and 1 s, the clay sheets labeled with Rhodamine B show no characteristic motions.

Study of dithiol monolayer as the interface for controlled deposition of gold nanoparticles

International Nuclear Information System (INIS)

Cichomski, M.; Tomaszewska, E.; Kosla, K.; Kozlowski, W.; Kowalczyk, P.J.; Grobelny, J.

2011-01-01

Self-assembled monolayer of dithiol molecules, deposited on polycrystalline Au (111), prepared at room atmosphere, was studied using scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). Dithiols were used as interface, which chemically bonds to the deposited gold nanoparticles through strong covalent bonds. The size and size distribution of the deposited nanoparticles were measured using dynamic light scattering (DLS), scanning electron microscopy (SEM) and atomic force microscopy (AFM). The AFM results showed that nanoparticles are immobilized and stable during scanning procedure and do not contaminate the AFM tip. The size of monodisperse nanoparticles obtained from the DLS measurements is slightly higher than that obtained from the AFM and SEM measurements. This is due to the fact that the DLS measures the hydrodynamic radius, dependent on the protective chemical layer on nanoparticles. - Research Highlights: → Dithiols molecules create chemically bounded layers on a Au (111) surface. → Gold nanoparticles can be chemically bounded to a self-assembled monolayer. → Nanoparticles are stable during AFM probe interactions.

A didactic experiment showing the Compton scattering by means of a clinical gamma camera.

Science.gov (United States)

Amato, Ernesto; Auditore, Lucrezia; Campennì, Alfredo; Minutoli, Fabio; Cucinotta, Mariapaola; Sindoni, Alessandro; Baldari, Sergio

2017-06-01

We describe a didactic approach aimed to explain the effect of Compton scattering in nuclear medicine imaging, exploiting the comparison of a didactic experiment with a gamma camera with the outcomes from a Monte Carlo simulation of the same experimental apparatus. We employed a 99m Tc source emitting 140.5keV photons, collimated in the upper direction through two pinholes, shielded by 6mm of lead. An aluminium cylinder was placed on the source at 50mm of distance. The energy of the scattered photons was measured on the spectra acquired by the gamma camera. We observed that the gamma ray energy measured at each step of rotation gradually decreased from the characteristic energy of 140.5keV at 0° to 102.5keV at 120°. A comparison between the obtained data and the expected results from the Compton formula and from the Monte Carlo simulation revealed a full agreement within the experimental error (relative errors between -0.56% and 1.19%), given by the energy resolution of the gamma camera. Also the electron rest mass has been evaluated satisfactorily. The experiment was found useful in explaining nuclear medicine residents the phenomenology of the Compton scattering and its importance in the nuclear medicine imaging, and it can be profitably proposed during the training of medical physics residents as well. Copyright © 2017 Associazione Italiana di Fisica Medica. Published by Elsevier Ltd. All rights reserved.

Structure of insoluble immune complexes as studied by spectroturbidimetry and dynamic light scattering

Science.gov (United States)

Khlebtsov, Boris N.; Burygin, Gennadii L.; Matora, Larisa Y.; Shchyogolev, Sergei Y.; Khlebtsov, Nikolai G.

2004-07-01

We describe two variants of a method for determining the average composition of insoluble immune complex particles (IICP). The first variant is based on measuring the specific turbidity (the turbidity per unit mass concentration of the dispersed substance) and the average size of IICP determined from dynamic light scattering (DLS). In the second variant, the wavelength exponent (i.e., the slope of the logarithmic turbidity spectrum) is used in combination with specific turbidity measurements. Both variants allow the average biopolymer volume fraction to be determined in terms of the average refractive index of IICP. The method is exemplified by two experimental antigen+antibody systems: (i) lipopolysaccharide-protein complex (LPPC) of Azospirillum brasilense Sp245+rabbit anti-LPPC; and (ii) human IgG (hIgG)+sheep anti-hIgG. Our measurements by the two methods for both types of systems gave, on the average, the same result: the volume fraction of the IICP biopolymers is about 30%; accordingly, the volume fraction of buffer solvent is 70%.

Trichoderma koningii assisted biogenic synthesis of silver nanoparticles and evaluation of their antibacterial activity

Science.gov (United States)

Tripathi, R. M.; Gupta, Rohit Kumar; Shrivastav, Archana; Singh, M. P.; Shrivastav, B. R.; Singh, Priti

2013-09-01

The present study demonstrates the biosynthesis of silver nanoparticles using Trichoderma koningii and evaluation of their antibacterial activity. Trichoderma koningii secretes proteins and enzymes that act as reducing and capping agent. The biosynthesized silver nanoparticles (AgNPs) were characterized by UV-Vis spectroscopy, dynamic light scattering (DLS), transmission electron microscopy (TEM) and x-ray diffraction (XRD). UV-Vis spectra showed absorbance peak at 413 nm corresponding to the surface plasmon resonance of silver nanoparticles. DLS was used to find out the size distribution profile. The size and morphology of the AgNPs was determined by TEM, which shows the formation of spherical nanoparticles in the size range of 8-24 nm. X-ray diffraction showed intense peaks corresponding to the crystalline silver. The antibacterial activity of biosynthesized AgNPs was evaluated by growth curve and inhibition zone and it was found that the AgNPs show potential effective antibacterial activity.

Polymeric nanoparticles stabilized by surfactants investigated by light scattering, small-angle neutron scattering, and Cryo-TEM methods

Czech Academy of Sciences Publication Activity Database

Pánek, Jiří; Filippov, Sergey K.; Koňák, Čestmír; Nallet, F.; Noirez, L.; Karlsson, G.; Štěpánek, Petr

2011-01-01

Roč. 32, č. 6 (2011), s. 888-897 ISSN 0193-2691 R&D Projects: GA ČR GA202/09/2078 Institutional research plan: CEZ:AV0Z40500505 Keywords : Cryo-TEM * DLS * nanoparticles Subject RIV: BO - Biophysics Impact factor: 0.560, year: 2011

Inverse Transformation: Unleashing Spatially Heterogeneous Dynamics with an Alternative Approach to XPCS Data Analysis.

Science.gov (United States)

Andrews, Ross N; Narayanan, Suresh; Zhang, Fan; Kuzmenko, Ivan; Ilavsky, Jan

2018-02-01

X-ray photon correlation spectroscopy (XPCS), an extension of dynamic light scattering (DLS) in the X-ray regime, detects temporal intensity fluctuations of coherent speckles and provides scattering vector-dependent sample dynamics at length scales smaller than DLS. The penetrating power of X-rays enables probing dynamics in a broad array of materials with XPCS, including polymers, glasses and metal alloys, where attempts to describe the dynamics with a simple exponential fit usually fails. In these cases, the prevailing XPCS data analysis approach employs stretched or compressed exponential decay functions (Kohlrausch functions), which implicitly assume homogeneous dynamics. In this paper, we propose an alternative analysis scheme based upon inverse Laplace or Gaussian transformation for elucidating heterogeneous distributions of dynamic time scales in XPCS, an approach analogous to the CONTIN algorithm widely accepted in the analysis of DLS from polydisperse and multimodal systems. Using XPCS data measured from colloidal gels, we demonstrate the inverse transform approach reveals hidden multimodal dynamics in materials, unleashing the full potential of XPCS.

Surface Modification of Magnetic Nanoparticles Using Gum Arabic

International Nuclear Information System (INIS)

Williams, Darryl N.; Gold, Katie A.; Holoman, Tracey R. Pulliam; Ehrman, Sheryl H.; Wilson, Otto C.

2006-01-01

Magnetite nanoparticles were synthesized and functionalized by coating the particle surfaces with gum arabic (GA) to improve particle stability in aqueous suspensions (i.e. biological media). Particle characterization was performed using transmission electron microscopy (TEM) and dynamic light scattering (DLS) to analyze the morphology and quantify the size distribution of the nanoparticles, respectively. The results from DLS indicated that the GA-treated nanoparticles formed smaller agglomerates as compared to the untreated samples over a 30-h time frame. Thermogravimetric analyses indicated an average weight loss of 23%, showing that GA has a strong affinity toward the iron oxide surface. GA most likely contributes to colloid stability via steric stabilization. It was determined that the adsorption of GA onto magnetite exhibits Langmuir behavior

Power law relation between particle concentrations and their sizes in the blood plasma

International Nuclear Information System (INIS)

Kirichenko, M N; Chaikov, L L; Zaritskii, A R

2016-01-01

This work is devoted to the investigation of sizes and concentrations of particles in blood plasma by dynamic light scattering (DLS). Blood plasma contains many different proteins and their aggregates, microparticles and vesicles. Their sizes, concentrations and shapes can give information about donor's health. Our DLS study of blood plasma reveals unexpected dependence: with increasing of the particle sizes r (from 1 nm up to 1 μm), their concentrations decrease as r -4 (almost by 12 orders). We found also that such dependence was repeated for model solution of fibrinogen and thrombin with power coefficient is -3,6. We believe that this relation is a fundamental law of nature that shows interaction of proteins (and other substances) in biological liquids. (paper)

Time-reversal of electromagnetic scattering for small scatterer classification

International Nuclear Information System (INIS)

Smith, J Torquil; Berryman, James G

2012-01-01

Time-reversal operators, or the alternatively labelled, but equivalent, multistatic response matrix methods, are used to show how to determine the number of scatterers present in an electromagnetic scattering scenario that might be typical of UneXploded Ordinance (UXO) detection, classification and removal applications. Because the nature of the target UXO application differs from that of many other common inversion problems, emphasis is placed here on classification and enumeration rather than on detailed imaging. The main technical issues necessarily revolve around showing that it is possible to find a sufficient number of constraints via multiple measurements (i.e. using several distinct views at the target site) to solve the enumeration problem. The main results show that five measurements with antenna pairs are generally adequate to solve the classification and enumeration problems. However, these results also demonstrate a need for decreasing noise levels in the multistatic matrix as the number n of scatterers increases for the intended practical applications of the method. (paper)

Formation of double layers: shocklike solutions of an mKdV-equation

International Nuclear Information System (INIS)

Raadu, M.A.; Chanteur, G.

1985-10-01

Small amplitude double layers (DLs) in a plasma with a suitable electron distribution may be identified with shocklike solutions of a modified Korteweg-deVries (mKdV) equation. A thought experiment for the formation of such DLs is specified to clarify the physical constraints and to demonstrate the emergence of a DL from an initial disturbance. A scattering formulation of the mKdV initial value problem may be diagonalised to give a pair of Schroedinger equations with a scattering potential satisfying the ordinary KdV equation. The initial value problem can then be treated using Khruslov's generalisation of the inverse scattering method which allows a difference in the asymptotic values of the potential. A necessary and sufficient condition for the emergence of a shocklike soliton (wave) train and of a finite number of isolated solitons may also be determined from the scattering properties of the initial potential. With 26 refs and 5 figures. (Author)

Trichoderma koningii assisted biogenic synthesis of silver nanoparticles and evaluation of their antibacterial activity

International Nuclear Information System (INIS)

Tripathi, R M; Shrivastav, Archana; Gupta, Rohit Kumar; Singh, M P; Shrivastav, B R; Singh, Priti

2013-01-01

The present study demonstrates the biosynthesis of silver nanoparticles using Trichoderma koningii and evaluation of their antibacterial activity. Trichoderma koningii secretes proteins and enzymes that act as reducing and capping agent. The biosynthesized silver nanoparticles (AgNPs) were characterized by UV–Vis spectroscopy, dynamic light scattering (DLS), transmission electron microscopy (TEM) and x-ray diffraction (XRD). UV–Vis spectra showed absorbance peak at 413 nm corresponding to the surface plasmon resonance of silver nanoparticles. DLS was used to find out the size distribution profile. The size and morphology of the AgNPs was determined by TEM, which shows the formation of spherical nanoparticles in the size range of 8–24 nm. X-ray diffraction showed intense peaks corresponding to the crystalline silver. The antibacterial activity of biosynthesized AgNPs was evaluated by growth curve and inhibition zone and it was found that the AgNPs show potential effective antibacterial activity. (paper)

Possible role of double scattering in electron-atom scattering in a laser field

International Nuclear Information System (INIS)

Rabadan, I.; Mendez, L.; Dickinson, A.S.

1996-01-01

By considering observations of double-scattering effects in the excitation of the 2 1 P level of He, gas density values estimated for the laser-assisted elastic scattering experiments of Wallbank and Holmes (1993, 1994a,b) for which the Kroll-Watson approximation appears to fail. Using comparable densities for He and lower densities for Ar, and assuming the Kroll-Watson approximation for single-scattering events, differential cross sections are calculated including double scattering for laser-assisted scattering for a range of energies and scattering angles. Comparison with the observed values shows that double-scattering effects can give a semi-quantitative explanation of the apparent breakdown of the Kroll-Watson approximation in both He and Ar. (author)

Small angle neutron scattering and small angle X-ray scattering ...

Indian Academy of Sciences (India)

Abstract. The morphology of carbon nanofoam samples comprising platinum nanopar- ticles dispersed in the matrix was characterized by small angle neutron scattering (SANS) and small angle X-ray scattering (SAXS) techniques. Results show that the structure of pores of carbon matrix exhibits a mass (pore) fractal nature ...

Chaotic scattering and quantum dynamics

International Nuclear Information System (INIS)

Doron, Eyal.

1992-11-01

The main concern of this thesis is the application of the semiclassical approximation to quantum chaotic scattering systems. We deal with two separate, although interconnected, subjects. The first subject dealt with is the semiclassical characterization of the fluctuations of the S matrix. A particular important parameter is the magnetic field B, and we show how the correlation length and line shape of S matrix elements under a change of B may be derived. An effect which is present in many physical wave systems is absorption of energy flux. We show how absorption affects both the reflectivity and the scattering phase and time delay of a scattering system. In the second part of the thesis, we show how the formalism and results obtained from chaotic scattering can be applied to the investigation of closed chaotic systems, and in particular to chaotic billiards. The semiclassical expansion for billiards is presented. In the last part of the thesis we deal with the statistics of S matrices of chaotic scattering systems. The main message of this work is that scattering matrix, and its classical counterpart the Poincare Scattering Map can be used to yield a powerful formulation of the quantum mechanical dynamics of bounded systems. (author)

Neutron scattering shows a droplet of oleic acid at the center of the BAMLET complex.

Science.gov (United States)

Rath, Emma M; Duff, Anthony P; Gilbert, Elliot P; Doherty, Greg; Knott, Robert B; Church, W Bret

2017-07-01

The anti-cancer complex, Bovine Alpha-lactalbumin Made LEthal to Tumors (BAMLET), has intriguing broad-spectrum anti-cancer activity. Although aspects of BAMLET's anti-cancer mechanism are still not known, it is understood that it involves the oleic acid or oleate component of BAMLET being preferentially released into cancer cell membranes leading to increased membrane permeability and lysis. The structure of the protein component of BAMLET has previously been elucidated by small angle X-ray scattering (SAXS) to be partially unfolded and dramatically enlarged. However, the structure of the oleic acid component of BAMLET and its disposition with respect to the protein component was not revealed as oleic acid has the same X-ray scattering length density (SLD) as water. Employing the difference in the neutron SLDs of hydrogen and deuterium, we carried out solvent contrast variation small angle neutron scattering (SANS) experiments of hydrogenated BAMLET in deuterated water buffers, to reveal the size, shape, and disposition of the oleic acid component of BAMLET. Our resulting analysis and models generated from SANS and SAXS data indicate that oleic acid forms a spherical droplet of oil incompletely encapsulated by the partially unfolded protein component. This model provides insight into the anti-cancer mechanism of this cache of lipid. The model also reveals a protein component "tail" not associated with the oleic acid component that is able to interact with the tail of other BAMLET molecules, providing a plausible explanation of how BAMLET readily forms aggregates. Proteins 2017; 85:1371-1378. © 2017 Wiley Periodicals, Inc. © 2017 Wiley Periodicals, Inc.

Decoupling single nanowire mobilities limited by surface scattering and bulk impurity scattering

International Nuclear Information System (INIS)

Khanal, D. R.; Levander, A. X.; Wu, J.; Yu, K. M.; Liliental-Weber, Z.; Walukiewicz, W.; Grandal, J.; Sanchez-Garcia, M. A.; Calleja, E.

2011-01-01

We demonstrate the isolation of two free carrier scattering mechanisms as a function of radial band bending in InN nanowires via universal mobility analysis, where effective carrier mobility is measured as a function of effective electric field in a nanowire field-effect transistor. Our results show that Coulomb scattering limits effective mobility at most effective fields, while surface roughness scattering only limits mobility under very high internal electric fields. High-energy α particle irradiation is used to vary the ionized donor concentration, and the observed decrease in mobility and increase in donor concentration are compared to Hall effect results of high-quality InN thin films. Our results show that for nanowires with relatively high doping and large diameters, controlling Coulomb scattering from ionized dopants should be given precedence over surface engineering when seeking to maximize nanowire mobility.

Surface-Enhanced Raman Scattering Nanoparticles as Optical Labels for Imaging Cell Surface Proteins

Science.gov (United States)

MacLaughlin, Christina M.

Assaying the expression of cell surface proteins has widespread application for characterizing cell type, developmental stage, and monitoring disease transformation. Immunophenotyping is conducted by treating cells with labelled targeting moieties that have high affinity for relevant surface protein(s). The sensitivity and specificity of immunophenotyping is defined by the choice of contrast agent and therefore, the number of resolvable signals that can be used to simultaneously label cells. Narrow band width surface-enhanced Raman scattering (SERS) nanoparticles are proposed as optical labels for multiplexed immunophenotying. Two types of surface coatings were investigated to passivate the gold nanoparticles, incorporate SERS functionality, and to facilitate attachment of targeting antibodies. Thiolated poly(ethylene glycol) forms dative bonds with the gold surface and is compatible with multiple physisorbed Raman-active reporter molecules. Ternary lipid bilayers are used to encapsulate the gold nanoparticles particles, and incorporate three different classes of Raman reporters. TEM, UV-Visible absorbance spectroscopy, DLS, and electrophoretic light scattering were used characterize the particle coating. Colourimetric protein assay, and secondary antibody labelling were used to quantify the antibody conjugation. Three different in vitromodels were used to investigate the binding efficacy and specificity of SERS labels for their biomarker targets. Primary human CLL cells, LY10 B lymphoma, and A549 adenocarcinoma lines were targeted. Dark field imaging was used to visualize the colocalization of SERS labels with cells, and evidence of receptor clustering was obtained based on colour shifts of the particles' Rayleigh scattering. Widefield, and spatially-resolved Raman spectra were used to detect labels singly, and in combination from labelled cells. Fluorescence flow cytometry was used to test the particles' binding specificity, and SERS from labelled cells was also

Cross plane scattering correction

International Nuclear Information System (INIS)

Shao, L.; Karp, J.S.

1990-01-01

Most previous scattering correction techniques for PET are based on assumptions made for a single transaxial plane and are independent of axial variations. These techniques will incorrectly estimate the scattering fraction for volumetric PET imaging systems since they do not take the cross-plane scattering into account. In this paper, the authors propose a new point source scattering deconvolution method (2-D). The cross-plane scattering is incorporated into the algorithm by modeling a scattering point source function. In the model, the scattering dependence both on axial and transaxial directions is reflected in the exponential fitting parameters and these parameters are directly estimated from a limited number of measured point response functions. The authors' results comparing the standard in-plane point source deconvolution to the authors' cross-plane source deconvolution show that for a small source, the former technique overestimates the scatter fraction in the plane of the source and underestimate the scatter fraction in adjacent planes. In addition, the authors also propose a simple approximation technique for deconvolution

Effects of Near Infrared Radiation on DNA. DLS and ATR-FTIR Study

Science.gov (United States)

Szymborska-Małek, Katarzyna; Komorowska, Małgorzata; Gąsior-Głogowska, Marlena

2018-01-01

We presume that the primary effect of Near Infrared (NIR) radiation on aqueous solutions of biological molecules concerns modification of hydrogen bonded structures mainly the global and the hydration shell water molecules. Since water has a significant influence on the DNA structure, we expect that the thermal stability of DNA could be modified by NIR radiation. The herring sperm DNA was exposed to NIR radiation (700-1100 nm) for 5, 10, and 20 min periods. The temperature dependent infrared measurements were done for the thin films formed on the diamond ATR crystal from evaporated DNA solutions exposed and unexposed to NIR radiation. For the NIR-treated samples (at room temperature) the B form was better conserved than in the control sample independently of the irradiation period. Above 50 °C a considerable increase in the A form was only observed for 10 min NIR exposed samples. The hydrodynamic radius, (Rh), studied by the dynamic light scattering, showed drastic decrease with the increasing irradiation time. Principal components analysis (PCA) allowed to detect the spectral features correlated with the NIR effect and thermal stability of the DNA films. Obtained results strongly support the idea that the photoionization of water by NIR radiation in presence of DNA molecules is the main factor influencing on its physicochemical properties.

New noninvasive index for evaluation of the vascular age of healthy and sick people

Science.gov (United States)

Fine, Ilya; Kuznik, Boris I.; Kaminsky, Alexander V.; Shenkman, Louis; Kustovsjya, Evgeniya M.; Maximova, Olga G.

2012-08-01

We conducted a study on 861 healthy and sick subjects and demonstrated that some calculated parameters based on measurement of the dynamic light scattering (DLS) signal from the finger correlate highly with chronological age ranging from 1.5 to 85 years old. Measurements of DLS signals were obtained during both occlusion and nonocclusion of blood flow in the finger. For the nonocclusion case we found that the low-frequency component of the DLS signal significantly correlates with the biological age while the high-frequency component of the DLS signal resembles the arterial pulse-wave and does correlate with age. However, the most prominent correlation between the DLS characteristics and age was noted with the stasis stage measurements. We propose that the observed age-related phenomena are caused by alterations in local blood viscosity and interactions of the endothelial cells with erythrocytes. Further, a new noninvasive index based on the age-related optical characteristics was introduced. This noninvasive index may be used as a research and diagnostic tool to examine the endothelial and thrombolytic properties of the vascular system.

Effect of Nitric Acid Concentrations on Synthesis and Stability of Maghemite Nanoparticles Suspension

Directory of Open Access Journals (Sweden)

Irwan Nurdin

2014-01-01

Full Text Available Maghemite (γ-Fe2O3 nanoparticles have been synthesized using a chemical coprecipitation method at different nitric acid concentrations as an oxidizing agent. Characterization of all samples performed by several techniques including X-ray diffraction (XRD, transmission electron microscopy (TEM, alternating gradient magnetometry (AGM, thermogravimetric analysis (TGA, dynamic light scattering (DLS, and zeta potential. The XRD patterns confirmed that the particles were maghemite. The crystallite size of all samples decreases with the increasing concentration of nitric acid. TEM observation showed that the particles have spherical morphology with narrow particle size distribution. The particles showed superparamagnetic behavior with decreased magnetization values at the increasing concentration of nitric acid. TGA measurement showed that the stability temperature decreases with the increasing concentration of nitric acid. DLS measurement showed that the hydrodynamic particle sizes decrease with the increasing concentration of nitric acid. Zeta potential values show a decrease with the increasing concentration of nitric acid. The increasing concentration of nitric acid in synthesis of maghemite nanoparticles produced smaller size particles, lower magnetization, better thermal stability, and more stable maghemite nanoparticles suspension.

Recent activity of international comparison for nanoparticle size measurement

Science.gov (United States)

Takahashi, Kayori; Takahata, Keiji; Misumi, Ichiko; Sugawara, Kentaro; Gonda, Satoshi; Ehara, Kensei

2014-08-01

Nanoparticle sizing is the most fundamental measurement for producing nanomaterials, evaluation of nanostructure, and the risk assessment of nanomaterials for human health. Dynamic light scattering (DLS) is widely used as a useful and convenient technique for determining nanoparticle size in liquid; however, the precision of this technique has been unclear. Some international comparisons are now in progress to verify the measurement accuracy of nanoparticle sizing, as a typical example of Asia Pacific Metrology Programme Supplementary Comparison. In this study, we evaluated the precision of DLS technique for nanoparticle sizing and estimated the uncertainty of the DLS data for polystyrene latex suspensions. The extrapolations of apparent diffusion coefficients to infinite dilution and to lower angles yielded more precise values than those obtained at one angle and one concentration. The extrapolated particle size measured by DLS was compared to the size determined by differential mobility analyzer (DMA), atomic force microscopy (AFM), and scanning electron microscopy (SEM). Before the comparison, the intensity-averaged size measured by DLS was recalculated to the number-averaged size, and the thickness of water layer attaching on the surface of particles were added into uncertainty of particle sizing by DLS. After the recalculation, the consistent values of mean particle diameter were obtained between those by DLS and by DMA, AFM, and SEM within the estimated uncertainties.

Quantitative characterization of nanoparticle agglomeration within biological media

International Nuclear Information System (INIS)

Hondow, Nicole; Brydson, Rik; Wang, Peiyi; Holton, Mark D.; Brown, M. Rowan; Rees, Paul; Summers, Huw D.; Brown, Andy

2012-01-01

Quantitative analysis of nanoparticle dispersion state within biological media is essential to understanding cellular uptake and the roles of diffusion, sedimentation, and endocytosis in determining nanoparticle dose. The dispersion of polymer-coated CdTe/ZnS quantum dots in water and cell growth medium with and without fetal bovine serum was analyzed by transmission electron microscopy (TEM) and dynamic light scattering (DLS) techniques. Characterization by TEM of samples prepared by plunge freezing the blotted solutions into liquid ethane was sensitive to the dispersion state of the quantum dots and enabled measurement of agglomerate size distributions even in the presence of serum proteins where DLS failed. In addition, TEM showed a reduced packing fraction of quantum dots per agglomerate when dispersed in biological media and serum compared to just water, highlighting the effect of interactions between the media, serum proteins, and the quantum dots. The identification of a heterogeneous distribution of quantum dots and quantum dot agglomerates in cell growth medium and serum by TEM will enable correlation with the previously reported optical metrology of in vitro cellular uptake of this quantum dot dispersion. In this paper, we present a comparative study of TEM and DLS and show that plunge-freeze TEM provides a robust assessment of nanoparticle agglomeration state.

Measurement of dispersion of nanoparticles in a dense suspension by high-sensitivity low-coherence dynamic light scattering

Science.gov (United States)

Ishii, Katsuhiro; Nakamura, Sohichiro; Sato, Yuki

2014-08-01

High-sensitivity low-coherence DLS apply to measurement of particle size distribution of pigments suspended in a ink. This method can be apply to extremely dense and turbid media without dilution. We show the temporal variation of particle size distribution of thixotropy and sedimentary pigments due to aggregation, agglomerate, and sedimentation. Moreover, we demonstrate the influence of dilution of ink to particle size distribution.

Toward a new polyethylene scattering law determined using inelastic neutron scattering

International Nuclear Information System (INIS)

Lavelle, C.M.; Liu, C.-Y.; Stone, M.B.

2013-01-01

Monte Carlo neutron transport codes such as MCNP rely on accurate data for nuclear physics cross-sections to produce accurate results. At low energy, this takes the form of scattering laws based on the dynamic structure factor, S(Q,E). High density polyethylene (HDPE) is frequently employed as a neutron moderator at both high and low temperatures, however the only cross-sections available are for ambient temperatures (∼300K), and the evaluation has not been updated in quite some time. In this paper we describe inelastic neutron scattering measurements on HDPE at 5 and 294 K which are used to improve the scattering law for HDPE. We review some of the past HDPE scattering laws, describe the experimental methods, and compare computations using these models to the measured S(Q,E). The total cross-section is compared to available data, and the treatment of the carbon secondary scatterer as a free gas is assessed. We also discuss the use of the measurement itself as a scattering law via the one phonon approximation. We show that a scattering law computed using a more detailed model for the Generalized Density of States (GDOS) compares more favorably to this experiment, suggesting that inelastic neutron scattering can play an important role in both the development and validation of new scattering laws for Monte Carlo work. -- Highlights: ► Polyethylene at 5 K and 300 K is measured using inelastic neutron scattering (INS). ► Measurements conducted at the Wide Angular-Range Chopper Spectrometer at SNS. ► Several models for Polyethylene are compared to measurements. ► Improvements to existing models for the polyethylene scattering law are suggested. ► INS is shown to be highly valuable tool for scattering law development

Innovative scattering analysis shows that hydrophobic disordered proteins are expanded in water

Energy Technology Data Exchange (ETDEWEB)

Riback, Joshua A.; Bowman, Micayla A.; Zmyslowski, Adam M.; Knoverek, Catherine R.; Jumper, John M.; Hinshaw, James R.; Kaye, Emily B.; Freed, Karl F.; Clark, Patricia L.; Sosnick, Tobin R.

2017-10-12

A substantial fraction of the proteome is intrinsically disordered, and even well-folded proteins adopt non-native geometries during synthesis, folding, transport, and turnover. Characterization of intrinsically disordered proteins (IDPs) is challenging, in part because of a lack of accurate physical models and the difficulty of interpreting experimental results. We have developed a general method to extract the dimensions and solvent quality (self-interactions) of IDPs from a single small-angle x-ray scattering measurement. We applied this procedure to a variety of IDPs and found that even IDPs with low net charge and high hydrophobicity remain highly expanded in water, contrary to the general expectation that protein-like sequences collapse in water. Our results suggest that the unfolded state of most foldable sequences is expanded; we conjecture that this property was selected by evolution to minimize misfolding and aggregation.

Zeta potential and Raman studies of PVP capped Bi2S3 nanoparticles synthesized by polyol method

Science.gov (United States)

Tarachand, Sathe, Vasant G.; Okram, Gunadhor S.

2018-05-01

Here we report the synthesis and characterisation of polyvinylpyrrolidone (PVP) capped Bi2S3 nanoparticles via one step catalyst-free polyol method. Raman spectroscopy, dynamic light scattering and zeta potential analysis were performed on it. Rietveld refinement of powder XRD of PVP capped samples confirmed the formation of single phase orthorhombic Bi2S3 for all PVP capped samples. The presence of eight obvious Raman modes further confirmed the formation of stoichiometric Bi2S3. Dynamic light scattering (DLS) studies show a clear increase in hydrodynamic diameter for samples made with increasing PVP concentration. Particle size obtained from DLS and XRD (using Scherrer's formula) combine with change in full width half maxima of Raman modes collectively suggest overall improvement in crystallinity and quality of product on introducing PVP. In zeta potential (ζ) measurement, steric hindrance of carbon chains plays very crucial role and a systematic reduction of ζ value is observed for samples made with decreasing PVP concentration. An isoelectric point is obtained for sample made with low PVP (1g). Present results are likely to open a window for its medical and catalytic applications.

Preparation of nanogels by radiation-induced cross-linking of interpolymer complexes of poly (acrylic acid) with poly (vinyl pyrrolidone) in aqueous medium

Science.gov (United States)

Ghaffarlou, Mohammadreza; Sütekin, S. Duygu; Güven, Olgun

2018-01-01

Functional nanogels were prepared from interpolymer complexes (IPC) of poly (vinyl pyrrolidone) and poly (acrylic acid) by gamma irradiation of their aqueous solutions. The coil size of IPCs prepared under different experimental conditions (polymer molecular weight, concentration, mixing ratios, pH and temperature) were measured by Dynamic Light Scattering (DLS) technique prior to irradiation. At relatively low absorbed doses of 5 and 10 kGy, IPC nanogels with a range of 30-250 nm diameters, -12 to -28 mV zeta potentials and polydispersities lower than 0.17 were obtained. The sizes of the nanogels were found to be smaller than the size of the precursor IPC coil sizes (40-300 nm) due to the formation of intra-chain crosslinks. Thus a recipe of preparing multifunctional nanogels with double amphiphilic properties carrying polyacidic and nonionic polymer structures with the range of above listed properties has been developed. These nanogels show narrow size distribution and high colloidal stability increasing their potential to be used as biocompatible drug carriers with controlled-release properties. PVP-PAA IPC nanogels were characterized by dynamic light scattering (DLS), atomic force microscopy (AFM) and scanning electron microscopy (SEM) techniques.

Neuronal uptake and intracellular superoxide scavenging of a fullerene (C60)-poly(2-oxazoline)s nanoformulation

KAUST Repository

Tong, Jing; Zimmerman, Matthew C.; Li, Shumin; Yi, Xiang; Luxenhofer, Robert; Jordan, Rainer; Kabanov, Alexander V.

2011-01-01

and random copolymer to form nano-complexes. These C(60)-polymer complexes were characterized by UV-vis spectroscopy, infrared spectroscopy (IR), dynamic light scattering (DLS), atomic force microscopy (AFM) and transmission electron microscopy (TEM

Influence of synthesis conditions on particle morphology of ...

Indian Academy of Sciences (India)

Wintec

diffraction (XRD), scanning electron microscopy (SEM), and dynamic light scattering (DLS). Cu/ZnO ... Considerable attention has been paid to copper metal nano- particles .... And also energy dispersive scanning (EDS) analyses of sample ...

NanoCrystalline Cellulose isolated from oil palm empty fruit bunch and its potential in cadmium metal removal

Directory of Open Access Journals (Sweden)

Lim Yong Hui

2016-01-01

Full Text Available NanoCrystalline Cellulose (NCC was isolated via ultrasonic cavitation assisted acid hydrolysis method. Characterization was done using Dynamic Light Scattering (DLS together with Scanning Electron Microscope (SEM imaging to double prove the existence of NCC. DLS measures length of 236.6 nm with width of 34.40 nm, supported by SEM which showed NCC a rod-like shaped particle with large surface area and high porosity. It was then attempted for heavy metal cadmium ion (Cd2+ removal from aqueous solution. The pH implication to the rate of Cd2+ adsorption was investigated by varying the solution to pH 4, pH 7 and pH 10 over a duration of 120 minutes. The removal efficiency was analyzed using Atomic Absorption Spectroscopy (AAS resulting in pH 7 being the most favorable for Cd2+ removal.

Quantifying the blue shift in the light absorption of small gold nanoparticles

International Nuclear Information System (INIS)

Tsekov, Roumen; Georgiev, Peter; Simeonova, Silviya; Balashev, Konstantin

2017-01-01

The dependence of the surface plasmons resonance (SPR) frequency on the size of gold nanoparticles (GNPs) is experimentally studied. The measured data for the SPR frequency by UV-Vis spectroscopy and GNPs diameter by Dynamic Light Scattering (DLS), Transmission Electron Microscopy (TEM) and Atomic Force Microscopy (AFM) are collected in the course of classical citrate GNPs synthesis. The relationship between the GNPs size and the blue shift of the light absorption is presented. They are fitted by an equation with a single free parameter, the dielectric permittivity of the surrounding media. Thus, the refractive index of the surrounding media is determined, which characterizes the GNPs surface shell. Key words: Gold nanoparticles (GNPs), Surface plasmon resonance (SPR), Dynamic Light Scattering (DLS), Transmission Electron Microscopy (TEM), Atomic Force Microscopy (AFM)

Application of the weighted total field-scattering field technique to 3D-PSTD light scattering model

Science.gov (United States)

Hu, Shuai; Gao, Taichang; Liu, Lei; Li, Hao; Chen, Ming; Yang, Bo

2018-04-01

PSTD (Pseudo Spectral Time Domain) is an excellent model for the light scattering simulation of nonspherical aerosol particles. However, due to the particularity of its discretization form of the Maxwell's equations, the traditional Total Field/Scattering Field (TF/SF) technique for FDTD (Finite Differential Time Domain) is not applicable to PSTD, and the time-consuming pure scattering field technique is mainly applied to introduce the incident wave. To this end, the weighted TF/SF technique proposed by X. Gao is generalized and applied to the 3D-PSTD scattering model. Using this technique, the incident light can be effectively introduced by modifying the electromagnetic components in an inserted connecting region between the total field and the scattering field region with incident terms, where the incident terms are obtained by weighting the incident field by a window function. To optimally determine the thickness of connection region and the window function type for PSTD calculations, their influence on the modeling accuracy is firstly analyzed. To further verify the effectiveness and advantages of the weighted TF/SF technique, the improved PSTD model is validated against the PSTD model equipped with pure scattering field technique in both calculation accuracy and efficiency. The results show that, the performance of PSTD seems to be not sensitive to variation of window functions. The number of the connection layer required decreases with the increasing of spatial resolution, where for spatial resolution of 24 grids per wavelength, a 6-layer region is thick enough. The scattering phase matrices and integral scattering parameters obtained by the improved PSTD show an excellent consistency with those well-tested models for spherical and nonspherical particles, illustrating that the weighted TF/SF technique can introduce the incident precisely. The weighted TF/SF technique shows higher computational efficiency than pure scattering technique.

Intermediate energy nucleon-deuteron scattering theory.

Science.gov (United States)

Wilson, J. W.

1973-01-01

Sloan's conclusion (1969) that terms of the multiple-scattering series beyond single scattering contribute only to S- and P-wave amplitudes in an S-wave separable model is examined. A comparison of experiments with the calculation at 146 MeV shows that the conclusion is valid in nucleon-deuteron scattering applications.

Virtual neutron scattering experiments

DEFF Research Database (Denmark)

Overgaard, Julie Hougaard; Bruun, Jesper; May, Michael

2017-01-01

. In the last week of the course, students travel to a large-scale neutron scattering facility to perform real neutron scattering experiments. Through student interviews and survey answers, we argue, that the virtual training prepares the students to engage more fruitfully with experiments by letting them focus......We describe how virtual experiments can be utilized in a learning design that prepares students for hands-on experiments at large-scale facilities. We illustrate the design by showing how virtual experiments are used at the Niels Bohr Institute in a master level course on neutron scattering...

Quantum Optical Multiple Scattering

DEFF Research Database (Denmark)

Ott, Johan Raunkjær

. In the first part we use a scattering-matrix formalism combined with results from random-matrix theory to investigate the interference of quantum optical states on a multiple scattering medium. We investigate a single realization of a scattering medium thereby showing that it is possible to create entangled...... states by interference of squeezed beams. Mixing photon states on the single realization also shows that quantum interference naturally arises by interfering quantum states. We further investigate the ensemble averaged transmission properties of the quantized light and see that the induced quantum...... interference survives even after disorder averaging. The quantum interference manifests itself through increased photon correlations. Furthermore, the theoretical description of a measurement procedure is presented. In this work we relate the noise power spectrum of the total transmitted or reflected light...

Λ scattering equations

Science.gov (United States)

Gomez, Humberto

2016-06-01

The CHY representation of scattering amplitudes is based on integrals over the moduli space of a punctured sphere. We replace the punctured sphere by a double-cover version. The resulting scattering equations depend on a parameter Λ controlling the opening of a branch cut. The new representation of scattering amplitudes possesses an enhanced redundancy which can be used to fix, modulo branches, the location of four punctures while promoting Λ to a variable. Via residue theorems we show how CHY formulas break up into sums of products of smaller (off-shell) ones times a propagator. This leads to a powerful way of evaluating CHY integrals of generic rational functions, which we call the Λ algorithm.

The interrelationship between ligand binding and thermal unfolding of the folate binding protein. The role of self-association and pH

DEFF Research Database (Denmark)

Holm, Jan; Babol, Linnea N.; Markova, Natalia

2014-01-01

The present study utilized a combination of DLS (dynamic light scattering) and DSC (differential scanning calorimetry) to address thermostability of high-affinity folate binding protein (FBP), a transport protein and cellular receptor for the vitamin folate. At pH7.4 (pI=7-8) ligand binding......, intermolecular forces involved in concentration-dependent multimerization thus contribute to the thermostability of holo-FBP. Hence, thermal unfolding and dissociation of holo-FBP multimers occur simultaneously consistent with a gradual decrease from octameric to monomeric holo-FBP (10μM) in DLS after a step-wise...

Newtonian versus black-hole scattering

International Nuclear Information System (INIS)

Siopsis, G.

1999-01-01

We discuss non-relativistic scattering by a Newtonian potential. We show that the gray-body factors associated with scattering by a black hole exhibit the same functional dependence as scattering amplitudes in the Newtonian limit, which should be the weak-field limit of any quantum theory of gravity. This behavior arises independently of the presence of supersymmetry. The connection to two-dimensional conformal field theory is also discussed. copyright 1999 The American Physical Society

Thermal-neutron multiple scattering: critical double scattering

International Nuclear Information System (INIS)

Holm, W.A.

1976-01-01

A quantum mechanical formulation for multiple scattering of thermal-neutrons from macroscopic targets is presented and applied to single and double scattering. Critical nuclear scattering from liquids and critical magnetic scattering from ferromagnets are treated in detail in the quasielastic approximation for target systems slightly above their critical points. Numerical estimates are made of the double scattering contribution to the critical magnetic cross section using relevant parameters from actual experiments performed on various ferromagnets. The effect is to alter the usual Lorentzian line shape dependence on neutron wave vector transfer. Comparison with corresponding deviations in line shape resulting from the use of Fisher's modified form of the Ornstein-Zernike spin correlations within the framework of single scattering theory leads to values for the critical exponent eta of the modified correlations which reproduce the effect of double scattering. In addition, it is shown that by restricting the range of applicability of the multiple scattering theory from the outset to critical scattering, Glauber's high energy approximation can be used to provide a much simpler and more powerful description of multiple scattering effects. When sufficiently close to the critical point, it provides a closed form expression for the differential cross section which includes all orders of scattering and has the same form as the single scattering cross section with a modified exponent for the wave vector transfer

Light Scatter in Optical Materials: Advanced Haze Modeling

Science.gov (United States)

2017-03-31

contrast sensitivity with glare. This study measured angular scatter in the test articles , and showed that the cumulative (total) scatter beyond...Sample under laser illumination for angular scatter measurements ................................4  Figure 3: Scatter measurement system at a small...scatter effects image quality , visual performance and user acceptance. The purpose of the present effort was to develop a computational model that

Retrieval method of aerosol extinction coefficient profile based on backscattering, side-scattering and Raman-scattering lidar

Science.gov (United States)

Shan, Huihui; Zhang, Hui; Liu, Junjian; Tao, Zongming; Wang, Shenhao; Ma, Xiaomin; Zhou, Pucheng; Yao, Ling; Liu, Dong; Xie, Chenbo; Wang, Yingjian

2018-03-01

Aerosol extinction coefficient profile is an essential parameter for atmospheric radiation model. It is difficult to get higher signal to noise ratio (SNR) of backscattering lidar from the ground to the tropopause especially in near range. Higher SNR problem can be solved by combining side-scattering and backscattering lidar. Using Raman-scattering lidar, aerosol extinction to backscatter ratio (lidar ratio) can be got. Based on side-scattering, backscattering and Raman-scattering lidar system, aerosol extinction coefficient is retrieved precisely from the earth's surface to the tropopause. Case studies show this method is reasonable and feasible.

An empirical correction for moderate multiple scattering in super-heterodyne light scattering.

Science.gov (United States)

Botin, Denis; Mapa, Ludmila Marotta; Schweinfurth, Holger; Sieber, Bastian; Wittenberg, Christopher; Palberg, Thomas

2017-05-28

Frequency domain super-heterodyne laser light scattering is utilized in a low angle integral measurement configuration to determine flow and diffusion in charged sphere suspensions showing moderate to strong multiple scattering. We introduce an empirical correction to subtract the multiple scattering background and isolate the singly scattered light. We demonstrate the excellent feasibility of this simple approach for turbid suspensions of transmittance T ≥ 0.4. We study the particle concentration dependence of the electro-kinetic mobility in low salt aqueous suspension over an extended concentration regime and observe a maximum at intermediate concentrations. We further use our scheme for measurements of the self-diffusion coefficients in the fluid samples in the absence or presence of shear, as well as in polycrystalline samples during crystallization and coarsening. We discuss the scope and limits of our approach as well as possible future applications.

Compton scatter tomography in TOF-PET

Science.gov (United States)

Hemmati, Hamidreza; Kamali-Asl, Alireza; Ay, Mohammadreza; Ghafarian, Pardis

2017-10-01

Scatter coincidences contain hidden information about the activity distribution on the positron emission tomography (PET) imaging system. However, in conventional reconstruction, the scattered data cause the blurring of images and thus are estimated and subtracted from detected coincidences. List mode format provides a new aspect to use time of flight (TOF) and energy information of each coincidence in the reconstruction process. In this study, a novel approach is proposed to reconstruct activity distribution using the scattered data in the PET system. For each single scattering coincidence, a scattering angle can be determined by the recorded energy of the detected photons, and then possible locations of scattering can be calculated based on the scattering angle. Geometry equations show that these sites lie on two arcs in 2D mode or the surface of a prolate spheroid in 3D mode, passing through the pair of detector elements. The proposed method uses a novel and flexible technique to estimate source origin locations from the possible scattering locations, using the TOF information. Evaluations were based on a Monte-Carlo simulation of uniform and non-uniform phantoms at different resolutions of time and detector energy. The results show that although the energy uncertainties deteriorate the image spatial resolution in the proposed method, the time resolution has more impact on image quality than the energy resolution. With progress of the TOF system, the reconstruction using the scattered data can be used in a complementary manner, or to improve image quality in the next generation of PET systems.

Pion scattering from very light nuclei

International Nuclear Information System (INIS)

Berman, B.

1993-01-01

Selected recent elastic and inelastic pion-scattering experiments on 3 H, 3 He, and 4 He will be reviewed. Particular attention will be given to multinucleon or cluster aspects of the data, and to possible comparisons with electron-scattering results. From elastic scattering from 3 H and 3 He at forward angles, one can extract the matter distribution of the paired neutrons in 3 H as well as that of the paired protons in 3 He. At backward angles, scattering from correlated nucleon pairs and/or two-step processes play an important role. For inelastic scattering, the momentum-transfer dependence of the cross section varies strongly with incident energy. Elastic scattering from a polarized 3 He target shows a strong asymmetry near 90 degrees. Elastic scattering from 4 He yields results which cannot be fitted with a simple optical model. An for inelastic scattering from 4 He, analysis of the data requires an important contribution from direct triton knockout

High-Throughput Quantification of Nanoparticle Degradation Using Computational Microscopy and Its Application to Drug Delivery Nanocapsules

KAUST Repository

Ray, Aniruddha; Li, Shuoran; Segura, Tatiana; Ozcan, Aydogan

2017-01-01

, current methods rely on estimating the size of the particles at discrete points over time using, for example, electron microscopy or dynamic light scattering (DLS), among other techniques, all of which have drawbacks and practical limitations. There is a

Spin observables in inelastic proton-nucleus scattering at intermediate energy

International Nuclear Information System (INIS)

Smith, R.D.

1984-01-01

This dissertation is a study of spin observables in inelastic proton-nucleus reactions for incident proton energies near 1 GeV. At this energy, the dominant reaction mechanisms are (1) quasi-free knockout of one or more nucleons, and (2) pion production through the Δ resonance. The cross section due to quasi-free knockout can be reasonably well understood theoretically in a multiple scattering picture, which uses measured NN amplitudes as input. Calculations of this sort were carried out in reference [10] using scalar NN amplitudes parameterized as Gaussians. The author has extended this picture to include spin dependent NN amplitudes. This allows calculation of all the spin observables, Ay, DLL, DSS, DNN, DLS, and DSL, as well as the cross section dsigma/dOmegadp due to quasi-free knockout of one or more particles. The cross section and polarization Ay have been measured at the LAMPF High Resolution Spectrometer at T/sub L/ = 800 MeV on 12 C. The theoretical results agree well with the data in the quasi-free region. The results for the remaining spin observables provide predictions for experiments which can be performed at LAMPF. By comparing the calculations with the data, it may be possible to separate the contribution due to a quasi-free knockout, and see a signature of quasi-free Δ production in the spin observables

The equivalent square concept for the head scatter factor based on scatter from flattening filter

Energy Technology Data Exchange (ETDEWEB)

Kim, Siyong; Palta, Jatinder R.; Zhu, Timothy C. [Department of Radiation Oncology, University of Florida College of Medicine, Gainesville, Florida (United States)

1998-06-01

The equivalent field relationship between square and circular fields for the head scatter factor was evaluated at the source plane. The method was based on integrating the head scatter parameter for projected shaped fields in the source plane and finding a field that produced the same ratio of head scatter to primary dose on the central axis. A value of {sigma}/R{approx_equal}0.9 was obtained, where {sigma} was one-half of the side length of the equivalent square and R was the radius of the circular field. The assumptions were that the equivalent field relationship for head scatter depends primarily on the characteristics of scatter from the flattening filter, and that the differential scatter-to-primary ratio of scatter from the flattening filter decreases linearly with the radius, within the physical radius of the flattening filter. Lam and co-workers showed empirically that the area-to-perimeter ratio formula, when applied to an equivalent square formula at the flattening filter plane, gave an accurate prediction of the head scatter factor. We have analytically investigated the validity of the area-to-perimeter ratio formula. Our results support the fact that the area-to-perimeter ratio formula can also be used as the equivalent field formula for head scatter at the source plane. The equivalent field relationships for wedge and tertiary collimator scatter were also evaluated. (author)

The equivalent square concept for the head scatter factor based on scatter from flattening filter

International Nuclear Information System (INIS)

Kim, Siyong; Palta, Jatinder R.; Zhu, Timothy C.

