Receding and advancing (CO_2 + brine + quartz) contact angles as a function of pressure, temperature, surface roughness, salt type and salinity

International Nuclear Information System (INIS)

Al-Yaseri, Ahmed Z.; Lebedev, Maxim; Barifcani, Ahmed; Iglauer, Stefan

2016-01-01

Highlights: • (Water + CO_2) contact angle on quartz increases substantially with pressure and salinity. • (Water + CO_2) contact angle on quartz increases slightly with temperature. • Surface roughness has only a minor influence on (water + CO_2 + quartz) contact angles. - Abstract: The wetting characteristics of CO_2 in rock are of vital importance in carbon geo-storage as they determine fluid dynamics and storage capacities. However, the current literature data has a high uncertainty, which translates into uncertain predictions in terms of containment security and economic project feasibility. We thus measured contact angles for the CO_2/water/quartz system at relevant reservoir conditions, and analysed the effects of pressure (0.1 to 20) MPa, temperature (296 to 343) K, surface roughness (56 to 1300) nm, salt type (NaCl, CaCl_2, and MgCl_2) and brine salinities (0 to 35) wt%. Water contact angles decreased with surface roughness, but increased with pressure, temperature, and brine salinity. Overall the contact angles were significantly increased at storage conditions (∼50°) when compared to ambient conditions (always 0°). Consequently quartz is weakly water-wet (not completely water-wet) at storage conditions, and structural and residual trapping capacities are reduced accordingly.

Salinity sources of Kefar Uriya wells in the Judea Group aquifer of Israel. Part 1—conceptual hydrogeological model

Science.gov (United States)

Avisar, D.; Rosenthal, E.; Flexer, A.; Shulman, H.; Ben-Avraham, Z.; Guttman, J.

2003-01-01

In the Yarkon-Taninim groundwater basin, the karstic Judea Group aquifer contains groundwater of high quality. However, in the western wells of the Kefar Uriya area located in the foothills of the Judea Mountains, brackish groundwater was locally encountered. The salinity of this water is caused presumably by two end members designated as the 'Hazerim' and 'Lakhish' water types. The Hazerim type represents surface water percolating through a highly fractured thin chalky limestone formation overlying the Judea Group aquifer. The salinity of the water derives conjointly from several sources such as leachates from rendzina and grumosols, dissolution of caliche crusts which contain evaporites and of rock debris from the surrounding formations. This surface water percolates downwards into the aquifer through a funnel- or chimney-like mechanism. This local salinization mechanism supercedes another regional process caused by the Lakhish waters. These are essentially diluted brines originating from deep formations in the western parts of the Coastal Plain. The study results show that salinization is not caused by the thick chalky beds of the Senonian Mt Scopus Group overlying the Judea Group aquifer, as traditionally considered but prevalently by aqueous leachates from soils and rock debris. The conceptual qualitative hydrogeological model of the salinization as demonstrated in this study, is supported by a quantitative hydrological model presented in another paper in this volume.

PRINCIPLE ROCK TYPES FOR RADIOACTIVE WASTE REPOSITORIES

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Sibila Borojević Šostarić

2012-07-01

Full Text Available Underground geological storage of high- and intermediate/low radioactive waste is aimed to represent a barrier between the surface environment and potentially hazardous radioactive elements. Permeability, behavior against external stresses, chemical reacatibility and absorption are the key geological parameters for the geological storage of radioactive waste. Three principal rock types were discussed and applied to the Dinarides: (1 evaporites in general, (2 shale, and (3 crystalline basement rocks. (1 Within the Dinarides, evaporite formations are located within the central part of a Carbonate platform and are inappropriate for storage. Offshore evaporites are located within diapiric structures of the central and southern part of the Adriatic Sea and are covered by thick Mesozoic to Cenozoic clastic sediment. Under very specific circumstances they can be considered as potential site locations for further investigation for the storage of low/intermediate level radioactive wast e. (2 Thick flysch type formation of shale to phyllite rocks are exposed at the basement units of the Petrova and Trgovska gora regions whereas (3 crystalline magmatic to metamorphic basement is exposed at the Moslavačka Gora and Slavonian Mts. regions. For high-level radioactive waste, basement phyllites and granites may represent the only realistic potential option in the NW Dinarides.

Discussion on the origin of sedimentary rock resistivity

International Nuclear Information System (INIS)

Dong Gangjian

2012-01-01

Conduction current way of sedimentary rock sedimentary rock is caused by the internal structure of sedimentary rock sedimentary rock pore resistance depends on the salinity of pore water and clay content and distribution. Resistivity of sedimentary rock sedimentary rock major factor in mineral composition, water resistance, oil resistance. and sedimentary structures. In practice, we should give full attention to the difference between lithology and physical properties. (author)

Study of the Effect of Clay Particles on Low Salinity Water Injection in Sandstone Reservoirs

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Sina Rezaei Gomari

2017-03-01

Full Text Available The need for optimal recovery of crude oil from sandstone and carbonate reservoirs around the world has never been greater for the petroleum industry. Water-flooding has been applied to the supplement primary depletion process or as a separate secondary recovery method. Low salinity water injection is a relatively new method that involves injecting low salinity brines at high pressure similar to conventional water-flooding techniques, in order to recover crude oil. The effectiveness of low salinity water injection in sandstone reservoirs depends on a number of parameters such as reservoir temperature, pressure, type of clay particle and salinity of injected brine. Clay particles present on reservoir rock surfaces adsorb polar components of oil and modify wettability of sandstone rocks to the oil-wet state, which is accountable for the reduced recovery rates by conventional water-flooding. The extent of wettability alteration caused by three low salinity brines on oil-wet sandstone samples containing varying clay content (15% or 30% and type of clay (kaolinite/montmorillonite were analyzed in the laboratory experiment. Contact angles of mica powder and clay mixture (kaolinite/montmorillonite modified with crude oil were measured before and after injection with three low salinity sodium chloride brines. The effect of temperature was also analyzed for each sample. The results of the experiment indicate that samples with kaolinite clay tend to produce higher contact angles than samples with montmorillonite clay when modified with crude oil. The highest degree or extent of wettability alteration from oil-wet to intermediate-wet state upon injection with low salinity brines was observed for samples injected with brine having salinity concentration of 2000 ppm. The increase in temperature tends to produce contact angles values lying in the higher end of the intermediate-wet range (75°–115° for samples treated at 50 °C, while their corresponding

Origin and evolution of formation water at the Jujo-Tecominoacan oil reservoir, Gulf of Mexico. Part 1: Chemical evolution and water-rock interaction

Energy Technology Data Exchange (ETDEWEB)

Birkle, Peter, E-mail: birkle@iie.org.mx [Instituto de Investigaciones Electricas (IIE), Gerencia de Geotermia, Av. Reforma 113, Cuernavaca, Morelos 62490 (Mexico); Garcia, Bernardo Martinez; Milland Padron, Carlos M. [PEMEX Exploracion y Produccion, Region Sur, Activo Integral Bellota-Jujo, Diseno de Explotacion, Cardenas, Tabasco (Mexico)

2009-04-15

The origin and evolution of formation water from Upper Jurassic to Upper Cretaceous mudstone-packstone-dolomite host rocks at the Jujo-Tecominoacan oil reservoir, located onshore in SE-Mexico at a depth from 5200 to 6200 m.b.s.l., have been investigated, using detailed water geochemistry from 12 producer wells and six closed wells, and related host rock mineralogy. Saline waters of Cl-Na type with total dissolved solids from 10 to 23 g/L are chemically distinct from hypersaline Cl-Ca-Na and Cl-Na-Ca type waters with TDS between 181 and 385 g/L. Bromine/Cl and Br/Na ratios suggest the subaerial evaporation of seawater beyond halite precipitation to explain the extreme hypersaline components, while less saline samples were formed by mixing of high salinity end members with surface-derived, low salinity water components. The dissolution of evaporites from adjacent salt domes has little impact on present formation water composition. Geochemical simulations with Harvie-M{phi}ller-Weare and PHRQPITZ thermodynamic data sets suggest secondary fluid enrichment in Ca, HCO{sub 3} and Sr by water-rock interaction. The volumetric mass balance between Ca enrichment and Mg depletion confirms dolomitization as the major alteration process. Potassium/Cl ratios below evaporation trajectory are attributed to minor precipitation of K feldspar and illitization without evidence for albitization at the Jujo-Tecominoacan reservoir. The abundance of secondary dolomite, illite and pyrite in drilling cores from reservoir host rock reconfirms the observed water-rock exchange processes. Sulfate concentrations are controlled by anhydrite solubility as indicated by positive SI-values, although anhydrite deposition is limited throughout the lithological reservoir column. The chemical variety of produced water at the Jujo-Tecominoacan oil field is related to a sequence of primary and secondary processes, including infiltration of evaporated seawater and original meteoric fluids, the subsequent

Origin and evolution of formation water at the Jujo-Tecominoacan oil reservoir, Gulf of Mexico. Part 1: Chemical evolution and water-rock interaction

International Nuclear Information System (INIS)

Birkle, Peter; Garcia, Bernardo Martinez; Milland Padron, Carlos M.

