Sensibility test for uranium ores from Qianjiadian sandstone type uranium deposit

International Nuclear Information System (INIS)

Zhang Mingyu

2005-01-01

Sensibility tests for uranium ores from Qianjiadian sandstone type uranium deposit in Songliao Basin which is suitable to in-situ leach are carried out, including water sensibility, velocity sensibility, salt sensibility, acid sensibility and alkaline sensibility. The sensibility critical value of this ore is determined. Some references on mining process and technical parameter are provided for in-situ leaching of uranium. (authors)

Water Vapor Diffusion and Adsorption of Sandstones: Influence of Rock Texture and Composition

Directory of Open Access Journals (Sweden)

Martin Keppert

2016-01-01

Full Text Available The term sandstone is used for wide range of rocks containing quartz clasts which can be cemented by secondary precipitated quartz or calcite; moreover the space between clasts can be filled by matrix. These facts result in existence of numerous rocks having highly various properties. Sandstones have been used as construction materials due to their good accessibility and workability. Since most of sandstones are porous, water vapor can penetrate through sandstone constructions. The rate of water vapor diffusion, as well as the vapor sorption isotherm, was determined for range of sandstone types. The diffusion resistance factor was found to be dependent on the total porosity of sandstone but the sorption behavior was strongly influenced by nature of the particular sandstone; the specific surface area of stone and presence of clay matrix are determining its sorption isotherm. The published data enable estimating (i diffusion resistance factor of a sandstone via knowledge of its total porosity and (ii the sorption isotherm via knowledge of the stone’s nature and specific surface area. This approach can significantly reduce the time necessary to acquire vapor-related properties of a sandstone.

Examples from the 1.6 Ga Chorhat Sandstone, Vindhyan

Indian Academy of Sciences (India)

This paper addresses macroscopic signatures of microbial mat-related structures within the 1.6 Ga-old Chorhat Sandstone of the Semri Group –the basal stratigraphic unit of the Vindhyan succession in Son valley.The Chorhat Sandstone broadly represents a prograding succession of three depositional facies ranging from ...

Assessment of marine and urban-industrial environments influence on built heritage sandstone using X-ray fluorescence spectroscopy and complementary techniques

Science.gov (United States)

Morillas, Héctor; García-Galan, Javier; Maguregui, Maite; Marcaida, Iker; García-Florentino, Cristina; Carrero, Jose Antonio; Madariaga, Juan Manuel

2016-09-01

The sandstone used in the construction of the tower of La Galea Fortress (Getxo, north of Spain) shows a very bad conservation state and a high percentage of sandstone has been lost. The fortress is located just on a cliff and close to the sea, and it experiments the direct influence of marine aerosol and also the impact of acid gases (SOx and NOx) coming from the surrounding industry and maritime traffic. This environment seems to be very harmful for the preservation of the sandstone used in it, promoting different pathologies (disintegration, alveolization, cracking or erosion blistering, salts crystallization on the pores, efflorescences etc.). In this work, a multianalytical methodology based on a preliminary in-situ screening of the affected sandstone using a handheld energy dispersive X-ray fluorescence spectrometer (HH-ED-XRF) and a subsequent characterization of extracted sample in the laboratory using elemental (μ-ED-XRF, Scanning Electron Microscope coupled to an X-Max Energy-Dispersive (SEM-EDS) and Inductively coupled plasma mass spectrometry (ICP-MS)) and molecular techniques (micro-Raman spectroscopy (μ-RS) and X-ray Diffraction (XRD)) was applied in order to characterize the original composition of this kind of stone and related deterioration products. With the whole methodology, it was possible to assess that the sandstone contain a notable percentage of calcite. The sulfation and nitration of this carbonate detected in the stone led to the dissolution process of the sandstone, promoting the observed material loss. Additionally, the presence of salts related with the influence of marine aerosol confirms that this kind of environment have influence on the conservation state of the sandstone building.

Distinguishing of uranium-bearing sandstone by the geochemical characteristics in northern Sichuan

International Nuclear Information System (INIS)

Wang Wangzhang; Zhang Zhufeng; Wang Yunliang; Sun Shuqin.

1994-01-01

Expounding geochemical characteristics of sandstone-type uranium deposits in northern Sichuan, the authors demonstrate the favourable and unfavourable conditions for enrichment of uranium on the basis of element abundances and ratios of U, Th and K measured by the gamma-ray spectroscopy surveying. The differences between uranium-bearing and non-uranium sandstones and between red sandstone (clay stone) and greenish sandstone can be determined by the gamma-ray spectroscopy (measuring U, Th and K) and XRF analysis (measuring As and Ba). Therefore, the prospecting of the sandstone-type uranium deposits in northern Sichuan can be concentrated in a certain range

Recent Atmospheric Deposition and its Effects on Sandstone Cliffs in Bohemian Switzerland National Park, Czech Republic

Czech Academy of Sciences Publication Activity Database

Vařilová, Z.; Navrátil, Tomáš; Dobešová, Irena

2011-01-01

Roč. 220, 1/4 (2011), s. 117-130 ISSN 0049-6979 Institutional research plan: CEZ:AV0Z30130516 Keywords : acid deposition * sandstone percolates * chemical weathering * salt efflorescence * Black Triangle * aluminum * sulfates Subject RIV: DD - Geochemistry Impact factor: 1.625, year: 2011

The Effects of NaCl Concentration and Confining Pressure on Mechanical and Acoustic Behaviors of Brine-Saturated Sandstone

Directory of Open Access Journals (Sweden)

Yan-Hua Huang

2018-02-01

Full Text Available To better understand the mechanical behavior of rock with brine saturation, conventional triaxial experiments were carried out on sandstone for a range of confining pressures (0–60 MPa and NaCl concentrations (0–30%. As the confining pressure and NaCl concentration increased, the triaxial compressive strength, crack damage threshold, Young’s modulus, cohesion, and internal friction angle all increased. Real-time ultrasonic wave and acoustic emission (AE techniques were used to obtain the relationship between acoustic behavior and stress level during the whole triaxial compression process. During the whole deformation process, the evolution of P-wave velocity and accumulated AE count could be divided into four phases. The microstructural characteristics of brine-saturated sandstone, before and after loading, indicated that the strength enhancement mechanism may be attributed to an increase in inter-particle friction resulting from salt crystallisation around the points of contact. The angle of friction increased by more than 86% at maximum NaCl concentration compared to that for distilled water. The NaCl deposition in the pore space resulted in nonlinear strength increases for the brine-saturated sandstone specimens with increasing salinity. The present study is expected to improve the knowledge of the strength and failure mechanisms of sedimentary rock in deep saline aquifers.

Determination of resistance to salt crystallization on natural stone measured with ultrasonic wave

DEFF Research Database (Denmark)

Alm, D.; Brix, S.; Kjærgaard, H. Howe

2008-01-01

and after salt exposure. Four different stones are investigated: the limestone Bateig Azul, the sandstone Oberkirchener, the limestone Perlatino, and the limestone Travertine. The procedure for the salt crystallization test is EN 12370 standard “Natural stone test methods – Determination of resistance...

Sandstone-type uranium deposits. Summary and conclusions

International Nuclear Information System (INIS)

Finch, W.I.

1985-01-01

The similarity of most of the deposits described in this report is striking even though they occur in sandstone host rocks ranging in age from Carboniferous to Tertiary and on every continent outside the polar regions. Geologic environments of the uranium deposits consist of distinctive sets of tectonic and sedimentary-depositional systems, all of which have some common threads of favorable geologic processes. In this summary paper it is hoped that this report has sharpened an understanding of the deposit's ''home environment'' that will aid future exploration for these resource-important sandstone-type uranium ores

Sandstone-type uranium deposits

International Nuclear Information System (INIS)

Finch, W.I.; Davis, J.F.

1985-01-01

World-class sandstone-type uranium deposits are defined as epigenetic concentrations of uranium minerals occurring as uneven impregnations and minor massive replacements primarily in fluvial, lacustrine, and deltaic sandstone formations. The main purpose of this introductory paper is to define, classify, and introduce to the general geologic setting for sandstone-type uranium deposits

Geologic characterization report for the Paradox Basin Study Region, Utah Study Areas. Volume 6. Salt Valley

International Nuclear Information System (INIS)

1984-12-01

Surface landforms in the Salt Valley Area are generally a function of the Salt Valley anticline and are characterized by parallel and subparallel cuestaform ridges and hogbacks and flat valley floors. The most prominent structure in the Area is the Salt Valley anticline. Erosion resulting from the Tertiary uplift of the Colorado Plateau led to salt dissolution and subsequent collapse along the crest of the anticline. Continued erosion removed the collapse material, forming an axial valley along the crest of the anticline. Paleozoic rocks beneath the salt bearing Paradox Formation consist of limestone, dolomite, sandstone, siltstone and shale. The salt beds of the Paradox Formation occur in distinct cycles separated by an interbed sequence of anhydrite, carbonate, and clastic rocks. The Paradox Formation is overlain by Pennsylvanian limestone; Permian sandstone; and Mesozoic sandstone, mudstone, conglomerate and shale. No earthquakes have been reported in the Area during the period of the historic record and contemporary seismicity appears to be diffusely distributed, of low level and small magnitude. The upper unit includes the Permian strata and upper Honaker Trail Formation. The current data base is insufficient to estimate ground-water flow rates and directions in this unit. The middle unit includes the evaporites in the Paradox Formation and no laterally extensive flow systems are apparent. The lower unit consists of the rocks below the Paradox Formation where permeabilities vary widely, and the apparent flow direction is toward the west. 108 refs., 39 figs., 9 tabs

Sandstone-type uranium deposits

International Nuclear Information System (INIS)

Austin, S.R.; D'Andrea, R.F. Jr.

1978-01-01

Three overall factors are necessary for formation of uranium deposits in sandstone: a source of uranium, host rocks capable of transmitting uranium-bearing solutions, and a precipitant. Possible sources of uranium in sandstone-type deposits include groundwaters emanating from granitic highlands, arkosic sediments, tuffaceous material within or overlying the host rocks, connate fluids, and overlying black shales. The first three sources are considered the most likely. Host rocks are generally immature sandstones deposited in alluvial-fan, intermontane-basin or marginal-marine environments, but uranium deposits do occur in well-winnowed barrier-bar or eolian sands. Host rocks for uranium deposits generally show coefficients of permeability on the order of 1 to 100 gal/day/ft 2 . Precipitants are normally agents capable of reducing uranium from the uranyl to the uranous state. The association of uranium with organic matter is unequivocal; H 2 S, a powerful reductant, may have been present at the time of formation of some deposits but may go unnoticed today. Vanadium can serve to preserve the tabular characteristics of some deposits in the near-surface environment, but is considered an unlikely primary precipitant for uranium. Uranium deposits in sandstone are divided into two overall types: peneconcordant deposits, which occur in locally reducing environments in otherwise oxidized sandstones; and roll-type deposits, which occur at the margin of an area where an oxidized groundwater has permeated an otherwise reduced sandstone. Uranium deposits are further broken down into four subclasses; these are described

Structure and ionic conductivity of block copolymer electrolytes over a wide salt concentration range

Science.gov (United States)

Chintapalli, Mahati; Le, Thao; Venkatesan, Naveen; Thelen, Jacob; Rojas, Adriana; Balsara, Nitash

Block copolymer electrolytes are promising materials for safe, long-lasting lithium batteries because of their favorable mechanical and ion transport properties. The morphology, phase behavior, and ionic conductivity of a block copolymer electrolyte, SEO mixed with LiTFSI was studied over a wide, previously unexplored salt concentration range using small angle X-ray scattering, differential scanning calorimetry and ac impedance spectroscopy, respectively. SEO exhibits a maximum in ionic conductivity at twice the salt concentration that PEO, the homopolymer analog of the ion-containing block, does. This finding is contrary to prior studies that examined a more limited range of salt concentrations. In SEO, the phase behavior of the PEO block and LiTFSI closely resembles the phase behavior of homopolymer PEO and LiTFSI. The grain size of the block copolymer morphology was found to decrease with increasing salt concentration, and the ionic conductivity of SEO correlates with decreasing grain size. Structural effects impact the ionic conductivity-salt concentration relationship in block copolymer electrolytes. SEO: polystyrene-block-poly(ethylene oxide); also PS-PEO LiTFSI: lithium bis(trifluoromethanesulfonyl imide

Wind-blown sandstones cemented by sulfate and clay minerals in Gale Crater, Mars

Science.gov (United States)

Milliken, R. E.; Ewing, R. C.; Fischer, W. W.; Hurowitz, J.

2014-02-01

Gale Crater contains Mount Sharp, a ~5 km thick stratigraphic record of Mars' early environmental history. The strata comprising Mount Sharp are believed to be sedimentary in origin, but the specific depositional environments recorded by the rocks remain speculative. We present orbital evidence for the occurrence of eolian sandstones within Gale Crater and the lower reaches of Mount Sharp, including preservation of wind-blown sand dune topography in sedimentary strata—a phenomenon that is rare on Earth and typically associated with stabilization, rapid sedimentation, transgression, and submergence of the land surface. The preserved bedforms in Gale are associated with clay minerals and elsewhere accompanied by typical dune cross stratification marked by bounding surfaces whose lateral equivalents contain sulfate salts. These observations extend the range of possible habitable environments that may be recorded within Gale Crater and provide hypotheses that can be tested in situ by the Curiosity rover payload.

Microspatial ecotone dynamics at a shifting range limit: plant-soil variation across salt marsh-mangrove interfaces.

Science.gov (United States)

Yando, E S; Osland, M J; Hester, M W

2018-05-01

Ecotone dynamics and shifting range limits can be used to advance our understanding of the ecological implications of future range expansions in response to climate change. In the northern Gulf of Mexico, the salt marsh-mangrove ecotone is an area where range limits and ecotone dynamics can be studied in tandem as recent decreases in winter temperature extremes have allowed for mangrove expansion at the expense of salt marsh. In this study, we assessed aboveground and belowground plant-soil dynamics across the salt marsh-mangrove ecotone quantifying micro-spatial patterns in horizontal extent. Specifically, we studied vegetation and rooting dynamics of large and small trees, the impact of salt marshes (e.g. species and structure) on mangroves, and the influence of vegetation on soil properties along transects from underneath the mangrove canopy into the surrounding salt marsh. Vegetation and rooting dynamics differed in horizontal reach, and there was a positive relationship between mangrove tree height and rooting extent. We found that the horizontal expansion of mangrove roots into salt marsh extended up to eight meters beyond the aboveground boundary. Variation in vegetation structure and local hydrology appear to control mangrove seedling dynamics. Finally, soil carbon density and organic matter did not differ within locations across the salt marsh-mangrove interface. By studying aboveground and belowground variation across the ecotone, we can better predict the ecological effects of continued range expansion in response to climate change.

Microspatial ecotone dynamics at a shifting range limit: plant–soil variation across salt marsh–mangrove interfaces

Science.gov (United States)

Yando, Erik S.; Osland, Michael J.; Hester, Mark H.

2018-01-01

Ecotone dynamics and shifting range limits can be used to advance our understanding of the ecological implications of future range expansions in response to climate change. In the northern Gulf of Mexico, the salt marsh–mangrove ecotone is an area where range limits and ecotone dynamics can be studied in tandem as recent decreases in winter temperature extremes have allowed for mangrove expansion at the expense of salt marsh. In this study, we assessed aboveground and belowground plant–soil dynamics across the salt marsh–mangrove ecotone quantifying micro-spatial patterns in horizontal extent. Specifically, we studied vegetation and rooting dynamics of large and small trees, the impact of salt marshes (e.g. species and structure) on mangroves, and the influence of vegetation on soil properties along transects from underneath the mangrove canopy into the surrounding salt marsh. Vegetation and rooting dynamics differed in horizontal reach, and there was a positive relationship between mangrove tree height and rooting extent. We found that the horizontal expansion of mangrove roots into salt marsh extended up to eight meters beyond the aboveground boundary. Variation in vegetation structure and local hydrology appear to control mangrove seedling dynamics. Finally, soil carbon density and organic matter did not differ within locations across the salt marsh-mangrove interface. By studying aboveground and belowground variation across the ecotone, we can better predict the ecological effects of continued range expansion in response to climate change.

Influence of the properties of granite and sandstone in the desalination process by electrokinetic technique

DEFF Research Database (Denmark)

Feijoo, J.; Ottosen, Lisbeth M.; Pozo-Antonio, J.S.

2015-01-01

) achieved in both stones.From the results obtained, it was possible to find those inherent factors to each stone which could have an influence on the efficacy of the treatment. With this technique it was possible to reduce the salt concentration in the granite almost to 100%. However, in the sandstone...... samples the decreases were not equally high, mainly at the intermediate levels where slight enrichments were observed. The results indicate that although the used technique is efficient for salt removal regardless of the porosimetric distribution of the rock, the better interconnection between the pores...... in the granite samples (favored a faster desalination process)....

Chapter 2. Assessment of undiscovered conventional oil and gas resources--Upper Jurassic-Lower Cretaceous Cotton Valley group, Jurassic Smackover interior salt basins total petroleum system, in the East Texas basin and Louisiana-Mississippi salt basins provinces.

Science.gov (United States)

Dyman, T.S.; Condon, S.M.

2006-01-01

The Jurassic Smackover Interior Salt Basins Total Petroleum System is defined for this assessment to include (1) Upper Jurassic Smackover Formation carbonates and calcareous shales and (2) Upper Jurassic and Lower Cretaceous Cotton Valley Group organic-rich shales. The Jurassic Smackover Interior Salt Basins Total Petroleum System includes four conventional Cotton Valley assessment units: Cotton Valley Blanket Sandstone Gas (AU 50490201), Cotton Valley Massive Sandstone Gas (AU 50490202), Cotton Valley Updip Oil and Gas (AU 50490203), and Cotton Valley Hypothetical Updip Oil (AU 50490204). Together, these four assessment units are estimated to contain a mean undiscovered conventional resource of 29.81 million barrels of oil, 605.03 billion cubic feet of gas, and 19.00 million barrels of natural gas liquids. The Cotton Valley Group represents the first major influx of clastic sediment into the ancestral Gulf of Mexico. Major depocenters were located in south-central Mississippi, along the Louisiana-Mississippi border, and in northeast Texas. Reservoir properties and production characteristics were used to identify two Cotton Valley Group sandstone trends across northern Louisiana and east Texas: a high-permeability blanket-sandstone trend and a downdip, low-permeability massive-sandstone trend. Pressure gradients throughout most of both trends are normal, which is characteristic of conventional rather than continuous basin-center gas accumulations. Indications that accumulations in this trend are conventional rather than continuous include (1) gas-water contacts in at least seven fields across the blanket-sandstone trend, (2) relatively high reservoir permeabilities, and (3) high gas-production rates without fracture stimulation. Permeability is sufficiently low in the massive-sandstone trend that gas-water transition zones are vertically extensive and gas-water contacts are poorly defined. The interpreted presence of gas-water contacts within the Cotton Valley

Relationship between characteristics of fan-delta sandstone bodies and in-situ leachable sandstone-type uranium mineralization

International Nuclear Information System (INIS)

Nie Fengjun; Zhou Weixun; Guan Taiyang; Li Sitian

2000-01-01

Like normal deltas, fan-deltas are composed of three parts, i.e., fan-delta plain, fan-delta front and pre-fin-delta, In-situ leachable uranium deposits are commonly distributed along the margins of in-land basins. The author analyzes the possible relationship between the basic characteristics of fan-delta sandstone bodies and uranium mineralization. Two examples, e.g., the fan delta depositional systems in the eastern part of Jungger basin and the southern part of Yili basin, are given to illustrate the fan-delta vertical sequence and planar distribution of sedimentary facies. It has been pointed out that the braided channel sandstone bodies on delta plain, sub-aqueous distributional channel sandstone bodies and delta front sandstone bodies may be the favourable host rocks for in-situ leachable sandstone uranium deposits

Cathodoluminescence characteristics of sandstone and the implications for sandstone type No. 512 uranium deposit

International Nuclear Information System (INIS)

Liu Xiaodong; Guan Taiyang

1998-12-01

Cathodoluminescence (CL) technique, as a special petrologic tool, has been applied to the studies of uranium hosted sandstone from No. 512 uranium deposit located in Xinjiang Autonomous Region, Northwest China. The detrital grains including quartz, feldspar, debris and cements display distinguishing CL properties. The quartz grains mainly demonstrate brown and dark blue CL, feldspar grains demonstrate blue and bright blue CL, calcite cement displays bright yellow-orange and orange-red CL with significant CL zoning, while the debris, mud and sand cements have dark red CL, multicolor CL or non-luminescence. The characteristics of overgrowth, fracture healing, and the original contact relations of detrital grains appear much more significant with CL than that with conventional visual methods. Much more information can be contributed by CL technique to decipher the provenance area, to explain the cementation, consolidation and other diagenesis processes of sandstone. The CL technique also provides and efficient tool for identifying detrital grains and cements, and for more precisely estimating the proportions of various detrital grains and cement components in sandstone. The CL emission of uranium hosted sandstone revealed the existence of radiation-damage rims of quartz grains at the places with a little or no uranium minerals nearby, which may imply a uranium-leaching episode during the diagenesis of sandstone

The salt stock of the Jura bassin in Ostholstein. A seismologic re-interpretation; Der Salzstock des ostholsteinischen Juratroges. Eine seismische Re-Interpretation

Energy Technology Data Exchange (ETDEWEB)

Brink, H.J.; Baykulov, M.; Gajewski, D.; Yoon, Mi-Kyung [Hamburg Univ. (Germany). Inst. fuer Geophysik

2008-10-23

The developing age of the Permian salt stocks in Schleswig-Holstein (Federal Republic of Germany) reaches from the Trias over the Jura up to the Tertiary period. In the context of the DGMK project 577-1, the reflection-rich salt dome in the East Holstein Jura was investigated seismically by means of the CRS method and speed tomography. These measurements enable the interpretation of a structural style with a substantial tectonically compressive component. Magnetotelluric measurements point to potential natural gas source rocks. The drift of the Permian salt contributes to the contact support of new red sandstone on the pre-salinar layers. Migration ways are opened which contributed to a filling of structurally high new red sandstone reservoirs in small depths.

Clay squirt: Local flow dispersion in shale-bearing sandstones

DEFF Research Database (Denmark)

Sørensen, Morten Kanne; Fabricius, Ida Lykke

2017-01-01

Dispersion of elastic-wave velocity is common in sandstone and larger in shaly sandstone than in clean sandstone. Dispersion in fluid-saturated shaly sandstone often exceeds the level expected from the stress-dependent elastic moduli of dry sandstone. The large dispersion has been coined clay...... squirt and is proposed to originate from a pressure gradient between the clay microporosity and the effective porosity. We have formulated a simple model that quantifies the clay-squirt effect on bulk moduli of sandstone with homogeneously distributed shale laminae or dispersed shale. The model...... predictions were compared with the literature data. For sandstones with dispersed shale, agreement was found, whereas other sandstones have larger fluid-saturated bulk modulus, possibly due to partially load-bearing shales or heterogeneous shale distribution. The data that agree with the clay-squirt model...

Experimental strain analysis of Clarens Sandstone colonised by endolithic lichens

Directory of Open Access Journals (Sweden)

D. Wessels

1995-08-01

Full Text Available Endolithic lichens occur commonly on Clarens Sandstone in South Africa, where they significantly contribute to the weathering of sandstone by means of mechanical and chemical weathering processes. This preliminary investigation reports on the success- ful use of strain gauges in detecting strain differences between sandstone without epilithic lichens and sandstone colonised by the euendolithic lichen Lecidea aff. sarcogynoides Korb. Mechanical weathering, expressed as strain changes, in Clarens Sandstone was studied during the transition from relatively dry winter to wet summer conditions. Daily weathering of sandstone due to thermal expansion and contraction of colonised and uncolonised sandstone could be shown. Our results show that liquid water in sandstone enhances the mechanical weathering of uncolonised Clarens Sandstone while water in the gaseous phase enhances mechanical weathering of sandstone by euendolithic lichens.

Geothermal characteristics of Buntsandstein sandstone reservoir of Alsace

International Nuclear Information System (INIS)

Haffen, Sebastien

2012-01-01

The Buntsandstein, located in the Upper Rhine Graben, appears to be an easy target for geothermal exploitation, linking sandstone and clay with the regional thermal anomaly. This study aims at characterizing petrophysical characteristics of these sandstones as well as the fracturing affecting them, with the intention of providing a conceptual model of the formation which will act as guide for future exploitation. The sedimentary facies are composed by five petrographical facies (clean sandstones, sandstones with clayey coating, clay matrix sandstones, silicified sandstones and carbonated matrix sandstones) which split with variable proportions and control a part of petrophysical properties measured at matrix scale. The comparison between petrophysical data, macroscopic data from temperature gradient analysis, modelling data and fracturing, allows the building of a Buntsandstein Sandstones fluids circulation conceptual model. This analysis points the role of the damage zone of fault zones for fluids transfer at large scale, but also that of two sedimentary facies: marginal erg and Playa Lake. The analysis of different outcrops shows that the fracturing evolves according to the situation in the sedimentary pile and according to the situation in comparison with major tectonic accidents. (author) [fr

Hydrogeology of the Potsdam Sandstone in northern New York

Science.gov (United States)

Williams, John H.; Reynolds, Richard J.; Franzi, David A.; Romanowicz, Edwin A.; Paillet, Frederick L.

2010-01-01

The Potsdam Sandstone of Cambrian age forms a transboundary aquifer that extends across northern New York and into southern Quebec. The Potsdam Sandstone is a gently dipping sequence of arkose, subarkose, and orthoquartzite that unconformably overlies Precambrian metamorphic bedrock. The Potsdam irregularly grades upward over a thickness of 450 m from a heterogeneous feldspathic and argillaceous rock to a homogeneous, quartz-rich and matrix-poor rock. The hydrogeological framework of the Potsdam Sandstone was investigated through an analysis of records from 1,500 wells and geophysical logs from 40 wells, and through compilation of GIS coverages of bedrock and surficial geology, examination of bedrock cores, and construction of hydrogeological sections. The upper several metres of the sandstone typically is weathered and fractured and, where saturated, readily transmits groundwater. Bedding-related fractures in the sandstone commonly form sub-horizontal flow zones of relatively high transmissivity. The vertical distribution of sub-horizontal flow zones is variable; spacings of less than 10 m are common. Transmissivity of individual flow zones may be more than 100 m2/d but typically is less than 10 m2/d. High angle fractures, including joints and faults, locally provide vertical hydraulic connection between flow zones. Hydraulic head gradients in the aquifer commonly are downward; a laterally extensive series of sub-horizontal flow zones serve as drains for the groundwater flow system. Vertical hydraulic head differences between shallow and deep flow zones range from 1 m to more than 20 m. The maximum head differences are in recharge areas upgradient from the area where the Chateauguay and Chazy Rivers, and their tributaries, have cut into till and bedrock. Till overlies the sandstone in much of the study area; its thickness is generally greatest in the western part, where it may exceed 50 m. A discontinuous belt of bedrock pavements stripped of glacial drift extends

Carbon 13 and oxygen 18 isotope record of the early eocene nammal formation, salt range, pakistan

International Nuclear Information System (INIS)

Ghazi, S.; Sajid, Z.

2014-01-01

The Nammal Formation is the lowermost unit of the Early Eocene succession in the Salt Range, Pakistan. It is well exposed throughout the Salt Range. The Nammal Formation having 30 to 35 meters thickness is predominantly composed of nodular limestone interbedded with marl and shale. The present study was focussed on stable carbon 13 and oxygen 18 isotopic analysis based on data from two stratigraphically important sections. The samples from the Nilawahan section provided with the delta 13C values varied between 1.34 to -1.56 (VPDB) and values of delta 18O fluctuated between -4.47 to -6.59 (VPDB). Likewise the sample analysis of BadshahPur section exhibited that the delta 13C values changes from 1.09 to -1.65 (VPDB) and delta 18O values range from -4.17 to -6.85 (VPDB). The isotopic records of carbon 13 and oxygen 18 indicated the shallow marine deposition of the Nammal Formation under tropical conditions. It highlighted the palaeo climatic and diagenetic conditions of the Nammal Formation at the time of deposition in the Salt Range region. (author)

Sedimentological reservoir characteristics of the Paleocene fluvial/lacustrine Yabus Sandstone, Melut Basin, Sudan

Science.gov (United States)

Mahgoub, M. I.; Padmanabhan, E.; Abdullatif, O. M.

2016-11-01

Melut Basin in Sudan is regionally linked to the Mesozoic-Cenozoic Central and Western African Rift System (CWARS). The Paleocene Yabus Formation is the main oil producing reservoir in the basin. It is dominated by channel sandstone and shales deposited in fluvial/lacustrine environment during the third phase of rifting in the basin. Different scales of sedimentological heterogeneities influenced reservoir quality and architecture. The cores and well logs analyses revealed seven lithofacies representing fluvial, deltaic and lacustrine depositional environments. The sandstone is medium to coarse-grained, poorly to moderately-sorted and sub-angular to sub-rounded, arkosic-subarkosic to sublitharenite. On the basin scale, the Yabus Formation showed variation in sandstone bodies, thickness, geometry and architecture. On macro-scale, reservoir quality varies vertically and laterally within Yabus Sandstone where it shows progressive fining upward tendencies with different degrees of connectivity. The lower part of the reservoir showed well-connected and amalgamated sandstone bodies, the middle to the upper parts, however, have moderate to low sandstone bodies' connectivity and amalgamation. On micro-scale, sandstone reservoir quality is directly affected by textures and diagenetic changes such as compaction, cementation, alteration, dissolution and kaolinite clays pore fill and coat all have significantly reduced the reservoir porosity and permeability. The estimated porosity in Yabus Formation ranges from 2 to 20% with an average of 12%; while permeability varies from 200 to 500 mD and up to 1 Darcy. The understanding of different scales of sedimentological reservoir heterogeneities might contribute to better reservoir quality prediction, architecture, consequently enhancing development and productivity.

Low field NMR surface relaxivity studies of chalk and argillaceous sandstones

DEFF Research Database (Denmark)

Katika, Konstantina; Fordsmand, Henrik; Fabricius, Ida Lykke

2017-01-01

the accuracy of predictions of petrophysical properties of various rocks with the use of NMR spectrometry. We perform laboratory transverse relaxation (T2) measurements on water saturated Gorm field chalk, Stevns Klint chalk, Solsort field greensand and Berea sandstone. These rocks are of particular interest...... field chalk and Solsort field greensand have higher ρ at higher Larmor frequency. By contrast, ρ of the purely calcitic Stevns chalk and quartzitic Berea sandstone proved not to be affected by the changes in frequency. T2 distributions at temperatures ranging from 10 °C to 60 °C provided comparison...

Electrical Spectroscopy of Permo-Triassic Sandstone From the United Kingdom

Science.gov (United States)

Scott, J.; Barker, R.

2003-12-01

Electrical spectroscopy measurements in the range of mHz to kHz have been made on the dominantly red Permo-Triassic sandstone from the United Kingdom. Samples have been selected from borehole cores from all of the main outcrop areas of sandstone and represent a wide variety of lithologies. This sandstone is an important aquifer for several major cities including Manchester and Birmingham. The samples have been fully saturated with sodium chloride brines and a synthetic groundwater solution that is higher in calcium and magnesium ions than sodium and which closely matches the cation concentrations of the groundwater at Birmingham. Electrical measurements were made using a four-electrode arrangement of silver-silver chloride electrodes. Most of the electrical spectra show a clear, slightly asymmetric, electrical relaxation phenomenon with relaxation peaks in the range of 0.001 Hz to 20 Hz. These relaxation phenomena can be fitted very well by a generalised Cole-Cole model. The relaxation time from this model is found to correlate closely with the dominant pore-throat size from mercury injection. Normalising the chargeability, Cole-Cole m parameter, by the conductivity gives a polarisation magnitude which correlates well with the pore surface to volume ratio (SPOR) for sandstone samples with an even distribution of surface coating clays. The information obtained from the electrical spectra is very useful. The pore-throat size is important in controlling the permeability and in particular the flow of non-aqueous phase fluids. The pore surface area has links to the sorbtion properties of the rock, which are important in estimating contaminant transport. The electrical spectra also provide a useful fingerprint of individual lithologies which could be used for correlation between boreholes or outcrops.

The Paleozoic-Mesozoic recycling of the Rakaia Terrane, South Island, New Zealand : sandstone clast and sandstone petrology, geochemistry, and geochronology

International Nuclear Information System (INIS)

Wandres, A.M.; Bradshaw, J.D.; Ireland, T.

2005-01-01

The Torlesse terranes - part of the New Zealand Eastern Province - are accretionary complexes that comprise an enormous volume of quartzofeldspathic sandstones and mudstones with subsidiary conglomerates plus minor oceanic assemblages. Two terranes are recognised in the South Island - the Permian to Late Triassic Rakaia Terrane and the Late Jurassic to Early Cretaceous Pahau Terrane. Sandstone clasts from two Rakaia Terrane and two Pahau Terrane conglomerates were collected. We present the first combined detailed information on petrography and geochemistry of Torlesse conglomerate sandstone clasts and use our own and published U-Pb SHRIMP detrital zircon age data to demonstrate the recycling of the Rakaia Terrane into Rakaia strata itself and into Pahau Terrane strata. Sandstone clast major and trace element chemical data largely support petrographic observations derived from thin-section analysis. The similarities of petrographic and geochemical data between sandstone clasts from the Rakaia Terrane and Rakaia sandstones suggest that clasts in the Permian Te Moana and Late Triassic Lake Hill Conglomerates were derived by autocannibalistic reworking of older, consolidated, Rakaia sediments. Data from sandstone clasts from the Pahau Terrane suggest that uplift of the Rakaia Terrane continued into the Cretaceous. These Pahau Terrane clasts indicate that at the time of the Pahau sedimentation Permian to early Late Triassic Rakaia rocks were exposed and recycled into the Pahau Basin. (author). 57 refs., 8 figs., 3 tables

) Sediment petrographic characterisation and diagenetic pathways of the Miocene Agbada sandstone, Niger delta

International Nuclear Information System (INIS)

Akaegbobi, I. M; Gaupp, R.; Fischer, C.

2003-01-01

Combined petrophysical and petrographic investigations of he Agbada sandstone interbeds has been undertaken in order to determine the controlling factors on the reservoir quality of he paralic sandstone facies. Well logs, petrophysical data and a set of core samples from two wells located in the eastern onshore of he Niger delta spanning a depth interval of 3200 to 330m, formed the basic material for the present study. Four sandstone and siltstone facies units ranging form coastal bar sands through transgressive sands to marine claystones were identified based on petrophysical log signatures. Thin section analysis of a selected set of sandstone samples revealed essentially a unimodal, homogeneous grain size distribution of the detrital mineral components. Quantitative assessment of the mineralogical composition using point count method (300 points) revealed the predominance of dring. etrital quartz (85%) over feldspar minerals (9%) and lithic fragments (6%). A database generated from the point counting of the sandstones provided a broad perspective to the relative variations of the intergranular porosities (28%), cementation and matrix. These are remarkable indicators for low compaction. Authigenic kaoline and illite were identified. The partial leaching of detrital feldspars are responsible for the low percentages of intragranular volume (secondary porosity). The main controlling factor on the high porosity can be traced to either low compactional effects (overpressure?) or total leaching of unknown early cements. We suggest that the excellent reservoir properties of the Agbada sandstones are due to under compaction, caused by continuous long-term over pressuring

The Upper Permian sandstones of Mountains Mecsek: form elements of uranium ore mineralization and facies relations Pt. 2

International Nuclear Information System (INIS)

Vincze, Janos; Somogyi, Janos

1984-01-01

The ore mineralization in the Upper Permian sandstones of Mountais Mecsek, Hungary, was brought about at the oxidation-reduction front between the grey and red sandstones; the predominant rock colour here is green. The sandstones of different colour are oxidation-reduction species. The formation is a megacycle containing in its core grey sandstones of reduced state with coalified plant remains and in its mantle oxidized red sandstones. Uranium accumulates mainly in the transitional green facies. Uranium content gets enriched to a commercial concentration only if the difference in potential of neighbouring beds is in the range of 400-480 mV. The relationship between organic matter and uranium content in the individual facies is shown. The principles of oxidation-reduction processes in the formation of boundary facies are discussed. (V.N.)

Elastic Dispersion and Attenuation in Fully Saturated Sandstones: Role of Mineral Content, Porosity, and Pressures

Science.gov (United States)

Pimienta, Lucas; Borgomano, Jan V. M.; Fortin, Jérôme; Guéguen, Yves

2017-12-01

Because measuring the frequency dependence of elastic properties in the laboratory is a technical challenge, not enough experimental data exist to test the existing theories. We report measurements of three fluid-saturated sandstones over a broad frequency band: Wilkenson, Berea, and Bentheim sandstones. Those sandstones samples, chosen for their variable porosities and mineral content, are saturated by fluids of varying viscosities. The samples elastic response (Young's modulus and Poisson's ratio) and hydraulic response (fluid flow out of the sample) are measured as a function of frequency. Large dispersion and attenuation phenomena are observed over the investigated frequency range. For all samples, the variation at lowest frequency relates to a large fluid flow directly measured out of the rock samples. These are the cause (i.e., fluid flow) and consequence (i.e., dispersion/attenuation) of the transition between drained and undrained regimes. Consistently, the characteristic frequency correlates with permeability for each sandstone. Beyond this frequency, a second variation is observed for all samples, but the rocks behave differently. For Berea sandstone, an onset of dispersion/attenuation is expected from both Young's modulus and Poisson's ratio at highest frequency. For Bentheim and Wilkenson sandstones, however, only Young's modulus shows dispersion/attenuation phenomena. For Wilkenson sandstone, the viscoelastic-like dispersion/attenuation response is interpreted as squirt flow. For Bentheim sandstone, the second effect does not fully follow such response, which could be due to a lower accuracy in the measured attenuation or to the occurence of another physical effect in this rock sample.

Sandstone Turning by Abrasive Waterjet

Czech Academy of Sciences Publication Activity Database

Hlaváček, Petr; Cárach, J.; Hloch, Sergej; Vasilko, K.; Klichová, Dagmar; Klich, Jiří; Lehocká, D.

2015-01-01

Roč. 48, č. 6 (2015), s. 2489-2493 ISSN 0723-2632 R&D Projects: GA MŠk ED2.1.00/03.0082; GA MŠk(CZ) LO1406 Institutional support: RVO:68145535 Keywords : turning away from the jet * conventional turning towards the jet * sandstone * abrasive water jet Subject RIV: JQ - Machines ; Tools Impact factor: 2.386, year: 2015 http://www.springerprofessional.de/sandstone-turning-by-abrasive-waterjet/6038028.html

Regional distribution regularity of sandstone uranium deposits in Asian continent and prospecting strategy for sandstone uranium deposits in China

International Nuclear Information System (INIS)

Chen Zuyi

2002-01-01

Since the 1980's, after the discovery of numerous sandstone uranium deposits in Middle Asia (Kazakhstan, Uzbekistan) many large sandstone uranium deposits have been found in both Russia and Mongolia. So that Asia has become the most concentrated region of sandstone uranium deposits. The known sandstone uranium deposits occur mostly in a arcual tectonic belt constrained from the north by the Siberian continental block, and the Tarim-North China continental block from the south. This belt is named by Russian geologists as the Central Asian Mobile Belt, and some Chinese geologists call it the 'Mongolian Arc'. A lot of large and super large metallic, non-metallic, gold, polymetallic, porphyry copper and gold, massive sulphide and uranium deposits (of sandstone and volcanic types) with different origin and various types concentrated occur in this belt. The abundant and colourful mineral resources in the region are closely associated with the specific geologic-tectonic evolution of the above belt. It is necessary to strengthen the detailed geologic research and uranium prospecting in the region

Petrographic study of core plugs from lower goru sandstones

International Nuclear Information System (INIS)

Memon, M.K.; Tunio, A.; Leghari, A.

2008-01-01

Petrographic rock type description is a fundamental component in the reservoir description processes and typically included measurement to identify sediment source, texture, composition and mineralogy. Petroleum workers have long used the Petrographic microscope as an in put device to aid in the study of pore systems. Standard Petrographic thin sections are typically 30 micrometers thick and are usually illuminated by transmitted light. Experienced examiners have trained themselves to see information such as pore size, mineralogy, compaction, etc by disregarding artifacts produced by passing light through a section. This method is adequate for qualitative interpretation of data from thin sections. Rocks in thin section under a microscope display great complexity in pore sizes and shapes. Petrographic study provides measurement on rock texture. Texture deals with the size, shape and arrangement of the component minerals of a rock. It is essentially the micro geometry of the rock. Permeability of collected core plugs of lower Goru sandstones was measured. From this Petrographic study we have identified as the sandstone of Lower Goru constitute almost entirely of quartz. The grains range in size from very fine to medium, moderately well sorted to well sorted and rounded to sub rounded in shape. Particularly attention was paid to mineral content present in Lower Goru Sandstone. The mineral composition from these core plugs of Lower Goru Sandstone as identified contain about 70-80% Quartz with traces of feldspar, muscovite, biotite, Epidote and hornblende. Calcite was present as cementing material and it was about 15 -30% of the total rock. (author)

Ferroan dolomite cement in Cambrian sandstones: burial history and hydrocarbon generation of the Baltic sedimentary basin

DEFF Research Database (Denmark)

Sliaupa, S.; Cyziene, J.; Molenaar, Nicolaas

2008-01-01

The conditions and timing of carbonate cementation in Cambrian sandstones of the Baltic sedimentary basin were determined by oxygen and carbon stable isotope and chemical data in combination with optical and cathodoluminescence petrographic studies. Studied samples represent a range in present...... burial depth from 340 to 2150 m. The carbonate cement is dominantly ferroan dolomite that occurs as dispersed patches of poikilotopic crystals. Temperatures of dolomite precipitation, based on delta O-18 values, range from 27 degrees C in the shallow buried to 95 degrees C in the deep buried sandstones...

Discussion on the origin of bleached sandstone of Qianjiadian uranium deposit

International Nuclear Information System (INIS)

Pang Yaqing; Xiang Weidong; Li Tiangang; Chen Xiaolin; Xia Yuliang

2007-01-01

Qianjiadian uranium deposit is a sandstone-type uranium deposit that has been discovered in Songliao Basin in recent years. Uranium ore bodies are planar or lenticular in shape and under the control of the contact between gray sandstones and bleached sandstones. The bleached sandstone is white in color, cemented loosely, nearly without TOC and pyrite contained and rich in uranium. Geochemical characteristics and types and assemblages of clay minerals of the bleached sandstone reveal that the bleached sandstone is the product of oxidation of the interlayer oxidation zone, and it is a part of the interlayer oxidation zone. The main reasons for white color of the bleached sandstone are transfer of iron ion, oxidation of TOC and kaolinization of sandstone. (authors)

Electrofacies vs. lithofacies sandstone reservoir characterization Campanian sequence, Arshad gas/oil field, Central Sirt Basin, Libya

Science.gov (United States)

Burki, Milad; Darwish, Mohamed

2017-06-01

The present study focuses on the vertically stacked sandstones of the Arshad Sandstone in Arshad gas/oil field, Central Sirt Basin, Libya, and is based on the conventional cores analysis and wireline log interpretation. Six lithofacies types (F1 to F6) were identified based on the lithology, sedimentary structures and biogenic features, and are supported by wireline log calibration. From which four types (F1-F4) represent the main Campanian sandstone reservoirs in the Arshad gas/oil field. Lithofacies F5 is the basal conglomerates at the lower part of the Arshad sandstones. The Paleozoic Gargaf Formation is represented by lithofacies F6 which is the source provenance for the above lithofacies types. Arshad sediments are interpreted to be deposited in shallow marginal and nearshore marine environment influenced by waves and storms representing interactive shelf to fluvio-marine conditions. The main seal rocks are the Campanian Sirte shale deposited in a major flooding events during sea level rise. It is contended that the syn-depositional tectonics controlled the distribution of the reservoir facies in time and space. In addition, the post-depositional changes controlled the reservoir quality and performance. Petrophysical interpretation from the porosity log values were confirmed by the conventional core measurements of the different sandstone lithofacies types. Porosity ranges from 5 to 20% and permeability is between 0 and 20 mD. Petrophysical cut-off summary of the lower part of the clastic dominated sequence (i. e. Arshad Sandstone) calculated from six wells includes net pay sand ranging from 19.5‧ to 202.05‧, average porosity from 7.7 to 15% and water saturation from 19 to 58%.

Permeability in Rotliegend gas sandstones to gas and brine as predicted from NMR, mercury injection and image analysis

DEFF Research Database (Denmark)

Rosenbrand, Esther; Fabricius, Ida Lykke; Fisher, Quentin

2015-01-01

Permeability characterisation of low permeability, clay-rich gas sandstones is part of production forecasting and reservoir management. The physically based Kozeny (1927) equation linking permeability with porosity and pore size is derived for a porous medium with a homogeneous pore size, whereas...... the pore sizes in tight sandstones can range from nm to μm. Nuclear magnetic resonance (NMR) transverse relaxation was used to estimate a pore size distribution for 63 samples of Rotliegend sandstone. The surface relaxation parameter required to relate NMR to pore size is estimated by combination of NMR...

Geohydrology of the Navajo sandstone in western Kane, southwestern Garfield, and southeastern Iron counties, Utah

Science.gov (United States)

Freethey, G.W.

1988-01-01

The upper Navajo and Lamb Point aquifers in the Navajo Sandstone are the principal source of water for the city of Kanab, irrigation, stock, and for rural homes in the study area. Well logs and outcrop descriptions indicate the Navajo Sandstone consists of the Lamb Point Tongue and an unnamed upper member that are separated by the Tenney Canyon Tongue of the Kayenta Formation. The main Kayenta Formation underlies the Lamb Point Tongue. The Lamb Point Tongue and the upper member of the Navajo Sandstone are saturated and hydraulically connected through the Tenney Canyon Tongue. Available data indicate that precipitation percolates to the groundwater reservoir where the Navajo Sandstone crops out. Estimates of the rate of recharge at the outcrop range from 0.1 to as much as 2.8 in/yr. Water level data indicate that water moves from the upper member of the Navajo Sandstone, through the Tenney Canyon Tongue, and into the Lamb Point Tongue. Lateral flow is generally from the outcrop areas toward the incised canyons formed by tributaries of Kanab Creek and Johnson Wash. Direction and rate of groundwater movement and the location and character of the natural hydrologic boundaries in the northern part of the area where the Navajo Sandstone is buried cannot be determined conclusively without additional water level data. (Author 's abstract)

Elastic moduli of sandstones saturated with a range of pore fluids correlated with kinematic viscosity and frequency ratio

DEFF Research Database (Denmark)

Sørensen, Morten Kanne; Fabricius, Ida Lykke

2011-01-01

. The purpose of this study is to investigate if frame parameters can be extracted from air saturated measurements in sandstones, because earlier studies have shown that air may have a non-negligible effect on carbonates due to the high kinematic viscosity of air (Fabricius et al., 2010)....

Anatomical adaptations of cynodon dactylon (l.) pers., from the salt range Pakistan, to salinity stress. I. root and stem anatomy

International Nuclear Information System (INIS)

Hameed, M.; Ashraf, M.; Naz, N.; Al-qurainy, F.

2010-01-01

A naturally adapted salt tolerant population of Cynodon dactylon (L.) Pers., from highly saline soils of Uchhali Lake, the Salt Range, Pakistan was evaluated for root and stem anatomical modifications. A population from the normal (non-saline) soils of the Faisalabad region was also collected for comparison. Both populations were subjected to salt stress hydroponically. The salt treatments used were: control (0 mM salt), 50, 100, 150 and 200 mM NaCl in 0.5 strength Hoagland's nutrient solution. The Salt Range population showed specific root and stem anatomical adaptations for its better survival under harsh saline environments. Increased exodermis and sclerenchyma, endodermis, cortex and pith parenchyma in roots were critical for checking water loss and enhancing water storage capability. In stem, increased stem area (succulence), increased epidermis and sclerenchyma thicknesses (preventing water loss), increased cortex thickness (increasing water storage), and increased number and area of vascular tissue (increased water conduction) seemed to be crucial for its better survival under harsh saline environments. (author)

Sedimentary uranium occurrences in Eastern Europe with special reference to sandstone formations

International Nuclear Information System (INIS)

Barthel, F.; Hahn, L.

1985-01-01

Sedimentary uranium deposits, especially in sandstones, play an important role in uranium mining in Eastern Europe. The paper reviews recent publications on uranium occurrences in sandstone formations in the German Democratic Republic, Poland, CSSR, Hungary, Romania, Bulgaria and Albania. The uranium deposits in sandstones in Yugoslavia are described in a separate paper in this volume. Sandstone deposits of the USSR are not reviewed. Uranium mineralizations occur in sandstones from Ordovician to Tertiary age. Major deposits are developed in Upper Carboniferous sandstones in association with coal (GDR, Poland), in Permian strata (CSSR, Hungary, Romania), in Cretaceous sandstones (GDR, CSSR), and in Tertiary sediments (CSSR). The Permian deposits can be compared with deposits of similar age in Northern Italy and Northern Yugoslavia. Roll-type orebodies are developed in some of the Cenomanian sandstones. Tertiary deposits are mainly associated with lignites. Uranium deposits in sandstones of Albania and Bulgaria are not described in the literature. Geologic similarities with sandstone basins in adjacent countries suggest the presence of uranium mineralizations in Permian, Lower Triassic, and Tertiary sandstones. (author)

Simulation of forced convection in non-Newtonian fluid through sandstones

Science.gov (United States)

Gokhale, M. Y.; Fernandes, Ignatius

2017-11-01

Numerical simulation is carried out to study forced convection in non-Newtonian fluids flowing through sandstones. Simulation is carried out using lattice Boltzmann method (LBM) for both shear-thinning and shear-thickening, by varying the power law index from 0.5 to 1.5 in Carreau-Yasuda model. Parameters involved in LBM and Carreau model are identified to achieve numerical convergence. Permeability and porosity are varied in the range of 10-10-10-6 and 0.1-0.7, respectively, to match actual geometrical properties of sandstone. Numerical technology is validated by establishing Darcy's law by plotting the graph between velocity and pressure gradient. Consequently, investigation is carried out to study the influence of material properties of porous media on flow properties such as velocity profiles, temperature profiles, and Nusselt number.

Effect of temperature on sandstone permeability

DEFF Research Database (Denmark)

Rosenbrand, Esther; Kjøller, Claus

Hot water injection in geothermal sandstone aquifers is considered for seasonal energy storage in Denmark. However, an increase in the aquifer temperature might reduce permeability, and thereby increase production costs. An understanding of the factors that control permeability is required in order...... and the Klinkenberg procedure showed the expected correlation between the two measures, however, differences could be around one order of magnitude. In tight gas sandstones, permeability is often sensitive to net stress, which might change due to the pore pressure change in the Klinkenberg procedure. Besides...... affecting the Klinkenberg procedure, the combined effect of slip and changes in permeability would affect production during pressure depletion in tight gas sandstone reservoirs; therefore effects of gas slip and net stress on permeability were combined in a model based on the Klinkenberg equation. A lower...

The Jurassic of Denmark and Greenland: Sedimentology and sequence stratigraphy of paralic and shallow marine Upper Jurassic sandstones in the northern Danish Central Graben

Directory of Open Access Journals (Sweden)

Johannessen, Peter N.

2003-10-01

Full Text Available Paralic and shallow marine sandstones were deposited in the Danish Central Graben during Late Jurassic rifting when half-grabens were developed and the overall eustatic sea level rose. During the Kimmeridgian, an extensive plateau area consisting of the Heno Plateau and the Gertrud Plateau was situated between two highs, the Mandal High to the north, and the combined Inge and Mads Highs to the west. These highs were land areas situated on either side of the plateaus and supplied sand to the Gertrud and Heno Plateaus. Two graben areas, the Feda and Tail End Grabens, flanked the plateau area to the west and east, respectively. The regressive–ransgressive succession consists of intensely bioturbated shoreface sandstones, 25–75 m thick. Two widespread unconformities (SB1, SB2 are recognised on the plateaus, forming the base of sequence 1 and sequence 2, respectively. These unconformities were created by a fall in relative sea level during which rivers may have eroded older shoreface sands and transported sediment across the Heno andGertrud Plateaus, resulting in the accumulation of shoreface sandstones farther out in the Feda and Tail End Grabens, on the south-east Heno Plateau and in the Salt Dome Province. Duringsubsequent transgression, fluvial sediments were reworked by high-energy shoreface processes on the Heno and Gertrud Plateaus, leaving only a lag of granules and pebbles on the marine transgressive surfaces of erosion (MTSE1, MTSE2.The sequence boundary SB1 can be traced to the south-east Heno Plateau and the Salt Dome Province, where it is marked by sharp-based shoreface sandstones. During low sea level, erosion occurred in the southern part of the Feda Graben, which formed part of the Gertrud and Heno Plateaus, and sedimentation occurred in the Norwegian part of the Feda Graben farther to the north. During subsequent transgression, the southern part of the Feda Graben began to subside, and a succession of backstepping back

Reviews on the metallogenic and geological features of sandstone-type uranium deposits in Japan

International Nuclear Information System (INIS)

Pei Chengkai; Huang Xianfang; Zhang Baoju

2006-01-01

Regional geologic settings of sandstone-type uranium deposits in Japan are firstly analyzed. The regional tectonic evolution characteristics of 'Green tuff region' and 'Non green tuff region' and their relationship with uranium mineralization are elaborated in depth. Based on those mentioned above, the uranium sources of sandstone-type uranium deposits in Japan are discussed deeply and the most favorable uranium sources are considered to come from the basement and the surrounding granites. Their intrusive epochs range from Later Cretaceous to Palaeogene (about 60 to 70 Ma ago). The characteristics of ore-bearing host rocks, matter compositions of the deposits, ore formation enrichment factors, the hydrogeologic conditions and so on are described by taking Ningyo-Toge and Tono deposits as examples. Finally, the prospecting measures for the palaeo-channel sandstone-type uranium deposits (basal type) are reviewed. (authors)

57Fe Mössbauer and X-ray characterisation of sandstones

International Nuclear Information System (INIS)

Mulaba-Bafubiandi, A. F.; Waanders, F. B.

2013-01-01

Sandstones from the Free State province in South Africa have been mined and processed mainly by small scale and artisanal miners in the rural areas. In the present investigation basic fire proof and water absorption tests, X-ray and γ-ray based characterisation techniques were used to study the sandstones. The collected samples were grouped according to their apparent colour in day light conditions and the elemental analysis showed the presence of a high amount of oxygen (>52%) and silicon (>38%) with Mn, Al, Fe and Ca as major elements in proportions related to the colour distribution of the various sandstones. The uniaxial compressive stress was found to be the highest (56 MPa) for the greyish sandstone and the lowest (8 MPa) for the white sandstone sample, also associated with the lowest (Al+Fe)/Si value of 0.082. The humidity test showed that the 6 % water absorption was lower than the recommended ASTM value of 8 %. The sandstone samples were also subjected to various high temperatures to simulate possible fire conditions and it was found that the non alteration of the mineral species might be one of the reasons why the sandstones are regarded as the most refractory amongst the building materials typically used. Mössbauer spectroscopy revealed that iron is present in all the sandstones, mainly as Fe 3 +  with the black sandstone showing an additional presence of 3 % Fe 2 +  indicating that a higher iron content coupled to higher silicon content, contributes to an increase in the uniaxial compressive strength.

Diagenetic history of the Surma Group sandstones (Miocene) in the Surma Basin, Bangladesh

Science.gov (United States)

Rahman, M. Julleh Jalalur; McCann, Tom

2012-02-01

This study examines the various diagenetic controls of the Miocene Surma Group sandstones encountered in petroleum exploration wells from the Surma Basin, which is situated in the northeastern part of the Bengal Basin, Bangladesh. The principal diagenetic minerals/cements in the Surma Group sandstones are Fe-carbonates (with Fe-calcite dominating), quartz overgrowths and authigenic clays (predominantly chlorite, illite-smectite and minor kaolin). The isotopic composition of the carbonate cement revealed a narrow range of δ 18O values (-10.3‰ to -12.4‰) and a wide range of δ 13C value (+1.4‰ to -23.1‰). The δ 13C VPDB and δ 18O VPDB values of the carbonate cements reveal that carbon was most likely derived from the thermal maturation of organic matter during burial, as well as from the dissolution of isolated carbonate clasts and precipitated from mixed marine-meteoric pore waters. The relationship between the intergranular volume (IGV) versus cement volume indicates that compaction played a more significant role than cementation in destroying the primary porosity. However, cementation also played a major role in drastically reducing porosity and permeability in sandstones with poikilotopic, pore-filling blocky cements formed in early to intermediate and deep burial areas. In addition to Fe-carbonate cements, various clay minerals including illite-smectite and chlorite occur as pore-filling and pore-lining authigenic phases. Significant secondary porosity has been generated at depths from 2500 m to 4728 m. The best reservoir rocks found at depths of 2500-3300 m are well sorted, relatively coarse grained; more loosely packed and better rounded sandstones having good porosities (20-30%) and high permeabilities (12-6000 mD). These good quality reservoir rocks are, however, not uniformly distributed and can be considered to be compartmentalized as a result of interbedding with sandstone layers of low to moderate porosities, low permeabilities owing to poor

Anthropogenic origin of salt crusts on sandstone sculptures of Prague's Charles Bridge (Czech Republic): Evidence of mineralogy and stable isotope geochemistry

Czech Academy of Sciences Publication Activity Database

Přikryl, R.; Svobodová, J.; Žák, K.; Hradil, David

2004-01-01

Roč. 16, č. 4 (2004), s. 609-617 ISSN 0935-1221 Institutional research plan: CEZ:AV0Z4032918 Keywords : sandstones * sulphate crusts * XRD study Subject RIV: CA - Inorganic Chemistry Impact factor: 1.207, year: 2004

Petrography and geochemistry of Jurassic sandstones from the ...

Indian Academy of Sciences (India)

V Periasamy

On the basis of geochemical results, sandstones are classified into arkose, ..... Geochemical classification diagram of sandstone samples from the Jhuran Formation based on log(SiO2/Al2O3)– ..... 1993) showing single trend for the Jhuran.

Sensing, Measuring and Modelling the Mechanical Properties of Sandstone

Science.gov (United States)

Antony, S. J.; Olugbenga, A.; Ozerkan, N. G.

2018-02-01

We present a hybrid framework for simulating the strength and dilation characteristics of sandstone. Where possible, the grain-scale properties of sandstone are evaluated experimentally in detail. Also, using photo-stress analysis, we sense the deviator stress (/strain) distribution at the micro-scale and its components along the orthogonal directions on the surface of a V-notch sandstone sample under mechanical loading. Based on this measurement and applying a grain-scale model, the optical anisotropy index K 0 is inferred at the grain scale. This correlated well with the grain contact stiffness ratio K evaluated using ultrasound sensors independently. Thereafter, in addition to other experimentally characterised structural and grain-scale properties of sandstone, K is fed as an input into the discrete element modelling of fracture strength and dilation of the sandstone samples. Physical bulk-scale experiments are also conducted to evaluate the load-displacement relation, dilation and bulk fracture strength characteristics of sandstone samples under compression and shear. A good level of agreement is obtained between the results of the simulations and experiments. The current generic framework could be applied to understand the internal and bulk mechanical properties of such complex opaque and heterogeneous materials more realistically in future.

Elevated Uranium in Aquifers of the Jacobsville Sandstone

Science.gov (United States)

Sherman, H.; Gierke, J.

2003-12-01

The EPA has announced a new standard for uranium in drinking water of 30 parts per billion (ppb). This maximum contaminant level (MCL) takes effect for community water supplies December 2003. The EPA's ruling has heightened awareness among residential well owners that uranium in drinking water may increase the risk of kidney disease and cancer and has created a need for a quantified, scientific understanding of the occurrence and distribution of uranium isotopes in aquifers. The authors are investigating the occurrence of elevated uranium in northern Michigan aquifers of the Middle Proterozoic Jacobsville sandstone, a red to mottled sequence of sandstones, conglomerates, siltstones and shales deposited as basin fill in the 1.1 Ga Midcontinent rift. Approximately 25% of 300 well water samples tested for isotopic uranium have concentrations above the MCL. Elevated uranium occurrences are distributed throughout the Jacobsville sandstone aquifers stretching across Michigan's Upper Peninsula. However, there is significant variation in well water uranium concentrations (from 0.01 to 190 ppb) and neighboring wells do not necessarily have similar concentrations. The authors are investigating hydrogeologic controls on ground water uranium concentrations in the Jacobsville sandstone, e.g. variations in lithology, mineralogy, groundwater residence time and geochemistry. Approximately 2000' of Jacobsville core from the Amoco St. Amour well was examined in conjunction with the spectral gamma ray log run in the borehole. Spikes in equivalent uranium (eU) concentration from the log are frequently associated with clay and heavy mineral layers in the sandstone core. The lithology and mineralogy of these layers will be determined by analysis of thin sections and x-ray diffraction. A portable spectrometer, model GRS-2000/BL, will be used on the sandstone cliffs along Lake Superior to characterize depositional and lithologic facies of the Jacobsville sandstone in terms of

Determination of Hydraulic and Transport Parameters of Organic Chemical and Inorganic Anions Solutes for Unfractured Cores of Berea Sandstone Using a Hydraulic Coreholder

Science.gov (United States)

Blanford, W. J.; Neil, L.

2017-12-01

To better evaluate the potential for toxic organic chemicals to migrate upward through the rock strata from hydraulic fracturing zones and into groundwater resources, a series of miscible displacement solute transport studies of cores of Berea Sandstone have been conducted using hydrostatic core holder. These tests involved passing aqueous solutions with natural background level of salts using a high pressure LC pump through 2 in wide by 3 in long unfractured cores held within the holder. Relative solute transport of 100 to 500ml pulses of target solutes including a series of chlorinated solvents and methylated benzenes was measured through in-line UV and fluorescence detectors and manual sampling and analysis with GCMS. The results found these sandstones to result in smooth ideal shaped breakthrough curves. Analysis with 1D transport models (CXTFIT) of the results found strong correlation with chemical parameters (diffusion coefficients, aqueous solubility, and octanol-water partitioning coefficients) showing that these parameter and QSPR relationships can be used to make accurate predictions for such a system. In addition to the results of the studies, lessons learned from this novel use of a coreholder for evaluation of porosity, water-saturated permeability, and solute transport of these sandstones (K = 1.5cm/day) and far less permeable sandstones samples (K = 0.15 cm/yr) from a hydraulic fracturing site in central Pennsylvania will be presented.

Micropore Structure Representation of Sandstone in Petroleum Reservoirs Using an Atomic Force Microscope

International Nuclear Information System (INIS)

Bai Yong-Qiang; Zhu Xing; Wu Jun-Zheng; Bai Wen-Guang

2011-01-01

The pore structure of sandstone in an oil reservoir is investigated using atomic force microscopy (AFM). At nanoscale resolution, AFM images of sandstone show us the fine structure. The real height data of images display the three-dimensional space structure of sandstone effectively. The three-dimensional analysis results show that the AFM images of sandstone have unique characteristics that, like fingerprints, can identify different structural properties of sandstones. The results demonstrate that AFM is an effective method used to represent original sandstone in petroleum reservoirs, and may help geologists to appreciate the sandstone in oil reservoirs fully. (general)

Transport of silver nanoparticles in single fractured sandstone

Science.gov (United States)

Neukum, Christoph

2018-02-01

Silver nanoparticles (Ag-NP) are used in various consumer products and are one of the most prevalent metallic nanoparticle in commodities and are released into the environment. Transport behavior of Ag-NP in groundwater is one important aspect for the assessment of environmental impact and protection of drinking water resources in particular. Ag-NP transport processes in saturated single-fractured sandstones using triaxial flow cell experiments with different kind of sandstones is investigated. Ag-NP concentration and size are analyzed using flow field-flow fractionation and coupled SEM-EDX analysis. Results indicate that Ag-NP are more mobile and show generally lower attachment on rock surface compared to experiments in undisturbed sandstone matrix and partially fractured sandstones. Ag-NP transport is controlled by the characteristics of matrix porosity, time depending blocking of attachment sites and solute chemistry. Where Ag-NP attachment occur, it is heterogeneously distributed on the fracture surface.

INAA and petrological study of sandstones from the Angkor monuments

International Nuclear Information System (INIS)

Kucera, J.; Kranda, K.; Soukal, L.; Novak, J.K.; Lang, M.; Poncar, J.; Krausova, I.; Cunin, O.

2008-01-01

We determined 35 major, minor and trace elements in sandstone samples taken from building blocks of 19 Angkor temples and from an old and a new quarry using INAA. We also characterized the sandstone samples with conventional microscopy and electron microprobe analysis. Using cluster analysis, we found no straightforward correlation between the chemical/petrological properties of the sandstones and a presumed period of individual temples construction. The poor correlation may result either from the inherent inhomogeneity of sandstone or just reflect the diversity of quarries that supplied building blocks for the construction of any particular temple. (author)

INTRODUCTION Sandstone beds within Auchi locality are the ...

African Journals Online (AJOL)

The major framework composition is Q F L which classifies the sandstone as Quartz ... The grains are texturally immature as depicted by their subangular edges but mineralogically ..... Fig 6 : Vertical Section of Bioturbated Sandstone Lithofacies Showing Trace Fossils ..... on Water Quality and Planktonic Production in an.