1998-01-01

The equivalent field relationship between square and circular fields for the head scatter factor was evaluated at the source plane. The method was based on integrating the head scatter parameter for projected shaped fields in the source plane and finding a field that produced the same ratio of head scatter to primary dose on the central axis. A value of σ/R≅0.9 was obtained, where σ was one-half of the side length of the equivalent square and R was the radius of the circular field. The assumptions were that the equivalent field relationship for head scatter depends primarily on the characteristics of scatter from the flattening filter, and that the differential scatter-to-primary ratio of scatter from the flattening filter decreases linearly with the radius, within the physical radius of the flattening filter. Lam and co-workers showed empirically that the area-to-perimeter ratio formula, when applied to an equivalent square formula at the flattening filter plane, gave an accurate prediction of the head scatter factor. We have analytically investigated the validity of the area-to-perimeter ratio formula. Our results support the fact that the area-to-perimeter ratio formula can also be used as the equivalent field formula for head scatter at the source plane. The equivalent field relationships for wedge and tertiary collimator scatter were also evaluated. (author)

Scattering of light by colloidal aluminosilicate particles produces the unusual sky-blue color of Río Celeste (Tenorio volcano complex, Costa Rica.

Directory of Open Access Journals (Sweden)

Erick Castellón

Full Text Available Río Celeste (Sky-Blue River in Tenorio National Park (Costa Rica, a river that derives from the confluence and mixing of two colorless streams--Río Buenavista (Buenavista River and Quebrada Agria (Sour Creek--is renowned in Costa Rica because it presents an atypical intense sky-blue color. Although various explanations have been proposed for this unusual hue of Río Celeste, no exhaustive tests have been undertaken; the reasons hence remain unclear. To understand this color phenomenon, we examined the physico-chemical properties of Río Celeste and of the two streams from which it is derived. Chemical analysis of those streams with ion-exchange chromatography (IC and inductively coupled plasma atomic emission spectroscopy (ICP-OES made us discard the hypothesis that the origin of the hue is due to colored chemical species. Our tests revealed that the origin of this coloration phenomenon is physical, due to suspended aluminosilicate particles (with diameters distributed around 566 nm according to a lognormal distribution that produce Mie scattering. The color originates after mixing of two colorless streams because of the enlargement (by aggregation of suspended aluminosilicate particles in the Río Buenavista stream due to a decrease of pH on mixing with the acidic Quebrada Agria. We postulate a chemical mechanism for this process, supported by experimental evidence of dynamic light scattering (DLS, zeta potential measurements, X-ray diffraction and scanning electron microscopy (SEM with energy-dispersive spectra (EDS. Theoretical modeling of the Mie scattering yielded a strong coincidence between the observed color and the simulated one.

Electron-atom scattering

International Nuclear Information System (INIS)

McCarthy, I.E.

1991-07-01

The coupled-channels-optical method has been implemented using two different approximations to the optical potential. The half-on-shell optical potential involves drastic approximations for numerical feasibility but still gives a good semiquantitative description of the effect of uncoupled channels on electron scattering from hydrogen, helium and sodium. The distorted-wave optical potential makes no approximations other than the weak coupling approximation for uncoupled channels. In applications to hydrogen and sodium it shows promise of describing scattering phenomena excellently at all energies. 27 refs., 5 figs

Solution Behavior and Activity of a Halophilic Esterase under High Salt Concentration

Science.gov (United States)

Rao, Lang; Zhao, Xiubo; Pan, Fang; Li, Yin; Xue, Yanfen; Ma, Yanhe; Lu, Jian R.

2009-01-01

Background Halophiles are extremophiles that thrive in environments with very high concentrations of salt. Although the salt reliance and physiology of these extremophiles have been widely investigated, the molecular working mechanisms of their enzymes under salty conditions have been little explored. Methodology/Principal Findings A halophilic esterolytic enzyme LipC derived from archeaon Haloarcula marismortui was overexpressed from Escherichia coli BL21. The purified enzyme showed a range of hydrolytic activity towards the substrates of p-nitrophenyl esters with different alkyl chains (n = 2−16), with the highest activity being observed for p-nitrophenyl acetate, consistent with the basic character of an esterase. The optimal esterase activities were found to be at pH 9.5 and [NaCl] = 3.4 M or [KCl] = 3.0 M and at around 45°C. Interestingly, the hydrolysis activity showed a clear reversibility against changes in salt concentration. At the ambient temperature of 22°C, enzyme systems working under the optimal salt concentrations were very stable against time. Increase in temperature increased the activity but reduced its stability. Circular dichroism (CD), dynamic light scattering (DLS) and small angle neutron scattering (SANS) were deployed to determine the physical states of LipC in solution. As the salt concentration increased, DLS revealed substantial increase in aggregate sizes, but CD measurements revealed the maximal retention of the α-helical structure at the salt concentration matching the optimal activity. These observations were supported by SANS analysis that revealed the highest proportion of unimers and dimers around the optimal salt concentration, although the coexistent larger aggregates showed a trend of increasing size with salt concentration, consistent with the DLS data. Conclusions/Significance The solution α-helical structure and activity relation also matched the highest proportion of enzyme unimers and dimers. Given that

Hierarchically Ordered Supramolecular Protein-Polymer Composites with Thermoresponsive Properties

Directory of Open Access Journals (Sweden)

Salla Välimäki

2015-05-01

Full Text Available Synthetic macromolecules that can bind and co-assemble with proteins are important for the future development of biohybrid materials. Active systems are further required to create materials that can respond and change their behavior in response to external stimuli. Here we report that stimuli-responsive linear-branched diblock copolymers consisting of a cationic multivalent dendron with a linear thermoresponsive polymer tail at the focal point, can bind and complex Pyrococcus furiosus ferritin protein cages into crystalline arrays. The multivalent dendron structure utilizes cationic spermine units to bind electrostatically on the surface of the negatively charged ferritin cage and the in situ polymerized poly(di(ethylene glycol methyl ether methacrylate linear block enables control with temperature. Cloud point of the final product was determined with dynamic light scattering (DLS, and it was shown to be approximately 31 °C at a concentration of 150 mg/L. Complexation of the polymer binder and apoferritin was studied with DLS, small-angle X-ray scattering, and transmission electron microscopy, which showed the presence of crystalline arrays of ferritin cages with a face-centered cubic (fcc, \\( Fm\\overline{3}m \\ Bravais lattice where lattice parameter a = 18.6 nm. The complexation process was not temperature dependent but the final complexes had thermoresponsive characteristics with negative thermal expansion.

Sizing of colloidal particle and protein molecules in a hanging fluid drop

Science.gov (United States)

Ansari, Rafat R.; Suh, Kwang I.

1995-01-01

We report non-invasive particle size measurements of polystyrene latex colloidal particles and bovine serum albumin (BSA) protein molecules suspended in tiny hanging fluid drops of 30 micro-Liter volume using a newly designed fiber optic probe. The probe is based upon the principles of the technique of dynamic light scattering (DLS). The motivation for this work comes from growing protein crystals in outer space. Protein crystals have been grown previously in hanging drops in microgravity experiments on-board the space shuttle orbiter. However, obtaining quantitative information on nucleation and growth of the protein crystals in real time has always been a desired goal, but hitherto not achieved. Several protein researchers have shown interest in using DLS to monitor crystal growth process in a droplet, but elaborate instrumentation and optical alignment problems have made in-situ applications difficult. We demonstrate that such an experiment is now possible. Our system offers fast (5 seconds) determination of particle size, utilize safe levels of very low laser power (less than or equal to 0.2 mW), a small scattering volume (approximately 2 x 10(exp -5) cu mm) and high spatial coherence (Beta) values. This is a major step forward when compared to currently available DLS systems.

Entanglement degradation in depolarizing light scattering

International Nuclear Information System (INIS)

Aiello, A.; Woerdman, J.P.

2005-01-01

Full text: In the classical regime, when a beam of light is scattered by a medium, it may emerge partially or completely depolarized depending on the optical properties of the medium. Correspondingly, in the quantum regime, when an entangled two-photon pair is scattered, the classical depolarization may result in an entanglement degradation. Here, relations between photon scattering, entanglement and multi-mode detection are investigated. We establish a general framework in which one- and two-photon elastic scattering processes can be discussed, and we focus on the study of the intrinsic entanglement degradation caused by a multi-mode detection. We show that any multi-mode scattered state cannot maximally violate the Bell-CHSH inequality because of the momentum spread. The results presented here have general validity and can be applied to both deterministic and random scattering processes. (author)

Automatically identifying scatter in fluorescence data using robust techniques

DEFF Research Database (Denmark)

Engelen, S.; Frosch, Stina; Hubert, M.

2007-01-01

as input data for three different PARAFAC methods. Firstly inserting missing values in the scatter regions are tested, secondly an interpolation of the scatter regions is performed and finally the scatter regions are down-weighted. These results show that the PARAFAC method to choose after scatter...

Recent development in magnetic neutron scattering studies

International Nuclear Information System (INIS)

Endoh, Yasuo

1993-01-01

Neutron scattering results contain many new concepts in modern magnetism. We review here the most recent neutron magnetic scattering studies from so called '214' copper oxide lamellar materials, because a number of important developments in magnetism are condensed in this novel subject. We show that neutron scattering has played crucial role in our understanding of modern magnetism. (author)

Length scale dependence of the dynamic properties of hyaluronic acid solutions in the presence of salt.

Science.gov (United States)

Horkay, Ferenc; Falus, Peter; Hecht, Anne-Marie; Geissler, Erik

2010-12-02

In solutions of the charged semirigid biopolymer hyaluronic acid in salt-free conditions, the diffusion coefficient D(NSE) measured at high transfer momentum q by neutron spin echo is more than an order of magnitude smaller than that determined by dynamic light scattering, D(DLS). This behavior contrasts with neutral polymer solutions. With increasing salt content, D(DLS) approaches D(NSE), which is independent of ionic strength. Contrary to theoretical expectation, the ion-polymer coupling, which dominates the low q dynamics of polyelectrolyte solutions, already breaks down at distance scales greater than the Debye-Hückel length.

Scattering of high energy electrons on deuteron

International Nuclear Information System (INIS)

Grossetete, B.

1964-12-01

The aim of this work is to obtain information on the neutron form factor from the study of the scattering of electrons on deuterium. The first part is dedicated to the theoretical study of the elastic and inelastic scattering. We introduce different form factors: Sachs form factor, the Pauli and Dirac form factors, they appear in the analytic expression of the scattering cross-section. We show how the deuteron form factors can be deduced from neutron's and proton's form factors. In the case of the inelastic scattering we show how the cross section can be broken into components associated to partial waves and we obtain different formulas for the inelastic cross-section based on the Breit formula or the Durand formalism. The second part is dedicated to the experiment setting of electron scattering on deuterium. The elastic scattering experiment has been made on solid or liquid CD 2 targets while inelastic scattering has been studied on a liquid target. We have used an electron beam produced by the Orsay linear accelerator and the scattered electrons have been analysed by a magnetic spectrometer and a Cerenkov detector. The results give a very low value (slightly positive)for the charge form factor of the neutron and a magnetic form factor for the neutron slightly below that of the proton [fr

Preparation, Characterization and Antibacterial Properties of Silver ...

African Journals Online (AJOL)

electron microscopy (SEM), differential scanning calorimetry (DSC), dynamic light scattering (DLS) and laser Doppler electrophoresis (LDE). The antibacterial ... silver nanoparticles. The size of the nanoparticles can be modulated by varying both chitosan MW and process conditions such as temperature and stirring speed.

Structural transition in aqueous lipid/bile salt [DPPC/NaDC] supramolecular aggregates: SANS and DLS study

Czech Academy of Sciences Publication Activity Database

Kiselev, M. A.; Janich, M.; Hildebrand, A.; Strunz, Pavel; Neubert, R.H.H.; Lombardo, D.

2013-01-01

Roč. 424, OCT (2013), s. 93-99 ISSN 0301-0104 Institutional support: RVO:61389005 Keywords : bile salt * phospholipids * phosphatidylcholine (DPPC) * small angle neutron scattering * Vesicle-micelle transition Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 2.028, year: 2013

Preliminary Examination of X-ray Scattering from Human Tissues

International Nuclear Information System (INIS)

Desouky, O.S.; Wilkinson, S.; Hall, C.; Rogers, K.; Round, A.

2008-01-01

Small Angle x-ray scattering (SAXS) and wide angle x-ray scattering (WAXS) patterns have been recorded from different human soft tissues using x-ray synchrotron radiation.Pathological breast, normal kidney and lung tissues show SAXS peaks at q-values equal to 0.291 nm -1 and 0.481 nm -1 (d 21.6 nm and d =13. nm) which are the 3 r d and 5 t h order of the well known axial D-spacing of collagen fibrils. The diffraction is particularly intense in the meridional direction indicating some febrile alignment. In contrast, the normal tissue of brain, liver and heart shows diffuse scatter.The wide-angle coherent scattering from normal human tissues of brain, liver, heart, lung, and kidney is typical of that for amorphous materials. The scatter of the healthy adipose breast tissue shows a sharp peak at momentum transfer 1.24 nm -1 (d= 0.417 nm). The data of the other tissues appears to consist of a broad scattering peak. The two scattering regimes succeed in differentiating between the two major components of breast tissue, collagen and adipose tissue. The results of this study suggest that the soft tissues may have scattering patterns that are characteristics for the particular tissue types and tissue disease state. These results indicate that it may be possible use the coherent scattering as a diagnostic tool

Traceable size determination of nanoparticles, a comparison among European metrology institutes

International Nuclear Information System (INIS)

Meli, Felix; Klein, Tobias; Buhr, Egbert; Frase, Carl Georg; Gleber, Gudrun; Krumrey, Michael; Duta, Alexandru; Duta, Steluta; Korpelainen, Virpi; Bellotti, Roberto; Picotto, Gian Bartolo; Boyd, Robert D; Cuenat, Alexandre

2012-01-01

Within the European iMERA-Plus project ‘Traceable Characterisation of Nanoparticles’ various particle measurement procedures were developed and finally a measurement comparison for particle size was carried out among seven laboratories across six national metrology institutes. Seven high quality particle samples made from three different materials and having nominal sizes in the range from 10 to 200 nm were used. The participants applied five fundamentally different measurement methods, atomic force microscopy, dynamic light scattering (DLS), small-angle x-ray scattering, scanning electron microscopy and scanning electron microscopy in transmission mode, and provided a total of 48 independent, traceable results. The comparison reference values were determined as weighted means based on the estimated measurement uncertainties of the participants. The comparison reference values have combined standard uncertainties smaller than 1.4 nm for particles with sizes up to 100 nm. All methods, except DLS, provided consistent results. (paper)

Radiation Synthesis of Nanogel for Bioactives Immobilization

International Nuclear Information System (INIS)

Hamzah, M.Y.

2009-01-01

Both hydrophilic and hydrophobic core nanogel are currently being developed for immobilization and delivery purposes in Malaysian Nuclear Agency. Hydrophilic nanogel is produced by using inverse micelles irradiation of polyethelyne glycol diacrylate (PEGDA). The hydrophobic nanogel is produced via irradiation of acrylated form of palm oil. These nanogels will be used to immobilize bio actives such as curcumin, tyhmoquinone, oryzanol and chitosan. Preliminary investigation of the nanogel size using dynamic light scattering (DLS) shows that nanogel with sizes below 100nm can be obtained. (author)

Radiation Synthesis of Nanogel for Bioactives Immobilization

Energy Technology Data Exchange (ETDEWEB)

Hamzah, M. Y. [Polymer Modification Group, Malaysian Nuclear Agency, Bangi (Malaysia)

2009-07-01

Both hydrophilic and hydrophobic core nanogel are currently being developed for immobilization and delivery purposes in Malaysian Nuclear Agency. Hydrophilic nanogel is produced by using inverse micelles irradiation of polyethelyne glycol diacrylate (PEGDA). The hydrophobic nanogel is produced via irradiation of acrylated form of palm oil. These nanogels will be used to immobilize bio actives such as curcumin, tyhmoquinone, oryzanol and chitosan. Preliminary investigation of the nanogel size using dynamic light scattering (DLS) shows that nanogel with sizes below 100nm can be obtained. (author)

Astrophysical applications of Delbrück scattering: Dust scattered gamma radiation from gamma ray bursts

International Nuclear Information System (INIS)

Kunwar, B.; Bhadra, A.; Gupta, S.K. Sen

2014-01-01

A preliminary, and perhaps the first, study of astrophysical applications of Delbrück scattering in a gamma-ray emitting celestial object like a gamma-ray burst (GRB) has been made. At energies≥100 MeV the elastic scattering of gamma-ray photons off the molecular dust surrounding the GRB site is dominated by Delbrück scattering. Expressions for Delbrück-scattered gamma-ray flux as a function of time has been obtained for a few selected energies by assuming a simple model of GRB. These are compared with Compton-scattered flux. At certain situations, interestingly, the former is found to exceed the latter for the first few milliseconds of the burst. The issue of detectability of Delbrück-scattered gamma-ray echo from the cloud of a GRB is discussed. Although it is observed that the detection of such an echo is not within the capability of the presently operating gamma-ray missions such as Fermi LAT, a rough estimate shows that one can be optimistic that future generation gamma-ray telescopes might be able to see such photons' contribution to the total flux. - Highlights: ► Astrophysical application of Delbrück scattering in a GRB has been made. ► Initially, the Delbrück scattering may dominate the scattering of GeV γ-rays. ► The issue of detectability of such radiations is discussed

Phase object retrieval through scattering medium

Science.gov (United States)

Zhao, Ming; Zhao, Meijing; Wu, Houde; Xu, Wenhai

2018-05-01

Optical imaging through a scattering medium has been an interesting and important research topic, especially in the field of biomedical imaging. However, it is still a challenging task due to strong scattering. This paper proposes to recover the phase object behind the scattering medium from one single-shot speckle intensity image using calibrated transmission matrices (TMs). We construct the forward model as a non-linear mapping, since the intensity image loses the phase information, and then a generalized phase retrieval algorithm is employed to recover the hidden object. Moreover, we show that a phase object can be reconstructed with a small portion of the speckle image captured by the camera. The simulation is performed to demonstrate our scheme and test its performance. Finally, a real experiment is set up, we measure the TMs from the scattering medium, and then use it to reconstruct the hidden object. We show that a phase object of size 32 × 32 is retrieved from 150 × 150 speckle grains, which is only 1/50 of the speckles area. We believe our proposed method can benefit the community of imaging through the scattering medium.

One-pot green synthesis of carbon dots by using Saccharum officinarum juice for fluorescent imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae) cells

Energy Technology Data Exchange (ETDEWEB)

Mehta, Vaibhavkumar N. [Applied Chemistry Department, S. V. National Institute of Technology, Surat, 395 007 (India); Jha, Sanjay [Gujarat Agricultural Biotechnology Institute, Navsari Agricultural University, Surat, 395007 (India); Kailasa, Suresh Kumar, E-mail: sureshkumarchem@gmail.com [Applied Chemistry Department, S. V. National Institute of Technology, Surat, 395 007 (India)

2014-05-01

We are reporting highly economical plant-based hydrothermal method for one-pot green synthesis of water-dispersible fluorescent carbon dots (CDs) by using Saccharum officinarum juice as precursor. The synthesized CDs were characterized by UV-visible, fluorescence, Fourier transform infrared (FT-IR), dynamic light scattering (DLS), high-resolution transmission electron microscopic (HR-TEM), and laser scanning confocal microscopic techniques. The CDs are well dispersed in water with an average size of ∼ 3 nm and showed bright blue fluorescence under UV-light (λ{sub ex} = 365 nm). These CDs acted as excellent fluorescent probes in cellular imaging of bacteria (Escherichia coli) and yeast (Saccharomyces cerevisiae). - Highlights: • One-pot green synthesis was used for fluorescent CDs. • FT-IR, DLS, and TEM were used for the characterization of CDs. • The CDs are well dispersed in water with an average size of ∼ 3 nm. • The CDs acted as fluorescent probes for imaging of bacteria and yeast cells.

Inelastic magnon scattering

Directory of Open Access Journals (Sweden)

Robert de Mello Koch

2017-05-01

Full Text Available We study the worldsheet S-matrix of a string attached to a D-brane in AdS5×S5. The D-brane is either a giant graviton or a dual giant graviton. In the gauge theory, the operators we consider belong to the su(2|3 sector of the theory. Magnon excitations of open strings can exhibit both elastic (when magnons in the bulk of the string scatter and inelastic (when magnons at the endpoint of an open string participate scattering. Both of these S-matrices are determined (up to an overall phase by the su(2|22 global symmetry of the theory. In this note we study the S-matrix for inelastic scattering. We show that it exhibits poles corresponding to boundstates of bulk and boundary magnons. A crossing equation is derived for the overall phase. It reproduces the crossing equation for maximal giant gravitons, in the appropriate limit. Finally, scattering in the su(2 sector is computed to two loops. This two loop result, which determines the overall phase to two loops, will be useful when a unique solution to the crossing equation is to be selected.

Neutron scattering treatise on materials science and technology

CERN Document Server

Kostorz, G

1979-01-01

Treatise on Materials Science and Technology, Volume 15: Neutron Scattering shows how neutron scattering methods can be used to obtain important information on materials. The book discusses the general principles of neutron scattering; the techniques used in neutron crystallography; and the applications of nuclear and magnetic scattering. The text also describes the measurement of phonons, their role in phase transformations, and their behavior in the presence of crystal defects; and quasi-elastic scattering, with its special merits in the study of microscopic dynamical phenomena in solids and

Structural phase transitions and Huang scattering

International Nuclear Information System (INIS)

Yamada, Yasusada

1980-01-01

The usefulness of the application of the concept of Huang scattering to the understandings of the origin of diffuse scatterings near structural phase transitions are discussed. It is pointed out that in several phase transitions, the observed diffuse scatterings can not be interpreted in terms of critical fluctuations of the order parameters associated with the structural phase transitions, and that they are rather interpreted as Huang scattering due to random distribution of individual order parameter which is 'dressed' by strain fields. Examples to show effective applications of this concept to analyze the experimental X-ray data and whence to understand microscopic mechanisms of structural phase transitions are presented. (author)

Controlled light scattering in transparent polycrystalline ferroelectrics

International Nuclear Information System (INIS)

Vasilevskaya, A.S.; Grodnenskij, I.M.; Sonin, A.S.

1977-01-01

Scattering indicatrices, birefringence, attenuation factor and time characteristics of the light scattering effect have been investigated in a polycrystal solid solution of Pbsub(0.92)Lasub(0.08)(Zrsub(0.65)Tisub(0.35))Osub(3) with the crystallite dimension 4-5 μm. The measurements have been taken for longitudinal and transverse scattering effects in the visible range of spectrum in the temperature range 20-200 deg C. The time characteristics of the scattering effect have been found to be significantly different when a sample transfers from a thermally depolarized state to an electrically polarized one and from an electrically polarized state to an electrically depolarized one. The shape of the scattering indicatrices depends on the polarization state of a sample. The distribution of the scattered light intensity in the part of the indicatrix characterizing the fundamental scattering is satisfactorily described by the Rayleigh-Hans theory. The diameter of scattering centres responsible for the scattering has been determined to be 6-7 μm. The experimental data show that there are different types of scattering centres, in the material. The fundamental scattering is caused by centres arising irreversibly during initial polarization of the sample. The second type of centres is responsible for the controlled part of scattering during repolarization

Light scattering in glass-ceramics

International Nuclear Information System (INIS)

Hendy, S.C.

2002-01-01

Full text: Glass-ceramic materials with microstructures comprised of dispersed nanocrystallites in a residual glass matrix show promise for many new technological applications. In particular, transparent glass-ceramics offer low thermal expansion and stability, in addition to the prospect of novel non-linear optical properties that can arise from the nanocrystallites. Good transparency requires low optical scattering and low atomic absorption. Light scattering in the glass-ceramic arises primarily from the glass-crystallite interface. The attenuation due to scattering (turbidity) will depend upon the difference in refractive index of the two phases and the size and distribution of nanocrystallites in the glass. Here we consider models of glass-ceramic structure formation and look at scattering in these model structures to increase our understanding of the transparency of glass-ceramics

Comparative Study of Non-Enveloped Icosahedral Viruses Size.

Directory of Open Access Journals (Sweden)

Nikolai Nikitin

Full Text Available Now, as before, transmission electron microscopy (TEM is a widely used technique for the determination of virions size. In some studies, dynamic light scattering (DLS has also been applied for this purpose. Data obtained by different authors and using different methods could vary significantly. The process of TEM sample preparation involves drying on the substrate, which can cause virions to undergo morphology changes. Therefore, other techniques should be used for measurements of virions size in liquid, (i.e. under conditions closer to native. DLS and nanoparticle tracking analysis (NTA provide supplementary data about the virions hydrodynamic diameter and aggregation state in liquid. In contrast to DLS, NTA data have a higher resolution and also are less sensitive to minor admixtures. In the present work, the size of non-enveloped icosahedral viruses of different nature was analyzed by TEM, DLS and NTA: the viruses used were the encephalomyocarditis virus (animal virus, and cauliflower mosaic virus, brome mosaic virus and bean mild mosaic virus (plant viruses. The same, freshly purified, samples of each virus were used for analysis using the different techniques. The results were compared with earlier published data and description databases. DLS data about the hydrodynamic diameter of bean mild mosaic virus, and NTA data for all examined viruses, were obtained for the first time. For all virus samples, the values of size obtained by TEM were less than virions sizes determined by DLS and NTA. The contribution of the electrical double layer (EDL in virions hydrodynamic diameter was evaluated. DLS and NTA data adjusted for EDL thickness were in better agreement with TEM results.

Synthesis of silver nanoparticles by sophorolipids: Effect of ...

Indian Academy of Sciences (India)

Wintec

various shapes and sizes. Typically, the ... two different types of sophorolipids are used for the synthesis of Ag NPs. ... 300 kV. 2.1c Dynamic light scattering measurements: DLS ..... 36 638. 4. Mirkin C A, Letsinger R L, Mucic R C and Storhoff J.

Interrelationships of glycosylation and aggregation kinetics for Peniophora lycii phytase

DEFF Research Database (Denmark)

Høiberg-Nielsen, R.; Fuglsang, C.C.; Arleth, L.

2006-01-01

The kinetics of thermally induced aggregation of the glycoprotein Peniophora lycii phytase (Phy) and a deglycosylated form (dgPhy) was studied by dynamic (DLS) and static (SLS) light scattering. This provided a detailed insight into the time course of the formation of small aggregates (similar...

Fast analytical scatter estimation using graphics processing units.

Science.gov (United States)

Ingleby, Harry; Lippuner, Jonas; Rickey, Daniel W; Li, Yue; Elbakri, Idris

2015-01-01

To develop a fast patient-specific analytical estimator of first-order Compton and Rayleigh scatter in cone-beam computed tomography, implemented using graphics processing units. The authors developed an analytical estimator for first-order Compton and Rayleigh scatter in a cone-beam computed tomography geometry. The estimator was coded using NVIDIA's CUDA environment for execution on an NVIDIA graphics processing unit. Performance of the analytical estimator was validated by comparison with high-count Monte Carlo simulations for two different numerical phantoms. Monoenergetic analytical simulations were compared with monoenergetic and polyenergetic Monte Carlo simulations. Analytical and Monte Carlo scatter estimates were compared both qualitatively, from visual inspection of images and profiles, and quantitatively, using a scaled root-mean-square difference metric. Reconstruction of simulated cone-beam projection data of an anthropomorphic breast phantom illustrated the potential of this method as a component of a scatter correction algorithm. The monoenergetic analytical and Monte Carlo scatter estimates showed very good agreement. The monoenergetic analytical estimates showed good agreement for Compton single scatter and reasonable agreement for Rayleigh single scatter when compared with polyenergetic Monte Carlo estimates. For a voxelized phantom with dimensions 128 × 128 × 128 voxels and a detector with 256 × 256 pixels, the analytical estimator required 669 seconds for a single projection, using a single NVIDIA 9800 GX2 video card. Accounting for first order scatter in cone-beam image reconstruction improves the contrast to noise ratio of the reconstructed images. The analytical scatter estimator, implemented using graphics processing units, provides rapid and accurate estimates of single scatter and with further acceleration and a method to account for multiple scatter may be useful for practical scatter correction schemes.

A surprise in the first Born approximation for electron scattering

International Nuclear Information System (INIS)

Treacy, M.M.J.; Van Dyck, D.

2012-01-01

A standard textbook derivation for the scattering of electrons by a weak potential under the first Born approximation suggests that the far-field scattered wave should be in phase with the incident wave. However, it is well known that waves scattered from a weak phase object should be phase-shifted by π/2 relative to the incident wave. A disturbing consequence of this missing phase is that, according to the Optical Theorem, the total scattering cross section would be zero in the first Born approximation. We resolve this mystery pedagogically by showing that the first Born approximation fails to conserve electrons even to first order. Modifying the derivation to conserve electrons introduces the correct phase without changing the scattering amplitude. We also show that the far-field expansion for the scattered waves used in many texts is inappropriate for computing an exit wave from a sample, and that the near-field expansion also give the appropriately phase-shifted result. -- Highlights: ► The first Born approximation is usually invoked as the theoretical physical basis for kinematical electron scattering theory. ► Although it predicts the correct scattering amplitude, it predicts the wrong phase; the scattered wave is missing a prefactor of i. ► We show that this arises because the standard textbook version of the first Born approximation does not conserve electrons. ► We show how this can be fixed.

Quantum scattering at low energies

DEFF Research Database (Denmark)

Derezinski, Jan; Skibsted, Erik

2009-01-01

For a class of negative slowly decaying potentials, including V(x):=−γ|x|−μ with 0quantum mechanical scattering theory in the low-energy regime. Using appropriate modifiers of the Isozaki–Kitada type we show that scattering theory is well behaved on the whole continuous spectrum...... of the Hamiltonian, including the energy 0. We show that the modified scattering matrices S(λ) are well-defined and strongly continuous down to the zero energy threshold. Similarly, we prove that the modified wave matrices and generalized eigenfunctions are norm continuous down to the zero energy if we use...... of the kernel of S(λ) experiences an abrupt change from passing from positive energies λ to the limiting energy λ=0 . This change corresponds to the behaviour of the classical orbits. Under stronger conditions one can extract the leading term of the asymptotics of the kernel of S(λ) at its singularities....

Elastic scattering of low energy γ-rays

International Nuclear Information System (INIS)

Whittingham, I.B.

1978-05-01

Theoretical cross sections for the elastic scattering of 245, 334, 444, 779, 1086, 1112 and 1408 keV γ-rays by Pb are obtained for scattering angles up to 150 degrees. Three sets of Rayleigh scattering amplitudes have been computed using (1) the calculations of Johnson and Cheng, (2) the K shell calculations of Brown and co-workers supplemented by form factors amplitudes for higher shells, and (3) form factor amplitudes for all shells. Nuclear Thomson amplitudes have been included for all energies and, for 1408 keV, Delbruck scattering based upon the calculations of Papatzacos and Mork has been included. Nuclear resonance scattering is show to be negligble for all energies

Quantum entanglement and neutron scattering experiments

International Nuclear Information System (INIS)

Cowley, R A

2003-01-01

It is shown that quantum entanglement in condensed matter can be observed with scattering experiments if the energy resolution of the experiments enables a clear separation between the elastic scattering and the scattering from the excitations in the system. These conditions are not satisfied in recent deep inelastic neutron scattering experiments from hydrogen-containing systems that have been interpreted as showing the existence of quantum entanglement for short times in, for example, water at room temperature. It is shown that the theory put forward to explain these experiments is inconsistent with the first-moment sum rule for the Van Hove scattering function and we suggest that the theory is incorrect. The experiments were performed using the unique EVS spectrometer at ISIS and suggestions are made about how the data and their interpretation should be re-examined

Wavefield separation by energy norm Born scattering

KAUST Repository

Sun, Bingbing

2017-08-17

In Reflection Based Waveform Inversion, the gradient is computed by cross-correlating the direct and Born scattered wavefield with their adjoints applied to the data residuals. In this case, the transmitted part of the Born scattered wavefield produces high wavenumber artifacts, which would harm the convergence of the inversion process. We propose an efficient Energy Norm Born Scattering (ENBS) to attenuate the transmission components of the Born modeling, and allow it to produce only reflections. ENBS is derived from the adjoint of the Energy Norm (inverse scattering) imaging condition and in order to get deeper insights of how this method works, we show analytically that given an image, in which reflectivity is represented by a Dirac delta function, ENBS attenuates transmission energy perfectly. We use numerical examples to demonstrate that ENBS works in both the time and the frequency domain. We also show that in reflection waveform inversion (RWI) the wave path constructed by ENBS would be cleaner and free of high wavenumber artifacts associated with conventional Born scattering.

Wavefield separation by energy norm Born scattering

KAUST Repository

Sun, Bingbing; Alkhalifah, Tariq Ali

2017-01-01

In Reflection Based Waveform Inversion, the gradient is computed by cross-correlating the direct and Born scattered wavefield with their adjoints applied to the data residuals. In this case, the transmitted part of the Born scattered wavefield produces high wavenumber artifacts, which would harm the convergence of the inversion process. We propose an efficient Energy Norm Born Scattering (ENBS) to attenuate the transmission components of the Born modeling, and allow it to produce only reflections. ENBS is derived from the adjoint of the Energy Norm (inverse scattering) imaging condition and in order to get deeper insights of how this method works, we show analytically that given an image, in which reflectivity is represented by a Dirac delta function, ENBS attenuates transmission energy perfectly. We use numerical examples to demonstrate that ENBS works in both the time and the frequency domain. We also show that in reflection waveform inversion (RWI) the wave path constructed by ENBS would be cleaner and free of high wavenumber artifacts associated with conventional Born scattering.

Thermoelectric band engineering: The role of carrier scattering

Science.gov (United States)

Witkoske, Evan; Wang, Xufeng; Lundstrom, Mark; Askarpour, Vahid; Maassen, Jesse

2017-11-01

Complex electronic band structures, with multiple valleys or bands at the same or similar energies, can be beneficial for thermoelectric performance, but the advantages can be offset by inter-valley and inter-band scattering. In this paper, we demonstrate how first-principles band structures coupled with recently developed techniques for rigorous simulation of electron-phonon scattering provide the capabilities to realistically assess the benefits and trade-offs associated with these materials. We illustrate the approach using n-type silicon as a model material and show that intervalley scattering is strong. This example shows that the convergence of valleys and bands can improve thermoelectric performance, but the magnitude of the improvement depends sensitively on the relative strengths of intra- and inter-valley electron scattering. Because anisotropy of the band structure also plays an important role, a measure of the benefit of band anisotropy in the presence of strong intervalley scattering is presented.

Splatterplots: overcoming overdraw in scatter plots.

Science.gov (United States)

Mayorga, Adrian; Gleicher, Michael

2013-09-01

We introduce Splatterplots, a novel presentation of scattered data that enables visualizations that scale beyond standard scatter plots. Traditional scatter plots suffer from overdraw (overlapping glyphs) as the number of points per unit area increases. Overdraw obscures outliers, hides data distributions, and makes the relationship among subgroups of the data difficult to discern. To address these issues, Splatterplots abstract away information such that the density of data shown in any unit of screen space is bounded, while allowing continuous zoom to reveal abstracted details. Abstraction automatically groups dense data points into contours and samples remaining points. We combine techniques for abstraction with perceptually based color blending to reveal the relationship between data subgroups. The resulting visualizations represent the dense regions of each subgroup of the data set as smooth closed shapes and show representative outliers explicitly. We present techniques that leverage the GPU for Splatterplot computation and rendering, enabling interaction with massive data sets. We show how Splatterplots can be an effective alternative to traditional methods of displaying scatter data communicating data trends, outliers, and data set relationships much like traditional scatter plots, but scaling to data sets of higher density and up to millions of points on the screen.

Surface-enhanced Raman scattering from silver electrodes

International Nuclear Information System (INIS)

Trott, G.R.

1982-01-01

The chemical and physical origins of the anomalously large enhancement of the Raman scattering cross section for molecules adsorbed on silver electrodes in an electrochemical cell were investigated. The effect of the chemical reactions which occur during the anodization/activation procedure were studied using the Ag-CN system. It was shown that the function of the anodization process is to roughen the electrode surface and create an activated site for bonding to the cyanide. A new nonelectrochemical technique for activating the silver surface, along with a study of the enhanced cyanide Raman scattering in different background electrolytes, showed that the Raman active entity on the surface must be a silver-cyanide complex. In order to study the physical mechanism of the enhancement, the angular dependence of the scattered radiation was measured from pyridine adsorbed on an evaporated silver electrode. Both polycrystalline and single crystalline silver films were used. The angular dependence of the scattered radiation from these films showed that the metal surface was controlling the directional properties of the scattered radiation, and not the polarizability tensor of the adsorbate. Based on these experimental results, it was concluded that for weakly roughened silver electrodes the source of the anomalous enhancement is due to a resonant Raman scattering process

Polarization recovery through scattering media.

Science.gov (United States)

de Aguiar, Hilton B; Gigan, Sylvain; Brasselet, Sophie

2017-09-01

The control and use of light polarization in optical sciences and engineering are widespread. Despite remarkable developments in polarization-resolved imaging for life sciences, their transposition to strongly scattering media is currently not possible, because of the inherent depolarization effects arising from multiple scattering. We show an unprecedented phenomenon that opens new possibilities for polarization-resolved microscopy in strongly scattering media: polarization recovery via broadband wavefront shaping. We demonstrate focusing and recovery of the original injected polarization state without using any polarizing optics at the detection. To enable molecular-level structural imaging, an arbitrary rotation of the input polarization does not degrade the quality of the focus. We further exploit the robustness of polarization recovery for structural imaging of biological tissues through scattering media. We retrieve molecular-level organization information of collagen fibers by polarization-resolved second harmonic generation, a topic of wide interest for diagnosis in biomedical optics. Ultimately, the observation of this new phenomenon paves the way for extending current polarization-based methods to strongly scattering environments.

A scatter-corrected list-mode reconstruction and a practical scatter/random approximation technique for dynamic PET imaging

International Nuclear Information System (INIS)

Cheng, J-C; Rahmim, Arman; Blinder, Stephan; Camborde, Marie-Laure; Raywood, Kelvin; Sossi, Vesna

2007-01-01

We describe an ordinary Poisson list-mode expectation maximization (OP-LMEM) algorithm with a sinogram-based scatter correction method based on the single scatter simulation (SSS) technique and a random correction method based on the variance-reduced delayed-coincidence technique. We also describe a practical approximate scatter and random-estimation approach for dynamic PET studies based on a time-averaged scatter and random estimate followed by scaling according to the global numbers of true coincidences and randoms for each temporal frame. The quantitative accuracy achieved using OP-LMEM was compared to that obtained using the histogram-mode 3D ordinary Poisson ordered subset expectation maximization (3D-OP) algorithm with similar scatter and random correction methods, and they showed excellent agreement. The accuracy of the approximated scatter and random estimates was tested by comparing time activity curves (TACs) as well as the spatial scatter distribution from dynamic non-human primate studies obtained from the conventional (frame-based) approach and those obtained from the approximate approach. An excellent agreement was found, and the time required for the calculation of scatter and random estimates in the dynamic studies became much less dependent on the number of frames (we achieved a nearly four times faster performance on the scatter and random estimates by applying the proposed method). The precision of the scatter fraction was also demonstrated for the conventional and the approximate approach using phantom studies

Cascaded Bragg scattering in fiber optics.

Science.gov (United States)

Xu, Y Q; Erkintalo, M; Genty, G; Murdoch, S G

2013-01-15

We report on a theoretical and experimental study of cascaded Bragg scattering in fiber optics. We show that the usual energy-momentum conservation of Bragg scattering can be considerably relaxed via cascade-induced phase-matching. Experimentally we demonstrate frequency translation over six- and 11-fold cascades, in excellent agreement with derived phase-matching conditions.

Renormalization Scale-Fixing for Complex Scattering Amplitudes

Energy Technology Data Exchange (ETDEWEB)

Brodsky, Stanley J.; /SLAC; Llanes-Estrada, Felipe J.; /Madrid U.

2005-12-21

We show how to fix the renormalization scale for hard-scattering exclusive processes such as deeply virtual meson electroproduction by applying the BLM prescription to the imaginary part of the scattering amplitude and employing a fixed-t dispersion relation to obtain the scale-fixed real part. In this way we resolve the ambiguity in BLM renormalization scale-setting for complex scattering amplitudes. We illustrate this by computing the H generalized parton distribution at leading twist in an analytic quark-diquark model for the parton-proton scattering amplitude which can incorporate Regge exchange contributions characteristic of the deep inelastic structure functions.

Forward Scattering of Loaded and Unloaded Antennas

DEFF Research Database (Denmark)

Gustafsson, Mats; Andersen, Jørgen Bach; Kristensson, Gerhard

2012-01-01

Forward scattering of antennas is related to antenna performance via the forward-scattering sum rule. The forward-scattering sum rule is an integral identity that shows that a weighted integral of the extinction cross section over all spectrum is proportional to the static polarizability...... of the antenna structure. Here, the forward-scattering sum rule is experimentally verified for loaded, short-circuit, and open-circuit cylindrical dipole antennas. It is also shown that the absorption efficiency cannot be greater than 1/2 for reciprocal linearly polarized lossless matched antennas...... with a symmetric radiation pattern in the forward and backward directions....

Techniques in high pressure neutron scattering

CERN Document Server

Klotz, Stefan

2013-01-01

Drawing on the author's practical work from the last 20 years, Techniques in High Pressure Neutron Scattering is one of the first books to gather recent methods that allow neutron scattering well beyond 10 GPa. The author shows how neutron scattering has to be adapted to the pressure range and type of measurement.Suitable for both newcomers and experienced high pressure scientists and engineers, the book describes various solutions spanning two to three orders of magnitude in pressure that have emerged in the past three decades. Many engineering concepts are illustrated through examples of rea

Atom-dimer scattering in a heteronuclear mixture with a finite intraspecies scattering length

Science.gov (United States)

Gao, Chao; Zhang, Peng

2018-04-01

We study the three-body problem of two ultracold identical bosonic atoms (denoted by B ) and one extra atom (denoted by X ), where the scattering length aB X between each bosonic atom and atom X is resonantly large and positive. We calculate the scattering length aad between one bosonic atom and the shallow dimer formed by the other bosonic atom and atom X , and investigate the effect induced by the interaction between the two bosonic atoms. We find that even if this interaction is weak (i.e., the corresponding scattering length aB B is of the same order of the van der Waals length rvdW or even smaller), it can still induce a significant effect for the atom-dimer scattering length aad. Explicitly, an atom-dimer scattering resonance can always occur when the value of aB B varies in the region with | aB B|≲ rvdW . As a result, both the sign and the absolute value of aad, as well as the behavior of the aad-aB X function, depends sensitively on the exact value of aB B. Our results show that, for a good quantitative theory, the intraspecies interaction is required to be taken into account for this heteronuclear system, even if this interaction is weak.

Double hard scattering without double counting

Energy Technology Data Exchange (ETDEWEB)

Diehl, Markus [Deutsches Elektronen-Synchrotron (DESY), Hamburg (Germany); Gaunt, Jonathan R. [VU Univ. Amsterdam (Netherlands). NIKHEF Theory Group; Schoenwald, Kay [Deutsches Elektronen-Synchrotron (DESY), Zeuthen (Germany)

2017-02-15

Double parton scattering in proton-proton collisions includes kinematic regions in which two partons inside a proton originate from the perturbative splitting of a single parton. This leads to a double counting problem between single and double hard scattering. We present a solution to this problem, which allows for the definition of double parton distributions as operator matrix elements in a proton, and which can be used at higher orders in perturbation theory. We show how the evaluation of double hard scattering in this framework can provide a rough estimate for the size of the higher-order contributions to single hard scattering that are affected by double counting. In a numeric study, we identify situations in which these higher-order contributions must be explicitly calculated and included if one wants to attain an accuracy at which double hard scattering becomes relevant, and other situations where such contributions may be neglected.

Double hard scattering without double counting

International Nuclear Information System (INIS)

Diehl, Markus; Gaunt, Jonathan R.

2017-02-01

Double parton scattering in proton-proton collisions includes kinematic regions in which two partons inside a proton originate from the perturbative splitting of a single parton. This leads to a double counting problem between single and double hard scattering. We present a solution to this problem, which allows for the definition of double parton distributions as operator matrix elements in a proton, and which can be used at higher orders in perturbation theory. We show how the evaluation of double hard scattering in this framework can provide a rough estimate for the size of the higher-order contributions to single hard scattering that are affected by double counting. In a numeric study, we identify situations in which these higher-order contributions must be explicitly calculated and included if one wants to attain an accuracy at which double hard scattering becomes relevant, and other situations where such contributions may be neglected.

On the microscopic foundation of scattering theory

International Nuclear Information System (INIS)

Moser, T.

2007-01-01

The aim of the thesis is to give a contribution to the microscopic foundation of scattering theory, i. e. to show, how the asymptotic formalism of scattering theory with objects like the S-matrix as well the initial and final asymptotics ψ in and ψ out can be derived from a microscopic description of the basic system. First the final statistics from a N-particle system through farly distant surfaces is derived. Thereafter we confine us to the 1-particle scattering and apply the final statistics in order to derive the scattering cross section from a microscopical description of the scattering situation. The basing dynamics are Bohm's mechanics, a theory on the motion of point particles, which reproduces all results of nonrelativistic quantum mechanics

Do Cloaked Objects Really Scatter Less?

Directory of Open Access Journals (Sweden)

Francesco Monticone

2013-10-01

Full Text Available We discuss the global scattering response of invisibility cloaks over the entire electromagnetic spectrum, from static to very high frequencies. Based on linearity, causality, and energy conservation, we show that the total extinction and scattering, integrated over all wavelengths, of any linear, passive, causal, and nondiamagnetic cloak, necessarily increase compared to the uncloaked case. In light of this general principle, we provide a quantitative measure to compare the global performance of different cloaking techniques and we discuss solutions to minimize the global scattering signature of an object using thin, superconducting shells. Our results provide important physical insights on how invisibility cloaks operate and affect the global scattering of an object, suggesting ways to defeat countermeasures aimed at detecting cloaked objects using short impinging pulses.

Solution of a simple inelastic scattering problem

International Nuclear Information System (INIS)

Knudson, S.K.

1975-01-01

Simple examples of elastic scattering, typically from square wells, serve as important pedagogical tools in discussion of the concepts and processes involved in elastic scattering events. An analytic solution of a model inelastic scattering system is presented here to serve in this role for inelastic events. The model and its solution are simple enough to be of pedagogical utility, but also retain enough of the important physical features to include most of the special characteristics of inelastic systems. The specific model chosen is the collision of an atom with a harmonic oscillator, interacting via a repulsive square well potential. Pedagogically important features of inelastic scattering, including its multistate character, convergence behavior, and dependence on an ''inelastic potential'' are emphasized as the solution is determined. Results are presented for various energies and strengths of inelastic scattering, which show that the model is capable of providing an elementary representation of vibrationally inelastic scattering

Scattered radiation in fan beam imaging systems

International Nuclear Information System (INIS)

Johns, P.C.; Yaffe, M.

1982-01-01

Scatter-to-primary energy fluence ratios (S/P) have been studied for fan x-ray beams as used in CT scanners and slit projection radiography systems. The dependence of S/P on phantom diameter, distance from phantom to image receptor, and kilovoltage is presented. An empirical equation is given that predicts S/P over a wide range of fan beam imaging configurations. For CT body scans on a 4th-generation machine, S/P is approximately 5%. Scattered radiation can produce a significant cupping artefact in CT images which is similar to that due to beam hardening. When multiple slices are used in scanned slit radiography, they can be arranged such that the increase in S/P is negligible. Calculations of scatter-to-primary ratios for first order scattering showed that for fan beams the contribution of coherent scatter is comparable to or greater than that of incoherent first scatter

Polarimetric SAR interferometry-based decomposition modelling for reliable scattering retrieval

Science.gov (United States)

Agrawal, Neeraj; Kumar, Shashi; Tolpekin, Valentyn

2016-05-01

Fully Polarimetric SAR (PolSAR) data is used for scattering information retrieval from single SAR resolution cell. Single SAR resolution cell may contain contribution from more than one scattering objects. Hence, single or dual polarized data does not provide all the possible scattering information. So, to overcome this problem fully Polarimetric data is used. It was observed in previous study that fully Polarimetric data of different dates provide different scattering values for same object and coefficient of determination obtained from linear regression between volume scattering and aboveground biomass (AGB) shows different values for the SAR dataset of different dates. Scattering values are important input elements for modelling of forest aboveground biomass. In this research work an approach is proposed to get reliable scattering from interferometric pair of fully Polarimetric RADARSAT-2 data. The field survey for data collection was carried out for Barkot forest during November 10th to December 5th, 2014. Stratified random sampling was used to collect field data for circumference at breast height (CBH) and tree height measurement. Field-measured AGB was compared with the volume scattering elements obtained from decomposition modelling of individual PolSAR images and PolInSAR coherency matrix. Yamaguchi 4-component decomposition was implemented to retrieve scattering elements from SAR data. PolInSAR based decomposition was the great challenge in this work and it was implemented with certain assumptions to create Hermitian coherency matrix with co-registered polarimetric interferometric pair of SAR data. Regression analysis between field-measured AGB and volume scattering element obtained from PolInSAR data showed highest (0.589) coefficient of determination. The same regression with volume scattering elements of individual SAR images showed 0.49 and 0.50 coefficients of determination for master and slave images respectively. This study recommends use of

THEORY AND SIMULATIONS OF REFRACTIVE SUBSTRUCTURE IN RESOLVED SCATTER-BROADENED IMAGES

Energy Technology Data Exchange (ETDEWEB)

Johnson, Michael D. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Gwinn, Carl R., E-mail: mjohnson@cfa.harvard.edu [Department of Physics, University of California, Santa Barbara, CA 93106 (United States)

2015-06-01

At radio wavelengths, scattering in the interstellar medium distorts the appearance of astronomical sources. Averaged over a scattering ensemble, the result is a blurred image of the source. However, Narayan and Goodman and Goodman and Narayan showed that for an incomplete average, scattering introduces refractive substructure in the image of a point source that is both persistent and wideband. We show that this substructure is quenched but not smoothed by an extended source. As a result, when the scatter-broadening is comparable to or exceeds the unscattered source size, the scattering can introduce spurious compact features into images. In addition, we derive efficient strategies to numerically compute realistic scattered images, and we present characteristic examples from simulations. Our results show that refractive substructure is an important consideration for ongoing missions at the highest angular resolutions, and we discuss specific implications for RadioAstron and the Event Horizon Telescope.

