Sample records for sand transport processes

  1. Sand transport processes in the surf and swash zones

    NARCIS (Netherlands)

    Zanden, van der Joep


    Long-term predictions of beach morphology using numerical models contribute to cost-effective coastal protection strategies. The physics of sand transport in the wave breaking region and the swash zone are not fully understood, leading to poor predictive capability of existing sand transport models

  2. Effect of Different Forcing Processes on the Longshore Sediment Transport at the Sand Motor, The Netherlands

    NARCIS (Netherlands)

    Kaji, A.O.; Luijendijk, A.P.; van Thiel de Vries, J.S.M.; De Schipper, M.A.; Stive, M.J.F.


    The Sand Motor is a pilot project of a ‘mega-nourishment’ built in the Dutch coast in 2011. In order to understand which conditions reshape those mega-nourishments the influence of different types of forcing on the longshore sediment transport along the Sand Motor has been assessed in this paper usi

  3. Effect of Different Forcing Processes on the Longshore Sediment Transport at the Sand Motor, The Netherlands

    NARCIS (Netherlands)

    Kaji, A.O.; Luijendijk, A.P.; van Thiel de Vries, J.S.M.; De Schipper, M.A.; Stive, M.J.F.


    The Sand Motor is a pilot project of a ‘mega-nourishment’ built in the Dutch coast in 2011. In order to understand which conditions reshape those mega-nourishments the influence of different types of forcing on the longshore sediment transport along the Sand Motor has been assessed in this paper

  4. Modelling and measurement of sand transport processes over full-scale ripples in oscillatory flow

    NARCIS (Netherlands)

    Werf, van der Jebbe J.; Ribberink, Jan S.; O'Donoghue, Tom; Doucette, Jeffrey C.


    A new series of laboratory experiments was performed in the Aberdeen Oscillatory Flow Tunnel (AOFT) and the Large Oscillating Water Tunnel (LOWT) to investigate time-averaged suspended sand concentrations and transport rates over rippled beds in regular and irregular oscillatory flow. The wave-induc

  5. Characteristics Of Basaltic Sand: Size, Shape, And Composition As A Function Of Transport Process And Distance (United States)

    Craddock, R. A.; Needell, Z. A.; Rose, T. R.


    quartz, feldspar, and heavy minerals commonly found in most terrestrial sedimentary deposits, basaltic sediments are composed of varying amounts of olivine, pyroxene, plagioclase, and vitric and lithic fragments. One of the few locations on Earth containing such material is the Ka'u Desert of Hawaii. This area is unique in that both eolian and fluvial sediment pathways occur in the same area, thus allowing a direct comparison of particles transported by different processes over identical distances (~20 km). We are currently documenting the physical and chemical changes that take place in basaltic sediments as they are transported by wind and water over increasing distances. This will result in an improvement in our understanding of traditional sedimentological concepts when applying them to Martian surface materials. Process: The Ka'u Desert is ~350 km2 and contains the largest basaltic dune fields on Earth. We have identified several different dune types located in various parts of the desert, including climbing and falling dunes, sand sheets, parabolic dunes (that were initially barchans), and crescentic dunes. Fluvial sediments occur as floodout deposits where ephemeral streams go from confined to unconfined flow outside the continuous Keanakako'i Formation [7]. There are also a number of sand bottom streams and playas that occur along a series of channels that extend from the Keanakako'i Formation ~20 km to the sea. We have collected samples from dunes and fluvial deposits at various locations in the Ka'u Desert, at varying distances from sources and subject to different environmental processes. In the lab, we have begun to use optical and scanning electron microscopic images to assess how grain size, shape, and angularity of individual particles change with increasing transport distances. We are also conducting point counts of particles contained within each sample to better understand how olivine, pyroxene, feldspar, and lithic and vitric fragments weather with

  6. Sand transport, erosion and granular electrification

    DEFF Research Database (Denmark)

    Merrison, J.P.


    The transport of granular materials by wind has a major impact on our environment through sand/soil erosion and the generation and transport of atmospheric dust aerosols. Terrestrially the transport of dust involves billions of tons of material every year, influencing the global climate and impac......The transport of granular materials by wind has a major impact on our environment through sand/soil erosion and the generation and transport of atmospheric dust aerosols. Terrestrially the transport of dust involves billions of tons of material every year, influencing the global climate...... can affect grain transport through the generation of intense electric fields and processes of electrostatic assembly. Importantly the transport of sand is characterized by saltation, which is known to be an active process for erosion and therefore a source for dust and sand formation. Using novel...... erosion simulation techniques the link between grain transport rates and erosion rates has been quantified. Furthermore this can be linked to production rates for dust and has been associated with chemical and mineral alteration through a process of mechanical activation of fractured surfaces. This work...

  7. Nearshore Sand Transport. (United States)


    Born November 19, 1956 - Peoria, Illinois 1978 B.S., Civil Engineering, University of Miami, Coral Gables, Florida 1978 B.S., Physics, University of...Aubrey, 1985, "Theoretical and observational estimates of nearshore bedload transport rates," Marino Geology, v 64, p 91-111. Guza, R.T., N.C. Clifton


    Calkins, G.D.; Bohlmann, E.G.


    A process for the recovery of thorium, uranium, and rare earths from monazite sands is presented. The sands are first digested and dissolved in concentrated NaOH, and the solution is then diluted causing precipitation of uranium, thorium and rare earth hydroxides. The precipitate is collected and dissolved in HCl, and the pH of this solution is adjusted to about 6, precipitating the hydroxides of thorium and uranium but leaving the rare earths in solution. The rare earths are then separated from the solution by precipitation at a still higher pH. The thorium and uranium containing precipitate is redissolved in HNO/sub 3/ and the two elements are separated by extraction into tributyl phosphate and back extraction with a weakly acidic solution to remove the thorium.

  9. Aeolian transport of sand. (United States)

    Almeida, M P; Andrade, J S; Herrmann, H J


    The airborne transport of particles on a granular surface by the saltation mechanism is studied through numerical simulation of particles dragged by turbulent air flow. We calculate the saturated flux q(s) and show that its dependence on the wind strength u(*) is consistent with several empirical relations obtained from experimental measurements. We propose and explain a new relation for fluxes close to the threshold velocity u(t), namely, q(s)=a(u(*)-u(t))(alpha) with alpha approximately 2. We also obtain the distortion of the velocity profile of the wind due to the drag of the particles and find a novel dynamical scaling relation. We also obtain a new expression for the dependence of the height of the saltation layer as function of the strength of the wind.

  10. Longshore sediment transport at Golden Sands (Bulgaria

    Directory of Open Access Journals (Sweden)

    Hristo Nikolov


    Full Text Available The paper presents the results of studies on the qualitative and quantitative features of the littoral drift at Golden Sands (Bulgaria, carried out jointly by Polish and Bulgarian researchers. The mathematical modelling of physical coastal processes took wave transformation (wave diffraction and refraction; the effects of shoaling and wave breaking and longshore sediment transport into account. The computations were carried out for the mean statistical annual wave climate, determined on the basis of IO BAS wave data, simulated using the WAM method from long-term Black Sea wind data. The results of sediment transport computations clearly show that its direction off the Golden Sands shore is from north to south.

  11. Discrete particle simulation of mixed sand transport

    Institute of Scientific and Technical Information of China (English)

    Fengjun Xiao; Liejin Guo; Debiao Li; Yueshe Wang


    An Eulerian/Lagrangian numerical simulation is performed on mixed sand transport.Volume averaged Navier-Stokes equations are solved to calculate gas motion,and particle motion is calculated using Newton's equation,involving a hard sphere model to describe particle-to-particle and particle-to-wall collisions.The influence of wall characteristics,size distribution of sand particles and boundary layer depth on vertical distribution of sand mass flux and particle mean horizontal velocity is analyzed,suggesting that all these three factors affect sand transport at different levels.In all cases,for small size groups,sand mass flux first increases with height and then decreases while for large size groups,it decreases exponentially with height and for middle size groups the behavior is in-between.The mean horizontal velocity for all size groups well fits experimental data,that is,increasing logarithmically with height in the middle height region.Wall characteristics greatly affects particle to wall collision and makes the flat bed similar to a Gobi surface and the rough bed similar to a sandy surface.Particle size distribution largely affects the sand mass flux and the highest heights they can reach especially for larger particles.


    Welt, M.A.; Smutz, M.


    A process is described for recovering thorium, uranium, and rare earth values from monazite sand. The monazite sand is first digested with sulfuric acid and the resulting "monazite sulfate" solution is adjusted to a pH of between 0.4 and 3.0, and oxalate anions are added causing precipitation of the thorium and the rare earths as the oxalates. The oxalate precipitate is separated from the uranium containing supernatant solution, and is dried and calcined to the oxides. The thorium and rare earth oxides are then dissolved in nitric acid and the solution is contacted with tribntyl phosphate whereby an organic extract phase containing the cerium and thorium values is obtained, together with an aqueous raffinate containing the other rare earth values. The organic phase is then separated from the aqueous raffinate and the cerium and thorium are back extracted with an aqueous medium.

  13. Modelling aeolian sand transport using a dynamic mass balancing approach (United States)

    Mayaud, Jerome R.; Bailey, Richard M.; Wiggs, Giles F. S.; Weaver, Corinne M.


    our DMB model at a temporal resolution of 4 s in cases where the temporal scale of investigation is relatively short (on the order of minutes), and at a resolution of 1 min for longer wind and transport datasets (on the order of hours). The proposed new sand transport model could prove to be significant for integrating turbulence-scale transport processes into longer-term, macro-scale landscape modelling of drylands.

  14. Transport velocities of coal and sand particles

    Energy Technology Data Exchange (ETDEWEB)

    Adanez, J. (Inst. de Carboquimica, Zaragoza (Spain)); Diego, L.F. de (Inst. de Carboquimica, Zaragoza (Spain)); Gayan, P. (Inst. de Carboquimica, Zaragoza (Spain))


    Transport velocities of narrow cut sizes of coarse particles of sand and coal were determined at room temperature and atmospheric pressure. These velocities were obtained by four different methods previously utilized by other authors with fine particles. The four methods tested gave good predictions of the transport velocities. The method based on the measurement of the time required for all the solids to leave the bed without feeding in any fresh solid is specially interesting because of its rapidity and simplicity. The determined transport velocities were strongly dependent on the solid particle size and density. The experimental values were fitted to an equation which fitted both the experimental results obtained in this work and other published results obtained with fine particles. (orig.)

  15. A transport-rate model of wind-blown sand

    Institute of Scientific and Technical Information of China (English)


    Sand transport by wind plays an important role in environmental problems.Formulating the sand-transport rate model has been of continuing significance,because the majority of the existing models relate sand-transport rate to the wind-shear velocity.However,the wind-shear velocity readapted to blown sand is difficult to determine from the measured wind profiles when sand movement occurs,especially at high wind velocity.Detailed wind tunnel tests were carried out to reformulate the sand-transport rate model,followed by attempts to relate sand-transport rate to parameters of wind velocity,threshold shear-velocity,and grain size.Finally,we validated the model based on the data from field observations.

  16. Sedimentation process of saturated sand under impact loading

    Institute of Scientific and Technical Information of China (English)

    ZHANG; Junfeng; MENG; Xiangyue


    The initial small inhomogeneity of saturated sand could be amplified during the sedimentation process after liquefaction, and cracks could be observed in the sand column. Layers of fine sand could also be found at the exact place where cracks developed and disappeared. The phenomena and the whole process were experimentally shown by X-rays images. To account for the phenomena, a linearized stability analysis of the sedimentation of saturated sand was conducted; however, it did not produce a satisfactory result. A three-phase flow model describing the transportation of fine sand is presented in this paper. It is shown that such a kind of erosion/deposition model was qualitatively in good agreement with the experimental observation.

  17. Modeling sheet-flow sand transport under progressive surface waves

    NARCIS (Netherlands)

    Kranenburg, W.M.


    In the near-shore zone, energetic sea waves generate sheet-flow sand transport. In present day coastal models, wave-induced sheet-flow sand transport rates are usually predicted with semi-empirical transport formulas, based on extensive research on this phenomenon in oscillatory flow tunnels. Howeve

  18. Sand transportation and reverse patterns over leeward face of sand dune (United States)

    Jiang, Hong; Dun, Hongchao; Tong, Ding; Huang, Ning


    Sand saltation has complex interactions with turbulent flow and dune form. Most models of wind-blown sand consider ideal circumstances such as steady wind velocity and a flat surface, and the bulk of data on wind flow and sand transport over an individual dune has focused mostly on the influence of dune shape or inter-dune space on the wind flow, neglecting the effect of morphology on sand saltation, particularly airflow and sand transportation over the leeward slope. Wind flow structures over the leeward slope of sand dunes have a fundamental influence on the organization of sand dunes. In order to understand sand dune dynamics, lee face airflow and sediment transportation should be paid more attention. Previous field observations could not measure turbulent flow structure well because of the limited observation points and the influence of experiment structure on wind field. In addition, the reverse sand particles over leeward face could not be collected by sand trap in field. Numerous field observations could not measure turbulent flow structure because of the limited observation points and the influence of experimental structures on the wind field. In addition, the reverse transport of sand particles over leeward face could not be collected by sand traps in field. Therefore, this paper aims to investigate the turbulent flow structure and sand transport pattern over the leeward slope. A numerical model of sand saltation over slope terrain is constructed, which also considers the coupling effects between air flow and sand particles. The large eddy simulation method is used to model turbulent flow. Sand transport is simulated by tracking the trajectory of each sand particle. The results show that terrain significantly alters the turbulent air flow structure and wind-blown sand movement, especially over the leeward slope. Here, mass flux increases initially and then decreases with height in the reversed flow region in the direction of wind flow, and the mass flux

  19. Sand transport in oscillatory sheet-flow; a literature review

    NARCIS (Netherlands)

    Janssen, C.M.


    This literature review is part of the ongoing research on sand transport in oscillatory sheet-flow, as taking place at the coast during storms. Because sheet-flow corresponds to conditions of high shear stress, large amounts of sand are transported. Therefore it is an important part of the total san

  20. experimental investigation of sand minimum transport velocity in ...

    African Journals Online (AJOL)


    minimum transport velocity models in pipelines, the analytical and empirical methods. Because of the ... identified two niche areas of research such as sand transport in .... operational conditions the limit deposit velocity passes through a ...

  1. Aeolian sand transport and aeolian deposits on Venus: A review (United States)

    Kreslavsly, Mikhail A.; Bondarenko, Nataliya V.


    We review the current state of knowledge about aeolian sand transport and aeolian bedforms on planet Venus. This knowledge is limited by lack of observational data. Among the four planetary bodies of the Solar System with sufficient atmospheres in contact with solid surfaces, Venus has the densest atmosphere; the conditions there are transitional between those for terrestrial subaerial and subaqueous transport. The dense atmosphere causes low saltation threshold and short characteristic saltation length, and short scale length of the incipient dunes. A few lines of evidence indicate that the typical wind speeds exceed the saltation threshold; therefore, sand transport would be pervasive, if sand capable of saltation is available. Sand production on Venus is probably much slower than on the Earth; the major terrestrial sand sinks are also absent, however, lithification of sand through sintering is expected to be effective under Venus' conditions. Active transport is not detectable with the data available. Aeolian bedforms (transverse dunes) resolved in the currently available radar images occupy a tiny area on the planet; however, indirect observations suggest that small-scale unresolved aeolian bedforms are ubiquitous. Aeolian transport is probably limited by sand lithification causing shortage of saltation-capable material. Large impact events likely cause regional short-term spikes in aeolian transport by supplying a large amount of sand-size particles, as well as disintegration and activation of older indurated sand deposits. The data available are insufficient to understand whether the global aeolian sand transport occurs or not. More robust knowledge about aeolian transport on Venus is essential for future scientific exploration of the planet, in particular, for implementation and interpretation of geochemical studies of surface materials. High-resolution orbital radar imaging with local to regional coverage and desirable interferometric capabilities is the

  2. A new turbulence-based model for sand transport (United States)

    Mayaud, Jerome; Wiggs, Giles; Bailey, Richard


    saltation system that has been reported in previous studies. Whilst the inclusion of both the u and w flow components is a key conceptual element of our new model, similar to recent field studies (e.g. Schönfeldt & von Löwis, 2003; Wiggs & Weaver, 2012; Chapman et al., 2013), we find that fluctuations in w are relatively unimportant for driving saltation, because wind-driven flux is more strongly associated with a positive u component. The best predictions of total sand transport are achieved using our turbulence model at a temporal resolution of 4 s in cases of partially developed saltation, and at a resolution of 1 min in cases of well-developed saltation. The proposed approach could prove to be significant for integrating turbulent transport processes into long-term, macro-scale landscape modelling of drylands References Chapman, C., Walker, I. J., Hesp, P. A., Bauer, B. O., Davidson-Arnott, R. G. D., & Ollerhead, J. (2013). Reynolds stress and sand transport over a foredune. Earth Surface Processes and Landforms, 38(14), 1735-1747. Dong, Z., Liu, X., Wang, H. & Wang, X. (2003). Aeolian sand transport: a wind tunnel model. Sedimentary Geology, 161, 71-83. Radok, U. (1977). Snow drift. Journal of Glaciology, 19, 123-139. Schönfeldt, H. J., & von Löwis, S. (2003). Turbulence-driven saltation in the atmospheric surface layer. Meteorologische Zeitschrift, 12(5), 257-268. Wiggs, G. F. S. & Weaver, C. M. (2012). Turbulent flow structures and aeolian sediment transport over a barchan sand dune. Geophysical Research Letters, 39(5), 1-7.

  3. Prediction of sand transport over immobile gravel from supply limited to capacity conditions. (United States)

    The prediction of the transport of sand in armored gravel reaches downstream of dams is complicated by variable bed conditions ranging from sand transported through gravel to sand in transport over buried gravel. Knowledge of the rate of sand transport in these conditions, however, is necessary for...

  4. Field Measurements of Influence of Sand Transport Rate on Structure of Wind-sand Flow over Coastal Transverse Ridge

    Institute of Scientific and Technical Information of China (English)

    DONG Yuxiang; S L NAMIKAS; P A HESP; MA Jun


    The structure of wind-sand flow under different total sand transport rates was measured with field vertical anemometer and sand trap on the crest of typical coastal transverse ridge in Changli Gold Coast of Hebei Province,which is one of the most typical coastal aeolian distribution regions in China and famous for the tall and typical coastal transverse ridges.The measurement results show that,on the conditions of approximate wind velocities and same surface materials and environments,some changes happen to the structure of wind-sand flow with the increase of total sand transport rate on the crest of coastal transverse ridge.First,the sand transport rates of layers at different heights in the wind-sand flow increase,with the maximum increase at the height layer of 4-8cm.Second,the ratios of sand transport rates of layers at different heights to total sand transport rate decrease at the low height layer (0-4cm),but increase at the high height layer (4-60cm).Third,the distribution of the sand transport rate in the wind-sand flow can be expressed by an exponential function at the height layer of 0-40cm,but it changes fi'om power function model to exponential function model in the whole height layer (0-60cm) and changes into polynomial function model at the height layer of 40-60cm with the increase of total sand transport rate.Those changes have a close relationship with the limit of sand grain size of wind flow transporting and composition of sand grain size in the wind-sand flow.

  5. Influence of silicate on the transport of bacteria in quartz sand and iron mineral-coated sand. (United States)

    Dong, Zhe; Yang, Haiyan; Wu, Dan; Ni, Jinren; Kim, Hyunjung; Tong, Meiping


    The influence of silicate on the transport and deposition of bacteria (Escherichia coli) in packed porous media were examined at a constant 20 mM ionic strength with different silicate concentrations (from 0 to 1 mM) at pH 7. Transport experiments were performed in two types of representative porous media, both bare quartz sand and iron mineral-coated quartz sand. In bare quartz sand, the breakthrough plateaus in the presence of silicate in suspensions were lower and the corresponding retained profiles were higher than those without silicate ions, indicating that the presence of silicate in suspensions decreased cell transport in bare quartz sand. Moreover, the decrease of bacteria transport in quartz sand induced by silicate was more pronounced with increasing silicate concentrations from 0 to 1 mM. However, when EPS was removed from cell surfaces, the presence of silicate in cell suspensions (with different concentrations) did not affect the transport behavior of bacteria in quartz sand. The interaction of silicate with EPS on cell surfaces negatively decreased the zeta potentials of bacteria, resulting in the decreased cell transport in bare quartz sand when silicate was copresent in bacteria suspensions. In contrast, the presence of silicate in suspensions increased cell transport in iron mineral-coated sand. Silicate ions competed with bacteria for the adsorption sites on mineral-coated sand, contributing to the increased cell transport in mineral-coated sand with silicate present in cell suspensions.

  6. Mineral processing of heavy mineral sands from Malawi and Malaysia


    Mitchell, C J


    Processing of heavy mineral sands involves many techniques including gravity, magnetic and electrostatic separation. As part of a laboratory programme to develop effective mineral processing techniques, two mineral sands from Malawi and Malaysia were processed using the standard techniques, with emphasis placed on the Carpco electrostatic separator. These sands were initially characterised mineralogically by scanning electron microscopy (SEM), electron microprobe analysis (EPMA...

  7. Oblique second-order sand transport pathways on an intertidal sand flat in a natural tidal inlet system

    DEFF Research Database (Denmark)

    Ernstsen, Verner Brandbyge; Lefebvre, Alice; Kroon, Aart


    . This indicates distinct second-order sand transport pathways oblique to the main tidal transport pathways. A conceptual model for the development of the bedforms and channels is presented, which comprises hypotheses of the hydrodynamic forcing of the different second-order sand transport pathways. During flood...

  8. 2007 Weather and Aeolian Sand-Transport Data from the Colorado River Corridor, Grand Canyon, Arizona (United States)

    Draut, Amy E.; Andrews, Timothy; Fairley, Helen C.; Brown, Christopher R.


    Weather data constitute an integral part of ecosystem monitoring in the Colorado River corridor and are particularly valuable for understanding processes of landscape change that contribute to the stability of archeological sites. Data collected in 2007 are reported from nine weather stations in the Colorado River corridor through Grand Canyon, Ariz. The stations were deployed in February and March 2007 to measure wind speed and direction, rainfall, air temperature, relative humidity, and barometric pressure. Sand traps near each weather station collect windblown sand, from which daily aeolian sand-transport rates are calculated. The data reported here were collected as part of an ongoing study to test and evaluate methods for quantifying processes that affect the physical integrity of archeological sites along the river corridor; as such, these data can be used to identify rainfall events capable of causing gully incision and to predict likely transport pathways for aeolian sand, two landscape processes integral to the preservation of archeological sites. Weather data also have widespread applications to other studies of physical, cultural, and biological resources in Grand Canyon. Aeolian sand-transport data reported here, collected in the year before the March 2008 High-Flow Experiment (HFE) at Glen Canyon Dam, represent baseline data against which the effects of the 2008 HFE on windblown sand will be compared in future reports.

  9. Experimental investigation on heat transport in gravel-sand materials

    DEFF Research Database (Denmark)

    Maureschat, Gerald; Heller, Alfred


    out in a small size experiment. The experiment consists of a highly insulated box filled with two kinds of sand material crossed by a plastic heat pipe. Heat transfer is measured under dry and water satured conditions in a cross-section.The conclusions are clear. To obtain necessary heat conduction......The project is a basic study on the expected thermal behaviour of gravel storage initiated as a part of a research and demonstration gravel storage for seasonal heat storage.The goal of the investigation is to determine the heat transfer between heat pipes and sand-gravel storage media by carrying...... media no convectional heat transport is found. It would be relevant to extend the investigation to media that enables convectional heat transport. A last conclusion is that such experiments, necessary for proper designing of sand-gravel storage types, are a very cheap form of collecting information...

  10. Experimental investigation on heat transport in gravel-sand materials

    DEFF Research Database (Denmark)

    Maureschat, Gerald; Heller, Alfred


    out in a small size experiment. The experiment consists of a highly insulated box filled with two kinds of sand material crossed by a plastic heat pipe. Heat transfer is measured under dry and water satured conditions in a cross-section.The conclusions are clear. To obtain necessary heat conduction...... in sand-gravel material, the storage media is to be water satured. In this case, handling of such material on site is rather complex. The conduction is highly dependent on the thermal properties of the storage media and so is the overall thermal performance of a storage applying such media. For sandy...... media no convectional heat transport is found. It would be relevant to extend the investigation to media that enables convectional heat transport. A last conclusion is that such experiments, necessary for proper designing of sand-gravel storage types, are a very cheap form of collecting information...

  11. 2008 Weather and Aeolian Sand-Transport Data from the Colorado River Corridor, Grand Canyon, Arizona (United States)

    Draut, Amy E.; Sondossi, Hoda A.; Hazel, Joseph E.; Andrews, Timothy; Fairley, Helen C.; Brown, Christopher R.; Vanaman, Karen M.


    This report presents measurements of weather parameters and aeolian (windblown) sand transport made in 2008 near selected archaeological sites in the Colorado River corridor through Grand Canyon, Ariz. The quantitative methods and data discussed here form a basis for monitoring ecosystem processes that affect archeological-site stability. Combined with forthcoming work to evaluate landscape evolution at nearby archaeological sites, these data can be used to document the relationship between physical processes, including weather and aeolian sand transport, and their effects on the physical integrity of archaeological sites. Data collected in 2008 reveal event- and seasonal-scale variations in rainfall, wind, temperature, humidity, and barometric pressure. Broad seasonal changes in aeolian sediment flux are also apparent at most study sites. The continuation of monitoring that began in 2007, and installation of equipment at several new sites in early 2008, allowed evaluation of the effects of the March 2008 high-flow experiment (HFE) on aeolian sand transport. At two of the nine sites studied, spring and summer winds reworked 2008 HFE sandbars to form new aeolian dunes, at which sand moved inland toward larger, well-established dune fields. At the other seven study sites, neither dune formation nor enhanced sand transport after the HFE were observed. At several of those sites, dominant wind directions in spring 2008 were not oriented such that much HFE sand would have moved inland; at other sites, lack of increased inland sand flux is attributable to lack of sandbar enlargement near the study sites or to inhibition of sand movement by vegetation or local topography.

  12. Transport of citrate-coated silver nanoparticles in unsaturated sand

    Energy Technology Data Exchange (ETDEWEB)

    Kumahor, Samuel K., E-mail: [Department of Soil Physics, Helmholtz Centre for Environmental Research–UFZ, Theodor-Lieser-Strasse 4, 06120 Halle-Saale (Germany); Hron, Pavel, E-mail: [Interdisciplinary Center for Scientific Computing, University of Heidelberg, Im Neuenheimer Feld 368, Raum 422, 69120 Heidelberg (Germany); Metreveli, George, E-mail: [Universität Koblenz-Landau, Institute for Environmental Sciences, Group of Environmental and Soil Chemistry, Fortstr. 7, D-76829 Landau (Germany); Schaumann, Gabriele E., E-mail: [Universität Koblenz-Landau, Institute for Environmental Sciences, Group of Environmental and Soil Chemistry, Fortstr. 7, D-76829 Landau (Germany); Vogel, Hans-Jörg, E-mail: [Department of Soil Physics, Helmholtz Centre for Environmental Research–UFZ, Theodor-Lieser-Strasse 4, 06120 Halle-Saale (Germany); Institute of Soil Science and Plant Nutrition, Martin-Luther-University Halle-Wittenberg, Von-Seckendorff-Platz 3, 06120 Halle-Saale (Germany)


    Chemical factors and physical constraints lead to coupled effects during particle transport in unsaturated porous media. Studies on unsaturated transport as typical for soils are currently scarce. In unsaturated porous media, particle mobility is determined by the existence of an air–water interface in addition to a solid–water interface. To this end, we measured breakthrough curves and retention profiles of citrate-coated Ag nanoparticles in unsaturated sand at two pH values (5 and 9) and three different flow rates corresponding to different water contents with 1 mM KNO{sub 3} as background electrolyte. The classical DLVO theory suggests unfavorable deposition conditions at the air–water and solid–water interfaces. The breakthrough curves indicate modification in curve shapes and retardation of nanoparticles compared to inert solute. Retention profiles show sensitivity to flow rate and pH and this ranged from almost no retention for the highest flow rate at pH = 9 to almost complete retention for the lowest flow rate at pH = 5. Modeling of the breakthrough curves, thus, required coupling two parallel processes: a kinetically controlled attachment process far from equilibrium, responsible for the shape modification, and an equilibrium sorption, responsible for particle retardation. The non-equilibrium process and equilibrium sorption are suggested to relate to the solid–water and air–water interfaces, respectively. This is supported by the DLVO model extended for hydrophobic interactions which suggests reversible attachment, characterized by a secondary minimum (depth 3–5 kT) and a repulsive barrier at the air–water interface. In contrast, the solid–water interface is characterized by a significant repulsive barrier and the absence of a secondary minimum suggesting kinetically controlled and non-equilibrium interaction. This study provides new insights into particle transport in unsaturated porous media and offers a model concept representing the

  13. The influence of rainfall on transport of beach sand by wind.

    NARCIS (Netherlands)

    Dijk, van P.M.; Stroosnijder, L.; Lima, de J.L.M.P.


    This paper deals with the effect of rainfall on the process of wind erosion of beach sands and presents results from both field and wind tunnel experiments. Although sediment transport by splash is of secondary importance on coastal dunes, splash-saltation processes can move sediments in conditions

  14. Modelling of sand transport under wave-generated sheet flows with a RANS diffusion model

    NARCIS (Netherlands)

    Hassan, Wael; Ribberink, Jan S.


    A 1DV-RANS diffusion model is used to study sand transport processes in oscillatory flat-bed/sheet flow conditions. The central aim is the verification of the model with laboratory data and to identify processes controlling the magnitude and direction (‘onshore’/‘offshore’) of the net time-averaged

  15. Transport of citrate-coated silver nanoparticles in unsaturated sand (United States)

    Kumahor, Samuel; Hron, Pavel; Metreveli, George; Schaumann, Gabriele; Vogel, Hans-Jörg


    Chemical factors and physical constraints lead to coupled effects during particle transport in unsaturated porous media. Unlike for saturated transport, studies on unsaturated transport as typical for soil are currently scarce. We investigated the mobility of citrate-coated Ag NPs in unsaturated sand (grain diameter: 0.1-0.3 mm). For three flux rates and a given pore-water ionic strength (1 mM KNO3), the citrate-coated Ag NPs were less mobile at pH = 5 compared to pH = 9. The classic Derjaguin-Landau-Verwey-Overbeek (DLVO) theory suggests unfavorable deposition conditions at both, the air-water interface and solid-water interface. Breakthrough curves measured under quasi-steady state unsaturated flow showed retardation of the citrate-coated Ag NPs compared to inert solute (KBr). After flushing with nanoparticle-free 1 mM KNO3 solution (pH-adjusted), retention was much lower in deeper depths compared to the surface where the particles entered the flow field. The results show a non-linear dependence of nanoparticle (NP) mobility on flux rate and water content. Especially the observed retardation similar to equilibrium sorption is in contrast to observations under saturated flow conditions. A convection-dispersion and reaction model that combines a reversible equilibrium process and a non-equilibrium interaction process reproduced the measured breakthrough curves reasonably well. From comparison between saturated and unsaturated experiments we conclude that the air-water interface is responsible for the reversible equilibrium process while the water-solid interface accounts for irreversible soption.

  16. Effects of woody vegetation on overbank sand transport during a large flood, Rio Puerco, New Mexico (United States)

    Griffin, Eleanor R.; Perignon, Mariela C.; Friedman, Jonathan M.; Tucker, Gregory E.


    Distributions of woody vegetation on floodplain surfaces affect flood-flow erosion and deposition processes. A large flood along the lower Rio Puerco, New Mexico, in August 2006 caused extensive erosion in a reach that had been sprayed with herbicide in September 2003 for the purpose of saltcedar (Tamarix spp.) control. Large volumes of sediment, including a substantial fraction of sand, were delivered to the reach downstream, which had not been treated with herbicide. We applied physically based, one-dimensional models of flow and suspended-sediment transport to compute volume concentrations of sand in suspension in floodplain flow at a site within the sprayed reach and at a site downstream from the sprayed reach. We computed the effects of drag on woody stems in reducing the skin friction shear stress, velocity of flow, and suspended-sand transport from open paths into patches of dense stems. Total flow and suspended-sand fluxes were computed for each site using well-constrained flood-flow depths, water-surface slopes, and measured shrub characteristics. Results show that flow in open paths carried high concentrations of sand in suspension with nearly uniform vertical distributions. Drag on woody floodplain stems reduced skin friction shear stresses by two orders of magnitude, yet sufficient velocities were maintained to transport sand more than 50 m into fields of dense, free-surface-penetrating stems. An increase in shrub canopy extent from 31% in the sprayed reach site to 49% in the downstream site was found to account for 69% of the computed decrease in discharge between the two sites. The results demonstrate the need to compute the spatial distribution of skin friction shear stress in order to effectively compute suspended-sand transport and to predict the fate of sediment and contaminants carried in suspension during large floods.

  17. Oblique second-order sand transport pathways on an intertidal sand flat in a natural tidal inlet system

    DEFF Research Database (Denmark)

    Ernstsen, Verner Brandbyge; Lefebvre, Alice; Kroon, Aart


    A detailed digital elevation model (DEM) of an intertidal sand flat in the Knudedyb tidal inlet in the Danish Wadden Sea, derived from high-resolution Light Detection And Ranging (LiDAR) data, reveals a large elongated bedform field with complex bedform morphologies and drainage channel networks....... This indicates distinct second-order sand transport pathways oblique to the main tidal transport pathways. A conceptual model for the development of the bedforms and channels is presented, which comprises hypotheses of the hydrodynamic forcing of the different second-order sand transport pathways. During flood...

  18. Microwave processing of oil sands and contribution of clay minerals


    John P. Robinson; Binner, Eleanor; Saeid, Abdul; Al-Harahsheh, Mohammad; Kingman, S. W.


    This study establishes the feasibility of microwave heating for extracting oil from Oil Sands in ex-situ processes. Previous studies in this area have shown some potential, but have not characterised the dielectric properties of the Oil Sands used, nor related them to the mineral composition, both of which are vital if successful scale up is to be achieved. In this work the fundamental interactions of microwave energy with Oil Sands are investigated and understood for the first time, and the ...

  19. Microwaves energy in curing process of water glass molding sands

    Directory of Open Access Journals (Sweden)

    Granat K.


    Full Text Available This work presents the results of investigation of microwave heating on hardening process of water glass molding sands. Essential influence of this heating process on basic properties such as: compression, bending and tensile strength as well as permeability and abrasion resistance has been found. It has been proved, that all investigated sorts of sodium water glass with a module between 2.0 and 3.3 can be used as a binder of molding sands in microwave curing process. It has been found during analysis of research results of sands with 2.5 % water glass addition that they are practically the same as in case of identical molding sands dried for 120 minutes at the temperature of 110°C, used for comparative purposes. Application of microwave curing of molding sands with water glass, however, guarantees reduction of hardening time (from 120 to 4 minutes as well as significant reduction of energy consumption. Attempts of two stage hardening of the investigated water glass molding sands have also been carried out, that is after an initial hardening during a classical CO2 process (identical sands have also been tested for comparison after CO2 blowing process and additional microwave heating. It has been found that application of this kind of treatment for curing sands with 2.5 % sodium water glass content and module from 2.0 up to 3.3 results in the improvement of properties in comparison to classical CO2 process.

  20. Batch and column studies of adsorption of Li, Ni and Br by a reference sand for contaminant transport experiments

    Energy Technology Data Exchange (ETDEWEB)

    Seigel, M.D. [Sandia National Labs., Albuquerque, NM (United States); Ward, D.B.; Bryan, C.R. [Univ. of New Mexico, Albuquerque, NM (United States)] [and others


    A processed quartz sand (Wedron 510), mined from the St. Peter sandstone, has been characterized by a variety of chemical and physical methods for use as a reference porous media in transport model validation experiments. Wedron 510 sand was used in an intermediate-scale experiment involving migration of Ni, Li and Br through a 6-m high x 3-m diameter caisson. Ni and Li adsorption/desorption, and Li/Ni site-competition experiments yielded information on the importance of the trace mineral phases to adsorption of Li and Ni by the sand. The presence of an iron hydroxide coating similar to goethite on the sand grains is suggested by visual observation and leaching experiments. Kaolinite was identified by SEM and XRD as a significant trace mineral phase in the sand and occurs as small particles coating the sand grains. Quartz, the predominant constituent of the sand by weight, does not appear to contribute significantly to the adsorption properties of the sand. Qualitatively, the adsorption properties of the sand can be adequately modeled as a two-mineral system (goethite and kaolinite). The studies described in this report should provide a basis for understanding transport of Ni, Li and Br through porous media similar to the reference sand. Techniques were developed for obtaining parameter values for surface complexation and kinetic adsorption models for the sand and its mineral components. These constants can be used directly in coupled hydrogeochemical transport codes. The techniques should be useful for characterization of other natural materials and elements in high-level nuclear waste in support of coupled hydrogeochemical transport calculations for Yucca Mountain.

  1. A Comparative Study on Sand Transport Modeling for Horizontal Multiphase Pipeline

    Directory of Open Access Journals (Sweden)

    Kan Wai Choong


    Full Text Available Presence of sand causes adverse effects on hydrocarbon production, pipeline erosion and problems at wellbore. If the problems persist, production may be stopped and delayed. This imposes workover cost. Hence, operating expenses increase and revenue reduces. There is no explicit calculation algorithm for sand transportation modeling readily available in flow simulators. Therefore, this study aims to develop an Excel-based spreadsheet on sand transportation to predict sand critical velocity and onset of sand deposition based on published literature. The authors reviewed nine sand transportation models in pipelines and made comparisons on the selected models based on various criteria. Four of which were then developed into a sand modeling spreadsheet. The four models are the Turian et al. (1987, Oudeman (1993, Stevenson et al. (2002b Model and Danielson (2007. The spreadsheet presently focuses on sand production prediction in horizontal two-phase flow. The Danielson model can predict sand hold up while the other models estimate grain size transportable and critical velocity of sand. Flowing pipeline properties, sand properties and results of simulations like using OLGA (for flow rate, velocity and superficial velocity of different phases are necessary inputs of the spreadsheet. A user selects any model based on different operating conditions or user preference. The spreadsheet was validated by comparing data extracted from the research papers. Sensitivity analyses can also be performed with the spreadsheet by manipulating the parameters such as grain size and flow rate. This review is useful for flow simulators’ development to include sand transport modeling.

  2. The role of suspended load transport in the occurrence of tidal sand waves

    NARCIS (Netherlands)

    Borsje, B.W.; Kranenburg, W.M.; Roos, P.C.; Matthieu, J.; Hulscher, S.J.M.H.


    Tidal sand waves are dynamic bed patterns which are formed by the complex interaction between hydrodynamics, sediment transport, and geomorphology. Field data from the southern North Sea reveal that sand waves are absent where suspended load transport is the dominant transport mode. In order to unde

  3. The role of suspended load transport in the occurrence of tidal sand waves

    NARCIS (Netherlands)

    Borsje, Bastiaan Wijnand; Kranenburg, Wouter; Roos, Pieter C.; Matthieu, J.; Hulscher, Suzanne J.M.H.


    Tidal sand waves are dynamic bed patterns which are formed by the complex interaction between hydrodynamics, sediment transport, and geomorphology. Field data from the southern North Sea reveal that sand waves are absent where suspended load transport is the dominant transport mode. In order to unde

  4. Sequential Subterranean Transport of Excavated Sand and Foraged Seeds in Nests of the Harvester Ant, Pogonomyrmex badius. (United States)

    Tschinkel, Walter R; Rink, William J; Kwapich, Christina L


    During their approximately annual nest relocations, Florida harvester ants (Pogonomyrmex badius) excavate large and architecturally-distinct subterranean nests. Aspects of this process were studied by planting a harvester ant colony in the field in a soil column composed of layers of 12 different colors of sand. Quantifying the colors of excavated sand dumped on the surface by the ants revealed the progress of nest deepening to 2 m and enlargement to 8 L in volume. Most of the excavation was completed within about 2 weeks, but the nest was doubled in volume after a winter lull. After 7 months, we excavated the nest and mapped its structure, revealing colored sand deposited in non-host colored layers, especially in the upper 30 to 40 cm of the nest. In all, about 2.5% of the excavated sediment was deposited below ground, a fact of importance to sediment dating by optically-stimulated luminescence (OSL). Upward transport of excavated sand is carried out in stages, probably by different groups of ants, through deposition, re-transport, incorporation into the nest walls and floors and remobilization from these. This results in considerable mixing of sand from different depths, as indicated in the multiple sand colors even within single sand pellets brought to the surface. Just as sand is transported upward by stages, incoming seeds are transported downward to seed chambers. Foragers collect seeds and deposit them only in the topmost nest chambers from which a separate group of workers rapidly transports them downward in increments detectable as a "wave" of seeds that eventually ends in the seed chambers, 20 to 80 cm below the surface. The upward and downward transport is an example of task-partitioning in a series-parallel organization of work carried out by a highly redundant work force in which each worker usually completes only part of a multi-step process.

  5. Computational fluid dynamics simulation of transport and retention of nanoparticle in saturated sand filters

    Energy Technology Data Exchange (ETDEWEB)

    Hassan, Ashraf Aly [U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, 26 W. Martin Luther King Drive, Cincinnati, OH 45268 (United States); Li, Zhen [School of Energy, Environmental, Biological, and Medical Engineering, Environmental Engineering Program, University of Cincinnati, Cincinnati, OH (United States); Sahle-Demessie, Endalkachew, E-mail: [U.S. Environmental Protection Agency, Office of Research and Development, National Risk Management Research Laboratory, 26 W. Martin Luther King Drive, Cincinnati, OH 45268 (United States); Sorial, George A. [School of Energy, Environmental, Biological, and Medical Engineering, Environmental Engineering Program, University of Cincinnati, Cincinnati, OH (United States)


    Highlights: ► Breakthrough curves used to study fate of NPs in slow sand filters (SSF). ► CFD simulate transport, attachment/detachment of NPs in SSFs. ► CFD predicted spatial and temporal changes for transient concentrations of NPs. ► CFD predicts low concentrations and steady NP influx would not be retained by SSFs. ► Pulse input is retained with outlet concentration of 0.2% of the inlet. -- Abstract: Experimental and computational investigation of the transport parameters of nanoparticles (NPs) flowing through porous media has been made. This work intends to develop a simulation applicable to the transport and retention of NPs in saturated porous media for investigating the effect of process conditions and operating parameters such, as ion strength, and filtration efficiency. Experimental data obtained from tracer and nano-ceria, CeO{sub 2}, breakthrough studies were used to characterize dispersion of nanoparticle with the flow and their interaction with sand packed columns with different heights. Nanoparticle transport and concentration dynamics were solved using the Eulerian computational fluid dynamics (CFD) solver ANSYS/FLUENT{sup ®} based on a scaled down flow model. A numerical study using the Navier–Stokes equation with second order interaction terms was used to simulate the process. Parameters were estimated by fitting tracer, experimental NP transport data, and interaction of NP with the sand media. The model considers different concentrations of steady state inflow of NPs and different amounts of spike concentrations. Results suggest that steady state flow of dispersant-coated NPs would not be retained by a sand filter, while spike concentrations could be dampened effectively. Unlike analytical solutions, the CFD allows estimating flow profiles for structures with complex irregular geometry and uneven packing.

  6. Aerolian erosion, transport, and deposition of volcaniclastic sands among the shifting sand dunes, Christmas Lake Valley, Oregon: TIMS image analysis (United States)

    Edgett, Kenneth S.; Ramsey, Michael S.; Christensen, Philip R.


    Remote sensing is a tool that, in the context of aeolian studies, offers a synoptic view of a dune field, sand sea, or entire desert region. Blount et al. (1990) presented one of the first studies demonstrating the power of multispectral images for interpreting the dynamic history of an aeolian sand sea. Blount's work on the Gran Desierto of Mexico used a Landsat TM scene and a linear spectral mixing model to show where different sand populations occur and along what paths these sands may have traveled before becoming incorporated into dunes. Interpretation of sand transport paths and sources in the Gran Desierto led to an improved understanding of the origin and Holocene history of the dunes. With the anticipated advent of the EOS-A platform and ASTER thermal infrared capability in 1998, it will become possible to look at continental sand seas and map sand transport paths using 8-12 mu m bands that are well-suited to tracking silicate sediments. A logical extension of Blount's work is to attempt a similar study using thermal infrared images. One such study has already begun by looking at feldspar, quartz, magnetite, and clay distributions in the Kelso Dunes of southern California. This paper describes the geology and application of TIMS image analysis of a less-well known Holocene dune field in south central Oregon using TIMS data obtained in 1991.

  7. The dune effect on sand-transporting winds on Mars (United States)

    Jackson, Derek W. T.; Bourke, Mary C.; Smyth, Thomas A. G.


    Wind on Mars is a significant agent of contemporary surface change, yet the absence of in situ meteorological data hampers the understanding of surface-atmospheric interactions. Airflow models at length scales relevant to landform size now enable examination of conditions that might activate even small-scale bedforms (ripples) under certain contemporary wind regimes. Ripples have the potential to be used as modern `wind vanes' on Mars. Here we use 3D airflow modelling to demonstrate that local dune topography exerts a strong influence on wind speed and direction and that ripple movement likely reflects steered wind direction for certain dune ridge shapes. The poor correlation of dune orientation with effective sand-transporting winds suggests that large dunes may not be mobile under modelled wind scenarios. This work highlights the need to first model winds at high resolution before inferring regional wind patterns from ripple movement or dune orientations on the surface of Mars today.

  8. The dune effect on sand-transporting winds on Mars. (United States)

    Jackson, Derek W T; Bourke, Mary C; Smyth, Thomas A G


    Wind on Mars is a significant agent of contemporary surface change, yet the absence of in situ meteorological data hampers the understanding of surface-atmospheric interactions. Airflow models at length scales relevant to landform size now enable examination of conditions that might activate even small-scale bedforms (ripples) under certain contemporary wind regimes. Ripples have the potential to be used as modern 'wind vanes' on Mars. Here we use 3D airflow modelling to demonstrate that local dune topography exerts a strong influence on wind speed and direction and that ripple movement likely reflects steered wind direction for certain dune ridge shapes. The poor correlation of dune orientation with effective sand-transporting winds suggests that large dunes may not be mobile under modelled wind scenarios. This work highlights the need to first model winds at high resolution before inferring regional wind patterns from ripple movement or dune orientations on the surface of Mars today.

  9. The dune effect on sand-transporting winds on Mars (United States)

    Jackson, Derek W. T.; Bourke, Mary C; Smyth, Thomas A. G.


    Wind on Mars is a significant agent of contemporary surface change, yet the absence of in situ meteorological data hampers the understanding of surface–atmospheric interactions. Airflow models at length scales relevant to landform size now enable examination of conditions that might activate even small-scale bedforms (ripples) under certain contemporary wind regimes. Ripples have the potential to be used as modern ‘wind vanes' on Mars. Here we use 3D airflow modelling to demonstrate that local dune topography exerts a strong influence on wind speed and direction and that ripple movement likely reflects steered wind direction for certain dune ridge shapes. The poor correlation of dune orientation with effective sand-transporting winds suggests that large dunes may not be mobile under modelled wind scenarios. This work highlights the need to first model winds at high resolution before inferring regional wind patterns from ripple movement or dune orientations on the surface of Mars today. PMID:26537669

  10. Geomorphology and sediment transport on a submerged back-reef sand apron: One Tree Reef, Great Barrier Reef (United States)

    Harris, Daniel L.; Vila-Concejo, Ana; Webster, Jody M.


    Back-reef sand aprons are conspicuous and dynamic sedimentary features in coral reef systems. The development of these features influences the evolution and defines the maturity of coral reefs. However, the hydrodynamic processes that drive changes on sand aprons are poorly understood with only a few studies directly assessing sediment entrainment and transport. Current and wave conditions on a back-reef sand apron were measured during this study and a digital elevation model was developed through topographic and bathymetric surveying of the sand apron, reef flats and lagoon. The current and wave processes that may entrain and transport sediment were assessed using second order small amplitude (Stokes) wave theory and Shields equations. The morphodynamic interactions between current flow and geomorphology were also examined. The results showed that sediment transport occurs under modal hydrodynamic conditions with waves the main force entraining sediment rather than average currents. A morphodynamic relationship between current flow and geomorphology was also observed with current flow primarily towards the lagoon in shallow areas of the sand apron and deeper channel-like areas directing current off the sand apron towards the lagoon or the reef crest. These results show that the short-term mutual interaction of hydrodynamics and geomorphology in coral reefs can result in morphodynamic equilibrium.

  11. Monitoring and characterisation of sand-mud sedimentation processes (United States)

    Cuthbertson, Alan J. S.; Ibikunle, Olugbenga; McCarter, W. John; Starrs, Gerard


    Estuaries and tidal inlets are often characterised by the presence of both cohesive and non-cohesive sediments. Knowledge of the sedimentation behaviour of sand-mud mixtures is therefore crucial to the understanding and prediction of the time-dependent structure (i.e. mixed or segregated), composition and erodibility of sediment bed deposits developing within these environments. In the current study, a series of settling column tests are conducted to investigate the hindered settling and initial bed consolidation phases of a range of sand-clay mixtures to determine the parametric conditions under which bed segregation occurs. A new, non-invasive, electrical resistivity measurement technique is employed to capture both temporal and spatial changes in the density, porosity and composition of the evolving sand-clay bed deposits, complimented by time-lapsed images of the sedimentation process within the column. The results show that the formation of segregated (sand-clay) bed layers with bed deposits is largely controlled by the initial fractional composition (i.e. relative sand and clay concentrations). Specifically, mixtures with low clay contents are shown to form well-defined (sand-clay) layer segregation within the resulting deposits, while higher clay contents result in more transitional segregation patterns or no layer segregation (for very high clay concentrations). The physical mechanisms under which these different segregation types can be generated are illustrated through predictions from an existing polydisperse hindered settling model. This model indicates that the degree of bed segregation, and time scale over which this occurs, correlates well with the difference in predicted hindered settling characteristics and upward displacements associated with the sand and clay fractions, respectively. In this regard, the new experimental dataset provides validation for the polydisperse model (for the first time), with the combined data and model predictions

  12. Agglomeration of a comprehensive model for the wind-driven sand transport at the Belgian Coast (United States)

    Strypsteen, Glenn; Rauwoens, Pieter


    Although a lot of research has been done in the area of Aeolian transport, it is only during the last years that attention has been drawn to Aeolian transport in coastal areas. In these areas, the physical processes are more complex, due to a large number of transport limiting parameters. In this PhD-project, which is now in its early stage, a model will be developed which relates the wind-driven sand transport at the Belgian coast with physical parameters such as the wind speed, humidity and grain size of the sand, and the slope of beach and dune surface. For the first time, the interaction between beach and dune dynamics is studied at the Belgian coast. The Belgian coastline is only 67km long, but densely populated and therefore subject to coastal protection and safety. The coast mostly consists of sandy beaches and dikes. Although, still 33km of dunes exist, whose dynamics are far less understood. The overall research approach consists of three pathways: (i) field measurements, (ii) physical model tests, and (iii) numerical simulations. Firstly and most importantly, several field campaigns will provide accurate data of meteo-marine conditions, morphology, and sand transport events on a wide beach at the Belgian Coastline. The experimental set-up consists of a monitoring station, which will provide time series of vegetation cover, shoreline position, fetch distances, surficial moisture content, wind speed and direction and transport processes. The horizontal and vertical variability of the event scale Aeolian sand transport is analyzed with 8 MWAC sand traps. Two saltiphones register the intensity and variations of grain impacts over time. Two meteo-masts, each with four anemometers and one wind vane, provide quantitative measurements of the wind flow at different locations on the beach. Surficial moisture is measured with a moisture sensor. The topography measurements are typically done with laser techniques. To start, two sites are selected for measurement

  13. The Effect of Air Density on Sand Transport Structures and the Adobe Abrasion Profile: A Field Wind-Tunnel Experiment Over a Wide Range of Altitude (United States)

    Han, Qingjie; Qu, Jianjun; Dong, Zhibao; Zu, Ruiping; Zhang, Kecun; Wang, Hongtao; Xie, Shengbo


    Aeolian sand transport results from interactions between the surface and the airflow above. Air density strongly constrains airflow characteristics and the resulting flow of sand, and therefore should not be neglected in sand transport models. In the present study, we quantify the influence of air density on the sand flow structure, sand transport rate, adobe abrasion profiles, and abrasion rate using a portable wind-tunnel in the field. For a given wind speed, the flow's ability to transport sand decreases at low air density, so total sand transport decreases, but the saltation height increases. Thus, the damage to human structures increases compared with what occurs at lower altitudes. The adobe abrasion rate by the cloud of blowing sand decreases exponentially with increasing height above the surface, while the wind erosion and dust emission intensity both increase with increasing air density. Long-term feedback processes between air density and wind erosion suggest that the development of low-altitude areas due to long-term deflation plays a key role in dust emission, and will have a profound significance for surface Aeolian processes and geomorphology.

  14. Potential for in situ chemical oxidation of acid extractable organics in oil sands process affected groundwater. (United States)

    Sohrabi, V; Ross, M S; Martin, J W; Barker, J F


    The process of bitumen extraction from oil sands in Alberta, Canada leads to an accumulation of toxic acid-extractable organics (AEOs) in oil sands process water (OSPW). Infiltration of OSPW from tailings ponds and from their retaining sand dykes and subsequent transport towards surface water has occurred. Given the apparent lack of significant natural attenuation of AEOs in groundwater, remediation may be required. This laboratory study evaluates the potential use of unactivated persulfate and permanganate as in situ oxidation agents for remediation of AEOs in groundwater. Naphthenic acids (NAs; CnH2n+zO2), which are a component of the acutely toxic AEOs, were degraded by both oxidants in OSPW samples. Permanganate oxidation yielded some residual dissolved organic carbon (DOC) whereas persulfate mineralized the AEO compounds with less residual DOC. Acid-extractable organics from oxidized OSPW had essentially no Microtox toxicity.

  15. Blocking effect of colloids on arsenate adsorption during co-transport through saturated sand columns. (United States)

    Ma, Jie; Guo, Huaming; Lei, Mei; Wan, Xiaoming; Zhang, Hanzhi; Feng, Xiaojuan; Wei, Rongfei; Tian, Liyan; Han, Xiaokun


    Transport of environmental pollutants through porous media is influenced by colloids. Co-transport of As(V) and soil colloids at different pH were systematically investigated by monitoring breakthrough curves (BTCs) in saturated sand columns. A solute transport model was applied to characterize transport and retention sites of As(V) in saturated sand in the presence of soil colloids. A colloid transport model and the DLVO theory were used to reveal the mechanism and hypothesis of soil colloid-promoted As(V) transport in the columns. Results showed that rapid transport of soil colloids, regulated by pH and ionic strength, promoted As(V) transport by blocking As(V) adsorption onto sand, although soil colloids had low adsorption for As(V). The promoted transport was more significant at higher concentrations of soil colloids (between 25 mg L(-1) and 150 mg L(-1)) due to greater blocking effect on As(V) adsorption onto the sand surfaces. The blocking effect of colloids was explained by the decreases in both instantaneous (equilibrium) As adsorption and first-order kinetic As adsorption on the sand surface sites. The discovery of this blocking effect improves our understanding of colloid-promoted As transport in saturated porous media, which provides new insights into role of colloids, especially colloids with low As adsorption capacity, in As transport and mobilization in soil-groundwater systems. Copyright © 2016 Elsevier Ltd. All rights reserved.

  16. Laser particle counter validation for aeolian sand transport measurements using a highspeed camera

    NARCIS (Netherlands)

    Duarte Campos, Leonardo Andres; Wijnberg, Kathelijne Mariken; Oyarte Galvez, Loreto Alejandra; Hulscher, Suzanne J.M.H.


    Measuring aeolian sand transport rates in the field has been a long-standing challenge. In this paper, we present the results of a laboratory experiment to test the ability of a laser particle counter sensor (Wenglor) to accurately count sand grains of various grain size classes and stainless steel

  17. Aeolian sand transport and its effects on the stability of Miramar-Caranzalem beach

    Digital Repository Service at National Institute of Oceanography (India)

    Reddy, G.V.; Sastry, J.S.

    Removal of sand by wind from the beach at Miramar-Caranzalem, Goa, has been found to effect its stability over a relatively longer time scale. This aeolian sand transport has been computed for this strip of the beach utilising the relation between...

  18. Cavity prediction in sand mould production applying the DISAMATIC process

    DEFF Research Database (Denmark)

    Hovad, Emil; Larsen, Per; Spangenberg, Jon


    The sand shot in the DISAMATIC process is simulated by the discrete element method (DEM) taking into account the influence and coupling of the airflow with computational fluid dynamics (CFD). The DEM model is calibrated by a ring shear test, a sand pile experiment and a slump test. Subsequently...... with three cases of different air vent settings which control the ventilation of the chamber. These settings resulted in different air- and particle-velocities as well as different accumulated masses in the cavities, which were successfully simulated by the model....

  19. New Look at the Process of Reclamation of Moulding Sands

    Directory of Open Access Journals (Sweden)

    Dobosz S.M.


    Full Text Available This paper presents a new perspective on the issue of reclamation of moulding and core sands. Taking as a premise that the reclamation process must remain on the surface of grains some not separated binding materials rests, it should be chosen the proper moulding sand’s composition that will be least harmful for the reclaim quality. There are two different moulding and core sands taken into examinations. The researches prove that a small correction of their compositions (hardener type improves the quality of the received reclaims. Carried out in this article studies have shown that such an approach to the problem of reclamation of the moulding and core sands is needed and reasonable.

  20. Beach Sand Supply and Transport at Kunduchi in Tanzania and ...

    African Journals Online (AJOL)

    OCEAN. Mombasa. Dar es. Salaam. KUNDUCHI. KENYA. TANZANIA ... Figure 2. a) Reef-platform transects at Bamburi. b) Beach plain sand ..... comprised coral debris covered by turf algae .... and ocean acidification should not be ruled.

  1. Facilitated transport of heavy metals by bacterial colloids in sand columns (United States)

    Guiné, V.; Martins, J.; Gaudet, J. P.


    The aim of this work is to evaluate the ability of biotic collois (e.g. bacterial cells) to facilitate the transport of heavy metals in soils. and to identify the main factors influencing colloid transport in order to detelmine the geo-chemical conditions where this secondary transport process may become dominant. The model colloids studied here are living cells of Escherichia coli and Ralstonia metallidurans. We studied the transport of mercury zinc, and cadmium in columns of Fontainebleau sand. The properties (i.e. optical and morphological properties, charge (zeta potential, zeta) and hydrophobia (water/hexadecane distribution parameter, K_{hw})) of the bacterial cells surface were characterised, as well as their potential for heavy metals sorption (kinetic and isotherm). Both surface charge (zeta=-54 and -14 mV) and hydrophobia (K_{hw} = 0.25 and 0.05) differ strongly for the two bacteria. Column studies were conducted with bacteria and heavy metals separately or simultaneously. The cell surface differences led to different transport behaviour of the two bacteria, although the retardation factor is close to 1 for both. We observed that colloid mobility increases when increasing bacterial cells concentration and when decreasing the ionic strength. We also observed that bacterial colloids appeared as excellent vectors for Hg, Zn and Cd. Indeed, heavy metals adsorbed on the Fontainebleau sand when injected alone in columns (retardation factors of 1.4 ; 2.9 and 3.8 for Hg, Zn and Cd, respectively); whereas no retardation (R≈1) is observed when injected in the presence of both bacteria. Moreover, transport of bio-sorbed metal appears to be 4 to 6 times higher than dissolved heavy-metal.

  2. Physical Modeling of the Cross-Shore Sediment Transport on a Sand-Gravel Beach (United States)

    Xharde, Regis; Brunelle, Corinne; Frandsen, Jannette


    The aim of the study is to investigate the cross-shore evolution of a nourished beach profile under storm wave conditions with specific emphasis on sediment transport within the breaking zone. To investigate the underlying mechanisms of the coastal transport processes, a physical model of the beach was built at scale 1:3 in the new Quebec Coastal Physics Laboratory (QCPL), Canada. The modeled beach is 4.2 m high, 5 m wide and 40 m long with a mean slope of 1:10. The beach is formed of a mixture of sediment with grain sizes ranging from 0.65 mm up to 20 mm. The stability of the beach is tested for operational and storm waves. We report on run-up and run-down processes via wave gages, video records of waves and ultrasonic water level measurements. Sediment transport processes within the surf zone and on the beach face are monitored using acoustic Doppler profilers and optical backscattering sensors. The beach profile is surveyed prior and after each test series using a topographic laser scanner. Initial results show that sand is transported off-shore to a breaker bar while cobbles are pushed on the upper beach by run-up. Details of the underlying mechanism of different breaker types and impact on sediment transport will be presented.

  3. Predicting bed load transport of sand and gravel on Goodwin Creek (United States)

    Bed load transport rates are difficult to predict in channels with bed material composed of sand and gravel mixtures. The transport of bed load was measured on Goodwin Creek, and in a laboratory flume channel with a similar bed material size distribution. The range of bed load transport rates meas...

  4. Flow Dynamics of green sand in the DISAMATIC moulding process using Discrete element method (DEM)

    DEFF Research Database (Denmark)

    Hovad, Emil; Larsen, P.; Walther, Jens Honore


    The DISAMATIC casting process production of sand moulds is simulated with DEM (discrete element method). The main purpose is to simulate the dynamics of the flow of green sand, during the production of the sand mould with DEM. The sand shot is simulated, which is the first stage of the DISAMATIC...

  5. Coagulation-flocculation pretreatment of oil sands process affected water

    Energy Technology Data Exchange (ETDEWEB)

    Pourrezaei, P.; El-Din, M.G. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering


    This presentation addressed the issue of water use in the oil sands industry and efforts to use this limited resource more efficiently. Three wastewater treatment schemes for oil sands tailings ponds were proposed, notably primary, secondary and tertiary treatment. Primary treatment involves the removal of suspended solids using physical-chemical treatments. Secondary treatment involves the removal of dissolved solids and organics using chemical oxidation, ultrafiltration or nanofiltration. Tertiary treatment involves removal of residual organics/solids using biological activated carbon filtration, sand filtration or reverse osmosis. The composition of oil sands process water (OSPW) was also discussed with reference to suspended solids, salts, hydrocarbons, other dissolved organics (such as naphthenic acids and phenols), ammonia, inorganic compounds and trace elements. The conventional coagulation/flocculation process is essential in industrial wastewater treatment. It is cost effective, easy to operate and energy efficient. The process is used because small suspended and colloidal particles and dissolved constituents cannot be removed quickly by sedimentation. A chemical method must be used. Coagulation/flocculation brings small suspended and colloidal particles into contact so that they collide, stick and grow to a size that settles readily. Alum is the predominant and least expensive water treatment coagulant used for the coagulation/flocculation process. It provides positively charged ions to neutralize the negative charge of colloidal particles resulting in aggregation. It creates big settling flocs that enmesh colloids as it settles. The factors affecting the process include pH, chemical type, chemical concentration, rapid mixing intensity, slow mixing intensity and time. tabs., figs.

  6. Oil sand process-affected water treatment using coke adsorption

    Energy Technology Data Exchange (ETDEWEB)

    Gamal El-Din, M.; Pourrezaei, P.; Chelme-Ayala, P.; Zubot, W. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering


    Oil sands operations generate an array of oil sands process-affected water (OSPW) that will eventually be released to the environment. This water must be evaluated within conventional and advanced water treatment technologies. Water management strategies propose options for increased reuse and recycling of water from settling ponds, as well as safe discharge. This presentation outlined the typical composition of OSPW. Constituents of concern in OSPW include suspended solids, hydrocarbons, salts, ammonia, trace metals, and dissolved organics such as naphthenic acids (NAs). Petroleum coke is one of the by-products generated from bitumen extraction in the oil sands industry and can be used as one of the possible treatment processes for the removal of organic compounds found in OSPW. Activated carbon adsorption is an effective process, able to adsorb organic substances such as oils, radioactive compounds, petroleum hydrocarbons, poly aromatic hydrocarbons and various halogenated compounds. The objectives of this study were to evaluate the production of activated carbon from petroleum coke using steam as the activation media; to determine the factors affecting the absorption of NAs; and to evaluate the activated coke adsorption capacity for the reduction of NAs and dissolved organic carbons present in OSPW. It was concluded that petroleum non-activated coke has the ability to decrease COD, alkalinity, and NA concentration. tabs., figs.

  7. Advanced testing and characterization of transportation soils and bituminous sands

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph


    Full Text Available This research study was intended to develop laboratory test procedures for advance testing and characterization of fine-grained cohesive soils and oil sand materials. The test procedures are based on typical field loading conditions and the loading...

  8. Natural headland sand bypassing; towards identifying and modelling the mechanisms and processes

    NARCIS (Netherlands)

    Bin Ab Razak, M.S.


    Natural headland sand bypassing: Towards identifying and modelling the mechanisms and processes contributes to the understanding of the mechanisms and processes of sand bypassing in artificial and non-artificial coastal environments through a numerical modelling study. Sand bypassing processes in ge

  9. A Multiphase First Order Model for Non-Equilibrium Sand Erosion, Transport and Sedimentation

    CERN Document Server

    Preziosi, Luigi; Bruno, Luca


    Three phenomena are involved in sand movement: erosion, wind transport, and sedimentation. This paper presents a comprehensive easy-to-use multiphase model that include all three aspects with a particular attention to situations in which erosion due to wind shear and sedimentation due to gravity are not in equilibrium. The interest is related to the fact that these are the situations leading to a change of profile of the sand bed.

  10. Bedload transport of sand-gravel mixtures with antidunes: flume experiments


    Núñez González, Francisco


    In this thesis, the interaction between flow and sediment in alluvial channels is studied from an empirical approach, for conditions close or pertaining to supercritical flow, and for four types of sediment: sand, gravel and two mixtures with sand and gravel in a relative proportion of 70-30 and 55-45, respectively. The objective is to obtain by means of laboratory experiments a data set with the characteristics of flow, sediment transport, bed configurations and sediment sorting patterns in ...

  11. Seismic behavior of tire waste-sand mixtures for transportation infrastructure in cold regions

    Institute of Scientific and Technical Information of China (English)

    Aye Edinliler; Ozgur Yildiz


    Tire wastes have many properties that are valuable from a geotechnical engineering perspective, such as low density, high strength, thermal insulation, energy absorption capacity, permeability, durability, compressibility, resilience, and high frictional strength. Thus, tire wastes offer good thermal characteristics in resisting frost penetration and have good drainage characteristics, being as permeable as coarse granular soil for fill materials. The many advantages of tire wastes make the material suitable for transportation infrastructure construction in cold regions. Also, tire wastes with high damping prop-erty make them a preferable admixture with sand for transportation infrastructures in seismic regions. This study aimed to determine the seismic performance of certain tire waste-sand mixtures in cold regions. A 70% sand-30% tire crumb mixture by weight (TC30) with a very high damping property was selected for analysis as an engineering material for transportation infrastructure. Small-scale shake-table tests were conducted on this material as well as on a sand-only sample under two different temperatures, 0 °C and 20 °C, to simulate cold-region and moderate-temperature performance, respectively. The 1999İzmit Earthquake Excitation (EW) (Mw=7.4) was taken as the input motion. Test results showed that the tire waste-sand mixture at 0 °C showed better seismic performance than that at room temperature, suggesting that a tire waste-sand mixture in cold regions may reduce seismic hazards to infrastructure.