Formation conditions and prospecting criteria for sandstone uranium deposit of interlayer oxidation type

International Nuclear Information System (INIS)

Huang Shijie

1994-01-01

This paper comprehensively analyses the geotectonic setting and favourable conditions, such as structure of the basin, sedimentary facies and paleogeography, geomorphology and climate, hydrodynamics and hydrogeochemistry, the development of interlayered oxidation etc, necessary for the formation of sandstone uranium deposit of interlayered oxidation type. The following prospecting criteria is proposed, namely: abundant uranium source, arid climate, stable big basin, flat-lying sandstone bed, big alluvial fan, little change in sedimentary facies, intercalation of sandstone and mudstone beds, shallow burying of sandstone bed, well-aquiferous sandstone bed, high permeability of sandstone bed, development of interlayered oxidation, and high content of reductant in sandstone. In addition, the 6 in 1 hydrogenic genetic model is proposed

Channel sandstone and bar morphology of the Beaufort group uranium district near Beaufort West

International Nuclear Information System (INIS)

Stear, W.M.

1980-01-01

Sheet-like and lenticular sandstone bodies in the Lower Beaufort Group (Adelaide Subgroup) uranium district occur in megacyclic repetition as superimposed systems of ephemeral fluvial channels that display characteristics of complex lateral and vertical accretion. Channel sandstone bodies are defined on morphological grounds into two types. Sheet sandstone bodies are the commonest type and comprise the bulk of sandstone packages in arenaceous zones of megacycles. Composite sandstone sheets result from multilateral coalescence of individual sandstone bodies. Isolated lenticular sandstone units in argillaceous zones of megacycles comprise sheet and ribbon sandstone types. Multi-storeying is a prominent feature of most channel sandstone bodies and often results in local sandstone thickening. Bedforms relate to the formation of compound bars and record periods of dynamic accretion and erosion. Rarely preserved palaeosurfaces vividly illustrate the fluctuating hydrodynamic conditions that typified ephemeral fluvial sedimentation in a semi-arid environment during Lower Beaufort times

Channel sandstone and bar morphology of the Beaufort group uranium district near Beaufort West

Energy Technology Data Exchange (ETDEWEB)

Stear, W M

1980-01-01

Sheet-like and lenticular sandstone bodies in the Lower Beaufort Group (Adelaide Subgroup) uranium district occur in megacyclic repetition as superimposed systems of ephemeral fluvial channels that display characteristics of complex lateral and vertical accretion. Channel sandstone bodies are defined on morphological grounds into two types. Sheet sandstone bodies are the commonest type and comprise the bulk of sandstone packages in arenaceous zones of megacycles. Composite sandstone sheets result from multilateral coalescence of individual sandstone bodies. Isolated lenticular sandstone units in argillaceous zones of megacycles comprise sheet and ribbon sandstone types. Multi-storeying is a prominent feature of most channel sandstone bodies and often results in local sandstone thickening. Bedforms relate to the formation of compound bars and record periods of dynamic accretion and erosion. Rarely preserved palaeosurfaces vividly illustrate the fluctuating hydrodynamic conditions that typified ephemeral fluvial sedimentation in a semi-arid environment during Lower Beaufort times.

ANALYSIS OF OIL-BEARING CRETACEOUS SANDSTONE HYDROCARBON RESERVOIRS, EXCLUSIVE OF THE DAKOTA SANDSTONE, ON THE JICARILLA APACHE INDIAN RESERVATION, NEW MEXICO

International Nuclear Information System (INIS)

Jennie Ridgley

2000-01-01

A goal of the Mesaverde project was to better define the depositional system of the Mesaverde in hopes that it would provide insight to new or by-passed targets for oil exploration. The new, detailed studies of the Mesaverde give us a better understanding of the lateral variability in depositional environments and facies. Recognition of this lateral variability and establishment of the criteria for separating deltaic, strandplain-barrier, and estuarine deposits from each other permit development of better hydrocarbon exploration models, because the sandstone geometry differs in each depositional system. Although these insights will provide better exploration models for gas exploration, it does not appear that they will be instrumental in finding more oil. Oil in the Mesaverde Group is produced from isolated fields on the Chaco slope; only a few wells define each field. Production is from sandstone beds in the upper part of the Point Lookout Sandstone or from individual fluvial channel sandstones in the Menefee. Stratigraphic traps rather than structural traps are more important. Source of the oil in the Menefee and Point Lookout may be from interbedded organic-rich mudstones or coals rather than from the Lewis Shale. The Lewis Shale appears to contain more type III organic matter and, hence, should produce mainly gas. Outcrop studies have not documented oil staining that might point to past oil migration through the sandstones of the Mesaverde. The lack of oil production may be related to the following: (1) lack of abundant organic matter of the type I or II variety in the Lewis Shale needed to produce oil, (2) ineffective migration pathways due to discontinuities in sandstone reservoir geometries, (3) cementation or early formation of gas prior to oil generation that reduced effective permeabilities and served as barriers to updip migration of oil, or (4) erosion of oilbearing reservoirs from the southern part of the basin. Any new production should mimic that of

Experimental deformation in sandstone, carbonates and quartz aggregate

Energy Technology Data Exchange (ETDEWEB)

Cheung, Cecilia See Nga [Stony Brook Univ., NY (United States)

2015-05-01

The first part of my thesis is mainly focused on the effect of grain size distribution on compaction localization in porous sandstone. To identify the microstructural parameters that influence compaction band formation, I conducted a systematic study of mechanical deformation, failure mode and microstructural evolution in Bleurswiller and Boise sandstones, of similar porosity (~25%) and mineralogy but different sorting. Discrete compaction bands were observed to develop over a wide range of pressure in the Bleurswiller sandstone that has a relatively uniform grain size distribution. In contrast, compaction localization was not observed in the poorly sorted Boise sandstone. My results demonstrate that grain size distribution exerts important influence on compaction band development, in agreement with recently published data from Valley of Fire and Buckskin Gulch, as well as numerical studies. The second part aimed to improve current knowledge on inelastic behavior, failure mode and brittle-ductile transition in another sedimentary rock, porous carbonates. A micritic Tavel (porosity of ~13%) and an allochemical Indiana (~18%) limestones were deformed under compaction in wet and dry conditions. At lower confining pressures, shear localization occurred in brittle faulting regime. Through transitional regime, the deformation switched to cataclastic flow regime at higher confining pressure. Specifically in the cataclastic regime, the (dry and wet) Tavel and dry Indiana failed by distributed cataclastic flow, while in contrast, wet Indiana failed as compaction localization. My results demonstrate that different failure modes and mechanical behaviors under different deformation regimes and water saturation are fundamental prior to any geophysical application in porous carbonates. The third part aimed to focus on investigating compaction on quartz aggregate starting at low (MPa) using X-ray diffraction. We report the diffraction peak evolution of quartz with increasing

Endolithic algae of semi-desert sandstones: systematic, biogeographic and ecophysiologic investigations

International Nuclear Information System (INIS)

Bell, R.A.

1986-01-01

Investigations were conducted into the ecology of an unusual algal community in northern Arizona. These microorganisms are called endolithic algae because they occur beneath the surface of rocks. Eighteen taxa, including representatives of both eukaryotic and prokaryotic genera, were isolated from below the surface of eight sandstones in four semi-desert and cold temperate biomes of the Colorado Plateau. As the macroclimate of the area changes from cold temperature desert scrub to cold temperate forest the taxonomic composition of the endolithic algal communities shifts from domination by coccoid blue-green algae to domination by coccoid and sarcinoid green algae. The algal communities varied in generic composition, chlorophyll a content, and in their location within the different sandstones. Investigations into the microclimate of the endolithic algal zone in two adjacent but differently-colored sections (white and brown) of Coconino sandstone have demonstrated differences between the environment above the rock surface and that just beneath the surface. In seasonal samples of the Coconino sandstone, chlorophyll a content ranged from 50 to 100 mg x m -2 in the white rock and 8 to 45 mg x m -2 in the brown rock. Primary production (as measured by 14 CO 2 incorporation) displayed marked seasonal patterns that appear to be correlated to the environmental conditions within the rocks as opposed to those outside the rocks. The widespread distribution of certain algae in the endolithic habitats of the Colorado Plateau and their presence in rocks at quite distant locations suggests that the endolithic habitat may be utilized by algae whenever it provides more favorable conditions than the surrounding surfaces

Distribution characteristics of Shihongtan uranium deposits calcareous sandstone and discussion on their genesis

International Nuclear Information System (INIS)

Zhu Huanqiao; Jia Heng; Xu Gaozhong; Li Zhanyou

2007-12-01

It is considered that the calcareous sandstone appear at layer along of a bunch of pear lens on and off, localled near up and down surface of sandbody or washed surface, has sandstone of more macro-grain and more gradation through statistics and analysis of calcareous sandstone in goal layer in Shihongtan uranium deposits. The calcareous sandstone accumulation thickness chorogram demonstrated that the calcareous sandstone centralized distribution in the ore body growth area, thus it can be seen, in the oxidation reduction intermediate belt the calcareous sandstone forms with the uranium mine has the certain origin relation. Choropleth map of summed thickness of calcareous sandstone deserves that it mainly appear in area of uranium body and related cause of formation of ore body of interlayer deacidizing--oxidation belt. (authors)

BASIN ANALYSIS AND PETROLEUM SYSTEM CHARACTERIZATION AND MODELING, INTERIOR SALT BASINS, CENTRAL AND EASTERN GULF OF MEXICO

Energy Technology Data Exchange (ETDEWEB)

Ernest A. Mancini; Donald A. Goddard; Ronald K. Zimmerman

2005-05-10

The principal research effort for Year 2 of the project has been data compilation and the determination of the burial and thermal maturation histories of the North Louisiana Salt Basin and basin modeling and petroleum system identification. In the first nine (9) months of Year 2, the research focus was on the determination of the burial and thermal maturation histories, and during the remainder of the year the emphasis has basin modeling and petroleum system identification. Existing information on the North Louisiana Salt Basin has been evaluated, an electronic database has been developed, regional cross sections have been prepared, structure and isopach maps have been constructed, and burial history, thermal maturation history and hydrocarbon expulsion profiles have been prepared. Seismic data, cross sections, subsurface maps and related profiles have been used in evaluating the tectonic, depositional, burial and thermal maturation histories of the basin. Oil and gas reservoirs have been found to be associated with salt-supported anticlinal and domal features (salt pillows, turtle structures and piercement domes); with normal faulting associated with the northern basin margin and listric down-to-the-basin faults (state-line fault complex) and faulted salt features; and with combination structural and stratigraphic features (Sabine and Monroe Uplifts) and monoclinal features with lithologic variations. Petroleum reservoirs are mainly Upper Jurassic and Lower Cretaceous fluvial-deltaic sandstone facies and Lower Cretaceous and Upper Cretaceous shoreline, marine bar and shallow shelf sandstone facies. Cretaceous unconformities significantly contribute to the hydrocarbon trapping mechanism capacity in the North Louisiana Salt Basin. The chief petroleum source rock in this basin is Upper Jurassic Smackover lime mudstone beds. The generation of hydrocarbons from Smackover lime mudstone was initiated during the Early Cretaceous and continued into the Tertiary

Facies architecture of the Bluejacket Sandstone in the Eufaula Lake area, Oklahoma: Implications for the reservoir characterization of the Bartlesville Sandstone

Energy Technology Data Exchange (ETDEWEB)

Ye, Liangmiao; Yang, Kexian [Univ. of Tulsa, OK (United States)

1997-08-01

Outcrop studies of the Bluejacket Sandstone (Middle Pennsylvanian) provide significant insights to reservoir architecture of the subsurface equivalent Bartlesville Sandstone. Quarry walls and road cuts in the Lake Eufaula area offer excellent exposures for detailed facies architectural investigations using high-precision surveying, photo mosaics. Directional minipermeameter measurements are being conducted. Subsurface studies include conventional logs, borehole image log, and core data. Reservoir architectures are reconstructed in four hierarchical levels: multi-storey sandstone, i.e. discrete genetic intervals; individual discrete genetic interval; facies within a discrete genetic interval; and lateral accretion bar deposits. In both outcrop and subsurface, the Bluejacket (Bartlesville) Sandstone comprises two distinctive architectures: a lower braided fluvial and an upper meandering fluvial. Braided fluvial deposits are typically 30 to 80 ft thick, and are laterally persistent filling an incised valley wider than the largest producing fields. The lower contact is irregular with local relief of 50 ft. The braided-fluvial deposits consist of 100-400-ft wide, 5-15-ft thick channel-fill elements. Each channel-fill interval is limited laterally by an erosional contact or overbank deposits, and is separated vertically by discontinuous mudstones or highly concentrated mudstone interclast lag conglomerates. Low-angle parallel-stratified or trough cross-stratified medium- to coarse-grained sandstones volumetrically dominate. This section has a blocky well log profile. Meandering fluvial deposits are typically 100 to 150 ft thick and comprise multiple discrete genetic intervals.

Elementary analysis on the main factors affecting the permeability of sandstones

International Nuclear Information System (INIS)

Gong Binli

2006-01-01

Researches show that in the early stage of sandstone diagenesis, compaction, pressure solution, cementation and replacement reduce both the porosity and the permeability. The cementation of authigenic kaolinite may preserve the tiny intergranular pore-space, and slightly influence the porosity, and even increase the permeability. During the middle to late stage of diagenesis, the organic matter becomes matured, hydrocarbon and acidic water are produced, which forms secondary porosity by the dissolution and the corrosion, and greatly increases the permeability of sandstones and provides a favorable prerequisite for the formation of sandstone-type uranium deposits. The interlayered oxidation alteration, oil-gas reduction and low-temperature hydrothermal alteration also produce secondary porosity in epigenetic reforming stage, which finally decides the permeability after the formation of sandstone-type uranium deposits. This is an important condition for in-situ leaching of sandstone-type uranium deposit. (authors)

Diagenetic effect on permeabilities of geothermal sandstone reservoirs

DEFF Research Database (Denmark)

Weibel, Rikke; Olivarius, Mette; Kristensen, Lars

The Danish subsurface contains abundant sedimentary deposits, which can be utilized for geothermal heating. The Upper Triassic – Lower Jurassic continental-marine sandstones of the Gassum Formation has been utilised as a geothermal reservoir for the Thisted Geothermal Plant since 1984 extracting...... and permeability is caused by increased diagenetic changes of the sandstones due to increased burial depth and temperatures. Therefore, the highest water temperatures typically correspond with the lowest porosities and permeabilities. Especially the permeability is crucial for the performance of the geothermal......-line fractures. Continuous thin chlorite coatings results in less porosity- and permeability-reduction with burial than the general reduction with burial, unless carbonate cemented. Therefore, localities of sandstones characterized by these continuous chlorite coatings may represent fine geothermal reservoirs...

The experimental modeling of gas percolation mechanisms in a coal-measure tight sandstone reservoir: A case study on the coal-measure tight sandstone gas in the Upper Triassic Xujiahe Formation, Sichuan Basin, China

Directory of Open Access Journals (Sweden)

Shizhen Tao

2016-12-01

Full Text Available Tight sandstone gas from coal-measure source rock is widespread in China, and it is represented by the Xujiahe Formation of the Sichuan Basin and the Upper Paleozoic of the Ordos Basin. It is affected by planar evaporative hydrocarbon expulsion of coal-measure source rock and the gentle structural background; hydrodynamics and buoyancy play a limited role in the gas migration-accumulation in tight sandstone. Under the conditions of low permeability and speed, non-Darcy flow is quite apparent, it gives rise to gas-water mixed gas zone. In the gas displacing water experiment, the shape of percolation flow curve is mainly influenced by core permeability. The lower the permeability, the higher the starting pressure gradient as well as the more evident the non-Darcy phenomenon will be. In the gas displacing water experiment of tight sandstone, the maximum gas saturation of the core is generally less than 50% (ranging from 30% to 40% and averaging at 38%; it is similar to the actual gas saturation of the gas zone in the subsurface core. The gas saturation and permeability of the core have a logarithm correlation with a correlation coefficient of 0.8915. In the single-phase flow of tight sandstone gas, low-velocity non-Darcy percolation is apparent; the initial flow velocity (Vd exists due to the slippage effect of gas flow. The shape of percolation flow curve of a single-phase gas is primarily controlled by core permeability and confining pressure; the lower the permeability or the higher the confining pressure, the higher the starting pressure (0.02–0.08 MPa/cm, whereas, the higher the quasi-initial flow speed, the longer the nonlinear section and the more obvious the non-Darcy flow will be. The tight sandstone gas seepage mechanism study shows that the lower the reservoir permeability, the higher the starting pressure and the slower the flow velocity will be, this results in the low efficiency of natural gas migration and accumulation as well as

Characterization of application of acu sandstone in ceramic mass

International Nuclear Information System (INIS)

Nobrega, L.F.P.M.; Souza, M.M.; Gomes, Y.S.; Fernandes, D.L.

2016-01-01

The sandstone is a sedimentary rock formed mainly by quartz grains. In Rio Grande do Norte, there is the Potiguar Basin with the Jandaira and Acu Formations. The latter consists of thick layers of whitish-colored sandstones. It stands out as a water storage facility in the state, but it is also used for building aggregates. This article aimed at the use of the sandstone of this formation in the ceramic mass for coating. Initially, the material was sampled. It went through the comminution process to achieve the required granulometry. After this, three formulations were made to incorporate this new material into the traditional ones. The methods were performed according to ISO 13816. After sintering at 1200 °C, the specimens were subjected to the physical tests. A positive result was obtained for the use of the Acu sandstone in low concentrations. It is clear, therefore, its use in ceramics for coating

Trilobites from the Middle Ordovician Stairway Sandstone, Amadeus Basin, central Australia

DEFF Research Database (Denmark)

Jakobsen, Kristian Grube; Nielsen, Arne Thorshøj; Harper, David Alexander Taylor

2014-01-01

During the Middle Ordovician (Darriwilian) sandstones and siltstones were deposited in the epicontinental Larapintine Sea, which covered large parts of central Australia. The Darriwilian Stairway Sandstone has, for the first time, been sampled stratigraphically for macrofossils to track marine...... benthic biodiversity in this clastic-dominated shallow-water palaeoenvironment situated along the margin of northeastern Gondwana. The faunas from the Stairway Sandstone are generally of low diversity and dominated by bivalves but include several animal groups, with trilobites representing 25......% of the entire shelly fauna. Thirteen trilobite taxa are described from the Stairway Sandstone; the fauna displays a high degree of endemism. One new species, Basilicus (Parabasilicus) brumbyensis sp. nov. is described....

Uranium distribution and sandstone depositional environments: oligocene and upper Cretaceous sediments, Cheyenne basin, Colorado

International Nuclear Information System (INIS)

Nibbelink, K.A.; Ethridge, F.G.

1984-01-01

Wyoming-type roll-front uranium deposits occur in the Upper Cretaceous Laramie and Fox Hills sandstones in the Cheyenne basin of northeastern Colorado. The location, geometry, and trend of specific depositional environments of the Oligocene White River and the Upper Cretaceous Laramie and Fox Hills formations are important factors that control the distribution of uranium in these sandstones. The Fox Hills Sandstone consists of up to 450 ft (140 m) of nearshore marine wave-dominated delta and barrier island-tidal channel sandstones which overlie offshore deposits of the Pierre Shale and which are overlain by delta-plain and fluvial deposits of the Laramie Formation. Uranium, which probably originated from volcanic ash in the White River Formation, was transported by groundwater through the fluvial-channel deposits of the White River into the sandstones of the Laramie and Fox Hills formations where it was precipitated. Two favorable depositional settings for uranium mineralization in the Fox Hills Sandstone are: (1) the landward side of barrier-island deposits where barrier sandstones thin and interfinger with back-barrier organic mudstones, and (2) the intersection of barrier-island and tidal channel sandstones. In both settings, sandstones were probably reduced during early burial by diagenesis of contained and adjacent organic matter. The change in permeability trends between the depositional strike-oriented barrier sandstones and the dip-oriented tidal-channel sandstones provided sites for dispersed groundwater flow and, as demonstrated in similar settings in other depositional systems, sites for uranium mineralization

STRUCTURAL HETEROGENEITIES AND PALEO FLUID FLOW IN AN ANALOG SANDSTONE RESERVOIR 2001-2004

International Nuclear Information System (INIS)

Pollard, David; Aydin, Atilla

2005-01-01

Fractures and faults are brittle structural heterogeneities that can act both as conduits and barriers with respect to fluid flow in rock. This range in the hydraulic effects of fractures and faults greatly complicates the challenges faced by geoscientists working on important problems: from groundwater aquifer and hydrocarbon reservoir management, to subsurface contaminant fate and transport, to underground nuclear waste isolation, to the subsurface sequestration of CO2 produced during fossil-fuel combustion. The research performed under DOE grant DE-FG03-94ER14462 aimed to address these challenges by laying a solid foundation, based on detailed geological mapping, laboratory experiments, and physical process modeling, on which to build our interpretive and predictive capabilities regarding the structure, patterns, and fluid flow properties of fractures and faults in sandstone reservoirs. The material in this final technical report focuses on the period of the investigation from July 1, 2001 to October 31, 2004. The Aztec Sandstone at the Valley of Fire, Nevada, provides an unusually rich natural laboratory in which exposures of joints, shear deformation bands, compaction bands and faults at scales ranging from centimeters to kilometers can be studied in an analog for sandstone aquifers and reservoirs. The suite of structures there has been documented and studied in detail using a combination of low-altitude aerial photography, outcrop-scale mapping and advanced computational analysis. In addition, chemical alteration patterns indicative of multiple paleo fluid flow events have been mapped at outcrop, local and regional scales. The Valley of Fire region has experienced multiple episodes of fluid flow and this is readily evident in the vibrant patterns of chemical alteration from which the Valley of Fire derives its name. We have successfully integrated detailed field and petrographic observation and analysis, process-based mechanical modeling, and numerical

Sandstone-filled normal faults: A case study from central California

Science.gov (United States)

Palladino, Giuseppe; Alsop, G. Ian; Grippa, Antonio; Zvirtes, Gustavo; Phillip, Ruy Paulo; Hurst, Andrew

2018-05-01

Despite the potential of sandstone-filled normal faults to significantly influence fluid transmissivity within reservoirs and the shallow crust, they have to date been largely overlooked. Fluidized sand, forcefully intruded along normal fault zones, markedly enhances the transmissivity of faults and, in general, the connectivity between otherwise unconnected reservoirs. Here, we provide a detailed outcrop description and interpretation of sandstone-filled normal faults from different stratigraphic units in central California. Such faults commonly show limited fault throw, cm to dm wide apertures, poorly-developed fault zones and full or partial sand infill. Based on these features and inferences regarding their origin, we propose a general classification that defines two main types of sandstone-filled normal faults. Type 1 form as a consequence of the hydraulic failure of the host strata above a poorly-consolidated sandstone following a significant, rapid increase of pore fluid over-pressure. Type 2 sandstone-filled normal faults form as a result of regional tectonic deformation. These structures may play a significant role in the connectivity of siliciclastic reservoirs, and may therefore be crucial not just for investigation of basin evolution but also in hydrocarbon exploration.

Geological principles of exploration for sandstone-hosted uranium deposits

International Nuclear Information System (INIS)

Le Roux, J.P.

1982-10-01

Although the importance of sandstone-hosted uranium deposits has seemingly faded in recent years due to the discovery of large, high -grade deposits elsewhere, a forecasted energy shortage in the near future will probably necessitate a new look at sedimentary basins as a source of uranium. Back-arc basins adjacent to calcalkaline source areas are especially favourable if they are filled with fluvial, post-Devonian sediments. Syn- and post-depositional tectonics play an important role in the sedimentation-mineralisation process and should be investigated. The oxidation-reduction state of the sandstones is a valid prospecting tool. Sedimentological environments govern the permeability and vegetal matter content of sandstones and directly control uranium mineralisation

Analyzing the Sand-fixing Effect of Feldspathic Sandstone from the Texture Characteristics

Science.gov (United States)

Zhang, lu; Ban, Jichang

2018-01-01

The purpose of this research was aimed to study the sand fixing effect of feldspathic sandstone in Mu Us Sandy Land, to provide a scienticic basis for desertification control, soil and water conservation and development of farming there. Methods of mixing feldspathic sandstone and aeolian sandy soil according to 1: 0, 1: 1, 1: 2, 1: 5, and 0: 1 mass ratioes, the graded composition and characteristics were studied with laser particle size analyzer. The result showed that these features of sand-based, loosely structured, easy to wind erosion of aeolian sandy soil were changed before feldspathic sandstone and aeolian sandy soil compounding. The <0.05 mm particle mass increased with feldspathic sandstone mass increasing. The texture presented this kind of change from sand to sandy loam to loam to silt loam. The small particle size distribution, good homogeneity and other features of aeolian sandy soil were improved to a certain degree, and the particle size distribution became broad before feldspathic sandstone and aeolian sandy soil compounding. The particle grading was continuous, and the grading characteristic was good when m(F): m(S) was 1: 5(Cu was 54.71 and Cc was 2.54) or when m(F): m(S) was 1: 2(Cu was 76.21, Cc was 1.12). The conclusion is that feldspathic sandstone has sand-fixing effect in texture characteristics, which heightens with feldspathic sandstone mass increasing, and when the mass ratio of feldspathic sandstone: aeolian sandy soil is 1: 2 or 1: 5 which compound better.

ANALYSIS OF OIL-BEARING CRETACEOUS SANDSTONE HYDROCARBON RESERVOIRS, EXCLUSIVE OF THE DAKOTA SANDSTONE, ON THE JICARILLA APACHE INDIAN RESERVATION, NEW MEXICO

International Nuclear Information System (INIS)

Jennie Ridgley

2000-01-01

An additional 450 wells were added to the structural database; there are now 2550 wells in the database with corrected tops on the Juana Lopez, base of the Bridge Creek Limestone, and datum. This completes the structural data base compilation. Fifteen oil and five gas fields from the Mancos-ElVado interval were evaluated with respect to the newly defined sequence stratigraphic model for this interval. The five gas fields are located away from the structural margins of the deep part of the San Juan Basin. All the fields have characteristics of basin-centered gas and can be considered as continuous gas accumulations as recently defined by the U.S. Geological Survey. Oil production occurs in thinly interbedded sandstone and shale or in discrete sandstone bodies. Production is both from transgressive and regressive strata as redefined in this study. Oil production is both stratigraphically and structurally controlled with production occurring along the Chaco slope or in steeply west-dipping rocks along the east margin of the basin. The ElVado Sandstone of subsurface usage is redefined to encompass a narrower interval; it appears to be more time correlative with the Dalton Sandstone. Thus, it was deposited as part of a regressive sequence, in contrast to the underlying rock units which were deposited during transgression

Biodegradation of phenols in a sandstone aquifer under aerobic conditions and mixed nitrate and iron reducing conditions

DEFF Research Database (Denmark)

Broholm, Mette; Arvin, Erik

2000-01-01

in the groundwater. The potential for biodegradation of the phenols in the sandstone aquifer at the site has been investigated in laboratory microcosms under aerobic (oxygen amended) and mixed nitrate and iron reducing (nitrate enriched and unamended) anaerobic conditions, at a range of concentrations (low: similar...... to 5 mg 1(-1): high: similar to 60 mg 1(-1), and very high: similar to 600 mg 1(-1)) and in the presence of other organic coal-tar compounds (mono- and polyaromatic hydrocarbons (BTEXs and PAHs) and heterocyclic compounds (NSOs)) and ammonia liquor. Sandstone cores and groundwater for the microcosms...

Digital Rock Physics Aplications: Visualisation Complex Pore and Porosity-Permeability Estimations of the Porous Sandstone Reservoir

Science.gov (United States)

Handoyo; Fatkhan; Del, Fourier

2018-03-01

Reservoir rock containing oil and gas generally has high porosity and permeability. High porosity is expected to accommodate hydrocarbon fluid in large quantities and high permeability is associated with the rock’s ability to let hydrocarbon fluid flow optimally. Porosity and permeability measurement of a rock sample is usually performed in the laboratory. We estimate the porosity and permeability of sandstones digitally by using digital images from μCT-Scan. Advantages of the method are non-destructive and can be applied for small rock pieces also easily to construct the model. The porosity values are calculated by comparing the digital image of the pore volume to the total volume of the sandstones; while the permeability values are calculated using the Lattice Boltzmann calculations utilizing the nature of the law of conservation of mass and conservation of momentum of a particle. To determine variations of the porosity and permeability, the main sandstone samples with a dimension of 300 × 300 × 300 pixels are made into eight sub-cubes with a size of 150 × 150 × 150 pixels. Results of digital image modeling fluid flow velocity are visualized as normal velocity (streamline). Variations in value sandstone porosity vary between 0.30 to 0.38 and permeability variations in the range of 4000 mD to 6200 mD. The results of calculations show that the sandstone sample in this research is highly porous and permeable. The method combined with rock physics can be powerful tools for determining rock properties from small rock fragments.

Cense Explosion Test Program. Report 1. Cense 1. Explosions in Sandstone

Science.gov (United States)

1977-09-01

series, "Analysis and Summary of CENSE Data." 10 * _ CHAPTER 2 APPROACH 2.1 DESCRIPTION OF TEST SITE An exposed outcrop of Kayenta sandstone with 180...ft/s seismic velocity previously determined (References 12-14) for the unweathered upper zone of the Kayenta sandstone. 16 I The P-wave propagation...Propagation along the horizontal radial was 8400 ft/s. The seismic velocity pre- viously determined for Kayenta sandstone in this area was 7500 ft/s

Brief analysis on relationship between red beds and sandstone-type uranium ore-formation

International Nuclear Information System (INIS)

Ji Zengxian

2006-01-01

Red beds are sandy gravel beds deposited under the arid and hot climates and correspondent to the oxidation environment of continental basins. As an exogenetic epigenetic uranium deposit, the formation of the sandstone-type uranium deposit needs a large chronologic gap between the diagenesis and the subsequent uranium metallogenesis of the ore-hosting target layer with a sedimentary discontinuity and an alternative humid-arid climate. Red beds are the product of this time. The evolutionary times of red beds are in accordance with the formation of the sandstone-type uranium deposit. Both domestic and abroad researches indicate that each times evolution of a red bed might be associated with uranium ore-formation in one or more sandstone layers in the region. In China, red beds are developed in many geologic periods, but sandstone-type uranium mineralization occurs mostly in Mesozoic-Cenozoic. Taking five known sandstone-type uranium deposits as examples, the author makes a primary analysis on the relationship between red beds and the subsequent sandstone-type uranium mineralization. It is suggested that the deposition of red beds and sandstone-type uranium metallogenesis are of 'cogenesis and coexistence' and that the deposition of red beds and its evolutionary times can be regarded as the prerequisites to judge the potential of sandstone-type uranium mineralization in a Mesozoic-Cenozoic sedimentary basin. (authors)

Sandstone landforms shaped by negative feedback between stress and erosion

Czech Academy of Sciences Publication Activity Database

Bruthans, J.; Soukup, J.; Vaculíková, J.; Filippi, Michal; Schweigstillová, Jana; Mayo, A. L.; Mašín, D.; Kletetschka, Günther; Řihošek, J.

2014-01-01

Roč. 7, č. 8 (2014), s. 597-601 ISSN 1752-0894 R&D Projects: GA ČR GA13-28040S Institutional support: RVO:67985831 ; RVO:67985891 Keywords : sandstone * sandstone landsforms * stress * erosion Subject RIV: DB - Geology ; Mineralogy Impact factor: 11.740, year: 2014

Characterizing flow pathways in a sandstone aquifer: Tectonic vs sedimentary heterogeneities

Science.gov (United States)

Medici, G.; West, L. J.; Mountney, N. P.

2016-11-01

Sandstone aquifers are commonly assumed to represent porous media characterized by a permeable matrix. However, such aquifers may be heavy fractured when rock properties and timing of deformation favour brittle failure and crack opening. In many aquifer types, fractures associated with faults, bedding planes and stratabound joints represent preferential pathways for fluids and contaminants. In this paper, well test and outcrop-scale studies reveal how strongly lithified siliciclastic rocks may be entirely dominated by fracture flow at shallow depths (≤ 180 m), similar to limestone and crystalline aquifers. However, sedimentary heterogeneities can primarily control fluid flow where fracture apertures are reduced by overburden pressures or mineral infills at greater depths. The Triassic St Bees Sandstone Formation (UK) of the East Irish Sea Basin represents an optimum example for study of the influence of both sedimentary and tectonic aquifer heterogeneities in a strongly lithified sandstone aquifer-type. This fluvial sedimentary succession accumulated in rapidly subsiding basins, which typically favours preservation of complete depositional cycles including fine grained layers (mudstone and silty sandstone) interbedded in sandstone fluvial channels. Additionally, vertical joints in the St Bees Sandstone Formation form a pervasive stratabound system whereby joints terminate at bedding discontinuities. Additionally, normal faults are present through the succession showing particular development of open-fractures. Here, the shallow aquifer (depth ≤ 180 m) was characterized using hydro-geophysics. Fluid temperature, conductivity and flow-velocity logs record inflows and outflows from normal faults, as well as from pervasive bed-parallel fractures. Quantitative flow logging analyses in boreholes that cut fault planes indicate that zones of fault-related open fractures characterize 50% of water flow. The remaining flow component is dominated by bed-parallel fractures

On the migration of uranium isotopes in sandstone aquifers

International Nuclear Information System (INIS)

Froehlich, K.; Gellermann, R.

1982-01-01

Measurements of natural 238 U and 234 U activity in groundwater of sandstone aquifers have been used to study the migration of these uranium isotopes. Regarding the uranium exchange between liquid phase and rock surface during migration, two different models were applied for evaluating the experimental results. Values of corresponding parameters (retardation factor K, removal rate R) reflecting different behaviour concerning this exchange were determined. For example, the values obtained for 238 U in a Triassic sandstone aquifer of the GDR are K = 8.6 x 10 6 and R = 1.3 x 10 -3 a -1 , respectively. It was found that, under the conditions of the sandstone aquifer concerned, the removal rate model is better suited for calculating uranium-isotope migration in groundwater. (author)

Greybull Sandstone Petroleum Potential on the Crow Indian Reservation, South-Central Montana

Energy Technology Data Exchange (ETDEWEB)

Lopez, David A.

2002-05-13

The focus of this project was to explore for stratigraphic traps that may be present in valley-fill sandstone at the top of the Lower Cretaceous Kootenai Formation. This sandstone interval, generally known as the Greybull Sandstone, has been identified along the western edge of the reservation and is a known oil and gas reservoir in the surrounding region. The Greybull Sandstone was chosen as the focus of this research because it is an excellent, well-documented, productive reservoir in adjacent areas, such as Elk Basin; Mosser Dome field, a few miles northwest of the reservation; and several other oil and gas fields in the northern portion of the Bighorn Basin.

Discussion on distribution characteristics of calcareous sandstone in Shihongtan uranium deposit and its genesis

International Nuclear Information System (INIS)

Zhu Huanqiao; Qiao Haiming; Jia Heng; Xu Gaozhong

2007-01-01

Based on the observation and statistics on the calcareous sandstone in the ore host layer in Shihongtan uranium deposit, this paper finds that the calcareous sandstone occurs on and off near the top or wash surface of the sandbody as beads-strings lens along the layer and concentrates in the area where the ore bodies are rich. In lithology, the calcareous sandstone is of coarse grain and fairly well sorted. According to the analysis on the lithogeochemical features and the carbon and oxygen isotopes of calcareous sandstones, it is realized that there some genetic relation between the formation of calcareous sandstone and uranium mineralization in the oxidation-deoxidation transitional belt, that is the precipitation and enrichment of uranium is accompanied by the deposition of carbonate and formation of calcareous sandstone. (authors)

Hydrocarbon Potential in Sandstone Reservoir Isolated inside Low Permeability Shale Rock (Case Study: Beruk Field, Central Sumatra Basin)

Science.gov (United States)

Diria, Shidqi A.; Musu, Junita T.; Hasan, Meutia F.; Permono, Widyo; Anwari, Jakson; Purba, Humbang; Rahmi, Shafa; Sadjati, Ory; Sopandi, Iyep; Ruzi, Fadli

2018-03-01

Upper Red Bed, Menggala Formation, Bangko Formation, Bekasap Formation and Duri Formationare considered as the major reservoirs in Central Sumatra Basin (CSB). However, Telisa Formation which is well-known as seal within CSB also has potential as reservoir rock. Field study discovered that lenses and layers which has low to high permeability sandstone enclosed inside low permeability shale of Telisa Formation. This matter is very distinctive and giving a new perspective and information related to the invention of hydrocarbon potential in reservoir sandstone that isolated inside low permeability shale. This study has been conducted by integrating seismic data, well logs, and petrophysical data throughly. Facies and static model are constructed to estimate hydrocarbon potential resource. Facies model shows that Telisa Formation was deposited in deltaic system while the potential reservoir was deposited in distributary mouth bar sandstone but would be discontinued bedding among shale mud-flat. Besides, well log data shows crossover between RHOB and NPHI, indicated that distributary mouth bar sandstone is potentially saturated by hydrocarbon. Target area has permeability ranging from 0.01-1000 mD, whereas porosity varies from 1-30% and water saturation varies from 30-70%. The hydrocarbon resource calculation approximates 36.723 MSTB.

A complex investigation of building sandstones from Saxony (Germany)

International Nuclear Information System (INIS)

Goetze, Jens; Siedel, Heiner

2007-01-01

The present paper provides a methodology for the investigation and characterization of building sandstones. This analytical scheme was designed for distinguishing mature arenites, which in general show very similar properties and are difficult to distinguish. This is shown for Cretaceous sandstones from various occurrences in Saxony (Germany), which have been used for centuries as building materials. The procedure is mainly based on the combination of macroscopic rock description, thin section polarizing microscopy (phase composition, texture, grain-size distribution) and cathodoluminescence (CL) microscopy (quartz types, feldspar and kaolinite content) coupled with image analysis, scanning electron microscopy (accessories, pore cement, diagenetic grain surface features), and analysis of pore space data. Sometimes, additional data from X-ray diffraction or chemical analyses (major and trace elements) can be used. Especially in the case of quartz rich arenites, CL is a powerful tool for provenance analysis. The detailed analysis of sandstone material in most cases allows us to assign historically used building material to a specific sandstone occurrence. These results are important for both interpreting the weathering behaviour of the building material and the conservation, reconstruction and stone replacement of historical monuments

Effects of Pisha sandstone content on solute transport in a sandy soil.

Science.gov (United States)

Zhen, Qing; Zheng, Jiyong; He, Honghua; Han, Fengpeng; Zhang, Xingchang

2016-02-01

In sandy soil, water, nutrients and even pollutants are easily leaching to deeper layers. The objective of this study was to assess the effects of Pisha sandstone on soil solute transport in a sandy soil. The miscible displacement technique was used to obtain breakthrough curves (BTCs) of Br(-) as an inert non-adsorbed tracer and Na(+) as an adsorbed tracer. The incorporation of Pisha sandstone into sandy soil was able to prevent the early breakthrough of both tracers by decreasing the saturated hydraulic conductivity compared to the controlled sandy soil column, and the impeding effects increased with Pisha sandstone content. The BTCs of Br(-) were accurately described by both the convection-dispersion equation (CDE) and the two-region model (T-R), and the T-R model fitted the experimental data slightly better than the CDE. The two-site nonequilibrium model (T-S) accurately fit the Na(+) transport data. Pisha sandstone impeded the breakthrough of Na(+) not only by decreasing the saturated hydraulic conductivity but also by increasing the adsorption capacity of the soil. The measured CEC values of Pisha sandstone were up to 11 times larger than those of the sandy soil. The retardation factors (R) determined by the T-S model increased with increasing Pisha sandstone content, and the partition coefficient (K(d)) showed a similar trend to R. According to the results of this study, Pisha sandstone can successfully impede solute transport in a sandy soil column. Copyright © 2015 Elsevier Ltd. All rights reserved.

Geophysical signature recognition of aquifuge and relatively impermeable interbed in ore-hosting sandstone layer at sandstone-type uranium deposit

International Nuclear Information System (INIS)

Zhao Xigang; Wu Hanning; Bai Guanjun; Zhu Huanqiao; Jia Heng

2006-01-01

Geophysical signature recognition of aquifuge and relatively impermeable interbed in ore-hosting aquifer has been carried out a Shihongtan uranium deposit by using comprehensive logging data. The spatial distribution of above aquifuge and impermeable interbed is discussed, and the relation of these layers to sandstone-type uranium deposit, and their impact to in-situ leach mining technology are discussed. It is suggested that the aquifuge and relatively impermeable interbed bring about significant effect to the formation of interlayer oxidation zone sandstone-type uranium deposit, as well as to in-situ leach mining of the deposit. (authors)

Chemical characterisation of himalayan rock salt

International Nuclear Information System (INIS)

Hassan, A.U.; Din, M.U.

2017-01-01

Present study involves the chemical evaluation of rock salt samples collected from the plugging sites of Himalayan salt (Khewra salt mines and Kalabagh salt mines) for their moisture content, water insoluble matter, calcium, magnesium, sulphate content and trace minerals such as Fe,Cu,Cd,Pb,As,Ag and Zn determined by atomic absorption spectroscopy. Moisture content of Khewra and Kalabagh salt samples ranged from 0.03 wt. % to 0.09 wt. % and 0.06 % to 0.08 %, respectively. Water insoluble matter ranged from 0.08 wt. % to 1.4 wt. % and 1.5 wt. % to 2.8wt. % for Khewra and Kalabagh salt samples, respectively. Sulphate content for Khewra salt sample was from 0.39 % to 0.91 % and for Kalabagh salt mines from 0.75 wt. % to 0.95 wt. %. For Khewra salt mines calcium ranged 0.15 wt. % to 0.32 wt. % and for Kalabagh salt samples from 0.1 wt. % to 0.27 wt. %. Magnesium ranged from 0.11 wt. % to 0.35 wt. % for Khewra salt mines, while for Kalabagh salt samples its range was 0.18 wt. % to 0.89 wt. %. Trace metals had the concentration ranges between 0.2 to 1.85 mg/kg for copper; between 0.21 to 0.42 mg/kg for manganese; between 0.04 to 0.06 mg/kg for zinc; between 0.12 to 0.18 mg/kg for arsenic and between 0.03 and 0.05 mg/kg for lead while cadmium content was either below the method's detection limits or in very trace amounts. The results show that the concentrations of all the parameters studied are below the limits set by World Health Organization (WHO) and Food and Agriculture Organization (FAO). Therefore, it can be concluded from the paper that the Himalayan salt from the plugging sites of Khewra and Kalabagh salt mines are safe to use. (author)

Fluoride salts and container materials for thermal energy storage applications in the temperature range 973 - 1400 K

Science.gov (United States)

Misra, Ajay K.; Whittenberger, J. Daniel

1987-01-01

Multicomponent fluoride salt mixtures were characterized for use as latent heat of fusion heat storage materials in advanced solar dynamic space power systems with operating temperatures in the range of 973 to 1400 K. The melting points and eutectic composition for many systems with published phase diagrams were verified, and several new eutectic compositions were identified. Additionally, the heats of fusion of several binary and ternary eutectics and congruently melting intermediate compounds were measured by differential scanning calorimetry. The extent of corrosion of various metals by fluoride melts was estimated from thermodynamic considerations, and equilibrium conditions inside a containment vessel were calculated as functions of the initial moisture content of the salt and free volume above the molten salt. Preliminary experimental data on the corrosion of commercial, high-temperature alloys in LiF-19.5CaF2 and NaF-27CaF2-36MgF2 melts are presented and compared to the thermodynamic predictions.

Temperature effect on microstructure and P-wave propagation in Linyi sandstone

International Nuclear Information System (INIS)

Sun, Hui; Sun, Qiang; Deng, Wenni; Zhang, Weiqiang; Lü, Chao

2017-01-01

Highlights: • Mass loss rate, P-wave velocity change rate and damage factor increase exponentially as temperatures rise. • The damage threshold temperature of sandstone samples is 300 °C and limit temperature is 900 °C. • P-wave velocity change rate of sandstone exhibits excellent linearity with mass loss rate. • Damage factor can be well expressed by mass loss rate. - Abstract: In order to study the effect of high temperature on the sandstone, scanning electron microscope (SEM) experiments and primary wave (P-wave) velocity tests have been carried out on sandstone specimens heated to different temperature. The results showed that: (1) the mass loss rate increases exponentially with the increase of temperature and reaches 2.97% at 900 °C; (2) the P-wave velocity change rate increases exponentially with the increase of temperature while there is some fluctuation before 500 °C; (3) the damage threshold temperature of sandstone samples is 300 °C and the limit temperature is 900 °C; (4) there is a good linear relationship between the mass loss rate and the P-wave velocity change rate, and the correlation coefficient (R) of the fitting line is 0.989; (5) the damage caused by high temperature can be reflected better by the mass loss rate than P-wave velocity change rate. The results obtained in this paper will be good for predicting the properties of sandstone when exposed to high temperature.

Hydrology of the Ferron sandstone aquifer and effects of proposed surface-coal mining in Castle Valley, Utah, with sections on stratigraphy and leaching of overburden

Science.gov (United States)

Lines, Gregory C.; Morrissey, Daniel J.; Ryer, Thomas A.; Fuller, Richard H.

1983-01-01

Coal in the Ferron Sandstone Member of the Mancos Shale of Cretaceous age has traditionally been mined by underground techniques in the Emery Coal Field in the southern end of Castle Valley in east-central Utah. However, approximately 99 million tons are recoverable by surface mining. Ground water in the Ferron is the sole source of supply for the town of Emery, but the aquifer is essentially untapped outside the Emery area.The Ferron Sandstone Member crops out along the eastern edge of Castle Valley and generally dips 2 ? to 10 ? to the northwest. Sandstones in the Ferron are enclosed between relatively impermeable shale in the Tununk and Blue Gate Members of the Mancos Shale. Along the outcrop, the Ferron ranges in thickness from about 80 feet in the northern part of Castle Valley to 850 feet in the southern part. The Ferron also generally thickens in the subsurface downdip from the outcrop. Records from wells and test holes indicate that the full thickness of the Ferron is saturated with water in most areas downdip from the outcrop area.Tests in the Emery area indicate that transmissivity of the Ferron sandstone aquifer ranges from about 200 to 700 feet squared per day where the Ferron is fully saturated. Aquifer transmissivity is greatest near the Paradise Valley-Joes Valley fault system where permeability has been increased by fracturing. Storage coefficient ranges from about 10 .6 to 10 -3 where the Ferron sandstone aquifer is confined and probably averages 5 x 10-2 where it is unconfined.

Characteristics and model of sandstone type uranium deposit in south of Songliao basin

International Nuclear Information System (INIS)

Yu Wenbin; Yu Zhenqing

2010-01-01

Through analyzing the uranium deposit tectonic environment, upper cretaceous sequence stratigraphy, depositional system, evolutionary characteristics of sand bodies, the effect of subsequent transformation and the characteristic of uranium deposit, the sandstone type uranium deposit in southern basin is different from typical interlayer oxidation zone sandstone type uranium deposit. The formation and evolution of sandstone-type uranium deposit are controlled by structure fensters; the favorable sedimentary facies type is braided river facies, and the ore body is braided river sand body. The size of uranium deposits is controlled by the local oxidation zone with the characteristics of sandstone type uranium deposit in partial oxidation zone. Uranium ore bodies which distribute in the roof wings of structure fenstes, and occur in gray layers between the upper and lower oxidation zone, showing tabular, and the plate of uranium ore body is controlled by the local oxidation zone. Based on the geological features of sandstone-type uranium deposits, the metallogenic model of local oxidation zones sandstone-type uranium deposits has been set up in the south of Songliao Baisn. (authors)

Coastal salt-marshes in Albania

OpenAIRE

JULIAN SHEHU; ALMA IMERI; RUDINA KOCI; ALFRED MULLAJ

2014-01-01

The salt marshes of Albania comprise a narrow belt along the Adriatic and Ionian Seas. They have been the subject of a range of human activities causing habitat loss. Enclosure for agricultural use, ports and other infrastructure has reduced many salt marshes to a narrow fringe along estuary shores. Salt marshes are important for a range of interests. In particular they support a range of specialist plant communities and associated animals (especially breeding and wintering birds) and often h...

Citronelle Dome: A giant opportunity for multizone carbon storage and enhanced oil recovery in the Mississippi Interior Salt Basin of Alabama

Science.gov (United States)

Esposito, R.A.; Pashin, J.C.; Walsh, P.M.

2008-01-01

The Citronelle Dome is a giant, salt-cored anticline in the eastern Mississippi Interior Salt Basin of southern Alabama that is located near several large-scale, stationary, carbon-emitting sources in the greater Mobile area. The dome forms an elliptical, four-way structural closure containing opportunities for CO2-enhanced oil recovery (CO2-EOR) and large-capacity saline reservoir CO2 sequestration. The Citronelle oil field, located on the crest of the dome, has produced more than 169 million bbl of 42-46?? API gravity oil from sandstone bodies in the Lower Cretaceous Rodessa Formation. The top seal for the oil accumulation is a thick succession of shale and anhydrite, and the reservoir is underfilled such that oil-water contacts are typically elevated 30-60 m (100-200 ft) above the structural spill point. Approximately 31-34% of the original oil in place has been recovered by primary and secondary methods, and CO2-EOR has the potential to increase reserves by up to 20%. Structural contour maps of the dome demonstrate that the area of structural closure increases upward in section. Sandstone units providing prospective carbon sinks include the Massive and Pilot sands of the lower Tuscaloosa Group, as well as several sandstone units in the upper Tuscaloosa Group and the Eutaw Formation. Many of these sandstone units are characterized by high porosity and permeability with low heterogeneity. The Tuscaloosa-Eutaw interval is capped by up to 610 m (2000 ft) of chalk and marine shale that are proven reservoir seals in nearby oil fields. Therefore, the Citronelle Dome can be considered a major geologic sink where CO2 can be safely stored while realizing the economic benefits associated with CO2-EOR. Copyright ?? 2008. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Sandstone uranium deposits: analogues for surf disposal in some sedimentary rocks

International Nuclear Information System (INIS)

Brookins, D.G.

1987-01-01

Sandstone uranium deposits are well suited as analogs for SURF. These deposits typically occur as tabular or lensoid masses of uraniferous sandstone, commonly where the argillaceous mineral and organic content is high. Primary minerals consist of pitchblende and/or coffinite, with possibly some urano-organic phases as well. The ore is usually associated with authigenic ferromagnesian clay minerals, such as chlorite and/or authigenic illite and/or mixed layer smectite-illite; and with pyrite ± jordisite ± seleniferrous species ± calcite. Organic matter is usually associated with the ore. The clay minerals in the ore zones are commonly vanadiferrous. The genesis of the sandstone uranium deposits is now fairly well understood and allows semi-quantitative estimates to be placed on behaviour of analog-elements for many constituents of SURF (or HLW). Prior to mineralization, oxidized species of U, V, Se, Mo, As are carried together as oxyanions; these species precipitate in a restricted range of Eh-pH when reducing conditions are met. Concomitant with removal of these species, due to formation of reduced, insoluble species, several other elements of interest are concentrated in the ore zones as well. Chalcophile elements, such as Cu, Co, Mn, Zn, Cd, Sb, and others are fixed in authigenic sulfide phases, and the alkalis Rb, K, and Cs are fixed in the authigenic illite and illitic mixed layer clays. The alkaline earth elements Sr and Ba are commonly fixed in sulfate-rich rock. The rare earth elements (REE) are incorporated into authigenic clay minerals or into oxy-hydroxide phases. (author)

Geology of the north end of the Salt Valley Anticline, Grand County, Utah

International Nuclear Information System (INIS)

Gard, L.M. Jr.

1976-01-01

The geology and hydrology of a portion of the Salt Valley anticline lying north of Moab, Utah, that is being studied as a potential site for underground storage of nuclear waste in salt are discussed. Selection of this area was based on recommendations made in an earlier appraisal of the potential of Paradox basin salt deposits for such use. Salt Valley anticline, a northwest-trending diapiric structure, consists of Mesozoic sedimentary rocks arched over a thick core of salt of the Paradox Member of the Middle Pennsylvanian Hermosa Formation. Salt began to migrate to form and/or develop this structure shortly after it was deposited, probably in response to faulting. This migration caused upwelling of the salt creating a linear positive area. This positive area, in turn, caused increased deposition of sediments in adjacent areas which further enhanced salt migration. Not until late Jurassic time had flowage of the salt slowed sufficiently to allow sediments of the Morrison and younger formations to be deposited across the salt welt. A thick cap of insoluble residue was formed on top of the salt diapir as a result of salt dissolution through time. The crest of the anticline is breached; it collapsed in two stages during the Tertiary Period. The first stage was graben collapse during the early Tertiary; the second stage occurred after Miocene regional uplift had caused downcutting streams to breach the salt core resulting in further collapse. The axis of the anticline is a narrow generally flat-floored valley containing a few hills composed of downdropped Mesozoic rocks foundered in thecaprock. The caprock, which underlies thin alluvium in the valley, is composed of contorted gypsum, shale, sandstone, and limestone--the insoluble residue of the Paradox salt

Integrated geomechanical, petrographical and petrophysical study of the sandstones of the Wajid Group, SW Saudi Arabia

Science.gov (United States)

Benaafi, Mohammed; Hariri, Mustafa; Al-Shaibani, Abdulaziz; Abdullatif, Osman; Makkawi, Mohammed

2018-07-01

The Cambro-Permian siliciclastic succession in southwestern Saudi Arabia is represented by the Wajid Group, which consists mainly of fluvial, shallow marine, aeolian, and glacial sandstones. The Wajid Group comprises the Dibsiyah, Sanamah, Qalibah, Khusayyayn, and Juwayl Formations. It is exposed in the Wadi Al-Dawasir area and extends to Najran City. The sandstones of the Wajid Group serve as groundwater aquifers in the Wadi Al-Dawasir and Najran areas and host hydrocarbon (mainly gas) reservoirs in the Rub' Al-Khali Basin. This study aims to characterize the geomechanical properties (rock strength and Young's modulus) of the sandstones of the Wajid Group using field and experimental techniques. A further objective is to investigate the relationships between the geomechanical properties and the petrographical and petrophysical properties of the studied sandstones. The geomechanical properties of the studied sandstones vary from glacial to non-glacial sandstones, as the glacial sandstones display high values of the geomechanical properties with high variability indices. Four geological factors including grain size, cement content, porosity and permeability were observed as the main controls on the geomechanical behaviour of the studied sandstones except for the Khusayyayn sandstone, where the mineral composition was also important. Significant correlations were observed between the petrographical and petrophysical properties and the geomechanical properties of the glacial sandstones. Predictive models of the geomechanical properties (RN, UCS, and E) were generated using regression analysis to account for the glacial sandstones.

CO2 Storage Potential of the Eocene Tay Sandstone, Central North Sea, UK

Science.gov (United States)

Gent, Christopher; Williams, John

2017-04-01

Carbon Capture and Storage (CCS) is crucial for low-carbon industry, climate mitigation and a sustainable energy future. The offshore capacity of the UK is substantial and has been estimated at 78 Gt of CO2 in saline aquifers and hydrocarbon fields. The early-mid Eocene Tay Sandstone Member of the Central North Sea (CNS) is a submarine-fan system and potential storage reservoir with a theoretical capacity of 123 Mt of CO2. The Tay Sandstone comprises of 4 sequences, amalgamating into a fan complex 125km long and 40 km at a minimum of 1500 m depth striking NW-SE, hosting several hydrocarbon fields including Gannett A, B, D and Pict. In order to better understand the storage potential and characteristics, the Tay Sandstone over Quadrant 21 has been interpreted using log correlation and 3D seismic. Understanding the internal and external geometry of the sandstone as well as the lateral extent of the unit is essential when considering CO2 vertical and horizontal fluid flow pathways and storage security. 3D seismic mapping of a clear mounded feature has revealed the youngest sequence of the Tay complex; a homogenous sand-rich channel 12 km long, 1.5 km wide and on average 100 m thick. The sandstone has porosity >35%, permeability >5 D and a net to gross of 0.8, giving a total pore volume of 927x106 m3. The remaining three sequences are a series of stacked channels and interbedded mudstones which are more quiescent on the seismic, however, well logs indicate each subsequent sequence reduce in net to gross with age as mud has a greater influence in the early fan system. Nevertheless, the sandstone properties remain relatively consistent and are far more laterally extensive than the youngest sequence. The Tay Sandstone spatially overlaps several other potential storage sites including the older Tertiary sandstones of the Cromarty, Forties and Mey Members and deeper Jurassic reservoirs. This favours the Tay Sandstone to be considered in a secondary or multiple stacked

Formation factor in Bentheimer and Fontainebleau sandstones: Theory compared with pore-scale numerical simulations

Science.gov (United States)

Ghanbarian, Behzad; Berg, Carl F.

2017-09-01

Accurate quantification of formation resistivity factor F (also called formation factor) provides useful insight into connectivity and pore space topology in fully saturated porous media. In particular the formation factor has been extensively used to estimate permeability in reservoir rocks. One of the widely applied models to estimate F is Archie's law (F = ϕ- m in which ϕ is total porosity and m is cementation exponent) that is known to be valid in rocks with negligible clay content, such as clean sandstones. In this study we compare formation factors determined by percolation and effective-medium theories as well as Archie's law with numerical simulations of electrical resistivity on digital rock models. These digital models represent Bentheimer and Fontainebleau sandstones and are derived either by reconstruction or directly from micro-tomographic images. Results show that the universal quadratic power law from percolation theory accurately estimates the calculated formation factor values in network models over the entire range of porosity. However, it crosses over to the linear scaling from the effective-medium approximation at the porosity of 0.75 in grid models. We also show that the effect of critical porosity, disregarded in Archie's law, is nontrivial, and the Archie model inaccurately estimates the formation factor in low-porosity homogeneous sandstones.

Anthropogenic salts from deteriorated stones of a historical monument (Kraków, Poland)

Science.gov (United States)

Marszałek, Mariola; Prajer, Marta

2017-04-01

The results focus on the stone architectonic elements of the Hebdowski Palace in the Okół, an old, medieval part of Kraków. The object was built around 1400, then rebuilt at the turn of the 17th century and at the first half of the 19th century. Its façade was covered with plaster, whose scaling fragments prior to the renovation in 2015 revealed underneath bricks, particularly in the lower part of the palace. The sandstone elements were used in the main portal, while the limestone ones in window frames of the lower section of the façade, base mouldings, and the buttresses at the corner of Poselska and Senacka streets (one of the oldest streets in Kraków). The stone blocks show various forms of damage, ranging from the accumulation of black crusts and efflorescences to crumbling and scaling of their surfaces. Optical microscopy, scanning electron microscopy (SEM-EDS), micro-Raman spectroscopy and X-ray diffractometry (XRD) were used for analysing deterioration products of the stone samples that were collected during the restoration campaign of 2015. The salt minerals detected in the efflorescences and the black crusts include mainly gypsum CaSO4•2H2O and halite NaCl. On the surface of the limestone gypsum is accompanied by oxalates (whewellite CaC2O4•H2O and/or weddellite CaC2O4•2H2O). The black crust developed on both stone types also contain numerous dust particles and a carbonaceous matter, probably soot. The origin of the anthropogenic salts can be mainly assigned to air pollution, to the stones themselves (mainly in the case of the limestone), and to migration of ions from some elements of the façade (e.g. plaster) in the case of the sandstone. The chemicals used for removing ice from streets and pavements (chiefly NaCl and CaCl2) also seem to be important in the formations of the salts. Finally, the existence of simple life forms, such as lichens and fungi, could result in the precipitation of oxalates. This work has been financially supported by

Study of the Effect of Clay Particles on Low Salinity Water Injection in Sandstone Reservoirs

Directory of Open Access Journals (Sweden)

Sina Rezaei Gomari

2017-03-01

Full Text Available The need for optimal recovery of crude oil from sandstone and carbonate reservoirs around the world has never been greater for the petroleum industry. Water-flooding has been applied to the supplement primary depletion process or as a separate secondary recovery method. Low salinity water injection is a relatively new method that involves injecting low salinity brines at high pressure similar to conventional water-flooding techniques, in order to recover crude oil. The effectiveness of low salinity water injection in sandstone reservoirs depends on a number of parameters such as reservoir temperature, pressure, type of clay particle and salinity of injected brine. Clay particles present on reservoir rock surfaces adsorb polar components of oil and modify wettability of sandstone rocks to the oil-wet state, which is accountable for the reduced recovery rates by conventional water-flooding. The extent of wettability alteration caused by three low salinity brines on oil-wet sandstone samples containing varying clay content (15% or 30% and type of clay (kaolinite/montmorillonite were analyzed in the laboratory experiment. Contact angles of mica powder and clay mixture (kaolinite/montmorillonite modified with crude oil were measured before and after injection with three low salinity sodium chloride brines. The effect of temperature was also analyzed for each sample. The results of the experiment indicate that samples with kaolinite clay tend to produce higher contact angles than samples with montmorillonite clay when modified with crude oil. The highest degree or extent of wettability alteration from oil-wet to intermediate-wet state upon injection with low salinity brines was observed for samples injected with brine having salinity concentration of 2000 ppm. The increase in temperature tends to produce contact angles values lying in the higher end of the intermediate-wet range (75°–115° for samples treated at 50 °C, while their corresponding

GREYBULL SANDSTONE PETROLEUM POTENTIAL ON THE CROW INDIAN RESERVATION, SOUTH-CENTRAL MONTANA

Energy Technology Data Exchange (ETDEWEB)

David A. Lopez

2000-12-14

Evaluation of the Lower Cretaceous Greybull Sandstone on the Crow Indian Reservation for potential stratigraphic traps in the valley-fill sandstone was the focus of this project. The Crow Reservation area, located in south-central Montana, is part of the Rocky Mountain Foreland structural province, which is characterized by Laramide uplifts and intervening structural basins. The Pryor and Bighorn mountains, like other foreland uplifts, are characterized by asymmetrical folds associated with basement-involved reverse faults. The reservation area east of the mountains is on the northwestern flank of the Powder River Basin. Therefore, regional dips are eastward and southeastward; however, several prominent structural features interrupt these regional dips. The nearly 4,000 mi{sup 2} reservation is under explored but has strong potential for increased oil and gas development. Oil and gas production is well established in the Powder River Basin of Wyoming to the south as well as in the areas north and west of the reservation. However, only limited petroleum production has been established within the reservation. Geologic relations and trends indicate strong potential for oil and gas accumulations, but drilling has been insufficient for their discovery. The Greybull Sandstone, which is part of the transgressive systems tract that includes the overlying Fall River Sandstone, was deposited on a major regional unconformity. The erosional surface at the base of the Greybull Sandstone is the +100 Ma, late Aptian-Early Albian regional unconformity of Weimer (1984). This lowstand erosional surface was controlled by a basin-wide drop in sea level. In areas where incised Greybull channels are absent, the lowstand erosional unconformity is at the base of the Fall River Sandstone and equivalent formations. During the pre-Greybull lowstand, sediment bypassed this region. In the subsequent marine transgression, streams began to aggrade and deposit sand of the lower Greybull Sandstone

Numerical simulation of roadway support in a sandstone-type uranium mine

International Nuclear Information System (INIS)

Liu Huipeng; Li Yu; Song Lixia

2009-01-01

At present, the most surrounding rocks of sandstone-type uranium mines in China are mudstone, sandstone, pelitic siltstone, and so on. They show the characteristics of soft rock. Such uranium deposit is not fit for in-situ leaching. If the uranium ores are mined by conventional mining method, one of the problems to be solved is the support technique in the soft rock roadway. So, taking a uranium mine in Inner Mongolia as the research object, the support technique in the soft rock roadway of the sandstone-type uranium deposits is studied. Through on-site engineering geological investigation and laboratory test, the main reasons for roadway damage are analyzed. A technique of support in the soft rock roadway of sandstone-type uranium deposits is put forward by drawing on the expericnce of soft rock roadway support in coal mines. The roadway shape and support parameters are optimized by using a numerical simulation method. The results verified the feasibility of the supporting technique. (authors)

Sediment transport direction in fluviatile Karharbari sandstone, Giridih Basin, Bihar

Energy Technology Data Exchange (ETDEWEB)

Tewari, R C; Casshyap, S M

1978-01-01

The sandstone is pebbly, very coarse grained in the lower part, and coarse to medium grained in the upper part. Shale and coal respectively constitute 9 and 5% of the strata Small and large erosional channels and successive sets of large scale cross-bedding characterize the sandstone. Palaeo- currents reveal that the paleodrainage and sediment transport were dominantly directed from SSW to NNE.

Utilisation of Sand from Kaolin Washing for the Manufacture of Alkali-activated Artificial Sandstone

Science.gov (United States)

Vavro, Martin; Vavro, Leona; Mec, Pavel; Soucek, Kamil; Pticen, Frantisek; Reiterman, Pavel

2017-04-01

Sandstones represent a traditional natural stones which are widely used in Czech architecture and sculpture over a long time. Thanks to their relatively easy workability, sandstones provide a wide range of stone products and also represent a popular material for architectural and sculptural purposes. In the field of restoration of artworks, they are therefore often used for manufacturing stone statue copies originally made from the same or similar type of stone. Despite a relatively common and varied occurrence of natural sandstones, the method of the artificial stone facsimiles creation in the form of various cast elements is also often applied in restoration practice. The history of application of artificial stones in civil engineering and architecture goes back to the ancient times, i.e. to Roman antiquity and possibly up to the time of ancient Egypt. The lack of appropriate natural rock, suitable in the view of colour, grain size or texture is the main reason of manufacturing copies based on synthetic mixtures. The other reason is high financial costs to create a sculpture copy from natural materials. Mixtures made from white and/or grey cements, sands, carefully selected crushed stone or well graded natural gravels, and mineral coloring pigments or mixtures with acrylate, polyester, and epoxy resins binder are the most frequently used artificial materials for cast stone manufacturing. This paper aims to bring information about composition and properties of artificial sandstones made from alkali-activated binder mixtures based on metakaolin and granulated blast furnace slag. The filler of this artificial stone is represented by fine-grained sand generated during kaolin wet processing. Used sand is mainly formed by quartz, feldspars, micas (muscovite > biotite), residual kaolin, and to a lesser extent also by Fe oxyhydroxides ("limonite"), titanium dioxide mineral (probably anatase), and carbonate mineral unidentified in detail. Annual Czech production of this

Middle Ordovician brachiopods from the Stairway Sandstone, Amadeus Basin, central Australia

DEFF Research Database (Denmark)

Jakobsen, Kristian Grube; Brock, Glenn A.; Nielsen, Arne Thorshøj

2014-01-01

-water palaeoenvironment along the margin of northeastern Gondwana. The brachiopods from the Stairway Sandstone are of low diversity and represent ca 9% of the entire shelly fauna. Five brachiopod taxa are described from the Stairway Sandstone; all are endemic to the Amadeus Basin at species level. Two new species...