Revealing the compact structure of lactic acid bacterial hetero-exopolysaccharides by SAXS and DLS

DEFF Research Database (Denmark)

Khan, Sanaullah; Birch, Johnny; Harris, Pernille

2017-01-01

solution structures of three lactic acid bacterial hetero-exopolysaccharides (HePS-1, HePS-2 and HePS-3). Values of radius of gyration RG, cross-sectional radius of gyration RXS, approximate length L and hydrodynamic diameter were not directly proportional to the molar mass and indicated the HePSs adopted...... Galf residues significantly influence the conformation. Ab initio scattering modeling of HePS-2 and HePS-3 gave excellent curve fittings with χ2 of 0.43 and 0.34 for best-fit models, respectively, compatible with coil-like conformation. The findings disclose solution behaviour of HePS relevant...

Virtual neutron scattering experiments

DEFF Research Database (Denmark)

Overgaard, Julie Hougaard; Bruun, Jesper; May, Michael

2016-01-01

We describe how virtual experiments can be utilized in a learning design that prepares students for hands-on experiments at large-scale facilities. We illustrate the design by showing how virtual experiments are used at the Niels Bohr Institute in a master level course on neutron scattering....... In the last week of the course, students travel to a large-scale neutron scattering facility to perform real neutron scattering experiments. Through student interviews and survey answers, we argue, that the virtual training prepares the students to engage more fruitfully with experiments by letting them focus...... on physics and data rather than the overwhelming instrumentation. We argue that this is because they can transfer their virtual experimental experience to the real-life situation. However, we also find that learning is still situated in the sense that only knowledge of particular experiments is transferred...

Cooperative scattering of scalar waves by optimized configurations of point scatterers

Science.gov (United States)

Schäfer, Frank; Eckert, Felix; Wellens, Thomas

2017-12-01

We investigate multiple scattering of scalar waves by an ensemble of N resonant point scatterers in three dimensions. For up to N = 21 scatterers, we numerically optimize the positions of the individual scatterers, to maximize the total scattering cross section for an incoming plane wave, on the one hand, and to minimize the decay rate associated to a long-lived scattering resonance, on the other. In both cases, the optimum is achieved by configurations where all scatterers are placed on a line parallel to the direction of the incoming plane wave. The associated maximal scattering cross section increases quadratically with the number of scatterers for large N, whereas the minimal decay rate—which is realized by configurations that are not the same as those that maximize the scattering cross section—decreases exponentially as a function of N. Finally, we also analyze the stability of our optimized configurations with respect to small random displacements of the scatterers. These results demonstrate that optimized configurations of scatterers bear a considerable potential for applications such as quantum memories or mirrors consisting of only a few atoms.

Schwinger–Keldysh canonical formalism for electronic Raman scattering

Energy Technology Data Exchange (ETDEWEB)

Su, Yuehua, E-mail: suyh@ytu.edu.cn

2016-03-01

Inelastic low-energy Raman and high-energy X-ray scatterings have made great progress in instrumentation to investigate the strong electronic correlations in matter. However, theoretical study of the relevant scattering spectrum is still a challenge. In this paper, we present a Schwinger–Keldysh canonical perturbation formalism for the electronic Raman scattering, where all the resonant, non-resonant and mixed responses are considered uniformly. We show how to use this formalism to evaluate the cross section of the electronic Raman scattering off an one-band superconductor. All the two-photon scattering processes from electrons, the non-resonant charge density response, the elastic Rayleigh scattering, the fluorescence, the intrinsic energy-shift Raman scattering and the mixed response, are included. In the mean-field superconducting state, Cooper pairs contribute only to the non-resonant response. All the other responses are dominated by the single-particle excitations and are strongly suppressed due to the opening of the superconducting gap. Our formalism for the electronic Raman scattering can be easily extended to study the high-energy resonant inelastic X-ray scattering.

Bistable scattering in graphene-coated dielectric nanowires.

Science.gov (United States)

Li, Rujiang; Wang, Huaping; Zheng, Bin; Dehdashti, Shahram; Li, Erping; Chen, Hongsheng

2017-06-22

In nonlinear plasmonics, the switching threshold of optical bistability is limited by the weak nonlinear responses from the conventional Kerr dielectric media. Considering the giant nonlinear susceptibility of graphene, here we develop a nonlinear scattering model under the mean field approximation and study the bistable scattering in graphene-coated dielectric nanowires based on the semi-analytical solutions. We find that the switching intensities of bistable scattering can be smaller than 1 MW cm -2 at the working frequency. To further decrease the switching intensities, we show that the most important factor that restricts the bistable scattering is the relaxation time of graphene. Our work not only reveals some general characteristics of graphene-based bistable scattering, but also provides a guidance to further applications of optical bistability in the high speed all-optical signal processing.

Charged mediators in dark matter scattering

Science.gov (United States)

Stengel, Patrick

2017-11-01

We consider a scenario, within the framework of the MSSM, in which dark matter is bino-like and dark matter-nucleon spin-independent scattering occurs via the exchange of light squarks which exhibit left-right mixing. We show that direct detection experiments such as LUX and SuperCDMS will be sensitive to a wide class of such models through spin-independent scattering. The dominant nuclear physics uncertainty is the quark content of the nucleon, particularly the strangeness content. We also investigate parameter space with nearly degenerate neutralino and squark masses, thus enhancing dark matter annihilation and nucleon scattering event rates.

Dorsolateral Striatum Engagement Interferes with Early Discrimination Learning

Directory of Open Access Journals (Sweden)

Hadley C. Bergstrom

2018-05-01

Full Text Available Summary: In current models, learning the relationship between environmental stimuli and the outcomes of actions involves both stimulus-driven and goal-directed systems, mediated in part by the DLS and DMS, respectively. However, though these models emphasize the importance of the DLS in governing actions after extensive experience has accumulated, there is growing evidence of DLS engagement from the onset of training. Here, we used in vivo photosilencing to reveal that DLS recruitment interferes with early touchscreen discrimination learning. We also show that the direct output pathway of the DLS is preferentially recruited and causally involved in early learning and find that silencing the normal contribution of the DLS produces plasticity-related alterations in a PL-DMS circuit. These data provide further evidence suggesting that the DLS is recruited in the construction of stimulus-elicited actions that ultimately automate behavior and liberate cognitive resources for other demands, but with a cost to performance at the outset of learning. : What is the contribution of the DLS in early discrimination learning? Bergstrom et al. show using in vivo optogenetics, fluorescence in situ hybridization, and brain-wide activity mapping that silencing the DLS facilitates early discrimination learning, drives activity in a parallel PL-DMS circuit, and preferentially recruits the DLS “direct” output pathway. Keywords: striatum, reward, goal-directed, habit, optogenetics, plasticity, cognition, Arc

Energy Transfer in Scattering by Rotating Potentials

Indian Academy of Sciences (India)

Quantum mechanical scattering theory is studied for time-dependent Schrödinger operators, in particular for particles in a rotating potential. Under various assumptions about the decay rate at infinity we show uniform boundedness in time for the kinetic energy of scattering states, existence and completeness of wave ...

Thermal electron acceleration by electric field spikes in the outer radiation belt: generation of field-aligned pitch angle distributions

Science.gov (United States)

Vasko, I.; Agapitov, O. V.; Mozer, F.; Artemyev, A.

2015-12-01

Van Allen Probes observations in the outer radiation belt have demonstrated an abundance non-linear electrostatic stucture called Time Domain Structures (TDS). One of the type of TDS is electrostatic electron-acoustic double layers (DL). Observed DLs are frequently accompanied by field-aligned (bi-directional) pitch angle distributions (PAD) of electrons with energies from hundred eVs up to several keV (rarely up to tens of keV). We perform numerical simulations of the DL interaction with thermal electrons making use of the test particle approach. DL parameters assumed in the simulations are adopted from observations. We show that DLs accelerate thermal electrons parallel to the magnetic field via the electrostatic Fermi mechanism, i.e. due to reflections from DL potential humps. Due to this interaction some fraction of electrons is scattered into the loss cone. The electron energy gain is larger for larger DL scalar potential amplitudes and higher propagation velocities. In addition to the Fermi mechanism electrons can be trapped by DLs in their generation region and accelerated due to transport to higher latitudes. Both mechanisms result in formation of field-aligned PADs for electrons with energies comparable to those found in observations. The Fermi mechanism provides field-aligned PADs for <1 keV electrons, while the trapping mechanism extends field-aligned PADs to higher energy electrons.

Norm-Minimized Scattering Data from Intensity Spectra

Directory of Open Access Journals (Sweden)

Alexander Seel

2016-01-01

Full Text Available We apply the l1 minimizing technique of compressive sensing (CS to nonlinear quadratic observations. For the example of coherent X-ray scattering we provide the formulas for a Kalman filter approach to quadratic CS and show how to reconstruct the scattering data from their spatial intensity distribution.

Inhibition of stimulated Raman scattering due to the excitation of stimulated Brillouin scattering

Science.gov (United States)

Zhao, Yao; Yu, Lu-Le; Weng, Su-Ming; Ren, Chuang; Liu, Chuan-Sheng; Sheng, Zheng-Ming

2017-09-01

The nonlinear coupling between stimulated Raman scattering (SRS) and stimulated Brillouin scattering (SBS) of intense laser in underdense plasma is studied theoretically and numerically. Based upon the fluid model, their coupling equations are derived, and a threshold condition of plasma density perturbations due to SBS for the inhibition of SRS is given. Particle-in-cell simulations show that this condition can be achieved easily by SBS in the so-called fluid regime with kLλDDebye length [Kline et al., Phys. Plasmas 13, 055906 (2006)]. SBS can reduce the saturation level of SRS and the temperature of electrons in both homogeneous and inhomogeneous plasma. Numerical simulations also show that this reduced SRS saturation is retained even if the fluid regime condition mentioned above is violated at a later time due to plasma heating.

Neutron scattering. Lectures

International Nuclear Information System (INIS)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner

2012-01-01

The following topics are dealt with: Neutron scattering in contemporary research, neutron sources, symmetry of crystals, diffraction, nanostructures investigated by small-angle neutron scattering, the structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic scattering, strongly correlated electrons, dynamics of macromolecules, applications of neutron scattering. (HSI)

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

As-prepared graphene oxide (GO) contains oxidative debris which can be washed using basic solutions. We present the isolation and characterization of these debris. Dynamic light scattering (DLS) is used to monitor the separation of the debris in various solvents in the presence of different protic and aprotic alkylamino ...

Brillouin scatter in laser-produced plasmas

International Nuclear Information System (INIS)

Phillion, D.W.; Kruer, W.L.; Rupert, V.C.

1977-01-01

The absorption of intense laser light is found to be reduced when targets are irradiated by 1.06 μm light with long pulse widths (150-400 psec) and large focal spots (100-250 μm). Estimates of Brillouin scatter which account for the finite heat capacity of the underdense plasma predict this reduction. Spectra of the back reflected light show red shifts indicative of Brillouin scattering

Scattering effect on entanglement propagation in RCFTs

Energy Technology Data Exchange (ETDEWEB)

Numasawa, Tokiro [Yukawa Institute for Theoretical Physics, Kyoto University,Kitashirakawa Oiwakecho, Sakyo-ku, Kyoto, 606-8502 (Japan); Kavli Institute for Theoretical Physics, University of California Santa Barbara,Santa Barbara, CA, 93106 (United States)

2016-12-14

In this paper we discuss the scattering effect on entanglement propagation in RCFTs. In our setup, we consider the time evolution of excited states created by the insertion of many local operators. Our results show that because of the finiteness of quantum dimension, entanglement is not changed after the scattering in RCFTs. In this mean, entanglement is conserved after the scattering event in RCFTs, which reflects the integrability of the system. Our results are also consistent with the free quasiparticle picture after the global quenches.

Diblock-copolymer-mediated self-assembly of protein-stabilized iron oxide nanoparticle clusters for magnetic resonance imaging.

Science.gov (United States)

Tähkä, Sari; Laiho, Ari; Kostiainen, Mauri A

2014-03-03

Superparamagnetic iron oxide nanoparticles (SPIONs) can be used as efficient transverse relaxivity (T2 ) contrast agents in magnetic resonance imaging (MRI). Organizing small (Doxide) diblock copolymer (P2QVP-b-PEO) to mediate the self-assembly of protein-cage-encapsulated iron oxide (γ-Fe2 O3 ) nanoparticles (magnetoferritin) into stable PEO-coated clusters. This approach relies on electrostatic interactions between the cationic N-methyl-2-vinylpyridinium iodide block and magnetoferritin protein cage surface (pI≈4.5) to form a dense core, whereas the neutral ethylene oxide block provides a stabilizing biocompatible shell. Formation of the complexes was studied in aqueous solvent medium with dynamic light scattering (DLS) and cryogenic transmission electron microcopy (cryo-TEM). DLS results indicated that the hydrodynamic diameter (Dh ) of the clusters is approximately 200 nm, and cryo-TEM showed that the clusters have an anisotropic stringlike morphology. MRI studies showed that in the clusters the longitudinal relaxivity (r1 ) is decreased and the transverse relaxivity (r2 ) is increased relative to free magnetoferritin (MF), thus indicating that clusters can provide considerable contrast enhancement. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Simulating Microwave Scattering for Wetland Vegetation in Poyang Lake, Southeast China, Using a Coherent Scattering Model

Directory of Open Access Journals (Sweden)

Jingjuan Liao

2015-07-01

Full Text Available We developed a polarimetric coherent electromagnetic scattering model for Poyang Lake wetland vegetation. Realistic canopy structures including curved leaves and the lodging situation of the vegetation were taken into account, and the situation at the ground surface was established using an Advanced Integral Equation Model combined with Oh’s 2002 model. This new model can reasonably describe the coherence effect caused by the phase differences of the electromagnetic fields scattered from different particles by different scattering mechanisms. We obtained good agreement between the modeling results and C-band data from the Radarsat-2 satellite. A simulation of scattering from the vegetation in Poyang Lake showed that direct vegetation scattering and the single-ground-bounce mechanism are the dominant scattering mechanisms in the C-band and L-band, while the effects of the double-ground-bounce mechanism are very small. We note that the curvature of the leaves and the lodging characteristics of the vegetation cannot be ignored in the modeling process. Monitoring soil moisture in the Poyang Lake wetland with the C-band data was not feasible because of the density and depth of Poyang Lake vegetation. When the density of Poyang Lake Carex increases, the backscattering coefficient either decreases or remains stable.

Scattering of electromagnetic waves from a half-space of randomly distributed discrete scatterers and polarized backscattering ratio law

Science.gov (United States)

Zhu, P. Y.

1991-01-01

The effective-medium approximation is applied to investigate scattering from a half-space of randomly and densely distributed discrete scatterers. Starting from vector wave equations, an approximation, called effective-medium Born approximation, a particular way, treating Green's functions, and special coordinates, of which the origin is set at the field point, are used to calculate the bistatic- and back-scatterings. An analytic solution of backscattering with closed form is obtained and it shows a depolarization effect. The theoretical results are in good agreement with the experimental measurements in the cases of snow, multi- and first-year sea-ice. The root product ratio of polarization to depolarization in backscattering is equal to 8; this result constitutes a law about polarized scattering phenomena in the nature.

Preparation and self-assembly of amphiphilic polylysine dendrons

DEFF Research Database (Denmark)

Mirsharghi, Sahar; Knudsen, Kenneth D.; Bagherifam, Shahla

2016-01-01

Polylysine dendrons with lipid tails prepared by divergent solid-phase synthesis showed self-assembling properties in aqueous solutions., Herein, we present the synthesis of new amphiphilic polylysine dendrons with variable alkyl chain lengths (C1–C18) at the C-terminal. The dendrons were...... synthesized in moderate to quantitative yields by divergent solid-phase synthesis (SPS) employing an aldehyde linker. The self-assembling properties of the dendrons in aqueous solutions were studied by small angle neutron scattering (SANS) and dynamic light scattering (DLS). The self-assembling properties...... were influenced by the length of the alkyl chain and the generation number (Gn). Increasing the temperature and concentration did not have significant impact on the hydrodynamic diameter, but the self-assembling properties were influenced by the pH value. This demonstrated the need for positively...

Rayleigh scattering in an emitter-nanofiber-coupling system

Science.gov (United States)

Tang, Shui-Jing; Gao, Fei; Xu, Da; Li, Yan; Gong, Qihuang; Xiao, Yun-Feng

2017-04-01

Scattering is a general process in both fundamental and applied physics. In this paper, we investigate Rayleigh scattering of a solid-state-emitter coupled to a nanofiber, by S -matrix-like theory in k -space description. Under this model, both Rayleigh scattering and dipole interaction are studied between a two-level artificial atom embedded in a nanocrystal and fiber modes (guided and radiation modes). It is found that Rayleigh scattering plays a critical role in the transport properties and quantum statistics of photons. On the one hand, Rayleigh scattering produces the transparency in the optical transmitted field of the nanofiber, accompanied by the change of atomic phase, population, and frequency shift. On the other hand, the interference between two kinds of scattering fields by Rayleigh scattering and dipole transition modifies the photon statistics (second-order autocorrelation function) of output fields, showing a strong wavelength dependence. This study provides guidance for the solid-state emitter acting as a single-photon source and can be extended to explore the scattering effect in many-body physics.

Small-angle scattering studies show distinct conformations of calmodulin in its complexes with two peptides based on the regulatory domain of the catalytic subunit of phosphorylase kinase

International Nuclear Information System (INIS)

Trewhella, J.; Blumenthal, D.K.; Rokop, S.E.; Seeger, P.A.

1990-01-01

Small-angle X-ray and neutron scattering have been used to study the solution structures of calmodulin complexed with synthetic peptides corresponding to residues 342-366 and 301-326, designated PhK5 and PhK13, respectively, in the regulatory domain of the catalytic subunit of skeletal muscle phosphorylase kinase. The scattering data show that binding of PhK5 to calmodulin induces a dramatic contraction of calmodulin, similar to that previously observed when calmodulin is complexed with the calmodulin-binding domain peptide from rabbit skeletal muscle myosin light chain kinase. In contrast, calmodulin remains extended upon binding PhK13. In the presence of both peptides, calmodulin also remains extended. Apparently, the presence of PhK13 inhibits calmodulin from undergoing the PhK5-induced contraction. These data indicate that there is a fundamentally different type of calmodulin-target enzyme interaction in the case of the catalytic subunit of phosphorylase kinase compared with that for myosin light chain kinase

Resonant neutrino scattering: An impossible experiment?

International Nuclear Information System (INIS)

Suzuki, D.; Sumikama, T.; Ogura, M.; Mittig, W.; Shiraki, A.; Ichikawa, Y.; Kimura, H.; Otsu, H.; Sakurai, H.; Nakai, Y.; Hussein, M.S.

2010-01-01

The experimental feasibility was investigated for the resonant scattering of monoenergetic neutrinos emitted in the two-body β decay. A simple general formula shows that the resonance cross section can be as large as of the order of 10 -17 cm 2 . The Moessbauer setup using a solid crystal was examined with a focus on the electronic structure of the emitter and the absorber. Based on realistic calculations, we show that interactions of valence electrons in the solid lead to a level broadening of the atomic ground state, which considerably suppresses the resonant scattering of neutrinos.

Direct Calculation of the Scattering Amplitude Without Partial Wave Analysis

Science.gov (United States)

Shertzer, J.; Temkin, A.; Fisher, Richard R. (Technical Monitor)

2001-01-01

Two new developments in scattering theory are reported. We show, in a practical way, how one can calculate the full scattering amplitude without invoking a partial wave expansion. First, the integral expression for the scattering amplitude f(theta) is simplified by an analytic integration over the azimuthal angle. Second, the full scattering wavefunction which appears in the integral expression for f(theta) is obtained by solving the Schrodinger equation with the finite element method (FEM). As an example, we calculate electron scattering from the Hartree potential. With minimal computational effort, we obtain accurate and stable results for the scattering amplitude.

Q-space analysis of scattering by particles: A review

International Nuclear Information System (INIS)

Sorensen, Christopher M.

2013-01-01

This review describes and demonstrates the Q-space analysis of light scattering by particles. This analysis involves plotting the scattered intensity versus the scattering wave vector q=(4π/λ)sin(θ/2) on a double log plot. The analysis uncovers power law descriptions of the scattering with length scale dependent crossovers between the power laws. It also systematically describes the magnitude of the scattering and the interference ripple structure that often underlies the power laws. It applies to scattering from dielectric spheres of arbitrary size and refractive index (Mie scattering), fractal aggregates and irregularly shaped particles such as dusts. The benefits of Q-space analysis are that it provides a simple and comprehensive description of scattering in terms of power laws with quantifiable exponents; it can be used to differentiate scattering by particles of different shapes, and it yields a physical understanding of scattering based on diffraction. -- Highlights: ► Angular scattering functions for spheres show power laws versus the wave vector q. ► The power laws uncover patterns involving length scales and functionalities. ► Similar power laws appear in scattering from aggregates and irregular particles. ► Power laws provide a comprehensive and quantitative description of scattering

Diffusive scattering of electrons by electron holes around injection fronts

Science.gov (United States)

Vasko, I. Y.; Agapitov, O. V.; Mozer, F. S.; Artemyev, A. V.; Krasnoselskikh, V. V.; Bonnell, J. W.

2017-03-01

Van Allen Probes have detected nonlinear electrostatic spikes around injection fronts in the outer radiation belt. These spikes include electron holes (EH), double layers, and more complicated solitary waves. We show that EHs can efficiently scatter electrons due to their substantial transverse electric fields. Although the electron scattering driven by EHs is diffusive, it cannot be evaluated via the standard quasi-linear theory. We derive analytical formulas describing local electron scattering by a single EH and verify them via test particle simulations. We show that the most efficiently scattered are gyroresonant electrons (crossing EH on a time scale comparable to the local electron gyroperiod). We compute bounce-averaged diffusion coefficients and demonstrate their dependence on the EH spatial distribution (latitudinal extent and spatial filling factor) and individual EH parameters (amplitude of electrostatic potential, velocity, and spatial scales). We show that EHs can drive pitch angle scattering of ≲5 keV electrons at rates 10-2-10-4 s-1 and, hence, can contribute to electron losses and conjugated diffuse aurora brightenings. The momentum and pitch angle scattering rates can be comparable, so that EHs can also provide efficient electron heating. The scattering rates driven by EHs at L shells L ˜ 5-8 are comparable to those due to chorus waves and may exceed those due to electron cyclotron harmonics.

Light scattering reviews 8 radiative transfer and light scattering

CERN Document Server

Kokhanovsky, Alexander A

2013-01-01

Light scattering review (vol 8) is aimed at the presentation of recent advances in radiative transfer and light scattering optics. The topics to be covered include: scattering of light by irregularly shaped particles suspended in atmosphere (dust, ice crystals), light scattering by particles much larger as compared the wavelength of incident radiation, atmospheric radiative forcing, astrophysical radiative transfer, radiative transfer and optical imaging in biological media, radiative transfer of polarized light, numerical aspects of radiative transfer.

Ab initio calculation of scattering length and cross sections at very low energies for electron-helium scattering

International Nuclear Information System (INIS)

Saha, H.P.

1993-01-01

The multiconfiguration Hartree-Fock method for continuum wave functions has been used to calculate the scattering length and phase shifts over extremely low energies ranging from 0 to 1 eV very accurately for electron-helium scattering. The scattering length is calculated very accurately with wave functions computed exactly at zero energy, resulting in an upper bound of 1.1784. The electron correlation and polarization of the target by the scattering electron, which are very important in these calculations, have been taken into account in an accurate ab initio manner through the configuration-interaction procedure by optimizing both bound and continuum orbitals simultaneously at each kinetic energy of the scattered electron. Detailed results for scattering length, differential, total, and momentum-transfer cross sections obtained from the phase shifts are presented. The present scattering length is found to be in excellent agreement with the experimental result of Andrick and Bitsch [J. Phys. B 8, 402 (1975)] and the theoretical result of O'Malley, Burke, and Berrington [J. Phys. B 12, 953 (1979)]. There is excellent agreement between the present total cross sections and the corresponding experimental measurements of Buckman and Lohmann [J. Phys. B 19, 2547 (1986)]. The present momentum-transfer cross sections also show remarkable agreement with the experimental results of Crompton, Elford, and Robertson [Aust. J. Phys. 23, 667 (1970)

Scattering of accelerated wave packets

Science.gov (United States)

Longhi, S.; Horsley, S. A. R.; Della Valle, G.

2018-03-01

Wave-packet scattering from a stationary potential is significantly modified when the wave packet is subject to an external time-dependent force during the interaction. In the semiclassical limit, wave-packet motion is simply described by Newtonian equations, and the external force can, for example, cancel the potential force, making a potential barrier transparent. Here we consider wave-packet scattering from reflectionless potentials, where in general the potential becomes reflective when probed by an accelerated wave packet. In the particular case of the recently introduced class of complex Kramers-Kronig potentials we show that a broad class of time-dependent forces can be applied without inducing any scattering, while there is a breakdown of the reflectionless property when there is a broadband distribution of initial particle momentum, involving both positive and negative components.

Kerr scattering coefficients via isomonodromy

Energy Technology Data Exchange (ETDEWEB)

Cunha, Bruno Carneiro da [Departamento de Física, Universidade Federal de Pernambuco,50670-901, Recife, Pernambuco (Brazil); Novaes, Fábio [International Institute of Physics, Federal University of Rio Grande do Norte,Av. Odilon Gomes de Lima 1722, Capim Macio, Natal-RN 59078-400 (Brazil)

2015-11-23

We study the scattering of a massless scalar field in a generic Kerr background. Using a particular gauge choice based on the current conservation of the radial equation, we give a generic formula for the scattering coefficient in terms of the composite monodromy parameter σ between the inner and the outer horizons. Using the isomonodromy flow, we calculate σ exactly in terms of the Painlevé V τ-function. We also show that the eigenvalue problem for the angular equation (spheroidal harmonics) can be calculated using the same techniques. We use recent developments relating the Painlevé V τ-function to Liouville irregular conformal blocks to claim that this scattering problem is solved in the combinatorial sense, with known expressions for the τ-function near the critical points.

Stabilization of silver nanoparticles in nonanoic acid: A temperature activated conformation reaction observed with surface enhanced Raman spectroscopy

International Nuclear Information System (INIS)

Henneke, Dale E.; Malyavanatham, Gokul; Kovar, Desiderio; O'Brien, D.T.; Becker, M.F.; Nichols, William T.; Keto, J.W.

2003-01-01

Silver nanoparticles were synthesized by ultraviolet (λ=248 nm) laser ablation of an aerosol of micron-sized source particles entrained in nitrogen. As a result of thermionic electron emission and photoionization, nanoparticles produced in this manner were highly charged. The resulting aerosol was primarily composed of nanometer sized particles. The charged nanoparticles were deflected by an electric field that was perpendicular to the aerosol flow. Deflected nanoparticles were deposited directly into n-nonanoic acid flowing along the negative collection electrode. Suspensions of nanoparticles collected in this manner were dark gray in color and were found to be flocculated. When the suspensions were heated to temperatures above 75 deg. C, a color change from gray to clear was observed. Ultraviolet/visible extinction spectroscopy was performed on each suspension following annealing at different temperatures and times. By modeling the absorption decrease as a first order reaction, a good fit for the data was found. Analysis by dynamic light scattering (DLS) showed that the initial mean flocculent size of the gray suspensions was 602 nm. DLS analysis of the suspensions taken at different annealing intervals showed that the flocculent size decreased, but maintained a narrow size distribution until the size shrank below the instrument resolution limit. The reduction in flocculent size coincided with the observed color change, and an irreversible transition to a deflocculated primary nanoparticle suspension is observed. Surface enhanced Raman scattering is used to confirm that the reaction results from a change in the orientation of the nonanoic molecule on the surface of the nanoparticle

Isolation and initial structural characterization of a 27 kDa protein from Zingiber officinale

Science.gov (United States)

Rasheed, Saima; Malik, Shoaib Ahmad; Falke, Sven; Arslan, Ali; Fazel, Ramin; Schlüter, Hartmut; Betzel, Christian; Choudhary, M. Iqbal

2018-03-01

Zingiber officinale Roscoe (Ginger) is a widely used traditional medicinal plant (for different ailments such as arthritis, constipation, and hypertension). This article describes the isolation and characterization of a so far unknown protein from ginger rhizomes applying ion exchange, affinity, size-exclusion chromatography, small angle X-ray scattering (SAXS), and mass spectrometry techniques. One-dimensional Coomassie-stained SDS-PAGE was performed under non-reducing conditions, showing one band corresponding to approx. 27 kDa. Dynamic light scattering (DLS) analysis of the protein solution revealed monodispersity and a monomeric state of the purified protein. Circular dichroism (CD) spectroscopy strongly indicated a β-sheet-rich protein, and disordered regions. MALDI-TOF-MS, and LC-MS/MS analysis resulted in the identification of 27.29 kDa protein, having 32.13% and 25.34% sequence coverage with Zingipain-1 and 2, respectively. The monomeric state and molecular weight were verified by small angle X-ray scattering (SAXS) studies. An elongated ab-initio model was calculated based on the scattering intensity distribution.

Neutron scattering. Lectures

Energy Technology Data Exchange (ETDEWEB)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner (eds.)

2010-07-01

The following topics are dealt with: Neutron sources, neutron properties and elastic scattering, correlation functions measured by scattering experiments, symmetry of crystals, applications of neutron scattering, polarized-neutron scattering and polarization analysis, structural analysis, magnetic and lattice excitation studied by inelastic neutron scattering, macromolecules and self-assembly, dynamics of macromolecules, correlated electrons in complex transition-metal oxides, surfaces, interfaces, and thin films investigated by neutron reflectometry, nanomagnetism. (HSI)

Neutron scattering. Lectures

International Nuclear Information System (INIS)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner

2010-01-01

The following topics are dealt with: Neutron sources, neutron properties and elastic scattering, correlation functions measured by scattering experiments, symmetry of crystals, applications of neutron scattering, polarized-neutron scattering and polarization analysis, structural analysis, magnetic and lattice excitation studied by inelastic neutron scattering, macromolecules and self-assembly, dynamics of macromolecules, correlated electrons in complex transition-metal oxides, surfaces, interfaces, and thin films investigated by neutron reflectometry, nanomagnetism. (HSI)

Coupling between scattering channels with SUSY transformations for equal thresholds

International Nuclear Information System (INIS)

Pupasov, Andrey M; Samsonov, Boris F; Sparenberg, Jean-Marc; Baye, Daniel

2009-01-01

Supersymmetric (SUSY) transformations of the multichannel Schroedinger equation with equal thresholds and arbitrary partial waves in all channels are studied. The structures of the transformation function and the superpotential are analysed. Relations between Jost and scattering matrices of superpartner potentials are obtained. In particular, we show that a special type of SUSY transformation allows us to introduce a coupling between scattering channels starting from a potential with an uncoupled scattering matrix. The possibility for this coupling to be trivial is discussed. We show that the transformation introduces bound and virtual states with a definite degeneracy at the factorization energy. A detailed study of the potential and scattering matrices is given for the 2 x 2 case. The possibility of inverting coupled-channel scattering data by such a SUSY transformation is demonstrated by several examples (s-s, s-p and s-d partial waves)

Neutron scattering. Lectures

International Nuclear Information System (INIS)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner

2013-01-01

The following topics are dealt with: Neutron sources, symmetry of crystals, nanostructures investigated by small-angle neutron scattering, structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic neutron scattering, strongly correlated electrons, polymer dynamics, applications of neutron scattering. (HSI)

Fe{sub 3}O{sub 4}/salicylic acid nanoparticles versatility in magnetic mediated vascular nanoblockage

Energy Technology Data Exchange (ETDEWEB)

Mîndrilă, I., E-mail: tutu0101@yahoo.com [University of Medicine and Pharmacy of Craiova, Faculty of Medicine (Romania); Buteică, S. A. [University of Medicine and Pharmacy of Craiova, Faculty of Pharmacy (Romania); Mihaiescu, D. E.; Badea, G.; Fudulu, A. [Politehnica University of Bucharest, Faculty of Applied Chemistry and Material Science (Romania); Mărgăritescu, D. N. [University of Medicine and Pharmacy of Craiova, Faculty of Medicine (Romania)

2016-01-15

An aqueous dispersion of Fe{sub 3}O{sub 4}/salicylic acid magnetic nanoparticles (SaMNPs) was synthesized by a modified Massart method, characterized by Inductively Coupled Plasma–Optic Emission Spectrometry (ICP-OES), High-Resolution Transmission Electron Microscopy (HRTEM) and Dynamic Light Scattering (DLS) methods, and tested on the chick chorioallantoic membrane (CAM) model to evaluate biocompatibility, biodistribution, intravascular time persistence, and ability to be magnetically target driven in order to block the blood supply into a tumor xenograft. ICP-OES, DLS, and HRTEM SaMNPs sample analyses showed a 0.356 mg/mL Fe concentration, a good stability in water (average Zeta potential of 39.3 mV), a hydrodynamic diameter around 52 nm and a core diameter in the 7–15 nm range for the Fe{sub 3}O{sub 4} nanoparticles. In vivo CAM assay showed that SaMNPs were biocompatible with the chick embryo, were fixed almost completely by the liver, had no embolic potential, and a threshold-dose-dependent intravascular magnetic targeting time. Study on the CAM tumor model showed that SaMNPs could be used for long-term magnetically mediated nanoblocking of the capillary networks and 70-µm smaller arterioles.

Neutron scattering. Lectures

Energy Technology Data Exchange (ETDEWEB)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner [eds.

2010-07-01

The following topics are dealt with: Neutron sources, symmetry of crystals, diffraction, nanostructures investigated by small-angle neutron scattering, the structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic scattering, strongly correlated electrons, dynamics of macromolecules, applications of neutron scattering. (HSI)

Neutron scattering. Lectures

International Nuclear Information System (INIS)

Brueckel, Thomas; Heger, Gernot; Richter, Dieter; Roth, Georg; Zorn, Reiner

2010-01-01

The following topics are dealt with: Neutron sources, symmetry of crystals, diffraction, nanostructures investigated by small-angle neutron scattering, the structure of macromolecules, spin dependent and magnetic scattering, structural analysis, neutron reflectometry, magnetic nanostructures, inelastic scattering, strongly correlated electrons, dynamics of macromolecules, applications of neutron scattering. (HSI)

Effects of carboxylic acids on nC60 aggregate formation

International Nuclear Information System (INIS)

Chang Xiaojun; Vikesland, Peter J.

2009-01-01

The discovery that negatively charged aggregates of C 60 fullerene (nC 60 ) are stable in water has raised concerns regarding the potential environmental and health effects of these aggregates. In this work, we show that nC 60 aggregates produced by extended mixing in the presence of environmentally relevant carboxylic acids (acetic acid, tartaric acid, citric acid) have surface charge and morphologic properties that differ from those produced by extended mixing in water alone. In general, aggregates formed in the presence of these acids have a more negative surface charge and are more homogeneous than those produced in water alone. Carboxylic acid identity, solution pH, and sodium ion concentration, which are all intricately coupled, play an important role in setting the measured surface charge. Comparisons between particle sizes determined by analysis of TEM images and those obtained by dynamic light scattering (DLS) indicate that DLS results require careful evaluation when used to describe nC 60 aggregates. - The effects of carboxylic acids on the formation of nC 60 aggregates are discussed

Quantum scattering of neon from a nanotextured surface

International Nuclear Information System (INIS)

Levi, A C; Huang, C; Allison, W; MacLaren, D A

2009-01-01

Phonon exchange is the usual cause of decoherence in atom-surface scattering. By including quantum effects in the treatment of Debye-Waller scattering, we show that phonon exchange becomes ineffective when the relevant phonon frequencies are high. The result explains the surprising observation of strong elastic scattering of Ne from a Cu(100) surface nanotextured with a c(2 x 2) Li adsorbate structure. We extend a previous model to describe the phonon spectra by an Einstein oscillator component with an admixture of a Debye spectrum. The Einstein oscillator represents the dominant, high frequency vibration of the adsorbate, normal to the surface, while the Debye spectrum represents the substrate contribution. Neon scattering is so slow that exciting the adsorbate mode has a low probability and is impossible if the incident energy is below the threshold. Thus, adsorbate vibrations are averaged out. A theoretical discussion and calculation shows that under such circumstances the vibrations of a light adsorbate do not contribute to the Debye-Waller effect, with the result that Ne scattering at thermal energies is quantum mechanical and largely elastic, explaining the high reflectivity and the diffraction peaks observed experimentally.

Gamma-ray scatter methods applied to industrial measurement systems

Energy Technology Data Exchange (ETDEWEB)

Holstad, Marie Bueie

2004-09-01

Throughout the work presented in this dissertation it has been confirmed that the use of scattered gamma-radiation is a complex but useful tool in industrial measurement science. Scattered radiation has shown to be useful both when traditional measurement principles cannot be used (Chapter 4) and when more information about a system is needed than what is obtained with transmission measurements (Chapter 6). All three main projects (Chapters 4, 5 and 6) confirm that the sensitivity and accuracy of systems based on scattered gamma-radiation depends strongly on the geometry of the setup and that that presence of multiple scattered radiation makes the problems complex. Chapter 4 shows that multiple scattered gamma-radiation can be used for detection of changes in density where the dimensions are too large to use transmitted radiation. There is, however, an upper limit on the thickness of the absorbing medium also when scattered radiation is utilized. As seen in Chapter 5, multiple scattered gamma-radiation can in principle also be used in level gauges with very compact measurement geometries. The main challenges are the sensitivity to interfaces between materials with similar densities and low count rate. These challenges could not be overcome for level measurements in gravitational separator tanks. The results presented in Chapter 6 show that it is feasible to combine transmission and scatter measurements to characterize produced water in the oil and gas industry. (Author)

Two-Loop Scattering Amplitudes from the Riemann Sphere

CERN Document Server

Geyer, Yvonne; Monteiro, Ricardo; Tourkine, Piotr

2016-01-01

The scattering equations give striking formulae for massless scattering amplitudes at tree level and, as shown recently, at one loop. The progress at loop level was based on ambitwistor string theory, which naturally yields the scattering equations. We proposed that, for ambitwistor strings, the standard loop expansion in terms of the genus of the worldsheet is equivalent to an expansion in terms of nodes of a Riemann sphere, with the nodes carrying the loop momenta. In this paper, we show how to obtain two-loop scattering equations with the correct factorization properties. We adapt genus-two integrands from the ambitwistor string to the nodal Riemann sphere and show that these yield correct answers, by matching standard results for the four-point two-loop amplitudes of maximal supergravity and super-Yang-Mills theory. In the Yang-Mills case, this requires the loop analogue of the Parke-Taylor factor carrying the colour dependence, which includes non-planar contributions.

Scattered P'P' waves observed at short distances

Science.gov (United States)

Earle, Paul S.; Rost, Sebastian; Shearer, Peter M.; Thomas, Christine

2011-01-01

We detect previously unreported 1 Hz scattered waves at epicentral distances between 30° and 50° and at times between 2300 and 2450 s after the earthquake origin. These waves likely result from off-azimuth scattering of PKPbc to PKPbc in the upper mantle and crust and provide a new tool for mapping variations in fine-scale (10 km) mantle heterogeneity. Array beams from the Large Aperture Seismic Array (LASA) clearly image the scattered energy gradually emerging from the noise and reaching its peak amplitude about 80 s later, and returning to the noise level after 150 s. Stacks of transverse versus radial slowness (ρt, ρr) show two peaks at about (2, -2) and (-2,-2) s/°, indicating the waves arrive along the major arc path (180° to 360°) and significantly off azimuth. We propose a mantle and surface PKPbc to PKPbc scattering mechanism for these observations because (1) it agrees with the initiation time and distinctive slowness signature of the scattered waves and (2) it follows a scattering path analogous to previously observed deep-mantle PK•KP scattering (Chang and Cleary, 1981). The observed upper-mantle scattered waves and PK•KP waves fit into a broader set of scattered waves that we call P′•d•P′, which can scatter from any depth, d, in the mantle.

Certain theories of multiple scattering in random media of discrete scatterers

International Nuclear Information System (INIS)

Olsen, R.L.; Kharadly, M.M.Z.; Corr, D.G.

1976-01-01

New information is presented on the accuracy of the heuristic approximations in two important theories of multiple scattering in random media of discrete scatterers: Twersky's ''free-space'' and ''two-space scatterer'' formalisms. Two complementary approaches, based primarily on a one-dimensional model and the one-dimensional forms of the theories, are used. For scatterer distributions of low average density, the ''heuristic'' asymptotic forms for the coherent field and the incoherent intensity are compared with asymptotic forms derived from a systematic analysis of the multiple scattering processes. For distributions of higher density, both in the average number of scatterers per wavelength and in the degree of packing of finite-size scatterers, the analysis is carried out ''experimentally'' by means of a Monte Carlo computer simulation. Approximate series expressions based on the systematic approach are numerically evaluated along with the heuristic expressions. The comparison (for both forward- and back-scattered field moments) is made for the worst-case conditions of strong multiple scattering for which the theories have not previously been evaluated. Several significant conclusions are drawn which have certain practical implications: in application of the theories to describe some of the scattering phenomena which occur in the troposphere, and in the further evaluation of the theories using experiments on physical models

Scattering cross section for various potential systems

Directory of Open Access Journals (Sweden)

Myagmarjav Odsuren

2017-08-01

Full Text Available We discuss the problems of scattering in this framework, and show that the applied method is very useful in the investigation of the effect of the resonance in the observed scattering cross sections. In this study, not only the scattering cross sections but also the decomposition of the scattering cross sections was computed for the α–α system. To obtain the decomposition of scattering cross sections into resonance and residual continuum terms, the complex scaled orthogonality condition model and the extended completeness relation are used. Applying the present method to the α–α and α–n systems, we obtained good reproduction of the observed phase shifts and cross sections. The decomposition into resonance and continuum terms makes clear that resonance contributions are dominant but continuum terms and their interference are not negligible. To understand the behavior of observed phase shifts and the shape of the cross sections, both resonance and continuum terms are calculated.

Photon scattering by the giant dipole resonance

International Nuclear Information System (INIS)

Bowles, T.J.; Holt, R.J.; Jackson, H.E.; McKeown, R.D.; Specht, J.R.

1979-01-01

Although many features of the giant dipole resonance are well known, the coupling between the basic dipole oscillation and other nuclear collective degrees of freedom such as surface vibrations and rotations is poorly understood. This aspect was investigated by elastic and inelastic bremsstrahlung scattering of tagged photons over the energy range 15 to 22 MeV. Target nuclei were 60 Ni, 52 Cr, 56 Fe, 92 Mo, and 96 Mo. Scattering and absorption cross sections are tabulated, along with parameters obtained from a two-Lorentzian analysis of the scattering cross sections; measured spectra are shown. It was necessary to remove Thomson scattering from the experimental results. It was found that coupling to surface vibrations in the giant dipole resonance is much weaker than the dynamic collective model suggests. The elastic scattering cross section for all targets but 60 Ni showed structure that is not evident in the absorption cross section measurement. 12 figures, 2 tables

Scattering cross section for various potential systems

Energy Technology Data Exchange (ETDEWEB)

Odsuren, Myagmarjav; Khuukhenkhuu, Gonchigdorj; Davaa, Suren [Nuclear Research Center, School of Engineering and Applied Sciences, National University of Mongolia, Ulaanbaatar (Mongolia); Kato, Kiyoshi [Nuclear Reaction Data Centre, Faculty of Science, Hokkaido University, Sapporo (Japan)

2017-08-15

We discuss the problems of scattering in this framework, and show that the applied method is very useful in the investigation of the effect of the resonance in the observed scattering cross sections. In this study, not only the scattering cross sections but also the decomposition of the scattering cross sections was computed for the α–α system. To obtain the decomposition of scattering cross sections into resonance and residual continuum terms, the complex scaled orthogonality condition model and the extended completeness relation are used. Applying the present method to the α–α and α–n systems, we obtained good reproduction of the observed phase shifts and cross sections. The decomposition into resonance and continuum terms makes clear that resonance contributions are dominant but continuum terms and their interference are not negligible. To understand the behavior of observed phase shifts and the shape of the cross sections, both resonance and continuum terms are calculated.

Monoacyl phosphatidylcholine inhibits the formation of lipid multilamellar structures during in vitro lipolysis of self-emulsifying drug delivery systems.

Science.gov (United States)

Tran, Thuy; Siqueira, Scheyla D V S; Amenitsch, Heinz; Rades, Thomas; Müllertz, Anette

2017-10-15

The colloidal structures formed during lipolysis of self-emulsifying drug delivery systems (SEDDS) might affect the solubilisation and possibly the absorption of drugs. The aim of the current study is to elucidate the structures formed during the in vitro lipolysis of four SEDDS containing medium-chain glycerides and caprylocaproyl polyoxyl-8 glycerides (Labrasol), with or without monoacyl phosphatidylcholine (MAPC). In situ synchrotron small-angle X-ray scattering (SAXS) was combined with ex situ cryogenic transmission electron microscopy (cryo-TEM) and dynamic light scattering (DLS) to elucidate the generated structures. The SAXS scattering curves obtained during the lipolysis of MAPC-free SEDDS containing 43-60% w/w Labrasol displayed a lamellar phase peak at q=2.13nm -1 that increased with Labrasol concentration, suggesting the presence of multilamellar structures (MLS) with a d-spacing of 2.95nm. However, SEDDS containing 20-30% w/w MAPC did not form MLS during the lipolysis. The cryo-TEM and DLS studies showed that MAPC-free SEDDS formed coarse emulsions while MAPC-containing SEDDS formed nanoemulsions during the dispersion in digestion medium. From the first minute and during the entire lipolysis process, SEDDS both with and without MAPC generated uni-, bi-, and oligo-lamellar vesicles. The lipolysis kinetics in the first minutes of the four SEDDS correlated with an increased intensity of the SAXS curves and the rapid transformation from lipid droplets to vesicles observed by cryo-TEM. In conclusion, the study elucidates the structures formed during in vitro lipolysis of SEDDS and the inhibitory effect of MAPC on the formation of MLS. Copyright © 2016 Elsevier B.V. All rights reserved.

Multimodal Dispersion of Nanoparticles: A Comprehensive Evaluation of Size Distribution with 9 Size Measurement Methods.

Science.gov (United States)

Varenne, Fanny; Makky, Ali; Gaucher-Delmas, Mireille; Violleau, Frédéric; Vauthier, Christine

2016-05-01

Evaluation of particle size distribution (PSD) of multimodal dispersion of nanoparticles is a difficult task due to inherent limitations of size measurement methods. The present work reports the evaluation of PSD of a dispersion of poly(isobutylcyanoacrylate) nanoparticles decorated with dextran known as multimodal and developed as nanomedecine. The nine methods used were classified as batch particle i.e. Static Light Scattering (SLS) and Dynamic Light Scattering (DLS), single particle i.e. Electron Microscopy (EM), Atomic Force Microscopy (AFM), Tunable Resistive Pulse Sensing (TRPS) and Nanoparticle Tracking Analysis (NTA) and separative particle i.e. Asymmetrical Flow Field-Flow Fractionation coupled with DLS (AsFlFFF) size measurement methods. The multimodal dispersion was identified using AFM, TRPS and NTA and results were consistent with those provided with the method based on a separation step prior to on-line size measurements. None of the light scattering batch methods could reveal the complexity of the PSD of the dispersion. Difference between PSD obtained from all size measurement methods tested suggested that study of the PSD of multimodal dispersion required to analyze samples by at least one of the single size particle measurement method or a method that uses a separation step prior PSD measurement.

Quantum graphs: a simple model for chaotic scattering

International Nuclear Information System (INIS)

Kottos, Tsampikos; Smilansky, Uzy

2003-01-01

We connect quantum graphs with infinite leads, and turn them into scattering systems. We show that they display all the features which characterize quantum scattering systems with an underlying classical chaotic dynamics: typical poles, delay time and conductance distributions, Ericson fluctuations, and when considered statistically, the ensemble of scattering matrices reproduces quite well the predictions of the appropriately defined random matrix ensembles. The underlying classical dynamics can be defined, and it provides important parameters which are needed for the quantum theory. In particular, we derive exact expressions for the scattering matrix, and an exact trace formula for the density of resonances, in terms of classical orbits, analogous to the semiclassical theory of chaotic scattering. We use this in order to investigate the origin of the connection between random matrix theory and the underlying classical chaotic dynamics. Being an exact theory, and due to its relative simplicity, it offers new insights into this problem which is at the forefront of the research in chaotic scattering and related fields

Light scattering of thin azobenzene side-chain polyester layers

DEFF Research Database (Denmark)

Kerekes, Á.; Lörincz, E.; Ramanujam, P.S.