2009-01-01

The origin and evolution of formation water from Upper Jurassic to Upper Cretaceous mudstone-packstone-dolomite host rocks at the Jujo-Tecominoacan oil reservoir, located onshore in SE-Mexico at a depth from 5200 to 6200 m.b.s.l., have been investigated, using detailed water geochemistry from 12 producer wells and six closed wells, and related host rock mineralogy. Saline waters of Cl-Na type with total dissolved solids from 10 to 23 g/L are chemically distinct from hypersaline Cl-Ca-Na and Cl-Na-Ca type waters with TDS between 181 and 385 g/L. Bromine/Cl and Br/Na ratios suggest the subaerial evaporation of seawater beyond halite precipitation to explain the extreme hypersaline components, while less saline samples were formed by mixing of high salinity end members with surface-derived, low salinity water components. The dissolution of evaporites from adjacent salt domes has little impact on present formation water composition. Geochemical simulations with Harvie-Mφller-Weare and PHRQPITZ thermodynamic data sets suggest secondary fluid enrichment in Ca, HCO 3 and Sr by water-rock interaction. The volumetric mass balance between Ca enrichment and Mg depletion confirms dolomitization as the major alteration process. Potassium/Cl ratios below evaporation trajectory are attributed to minor precipitation of K feldspar and illitization without evidence for albitization at the Jujo-Tecominoacan reservoir. The abundance of secondary dolomite, illite and pyrite in drilling cores from reservoir host rock reconfirms the observed water-rock exchange processes. Sulfate concentrations are controlled by anhydrite solubility as indicated by positive SI-values, although anhydrite deposition is limited throughout the lithological reservoir column. The chemical variety of produced water at the Jujo-Tecominoacan oil field is related to a sequence of primary and secondary processes, including infiltration of evaporated seawater and original meteoric fluids, the subsequent mixing of

The origin of groundwater salinity in granitic rocks: identification and characterisation of chloride sources; Origine de la salinite des eaux souterraines en milieu granitique: identification et caracterisation des sources de chlorure

Energy Technology Data Exchange (ETDEWEB)

Savoye, S.

1998-04-29

Hydrogeological research in crystalline rocks, developed either in geothermics or in feasibility studies for geological disposal of radioactive waste, points out a wide range of chloride contents in associated groundwaters. The aim of this dissertation is to identify the possible origins of chloride in groundwaters within different geological conditions. The three possible chloride reservoirs (chloride-bearing minerals, fluid inclusions, micro-porosity) located in rock have been characterised by studying samples from eight granitic sites with different technical approaches (electronic microbeam, alkaline fusion, micro-thermometry, crush-leaching, diffusion experiment). Firstly, this allows the definition of a new typology of the sites, by considering not only hydrogeological features but also occurrence of salt-rich fluid inclusions with sedimentary origin. Secondly, the use of tracers (such as Cl/Br ratio, {delta}{sup 37}Cl) and mass balance calculations shows that the contribution of fluid inclusions trapped in quartz and chloride-bearing minerals cannot account for the high salinity of groundwater. In this case, the chloride origin could be of sedimentary type. Chloride would be stored in micro-porosity and in fluid inclusions trapped in carbonates. Thirdly, we have pointed out the importance of micro-porosity, acting more as a sieve and a buffer than as a source. Finally, we have shown that the low salinity of groundwaters has not always an internal origin. (author) 187 refs.

Chemistry and origin of deep ground water in crystalline rocks; Kemi och genes av djupa grundvatten i kristallint berg

Energy Technology Data Exchange (ETDEWEB)

Lagerblad, B [Swedish Cement and Concrete Research Inst., Stockholm (Sweden)

1995-11-01

This report discusses the interactions between water and crystalline rocks and its consequences for the chemical composition of the water. It also treats how flows of different types of water are modified by the rock, and the possible consequences for the ground water near a nuclear waste repository. The focus of the work is the changes in composition that ground water gets at deep levels in the rock. Data from Finnsjoen and Aespoe in Sweden show higher salinity in deep rock, which has been interpreted as a result of marine inflow of water during glaciation. Data from other, deeper boreholes in Finland, Canada, Russia, England and Sweden show that the increasing salinity is a rule and very high at great depths, higher than marine water can produce. Therefore, the deep waters from Finnsjoen and Aespoe are probably very old, and the high salinity a result from geological processes. Differing cation and isotopic composition than seawater also indicate geologic water. Differing theories on the origin of the ground water should be regarded in the safety analysis for a repository. 36 refs, 3 figs, 1 tab.

Mg-spinel lithology: A new rock type on the lunar farside

Science.gov (United States)

Pieters, C.M.; Besse, S.; Boardman, J.; Buratti, B.; Cheek, L.; Clark, R.N.; Combe, J.-P.; Dhingra, D.; Goswami, J.N.; Green, R.O.; Head, J.W.; Isaacson, P.; Klima, R.; Kramer, G.; Lundeen, S.; Malaret, E.; McCord, T.; Mustard, J.; Nettles, J.; Petro, N.; Runyon, C.; Staid, M.; Sunshine, J.; Taylor, L.A.; Thaisen, K.; Tompkins, S.; Whitten, J.

2011-01-01

High-resolution compositional data from Moon Mineralogy Mapper (M 3) for the Moscoviense region on the lunar farside reveal three unusual, but distinctive, rock types along the inner basin ring. These are designated "OOS" since they are dominated by high concentrations of orthopyroxene, olivine, and Mg-rich spinel, respectively. The OOS occur as small areas, each a few kilometers in size, that are widely separated within the highly feldspathic setting of the basin rim. Although the abundance of plagioclase is not well constrained within the OOS, the mafic mineral content is exceptionally high, and two of the rock types could approach pyroxenite and harzburgite in composition. The third is a new rock type identified on the Moon that is dominated by Mg-rich spinel with no other mafic minerals detectable (lunar crust; they may thus be near contemporaneous with crustal products from the cooling magma ocean. Copyright ?? 2011 by the American Geophysical Union.

Relationships of stable isotopes, water-rock interaction and salinization in fractured aquifers, Petrolina region, Pernambuco State, Brazil

Energy Technology Data Exchange (ETDEWEB)

Silva, Priscila Sousa, E-mail: priscila.silva@cprm.gov.br [Serviço Geológico do Brasil (CPRM), Manaus, AM (Brazil); Campos, José Eloi Guimarães; Cunha, Luciano Soares; Mancini, Luís Henrique, E-mail: eloi@unb.br, E-mail: lucianosc@unb.br, E-mail: lmancini@unb.br [Universidade de Brasília (UnB), Brasília, DF (Brazil)

2018-01-15

The Petrolina County, Pernambuco State, Brazil, presents specificities that make it unique from a hydrogeological point of view. Water resource scarcity is both a quantitative and qualitative issue. The climate is classified as semiarid, having low precipitation, along with high temperatures and evapotranspiration rates. Aquifer zones are related to low connected fractures resulting in a restricted water flow in the aquifer. The recharge is limited and the groundwater salinity is high. Stable isotope analyses of H and O were developed in groundwater samples (with different electrical conductivity) and surface water collected in a bypass channel flowing from the São Francisco River. The results were plotted in a δD ‰ versus δ{sup 18}O ‰ graph along with the curves of the global and local meteoric water line. Groundwater samples showed unexpected results showing a lighter sign pattern when compared to the meteoric waters. More negative δD and δ{sup 18}O values indicate an enrichment in light isotopes, which show that this process is not influenced by surface processes, where the enrichment occurs in heavy isotopes due to evaporation. The isotopic signature observed is interpreted either as resulting from the water-rock interaction, or as resulting from recharge from paleo rains. The waters are old and show restricted flow. So the water-rock contact time is extended. In the rock weathering processes, through the hydration of feldspars, there is preferential assimilation of heavy isotopes at the expense of the lighter ones that remain in the water. Analyses of the {sup 87}Sr/{sup 86}Sr ratio and isotopic groundwater dating assist in the interpretations. (author)

Pattern Recognition of Signals for the Fault-Slip Type of Rock Burst in Coal Mines

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X. S. Liu

2015-01-01

Full Text Available The fault-slip type of rock burst is a major threat to the safety of coal mining, and effectively recognizing its signals patterns is the foundation for the early warning and prevention. At first, a mechanical model of the fault-slip was established and the mechanism of the rock burst induced by the fault-slip was revealed. Then, the patterns of the electromagnetic radiation, acoustic emission (AE, and microseismic signals in the fault-slip type of rock burst were proposed, in that before the rock burst occurs, the electromagnetic radiation intensity near the sliding surface increases rapidly, the AE energy rises exponentially, and the energy released by microseismic events experiences at least one peak and is close to the next peak. At last, in situ investigations were performed at number 1412 coal face in the Huafeng Mine, China. Results showed that the signals patterns proposed are in good agreement with the process of the fault-slip type of rock burst. The pattern recognition can provide a basis for the early warning and the implementation of relief measures of the fault-slip type of rock burst.