Application potential of sequence stratigraphy to prospecting for sandstone-type uranium deposit in continental depositional basins

International Nuclear Information System (INIS)

Li Shengxiang; Chen Zhaobo; Chen Zuyi; Xiang Weidong; Cai Yuqi

2001-01-01

Sequence stratigraphy has been widely used in hydrocarbon exploration and development, and great achievements have been achieved. However, its application to the prospecting for sandstone-type uranium deposits is just beginning. The metallogenic characteristics of sandstone-type uranium deposits and those of oil and gas are compared, and the relationship between sandstone-type uranium metallogenesis and the system tracts of sequence stratigraphy is studied. The authors propose that highest and system tracts are the main targets for prospecting interlayer oxidation zone type sandstone uranium deposits, and the incised valleys of low stand system tracts are favourable places for phreatic oxidation zone type sandstone uranium deposits, and transgressive system tracts are generally unfavorable to the formation of in-situ leachable sandstone-type uranium deposits. Finally, the authors look ahead the application potential of sequence stratigraphy to the prospecting for sandstone-type uranium deposits in continental depositional basins

Fluoride salts and container materials for thermal energy storage applications in the temperature range 973 to 1400 K

Science.gov (United States)

Misra, Ajay K.; Whittenberger, J. Daniel

1987-01-01

Multicomponent fluoride salt mixtures were characterized for use as latent heat of fusion heat storage materials in advanced solar dynamic space power systems with operating temperatures in the range of 973 to 1400 K. The melting points and eutectic composition for many systems with published phase diagrams were verified, and several new eutectic compositions were identified. Additionally, the heats of fusion of several binary and ternary eutectics and congruently melting intermediate compounds were measured by differential scanning calorimetry. The extent of corrosion of various metals by fluoride melts was estimated from thermodynamic considerations, and equilibrium conditions inside a containment vessel were calculated as functions of the initial moisture content of the salt and free volume above the molten salt. Preliminary experimental data on the corrosion of commercial, high-temperature alloys in LiF-19.5CaF2 and NaF-27CaF2-36MgF2 melts are presented and compared to the thermodynamic predictions.

Discussion on metallogenic prospect of sandstone-type uranium deposit in Yabulai basin

International Nuclear Information System (INIS)

Wang Lianshe; Li Xiangping

2003-01-01

Based on characteristics of initial basin type and tectonic reworking process, this article analyses the distribution features of depositional system and subsequent alteration of the target horizon of sandstone-type uranium deposits in Yabulai basin. Guided by prognostic criteria of sandstone-type uranium deposits, authors suggest that the post-depositional tectonic reworking in the basin was quite intense, and uranium metallogenic prospects are unfavorable. However, the Lower Cretaceous in the paleo-slope at the middle of the basin does show certain metallogenic prospects for sandstone-type uranium deposits

Experimental measurements of the SP response to concentration and temperature gradients in sandstones with application to subsurface geophysical monitoring

Science.gov (United States)

Leinov, E.; Jackson, M. D.

2014-09-01

Exclusion-diffusion potentials arising from temperature gradients are widely neglected in self-potential (SP) surveys, despite the ubiquitous presence of temperature gradients in subsurface settings such as volcanoes and hot springs, geothermal fields, and oil reservoirs during production via water or steam injection. Likewise, with the exception of borehole SP logging, exclusion-diffusion potentials arising from concentration gradients are also neglected or, at best, it is assumed that the diffusion potential dominates. To better interpret these SP sources requires well-constrained measurements of the various coupling terms. We report measurements of thermoelectric and electrochemical exclusion-diffusion potentials across sandstones saturated with NaCl brine and find that electrode effects can dominate the measured voltage. After correcting for these, we find that Hittorf transport numbers are the same within experimental error regardless of whether ion transport occurs in response to temperature or concentration gradients over the range of NaCl concentration investigated that is typical of natural systems. Diffusion potentials dominate only if the pore throat radius is more than approximately 4000 times larger than the diffuse layer thickness. In fine-grained sandstones with small pore throat diameter, this condition is likely to be met only if the saturating brine is of relatively high salinity; thus, in many cases of interest to earth scientists, exclusion-diffusion potentials will comprise significant contributions from both ionic diffusion through, and ionic exclusion from, the pore space of the rock. However, in coarse-grained sandstones, or sandstones saturated with high-salinity brine, exclusion-diffusion potentials can be described using end-member models in which ionic exclusion is neglected. Exclusion-diffusion potentials in sandstones depend upon pore size and salinity in a complex way: they may be positive, negative, or zero depending upon sandstone

Multidisciplinary studies on ancient sandstone quarries of Western Sardinia (Italy).

Science.gov (United States)

Grillo, Silvana Maria; Del Vais, Carla; Naitza, Stefano

2013-04-01

The ancient coastal quarries of Mediterranean are increasingly considered geosites of multidisciplinary relevance. They are sites of historical-archaeological interest that show ancient techniques of stone extraction; they are significant for cultural heritage conservation and restoration, as sources of the stones used in ancient buildings and monuments; they are sites of geological relevance, as often retain important stratigraphic sections; they are also useful markers of secular changes in the sea level. A multisciplinary study is in progress on the ancient quarries of the Sinis region (western Sardinia island), integrating archaeological, geological, minero-petrographical data. In Sardinia, coastal quarries have been established from Punic and Roman times. Many of them exploited Quaternary sediments along the southern and western coasts of the island. They consist of middle-late Pleistocene marine conglomerates and carbonate sandstones, and of coastal (aeolian) carbonate sandstones. Sandstone blocks of different sizes have been widely used in ancient cities for buildings, defensive works, harbours, etc. Three main areas of stone extraction (San Giovanni di Sinis, Punta Maimoni, Is Arutas) have been so far recognized in the Sinis. GIS-supported mapping and documentation of the sites includes their geology and stratigraphy, the extension and layout of the quarries, and an evaluation of volumes of extracted rocks. Documented archaeological evidences include ancient extraction fronts, spoil heaps, working areas, working traces in the old fronts, transport routes of blocks, and traces of loading facilities. The study is aimed at reconstructing the relationships of the quarries with the urban areas of Sinis, as the ancient Punic-Roman city of Tharros. Consequently, a minero-petrographical characterization (optical microscopy, XRD) is performed on sandstones sampled in each quarry, and in historical buildings in Tharros and other centres of the region (Cabras

Diagenetic controls on porosity variations within an aeolian sandstone reservoir, borehole Kudu 9A-3

International Nuclear Information System (INIS)

Marot, J.E.B.

1990-01-01

Three boreholes, Kudu 9A-1, 9A-2 and 9A-3, were drilled approximately 125 km west of the Orange River mouth to test a gas-bearing structure of Barremian age. The reservoir interval comprises an upper unit of interbedded shallow marine sandstones, limestones and volcaniclastic mass flow deposits, and a lower non-marine unit of interbedded aeolian sandstones, basaltic lavas and volcaniclastic deposits. Despite the overall good poroperm characteristics of the aeolian sandstone and its apparent mineralogical homogeneity, as implied by a gamma ray trace, the core analysis results show an extreme variation in porosity and permeability values. In order to assist in reservoir quality prediction and to assess the regional prospectivity of the sandstone, it was necessary to explain these variations. The resuls of the study indicate that compositionally and texturally the sandstones are extremely homogeneous. It is concluded that the marked variation in the poroperm characteristics of the aeolian sandstones is a result of a relatively complex diagenesis. A fluctuating water table resulted in the formation of a pattern of calcite, anhydrite and quartz cements within an aeolian dune sandstone. 7 refs., 1 fig

Characteristics of isotope geology of sandstone-type uranium deposit in Turpan-Hami Basin

International Nuclear Information System (INIS)

Liu Hanbin; Xia Yuliang; Lin Jinrong; Fan Guang

2003-01-01

This paper expounds the isotope characteristics of in-situ leachable sandstone-type uranium deposit of Shihongtan in the southwestern part of Turpan-Hami basin. The results suggest that uranium mineralization age of 48 ± 2 Ma and 28 ± 4 Ma are obtained. The ages of the porphyritic granite and gneissic granite from the southwestern area are 422 ± 5 Ma and 268 ± 23 Ma. The U-Pb age of clastic zircons from ore-bearing sandstone is 283 ± 67 Ma, which is corresponding to the age of gneissic granite of the provenance area indicating the material source of uraniferous sandstone.Based. The sources are uraniferous sandstone accumulated during the deposition and the uranium leached from provenance area rocks by weathering. (authors)

Pore network properties of sandstones in a fault damage zone

Science.gov (United States)

Bossennec, Claire; Géraud, Yves; Moretti, Isabelle; Mattioni, Luca; Stemmelen, Didier

2018-05-01

The understanding of fluid flow in faulted sandstones is based on a wide range of techniques. These depend on the multi-method determination of petrological and structural features, porous network properties and both spatial and temporal variations and interactions of these features. The question of the multi-parameter analysis on fluid flow controlling properties is addressed for an outcrop damage zone in the hanging wall of a normal fault zone on the western border of the Upper Rhine Graben, affecting the Buntsandstein Group (Early Triassic). Diagenetic processes may alter the original pore type and geometry in fractured and faulted sandstones. Therefore, these may control the ultimate porosity and permeability of the damage zone. The classical model of evolution of hydraulic properties with distance from the major fault core is nuanced here. The hydraulic behavior of the rock media is better described by a pluri-scale model including: 1) The grain scale, where the hydraulic properties are controlled by sedimentary features, the distance from the fracture, and the impact of diagenetic processes. These result in the ultimate porous network characteristics observed. 2) A larger scale, where the structural position and characteristics (density, connectivity) of the fracture corridors are strongly correlated with both geo-mechanical and hydraulic properties within the damage zone.

Applying reaction condition index to predict sandstone type uranium deposit

International Nuclear Information System (INIS)

Chen Gongxin; Liu Jinhui; Cheng Hai

2002-01-01

On the basic of the explanation of reaction condition index, the deduction of reaction condition index calculation principle, the hydrogeological setting in Gongpoquan basin in Baishan, Gansu province and the study of reaction condition index of its water source point, the north Luotuoquan area in Gongpoquan basin seems to be a favourable place for sandstone type uranium deposit, and the prospect area for sandstone type uranium deposit is delimitated

High-resolution 3D X-ray microtomography as tool to investigate size distribution of grain phase and pore space in sandstones

Science.gov (United States)

Kahl, Wolf-Achim; Holzheid, Astrid

2013-04-01

The geometry and internal structures of sandstone reservoirs, like grain size, sorting, degree of bioturbation, and the history of the diagenetic alterations determine the quantity, flow rates, and recovery of hydrocarbons present in the pore space. In this respect, processes influencing the deep reservoir quality in sandstones are either of depositional, shallow diagenetic, or deep-burial origin. To assess the effect of compaction and cementation on the pore space during diagenesis, we investigated a set of sandstone samples using high-resolution microtomography (µ-CT). By high-resolution µ-CT, size distributions (in 2D and 3D), surface areas and volume fractions of the grain skeleton and pore space of sandstones and - in addition - of mineral powders have been determined. For this study, we analysed aliquots of sandstones that exhibit either complete, partial or no cemententation of the pore space, and sets of mineral powders (quartz, feldspar, calcite). As the resolution of the µ-CT scans is in the µm-range, the surface areas determined for sandstones and powders do detect the geometric surface of the material (Kahl & Holzheid, 2010). Since there are differing approaches to "size" parameters like e.g., long/short particle axes, area equivalent radius, Feret-diameter (2D), and structural thickness (3D), we decided to illustrate the effect of various size determinations for (a) single grains, (b) grain skeletons, and (c) pore space. Therefor, the computer-aided morphometric analysis of the segmented 3D models of the reconstructed scan images comprises versatile calculation algorithms. For example, size distribution of the pore space of partially cemented sandstones can be used to infer the timing of the formation of the cement in respect to tectonic/diagenetic activities. In the case of a late-stage partial cementation of a Bunter sandstone, both pore space and cement phase show identical size distributions. On the contrary, the anhydrite cement of a

Sedimentological Characteristics and Re-interpretation of the Paleoenvironment of Lokoja Sandstone, Southern Bida Basin, Nigeria

International Nuclear Information System (INIS)

Ojo, O. J.; Akande, S. O.

2002-01-01

Detail mapping of the Lokoja Formation consisting predominantly of sandstones exposed along Okene-Abuja highway near the confluence of Rivers Niger and Benue in the southern Bida Basin was undertaken in an attempt to reconstruct their depositional history. The analyses of the lithofacies characteristics, pebble morphogenesis and ichnofossil content of the Lokoja sandstones in the study area reveal their depositional environments which evolved from alluvial fans through braided stream into nearshore shallow marine conditions. The massive, immature, matrix to grain supported conglomerate subfacies can be interpreted as debris flow. The conglomeratic sandstone facies (massive, cross stratified and graded subfacies) reflect deposits of deep braided channels. The bioturbated and herringbone cross stratified conglomeratic sandstones indicate shallowing to marginal marine environments. The fine to medium grained sandstones, siltstones and claystones are interpreted as channel bars and floodplain deposits.Results of pebble morphogenesis analysis indicate predominance of fluvial processes. Minor high energy (probably beach) condition is indicated by some individual clasts from the conglomeratic sandstone facies with sphericity and OP index values less that 0.66 and -1.5 respectively.The study is significant because it represents the first sedimentological evidence of influence of shallow marine in the development of Lokoja sandstones during Campanian-Maastrichtian times

PALEOEVIRONMENT OF NIGERIA'S AJALI SANDSTONES: A ...

African Journals Online (AJOL)

The Ajali Sandstone is a major clastic formation of Campanian-Maastrichtian age occuring within the Anambra Basin, Southeastern Nigeria. ... The result is in line with earlier conclusions of fluvial or fluviodeltaic depositional environment based on analysis of faceis, sedimentary rock which are suitable for morphometrical ...

The Bentheim Sandstone: Geology, petrophysics, varieties and it's use as dimension stone

NARCIS (Netherlands)

Dubelaar, C.W.; Nijland, T.G.

2014-01-01

The shallow-marine Bentheim Sandstone was deposited in one of the NW-SE trending basins north of the London-Brabant and Rhenish massifs during the Valanginian (Early Cretaceous). The Bentheim Sandstone forms an important reservoir rock for petroleum, but has also proven itself as a very durable

On the water saturation calculation in hydrocarbon sandstone reservoirs

Energy Technology Data Exchange (ETDEWEB)

Stalheim, Stein Ottar

2002-07-01

The main goal of this work was to identify the most important uncertainty sources in water saturation calculation and examine the possibility for developing new S{sub w} - equations or possibility to develop methods to remove weaknesses and uncertainties in existing S{sub w} - equations. Due to the need for industrial applicability of the equations we aimed for results with the following properties: The accuracy in S{sub w} should increase compared with existing S{sub w} - equations. The equations should be simple to use in petrophysical evaluations. The equations should be based on conventional logs and use as few as possible input parameters. The equations should be numerical stable. This thesis includes an uncertainty and sensitivity analysis of the most common S{sub w} equations. The results are addressed in chapter 3 and were intended to find the most important uncertainty sources in water saturation calculation. To increase the knowledge of the relationship between R{sub t} and S{sub w} in hydrocarbon sandstone reservoirs and to understand how the pore geometry affects the conductivity (n and m) of the rock a theoretical study was done. It was also an aim to examine the possibility for developing new S{sub w} - equations (or investigation an effective medium model) valid inhydrocarbon sandstone reservoirs. The results are presented in paper 1. A new equation for water saturation calculation in clean sandstone oil reservoirs is addressed in paper 2. A recommendation for best practice of water saturation calculation in non water wet formation is addressed in paper 3. Finally a new equation for water saturation calculation in thinly interbedded sandstone/mudstone reservoirs is presented in paper 4. The papers are titled: 1) Is the saturation exponent n a constant. 2) A New Model for Calculating Water Saturation In 3) Influence of wettability on water saturation modeling. 4) Water Saturation Calculations in Thinly Interbedded Sandstone/mudstone Reservoirs. A

Thermophysical properties of reconsolidating crushed salt.

Energy Technology Data Exchange (ETDEWEB)

Bauer, Stephen J. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Urquhart, Alexander [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

2014-03-01

Reconsolidated crushed salt is being considered as a backfilling material placed upon nuclear waste within a salt repository environment. In-depth knowledge of thermal and mechanical properties of the crushed salt as it reconsolidates is critical to thermal/mechanical modeling of the reconsolidation process. An experimental study was completed to quantitatively evaluate the thermal conductivity of reconsolidated crushed salt as a function of porosity and temperature. The crushed salt for this study came from the Waste Isolation Pilot Plant (WIPP). In this work the thermal conductivity of crushed salt with porosity ranging from 1% to 40% was determined from room temperature up to 300°C, using two different experimental methods. Thermal properties (including thermal conductivity, thermal diffusivity and specific heat) of single-crystal salt were determined for the same temperature range. The salt was observed to dewater during heating; weight loss from the dewatering was quantified. The thermal conductivity of reconsolidated crushed salt decreases with increasing porosity; conversely, thermal conductivity increases as the salt consolidates. The thermal conductivity of reconsolidated crushed salt for a given porosity decreases with increasing temperature. A simple mixture theory model is presented to predict and compare to the data developed in this study.

Mesozoic-Cenozoic tectonic evolution and its relation to sandstone-type uranium mineralization in northern Tarim area--Evidence from apatite fission track

International Nuclear Information System (INIS)

Liu Hongxu; Dong Wenming; Liu Zhangyue; Chen Xiaolin

2009-01-01

The apatite fission track dating and inversion result of geological thermal history of four rock specimens from Sawafuqi area and Talike area in northern Tarim Basin show that two areas uplifted at different ages. The apatite fission track ages of Sawafuqi range from 3.5 to 3.9 Ma, while the ages of Talike range from 53 to 59 Ma. The thermal history recorded by rock samples reveals that there are at least three prominent cooling phases since Late Cretaceous epoch. Detailed study was made on the division of uplifting stages during Mesozoic and Cenozoic tectonic evolution with the existing data in northern Tarim area. And new ideas on tectonic evolution and sandstone-type uranium mineralization have been put forward by combining with the sandstone-type uranium mineralization ages in this area.(authors)

Preliminary study on features of mineralogical zoning of epigenetic alteration at sandstone-type uranium deposit, Dongsheng area, Ordos basin

International Nuclear Information System (INIS)

Xiao Xinjian; Li Ziying; Chen Anping

2004-01-01

Sandstone-type uranium deposits located in Dongsheng area, northern Ordos basin, occur in Zhiluo Formation, Middle Jurassic. The Zhiluo Formation is divided into two members. The lower member is further divided into two submembers. The lower submember is dominantly composed of grey sandstone being the ore-hosting horizon; the upper submember consists of grey-green sandstone and mudstone. The upper member of Zhiluo Formation is made of mottled medium-fine grained sandstone and mudstone. Through the microscopic observation and study on sandstones of Zhiluo Formation, authors have established a vertical zonation of epigenetic alteration (from the top to the bottom): the limonitization + clayization + carbonation in the mottled fine-grained sandstone of the upper member of Zhiluo Formation; the green alteration (II) (mainly the chloritization of biotite, as well as the chloritization and epidotization of feldspar) + clayization + carbonation in the grey-green sandstone of the upper submember of the lower member of Zhiluo Formation; and the green alteration (I) (mainly the epidotization of feldspar) + carbonation in grey, grey-white sandstone of the lower submember. The epigenetic alteration basically occurs in grey-green sandstone. The sandstone shows grey-green color because it contains much green biotite (not chlorite). The epigenetic alteration in sandstone layer is closely associated with the uranium ore-formation

Microbial mat structures in profile: The Neoproterozoic Sonia Sandstone, Rajasthan, India

Science.gov (United States)

Samanta, Pradip; Mukhopadhyay, Soumik; Mondal, Anudeb; Sarkar, Subir

2011-01-01

Ubiquitous microorganisms, especially cyanobacteria preferably grow on the sediment surface thereby producing microbial mats. In the absence of grazers and bioturbators, microbial mat is a unique feature of the Proterozoic. Most of the papers so far published described a wide variety of bed surface microbial mat structures with rare illustrations from sections perpendicular to bedding. Nonetheless, bed surface exposures are relatively rare in rock records. This limitation of bed surface exposures in rock records suggest that a study of microbial mats in bed-across sections is needed. The 60 m thick coastal marine interval of the Sonia Sandstone Formation is bounded between two terrestrial intervals, a transgressive lag at the base and an unconformity at the top, and has been chosen for exploration of microbial mat structures in bed-across sections. A wide variety of microbial mat-induced structures in bed-across sections are preserved within the coastal interval of the Sonia Sandstone. Though many of these structures are similar in some aspects with bed surface structures, some of those presented here are new. The palaeogeographic range of these microbial structures extends from supralittoral to neritic. Diagenetic alterations of microbial mats produce pyrite and those zones are suitable for the preservation of microbial remains. SEM and EDAX analyses show fossil preservation of filamentous microbial remains that confirm the presence of microbial mats within the coastal interval of the Sonia Sandstone. Effects of proliferation of microbial mats in the siliciclastic depositional setting are numerous. The mat-cover on sediment surfaces hinders reworking and/or erosion of the sediments thereby increases the net sedimentation rate. Successive deposition and preservation of thick microbial mat layer under reducing environments should have a great potential for hydrocarbon production and preservation and therefore these Proterozoic formations could be a target for

New Acid Combination for a Successful Sandstone Acidizing

Science.gov (United States)

Shafiq, M. U.; Mahmud, H. K. B.; Rezaee, R.

2017-05-01

With the development of new enhanced oil recovery techniques, sandstone acidizing has been introduced and played a pivotal role in the petroleum industry. Different acid combinations have been applied, which react with the formation, dissolve the soluble particles; thus increase the production of hydrocarbons. To solve the problems which occurred using current preflush sandstone acidizing technology (hydrochloric acid); a new acid combination has been developed. Core flooding experiments on sandstone core samples with dimensions 1.5 in. × 3 in. were conducted at a flow rate of 2 cm3/min. A series of hydrochloric-acetic acid mixtures with different ratios were tested under 150°F temperature. The core flooding experiments performed are aimed to dissolve carbonate, sodium, potassium and calcium particles from the core samples. These experiments are followed by few important tests which include, porosity-permeability, pH value, Inductively Coupled Plasma (ICP) analysis and Nuclear Magnetic Resonance (NMR measurements). All the results are compared with the results of conventional hydrochloric acid technology. NMR and porosity analysis concluded that the new acid combination is more effective in creating fresh pore spaces and thus increasing the reservoir permeability. It can be seen from the pore distribution before and after the acidizing. Prior applying acid; the large size of pores appears most frequently in the pore distribution while with the applied acid, it was found that the small pore size is most the predominant of the pore distribution. These results are validated using ICP analysis which shows the effective removal of calcium and other positive ions from the core sample. This study concludes that the combination of acetic-hydrochloric acid can be a potential candidate for the preflush stage of sandstone acidizing at high temperature reservoirs.

Heavy mineral sorting in downwards injected Palaeocene sandstone, Siri Canyon, Danish North Sea

DEFF Research Database (Denmark)

Kazerouni, Afsoon Moatari; Friis, Henrik; Svendsen, Johan Byskov

2011-01-01

Post-depositional remobilization and injection of sand are often seen in deep-water clastic systems and has been recently recognised as a significant modifier of deep-water sandstone geometry. Large-scale injectite complexes have been interpreted from borehole data in the Palaeocene Siri Canyon...... of depositional structures in deep-water sandstones, the distinction between "in situ" and injected or remobilised sandstones is often ambiguous. Large scale heavy mineral sorting (in 10 m thick units) is observed in several reservoir units in the Siri Canyon and has been interpreted to represent the depositional...... sorting. In this study we describe an example of effective shear-zone sorting of heavy minerals in a thin downward injected sandstone dyke which was encountered in one of the cores in the Cecilie Field, Siri Canyon. Differences in sorting pattern of heavy minerals are suggested as a tool for petrographic...

A new bee species that excavates sandstone nests.

Science.gov (United States)

Orr, Michael C; Griswold, Terry; Pitts, James P; Parker, Frank D

2016-09-12

Humanity has long been fascinated by animals with apparently unfavorable lifestyles [1]. Nesting habits are especially important because they can limit where organisms live, thereby driving population, community, and even ecosystem dynamics [2]. The question arises, then, why bees nest in active termite mounds [3] or on the rim of degassing volcanoes, seemingly preferring such hardship [4]. Here, we present a new bee species that excavates sandstone nests, Anthophora (Anthophoroides) pueblo Orr (described in Supplemental Information, published with this article online), despite the challenges already inherent to desert life. Ultimately, the benefits of nesting in sandstone appear to outweigh the associated costs in this system. Copyright © 2016 Elsevier Ltd. All rights reserved.

Architecture and quantitative assessment of channeled clastic deposits, Shihezi sandstone (Lower Permian, Ordos Basin, China

Directory of Open Access Journals (Sweden)

Chengye Jia

2017-02-01

Full Text Available Lower Permian Shihezi sandstone in Ordos Basin is the largest gas reservoir in China. Architecture elements of channel, overbank and floodplain facies of braided channel deposits were identified through an outcrops survey, and their proportion of channel facies have been quantitatively estimated from well logging. Characteristics of architecture elements, such as sand thickness, bounding surfaces and lithofacies were investigated through outcrops and core. Petrology of Shihezi sandstone has also been studied in detail. Analysis on sandstone components shows that monocrystalline quartz with approximately 76% bulk volume, and lithic up to 5%–45% bulk volume, are the two main components. Litharenite and lithic quartz sandstone are the main rock types. Compaction is concluded by former researchers as the control factor of low permeability. Examination through thin section reveals that secondary pores developed well in coarse sand. Inter-granular dissolution is included as the positive effect to increasing porosity, and is concluded as the control factor to the generation of net pay. Scale of coarse grained channel fills and channel bar sandstone bodies are quantitatively estimated. Strike-oriented, dip-oriented, and vertical distribution of channel fills and channel bar sandstone bodies have been investigated. The geometry of sand bodies can be depicted as an elongated lens. Subsurface mapping reveals that channel sandstone bodies distribute widely from both lateral and longitudinal cross section profiles, and are poorly connected.

Performance of Different Acids on Sandstone Formations

Directory of Open Access Journals (Sweden)

M. A. Zaman

2013-12-01

Full Text Available Stimulation of sandstone formations is a challenging task, which involves several chemicals and physical interactions of the acid with the formation. Some of these reactions may result in formation damage. Mud acid has been successfully used to stimulate sandstone reservoirs for a number of years. It is a mixture of hydrofluoric (HF and hydrochloric (HCl acids designed to dissolve clays and siliceous fines accumulated in the near-wellbore region. Matrix acidizing may also be used to increase formation permeability in undamaged wells. The change may be up to 50% to 100% with the mud acid. For any acidizing process, the selection of acid (Formulation and Concentration and the design (Pre-flush, Main Acid, After-flush is very important. Different researchers are using different combinations of acids with different concentrations to get the best results for acidization. Mainly the common practice is combination of Hydrochloric Acid – Hydrofluoric with Concentration (3% HF – 12% HCl. This paper presents the results of a laboratory investigation of Orthophosphoric acid instead of hydrochloric acid in one combination and the second combination is Fluoboric and formic acid and the third one is formic and hydrofluoric acid. The results are compared with the mud acid and the results calculated are porosity, permeability, and FESEM Analysis and Strength tests. All of these new combinations shows that these have the potential to be used as acidizing acids on sandstone formations.

Fluvial-deltaic sedimentation and stratigraphy of the ferron sandstone

Science.gov (United States)

Anderson, P.B.; Chidsey, T.C.; Ryer, T.A.

1997-01-01

East-central Utah has world-class outcrops of dominantly fluvial-deltaic Turonian to Coniacian aged strata deposited in the Cretaceous foreland basin. The Ferron Sandstone Member of the Mancos Shale records the influences of both tidal and wave energy on fluvial-dominated deltas on the western margin of the Cretaceous western interior seaway. Revisions of the stratigraphy are proposed for the Ferron Sandstone. Facies representing a variety of environments of deposition are well exposed, including delta-front, strandline, marginal marine, and coastal-plain. Some of these facies are described in detail for use in petroleum reservoir characterization and include permeability structure.

Geology of groundwater occurrences of the Lower Cretaceus sandstone aquifer in East Central Sinai, Egypt

Directory of Open Access Journals (Sweden)

Saad Younes Ghoubachi

2017-01-01

Full Text Available The present study focused on investigating the impact of geological setting on the groundwater occurrences of the Lower Cretaceous sandstone aquifer (Malha. The Lower Cretaceous sandstone aquifer is subdivided into 3 units according to their lithological characters for the first time in this present work. The study area is dissected by normal faults with their downthrown sides due north direction. The groundwater flows from southeast recharge area (outcrop to the northwest direction with an average hydraulic gradient of 0.0035. The hydraulic parameters of the Lower Cretaceous sandstone aquifer were determined and evaluated through 7 pumping tests carried out on productive wells. The Lower Cretaceous aquifer in the study area is characterized by moderate to high potential. The calculated groundwater volume of the Lower Cretaceous aquifer (6300 km2 in the study area attains about 300 bcm, while the estimated recharge to the same aquifer reaches about 44,500 m3/day with an annual recharge of 16 mcm/year. Expended Durov diagram plot revealed that the groundwater has been evolved from Mg-SO4 and Mg-Cl dissolution area types that eventually reached a final stage of evolution represented by a Na-Cl water type. This diagram helps also in identifying groundwater flow direction. The groundwater salinity ranges from 1082 ppm (Shaira to 1719 ppm (Nakhl, in the direction of groundwater movement towards north.

Age, sedimentary environments, and other aspects of sandstone and related host rocks for uranium deposits

International Nuclear Information System (INIS)

1983-01-01

Project II of the Uranium Geology Working Group was assigned to the study of sedimentary basins and sandstone - type uranium deposits. About 40% of the worlds's uranium resources are contained in sandstone-type deposits, which has led to extensive research. The research was carried out mainly by correspondence, and the results reported by 21 geologists from 10 nations are summarized in this report. It investigated five topics dealing with important aspects of the geology of uranium ores in sandstone host formations: age of host rock; partitioning of uranium between continental and marine sediments; latitude limitation on formation of sandstone deposits; effect of rock formation dip on sandstone ores; usefulness of stable isotope and fluid inclusion studies. The results of studies on these subjects form part of a wider programme of the Working Group, whose final results will be presented at the 27th International Geological Congress in Moscow in 1984

Electrical conductivity of sandstone, limestone, and granite

Energy Technology Data Exchange (ETDEWEB)

Duba, A.; Piwinskii, A.J.; Santor, M.; Weed, H.C.

1978-01-01

The electrical conductivity of cylindrical cores of Westerly granite, Indiana limestone and Nugget, St Peter and Kayenta sandstones was measured at about 25/sup 0/C in vacuo, in air, and after saturation in distilled water, tap water, and 0.1 M NaCl solution. The three-electrode technique with a guard ring and the two-electrode technique without a guard ring were used. Core aspect ratio over the range of 2.00 to 0.25, as well as frequency over the range of 50 Hz to 10 kHz, influences the conductivity of all rocks, especially those measured in vacuo. Measurements from water-saturated samples using a guard ring are not appreciably different from those obtained without a guard ring. The conductivity of rocks saturated in 0.1 M NaCl solution changes least with a change in aspect ratio; for these rocks a linear relationship, known as Archie's Law, exists between log porosity and log conductivity. No simple correlation was found between those factors in rocks saturated with tap or distilled water. Thus, it appears Archie's Law is of questionable value for correlating laboratory data from rocks saturated with low-conductivity fluids.

Sandstone Relief Geohazards and their Mitigation: Rock Fall Risk Management in the Bohemian Switzerland National Park

Czech Academy of Sciences Publication Activity Database

Vařilová, Zuzana; Zvelebil, J.

2005-01-01

Roč. 44, - (2005), s. 53-58 ISSN 1682-5519. [Sandstone Landscapes in Europe. Past, Present and Future. International Conference on Sandstone Landscapes /2./. Vianden, 25.05.2005-28.05.2005] Keywords : sandstones * rock-slope instability * rock fall * risk evalution and mitigation * monitoring net * remedial works Subject RIV: DO - Wilderness Conservation

Study of petrological characteristics of uranium-bearing sandstone in the south of ordos basin, China

International Nuclear Information System (INIS)

Tian Cheng; Jia Licheng; Li Song; Zhang Zimin

2007-01-01

This paper discusses the relation between uranium-bearing abundance and texture constituent of sedimentary rock, on the basis of the research of petrological characteristic of sandstone in the south of Ordos basin. The influence of infiltration of sandstone and uranium migration and accumulation by the major diagenesis of compaction and cementation, clay minerals evolution, corrosion and forming of secondary porosity are discussed. Uranium-bearing sandstones are divided into four types and their petrological characteristics are discussed. After mineralization conditions being summed up, the uranium-mineralization model of sandstone-type is built. Reliable petrological evidences for evaluating favourable uranium mineralization rich areas are furnished. (authors)

Rate type isotach compaction of consolidated sandstone

NARCIS (Netherlands)

Waal, J.A. de; Thienen-Visser, K. van; Pruiksma, J.P.

2015-01-01

Laboratory experiments on samples from a consolidated sandstone reservoir are presented that demonstrate rate type compaction behaviour similar to that observed on unconsolidated sands and soils. Such rate type behaviour can have large consequences for reservoir compaction, surface subsidence and

Molten salt reactor technology for long-range and wide-scale nuclear energy system

International Nuclear Information System (INIS)

Ignatiev, V.; Alexseev, P.; Menshikov, L.; Prusakov, V.; Subbotine, S.

1997-01-01

A possibility of creation of multi-component nuclear power system in which alongside with thermal and fast reactors, molten salt burner reactors, for incineration of weapon grade plutonium, some minor actinides and transmutation of some fission products will be presented. The purposes of this work are to review the present status of the molten salt reactor technology and innovative non-aqueous chemical processing methods, to indicate the importance of the uncertainties remaining, to identify the additional work needed, and to evaluate the probability of success in obtaining improved safety characteristics for new concept of molten salt - burner reactor with external neutron source. 8 refs., 3 figs., 2 tabs

Implications of diapir-derived detritus and gypsic paleosols in Lower Triassic strata near the Castle Valley salt wall, Paradox Basin, Utah

Science.gov (United States)

Lawton, Timothy F.; Buck, Brenda J.

2006-10-01

Gypsum-bearing growth strata and sedimentary facies of the Moenkopi Formation on the crest and NE flank of the Castle Valley salt wall in the Paradox Basin record salt rise, evaporite exposure, and salt-withdrawal subsidence during the Early Triassic. Detrital gypsum and dolomite clasts derived from the middle Pennsylvanian Paradox Formation were deposited in strata within a few kilometers of the salt wall and indicate that salt rise rates roughly balanced sediment accumulation, resulting in long-term exposure of mobile evaporite. Deposition took place primarily in flood-basin or inland sabkha settings that alternated between shallow subaqueous and subaerial conditions in a hyperarid climate. Matrix-supported and clast-supported conglomerates with gypsum fragments represent debris-flow deposits and reworked debris-flow deposits, respectively, interbedded with flood-basin sandstone and siltstone during development of diapiric topography. Mudstone-rich flood-basin deposits with numerous stage I to III gypsic paleosols capped by eolian gypsum sand sheets accumulated during waning salt-withdrawal subsidence. Association of detrital gypsum, eolian gypsum, and gypsic paleosols suggests that the salt wall provided a common source for gypsum in the surrounding strata. This study documents a previously unrecognized salt weld with associated growth strata containing diapir-derived detritus and gypsic palesols that can be used to interpret halokinesis.

Characterization of a fluvial aquifer at a range of depths and scales: the Triassic St Bees Sandstone Formation, Cumbria, UK

Science.gov (United States)

Medici, Giacomo; West, L. J.; Mountney, N. P.

2018-03-01

Fluvial sedimentary successions represent porous media that host groundwater and geothermal resources. Additionally, they overlie crystalline rocks hosting nuclear waste repositories in rift settings. The permeability characteristics of an arenaceous fluvial succession, the Triassic St Bees Sandstone Formation in England (UK), are described, from core-plug to well-test scale up to 1 km depth. Within such lithified successions, dissolution associated with the circulation of meteoric water results in increased permeability ( K 10-1-100 m/day) to depths of at least 150 m below ground level (BGL) in aquifer systems that are subject to rapid groundwater circulation. Thus, contaminant transport is likely to occur at relatively high rates. In a deeper investigation (> 150 m depth), where the aquifer has not been subjected to rapid groundwater circulation, well-test-scale hydraulic conductivity is lower, decreasing from K 10-2 m/day at 150-400 m BGL to 10-3 m/day down-dip at 1 km BGL, where the pore fluid is hypersaline. Here, pore-scale permeability becomes progressively dominant with increasing lithostatic load. Notably, this work investigates a sandstone aquifer of fluvial origin at investigation depths consistent with highly enthalpy geothermal reservoirs ( 0.7-1.1 km). At such depths, intergranular flow dominates in unfaulted areas with only minor contribution by bedding plane fractures. However, extensional faults represent preferential flow pathways, due to presence of high connective open fractures. Therefore, such faults may (1) drive nuclear waste contaminants towards the highly permeable shallow (< 150 m BGL) zone of the aquifer, and (2) influence fluid recovery in geothermal fields.

Structural diagenesis in Upper Carboniferous tight gas sandstones. Lessons learned from the Piesberg analog study

Energy Technology Data Exchange (ETDEWEB)

Steindorf, P.; Hoehne, M.; Becker, S.; Hilgers, C. [RWTH Aachen Univ. (Germany). Energy and Mineral Resources Group (EMR); Koehrer, B. [Wintershall Holding GmbH, Barnstorf (Germany)

2013-08-01

Upper Carboniferous tight gas sandstone reservoirs in NW-Germany consist of thick successions of cyclothems. Our focus is the Westphalian D of the Piesberg quarry near Osnabrueck, which exposes cemented, faulted and jointed third-order coarse- to fine-grained sandstone cycles separated by anthracite coal seams. We characterize the rocks and the lateral variation of rock properties such as porosity to better constrain input data for reservoir modelling. Three cycles are exposed, each approximately 50 m thick. Rock types can be clearly distinguished by spectral gamma ray in the quarry. Sandstones are intensely compacted and cemented with quartz and generally characterized by low porosities < 8 % (Hepycnometry on plugs and cuttings). Porosities are secondary and mainly related to detrital carbonate dissolution. Around faults dissolution is higher and the porosities can increase to up to 25%. The normal faults show different throws in the quarry and bands of shale and coal have smeared into the fault at juxtaposed beds, which may result in compartments. They dominantly strike W-E and NNW-SSE, but subordinate NE-SW striking fault patterns are also present. Joints were analyzed in a 50 x 50 m section of the quarry wall using Lidar (Light detection and ranging) laser scanning, which allows the characterization of the lithology and quantitative measurement of bedding and fracture orientation data in inaccessible areas. NNE-SSW and W-E joint sets are accompanied by northeasterly and northwesterly striking sets. Around faults, fault planes and fractures are cemented with quartz veins, showing localized mass transport. Due to the intense cementation, the sandstones can reach uniaxial strengths of more than 100 MPa normal to bedding, and approximately 50 MPa parallel to bedding. Sandstone beds within and close to faults are leached by fluids, and their uniaxial strength is reduced by a factor of more than two. Our high resolution field data enables a better understanding of

The Saint Martin de Belleville syncline and its uraniferous permian sandstone

International Nuclear Information System (INIS)

Schade, Johannes

1983-01-01

This dissertation (these de specialite) is a study of the geology of the St.Martin d.B. syncline and the uranium prospect 'le Cochet' in the Carboniferous Brianconnais Zone of Savoy. Stratigraphy and sedimentology: This syncline presents continental detrital sediments ranging from U.Carboniferous to L.Triassic. In the U.Carboniferous, magmatic activity begins with the Moriaz Layers acid volcanics that are considered as a lateral equivalent of the Stephanian Courchevel Conglomerates. In Permian times, parts of an alluvial fan seem to occupy the north of the study area (gray and green conglomeratic sandstone). Southwards these inter-finger with flood plain sediments (red slate) including a locally oolitic limestone. Volcanic detritus is important in the Permian. Tourmalinite pebbles are frequent and seem to be related to the regional Permian magmatism. Albitization of feldspars is general in the Carboniferous and the Permian. The Permo-triassic typically shows microcline bearing dolomitic sandstones. In the Scythian quartzites orthoclase is the dominant feldspar. The quartzites are overlain by L.Triassic evaporites identified by the sulfur isotope ratio of their gypsum. The morphology of the zircons in the sandstones has been investigated using the typological method of J.P. Pupin. Regional Permian magmatism apparently produces volcanics of the calc-alkalic and tholeiitic series as well as a high level granitic intrusion of anatectic origin. The uranium occurrences are strata-bound on a kilometric and hecto-metric scale. They are developed almost exclusively in the gray variety of the Permian sandstones whose gray and red varieties are always barren. Within this unit, the mineralization impregnates irregularly distributed lenses and pods of coal material. Uranium is accompanied by vanadium occurring as roscoelite. The association U-V, of bio-philic character, reflects the concentration in the sedimentary environment and argues for a quite indirect relation with the

Fast evolving conduits in clay-bonded sandstone: Characterization, erosion processes and significance for the origin of sandstone landforms

Czech Academy of Sciences Publication Activity Database

Bruthans, J.; Svetlik, D.; Soukup, J.; Schweigstillová, Jana; Válek, Jan; Sedláčková, M.; Mayo, A.L.

2012-01-01

Roč. 177, December (2012), s. 178-193 ISSN 0169-555X R&D Projects: GA AV ČR IAA300130806 Institutional support: RVO:67985891 ; RVO:68378297 Keywords : sandstone * erosion * piping * tensile strength * conduit * landform Subject RIV: DA - Hydrology ; Limnology Impact factor: 2.552, year: 2012

A special kind of sandstone-type uranium deposit related to Jurassic palaeochannel systems in the northeastern Ordos Basin, China

International Nuclear Information System (INIS)

Li Ziying; Fang Xiheng; Xia Yuliang; Sun Ye; Jiao Yangquan; Chen Anping; Zhang Ke

2010-01-01

Dongsheng sandstone-type uranium deposit is a large one discovered in recent years in the northeastern Ordos Basin, China. It is a special kind of sandstone-type uranium deposit,different from other ordinary sandstone-type deposits because of its unique signatures. It is generally controlled by a transitional zone between greenish and grayish sandstones, both of those two kinds of sandstones now indicate reduced geochemical environments. The greenish color of the palaeo-oxidized sandstones mainly results from chloritization and epidotization related to oil and gas secondary reduction processes. The deposit genetically is different from ordinary sandstone uranium deposits,which is of more complex origin,undergoing not only palaeo-oxidization mineralization process, but also oil-gas fluid and hydrothermal reworking processes. It is spatially related to Jurassic Zhiluo Formation with braided palaeo channel systems. The uranium mineralization zone with higher grade usually exists in the branching area of the distributary channels of main braided streams, whose sandstone heterogeneity shows a transfer sedimentary facies from the braided stream sedimentary system to the braided delta sedimentary system. Statistical results show that medium and fine-grained sandstones are the most favorable rock types for uranium mineralization. (authors)

Analysis on metallogenic conditions of paleochannel sandstone type uranium deposits in kelulun region

Energy Technology Data Exchange (ETDEWEB)

Mingyue, Feng [Beijing Research Inst. of Uranium Geology, Beijing (China)

1999-07-01

On the basis of comprehensively analyzing metallogenic conditions of paleochannel sandstone type uranium deposits, the author discusses regional geologic background, characteristics of the basement and sedimentary cover of Kelulun basin and Huchawula-Hulun Lake basin, and the metallogenic potential of paleochannel sandstone type uranium deposits is proposed.

Analysis on metallogenic conditions of paleochannel sandstone type uranium deposits in kelulun region

International Nuclear Information System (INIS)

Feng Mingyue

1999-01-01

On the basis of comprehensively analyzing metallogenic conditions of paleochannel sandstone type uranium deposits, the author discusses regional geologic background, characteristics of the basement and sedimentary cover of Kelulun basin and Huchawula-Hulun Lake basin, and the metallogenic potential of paleochannel sandstone type uranium deposits is proposed

Radionuclide transport in sandstones with WIPP brine

International Nuclear Information System (INIS)

Weed, H.C.; Bazan, F.; Fontanilla, J.; Garrison, J.; Rego, J.; Winslow, A.M.

1981-02-01

Retardation factors (R) have been measured for the transport of 3 H, /sup 95m/Tc, and 85 Sr in WIPP brine using St. Peter, Berea, Kayenta, and San Felipe sandstone cores. If tritium is assumed to have R=1, /sup 95m/Tc has R=1.0 to 1.3 and therefore is essentially not retarded. Strontium-85 has R = 1.0 to 1.3 on St. Peter, Berea, and Kayenta, but R=3 on San Felipe. This is attributed to sorption on the matrix material of San Felipe, which has 45 volume % matrix compared with 1 to 10 volume % for the others. Retardation factors (R/sub s/) for 85 Sr calculated from static sorption measurements are unity for all the sandstones. Therefore, the static and transport results for 85 Sr disagree in the case of San Felipe, but agree for St. Peter, Berea, and Kayenta

Analysis on depositional system and prospect of sandstone-type uranium deposits of Bayanhua formation in Yilemen basin

International Nuclear Information System (INIS)

Sun Zexuan; Li Guoxin; He Fayang; Wei Yunjie

2002-01-01

Yilemen basin is a typical Mesozoic intra-mountain one. The author analyses characteristics of depositional system and the prospect of sandstone-type uranium deposit in the sedimentary cover of the Bayanhua Formation, Lower Cretaceous. Authors suggest that the conglomerate, sandstone-conglomerate and sandstone beds of braided stream and delta are favourable horizons for locating phreatic and interlayer oxidation zone sandstone-type uranium deposits, i.e. the northwestern side of Dalai uplifted zone, the Chagantaigebuqi narrow sag, and the southern area of Baolinbuqi

Detrital zircon provenance of the Hartselle Sandstone Unit, Southeastern USA: Insights into sediment source, paleogeography, and setting

Science.gov (United States)

Harthy, M. A.; Gifford, J.

2017-12-01

The Hartselle sandstone is an excellent example of an Oil sand, a resource rich in bitumen. The unit is a light-colored thick-bedded to massive quartzose sandstone, that is widespread across an area from Georgia in the east to Mississippi in the west, and south from Alabama to Kentucky as a northern border. Formation thickness ranges from 0 to more than 150 feet. The unit has been stratigraphically dated to the Middle-Upper Mississippian age. One hypothesis suggests that the sandstone unit formed from the geological remains of barrier islands located in the ocean between Gondwana and Laurentia. The Hartselle is thought to have formed by the movement waves and currents along the shoreline, which carried sand and concentrated it into a set of northwest to southeast trending barrier islands. Transgression-regression events shifted the islands back and forth in relation to the position of the shoreline, leading to the large areal extent of the unit. However, the current data are not enough to explain the geographical position of the Hartselle sandstone unit as it is not running parallel to the ancient shoreline. Another mystery is the source of the sand, some believing the source was from the south (Gondwana) and others that erosion was from the north (Laurentia). Detrital zircon provenance analysis will address the uncertainty in sediment source. We will compare zircon U-Pb age spectra to possible Laurentian and Gondwanan source areas to discriminate between these possibilities. In addition, the age of the youngest detrital zircon population will provide additional constraints on the maximum age of deposition for the unit. These detrital ages will also help us to understand the tectonic setting at the time of Hartselle deposition. Lastly, we aim to explain the widespread nature of the unit and the processes involved in the formation of the Hartselle sandstone. When taken together, these interpretations will illuminate the age, depositional and tectonic setting of a

Remote sensing technology prospecting methods of interlayer oxidation zone type sandstone uranium deposit in Yili basin

International Nuclear Information System (INIS)

Huang Xianfang; Huang Shutao; Pan Wei; Feng Jie; Liu Dechang; Zhang Jingbo; Xuan Yanxiu; Rui Benshan

1998-12-01

Taking Yili Basin as an example, remote sensing technology and method of interlayer oxidation zone type sandstone uranium deposit have systematically been summarized. Firstly, principle, methods and procedures of the second development of scientific experimental satellite photograph have been elaborated in detail. Three dimensional stereo simulation, display, and multi-parameters extraction have been recommended. Secondarily, the research is focused on prospective section image features in different type images and their geological implications and on establishing recognition keys of promising areas. Finally, based on above research results, three graded predictions, i.e. regional prospect, promising sections and favourable location in the deposit have been made step by step and reconnaissance and prospecting range are gradually reduced. The practice has indicated that breakthrough progress has been made in application to prospect prognosis of interlayer oxidation zone type sandstone uranium deposit and good verified results have been obtained

On the Theory of Solitons of Fluid Pressure and Solute Density in Geologic Porous Media, with Applications to Shale, Clay and Sandstone

Science.gov (United States)

Caserta, A.; Kanivetsky, R.; Salusti, E.

2017-11-01

We here analyze a new model of transients of pore pressure p and solute density ρ in geologic porous media. This model is rooted in the nonlinear wave theory, its focus is on advection and effect of large pressure jumps on strain. It takes into account nonlinear and also time-dependent versions of the Hooke law about stress, rate and strain. The model solutions strictly relate p and ρ evolving under the effect of a strong external stress. As a result, the presence of quick and sharp transients in low permeability rocks is unveiled, i.e., the nonlinear "Burgers solitons". We, therefore, show that the actual transport process in porous rocks for large signals is not only the linear diffusion, but also a solitons presence could control the process. A test of a presence of solitons is applied to Pierre shale, Bearpaw shale, Boom clay and Oznam-Mugu silt and clay. An application about the presence of solitons for nuclear waste disposal and salt water intrusions is also discussed. Finally, in a kind of "theoretical experiment" we show that solitons could also be present in higher permeability rocks (Jordan and St. Peter sandstones), thus supporting the idea of a possible occurrence of osmosis also in sandstones.

Fluoride salts as phase change materials for thermal energy storage in the temperature range 1000-1400 K

Science.gov (United States)

Misra, Ajay K.

1988-01-01

Eutectic compositions and congruently melting intermediate compounds in binary and ternary fluoride salt systems were characterized for potential use as latent heat of fusion phase change materials to store thermal energy in the temperature range 1000-1400 K. The melting points and eutectic compositions for many systems with published phase diagrams were experimentally verified and new eutectic compositions having melting points between 1000 and 1400 K were identified. Heats of fusion of several binary and ternary eutectics and congruently melting compounds were experimentally measured by differential scanning calorimetry. For a few systems in which heats of mixing in the melts have been measured, heats of fusion of the eutectics were calculated from thermodynamic considerations and good agreement was obtained between the measured and calculated values. Several combinations of salts with high heats of fusion per unit mass (greater than 0.7 kJ/g) have been identified for possible use as phase change materials in advanced solar dynamic space power applications.

Emplacement processes of tuffaceous sandstones at IODP Site C0011B, Nankai Trough, derived from modal analysis

Science.gov (United States)

Schindlbeck, J. C.; Kutterolf, S.; Freundt, A.

2011-12-01

Tuffaceous sandstones are characterized by their high amount (25 to 75%) of pyroclasts in their modal composition. During IODP Expedition 322 three interbeds of tuffaceous sandstones have been found within a moderately lithified and bioturbated silty claystone sequence in the late Miocene (>7.07 to ~9.0 Ma) upper part of the middle Shikoku Basin facies. Of the three sandstones, units 1 and 2 are single beds whereas unit 3 is composed of three beds. Modal analyses of 29 sandstone thin sections reveal systematic vertical changes within each bed. Generally low-density pyroclasts are enriched at the top (50-60 vol%) of each sandstone bed whereas dense lithic components (25-30 vol%) and minerals (25-30 vol%) are enriched at the bottom. The vertically varying abundance of various types of lithic fragments (sedimentary, volcanoclastic and metamorphic) suggests that these have also been segregated according to their respective densities. The highest amount of fine-grained matrix glass is found in the middle of each bed. Pumice and lithic fragments in the middle and upper parts of the sandstone beds carry ash coatings. For sandstone package 3, in contrast to 1 and 2, core pictures and thin section analyses indicate a subdivision in three units showing the same significant variations in top to bottom enrichment. This suggests three sedimentation events following each other in short time intervals. Glass and mineral chemistry of each sandstone bed show no significant vertical variations. Specifically the matrix glass-shard major element compositions are identical to the pumice clast composition in each tuffaceous sandstone bed. The compositions of amphibole and pyroxene crystals differ only slightly between the sandstone packages. Application of the Ridolfi et al. (2009) thermobarometric calculations to amphiboles of sandstone packages 1 and 2 suggests that each of these was derived from a volcanic system comprising both a deep and a shallow magma reservoir. Thickness and

Desert and groundwater dynamics of the Jurassic Navajo Sandstone, southeast Utah

Science.gov (United States)

Chan, M. A.; Hasiotis, S. T.; Parrish, J. T.

2017-12-01

The Jurassic Navajo Sandstone of southeastern Utah is a rich archive of a desert complex with an active groundwater system, influenced by climate changes and recharge from the Uncompahgre Uplift of the Ancestral Rocky Mountains. This eastern erg margin was dominated by dune deposits of large (>10 m thick) and small (m-scale) crossbedded sandstone sets. Within these porous deposits, common soft sediment deformation is expressed as contorted and upturned bedding, fluid escape structures, concentrations of clastic pipes with ring faults, and thick intervals of massive sandstone embedded in crossbedded sandstone. Collectively, these deformation features reflect changes and/or overpressure in the groundwater system. Interdune deposits record laterally variable bounding surfaces, resulting from the change in position of and proximity to the water table. Interdune modification by pedogenesis from burrows, roots, and trees suggest stable periods of moisture and water supply, as well as periodic drying expressed as polygonal cracked mud- to sand-cracked layers. Freshwater bedded and platy limestone beds represent lakes of decameter to kilometer extent, common in the upper part of the formation. Some carbonate springs that fed the lakes are preserved as limestone buildups (tufa mounds) with microbial structures. Extradunal deposits of rivers to small ephemeral streams show channelized and lenticular, subhorizontal, cm- to m-scale sandstone bodies with basal scours and rip-up clasts. Proxy records of the active hydrology imply a changing landscape at the Navajo desert's edge, punctuated by periods of significant rainfall, runoff, rivers, lakes, and springs, fed by high water table conditions to sustain periods of flourishing communities of plants, arthropods, reptiles, mammals, and dinosaurs. Strong ground motion perturbations periodically disrupted porous, water-saturated sands with possible surface eruptions, adding to the dynamic activity of the desert regime.

Application status and vistas of sequence stratigraphy to the exploration of sandstone-hosted uranium deposits

International Nuclear Information System (INIS)

Guo Qingyin; Chen Zuyi; Yu Jinshui; Han Shuqin

2008-01-01

Sequence stratigraphy is a newly developed subject based on seismostratigraphy, and has been widely applied in the exploration of hydrocarbon and other sedimentogenic mineral deposits and great achievements have been obtained. However, the application of sequence stratigraphy to the exploration of sandstone-hosted uranium deposits is just at the beginning. In this paper, some primary research achievements of sequence stratigraphy to the exploration of sandstone-hosted uranium deposits are summarized, and problems and their reasons of the application of sequence stratigraphy are discussed. Further more, according to characteristics of sandstone-hosted uranium deposits and the development of sequence stratigraphy, the application vistas of sequence stratigraphy to the exploration of sandstone-hosted uranium deposits are estimated. Finally, application directions are proposed, and some specific suggestions are given. (authors)

Effects of Heating Rate on the Dynamic Tensile Mechanical Properties of Coal Sandstone during Thermal Treatment

Directory of Open Access Journals (Sweden)

Ming Li

2017-01-01

Full Text Available The effects of coal layered combustion and the heat injection rate on adjacent rock were examined in the process of underground coal gasification and coal-bed methane mining. Dynamic Brazilian disk tests were conducted on coal sandstone at 800°C and slow cooling from different heating rates by means of a Split Hopkinson Pressure Bar (SHPB test system. It was discovered that thermal conditions had significant effects on the physical and mechanical properties of the sandstone including longitudinal wave velocity, density, and dynamic linear tensile strength; as the heating rates increased, the thermal expansion of the sandstone was enhanced and the damage degree increased. Compared with sandstone at ambient temperature, the fracture process of heat-treated sandstone was more complicated. After thermal treatment, the specimen had a large crack in the center and cracks on both sides caused by loading; the original cracks grew and mineral particle cracks, internal pore geometry, and other defects gradually appeared. With increasing heating rates, the microscopic fracture mode transformed from ductile fracture to subbrittle fracture. It was concluded that changes in the macroscopic mechanical properties of the sandstone were result from changes in the composition and microstructure.

Quantitative mineralogical analysis of sandstones using x-ray diffraction techniques

International Nuclear Information System (INIS)

Ward, C.R.; Taylor, J.C.

1999-01-01

Full text: X-ray diffraction has long been used as a definitive technique for mineral identification based on the measuring the internal atomic or crystal structures present in powdered rocks; soils and other mineral mixtures. Recent developments in data gathering and processing, however, have provided an improved basis for its use as a quantitative tool, determining not only the nature of the minerals but also the relative proportions of the different minerals present. The mineralogy of a series of sandstone samples from the Sydney and Bowen Basins of eastern Australia has been evaluated by X-ray diffraction (XRD) on a quantitative basis using the Australian-developed SIROQUANT data processing technique. Based on Rietveld principles, this technique generates a synthetic X-ray diffractogram by adjusting and combining full-profile patterns of minerals nominated as being present in the sample and interactively matches the synthetic diffractogram under operator instructions to the observed diffractogram of the sample being analysed. The individual mineral patterns may be refined in the process, to allow for variations in crystal structure of individual components or for factors such as preferred orientation in the sample mount. The resulting output provides mass percentages of the different minerals in the mixture, and an estimate of the error associated with each individual percentage determination. The chemical composition of the mineral mixtures indicated by SIROQUANT for each individual sandstone studied was estimated using a spreadsheet routine, and the indicated proportion of each oxide in each sample compared to the actual chemical analysis of the same sandstone as determined independently by X-ray fluorescence spectrometry. The results show a high level of agreement for all major chemical constituents, indicating consistency between the SIROQUANT XRD data and the whole-rock chemical composition. Supplementary testing with a synthetic corundum spike further

Current status and prospects of uranium geology developments of foreign in-situ leachable sandstone type uranium deposits

International Nuclear Information System (INIS)

Wang Zhengbang

2002-01-01

Firstly, with emphasis on in-situ leachable sandstone-type uranium deposits, the prospecting history of uranium deposits worldwide and its scientific research development are generally reviewed in four steps, and their basic historical experience is also summarized. Secondly, based on the detailed description of current development status of uranium geology of foreign in-situ leachable sandstone-type uranium deposits the important strategic position of sandstone-type uranium deposits in overall uranium resources all-over-the-world and its classification, spatial-temporal distribution and regulation, and metallogenic condition of sandstone-type uranium deposits are analysed thoroughly in five aspects: techtonics, paleo-climate, hydrogeology, sedimentary facies and lithology, as well as uranium sources: Afterwards, evaluation principles of three type of hyper-genic, epigenetic infiltrated sandstone-type uranium deposits are summarized. Based on sandstone-type uranium deposits located two important countries: the United States and Russia, the current development status of prospecting technology for in-situ leachable sandstone-type uranium deposits in foreign countries is outlined. Finally, according to the prospects of supply-demand development of global uranium resources, the author points out seriously that Chinese uranium geology is faced with a severe challenge, and proposes directly four strategic measures that should be taken

Nodular features from Proterozoic Sonia Sandstone, Jodhpur Group ...

Indian Academy of Sciences (India)

Corresponding author. e-mail: parthageology@gmail.com. The Sonia ..... cement variety in the form of dispersed dark brown clots and .... content within the nodule sandstones bear sig- nature in ..... Carbonates and Evaporites 21 133–143.

Dzhezkazgan and associated sandstone copper deposits of the Chu-Sarysu basin, Central Kazakhstan

Science.gov (United States)

Box, Stephen E.; Seltmann, Reimar; Zientek, Michael L.; Syusyura, Boris; Creaser, Robert A.; Dolgopolova, Alla

2012-01-01

Sandstone-hosted copper (sandstone Cu) deposits occur within a 200-km reach of the northern Chu-Sarysu basin of central Kazakhstan (Dzhezkazgan and Zhaman-Aibat deposits, and the Zhilandy group of deposits). The deposits consist of Cu sulfide minerals as intergranular cement and grain replacement in 10 ore-bearing members of sandstone and conglomerate within a 600- to 1,000-m thick Pennsylvanian fluvial red-bed sequence. Copper metal content of the deposits ranges from 22 million metric tons (Mt, Dzehzkazgan) to 0.13Mt (Karashoshak in the Zhilandy group), with average grades of 0.85 to 1.7% Cu and significant values for silver (Ag) and rhenium (Re). Broader zones of iron reduction (bleaching) of sandstones and conglomerates of the red-bed sequence extend over 10 km beyond each of the deposits along E-NE-trending anticlines, which began to form in the Pennsylvanian. The bleached zones and organic residues within them are remnants of ormer petroleum fluid accumulations trapped by these anticlines. Deposit sites along these F1anticlines are localized at and adjacent to the intersections of nearly orthogonal N-NW-trending F2synclines. These structural lows served to guide the flow of dense ore brines across the petroleum-bearing anticlines, resulting in ore sulfide precipitation where the two fluids mixed. The ore brine was sourced either from the overlying Early Permian lacustrine evaporitic basin, whose depocenter occurs between the major deposits, or from underlying Upper Devonian marine evaporites. Sulfur isotopes indicate biologic reduction of sulfate but do not resolve whether the sulfate was contributed from the brine or from the petroleum fluids. New Re-Os age dates of Cu sulfides from the Dzhezkazgan deposit indicate that mineralization took place between 299 to 309 Ma near the Pennsylvanian-Permian age boundary. At the Dzhezkazgan and some Zhilandy deposits, F2fold deformation continued after ore deposition. Copper orebodies in Lower Permian

A New Multichelating Acid System for High-Temperature Sandstone Reservoirs

Directory of Open Access Journals (Sweden)

Nianyin Li

2015-01-01

Full Text Available Sandstone reservoir acidizing is a complex and heterogeneous acid-rock reaction process. If improper acid treatment is implemented, further damage can be induced instead of removing the initial plug, particularly in high-temperature sandstone reservoirs. An efficient acid system is the key to successful acid treatment. High-temperature sandstone treatment with conventional mud acid system faces problems including high acid-rock reaction rate, short acid effective distance, susceptibility to secondary damage, and serious corrosion to pipelines. In this paper, a new multichelating acid system has been developed to overcome these shortcomings. The acid system is composed of ternary weak acid, organic phosphonic chelating agent, anionic polycarboxylic acid chelating dispersant, fluoride, and other assisted additives. Hydrogen ion slowly released by multistage ionization in ternary weak acid and organic phosphonic within the system decreases the concentration of HF to achieve retardation. Chelating agent and chelating dispersant within the system inhibited anodic and cathodic reaction, respectively, to protect the metal from corrosion, while chelating dispersant has great chelating ability on iron ions, restricting the depolarization reaction of ferric ion and metal. The synergic effect of chelating agent and chelating dispersant removes sulfate scale precipitation and inhibits or decreases potential precipitation such as CaF2, silica gel, and fluosilicate. Mechanisms of retardation, corrosion-inhibition, and scale-removing features have been discussed and evaluated with laboratory tests. Test results indicate that this novel acid system has good overall performance, addressing the technical problems and improving the acidizing effect as well for high-temperature sandstone.

Architecture of an Upper Jurassic barrier island sandstone reservoir, Danish Central Graben:

DEFF Research Database (Denmark)

Johannessen, Peter N.; Nielsen, Lars H.; Nielsen, Lars

2010-01-01

An unusually thick (c. 88 m), transgressive barrier island and shoreface sandstone succession characterizes the Upper Jurassic Heno Formation reservoir of the Freja oil field situated on the boundary of Denmark and Norway. The development and preservation of such thick transgressive barrier island...... sands is puzzling since a barrier island typically migrates landwards during transgression and only a thin succession of back-barrier and shoreface sands is preserved. Investigation of the development and geometry of the Freja reservoir sandstones is problematic since the reservoir is buried c. 5 km...... and seismic resolution is inadequate for architectural analysis. Description of the reservoir sandstone bodies is thus based on sedimentological interpretation and correlation of seven wells, of which five were cored. Palaeotopography played a major role in the position and preservation of the thick reservoir...