2002-01-01

Light scattering properties of liquid crystalline and amorphous azobenzene side-chain polyester layers used for optical data storage were examined by means of transmissive scatterometry. Comparative experiments show that the amorphous polyester has significantly lower light scattering...... characteristics than the liquid crystalline polyester. The amorphous samples have negligible polarization part orthogonal to the incident beam. the liquid crystalline samples have relative high orthogonal polarization part in light scattering, The light scattering results can be used to give a lower limit...... for the domain size in thin liquid crystalline polyester layers being responsible for the dominant light scattering. The characteristic domain Sizes obtained from the Fourier transformation of polarization microscopic Pictures confirm these values....

Concise formulation of the three-dimensional multiple-scattering theory.

Science.gov (United States)

Oyhenart, Laurent; Vignéras, Valérie

2012-08-01

The scattering of an electromagnetic wave by a set of dielectric and metallic spheres is a well-known physical problem. We show a mathematical simplification of the multiple-scattering theory. In this paper, we will establish the multiple-scattering equation in two different ways. Through the study of the equation form, we can choose the simplest spherical wave expansion for calculations. Then, we propose concise expressions of the Mie scattering coefficients and translation coefficients for both polarizations. With these simplified expressions, large spheres are studied without loss of accuracy. Far-field expressions, cross-sections, and the scattering matrix are also simplified. Thus, we obtain formulas that can be easily understood from a physical point of view.

Quantum scattering from classical field theory

International Nuclear Information System (INIS)

Gould, T.M.; Poppitz, E.R.

1995-01-01

We show that scattering amplitudes between initial wave packet states and certain coherent final states can be computed in a systematic weak coupling expansion about classical solutions satisfying initial-value conditions. The initial-value conditions are such as to make the solution of the classical field equations amenable to numerical methods. We propose a practical procedure for computing classical solutions which contribute to high energy two-particle scattering amplitudes. We consider in this regard the implications of a recent numerical simulation in classical SU(2) Yang-Mills theory for multiparticle scattering in quantum gauge theories and speculate on its generalization to electroweak theory. We also generalize our results to the case of complex trajectories and discuss the prospects for finding a solution to the resulting complex boundary value problem, which would allow the application of our method to any wave packet to coherent state transition. Finally, we discuss the relevance of these results to the issues of baryon number violation and multiparticle scattering at high energies. ((orig.))

Effective temperatures and scattering cross sections in water mixtures determined by Deep Inelastic Neutron Scattering

International Nuclear Information System (INIS)

Dawidowski, J.; Rodríguez Palomino, L.A.; Márquez Damián, J.I.; Blostein, J.J.; Cuello, G.J.

2016-01-01

Highlights: • Effective temperatures of atoms can be determined by the DINS technique. • This is the first time that such application of this experimental technique is made. • This technique is able to measure the known cross sections of the atoms. • No anomalous cross section was found, at variance with Dreissmann’s et al. claims. - Abstract: The present work shows a series of results of Deep Inelastic Neutron Scattering (DINS) experiments on light and heavy water mixtures performed at the spectrometer VESUVIO (Rutherford Appleton Laboratory, UK) employing an analysis method based on the information provided by individual detectors in forward and backward scattering positions. We investigated the effective temperatures of the different atoms composing the samples, a magnitude of considerable interest for Nuclear Engineering. The peak intensities and their relation with the bound-atom cross sections is analyzed, showing a good agreement with tabulated values which supports the use of this technique as non-destructive mass spectrometry. Previous results in the determination of scattering cross sections by this technique (known in the literature) that were at variance with the present findings are commented.

Characterization of colloidal manganese hydroxylapatite: A potential magnetic resonance contrast agent

Science.gov (United States)

Dorshow, Richard B.; Kofi Adzamli, I.; Nosco, Dennis L.; Joslin, Frederick L.

1996-03-01

Particulate contrast agents for blood pool imaging need to be constructed with the appropriate particle size distribution (PSD), and need to be resistant to opsonization. Hence, the PSD of an aqueous colloidal suspension of polyethylene glycol (PEG)-stabilized manganese hydroxylapatite (potentially useful as a magnetic resonance contrast agent for blood pool imaging) has been investigated as a function of PEG concentration and molecular weight. At low PEG concentrations, dynamic light scattering (DLS) and sedimentation field flow fractionation measurements yield a broad PSD, with the largest particle diameters near 100nm. Flow field flow fractionation (FlFFF) measurements, however, yield a distinct population near 10nm, which is not readily detectable by the other two techniques. As the PEG concentration is increased, the PSD shifts toward the lower size population. At the highest PEG concentration employed, only particles of diameter 10nm remain, verified by both FlFFF and DLS. Thus, the search for an optimum PSD for blood pool imaging is facilitated by choice of PEG molecular weight and concentration, and by employing complementary use of light scattering and field flow fractionation techniques.

Magnetic diffuse scattering: a theorist's perspective

International Nuclear Information System (INIS)

Long, M.W.

1996-01-01

We attempt to show that magnetic diffuse scattering is the natural probe for frustrated antiferromagnetism. Comparison between nuclear and magnetic diffuse scattering compares the range of atomic clustering with the range of the magnetic impurity. At low temperature frustration is expected to lead to large differences which are a natural signature for the relevance of such frustration effects. We provide some elementary examples in first-row transition metals which display fairly dramatic effects. (author) 11 figs., tabs., 8 refs

Molecular-beam scattering

International Nuclear Information System (INIS)

Vernon, M.F.

1983-07-01

The molecular-beam technique has been used in three different experimental arrangements to study a wide range of inter-atomic and molecular forces. Chapter 1 reports results of a low-energy (0.2 kcal/mole) elastic-scattering study of the He-Ar pair potential. The purpose of the study was to accurately characterize the shape of the potential in the well region, by scattering slow He atoms produced by expanding a mixture of He in N 2 from a cooled nozzle. Chapter 2 contains measurements of the vibrational predissociation spectra and product translational energy for clusters of water, benzene, and ammonia. The experiments show that most of the product energy remains in the internal molecular motions. Chapter 3 presents measurements of the reaction Na + HCl → NaCl + H at collision energies of 5.38 and 19.4 kcal/mole. This is the first study to resolve both scattering angle and velocity for the reaction of a short lived (16 nsec) electronic excited state. Descriptions are given of computer programs written to analyze molecular-beam expansions to extract information characterizing their velocity distributions, and to calculate accurate laboratory elastic-scattering differential cross sections accounting for the finite apparatus resolution. Experimental results which attempted to determine the efficiency of optically pumping the Li(2 2 P/sub 3/2/) and Na(3 2 P/sub 3/2/) excited states are given. A simple three-level model for predicting the steady-state fraction of atoms in the excited state is included

Deuteron-deuteron elastic scattering at high energies

International Nuclear Information System (INIS)

Fazal-e-Aleem; Ali, S.

1991-01-01

The eikonal picture which has theoretical foundations in some areas of physics has been successful in explaining various aspects of elastic scattering at high energies. Chou and Yang first proposed a preliminary version of the eikonal model for hadron-hadron elastic scattering. The model is based on geometrical considerations in which hadrons are treated as extended objects. Elastic scattering then results from the propagation of attenuated wave function. By assuming that at high energies the scattering amplitude is purely imaginary and that the hadronic matter distribution is proportional to the charge distribution on protons, Durand and Lipes studied high energy pp scattering on the basis of this prestine model. Later on, the model was extended to other elastic reactions. However, a survey of literature shows that it has been successful only in the diffraction peak region. It has been shown that the pristine Chou-Yange model can explain the differential cross section for deuteron-deuteron elastic scattering at √s = 53 GeV in the diffraction peak region. In order to fit the large momentum transfer data, the generalized Chou-Yang model is used

Scattering theory of infrared divergent Pauli-Fierz Hamiltonians

CERN Document Server

Derezinski, J

2003-01-01

We consider in this paper the scattering theory of infrared divergent massless Pauli-Fierz Hamiltonians. We show that the CCR representations obtained from the asymptotic field contain so-called {\\em coherent sectors} describing an infinite number of asymptotically free bosons. We formulate some conjectures leading to mathematically well defined notion of {\\em inclusive and non-inclusive scattering cross-sections} for Pauli-Fierz Hamiltonians. Finally we give a general description of the scattering theory of QFT models in the presence of coherent sectors for the asymptotic CCR representations.

Scattering of light from small nematic spheres with radial dielectric anisotropy

International Nuclear Information System (INIS)

Karacali, H.; Risser, S.M.; Ferris, K.F.

1997-01-01

We have calculated the scattering cross sections of small anisotropic nematic droplets embedded in a polymer matrix as a function of the dielectric constants of the nematic and the polymer. We have derived the general form for the Helmholtz wave equation for a droplet which has spatially varying radial anisotropy, and have explicitly solved this equation for three distinct models of the dielectric anisotropy, including one model where the anisotropy increases linearly with droplet radius. Numerical calculations of the scattering amplitudes for droplets much smaller than the wavelength of the incident radiation show that droplets with continual variation in the dielectric anisotropy have much larger scattering amplitude than droplets with fixed anisotropy. The scattering from droplets with linearly varying anisotropy exhibits a scattering minimum for much smaller polymer dielectric constants than the other models. These results show that the scattering from small anisotropic droplets is sensitive to details of the internal structure and anisotropy of the droplet. copyright 1997 The American Physical Society

Software correction of scatter coincidence in positron CT

International Nuclear Information System (INIS)

Endo, M.; Iinuma, T.A.

1984-01-01

This paper describes a software correction of scatter coincidence in positron CT which is based on an estimation of scatter projections from true projections by an integral transform. Kernels for the integral transform are projected distributions of scatter coincidences for a line source at different positions in a water phantom and are calculated by Klein-Nishina's formula. True projections of any composite object can be determined from measured projections by iterative applications of the integral transform. The correction method was tested in computer simulations and phantom experiments with Positologica. The results showed that effects of scatter coincidence are not negligible in the quantitation of images, but the correction reduces them significantly. (orig.)

Learning from the scatter in type ia supernovae

Energy Technology Data Exchange (ETDEWEB)

Dodelson, Scott; /Fermilab /Chicago U., Astron. Astrophys. Ctr.; Vallinotto, Alberto; /Fermilab /Chicago U.

2005-11-01

Type Ia Supernovae are standard candles so their mean apparent magnitude has been exploited to learn about the redshift-distance relationship. Besides intrinsic scatter in this standard candle, additional scatter is caused by gravitational magnification by large scale structure. Here they probe the dependence of this dispersion on cosmological parameters and show that information about the amplitude of clustering, {sigma}{sub s}, is contained in the scatter. In principle, it will be possible to constrain {sigma}{sub s} to within 5% with observations of 2000 Type Ia Supernovae. They identify three sources of systematic error--evolution of intrinsic scatter, baryon contributions to lensing, and non-Gaussianity of lensing--which will make this measurement difficult.

The problem of scattering in fibre-fed VPH spectrographs and possible solutions

Science.gov (United States)

Ellis, S. C.; Saunders, Will; Betters, Chris; Croom, Scott

2014-07-01

All spectrographs unavoidably scatter light. Scattering in the spectral direction is problematic for sky subtraction, since atmospheric spectral lines are blurred. Scattering in the spatial direction is problematic for fibre fed spectrographs, since it limits how closely fibres can be packed together. We investigate the nature of this scattering and show that the scattering wings have both a Lorentzian component, and a shallower (1/r) component. We investigate the causes of this from a theoretical perspective, and argue that for the spectral PSF the Lorentzian wings are in part due to the profile of the illumination of the pupil of the spectrograph onto the diffraction grating, whereas the shallower component is from bulk scattering. We then investigate ways to mitigate the diffractive scattering by apodising the pupil. In the ideal case of a Gaussian apodised pupil, the scattering can be significantly improved. Finally we look at realistic models of the spectrograph pupils of fibre fed spectrographs with a centrally obstructed telescope, and show that it is possible to apodise the pupil through non-telecentric injection into the fibre.

A scattering model for rain depolarization

Science.gov (United States)

Wiley, P. H.; Stutzman, W. L.; Bostian, C. W.

1973-01-01

A method is presented for calculating the amount of depolarization caused by precipitation for a propagation path. In the model the effects of each scatterer and their interactions are accounted for by using a series of simplifying steps. It is necessary only to know the forward scattering properties of a single scatterer. For the case of rain the results of this model for attenuation, differential phase shift, and cross polarization agree very well with the results of the only other model available, that of differential attenuation and differential phase shift. Calculations presented here show that horizontal polarization is more sensitive to depolarization than is vertical polarization for small rain drop canting angle changes. This effect increases with increasing path length.

A neutron scattering study of DCN

International Nuclear Information System (INIS)

Mackenzie, G.A.; Pawley, G.S.

1979-01-01

Phonons in deuterium cyanide have been measured by neutron coherent inelastic scattering. The main subject of study was the transverse acoustic mode in the (110) direction polarised along (110) which is associated with the first-order structural phase transition at 160 K. Measurements have shown that the frequency decreases by about 25% between about 225 and 160 K as the transition temperature is approached. The other acoustic modes observable in the a*b* scattering plane have been measured and show no anomalous temperature dependence. Optic modes were unobservable because of the small size of the single-crystal sample which gave insufficient scattered intensity. Apart from the 'soft' mode, the measured frequencies are in good agreement with lattice dynamics calculations. (author)

Silver nanoparticles: Large scale solvothermal synthesis and optical properties

Energy Technology Data Exchange (ETDEWEB)

Wani, Irshad A.; Khatoon, Sarvari [Nanochemistry Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025 (India); Ganguly, Aparna [Nanochemistry Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025 (India); Department of Chemistry, Indian Institute of Technology, Hauz Khas, New Delhi 110016 (India); Ahmed, Jahangeer; Ganguli, Ashok K. [Department of Chemistry, Indian Institute of Technology, Hauz Khas, New Delhi 110016 (India); Ahmad, Tokeer, E-mail: tokeer.ch@jmi.ac.in [Nanochemistry Laboratory, Department of Chemistry, Jamia Millia Islamia, New Delhi 110025 (India)

2010-08-15

Silver nanoparticles have been successfully synthesized by a simple and modified solvothermal method at large scale using ethanol as the refluxing solvent and NaBH{sub 4} as reducing agent. The nanopowder was investigated by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), dynamic light scattering (DLS), UV-visible and BET surface area studies. XRD studies reveal the monophasic nature of these highly crystalline silver nanoparticles. Transmission electron microscopic studies show the monodisperse and highly uniform nanoparticles of silver of the particle size of 5 nm, however, the size is found to be 7 nm using dynamic light scattering which is in good agreement with the TEM and X-ray line broadening studies. The surface area was found to be 34.5 m{sup 2}/g. UV-visible studies show the absorption band at {approx}425 nm due to surface plasmon resonance. The percentage yield of silver nanoparticles was found to be as high as 98.5%.

Combined Dynamic Light Scattering and Raman Spectroscopy Approach for Characterizing the Aggregation of Therapeutic Proteins

Directory of Open Access Journals (Sweden)

E. Neil Lewis

2014-12-01

Full Text Available Determination of the physicochemical properties of protein therapeutics and their aggregates is critical for developing formulations that enhance product efficacy, stability, safety and manufacturability. Analytical challenges are compounded for materials: (1 that are formulated at high concentration, (2 that are formulated with a variety of excipients, and (3 that are available only in small volumes. In this article, a new instrument is described that measures protein secondary and tertiary structure, as well as molecular size, over a range of concentrations and formulation conditions of low volume samples. Specifically, characterization of colloidal and conformational stability is obtained through a combination of two well-established analytical techniques: dynamic light scattering (DLS and Raman spectroscopy, respectively. As the data for these two analytical modalities are collected on the same sample at the same time, the technique enables direct correlation between them, in addition to the more straightforward benefit of minimizing sample usage by providing multiple analytical measurements on the same aliquot non-destructively. The ability to differentiate between unfolding and aggregation that the combination of these techniques provides enables insights into underlying protein aggregation mechanisms. The article will report on mechanistic insights for aggregation that have been obtained from the application of this technique to the characterization of lysozyme, which was evaluated as a function of concentration and pH.

Diffractive scattering on nuclei in multiple scattering theory with inelastic screening

International Nuclear Information System (INIS)

Zoller, V.R.

1988-01-01

The cross sections for the diffractive scattering of hadrons on nuclei are calculated in the two-channel approximation of multiple scattering theory. In contrast to the standard Glauber approach, it is not assumed that the nucleon scattering profile is a Gaussian or that the Regge radius of the hadron is small compared to the nuclear radius. The AGK Reggeon diagrammatic technique is used to calculate the topological cross sections and the cross sections for coherent and incoherent diffractive dissociation and quasielastic scattering. The features of hadron-nucleus scattering at superhigh energies are discussed

Compton-scatter tissue densitometry: calculation of single and multiple scatter photon fluences

International Nuclear Information System (INIS)

Battista, J.J.; Bronskill, M.J.

1978-01-01

The accurate measurement of in vivo electron densities by the Compton-scatter method is limited by attenuations and multiple scattering in the patient. Using analytic and Monte Carlo calculation methods, the Clarke tissue density scanner has been modelled for incident monoenergetic photon energies from 300 to 2000 keV and for mean scattering angles of 30 to 130 degrees. For a single detector focussed to a central position in a uniform water phantom (25 x 25 x 25 cm 3 ) it has been demonstrated that: (1) Multiple scatter contamination is an inherent limitation of the Compton-scatter method of densitometry which can be minimised, but not eliminated, by improving the energy resolution of the scattered radiation detector. (2) The choice of the incident photon energy is a compromise between the permissible radiation dose to the patient and the tolerable level of multiple scatter contamination. For a mean scattering angle of 40 degrees, the intrinsic multiple-single scatter ratio decreases from 64 to 35%, and the radiation dose (per measurement) increases from 1.0 to 4.1 rad, as the incident photon energy increases from 300 to 2000 keV. These doses apply to a sampled volume of approximately 0.3 cm 3 and an electron density precision of 0.5%. (3) The forward scatter densitometer configuration is optimum, minimising both the dose and the multiple scatter contamination. For an incident photon energy of 1250 keV, the intrinsic multiple-single scatter ratio reduces from 122 to 27%, and the dose reduces from 14.3 to 1.2 rad, as the mean scattering angle decreases from 130 to 30 degrees. These calculations have been confirmed by experimental measurements. (author)

Numerical simulation of scattering wave imaging in a goaf

Institute of Scientific and Technical Information of China (English)

Li Juanjuan; Pan Dongming; Liao Taiping; Hu Mingshun; Wang Linlin

2011-01-01

Goafs are threats to safe mining. Their imaging effects or those of other complex geological bodies are often poor in conventional reflected wave images. Hence, accurate detection of goals has become an important problem, to be solved with a sense of urgency. Based on scattering theory, we used an equivalent offset method to extract Common Scattering Point gathers, in order to analyze different scattering wave characteristics between Common Scattering Point and Common Mid Point gathers and to compare stack and migration imaging effects. Our research results show that the scattering wave imaging method is more efficient than the conventional imaging method and is therefore a more effective imaging method for detecting goats and other complex geological bodies. It has important implications for safe mining procedures and infrastructures.

Rayleigh scattering and nonlinear inversion of elastic waves

Energy Technology Data Exchange (ETDEWEB)

Gritto, Roland [Univ. of California, Berkeley, CA (United States)

1995-12-01

Rayleigh scattering of elastic waves by an inclusion is investigated and the limitations determined. In the near field of the inhomogeneity, the scattered waves are up to a factor of 300 stronger than in the far field, excluding the application of the far field Rayleigh approximation for this range. The investigation of the relative error as a function of parameter perturbation shows a range of applicability broader than previously assumed, with errors of 37% and 17% for perturbations of -100% and +100%, respectively. The validity range for the Rayleigh limit is controlled by large inequalities, and therefore, the exact limit is determined as a function of various parameter configurations, resulting in surprisingly high values of up to k_pR = 0.9. The nonlinear scattering problem can be solved by inverting for equivalent source terms (moments) of the scatterer, before the elastic parameters are determined. The nonlinear dependence between the moments and the elastic parameters reveals a strong asymmetry around the origin, which will produce different results for weak scattering approximations depending on the sign of the anomaly. Numerical modeling of cross hole situations shows that near field terms are important to yield correct estimates of the inhomogeneities in the vicinity of the receivers, while a few well positioned sources and receivers considerably increase the angular coverage, and thus the model resolution of the inversion parameters. The pattern of scattered energy by an inhomogeneity is complicated and varies depending on the object, the wavelength of the incident wave, and the elastic parameters involved. Therefore, it is necessary to investigate the direction of scattered amplitudes to determine the best survey geometry.

Light Scattering by Ice Crystals Containing Air Bubbles

Science.gov (United States)

Zhang, J.; Panetta, R. L.; Yang, P.; Bi, L.

2014-12-01

The radiative effects of ice clouds are often difficult to estimate accurately, but are very important for interpretation of observations and for climate modeling. Our understanding of these effects is primarily based on scattering calculations, but due to the variability in ice habit it is computationally difficult to determine the required scattering and absorption properties, and the difficulties are only compounded by the need to include consideration of air and carbon inclusions of the sort frequently observed in collected samples. Much of the previous work on effects of inclusions in ice particles on scattering properties has been conducted with variants of geometric optics methods. We report on simulations of scattering by ice crystals with enclosed air bubbles using the pseudo-spectral time domain method (PSTD) and improved geometric optics method (IGOM). A Bouncing Ball Model (BBM) is proposed as a parametrization of air bubbles, and the results are compared with Monte Carlo radiative transfer calculations. Consistent with earlier studies, we find that air inclusions lead to a smoothing of variations in the phase function, weakening of halos, and a reduction of backscattering. We extend these studies by examining the effects of the particular arrangement of a fixed number of bubbles, as well as the effects of splitting a given number of bubbles into a greater number of smaller bubbles with the same total volume fraction. The result shows that the phase function will not change much for stochastic distributed air bubbles. It also shows that local maxima of phase functions are smoothed out for backward directions, when we break bubbles into small ones, single big bubble scatter favors more forward scattering than multi small internal scatters.

Very High Energy Neutron Scattering from Hydrogen

International Nuclear Information System (INIS)

Cowley, R A; Stock, C; Bennington, S M; Taylor, J; Gidopoulos, N I

2010-01-01

The neutron scattering from hydrogen in polythene has been measured with the direct time-of flight spectrometer, MARI, at the ISIS facility of the Rutherford Appleton Laboratory with incident neutron energies between 0.5 eV and 600 eV. The results of experiments using the spectrometer, VESUVIO, have given intensities from hydrogen containing materials that were about 60% of the intensity expected from hydrogen. Since VESUVIO is the only instrument in the world that routinely operates with incident neutron energies in the eV range we have chosen to measure the scattering from hydrogen at high incident neutron energies with a different type of instrument. The MARI, direct time-of-flight, instrument was chosen for the experiment and we have studied the scattering for several different incident neutron energies. We have learnt how to subtract the gamma ray background, how to calibrate the incident energy and how to convert the spectra to an energy plot . The intensity of the hydrogen scattering was independent of the scattering angle for scattering angles from about 5 degrees up to 70 degrees for at least 3 different incident neutron energies between 20 eV and 100 eV. When the data was put on an absolute scale, by measuring the scattering from 5 metal foils with known thicknesses under the same conditions we found that the absolute intensity of the scattering from the hydrogen was in agreement with that expected to an accuracy of ± 5.0% over a wide range of wave-vector transfers between 1 and 250 A -1 . These measurements show that it is possible to measure the neutron scattering with incident neutron energies up to at least 100 eV with a direct geometry time-of-flight spectrometer and that the results are in agreement with conventional scattering theory.

X-ray scattering signatures of β-thalassemia

International Nuclear Information System (INIS)

Desouky, Omar S.; Elshemey, Wael M.; Selim, Nabila S.

2009-01-01

X-ray scattering from lyophilized proteins or protein-rich samples is characterized by the presence of two characteristic broad peaks at scattering angles equivalent to momentum transfer values of 0.27 and 0.6 nm -1 , respectively. These peaks arise from the interference of coherently scattered photons. Once the conformation of a protein is changed, these two peaks reflect such change with considerable sensitivity. The present work examines the possibility of characterizing the most common cause of hemolytic anaemia in Egypt and many Mediterranean countries; β-thalassemia, from its X-ray scattering profile. This disease emerges from a genetic defect causing reduced rate in the synthesis of one of the globin chains that make up hemoglobin. As a result, structurally abnormal hemoglobin molecules are formed. In order to detect such molecular disorder, hemoglobin samples of β-thalassemia patients are collected, lyophilized and measured using a conventional X-ray diffractometer. Results show significant differences in the X-ray scattering profiles of most of the diseased samples compared to control. The shape of the first scattering peak at 0.27 nm -1 , in addition to the relative intensity of the first to the second scattering peaks, provides the most reliable signs of abnormality in diseased samples. The results are interpreted and confirmed with the aid of Fourier Transform Infrared (FTIR) spectroscopy of normal and thalassemia samples.

X-ray scattering signatures of β-thalassemia

Science.gov (United States)

Desouky, Omar S.; Elshemey, Wael M.; Selim, Nabila S.

2009-08-01

X-ray scattering from lyophilized proteins or protein-rich samples is characterized by the presence of two characteristic broad peaks at scattering angles equivalent to momentum transfer values of 0.27 and 0.6 nm -1, respectively. These peaks arise from the interference of coherently scattered photons. Once the conformation of a protein is changed, these two peaks reflect such change with considerable sensitivity. The present work examines the possibility of characterizing the most common cause of hemolytic anaemia in Egypt and many Mediterranean countries; β-thalassemia, from its X-ray scattering profile. This disease emerges from a genetic defect causing reduced rate in the synthesis of one of the globin chains that make up hemoglobin. As a result, structurally abnormal hemoglobin molecules are formed. In order to detect such molecular disorder, hemoglobin samples of β-thalassemia patients are collected, lyophilized and measured using a conventional X-ray diffractometer. Results show significant differences in the X-ray scattering profiles of most of the diseased samples compared to control. The shape of the first scattering peak at 0.27 nm -1, in addition to the relative intensity of the first to the second scattering peaks, provides the most reliable signs of abnormality in diseased samples. The results are interpreted and confirmed with the aid of Fourier Transform Infrared (FTIR) spectroscopy of normal and thalassemia samples.

X-ray scattering signatures of {beta}-thalassemia

Energy Technology Data Exchange (ETDEWEB)

Desouky, Omar S. [Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT) (Egypt); Elshemey, Wael M. [Biophysics Department, Faculty of Science, Cairo University (Egypt)], E-mail: waelelshemey@yahoo.com; Selim, Nabila S. [Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT) (Egypt)

2009-08-11

X-ray scattering from lyophilized proteins or protein-rich samples is characterized by the presence of two characteristic broad peaks at scattering angles equivalent to momentum transfer values of 0.27 and 0.6 nm{sup -1}, respectively. These peaks arise from the interference of coherently scattered photons. Once the conformation of a protein is changed, these two peaks reflect such change with considerable sensitivity. The present work examines the possibility of characterizing the most common cause of hemolytic anaemia in Egypt and many Mediterranean countries; {beta}-thalassemia, from its X-ray scattering profile. This disease emerges from a genetic defect causing reduced rate in the synthesis of one of the globin chains that make up hemoglobin. As a result, structurally abnormal hemoglobin molecules are formed. In order to detect such molecular disorder, hemoglobin samples of {beta}-thalassemia patients are collected, lyophilized and measured using a conventional X-ray diffractometer. Results show significant differences in the X-ray scattering profiles of most of the diseased samples compared to control. The shape of the first scattering peak at 0.27 nm{sup -1}, in addition to the relative intensity of the first to the second scattering peaks, provides the most reliable signs of abnormality in diseased samples. The results are interpreted and confirmed with the aid of Fourier Transform Infrared (FTIR) spectroscopy of normal and thalassemia samples.

Neutron scattering from polarised proton domains

CERN Document Server

Van den Brandt, B; Kohbrecher, J; Konter, J A; Mango, S; Glattli, H; Leymarie, E; Grillo, I; May, R P; Jouve, H; Stuhrmann, H B; Stuhrmann, H B; Zimmer, O

2002-01-01

Time-dependent small-angle polarised neutron scattering from domains of polarised protons has been observed at the onset of dynamic nuclear polarisation in a frozen solution of 98% deuterated glycerol-water at 1 K containing a small concentration of paramagnetic centres (EHBA-Cr sup V). Simultaneous NMR measurements show that the observed scattering arises from protons around the Cr sup V -ions which are polarised to approx 10% in a few seconds, much faster than the protons in the bulk. (authors)

X-Ray Temperatures, Luminosities, and Masses from XMM-Newton Follow-up of the First Shear-selected Galaxy Cluster Sample

Energy Technology Data Exchange (ETDEWEB)

Deshpande, Amruta J.; Hughes, John P. [Department of Physics and Astronomy, Rutgers the State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Wittman, David, E-mail: amrejd@physics.rutgers.edu, E-mail: jph@physics.rutgers.edu, E-mail: dwittman@physics.ucdavis.edu [Department of Physics, University of California, Davis, One Shields Avenue, Davis, CA 95616 (United States)

2017-04-20

We continue the study of the first sample of shear-selected clusters from the initial 8.6 square degrees of the Deep Lens Survey (DLS); a sample with well-defined selection criteria corresponding to the highest ranked shear peaks in the survey area. We aim to characterize the weak lensing selection by examining the sample’s X-ray properties. There are multiple X-ray clusters associated with nearly all the shear peaks: 14 X-ray clusters corresponding to seven DLS shear peaks. An additional three X-ray clusters cannot be definitively associated with shear peaks, mainly due to large positional offsets between the X-ray centroid and the shear peak. Here we report on the XMM-Newton properties of the 17 X-ray clusters. The X-ray clusters display a wide range of luminosities and temperatures; the L {sub X} − T {sub X} relation we determine for the shear-associated X-ray clusters is consistent with X-ray cluster samples selected without regard to dynamical state, while it is inconsistent with self-similarity. For a subset of the sample, we measure X-ray masses using temperature as a proxy, and compare to weak lensing masses determined by the DLS team. The resulting mass comparison is consistent with equality. The X-ray and weak lensing masses show considerable intrinsic scatter (∼48%), which is consistent with X-ray selected samples when their X-ray and weak lensing masses are independently determined.

Glyco-Nanoparticles Made from Self-Assembly of Maltoheptaose-block-Poly(methyl methacrylate): Micelle, Reverse Micelle, and Encapsulation.

Science.gov (United States)

Zepon, Karine M; Otsuka, Issei; Bouilhac, Cécile; Muniz, Edvani C; Soldi, Valdir; Borsali, Redouane

2015-07-13

The synthesis and the solution-state self-assembly of the "hybrid" diblock copolymers, maltoheptaose-block-poly(methyl methacrylate) (MH-b-PMMA), into large compound micelles (LCMs) and reverve micelle-type nanoparticles, are reported in this paper. The copolymers were self-assembled in water and acetone by direct dissolution method, and the morphologies of the nanoparticles were investigated by dynamic light scattering (DLS), nanoparticle tracking analysis (NTA), transmission electron microscopy (TEM), atomic force microscopy (AFM), proton nuclear magnetic resonance ((1)H NMR), and fluorescence spectroscopy as a function of the volume fraction of the copolymer hydrophobic block, copolymer concentration, stirring speed, and solvent polarity. The DLS measurements and TEM images showed that the hydrodynamic radius (Rh) of the LCMs obtained in water increases with the copolymer concentration. Apart from that, increasing the stirring speed leads to polydispersed aggregations of the LCMs. On the other hand, in acetone, the copolymers self-assembled into reverse micelle-type nanoparticles having Rh values of about 6 nm and micellar aggregates, as revealed the results obtained from DLS, AFM, and (1)H NMR analyses. The variation in micellar structure, that is, conformational inversion from LCMs to reverse micelle-type structures in response to polarity of the solvent, was investigated by apparent water contact angle (WCA) and (1)H NMR analyses. This conformational inversion of the nanoparticles was further confirmed by encapsulation and release of hydrophobic guest molecule, Nile red, characterized by fluorescence spectroscopy.

Methods of contrast variation by nuclear polarisation in small-angle neutron scattering: Observation of domains of nuclear polarisation by neutron scattering

International Nuclear Information System (INIS)

Leymarie, E.

2002-11-01

In this thesis we study the theoretical and experimental aspects of Contrast Variation by Nuclear Polarization (CVNP) applied to small-angle neutron scattering. The basics of neutron scattering theory is developed by highlighting the origin of the CVNP method: the strong spin dependence of thermal neutron scattering, especially on protons. We also present the principles of NMR with a special attention on the method of dynamic nuclear polarization by the solid effect which makes it possible to control the proton polarization and therefore the contrast for neutron scattering. We present a theoretical study of the CVNP method called static which supposes that the nuclear polarization is homogeneous in the sample and constant during the experiment. We show that it allows one to obtain partial structure functions of systems with multiple components, by carrying out several acquisitions with different polarizations on a single sample. For this purpose, we tested a simple device to stabilize the nuclear polarization. We describe finally a new application of the CVNP method called dynamic. In a solution of deuterated glycerol-water containing a small concentration of paramagnetic centres, we showed the existence of domains of polarized protons at the onset of dynamic polarization. This reinforces considerably the coherent scattering of paramagnetic centres. We describe the theoretical reasons explaining the appearance of these domains of polarization, as well as the various techniques used to observe them by neutron scattering. (author)

Study on interaction between palladium(ІІ)-Linezolid chelate with eosin by resonance Rayleigh scattering, second order of scattering and frequency doubling scattering methods using Taguchi orthogonal array design

Science.gov (United States)

Thakkar, Disha; Gevriya, Bhavesh; Mashru, R. C.

2014-03-01

Linezolid reacted with palladium to form 1:1 binary cationic chelate which further reacted with eosin dye to form 1:1 ternary ion association complex at pH 4 of Walpole's acetate buffer in the presence of methyl cellulose. As a result not only absorption spectra were changed but Resonance Rayleigh Scattering (RRS), Second-order Scattering (SOS) and Frequency Doubling Scattering (FDS) intensities were greatly enhanced. The analytical wavelengths of RRS, SOS and FDS (λex/λem) of ternary complex were located at 538 nm/538 nm, 240 nm/480 nm and 660 nm/330 nm, respectively. The linearity range for RRS, SOS and FDS methods were 0.01-0.5 μg mL-1, 0.1-2 μg mL-1 and 0.2-1.8 μg mL-1, respectively. The sensitivity order of three methods was as RRS > SOS > FDS. Accuracy of all methods were determined by recovery studies and showed recovery between 98% and 102%. Intraday and inter day precision were checked for all methods and %RSD was found to be less than 2 for all methods. The effects of foreign substances were tested on RRS method and it showed the method had good selectivity. For optimization of process parameter, Taguchi orthogonal array design L8(24) was used and ANOVA was adopted to determine the statistically significant control factors that affect the scattering intensities of methods. The reaction mechanism, composition of ternary ion association complex and reasons for scattering intensity enhancement was discussed in this work.

PREFACE: Atom-surface scattering Atom-surface scattering

Science.gov (United States)

Miret-Artés, Salvador

2010-08-01

It has been a privilege and a real pleasure to organize this special issue or festschrift in the general field of atom-surface scattering (and its interaction) in honor of J R Manson. This is a good opportunity and an ideal place to express our deep gratitude to one of the leaders in this field for his fundamental and outstanding scientific contributions. J R Manson, or Dick to his friends and colleagues, is one of the founding fathers, together with N Cabrera and V Celli, of the 'Theory of surface scattering and detection of surface phonons'. This is the title of the very well-known first theoretical paper by Dick published in Physical Review Letters in 1969. My first meeting with Dick was around twenty years ago in Saclay. J Lapujoulade organized a small group seminar about selective adsorption resonances in metal vicinal surfaces. We discussed this important issue in surface physics and many other things as if we had always known each other. This familiarity and warm welcome struck me from the very beginning. During the coming years, I found this to be a very attractive aspect of his personality. During my stays in Göttingen, we had the opportunity to talk widely about science and life at lunch or dinner time, walking or cycling. During these nice meetings, he showed, with humility, an impressive cultural background. It is quite clear that his personal opinions about history, religion, politics, music, etc, come from considering and analyzing them as 'open dynamical systems'. In particular, with good food and better wine in a restaurant or at home, a happy cheerful soirée is guaranteed with him, or even with only a good beer or espresso, and an interesting conversation arises naturally. He likes to listen before speaking. Probably not many people know his interest in tractors. He has an incredible collection of very old tractors at home. In one of my visits to Clemson, he showed me the collection, explaining to me in great detail, their technical properties

Molecular beam scattering experiments with polar molecules. 1. Differential elastic scattering of H2+NH3 and H2+H2O

International Nuclear Information System (INIS)

Bickes, R.W. Jr.; Scoles, G.; Smith, K.M.

1974-01-01

Differential elastic scattering cross sections with well resolved quantum oscillations have been measuremed for the systems H 2 +NH 3 and H 2 +H 2 O. Assuming a spherically symmetric interaction the data show that a simple spherical potential (i.e. Lennard-Jones) does not properly describe the scattering

Synthesis and stabilization of gold nanoparticles for biotechnological and cosmetics uses; Síntese e estabilização de nanopartículas de ouro para fins biotecnológicos e cosméticos

Energy Technology Data Exchange (ETDEWEB)

Silva, Andressa Alves da

2016-07-01

This study focuses on the synthesis and characterization of gold nanoparticles (AuNPs) with reducing agents and stabilizing sodium citrate and gum arabic. The synthesis was carried out by heating and use of gamma radiation source {sup 60}Co in doses 1, 7.5 and 15 kGy. In this context, we studied the properties and stability of AuNPs formed through characterization techniques such as UV- Vis absorption, checking the characteristics of AuNPs bands as well as the physical stability thereof. The samples synthesized with sodium citrate (AuCit) showed wavelengths ranging from 520 to 525 nm and the samples synthesized with gum arabic (AuGA) showed wavelengths between 530 and 540 nm. The dynamic light scattering analysis (DLS) was used to determine the hydrodynamic diameter of nanoparticles formed during a period of three months, demonstrating that AuCit samples showed mean hydrodynamic sizes ranging from 20 to 50 nm while AuGA samples synthesized by heating and the use of gamma radiation had mean hydrodynamic sizes ranging 50 - 115 nm. Analysis of scanning electron microscope with field emission (SEM - FEG) and transmission electron microscopy (TEM) were used to determine the actual size distribution of nanoparticles and their geometric shape. The characterization of the AuGA showed smaller diameters in comparison to the one resulted from the DLS analysis, thus suggesting possible encapsulation of AuNPs. (author)

Synthesis and stabilization of gold nanoparticles for biotechnological and cosmetics uses

International Nuclear Information System (INIS)

Silva, Andressa Alves da

2016-01-01

This study focuses on the synthesis and characterization of gold nanoparticles (AuNPs) with reducing agents and stabilizing sodium citrate and gum arabic. The synthesis was carried out by heating and use of gamma radiation source 60 Co in doses 1, 7.5 and 15 kGy. In this context, we studied the properties and stability of AuNPs formed through characterization techniques such as UV- Vis absorption, checking the characteristics of AuNPs bands as well as the physical stability thereof. The samples synthesized with sodium citrate (AuCit) showed wavelengths ranging from 520 to 525 nm and the samples synthesized with gum arabic (AuGA) showed wavelengths between 530 and 540 nm. The dynamic light scattering analysis (DLS) was used to determine the hydrodynamic diameter of nanoparticles formed during a period of three months, demonstrating that AuCit samples showed mean hydrodynamic sizes ranging from 20 to 50 nm while AuGA samples synthesized by heating and the use of gamma radiation had mean hydrodynamic sizes ranging 50 - 115 nm. Analysis of scanning electron microscope with field emission (SEM - FEG) and transmission electron microscopy (TEM) were used to determine the actual size distribution of nanoparticles and their geometric shape. The characterization of the AuGA showed smaller diameters in comparison to the one resulted from the DLS analysis, thus suggesting possible encapsulation of AuNPs. (author)

Effects of terraces, surface steps and 'over-specular' reflection due to inelastic energy losses on angular scattering spectra for glancing incidence scattering

CERN Document Server

Danailov, D; O'Connor, D J

2002-01-01

Recent experiments and our molecular-dynamics simulations indicate that the main signal of the angular scattering spectra of glancing incidence scattering are not affected by the thermal motion of surface atoms and can be explained by our row-model with averaged cylindrical potentials. At the ICACS-18 Conference [Nucl. Instr. and Meth. B 164-165 (2000) 583] we reported good agreement between experimental and calculated multimodal azimuthal angular scattering spectra for the glancing scattering of 10 and 15 keV [Nucl. Instr. and Meth. B 180 (2001) 265, Appl. Surf. Sci. 171 (2001) 113] He sup 0 beam along the [1 0 0] direction on the Fe(1 0 0) face. Our simulations also predicted that in contrast to the 2D angular scattering distribution, the 1D azimuthal angular distribution of scattered particles is very sensitive to the interaction potential used. Here, we report more detailed calculations incorporating the influence of terraces and surface steps on surface channeling, which show a reduction of the angular s...

Investigations of time resolved x-ray wide-angle scattering and x-ray small-angle scattering at DESY

International Nuclear Information System (INIS)

Zachmann, H.G.; Gehrke, R.; Prieske, W.; Riekel, C.

1985-01-01

Instrumentation is described for the simultaneous wide-angle and small-angle x-ray scattering. The method was applied to the study of the isothermal crystallization of polyethylene terephthalates. In agreement with the classical theories of crystallization, the data showed that the density difference between the crystals and the non-crystalline regions does not change with time. The mechanisms of melting, recrystallization, and crystal thickening were investigated by small-angle x-ray scattering with stepwise changes and continuous changes of temperature using polyethylene terephthalate

Interstellar scattering in the inner parts of the galaxy

International Nuclear Information System (INIS)

Rao, A.P.; Ananthakrishnan, S.

1984-01-01

A new survey of the galactic plane for sources with size less than 1 arc s at 327 MHz shows that towards the inner parts of the galaxy for galactic latitudes less than 5deg, interstellar scattering is much larger than expected from data at higher latitudes. The enhanced scattering varies both with galactic latitude and longitude. A two-component model for the distribution of scattering matter in the Galaxy is proposed to interpret the observations. (author)

Light transport in turbid media with non-scattering, low-scattering and high absorption heterogeneities based on hybrid simplified spherical harmonics with radiosity model.

Science.gov (United States)

Yang, Defu; Chen, Xueli; Peng, Zhen; Wang, Xiaorui; Ripoll, Jorge; Wang, Jing; Liang, Jimin

2013-01-01

Modeling light propagation in the whole body is essential and necessary for optical imaging. However, non-scattering, low-scattering and high absorption regions commonly exist in biological tissues, which lead to inaccuracy of the existing light transport models. In this paper, a novel hybrid light transport model that couples the simplified spherical harmonics approximation (SPN) with the radiosity theory (HSRM) was presented, to accurately describe light transport in turbid media with non-scattering, low-scattering and high absorption heterogeneities. In the model, the radiosity theory was used to characterize the light transport in non-scattering regions and the SPN was employed to handle the scattering problems, including subsets of low-scattering and high absorption. A Neumann source constructed by the light transport in the non-scattering region and formed at the interface between the non-scattering and scattering regions was superposed into the original light source, to couple the SPN with the radiosity theory. The accuracy and effectiveness of the HSRM was first verified with both regular and digital mouse model based simulations and a physical phantom based experiment. The feasibility and applicability of the HSRM was then investigated by a broad range of optical properties. Lastly, the influence of depth of the light source on the model was also discussed. Primary results showed that the proposed model provided high performance for light transport in turbid media with non-scattering, low-scattering and high absorption heterogeneities.

Neutron Scattering Software

Science.gov (United States)

Home Page | Facilities | Reference | Software | Conferences | Announcements | Mailing Lists Neutron Scattering Banner Neutron Scattering Software A new portal for neutron scattering has just been established sets KUPLOT: data plotting and fitting software ILL/TAS: Matlab probrams for analyzing triple axis data

Periodic instantons and scattering amplitudes

International Nuclear Information System (INIS)

Khlebnikov, S.Yu.; Rubakov, V.A.; Tinyakov, P.G.

1991-04-01

We discuss the role of periodic euclidean solutions with two turning points and zero winding number (periodic instantons) in instanton induced processes below the sphaleron energy E sph . We find that the periodic instantons describe certain multiparticle scattering events leading to the transitions between topologically distinct vacua. Both the semiclassical amplitudes and inital and final states of these transitions are determined by the periodic instantons. Furthermore, the corresponding probabilities are maximal among all states of given energy. We show that at E ≤ E sph , the periodic instantons can be approximated by infinite chains of ordinary instantons and anti-instantons, and they naturally emerge as deformations of the zero energy instanton. In the framework of 2d abelian Higgs model and 4d electroweak theory we show, however, that there is not obvious relation between periodic instantons and two-particle scattering amplitudes. (orig.)

Quantum scattering at low energies

DEFF Research Database (Denmark)

Derezinski, Jan; Skibsted, Erik

For a class of negative slowly decaying potentials, including with , we study the quantum mechanical scattering theory in the low-energy regime. Using modifiers of the Isozaki--Kitada type we show that scattering theory is well behaved on the {\\it whole} continuous spectrum of the Hamiltonian......, including the energy . We show that the --matrices are well-defined and strongly continuous down to the zero energy threshold. Similarly, we prove that the wave matrices and generalized eigenfunctions are norm continuous down to the zero energy if we use appropriate weighted spaces. These results are used...... from positive energies to the limiting energy . This change corresponds to the behaviour of the classical orbits. Under stronger conditions we extract the leading term of the asymptotics of the kernel of at its singularities; this leading term defines a Fourier integral operator in the sense...

Interaction between β-lactoglobulin and structurally different heteroexopolysaccharides investigated by solution scattering and analytical ultracentrifugation study

DEFF Research Database (Denmark)

Khan, Sanaullah; Birch, Johnny; Harris, Pernille

strongly with these HePSs. β-lactoglobulin exists as a dimer at pH 4 in the absence of HePSs. When mixed with HePSs, SAXS analysis showed that β-lactoglobulin formed large aggregates. DLS also showed formation of large aggregates of β-lactoglobulin with HePSs, thus validating SAXS data. Turbidity and AUC...... heteroexopolysaccharides (HePS-1–HePS-4) from lactic acid bacteria (LAB) and their interactions with β-lactoglobulin. We have previously shown that these HePSs exhibited a compact conformation in solution. Here, SAXS data for HePSs (HePS-1–HePS-4) complexes with β-lactoglobulin showed that β-lactoglobulin aggregated...... data indicated that both soluble and insoluble BLG–HePSs complexes were formed. This study provides new insights into the role of molecular structures in associative interactions between HePSs and BLG which has relevance for various industrial applications....

Quantum effets in nonresonant X-ray scattering

Energy Technology Data Exchange (ETDEWEB)

Slowik, Jan Malte

2015-11-15

experiments. In the quantum theory it has however been revealed that X-ray scattering patterns of electronic motion are related to complex spatio-temporal correlations, instead of the instantaneous electron density. I scrutinize the time-resolved scattering pattern from coherent electronic wave packets. I show that timeresolved PCI recovers the instantaneous electron density of electronic motion. For the far-field diffraction scattering pattern, I analyze the influence of photon energy resolution of the detector. Moreover, I demonstrate that X-ray scattering from a crystal of identical wave packets also recovers the instantaneous electron density. I point out that a generalized electron density propagator of the wave packet can be reconstructed from a scattering experiment. Finally, I propose timeresolved Compton scattering of electronic wave packets. I show that X-ray scattering with large energy transfer can be used to recover the instantaneous momentum space density of the target. The third topic of this dissertation is Compton scattering in single molecule coherent diffractive imaging (CDI). The structure determination of single macromolecules via CDI is one of the key applications of XFELs. The structure of the molecule can be reconstructed from the elastic diffraction pattern. Inelastic X-ray scattering generates a background signal, which I determine for typical high-intensity imaging conditions. I find that at high X-ray fluence the background signal becomes dominating, posing a problem for high resolution imaging. The strong ionization by the X-ray pulse may ionize several electrons per atom. Scattering from these free electrons makes a major contribution to the background signal. I present and discuss detailed numerical studies for different X-ray fluence and photon energy.

Quantum effets in nonresonant X-ray scattering

International Nuclear Information System (INIS)

Slowik, Jan Malte

2015-11-01

experiments. In the quantum theory it has however been revealed that X-ray scattering patterns of electronic motion are related to complex spatio-temporal correlations, instead of the instantaneous electron density. I scrutinize the time-resolved scattering pattern from coherent electronic wave packets. I show that timeresolved PCI recovers the instantaneous electron density of electronic motion. For the far-field diffraction scattering pattern, I analyze the influence of photon energy resolution of the detector. Moreover, I demonstrate that X-ray scattering from a crystal of identical wave packets also recovers the instantaneous electron density. I point out that a generalized electron density propagator of the wave packet can be reconstructed from a scattering experiment. Finally, I propose timeresolved Compton scattering of electronic wave packets. I show that X-ray scattering with large energy transfer can be used to recover the instantaneous momentum space density of the target. The third topic of this dissertation is Compton scattering in single molecule coherent diffractive imaging (CDI). The structure determination of single macromolecules via CDI is one of the key applications of XFELs. The structure of the molecule can be reconstructed from the elastic diffraction pattern. Inelastic X-ray scattering generates a background signal, which I determine for typical high-intensity imaging conditions. I find that at high X-ray fluence the background signal becomes dominating, posing a problem for high resolution imaging. The strong ionization by the X-ray pulse may ionize several electrons per atom. Scattering from these free electrons makes a major contribution to the background signal. I present and discuss detailed numerical studies for different X-ray fluence and photon energy.