Comparative Study on Growth Performance of Transgenic (Over-Expressed OsNHX1 and Wild-Type Nipponbare under Different Salinity Regimes

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Nurul Kahrani ISHAK

2015-11-01

Full Text Available Transgenic Nipponbare which over-expressed a Na+/H+ antiporter gene OsNHX1 was used to compare its growth performance, water status and photosynthetic efficiency with its wild type under varying salinity regimes. Chlorophyll content, quantum yield and photosynthetic rate were measured to assess the impact of salinity stress on photosynthetic efficiency for transgenic and wild-type Nipponbare. Effects of salinity on water status and gas exchange to both lines were studied by measuring water use efficiency, instantaneous transpiration rate and stomatal conductance. Dry shoot weight and leaf area were determined after three months of growth to assess the impacts of salinity on the growth of those two lines. Our study showed that both lines were affected by salinity stress, however, the transgenic line showed higher photosynthetic efficiency, better utilization of water, and better growth due to low transpiration rate and stomatal conductance. Reduction of photosynthetic efficiency exhibited by the wild-type Nipponbare was correlated to its poor growth under salinity stress.

Climatic Oscillations 10,000-155,000 yr B.P. at Owens Lake, California Reflected in Glacial Rock Flour Abundance and Lake Salinity in Core OL-92

Science.gov (United States)

Bischoff, James L.; Menking, Kirsten M.; Fitts, Jeffrey P.; Fitzpatrick, John A.

1997-11-01

Chemical analyses of the acid-soluble and clay-size fractions of sediment samples (1500-yr resolution) reveal oscillations of lake salinity and of glacial advances in core OL-92 back to 155,000 yr B.P. Relatively saline conditions are indicated by the abundance of carbonate and smectite (both pedogenic and authigenic), reflected by Ca, Sr, and Mg in the acid-soluble suite, and by Cs 2O, excess MgO, and LOI (loss on ignition) in the clay-size fraction. Rock flour produced during glacial advances is represented by the abundance of detrital plagioclase and biotite in the clay-size fraction, the ratio of which remains essentially constant over the entire time span. These phases are quantitatively represented by Na 2O, TiO 2, Ba, and Mn in the clay fraction. The rock-flour record indicates two major ice-advances during the penultimate glacial cycle corresponding to marine isotope stage (MIS) 6, no major advances during the last interglaciation (entire MIS 5), and three major advances during the last glacial cycle (MIS 2, 3, and 4). The ages of the latter three correspond rather well to 36Cl dates reported for Sierra Nevada moraines. The onset of the last interglaciation is shown by abrupt increases in authigenic CaCO 3and an abrupt decrease in rock flour, at about 118,000 yr B.P. according to our time scale. In contrast, the boundary appears to be gradual in the δ 18O record in which the change from light to heavy values begins at about 140,000 yrs B.P. The exact position of the termination, therefore, may be proxy-dependent. Conditions of high carbonate and low rock flour prevailed during the entire period from 118,000 yr B.P. until the glacial advance at 53,000 yr B.P. signaled the end of this long interglaciation.

Characterization and differentiation of rock varnish types from different environments by microanalytical techniques

Energy Technology Data Exchange (ETDEWEB)

Macholdt, D. S. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Jochum, K. P. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Pöhlker, C. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Arangio, A. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Förster, J. -D. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Stoll, B. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Weis, U. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Weber, B. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Müller, M. [Max Planck Inst. for Polymer Research, Mainz (Germany); Kappl, M. [Max Planck Inst. for Polymer Research, Mainz (Germany); Shiraiwa, M. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Kilcoyne, A. L. D. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Weigand, M. [Max Planck Inst. for Intelligent Systems, Stuttgart (Germany); Scholz, D. [Johannes Gutenberg Univ., Mainz (Germany); Haug, G. H. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; Al-Amri, A. [King Saud Univ., Riyadh (Saudi Arabia); Andreae, M. O. [Max Planck Society, Mainz (Germany). Max Planck Inst. for Chemistry; King Saud Univ., Riyadh (Saudi Arabia)

2017-04-13

We investigated rock varnishes collected from several locations and environments worldwide by a wide range of microanalytical techniques. These techniques were selected to address the challenges posed by the chemical and structural complexity within the micrometer- to nanometer-sized structures in these geological materials. Femtosecond laser ablation-inductively coupled plasma-mass spectrometry (fs LA-ICP-MS), scanning transmission X-ray microscopy-near edge X-ray adsorption fine structure spectroscopy (STXM-NEXAFS) in combination with scanning electron microscopy (SEM) of focused ion beam (FIB) ultra-thin (100–200 nm) sections, conventional and polarization microscopy, as well as electron paramagnetic resonance (EPR) measurements were used to obtain information about these rock varnishes. Rock varnishes from different environments, which cannot readily be distinguished based on their macroscopic appearance, differ significantly in their constituent elemental mass fractions, e.g., of Mn, Fe, Ni, Co, Ba, and Pb, and their rare earth element (REE) patterns. Structural characteristics such as the particle sizes of embedded dust grains, internal structures such as layers of Mn-, Fe-, and Ca -rich material, and structures such as cavities varied between varnishes from different environments and regions in the world. The EPR spectra were consistent with aged biogenic Mn oxides in all samples, but showed subtle differences between samples of different origin. Our observations allow us to separate rock varnishes into different types, with differences that might be indicators of distinct geneses. Five different types of rock varnish could be distinguished, Type I–V, of which only Type I might be used as potential paleoclimate archive. Each varnish type has specific characteristics in terms of their elemental composition, element distribution, and structures. The combination of element ratios (Mn/Ba, Al/Ni, Mn/REY, Mn/Ce, Mn/Pb, La N /Yb N , and Ce/Ce*), total REE

An evaluation of thematic mapper simulator data for the geobotanical discrimination of rock types in Southwest Oregon

Science.gov (United States)

Weinstock, K. J.; Morrissey, L. A.

1984-01-01

Rock type identification may be assisted by the use of remote sensing of associated vegetation, particularly in areas of dense vegetative cover where surface materials are not imaged directly by the sensor. The geobotanical discrimination of ultramafic parent materials was investigated and analytical techniques for lithologic mapping and mineral exploration were developed. The utility of remotely sensed data to discriminate vegetation types associated with ultramafic parent materials in a study area in southwest Oregon were evaluated. A number of specific objectives were identified, which include: (1) establishment of the association between vegetation and rock types; (2) examination of the spectral separability of vegetation types associated with rock types; (3) determination of the contribution of each TMS band for discriminating vegetation associated with rock types and (4) comparison of analytical techniques for spectrally classifying vegetation.

Phosphorus sorption capacity of biochars varies with biochar type and salinity level.

Science.gov (United States)

Dugdug, Abdelhafid Ahmed; Chang, Scott X; Ok, Yong Sik; Rajapaksha, Anushka Upamali; Anyia, Anthony

2018-02-10

Biochar is recognized as an effective material for recovering excess nutrients, including phosphorus (P), from aqueous solutions. Practically, that benefits the environment through reducing P losses from biochar-amended soils; however, how salinity influences P sorption by biochar is poorly understood and there has been no direct comparison on P sorption capacity between biochars derived from different feedstock types under non-saline and saline conditions. In this study, biochars derived from wheat straw, hardwood, and willow wood were used to compare P sorption at three levels of electrical conductivity (EC) (0, 4, and 8 dS m -1 ) to represent a wide range of salinity conditions. Phosphorus sorption by wheat straw and hardwood biochars increased as aqueous solution P concentration increased, with willow wood biochar exhibiting an opposite trend for P sorption. However, the pattern for P sorption became the same as the other biochars after the willow wood biochar was de-ashed with 1 M HCl and 0.05 M HF. Willow wood biochar had the highest P sorption (1.93 mg g -1 ) followed by hardwood (1.20 mg g -1 ) and wheat straw biochars (1.06 mg g -1 ) in a 25 mg L -1 P solution. Although the pH in the equilibrium solution was higher with willow wood biochar (~ 9.5) than with the other two biochars (~ 6.5), solution pH had no or minor effects on P sorption by willow wood biochar. The high sorption rate of P by willow wood biochar could be attributed to the higher concentrations of salt and other elements (i.e., Ca and Mg) in the biochar in comparison to that in wheat straw and hardwood biochars; the EC values were 2.27, 0.53, and 0.27 dS m -1 for willow wood, wheat straw, and hardwood biochars, respectively. A portion of P desorbed from the willow wood biochar; and that desorption increased with the decreasing P concentration in the aqueous solution. Salinity in the aqueous solution influenced P sorption by hardwood and willow wood but not by wheat straw

Distribution regularities and prospecting of carbonate-siliceous-argillitic rock type uranium deposit in China

International Nuclear Information System (INIS)

Zhao Fengmin; Pan Yan

2012-01-01

The carbonate-siliceous-argillitic rock type uranium deposit is one of the important types of uranium deposits in China. Exogenic permeability type and hydrothermal type are dominated in genetic type. Four mineralization zones, two independent mineralization districts, two potential mineralization zones can be classified in China, uranium mineralization districts can be classified further. They are classified as four levels through the potential metallogenic evaluation on the mineralization districts, an important prospective area in the near future. In order to develop and make use of carbonate-siliceous-argillitic rock type uranium resources, exploration and study should be listed in the development planning on uranium geology. (authors)

Uranium occurrence in major rock types by fission-track mapping

International Nuclear Information System (INIS)

Ledger, E.G.; Bomber, B.J.; Schaftenaar, W.E.; Tieh, T.T.