  12. Sand Dune Encroachment and Desertification Processes of the Rigboland Sand Sea, Central Iran. (United States)

    Ahmady-Birgani, Hesam; McQueen, Kenneth G; Moeinaddini, Mazaher; Naseri, Hamidreza


    Early studies on sand dune movement and desertification in Iran have not always been convincingly demonstrated because of problems with the field-based measurements. In some areas where various land uses have been engulfed by aeolian sand dunes, desertification is clear, but in other less settled areas, it may not be so obvious. The objective of this study is to demonstrate encroachments of the Rigboland sand sea, central Iran, in its different directions and variable magnitude rates. Determining the rate and direction of the sand sea movements is critical for specifying which lands should be prioritized and quickly protected. The study has trialed a change detection technique which uses a Cross-Tabulation module to compare two available LandsatTM images over the Rigboland sand sea. This indicates that within a ten-year span (from 1988 to 1998) more than 200 ha/yr were added to the Rigboland sand sea, from the alluvial fan landforms in the eastern upstream, outer margins of the Rigboland sand sea. Coupled with GIS techniques, this type of analysis of the remote sensing (RS) images provides an effective tool for the monitoring and prognostication of sand dune movement and sand sea change.

  13. On the application of heat integration in oil sands processing

    Energy Technology Data Exchange (ETDEWEB)

    Salama, A.I.A. [Natural Resources Canada, Devon, AB (Canada). CANMET Western Research Centre


    During bitumen recovery, process heat is generated by burning natural gas or by using electrical energy that is also generated from a hydrocarbon source, typically coal. This adds carbon dioxide (CO{sub 2}) emissions to the atmosphere and contributes to global warming. The Canadian oil sands industry is challenged by stringent environmental regulations, including Kyoto Protocol obligations. In order to address the challenge of reducing CO{sub 2} emissions to the atmosphere, the oil sands industry has adopted more efficient operations, has implemented heat and process integration and efficient energy management into its bitumen recovery operations. In particular, it has targeted the optimal integration of the supply and removal of heat among the process streams. The use of heat integration schemes results in conservation of heat energy and reductions in utility requirements, energy consumption, and production cost per unit of production. This paper described a heat exchanger network (HEN) design automation using pinch technology in which the existing problem table algorithm (PTA) is used to determine the optimal heat energy targets. It then proposed a simple modification of the existing PTA and presented a newly developed and improved algorithm called the simple problem table algorithm (SPTA) that eliminates the lumping stage in the PTA. The algorithm is used to determine the optimal heat energy targets. The main objective of this method is to save expense by maximizing process to-process heat recovery. This also reduces the external utility requirements for steam and cooling water. 22 refs., 4 tabs., 7 figs.

  14. Computer Modeling of Sand Transport on Mars Using a Compart-Mentalized Fluids Algorithm (CFA) (United States)

    Marshall, J.; Stratton, D.


    It has been postulated that aeolian transport on Mars may be significantly different from that on Earth. From laboratory experiments simulating martian grain transport [2], it has been observed that (saltating) grains striking the bed can cause hundreds of secondary reptation trajectories when impact occurs at speeds postulated for Mars. Some of the ballistically induced trajectories "die ouf' and effectively join the ranks on the creep population that is merely nudged along by impact. Many of the induced reptation trajectories, however, are sufficiently high for the grains to become part of the saltation load (it is irrelevant to the boundary layer how a grain attained its initial lift force). When these grains, in turn, strike the surface, they too are capable of inducing more reptating grains. This cascading effect has been discussed in connection with terrestrial aeolian transport in an attempt to dispel the notion that sand motion is divisible only into creep and saltation loads. On Earth, only a few grains are splashed by impact. On Mars, it may be hundreds. We developed a computer model to address this phenomenon because there are some important ramifications: First, this ratio may mean that martian aeolian transport is dominated by reptation flux rather than saltation. On Earth, the flux would be a roughly balanced mixture between reptation/creep and saltation. On Venus, there would be no transport other than by saltation. In other words, an understanding of planetary aeolian processes may not be necessarily understood by extrapolating from the "Earth case", with only gravity and atmospheric density/viscosity being considered as variables. Second, the reptation flux on Mars may be self sustaining, so that little input is required by the wind once transport has been initiated. The number of grains saturating the boundary layer near the bed may mean that average grain speed on Mars might conceivably be less than that on Earth. This would say much for models

  15. Turbulent Flow and Sand Dune Dynamics: Identifying Controls on Aeolian Sediment Transport (United States)

    Weaver, C. M.; Wiggs, G.


    Sediment transport models are founded on cubic power relationships between the transport rate and time averaged flow parameters. These models have achieved limited success and recent aeolian and fluvial research has focused on the modelling and measurement of sediment transport by temporally varying flow conditions. Studies have recognised turbulence as a driving force in sediment transport and have highlighted the importance of coherent flow structures in sediment transport systems. However, the exact mechanisms are still unclear. Furthermore, research in the fluvial environment has identified the significance of turbulent structures for bedform morphology and spacing. However, equivalent research in the aeolian domain is absent. This paper reports the findings of research carried out to characterise the importance of turbulent flow parameters in aeolian sediment transport and determine how turbulent energy and turbulent structures change in response to dune morphology. The relative importance of mean and turbulent wind parameters on aeolian sediment flux was examined in the Skeleton Coast, Namibia. Measurements of wind velocity (using sonic anemometers) and sand transport (using grain impact sensors) at a sampling frequency of 10 Hz were made across a flat surface and along transects on a 9 m high barchan dune. Mean wind parameters and mass sand flux were measured using cup anemometers and wedge-shaped sand traps respectively. Vertical profile data from the sonic anemometers were used to compute turbulence and turbulent stress (Reynolds stress; instantaneous horizontal and vertical fluctuations; coherent flow structures) and their relationship with respect to sand transport and evolving dune morphology. On the flat surface time-averaged parameters generally fail to characterise sand transport dynamics, particularly as the averaging interval is reduced. However, horizontal wind speed correlates well with sand transport even with short averaging times. Quadrant

  16. Transport of atrazine versus bromide and δO18 in sand (United States)

    Tindall, James A.; Friedel, Michael J.


    The objective of this research was to determine the process of atrazine transport compared to bromide and δO18 transport in sands near Denver. Three 1.5 × 2 × 1.5-m plots were installed and allowed to equilibrate for 2 years before research initiation and were instrumented with 1.5 × 2-m zero-tension pan lysimeters installed at 1.5-m depths. Additionally, each plot was instrumented with suction lysimeters, tensiometers, time domain reflectometry (TDR) moisture probes, and thermocouples (to measure soil temperature) at 15-cm depth increments. All plots were enclosed with a raised frame (of 8-cm height) to prevent surface runoff. During the 2-year period before research began, all suction and pan lysimeters were purged monthly and were sampled for fluids immediately prior to atrazine and KBr application to obtain background concentrations. Atrazine illustrated little movement until after a significant rainfall event, which peaked concentrations at depths of about 90 to 135 cm. Both Br− and δO18 moved rapidly through the soil, probably owing to soil porosity and anion exclusion for Br−. Concentrations of atrazine exceeding 5.0 μL−1 were observed with depth (90 to 150 cm) after several months. It appears that significant rainfall events were a key factor in the movement of atrazine in the sand, which allowed the chemicals to move to greater depths and thus avoid generally found biodegradation processes.

  17. Discrete Element Method simulations of the saturation of aeolian sand transport

    CERN Document Server

    Pähtz, Thomas; Carneiro, Marcus V; Araújo, Nuno A M; Herrmann, Hans J


    The saturation length of aeolian sand transport ($L_s$), characterizing the distance needed by wind-blown sand to adapt to changes in the wind shear, is essential for accurate modeling of the morphodynamics of Earth's sandy landscapes and for explaining the formation and shape of sand dunes. In the last decade, it has become a widely-accepted hypothesis that $L_s$ is proportional to the characteristic distance needed by transported particles to reach the wind speed (the ``drag length''). Here we challenge this hypothesis. From extensive numerical Discrete Element Method simulations, we find that, for medium and strong winds, $L_s\\propto V_s^2/g$, where $V_s$ is the saturated value of the average speed of sand particles traveling above the surface and $g$ the gravitational constant. We show that this proportionality is consistent with a recent analytical model, in which the drag length is just one of four similarly important length scales relevant for sand transport saturation.

  18. Saltation of Non-Spherical Sand Particles (United States)

    Wang, Zhengshi; Ren, Shan; Huang, Ning


    Saltation is an important geological process and the primary source of atmospheric mineral dust aerosols. Unfortunately, no studies to date have been able to precisely reproduce the saltation process because of the simplified theoretical models used. For example, sand particles in most of the existing wind sand movement models are considered to be spherical, the effects of the sand shape on the structure of the wind sand flow are rarely studied, and the effect of mid-air collision is usually neglected. In fact, sand grains are rarely round in natural environments. In this paper, we first analyzed the drag coefficients, drag forces, and starting friction wind speeds of sand grains with different shapes in the saltation process, then established a sand saltation model that considers the coupling effect between wind and the sand grains, the effect of the mid-air collision of sand grains, and the effect of the sand grain shape. Based on this model, the saltation process and sand transport rate of non-spherical sand particles were simulated. The results show that the sand shape has a significant impact on the saltation process; for the same wind speed, the sand transport rates varied for different shapes of sand grains by as much as several-fold. Therefore, sand shape is one of the important factors affecting wind-sand movement. PMID:25170614

  19. Detecting oil sands process-affected waters in the Alberta oil sands region using synchronous fluorescence spectroscopy. (United States)

    Kavanagh, Richard J; Burnison, B Kent; Frank, Richard A; Solomon, Keith R; Van Der Kraak, Glen


    Large volumes of oil sands process-affected waters (OSPW) are produced during the extraction of bitumen from oil sand. There are approximately 10(9) m(3) of OSPW currently being stored in settling basins on oil sands mining sites in Northern Alberta. Developers plan to create artificial lakes with OSPW and it is expected that this water may eventually enter the environment. This study was conducted in order to determine if synchronous fluorescence spectroscopy (SFS) could detect OSPW contamination in water systems. Water samples collected from ponds containing OSPW and selected sites in the Alberta oil sands region were evaluated using SFS with an offset value of 18 nm. OSPW ponds consistently displayed a minor peak at 282.5 nm and a broad major peak ranging between 320 and 340 nm. Water from reference sites within the oil sands region had little fluorescence at 282.5 nm but greater fluorescence beyond 345 nm. Naphthenic acids are the major toxic component of OSPW. Both a commercial naphthenic acid and a naphthenic acid extract prepared from OSPW had similar fluorescent spectra with peaks at 280 nm and 320 nm and minor shoulders at approximately 303 and 331 nm. The presence of aromatic acids closely associated with the naphthenic acids may be responsible for unique fluorescence at 320-340 nm. SFS is proposed to be a simple and fast method to monitor the release of OSPW into ground and surface waters in the oil sands region.

  20. Electronmicroscopic Study of Sand Erosion Processes in Metals. (United States)


    AO—A073 k97 ISRAEL INST OF MEtALS HAIFA - ~ - - — Ffl 11/6 ELECTROI~~ICROSCOPIC STUDY OF SAND EROSION PROCESSES IN METALS, IU) UNCLASSIFIED 79...General Appearance 8 4.2.2 Local Erosion Processes and Hard Phase Par t icles 9 5. Further Discussion 10 S S-_ S _~S _~~SS ~~~ S ~~~~~~~~~~~~~~~~~~ __SS...research was to ga in addit iona l unders tan di ng of the mechanism of loca l mater ia l removal from eroded compos ite meta l l i c surface

  1. Influence of enterococcal surface protein (esp) on the transport of Enterococcus faecium within saturated quartz sands. (United States)

    Johanson, Jennifer J; Feriancikova, Lucia; Xu, Shangping


    Enterococcus was selected by US EPA as a Gram-positive indicator microorganism for groundwater fecal contamination. It was recently reported that enterococcal surface protein (esp) was more prevalent in Enterococcus from human sources than in Enterococcus from nonhuman sources and esp could potentially be used as a source tracking tool for fecal contamination (Scott et al., 2005). In this research, we performed laboratory column transport experiments to investigate the transport of Enterococcus faecium within saturated quartz sands. Particularly, we used a wild type strain (E1162) and a mutant (E1162Δesp) to examine the influence of esp on the transport behavior of E. faecium. Our results showed that esp could significantly enhance the attachment of E. faecium cells onto the surface of silica sands and thus lower the mobility of E. faecium within sand packs. Cell surface properties (e.g., zeta potential) were determined and the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory was applied to explain the effects of esp on the retention of E. faecium. Overall, our results suggested that E. faecium strains with esp could display lower mobility within saturated sand packs than E. faecium strains without esp. The disparity in the transport behavior of E. faecium with and without esp could limit the effectiveness of esp as a source tracking tool within the groundwater system.

  2. Transport and retention of bacteria and viruses in biochar-amended sand. (United States)

    Sasidharan, Salini; Torkzaban, Saeed; Bradford, Scott A; Kookana, Rai; Page, Declan; Cook, Peter G


    The transport and retention of Escherichia coli and bacteriophages (PRD1, MS2 and ФX174), as surrogates for human pathogenic bacteria and viruses, respectively, were studied in the sand that was amended with several types of biochar produced from various feedstocks. Batch and column studies were conducted to distinguish between the role of attachment and straining in microbe retention during transport. Batch experiments conducted at various solution chemistries showed negligible attachment of viruses and bacteria to biochar before or after chemical activation. At any given solution ionic strength, the attachment of viruses to sand was significantly higher than that of biochar, whereas bacteria showed no attachment to either sand or biochar. Consistent with batch results, biochar addition (10% w/w) to sand reduced virus retention in the column experiments, suggesting a potential negative impact of biochar application to soil on virus removal. In contrast, the retention of bacteria was enhanced in biochar-amended sand columns. However, elimination of the fine fraction (bacteria retention. Results from batch and column experiments suggest that land application of biochar may only play a role in microbe retention via straining, by alteration of pore size distribution, and not via attachment. Consequently, the particle size distribution of biochar and sediments is a more important factor than type of biochar in determining whether land application of biochar enhances or diminishes microbial retention.

  3. Groundwater Flow and Salt Transport at a Sand Tailings Dam: Field Observations and Modelling Results. (United States)

    Price, A. C.; Mendoza, C. A.


    Large volumes of sand tailings are produced during the extraction of bitumen from the oil sands of Northeastern Alberta. The long-term groundwater response and subsequent movement of water and solutes within the large permeable sand tailings storage areas is uncertain. At the Southwest Sand Storage (SWSS) Facility, located at Syncrude's Mildred Lake operations near Ft. McMurray, there is concern that salts from the tailings water may discharge to newly placed reclamation material that covers the sand tailings. This saline discharge water could destroy the reclamation soil structure and negatively impact vegetation. The steady-state groundwater flow and transient movement of salts at the local (bench and slope) and intermediate (pile) scales in the SWSS are investigated. Water levels, seepage and groundwater quality (including TDS) have been measured for over a year along two transects of piezometers installed in the SWSS. The field data have been used to complete traditional hydrogeological interpretations of the site, and to develop a conceptual model of flow and transport. The local and intermediate flow systems and salt transport in the dam are being evaluated with numerical models. The models will allow possible future hydrogeological behaviour of the structure to be tested. Preliminary results show differences in flow systems and salinity distribution that depend on the deposition of the SWSS. This research will facilitate better long-term environmental management of this and similar sites.

  4. Transport and deposition of suspended soil colloids in saturated sand columns

    DEFF Research Database (Denmark)

    Sharma, Anu; Kawamoto, Ken; Møldrup, Per;


    Understanding colloid mobilization, transport and deposition in the subsurface is a prerequisite for predicting colloid‐facilitated transport of strongly adsorbing contaminants and further developing remedial activities. This study investigated the transport behavior of soil‐colloids extracted from...... a red‐yellow soil from Okinawa, Japan. Different concentrations of suspended‐soil colloids (with diameter ....21 mm) sands. The transport and retention of colloids were studied by analyzing colloid effluent breakthrough curves (BTCs), particle size distribution in the effluent, and colloid deposition profiles within the column. The results showed a significant influence of flow velocity: Low flow velocity...

  5. Influence of Perfluorooctanoic Acid on the Transport and Deposition Behaviors of Bacteria in Quartz Sand. (United States)

    Wu, Dan; Tong, Meiping; Kim, Hyunjung


    The significance of perfluorooctanoic acid (PFOA) on the transport and deposition behaviors of bacteria (Gram-negative Escherichia coli and Gram-positive Bacillus subtilis) in quartz sand is examined in both NaCl and CaCl2 solutions at pH 5.6 by comparing both breakthrough curves and retained profiles with PFOA in solutions versus those without PFOA. All test conditions are found to be highly unfavorable for cell deposition regardless of the presence of PFOA; however, 7%-46% cell deposition is observed depending on the conditions. The cell deposition may be attributed to micro- or nanoscale roughness and/or to chemical heterogeneity of the sand surface. The results show that, under all examined conditions, PFOA in suspensions increases cell transport and decreases cell deposition in porous media regardless of cell type, presence or absence of extracellular polymeric substances, ionic strength, and ion valence. We find that the additional repulsion between bacteria and quartz sand caused by both acid-base interaction and steric repulsion as well as the competition for deposition sites on quartz sand surfaces by PFOA are responsible for the enhanced transport and decreased deposition of bacteria with PFOA in solutions.

  6. Influence of Bisphenol A on the transport and deposition behaviors of bacteria in quartz sand. (United States)

    Wu, Dan; He, Lei; Sun, Ruonan; Tong, Meiping; Kim, Hyunjung


    The influence of Bisphenol A (BPA) on the transport and deposition behaviors of bacteria in quartz sand was examined in both NaCl (10 and 25 mM) and CaCl2 solutions (1.2 and 5 mM) by comparing the breakthrough curves and retained profiles of cell with BPA in suspensions versus those without BPA. Gram-negative Escherichia coli and Gram-positive Bacillus subtilis were employed as model cells in the present study. The extended Derjaguin-Landau-Verwey-Overbeek interaction energy calculation revealed that the presence of BPA in cell suspensions led to a lower repulsive interaction between the cells and the quartz sand. This suggests that, theoretically, increased cell deposition on quartz sand would be expected in the presence of BPA. However, under all examined solution conditions, the presence of BPA in cell suspensions increased transport and decreased deposition of bacteria in porous media regardless of cell type, ionic strength, ion valence, the presence or absence of extracellular polymeric substances. We found that competition by BPA through hydrophobicity for deposition sites on the quartz sand surfaces was the sole contributor to the enhanced transport and decreased deposition of bacteria in the presence of BPA. Copyright © 2017. Published by Elsevier Ltd.

  7. Seasonal geomorphic processes and rates of sand movement at Mount Baldy dune in Indiana, USA (United States)

    Kilibarda, Zoran; Kilibarda, Vesna


    Winds are very strong, frequent, and have high energy (annual DP ∼800 VU) along the southern shores of Lake Michigan, allowing the coexistence of fixed and active dunes. Six years (2007-13) of monitoring Mount Baldy in the Indiana Dunes National Lakeshore reveals that this is the most active coastal dune in the Great Lakes region. This paper documents aeolian processes and changes in the dune's morphology that occur temporarily, following storms, or seasonally, due to weather (climate) variations. Most of the sand transport in this area takes place during strong storms with gale force (>17.5 m/s) winds, which occur in the autumn and winter months. A single storm, such as the October 28-31, 2013 event, can contribute 25% of the annual sand transport and dune movement inland. In its most active year (June 1, 2011 through May 31, 2012), Mount Baldy moved inland on average 4.34 m, with a maximum of 6.52 m along the blowout's axis (155° azimuth). During this particularly active season, there were six storms with sustained gale force winds, winter air temperatures were warmer than average, and shelf ice on Lake Michigan lasted only one day. The dune is least active during the summer season, when the winds are weakest. The late fall and winter winds are the strongest. But in a typical year, most of the dune's advance inland takes place during the spring thaw when sand is released from over-steepened and lumpy slip face, allowing it to avalanche to the toe of the slip face. However, with a warming air temperatures, a reduction in the duration of winter shelf ice, and rising Lake Michigan levels, the annual rates of sand transport and dune movement may increase. The recent Mount Baldy management strategy, which includes planting vegetation and installing wind barriers on the dune's stoss side in an effort to fix the dune and stop its further movement inland, may potentially cause the destruction of the mobile sand, open dune habitat, resulting in the extinction of rare

  8. Application of Special Cause Control Charts to Green Sand Process

    Directory of Open Access Journals (Sweden)

    Perzyk M.


    Full Text Available Statistical Process Control (SPC based on the well known Shewhart control charts, is widely used in contemporary manufacturing industry, including many foundries. However, the classic SPC methods require that the measured quantities, e.g. process or product parameters, are not auto-correlated, i.e. their current values do not depend on the preceding ones. For the processes which do not obey this assumption the Special Cause Control (SCC charts were proposed, utilizing the residual data obtained from the time-series analysis. In the present paper the results of application of SCC charts to a green sand processing system are presented. The tests, made on real industrial data collected in a big iron foundry, were aimed at the comparison of occurrences of out-of-control signals detected in the original data with those appeared in the residual data. It was found that application of the SCC charts reduces numbers of the signals in almost all cases It is concluded that it can be helpful in avoiding false signals, i.e. resulting from predictable factors.

  9. Characterization of napthenic acids in oil sands process-affected waters using fluorescence technology

    Energy Technology Data Exchange (ETDEWEB)

    Brown, L.; Alostaz, M.; Ulrich, A. [Alberta Univ., Edmonton, AB (Canada). Dept. of Civil and Environmental Engineering


    Process-affected water from oil sands production plants presents a major environmental challenge to oil sands operators due to its toxicity to different organisms as well as its corrosiveness in refinery units. This abstract investigated the use of fluorescence excitation-emission matrices to detect and characterize changes in naphthenic acid in oil sands process-affected waters. Samples from oil sands production plants and storage ponds were tested. The study showed that oil sands naphthenic acids show characteristic fluorescence signatures when excited by ultraviolet light in the range of 260 to 350 mm. The signal was a unique attribute of the naphthenic acid molecule. Changes in the fluorescence signature can be used to determine chemical changes such as degradation or aging. It was concluded that the technology can be used as a non-invasive continuous water quality monitoring tool to increase process control in oil sands processing plants.

  10. Antimatter transport processes (United States)

    Van Der Werf, D. P.; Andresen, G. B.; Ashkezari, M. D.; Baquero-Ruiz, M.; Bertsche, W.; Bowe, P. D.; Bray, C. C.; Butler, E.; Cesar, C. L.; Chapman, S.; Charlton, M.; Fajans, J.; Friesen, T.; Fujiwara, M. C.; Gill, D. R.; Hangst, J. S.; Hardy, W. N.; Hayano, R. S.; Hayden, M. E.; Humphries, A. J.; Hydomako, R.; Jonsell, S.; Jørgensen, L. V.; Kurchaninov, L.; Lambo, R.; Madsen, N.; Menary, S.; Nolan, P.; Olchanski, K.; Olin, A.; Povilus, A.; Pusa, P.; Robicheaux, F.; Sarid, E.; Silveira, D. M.; So, C.; Storey, J. W.; Thompson, R. I.; Wurtele, J. S.; Yamazaki, Y.; Alpha Collaboration


    A comparison of the 1S-2S transitions of hydrogen and antihydrogen will yield a stringent test of CPT conservation. Necessarily, the antihydrogen atoms need to be trapped to perform high precision spectroscopy measurements. Therefore, an approximately 0.75 T deep neutral atom trap, equivalent to about 0.5 K for ground state (anti)hydrogen atoms, has been superimposed on a Penning-Malmberg trap in which the anti-atoms are formed. The antihydrogen atoms are produced following a number of steps. A bunch of antiprotons from the CERN Antiproton Decelerator is caught in a Penning-Malmberg trap and subsequently sympathetically cooled and then compressed using rotating wall electric fields. A positron plasma, formed in a separate accumulator, is transported to the main system and also compressed. Antihydrogen atoms are then formed by mixing the antiprotons and positrons. The velocity of the anti-atoms, and their binding energies, will strongly depend on the initial conditions of the constituent particles, for example their temperatures and densities, and on the details of the mixing process. In this paper the complete lifecycle of antihydrogen atoms will be presented, starting with the production of the constituent antiparticles and the description of the manipulations necessary to prepare them appropriately for antihydrogen formation. The latter will also be described, as will the possible fates of the anti-atoms.

  11. Fundamentals of Biomedical Transport Processes

    CERN Document Server

    Miller, Gerald


    Transport processes represent important life-sustaining elements in all humans. These include mass transfer processes, including gas exchange in the lungs, transport across capillaries and alveoli, transport across the kidneys, and transport across cell membranes. These mass transfer processes affect how oxygen and carbon dioxide are exchanged in your bloodstream, how metabolic waste products are removed from your blood, how nutrients are transported to tissues, and how all cells function throughout the body. A discussion of kidney dialysis and gas exchange mechanisms is included. Another elem

  12. A novel wastewater cleaning system for the stone-crushing and sand-making process

    Institute of Scientific and Technical Information of China (English)

    Zhang Wenjun; Li Yanfeng; Tang Jie


    The nature of the slurry from the stone-crushing and sand-making processes is analyzed to develop a novel separation process.The process comprises hydro-cyclone separation followed by screening of the fines,clarification,and filtration.Recovering fine sand and clean wastewater for recycle is demonstrated.The +0.045 mm fine sand fraction and-0.045 mm ultra-fine clay in the slurry are separated and recovered.Fine sand that was previously lost and wasted is now recoverable.The cleaned and reused water is as much as 94% of the total.

  13. Effect of Vibrational Modes on Sand Pressure and Pattern Deformation in the EPC Process

    Institute of Scientific and Technical Information of China (English)

    A.Ikenaga; G.S.Cho; K.H.Choe; K.W.Lee


    During the EPC (expendable pattern casting) process, one of the essential requirements is to prevent pattern distortion during sand filling and compaction. A new method which vibrates the system in a two-dimensional circular mode has been applied to the EPC process. The molding properties of unbonded sand obtained by this new vibration mode are investigated and compared with those in the one-dimensional vertical mode. For adequate compaction of sand, the circular vibration mode is more effective than the vertical mode. Sand became more fluidized by the circular vibration and the particle pressure coefficient was close to unity. The particle pressure coefficient, which is defined as the ratio of horizontal to vertical sand pressure, is responsible for the effectiveness of sand filling.

  14. Transport of soil-aged silver nanoparticles in unsaturated sand (United States)

    Kumahor, Samuel K.; Hron, Pavel; Metreveli, George; Schaumann, Gabriele E.; Klitzke, Sondra; Lang, Friederike; Vogel, Hans-Jörg


    Engineered nanoparticles released into soils may be coated with humic substances, potentially modifying their surface properties. Due to their amphiphilic nature, humic coating is expected to affect interaction of nanoparticle at the air-water interface. In this study, we explored the roles of the air-water interface and solid-water interface as potential sites for nanoparticle attachment and the importance of hydrophobic interactions for nanoparticle attachment at the air-water interface. By exposing Ag nanoparticles to soil solution extracted from the upper soil horizon of a floodplain soil, the mobility of the resulting "soil-aged" Ag nanoparticles was investigated and compared with the mobility of citrate-coated Ag nanoparticles as investigated in an earlier study. The mobility was determined as a function of hydrologic conditions and solution chemistry using column breakthrough curves and numerical modeling. Specifically, we compared the mobility of both types of nanoparticles for different unsaturated flow conditions and for pH = 5 and pH = 9. The soil-aged Ag NP were less mobile at pH = 5 than at pH = 9 due to lower electrostatic repulsion at pH = 5 for both types of interfaces. Moreover, the physical flow field at different water contents modified the impact of chemical forces at the solid-water interface. An extended Derjaguin-Landau-Verwey-Overbeek (eDLVO) model did not provide satisfactory explanation of the observed transport phenomena unlike for the citrate-coated case. For instance, the eDLVO model assuming sphere-plate geometry predicts a high energy barrier (> 90 kT) for the solid-water interface, indicating that nanoparticle attachment is less likely. Furthermore, retardation through reversible sorption at the air-water interface was probably less relevant for soil-aged nanoparticles than for citrate-coated nanoparticles. An additional cation bridging mechanism and straining within the flow field may have enhanced nanoparticle retention at the

  15. Transport of soil-aged silver nanoparticles in unsaturated sand. (United States)

    Kumahor, Samuel K; Hron, Pavel; Metreveli, George; Schaumann, Gabriele E; Klitzke, Sondra; Lang, Friederike; Vogel, Hans-Jörg


    Engineered nanoparticles released into soils may be coated with humic substances, potentially modifying their surface properties. Due to their amphiphilic nature, humic coating is expected to affect interaction of nanoparticle at the air-water interface. In this study, we explored the roles of the air-water interface and solid-water interface as potential sites for nanoparticle attachment and the importance of hydrophobic interactions for nanoparticle attachment at the air-water interface. By exposing Ag nanoparticles to soil solution extracted from the upper soil horizon of a floodplain soil, the mobility of the resulting "soil-aged" Ag nanoparticles was investigated and compared with the mobility of citrate-coated Ag nanoparticles as investigated in an earlier study. The mobility was determined as a function of hydrologic conditions and solution chemistry using column breakthrough curves and numerical modeling. Specifically, we compared the mobility of both types of nanoparticles for different unsaturated flow conditions and for pH=5 and pH=9. The soil-aged Ag NP were less mobile at pH=5 than at pH=9 due to lower electrostatic repulsion at pH=5 for both types of interfaces. Moreover, the physical flow field at different water contents modified the impact of chemical forces at the solid-water interface. An extended Derjaguin-Landau-Verwey-Overbeek (eDLVO) model did not provide satisfactory explanation of the observed transport phenomena unlike for the citrate-coated case. For instance, the eDLVO model assuming sphere-plate geometry predicts a high energy barrier (>90 kT) for the solid-water interface, indicating that nanoparticle attachment is less likely. Furthermore, retardation through reversible sorption at the air-water interface was probably less relevant for soil-aged nanoparticles than for citrate-coated nanoparticles. An additional cation bridging mechanism and straining within the flow field may have enhanced nanoparticle retention at the solid

  16. Chemical mass transport between fluid fine tailings and the overlying water cover of an oil sands end pit lake (United States)

    Dompierre, Kathryn A.; Barbour, S. Lee; North, Rebecca L.; Carey, Sean K.; Lindsay, Matthew B. J.


    Fluid fine tailings (FFT) are a principal by-product of the bitumen extraction process at oil sands mines. Base Mine Lake (BML)—the first full-scale demonstration oil sands end pit lake (EPL)—contains approximately 1.9 × 108 m3 of FFT stored under a water cover within a decommissioned mine pit. Chemical mass transfer from the FFT to the water cover can occur via two key processes: (1) advection-dispersion driven by tailings settlement; and (2) FFT disturbance due to fluid movement in the water cover. Dissolved chloride (Cl) was used to evaluate the water cover mass balance and to track mass transport within the underlying FFT based on field sampling and numerical modeling. Results indicated that FFT was the dominant Cl source to the water cover and that the FFT is exhibiting a transient advection-dispersion mass transport regime with intermittent disturbance near the FFT-water interface. The advective pore water flux was estimated by the mass balance to be 0.002 m3 m-2 d-1, which represents 0.73 m of FFT settlement per year. However, the FFT pore water Cl concentrations and corresponding mass transport simulations indicated that advection rates and disturbance depths vary between sample locations. The disturbance depth was estimated to vary with location between 0.75 and 0.95 m. This investigation provides valuable insight for assessing the geochemical evolution of the water cover and performance of EPLs as an oil sands reclamation strategy.

  17. Non-standard tests for process control in chemically bonded sands

    Directory of Open Access Journals (Sweden)

    S. Ramrattan


    Full Text Available Chemically bonded sand cores and molds are more commonly referred to as precision sand systems in the high production automotive powertrain sector. Their behavior in contact with molten metal can lead to casting defects. Consequently, the interaction is of great interest and an important part of metal casting technology. The American Foundry Society (AFS sand testing is based on physical, mechanical, thermal and chemical properties of the sand system. Foundry engineers have long known that certain AFS sand tests provide limited information regarding control of molding and casting quality. The inadequacy is due to the fact that sand casting processes are inherently thermo-mechanical, thermo-chemical and thermo-physical. Non-standard foundry sand testing has proven useful for laboratory measurement of these characteristics in foundry sand using a disc-shaped specimen. Similarly, the equivalent disc-shaped specimens are used for casting trials. In order to accomplish near-net-shape casting with minimal defects, it is necessary to understand both the properties of the sand system, as well as the interface of molten metal when different binders, additives and/or refractory coatings are used. The methodology for the following non-standard chemically bonded sand tests is described: (1 disc transverse; (2 impact; (3 modified permeability; (4 abrasion; (5 thermal distortion; (6 quick loss on ignition. The data related to the non-standard sand tests were analyzed and interpreted. The test results indicate that there is relatively lower test-to-test variability with the disc-shaped specimens. The non-standard tests were able to discriminate between the chemically bonded polyurethane cold box sand specimens. Further studies should be conducted on various other sand and binder systems as well as on different specimen thicknesses.

  18. Non-standard tests for process control in chemically bonded sands

    Directory of Open Access Journals (Sweden)

    S. Ramrattan


    Full Text Available Chemically bonded sand cores and molds are more commonly referred to as precision sand systems in the high production automotive powertrain sector. Their behavior in contact with molten metal can lead to casting defects. Consequently, the interaction is of great interest and an important part of metal casting technology. The American Foundry Society (AFS sand testing is based on physical, mechanical, thermal and chemical properties of the sand system. Foundry engineers have long known that certain AFS sand tests provide limited information regarding control of molding and casting quality. The inadequacy is due to the fact that sand casting processes are inherently thermo-mechanical, thermo-chemical and thermo-physical. Non-standard foundry sand testing has proven useful for laboratory measurement of these characteristics in foundry sand using a disc-shaped specimen. Similarly, the equivalent disc-shaped specimens are used for casting trials. In order to accomplish near-net-shape casting with minimal defects, it is necessary to understand both the properties of the sand system, as well as the interface of molten metal when different binders, additives and/or refractory coatings are used. The methodology for the following non-standard chemically bonded sand tests is described: (1 disc transverse; (2 impact; (3 modified permeability; (4 abrasion; (5 thermal distortion; (6 quick loss on ignition. The data related to the non-standard sand tests were analyzed and interpreted. The test results indicate that there is relatively lower test-to-test variability with the disc-shaped specimens. The non-standard tests were able to discriminate between the chemically bonded polyurethane cold box sand specimens. Further studies should be conducted on various other sand and binder systems as well as on different specimen thicknesses.

  19. Influence Of Carboxymethyl Cellulose For The Transport Of Titanium Dioxide Nanoparticles In Clean Silica And Mineral-Coated Sands (United States)

    The transport properties of titanium dioxide (anatase polymorph) nanoparticles encapsulated by carboxymethyl cellulose (CMC) were evaluated as a function of changes in the solute chemical properties in clean quartz, amorphous aluminum and iron hydroxide-coated sands. While prist...


    Directory of Open Access Journals (Sweden)

    Loredana Anne-Marie BĂDESCU


    Full Text Available This paper presents the modelling of over-finishing grinding with abrasive brushes and also a comparative study between the absorbed power when over-finishing grinding the beech, the spruce and the MDF with this kind of tools as compared to the absorbed power when over-finishing grinding under similar conditions using the wide belt sanding (grinding technology, presenting the advantages of reconsidering such a technological process.

  1. A Life Cycle Assessment of Silica Sand: Comparing the Beneficiation Processes

    Directory of Open Access Journals (Sweden)

    Anamarija Grbeš


    Full Text Available Silica sand or quartz sand is a mineral resource with a wide variety of application; glass industry, construction and foundry are the most common examples thereof. The Republic of Croatia has reserves of 40 million tons of silica sand and a long tradition of surface mining and processing. The average annual production of raw silica sand in Croatia in the period from 2006 to 2011 amounted to 150 thousand tons. This paper presents cradle to gate LCA results of three different types of beneficiation techniques: electrostatic separation; flotation; gravity concentration. The aim of this research is to identify and quantify the environmental impacts of the silica sand production, to learn the range of the impacts for different processing methods, as well as to identify the major contributors and focus for further process design development.

  2. Crew Transportation Technical Management Processes (United States)

    Mckinnie, John M. (Compiler); Lueders, Kathryn L. (Compiler)


    Under the guidance of processes provided by Crew Transportation Plan (CCT-PLN-1100), this document, with its sister documents, International Space Station (ISS) Crew Transportation and Services Requirements Document (CCT-REQ-1130), Crew Transportation Technical Standards and Design Evaluation Criteria (CCT-STD-1140), Crew Transportation Operations Standards (CCT STD-1150), and ISS to Commercial Orbital Transportation Services Interface Requirements Document (SSP 50808), provides the basis for a National Aeronautics and Space Administration (NASA) certification for services to the ISS for the Commercial Provider. When NASA Crew Transportation System (CTS) certification is achieved for ISS transportation, the Commercial Provider will be eligible to provide services to and from the ISS during the services phase.

  3. Influence of clay particles on the transport and retention of titanium dioxide nanoparticles in quartz sand. (United States)

    Cai, Li; Tong, Meiping; Wang, Xueting; Kim, Hyunjung


    This study investigated the influence of two representative suspended clay particles, bentonite and kaolinite, on the transport of titanium dioxide nanoparticles (nTiO2) in saturated quartz sand in both NaCl (1 and 10 mM ionic strength) and CaCl2 solutions (0.1 and 1 mM ionic strength) at pH 7. The breakthrough curves of nTiO2 with bentonite or kaolinite were higher than those without the presence of clay particles in NaCl solutions, indicating that both types of clay particles increased nTiO2 transport in NaCl solutions. Moreover, the enhancement of nTiO2 transport was more significant when bentonite was present in nTiO2 suspensions relative to kaolinite. Similar to NaCl solutions, in CaCl2 solutions, the breakthrough curves of nTiO2 with bentonite were also higher than those without clay particles, while the breakthrough curves of nTiO2 with kaolinite were lower than those without clay particles. Clearly, in CaCl2 solutions, the presence of bentonite in suspensions increased nTiO2 transport, whereas, kaolinite decreased nTiO2 transport in quartz sand. The attachment of nTiO2 onto clay particles (both bentonite and kaolinite) were observed under all experimental conditions. The increased transport of nTiO2 in most experimental conditions (except for kaolinite in CaCl2 solutions) was attributed mainly to the clay-facilitated nTiO2 transport. The straining of larger nTiO2-kaolinite clusters yet contributed to the decreased transport (enhanced retention) of nTiO2 in divalent CaCl2 solutions when kaolinite particles were copresent in suspensions.

  4. Hydrophobicity of biofilm coatings influences the transport dynamics of polystyrene nanoparticles in biofilm-coated sand. (United States)

    Mitzel, Michael R; Sand, Stefanie; Whalen, Joann K; Tufenkji, Nathalie


    Engineered nanoparticles (ENPs) are used in the manufacture of over 2000 industrial and consumer products to enhance their material properties and functions or to enable new nanoparticle-dependent functions. The widespread use of ENPs will result in their release to the subsurface and aquatic environments, where they will interact with indigenous biota. Laboratory column experiments were designed to understand the influence of two different Pseudomonas aeruginosa biofilms on the mobility of polystyrene latex nanoparticles in granular porous media representative of groundwater aquifers or riverbank filtration settings. The transport behavior of 20 nm carboxylate-modified (CLPs) and sulfate (SLPs) polystyrene latex ENPs suspended in NaCl or CaCl2 (1 and 10 mM ionic strength, pH 7) was studied in columns packed with quartz sand coated with biofilms formed by two P. aeruginosa strains that differed in cell surface hydrophobicity (P. aeruginosa 9027™, relatively hydrophilic and P. aeruginosa PAO1, relatively hydrophobic). Biofilm-coated quartz sand retained more of the electrostatically-stabilized latex ENPs than clean, uncoated sand, regardless of the serotype. As IS increased, clear differences in the shape of the ENP breakthrough curves were observed for each type of biofilm coating. ENP breakthrough in the P. aeruginosa PAO1 biofilm-coated sand was generally constant with time whereby breakthrough in the P. aeruginosa 9027 biofilm-coated sand showed dynamic behavior. This indicates a fundamental difference in the mechanisms of ENP deposition onto hydrophilic or hydrophobic biofilm coatings due to the hydration properties of these biofilms. The results of this study demonstrate the importance of considering the surface properties of aquifer grain coatings when evaluating ENP fate in natural subsurface environments.

  5. Application of a power quality analyser to the monitoring of sand preparation processes in foundry plants

    Directory of Open Access Journals (Sweden)

    K. Smyksy


    Full Text Available Process control plays a major role in supervision and identification of states, for example in monitoring of electric circuits power- supplying the foundry machines and devices, such as sand preparation processes, moulding technologies, melting, cleaning and finishing of castings. The monitoring and control equipment includes the power quality analysers. Testing is done using a Japanese analyser KEW 6319 (Kyoritsu applied to monitoring of the sand preparation process in a foundry plant with low level of mechanization, equipped with the sand preparation unit based on a roller mixer.

  6. Vertical structure of aeolian turbulence in a boundary layer with sand transport (United States)

    Lee, Zoe S.; Baas, Andreas C. W.


    originating from the top of the boundary layer, indicating a downwards direction of eddy motion. While directionality of turbulence cannot be definitively determined, our results indicate that the top-down turbulence model is a suitable explanation, further supported by the presence of 'incomplete' eddies which originate at higher elevations but fail to extend to the surface. This provides the first evidence in support of a top down turbulence model as observed in aeolian geomorphology, and we present preliminary findings on its relationship to sand transport activity. Lee, Z.S., Baas, A.C.W. (2016) Variable and conflicting shear stress estimates inside a boundary layer with sediment transport. Earth Surface Processes and Landforms; DOI: 10.1002/esp.3829

  7. Influence of sulfate on the transport of bacteria in quartz sand. (United States)

    Shen, Xiufang; Han, Peng; Yang, Haiyan; Kim, Hyunjung; Tong, Meiping


    The influence of sulfate on the transport of bacteria in packed quartz sand was examined at a constant 25mM ionic strength with the sulfate concentration progressively increased from 0 to 20mM at pH 6.0. Two representative cell types, Escherichia coli BL21 (Gram-negative) and Bacillus subtilis (Gram-positive), were used to determine the effect of sulfate on cell transport behavior. For both examined cell types, the breakthrough plateaus in the presence of sulfate in suspensions were higher and the corresponding retained profiles were lower than those without sulfate ions, indicating that the presence of sulfate in suspensions increased cell transport in packed quartz sand regardless of the examined cell types (Gram-positive or Gram-negative). Moreover, the enhancement of bacteria transport induced by the presence of sulfate was more pronounced with increasing sulfate concentration from 5 to 20mM. In contrast with the results for EPS-present bacteria, the presence of sulfate in solutions did not change the transport behavior for EPS-removed cells. The zeta potentials of EPS-present cells with sulfate were found to be more negative relative to those without sulfate in suspensions, whereas, the zeta potentials for EPS-removed cells in the presence of sulfate were similar as those without sulfate. We proposed that sulfate could interact with EPS on cell surfaces and thus negatively increased the zeta potentials of bacteria, contributing to the increased transport in the presence of sulfate in suspensions.

  8. Complexity confers stability: Climate variability, vegetation response and sand transport on longitudinal sand dunes in Australia's deserts (United States)

    Hesse, Paul P.; Telfer, Matt W.; Farebrother, Will


    The relationship between antecedent precipitation, vegetation cover and sand movement on sand dunes in the Simpson and Strzelecki Deserts was investigated by repeated (up to four) surveys of dune crest plots (≈25 × 25 m) over a drought cycle (2002-2012) in both winter (low wind) and spring (high wind). Vegetation varied dramatically between surveys on vegetated and active dune crests. Indices of sand movement had significant correlations with vegetation cover: the depth of loose sand has a strong inverse relationship with crust (cyanobacterial and/or physical) while the area covered by ripples has a strong inverse relationship with the areal cover of vascular plants. However, the relationship between antecedent rainfall and vegetation cover was found to be complex. We tentatively identify two thresholds; (1) >10 mm of rainfall in the preceding 90 days leads to rapid and near total cover of crust and/or small plants 400 mm of rainfall in the preceding three years leads to higher cover of persistent and longer-lived plants >50 cm tall. These thresholds were used to predict days of low vegetation cover on dune crests. The combination of seasonality of predicted bare-crest days, potential sand drift and resultant sand drift direction explains observed patterns of sand drift on these dunes. The complex vegetation and highly variable rainfall regime confer meta-stability on the dunes through the range of responses to different intervals of antecedent rainfall and non-linear growth responses. This suggests that the geomorphic response of dunes to climate variation is complex and non-linear.

  9. Transport Phenomena and Materials Processing (United States)

    Kou, Sindo


    An extremely useful guide to the theory and applications of transport phenomena in materials processing This book defines the unique role that transport phenomena play in materials processing and offers a graphic, comprehensive treatment unlike any other book on the subject. The two parts of the text are, in fact, two useful books. Part I is a very readable introduction to fluid flow, heat transfer, and mass transfer for materials engineers and anyone not yet thoroughly familiar with the subject. It includes governing equations and boundary conditions particularly useful for studying materials processing. For mechanical and chemical engineers, and anyone already familiar with transport phenomena, Part II covers the many specific applications to materials processing, including a brief description of various materials processing technologies. Readable and unencumbered by mathematical manipulations (most of which are allocated to the appendixes), this book is also a useful text for upper-level undergraduate and graduate-level courses in materials, mechanical, and chemical engineering. It includes hundreds of photographs of materials processing in action, single and composite figures of computer simulation, handy charts for problem solving, and more. Transport Phenomena and Materials Processing: * Describes eight key materials processing technologies, including crystal growth, casting, welding, powder and fiber processing, bulk and surface heat treating, and semiconductor device fabrication * Covers the latest advances in the field, including recent results of computer simulation and flow visualization * Presents special boundary conditions for transport phenomena in materials processing * Includes charts that summarize commonly encountered boundary conditions and step-by-step procedures for problem solving * Offers a unique derivation of governing equations that leads to both overall and differential balance equations * Provides a list of publicly available computer

  10. Laser particle counter validation for aeolian sand transport measurements using a highspeed camera (United States)

    Duarte-Campos, Leonardo; Wijnberg, Kathelijne M.; Oyarte-Gálvez, Loreto; Hulscher, Suzanne J. M. H.


    Measuring aeolian sand transport rates in the field has been a long-standing challenge. In this paper, we present the results of a laboratory experiment to test the ability of a laser particle counter sensor (Wenglor) to accurately count sand grains of various grain size classes and stainless steel beads. We compared the count data collected by the Wenglor with images from a Highspeed camera which revealed the actual number of grains passing the laser beam. A Silicon photodiode was used to record the laser intensity reduction induced by the sand grain passage through the laser beam to derive the minimal necessary reduction for the Wenglor to count grains. For the two possible settings of the Wenglor, i.e., Minimal Teach-in or Normal Teach-in, a minimum of 18% and 78% blocking of the laser beam was required for recording a count. This implies that the minimum grain size that can be observed by the Wenglor is 210 ± 3 μm and 495 ± 10 μm for the two settings respectively, which is considerably coarser than previously assumed. Due to the non-uniform power distribution of the laser sensor intensity, at the detection limit of 210 μm, only grains passing through the centre of the beam will be counted.

  11. A Statistics-Based Cracking Criterion of Resin-Bonded Silica Sand for Casting Process Simulation (United States)

    Wang, Huimin; Lu, Yan; Ripplinger, Keith; Detwiler, Duane; Luo, Alan A.


    Cracking of sand molds/cores can result in many casting defects such as veining. A robust cracking criterion is needed in casting process simulation for predicting/controlling such defects. A cracking probability map, relating to fracture stress and effective volume, was proposed for resin-bonded silica sand based on Weibull statistics. Three-point bending test results of sand samples were used to generate the cracking map and set up a safety line for cracking criterion. Tensile test results confirmed the accuracy of the safety line for cracking prediction. A laboratory casting experiment was designed and carried out to predict cracking of a cup mold during aluminum casting. The stress-strain behavior and the effective volume of the cup molds were calculated using a finite element analysis code ProCAST®. Furthermore, an energy dispersive spectroscopy fractographic examination of the sand samples confirmed the binder cracking in resin-bonded silica sand.

  12. Processing of tailings in Canadian oil sands industry

    Institute of Scientific and Technical Information of China (English)


    Vast amounts of tailings are produced daily in bitumen extraction from the Athabasca oil sands. The coarse sand from the tailings stream is used to build dykes around the containment basin. The run-off slurry arrives at the water's edge in the tailings pond at a solids concentration of about 3%~8% by mass. Settling of the solids takes place "relatively fast", over several days, creating a "free water zone" that contains little solids. When the fine mineral solids concentration has reached about 15% by mass, the suspension develops non-Newtonian properties. After 2~3 years, the suspension concentration reaches a value of about 30% by mass at which the settling rate becomes extremely slow. Methods to handle the already created tailings ponds and new approaches to eliminate the creation of new ones will be discussed both from the industrial and fundamental prospective.

  13. A novel and innovative process to produce oil from tar sands and heavy oil

    Energy Technology Data Exchange (ETDEWEB)

    Denivelle, C. [OSEAD, Paris (France); Fourt, J.F. [Truffle Capital, Paris (France)


    Oil sands extraction by adsorption (OSEAD) was created in October 2006 to develop an innovative hydrocarbon extraction technology from oil sands. It has since grown by taking control of a lead, zinc and silver mine in Morocco. This paper discussed the novel and innovative OSEAD process to produce oil from tar sands and heavy oil. The paper provided a description of the oil sand samples and discussed lab testing. The adsorption and desorption phases were both outlined. The main properties of the agent were identified. A summary of the test work results was also presented. The optimized OSEAD process includes an ore preparation step involving mixing of oil sand and water at ambient temperature; an adsorption step involving addition of agent to the sand/water mix; a phase separation step; a desorption step; and a tailings treatment step. It was concluded that the laboratory test work performed on Canadian oil sands is conclusive in demonstrating the capacity of the OSEAD process to efficiently adsorb heavy and viscous hydrocarbon at ambient temperature and with limited amount of water addition. 11 figs., 1 appendix.

  14. The effects of surfactants and solution chemistry on the transport of multiwalled carbon nanotubes in quartz sand-packed columns. (United States)

    Lu, Yinying; Xu, Xiaopan; Yang, Kun; Lin, Daohui


    The effect of different surfactants on the transport of multiwalled carbon nanotubes (MWCNTs) in quartz sand-packed columns was firstly investigated under various conditions. The stable plateau values (C(max)) of the breakthrough curves (BTCs), critical PVs (the number of pore volumes of infusions needed to reach the C(max)), maximum transport distances (L(max)), deposition rate coefficients (kd) and retention rates were calculated to compare the transport and retention of MWCNTs under various conditions. Stability of the MWCNT suspensions as a function of the influencing factors was examined to reveal the underlying mechanism of the MWCNT retention. Results showed that MWCNTs suspended by different surfactants presented different BTCs; the MWCNT transport increased with increasing sand size and MWCNT concentration; high flow velocity was favorable for the MWCNT transport, while high Ca(2+) concentration and low pH were unfavorable for the transport; hetero-aggregation, straining and site blocking occurred during the transport.

  15. Influence of core sand properties on flow dynamics of core shooting process based on experiment and multiphase simulation

    Directory of Open Access Journals (Sweden)

    Chang-jiang Ni


    Full Text Available The influence of core sand properties on flow dynamics was investigated synchronously with various core sands, transparent core-box and high-speed camera. To confirm whether the core shooting process has significant turbulence, the flow pattern of sand particles in the shooting head and core box was reproduced with colored core sands. By incorporating the kinetic theory of granular flow (KTGF, kinetic-frictional constitutive correlation and turbulence model, a two-fluid model (TFM was established to study the flow dynamics of the core shooting process. Two-fluid model (TFM simulations were then performed and a areasonable agreement was achieved between the simulation and experimental results. Based on the experimental and simulation results, the effects of turbulence, sand density, sand diameter and binder ratio were analyzed in terms of filling process, sand volume fraction (αs and sand velocity (Vs.

  16. Sensitivity of growth characteristics of tidal sand ridges and long bed waves to formulations of bed shear stress, sand transport and tidal forcing: A numerical model study (United States)

    Yuan, Bing; de Swart, Huib E.; Panadès, Carles


    Tidal sand ridges and long bed waves are large-scale bedforms that are observed on continental shelves. They differ in their wavelength and in their orientation with respect to the principal direction of tidal currents. Previous studies indicate that tidal sand ridges appear in areas where tidal currents are above 0.5 m s-1, while long bed waves occur in regions where the maximum tidal current velocity is slightly above the critical velocity for sand erosion and the current is elliptical. An idealized nonlinear numerical model was developed to improve the understanding of the initial formation of these bedforms. The model governs the feedbacks between tidally forced depth-averaged currents and the sandy bed on the outer shelf. The effects of different formulations of bed shear stress and sand transport, tidal ellipticity and different tidal constituents on the characteristics of these bedforms (growth rate, wavelength, orientation of the preferred bedforms) during their initial formation were examined systematically. The results show that the formulations for bed shear stress and slope-induced sand transport are not critical for the initial formation of these bedforms. For tidal sand ridges, under rectilinear tidal currents, increasing the critical bed shear stress for sand erosion decreases the growth rate and the wavelength of the preferred bedforms significantly, while the orientation angle slightly decreases. The dependence of the growth rate, wavelength and the orientation of the preferred bedforms on the tidal ellipticity is non-monotonic. A decrease in tidal frequency results in preferred bedforms with larger wavelength and smaller orientation angle, while their growth rate hardly changes. In the case of joint diurnal and semidiurnal tides, or spring-neap tides, the characteristics of the bedforms are determined by the dominant tidal constituent. For long bed waves, the number of anticyclonically/cyclonically oriented bedforms with respect to the principal

  17. Effect of Low Energy Waves on the Accumulation and Transport of Fecal Indicator Bacteria in Sand and Pore Water at Freshwater Beaches. (United States)

    Wu, Ming Zhi; O'Carroll, Denis M; Vogel, Laura J; Robinson, Clare E


    Elevated fecal indicator bacteria (FIB) in beach sand and pore water represent an important nonpoint source of contamination to surface waters. This study examines the physical processes governing the accumulation and distribution of FIB in a beach aquifer. Field data indicate E. coli and enterococci can be transported 1 and 2 m, respectively, below the water table. Data were used to calibrate a numerical model whereby FIB are delivered to a beach aquifer by wave-induced infiltration across the beach face. Simulations indicate FIB rapidly accumulate in a beach aquifer with FIB primarily associated with sand rather than freely residing in the pore water. Simulated transport of E. coli in a beach aquifer is complex and does not correlate with conservative tracer transport. Beaches with higher wave-induced infiltration rate and vertical infiltration velocity (i.e., beaches with higher beach slope and wave height, and lower terrestrial groundwater discharge) had greater E. coli accumulation and E. coli was transported deeper below the beach face. For certain beach conditions, the amount of FIB accumulated in sand over 5-6 days was found to be sufficient to trigger a beach advisory if eroded to surface water.

  18. Sediment transport and dispersal pathways in the Lower Cretaceous sands of the Britannia Field, derived from magnetic anisotropy

    Energy Technology Data Exchange (ETDEWEB)

    Hailwood, E.; Ding, F. [Core Magnetics, Sedbergh (United Kingdom)


    Sediment transport directions and dispersal patterns in the Lower Cretaceous sands of the Britannia Field have been investigated, using magnetic anisotropy and palaeomagnetic core re-orientation methods, to aid understanding of the geometry and architecture of the reservoir sand units. The results indicate that sands were sourced mainly from the north. This applies both to the massive sand bodies with lobate geometry in the lower reservoir zones in the western part of the field and to the laminated slurried beds with tabular geometry in the upper zones in the eastern part. Thus, sediment in this part of the Outer Moray Firth play appears to have been derived largely from a discrete point source to the north rather than from axial flow along the Witch Ground Graben. (Author)

  19. Transport processes at fluidic interfaces

    CERN Document Server

    Reusken, Arnold


    There are several physico-chemical processes that determine the behavior of multiphase fluid systems – e.g., the fluid dynamics in the different phases and the dynamics of the interface(s), mass transport between the fluids, adsorption effects at the interface, and transport of surfactants on the interface – and result in heterogeneous interface properties. In general, these processes are strongly coupled and local properties of the interface play a crucial role. A thorough understanding of the behavior of such complex flow problems must be based on physically sound mathematical models, which especially account for the local processes at the interface. This book presents recent findings on the rigorous derivation and mathematical analysis of such models and on the development of numerical methods for direct numerical simulations. Validation results are based on specifically designed experiments using high-resolution experimental techniques. A special feature of this book is its focus on an interdisciplina...

  20. The growth and photosynthesis of Typha in oil sands process affected material and water

    Energy Technology Data Exchange (ETDEWEB)

    Foote, L. [Alberta Univ., Edmonton, AB (Canada); Hornung, J. [Petro-Canada, Calgary, AB (Canada)


    Aquatic plants such as cattail contribute substantially to the energy flow in wetlands. Since Typha (cattail) plants acquire and cycle carbon and nutrients through wetlands, their growth and recycling of captured nutrients are an important part of natural, healthy wetland ecosystems. Cattail are pervasive and satisfy many of the criteria to be used as indicators of wetland integrity. This study investigated if cattail growth and carbon accrual were influenced by oil sands process materials (OSPM) such as consolidated tailings (CT). The purpose was to facilitate land reclamation initiatives by evaluating the impact that constituents of oil sands process material have on aquatic plant growth. The study was conducted at Suncor's experimental trenches. Six lined basins were used, of which 3 were filled with natural water and 3 were filled with trench water. Cattail were planted in different growth medium combinations, including CT over CT; soil over soil; soil over CT; and soil over sterilized sand. All leaf lengths and widths were measured along with the photosynthesis of the leaves and root and plant biomass at planting and after 2-years growth. A larger leaf area was observed under oil sands process influence, which may indicate increased carbon accrual above ground. Leaf area data suggested that CT affected plants are quite productive. The study also indicated that oil sands affected water may reduce plant fitness, and therefore could influence the overall oil sands reclamation timelines. Conversely, cattail grown in soil capped process affected material had a much larger leaf area compared to those grown in soil capped sand, most likely due to the higher levels of ammonia in process affected material.

  1. Assessing the bioremediation potential of algal species indigenous to oil sands process-affected waters on mixtures of oil sands acid extractable organics. (United States)

    Ruffell, Sarah E; Frank, Richard A; Woodworth, Adam P; Bragg, Leslie M; Bauer, Anthony E; Deeth, Lorna E; Müller, Kirsten M; Farwell, Andrea J; Dixon, D George; Servos, Mark R; McConkey, Brendan J


    Surface mining extraction of bitumen from oil sand in Alberta, Canada results in the accumulation of oil sands process-affected water (OSPW). In attempts to maximize water recycling, and because its constituents are recognized as being toxic, OSPW is retained in settling basins. Consequently, research efforts are currently focused on developing remediation strategies capable of detoxifying OSPW to allow for eventual release. One potential bioremediation strategy proposes to utilize phytoplankton native to the Alberta oil sand region to sequester, break down, or modify the complex oil sands acid extractable organic (AEO) mixtures in OSPW. Preliminary attempts to quantify changes in total oil sands AEO concentration in test solutions by ESI-MS following a 14-day algal remediation period revealed the presence of unknown organic acids in control samples, likely released by the phytoplankton strains and often of the same atomic mass range as the oil sands AEO under investigation. To address the presence of these "biogenic" organic acids in test samples, ESI-MS in MRM mode was utilized to identify oil sands AEO "marker ions" that were a) present within the tested oil sands AEO extract and b) unique to the oil sands AEO extract only (e.g. atomic masses different from biogenic organic acids). Using this approach, one of the 21 tested algal strains, Stichococcus sp. 1, proved capable of significantly reducing the AEO marker ion concentration at test concentrations of 10, 30, and 100mgL(-1). This result, along with the accelerated growth rate and recalcitrance of this algal strain with exposure to oil sands AEO, suggests the strong potential for the use of the isolated Stichococcus sp. 1 as a candidate for bioremediation strategies.

  2. Sand-Mud Sediment Transport induced by tidal currents and wind waves in shallow microtidal basins (United States)

    Carniello, L.; Defina, A.; D'Alpaos, L.


    Field data and mathematical modeling have demonstrated that the morphological evolution of shallow tidal basins is the result of the combined effect of tidal currents and wind waves. Tidal currents, in particular, drive the morphological evolution of shallow tidal systems in proximity of the inlets and within the channel network, whereas in shallow areas tidal current mainly acts enhancing the bottom shear stress due to wind waves and redistributing sediments within the basin. In this study we present a mathematical model for sediment entrainment, transport and deposition due to the combined effect of tidal currents and wind waves. The model is coupled with a hydrodynamic module based on the shallow water equations and with a module for the generation and propagation of wind waves. The sediment transport model describes the sediments by the way of a bi-granular mixtures composed by both cohesive and non-cohesive sediments thus considering the contemporary presence of clay, silt and sand which usually characterizes estuaries and tidal basins. Moreover, the model describes the bed evolution and evaluates the variation of bed sediment composition considering also the transition between cohesive and non-cohesive behavior. Attention is focused on some issues concerning the definition of a reliable initial bed composition and the incipient sediment motion which is treated following a stochastic approach for the bottom shear stress and for the critical shear stress distribution. The model is applied to the Lagoon of Venice (Italy) and the results of different simulations are compared, with good agreement, to a series of turbidity measurements collected inside the lagoon. The application of the model to the present bathymetry of the Venice lagoon allows for a first estimation of the actual net amount of sand and mud flowing through the three inlets and also gives some information on bottom evolution in terms of elevation and composition.

  3. The effect of EDTA on the groundwater transport of thorium through sand. (United States)

    May, Colin C; Young, Lindsay; Worsfold, Paul J; Heath, Sarah; Bryan, Nick D; Keith-Roach, Miranda J


    The effect of the anthropogenic complexing agent EDTA on thorium transport in groundwater has been studied using sand-packed columns and flow rates in the range of 20-100 m y⁻¹. The concentrations injected into the columns were in the range of 0.4-4 mM for Th and 4-40 mM for EDTA, and with EDTA:Th ratios in the range 1:1 to 10:1. The results show that EDTA can significantly increase Th transport, but two very different behaviours are observed at Th concentrations of 0.4 and 4 mM. At the lower concentration, Th breakthrough is retarded with respect to a conservative tracer, with a peak width that is consistent with a single K(d) value, followed by a longer tail, and the behaviour is very sensitive to the flow rate. However at 4 mM Th, the breakthrough peak appears near to that of the tracer, and the width of the peak is consistent with a distribution of K(d) values and/or a larger dispersivity than the tracer. Speciation and transport modelling have been used to interpret the data, and a model was developed that could explain the 0.4 mM behaviour. This suggests that ternary surface complexes are important in these systems, with at least two different species involved, although the complexity of Th speciation in these systems leads to significant uncertainty in the values of the equilibrium and kinetic parameters. For the 4 mM systems, the rapid transport observed could not be explained by a simple chemical model; instead it is likely that EDTA plays an important role in stabilising and transporting thorium colloids and clusters.

  4. Eolian sand transport pathways in the southwestern United States: Importance of the Colorado River and local sources (United States)

    Muhs, D.R.; Reynolds, R.L.; Been, J.; Skipp, G.


    Geomorphologists have long recognized that eolian sand transport pathways extend over long distances in desert regions. Along such pathways, sediment transport by wind can surmount topographic obstacles and cross major drainages. Recent studies have suggested that three distinct eolian sand transport pathways exist (or once existed) in the Mojave and Sonoran Desert regions of the southwestern United States. One hypothesized pathway is colian sand transport from the eastern Mojave Desert of California into western Arizona, near Parker, and would require sand movement across what must have been at least a seasonally dry Colorado River valley. We tested this hypothesis by mineralogical, geochemical and magnetic analyses of eolian sands on both sides of the Colorado River, as well as sediment from the river itself. Results indicate that dunes on opposite sides of the Colorado River are mineralogically distinct: eastern California dunes are feldspar-rich whereas western Arizona dunes are quartz-rich, derived from quartz-rich Colorado River sediments. Because of historic vegetation changes, little new sediment from the Colorado River is presently available to supply the Parker dunes. Based on this study and previous work, the Colorado River is now known to be the source of sand for at least three of the major dune fields of the Sonoran Desert of western Arizona and northern Mexico. On the other hand, locally derived alluvium appears to be a more important source of dune fields in the Mojave Desert of California. Although many geomorphologists have stressed the importance of large fluvial systems in the origin of desert dune fields, few empirical data actually exist to support this theory. The results presented here demonstrate that a major river system in the southwestern United States is a barrier to the migration of some dune fields, but essential to the origin of others. Published by Elsevier Science Ltd.

  5. Microbial processes in the Athabasca Oil Sands and their potential applications in microbial enhanced oil recovery. (United States)

    Harner, N K; Richardson, T L; Thompson, K A; Best, R J; Best, A S; Trevors, J T


    The Athabasca Oil Sands are located within the Western Canadian Sedimentary Basin, which covers over 140,200 km(2) of land in Alberta, Canada. The oil sands provide a unique environment for bacteria as a result of the stressors of low water availability and high hydrocarbon concentrations. Understanding the mechanisms bacteria use to tolerate these stresses may aid in our understanding of how hydrocarbon degradation has occurred over geological time, and how these processes and related tolerance mechanisms may be used in biotechnology applications such as microbial enhanced oil recovery (MEOR). The majority of research has focused on microbiology processes in oil reservoirs and oilfields; as such there is a paucity of information specific to oil sands. By studying microbial processes in oil sands there is the potential to use microbes in MEOR applications. This article reviews the microbiology of the Athabasca Oil Sands and the mechanisms bacteria use to tolerate low water and high hydrocarbon availability in oil reservoirs and oilfields, and potential applications in MEOR.

  6. Facilitated transport of Cu with hydroxyapatite nanoparticles in saturated sand: Effects of solution ionic strength and composition (United States)

    Column experiments were conducted to investigate the facilitated transport of Cu in association with hydroxyapatite nanoparticles (nHAP) in water-saturated quartz sand at different solution concentrations of NaCl (0 to 100 mM) or CaCl2 (0.1 to 1.0 mM). The experimental breakthrough curves and retent...

  7. Inhibited transport of graphene oxide nanoparticles in granular quartz sand coated with Bacillus subtilis and Pseudomonas putida biofilms. (United States)

    He, Jian-Zhou; Wang, Deng-Jun; Fang, Huan; Fu, Qing-Long; Zhou, Dong-Mei


    Increasing production and use of graphene oxide nanoparticles (GONPs) boost their wide dissemination in the subsurface environments where biofilms occur ubiquitously, representative of the physical and chemical heterogeneities. This study aimed at investigating the influence of Gram-positive Bacillus subtilis (BS) and Gram-negative Pseudomonas putida (PP) biofilms on the transport of GONPs under different ionic strengths (0.1, 0.5, and 1.0 mM CaCl2) at neutral pH 7.2 in water-saturated porous media. Particularly, the X-ray micro-computed tomography was used to quantitatively characterize the pore structures of sand columns in the presence and absence of biofilms. Our results indicated that the presence of biofilms reduced the porosity and narrowed down the pore sizes of packed columns. Transport experiments in biofilm-coated sand showed that biofilms, irrespective of bacterial species, significantly inhibited the mobility of GONPs compared to that in cleaned sand. This could be due to the Ca(2+) complexation, increased surface roughness and charge heterogeneities of collectors, and particularly enhanced physical straining caused by biofilms. The two-site kinetic retention model-fitted value of maximum solid-phase concentration (Smax2) for GONPs was higher for biofilm-coated sand than for cleaned sand, demonstrating that biofilms act as favorable sites for GONPs retention. Our findings presented herein are important to deepen our current understanding on the nature of particle-collector interactions.