Research on geochronology and uranium source of sandstone-hosted uranium ore-formation in major uranium-productive basins, Northern-China

International Nuclear Information System (INIS)

Xia Yuliang; Liu Hanbin; Lin Jinrong; Fan Guang; Hou Yanxian

2004-12-01

A method is developed for correcting uranium content in uranium ore samples by considering the U-Ra equilibrium coefficient, then a U-Pb isochron is drawn up. By performing the above correction ore-formation ages of sandstone-hosted uranium mineralization which may be more realistic have been obtained. The comparative research on U-Pb isotopic ages of detritic zircon in ore-hosting sandstone and zircon in intermediate-acid igneous rocks in corresponding provenance area indicates that the ore-hosting sandstone is originated from the erosion of intermediate-acid igneous rocks and the latters are the material basis for the formation of the uranium-rich sandstone beds. On the basis of the study on U-Pb isotopic system evolution of the provenance rocks and sandstones from ore-hosting series, it is verified that the uranium sources of the sandstone-hosted uranium deposit are: the intermediate-acid igneous rocks with high content of mobile uranium, and the sandstone bodies pre-concentrated uranium. (authors)

Study on U-Ra equilibrium coefficient of the in-situ leaching sandstone-type uranium deposits: A case study of Qianjiadian uranium deposit

International Nuclear Information System (INIS)

Xia Yuliang; Xiu Qunye; Han Jun; Li Linqiang; Zheng Jiwei

2013-01-01

This paper investigated the U-Ra equilibrium coefficient (K-p) of mineralized sandstone and mudstone, and unmineralized sandstone and mudstone for the in-situ leaching sandstone-type uranium deposits. It is surprised that all of the mineralized sandstone and mudstone are both relatively to be partial to uranium, but all of the unmineralized sandstone and mudstone are both relatively to be partial to radium. Meanwhile the uranium in mineralized mudstone is relatively richer than that in mineralized sandstone, and the radium in unmineralized mudstone is relatively richer than that in unmineralized sandstone. It is suggested that mudstones were permeable at the uranium mineralized phase and the unmineralized mudstone and sandstone could serve as important mineralized uranium source. (authors)

Preliminary evaluation of the uranium favorability in the Kaiparowits Plateau Region, Garfield and Kane Counties, Utah

International Nuclear Information System (INIS)

Dubyk, W.S.; Young, P.

1978-05-01

The basal sandstone of the Chinle Formation (Upper Triassic) and the Salt Wash Member of the Morrison Formation (Upper Jurassic) in the Kaiparowits Plateau, southcentral Utah, were evaluated in terms of uranium potential. Both surface and subsurface data were utilized. Favorability of the basal Chinle sandstone was based on (1) presence of intermediate-size sandstone-filled channels cut into the Moenkopi; (2) presence of carbonaceous material; (3) an adequate source of uranium; and (4) gamma-ray anomalies from test-hole logs. Favorability of the Salt Wash Member of the Morrison Formation was based on (1) sandstone-mudstone ratios that approach equality, and (2) presence of thick sandstone lenses, carbonaceous material, and halos of light-tan to brown limonite staining. Although the basal Chinle sandstone and the Salt Wash Member of the Morrison contain sizable uranium deposits throughout much of the Colorado Plateau, both units lack characteristics that are favorable for significant uranium deposits in the Kaiparowits Plateau

Pore Structure and Limit Pressure of Gas Slippage Effect in Tight Sandstone

Science.gov (United States)

You, Lijun; Xue, Kunlin; Kang, Yili; Liao, Yi

2013-01-01

Gas slip effect is an important mechanism that the gas flow is different from liquid flow in porous media. It is generally considered that the lower the permeability in porous media is, the more severe slip effect of gas flow will be. We design and then carry out experiments with the increase of backpressure at the outlet of the core samples based on the definition of gas slip effect and in view of different levels of permeability of tight sandstone reservoir. This study inspects a limit pressure of the gas slip effect in tight sandstones and analyzes the characteristic parameter of capillary pressure curves. The experimental results indicate that gas slip effect can be eliminated when the backpressure reaches a limit pressure. When the backpressure exceeds the limit pressure, the measured gas permeability is a relatively stable value whose range is less than 3% for a given core sample. It is also found that the limit pressure increases with the decreasing in permeability and has close relation with pore structure of the core samples. The results have an important influence on correlation study on gas flow in porous medium, and are beneficial to reduce the workload of laboratory experiment. PMID:24379747

Geology of the north end of the Salt Valley Anticline, Grand County, Utah

Science.gov (United States)

Gard, Leonard Meade

1976-01-01

Miocene regional uplift had caused downcutting streams to breach the salt core resulting in further collapse. The axis of the anticline is a narrow generally flat-floored valley containing a few hills composed of downdropped Mesozoic rocks foundered, in the caprock. The caprock, which underlies thin alluvium in the valley, is composed of contorted gypsum, shale, sandstone, and limestone--the insoluble residue of the Paradox salt.

Integrated prediction based on GIS for sandstone-type uranium deposits in the northwest of Ordos Basin

International Nuclear Information System (INIS)

Han Shaoyang; Ke Dan; Hu Shuiqing; Guo Qingyin; Hou Huiqun

2005-01-01

The integrated prediction model of sandstone-type uranium deposits and its integrated evaluation methods as well as flow of the work based on GIS are studied. A software for extracting metallogenic information is also developed. A multi-source exploring information database is established in the northwest of Ordos Basin, and an integrated digital mineral deposit prospecting model of sandstone-type uranium deposits is designed based on GIS. The authors have completed metallogenic information extraction and integrated evaluation of sandstone-type uranium deposits based on GIS in the study area. Research results prove that the integrated prediction of sandstone-type uranium deposits based on GIS may further delineate prospective target areas rapidly and improve the predictive precision. (authors)

Application research on remote sensing geology of sandstone-type uranium deposit in Yili basin

International Nuclear Information System (INIS)

Wang Huaiwu

2002-01-01

Based on remote sensing images and practical materials, and new ideas of laying particular emphasis on the research of regional geologic structures, and large in-situ leachable sandstone-type uranium deposits, applying the theory of plate tectonics, the author makes a comprehensive analysis on the uranium metallogenic environments, characteristics of regional geologic structures, the ore-controlling mechanism and factors, and uranium metallogeny. Authors propose that large interlayer oxidation zone sandstone-type uranium deposits are controlled by the combination of the stable block in Meso-Cenozoic compressive-shearing faulted subsided basin on the Yili multiphase massif in Tianshan paleo-island arc system, and the specific paleo-geographic environments and its' structural terrace'. The origin of hydrogenic sandstone-type uranium deposits is summarized by the authors as the 'mixing and neutralization' genetic model, and the 'eight ore-controlling factors merge into an organic whole' prospecting model. The above mentioned provides clear prospecting direction and new ideas for the forecasting direction for prospecting large sandstone-type uranium deposits

Study on integrated evaluation of sandstone-hosted uranium metallogenic potential in southern Yili basin

International Nuclear Information System (INIS)

Han Shaoyang; Ke Dan; Xu Jianguo; Zheng Enjiu; Li Shengxiang

2008-01-01

Plenty of geological data have been accumulated during mineral resource survey in China; under the guidance of new metallogenic theories, it is an important task of how to use these data most effectively for the new cycle uranium survey. In this paper, the flow of establishing the integrated mineral deposits prospecting model for sandstone-hosted uranium deposits is put forward. Based on studying geologic, hydrogeologic and regional geophysical field characteristics of representative uranium deposits No. 512 in southern Yili basin, its multi-source information descriptive model has been established, from which 512-type integrated prospecting models of sandstone-hosted uranium orefield and deposits are summarized. According to the established integrated prospecting models, the metallogenic information extraction of sandstone-hosted uranium deposits has completed in the study area. Finally, the integrated quantitative evaluation of sandstone-hosted uranium metallogenic potential is performed by using the evidence weighing method to integrate middle scale multi-source metallogenic information in the southern Yili basin, and good prediction effect is obtained. (authors)

Experimental and Numerical Investigations on Strength and Deformation Behavior of Cataclastic Sandstone

Science.gov (United States)

Zhang, Y.; Shao, J. F.; Xu, W. Y.; Zhao, H. B.; Wang, W.

2015-05-01

This work is devoted to characterization of the deformation and strength properties of cataclastic sandstones. Before conducting mechanical tests, the physical properties were first examined. These sandstones are characterized by a loose damaged microstructure and poorly cemented contacts. Then, a series of mechanical tests including hydrostatic, uniaxial, and triaxial compression tests were performed to study the mechanical strength and deformation of the sandstones. The results obtained show nonlinear stress-strain responses. The initial microcracks are closed at hydrostatic stress of 2.6 MPa, and the uniaxial compressive strength is about 0.98 MPa. Under triaxial compression, there is a clear transition from volumetric compressibility to dilatancy and a strong dependency on confining pressure. Based on the experimental evidence, an elastoplastic model is proposed using a linear yield function and a nonassociated plastic potential. There is good agreement between numerical results and experimental data.

The controlling role of positive structures over the metallogenesis and emplacement of inter layer oxidation sandstone type uranium deposits

International Nuclear Information System (INIS)

Gu Kangheng; Chen Zuyi

2010-01-01

The positive structures in this paper mean the geological structures related to the occurrence of U-metallogenic zones or U-deposit such as anticlines, uplifts and uplifted fault-blocks. Occurrence features of interlayer oxidation sandstone type deposit at the southern margin of Yili basin and southwestern margin of Turpan-Hami basin, the northeastern margin of Jiudong basin illustrate that the sandstone-hosted uranium deposits, the U-mineralized sections and the uranium occurrences are always selectively emplaced on/in positive structures. The reasons for this lie in the formation mechanism of sandstone-hosted U-deposits. The positive structures raised the elevation of ore-hosting sandstone horizon and make it close to ground surface or exposed at the ground surface, which result in the infiltration of uranium and oxygen bearing groundwater from recharge area into host sandstone horizon, and the interlayer oxidation of host sandstone, as well as the dissolution and the migration of uranium in host sandstone, and the reduction mineralization at the oxidation-reduction interface. Sufficient attention should be paid to the controlling role of positive structures over the metallogenesis and emplacement of sandstone-hosted uranium deposits. They could act as an important criterion for recognizing and prognosticating potential uranium mineralized areas in uranium metallogenic zones or uranium-productive sedimentary basins. (authors)

The sedimentology of uranium-bearing sandstones on the farm Ryst Kuil 351 Beaufort West area

International Nuclear Information System (INIS)

Cole, D.I.

1979-06-01

A study of the sedimentology of some uranium-bearing sandstones on the farm Ryst Kuil 351 was made in order to assess possible relationships between the mineralisation and the sedimentary facies and/or the palaeo-environment. Use was made of 6 vertical profiles, derived from horizontal traverses. 12 sedimentary facies were recognised according to grain-size and sedimentary structure. The transitions between these facies, as derived from the vertical profiles, were subjected to Markov analysis. Only 3 Markov-dependent transitions were derived, but several facies transitions and associations occurred with greater than random frequency. These, together with the vertical profiles, were used to interpret the palaeo-environmental succession. This succession is fluvial meandering and two sub-environments - channel and flood plain - were delineated according to the prevalence of sandstone or mudstone facies. The uranium-bearing sandstones occur in the lower part of a thick (29 - 46m) multistorey point bar sequence within the channel sub-environment. The mineralisation is associated with koffieklip and is restricted to two sedimentary facies - massive very fine-to-finegrained sandstone and horizontally bedded, very fine- to fine-grained sandstone. The mineralisation normally occurs near the bases of the point bars

Quantifying the effect of squirt flow dispersion from compliant clay porosity in clay bearing sandstones

DEFF Research Database (Denmark)

Sørensen, Morten Kanne; Fabricius, Ida Lykke

2013-01-01

Compliant porosity in the form of cracks is known to cause significant attenuation and velocity dispersion through pore pressure gradients and consequent relaxation, dubbed squirt flow. Squirt flow from cracks vanish at high confining stress due to crack closing. Studies on clay bearing sandstones......-squirt flow on the bulk modulus of a clay bearing sandstone. The predicted magnitude of the clay-squirt effect on the bulk modulus is compared with experimental data. The clay-squirt effect is found to possibly account for a significant portion of the deviances from Gassmann fluid substitution in claybearing...... sandstones....

Multielement statistical evidence for uraniferous hydrothermal activity in sandstones overlying the Phoenix uranium deposit, Athabasca Basin, Canada

Science.gov (United States)

Chen, Shishi; Hattori, Keiko; Grunsky, Eric C.

2018-04-01

The Phoenix U deposit, with indicated resources of 70.2 M lb U3O8, occurs along the unconformity between the Proterozoic Athabasca Group sandstones and the crystalline basement rocks. Principal component analysis (PCA) is applied to the compositions of sandstones overlying the deposit. Among PCs, PC1 accounts for the largest variability of U and shows a positive association of U with rare earth elements (REEs) + Y + Cu + B + Na + Mg + Ni + Be. The evidence suggests that U was dispersed into sandstones together with these elements during the uraniferous hydrothermal activity. Uranium shows an inverse association with Zr, Hf, Th, Fe, and Ti. Since they are common in detrital heavy minerals, such heavy minerals are not the major host of U. The elements positively associated with U are high in concentrations above the deposit, forming a "chimney-like" or "hump-like" distribution in a vertical section. Their enrichment patterns are explained by the ascent of basement fluids through faults to sandstones and the circulation of basinal fluids around the deposit. The Pb isotope compositions of whole rocks are similar to expected values calculated from the concentrations of U, Th, and Pb except for sandstones close to the deposit. The data suggest that in situ decay of U and Th is responsible for the Pb isotope compositions of most sandstones and that highly radiogenic Pb dispersed from the deposit to the proximal sandstones long after the mineralization. This secondary dispersion is captured in PC8, which has low eigenvalue. The data suggests that the secondary dispersion has minor effect on the overall lithogeochemistry of sandstones.

Controls on the variability of net infiltration to desert sandstone

Science.gov (United States)

Heilweil, Victor M.; McKinney, Tim S.; Zhdanov, Michael S.; Watt, Dennis E.

2007-01-01

As populations grow in arid climates and desert bedrock aquifers are increasingly targeted for future development, understanding and quantifying the spatial variability of net infiltration becomes critically important for accurately inventorying water resources and mapping contamination vulnerability. This paper presents a conceptual model of net infiltration to desert sandstone and then develops an empirical equation for its spatial quantification at the watershed scale using linear least squares inversion methods for evaluating controlling parameters (independent variables) based on estimated net infiltration rates (dependent variables). Net infiltration rates used for this regression analysis were calculated from environmental tracers in boreholes and more than 3000 linear meters of vadose zone excavations in an upland basin in southwestern Utah underlain by Navajo sandstone. Soil coarseness, distance to upgradient outcrop, and topographic slope were shown to be the primary physical parameters controlling the spatial variability of net infiltration. Although the method should be transferable to other desert sandstone settings for determining the relative spatial distribution of net infiltration, further study is needed to evaluate the effects of other potential parameters such as slope aspect, outcrop parameters, and climate on absolute net infiltration rates.

INAA and petrological study of sandstones from Khmer temples in Angkor

International Nuclear Information System (INIS)

Kucera, J.; Kranda, K.; Novak, J.K.; Poncar, J.; Krausova, I.; Soukal, L.

2009-01-01

INAA was used to determine 35 major, minor and trace elements in sandstone samples taken from building blocks of 21 Khmer temples in Angkor, Cambodia. The sandstone samples were also characterized by conventional optical microscopy, X-ray diffraction analysis and electron microprobe analysis. The aim of this work was to examine the hypothesis that a particular elemental and/or mineral composition of the building materials can be characteristic of a particular architectural style/building period in the history of constructing the Angkor monuments. Preliminary results of this study are presented

Research and performance evaluation on an HA integrated acid system for sandstone acidizing

Directory of Open Access Journals (Sweden)

Liqiang Zhao

2018-03-01

Full Text Available When the conventional sandstone acidizing technologies are adopted, many slugs are needed in the injection of prepad fluid, treatment fluid and postpad fluid, and consequently the production and operation suffers inconveniences and difficulties. In view of this, a kind of HA integrated acid system which is mainly composed of organic polybasic acids (HA+HCl + HF and an efficient organic solvent was developed in this paper based on the idea of integrated acid replacing ''multiple steps'' and high efficiency and intensification. Via this HA integrated acid system, the complicated blockage in sandstone reservoirs can be removed effectively. Then, experiments were carried out on this system to evaluate its performance in terms of its retardance, organic blockage dissolution, chelating and precipitation inhibition. It is indicated that this new system can not only realize the acidizing of conventional integrated acid, but also present a good retarding performance by controlling H+ multi-stage ionization step by step and by forming silica acid-aluminum phosphonate film on the surface of clay minerals; that via this new HA integrated acid system, the organic blockage can be removed efficiently; and that it is wider in pH solution range than conventional APCs (aminopolycarboxyliates chelants, stronger in chelating capacity of Ca2+, Mg2+ and Fe3+ than conventional chelants (e.g. EDTA, NTA and DTPA, and better in precipitation inhibition on metal fluoride, fluosilicic acid alkali metal, fluoaluminic acid alkali metal and hydroxide than multi-hydrogen acid, fluoboric acid and mud acid systems. These research results provide a technical support for the plugging removal in high-temperature deep oil and gas reservoirs. Keywords: Organic polybasic acid, Integrated acid, Retardance, Chelating, Precipitation, Acidizing, Sandstone, Reservoir

Recent exploration progresses on sandstone-hosted uranium deposits in north-western China

International Nuclear Information System (INIS)

Li, Z.

2014-01-01

The metallogenic target selection using multiple exploration techniques and drilling program for sandstone-hosted uranium deposits have been intensively carried out for recent years, and big progresses on new discoveries of uranium reserve/resource have been made in the Mesozoic sedimentary basins such as in Yili, Ordos etc. in North-western China The Yili basin is a depression one within the Tianshan Mountain belt in the western part of China. Its basement is composed of Proterozoic-Paleozoic metamorphic and sedimentary rocks, and covers of Mesozoic sediments. The early-middle Jurassic Shuixigou Group is major uranium-productive beds which are composed of three Formations such as Badaowan, Sangonghe, Xisanyao and eight sedimentary cycles. Uranium deposits are found in the south margin of the Basin and controlled by the redox zone. The combined exploration techniques of detailed sedimentary facies study, Rn-survey, high-precision magnetic and soil geochemical and seismic surveys have been successfully used to have locate the potential targets and mineralization zones. The enlargement of uranium reserve/resources in the known deposits and new resources in the selected new targets and cycles have been achieved through further drilling programs. The Ordos basin is a large Meso-Cenozoic basin developed in North China Platform, with its size of approximately 250,000 km"2 and is well known as an important “energy resources basin” because of abundance of coal, oil and gas deposits. The Dongsheng sandstone type uranium deposit is a large one discovered in recent years in northeastern Ordos basin. It is a special kind of sandstone type uranium deposit, different from other ordinary sandstone type deposits because of its unique signatures. It is generally controlled by a transitional zone between greenish and grayish sandstones, both of those two kinds of sandstones now indicate reduced geochemical environments. The greenish color of the paleooxidized sandstones mainly

A new bee species that excavates sandstone nests

Science.gov (United States)

Many wonder why animals act in seemingly injurious ways. Understanding the behavior of pollinators such as bees is especially important because of the necessary ecosystem service they provide. The new species Anthophora pueblo, discovered excavating sandstone nests, provides a model system for addre...

Mechanical Behavior of Red Sandstone under Incremental Uniaxial Cyclical Compressive and Tensile Loading

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Baoyun Zhao

2017-01-01

Full Text Available Uniaxial experiments were carried out on red sandstone specimens to investigate their short-term and creep mechanical behavior under incremental cyclic compressive and tensile loading. First, based on the results of short-term uniaxial incremental cyclic compressive and tensile loading experiments, deformation characteristics and energy dissipation were analyzed. The results show that the stress-strain curve of red sandstone has an obvious memory effect in the compressive and tensile loading stages. The strains at peak stresses and residual strains increase with the cycle number. Energy dissipation, defined as the area of the hysteresis loop in the stress-strain curves, increases nearly in a power function with the cycle number. Creep test of the red sandstone was also conducted. Results show that the creep curve under each compressive or tensile stress level can be divided into decay and steady stages, which cannot be described by the conventional Burgers model. Therefore, an improved Burgers creep model of rock material is constructed through viscoplastic mechanics, which agrees very well with the experimental results and can describe the creep behavior of red sandstone better than the Burgers creep model.

Aptian ‘Shale Gas’ Prospectivity in the Downdip Mississippi Interior Salt Basin, Gulf Coast, USA

Science.gov (United States)

Hackley, Paul C.; Valentine, Brett J.; Enomoto, Catherine B.; Lohr, Celeste D.; Scott, Krystina R.; Dulong, Frank T.; Bove, Alana M.

2016-01-01

This study evaluates regional ‘shale gas’ prospectivity of the Aptian section (primarily Pine Island Shale) in the downdip Mississippi Salt Basin (MSB). Previous work by the U.S. Geological Survey estimated a mean undiscovered gas resource of 8.8 trillion cubic feet (TCF) in the chronostratigraphic-equivalent Pearsall Formation in the Maverick Basin of south Texas, where industry has established a moderately successful horizontal gas and liquids play. Wells penetrating the downdip MSB Aptian section at depths of 12,000-15,000 ft were used to correlate formation tops in a 15-well cross-section extending about 200 miles (mi) east-southeastward from Adams Co. to Jackson Co. Legacy cuttings from these wells were analyzed for thermal maturity and source rock quality. Bitumen reflectance (n=53) increases with increasing present-day burial depth in the east-central study area from 1.0% to 1.7%. As the Aptian section shallows in Adams Co. to the west, bitumen Ro values are higher (1.7-2.0%), either from relatively greater heat flux or greater mid-Cenomanian uplift and erosion in this area. Total organic carbon (TOC) content ranges 0.01-1.21 and averages 0.5 wt.% (n=51); pyrolysis output (S2; n=51) averages 0.40 mg HC/g rock, indicating little present-day hydrocarbon-generative potential. Bitumen reflectance is preferred as a thermal maturity parameter as Tmax values are unreliable. Normalized X-ray diffraction (XRD) mineral analyses (n=26) indicate high average clay abundance (53 wt.%) relative to quartz (29%) and carbonate (18%). Mineral content shows a spatial relationship to an Appalachian orogen clastic sediment source, with proximal high clay and quartz and distal high carbonate content. Clastic influx from the Appalachian orogen is confirmed by detrital zircon U-Pb ages with dominant Grenville and Paleozoic components [105 ages from a Rodessa sandstone and 112 ages from a Paluxy (Albian) sandstone]. Preliminary information from fluid inclusion microthermometry

The effects of impure CO2 on reservoir sandstones: results from mineralogical and geomechanical experiments

Science.gov (United States)

Marbler, H.; Erickson, K. P.; Schmidt, M.; Lempp, Ch.; Pöllmann, H.

2012-04-01

An experimental study of the behaviour of reservoir sandstones from deep saline aquifers during the injection and geological storage of CO2 with the inherent impurities SOX and NOX is part of the German national project COORAL*. Sample materials were taken from outcrops of possible reservoir formations of Rotliegend and Bunter Sandstones from the North German Basin. A combination of mineralogical alteration experiments and geomechanical tests was carried out on these rocks to study the potential effects of the impurities within the CO2 pore fluid. Altered rock samples after the treatment with CO2 + SOX/NOX in an autoclave system were loaded in a triaxial cell under in-situ pressure and temperature conditions in order to estimate the modifications of the geomechanical rock properties. Mineralogical alterations were observed within the sandstones after the exposure to impure supercritical (sc)CO2 and brine, mainly of the carbonatic, but also of the silicatic cements, as well as of single minerals. Besides the partial solution effects also secondary carbonate and minor silicate mineral precipitates were observed within the pore space of the treated sandstones. These alterations affect the grain structure of the reservoir rock. Results of geomechanical experiments with unaltered sandstones show that the rock strength is influenced by the degree of rock saturation before the experiment and the chemical composition of the pore fluid (scCO2 + SOX + NOX). After long-term autoclave treatment with impure scCO2, the sandstone samples exhibit modified strength parameters and elastic deformation behaviour as well as changes in porosity compared to untreated samples. Furthermore, the injected fluid volume into the pore space of sandstones from the same lithotype varies during triaxial loading depending on the chemistry of the pore fluid. CO2 with NOX and SOX bearing fluid fills a significantly larger proportion of the sandstone pore space than brine with pure scCO2. * The

Coastal dune facies, Permian Cutler Formation (White Rim Sandstone), Capitol Reef National Park area, southern Utah

Science.gov (United States)

Kamola, Diane L.; Chan, Marjorie A.

1988-04-01

The Permian Cutler Formation (White Rim Sandstone) in the Capitol Reef National Park area in southern Utah is an excellent example of a coastal dune complex subjected to periodic flooding by marine waters. Wind-ripple, grainfall and grainflow laminae compose the cross-sets deposited by eolian dunes. However, wave-reworked structures such as oscillation ripples, the occurrence of the characteristically marine trace fossils Thalassinoides and Chondrites, and interfingering marine carbonate beds of the Kaibab Formation collectively indicate marine interaction with the eolian environment. Four facies are distinguished: cross-stratified sandstone, burrowed to bioturbated sandstone, brecciated and deformed sandstone, and ripple-laminated sandstone and thin carbonate beds. One unusual aspect of the cross-stratified sandstone facies is the abundance of coarse-grained sand. Coarse-grained sand is atypical in many ancient eolian slipface deposits, but occurs here in large slipface foresets as both grainflow and wind-ripple deposits. No water-laid structures are found in these slipface deposits. Coarse-grained sand was probably transported to the Cutler shoreline by fluvial systems draining the Uncompahgre Uplift to the east, and then concentrated as coarse-grained ripples in interdune areas. Some of these coarse-grained ripples migrated up the stoss side of the dunes and accumulations of coarse-grained sand avalanched down the crest to form grainflow deposits. An extensive amount of soft-sediment deformation is indicated by the presence of convolute bedding and brecciation. These features occur near the zone of interfingering with marine carbonate beds of the Kaibab Formation. The water-saturated and moist conditions required for extensive deformation may have been controlled by the proximity of these sandstones to the shoreline, and fluctuations in the associated groundwater table.

Salt consumption and the effect of salt on mineral metabolism in horses.

Science.gov (United States)

Schryver, H F; Parker, M T; Daniluk, P D; Pagan, K I; Williams, J; Soderholm, L V; Hintz, H F

1987-04-01

The voluntary salt consumption of mature unexercised horses was measured weekly for up to 45 weeks. Voluntary intake among horses was quite variable ranging from 19 to 143 g of salt per day and was inversely related to total salt intake (salt in feeds plus voluntary intake). Mean daily voluntary salt consumption was 53 g. Season of the year did not influence voluntary intake. In preference tests which evaluated every two choice combination of 0.2% and 4% NaCl in test diets fed daily for four days, ponies generally preferred diets containing the lower amount of salt. In similar preference studies which used NaHCO3 as a sodium source, ponies always preferred the diet containing the lower level of NaHCO3. Metabolism studies employing diets containing 1, 3 or 5% NaCl showed that urinary excretion was the major excretory pathway for sodium and chloride. Fecal excretion, intestinal absorption and retention of sodium were not affected by level of salt intake. Urinary calcium excretion was unaffected by salt intake but calcium and phosphorus absorption and retention were enhanced when ponies were fed diets containing 3 or 5% sodium chloride. Magnesium and copper metabolism were unaffected by salt intake. Horses voluntarily consume relatively large amounts of sodium chloride but it is likely that not all voluntary consumption is related to the salt requirement of the horse. Habit and taste preference could also be involved. Salt consumption at the levels used in these studies does not appear to be detrimental to the metabolism of other minerals in the horse.

The sedimentology of uranium-bearing sandstones on the farm Riet Kuil 307, Beaufort West area

International Nuclear Information System (INIS)

Cole, D.I.

1980-10-01

The sedimentology of four sandstones was studied in outcrop and in the subsurface on the farm Riet Kuil 307, near Beaufort West. Only two of these sandstones are mineralised. These are four surface and two subsurface uranium anomalies and one surface uranium anomaly. The sedimentological study was made by means of 47 vertical profiles measured across and adjacent to the surface anomalies as well as 11 core-logs, which intersected the subsurface anomalies. The unmineralised sandstones are included in this study. A total of 19 sedimentary facies was recognised within the fluvial sandstone sequence according to the criteria of grain-size and sedimentary structure. Transitions between the facies were subjected to a Markov chain analysis in order to delineate Markov-dependent transitions. Uranium mineralisation is almost entirely confined to the coarser-grained sedimentary facies, which probably acted as suitable aquifers for the transport of uraniferous solutions prior to the precipitation of the uranium. Horizontally bedded sandstone facies comprises 60 per cent of the total cumulative thickness of mineralisation. The nature of the bedding of this facies may have provided a more effective permeability zone for the transport of uraniferous solutions. This facies contains an abundance of carbonaceous material which acted as an important indirect reductant for the precipitation of uranium from solution. The direct reductant was most probably H 2 S produced by enaerobic bacteria acting on this carbonaceous material shortly after deposition of the sediments. Carbonaceous material also occurs in the other mineralised facies and is considered to be the major control on the mineralisation in the uranium-bearing sandstones

Fe-oxide grain coatings support bacterial Fe-reducing metabolisms in 1.7-2.0 km-deep subsurface quartz arenite sandstone reservoirs of the Illinois Basin (USA

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Yiran eDong

2014-09-01

Full Text Available The Cambrian-age Mt. Simon Sandstone, deeply buried within the Illinois Basin of the midcontinent of North America, contains quartz sand grains ubiquitously encrusted with iron-oxide cements and dissolved ferrous iron in pore-water. Although microbial iron reduction has previously been documented in the deep terrestrial subsurface, the potential for diagenetic mineral cementation to drive microbial activity has not been well studied. In this study, two subsurface formation water samples were collected at 1.72 and 2.02 km, respectively, from the Mt. Simon Sandstone in Decatur, Illinois. Low-diversity microbial communities were detected from both horizons and were dominated by Halanaerobiales of Phylum Firmicutes. Iron-reducing enrichment cultures fed with ferric citrate were successfully established using the formation water. Phylogenetic classification identified the enriched species to be related to Vulcanibacillus from the 1.72 km depth sample, while Orenia dominated the communities at 2.02 km of burial depth. Species-specific quantitative analyses of the enriched organisms in the microbial communities suggest that they are indigenous to the Mt. Simon Sandstone. Optimal iron reduction by the 1.72 km enrichment culture occurred at a temperature of 40oC (range 20 to 60oC and a salinity of 25 parts per thousand (range 25-75 ppt. This culture also mediated fermentation and nitrate reduction. In contrast, the 2.02 km enrichment culture exclusively utilized hydrogen and pyruvate as the electron donors for iron reduction, tolerated a wider range of salinities (25-200 ppt, and exhibited only minimal nitrate- and sulfate-reduction. In addition, the 2.02 km depth community actively reduces the more crystalline ferric iron minerals goethite and hematite. The results suggest evolutionary adaptation of the autochthonous microbial communities to the Mt. Simon Sandstone and carries potentially important implications for future utilization of this reservoir

Experimental Investigation on Shock Mechanical Properties of Red Sandstone under Preloaded 3D Static Stresses

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Niu Yong

2015-11-01

Full Text Available Triaxial impact mechanical performance experiment was performed to study the mechanical properties of red sandstone subjected to three-dimensional (3D coupled static and dynamic loads, i.e., three confining pressures (0, 5, and 10 MPa and three axial pressures (11, 27, and 43 MPa. A modified 3D split Hopkinson pressure bar testing system was used. The change trend in the deformation of red sandstone and the strength and failure modes under axial pressures and confining pressures were analyzed. Results show that, when the confining pressure is constant, the compressive strength, secant modulus, and energy absorbed per unit volume of red sandstone initially increases and subsequently decreases, whereas the average strain rate exhibits an opposite trend. When the axial pressure is constant, both the compressive strength and secant modulus of red sandstone are enhanced, but the average strain rate is decreased with increasing confining pressure. The energy absorbed per unit volume is initially increased and subsequently decreased as the confining pressure increases. Red sandstone exhibits a cone-shaped compression–shear failure mode under the 3D coupled static and dynamic loads. The conclusions serve as theoretical basis on the mechanical properties of deep medium-strength rock under a high ground stress and external load disturbance condition

Application of Rock-Eval pyrolysis to the detection of hydrocarbon property in sandstone-type uranium deposits

International Nuclear Information System (INIS)

Sun Ye; Li Ziying; Guo Qingyin; Xiao Xinjian

2006-01-01

Rock-Eval pyrolysis is introduced into the research of uranium geology by means of oil-gas geochemical evaluation. Hydrocarbon (oil-gas) components in DS sandstone-type uranium deposit are detected quantitatively. Through analyzing the oil-gas bearing categories of the uranium-bearing sandstones, the internal relationships between the uranium deposit and the oil-gas are revealed. Rock-Eval pyrolysis is an effective method to study the interaction between inorganic and organic matters, and should be extended to the study of sandstone-type uranium deposits. (authors)

Physical and chemical properties for sandstone and bentonites

International Nuclear Information System (INIS)

Sato, Haruo

2004-01-01

Physical and chemical properties such as porosity, pore-size distribution, dry density, solid density, mineralogy and chemical composition, which are important parameters for the understanding and analysis of the diffusion phenomena of radionuclides and ions in bentonite and in the geosphere, were measured. The measurements were performed for sandstone, of which fundamental data and information are limited. For bentonite, 3 kinds of bentonites with different smectite contents (Kunigel-V1, Kunipia-F, MX80) were used. In the measurements of the physical and chemical properties of rock, the measurements of solid density by pychnometer, the measurements of porosity, dry density and solid density by water saturation method, the measurements of porosity, dry density, solid density, pore-size distribution and specific surface area of pores by Hg porosimetry, the identifications of constituent minerals by X-ray Diffractometry (XRD), the measurement of chemical composition by whole rock analysis, the observations of micropore structure by Laser Confocal Microscope (LCM), the measurements of water vaporization curves and the measurements of the homogeneity of the rock by penetration of KMnO 4 were performed. While, in the measurements of the physical and chemical properties for bentonite, water basis water content, water content, porosity, dry density, solid density and their distributions in samples were measured, and the degree of inhomogeneity was quantitatively evaluated by comparing with data and information reported up to date. The porosities of sandstone are 15.6±0.21% for water saturation method and 15.5±0.2% for Hg porosimetry, and similar values were obtained in both methods. The solid densities ranged 2.65-2.69 Mg/m 3 for 3 methods, and the average value was 2.668±0.012 Mg/m 3 . The average pore size was 88.8±0.5nm, and pore sizes ≤10μm shared 80% of total pore volume and pore sizes ≤1μm shared 40%. The specific surface area of the pores is 4.09±0.017 m

Different effects of temperature and salinity on permeability reduction by fines migration in Berea sandstone

DEFF Research Database (Denmark)

Rosenbrand, Esther; Kjøller, Claus; Riis, Jacob Fabricius

2015-01-01

Hot water injection into geothermal aquifers is considered in order to store energy seasonally. Berea sandstone is often used as a reference formation to study mechanisms that affect permeability in reservoir sandstones. Both heating of the pore fluid and reduction of the pore fluid salinity can...

New isotopic evidence for the origin of groundwater from the Nubian Sandstone Aquifer in the Negev, Israel

Science.gov (United States)

Vengosh, A.; Hening, S.; Ganor, J.; Mayer, B.; Weyhenmeyer, C.E.; Bullen, T.D.; Paytan, A.

2007-01-01

significantly to the salt budget of the Nubian Sandstone aquifer. The unique chemical and isotopic composition of the Jurassic groundwater (??34SSO4 ??? +14???; ??18OSO4 ??? 14???; 87Sr/86Sr ???0.70764) is interpreted as reflecting dissolution of Late Triassic marine gypsum deposits. In the southern Arava Valley the authors postulate that SO4-rich groundwater with distinctively high Br/Cl (3 ?? 10-3) low 87Sr/86Sr (0.70734), and high ??34SSO4 values (+15???) is derived from mixing with underlying brines from the Paleozoic units. The radiocarbon measurements reveal low 14C activities (0.2-5.8 pmc) in both the northeastern Negev and southern Arava Valley. Taking into account dissolution of carbonate rocks and bacterial SO4 reduction in the unconfined area, estimated mean residence times of groundwater in the confined zone in the northeastern Negev are on the order of 21-38 ka, which suggests recharge predominantly during the last glacial period. The 14C signal in groundwater from the southern Arava Valley is equally low but due to evidence for mixing with external water sources the residence time estimates are questionable. ?? 2007 Elsevier Ltd. All rights reserved.

Full-scale laboratory drilling tests on sandstone and dolomite. Final report

Energy Technology Data Exchange (ETDEWEB)

Black, A. D.; Green, S. J.; Rogers, L. A.

1977-08-01

Full-scale laboratory drilling experiments were performed under simulated downhole conditions to determine what effect changing various drilling parameters has on penetration rate. The two rock types, typical of deep oil and gas reservoirs, used for the tests were Colton Sandstone and Bonne Terre Dolomite. Drilling was performed with standard 7/sup 7///sub 8/ inch rotary insert bits and water base mud. The results showed the penetration rate to be strongly dependent on bit weight, rotary speed and borehole mud pressure. There was only a small dependence on mud flow rate. The drilling rate decreased rapidly with increasing borehole mud pressure for borehole pressures up to about 2,000 psi. Above this pressure, the borehole pressure and rotary speeds had a smaller effect on penetration rate. The penetration rate was then dependent mostly on the bit weight. Penetration rate per horsepower input was also shown to decrease at higher mud pressures and bit weights. The ratio of horizontal confining stress to axial overburden stress was maintained at 0.7 for simulated overburden stresses between 0 and 12,800 psi. For this simulated downhole stress state, the undrilled rock sample was within the elastic response range and the confining pressures were found to have only a small or negligible effect on the penetration rate. Visual examination of the bottomhole pattern of the rocks after simulated downhole drilling, however, revealed ductile chipping of the Sandstone, but more brittle behavior in the Dolomite.

The influence of climate on early and burial diagenesis of Triassic and Jurassic sandstones from the Norwegian – Danish Basin

DEFF Research Database (Denmark)

Weibel, Rikke; Olivarius, Mette; Kjøller, Claus

2017-01-01

Climate changes preserved in sandstones are documented by comparing the sediment composition and early diagenetic changes in sandstones deposited during arid to semi-arid conditions, the Skagerrak Formation, with sandstones of the Gassum Formation deposited in a humid well-vegetated environment...

Possible application of underground leaching of uranium in ''sandstone'' deposits by drilling method

International Nuclear Information System (INIS)

Bareja, E.

1988-01-01

Underground leaching as the method for excavation of uranium from its sandstone deposits is applied in many countries. A preliminary examination of a possible use of this method to sandstone deposits in Poland suggests it to be analysed against the uranium mineralization, noted within sediments of the Lower Triassic age in the Peribaltic Syneclise in the Krynica Morska - Paslek area. Before a definite decision on such exploitation of uranium, geologic and hydrogeologic conditions should be studied of individual uranium-bearing beds, particularly their permeability and insulation by impermeable claystone series as well as extraction of uranium from its bearing sandstones. The depth at which uranium-bearing beds occur, forms a very important item. The depth at which uranium ores described in literature and exploited by this method occur, does not exceed 700 m. 7 refs. (author)

Stable isotopic mass balance in sandstone-shale couplets. An example from the Neogene Pannonian Basin

International Nuclear Information System (INIS)

Matyas, J.; Geologisches Institut.

1996-01-01

Oxygen isotopic ratios of carbonate cements in the Neogene sandstones of the Pannonian Basin show distinct variations: early calcites 3-6 per mille lighter than the late calcites from the same location and depth. This shift is thought to be related to the isotopically heavy oxygen released from the mixed-layer illite/smectite during illitisation. For sandstones dominated by compactional flow, closed system mass balance calculations predict an isotopic shift comparable to that deducted from petrographic and geochemical observations. The model suggests that variations of geothermal gradient has little effect on isotopic evolution; much more significant is the sandstone: shale ratio in the couplets. (author)

Emanation-thermal characteristics of Ba-salts of some aromatic acids in the temperature range between 298 and 373 K

Energy Technology Data Exchange (ETDEWEB)

Balek, V; Prachar, M [Ustav Jaderneho Vyzkumu, Rez (Czechoslovakia); Kroupa, J [Vyzkumny Ustav Syntetickych Pryskyric a Laku, Pardubice (Czechoslovakia)

1977-01-01

The paper presents the emanation-thermal characteristics of Ba salts of some monocarboxylic acids (phtalic, isophtalic and terephtalic) and dicarboxylic acids (benzoic, salicylic, 1,4-aminobenzoic, 1,2-Cl-benzoic and 1,2-I-benzoic). It is shown that the emanation thermal characteristics measured in the temperature range between 298 and 373 K are suitable for estimating diffusion properties of studied organic solids. An apparatus for determining emanation-thermal characteristics is proposed.

Regional diagenesis of sandstone in the Upper Jurassic Morrison Formation, San Juan Basin, New Mexico and Colorado

International Nuclear Information System (INIS)

Hansley, P.L.

1990-01-01

The author reports that early authigenic mineral assemblages and vitroclastic textures are very well preserved in upper sandstones of the Upper Jurassic Morrison Formation. The distributions of the authigenic minerals were controlled, in part, by chemical gradients in a large saline, alkaline lake (Lake T'oo'dichi) that existed in late Morrison time. Sandstones on lake margins were cemented by smectite and silica, whereas sandstones nearer the lake center, in which waters were most saline and alkaline, were cemented by zeolites. Diagenetic alterations in sandstones were promoted by alkaline interstitial waters that emanated from adjacent fine-grained, tuffaceous lake beds. Metastable phases that precipitated first were replaced relatively quickly by more stable, ordered phases in the geochemically favorable environment of the closed basin setting. Elevation of temperatures above the geothermal gradient was proved by the influx of warm, deep-basin waters that locally modified early diagenetic assemblages during burial diagenesis. In organic- (and commonly also uranium ore-) bearing sandstones located primarily in the southern part of the basin, complex diagenetic assemblages resulted from water/rock reactions involving soluble organic complexes

Highway deicing salt dynamic runoff to surface water and subsequent infiltration to groundwater during severe UK winters.

Science.gov (United States)

Rivett, Michael O; Cuthbert, Mark O; Gamble, Richard; Connon, Lucy E; Pearson, Andrew; Shepley, Martin G; Davis, John

2016-09-15

Dynamic impact to the water environment of deicing salt application at a major highway (motorway) interchange in the UK is quantitatively evaluated for two recent severe UK winters. The contaminant transport pathway studied allowed controls on dynamic highway runoff and storm-sewer discharge to a receiving stream and its subsequent leakage to an underlying sandstone aquifer, including possible contribution to long-term chloride increases in supply wells, to be evaluated. Logged stream electrical-conductivity (EC) to estimate chloride concentrations, stream flow, climate and motorway salt application data were used to assess salt fate. Stream loading was responsive to salt applications and climate variability influencing salt release. Chloride (via EC) was predicted to exceed the stream Environmental Quality Standard (250mg/l) for 33% and 18% of the two winters. Maximum stream concentrations (3500mg/l, 15% sea water salinity) were ascribed to salt-induced melting and drainage of highway snowfall without dilution from, still frozen, catchment water. Salt persistance on the highway under dry-cold conditions was inferred from stream observations of delayed salt removal. Streambed and stream-loss data demonstrated chloride infiltration could occur to the underlying aquifer with mild and severe winter stream leakage estimated to account for 21 to 54% respectively of the 70t of increased chloride (over baseline) annually abstracted by supply wells. Deicing salt infiltration lateral to the highway alongside other urban/natural sources were inferred to contribute the shortfall. Challenges in quantifying chloride mass/fluxes (flow gauge accuracy at high flows, salt loading from other roads, weaker chloride-EC correlation at low concentrations), may be largely overcome by modest investment in enhanced data acquisition or minor approach modification. The increased understanding of deicing salt dynamic loading to the water environment obtained is relevant to improved

Properties and durability assessment of glauconitic sandstone: A case study on Zamel sandstone from Bohemian Cretaceous Basin (Czech Republic)

Czech Academy of Sciences Publication Activity Database

Martinec, Petr; Vavro, M.; Ščučka, Jiří; Mašláň, M.

2010-01-01

Roč. 115, 3/4 (2010), s. 175-181 ISSN 0013-7952 R&D Projects: GA ČR GP101/07/P512; GA ČR(CZ) GA103/07/1662 Institutional research plan: CEZ:AV0Z30860518 Keywords : building stone * sandstone * physical properties Subject RIV: DB - Geology ; Mineralogy Impact factor: 1.442, year: 2010 http://www.sciencedirect.com/science

Distribution of K, Na, Th and U in sandstones and shales from western Shikoku, Japan

International Nuclear Information System (INIS)

Ishihara, Shunso; Sakamaki, Yukio; Mochizuki, Tsunekazu; Terashima, Shigeru; Endo, Yuji

1981-01-01

The regional variation of K, Na, Th and U distributions was studied on 58 sandstones, 81 shales and 3 green schists from the sedimentary terrains across western Shikoku. The geological structure of the studied district is explained. The regional characteristics of the sedimentary rocks are best demonstrated in the composition of the sandstones. The sandstones, in the source areas of which granitic and rhyolitic rocks exist and which have been deposited rapidly, were rich in K, whereas those derived mainly from mafic volcanic areas showed high Na content. The sandstones of the Shimanto Supergroup had the intermediate values, and K and K + Na contents became low in the south where the younger Upper Shimanto Group is exposed. Th and U in both sandstones and shales were highest in the Izumi Group, and generally low in the Shimanto Supergroup. The black shales of the Shimanto Supergroup did not show U-anomaly. In each group, highly matured rocks gave slightly higher Th/U ratio. Highly matured polycyclic sediments contained the least amount of radioactive elements. The radioactive anomaly due to the anomalous K contained in sericite, and that due to U in black shale were found in Chichibu and Sambosan belts. Similar anomaly was discovered in the foot wall of Mn deposits in the same zone. The possibility of anomalous U may be the least in the Shimanto Supergroup. (Kako, I.)

An Effective Acid Combination for Enhanced Properties and Corrosion Control of Acidizing Sandstone Formation

International Nuclear Information System (INIS)

Shafiq, Mian Umer; Mahmud, Hisham Khaled Ben

2016-01-01

To fulfill the demand of the world energy, more technologies to enhance the recovery of oil production are being developed. Sandstone acidizing has been introduced and it acts as one of the important means to increase oil and gas production. Sandstone acidizing operation generally uses acids, which create or enlarge the flow channels of formation around the wellbore. In sandstone matrix acidizing, acids are injected into the formation at a pressure below the formation fracturing pressure, in which the injected acids react with mineral particles that may restrict the flow of hydrocarbons. Most common combination is Hydrofluoric Acid - Hydrochloric with concentration (3% HF - 12% HCl) known as mud acid. But there are some problems associated with the use of mud acid i.e., corrosion, precipitation. In this paper several new combinations of acids were experimentally screened to identify the most effective combination. The combinations used consist of fluoboric, phosphoric, formic and hydrofluoric acids. Cores were allowed to react with these combinations and results are compared with the mud acid. The parameters, which are analyzed, are Improved Permeability Ratio, strength and mineralogy. The analysis showed that the new acid combination has the potential to be used in sandstone acidizing. (paper)

Thermochemical Properties of Nicotine Salts

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Riggs DM

2014-12-01

Full Text Available The thermal gravimetric analysis (TGA and differential scanning calorimetry (DSC results presented in this report clearly show that the thermal stability and the endothermic peak nicotine release temperatures are different for different nicotine salts and these temperatures appear to be linked to the general microstructural details of the salt itself. In addition, the peak nicotine release temperatures are highly dependent upon the sample size used. The heat of vaporization for neat (non-protonated nicotine is also sample-size dependent. The TGA data showed that the least stable of the salts tested at elevated temperatures was the liquid salt nicotine triacetate followed by the crystalline materials (e.g., nicotine gallate and finally, the amorphous salts (e.g., nicotine alginate. The DSC results revealed that the liquid and crystalline salts exhibit nicotine release endotherms that are strongly related to the sample weight being tested. The amorphous salts show nicotine endotherm peak temperatures that are nearly independent of the sample weight. The range of peak nicotine release temperatures varied depending upon the specific salts and the sample size from 83 oC to well over 200 oC. Based on these results, the evolution of nicotine from the nicotine salt should be expected to vary based on the composition of the salt, the details of its microstructure, and the amount of nicotine salt tested.

The Collyhurst Sandstone as a secondary storage unit for CCS in the East Irish Sea Basin (UK)

Science.gov (United States)

Gamboa, D.; Williams, J. D. O.; Kirk, K.; Gent, C. M. A.; Bentham, M.; Schofield, D. I.

2016-12-01

Carbon Capture and Storage (CCS) is key technology for low-carbon energy and industry. The UK hosts a large CO2 storage potential offshore with an estimated capacity of 78 Gt. The East Irish Sea Basin (EISB) is the key area for CCS in the western UK, with a CO2 storage potential of 1.7 Gt in hydrocarbon fields and in saline aquifers within the Triassic Sherwood Sandstone Formation. However, this theoretical storage capacity does not consider the secondary storage potential in the lower Permian Collyhurst Sandstone Formation. 3D seismic data were used to characterise the Collyhurst Sandstone Formation in the EISB. On the southern basin domain, numerous fault-bound blocks limit the lateral continuity of the sandstone strata, while on the northern domain the sandstones are intersected by less faults. The caprock for the Collyhurst sandstones is variable. The Manchester Marls predominate in the south, transitioning to the St. Bees evaporites towards the north. The evaporites in the EISB cause overburden faults to terminate or detach along Upper Permian strata, limiting the deformation of the underlying reservoir units. Five main storage closures have been identified in the Permian strata. In the southern and central area these are predominantly fault bounded, occurring at depths over 1000m. Despite the higher Collyhurst sandstone thickness in the southern IESB, the dolomitic nature of the caprock constitutes a storage risk in this area. Closures in the northern area are deeper (around 2000-2500m) and wider, reaching areas of 34Km2, and are overlain by evaporitic caprocks. The larger Collyhurst closures to the north underlie large Triassic fields with high storage potential. The spatial overlap favours storage plans including secondary storage units in the EISB. The results of this work also expand the understanding of prospective areas for CO2 sequestration in the East Irish Sea Basin in locations where the primary Sherwood Sandstone Formation is either too shallow

An experimental study of the response of the Galesville sandstone to simulated CAES conditions

Energy Technology Data Exchange (ETDEWEB)

Erikson, R L; Stottlemyre, J A; Smith, R P

1980-07-01

The objective of this experimental study was to determine how the mineralogical and physical characteristics of host rock formations are affected by environmental conditions anticipated for compressed air energy storage (CAES) in porous, permeable rock. In this study, Galesville sandstone cores were reacted in autoclave pressure vessels supporting one of four environments: dry air; heated, air-water vapor; heated, nitrogen-water vapor mixtures; and heated, compressed, liquid water. The simulated CAES environments were maintained in autoclave pressure vessels by controlling the following independent variables: temperature, pressure, time, oxygen content, carbon dioxide content, nitrogen content, and liquid volume. The dependent variables studied were: apparent porosity, gas permeability, water permeability, and friability. These variables were measured at ambient temperature and pressure before and after each sandstone sample was reacted in one of the CAES environments. The experiments gave the following results: the Galesville sandstone exhibited excellent stability in dry air at all temperatures tested (50/sup 0/ to 300/sup 0/C); and significant physical alterations occurred in sandstone samples exposed to liquid water above 150/sup 0/C. Samples shielded from dripping water exhibited excellent stability to 300/sup 0/C; sandstone may be a suitable storage media for heated, humid air provided elevated temperature zones are relatively free of mobile liquid water; and observed changes in the physical properties of the rock may have been caused, in part, by the lack of confining stress on the sample. The inability to apply confining pressure is a severe limitation of autoclave experiments.

Remote sensing information acquisition of paleo-channel sandstone-type uranium deposit in Nuheting area

International Nuclear Information System (INIS)

Liu Jianjun

2000-01-01

The author briefly describes the genesis and ore-formation mechanism of paleo-channel sandstone-type uranium deposit in Nuheting area. Techniques such as remote sensing digital image data processing and data enhancement, as well as 3-dimension quantitative analysis of drill hole data are applied to extract information on metallogenic environment of paleo-channel sandstone-type uranium deposit and the distribution of paleo-channel

Temperature Effects on Stiffness Moduli of Reservoir Sandstone from the Deep North Sea

DEFF Research Database (Denmark)

Orlander, Tobias; Andreassen, Katrine Alling; Fabricius, Ida Lykke

We investigate effect of testing temperature on the dynamic frame stiffness of quartz-bearing North Sea sandstone from depths of 5 km. We show that at low stress levels, the rock frame stiffens with increasing temperature and we propose an explanation for the controlling mechanisms. While...... temperature. This is unfortunate and hence, we designed a testing program with the intension of separating and quantifying effects of temperature and stress, specifically for the sandstone material subject to this study....

The effect of hot water injection on sandstone permeability

DEFF Research Database (Denmark)

Rosenbrand, Esther; Haugwitz, Christian; Jacobsen, Peter Sally Munch

2014-01-01

Seasonal energy storage can be achieved by hot water injection in geothermal sandstone aquifers. We present an analysis of literature data in combination with new short-term flow through permeability experiments in order to address physical and physico-chemical mechanisms that can alter...

Influence of fluvial sandstone architecture on geothermal energy production

NARCIS (Netherlands)

Willems, C.J.L.; Maghami Nick, Hamidreza M.; Weltje, G.J.; Donselaar, M.E.; Bruhn, D.F.

2015-01-01

Fluvial sandstone reservoirs composed of stacked meander belts are considered as potential geothermal resources in the Netherlands. Net-to-gross, orientation and stacking pattern of the channel belts is of major importance for the connectivity between the injection and production well in such

Experimental Study of Cement - Sandstone/Shale - Brine - CO2 Interactions.

Science.gov (United States)

Carroll, Susan A; McNab, Walt W; Torres, Sharon C

2011-11-11

Reactive-transport simulation is a tool that is being used to estimate long-term trapping of CO2, and wellbore and cap rock integrity for geologic CO2 storage. We reacted end member components of a heterolithic sandstone and shale unit that forms the upper section of the In Salah Gas Project carbon storage reservoir in Krechba, Algeria with supercritical CO2, brine, and with/without cement at reservoir conditions to develop experimentally constrained geochemical models for use in reactive transport simulations. We observe marked changes in solution composition when CO2 reacted with cement, sandstone, and shale components at reservoir conditions. The geochemical model for the reaction of sandstone and shale with CO2 and brine is a simple one in which albite, chlorite, illite and carbonate minerals partially dissolve and boehmite, smectite, and amorphous silica precipitate. The geochemical model for the wellbore environment is also fairly simple, in which alkaline cements and rock react with CO2-rich brines to form an Fe containing calcite, amorphous silica, smectite and boehmite or amorphous Al(OH)3. Our research shows that relatively simple geochemical models can describe the dominant reactions that are likely to occur when CO2 is stored in deep saline aquifers sealed with overlying shale cap rocks, as well as the dominant reactions for cement carbonation at the wellbore interface.

Lattice strain measurements on sandstones under load using neutron diffraction

Science.gov (United States)

Frischbutter, A.; Neov, D.; Scheffzük, Ch.; Vrána, M.; Walther, K.

2000-11-01

Neutron diffraction methods (both time-of-flight- and angle-dispersive diffraction) are applied to intracrystalline strain measurements on geological samples undergoing uniaxial increasing compressional load. The experiments were carried out on Cretaceous sandstones from the Elbezone (East Germany), consisting of >95% quartz which are bedded but without crystallographic preferred orientation of quartz. From the stress-strain relation the Young's modulus for our quartz sample was determined to be (72.2±2.9) GPa using results of the neutron time-of-flight method. The influence of different kinds of bedding in sandstones (laminated and convolute bedding) could be determined. We observed differences of factor 2 (convolute bedding) and 3 (laminated bedding) for the elastic stiffness, determined with angle dispersive neutron diffraction (crystallographic strain) and with strain gauges (mechanical strain). The data indicate which geological conditions may influence the stress-strain behaviour of geological materials. The influence of bedding on the stress-strain behaviour of a laminated bedded sandstone was indicated by direct residual stress measurements using neutron time-of-flight diffraction. The measurements were carried out six days after unloading the sample. Residual strain was measured for three positions from the centre to the periphery and within two radial directions of the cylinder. We observed that residual strain changes from extension to compression in a different manner for two perpendicular directions of the bedding plane.

Cathodoluminescence, fluid inclusions and trace element data for the syntaxial quartz cementation in the sandstones of Ora Formation, northern Iraq

DEFF Research Database (Denmark)

Omer, Muhamed Fakhri; Friis, Henrik

2018-01-01

Quartz cements of the quartz arenitic sandstones from the Chalky Nasara and Ora section of the (Devonian-Carboniferous) Ora Formation in northern Iraq have been studied. A combination of Hot-Cathodoluminescence (CL), LA-ICP-MS and fluid inclusions microthermometry revealed three syntaxial quartz......-bedded sandstones than in the6 thickly-bedded sandstones filling most of remaining pore space during mesogenesis. The Q3 was formed during early telogenesis stage fully cementing the sandstones and the fractures were filled by hydrothermal chlorite and sulfides. Significant amount of trace elements Al, Li, Ge...

Nivelstein sandstone, weakly lithified pure silica sands from the Dutch-German border area, intermittently used in architecture for two millennia

Science.gov (United States)

Nijland, Timo G.; Wim Dubelaar, C.

2017-04-01

The current paper provides a concise overview of the geological setting of the Nivelstein sandstone in broad sense, its petrographic and physical characteristics, and its use as natural stone. Miocene pure silica sands occur around Heerlen in the southeastern part of the Dutch province of Limburg and Herzogenrath in adjacent Germany, as well as in the Belgian province of Limburg near Opgrimbie. In Dutch Limburg and in Germany are three large active exploitations, quarrying the sands for industrial purposes. On top of the unconsolidated sands in the Herzogenrath quarry, lithified banks of sandstone occur, known as Nivelstein (or more rarely Herzogenrath) sandstone. This sandstone has been used as dimension stone and ornamental stone since Roman times. In the 11th century the quarry was reopened and after a long period of disuse sandstone blocks were again quarried in the second half of the 19th century. The lithification of the Nivelstein sandstone usually is very weak, with grain to grain contacts and some newly formed quartz rims only. The clay content is extremely low and is restricted to tiny booklets of kaolinite. Despite the weak cementation the Nivelstein sandstone has proved to be very time-resistant building stone that forms a major element in the stone cultural heritage of the Dutch- German border area.

PETROFACIES CHARACTERISTICS OF THE SANDSTONES OF THE UPPER MIOCENELOWER PLIOCENE AGED IN THE ULUMUHSİNE-TATKÖY (KONYA AREA

Directory of Open Access Journals (Sweden)

A. Müjdat ÖZKAN

2000-03-01

Full Text Available In the study area, Upper Miocene-Lower Pliocene aged Ulumuhsine formation, was formed in a shallow, open lake and river environment. The lithologies of this formation are thin-medium bedded, laminated and fossil rich limestone, thin-thick bedded mudstone, thin-thick bedded marl, thin-thick bedded dolomite with stromatolite interbedded limestone, tuffite, chert bands and coal-rich levels. In addition, it includes conglomerates and sandstones of underwater distrubution channels in lacustrine, and channel and bar sediments in stream environments. Red, gray, rarely green colored sandstones are thin-thick bedded, and in some levels well sorting, in some levels proorly sorting. They present sedimentary structures, as graded, herringbone cross-bedding, symmetric ripple-marks, and laminate. Sandstones are named lithic arenite and lithic graywacke and litharenite, feldspathic litharenite and sublithic arenite. These sandstones are rich rock fragments and quartzs, in addition they contain plagioclase, biotite, muskovite, opaque mineral and epidote. Binding materials of sandstones are mainly calcite cements and clay matrix, and iron oxide cement in little amount. From the mineralogical and textural point of view. As a tectonic environment, the main source of sandstones are recycled orogen (thrust, collision and land uplift and recyded lithic fragments.

provenance of sandstone on the western flank of anambra basin

African Journals Online (AJOL)

HP

GLOBAL JOURNAL OF GEOLOGICAL SCIENCES VOL. 14, 2016: 13-21. COPYRIGHT© ... from Fugar locality. The sandstones each classify as quartz arenites and sublitharenites. ... Tectonic movement in the Santonian times resulted in the ...

Evaluation of salt content in school meals

Directory of Open Access Journals (Sweden)

Cláudia Alexandra Colaço Lourenço Viegas

2015-04-01

Full Text Available OBJECTIVE: High blood pressure is a major rick factor for cardiovascular disease, and it is closely associated with salt intake. Schools are considered ideal environments to promote health and proper eating habits. Therefore the objective of this study was to evaluate the amount of salt in meals served in school canteens and consumers' perceptions about salt. METHODS: Meals, including all the components (bread, soup, and main dish were retrieved from school canteens. Salt was quantified by a portable salt meter. For food perception we constructed a questionnaire that was administered to high school students. RESULTS: A total of 798 food samples were analysed. Bread had the highest salt content with a mean of 1.35 g/100 g (SD=0.12. Salt in soups ranged from 0.72 g/100 g to 0.80 g/100 g (p=0.05 and, in main courses, from 0.71 g/100 to 0.97 g/100g (p=0.05. The salt content of school meals is high with a mean value of 2.83 to 3.82 g of salt per meal. Moreover, a high percentage of students consider meals neither salty nor bland, which shows they are used to the intensity/amount of salt consumed. CONCLUSION: The salt content of school meals is high, ranging from 2 to 5 times more than the Recommended Dietary Allowances for children, clearly exceeding the needs for this population, which may pose a health risk. Healthy choices are only possible in environments where such choices are possible. Therefore, salt reduction strategies aimed at the food industry and catering services should be implemented, with children and young people targeted as a major priority.

Applications of molten salts in plutonium processing

International Nuclear Information System (INIS)

Bowersox, D.F.; Christensen, D.C.; Williams, J.D.

1987-01-01

Plutonium is efficiently recovered from scrap at Los Alamos by a series of chemical reactions and separations conducted at temperatures ranging from 700 to 900 0 C. These processes usually employ a molten salt or salt eutectic as a heat sink and/or reaction medium. Salts for these operations were selected early in the development cycle. The selection criteria are being reevaluated. In this article we describe the processes now in use at Los Alamos and our studies of alternate salts and eutectics

Discussion on several problems on the mineralization of paleo-channel sandstone type uranium deposits

International Nuclear Information System (INIS)

Huang Shijie

1997-01-01

On the basis of comprehensively analyzing paleo-channel sandstone type uranium deposits at home and abroad, the author discusses the division of mineralization types of paleo-channel sandstone type uranium deposits, and analyzes the metallogenic geologic conditions such as regional geologic background, climatic and geomorphological conditions, basement and sedimentary cover, characteristics of paleo-valley and paleo-channel, mineralization features as well as epigenetic metallogenic process. Future prospecting direction is also proposed

Clay minerals in sandstone uranium deposits: radwaste applications

International Nuclear Information System (INIS)

Brookins, D.G.

1990-01-01

Clay minerals play an important role in the genesis of uranium deposits in sandstones. They incorporate the rate earths (REE), U, Sb, Th, Cs, Rb, Sr, Y, Ba, and even small amounts of chalcophiles. These minerals possess analog elements for many of the radwaste fission products as well as actinides and some actinide daughters. In sandstone uranium deposits, clay minerals are also associated with sulfide minerals, usually pyrite, and organic carbonaceous matter. The primary clay minerals are usually smectites, illites, chlorites and mixed layer varieties. The integrity of these clay minerals is demonstrated by their retention of formational-mineralization ages determined by Rb-Sr geochronologic investigation of the Grants Mineral Belt of the United States. The importance of the clay minerals as analog for parts of the multi-barrier concept in radwaste disposal is their ability to impede water penetration into - and movement of key elements out of uranium rich zones. The clay minerals further sorb and in other ways incorporate into their structures many fission products and actinide analogs from man-made nuclear wastes. 22 refs., 1 fig., 3 tabs

Modelling of a diffusion-sorption experiment on sandstone

International Nuclear Information System (INIS)

Smith, P.A.

1989-11-01

The results of a diffusion-sorption experiment on a sample of Darley Dale sandstone, using simulated groundwater spiked with a mixture of 125 I, 85 Sr and 137 Cs, are modelled by a one-dimensional porous medium approach in which sorption is described by Freundlich isotherms. The governing equations are solved analytically for the special case of a linear isotherm, and numerically using the computer code RANCHDIFF for non-linear isotherms. A set of time-dependent, ordinary differential equations is obtained using the Lagrange interpolation technique and integrated by Gear's variable order predictor-corrector method. It is shown that the sorption behaviour of 85 Sr can be modelled successfully by a linear isotherm, using a sorption parameter consistent with batch-sorption tests. The behaviour of 137 Cs may be modelled by a non-linear isotherm, but the amount of 137 Cs sorbed is less than that anticipated from batch-sorption tests. 125 I is assumed to be non-sorbing and is used to determine the porosity of the sandstone. (author) 10 figs., 4 tabs., 6 refs

Molten salt thermal energy storage systems: salt selection

Energy Technology Data Exchange (ETDEWEB)

Maru, H.C.; Dullea, J.F.; Huang, V.S.