1984-01-01

Microscopic occurrence of uranium has been determined in about 50 igneous rocks from various location, and in a genetically unrelated sandstone from south Texas. Precambrian granites from the Llano uplift of central Texas contain from a few ppm uranium (considered normal) to over 100 ppm on a whole-rock basis. In granite, uranium is concentrated in: (1) accessory minerals including zircon, biotite, allanite, Fe-Ti oxides, and altered sphene, (2) along grain boundaries and in microfractures by precipitation from deuteric fluids, and (3) as point sources (small inclusions) in quartz and feldspars. Tertiary volcanic rocks from the Davis Mountains of west Texas include diverse rock types from basalt to rhyolite. Average uranium contents increase from 1 ppm in basalts to 7 ppm in rhyolites. Concentration occurs: (1) in iron-titanium-oxides, zircon, and rutile, (2) in the fine-grained groundmass as uniform and point-source concentrations, and (3) as late uranium in cavities associated with banded, silica-rich material. Uranium in ore-grade sandstone is concentrated to more than 3%. Specific occurrences include (1) leucoxene and/or anatase, (2) opaline and calcite cements, (3) mud clasts and altered volcanic rock fragments, and (4) in a few samples, as silt-size uranium- and molybdenum-rich spheres. Uranium content is quite low in pyrite, marcasite, and zeolites

Effects Of Irrigation With Saline Water, And Soil Type On Germination And Seedling Growth Of Sweet Maize (Zea Mays L.)

International Nuclear Information System (INIS)

Mostafa, A.Z.; Amato, M.; Hamdi, A.; Mostafa, A.Z.; Galal, Y.G.M.; Lotfy, S.M.

2012-01-01

Germination and early growth of maize Sweet Maize (Zea mays L.), var. (SEL. CONETA) under irrigation with saline water were investigated in a pot experiment with different soil types. Seven salinity levels of irrigation water up to 12 dS/m were used on a Clay soil (C) and a Sandy-Loam (SL). Emergence of maize was delayed under irrigation with saline water, and the final percentage of germination was reduced only at 8 dS/m or above. Seedling shoot and root growth were reduced starting at 4 dS/m of irrigation water. Salts accumulated more in the C soil but reductions in final germination rate and seedling growth were larger in the SL soil, although differences were not always significant. Data indicate that germination is rather tolerant to salinity level in var. SEL. CONETA whereas seedling growth is reduced at moderate salinity levels, and that soil type affects plant performance under irrigation with saline water

Origin of Boron and Brine Evolution in Saline Springs in the Nangqen Basin, Southern Tibetan Plateau

Directory of Open Access Journals (Sweden)

Ji-long Han

2018-01-01

Full Text Available The Nangqen Basin is a typical shearing-extensional basin situated in the hinterland of the Tibetan Plateau. It contains abundant saline spring resources and abnormal trace element enrichments. The hydrochemical molar ratios (Na/Cl, B/Cl, and Br/Cl, H-O isotopes, and B isotopes of the saline spring were systematically measured to describe the evolution of brines and the origin of the boron. The sodium chloride coefficient of the water samples in this area is around 1.0 or slightly greater, which is characteristic of leached brines; the highest B/Cl value is 4.25 (greater than that of seawater. The Na/Cl, B/Cl, and Br/Cl values of the springs are clear indicators of a crustal origin. The δ18O values of the spring waters range from −12.88‰ to −16.05‰, and the δD values range from −100.91‰ to −132.98‰. Meanwhile the B content and B isotopes in the saline springs are in the ranges of 1.00 to 575.56 ppm and +3.55‰ to +29.59‰, respectively. It has been proven that the saline springs in the Nangqen Basin are a type of leached brine, suggesting that the saline springs have a terrestrial origin. The δ11B-B characteristics of the springs are similar to those observed in the Tibetan geothermal area, indicating that these two places have the same B source. Moreover, they have a crustal origin (marine carbonate rocks and volcanic rocks instead of a deep mantle source.

Climatic Oscillations 10,000-155,000 yr B.P. at Owens Lake, California Reflected in Glacial Rock Flour Abundance and Lake Salinity in Core OL-92

Science.gov (United States)

Bischoff, J.L.; Menking, K.M.; Fitts, J.P.; Fitzpatrick, J.A.

1997-01-01

Chemical analyses of the acid-soluble and clay-size fractions of sediment samples (1500-yr resolution) reveal oscillations of lake salinity and of glacial advances in core OL-92 back to 155,000 yr B.P. Relatively saline conditions are indicated by the abundance of carbonate and smectite (both pedogenic and authigenic), reflected by Ca, Sr, and Mg in the acid-soluble suite, and by Cs2O, excess MgO, and LOI (loss on ignition) in the clay-size fraction. Rock flour produced during glacial advances is represented by the abundance of detrital plagioclase and biotite in the clay-size fraction, the ratio of which remains essentially constant over the entire time span. These phases are quantitatively represented by Na2O, TiO2, Ba, and Mn in the clay fraction. The rock-flour record indicates two major ice-advances during the penultimate glacial cycle corresponding to marine isotope stage (MIS) 6, no major advances during the last interglaciation (entire MIS 5), and three major advances during the last glacial cycle (MIS 2, 3, and 4). The ages of the latter three correspond rather well to 36Cl dates reported for Sierra Nevada moraines. The onset of the last interglaciation is shown by abrupt increases in authigenic CaCO3 and an abrupt decrease in rock flour, at about 118,000 yr B.P. according to our time scale. In contrast, the boundary appears to be gradual in the ??18O record in which the change from light to heavy values begins at about 140,000 yrs B.P. The exact position of the termination, therefore, may be proxy-dependent. Conditions of high carbonate and low rock flour prevailed during the entire period from 118,000 yr B.P. until the glacial advance at 53,000 yr B.P. signaled the end of this long interglaciation. ?? 1997 University of Washington.

Fluid inclusions in jadeitite and jadeite-rich rock from serpentinite mélanges in northern Hispaniola: Trapped ambient fluids in a cold subduction channel

Science.gov (United States)

Kawamoto, Tatsuhiko; Hertwig, Andreas; Schertl, Hans-Peter; Maresch, Walter V.

2018-05-01

Freezing-point depression was measured in aqueous fluid inclusions to determine salinities in six samples of jadeitite and jadeite-rich rock from the Jagua Clara serpentinite mélange of the Rio San Juan Complex, Dominican Republic. The mélange represents a fossil subduction-zone channel from a cold, mature subduction zone with a geothermal gradient of 6 °C/km. One hundred and twenty-five determinations of salinity in primary inclusions hosted in jadeite, quartz, apatite and lawsonite range between extremes of 1.2 and 8.7, but yield a well-defined mean of 4.5 ± 1.1 wt% (±1 s.d.) NaCl equiv, slightly higher than mean seawater (3.5 wt%). In one sample, eight additional fluid inclusions in quartz aligned along grain boundaries yield slightly lower values of 2.7 ± 1.3 wt% NaCl equiv. Homogenization temperatures were also measured for 47 fluid inclusions in two samples, but primary entrapment densities are not preserved. It is significant that the suite includes two types of samples: those precipitated directly from an aqueous fluid as well as examples of metasomatic replacement of a pre-existing magmatic rock. Nevertheless, the results indicate identical salinity for both types and suggest a much stronger genetic link between the two types of jadeitite and jadeite-rich rock than has previously been assumed. Based on the results of conductivity measurements in modern subduction zones, we envision a pervasive fluid in the subduction channel that evolved from salinity levels lower than those in sea-water up to the measured values due to on-going but largely completed serpentinization in the subduction channel. The present data represent a reference marker for the subduction channel of the Rio San Juan intra-oceanic subduction zone at 30-50 km depth and after 50-60 Myr of operation.