  8. Influence of gravity on transport and retention of representative engineered nanoparticles in quartz sand. (United States)

    Cai, Li; Zhu, Jinghan; Hou, Yanglong; Tong, Meiping; Kim, Hyunjung


    Four types of NPs: carbon nanotubes and graphene oxide (carbon-based NPs), titanium dioxide and zinc oxide metal-oxide NPs, were utilized to systematically determine the influence of gravity on the transport of NPs in porous media. Packed column experiments for two types of carbon-based NPs were performed under unfavorable conditions in both up-flow (gravity-negative) and down-flow (gravity-positive) orientations, while for two types of metal-oxide NPs, experiments were performed under both unfavorable and favorable conditions in both up-flow and down-flow orientations. Both breakthrough curves and retained profiles of two types of carbon-based NPs in up-flow orientation were equivalent to those in down-flow orientation, indicating that gravity had negligible effect on the transport and retention of carbon-based NPs under unfavorable conditions. In contrast, under both unfavorable and favorable conditions, the breakthrough curves for two types of metal-oxide NPs in down-flow orientation were lower relative to those in up-flow orientation, indicating that gravity could decrease the transport of metal-oxide NPs in porous media. The distinct effect of gravity on the transport and retention of carbon-based and metal-oxide NPs was mainly attributed to the contribution of gravity to the force balance on the NPs in quartz sand. The contribution of gravity was determined by the interplay of the density and sizes of NP aggregates under examined solution conditions. Copyright © 2015 Elsevier B.V. All rights reserved.

  9. Sand supply to beaches (United States)

    Aagaard, Troels


    In most cases, beaches and dunes are built by sand that has been transported onshore from the shoreface. While this has been known for a long time, we are still not able to quantitatively predict onshore sediment transport and sand supply to beaches. Sediment transport processes operating during brief, high-energy stormy conditions - when beaches erode and sand moves offshore - are fairly well known and they can be modelled with a reasonable degree of confidence. However, the slower onshore sand transport leading to beach recovery under low-to-moderate energy conditions - and the reason why beaches and dunes exist in the first place - is not yet well understood. This severely limits our capability to understand and predict coastal behaviour on long time scales, for example in response to changing sea level or wave conditions. This paper will discuss issues and recent developments in sediment transport measurement and prediction on the lower and upper shoreface and into the swash zone. The focus will be on the integration and upscaling of small-scale deterministic process measurements into parametric models that may increase modelling capabilities of coastal behaviour on larger temporal and spatial scales.

  10. Conditions and processes affecting sand resources at archeological sites in the Colorado River corridor below Glen Canyon Dam, Arizona (United States)

    East, Amy E.; Collins, Brian D.; Sankey, Joel B.; Corbett, Skye C.; Fairley, Helen C.; Caster, Joshua


    This study examined links among fluvial, aeolian, and hillslope geomorphic processes that affect archeological sites and surrounding landscapes in the Colorado River corridor downstream from Glen Canyon Dam, Arizona. We assessed the potential for Colorado River sediment to enhance the preservation of river-corridor archeological resources through aeolian sand deposition or mitigation of gully erosion. By identifying locally prevailing wind directions, locations of modern sandbars, and likely aeolian-transport barriers, we determined that relatively few archeological sites are now ideally situated to receive aeolian sand supply from sandbars deposited by recent controlled floods. Whereas three-fourths of the 358 river-corridor archeological sites we examined include Colorado River sediment as an integral component of their geomorphic context, only 32 sites currently appear to have a high degree of connectivity (coupled interactions) between modern fluvial sandbars and sand-dominated landscapes downwind. This represents a substantial decrease from past decades, as determined by aerial-photograph analysis. Thus, we infer that recent controlled floods have had a limited, and declining, influence on archeological-site preservation.

  11. Effects of Outer Membrane Proteins (OMPs) on the Transport of Escherichia coli within Saturated Sands (United States)

    Xu, S.; Bardy, S.; Feriancikova, L.


    A thorough understanding of the transport behavior of bacteria within the groundwater system is critical to the protection of groundwater resources from microbial contamination and the reduction of associated public health risks. In this study, we used TolC and Ag43 positive and negative E. coli mutants to evaluate the effects of OMP TolC and Ag43 on the transport behavior of E. coli under a wide range of water chemistry conditions. The surface properties (e.g., zeta potential, contact angles of three probing liquid) of TolC and Ag43 positive and negative E. coli cells were determined and the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory, which considers Lifshitz-van der Waals (LW) interaction, the electrostatic double layer (EDL) interaction as well as the Lewis acid-base (AB) (i.e., hydrophobic) interaction between E. coli cells and the surface of quartz sands, were used to explain the observed trend in E. coli mobility. In general, good agreements between the experimental observations and XDLVO calculations were observed. Findings from this research suggested that OMPs could significantly impact bacterial mobility in sandy aquifers.

  12. Effects of Heterogeneous Adsorption Affinity on Natural Organic Matter (NOM) Transport in Laboratory Sand Columns (United States)

    McInnis, D. P.; Bolster, D.; Maurice, P. A.


    Transport of reactive sorbing solutes through porous media is commonly quantified by implementing an effective retardation coefficient in the advection-dispersion equation (ADE), which describes dispersion in accordance with Fick's law. However, anomalous (non-Fickian) transport behavior can be observed in systems with heterogeneous retardation coefficients (Dentz & Castro, 2009). In such systems, the ADE is unable to reproduce the non-Fickian nature of plume shapes and breakthrough curves, motivating the development and application of alternative solute transport theories, such as the continuous time random walk (CTRW) or multi-rate mass transfer (MRMT). Heterogeneity in retardation coefficients in practice arises from variability in the geochemical properties controlling sorption-desorption kinetics between the solute and mineral surfaces. These distributions have been described in the context of heterogeneity of the porous medium, but to date little attention has been given to the potential role of a geochemically heterogeneous solute. In this work, we consider a system in which anomalous transport arises during the passage of natural organic matter (NOM), a polydisperse mixture of compounds derived from the breakdown of plants and microorganisms in the environment, through homogeneous laboratory sand columns. NOM solutions were passed through columns containing either hematite, corundum, or a naturally-coated quartz sand at a variety of pH and ionic strength conditions. Influent and effluent NOM concentration was measured as UV absorbance at 254 nm. The resulting breakthrough curves are non-Fickian, displaying power-law tailing at late times. Such curves cannot be predicted by the ADE model. Reactivity of NOM components is known to be related to their molecular weight (MW), which tends to be log-normally distributed in aquatic NOM isolates (Cabaniss et al., 2000). Low-MW compounds are more water-soluble, have a higher diffusion coefficient, and due to their

  13. Flow and suspended sediment transport through the gravel-sand transition in the Fraser River, British Columbia



    The Fraser River, British Columbia is a large alluvial channel that features an abrupt gravel-sand transition that occurs due to a dramatic slope change and the ocean base-level control. There have been no previous observations of the sediment dynamics through transitions in rivers of this scale. I examine the spatial and temporal changes in flow and the suspended sediment transport regime through the transition using hydro-acoustics in an attempt to test the hypothesis that sand in the grave...

  14. Sand, die and investment cast parts via the SLS selective laser sintering process (United States)

    van de Crommert, Simon; Seitz, Sandra; Esser, Klaus K.; McAlea, Kevin


    Complex three-dimensional parts can be manufactured directly from CAD data using rapid prototyping processes. SLS selective laser sintering is a rapid prototyping process developed at the University of Texas at Austin and commercialized by DTM Corporation. SLS parts are constructed layer by layer from powdered materials using laser energy to melt CAD specified cross sections. Polymer, metal, and ceramic powders are all potential candidate materials for this process. In this paper the fabrication of complex metal parts rapidly using the investment, die and sand casting technologies in conjunction with the selective laser sintering process are being explained and discussed. TrueForm and polycarbonate were used for investment casting, while RapidSteel metal mould inserts were used for the die casting trials. Two different SandForm materials, zircon and silica sand, are currently available for the direct production of sand moulds and cores. The flexible and versatile selective laser sintering process all these materials on one single sinterstation. Material can be changed fast and easily between two different builds.

  15. Debris flows on the Great Kobuk Sand Dunes, Alaska: Implications for analogous processes on Mars (United States)

    Hooper, Donald M.; Dinwiddie, Cynthia L.


    We observed niveo-aeolian deposits, denivation features, and small meltwater-induced debris flows that had formed at the Great Kobuk Sand Dunes, northwestern interior Alaska in late March 2010. This high-latitude, cold-climate dune field is being studied as a planetary analog to improve our understanding of factors that may trigger debris flows on the lee slopes of martian aeolian dunes. Debris flows consisted of a sand and liquid water mixture that cascaded down the lee slopes of two barchanoid dunes on days when measured ground surface temperatures were below freezing. We hypothesize that relatively dark sand on snow caused local hot spots where solar radiation could be absorbed by the sand and conducted into the underlying snow, enabling meltwater to form and sand to be mobilized. This investigation provides insights into the interactions between niveo-aeolian deposition, slope aspect and insolation, thawing, and initiation of alluvial processes. These debris flows are morphologically similar to those associated with seasonal gullies or erosion tracks visible on the slopes of mid- to high-latitude dune fields in both martian hemispheres. Localized heating and thawing at scales too small for orbital sensors to identify may yield martian debris flows at current climate conditions.

  16. Characterization of oil sands process-affected waters by liquid chromatography orbitrap mass spectrometry. (United States)

    Pereira, Alberto S; Bhattacharjee, Subir; Martin, Jonathan W


    Recovery of bitumen from oil sands in northern Alberta, Canada, occurs by surface mining or in situ thermal recovery, and both methods produce toxic oil sands process-affected water (OSPW). A new characterization strategy for surface mining OSPW (sm-OSPW) and in situ OSPW (is-OSPW) was achieved by combining liquid chromatography with orbitrap mass spectrometry (MS). In electrospray positive and negative ionization modes (ESI(+)/ESI(-)), mass spectral data were acquired with high resolving power (RP > 100,000-190,000) and mass accuracy (method should be further applied to environmental forensic analysis of water in the region.

  17. Ozonation of oil sands process water removes naphthenic acids and toxicity. (United States)

    Scott, Angela C; Zubot, Warren; MacKinnon, Michael D; Smith, Daniel W; Fedorak, Phillip M


    Naphthenic acids are naturally-occurring, aliphatic or alicyclic carboxylic acids found in petroleum. Water used to extract bitumen from the Athabasca oil sands becomes toxic to various organisms due to the presence of naphthenic acids released from the bitumen. Natural biodegradation was expected to be the most cost-effective method for reducing the toxicity of the oil sands process water (OSPW). However, naphthenic acids are poorly biodegraded in the holding ponds located on properties leased by the oil sands companies. In the present study, chemical oxidation using ozone was investigated as an option for mitigation of this toxicity. Ozonation of sediment-free OSPW was conducted using proprietary technology manufactured by Seair Diffusion Systems Inc. Ozonation for 50min generated a non-toxic effluent (based on the Microtox bioassay) and decreased the naphthenic acids concentration by approximately 70%. After 130min of ozonation, the residual naphthenic acids concentration was 2mgl(-1): or = 22).

  18. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research

    Energy Technology Data Exchange (ETDEWEB)

    Speight, J.G.


    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO[sub 2] HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.


    Institute of Scientific and Technical Information of China (English)


    The flow in funnel chamber is typical three-di-mensional flow. The experimental results of clear water flowfield and muddy water flow field show that the flow character-istics in the funnel chamber are favorable to the separation ofwater and sand. Tangential velocity sustains the vortexstrength of the funnel chamber, axial velocity is benefit to thesediment sinking, and radial velocity is benefit to sedimentmoving to desilting hole. So the sand funnel is successful insediment disposal. The sand funnel projection has also gooddesilting effectiveness in practice. Its average flushing dis-charge is 3% of inlet canal discharge, the sand disposal rate is100% for the sand with grain diameter of more than 0. 5mm,and is more than 90% for the sand with grain diameter of lessthan 0. 5mm.

  20. Cell abundance and microbial community composition along a complete oil sand mining and reclamation process (United States)

    Lappé, M.; Schneider, B.; Kallmeyer, J.


    Hydrocarbons constitute an important energy source for microbes but can also be of environmental concern. Microbial activity causes hydrocarbon degradation and thereby loss of economical value, but also helps to remove hydrocarbons from the environment. The present study characterizes the abundance of microbes along the oil sand mining process in Alberta, Canada, as a first approach to assess the impact of mining and oil extraction on the microbial population. After mining the oil is extracted from the sediment by a hot-water extraction (50-60°C), resulting in three major fractions: crude oil, tailings sand and fine tailings. The tailings sand is used as substratum for newly developing soils on the reclamation areas. The very liquid fine tailings still have a TOC content of about 4.3% and are pumped into tailings ponds, where they need up to three decades to settle and solidify. After deposition, these mature fine tailings (MFTs) are enriched in organics (TOC content between 9.6 and 16.8%) and dredged out of the ponds and put on dumps for several years for dewatering. Finally they are brought out onto the reclamation sites and deposited below the sand layer. Cells were extracted from oily sediments according to the protocol of Lappé and Kallmeyer (2011), stained with SYBR Green I and counted by fluorescence microscopy. Cell abundance in the unprocessed oil sand is around 1.6 x 107 cells cm-3. After processing the fresh fine tailings still contain around 1.6 x 107 cells cm-3. Cell counts in the processed MFTs are 5.8 x 107 cells cm-3, whereas in the sand used as substratum for newly developing soils, they are twice as high (1.4 x 108). In root-bearing horizons, cell counts reach 1.1 x 109 cell cm-3. Cell numbers calculated from cultivation experiments are in the same range. Higher cell counts in the tailings sand are probably due to a higher nitrogen supply through the addition of a 35 cm top layer of a peat-mineral mix. In the sand nitrate concentrations are high

  1. Productivity of chironomid larvae exposed to oil sands process water : in situ vs. lab bioassay results

    Energy Technology Data Exchange (ETDEWEB)

    Kennedy, K.; Ciborowski, J. [Windsor Univ., ON (Canada)


    Oil sands process water (OSPW) contains toxic concentrations of salts and napthenic acids that may compromise wetland reclamation efforts. The productivity of wetland biota is one of the criteria used by the Alberta government to determine if land leased to oil sands mining companies is restored. This study determined how chironomid productivity is influenced by the water from oil sands process material (OSPM) affected wetland. In this study, 26 10-day in situ and laboratory bioassays from water of three oil sands process material (OSPM) were compared with water from 3 reference wetlands to determine the influence of water from OSPM affected wetlands on chironomid productivity. Parallel studies were conducted with Chironomus riparius lab-cultured larvae and Chironomus sp larvae cultured from egg masses collected from an OSPW-affected wetland. In situ, chironomids were housed in small cylinders with fine-mesh netting to allow water exchange and contact with the sediment. Preliminary estimates of chironomids emerging from study wetlands indicated that native and lab cultured chironomids are not uniformly responsive to OSPW.

  2. Transport of heavy metals and chemical compatibility of hydraulic conductivity of a compacted sand-bentonite mixture

    Directory of Open Access Journals (Sweden)

    Nanthanit Charoenthaisong


    Full Text Available Clayey soils are usually used as barrier material in landfill liners because of its low hydraulic conductivity and high sorption capacity. Bentonite, which consists mainly of montmorillonite, has a high cation exchange capacity resulting in a high retention capacity of heavy metals. Sand is a permeable material but its hydraulic conductivity decreases significantly when mixed with bentonite. However, using a sand-bentonite mixture as landfill liners is questionable, because the hydraulic conductivity of the sand-bentonite mixture may increase when permeated with heavy metal solutions, which are normally found in landfill leachates. In this paper, transport of heavy metals through a compacted sand-bentonite mixture and its chemical compatibility were studied through the batch adsorption test, the column test, and the hydraulic conductivity test.Experimental results indicate that the sorption capacity of the bentonite, ranked in descending order, was Cr3+, Pb2+, Cd2+, Zn2+, and Ni2+, respectively. The diffusion coefficients of the sand-bentonite mixture were in the order of 10-5 cm2/s and the retardation factors were 130, 115, 111, and 90 for Pb2+, Ni2+, Zn2+, and Cd2+, respectively. The hydraulic conductivity of thesand-bentonite mixture was only compatible with a chromium solution having a concentration not greater than 0.001 M.

  3. Sand deposit-detecting method and its application in model test of sand flow

    Institute of Scientific and Technical Information of China (English)

    黎伟; 房营光; 莫海鸿; 谷任国; 陈俊生


    Against the background of the sand-flow foundation treatment engineering of Guangzhou Zhoutouzui variable cross-section immersed tunnel, a kind of sand deposit-detecting method was devised on the basis of full-scale model test of sand-flow method. The real-time data of sand-deposit height and radius were obtained by the self-developed sand-deposit detectors. The test results show that the detecting method is simple and has high precision. In the use of sand-flow method, the sand-carrying capability of fluid is limited, and sand particles are all transported to the sand-deposit periphery through crater, gap and chutes after the sand deposit formed. The diffusion range of the particles outside the sand-deposit does not exceed 2.0 m. Severe sorting of sand particles is not observed because of the unique oblique-layered depositing process. The temporal and spatial distributions of gap and chutes directly affect the sand-deposit expansion, and the expansion trend of the average sand-deposit radius accords with quadratic time-history curve.

  4. Sand Transport and Turbulence over Immobile Gravel and Cobble Beds: Similarities and Differences Caused by Roughness Scale (United States)

    Wren, D. G.; Langendoen, E. J.; Kuhnle, R. A.


    Characterizing the turbulence generated by flow over rough beds has become increasingly important in support of efforts to predict sediment transport downstream of dams. The advanced age and impending decommissioning of many dams have brought increased attention to the fate of sediments stored in reservoirs. In many cases, fine sediments are reintroduced to coarse substrates that have large volumes of pore space available for storage after having sediments removed by years of sediment-starved flow. The roughness and porosity of the coarse substrate are both affected by the fine sediment elevation relative to the coarse substrate; therefore, the turbulence characteristics and sediment transport over and through these beds are significantly altered after sediment is reintroduced. Experiments at the USDA-ARS-National Sedimentation Laboratory have focused on sand transport and turbulence over two different rough, immobile, substrates: 35 mm gravel and 150 mm cobbles. Detailed acoustic Doppler-based measurements of turbulence structure over the gravel and cobble beds have allowed the influence of the scale of roughness on both the turbulence and sand transport to be evaluated. It was found that the sand transport in both the gravel and cobble beds showed a strong relationship with bed shear stress scaled by the value of the cumulative distribution of bed elevation at the level of sand within the rough bed. Reynolds stresses near and just below the top of the cobble bed show a region of near constant value with depth, while, for the gravel bed there is a gradual decrease in Reynolds stress beginning just above the gravel and decreasing with increasing depth into the gravel. Dispersive stresses show a very similar patter with a peak at the top of the roughness elements decaying to zero with increasing distance above and below.

  5. Imidacloprid transport and sorption nonequilibrium in single and multilayered columns of Immokalee fine sand. (United States)

    Leiva, Jorge A; Nkedi-Kizza, Peter; Morgan, Kelly T; Kadyampakeni, Davie M


    Imidacloprid (IMD) is a neonicotinoid pesticide soil-drenched to many crops to control piercing-sucking insects such as the Asian citrus psyllid (ACP). Neonicotinoids are persistent in the environment and transport analyses are helpful estimate leaching potential from soils that could result in groundwater pollution. The objective of this study was to analyze IMD breakthrough under saturated water flow in soil columns packed with three horizons (A, E, Bh) of Immokalee Fine Sand (IFS). Also, we used the dimensionless form of the convective-dispersive model (CD-Model) to compare the optimized transport parameters from each column experiment (retardation factor, R; fraction of instantaneous-to-total retardation, β; and mass transfer coefficient, ω) with the parameters obtained from sorption batch equilibria and sorption kinetics. The tracer (Cl-) breakthrough curves (BTCs) were symmetrical and properly described by the CD-Model. IMD BTCs from A, Bh, and multilayered [A+E+Bh] soil columns showed steep fronts and tailing that were well described by the one-site nonequilibrium (OSNE) model, which was an evidence of non-ideal transport due to IMD mass transfer into the soil organic matter. In general, IMD was weakly-sorbed in the A and Bh horizons (R values of 3.72 ± 0.04 and 3.08 ± 0.07, respectively), and almost no retardation was observed in the E horizon (R = 1.20 ± 0.02) due to its low organic matter content (0.3%). Using the HYDRUS-1D package, optimized parameters (R, β, ω) from the individual columns successfully simulated IMD transport in a multilayered column mimicking an IFS soil profile. These column studies and corresponding simulations agreed with previous findings from batch sorption equilibria and kinetics experiments, where IMD showed one-site kinetic mass transfer between soil surfaces and soil solution. Ideally, sandy soils should be maintained unsaturated by crop irrigation systems and rainfall monitoring during and after soil-drench application

  6. Simulation of aeolian sand saltation with rotational motion (United States)

    Huang, Ning; Wang, Cong; Pan, Xiying


    In this work, we propose a theoretical model based on the distribution functions of initial liftoff velocity and angular velocity of sand grains to describe a sand saltation process in which both wind field-sand grain coupling and the Magnus force experienced by saltating sand grains have been incorporated. The computation results showed that the Magnus force had significant effects on sand grain saltation. In particular, when the Magnus force was incorporated, the calculated sand transport fluxes and sand transport rate per unit width were closer to the experimental value than when this force was excluded. The sand transport flux is enhanced because the Magnus force owing to particle rotation causes the particles to have higher and longer trajectories, so the particles can get more speed and energy from the wind, which leads to a larger sand transport flux. In addition, it was found that when taking the Magnus force into account, the probability density of the impact velocity and angular velocity of saltating sand grains followed an exponential distribution and a unimodal asymmetric distribution, respectively. Moreover, the sand energy flux increased with the height above the sand surface until the energy flux reached its maximum and then decreased. Furthermore, the energy flux near the ground surface decreased as the grain diameter increased, but beyond a specific height the energy flux increased with the grain diameter. Finally, for the same sand grain diameter, the energy flux increased with the friction velocity.

  7. Literature survey of in situ processes for application to the US tar sand resource

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, Jr., L. A.


    Tar sands in the United States and worldwide are a large potential source of hydrocarbon liquids that has yet to be sufficiently developed. The development of the US tar sand resource lags the worldwide development and poses a challenge that has not been eagerly accepted by the petroleum industry. This paper reviews the developmental status of in situ enhanced oil recovery techniques that have been proposed for the production of heavy oils or bitumen and determines which process or processes are in the forefront for application to the US resource. Also noted is what developmental work, if any, remains to be accomplished before field testing of the process(es). The review used only information available in the public domain. 196 refs., 1 fig., 2 tabs.

  8. Shining a light on oil sands production : spectroscopy could bring flash of insight to ore processing

    Energy Technology Data Exchange (ETDEWEB)

    Zlotnikov, D.


    Oil sands are a mixture of silts, sands and clay, and the variability poses challenges to surface mine operators. A professor of Earth and Atmospheric Sciences at the University of Alberta has been working on a spectroscopy project to provide the oil sand industry with real-time ore composition and particle size readings from the mine face. These can then be used to adjust processing conditions at the extraction plant or froth treatment facility, ensuring optimal recovery levels and smooth operation. Developing a spectrographic fingerprint of an ore sample involves shining a very narrow wavelength of light at the sample, recording the intensity of reflected light and repeating the process across a range of wavelengths. The challenges of putting the spectroscopic equipment at the mine site were described. The project is 1 of the more than 20 projects currently at the Centre for Oil Sands Innovation (COSI), a partnership between Imperial Oil and the University of Alberta. Imperial contributed $10 million in funding over the following 5 years, with the governments of Alberta and Canada contributing additional funds. Imperial Oil is not the only beneficiary of COSI research, as all work that comes out of COSI is ultimately published. 1 fig.

  9. Sand Resources, Regional Geology, and Coastal Processes of the Chandeleur Islands Coastal System: an Evaluation of the Breton National Wildlife Refuge (United States)

    Lavoie, Dawn


    Monkey Bayou at the southern end of the Chandeleur Islands. Numerical simulation of waves and sediment transport supports the geophysical results and indicates that vast areas of the lower shoreface are affected and are undergoing erosion during storm events, that there is little or no fair weather mechanism to rework material into the littoral system, and that as a result, there is a net loss of sediment from the system. Lidar surveys revealed that the island chain immediately after Hurricane Katrina lost about 84 percent of its area and about 92 percent of its prestorm volume. Marsh platforms that supported the islands' sand prior to the storm were reduced in width by more than one-half. Repeated lidar surveys document that in places the shoreline has retreated about 100 m under the relatively low-energy waves since Hurricanes Katrina and Rita; however, this retreat is nonuniform. Recent high-resolution geophysical surveys of the sea floor and subsurface within 5-6 km of the Chandeleur Islands during 2006 and 2007 show that, in addition to the sand that is rebuilding portions of the island chain, a large volume of sand is contained in Hewes Point, in an extensive subtidal spit platform that has formed at the northern end of the Chandeleur Islands. Hewes Point appears to be the depositional terminus of the alongshore transport system. In the southern Chandeleurs, sand is being deposited in a broad tabular deposit near Breton Island called the southern offshore sand sheet. These two depocenters account for approximately 70 percent of the estimated sediment volume located in potential borrow sites. An additional large potential source of sand for restoration lies in the St. Bernard Shoals, which are estimated to contain approximately 200 ? 106 m3 of sand. Successful restoration planning for the Breton National Wildlife Refuge should mimic the natural processes of early stages of barrier island evolution including lateral transport to the flanks of the island chain

  10. 砂再生与砂冷却工艺装备的技术创新%The innovation of the sand regeneration and sand cooling process equipment

    Institute of Scientific and Technical Information of China (English)



    the paper introduces the casting process and the new development of the old sand regeneration and cooling process equipment technical characteristics. Sand regeneration, sand cooling and the application state of typical process equipment is analyzed. Provide process and technical support for the regeneration of foundry sand. Expand the development direction of the casting process equipment and production application.%介绍了近几年自硬砂工艺应用中新研发应用的旧砂再生、冷却工艺装备的技术特性.分析了自硬砂铸造工艺应用中砂再生、砂冷却及典型工艺装备的应用状态.为铸造业砂再生提供工艺及技术支持,拓展铸造工艺装备与生产应用的创新发展思路.

  11. Transport, retention, and long-term release behavior of ZnO nanoparticle aggregates in saturated quartz sand: Role of solution pH and biofilm coating (United States)

    The transport, retention, and long-term fate of zinc oxide nanoparticles (ZnO-NPs) were investigated in saturated, bare and biofilm (Pseudomonas putida) coated sand packed columns. Almost complete retention of ZnO-NPs occurred in bare and biofilm coated sand when the influent solution pH was 9 and t...

  12. Deficit of sand in a sediment transport model favors coral reef development in Brazil

    Directory of Open Access Journals (Sweden)

    Abílio C.S.P. Bittencourt


    Full Text Available This paper shows that the location of the shoreface bank reefs along the northeastern and eastern coasts of Brazil, in a first order approximation, seem to be controlled by the deficit of sediment in the coastal system. The sediment transport pattern defined by a numerical modeling of wave refraction diagrams, representing circa 2000 km of the northeastern and eastern coasts of Brazil, permitted the regional-scale reproduction of several drift cells of net longshore sediment transport. Those drift cells can reasonably explain the coastal sections that present sediment surplus or sediment deficit, which correspond, respectively, to regions where there is deposition and erosion or little/no deposition of sand. The sediment deficit allows the exposure and maintenance of rocky substrates to be free of sediment, a favorable condition for the fixation and development of coral larvae.Este trabalho mostra que a localização dos recifes de coral ao longo dos litorais leste e nordeste do Brasil, em uma aproximação de primeira ordem, parece ser controlada pelo déficit de sedimentos no sistema costeiro. O padrão de transporte de sedimentos definido por modelagem numérica a partir de diagramas de refração de ondas, representando cerca de 2000 km dos litorais leste e nordeste do Brasil, permitiu a reprodução, em escala regional, de várias células de deriva litorânea efetiva de sedimentos. Essas células de deriva podem razoavelmente explicar os segmentos costeiros que representam superávit, ou deficit de sedimentos que correspondem, respectivamente, a regiões onde existe deposição e erosão ou pouca/nenhuma deposição de areia. O deficit de sedimentos propicia a exposição e manutenção de substratos rochosos livres de sedimento, uma condição favorável para a fixação e desenvolvimento das larvas de coral.

  13. 从砂处理系统改造谈型砂性能控制%Control of Sand Properties by Sand Processing System Reform

    Institute of Scientific and Technical Information of China (English)



    The sand processing equipments were reformed to improve and stabilize the sand quality of product line, and the influencing factors of sand performance were analyzed. The sand quality is improved by the control of sand properties, and the ratio of effective bentonite content and moisture content, the ratio of compactability and moisture content are more reasonable. The rejection rate of crush and blowhole is reduced greatly.%为了提高和稳定生产线的型砂质量,对砂处理系统设备进行了整体改造,分析了型砂性能的影响因素。通过严格控制型砂性能指标,提高了型砂质量,使有效膨润土与水分比、紧实率与水分比趋于合理,铸件落砂、气孔废品率大幅下降。

  14. Phenomenological Description of Acoustic Emission Processes Occurring During High-Pressure Sand Compaction (United States)

    Delgado-Martín, Jordi; Muñoz-Ibáñez, Andrea; Grande-García, Elisa; Rodríguez-Cedrún, Borja


    Compaction, pore collapse and grain crushing have a significant impact over the hydrodynamic properties of sand formations. The assessment of the crushing stress threshold constitutes valuable information in order to assess the behavior of these formations provided that it can be conveniently identified. Because of the inherent complexities of the direct observation of sand crushing, different authors have developed several indirect methods, being acoustic emission a promising one. However, previous researches have evidenced that there are different processes triggering acoustic emissions which need to be carefully accounted. Worth mentioning among them are grain bearing, grain to container friction, intergranular friction and crushing. The work presented here addresses this purpose. A broadband acoustic emission sensor (PA MicroHF200) connected to a high-speed data acquisition system and control software (AeWIN for PCI1 2.10) has been attached to a steel ram and used to monitor the different processes occurring during the oedometric compaction of uniform quartz sand up to an axial load of about 110 MPa and constant temperature. Load was stepwise applied using a servocontrolled hydraulic press acting at a constant load rate. Axial strain was simultaneously measured with the aid of a LDT device. Counts, energy, event duration, rise time and amplitude were recorded along each experiment and after completion selected waveforms were transformed from the time to the frequency domain via FFT transform. Additional simplified tests were performed in order to isolate the frequency characteristics of the dominant processes occurring during sand compaction. Our results show that, from simple tests, it is possible to determine process-dependent frequency components. When considering more complex experiments, many of the studied processes overlap but it is still possible to identify when a particular one dominates as well as the likely onset of crushing.

  15. Processes of coastal bluff erosion in weakly lithified sands, Pacifica, California, USA (United States)

    Collins, B.D.; Sitar, N.


    Coastal bluff erosion and landsliding are currently the major geomorphic processes sculpting much of the marine terrace dominated coastline of northern California. In this study, we identify the spatial and temporal processes responsible for erosion and landsliding in an area of weakly lithified sand coastal bluffs located south of San Francisco, California. Using the results of a five year observational study consisting of site visits, terrestrial lidar scanning, and development of empirical failure indices, we identify the lithologic and process controls that determine the failure mechanism and mode for coastal bluff retreat in this region and present concise descriptions of each process. Bluffs composed of weakly cemented sands (unconfined compressive strength - UCS between 5 and 30??kPa) fail principally due to oversteepening by wave action with maximum slope inclinations on the order of 65 at incipient failure. Periods of significant wave action were identified on the basis of an empirical wave run-up equation, predicting failure when wave run-up exceeds the seasonal average value and the bluff toe elevation. The empirical relationship was verified through recorded observations of failures. Bluffs composed of moderately cemented sands (UCS up to 400??kPa) fail due to precipitation-induced groundwater seepage, which leads to tensile strength reduction and fracture. An empirical rainfall threshold was also developed to predict failure on the basis of a 48-hour cumulative precipitation index but was found to be dependent on a time delay in groundwater seepage in some cases.

  16. Transport and Retention of Toxoplasma gondii Oocysts in Loamy Sand and Sandy Loam Soils (United States)

    Kinsey, E. N.; Korte, C.; L'Ollivier, C.; Dubey, J. P.; Aurélien, D.; Darnault, C. J. G.


    Toxoplasma gondii is one of the most prevalent parasites affecting warm-blooded animals and humans. It has a complex life cycle that involves a wide variety of intermediate hosts with felids as a definitive host. Humans may contract it through consumption of infected, undercooked meat or by water or food sources contaminated with the oocyst form of the parasite. Infection of pregnant women can cause stillbirth, neurological effects or blindness. Because of the prevalence of cats, including on farms where oocyst-contaminated cat feces, animal feed, soil and water have been found, T. gondii is spread almost throughout the entire globe. It has been implicated or suspected in waterborne infections since the 1990s. This study aims to characterize the transport and retention of T. gondii oocysts in field soils. The four soils used were collected from fallow and cultivated fields in Illinois and Utah, USA. They are classified as loamy sands and sandy loams. Soil columns were subjected to continuous artificial rainfall until they reached steady state at which point pulses that included 2.5 million T. gondii oocysts (Me49 strain) and KBr as a tracer were added. After the pulse infiltrated, continuous rainfall was resumed. Rain applied all columns was a 1 mM KCl solution. Leachate samples were collected, analyzed using qPCR for T. gondii and bromide ions and breakthrough curves were produced. Soil was sliced into 1 to 2 cm sections, for which water content and T. gondii concentration were measured to access degree of saturation and oocyst retention.

  17. An airborne assessment of atmospheric particulate emissions from the processing of Athabasca oil sands

    Directory of Open Access Journals (Sweden)

    S. G. Howell


    Full Text Available During the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS campaign, two NASA research aircraft, a DC-8 and a P-3B, were outfitted with extensive trace gas (the DC-8 and aerosol (both aircraft instrumentation. Each aircraft spent about a half hour sampling air around the oil sands mining and upgrading facilities near Ft. McMurray, Alberta, Canada. The DC-8 circled the area, while the P-3B flew directly over the upgrading plants, sampling close to the exhaust stacks, then headed downwind to monitor the aerosol as it aged. At short range, the plume from the oil sands is a complex mosaic of freshly nucleated ultrafine particles from a SO2 and NO2-rich plume, fly ash and soot from industrial processes, and dust from dirt roads and mining operations. Shortly downwind, organic aerosol appears in quantities that rival SO4=, either as volatile organic vapors condense or as they react with the H2SO4. The DC-8 pattern allowed us to integrate total flux from the oil sands facilities within about a factor of two uncertainty that spanned values consistent with 2008 estimates from reported SO2 and NO2 emissions. In contrast, CO fluxes exceeded reported regional emissions, due either to variability in production or sources missing from the emissions inventory. The conversion rate of SO2 to aerosol SO4= of ~6% per hour is consistent with earlier reports, though OH concentrations are insufficient to accomplish this. Other oxidation pathways must be active. Altogether, organic aerosol and black carbon emissions from the oil sands operations are small compared with the forest fires present in the region during the summer. The oil sands do contribute significant sulfate and exceed fire production of SO2 by an order of magnitude.

  18. Preliminary Research on Granulation Process of Dust Waste from Reclamation Process of Moulding Sands with Furan Resin

    Directory of Open Access Journals (Sweden)

    J. Kamińska


    Full Text Available The results of investigations of the granulation process of foundry dusts generated in the dry mechanical reclamation process of usedsands, where furan resins were binders are presented in the paper. Investigations concerned producing of granules of the determineddimensions and strength parameters.Granules were formed from the dusts mixture consisting in 50 mass% of dusts obtained after the reclamation of the furane sands and in50 mass % of dusts from sands with bentonite. Dusts from the bentonite sands with water were used as a binder allowing the granulation of after reclamation dusts from the furane sands.The following parameters of the ready final product were determined: moisture content (W, shatter test of granules (Wz performeddirectly after the granulation process and after 1, 3, 5, 10 days and nights of seasoning, water-resistance of granules after 24 hours of being immersed in water, surface porosity ep and volumetric porosity ev. In addition the shatter test and water-resistance of granulate dried at a temperature of 105oC were determined.Investigations were performed at the bowl angle of inclination 45o, for three rotational speeds of the bowl being: 10, 15, 20 rpm.For the speed of 10 rpm the granulation tests of dusts mixture after the preliminary mixing in the roller mixer and with the addition ofwater-glass in the amount of 2% in relation to the amount of dust were carried out.The obtained results indicate that the granulator allows to obtain granules from dusts originated from the reclamations of mouldingsands with the furane resin with an addition of dusts from the bentonite sands processing plants.

  19. Hydrodynamic and Sediment Transport Model Application for OSAT3 Guidance: Surf-zone integrated alongshore potential flux for oil-sand balls (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey has developed a method for estimating the mobility and potential alongshore transport of heavier-than-water sand and oil agglomerates...

  20. Hydrodynamic and Sediment Transport Model Application for OSAT3 Guidance: Surf-zone integrated alongshore potential flux for oil-sand balls (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey has developed a method for estimating the mobility and potential alongshore transport of heavier-than-water sand and oil agglomerates...

  1. Purification of wet process phosphoric acid by decreasing iron and uranium using white silica sand

    Energy Technology Data Exchange (ETDEWEB)

    El-Bayaa, A.A., E-mail: [Chemistry Department, Faculty of Science, Al-Azhar University (Girls), Nasr City, Cairo (Egypt); Badawy, N.A.; Gamal, A.M.; Zidan, I.H.; Mowafy, A.R. [Chemistry Department, Faculty of Science, Al-Azhar University (Girls), Nasr City, Cairo (Egypt)


    Natural white silica sand as an adsorbent has been developed to reduce the concentration of iron and uranium ions as inorganic impurities in crude Egyptian phosphoric acid. Several parameters such as adsorbate concentration, adsorbent dose, volume to weight ratio and temperature, were investigated. Equilibrium isotherm studies were used to evaluate the maximum sorption capacity of adsorbent. Thermodynamic parameters showed the exothermic nature of the process and the negative entropy reflects the affinity of the adsorbent material towards each metal ion.

  2. Application of forward osmosis membrane technology for oil sands process-affected water desalination. (United States)

    Jiang, Yaxin; Liang, Jiaming; Liu, Yang


    The extraction process used to obtain bitumen from the oil sands produces large volumes of oil sands process-affected water (OSPW). As a newly emerging desalination technology, forward osmosis (FO) has shown great promise in saving electrical power requirements, increasing water recovery, and minimizing brine discharge. With the support of this funding, a FO system was constructed using a cellulose triacetate FO membrane to test the feasibility of OSPW desalination and contaminant removal. The FO systems were optimized using different types and concentrations of draw solution. The FO system using 4 M NH4HCO3 as a draw solution achieved 85% water recovery from OSPW, and 80 to 100% contaminant rejection for most metals and ions. A water backwash cleaning method was applied to clean the fouled membrane, and the cleaned membrane achieved 77% water recovery, a performance comparable to that of new FO membranes. This suggests that the membrane fouling was reversible. The FO system developed in this project provides a novel and energy efficient strategy to remediate the tailings waters generated by oil sands bitumen extraction and processing.

  3. Filtration treatment of processing kapuas river's water by coral sands/kaolinite/activated carbon (United States)

    Sasri, Risya; Wahyuni, Nelly; Utomo, Kiki Prio


    Filtration treatment of processing Kapuas river's water in the Sepuk Keladi village, West Kalimantan has been conducted. The aims of the treatments to process kapuas river's water with the characteristics of peat into clean water. Processing method using flow-up-flow filtration system with filter media coral sands / kaolinite / activated carbon. Coral sands was obtained from Kijing beach and characterized using X-Ray Diffraction (XRD) and BET method. The XRD spectrum showed strongest peak at 33.09°, 52.40°, 29.34° and it can be concluded that mineral was verified corresponding to calcium consisting of calcite phase. While the result of BET plot point that surface area of coral sands was 4.954 m2/g. The effectiveness of the filtration media was determined by testing parameters such as pH, total suspended solid (TSS), total dissolved solid (TDS), chloride as Cl, and iron as Fe, before and after filtration of Kapuas river's water. The result show that kapuas river's water after filtration treatment was increased pH from 6,53 to 7,2. Filtration using this systems resulted in an average 43,53% reduction in TSS, 91,63% reduction in TDS, 83,63% reduction in content of chloride as Cl and 33,56 % reduction in content iron as Fe, respectively.

  4. Microbially induced carbonate precipitation (MICP) by denitrification as ground improvement method - Process control in sand column experiments (United States)

    Pham, Vinh; van Paassen, Leon; Nakano, Akiko; Kanayama, Motohei; Heimovaara, Timo


    Calcite precipitation induced by microbes has been proven to be efficient in stabilizing granular soils, especially with urea hydrolysis, as it has been successfully demonstrated in a pilot application 2010. However, as a byproduct highly concentrated ammonium chloride (NH4Cl) solution is produced, which has to be removed and disposed and forms a significant disadvantage of the technique that makes an alternative process like denitrification preferred. The proof of principle of microbially induced calcite precipitation (MICP) by denitrification has been demonstrated by Van Paassen et al (2010) who suggested that instead of producing waste as a byproduct, different pre-treated waste streams could be used as substrates for in situ growth of denitrifying bacteria and simultaneous cementation without producing waste to be removed. In this study sand column experiments are performed in which calcium carbonate was successfully precipitated by indigenous denitrifying micro-organisms, which were supplied weekly with a pulse of a substrate solution containing calcium acetate and calcium nitrate. Besides the production of calcite and the growth of bacteria in biofilms, the reduction of nitrate resulted in the production of (nitrogen) gas. It was observed that this gas partly fills up the pore space and consequently contributed to a reduction of the permeability of the treated sand. The presence of gas in the pore space affected the flow of the injected substrates and influenced to the distribution of calcium carbonate. The effect of the mean particle size (D50) on the flow and transport of solutes and gas in the porous media has been evaluated by treating several columns with varying grain size distribution and comparing the change in permeability after each incubation period and analyzing the distribution of the gas throughout the columns using X-ray computed tomography (CT) scanning. The present results show that there is a considerable decrease of permeability - a

  5. Technology strategy for subsea processing and transport; Technology Target Areas; TTA6 - Subsea processing and transportation

    Energy Technology Data Exchange (ETDEWEB)


    OG21 ( Norway's official technology strategy for the petroleum sector issued a revised strategy document in November 2005 (new strategy planned in 2009). In this document 'Subsea processing and transport' was identified as one of the eight new technology target areas (TTAs). The overall OG21 strategy document is on an aggregated level, and therefore the Board of OG21 decided that a sub-strategy for each TTA was needed. This document proposes the sub-strategy for the technology target area 'Subsea processing and transport' which covers the technology and competence necessary to effectively transport well stream to a platform or to onshore facilities. This includes multiphase flow modelling, flow assurance challenges to avoid problems with hydrates, asphaltenes and wax, subsea or downhole fluid conditioning including bulk water removal, and optionally complete water removal, and sand handling. It also covers technologies to increase recovery by pressure boosting from subsea pumping and/or subsea compression. Finally it covers technologies to facilitate subsea processing such as control systems and power supply. The vision of the Subsea processing and transport TTA is: Norway is to be the leading international knowledge- and technology cluster in subsea processing and transport: Sustain increased recovery and accelerated production on the NCS by applying subsea processing and efficient transport solutions; Enable >500 km gas/condensate multiphase well stream transport; Enable >200 km oil-dominated multiphase well stream transport; Enable well stream transport of complex fluids; Enable subsea separation, boosting compression, and water injection; Enable deepwater developments; Enable environmentally friendly and energy efficient field development. Increase the export of subsea processing and transport technology: Optimize technology from the NCS for application worldwide; Develop new technology that can meet the challenges found in

  6. Microfluidics and microscale transport processes

    CERN Document Server

    Chakraborty, Suman


    With an intense focus on micro- and nanotechnology from a fluidic perspective, this book details the research activities in key directions on both the theoretical and experimental fronts. As part of the IIT Kharagpur Research Monograph series, the text discusses topics such as capillary transport in microchannels, fluid friction and heat transfer in microchannels, electrokinetics, and interfacial transport in nanochannels. It also covers nanoparticle transport in colloidal suspensions, bubble generation in microfluidic channels, micro-heat pipe, the lattice Boltzmann method for phase changing

  7. Influence of Geometric Parameters of the Hydrocyclone and Sand Concentration on the Water/Sand/Heavy-Oil Separation Process: Modeling and Simulation

    Directory of Open Access Journals (Sweden)

    F Farias


    Full Text Available In the oil exploitation, produced fluids are composed of oil, gas, water and sand (depending on the reservoir location. The presence of sand in flow oil leads to several industrial problems for example: erosion and accumulation in valves and pipeline. Thus, it is necessary to stop production for manual cleaning of equipments and pipes. These facts have attracted attention of academic and industrial areas, enabling the appearing of new technologies or improvement of the water/oil/sand separation process. One equipment that has been used to promote phase separation is the hydrocyclone due to high performance of separation and required low cost to installation and maintenance. In this sense, the purpose of this work is to study numerically the effect of geometric parameters (vortex finder diameter of the hydrocyclone and sand concentration on the inlet fluid separation process. A numerical solution of the governing equations was obtained by the ANSYS CFX-11 commercial code. Results of the streamlines, pressure drop and separation efficiency on the hydrocyclone are presented and analyzed. It was observed that the particles concentration and geometry affect the separation efficiency of the hydrocyclone.

  8. Rebounding process of moulding sands-thermal degradation of bentonite binding qualities

    Directory of Open Access Journals (Sweden)

    R. Dańko


    Full Text Available Problems related to a gradual degradation of binding qualities of montmorillonite, the main component of foundry bentonites, are presented in the paper. This degradation is caused by high temperatures originated from liquid metal influencing moulding sands. Laboratory measurements of an active binding agent content in classic moulding sands prepared with two types of bentonite and subjected to a controlled heating to high temperatures – were performed. These laboratory examinations were compared to industrial tests, in which a temperature distribution was being determined in several places in the thickness of the casting ingot mould for 24 hours from the moment of pouring liquid metal. On the basis of the performed examinations, the method allowing to determine optimal additions in the rebounding process of the tested bentonites was developed.

  9. Effect of different-sized colloids on the transport and deposition of titanium dioxide nanoparticles in quartz sand. (United States)

    Cai, Li; Peng, Shengnan; Wu, Dan; Tong, Meiping


    Colloids (non-biological and biological) with different sizes are ubiquitous in natural environment. The investigations regarding the influence of different-sized colloids on the transport and deposition behaviors of engineered-nanoparticles in porous media yet are still largely lacking. This study investigated the effects of different-sized non-biological and biological colloids on the transport of titanium dioxide nanoparticles (nTiO2) in quartz sand under both electrostatically favorable and unfavorable conditions. Fluorescent carboxylate-modified polystyrene latex microspheres (CML) with sizes of 0.2-2 μm were utilized as model non-biological colloids, while Gram-negative Escherichia coli (∼ 1 μm) and Gram-positive Bacillus subtilis (∼ 2 μm) were employed as model biological colloids. Under the examined solution conditions, both breakthrough curves and retained profiles of nTiO2 with different-sized CML particles/bacteria were similar as those without colloids under favorable conditions, indicating that the copresence of model colloids in suspensions had negligible effects on the transport and deposition of nTiO2 under favorable conditions. In contrast, higher breakthrough curves and lower retained profiles of nTiO2 with CML particles/bacteria relative to those without copresent colloids were observed under unfavorable conditions. Clearly, the copresence of model colloids increased the transport and decreased the deposition of nTiO2 in quartz sand under unfavorable conditions (solution conditions examined in present study). Both competition of deposition sites on quartz sand surfaces and the enhanced stability/dispersion of nTiO2 induced by copresent colloids were found to be responsible for the increased nTiO2 transport with colloids under unfavorable conditions. Moreover, the smallest colloids had the highest coverage on sand surface and most significant dispersion effect on nTiO2, resulting in the greatest nTiO2 transport. Copyright © 2015. Published

  10. Sand sources and transport pathways for the San Francisco Bay coastal system, based on X-ray diffraction mineralogy (United States)

    Hein, James R.; Mizell, Kira; Barnard, Patrick L.; Barnard, P.L.; Jaffee, B.E.; Schoellhamer, D.H.


    The mineralogical compositions of 119 samples collected from throughout the San Francisco Bay coastal system, including bayfloor and seafloor, area beaches, cliff outcrops, and major drainages, were determined using X-ray diffraction (XRD). Comparison of the mineral concentrations and application of statistical cluster analysis of XRD spectra allowed for the determination of provenances and transport pathways. The use of XRD mineral identifications provides semi-quantitative compositions needed for comparisons of beach and offshore sands with potential cliff and river sources, but the innovative cluster analysis of XRD diffraction spectra provides a unique visualization of how groups of samples within the San Francisco Bay coastal system are related so that sand-sized sediment transport pathways can be inferred. The main vector for sediment transport as defined by the XRD analysis is from San Francisco Bay to the outer coast, where the sand then accumulates on the ebb tidal delta and also moves alongshore. This mineralogical link defines a critical pathway because large volumes of sediment have been removed from the Bay over the last century via channel dredging, aggregate mining, and borrow pit mining, with comparable volumes of erosion from the ebb tidal delta over the same period, in addition to high rates of shoreline retreat along the adjacent, open-coast beaches. Therefore, while previously only a temporal relationship was established, the transport pathway defined by mineralogical and geochemical tracers support the link between anthropogenic activities in the Bay and widespread erosion outside the Bay. The XRD results also establish the regional and local importance of sediment derived from cliff erosion, as well as both proximal and distal fluvial sources. This research is an important contribution to a broader provenance study aimed at identifying the driving forces for widespread geomorphic change in a heavily urbanized coastal-estuarine system.

  11. Transport Processes in Dendritic Crystallization (United States)

    Glicksman, M. E.


    Free dentritic growth refers to the unconstrained development of crystals within a supercooled melt, which is the classical dendrite problem. The development of theoretical understanding of dendritic growth and its experimental status is sketched showing that transport theory and interfacial thermodynamics (capillarity theory) are insufficient ingredients to develop a truly predictive model of dendrite formation. The convenient, but incorrect, notion of maximum velocity was used for many years to estimate the behavior of dendritic transformations until supplanted by modern dynamic stability theory. The proper combinations of transport theory and morphological stability seem to be able to predict the salient aspects of dendritic growth, especially in the neighborhood of the tip.

  12. Transport processes of the legume symbiosome membrane

    Directory of Open Access Journals (Sweden)

    Victoria C Clarke


    Full Text Available The symbiosome membrane (SM is a physical barrier between the host plant and nitrogen-fixing bacteria in the legume-rhizobium symbiosis, and represents a regulated interface for the movement of solutes between the symbionts that is under plant control. The primary nutrient exchange across the SM is the transport of a carbon energy source from plant to bacteroid in exchange for fixed nitrogen. At a biochemical level two channels have been implicated in movement of fixed nitrogen across the SM and a uniporter that transports monovalent dicarboxylate ions has been characterized that would transport fixed carbon. The aquaporin NOD26 may provide a channel for ammonia, but the genes encoding the other transporters have not been identified. Transport of several other solutes, including calcium and potassium, have been demonstrated in isolated symbiosomes, and genes encoding transport systems for the movement of iron, nitrate, sulfate and zinc in nodules have been identified. However, definitively matching transport activities with these genes has proved difficult and many further transport processes are expected on the SM to facilitate the movement of nutrients between the symbionts. Recently, work detailing the SM proteome in soybean has been completed, contributing significantly to the database of known SM proteins. This represents a valuable resource for the identification of transporter protein candidates, some of which may correspond to transport processes previously described, or to novel transport systems in the symbiosis. Putative transporters identified from the proteome include homologues of transporters of sulfate, calcium, peptides and various metal ions. Here we review current knowledge of transport processes of the SM and discuss the requirements for additional transport routes of other nutrients exchanged in the symbiosis, with a focus on transport systems identified through the soybean SM proteome.

  13. 铸造中的联合工艺%Combined Process of Investment Casting and Sand Casting

    Institute of Scientific and Technical Information of China (English)

    陈平; 杨忠耀; 张百堂


    采用水玻璃精铸生产销孔座系列产品遇到了烧砂问题(指在焙烧或浇注中模壳局部烧结并鼓胀导致铸件形成不规则的凹缺陷).由于水玻璃精铸中的涂料耐火度低,且涂料为层状、厚度大、易堆积而形成烧砂,但相同条件下水玻璃砂铸的铸件就不易出现烧砂.试验表明,在水玻璃精铸中局部采用水玻璃砂铸的联合工艺能十分有效地、经济地解决销孔座系列产品的烧砂问题.联合工艺经常是一种解决特殊铸件质量问题的有效方法.%The burn sand problem (Burn sand is a common defect in investment casting which means part of the shell mould gets sintered and deformed during the roasting or pouring) was found in investment casting of pinhole seat series products using sodium silicate sand. It is due to the low refractoriness and thick layer of the coating in the sodium silicate sand, which prones to accumulate, and then cause the burn sand easily. But under the same condition, burn sand does not occur in the sand casting process. The experiments show that combining sand casting process with the investment casting process in the production of pinhole seat series products can remove the burn sand defect effectively and economically. Generally, combined process is an effective method in the production of special castings.

  14. Quantifying the effects of European beach grass on aeolian sand transport over the last century: Bodega Marine Reserve, California (United States)

    Cesmat, R.; Werner, S.; Smith, M. E.; Riedel, T.; Best, R.; Olyarnik, S.


    Introduction of European beach grass (Ammophila arenaria) to coastal dune systems of western North America induced significant changes to the transport and storage of sediment, and consequently the nesting habitat of the western snowy plover (Charadrius alexandrinus nivosus). At the Bodega Marine Reserve and Sonoma Coast State Park, Ammophila was introduced within the ~0.5 km2 dune area in the 1920's to limit the flux of sand through Bodega Harbor and agricultural land. To assess the potential impact of restoration efforts (Ammophila removal) on aeolian sediment flux, we measured sediment flux as a function of wind speeds and ground cover, and used these measurements to parameterize a spatial model for historical sand deposition Fine- to coarse-grained lithic to sub-lithic sand is delivered to the Bodega dune system from Salmon Creek beach, the down-shore terminus of a littoral system fed by the 3846 km2 Russian River catchment, several small (Littoral sediment traverses the 1.8 km wide dune system from NW to SE via aeolian transport. Ammophila colonization occurred initially adjacent to the shoreface, inducing deposition of a ~10 meter-high foredune and has subsequently encroached the ~0.5 km2 region between the foredune and Bodega Harbor. Comparison of historical topographic maps via raster subtraction indicates rapid construction of both the foredune and a ~15 meter-high transverse dune (Gaffney ridge) at the edge of the planted region. An average accumulation rate of ~4,000 m3/yr is indicated within the study swath by the preserved sediment volumes. Within the modern dune system, unvegetated areas exhibit 2-3 meter wavelength, ~1/2 meter amplitude mega-ripples, and the uppermost 2-10 cm consists of coarse-sand to granule-sized armor layer. In contrast, grain-sizes in vegetated areas are largely vertically homogenous. Open areas are typically 2-8 meters lower than adjacent vegetated areas, and show evidence for net lowering of the land surface (i.e., exposed

  15. Effects of slope gradient on hydro-erosional processes on an aeolian sand-covered loess slope under simulated rainfall (United States)

    Zhang, F. B.; Yang, M. Y.; Li, B. B.; Li, Z. B.; Shi, W. Y.


    The aeolian sand-covered loess slope of the Wind-Water Erosion Crisscross Region of the Loess Plateau in China may play a key role in contributing excessive sediment to the Yellow River. Understanding its hydro-erosional processes is crucial to assessing, controlling and predicting soil and water losses in this region and maintaining the ecological sustainability of the Yellow River. Simulated rainfall (intensity 90 mm h-1) was used to investigate the runoff and soil loss from loess slopes with different slope gradients (18%, 27%, 36%, 47%, and 58%) and overlying sand layer thicknesses (0, 5 and 10 cm). As compared with uncovered loess slopes, an overlying sand layer delayed runoff production, reduced cumulative runoff and increased cumulative soil loss, as well as enhancing variations among slope gradients. Cumulative runoff and soil loss from the sand-covered loess slopes increased with increasing slope gradients and then slightly decreased, with a peak at about 47% gradient; they both were greater from the 10-cm sand-covered loess slope than from the 5-cm except for with 18% slope gradient. In general, differences in cumulative runoff between sand layer thicknesses became smaller, while those in cumulative soil loss became larger, with increasing slope gradient. Runoff and soil loss rates on the sand-covered loess slopes exhibited unimodal distributions during the rainstorms. Maximum values tended to occur at the same rain duration, and increased considerably with increasing slope gradient and sand layer thickness on slopes that were less than 47%. Liquefaction process might occur on the lower loess slopes covered with thinner sand layers but failures similar to shallow landslides might occur when the sand layer was thicker on steeper slopes. The presence of an overlying sand layer changed the relationship between runoff and soil loss rates during intense rainstorms and this change varied with different slope gradients. Our results demonstrated that the effects

  16. Characterization of physical mass transport through oil sands fluid fine tailings in an end pit lake: a multi-tracer study (United States)

    Dompierre, Kathryn A.; Barbour, S. Lee


    Soft tailings pose substantial challenges for mine reclamation due to their high void ratios and low shear strengths, particularly for conventional terrestrial reclamation practices. Oil sands mine operators have proposed the development of end pit lakes to contain the soft tailings, called fluid fine tailings (FFT), generated when bitumen is removed from oil sands ore. End pit lakes would be constructed within mined-out pits with FFT placed below the lake water. However, the feasibility of isolating the underlying FFT has yet to be fully evaluated. Chemical constituents of interest may move from the FFT into the lake water via two key processes: (1) advective-diffusive mass transport with upward pore water flow caused by settling of the FFT; and (2) mixing created by wind events or unstable density profiles through the lake water and upper portion of the FFT. In 2013 and 2014, temperature and stable isotopes of water profiles were measured through the FFT and lake water in the first end pit lake developed by Syncrude Canada Ltd. Numerical modelling was undertaken to simulate these profiles to identify the key mechanisms controlling conservative mass transport in the FFT. Shallow mixing of the upper 1.1 m of FFT with lake water was required to explain the observed temperature and isotopic profiles. Following mixing, the re-establishment of both the temperature and isotope profiles required an upward advective flux of approximately 1.5 m/year, consistent with average FFT settling rates measured at the study site. These findings provide important insight on the ability to sequester soft tailings in an end pit lake, and offer a foundation for future research on the development of end pit lakes as an oil sands reclamation strategy.

  17. Effects of outer membrane protein TolC on the transport of Escherichia coli within saturated quartz sands. (United States)

    Feriancikova, Lucia; Bardy, Sonia L; Wang, Lixia; Li, Jin; Xu, Shangping


    The outer membrane protein (OMP) TolC is the cell surface component of several drug efflux pumps that are responsible for bacterial resistance against a variety of antibiotics. In this research, we investigated the effects of OMP TolC on E. coli transport within saturated sands through column experiments using a wild-type E. coli K12 strain (with OMP TolC), as well as the corresponding transposon mutant (tolC::kan) and the markerless deletion mutant (ΔtolC). Our results showed OMP TolC could significantly enhance the transport of E. coli when the ionic strength was 20 mM NaCl or higher. The deposition rate coefficients for the wild-type E. coli strain (with OMP TolC) was usually >50% lower than those of the tolC-negative mutants. The measurements of contact angles using three probe liquids suggested that TolC altered the surface tension components of E. coli cells and lead to lower Hamaker constants for the cell-water-sand system. The interaction energy calculations using the extended Derjaguin-Landau-Verwey-Overbeek (XDLVO) theory suggested that the deposition of the E. coli cell primarily occurred at the secondary energy minimum. The depth of the secondary energy minimum increased with ionic strength, and was greater for the TolC-deletion strains under high ionic strength conditions. Overall, the transport behavior of three E. coli strains within saturated sands could be explained by the XDLVO calculations. Results from this research suggested that antibiotic resistant bacteria expressing OMP TolC could spread more widely within sandy aquifers.

  18. Assessment of existing sediment transport models for sand barrier dynamics under wave and currents

    Digital Repository Service at National Institute of Oceanography (India)

    Thuy, T.T.V.; Nghiem, L.T.; Jayakumar, S.; Nielsen, P.

    The paper summarizes morphology changes over rippled sand barriers under wave and wave combined current of 27 laboratorial experiments. Data of 4 wave conditions (H=10cm, T=1s; H=12cm, T=1s; H=12cm, T=1.5s; H=14cm, T=1.5s) and 6 currents (Q= 10, -10...

  19. Petroleum coke adsorption as a water management option for oil sands process-affected water

    Energy Technology Data Exchange (ETDEWEB)

    Zubot, Warren [Syncrude Canada Ltd., Research and Development, Edmonton, Alberta, Canada T6N 1H4 (Canada); MacKinnon, Michael D. [OSPM Solutions Ltd., Hamilton, Ontario, Canada L8H 6X2 (Canada); Chelme-Ayala, Pamela; Smith, Daniel W. [University of Alberta, Department of Civil and Environmental Engineering, Edmonton, Alberta, Canada T6G 2W2 (Canada); Gamal El-Din, Mohamed, E-mail: [University of Alberta, Department of Civil and Environmental Engineering, Edmonton, Alberta, Canada T6G 2W2 (Canada)


    Water is integral to both operational and environmental aspects of the oil sands industry. A water treatment option based on the use of petroleum coke (PC), a by-product of bitumen upgrading, was examined as an opportunity to reduce site oil sands process-affected water (OSPW) inventories and net raw water demand. Changes in OSPW quality when treated with PC included increments in pH levels and concentrations of vanadium, molybdenum, and sulphate. Constituents that decreased in concentration after PC adsorption included total acid-extractable organics (TAO), bicarbonate, calcium, barium, magnesium, and strontium. Changes in naphthenic acids (NAs) speciation were observed after PC adsorption. A battery of bioassays was used to measure the OSPW toxicity. The results indicated that untreated OSPW was toxic towards Vibrio fischeri and rainbow trout. However, OSPW treated with PC at appropriate dosages was not acutely toxic towards these test organisms. Removal of TAO was found to be an adsorption process, fitting the Langmuir and Langmuir-Freundlich isotherm models. For TAO concentrations of 60 mg/L, adsorption capacities ranged between 0.1 and 0.46 mg/g. This study demonstrates that freshly produced PC from fluid cokers provides an effective treatment of OSPW in terms of key constituents' removal and toxicity reduction. - Highlights: Black-Right-Pointing-Pointer Treatment of oil sands process-affected water (OSPW) using petroleum coke (PC) adsorption was investigated. Black-Right-Pointing-Pointer PC was effective at adsorbing naphthenic acids with higher cyclicity. Black-Right-Pointing-Pointer OSPW treated with PC at appropriate dosages was not toxic towards Vibrio fisheri and rainbow trout. Black-Right-Pointing-Pointer The adsorption of organic acids fitted the Langmuir and Langmuir-Freundlich isotherm models. Black-Right-Pointing-Pointer PC has the potential to be an effective adsorbent to treat OSPW either directly or as a pretreatment step.

  20. Effects of plasma treatment and sanding process on surface roughness of wood veneers



    An ideal veneer surface is crucial for good panel properties in plywood manufacturing. The aim of this study was to compare plasma treatments and sanding (mechanical) processes with respect to the surface roughness of veneers. Rotary-cut veneers with a thickness of 2 mm from Scots pine (Pinus sylvestris) logs were used as material. After rotary peeling, veneer sheets were dried at 110 °C in a veneer dryer. Veneer sheets were divided into 4 main groups. The surfaces of the control veneer sheet...

  1. Investigations of physicochemical properties of dusts generated in mechanical reclamation process of spent moulding sands with alkaline resins

    Directory of Open Access Journals (Sweden)

    R. Dańko


    Full Text Available Mechanical reclamation processes of spent moulding sands generate large amounts of post-reclamation dusts mainly containing rubbed spent binding agents and quartz dusts. The amount of post-reclamation dusts, depending in the reclamation system efficiency and the reclaim dedusting system, can reach 5%-10% in relation to the total reclaimed spent moulding sand. The proper utilization of such material is a big problem facing foundries these days. This study presents the results of investigations of physicochemical properties of post- reclamation dusts. All tested dusts originated from various Polish cast steel plants applying the mechanical reclamation process of moulding sands with alkaline resins, obtained from different producers. Different dusts, delivered from foundries, were tested to determine their chemical composition, granular characterization, physicochemical and energetic properties. Presented results confirmed assumptions that it is possible to utilize dusts generated during mechanical reclamation of used sands with organic resins as a source of energy.

  2. Transport and Retention of CdSe/ZnS Quantum Dots in Saturated Sand: Effects of Organic Ligands, pH and Ionic Strength (United States)

    Li, Chunyan; Snee, Preston; Darnault, Christophe


    The presence of nanomaterials in soil, water, and air systems following their life cycle or accidents and their effects on the environment and public health are inevitable. Ability to forecast the public health and ecological impacts of these nanomaterials encountered in the environment is limited. Therefore, it is critical to be able to predict the fate and transport on nanomaterials in the environment, in particular the subsurface, in order to conduct risk assessments. To assess the transport and retention of nanomaterials in the subsurface environment, we selected quantum dots (QDs). QDs are metal and semiconductor based nanomaterials that are essential to nanoscience and nanotechnology. Understanding the parameters that effect the transport and retention of QDs in the soil water environment is critical. Natural organic ligands are commonly found in soils and impact the soil physico-chemical processes through multifaceted reactions with metal ions present in soil solution and ligand exchange reactions on soil surfaces. Therefore, ligands may modify the surface properties of QDs and effect their stability, transport and retention in the subsurface environment. In this research, size, surface charge, and stability of CdSe/ZnS QDs in water solutions are monitored in batch experiments. The influence of organic ligands (acetate, oxalate, and citrate) on the stability of QDs at different pHs (1.5, 3.5, 5, 7 and 9) and ionic strengths (0.05 and 0.1 M) conditions were examined. The stability and aggregation phenomena of QDs were studied using UV-vis and DLS methods. Parameters from batch studies were selected to establish chemical conditions to be used in transport experiments to produce breakthrough curves and retention profiles in order to characterize the fate and transport of QDs in saturated sand. These transport experiments are essential to understand the mobility and retention processes in porous media where QD interactions with surfaces of heterogeneous

  3. Limitation of fluorescence spectrophotometry in the measurement of naphthenic acids in oil sands process water. (United States)

    Lu, Weibing; Ewanchuk, Andrea; Perez-Estrada, Leonidas; Sego, Dave; Ulrich, Ania


    Fluorescence spectrophotometry has been proposed as a quick screening technique for the measurement of naphthenic acids (NAs). To evaluate the feasibility of this application, the fluorescence emission spectra of NAs extracted from three oil sands process water sources were compared with that of commercial NAs. The NAs resulting from the bitumen extraction process cannot be differentiated because of the similarity of the fluorescence spectra. Separation of the fluorescent species in NAs using high performance liquid chromatography with fluorescence detector proved unsuccessful. The acidic fraction of NAs is fluorescent but the basic fraction of NAs is not fluorescent, implying that aromatic acids in NAs give rise to the fluorescent signals. The concentrations of NAs in oil sands process water were measured by Fourier transform infrared spectroscopy (FTIR), fluorescence spectrophotometry and ultra high performance liquid chromatography-time of flight/mass spectrometry (UPLC-TOF/MS). Commercial Merichem and Kodak NAs are the best standards to use when measuring NAs concentration with FTIR and fluorescence spectrophotometry. In addition, the NAs concentrations measured by fluorescence spectrophotometry are about 30 times higher than those measured by FTIR and UPLC-TOF/MS. The findings in this study underscore the limitation of fluorescence spectrophotometry in the measurement of NAs.

  4. Simulation of groundwater flow and chloride transport in the “1,200-foot” sand with scenarios to mitigate saltwater migration in the “2,000-foot” sand in the Baton Rouge area, Louisiana (United States)

    Heywood, Charles E.; Lovelace, John K.; Griffith, Jason M.