1976-08-01

A research program aimed at the development of a molten salt thermal energy storage system commenced in June 1976. This topical report describes Work performed under Task I: Salt Selection is described. A total of 31 inorganic salts and salt mixtures, including 9 alkali and alkaline earth carbonate mixtures, were evaluated for their suitability as heat-of-fusion thermal energy storage materials at temperatures of 850 to 1000/sup 0/F. Thermophysical properties, safety hazards, corrosion, and cost of these salts were compared on a common basis. We concluded that because alkali carbonate mixtures show high thermal conductivity, low volumetric expansion on melting, low corrosivity and good stability, they are attractive as heat-of-fusion storage materials in this temperature range. A 35 wt percent Li/sub 2/CO/sub 3/-65 wt percent K/sub 2/CO/sub 3/ (50 mole percent Li/sub 2/CO/sub 3/-50 mole percent K/sub 2/CO/sub 3/) mixture was selected as a model system for further experimental work. This is a eutectoid mixture having a heat of fusion of 148 Btu/lb (82 cal/g) that forms an equimolar compound, LiKCO/sub 3/. The Li/sub 2/CO/sub 3/-K/sub 2/CO/sub 3/ mixture is intended to serve as a model system to define heat transfer characteristics, potential problems, and to provide ''first-cut'' engineering data required for the prototype system. The cost of a thermal energy storage system containing this mixture cannot be predicted until system characteristics are better defined. However, our comparison of different salts indicated that alkali and alkaline earth chlorides may be more attractive from a salt cost point of view. The long-term corrosion characteristics and the effects of volume change on melting for the chlorides should be investigated to determine their overall suitability as a heat-of-fusion storage medium.

Metallogenic characteristics, model and exploration prospect for the paleo-interlayer-oxidation type sandstone-hosted uranium deposits in China

International Nuclear Information System (INIS)

Huang Jingbai; Li Shengxiang

2007-01-01

In this paper, the paleo-interlayer-oxidation type sandstone-hosted uranium deposits occurred in the Meso-Cenozoic continental basins in China are divided into 3 subtype, they are stratum over lapping buried subtype, structure-uplifting destroy subtype and faulted-folding conserved subtype. The metallogenic characteristics, metallogenic model and exploration prospect for these 3 subtypes uranium deposits are discussed. It is proposed that the paleo-interlayer-oxidation type sandstone-hosted uranium deposits, besides the recent interlayer oxidation type sandstone-hosted uranium deposits, are of great prospecting potential in the Meso-Cenozoic continental basins in China. Therefore, the metallogenic theory of these types uranium deposits should be conscientiously summarized and replenished continuously so as to propel forward the exploration of the sandstone-hosted uranium deposits in China. (authors)

Preliminary research on finite difference method to solve radon field distribution over sandstone-type uranium ore body

International Nuclear Information System (INIS)

Li Bihong; Shuang Na; Liu Qingcheng

2006-01-01

The principle of finite difference method is introduced, and the radon field distribution over sandstone-type uranium deposit is narrated. The radon field distribution theory equation is established. To solve radon field distribution equation using finite difference algorithm is to provide the value computational method for forward calculation about radon field over sandstone-type uranium mine. Study on 2-D finite difference method on the center of either high anomaly radon fields in view of the character of radon field over sandstone-type uranium provide an algorithm for further research. (authors)

CHARACTERIZATION OF SANDSTONE RESERVOIRS FOR ENHANCED OIL RECOVERY: THE PERMIAN UPPER MINNELUSA FORMATION, POWDER RIVER BASIN, WYOMING.

Science.gov (United States)

Schenk, C.J.; Schmoker, J.W.; Scheffler, J.M.

1986-01-01

Upper Minnelusa sandstones form a complex group of reservoirs because of variations in regional setting, sedimentology, and diagenetic alteration. Structural lineaments separate the reservoirs into northern and southern zones. Production in the north is from a single pay sand, and in the south from multi-pay sands due to differential erosion on top of the Upper Minnelusa. The intercalation of eolian dune, interdune, and sabkha sandstones with marine sandstones, carbonates, and anhydrites results in significant reservoir heterogeneity. Diagenetic alterations further enhance heterogeneity, because the degree of cementation and dissolution is partly facies-related.

Uranium-series disequilibria as a means to study recent migration of uranium in a sandstone-hosted uranium deposit, NW China

International Nuclear Information System (INIS)

Min Maozhong; Peng Xinjian; Wang Jinping; Osmond, J.K.

2005-01-01

Uranium concentration and alpha specific activities of uranium decay series nuclides 234 U, 238 U, 230 Th, 232 Th and 226 Ra were measured for 16 oxidized host sandstone samples, 36 oxic-anoxic (mineralized) sandstone samples and three unaltered primary sandstone samples collected from the Shihongtan deposit. The results show that most of the ores and host sandstones have close to secular equilibrium alpha activity ratios for 234 U/ 238 U, 230 Th/ 238 U, 230 Th/ 234 U and 226 Ra/ 230 Th, indicating that intensive groundwater-rock/ore interaction and uranium migration have not taken place in the deposit during the last 1.0 Ma. However, some of the old uranium ore bodies have locally undergone leaching in the oxidizing environment during the past 300 ka to 1.0 Ma or to the present, and a number of new U ore bodies have grown in the oxic-anoxic transition (mineralized) subzone during the past 1.0 Ma. Locally, uranium leaching has taken place during the past 300 ka to 1.0 Ma, and perhaps is still going on now in some sandstones of the oxidizing subzone. However, uranium accumulation has locally occurred in some sandstones of the oxidizing environment during the past 1 ka to 1.0 Ma, which may be attributed to adsorption of U(VI) by clays contained in oxidized sandstones. A recent accumulation of uranium has locally taken place within the unaltered sandstones of the primary subzone close to the oxic-anoxic transition environment during the past 300 ka to 1.0 Ma. Results from the present study also indicate that uranium-series disequilibrium is an important tool to trace recent migration of uranium occurring in sandstone-hosted U deposits during the past 1.0 Ma and to distinguish the oxidation-reduction boundary

Ultrasonic Technique for Predicting Grittiness of Salted Duck Egg

Science.gov (United States)

Erawan, S.; Budiastra, I. W.; Subrata, I. D. M.

2018-05-01

Grittiness of egg yolk is a major factor in consumer acceptance of salted duck egg product. Commonly, the grittiness level is determined by the destructive method. Salted egg industries need a grading system that can judge the grittiness accurately and nondestructively. The purpose of this study was to develop a method for determining grittiness of salted duck eggs nondestructively based on ultrasonic method. This study used 100 samples of salted duck eggs with 7,10,14 and 21 days of salting age. Velocity and attenuation were measured by an ultrasonic system at frequency 50 kHz, followed by physicochemical properties measurement (hardness of egg yolks and salt content), and organoleptic test. Ultrasonic wave velocity in salted duck eggs ranged from 620.6 m/s to 1334.6 m/s, while the coefficient of attenuation value ranged from – 0.76 dB/m to -0.51 dB/m. Yolk hardness was 2.68 N at 7 days to 5.54 N at 21 days of salting age. Salt content was 1.81 % at 7 days to 5.71 % at 21 days of salting age. Highest scores of organoleptic tests on salted duck eggs were 4.23 and 4.18 for 10 and 14 days of salting age, respectively. Discriminant function using ultrasonic velocity variables in minor and major diameter could predict grittiness with 95 % accuracy.

Prospect analysis for sandstone-type uranium mineralization in the northern margin of Qaidam basin

International Nuclear Information System (INIS)

Liu Lin; Song Xiansheng; Feng Wei; Song Zhe; Li Wei

2010-01-01

Affected by the regional geological structural evolution, a set of sedimentary structure, i.e. the construction of coal-bearing classic rocks which is in favor of the sandstone-type uranium mineralization has deposited in the northern margin of Qaidam Basin since Meso-Cenozoic. A NWW thrust nappe tectonic belt, i.e. the ancient tectonic belt which is the basis for the development of ancient interlayer oxidation zone formed by the tectonic reverse in late Jurassic and Cretaceous. The Mid and late Jurassic layer was buried by the weak extension in Paleogene and the depression in early Neogene. The extrusion reversal from late Neogene to Quaternary made the basin into the development era of the modern interlayer oxidation zone. It can be concluded that the layer of the northern margin of Qaidam Basin has the premise for the formation of sandstone-type uranium ore. Based on the analysis of the characteristics of the thrust belt, the structure of the purpose layer, the sand body, the hydrogeology, the interlayer oxidation zone and uranium mineralization, the results indicated that the ancient interlayer oxidation zone is the prospecting type of sandstone-type uranium ore. Beidatan and the east of Yuqia are the favorable prospective area of sandstone-type uranium mineralization. (authors)

The migration of uranium through sandstone

International Nuclear Information System (INIS)

Bennett, D.G.; Read, D.; Lawless, T.A.; Sims, R.J.

1992-01-01

Three column experiments are described in which the migration of uranium through Clashach Sandstone was studied. A priori predictions of uranium migration in the experiments were made using an equilibrium chemical transport model. The experimental results showed that, even under oxidising conditions, the migration of uranium is strongly retarded owing to the affinity of uranium for mineral surfaces. For the relatively simple chemical system investigated, the chemical transport model was successful in predicting the migration of uranium and its distribution along the column. (author)

Petrographic characteristic of the sandstones of the upper paleocene-middle eocene aged in the Yildizli-Aydinkent (Ereğli-Konya area

Directory of Open Access Journals (Sweden)

A. Müjdat Özkan

2002-03-01

Full Text Available In the study area, Upper Paleocene - Middle Eocene aged Halkapınar formation, was formed in a shallow and deep marine environment. The lithologies of this formation are medium - thick bedded conglomerate, thin - thick bedded sandstone, thin - very thick bedded shale, thin - medium bedded marl with chert nodules and bands. In addition olistolithes of ophiolitic melange are found at the top of the sandstones, which includes basalt interbands. Yellowish gray, greenish gray, beige, gray colored sandstones include some sedimentary structures, namely ripple - marks, graded bedding, laminate, convolute lamination, current ripple, tool marks. Constituents of the sandstones are quartz, plagioclase, sanidine, orthoclase, fragments of sedimentary and methamorphic rocks, biotite, muscovite, opaque mineral and glauconite. The sandstones, which are not matured in terms of mineralogy and texture, are mainly cemented by calcite, clay matrix and minor iron oxide and glauconite matrix. The sandstones are named lithic arenite, lithic graywacke, feldspathic litharenite and litharenite.

Sandstone uranium deposits of Meghalaya: natural analogues for radionuclide migration and backfill material in geological repository for high level radioactive waste disposal

International Nuclear Information System (INIS)

Bajpai, R.K.; Narayan, P.K.

2008-01-01

Sandstone uranium deposits serve as potential natural analogue to demonstrate safety offered by geological media against possible release of nuclear waste from their confinement and migration towards biosphere. In this study, available database on geochemical aspects of Domisiat uranium deposit of Meghalaya has been evaluated to highlight the behavior of radionuclides of concern over long term in a geological repository. Constituents like actinides (U and Th), fission products and RE elements are adequately retained in clays and organic matters associated with these sandstone deposits. The study also highlights the possibility of utilization of lean ore discarded during mining and milling as backfill material in far field areas and optimizing near field buffers/backfills in a geological repository located in granitic rocks in depth range of 400-500m. (author)

Diagenesis and reservoir quality of the Lower Cretaceous Quantou Formation tight sandstones in the southern Songliao Basin, China

Science.gov (United States)

Xi, Kelai; Cao, Yingchang; Jahren, Jens; Zhu, Rukai; Bjørlykke, Knut; Haile, Beyene Girma; Zheng, Lijing; Hellevang, Helge

2015-12-01

The Lower Cretaceous Quantou Formation in the southern Songliao Basin is the typical tight oil sandstone in China. For effective exploration, appraisal and production from such a tight oil sandstone, the diagenesis and reservoir quality must be thoroughly studied first. The tight oil sandstone has been examined by a variety of methods, including core and thin section observation, XRD, SEM, CL, fluorescence, electron probing analysis, fluid inclusion and isotope testing and quantitative determination of reservoir properties. The sandstones are mostly lithic arkoses and feldspathic litharenites with fine to medium grain size and moderate to good sorting. The sandstones are dominated by feldspar, quartz, and volcanic rock fragments showing various stages of disintegration. The reservoir properties are quite poor, with low porosity (average 8.54%) and permeability (average 0.493 mD), small pore-throat radius (average 0.206 μm) and high displacement pressure (mostly higher than 1 MPa). The tight sandstone reservoirs have undergone significant diagenetic alterations such as compaction, feldspar dissolution, quartz cementation, carbonate cementation (mainly ferrocalcite and ankerite) and clay mineral alteration. As to the onset time, the oil emplacement was prior to the carbonate cementation but posterior to the quartz cementation and feldspar dissolution. The smectite to illite reaction and pressure solution at stylolites provide a most important silica sources for quartz cementation. Carbonate cements increase towards interbedded mudstones. Mechanical compaction has played a more important role than cementation in destroying the reservoir quality of the K1q4 sandstone reservoirs. Mixed-layer illite/smectite and illite reduced the porosity and permeability significantly, while chlorite preserved the porosity and permeability since it tends to be oil wet so that later carbonate cementation can be inhibited to some extent. It is likely that the oil emplacement occurred

Tertiary lithofacies and paleo-geographic framework and interlayer oxidation zone sandstone uranium deposits in Longjiang-Zhaozhou area

International Nuclear Information System (INIS)

Zhang Zhenqiang

2003-01-01

The main points of views for the experiment are: (1) Yi'an formation is mainly composed of limnetic facies of siltstone and fine sandstone, due to weak surface water, limited sedimentation and simple material source; (2) strengthened surface water and enormous material brought from north and west-north and enlarged sedimentation from north to south, the major deposition during Da'an period are channel facies of conglomerate and river bed facies of sandstone; (3) stronger surface water during Taikang period, led alluvial-flood plain facies brown-yellow conglomerate to develop along western margin of the basin, the channel facies of conglomerate and river bed facies of grey-green sandstone, pelitic siltstone were widely formed southward and eastward; (4) according to the lithofacies criterion for in-situ leachable sandstone uranium ore, Taikang formation is an ideal horizon, river bed facies is suitable for interlayer oxidation type uranium deposit. (author)

Petrology of arkosic sandstones, Pennsylvanian Minturn Formation and Pennsylvanian and Permian Sangre de Cristo Formation, Sangre de Cristo Range, Colorado - data and preliminary interpretations

Science.gov (United States)

Lindsey, D.A.

2000-01-01

This report describes the mineral and chemical composition of immature, arkosic sandstones of the Pennsylvanian Minturn and Pennsylvanian and Permian Sangre de Cristo Formations, which were derived from the Ancestral Rocky Mountains. Located in the Sangre de Cristo Range of southern Colorado, the Minturn and Sangre de Cristo Formations contain some of the most immature, sodic arkoses shed from the Ancestral Rocky Mountains. The Minturn Formation was deposited as fan deltas in marine and alluvial environments; the Sangre de Cristo Formation was deposited as alluvial fans. Arkoses of the Minturn and Sangre de Cristo Formations are matrix-rich and thus may be properly considered arkosic wackes in the terminology of Gilbert (Williams and others, 1954). In general, potassium feldspar and plagioclase are subequal in abundance. Arkose of the Sangre de Cristo Formation is consistently plagioclase-rich; arkose from the Minturn Formation is more variable. Quartz and feldspar grains are accompanied by a few percent rock fragments, consisting mostly of intermediate to granitic plutonic rocks, gneiss, and schist. All of the rock fragments seen in sandstone are present in interbedded conglomerate, consistent with derivation from a Precambrian terrane of gneiss and plutonic rocks much like that exposed in the present Sangre de Cristo Range. Comparison of mineral and major oxide abundances reveals a strong association of detrital quartz with SiO2, all other detrital minerals (totaled) with Al2O3, potassium feldspar plus mica with K2O, and plagioclase with Na2O. Thus, major oxide content is a good predictor of detrital mineralogy, although contributions from matrix and cement make these relationships less than perfect. Detrital minerals and major oxides tend to form inverse relationships that reflect mixtures of varying quantities of minerals; when one mineral is abundant, the abundance of others declines by dilution. In arkose of the Minturn and Sangre de Cristo Formations, the

Experimental Investigation on Hydraulic Properties of Granular Sandstone and Mudstone Mixtures

Directory of Open Access Journals (Sweden)

Dan Ma

2018-01-01

Full Text Available The caved zone during longwall mining has high permeability, resulting in a mass of groundwater storage which causes a threat of groundwater inrush hazard to the safe mining. To investigate the hazard mechanism of granular sandstone and mudstone mixture (SMM in caved zone, this paper presents an experimental study on the effect of sandstone particle (SP and mudstone particle (MP weight ratio on the non-Darcy hydraulic properties evolution. A self-designed granular rock seepage experimental equipment has been applied to conduct the experiments. The variation of particle size distribution was induced by loading and water seepage during the test, which indicated that the particle crushing and erosion properties of mudstone were higher than those of sandstone. Porosity evolution of SMM was strongly influenced by loading (sample height and SP/MP weight ratio. The sample with higher sample height and higher weight ratio of SP achieved higher porosity value. In particular, a non-Darcy equation, for hydraulic properties (permeability κ and non-Darcy coefficient ζ calculation, was sufficient to fit the relation between the hydraulic gradient and seepage velocity. The test results indicated that, due to the absence and narrowing of fracture and void during loading, the permeability κ decreases and the non-Darcy coefficient ζ increases. The variation of the hydraulic properties of the sample within the same particle size and SP/MP weight ratio indicated that groundwater inrush hazard showed a higher probability of occurrence in sandstone strata and crushed zone (e.g., faults. Moreover, isolated fractures and voids were able to achieve the changeover from self-extension to interconnection at the last loading stage, which caused the fluctuation tendency of κ and ζ. Fluctuation ability in mudstone was higher than that in sandstone. The performance of an empirical model was also investigated for the non-Darcy hydraulic properties evolution prediction of

Density, viscosity, and N2O solubility of aqueous amino acid salt and amine amino acid salt solutions

International Nuclear Information System (INIS)

Aronu, Ugochukwu E.; Hartono, Ardi; Svendsen, Hallvard F.

2012-01-01

Highlights: ► Density of amino acid salt and amine amino acid salt. ► Viscosity of amino acid salt and amine amino acid salt. ► Henry’s law constant/N 2 O solubility of amino acid salt and amine amino acid salt. ► Schumpe model. Correlations for density, viscosity, and N 2 O solubility. - Abstract: Physicochemical properties of aqueous amino acid salt (AAS), potassium salt of sarcosine (KSAR) and aqueous amine amino acid salt (AAAS), 3-(methylamino)propylamine/sarcosine (SARMAPA) have been studied. Densities of KSAR were measured for sarcosine mole fraction 0.02 to 0.25 for temperature range 298.15 K to 353.15 K, the viscosities were measured for 0.02 to 0.10 mole fraction sarcosine (293.15 K to 343.15 K) while the N 2 O solubilities were measured from 0.02 to 0.10 mole fraction sarcosine solutions (298.15 K to 363.15 K). Densities of SARMAPA were measured for sarcosine mole fraction 0.02 to 0.23 for temperature range (298.15 K to 353.15 K), viscosities were measured for 0.02 to 0.16 mole fraction sarcosine (293.15 K to 343.15 K) while the N 2 O solubilities were measured from 0.02 to 0.16 mole fraction sarcosine solutions (298.15 K to 343.15 K). Experimental results were correlated well with empirical correlations and N 2 O solubility results for KSAR were predicted adequately by a Schumpe model. The solubilities of N 2 O in AAS and AAAS are significantly lower than values for amines. The solubilities vary as: amine > AAAS > AAS.

Self-monitoring urinary salt excretion in adults: A novel education program for restricting dietary salt intake.

Science.gov (United States)

Yasutake, Kenichiro; Sawano, Kayoko; Yamaguchi, Shoko; Sakai, Hiroko; Amadera, Hatsumi; Tsuchihashi, Takuya

2011-07-01

This study aimed to examine the usefulness of the self-monitoring of urinary salt excretion for educating individuals about the risk of excessive dietary salt intake. The subjects were 30 volunteers (15 men and 15 women) not consuming anti-hypertensive medication. The subjects measured urinary salt excretion at home for 4 weeks using a self-monitoring device. Blood pressure (BP), anthropometric variables and nutritional variables (by a dietary-habits questionnaire) were measured before and after the measurement of urinary salt excretion. Statistical analyses were performed, including paired t-tests, Chi-square test, Pearson's product moment correlation coefficient and multiple linear regression analysis. In all subjects, the average urinary salt excretion over 4 weeks was 8.05±1.61 g/day and the range (maximum-minimum value) was 5.58±2.15 g/day. Salt excretion decreased significantly in weeks 3 and 4 (Pself-monitoring device appears to be an effective educational tool for improving the quality of life of healthy adults.

Microbiology of solar salt ponds

Science.gov (United States)

Javor, B.

1985-01-01

Solar salt ponds are shallow ponds of brines that range in salinity from that of normal seawater (3.4 percent) through NaCl saturation. Some salterns evaporate brines to the potash stage of concentration (bitterns). All the brines (except the bitterns, which are devoid of life) harbor high concentrations of microorganisms. The high concentrations of microorganisms and their adaptation to life in the salt pond are discussed.

Aspects of the sedimentology of some uranium-bearing sandstones in the Beaufort West area, Cape Province

International Nuclear Information System (INIS)

Cole, D.I.

1980-01-01

The sedimentology of some uranium-bearing sandstones from the Beaufort Group in the Beaufort West area was studied by use of some 116 vertical profiles measured across and adjacent to 14 mineralized deposits. The vertical profiles consist of 91 field sections and 25 borehole logs. The sandstones are usually multistorey and alternate with a mudstone and/or siltstone succession. The vertical profiles basically consist of a succession of facies. Some 19 facies were recognised within the sandstones on the basis of texture and sedimentary structure. The facies transitions within the sandstone sequence were subjected to a one-step Markov chain analysis. The cumulative thickness of uranium mineralization for each sedimentary facies within the sandstone sequence was measured. Some 99 per cent of the total cumulative thickness occurs within the coarser-grained facies (grain sizes in excess of very fine), which suggests that permeability was an important control on the mineralization. The coarser-grained facies, which mostly represent lower point bar or channel bar deposits near the base of each storey, probably acted as suitable aquifers for the transport of uraniferous solutions. Irregularities in the base of each storey may have interrupted the flow of these solutions and allowed sufficient time for precipitation of the uranium. Carbonaceous debris is frequently associated with the mineralized deposits and most likely acted as an indirect reductant for this precipitation. Mineralization decreases upwards in the sandstone sequence and some 40 per cent of the total cumulative thickness is restricted to the initial storey. The horizontally bedded facies contain a high proportion of the total cumulative thickness of mineralization (45 per cent) and this again may be related to a more abundant content of carbonaceous debris

The effect of grain size and cement content on index properties of weakly solidified artificial sandstones

Science.gov (United States)

Atapour, Hadi; Mortazavi, Ali

2018-04-01

The effects of textural characteristics, especially grain size, on index properties of weakly solidified artificial sandstones are studied. For this purpose, a relatively large number of laboratory tests were carried out on artificial sandstones that were produced in the laboratory. The prepared samples represent fifteen sandstone types consisting of five different median grain sizes and three different cement contents. Indices rock properties including effective porosity, bulk density, point load strength index, and Schmidt hammer values (SHVs) were determined. Experimental results showed that the grain size has significant effects on index properties of weakly solidified sandstones. The porosity of samples is inversely related to the grain size and decreases linearly as grain size increases. While a direct relationship was observed between grain size and dry bulk density, as bulk density increased with increasing median grain size. Furthermore, it was observed that the point load strength index and SHV of samples increased as a result of grain size increase. These observations are indirectly related to the porosity decrease as a function of median grain size.

Aquifer prospect and vulnerability of Upper Maastrichtian sandstones: Case of Ajali and Nsukka formations in the Northern Enugu Province, southeastern Nigeria

Science.gov (United States)

Ukpai, Stephen N.; Ezeh, Hilary N.; Igwe, James O.

2017-11-01

Two typical aquifer systems, namely, regional aquifer and local Perched aquifer have been delineated in the study area. The regional aquifer was identified at about 100 m depth around lowland areas, although prone to polluting effects from farming activities, erosion and weathering processes. This study investigated extents of groundwater pollution and permeability of the aquifers from water sample and grain size analyses. Results show porosity ranging from 49 to 50% and hydraulic conductivities as follows: 7.0 m/day for the sandstone of Nsukka Formation, 34.6 m/day for the outcrop of Ajali sandstone and 10.4 m/day for the sandstone at saturated subsurface zone with transmissivity of about 572 m2/day. The results signify that the regional aquifer is recharged by substantial rate of infiltrations vis-a-vis surface outcrops, and is therefore vulnerable to infiltration of pollution plumes. The groundwater is mainly acidic at pH ranging from 5.05 to 7.41 with a mean value of about 6.48, hence the pollution from dissolved iron in many places. Three main water types were identified, namely, Ca-Mg-HCO3, Ca-HCO3-Cl2 and Mg-Na-HCO3-SO4-Cl2 facies, all signifying dominance of groundwater species arising from precipitation recharge. This has resulted in the influences of surface effluents from run off as indicated by nitrate pollution in some areas. Thus, active hydrologic cycle controls the chemical facies in the water resources of the region, and with its hydraulic influence on the landscape, the quality status of groundwater, as well as the growth of agricultural products have been impaired.

The sedimentology of uranium-bearing sandstones on the farm Kaffersfontein 328, Beaufort West area

International Nuclear Information System (INIS)

Cole, D.I.

1979-10-01

The sedimentology of uranium-bearing sandstones on the farm Kaffersfontein 328 was studied by use of 23 vertical profiles measured across and adjacent to 3 mineralised deposits. The profiles consist of 18 field sections and 5 borehole logs. The vertical profiles basically consist of a succession of sedimentary facies. A total of 18 facies were recognised within the fluvial sandstone sequence according to the criteria of grain-size and sedimentary structures. Transitions between the facies were subjected to a Markov chain analysis in order to delineate Markov-dependent transitions. Uranium mineralisation coincides with areas of thicker sandstone, usually where channel over-deepening has taken place. It always occurs above the base of a channel, which often marks the base of the fluvial sandstone sequence. Irregularities in the base of the channel probably caused interruptions to the flow of uraniferous solutions and allowed sufficient time for the precipitation of the uranium. Carbonaceous debris is always associated with the mineralisation and most likely acted as an indirect reductant for the precipitation of uranium from solution. The direct reductant was most probably H 2 S produced by anaerobic bacteria acting on the carbonaceous debris. The mineralisation is confined to the coarser-grained sedimentary facies, which suggests that permeability was an important control on the mineralisation. These facies probably acted as suitable aquifers for the transport of uraniferous solutions. Horizontally bedded sandstone facies comprises 41 per cent of the total cumulative thickness of mineralisation. This facies represents a higher stream power and may consequently contain more carbonaceous material derived from plants, which were eroded from upstream areas. The nature of the bedding may also have provided a more effective permeability zone for the transport of uraniferous solutions prior to precipitation of the uranium

Dehydration of ethanol with salt extractive distillation-a comparative analysis between processes with salt recovery

Energy Technology Data Exchange (ETDEWEB)

Ligero, E.L.; Ravagnani, T.M.K. [Departamento de Engenharia de Sistemas Qumicos, Faculdade de Engenharia Qumica, Universidade Estadual de Campinas, Campinas, Sao Paulo (Brazil)

2003-07-01

Anhydrous ethanol can be obtained from a dilute aqueous solution of ethanol via extractive distillation with potassium acetate. Two process flowsheets with salt recovery were proposed. In the first, dilute ethanol is directly fed to a salt extractive distillation column and, after that, the salt is recovered in a multiple effect evaporator followed by a spray dryer. In the second, the concentrated ethanol from conventional distillation is fed to a salt extractive distillation column. In this case, salt is recovered in a single spray dryer. In both processes the recovered salt is recycled to be used in the extractive distillation column. Every component of each process was rigorously modeled and its behavior was simulated for a wide range of operating conditions. A global simulation was then carried out. The results show that the second process is more interesting in terms of energy consumption than the first. Furthermore, it would be easier to implement changes on existing benzene extractive anhydrous ethanol plants to convert them to more ecologically attractive concentrated ethanol feed processes. (author)

Remote detection of fluid-related diagenetic mineralogical variations in the Wingate Sandstone at different spatial and spectral resolutions

Science.gov (United States)

Okyay, Unal; Khan, Shuhab D.

2016-02-01

Well-exposed eolian units of the Jurassic system on the Colorado Plateau including the Wingate Sandstone, show prominent color variations throughout southeastern Utah due to diagenetic changes that include precipitation and/or removal of iron oxide, clay, and carbonate cement. Spatially variable characteristic diagenetic changes suggest fluid-rock interactions through the sandstone. Distinctive spectral signatures of diagenetic minerals can be used to map diagenetic mineral variability and possibly fluid-flow pathways. The main objective of this work was to identify characteristic diagenetic minerals, and map their spatial variability from regional to outcrop scale in Wingate Sandstone exposures of Lisbon Valley, Utah. Laboratory reflectance spectroscopy analysis of the samples facilitated identification of diagnostic spectral characteristics of the common diagenetic minerals and their relative abundances between altered and unaltered Wingate Sandstone. Comparison of reflectance spectroscopy with satellite, airborne, and ground-based imaging spectroscopy data provided a method for mapping and evaluating spatial variations of diagenetic minerals. The Feature-oriented Principal Component Selection method was used on Advanced Spaceborne Thermal Emission and Reflection Radiometer data so as to map common mineral groups throughout the broader Wingate Sandstone exposure in the area. The Minimum Noise Fraction and Spectral Angle Mapper methods were applied on airborne HyMap and ground-based hyperspectral imaging data to identify and map mineralogical changes. The satellite and airborne data showed that out of 25.55 km2 total exposure of Wingate Sandstone in Lisbon Valley, unaltered sandstone cover 12.55 km2, and altered sandstone cover 8.90 km2 in the northwest flank and 5.09 km2 in the southern flank of the anticline. The ground-based hyperspectral data demonstrated the ability to identify and map mineral assemblages with two-dimensional lateral continuity on near

Application of base-level cycles to sandstone-type uranium deposit: taking Dongsheng uranium deposits as an example

International Nuclear Information System (INIS)

Yang Renchao; Han Zuozhen; Fan Aiping; Chang Xiangchun

2006-01-01

High-resolution sequence stratigraphy taking base-level cycles as interface of reference was developed rapidly in recent years. Its greatest predominance lies in that it can be applied to multi-controled continental sedimentary basins and can effectively improve accuracy and distinguishability of sequence stratigraphy analysis. Principles of base-level cycles can also be applied to the research and practice of the exploration and exploitation of sandstone-type uranium deposits as they control the spatial distribution, porosity, the permeability and the sealing ability of sandstone and mudstone, and stacking patterns of strata configuration. Taking Dongsheng uranium deposits as an example, the application of base-level cycles to exploration and exploitation of sandstone uranium deposits was analyzed. It is suggested that favorable strata framework of sandstone and mudstone was developed very well in the fluctuation of base-level cycles. Sand bodies were provided with good connectedness, coarse granularity, high debris content, low matrix content and good porosity-permeability becoming the most important uranium hosted strata. (authors)

Water-borne radon and hydrogeochemical based uranium exploration in Rajamundry sandstone, W. Godavari district, Andhra Pradesh

International Nuclear Information System (INIS)

Jeyagopal, A.V.; Rajaraman, H.S.; Som, Anjan

2010-01-01

The lithology and sedimentary structures of the Rajamundry Formation of the Mio-Pliocene age covering an area of 1100 sq.km. indicate that it may be a typical valley fill sediment. It is about 600 m thick comprising sandstone and clay with lignite as the main lithounits. It is continental in onshore and marine in the offshore and is in contact with Gondwana sediments and Rajamundry traps. Tertiary sandstones are important hosts for uranium mineralisation. The reducing gas (Methane or other volatile hydrocarbon) moving to uraniferous oxidising water has precipitated uranium in the sediments in South Texas and Northwest Colorado, USA: (a) along faults, (b) above petroliferous aquifers, (c) vertically above hydrocarbon accumulations and (d) oil-water interface at hydrocarbon accumulations i.e., at the points of introduction of reducent into oxidising ground waters. In this context, Rajamundry sandstone lying above the natural gas and petroleum bearing Krishna Godavari basin with faults is an important geological setting for uranium mineralisation. The exploration strategies of hydrogeochemical survey and water-borne Radon (Rn) surveys were selected in this soil-covered area. Hydrogeochemical survey carried out in the Rajamundry sandstone has brought out four hydro-uranium anomalous zones with water samples (10-45ppb) falling around Kadiyadda, Madhavaram, Erramalla and Chinna Malapalle areas of West Godavari district, Andhra Pradesh. The zones vary from 9 to 24 sq km area. Water-borne Radon was utilized as a tool for exploration of uranium in this soil covered terrain. Rn contours cluster around two zones around Kadiyadda and SW of Gollagudem wherein the Rn value is >60 counts/50 sec/500 ml. These Rn anomalies fall within the above mentioned hydrouranium anomalous zones. Gamma-ray logging of private bore wells has recorded relatively higher radioactivity in Kommugudem, which also falls in the high hydrouranium - high waterborne radon zone. These data and

How Pore Filling Shale Affects Elastic Wave Velocities in Fully and Partially Saturated Sandstone: Characterization, Measurement, and Modelling

DEFF Research Database (Denmark)

Sørensen, Morten Kanne; Fabricius, Ida Lykke

2017-01-01

The elastic bulk modulus of a sandstone is affected by the fluid saturation as compression induces a pressure in the fluid thus increasing the bulk modulus of the sandstone as a whole. Assuming a uniform induced pressure and no interaction between the saturating fluid and the solid rock the fluid...... contribution to the elastic bulk modulus is quantified by Gassmann's equations. Experimental measurements of the fluid contribution to the elastic moduli are, however often much larger than predicted within the assumptions of Gassmann. Clay-rich low-mobility sandstones are especially prone to having elastic...... moduli highly sensitive to the fluid saturation. The presence of clay in a sandstone can affect two of the underlying assumptions to Gassmann's equations: decreased fluid mobility can cause pressure gradients and fluid-clay interactions are common. The elastic and petrophysical properties of clay...

Provenance of Late Ordovician Sandstones along the southeastern Appalachian Mountains: Implications for the Tectonic Model of the Taconic Orogeny

Science.gov (United States)

Guerrero, J. C.; Herrmann, A. D.; Haynes, J.

2017-12-01

A provenance study of sandstones along the southeastern Appalachian Mountains has been conducted in order to test the current volcanic arc-continent collision and foreland basin formation model of the Taconic Orogeny. Samples along the southeastern Appalachians were taken from sandstone sequences deposited between 460-450 Ma. Results from these sandstones show three dominate age ranges: 465-685 Ma, 980-1300 Ma, and 1300-1500 Ma. The 980-1300 Ma and 1300-1500 Ma ages are seen throughout the study area and are compatible with previously reported ages of the Grenville Orogeny and the Rhyolite-Granite Province. The northernmost samples have a small quantity of 465-685 Ma zircons which is attributed to an accretionary wedge that formed as a result of the continent-island arc collision and acted as a physical barrier keeping sediment from depositing within the basin. The younger age signal becomes stronger to the south, as samples in Georgia and Alabama show strong concentrations of 465-685 zircons. These ages are attributed to exotic terranes (Dalhonega Terrane and Carolina Terrane) that were accreted onto Laurentia during the Taconic Orogeny and/or a possible change in subduction direction leading to a back-arc basin model for the southern Appalachian Taconic Orogeny. The results from this provenance analysis support previous studies indicating that the model for the Taconic Orogeny is a combined A-type subduction for the north and a B-type subduction model for the southern part of the orogeny.

The sedimentology of uranium-bearing sandstones on the Waterval portion of the farm Brandewyns Gat 214, Beaufort West area

International Nuclear Information System (INIS)

Cole, D.I.

1980-08-01

The sedimentology of two uranium-bearing sandstones on the Waterval portion of the farm Brandewyns Gat 214 was studied by means of 36 vertical profiles measured across, through and adjacent to 4 mineralised deposits. The vertical profiles basically consist of a succession of sedimentary facies. A total of 19 facies was recognised within the fluvial sandstone sequence according to the criteria of grain-size and sedimentary structure. Transitions between the facies were subjected to a Markov chain analysis in order to delineate Markov-dependent transitions. Uranium mineralisation occurs mostly within the lower half of the fluvial sandstone sequence and is confined to the coarser-grained sedimentary facies. These facies probably acted as suitable aquifers for the transport of uraniferous solutions and permeability differences between the sandstone and the underlying mudstone and siltstone must have restricted these solutions to the lower half of the channel sandstone. The massive mudstone facies contains 13 per cent of the total cumulative thickness of mineralisation. This mineralisation probably originated from synchronously deposited tuffaceous material. Subsequent migration of uraniferous solutions may have concentrated the uranium

Comparative sound velocity measurements between porous rock and fully-dense material under crustal condition: The cases of Darley Dale sandstone and copper block

Science.gov (United States)

Kung, J.; Chien, Y. V.; Wu, W.; Dong, J.; Chang, Y.; Tsai, C.; Yang, M.; Wang, K.

2012-12-01

Previous studies showed that the voids and their geometry in the sedimentary rocks have great influence on the compressibility of rock, which reflects on its elastic velocities. Some models were developed to discuss the relations among velocity, porosity and void geometry. Therefore, the information of porosity, and void geometry and its distribution in rock is essential for understanding how the elastic properties of porous rocks affected by their poregeometry. In this study, we revisited a well-studied porous rock, Darley Dale sandstone, which has been studied by different groups with different purposes. Most of them are the deformation experiments. Different from previous studies, we measured the sound velocity of Darley dale sandstone under hydrostatic conditions. Also, we employed different techniques to investigate the pore geometry and porosity of Darley Dale sandstone to gain the insight of velocity changing behavior under the crustal conditions. Here, we measured a fully-dense copper block for a comparison. We performed X-ray CT scanning (XCT) to image the pore space of sandstone to construct the 3-D image of pore geometry, distribution and the pore size. The CT image data are allowed us to estimate the porosity of sandstone, too. One the other hand, the porosity of sample was measured using imbibitions method at ambient conditions and helium porosimeter at high pressure (up to 150 MPa). A set of specimens were cored from Darley Dale sandstone block. P and S wave velocities of specimens were measured at ambient conditions. We also performed high pressure velocity measurements on a selected rock specimen and a copper block up to 150 MPa under dry condition. Porosity of a set of rock specimens measured by imbibitions method was spanned from 6% to 15%, largely distributed within a range of 8%-11%. Compared the porosity obtained from three different techniques, imbibitions method, helium porosimeter and XCT, values from those measurements are in good agreement

Towards a typology of the mares sandstone of Mallorca Concept, characterization and stratigraphy

International Nuclear Information System (INIS)

Mas Gornals, C.

2017-01-01

The mares sandstone has traditionally been the most representative and characteristic building stone on the island of Mallorca, used practically exclusively as construction material for centuries, since the abandonment of stone-and-mortar walls, until its progressive disuse with the appearance of the re-enforced concrete, which finally eclipsed its use. Such emblematic buildings for the island, as Bellver Castle, the Cathedral, La Lonja or the old city walls of Palma, bear witness to this. In Mallorca, the mares sandstone is quarried in the open air or in subterranean galleries. Vernacular architecture has always used the most accessible appropriate materials, and in the case of the mares sandstone, its abundance, sufficient softness, which facilitates its extraction, Together with sufficient hardness to confer solidity and durability in constructions, converge. The lack of specific scientific and geological data published about the different types of mares in Mallorca, added to the recent resurgence of technical, applied and landscape interest in this stone, have made a revision of its definition, characterization and classification necessary. [es

Petrofabric changes in heated and irradiated salt from Project Salt Vault, Lyons, Kansas

International Nuclear Information System (INIS)

Holdoway, K.A.

1972-01-01

Rock salt was heated and irradiated in situ by implanted radioactive wastes during the Project Salt Vault experiment which was carried out at Lyons, Kansas, in the abandoned Carey Salt mine between 1965 and 1967. It was found that irradiation results in coloration of the salt, producing colors ranging from blue-black nearest the radiation source, to pale blue and purple farther from the source. Bleached areas are common in the radiation-colored salt, many representing trails produced by the migration of fluid inclusions towards the heat source. These visible trails are thought to have formed during the cooling down of the salt after the removal of the heaters and radiation sources. The distribution of primary structures in the salt suggests that little migration, if any, occurred during the course of the experiment. It is proposed that radiolysis of the brine within the inclusions may have led to the production of gases which impeded or prevented migration. Evidence of strain was observed in slip planes at 4 in. (10 cm) and between 5.5 and 10 in. (13.5 to 25.4 cm) from the array hole. Deformed bleached areas in the salt between the areas were slip planes are developed suggest that slight plastic deformation or flow may have occurred at 6 in. (15 cm) from the array hole. Differential thermal analysis shows that the maximum amount of stored energy also occurs at 6 in. (15 cm) from the array hole. This region may therefore represent the zone where the combined effect of stress and radiation was greatest

Architectural features of the Kayenta formation (Lower Jurassic), Colorado Plateau, USA: relationship to salt tectonics in the Paradox Basin

Science.gov (United States)

Bromley, Michael H.

1991-09-01

Fluvial sandstones of the Kayenta Formation were analyzed using architectural element analysis. Paleocurrent trends, the distribution of lacustrine facies and local silcrete development indicate that synsedimentary movement of evaporites in the underlying Paradox Basin created an unstable basin floor beneath the Kayenta fluvial system. This instability resulted in deflection of fluvial axes, local basin development and local areas of interrupted fluvial deposition with eolian dunes. Paleocurrent trends in the Kayenta system reflect periodic interruptions of southwesterly flow. Salt migrating laterally out of a rim syncline into an adjacent salt anticline resulted in a rim syncline of slight topographic relief. The resulting basin was probably rapidly filled, allowing the resumption of southwesterly flow. Differential movement of salt (incipient solution collapse features (?)) resulted in the formation of small centripetal basins in which playa mudstones formed. A laterally extensive resistant ledge underlies a horizontal surface, suggestive of deflation to the water table of an exposed section of valley fill. A channel scour in the top of one of these surfaces has margins much steeper ( > 60°) than the angle of repose for unconsolidated sand. Early cementation of the exposed floodplain could account for this resistance.

Trap architecture of the Early Cretaceous Sarir Sandstone in the eastern Sirt Basin, Libya

Energy Technology Data Exchange (ETDEWEB)

Gras, R. [Schlumberger GeoQuest, Cedex (France); Thusu, B. [Arabian Gulf Oil Company, Benghazi (Libyan Arab Jamahiriya)

1998-12-31

The Sarir Sandstone is the principal reservoir for oil accumulations in the eastern Sirt Basin in Libya. The main phase of the rifting in this area took place in the Late Jurassic-Early Cretaceous, during which time the Sarir Sandstone was deposited as a non-marine, intra-continental clastic syn-rift sequence. Although successfully explored from 1959 onwards, the prolific eastern Sirt Basin is in a relatively immature stage of exploration regarding wildcat drilling and 3D seismic data acquisition. The most recent phase of exploration, utilizing 3D seismic techniques, revealed a complex structural development. The trap geometries are often related to E-W trending, basement-controlled fault systems, oblique to the NNW-SSE Sirt Basin trend. The fault systems were active during the Sarir Sandstone deposition, giving rise to structural as well as combined structural-traps. An increased understanding of trap architecture has led to both re-evaluation of older fields and new discoveries. (author)

Study of lixiviant damage of a sandstone deposit during in-situ leaching of uranium

International Nuclear Information System (INIS)

Liao Wensheng; Wang Limin; Jiang Yan; Jiang Guoping; Tan Yahui

2014-01-01

The permeability of sandstone deposit is a key factor for economical uranium recovery during in-situ leaching uranium. Low permeability sandstone uranium deposits behave low push-pull capacity, and show formation damage in leaching operations. It is important to study formation damage of permeability, therefore, and to stabilize even improve the push-pull power of drillholes during in-situ leaching. In this paper, formation damage caused by lixiviants was investigated based on a low permeability sandstone uranium deposit. The resulted showed that, under the conditions of in-situ leaching, the salinity of leaching fluid has no harm to formation permeability, on the contrary, the increment of salinity of lixiviant during in-situ leaching improve the permeability of the deposit. The alkalinity, hydrogen peroxide and productivity of the lixiviant cause no significant formation damage. But the fine particles in the lixiviant shows formation damage significantly, and the quantity of the particles should be controlled during production. (authors)

Prediction of calcite Cement Distribution in Shallow Marine Sandstone Reservoirs using Seismic Data

Energy Technology Data Exchange (ETDEWEB)

Bakke, N.E.

1996-12-31

This doctoral thesis investigates how calcite cemented layers can be detected by reflection seismic data and how seismic data combined with other methods can be used to predict lateral variation in calcite cementation in shallow marine sandstone reservoirs. Focus is on the geophysical aspects. Sequence stratigraphy and stochastic modelling aspects are only covered superficially. Possible sources of calcite in shallow marine sandstone are grouped into internal and external sources depending on their location relative to the presently cemented rock. Well data and seismic data from the Troll Field in the Norwegian North Sea have been analysed. Tuning amplitudes from stacks of thin calcite cemented layers are analysed. Tuning effects are constructive or destructive interference of pulses resulting from two or more closely spaced reflectors. The zero-offset tuning amplitude is shown to depend on calcite content in the stack and vertical stack size. The relationship is found by regression analysis based on extensive seismic modelling. The results are used to predict calcite distribution in a synthetic and a real data example. It is found that describing calcite cemented beds in shallow marine sandstone reservoirs is not a deterministic problem. Hence seismic inversion and sequence stratigraphy interpretation of well data have been combined in a probabilistic approach to produce models of calcite cemented barriers constrained by a maximum amount of information. It is concluded that seismic data can provide valuable information on distribution of calcite cemented beds in reservoirs where the background sandstones are relatively homogeneous. 63 refs., 78 figs., 10 tabs.

Response of Tomato Genotypes to Induced Salt Stress | Agong ...

African Journals Online (AJOL)

Thirteen tomato (Lycopersicon esculentum L.) genotypes were subjected to salt treatment under hydroponics and their responses monitored in a set of two experiments with the objective of advancing them as potential salt tolerant tomato scion and/or rootstocks. Salt applications ranged from 0 to 2% NaCl, with the resultant ...

A method for automatic grain segmentation of multi-angle cross-polarized microscopic images of sandstone

Science.gov (United States)

Jiang, Feng; Gu, Qing; Hao, Huizhen; Li, Na; Wang, Bingqian; Hu, Xiumian

2018-06-01

Automatic grain segmentation of sandstone is to partition mineral grains into separate regions in the thin section, which is the first step for computer aided mineral identification and sandstone classification. The sandstone microscopic images contain a large number of mixed mineral grains where differences among adjacent grains, i.e., quartz, feldspar and lithic grains, are usually ambiguous, which make grain segmentation difficult. In this paper, we take advantage of multi-angle cross-polarized microscopic images and propose a method for grain segmentation with high accuracy. The method consists of two stages, in the first stage, we enhance the SLIC (Simple Linear Iterative Clustering) algorithm, named MSLIC, to make use of multi-angle images and segment the images as boundary adherent superpixels. In the second stage, we propose the region merging technique which combines the coarse merging and fine merging algorithms. The coarse merging merges the adjacent superpixels with less evident boundaries, and the fine merging merges the ambiguous superpixels using the spatial enhanced fuzzy clustering. Experiments are designed on 9 sets of multi-angle cross-polarized images taken from the three major types of sandstones. The results demonstrate both the effectiveness and potential of the proposed method, comparing to the available segmentation methods.

Carbon dioxide/brine wettability of porous sandstone versus solid quartz: An experimental and theoretical investigation.

Science.gov (United States)

Alnili, Firas; Al-Yaseri, Ahmed; Roshan, Hamid; Rahman, Taufiq; Verall, Michael; Lebedev, Maxim; Sarmadivaleh, Mohammad; Iglauer, Stefan; Barifcani, Ahmed

2018-08-15

Wettability plays an important role in underground geological storage of carbon dioxide because the fluid flow and distribution mechanism within porous media is controlled by this phenomenon. CO 2 pressure, temperature, brine composition, and mineral type have significant effects on wettability. Despite past research on this subject, the factors that control the wettability variation for CO 2 /water/minerals, particularly the effects of pores in the porous substrate on the contact angle at different pressures, temperatures, and salinities, as well as the physical processes involved are not fully understood. We measured the contact angle of deionised water and brine/CO 2 /porous sandstone samples at different pressures, temperatures, and salinities. Then, we compared the results with those of pure quartz. Finally, we developed a physical model to explain the observed phenomena. The measured contact angle of sandstone was systematically greater than that of pure quartz because of the pores present in sandstone. Moreover, the effect of pressure and temperature on the contact angle of sandstone was similar to that of pure quartz. The results showed that the contact angle increases with increase in temperature and pressure and decreases with increase in salinity. Copyright © 2018 Elsevier Inc. All rights reserved.

Concurrent nitrate and Fe(III) reduction during anaerobic biodegradation of phenols in a sandstone aquifer

DEFF Research Database (Denmark)

Broholm, Mette; Crouzet, C.; Arvin, Erik

2000-01-01

The biodegradation of phenols (similar to 5, 60, 600 mg 1(-1)) under anaerobic conditions (nitrate enriched and unamended) was studied in laboratory microcosms with sandstone material and groundwater from within an anaerobic ammonium plume in an aquifer, The aqueous phase was sampled and analyzed...... for phenols and selected redox sensitive parameters on a regular basis. An experiment with sandstone material from specific depth intervals from a vertical profile across the ammonium plume was also conducted. The miniature microcosms used in this experiment were sacrificed for sampling for phenols...... and selected redox sensitive parameters at the end of the experiment. The sandstone material was characterized with respect to oxidation and reduction potential and Fe(II) and Fe(III) speciation prior to use for all microcosms and at the end of the experiments for selected microcosms. The redox conditions...

Permanent Disposal of Nuclear Waste in Salt

Science.gov (United States)

Hansen, F. D.

2016-12-01

Salt formations hold promise for eternal removal of nuclear waste from our biosphere. Germany and the United States have ample salt formations for this purpose, ranging from flat-bedded formations to geologically mature dome structures. Both nations are revisiting nuclear waste disposal options, accompanied by extensive collaboration on applied salt repository research, design, and operation. Salt formations provide isolation while geotechnical barriers reestablish impermeability after waste is placed in the geology. Between excavation and closure, physical, mechanical, thermal, chemical, and hydrological processes ensue. Salt response over a range of stress and temperature has been characterized for decades. Research practices employ refined test techniques and controls, which improve parameter assessment for features of the constitutive models. Extraordinary computational capabilities require exacting understanding of laboratory measurements and objective interpretation of modeling results. A repository for heat-generative nuclear waste provides an engineering challenge beyond common experience. Long-term evolution of the underground setting is precluded from direct observation or measurement. Therefore, analogues and modeling predictions are necessary to establish enduring safety functions. A strong case for granular salt reconsolidation and a focused research agenda support salt repository concepts that include safety-by-design. Sandia National Laboratories is a multi-program laboratory managed and operated by Sandia Corporation, a wholly owned subsidiary of Lockheed Martin Corporation, for the U.S. Department of Energy's National Nuclear Security Administration under contract DE-AC04-94AL85000. Author: F. D. Hansen, Sandia National Laboratories

Microstructure parameters evaluation of Botucatu formation sandstone by X-ray microtomography

Energy Technology Data Exchange (ETDEWEB)

Fernandes, Jaquiel S.; Appoloni, Carlos R.; Marques, Leonardo C., E-mail: jaquielfernandes@yahoo.com.b, E-mail: appoloni@uel.b, E-mail: leocarma@yahoo.com.b [Universidade Estadual de Londrina (UEL), PR (Brazil). Dept. de Fisica. Lab. de Fisica Nuclear Aplicada; Fernandes, Celso P., E-mail: celso@lmpt.ufsc.b [Universidade Federal de Santa Catarina (UFSC), Florianopolis, SC (Brazil). Dept. de Engenharia Mecanica. Lab. de Meios Porosos e Propriedades TermoFisicas (LMPT)

2009-07-01

Microstructural parameters evaluation of reservoir rocks are very important to petroleum industry. This work presents total porosity and pore size distribution measurement of a silicified sandstone sample from the Botucatu formation, collected at municipal district of Faxinal, Parana, Brazil. Porosity and pores size distribution were determined using X-Ray microtomography and imaging techniques. Acquired images had 2.9 mum spatial resolution. 800 2-D images where reconstructed for the microstructure analysis. The determined average porosity was 6.1 +- 2.1 %. 95 % of the porous phase refers to pores with radius ranging from 2.9 to 167.4 mum, presenting the larger frequency (6 %) at 5.9 mum radius. The 3-D volume of the sample was reconstructed and compared with the 3-D model obtained through the autocorrelation functions from the 2-D images analysis. (author)

Salting-out-enhanced ionic liquid microextraction with a dual-role solvent for simultaneous determination of trace pollutants with a wide polarity range in aqueous samples.

Science.gov (United States)

Gao, Man; Qu, Jingang; Chen, Kai; Jin, Lide; Dahlgren, Randy Alan; Wang, Huili; Tan, Chengxia; Wang, Xuedong

2017-11-01

In real aquatic environments, many occupational pollutants with a wide range of polarities coexist at nanogram to milligram per liter levels. Most reported microextraction methods focus on extracting compounds with similar properties (e.g., polarity or specific functional groups). Herein, we developed a salting-out-enhanced ionic liquid microextraction based on a dual-role solvent (SILM-DS) for simultaneous detection of tetracycline, doxycycline, bisphenol A, triclosan, and methyltriclosan, with log K ow ranging from -1.32 to 5.40 in complex milk and environmental water matrices. The disperser in the ionic-liquid-based dispersive liquid-liquid microextraction was converted to the extraction solvent in the subsequent salting-out-assisted microextraction procedures, and thus a single solvent performed a dual role as both extractant and disperser in the SILM-DS process. Acetonitrile was selected as the dual-role solvent because of its strong affinity for both ionic liquids and water, as well as the extractant in the salting-out step. Optimized experimental conditions were 115 μL [C 8 MIM][PF 6 ] as extractor, 1200 μL acetonitrile as dual-role solvent, pH 2.0, 5.0 min ultrasound extraction time, 3.0 g Na 2 SO 4 , and 3.0 min vortex extraction time. Under optimized conditions, the recoveries of the five pollutants ranged from 74.5 to 106.9%, and their LODs were 0.12-0.75 μg kg -1 in milk samples and 0.11-0.79 μg L -1 in environmental waters. Experimental precision based on relative standard deviation was 1.4-6.4% for intraday and 2.3-6.5% for interday analyses. Compared with previous methods, the prominent advantages of the newly developed method are simultaneous determination of pollutants with a wide range of polarities and a substantially reduced workload for ordinary environmental monitoring and food tests. Therefore, the new method has great application potential for simultaneous determination of trace pollutants with strongly contrasting polarities in several

A method of quantitative prediction for sandstone type uranium deposit in Russia and its application

International Nuclear Information System (INIS)

Chang Shushuai; Jiang Minzhong; Li Xiaolu

2008-01-01

The paper presents the foundational principle of quantitative predication for sandstone type uranium deposits in Russia. Some key methods such as physical-mathematical model construction and deposits prediction are described. The method has been applied to deposits prediction in Dahongshan region of Chaoshui basin. It is concluded that the technique can fortify the method of quantitative predication for sandstone type uranium deposits, and it could be used as a new technique in China. (authors)

Evaluation of consolidating and water repellent treatments applied to the miocene sandstone used in Tunisian Heritage Monuments

Directory of Open Access Journals (Sweden)

Zoghlami, K.

2005-03-01

Full Text Available Summary The research reported in the present paper focused on the behaviour of the Miocene sandstone used to build the Roman aqueduct at Zaghouan-Carthage and other Tunisian Heritage monuments, after application of water repellent and consolidating treatments as a preliminary to restoration. Commercial consolidants and water repellents were used in the experiments: two ethyl silicate consolidants, Tegovakon (TV and Keim-Silex OH (KSOH; two (siloxane water repellents, Tegosivin THE 328 (THE and Tegosivin HLJ00 (THE; and a dual (consolidate and water repellent action substance, Keim- Silex H (KSH (silicate acid ester base with siloxane. A mixed treatment consisting of successive coats of TV and THL (TVHL was also applied. These organosilicate consolidants and water repellents acted on the porous structure of the sandstone, reducing total porosity and water vapour permeability. The water repellent THE was found to affect these properties least, with a pore size distribution that resembled the distribution in the untreated sandstone most closely. Water repellents diminish water absorption and consolidants increase mechanical strength. The TV-THL mix, which yielded results similar to those obtained with water repellents alone, was unable to prevent the substantial scaling that occurs during (RILEM salt crystallisation-induced artificial ageing. The best results were found with the dual action consolidant! water repellent product (KSH, which improved the mechanical properties while affording protection from the decay caused by salts in artificial ageing trials. This substance was found to reduce water vapour permeability, however

Esta investigación se centra en la evaluación del comportamiento de la arenisca miocénica utilizada en el acueducto de Zaghouan-Cartago y otros monumentos del Patrimonio Monumental de Túnez tras la aplicación de tratamientos de hidrofugación y de consolidación. Para los tratamientos se han seleccionado productos

Geology and potential of the formation of sandstone type uranium mineralization at Hatapang region, North Sumatera

International Nuclear Information System (INIS)

Ngadenin

2013-01-01

The Study based on geological setting of Hatapang region, North Sumatera, identified as a favourable area to the formation of sandstone type uranium mineralization. This characterized by the occurred of anomalous radioactivity, uranium contents of the upper cretaceous granite intrusions and radioactivity anomalous of tertiary sedimentary rocks deposited in terrestrial environments. The study is objective to find out the potential formation of sandstone type-uranium mineralization within tertiary sedimentary rocks based on data’s studies of geological, geochemical, mineralogy, radioactivity of rocks. Stratigraphy of Hatapang area of the oldest to youngest are quartz units (permian-carboniferous), sandstone units (upper Triassic), granite (upper cretaceous), conglomerate units (Lower –middle Miocene) and tuff units (Pleistocene). Hatapang’s granite is S type granite which is not only potential as source of radioactive minerals, particularly placer type monazite, but also potential as source rocks of sandstone type-uranium mineralization on lighter sedimentary rocks. Sedimentary rock of conglomerate units has potential as host rock, even though uranium did not accumulated in its rocks since the lack number of carbon as precipitant material and dissolved U"+"6 in water did not reduced into U"+"4 caused the uranium mineralization did not deposited. (author)

Hydrological modelling in sandstone rocks watershed

Science.gov (United States)

Ponížilová, Iva; Unucka, Jan

2015-04-01

The contribution is focused on the modelling of surface and subsurface runoff in the Ploučnice basin. The used rainfall-runoff model is HEC-HMS comprising of the method of SCS CN curves and a recession method. The geological subsurface consisting of sandstone is characterised by reduced surface runoff and, on the contrary, it contributes to subsurface runoff. The aim of this paper is comparison of the rate of influence of sandstone on reducing surface runoff. The recession method for subsurface runoff was used to determine the subsurface runoff. The HEC-HMS model allows semi- and fully distributed approaches to schematisation of the watershed and rainfall situations. To determine the volume of runoff the method of SCS CN curves is used, which results depend on hydrological conditions of the soils. The rainfall-runoff model assuming selection of so-called methods of event of the SCS-CN type is used to determine the hydrograph and peak flow rate based on simulation of surface runoff in precipitation exceeding the infiltration capacity of the soil. The recession method is used to solve the baseflow (subsurface) runoff. The method is based on the separation of hydrograph to direct runoff and subsurface or baseflow runoff. The study area for the simulation of runoff using the method of SCS CN curves to determine the hydrological transformation is the Ploučnice basin. The Ploučnice is a hydrologically significant river in the northern part of the Czech Republic, it is a right tributary of the Elbe river with a total basin area of 1.194 km2. The average value of CN curves for the Ploučnice basin is 72. The geological structure of the Ploučnice basin is predominantly formed by Mesozoic sandstone. Despite significant initial loss of rainfall the basin response to the causal rainfall was demonstrated by a rapid rise of the surface runoff from the watershed and reached culmination flow. Basically, only surface runoff occures in the catchment during the initial phase of

Selected trace and minor elements in sandstones from Paraguay

International Nuclear Information System (INIS)

Facetti-Masulli, J.F.; Gonzalez, E.; Kump, P.

2010-01-01

Selected trace and minor elements analyzed by XRF in sandstone samples were Rb-Sr-Zr-Nb-Ba-La-Ce-Nd as well as Ti-Mn-Fe with which they are often correlated. Refractory elements like REE are considered useful indicators of geochemical processes and, in this case, of provenance. Usually they maintain their original relationships and are transferred almost directly into sediments. The values here found, absolute and normalized, show correlations among the samples, allowing the establishment of their origin. Most of them in the spidergram patterns display positive spikes of Zr, and negative anomalies at Nb, Sr, Ti: differences in their height/depth could be in relation with the different Series or Formations. Strikingly, spidergrams of samples collected from the Patino Formation show marked negative anomalies interalia of Ba, as well as positive spikes of Nb and Zr, very similar to those found in magmatic specimens from Misiones, Carapegua-Acahay and Alto Paraguay Province and quite different from the other analyzed samples. In addition a remarkable presence of Precambrian signatures were found in the analyzed sandstones from the Paleozoic. (orig.)

Selected trace and minor elements in sandstones from Paraguay

Energy Technology Data Exchange (ETDEWEB)

Facetti-Masulli, J.F.; Gonzalez, E. [Hydroconsult SRL, Asuncion (Paraguay); Kump, P. [J. Stefan Inst., Ljubljana (Slovenia)

2010-07-01

Selected trace and minor elements analyzed by XRF in sandstone samples were Rb-Sr-Zr-Nb-Ba-La-Ce-Nd as well as Ti-Mn-Fe with which they are often correlated. Refractory elements like REE are considered useful indicators of geochemical processes and, in this case, of provenance. Usually they maintain their original relationships and are transferred almost directly into sediments. The values here found, absolute and normalized, show correlations among the samples, allowing the establishment of their origin. Most of them in the spidergram patterns display positive spikes of Zr, and negative anomalies at Nb, Sr, Ti: differences in their height/depth could be in relation with the different Series or Formations. Strikingly, spidergrams of samples collected from the Patino Formation show marked negative anomalies interalia of Ba, as well as positive spikes of Nb and Zr, very similar to those found in magmatic specimens from Misiones, Carapegua-Acahay and Alto Paraguay Province and quite different from the other analyzed samples. In addition a remarkable presence of Precambrian signatures were found in the analyzed sandstones from the Paleozoic. (orig.)

Digitization of uranium deposit information in basin. A new strategy of ISL sandstone-type uranium deposits exploration

International Nuclear Information System (INIS)

Tan Chenglong

2006-01-01

The discovered ISL sandstone-type uranium deposits in the entire world are mostly blind deposits, many of them occur in bleak desert, gobi desert, and semi-hilly land area. Exploration methods for these deposits mainly depend on great and systematic drilling. There are many large-medium size Meso-Cenozoic sedimentary basins in northern China, and over twenty of them are thick overburden basins which are mostly the virgin land for ISL sandstone-type uranium deposit. Due to the comprehensive national power, geological background, uranium exploration ability, great and systematic drilling is not favorable for prospecting ISL sandstone-type uranium deposit in China. According to the exploration and prospecting experiences for mineral ore bodies at home and abroad, uranium information mapping based on geochemical survey of the basins is a new strategy for ISL sandstone-type uranium deposits. It is an economic, practical, fast and effective method, and has been manifested by the performing information digitization for oil and gas resources, gold mineral resources in China and the mapping of uranium information for whole Europe continent. (authors)

The variability of reported salt levels in fast foods across six countries: opportunities for salt reduction.

Science.gov (United States)

Dunford, Elizabeth; Webster, Jacqueline; Woodward, Mark; Czernichow, Sebastien; Yuan, Wen Lun; Jenner, Katharine; Ni Mhurchu, Cliona; Jacobson, Michael; Campbell, Norm; Neal, Bruce

2012-06-12

Several fast food companies have made commitments to reduce the levels of salt in the foods they serve, but technical issues are often cited as a barrier to achieving substantial reductions. Our objective was to examine the reported salt levels for products offered by leading multinational fast food chains. Data on salt content for products served by six fast food chains operating in Australia, Canada, France, New Zealand, the United Kingdom and the United States were collected by survey in April 2010. Mean salt contents (and their ranges) were calculated and compared within and between countries and companies. We saw substantial variation in the mean salt content for different categories of products. For example, the salads we included in our survey contained 0.5 g of salt per 100 g, whereas the chicken products we included contained 1.6 g. We also saw variability between countries: chicken products from the UK contained 1.1 g of salt per 100 g, whereas chicken products from the US contained 1.8 g. Furthermore, the mean salt content of food categories varied between companies and between the same products in different countries (e.g., McDonald's Chicken McNuggets contain 0.6 g of salt per 100 g in the UK, but 1.6 g of salt per 100 g in the US). The salt content of fast foods varies substantially, not only by type of food, but by company and country in which the food is produced. Although the reasons for this variation are not clear, the marked differences in salt content of very similar products suggest that technical reasons are not a primary explanation. In the right regulatory environment, it is likely that fast food companies could substantially reduce the salt in their products, translating to large gains for population health.