Collective dynamics and self-diffusion in a diblock copolymer melt in the body-centered cubic phase

DEFF Research Database (Denmark)

Papadakis, C.M.; Rittig, F.; Almdal, K.

2004-01-01

The structure and dynamics of a strongly asymmetric poly(ethylene propylene)poly (dimethylsiloxane) (PEP-PDMS) diblock copolymer in the melt have been studied over a wide temperature range. Small-angle neutron scattering reveals that the sample exhibits two stable phases in this temperature range......: Above the order-to-disorder transition temperature, it is disordered, whereas the domain structure is body-centered cubic (bcc) below, being stable down to the lowest temperatures measured. In the disordered state, dynamic light scattering (DLS) in the polarized geometry reveals the heterogeneity mode...

Experimental study on stimulated scattering of ZnO nanospheres dispersed in water

Energy Technology Data Exchange (ETDEWEB)

Shi, Jiulin, E-mail: hyq1304@126.com; Wu, Haopeng [Nanchang Hangkong University, Jiangxi Engineering Laboratory for Optoelectronics Testing Technology (China); Yan, Feng; Yang, Junjie [Nanchang Hangkong University, School of Measuring and Optical Engineering (China); He, Xingdao, E-mail: xingdaohe@126.com [Nanchang Hangkong University, Jiangxi Engineering Laboratory for Optoelectronics Testing Technology (China)

2016-01-15

The backward stimulated scattering (BSS) from ZnO nanospheres dispersed in water has been investigated experimentally by employing a Nd:YAG pulse laser with ∼532 nm wavelength and ∼8 ns pulse width as the pump laser source. The present results show that the BSS effect is uniquely and unequivocally different compared to other known stimulated scattering, such as stimulated Rayleigh scattering, stimulated Brillouin scattering, and stimulated Raman scattering, and it displays the characteristics of no frequency shift and threshold dependence on initial spontaneous Mie scattering seed source. These can be understood by means of the Mie scattering theory and a laser-induced stationary Bragg grating model.

Deconvolution of shift-variant broadening for Compton scatter imaging

International Nuclear Information System (INIS)

Evans, Brian L.; Martin, Jeffrey B.; Roggemann, Michael C.

1999-01-01

A technique is presented for deconvolving shift-variant Doppler broadening of singly Compton scattered gamma rays from their recorded energy distribution. Doppler broadening is important in Compton scatter imaging techniques employing gamma rays with energies below roughly 100 keV. The deconvolution unfolds an approximation to the angular distribution of scattered photons from their recorded energy distribution in the presence of statistical noise and background counts. Two unfolding methods are presented, one based on a least-squares algorithm and one based on a maximum likelihood algorithm. Angular distributions unfolded from measurements made on small scattering targets show less evidence of Compton broadening. This deconvolution is shown to improve the quality of filtered backprojection images in multiplexed Compton scatter tomography. Improved sharpness and contrast are evident in the images constructed from unfolded signals

VPD residue search by monitoring scattered x-rays

International Nuclear Information System (INIS)

Mori, Y.; Yamagami, M.; Yamada, T.

2000-01-01

Recently, VPD-TXRF has come into wide use for semiconductor analysis. In VPD-TXRF technique, adjusting the mechanical measuring point to the center of dried residue is of importance for accurate determination. Until now, the following searching methods have been used: monitoring light scattering under bright illumination, using laser scattering particle mapper, applying internal standard as a marker. However, each method has individual disadvantage. For example, interference of Kβ line (ex. Sc-Kβ to Ti-Kα) occurs in the internal standard method. We propose a new searching method 'scattered x-ray search' which utilizes x-ray scattering form the dried residue as a marker. Since the line profile of x-ray scattering agrees with that of fluorescent x-rays, scattered x-ray can be used as an alternative marker instead of internal standard. According to our experimental results, this search method shows the same accuracy as internal standard method. The merits are as follows: 1) no need to add internal standard, 2) rapid search because of high intensity of scattered x-rays, 3) searching software for internal standard can be applied without any modification. In this method, diffraction of incident x-rays by substrate causes irregular change over the detected scattering x-rays. Therefore, this method works better under x-y controlled stage than r-Θ one. (author)

Design of fiber optic probes for laser light scattering

Science.gov (United States)

Dhadwal, Harbans S.; Chu, Benjamin

1989-01-01

A quantitative analysis is presented of the role of optical fibers in laser light scattering. Design of a general fiber optic/microlens probe by means of ray tracing is described. Several different geometries employing an optical fiber of the type used in lightwave communications and a graded index microlens are considered. Experimental results using a nonimaging fiber optic detector probe show that due to geometrical limitations of single mode fibers, a probe using a multimode optical fiber has better performance, for both static and dynamic measurements of the scattered light intensity, compared with a probe using a single mode fiber. Fiber optic detector probes are shown to be more efficient at data collection when compared with conventional approaches to measurements of the scattered laser light. Integration of fiber optic detector probes into a fiber optic spectrometer offers considerable miniaturization of conventional light scattering spectrometers, which can be made arbitrarily small. In addition static and dynamic measurements of scattered light can be made within the scattering cell and consequently very close to the scattering center.

Quantum-mechanical scattering in one dimension

International Nuclear Information System (INIS)

Boya, Luis J.

2008-01-01

The purpose of this mainly pedagogical review is to fill a lacuna in the usual treatment of scattering in quantum mechanics, by showing the essential of it in the simplest, one-dimensional setting. We define in this situation amplitudes and scattering coefficients and deal with optical and Levinson' theorems as consequences of unitarity in coordinate or momentum space. Parity waves en lieu of partial waves, integral equations and Born series, etc., are defined naturally in this frame. Several solvable examples are shown. Two topics best studied in 1d are transparent potentials and supersymmetric quantum mechanics. Elementary analytical properties and general behaviour of amplitudes give rise to study inverse problems, that is, recovering the potential from scattering data. Isospectral deformations of the wave equation give relations with some nonlinear evolution equations (Lax), solvable by the inverse scattering method (Kruskal), and we consider the KdV equation as an example. We also refer briefly to some singular potentials, where, e.g., the essence of renormalization can be read off again in the simplest setting. The whole paper emphasizes the tutorial and introductory aspects

An analysis of scattered light in low dispersion IUE spectra

Science.gov (United States)

Basri, G.; Clarke, J. T.; Haisch, B. M.

1985-01-01

A detailed numerical simulation of light scattering from the low-resolution grating in the short wavelength spectrograph of the IUE Observatory was developed, in order to quantitatively analyze the effects of scattering on both continuum and line emission spectra. It is found that: (1) the redistribution of light by grating scattering did not appreciably alter either the shape or the absolute flux level of continuum spectra for A-F stars; (2) late-type stellar continua showed a tendency to flatten when observed in scattered light toward the shorter wavelengths; and (3) the effect of grating scattering on emission lines is to decrease measured line intensities by an increasing percentage toward the shorter wavelengths. The spectra obtained from scattering experiments for solar-type and late type stars are reproduced in graphic form.

Connection of Scattering Principles: A Visual and Mathematical Tour

Science.gov (United States)

Broggini, Filippo; Snieder, Roel

2012-01-01

Inverse scattering, Green's function reconstruction, focusing, imaging and the optical theorem are subjects usually studied as separate problems in different research areas. We show a physical connection between the principles because the equations that rule these "scattering principles" have a similar functional form. We first lead the reader…

LIDAR Thomson scattering for ITER core plasma revisited

International Nuclear Information System (INIS)

Gowers, C.; Nielsen, P.; Salzmann, H.

2016-01-01

The authors have become aware that the development of the hitherto planned time-of-flight Thomson scattering system for the ITER core plasma is not proceeding and that conventional Thomson scattering set-ups are being discussed as an alternative. In this paper, we want to point out the advantages of LIDAR and show how criticized details of the original design can be improved. We present a design of the front optics, which in neutronics terms closely resembles a layout already previously accepted. The presented design does not require Raman scattering calibration for the density measurement. Comparison with the JET Core LIDAR system and simulations at higher temperatures both show that with the new design the specified accuracy can be met with a 1–2 J laser. Current laser and detector technology is reviewed. A strategy for how to proceed is presented

Variation of entanglement entropy in scattering process

Energy Technology Data Exchange (ETDEWEB)

Seki, Shigenori, E-mail: sigenori@hanyang.ac.kr [Research Institute for Natural Science, Hanyang University, Seoul 133-791 (Korea, Republic of); Park, I.Y., E-mail: inyongpark05@gmail.com [Department of Applied Mathematics, Philander Smith College, Little Rock, AR 72223 (United States); Sin, Sang-Jin, E-mail: sjsin@hanyang.ac.kr [Department of Physics, Hanyang University, Seoul 133-791 (Korea, Republic of)

2015-04-09

In a scattering process, the final state is determined by an initial state and an S-matrix. We focus on two-particle scattering processes and consider the entanglement between these particles. For two types initial states, i.e., an unentangled state and an entangled one, we calculate perturbatively the change of entanglement entropy from the initial state to the final one. Then we show a few examples in a field theory and in quantum mechanics.

High energy scattering in gravity and supergravity

DEFF Research Database (Denmark)

B. Giddings, Steven; Schmidt-Sommerfeld, Maximilian; Andersen, Jeppe Rosenkrantz

2010-01-01

We investigate features of perturbative gravity and supergravity by studying scattering in the ultraplanckian limit, and sharpen arguments that the dynamics is governed by long-distance physics. A simple example capturing aspects of the eikonal resummation suggests why short distance phenomena...... and in particular divergences or nonrenormalizability do not necessarily play a central role in this regime. A more profound problem is apparently unitarity. These considerations can be illustrated by showing that known gravity and supergravity amplitudes have the same long-distance behavior, despite the extra...... a physical scattering process, and ultraplanckian scattering exhibiting Regge behavior. These arguments sharpen the need to find a nonperturbative completion of gravity with mechanisms which restore unitarity in the strong gravity regime....

Effective string theory and QCD scattering amplitudes

International Nuclear Information System (INIS)

Makeenko, Yuri

2011-01-01

QCD string is formed at distances larger than the confinement scale and can be described by the Polchinski-Strominger effective string theory with a nonpolynomial action, which has nevertheless a well-defined semiclassical expansion around a long-string ground state. We utilize modern ideas about the Wilson-loop/scattering-amplitude duality to calculate scattering amplitudes and show that the expansion parameter in the effective string theory is small in the Regge kinematical regime. For the amplitudes we obtain the Regge behavior with a linear trajectory of the intercept (d-2)/24 in d dimensions, which is computed semiclassically as a momentum-space Luescher term, and discuss an application to meson scattering amplitudes in QCD.

Neutron scattering studies of modulated magnetic structures

Energy Technology Data Exchange (ETDEWEB)

Aagaard Soerensen, Steen

1999-08-01

This report describes investigations of the magnetic systems DyFe{sub 4}Al{sub 8} and MnSi by neutron scattering and in the former case also by X-ray magnetic resonant scattering. The report is divided into three parts: An introduction to the technique of neutron scattering with special emphasis on the relation between the scattering cross section and the correlations between the scattering entities of the sample. The theoretical framework of neutron scattering experiments using polarized beam technique is outlined. The second part describes neutron and X-ray scattering investigation of the magnetic structures of DyFe{sub 4}Al{sub 8}. The Fe sublattice of the compound order at 180 K in a cycloidal structure in the basal plane of the bct crystal structure. At 25 K the ordering of the Dy sublattice shows up. By the element specific technique of X-ray resonant magnetic scattering, the basal plane cycloidal structure was also found for the Dy sublattice. The work also includes neutron scattering studies of DyFe{sub 4}Al{sub 8} in magnetic fields up to 5 T applied along a <110> direction. The modulated structure at the Dy sublattice is quenched by a field lower than 1 T, whereas modulation is present at the Fe sublattice even when the 5 T field is applied. In the third part of the report, results from three small angle neutron experiments on MnSi are presented. At ambient pressure, a MnSi is known to form a helical spin density wave at temperature below 29 K. The application of 4.5 kbar pressure intended as hydrostatic decreased the Neel temperature to 25 K and changed the orientation of the modulation vector. To understand this reorientation within the current theoretical framework, anisotropic deformation of the sample crystal must be present. The development of magnetic critical scattering with an isotropic distribution of intensity has been studied at a level of detail higher than that of work found in the literature. Finally the potential of a novel polarization

Magnetic photon scattering

International Nuclear Information System (INIS)

Lovesey, S.W.

1987-05-01

The report reviews, at an introductory level, the theory of photon scattering from condensed matter. Magnetic scattering, which arises from first-order relativistic corrections to the Thomson scattering amplitude, is treated in detail and related to the corresponding interaction in the magnetic neutron diffraction amplitude. (author)

Two-dimensional phononic crystals with time-varying properties: a multiple scattering analysis

International Nuclear Information System (INIS)

Wright, D W; Cobbold, R S C

2010-01-01

Multiple scattering theory is a versatile two- and three-dimensional method for characterizing the acoustic wave transmission through many scatterers. It provides analytical solutions to wave propagation in scattering structures, and its computational complexity grows logarithmically with the number of scatterers. In this paper we show how the 2D method can be adapted to include the effects of time-varying material parameters. Specifically, a new T-matrix is defined to include the effects of frequency modulation that occurs in time-varying phononic crystals. Solutions were verified against finite difference time domain (FDTD) simulations and showed excellent agreement. This new method enables fast characterization of time-varying phononic crystals without the need to resort to lengthy FDTD simulations. Also, the method of combining T-matrices to form the T-supermatrix remains unchanged provided that the new matrix definitions are used. The method is quite compatible with existing implementations of multiple scattering theory and could be readily extended to three-dimensional multiple scattering theory

Reduction of Raman scattering and fluorescence from anvils in high pressure Raman scattering

Science.gov (United States)

Dierker, S. B.; Aronson, M. C.

2018-05-01

We describe a new design and use of a high pressure anvil cell that significantly reduces the Raman scattering and fluorescence from the anvils in high pressure Raman scattering experiments. The approach is particularly useful in Raman scattering studies of opaque, weakly scattering samples. The effectiveness of the technique is illustrated with measurements of two-magnon Raman scattering in La2CuO4.

FDTD scattered field formulation for scatterers in stratified dispersive media.

Science.gov (United States)

Olkkonen, Juuso

2010-03-01

We introduce a simple scattered field (SF) technique that enables finite difference time domain (FDTD) modeling of light scattering from dispersive objects residing in stratified dispersive media. The introduced SF technique is verified against the total field scattered field (TFSF) technique. As an application example, we study surface plasmon polariton enhanced light transmission through a 100 nm wide slit in a silver film.

One pot phytosynthesis of gold nanoparticles using Genipa americana fruit extract and its biological applications

International Nuclear Information System (INIS)

Kumar, Brajesh; Smita, Kumari; Cumbal, Luis; Camacho, Javier; Hernández-Gallegos, Elisabeth; Guadalupe Chávez-López, María de; Grijalva, Marcelo; Andrade, Kleber

2016-01-01

In this article, rapid one pot synthesis of gold nanoparticles (GNPs) using an eco-friendly extract of Genipa americana L. fruit is described. Electrospray ionization mass spectrometry (ESI-MS) and Fourier transform infrared (FTIR) spectroscopic studies demonstrated that small molecules such as genipin, genipaol, geniposide and ranolazine can act as reducer as well as stabilizers. The monodispersed, spherical GNPs were further characterized by UV–vis spectroscopy at λ max = 535 nm, transmission electron microscopy (TEM), dynamic light scattering (DLS) and X-ray diffraction (XRD) analysis. This synthetic approach offers a greener and alternate route to the preparation of GNPs free from toxic chemical components and stable for 6–7 months under room temperature. The green synthesized GNPs showed weak antioxidant efficacy against 1,1-diphenyl-2-picrylhydrazyl and no cytotoxicity against A-549 and HeLa human cancer cell lines, from lung and cervix. This study opens a new industrial scope of G. americana fruit in nanoscience and as surface modified GNPs can be developed into a successful drug carrier for future pharmaceutical products. - Highlights: • Gold nanoparticles can be synthesized by Genipa americana fruit extract. • TEM-DLS analysis confirmed that the average particle size is 30.4 ± 14.9 nm. • Nanoparticles showed weak antioxidant and no cytotoxicity activity.

Self-aggregation of bio-surfactants within ionic liquid 1-ethyl-3-methylimidazolium bromide: A comparative study and potential application in antidepressants drug aggregation

Science.gov (United States)

Banjare, Manoj Kumar; Behera, Kamalakanta; Kurrey, Ramsingh; Banjare, Ramesh Kumar; Satnami, Manmohan L.; Pandey, Siddharth; Ghosh, Kallol K.

2018-06-01

Aggregation behavior of bio-surfactants (BS) sodium cholate (NaC) and sodium deoxycholate (NaDC) within aqueous solution of ionic liquid (IL) 1-ethyl-3-methylimidazolium bromide [Emim][Br] has been investigated using surface tension, conductivity, steady state fluorescence, FT-IR and dynamic light scattering (DLS) techniques. Various interfacial and thermodynamic parameters are determined in the presence of different wt% of IL [Emim][Br]. Information regarding the local microenvironment and size of the aggregates is obtained from fluorescence and DLS, respectively. FT-IR spectral response is used to reveal the interactions taking place within aqueous NaC/NaDC micellar solutions. It is noteworthy to mention that increasing wt% of [Emim][Br] results in an increase in the spontaneity of micelle formation and the hydrophilic IL shows more affinity for NaC as compared to NaDC. Further, the micellar solutions of BS-[Emim][Br] are utilized for studying the aggregation of antidepressants drug promazine hydrochloride (pH). UV-vis spectroscopic investigation reveals interesting outcomes and the results show changes in spectral absorbance of PH drug on the addition of micellar solution (BS-[Emim][Br]). Highest binding affinity and most promising activity are shown for NaC as compared to NaDC.

One pot phytosynthesis of gold nanoparticles using Genipa americana fruit extract and its biological applications

Energy Technology Data Exchange (ETDEWEB)

Kumar, Brajesh, E-mail: krmbraj@gmail.com [Centro de Nanociencia y Nanotecnologia, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, Sangolqui, P.O. BOX 171-5-231B (Ecuador); Smita, Kumari; Cumbal, Luis [Centro de Nanociencia y Nanotecnologia, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, Sangolqui, P.O. BOX 171-5-231B (Ecuador); Camacho, Javier [Centro de Nanociencia y Nanotecnologia, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, Sangolqui, P.O. BOX 171-5-231B (Ecuador); Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Departamento de Farmacología, C.P. 07360 Mexico City (Mexico); Hernández-Gallegos, Elisabeth; Guadalupe Chávez-López, María de [Centro de Investigación y de Estudios Avanzados del Instituto Politécnico Nacional, Departamento de Farmacología, C.P. 07360 Mexico City (Mexico); Grijalva, Marcelo; Andrade, Kleber [Centro de Nanociencia y Nanotecnologia, Universidad de las Fuerzas Armadas ESPE, Av. Gral. Rumiñahui s/n, Sangolqui, P.O. BOX 171-5-231B (Ecuador)

2016-05-01

In this article, rapid one pot synthesis of gold nanoparticles (GNPs) using an eco-friendly extract of Genipa americana L. fruit is described. Electrospray ionization mass spectrometry (ESI-MS) and Fourier transform infrared (FTIR) spectroscopic studies demonstrated that small molecules such as genipin, genipaol, geniposide and ranolazine can act as reducer as well as stabilizers. The monodispersed, spherical GNPs were further characterized by UV–vis spectroscopy at λ{sub max} = 535 nm, transmission electron microscopy (TEM), dynamic light scattering (DLS) and X-ray diffraction (XRD) analysis. This synthetic approach offers a greener and alternate route to the preparation of GNPs free from toxic chemical components and stable for 6–7 months under room temperature. The green synthesized GNPs showed weak antioxidant efficacy against 1,1-diphenyl-2-picrylhydrazyl and no cytotoxicity against A-549 and HeLa human cancer cell lines, from lung and cervix. This study opens a new industrial scope of G. americana fruit in nanoscience and as surface modified GNPs can be developed into a successful drug carrier for future pharmaceutical products. - Highlights: • Gold nanoparticles can be synthesized by Genipa americana fruit extract. • TEM-DLS analysis confirmed that the average particle size is 30.4 ± 14.9 nm. • Nanoparticles showed weak antioxidant and no cytotoxicity activity.

Measurement of the average mass of proteins adsorbed to a nanoparticle by using a suspended microchannel resonator.

Science.gov (United States)

Nejadnik, M Reza; Jiskoot, Wim

2015-02-01

We assessed the potential of a suspended microchannel resonator (SMR) to measure the adsorption of proteins to nanoparticles. Standard polystyrene beads suspended in buffer were weighed by a SMR system. Particle suspensions were mixed with solutions of bovine serum albumin (BSA) or monoclonal human antibody (IgG), incubated at room temperature for 3 h and weighed again with SMR. The difference in buoyant mass of the bare and protein-coated polystyrene beads was calculated into real mass of adsorbed proteins. The average surface area occupied per protein molecule was calculated, assuming a monolayer of adsorbed protein. In parallel, dynamic light scattering (DLS), nanoparticle tracking analysis (NTA), and zeta potential measurements were performed. SMR revealed a statistically significant increase in the mass of beads because of adsorption of proteins (for BSA and IgG), whereas DLS and NTA did not show a difference between the size of bare and protein-coated beads. The change in the zeta potential of the beads was also measurable. The surface area occupied per protein molecule was in line with their known size. Presented results show that SMR can be used to measure the mass of adsorbed protein to nanoparticles with a high precision in the presence of free protein. © 2014 Wiley Periodicals, Inc. and the American Pharmacists Association.

Biophysical characterization of the feline immunodeficiency virus p24 capsid protein conformation and in vitro capsid assembly.

Directory of Open Access Journals (Sweden)

Jennifer Serrière

Full Text Available The Feline Immunodeficiency Virus (FIV capsid protein p24 oligomerizes to form a closed capsid that protects the viral genome. Because of its crucial role in the virion, FIV p24 is an interesting target for the development of therapeutic strategies, although little is known about its structure and assembly. We defined and optimized a protocol to overexpress recombinant FIV capsid protein in a bacterial system. Circular dichroism and isothermal titration calorimetry experiments showed that the structure of the purified FIV p24 protein was comprised mainly of α-helices. Dynamic light scattering (DLS and cross-linking experiments demonstrated that p24 was monomeric at low concentration and dimeric at high concentration. We developed a protocol for the in vitro assembly of the FIV capsid. As with HIV, an increased ionic strength resulted in FIV p24 assembly in vitro. Assembly appeared to be dependent on temperature, salt concentration, and protein concentration. The FIV p24 assembly kinetics was monitored by DLS. A limit end-point diameter suggested assembly into objects of definite shapes. This was confirmed by electron microscopy, where FIV p24 assembled into spherical particles. Comparison of FIV p24 with other retroviral capsid proteins showed that FIV assembly is particular and requires further specific study.

Formation of stable nanoparticles via electrostatic complexation between sodium caseinate and gum arabic.

Science.gov (United States)

Ye, Aiqian; Flanagan, John; Singh, Harjinder

2006-06-05

The formation of electrostatic complexes between sodium caseinate and gum arabic (GA) was studied as a function of pH (2.0-7.0), using slow acidification in situ with glucono-delta-lactone (GDL) or titration with HCl. The colloidal behavior of the complexes under specific conditions was investigated using absorbance measurements (at 515 or 810 nm) and dynamic light scattering (DLS). In contrast to the sudden increase in absorbance and subsequent precipitation of sodium caseinate solutions at pH sodium caseinate and GA increased to a level that was dependent on GA concentration at pH 5.4 (pH(c)). The absorbance values remained constant with further decreases in pH until a sudden increase in absorbance was observed (at pH(phi)). The pH(phi) was also dependent upon the GA concentration. Dynamic light scattering (DLS) data showed that the sizes of the particles formed by the complexation of sodium caseinate and GA between pH(c) and pH(phi) were between 100 and 150 nm and these nanoparticles were visualized using negative staining transmission electron microscopy (TEM). Below pH(phi), the nanoparticles associated to form larger particles, causing phase separation. zeta-Potential measurements of the nanoparticles and chemical analysis after phase separation showed that phase separation was a consequence of charge neutralization. The formation of complexes between sodium caseinate and GA was inhibited at high ionic strength (>50 mM NaCl). It is postulated that the structure of the nanoparticles comprises an aggregated caseinate core, protected from further aggregation by steric repulsion of one, or more, electrostatically attached GA molecules. Copyright 2005 Wiley Periodicals, Inc.

Nuclear matter and electron scattering

Energy Technology Data Exchange (ETDEWEB)

Sick, I [Dept. fuer Physik und Astronomie, Univ. Basel (Switzerland)

1998-06-01

We show that inclusive electron scattering at large momentum transfer allows a measurement of short-range properties of nuclear matter. This provides a very valuable constraint in selecting the calculations appropriate for predicting nuclear matter properties at the densities of astrophysical interest. (orig.)

Landau retardation on the occurrence scattering time in quantum electron–hole plasmas

International Nuclear Information System (INIS)

Hong, Woo-Pyo; Jung, Young-Dae

2016-01-01

The Landau damping effects on the occurrence scattering time in electron collisions are investigated in a quantum plasma composed of electrons and holes. The Shukla–Stenflo–Bingham effective potential model is employed to obtain the occurrence scattering time in a quantum electron–hole plasma. The result shows that the influence of Landau damping produces the imaginary term in the scattering amplitude. It is then found that the Landau damping generates the retardation effect on the occurrence scattering time. It is found that the occurrence scattering time increases in forward scattering domains and decreases in backward scattering domains with an increase of the Landau parameter. It is also found that the occurrence scattering time decreases with increasing collision energy. In addition, it is found that the quantum shielding effect enhances the occurrence scattering time in the forward scattering and, however, suppresses the occurrence scattering time in the backward scattering. - Highlights: • The Landau damping effects on the occurrence scattering time are investigated in a quantum electron–hole plasma. • The Shukla–Stenflo–Bingham potential model is employed to obtain the occurrence scattering time in quantum plasmas. • The influence of quantum shielding on the occurrence scattering time is discussed.

A new instrumental set-up for polarized neutron scattering experiments

International Nuclear Information System (INIS)

Schmidt, Wolfgang; Ohl, Michael

2005-01-01

Neutron scattering with polarization analysis is a powerful tool to determine magnetic structures and excitations. A common setup is to mount the sample at the center of a Helmholtz-type coil which can provide a magnetic field of any direction at the sample position and also a guide field along the neutron flight paths around the sample. Recent experiments showed quite a high demand for measurements at low momentum transfers. For the corresponding low scattering angles air scattering gives rise to a very large background. For this reason we have extended the standard setup to a combination of a large vacuum tank surrounded by electrical coils. The vacuum tank eliminates the air scattering and we can use the polarization analysis down to the lowest accessible momentum transfers. The coils themselves also show some new features: In contrary to the classic (symmetric) coil distribution we use an asymmetric setup which gives the advantage of a larger scattering window. Due to a more sophisticated current distribution this modified coil arrangement needs not to be rotated for different scattering conditions. The whole set-up will soon be available at IN12, a cold neutrons three-axis spectrometer operated by FZ Juelich in collaboration with CEA Grenoble as a CRG-B instrument at the Institut Laue Langevin in Grenoble

Anomalously Weak Scattering in Metal-Semiconductor Multilayer Hyperbolic Metamaterials

Directory of Open Access Journals (Sweden)

Hao Shen

2015-05-01

Full Text Available In contrast to strong plasmonic scattering from metal particles or structures in metal films, we show that patterns of arbitrary shape fabricated out of multilayer hyperbolic metamaterials become invisible within a chosen band of optical frequencies. This is due to anomalously weak scattering when the in-plane permittivity of the multilayer hyperbolic metamaterials is tuned to match with the surrounding medium. This new phenomenon is described theoretically and demonstrated experimentally by optical characterization of various patterns in Au-Si multilayer hyperbolic metamaterials. This anomalously weak scattering is insensitive to pattern sizes, shapes, and incident angles, and has potential applications in scattering cross-section engineering, optical encryption, low-observable conductive probes, and optoelectric devices.

Experiment on direct nn scattering - The radiation-induced outgassing complication

Energy Technology Data Exchange (ETDEWEB)

Stephenson, S.L., E-mail: sstephen@gettysburg.edu [Gettysburg College, Gettysburg, PA 17325 (United States); Crawford, B.E. [Gettysburg College, Gettysburg, PA 17325 (United States); Furman, W.I.; Lychagin, E.V.; Muzichka, A.Yu.; Nekhaev, G.V.; Sharapov, E.I.; Shvetsov, V.N.; Strelkov, A.V. [Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Levakov, B.G.; Lyzhin, A.E.; Chernukhin, Yu.I. [Russian Federal Nuclear Center - All Russian Research Institute of Technical Physics, P.O. Box 245, 456770 Snezhinsk (Russian Federation); Howell, C.R. [Duke University and Triangle Universities Nuclear Laboratory, Durham, NC 27708-0308 (United States); Mitchell, G.E. [North Carolina State University, Raleigh, NC 27695-8202 (United States); Triangle Universities Nuclear Laboratory, Durham, NC 27708-0308 (United States); Tornow, W. [Duke University and Triangle Universities Nuclear Laboratory, Durham, NC 27708-0308 (United States); Showalter-Bucher, R.A. [Northeastern University, Boston, MA 02115 (United States)

2012-12-01

The first direct neutron-neutron scattering experiment using the YAGUAR pulsed reactor has yielded initial results. They show a unforeseen significant thermal neutron background as a result of radiation-induced desorption within the scattering chamber. Thermal neutrons are mostly scattering not from other neutrons but instead from the desorbed gas molecules. Analysis of the obtained neutron time-of-flight spectra suggests neutron scattering from H{sub 2} molecules. The presented desorption model agrees with our experimental value of the desorption yield {eta}{sub {gamma}}=0.02 molecules/gamma. Possible techniques to reduce the effect of the desorption background are presented.

Scattering of mass-3 projectiles from heavy nuclei

International Nuclear Information System (INIS)

Mukhopadyay, S.; Srivastava, D.K.; Ganguly, N.K.

1976-01-01

The interaction between heavy ions is a subject of great interest. It is well known that α-particle scattering shows most of the features which are observed in heavy ion scattering. In as much as mass-3 system is intermediate between heavy and light particles it will be interesting to investigate the scattering of mass-3 projectiles to see if it is possible to extend it to study the heavy ion scattering. Indeed; it has been seen that the 'molecular type' potentials, with a soft repulsive core and a shallow attractive well used for heavy ion collisions can be used to fit the elastic scattering data of mass-3 projectiles also. In the first part of this paper, a description is given of how this potential is generated with a special emphasis on saturation and second order effect through a density dependent interaction between nucleon and mass-3 projectiles. In the second part it is shown that the asymmetry dependence observed in the potential describing the scattering of mass-3 particles from heavier nuclei actually originates from the isospin interaction, when triton and helion are treated as two members of an isospin doublet. (Auth.)

Transport cross section for small-angle scattering

International Nuclear Information System (INIS)

D'yakonov, M.I.; Khaetskii, A.V.

1991-01-01

Classical mechanics is valid for describing potential scattering under the conditions (1) λ much-lt α and (2) U much-gt ℎυ/α, where λ is the de Broglie wavelength, α is the characteristic size of the scatterer, U is the characteristic value of the potential energy, and υ is the velocity of the scattered particle. The second of these conditions means that the typical value of the classical scattering angle is far larger than the diffraction angle λ/α. In this paper the authors show that this second condition need not hold in a derivation of the transport cross section. In other words, provided that the condition λ much-lt α holds, it is always possible to calculate the transport cross section from the expressions of classical mechanics, even in the region U approx-lt ℎυ/α, where the scattering is diffractive,and the differential cross section is greatly different from the classical cross section. The transport cross section is found from the classical expression even in the anticlassical case U much-lt ℎυ/α, where the Born approximation can be used

The Aharonov–Bohm effect in scattering theory

International Nuclear Information System (INIS)

Sitenko, Yu.A.; Vlasii, N.D.

2013-01-01

The Aharonov–Bohm effect is considered as a scattering event with nonrelativistic charged particles of the wavelength which is less than the transverse size of an impenetrable magnetic vortex. The quasiclassical WKB method is shown to be efficient in solving this scattering problem. We find that the scattering cross section consists of two terms, one describing the classical phenomenon of elastic reflection and another one describing the quantum phenomenon of diffraction; the Aharonov–Bohm effect is manifested as a fringe shift in the diffraction pattern. Both the classical and the quantum phenomena are independent of the choice of a boundary condition at the vortex edge, providing that probability is conserved. We show that a propagation of charged particles can be controlled by altering the flux of a magnetic vortex placed on their way. -- Highlights: •Aharonov–Bohm effect as a scattering event. •Impenetrable magnetic vortex of nonzero transverse size. •Scattering cross section is independent of a self-adjoint extension employed. •Classical phenomenon of elastic reflection and quantum phenomenon of diffraction. •Aharonov–Bohm effect as a fringe shift in the diffraction pattern

Neutron spin echo scattering angle measurement (SESAME)

International Nuclear Information System (INIS)

Pynn, R.; Fitzsimmons, M.R.; Fritzsche, H.; Gierlings, M.; Major, J.; Jason, A.

2005-01-01

We describe experiments in which the neutron spin echo technique is used to measure neutron scattering angles. We have implemented the technique, dubbed spin echo scattering angle measurement (SESAME), using thin films of Permalloy electrodeposited on silicon wafers as sources of the magnetic fields within which neutron spins precess. With 30-μm-thick films we resolve neutron scattering angles to about 0.02 deg. with neutrons of 4.66 A wavelength. This allows us to probe correlation lengths up to 200 nm in an application to small angle neutron scattering. We also demonstrate that SESAME can be used to separate specular and diffuse neutron reflection from surfaces at grazing incidence. In both of these cases, SESAME can make measurements at higher neutron intensity than is available with conventional methods because the angular resolution achieved is independent of the divergence of the neutron beam. Finally, we discuss the conditions under which SESAME might be used to probe in-plane structure in thin films and show that the method has advantages for incident neutron angles close to the critical angle because multiple scattering is automatically accounted for

Neutron-proton scattering

International Nuclear Information System (INIS)

Doll, P.

1990-02-01

Neutron-proton scattering as fundamental interaction process below and above hundred MeV is discussed. Quark model inspired interactions and phenomenological potential models are described. The seminar also indicates the experimental improvements for achieving new precise scattering data. Concluding remarks indicate the relevance of nucleon-nucleon scattering results to finite nuclei. (orig.) [de

Magnetic diffuse scattering: a theorist`s perspective

Energy Technology Data Exchange (ETDEWEB)

Long, M W [Birmingham Univ., School of Physics, Birmingham (United Kingdom)

1996-11-01

We attempt to show that magnetic diffuse scattering is the natural probe for frustrated antiferromagnetism. Comparison between nuclear and magnetic diffuse scattering compares the range of atomic clustering with the range of the magnetic impurity. At low temperature frustration is expected to lead to large differences which are a natural signature for the relevance of such frustration effects. We provide some elementary examples in first-row transition metals which display fairly dramatic effects. (author) 11 figs., tabs., 8 refs.

Scattering theory

International Nuclear Information System (INIS)

Sitenko, A.

1991-01-01

This book emerged out of graduate lectures given by the author at the University of Kiev and is intended as a graduate text. The fundamentals of non-relativistic quantum scattering theory are covered, including some topics, such as the phase-function formalism, separable potentials, and inverse scattering, which are not always coverded in textbooks on scattering theory. Criticisms of the text are minor, but the reviewer feels an inadequate index is provided and the citing of references in the Russian language is a hindrance in a graduate text

Neutron Scattering Differential Cross Sections for 12C

Science.gov (United States)

Byrd, Stephen T.; Hicks, S. F.; Nickel, M. T.; Block, S. G.; Peters, E. E.; Ramirez, A. P. D.; Mukhopadhyay, S.; McEllistrem, M. T.; Yates, S. W.; Vanhoy, J. R.

2016-09-01

Because of the prevalence of its use in the nuclear energy industry and for our overall understanding of the interactions of neutrons with matter, accurately determining the effects of fast neutrons scattering from 12C is important. Previously measured 12C inelastic neutron scattering differential cross sections found in the National Nuclear Data Center (NNDC) show significant discrepancies (>30%). Seeking to resolve these discrepancies, neutron inelastic and elastic scattering differential cross sections for 12C were measured at the University of Kentucky Acceleratory Laboratory for incident neutron energies of 5.58, 5.83, and 6.04 MeV. Quasi mono-energetic neutrons were scattered off an enriched 12C target (>99.99%) and detected by a C6D6 liquid scintillation detector. Time-of-flight (TOF) techniques were used to determine scattered neutron energies and allowed for elastic/inelastic scattering distinction. Relative detector efficiencies were determined through direct measurements of neutrons produced by the 2H(d,n) and 3H(p,n) source reactions, and absolute normalization factors were found by comparing 1H scattering measurements to accepted NNDC values. This experimental procedure has been successfully used for prior neutron scattering measurements and seems well-suited to our current objective. Significant challenges were encountered, however, with measuring the neutron detector efficiency over the broad incident neutron energy range required for these measurements. Funding for this research was provided by the National Nuclear Security Administration (NNSA).

Scattering calculation and image reconstruction using elevation-focused beams.

Science.gov (United States)

Duncan, David P; Astheimer, Jeffrey P; Waag, Robert C

2009-05-01

Pressure scattered by cylindrical and spherical objects with elevation-focused illumination and reception has been analytically calculated, and corresponding cross sections have been reconstructed with a two-dimensional algorithm. Elevation focusing was used to elucidate constraints on quantitative imaging of three-dimensional objects with two-dimensional algorithms. Focused illumination and reception are represented by angular spectra of plane waves that were efficiently computed using a Fourier interpolation method to maintain the same angles for all temporal frequencies. Reconstructions were formed using an eigenfunction method with multiple frequencies, phase compensation, and iteration. The results show that the scattered pressure reduces to a two-dimensional expression, and two-dimensional algorithms are applicable when the region of a three-dimensional object within an elevation-focused beam is approximately constant in elevation. The results also show that energy scattered out of the reception aperture by objects contained within the focused beam can result in the reconstructed values of attenuation slope being greater than true values at the boundary of the object. Reconstructed sound speed images, however, appear to be relatively unaffected by the loss in scattered energy. The broad conclusion that can be drawn from these results is that two-dimensional reconstructions require compensation to account for uncaptured three-dimensional scattering.

The scattering of a cylindrical invisibility cloak: reduced parameters and optimization

DEFF Research Database (Denmark)

Peng, Liang; Ran, L.; Mortensen, Asger

2011-01-01

We investigate the scattering of 2D cylindrical invisibility cloaks with simplified constitutive parameters with the assistance of scattering coefficients. We show that the scattering of the cloaks originates not only from the boundary conditions but also from the spatial variation of the component...... of permittivity/permeability. According to our formulation, we propose some restrictions to the invisibility cloak in order to minimize its scattering after the simplification has taken place. With our theoretical analysis, it is possible to design a simplified cloak using some peculiar composites...

Scattered radiation from applicators in clinical electron beams

International Nuclear Information System (INIS)

Battum, L J van; Zee, W van der; Huizenga, H

2003-01-01

In radiotherapy with high-energy (4-25 MeV) electron beams, scattered radiation from the electron applicator influences the dose distribution in the patient. In most currently available treatment planning systems for radiotherapy this component is not explicitly included and handled only by a slight change of the intensity of the primary beam. The scattered radiation from an applicator changes with the field size and distance from the applicator. The amount of scattered radiation is dependent on the applicator design and on the formation of the electron beam in the treatment head. Electron applicators currently applied in most treatment machines are essentially a set of diaphragms, but still do produce scattered radiation. This paper investigates the present level of scattered dose from electron applicators, and as such provides an extensive set of measured data. The data provided could for instance serve as example input data or benchmark data for advanced treatment planning algorithms which employ a parametrized initial phase space to characterize the clinical electron beam. Central axis depth dose curves of the electron beams have been measured with and without applicators in place, for various applicator sizes and energies, for a Siemens Primus, a Varian 2300 C/D and an Elekta SLi accelerator. Scattered radiation generated by the applicator has been found by subtraction of the central axis depth dose curves, obtained with and without applicator. Scattered radiation from Siemens, Varian and Elekta electron applicators is still significant and cannot be neglected in advanced treatment planning. Scattered radiation at the surface of a water phantom can be as high as 12%. Scattered radiation decreases almost linearly with depth. Scattered radiation from Varian applicators shows clear dependence on beam energy. The Elekta applicators produce less scattered radiation than those of Varian and Siemens, but feature a higher effective angular variance. The scattered

Size measuring techniques as tool to monitor pea proteins intramolecular crosslinking by transglutaminase treatment.

Science.gov (United States)

Djoullah, Attaf; Krechiche, Ghali; Husson, Florence; Saurel, Rémi

2016-01-01

In this work, techniques for monitoring the intramolecular transglutaminase cross-links of pea proteins, based on protein size determination, were developed. Sodium dodecyl sulfate-polyacrylamide gel electrophoresis profiles of transglutaminase-treated low concentration (0.01% w/w) pea albumin samples, compared to the untreated one (control), showed a higher electrophoretic migration of the major albumin fraction band (26 kDa), reflecting a decrease in protein size. This protein size decrease was confirmed, after DEAE column purification, by dynamic light scattering (DLS) where the hydrodynamic radius of treated samples appears to be reduced compared to the control one. Copyright © 2015 Elsevier Ltd. All rights reserved.

Characterization of tin oxide nanoparticles synthesized via oxidation from metal

International Nuclear Information System (INIS)

Abruzzi, R.C.; Dedavid, B.A.; Pires, M.J.R.; Streicher, M.

2014-01-01

The tin oxide (SnO_2) is a promising material with great potential for applications such as gas sensors and catalysts. This oxide nanostructures show higher activation efficiency due to its larger effective surface. This paper presents the synthesis and characterization of the tin oxide in different conditions, via oxidation of pure tin with nitric acid. Results obtained from the characterization of SnO_2 powder by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDX), Particle size by Dynamic Light Scattering (DLS) and Infrared Spectroscopy (FTIR) indicated that the conditions were suitable for the synthesis to obtain manometric tin oxide granules with crystalline structure of rutile. (author)

Effective exchange potentials for electronically inelastic scattering

International Nuclear Information System (INIS)

Schwenke, D.W.; Staszewska, G.; Truhlar, D.G.

1983-01-01

We propose new methods for solving the electron scattering close coupling equations employing equivalent local exchange potentials in place of the continuum-multiconfiguration-Hartree--Fock-type exchange kernels. The local exchange potentials are Hermitian. They have the correct symmetry for any symmetries of excited electronic states included in the close coupling expansion, and they have the same limit at very high energy as previously employed exchange potentials. Comparison of numerical calculations employing the new exchange potentials with the results obtained with the standard nonlocal exchange kernels shows that the new exchange potentials are more accurate than the local exchange approximations previously available for electronically inelastic scattering. We anticipate that the new approximations will be most useful for intermediate-energy electronically inelastic electron--molecule scattering

Born amplitudes and seagull term in meson-soliton scattering

International Nuclear Information System (INIS)

Liang, Y.G.; Li, B.A.; Liu, K.F.; Su, R.K.

1990-01-01

The meson-soliton scattering for the φ 4 theory in 1+1 dimensions is calculated. We show that when the seagull term from the equal time commutator is included in addition to the Born amplitudes, the t-matrix from the reduction formula approach is identical to that of the potential scattering with small quantum fluctuations to leading order in weak coupling. The seagull term is equal to the Born term in the potential scattering. This confirms the speculation that the leading order Yukawa coupling is derivable from the classical soliton. (orig.)

Concentric layered Hermite scatterers

Science.gov (United States)

Astheimer, Jeffrey P.; Parker, Kevin J.

2018-05-01

The long wavelength limit of scattering from spheres has a rich history in optics, electromagnetics, and acoustics. Recently it was shown that a common integral kernel pertains to formulations of weak spherical scatterers in both acoustics and electromagnetic regimes. Furthermore, the relationship between backscattered amplitude and wavenumber k was shown to follow power laws higher than the Rayleigh scattering k2 power law, when the inhomogeneity had a material composition that conformed to a Gaussian weighted Hermite polynomial. Although this class of scatterers, called Hermite scatterers, are plausible, it may be simpler to manufacture scatterers with a core surrounded by one or more layers. In this case the inhomogeneous material property conforms to a piecewise continuous constant function. We demonstrate that the necessary and sufficient conditions for supra-Rayleigh scattering power laws in this case can be stated simply by considering moments of the inhomogeneous function and its spatial transform. This development opens an additional path for construction of, and use of scatterers with unique power law behavior.

POLARIZATION IMAGING AND SCATTERING MODEL OF CANCEROUS LIVER TISSUES

Directory of Open Access Journals (Sweden)

DONGZHI LI

2013-07-01

Full Text Available We apply different polarization imaging techniques for cancerous liver tissues, and compare the relative contrasts for difference polarization imaging (DPI, degree of polarization imaging (DOPI and rotating linear polarization imaging (RLPI. Experimental results show that a number of polarization imaging parameters are capable of differentiating cancerous cells in isotropic liver tissues. To analyze the contrast mechanism of the cancer-sensitive polarization imaging parameters, we propose a scattering model containing two types of spherical scatterers and carry on Monte Carlo simulations based on this bi-component model. Both the experimental and Monte Carlo simulated results show that the RLPI technique can provide a good imaging contrast of cancerous tissues. The bi-component scattering model provides a useful tool to analyze the contrast mechanism of polarization imaging of cancerous tissues.

In-vitro efficacy of different morphology zinc oxide nanopowders on Streptococcus sobrinus and Streptococcus mutans.

Science.gov (United States)

Mohd Bakhori, Siti Khadijah; Mahmud, Shahrom; Ling, Chuo Ann; Sirelkhatim, Amna Hassan; Hasan, Habsah; Mohamad, Dasmawati; Masudi, Sam'an Malik; Seeni, Azman; Abd Rahman, Rosliza

2017-09-01

ZnO with two different morphologies were used to study the inhibition of Streptococcus sobrinus and Streptococcus mutans which are closely associated with tooth cavity. Rod-like shaped ZnO-A and plate-like shaped ZnO-B were produced using a zinc boiling furnace. The nanopowders were characterized using energy filtered transmission electron microscopy (EFTEM), X-ray diffraction (XRD), photoluminescence (PL) spectroscopy, Raman spectroscopy and dynamic light scattering (DLS) to confirm the properties of the ZnO polycrystalline wurtzite structures. XRD results show that the calculated crystallite sizes of ZnO-A and ZnO-B were 36.6 and 39.4nm, respectively, whereas DLS revealed particle size distributions of 21.82nm (ZnO-A) and 52.21nm (ZnO-B). PL spectra showed ion vacancy defects related to green and red luminescence for both ZnO particles. These defects evolved during the generation of reactive oxygen species which contributed to the antibacterial activity. Antibacterial activity was investigated using microdilution technique towards S. sobrinus and S. mutans at different nanopowder concentrations. Results showed that ZnO-A exhibited higher inhibition on both bacteria compared with ZnO-B. Moreover, S. mutans was more sensitive compared with S. sobrinus because of its higher inhibition rate. Copyright © 2017 Elsevier B.V. All rights reserved.

A 'range test' for determining scatterers with unknown physical properties

Science.gov (United States)

Potthast, Roland; Sylvester, John; Kusiak, Steven

2003-06-01

We describe a new scheme for determining the convex scattering support of an unknown scatterer when the physical properties of the scatterers are not known. The convex scattering support is a subset of the scatterer and provides information about its location and estimates for its shape. For convex polygonal scatterers the scattering support coincides with the scatterer and we obtain full shape reconstructions. The method will be formulated for the reconstruction of the scatterers from the far field pattern for one or a few incident waves. The method is non-iterative in nature and belongs to the type of recently derived generalized sampling schemes such as the 'no response test' of Luke-Potthast. The range test operates by testing whether it is possible to analytically continue a far field to the exterior of any test domain Omegatest. By intersecting the convex hulls of various test domains we can produce a minimal convex set, the convex scattering support of which must be contained in the convex hull of the support of any scatterer which produces that far field. The convex scattering support is calculated by testing the range of special integral operators for a sampling set of test domains. The numerical results can be used as an approximation for the support of the unknown scatterer. We prove convergence and regularity of the scheme and show numerical examples for sound-soft, sound-hard and medium scatterers. We can apply the range test to non-convex scatterers as well. We can conclude that an Omegatest which passes the range test has a non-empty intersection with the infinity-support (the complement of the unbounded component of the complement of the support) of the true scatterer, but cannot find a minimal set which must be contained therein.

K-nucleon scattering and the cloudy bag model

International Nuclear Information System (INIS)

Jennings, B.K.