    Groundwater withdrawals have caused saltwater to encroach into freshwater-bearing aquifers beneath Baton Rouge, Louisiana. The 10 aquifers beneath the Baton Rouge area, which includes East and West Baton Rouge Parishes, Pointe Coupee Parish, and East and West Feliciana Parishes, provided about 184.3 million gallons per day (Mgal/d) for public supply and industrial use in 2012. Groundwater withdrawals from the “1,200-foot” sand in East Baton Rouge Parish have caused water-level drawdown as large as 177 feet (ft) north of the Baton Rouge Fault and limited saltwater encroachment from south of the fault. The recently developed groundwater model for simulating transport in the “2,000-foot” sand was rediscretized to also enable transport simulation within the “1,200-foot” sand and was updated with groundwater withdrawal data through 2012. The model was recalibrated to water-level observation data through 2012 with the parameter-estimation code PEST and calibrated to observed chloride concentrations at observation wells within the “1,200-foot” sand and “2,000-foot” sand. The model is designed to evaluate strategies to control saltwater migration, including changes in the distribution of groundwater withdrawals and installation of scavenger wells to intercept saltwater before it reaches existing production wells.


    Institute of Scientific and Technical Information of China (English)

    佟鼎; 黄宁


    Sand velocity in aeolian sand transport is measured using the PIV system(Particle Imaging Velocimetry) in a wind tunnel.The velocity probability distribution of ascending and descending particles,as well the influences of sand ripple on the sand particle motion are analyzed.The results show that velocity distributions of take-off particles and particles during sand movement accord with logarithm normal distribution.The mean incident velocity of sand particles is 1.005-1.4 times higher than take-off ones with different wind speed.It is found that sand ripples play an important role on the sand particles motion,which is a key factor that can not be neglected.%采用PIV(Particle Image Velocimetry)系统测量了天然混合沙风沙两相流中沙粒的速度分布特征,得到了沙粒入射以及起跳的速度分布情况,并且分析了沙波纹对风沙运动的影响。结果表明:沙粒运动过程中的速度分布与沙粒起跳速度的分布可以应用对数正态分布来表明;当有沙波纹存在时,沙粒总体速度分布与平坦沙床面差别很大,是不可忽略的重要因素;平坦沙床面沙粒平均入射速度是起跳平均速度的1.005倍~1.4倍,具体关系可以应用线性函数来拟合。

  6. Transport processes in pea seed coats

    NARCIS (Netherlands)

    Dongen, Joost Thomas van


    The research described in this thesis concerns transport processes in coats of developing pea seeds. The scope of the investigation ranges from seed coat anatomy, via transport studies to the cloning of cDNA encoding proteinaceous membrane pores, and the heterologous expression of these protei

  7. Mimicking Retention and Transport of Rotavirus and Adenovirus in Sand Media Using DNA-labeled, Protein-coated Silica Nanoparticles (United States)

    Pang, Liping; Farkas, Kata; Bennett, Grant; Varsani, Arvind; Easingwood, Richard; Tilley, Richard; Nowostawska, Urszula; Lin, Susan


    Rotavirus (RoV) and adenovirus (AdV) are important viral pathogens for the risk analysis of drinking water. Despite this, little is known about their retention and transport behaviors in porous media (e.g. sand filtered used for water treatment and groundwater aquifers due to a lack of representative surrogates. In this study, we developed RoV and AdV surrogates by covalently coating 70-nm sized silica nanoparticles with specific proteins and a DNA marker for sensitive detection. Filtration experiments using beach sand columns demonstrated the similarity of the surrogates' concentrations, attachment, and filtration efficiencies to the target viruses. The surrogates showed the same magnitude of concentration reduction as the viruses. Conversely, MS2 phage (a traditional virus model) over predicted concentrations of AdV and RoV by 1- and 2-orders of magnitude, respectively. The surrogates remained stable in size, surface charge and DNA concentration for at least one year. They can be easily and rapidly detected at concentrations down to one particle per PCR reaction and are readily detectable in natural waters and even in effluent. With up-scaling validation in pilot trials, the surrogates can be a useful cost-effective new tool for studying virus retention and transport in porous media, e.g. for assessing filter efficiency in water and wastewater treatment, tracking virus migration in groundwater after effluent land disposal, and establishing safe setback distances for groundwater protection.

  8. Humic acid facilitates the transport of ARS-labeled hydroxyapatite nanoparticles in iron oxyhydroxide-coated sand (United States)

    Wang, Dengjun; Bradford, Scott A.; Harvey, Ronald W.; Gao, Bin; Cang, Long; Zhou, Dongmei


    Hydroxyapatite nanoparticles (nHAP) have been widely used to remediate soil and wastewater contaminated with metals and radionuclides. However, our understanding of nHAP transport and fate is limited in natural environments that exhibit significant variability in solid and solution chemistry. The transport and retention kinetics of Alizarin red S (ARS)-labeled nHAP were investigated in water-saturated packed columns that encompassed a range of humic acid concentrations (HA, 0–10 mg L–1), fractional surface coverage of iron oxyhydroxide coatings on sand grains (λ, 0–0.75), and pH (6.0–10.5). HA was found to have a marked effect on the electrokinetic properties of ARS-nHAP, and on the transport and retention of ARS-nHAP in granular media. The transport of ARS-nHAP was found to increase with increasing HA concentration because of enhanced colloidal stability and the reduced aggregate size. When HA = 10 mg L–1, greater ARS-nHAP attachment occurred with increasing λ because of increased electrostatic attraction between negatively charged nanoparticles and positively charged iron oxyhydroxides, although alkaline conditions (pH 8.0 and 10.5) reversed the surface charge of the iron oxyhydroxides and therefore decreased deposition. The retention profiles of ARS-nHAP exhibited a hyperexponential shape for all test conditions, suggesting some unfavorable attachment conditions. Retarded breakthrough curves occurred in sands with iron oxyhydroxide coatings because of time-dependent occupation of favorable deposition sites. Consideration of the above effects is necessary to improve remediation efficiency of nHAP for metals and actinides in soils and subsurface environments.

  9. Effect of Tube Length on Transport of Multi-Wall Nanotubes (MWNTs) in a Water-Saturated Quartz Sand (United States)

    Wang, Y.; Baek, J.; Kim, J.; Pennell, K. D.


    With expanding commercial interests from various application areas, the production of carbon nanotubes (CNTs) in large scale is expected to grow rapidly. The inevitable release of CNTs into the environment and identification of the cytotoxicity of dispersed CNTs prompt the necessity of understanding their transport behavior in porous media. In this study, one-dimensional column experiments were conducted to assess the transport and retention of multi-wall nanotubes (MWNTs) in water-saturated 40-50 mesh Ottawa sand as a function of of tube length. In order to avoid damages to nanotube length by ultrasonication or superacids (e.g., HNO3), a chemical modification method involving a mild acid treatment was adopted to prepare suspensions of MWNTs with three different manufacture-reported (MR) lengths (0.5-2, 10-20, and 50 μm). For each experiment, a pulse (e.g., 5 pore volumes) of MWNT suspension was introduced into the column, followed by 3 pore volumes of MWNT-free solution elution. Measured concentrations of MWNTs in effluent and dissected solid samples were used to construct effluent breakthrough curves and retention profiles, respectively. For an input concentration of ca. 90 mg/L, MWNTs breakthrough concentrations decreased with the increasing MR length. Even with an MR length of 50 μm, MWNTs were readily transported through the packed bed, where ca. 80% of total injected nanotubes passed through the column. While the retention of MWNTs increased with MR length, concentrations of retained nanotubes decreased hyper-exponentially with distance from the column inlet. Further analysis of these findings suggests that clean-bed filtration theory alone is not sufficient to describe MWNT transport and retention behavior in a water-saturated quartz sand.

  10. Solar photocatalytic degradation of naphthenic acids in oil sands process-affected water. (United States)

    Leshuk, Tim; Wong, Timothy; Linley, Stuart; Peru, Kerry M; Headley, John V; Gu, Frank


    Bitumen mining in the Canadian oil sands creates large volumes of oil sands process-affected water (OSPW), the toxicity of which is due in part to naphthenic acids (NAs) and other acid extractable organics (AEO). The objective of this work was to evaluate the potential of solar photocatalysis over TiO2 to remove AEO from OSPW. One day of photocatalytic treatment under natural sunlight (25 MJ/m(2) over ∼14 h daylight) eradicated AEO from raw OSPW, and acute toxicity of the OSPW toward Vibrio fischeri was eliminated. Nearly complete mineralization of organic carbon was achieved within 1-7 day equivalents of sunlight exposure, and degradation was shown to proceed through a superoxide-mediated oxidation pathway. High resolution mass spectrometry (HRMS) analysis of oxidized intermediate compounds indicated preferential degradation of the heavier and more cyclic NAs (higher number of double bond equivalents), which are the most environmentally persistent fractions. The photocatalyst was shown to be recyclable for multiple uses, and thus solar photocatalysis may be a promising "green" advanced oxidation process (AOP) for OSPW treatment.

  11. Growth of Chironomus dilutus larvae exposed to ozone-treated and untreated oil sands process water

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, J.; Wiseman, S.; Franz, E.; Jones, P.; Liber, K.; Giesy, J. [Saskatchewan Univ., Saskatoon, SK (Canada); Gamal El-Din, M.; Marin, J. [Alberta Univ., Edmonton, AB (Canada)


    Oil sand processing operations require large quantities of freshwater and produce large volumes of oil sands process water (OSPW) which must be stored on-site. This presentation reviewed various treatment methods for remediating OSPW in order to eliminate downstream toxicity. Naphthenic acids are the most important target fractions for treatment because they are primarily responsible for the acute toxicity of OSPW. Although ozonation has shown promise for reducing OSPW toxicity, the effects of ozonation on aquatic invertebrates remain unknown. This study investigated the effects of exposure to untreated and ozonated OSPW in Chironomus dilutus larvae. OSPW was treated with either a 50 or 80 mg O{sub 3}/L dose of ozonation. The effects of ozonation levels on C. dilutus survival and growth were examined. The study showed that after a 10-day exposure, there were pronounced effects on survival of larvae exposed to ozone-treated or untreated OSPW. Larvae exposed to OSPW were 64-77 percent smaller than their respective controls, but the mean wet mass of organisms exposed to 50 mg O{sub 3}/L ozonated OSPW was not much different from that of the controls. Larvae exposed to 80 mg O{sub 3}/L ozone-treated OSPW were 40 percent smaller than the freshwater controls, and the mean wet mass was also much larger than the untreated OSPW. It was concluded that the toxicity of OSPW to benthic invertebrates may be reduced by ozone treatment.

  12. Mature fine tailings from oil sands processing harbour diverse methanogenic communities. (United States)

    Penner, Tara J; Foght, Julia M


    Processing oil sands to extract bitumen produces large volumes of a tailings slurry comprising water, silt, clays, unrecovered bitumen, and residual solvent used in the extraction process. Tailings are deposited into large settling basins, where the solids settle by gravity to become denser mature fine tailings (MFT). A substantial flux of methane, currently estimated at ~40 million L/day, is being emitted from the Mildred Lake Settling Basin. To better understand the biogenesis of this greenhouse gas, the methanogenic consortia in MFT samples from depth profiles in 2 tailings deposits (Mildred Lake Settling Basin and West In-Pit) were analyzed by constructing clone libraries of amplified archaeal and bacterial 16S rRNA genes. The archaeal sequences, whose closest matches were almost exclusively cultivated methanogens, were comparable within and between basins and were predominantly (87% of clones) affiliated with acetoclastic Methanosaeta spp. In contrast, bacterial clone libraries were unexpectedly diverse, with the majority (~55%) of sequences related to Proteobacteria, including some presumptive nitrate-, iron-, or sulfate-reducing, hydrocarbon-degrading genera (e.g., Thauera, Rhodoferax, and Desulfatibacillum). Thus, MFT harbour a diverse community of prokaryotes presumptively responsible for producing methane from substrates indigenous to the MFT. These findings contribute to our understanding of biogenic methane production and densification of MFT in oil sands tailings deposits.

  13. Dehydration of moulding sand in simulated casting process examined with neutron radiography

    Energy Technology Data Exchange (ETDEWEB)

    Schillinger, B., E-mail: [Technische Universitaet Muenchen, FRM II and Faculty for Physics E21, Lichtenbergstr. 1, 85748 Garching (Germany); Calzada, E. [Technische Universitaet Muenchen, FRM II and Faculty for Physics E21, Lichtenbergstr. 1, 85748 Garching (Germany); Eulenkamp, C.; Jordan, G.; Schmahl, W.W. [Ludwig-Maximilians-Universitaet Muenchen, Department fuer Geo- und Umweltwissenschaften, Sektion Kristallographie, Theresienstr. 41, 80333 Muenchen (Germany)


    Natural bentonites are an important material in the casting industry. Smectites as the main component of bentonites plasticize and stabilise sand moulds. Pore water as well as interlayer water within the smectites are lost as a function of time, location and temperature. Although rehydration of the smectites should be a reversible process, the industrially dehydrated smectites lose their capability to reabsorb water. This limits the number of possible process cycles of the mould material. A full understanding of the dehydration process would help to optimise the amount of fresh material to be added and thus save resources. A simulated metal casting was investigated with neutron radiography at the ANTARES neutron imaging facility of the FRM II reactor of Technische Universitaet Muenchen, Germany.

  14. Dehydration of moulding sand in simulated casting process examined with neutron radiography (United States)

    Schillinger, B.; Calzada, E.; Eulenkamp, C.; Jordan, G.; Schmahl, W. W.


    Natural bentonites are an important material in the casting industry. Smectites as the main component of bentonites plasticize and stabilise sand moulds. Pore water as well as interlayer water within the smectites are lost as a function of time, location and temperature. Although rehydration of the smectites should be a reversible process, the industrially dehydrated smectites lose their capability to reabsorb water. This limits the number of possible process cycles of the mould material. A full understanding of the dehydration process would help to optimise the amount of fresh material to be added and thus save resources. A simulated metal casting was investigated with neutron radiography at the ANTARES neutron imaging facility of the FRM II reactor of Technische Universität München, Germany.

  15. Fathead minnow (Pimephales promelas) reproduction is impaired in aged oil sands process-affected waters. (United States)

    Kavanagh, Richard J; Frank, Richard A; Oakes, Ken D; Servos, Mark R; Young, Rozlyn F; Fedorak, Phillip M; MacKinnon, Mike D; Solomon, Keith R; Dixon, D George; Van Der Kraak, Glen


    Large volumes of fluid tailings are generated during the extraction of bitumen from oil sands. As part of their reclamation plan, oil sands operators in Alberta propose to transfer these fluid tailings to end pit lakes and, over time, these are expected to develop lake habitats with productive capabilities comparable to natural lakes in the region. This study evaluates the potential impact of various oil sands process-affected waters (OSPW) on the reproduction of adult fathead minnow (Pimephales promelas) under laboratory conditions. Two separate assays with aged OPSW (>15 years) from the experimental ponds at Syncrude Canada Ltd. showed that water containing high concentrations of naphthenic acids (NAs; >25 mg/l) and elevated conductivity (>2000 μS/cm) completely inhibited spawning of fathead minnows and reduced male secondary sexual characteristics. Measurement of plasma sex steroid levels showed that male fathead minnows had lower concentrations of testosterone and 11-ketotestosterone whereas females had lower concentrations of 17β-estradiol. In a third assay, fathead minnows were first acclimated to the higher salinity conditions typical of OSPW for several weeks and then exposed to aged OSPW from Suncor Energy Inc. (NAs ∼40 mg/l and conductivity ∼2000 μS/cm). Spawning was significantly reduced in fathead minnows held in this effluent and male fathead minnows had lower concentrations of testosterone and 11-ketotestosterone. Collectively, these studies demonstrate that aged OSPW has the potential to negatively affect the reproductive physiology of fathead minnows and suggest that aquatic habitats with high NAs concentrations (>25 mg/l) and conductivities (>2000 μS/cm) would not be conducive for successful fish reproduction.

  16. Performance of wetland forbs transplanted into marshes amended with oil sands processed water. (United States)

    Mollard, Federico P O; Roy, Marie-Claude; Foote, A Lee


    Companies mining oil sands in Alberta (Canada) face the challenge of reclaiming wetlands under water use restrictions. Wetland reclamation after mining will generate marshes characterized by elevated salinity and residual hydrocarbons. Oil sands wetlands are also impoverished in forbs, suggesting that their establishment may be constrained by water chemistry. We transplanted skullcap, mint, and smartweed plants into experimental trenches that simulated two possible reclamation scenarios: wetlands amended with on-site freshwater or with oil sands processed water (OSPW). The main scientific question was is OSPW a suitable water amendment as freshwater for reclaiming wetland forb habitat? As a surrogate of plant health, we studied plant ecophysiology (gas exchange, leaf fluorescence), leaf chemistry, and plant growth. Results showed that there were no differences in skullcap mineral contents under either treatment; however, mint and smartweed plants subjected to OSPW had a significantly higher Na content than those under freshwater. Smartweed dark-adapted leaf fluorescence showed a reduced photochemistry in OSPW relative to plants in freshwater. Mint leaves exhibited lower stomatal conductance in OSPW than in freshwater, a condition that negatively affected transpiration and carboxylation. Skullcap plants grown in OSPW had lower net CO2 assimilation rates than those in freshwater but did not show any other ecophysiological difference between treatments. Mint plants experienced growth reductions (i.e., shoot height) in OSPW. Our results show, for the first time in the literature, that plants photosynthetic capacity was negatively affected by OSPW. Conditions in OSPW proved to be suitable for establishment as transplanted forbs showed 100 % survival after the first growing season. However, impaired physiological functions in plants subjected to OSPW indicated that OSPW amendment created a less hospitable habitat for wetland forbs than freshwater.

  17. Applying the Analytic Hierarchy Process to Oil Sands Environmental Compliance Risk Management (United States)

    Roux, Izak Johannes, III

    Oil companies in Alberta, Canada, invested $32 billion on new oil sands projects in 2013. Despite the size of this investment, there is a demonstrable deficiency in the uniformity and understanding of environmental legislation requirements that manifest into increased project compliance risks. This descriptive study developed 2 prioritized lists of environmental regulatory compliance risks and mitigation strategies and used multi-criteria decision theory for its theoretical framework. Information from compiled lists of environmental compliance risks and mitigation strategies was used to generate a specialized pairwise survey, which was piloted by 5 subject matter experts (SMEs). The survey was validated by a sample of 16 SMEs, after which the Analytic Hierarchy Process (AHP) was used to rank a total of 33 compliance risks and 12 mitigation strategy criteria. A key finding was that the AHP is a suitable tool for ranking of compliance risks and mitigation strategies. Several working hypotheses were also tested regarding how SMEs prioritized 1 compliance risk or mitigation strategy compared to another. The AHP showed that regulatory compliance, company reputation, environmental compliance, and economics ranked the highest and that a multi criteria mitigation strategy for environmental compliance ranked the highest. The study results will inform Alberta oil sands industry leaders about the ranking and utility of specific compliance risks and mitigations strategies, enabling them to focus on actions that will generate legislative and public trust. Oil sands leaders implementing a risk management program using the risks and mitigation strategies identified in this study will contribute to environmental conservation, economic growth, and positive social change.

  18. Transport processes in anisotropic gravitational collapse

    CERN Document Server

    Martínez, J


    In this paper we introduce a new method to study the influence of thermal conduction and viscous processes in anisotropic gravitational collapse. To this end we employ the HJR method to solve the Einstein equations. The Maxwell-Cattaneo type transport equations are used to find the temperature and bulk and shear viscous pressures. Under some conditions Maxwell-Cattaneo transport equations comply with relativistic causality. Thus, it is advisable to use them instead of Eckart transport equations. In the inner layers of the star the temperature ceases to be sensitive to the boundary condition. This behavior, which can be explained in terms of the Eddington approximation, allows us to find the thickness of the neutrinosphere. The dynamics of collapsing dense stars is deeply influenced by the neutrino emission/absorption processes. These cool the star and drive it to a new equilibrium state. Therefore, the calculation of transport coefficients is based on these processes.

  19. Evolution of seismic velocities in heavy oil sand reservoirs during thermal recovery process

    CERN Document Server

    Nauroy, Jean-François; Guy, N; Baroni, Axelle; Delage, Pierre; Mainguy, Marc; 10.2516/ogst/2012027


    In thermally enhanced recovery processes like cyclic steam stimulation (CSS) or steam assisted gravity drainage (SAGD), continuous steam injection entails changes in pore fluid, pore pressure and temperature in the rock reservoir, that are most often unconsolidated or weakly consolidated sandstones. This in turn increases or decreases the effective stresses and changes the elastic properties of the rocks. Thermally enhanced recovery processes give rise to complex couplings. Numerical simulations have been carried out on a case study so as to provide an estimation of the evolution of pressure, temperature, pore fluid saturation, stress and strain in any zone located around the injector and producer wells. The approach of Ciz and Shapiro (2007) - an extension of the poroelastic theory of Biot-Gassmann applied to rock filled elastic material - has been used to model the velocity dispersion in the oil sand mass under different conditions of temperature and stress. A good agreement has been found between these pre...

  20. Evaluating the Metal Tolerance Capacity of Microbial Communities Isolated from Alberta Oil Sands Process Water.

    Directory of Open Access Journals (Sweden)

    Mathew L Frankel

    Full Text Available Anthropogenic activities have resulted in the intensified use of water resources. For example, open pit bitumen extraction by Canada's oil sands operations uses an estimated volume of three barrels of water for every barrel of oil produced. The waste tailings-oil sands process water (OSPW-are stored in holding ponds, and present an environmental concern as they are comprised of residual hydrocarbons and metals. Following the hypothesis that endogenous OSPW microbial communities have an enhanced tolerance to heavy metals, we tested the capacity of planktonic and biofilm populations from OSPW to withstand metal ion challenges, using Cupriavidus metallidurans, a known metal-resistant organism, for comparison. The toxicity of the metals toward biofilm and planktonic bacterial populations was determined by measuring the minimum biofilm inhibitory concentrations (MBICs and planktonic minimum inhibitory concentrations (MICs using the MBEC ™ assay. We observed that the OSPW community and C. metallidurans had similar tolerances to 22 different metals. While thiophillic elements (Te, Ag, Cd, Ni were found to be most toxic, the OSPW consortia demonstrated higher tolerance to metals reported in tailings ponds (Al, Fe, Mo, Pb. Metal toxicity correlated with a number of physicochemical characteristics of the metals. Parameters reflecting metal-ligand affinities showed fewer and weaker correlations for the community compared to C. metallidurans, suggesting that the OSPW consortia may have developed tolerance mechanisms toward metals present in their environment.

  1. Oil sands process-affected water impairs feeding by Daphnia magna. (United States)

    Lari, Ebrahim; Steinkey, Dylan; Morandi, Garrett; Rasmussen, Joseph B; Giesy, John P; Pyle, Greg G


    Growth in extraction of bitumen from oil sands has raised concerns about influences of this industry on surrounding environments. Water clearance rate (a surrogate of feeding rate by Daphnia magna) in water containing D. magna exposed to oil sands process-affected water (OSPW) and its principal components, dissolved component (DC) and suspended particulate matter (SPM), was reduced to 72, 29, and 59% of controls, respectively. This study also examined several possible mechanisms for the observed changes algal cell density (i.e., feeding rate). There was no change in the digestive enzymes trypsin or amylase when D. magna were exposed to DC or SPM; however, exposure to total OSPW reduced trypsin activity. Mandible rolling or post-abdominal rejections, which are indicators of feeding and palatability of food, were not affected by any exposures to OSPW. Beating of thoracic limbs, which provides water flow toward the feeding groove, was reduced by exposure to SPM or total OSPW. Peristaltic activity was reduced by exposure to DC, which then might result in reduced digestion time in D. magna exposed to DC, SPM or whole OSPW. All treatments caused an increase in numbers of intact algae cells in the hindgut and excreted material. These results suggest that both DC and SPM affect feeding of D. magna by impairing actions of the digestive system, but most probably not by reducing rates of ingestion.

  2. Heterogeneity of Rapid Sand Filters and Its Effect on Contaminant Transport and Nitrification Performance

    DEFF Research Database (Denmark)

    Lopato, Laure Rose; Galaj, Zofia; Delpont, Sébastien


    dispersivity of more than 33% in the 116 h after the start of filtration with a constant pore-water velocity and a zero-order nitrification rate of 9 mgN=L=h. The full-scale experiments showed that the rapid sand filter was heterogeneous with pore-water velocities ranging from 2.2 to 3:3 m=h for the same inlet...... flow. A first-order nitrification reaction with spatially variable pore-water velocity could be interpreted as a zero-order reaction with a constant pore-water velocity. A model demonstrated that filter heterogeneity could result in higher filter outlet ammonium concentrations....

  3. Mixed sand and gravel beaches: accurate measurement of active layer depth and sediment transport volumes using PIT tagged tracer pebbles (United States)

    Holland, A.; Moses, C.; Sear, D. A.; Cope, S.


    As sediments containing significant gravel portions are increasingly used for beach replenishment projects globally, the total number of beaches classified as `mixed sand and gravel' (MSG) increases. Calculations for required replenishment sediment volumes usually assume a uniform layer of sediment transport across and along the beach, but research into active layer (AL) depth has shown variations both across shore and according to sediment size distribution. This study addresses the need for more accurate calculations of sediment transport volumes on MSG beaches by using more precise measurements of AL depth and width, and virtual velocity of tracer pebbles. Variations in AL depth were measured along three main profile lines (from MHWS to MLWN) at Eastoke, Hayling Island (Hampshire, UK). Passive Integrated Transponder (PIT) tagged pebbles were deployed in columns, and their new locations repeatedly surveyed with RFID technology. These data were combined with daily dGPS beach profiles and sediment sampling for detailed analysis of the influence of beach morphodynamics on sediment transport volumes. Data were collected over two consecutive winter seasons: 2014-15 (relatively calm, average wave height sandy lower foreshore reduced the AL to 10% of wave height in this area. The disparity in AL depth across the beach profile indicates that traditional models are not accurately representing bulk sediment transport on MSG beaches. It is anticipated that by improving model inputs, beach managers will be better able to predict necessary volumes and sediment grain size proportions of replenishment material for effective management of MSG beaches.

  4. Real-Time Simulation of Aeolian Sand Movement and Sand Ripple Evolution: A Method Based on the Physics of Blown Sand

    Institute of Scientific and Technical Information of China (English)

    Ning Wang; Bao-Gang Hu


    Simulation and visualization of aeolian sand movement and sand ripple evolution are a challenging subject.In this paper,we propose a physically based modeling and simulating method that can be used to synthesize sandy terrain in various patterns.Our method is based on the mechanical behavior of individual sand grains,which are widely studied in the physics of blown sand.We accounted significant mechanisms of sand transportation into the sand model,such as saltation,successive saltation and collapsing,while simplified the vegetation model and wind field model to make the simulation feasible and affordable.We implemented the proposed method on the programming graphics processing unit (GPU) to get real-time simulation and rendering.Finally,we proved that our method can reflect many characteristics of sand ripple evolution through several demonstrations.We also gave several synthesized desert scenes made from the simulated height field to display its significance on application.

  5. Criteria for an advanced assessment of quality of moulding sands with organic binders and reclamation process products

    Directory of Open Access Journals (Sweden)

    R. Dańko


    Full Text Available Reclamation of used moulding and core sands has been defined as a treatment of waste moulding refractory materials, enabling a recovery of at least one of the components having properties similar to those of the fresh component, and reuse for production of casting moulds and cores. However, at present, there is a lack of a reclaimed material assessment index, which could be applied to each type of moulding sand and reclaim. Modern investigation methods and equipment for the estimation of the quality of the moulding sands matrices with organic binders, in their circulation process, are presented in this paper. These methods, utilizing the special equipment combined with the author’s investigation methods developed in the Faculty of Foundry Engineering, AGH - University of Science and Technology, allow the better estimation of the matrix quality both in an aspect of its application as a fresh sand substitute in the preparation of moulding sands, and also with regard to the environmental protection. The most important criteria for the technological assessment of the reclaimed materials and the quality of sands with organic binders are presented in this paper.

  6. Coupled transport processes in semipermeable media

    Energy Technology Data Exchange (ETDEWEB)

    Jacobsen, J.S.; Carnahan, C.L.


    The thermodynamics of irreversible processes leads to nonlinear governing equations for direct and coupled mass transport processes. Analytical solutions of linearized versions of these equations can be used to verify numerical solutions of the nonlinear equations under conditions such that nonlinear terms are relatively small. This report presents derivations of the analytical solutions for one-dimensional and axisymmetric geometries. 7 refs.

  7. Application of radiometric analysis in the study of provenance and transport processes of Brazilian coastal sediments

    Energy Technology Data Exchange (ETDEWEB)

    Carvalho, C. [Laboratorio de Radioecologia (LARA), Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza, s/no, Gragoata, 24210-346 Niteroi, RJ (Brazil); Anjos, R.M., E-mail: meigikos@if.uff.b [Laboratorio de Radioecologia (LARA), Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza, s/no, Gragoata, 24210-346 Niteroi, RJ (Brazil); Veiga, R.; Macario, K. [Laboratorio de Radioecologia (LARA), Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza, s/no, Gragoata, 24210-346 Niteroi, RJ (Brazil)


    Natural gamma radiation of beach sand deposits was measured along the south coast of Rio de Janeiro State, Brazil, with the aim of studying the provenance and transport processes of sediments in this area. Concentrations of thorium, uranium and potassium were evaluated using {gamma}-ray spectrometry and a behavioral study of eTh/eU and eTh/K cross plots was performed, reflecting the mineralogical properties of beach sands, as well as their history of transport and sorting processes. The results show that such technique can be efficiently used to map heavy mineral distributions and to distinguish the different origins of coastal sediments disclosing the influence of nearby rivers. - Research highlights: {yields} Based on the natural {gamma}-ray analyses of beach sand, high concentrations of heavy minerals have been found around the Mambucaba River deltaic complex, located in the South of Rio de Janeiro State, Brazil. {yields} Concentrations of thorium, uranium and potassium concentration can give information on the mineral composition and provenance of beach sands and consequently investigate heavy mineral deposits.

  8. Sulfate reducing bacteria and their activities in oil sands process-affected water biofilm

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Hong; Yu, Tong, E-mail:; Liu, Yang, E-mail:


    Biofilm reactors were constructed to grow stratified multispecies biofilm in oil sands process-affected water (OSPW) supplemented with growth medium. The development of sulfate reducing bacteria (SRB) within the biofilm and the biofilm treatment of OSPW were evaluated. The community structure and potential activity of SRB in the biofilm were investigated with H{sub 2}S microsensor measurements, dsrB gene-based denaturing gradient gel electrophoresis (DGGE), and the real time quantitative polymerase chain reaction (qPCR). Multispecies biofilm with a thickness of 1000 μm was successfully developed on engineered biocarriers. H{sub 2}S production was observed in the deeper anoxic zone of the biofilm from around 750 μm to 1000 μm below the bulk water-biofilm interface, revealing sulfate reduction in the deeper zone of the stratified biofilm. The biofilm removed chemical oxygen demand (COD), sulfate, and nitrogen. The study expands current knowledge of biofilm treatment of OSPW and the function of anaerobic SRB in OSPW biofilm, and thus provides information for future bioreactor development in the reclamation of OSPW. - Graphical abstract: The development of sulfate reducing bacteria (SRB) within Oil Sands Process-affected Water (OSPW) biofilm and the biofilm treatment of OSPW were evaluated by Liu and coworkers. Combined microsensor and molecular biology techniques were utilized in this study. Their results demonstrated that multispecies biofilm with a thickness of 1000 μm was successfully developed on engineered biocarriers. H{sub 2}S production was observed in the deeper anoxic zone of the biofilm from around 750 μm to 1000 μm below the bulk water-biofilm interface, revealing sulfate reduction in the deeper zone of the biofilm. The biofilm removed chemical oxygen demand (COD), sulfate, and nitrogen. - Highlights: • Biofilm in oil sands wastewater was developed on engineered biocarriers. • Bacterial community and in situ activity of SRB were studied in the

  9. Computational Fluid Dynamics Simulation of Transport and Retention of Nanoparticle in Saturated Sand Filters (United States)

    Experimental and computational investigation of the transport parameters of nano particles flowing through porous media has been made. The objective of this work was to develop a simulation capability applicable to the transport and retention of nanoparticles (NPs) in saturated p...

  10. Sand resources, regional geology, and coastal processes for shoreline restoration: case study of Barataria shoreline, Louisiana (United States)

    Kindinger, Jack G.; Flocks, James G.; Kulp, Mark; Penland, Shea; Britsch, Louis D.


    The Louisiana barrier shoreline of Barataria Basin, which lies within the western Mississippi River delta, has undergone significant retreat during the past 100 years. The most practical restoration method to rebuild these shorelines is sand nourishment. Seismic and sonar interpretations verified with geologic samples (vibracores and borings) indicate that there are nine sand targets within the Barataria study area that meet or exceed the minimum criteria for potential resource sites. However, the near surface lithology in the basin is typically silts and clays. Locating suitable sand resources for shoreline restoration is challenging. The sand units are associated with geologic depositional systems such as ebb-tidal deltas, distributary mouth bars, and channel fill (undifferentiated fluvial or tidal inlet channels). The nine potential sand targets consist primarily of fine sand and can be delineated into three surficial and six buried features. The surficial features contain approximately 10% of the total sand resources identified. At least 90% of the sand resources need overburden sediment removed prior to use; almost 570 million yd3 (438.5 mil m3) of overburden will need to be removed if the entire resource is mined. In this study, we identified 396 to 532 mil yd3 (305.8 to 410.8 mil m3) of potential sand deposits for shoreline restoration. Previous studies using less dense survey methods greatly over-estimated sand resources available in this area. Many fluvial channels reported previously as sand-filled are mud-filled. Contrary to these previous studies, few fluvial subsystems in this region have abundant sand resources.

  11. Diamondoid diacids ('O4' species) in oil sands process-affected water. (United States)

    Lengger, Sabine K; Scarlett, Alan G; West, Charles E; Rowland, Steven J


    As a by-product of oil sands extraction, large volumes of oil sands process water (OSPW) are generated, which are contaminated with a large range of water-soluble organic compounds. The acids are thought to be derived from hydrocarbons via natural biodegradation pathways such as α- and β-oxidation of alkyl substituents, which could produce mono- and diacids, for example. However, while several monoacids ('O2' species) have been identified, the presence of diacids (i.e. 'O4' species) has only been deduced from results obtained via Fourier transform infrared (FTIR) spectroscopy, Fourier transform ion cyclotron resonance high-resolution mass spectrometry (FTICR-HRMS) and nuclear magnetic resonance ((1)H-NMR) spectroscopy and the structures have never been confirmed. An extract of an OSPW from a Canadian tailings pond was analysed and the retention times and the electron ionization mass spectra of some analytes were compared with those of bis-methyl esters of authentic diacids by gas chromatography × gas chromatography/time-of-flight mass spectrometry (GCxGC/TOFMS) in nominal and accurate mass configurations. Two diamondoid diacids (3-carboxymethyladamantane-1-carboxylic acid and adamantane-1,3-dicarboxylic acid) were firmly identified as their bis-methyl esters by retention time and mass spectral matching and several other structural isomers were more tentatively assigned. Diacids have substantially increased polarity over the hydrocarbon and monoacid species from which they probably derive: as late members of biodegradation processes they may be useful indicators of weathering and ageing, not only of OSPW, but potentially of crude oil residues more generally. Structures of O4 species in OSPW have been identified. This confirms pathways of microbial biodegradation, which were only postulated previously, and may be a further indication that remediation of OSPW toxicity can occur by natural microbial action. The presence and abundance of these diacids might

  12. Processes of microbial pesticide degradation in rapid sand filters for treatment of drinking water

    DEFF Research Database (Denmark)

    Hedegaard, Mathilde Jørgensen; Albrechtsen, Hans-Jørgen

    concentrations of 0.04-2.4 μg/L. The pesticides were removed from the water in microcosms with filter sand from all three investigated sand filters. Within the experimental periode of six to 13 days, 65-85% of the bentazone, 86-93% of the glyphosate, 97-99% of the p-nitrophenol was removed from the water phase......Aerobic rapid sand filters for treatment of groundwater at waterworks were investigated for the ability to remove pesticides. The potential, kinetics and mechanisms of microbial pesticide removal was investigated in microcosms consisting of filter sand, treated water and pesticides in initial...

  13. Size- and concentration-dependent deposition of fluorescent silica colloids in saturated sand columns: transport experiments and modeling. (United States)

    Vitorge, Elsa; Szenknect, Stéphanie; Martins, Jean M F; Gaudet, Jean-Paul


    This study investigates the size and concentration effects on the transport of silica colloids in columns of sandy aquifer material. Colloid transport experiments were performed with specifically developed fluorescent labeled silica colloids in columns of a repacked natural porous medium under hydro-geochemical conditions representative of sandy aquifers. Breakthrough curves and vertical deposition profiles of colloids were measured for various colloid concentrations and sizes. The results showed that for a given colloid concentration injected, deposition increased when increasing the size of the colloids. For a given colloid size, retention was also shown to be highly concentration-dependent with a non-monotonous pattern presenting low and high concentration specificities. Deposition increases when increasing both size and injected concentration, until a threshold concentration is reached, above which retention decreases, thus increasing colloid mobility. Results observed above the threshold concentration agree with a classical blocking mechanism typical of a high concentration regime. Results observed at lower colloid concentrations were not modeled with a classical blocking model and a depth- and time-dependent model with a second order kinetic law was necessary to correctly fit the experimental data in the entire range of colloid concentrations with a single set of parameters for each colloidal size. The colloid deposition mechanisms occuring at low concentrations were investigated through a pore structure analysis carried out with Mercury Intrusion Porosimetry and image analysis. The determined pore size distribution permitted estimation of the maximal retention capacity of the natural sand as well as some low flow zones. Altogether, these results stress the key role of the pore space geometry of the sand in controlling silica colloids deposition under hydro-geochemical conditions typical of sandy aquifers. Our results also showed originally that colloid

  14. Response to Oil Sands Products Assessment (United States)


    Tailings ponds are an operating facility common to all types of surface mining. For oil sands, tailings consisting of water , sand, clay, and residual ...oil, are pumped to these basins—or ponds— where settling occurs and water is recycled for reuse in the process. When the ponds are no longer required...of crude oil transported by tank vessel in Washington waters . In a 2013 Bloomburg Business news article , Dan Murtaugh states, “The dock probably

  15. Investigating salt and naphthenic acids interactions in the toxicity of oil sands process water to freshwater invertebrates

    Energy Technology Data Exchange (ETDEWEB)

    Turcotte, D.; Kautzman, M.; Wojnarowicz, P.; Cutter, J.; Bird, E.; Liber, K. [Saskatchewan Univ., Regina, SK (Canada)


    The hot water extraction process used to produce bitumens from oil sands produces a large volume of oil sands process water (OSPW) that contain elevated concentrations of naphthenic acids (NA) and salts. Many oil sands reclamation projects are proposing the use of OSPW as part of reconstructed wetlands projects. This study investigated the toxicity of OSPW to freshwater invertebrates. The toxic interactions between NA and salinity on freshwater invertebrates were assessed. Bioassays with laboratory-cultured Ceriodaphnia dubia were conducted to determine the toxicity of OSPW from selected water bodies. The study showed that while the concentrations of NAs and salinity were elevated in OSPW waters that caused toxic responses, the concentrations of salinity ions varied greatly among the OSPW samples. Results of the study suggested that ion composition may be a factor in toxicity. Interactions between NAs and salinity were then assessed by performing bioassays with mixtures representing major ion combinations in OSPW.

  16. Lagrangian coherent structures and plasma transport processes

    CERN Document Server

    Falessi, M V; Schep, T J


    A dynamical system framework is used to describe transport processes in plasmas embedded in a magnetic field. For periodic systems with one degree of freedom the Poincar\\'e map provides a splitting of the phase space into regions where particles have different kinds of motion: periodic, quasi-periodic or chaotic. The boundaries of these regions are transport barriers; i.e., a trajectory cannot cross such boundaries during the whole evolution of the system. Lagrangian Coherent Structure (LCS) generalize this method to systems with the most general time dependence, splitting the phase space into regions with different qualitative behaviours. This leads to the definition of finite-time transport barriers, i.e. trajectories cannot cross the barrier for a finite amount of time. This methodology can be used to identify fast recirculating regions in the dynamical system and to characterize the transport between them.

  17. Screening of genotoxicity and mutagenicity in extractable organics from oil sands process-affected water. (United States)

    Zetouni, Nikolas C; Siraki, Arno G; Weinfeld, Michael; Pereira, Alberto Dos Santos; Martin, Jonathan W


    Large volumes of oil sands process-affected water (OSPW) are produced by the oil sands surface mining industry during alkaline hot-water extraction of bitumen. It is well documented that the acid extractable organics (AEOs) in OSPW, a highly complex mixture of acidic and polar neutral substances, are acutely toxic; but few studies have examined the genotoxicity or mutagenicity of this mixture. In the present study, the in vitro SOS Chromotest and the Ames test (TA98 and TA100 strains) were used to evaluate genotoxicity and mutagenicity for whole OSPW AEOs in the presence and absence of biotransformation by rat S9 liver enzymes. Two subfractions were also examined in the same assays: neutral extractable fraction (F1-NE), and the subsequent acid extractable fraction (F2-AE). In the SOS assay, whole AEO was cytotoxic when concentrated 2× (i.e., twice as concentrated as the environmental sample) and showed increasing genotoxic response above 6×. Co-exposure with S9 had a protective effect on the cell SOS-inducing factor and survival but did not eliminate genotoxicity above 6× concentrations. Most of the cytotoxicity was attributable to F2-AE, but both F1-NE and F2-AE had similar genotoxic dose-responses above 6×. In the Ames test without S9, whole AEO was mutagenic in both strains above 10× concentrations. Co-incubation with S9 had little effect on the TA100 strain but with TA98 resulted in bioactivation at midlevel doses (1.5-6.3×) and protection at higher doses (10-25×). The 2 subfractions were mutagenic in both strains but with different dose-responses. Further research in vivo or in more relevant cells is warranted to investigate the carcinogenic risks of OSPW. Environ Toxicol Chem 2016;9999:1-8. © 2016 SETAC.

  18. Field trial on the transport of Pseudomonas putida and Escherichia coli bacteria in the tertiary sand of Neuherberg test field; Gelaendeversuche zum Transport der Bakterien Pseudomonas putida und Escherichia coli im tertiaeren Sand des Versuchsfeldes Neuherberg

    Energy Technology Data Exchange (ETDEWEB)

    Mallen, G.; Engel, M.; Maloszewski, P.; Reichlmayr, E. [GSF - Forschungszentrum fuer Umwelt und Gesundheit GmbH, Neuherberg (Germany). Inst. fuer Hydrologie


    The groundwater in the highly permeable, predominantly pebbly Quaternary structure of the Munich boulder plain is subject to considerable contamination and hazards. In the past this led some municipalities and large consumers (e.g. breweries) to draw groundwater from the underlying tertiary sands and coarse clay of the Upper Lacustrine Molasse. In spite of thick, barely permeable intermediate layers anthropogenic influences are gradually progressing further into the deep, compelling those concerned to draw groundwater from deeper and deeper aquifer layers. Formerly restricted to Quaternary aquifers, studies on the input, transport and fate of various pollutants must therefore now be extended to include Tertiary formations. [German] Das Grundwasser im hochdurchlaessigen, ueberwiegend kiesigen Quartaer der Muenchener Schotterebene ist erheblichen Belastungen und Gefaehrdungen ausgesetzt. Daher erschlossen einige Gemeinden und Grossverbraucher (z.B. Brauereien) in der Vergangenheit das GW aus den darunterliegenden tertiaeren Sanden und Schluffen der Oberen Suesswassermolasse. Trotz maechtiger, sehr geringdurchlaessiger stauender Zwischenschichten schreitet auch hier die anthropogene Beeinflussung von oben nach unten fort und erzwingt gleichzeitig die Erschliessung von GW-Vorkommen aus zunehmend tieferen Aquiferschichten. Bisher meist in quartaeren Aquiferen durchgefuehrte Untersuchungen zum Eintrag, Transport und Verbleib verschiedener Schadstoffe muessen daher auch auf das Tertiaer ausgedehnt werden. (orig.)

  19. A risk-based approach for identifying constituents of concern in oil sands process-affected water from the Athabasca Oil Sands region. (United States)

    McQueen, Andrew D; Kinley, Ciera M; Hendrikse, Maas; Gaspari, Daniel P; Calomeni, Alyssa J; Iwinski, Kyla J; Castle, James W; Haakensen, Monique C; Peru, Kerry M; Headley, John V; Rodgers, John H


    Mining leases in the Athabasca Oil Sands (AOS) region produce large volumes of oil sands process-affected water (OSPW) containing constituents that limit beneficial uses and discharge into receiving systems. The aim of this research is to identify constituents of concern (COCs) in OSPW sourced from an active settling basin with the goal of providing a sound rational for developing mitigation strategies for using constructed treatment wetlands for COCs contained in OSPW. COCs were identified through several lines of evidence: 1) chemical and physical characterization of OSPW and comparisons with numeric water quality guidelines and toxicity endpoints, 2) measuring toxicity of OSPW using a taxonomic range of sentinel organisms (i.e. fish, aquatic invertebrates, and a macrophyte), 3) conducting process-based manipulations (PBMs) of OSPW to alter toxicity and inform treatment processes, and 4) discerning potential treatment pathways to mitigate ecological risks of OSPW based on identification of COCs, toxicological analyses, and PBM results. COCs identified in OSPW included organics (naphthenic acids [NAs], oil and grease [O/G]), metals/metalloids, and suspended solids. In terms of species sensitivities to undiluted OSPW, fish ≥ aquatic invertebrates > macrophytes. Bench-scale manipulations of the organic fractions of OSPW via PBMs (i.e. H2O2+UV254 and granular activated charcoal treatments) eliminated toxicity to Ceriodaphnia dubia (7-8 d), in terms of mortality and reproduction. Results from this study provide critical information to inform mitigation strategies using passive or semi-passive treatment processes (e.g., constructed treatment wetlands) to mitigate ecological risks of OSPW to aquatic organisms. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Conceptual Model for Flow and Transport through Unsaturated Silty Loams and Sands in North Mississippi (United States)

    Coleman, S. H.; Corley, D. S.; van Volkenburg, G. J.; Wildman, J. C.; Holt, R. M.


    We conducted a five-day ponded infiltration test at the University of Mississippi (UM) Soil Moisture Observatory (SMO). The 5 acre SMO is located in a former agricultural field at the UM Field Station, a 740 acre tract of land with restricted access located 11 miles from the UM campus in Oxford, Mississippi. At the infiltration site, the near surface soils consist of about infiltration test, the soil surface was leveled and a 2.0 m diameter infiltration ring was installed. Six neutron access tubes were installed to a depth of 2.5 m around the infiltration ring. A constant ponding depth of 13 cm was maintained throughout the duration of the experiment. Blue dye was added to the water to enable mapping of infiltration paths. During the experiment, moisture content profiles were periodically measured at each neutron access tube. Neutron probe data suggested that infiltration was dominated by capillary forces. However, later mapping of a trench through the infiltration site revealed that infiltration in the upper silt loam was dominated by macropore flow along roots and microfractures in the soil. In the sand, gravity driven fingers formed below the root-zone, where deep roots focused flow.

  1. Transport of microbial tracers in clean and organically contaminated silica sand in laboratory columns compared with their transport in the field

    Energy Technology Data Exchange (ETDEWEB)

    Weaver, Louise, E-mail:; Sinton, Lester W.; Pang, Liping; Dann, Rod; Close, Murray


    Waste disposal on land and the consequent transport of bacterial and viral pathogens in soils and aquifers are of major concern worldwide. Pathogen transport can be enhanced in the presence of organic matter due to occupation of attachment sites in the aquifer materials thus preventing pathogen attachment leading to their faster transport for longer distances. Laboratory column studies were carried out to investigate the effect of organic matter, in the form of dissolved organic carbon (DOC), on the transport of Escherichia coli and MS2 phage in saturated clean silica sand. Transport rates of these microbial tracers were also studied in a contaminated field site. Laboratory column studies showed that low concentrations (0.17 mg L{sup −1}) of DOC had little effect on E. coli J6-2 removal and slightly reduced the attachment of MS2 phage. After progressive conditioning of the column with DOC (1.7 mg L{sup −1} and 17 mg L{sup −1}), neither E. coli J6-2 nor MS2 phage showed any attachment and recovery rates increased dramatically (up to 100%). The results suggest that DOC can affect the transport rates of microbial contaminants. For E. coli J6-2 the predominant effect appeared to be an increase in the secondary energy minimum leading to an increase in E. coli attachment initially. However, after 17 mg L{sup −1} DOC conditioning of the silica sand no attachment of E. coli was observed as the DOC took up attachment sites in the porous media. MS2 phage appeared to be affected predominantly by out-competition of binding sites in the clean silica sand and a steady reduction in attachment was observed as the DOC conditioning increased. Field study showed a high removal of both E. coli and MS2 phage, although E. coli was removed at a lower rate than MS2 phage. In the field it is likely that a combination of effects are seen as the aquifer material will be heterogeneous in its surface nanoscale properties, demonstrated by the differing removal of E. coli and MS2 phage

  2. A 3-Dimensional Simulation of Mixed Sand Transport%三维混合沙输运数值模拟

    Institute of Scientific and Technical Information of China (English)

    肖锋军; 郭烈锦; 王跃社; 李德标


    采用计算流体力学和颗粒离散元耦合的方法模拟了三维混合沙输运过程。采用体平均的Navier—stokes方程来描述气相运动,考虑了气相和颗粒相的相互作用。颗粒运动通过求解牛顿运动方程来求解,采用硬球模型描述颗粒和颗粒及颗粒和壁面的碰撞。本模型中,颗粒运动是三维的而气相运动是二维的。计算结果表明:总输沙率沿高度方向在大于2cm以上按照指数衰减,在2cm以下则偏大;各粒径颗粒具有不同的输沙率分布,粗粒径颗粒按指数规律衰减,其它粒径颗粒输沙率随高度先指数增加后减少;各粒径颗粒平均水平速度随高度对数函数增加且同高度时随粒径增大而减小,1cm高度以下则相反;沙粒平均粒径沿高度线性递减,2cm以下粒径偏大。%A combined computational fluid dynamics and discrete particle method approach was proposed to perform numerical simulation on a mixed sand transport. In this paper the volume averaged Navier-stokes equations were solved to calculate the gas motion, taking into account the interaction between gas and particles; the particle motion was calculated using Newton's equation of motion, where a hard sphere model was used to describe the particle-particle and particle-wall collisions. In this model, the motion of individual particle was three-dimensional and the flow of continuous gas was two-dimensional. The results showed that, the total sand mass flux decreased exponentially with height above 2 cm and deviated below 2 cm. The distributions of mass flux of each size group were very different from each other. For the large size group, the sand mass flux decreased exponentially with height, while the sand mass flux increased with height firstly and then decreased for the other size groups. The particle mean horizontal velocity of all sand groups increased logarithmically with height and decreased with particle size at the same height

  3. The Influence of the Content of Furfuryl Alcohol Monomer on the Process of Moulding Sand's Thermal Destruction

    Directory of Open Access Journals (Sweden)

    Dobosz St. M.


    Full Text Available The article discusses the issue of the influence of furfuryl alcohol content in resin binders on properties of moulding sand at elevated temperature. Reducing the share of this component - due to the requirements of the European Union regarding its toxicity - may cause a decrease in temperature of moulding sands’ destruction and, consequently, the thermal deformation of moulds and the creation of many casting defects. The study examined the impact of the furfuryl alcohol content of the thermal destruction processes and on the strength of the moulding sand at an ambient temperature and the tendency to thermal deformation.

  4. TQM brings collaboration to patient transport process. (United States)

    Houston, K L; Clute, C; Ryan-Crepin, K; Kimball, M; Matthews, R


    Total quality management (TQM) principles can be utilized to achieve successful outcomes of an interdepartmental problem-solving process prior to implementation of a TQM formal structure within an organization. Prior to implementation of the new process, patient transport time from nursing units to lab destination was calculated at 17.6 minutes; postimplementation, an institutional benchmark of 15.4 minutes has been set. The mechanisms utilized for development, implementation, and evaluation of a process improvement team is the focus of the article. The reader will be taken on a journey through an interdepartmental problem-solving process utilizing the TQM principles.

  5. Estimating bedload transport in a large sand-gravel bed river from direct sampling, dune tracking and empirical formulas (United States)

    Claude, Nicolas; Rodrigues, Stéphane; Bustillo, Vincent; Bréhéret, Jean-Gabriel; Macaire, Jean-Jacques; Jugé, Philippe


    Three methods used to estimate river bedload discharges were compared in a large sand-gravel bed river. The unit and total bedload transport rates estimated by sediment sampling, dune tracking method and the equations of Van Rijn and Meyer-Peter and Müller were compared. The analysis was based on a large data set obtained from field surveys that combined sediment sampling, acoustic doppler profiler (ADP) measurements, and multibeam echosoundings of the middle reach of the River Loire (France) for contrasting flow conditions ranging from low flows to 2-year floods. For transport stages between 2 and 6 (i.e. between the annual mean discharge and the discharge for a 2-year flood), the tested equations predicted fairly well the unit and total bedload discharges and roughly estimated the temporal variability of the bedload during floods. For these transport conditions, the best agreement with the sediment sampling measurements was observed with the Van Rijn formula. For lower flow conditions, the tested formulas provide lower estimates than those sampled. To improve the accuracy of the equations for low flows, potential solutions include integrating near-bed turbulences and non uniformity of bed particles into the models. The ability of the formulas to predict the temporal variability of the bedload can be improved by using the bedform roughness to adjust the estimates. The bedload transport rates calculated with dune tracking method are lower than the fluxes sampled because a substantial fraction of the bedload does not participate to the dune migration. Finally, a first rating curve that was implemented for the River Loire estimates the annual bedload discharge for 2010 to be 480,000 t.

  6. Particle size distribution, concentration, and magnetic attraction affect transport of polymer-modified Fe(0) nanoparticles in sand columns. (United States)

    Phenrat, Tanapon; Kim, Hye-Jin; Fagerlund, Fritjof; Illangasekare, Tissa; Tilton, Robert D; Lowry, Gregory V


    The effect of particle concentration, size distribution (polydispersity) and magnetic attractive forces (Fe(0) content) on agglomeration and transport of poly(styrene sulfonate) (PSS) modified NZVI was studied in water-saturated sand (d(p) = 300 microm) columns. Particle concentrations ranged from 0.03 to 6 g/L in 5 mM NaCl/5 mM NaHCO3 at a pore water velocity of 3.2 x 10(-4) m/s. Three NZVI dispersions with different intrinsic particle size distributions obtained from sequential sedimentation are compared. The influence of magnetic attraction (Fe(0) content) on NZVI agglomeration and deposition in porous media is assessed by comparing the deposition behavior of PSS-modified NZVI (magnetic) having different Fe(0) contents with PSS-modified hematite (nonmagnetic) with the same surface modifier. At low particle concentration (30 mg/L) all particles were mobile in sand columns regardless of size or magnetic attractive forces. At high concentration (1 to 6 g/L), deposition of the relatively monodisperse dispersion containing PSS-modified NZVI (hydrodynamic radius (R(H)) = 24 nm) with the lowest Fe(0) content (4 wt%) is low (attachment efficiency (alpha) = 2.5 x 10(-3)), insensitive to particle concentration, and similar to PSS-modified hematite. At 1 to 6 g/L, the attachment efficiency of polydisperse dispersions containing both primary particles and sintered aggregates (R(H) from 15 to 260 nm) of PSS-modified NZVI with a range of Fe(0) content (10-60%) is greater (alpha = 1.2 x 10(-2) to 7.2 x 10(-2) and is sensitive to particle size distribution. The greater attachment for larger, more polydisperse Fe(0) nanoparticles with higher Fe(0) content is a result of their agglomeration during transport in porous media because the magnetic attractive force between particles increases with the sixth power of particle/agglomerate radius. A filtration model that considers agglomeration in porous media and subsequent deposition explains the observed transport of polydisperse PSS

  7. Gravity-Dependent Transport in Industrial Processes (United States)

    Ostrach, Simon; Kamotani, Yasuhiro


    Gravity dependent transport phenomena in various industrial processes are investigated in order to indicate new directions for micro-gravity research that enhance the commercial success of the space program. The present article describes the commercialization possibilities of such topics associated with physicochemical transport phenomena. The topics are: coating flow, rotating electrochemical system, and convection in low Plandtl number fluids. The present study is directed to understand these phenomena, and to develop a knowledge base for their applications with emphasis to a micro-gravity environment.

  8. The processing of weathered fly ash in sand-lime bricks. Verwerking van verweerde vliegas in kalkzandsteen

    Energy Technology Data Exchange (ETDEWEB)

    Bloem, P.J.C.; Sciarone, B.J.G. (KEMA Milieu Technologie, Arnhem (Netherlands))


    After hardening of sand-lime bricks samples, in which eight-year-weathered fly ash and normal fly ash were processed, the pressure strength, the porosity and the water absorption coefficient have been determined. The processing of both types of fly ash leads to equally good results. The application of the eight year old basic fly ash (not weathered) can only be processed satisfactorily when sieved and grinded

  9. Transport and removal of viruses in saturated sand columns under oxic and anoxic conditions--Potential implications for groundwater protection. (United States)

    Frohnert, Anne; Apelt, Susann; Klitzke, Sondra; Chorus, Ingrid; Szewzyk, Regine; Selinka, Hans-Christoph


    To protect groundwater as a drinking water resource from microbiological contamination, protection zones are installed. While travelling through these zones, concentrations of potential pathogens should decline to levels that pose no risks to human health. Removal of viruses during subsurface passage is influenced by physicochemical conditions, such as oxygen concentration, which also affects virus survival. The aim of our study was to evaluate the effect of redox conditions on the removal of viruses during sand filtration. Experiments in glass columns filled with medium-grained sand were conducted to investigate virus removal in the presence and absence of dissolved oxygen. Bacteriophages MS2 and PhiX174, as surrogates for human enteric viruses were spiked in pulsed or in continuous mode and pumped through the columns at a filter velocity of about 1m/d. Virus breakthrough curves were analyzed by calculating total viral elimination and fitted using one-dimensional transport models (CXTFIT and HYDRUS-1D). While short-term experiments with pulsed virus application showed only small differences with regard to virus removal under oxic and anoxic conditions, a long-term experiment with continuous dosing revealed a clearly lower elimination of viruses under anoxic conditions. These findings suggest that less inactivation and less adsorption of viruses in anoxic environments affect their removal. Therefore, in risk assessment studies aimed to secure drinking water resources from viral contamination and optimization of protection zones, the oxic and anoxic conditions in the subsurface should also be considered. Copyright © 2014 Elsevier GmbH. All rights reserved.

  10. Stochastic transport processes in discrete biological systems

    CERN Document Server

    Frehland, Eckart


    These notes are in part based on a course for advanced students in the applications of stochastic processes held in 1978 at the University of Konstanz. These notes contain the results of re­ cent studies on the stochastic description of ion transport through biological membranes. In particular, they serve as an introduction to an unified theory of fluctuations in complex biological transport systems. We emphasize that the subject of this volume is not to introduce the mathematics of stochastic processes but to present a field of theoretical biophysics in which stochastic methods are important. In the last years the study of membrane noise has become an important method in biophysics. Valuable information on the ion transport mechanisms in membranes can be obtained from noise analysis. A number of different processes such as the opening and closing of ion channels have been shown to be sources of the measured current or voltage fluctuations. Bio­ logical 'transport systems can be complex. For example, the tr...

  11. Reactive transport of gentisic acid in a hematite-coated sand column: Experimental study and modeling (United States)

    Hanna, K.; Rusch, B.; Lassabatere, L.; Hofmann, A.; Humbert, B.


    The adsorption of gentisic acid (GA) by hematite nano-particles was examined under static and dynamic conditions by conducting batch and column tests. To simulate natural sediments, the iron oxide was deposited on 10 μm quartz particles. The GA adsorption was described by a surface complexation model fitted to pH-adsorption curves with GA concentrations of 0.1-1 mM in a pH range of 3-10. The surface was described with one type of site ( tbnd FeOH°), while gentisic acid at the surface was described by two surface complexes ( tbnd FeLH 2°, log Kint = 8.9 and tbnd FeLH -, log Kint = -8.2). Modeling was conducted with PHREEQC-2 using the MINTEQ database. From a kinetic point of view, the intrinsic chemical reactions were likely to be the rate-limiting step of sorption (˜10 -3 s -1) while external and internal mass transfer rates (˜10 2 s -1) were much faster. Under flow through conditions (column), adsorption of GA to hematite-coated sand was about 7-times lower than under turbulent mixing (batch). This difference could not be explained by chemical adsorption kinetics as shown by test calculations run with HYDRUS-1D software. Surface complexation model simulations however successfully described the data when the surface area was adjusted, suggesting that under flow conditions the accessibility to the reactive surface sites was reduced. The exact mechanism responsible for the increased mobility of GA could not be determined but some parameters suggested that decreased external mass transfer between solution and surface may play a significant role under flow through conditions.

  12. Two-site kinetic modeling of bacteriophages transport through columns of saturated dune sand. (United States)

    Schijven, Jack F; Hassanizadeh, S Majid; de Bruin, Ria H A M


    Breakthrough curves, on a semi-log scale, from tests in porous media with block-input of viruses, bacteria, protozoa and colloidal particles often exhibit a typical skewness: a rather slowly rising limb and a smooth transition of a declining limb to a very long tail. One-site kinetic models fail to fit the rising and declining limbs together with the tail satisfactorily. Inclusion of an equilibrium adsorption site does not seem to improve simulation results. This was encountered in the simulation of breakthrough curves from a recent field study on the removal of bacteriophages MS2 and PRD1 by passage through dune sand. In the present study, results of laboratory experiments for the study of this issue are presented. Breakthrough curves of salt and bacteriophages MS2, PRDI, and phiX174 in 1 D column experiments have been measured. One- and two-site kinetic models have been applied to fit and predict breakthrough curves from column experiments. The two-site model fitted all breakthrough curves very satisfactorily, accounting for the skewness of the rising limb as well as for the smooth transition of the declining limb to the tail of the breakthrough curve. The one-site model does not follow the curvature of the breakthrough tail, leading to an overestimation of the inactivation rate coefficient for attached viruses. Interaction with kinetic site 1 is characterized by relatively fast attachment and slow detachment, whereas attachment to and detachment from kinetic site 2 is fast. Inactivation of viruses and interaction with kinetic site 2 provide only a minor contribution to removal. Virus removal is mainly determined by the attachment to site 1. Bacteriophage phiX174 attached more than MS2 and PRD1, which can be explained by the greater electrostatic repulsion that MS2 and PRD1 experience compared to the less negatively charged phiX174.

  13. ET-DSP{sup TM} : an environmentally friendly process for the oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Heath, G. [E-T Energy Ltd., Calgary, AB (Canada)


    Although the Electro-Thermal Dynamic Stripping Process (ET-DSP{sup TM}) was initially developed to remediate contaminated soils, it has evolved into an environmentally sound method for recovering bitumen from the Athabasca oil sands. This progression was in response to environmental concerns and the need for an economical alternative to mining and other energy-intensive, in-situ resource recovery methods. The key metrics needed to design a commercially viable pilot project were identified and quantified using a proof-of-concept test and an expanded field test. Geological modeling of 8 sections of land confirmed that sufficient resources are available to justify a commercial development. The economic viability of proceeding with the commercial production of 1,590 m{sup 3} of bitumen per day was verified with financial modeling of the ET-DSP process. The model envisaged the drilling of approximately 1,000 wells per year for the next 20 years. The model emphasized that the integrated development plan must incorporate the lessons learned from the preceding test phases coupled with further innovations in both drilling and production techniques. The plan must also continue to lower energy intensity, reduce water use, reduce greenhouse gas emissions and ensure reclamation of surface disturbances.

  14. Prediction of Shrinkage Porosity Defect in Sand Casting Process of LM25 (United States)

    Rathod, Hardik; Dhulia, Jay K.; Maniar, Nirav P.


    In the present worldwide and aggressive environment, foundry commercial enterprises need to perform productively with least number of rejections and create casting parts in shortest lead time. It has become extremely difficult for foundry industries to meet demands of defects free casting and meet strict delivery schedules. The process of casting solidification is complex in nature. Prediction of shrinkage defect in metal casting is one of the critical concern in foundries and is one of the potential research areas in casting. Due to increasing pressure to improve quality and to reduce cost, it is very essential to upgrade the level of current methodology used in foundries. In the present research work, prediction methodology of shrinkage porosity defect in sand casting process of LM25 using experimentation and ANSYS is proposed. The objectives successfully achieved are prediction of shrinkage porosity distribution in Al-Si casting and determining effectiveness of investigated function for predicting shrinkage porosity by correlating results of simulating studies to those obtained experimentally. The real-time application of the research reflects from the fact that experimentation is performed on 9 different Y junctions at foundry industry and practical data obtained from experimentation are used for simulation.

  15. Pseudomonads biodegradation of aromatic compounds in oil sands process-affected water. (United States)

    Zhang, Yanyan; McPhedran, Kerry N; Gamal El-Din, Mohamed


    Aromatic naphthenic acids (NAs) have been shown to be more toxic than the classical NAs found in oil sands process-affected water (OSPW). To reduce this toxicity, Pseudomonas fluorescens and Pseudomonas putida were used to determine their ability to biodegrade aromatic compounds including treatments considering the impacts of external carbon and iron addition. Results showed that with added carbon P. fluorescens and P. putida have the capability of biodegrading these aromatics. In the presence of external carbon, gene expression of a functional PAH-ring hydroxylating dioxygenase (PAH-RHDα) was determined through reverse transcription real-time PCR, suggesting active degradation of OSPW aromatic compounds. Although no significant classical NAs removal was observed during this process, toxicity was reduced by 49.3% under optimal conditions. OSPW toxicity was eliminated with the combination of ozonation at a dose of 80 mg/L followed by biodegradation, indicating that it is a promising combined OSPW treatment approach for the safe discharge to the aquatic environment.

  16. Transient transport processes in deformable porous media

    Institute of Scientific and Technical Information of China (English)

    Cs. Mészáros; (A). Bálint


    The basic partial differential equations relevant for convection-diffusion and convection-diffusion-wave phenomena are presented and solved analytically by using the MAPLE symbolic computer algebra system.The possible general nonlinear character of the constitutive equation of the convection-discussion process is replaced by a direct posteriori stochastic refinement of its solution represented for Dirichlet-type boundary conditions.A thermodynamic analysis is performed for connecting the relaxation time constants and Jacobi-determinants of deformations at transient transport processes.Finally,a new procedure for general description of coupled transport processes on the basis of the formalism originally developed for convection-free phenomena is presented by matrix analysis methods in the Fourier space.

  17. Comment on "Generalized exclusion processes: Transport coefficients" (United States)

    Becker, T.; Nelissen, K.; Cleuren, B.; Partoens, B.; Van den Broeck, C.


    In a recent paper, Arita et al. [Phys. Rev. E 90, 052108 (2014), 10.1103/PhysRevE.90.052108] consider the transport properties of a class of generalized exclusion processes. Analytical expressions for the transport-diffusion coefficient are derived by ignoring correlations. It is claimed that these expressions become exact in the hydrodynamic limit. In this Comment, we point out that (i) the influence of correlations upon the diffusion does not vanish in the hydrodynamic limit, and (ii) the expressions for the self- and transport diffusion derived by Arita et al. are special cases of results derived in Becker et al. [Phys. Rev. Lett. 111, 110601 (2013), 10.1103/PhysRevLett.111.110601].