Characterization of application of acu sandstone in ceramic mass; Caracterizacao da aplicacao do arenito acu na massa ceramica

Energy Technology Data Exchange (ETDEWEB)

Nobrega, L.F.P.M.; Souza, M.M.; Gomes, Y.S.; Fernandes, D.L., E-mail: junior.luiz09@hotmail.com [Universidade Federal do Rio Grande do Norte (DIAREN/UFRN), Natal, RN (Brazil). Laboratorio de Processamento Mineral e Residuo

2016-07-01

The sandstone is a sedimentary rock formed mainly by quartz grains. In Rio Grande do Norte, there is the Potiguar Basin with the Jandaira and Acu Formations. The latter consists of thick layers of whitish-colored sandstones. It stands out as a water storage facility in the state, but it is also used for building aggregates. This article aimed at the use of the sandstone of this formation in the ceramic mass for coating. Initially, the material was sampled. It went through the comminution process to achieve the required granulometry. After this, three formulations were made to incorporate this new material into the traditional ones. The methods were performed according to ISO 13816. After sintering at 1200 °C, the specimens were subjected to the physical tests. A positive result was obtained for the use of the Acu sandstone in low concentrations. It is clear, therefore, its use in ceramics for coating.

Provenance, diagenesis, tectonic setting and reservoir quality of the sandstones of the Kareem Formation, Gulf of Suez, Egypt

Science.gov (United States)

Zaid, Samir M.

2013-09-01

The Middle Miocene Kareem sandstones are important oil reservoirs in the southwestern part of the Gulf of Suez basin, Egypt. However, their diagenesis and provenance and their impact on reservoir quality, are virtually unknown. Samples from the Zeit Bay Oil Field, and the East Zeit Oil Field represent the Lower Kareem (Rahmi Member) and the Upper Kareem (Shagar Member), were studied using a combination of petrographic, mineralogical and geochemical techniques. The Lower Rahmi sandstones have an average framework composition of Q95F3.4R1.6, and 90% of the quartz grains are monocrystalline. By contrast, the Upper Shagar sandstones are only slightly less quartzose with an average framework composition of Q76F21R3 and 82% of the quartz grains are monocrystalline. The Kareem sandstones are mostly quartzarenite with subordinate subarkose and arkose. Petrographical and geochemical data of sandstones indicate that they were derived from granitic and metamorphic terrains as the main source rock with a subordinate quartzose recycled sedimentary rocks and deposited in a passive continental margin of a syn rift basin. The sandstones of the Kareem Formation show upward decrease in maturity. Petrographic study revealed that dolomite is the dominant cement and generally occurs as fine to medium rhombs pore occluding phase and locally as a grain replacive phase. Authigenic quartz occurs as small euhedral crystals, locally as large pyramidal crystals in the primary pores. Authigenic anhydrites typically occur as poikilotopic rhombs or elongate laths infilling pores but also as vein filling cement. The kaolinite is a by-product of feldspar leaching in the presence of acidic fluid produced during the maturation of organic matter in the adjacent Miocene rocks. Diagenetic features include compaction; dolomite, silica and anhydrite cementation with minor iron-oxide, illite, kaolinite and pyrite cements; dissolution of feldspars, rock fragments. Silica dissolution, grain replacement and

Unweaving the joints in Entrada Sandstone, Arches National Park, Utah, U.S.A.

Science.gov (United States)

Cruikshank, Kenneth M.; Aydin, Atilla

1995-03-01

On the southwest limb of Salt Valley Anticline, Arches National Park, Utah three sets of joints are developed in the Entrada Sandstone covering an area of about 6 km 2. Within the 20 m thick Moab Member, a single joint set is is found in three distinct areas, separated by a second set of joints at a 35° angle to the first set. Joint interaction features show that the second set is younger than the first. This illustrates that joints of a single set do not have to fill the entire area across which the stresses that formed the joints were acting. The underlying Slickrock Member contains a third set of joints, which is at an angle of 5°-35° to joints in the Moab Member. The Slickrock set nucleated from the lower edges of joints of all orientations in the overlying Moab Member. Thus, the fracture pattern evolved both horizontally, within the same unit, and vertically between units. The sequence of jointing is determined by establishing the relative ages of each joint set. Each joint orientation is best interpreted as representing a direction of maximum compression, ruling out the possibility that the joints are a conjugate set. The joints, and an earlier set of deformation bands, record a 95° counterclockwise rotation of the direction of maximum compression.

Diagenesis, provenance and depositional environments of the Bunter Sandstone Formation

DEFF Research Database (Denmark)

Olivarius, Mette; Weibel, Rikke; Friis, Henrik

The Bunter Sandstone Formation in the northern North German Basin has large geothermal potential with high porosity and permeability (generally >15% and >100 mD, respectively) and with pore fluid temperatures that are adequate for geothermal energy production (c. 55–60˚C). A combined investigation...

Petrographic and geochemical analysis of the Givetian-Frasnian sandstones in the Kuh-e-Tizi section, southeastern Central Iran

Science.gov (United States)

Hejazi, S. H.; Adabi, M. H.; Moussavi Harami, S. R.; Khosro Tehrani, K.

2009-04-01

The Givetian-Frasnian sandstones at the type section of Zarand Formation, sensu Wendt et al. (2002), unconformably overlie the Upper Cambrian Kuhbanan and underlie the Lower Carboniferous Hutk Formations respectively, in southeastern Central Iran. Petrographical data show that these sandstones are well-sorted and sub-angular to rounded grains quartzarenite. They are highly enriched in quartz, but poor in feldspar, lithic fragments and heavy minerals. Diagenetic features include physical and chemical compactions (straight, concavo-convex, sutured grain contacts and pressure solution of quartz grain), reduction of the pore space through rearrangements, and cementation (mostly silica, as quartz overgrowth). The provenance and tectonic setting of these sandstones have been interpreted using integrated petrographic and geochemical data. Petrographic analysis using standard methods (Basu et al., 1975; Dickinson et al., 1983) revealed that mono and poly-crystalline quartz grains have been derived from plutonic rocks of an interior cratonic setting. Elemental analysis and their ratios used for provenance studies (Th/Sc & La/Sc) which are similar to sediments derived from weathering of mostly felsic rocks (Amstrong-Altrin et al., 2004). Values representing chemical index of alteration (CIA) and the plagioclase index of alteration (PIA) range from 44.24 to 83.43, with an average of 69.96, and from 42.98 to 92.56, with an average of 75.8, respectively. However, most samples have values greater than 60, suggesting moderate to high weathering in the source area or during transportation prior to deposition. Major and trace element concentrations indicated a depositional setting in a passive continental margin, resembling those defined by Bhatia (1983), Bhatia & Crook (1986), Roser & Korsch (1986) and Kroonenberg (1994). Therefore, it can be concluded that these sandstones have been derived from stable cratonic setting. Refrences: Amstrong-Altrin, J.S., Lee, Y.I., Verma, S

Hydrogeology of the Pictured Cliffs Sandstone in the San Juan structural basin, New Mexico, Colorado, Arizona, and Utah

Science.gov (United States)

Dam, William L.; Kernodle, J.M.; Thorn, C.R.; Levings, G.W.; Craigg, S.D.

1990-01-01

This report is one in a series resulting from the U.S. Geological Survey's Regional Aquifer System Analysis (RASA) study of the San Juan structural basin that began in October 1984. The purposes of the study (Welder, 1986) are to: (1) Define and evaluate the aquifer system; (2) assess the effects of past, present, and potential ground-water use on aquifers and streams, and (3) determine the availability and quality of ground water. Previous reports in this series describe the hydrogeology of the Dakota Sandstone (Craigg and others, 1989), Gallup Sandstone (Kernodle and others, 1989), Morrison Formation (Dam and others, 1990), Point Lookout Sandstone (Craigg and others, 1990), Kirtland Shale and Fruitland Formation (Kernodle and others, 1990), Menefee Formation (Levings and others, 1990), Cliff House Sandstone (Thorn and others, 1990), and Ojo Alamo Sandstone (Thorn and others, 1990) in the San Juan structural basin. This report summarizes information on the geology and the occurrence and quality of water in the Pictured Cliffs Sandstone, one of the primary water-bearing units in the regional aquifer system. Data used in this report were collected during the RASA study or derived from existing records in the U.S. Geological Survey's computerized National Water Information System (NWIS) data base, the Petroleum Information Corporation's data base, and the Dwight's ENERGYDATA Inc. BRIN database. Although all data available for the Pictured Cliffs Sandstone were considered in formulating the discussions in the text, not all those data could be plotted on the illustrations. The San Juan structural basin in New Mexico, Colorado, Arizona, and Utah has an area of about 21,600 square miles (fig. 1). The structural basin is about 140 miles wide and about 200 miles long. The study area is that part of the structural basin that contains rocks of Triassic and younger age; therefore, the study area is less extensive than the structural basin. Triassic through Tertiary

Compatibility studies of potential molten-salt breeder reactor materials in molten fluoride salts

International Nuclear Information System (INIS)

Keiser, J.R.

1977-05-01

The molten fluoride salt compatibility studies carried out during the period 1974--76 in support of the Molten-Salt Reactor Program are summarized. Thermal-convection and forced-circulation loops were used to measure the corrosion rate of selected alloys. Results confirmed the relationship of time, initial chromium concentration, and mass loss developed by previous workers. The corrosion rates of Hastelloy N and Hastelloy N modified by the addition of 1--3 wt percent Nb were well within the acceptable range for use in an MSBR. 13 figures, 3 tables

Lack of inhibiting effect of oil emplacement on quartz cementation: Evidence from Cambrian reservoir sandstones, Paleozoic Baltic Basin

DEFF Research Database (Denmark)

Molenaar, Nicolaas; Cyziene, Jolanta; Sliaupa, Saulius

2008-01-01

Currently, the question of whether or not the presence of oil in sandstone inhibits quartz cementation and preserves porosity is still debated. Data from a number of Cambrian sandstone oil fields and dry fields have been studied to determine the effects of oil emplacement on quartz cementation. T...

Target salt 2025: a global overview of national programs to encourage the food industry to reduce salt in foods.

Science.gov (United States)

Webster, Jacqui; Trieu, Kathy; Dunford, Elizabeth; Hawkes, Corinna

2014-08-21

Reducing population salt intake has been identified as a priority intervention to reduce non-communicable diseases. Member States of the World Health Organization have agreed to a global target of a 30% reduction in salt intake by 2025. In countries where most salt consumed is from processed foods, programs to engage the food industry to reduce salt in products are being developed. This paper provides a comprehensive overview of national initiatives to encourage the food industry to reduce salt. A systematic review of the literature was supplemented by key informant questionnaires to inform categorization of the initiatives. Fifty nine food industry salt reduction programs were identified. Thirty eight countries had targets for salt levels in foods and nine countries had introduced legislation for some products. South Africa and Argentina have both introduced legislation limiting salt levels across a broad range of foods. Seventeen countries reported reductions in salt levels in foods-the majority in bread. While these trends represent progress, many countries have yet to initiate work in this area, others are at early stages of implementation and further monitoring is required to assess progress towards achieving the global target.

Molten salts and nuclear energy production

International Nuclear Information System (INIS)

Le Brun, Christian

2007-01-01

Molten salts (fluorides or chlorides) were considered near the beginning of research into nuclear energy production. This was initially due to their advantageous physical and chemical properties: good heat transfer capacity, radiation insensitivity, high boiling point, wide range solubility for actinides. In addition it was realised that molten salts could be used in numerous situations: high temperature heat transfer, core coolants with solid fuels, liquid fuel in a molten salt reactor, solvents for spent nuclear solid fuel in the case of pyro-reprocessing and coolant and tritium production in the case of fusion. Molten salt reactors, one of the six innovative concepts chosen by the Generation IV international forum, are particularly interesting for use as either waste incinerators or thorium cycle systems. As the neutron balance in the thorium cycle is very tight, the possibility to perform online extraction of some fission product poisons from the salt is very attractive. In this article the most important questions that must be addressed to demonstrate the feasibility of molten salt reactor will be reviewed

Characterization of the Lower Cambrian sandstone aquifer in the Swedish Baltic Sea area - assessment regarding its potential suitability for storage of CO2

Science.gov (United States)

Erlström, M.; Sivhed, U.

2012-04-01

range of 10-16% and permeabilities of 200-400 mD. Wire line logs indicate uniform physical properties of the member. The Faludden sandstone is in addition interpreted as a closed aquifer since it wedges out updip and is overlain by alum shale and several hundred metres of Ordovician-Silurian argillaceous limestone with bentonite clays acting as a significant seal. The regional distribution in combination with the satisfactory physical properties makes it an interesting candidate for CO2 storage. Investigations of the hydraulic properties of the aquifer as well as properties of the seal, in combination with numeric modelling have to be performed as to achieve a reliable assessment of the storage capacity. Research projects regarding this are now being launched by the Geological Survey of Sweden, Uppsala University, Lund University and the industry. Existing data regarding the Lower Cambrian sandstone in the Baltic Sea will also be included in the Nordic CCS GIS Atlas and data base within the recently launched Nordiccs-project.

REE characteristics and uranium metallogenesis of sandstone-type uranium deposits in northern Sichuan

International Nuclear Information System (INIS)

Zhu Xiyang; Wang Yunliang; Wang Zhichang; Zhang Chengjiang

2004-01-01

On the basis of the analysis of a large number of samples at sandstone-type uranium deposits in northern Sichuan, this paper analyses the REE composition of country rocks, ores, calcite-veins and uranium minerals, and systematically summarizes their REE geochemical characteristics, and discusses variation regularity of REE during depositional and diagenetic processes. By comparing these characteristics with those of typical hydrothermal volcanics-type and metamorphic rock type uranium deposits both at home and abroad, authors suggest that sandstone-type uranium deposits in northern Sichuan are characterized by REE geochemical features of hydrothermal reworking metallogenesis, the uranium mineralization has experienced two stages: the diagenetic preconcentration and the concentration of hydrothermal reworking

Wettability of Chalk and Argillaceous Sandstones Assessed from T1/T2 Ratio

DEFF Research Database (Denmark)

Katika, Konstantina; Saidian, M.; Fabricius, Ida Lykke

ratio can quantify the affinity between the rock and wetting pore fluid. The affinity is a measure directly linked to wettability. In order to investigate the T2-shortening, we performed T1-T2 NMR experiments on different samples of chalk, Berea sandstone, and chloritic greensand, saturated either...... with water, oil or oil/water at irreducible water saturation. The T1/T2 ratio obtained from T1-T2 maps reflects the T2-shortening. We compare the T1/T2 ratio for the same type of rock, saturated with different fluids. The chalk shows high affinity for water, Berea sandstone has no clear preference for oil...

Permeability model of tight reservoir sandstones combining core-plug and miniperm analysis of drillcore; longyearbyen co2lab, Svalbard

NARCIS (Netherlands)

Magnabosco, Cara; Braathen, Alvar; Ogata, Kei

2014-01-01

Permeability measurements in Mesozoic, low-permeability sandstone units within the strata cored in seven drillholes near Longyearbyen, Svalbard, have been analysed to assess the presence of aquifers and their potentials as reservoirs for the storage of carbon dioxide. These targeted sandstones are

Effect of Crushed Sandstone Sand on the Properties of High ...

African Journals Online (AJOL)

This paper presents results of the laboratory investigation on high performance concrete (HPC) using crushed sandstone sand as 20%, 40%, and 60% replacement of river sand together with superplastisizer and silica fume (SF). The fresh concrete properties such as slump, air content and fresh concrete density have been ...

Aeromagnetic gradient survey used in sandstone type uranium deposits prospecting

International Nuclear Information System (INIS)

Li Xiaolu; Chang Shushuai

2014-01-01

The principle, advantage and data processing of aeromagnetic gradient survey approach is introduced in this paper which was used in sandstone type uranium deposits prospecting to study the shallow surface faults, uranium ore-forming environment and depth of magnetic body, which proved to be a good results. (authors)

Impulse radar scanning of intact salt at the Avery Island Mine

International Nuclear Information System (INIS)

Cook, C.W.

1980-05-01

A series of experiments was run in the Avery Island Mine to evaluate the capability of an impulse radar to locate anomalies and simulated waste targets in intact dome salt. Voids in salt were difficult to detect. On the positive side, metal targets and simulated waste (glass) were easily located in intact salt. Radar scanning at ranges of greater than 25 meters and short-range resolution of target positions to within a few centimeters were achieved

Factors controlling localization of uranium deposits in the Dakota Sandstone, Gallup and Ambrosia Lake mining districts, McKinley County, New Mexico

Science.gov (United States)

Pierson, Charles Thomas; Green, Morris W.

1977-01-01

Geologic studies were made at all of the uranium mines and prospects in the Dakota Sandstone of Early(?) and Late Cretaceous age in the Gallup mining district, McKinley County, New Mexico. Dakota mines in the adjacent Ambrosia Lake mining district were visited briefly for comparative purposes. Mines in the eastern part of the Gallup district, and in the Ambrosia Lake district, are on the Chaco slope of the southern San Juan Basin in strata which dip gently northward toward the central part of the basin. Mines in the western part of the Gallup district are along the Gallup hogback (Nutria monocline) in strata which dip steeply westward into the Gallup sag. Geologic factors which controlled formation of the uranium deposits in the Dakota Sandstone are: (1) a source of uranium, believed to be uranium deposits of the underlying Morrison Formation of Late Jurassic age; (2) the accessibility to the Dakota of uranium-bearing solutions from the Morrison; (3) the presence in the Dakota of permeable sandstone beds overlain by impermeable carbonaceous shale beds; and (4) the occurrence within the permeable Dakota sandstone beds of carbonaceous reducing material as bedding-plane laminae, or as pockets of carbonaceous trash. Most of the Dakota uranium deposits are found in the lower part of the formation in marginal-marine distributary-channel sandstones which were deposited in the backshore environment. However, the Hogback no. 4 (Hyde) Mine (Gallup district) occurs in sandy paludal shale of the backshore environment, and another deposit, the Silver Spur (Ambrosia Lake district), is found in what is interpreted to be a massive beach or barrier-bar sandstone of the foreshore environment in the upper part of the Dakota. The sedimentary depositional environment most favorable for the accumulation of uranium is that of backshore areas lateral to main distributary channels, where levee, splay, and some distributary-channel sandstones intertongue with gray carbonaceous shales and

The effects of tree establishment on water and salt dynamics in naturally salt-affected grasslands.

Science.gov (United States)

Nosetto, Marcelo D; Jobbágy, Esteban G; Tóth, Tibor; Di Bella, Carlos M

2007-07-01

Plants, by influencing water fluxes across the ecosystem-vadose zone-aquifer continuum, can leave an imprint on salt accumulation and distribution patterns. We explored how the conversion of native grasslands to oak plantations affected the abundance and distribution of salts on soils and groundwater through changes in the water balance in naturally salt-affected landscapes of Hortobagy (Hungary), a region where artificial drainage performed approximately 150 years ago lowered the water table (from -2 to -5 m) decoupling it from the surface ecosystem. Paired soil sampling and detailed soil conductivity transects revealed consistently different salt distribution patterns between grasslands and plantations, with shallow salinity losses and deep salinity gains accompanying tree establishment. Salts accumulated in the upper soil layers during pre-drainage times have remained in drained grasslands but have been flushed away under tree plantations (65 and 83% loss of chloride and sodium, respectively, in the 0 to -0.5 m depth range) as a result of a five- to 25-fold increase in infiltration rates detected under plantations. At greater depth, closer to the current water table level, the salt balance was reversed, with tree plantations gaining 2.5 kg sodium chloride m(-2) down to 6 m depth, resulting from groundwater uptake and salt exclusion by tree roots in the capillary fringe. Diurnal water table fluctuations, detected in a plantation stand but not in the neighbouring grasslands, together with salt mass balances suggest that trees consumed approximately 380 mm groundwater per year, re-establishing the discharge regime and leading to higher salt accumulation rates than those interrupted by regional drainage practices more than a century ago. The strong influences of vegetation changes on water dynamics can have cascading consequences on salt accumulation and distribution, and a broad ecohydrological perspective that explicitly considers vegetation-groundwater links is

Modal analysis and geochemistry of two sandstones of the Bhander ...

Indian Academy of Sciences (India)

and tectonic setting interpretations are based on modal analysis and whole rock geochemistry. The average ... that major part of the sediments were derived from the granitic source area. The sandstone ...... The geochemical gap shown by trace and rare ... of the Council of Scientific and Industrial Research,. New Delhi, in ...

Provenance of sandstone on the western flank of Anambra Basin ...

African Journals Online (AJOL)

Petrographic and heavy mineral studies were carried out on clastic deposits that crop out in Ikpeshi, Auchi and Fugar localities in order to determine the provenance of the ... The heavy mineral suites and the petrographic signatures of the sandstones suggest derivation mainly from acid igneous rocks, gneisses and older ...

Quantifying drag on wellbore casings in moving salt sheets

Science.gov (United States)

Weijermars, R.; Jackson, M. P. A.; Dooley, T. P.

2014-08-01

Frontier hydrocarbon development projects in the deepwater slopes of the Gulf of Mexico Basin, Santos Basin and Lower Congo Basin all require wells to cross ductile layers of autochthonous or allochthonous salt moving at peak rates of 100 mm yr-1. The Couette-Poiseuille number is introduced here to help pinpoint the depth of shear stress reversal in such salt layers. For any well-planned through salt, the probable range of creep forces of moving salt needs to be taken into account when designing safety margins and load-factor tolerance of the well casing. Drag forces increase with wellbore diameter, but more significantly with effective viscosity and speed of the creeping salt layer. The potential drag forces on cased wellbores in moving salt sheets are estimated analytically using a range of salt viscosities (1015-1019 Pa s) and creep rates (0-10 mm yr-1). Drag on perfectly rigid casing of infinite strength may reach up to 13 Giga Newton per meter wellbore length in salt having a viscosity of 1019 Pa s. Well designers may delay stress accumulations due to salt drag when flexible casing accommodates some of the early displacement and strain. However, all creeping salt could displace, fracture and disconnect well casing, eventually. The shear strength of typical heavy duty well casing (about 1000 MPa) can be reached due to drag by moving salt. Internal flow of salt will then fracture the casing near salt entry and exit points, but the structural damage is likely to remain unnoticed early in the well-life when the horizontal shift of the wellbore is still negligibly small (at less than 1 cm yr-1). Disruption of casing and production flow lines within the anticipated service lifetime of a well remains a significant risk factor within distinct zones of low-viscosity salt which may reach ultrafast creep rates of 100 mm yr-1.

Morphology of channels and channel-sand bodies in the Glauconitic sandstone member (Upper Mannville), Little Bow area, Alberta

Energy Technology Data Exchange (ETDEWEB)

Hopkins, J.C.; Hermanson, S.W.; Lawton, D.C.

1982-12-01

Large channels in the Glauconitic sandstone member of southern Alberta have proved to be difficult exploration targets because of an irregular distribution of reservoir sands within the channels. In the Little Bow area, two channels are present in the lower part of the Glauconitic member and have cut into the underlying Calcareous member. The channels can be recognized where they truncate regional markers of the Calcareous member -- the Bantry shale and Ostracod limestone, and where channel-fill deposits exhibit uniform geophysical log characters, indicating sandstone- or mudstone-filled reaches. Sediments of the Glauconitic member adjacent to the channels comprise a series of splay sandstones and mudstones that prograded into interdistributary bays of the lower delta plain. The two channels associated with these deposits are interpreted as distributary channels. Sand bodies within the channels formed as lateral bars and are isolated by mudstones which mark the abandoned stream course. Geological exploration for these discontinuous channel sandstones is difficult, and high-resolutio seismic data integrated with sound geologic modelling are critical for successful prospect delineation.

Experimental study and theoretical interpretation of saturation effect on ultrasonic velocity in tight sandstones under different pressure conditions

Science.gov (United States)

Li, Dongqing; Wei, Jianxin; Di, Bangrang; Ding, Pinbo; Huang, Shiqi; Shuai, Da

2018-03-01

Understanding the influence of lithology, porosity, permeability, pore structure, fluid content and fluid distribution on the elastic wave properties of porous rocks is of great significance for seismic exploration. However, unlike conventional sandstones, the petrophysical characteristics of tight sandstones are more complex and less understood. To address this problem, we measured ultrasonic velocity in partially saturated tight sandstones under different effective pressures. A new model is proposed, combining the Mavko-Jizba-Gurevich relations and the White model. The proposed model can satisfactorily simulate and explain the saturation dependence and pressure dependence of velocity in tight sandstones. Under low effective pressure, the relationship of P-wave velocity to saturation is pre-dominantly attributed to local (pore scale) fluid flow and inhomogeneous pore-fluid distribution (large scale). At higher effective pressure, local fluid flow gradually decreases, and P-wave velocity gradually shifts from uniform saturation towards patchy saturation. We also find that shear modulus is more sensitive to saturation at low effective pressures. The new model includes wetting ratio, an adjustable parameter that is closely related to the relationship between shear modulus and saturation.

Community solar salt production in Goa, India.

Science.gov (United States)

Mani, Kabilan; Salgaonkar, Bhakti B; Das, Deepthi; Bragança, Judith M

2012-12-01

Traditional salt farming in Goa, India has been practised for the past 1,500 years by a few communities. Goa's riverine estuaries, easy access to sea water and favourable climatic conditions makes salt production attractive during summer. Salt produced through this natural evaporation process also played an important role in the economy of Goa even during the Portuguese rule as salt was the chief export commodity. In the past there were 36 villages involved in salt production, which is now reduced to 9. Low income, lack of skilled labour, competition from industrially produced salt, losses incurred on the yearly damage of embankments are the major reasons responsible for the reduction in the number of salt pans.Salt pans (Mithagar or Mithache agor) form a part of the reclaimed waterlogged khazan lands, which are also utilised for aquaculture, pisciculture and agriculture. Salt pans in Goa experience three phases namely, the ceased phase during monsoon period of June to October, preparatory phase from December to January, and salt harvesting phase, from February to June. After the monsoons, the salt pans are prepared manually for salt production. During high tide, an influx of sea water occurs, which enters the reservoir pans through sluice gates. The sea water after 1-2 days on attaining a salinity of approximately 5ºBé, is released into the evaporator pans and kept till it attains a salinity of 23 - 25ºBé. The brine is then released to crystallizer pans, where the salt crystallises out 25 - 27ºBé and is then harvested.Salt pans form a unique ecosystem where succession of different organisms with varying environmental conditions occurs. Organisms ranging from bacteria, archaea to fungi, algae, etc., are known to colonise salt pans and may influence the quality of salt produced.The aim of this review is to describe salt farming in Goa's history, importance of salt production as a community activity, traditional method of salt production and the biota

Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

Energy Technology Data Exchange (ETDEWEB)

Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

2003-11-15

The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

International Nuclear Information System (INIS)

Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

2003-01-01

The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

Application of anatectic mineralization to prospecting in-situ leachable sandstone type uranium ore in South Songliao Basin

International Nuclear Information System (INIS)

Zhao Zhonghua

2001-01-01

The deep ore-forming origin is a new theory for prospecting in-situ leachable sandstone type uranium. Tectonics, lithologic and geochemistry are basic forecasting criteria. Previous unconsolidated sand, source area and geochemical barrier are three essential conditions for forming uranium deposit. Metallogenic environment and prospective region are found. Tertiary system is prospective layer for prospecting in-situ leachable sandstone type uranium ore in south Songliao Basin

Effect of modified ethylsilicate consolidants on the mechanical properties of sandstone

Czech Academy of Sciences Publication Activity Database

Remzová, Monika; Šašek, Petr; Frankeová, Dita; Slížková, Zuzana; Rathouský, Jiří

2016-01-01

Roč. 112, JUN 2016 (2016), s. 674-681 ISSN 0950-0618 R&D Projects: GA MK(CZ) DF11P01OVV012 Keywords : sandstones * ethylsilicate consolidant * sol-gel process Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 3.169, year: 2016

Pore Fluid Effects on Shear Modulus for Sandstones with Soft Anisotropy

International Nuclear Information System (INIS)

Berryman, J G

2004-01-01

A general analysis of poroelasticity for vertical transverse isotropy (VTI) shows that four eigenvectors are pure shear modes with no coupling to the pore-fluidmechanics. The remaining two eigenvectors are linear combinations of pure compression and uniaxial shear, both of which are coupled to the fluid mechanics. After reducing the problem to a 2x2 system, the analysis shows in a relatively elementary fashion how a poroelastic system with isotropic solid elastic frame, but with anisotropy introduced through the poroelastic coefficients, interacts with the mechanics of the pore fluid and produces shear dependence on fluid properties in the overall mechanical system. The analysis shows, for example, that this effect is always present (though sometimes small in magnitude) in the systems studied, and can be quite large (up to a definite maximum increase of 20 per cent) in some rocks--including Spirit River sandstone and Schuler-Cotton Valley sandstone

Monitoring CO2 penetration and storage in the brine-saturated low permeable sandstone by the geophysical exploration technologies

Science.gov (United States)

Honda, H.; Mitani, Y.; Kitamura, K.; Ikemi, H.; Imasato, M.

2017-12-01

Carbon dioxide (CO2) capture and storage (CCS) plays a vital role in reducing greenhouse gas emissions. In the northern part of Kyushu region of Japan, complex geological structure (Coalfield) is existed near the CO2 emission source and has 1.06 Gt of CO2 storage capacity. The geological survey shows that these layers are formed by low permeable sandstone. It is necessary to monitor the CO2 behavior and clear the mechanisms of CO2 penetration and storage in the low permeable sandstone. In this study, measurements of complex electrical impedance (Z) and elastic wave velocity (P-wave velocity: Vp) were conducted during the supercritical CO2 injection experiment into the brine-saturated low permeable sandstone. The experiment conditions were as follows; Confining pressure: 20 MPa, Initial pore pressure: 10 MPa, 40 °, CO2 injection rate: 0.01 to 0.5 mL/min. Z was measured in the center of the specimen and Vp were measured at three different heights of the specimen at constant intervals. In addition, we measured the longitudinal and lateral strain at the center of the specimen, the pore pressure and CO2 injection volume (CO2 saturation). During the CO2 injection, the change of Z and Vp were confirmed. In the drainage terms, Vp decreased drastically once CO2 reached the measurement cross section.Vp showed the little change even if the flow rate increased (CO2 saturation increased). On the other hand, before the CO2 front reached, Z decreased with CO2-dissolved brine. After that, Z showed continuously increased as the CO2 saturation increased. From the multi-parameter (Hydraulic and Rock-physics parameters), we revealed the detail CO2 behavior in the specimen. In the brine-saturated low permeable sandstone, the slow penetration of CO2 was observed. However, once CO2 has passed, the penetration of CO2 became easy in even for brine-remainded low permeable sandstone. We conclude low permeable sandstone has not only structural storage capacity but also residual tapping

Trifolium isthmocarpum Brot, a salt-tolerant wild leguminous forage crop in salt-affected soils

Directory of Open Access Journals (Sweden)

Kawtar Bennani

2013-08-01

Full Text Available Plant scientists are investigating the potential of previously unexploited legume species where environmental and biological stresses constrain the use of more conventional forage crops or where these species are better suited to the needs of sustainable agriculture. Trifolium isthmocarpum Brot., Moroccan clover, occurs as a weed in different habitats in Morocco. It grows in moderately saline areas, where traditional forage legumes cannot be cultivated; however, it has not been widely studied despite its good palatability. The salt tolerance was studied between natural field conditions and glasshouse. The extensive field studies have recorded the species in many different habitats ranging from healthy agricultural lands to abandoned saline areas. The plants maintained high nodulation capacity (ranging between 60% and 97% and nitrogenase activities (average 2.04 µmol C2H4 plant-1 h-1 in different habitats. Shoot systems of plants collected from salt-affected soils exhibited higher concentrations of Na+ and Cl- than those collected from healthy soils. Greenhouse experiments showed that germination percentage and vigor value of the studied species was not significantly (P > 0.05 affected at 160 mM NaCl, and that 25% of the germination ability was maintained when growing on substrats containing 240 mM NaCl. The growth rate of seedlings was not signicantly affected by 160 mM NaCl but was reduced by 38% under 240 mM NaCl. Leaf succulence and indices of leaf water status did not differ among the salt treatments, whereas relative water content was reduced by only 8% and water content at saturation increased by about 12% at high salt concentrations in the growing medium. This study suggest recommending the cultivation of T. isthmocarpum in salt-affected soils, which are widespread and pose a problem for the farmers of Morocco and other countries in the world’s arid belt.

Laboratory investigation of crushed salt consolidation and fracture healing

International Nuclear Information System (INIS)

1987-01-01

A laboratory test program was conducted to investigate the consolidation behavior of crushed salt and fracture healing in natural and artificial salt. Crushed salt is proposed for use as backfill in a nuclear waste repository in salt. Artificial block salt is proposed for use in sealing a repository. Four consolidation tests were conducted in a hydrostatic pressure vessel at a maximum pressure of 2500 psi (17.2 MPa) and at room temperature. Three 1-month tests were conducted on salt obtained from the Waste Isolation Pilot Plant and one 2-month test was conducted on salt from Avery Island. Permeability was obtained using argon and either a steady-state or transient method. Initial porosities ranged from 0.26 to 0.36 and initial permeabilities from 2000 to 50,000 md. Final porosities and permeabilities ranged from 0.05 to 0.19 and from -5 md to 110 md, respectively. The lowest final porosity (0.05) and permeability ( -5 md) were obtained in a 1-month test in which 2.3% moisture was added to the salt at the beginning of the test. The consolidation rate was much more rapid than in any of the dry salt tests. The fracture healing program included 20 permeability tests conducted on fractured and unfractured samples. The tests were conducted in a Hoek cell at hydrostatic pressures up to 3000 psi (20.6 MPa) with durations up to 8 days. For the natural rock salt tested, permeability was strongly dependent on confining pressure and time. The effect of confining pressure was much weaker in the artificial salt. In most cases the combined effects of time and pressure were to reduce the permeability of fractured samples to the same order of magnitude (or less) as the permeability measured prior to fracturing

Reservoir Characterization of Bridgeport and Cypress Sandstones in Lawrence Field Illinois to Improve Petroleum Recovery by Alkaline-Surfactant-Polymer Flood

Energy Technology Data Exchange (ETDEWEB)

Seyler, Beverly; Grube, John; Huff, Bryan; Webb, Nathan; Damico, James; Blakley, Curt; Madhavan, Vineeth; Johanek, Philip; Frailey, Scott

2012-12-21

Within the Illinois Basin, most of the oilfields are mature and have been extensively waterflooded with water cuts that range up to 99% in many of the larger fields. In order to maximize production of significant remaining mobile oil from these fields, new recovery techniques need to be researched and applied. The purpose of this project was to conduct reservoir characterization studies supporting Alkaline-Surfactant-Polymer Floods in two distinct sandstone reservoirs in Lawrence Field, Lawrence County, Illinois. A project using alkaline-surfactantpolymer (ASP) has been established in the century old Lawrence Field in southeastern Illinois where original oil in place (OOIP) is estimated at over a billion barrels and 400 million barrels have been recovered leaving more than 600 million barrels as an EOR target. Radial core flood analysis using core from the field demonstrated recoveries greater than 20% of OOIP. While the lab results are likely optimistic to actual field performance, the ASP tests indicate that substantial reserves could be recovered even if the field results are 5 to 10% of OOIP. Reservoir characterization is a key factor in the success of any EOR application. Reservoirs within the Illinois Basin are frequently characterized as being highly compartmentalized resulting in multiple flow unit configurations. The research conducted on Lawrence Field focused on characteristics that define reservoir compartmentalization in order to delineate preferred target areas so that the chemical flood can be designed and implemented for the greatest recovery potential. Along with traditional facies mapping, core analyses and petrographic analyses, conceptual geological models were constructed and used to develop 3D geocellular models, a valuable tool for visualizing reservoir architecture and also a prerequisite for reservoir simulation modeling. Cores were described and potential permeability barriers were correlated using geophysical logs. Petrographic analyses

Salt disposition alternatives filtration at SRTC

International Nuclear Information System (INIS)

Walker, B. W.; Hobbs, D.

2000-01-01

Several of the prospective salt disposition alternative technologies require a monosodium titanate (MST) contact to remove strontium and actinides from inorganic salt solution feedstock. This feedstock also contains sludge solids from waste removal operations and may contain defoamers added in the evaporator systems. Filtration is required to remove the sludge and MST solids before sending the salt solution for further processing. This report describes testing performed using the Parallel Theological Experimental Filter (PREF). The PREF contains two single tube Mott sintered metal crossflow filters. For this test one filter was isolated so that the maximum velocities could be achieved. Previous studies showed slurries of MST and sludge in the presence of sodium tetraphenylborate (NaTPB) were filterable since the NaTPB slurry formed a filter cake which aided in removing the smaller MST and sludge particles. Some of the salt disposition alternative technologies do not use NaTPB raising the question of how effective crossflow filtration is with a feed stream containing only sludge and MST. Variables investigated included axial velocity, transmembrane pressure, defoamer effects, and solids concentration (MST and sludge). Details of the tests are outlined in the technical report WSRC-RP-98-O0691. Key conclusions from this study are: (1) Severe fouling of the Mott sintered metal filter did not occur with any of the solutions filtered. (2) The highest fluxes, in the range of .46 to 1.02 gpm/f 2 , were obtained when salt solution decanted from settled solids was fed to the filter. These fluxes would achieve 92 to 204 gpm filtrate production for the current ITP filters. The filtrate fluxes were close to the flux of 0.42 gpm/f 2 reported for In Tank Precipitation Salt Solution by Morrisey. (3) For the range of solids loading studied, the filter flux ranged from .04 to .17 gpm/f 2 which would result in a filtrate production rate of 9 to 31 gpm for the current HP filter. (4

Investigated Miscible CO2 Flooding for Enhancing Oil Recovery in Wettability Altered Chalk and Sandstone Rocks

Energy Technology Data Exchange (ETDEWEB)

Tabrizy, Vahid Alipour

2012-07-01

The thesis addresses oil recovery by miscible CO2 flooding from modified sandstone and chalk rocks. Calcite mineral surface is modified with stearic acid (SA) and asphaltene, and the silicate mineral surfaces are modified with N,N-dimethyldodecylamine (NN-DMDA) and asphaltene. The stability of adsorbed polar components in presence of SO4 2- and Mg2 + ions is also investigated. Recovery from sandstone cores is consistently lower than that from chalk cores saturated with the same oil and flooded with CO2 at all miscible flooding conditions. This may be due to the larger permeability contrasts in sandstone cores, which promote the fingering phenomenon. Miscible CO2 flooding for chalk and sandstone cores with distilled water, as initial water saturation, shows also lower oil recovery than cores saturated with different ions. At higher miscible flooding conditions, higher oil recovery is obtained. However, presence of light components (such as C1 or C3) in oil reduced the recovery. Oil recovery in presence of methane (C1) is lower than that in presence of methane and propane (C1/C3). A ternary diagram was constructed in order to understand the CO2 flooding mechanism(s) at the different flooding conditions and in presence of light components. The side effect of the flooding with CO2 is the probability for asphaltene deposition. An approach based on solubility parameter in the liquid, is used to assess the risk for asphaltene deposition during CO2 miscible flooding. The light components (C1/C3) and higher flooding conditions enhanced the risk for asphaltene instability. It is also shown higher amount of asphaltene deposition in chalk cores than that in sandstone cores at similar miscibility conditions.(au)

A Effect discussion of transient electromagnetic sounding technique in paleochannel-type sandstone-hosted uranium deposit

International Nuclear Information System (INIS)

Yang Jianchun; Fang Genxian; Yang Yaxin

2003-01-01

On the base of the application of transient electromagnetic technique of paleochannel-type sandstone-hosted uranium deposits in Tengchong region of Yunan Province, this paper analyses the detect example. It discusses the theory foundation of TEM, fieldwork means, data processing and interpret. By contrast with routine electricity farad, the transient electromagnetic technique have the special merit and favorable space resolve gender under conditions of intricacy terrain. This means can get good effect in detecting paleochannel-type sandstone-hosted uranium deposits space position. It is a good reference for other prospecting and exploration work

Origin of brackish groundwater in a sandstone aquifer on Bornholm, Denmark

DEFF Research Database (Denmark)

Jørgensen, Niels Oluf; Heinemeier, Jan

2008-01-01

A multi-isotope approach in combination with hydrochemical data and borehole logging is applied to identify the source of brackish groundwater in a borehole in the well field of Neksø Municipal Waterworks in Bornholm, Denmark. The aquifer lithology consists of fractured Lower Cambrian sandstones...

Thermophysical property characterization of aqueous amino acid salt solution containing serine

International Nuclear Information System (INIS)

Navarro, Shanille S.; Leron, Rhoda B.; Soriano, Allan N.; Li, Meng-Hui

2014-01-01

Highlights: • Thermophysical properties of aqueous potassium and sodium salt solutions of serine were studied. • Density, viscosity, refractive index and electrolytic conductivity of the solution were measured. • The concentrations of amino acid salt ranges from x 1 = 0.009 to 0.07. • The temperature range studied was (298.15 to 343.15) K. • The measured data were represented satisfactorily by using the applied correlations. - Abstract: Thermophysical property characterization of aqueous potassium and sodium salt solutions containing serine was conducted in this study; specifically the system’s density, refractive index, electrical conductivity, and viscosity. Measurements were obtained over a temperature range of (298.15 to 343.15) K and at normal atmospheric pressure. Composition range from x 1 = 0.009 to 0.07 for aqueous potassium and sodium salt solutions containing serine was used. The sensitivity of the system’s thermophysical properties on temperature and composition variation were discussed and correlated based on the equations proposed for room temperature ionic liquids. The density, viscosity, and refractive index measurements of the aqueous systems were found to decrease as the temperature increases at fixed concentration and the values increase as the salt concentration increases (water composition decreases) at fixed temperature. Whereas, a different trend was observed for the electrical conductivity data; at fixed concentration, the conductivity values increase as the temperature increases and at fixed temperature, its value generally increases as the salt concentration increases but only to a certain level (specific concentration) wherein the conductivity of the solution starts to decrease when the concentration of the salt is further increased. Calculation results show that the applied models were satisfactory in representing the measured properties in the aqueous amino acid salt solution containing serine

Estimation of uranium migration parameters in sandstone aquifers.

Science.gov (United States)

Malov, A I

2016-03-01

The chemical composition and isotopes of carbon and uranium were investigated in groundwater samples that were collected from 16 wells and 2 sources in the Northern Dvina Basin, Northwest Russia. Across the dataset, the temperatures in the groundwater ranged from 3.6 to 6.9 °C, the pH ranged from 7.6 to 9.0, the Eh ranged from -137 to +128 mV, the total dissolved solids (TDS) ranged from 209 to 22,000 mg L(-1), and the dissolved oxygen (DO) ranged from 0 to 9.9 ppm. The (14)C activity ranged from 0 to 69.96 ± 0.69 percent modern carbon (pmC). The uranium content in the groundwater ranged from 0.006 to 16 ppb, and the (234)U:(238)U activity ratio ranged from 1.35 ± 0.21 to 8.61 ± 1.35. The uranium concentration and (234)U:(238)U activity ratio increased from the recharge area to the redox barrier; behind the barrier, the uranium content is minimal. The results were systematized by creating a conceptual model of the Northern Dvina Basin's hydrogeological system. The use of uranium isotope dating in conjunction with radiocarbon dating allowed the determination of important water-rock interaction parameters, such as the dissolution rate:recoil loss factor ratio Rd:p (a(-1)) and the uranium retardation factor:recoil loss factor ratio R:p in the aquifer. The (14)C age of the water was estimated to be between modern and >35,000 years. The (234)U-(238)U age of the water was estimated to be between 260 and 582,000 years. The Rd:p ratio decreases with increasing groundwater residence time in the aquifer from n × 10(-5) to n × 10(-7) a(-1). This finding is observed because the TDS increases in that direction from 0.2 to 9 g L(-1), and accordingly, the mineral saturation indices increase. Relatively high values of R:p (200-1000) characterize aquifers in sandy-clayey sediments from the Late Pleistocene and the deepest parts of the Vendian strata. In samples from the sandstones of the upper part of the Vendian strata, the R:p value is ∼ 24, i.e., sorption processes are

Hydration patterns and salting effects in sodium chloride solution.

Science.gov (United States)

Li, Weifeng; Mu, Yuguang

2011-10-07

The salting effects of 2M sodium chloride electrolyte are studied based on a series of model solutes with properties ranging from hydrophobic to hydrophilic. Generally, hydrophobic solutes will be salted out and hydrophilic solutes will be salted in by NaCl solution. The solvation free energy changes are highly correlated with Kirkwood-Buff integrals. The underlying mechanism resorts to the preferential binding of ions and water to solutes. Our results demonstrate that the salting effect not only depends on the salt's position in Hofmeister series, but also on the solutes' specifics. Taking the hydration free energies of solutes and ions as independent variables, a schematic diagram of salting effects is suggested. The resolved multifaceted salting effects rely on the sensitive balance of the tripartite interaction among solutes, ions, and water. © 2011 American Institute of Physics

Hydrologic environment of the Silurian salt deposits in parts of Michigan, Ohio, and New York

Science.gov (United States)

Norris, Stanley E.

1978-01-01

The aggregate thickness of evaporites (salt, gypsum, and anhydrite) in the Silurian Salina sequence in Michigan exceeds 1200 feet in areas near the periphery of the Michigan basin, where the salt beds are less than 3000 feet below land surface. In northeast Ohio the aggregate thickness of salt beds is as much as 200 feet in places, and in western New York it is more than 500 feet, where th beds are less than 3000 feet deep. The salt-bearing rocks dip regionally on the order of 50 feet per mile; those in Michigan dip toward the center of the Michigan basin, and those in Ohio and New York, in the Appalachian basin, dip generally southward. The rocks in both basins thicken downdip. Minor folds and faults occur in the salt-bearing rocks in all three states. Some of this defrmation has been attenuated or absorbed bo the salt beds. Occuring near the middle of thick sedimentary sequences, the salt beds are bounded aboe and below by beds containing water having dissolved-solids concentrations several times that seawter. The brines occur commonly in discrete zones of high permeability at specific places in the stratigraphic sequence. In northeast Ohio two prominent brine zones are recognized by the driller, the Devonian Oriskany Sandstone, or 'first water' zone, above the Salina Formation, and the Newburg or 'second water' zone below the Salina. In each aquifer there is a vertical component of hydraulic head, but little brine probably moves through the salt beds because their permeability is extremely low. Also, ther is little evidence of dissolution of the salt in areas distant from the outcrop, suggesting that if brine does move through the salt, movement is at a slow enough rate so that, in combination with the saturated or near-saturated condition of the water, it precludes significant dissolution. Principal brine movement is probably in the permeable zones in the direction of the hydraulic gradient. Two areas in Michigan and one area each in Ohio and New York appear

Liking, salt taste perception and use of table salt when consuming reduced-salt chicken stews in light of South Africa's new salt regulations.

Science.gov (United States)

De Kock, H L; Zandstra, E H; Sayed, N; Wentzel-Viljoen, E

2016-01-01

This study investigated the impact of salt reduction on liking, salt taste perception, and use of table salt when consuming chicken stew in light of South Africa's new salt recommendations. In total, 432 South-African consumers (aged 35.2 ± 12.3 years) consumed a full portion of a chicken stew meal once at a central location. Four stock cube powders varying in salt content were used to prepare chicken stews: 1) no reduction - 2013 Na level; regular salt level as currently available on the South African market (24473 mg Na/100 g), 2) salt reduction smaller than 2016 level, i.e. 10%-reduced (22025 mg Na/100 g), 3) 2016 salt level, as per regulatory prescriptions (18000 mg Na/100 g), 4) 2019 salt level, as per regulatory prescriptions (13000 mg Na/100 g). Consumers were randomly allocated to consume one of the four meals. Liking, salt taste perception, and use of table salt and pepper were measured. Chicken stews prepared with reduced-salt stock powders were equally well-liked as chicken stews with the current salt level. Moreover, a gradual reduction of the salt in the chicken stews resulted in a reduced salt intake, up to an average of 19% for the total group compared to the benchmark 2013 Na level stew. However, 19% of consumers compensated by adding salt back to full compensation in some cases. More salt was added with increased reductions of salt in the meals, even to the point of full compensation. Further investigation into the impacts of nutrition communication and education about salt reduction on salt taste perception and use is needed. This research provides new consumer insights on salt use and emphasises the need for consumer-focused behaviour change approaches, in addition to reformulation of products. Copyright © 2015 Elsevier Ltd. All rights reserved.

Spectroscopic Characterization of Omeprazole and Its Salts

Directory of Open Access Journals (Sweden)

Tomislav Vrbanec

2017-01-01

Full Text Available During drug development, it is important to have a suitable crystalline form of the active pharmaceutical ingredient (API. Mostly, the basic options originate in the form of free base, acid, or salt. Substances that are stable only within a certain pH range are a challenge for the formulation. For the prazoles, which are known to be sensitive to degradation in an acid environment, the formulation is stabilized with alkaline additives or with the application of API formulated as basic salts. Therefore, preparation and characterization of basic salts are needed to monitor any possible salinization of free molecules. We synthesized salts of omeprazole from the group of alkali metals (Li, Na, and K and alkaline earth metals (Mg, Ca. The purpose of the presented work is to demonstrate the applicability of vibrational spectroscopy to discriminate between the OMP and OMP-salt molecules. For this reason, the physicochemical properties of 5 salts were probed using infrared and Raman spectroscopy, NMR, TG, DSC, and theoretical calculation of vibrational frequencies. We found out that vibrational spectroscopy serves as an applicable spectroscopic tool which enables an accurate, quick, and nondestructive way to determine the characteristic of OMP and its salts.

Development of High Throughput Salt Separation System with Integrated Liquid Salt Separation - Salt Distillation Assembly

Energy Technology Data Exchange (ETDEWEB)

Kwon, Sangwoon; Park, K. M.; Kim, J. G.; Jeong, J. H.; Lee, S. J.; Park, S. B.; Kim, S. S.

2013-01-15

The capacity of a salt distiller should be sufficiently large to reach the throughput of uranium electro-refining process. In this study, an assembly composing a liquid separation sieve and a distillation crucible was developed for the sequential operation of a liquid salt separation and a vacuum distillation in the same tower. The feasibility of the sequential salt separation was examined by the rotation test of the sieve-crucible assembly and sequential operation of a liquid salt separation and a vacuum distillation. The adhered salt in the uranium deposits was removed successfully. The salt content in the deposits was below 0.1 wt% after the sequential operation of the liquid salt separation - salt distillation. From the results of this study, it could be concluded that efficient salt separation can be realized by the sequential operation of liquid salt separation and vacuum distillation in one distillation tower since the operation procedures are simplified and no extra operation of cooling and reheating is necessary.

First salt making in Europe: an overview from Neolithic times

Directory of Open Access Journals (Sweden)

Olivier Weller

2015-12-01

Full Text Available This paper deals with the origin of salt production and discusses different approaches ranging from technology, ethnoarchaeology and paleoenvironmental studies to chemical analyses. Starting from the current research on the Neolithic exploitation of salt in Europe, we examine the types and nature of the salt resources (sea water, salt springs, soil or rock, the diversity of archaeological evidence of forms of salt working. We also scrutinize the types of production for these early forms of salt exploitation, with or without the use of crudely fired clay vessels (briquetage. Finally, we contextualise the socio-economic dimensions and highlight both the diversity of salt products and their characteristics, which go well beyond dietary roles.

Sea Salt vs. Table Salt: What's the Difference?

Science.gov (United States)

... and healthy eating What's the difference between sea salt and table salt? Answers from Katherine Zeratsky, R.D., L.D. The main differences between sea salt and table salt are in their taste, texture ...

Thermal study of sandstones from different Czech localities

Czech Academy of Sciences Publication Activity Database

Plevová, Eva; Vaculíková, Lenka; Kožušníková, Alena; Daněk, T.; Ritz, M.; Simha Martynková, G.

2011-01-01

Roč. 103, č. 3 (2011), s. 835-843 ISSN 1388-6150 R&D Projects: GA ČR GA105/08/1398; GA ČR GP105/07/P416 Grant - others:GA ČR(CZ) GP105/09/397 Institutional research plan: CEZ:AV0Z30860518 Keywords : thermomechanical and differential thermal analysis * optical microscopy * sandstones Subject RIV: CA - Inorganic Chemistry Impact factor: 1.604, year: 2011 http://www.springerlink.com/content/71n5427j2707g331/

The effectiveness of starting the developement of lenticular sandstone and siltstone

Energy Technology Data Exchange (ETDEWEB)

Oshitki, V M; Khmelevskiy, Y I; Kolesnkikova, S A; Musin, M M; Sukhanov, N A

1980-01-01

Studies the determination of the effectiveness of working reserves for several typical cases of implementing development of collector-sandstone and siltstonee lenses. Shows that Siltstones require the use of amore rapid development system: with a ratio of injection to working wells of at least 1:3.

Salt-specific effects in lysozyme solutions

Directory of Open Access Journals (Sweden)

T. Janc

2016-03-01

Full Text Available The effects of additions of low-molecular-mass salts on the properties of aqueous lysozyme solutions are examined by using the cloud-point temperature, T_{cloud}, measurements. Mixtures of protein, buffer, and simple salt in water are studied at pH=6.8 (phosphate buffer and pH=4.6 (acetate buffer. We show that an addition of buffer in the amount above I_{buffer} = 0.6 mol dm^{-3} does not affect the T_{cloud} values. However, by replacing a certain amount of the buffer electrolyte by another salt, keeping the total ionic strength constant, we can significantly change the cloud-point temperature. All the salts de-stabilize the solution and the magnitude of the effect depends on the nature of the salt. Experimental results are analyzed within the framework of the one-component model, which treats the protein-protein interaction as highly directional and of short-range. We use this approach to predict the second virial coefficients, and liquid-liquid phase diagrams under conditions, where T_{cloud} is determined experimentally.

Observation of vapor pressure enhancement of rare-earth metal-halide salts in the temperature range relevant to metal-halide lamps

Energy Technology Data Exchange (ETDEWEB)

Curry, J. J.; Henins, A.; Hardis, J. E. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Estupinan, E. G. [Osram Sylvania Inc., Beverly, Massachusetts 01915 (United States); Lapatovich, W. P. [Independent Consultant, 51 Pye Brook Lane, Boxford, Massachusetts 01921 (United States); Shastri, S. D. [Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States)

2012-02-20

Total vapor-phase densities of Dy in equilibrium with a DyI{sub 3}/InI condensate and Tm in equilibrium with a TmI{sub 3}/TlI condensate have been measured for temperatures between 900 K and 1400 K. The measurements show strong enhancements in rare-earth vapor densities compared to vapors in equilibrium with the pure rare-earth metal-halides. The measurements were made with x-ray induced fluorescence on the sector 1-ID beam line at the Advanced Photon Source. The temperature range and salt mixtures are relevant to the operation of metal-halide high-intensity discharge lamps.

Geological characteristics and prospecting potential of sandstone-type uranium deposits in the north margin of Qaidam basin

International Nuclear Information System (INIS)

Liu Lin; Song Xiansheng; Feng Wei

2012-01-01

The north margin of Qaidam Basin is composed with rift trough and Oulongbuluke landmass which is clamped by Qilian Mountain and Qaidam block Suture zone. The two activities provide a rich source of uranium for the basin area. The coal-bearing rocks as stratums of medium and lower Jurassic, is the main exploration target zones of sandstone-type uranium ore. Through geological survey and drilling, we think that the interlayer oxidation zone. being primary factors of sandstone-type uranium, can be divided into ancient type and modern type. The ancient interlayer oxidation zone type uranium deposit is the main prospecting types in the north margin of Qaidam Basin. Combined with analysis on geological conditions of sandstone-type uranium mineralization, we propose that eastern edge of Yuqia, southern edge of Lucao Mountain, Beidatan and northwest edge of Ulan depression are good prospects. (authors)

Hydrogeochemical and stream sediment sampling for uranium in the sandstone environment

International Nuclear Information System (INIS)

Wenrich, K.J.

1985-01-01

Sandstone terranes commonly host uranium occurrences in the western United States. In addition, because sedimentary terranes, particularly shales and immature, not well cemented sandstone, contribute more sediment and soluble material than do plutonic, volcanic, or metamorphic terranes they are an excellent regime for hydrogeochemical and stream-sediment prospecting. Because of higher conductivity, and hence higher uranium content, of waters draining such environments the sampling need not be as precise nor the analytical detection limit as low as in other terranes to yield a successful survey. Nevertheless, reasonable preparation and care of the samples is recommended: (1) The water samples should be filtered through 0.45 μm membranes and acidified to a pH of less than 1. (2) Because the adsorption of uranium by organic material is so significant it is recommended that the reasonable finest stream-sediment fraction, 4 , conductivity, etc.) are useful in the data reduction towards the elimination of false anomalies. (author)

Multi-scale nitrate transport in a sandstone aquifer system under intensive agriculture

Science.gov (United States)

Paradis, Daniel; Ballard, Jean-Marc; Lefebvre, René; Savard, Martine M.

2018-03-01

Nitrate transport in heterogeneous bedrock aquifers is influenced by mechanisms that operate at different spatial and temporal scales. To understand these mechanisms in a fractured sandstone aquifer with high porosity, a groundwater-flow and nitrate transport model—reproducing multiple hydraulic and chemical targets—was developed to explain the actual nitrate contamination observed in groundwater and surface water in a study area on Prince Edward Island, Canada. Simulations show that nitrate is leached to the aquifer year-round, with 61% coming from untransformed and transformed organic sources originating from fertilizers and manure. This nitrate reaches the more permeable shallow aquifer through fractures in weathered sandstone that represent only 1% of the total porosity (17%). Some of the nitrate reaches the underlying aquifer, which is less active in terms of groundwater flow, but most of it is drained to the main river. The river-water quality is controlled by the nitrate input from the shallow aquifer. Groundwater in the underlying aquifer, which has long residence times, is also largely influenced by the diffusion of nitrate in the porous sandstone matrix. Consequently, following a change of fertilizer application practices, water quality in domestic wells and the river would change rapidly due to the level of nitrate found in fractures, but a lag time of up to 20 years would be necessary to reach a steady level due to diffusion. This demonstrates the importance of understanding nitrate transport mechanisms when designing effective agricultural and water management plans to improve water quality.

Petrological features of selected components of the Cergowa sandstones (Outer Carpathians) recorded by scanning electron microscopy - preliminary study

Science.gov (United States)

Pszonka, Joanna

2017-11-01

The scanning electron microscope analysis of the Cergowa sandstones brings new data on their petrological features and chemical composition. Previous work in standard petrographic examination, e.g. polarising (PL) or cathodoluminescence (CL) microscopy, displayed limited information on grain surface topography and only assumptions to their geochemistry. Both identification and characterisation of minerals are fundamental in the progress of mining and minerals processing systems. Detrital grains of the Cergowa sandstones are bound by calcite and dolomitic cement and commonly corroded by diagenetic fluids, however, in varying degrees, which is illustrated here by feldspar, quartz and dolomite minerals. Dissolution processes of marginal parts of these mineral grains resulted in corrosion, which increased the contact surface between the grains and the cement. The difference in resistance to these processes was observed not only among distinct groups of minerals, but also within the group of feldspars: between K-feldspars and minerals of plagioclase. That combination resulted in exceptionally strong cementation of the Cergowa sandstones, which is expressed by their high hardness and resistance to abrasion, freezing, and thawing. Inherent parameters of sandstones are characterised by their petrographical properties.

Hydrophobization by Means of Nanotechnology on Greek Sandstones Used as Building Facades

Directory of Open Access Journals (Sweden)

Georgios Karagiannis

2013-01-01

Full Text Available Modern sustainable architecture indicates the use of local natural stones for building. Greek sandstones from Epirus (Demati, Greece, EN 12440 used as building facades meet aesthetic and have high mechanical properties, but the inevitable interaction between stone materials and natural or anthropogenic weathering factors controls the type, and extent of stone damages. In the present paper, samples of sandstone were treated with a conventional hydrophobic product and four solutions of the same product, enriched with nanosilica of different concentrations. The properties of the treated samples, such as porosity and pore size distribution, microstructure, static contact angle of a water droplet, and durability to deterioration cycles (freeze-thaw were recorded and conclusions were drawn. The research indicates the increased hydrophobic properties in nanosilica solutions but also the optimum content in nanoparticles that provides hydrophobicity without altering the properties of the stone.

Geology and recognition criteria for sandstone uranium deposits in mixed fluvial-shallow marine sedimentary sequences, South Texas. Final report

Energy Technology Data Exchange (ETDEWEB)

Adams, S.S.; Smith, R.B.

1981-01-01

Uranium deposits in the South Texas Uranium Region are classical roll-type deposits that formed at the margin of tongues of altered sandstone by the encroachment of oxidizing, uraniferous solutions into reduced aquifers containing pyrite and, in a few cases, carbonaceous plant material. Many of the uranium deposits in South Texas are dissimilar from the roll fronts of the Wyoming basins. The host sands for many of the deposits contain essentially no carbonaceous plant material, only abundant disseminated pyrite. Many of the deposits do not occur at the margin of altered (ferric oxide-bearing) sandstone tongues but rather occur entirely within reduced, pyurite-bearing sandstone. The abundance of pyrite within the sands probably reflects the introduction of H/sub 2/S up along faults from hydrocarbon accumulations at depth. Such introductions before ore formation prepared the sands for roll-front development, whereas post-ore introductions produced re-reduction of portions of the altered tongue, leaving the deposit suspended in reduced sandstone. Evidence from three deposits suggests that ore formation was not accompanied by the introduction of significant amounts of H/sub 2/S.

Geology and recognition criteria for sandstone uranium deposits in mixed fluvial-shallow marine sedimentary sequences, South Texas. Final report

International Nuclear Information System (INIS)

Adams, S.S.; Smith, R.B.

1981-01-01

Uranium deposits in the South Texas Uranium Region are classical roll-type deposits that formed at the margin of tongues of altered sandstone by the encroachment of oxidizing, uraniferous solutions into reduced aquifers containing pyrite and, in a few cases, carbonaceous plant material. Many of the uranium deposits in South Texas are dissimilar from the roll fronts of the Wyoming basins. The host sands for many of the deposits contain essentially no carbonaceous plant material, only abundant disseminated pyrite. Many of the deposits do not occur at the margin of altered (ferric oxide-bearing) sandstone tongues but rather occur entirely within reduced, pyurite-bearing sandstone. The abundance of pyrite within the sands probably reflects the introduction of H 2 S up along faults from hydrocarbon accumulations at depth. Such introductions before ore formation prepared the sands for roll-front development, whereas post-ore introductions produced re-reduction of portions of the altered tongue, leaving the deposit suspended in reduced sandstone. Evidence from three deposits suggests that ore formation was not accompanied by the introduction of significant amounts of H 2 S

Muddy and dolomitic rip-up clasts in Triassic fluvial sandstones: Origin and impact on potential reservoir properties (Argana Basin, Morocco)

Science.gov (United States)

Henares, Saturnina; Arribas, Jose; Cultrone, Giuseppe; Viseras, Cesar

2016-06-01

The significance of rip-up clasts as sandstone framework grains is frequently neglected in the literature being considered as accessory components in bulk sandstone composition. However, this study highlights the great value of muddy and dolomitic rip-up clast occurrence as: (a) information source about low preservation potential from floodplain deposits and (b) key element controlling host sandstone diagenetic evolution and thus ultimate reservoir quality. High-resolution petrographic analysis on Triassic fluvial sandstones from Argana Basin (T6 and T7/T8 units) highlights the significance of different types of rip-up clasts as intrabasinal framework components of continental sediments from arid climates. On the basis of their composition and ductility, three main types are distinguished: (a) muddy rip-up clasts, (b) dolomitic muddy rip-up clasts and (c) dolomite crystalline rip-up clasts. Spatial distribution of different types is strongly facies-related according to grain size. Origin of rip-up clasts is related to erosion of coeval phreatic dolocretes, in different development stages, and associated muddy floodplain sediments. Cloudy cores with abundant inclusions and clear outer rims of dolomite crystals suggest a first replacive and a subsequent displacive growth, respectively. Dolomite crystals are almost stoichiometric. This composition is very similar to that of early sandstone dolomite cement, supporting phreatic dolocretes as dolomite origin in both situations. Sandstone diagenesis is dominated by mechanical compaction and dolomite cementation. A direct correlation exists between: (1) muddy rip-up clast abundance and early reduction of primary porosity by compaction with irreversible loss of intergranular volume (IGV); and (2) occurrence of dolomitic rip-up clasts and dolomite cement nucleation in host sandstone, occluding adjacent pores but preserving IGV. Both processes affect reservoir quality by generation of vertical and 3D fluid flow baffles and

Characterization and 3D reservoir modelling of fluvial sandstones of the Williams Fork Formation, Rulison Field, Piceance Basin, Colorado, USA

International Nuclear Information System (INIS)

Pranter, Matthew J; Vargas, Marielis F; Davis, Thomas L

2008-01-01

This study describes the stratigraphic characteristics and distribution of fluvial deposits of the Upper Cretaceous Williams Fork Formation in a portion of Rulison Field and addresses 3D geologic modelling of reservoir sand bodies and their associated connectivity. Fluvial deposits include isolated and stacked point-bar deposits, crevasse splays and overbank (floodplain) mudrock. Within the Williams Fork Formation, the distribution and connectivity of fluvial sandstones significantly impact reservoir productivity and ultimate recovery. The reservoir sandstones are primarily fluvial point-bar deposits interbedded with shales and coals. Because of the lenticular geometry and limited lateral extent of the reservoir sandstones (common apparent widths of ∼500–1000 ft; ∼150–300 m), relatively high well densities (e.g. 10 acre (660 ft; 200 m) spacing) are often required to deplete the reservoir. Heterogeneity of these fluvial deposits includes larger scale stratigraphic variability associated with vertical stacking patterns and structural heterogeneities associated with faults that exhibit lateral and reverse offsets. The discontinuous character of the fluvial sandstones and lack of distinct marker beds in the middle and upper parts of the Williams Fork Formation make correlation between wells tenuous, even at a 10 acre well spacing. Some intervals of thicker and amalgamated sandstones within the middle and upper Williams Fork Formation can be correlated across greater distances. To aid correlation and for 3D reservoir modelling, vertical lithology proportion curves were used to estimate stratigraphic trends and define the stratigraphic zonation within the reservoir interval. Object-based and indicator-based modelling methods have been applied to the same data and results from the models were compared. Results from the 3D modelling indicate that sandstone connectivity increases with net-to-gross ratio and, at lower net-to-gross ratios (<30%), differences exist in

Compatibility tests between molten salts and metal materials (2)

International Nuclear Information System (INIS)

Shiina, Yasuaki

2003-08-01

Latent heat storage technology using molten salts can reduce temperature fluctuations of heat transfer fluid by latent heat for middle and high temperature regions. This enables us to operate several heat utilization systems in cascade connected to High Temperature Gas Cooled Reactors (HTGRs) from high to low temperature range by setting the latent heat storage system after a heat utilization system to reduce thermal load after the heat utilization systems. This latent heat technology is expected to be used for effective use of heat such as equalization of electric load between night and daytime. In the application of the latent heat technology, compatibility between molten salts and metal materials is very important because molten salts are corrosive, and heat transfer pipes and vessels will contact with the molten salts. It will be necessary to prevail the latent heat storage technique that normal metal materials can be used for the pipes and vessels. However, a few studies have been reported of compatibility between molten salts and metals in middle and high temperature ranges. In this study, four molten salts, range of the melting temperature from 490degC to 800degC, are selected and five metals, high temperature and corrosion resistance steels of Alloy600, HastelloyB2, HastelloyC276, SUS310S and pure Nickel are selected for the test with the consideration of metal composition. Test was performed in an electric furnace by setting the molten salts and the metals in melting pots in an atmosphere of nitrogen. Results revealed excellent corrosion resistance of pure Nickel and comparatively low corrosion resistance of nickel base alloys such as Alloy600 and Hastelloys against Li 2 CO 3 . Corrosion resistance of SUS310S was about same as nickel based alloys. Therefore, if some amount of corrosion is permitted, SUS310S would be one of the candidate alloys for structure materials. These results will be used as reference data to select metals in latent heat technology

Salt Tolerance and Polyphyly in the Cyanobacterium Chroococcidiopsis (Pleurocapsales)1

Science.gov (United States)

Cumbers, John Robert; Rothschild, Lynn J.