Geochemical characteristics of Tertiary saline lacustrine oils in the Western Qaidam Basin, northwest China

International Nuclear Information System (INIS)

Zhu Yangming; Weng Huanxin; Su Aiguo; Liang Digang; Peng Dehua

2005-01-01

Based on the systematic analyses of light hydrocarbon, saturate, aromatic fractions and C isotopes of over 40 oil samples along with related Tertiary source rocks collected from the western Qaidam basin, the geochemical characteristics of the Tertiary saline lacustrine oils in this region was investigated. The oils are characterized by bimodal n-alkane distributions with odd-to-even (C 11 -C 17 ) and even-to-odd (C 18 -C 28 ) predominance, low Pr/Ph (mostly lower than 0.6), high concentration of gammacerane, C 35 hopane and methylated MTTCs, reflecting the high salinity and anoxic setting typical of a saline lacustrine depositional environment. Mango's K 1 values in the saline oils are highly variable (0.99-1.63), and could be associated with the facies-dependent parameters such as Pr/Ph and gammacerane indexes. Compared with other Tertiary oils, the studied Tertiary saline oils are marked by enhanced C 28 sterane abundance (30% or more of C 27 -C 29 homologues), possibly derived from halophilic algae. It is noted that the geochemical parameters of the oils in various oilfields exhibit regular spatial changes, which are consistent with the depositional phase variations of the source rocks. The oils have uncommon heavy C isotopic ratios (-24%o to -26%o) and a flat shape of the individual n-alkane isotope profile, and show isotopic characteristics similar to marine organic matter. The appearance of oleanane and high 24/(24 + 27)-norcholestane ratios (0.57-0.87) in the saline oils and source rocks confirm a Tertiary organic source

THM-coupled modeling of selected processes in argillaceous rock relevant to rock mechanics

International Nuclear Information System (INIS)

Czaikowski, Oliver

2012-01-01

Scientific investigations in European countries other than Germany concentrate not only on granite formations (Switzerland, Sweden) but also on argillaceous rock formations (France, Switzerland, Belgium) to assess their suitability as host and barrier rock for the final storage of radioactive waste. In Germany, rock salt has been under thorough study as a host rock over the past few decades. According to a study by the German Federal Institute for Geosciences and Natural Resources, however, not only salt deposits but also argillaceous rock deposits are available at relevant depths and of extensions in space which make final storage of high-level radioactive waste basically possible in Germany. Equally qualified findings about the suitability/unsuitability of non-saline rock formations require fundamental studies to be conducted nationally because of the comparatively low level of knowledge. The article presents basic analyses of coupled mechanical and hydraulic properties of argillaceous rock formations as host rock for a repository. The interaction of various processes is explained on the basis of knowledge derived from laboratory studies, and open problems are deduced. For modeling coupled processes, a simplified analytical computation method is proposed and compared with the results of numerical simulations, and the limits to its application are outlined. (orig.)

Types, harms and improvement of saline soil in Songnen Plain

Science.gov (United States)

Wang, Zhengjun; Zhuang, Jingjing; Zhao, Anping; Li, Xinxin

2018-03-01

Saline soil is an extremely difficult and modified soil, widely distributed around the world. According to UN-UNESCO and FAO, the world’s saline soil area is about 9.54×108hm2, and there is a growing trend, every year in 1.0×106-1.5×106hm2 speed growth, the effective utilization of land resources to the world is the most serious threat. The total area of saline-alkali land in China is about 9.91×107hm2, including the Songnen Plain, which is called one of the three major saline soil concentrations in the world. The Songnen plain is an important grain producing area in China, and the saline soil occupies most of the Songnen plain, so it is of great significance to study the saline soil and improvement in Songnen plain.

Effects of salinity and sea salt type on egg activation, fertilization, buoyancy and early embryology of European eel, Anguilla anguilla

DEFF Research Database (Denmark)

Sørensen, Sune Riis; Butts, Ian; Munk, Peter

2016-01-01

sizes, while the remaining four salt types resulted in smaller eggs. All salt types except NaCl treatments led to high fertilization rates and had no effect on fertilization success as well as egg neutral buoyancies at 7 h post-fertilization. The study points to the importance of considering ionic...... and egg buoyancy. Egg diameter after activation, using natural seawater adjusted to different salinities, varied among female eels, but no consistent pattern emerged. Activation salinities between 30–40 practical salinity unit (psu) produced higher quality eggs and generally larger egg diameters. Chorion...

Joint simulation of stationary grade and non-stationary rock type for quantifying geological uncertainty in a copper deposit

Science.gov (United States)

Maleki, Mohammad; Emery, Xavier

2017-12-01

In mineral resources evaluation, the joint simulation of a quantitative variable, such as a metal grade, and a categorical variable, such as a rock type, is challenging when one wants to reproduce spatial trends of the rock type domains, a feature that makes a stationarity assumption questionable. To address this problem, this work presents methodological and practical proposals for jointly simulating a grade and a rock type, when the former is represented by the transform of a stationary Gaussian random field and the latter is obtained by truncating an intrinsic random field of order k with Gaussian generalized increments. The proposals concern both the inference of the model parameters and the construction of realizations conditioned to existing data. The main difficulty is the identification of the spatial correlation structure, for which a semi-automated algorithm is designed, based on a least squares fitting of the data-to-data indicator covariances and grade-indicator cross-covariances. The proposed models and algorithms are applied to jointly simulate the copper grade and the rock type in a Chilean porphyry copper deposit. The results show their ability to reproduce the gradual transitions of the grade when crossing a rock type boundary, as well as the spatial zonation of the rock type.

Salinity Trends in the Upper Colorado River Basin Upstream From the Grand Valley Salinity Control Unit, Colorado, 1986-2003

Science.gov (United States)

Leib, Kenneth J.; Bauch, Nancy J.

2008-01-01

Salinity Control Unit was 10,700 tons/year. This accounts for approximately 27 percent of the decrease observed downstream from the Grand Valley Salinity Control Unit. Salinity loads were decreasing at the fastest rate (6,950 tons/year) in Region 4, which drains an area between the Colorado River at Cameo, Colorado (station CAMEO) and Colorado River above Glenwood Springs, Colorado (station GLEN) streamflow-gaging stations. Trends in salinity concentration and streamflow were tested at station CAMEO to determine if salinity concentration, streamflow, or both are controlling salinity loads upstream from the Grand Valley Salinity Control Unit. Trend tests of individual ion concentrations were included as potential indicators of what sources (based on mineral composition) may be controlling trends in the upper Colorado. No significant trend was detected for streamflow from 1986 to 2003 at station CAMEO; however, a significant downward trend was detected for salinity concentration. The trend slope indicates that salinity concentration is decreasing at a median rate of about 3.54 milligrams per liter per year. Five major ions (calcium, magnesium, sodium, sulfate, and chloride) were tested for trends. The results indicate that processes within source areas with rock and soil types (or other unidentified sources) bearing calcium, sodium, and sulfate had the largest effect on the downward trend in salinity load upstream from station CAMEO. Downward trends in salinity load resulting from ground-water sources and/or land-use change were thought to be possible reasons for the observed decreases in salinity loads; however, the cause or causes of the decreasing salinity loads are not fully understood. A reduction in the amount of ground-water percolation from Region 4 (resulting from work done through Federal irrigation system improvement programs as well as privately funded irrigation system improvements) has helped reduce annual salinity load from Region 4 by approxima

Rock Tea extract (Jasonia glutinosa) relaxes rat aortic smooth muscle by inhibition of L-type Ca(2+) channels.

Science.gov (United States)

Valero, Marta Sofía; Oliván-Viguera, Aida; Garrido, Irene; Langa, Elisa; Berzosa, César; López, Víctor; Gómez-Rincón, Carlota; Murillo, María Divina; Köhler, Ralf

2015-12-01

In traditional herbal medicine, Rock Tea (Jasonia glutinosa) is known for its prophylactic and therapeutic value in various disorders including arterial hypertension. However, the mechanism by which Rock Tea exerts blood pressure-lowering actions has not been elucidated yet. Our aim was to demonstrate vasorelaxing effects of Rock Tea extract and to reveal its possible action mechanism. Isometric myography was conducted on high-K+-precontracted rings from rat thoracic aorta and tested extracts at concentrations of 0.5-5 mg/ml. Whole-cell patch-clamp experiments were performed in rat aortic vascular smooth muscle cells (line A7r5) to determine blocking effects on L-type Ca(2+) channels. Rock Tea extract relaxed the aorta contracted by high [K+] concentration dependently with an EC50 of ≈2.4 mg/ml and produced ≈75 % relaxation at the highest concentration tested. The L-type Ca(2+) channel blocker, verapamil (10(-6) M), had similar effects. Rock Tea extract had no effect in nominally Ca(2+)-free high-K(+) buffer but significantly inhibited contractions to re-addition of Ca(2+). Rock Tea extract inhibited the contractions induced by the L-type Ca(2+) channel activator Bay K 8644 (10(-5) M) and by phenylephrine (10(-6) M). Rock Tea extract and Y-27632 (10(-6) M), Rho-kinase inhibitor, had similar effects and the respective effects were not additive. Patch-clamp experiments demonstrated that Rock Tea extract (2.5 mg/ml) virtually abolished L-type Ca(2+) currents in A7r5. We conclude that Rock Tea extract produced vasorelaxation of rat aorta and that this relaxant effect is mediated by inhibition of L-type Ca(2+) channels. Rock Tea extracts may be of phytomedicinal value for prevention and adjuvant treatment of hypertension and other cardiovascular diseases.