  18. Sediment transport processes in the Pearl River Estuary as revealed by grain-size end-member modeling and sediment trend analysis (United States)

    Li, Tao; Li, Tuan-Jie


    The analysis of grain-size distribution enables us to decipher sediment transport processes and understand the causal relations between dynamic processes and grain-size distributions. In the present study, grain sizes were measured from surface sediments collected in the Pearl River Estuary and its adjacent coastal areas. End-member modeling analysis attempts to unmix the grain sizes into geologically meaningful populations. Six grain-size end-members were identified. Their dominant modes are 0 Φ, 1.5 Φ, 2.75 Φ, 4.5 Φ, 7 Φ, and 8 Φ, corresponding to coarse sand, medium sand, fine sand, very coarse silt, silt, and clay, respectively. The spatial distributions of the six end-members are influenced by sediment transport and depositional processes. The two coarsest end-members (coarse sand and medium sand) may reflect relict sediments deposited during the last glacial period. The fine sand end-member would be difficult to transport under fair weather conditions, and likely indicates storm deposits. The three remaining fine-grained end-members (very coarse silt, silt, and clay) are recognized as suspended particles transported by saltwater intrusion via the flood tidal current, the Guangdong Coastal Current, and riverine outflow. The grain-size trend analysis shows distinct transport patterns for the three fine-grained end-members. The landward transport of the very coarse silt end-member occurs in the eastern part of the estuary, the seaward transport of the silt end-member occurs in the western part, and the east-west transport of the clay end-member occurs in the coastal areas. The results show that grain-size end-member modeling analysis in combination with sediment trend analysis help to better understand sediment transport patterns and the associated transport mechanisms.

  19. Determination of the solid consumption in the transport of sands in sea beds with gold 198; Determinacion del gasto solido en el transporte de arenas en lechos marinos con oro 198

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez A, G


    The study of the movement of sediments in sea beds, is necessary when one plans to build a port. Among the techniques used for this studies, it is the radiotracer balance that gives an useful estimation of the quantity of sediment that it moves per day and by meter (perpendicular to the displacement). The main objectives of this work are: to) to present the characteristics of the obtaining of the used radiotracer, describing details those used safety measures, b) to describe the handling of the radiotracer and it radiological safety, during the transport and injection in the sea bottom, c) description of the detection way and the used equipment, d) to describe the information processing obtained in the field and finally, e) the estimate of the solid consumption and the determination of the direction and speed of displacement of those sediments in the sea bottom, in front of the Tabasco coast, to be used jointly with the information obtained by means of other techniques so that one can make a good planning of the operations of dredging during the construction and later on the maintenance of the Dos Bocas marine terminal. The first step is to obtain the radiotracer that in this case was sand of uniform grain metric, marked superficially with Gold-198. The second step is to transport the sand to the place of interest, to place it in the injection equipment and to deposit it in the sea bottom. The third step is to detect the radiotracer in the sea bed, from a craft that drags a sled, which takes mounted a scintillation detector of sodium iodide activated with thallium NaI(Tl) (probe). The fourth step is to process the field information and to obtain the corresponding results. (Author)

  20. Dissolved organic compounds in reused process water for steam-assisted gravity drainage oil sands extraction. (United States)

    Kawaguchi, Hideo; Li, Zhengguo; Masuda, Yoshihiro; Sato, Kozo; Nakagawa, Hiroyuki


    The in situ oil sands production method called steam-assisted gravity drainage (SAGD) reuses process wastewater following treatment. However, the treatment and reuse processes concentrate contaminants in the process water. To determine the concentration and dynamics of inorganic and organic contaminants, makeup water and process water from six process steps were sampled at a facility employing the SAGD process in Alberta, Canada. In the groundwater used for the makeup water, the total dissolved organic carbon (DOC) content was 4 mg/L. This significantly increased to 508 mg/L in the produced water, followed by a gradual increase with successive steps in subsequent water treatments. The concentrations and dynamics of DOC constituents in the process water determined by gas chromatography-mass spectrometry showed that in the produced water, volatile organic compounds (VOCs) such as acetone (33.1 mg/L) and 2-butanone (13.4 mg/L) predominated, and there were significant amounts of phenolic compounds (total 9.8 mg/L) and organic acids including naphthenic acids (NAs) corresponding to the formula C(n)H(2n+Z)O(X) for combinations of n = 4 to 18, Z = 0 and -2, and X = 2 to 4 (53 mg/L) with trace amounts of polycyclic aromatic hydrocarbons (PAHs) such as naphthalene and phenanthrene. No organic contaminants, except for saturated fatty acids, were detected in the groundwater. The concentration of DOC in the recycled water was 4.4-fold higher than that in the produced water. Likewise, the total concentrations of phenols and organic acids in the recycled water were 1.7- and 4.5-fold higher than in the produced water, whereas the total concentrations of VOCs and PAHs in the recycled water were reduced by over 80%, suggesting that phenols and organic acids are selectively concentrated in the process water treatment. This comprehensive chemical analysis thus identified organic constituents that were concentrated in the process water and which interfere with subsequent

  1. Transport process and block diagram of Cd in Jiaozhou Bay (United States)

    Yang, Dongfang; Wei, Linzhen; Feng, Ming; Chen, Mei; Miao, Zhenqing


    Many marine bays have been polluted by various pollutants due to the rapid development of economic and population. Understanding the transport processes of pollutants in marine bays is essential to pollution control. This paper analyzed the transport processes of Cd in Jiaozhou Bay based on investigation data during 1979-1983. Results showed that the major transport processes of Cd included terrestrial transport process, atmospheric transport process and oceanic transport process, respectively. Furthermore, this paper provided the block diagrams for these transport processes, which were determining the migrating paths and traces of Cd.

  2. Integration of High Temperature Gas-cooled Reactor Technology with Oil Sands Processes

    Energy Technology Data Exchange (ETDEWEB)

    L.E. Demick


    This paper summarizes an evaluation of siting an HTGR plant in a remote area supplying steam, electricity and high temperature gas for recovery and upgrading of unconventional crude oil from oil sands. The area selected for this evaluation is the Alberta Canada oil sands. This is a very fertile and active area for bitumen recovery and upgrading with significant quantities piped to refineries in Canada and the U.S Additionally data on the energy consumption and other factors that are required to complete the evaluation of HTGR application is readily available in the public domain. There is also interest by the Alberta oil sands producers (OSP) in identifying alternative energy sources for their operations. It should be noted, however, that the results of this evaluation could be applied to any similar oil sands area.

  3. Sulfate reducing bacteria and their activities in oil sands process-affected water biofilm. (United States)

    Liu, Hong; Yu, Tong; Liu, Yang


    Biofilm reactors were constructed to grow stratified multispecies biofilm in oil sands process-affected water (OSPW) supplemented with growth medium. The development of sulfate reducing bacteria (SRB) within the biofilm and the biofilm treatment of OSPW were evaluated. The community structure and potential activity of SRB in the biofilm were investigated with H2S microsensor measurements, dsrB gene-based denaturing gradient gel electrophoresis (DGGE), and the real time quantitative polymerase chain reaction (qPCR). Multispecies biofilm with a thickness of 1000 μm was successfully developed on engineered biocarriers. H2S production was observed in the deeper anoxic zone of the biofilm from around 750 μm to 1000 μm below the bulk water-biofilm interface, revealing sulfate reduction in the deeper zone of the stratified biofilm. The biofilm removed chemical oxygen demand (COD), sulfate, and nitrogen. The study expands current knowledge of biofilm treatment of OSPW and the function of anaerobic SRB in OSPW biofilm, and thus provides information for future bioreactor development in the reclamation of OSPW.

  4. Effect of modifying process on mechanical properties of EN AC-43300 silumin cast into sand moulds

    Directory of Open Access Journals (Sweden)

    J. Pezda


    Full Text Available Significance of alloy modification in course of casting process is the most explicitly visible on example of Al-Si alloys. Broad application of these alloys in foundry industry has become possible after invention of a method which changes solidification form of Al-Si eutectic mixture. Such primarily thick, acicular shape of silicon crystals becomes changed into fine and compact structure due to introduction of a small quantity of modifier to liquid alloy. The paper presents an attempt of assessment of melting and modification with strontium effects on mechanical properties of EN AC-43300 alloy cast into sand moulds. Obtained results concern selection of optimal quantity of strontium additive in aspect of obtained mechanical properties (Rm, A5, KCV, HB. Effect of strontium additive on change of mechanical properties of the investigated alloy was presented in graphical form. Further investigations shall be connected with determination of an effect of strontium additive on mechanical properties of the alloy after solution heat treatment and ageing treatment.

  5. Intelligent Machine Vision Based Modeling and Positioning System in Sand Casting Process

    Directory of Open Access Journals (Sweden)

    Shahid Ikramullah Butt


    Full Text Available Advanced vision solutions enable manufacturers in the technology sector to reconcile both competitive and regulatory concerns and address the need for immaculate fault detection and quality assurance. The modern manufacturing has completely shifted from the manual inspections to the machine assisted vision inspection methodology. Furthermore, the research outcomes in industrial automation have revolutionized the whole product development strategy. The purpose of this research paper is to introduce a new scheme of automation in the sand casting process by means of machine vision based technology for mold positioning. Automation has been achieved by developing a novel system in which casting molds of different sizes, having different pouring cup location and radius, position themselves in front of the induction furnace such that the center of pouring cup comes directly beneath the pouring point of furnace. The coordinates of the center of pouring cup are found by using computer vision algorithms. The output is then transferred to a microcontroller which controls the alignment mechanism on which the mold is placed at the optimum location.

  6. Ozonation of oil sands process-affected water accelerates microbial bioremediation. (United States)

    Martin, Jonathan W; Barri, Thaer; Han, Xiumei; Fedorak, Phillip M; El-Din, Mohamed Gamal; Perez, Leonidas; Scott, Angela C; Jiang, Jason Tiange


    Ozonation can degrade toxic naphthenic acids (NAs) in oil sands process-affected water (OSPW), but even after extensive treatment a residual NA fraction remains. Here we hypothesized that mild ozonation would selectively oxidize the most biopersistent NA fraction, thereby accelerating subsequent NA biodegradation and toxicity removal by indigenous microbes. OSPW was ozonated to achieve approximately 50% and 75% NA degradation, and the major ozonation byproducts included oxidized NAs (i.e., hydroxy- or keto-NAs). However, oxidized NAs are already present in untreated OSPW and were shown to be formed during the microbial biodegradation of NAs. Ozonation alone did not affect OSPW toxicity, based on Microtox; however, there was a significant acceleration of toxicity removal in ozonated OSPW following inoculation with native microbes. Furthermore, all residual NAs biodegraded significantly faster in ozonated OSPW. The opposite trend was found for ozonated commercial NAs, which are known to contain no significant biopersistent fraction. Thus, we suggest that ozonation preferentially degraded the most biopersistent OSPW NA fraction, and that ozonation is complementary to the biodegradation capacity of microbial populations in OSPW. The toxicity of ozonated OSPW to higher organisms needs to be assessed, but there is promise that this technique could be applied to accelerate the bioremediation of large volumes of OSPW in Northern Alberta, Canada.


    Institute of Scientific and Technical Information of China (English)


    This paper presents an alternate method to re-move the sand carried by natural gas in the upstream pipelinestherefore preventing sand abrasive erosion in pipelines used intransporting high-speed natural gas. Conventionally, most ex-perts pay much attention to improving the anti-erosion charac-teristics of the pipeline materials to solve the problem of seri-ous abrasive erosion, but without significant success. Basedon the theory of multiphase flow and analysis of the character-istics of sandy jets, a new equipment named "Sand Catcher" isintroduced in this article. Experimental results show that theSand Catcher effectively removes most of the sand in the natu-ral gas and significantly reduces the abrasive erosion of thepipelines. The Sand Catcher can be widely applied in practicein the near future.



    Dimitrov, D.; Wijk, W.; Beer, N.


    ENGLISH ABSTRACT: This paper discusses the results obtained from studies on different Rapid Tooling process chains in order to improve the design and manufacture of foundry equipment that is used for sand casting of prototypes in final material. These prototypes are intended for functional and pre-production tests of vehicles. The Three Dimensional Printing process is used as core technology. Subsequently, while considering aspects such as time, cost, quality (accuracy and surface ro...

  9. Modelling the interaction of aeolian and fluvial processes with a combined cellular model of sand dunes and river systems (United States)

    Liu, Baoli; Coulthard, Tom J.


    Aeolian and fluvial processes are important agents for shaping the surface of the Earth, but are largely studied in isolation despite there being many locations where both processes are acting together and influencing each other. Using field data to investigate fluvial-aeolian interactions is, however, hampered by our short length of record and low temporal resolution of observations. Here we use numerical modelling to investigate, for the first time, the interplay between aeolian (sand dunes) and fluvial (river channel) processes. This modelling is carried out by combining two existing cellular models of aeolian and fluvial processes that requires considerable consideration of the different process representation and time stepping used. The result is a fully coupled (in time and space) sand dune - river model. Over a thousand-year simulation the model shows how the migration of sand dunes is readily blocked by rivers, yet aeolian processes can push the channel downwind. Over time cyclic channel avulsions develop indicating that aeolian action on fluvial systems may play an important part in governing avulsion frequency, and thus alluvial architecture.

  10. Coupled transport processes in semipermeable media

    Energy Technology Data Exchange (ETDEWEB)

    Carnahan, C.L.; Jacobsen, J.S.


    The thermodynamics of irreversible processes (TTIP) is used to derive governing equations and phenomenological equations for transport processes and chemical reactions in water-saturated semipermeable media. TTIP is based on three fundamental postulates. The first postulate, the assumption of local equilibrium, allows the formulation of balance equations for entropy. These equations are the bases for the derivation of governing equations for the thermodynamic variables, temperature, pressure, and composition. The governing equations involve vector fluxes of heat and mass and scalar rates of chemical reactions; in accordance with the second postulate of TTIP, these fluxes and rates are related, respectively, to all scalar driving forces (gradients of thermodynamic variables) acting within the system. The third postulate of TTIP states equality (the Onsager reciprocal relations) between certain of the phenomenological coefficients relating forces and fluxes. The description by TTIP of a system undergoing irreversible processes allows consideration of coupled transport processes such as thermal osmosis, chemical osmosis, and ultrafiltration. The coupled processes can make significant contributions to flows of mass and energy in slightly permeable, permselective geological materials such as clays and shales.

  11. Numerical modeling of wind-blown sand on Mars. (United States)

    Huang, HaoJie; Bo, TianLi; Zheng, XiaoJing


    Recent observation results show that sand ripples and dunes are movable like those on Earth under current Martian climate. And the aeolian process on Mars therefore is re-attracting the eyes of scientific researchers in different fields. In this paper, the spatial and temporal evolution of wind-blown sand on Mars is simulated by the large-eddy simulation method. The simulations are conducted under the conditions of both friction wind speed higher and lower than the "fluid threshold", respectively. The fluid entrainment of the sand particles, the processes among saltation sand particles and sand bed, and the negative feedback of sand movement to flow field are considered. Our results show that the "overshoot" phenomenon also exists in the evolution of wind-blown sand on Mars both temporally and spatially; impact entrainment affects the sand transport rate on Mars when the wind speed is smaller or larger than the fluid threshold; and both the average saltation length and height are one order of magnitudes larger than those on Earth. Eventually, the formulas describing the sand transport rate, average saltation length and height on Mars are given, respectively.

  12. Fluvial Transport Model from Spatial Distribution Analysis of Libyan Desert Glass Mass on the Great Sand Sea (Southwest Egypt: Clues to Primary Glass Distribution

    Directory of Open Access Journals (Sweden)

    Nancy Jimenez-Martinez


    Full Text Available Libyan Desert Glass (LDG is a natural silica-rich melted rock found as pieces scattered over the sand and bedrock of the Western Desert of Egypt, northeast of the Gilf Kebir. In this work, a population mixture analysis serves to relate the present spatial distribution of LDG mass density with the Late Oligocene–Early Miocene fluvial dynamics in the Western Desert of Egypt. This was verified from a spatial distribution model that was predicted from the log-normal kriging method using the LDG–mass-dependent transformed variable, Y(x. Both low- and high-density normal populations (–9.2 < Y(x < –3.5 and –3.8 < Y(x < 2.1, respectively were identified. The low-density population was the result of an ordinary fluvial LDG transport/deposition sequence that was active from the time of the melting process, and which lasted until the end of activity of the Gilf River. The surface distribution of the high-density population allowed us to restrict the source area of the melting process. We demonstrate the importance of this geostatistical study in unveiling the probable location of the point where the melting of surficial material occurred and the role of the Gilf River in the configuration of the observed strewn field.

  13. Modified biopolymers as sorbents for the removal of naphthenic acids from oil sands process affected water (OSPW). (United States)

    Arshad, Muhammad; Khosa, M A; Siddique, Tariq; Ullah, Aman


    Oil sands operations consume large volumes of water in bitumen extraction process and produce tailings that express pore water to the surface of tailings ponds known as oil sands process-affected water (OSPW). The OSPW is toxic and cannot be released into the environment without treatment. In addition to metals, dissolved solids, dissolved gases, hydrocarbons and polyaromatic compounds etc., OSPW also contains a complex mixture of dissolved organic acids, referred to as naphthenic acids (NAs). The NAs are highly toxic and react with metals to develop highly corrosive functionalities which cause corrosion in the oil sands processing and refining processes. We have chemically modified keratin biopolymer using polyhedral oligomeric silsesquioxanes (POSS) nanocages and goethite dopant to unfold keratinous structure for improving functionality. The untreated neat keratin and two modified sorbents were characterized to investigate structural, morphological, dimensional and thermal properties. These sorbents were then tested for the removal of NAs from OSPW. The NAs were selectively extracted and quantified before and after sorption process. The biosorption capacity (Q), rejection percentage (R%) and isotherm models were studied to investigate NAs removal efficiency of POSS modified keratin biopolymer (PMKB) and goethite modified keratin biopolymer (GMKB) from aliquots of OSPW.


    Directory of Open Access Journals (Sweden)

    N. A. Filippova


    Full Text Available Background: is to improve information support for the organization and functioning of multimodal systems delive-ry modes of transport in the northern regions of the Russian Federation on the basis of the development of theoretical and methodological and practical provisions, criteria, methods and mathematical models.Method or methodology of the work: a methodology placement vehicle logistics center (TLC in the Nordic region, providing links all transport modes involved in the delivery of energy, developed a model to optimize the parameters of the transport network, used for traffic, the most effective schemes of delivery of goods in multimodal report, taking into account the specifics of the Nordic region, and funding.Results: Studies have applied and may be used by the fe-deral and regional authorities and management in the deve-lopment of integrated programs for energy-Northern regions. Proposed in the theoretical research and methodological approaches are one way to increase the efficiency of the delivery of goods in the event of a little predictable situations on the route, TLC and transhipment points. The developed techniques are used and can be used to improve the northern region of the process control of cargo delivery.Conclusion: Therefore, based on the analysis of the status of the issue, it is quite obvious that the very topical area of optimization of the transport needs of the region to ensure the development and implementation of methods to improve the efficiency and quality of freight traffic by improving organizational structures and technology traffic control all transport space in the region.

  15. Sands at Gusev Crater, Mars (United States)

    Cabrol, Nathalie A.; Herkenhoff, Kenneth E.; Knoll, Andrew H.; Farmer, Jack D.; Arvidson, Raymond E.; Grin, E.A.; Li, Ron; Fenton, Lori; Cohen, B.; Bell, J.F.; Yingst, R. Aileen


    Processes, environments, and the energy associated with the transport and deposition of sand at Gusev Crater are characterized at the microscopic scale through the comparison of statistical moments for particle size and shape distributions. Bivariate and factor analyses define distinct textural groups at 51 sites along the traverse completed by the Spirit rover as it crossed the plains and went into the Columbia Hills. Fine-to-medium sand is ubiquitous in ripples and wind drifts. Most distributions show excess fine material, consistent with a predominance of wind erosion over the last 3.8 billion years. Negative skewness at West Valley is explained by the removal of fine sand during active erosion, or alternatively, by excess accumulation of coarse sand from a local source. The coarse to very coarse sand particles of ripple armors in the basaltic plains have a unique combination of size and shape. Their distribution display significant changes in their statistical moments within the ~400 m that separate the Columbia Memorial Station from Bonneville Crater. Results are consistent with aeolian and/or impact deposition, while the elongated and rounded shape of the grains forming the ripples, as well as their direction of origin, could point to Ma'adim Vallis as a possible source. For smaller particles on the traverse, our findings confirm that aeolian processes have dominated over impact and other processes to produce sands with the observed size and shape patterns across a spectrum of geologic (e.g., ripples and plains soils) and aerographic settings (e.g., wind shadows).

  16. Elemental and spectroscopic characterization of fractions of an acidic extract of oil sands process water. (United States)

    Jones, D; Scarlett, A G; West, C E; Frank, R A; Gieleciak, R; Hager, D; Pureveen, J; Tegelaar, E; Rowland, S J


    'Naphthenic acids' (NAs) in petroleum produced water and oil sands process water (OSPW), have been implicated in toxicological effects. However, many are not well characterized. A method for fractionation of NAs of an OSPW was used herein and a multi-method characterization of the fractions conducted. The unfractionated OSPW acidic extract was characterized by elemental analysis, electrospray ionization-Orbitrap-mass spectrometry (ESI-MS), and an esterified extract by Fourier Transform infrared (FTIR) and ultraviolet-visible (UV) absorption spectroscopy and by comprehensive multidimensional gas chromatography-MS (GCxGC-MS). Methyl esters were fractionated by argentation solid phase extraction (Ag(+) SPE) and fractions eluting with: hexane; diethyl ether: hexane and diethyl ether, examined. Each was weighed, examined by elemental analysis, FTIR, UV, GC-MS and GCxGC-MS (both nominal and high resolution MS). The ether fraction, containing sulfur, was also examined by GCxGC-sulfur chemiluminescence detection (GCxGC-SCD). The major ions detected by ESI-MS in the OSPW extract were assigned to alicyclic and aromatic 'O2' acids; sulfur was also present. Components recovered by Ag(+) SPE were also methyl esters of alicyclic and aromatic acids; these contained little sulfur or nitrogen. FTIR spectra showed that hydroxy acids and sulfoxides were absent or minor. UV spectra, along with the C/H ratio, further confirmed the aromaticity of the hexane:ether eluate. The more minor ether eluate contained further aromatics and 1.5% sulfur. FTIR spectra indicated free carboxylic acids, in addition to esters. Four major sulfur compounds were detected by GCxGC-SCD. GCxGC-high resolution MS indicated these were methyl esters of C18 S-containing, diaromatics with ≥C3 carboxylic acid side chains. Copyright © 2013 Crown Copyright and Elsevier Ltd. Published by Elsevier Ltd.. All rights reserved.

  17. In situ heat treatment of a tar sands formation after drive process treatment (United States)

    Vinegar, Harold J.; Stanecki, John


    A method for treating a tar sands formation includes providing a drive fluid to a hydrocarbon containing layer of the tar sands formation to mobilize at least some hydrocarbons in the layer. At least some first hydrocarbons from the layer are produced. Heat is provided to the layer from one or more heaters located in the formation. At least some second hydrocarbons are produced from the layer of the formation. The second hydrocarbons include at least some hydrocarbons that are upgraded compared to the first hydrocarbons produced by using the drive fluid.

  18. Transport of bacteriophage PRD1 through saturated clean sand columns as a function of pH and ionic strength (United States)

    Sadeghi, G.; Schijven, J. F.; Hassanizadeh, S. M.; Behrends, T.; Gerritse, J.


    Groundwater is a major source for drinking water, because of its good microbial quality in its natural state as compared with fresh surface water. Nevertheless, it may be contaminated with pathogenic microorganisms, especially viruses, and that may hamper drinking water production. The two most significant processes controlling virus mobility in the subsurface environment are virus attachment and inactivation. Based on previous studies, many factors have been identified that impact these processes, among them, pH and ionic strength (IS) seem to have the largest influence on virus removal. The objective of this work was to investigate the effects of pH and IS on virus removal in saturated porous media. In addition, it was the objective to determine quantitative relations for these effects. In order to do so, a systematic study was conducted in columns with clean sand under saturated conditions at various pH and IS values within the range of field conditions using bacteriophage PRD1 as a model virus. These experiments were conducted in a 50-cm column with clean quartz sand under saturated conditions and various combinations of pH and ionic strength. Values of pH were 5, 6, 7 and 8 and ionic strength values were 1, 10 and 20 mM. Bacteriophage PRD1 was used as a conservative model virus for virus removal. Attachment, detachment and inactivation rate coefficients were determined from fitting the breakthrough curves. Attachment rate coefficients were found to increase with decreasing pH and increasing ionic strength. Results were used to calculate sticking efficiency values and an empirical formula for it as a function of pH and ionic strength was developed. The applicability of this empirical formula at field scale requires further investigation. Effects of pH and ionic strength on the values of the detachment rate coefficients as well as on inactivation rate coefficients of attached virus particles were also determined but required higher certainty to obtain

  19. Tar sand

    Energy Technology Data Exchange (ETDEWEB)

    McLendon, T.R.; Bartke, T.C.


    Research on tar sand is briefly discussed. The research program supported by the US Department of Energy (DOE) includes a variety of surface extraction schemes. The University of Utah has process development units (PDU) employing fluidized bed, hot, water-assisted, and fluidized-bed/heat-pipe, coupled combustor technology. Considerable process variable test data have been gathered on these systems: (1) a rotary kiln unit has been built recently; (2) solvent extraction processing is being examined; and (3) an advanced hydrogenation upgrading scheme (hydropyrolysis) has been developed. The University of Arkansas, in collaboration with Diversified Petroleum, Inc., has been working on a fatty acid, solvent extraction process. Oleic acid is the solvent/surfactant. Solvent is recovered by adjusting processing fluid concentrations to separate without expensive operations. Western Research Institute has a PDU-scale scheme called the Recycle Oil Pyrolysis and Extraction (ROPE) process, which combines solvent (hot recycle bitumen) and pyrolytic extraction. 14 refs., 19 figs.

  20. 湿型砂造型中型砂质量的控制%Quality Control of Mould Sand in Green Sand Molding Process

    Institute of Scientific and Technical Information of China (English)

    赵洪仁; 边庆月; 马顺龙


    介绍了湿型砂各组分的作用.论述了型砂性能与其组分的关系,并指出控制好有效膨润土量和有效添加剂量是控制型砂质量的关键,结合生产实例阐述了型砂质量的控制要点.指出提高型砂质量控制水平、生产优质铸件和实现铸造生产循环用砂是铸造生产节能减排的有效方法.%In this paper, the functions of every component in green sand were outlined and the relationship between properties of mould sand and its component was discussed. It is the key to control content of effective bentonite and additives for mould sand quality. The main points of mould sand quality control were showed by practical production case. Enhancing quality control level for mould sand, producing high quality casting and realizing recycling use of sand in foundry production are effective methods in realization of energy saving and emission reduction of foundry production.

  1. Saturn Plasma Sources and Associated Transport Processes (United States)

    Blanc, M.; Andrews, D. J.; Coates, A. J.; Hamilton, D. C.; Jackman, C. M.; Jia, X.; Kotova, A.; Morooka, M.; Smith, H. T.; Westlake, J. H.


    This article reviews the different sources of plasma for Saturn's magnetosphere, as they are known essentially from the scientific results of the Cassini-Huygens mission to Saturn and Titan. At low and medium energies, the main plasma source is the H2O cloud produced by the "geyser" activity of the small satellite Enceladus. Impact ionization of this cloud occurs to produce on the order of 100 kg/s of fresh plasma, a source which dominates all the other ones: Titan (which produces much less plasma than anticipated before the Cassini mission), the rings, the solar wind (a poorly known source due to the lack of quantitative knowledge of the degree of coupling between the solar wind and Saturn's magnetosphere), and the ionosphere. At higher energies, energetic particles are produced by energy diffusion and acceleration of lower energy plasma produced by the interchange instabilities induced by the rapid rotation of Saturn, and possibly, for the highest energy range, by contributions from the CRAND process acting inside Saturn's magnetosphere. Discussion of the transport and acceleration processes acting on these plasma sources shows the importance of rotation-induced radial transport and energization of the plasma, and also shows how much the unexpected planetary modulation of essentially all plasma parameters of Saturn's magnetosphere remains an unexplained mystery.

  2. Modeling the simultaneous transport of silver nanoparticles and dissolved silver ions in water-saturated sand columns (United States)

    Taghavy, A.; Wang, Y.; Mittelman, A.; Becker, M. D.; Pennell, K. D.; Abriola, L. M.


    Concerns over the potential adverse impacts of nanosilver particles (nAg) on human health and the environment have arisen based upon their widespread use in various commercial and biomedical products. In addition, in situ dissolution of deposited nAg could enhance its environmental impact through the formation of dissolved silver ion (Ag+) plumes. A hybrid mathematical model is presented that simulates the simultaneous reactive transport of nAg/Ag+ in porous media. The simulator couples a Lagrangian Random Walk-based Particle Tracking (RWPT) method for nAg transport with a conventional Eulerian Finite Differencing (FD) scheme for the reactive transport of dissolved solutes. In the absence of oxidants other than dissolved oxygen (DO), nAg is assumed to dissolve via a cooperative oxidation reaction with DO and proton ions (H+), and dissolution is modeled by a first-order kinetic expression. An existing empirical correlation is implemented for evaluation of the dissolution rate constant from physiochemical characteristics of the system and nanoparticles, including solution pH, particle specific surface area (SSA), and temperature. The hybrid modeling approach enables the consideration of different particle size classes and the associated particle-specific dissolution rates. The utility of simulator is demonstrated by modeling results obtained from nAg/ Ag+ transport studies performed in ca. 10.8-cm long borosilicate glass columns with an inside diameter of 2.5 cm. Three column experiments were performed at a constant flow rate, yielding a particle approach velocity of 7.68±0.04 m/day, at dissolved oxygen concentrations ranging from 1.65 mg/L to 8.99 mg/L. A 3 pore volume pulse of nAg suspension, containing 3.17±0.07 mg/L total Ag and 10mM NaNO3 at pH 7.07, was injected into water-saturated columns packed with washed 40-50 mesh Ottawa sand. Following nAg injection, the columns were flushed with nAg-free background solution for an additional 3 pore volumes, which

  3. Hydrodynamic and Sediment Transport Model Application for OSAT3 Guidance: Ratio of wave- and current-induced shear stress to critical values for oil-sand ball and sediment mobilization (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey has developed a method for estimating the mobility and potential alongshore transport of heavier-than-water sand and oil agglomerates...

  4. Hydrodynamic and Sediment Transport Model Application for OSAT3 Guidance: Surf-zone integrated alongshore potential flux for oil-sand balls of varying sizes weighted by probability of wave scenario occurrence (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey has developed a method for estimating the mobility and potential alongshore transport of heavier-than-water sand and oil agglomerates...

  5. Hydrodynamic and Sediment Transport Model Application for OSAT3 Guidance: Ratio of wave- and current-induced shear stress to critical values for oil-sand ball and sediment mobilization (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey has developed a method for estimating the mobility and potential alongshore transport of heavier-than-water sand and oil agglomerates...

  6. Hydrodynamic and Sediment Transport Model Application for OSAT3 Guidance: Surf-zone integrated alongshore potential flux for oil-sand balls of varying sizes weighted by probability of wave scenario occurrence (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey has developed a method for estimating the mobility and potential alongshore transport of heavier-than-water sand and oil agglomerates...

  7. Potential impacts to perennial springs from tar sand mining, processing, and disposal on the Tavaputs Plateau, Utah, USA

    Energy Technology Data Exchange (ETDEWEB)

    Johnson, William P.; Frederick, Logan E.; Millington, Mallory R. [University of Utah, Department of Geology & Geophysics, Salt lake City, UT 84112 (United States); Vala, David [Murray High School, Murray, UT 84107 (United States); Reese, Barbara K. [Butler Middle School, Cottonwood Heights, UT 84121 (United States); Freedman, Dina R. [Hillside Middle School, Salt Lake City, UT 84108 (United States); Stenten, Christina J. [Draper Park Middle School, Draper, UT 84020 (United States); Trauscht, Jacob S.; Tingey, Christopher E.; Kip Solomon, D.; Fernandez, Diego P.; Bowen, Gabriel J. [University of Utah, Department of Geology & Geophysics, Salt lake City, UT 84112 (United States)


    Similar to fracking, the development of tar sand mining in the U.S. has moved faster than understanding of potential water quality impacts. Potential water quality impacts of tar sand mining, processing, and disposal to springs in canyons incised approximately 200 m into the Tavaputs Plateau, at the Uinta Basin southern rim, Utah, USA, were evaluated by hydrogeochemical sampling to determine potential sources of recharge, and chemical thermodynamic estimations to determine potential changes in transfer of bitumen compounds to water. Because the ridgetops in an area of the Tavaputs Plateau named PR Spring are starting to be developed for their tar sand resource, there is concern for potential hydrologic connection between these ridgetops and perennial springs in adjacent canyons on which depend ranching families, livestock, wildlife and recreationalists. Samples were collected from perennial springs to examine possible progression with elevation of parameters such as temperature, specific conductance, pH, dissolved oxygen, isotopic tracers of phase change, water-rock interaction, and age since recharge. The groundwater age dates indicate that the springs are recharged locally. The progression of hydrogeochemical parameters with elevation, in combination with the relatively short groundwater residence times, indicate that the recharge zone for these springs includes the surrounding ridges, and thereby suggests a hydrologic connection between the mining, processing, disposal area and the springs. Estimations based on chemical thermodynamic approaches indicate that bitumen compounds will have greatly enhanced solubility in water that comes into contact with the residual bitumen–solvent mixture in disposed tailings relative to water that currently comes into contact with natural tar. - Highlights: • The potential water quality impacts of the first US tar sand development are considered. • Analyses of perennial springs in adjacent canyons indicate hydrologic

  8. Provenance, transport and composition of Dendê Coast beach sands in Bahia, central coast of Brazil

    Directory of Open Access Journals (Sweden)

    Renata Cardia Rebouças


    Full Text Available The great physiographic diversity of the Dendê Coast favors the production of different beach sediment types, including bioclastic components. In this study 74 beach samples collected at 2 km intervals were used to evaluate beach sediment composition. For each sample, 300 grains were identified for each grain size class coarser than 0.125 mm, using a binocular microscope. The beach sediments of the Dendê Coast are essentially siliciclastic (80-100%. Quartz is the major component (70-100%. Only at the Tinharé and Boipeba islands bioclasts are major components of beach sands reaching up to 80-100%. These sediments are made up essentially of fragments of Halimeda, reaching percentages up to 70%. Coralline algae and mollusks also contribute significantly to these sediments (up to 30%. The results obtained show that the spatial distribution of the bioclastic components provide important information on the environmental conditions present at the shoreline (energy levels, availability of hard substrates and protected areas, pattern of sediment dispersion and on the sediment sources as well. The composition of the beach sediments on the Dendê Coast reflects the present day environmental conditions and show that these sediments do not experience significant lateral transport. This situation is favored by an impeded longshore transport that characterizes most of the region. Although, in general, the rivers that discharge on the Dendê Coast appear to transport few sediments to the coastal zone, the presence of heavy minerals, micas and feldspars suggests river contributions to the beach sediments. On the other hand, the coral and coralline algae reefs, besides offering a natural protection to the shoreline, also represent an important source of beach sands.A grande diversidade fisiográfica da Costa do Dendê favorece a deposição de diferentes tipos de sedimentos em suas praias, inclusive sedimentos ricos em carbonato de cálcio. Neste estudo 86

  9. Signal Processing Model for Radiation Transport

    Energy Technology Data Exchange (ETDEWEB)

    Chambers, D H


    This note describes the design of a simplified gamma ray transport model for use in designing a sequential Bayesian signal processor for low-count detection and classification. It uses a simple one-dimensional geometry to describe the emitting source, shield effects, and detector (see Fig. 1). At present, only Compton scattering and photoelectric absorption are implemented for the shield and the detector. Other effects may be incorporated in the future by revising the expressions for the probabilities of escape and absorption. Pair production would require a redesign of the simulator to incorporate photon correlation effects. The initial design incorporates the physical effects that were present in the previous event mode sequence simulator created by Alan Meyer. The main difference is that this simulator transports the rate distributions instead of single photons. Event mode sequences and other time-dependent photon flux sequences are assumed to be marked Poisson processes that are entirely described by their rate distributions. Individual realizations can be constructed from the rate distribution using a random Poisson point sequence generator.

  10. Monitoring the Effects of Oil Sands Process-Affected Water (OSPW) on Thecamoebian Assemblages: An Experimental Approach (United States)

    Christie, D. G.; McCarthy, F. F.; Penner, T.; MacKinnon, M. M.


    Thecamoebian (testate amoeba) assemblages have been shown to respond over short time periods to environmental conditions in aquatic reclamation options under development at oil sands operations in northeastern Alberta. This makes them a useful bio-monitoring tool for assessing reclamation success. Thecamoebian responses to Oil Sands Process Water (OSPW) have been monitored in the field at lacustrine and wetland test sites established by Syncrude Canada Ltd. and Suncor Energy Ltd. These field studies have confirmed that the generation times of testate amoebas is sufficiently rapid to permit the construction of a controlled laboratory experiment to be completed within one year, where controlled exposures of a natural assemblage of thecamoebians to OSPW can be undertaken to better understand the community responses to stressors We intend to culture these protists in the lab and monitor their response to different concentrations of OSPW in a controlled environment. Survival and changes in relative community composition (difflugiids vs. centropyxids) will be used to establish the dilution of OSPW in which thecameobians can survive and examine how a natural assemblage changes over time in response to increased concentrations of OSPW. This will assist in reclamation management in the Oil Sands region of Alberta.

  11. Fontainebleau Sand

    DEFF Research Database (Denmark)

    Leth, Caspar Thrane


    The report is a summary of results from laboratory tests in the geotechncial research group on Fontainebleau sand.......The report is a summary of results from laboratory tests in the geotechncial research group on Fontainebleau sand....

  12. 改性水玻璃砂工艺在铸钢生产中的应用%Application of Modified Sodium Silicate Sand Process in Steel Production

    Institute of Scientific and Technical Information of China (English)



    简要回顾了水玻璃砂在铸造生产应用中的发展历程,介绍了改性水玻璃砂的工艺性能及在机车车辆铸件中的应用。%The paper brief review of the silicate sand casting production applications in the development process,introduced the process performance of modified sodium silicate sand and applications in rolling stock casting.

  13. The extraction of bitumen from western oil sands. Quarterly report, April--June 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.


    Accomplishments are briefly described for the following tasks: environmental impact statement; coupled fluidized bed bitumen recovery and coked sand combustion; water-based recovery of bitumen; rotary kiln process for recovery of bitumen and combustion of coke sand; recovery of bitumen from oil sands using fluidized bed reactors and combustion of spent sands in transport reactors; recovery of bitumen from oil sand and upgrading of bitumen by solvent extraction; catalytic and thermal upgrading of bitumens and bitumen-derived liquids; evaluation of Utah`s major oil sand deposits for the production of asphalt, high energy jet fuels and other specialty products; development of mathematical models for bitumen recovery and processing; completion of the cost examination study of the pilot plant restoration; development studies of equipment for three-product gravity separation of bitumen and sand; determine thickener requirements; and environmental studies of the North Salt Lake pilot plant rehabilitation and eventual operation and those environmental problems associated with eventual commercial products.

  14. Granular activated carbon for simultaneous adsorption and biodegradation of toxic oil sands process-affected water organic compounds. (United States)

    Islam, Md Shahinoor; Zhang, Yanyan; McPhedran, Kerry N; Liu, Yang; Gamal El-Din, Mohamed


    Naphthenic acids (NAs) released into oil sands process-affected water (OSPW) during bitumen processing in Northern Alberta are problematic for oil sands industries due to their toxicity in the environment and resistance to degradation during conventional wastewater treatment processes. Granular activated carbon (GAC) has shown to be an effective media in removing biopersistent organics from wastewater using a combination of adsorption and biodegradation removal mechanisms. A simultaneous GAC (0.4 g GAC/L) adsorption and biodegradation (combined treatment) study was used for the treatment of raw and ozonated OSPW. After 28 days of batch treatment, classical and oxidized NAs removals for raw OSPW were 93.3% and 73.7%, and for ozonated OSPW were 96.2% and 77.1%, respectively. Synergetic effects of the combined treatment process were observed in removals of COD, the acid extractable fraction, and oxidized NAs, which indicated enhanced biodegradation and bioregeneration in GAC biofilms. A bacteria copy number >10(8) copies/g GAC on GAC surfaces was found using quantitative real time polymerase chain reaction after treatment for both raw and ozonated OSPW. A Microtox(®) acute toxicity test (Vibrio fischeri) showed effective toxicity removal (>95.3%) for the combined treatments. Therefore, the simultaneous GAC adsorption and biodegradation treatment process is a promising technology for the elimination of toxic OSPW NAs.

  15. Transport, retention, and long-term release behavior of ZnO nanoparticle aggregates in saturated quartz sand: Role of solution pH and biofilm coating. (United States)

    Han, Yosep; Hwang, Gukhwa; Kim, Donghyun; Bradford, Scott A; Lee, Byoungcheun; Eom, Igchun; Kim, Pil Je; Choi, Siyoung Q; Kim, Hyunjung


    The transport, retention, and long-term release of zinc oxide nanoparticle aggregates (denoted below as ZnO-NPs) were investigated in saturated, bare and biofilm (Pseudomonas putida) coated sand packed columns. Almost complete retention of ZnO-NPs occurred in bare and biofilm coated sand when the influent solution pH was 9 and the ionic strength (IS) was 0.1 or 10 mM NaCl, and the retention profiles were always hyper-exponential. Increasing the solution IS and biofilm coating produced enhanced retention of ZnO-NPs near the column inlet. The enhanced NPs retention at high IS was attributed to more favorable NP-silica and NP-NP interactions; this was consistent with the interaction energy calculations. Meanwhile, the greater NPs retention in the presence of biofilm was attributed to larger roughness heights which alter the mass transfer rate, the interaction energy profile, and lever arms associated with the torque balance; e.g., scanning electron and atomic force microscopy was used to determine roughness heights of 33.4 nm and 97.8 nm for bare sand and biofilm-coated sand, respectively. Interactions between NPs and extracellular polymeric substances may have also contributed to enhanced NP retention in biofilm-coated sand at low IS. The long-term release of retained ZnO-NPs was subsequently investigated by continuously injecting NP-free solution at pH 6, 9, or 10 and keeping the IS constant at 10 mM. The amount and rate of retained ZnO-NP removal was strongly dependent on the solution pH. Specifically, almost complete removal of retained ZnO-NPs was observed after 627 pore volumes when the solution pH was 6, whereas much less Zn was recovered when the eluting solution pH was buffered to pH = 9 and especially 10. This long-term removal was attributed to pH-dependent dissolution of retained ZnO-NPs because: (i) the solubility of ZnO-NPs increases with decreasing pH; and (ii) ZnO-NPs were not detected in the effluent. The presence of biofilm also decreased the

  16. Degradation and aquatic toxicity of naphthenic acids in oil sands process-affected waters using simulated wetlands. (United States)

    Toor, Navdeep S; Franz, Eric D; Fedorak, Phillip M; MacKinnon, Michael D; Liber, Karsten


    Oil sands process-affected waters (OSPWs) produced during the extraction of bitumen at the Athabasca Oil Sands (AOS) located in northeastern Alberta, Canada, are toxic to many aquatic organisms. Much of this toxicity is related to a group of dissolved organic acids known as naphthenic acids (NAs). Naphthenic acids are a natural component of bitumen and are released into process water during the separation of bitumen from the oil sand ore by a caustic hot water extraction process. Using laboratory microcosms as an analogue of a proposed constructed wetland reclamation strategy for OSPW, we evaluated the effectiveness of these microcosms in degrading NAs and reducing the aquatic toxicity of OSPW over a 52-week test period. Experimental manipulations included two sources of OSPW (one from Syncrude Canada Ltd. and one from Suncor Energy Inc.), two different hydraulic retention times (HRTs; 40 and 400 d), and increased nutrient availability (added nitrate and phosphate). Microcosms with a longer HRT (for both OSPWs) showed higher reductions in total NAs concentrations (64-74% NAs reduction, p100% v/v) independent of HRT. However, EC20s from separate Microtox® bioassays were relatively unchanged when comparing the input and microcosm waters at both HRTs over the 52-week study period (p>0.05), indicating that some sub-lethal toxicity persisted under these experimental conditions. The present study demonstrated that given sufficiently long HRTs, simulated wetland microcosms containing OSPW significantly reduced total NAs concentrations and acute toxicity, but left behind a persistent component of the NAs mixture that appeared to be associated with residual chronic toxicity.

  17. Application of design projects developed by Foundry Research Institute in Krakow in construction of integrated stand for processing and reclamation of moulding sands

    Directory of Open Access Journals (Sweden)

    I. Izdebska-Szanda


    Full Text Available The article is devoted to the description of a new integrated system for processing and reclamation of moulding and core sands using the equipment developed by Foundry Research Institute in Krakow. The idea and operation of a complex stand, which allows for co-existence of three routes of material circulation, i.e. system sand, new sand and reclaim, with maximum utilisation of the existing equipment have been presented. Various aspects, economical and ecological, of the proposed design have been discussed.

  18. Evaluating the oil sands reclamation process: Assessing policy capacity and stakeholder access for government and non-governmental organizations operating in Alberta's oil sands (United States)

    Patterson, Tyler

    By employing interpretive policy analysis this thesis aims to assess, measure, and explain policy capacity for government and non-government organizations involved in reclaiming Alberta's oil sands. Using this type of analysis to assess policy capacity is a novel approach for understanding reclamation policy; and therefore, this research will provide a unique contribution to the literature surrounding reclamation policy. The oil sands region in northeast Alberta, Canada is an area of interest for a few reasons; primarily because of the vast reserves of bitumen and the environmental cost associated with developing this resource. An increase in global oil demand has established incentive for industry to seek out and develop new reserves. Alberta's oil sands are one of the largest remaining reserves in the world, and there is significant interest in increasing production in this region. Furthermore, tensions in several oil exporting nations in the Middle East remain unresolved, and this has garnered additional support for a supply side solution to North American oil demands. This solution relies upon the development of reserves in both the United States and Canada. These compounding factors have contributed to the increased development in the oil sands of northeastern Alberta. Essentially, a rapid expansion of oil sands operations is ongoing, and is the source of significant disturbance across the region. This disturbance, and the promises of reclamation, is a source of contentious debates amongst stakeholders and continues to be highly visible in the media. If oil sands operations are to retain their social license to operate, it is critical that reclamation efforts be effective. One concern non-governmental organizations (NGOs) expressed criticizes the current monitoring and enforcement of regulatory programs in the oil sands. Alberta's NGOs have suggested the data made available to them originates from industrial sources, and is generally unchecked by government

  19. Geochemical interactions between process-affected water from oil sands tailings ponds and North Alberta surficial sediments. (United States)

    Holden, A A; Donahue, R B; Ulrich, A C


    In Northern Alberta, the placement of out-of-pit oil sands tailings ponds atop natural buried sand channels is becoming increasingly common. Preliminary modeling of such a site suggests that process-affected (PA) pond water will infiltrate through the underlying clay till aquitard, reaching the sand channel. However, the impact of seepage upon native sediments and groundwater resources is not known. The goal of this study is to investigate the role of adsorption and ion exchange reactions in the clay till and their effect on the attenuation or release of inorganic species. This was evaluated using batch sorption experiments (traditional and a recent modification using less disturbed sediment samples) and geochemical modeling with PHREEQC. The results show that clay till sediments have the capacity to mitigate the high concentrations of ingressing sodium (600 mg L(-1)), with linear sorption partitioning coefficients (K(d)) of 0.45 L kg(-1). Ion exchange theory was required to account for all other cation behaviour, precluding the calculation of such coefficients for other species. Qualitative evidence suggests that chloride will behave conservatively, with high concentrations remaining in solution (375 mg L(-1)). As a whole, system behaviour was found to be controlled by a combination of competitive ion exchange, dissolution and precipitation reactions. Observations, supported by PHREEQC simulations, suggest that the influx of PA water will induce the dissolution of pre-existing sulphate salts. Sodium present in the process-affected water will exchange with sediment-bound calcium and magnesium, increasing the divalent ions' pore fluid concentrations, and leading to the precipitation of a calcium-magnesium carbonate mineral phase. Thus, in similar tailings pond settings, particularly if the glacial till coverage is thin or altogether absent, it is reasonable to expect that high concentrations of sodium and chloride will remain in solution, while sulphate

  20. Modeling the transport of shigella in silty and fine sand in shallow aquifers in Caostal area of bonny Niger delta; rivers state of Nigeria

    Directory of Open Access Journals (Sweden)

    Solomon Ndubuisi Eluozo


    Full Text Available Modeling the transport of shigella in silty and fine sand formation in shallow aquifer has been developed, the model were generated to monitor the transport of shigella in coastal area of bonny, as coastal environment  there are lots of  influence in the soil formation, the major variable were considered in the development of the theoretical model, this condition were assessed and were integrated , this variables were  considered and it  develop a system that generated the model equation since the microbes are  found to be in exponential phase ,because of high degree of porosity and permeability of the soil formation, the mathematical equation  were found to  consider  these variables to ensure it predict the rate of deposition of shigella in  silty and fine sand formation, the model developed predict the transport of shigella in the coastal area of bonny, Niger Delta area of Nigeria, the model will be one of the baseline to reduce high rate of shigella  in the study area, the study has also provide a design benchmark for practicing  engineers and scientist to ensure that thorough ground are provide by application of the these design model.  

  1. The dimensions of sand ripples in full-scale oscillatory flows

    NARCIS (Netherlands)

    O'Donoghue, T.; Doucette, J.C.; Werf, van der J.J.; Ribberink, J.S.


    New large-scale experiments have been carried out in two oscillatory flow tunnels to study ripple regime sand suspension and net sand transport processes in full-scale oscillatory flows. The paper focuses on ripple dimensions and the new data are combined with existing data to make a large dataset o

  2. Microbes in Beach Sands: Integrating Environment, Ecology and Public Health. (United States)

    Whitman, Richard; Harwood, Valerie J; Edge, Thomas A; Nevers, Meredith; Byappanahalli, Muruleedhara; Vijayavel, Kannappan; Brandão, João; Sadowsky, Michael J; Alm, Elizabeth Wheeler; Crowe, Allan; Ferguson, Donna; Ge, Zhongfu; Halliday, Elizabeth; Kinzelman, Julie; Kleinheinz, Greg; Przybyla-Kelly, Kasia; Staley, Christopher; Staley, Zachery; Solo-Gabriele, Helena M


    Beach sand is a habitat that supports many microbes, including viruses, bacteria, fungi and protozoa (micropsammon). The apparently inhospitable conditions of beach sand environments belie the thriving communities found there. Physical factors, such as water availability and protection from insolation; biological factors, such as competition, predation, and biofilm formation; and nutrient availability all contribute to the characteristics of the micropsammon. Sand microbial communities include autochthonous species/phylotypes indigenous to the environment. Allochthonous microbes, including fecal indicator bacteria (FIB) and waterborne pathogens, are deposited via waves, runoff, air, or animals. The fate of these microbes ranges from death, to transient persistence and/or replication, to establishment of thriving populations (naturalization) and integration in the autochthonous community. Transport of the micropsammon within the habitat occurs both horizontally across the beach, and vertically from the sand surface and ground water table, as well as at various scales including interstitial flow within sand pores, sediment transport for particle-associated microbes, and the large-scale processes of wave action and terrestrial runoff. The concept of beach sand as a microbial habitat and reservoir of FIB and pathogens has begun to influence our thinking about human health effects associated with sand exposure and recreational water use. A variety of pathogens have been reported from beach sands, and recent epidemiology studies have found some evidence of health risks associated with sand exposure. Persistent or replicating populations of FIB and enteric pathogens have consequences for watershed/beach management strategies and regulatory standards for safe beaches. This review summarizes our understanding of the community structure, ecology, fate, transport, and public health implications of microbes in beach sand. It concludes with recommendations for future work in

  3. Simple stochastic cellular automaton model for starved beds and implications about formation of sand topographic features in terms of sand flux (United States)

    Endo, Noritaka


    A simple stochastic cellular automaton model is proposed for simulating bedload transport, especially for cases with a low transport rate and where available sediments are very sparse on substrates in a subaqueous system. Numerical simulations show that the bed type changes from sheet flow through sand patches to ripples as the amount of sand increases; this is consistent with observations in flume experiments and in the field. Without changes in external conditions, the sand flux calculated for a given amount of sand decreases over time as bedforms develop from a flat bed. This appears to be inconsistent with the general understanding that sand flux remains unchanged under the constant-fluid condition, but it is consistent with the previous experimental data. For areas of low sand abundance, the sand flux versus sand amount (flux-density relation) in the simulation shows a single peak with an abrupt decrease, followed by a long tail; this is very similar to the flux-density relation seen in automobile traffic flow. This pattern (the relation between segments of the curve and the corresponding bed states) suggests that sand sheets, sand patches, and sand ripples correspond respectively to the free-flow phase, congested phase, and jam phase of traffic flows. This implies that sand topographic features on starved beds are determined by the degree of interference between sand particles. Although the present study deals with simple cases only, this can provide a simplified but effective modeling of the more complicated sediment transport processes controlled by interference due to contact between grains, such as the pulsatory migration of grain-size bimodal mixtures with repetition of clustering and scattering.

  4. Respiratory fluid mechanics and transport processes. (United States)

    Grotberg, J B


    The field of respiratory flow and transport has experienced significant research activity over the past several years. Important contributions to the knowledge base come from pulmonary and critical care medicine, surgery, physiology, environmental health sciences, biophysics, and engineering. Several disciplines within engineering have strong and historical ties to respiration including mechanical, chemical, civil/environmental, aerospace and, of course, biomedical engineering. This review draws from a wide variety of scientific literature that reflects the diverse constituency and audience that respiratory science has developed. The subject areas covered include nasal flow and transport, airway gas flow, alternative modes of ventilation, nonrespiratory gas transport, aerosol transport, airway stability, mucus transport, pulmonary acoustics, surfactant dynamics and delivery, and pleural liquid flow. Within each area are a number of subtopics whose exploration can provide the opportunity of both depth and breadth for the interested reader.

  5. Photocatalytic degradation kinetics of naphthenic acids in oil sands process-affected water: Multifactorial determination of significant factors. (United States)

    Leshuk, Tim; de Oliveira Livera, Diogo; Peru, Kerry M; Headley, John V; Vijayaraghavan, Sucharita; Wong, Timothy; Gu, Frank


    Oil sands process-affected water (OSPW) is generated as a byproduct of bitumen extraction in Canada's oil sands. Due to the water's toxicity, associated with dissolved acid extractable organics (AEO), especially naphthenic acids (NAs), along with base-neutral organics, OSPW may require treatment to enable safe discharge to the environment. Heterogeneous photocatalysis is a promising advanced oxidation process (AOP) for OSPW remediation, however, predicting treatment efficacy can be challenging due to the unique water chemistry of OSPW from different tailings ponds. The objective of this work was to study various factors affecting the kinetics of photocatalytic AEO degradation in OSPW. The rate of photocatalytic treatment varied significantly in two different OSPW sources, which could not be accounted for by differences in AEO composition, as studied by high resolution mass spectrometry (HRMS). The effects of inorganic water constituents were investigated using factorial and response surface experiments, which revealed that hydroxyl (HO) radical scavenging by iron (Fe(3+)) and bicarbonate (HCO3(-)) inhibited the NA degradation rate. The effects of NA concentration and temperature on the treatment kinetics were also evaluated in terms of Langmuir-Hinshelwood and Arrhenius models; pH and temperature were identified as weak factors, while dissolved oxygen (DO) was critical to the photo-oxidation reaction. Accounting for all of these variables, a general empirical kinetic expression is proposed, enabling prediction of photocatalytic treatment performance in diverse sources of OSPW.

  6. Degradation of Reactive Black 5 dye by CWPO using Fe/mining sand under photo-Fenton process (United States)

    Amri, Nurulhuda; Nasuha, Norhaslinda; Halim, Siti Fatimah Abdul; Ngah, Khairuddin


    This present study was conducted to investigate the effectiveness of catalytic wet peroxide oxidation (CWPO) process using photo-Fenton method and the used of mining sand as support catalyst as well as to determine the optimum parameters and effect of catalyst wt%, pH, H2O2 concentration, initial dye concentration and catalyst dosage on RB 5 degradation. The Fe/mining sand was prepared by impregnation technique and a solar degradation of RB 5 carried out by mean photo-Fenton reaction promoted by solar energy. The dye degradation was monitored during the experimental runs through UV/Vis spectrophotometer. In this process, the reaction condition were optimized at 0.4 of catalyst wt%, pH 2, 4 mM of H2O2 concentration and 0.5 g of catalyst dosage which achieved degradation efficiency at 100% for the three experiments except catalyst dosage which achieved 97.54% respectively within 180 min. The degradation of RB 5 also decreased with the increasing of dye concentration with 10 mg/L achieved the optimum degradation of 99.93%. The results demonstrated that photo-Fenton method could effectively degrade RB 5 and reduce the operating cost by conducting the experiment at optimum conditions.

  7. Shifts in leaf N:P stoichiometry during rehabilitation in highly alkaline bauxite processing residue sand. (United States)

    Goloran, Johnvie B; Chen, Chengrong; Phillips, Ian R; Elser, James J


    Large quantities of sodic and alkaline bauxite residue are produced globally as a by-product from alumina refineries. Ecological stoichiometry of key elements [nitrogen (N) and phosphorus (P)] plays a critical role in establishing vegetation cover in bauxite residue sand (BRS). Here we examined how changes in soil chemical properties over time in rehabilitated sodic and alkaline BRS affected leaf N to P stoichiometry of native species used for rehabilitation. Both Ca and soil pH influenced the shifts in leaf N:P ratios of the study species as supported by consistently significant positive relationships (P stoichiometry can effectively provide a meaningful assessment on understanding nutrient limitation and productivity of native species used for vegetating highly sodic and alkaline BRS, and is a crucial indicator for assessing ecological rehabilitation performance.

  8. Dry reusing and wet reclaiming of used sodium silicate sand

    Institute of Scientific and Technical Information of China (English)


    Based on the characteristics of used sodium silicate sand and the different use requirements for recycled sand, "dry reusing and wet reclaiming of used sodium silicate sand" is considered as the most suitable technique for the used sand. When the recycled sand is used as support sand, the used sand is only reused by dry process including breaking, screening, dust-removal, etc., and it is not necessary that the used sand is reclaimed with strongly rubbing and scraping method, but when the recycled sand is used as facing sand (or single sand), the used sand must be reclaimed by wet method for higher removal rate of the residual binders. The characteristics and the properties of the dry reused sand are compared with the wet reclaimed sand after combining the different use requirements of support sand and facing sand (or single sand), and above the most adaptive scheme has also been validated.

  9. Development of 3D beach evolution model for sand nourishments and its application to morphodynamics around coastal structures


    Kuroiwa, M.; Matsubara, Y.; Fujitani, H.; H. Mase


    A numerical model to predict three-dimensional (3D) beach evolution after sand nourishment was developed. The injection process of sand to near shoreline or offshore area was expressed by the sediment flux in the conservation equation associated with sediment transports and water depth changes, furthermore, sand dredging process was considered. In this study, First, computation of beach evolution around a coastal structure with and without nourishment was carried out. Secondly, the develop...

  10. 厦门岛东南部海岸演变与泥沙输移%Coast evolution and sand transportation in east-southern Xiamen Island

    Institute of Scientific and Technical Information of China (English)

    陈坚; 蔡锋


    By means of coastal morphology and sediment investigation, shore change and littoral sand transportation rate calculation et al., characteristics of beach evolution in east-southern Xiamen Island were analyzed and studied. It is announced that the direction of net littoral sand transportation is from east-north to west-south and from east to west. Coast hereof is divided into 6 types, which are serious erosion type, mild-serious erosion type, mild erosion type, slight erosion type, slight deposit type and undefined type. Moreover, sand mining was defined as one of the most important factors for coast erosion.%通过海岸地貌调查、沉积物分布、岸线对比、沿岸输沙率计算等手段,分析研究了厦门岛东南部海岸海滩的演变特征.认为厦门岛东南部海岸的沿岸净输沙方向是由东北向西南,由东向西;黄厝湾中北部存在反向输沙.文中划分了中-强侵蚀海岸、中侵蚀海岸、中-弱侵蚀海岸、弱侵蚀海岸、弱淤积海岸和不确定海岸等6种类型.人工采沙是引起海岸侵蚀的最重要因素之一.

  11. Testing Shelter Index and a Simple Wind Speed Parameter to Characterize Vegetation Control of Sand Transport Threshold and Flux (United States)

    Gillies, John; Nield, Joanna; Nickling, William; Furtak-Cole, Eden


    Wind erosion and dust emissions occur in the Chihuahuan Desert surrounding Las Cruces NM from a range of surfaces with different types and amounts of vegetation. Understanding how vegetation modulates these processes remains a research challenge. One important aspect of research is to develop a relationship between a descriptor of the surface roughness that can be used to provide an indication of how susceptible the sediment transport system is to activation by wind. Here we present results from a study that examines the relationship between an index of shelter (distance from a point to the nearest upwind vegetation/vegetation height), as originally proposed by Okin (2008), and particle threshold expressed as a ratio of wind measured at 0.45 times the plant height divided by the wind speed at 17 m, and saltation flux (g cm-2 s-1). Saltation flux was measured using sediment traps positioned 15 cm above the surface and nearby optical gate sensors (Wenglor® model YH03PCT8)measuring saltation activity also placed at a height of 15 cm. The results are used to evaluate shelter index as a parameter to characterize the local winds as influenced by the vegetation and sediment transport conditions (threshold and transport). Wind speed, wind direction, saltation activity and point saltation flux were measured at 35 locations in defined test areas (~13,000 m2) in three vegetation communities: mature mesquite covered nebkha dunes, incipient nebkha dunes dominated by low mesquite plants, and a mature creosote bush area. Measurement positions represent the most open areas, and hence those places most susceptible to wind erosion among the vegetation elements. Shelter index was calculated for each measurement position for each approximately 10 degree wind direction bin using digital elevation models for each site acquired using terrestrial laser scanning.

  12. Dual Transport Process for Targeted Delivery in Porous Media (United States)

    Deng, W.; Fan, J.


    The targeted delivery in porous media is a promising technology to encapsulate the solute (i.e., the cargo) in colloid-like microcapsules (i.e., the carriers), transport the microcapsules in the targeted location in porous media, and then release the solute. While extensive literatures and applications about the drug delivery in human and animal bodies exist, the targeted delivery using similar delivery carriers in subsurface porous media is not well understood. The dual transport process study is an explorative study for the targeted delivery in porous media. While the colloid transport is dominated by the advection process and the solute transport is dominated by the advection-dispersion, the dual transport process is the process with the first step of carrier transport, which is dominated by advection, and then after the release of cargo, the transport of cargo is dominated by advection-dispersion. By applying the random walk particle tracking (RWPT) approach, we investigate how the carriers transport in porous media and how the cargo release mechanisms affect the cargo distribution for the targeted delivery in various patterns of porous media. The RWPT numerical model will be verified against the experimental results of dual transport process in packed-disk 2D micromodels. The understanding of the mechanism of dual transport process is crucial to achieve the potential applications of targeted delivery in improved oil and gas recovery, CO2 sequestration, environmental remediation, and soil biomediation.

  13. Biological removal of iron and manganese in rapid sand filters - Process understanding of iron and manganese removal

    DEFF Research Database (Denmark)

    Lin, Katie

    -filter, where iron is removed. Step 2: Filtration in an after-filter where e.g. ammonium and manganese is removed. The treatment relies on microbial processes and may present an alternative, greener and more sustainable approach for drinking water production spending less chemicals and energy than chemical (e.......g. flocculation) and physical (e.g. membrane filtration) based technologies. The removal of dissolved manganese and iron is important. If manganese and iron enter the distribution system, the water will become coloured and have a metallic taste, and it may cause problems in the distribution network due......, it is essential to ensure that the required microorganisms are present and that both the physical and the nutritional requirements of those organisms are fulfilled. However, the knowledge on the microbiology and processes in rapid sand filters is limited, especially on which parameters that affect the biological...

  14. Are there toxic interactions between salinity and naphthenic acids in the toxicity of oil sands process water to freshwater invertebrates?

    Energy Technology Data Exchange (ETDEWEB)

    Turcotte, D.; Pasloski, A.; Lanser, B.; Alm, K.; Liber, K. [Saskatchewan Univ., Saskatoon, SK (Canada)


    Large volumes of water are used to extract oil from the oil sands in the Athabasca deposit. The resulting oil sands process water (OSPW) has been proposed for use in future reclamation landscapes. Therefore, it is necessary to evaluate the toxicity of OSPW to freshwater invertebrates in order to develop environmentally acceptable OSPW reclamation plans. The OSPW generally contains high concentrations of salts and naphthenic acids (NAs), but low levels of other contaminants such as PAHs and metals. This study investigated the combined toxic effect of NAs and salinity on freshwater invertebrates. Laboratory cultured Ceriodaphnia dubia were used initially to determine the toxicity of OSPW from selected water bodies. The pond waters that generated a toxic response had elevated levels of NAs and salinity, but the concentrations of salinity ions varied considerably among ponds. Results suggested that ion composition may be a factor in toxicity. Subsequent bioassays were performed with single salts and with mixtures representing major ion combinations present in the OSPW, such as carbonate, sulphate, chloride and sodium. The interaction between NAs and salinity was evaluated by exposing Ceriodaphnia dubia and Daphnia pulex to mixtures of NAs extracted from OSPW and relevant major ions chosen according to the salt toxicity test results.

  15. Elucidating mechanisms of toxic action of dissolved organic chemicals in oil sands process-affected water (OSPW). (United States)

    Morandi, Garrett D; Wiseman, Steve B; Guan, Miao; Zhang, Xiaowei W; Martin, Jonathan W; Giesy, John P


    Oil sands process-affected water (OSPW) is generated during extraction of bitumen in the surface-mining oil sands industry in Alberta, Canada, and is acutely and chronically toxic to aquatic organisms. It is known that dissolved organic compounds in OSPW are responsible for most toxic effects, but knowledge of the specific mechanism(s) of toxicity, is limited. Using bioassay-based effects-directed analysis, the dissolved organic fraction of OSPW has previously been fractionated, ultimately producing refined samples of dissolved organic chemicals in OSPW, each with distinct chemical profiles. Using the Escherichia coli K-12 strain MG1655 gene reporter live cell array, the present study investigated relationships between toxic potencies of each fraction, expression of genes and characterization of chemicals in each of five acutely toxic and one non-toxic extract of OSPW derived by use of effects-directed analysis. Effects on expressions of genes related to response to oxidative stress, protein stress and DNA damage were indicative of exposure to acutely toxic extracts of OSPW. Additionally, six genes were uniquely responsive to acutely toxic extracts of OSPW. Evidence presented supports a role for sulphur- and nitrogen-containing chemical classes in the toxicity of extracts of OSPW. Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Reproductive and stress hormone levels in goldfish (Carassius auratus) exposed to oil sands process-affected water. (United States)

    Lister, A; Nero, V; Farwell, A; Dixon, D G; Van Der Kraak, G


    Athabasca oil sands mining in northern Alberta produces process-affected waters that are characterized by the presence of naphthenic acids, polycyclic aromatic hydrocarbons, and high salinity. The purpose of this study was to examine the impact of these process-affected waters on reproductive and stress related endpoints in mature goldfish, Carassius auratus. In two separate studies, testosterone and 17beta-estradiol levels in the plasma were significantly reduced in both male and female goldfish caged for 19 days in process-affected waters relative to controls. This effect was most pronounced in goldfish caged at a site containing mature fine tailing and tailings pond water (P5). Ovarian and testicular tissues from fish in the caging studies were incubated in vitro to evaluate potential differences in basal steroid production levels and responsiveness to human chorionic gonadotropin (hCG). Basal levels of testosterone were reduced significantly in males and females from P5 compared with the control pond (P1) demonstrating that the gonads from exposed fish had a diminished steroidogenic capacity. Gonadal tissues of fish from all ponds responded similarly to hCG suggesting that the steroid biosynthetic pathway remained functionally intact. Plasma cortisol levels were significantly higher in male goldfish caged in a pond containing mature fine tailings and capped with uncontaminated water (P3) and in P5 compared with P1. Collectively, these studies suggest that waste products of oil sands mining have the potential to disrupt the normal endocrine functioning in exposed fish through alterations to both reproductive and glucocorticoid hormone biosynthesis. In additional laboratory studies, exposure of goldfish to a naphthenic acid extract for 7 days failed to replicate the effects of processes-affected waters on plasma steroid levels and the causative agent(s) responsible for the effects on steroid biosynthesis remains to be identified.