2014-01-01

Chroococcidiopsis Geitler (Geitler 1933) is a genus of cyanobacteria containing desiccation and radiation resistant species. Members of the genus live in habitats ranging from hot and cold deserts to fresh and saltwater environments. Morphology and cell division pattern have historically been used to define the genus. To better understand the genetic and phenotypic diversity of the genus, 15 species were selected that had been previously isolated from different locations, including salt and freshwater environments. Four markers were sequenced from these 15 species, the 16S rRNA, rbcL, desC1 and gltX genes. Phylogenetic trees were generated which identified two distinct clades, a salt-tolerant clade and a freshwater clade. This study demonstrates that the genus is polyphyletic based on saltwater and freshwater phenotypes. To understand the resistance to salt in more details, species were grown on a range of sea salt concentrations which demonstrated that the freshwater species were salt-intolerant whilst the saltwater species required salt for growth. This study shows an increased resolution of the phylogeny of Chroococcidiopsis and provides further evidence that the genus is polyphyletic and should be reclassified to improve clarity in the literature.

Secondary Aluminum Processing Waste: Salt Cake Characterization and Reactivity

Science.gov (United States)

Thirty-nine salt cake samples were collected from 10 SAP facilities across the U.S. The facilities were identified by the Aluminum Association to cover a wide range of processes. Results suggest that while the percent metal leached from the salt cake was relatively low, the leac...

SSR-based association mapping of salt tolerance in cotton (Gossypium hirsutum L.).

Science.gov (United States)

Zhao, Y L; Wang, H M; Shao, B X; Chen, W; Guo, Z J; Gong, H Y; Sang, X H; Wang, J J; Ye, W W

2016-05-25

The identification of simple sequence repeat (SSR) markers associated with salt tolerance in cotton contributes to molecular assisted selection (MAS), which can improve the efficiency of traditional breeding. In this study, 134 samples of upland cotton cultivars were selected. The seedling emergence rates were tested under 0.3% NaCl stress. A total of 74 SSR markers were used to scan the genomes of these samples. To identify SSR markers associated with salt tolerance, an association analysis was performed between salt tolerance and SSR markers using TASSEL 2.1, based on the analysis of genetic structure using Structure 2.3.4. The results showed that the seedling emergence rates of 134 cultivars were significantly different, and 27 salt-sensitive and 10 salt-tolerant cultivars were identified. A total of 148 loci were found in 74 SSR markers involving 246 allelic variations, which ranged from 2 to 7 with an average of 3.32 per SSR marker. The gene diversity ranged from 0.0295 to 0.4959, with the average being 0.2897. The polymorphic information content ranged from0.0290 to 0.3729, with the average being 0.2381. This natural population was classified into two subgroups by Structure 2.3.4, containing 89 and 45 samples, respectively. Finally, eight SSR sites associated with salt tolerance ware found through an association analysis, with the rate of explanation ranging from 2.91 to 7.82% and an average of 4.32%. These results provide reference data for the use MAS for salt tolerance in cotton.

Salt pill design and fabrication for adiabatic demagnetization refrigerators

Science.gov (United States)

Shirron, Peter J.; McCammon, Dan

2014-07-01

The performance of an adiabatic demagnetization refrigerator (ADR) is critically dependent on the design and construction of the salt pills that produce cooling. In most cases, the primary goal is to obtain the largest cooling capacity at the low temperature end of the operating range. The realizable cooling capacity depends on a number of factors, including refrigerant mass, and how efficiently it absorbs heat from the various instrument loads. The design and optimization of “salt pills” for ADR systems depend not only on the mechanical, chemical and thermal properties of the refrigerant, but also on the range of heat fluxes that the salt pill must accommodate. Despite the fairly wide variety of refrigerants available, those used at very low temperature tend to be hydrated salts that require a dedicated thermal bus and must be hermetically sealed, while those used at higher temperature - greater than about 0.5 K - tend to be single- or poly-crystals that have much simpler requirements for thermal and mechanical packaging. This paper presents a summary of strategies and techniques for designing, optimizing and fabricating salt pills for both low- and mid-temperature applications.

Salt Pill Design and Fabrication for Adiabatic Demagnetization Refrigerators

Science.gov (United States)

Shirron, Peter J.; Mccammon, Dan

2014-01-01

The performance of an adiabatic demagnetization refrigerator (ADR) is critically dependent on the design and construction of the salt pills that produce cooling. In most cases, the primary goal is to obtain the largest cooling capacity at the low temperature end of the operating range. The realizable cooling capacity depends on a number of factors, including refrigerant mass, and how efficiently it absorbs heat from the various instrument loads. The design and optimization of "salt pills" for ADR systems depend not only on the mechanical, chemical and thermal properties of the refrigerant, but also on the range of heat fluxes that the salt pill must accommodate. Despite the fairly wide variety of refrigerants available, those used at very low temperature tend to be hydrated salts that require a dedicated thermal bus and must be hermetically sealed, while those used at higher temperature - greater than about 0.5 K - tend to be single-­- or poly-­-crystals that have much simpler requirements for thermal and mechanical packaging. This paper presents a summary of strategies and techniques for designing, optimizing and fabricating salt pills for both low-­- and mid-­-temperature applications.

Mass transport in bedded salt and salt interbeds

International Nuclear Information System (INIS)

Hwang, Y.; Pigford, T.H.; Chambre, P.L.; Lee, W.W.L.

1989-08-01

Salt is the proposed host rock for geologic repositories of nuclear waste in several nations because it is nearly dry and probably impermeable. Although experiments and experience at potential salt sites indicate that salt may contain brine, the low porosity, creep, and permeability of salt make it still a good choice for geologic isolation. In this paper we summarize several mass-transfer and transport analyses of salt repositories. The mathematical details are given in our technical reports

Projected Salt Waste Production from a Commercial Pyroprocessing Facility

Directory of Open Access Journals (Sweden)

Michael F. Simpson

2013-01-01

Full Text Available Pyroprocessing of used nuclear fuel inevitably produces salt waste from electrorefining and/or oxide reduction unit operations. Various process design characteristics can affect the actual mass of such waste produced. This paper examines both oxide and metal fuel treatment, estimates the amount of salt waste generated, and assesses potential benefit of process options to mitigate the generation of salt waste. For reference purposes, a facility is considered in which 100 MT/year of fuel is processed. Salt waste estimates range from 8 to 20 MT/year from considering numerous scenarios. It appears that some benefit may be derived from advanced processes for separating fission products from molten salt waste, but the degree of improvement is limited. Waste form production is also considered but appears to be economically unfavorable. Direct disposal of salt into a salt basin type repository is found to be the most promising with respect to minimizing the impact of waste generation on the economic feasibility and sustainability of pyroprocessing.

Aeromagnetic gradient survey and elementary application in sandstone type uranium deposits prospecting

International Nuclear Information System (INIS)

Li Xiaolu; Chang Shushuai

2009-01-01

The principle,advantage and data processing of aeromagnetic gradient survey approach is introduced in this paper, and used to identify the shallow surface faults, uranium ore-forming environment and depth of magnetic body for the prospecting of sandstone type uranium deposits. (authors)

Cyclicity recorded in the provenance sandstones in the sedimentary in fill of the Cameros basin (N. Spain)

Energy Technology Data Exchange (ETDEWEB)

Gonzalez-Acebron, L.; Arribas, J.; Omodeo-Sale, S.; Arribas, E.; Le Pera, E.; Mas, R.; Lopez-Elorza, M.; Fernandez-Diaz, P. R.

2013-06-01

The intra plate Cameros rift basin in the north of Spain was formed came into being between the Tithonian and the Early Albian and contains 9 000 m of mostly continental sediments. This basin is a good example of cyclicity of different depositional sequences (DSs) in sedimentary environments, which show clear repetition in their sandstone composition (petrofacies) and diagenetic patterns. The DSs are arranged in two mega sequences (MSs) separated by a tectonic unconformity. A similar vertical sandstone compositional evolution, subdivided into two stages that repeat cyclically, has been recognised in both MSs: the first comprises quartzo-sedimentolithic petrofacies and the second is made up of several quartzo-feldspathic petrofacies. This was caused by a progression from the recycling of the pre-rift sedimentary cover to the erosion of the mainly plutonic and metamorphic crystalline basement. These changes in the erosion of the different source areas were conditioned by the tectonics of the basin. Furthermore, the original sandstone framework composition conditioned the diagenetic pattern of the two stages: quartzo-sedimentolithic sandstones containing large amounts of very pervasive carbonate cement that reduce their original porosity considerably, and quartzo-feldspathic petrofacies with a rigid framework that maintained the original pores during burial diagenesis. This compositional and diagenetic pattern is probably applicable to other non-volcanic rifted basins, depending upon the original amount of carbonate rock fragments present. (Author)

Methodology for the design of the method of siliceous sandstones operation using special software

Directory of Open Access Journals (Sweden)

Luis Ángel Lara-González

2014-12-01

Full Text Available The methodologies used for the design of the method of sandstones explotation by descending staggered banks using specialized software tools are reported. The data analyzed were collected in the field for the operating license 14816 in Melgar, Tolima. The characterization of the rock mass was held from physical and mechanical tests, performed on cylindrical test tubes in order to obtain the value of the maximum strenght and elastic modulus of the rock. The direction and dip of the sandstone package was rock. The direction and dip of the sandstone package was determined by using the stereographic projection whit DIPS®  software, and the safety factor of the slope was obtained with established banks whit SLIDE® . The slops are 8 meters high and 8 meters wide whit a tilt angle 60°, which generated a safety factor  of 2.1. The design  of the mining method was carried out with GEOVIA SURPAC® , at an early stage of development ascending to the level 11 of the exploitation, to then start mining in descending order to control the stabiLity of slopes. The results obtained allow a general methodology for the development of projects to optimize the process of evaluation and selection of mining method by using specialized design tools.

A economic evaluation system software on in-situ leaching mining sandstone uranium deposits

International Nuclear Information System (INIS)

Yao Yixuan; Su Xuebin; Xie Weixing; Que Weimin

2001-01-01

The author presents the study results of applying computer technology to evaluate quantitatively the technical-economic feasibility of in-situ leaching mining sandstone uranium deposits. A computer system software have been developed. Under specifying deposit conditions and given production size per year, the application of the software will generate total capital and mine life operating costs as well as solve for the movable and static financial assessment targets through discounted cash flow analysis. According to the characters of two kinds of sandstone uranium deposits, a data bases of economic and technique parameters of in-situ leaching have been designed. Also the system software can be used to study the economic value of deposits and to optimize the key project parameters. Its features, data input method and demand, main functions, structure and operating environments are described

Some aspects of the development of NW-German salt domes

International Nuclear Information System (INIS)

Jaritz, W.

1980-01-01

Aspects of the development of salt structures that may be of some importance to the safety of a final disposal site for radioactive waste are salt ascent and salt dissolution at the surface. The geological history of the salt domes is described in terms of the dissolution of the salt at the dome surface. In many cases it can be distinguished whether dissolution was caused by the ascent of the salt into strata containing groundwater by diapirism or by epeirogenic uplift or both. The salt domes of Wesendorf, Heide, and Marne are used as examples in a discussion of the transition from dissolution to the deposition of a cover of impermeable sediments. Moreover, the development of the Gorleben salt dome is described. The author's studies show the average rate of uplift of the NW-German salt domes in the diapiric stage to have ranged from a little less than 0.1 to about 0.5 mm per year. For salt domes in later stages, the rate of uplift is several hundredths of a millimeter per year at most. (orig.) [de

Local diversity versus geographical distribution of arthropods occuring in a sandstone rock labyrinth

Czech Academy of Sciences Publication Activity Database

Růžička, Vlastimil; Mlejnek, R.; Šmilauer, P.

2010-01-01

Roč. 58, č. 3 (2010), s. 533-544 ISSN 1505-2249 Institutional research plan: CEZ:AV0Z50070508 Keywords : sandstone * microclimate * paleorefugium Subject RIV: EH - Ecology, Behaviour Impact factor: 0.542, year: 2010

Comparison of Buffer Effect of Different Acids During Sandstone Acidizing

International Nuclear Information System (INIS)

Shafiq, Mian Umer; Mahmud, Hisham Khaled Ben; Hamid, Mohamed Ali

2015-01-01

The most important concern of sandstone matrix acidizing is to increase the formation permeability by removing the silica particles. To accomplish this, the mud acid (HF: HCl) has been utilized successfully for many years to stimulate the sandstone formations, but still it has many complexities. This paper presents the results of laboratory investigations of different acid combinations (HF: HCl, HF: H 3 PO 4 and HF: HCOOH). Hydrofluoric acid and fluoboric acid are used to dissolve clays and feldspar. Phosphoric and formic acids are added as a buffer to maintain the pH of the solution; also it allows the maximum penetration of acid into the core sample. Different tests have been performed on the core samples before and after the acidizing to do the comparative study on the buffer effect of these acids. The analysis consists of permeability, porosity, color change and pH value tests. There is more increase in permeability and porosity while less change in pH when phosphoric and formic acids were used compared to mud acid. From these results it has been found that the buffer effect of phosphoric acid and formic acid is better than hydrochloric acid. (paper)

Perspective and resource evaluation and metallogenic studies on sandstone-type uranium deposit in Qianjiadian depression of Songliao Basin

Energy Technology Data Exchange (ETDEWEB)

Yuliang, Xia; Jinrong, Lin; Ziying, Li; Shengxiang, Li; Hanbin, Liu; Zhiming, Wang; Guang, Fan [Beijing Research Inst. of Uranium Geology, Beijing (China); Jiwei, Zheng; Zhenji, Li; Mingyu, Zhang [Liaohe Oil Field, Panjin (China)

2003-07-01

The geotectonic evolution history of the southeastern part of Songliao Basin has been clearly described and it is pointed out that both of the provenance rocks and evolution features of the studied area are favorable to the formation of U-rich sandstone bodies, development of interlayered oxidation and providing uranium source for mineralization. Yaojia Formation in Qianjiadian depression has been found out to be the favorable target ore bed for looking for sandstone-type uranium deposit. On the basis of analysis of metallogenetic conditions, the perspective target area has been circled and a sandstone-type uranium deposit with a certain amounts of uranium tonnages has been discovered. The achievements and data have been gotten in the following aspects: constitution and features of ore-forming beds and sandstone bodies, uranium existence forms and mineralogical and chemical compositions of the ores, associated elements and their economic values for comprehensive mining. The study of metallogenetic features and mechanism of the uranium deposit suggested that pre-enrichment of uranium during the depositional-diagenetic stage provide a good basis for uranium mineralization, and hereafter interlayered oxidation as well as oil-gas reduction processes played a decisive role to uranium mineralization. U-Pb isotopic studies indicate that the ores have two isochron ages of 53{+-}3 Ma and 7.0{+-}0 Ma, corresponding to the periods of arid and semiarid paleo-climates which are favorable to interlayered oxidation development and uranium mineralization. It is concluded that the Qianjiadian sandstone-type uranium deposit is genetically related to interlayered oxidation and secondary reduction of oil-gas. The metallogenic model of Qianjiadian uranium deposit was set up. (authors)

Perspective and resource evaluation and metallogenic studies on sandstone-type uranium deposit in Qianjiadian depression of Songliao Basin

International Nuclear Information System (INIS)

Xia Yuliang; Lin Jinrong; Li Ziying; Li Shengxiang; Liu Hanbin; Wang Zhiming; Fan Guang; Zheng Jiwei; Li Zhenji; Zhang Mingyu

2003-01-01

The geotectonic evolution history of the southeastern part of Songliao Basin has been clearly described and it is pointed out that both of the provenance rocks and evolution features of the studied area are favorable to the formation of U-rich sandstone bodies, development of interlayered oxidation and providing uranium source for mineralization. Yaojia Formation in Qianjiadian depression has been found out to be the favorable target ore bed for looking for sandstone-type uranium deposit. On the basis of analysis of metallogenetic conditions, the perspective target area has been circled and a sandstone-type uranium deposit with a certain amounts of uranium tonnages has been discovered. The achievements and data have been gotten in the following aspects: constitution and features of ore-forming beds and sandstone bodies, uranium existence forms and mineralogical and chemical compositions of the ores, associated elements and their economic values for comprehensive mining. The study of metallogenetic features and mechanism of the uranium deposit suggested that pre-enrichment of uranium during the depositional-diagenetic stage provide a good basis for uranium mineralization, and hereafter interlayered oxidation as well as oil-gas reduction processes played a decisive role to uranium mineralization. U-Pb isotopic studies indicate that the ores have two isochron ages of 53±3 Ma and 7.0±0 Ma, corresponding to the periods of arid and semiarid paleo-climates which are favorable to interlayered oxidation development and uranium mineralization. It is concluded that the Qianjiadian sandstone-type uranium deposit is genetically related to interlayered oxidation and secondary reduction of oil-gas. The metallogenic model of Qianjiadian uranium deposit was set up. (authors)

Alternatives for definse waste-salt disposal

International Nuclear Information System (INIS)

Benjamin, R.W.; McDonell, W.R.

1983-01-01

Alternatives for disposal of decontaminated high-level waste salt at Savannah River were reviewed to estimate costs and potential environmental impact for several processes. In this review, the reference process utilizing intermediate-depth burial of salt-concrete (saltcrete) monoliths was compared with alternatives including land application of the decontaminated salt as fertilizer for SRP pine stands, ocean disposal with and without containment, and terminal storage as saltcake in existing SRP waste tanks. Discounted total costs for the reference process and its modifications were in the same range as those for most of the alternative processes; uncontained ocean disposal with truck transport to Savannah River barges and storage as saltcake in SRP tanks had lower costs, but presented other difficulties. Environmental impacts could generally be maintained within acceptable limits for all processes except retention of saltcake in waste tanks, which could result in chemical contamination of surrounding areas on tank collapse. Land application would require additional salt decontamination to meet radioactive waste disposal standards, and ocean disposal without containment is not permitted in existing US practice. The reference process was judged to be the only salt disposal option studied which would meet all current requirements at an acceptable cost

Sandstone uranium deposits in the United States: a review of the history, distribution, genesis, mining areas, and outlook

International Nuclear Information System (INIS)

Crawley, R.A.

1983-03-01

Sandstone uranium deposits account for about 94 percent of uranium reserves in the United States. Most sandstone uranium districts had been found by the mid-1950s in response to incentives promulgated by the US Atomic Energy Commission. Principal uranium resource regions in the United States are the Colorado Plateau, Wyoming Basins, and Texas Coastal Plain. Statistical data published annually by the US Department of Energy show trends of uranium exploration and production, estimates of resources, and distributions and characteristics of reserves. At present, US exploration and production are curtailed because of uranium oversupply, a trend that will continue for the next few years. Although the outlook is more optimistic over the longer term, it is clouded by possible competition from foreign low-cost, nonsandstone uranium. Roll-type and peneconcordant are the two principal types of sandstone uranium deposits. Roll deposits are formed at geochemical fronts where oxidizing uranium-bearing groundwater penetrates reduced sandstone. Uranium is precipitated by reduction at the front. Under mildly reducing conditions, uranium may remain in solution until it is locally precipitated by reduction, chelation, or complexing to form peneconcordant deposits. Proposed precipitating agents include carbonaceous matter, humate, pyrite, and hydrogen sulfide. The uranium is thought to have been derived from leaching of tuffaceous or arkosic sediments, or of granitic rocks

An Experimental Study of the Fracture Coalescence Behaviour of Brittle Sandstone Specimens Containing Three Fissures

Science.gov (United States)

Yang, S. Q.; Yang, D. S.; Jing, H. W.; Li, Y. H.; Wang, S. Y.

2012-07-01

To analyse the fracture coalescence behaviour of rock, rectangular prismatic sandstone specimens (80 × 160 × 30 mm in size) containing three fissures were tested under uniaxial compression. The strength and deformation behaviours of the specimens are first analysed by investigating the effects of the ligament angle β2 on the peak strength, peak strain and crack initiation stress of the specimens. To confirm the sequence of crack coalescence, a photographic monitoring technique is used throughout the entire period of deformation. Based on the results, the relationship between the real-time crack coalescence process and the axial stress-strain curve of brittle sandstone specimens is also developed, and this relationship can be used to evaluate the macroscopic deformation characteristics of pre-cracked rock. The equivalent strain evolution fields of the specimen, with α = β1 = 45° and β2 = 90°, are obtained using the digital image correlation technique and show good agreement with the experimental results of pre-cracked brittle sandstone. These experimental results are expected to improve the understanding of fracture mechanisms and be used in rock engineering with intermittent structures, such as deep underground excavated tunnels.

Chain stiffness, salt valency, and concentration influences on titration curves of polyelectrolytes: Monte Carlo simulations

Science.gov (United States)

Carnal, Fabrice; Stoll, Serge

2011-01-01

Monte Carlo simulations have been used to study two different models of a weak linear polyelectrolyte surrounded by explicit counterions and salt particles: (i) a rigid rod and (ii) a flexible chain. We focused on the influence of the pH, chain stiffness, salt concentration, and valency on the polyelectrolyte titration process and conformational properties. It is shown that chain acid-base properties and conformational properties are strongly modified when multivalent salt concentration variation ranges below the charge equivalence. Increasing chain stiffness allows to minimize intramolecular electrostatic monomer interactions hence improving the deprotonation process. The presence of di and trivalent salt cations clearly promotes the chain degree of ionization but has only a limited effect at very low salt concentration ranges. Moreover, folded structures of fully charged chains are only observed when multivalent salt at a concentration equal or above charge equivalence is considered. Long-range electrostatic potential is found to influence the distribution of charges along and around the polyelectrolyte backbones hence resulting in a higher degree of ionization and a lower attraction of counterions and salt particles at the chain extremities.

The sandstone's chromatic alteration of the florentine cultural heritage

Science.gov (United States)

Vettori, S.; Pecchioni, E.; Cantisani, E.; Ricci, M.; Fratini, F.; Garzonio, C. A.

2012-04-01

Pietra Serena is one of the materials more used in Florentine architecture. It is a sandstone that outcrops in the hills north of the city in the municipality of Fiesole and it has been employed mainly for ornamental purposes. This litotype belongs to the the Macigno Formation (Oligocene Upper- Miocene Lower) which consists of beds of turbiditic sandstones separated by pelitic levels which are the finest components of each single turbidity layer. Petrographically, Pietra Serena can be defined as a medium-coarse-grained greywacke made of quartz, feldspars, micas, fragments of metamorphic and magmatic rocks. The clayey matrix is quite abundant, mainly composed by illite, kaolinite and chlorite-vermiculite (present only in some quarries). It is well known that the processes of decay of the sandstones are related to the type of matrix, the amount of cement, the kind of clay minerals and to the pore size distribution, which lead to water infiltrations, swelling of the clay minerals, separation of the clayey matrix, with resulting exfoliation and peeling of the stone artefacts. Pietra Serena has a bluish-grey colour in fresh cut, but many times it is easily oxidized acquiring an ochraceous-reddish brown colour on buildings. Such changes in colour, appear to be due in part to the oxidation of iron, proceeding very quickly from the surface to the inside, though the cohesion is not affected. It is possible to hypothesize that the chromatic changes not necessarily involve a progressive state of alteration of the artefact, but they may often to represents a natural patina acquired with the time. Nevertheless it is necessary to remember that the oxidized layer and its hardness could also be the result of treatments performed in the past. In Florence, several monuments and buildings are affected by such phenomenon, in particular it is possible to note an intense and diffuse reddish colouring on the Pietra Serena utilized for columns and for façade's decorations. In this work

Petrological features of selected components of the Cergowa sandstones (Outer Carpathians recorded by scanning electron microscopy – preliminary study

Directory of Open Access Journals (Sweden)

Pszonka Joanna

2017-01-01

Full Text Available The scanning electron microscope analysis of the Cergowa sandstones brings new data on their petrological features and chemical composition. Previous work in standard petrographic examination, e.g. polarising (PL or cathodoluminescence (CL microscopy, displayed limited information on grain surface topography and only assumptions to their geochemistry. Both identification and characterisation of minerals are fundamental in the progress of mining and minerals processing systems. Detrital grains of the Cergowa sandstones are bound by calcite and dolomitic cement and commonly corroded by diagenetic fluids, however, in varying degrees, which is illustrated here by feldspar, quartz and dolomite minerals. Dissolution processes of marginal parts of these mineral grains resulted in corrosion, which increased the contact surface between the grains and the cement. The difference in resistance to these processes was observed not only among distinct groups of minerals, but also within the group of feldspars: between K–feldspars and minerals of plagioclase. That combination resulted in exceptionally strong cementation of the Cergowa sandstones, which is expressed by their high hardness and resistance to abrasion, freezing, and thawing. Inherent parameters of sandstones are characterised by their petrographical properties.

Catalytic Conversion of Dihydroxyacetone to Lactic Acid Using Metal Salts in Water

NARCIS (Netherlands)

Rasrendra, Carolus B.; Fachri, Boy A.; Makertihartha, I. Gusti B. N.; Adisasmito, Sanggono; Heeres, Hero J.

2011-01-01

We herein present a study on the application of homogeneous catalysts in the form of metal salts on the conversion of trioses, such as dihydroxyacetone (DHA), and glyceraldehyde (GLY) to lactic acid (LA) in water. A wide range of metal salts (26 in total) were examined. Al(III) salts were identified

Comparative organic petrology of interlayered sandstones, siltstones, mudstones and coals in the Upper Carboniferous Ruhr basin, northwest Germany, and their thermal history and methane generation

Energy Technology Data Exchange (ETDEWEB)

Scheidt, G.; Littke, R. (Harress Geotechnik GmbH, Floersheim (Germany, F.R.))

1989-01-01

In the coal-mining Ruhr-area, Upper Carboniferous rocks consist of interlayered sandstones, siltstones, mudstones and coals. They were deposited in a tropical, paralic environment where alternating fluvial sedimentation, occasional marine ingressions, and swamp growth resulted in an irregular cyclic succession. The total sedimentary package contains on an average 6 Vol.% of organic manner. About 70 Vol. % of the organic matter occurs in coal seams, the rest as dispersed organic matter in clastic rocks. The organic matter is autochthonous in the coals and allochthonous in associated sandstones and siltstones. It consists of about 70% vitrinite, 20% inertinite, and 10% liptinite. The overall maceral group composition is the same for coals and dispersed organic matter. This surprising similarity is caused by a nearly exclusive input of land-plant derived organic matter to swamps and fluvial systems and a similar degree of preservation. Highest average liptinite contents were found in unrooted mudstones, highest average inertinite contents in coarse-grained siltstones and highest average vitrinite percentages in sandstones. Maturities of the sediments studied are well within the hydrocarbon generation window, e.g. vitrinite reflectivities range from 0.6% to 1.6%. Reflectivities measured on dispersed particles in clastic rocks are similar to those measured in coal seams. Calculations of the amount of methane generated indicate that coal seams contributed more to the total hydrocarbon generation than dispersed organic matter. 51 refs., 13 figs.

Thermophysical behavior of St. Peter sandstone: application to compressed air energy storage in an aquifer

Energy Technology Data Exchange (ETDEWEB)

Erikson, R.L.

1983-12-01

The long-term stability of a sandstone reservoir is of primary importance to the success of compressed air energy storage (CAES) in aquifers. The purpose of this study was to: develop experimental techniques for the operation of the CAES Porous Media Flow Loop (PMFL), an apparatus designed to study the stability of porous media in subsurface geologic environments, conduct experiments in the PMFL designed to determine the effects of temperature, stress, and humidity on the stability of candidate CAES reservoir materials, provide support for the CAES field demonstration project in Pittsfield, Illinois, by characterizing the thermophysical stability of Pittsfield reservoir sandstone under simulated field conditions.

Genesis of sandstone-type uranium deposits in the Sierra Pintada district, Mendoza, Argentina: a Moessbauer study

International Nuclear Information System (INIS)

Labenski, F.; Saragovi-Badler, C.

1982-01-01

The genesis of sandstone-type uranium deposits in the Cochico Group (Permo-Triassic) of the Sierra Pintada district, San Rafael, Mendoza, has been studied. This is the most important uranium district in Argentina. Uranium sources, uranium transport and precipitation are discussed. Uraninite and brannerite, the main uranium minerals, occur within the matrix of sandstone. Several phenomena can be deduced regarding the depositional environment. Where oxygen was available, precipitation of hydrated ferric oxides occurred; γFe 2 O 3 .nH 2 O varieties (identified by Moessbauer spectroscopy) precipitated in the upper levels of the aquifer, where CO 2 partial pressure was lower, giving reddish or reddish-brown beds. The CO 2 partial pressure also determines the distribution of biogenic agents such as bacteria. Bacteria thus find a more favourable environment for their development and action in upper levels of an aquifer. In the corresponding horizons local reduction occurred where UO 2 precipitated; therefore the highest uranium concentrations correspond to sandstone levels with reddish or reddish-brown pigment. These pigments have been identified by Moessbauer spectroscopy. (Auth.)

Home ranges of brown hares in a natural salt marsh: comparisons with agricultural systems

NARCIS (Netherlands)

Kunst, P.; Wal, van der R.; Wieren, van S.E.

2001-01-01

This is the first study on spatial behaviour of brown hares Lepus europaeus Pallas, 1778 based on radio-telemetry in a natural system, which we contrast with data from agricultural systems. Radio tracking took place in a Dutch salt marsh over a 10-month period, with intensive tracking sessions

Home ranges of brown hares in a natural salt marsh : comparisons with agricultural systems

NARCIS (Netherlands)

Kunst, PJG; van der Wal, R; van Wieren, Sip

This is the first study on spatial behaviour of brown hares Lepus europaeus Pallas, 1778 based on radio-telemetry in a natural system, which we contrast with data from agricultural systems. Radio tracking took place in a Dutch salt marsh over a 10-month period, with intensive tracking sessions

Research and application of information system for sandstone-type uranium exploration

International Nuclear Information System (INIS)

Han Shaoyang; Huang Shutao; Hou Huiqun

2003-01-01

The GIS (Geographical Information System) technique is applied to the exploration and evaluation of in-situ leachable sandstone-type uranium deposits and the GIS application system of desktop is created for non-GIS professionals. ArcView3.2 is taken as compositive platform of the information system. The secondary design is developed through the AVENUE language provided by ArcView3.2 on the software functions. According to the needs of multi-source information management and integrated evaluation, a series of new functions are appended to the basic platform through AVENUE language on a basis of sufficiently inheriting ArcView3.2 software functions and a friendly graphic user interface is also created, so that the system implements the following functions better, including information query, data base management, editing graphics, geologic mapping, image processing, spatial analysis, model analysis and result output. In order to manage the plenty of borehole data better and quickly realize the borehole mapping, a system software of borehole data management and mapping on the base of GIS software platform is developed. The system software has been applied to uranium survey project in the west of Hailaer basin. Based on multi-source geoscience information database including geologic, geophysical, geochemical and remote sensing data, the system software has been used to perform the integrated analysis of spatial data for realizing the deep analysis and studies of the metallogenic geologic environments of sandstone-type uranium deposits. In the Kelulun basin, the weights of evidence analysis have been used to quantitatively predict the prospective areas of sandstone uranium deposits. Information system has also been applied to the integrated evaluation of uranium resource in the south of Yili basin, Songliao basin and other areas. (authors)

Boric Ester-Type Molten Salt via Dehydrocoupling Reaction

Directory of Open Access Journals (Sweden)

Noriyoshi Matsumi

2014-11-01

Full Text Available Novel boric ester-type molten salt was prepared using 1-(2-hydroxyethyl-3-methylimidazolium chloride as a key starting material. After an ion exchange reaction of 1-(2-hydroxyethyl-3-methylimidazolium chloride with lithium (bis-(trifluoromethanesulfonyl imide (LiNTf2, the resulting 1-(2-hydroxyethyl-3-methylimidazolium NTf2 was reacted with 9-borabicyclo[3.3.1]nonane (9-BBN to give the desired boric ester-type molten salt in a moderate yield. The structure of the boric ester-type molten salt was supported by 1H-, 13C-, 11B- and 19F-NMR spectra. In the presence of two different kinds of lithium salts, the matrices showed an ionic conductivity in the range of 1.1 × 10−4–1.6 × 10−5 S cm−1 at 51 °C. This was higher than other organoboron molten salts ever reported.

An Experimental and Numerical Study on Cracking Behavior of Brittle Sandstone Containing Two Non-coplanar Fissures Under Uniaxial Compression

Science.gov (United States)

Yang, Sheng-Qi; Tian, Wen-Ling; Huang, Yan-Hua; Ranjith, P. G.; Ju, Yang

2016-04-01

To understand the fracture mechanism in all kinds of rock engineering, it is important to investigate the fracture evolution behavior of pre-fissured rock. In this research, we conducted uniaxial compression experiments to evaluate the influence of ligament angle on the strength, deformability, and fracture coalescence behavior of rectangular prismatic specimens (80 × 160 × 30 mm) of brittle sandstone containing two non-coplanar fissures. The experimental results show that the peak strength of sandstone containing two non-coplanar fissures depends on the ligament angle, but the elastic modulus is not closely related to the ligament angle. With the increase of ligament angle, the peak strength decreased at a ligament angle of 60°, before increasing up to our maximum ligament angle of 120°. Crack initiation, propagation, and coalescence were all observed and characterized from the inner and outer tips of pre-existing non-coplanar fissures using photographic monitoring. Based on the results, the sequence of crack evolution in sandstone containing two non-coplanar fissures was analyzed in detail. In order to fully understand the crack evolution mechanism of brittle sandstone, numerical simulations using PFC2D were performed for specimens containing two non-coplanar fissures under uniaxial compression. The results are in good agreement with the experimental results. By analyzing the stress field, the crack evolution mechanism in brittle sandstone containing two non-coplanar fissures under uniaxial compression is revealed. These experimental and numerical results are expected to improve the understanding of the unstable fracture mechanism of fissured rock engineering structures.

21 CFR 100.155 - Salt and iodized salt.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Salt and iodized salt. 100.155 Section 100.155 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) FOOD FOR HUMAN CONSUMPTION GENERAL Specific Administrative Rulings and Decisions § 100.155 Salt and iodized salt. (a) For the purposes of this section, the...

Measuring the zeta potential. The relationships with sandstone fineness

Directory of Open Access Journals (Sweden)

de Luxán, M. P.

1989-09-01

Full Text Available The application of the zeta potential technique in the area of construction materials and Portland cement is quite recent. The initial research work involved the study of cement suspensions or suspensions of one of the components of cement, such as alite, tricalcium alumínate, in the presence of additives and, more specifically, superplasticizers. The studies of this sort were extended with the mixing of active additions into cement (fly ashes, etc.. The present study discusses the application of siliceous materials (sandstone as a basis of the research into the behaviour of sandstone mortars containing repair products.

La aplicación de la técnica del potencial zeta en el campo de los materiales de construcción y del cemento portland es muy reciente. Las primeras investigaciones se refieren al estudio de suspensiones de cemento o de alguno de sus compuestos que lo forman como alita, aluminato tricálcico, en presencia de aditivos y, más concretamente, de superfluidificantes. Con la incorporación de adiciones activas al cemento (cenizas volantes,... se amplían los estudios de este tipo de cementos. En este trabajo se considera la aplicación a los materiales silíceos (arenisca como base para la investigación del comportamiento de los morteros de arenisca conteniendo productos de reparación.

Uranium isotopes in groundwater: their use in prospecting for sandstone-type uranium deposits

International Nuclear Information System (INIS)

Cowart, J.B.; Osmond, J.K.

1977-01-01

The relative abundances of dissolved 238 U and its daughter 234 U appear to be greatly affected as the uranium is transported downdip in sandstone aquifers. In an actively forming uranium accumulation at a reducing barrier, an input of 234 U occurs in proximity to the isotopically non-selective precipitation of uranium from the water. The result is a downdip water much lower in uranium concentration but relatively enriched in 234 U. The measurement of isotopic as well as concentration changes may increase the effectiveness of hydrogeochemical exploration of uranium. The investigation includes the uranium isotopic patterns in aquifers associated with known uranium orebodies in the Powder River and Shirley Basins, Wyoming, and Karnes County, Texas, USA. In addition, the Carrizo sandstone aquifer of Texas was studied in detail and the presence of an uranium accumulation inferred

Changes in the composition and properties of Ashalchinskoye bitumen-saturated sandstones when exposed to water vapor

Science.gov (United States)

Korolev, E.; Eskin, A.; Kolchugin, A.; Morozov, V.; Khramchenkov, M.; Gabdelvalieva, R.

2018-05-01

Ashalchinskoye bitumen deposit is an experimental platform for testing technology of high-viscosity oil extraction from reservoir rocks. Last time for enhanced of oil recovery in reservoir used pressurization a water vapor with a temperature of ∼ 180 ° C (SAGD technology). However, what happens in sandstone reservoir is little known. We did a study of the effects of water vapor on the structural components of bitumen saturated sandstone. In paper were studied the rock samples at base condition and after one week exposure by water vapour. The thermal analysis showed that steaming helps to removes light and middle oil fractions with a boiling point up to 360 ° C from oil saturated sandstones. Content of heavy oil fractions virtually unchanged. Studying the composition of water extractions of samples showed that the process of aquathermolysis of oil is accompanied by a lowering of the pH of the pore solution from 7.4 to 6.5 and rise content in several times of mobile cations Ca2+, Mg2+ and HCO3 -, SO4 2- anions. Follows from this that the thermal steam effect by bitumen saturated sandstones leads to partial oxidation of hydrocarbons with to form a carbon dioxide. The source of sulfate ions were oxidized pyrite aggregates. Due to the increasing acidity of condensed water, which fills the pore space of samples, pore fluid becomes aggressive to calcite and dolomite cement of bitumen saturated sandstones. As a result of the dissolution of carbonate cement the pore fluid enriched by calcium and magnesium cations. Clearly, that the process is accompanied by reduction of contact strength between fragments of minerals and rocks. Resulting part of compounds is separated from the outer side of samples and falls to bottom of water vapor container. Decreasing the amount of calcite and dolomite anions in samples in a steam-treated influence is confirmed by X-Ray analysis. X-Ray analysis data of study adscititious component of rocks showed that when influenced of water vapor to

Palaeoclimatic trends deduced from the hydrochemistry of a Triassic sandstone aquifer, United Kingdom

International Nuclear Information System (INIS)

Bath, A.H.; Edmunds, W.M.; Andrews, J.N.

1979-01-01

A detailed geochemical study (elemental, isotopic and dissolved inert gases) of unconfined and confined sections of the Triassic non-marine sandstone aquifer in eastern England has been undertaken. Aspects of the recharge history of this aquifer over the past 40,000 years are revealed by examination of the data. 14 C activity and delta 13 C values show downgradient decrease and increase, respectively, the latter from -12 to -13 per mille (PDB) at outcrop to -8.5 per mille in deep confined groundwaters, indicating a continuing reaction between water and carbonate mineral phases. Although the bulk carbonate contained in sandstone samples gives delta 13 C around -7 per mille, modelling of the carbon isotopic evolution and consideration of the resulting 14 C age corrections suggest that a carbonate with delta 13 C closer to 0 per mille has played a major role in at least the earlier stages of hydrochemical evolution. The corrected radiocarbon age ranges, generated by the computer program WATEQF-ISOTOP, are used as a framework in which the palaeo-environmental information from oxygen and hydrogen isotope data, inert gas contents, and chloride levels are discussed. The measurement of dissolved helium levels demonstrates an excess of 4 He in many samples, which correlates with radiocarbon ages. The assumption of bulk chemical and physical properties for the aquifer rock allows independent 'excess 4 He' ages to be computed, which are mostly in excess of the corrected 14 C ages. The trend of delta 18 O is from about -8 per mille at outcrop to -9.7 per mille (SMOW) downgradient, which is significantly more depleted than has been found in previous studies of UK basins. The delta 2 H and delta 18 O values are related by the regression line delta 2 H=6.6delta 18 O+1; data from other UK studies also lie close to this trend

Improved Design and Fabrication of Hydrated-Salt Pills

Science.gov (United States)

Shirron, Peter J.; DiPirro, Michael J.; Canavan, Edgar R.

2011-01-01

A high-performance design, and fabrication and growth processes to implement the design, have been devised for encapsulating a hydrated salt in a container that both protects the salt and provides thermal conductance between the salt and the environment surrounding the container. The unitary salt/container structure is known in the art as a salt pill. In the original application of the present design and processes, the salt is, more specifically, a hydrated paramagnetic salt, for use as a refrigerant in a very-low-temperature adiabatic demagnetization refrigerator (ADR). The design and process can also be applied, with modifications, to other hydrated salts. Hydrated paramagnetic salts have long been used in ADRs because they have the desired magnetic properties at low temperatures. They also have some properties, disadvantageous for ADRs, that dictate the kind of enclosures in which they must be housed: Being hydrated, they lose water if exposed to less than 100-percent relative humidity. Because any dehydration compromises their magnetic properties, salts used in ADRs must be sealed in hermetic containers. Because they have relatively poor thermal conductivities in the temperature range of interest (<0.1 K), integral thermal buses are needed as means of efficiently transferring heat to and from the salts during refrigeration cycles. A thermal bus is typically made from a high-thermal-conductivity met al (such as copper or gold), and the salt is configured to make intimate thermal contact with the metal. Commonly in current practice (and in the present design), the thermal bus includes a matrix of wires or rods, and the salt is grown onto this matrix. The density and spacing of the conductors depend on the heat fluxes that must be accommodated during operation.

Coronation Hill U-Au mine, South Alligator Valley, Northern Territory: an epigenetic sandstone-type deposit hosted by debris-flow conglomerate

International Nuclear Information System (INIS)

Needham, R.S.; Stuart-Smith, P.G.

1987-01-01

The host rock at the Coronation Hill U-Au mine is a debris flow conglomerate, developed in a high-energy fluvial environment during deposition of the Coronation Sandstone of the El Sherana Group. Mineralisation took place by movement of low-temperature fluids from the U-enriched volcanics into the conduit sandstone and eventually into the reduced debris flow conglomerate and carbonaceous shale

Subsurface stratigraphy and uranium--vanadium favorability of the Morrison Formation, Sage Plain Area, southeastern Utah and southwestern Colorado

International Nuclear Information System (INIS)

Girdley, W.A.; Flook, J.E.; Harris, R.E.

1975-08-01

The four members of the Morrison Formation that are recognizable in the area studied are, in ascending order, the Salt Wash, Recapture, Westwater Canyon, and Brushy Basin. The Salt Wash member has the highest uranium favorability of all the Morrison strata in the area studied. An especially favorable area, in which the Salt Wash interval is thick and contains several thick sandstones, is situated on either side of the Utah-Colorado state line between Monticello, Utah, and Dove Creek, Colorado. The upper Morrison strata (Westwater Canyon and Brushy Basin members) have low uranium favorability. The Westwater Canyon member contains adequate sandstones but lacks known uranium deposits in the project area. The Brushy Basin member, although rated as having low potential, nevertheless does possess some attributes that make it worthy of further attention. The Recapture member does not contain sufficient well-developed sandstones or uranium deposits to merit its being classed as favorable for potential uranium-vanadium resources. (LK)

Strain localization and elastic-plastic coupling during deformation of porous sandstone

Energy Technology Data Exchange (ETDEWEB)

Dewers, Thomas A. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States). Geomechanics Dept.; Issen, Kathleen A. [Clarkson Univ., Potsdam, NY (United States). Mechanical and Aeronautical Engineering; Holcomb, David J. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States). Geomechanics Dept.; Olsson, William A. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States). Geomechanics Dept.; Ingraham, Mathew D. [Sandia National Laboratories (SNL-NM), Albuquerque, NM (United States). Geomechanics Dept.

2017-09-12

Results of axisymmetric compression tests on weak, porous Castlegate Sandstone (Cretaceous, Utah, USA), covering a range of dilational and compactional behaviors, are examined for localization behavior. Assuming isotropy, bulk and shear moduli evolve as increasing functions of mean stress and Mises equivalent shear stress respectively, and as decreasing functions of work-conjugate plastic strains. Acoustic emissions events located during testing show onset of localization and permit calculation of observed shear and low-angle compaction localization zones, or bands, as localization commences. Total strain measured experimentally partitions into: A) elastic strain with constant moduli, B) elastic strain due to stress dependence of moduli, C) elastic strain due to moduli degradation with increasing plastic strain, and D) plastic strain. The third term is the elastic-plastic coupling strain, and though often ignored, contributes significantly to pre-failure total strain for brittle and transitional tests. Constitutive parameters and localization predictions derived from experiments are compared to theoretical predictions. In the brittle regime, predictions of band angles (angle between band normal and maximum compression) demonstrate good agreement with observed shear band angles. Compaction localization was observed in the transitional regime in between shear localization and spatially pervasive compaction, over a small range of mean stresses. In contrast with predictions however, detailed acoustic emissions analyses in this regime show low angle, compaction-dominated but shear-enhanced, localization.

Sea salts as a potential source of food spoilage fungi.

Science.gov (United States)

Biango-Daniels, Megan N; Hodge, Kathie T

2018-02-01

Production of sea salt begins with evaporation of sea water in shallow pools called salterns, and ends with the harvest and packing of salts. This process provides many opportunities for fungal contamination. This study aimed to determine whether finished salts contain viable fungi that have the potential to cause spoilage when sea salt is used as a food ingredient by isolating fungi on a medium that simulated salted food with a lowered water activity (0.95 a w ). The viable filamentous fungi from seven commercial salts were quantified and identified by DNA sequencing, and the fungal communities in different salts were compared. Every sea salt tested contained viable fungi, in concentrations ranging from 0.07 to 1.71 colony-forming units per gram of salt. In total, 85 fungi were isolated representing seven genera. One or more species of the most abundant genera, Aspergillus, Cladosporium, and Penicillium was found in every salt. Many species found in this study have been previously isolated from low water activity environments, including salterns and foods. We conclude that sea salts contain many fungi that have potential to cause food spoilage as well as some that may be mycotoxigenic. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

Reservoir characterization of Pennsylvanian sandstone reservoirs. Final report

Energy Technology Data Exchange (ETDEWEB)

Kelkar, M.

1995-02-01

This final report summarizes the progress during the three years of a project on Reservoir Characterization of Pennsylvanian Sandstone Reservoirs. The report is divided into three sections: (i) reservoir description; (ii) scale-up procedures; (iii) outcrop investigation. The first section describes the methods by which a reservoir can be described in three dimensions. The next step in reservoir description is to scale up reservoir properties for flow simulation. The second section addresses the issue of scale-up of reservoir properties once the spatial descriptions of properties are created. The last section describes the investigation of an outcrop.

Early cretaceous Obernirchen and Bentheim sandstones from Germany used as dimension stone in the Netherlands: geology physical properties, architectural use and comparative weathering

NARCIS (Netherlands)

Dubelaar, C.W.; Nijland, T.G.

2015-01-01

The Netherlands, with only scarce occurrences of outcropping or shallow buried natural stone, has over centuries imported huge quantities of Early Cretaceous Bentheim Sandstone and Obernkirchen Sandstone from Germany. The present paper provides an overview of their distribution and properties

Anatomy of an ancient aeolian sandstone on Mars: the Stimson formation, Gale crater, Mars

Science.gov (United States)

Gupta, Sanjeev; Banham, Steven; Rubin, David; Watkins, Jessica; Sumner, Dawn; Grotzinger, John P.; Lewis, Kevin; Edgett, Kenneth S.; Edgar, Lauren; Stack, Kathryn; Day, McKenzie; Ewing, Ryan; Lapotre, Mathieu

2016-10-01

Since landing in 2012, the Mars Science Laboratory's (MSL) rover Curiosity has traversed the plains and foothills of Aeolis Mons (informally known as Mt. Sharp) investigating the environments preserved in the stratigraphic record of Gale crater. Recently, the Curiosity team has been investigating the Stimson formation, a sandstone exhibiting abundant crossbedding that drapes the underlying Murray formation mudstones. The contact between the Stimson and underlying Murray formation exhibits several meters relief over several 100 m hundred metres where encountered thus far. The Stimson is observed to onlap onto this contact, indicating that accumulating Stimson sandstones unconformably onlapped or buried local palaeotopography.Facies and architectural elements observed within the Stimson are interpreted to represent deposition within an ancient dune field. The Stimson formation is typically composed of decimeter-scale and meter-scale crossbedded sandstones, (exhibiting wind-ripple lamination and well rounded particles up to granule size). Architectural elements are visible in outcrops oriented perpendicular to the regional northwest dip. These consist of undulating surfaces parallel to the regional dip with observed lateral extents up to 30 m that truncate underlying cross-sets and commonly act as basal surfaces to overlying cross-sets. Undulating surfaces are interpreted possibly to be deflationary supersurfaces, which formed in response to deflation or dune-field stabilisation across a regional extent. Surfaces inclined relative to the regional dip ascend between supersurfaces towards the north east at an observed angle of 3-4°. These surfaces are interpreted to be dune bounding surfaces, which are preserved when dunes climb as a result of dune-field aggradation. Aggradation of the system during the duration of the dune field's existence possibly occurred as a response to episodic increases of sediment supply into the basin, allowing dunes to climb and preserving

Salt supply to and significance of asymmetric salt diapirs

DEFF Research Database (Denmark)

Koyi, H.; Burliga, S.; Chemia, Zurab

2012-01-01

Salt diapirs can be asymmetric both internally and externally reflecting their evolution history. As such, this asymmetry bear a significant amount of information about the differential loading (± lateral forces) and in turn the salt supply that have shaped the diapir. In two dimensions......, In this study we compare results of analogue and numerical models of diapirs with two natural salt diapris (Klodawa and Gorleben diapirs) to explain their salt supply and asymmetric evolution. In a NW-SE section, the Gorleben salt diapir possesses an asymmetric external geometry represented by a large...... southeastern overhang due to salt extrusion during Middle Cretaceous followed by its burial in Tertiary. This external asymmetry is also reflected in the internal configuration of the diapir which shows different rates of salt flow on the two halves of the structure. The asymmetric external and internal...

Catalytic Gasification of Coal using Eutectic Salt Mixtures

Energy Technology Data Exchange (ETDEWEB)

Atul Sheth; Pradeep Agrawal; Yaw D. Yeboah

1998-12-04

eutectic salt mixture consisting of Li- Na- and K- carbonates has the potential as gasification catalyst. To verify the literature reported, melting points for various compositions consisting of these three salts and the temperature range over which the mixture remained molten were determined in the lab. For mixtures with different concentrations of the three salts, the temperatures at which the mixtures were found to be in complete molten state were recorded. By increasing the amount of Li2CO3, the melting temperature range was reduced significantly. In the literature, the eutectic mixtures of Li- Na- and K-carbonates are claimed to have a lower activation energy than that of K2CO3 alone and they remain molten at a lower temperature than pure K2CO3. The slow increase in the gasification rates with eutectics reported in the literature is believed to be due to a gradual penetration of the coals and coal char particles by the molten and viscous catalyst phase. The even spreading of the salt phase seems to increase the overall carbon conversion rate. In the next reporting period, a number of eutectic salts and methods of their application on the coal will be identified and tested.

The analyzing stratum formation and sediment environment using TEM for finding sandstone type uranium deposits in Mahuangquan area

International Nuclear Information System (INIS)

Zhao Xigang; He Jianguo; Zhao Cuiping; Lou Hansheng

2010-01-01

Transient electromagnetic method (TEM) is used to detect deep geological information for insidious sandstone type uranium deposits in Mahuangquan area. TEM surveying data is processed to build the relation between resistance rate and different petrology, to ensure three large electronic strata, and to explain the space position of sediment center and alluvial fan. Combining with ore control factors of sandstone type uranium deposit, it can conclude that the slope area and the alluvial fan are the key areas for further exploration work. (authors)

Origin of sandstone-hosted uranium deposits, Frome Embayment, South Australia

International Nuclear Information System (INIS)

Sanford, R.F.

1985-01-01

The formation of sandstone-hosted uranium deposits in the Frome Embayment of South Australia is largely a result of tectonic events possibly as old as the Archean. Uranium deposits of several types and ages in the region demonstrate the importance of uranium enrichment in the source area. Mobile zones around the Archean terrane of the Gawler block have been the locus of intermittent tectonic activity from Early Proterozoic to recent time. Vein-type uranium deposits in basement source rocks are concentrated in these zones, because they favor deep crustal partial melting and ascent of Na-rich granitic magmas and hydrothermal solutions. Relatively stable areas bordered by mobile zones, are important for the formation of sandstone-hosted uranium deposits because they act as platforms for terrigenous sedimentation from the surrounding, uplifted, uranium-rich basement rocks. Wet, subtropical conditions prevailing at the time of uplift aided rapid erosion and subaerial deposition of channel sands with intermixed organic detritus. Later uplift accompanied by erosion of the recently deposited sands in the headwater area caused increased recharge of oxygenated uraniferous ground water, which led to the formation of geochemical-cell roll-front type deposits like those in the Wyoming basins. Subsequent arid conditions helped preserve the deposits. (author)

Investigation of the source of residual phthalate in sundried salt.

Science.gov (United States)

Kim, Jin Hyo; Lee, Jin Hwan; Kim, So-Young

2014-03-01

Phthalate contamination in sundried salt has recently garnered interest in Korea. Phthalate concentrations were investigated in Korean sundried salts, source waters, and aqueous extracts from polyvinyl chloride materials used in salt ponds. Preliminary screening results for phthalates in Korean sundried salts revealed that only di(2-ethylhexyl)phthalate (DEHP) was over the limit of detection, with an 8.6% detection rate, and the concentration ranged from below the limit of detection to 0.189 mg/kg. The tolerable daily intake contribution ratio of the salt was calculated to be only 0.001%. Residual phthalates were below 0.026 mg/liter in source water, and the aqueous extracted di-n-butylphthalate, benzylbutylphthalate, and DEHP, which are considered endocrine disruptors, were below 0.029 mg/kg as derived from the polyvinyl chloride materials in salt ponds. The transfer ratios of the six phthalates from seawater to sundried salts were investigated; transfer ratio was correlated with vapor pressure (r(2) = 0.9875). Thus, di-n-butylphthalate, benzylbutylphthalate, DEHP, and di-n-octylphthalate can be considered highly likely residual pollutants in some consumer salts.

Development of High-Temperature Transport System for Molten Salt in Pyroprocessing

International Nuclear Information System (INIS)

Lee, Sung Ho; Kim, In Tae; Park, Sung Bin

2014-01-01

-temperature molten salt transport technology were carried out. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate under a vacuum range of 100 mtorr to 10torr at 500 .deg. C. From the results of molten salt transport experiments under a vacuum range of 200 mtorr 10torr at 500 .deg. C via suction time, the mass flow rate via suction time is 1.54kg/min. To establish engineering- scale salt transport technology, a PRIDE salt transport system was designed and installed in an Ar cell, the second PRIDE facility for engineering-scale salt transport demonstration, and its performance was confirmed

Development of High-Temperature Transport System for Molten Salt in Pyroprocessing

Energy Technology Data Exchange (ETDEWEB)

Lee, Sung Ho; Kim, In Tae; Park, Sung Bin [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

2014-05-15

-temperature molten salt transport technology were carried out. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate under a vacuum range of 100 mtorr to 10torr at 500 .deg. C. From the results of molten salt transport experiments under a vacuum range of 200 mtorr 10torr at 500 .deg. C via suction time, the mass flow rate via suction time is 1.54kg/min. To establish engineering- scale salt transport technology, a PRIDE salt transport system was designed and installed in an Ar cell, the second PRIDE facility for engineering-scale salt transport demonstration, and its performance was confirmed.

Tectono-sedimentary evolution of Erlian basin since late mesozoic and sandstone-hosted uranium metallogenesis

International Nuclear Information System (INIS)

Wei Sanyuan; Qin Mingkuan; Li Yuexiang; He Zhongbo; Chen Anping; Shen Kefeng; Cao Jianying

2006-01-01

Various mineral resources in a basin are associated with its tectono-sedimentary evolution. Based on the analysis of the tectono-sedimentary evolution of Erlian basin, three evolutional stages of Erlian basin are classified, they are: the continental extensional down-faulting stage, the transitional stage from down-faulting to down-warping in Early Cretaceous, and slightly compressional differentiated uplifting-subsidence since Late Cretaceous. According to the mechanism of sandstone-hosted uranium metallogenesis it is suggested that the grey clastic rock series deposited at the stage of down-faulting down-warping transition must be the important target for uranium prospecting, and the differentiated uplifting-subsidence offers necessary conditions for sandstone-hosted uranium ore-formation. Then, types of uranium mineralization that could occur in Erlian basin are discussed, and uranium metallogenic model has been preliminarily summarized. (authors)

Sandstone columns of the 3rd Nile Cataract (Nubia, Northern Sudan)

Czech Academy of Sciences Publication Activity Database

Cílek, Václav; Adamovič, Jiří; Suková, L.

2015-01-01

Roč. 59, Supplement 1 (2015), s. 151-165 ISSN 0372-8854 Grant - others:Program interní podpory projektů mezinárodní spolupráce AV ČR(CZ) M100130902 Institutional support: RVO:67985831 Keywords : Nubian sandstone * columnar jointing * Voronoi fragmentation * 3rd Nile Cataract * Sudan Subject RIV: DB - Geology ; Mineralogy Impact factor: 1.103, year: 2015

The mineralogical composition of sandstone and its effect on sulphur dioxide deposition

Directory of Open Access Journals (Sweden)

Müller, Urs

2008-06-01

Full Text Available Air pollutants often accelerate stone deterioration in historical buildings and monuments in urban areas. The pollutants are themselves the products of fossil fuel combustion and intensive farming. While this trend seems to have been curbed by strict emission laws in the European Union, in most developing and emerging countries air pollution is an ongoing process due to increasing energy needs and vehicle traffic. Many factors condition natural stone behaviour with respect to gaseous pollutants. Two of the more prominent of such factors are the composition of the atmosphere and the type of stone. Due to their porosity, sandstones are particularly vulnerable to air pollutant attack. Many of the reactions between non-carbonaceous sandstones and these gases are not well understood, however. The present study aimed to acquire an understanding of the processes and factors governing sandstone behaviour when exposed to sulphur dioxide. Seven different sandstones from southern and eastern Germany were analyzed for the study. The binder composition of the stones varied significantly. They also exhibited completely different behaviour in connection with SO2 sorption. Interestingly, while the amount of SO2 deposited was unrelated to the specific surface area of the sandstones, this parameter was closely correlated to the iron oxide content. Iron oxide phases are believed to act as a catalyst in the oxidation of SO2 to SO3. The type and amount of clay mineral, in turn, was found to have no significant impact on initial SO2 deposition in sandstones.Los contaminantes atmosféricos son con frecuencia responsables de la aceleración de la degradación de la piedra en los edificios y monumentos históricos de las zonas urbanas. Los contaminantes en sí son productos de reacción procedentes de la combustión de los hidrocarburos y de la agricultura intensiva. Dentro de la Comunidad Europea, el avance parece haberse ralentizado mediante restrictivas leyes sobre

Geochemical interpretation of the Precambrian basement and overlying Cambrian sandstone on Bornholm, Denmark: Implications for the weathering history

DEFF Research Database (Denmark)

Zhou, Lingli; Friis, Henrik; Yang, Tian

2017-01-01

show a depletion of major elements in the following order: Na N Ca N Mg N Si; Al and Ti are immobile and stay constant; K shows sample dependent enrichment or depletion; Fe is slightly enriched. The Cambrian sandstone overlying the basement in the Borggård borehole, assigned to the Gadeby Member...... but lost most of the plagioclase. The LSF has a comparable weathering history (CIA = 63–73), but the plagioclase is better preserved (PIA = 65–78). The significant variation of weathering rates of plagioclase and K-feldspar in the basement granite and the provenance of sandstone from the Borggård borehole...... are likely due to the different permeability developed within the internal crystal structures, a Ca- rich plagioclase original composition of the plagioclase, and the occurrence of weathering in a very humid climate. K metasomatism occurred in the basement granite and sandstone in both the Borggård and the G...

Effect of drilling fluids on permeability of uranium sandstone. Report of Investigations/1984

International Nuclear Information System (INIS)

Ahlness, J.K.; Johnson, D.I.; Tweeton, D.R.

1984-01-01

The Bureau of Mines conducted laboratory and field experiments to determine the amount of permeability reduction in uranium sandstone after its exposure to different drilling fluids. Seven polymer and two bentonite fluids were laboratory-tested in their clean condition, and six polymer fluids were tested with simulated drill cuttings added. Sandstone cores cut from samples collected at an open pit uranium mine were the test medium. The clean fluid that resulted in the least permeability reduction was an hydroxyethyl cellulose polymer fluid. The greatest permeability reduction of the clean polymers came from a shale-inhibiting synthetic polymer. Six polymer fluids were tested with simulated drill cuttings added to represent field use. The least permeability reduction was obtained from a multi-polymer blend fluid. A field experiment was performed to compare how two polymer fluids affect formation permeability when used for drilling in situ uranium leaching wells

Strength curves for shales and sandstones under hydrostatic confining pressures

International Nuclear Information System (INIS)

Gupta, S.C.; Sikka, S.K.

1978-01-01

The experimental data for the effect of confining pressures on the fracture stress have been analysed for shales and sandstones. The normalized compressive strengths are found to lie in a narrow region so that Ohnaka's equation for crystalline rocks, can be fitted to the data. The fitted parameters are physically reasonable and indicate that the functional dependence of strength on porosity, strain rate and temperature is independent of the confining pressures. (author)

Geological and petrophysical characterization of the Ferron Sandstone for 3-D simulation of a fluvial-deltaic reservoir. Deliverable 2.5.4, Ferron Sandstone lithologic strip logs, Emergy & Sevier Counties, Utah: Volume I

Energy Technology Data Exchange (ETDEWEB)

Allison, M.L.

1995-12-08

Strip logs for 491 wells were produced from a digital subsurface database of lithologic descriptions of the Ferron Sandstone Member of the Mancos Shale. This subsurface database covers wells from the parts of Emery and Sevier Counties in central Utah that occur between Ferron Creek on the north and Last Chance Creek on the south. The lithologic descriptions were imported into a logging software application designed for the display of stratigraphic data. Strip logs were produced at a scale of one inch equals 20 feet. The strip logs were created as part of a study by the Utah Geological Survey to develop a comprehensive, interdisciplinary, and qualitative characterization of a fluvial-deltaic reservoir using the Ferron Sandstone as a surface analogue. The study was funded by the U.S. Department of Energy (DOE) under the Geoscience/Engineering Reservoir Characterization Program.

[Advance in the study of the powdered weathering profile of sandstone on China Yungang Grottoes based on VIS/NIR hyperspectral imaging].

Science.gov (United States)

Zhou, Xiao; Gao, Feng; Zhang, Ai-wu; Zhou, Ke-chao

2012-03-01

Yungang Grottoes were built in the mid-5th century A. D., and named as a UNESCO World Heritage site in 2001. Most of the grottoes were built on the feldspathic quartz sandstones. They were seriously damaged due to the environmental impact. The main form of the weathering is the powdered weathering. The weathering conditions are generally characterized by electrical sounding, penetration resistance, molecular spectroscopy, etc. However, although these methods can give good results about the weathering conditions for a specified sample or site, they are not suitable for providing a global profile of the weathering conditions. The present paper provides a method for effectively and roundly assessing the overall powdered weathering conditions of the Yungang Grottoes based on hyperspectral imaging. Powdered weathering could change the structure and granularity of the sandstone, and thus change the spectral reflectance of the sandstone surface. Based on the hyperspectral data collected from 400 nm to 1 000 nm and normalized by log residuals method, the powdered weathering conditions of the sandstones were classified into strong weathering and weak weathering. The weathering profile was also mapped in the Envi platform. The mapping images were verified using the measured hyperspectal data of the columns in front of the 9th and 10th grottoes as the examples. The mapping images were substantially fitted to the real observations, showing that hyperspectral imaging can be used to estimate the overall powdered weathering of the sandstones.