1986-01-01

The cloudy bag model (CBM) has been applied with considerable success to low energy meson-nucleon scattering. In this talk I will describe in particular calculations for kaon-nucleon and antikaon-nucleon scattering. The main emphasis will be on s-waves with special attention paid to the antikaon-nucleon system in the isospin zero channel where the Λ(1405) is important. In the CBM the Λ(1405) is an antikaon-nucleon bound state and I show that this interpretation is consistent with the antikaon-nucleon scattering in the region of the Λ(1670) and Λ(1800) although ambiguities in the phase shift analysis prevent a definite conclusion

K-nucleon scattering and the cloudy bag model

Science.gov (United States)

Jennings, B. K.

1986-10-01

The cloudy bag model (CBM) has been applied with considerable success to low energy meson-nucleon scattering. In this talk I will describe in particular calculations for kaon-nucleon and antikaon-nucleon scattering. The main emphasis will be on s-waves with special attention paid to the antikaon-nucleon system in the isospin zero channel where the Λ(1405) is important. In the CBM the Λ(1405) is an antikaon-nucleon bound state and I show that this interpretation is consistent with the antikaon-nucleon scattering in the region of the Λ(1670) and Λ(1800) although ambiguities in the phase shift analysis prevent a definite conclusion.

Four-phonon scattering significantly reduces intrinsic thermal conductivity of solids

Science.gov (United States)

Feng, Tianli; Lindsay, Lucas; Ruan, Xiulin

2017-10-01

For decades, the three-phonon scattering process has been considered to govern thermal transport in solids, while the role of higher-order four-phonon scattering has been persistently unclear and so ignored. However, recent quantitative calculations of three-phonon scattering have often shown a significant overestimation of thermal conductivity as compared to experimental values. In this Rapid Communication we show that four-phonon scattering is generally important in solids and can remedy such discrepancies. For silicon and diamond, the predicted thermal conductivity is reduced by 30% at 1000 K after including four-phonon scattering, bringing predictions in excellent agreement with measurements. For the projected ultrahigh-thermal conductivity material, zinc-blende BAs, a competitor of diamond as a heat sink material, four-phonon scattering is found to be strikingly strong as three-phonon processes have an extremely limited phase space for scattering. The four-phonon scattering reduces the predicted thermal conductivity from 2200 to 1400 W/m K at room temperature. The reduction at 1000 K is 60%. We also find that optical phonon scattering rates are largely affected, being important in applications such as phonon bottlenecks in equilibrating electronic excitations. Recognizing that four-phonon scattering is expensive to calculate, in the end we provide some guidelines on how to quickly assess the significance of four-phonon scattering, based on energy surface anharmonicity and the scattering phase space. Our work clears the decades-long fundamental question of the significance of higher-order scattering, and points out ways to improve thermoelectrics, thermal barrier coatings, nuclear materials, and radiative heat transfer.

SCATTER

International Nuclear Information System (INIS)

Broome, J.

1965-11-01

The programme SCATTER is a KDF9 programme in the Egtran dialect of Fortran to generate normalized angular distributions for elastically scattered neutrons from data input as the coefficients of a Legendre polynomial series, or from differential cross-section data. Also, differential cross-section data may be analysed to produce Legendre polynomial coefficients. Output on cards punched in the format of the U.K. A. E. A. Nuclear Data Library is optional. (author)

Moeller scattering and the measurement of beta-ray longitudinal polarization

International Nuclear Information System (INIS)

Kliwer, J.

1989-01-01

Two problems that are inherent in the measurement of longitudinal polarization of beta rays via Moeller scattering (Bhabha scattering for positrons) are the low signal-to-noise ratio due to the electron-nucleon-scattered background and the small fraction of electrons that are polarized in the target. The present article shows how to optimize the signal-to-noise ratio by the collection of Moeller-scattered events using a thick-lens beta-ray spectrometer where the entrance baffle is set very narow to accommodate the relativistically contracted cone of Moeller events; this in turn minimizes the electron-nucleon-scattered background and maximizes the signal-to-noise ratio. In the case of positrons, recent studies of electron channeling in crystals suggest a target that will reduce Bhabha scattering from the large fraction of unpolarized inner-shell electrons and predominantly pick off the polarized fraction of target electrons. (orig.)

Diffractive scattering

CERN Document Server

De Wolf, E.A.

2002-01-01

We discuss basic concepts and properties of diffractive phenomena in soft hadron collisions and in deep-inelastic scattering at low Bjorken-x. The paper is not a review of the rapidly developing field but presents an attempt to show in simple terms the close inter-relationship between the dynamics of high-energy hadronic and deep-inelastic diffraction. Using the saturation model of Golec-Biernat and Wusthoff as an example, a simple explanation of geometrical scaling is presented. The relation between the QCD anomalous multiplicity dimension and the Pomeron intercept is discussed.

Diffractive Scattering

International Nuclear Information System (INIS)

Wolf, E.A. de

2002-01-01

We discuss basic concepts and properties of diffractive phenomena in soft hadron collisions and in deep-inelastic scattering at low Bjorken - x. The paper is not a review of the rapidly developing field but presents an attempt to show in simple terms the close inter-relationship between the dynamics of high-energy hadronic and deep-inelastic diffraction. Using the saturation model of Golec-Biernat and Wuesthoff as an example, a simple explanation of geometrical scaling is presented. The relation between the QCD anomalous multiplicity dimension and the Pomeron intercept is discussed. (author)

Absorption in multiple scattering systems of coated spheres: design applications

International Nuclear Information System (INIS)

Stout, Brian; Andraud, Christine; Stout, Sophie; Lafait, Jacques

2003-01-01

We illustrate the utility of some recently derived transfer matrix methods for electromagnetic scattering calculations in systems composed of coated spherical scatterers. Any of the spherical coatings, cores, or host media may be composed of absorbing materials. Our formulae permit the calculation of local absorption in either orientation fixed or orientation averaged situations. We introduce methods for estimating the macroscopic transport properties of such media, and show how our scattering calculations can permit 'design' optimization of macroscopic properties

Locally-enhanced light scattering by a monocrystalline silicon wafer

Directory of Open Access Journals (Sweden)

Li Ma

2018-03-01

Full Text Available We study the optical properties of light scattering by a monocrystalline silicon wafer, by using transparent material to replicate its surface structure and illuminating a fabricated sample with a laser source. The experimental results show that the scattering field contains four spots of concentrated intensity with high local energy, and these spots are distributed at the four vertices of a square with lines of intensity linking adjacent spots. After discussing simulations of and theory about the formation of this light scattering, we conclude that the scattering field is formed by the effects of both geometrical optics and physical optics. Moreover, we calculate the central angle of the spots in the light field, and the result indicates that the locally-enhanced intensity spots have a definite scattering angle. These results may possibly provide a method for improving energy efficiency within mono-Si based solar cells.

DISCUS, Neutron Single to Double Scattering Ratio in Inelastic Scattering Experiment by Monte-Carlo

International Nuclear Information System (INIS)

Johnson, M.W.

1993-01-01

1 - Description of problem or function: DISCUS calculates the ratio of once-scattered to twice-scattered neutrons detected in an inelastic neutron scattering experiment. DISCUS also calculates the flux of once-scattered neutrons that would have been observed if there were no absorption in the sample and if, once scattered, the neutron would emerge without further re-scattering or absorption. Three types of sample geometry are used: an infinite flat plate, a finite flat plate or a finite length cylinder. (The infinite flat plate is included for comparison with other multiple scattering programs.) The program may be used for any sample for which the scattering law is of the form S(/Q/, omega). 2 - Method of solution: Monte Carlo with importance sampling is used. Neutrons are 'forced' both into useful angular trajectories, and useful energy bins. Biasing of the collision point according to the point of entry of the neutron into the sample is also utilised. The first and second order scattered neutron fluxes are calculated in independent histories. For twice-scattered neutron histories a square distribution in Q-omega space is used to sample the neutron coming from the first scattering event, whilst biasing is used for the second scattering event. (A square distribution is used so as to obtain reasonable inelastic-inelastic statistics.) 3 - Restrictions on the complexity of the problem: Unlimited number of detectors. Max. size of (Q, omega) matrix is 39*149. Max. number of points in momentum space for the scattering cross section is 199

Some Notes on Neutron Up-Scattering and the Doppler-Broadening of High-Z Scattering Resonances

Energy Technology Data Exchange (ETDEWEB)

Parsons, Donald Kent [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-09-28

When neutrons are scattered by target nuclei at elevated temperatures, it is entirely possible that the neutron will actually gain energy (i.e., up-scatter) from the interaction. This phenomenon is in addition to the more usual case of the neutron losing energy (i.e., down-scatter). Furthermore, the motion of the target nuclei can also cause extended neutron down-scattering, i.e., the neutrons can and do scatter to energies lower than predicted by the simple asymptotic models. In recent years, more attention has been given to temperature-dependent scattering cross sections for materials in neutron multiplying systems. This has led to the inclusion of neutron up-scatter in deterministic codes like Partisn and to free gas scattering models for material temperature effects in Monte Carlo codes like MCNP and cross section processing codes like NJOY. The free gas scattering models have the effect of Doppler Broadening the scattering cross section output spectra in energy and angle. The current state of Doppler-Broadening numerical techniques used at Los Alamos for scattering resonances will be reviewed, and suggestions will be made for further developments. The focus will be on the free gas scattering models currently in use and the development of new models to include high-Z resonance scattering effects. These models change the neutron up-scattering behavior.

Thermal diffuse scattering in transmission electron microscopy

Energy Technology Data Exchange (ETDEWEB)

Forbes, B.D.; D' Alfonso, A.J. [School of Physics, University of Melbourne, Parkville, Victoria 3010 (Australia); Findlay, S.D. [School of Physics, Monash University, Victoria 3800 (Australia); Van Dyck, D. [EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp (Belgium); LeBeau, J.M. [North Carolina State University, Raleigh, NC 27695-7907 (United States); Stemmer, S. [Materials Department, University of California, Santa Barbara, CA 93106-5050 (United States); Allen, L.J., E-mail: lja@unimelb.edu.au [School of Physics, University of Melbourne, Parkville, Victoria 3010 (Australia)

2011-12-15

In conventional transmission electron microscopy, thermal scattering significantly affects the image contrast. It has been suggested that not accounting for this correctly is the main cause of the Stobbs factor, the ubiquitous, large contrast mismatch found between theory and experiment. In the case where a hard aperture is applied, we show that previous conclusions drawn from work using bright field scanning transmission electron microscopy and invoking the principle of reciprocity are reliable in the presence of thermal scattering. In the aperture-free case it has been suggested that even the most sophisticated mathematical models for thermal diffuse scattering lack in their numerical implementation, specifically that there may be issues in sampling, including that of the contrast transfer function of the objective lens. We show that these concerns can be satisfactorily overcome with modest computing resources; thermal scattering can be modelled accurately enough for the purpose of making quantitative comparison between simulation and experiment. Spatial incoherence of the source is also investigated. Neglect or inadequate handling of thermal scattering in simulation can have an appreciable effect on the predicted contrast and can be a significant contribution to the Stobbs factor problem. -- Highlights: Black-Right-Pointing-Pointer We determine the numerical requirements for accurate simulation of TDS in CTEM. Black-Right-Pointing-Pointer TDS can be simulated to high precision using the Born-Oppenheimer model. Black-Right-Pointing-Pointer Such calculations establish the contribution of TDS to the Stobbs factor problem. Black-Right-Pointing-Pointer Treating spatial incoherence using envelope functions increases image contrast. Black-Right-Pointing-Pointer Rigorous treatment of spatial incoherence significantly reduces image contrast.

Thomson Scattering

NARCIS (Netherlands)

Donne, A. J. H.

1994-01-01

Thomson scattering is a very powerful diagnostic which is applied at nearly every magnetic confinement device. Depending on the experimental conditions different plasma parameters can be diagnosed. When the wave vector is much larger than the plasma Debye length, the total scattered power is

Seismic scatterers in the mid-lower mantle beneath Tonga-Fiji

Science.gov (United States)

Kaneshima, Satoshi

2018-01-01

We analyze deep and intermediate-depth earthquakes at the Tonga-Fiji region in order to reveal the distribution of scattering objects in the mid-lower mantle. By array processing waveform data recorded at regional seismograph stations in the US, Alaska, and Japan, we investigate S-to-P scattering waves in the P coda, which arise from kilometer-scale chemically distinct objects in the mid-lower mantle beneath Tonga-Fiji. With ten scatterers previously reported by the author included, twenty-three mid-lower mantle scatterers have been detected below 900 km depth, while scatterers deeper than 1900 km have not been identified. Strong mid-lower mantle S-to-P scattering most frequently occurs at the scatterers located within a depth range between 1400 km and 1600 km. The number of scatterers decreases below 1600 km depth, and the deeper objects tend to be weaker. The scatterer distribution may reflect diminishing elastic anomalies of basaltic rocks with depth relative to the surrounding mantle rocks, which mineral physics has predicted to occur. The predominant occurrence of strong S-to-P scattering waves within a narrow depth range may reflect significant reduction of rigidity due to the ferro-elastic transformation of stishovite in basaltic rocks. Very large signals associated with mid-mantle scatterers are observed only for a small portion of the entire earthquake-array pairs. Such infrequent observations of large scattering signals, combined with quite large event-to-event differences in the scattering intensity for each scatterer, suggest both that the strong arrivals approximately represent ray theoretical S-to-P converted waves at objects with a plane geometry. The plane portions of the strong scatterers may often dip steeply, with the size exceeding 100 km. For a few strong scatterers, the range of receivers showing clear scattered waves varies substantially from earthquake-array pair to pair. Some of the scatterers are also observed at different arrays that have

Scattering of 20Ne atoms from the (001) face of LiF

International Nuclear Information System (INIS)

Semerad, E.; Hoerl, E.M.

1983-01-01

An apparatus for measurements of inelastic scattering processes of gas atoms from crystal surfaces is described. Scattering experiments with Neon atoms of thermal energy on the (001) LiF surface in the azimuth are discussed. Inelastic scattering shows large contributions of single phonon interactions as well as of modes originating from the bulk bands. (Author)

Polarized Neutron Scattering

OpenAIRE

Roessli, B.; Böni, P.

2000-01-01

The technique of polarized neutron scattering is reviewed with emphasis on applications. Many examples of the usefulness of the method in various fields of physics are given like the determination of spin density maps, measurement of complex magnetic structures with spherical neutron polarimetry, inelastic neutron scattering and separation of coherent and incoherent scattering with help of the generalized XYZ method.

Ultrasound scatter in heterogeneous 3D microstructures: Parameters affecting multiple scattering

Science.gov (United States)

Engle, B. J.; Roberts, R. A.; Grandin, R. J.

2018-04-01

This paper reports on a computational study of ultrasound propagation in heterogeneous metal microstructures. Random spatial fluctuations in elastic properties over a range of length scales relative to ultrasound wavelength can give rise to scatter-induced attenuation, backscatter noise, and phase front aberration. It is of interest to quantify the dependence of these phenomena on the microstructure parameters, for the purpose of quantifying deleterious consequences on flaw detectability, and for the purpose of material characterization. Valuable tools for estimation of microstructure parameters (e.g. grain size) through analysis of ultrasound backscatter have been developed based on approximate weak-scattering models. While useful, it is understood that these tools display inherent inaccuracy when multiple scattering phenomena significantly contribute to the measurement. It is the goal of this work to supplement weak scattering model predictions with corrections derived through application of an exact computational scattering model to explicitly prescribed microstructures. The scattering problem is formulated as a volume integral equation (VIE) displaying a convolutional Green-function-derived kernel. The VIE is solved iteratively employing FFT-based con-volution. Realizations of random microstructures are specified on the micron scale using statistical property descriptions (e.g. grain size and orientation distributions), which are then spatially filtered to provide rigorously equivalent scattering media on a length scale relevant to ultrasound propagation. Scattering responses from ensembles of media representations are averaged to obtain mean and variance of quantities such as attenuation and backscatter noise levels, as a function of microstructure descriptors. The computational approach will be summarized, and examples of application will be presented.

Visualizing quantum scattering on the CM-2 supercomputer

International Nuclear Information System (INIS)

Richardson, J.L.

1991-01-01

We implement parallel algorithms for solving the time-dependent Schroedinger equation on the CM-2 supercomputer. These methods are unconditionally stable as well as unitary at each time step and have the advantage of being spatially local and explicit. We show how to visualize the dynamics of quantum scattering using techniques for visualizing complex wave functions. Several scattering problems are solved to demonstrate the use of these methods. (orig.)

The scattering properties of anisotropic dielectric spheres on electromagnetic waves

International Nuclear Information System (INIS)

Chen Hui; Zhang Weiyi; Wang Zhenlin; Ming Naiben

2004-01-01

The scattering coefficients of spheres with dielectric anisotropy are calculated analytically in this paper using the perturbation method. It is found that the different modes of vector spherical harmonics and polarizations are coupled together in the scattering coefficients (c-matrix) in contrast to the isotropic case where all modes are decoupled from each other. The generalized c-matrix is then incorporated into our codes for a vector wave multiple scattering program; the preliminary results on face centred cubic structure show that dielectric anisotropy reduces the symmetry of the scattering c-matrix and removes the degeneracy in photonic band structures composed of isotropic dielectric spheres

Relativistic theory of particles in a scattering flow III: photon transport.

Science.gov (United States)

Achterberg, A.; Norman, C. A.

2018-06-01

We use the theory developed in Achterberg & Norman (2018a) and Achterberg & Norman (2018b) to calculate the stress due to photons that are scattered elastically by a relativistic flow. We show that the energy-momentum tensor of the radiation takes the form proposed by Eckart (1940). In particular we show that no terms associated with a bulk viscosity appear if one makes the diffusion approximation for radiation transport and treats the radiation as a separate fluid. We find only shear (dynamic) viscosity terms and heat flow terms in our expression for the energy-momentum tensor. This conclusion holds quite generally for different forms of scattering: Krook-type integral scattering, diffusive (Fokker-Planck) scattering and Thomson scattering. We also derive the transport equation in the diffusion approximation that shows the effects of the flow on the photon gas in the form of a combination of adiabatic heating and an irreversible heating term. We find no diffusive changes to the comoving number density and energy density of the scattered photons, in contrast with some published results in Radiation Hydrodynamics. It is demonstrated that these diffusive corrections to the number- and energy density of the photons are in fact higher-order terms that can (and should) be neglected in the diffusion approximation. Our approach eliminates these terms at the root of the expansion that yields the anisotropic terms in the phase-space density of particles and photons, the terms responsible for the photon viscosity.

X-ray small angle scattering of polymer solutions

International Nuclear Information System (INIS)

Koyama, Ryuzo

1975-01-01

In recent papers, the calculated results were reported on the angular dependence of the intensity of scattered light or X-ray by chain polymers, on the basis of a stiff chain model. As the results, the curves of S 2 P (theta) corresponding to Kratky plot, for different molecular expansion, showed a plateau, and the height of the plateau was proportional to the inverse of molecular expansion coefficient α 2 . But as seen later, there is some possibility that the assumption made in the calculation overestimated the expansion of small segments which theoretically determines scattering curves at large scattering angles, such as the plateau. Accordingly, modified calculation was carried out by adopting the stiff chain polymer model as the previous case. When the contour length of a chain segment is very long, it can be treated approximately as a Gaussian coil, thus the equation for a chain segment expansion coefficient α (t) was obtained. Then the mean square distance of chain segments of polymer molecules was able to be determined, and the equation for a particle scattering factor P(theta) was obtained. The numerical calculation of P(theta) showed that this modified assumption considerably decreased the effect of molecular expansion on P(theta), and the curves of S 2 P(theta) increased monotonously without showing the plateau. The result of this calculation was compared with the experimental curves of polystyrene-toluene solution, and the agreement better than before was obtained. (Kako, I.)

Medium energy ion scattering (MEIS)

International Nuclear Information System (INIS)

Dittmann, K.; Markwitz, A.

2009-01-01

This report gives an overview about the technique and experimental study of medium energy ion scattering (MEIS) as a quantitative technique to determine and analyse the composition and geometrical structure of crystalline surfaces and near surface-layers by measuring the energy and yield of the backscattered ions. The use of a lower energy range of 50 to 500 keV accelerated ions impinging onto the target surface and the application of a high-resolution electrostatic energy analyser (ESA) makes medium energy ion scattering spectroscopy into a high depth resolution and surface-sensitive version of RBS with less resulting damage effects. This report details the first steps of research in that field of measurement technology using medium energetic backscattered ions detected by means of a semiconductor radiation detector instead of an ESA. The study of medium energy ion scattering (MEIS) has been performed using the 40 keV industrial ion implanter established at GNS Sciences remodelled with supplementary high voltage insulation for the ion source in order to apply voltages up to 45 kV, extra apertures installed in the beamline and sample chamber in order to set the beam diameter accurately, and a semiconductor radiation detector. For measurement purposes a beam of positive charged helium ions accelerated to an energy of about 80 keV has been used impinging onto target surfaces of lead implanted into silicon (PbSi), scandium implanted into aluminium (ScAl), aluminium foil (Al) and glassy carbon (C). First results show that it is possible to use the upgraded industrial implanter for medium energy ion scattering. The beam of 4 He 2+ with an energy up to 88 keV has been focussed to 1 mm in diameter. The 5 nA ion beam hit the samples under 2 x 10 -8 mbar. The results using the surface barrier detector show scattering events from the samples. Cooling of the detector to liquid nitrogen temperatures reduced the electronic noise in the backscattering spectrum close to zero. A

Scattering amplitude of ultracold atoms near the p-wave magnetic Feshbach resonance

International Nuclear Information System (INIS)

Zhang Peng; Naidon, Pascal; Ueda, Masahito

2010-01-01

Most of the current theories on the p-wave superfluid in cold atomic gases are based on the effective-range theory for the two-body scattering, where the low-energy p-wave scattering amplitude f 1 (k) is given by f 1 (k)=-1/[ik+1/(Vk 2 )+1/R]. Here k is the incident momentum, V and R are the k-independent scattering volume and effective range, respectively. However, due to the long-range nature of the van der Waals interaction between two colliding ultracold atoms, the p-wave scattering amplitude of the two atoms is not described by the effective-range theory [J. Math. Phys. 4, 54 (1963); Phys. Rev. A 58, 4222 (1998)]. In this paper we provide an explicit calculation for the p-wave scattering of two ultracold atoms near the p-wave magnetic Feshbach resonance. We show that in this case the low-energy p-wave scattering amplitude f 1 (k)=-1/[ik+1/(V eff k 2 )+1/(S eff k)+1/R eff ] where V eff , S eff , and R eff are k-dependent parameters. Based on this result, we identify sufficient conditions for the effective-range theory to be a good approximation of the exact scattering amplitude. Using these conditions we show that the effective-range theory is a good approximation for the p-wave scattering in the ultracold gases of 6 Li and 40 K when the scattering volume is enhanced by the resonance.

The scattering of a cylindrical invisibility cloak: reduced parameters and optimization

International Nuclear Information System (INIS)

Peng, L; Mortensen, N A; Ran, L

2011-01-01

We investigate the scattering of 2D cylindrical invisibility cloaks with simplified constitutive parameters with the assistance of scattering coefficients. We show that the scattering of the cloaks originates not only from the boundary conditions but also from the spatial variation of the component of permittivity/permeability. According to our formulation, we propose some restrictions to the invisibility cloak in order to minimize its scattering after the simplification has taken place. With our theoretical analysis, it is possible to design a simplified cloak using some peculiar composites such as photonic crystals which mimic an effective refractive index landscape rather than offering effective constitutives, meanwhile cancelling the scattering from the inner and outer boundaries.

Verification of Compton scattering spectrum of a 662 keV photon beam scattered on a cylindrical steel target using MCNP5 code

International Nuclear Information System (INIS)

Thanh, Tran Thien; Nguyen, Vo Hoang; Chuong, Huynh Dinh; Tran, Le Bao; Tam, Hoang Duc; Binh, Nguyen Thi; Tao, Chau Van

2015-01-01

This article focuses on the possible application of a "1"3"7Cs low-radioactive source (5 mCi) and a NaI(Tl) detector for measuring the saturation thickness of solid cylindrical steel targets. In order to increase the reliability of the obtained experimental results and to verify the detector response function of Compton scattering spectrum, simulation using Monte Carlo N-particle (MCNP5) code is performed. The obtained results are in good agreement with the response functions of the simulation scattering and experimental scattering spectra. On the basis of such spectra, the saturation depth of a steel cylinder is determined by experiment and simulation at about 27 mm using gamma energy of 662 keV ("1"3"7Cs) at a scattering angle of 120°. This study aims at measuring the diameter of solid cylindrical objects by gamma-scattering technique. - Highlights: • This study aims a possible application a "1"3"7Cs low-radioactive source (5 mCi) and a NaI(Tl) detector for measuring the saturation thickness of solid cylindrical steel targets by gamma-scattering technique. • Monte Carlo N-particle (MCNP5) code is performed to verify on the detector response function of Compton scattering spectrum. • The results show a good agreement in response function of the experimental and simulation scattering spectra. • The saturation depth of a steel cylinder is determined by experiment and simulation at about 27 mm using gamma energy of 662 keV ("1"3"7Cs) at a scattering angle of 120°.

Strong Three-magnon Scattering in Cuprates by Resonant X-rays

OpenAIRE

Ament, Luuk J. P.; Brink, Jeroen van den

2010-01-01

We show that Resonant Inelastic X-ray scattering (RIXS) is sensitive to three-magnon excitations in cuprates. Even if it requires three electrons to simultaneously flip their spin, the RIXS tri-magnon scattering amplitude is not small. At the Cu $L$-edge its intensity is generally larger than the bi-magnon one and at low transferred momentum even larger than the single-magnon intensity. At the copper $M$-edge the situation is yet more extreme: in this case three-magnon scattering is dominatin...

The Effect of pH and Time on The Stability of Superparamagnetic Maghemite Nanoparticle Suspensions

Directory of Open Access Journals (Sweden)

Nurdin Irwan

2016-01-01

Full Text Available Maghemite (γ-Fe2O3 nanoparticles have been synthesized using a chemical co-precipitation method. The morphology and particle size is characterized using Transmission Electron Microscopy (TEM, and magnetic characterization using Alternating Gradient Magnetometry (AGM. The stability of the maghemite nanoparticles suspension were studied at different pH and time of storage. Dynamic Light Scattering (DLS and Zeta Potential were conducted to determine the stability of the suspensions. TEM observation showed that the particles size is 9.6 nm and have spherical morphology. The particles showed superparamagnetic behavior with saturation magnetization 25.5 emu/g. The suspensions are stable in the acidic condition at pH 4 and alkaline condition at pH 10. The suspensions remain stable after 4 weeks of storage.

Towards a qualitative understanding of the scattering of topological defects

International Nuclear Information System (INIS)

Rosenzweig, C.; Srivastava, A.M.

1991-01-01

Head-on collisions of strings, monopoles, and Skyrmions result in 90 degree scattering. We propose a unified description of these objects (for the global case) as members of a definite class of topological defects. All soliton-soliton pairs that are members of this class scatter at 90 degree in head-on collisions. Our analysis also shows that the scattered solitons are composed of half-portions of the original solitons. We further predict back-to-back scattering for head-on collisions of a soliton-antisoliton pair at sufficiently high energies. We argue that these qualitative aspects of scattering are common because strings, monopoles, and Skyrmions correspond to various winding-number mappings from S n to S n . Our analysis concentrates on the smoothness of the field configurations and may be extendible to the scattering of gauged topological defects. For the case of strings our results lead to an understanding of intercommutivity and the accompanying formation of kinks

Development of general X-ray scattering model

International Nuclear Information System (INIS)

Gray, Joe; Wendt, Scott

2015-01-01

X-ray scattering is a complex process made difficult to describe due to the effects of a complex energy spectrum interacting with a wide range of material types in complex geometry. The scattering is further complicated by the volume of material illuminated and the experimental configuration of the data acquisition. The importance of accounting for the key physics in scattering modeling is critical to the viability of the model. For example, scattering in the detector and the speed of the detector, as measured by the absorbed dose needed to produce a signal, are important in capturing undercut effects. Another example is the noise properties of the detectors are dependent on photon energy. We report on a semi-empirical treatment of x-ray scattering that includes a full energy treatment for a wide range of material types. We also include complex geometry effects that the part shape introduces. The treatment is based on experimental measurements using an energy dispersive germanium detector over energies from treatment is showing good results with experimental measurements of the scattering component agreeing with the model results to the 10% level over the range of x-ray energies and materials typical in industrial applications. Computation times for this model are in the 20 keV to 320 keV. Detector stripping routines for detector artifacts were developed. The computation time is in the range of a few minutes on a typical PC

X-ray scatter data for diagnostic radiology

International Nuclear Information System (INIS)

Dick, C.E.; Soares, C.G.; Motz, J.W.

1978-01-01

The ratio of the scattered to the total X-ray fluence (scatter fraction) at the centre of the image plane for X-rays transmitted through polystyrene phantoms has been measured for X-ray energies of 32 and 69 keV, X-ray beam diameters from 4 to 40 cm, phantom thicknesses from 5 to 30 cm and phantom-to-image-plane separations from 0.3 to 40 cm. The experimental values for this ratio have less than a 10% variation for these two X-ray energies and the experimental data show good agreement with Monte Carlo calculations and available experimental results for low atomic number materials. Based on these results, simple curves are generated which give estimates (+ - 10%) of the scatter fraction for all combinations of the geometric parameters encountered in diagnostic radiology. (author)

The nucleon-nucleus scattering at intermediate energies

International Nuclear Information System (INIS)

Auger, J.-P.

1976-01-01

The Glauber model has the merit to connect directly the nucleon-nucleus elastic differential cross section with the nucleon-nucleon amplitude and nuclear densities. The general agreement between the 1 GeV proton elastic scattering differential cross sections calculated without adjustable parameter and the experimental data (from He 4 to Pb 208 ) is rather satisfactory up to 2. - 2.5 fm -1 momentum transfer. Although the 1 GeV proton elastic scattering experiments constitute at present one of the best method in determining neutron densities, it seems that self-consistent calculations bring the best knowledge of these densities. The model independent analysis performed with electron and proton scattering experiments show that the difference between neutron and proton r.m.s. radius cannot be determined better than 25-30% for Pb 208 [fr

Matter scattering in quadratic gravity and unitarity

Science.gov (United States)

Abe, Yugo; Inami, Takeo; Izumi, Keisuke; Kitamura, Tomotaka

2018-03-01

We investigate the ultraviolet (UV) behavior of two-scalar elastic scattering with graviton exchanges in higher-curvature gravity theory. In Einstein gravity, matter scattering is shown not to satisfy the unitarity bound at tree level at high energy. Among some of the possible directions for the UV completion of Einstein gravity, such as string theory, modified gravity, and inclusion of high-mass/high-spin states, we take R_{μν}^2 gravity coupled to matter. We show that matter scattering with graviton interactions satisfies the unitarity bound at high energy, even with negative norm states due to the higher-order derivatives of metric components. The difference in the unitarity property of these two gravity theories is probably connected to that in another UV property, namely, the renormalizability property of the two.

Optimization-based scatter estimation using primary modulation for computed tomography

Energy Technology Data Exchange (ETDEWEB)

Chen, Yi; Ma, Jingchen; Zhao, Jun, E-mail: junzhao@sjtu.edu.cn [School of Biomedical Engineering, Shanghai Jiao Tong University, Shanghai 200240 (China); Song, Ying [Department of Radiation Oncology, West China Hospital, Sichuan University, Chengdu 610041 (China)

2016-08-15

Purpose: Scatter reduces the image quality in computed tomography (CT), but scatter correction remains a challenge. A previously proposed primary modulation method simultaneously obtains the primary and scatter in a single scan. However, separating the scatter and primary in primary modulation is challenging because it is an underdetermined problem. In this study, an optimization-based scatter estimation (OSE) algorithm is proposed to estimate and correct scatter. Methods: In the concept of primary modulation, the primary is modulated, but the scatter remains smooth by inserting a modulator between the x-ray source and the object. In the proposed algorithm, an objective function is designed for separating the scatter and primary. Prior knowledge is incorporated in the optimization-based framework to improve the accuracy of the estimation: (1) the primary is always positive; (2) the primary is locally smooth and the scatter is smooth; (3) the location of penumbra can be determined; and (4) the scatter-contaminated data provide knowledge about which part is smooth. Results: The simulation study shows that the edge-preserving weighting in OSE improves the estimation accuracy near the object boundary. Simulation study also demonstrates that OSE outperforms the two existing primary modulation algorithms for most regions of interest in terms of the CT number accuracy and noise. The proposed method was tested on a clinical cone beam CT, demonstrating that OSE corrects the scatter even when the modulator is not accurately registered. Conclusions: The proposed OSE algorithm improves the robustness and accuracy in scatter estimation and correction. This method is promising for scatter correction of various kinds of x-ray imaging modalities, such as x-ray radiography, cone beam CT, and the fourth-generation CT.

Modeling of detective quantum efficiency considering scatter-reduction devices

Energy Technology Data Exchange (ETDEWEB)

Park, Ji Woong; Kim, Dong Woon; Kim, Ho Kyung [Pusan National University, Busan (Korea, Republic of)

2016-05-15

The reduction of signal-to-noise ratio (SNR) cannot be restored and thus has become a severe issue in digital mammography.1 Therefore, antiscatter grids are typically used in mammography. Scatter-cleanup performance of various scatter-reduction devices, such as air gaps,2 linear (1D) or cellular (2D) grids,3, 4 and slot-scanning devices,5 has been extensively investigated by many research groups. In the present time, a digital mammography system with the slotscanning geometry is also commercially available.6 In this study, we theoretically investigate the effect of scattered photons on the detective quantum efficiency (DQE) performance of digital mammography detectors by using the cascaded-systems analysis (CSA) approach. We show a simple DQE formalism describing digital mammography detector systems equipped with scatter reduction devices by regarding the scattered photons as additive noise sources. The LFD increased with increasing PMMA thickness, and the amounts of LFD indicated the corresponding SF. The estimated SFs were 0.13, 0.21, and 0.29 for PMMA thicknesses of 10, 20, and 30 mm, respectively. While the solid line describing the measured MTF for PMMA with 0 mm was the result of least-squares of regression fit using Eq. (14), the other lines were simply resulted from the multiplication of the fit result (for PMMA with 0 mm) with the (1-SF) estimated from the LFDs in the measured MTFs. Spectral noise-power densities over the entire frequency range were not much changed with increasing scatter. On the other hand, the calculation results showed that the spectral noise-power densities increased with increasing scatter. This discrepancy may be explained by that the model developed in this study does not account for the changes in x-ray interaction parameters for varying spectral shapes due to beam hardening with increasing PMMA thicknesses.

Study of the multiple scattering effect in TEBENE using the Monte Carlo method

International Nuclear Information System (INIS)

Singkarat, Somsorn.

1990-01-01

The neutron time-of-flight and energy spectra, from the TEBENE set-up, have been calculated by a computer program using the Monte Carlo method. The neutron multiple scattering within the polyethylene scatterer ring is closely investigated. The results show that multiple scattering has a significant effect on the detected neutron yield. They also indicate that the thickness of the scatterer ring has to be carefully chosen. (author)

Rayleigh scattering in few-mode optical fibers.

Science.gov (United States)

Wang, Zhen; Wu, Hao; Hu, Xiaolong; Zhao, Ningbo; Mo, Qi; Li, Guifang

2016-10-24

The extremely low loss of silica fibers has enabled the telecommunication revolution, but single-mode fiber-optic communication systems have been driven to their capacity limits. As a means to overcome this capacity crunch, space-division multiplexing (SDM) using few-mode fibers (FMF) has been proposed and demonstrated. In single-mode optical fibers, Rayleigh scattering serves as the dominant mechanism for optical loss. However, to date, the role of Rayleigh scattering in FMFs remains elusive. Here we establish and experimentally validate a general model for Rayleigh scattering in FMFs. Rayleigh backscattering not only sets the intrinsic loss limit for FMFs but also provides the theoretical foundation for few-mode optical time-domain reflectometry, which can be used to probe perturbation-induced mode-coupling dynamics in FMFs. We also show that forward inter-modal Rayleigh scattering ultimately sets a fundamental limit on inter-modal-crosstalk for FMFs. Therefore, this work not only has implications specifically for SDM systems but also broadly for few-mode fiber optics and its applications in amplifiers, lasers, and sensors in which inter-modal crosstalk imposes a fundamental performance limitation.

Collective Excitations in Liquid Hydrogen Observed by Coherent Neutron Scattering

DEFF Research Database (Denmark)

da Costa Carneiro, Kim; Nielsen, M.; McTague, J. P.

1973-01-01

Coherent scattering of neutrons by liquid parahydrogen shows the existence of well-defined collective excitations in this liquid. Qualitative similarity with the scattering from liquid helium is found. Furthermore, in the range of observed wave vectors, 0.7 Å-1 ≤κ≤3.1 Å-1, extending from the firs...

About statistical process contribution to elastic diffraction scattering

International Nuclear Information System (INIS)

Ismanov, E.I.; Dzhuraev, Sh. Kh.; Paluanov, B.K.

1999-01-01

The experimental data on angular distribution show two basic properties. The first one is the presence of back and front peaks. The second one is the angular isotropic distribution near 90 degree, and has a big energy dependence. Different models for partial amplitudes a dl of the diffraction statistical scattering, particularly the model with Gaussian and exponential density distribution, were considered. The experimental data on pp-scattering were analyzed using the examined models

Deep inelastic muon scattering from nuclei at Fermilab

International Nuclear Information System (INIS)

Kaufman, S.B.

1992-01-01

Electron scattering experiments by Friedman, Kendall, and Taylor at SLAC first showed in 1968 that the proton was composed of point-like constituents (quarks). More recently the European Muon Collaboration (EMC) found in muon scattering experiments that the structure functions of a free nucleon are different from a heavy nucleus (open-quotes EMC effectclose quotes). Fermilab experiment E665 is now studying deep inelastic scattering of 490 GeV muons from targets ranging from hydrogen to lead, including measurements of the final state hadrons in order to learn more about these effects. The author describes this experiment and presents some initial results on the effects of the nuclear environment on the quark structure of nucleons

2D scattering of unpolarized beams of electrons by charged nanomagnets

Energy Technology Data Exchange (ETDEWEB)

Senbeta, Teshome, E-mail: teshearada@yahoo.com [Department of Physics, Addis Ababa University, P.O. Box 1176, Addis Ababa (Ethiopia); Mal' nev, V.N., E-mail: vnmalnev@aau.edu.et [Department of Physics, Addis Ababa University, P.O. Box 1176, Addis Ababa (Ethiopia)

2012-07-15

2D spin-dependent scattering of slow unpolarized beams of electrons by charged nanomagnets is analyzed in the Born approximation. The obtained scattering lengths are larger than those from the neutral nanomagnets approximately by one order. It is shown that for particular parameters of the system it is possible to polarize completely the scattered electrons in a narrow range of scattering angles. The most suitable system for realization of these effects is 2D Si electron gas with immersed nanomagnets. - Highlights: Black-Right-Pointing-Pointer We study 2D spin dependent electron scattering by charged nanomagnets. Black-Right-Pointing-Pointer The applicability of the Born approximation to the problem is discussed. Black-Right-Pointing-Pointer Unpolarized incident beams used to obtain completely polarized scattered electrons. Black-Right-Pointing-Pointer The study shows peculiarities of 2D spin dependent scattering enhanced by Coulomb potential. Black-Right-Pointing-Pointer The result obtained can be used as one method of controlling spin currents.

Polarimetric neutron scattering

International Nuclear Information System (INIS)

Tasset, F.

2001-01-01

Polarimetric Neutron Scattering in introduced, both by, explaining methodological issues and the corresponding instrumental developments. After a short overview of neutron spin polarization and the neutron polarization 3d-vector a pictorial approach of the microscopic theory is used to show how a polarized beam interacts with lattice and magnetic Fourier components in a crystal. Examples are given of using Spherical Neutron Polarimetry (SNP) and the corresponding Cryopad polarimeter for the investigation of non-collinear magnetic structures. (R.P.)

Light Scattering at Various Angles

Science.gov (United States)

Latimer, Paul; Pyle, B. E.

1972-01-01

The Mie theory of scattering is used to provide new information on how changes in particle volume, with no change in dry weight, should influence light scattering for various scattering angles and particle sizes. Many biological cells (e.g., algal cells, erythrocytes) and large subcellular structures (e.g., chloroplasts, mitochondria) in suspension undergo this type of reversible volume change, a change which is related to changes in the rates of cellular processes. A previous study examined the effects of such volume changes on total scattering. In this paper scattering at 10° is found to follow total scattering closely, but scattering at 45°, 90°, 135°, and 170° behaves differently. Small volume changes can cause very large observable changes in large angle scattering if the sample particles are uniform in size; however, the natural particle size heterogeneity of most samples would mask this effect. For heterogeneous samples of most particle size ranges, particle shrink-age is found to increase large angle scattering. PMID:4556610

Inelastic Light Scattering Processes

Science.gov (United States)

Fouche, Daniel G.; Chang, Richard K.

1973-01-01

Five different inelastic light scattering processes will be denoted by, ordinary Raman scattering (ORS), resonance Raman scattering (RRS), off-resonance fluorescence (ORF), resonance fluorescence (RF), and broad fluorescence (BF). A distinction between fluorescence (including ORF and RF) and Raman scattering (including ORS and RRS) will be made in terms of the number of intermediate molecular states which contribute significantly to the scattered amplitude, and not in terms of excited state lifetimes or virtual versus real processes. The theory of these processes will be reviewed, including the effects of pressure, laser wavelength, and laser spectral distribution on the scattered intensity. The application of these processes to the remote sensing of atmospheric pollutants will be discussed briefly. It will be pointed out that the poor sensitivity of the ORS technique cannot be increased by going toward resonance without also compromising the advantages it has over the RF technique. Experimental results on inelastic light scattering from I(sub 2) vapor will be presented. As a single longitudinal mode 5145 A argon-ion laser line was tuned away from an I(sub 2) absorption line, the scattering was observed to change from RF to ORF. The basis, of the distinction is the different pressure dependence of the scattered intensity. Nearly three orders of magnitude enhancement of the scattered intensity was measured in going from ORF to RF. Forty-seven overtones were observed and their relative intensities measured. The ORF cross section of I(sub 2) compared to the ORS cross section of N2 was found to be 3 x 10(exp 6), with I(sub 2) at its room temperature vapor pressure.

The hydrogen anomaly problem in neutron Compton scattering

Science.gov (United States)

Karlsson, Erik B.

2018-03-01

Neutron Compton scattering (also called ‘deep inelastic scattering of neutrons’, DINS) is a method used to study momentum distributions of light atoms in solids and liquids. It has been employed extensively since the start-up of intense pulsed neutron sources about 25 years ago. The information lies primarily in the width and shape of the Compton profile and not in the absolute intensity of the Compton peaks. It was therefore not immediately recognized that the relative intensities of Compton peaks arising from scattering on different isotopes did not always agree with values expected from standard neutron cross-section tables. The discrepancies were particularly large for scattering on protons, a phenomenon that became known as ‘the hydrogen anomaly problem’. The present paper is a review of the discovery, experimental tests to prove or disprove the existence of the hydrogen anomaly and discussions concerning its origin. It covers a twenty-year-long history of experimentation, theoretical treatments and discussions. The problem is of fundamental interest, since it involves quantum phenomena on the subfemtosecond time scale, which are not visible in conventional thermal neutron scattering but are important in Compton scattering where neutrons have two orders of magnitude times higher energy. Different H-containing systems show different cross-section deficiencies and when the scattering processes are followed on the femtosecond time scale the cross-section losses disappear on different characteristic time scales for each H-environment. The last section of this review reproduces results from published papers based on quantum interference in scattering on identical particles (proton or deuteron pairs or clusters), which have given a quantitative theoretical explanation both regarding the H-cross-section reduction and its time dependence. Some new explanations are added and the concluding chapter summarizes the conditions for observing the specific quantum

Light scattering studies of solids and atomic vapors

International Nuclear Information System (INIS)

Chiang, T.C.

1978-09-01

The general technique of light scattering and luminescence was used to study the properties of a number of material systems. First, multi-phonon resonant Raman scattering up to four phonons in GaSe and one- and two-phonon resonant Raman scattering in the mixed GaS/sub x/Se/sub 1-x/ crystals with x 2 is reported. The result is used to determine the position of the direct gap of HfS 2 . Third, the first observation of the π-polarized one-magnon luminescence sideband of the 4 T/sub lg/ ( 4 G) → 6 A/sub lg/( 6 S) excitonic transition in antiferromagnetic MnF 2 is presented. An effective temperature of the crystal is deduced from the simultaneously observed anti-Stokes sideband emission. Multi-magnon ( 2 , KMnF 2 , and RbMnF 3 using pulsed excitation and detection. A simple model based on two-ion local exchange is proposed to explain the results qualitatively. Fourth, the first observation of two-magnon resonant Raman scattering in MnF 2 around the magnon sidebands is reported. A simple theoretical description explains the experimental observations. Fifth, a detailed theory of exciton-exciton interaction in MnF 2 is developed to explain and to predict the experimental results on two-exciton absorption, high level excitation, and exciton--exciton scattering. Sixth, Brillouin scattering was used to obtain the five independent elastic constants of the layered compound GaSe. The results show clear elastic anisotropy of the crystal. Resonant Brillouin scattering near the absorption edge was also studied, but no resonant enhancement was found. Seventh, two-photon parametric scattering in sodium vapor was studied. Phase matching angles and scattering cross sections are calculated for a given set of experimental conditions

Size, flexibility, and scattering functions of semiflexible polyelectrolytes with excluded volume effects: Monte Carlo simulations and neutron scattering experiments

DEFF Research Database (Denmark)

Cannavacciuolo, L.; Sommer, C.; Pedersen, J.S.

2000-01-01

outlined in the Odijk-Skolnick-Fixman theory, in which the behavior of charged polymers is described only in terms of increasing local rigidity and excluded volume effects. Moreover, the Monte Carlo data are found to be in very good agreement with experimental scattering measurements with equilibrium......We present a systematic Monte Carlo study of the scattering function S(q) of semiflexible polyelectrolytes at infinite dilution, in solutions with different concentrations of added salt. In the spirit of a theoretical description of polyelectrolytes in terms of the equivalent parameters, namely......, persistence length and excluded volume interactions, we used a modified wormlike chain model, in which the monomers are represented by charged hard spheres placed at distance a. The electrostatic interactions are approximated by a Debye-Huckel potential. We show that the scattering function is quantitatively...

Double Bounce Component in Cross-Polarimetric SAR from a New Scattering Target Decomposition

Science.gov (United States)

Hong, Sang-Hoon; Wdowinski, Shimon

2013-08-01

Common vegetation scattering theories assume that the Synthetic Aperture Radar (SAR) cross-polarization (cross-pol) signal represents solely volume scattering. We found this assumption incorrect based on SAR phase measurements acquired over the south Florida Everglades wetlands indicating that the cross-pol radar signal often samples the water surface beneath the vegetation. Based on these new observations, we propose that the cross-pol measurement consists of both volume scattering and double bounce components. The simplest multi-bounce scattering mechanism that generates cross-pol signal occurs by rotated dihedrals. Thus, we use the rotated dihedral mechanism with probability density function to revise some of the vegetation scattering theories and develop a three- component decomposition algorithm with single bounce, double bounce from both co-pol and cross-pol, and volume scattering components. We applied the new decomposition analysis to both urban and rural environments using Radarsat-2 quad-pol datasets. The decomposition of the San Francisco's urban area shows higher double bounce scattering and reduced volume scattering compared to other common three-component decomposition. The decomposition of the rural Everglades area shows that the relations between volume and cross-pol double bounce depend on the vegetation density. The new decomposition can be useful to better understand vegetation scattering behavior over the various surfaces and the estimation of above ground biomass using SAR observations.

Scattering with polarized neutrons

International Nuclear Information System (INIS)

Schweizer, J.

2007-01-01

In the history of neutron scattering, it was shown very soon that the use of polarized neutron beams brings much more information than usual scattering with unpolarized neutrons. We shall develop here the different scattering methods that imply polarized neutrons: 1) polarized beams without polarization analysis, the flipping ratio method; 2) polarized beams with a uniaxial polarization analysis; 3) polarized beams with a spherical polarization analysis. For all these scattering methods, we shall give examples of the physical problems which can been solved by these methods, particularly in the field of magnetism: investigation of complex magnetic structures, investigation of spin or magnetization densities in metals, insulators and molecular compounds, separation of magnetic and nuclear scattering, investigation of magnetic properties of liquids and amorphous materials and even, for non magnetic material, separation between coherent and incoherent scattering. (author)

Introductory theory of neutron scattering

International Nuclear Information System (INIS)

Gunn, J.M.F.

1986-12-01

The paper comprises a set of six lecture notes which were delivered to the summer school on 'Neutron Scattering at a pulsed source', Rutherford Laboratory, United Kingdom, 1986. The lectures concern the physical principles of neutron scattering. The topics of the lectures include: diffraction, incoherent inelastic scattering, connection with the Schroedinger equation, magnetic scattering, coherent inelastic scattering, and surfaces and neutron optics. (UK)

Plasmonic nanoparticle scattering for color holograms.