  17. Redox transformations and transport of cesium and iodine (-1, 0, +5) in oxidizing and reducing zones of a sand and gravel aquifer (United States)

    Fox, P.M.; Kent, D.B.; Davis, J.A.


    Tracer tests were performed in distinct biogeochemical zones of a sand and gravel aquifer in Cape Cod, MA, to study the redox chemistry (I) and transport (Cs, I) of cesium and iodine in a field setting. Injection of iodide (I -) into an oxic zone of the aquifer resulted in oxidation of I - to molecular iodine (I2) and iodate (IO3-) over transport distances of several meters. Oxidation is attributed to Mn-oxides present in the sediment. Transport of injected IO 3- and Cs+ was retarded in the mildly acidic oxic zone, with retardation factors of 1.6-1.8 for IO3- and 2.3-4.4for Cs. Cs retardation was likely due to cation exchange reactions. Injection of IO3- into a Fe-reducing zone of the aquifer resulted in rapid and complete reduction to I- within 3 m of transport. The nonconservative behavior of Cs and I observed during the tracer tests underscores the necessity of taking the redox chemistry of I as well as sorption properties of I species and Cs into account when predicting transport of radionuclides (e.g., 129I and 137Cs) in the environment.

  18. The dynamics of local processes towards environmentally sustainable transport

    DEFF Research Database (Denmark)

    Hansen, Carsten Jahn


    The paper explores and discusses the dynamics of local leading towards the creation of an environmentally sustainable transport system. processes......The paper explores and discusses the dynamics of local leading towards the creation of an environmentally sustainable transport system. processes...

  19. Transport of contaminants from energy-process-waste leachates through subsurface soils and soil components: laboratory experiments

    Energy Technology Data Exchange (ETDEWEB)

    Wangen, L.E.; Stallings, E.A.; Walker, R.D.


    The subsurface transport and attenuation of inorganic contaminants common to a variety of energy process waste leachates are being studied using laboratory column methods. Anionic species currently being emphasized are As, B, Mo, and Se. Transport of the cations Cd and Ni is also being studied. The solid adsorbents consist of three soil mineral components (silica sand, kaolinite, and goethite), and four subsurface soils (a dunal sand, an oxidic sandy clay loam, an acidic clay loam, and an alkaline clay loam). Breakthrough patterns of these species from packed soil columns are followed by monitoring eluent concentrations vs time under carefully controlled laboratory conditions. This report describes the experimental methods being used, the results of preliminary batch adsorption studies, and the results of column experiments completed through calendar year 1981. Using column influent concentrations of about 10 mg/l, adsorption (mmoles/100 g) has been determined from the eluent volume corresponding to 50% breakthrough. On silica sand, kaolinite, dunal sand, and goethite, respectively, these are 2.0 x 10/sup -4/, 0.020, 0.013, and 0.31 for cadmium, 4.4 x 10/sup -4/, 0.039, 0.020, and 0.98 for nickel. On kaolinite, dunal sand, and goethite, respectively, adsorption values (mmoles/100 g) are As (0.24, 0.019, and 20.5), B (0.041, 0.0019, and 1.77), Mo (0.048, 0.0010, and 5.93), and Se (0.029, 0.00048, and 1.30). Arsenic is the most highly adsorbed contaminant species and goethite has the largest adsorption capacity of the adsorbents.

  20. Reproductive and health assessment of fathead minnows (Pimephales promelas) inhabiting a pond containing oil sands process-affected water

    Energy Technology Data Exchange (ETDEWEB)

    Kavanagh, Richard J., E-mail: [Department of Integrative Biology, University of Guelph, Guelph, ON, Canada N1G 2W1 (Canada); Frank, Richard A.; Solomon, Keith R. [Centre for Toxicology, University of Guelph, Guelph, ON, Canada N1G 2W1 (Canada); Van Der Kraak, Glen [Department of Integrative Biology, University of Guelph, Guelph, ON, Canada N1G 2W1 (Canada)


    Highlights: ► Fish were collected from a pond containing oil sands process-affected water (OSPW). ► They were compared to fish from two reference sites within the oil sands region. ► Differences in GSIs and tubercle numbers were observed in fish from the OSPW pond. ► Opercula, gills, and 11-KT concentrations also differed in fish from the OSPW pond. ► Black spot and tapeworms were not observed in any of the fish from the OSPW pond. -- Abstract: Previous laboratory based studies have shown that oil sands process-affected waters (OSPWs) containing high concentrations of naphthenic acids (>25 mg/l) have adverse effects on the reproductive physiology of fish. The purpose of this study was to assess the reproductive development and health of a wild population of fathead minnows (Pimephales promelas) inhabiting an OSPW pond that has moderate concentrations of naphthenic acids (∼10 mg/l). Fathead minnows were collected at various times during the period of 2006 through 2008 from Demonstration Pond (OSPW) located at Syncrude Canada Ltd., and two reference sites, Beaver Creek reservoir and Poplar Creek reservoir, which are all north of Fort McMurray, AB, Canada. Condition factor, gill histopathology, gonadosomatic indices, liver somatic indices, male secondary sexual characteristics, and plasma sex steroids were examined. Depending on the time of year that fathead minnows were collected, there were differences in the condition factor, gonadosomatic indices, liver somatic indices, and secondary sexual characteristics of fathead minnows (in males) from Demonstration Pond when compared to the fathead minnows from the reference sites. In comparison to reference fish, lower concentrations of 11-ketotestosterone were measured in the plasma of male fathead minnows collected from Demonstration Pond in June 2006 and July 2007. Black spot disease and Ligula intestinalis were prevalent in fathead minnows from the reference sites but were not observed in fathead minnows

  1. In vitro evaluation of the toxic effects and endocrine disrupting potential of oil sands processed water and naphthenic acids

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, X.; Wiseman, S.; Higley, E.; Jones, P.D.; Hecker, M.; Giesy, J.P. [Saskatchewan Univ., Saskatoon, SK (Canada); Gamel El Din, M.; Martin, J.W. [Alberta Univ., Edmonton, AB (Canada)


    Naphthenic acids (NAs) are the primary toxic constituents of oil sands process-affected waters (OSPW). This presentation reported on a series of in vitro studies that were initiated to evaluate potential endocrine modulating effects of OSPW and their constituent NAs. The H295R steroidogenesis bioassay was used to examine the impact of OSPW and NA on 52 steroidogenesis. In particular, dose-response and time course studies were conducted to evaluate the impact of OSPW and NAs on testosterone and estradiol production. Aromatase activity and transcript abundance of the key 11 steroidogenic enzymes were also quantified to complement analysis of hormone levels. The MVLN trans-activation assay was used to test the estrogenicity/anti-estrogenicity of OSPW and NAs. In vitro cell viability and apoptosis (live-dead) caused by OSPW and NAs was quantified by the MTS reduction and caspase-3/7 activity in H295R and MVLN cells.

  2. Naphthenic acids speciation and removal during petroleum-coke adsorption and ozonation of oil sands process-affected water. (United States)

    Gamal El-Din, Mohamed; Fu, Hongjing; Wang, Nan; Chelme-Ayala, Pamela; Pérez-Estrada, Leonidas; Drzewicz, Przemysław; Martin, Jonathan W; Zubot, Warren; Smith, Daniel W


    The Athabasca Oil Sands industry produces large volumes of oil sands process-affected water (OSPW) as a result of bitumen extraction and upgrading processes. Constituents of OSPW include chloride, naphthenic acids (NAs), aromatic hydrocarbons, and trace heavy metals, among other inorganic and organic compounds. To address the environmental issues associated with the recycling and/or safe return of OSPW into the environment, water treatment technologies are required. This study examined, for the first time, the impacts of pretreatment steps, including filtration and petroleum-coke adsorption, on ozonation requirements and performance. The effect of the initial OSPW pH on treatment performance, and the evolution of ozonation and its impact on OSPW toxicity and biodegradability were also examined. The degradation of more than 76% of total acid-extractable organics was achieved using a semi-batch ozonation system at a utilized ozone dose of 150 mg/L. With a utilized ozone dose of 100 mg/L, the treated OSPW became more biodegradable and showed no toxicity towards Vibrio fischeri. Changes in the NA profiles in terms of carbon number and number of rings were observed after ozonation. The filtration of the OSPW did not improve the ozonation performance. Petroleum-coke adsorption was found to be effective in reducing total acid-extractable organics by a 91%, NA content by an 84%, and OSPW toxicity from 4.3 to 1.1 toxicity units. The results of this study indicate that the combination of petroleum-coke adsorption and ozonation is a promising treatment approach to treat OSPW.

  3. The extraction of bitumen from western oil sands: Volume 1. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.


    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains an executive summary and reports for five of these projects. 137 figs., 49 tabs.

  4. The extraction of bitumen from western oil sands: Volume 2. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.


    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains reports on nine of these projects, references, and a bibliography. 351 refs., 192 figs., 65 tabs.


    Directory of Open Access Journals (Sweden)

    Elisabeta Mihaela CIORTEA


    Full Text Available Purpose of the paper is to analyze the Petri net model, to describe the transport process, part of amanufacturing system and its dynamics.A hibrid Petri net model is built to describe the dinamics of the transport process manufacturingsystem. Mathematical formulation of the dinamycs processes a detailed description. Based on this model, theanalysis of the transport process is designed to be able to execute a production plan and resolve any conflictsthat may arise in the system.In the analysis dinamics known two stages: in the continuous variables are discrete hybrid system in thehibrid discrete variables are used as safety control with very well defined responsibilities.In terms of the chosen model, analyze transport process is designed to help execute a production planand resolve conflicts that may arise in the process, and then the ones in the system

  6. Conditions and processes affecting radionuclide transport (United States)

    Simmons, Ardyth M.; Neymark, Leonid A.


    Characteristics of host rocks, secondary minerals, and fluids would affect the transport of radionuclides from a previously proposed repository at Yucca Mountain, Nevada. Minerals in the Yucca Mountain tuffs that are important for retarding radionuclides include clinoptilolite and mordenite (zeolites), clay minerals, and iron and manganese oxides and hydroxides. Water compositions along flow paths beneath Yucca Mountain are controlled by dissolution reactions, silica and calcite precipitation, and ion-exchange reactions. Radionuclide concentrations along flow paths from a repository could be limited by (1) low waste-form dissolution rates, (2) low radionuclide solubility, and (3) radionuclide sorption onto geological media.


    Directory of Open Access Journals (Sweden)

    L. V. Martsenyuk


    Full Text Available Purpose. For Ukraine as for a post-socialist state there is an objective need of reforming on railway transport. In order to meet the requirements of consumers both within the country and outside of it, it is necessary to solve transport problems in time and to introduce new technologies, without lagging behind the developed European states. The purpose of this article is identification of problems in the process of freight transportations and development of ways of their overcoming, formation of the principles of economic efficiency increase for the use of freight cars using the improvement of management mechanism of freight transportations in the conditions of reforming. Methodology. Methods of strategic planning, system approach for research on improvement of the management mechanism of freight transportations, as well as the organizational-administrative method for structure of management construction were used in this research. Findings. Authors have explored the problems arising in the process of transportation of goods and measures, which will increase the efficiency of goods transportation. Advanced mechanism of freight transportation management for its application in the conditions of the railway transport reforming was developed. It is based on management centralization. Originality. The major factors, which slow down process of cargo transportations, are investigated in the article. The principles of management mechanism improvement of freight transportations are stated. They are based on association of commercial and car-repair activity of depots. All this will allow reducing considerably a car turn by decrease in duration of idle times on railway transport, increasing the speed of freight delivery and cutting down a transport component in the price of delivered production. Practical value. The offered measures will improve the efficiency of rolling stock use and increase cargo volumes turnover, promote links of Ukraine with


    Directory of Open Access Journals (Sweden)

    D. Dimitrov


    Full Text Available

    ENGLISH ABSTRACT: This paper discusses the results obtained from studies on different Rapid Tooling process chains in order to improve the design and manufacture of foundry equipment that is used for sand casting of prototypes in final material. These prototypes are intended for functional and pre-production tests of vehicles. The Three Dimensional Printing process is used as core technology. Subsequently, while considering aspects such as time, cost, quality (accuracy and surface roughness, and tool life, a framework is presented for the evaluation and selection of the most suitable process chain in accordance with specific requirements. This research builds on an in-depth characterisation of the accuracy and repeatability of a 3D printing process.

    AFRIKAANSE OPSOMMING: Hierdie artikel bespreek die resultate wat verkry is tydens studies op verskillende Snel-Gereedskapvervaardigingproseskettings wat ondersoek is teneinde die ontwerp en vervaardiging van sandgietgereedskap, om prototipes in finale materiaal te vervaardig, te verbeter. Die prototipes is bestem vir gebruik in funksionele- en voorproduksietoetse van voertuie. Die sogenaamde Driedimensionele Drukproses (3DP is as kerntegnologie aangewend. Gevolglik, na oorweging van aspekte soos tyd, koste, kwaliteit (akkuraatheid en oppervlakafwerking, en gereedskapleeftyd, is ’n raamwerk ontwikkel vir die evaluering en seleksie van die mees geskikte prosesketting met inagname van spesifieke vereistes. Hierdie navorsing bou op ’n diepgaande karakterisering van die akkuraatheids- en herhaalbaarheidsvermoë van ’n 3D drukproses.

  9. Role of astrocytic transport processes in glutamatergic and GABAergic neurotransmission

    DEFF Research Database (Denmark)

    Schousboe, A; Sarup, A; Bak, L K


    The fine tuning of both glutamatergic and GABAergic neurotransmission is to a large extent dependent upon optimal function of astrocytic transport processes. Thus, glutamate transport in astrocytes is mandatory to maintain extrasynaptic glutamate levels sufficiently low to prevent excitotoxic...... neuronal damage. In GABA synapses hyperactivity of astroglial GABA uptake may lead to diminished GABAergic inhibitory activity resulting in seizures. As a consequence of this the expression and functional activity of astrocytic glutamate and GABA transport is regulated in a number of ways...

  10. Intrinsic and extrinsic negative regulators of nuclear protein transport processes


    Sekimoto, Toshihiro; Yoneda, Yoshihiro


    The nuclear–cytoplasmic protein transport is a critical process in cellular events. The identification of transport signals (nuclear localization signal and nuclear export signal) and their receptors has facilitated our understanding of this expanding field. Nuclear transport must be appropriately regulated to deliver proteins through the nuclear pore when their functions are required in the nucleus, and to export them into the cytoplasm when they are not needed in the nucleus. Altered nuclea...

  11. Mass spectral characterisation of a polar, esterified fraction of an organic extract of an oil sands process water. (United States)

    Rowland, S J; Pereira, A S; Martin, J W; Scarlett, A G; West, C E; Lengger, S K; Wilde, M J; Pureveen, J; Tegelaar, E W; Frank, R A; Hewitt, L M


    Characterising complex mixtures of organic compounds in polar fractions of heavy petroleum is challenging, but is important for pollution studies and for exploration and production geochemistry. Oil sands process-affected water (OSPW) stored in large tailings ponds by Canadian oil sands industries contains such mixtures. A polar OSPW fraction was obtained by silver ion solid-phase extraction with methanol elution. This was examined by numerous methods, including electrospray ionisation (ESI) Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) and ultra-high-pressure liquid chromatography (uHPLC)/Orbitrap MS, in multiple ionisation and MS/MS modes. Compounds were also synthesised for comparison. The major ESI ionisable compounds detected (+ion mode) were C15-28 SO3 species with 3-7 double bond equivalents (DBE) and C27-28 SO5 species with 5 DBE. ESI-MS/MS collision-induced losses were due to water, methanol, water plus methanol and water plus methyl formate, typical of methyl esters of hydroxy acids. Once the fraction was re-saponified, species originally detected by positive ion MS, could be detected only by negative ion MS, consistent with their assignment as sulphur-containing hydroxy carboxylic acids. The free acid of a keto dibenzothiophene alkanoic acid was added to an unesterified acid extract of OSPW in known concentrations as a putative internal standard, but attempted quantification in this way proved unreliable. The results suggest the more polar acidic organic SO3 constituents of OSPW include C15-28  S-containing, alicyclic and aromatic hydroxy carboxylic acids. SO5 species are possibly sulphone analogues of these. The origin of such compounds is probably via further biotransformation (hydroxylation) of the related S-containing carboxylic acids identified previously in a less polar OSPW fraction. The environmental risks, corrosivity and oil flow assurance effects should be easier to assess, given that partial structures are now known

  12. [Crust development and subsurface soil properties under dominant shrubs in the process of dune restoration, Horqin Sand Land]. (United States)

    Guo, Yi-rui; Zhao, Ha-lin; Zuo, Xiao-an; Li, Yu-Lin; Huang, Yin-xin; Wang, Shao-kun


    Soil crust is a common and widespread phenomenon in desert areas all over the world due to its extraordinary ability to survive desiccation and extreme temperatures, high pH and salinity. Despite its unassuming appearance, biological soil crusts play a significant role in desert ecosystems, including involvement in the process of formation, stability and fertility of soil, preventing soil erosion by water or wind, increasing the possibility of vascular plant colonization, and being responsible for the stabilization of sand dunes. This study taking Horqin Sand Land as research region, by field sampling, crust and topsoil (0-2.5 cm and 2.5-5 cm under crust) samples in different dune habitats and shrub communities were collected, and their physicochemical properties were analyzed, including particle size distribution, bulk density, total nutrients and available nutrients, pH, EC and CaCO3 content. The result revealed that Artemisia halodendron in semi-mobile dune, Caragana microphylla in semi-fix dune, Artemisia frigida in fix dune and Salix microstachya in interdunal lowland were respectively developed physical soil crust, algae crust, lichen crust and moss crust. Crust thickness, hardness, water content, fine fraction, total and available nutrients gradually increased by semi-mobile dune dune dune dune habitats, and by physical soil crust dune to interdunal lowland. As to each crust, the parameters of 0-2.5 cm subsurface soil layer were higher than that in 2.5-5 cm soil layer. The result also showed that the fine fraction and nutrient content of moss crust under Salix microstachya in interdunal lowland were higher than others, so did the 0-5 cm subsurface soil under it.

  13. Ionic transport processes in electrochemistry and membrane science

    CERN Document Server

    Kontturi, Kyösti; Manzanares, José A


    Modelling of heterogeneous processes, such as electrochemical reactions, extraction or ion-exchange, usually requires solving the transport problem associated to the process. Since the processes at the phase boundary are described by scalar quantities and transport quantities are vectors or tensors, coupling of them can take place only via conservation of mass, charge or momentum. In this book, transport of ionic species is addressed in a versatile manner, emphasizing the mutualcoupling of fluxes in particular. Treatment is based on the formalism of irreversible thermodynamics, i.e. on linear

  14. Evaluation of the performance of the cross-flow air classifier in manufactured sand processing via CFD-DEM simulations (United States)

    Petit, H. A.; Irassar, E. F.; Barbosa, M. R.


    Manufactured sands are particulate materials obtained as by product of rock crushing. Particle sizes in the sand can be as high as 6 mm and as low as a few microns. The concrete industry has been increasingly using these sands as fine aggregates to replace natural sands. The main shortcoming is the excess of particles smaller than element modelling (DEM) were used for the assessment. Results show that the correct classification set up improves the size distribution of the raw materials. The cross-flow air classification is found to be influenced by the particle size distribution and the turbulence inside the chamber. The classifier can be re-designed to work at low inlet velocities to produce manufactured sand for the concrete industry.

  15. Turbine Fuels from Tar Sands Bitumen and Heavy Oil. Phase I. Preliminary Process Analysis. (United States)


    Process Analysis A. F. Talbot. V. Elanchenny, L. H. Finkel, A. Macris and 3. P. Schwedock Sun Tech, Inc., A Subsidiary of Sun Co. P. 0. Box 1135 Marcus Hook...investigation be carried out in three discrete phases, as described below: Phase I - Preliminary process analysis includes an eval- uation of the potential of

  16. Divide and conquer: processive transport enables multidrug transporters to tackle challenging drugs. (United States)

    Fluman, Nir; Bibi, Eitan


    Multidrug transporters are membrane proteins that catalyze efflux of antibiotics and other toxic compounds from cells, thereby conferring drug resistance on various organisms. Unlike most solute transporters that transport a single type of compound or similar analogues, multidrug transporters are extremely promiscuous. They transport a broad spectrum of dissimilar drugs and represent a serious obstacle to antimicrobial or anticancer chemotherapy. Many challenging aspects of multidrug transporters, which are unique, have been studied in detail, including their ability to interact with chemically unrelated drugs, and how they utilize energy to drive efflux of compounds that are not only structurally but electrically different. A new and surprising dimension of the promiscuous nature of multidrug transporters has been described recently: they can move long molecules through the membrane in a processive manner.

  17. Divide and conquer: processive transport enables multidrug transporters to tackle challenging drugs

    Directory of Open Access Journals (Sweden)

    Nir Fluman


    Full Text Available Multidrug transporters are membrane proteins that catalyze efflux of antibiotics and other toxic compounds from cells, thereby conferring drug resistance on various organisms. Unlike most solute transporters that transport a single type of compound or similar analogues, multidrug transporters are extremely promiscuous. They transport a broad spectrum of dissimilar drugs and represent a serious obstacle to antimicrobial or anticancer chemotherapy. Many challenging aspects of multidrug transporters, which are unique, have been studied in detail, including their ability to interact with chemically unrelated drugs, and how they utilize energy to drive efflux of compounds that are not only structurally but electrically different. A new and surprising dimension of the promiscuous nature of multidrug transporters has been described recently: they can move long molecules through the membrane in a processive manner.

  18. Treatment of oil sands process-affected water using moving bed biofilm reactors: With and without ozone pretreatment. (United States)

    Shi, Yijing; Huang, Chunkai; Rocha, Ketley Costa; El-Din, Mohamed Gamal; Liu, Yang


    Two moving bed biofilm reactors (MBBRs) were operated to treat raw (untreated) and 30 mg/L ozone-treated oil sands process-affected water (OSPW). After 210 days, the MBBR process showed 18.3% of acid-extractable fraction (AEF) and 34.8% of naphthenic acids (NAs) removal, while the ozonation combined MBBR process showed higher removal of AEF (41.0%) and NAs (78.8%). Biodegradation of raw and ozone treated OSPW showed similar performance. UPLC/HRMS analysis showed a highest NAs removal efficiency with a carbon number of 14 and a -Z number of 4. Confocal laser scanning microscopy (CLSM) showed thicker biofilms in the raw OSPW MBBR (97 ± 5 μm) than in the ozonated OSPW MBBR (71 ± 12 μm). Quantitative polymerase chain reaction (q-PCR) results showed higher abundance of gene copies of total bacteria and nitrogen removal relevant bacteria in the ozonated OSPW MBBR, but no significant difference was found. MiSeq sequencing showed Proteobacteria, Nitrospirae, and Acidobacteria were dominant.

  19. Extracellular Electron Transport Coupling Biogeochemical Processes Centimeters

    DEFF Research Database (Denmark)

    Risgaard-Petersen, Nils; Fossing, Henrik; Christensen, Peter Bondo


    confirmed the depth range of the electric communication and indicated donation of electrons directly from organotrophic bacteria. The separation of oxidation and reduction processes created steep pH gradients eventually causing carbonate precipitation at the surface. The results indicate that electron...... of the oxygen uptake in laboratory incubations of initially homogenized and stabilized sediment. Using microsensors and process rate measurements we further investigated the effect of the electric currents on sediment biogeochemistry. Dissolved sulfide readily donated electrons to the networks and could...

  20. The impact of transport processes standardization on supply chain efficiency

    Directory of Open Access Journals (Sweden)

    Maciej Stajniak


    Full Text Available Background: During continuous market competition, focusing on the customer service level, lead times and supply flexibility is very important to analyze the efficiency of logistics processes. Analysis of supply chain efficiency is one of the fundamental elements of controlling analysis. Transport processes are a key process that provides physical material flow through the supply chain. Therefore, in this article Authors focus attention on the transport processes efficiency. Methods: The research carried out in the second half of 2014 year, in 210 enterprises of the Wielkopolska Region. Observations and business practice studies conducted by the authors, demonstrate a significant impact of standardization processes on supply chain efficiency. Based on the research results, have been developed standard processes that have been assessed as being necessary to standardize in business practice. Results: Based on these research results and observations, authors have developed standards for transport processes by BPMN notation. BPMN allows authors to conduct multivariate simulation of these processes in further stages of research. Conclusions: Developed standards are the initial stage of research conducted by Authors in the assessment of transport processes efficiency. Further research direction is to analyze the use efficiency of transport processes standards in business practice and their impact on the effectiveness of the entire supply chain.

  1. Shelter Index and a simple wind speed parameter to characterize vegetation control of sand transport threshold and Flu (United States)

    Gillies, J. A.; Nield, J. M.; Nickling, W. G.; Furtak-Cole, E.


    Wind erosion and dust emissions occur in many dryland environments from a range of surfaces with different types and amounts of vegetation. Understanding how vegetation modulates these processes remains a research challenge. Here we present results from a study that examines the relationship between an index of shelter (SI=distance from a point to the nearest upwind vegetation/vegetation height) and particle threshold expressed as the ratio of wind speed measured at 0.45 times the mean plant height divided by the wind speed at 17 m when saltation commences, and saltation flux. The results are used to evaluate SI as a parameter to characterize the influence of vegetation on local winds and sediment transport conditions. Wind speed, wind direction, saltation activity and point saltation flux were measured at 35 locations in defined test areas (~13,000 m2) in two vegetation communities: mature streets of mesquite covered nebkhas and incipient nebkhas dominated by low mesquite plants. Measurement positions represent the most open areas, and hence those places most susceptible to wind erosion among the vegetation elements. Shelter index was calculated for each measurement position for each 10° wind direction bin using digital elevation models for each site acquired using terrestrial laser scanning. SI can show the susceptibility to wind erosion at different time scales, i.e., event, seasonal, or annual, but in a supply-limited system it can fail to define actual flux amounts due to a lack of knowledge of the distribution of sediment across the surface of interest with respect to the patterns of SI.

  2. Processes of Salt Transport in Disturbed Streams (United States)

    Chitrakar, S.; Miller, S. N.; Caffrey, P. A.; Stern, J.


    The extraction of coal bed methane natural gas involves removal of large amount of ground/Coal Bed Methane (CBM) water which is commonly discharged to surface-water drainages or constructed reservoirs. The extraction of large volume of water and its disposal on soil surface not only lowers the water table but also potentially accelerate soil erosions, contaminate surface water resources, and alter the natural flows. Due to the difference in quality and quantity between the surface discharge and disposed CBM water, this management strategy potentially poses threats to quality of surface water and soil. CBM discharge water typically contains high concentrations of sodium and low concentrations of calcium and magnesium, resulting in high sodium adsorption ratio (SAR). Similarly, it also contains high concentration of other ions which could results in increasing salt concentrations. Our study area is in the Atlantic Rim development area of the Muddy Creek, SE of Wyoming, a tributary to Colorado River, where significant development of CBM wells is ongoing. Since Muddy Creek is part of the Upper Colorado River, the greatest concern is its potential to contribute to surface water quality (primarily salinity) impairment downstream. However, very few studies have made efforts to assess the water quality in this particular region. The alteration of stream water quality in this region is still not fully understood if it due to CBM water discharge or via soil/water interactions, erosion, and sediment transport. Efforts are being made to identify crucial water quality parameters such as SAR and EC along with the quantification of solute/salt loadings at both CBM discharge fed streams and natural streams at different seasons to distinguish effect of CBM discharge on water quality. We have been continuously monitoring water quality on monthly basis and discharge measurement on daily basis at sampling sites that are placed to discriminate CBM fed streams and natural streams. The

  3. 试论砂光质量、效率和成本%Quality, Productivity and Cost in Wood-based Panel Sanding Process

    Institute of Scientific and Technical Information of China (English)



    Thorough analysis and discussion are made on several hot topics of common interest to wood-based panel manufacturers,including 1 )how to detennine internal control standard for sanding quality? 2)how to assess the sanding parameters through mathematical calculation? 3)how to reduce the cost in sanding process?%就人造板生产企业当前所关注的几个热点问题,包括:如何确定砂光质量的内控标准、如何利用计算法来决定砂光工艺参数和如何降低砂光成本等作了较深入的分析和讨论。

  4. Extracellular Electron Transport Coupling Biogeochemical Processes Centimeters

    DEFF Research Database (Denmark)

    Risgaard-Petersen, Nils; Fossing, Henrik; Christensen, Peter Bondo


    of the oxygen uptake in laboratory incubations of initially homogenized and stabilized sediment. Using microsensors and process rate measurements we further investigated the effect of the electric currents on sediment biogeochemistry. Dissolved sulfide readily donated electrons to the networks and could...... confirmed the depth range of the electric communication and indicated donation of electrons directly from organotrophic bacteria. The separation of oxidation and reduction processes created steep pH gradients eventually causing carbonate precipitation at the surface. The results indicate that electron...... exchanging organisms have major biogeochemical importance as they allow widely separated electron donors and acceptors to react with one another....

  5. Interfacial fluid dynamics and transport processes

    CERN Document Server

    Schwabe, Dietrich


    The present set of lectures and tutorial reviews deals with various topical aspects related to instabilities of interfacial processes and driven flows from both the theoretical and experimental point of views. New research has been spurred by the many demands for applications in material sciences (melting, solidification, electro deposition), biomedical engineering and processing in microgravity environments. This book is intended as both a modern source of reference for researchers in the field as well as an introduction to postgraduate students and non-specialists from related areas.

  6. Oil shale, tar sand, coal research advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, October--December 1992

    Energy Technology Data Exchange (ETDEWEB)

    Speight, J.G.


    Accomplishments for the past quarter are presented for the following five tasks: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale research covers oil shale process studies. Tar sand research is on process development of Recycle Oil Pyrolysis and Extraction (ROPE) Process. Coal research covers: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes: advanced process concepts;advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; PGI demonstration project; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; flow-loop testing of double-wall pipe for thermal applications; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; NMR analysis of samples from the ocean drilling program; in situ treatment of manufactured gas plant contaminated soils demonstration program; and solid state NMR analysis of naturally and artificially matured kerogens.

  7. Damage costs due to bedload transport processes in Switzerland (United States)

    Badoux, A.; Andres, N.; Turowski, J. M.


    In Alpine regions, floods are often associated with erosion, transport and deposition of coarse sediment along the streams. These processes are related to bedload transport and pose a hazard in addition to the elevated water discharge. However, it is unclear to what extent they contribute to total damage caused by natural hazards. Using the Swiss flood and landslide damage database - which collects financial damage data of naturally triggered floods, debris flows and landslides - we estimated the contribution of fluvial bedload transport processes to total damage costs in Switzerland. For each database entry an upper and lower limit of financial losses caused by or related to bedload transport processes was estimated, and the quality of the estimate was judged. When compared to total damage, the fraction of bedload transport damage in the 40 yr study period lies between 0.32 and 0.37. However, this value is highly variable for individual years (from 0.02 to 0.72). Bedload transport processes have induced cumulative financial losses between CHF 4.3 and 5.1 billion. Spatial analysis revealed a considerable heterogeneous distribution with largest damage for mountainous regions. The analysis of the seasonal distribution shows that more than 75 % of the bedload damage costs occurs in summer (June-August), and ∼ 23% in autumn (September-November). With roughly 56 %, by far most of the damage has been registered in August. Bedload transport processes are presently still inadequately understood, and the predictive quality of common bedload equations is often poor. Our analysis demonstrates the importance of bedload transport as a natural hazard and financial source of risk, and thus the need for future structured research on transport processes in steep streams.

  8. Quantitative analysis of flow processes in a sand using synchrotron-based X-ray microtomography

    DEFF Research Database (Denmark)

    Wildenschild, Dorthe; Hopmans, J.W.; Rivers, M.L.


    been of a mostly qualitative nature and no experiments have been presented in the existing literature where a truly quantitative approach to investigating the multiphase flow process has been taken, including a thorough image-processing scheme. The tomographic images presented here show, both...... on observed dynamic effects in the measured pressure-saturation curves; a significantly higher residual and higher capillary pressures were found when the sample was drained fast using a high air-phase pressure. Prior work applying the X-ray microtomography technique to pore-scale multiphase flow problems has...

  9. Intelligent Transportation Control based on Proactive Complex Event Processing

    Directory of Open Access Journals (Sweden)

    Wang Yongheng


    Full Text Available Complex Event Processing (CEP has become the key part of Internet of Things (IoT. Proactive CEP can predict future system states and execute some actions to avoid unwanted states which brings new hope to intelligent transportation control. In this paper, we propose a proactive CEP architecture and method for intelligent transportation control. Based on basic CEP technology and predictive analytic technology, a networked distributed Markov decision processes model with predicting states is proposed as sequential decision model. A Q-learning method is proposed for this model. The experimental evaluations show that this method works well when used to control congestion in in intelligent transportation systems.

  10. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, January--March 1993

    Energy Technology Data Exchange (ETDEWEB)


    Accomplishments for the past quarter are briefly described for the following areas of research: oil shale; tar sand; coal; advanced exploratory process technology; and jointly sponsored research. Oil shale and tar sand researches cover processing studies. Coal research includes: coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology covers: advanced process concepts; advanced mitigation concepts; and oil and gas technology. Jointly sponsored research includes: organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sub 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin tight gas sands; characterization of petroleum residue; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of naturally and artificially matured kerogens; and development of an effective method for the clean-up of natural gas.

  11. Thermal stress analysis method considering geometric effect of risers in sand mold casting process

    Institute of Scientific and Technical Information of China (English)

    S Y Kwak; HY Hwang; C Cho


    Solidification and fluid flow analysis using computer simulation is a current common practice. There is also a high demand for thermal stress analysis in the casting process because casting engineers want to control the defects related to thermal stresses, such as large deformation and crack generation during casting. The riser system is an essential part of preventing the shrinkage defects in the casting process, and it has a great influence on thermal phenomena. The analysis domain is dramatical y expanded by attaching the riser system to a casting product due to its large volume, and it makes FEM mesh generation difficult. However, it is difficult to study and solve the above proposed problem caused by riser system using traditional analysis methods which use single numerical method such as FEM or FDM. In this paper, some research information is presented on the effects of the riser system on thermal stress analysis using a FDM/FEM hybrid method in the casting process simulation. The results show the optimal conditions for stress analysis of the riser model in order to save computation time and memory resources.

  12. Thermodynamically coupled mass transport processes in a saturated clay

    Energy Technology Data Exchange (ETDEWEB)

    Carnahan, C.L.


    Gradients of temperature, pressure, and fluid composition in saturated clays give rise to coupled transport processes (thermal and chemical osmosis, thermal diffusion, ultrafiltration) in addition to the direct processes (advection and diffusion). One-dimensional transport of water and a solute in a saturated clay subjected to mild gradients of temperature and pressure was simulated numerically. When full coupling was accounted for, volume flux (specific discharge) was controlled by thermal osmosis and chemical osmosis. The two coupled fluxes were oppositely directed, producing a point of stagnation within the clay column. Solute flows were dominated by diffusion, chemical osmosis, and thermal osmosis. Chemical osmosis produced a significant flux of solute directed against the gradient of solute concentration; this effect reduced solute concentrations relative to the case without coupling. Predictions of mass transport in clays at nuclear waste repositories could be significantly in error if coupled transport processes are not accounted for. 14 references, 8 figures, 1 table.

  13. Characteristic of Core Manufacturing Process with Use of Sand, Bonded by Ecological Friendly Nonorganic Binders

    Directory of Open Access Journals (Sweden)

    A. Fedoryszyn


    Full Text Available Mechanization of the process of core making with the use of inorganic and organic binders is based, almost solely, on core blowing machines. Presently the core blowing machines are equipped with tools and devices that allow for application of different technologies of core making. Cold-box, hot-box and warm-air technologies require that core blowing machines shall be additionally equipped with either core-box pre-heating system or gas purging and neutralization system, or hot air purging systems.

  14. Transport Induced by Mean-Eddy Interaction: II. Analysis of Transport Processes

    CERN Document Server

    Ide, Kayo


    We present a framework for the analysis of transport processes resulting from the mean-eddy interaction in a flow. The framework is based on the {\\bf T}ransport {\\bf I}nduced by the {\\bf M}ean-{\\bf E}ddy {\\bf I}nteraction (TIME) method presented in a companion paper \\cite{ide_wiggins_pd06a}. The TIME method estimates the (Lagrangian) transport across stationary (Eulerian) boundaries defined by chosen streamlines of the mean flow. Our framework proceeds after first carrying out a sequence of preparatory steps that link the flow dynamics to the transport processes. This includes the construction of the so-called "instantaneous flux" as the Hovm\\"{o}ller diagram. Transport processes are studied by linking the signals of the instantaneous flux field to the dynamical variability of the flow. This linkage also reveals how the variability of the flow contributes to the transport. The spatio-temporal analysis of the flux diagram can be used to assess the efficiency of the variability in transport processes. We apply ...

  15. Effects of kaolinite colloids on Cd²⁺ transport through saturated sand under varying ionic strength conditions: Column experiments and modeling approaches. (United States)

    Wikiniyadhanee, Rakkreat; Chotpantarat, Srilert; Ong, Say Kee


    Column experiments were performed under various ionic strengths (0.0-0.9 mM) using 10 mg L(-1) of Cd(2+) without kaolinite colloids and 10 mg L(-1) Cd(2+) mixed with 100 mg L(-1) kaolinite colloids. The nonequilibrium two-site model (TSM) described the behavior of both Cd(2+) transport and Cd(2+) co-transported with kaolinite colloids better than the equilibrium model (CD(eq)) (R(2)=0.978-0.996). The results showed that an increase in ionic strength negatively impacted the retardation factors (R) of both Cd(2+) and Cd(2+) mixed with kaolinite colloids. The presence of kaolinite colloids increased the retardation factors of Cd(2+) from 7.23 to 7.89, 6.76 to 6.61 and 3.79 to 6.99 for ionic strengths of 0.225, 0.45 and 0.9 mM, respectively. On the other hand, the presence of kaolinite colloids decreased the retardation factor of Cd(2+) from 8.13 to 7.83 for ionic strength of 0.0 mM. The fraction of instantaneous sorption sites (f) parameters, kinetic constant for sorption sites (α) and Freundlich constant (K(f)) were estimated from HYDRUS-1D of TSM for Cd(2+) transport. The fraction of instantaneous sorption sites was found to increase for an increase in ionic strength. K(f) values of Cd(2+) transport without kaolinite colloids for 0.0, 0.225 and 0.45 mM were found to be higher than those of Cd(2+) transport with kaolinite colloids, except for ionic strength of 0.9 mM. Hence, the presence of kaolinite colloids probably retarded the mobility of Cd(2+) in porous media for higher ionic strengths. Furthermore, retardation factors and K(f) values of both Cd(2+) transport and Cd(2+) co-transport were shown to decrease when ionic strength increased. Interestingly, according to TSM, the fraction of instantaneous sorption sites tends to increase for an increase in ionic strength, which imply that the mechanism of Cd(2+) sorption onto quartz sand can be better described using equilibrium sorption rather than nonequilibrium sorption for an increase in ionic strength. Copyright

  16. Modeling and sensitivity analysis on the transport of aluminum oxide nanoparticles in saturated sand: effects of ionic strength, flow rate, and nanoparticle concentration. (United States)

    Rahman, Tanzina; Millwater, Harry; Shipley, Heather J


    Aluminum oxide nanoparticles have been widely used in various consumer products and there are growing concerns regarding their exposure in the environment. This study deals with the modeling, sensitivity analysis and uncertainty quantification of one-dimensional transport of nano-sized (~82 nm) aluminum oxide particles in saturated sand. The transport of aluminum oxide nanoparticles was modeled using a two-kinetic-site model with a blocking function. The modeling was done at different ionic strengths, flow rates, and nanoparticle concentrations. The two sites representing fast and slow attachments along with a blocking term yielded good agreement with the experimental results from the column studies of aluminum oxide nanoparticles. The same model was used to simulate breakthrough curves under different conditions using experimental data and calculated 95% confidence bounds of the generated breakthroughs. The sensitivity analysis results showed that slow attachment was the most sensitive parameter for high influent concentrations (e.g. 150 mg/L Al2O3) and the maximum solid phase retention capacity (related to blocking function) was the most sensitive parameter for low concentrations (e.g. 50 mg/L Al2O3).

  17. Biostimulation of Oil Sands Process-Affected Water with Phosphate Yields Removal of Sulfur-Containing Organics and Detoxification. (United States)

    Quesnel, Dean M; Oldenburg, Thomas B P; Larter, Stephen R; Gieg, Lisa M; Chua, Gordon


    The ability to mitigate toxicity of oil sands process-affected water (OSPW) for return into the environment is an important issue for effective tailings management in Alberta, Canada. OSPW toxicity has been linked to classical naphthenic acids (NAs), but the toxic contribution of other acid-extractable organics (AEOs) remains unknown. Here, we examine the potential for in situ bioremediation of OSPW AEOs by indigenous algae. Phosphate biostimulation was performed in OSPW to promote the growth of indigenous photosynthetic microorganisms and subsequent toxicity and chemical changes were determined. After 12 weeks, the AEO fraction of phosphate-biostimulated OSPW was significantly less toxic to the fission yeast Schizosaccharomyces pombe than unstimulated OSPW. Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) analysis of the AEO fraction in phosphate-biostimulated OSPW showed decreased levels of SO3 class compounds, including a subset that may represent linear arylsulfonates. A screen with S. pombe transcription factor mutant strains for growth sensitivity to the AEO fraction or sodium dodecylbenzenesulfonate revealed a mode of toxic action consistent with oxidative stress and detrimental effects on cellular membranes. These findings demonstrate a potential algal-based in situ bioremediation strategy for OSPW AEOs and uncover a link between toxicity and AEOs other than classical NAs.

  18. Assessing spatial and temporal variability of acid-extractable organics in oil sands process-affected waters. (United States)

    Frank, Richard A; Milestone, Craig B; Rowland, Steve J; Headley, John V; Kavanagh, Richard J; Lengger, Sabine K; Scarlett, Alan G; West, Charles E; Peru, Kerry M; Hewitt, L Mark


    The acid-extractable organic compounds (AEOs), including naphthenic acids (NAs), present within oil sands process-affected water (OSPW) receive great attention due to their known toxicity. While recent progress in advanced separation and analytical methodologies for AEOs has improved our understanding of the composition of these mixtures, little is known regarding any variability (i.e., spatial, temporal) inherent within, or between, tailings ponds. In this study, 5 samples were collected from the same location of one tailings pond over a 2-week period. In addition, 5 samples were collected simultaneously from different locations within a tailings pond from a different mine site, as well as its associated recycling pond. In both cases, the AEOs were analyzed using SFS, ESI-MS, HRMS, GC×GC-ToF/MS, and GC- & LC-QToF/MS (GC analyses following conversion to methyl esters). Principal component analysis of HRMS data was able to distinguish the ponds from each other, while data from GC×GC-ToF/MS, and LC- and GC-QToF/MS were used to differentiate samples from within the temporal and spatial sample sets, with the greater variability associated with the latter. Spatial differences could be attributed to pond dynamics, including differences in inputs of tailings and surface run-off. Application of novel chemometric data analyses of unknown compounds detected by LC- and GC-QToF/MS allowed further differentiation of samples both within and between data sets, providing an innovative approach for future fingerprinting studies.

  19. Sintering as a process of transport of activated volume

    Directory of Open Access Journals (Sweden)

    Nikolić Nataša S.


    Full Text Available Starting with the fact that sintering is the consequence of the process of transport of activated volume, it has been shown how the kinetics of the sintering process can be defined. The activated volume was in principle defined as a parameter which describes a system’s deffectivity on an atomic level.

  20. Particle Tracking Model and Abstraction of Transport Processes

    Energy Technology Data Exchange (ETDEWEB)

    B. Robinson


    The purpose of the transport methodology and component analysis is to provide the numerical methods for simulating radionuclide transport and model setup for transport in the unsaturated zone (UZ) site-scale model. The particle-tracking method of simulating radionuclide transport is incorporated into the FEHM computer code and the resulting changes in the FEHM code are to be submitted to the software configuration management system. This Analysis and Model Report (AMR) outlines the assumptions, design, and testing of a model for calculating radionuclide transport in the unsaturated zone at Yucca Mountain. In addition, methods for determining colloid-facilitated transport parameters are outlined for use in the Total System Performance Assessment (TSPA) analyses. Concurrently, process-level flow model calculations are being carrier out in a PMR for the unsaturated zone. The computer code TOUGH2 is being used to generate three-dimensional, dual-permeability flow fields, that are supplied to the Performance Assessment group for subsequent transport simulations. These flow fields are converted to input files compatible with the FEHM code, which for this application simulates radionuclide transport using the particle-tracking algorithm outlined in this AMR. Therefore, this AMR establishes the numerical method and demonstrates the use of the model, but the specific breakthrough curves presented do not necessarily represent the behavior of the Yucca Mountain unsaturated zone.




    The evaluation of transport projects has become increasingly complex. Different aspects have to be taken into account and the consequences of the problems are usually far reaching and the different policy alternatives are numerous and difficult to predict. Several pressure or action groups have also emerged causing an even more complex decision making process. The use of multi criteria analysis for the evaluation of transport projects has increased due to this increasing complexity of the pro...

  2. Quantum Transport in Solids: Two-Electron Processes. (United States)


    The central objective of this research program has been to study theoretically the underlying principles of quantum transport in solids. The area of...research investigated has emphasized the understanding of two electron processes in quantum transport . The problems have been treated analytically to...the extent possible through the use of dynamical localized Wannier functions. These results have been and are being incorporated in a full quantum

  3. Triaxial tests in Fontainebleau sand

    DEFF Research Database (Denmark)

    Latini, Chiara; Zania, Varvara


    The purpose of this internal report is to examine the influence of relative density on the strength and deformation characteristics of Fontainebleau sand. Compression triaxial tests were performed on saturated sand samples with different densities and initial confining pressure. Note that the tes......The purpose of this internal report is to examine the influence of relative density on the strength and deformation characteristics of Fontainebleau sand. Compression triaxial tests were performed on saturated sand samples with different densities and initial confining pressure. Note...... that the testing procedure and the data processing were carried out according to the specifications of ETCS-F1.97....

  4. The extraction of bitumen from western oil sands. Quarterly report, July--September, 1993

    Energy Technology Data Exchange (ETDEWEB)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.


    This report cites task number followed by a brief statement of each task and the action taken this quarter. The tasks are: NEPA environmental information statement; coupled fluidized-bed bitumen recovery and coked sand combustion; water-based recovery of bitumen; rotary kiln process for recovery of bitumen and combustion of coke sand; recovery of bitumen from oil sands using fluidized bed reactors and combustion of spent sands in transport reactors; recovery of bitumen from oil sand and upgrading of bitumen by solvent extraction; catalytic and thermal upgrading of bitumens and bitumen-derived liquids; evaluation of Utah`s major oil sand deposits for the production of asphalt, high energy jet fuels, and other specialty products; development of mathematical models for bitumen recovery and processing; completion of the cost estimation study of the pilot plant restoration; development studies of equipment for three-product gravity separation of bitumen and sand; development studies of disposal of sand by conveying or pumping of high solids concentration sand-water slurries; and environmental studies of the North Salt Lake pilot plant rehabilitation and eventual operation and those environmental problems associated with eventual commercial products.

  5. Suspended sediment transport response to upstream wash-load supply in the sand-bed reach of the Upper Yellow River, China (United States)

    Ta, Wanquan; Wang, Haibin; Jia, Xiaopeng


    Wash load is a major component of suspended sediment transport in the sand-bed reach of the Upper Yellow River, China. This wash load sediment originates from the Loess region, with the high runoff mainly originating from the rock mountains of its upstream basin. These characteristics result in a mismatch between water and sediment sources and a low probability of high runoffs meeting high suspended sediment concentration (SSC) flows. As a result, higher runoff with lower SSC levels (HR-LS) and lower runoff with higher SSC values (HS) occur, whose SSCs do not follow the typical power form for flow discharges, Ci = αQβ, where Ci and Q are SSC and flow discharge, respectively. Here, we modify the traditional power form with an upstream wash-load supply function C1-β to satisfy the relation between the water and wash load sediment concentrations in water-sediment mismatched cases, Ci = αQβC1-β, where C is an input flow's SSC. Using the daily flow discharges and SSCs of nine typical HR-LS flows and 18 HS flows in our study reach from 1960 to 2012, we find that β changes in response to input flow conditions and downstream transport distances. When the downstream transport distance is between 360 and 663.5 km, β varies between 0.3 and 0.6 in a HS input flow condition, while in the HR-LS input flow case, β tends to be greater than 0.6 (between 0.74 and 0.65). The entrainment rate of an HR-LS flow and the deposition rate of an HS flow appear to be asymmetrically balanced, establishing a primary mechanism for channel aggradation and upward fining of floodplains in our study reach.

  6. Desalination of oil sands process-affected water and basal depressurization water in Fort McMurray, Alberta, Canada: application of electrodialysis. (United States)

    Kim, Eun-Sik; Dong, Shimiao; Liu, Yang; Gamal El-Din, Mohamed


    The high content of inorganic species in water used to extract bitumen from the Alberta oil sands and in the groundwater below the oil sands is an increasing environmental concern. These water matrices require treatment before they can be reused or safely discharged. Desalination of the oil sands process-affected water (OSPW) and groundwater, or basal depressurization water (BDW), can be accomplished with deionization techniques such as electrodialysis (ED). In order to achieve the effective ED treatment, OSPW and BDW were pretreated with coagulation-flocculation-sedimentation to remove solid species and turbidity. We demonstrated that a conductivity range for industrial reuse of OSPW and BDW can be achieved with the ED treatment and showed the possibility of applying ED in the oil sands industry. A continuous ED system that reuses the diluate stream as a source for the concentrate stream was designed. The cost of a hypothetical ED water treatment plant in Fort McMurray, Alberta, was estimated to be C$10.71 per cubic meter of treated water.

  7. Particle Tracking Model and Abstraction of Transport Processes

    Energy Technology Data Exchange (ETDEWEB)

    B. Robinson


    The purpose of this report is to document the abstraction model being used in total system performance assessment (TSPA) model calculations for radionuclide transport in the unsaturated zone (UZ). The UZ transport abstraction model uses the particle-tracking method that is incorporated into the finite element heat and mass model (FEHM) computer code (Zyvoloski et al. 1997 [DIRS 100615]) to simulate radionuclide transport in the UZ. This report outlines the assumptions, design, and testing of a model for calculating radionuclide transport in the UZ at Yucca Mountain. In addition, methods for determining and inputting transport parameters are outlined for use in the TSPA for license application (LA) analyses. Process-level transport model calculations are documented in another report for the UZ (BSC 2004 [DIRS 164500]). Three-dimensional, dual-permeability flow fields generated to characterize UZ flow (documented by BSC 2004 [DIRS 169861]; DTN: LB03023DSSCP9I.001 [DIRS 163044]) are converted to make them compatible with the FEHM code for use in this abstraction model. This report establishes the numerical method and demonstrates the use of the model that is intended to represent UZ transport in the TSPA-LA. Capability of the UZ barrier for retarding the transport is demonstrated in this report, and by the underlying process model (BSC 2004 [DIRS 164500]). The technical scope, content, and management of this report are described in the planning document ''Technical Work Plan for: Unsaturated Zone Transport Model Report Integration'' (BSC 2004 [DIRS 171282]). Deviations from the technical work plan (TWP) are noted within the text of this report, as appropriate. The latest version of this document is being prepared principally to correct parameter values found to be in error due to transcription errors, changes in source data that were not captured in the report, calculation errors, and errors in interpretation of source data.

  8. A continuously weighing, high frequency sand trap: Wind tunnel and field evaluations (United States)

    Yang, Fan; Yang, XingHua; Huo, Wen; Ali, Mamtimin; Zheng, XinQian; Zhou, ChengLong; He, Qing


    A new continuously weighing, high frequency sand trap (CWHF) has been designed. Its sampling efficiency is evaluated in a wind tunnel and the potential of the new trap has been demonstrated in field trials. The newly designed sand trap allows fully automated and high frequency measurement of sediment fluxes over extensive periods. We show that it can capture the variations and structures of wind-driven sand transport processes and horizontal sediment flux, and reveal the relationships between sand transport and meteorological parameters. Its maximum sampling frequency can reach 10 Hz. Wind tunnel tests indicated that the sampling efficiency of the CWHF sand trap varies between 39.2 to 64.3%, with an average of 52.5%. It achieved a maximum sampling efficiency of 64.3% at a wind speed of 10 m s- 1. This is largely achieved by the inclusion of a vent hole which leads to a higher sampling efficiency than that of a step-like sand trap at high wind speeds. In field experiments, we show a good agreement between the mass of sediment from the CWHF sand trap, the wind speed at 2 m and the number of saltating particles at 5 cm above the ground surface. According to analysis of the horizontal sediment flux at four heights from the CWHF sand trap (25, 35, 50, and 100 cm), the vertical distribution of the horizontal sediment flux up to a height of 100 cm above the sand surface follows an exponential function. Our field experiments show that the new instrument can capture more detailed information on sediment transport with much reduced labor requirement. Therefore, it has great potential for application in wind-blown sand monitoring and process studies.

  9. Facilitated transport of titanium dioxide nanoparticles via hydrochars in the presence of ammonium in saturated sands: Effects of pH, ionic strength, and ionic composition. (United States)

    Xu, Nan; Cheng, Xueying; Zhou, Kairong; Xu, Xiaoting; Li, Zuling; Chen, Jianping; Wang, Dongtian; Li, Duo


    The widespread use of nanoparticles (NPs) has led to their inevitable introduction into environmental systems. How the existence of hydrochars in crop soils will affect the mobility of nanoparticle titanium dioxide (nTiO2), especially in the presence of ammonium (NH4(+)), remains unknown. Research is needed to study the effects of hydrochars on the transport and retention of nTiO2 and to uncover the mechanisms of these effects on nTiO2 transport. Column experiments with nTiO2 and hydrochars were performed in various electrolyte (NaCl, NH4Cl, and CaCl2) solutions under a controlled pH (6.0 and 8.0). Additionally, the size distributions and scanning electron microscope (SEM) and transmission electron microscope (TEM) images of the NPs were observed. The experimental results suggested that the mobility of the hydrochars was much better than that of nTiO2. Thus, the mobility of nTiO2 was improved upon their attachment to the hydrochars. The facilitated transport of nTiO2 in the presence of hydrochars was stronger at pH8.0 than at pH6.0, and facilitated transport was nearly independent of the electrolyte cation at pH8.0. However, at pH6.0, the facilitated transport in various electrolytes had the following order: NaCl>NH4Cl>CaCl2. The conversion from a completely reversible to a partially irreversible deposition of nTiO2 in sand was induced by the partially irreversible retention of hydrochars, and this phenomenon was more pronounced in the presence of NH4(+) than in the presence of Na(+). In particular, the irreversible deposition of nTiO2-hydrochars was enhanced as the cation concentration increased. The increased irreversible retention of nTiO2 was related to the greater k2 value (irreversible attachment coefficients) on site 2 for hydrochars based on two-site kinetic retention modeling. Thus, there is a potential risk of contaminating crops, soil, and underground water when nTiO2 exists in a hydrochar-amended environment, especially when associated with NH4-N

  10. Gathering Information from Transport Systems for Processing in Supply Chains (United States)

    Kodym, Oldřich; Unucka, Jakub


    Paper deals with complex system for processing information from means of transport acting as parts of train (rail or road). It focuses on automated information gathering using AutoID technology, information transmission via Internet of Things networks and information usage in information systems of logistic firms for support of selected processes on MES and ERP levels. Different kinds of gathered information from whole transport chain are discussed. Compliance with existing standards is mentioned. Security of information in full life cycle is integral part of presented system. Design of fully equipped system based on synthesized functional nodes is presented.

  11. Electro-osmotic transport in wet processing of textiles (United States)

    Cooper, John F.


    Electro-osmotic (or electrokinetic) transport is used to efficiently force a solution (or water) through the interior of the fibers or yarns of textile materials for wet processing of textiles. The textile material is passed between electrodes that apply an electric field across the fabric. Used alone or in parallel with conventional hydraulic washing (forced convection), electro-osmotic transport greatly reduces the amount of water used in wet processing. The amount of water required to achieve a fixed level of rinsing of tint can be reduced, for example, to 1-5 lbs water per pound of fabric from an industry benchmark of 20 lbs water/lb fabric.

  12. Transport simulation of sorptive contaminants considering sediment-associated processes

    Institute of Scientific and Technical Information of China (English)

    LI Ruijie; LU Shasha; ZHENG Jun


    Sediment-associated processes,such as sediment erosion,deposition,and pore water diffusion/advection affect sorptive contaminant transport.By considering these processes,we developed an equation to simulate contaminant transport.Erosion and deposition processes are considered as erosion and deposition fluxes of sediment,and adsorption-desorption processes of contaminants by sediment are simulated using the Langmuir Equation.Pore water diffusion is calculated based on the contaminant concentration gradient across the sediment-water interface.Pore water advection is estimated using pore water contained in the sediments of erosion flux.The equation is validated to simulate total phosphorus concentrations in Guanhe estuary in the northern Jiangsu,China.The simulated total phosphorus concentrations show better agreement with field observations compared to estimations that do consider sediment-associated processes.

  13. The kinetics of activation and deactivation in the process of water ozonising used for advanced oxidation of the dust waste from moulding sands

    Directory of Open Access Journals (Sweden)

    A. Baliński


    Full Text Available Adding coal dust and organic carriers of the lustrous carbon to bentonite-bonded moulding sands in amounts justified by thetechnological regime and the use of cores and protective coatings based on organic compounds create serious threats to the environment.During thermal destruction of the individual components of moulding and core sands, some toxic organic compounds are emitted. They formthe majority of the Hazardous Air Pollutants (HAPs, and include mainly compounds like benzene, toluene, xylene, naphtalene, hexane,acetaldehyde, acrolein, aniline, cresol and cumene, their polycyclic derivatives, phenol, formaldehyde, and other similar matters. In thusformed dust waste, the amount of which constitutes about 20% of all the waste from foundries using traditional moulding and core sands, there are still full-value materials which can undergo total recycling, providing the HAPs are partially or totally removed from them. The article discusses some problems of the advanced oxidation of selected toxic chemical compounds present in bentonite-bonded moulding sands due to the effect of high temperature. The results of the investigations of the kinetics of the process of maximum water saturation with ozone (acting as an oxidiser and of the kinetics of the natural process of ozone decomposition to diatomic oxygen were presented. It has been stated that the maximum time of water saturation with ozone using an OZOMATIC OSC-MODULAR 4HC ozone generator and a 1m3 capacity tank with water is 60 minutes. After 30 minute break in the ozonising process, the ozone concentration in water decreases by 40 to 50%. To obtain maximum ozone concentration in water during the next ozonising cycle, it is necessary to have the ozone-generating device running for the next 30 minutes. The stabilisation of ozone concentration in water takes place only after the third ozonising cycle, when it reaches nearly 80%of the maximum value obtained after the first process cycle

  14. Heterogeneous Wireless Sensor Network for Real Time Remote Monitoring of Sand Dynamics on Coastal Dunes (United States)

    Pozzebon, Alessandro; Bove, Carmine; Cappelli, Irene; Alquini, Fernanda; Bertoni, Duccio; Sarti, Giovanni


    In this paper, the architecture of a heterogeneous Wireless Sensor Network (WSN) to be deployed on coastal sand dunes is described, the aim of which is to provide real time measurements of physical parameters to better define the sediment transport in connection with Aeolian processes. The WSN integrates different typologies of sensors and is provided with both local and remote connection. In particular, three different typologies of sensors are integrated in the network: a multilayer anemometric station, a sensor developed ad-hoc to measure the sand dune level and a sand collector capable of measuring the weight of trapped sand and its quantity. Each sensor node is made up at least of a ZigBee radio module that is able to transmit the data collected by the sensor at a distance of about 100 meters. While the sand level sensor and the sand collector are provided only with this transmission module, the anemometric station also integrates a microprocessor board in charge of data processing. A Gateway node provided with a GSM connection for remote data transmission and a Zigbee radio module for Local Area communication has also been developed. This node is in charge of collecting all the data packets sent by the Sensor Nodes and transmit them to a remote server through GPRS connection. A Web server has been set up to collect these packets and store them in a database. The proposed WSN can provide both a static and a dynamic framework of sand transport processes acting on coastal dunes.

  15. Reply to "Comment on `Generalized exclusion processes: Transport coefficients' " (United States)

    Arita, Chikashi; Krapivsky, P. L.; Mallick, Kirone


    We reply to the Comment of Becker, Nelissen, Cleuren, Partoens, and Van den Broeck [Phys. Rev. E 93, 046101 (2016), 10.1103/PhysRevE.93.046101] on our article [Arita, Krapivsky, and Mallick, Phys. Rev. E 90, 052108 (2014), 10.1103/PhysRevE.90.052108] about the transport properties of a class of generalized exclusion processes.

  16. The process of motor transport technology development in intelligent transport systems

    Directory of Open Access Journals (Sweden)

    Rudzinska O.V.


    Full Text Available Traffic is now regarded as one of the most complicated components of social and economic development in cities and suburban regions. The most advanced technologies for collecting and processing information about traffic parameters (density, speed, rolling stock should be used in these areas to ensure non-stop traffic flow on the roads. Methodological formation of ITS is based on the systematic approach, which considers the development of ITS services as a system rather than individual modules. Therefore a single open system architecture, protocols, information exchange, form of transport documents, standardization of means of communication parameters used for monitoring and control of vehicles are formed. Some specifications for the list of functions and service groups were made while searching for a solution of transport technology domain problems - commercial vehicles. Typical issues solved in service groups, on organisation of trucking transportations using the intelligent transport systems were defined – interpretation, diagnosis, monitoring, synthesis, forecasting, training and supporting the decisions already taken.

  17. Environmental survey - tar sands in situ processing research program (Vernal, Uintah County, Utah). [Reverse-forward combustion; steam injection

    Energy Technology Data Exchange (ETDEWEB)

    Skinner, Q.


    Research will be done on the reverse-forward combustion and steam injection for the in-situ recovery of oil from tar sands. This environmental survey will serve as a guideline for the consideration of environmental consequences of such research. It covers the construction phase, operational phase, description of the environment, potential impacts and mitigations, coordination, and alternatives. (DLC)

  18. Modelling sediment transport processes in macro-tidal estuary

    Institute of Scientific and Technical Information of China (English)

    Rauen; William; B.


    This paper outlines a numerical modeling study to predict the sediment transport processes in a macro-tidal estuary, namely the Mersey Estuary, UK. An integrated numerical model study is conducted to investigate the interaction between the hydrodynamic, morphological and sediment transport processes occurring in the estuary. The numerical model widely used in environmental sediment transport studies worldwide, namely ECOMSED is used to simulate flow and sediment transport in estuary. A wetting and drying scheme is proposed and applied to the model, which defines "dry" cells as regions with a thin film of fluid O (cm). The primitive equations are solved in the thin film as well as in other regular wet cells. A model for the bed load transport is included in the code to account for the dynamics of the mobile bed boundary. The bed evolution due to bed load transport which is calculated according to van Rijn (1984a) is obtained by solving the sediment mass-balance equation. An estuary-related laboratory flume experiment is used to verify the model. Six sets of field measured hydrodynamic data are used to verify the corresponding predictions of the model, with the model-predicted water elevations and salinity levels generally agreeing well with the field measurements. The numerical model results show that in the Mersey Estuary both the tidal level and river discharge affect significantly the sediment transport. Reasonable agreement between the model results and field data has been obtained, indicating that the model can be used as computer-based tool for the environment management of estuarine system.

  19. Dark grains of sand: a geological storytelling (United States)

    Gallo Maresca, Magda


    In the secondary Italian school the Earth science learning begins at first year, in synergy with other natural science subjects such as Astronomy, Chemistry and Biology. Italian teachers have to focus on the landscape geomorphological aspects and often Earth processes are difficult to display since they are related to certain phenomena happened during the past and often far from the involved country. In order to better understand the environment surrounding us, very simple and poor materials, like sands, allow the teachers to create attractive lab experiences. According to the IBSE (Inquiry Based Science Education) approach, a learning unit has been implemented starting from a walking along the light carbonate beaches of the Adriatic sea: a smart look to the sands ("engage step"), stroke the students fantasy pushing them to explore some strange black grains on the sands. Dirty sands? Or rock landscape, soil degradation and Ofanto river and coastal processes (erosion, transportation and deposition)? This was the teaching challenge. Due to the youngest age, a third level, guided inquiry, was adopted so the teacher is the "guide of inquiry" encouraging the students using the research question ("Why is the sand dark?", "Do all sands look the same?", "Where does it come from?") and driving the students around their investigation plans ("How can I measure grain size?"). A procedure to answer the above questions and validate the results and explanations has been implemented to allow the students to be proactive in their study. During the learning activities will be the students to ask for field trip to elaborate their new knowledge, verify and visualize the speculated processes. The teaching skills allow to address several geosciences domains such as mineralogy, petrology, regional geology and geodynamics as well as other scientific disciplines such as mathematics (more specifically statistics), forensic science and even life sciences (the presence of bioclasts might

  20. Development of wear resistant nanostructured duplex coatings by high velocity oxy-fuel process for use in oil sands industry. (United States)

    Saha, Gobinda C; Khan, Tahir I; Glenesk, Larry B


    Oil sands deposits in Northern Alberta, Canada represent a wealth of resources attracting huge capital investment and significant research focus in recent years. As of 2005, crude oil production from the current oil sands operators accounted for 50% of Canada's domestic production. Alberta's oil sands deposits contain approximately 1.7 trillion barrels of bitumen, of which over 175 billion are recoverable with current technology, and 315 billion barrels are ultimately recoverable with technological advances. A major problem of operating machinery and equipment in the oil sands is the unpredictable failure from operating in this highly aggressive environment. One of the significant causes of that problem is premature material wear. An approach to minimize this wear is the use of protective coatings and, in particular, a cermet thin coating. A high level of coating homogeneity is critical for components such as bucketwheels, draglines, conveyors, shovels, heavyhauler trucks etc. that are subjected to severe degradation through abrasive wear. The identification, development and application of optimum wear solutions for these components pose an ongoing challenge. Nanostructured cermet coatings have shown the best results of achieving the degree of homogeneity required for these applications. In this study, WC-17Co cermet powder with nanocrystalline WC core encapsulated with 'duplex' Co layer was used to obtain a nanostructured coating. To apply this coating, high velocity oxy-fuel (HVOF) thermal spraying technique was used, as it is known for producing wear-resistant coatings superior to those obtained from plasma-based techniques. Mechanical, sliding wear and microstructural behavior of the coating was compared with those of the microstructured coating obtained from spraying WC-10Co-4Cr cermet powder by HVOF technique. Results from the nanostructured coating, among others, showed an average of 25% increase in microhardness, 30% increase in sliding wear resistance and

  1. An Investigation into the Processes and Quantity of Dust Emissions over Gravel and Sand Deserts in North-Western China (United States)

    Zhang, Zhengcai; Dong, Zhibao; Qian, Guangqian; Wu, Guoxi; Cui, Xujia


    Year-long field observations have shown that there are spatial and temporal variations in the quantity of dust emissions for particulate matter {<}10 μm (PM10), particulate matter {<}63 μm (PM63) and vertical dust flux over different gravel surfaces (with loose sand, without loose sand, with a crust, and without a crust), with the greatest emissions occurring in the spring. The largest quantity of PM10 and PM63 emissions occurred over gravel with a loose sand surface (1.1 × 10^{-3} and 10.2 × 10^{-3} kg m^{-1} day^{-1}, respectively). The gravel surface without loose sand and without a crust presents the lowest values of PM63 (1.6 × 10^{-3} kg m^{-1} day^{-1}) and PM10 (3.3 × 10^{-4} kg m^{-1} day^{-1}). However, the vertical dust flux was largest at over sandy surface (373 × 10^{-3 } kg m^{-2} day^{-1}). Multivariate correlation analysis indicates that the quantity of PM10 is strongly negatively correlated to gravel coverage (R^{2 }= 0.55). The quantity of PM10 dust emissions over a gravel surface with loose sand is approximately three times greater than that of a gravel surface with a crust. The mean quantity of PM10, PM63 and vertical dust flux over a gravel surface decreased with increasing gravel coverage. By comparing the quantity of PM10 dust emissions over gravel and sandy deserts, we found that gravel deserts and sandy deserts are both major sources of dust for dust storms in this region.