The results of the investigations on rock mechanics in HDB-9-11 boreholes and update of the rock mechanical model around the Horonobe URL construction area

International Nuclear Information System (INIS)

Sanada, Hiroyuki; Niunoya, Sumio; Matsui, Hiroya

2008-09-01

Horonobe URL (Underground Research Laboratory) Project is conducted at Horonobe-cho, Teshio-gun, Hokkaido. This research report shows the result of the rock mechanical investigations which have been carried out from 2004 to 2005 as a part of the project. The objectives of the rock mechanical investigation are as follows: To obtain the data which were necessary for construction design of URL. To confirm the distribution of rock mechanical properties in and around URL construction area. The results of the investigations are summarized as follows: 1) Variation and values of depth direction of physical and mechanical properties in the laboratory construction area corresponded approximately to the results obtained from the rock mechanical investigations of HDB-1-8. 2) The major redesign had been not had about physical and mechanical properties in the laboratory construction area being able to divide into three zones and length of its own zone in updating rock mechanical model. 3) From the results of initial stress measured by hydraulic fracturing, the results that the direction of the maximum principle stress is E-W was no different from results obtained from the investigations of HDB-1-8, but the magnitude correlation among maximum, minimum principle stress and overburden pressure measured around G.L.-927 m showed different trends compared with the results of HDB-1-8. 4) Diatomaceous mudstone was yielded under isotropic compression. Cam-clay model as constitutive law of diatomaceous mudstone should be used for tunnel excavation analysis. 5) Uniaxial compression strength of rock saturated under saline water is larger than that of saturated under freshwater. Poisson's ratio of rock saturated under saline water is smaller than that of saturated under saline water. 6) The effective confining pressure increases with the equivalent opening width and permeability decreases. 7) The value of principle stress obtained from DSCA method is larger than that obtained from hydraulic

Salinization and Saline Environments

Science.gov (United States)

Vengosh, A.

2003-12-01

-arid zones. The increasing demand for water has created tremendous pressures on water resources that have resulted in lowering water level and increasing salinization. For example, in the Middle East salinity is the main factor that limits water utilization, and future prospects for water use in Israel, Palestinian Authority, and Jordan are overshadowed by the increasing salinization (Vengosh and Rosenthal, 1994; Salameh, 1996). The salinity problem has numerous grave economic, social, and political consequences, particularly in cross-boundary basins that are shared by different communities (e.g., Salinas Valley California; Vengosh et al., 2002a), friendly states (e.g., salinization of the Colorado River along Mexico-US border; Stanton et al., 2001), and hostile states (e.g., the Jordan River, Vengosh et al., 2001; Aral Basin, Weinthal, 2002; Euphrates River, Beaumont, 1996; and the Nile River, Ohlsson, 1995).Salinization of water resources also affects agricultural management. The type of irrigation water and its quality determine the salinity and fertility of the soil and eventually the quality of the underlying water resource. The use of treated wastewater or other marginal water (e.g., brackish water) depends on the salinity and the chemical composition of the water. Treated wastewater with high contents of chloride, sodium, and boron is suitable only for salt-tolerant crops and requires special treatment of the soil. Finally, high boron in irrigation water and consequently in soil water is also an important limiting factor for crops, as boron is an essential micronutrient for plants but becomes toxic at high levels (typically >0.75 mg L-1 in irrigation water).This chapter investigates the different mechanisms and geochemistry of salinization in different parts of the world. The role of the unsaturated zone in shaping the chemical composition of dryland salinization is discussed. Special emphasis is on the anthropogenic effects and to man-made fluids and reused water

Tourmaline orbicules in peraluminous monzogranites of Argentina: A study case of fluid-rock interaction between leucogranite and country-rock metasediments

Science.gov (United States)

Lira, Raúl; Poklepovic, María F.

2017-12-01

Tourmaline orbicules hosted in peraluminous granites are documented worldwide. Seven occurrences were identified in Argentina. Petrography, mineral chemistry, whole-rock geochemistry mass balance and microthermometric studies were performed in orbicules formed at the cupola of a peraluminous A-type leucogranite (Los Riojanos pluton), as well as complementary investigation was achieved in other orbicules of similar geological setting. Mass balance computations in zoned orbicules consistently confirmed immobility of Si both in core and halo, immobility of K and little loss of Al during halo reactions. Elements gained and lost in the schorl-rich core are Fe, Al, Mg, Ti, Ba, Sr, Y and Zr, and Na, K, Rb and Nb, respectively; in the halo, K, Ba, Sr, Y, Zr and locally CaO, were gained, and Fe, Mg, Na, Al, Rb and Nb were lost. The schorl-rich core is enriched in LREE relative to the leucogranite host. A temperature-salinity plot from fluid inclusion data delineates a magmatic-meteoric mixing trend of diluting salinity with descending temperature. Computed δDH20 values from Los Riojanos orbicule schorl suggest magmatic and magmatic-meteoric mixed origins. In Los Riojanos, mass balance constraints suggest that Fe, Mg, Ba, Sr and metallic traces like Zn and V (±Pb) were most likely derived from country-rock schists and gneisses through fluid-rock exchange reactions. A late magmatic-, volatile-rich- fluid exsolution scenario for the formation of orbicules is envisaged. Schorl crystallization was likely delayed to the latest stages of leucogranite consolidation, not only favored by the high diffusivity of B2O3 preferentially partitioned into the exsolved aqueous-rich fluid, but also likely limited to the low availability of Fe and Mg from the scarce granitic biotite, and to the high F- content of the melt. The spatial confination of orbicules to the contact zone granite-metasediments suggests that orbicules were not formed until exsolved fluids reached the boundary with the

Ion microprobe analyses of aluminous lunar glasses - A test of the 'rock type' hypothesis

Science.gov (United States)

Meyer, C., Jr.

1978-01-01

Previous soil survey investigations found that there are natural groupings of glass compositions in lunar soils and that the average major element composition of some of these groupings is the same at widely separated lunar landing sites. This led soil survey enthusiasts to promote the hypothesis that the average composition of glass groupings represents the composition of primary lunar 'rock types'. In this investigation the trace element composition of numerous aluminous glass particles was determined by the ion microprobe method as a test of the above mentioned 'rock type' hypothesis. It was found that within any grouping of aluminous lunar glasses by major element content, there is considerable scatter in the refractory trace element content. In addition, aluminous glasses grouped by major elements were found to have different average trace element contents at different sites (Apollo 15, 16 and Luna 20). This evidence argues that natural groupings in glass compositions are determined by regolith processes and may not represent the composition of primary lunar 'rock types'.

Characterization of Rock Types at Meridiani Planum, Mars using MER 13-Filter Pancam Spectra

Science.gov (United States)

Nuding, D. L.; Cohen, B. A.

2009-01-01

The Mars Exploration Rover Opportunity has traversed more than 13 km across Meridiani Planum, finding evidence of ancient aqueous environments that, in the past, may have been suitable for life. Meridiani bedrock along the rover traverse is a mixture in composition and bulk mineralogy between a sulfate-rich sedimentary rock and hematite spherules ("blueberries"). On top of the bedrock, numerous loose rocks exist. These rocks consist of both local bedrock and "cobbles" of foreign origin. The cobbles provide a window into lithologic diversity and a chance to understand other types of martian rocks and meteorites. This study was also an attempt to establish a method to expand upon those of Mini-TES to remotely identify rocks of interest to make efficient use of the rover s current resources.

Cooling of a polyethylene tunnel type greenhouse by means of a rock bed

Energy Technology Data Exchange (ETDEWEB)

Kurklu, Ahmet; Bilgin, Sefai [Akdeniz Univ., Dept. of Agricultural Mechanisation, Antalya (Turkey)

2004-10-01

An experiment was conducted to cool a 15 m{sup 2} ground area plastic-tunnel-type greenhouse by the use of a rock bed. An identical greenhouse with no rock bed was also erected for control purposes. Two rock-bed canals, each with the dimensions of 3 x l.25 x 0.75 m, were dug in the soil of the experimental greenhouse. After the canals were filled with the rocks and insulated, the top surface was covered by a soil layer of thickness enough for the root development depth of the plants. Air was pushed through the rock bed by a centrifugal fan with a 1100 m{sup 3}/h flow rate. Energy stored in the rock bed during the day was dumped outside the greenhouse at night using the cooler outside air. The results of the measurements showed that the rock-bed system maintained air temperature 14 deg C lower at maximum in the experimental greenhouse than the control one. The temperature difference seemed to increase with increasing solar radiation and outside air temperature. Relative humidity during the day remained at about 40% in the experimental greenhouse and was always higher than that in the control one. The coefficient of performance (COP) of the rock-bed system was higher than 3 in general, and it was observed that this value increased with decreasing rock-bed temperature. The average solar collection efficiency was 38%. The rock-bed system seems to have a significant potential for cooling applications in greenhouses. (Author)

Change in behavior of uniaxial compression due to degradation of salt water and freezing and thawing for rock

International Nuclear Information System (INIS)

Yamamoto, Kiyohito; Kobayashi, Akira; Aoyama, Shigeyasu

2007-01-01

To investigate the effect of the degradation on the mechanical behavior, the degraded rock samples were prepared to the uniaxial compression test. The degradation methods are divided into two types. One type is submerged in the 10% saline water (10%NaCl) for 90 days, and another one is freezing and thawing for 240 cycles. The degraded Smaland-granites were preserved in saline water. Kurihashi-granodiorite, Tage-tuff and Funyu-tuff were imposed on freezing and thawing test to make degraded state. The damage parameters were identified from the stress-strain relation obtained from the uniaxial compression tests. The damage parameters are K υ , n υ , K d , n d and B 0 . K υ and n υ are related to expansive strain. K d , n d and B 0 are subject to behavior of Young's modulus. By investigating the change in the damage parameters of the degraded rock, the effect of the degradation was tried to infer. As the results, it was inferred using the damage parameters that the Smaland-granite becomes more expansive material and the damage occurs earlier due to saline water degradation. Moreover, it was considered that the Kurihashi-granodiorite and Tage-tuff become more expansive and the axial strain at the failure decreases by freezing and thawing degradation, however the axial strain of the Funyu-tuff at the failure becomes large. It was found the proposed damage parameters can be good index for volumetric strain behavior after degradation. (author)