Science.gov (United States)

Montelongo, Yunuen; Tenorio-Pearl, Jaime Oscar; Williams, Calum; Zhang, Shuang; Milne, William Ireland; Wilkinson, Timothy David

2014-09-02

This work presents an original approach to create holograms based on the optical scattering of plasmonic nanoparticles. By analogy to the diffraction produced by the scattering of atoms in X-ray crystallography, we show that plasmonic nanoparticles can produce a wave-front reconstruction when they are sampled on a diffractive plane. By applying this method, all of the scattering characteristics of the nanoparticles are transferred to the reconstructed field. Hence, we demonstrate that a narrow-band reconstruction can be achieved for direct white light illumination on an array of plasmonic nanoparticles. Furthermore, multicolor capabilities are shown with minimal cross-talk by multiplexing different plasmonic nanoparticles at subwavelength distances. The holograms were fabricated from a single subwavelength thin film of silver and demonstrate that the total amount of binary information stored in the plane can exceed the limits of diffraction and that this wavelength modulation can be detected optically in the far field.

X-ray small-angle scattering of polytetrahydrofuran solution, 3

International Nuclear Information System (INIS)

Izumi, Yoshinobu; Fuji, Masayuki; Shinbo, Kazuyuki; Miyake, Yasuhiro

1975-01-01

In a previous report, the conformation of polytetrahydrofuran (PTHF) in isopropyl alcohol as a theta solvent and in n-butyl alcohol as an intermediate solvent was examined by the small angle scattering of X-ray. As the result, the experimental scattering curve at theta temperature was explained well with the calculated curve obtained by superposing, while it was impossible to apply the similar method to the analysis of the scattering curve in the intermediate solvent. Recently, as the results of the calculation by Koyama on the angular distribution of light intensity scattered by stiff chain polymers and of the studies by Edwards and de Gennes on the asymptotic behavior of scattering curves in good solvents, the direct comparison of experimental and calculated scattering curves became possible. In this report, the comparison of the scattering curves of PTHF-alcohol systems is described. The systems employed were PTHF-n-propyl alcohol, PTHF-isobutyl alcohol, PTHF-sec-butyl alcohol, and PTHF-tert-butyl alcohol in addition to the previous two systems. The Guinier plots of the cross section factors of the PTHF-alcohol systems showed that the Guinier approximation on cross sections was not satisfied in cases of PTHF-isobutyl alcohol and PTHF-sec-butyl alcohol. The light scattering data at 44.6 0 C, the theta temperature of PTHF-isopropyl alcohol, are given. From the figures comparing experimental and calculated scattering curves, it was shown that there was appreciable solvent effect on the scattering curves of PTHF-alcohol systems. The relation predicted by Edwards and de Gennes was satisfied well in case of the systems in good solvents. (Kako, I.)

The Kemmer-Duffin-Petiau formalism and intermediate-energy deuteron-nucleus scattering

International Nuclear Information System (INIS)

Kozack, R.E.; Clark, B.C.; Hama, S.; Mishra, V.K.; Kaelbermann, G.; Mercer, R.L.; Ray, L.

1988-01-01

The spin-1 Kemmer-Duffin-Petiau (KDP) equations are described and applied to deuteron-nucleus scattering. Comparison with d + 58 Ni elastic scattering data at 400 MeV shows that the KDP model; reproduces experimental spin observables very well. 11 refs., 1 fig

Sound extinction by fish schools: forward scattering theory and data analysis.

Science.gov (United States)

Raveau, M; Feuillade, C

2015-02-01

A model used previously to study collective back scattering from fish schools [Feuillade et al., J. Acoust. Soc. Am. 99(1), 196-208 (1996)], is used to analyze the forward scattering properties of these objects. There is an essential physical difference between back and forward scattering from fish schools. Strong frequency dependent interference effects, which affect the back scattered field amplitude, are absent in the forward scattering case. This is critically important for data analysis. There is interest in using back scattering and transmission data from fish schools to study their size, the species and abundance of fish, and fish behavior. Transmission data can be processed to determine the extinction of the field by a school. The extinction of sound depends on the forward scattering characteristics of the school, and data inversion to provide information about the fish should be based upon a forward scattering paradigm. Results are presented of an analysis of transmission data obtained in September 1995 during an experiment performed in the Gulf of Lion in the Mediterranean Sea [Diachok, J. Acoust. Soc. Am. 105(4), 2107-2128 (1999)]. The analysis shows that using forward scattering leads to significantly larger estimates of fish abundance than previous analysis based upon back scattering approaches.

Multiple scattering of electromagnetic waves in disordered magnetic media localization parameter, energy transport velocity and diffusion constant

CERN Document Server

Pinheiro, F A; Martínez, A S

2001-01-01

We review some of our recent results concerning the single and multiple electromagnetic scattering by magnetic spherical particles. For a single electromagnetic scattering we show that the magnetic contribution alters, when compared to nonmagnetic scattering, the behavior of the cross sections and mean cosine of the scattering angle (cos omega). For ferromagnetic particles, resonances may occur even in the small-particle limit when the particle radius is much smaller than the wavelength. The resonances increase the cross sections while (cos omega) is diminished , and even may become negative. Several quantities such the Ioffe-Regel parameter for localization are calculated for the multiple scattering regime. We show that magnetic scattering favors the observation of localization of electromagnetic waves in three dimensions. Further, this is also verified for dynamical experiments, where we show that the diffusion constant can be very small. Since the magnetic permeability of the scatterers can vary significan...

Electron scattering from tetrahydrofuran

International Nuclear Information System (INIS)

Fuss, M C; Sanz, A G; García, G; Muñoz, A; Oller, J C; Blanco, F; Do, T P T; Brunger, M J; Almeida, D; Limão-Vieira, P

2012-01-01

Electron scattering from Tetrahydrofuran (C 4 H 8 O) was investigated over a wide range of energies. Following a mixed experimental and theoretical approach, total scattering, elastic scattering and ionization cross sections as well as electron energy loss distributions were obtained.

Distorted-wave Born approximation in the case of an optical scattering potential

International Nuclear Information System (INIS)

Mytnichenko, Sergey V.

2005-01-01

Application of the distorted-wave Born approximation in the conventional form developed for the case of a real scattering potential is shown to cause significant errors in calculating X-ray diffuse scattering from non-ideal crystals, superlattices, multilayers and other objects if energy dissipation (photoabsorption, inelastic scattering, and so on) is not negligible, or in other words, in the case of an optical (complex) scattering potential. We show how a correct expression for the X-ray diffuse-scattering cross-section can be obtained in this case. Generally, the diffuse-scattering cross-section from an optical potential is not T-invariant, i.e. the reciprocity principle is violated. Violations of T-invariance are more evident when the dynamical nature of the diffraction is more critical

Polarization transfer in inelastic scattering

International Nuclear Information System (INIS)

Moss, J.M.

1980-01-01

Polarization transfer experiments are now feasible for inelastic scattering experiments on complex nuclei. Experiments thus far have dealt with the spin-flip probability; this observable is sensitive to the action of spin-spin and tensor forces in inelastic scattering. Spin-flip probabilities at E approx. 40 MeV in isoscalar transitions in 12 C(12.71 MeV) and 15 O(8.89 MeV) show considerable deviation from DWBA-shell model predictions; this deviation indicates evidence for more complex reaction mechanisms. Experiments at intermediate energies will soon be possible and will yield data of much higher precision than is possible at lower (E < 100 MeV) energies. These experiments hold exciting promise in such areas as nuclear critical opalescence. 7 figures, 1 table

Physicochemical analyses of plant biostimulant formulations and characterisation of commercial products by instrumental techniques

OpenAIRE

Sharma, H. S. S.; Selby, C.; Carmichael, E.; McRoberts, C.; Rao, J. R.; Ambrosino, P.; Chiurazzi, M.; Pucci, M.; Martin, T.

2016-01-01

Background: The objective of this study was to develop instrumental protocols for evaluating physicochemical characteristics of plant biostimulant/biofertiliser formulations. Six formulations (Rygex, Algavyt, Ryzoset, Manek, Ecoryg and Algavyt Zn/Mn) containing algal/plant extracts, humic and amino acids, lipids and inorganic components were assessed for particle size distribution and zeta potential (ZP) by dynamic light scattering (DLS) and gross compositional differences by thermogravimetri...

Neutron scattering analysis of rubber carbon black composite structure

International Nuclear Information System (INIS)

Hjelm, R.P. Jr.; Wampler, W.A.; Gerspacher, M.

1994-01-01

We explore the uses of small-angle neutron scattering to dissect component form, structure and distribution in carbon black-reinforced rubber by varying the contrast of the system relative to some fluid by changing the fluid scattering-length density. This is the method of contrast variation. Contrast variation allows us to separate scattering contributions from the different components. Here, we extend our studies on high surface area (HSA) carbon black suspended in cyclohexane/deuterocyclohexane to HSA mixed with polyisoprene as a gel of ''bound'' rubber swollen with the same solvent mixtures. Contrast variation of swollen composite gels shows that there are two length scales in the gel structure. Above 1 nm fluctuations in the carbon black predominate. Interactions with elastomer hold the HSA aggregates appart. Below 1 nm the scattering is largely from the elastomer. The smooth surface structure of the carbon black is unaltered by the interactions with elastomer and appears smooth over length scales above about 1 nm. These results show that contrast variation can provide information on composite structure that is not available by other means. This information relates to the reinforcement mechanism of elastomers by carbon blacks

Study on the Light Scattering from Random Rough Surfaces by Kirrhoff Approximation

Directory of Open Access Journals (Sweden)

Keding Yan

2014-07-01

Full Text Available In order to study the space distribution characteristics of light scattering from random rough surfaces, the linear filtering method is used to generate a series of Gaussian randomly rough surfaces, and the Kirchhoff Approximation is used to calculate the scattered light intensity distribution from random metal and dielectric rough surfaces. The three characteristics of the scattered light intensity distribution peak, the intensity distribution width and the position of peak are reviewed. Numerical calculation results show that significant differences between scattering characteristics of metal surfaces and the dielectric surfaces exist. The light scattering characteristics are jointly influenced by the slope distribution and reflectance of surface element. The scattered light intensity distribution is affected by common influence of surface local slope distribution and surface local reflectivity. The results can provide a basis theory for the research to lidar target surface scattering characteristics.

Subsurface Scattering-Based Object Rendering Techniques for Real-Time Smartphone Games

Directory of Open Access Journals (Sweden)

Won-Sun Lee

2014-01-01

Full Text Available Subsurface scattering that simulates the path of a light through the material in a scene is one of the advanced rendering techniques in the field of computer graphics society. Since it takes a number of long operations, it cannot be easily implemented in real-time smartphone games. In this paper, we propose a subsurface scattering-based object rendering technique that is optimized for smartphone games. We employ our subsurface scattering method that is utilized for a real-time smartphone game. And an example game is designed to validate how the proposed method can be operated seamlessly in real time. Finally, we show the comparison results between bidirectional reflectance distribution function, bidirectional scattering distribution function, and our proposed subsurface scattering method on a smartphone game.

Coherent transmission of an ultrasonic shock wave through a multiple scattering medium.

Science.gov (United States)

Viard, Nicolas; Giammarinaro, Bruno; Derode, Arnaud; Barrière, Christophe

2013-08-01

We report measurements of the transmitted coherent (ensemble-averaged) wave resulting from the interaction of an ultrasonic shock wave with a two-dimensional random medium. Despite multiple scattering, the coherent waveform clearly shows the steepening that is typical of nonlinear harmonic generation. This is taken advantage of to measure the elastic mean free path and group velocity over a broad frequency range (2-15 MHz) in only one experiment. Experimental results are found to be in good agreement with a linear theoretical model taking into account spatial correlations between scatterers. These results show that nonlinearity and multiple scattering are both present, yet uncoupled.

Mitigating the effect of optical back-scatter in multispectral underwater imaging

International Nuclear Information System (INIS)

Mortazavi, Halleh; Oakley, John P; Barkat, Braham

2013-01-01

Multispectral imaging is a very useful technique for extracting information from the underwater world. However, optical back-scatter changes the intensity value in each spectral band and this distorts the estimated spectrum. In this work, a filter is used to detect the level of optical back-scatter in each spectral band from a set of multispectral images. Extraction of underwater object spectra can be done by subtracting the estimated level of optical back-scatter and scaling the remainder in each spectral band from the captured image in the corresponding band. An experiment has been designed to show the performance of the proposed filter for correcting the set of multispectral underwater images and recovering the pixel spectra. The multispectral images are captured by a B/W CCD digital camera with a fast tunable liquid-crystal filter in 33 narrow spectral bands in clear and different levels of turbid water. Reference estimates for the optical back-scatter spectra are found by comparing a clear and a degraded set of multispectral images. The accuracy and consistency of the proposed method, the extended Oakley–Bu cost function, is examined by comparing the estimated values with the reference level of an optical back-scatter spectrum. The same comparison is made for the simple estimation approach. The results show that the simple method is not reliable and fail to estimate the level of optical back-scatter spectrum accurately. The results from processing experimental images in turbid water show that the effect of optical back-scatter can be mitigated in the image of each spectral band and, as a result, the spectra of the object can be recovered. However, for a very high level of turbid water the recovery is limited because of the effect of extinction. (paper)

Modifications of nucleons in nuclei in quasi-elastic electron-nucleus scattering

International Nuclear Information System (INIS)

Mulders, P.J.

1988-01-01

In inelastic electron scattering two scaling regions are observed in which the scattering is dominated by quasi-elastic scattering. For large momentum transfers, √Q 2 > 2 GeV/c, the scattering process is dominated by quasi-elastic scattering off quarks, whereas for √Q 2 ≅ 0.5 GeV/c the dominant contribution is quasi-elastic scattering off nucleons. This corresponds nicely to our first order picture of the nucleus consisting of nucleons, which in turn are composed of quarks. In the nucleon-scaling region, possible modifications of nucleon properties show up through a study of the Q 2 dependence and the relative strength of the transverse and longitudinal cross sections. Results of both inclusive (e,e') and exclusive (e,e'p) experiments in the quasi-elastic scattering region indeed show a behavior that could indicate modifications of intrinsic properties of individual nucleons in the nucleus, although the question remains if one has correctly disentangled the effects of the (long range) interactions between nucleons and those connected to the internal structure of nucleons. Even so, a simple (one-parameter) size rescaling for nucleons appears to be inconsistent with the data and also with some known conventional nuclear physics observables. Therefore the inclusion of two-nucleon correlations appears necessary in order to be able to understand the data. Such correlations can for instance be due to the effect of the Pauli principle on the quark level. (orig.)

MAGNETIC NEUTRON SCATTERING

Energy Technology Data Exchange (ETDEWEB)

ZALIZNYAK,I.A.; LEE,S.H.

2004-07-30

Much of our understanding of the atomic-scale magnetic structure and the dynamical properties of solids and liquids was gained from neutron-scattering studies. Elastic and inelastic neutron spectroscopy provided physicists with an unprecedented, detailed access to spin structures, magnetic-excitation spectra, soft-modes and critical dynamics at magnetic-phase transitions, which is unrivaled by other experimental techniques. Because the neutron has no electric charge, it is an ideal weakly interacting and highly penetrating probe of matter's inner structure and dynamics. Unlike techniques using photon electric fields or charged particles (e.g., electrons, muons) that significantly modify the local electronic environment, neutron spectroscopy allows determination of a material's intrinsic, unperturbed physical properties. The method is not sensitive to extraneous charges, electric fields, and the imperfection of surface layers. Because the neutron is a highly penetrating and non-destructive probe, neutron spectroscopy can probe the microscopic properties of bulk materials (not just their surface layers) and study samples embedded in complex environments, such as cryostats, magnets, and pressure cells, which are essential for understanding the physical origins of magnetic phenomena. Neutron scattering is arguably the most powerful and versatile experimental tool for studying the microscopic properties of the magnetic materials. The magnitude of the cross-section of the neutron magnetic scattering is similar to the cross-section of nuclear scattering by short-range nuclear forces, and is large enough to provide measurable scattering by the ordered magnetic structures and electron spin fluctuations. In the half-a-century or so that has passed since neutron beams with sufficient intensity for scattering applications became available with the advent of the nuclear reactors, they have became indispensable tools for studying a variety of important areas of modern

Inelastic neutron scattering from glass formers

International Nuclear Information System (INIS)

Buchenau, U.

1997-01-01

Neutron spectra below and above the glass transition temperature show a pronounced difference between strong and fragile glass formers in Angell's fragility scheme. The strong anharmonic increase of the inelastic scattering with increasing temperature in fragile substances is absent in the strongest glass former SiO 2 . That difference is reflected in the temperature dependence of Brillouin sound velocities above the glass transition. Coherent inelastic neutron scattering data indicate a mixture of sound waves and local modes at the low frequency boson peak. A relation between the fragility and the temperature dependence of the transverse hypersound velocity at the glass temperature is derived. (author)

Light scattering in additively colored alkali-halide crystals

International Nuclear Information System (INIS)

Trakhbrot, B.M.

1979-01-01

Studied is extinction in ultra-violet, visible and infrared spectrum ranges, caused by light scattering in additively colored KCl and KBr crystals. The crystals were prepared of the powder. The specimens were annealed in saturated potassium vapours: KBr - at 600-630 deg C, KCl - at 700 deg C. While investigating the spectra it is observed that the optical density of the specimens processed in such a regime is more than 2 in the ultraviolet and visible spectrum ranges at the 0.1-0.05 cm thickness of the specimens. In the infrared spectra the growth of the extinction coefficient with the wave length decrease is observed. The spectrum character shows IR radiation scattering by the defects in the crystal lattice. The attempt of determination of the scattering centres nature is taken. It is shown that the possible centres causing the light scattering observed can be colloid and quasicolloid centres in the additively colored materials

LIGHT SCATTERING BY FRACTAL DUST AGGREGATES. I. ANGULAR DEPENDENCE OF SCATTERING

Energy Technology Data Exchange (ETDEWEB)

Tazaki, Ryo [Department of Astronomy, Graduate School of Science, Kyoto University, Kitashirakawa-Oiwake-cho, Sakyo-ku, Kyoto 606-8502 (Japan); Tanaka, Hidekazu [Astronomical Institute, Tohoku University, 6-3 Aramaki, Aoba-ku, Sendai 980-8578 (Japan); Okuzumi, Satoshi; Nomura, Hideko [Department of Earth and Planetary Sciences, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro-ku, Tokyo 152-8551 (Japan); Kataoka, Akimasa, E-mail: rtazaki@kusastro.kyoto-u.ac.jp [Institute for Theoretical Astrophysics, Heidelberg University, Albert-Ueberle-Strasse 2, D-69120 Heidelberg (Germany)

2016-06-01

In protoplanetary disks, micron-sized dust grains coagulate to form highly porous dust aggregates. Because the optical properties of these aggregates are not completely understood, it is important to investigate how porous dust aggregates scatter light. In this study, the light scattering properties of porous dust aggregates were calculated using a rigorous method, the T -matrix method, and the results were then compared with those obtained using the Rayleigh–Gans–Debye (RGD) theory and Mie theory with the effective medium approximation (EMT). The RGD theory is applicable to moderately large aggregates made of nearly transparent monomers. This study considered two types of porous dust aggregates—ballistic cluster–cluster agglomerates (BCCAs) and ballistic particle–cluster agglomerates. First, the angular dependence of the scattered intensity was shown to reflect the hierarchical structure of dust aggregates; the large-scale structure of the aggregates is responsible for the intensity at small scattering angles, and their small-scale structure determines the intensity at large scattering angles. Second, it was determined that the EMT underestimates the backward scattering intensity by multiple orders of magnitude, especially in BCCAs, because the EMT averages the structure within the size of the aggregates. It was concluded that the RGD theory is a very useful method for calculating the optical properties of BCCAs.

Diffuse scattering of neutrons

International Nuclear Information System (INIS)

Novion, C.H. de.

1981-02-01

The use of neutron scattering to study atomic disorder in metals and alloys is described. The diffuse elastic scattering of neutrons by a perfect crystal lattice leads to a diffraction spectrum with only Bragg spreads. the existence of disorder in the crystal results in intensity and position modifications to these spreads, and above all, to the appearance of a low intensity scatter between Bragg peaks. The elastic scattering of neutrons is treated in this text, i.e. by measuring the number of scattered neutrons having the same energy as the incident neutrons. Such measurements yield information on the static disorder in the crystal and time average fluctuations in composition and atomic displacements [fr

Gravitational Bhabha scattering

International Nuclear Information System (INIS)

Santos, A F; Khanna, Faqir C

2017-01-01

Gravitoelectromagnetism (GEM) as a theory for gravity has been developed similar to the electromagnetic field theory. A weak field approximation of Einstein theory of relativity is similar to GEM. This theory has been quantized. Traditional Bhabha scattering, electron–positron scattering, is based on quantized electrodynamics theory. Usually the amplitude is written in terms of one photon exchange process. With the development of quantized GEM theory, the scattering amplitude will have an additional component based on an exchange of one graviton at the lowest order of perturbation theory. An analysis will provide the relative importance of the two amplitudes for Bhabha scattering. This will allow an analysis of the relative importance of the two amplitudes as the energy of the exchanged particles increases. (paper)

Speckle-learning-based object recognition through scattering media.

Science.gov (United States)

Ando, Takamasa; Horisaki, Ryoichi; Tanida, Jun

2015-12-28

We experimentally demonstrated object recognition through scattering media based on direct machine learning of a number of speckle intensity images. In the experiments, speckle intensity images of amplitude or phase objects on a spatial light modulator between scattering plates were captured by a camera. We used the support vector machine for binary classification of the captured speckle intensity images of face and non-face data. The experimental results showed that speckles are sufficient for machine learning.

Scattering Amplitudes and Worldsheet Models of QFTs

CERN Multimedia

CERN. Geneva

2016-01-01

I will describe recent progress on the study of scattering amplitudes via ambitwistor strings and the scattering equations. Ambitwistor strings are worldsheet models of quantum field theories, inspired by string theory. They naturally lead to a representation of amplitudes based on the scattering equations. While worldsheet models and related ideas have had a wide-ranging impact on the modern study of amplitudes, their direct application at loop level is a very recent success. I will show how a major difficulty in the loop-level story, the technicalities of higher-genus Riemann surfaces, can be avoided by turning the higher-genus surface into a nodal Riemann sphere, with the nodes representing the loop momenta. I will present new formulas for the one-loop integrands of gauge theory and gravity, with or without supersymmetry, and also some two-loop results.

Incoherent imaging using dynamically scattered coherent electrons

International Nuclear Information System (INIS)

Nellist, P.D.; Pennycook, S.J.

1999-01-01

We use a Bloch wave approach to show that, even for coherent dynamical scattering from a stationary lattice with no absorption, annular dark-field imaging in a scanning transmission electron microscope gives a direct incoherent structure image of the atomic-column positions of a zone-axis-aligned crystal. Although many Bloch waves may be excited by the probe, the detector provides a filtering effect so that the 1s-type bound states are found to dominate the image contrast for typical experimental conditions. We also find that the column intensity is related to the transverse kinetic energy of the 1s states, which gives atomic number, Z, contrast. The additional effects of phonon scattering are discussed, in particular the reasons why phonon scattering is not a prerequisite for transverse incoherence. (Copyright (c) 1999 Elsevier Science B.V., Amsterdam. All rights reserved.)

Diffuse neutron scattering study of Cu2−xSe

DEFF Research Database (Denmark)

Cava, R. J.; Andersen, Niels Hessel; Clausen, Kurt Nørgaard

1986-01-01

We have measured the diffuse neutron scattering in the hkk plane for Cu2Se and Cu1.8Se at 180°C and 51°C, respectively, in the cubic antifluorite type phase. The diffuse scattering shows significant structure, indicative of correlated short range mobile ion ordering. The short range order is foun...

Extracting the σ-term from low-energy pion-nucleon scattering

Science.gov (United States)

Ruiz de Elvira, Jacobo; Hoferichter, Martin; Kubis, Bastian; Meißner, Ulf-G.

2018-02-01

We present an extraction of the pion-nucleon (π N) scattering lengths from low-energy π N scattering, by fitting a representation based on Roy-Steiner equations to the low-energy data base. We show that the resulting values confirm the scattering-length determination from pionic atoms, and discuss the stability of the fit results regarding electromagnetic corrections and experimental normalization uncertainties in detail. Our results provide further evidence for a large π N σ-term, {σ }π N=58(5) {{MeV}}, in agreement with, albeit less precise than, the determination from pionic atoms.

Small scatterers in the lower mantle observed at German broadband arrays

Science.gov (United States)

Thomas, C.; Weber, M.; Wicks, C.W.; Scherbaum, F.

1999-01-01

Seismograms of earthquakes from the South Pacific recorded at a German broadband array and network show precursors to PKPdf. These precursors mainly originate from off-path scattering of PKPab or a nearby PKPbc to P (for receiver-side scattering) or from scattering of P to PKPab or PKPbc on the PKPdf path (for source-side scattering). Standard array processing techniques based on plane wave approximations (such as vespagram or frequency-wavenumber analysis) are inadequate for investigating these precursors since scattered waves cannot be approximated as plane waves for arrays and networks larger than 300 x 300 km for short-period waves. We therefore develop a migration method to estimate the location of scatterers in the mantle, at the core-mantle boundary and at the top of the outer core. With our method we are able to find isolated scatterers at the source side and the receiver side, although the depth of the scatterer is not well constrained. However, from looking at the first possible arrival time of precursors at different depth and the region where scattering can take place (scattering volume), we believe that the location of the scatterers is in the lowermost mantle. Since we have detected scatterers in regions where ultralow-velocity zones have been discovered recently, we think that the precursor energy possibly originates from scattering at partial melt at the base of the mantle. Comparing results from broadband and band-pass-filtered data the detection of small-scale structure of the ultralow-velocity zones becomes possible. Copyright 1999 by the American Geophysical Union.

REVISITING THE SCATTERING GREENHOUSE EFFECT OF CO2 ICE CLOUDS

International Nuclear Information System (INIS)

Kitzmann, D.

2016-01-01

Carbon dioxide ice clouds are thought to play an important role for cold terrestrial planets with thick CO 2 dominated atmospheres. Various previous studies showed that a scattering greenhouse effect by carbon dioxide ice clouds could result in a massive warming of the planetary surface. However, all of these studies only employed simplified two-stream radiative transfer schemes to describe the anisotropic scattering. Using accurate radiative transfer models with a general discrete ordinate method, this study revisits this important effect and shows that the positive climatic impact of carbon dioxide clouds was strongly overestimated in the past. The revised scattering greenhouse effect can have important implications for the early Mars, but also for planets like the early Earth or the position of the outer boundary of the habitable zone

Oil classification using X-ray scattering and principal component analysis

Energy Technology Data Exchange (ETDEWEB)

Almeida, Danielle S.; Souza, Amanda S.; Lopes, Ricardo T., E-mail: dani.almeida84@gmail.com, E-mail: ricardo@lin.ufrj.br, E-mail: amandass@bioqmed.ufrj.br [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil); Oliveira, Davi F.; Anjos, Marcelino J., E-mail: davi.oliveira@uerj.br, E-mail: marcelin@uerj.br [Universidade do Estado do Rio de Janeiro (UERJ), Rio de Janeiro, RJ (Brazil). Inst. de Fisica Armando Dias Tavares

2015-07-01

X-ray scattering techniques have been considered promising for the classification and characterization of many types of samples. This study employed this technique combined with chemical analysis and multivariate analysis to characterize 54 vegetable oil samples (being 25 olive oils)with different properties obtained in commercial establishments in Rio de Janeiro city. The samples were chemically analyzed using the following indexes: iodine, acidity, saponification and peroxide. In order to obtain the X-ray scattering spectrum, an X-ray tube with a silver anode operating at 40kV and 50 μA was used. The results showed that oils cab ne divided in tow large groups: olive oils and non-olive oils. Additionally, in a multivariate analysis (Principal Component Analysis - PCA), two components were obtained and accounted for more than 80% of the variance. One component was associated with chemical parameters and the other with scattering profiles of each sample. Results showed that use of X-ray scattering spectra combined with chemical analysis and PCA can be a fast, cheap and efficient method for vegetable oil characterization. (author)

Oil classification using X-ray scattering and principal component analysis

International Nuclear Information System (INIS)

Almeida, Danielle S.; Souza, Amanda S.; Lopes, Ricardo T.; Oliveira, Davi F.; Anjos, Marcelino J.

2015-01-01

X-ray scattering techniques have been considered promising for the classification and characterization of many types of samples. This study employed this technique combined with chemical analysis and multivariate analysis to characterize 54 vegetable oil samples (being 25 olive oils)with different properties obtained in commercial establishments in Rio de Janeiro city. The samples were chemically analyzed using the following indexes: iodine, acidity, saponification and peroxide. In order to obtain the X-ray scattering spectrum, an X-ray tube with a silver anode operating at 40kV and 50 μA was used. The results showed that oils cab ne divided in tow large groups: olive oils and non-olive oils. Additionally, in a multivariate analysis (Principal Component Analysis - PCA), two components were obtained and accounted for more than 80% of the variance. One component was associated with chemical parameters and the other with scattering profiles of each sample. Results showed that use of X-ray scattering spectra combined with chemical analysis and PCA can be a fast, cheap and efficient method for vegetable oil characterization. (author)

Simulated x-ray scattering of protein solutions using explicit-solvent models

International Nuclear Information System (INIS)

Park, Sanghyun; Bardhan, Jaydeep P.; Makowski, Lee; Roux, Benoit

2009-01-01

X-ray solution scattering shows new promise for the study of protein structures, complementing crystallography and nuclear magnetic resonance. In order to realize the full potential of solution scattering, it is necessary to not only improve experimental techniques but also develop accurate and efficient computational schemes to relate atomistic models to measurements. Previous computational methods, based on continuum models of water, have been unable to calculate scattering patterns accurately, especially in the wide-angle regime which contains most of the information on the secondary, tertiary, and quaternary structures. Here we present a novel formulation based on the atomistic description of water, in which scattering patterns are calculated from atomic coordinates of protein and water. Without any empirical adjustments, this method produces scattering patterns of unprecedented accuracy in the length scale between 5 and 100 A, as we demonstrate by comparing simulated and observed scattering patterns for myoglobin and lysozyme.

The inside–outside duality for inverse scattering problems with near field data

International Nuclear Information System (INIS)

Lechleiter, Armin; Peters, Stefan

2015-01-01

We derive an inside–outside duality for near field scattering data generated by time-harmonic scattering of acoustic point sources from a sound-soft scatterer. This duality in particular rigorously characterizes interior Dirichlet eigenvalues of the scattering object by near field operators for an interval of wave numbers. As a crucial new concept to prove this duality we exploit the numerical ranges of certain modifications of these near field operators. We also show that our theoretical results can be numerically used to approximate interior Dirichlet eigenvalues from multi-frequency near field measurements. (paper)

Precision calculation of threshold πd scattering, πN scattering lengths, and the GMO sum rule

Science.gov (United States)

Baru, V.; Hanhart, C.; Hoferichter, M.; Kubis, B.; Nogga, A.; Phillips, D. R.

2011-12-01

We use chiral perturbation theory (ChPT) to calculate the πd scattering length with an accuracy of a few percent, including isospin-violating corrections in both the two- and three-body sectors. In particular, we provide the technical details of a recent letter (Baru et al., 2011) [1], where we used data on pionic deuterium and pionic hydrogen atoms to extract the isoscalar and isovector pion-nucleon scattering lengths a and a. We study isospin-breaking contributions to the three-body part of a due to mass differences, isospin violation in the πN scattering lengths, and virtual photons. This last class of effects is ostensibly infrared enhanced due to the smallness of the deuteron binding energy. However, we show that the leading virtual-photon effects that might undergo such enhancement cancel, and hence the standard ChPT counting provides a reliable estimate of isospin violation in a due to virtual photons. Finally, we discuss the validity of the Goldberger-Miyazawa-Oehme sum rule in the presence of isospin violation, and use it to determine the charged-pion-nucleon coupling constant.

Vector Monte Carlo simulations on atmospheric scattering of polarization qubits.

Science.gov (United States)

Li, Ming; Lu, Pengfei; Yu, Zhongyuan; Yan, Lei; Chen, Zhihui; Yang, Chuanghua; Luo, Xiao

2013-03-01

In this paper, a vector Monte Carlo (MC) method is proposed to study the influence of atmospheric scattering on polarization qubits for satellite-based quantum communication. The vector MC method utilizes a transmittance method to solve the photon free path for an inhomogeneous atmosphere and random number sampling to determine whether the type of scattering is aerosol scattering or molecule scattering. Simulations are performed for downlink and uplink. The degrees and the rotations of polarization are qualitatively and quantitatively obtained, which agree well with the measured results in the previous experiments. The results show that polarization qubits are well preserved in the downlink and uplink, while the number of received single photons is less than half of the total transmitted single photons for both links. Moreover, our vector MC method can be applied for the scattering of polarized light in other inhomogeneous random media.

Evaluation of the scatter-to-primary ratio in mammography and performance of anti-scatter grids by Monte Carlo simulations

International Nuclear Information System (INIS)

Cunha, Diego M.; Tomal, Alessandra; Poletti, Martin E.

2009-01-01

In this work, a computational code was developed for the study of image quality in screen-film mammography through Monte Carlo (MC) simulations. The code includes implementation of interference and energy broadening effects, for the elastic and inelastic scattered photons, respectively. The contribution of scattered photons to the mammographic image was evaluated through the ratio between the energy deposited in the image receptor by scattered and primary photons (S/P ratio). The spatial distribution of the S1P ratio on the receptor was obtained for breasts of different thickness, between 2 and 8cm, considering a 50% adipose-SO% glandular breast. Different tube voltages were evaluated, for a Mo/Mo anode-filter combination. The S/P ratio was a/so obtained considering two different grids: a linear grid (grid ratio of 5:1) and a cellular grid (grid ratio of 3.8:1). Grid performance was computed through the contrast improvement factor (CIF) and Bucky factor (BF). Results showed that the S/P ratio increases linearly with breast thickness, and, for a given thickness, it showed considerably spatial variations on the image receptor. On the other hand, little dependence of the S/P ratio on the tube voltage was observed. Grid comparison showed that the cellular grid has better performance than the linear one, since it provides a greater CIF, with smaller values of BF. (author)

Dressing effects on the occurrence scattering time retardation and advance in a dusty plasma

Science.gov (United States)

Lee, Myoung-Jae; Jung, Young-Dae; Hanyang Plasma Team

2017-10-01

The dressing effects on the occurrence scattering time for the dust-dust interaction are investigated in a complex plasma. The first-order eikonal analysis is applied to obtain the scattering amplitude and the occurrence scattering time for the dust-dust interaction. The result shows that dressing effect enhances the retardation phenomena of the occurrence scattering time in the forward scattering domain. It is shown that the oscillatory behavior of the scaled occurrence scattering time is getting more significant with an increase of the Debye length. It is also found that the retardation domain of the occurrence scattering time increases with a decrease of the Debye length. The variation of the occurrence scattering time retardation and advance due to the dressing effect is also discussed.

Reaction Mechanism and Structure Interplay for Proton Elastic Scattering from Halo Nuclei

International Nuclear Information System (INIS)

Crespo, R.; Johnson, R.C.

1999-01-01

The aim of this work is to clarify what properties of the projectile w.f. are relevant to describe elastic scattering of halo nuclei from stable nuclei. In particular, we examine how far elastic scattering observables probe correlation effects among projectile nucleons. Our treatment is based on a multiple scattering expansion of the proton-projectile transition amplitude in a form which is well adapted to the weakly bound cluster picture of halo nuclei. In the specific case of 11 Li scattering from protons at 800 MeV/u we show that because core recoil effects are significant, scattering cross sections can not, in general, be deduced from knowledge of the total matter density alone. We advocate that the optical potential concept for the scattering of halo nuclei on protons should be avoided and that the multiple scattering series for the full transition amplitude should be used instead

Reaction mechanism and structure interplay for proton elastic scattering from halo nuclei

International Nuclear Information System (INIS)

Crespo, R.; Johnson, R. C.

1999-01-01

The aim of this work is to clarify what properties of the projectile w.f. are relevant to describe elastic scattering of halo nuclei from stable nuclei. In particular, we examine how far elastic scattering observables probe correlation effects among projectile nucleons. Our treatment is based on a multiple scattering expansion of the proton-projectile transition amplitude in a form which is well adapted to the weakly bound cluster picture of halo nuclei. In the specific case of 11 Li scattering from protons at 800 MeV/u we show that because core recoil effects are significant, scattering crosssections cannot, in general, be deduced from knowledge of the total matter density alone. We advocate that the optical potential concept for the scattering of halo nuclei on protons should be avoided and that the multiple scattering series for the full transition amplitude should be used instead

Colloidal properties of sodium caseinate-stabilized nanoemulsions prepared by a combination of a high-energy homogenization and evaporative ripening methods.

Science.gov (United States)

Montes de Oca-Ávalos, J M; Candal, R J; Herrera, M L

2017-10-01

Nanoemulsions stabilized by sodium caseinate (NaCas) were prepared using a combination of a high-energy homogenization and evaporative ripening methods. The effects of protein concentration and sucrose addition on physical properties were analyzed by dynamic light scattering (DLS), Turbiscan analysis, confocal laser scanning microscopy (CLSM) and small angle X-ray scattering (SAXS). Droplets sizes were smaller (~100nm in diameter) than the ones obtained by other methods (200 to 2000nm in diameter). The stability behavior was also different. These emulsions were not destabilized by creaming. As droplets were so small, gravitational forces were negligible. On the contrary, when they showed destabilization the main mechanism was flocculation. Stability of nanoemulsions increased with increasing protein concentrations. Nanoemulsions with 3 or 4wt% NaCas were slightly turbid systems that remained stable for at least two months. According to SAXS and Turbiscan results, aggregates remained in the nano range showing small tendency to aggregation. In those systems, interactive forces were weak due to the small diameter of flocs. Copyright © 2017 Elsevier Ltd. All rights reserved.

Direct sampling methods for inverse elastic scattering problems

Science.gov (United States)

Ji, Xia; Liu, Xiaodong; Xi, Yingxia

2018-03-01

We consider the inverse elastic scattering of incident plane compressional and shear waves from the knowledge of the far field patterns. Specifically, three direct sampling methods for location and shape reconstruction are proposed using the different component of the far field patterns. Only inner products are involved in the computation, thus the novel sampling methods are very simple and fast to be implemented. With the help of the factorization of the far field operator, we give a lower bound of the proposed indicator functionals for sampling points inside the scatterers. While for the sampling points outside the scatterers, we show that the indicator functionals decay like the Bessel functions as the sampling point goes away from the boundary of the scatterers. We also show that the proposed indicator functionals continuously dependent on the far field patterns, which further implies that the novel sampling methods are extremely stable with respect to data error. For the case when the observation directions are restricted into the limited aperture, we firstly introduce some data retrieval techniques to obtain those data that can not be measured directly and then use the proposed direct sampling methods for location and shape reconstructions. Finally, some numerical simulations in two dimensions are conducted with noisy data, and the results further verify the effectiveness and robustness of the proposed sampling methods, even for multiple multiscale cases and limited-aperture problems.

Probing the phase of the elastic pp scattering amplitude with vortex proton beams

International Nuclear Information System (INIS)

Ivanov, I. P.

2013-01-01

We show that colliding vortex proton beams instead of (approximate) plane waves can lead to a direct measurement of how the overall phase of the scattering amplitude changes with the scattering angle. In elastic pp scattering, this will open a novel way to measure the parameter ρ(t) and probe the real part of the Pomeron.

Probing the phase of the elastic pp scattering amplitude with vortex proton beams

Energy Technology Data Exchange (ETDEWEB)

Ivanov, I. P. [IFPA, Universite de Liege, Allee du 6 Aout 17, batiment B5a, 4000 Liege, Belgium Sobolev Institute of Mathematics, Koptyug avenue 4, 630090, Novosibirsk (Russian Federation)

2013-04-15

We show that colliding vortex proton beams instead of (approximate) plane waves can lead to a direct measurement of how the overall phase of the scattering amplitude changes with the scattering angle. In elastic pp scattering, this will open a novel way to measure the parameter {rho}(t) and probe the real part of the Pomeron.

Indirect transformation in reciprocal space: desmearing of small-angle scattering data from partially ordered systems

International Nuclear Information System (INIS)

Glatter, O.; Gruber, K.

1993-01-01

Indirect Fourier transformation is a widely used technique for the desmearing of instrumental broadening effects, for data smoothing and for Fourier transformation of small-angle scattering data. This technique, however, can only be applied to scattering curves with a band-limited Fourier transform, i.e. separated and noninteracting scattering centers. It can therefore not be used for scattering data from partially ordered systems. In this paper, a modified technique for partially ordered systems working in reciprocal space is presented. A peak-recognition technique allows its application to scattering functions with narrow peaks, such as the scattering functions of layered systems like lamellar stacks or strongly interacting particles. Arbitrary geometry effects and wavelength effects can be corrected. Examples of simulations show the merits and limits of this new method. One example shows its applicability to real data. (orig.)

Some results on inverse scattering

International Nuclear Information System (INIS)

Ramm, A.G.

2008-01-01

A review of some of the author's results in the area of inverse scattering is given. The following topics are discussed: (1) Property C and applications, (2) Stable inversion of fixed-energy 3D scattering data and its error estimate, (3) Inverse scattering with 'incomplete' data, (4) Inverse scattering for inhomogeneous Schroedinger equation, (5) Krein's inverse scattering method, (6) Invertibility of the steps in Gel'fand-Levitan, Marchenko, and Krein inversion methods, (7) The Newton-Sabatier and Cox-Thompson procedures are not inversion methods, (8) Resonances: existence, location, perturbation theory, (9) Born inversion as an ill-posed problem, (10) Inverse obstacle scattering with fixed-frequency data, (11) Inverse scattering with data at a fixed energy and a fixed incident direction, (12) Creating materials with a desired refraction coefficient and wave-focusing properties. (author)

Spectroscopic study of light scattering in linear alkylbenzene for liquid scintillator neutrino detectors

Energy Technology Data Exchange (ETDEWEB)

Zhou, Xiang; Zhang, Zhenyu [Wuhan University, Hubei Nuclear Solid Physics Key Laboratory, Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan (China); Liu, Qian; Zheng, Yangheng [University of Chinese Academy of Sciences, School of Physics, Beijing (China); Han, Junbo [Huazhong University of Science and Technology, Wuhan National High Magnetic Field Center, Wuhan (China); Zhang, Xuan; Ding, Yayun; Zhou, Li; Cao, Jun; Wang, Yifang [Chinese Academy of Sciences, Institute of High Energy Physics, Beijing (China)

2015-11-15

We have set up a light scattering spectrometer to study the depolarization of light scattering in linear alkylbenzene. The scattering spectra show that the depolarized part of light scattering is due to Rayleigh scattering. The additional depolarized Rayleigh scattering can make the effective transparency of linear alkylbenzene much better than expected. Therefore, sufficient scintillation photons can transmit through large liquid scintillator detector, such as that of the JUNO experiment. Our study is crucial to achieving an unprecedented energy resolution of 3 %/√(E(MeV)) required for the JUNO experiment to determine the neutrino mass hierarchy. The spectroscopic method can also be used to examine the depolarization of other organic solvents used in neutrino experiments. (orig.)

Spectroscopic study of light scattering in linear alkylbenzene for liquid scintillator neutrino detectors

Energy Technology Data Exchange (ETDEWEB)

Zhou, Xiang, E-mail: xiangzhou@whu.edu.cn [Hubei Nuclear Solid Physics Key Laboratory, Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, 430072, Wuhan (China); Liu, Qian, E-mail: liuqian@ucas.ac.cn [School of Physics, University of Chinese Academy of Sciences, 100049, Beijing (China); Han, Junbo [Wuhan National High Magnetic Field Center, Huazhong University of Science and Technology, 430074, Wuhan (China); Zhang, Zhenyu [Hubei Nuclear Solid Physics Key Laboratory, Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, 430072, Wuhan (China); Zhang, Xuan; Ding, Yayun [Institute of High Energy Physics, Chinese Academy of Sciences, 100049, Beijing (China); Zheng, Yangheng [School of Physics, University of Chinese Academy of Sciences, 100049, Beijing (China); Zhou, Li; Cao, Jun; Wang, Yifang [Institute of High Energy Physics, Chinese Academy of Sciences, 100049, Beijing (China)

2015-11-21

We have set up a light scattering spectrometer to study the depolarization of light scattering in linear alkylbenzene. The scattering spectra show that the depolarized part of light scattering is due to Rayleigh scattering. The additional depolarized Rayleigh scattering can make the effective transparency of linear alkylbenzene much better than expected. Therefore, sufficient scintillation photons can transmit through large liquid scintillator detector, such as that of the JUNO experiment. Our study is crucial to achieving an unprecedented energy resolution of 3 %/√(E(MeV)) required for the JUNO experiment to determine the neutrino mass hierarchy. The spectroscopic method can also be used to examine the depolarization of other organic solvents used in neutrino experiments.

Markov chain solution of photon multiple scattering through turbid slabs.

Science.gov (United States)

Lin, Ying; Northrop, William F; Li, Xuesong

2016-11-14

This work introduces a Markov Chain solution to model photon multiple scattering through turbid slabs via anisotropic scattering process, i.e., Mie scattering. Results show that the proposed Markov Chain model agree with commonly used Monte Carlo simulation for various mediums such as medium with non-uniform phase functions and absorbing medium. The proposed Markov Chain solution method successfully converts the complex multiple scattering problem with practical phase functions into a matrix form and solves transmitted/reflected photon angular distributions by matrix multiplications. Such characteristics would potentially allow practical inversions by matrix manipulation or stochastic algorithms where widely applied stochastic methods such as Monte Carlo simulations usually fail, and thus enable practical diagnostics reconstructions such as medical diagnosis, spray analysis, and atmosphere sciences.

Quasiresonant scattering

International Nuclear Information System (INIS)

Hategan, Cornel; Comisel, Horia; Ionescu, Remus A.

2004-01-01

The quasiresonant scattering consists from a single channel resonance coupled by direct interaction transitions to some competing reaction channels. A description of quasiresonant Scattering, in terms of generalized reduced K-, R- and S- Matrix, is developed in this work. The quasiresonance's decay width is, due to channels coupling, smaller than the width of the ancestral single channel resonance (resonance's direct compression). (author)

Elastic and quasielastic scattering of light nuclei in the theory of multiple scattering

International Nuclear Information System (INIS)

Ismatov, E.I.; Kuterbekov, K.A.; Dzhuraev, Sh.Kh.; Ehsaniyazov, Sh.P.; Zholdasova, S.M.

2005-01-01

In the work the calculation method for diffraction scattering amplitudes of light nuclei by heavy nuclei is developed. For A 1 A 2 -scattering effects of pair-, three-fold, and four-fold screenings are estimated. It is shown, that in amplitude calculations for A 1 A 2 elastic scattering it is enough come to nothing more than accounting of total screenings in the first order. Analysis of nucleus-nucleus scattering sensitive characteristics to choice of single-particle nuclear densities parametrization is carried out

Exact multiple scattering theory of two-nucleus collisions including the Pauli principle

International Nuclear Information System (INIS)

Gurvitz, S.A.

1981-01-01

Exact equations for two-nucleus scattering are derived in which the effects of the Pauli principle are fully included. Our method exploits a modified equation for the scattering of two identical nucleons, which is obtained at the beginning. Considering proton-nucleus scattering we found that the resulting amplitude has two components, one resembling a multiple scattering series for distinguishable particles, and the other a distorted (A-1) nucleon cluster exchange. For elastic pA scattering the multiple scattering amplitude is found in the form of an optical potential expansion. We show that the Kerman-McManus-Thaler theory of the optical potential could be easily modified to include the effects of antisymmetrization of the projectile with the target nucleons. Nucleus-nucleus scattering is studied first for distinguishable target and beam nucleus. Afterwards the Pauli principle is included, where only the case of deuteron-nucleus scattering is discussed in detail. The resulting amplitude has four components. Two of them correspond to modified multiple scattering expansions and the others are distorted (A-1)- and (A-2)- nucleon cluster exchange. The result for d-A scattering is extended to the general case of nucleus-nucleus scattering. The equations are simple to use and as such constitute an improvement over existing schemes

Selective scattering in a zigzag graphene nanoribbon

International Nuclear Information System (INIS)

Nakabayashi, Jun; Kurihara, Susumu

2009-01-01

Electric transport of a zigzag graphene nanoribbon through a step-like potential or a potential barrier is studied by using the recursive Green's function method. The results for a step-like potential show that scattering processes in a zigzag graphene nanoribbon obey a following selection rule: when the number of zigzag chains N is even, electrons in the band m are only scattered into the bands m+2n, where n is an integer. According to this selection rule, a step-like potential blocks the current when the potential height exceeds the incident energy as long as only the low-energy region is treated. Then, replacing a step-like potential with a potential barrier, we also show that it can play the role of a b and-selective filter .

No surprise in the first Born approximation for electron scattering

International Nuclear Information System (INIS)

Lentzen, M.