  2. Identification of Radar Facies and Linked Process-Based Palaeo-environmental Interpretations, Cooloola Sand Mass, Queensland, Australia (United States)

    Gontz, A. M.; McCallum, A. B.; Moss, P. T.; Shulmeister, J.


    During 2015 and 2014, nearly 60 km of high-resolution ground penetrating radar data were acquired on the Cooloola Sand Mass (CSM) in southeastern coastal Queensland. The CSM is part of the world's largest downdrift sand system. It contains three of the world's largest sand islands, several National Parks, a UNESCO World Heritage Site and covers 500 km of the eastern Australian coastline in northern New South Wales and southern Queensland. The large (>200 m) composite dunes of the CSM exhibit multiple activation phases, coastally eroding bluffs and dune development is not obvious from surficial exposures. This provides an ideal environment for ground penetrating radar. The dune sequences have been provisionally dated to the mid Quaternary through present and represent the potential for a large palaeo-environmental proxy dataset. GPR imagery was collected using a MALA GeoSciences Ground Explorer (GX) system with 160 and 450 MHz antennae from the numerous physiographic and ecological provinces as well as mapped surficial soil units at the CSM. These data were used to determine the subsurface architecture, identify radar facies and develop environmental interpretations. In the clean, aeolian quartz-rich sands, radar wave penetration exceeded 30 m (radar velocity = 0.07 m/ns) with the 160 MHz antenna. From the interpreted environmental units including palaeosol, dune slip face, dune stoss face, sand blow, beach, estuarine and fluvial, we are developing maps to relate the units and focus a detailed sampling regime that includes OSL, sediment geochemistry and sedimentology, The interpreted units, stratigraphic correlation and spatial distribution of the facies is the first step in a broader project to unravel the Quaternary environmental and climate records that are archived within the sediments of the CSM.

  3. Oil shale, tar sand, coal research, advanced exploratory process technology, jointly sponsored research. Quarterly technical progress report, April--June 1993

    Energy Technology Data Exchange (ETDEWEB)


    Progress made in five areas of research is described briefly. The subtask in oil shale research is on oil shale process studies. For tar sand the subtask reported is on process development. Coal research includes the following subtasks: Coal combustion; integrated coal processing concepts; and solid waste management. Advanced exploratory process technology includes the following: Advanced process concepts; advanced mitigation concepts; oil and gas technology. Jointly sponsored research includes: Organic and inorganic hazardous waste stabilization; CROW{sup TM} field demonstration with Bell Lumber and Pole; development and validation of a standard test method for sequential batch extraction fluid; operation and evaluation of the CO{sup 2} HUFF-N-PUFF Process; fly ash binder for unsurfaced road aggregates; solid-state NMR analysis of Mesaverde Group, Greater Green River Basin, tight gas sands; characterization of petroleum residua; shallow oil production using horizontal wells with enhanced oil recovery techniques; surface process study for oil recovery using a thermal extraction process;NMR analysis of samples from the ocean drilling program; oil field waste cleanup using tank bottom recovery process; remote chemical sensor development; in situ treatment of manufactured gas plant contaminated soils demonstration program; solid-state NMR analysis of Mowry formation shale from different sedimentary basins; solid-state NMR analysis of naturally and artificially matured kerogens; and development of effective method for the clean-up of natural gas.

  4. Effects of two Asian sand dusts transported from the dust source regions of Inner Mongolia and northeast China on murine lung eosinophilia

    Energy Technology Data Exchange (ETDEWEB)

    He, Miao, E-mail: [Environment and Chronic Non-communicable Disease Research Center, College of Public Health, China Medical University, 11001 Shenyang (China); Department of Health Sciences, Oita University of Nursing and Health Sciences, 870-1201 Oita (Japan); Ichinose, Takamichi, E-mail: [Department of Health Sciences, Oita University of Nursing and Health Sciences, 870-1201 Oita (Japan); Song, Yuan, E-mail: [Department of Immunology and Parasitology, School of Medicine, University of Occupational and Environmental Health, Iseigaoka, Yahata-nishi-ku, Kitakyushu, 807-8555 Fukuoka (Japan); Yoshida, Yasuhiro, E-mail: [Department of Immunology and Parasitology, School of Medicine, University of Occupational and Environmental Health, Iseigaoka, Yahata-nishi-ku, Kitakyushu, 807-8555 Fukuoka (Japan); Arashidani, Keiichi, E-mail: [Department of Immunology and Parasitology, School of Medicine, University of Occupational and Environmental Health, Iseigaoka, Yahata-nishi-ku, Kitakyushu, 807-8555 Fukuoka (Japan); Yoshida, Seiichi, E-mail: [Department of Health Sciences, Oita University of Nursing and Health Sciences, 870-1201 Oita (Japan); Liu, Boying, E-mail: [Environment and Chronic Non-communicable Disease Research Center, College of Public Health, China Medical University, 11001 Shenyang (China); Department of Health Sciences, Oita University of Nursing and Health Sciences, 870-1201 Oita (Japan); Nishikawa, Masataka, E-mail: [Environmental Chemistry Division, National Institute for Environmental Studies, 305-8506 Tsukuba, Ibaraki (Japan); Takano, Hirohisa, E-mail: [Environmental Health Division, Department of Environmental Engineering, Graduate School of Engineering, Kyoto University, Kyoto daigaku-Katsura, Nishikyo-ku, Kyoto 615-8530 (Japan); and others


    The quality and quantity of toxic materials adsorbed onto Asian sand dust (ASD) are different based on dust source regions and passage routes. The aggravating effects of two ASDs (ASD1 and ASD2) transported from the source regions of Inner Mongolia and northeast China on lung eosinophilia were compared to clarify the role of toxic materials in ASD. The ASDs contained different amounts of lipopolysaccharides (LPS) and β-glucan (ASD1 < ASD2) and SiO{sub 2} (ASD1 > ASD2). CD-1 mice were instilled intratracheally with ASD1, ASD2 and/or ovalbumin (OVA) four times at 2-week intervals. ASD1 and ASD2 enhanced eosinophil recruitment induced by OVA in the submucosa of the airway, with goblet cell proliferation in the bronchial epithelium. ASD1 and ASD2 synergistically increased OVA-induced eosinophil-relevant cytokines interleukin-5 (IL-5), IL-13 (ASD1 < ASD2) and chemokine eotaxin (ASD1 > ASD2) in bronchoalveolar lavage fluid. ASD2 aggravating effects on lung eosinophilia were greater than ASD1. The role of LPS and β-glucan in ASD2 on the production of pro-inflammatory mediators was assessed using in vitro bone marrow-derived macrophages (BMDMs) from wild type, Toll-like receptor 2-deficient (TLR2 −/−), TLR4 −/−, and MyD88 −/− mice (on Balb/c background). ASD2-stimulated TLR2 −/− BMDMs enhanced IL-6, IL-12, TNF-α, MCP-1 and MIP-1α secretion compared with ASD2-stimulated TLR4 −/− BMDMs. Protein expression from ASD2-stimulated MyD88 −/− BMDM were very low or undetectable. The in vitro results indicate that lung eosinophilia caused by ASD is TLR4 dependent. Therefore, the aggravation of OVA-related lung eosinophilia by ASD may be dependent on toxic substances derived from microbes, such as LPS, rather than SiO{sub 2}. - Highlights: • Asian sand dust (ASD) from the deserts of China causes serious respiratory problems. • The aggravating effects of two ASDs on lung eosinophilia were compared. • The ASDs contained different LPS and β-glucan (ASD1

  5. Features, Events, and Processes in UZ Flow and Transport

    Energy Technology Data Exchange (ETDEWEB)

    J.E. Houseworth


    Unsaturated zone (UZ) flow and radionuclide transport is a component of the natural barriers that affects potential repository performance. The total system performance assessment (TSPA) model, and underlying process models, of this natural barrier component capture some, but not all, of the associated features, events, and processes (FEPs) as identified in the FEPs Database (Freeze, et al. 2001 [154365]). This analysis and model report (AMR) discusses all FEPs identified as associated with UZ flow and radionuclide transport. The purpose of this analysis is to give a comprehensive summary of all UZ flow and radionuclide transport FEPs and their treatment in, or exclusion from, TSPA models. The scope of this analysis is to provide a summary of the FEPs associated with the UZ flow and radionuclide transport and to provide a reference roadmap to other documentation where detailed discussions of these FEPs, treated explicitly in TSPA models, are offered. Other FEPs may be screened out from treatment in TSPA by direct regulatory exclusion or through arguments concerning low probability and/or low consequence of the FEPs on potential repository performance. Arguments for exclusion of FEPs are presented in this analysis. Exclusion of specific FEPs from the UZ flow and transport models does not necessarily imply that the FEP is excluded from the TSPA. Similarly, in the treatment of included FEPs, only the way in which the FEPs are included in the UZ flow and transport models is discussed in this document. This report has been prepared in accordance with the technical work plan for the unsaturated zone subproduct element (CRWMS M&O 2000 [153447]). The purpose of this report is to document that all FEPs are either included in UZ flow and transport models for TSPA, or can be excluded from UZ flow and transport models for TSPA on the basis of low probability or low consequence. Arguments for exclusion are presented in this analysis. Exclusion of specific FEPs from UZ flow and

  6. RANS-based simulation of turbulent wave boundary layer and sheet-flow sediment transport processes

    DEFF Research Database (Denmark)

    Fuhrman, David R.; Schløer, Signe; Sterner, Johanna


    suspended sediment concentrations, (2) turbulence suppression due to density gradients in the water–sand mixture, (3) boundary layer streaming due to convective terms, and (4) converging–diverging effects due to a sloping bed. The present model therefore provides a framework for simultaneous inclusion...... of a number of local factors important within cross-shore wave boundary layer and sediment transport dynamics. The hydrodynamic model is validated for both hydraulically smooth and rough conditions, based on wave friction factor diagrams and boundary layer streaming profiles, with the results in excellent...... to investigate the importance of boundary layer streaming effects on sediment transport in selected velocity-skewed conditions. For the medium sand grain conditions considered, the model results suggest that streaming effects can enhance onshore sediment transport rates by asmuch as a factor of two...

  7. Analysis of Transport Processes Management for a Romanian Food Market

    Directory of Open Access Journals (Sweden)

    Maria NEAGU


    Full Text Available This paper presents the study of optimization process for the products transportation for a Romanian food-market. The vehicle routing problem was solves using Lingo 13.0 software and an analysis was conducted in order to determine the optimal routes for the vehicles in the conditions of products request variation. The program developed is considering one storing place from where the products are transported to other six delivery points using three vehicles. Each vehicle has a constant capacity and a constant travel velocity.

  8. 铸造铝合金冷硬树脂砂工艺研究%Study on Cold Resin Sand Casting Process of Aluminum Alloy

    Institute of Scientific and Technical Information of China (English)



    T he raw materials selection of the cold resin sand ,curing characteristics and influ‐ence factors are experimented and studied .The study results show that cold resin sand cast‐ing process is cost‐effective ,quickly efficient ,economic‐effective ,and with high practical value .%对冷硬树脂砂原材料的选择、固化特性及影响因素开展了实验及研究,结果表明,冷硬树脂砂造型工艺是一项投资少、见效快、经济效益显著、实用价值高的新型实用型铸造工艺。

  9. Grain-size features of aeolian sand on the east coast of Hainan Island and the revealed evolutionary processes of the sedimentary environment

    Institute of Scientific and Technical Information of China (English)


    The Mudui stratigraphic section represents the typical records of sedimentation processes of sand dunes and interdune depressions on the east coast of Hainan Island.Based on high-density sampling and optically stimulated luminescence(OSL) dating of the strata of the section,the grain-size composition,grain-size parameters,cumulative distribution probability curve,and grain-size-sensitivity indexes(SC/D) were analyzed.The analyzed results show that the grain-size features of aeolian sand,weakly developed sandy paleosol,two-facies(aeolian and aqueous) deposits,and lagoon deposits are all different.This indicates four evolutionary phases of the sedimentary environment of the east coast of Hainan Island since 38 ka B.P.Phase I:38-22 ka B.P.;phase II:22-17 ka B.P.;phase III:17-10 ka B.P.;phase IV:10 ka B.P.-present.The climate experienced the hot-wet/hot-dry,hot-wet/hot-dry,and warm-wet/hot-wet fluctuations,and the sedimentary environment also underwent lagoon deposition,dune and interdune depression deposition,dune stabilization and soil development,shifting sand deposition,and evolutionary processes.

  10. An Experimental investigation of sea sand as an Abrasive material in vibrating chamber by using Tungsten Carbide Nozzle in Abrasive Jet machining Process.

    Directory of Open Access Journals (Sweden)

    N. S. Pawar


    Full Text Available A large number of investigation carried out in Abrasive jet machining and water jet machining process with different parameter but no detailed work have been found or carried out by using sea sand as an abrasive in AJM process by using different types of nozzles and variable parameters. The present work gives performance of sand having grain structure of 100-150 micron in the tungsten carbide nozzle. Theexperimentation in this study give characteristic of sea sand as abrasive material. The parameter like pressure, standoff distance of nozzle from work piece keeping constant and variable. It give the result of material removal rate , powder flow rate, similar to actually abrasive used like Aluminum oxide, silicon oxide etc. The R square value o.97 to 0.996 degree of polynomial equation. It is also notice that width of cut slightly increase with increase of feed rate .The taper cut slot was found to be a higher at greater stand of distance and work feed rate .Tungsten carbide is very hard. It maintain high cutting ability as abrasive strike on work piece

  11. Laboratory studies of aeolian sediment transport processes on planetary surfaces (United States)

    Rasmussen, Keld R.; Valance, Alexandre; Merrison, Jonathan


    , but not all, older or recent wind tunnel observations. Similarly some measurements performed with uniform sand samples having grain diameters of the order of 0.25-0.40 mm indicate that ripple spacing depends on friction velocity in a similar way as particle jump length. The observations are thus in agreement with a recent ripple model that link the typical jump length to ripple spacing. A possible explanation for contradictory observations in some experiments may be that long observation sequences are required in order to assure that equilibrium exists between ripple geometry and wind flow. Quantitative understanding of saltation characteristics on Mars still lacks important elements. Based upon image analysis and numerical predictions, aeolian ripples have been thought to consist of relatively large grains (diameter > 0.6 mm) and that saltation occurs at high wind speeds (> 26 m/s) involving trajectories that are significantly longer than those on Earth (by a factor of 10-100). However, this is not supported by recent observations from the surface of Mars, which shows that active ripples in their geometry and composition have characteristics compatible with those of terrestrial ripples (Sullivan et al., 2008). Also the highest average wind speeds on Mars have been measured to be terrestrial conditions electric fields typically observed are not intense enough to significantly affect sand transport rates while little is known in the case of extra-terrestrial environments.

  12. Kinetic theory of transport processes in partially ionized reactive plasma, II: Electron transport properties (United States)

    Zhdanov, V. M.; Stepanenko, A. A.


    The previously obtained in (Zhdanov and Stepanenko, 2016) general transport equations for partially ionized reactive plasma are employed for analysis of electron transport properties in molecular and atomic plasmas. We account for both elastic and inelastic interaction channels of electrons with atoms and molecules of plasma and also the processes of electron impact ionization of neutral particles and three-body ion-electron recombination. The system of scalar transport equations for electrons is discussed and the expressions for non-equilibrium corrections to electron ionization and recombination rates and the diagonal part of the electron pressure tensor are derived. Special attention is paid to analysis of electron energy relaxation during collisions with plasma particles having internal degrees of freedom and the expression for the electron coefficient of inelastic energy losses is deduced. We also derive the expressions for electron vector and tensorial transport fluxes and the corresponding transport coefficients for partially ionized reactive plasma, which represent a generalization of the well-known results obtained by Devoto (1967). The results of numerical evaluation of contribution from electron inelastic collisions with neutral particles to electron transport properties are presented for a series of molecular and atomic gases.

  13. Sands styrke

    DEFF Research Database (Denmark)

    Jacobsen, H. Moust; Jørgensen, Mogens B.; Poulsen, H. Serup


    På grundlag af triaxialforsøg med D=7 og 20 cm og varierende højde på løse og faste lejringer af Blokhussand kan effekten af varierende højde-breddeforhold og spændingsniveau samt skalaeffekten bestemmes. Ved sammenligning med pladeforsøg med overfladelast op til 8 t/m2 kan den almindelige fremga...... fremgangsmåde ved bæreevneberegninger på sand undersøges....

  14. Review of modeling and control during transport airdrop process

    Directory of Open Access Journals (Sweden)

    Bin Xu


    Full Text Available This article presents the review of modeling and control during the airdrop process of transport aircraft. According to the airdrop height, technology can be classified into high and low altitude airdrop and in this article, the research is reviewed based on the two scenarios. While high altitude airdrop is mainly focusing on the precise landing control of cargo, the low altitude flight airdrop is on the control of transport aircraft dynamics to ensure flight safety. The history of high precision airdrop system is introduced first, and then the modeling and control problem of the ultra low altitude airdrop in transport aircraft is presented. Finally, the potential problems and future direction of low altitude airdrop are discussed.

  15. Recent achievements in facilitated transport membranes for separation processes

    Directory of Open Access Journals (Sweden)

    H. C. Ferraz


    Full Text Available Membrane separation processes have been extensively used for some important industrial separations, substituting traditional methods. However, some applications require the development of new membranes. In this work, we discuss recent progress achieved in this field, focusing on gas and liquid separation using facilitated transport membranes. The advantages of using a carrier species either in a liquid membrane or fixed in a polymer matrix to enhance both the flux and the selectivity of the transport are summarized. The most probable transport mechanisms in these membranes are presented and the improvements needed to spread this technology are also discussed. As examples, we discuss our very successful experiences in air fractioning, olefin/paraffin separation and sugar recovery using liquid and fixed carrier membranes.

  16. Effect of adsorbed metals ions on the transport of Zn- and Ni-EDTA complexes in a sand and gravel aquifer (United States)

    Kent, D.B.; Davis, J.A.; Anderson, L.C.D.; Rea, B.A.; Coston, J.A.


    Adsorption, complexation, and dissolution reactions strongly influenced the transport of metal ions complexed with ethylenediaminetetraacetic acid (EDTA) in a predominantly quartz-sand aquifer during two tracer tests conducted under mildly reducing conditions at pH 5.8 to 6.1. In tracer test M89, EDTA complexes of zinc (Zn) and nickel (Ni), along with excess free EDTA, were injected such that the lower portion of the tracer cloud traveled through a region with adsorbed manganese (Mn) and the upper portion of the tracer cloud traveled through a region with adsorbed Zn. In tracer test S89, Ni- and Zn-EDTA complexes, along with excess EDTA complexed with calcium (Ca), were injected into a region with adsorbed Mn. The only discernable chemical reaction between Ni-EDTA and the sediments was a small degree of reversible adsorption leading to minor retardation. In the absence of adsorbed Zn, the injected Zn was displaced from EDTA complexes by iron(III) [Fe(III)] dissolved from the sediments. Displacement of Zn by Fe(III) on EDTA became increasingly thermodynamically favorable with decreasing total EDTA concentration. The reaction was slow compared to the time-scale of transport. Free EDTA rapidly dissolved aluminum (Al) from the sediments, which was subsequently displaced slowly by Fe. In the portion of tracer cloud M89 that traveled through the region contaminated with adsorbed Zn, little displacement of Zn complexed with EDTA was observed, and Al was rapidly displaced from EDTA by Zn desorbed from the sediments, in agreement with equilibrium calculations. In tracer test S89, desorption of Mn dominated over the more thermodynamically favorable dissolution of Al oxyhydroxides. Comparison with results from M89 suggests that dissolution of Al oxyhydroxides in coatings on these sediment grains by Ca-EDTA was rate-limited whereas that by free EDTA reached equilibrium on the time-scale of transport. Rates of desorption are much faster than rates of dissolution of Fe

  17. Isolation and estimation of the 'aromatic' naphthenic acid content of an oil sands process-affected water extract. (United States)

    Jones, David; West, Charles E; Scarlett, Alan G; Frank, Richard A; Rowland, Steven J


    The naphthenic acids of oil sands process-affected water (OSPW) are said to be important toxicants. The major acids are stated to have alicyclic structures and recently, numerous of these have been identified, but some evidence suggests 'aromatic' acids are also present. The proportions of such acids have not been reported because they exist in so-called supercomplex mixtures with the alicyclic species. Their contribution to the toxicity of OSPW, if any, is therefore unknown. Here we report the use of multidimensional comprehensive gas chromatography-mass spectrometry (GC×GC-MS) with polar first dimension and non-polar second dimension GC columns and argentation solid phase extraction, to separate methyl esters of the acids of an OSPW supercomplex, into distinct fractions. A major fraction (ca 70%) was shown to contain acids (methyl esters) previously identified as alicyclic species. Authentic adamantane acid methyl esters were shown to chromatograph in this fraction. This fraction was isolated by argentation solid phase extraction (SPE) by elution with hexane. GC-MS and GC×GC-MS confirmed this to be the major fraction in the original supercomplex containing alicyclic acids (methyl esters). A second fraction shown to contain monoaromatic acids (methyl esters) by GC×GC-MS was unexpectedly abundant (ca 30% relative to the acyclic acids). The naphtheno-aromatic dehydroabietic acid was confirmed by co-injection with an authentic compound and several acids previously tentatively identified as naphtheno-monoaromatics were present. This fraction was isolated by argentation SPE by elution with more polar 5% diethyl ether in hexane. GC-MS and GC×GC-MS confirmed that the fraction represented a significant proportion of the original supercomplex. A further fraction, eluting from the argentation SPE column with more 5% diethyl ether in hexane in the same retention volume as authentic methyl naphthoate, contained, in addition to some of the second fraction, a third, much

  18. Green Transport Balanced Scorecard Model with Analytic Network Process Support

    Directory of Open Access Journals (Sweden)

    David Staš


    Full Text Available In recent decades, the performance of economic and non-economic activities has required them to be friendly with the environment. Transport is one of the areas having considerable potential within the scope. The main assumption to achieve ambitious green goals is an effective green transport evaluation system. However, these systems are researched from the industrial company and supply chain perspective only sporadically. The aim of the paper is to design a conceptual framework for creating the Green Transport (GT Balanced Scorecard (BSC models from the viewpoint of industrial companies and supply chains using an appropriate multi-criteria decision making method. The models should allow green transport performance evaluation and support of an effective implementation of green transport strategies. Since performance measures used in Balanced Scorecard models are interdependent, the Analytic Network Process (ANP was used as the appropriate multi-criteria decision making method. The verification of the designed conceptual framework was performed on a real supply chain of the European automotive industry.

  19. Coagulation/flocculation process with polyaluminum chloride for the remediation of oil sands process-affected water: Performance and mechanism study. (United States)

    Wang, Chengjin; Alpatova, Alla; McPhedran, Kerry N; Gamal El-Din, Mohamed


    This study investigated the application of polyaluminum chloride (PACl) for the treatment of the oil sands process-affected water (OSPW). These coagulants are commonly used in water treatment with the most effective species reported to be Al13. PACl with 83.6% Al13 was synthesized using the slow base titration method and compared with a commercially available PACl in terms of aluminum species distribution, coagulation/flocculation (CF) performance, floc morphology, and contaminant removal. Both coagulants were effective in removing suspended solids, achieving over 96% turbidity removal at all applied coagulant doses (0.5-3.0 mM Al). The removal efficiencies of metals varied among different metals depending on their pKa values with metal cations having pKa values (Fe, Al, Ga, and Ti) below OSPW pH of 6.9-8.1 (dose dependent) being removed by more than 90%, while cations with higher pKa values (K, Na, Ca, Mg and Ni) had removals of less than 40%. Naphthenic acids were not removed due to their low molecular weights, negative charges, and hydrophilic characteristics at the OSPW pH. At the highest applied coagulant dose of 3.0 mM Al, the synthetic PACl reduced Vibrio fischeri inhibition effect to 43.3 ± 3.0% from 49.5 ± 0.4% in raw OSPW. In contrast, no reduction of toxicity was found for OSPW treated with the commercial PACl. Based on water quality and floc analyses, the dominant CF mechanism for particle removal during OSPW treatment was considered to be enmeshment in the precipitates (i.e., sweep flocculation). Overall, the CF using synthesized PACl can be a valuable pretreatment process for OSPW to create wastewater that is more easily treated by downstream processes.

  20. Innovative approach to collaboration in joint organization of transport processes

    Directory of Open Access Journals (Sweden)

    Marcin Hajdul


    Full Text Available Background: The paper presents an innovative approach to the collaboration in joint transport processes within existing supply chains which has been implementing by member companies of ECR Poland. Current approach results in inefficient use of resources due to mainly horizontal cooperation between individual service users and service providers. This effect has been demonstrated by research conducted by the author as well as by the European Environmental Agency. Methods: The aim of this paper is to present how design thinking approach allows creation of new transport business model and communication platform. Results: Created solution allowing simultaneous vertical and horizontal co-operation of independent companies involved in the organization of transport processes. The result of such cooperation is the elimination of identified inefficiencies through sustainable use of available resources. Conclusions: The work is summarized by the results of the implementation of presented solutions within the group of companies operating in the FMCG sector in Poland. Companies were able to reduce their transport costs, increase load factor, reduce empty runs as well as reduce congestion on roads where they operate.

  1. Distribution of clay minerals in marine sediments off Chennai, Bay of Bengal, India:Indicators of sediment sources and transport processes

    Institute of Scientific and Technical Information of China (English)

    Subramanian VEERASINGAM; Ramdoss VENKATACHALAPATHY; Thirunavukkarasu RAMKUMAR


    Clay mineralogy, texture size and statistical analyses were carried out on surface sediments from the continental shelf of Chennai, Bay of Bengal, India. The purpose of this study is to characterize the clay mineral distribution and its relation to the hydrodynamics off Chennai to identify the sources and transport pathways of the marine sediments. Characterization of clay minerals in coastal sediments by Fourier Transform Infrared (FTIR) spectroscopy has provided the association of quartz, feldspar, kaolinite, chlorite, illite and iron oxides (magnetite and hematite) derived from river catchments and coastal erosion. Kaolinite, chlorite, illite, iron oxides, and organic matter are the dominant minerals in Cooum, and Adayar region. High quartz and feldspar zones were identified in Marina, which are being confined the sand zone and paralleling the coast. The strong relationships among the wave energy density, sand, quartz and carbonate revealed that wave induced littoral drift system play a dominant role in transportation and deposition of sediments in the Chennai coast. The sediment texture and minerals data are in agreement well with the previous results of hydrodynamics and littoral drift models in this region. Multivariate statistical analyses (correlation, cluster and factor analyses) were carried out and obtained results suggested that clay minerals and organic matter are trapped in silt and clay particles, whereas quartz, feldspar and carbonate are associated with sand particles. Results of sediment sources and transport processes from this study will be useful to predict the fate of the pollutants released from land or the potential change in sediment delivery to coastal areas.

  2. Transport Processes from Mechanics: Minimal and Simplest Models (United States)

    Bunimovich, Leonid A.; Grigo, Alexander


    We review the current state of a fundamental problem of rigorous derivation of transport processes in classical statistical mechanics from classical mechanics. Such derivations for diffusion and momentum transport (viscosities) were obtained for minimal models of these processes involving one and two particles respectively. However, a minimal model which demonstrates heat conductivity contains three particles. Its rigorous analysis is currently out of reach for existing mathematical techniques. The gas of localized balls is widely accepted as a basis for a simplest model for derivation of Fourier's law. We suggest a modification of the localized balls gas and argue that this gas of localized activated balls is a good candidate to rigorously prove Fourier's law. In particular, hyperbolicity is derived for a reduced version of this model.

  3. Transport Processes from Mechanics: Minimal and Simplest Models (United States)

    Bunimovich, Leonid A.; Grigo, Alexander


    We review the current state of a fundamental problem of rigorous derivation of transport processes in classical statistical mechanics from classical mechanics. Such derivations for diffusion and momentum transport (viscosities) were obtained for minimal models of these processes involving one and two particles respectively. However, a minimal model which demonstrates heat conductivity contains three particles. Its rigorous analysis is currently out of reach for existing mathematical techniques. The gas of localized balls is widely accepted as a basis for a simplest model for derivation of Fourier's law. We suggest a modification of the localized balls gas and argue that this gas of localized activated balls is a good candidate to rigorously prove Fourier's law. In particular, hyperbolicity is derived for a reduced version of this model.

  4. Contemporary sediment-transport processes in submarine canyons. (United States)

    Puig, Pere; Palanques, Albert; Martín, Jacobo


    Submarine canyons are morphological incisions into continental margins that act as major conduits of sediment from shallow- to deep-sea regions. However, the exact mechanisms involved in sediment transfer within submarine canyons are still a subject of investigation. Several studies have provided direct information about contemporary sedimentary processes in submarine canyons that suggests different modes of transport and various triggering mechanisms. Storm-induced turbidity currents and enhanced off-shelf advection, hyperpycnal flows and failures of recently deposited fluvial sediments, dense shelf-water cascading, canyon-flank failures, and trawling-induced resuspension largely dominate present-day sediment transfer through canyons. Additionally, internal waves periodically resuspend ephemeral deposits within canyons and contribute to dispersing particles or retaining and accumulating them in specific regions. These transport processes commonly deposit sediments in the upper- and middle-canyon reaches for decades or centuries before being completely or partially flushed farther down-canyon by large sediment failures.

  5. Observations of several characteristics of aeolian sand movement in the Taklimakan Desert

    Institute of Scientific and Technical Information of China (English)

    HAN; Zhiwen; DONG; Zhibao; WANG; Tao; CHEN; Guangting; YAN


    With both sides of the Taklimakan Desert highway line as the study area, three typical aeolian sand landforms, i.e. complex dune ridge, barchan dune and flat sand land, were selected as sand beds for the observation, analysis and research of the characteristics of aeolian sand movement such as aeolian sand stream structure, sand transport intensity, etc. in the Taklimakan Desert. The results show that there is a linear relation between the height and the log of sand transport rate over transverse dune chain, longitudinal dune ridge and flat sand land, i.e. the sand transport percentage decreases exponentially with increasing height. Sand transport rate within the 10 cm height above the bed surface accounts for 80%-95% of the total sand transport rate of the observed height (40 cm), while the sand transport rate in 20 cm occupies 98% of the total amount. Sand transport rate (g·cm-1·min-1) differs greatly with respect to different landform types and different topographic positions. Based on the investigation and analysis on aeolian sand landform origin, morphological type and distribution feature, the two typical landform assemblages, complex transverse dune chain-alluvial plain and huge longitudinal dune ridge-interridge lowland in the Taklimakan Desert were divided into several characteristic zones of aeolian sand movement states. From this one can qualitatively judge the types and severities of sand disasters at various topographic positions in the engineering installation region and further put forward concrete schemes and measures to control sand damages.

  6. Nonlinear closure relations theory for transport processes in nonequilibrium systems. (United States)

    Sonnino, Giorgio


    A decade ago, a macroscopic theory for closure relations has been proposed for systems out of Onsager's region. This theory is referred to as the thermodynamic field theory (TFT). The aim of this work was to determine the nonlinear flux-force relations that respect the thermodynamic theorems for systems far from equilibrium. We propose a formulation of the TFT where one of the basic restrictions, namely, the closed-form solution for the skew-symmetric piece of the transport coefficients, has been removed. In addition, the general covariance principle is replaced by the De Donder-Prigogine thermodynamic covariance principle (TCP). The introduction of TCP requires the application of an appropriate mathematical formalism, which is referred to as the entropy-covariant formalism. By geometrical arguments, we prove the validity of the Glansdorff-Prigogine universal criterion of evolution. A new set of closure equations determining the nonlinear corrections to the linear ("Onsager") transport coefficients is also derived. The geometry of the thermodynamic space is non-Riemannian. However, it tends to be Riemannian for high values of the entropy production. In this limit, we recover the transport equations found by the old theory. Applications of our approach to transport in magnetically confined plasmas, materials submitted to temperature, and electric potential gradients or to unimolecular triangular chemical reactions can be found at references cited herein. Transport processes in tokamak plasmas are of particular interest. In this case, even in the absence of turbulence, the state of the plasma remains close to (but, it is not in) a state of local equilibrium. This prevents the transport relations from being linear.

  7. Quantifying solute transport processes: are chemically "conservative" tracers electrically conservative? (United States)

    Singha, Kamini; Li, Li; Day-Lewis, Frederick D.; Regberg, Aaron B.


    The concept of a nonreactive or conservative tracer, commonly invoked in investigations of solute transport, requires additional study in the context of electrical geophysical monitoring. Tracers that are commonly considered conservative may undergo reactive processes, such as ion exchange, thus changing the aqueous composition of the system. As a result, the measured electrical conductivity may reflect not only solute transport but also reactive processes. We have evaluated the impacts of ion exchange reactions, rate-limited mass transfer, and surface conduction on quantifying tracer mass, mean arrival time, and temporal variance in laboratory-scale column experiments. Numerical examples showed that (1) ion exchange can lead to resistivity-estimated tracer mass, velocity, and dispersivity that may be inaccurate; (2) mass transfer leads to an overestimate in the mobile tracer mass and an underestimate in velocity when using electrical methods; and (3) surface conductance does not notably affect estimated moments when high-concentration tracers are used, although this phenomenon may be important at low concentrations or in sediments with high and/or spatially variable cation-exchange capacity. In all cases, colocated groundwater concentration measurements are of high importance for interpreting geophysical data with respect to the controlling transport processes of interest.

  8. Development of the Gran Desierto sand sea, northwestern Mexico (United States)

    Blount, Grady; Lancaster, Nicholas


    Three major eolian sand populations can be recognized in the Gran Desierto sand sea of northwestern Mexico by using spectral data from the Landsat thematic mapper in conjunction with textural and mineralogical studies of surface sands. Each sand population has distinct textural, mineralogic, and spectral properties that can be related to sand-dune morphology and position with reference to source areas and transport paths of the sands. The oldest eolian sediment in the sand sea was derived from the early to middle Pleistocene Colorado River that flowed through the area of the western Gran Desierto. Subsequent inputs of eolian sands came from the area of the present Colorado River valley and the coast south of the sand sea. The spatial and temporal pattern of eolian deposition in the region has been controlled by Quaternary tectonic and climatic changes, resulting in the episodic input and deposition of sand.

  9. 锰砂/石英砂滤池与纳滤膜组合工艺去除水中砷的研究%Study on the combined process of manganese sand/quartz sand filter and nanofiltration membrane to remove the arsenic in water

    Institute of Scientific and Technical Information of China (English)

    郭成会; 张维佳; 夏圣骥


    In this paper by employing the combined process of manganese sand/quartz sand filter and nanofiltration membrane to remove the arsenic in water, and the arsenic removal effects of manganese sand/quartz sand, nanofiltration membrane (NF90, HL), and combined process of manganese sand/quartz sand and nanofiltration were studied. The result showed that As ( Ⅲ ) and As( V )could be removed effectively by manganese sand/quartz sand filtration, and the effluent arsenic concentration could be less than 50 μg/L when the influent arsenic concentration was 250 μg/L; nanofiltration membrane could remove As(V) more than 90%, but only remove As(Ⅲ)about 40~60%; combined process of manganese sand/quartz sand and nanofiltration had strong removal effect of arsenic in water, and the arsenic concentration in effluent was less than 10 μg/L,which demonstrated that the combined process was an ideal process to remove arsenic in water.%采用锰砂/石英砂滤池与纳滤膜组合工艺处理含砷水,考察锰砂/石英砂、纳滤膜(NF90、HL)、锰砂/石英砂滤池与纳滤膜组合工艺对水中砷的去除效果.结果表明,三价砷(As(Ⅲ))和五价砷(As(Ⅴ))经锰砂/石英砂过滤后能得到很好的去除,原水砷浓度250 μg/L,出水砷浓度小于50μg/L;纳滤膜对五价砷(As(Ⅴ))的去除能力很高,能达到90%以上,但是对三价砷(As(Ⅲ))的去除率不理想,为40%~60%;锰砂/石英砂复合滤池与纳滤膜组合工艺对水中砷有很好的去除效果,出水砷浓度均小于10μg/L,是理想的饮用水除砷方法.

  10. It's in the sand


    Mitchell, Clive


    Sand is sand isn’t it? Sand gets everywhere but rather than a nuisance it is a valuable, high-purity raw material. Clive Mitchell, Industrial Minerals Specialist at the British Geological Survey (BGS), talks us through what sand is, what it can be used for and how to find it. His exploration of sand takes us from the deserts of Arabia to the damp sand pits of Mansfield!

  11. Application of passive sonar technology to mineral processing and oil sands applications : if you can measure it, you can manage it

    Energy Technology Data Exchange (ETDEWEB)

    O' Keefe, C.; Viega, J.; Fernald, M. [CiDRA Corp., Wallingford, CT (United States)


    SONAR-based flow and entrained air measurement instruments were described. This new class of industrial flow and compositional analyzers was developed by CiDRA to provide new measurement insight and quantifiable value to industrial process operators. Passive sonar array-based processing units have been installed worldwide in several industrial applications and are particularly suited for a wide range of mineral processing applications, including slurry flow rate measurement and fluid characterization. This paper also described the SONAR-based, clamp-on SONARtrac technology, a scalable platform that provides several other value added measurements and information such as speed of sound, entrained air/gas, gas hold-up, and velocity profile. Oil sands, tailings and bitumen slurries present considerable measurement challenges for in-line flow measurement devices in terms of measurement accuracy, reliability and maintenance. The sonar-based technology platform has been used in a variety of oil sands processes, hydrotransport, and minerals beneficiation applications. This paper described these applications with particular reference to difficult slurry flow measurement and control in the areas of comminution and flotation such as mill discharge, hydrocyclone feed/overflow, final concentrate, thickener discharge, and tailings. 5 refs., 4 tabs., 23 figs.

  12. Prediction of naphthenic acid species degradation by kinetic and surrogate models during the ozonation of oil sands process-affected water. (United States)

    Islam, Md Shahinoor; Moreira, Jesús; Chelme-Ayala, Pamela; Gamal El-Din, Mohamed


    Oil sands process-affected water (OSPW) is a complex mixture of organic and inorganic contaminants, and suspended solids, generated by the oil sands industry during the bitumen extraction process. OSPW contains a large number of structurally diverse organic compounds, and due to variability of the water quality of different OSPW matrices, there is a need to select a group of easily measured surrogate parameters for monitoring and treatment process control. In this study, kinetic and surrogate correlation models were developed to predict the degradation of naphthenic acids (NAs) species during the ozonation of OSPW. Additionally, the speciation and distribution of classical and oxidized NA species in raw and ozonated OSPW were also examined. The structure-reactivity of NA species indicated that the reactivity of individual NA species increased as the carbon and hydrogen deficiency numbers increased. The kinetic parameters obtained in this study allowed calculating the evolution of the concentrations of the acid-extractable fraction (AEF), chemical oxygen demand (COD), and NA distributions for a given ozonation process. High correlations between the AEF and COD and NA species were found, suggesting that AEF and COD can be used as surrogate parameters to predict the degradation of NAs during the ozonation of OSPW.

  13. Study of Black Sand Particles from Sand Dunes in Badr, Saudi Arabia Using Electron Microscopy

    Directory of Open Access Journals (Sweden)

    Haider Abbas Khwaja


    Full Text Available Particulate air pollution is a health concern. This study determines the microscopic make-up of different varieties of sand particles collected at a sand dune site in Badr, Saudi Arabia in 2012. Three categories of sand were studied: black sand, white sand, and volcanic sand. The study used multiple high resolution electron microscopies to study the morphologies, emission source types, size, and elemental composition of the particles, and to evaluate the presence of surface “coatings or contaminants” deposited or transported by the black sand particles. White sand was comprised of natural coarse particles linked to wind-blown releases from crustal surfaces, weathering of igneous/metamorphic rock sources, and volcanic activities. Black sand particles exhibited different morphologies and microstructures (surface roughness compared with the white sand and volcanic sand. Morphological Scanning Electron Microscopy (SEM and Laser Scanning Microscopy (LSM analyses revealed that the black sand contained fine and ultrafine particles (50 to 500 nm ranges and was strongly magnetic, indicating the mineral magnetite or elemental iron. Aqueous extracts of black sands were acidic (pH = 5.0. Fe, C, O, Ti, Si, V, and S dominated the composition of black sand. Results suggest that carbon and other contaminant fine particles were produced by fossil-fuel combustion and industrial emissions in heavily industrialized areas of Haifa and Yanbu, and transported as cloud condensation nuclei to Douf Mountain. The suite of techniques used in this study has yielded an in-depth characterization of sand particles. Such information will be needed in future environmental, toxicological, epidemiological, and source apportionment studies.

  14. Characterization of sand lenses embedded in tills

    DEFF Research Database (Denmark)

    Kessler, Timo Christian; Klint, K.E.S.; Nilsson, B.


    of the various types of sand lenses is discussed, primarily in relation to the depositional and glaciotectonic processes they underwent. Detailed characterization of sand lenses facilitates such interpretations. Finally, the observations are linked to a more general overview of the distribution of sand lenses......Tills dominate large parts of the superficial sediments on the Northern hemisphere. These glacial diamictons are extremely heterogeneous and riddled with fractures and lenses of sand or gravel. The frequency and geometry of sand lenses within tills are strongly linked to glaciodynamic processes...... occurring in various glacial environments. This study specifically focuses on the appearance and spatial distribution of sand lenses in tills. It introduces a methodology on how to measure and characterize sand lenses in the field with regard to size, shape and degree of deformation. A set of geometric...

  15. Development and Application of the Lifting Process Pipe String for Sand Sticking-proof%防砂卡分采举升工艺管柱研制

    Institute of Scientific and Technical Information of China (English)

    李志广; 李风涛; 闫永维; 李川; 张子佳


    机械卡堵水技术在实际生产中应用越来越多,生产管柱因卡层出砂导致的砂卡管柱现象日趋严重,经常因砂卡造成管柱大修。研究一种新型分采举升工艺管柱技术,解决卡层出砂导致分采生产管柱砂卡的问题。关键技术是通过工艺管柱的优化设计及配套工具技术研制,在管柱发生砂卡时,通过上提管柱而解卡。如果上提管柱不能解卡,则可从安全释放装置处顺利释放,然后对井筒内管柱进行套洗冲砂,最后将井筒内剩余管柱依次捞出,避免油井进行大修作业。%Mechanical technology for plugging water is widely used in the actual production,and sand stick caused by sand layer in production pipe string is becoming more and more serious,often leading to workover.Therefore,developing a new type of production pipe string technology to a-void the workover caused by sand stick is necessary,the key technology is the optimization design of the lifting process pipe string and matching tool technology development,when pipe string is stuck by sand in controlled layer,it is likely to be released by rising pipe string,if this solution fails,the pipe string can be released from the safety joint smoothly,then wash sand between pipe string and casing in wellbore,finally get the pipe string out of wellbore sequentially,avoiding the workover operation.

  16. Casting Process Control of Permanent Mold with Sand Lining for Traction Sheave%曳引轮铁模覆砂铸造过程控制

    Institute of Scientific and Technical Information of China (English)

    王树成; 俞水铭; 章舟


    介绍了曳引轮铁模覆砂的生产工艺,在试生产过程中通过采取针对性措施,消除了铸件夹砂、夹渣、变形等缺陷,产品合格率大幅度提高。%The casting process of permanent mold with sand lining for traction sheave was presented. The casting defects, such as scab, slag inclusion and warping were eliminated by special measures in pilot production, and the products percent of pass were increased substantially.

  17. Transport Process of Isopropanol Aqueous Solution by Pervaporation

    Institute of Scientific and Technical Information of China (English)


    To study the transport process of isopropanol aqueous solution by pervaporation, the transport model of isopropanol and that of water at 323 K in polyvinyl alcohol(PVA) membrane were obtained in this paper. Theoretical predictions agreed well with the experimental results. The interactional parameter between water and PVA membrane is less than that between isopropanol and PVA membrane, which shows that water is preferentially dissolved in PVA membrane. The plasticizing coefficient and diffusion coefficient at infinite dilution of water are larger than those of isopropanol,which shows that the dissolution and permeation in PVA membrane of water are greater than those of isopropanol. Both the interactional parameter between water and isopropanol in the membrane and that in feed rise with the increase of isopropanol content in feed, which shows that the larger isopropanol content is, the higher selectivity of the membrane is and the more remarkable separation effect of pervaporation is.

  18. Chapman Conference on Sediment Transport Processes in Estuaries (United States)

    Perillo, Gerardo M. E.; Lavelle, J. William

    During the week of June 13-17, 1988, 72 sediment transport researchers “aggregated” at the Universidad Nacional del Sur in Bahfa Blanca, Argentina, to participate in an AGU Chapman Conference on Sediment Transport Processes in Estuaries. The main goals of the meeting were to discuss recent advances in estuarine science, to appraise promising future research directions, and to develop contacts and establish working relationships between Latin American and non-Latin- American estuarine researchers. The meeting drew participants from Argentina, Brazil, Chile, Uruguay, Venezuela, the U.S., Canada, Britain, France, the Federal Republic of Germany, The Netherlands, and South Africa. Meeting cosponsors were UNESCO, Secretaria de Ciencía y Técnica, Consejo Nacional de Investigaciones Cientificas y Técnicas, Comision de Investigaciones Cientificas de la Provincia de Buenos Aires, Universidad del Sur, Municipalidad de Bahia Blanca, Asociaciôn Argentina de Geofisicos y Geodestas (AGU sister organization), and the Instituto Argentino de Oceanografia (IADO).

  19. Hyporheic flow and transport processes: mechanisms, models, and biogeochemical implications (United States)

    Boano, Fulvio; Harvey, Judson W.; Marion, Andrea; Packman, Aaron I.; Revelli, Roberto; Ridolfi, Luca; Anders, Wörman


    Fifty years of hyporheic zone research have shown the important role played by the hyporheic zone as an interface between groundwater and surface waters. However, it is only in the last two decades that what began as an empirical science has become a mechanistic science devoted to modeling studies of the complex fluid dynamical and biogeochemical mechanisms occurring in the hyporheic zone. These efforts have led to the picture of surface-subsurface water interactions as regulators of the form and function of fluvial ecosystems. Rather than being isolated systems, surface water bodies continuously interact with the subsurface. Exploration of hyporheic zone processes has led to a new appreciation of their wide reaching consequences for water quality and stream ecology. Modern research aims toward a unified approach, in which processes occurring in the hyporheic zone are key elements for the appreciation, management, and restoration of the whole river environment. In this unifying context, this review summarizes results from modeling studies and field observations about flow and transport processes in the hyporheic zone and describes the theories proposed in hydrology and fluid dynamics developed to quantitatively model and predict the hyporheic transport of water, heat, and dissolved and suspended compounds from sediment grain scale up to the watershed scale. The implications of these processes for stream biogeochemistry and ecology are also discussed."

  20. Condensation and transport in the totally asymmetric inclusion process (TASIP) (United States)

    Knebel, Johannes; Weber, Markus F.; Krueger, Torben; Frey, Erwin

    Transport phenomena are often modeled by the hopping of particles on regular lattices or networks. Such models describe, e.g., the exclusive movement of molecular motors along microtubules: no two motors may occupy the same site. In our work, we study inclusion processes that are the bosonic analogues of the fermionic exclusion processes. In inclusion processes, many particles may occupy a single site and hopping rates depend linearly on the occupation of departure and arrival sites. Particles thus attract other particles to their own site. Condensation occurs when particles collectively cluster in one or multiple sites, whereas other sites become depleted.We showed that inclusion processes describe both the selection of strategies in evolutionary zero-sum games and the condensation of non-interacting bosons into multiple quantum states in driven-dissipative systems. The condensation is captured by the antisymmetric Lotka-Volterra equation (ALVE), which constitutes a nonlinearly coupled dynamical system. We derived an algebraic method to analyze the ALVE and to determine the condensates. Our approach allows for the design of networks that result in condensates with oscillating occupations, and yields insight into the interplay between network topology and transport properties. Deutsche Forschungsgemeinschaft (SFB-TR12), German Excellence Initiative (Nanosystems Initiative Munich), Center for NanoScience Munich.

  1. The Relationship Between Shoreline Change and Surf Zone Sand Thickness (United States)

    Miselis, J. L.; McNinch, J. E.


    There is a lack of information concerning surf zone geologic processes and their relationship to shoreline behavior despite the consensus that the two are intimately linked. Variations in sand thickness over a highly irregular migration surface close to the shoreline may influence wave dynamics and sediment transport and thus may be connected to hotspot formation. A nearshore survey, spanning 40km from north of the USACE-FRF pier in Duck, NC to just north of Oregon Inlet, was conducted using an interferometric swath bathymetry system and a chirp sub-bottom profiler. The study was conducted within 1km of the shore (in the surf zone) to investigate the processes that may be responsible for the behavior of shoreline hotspots in the area. The topmost reflector and the seafloor of the seismic profile were digitized and the depth difference between them was calculated. Though no ground truths were done in the survey area, cores collected from just north of the site suggest that the topmost reflector is a pre-modern ravinement surface (cohesive muds with layers of sand and gravel) upon which the Holocene sands migrate. An isopach map was generated and shows that the layer of sand above the first sub-bottom reflector is very thin and in some places, exposed. There are many variables that may influence hotspot behavior, including bar position and wave conditions, however, the purpose of this study is to determine if there is a spatial correlation between a thin or absent (exposed reflector) nearshore sand layer and the presence of a shoreline hotspot. In an area associated with a hotspot approximately 14km south of the USACE-FRF pier in Duck, the maximum thickness of Holocene sands was less than 2.5m. The average thickness was less than 1m (0.705m). Thicknesses that were less than 0.2m were classified as areas where the reflector was exposed and accounted for 5 percent of those calculated. It seems the thin layer of sand may represent a deficient nearshore sand source

  2. Driven transport on open filaments with interfilament switching processes (United States)

    Ghosh, Subhadip; Pagonabarraga, Ignacio; Muhuri, Sudipto


    We study a two-filament driven lattice gas model with oppositely directed species of particles moving on two parallel filaments with filament-switching processes and particle inflow and outflow at filament ends. The filament-switching process is correlated with the occupation number of the adjacent site such that particles switch filaments with finite probability only when oppositely directed particles meet on the same filament. This model mimics some of the coarse-grained features observed in context of microtubule-(MT) based intracellular transport, wherein cellular cargo loaded and off-loaded at filament ends are transported on multiple parallel MT filaments and can switch between the parallel microtubule filaments. We focus on a regime where the filaments are weakly coupled, such that filament-switching rate of particles scale inversely as the length of the filament. We find that the interplay of (off-) loading processes at the boundaries and the filament-switching process of particles leads to some distinctive features of the system. These features includes occurrence of a variety of phases in the system with inhomogeneous density profiles including localized density shocks, density difference across the filaments, and bidirectional current flows in the system. We analyze the system by developing a mean field (MF) theory and comparing the results obtained from the MF theory with the Monte Carlo (MC) simulations of the dynamics of the system. We find that the steady-state density and current profiles of particles and the phase diagram obtained within the MF picture matches quite well with MC simulation results. These findings maybe useful for studying multifilament intracellular transport.

  3. Optimal array of sand fences. (United States)

    Lima, Izael A; Araújo, Ascânio D; Parteli, Eric J R; Andrade, José S; Herrmann, Hans J


    Sand fences are widely applied to prevent soil erosion by wind in areas affected by desertification. Sand fences also provide a way to reduce the emission rate of dust particles, which is triggered mainly by the impacts of wind-blown sand grains onto the soil and affects the Earth's climate. Many different types of fence have been designed and their effects on the sediment transport dynamics studied since many years. However, the search for the optimal array of fences has remained largely an empirical task. In order to achieve maximal soil protection using the minimal amount of fence material, a quantitative understanding of the flow profile over the relief encompassing the area to be protected including all employed fences is required. Here we use Computational Fluid Dynamics to calculate the average turbulent airflow through an array of fences as a function of the porosity, spacing and height of the fences. Specifically, we investigate the factors controlling the fraction of soil area over which the basal average wind shear velocity drops below the threshold for sand transport when the fences are applied. We introduce a cost function, given by the amount of material necessary to construct the fences. We find that, for typical sand-moving wind velocities, the optimal fence height (which minimizes this cost function) is around 50 cm, while using fences of height around 1.25 m leads to maximal cost.


    Institute of Scientific and Technical Information of China (English)

    ZHANG Hong-mei; SU Bao-yu


    The transport and transformation of fluoride in sand were studied by using soil tank test under the condition of saturated water in this article. Based on the analysis of the laboratory experiments, the rules of fluorine transportation and transformation were simulated in sand by solving the advection-diffusion equation. Through comparison between computed results and observed data , it is shown that the established model and determined parameters could be used to simulate the fluoride transport in sand.

  5. Standardization of the process of smelting for sands with self-forgeling resins in the Military Industry Santa Bárbara Factory

    Directory of Open Access Journals (Sweden)

    Lina Consuelo Carvajal-Fernández


    Full Text Available This article describes the standardization of the smelting process for sands with self-forgeling resins in the Military Industry Santa Barbara Factory. The molding process was studied in the Smelter for six months, to set standards for workforce and raw materials, so that would allow truthfully evaluate the costs per kilogram of casting. 41 pieces of civil and military sectors throughout the development of the project were worked. Finally both standards were evaluated, labor as raw material for different parts, with results was evidenced improved process, essentially in workforce, while in raw material standards did not show significantly change, in this case is corroborated that existing ones are applicable to the process

  6. Determination of application possibilities of microwave heating in the curing process of water glass molding sands with fluid esters. Part 1

    Directory of Open Access Journals (Sweden)

    K. Granat


    Full Text Available This article presents results of the experimental trial of combination of the chemical method of water glass molding sands’ curing, used in foundry industry, with an innovative microwave heating. The research objective was to indicate at new areas of microwave energy application. The sands prepared, according to recommendations for curing technology, with the use of ethylene glycol diacetate, have been subject to microwave influence. The attempt at determination of microwave influence on qualitative changes of the binding bridges created during the curing process concerned such parameters as: bending and tensile strength, permeability as well as wear resistance. Moreover,we also determined the influence of microwave curing on the phenomena accompanying the process as well as bond stability (storage time of the prepared molding and core sands. It has been found, basing on the result analysis, that the innovative microwave heating might constitute a very good supplementation of the ester curing method. The advantages of the combined chemical and microwave gelation process include, among others, improvement of the described resistance and technological parameters as well as significant decrease of preparation time of foundry moulds and cores. The subject discussed in this article will be continued in its second part.

  7. Origins of late- Pleistocene coastal dune sheets, Magdalena and Guerrero Negro, from continental shelf low-stand supply (70-20 ka), under conditions of southeast littoral- and eolian-sand transport, in Baja California Sur, Mexico (United States)

    Peterson, Curt D.; Murillo-Jiménez, Janette M.; Stock, Errol; Price, David M.; Hostetler, Steve W.; Percy, David


    Shallow morpho-stratigraphic sections (n = 11) in each of two large coastal dune sheets including the Magdalena (7000 km2) and Guerrero Negro (8000 km2) dune sheets, from the Pacific Ocean side of Baja California Sur, Mexico, have been analyzed for dune deposit age. The shallow morpho-stratigraphic sections (∼2-10 m depth) include 11 new TL and 14C ages, and paleosol chronosequences, that differentiate cemented late Pleistocene dune deposits (20.7 ± 2.1 to 99.8 ± 9.4 ka) from uncemented Holocene dune deposits (0.7 ± 0.05 to at least 3.2 ± 0.3 ka). Large linear dune ridges (5-10 m in height) in the dune sheet interiors trend southeast and are generally of late Pleistocene age (∼70-20 ka). The late Pleistocene dune deposits reflect eolian transport of marine sand across the emerged continental shelf (30-50 km southeast distance) from low-stand paleo-shorelines (-100 ± 25 m elevation), which were locally oriented nearly orthogonal to modeled deep-water wave directions (∼300° TN). During the Holocene marine transgression, onshore and alongshore wave transport delivered remobilized shelf-sand deposits to the nearshore areas of the large dune sheets, building extensive barrier islands and sand spits. Submerged back-barrier lagoons generally precluded marine sand supply to dune sheet interiors in middle to late Holocene time, though exceptions occur along some ocean and lagoon shorelines. Reactivation of the late Pleistocene dune deposits in the dune sheet interiors lead to generally thin (1-3 m thickness), but widespread, covers of Holocene dune deposits (0.41 ± 0.05 to 10.5 ± 1.6 ka). Mechanical drilling will be required to penetrate indurated subsoil caliche layers to reach basal Pleistocene dune deposits.

  8. Simulation of business processes of processing and distribution of orders in transportation

    Directory of Open Access Journals (Sweden)

    Ольга Ігорівна Проніна


    Full Text Available Analyzing modern passenger transportation in Ukraine, we can conclude that with the increasing number of urban population the necessity to develop passenger traffic, as well as to improve the quality of transport services is increasing too. The paper examines the three existing models of private passenger transportation (taxi: a model with the use of dispatching service, without dispatching service model and a mixed model. An algorithm of getting an order, processing it, and its implementation according to the given model has been considered. Several arrangements schemes that characterize the operation of the system have been shown in the work as well. The interrelation of the client making an order and the driver who receives the order and executes it has been represented, the server being a connecting link between the customer and the driver and regulating the system as a whole. Business process of private passenger transportation without dispatching service was simulated. Basing on the simulation results it was proposed to supplement the model of private transportation by the making advice system, as well as improving the car selection algorithm. Advice system provides the optimum choice of the car, taking into account a lot of factors. And it will also make it possible to use more efficiently the specific additional services provided by the drivers. Due to the optimization of the order handling process it becomes possible to increase the capacity of the drivers thus increasing their profits. Passenger transportation without the use of dispatching service has some weak points and they were identified. Application of the system will improve transport structure in modern conditions, and improve the transportation basing on modern operating system

  9. Engineered Barrier System Degradation, Flow, and Transport Process Model Report

    Energy Technology Data Exchange (ETDEWEB)

    E.L. Hardin


    The Engineered Barrier System Degradation, Flow, and Transport Process Model Report (EBS PMR) is one of nine PMRs supporting the Total System Performance Assessment (TSPA) being developed by the Yucca Mountain Project for the Site Recommendation Report (SRR). The EBS PMR summarizes the development and abstraction of models for processes that govern the evolution of conditions within the emplacement drifts of a potential high-level nuclear waste repository at Yucca Mountain, Nye County, Nevada. Details of these individual models are documented in 23 supporting Analysis/Model Reports (AMRs). Nineteen of these AMRs are for process models, and the remaining 4 describe the abstraction of results for application in TSPA. The process models themselves cluster around four major topics: ''Water Distribution and Removal Model, Physical and Chemical Environment Model, Radionuclide Transport Model, and Multiscale Thermohydrologic Model''. One AMR (Engineered Barrier System-Features, Events, and Processes/Degradation Modes Analysis) summarizes the formal screening analysis used to select the Features, Events, and Processes (FEPs) included in TSPA and those excluded from further consideration. Performance of a potential Yucca Mountain high-level radioactive waste repository depends on both the natural barrier system (NBS) and the engineered barrier system (EBS) and on their interactions. Although the waste packages are generally considered as components of the EBS, the EBS as defined in the EBS PMR includes all engineered components outside the waste packages. The principal function of the EBS is to complement the geologic system in limiting the amount of water contacting nuclear waste. A number of alternatives were considered by the Project for different EBS designs that could provide better performance than the design analyzed for the Viability Assessment. The design concept selected was Enhanced Design Alternative II (EDA II).

  10. Modelling of transport phenomena and defects in crystal growth processes

    Indian Academy of Sciences (India)

    S Pendurti; H Zhang; V Prasad


    A brief review of single crystal growth techniques and the associated problems is presented. Emphasis is placed on models for various transport and defect phenomena involoved in the growth process with the ultimate aim of integrating them into a comprehensive numerical model. The sources of dislocation nucleation in the growing crystal are discussed, and the propagation and multiplication of these under the action of thermal stresses is discussed. A brief description of a high-level numerical technique based on multiple adaptive grid generation and finite volume discretization is presented, followed by the result of a representative numerical simulation.

  11. Representing Microbial Processes in Environmental Reactive Transport Models (United States)

    van Cappellen, P.


    Microorganisms play a key role in the biogeochemical functioning of the earth's surface and shallow subsurface. In the context of reactive transport modeling, a major challenge is to derive, parameterize, calibrate and verify mathematical expressions for microbially-mediated reactions in the environmental. This is best achieved by combining field observations, laboratory experiments, theoretical principles and modeling. Here, I will illustrate such an integrated approach for the case of microbial respiration processes in aquatic sediments. Important issues that will be covered include experimental design, model consistency and performance, as well as the bioenergetics and transient behavior of geomicrobial reaction systems.

  12. Advances in carbon dioxide compression and pipeline transportation processes

    CERN Document Server

    Witkowski, Andrzej; Majkut, Mirosław; Rulik, Sebastian; Stolecka, Katarzyna


    Providing a comprehensive analysis of CO2 compression, transportation processes and safety issues for post combustion CO2 capture applications for a 900 MW pulverized hard coal-fired power plant, this book assesses techniques for boosting the pressure of CO2 to pipeline pressure values with a minimal amount of energy. Four different types of compressors are examined in detail: a conventional multistage centrifugal compressor, integrally geared centrifugal compressor, supersonic shock wave compressor, and pump machines. The study demonstrates that the total compression power is closely related

  13. Rheological Characterization of Green Sand Flow

    DEFF Research Database (Denmark)

    Jabbaribehnam, Mirmasoud; Spangenberg, Jon; Hovad, Emil


    The main aim of this paper is to characterize experimentally the flow behaviour of the green sand that is used for casting of sand moulds. After the sand casting process is performed, the sand moulds are used for metal castings. The rheological properties of the green sand is important to quantify...... module for characterizing granular materials. The new module enables viscosity measurements of the green sand as function of the shear rate at different flow rates, i.e. 0, 2, 4, 6, 8, 10, 12 and 15 L/min. The results show generally that the viscosity decreases with both the shear- and flow rate....... In addition, the measurements show that the green sand flow follows a shear-thinning behaviour even after the full fluidization point....

  14. Recent advances in waterglass sand technologies

    Institute of Scientific and Technical Information of China (English)

    ZHU Chun-xi


    This paper reports some new understandings and advances in waterglass sand technologies. The multiple chemical modification process can increase the binding strength of the waterglass sand by up to 50%-70%.Therefore, the additions of the modified waterglass can be decreased to 3.0%-4.0% for CO2 process and to 2.0%-2.5% for organic ester hardening process, and greatly improve the collapsibility and reclaimability of the sand. Based on the new understandings and experimental results reported in this paper, several original ideas, such as nano modification, have been proposed to promote advances of waterglass sand technologies,

  15. Industrial sand and gravel (United States)

    Dolley, T.P.


    Domestic production of industrial sand and gravel in 2012 was about 49.5 Mt (55 million st), increasing 13 percent compared with that of 2011. Some important end uses for industrial sand and gravel include abrasives, filtration, foundry, glassmaking, hydraulic fracturing sand (frac sand) and silicon metal applications.

  16. Features, Events and Processes in UZ Flow and Transport

    Energy Technology Data Exchange (ETDEWEB)

    P. Persoff


    The purpose of this report is to evaluate and document the inclusion or exclusion of the unsaturated zone (UZ) features, events, and processes (FEPs) with respect to modeling that supports the total system performance assessment (TSPA) for license application (LA) for a nuclear waste repository at Yucca Mountain, Nevada. A screening decision, either Included or Excluded, is given for each FEP, along with the technical basis for the screening decision. This information is required by the U.S. Nuclear Regulatory Commission (NRC) in 10 CFR 63.114 (d, e, and f) [DIRS 173273]. The FEPs deal with UZ flow and radionuclide transport, including climate, surface water infiltration, percolation, drift seepage, and thermally coupled processes. This analysis summarizes the implementation of each FEP in TSPA-LA (that is, how the FEP is included) and also provides the technical basis for exclusion from TSPA-LA (that is, why the FEP is excluded). This report supports TSPA-LA.

  17. Analysis of reaction and transport processes in zinc air batteries

    CERN Document Server

    Schröder, Daniel


    This book contains a novel combination of experimental and model-based investigations, elucidating the complex processes inside zinc air batteries. The work presented helps to answer which battery composition and which air-composition should be adjusted to maintain stable and efficient charge/discharge cycling. In detail, electrochemical investigations and X-ray transmission tomography are applied on button cell zinc air batteries and in-house set-ups. Moreover, model-based investigations of the battery anode and the impact of relative humidity, active operation, carbon dioxide and oxygen on zinc air battery operation are presented. The techniques used in this work complement each other well and yield an unprecedented understanding of zinc air batteries. The methods applied are adaptable and can potentially be applied to gain further understanding of other metal air batteries. Contents Introduction on Zinc Air Batteries Characterizing Reaction and Transport Processes Identifying Factors for Long-Term Stable O...

  18. Reported Design Processes for Accessibility in Rail Transport

    DEFF Research Database (Denmark)

    Herriott, Richard; Cook, Sharon


    ). The research found that the role of users in the design process of manufacturers was limited and that compliance with industry standards was the dominant means to achieving accessibility goals. Design consultancies were willing to apply more user-centred design if the client requested it. Where operators were......Accessibility is a fundamental requirement in public transport (PT) yet there exists little research on design for accessibility or inclusive design (ID) in this area. This paper sets out to discover what methods are used in the rail sector to achieve accessibility goals and to examine how far...... these methods deviate from user-centred and ID norms. Semi-structured interviews were conducted with nine rolling stock producers, operators and design consultancies. The purpose was to determine if ID design methods are used explicitly and the extent to which the processes used conformed to ID (if at all...

  19. Analysis of suspended solids transport processes in primary settling tanks. (United States)

    Patziger, Miklós; Kiss, Katalin


    The paper shows the results of a long-term research comprising FLUENT-based numerical modeling, in situ measurements and laboratory tests to analyze suspended solids (SS) transport processes in primary settling tanks (PSTs). The investigated PST was one of the rectangular horizontal flow PSTs at a large municipal wastewater treatment plant (WWTP) of a capacity of 500,000 population equivalent. Many middle-sized and large WWTPs are equipped with such PSTs. The numerical PST model was calibrated and validated based on the results of comprehensive in situ flow and SS concentration measurements from low (5 m/h) up to quite high surface overflow rates of 9.5 and 13.0 m/h and on settling and other laboratory tests. The calibrated and validated PST model was also successfully used for evaluation of some slight modifications of the inlet geometry (removing lamellas, installing a flocculation 'box', shifting the inlet into a 'bottom-near' or into a 'high' position), which largely affect PST behavior and performance. The investigations provided detailed insight into the flow and SS transport processes within the investigated PST, which strongly contributes to hydrodynamically driven design and upgrading of PSTs.

  20. Imaging on a Shoestring: Cost-Effective Technologies for Probing Vadose Zone Transport Processes (United States)

    Corkhill, C.; Bridge, J. W.; Barns, G.; Fraser, R.; Romero-Gonzalez, M.; Wilson, R.; Banwart, S.