Ore-forming environment and ore-forming system of carbonaceous-siliceous-pelitic rock type uranium deposit in China

International Nuclear Information System (INIS)

Qi Fucheng; Zhang Zilong; Li Zhixing; He Zhongbo; Wang Wenquan

2012-01-01

It is proposed that there are four types of ore-forming systems about carbonaceous-siliceous-pelitic rock type uranium deposit in China based on systematic study on structural environment and distribution regularity of uraniferous construction of marine carbonaceous-siliceous-pelitic rock in China: continental margin rift valley ore-forming systems, continental margin rifting deep fracture zone ore-forming systems, landmass boundary borderland basin ore-forming systems and epicontinental mobile belt downfaulted aulacogen ore-forming systems. It is propounded definitely that it is controlled by margin rift valley ore-forming systems and continental margin rifting deep fracture zone ore-forming systems for large-scale uranium mineralization of carbonaceous-siliceous-pelitic rock type uranium deposit in China, which is also controlled by uraniferous marine carbonaceous-siliceous-pelitic rock construction made up of silicalite, siliceous phosphorite and carbonaceous-siliceous-pelitic rock, which settled down accompany with submarine backwash and sub marine volcanic eruption in margin rift valley and continental margin rifting mineralizing environment. Continental mar gin rift valley and continental margin rifting thermal sedimentation or exhalation sedimentation is the mechanism of forming large-scale uraniferous marine carbonaceous-siliceous-pelitic rock construction Early Palaeozoic Era in China or large-scale uranium-polymetallic mineralization. (authors)

Tracing groundwater salinization processes in coastal aquifers: a hydrogeochemical and isotopic approach in Na-Cl brackish waters of north-western Sardinia, Italy

Science.gov (United States)

Mongelli, G.; Monni, S.; Oggiano, G.; Paternoster, M.; Sinisi, R.

2013-01-01

In the Mediterranean area the demand of good quality water is often threatened by salinization, especially in coastal areas. The salinization is the result of concomitant processes due to both marine water intrusion and rock-water interaction, which in some cases are hardly distinguishable. In northwestern Sardinia, in the Nurra area, salinization due to marine water intrusion has been recently evidenced as consequence of bore hole exploitation. However, the geology of the Nurra records a long history from Paleozoic to Quaternary, resulting in relative structural complexity and in a wide variety of lithologies, including Triassic evaporites. To elucidate the origin of the saline component in the Nurra aquifer, may furnish a useful and more general model for the salinization processes in the Mediterranean area, where the occurrence of evaporitic rocks in coastal aquifers is a common feature. In addition, due to intensive human activities and recent climatic changes, the Nurra has become vulnerable to desertification and, similarly to other Mediterranean islands, surface-water resources can periodically suffer from drastic shortage. With this in mind we report new data, regarding brackish waters of Na-Cl type of the Nurra, including major ions and selected trace elements (B, Br, I and Sr) and isotopic data, including δ18O, δD in water, and δ34S and δ18O in dissolved sulphate. To better depict the origin of the salinity we also analyzed a set of Nurra Triassic evaporites for mineralogical and isotopic composition. The brackish waters have Cl contents up to 2025 mg L-1 and the ratios between dissolved ions and chlorine, with the exception of the Br/Cl ratio, are not those expected on the basis of a simple mixing between rain water and seawater. The δ18O and δD data indicate that most of the waters are within the Regional Meteoric Water Line and the Global Meteoric Water Line supporting the idea that they are meteoric in origin. A relevant consequence of the

A computer-assisted rock type data catalogue for gas formations; Ein rechnergestuetzter Gesteinsdatenkatalog fuer Gasformationen

Energy Technology Data Exchange (ETDEWEB)

Reitenbach, V.; Pusch, G.; Moeller, M.; Koll, S. [TU Clausthal (Germany). Inst. fuer Erdoel- und Erdgastechnik; Constantini, A.; Junker, A.; Anton, H. [RWE Dea AG, Hamburg (Germany)

2007-09-13

Modern reservoir management commonly requires versatile reservoir data which are neces-sary for integrated reservoir characterization, evaluation and development planning. The rock data necessary for numerical reservoir simulation studies often have to be collected from different sources, analysed and sorted with a considerable effort. In a framework of DGMK research program (DGMK project 593-9/4), the Institute of Petro-leum Engineering (Clausthal University of Technology) and RWE DEA AG have developed a new tool named Rock Data Catalogue, which is capable of managing large amounts of rock data more efficiently and deriving new specific correlations for European rock types. The use of Rock Data Catalogue can facilitate the essential input data generation and proc-essing procedure for reservoir simulation studies. The Rock Data Catalogue is comprised of a Data Base Module of digitalized reservoir rock data and an interactive Data Correlation Module. Both modules are built-up as an interface to common reservoir simulation software. The universal structure of the software also makes it possible to exchange the data with other rock data information systems. The Data Correlation Module implements a ''Decision-Structure'' module, which helps the reservoir engineer to select the rock data for analysis and correlation depending on its litho-facial type and permeability class. The Data Base Module enables a quick search of appro-priated data sets and their export into the correlation module. The open source data of the North German Rotliegend gas formations as well as the data of measurements on Rotliegend core samples performed at the ITE in course of the DGMK tight gas projects were implemented in the rock data base. Correlations of poro/perm data, two-phase flow and capillary pressure functions of the Rotliegend sandstones with the per-meability range between 20 and 0.01 mD are implemented in the rock data base and serve for quality checking of the

Ocean acidification narrows the acute thermal and salinity tolerance of the Sydney rock oyster Saccostrea glomerata.

Science.gov (United States)

Parker, Laura M; Scanes, Elliot; O'Connor, Wayne A; Coleman, Ross A; Byrne, Maria; Pörtner, Hans-O; Ross, Pauline M

2017-09-15

Coastal and estuarine environments are characterised by acute changes in temperature and salinity. Organisms living within these environments are adapted to withstand such changes, yet near-future ocean acidification (OA) may challenge their physiological capacity to respond. We tested the impact of CO 2 -induced OA on the acute thermal and salinity tolerance, energy metabolism and acid-base regulation capacity of the oyster Saccostrea glomerata. Adult S. glomerata were acclimated to three CO 2 levels (ambient 380μatm, moderate 856μatm, high 1500μatm) for 5weeks (24°C, salinity 34.6) before being exposed to a series of acute temperature (15-33°C) and salinity (34.2-20) treatments. Oysters acclimated to elevated CO 2 showed a significant metabolic depression and extracellular acidosis with acute exposure to elevated temperature and reduced salinity, especially at the highest CO 2 of 1500μatm. Our results suggest that the acute thermal and salinity tolerance of S. glomerata and thus its distribution will reduce as OA continues to worsen. Copyright © 2017 Elsevier Ltd. All rights reserved.

Groundwater salinity at Olkiluoto and its effects on a spent fuel repository

Energy Technology Data Exchange (ETDEWEB)

Vieno, T. [VTT Energy, Espoo (Finland)

2000-06-01

The Olkiluoto island rose from the Baltic Sea 2500 to 3000 years ago. The layered sequence of groundwaters can be related to climatic and shoreline changes from modern tune through former Baltic stages to the deglaciation phase about 10 000 years ago and even to preglacial times. Fresh groundwater is found to the depth of about 150 metres, brackish between 100 and 400 metres, deeper groundwaters are saline. At the depth of 500 meters, the content of Total Dissolved Solids (TDS) varies between 10 and 25 g/l. The most saline waters at depths greater than 800 metres have TDS values between 30 and 75 g/l. These deep saline waters seem to have been undisturbed during the most recent glaciation and even much longer in the past. Today fresh water infiltrating at the surface gradually displaces brackish and saline groundwater in the bedrock. Due to the still ongoing postglacial land uplift, Olkiluoto is likely to become an inland site with brackish or fresh groundwater at the depth of 500 metres within the next 10 000 years. During the construction and operation phases groundwater will be drawn into the repository from the surrounding bedrock. As a consequence, more saline groundwaters, presently laying 100 to 200 metres below the repository level, may rise to the disposal level. After the closing of the repository the salinity distribution will gradually return towards the natural state. During the glacial cycle groundwater salinity may increase, for example, during freezing of groundwater into permafrost, when dissolved solids concentrate in the remaining water phase, and in a situation where deep saline groundwaters from under the centre of the glacier are pushed to the upper parts of the bedrock at the periphery of the glacier. The most significant open issue related to saline groundwater is the performance of the tunnel backfill which in the BS-3 concept has been planned to consist of a mixture of crushed rock and 10-30% of bentonite. Saline groundwater may

Petrology and geochemistry of mafic magmatic rocks from the Sarve-Abad ophiolites (Kurdistan region, Iran): Evidence for interaction between MORB-type asthenosphere and OIB-type components in the southern Neo-Tethys Ocean