New discovery in study of remote sensing image characteristics at sandstone-type uranium deposits in China and its important significance

International Nuclear Information System (INIS)

Liu Dechang; Huang Xianfang; Ye Fawang

2004-01-01

Sandstone-type uranium deposit now is one of main targets in uranium prospecting in China. During the prospecting, the study is often emphasized on those ore-controlling factors such as the lithology and lithofacies of ore-hosting strata. While the ore-controlling factor of fault structure is usually neglected. By means of systematic research on remote sensing image features of sandstone-type uranium deposits, it is found that fault structure is always present at most main sandstone-type uranium ore districts. Based on above research achievements characteristics of ore-controlling fault and its ore-controlling role are analysed and a new metallogenetic model--'structural-geochemical barrier model' is put forward. Finally, the difference between the sturctural-geochemical barrier model and traditional interlayer oxidation zone front model is elaborated and its important significance is discussed. (authors)

Salt-assisted and salt-suppressed sol-gel transitions of methylcellulose in water.

Science.gov (United States)

Xu, Y; Wang, C; Tam, K C; Li, L

2004-02-03

The effects of various salts on the sol-gel transition of aqueous methylcellulose (MC) solutions have been studied systematically by means of a micro differential scanning calorimeter. It was found that the heating process was endothermic while the cooling process was exothermic for both MC solutions with and without salts. The addition of salts did not change the patterns of gelation and degelation of MC. However, the salts could shift the sol-gel transition and the gel-sol transition to lower or higher temperatures from a pure MC solution, depending on the salt type. These opposite effects were termed the salt-assisted and salt-suppressed sol-gel transitions. Either the salt-assisted transition or the salt-suppressed sol-gel transition was a function of salt concentration. In addition, each salt was found to have its own concentration limit for producing a stable aqueous solution of MC at a given concentration of MC, which was related to the anionic charge density of the salt. Cations were proved to have weaker effects than anions. The "salt-out strength", defined as the salt effect per mole of anion, was obtained for each anion studied. The thermodynamic mechanisms involved in the salt-assisted and salt-suppressed sol-gel transitions are discussed.

Interpretation of massive sandstones in ephemeral fluvial settings: A case study from the Upper Candelária Sequence (Upper Triassic, Paraná Basin, Brazil)

Science.gov (United States)

Horn, Bruno Ludovico Dihl; Goldberg, Karin; Schultz, Cesar Leandro

2018-01-01

Ephemeral rivers display a wide range of upper- and lower-flow regime structures due to great flow-velocity changes during the floods. The development of flow structures in these setting is yet to be understood, especially in the formation of thick, massive sandstones. The Upper Triassic of Southern Gondwana was marked by a climate with great seasonal changes, yet there is no description of river systems with seasonal characteristics in Southern Gondwana. This work aims to characterize a ephemeral alluvial system of the Upper Triassic of the Paraná Basin. The characteristics of the deposits are discussed in terms of depositional processes through comparison with similar deposits from literature, flow characteristics and depositional signatures compared to flume experiments. The alluvial system is divided in four facies associations: (1) channels with wanning fill, characterized by low width/thickness ratio, tabular bodies, scour-and-fill structures with upper- and lower-flow regime bedforms; (2) channels with massive fill, characterized by low w/t ratio, sheet-like bodies, scour-and-fill structures with massive sandstones; (3) proximal sheetfloods, characterized by moderate w/t ratio, sheet-like bodies with upper- and lower-flow regime bedforms and (4) distal sheetfloods, characterized by high w/t ratio, sheet-like bodies with lower-flow regime bedforms. Evidence for the seasonal reactivation of the riverine system includes the scarcity of well-developed macroforms and presence of in-channel mudstones, thick intraformational conglomerates, and the occurrence of well- and poorly-preserved vertebrate bones in the same beds. The predominantly massive sandstones indicate deposition from a hyperconcentrated flow during abrupt changes in flow speed, caused by de-confinement or channel avulsion, whereas turbulent portions of the flow formed the upper- and lower-flow regime bedforms after the deposition of the massive layers. The upper portion of the Candelária Sequence

New geochronologic and stratigraphic evidence confirms the paleocene age of the dinosaur-bearing ojo alamo sandstone and animas formation in the San Juan Basin, New Mexico and Colorado

Science.gov (United States)

Fassett, J.E.

2009-01-01

Dinosaur fossils are present in the Paleocene Ojo Alamo Sandstone and Animas Formation in the San Juan Basin, New Mexico, and Colorado. Evidence for the Paleo-cene age of the Ojo Alamo Sandstone includes palynologic and paleomagnetic data. Palynologic data indicate that the entire Ojo Alamo Sandstone, including the lower dinosaur-bearing part, is Paleocene in age. All of the palynomorph-productive rock samples collected from the Ojo Alamo Sandstone at multiple localities lacked Creta-ceous index palynomorphs (except for rare, reworked specimens) and produced Paleocene index palynomorphs. Paleocene palynomorphs have been identified strati-graphically below dinosaur fossils at two separate localities in the Ojo Alamo Sand-stone in the central and southern parts of the basin. The Animas Formation in the Colorado part of the basin also contains dinosaur fossils, and its Paleocene age has been established based on fossil leaves and palynology. Magnetostratigraphy provides independent evidence for the Paleocene age of the Ojo Alamo Sandstone and its dinosaur-bearing beds. Normal-polarity magnetochron C29n (early Paleocene) has been identified in the Ojo Alamo Sandstone at six localities in the southern part of the San Juan Basin. An assemblage of 34 skeletal elements from a single hadrosaur, found in the Ojo Alamo Sandstone in the southern San Juan Basin, provided conclusive evidence that this assemblage could not have been reworked from underlying Cretaceous strata. In addition, geochemical studies of 15 vertebrate bones from the Paleocene Ojo Alamo Sandstone and 15 bone samples from the underlying Kirtland Formation of Late Creta-ceous (Campanian) age show that each sample suite contained distinctly different abundances of uranium and rare-earth elements, indicating that the bones were miner-alized in place soon after burial, and that none of the Paleocene dinosaur bones ana-lyzed had been reworked. ?? U.S. Geological Survey, Public Domain April 2009.

Salt damage of stone, plaster and painted layers at a medieval church, South-Hungary

Science.gov (United States)

Török, Ákos; Galambos, Éva

2016-04-01

The Chapel of Pécsvárad is one of the best preserved and oldest medieval stone monument in South Hungary. It dates back to the 11th century. The interior of the chapel is decorated with wall paintings, which are later and probably originating from the late 12th century. The wall painting is partly preserved and it is located on an interior stone wall of the chapel facing to the East. The wall painting shows various forms of damage from salt efflorescence to chipping. The current research provides information on the in situ and laboratory analyses of salts, plasters, pigments and stone material suggesting mechanisms of decay that lead to partial loss of the painting. Both on site techniques and laboratory analyses were performed. Imaging techniques such as UV luminescence and IR thermography were used to identify the moist and salt covered zones on the wall surface. Portable moisture meter were also applied to map the wet zones in the interior and also at the external part of the chapel. Schmidt hammer and Duroscop were used for testing the surface strength of stone. Laboratory tests were focused on mineralogical and chemical compositional analyses. Small samples of stone, mortar, plaster and pigments were tested by optical microscopy, SEM-EDX, XRD and Thermogravimetric analyses. According to our tests the chapel was predominantly made of porous limestone and sandstone. Laboratory analyses proved that the major salt responsible for the damage of external walls are gypsum and halite, while in the interior part higher amount of halite and significant amount of sodium-nitrate were found besides gypsum. The painted layers are on Byzantine-type of plaster with organic compounds (plant fragments) and with a substrate layer rich in calcium carbonate. The identified pigments are dominantly earth pigments such as iron-oxide containing red and yellow (ochre) and green earth. A unique preservation of ultramarine blue in Hungary was found on the wall painting. The partial

Where Does Road Salt Go - a Static Salt Model

Science.gov (United States)

Yu, C. W.; Liu, F.; Moriarty, V. W.

2017-12-01

Each winter, more than 15 million tons of road salt is applied in the United States for the de-icing purpose. Considerable amount of chloride in road salt flows into streams/drainage systems with the snow melt runoff and spring storms, and eventually goes into ecologically sensitive low-lying areas in the watershed, such as ponds and lakes. In many watersheds in the northern part of US, the chloride level in the water body has increased significantly in the past decades, and continues an upward trend. The environmental and ecological impact of the elevated chloride level can no longer be ignored. However although there are many studies on the biological impact of elevated chloride levels, there are few investigations on how the spatially distributed road salt application affects various parts of the watershed. In this presentation, we propose a static road salt model as a first-order metric to address spacial distribution of salt loading. Derived from the Topological Wetness Index (TWI) in many hydrological models, this static salt model provides a spatial impact as- sessment of road salt applications. To demonstrate the effectiveness of the static model, National Elevation Dataset (NED) of ten-meter resolution of Lake George watershed in New York State is used to generate the TWI, which is used to compute a spatially dis- tributed "salt-loading coefficient" of the whole watershed. Spatially varying salt applica- tion rate is then aggregated, using the salt-loading coefficients as weights, to provide salt loading assessments of streams in the watershed. Time-aggregated data from five CTD (conductivity-temperature-depth) sensors in selected streams are used for calibration. The model outputs and the sensor data demonstrate a strong linear correlation, with the R value of 0.97. The investigation shows that the static modeling approach may provide an effective method for the understanding the input and transport of road salt to within watersheds.

Extraction and LC determination of lysine clonixinate salt in water/oil microemulsions.

Science.gov (United States)

Pineros, I; Ballesteros, P; Lastres, J L

2002-02-01

A new reversed-phase high performance liquid chromatography method has been developed and validated for the quantitative determination of lysine clonixinate salt in water/oil microemulsions. The mobile phase was acetonitrile-buffer phosphate pH 3.3. Detection was UV absorbance at 252 nm. The precision and accurately of the method were excellent. The established linearity range was 5-60 microg ml(-1) (r(2)=0.999). Microemulsions samples were dispersed with chloroform and extracted lysine clonixinate salt with water. This easy method employing chloroformic extraction has been done three times. The recovery of lysine clonixinate salt from spiked placebo and microemulsion were >90% over the linear range.

Radionuclide concentrations in salt pans in the coastal area of Cox's Bazar, Bangladesh

International Nuclear Information System (INIS)

Alam, M.N.; Chowdhury, M.I.; Zafar, M.; Kamal, M.; Ghose, S.; Kamal, A.H.M.

1998-01-01

Radionuclide concentrations of 226 Ra, 232 Th, 137 Cs, 134 Cs and 40 K in samples of water, soil and salt from three gradients of salt pans (reservoir, condenser and crystalliser) in the coastal area of Cox's Bazar, Bangladesh and in samples of refined salts were measured using γ-spectrometry. The activities of 226 Ra in the salt pans were found to be in the range 3·18±1·02 Bq l -1 in water to 25·17±5·76 Bq kg -1 in soil; 232 Th activities were 2·01±0·89 Bq l -1 in water to 42·33±2·54 Bq kg -1 in soil, and 40 K activities ranged from 109·60±27·77 Bq l -1 in water to 651·89±65·89 Bq kg -1 in soil. No 137 Cs or 134 Cs was found in soil, salt and water from the salt pans investigated. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

Early Cretaceous marine sediments of the Lower Saxony Basin. The Gildehaus Sandstone

Energy Technology Data Exchange (ETDEWEB)

Dellepiane, S.; Weiel, D. [Wintershall Holding GmbH, Barnstorf (Germany); Gerwert, D.; Mutterlose, J. [Bochum Univ. (Germany). Inst. fuer Geologie, Mineralogie und Geophysik

2013-08-01

During the Early Cretaceous (Berriasian - Aptian) the Lower Saxony Basin (LSB) formed the southernmost extension of the North Sea Basin. Sedimentation patterns of the LSB were controlled by divergent dextral shear movement causing differential subsidence related to early rifting in the North Sea. Up to 2000m of fine grained mudstones accumulated in the basin centre, while marginal marine, coarser grained siliciclastics were deposited along the western and southern margins of the LSB. The western marginal facies, outcropping along the Dutch-German border, is characterised by shallow marine sandstones of Valanginian - Hauterivian age. These units, which are separated by clay rich intervals, include the Bentheim Sdst., the Dichotomites Sdst., the Grenz Sdst., the Noricum Sdst. and the Gildehaus Sdst. These sandstones form a series of overall backstepping units, controlled by a main transgressive trend. Economically important are the Bentheim Sdst. and the Gildehaus Sdst., with a long oil producing history. The Bentheim Sdst. (early Valanginian) has been interpreted as an overall retrograding unit related to an incised valley infill with material mainly coming from the South. Tidal processes dominated the deposition of the Bentheim Sdst. The origin and genesis of the Gildehaus Sdst. (mid Hauterivian) is, however, less well understood. Here we present data from two wells drilled to the Gildehaus Sdst. (Emlichheim oil field) which provide evidence for a two fold subdivision of the unit. A well sorted massive quartz sandstone is followed by an interval composed of reworked coarse clastics of massflow origin. Micropalaeontological evidence suggests a fully marine, hemi-pelagic origin of the mud dominated matrix throughout the Gildehaus Sdst. These findings indicate a depositional environment quite different from that of the Bentheim Sdst. Short termed pulses of substantial input of clastic material from two different sources in the West to Southwest punctuated the overall

Origin of salt giants in abyssal serpentinite systems

Science.gov (United States)

Scribano, Vittorio; Carbone, Serafina; Manuella, Fabio C.; Hovland, Martin; Rueslåtten, Håkon; Johnsen, Hans-K.

2017-10-01

Worldwide marine salt deposits ranging over the entire geological record are generally considered climate-related evaporites, derived from the precipitation of salts (mainly chlorides and sulfates) from saturated solutions driven by solar evaporation of seawater. This explanation may be realistic for a salt thickness ≤100 m, being therefore inadequate for thicker (>1 km) deposits. Moreover, sub-seafloor salt deposits in deep marine basins are difficult to reconcile with a surface evaporation model. Marine geology reports on abyssal serpentinite systems provide an alternative explanation for some salt deposits. Seawater-driven serpentinization consumes water and increases the salinity of the associated aqueous brines. Brines can be trapped in fractures and cavities in serpentinites and the surrounding `country' rocks. Successive thermal dehydration of buried serpentinites can mobilize and accumulate the brines, forming highly saline hydrothermal solutions. These can migrate upwards and erupt onto the seafloor as saline geysers, which may form salt-saturated water pools, as are currently observed in numerous deeps in the Red Sea and elsewhere. The drainage of deep-seated saline brines to seafloor may be a long-lasting, effective process, mainly occurring in areas characterized by strong tectonic stresses and/or igneous intrusions. Alternatively, brines could be slowly expelled from fractured serpentinites by buoyancy gradients and, hence, separated salts/brines could intrude vertically into surrounding rocks, forming salt diapirs. Serpentinization is an ubiquitous, exothermic, long-lasting process which can modify large volumes of oceanic lithosphere over geological times. Therefore, buried salt deposits in many areas of the world can be reasonably related to serpentinites.

Reservoir heterogeneity in carboniferous sandstone of the Black Warrior basin. Final report

Energy Technology Data Exchange (ETDEWEB)

Kugler, R.L.; Pashin, J.C.; Carroll, R.E.; Irvin, G.D.; Moore, H.E.

1994-06-01

Although oil production in the Black Warrior basin of Alabama is declining, additional oil may be produced through improved recovery strategies, such as waterflooding, chemical injection, strategic well placement, and infill drilling. High-quality characterization of reservoirs in the Black Warrior basin is necessary to utilize advanced technology to recover additional oil and to avoid premature abandonment of fields. This report documents controls on the distribution and producibility of oil from heterogeneous Carboniferous reservoirs in the Black Warrior basin of Alabama. The first part of the report summarizes the structural and depositional evolution of the Black Warrior basin and establishes the geochemical characteristics of hydrocarbon source rocks and oil in the basin. This second part characterizes facies heterogeneity and petrologic and petrophysical properties of Carter and Millerella sandstone reservoirs. This is followed by a summary of oil production in the Black Warrior basin and an evaluation of seven improved-recovery projects in Alabama. In the final part, controls on the producibility of oil from sandstone reservoirs are discussed in terms of a scale-dependent heterogeneity classification.

Reservoir heterogeneity in Carboniferous sandstone of the Black Warrior basin. Final report

Energy Technology Data Exchange (ETDEWEB)

Kugler, R.L.; Pashin, J.C.; Carroll, R.E.; Irvin, G.D.; Moore, H.E.

1994-04-01

Although oil production in the Black Warrior basin of Alabama is declining, additional oil may be produced through improved recovery strategies, such as waterflooding, chemical injection, strategic well placement, and infill drilling. High-quality characterization of reservoirs in the Black Warrior basin is necessary to utilize advanced technology to recover additional oil and to avoid premature abandonment of fields. This report documents controls on the distribution and producibility of oil from heterogeneous Carboniferous reservoirs in the Black Warrior basin of Alabama. The first part of the report summarizes the structural and depositional evolution of the Black Warrior basin and establishes the geochemical characteristics of hydrocarbon source rocks and oil in the basin. This second part characterizes facies heterogeneity and petrologic and petrophysical properties of Carter and Millerella sandstone reservoirs. This is followed by a summary of oil production in the Black Warrior basin and an evaluation of seven improved-recovery projects in Alabama. In the final part, controls on the producibility of oil from sandstone reservoirs are discussed in terms of a scale-dependent heterogeneity classification.

EFFECT OF SANDSTONE ANISOTROPY ON ITS HEAT AND MOISTURE TRANSPORT PROPERTIES

Directory of Open Access Journals (Sweden)

Jan Fořt

2015-09-01

Full Text Available Each type of natural stone has its own geological history, formation conditions, different chemical and mineralogical composition, which influence its possible anisotropy. Knowledge in the natural stones anisotropy represents crucial information for the process of stone quarrying, its correct usage and arrangement in building applications. Because of anisotropy, many natural stones exhibit different heat and moisture transport properties in various directions. The main goal of this study is to analyse several anisotropy indices and their effect on heat transport and capillary absorption. For the experimental determination of the anisotropy effect, five types of sandstone coming from different operating quarries in the Czech Republic are chosen. These materials are often used for restoration of culture heritage monuments as well as for other building applications where they are used as facing slabs, facade panels, decoration stones, paving, etc. For basic characterization of studied materials, determination of their bulk density, matrix density and total open porosity is done. Chemical composition of particular sandstones is analysed by X-Ray Fluorescence. Anisotropy is examined by the non-destructive measurement of velocity of ultrasonic wave propagation. On the basis of ultrasound testing data, the relative anisotropy, total anisotropy and anisotropy coefficient are calculated. Then, the measurement of thermal conductivity and thermal diffusivity in various directions of samples orientation is carried out. The obtained results reveal significant differences between the parameters characterizing the heat transport in various directions, whereas these values are in accordance with the indices of anisotropy. Capillary water transport is described by water absorption coefficient measured using a sorption experiment, which is performed for distilled water and 1M NaCl water solution.  The measured data confirm the effect of anisotropy which is

Uranium leaching from phosphatic sandstone and shale of Qatrani using citrate as a new leaching reagent

International Nuclear Information System (INIS)

Hussein, E.M.

1997-01-01

Uranium is found in Qatrani area (Southwest of Cairo and North of lake Qarun) in various forms in sedimentary rocks. Two important ore materials have been chosen for studying the recovery of their uranium contents namely; the phosphatic sandstone and the carbonaceous shale. The main emphasis in this thesis is the choice of an acid that would selectively leach uranium from thesis ores while leaving calcium phosphate and carbonate minerals minerals almost completely intact. Citric acid was indeed found advantageous due primarily to its strong ability to form stable complexes with uranium over a wide range of PH values beside the possibility of controlling thr solubility of calcium-bearing compounds by adding calcium citrate. The latter is actually characterized by its ability to exist in an unionized or associated from in citric acid solutions. From the general leaching characteristics of both uranium and P 2 O 5 from Qatrani phosphatic sandstone by citric acid, it was found that uranium could be completely leached beside the possibility of realizing a differential leaching percent values vs P 2 O 5 which is generally of limited solubility. Such a low solubility of P 2 O 5 has even been completely inhibited by providing calcium citrate to the citric acid solutions in amounts sufficient to exist in an optimum ionized non-associated state. Such a provision would render the solution unable to carry any further calcium ions thus the breakdown of the phosphate mineral was hindered while uranium has completely been selectively

Chemical and physical hydrogeology of coal, mixed coal-sandstone and sandstone aquifers from coal-bearing formations in the Alberta Plains region, Alberta

International Nuclear Information System (INIS)

Lemay, T.G.

2003-09-01

With the decline of conventional oil and gas reserves, natural gas from coal (NGC) is an unconventional gas resource that is receiving much attention from petroleum exploration and development companies in Alberta. Although the volume of the NGC resource is large, there are many challenges facing NGC development in Alberta, including technical and economic issues, land access, water disposal, water diversion and access to information. Exploration and development of NGC in Alberta is relatively new, therefore there is little baseline data on which to base regulatory strategies. Some important information gaps have been filled through water well sampling in coal, mixed coal-sandstone and sandstone aquifers throughout Alberta. Analyses focused on the chemical and physical characteristics aquifers in use for domestic or agricultural purposes. Aquifer depths were generally less than 100 metres. Samples collected from Paskapoo-Scollard Formation, Horseshoe Canyon Formation and Belly River Group aquifers exceed Canadian water quality guideline values with respect to pH, sodium, manganese, chloride, chromium, sulphate, phenols and total dissolved solids. Pump tests conducted within the aquifers indicate that the groundwater flow is complicated. Water quality will have to be carefully managed to ensure responsible disposal practices are followed. Future studies will focus on understanding the chemical and biological process that occur within the aquifers and the possible link between these processes and gas generation. Mitigation and disposal strategies for produced water will also be developed along with exploration strategies using information obtained from hydrogeologic studies. 254 refs., 182 tabs., 100 figs., 3 appendices

Wettability Alteration of Sandstone and Carbonate Rocks by Using ZnO Nanoparticles in Heavy Oil Reservoirs

Directory of Open Access Journals (Sweden)

Masoumeh Tajmiri

2015-10-01

Full Text Available Efforts to enhance oil recovery through wettability alteration by nanoparticles have been attracted in recent years. However, many basic questions have been ambiguous up until now. Nanoparticles penetrate into pore volume of porous media, stick on the core surface, and by creating homogeneous water-wet area, cause to alter wettability. This work introduces the new concept of adding ZnO nanoparticles by an experimental work on wettability alteration and oil recovery through spontaneous imbibition mechanism. Laboratory tests were conducted in two experimental steps on four cylindrical core samples (three sandstones and one carbonate taken from a real Iranian heavy oil reservoir in Amott cell. In the first step, the core samples were saturated by crude oil. Next, the core samples were flooded with nanoparticles and saturated by crude oil for about two weeks. Then, the core samples were immersed in distilled water and the amount of recovery was monitored during 30 days for both steps. The experimental results showed that oil recovery for three sandstone cores changed from 20.74, 4.3, and 3.5% of original oil in place (OOIP in the absence of nanoparticles to 36.2, 17.57, and 20.68% of OOIP when nanoparticles were added respectively. Moreover, for the carbonate core, the recovery changed from zero to 8.89% of OOIP by adding nanoparticles. By the investigation of relative permeability curves, it was found that by adding ZnO nanoparticles, the crossover-point of curves shifted to the right for both sandstone and carbonate cores, which meant wettability was altered to water- wet. This study, for the first time, illustrated the remarkable role of ZnO nanoparticles in wettability alteration toward more water-wet for both sandstone and carbonate cores and enhancing oil recovery.

Molten salt fueled reactors with a fast salt draining

International Nuclear Information System (INIS)

Ventre, Edmond; Blum, J.M.

1976-01-01

This invention relates to a molten salt nuclear reactor which comprises a new arrangement for shutting it down in complete safety. This nuclear reactor has a molten salt primary circuit comprising, in particular, the core of this reactor. It includes a leak tight vessel the capacity of which is appreciably greater than that of the molten salt volume of the circuit and placed so that the level of the molten salt, when all the molten salt of the circuit is contained in this vessel, is less than that of the base of the core. There are facilities for establishing and maintaining an inert gas pressure in the vessel above the molten salt, for releasing the compressed gas and for connecting the vessel to the primary circuit entering this vessel at a lower level than that of the molten salt and enabling molten salt to enter or leave the vessel according to the pressure of the inert gas. The particular advantage of this reactor is that it can be shut down safely since the draining of the primary circuit no longer results from a 'positive action' but from the suppression of an arrangement essential for the operation of the reactor consisting of the build-up of the said inert gas pressure in the said vessel [fr

Rock Physics and Petrographic Parameters Relationship Within Siliciclastic Rocks: Quartz Sandstone Outcrop Study Case

Science.gov (United States)

Syafriyono, S.; Caesario, D.; Swastika, A.; Adlan, Q.; Syafri, I.; Abdurrokhim, A.; Mardiana, U.; Mohamad, F.; Alfadli, M. K.; Sari, V. M.

2018-03-01

Rock physical parameters value (Vp and Vs) is one of fundamental aspects in reservoir characterization as a tool to detect rock heterogenity. Its response is depend on several reservoir conditions such as lithology, pressure and reservoir fluids. The value of Vp and Vs is controlled by grain contact and contact stiffness, a function of clay mineral content and porosity also affected by mineral composition. The study about Vp and Vs response within sandstone and its relationship with petrographic parameters has become important to define anisotrophy of reservoir characteristics distribution and could give a better understanding about local diagenesis that influence clastic reservoir properties. Petrographic analysis and Vp-Vs calculation was carried out to 12 core sample which is obtained by hand-drilling of the outcrop in Sukabumi area, West Java as a part of Bayah Formation. Data processing and interpretation of sedimentary vertical succession showing that this outcrop comprises of 3 major sandstone layers indicating fluvial depositional environment. As stated before, there are 4 petrographic parameters (sorting, roundness, clay mineral content, and grain contact) which are responsible to the differences of shear wave and compressional wave value in this outcrop. Lithology with poor-sorted and well- roundness has Vp value lower than well-sorted and poor-roundness (sub-angular) grain. For the sample with high clay content, Vp value is ranging from 1681 to 2000 m/s and could be getting high until 2190 to 2714 m/s in low clay content sample even though the presence of clay minerals cannot be defined neither as matrix nor cement. The whole sample have suture grain contact indicating telogenesis regime whereas facies has no relationship with Vp and Vs value because of the different type of facies show similar petrographic parameters after diagenesis.

Salt content in canteen and fast food meals in Denmark

DEFF Research Database (Denmark)

Rasmussen, Lone Banke; Lassen, Anne Dahl; Hansen, Kirsten

2010-01-01

Background: A high salt (NaCl) intake is associated with high blood pressure, and knowledge of salt content in food and meals is important, if the salt intake has to be decreased in the general population. Objective: To determine the salt content in worksite canteen meals and fast food. Design...... fast food samples were collected from 52 retail places representing both city (Aarhus) and provincial towns. The canteen meals and fast food samples were analyzed for chloride by potentiometric titration with silver nitrate solution, and the salt content was estimated. Results: The salt content...... in lunch meals in worksite canteens were 3.891.8 g per meal and 14.795.1 g per 10 MJ for men (n 109), and 2.891.2 g per meal and 14.496.2 g per 10 MJ for women (n 71). Salt content in fast food ranged from 11.892.5 g per 10 MJ (burgers) to 16.394.4 g per 10 MJ (sausages) with a mean content of 13.893.8 g...

Depositional and diagenetic variability within the Cambrian Mount Simon Sandstone: Implications for carbon dioxide sequestration

Science.gov (United States)

Bowen, B.B.; Ochoa, R.I.; Wilkens, N.D.; Brophy, J.; Lovell, T.R.; Fischietto, N.; Medina, C.R.; Rupp, J.A.

2011-01-01

The Cambrian Mount Simon Sandstone is the major target reservoir for ongoing geologic carbon dioxide (CO2) sequestration demonstrations throughout the midwest United States. The potential CO2 reservoir capacity, reactivity, and ultimate fate of injected CO2 depend on textural and compositional properties determined by depositional and diagenetic histories that vary vertically and laterally across the formation. Effective and efficient prediction and use of the available pore space requires detailed knowledge of the depositional and diagenetic textures and mineralogy, how these variables control the petrophysical character of the reservoir, and how they vary spatially. Here, we summarize the reservoir characteristics of the Mount Simon Sandstone based on examination of geophysical logs, cores, cuttings, and analysis of more than 150 thin sections. These samples represent different parts of the formation and depth ranges of more than 9000 ft (>2743 m) across the Illinois Basin and surrounding areas. This work demonstrates that overall reservoir quality and, specifically, porosity do not exhibit a simple relationship with depth, but vary both laterally and with depth because of changes in the primary depositional facies, framework composition (i.e., feldspar concentration), and diverse diagenetic modifications. Diagenetic processes that have been significant in modifying the reservoir include formation of iron oxide grain coatings, chemical compaction, feldspar precipitation and dissolution, multiple generations of quartz overgrowth cementation, clay mineral precipitation, and iron oxide cementation. These variables provide important inputs for calculating CO2 capacity potential, modeling reactivity, and are also an important baseline for comparisons after CO2 injection. Copyright ??2011. The American Association of Petroleum Geologists/Division of Environmental Geosciences. All rights reserved.

Pore Structure Model for Predicting Elastic Wavespeeds in Fluid-Saturated Sandstones

Science.gov (United States)

Zimmerman, R. W.; David, E. C.

2011-12-01

During hydrostatic compression, in the elastic regime, ultrasonic P and S wave velocities measured on rock cores generally increase with pressure, and reach asymptotic values at high pressures. The pressure dependence of seismic velocities is generally thought to be due to the closure of compliant cracks, in which case the high-pressure velocities must reflect only the influence of the non-closable, equant "pores". Assuming that pores can be represented by spheroids, we can relate the elastic properties to the pore structure using an effective medium theory. Moreover, the closure pressure of a thin crack-like pore is directly proportional to its aspect ratio. Hence, our first aim is to use the pressure dependence of seismic velocities to invert the aspect ratio distribution. We use a simple analytical algorithm developed by Zimmerman (Compressibility of Sandstones, 1991), which can be used for any effective medium theory. Previous works have used overly restrictive assumptions, such as assuming that the stiff pores are spherical, or that the interactions between pores can be neglected. Here, we assume that the rock contains an exponential distribution of crack aspect ratios, and one family of stiff pores having an aspect ratio lying somewhere between 0.01 and 1. We develop our model in two versions, using the Differential Scheme, and the Mori-Tanaka scheme. The inversion is done using data obtained in dry experiments, since pore fluids have a strong effect on velocities and tend to mask the effect of the pore geometry. This avoids complicated joint inversion of dry and wet data, such as done by Cheng and Toksoz (JGR, 1979). Our results show that for many sets of data on sandstones, we can fit very well the dry velocities. Our second aim is to predict the saturated velocities from our pore structure model, noting that at a given differential stress, the pore structure should be the same as for a dry test. Our results show that the Biot-Gassmann predictions always

Molten salt oxidation of organic hazardous waste with high salt content.

Science.gov (United States)

Lin, Chengqian; Chi, Yong; Jin, Yuqi; Jiang, Xuguang; Buekens, Alfons; Zhang, Qi; Chen, Jian

2018-02-01

Organic hazardous waste often contains some salt, owing to the widespread use of alkali salts during industrial manufacturing processes. These salts cause complications during the treatment of this type of waste. Molten salt oxidation is a flameless, robust thermal process, with inherent capability of destroying the organic constituents of wastes, while retaining the inorganic ingredients in the molten salt. In the present study, molten salt oxidation is employed for treating a typical organic hazardous waste with a high content of alkali salts. The hazardous waste derives from the production of thiotriazinone. Molten salt oxidation experiments have been conducted using a lab-scale molten salt oxidation reactor, and the emissions of CO, NO, SO 2 , HCl and dioxins are studied. Impacts are investigated from the composition of the molten salts, the types of feeding tube, the temperature of molten carbonates and the air factor. Results show that the waste can be oxidised effectively in a molten salt bath. Temperature of molten carbonates plays the most important role. With the temperature rising from 600 °C to 750 °C, the oxidation efficiency increases from 91.1% to 98.3%. Compared with the temperature, air factor has but a minor effect, as well as the composition of the molten salts and the type of feeding tube. The molten carbonates retain chlorine with an efficiency higher than 99.9% and the emissions of dioxins are below 8 pg TEQ g -1 sample. The present study shows that molten salt oxidation is a promising alternative for the disposal of organic hazardous wastes containing a high salt content.

Experimental Investigation of Crack Extension Patterns in Hydraulic Fracturing with Shale, Sandstone and Granite Cores

Directory of Open Access Journals (Sweden)

Jianming He

2016-12-01

Full Text Available Hydraulic fracturing is an important method of reservoir stimulation in the exploitation of geothermal resources, and conventional and unconventional oil and gas resources. In this article, hydraulic fracturing experiments with shale, sandstone cores (from southern Sichuan Basin, and granite cores (from Inner Mongolia were conducted to investigate the different hydraulic fracture extension patterns in these three reservoir rocks. The different reactions between reservoir lithology and pump pressure can be reflected by the pump pressure monitoring curves of hydraulic fracture experiments. An X-ray computer tomography (CT scanner was employed to obtain the spatial distribution of hydraulic fractures in fractured shale, sandstone, and granite cores. From the microscopic and macroscopic observation of hydraulic fractures, different extension patterns of the hydraulic fracture can be analyzed. In fractured sandstone, symmetrical hydraulic fracture morphology could be formed, while some micro cracks were also induced near the injection hole. Although the macroscopic cracks in fractured granite cores are barely observed by naked eye, the results of X-ray CT scanning obviously show the morphology of hydraulic fractures. It is indicated that the typical bedding planes well developed in shale formation play an important role in the propagation of hydraulic fractures in shale cores. The results also demonstrated that heterogeneity influenced the pathway of the hydraulic fracture in granite cores.

Characterization of the Qishn sandstone reservoir, Masila Basin-Yemen, using an integrated petrophysical and seismic structural approach

Science.gov (United States)

Lashin, Aref; Marta, Ebrahim Bin; Khamis, Mohamed

2016-03-01

This study presents an integrated petrophysical and seismic structural analysis that is carried out to evaluate the reservoir properties of Qishn sandstone as well as the entrapment style of the hydrocarbons at Sharyoof field, Sayun-Masila Basin that is located at the east central of Yemen. The reservoir rocks are dominated by clean porous and permeable sandstones zones usually intercalated with some clay stone interbeds. As identified from well logs, Qishn sandstone is classified into subunits (S1A, S1B, S1C and S2) with different reservoir characteristics and hydrocarbon potentiality. A number of qualitative and quantitative well logging analyses are used to characterize the different subunits of the Qishn reservoir and identify its hydrocarbon potentiality. Dia-porosity, M-N, Pickett, Buckles plots, petrophysical analogs and lateral distribution maps are used in the analysis. Shale volume, lithology, porosity, and fluid saturation are among the most important deduced parameters. The analysis revealed that S1A and S1C are the main hydrocarbon-bearing units. More specifically, S1A unit is the best, as it attains the most prolific hydrocarbon saturations (oil saturation "SH″ up to 65) and reservoir characteristics. An average petrophysical ranges of 4-21%, 16-23%, 11-19%, 0-65%, are detected for S1A unit, regarding shale volume, total and effective porosity, and hydrocarbon saturation, respectively. Meanwhile, S1B unit exhibits less reservoir characteristics (Vsh>30%, ϕEff<15% and SH< 15%). The lateral distribution maps revealed that most of the hydrocarbons (for S1A and S1C units) are indicated at the middle of the study area as NE-SW oriented closures. The analysis and interpretation of seismic data had clarified that the structure of study area is represented by a big middle horst bounded by a group of step-like normal faults at the extreme boundaries (faulted anticlinal-structure). In conclusion, the entrapment of the encountered hydrocarbon at Sharyoof oil

Relation between electric properties and water saturation for hematitic sandstone with frequency

Directory of Open Access Journals (Sweden)

M. M. Gomaa

2008-06-01

Full Text Available This paper focuses on the effect of water saturation on A. C. electrical conductivity and dielectric constant of fully and partially saturated hematitic sandstone sample (Aswan area, Egypt. The saturation of the sample was changed from partial to full saturation. Complex resistivity measurements at room temperature (~16°C, were performed in the frequency range from 0.1 Hz to 100 KHz. Experimental electrical spectra indicate, generally, that the electrical conductivity and dielectric constant vary strongly with water saturations and frequency. The low frequency electrical conductivity and dielectric constant are mainly controlled by surface conduction and polarization of the electrical double layer. The behaviour of the electrical conductivity and dielectric constant, with increasing water content, were argued to the orientational polarization of bound water for very low saturations, displacement of the excess surface charges for relatively low saturations, and free exchange of excess ions in double layer with the bulk electrolyte and generation of transient diffusion potentials which lag behind the applied field for high saturations.

Coniacian sandstones from the North Sudetic Synclinorium revisited: palaeoenvironmental and palaeogeographical reconstructions based on trace fossil analysis and associated body fossils

Science.gov (United States)

Chrząstek, Alina; Wypych, Monika

2018-03-01

The Coniacian quartz sandstones (Żerkowice Member, Rakowice Wielkie Formation) that crop out at quarries near Czaple-Nowa Wieś Grodziska (North Sudetic Synclinorium) contain a low-diversity assemblage of trace fossils: Gyrochorte isp., Ophiomorpha nodosa (Lundgren, 1891), Ophiomorpha isp., Phycodes cf. curvipalmatum (Pollard, 1981), ?Phycodes isp., Planolites cf. beverleyensis (Billings, 1862), Thalassinoides paradoxicus (Woodward, 1830) and ?Thalassinoides isp. Moreover, interesting compound burrow systems, here referred to as Thalassinoides-Phycodes cf. palmatus and ?Thalassinoides-Phycodes, were recognised at the Czaple Quarry. Additionally, ?Gyrochorte isp., Phycodes cf. flabellum (Miller and Dyer, 1878) and ?Treptichnus isp. were encountered at correlative levels in the Rakowice Małe Quarry. Some of these ichnotaxa have not been recorded previously from Coniacian sandstones of the Żerkowice Member. Additionally, in slabs of these sandstones, the gastropod Nerinea bicincta (Bronn, 1836) and the bivalve Lima haidingeri (Zittel, 1866) were found. These interesting finds, in particular the gastropods, were already noted from the study area in the first half of the twentieth century by (Scupin (1912-1913)). Ethologically, the trace fossil assemblage is represented by domichnia or domichnia/fodinichnia (Ophiomorpha, Thalassinoides), fodinichnia (Phycodes) and pascichnia (Gyrochorte, Planolites). The compound burrow systems (Thalassinoides-Phycodes) are interpreted as dwelling/feeding structures. The possible tracemakers are crustaceans (Ophiomorpha, Thalassinoides) or worm-like animals (annelids and other) (Planolites, ?Phycodes, Gyrochorte and ?Treptichnus). The assemblage of trace fossils is characteristic of the Skolithos ichnofacies and Cruziana ichnofacies, typical of shallow-marine settings. Ichnological studies, as well as the presence of accompanying fossils (bivalves, gastropods), confirm the palaeoenvironmental reconstruction of the Żerkowice Member

Assessment of undiscovered sandstone copper deposits of the Kodar-Udokan area, Russia: Chapter M in Global mineral resource assessment

Science.gov (United States)

Zientek, Michael L.; Chechetkin, Vladimir S.; Parks, Heather L.; Box, Stephen E.; Briggs, Deborah A.; Cossette, Pamela M.; Dolgopolova, Alla; Hayes, Timothy S.; Seltmann, Reimar; Syusyura, Boris; Taylor, Cliff D.; Wintzer, Niki E.

2014-01-01

Mineral resource assessments integrate and synthesize available information as a basis for estimating the location, quality, and quantity of undiscovered mineral resources. This probabilistic mineral resource assessment of undiscovered sandstone copper deposits within Paleoproterozoic metasedimentary rocks of the Kodar-Udokan area in Russia is a contribution to a global assessment led by the U.S. Geological Survey (USGS). The purposes of this study are to (1) delineate permissive areas (tracts) to indicate where undiscovered sandstone-hosted copper deposits may occur within 2 km of the surface, (2) provide a database of known sandstone copper deposits and significant prospects, (3) estimate numbers of undiscovered deposits within these permissive tracts at several levels of confidence, and (4) provide probabilistic estimates of amounts of copper (Cu) and mineralized rock that could be contained in undiscovered deposits within each tract. The workshop for the assessment, held in October 2009, used a three-part form of mineral resource assessment as described by Singer (1993) and Singer and Menzie (2010).

Topological representation of the porous structure and its evolution of reservoir sandstone under excavation-induced loads

Directory of Open Access Journals (Sweden)

Ju Yang

2017-01-01

Full Text Available The porous structure of a reservoir rock greatly influences its evolutive deformation and fracture behavior during excavation of natural resources reservoirs. Most numerical models for porous structures have been used to predict the quasi-static mechanical properties, but few are available to accurately characterize the evolution process of the porous structure and its influence on the macroscopic properties of reservoir rocks. This study reports a novel method to characterize the porous structure of sandstone using its topological parameters and to determine the laws that govern the evolutive deformation and failure of the topological structure under various uniaxial compressive loads. A numerical model of the porous sandstone was established based on the pore characteristics that were acquired using computed tomography imaging techniques. The analytical method that integrates the grassfire algorithm and the maximum inscribed sphere algorithm was proposed to create the 3-D topological model of the deformed porous structure, through which the topological parameters of the structure were measured and identified. The evolution processes of the porous structure under various loads were characterized using its equivalent topological model and parameters. This study opens a new way to characterize the dynamic evolution of the pore structure of reservoir sandstone under excavation disturbance.

Sandstone uranium deposits of Eurasia – from genetic concepts to forecasting and new discoveries

International Nuclear Information System (INIS)

Pechenkin, I.

2014-01-01

Along the Eurasian continent’s southern borders lie uranium ore provinces and regions controlling medium-sized and, on rare occasions, large sandstone deposits. Central French, Eastern Rhodope and other regions are known in the west. Large uranium ore provinces were discovered in the south of the Turan Plate and in the depressions of South Kazakhstan, viz. Central Kyzyl Kum, Syr Darya, Chu Sarysu. A common criterion has been established for all objects of the sandstone type, located in oil and gas, coal etc. sedimentary basins – the zone of interlayer or ground-interlayer oxidation, controlling uranium mineralization. In 2003 we were able to justify the concept that the formation of giant deposits in Chu Sarysu province was caused by the collision between the Indian Plate and the southern part of the Eurasian continent. Within the limits of Pacific ore belt there is a zonal distribution of ore deposits. Ordinary mineralization is drawn towards its eastern fringe: gold, tin, copper, tungsten etc. Volcanic and tectonic structures of central type of Mesozoic age are located further west, from the north to the south, that is large calderas – Streltsovskaya (Russia), Dornot (Mongolia), Sian Shan (China), which control large and unique endogene uranium deposits. In the far west, in the region of subsiding tectonic tensions, there are sandstone deposits of uranium in Transbaikalia, Mongolia and Yunnan, which are specially connected to young basalts. Infiltration deposits of Vitim region are adjacent to endogene deposits of Streltsovsky region in the southern-easterly direction, and to the east of the deposits of Yunnan at the same latitude lay the Sian Shan caldera with geothermal deposits of uranium and other metals. We combined them into the unified submeridional Baikal-Southern China uranium ore belt. After examining the southern extremities of the Eurasian continent, the region of the collision of the Indian Plate, a distinct similarity can be perceived between

Characterization of the Oriskany and Berea Sandstones: Evaluating Biogeochemical Reactions of Potential Sandstone–Hydraulic Fracturing Fluid Interaction

Energy Technology Data Exchange (ETDEWEB)

Verba, Circe [National Energy Technology Lab. (NETL), Albany, OR (United States); Harris, Aubrey [National Energy Technology Lab. (NETL), Albany, OR (United States)

2016-07-07

The Marcellus shale, located in the mid-Atlantic Appalachian Basin, has been identified as a source for natural gas and targeted for hydraulic fracturing recovery methods. Hydraulic fracturing is a technique used by the oil and gas industry to access petroleum reserves in geologic formations that cannot be accessed with conventional drilling techniques (Capo et al., 2014). This unconventional technique fractures rock formations that have low permeability by pumping pressurized hydraulic fracturing fluids into the subsurface. Although the major components of hydraulic fracturing fluid are water and sand, chemicals, such as recalcitrant biocides and polyacrylamide, are also used (Frac Focus, 2015). There is domestic concern that the chemicals could reach groundwater or surface water during transport, storage, or the fracturing process (Chapman et al., 2012). In the event of a surface spill, understanding the natural attenuation of the chemicals in hydraulic fracturing fluid, as well as the physical and chemical properties of the aquifers surrounding the spill site, will help mitigate potential dangers to drinking water. However, reports on the degradation pathways of these chemicals are limited in existing literature. The Appalachian Basin Marcellus shale and its surrounding sandstones host diverse mineralogical suites. During the hydraulic fracturing process, the hydraulic fracturing fluids come into contact with variable mineral compositions. The reactions between the fracturing fluid chemicals and the minerals are very diverse. This report: 1) describes common minerals (e.g. quartz, clay, pyrite, and carbonates) present in the Marcellus shale, as well as the Oriskany and Berea sandstones, which are located stratigraphically below and above the Marcellus shale; 2) summarizes the existing literature of the degradation pathways for common hydraulic fracturing fluid chemicals [polyacrylamide, ethylene glycol, poly(diallyldimethylammonium chloride), glutaraldehyde

Ormosioxylon chinjiensis sp. nov., a new fossil wood of family Fabaceae from the Chinji formation Salt Range Punjab, Pakistan

International Nuclear Information System (INIS)

Soomro, N.; Arain, B. A.; Rajput, T. M.; Tahir, S. S.

2016-01-01

The present work deals with anatomical study of fossil wood collected from the Chinji formation (72 degree 22 min E, 32 degree 4 min N) of Miocene age exposed at the Chinji National Reserve at salt Range Punjab, Pakistan. The material consisted of a single piece of petrified wood. Taxonomical characters of the fossil wood were compared with modern and fossil wood. The sample wood was found comparable to the family Fabaceae. The closest resemblance of the fossil wood was with the wood of Ormosia. The fossil wood under investigation showed close resemblance of vessels, fibers, parenchyma and xylem rays, with the genus Ormosia but shows differences from already reported species of this genus. Hence it is described as a new species as Ormosioxylon chinjiensis sp. nov. The specific epithet refers to Chinji Formation from which the fossil wood is collected. (author)

ERG review of salt constitutive law, salt stress determinations, and salt corrosion and modeling studies

International Nuclear Information System (INIS)

Balon, J.E.

1986-03-01

The Engineering Review Group (ERG) was established by the Office of Nuclear Waste Isolation (ONWI) to help evaluate engineering-related issues in the US Department of Energy's nuclear waste repository program. The August 1983 meeting of the ERG reviewed a RE/SPEC technical report containing a review of eight constitutive laws that have been proposed to model the creep of salt over the ranges of stress and temperature anticipated in a nuclear repository. This report documents the ERG's comments and recommendations on this subject and the ONWI responses to the specific points raised by the ERG

Hot water, fresh beer, and salt

International Nuclear Information System (INIS)

Crawford, F.S.

1990-01-01

In the ''hot chocolate effect'' the best musical scales (those with the finest tone quality, largest range, and best tempo) are obtained by adding salt to a glass of hot water supersaturated with air. Good scales can also be obtained by adding salt to a glass of freshly opened beer (supersaturated with CO 2 ) provided you first (a) get rid of much of the excess CO 2 so as to produce smaller, hence slower, rising bubbles, and (b) get rid of the head of foam, which damps the standing wave and ruins the tone quality. Finally the old question, ''Do ionizing particles produce bubbles in fresh beer?'' is answered experimentally

Hot water, fresh beer, and salt

Science.gov (United States)

Crawford, Frank S.

1990-11-01

In the ``hot chocolate effect'' the best musical scales (those with the finest tone quality, largest range, and best tempo) are obtained by adding salt to a glass of hot water supersaturated with air. Good scales can also be obtained by adding salt to a glass of freshly opened beer (supersaturated with CO2) provided you first (a) get rid of much of the excess CO2 so as to produce smaller, hence slower, rising bubbles, and (b) get rid of the head of foam, which damps the standing wave and ruins the tone quality. Finally the old question, ``Do ionizing particles produce bubbles in fresh beer?'' is answered experimentally.

A new biostratigraphical tool for reservoir characterisation and well correlation in permo-carboniferous sandstones

NARCIS (Netherlands)

Garming, J.F.L.; Cremer, H.; Verreussel, R.M.C.H.; Guasti, E.; Abbink, O.A.

2010-01-01

Permo-Carboniferous sandstones are important reservoir rocks for natural gas in the Southern North Sea basin. This is a mature area which makes tools for reservoir characterization and well to well correlation important for field optimalisation and ongoing exploration activities. Within the

Synthesis and Characterization of Processable Polyaniline Salts

International Nuclear Information System (INIS)

Gul, Salma; Bilal, Salma; Shah, Anwar-ul-Haq Ali

2013-01-01

Polyaniline (PANI) is one of the most promising candidates for possible technological applications. PANI has potential applications in batteries, anion exchanger, tissue engineering, inhibition of steel corrosion, fuel cell, sensors and so on. However, its insolubility in common organic solvents limits its range of applications. In the present study an attempt has been made to synthesize soluble polyaniline salt via inverse polymerization pathway using benzoyl peroxide as oxidant and dodecylbenzenesulfonic acid (DBSA) as dopant as well as a surfactant. A mixture of chloroform and 2-butanol was used as dispersion medium for the first time. The influence of synthesis parameters such as concentration of aniline, benzoyl peroxide and DBSA on the yield and other properties of the resulting PANI salt was studied. The synthesized PANI salt was found to be completely soluble in DMSO, DMF, chloroform and in a mixture of toluene and 2-propanol. The synthesized polymer salt was also characterized with cyclic voltam-metry, SEM, XRD, UV-Vis spectroscopy and viscosity measurements. TGA was used to analyze the thermal properties of synthesized polymer. The extent of doping of the PANI salt was determined from UV-Vis spectra and TGA analysis. The activation energy for the degradation of the polymer was calculated with the help of TGA.

A GIS-based model of potential groundwater yield zonation for a sandstone aquifer in the Juye Coalfield, Shangdong, China

Science.gov (United States)

Yin, Huiyong; Shi, Yongli; Niu, Huigong; Xie, Daolei; Wei, Jiuchuan; Lefticariu, Liliana; Xu, Shuanxiang

2018-02-01

Resolving the potential groundwater yield zonation of sandstone aquifers occurring at depths of several hundred meters has been an important and challenging objective of the hydrogeological research focused on preventing flood hazards in coal mines. Using accessible geological exploration data we put forward a method of predicting the spatial distribution of groundwater storage potential in sandstone aquifers from Permian-age coal deposits in Juye Coalfield, Shangdong, China. A Geological, Tectonic and Lithological Composition Index (GTLCI) model was created using the following parameters: sandstone depth and thickness, faults length density (FaLD), faults density (FaD), fault frequency density (FaFD), fault scale density (FaSD), variation coefficient of the slope (VCS) of the coal seam, intensity index of folds in horizontal direction (IIFoH), and lithological composition index (LCI). Each of these factors was subsequently divided into 5 classes. The analytic hierarchy process (AHP) and trapezoidal fuzzy number (TFN) method was applied to calculate the weight of the conditioning factor and their respective sub-classes. Groundwater yield potential contour map, which was initially constructed using the GTLCI values revealed four groundwater abundance zones. The map was further refined by taking into account hydrogeologic data collected during mining activities. The GTLCI model predictive success rate of 80% was explained by the limited number of boreholes available for validation. It is considered that the GTLCI model is effective at predicting zonation of groundwater yield in the sandstone aquifers from Permian- age coal deposits in Juye Coalfield, China.

Mesocarbon microbead based graphite for spherical fuel element to inhibit the infiltration of liquid fluoride salt in molten salt reactor

Energy Technology Data Exchange (ETDEWEB)

Zhong, Yajuan, E-mail: yajuan.zhong@gmail.com [Center for Thorium Molten Salt Reactor System, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China); Zhang, Junpeng [CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China); Lin, Jun, E-mail: linjun@sinap.ac.cn [Center for Thorium Molten Salt Reactor System, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Xu, Liujun [Center for Thorium Molten Salt Reactor System, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhang, Feng; Xu, Hongxia; Chen, Yu; Jiang, Haitao; Li, Ziwei; Zhu, Zhiyong [Center for Thorium Molten Salt Reactor System, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800 (China); Guo, Quangui [CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001 (China)

2017-07-15

Mesocarbon microbeads (MCMB) and quasi-isostatic pressing method were used to prepare MCMB based graphite (MG) for spherical fuel element to inhibit the infiltration of liquid fluoride salt in molten salt reactor (MSR). Characteristics of mercury infiltration and molten salt infiltration in MG were investigated and compared with A3-3 (graphite for spherical fuel element in high temperature gas cooled reactor) to identify the infiltration behaviors. The results indicated that MG had a low porosity about 14%, and an average pore diameter of 96 nm. Fluoride salt occupation of A3-3 (average pore diameter was 760 nm) was 10 wt% under 6.5 atm, whereas salt gain did not infiltrate in MG even up to 6.5 atm. It demonstrated that MG could inhibit the infiltration of liquid fluoride salt effectively. Coefficient of thermal expansion (CTE) of MG lies in 6.01 × 10{sup −6} K{sup −1} (α{sub ∥}) and 6.15 × 10{sup −6} K{sup −1} (α{sub ⊥}) at the temperature range of 25–700 °C. The anisotropy factor of MG calculated by CTE maintained below 1.02, which could meet the requirement of the spherical fuel element (below 1.30). The constant isotropic property of MG is beneficial for the integrity and safety of the graphite used in the spherical fuel element for a MSR.

Mesocarbon microbead based graphite for spherical fuel element to inhibit the infiltration of liquid fluoride salt in molten salt reactor

International Nuclear Information System (INIS)

Zhong, Yajuan; Zhang, Junpeng; Lin, Jun; Xu, Liujun; Zhang, Feng; Xu, Hongxia; Chen, Yu; Jiang, Haitao; Li, Ziwei; Zhu, Zhiyong; Guo, Quangui

2017-01-01

Mesocarbon microbeads (MCMB) and quasi-isostatic pressing method were used to prepare MCMB based graphite (MG) for spherical fuel element to inhibit the infiltration of liquid fluoride salt in molten salt reactor (MSR). Characteristics of mercury infiltration and molten salt infiltration in MG were investigated and compared with A3-3 (graphite for spherical fuel element in high temperature gas cooled reactor) to identify the infiltration behaviors. The results indicated that MG had a low porosity about 14%, and an average pore diameter of 96 nm. Fluoride salt occupation of A3-3 (average pore diameter was 760 nm) was 10 wt% under 6.5 atm, whereas salt gain did not infiltrate in MG even up to 6.5 atm. It demonstrated that MG could inhibit the infiltration of liquid fluoride salt effectively. Coefficient of thermal expansion (CTE) of MG lies in 6.01 × 10 −6 K −1 (α ∥ ) and 6.15 × 10 −6 K −1 (α ⊥ ) at the temperature range of 25–700 °C. The anisotropy factor of MG calculated by CTE maintained below 1.02, which could meet the requirement of the spherical fuel element (below 1.30). The constant isotropic property of MG is beneficial for the integrity and safety of the graphite used in the spherical fuel element for a MSR.

Simulation of channel sandstone architecture in an incised valley

Energy Technology Data Exchange (ETDEWEB)

Frykman, P.; Johannessen, P.; Andsbjerg, J.

1998-12-31

The present report describes a geostatistical modelling study that is aimed at reflecting the architecture of the channel sandstones in an incised valley fill. The example used for this study is a part of the Middle Jurassic sandy succession of the Bryne Formation in the Danish central Graben. The succession consists mainly of fluvial sediments in the lower part, overlain by tidal influenced sediments, which again is overlain by shallow marine sediments. The modelling study has been performed on a sequence of incised valley sediments in the upper part of the Bryne Formation overlying fluvial sediments. (au) EFP-96. 19 refs.

Palaeoclimatic trends deduced from the hydrochemistry of a Triassic sandstone aquifer, U.K

International Nuclear Information System (INIS)

Bath, A.H.; Edmunds, W.M.; Andrews, J.N.

1978-01-01

A detailed geochemical study (elemental, isotopic and dissolved inert gases) of unconfined and confined sections of the Triassic non-marine sandstone aquifer in Eastern England has been undertaken. Aspects of the recharge history of this aquifer over the past 40 000 years are revealed by examination of the data. (orig./HK) [de

Salt-saturated concrete strength and permeability

International Nuclear Information System (INIS)

Pfeifle, T.W.; Hansen, F.D.; Knowles, M.K.

1996-01-01

Laboratory-scale experiments applicable to the use of salt-saturated concrete as a seal material for a transuranic waste repository have been completed. Nitrogen gas permeability measurements were made using a flexible-wall permeameter, a confining pressure of 1 MPa, and gas pressure gradients ranging from 0.3 MPa to 0.75 MPa. Results show that salt-saturated concrete has very low intrinsic permeability with values ranging from 9.4 x 10 -22 m 2 to 9.7 x 10 -17 m 2 . Strength and deformation characteristics were investigated under conditions of triaxial compression with confining pressures ranging from 0 to 15 MPa using either axial strain-rate or axial stress-rate control and show that the failure strength of concrete increases with confining pressure which can be adequately described through pressure-sensitive failure criteria. Axial, radial, and volumetric strains were also measured during each test and these data were used to determine elastic properties. Experimental results are applicable in the design and analysis of scale-related functions and apply to other concrete structures subjected to compressive loadings such as dams and prestressed structural members

Combined rock-physical modelling and seismic inversion techniques for characterisation of stacked sandstone reservoir

NARCIS (Netherlands)

Justiniano, A.; Jaya, Y.; Diephuis, G.; Veenhof, R.; Pringle, T.

2015-01-01

The objective of the study is to characterise the Triassic massive stacked sandstone deposits of the Main Buntsandstein Subgroup at Block Q16 located in the West Netherlands Basin. The characterisation was carried out through combining rock-physics modelling and seismic inversion techniques. The

Salt brickwork as long-term sealing in salt formations

International Nuclear Information System (INIS)

Walter, F.; Yaramanci, U.

1993-01-01

Radioactive wastes can be disposed of in deep salt formations. Rock salt is a suitable geologic medium because of its unique characteristics. Open boreholes, shafts and drifts are created to provide physical access to the repository. Long-term seals must be emplaced in these potential pathways to prevent radioactive release into the biosphere. The sealing materials must be mechanically and, most important, geochemically stable within the host rock. Salt bricks made from compressed salt-powder are understood to be the first choice long-term sealing material. Seals built of salt bricks will be ductile. Large sealing systems are built by combining the individual bricks with mortar. Raw materials for mortar are fine-grained halite powder and ground saliferous clay. This provides for the good adhesive strength of the mortar to the bricks and the high shear-strength of the mortar itself. To test the interaction of rock salt with an emplaced long-term seal, experiments will be carried out in situ, in the Asse salt mine in Germany. Simple borehole sealing experiments will be performed in horizontal holes and a complicated drift sealing experiment is planned, to demonstrate the technology of sealing a standard size drift or shaft inside a disturbed rock mass. Especially, the mechanical stability of the sealing system has to be demonstrated

Net-infiltration map of the Navajo Sandstone outcrop area in western Washington County, Utah

Science.gov (United States)

Heilweil, Victor M.; McKinney, Tim S.

2007-01-01

As populations grow in the arid southwestern United States and desert bedrock aquifers are increasingly targeted for future development, understanding and quantifying the spatial variability of net infiltration and recharge becomes critically important for inventorying groundwater resources and mapping contamination vulnerability. A Geographic Information System (GIS)-based model utilizing readily available soils, topographic, precipitation, and outcrop data has been developed for predicting net infiltration to exposed and soil-covered areas of the Navajo Sandstone outcrop of southwestern Utah. The Navajo Sandstone is an important regional bedrock aquifer. The GIS model determines the net-infiltration percentage of precipitation by using an empirical equation. This relation is derived from least squares linear regression between three surficial parameters (soil coarseness, topographic slope, and downgradient distance from outcrop) and the percentage of estimated net infiltration based on environmental tracer data from excavations and boreholes at Sand Hollow Reservoir in the southeastern part of the study area.Processed GIS raster layers are applied as parameters in the empirical equation for determining net infiltration for soil-covered areas as a percentage of precipitation. This net-infiltration percentage is multiplied by average annual Parameter-elevation Regressions on Independent Slopes Model (PRISM) precipitation data to obtain an infiltration rate for each model cell. Additionally, net infiltration on exposed outcrop areas is set to 10 percent of precipitation on the basis of borehole net-infiltration estimates. Soils and outcrop net-infiltration rates are merged to form a final map.Areas of low, medium, and high potential for ground-water recharge have been identified, and estimates of net infiltration range from 0.1 to 66 millimeters per year (mm/yr). Estimated net-infiltration rates of less than 10 mm/yr are considered low, rates of 10 to 50 mm/yr are

Textural patterns, mineralogy, and chemistry of sandstone-related Calçadinha chalcedony (Piauí, Brazil

Directory of Open Access Journals (Sweden)

Marcondes Lima da Costa

Full Text Available ABSTRACT: Paleozoic sandstones of the Parnaíba Basin, in addition to hosting opal deposits, also have occurrences of chalcedonies with potential for mineral and ornamental handicrafts, in addition to assisting the understanding of the geological evolution of the basin. However, the chalcedonies were not investigated yet, and this study intended to fulfill this gap by the investigation of the chalcedonies of Calçadinha in Piauí. Fieldwork, microtexturals analysis, X-ray diffraction and scanning electron microscopy with energy dispersive spectrometry, chemical analysis, and gemological assessments were developed. Four distinct types of chalcedonies have been distinguished. They stand out for their well distribution of Fe and Mn dendrites, which involves opal nodules, and contains microcavities with well-formed microcrystalline quartz, nontronite, and palygorskite. The mesoscopic features of these chalcedonies and cabochon and free forms cutting show potential for use in mineral crafts and semi-jewels. As expected, the chalcedonies are dominated by high contents of SiO2, besides the low and variable contents of Al2O3, Fe2O3, MgO, and TiO2. Among trace elements that show high Ba contents, bound in barite, seem also to be a geochemical signature of the country sandstones in Parnaíba basin. These chalcedonies were formed during the partial solubilization of SiO2 of sandstones, which was promoted during their tectonic formation in faults and fractures zones.

Estimates of vertical hydraulic conductivity in the middle Dakota Sandstone, Monticello, Utah

International Nuclear Information System (INIS)

Kautsky, M.; Kearl, P.M.; Dexter, J.J.; Zinkl, R.J.

1986-01-01

There are about 2 million tons of uranium mill tailings which lie directly on top of an alluvial aquifer at the Monticello millsite, Utah. The aquifer is contaminated as a consequence of leachate percolating through the tailings. The Burro Canyon Formation which is the local culinary aquifer, underlies the site at depth, but is isolated from the alluvial aquifer by an aquitard composed primarily of middle Dakota Sandstone, and some Mancos Shale. Water quality monitoring of the Burro Canyon aquifer has indicated that it contains very low to no contamination by radionuclides. Tritium data have shown that the recharge to the aquifer predates 1953. Pump tests conducted on the system using the ratio method, have shown the vertical hydraulic conductivity of the aquitard is some 5.2 x 10/sup -7/ to 8.0 x 10/sup -9/ m/d (1.7 x 10/sup -6/ to 2.6 x 10/sup -8/ ft/d). Based upon the aquifer monitoring and test data, the middle Dakota Sandstone appears to be an effective aquitard impeding the downward migration of contaminants from the alluvial aquifer to the Burro Canyon aquifer

Correlation development between indentation parameters and uniaxial compressive strength for Colombian sandstones

International Nuclear Information System (INIS)

Mateus, Jefferson; Saavedra, Nestor Fernando; Calderon Carrillo, Zuly; Mateus, Darwin

2007-01-01

A new way to characterize the perforated formation strength has been implemented using the indentation test. This test can be performed on irregular cuttings mounted in acrylic resins forming a disc. The test consists of applying load on each sample by means of a flat and indenter. A graph of the load applied VS penetration of the indenter is developed, and the modules of the test, denominated indentation modulus (IM) and Critical Transition Force (CTF) are obtained (Ringstad et al., 1998). Based on the success of previous studies we developed correlations between indentation and mechanical properties for some Colombian sandstone. These correlations were obtained using o set of 248 indentation tests and separate compression fasts on parallel sandstone samples from the same depth. This analysis includes Barco Formation, Mirador Formation, and Tambor Formation. For the correlations, IM-UCS and CTF-UCS, the correlation coefficient is 0.81 and 0.70 respectively. The use of the correlations and the indentation test is helpful for in-situ calibration of the geomechanical models since the indentation test can be performed in real time thus reducing costs and time associated with delayed conventional characterization

Laboratory Mid-frequency (Kilohertz) Range Seismic Property Measurements and X-ray CT Imaging of Fractured Sandstone Cores During Supercritical CO2 Injection

Science.gov (United States)