    Key barriers to the widespread uptake of imaging technology for high spatial resolution monitoring of porous media systems are cost and accessibility. X-ray tomography, magnetic resonance imaging (MRI), gamma and neutron radiography require highly specialised equipment, controlled laboratory environments and/or access to large synchrotron facilities. Here we present results from visible light, fluorescence and autoradiographic imaging techniques developed at low cost and applied in standard analytical laboratories, adapted where necessary at minimal capital expense. UV-visible time lapse fluorescence imaging (UV-vis TLFI) in a transparent thin bed chamber enabled microspheres labelled with fluorescent dye and a conservative fluorophore solute (disodium fluorescein) to be measured simultaneously in saturated, partially-saturated and actively draining quartz sand to elucidate empirical values for colloid transport and deposition parameters distributed throughout the flow field, independently of theoretical approximations. Key results include the first experimental quantification of the effects of ionic strength and air-water interfacial area on colloid deposition above a capillary fringe, and the first direct observations of particle mobilisation and redeposition by moving saturation gradients during drainage. UV-vis imaging was also used to study biodegradation and reactive transport in a variety of saturated conditions, applying fluorescence as a probe for oxygen and nitrate concentration gradients, pH, solute transport parameters, reduction of uranium, and mapping of two-dimensional flow fields around a model dipole flow borehole system to validate numerical models. Costs are low: LED excitation sources (< US 50), flow chambers (US 200) and detectors (although a complete scientific-grade CCD set-up costs around US$ 8000, robust datasets can be obtained using a commercial digital SLR camera) mean that set-ups can be flexible to meet changing experimental

  1. Understanding the transport processes in polymer electrolyte membrane fuel cells (United States)

    Cheah, May Jean

    Polymer electrolyte membrane (PEM) fuel cells are energy conversion devices suitable for automotive, stationary and portable applications. An engineering challenge that is hindering the widespread use of PEM fuel cells is the water management issue, where either a lack of water (resulting in membrane dehydration) or an excess accumulation of liquid water (resulting in fuel cell flooding) critically reduces the PEM fuel cell performance. The water management issue is addressed by this dissertation through the study of three transport processes occurring in PEM fuel cells. Water transport within the membrane is a combination of water diffusion down the water activity gradient and the dragging of water molecules by protons when there is a proton current, in a phenomenon termed electro-osmotic drag, EOD. The impact of water diffusion and EOD on the water flux across the membrane is reduced due to water transport resistance at the vapor/membrane interface. The redistribution of water inside the membrane by EOD causes an overall increase in the membrane resistance that regulates the current and thus EOD, thereby preventing membrane dehydration. Liquid water transport in the PEM fuel cell flow channel was examined at different gas flow regimes. At low gas Reynolds numbers, drops transitioned into slugs that are subsequently pushed out of the flow channel by the gas flow. The slug volume is dependent on the geometric shape, the surface wettability and the orientation (with respect to gravity) of the flow channel. The differential pressure required for slug motion primarily depends on the interfacial forces acting along the contact lines at the front and the back of the slug. At high gas Reynolds number, water is removed as a film or as drops depending on the flow channel surface wettability. The shape of growing drops at low and high Reynolds number can be described by a simple interfacial energy minimization model. Under flooding conditions, the fuel cell local current


    In this report, we summarize a portion of the results of a large-scale tracer test conducted at the U. S. Geological Survey research site on Cape Cod, Massachusetts. The site is located on a large sand and gravel glacial outwash plain in an unconfined aquifer. In April 1993, ab...

  3. Natural and human controls of the Holocene evolution of the beach, aeolian sand and dunes of Caesarea (Israel) (United States)

    Roskin, J.; Sivan, D.; Shtienberg, G.; Roskin, E.; Porat, N.; Bookman, R.


    The study focuses on the Holocene appearance, chronology and drivers of beach sand deposition and inland aeolian sand transport around the Roman-Byzantine ruins of Caesarea, Israel. Beach sand, sand sheets, nebkha, linear and transverse dunes as well as parabolic and transverse interdunes along two transects were sampled in the current study down to their substrate. Sixteen new optically stimulated luminescence ages cluster at ∼5.9-3.3 ka, ∼1.2-1.1 ka (800-900 AD) and ∼190-120 years ago (1825-1895 AD) indicating times of middle and late Holocene sand sheet depositions and historical dune stabilization. The first age cluster indicates that beach sand accumulated when rates of global sea level rise declined around 6-5 ka. Until ∼4 ka sand sheets encroached up to 2.5 km inland. Historical and archaeological evidence points to sand mobilization since the first century AD. Sand sheets dating to 1.2-1.1 ka, coevally found throughout the dunefield represent sand stabilization due to vegetation reestablishment attributed to gradual and fluctuating decline in human activity from the middle Early Islamic period until the 10th century. Historical and chronological evidence of the existence of transverse and coppice dunes from the 19th century suggest that dunes only formed in the last few centuries. The study illustrates the initial role of natural processes, in this case decline in global sea level rise and the primary and later role of fluctuating human activity upon coastal sand mobility. The study distinguishes between sand sheets and dunes and portrays them as sensors of environmental changes.

  4. An omic approach for the identification of oil sands process-affected water compounds using multivariate statistical analysis of ultrahigh resolution mass spectrometry datasets. (United States)

    Chen, Yuan; McPhedran, Kerry N; Perez-Estrada, Leonidas; Gamal El-Din, Mohamed


    Oil sands process-affected water (OSPW) is a major environmental issue due to its acute and chronic toxicity to aquatic life. Advanced oxidation processes are promising treatments to successfully degrade toxic OSPW compounds. This study applied high resolution mass spectrometry to detect over 1000 compounds in OSPW samples after treatments including general ozonation, and ozone with carbonate, tert-butyl-alcohol, carbonate/tert-butyl-alcohol, tetranitromethane, or iron. Hierarchal clustering analysis showed that samples clustered based on sampling time and principal component analysis corroborated these results while also providing information on significant markers responsible for the clustering. Some markers were uniquely present in certain treatment conditions, while others showed variable behaviors in two or more treatments due to the presence of scavengers/catalysts. This advanced approach to monitoring significant changes of markers by using multivariate analysis can be invaluable for future work on OSPW treatment by-products and their potential toxicity to receiving environment organisms.

  5. 23 CFR 450.306 - Scope of the metropolitan transportation planning process. (United States)


    ... Programming § 450.306 Scope of the metropolitan transportation planning process. (a) The metropolitan transportation planning process shall be continuous, cooperative, and comprehensive, and provide for... shall be reflected, as appropriate, in the metropolitan transportation planning process. The degree of...

  6. 23 CFR 450.206 - Scope of the statewide transportation planning process. (United States)


    ... 23 Highways 1 2010-04-01 2010-04-01 false Scope of the statewide transportation planning process....206 Scope of the statewide transportation planning process. (a) Each State shall carry out a continuing, cooperative, and comprehensive statewide transportation planning process that provides for...

  7. Potential of capillary electrophoresis mass spectrometry for the characterization and monitoring of amine-derivatized naphthenic acids from oil sands process-affected water. (United States)

    MacLennan, Matthew S; Tie, Cai; Kovalchik, Kevin; Peru, Kerry M; Zhang, Xinxiang; Headley, John V; Chen, David D Y


    Capillary electrophoresis coupled to mass spectrometry (CE-MS) was used for the analysis of naphthenic acid fraction compounds (NAFCs) of oil sands process-affected water (OSPW). A standard mixture of amine-derivatized naphthenic acids is injected directly onto the CE column and analyzed by CE-MS in less than 15min. Time of flight MS analysis (TOFMS), optimized for high molecular weight ions, showed NAFCs between 250 and 800m/z. With a quadrupole mass analyzer, only low-molecular weight NAFCs (between 100 and 450m/z) are visible under our experimental conditions. Derivatization of NAFCs consisted of two-step amidation reactions mediated by 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC), or mediated by a mixture of EDC and N-hydroxysuccinimide, in dimethyl sulfoxide, dichloromethane or ethyl acetate. The optimum background electrolyte composition was determined to be 30% (V/V) methanol in water and 2% (V/V) formic acid. NAFCs extracted from OSPW in the Athabasca oil sands region were used to demonstrate the feasibility of CE-MS for the analysis of NAFCs in environmental samples, showing that the labeled naphthenic acids are in the mass range of 350 to 1500m/z. Copyright © 2016. Published by Elsevier B.V.

  8. Naphthenic Acid Mixtures from Oil Sands Process-Affected Water Enhance Differentiation of Mouse Embryonic Stem Cells and Affect Development of the Heart. (United States)

    Mohseni, Paria; Hahn, Noah A; Frank, Richard A; Hewitt, L Mark; Hajibabaei, Mehrdad; Van Der Kraak, Glen


    Extraction of petrochemicals from the surface mining of oil sand deposits results in generation of large volumes of oil sands process-affected water (OSPW). Naphthenic acids (NA) are generally considered to be among the most toxic components of OSPW. Previous studies have shown that NAs are toxic to aquatic organisms, however knowledge of their effects on mammalian health and development is limited. In the present study, we evaluated the developmental effects of an NA extract prepared from fresh OSPW on differentiating mouse embryonic stem cells (ESC). We found that treatment of differentiating cells with the NA extract at noncytotoxic concentrations alters expression of various lineage specification markers and development of the heart. Notably, expression of cardiac specific markers such as Nkx2.5, Gata4, and Mef2c were significantly up-regulated. Moreover, exposure to the NA extract enhanced differentiation of embryoid bodies and resulted in the early appearance of spontaneously beating clusters. Interestingly, exposure of undifferentiated mouse ESCs to the NA extract did not change the expression level of pluripotency markers (i.e., Oct4, Nanog, and Sox2). Altogether, these data identify some of the molecular pathways affected by components within this NA extract during differentiation of mammalian cells.

  9. Processo da retrolavagem em filtros de areia usados na irrigação localizada Backwash process in sand filters used in localized irrigation

    Directory of Open Access Journals (Sweden)

    Juan C Salcedo


    Full Text Available O processo da retrolavagem consiste na passagem da água através do filtro em sentido contrário ao fluxo de filtragem com o objetivo de remover partículas orgânicas e inorgânicas retidas no meio filtrante. O projeto de filtros de areia com configurações ineficientes e a ocorrência de condições operacionais inadequadas contribuem para limitar o desempenho desse processo, causando deficiências na limpeza dos meios filtrantes e comprometendo o funcionamento dos sistemas de irrigação localizada. O objetivo do presente trabalho é proporcionar uma revisão sobre os conceitos associados ao processo da retrolavagem nos filtros de areia, relacionando informações existentes na literatura com experiências de laboratório. Foi gerado um texto básico com informações técnico-científicas sobre o tema, visando a criar um momento de reflexão sobre o processo de retrolavagem e a contribuir para a melhoria do desempenho desses equipamentos na irrigação localizada.The backwash process consists of water passing through the filter in the opposite direction of the filtering flow to remove organic and inorganic particles of media filter. Inefficient sand filters designs and the occurrence of inadequate operating conditions contribute to restrict the process performance, causing deficiencies in the filter cleaning and compromise the operation of localized irrigation systems. The objective of this study is to provide a review about concepts associated with the backwash process in sand filters, relating literature information with laboratory experiments. A basic documentation was produced with technical and scientific information on this subject to create a reflection about the backwash process and contribute to the improvement of the equipment performance in the localized irrigation.

  10. Stochastic simulations of cargo transport by processive molecular motors. (United States)

    Korn, Christian B; Klumpp, Stefan; Lipowsky, Reinhard; Schwarz, Ulrich S


    We use stochastic computer simulations to study the transport of a spherical cargo particle along a microtubule-like track on a planar substrate by several kinesin-like processive motors. Our newly developed adhesive motor dynamics algorithm combines the numerical integration of a Langevin equation for the motion of a sphere with kinetic rules for the molecular motors. The Langevin part includes diffusive motion, the action of the pulling motors, and hydrodynamic interactions between sphere and wall. The kinetic rules for the motors include binding to and unbinding from the filament as well as active motor steps. We find that the simulated mean transport length increases exponentially with the number of bound motors, in good agreement with earlier results. The number of motors in binding range to the motor track fluctuates in time with a Poissonian distribution, both for springs and cables being used as models for the linker mechanics. Cooperativity in the sense of equal load sharing only occurs for high values for viscosity and attachment time.

  11. Features, Events, and Processes in SZ Flow and Transport

    Energy Technology Data Exchange (ETDEWEB)

    K. Economy


    This analysis report evaluates and documents the inclusion or exclusion of the saturated zone (SZ) features, events, and processes (FEPs) with respect to modeling used to support the total system performance assessment (TSPA) for license application (LA) of a nuclear waste repository at Yucca Mountain, Nevada. A screening decision, either ''Included'' or ''Excluded'', is given for each FEP along with the technical basis for the decision. This information is required by the U.S. Nuclear Regulatory Commission (NRC) at 10 CFR 63.114 (d), (e), (f) (DIRS 156605). This scientific report focuses on FEP analysis of flow and transport issues relevant to the SZ (e.g., fracture flow in volcanic units, anisotropy, radionuclide transport on colloids, etc.) to be considered in the TSPA model for the LA. For included FEPs, this analysis summarizes the implementation of the FEP in TSPA-LA (i.e., how the FEP is included). For excluded FEPs, this analysis provides the technical basis for exclusion from TSPA-LA (i.e., why the FEP is excluded).

  12. Features, Events, and Processes in SZ Flow and Transport

    Energy Technology Data Exchange (ETDEWEB)

    S. Kuzio


    This analysis report evaluates and documents the inclusion or exclusion of the saturated zone (SZ) features, events, and processes (FEPs) with respect to modeling used to support the total system performance assessment (TSPA) for license application (LA) of a nuclear waste repository at Yucca Mountain, Nevada. A screening decision, either Included or Excluded, is given for each FEP along with the technical basis for the decision. This information is required by the U.S. Nuclear Regulatory Commission (NRC) at 10 CFR 63.11(d), (e), (f) [DIRS 173273]. This scientific report focuses on FEP analysis of flow and transport issues relevant to the SZ (e.g., fracture flow in volcanic units, anisotropy, radionuclide transport on colloids, etc.) to be considered in the TSPA model for the LA. For included FEPs, this analysis summarizes the implementation of the FEP in TSPA-LA (i.e., how the FEP is included). For excluded FEPs, this analysis provides the technical basis for exclusion from TSPA-LA (i.e., why the FEP is excluded).

  13. Predictive hydrogeochemical modelling of bauxite residue sand in field conditions. (United States)

    Wissmeier, Laurin; Barry, David A; Phillips, Ian R


    The suitability of residue sand (the coarse fraction remaining from Bayer's process of bauxite refining) for constructing the surface cover of closed bauxite residue storage areas was investigated. Specifically, its properties as a medium for plant growth are of interest to ensure residue sand can support a sustainable ecosystem following site closure. The geochemical evolution of the residue sand under field conditions, its plant nutrient status and soil moisture retention were studied by integrated modelling of geochemical and hydrological processes. For the parameterization of mineral reactions, amounts and reaction kinetics of the mineral phases natron, calcite, tricalcium aluminate, sodalite, muscovite and analcime were derived from measured acid neutralization curves. The effective exchange capacity for ion adsorption was measured using three independent exchange methods. The geochemical model, which accounts for mineral reactions, cation exchange and activity corrected solution speciation, was formulated in the geochemical modelling framework PHREEQC, and partially validated in a saturated-flow column experiment. For the integration of variably saturated flow with multi-component solute transport in heterogeneous 2D domains, a coupling of PHREEQC with the multi-purpose finite-element solver COMSOL was established. The integrated hydrogeochemical model was applied to predict water availability and quality in a vertical flow lysimeter and a cover design for a storage facility using measured time series of rainfall and evaporation from southwest Western Australia. In both scenarios the sand was fertigated and gypsum-amended. Results show poor long-term retention of fertilizer ions and buffering of the pH around 10 for more than 5 y of leaching. It was concluded that fertigation, gypsum amendment and rainfall leaching alone were insufficient to render the geochemical conditions of residue sand suitable for optimal plant growth within the given timeframe. The

  14. Engineering charge transport by heterostructuring solution-processed semiconductors (United States)

    Voznyy, Oleksandr; Sutherland, Brandon R.; Ip, Alexander H.; Zhitomirsky, David; Sargent, Edward H.


    Solution-processed semiconductor devices are increasingly exploiting heterostructuring — an approach in which two or more materials with different energy landscapes are integrated into a composite system. Heterostructured materials offer an additional degree of freedom to control charge transport and recombination for more efficient optoelectronic devices. By exploiting energetic asymmetry, rationally engineered heterostructured materials can overcome weaknesses, augment strengths and introduce emergent physical phenomena that are otherwise inaccessible to single-material systems. These systems see benefit and application in two distinct branches of charge-carrier manipulation. First, they influence the balance between excitons and free charges to enhance electron extraction in solar cells and photodetectors. Second, they promote radiative recombination by spatially confining electrons and holes, which increases the quantum efficiency of light-emitting diodes. In this Review, we discuss advances in the design and composition of heterostructured materials, consider their implementation in semiconductor devices and examine unexplored paths for future advancement in the field.

  15. Oil sand production and processing. Technology, economy, environmental aspects. 2. ed.; Oelsandgewinnung und -verarbeitung. Technik, Oekonomie, Umweltaspekte

    Energy Technology Data Exchange (ETDEWEB)

    Meyer-Renschhausen, Martin


    The nearing decline in global oil production with all its consequences gives rise to the question as to possible alternative technologies, both on the application and the supply side. What contribution can come from a more efficient use of oil? What other liquid fuels can replace today's supply of crude oil? What role will unconventional oil resources play in the future? What quantities of oil can be made available from these reserves and over which time horizons? What restrictions exist on their exploitation? The purpose of the present study was to examine these questions for the example of one of the most significant alternative technologies on the supply side, namely that of unconventional oil resources. Since unconventional oil resources are very heterogeneous in terms of deposit characteristics, oil quality and exploitation technologies, the present study was restricted to a single type, namely that of oil sand extraction. This is currently the furthest developed unconventional oil resource both technically and economically, making it an ideal choice for a case study on the opportunities and risks of unconventional oil resources.

  16. Eastern Scheldt Sand, Baskarp Sand No. 15

    DEFF Research Database (Denmark)

    Andersen, A. T; Madsen, E. B.; Schaarup-Jensen, A. L.

    The present data report contains data from 13 drained triaxial tests, performed on two different sand types in the Soil Mechanics Laboratory at Aalborg University in March, 1997. Two tests have been performed on Baskarp Sand No. 15, which has already ken extensively tested in the Soil Mechanics...... Laboratory. The remaining 11 triaxial tests have ben performed on Eastern Scheldt Sand, which is a material not yet investigated at the Soil Mechanics Laboratory. In the first pari of this data report, the characteristics of the two sand types in question will be presented. Next, a description...

  17. Development of Modeling Methods and Tools for Predicting Coupled Reactive Transport Processes in Porous Media at Multiple Scales

    Energy Technology Data Exchange (ETDEWEB)

    Clement, T Prabhakar; Barnett, Mark O; Zheng, Chunmiao; Jones, Norman L


    DE-FG02-06ER64213: Development of Modeling Methods and Tools for Predicting Coupled Reactive Transport Processes in Porous Media at Multiple Scales Investigators: T. Prabhakar Clement (PD/PI) and Mark O. Barnett (Auburn), Chunmiao Zheng (Univ. of Alabama), and Norman L. Jones (BYU). The objective of this project was to develop scalable modeling approaches for predicting the reactive transport of metal contaminants. We studied two contaminants, a radioactive cation [U(VI)] and a metal(loid) oxyanion system [As(III/V)], and investigated their interactions with two types of subsurface materials, iron and manganese oxyhydroxides. We also developed modeling methods for describing the experimental results. Overall, the project supported 25 researchers at three universities. Produced 15 journal articles, 3 book chapters, 6 PhD dissertations and 6 MS theses. Three key journal articles are: 1) Jeppu et al., A scalable surface complexation modeling framework for predicting arsenate adsorption on goethite-coated sands, Environ. Eng. Sci., 27(2): 147-158, 2010. 2) Loganathan et al., Scaling of adsorption reactions: U(VI) experiments and modeling, Applied Geochemistry, 24 (11), 2051-2060, 2009. 3) Phillippi, et al., Theoretical solid/solution ratio effects on adsorption and transport: uranium (VI) and carbonate, Soil Sci. Soci. of America, 71:329-335, 2007

  18. 混配土替代煤粉的型砂工艺及在KW线上的生产实践%Molding-sand Process of Additrol instead of Coal Dust and Its Application in KW Molding Line

    Institute of Scientific and Technical Information of China (English)



    使用混配土(Additrol)替代煤粉的型砂工艺,结合KW静压造型线铸件生产对型砂性能的实际要求,对型砂配方(如新砂、膨润土的加入量)进行了调整,对型砂性能如紧实率、水分、含泥量等参数进行了调整和优化.经生产验证,该工艺可提高型砂的综合性能,降低造型废型率、铸件废品率,降低了生产成本.%Using additrol instead of coal dust in molding-sand technology, based on the sand parameters which are required by KW molding line, the sand ratio was adjusted, such as new sand, bentonite etc, and the sand parameters are optimized, such as CB, moisture, AFS clay. Production proven that the process can improve the integrated performance of the sand, reduce the scrap rate in molding and the scrap rate of casting, and reduce production costs.

  19. A Cloud Computing Model for Optimization of Transport Logistics Process

    Directory of Open Access Journals (Sweden)

    Benotmane Zineb


    Full Text Available In any increasing competitive environment and even in companies; we must adopt a good logistic chain management policy which is the main objective to increase the overall gain by maximizing profits and minimizing costs, including manufacturing costs such as: transaction, transport, storage, etc. In this paper, we propose a cloud platform of this chain logistic for decision support; in fact, this decision must be made to adopt new strategy for cost optimization, besides, the decision-maker must have knowledge on the consequences of this new strategy. Our proposed cloud computing platform has a multilayer structure; this later is contained from a set of web services to provide a link between applications using different technologies; to enable sending; and receiving data through protocols, which should be understandable by everyone. The chain logistic is a process-oriented business; it’s used to evaluate logistics process costs, to propose optimal solutions and to evaluate these solutions before their application. As a scenario, we have formulated the problem for the delivery process, and we have proposed a modified Bin-packing algorithm to improve vehicles loading.

  20. Dynamical models for sand ripples beneath surface waves

    DEFF Research Database (Denmark)

    Andersen, Ken Haste; Chabanol, M.-L.; v. Hecke, M.


    We introduce order parameter models for describing the dynamics of sand ripple patterns under oscillatory flow. A crucial ingredient of these models is the mass transport between adjacent ripples, which we obtain from detailed numerical simulations for a range of ripple sizes. Using this mass...... transport function, our models predict the existence of a stable band of wave numbers limited by secondary instabilities. Small ripples coarsen in our models and this process leads to a sharply selected final wave number, in agreement with experimental observations....

  1. Global sand trade is paving the way for a tragedy of the sand commons (United States)

    Torres, A.; Brandt, J.; Lear, K.; Liu, J.


    In the first 40 years of the 21st century, planet Earth is highly likely to experience more urban land expansion than in all of history, an increase in transportation infrastructure by more than a third, and a great variety of land reclamation projects. While scientists are beginning to quantify the deep imprint of human infrastructure on biodiversity at large scales, its off-site impacts and linkages to sand mining and trade have been largely ignored. Sand is the most widely used building material in the world. With an ever-increasing demand for this resource, sand is being extracted at rates that far exceed its replenishment, and is becoming increasingly scarce. This has already led to conflicts around the world and will likely lead to a "tragedy of the sand commons" if sustainable sand mining and trade cannot be achieved. We investigate the environmental and socioeconomic interactions over large distances (telecouplings) of infrastructure development and sand mining and trade across diverse systems through transdisciplinary research and the recently proposed telecoupling framework. Our research is generating a thorough understanding of the telecouplings driven by an increasing demand for sand. In particular, we address three main research questions: 1) Where are the conflicts related to sand mining occurring?; 2) What are the major "sending" and "receiving" systems of sand?; and 3) What are the main components (e.g. causes, effects, agents, etc.) of telecoupled systems involving sand mining and trade? Our results highlight the role of global sand trade as a driver of environmental degradation that threatens the integrity of natural systems and their capacity to deliver key ecosystem services. In addition, infrastructure development and sand mining and trade have important implications for other sustainability challenges such as over-fishing and global warming. This knowledge will help to identify opportunities and tools to better promote a more sustainable use

  2. Sand Bed Morphodynamics under Standing Waves and Vegetated Conditions (United States)

    Landry, B. J.; Garcia, M. H.


    Littoral processes such as sediment transport, wave attenuation, and boundary layer development are governed by the presence of bathymetric features, which include large-scale sand bars upon which smaller-scale sand ripples are superimposed, as well as the presence of submarine vegetation. Numerous studies on sand ripples and bars have aided to elucidate the dynamics in oscillatory flows; however, the effect of vegetation on the system is less understood. Recent laboratory studies have focused on quantifying wave attenuation by emergent vegetation as a natural method to mitigate storm surges. The emergent vegetation, while promising for coastal protection, alters sediment transport rates directly by the physical presence of the plants near the bed and indirectly from reduction in near-bed shear stresses due to attenuated wave energy. The experimental work herein focuses on the area near the deeply submerged vegetated canopy limit (current work has a ratio of mean still water depth to plant height, H/h, = 7.9) to minimize the effect on the surface waves and discern the direct impact vegetation has on sand bed morphodynamics. Experiments were conducted in the large wave tank (49-m long by 1.83-m wide by 1.22-m deep) in the Ven Te Chow Hydrosystems Laboratory at the University of Illinois in which a high reflection wave forcing was used over a uniform sand bed with a 0.25-mm median sediment diameter in which staggered and uniform arrangements of idealized vegetation (i.e., 6.35-mm diameter rigid wooden cylinders) were positioned along the bed (e.g., at predetermined sand bar troughs and over an entire sand bar). The resulting bathymetric evolution from the vegetated case experiments were compared to the base case of no vegetation using two optical methods: a high-resolution laser displacement sensor for three-dimensional surveys and digitized profiles via high-definition panoramic images of the entire test section. The experimental findings illustrate the profound

  3. Effect of impurities on kinetic transport processes in fusion plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Braun, Stefanie


    Within the framework of this thesis, different problems arising in connection with impurities have been investigated. Collisional damping of zonal flows in tokamaks: Since the Coulomb collision frequency increases with increasing ion charge, heavy, highly charged impurities play an important role in this process. The effect of such impurities on the linear response of the plasma to an external potential perturbation, as caused by zonal flows, is calculated with analytical methods. In comparison with a pure plasma, the damping of the flows occurs, as expected, considerably faster; for experimentally relevant parameters, the enhancement exceeds the effective charge Z{sub eff} of the plasma. Impurity transport driven by microturbulence in tokamaks: With regard to impurities, it is especially important whether the resulting flows are directed inwards or outwards, since they are deleterious for core energy confinement on the one hand, but on the other hand help protecting plasma-facing components from too high energy fluxes in the edge region. A semi-analytical model is presented describing the resulting impurity fluxes and the stability boundary of the underlying mode. The main goal is to bridge the gap between, on the one hand, costly numerical simulations, which are applicable to a broad range of problems but yield scarcely traceable results, and, on the other hand, analytical theory, which might ease the interpretation of the results but is so far rather rudimentary. The model is based on analytical formulae whenever possible but resorts to a numerical treatment when the approximations necessary for an analytical solution would lead to a substantial distortion of the results. Both the direction of the impurity flux and the stability boundary are found to depend sensitively on the plasma parameters such as the impurity density and the temperature gradient. Pfirsch-Schlueter transport in stellarators: Due to geometry effects, collisional transport plays a much more

  4. Kinetic simulation of neutral particle transport in sputtering processes (United States)

    Trieschmann, Jan; Gallian, Sara; Brinkmann, Ralf Peter; Mussenbrock, Thomas; Ries, Stefan; Bibinov, Nikita; Awakowicz, Peter


    For many physical vapor deposition applications using sputtering processes, knowledge about the detailed spatial and temporal evolution of the involved gas species is of great importance. Modeling of the involved gas dynamic and plasma processes is however challenging, because the operating pressure is typically below 1 Pa. In consequence, only kinetic descriptions are appropriate. In order to approach this problem, the dynamics of sputtered particle transport through a neutral gas background is simulated. For this study, a modified version of the three-dimensional Direct Simulation Monte Carlo (DSMC) code dsmcFoam is utilized. The impact of a transient sputtering wind is investigated in a generic reactor geometry, which may be used for dc Magnetron Sputtering (dcMS), High Power Impulse Magnetron Sputtering (HiPIMS), as well as sputtering in capacitively coupled discharges. In the present work a rarefaction of the background gas is observed. Moreover in pulsed mode the temporal dynamics of the rarefaction and subsequent recovery of the background gas is investigated. This work is supported by the German Research Foundation in the frame of TRR 87.

  5. Features, Events, and Processes in UZ and Transport

    Energy Technology Data Exchange (ETDEWEB)

    P. Persoff


    The purpose of this report is to evaluate and document the inclusion or exclusion of the unsaturated zone (UZ) features, events, and processes (FEPs) with respect to modeling that supports the total system performance assessment (TSPA) for license application (LA) for a nuclear waste repository at Yucca Mountain, Nevada. A screening decision, either ''Included'' or ''Excluded'', is given for each FEP, along with the technical basis for the screening decision. This information is required by the U.S. Nuclear Regulatory Commission (NRC) in 10 CFR 63.114 (d, e, and f) [DIRS 156605]. The FEPs deal with UZ flow and radionuclide transport, including climate, surface water infiltration, percolation, drift seepage, and thermally coupled processes. This analysis summarizes the implementation of each FEP in TSPA-LA (that is, how the FEP is included) and also provides the technical basis for exclusion from TSPA-LA (that is, why the FEP is excluded). This report supports TSPA-LA.

  6. Removal of organic compounds and trace metals from oil sands process-affected water using zero valent iron enhanced by petroleum coke. (United States)

    Pourrezaei, Parastoo; Alpatova, Alla; Khosravi, Kambiz; Drzewicz, Przemysław; Chen, Yuan; Chelme-Ayala, Pamela; Gamal El-Din, Mohamed


    The oil production generates large volumes of oil sands process-affected water (OSPW), referring to the water that has been in contact with oil sands or released from tailings deposits. There are concerns about the environmental impacts of the release of OSPW because of its toxicity. Zero valent iron alone (ZVI) and in combination with petroleum coke (CZVI) were investigated as environmentally friendly treatment processes for the removal of naphthenic acids (NAs), acid-extractable fraction (AEF), fluorophore organic compounds, and trace metals from OSPW. While the application of 25 g/L ZVI to OSPW resulted in 58.4% removal of NAs in the presence of oxygen, the addition of 25 g petroleum coke (PC) as an electron conductor enhanced the NAs removal up to 90.9%. The increase in ZVI concentration enhanced the removals of NAs, AEF, and fluorophore compounds from OSPW. It was suggested that the electrons generated from the oxidation of ZVI were transferred to oxygen, resulting in the production of hydroxyl radicals and oxidation of NAs. When OSPW was de-oxygenated, the NAs removal decreased to 17.5% and 65.4% during treatment with ZVI and CZVI, respectively. The removal of metals in ZVI samples was similar to that obtained during CZVI treatment. Although an increase in ZVI concentration did not enhance the removal of metals, their concentrations effectively decreased at all ZVI loadings. The Microtox(®) bioassay with Vibrio fischeri showed a decrease in the toxicity of ZVI- and CZVI-treated OSPW. The results obtained in this study showed that the application of ZVI in combination with PC is a promising technology for OSPW treatment. Copyright © 2014 Elsevier Ltd. All rights reserved.

  7. Liquefaction of Sand under Low Confining Pressure

    Institute of Scientific and Technical Information of China (English)

    YANG Shaoli; Rolf Sandven; Lars Grande


    Undrained behaviour of sand under low cell pressure was studied in static and cyclic triaxial tests. It was found that very loose sand liquefies under static loading with the relative density being a key parameter for the undrained behaviour of sand. In cyclic triaxial tests, pore water pressures built up during the cyclic loading and exceeded the confining cell pressure. This process was accompanied by a large sudden increase in axial deformation. The necessary number of cycles to obtain liquefaction was related to the confining cell pressure, the amplitude of cyclic loading and the relative density of sand.In addition, the patterns of pore water pressure response are different from those of sand samples with different relative densities. The test results are very useful for expounding scour mechanism around coastal structures since they relate to the low stress behaviour of the sand.

  8. Application studies of RFID technology in the process of coal logistics transport (United States)

    Qiao, Bingqin; Chang, Xiaoming; Hao, Meiyan; Kong, Dejin


    For quality control problems in coal transport, RFID technology has been proposed to be applied to coal transportation process. The whole process RFID traceability system from coal production to consumption has been designed and coal supply chain logistics tracking system integration platform has been built, to form the coal supply chain traceability and transport tracking system and providing more and more transparent tracking and monitoring of coal quality information for consumers of coal. Currently direct transport and combined transport are the main forms of coal transportation in China. The means of transport are cars, trains and ships. In the booming networking environment of RFID technology, the RFID technology will be applied to coal logistics and provide opportunity for the coal transportation tracking in the process transportation.

  9. Influence green sand system by core sand additions


    N. Špirutová; J. Beňo; V. Bednářová; J. Kříž; M. Kandrnál


    Today, about two thirds of iron alloys casting (especially for graphitizing alloys of iron) are produced into green sand systems with usually organically bonded cores. Separation of core sands from the green sand mixture is very difficult, after pouring. The core sand concentration increase due to circulation of green sand mixture in a closed circulation system. Furthermore in some foundries, core sands have been adding to green sand systems as a replacement for new sands. The goal of this co...

  10. The contribution of an overlooked transport process to a wetland's methane emissions (United States)

    Poindexter, Cristina M.; Baldocchi, Dennis D.; Matthes, Jaclyn Hatala; Knox, Sara Helen; Variano, Evan A.


    Wetland methane transport processes affect what portion of methane produced in wetlands reaches the atmosphere. We model what has been perceived to be the least important of these transport processes: hydrodynamic transport of methane through wetland surface water and show that its contribution to total methane emissions from a temperate freshwater marsh is surprisingly large. In our 1 year study, hydrodynamic transport comprised more than half of nighttime methane fluxes and was driven primarily by water column thermal convection occurring overnight as the water surface cooled. Overall, hydrodynamic transport was responsible for 32% of annual methane emissions. Many methane models have overlooked this process, but our results show that wetland methane fluxes cannot always be accurately described using only other transport processes (plant-mediated transport and ebullition). Modifying models to include hydrodynamic transport and the mechanisms that drive it, particularly convection, could help improve predictions of future wetland methane emissions.

  11. Baskarp Sand No. 15

    DEFF Research Database (Denmark)

    Borup, Marianne; Hedegaard, Jette

    The Soil Mechanics Laboratory has started performing tests with a new sand, Baskarp No 15. Baskarp No 15 is a graded sand from Sweden. The shapes of the largest grains are round, while the small grains have sharp edges. The main part of of Baskarp No 15 is quarts, but it also contains feldspar...... and biotit. Mainly the sand will be used for tests concerning the development og the theory of building up pore pressure in sand, L. B. Ibsen 1993....

  12. Lund Sand No 0

    DEFF Research Database (Denmark)

    Ibsen, Lars Bo; Jakobsen, Finn Rosendal

    During the last 15 years the Geotechnical Engineering Group (GEG) at Aalborg University has performed triaxial tests with a sand called Lund No 0. Lund No 0 is a graded sand from a gravel pit near Horsens in Denmark. For the classification of the sand the following tests have been performed: Sieve...

  13. Physical processes that control droplet transport in rock fracture systems (United States)

    Hay, Katrina Moran

    Aquifer recharge is generally driven by fluids that move from the Earths surface to groundwater through the unsaturated zone, also known as the vadose zone. When the vadose zone is fractured, fluids, which may include contaminants, can move through the fracture network as well as the porous matrix. Such a network of fractures can provide a more rapid path, thereby reducing contact time between the fluid and the matrix. Contact time allows for exchange of solutes between the fluid and the porous matrix, thus being able to quantify contact time is important. In addition, the behavior of fluids within a fracture network has been found to be very complex; large-scale models are yet not able to predict transport paths or flux rates. Because, small-scale flow phenomena can strongly influence the large-scale behavior of fluid movement through systems of fractures, it is important that small-scale dynamics be properly understood in order to improve our predictive capabilities in these complex systems. Relevant flow dynamics includes the impact of boundary conditions, fluid modes that evolve in time and space and transitions between modes. This thesis presents three investigations aimed at understanding the physical processes governing fluid movement in unsaturated fractures, with the ultimate goal of improving predictive relationships for fluid transport in rock fracture systems. These investigations include a theoretical analysis of the wetting of a rough surface, an experimental study of the dynamics of fluid droplets (or liquid bridges) moving in a single fracture and a theoretical analysis of the movement of a fluid droplet encountering a fracture intersection. Each investigation is motivated by environmental applications. Development of an analytical equation for the wetting of a rough surface is based on a balance between capillary forces and frictional resistive forces. The resulting equation predicts movement of the liquid invasion front driven solely by the

  14. Toxicokinetics and toxicodynamics of chlorpyrifos is altered in embryos of Japanese medaka exposed to oil sands process-affected water: evidence for inhibition of P-glycoprotein. (United States)

    Alharbi, Hattan A; Alcorn, Jane; Al-Mousa, Ahmed; Giesy, John P; Wiseman, Steve B


    Oil sands process-affected water (OSPW) is generated during extraction of bitumen in the surface mining oil sands industry in Alberta, Canada. Studies were performed in vitro by use of Caco-2 cells, and in vivo with larvae of Japanese medaka (Oryzias latipes) to determine if organic compounds from the aqueous phase of OSPW inhibit ATP binding cassette protein ABCB1 (permeability-glycoprotein, P-gp). Neutral and basic fractions of OSPW inhibited activity of P-gp in Caco-2 cells by 1.9- and 2.0-fold, respectively, while the acidic fraction had the least effect. The organophosphate pesticides chlorpyrifos (a substrate of P-gp) and malathion (not a substrate of P-gp), were used as model chemicals to investigate inhibition of P-gp in larvae. Co-exposure to chlorpyrifos and an extract of OSPW containing basic and neutral compounds reduced survival of larvae to 26.5% compared to survival of larvae exposed only to chlorpyrifos, which was 93.7%. However, co-exposure to malathion and the extract of OSPW did not cause acute lethality compared to exposure only to malathion. Accumulation and bioconcentration of chlorpyrifos, but not malathion, was greater in larvae co-exposed with the extract of OSPW. The terminal elimination half-life of chlorpyrifos in larvae exposed to chlorpyrifos in freshwater was 5 days compared with 11.3 days in larvae exposed to chlorpyrifos in OSPW. Results suggest that in non-acute exposures, basic and neutral organic compounds in the water-soluble fraction of OSPW inhibit activity of P-gp, which suggests that OSPW has the potential to cause adverse effects by chemosensitization. Copyright © 2016 John Wiley & Sons, Ltd.

  15. Comprehensive analysis of oil sands processed water by direct-infusion Fourier-transform ion cyclotron resonance mass spectrometry with and without offline UHPLC sample prefractionation. (United States)

    Nyakas, Adrien; Han, Jun; Peru, Kerry M; Headley, John V; Borchers, Christoph H


    Oil sands processed water (OSPW) is the main byproduct of the large-scale bitumen extraction activity in the Athabasca oil sands region (Alberta, Canada). We have investigated the acid-extractable fraction (AEF) of OSPW by extraction-only (EO) direct infusion (DI) negative-ion mode electrospray ionization (ESI) on a 12T-Fourier transform ion cyclotron resonance mass spectrometer (FTICR-MS), as well as by offline ultrahigh performance liquid chromatography (UHPLC) followed by DI-FTICR-MS. A preliminary offline UHPLC separation into 8 fractions using a reversed-phase C4 column led to approximately twice as many detected peaks and identified compounds (973 peaks versus 2231 peaks, of which 856 and 1734 peaks, respectively, could be assigned to chemical formulas based on accurate mass measurements). Conversion of these masses to the Kendrick mass scale allowed the straightforward recognition of homologues. Naphthenic (CnH2n+zO2) and oxy-naphthenic (CnH2n+zOx) acids represented the largest group of molecules with assigned formulas (64%), followed by sulfur-containing compounds (23%) and nitrogen-containing compounds (8%). Pooling of corresponding fractions from two consecutive offline UHPLC runs prior to MS analysis resulted in ~50% more assignments than a single injection, resulting in 3-fold increase of identifications compared to EO-DI-FTICR-MS using the same volume of starting material. Liquid-liquid extraction followed by offline UHPLC fractionation thus holds enormous potential for a more comprehensive profiling of OSPW, which may provide a deeper understanding of its chemical nature and environmental impact.

  16. NATO Advanced Study Institute on Chemical Transport in Melasomatic Processes

    CERN Document Server


    As indicated on the title page, this book is an outgrowth of the NATO Advanced Study Institute (ASI) on Chemical Transport in Metasomatic Processes, which was held in Greece, June 3-16, 1985. The ASI consisted of five days of invited lectures, poster sessions, and discussion at the Club Poseidon near Loutraki, Corinthia, followed by a two-day field trip in Corinthia and Attica. The second week of the ASI consisted of an excursion aboard M/S Zeus, M/Y Dimitrios II, and the M/S Irini to four of the Cycladic Islands to visit, study, and sample outstanding exposures of metasomatic activity on Syros, Siphnos, Seriphos, and Naxos. Nine­ teen invited lectures and 10 session chairmen/discussion leaders participated in the ASI, which was attended by a total of 92 professional scientists and graduate stu­ dents from 15 countries. Seventeen of the invited lectures and the Field Excursion Guide are included in this volume, together with 10 papers and six abstracts representing contributed poster sessions. Although more...

  17. Space Transportation System Liftoff Debris Mitigation Process Overview (United States)

    Mitchell, Michael; Riley, Christopher


    Liftoff debris is a top risk to the Space Shuttle Vehicle. To manage the Liftoff debris risk, the Space Shuttle Program created a team with in the Propulsion Systems Engineering & Integration Office. The Shutt le Liftoff Debris Team harnesses the Systems Engineering process to i dentify, assess, mitigate, and communicate the Liftoff debris risk. T he Liftoff Debris Team leverages off the technical knowledge and expe rtise of engineering groups across multiple NASA centers to integrate total system solutions. These solutions connect the hardware and ana lyses to identify and characterize debris sources and zones contribut ing to the Liftoff debris risk. The solutions incorporate analyses sp anning: the definition and modeling of natural and induced environmen ts; material characterizations; statistical trending analyses, imager y based trajectory analyses; debris transport analyses, and risk asse ssments. The verification and validation of these analyses are bound by conservative assumptions and anchored by testing and flight data. The Liftoff debris risk mitigation is managed through vigilant collab orative work between the Liftoff Debris Team and Launch Pad Operation s personnel and through the management of requirements, interfaces, r isk documentation, configurations, and technical data. Furthermore, o n day of launch, decision analysis is used to apply the wealth of ana lyses to case specific identified risks. This presentation describes how the Liftoff Debris Team applies Systems Engineering in their proce sses to mitigate risk and improve the safety of the Space Shuttle Veh icle.

  18. Silica sand resources in the Netherlands

    NARCIS (Netherlands)

    Meulen, M.J. van der; Westerhoff, W.E.; Menkovic, A.; Gruijters, S.H.L.L.; Dubelaar, C.W.; Maljers, D.


    Silica sand, (almost) pure quartz sand, is a valuable and scarce mineral resource within the shallow Dutch subsurface. High-grade deposits are exploited in the southeastemmost part of the country, as raw material for the glass, ceramic, chemical and other process industries. Dutch land-use policy re

  19. Quantitative analysis of microtubule transport in growing nerve processes

    DEFF Research Database (Denmark)

    Ma*, Ytao; Shakiryanova*, Dinara; Vardya, Irina;


    the translocation of MT plus ends in the axonal shaft by expressing GFP-EB1 in Xenopus embryo neurons in culture. Formal quantitative analysis of MT assembly/disassembly indicated that none of the MTs in the axonal shaft were rapidly transported. Our results suggest that transport of axonal MTs is not required...

  20. 覆砂铁型铸造工艺生产ADI摩擦斜楔%ADI Oblique Wedge Produced with Resin Sand Coated-Iron Mold Casting Process

    Institute of Scientific and Technical Information of China (English)

    王彬; 鲍玉龙; 王德军


    The casting method and heat treatment process adopted for using resin sand coated-iron mold to produce ADI oblique wedge of railway vehicles was introduced. By adopting semi -pressurized gating system and filter to skim slag, choosing rational melting charge mixture ratio and the cored-wire injection nodularizing process, using salt bath isothermal quenching process, the hi-strength , hi-hardness and hi-toughness ADI castings with bainite + residual austenite as matrix were finally obtained.%介绍了采用覆砂铁型铸造生产火车用摩擦斜楔ADI铸件的铸造工艺和热处理工艺.通过采用半封闭式浇注系统和过滤网挡渣;选用合理的炉料配比及喂丝球化处理工艺;采用盐浴等温淬火工艺,最终获得以贝氏体+残余奥氏体为基体的高强度、高硬度及高韧性的ADI铸件.

  1. Research investigations in oil shale, tar sand, coal research, advanced exploratory process technology, and advanced fuels research: Volume 1 -- Base program. Final report, October 1986--September 1993

    Energy Technology Data Exchange (ETDEWEB)

    Smith, V.E.


    Numerous studies have been conducted in five principal areas: oil shale, tar sand, underground coal gasification, advanced process technology, and advanced fuels research. In subsequent years, underground coal gasification was broadened to be coal research, under which several research activities were conducted that related to coal processing. The most significant change occurred in 1989 when the agreement was redefined as a Base Program and a Jointly Sponsored Research Program (JSRP). Investigations were conducted under the Base Program to determine the physical and chemical properties of materials suitable for conversion to liquid and gaseous fuels, to test and evaluate processes and innovative concepts for such conversions, to monitor and determine environmental impacts related to development of commercial-sized operations, and to evaluate methods for mitigation of potential environmental impacts. This report is divided into two volumes: Volume 1 consists of 28 summaries that describe the principal research efforts conducted under the Base Program in five topic areas. Volume 2 describes tasks performed within the JSRP. Research conducted under this agreement has resulted in technology transfer of a variety of energy-related research information. A listing of related publications and presentations is given at the end of each research topic summary. More specific and detailed information is provided in the topical reports referenced in the related publications listings.

  2. Impact of ozonation pre-treatment of oil sands process-affected water on the operational performance of a GAC-fluidized bed biofilm reactor. (United States)

    Islam, Md Shahinoor; Dong, Tao; McPhedran, Kerry N; Sheng, Zhiya; Zhang, Yanyan; Liu, Yang; Gamal El-Din, Mohamed


    Treatment of oil sands process-affected water (OSPW) using biodegradation has the potential to be an environmentally sound approach for tailings water reclamation. This process is both economical and efficient, however, the recalcitrance of some OSPW constituents, such as naphthenic acids (NAs), require the pre-treatment of raw OSPW to improve its biodegradability. This study evaluated the treatment of OSPW using ozonation followed by fluidized bed biofilm reactor (FBBR) using granular activated carbon (GAC). Different organic and hydraulic loading rates were applied to investigate the performance of the bioreactor over 120 days. It was shown that ozonation improved the adsorption capacity of GAC for OSPW and improved biodegradation by reducing NAs cyclicity. Bioreactor treatment efficiencies were dependent on the organic loading rate (OLR), and to a lesser degree, the hydraulic loading rate (HLR). The combined ozonation, GAC adsorption, and biodegradation process removed 62 % of chemical oxygen demand (COD), 88 % of acid-extractable fraction (AEF) and 99.9 % of NAs under optimized operational conditions. Compared with a planktonic bacterial community in raw and ozonated OSPW, more diverse microbial communities were found in biofilms colonized on the surface of GAC after 120 days, with various carbon degraders found in the bioreactor including Burkholderia multivorans, Polaromonas jejuensis and Roseomonas sp.

  3. A study of K variability and its effect on solute transport in subsurface-flow sand filters by measurement and modelling. (United States)

    Kløve, Bjørn; Xu, Shulan; Lindahl, Anna; Wörman, Anders; Søvik, Anne-Kristine


    Hydraulics of subsurface flow filters (SSF) was studied by measurement of soil hydraulic conductivity (K) variation and performing tracer tests in two SSF filters consisting of 1-4 mm Ca rich sand (shell sand). Soil samples were carefully taken at several locations in Filter I. A tracer experiment was conducted in the undisturbed Filter II using KI. The measured K variability in Filer I was used to analyze the variations in tracer breakthrough. The spatially distribution of K was obtained by fitting a variogram to observed data and interpolation using Kriging. The tracer residence probability density function (PDF) was determined by modelling the tracer movement with a 3-D groundwater model. The observed and simulated tracer arrival was compared for cases with constant K, constant K and dispersion (D), and for spatially variable K and dispersion. The results show that groundwater models were well suited to simulate solute movement in the SSF system studied. An almost perfect fit to observed tracer PDF was obtained when variable K and dispersion was included in the model. This indicates that information on K variability and dispersion is important for studying solute movement in SSF constructed wetlands.

  4. Solution processed metal oxide thin film hole transport layers for high performance organic solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Steirer, K. Xerxes; Berry, Joseph J.; Chesin, Jordan P.; Lloyd, Matthew T.; Widjonarko, Nicodemus Edwin; Miedaner, Alexander; Curtis, Calvin J.; Ginley, David S.; Olson, Dana C.


    A method for the application of solution processed metal oxide hole transport layers in organic photovoltaic devices and related organic electronics devices is disclosed. The metal oxide may be derived from a metal-organic precursor enabling solution processing of an amorphous, p-type metal oxide. An organic photovoltaic device having solution processed, metal oxide, thin-film hole transport layer.


    Directory of Open Access Journals (Sweden)

    P. Gorbachev


    Full Text Available The mathematical model to determine the profit of trucking companies, which takes into account the probabilistic properties of transport process elements when performing single orders in international cargo transportation is prognosed. The proposed criterion makes it possible to obtain a probabilistic assessment of trip results in both directions and choosing the most effective directions of cargo transportation.

  6. An experiment to restore coastal sand dunes at Miramar beach, Goa: An appraisal

    Digital Repository Service at National Institute of Oceanography (India)

    Mascarenhas, A.

    . Loss of vegetation is attributed to continuous trampling by humans, resulting in the creation of loose free sand that gets transported landwards. During windy days, large quantities of beach sand are blown from the beach and subsequently accumulate...

  7. Field-based observations confirm linear scaling of sand flux with wind stress

    CERN Document Server

    Martin, Raleigh L


    Wind-driven sand transport generates atmospheric dust, forms dunes, and sculpts landscapes. However, it remains unclear how the sand flux scales with wind speed, largely because models do not agree on how particle speed changes with wind shear velocity. Here, we present comprehensive measurements from three new field sites and three published studies, showing that characteristic saltation layer heights, and thus particle speeds, remain approximately constant with shear velocity. This result implies a linear dependence of saltation flux on wind shear stress, which contrasts with the nonlinear 3/2 scaling used in most aeolian process predictions. We confirm the linear flux law with direct measurements of the stress-flux relationship occurring at each site. Models for dust generation, dune migration, and other processes driven by wind-blown sand on Earth, Mars, and several other planetary surfaces should be modified to account for linear stress-flux scaling.

  8. DEM analyses of the whole failure process of shallow foundation in plate load test on dense sand (United States)

    Li, L.; Jiang, M. J.; Li, T.; Chen, S. L.


    Shallow foundations are widely used in civil engineering practice, but the instability mechanism is still unclear yet. Previously, the Finite Element Method (FEM) was commonly used to analyze the failure process of shallow foundations, but it meets difficulty in properly simulating the whole failure process of shallow foundation on the strain-softening material. Hence, the Discrete Element Method (DEM) is employed in this paper to study the instability mechanism of the shallow foundation via numerical plate load test with focus on the microscopic features evolution during vertical loading. In the simulation, an amplified gravity was applied to a dense granular ground to reproduce a gravity stress state at a large scale. Then, a plate was put on the granular ground to simulate the plate load test. Deformation pattern, particle velocity and distribution of void ratio in the ground were examined to illustrate the microscopic features in the whole failure process of the granular ground. The results show that: 1) There are a marked peak value and a settlement softening branch in the stress-settlement relationship. 2) The grids close to the edge of the plate are peculiarly extended and twisted. 3) Four particle motion patterns were observed in the velocity fields and the percentage of each motion pattern changes during loading. 4) The void ratio field varies during loading, and the distinguishing interface tends to be similar to Terzaghi's shear failure surface.

  9. Regulation of transport processes across the tonoplast membrane

    Directory of Open Access Journals (Sweden)

    Oliver eTrentmann


    Full Text Available In plants, the vacuole builds up the cellular turgor and represents an important component in cellular responses to diverse stress stimuli. Rapid volume changes of cells, particularly of motor cells, like guard cells, are caused by variation of osmolytes and consequently of the water contents in the vacuole. Moreover, directed solute uptake into or release out of the large central vacuole allows adaptation of cytosolic metabolite levels according to the current physiological requirements and specific cellular demands. Therefore, solute passage across the vacuolar membrane, the tonoplast, has to be tightly regulated. Important principles in vacuolar transport regulation are changes of tonoplast transport protein abundances by differential expression of genes or changes of their activities, e.g. due to post-translational modification or by interacting proteins. Because vacuolar transport is in most cases driven by an electro-chemical gradient altered activities of tonoplast proton pumps significantly influence vacuolar transport capacities. Intense studies on individual tonoplast proteins but also unbiased system biological approaches have provided important insights into the regulation of vacuolar transport. This short review refers to selected examples of tonoplast proteins and their regulation, with special focus on protein phosphorylation.

  10. Sand Waves in Environmental Flows: Insights gained by LES (United States)

    Sotiropoulos, Fotis


    In fluvial and coastal environments, sediment transport processes induced by near-bed coherent structures in the turbulent boundary layer developing over a mobile sediment bed result in the formation of dynamically rich sand waves, or bed forms, which grow and migrate continuously. Bed form migration alters streambed roughness and provides the primary mechanism for transporting large amounts of sediment through riverine systems impacting the morphology, streambank stability, and ecology of waterways. I will present recent computational advances, which have enabled coupled, hydro-morphodynamic large-eddy simulation (LES) of turbulent flow in mobile-bed open channels. Numerical simulations: 1) elucidate the role of near-bed sweeps in the turbulent boundary layer as the mechanism for initiating the instability of the initially flat sand bed; 2) show how near-bed processes give rise to aperiodic eruptions of suspended sediment at the free surface; and 3) clarify the mechanism via which sand waves migrate. Furthermore, in agreement with recent experimental observations, the computed spectra of the resolved velocity fluctuations above the bed exhibit a distinct spectral gap whose width increases with distance from the bed. The spectral gap delineates the spectrum of turbulence from that of slowly evolving coherent structures associated with sand wave migration. The talk will also present computational results demonstrating the feasibility of carrying out coupled, hydro-morphodynamic LES of large dunes migrating in meandering streams and rivers with embedded hydraulic structures and discuss future challenges and opportunities. This work was supported by NSF Grants EAR-0120914 and EAR-0738726, and National Cooperative Highway Research Program Grant NCHRP-HR 24-33.

  11. Extensive formation of sinkholes in unconsolidated rock due to underground erosive removal of sand at a marginal batter of an opencast mine - causes, process and geotechnical safety measures. Grossflaechige Erdfallbildungen im Lockergestein durch unterirdische erosive Ausraeumung von Sand and einer Tagebauendboeschung - Ursachen, Verlauf und geotechnische Sicherung

    Energy Technology Data Exchange (ETDEWEB)

    Pfeiffer, H.


    When the ground water rose in the marginal batter of an opencast mine damage occurred. This was caused by the processes of internal erosion and suffusion in fine sand layers of slight thickness and by the disintegration of the overlying strata due to the formation of sinkholes. Effective safety measures involved lowering the ground-water level in the zone immediately in front of the area in question and installing an auxiliary filter unit at the marginal batter. (orig.).

  12. Structural variations of sand-bearing airflow over dune at southeastern fringe of Tengger Desert

    Institute of Scientific and Technical Information of China (English)

    Hasi Eerdum


    From the analytical results of observed data on sand transport rates at different positions of dune surface at southeastern fringe of Tengger Desert, it has been found that the vertical distribution of blown sand flux exhibits a noticeable variation when sand grains move upslope and downslope of dune surface under the action of wind force. Within the height of 20 cm above the sand surface, the vertical distribution of mass flux at different positions from toe to dune crest of stoss slope of sand dunes coincides with a single exponentially decaying law; while the vertical distribution of mass flux over the lee slope occurs as two variable zones, with the height of 8—12 cm as the dividing line, the sand transport rate below this height exponentially decreases with increasing height, but above this height decreases in a power function law. On the stoss slope, the relative sand transport rate in the upper layer of sand flow tends to decrease with the increasing wind velocity and the total sand transport rate towards the dune crest due to the shortened trajectory length of saltation sand grains moving upslope. On the lee slope, the increase in lift-off height and trajectory length of saltation sand grains moving downslope leads to the increase in relative sand transport rate in the upper layer of sand flow.

  13. Benthic processes affecting contaminant transport in Upper Klamath Lake, Oregon (United States)

    Kuwabara, James S.; Topping, Brent R.; Carter, James L.; Carlson, Rick A; Parchaso, Francis; Fend, Steven V.; Stauffer-Olsen, Natalie; Manning, Andrew J.; Land, Jennie M.


    Executive SummaryMultiple sampling trips during calendar years 2013 through 2015 were coordinated to provide measurements of interdependent benthic processes that potentially affect contaminant transport in Upper Klamath Lake (UKL), Oregon. The measurements were motivated by recognition that such internal processes (for example, solute benthic flux, bioturbation and solute efflux by benthic invertebrates, and physical groundwater-surface water interactions) were not integrated into existing management models for UKL. Up until 2013, all of the benthic-flux studies generally had been limited spatially to a number of sites in the northern part of UKL and limited temporally to 2–3 samplings per year. All of the benthic invertebrate studies also had been limited to the northern part of the lake; however, intensive temporal (weekly) studies had previously been completed independent of benthic-flux studies. Therefore, knowledge of both the spatial and temporal variability in benthic flux and benthic invertebrate distributions for the entire lake was lacking. To address these limitations, we completed a lakewide spatial study during 2013 and a coordinated temporal study with weekly sampling of benthic flux and benthic invertebrates during 2014. Field design of the spatially focused study in 2013 involved 21 sites sampled three times as the summer cyanobacterial bloom developed (that is, May 23, June 13, and July 3, 2013). Results of the 27-week, temporally focused study of one site in 2014 were summarized and partitioned into three periods (referred to herein as pre-bloom, bloom and post-bloom periods), each period involving 9 weeks of profiler deployments, water column and benthic sampling. Partitioning of the pre-bloom, bloom, and post-bloom periods were based on water-column chlorophyll concentrations and involved the following date intervals, respectively: April 15 through June 10, June 17 through August 13, and August 20 through October 16, 2014. To examine

  14. Element Geochemical Analysis of the Contribution of Aeolian Sand to Suspended Sediment in Desert Stream Flash Floods

    Directory of Open Access Journals (Sweden)

    Xiaopeng Jia


    Full Text Available The interaction of wind and water in semiarid and arid areas usually leads to low-frequency flash flood events in desert rivers, which have adverse effects on river systems and ecology. In arid zones, many aeolian dune-fields terminate in stream channels and deliver aeolian sand to the channels. Although aeolian processes are common to many desert rivers, whether the aeolian processes contribute to fluvial sediment loss is still unknown. Here, we identified the aeolian-fluvial cycling process responsible for the high rate of suspended sediment transport in the Sudalaer desert stream in the Ordos plateau of China. On the basis of element geochemistry data analysis, we found that aeolian sand was similar to suspended sediment in element composition, which suggests that aeolian sand contributes to suspended sediment in flash floods. Scatter plots of some elements further confirm that aeolian sand is the major source of the suspended sediment. Factor analysis and the relation between some elements and suspended sediment concentration prove that the greater the aeolian process, the higher the suspended sediment concentration and the greater the contribution of aeolian sand to suspended sediment yield. We conclude that aeolian sand is the greatest contributor to flash floods in the Sudalaer desert stream.

  15. Element geochemical analysis of the contribution of aeolian sand to suspended sediment in desert stream flash floods. (United States)

    Jia, Xiaopeng; Wang, Haibing


    The interaction of wind and water in semiarid and arid areas usually leads to low-frequency flash flood events in desert rivers, which have adverse effects on river systems and ecology. In arid zones, many aeolian dune-fields terminate in stream channels and deliver aeolian sand to the channels. Although aeolian processes are common to many desert rivers, whether the aeolian processes contribute to fluvial sediment loss is still unknown. Here, we identified the aeolian-fluvial cycling process responsible for the high rate of suspended sediment transport in the Sudalaer desert stream in the Ordos plateau of China. On the basis of element geochemistry data analysis, we found that aeolian sand was similar to suspended sediment in element composition, which suggests that aeolian sand contributes to suspended sediment in flash floods. Scatter plots of some elements further confirm that aeolian sand is the major source of the suspended sediment. Factor analysis and the relation between some elements and suspended sediment concentration prove that the greater the aeolian process, the higher the suspended sediment concentration and the greater the contribution of aeolian sand to suspended sediment yield. We conclude that aeolian sand is the greatest contributor to flash floods in the Sudalaer desert stream.

  16. Influence of marine and continental processes on the dynamics of a sand-ridge at the mouth of the Mafaguaqu river (Caraguatabuba - SP: preliminary conditions

    Directory of Open Access Journals (Sweden)

    May Christine Modenesi


    Full Text Available This paper deals with the sedimentation and erosion dynamics of a sand-ridge on the Maçaguaçu River mouth on the São Paulo coastal plain, north of Caraguatatuba Bay. Sedimentological, climatic and hydrodynamic data were analysed from an integrative point of view, considering relationships between continental and marine antagonic forces. Even if incomplete these preliminary observation show that erosion only occurs when more intense rains and higher tidal cycles coincide and that even the intense occurrence of one of these phenomena is not enough to trigger the destructive processes.A dinâmica de sedimentação e erosão do "spit-bar" do rio Maçaguaçu (Caragua tatuba, São Paulo foi preliminarmente avaliada através da integração de es tudos climáticos, hidrodinámicos e sedimentologicos, considerando-se as interrelaçoes das forças antagónicas entre os processos continental e marinho. A feição construtiva do "spit-bar" parece estar conectada com a dinámica dos processos marinhos. Suas características erosionáis parecem ser o resultado dos processos fluviais, intimamente relacionados aos períodos de intensa pluviosidade nas escarpas da Serra do Mar, quando da passagem de frentes atmosféricas.

  17. An 18. century ingredient in a 21. century solution : a steam-based process is helping overcome the challenges of in situ oil sands recovery

    Energy Technology Data Exchange (ETDEWEB)

    Sundararajan, B.


    Recent technological innovations, more efficient methods such as steam-assisted gravity drainage (SAGD), as well as the favorability of oil prices have led to renewed interest in extracting oil from in situ deposits. This article provided background information on the origins of SAGD and discussed technical consultation services that are offered by Canadian-based Norwest Corporation. Norwest provides comprehensive services aimed at optimizing every stage of project development in four principal areas, notably geology, engineering, water resources, and environmental and management consulting. Key challenges in the SAGD process were also outlined with particular reference to the situation of vertical and horizontal bores; insensitivity to thin shale streaks and other vertical barriers to steam and fluid flow; and cost of steam generation. It was concluded that both mining and in-situ oil sands developers are committed to minimizing the impact they have on the land by avoiding sensitive habitats, optimizing land use and working with other users to reduce the overall footprint of industry. 2 figs.

  18. Adsorption of acid-extractable organics from oil sands process-affected water onto biomass-based biochar: Metal content matters. (United States)

    Bhuiyan, Tazul I; Tak, Jin K; Sessarego, Sebastian; Harfield, Don; Hill, Josephine M


    The impact of biochar properties on acid-extractable organics (AEO) adsorption from oil sands process-affected water (OSPW) was studied. Biochar from wheat straw with the highest ash content (14%) had the highest adsorption capacity (0.59 mg/g) followed by biochar from pulp mill sludge, switchgrass, mountain pine, hemp shives, and aspen wood. The adsorption capacity had no obvious trend with surface area, total pore volume, bulk polarity and aromaticity. The large impact of metal content was consistent with the carboxylates (i.e., naphthenate species) in the OSPW binding to the metals (mainly Al and Fe) on the carbon substrate. Although the capacity of biochar is still approximately two orders of magnitude lower than that of a commercial activated carbon, confirming the property (i.e., metal content) that most influenced AEO adsorption, may allow biochar to become competitive with activated carbon after normalizing for cost, especially if this cost includes environmental impacts. Copyright © 2016 Elsevier Ltd. All rights reserved.

  19. Treatment of oil sands process-affected water (OSPW) using a membrane bioreactor with a submerged flat-sheet ceramic microfiltration membrane. (United States)

    Xue, Jinkai; Zhang, Yanyan; Liu, Yang; Gamal El-Din, Mohamed


    The release of oil sands process-affected water (OSPW) into the environment is a concern because it contains persistent organic pollutants that are toxic to aquatic life. A modified Ludzack-Ettinger membrane bioreactor (MLE-MBR) with a submerged ceramic membrane was continuously operated for 425 days to evaluate its feasibility on OSPW treatment. A stabilized biomass concentration of 3730 mg mixed liquor volatile suspended solids per litre and a naphthenic acid (NA) removal of 24.7% were observed in the reactor after 361 days of operation. Ultra Performance Liquid Chromatography/High Resolution Mass Spectrometry analysis revealed that the removal of individual NA species declined with increased ring numbers. Pyrosequencing analysis revealed that Betaproteobacteria were dominant in sludge samples from the MLE-MBR, with microorganisms such as Rhodocyclales and Sphingobacteriales capable of degrading hydrocarbon and aromatic compounds. During 425 days of continuous operation, no severe membrane fouling was observed as the transmembrane pressure (TMP) of the MLE-MBR never exceeded -20 kPa given that the manufacturer's suggested critical TMP for chemical cleaning is -35 kPa. Our results indicated that the proposed MLE-MBR has a good potential for removing recalcitrant organics in OSPW.

  20. The effect of oil sands process-affected water and model naphthenic acids on photosynthesis and growth in Emiliania huxleyi and Chlorella vulgaris. (United States)

    Beddow, Jessica; Johnson, Richard J; Lawson, Tracy; Breckels, Mark N; Webster, Richard J; Smith, Ben E; Rowland, Steven J; Whitby, Corinne


    Naphthenic acids (NAs) are among the most toxic organic pollutants present in oil sands process waters (OSPW) and enter marine and freshwater environments through natural and anthropogenic sources. We investigated the effects of the acid extractable organic (AEO) fraction of OSPW and individual surrogate NAs, on maximum photosynthetic efficiency of photosystem II (PSII) (FV/FM) and cell growth in Emiliania huxleyi and Chlorella vulgaris as representative marine and freshwater phytoplankton. Whilst FV/FM in E. huxleyi and C. vulgaris was not inhibited by AEO, exposure to two surrogate NAs: (4'-n-butylphenyl)-4-butanoic acid (n-BPBA) and (4'-tert-butylphenyl)-4-butanoic acid (tert-BPBA), caused complete inhibition of FV/FM in E. huxleyi (≥10 mg L(-1)n-BPBA; ≥50 mg L(-1)tert-BPBA) but not in C. vulgaris. Growth rates and cell abundances in E. huxleyi were also reduced when exposed to ≥10 mg L(-1)n- and tert-BPBA; however, higher concentrations of n- and tert-BPBA (100 mg L(-1)) were required to reduce cell growth in C. vulgaris. AEO at ≥10 mg L(-1) stimulated E. huxleyi growth rate (p ≤ 0.002), yet had no apparent effect on C. vulgaris. In conclusion, E. huxleyi was generally more sensitive to NAs than C. vulgaris. This report provides a better understanding of the physiological responses of phytoplankton to NAs which will enable improved monitoring of NA pollution in aquatic ecosystems in the future.