2014-01-01

In a recent article it is argued that the far-field expansion of electron scattering, a pillar of electron diffraction theory, is wrong (Treacy and Van Dyck, 2012 [1]). It is further argued that in the first Born approximation of electron scattering the intensity of the electron wave is not conserved to first order in the scattering potential. Thus a “mystery of the missing phase” is investigated, and the supposed flaw in scattering theory is seeked to be resolved by postulating a standing spherical electron wave (Treacy and Van Dyck, 2012 [1]). In this work we show, however, that these theses are wrong. A review of the essential parts of scattering theory with careful checks of the underlying assumptions and limitations for high-energy electron scattering yields: (1) the traditional form of the far-field expansion, comprising a propagating spherical wave, is correct; (2) there is no room for a missing phase; (3) in the first Born approximation the intensity of the scattered wave is conserved to first order in the scattering potential. The various features of high-energy electron scattering are illustrated by wave-mechanical calculations for an explicit target model, a Gaussian phase object, and for a Si atom, considering the geometric conditions in high-resolution transmission electron microscopy. - Highlights: Treacy and Van Dyck (2012) argue that the far-field expansion of electron scattering is wrong. The chief theses of that former work are wrong. There is no room for the missing phase proposed by Treacy and Van Dyck. There is no violation of the intensity conservation to first order in the scattering potential. Calculations for a phase object and an atomic target confirm traditional scattering theory

Continuum multiple-scattering approach to electron-molecule scattering and molecular photoionization

International Nuclear Information System (INIS)

Dehmer, J.L.; Dill, D.

1979-01-01

The multiple-scattering approach to the electronic continuum of molecules is described. The continuum multiple-scattering model (CMSM) was developed as a survey tool and, as such was required to satisfy two requirements. First, it had to have a very broad scope, which means (i) molecules of arbitrary geometry and complexity containing any atom in the periodic system, (ii) continuum electron energies from 0-1000 eV, and (iii) capability to treat a large range of processes involving both photoionization and electron scattering. Second, the structure of the theory was required to lend itself to transparent, physical interpretation of major spectral features such as shape resonances. A comprehensive theoretical framework for the continuum multiple scattering method is presented, as well as its applications to electron-molecule scattering and molecular photoionization. Highlights of recent applications in these two areas are reviewed. The major impact of the resulting studies over the last few years has been to establish the importance of shape resonances in electron collisions and photoionization of practically all (non-hydride) molecules

Ocular forward light scattering and corneal backward light scattering in patients with dry eye.

Science.gov (United States)

Koh, Shizuka; Maeda, Naoyuki; Ikeda, Chikako; Asonuma, Sanae; Mitamura, Hayato; Oie, Yoshinori; Soma, Takeshi; Tsujikawa, Motokazu; Kawasaki, Satoshi; Nishida, Kohji

2014-09-18

To evaluate ocular forward light scattering and corneal backward light scattering in patients with dry eye. Thirty-five eyes in 35 patients with dry eye and 20 eyes of 20 healthy control subjects were enrolled. The 35 dry eyes were classified into two groups according to whether superficial punctate keratopathy in the central 6-mm corneal zone (cSPK) was present or not. Ocular forward light scattering was quantified with a straylight meter. Corneal backward light scattering from the anterior, middle, and posterior corneal parts was assessed with a corneal densitometry program using the Scheimpflug imaging system. Both dry eye groups had significantly higher intraocular forward light scattering than the control group (both Pdry eye group with cSPK had significantly higher values in anterior and total corneal backward light scattering than the other two groups. Moderate positive correlations were observed between the cSPK score and corneal backward light scattering from the anterior cornea (R=0.60, Pdry eyes than in normal eyes. Increased corneal backward light scattering in dry eye at least partially results from cSPK overlying the optical zone. Copyright 2014 The Association for Research in Vision and Ophthalmology, Inc.

More effective field theory for non-relativistic scattering

International Nuclear Information System (INIS)

Kaplan, D.B.

1997-01-01

An effective field theory treatment of nucleon-nucleon scattering at low energy shows much promise and could prove to be a useful tool in the study of nuclear matter at both ordinary and extreme densities. The analysis is complicated by the existence a large length scale - the scattering length -which arises due to couplings in the short distance theory being near critical values. I show how this can be dealt with by introducing an explicit s-channel state in the effective field theory. The procedure is worked out analytically in a toy example. I then demonstrate that a simple effective field theory excellently reproduces the 1 S 0 np phase shift up to the pion production threshold. (orig.)

Sagittal plane analysis of the spine and pelvis in degenerative lumbar scoliosis.

Science.gov (United States)

Han, Fei; Weishi, Li; Zhuoran, Sun; Qingwei, Ma; Zhongqiang, Chen

2017-01-01

Previous studies have reported the normative values of pelvic sagittal parameters, but no study has analyzed the sagittal spino-pelvic alignment in degenerative lumbar scoliosis (DLS) and its role in the pathogenesis. Retrospective analysis was applied to 104 patients with DLS, together with 100 cases of asymptomatic young adults as a control group and another control group consisting of 145 cases with cervical spondylosis. The coronal and sagittal parameters were measured on the anteroposterior and lateral radiograph of the whole spine in the DLS group as well as in the two control groups. Statistical analysis showed that the DLS group had a higher pelvic incidence (PI) value (50.5° ± 10.2°), than the normal control group (with PI 47.2° ± 8.8°) and the cervical spondylosis group (46.9° ± 9.1°). In DLS group, there were 38 cases (36.5%) complicated with degenerative lumbar spondylolisthesis, who had higher PI values than patients without it. Besides, the lumbar lordosis (LL) and sacral slope (SS) of DLS group were lower; the scoliosis Cobb's angle was correlated with pelvic tilt (PT); thoracic kyphosis was correlated with LL, SS, and PT; and LL was correlated with other sagittal parameters. Patients with DLS may have a higher PI, which may impact the pathogenesis of DLS. A high PI value is probably associated with the high prevalence of degenerative lumbar spondylolisthesis among DLS patients. In DLS patients, the lumbar spine maintains the ability of regulating the sagittal balance, and the regulation depends more on thoracic curve.

Development of neutron diffuse scattering analysis code by thin film and multilayer film

International Nuclear Information System (INIS)

Soyama, Kazuhiko

2004-01-01

To research surface structure of thin film and multilayer film by neutron, a neutron diffuse scattering analysis code using DWBA (Distorted-Wave Bron Approximation) principle was developed. Subjects using this code contain the surface and interface properties of solid/solid, solid/liquid, liquid/liquid and gas/liquid, and metal, magnetism and polymer thin film and biomembran. The roughness of surface and interface of substance shows fractal self-similarity and its analytical model is based on DWBA theory by Sinha. The surface and interface properties by diffuse scattering are investigated on the basis of the theoretical model. The calculation values are proved to be agreed with the experimental values. On neutron diffuse scattering by thin film, roughness of surface of thin film, correlation function, neutron propagation by thin film, diffuse scattering by DWBA theory, measurement model, SDIFFF (neutron diffuse scattering analysis program by thin film) and simulation results are explained. On neutron diffuse scattering by multilayer film, roughness of multilayer film, principle of diffuse scattering, measurement method and simulation examples by MDIFF (neutron diffuse scattering analysis program by multilayer film) are explained. (S.Y.)To research surface structure of thin film and multilayer film by neutron, a neutron diffuse scattering analysis code using DWBA (Distorted-Wave Bron Approximation) principle was developed. Subjects using this code contain the surface and interface properties of solid/solid, solid/liquid, liquid/liquid and gas/liquid, and metal, magnetism and polymer thin film and biomembran. The roughness of surface and interface of substance shows fractal self-similarity and its analytical model is based on DWBA theory by Sinha. The surface and interface properties by diffuse scattering are investigated on the basis of the theoretical model. The calculation values are proved to be agreed with the experimental values. On neutron diffuse scattering

Planet-planet scattering leads to tightly packed planetary systems

OpenAIRE

Raymond, Sean N.; Barnes, Rory; Veras, Dimitri; Armitage, Philip J.; Gorelick, Noel; Greenberg, Richard

2009-01-01

The known extrasolar multiple-planet systems share a surprising dynamical attribute: they cluster just beyond the Hill stability boundary. Here we show that the planet-planet scattering model, which naturally explains the observed exoplanet eccentricity distribution, can reproduce the observed distribution of dynamical configurations. We calculated how each of our scattered systems would appear over an appropriate range of viewing geometries; as Hill stability is weakly dependent on the masse...

Elastic scattering of low energy electrons by hydrogen molecule

International Nuclear Information System (INIS)

Freitas, L.C.G.; Mu-Tao, L.; Botelho, L.F.

1987-01-01

The coherent version of the Renormalized Multiple-Centre Potential Model (RMPM) has been extended to treat the elastic scattering of low energy electrons by H2 molecule. The intramolecular Multiple Scattering (MS) effect has also been included. The comparison against the experimental data shows that the inclusion of the MS improves significantly with experiment. The extension of the present method to study electron-polyatomic molecule interaction is also discussed. (author) [pt

On the theory of inelastic scattering of slow electrons by surface excitations: 2. Thin film formalism

International Nuclear Information System (INIS)

Nkoma, J.S.

1982-08-01

A quantum-mechanical theory for the inelastic scattering of slow electrons (ISSE) by surface excitations in a thin film is developed. The scattered wave function inside the thin film is obtained by solving the inhomogeneous Schroedinger equation, and it is found to contain terms which show that the back scattered intensity is smaller than the forward scattered intensity. A scattering cross-section for forward scattering is derived and is found to be dependent on transmission factors, wavevectors and fluctuations of the scattering potential. (author)

Quantum theory of scattering

CERN Document Server

Wu Ta You

1962-01-01

This volume addresses the broad formal aspects and applications of the quantum theory of scattering in atomic and nuclear collisions. An encyclopedic source of pioneering work, it serves as a text for students and a reference for professionals in the fields of chemistry, physics, and astrophysics. The self-contained treatment begins with the general theory of scattering of a particle by a central field. Subsequent chapters explore particle scattering by a non-central field, collisions between composite particles, the time-dependent theory of scattering, and nuclear reactions. An examinati

Bubble nonlinear dynamics and stimulated scattering process

Science.gov (United States)

Jie, Shi; De-Sen, Yang; Sheng-Guo, Shi; Bo, Hu; Hao-Yang, Zhang; Shi-Yong, Hu

2016-02-01

A complete understanding of the bubble dynamics is deemed necessary in order to achieve their full potential applications in industry and medicine. For this purpose it is first needed to expand our knowledge of a single bubble behavior under different possible conditions including the frequency and pressure variations of the sound field. In addition, stimulated scattering of sound on a bubble is a special effect in sound field, and its characteristics are associated with bubble oscillation mode. A bubble in liquid can be considered as a representative example of nonlinear dynamical system theory with its resonance, and its dynamics characteristics can be described by the Keller-Miksis equation. The nonlinear dynamics of an acoustically excited gas bubble in water is investigated by using theoretical and numerical analysis methods. Our results show its strongly nonlinear behavior with respect to the pressure amplitude and excitation frequency as the control parameters, and give an intuitive insight into stimulated sound scattering on a bubble. It is seen that the stimulated sound scattering is different from common dynamical behaviors, such as bifurcation and chaos, which is the result of the nonlinear resonance of a bubble under the excitation of a high amplitude acoustic sound wave essentially. The numerical analysis results show that the threshold of stimulated sound scattering is smaller than those of bifurcation and chaos in the common condition. Project supported by the Program for Changjiang Scholars and Innovative Research Team in University, China (Grant No. IRT1228) and the Young Scientists Fund of the National Natural Science Foundation of China (Grant Nos. 11204050 and 11204049).

Gravitational scattering of electromagnetic radiation

Science.gov (United States)

Brooker, J. T.; Janis, A. I.

1980-01-01

The scattering of electromagnetic radiation by linearized gravitational fields is studied to second order in a perturbation expansion. The incoming electromagnetic radiation can be of arbitrary multipole structure, and the gravitational fields are also taken to be advanced fields of arbitrary multipole structure. All electromagnetic multipole radiation is found to be scattered by gravitational monopole and time-varying dipole fields. No case has been found, however, in which any electromagnetic multipole radiation is scattered by gravitational fields of quadrupole or higher-order multipole structure. This lack of scattering is established for infinite classes of special cases, and is conjectured to hold in general. The results of the scattering analysis are applied to the case of electromagnetic radiation scattered by a moving mass. It is shown how the mass and velocity may be determined by a knowledge of the incident and scattered radiation.

Spectral scattering characteristics of space target in near-UV to visible bands.

Science.gov (United States)

Bai, Lu; Wu, Zhensen; Cao, Yunhua; Huang, Xun

2014-04-07

In this study, the spectral scattering characteristics of a space target are calculated in the near-UV to visible bands on the basis of measured data of spectral hemispheric reflectivity in the upper half space. Further, the bidirectional reflection distribution function (BRDF) model proposed by Davies is modified to describe the light scattering properties of a target surface. This modification aims to improve the characteristics identifying ability for different space targets. By using this modified Davies spectrum BRDF model, the spectral scattering characteristics of each subsurface can be obtained. A mathematical model of spectral scattering properties of the space target is built by summing all the contributing surface grid reflection scattering components, considering the impact of surface shadow effect.Moreover, the spectral scattering characteristics of the space target calculated with both the traditional and modified Davies BRDF models are compared. The results show that in the fixed and modified cases, the hemispheric reflectivity significantly affects the spectral scattering irradiance of the target.

Diffuse scattering in Ih ice

International Nuclear Information System (INIS)

Wehinger, Björn; Krisch, Michael; Bosak, Alexeï; Chernyshov, Dmitry; Bulat, Sergey; Ezhov, Victor

2014-01-01

Single crystals of ice Ih, extracted from the subglacial Lake Vostok accretion ice layer (3621 m depth) were investigated by means of diffuse x-ray scattering and inelastic x-ray scattering. The diffuse scattering was identified as mainly inelastic and rationalized in the frame of ab initio calculations for the ordered ice XI approximant. Together with Monte-Carlo modelling, our data allowed reconsidering previously available neutron diffuse scattering data of heavy ice as the sum of thermal diffuse scattering and static disorder contribution. (paper)

Scattering of intermediate energy protons

International Nuclear Information System (INIS)

Chaumeaux, Alain.

1980-06-01

The scattering of 1 GeV protons appears to be a powerful means of investigating nuclear matter. We worked with SPESI and the formalism of Kerman-Mc Manus and Thaler. The amplitude of nucleon-nucleon scattering was studied as were the aspects of 1 GeV proton scattering (multiple scattering, absorption, spin-orbit coupling, N-N amplitude, KMT-Glauber comparison, second order effects). The results of proton scattering on 16 O, the isotopes of calcium, 58 Ni, 90 Zr and 208 Pb are given [fr

Electronic properties of Be and Al by Compton scattering technique

International Nuclear Information System (INIS)

Aguiar, J.C.; Di Rocco, H.O.

2011-01-01

In this work, electronic properties of beryllium and aluminum are examined by using Compton scattering technique. The method is based on the irradiation of samples using a beam narrow of mono- energetic photons of 59.54 keV product of radioactive decay of Am -241 . Scattered radiation is collected by a high resolution semiconductor detector positioned at an angle of 90°. The measured spectrum is commonly called Compton profile and contains useful information about the electronic structure of the material. The experimental results are compared with theoretical calculations such as density functional theory showing a good agreement. However, these results show some discrepancies with many libraries used in codes such as Monte Carlo simulation. Since these libraries are based on the values tabulated by Biggs, Mendelsohn and Mann 1975 thus overestimating the scattered radiation on the material. (authors) [es

Neutron scattering from (CD3ND3)2MnCl4

International Nuclear Information System (INIS)

Lehner, N.

1978-12-01

For the perovskite-type crystal (CD 3 ND 3 ) 2 MnCl 4 neutron scattering experiments were performed concerning the magnetic behaviour, critical phenomena and lattice dynamics. The crystal is built up from layers, resulting in a quasi two-dimensional antiferromagnetic order, whereas the lattice dynamics shows a more three-dimensional behaviour; this can be explained by long-range Coulomb forces. Only the correlation lengths, which were determined by critical scattering, show a pronounced anisotropy. (orig.) [de

Imaging moving objects from multiply scattered waves and multiple sensors

International Nuclear Information System (INIS)

Miranda, Analee; Cheney, Margaret

2013-01-01

In this paper, we develop a linearized imaging theory that combines the spatial, temporal and spectral components of multiply scattered waves as they scatter from moving objects. In particular, we consider the case of multiple fixed sensors transmitting and receiving information from multiply scattered waves. We use a priori information about the multipath background. We use a simple model for multiple scattering, namely scattering from a fixed, perfectly reflecting (mirror) plane. We base our image reconstruction and velocity estimation technique on a modification of a filtered backprojection method that produces a phase-space image. We plot examples of point-spread functions for different geometries and waveforms, and from these plots, we estimate the resolution in space and velocity. Through this analysis, we are able to identify how the imaging system depends on parameters such as bandwidth and number of sensors. We ultimately show that enhanced phase-space resolution for a distribution of moving and stationary targets in a multipath environment may be achieved using multiple sensors. (paper)

Influence of orientation averaging on the anisotropy of thermal neutrons scattering on water molecules

International Nuclear Information System (INIS)

Markovic, M. I.; Radunovic, J. B.

1976-01-01

Determination of spatial distribution of neutron flux in water, most frequently used moderator in thermal reactors, demands microscopic scattering kernels dependence on cosine of thermal neutrons scattering angle when solving the Boltzmann equation. Since spatial orientation of water molecules influences this dependence it is necessary to perform orientation averaging or rotation-vibrational intermediate scattering function for water molecules. The calculations described in this paper and the obtained results showed that methods of orientation averaging do not influence the anisotropy of thermal neutrons scattering on water molecules, but do influence the inelastic scattering

TH-AB-209-10: Breast Cancer Identification Through X-Ray Coherent Scatter Spectral Imaging

Energy Technology Data Exchange (ETDEWEB)

Kapadia, A; Morris, R; Albanese, K; Spencer, J; McCall, S; Greenberg, J [Duke University, Durham, NC (United States)

2016-06-15

Purpose: We have previously described the development and testing of a coherent-scatter spectral imaging system for identification of cancer. Our prior evaluations were performed using either tissue surrogate phantoms or formalin-fixed tissue obtained from pathology. Here we present the first results from a scatter imaging study using fresh breast tumor tissues obtained through surgical excision. Methods: A coherent-scatter imaging system was built using a clinical X-ray tube, photon counting detectors, and custom-designed coded-apertures. System performance was characterized using calibration phantoms of biological materials. Fresh breast tumors were obtained from patients undergoing mastectomy and lumpectomy surgeries for breast cancer. Each specimen was vacuum-sealed, scanned using the scatter imaging system, and then sent to pathology for histological workup. Scatter images were generated separately for each tissue specimen and analyzed to identify voxels containing malignant tissue. The images were compared against histological analysis (H&E + pathologist identification of tumors) to assess the match between scatter-based and histological diagnosis. Results: In all specimens scanned, the scatter images showed the location of cancerous regions within the specimen. The detection and classification was performed through automated spectral matching without the need for manual intervention. The scatter spectra corresponding to cancer tissue were found to be in agreement with those reported in literature. Inter-patient variability was found to be within limits reported in literature. The scatter images showed agreement with pathologist-identified regions of cancer. Spatial resolution for this configuration of the scanner was determined to be 2–3 mm, and the total scan time for each specimen was under 15 minutes. Conclusion: This work demonstrates the utility of coherent scatter imaging in identifying cancer based on the scatter properties of the tissue. It

Multiple-scattering in radar systems: A review

International Nuclear Information System (INIS)

Battaglia, Alessandro; Tanelli, Simone; Kobayashi, Satoru; Zrnic, Dusan; Hogan, Robin J.; Simmer, Clemens

2010-01-01

predominantly in the forward direction. A complete understanding of radiation transport modeling and data analysis methods under wide-angle multiple scattering conditions is mandatory for a correct interpretation of echoes observed by space-borne millimeter radars. This paper reviews the status of research in this field. Different numerical techniques currently implemented to account for higher order scattering are reviewed and their weaknesses and strengths highlighted. Examples of simulated radar backscattering profiles are provided with particular emphasis given to situations in which the multiple scattering contributions become comparable or overwhelm the single scattering signal. We show evidences of multiple scattering effects from air-borne and from CloudSat observations, i.e. unique signatures which cannot be explained by single scattering theory. Ideas how to identify and tackle the multiple scattering effects are discussed. Finally perspectives and suggestions for future work are outlined. This work represents a reference-guide for studies focused at modeling the radiation transport and at interpreting data from high frequency space-borne radar systems that probe highly opaque scattering media such as thick ice clouds or precipitating clouds.

Characterizing the behavior of scattered radiation in multi-energy x-ray imaging

Energy Technology Data Exchange (ETDEWEB)

Sossin, Artur, E-mail: artur.sossin@gmail.com [CEA-LETI MINATEC Grenoble, F-38054 Grenoble (France); Rebuffel, V.; Tabary, J. [CEA-LETI MINATEC Grenoble, F-38054 Grenoble (France); Létang, J.M.; Freud, N. [Univ Lyon, INSA-Lyon, Université Lyon 1, UJM-Saint Etienne, CNRS, Inserm, Centre Léon Bérard, CREATIS UMR 5220 U1206, F-69373 Lyon (France); Verger, L. [CEA-LETI MINATEC Grenoble, F-38054 Grenoble (France)

2017-04-01

Scattered radiation results in various undesirable effects in medical diagnostics, non-destructive testing (NDT) and security x-ray imaging. Despite numerous studies characterizing this phenomenon and its effects, the knowledge of its behavior in the energy domain remains limited. The present study aims at summarizing some key insights on scattered radiation originating from the inspected object. In addition, various simulations and experiments with limited collimation on both simplified and realistic phantoms were conducted in order to study scatter behavior in multi-energy x-ray imaging. Results showed that the spectrum shape of the scatter component can be considered preserved in the first approximation across the image plane for various acquisition geometries and phantoms. The variations exhibited by the scatter spectrum were below 10% for most examined cases. Furthermore, the corresponding spectrum shape proved to be also relatively invariant for different experimental angular projections of one of the examined phantoms. The observed property of scattered radiation can potentially lead to the decoupling of spatial and energy scatter components, which can in turn enable speed ups in scatter simulations and reduce the complexity of scatter correction.

Pump Side-scattering in Ultra-powerful Backward Raman Amplifiers

International Nuclear Information System (INIS)

Solodov, A.A.; Malkin, V.M.; Fisch, N.J.

2004-01-01

Extremely large laser power might be obtained by compressing laser pulses through backward Raman amplification (BRA) in plasmas. Premature Raman backscattering of a laser pump by plasma noise might be suppressed by an appropriate detuning of the Raman resonance, even as the desired amplification of the seed persists with a high efficiency. In this paper, we analyze side-scattering of laser pumps by plasma noise in backward Raman amplifiers. Though its growth rate is smaller than that of backscattering, the side-scattering can nevertheless be dangerous, because of a longer path of side-scattered pulses in plasmas and because of an angular dependence of the Raman resonance detuning. We show that side-scattering of laser pumps by plasma noise in BRA might be suppressed to a tolerable level at all angles by an appropriate combination of two detuning mechanisms associated with plasma density gradient and pump chirp

Linear systems formulation of scattering theory for rough surfaces with arbitrary incident and scattering angles.

Science.gov (United States)

Krywonos, Andrey; Harvey, James E; Choi, Narak

2011-06-01

Scattering effects from microtopographic surface roughness are merely nonparaxial diffraction phenomena resulting from random phase variations in the reflected or transmitted wavefront. Rayleigh-Rice, Beckmann-Kirchhoff. or Harvey-Shack surface scatter theories are commonly used to predict surface scatter effects. Smooth-surface and/or paraxial approximations have severely limited the range of applicability of each of the above theoretical treatments. A recent linear systems formulation of nonparaxial scalar diffraction theory applied to surface scatter phenomena resulted first in an empirically modified Beckmann-Kirchhoff surface scatter model, then a generalized Harvey-Shack theory that produces accurate results for rougher surfaces than the Rayleigh-Rice theory and for larger incident and scattered angles than the classical Beckmann-Kirchhoff and the original Harvey-Shack theories. These new developments simplify the analysis and understanding of nonintuitive scattering behavior from rough surfaces illuminated at arbitrary incident angles.

Characterization of tin oxide nanoparticles synthesized via oxidation from metal; Caracterizacao de nanoparticulas de oxido de estanho sintetizado via oxidacao do metal

Energy Technology Data Exchange (ETDEWEB)

Abruzzi, R.C.; Dedavid, B.A.; Pires, M.J.R.; Streicher, M., E-mail: afael.abruzzi@acad.pucrs.br [Pontificia Universidade Catolica do Rio Grande do Sul (PUC-RS), Porto Alegre, RS (Brazil). Pos-Graduacao em Engenharia e Tecnologia de Materiais

2014-07-01

The tin oxide (SnO{sub 2}) is a promising material with great potential for applications such as gas sensors and catalysts. This oxide nanostructures show higher activation efficiency due to its larger effective surface. This paper presents the synthesis and characterization of the tin oxide in different conditions, via oxidation of pure tin with nitric acid. Results obtained from the characterization of SnO{sub 2} powder by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDX), Particle size by Dynamic Light Scattering (DLS) and Infrared Spectroscopy (FTIR) indicated that the conditions were suitable for the synthesis to obtain manometric tin oxide granules with crystalline structure of rutile. (author)

Exosomes in Development and Therapy of Malignant Mesothelioma

Science.gov (United States)

2015-09-01

exosomes. B. Dynamic light scattering (DLS) showing the size of the exosomes. 6 Histone H4 OS=Homo sapiens GN=HIST1H4A PE=1 SV=2 H4_HUMAN Keratin, type I...cytoskeletal 9 OS=Homo sapiens GN=KRT9 PE=1 SV=3 K1C9_HUMAN Isoform 2 of Clathrin heavy chain 1 OS=Homo sapiens GN=CLTC sp|Q00610-2|CLH1_HUMAN (+1...Clathrin heavy chain 2 OS=Homo sapiens GN=CLTCL1 PE=1 SV=2 sp|P53675|CLH2_HUMAN Cluster of Histone H2A type 1-B/E OS=Homo sapiens GN=HIST1H2AB PE=1 SV

Characterization of the Spindle Morphology Nanomicelles Assembled from Sericin and Gelatin

Directory of Open Access Journals (Sweden)

Xiaozhou Su

2017-01-01

Full Text Available Complex nanomicelles were prepared by sericin and type A gelatin with molecular weight of 5789 Da and 128664 Da separately. The assembling conditions were as follows: mass ratio (sericin/gelatin was 1 : 1, protein concentration was 0.5%, temperature was 35°C, and assembling time was 18 hours. Scanning electron microscopy (SEM, atomic force microscopy (AFM, transmission electron microscopy (TEM, Fourier transform infrared (FT-IR spectroscopy, differential scanning calorimetry (DSC, and dynamic light scattering (DLS were conducted to observe and characterize the complex nanomicelles. Results showed that the complex sericin/gelatin micelles was a kind of nanospindle micelles. The micelles had high electrochemical stability, thermal stability, antidilution stability, and storage stability.

Neutron scattering on partially deuterated polybutadiene

CERN Document Server

Kahle, S; Monkenbusch, M; Richter, D; Arbe, A; Colmenero, J; Frick, B

2002-01-01

The molecular nature of the secondary relaxation (Johari-Goldstein relaxation) and its relationship with the alpha relaxation is in most cases still unknown. In order to access these processes on a molecular level, it is necessary to obtain spatial information of the relaxation. Through the momentum-transfer dependence of the dynamic structure factor S(Q,t), this information can be provided by quasielastic neutron scattering techniques. The large difference in scattering lengths between hydrogen and deuterium allows us to accentuate specific correlations between atoms in a polymer melt. Here, we report on recent results on a polybutadiene melt, where the double bond was hydrogeneous, while the methylene groups carried deuterons (d4h2-PB). In this way the correlations between the double bonds are emphasised. We will show that the double bond/double bond correlation function, generated in this way, shows the same temperature dependence as the viscosity at higher temperatures at the structure factor peak maximum...

Collective scattering of electromagnetic waves and cross-B plasma diffusion

International Nuclear Information System (INIS)

Gresillon, D.; Cabrit, B.; Truc, A.

1992-01-01

Magnetized plasmas occuring in nature as well as in fusion laboratories are oftenly irregularly shaked by magnetic field fluctuations. The so-called ''coherent scattering'' of electromagnetic wave from nonuniform, irregularly moving plasmas is investigated in the case where the scattering wavelength is large compared to the Debye length, but of the order of the irregularities correlation length. The scattered signal frequency spectrum is shown to be a transform of the plasma motion statistical characteristics. When the scattering wavelength is larger than the plasma motion correlation length, the frequency spectrum is shown to be of a lorentzian shape, with a frequency width that provides a direct measurement of the cross-B particle diffusion coefficient. This is illustrated by two series of recently obtained experimental results: radar coherent backscattering observations of the auroral plasma, and far infrared scattering from tokamak fusion plasma. Radar coherent backscattering shows the transition from Gauss to Lorentz scattered frequency spectra. In infrared Laser coherent scattering experiments from the Tore-Supra tokamak, a particular frequency line is observed to present a Lorentzian shape, that directly provides an electron cross-field diffusion coefficient. This diffusion coefficient agrees with the electron heat conductivity coefficient that is obtained from the observation of temperature profiles and energy balance. (Author)

Characterization of a material by probability of linear scattering using effect of target thickness

International Nuclear Information System (INIS)

Nghiep, T.D.; Khai, N.T.; Cong, N.T.; Minh, D.T.N.

2013-01-01

We report on an experimental test with 662 keV gamma photons scattered from a set of samples from 6 C, 13 Al, 26 Fe, 29 Cu, 47 Ag, 82 Pb and stainless steel for determination of probability of linear scattering, which can be used for characterization of a material. The results show that for the given target and scattering angle, the effect of target thickness in gamma photons scattering relates to single and multiple scattering and that the scattered events exponentially increase with an increase in target thickness and saturation at some values of thickness. The experimental results correlate with the typical function of energy transfer model. (author)

A direct sampling method to an inverse medium scattering problem

KAUST Repository

Ito, Kazufumi

2012-01-10

In this work we present a novel sampling method for time harmonic inverse medium scattering problems. It provides a simple tool to directly estimate the shape of the unknown scatterers (inhomogeneous media), and it is applicable even when the measured data are only available for one or two incident directions. A mathematical derivation is provided for its validation. Two- and three-dimensional numerical simulations are presented, which show that the method is accurate even with a few sets of scattered field data, computationally efficient, and very robust with respect to noises in the data. © 2012 IOP Publishing Ltd.

Influence of Kohn singularity on the occurrence scattering time in degenerate quantum collisional plasmas

Science.gov (United States)

Lee, Myoung-Jae; Jung, Young-Dae

2017-10-01

The influence of Kohn singularity on the occurrence scattering time for the electron-ion interaction is investigated in degenerate quantum collisional plasmas. The first-order eikonal analysis is used to obtain the scattering amplitude and the occurrence scattering time. The result shows that the Friedel oscillation due to the Kohn singularity suppresses the advance phenomena of occurrence scattering time in both forward and backward scattering domains. It is shown that the increase of plasmon energy would reduce the time advance for both forward and backward scattering domains. However, the increase of Fermi energy would enhance the phenomena of time advance. It is also found that the time advance with high collision frequency is larger than that with low collision frequency for the forward scattering domain and vice versa for the backward scattering domain. We have shown that the time advance is stronger in general for the forward scattering domain than that for the backward scattering domain.

A mathematical formulation of the Mahaux-Weidenmueller formula for the scattering matrix

International Nuclear Information System (INIS)

Christiansen, T J; Zworski, M

2009-01-01

This paper gives a mathematical exposition of a formula for the scattering matrix for a manifold with infinite cylindrical ends or a waveguide. This formula is well known in the physics literature and we show that a variant of this formula gives the scattering matrix of the mathematics literature. Moreover, we bound the difference between the scattering matrix and an approximation of it computed using a finite rank approximation of the interaction matrix.

Rayleigh scattering for a magnetized cold plasma sphere

International Nuclear Information System (INIS)

Li Yingle; Wang Mingjun; Tang Gaofeng; Li Jin

2010-01-01

The transformation of parameter tensors for anisotropic medium in different coordinate systems is derived. The electric field for a magnetized cold plasma sphere and the general expression of scattering field from anisotropic target are obtained. The functional relations of differential scattering cross section and the radar cross section for the magnetized plasma sphere are presented. Simulation results agree with that in the literatures, which shows the method used is correct and therefore the results may provide a theoretical base for anisotropic target identification. (authors)

Scattering-matrix elements of coated infinite-length cylinders

International Nuclear Information System (INIS)

Manickavasagam, S.; Menguec, M.P.

1998-01-01

The angular variations of scattering-matrix elements of coated cylindrical particles are presented. The sensitivity of different elements for a number of physical parameters are discussed, including size parameter, real and imaginary parts of the refractive index of the outer coat, and the inner core. The numerical predictions are presented for typical index-of-refraction values of cotton fibers. These results show that the physical structure of coated cylinders can be determined from carefully conducted light-scattering experiments. copyright 1998 Optical Society of America

Photon scattering from a system of multilevel quantum emitters. I. Formalism

Science.gov (United States)

Das, Sumanta; Elfving, Vincent E.; Reiter, Florentin; Sørensen, Anders S.

2018-04-01

We introduce a formalism to solve the problem of photon scattering from a system of multilevel quantum emitters. Our approach provides a direct solution of the scattering dynamics. As such the formalism gives the scattered fields' amplitudes in the limit of a weak incident intensity. Our formalism is equipped to treat both multiemitter and multilevel emitter systems, and is applicable to a plethora of photon-scattering problems, including conditional state preparation by photodetection. In this paper, we develop the general formalism for an arbitrary geometry. In the following paper (part II) S. Das et al. [Phys. Rev. A 97, 043838 (2018), 10.1103/PhysRevA.97.043838], we reduce the general photon-scattering formalism to a form that is applicable to one-dimensional waveguides and show its applicability by considering explicit examples with various emitter configurations.

Software design of control system of CCD side-scatter lidar

Science.gov (United States)

Kuang, Zhiqiang; Liu, Dong; Deng, Qian; Zhang, Zhanye; Wang, Zhenzhu; Yu, Siqi; Tao, Zongming; Xie, Chenbo; Wang, Yingjian

2018-03-01

Because of the existence of blind zone and transition zone, the application of backscattering lidar in near-ground is limited. The side-scatter lidar equipped with the Charge Coupled Devices (CCD) can separate the transmitting and receiving devices to avoid the impact of the geometric factors which is exited in the backscattering lidar and, detect the more precise near-ground aerosol signals continuously. Theories of CCD side-scatter lidar and the design of control system are introduced. The visible control of laser and CCD and automatic data processing method of the side-scatter lidar are developed by using the software of Visual C #. The results which are compared with the calibration of the atmospheric aerosol lidar data show that signals from the CCD side- scatter lidar are convincible.

Preparation of Nanosilver and Nanogold Based on Dog Rose Aqueous Extract

OpenAIRE

Pulit, Jolanta; Banach, Marcin

2014-01-01

This paper describes a process of obtaining nanosilver and nanogold based on chemical reduction using substances contained in the aqueous extract of dog rose (Rosa canina). The resulting products were subjected to spectrophotometric analysis (UV-Vis), and testing of the nanoparticles’ size and suspension stability was carried out by measuring the electrokinetic potential, ζ, via dynamic light scattering (DLS). Solid samples were imaged by scanning electron microscopy (SEM). The obtained data ...

Enhanced Antifungal Effect of Chitosan/Pepper Tree (Schinus molle) Essential Oil Bionanocomposites on the Viability of Aspergillus parasiticus Spores

OpenAIRE

Ana Guadalupe Luque-Alcaraz; Mario Onofre Cortez-Rocha; Carlos Arturo Velázquez-Contreras; Ana Lilian Acosta-Silva; Hisila del Carmen Santacruz-Ortega; Armando Burgos-Hernández; Waldo Manuel Argüelles-Monal; Maribel Plascencia-Jatomea

2016-01-01

Chitosan nanoparticles (CS) and chitosan/pepper tree (Schinus molle) essential oil (CS-EO) bionanocomposites were synthesized by nanoprecipitation method and the in vitro antifungal activity against Aspergillus parasiticus spores was evaluated. The shape and size were evaluated by scanning electron microscopy (SEM) and dynamic light scattering (DLS). The surface charge was determined by assessing the zeta potential and the inclusion of essential oil in bionanocomposites using Fourier transfor...

Critical scattering

International Nuclear Information System (INIS)

Stirling, W.G.; Perry, S.C.

1996-01-01

We outline the theoretical and experimental background to neutron scattering studies of critical phenomena at magnetic and structural phase transitions. The displacive phase transition of SrTiO 3 is discussed, along with examples from recent work on magnetic materials from the rare-earth (Ho, Dy) and actinide (NpAs, NpSb, USb) classes. The impact of synchrotron X-ray scattering is discussed in conclusion. (author) 13 figs., 18 refs

Light scattering from a binary-liquid entanglement gel

Science.gov (United States)

Xia, K.-Q.; Maher, J. V.

1987-09-01

Light-scattering experiments have been carried out on an entanglement gel with a binary-liquid mixture as solvent. The onset temperature for critical opalescence has a composition dependence which is similar to the coexistence curve of the free-liquid mixture. This system resembles previously reported work on the cross-linked gel polyacrylamide in two ways: (1) As temperature is lowered toward the critical temperature of the free-liquid mixture, the binary-fluid gel exhibits a strong and increasing light scattering over a broad temperature region of several kelvins, and (2) no appreciable temporal fluctuations are observed throughout this temperature region. Two added features are observed in the present, entanglement-gel measurements: (a) Gel samples with solvent composition both near and off the critical composition of the free-liquid mixture exhibit similar light-scattering behavior, and (b) a Lorentzian-squared fit to the light-scattering angular distributions yields a characteristic wave number which does not change with temperature and an amplitude which shows a very strong dependence on the temperature.

Effective spectral function for quasielastic scattering on nuclei

Energy Technology Data Exchange (ETDEWEB)

Bodek, A.; Coopersmith, B. [University of Rochester, Department of Physics and Astronomy, Rochester, NY (United States); Christy, M.E. [Hampton University, Hampton, VA (United States)

2014-10-15

Spectral functions that are used in neutrino event, generators to model quasielastic (QE) scattering from nuclear targets include Fermi gas, Local Thomas Fermi gas (LTF), Bodek-Ritchie Fermi gas with high momentum tail, and the Benhar-Fantoni two dimensional spectral function. We find that the ν dependence of predictions of these spectral functions for the QE differential cross sections (d{sup 2}σ/dQ{sup 2}dν) are in disagreement with the prediction of the ψ' superscaling function which is extracted from fits to quasielastic electron scattering data on nuclear targets. It is known that spectral functions do not fully describe quasielastic scattering because they only model the initial state. Final state interactions distort the shape of the differential cross section at the peak and increase the cross section at the tails of the distribution. We show that the kinematic distributions predicted by the ψ' superscaling formalism can be well described with a modified effective spectral function (ESF). By construction, models using ESF in combination with the transverse enhancement contribution correctly predict electron QE scattering data. (orig.)

Effective spectral function for quasielastic scattering on nuclei

International Nuclear Information System (INIS)

Bodek, A.; Coopersmith, B.; Christy, M.E.

2014-01-01

Spectral functions that are used in neutrino event, generators to model quasielastic (QE) scattering from nuclear targets include Fermi gas, Local Thomas Fermi gas (LTF), Bodek-Ritchie Fermi gas with high momentum tail, and the Benhar-Fantoni two dimensional spectral function. We find that the ν dependence of predictions of these spectral functions for the QE differential cross sections (d 2 σ/dQ 2 dν) are in disagreement with the prediction of the ψ' superscaling function which is extracted from fits to quasielastic electron scattering data on nuclear targets. It is known that spectral functions do not fully describe quasielastic scattering because they only model the initial state. Final state interactions distort the shape of the differential cross section at the peak and increase the cross section at the tails of the distribution. We show that the kinematic distributions predicted by the ψ' superscaling formalism can be well described with a modified effective spectral function (ESF). By construction, models using ESF in combination with the transverse enhancement contribution correctly predict electron QE scattering data. (orig.)

A hybrid Scatter/Transform cloaking model

Directory of Open Access Journals (Sweden)

Gad Licht

2015-01-01

Full Text Available A new Scatter/Transform cloak is developed that combines the light bending of refraction characteristic of a Transform cloak with the scatter cancellation characteristic of a Scatter cloak. The hybrid cloak incorporates both Transform’s variable index of refraction with modified linear intrusions to maximize the Scatter cloak effect. Scatter/Transform improved the scattering cross-section of cloaking in a 2-dimensional space to 51.7% compared to only 39.6% or 45.1% respectively with either Scatter or Transform alone. Metamaterials developed with characteristics based on the new ST hybrid cloak will exhibit superior cloaking capabilities.

X-ray scattering for the characterization of lyophilized breast tissue samples

International Nuclear Information System (INIS)

Elshemey, Wael M.; Mohamed, Fayrouz S.; Khater, Ibrahim M.

2013-01-01

This work investigates the possibility of characterizing breast cancer by measuring the X-ray scattering profiles of lyophilized excised breast tissue samples. Since X-ray scattering from water-rich tissue is dominated by scattering from water, the removal of water by lyophilization would enhance the characterization process. In the present study, X-ray scattering profiles of 22 normal, 22 malignant and 10 benign breast tissue samples are measured. The cut-offs of scatter diagrams, sensitivity, specificity and diagnostic accuracy of three characterization parameters (full width at half maximum (FWHM) for the peak at 1.1 nm −1 , area under curve (AUC), and ratio of 1st to 2nd scattering peak intensities (I 1 /I 2 %)) are calculated and compared to the data from non-lyophilized samples. Results show increased sensitivity (up to 100%) of the present data on lyophilized breast tissue samples compared to previously reported data for non-lyophilized samples while the specificity (up to 95.4%), diagnostic accuracy (up to 95.4%) and receiver operating characteristic (ROC) curve values (up to 0.9979) for both sets of data are comparable. The present study shows significant differences between normal samples and each of malignant and benign samples. Only subtle differences exist between malignant and benign lyophilized breast tissue samples where FWHM=0.7±0.1 and 0.8±0.3, AUC=1.3±0.2 and 1.4±0.2 and I 1 /I 2 %=44.9±11.0 and 52.4±7.6 for malignant and benign samples respectively. - Highlights: • X-ray scattering profiles of breast tissue samples are acquired. • Three X-ray profile characterization parameters are calculated. • The cut-offs, sensitivity, specificity and diagnostic accuracy are calculated. • They are compared to the data from non-lyophilized samples. • Results show increased sensitivity in case of lyophilized samples

Study on the scattering law and scattering kernel of hydrogen in zirconium hydride

International Nuclear Information System (INIS)

Jiang Xinbiao; Chen Wei; Chen Da; Yin Banghua; Xie Zhongsheng

1999-01-01

The nuclear analytical model of calculating scattering law and scattering kernel for the uranium zirconium hybrid reactor is described. In the light of the acoustic and optic model of zirconium hydride, its frequency distribution function f(ω) is given and the scattering law of hydrogen in zirconium hydride is obtained by GASKET. The scattering kernel σ l (E 0 →E) of hydrogen bound in zirconium hydride is provided by the SMP code in the standard WIMS cross section library. Along with this library, WIMS is used to calculate the thermal neutron energy spectrum of fuel cell. The results are satisfied

Light scattering studies at UNICAMP

International Nuclear Information System (INIS)

Luzzi, R.; Cerdeira, H.A.; Salzberg, J.; Vasconcellos, A.R.; Frota Pessoa, S.; Reis, F.G. dos; Ferrari, C.A.; Algarte, C.A.S.; Tenan, M.A.

1975-01-01

Current theoretical studies on light scattering spectroscopy at UNICAMP is presented briefly, such as: inelastic scattering of radiation from a solid state plasma; resonant Ramman scattering; high excitation effects; saturated semiconductors and glasses

Coupled radiative transfer equation and diffusion approximation model for photon migration in turbid medium with low-scattering and non-scattering regions

International Nuclear Information System (INIS)

Tarvainen, Tanja; Vauhkonen, Marko; Kolehmainen, Ville; Arridge, Simon R; Kaipio, Jari P

2005-01-01

In this paper, a coupled radiative transfer equation and diffusion approximation model is extended for light propagation in turbid medium with low-scattering and non-scattering regions. The light propagation is modelled with the radiative transfer equation in sub-domains in which the assumptions of the diffusion approximation are not valid. The diffusion approximation is used elsewhere in the domain. The two equations are coupled through their boundary conditions and they are solved simultaneously using the finite element method. The streamline diffusion modification is used to avoid the ray-effect problem in the finite element solution of the radiative transfer equation. The proposed method is tested with simulations. The results of the coupled model are compared with the finite element solutions of the radiative transfer equation and the diffusion approximation and with results of Monte Carlo simulation. The results show that the coupled model can be used to describe photon migration in turbid medium with low-scattering and non-scattering regions more accurately than the conventional diffusion model

Scattering influence in mammographic image

International Nuclear Information System (INIS)

Poletti, Martin Eduardo; Almeida, Adelaide de

1996-01-01

The quantification of mammographic images affected by scattered radiation is studied. The average glandular dose as a function of kVp and breast thickness for breast composition 50/50% is also evaluated. The results show that the contrast decreases with increasing of kVp and breast thickness, and the average glandular dose increase with increasing breast thickness and decreases with increasing kVp

An Insight into the Interactions between a-Tocopherol and Chitosan in Ultrasound-Prepared Nanoparticles

International Nuclear Information System (INIS)

Naghibzadeh, M.; Amani, A.; Esmaeilzadeh, E.; Amini, M.; Mottaghi-Dastjerdi, N.; Faramarzi, M.A.; Faramarzi, M.A.

2010-01-01

The aim of this study was to investigate the interactions between a-tocopherol and chitosan molecules prepared subsequent to preparation of a-tocopherol-loaded chitosan nanoparticles using ultrasonication. Dynamic light scattering (DLS) and scanning electron microscopy (SEM) analyses showed semi spherical particles with an average size of approximately 350 nm. Also from reconstitution test, a-tocopherol was suggested as stabilizing agent during lyophilization/reconstitution process. The zeta potentials of chitosan and a-tocopherol nanoparticles were larger than ±30 mV, representing suitable stability. Data obtained from FTIR showed possibility of chemical interaction between chitosan and a-tocopherol. Furthermore, the results from FTIR, NMR, and XRD spectroscopy confirmed electrostatic interactions between the two molecules. Overall, this procedure could be considered as a facile method to prepare a-tocopherol-loaded nanoparticles.

Nanostructured oxygen sensor--using micelles to incorporate a hydrophobic platinum porphyrin.

Directory of Open Access Journals (Sweden)

Fengyu Su

Full Text Available Hydrophobic platinum(II-5,10,15,20-tetrakis-(2,3,4,5,6-pentafluorophenyl-porphyrin (PtTFPP was physically incorporated into micelles formed from poly(ε-caprolactone-block-poly(ethylene glycol to enable the application of PtTFPP in aqueous solution. Micelles were characterized using dynamic light scattering (DLS and atomic force microscopy (AFM to show an average diameter of about 140 nm. PtTFPP showed higher quantum efficiency in micellar solution than in tetrahydrofuran (THF and dichloromethane (CH₂Cl₂. PtTFPP in micelles also exhibited higher photostability than that of PtTFPP suspended in water. PtTFPP in micelles exhibited good oxygen sensitivity and response time. This study provided an efficient approach to enable the application of hydrophobic oxygen sensors in a biological environment.

Incoherent Thomson scattering

NARCIS (Netherlands)

Donne, A. J. H.

1996-01-01

Thomson scattering is a very powerful diagnostic which is applied at nearly every magnetic confinement device. Depending on the experimental conditions different plasma parameters can be diagnosed. When the wave vector is much larger than the plasma Debye length, the total scattered power is

Single Crystal Diffuse Neutron Scattering

Directory of Open Access Journals (Sweden)

Richard Welberry

2018-01-01

Full Text Available Diffuse neutron scattering has become a valuable tool for investigating local structure in materials ranging from organic molecular crystals containing only light atoms to piezo-ceramics that frequently contain heavy elements. Although neutron sources will never be able to compete with X-rays in terms of the available flux the special properties of neutrons, viz. the ability to explore inelastic scattering events, the fact that scattering lengths do not vary systematically with atomic number and their ability to scatter from magnetic moments, provides strong motivation for developing neutron diffuse scattering methods. In this paper, we compare three different instruments that have been used by us to collect neutron diffuse scattering data. Two of these are on a spallation source and one on a reactor source.

Non-eikonal effects in high-energy scattering IV. Inelastic scattering

International Nuclear Information System (INIS)

Gurvitz, S.A.; Kok, L.P.; Rinat, A.S.

1978-01-01

Amplitudes of inelastically scattered high-energy projections were calculated. In the scattering on 12 C(Tsub(P)=1 GeV) sizeable non-eikonal corrections in diffraction extrema even for relatively small q 2 are demonstrated. At least part of the anomaly in the 3 - distribution may be due to these non-eikonal effects. (B.G.)

A Discrete Scatterer Technique for Evaluating Electromagnetic Scattering from Trees

Science.gov (United States)

2016-09-01

Trees by DaHan Liao Approved for public release; distribution is unlimited. NOTICES Disclaimers The findings...for Evaluating Electromagnetic Scattering from Trees by DaHan Liao Sensors and Electron Devices Directorate, ARL...Technique for Evaluating Electromagnetic Scattering from Trees 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S

Scattering from black holes