Science.gov (United States)

Saccani, Emilio; Allahyari, Khalil; Rahimzadeh, Bahman

2014-05-01

The Sarve-Abad (Sawlava) ophiolites crop out in the Main Zagros Thrust Zone and represent remnants of the Mesozoic southern Neo-Tethys Ocean that was located between the Arabian shield and Sanandaj-Sirjan continental block. They consist of several incomplete ophiolitic sequences including gabbroic bodies, a dyke complex, and pillow lava sequences. These rocks generally range from sub-alkaline to transitional character. Mineral chemistry and whole-rock geochemistry indicate that they have compositions akin to enriched-type mid-ocean ridge basalts (E-MORB) and plume-type MORB (P-MORB). Nonetheless, the different depletion degrees in heavy rare earth elements (HREE), which can be observed in both E-MORB like and P-MORB like rocks enable two main basic chemical types of rocks to be distinguished as Type-I and Type-II. Type-I rocks are strongly depleted in HREE (YbN 9.0). Petrogenetic modeling shows that Type-I rocks originated from 7 to 16% polybaric partial melting of a MORB-type mantle source, which was significantly enriched by plume-type components. These rocks resulted from the mixing of variable fractions of melts generated in garnet-facies and the spinel-facies mantle. In contrast, Type-II rocks originated from 5 to 8% partial melting in the spinel-facies of a MORB-type source, which was moderately enriched by plume-type components. A possible tectono-magmatic model for the generation of the southern Neo-Tethys oceanic crust implies that the continental rift and subsequent oceanic spreading were associated with uprising of MORB-type asthenospheric mantle featuring plume-type component influences decreasing from deep to shallow mantle levels. These deep plume-type components were most likely inherited from Carboniferous mantle plume activity that was associated with the opening of Paleo-Tethys in the same area.

Salinization mechanisms in semi-arid regions

International Nuclear Information System (INIS)

Santiago, M.M.F.

1984-01-01

During a period of three years the basins of the Pereira de Miranda and Caxitore dams, located in the crystalline rock area of Ceara, Brazil, were studied in order to determine the mechanisms of salinization of their waters. Isotope methods ( 18 O/ 16 O) and hidrochemistry (determination of the of the maior ions) were applied to surface, underground and rain water in this study. An isotope model was designed and applied to the determination of evaporation and percolation of dams in semi-arid zones during the dry season. The results are compared to those from a conventional chemical model. As causes of salinization of the water in the dams, the contributions of the rain itself and the lixiviation of the soil are quantified. An interaction between the dams and the underground water is imperceptible. The salinization of the underground water is attributed to recharge of the aquifer with rain water from the surface runoff followed by evaporation of the water rising, due to capilarity, in a one-directional flow to the surface. (Author) [pt

Effect of Soil Salinity, Type and Amount of Nitrogen Fertilizer on Yield and Biochemical Properties of Mustard (Brassica rapa L.

Directory of Open Access Journals (Sweden)

S Tandisseh

2017-03-01

Full Text Available Introduction Soil salinity is a major limiting factor in agricultural development within Iran. Nitrogen is the most important nutrient that its uptake is limited over other elements under saline conditions due to decrease in the permeability of plant roots, soil microbial activity and mineralization of organic compounds and nitrate uptake by high concentrations of chloride anions in the root zone of the plant. Mustard plant has a good compatibility to weather conditions and since there is an extreme need of vegetable oilseed in our country and also wide extent of saline soils in Iran, this study was conducted to determine the best type and amount of nitrogen fertilizers between calcium nitrate and ammonium sulfate under saline conditions. Materials and Methods A greenhouse experiment was conducted in a completely randomized design (factorial with three replications in February 2012 in the Research greenhouse of the Ferdowsi University of Mashhad. The treatments were consisted of two types of nitrogen fertilizer (calcium nitrate and ammonium sulfate, each with three levels of N (40, 80 and 120 mg per kg of soil in three levels of soil salinity (C0= control, C1= 5 and C2= 10dS m-1. Experimental soil (control collected from agricultural experimental station was leached by salt solutions containing salts of calcium chloride, magnesium chloride and sodium sulfate with specified concentrations and ratios during 50 days to reach the similar salt concentrations of leached water consisting the desired levels of salinity. The seeds of mustard were planted at a depth of one centimeter in soil of each pot and were irrigated with tap water to field capacity (by weight. Plants were harvested after 5 months and plant fresh and dry weights and nitrogen concentration and uptake of plant were measured by the Kjeldahl method. Irrigation water and physical and chemical properties of soil before and after harvest were determined. Data obtained were analyzed using

Preliminary state-of-the-art survey: mining techniques for salt and other rock types

Energy Technology Data Exchange (ETDEWEB)

1976-12-01

This is a systematic review of the state-of-the-art of underground mining and excavation technology in the U.S. as applied to salt, limestone, shale, and granite. Chapter 2 covers the basic characteristics of these rock types, the most frequently used underground mining methods, shaft and slope entry construction, equipment, and safety and productivity data. Chapters 3 and 4 summarize underground salt and limestone mining in the U.S. Chapter 5 shows that large amounts of thick shale exist in the U.S., but little is mined. Chapter 6 discusses underground excavations into granite-type rocks. Suggestions are given in the last chapter for further study. (DLC)

Site investigation SFR. Rock type coding, overview geological mapping and identification of rock units and possible deformation zones in drill cores from the construction of SFR

Energy Technology Data Exchange (ETDEWEB)

Petersson, Jesper (Vattenfall Power Consultant AB, Stockholm (Sweden)); Curtis, Philip; Bockgaard, Niclas (Golder Associates AB (Sweden)); Mattsson, Haakan (GeoVista AB, Luleaa (Sweden))

2011-01-15

This report presents the rock type coding, overview lithological mapping and identification of rock units and possible deformation zones in drill cores from 32 boreholes associated with the construction of SFR. This work can be seen as complementary to single-hole interpretations of other older SFR boreholes earlier reported in /Petersson and Andersson 2010/: KFR04, KFR08, KFR09, KFR13, KFR35, KFR36, KFR54, KFR55, KFR7A, KFR7B and KFR7C. Due to deficiencies in the available material, the necessary activities have deviated somewhat from the established methodologies used during the recent Forsmark site investigations for the final repository for spent nuclear fuel. The aim of the current work has been, wherever possible, to allow the incorporation of all relevant material from older boreholes in the ongoing SFR geological modelling work in spite of the deficiencies. The activities include: - Rock type coding of the original geological mapping according to the nomenclature used during the preceding Forsmark site investigation. As part of the Forsmark site investigation such rock type coding has already been performed on most of the old SFR boreholes if the original geological mapping results were available. This earlier work has been complemented by rock type coding on two further boreholes: KFR01 and KFR02. - Lithological overview mapping, including documentation of (1) rock types, (2) ductile and brittle-ductile deformation and (3) alteration for drill cores from eleven of the boreholes for which no original geological borehole mapping was available (KFR31, KFR32, KFR34, KFR37,KFR38, KFR51, KFR69, KFR70, KFR71, KFR72 and KFR89). - Identification of possible deformation zones and merging of similar rock types into rock units. This follows SKB's established criteria and methodology of the geological Single-hole interpretation (SHI) process wherever possible. Deviations from the standard SHI process are associated with the lack of data, for example BIPS images

Site investigation SFR. Rock type coding, overview geological mapping and identification of rock units and possible deformation zones in drill cores from the construction of SFR

International Nuclear Information System (INIS)

Petersson, Jesper; Curtis, Philip; Bockgaard, Niclas; Mattsson, Haakan

2011-01-01

This report presents the rock type coding, overview lithological mapping and identification of rock units and possible deformation zones in drill cores from 32 boreholes associated with the construction of SFR. This work can be seen as complementary to single-hole interpretations of other older SFR boreholes earlier reported in /Petersson and Andersson 2010/: KFR04, KFR08, KFR09, KFR13, KFR35, KFR36, KFR54, KFR55, KFR7A, KFR7B and KFR7C. Due to deficiencies in the available material, the necessary activities have deviated somewhat from the established methodologies used during the recent Forsmark site investigations for the final repository for spent nuclear fuel. The aim of the current work has been, wherever possible, to allow the incorporation of all relevant material from older boreholes in the ongoing SFR geological modelling work in spite of the deficiencies. The activities include: - Rock type coding of the original geological mapping according to the nomenclature used during the preceding Forsmark site investigation. As part of the Forsmark site investigation such rock type coding has already been performed on most of the old SFR boreholes if the original geological mapping results were available. This earlier work has been complemented by rock type coding on two further boreholes: KFR01 and KFR02. - Lithological overview mapping, including documentation of (1) rock types, (2) ductile and brittle-ductile deformation and (3) alteration for drill cores from eleven of the boreholes for which no original geological borehole mapping was available (KFR31, KFR32, KFR34, KFR37,KFR38, KFR51, KFR69, KFR70, KFR71, KFR72 and KFR89). - Identification of possible deformation zones and merging of similar rock types into rock units. This follows SKB's established criteria and methodology of the geological Single-hole interpretation (SHI) process wherever possible. Deviations from the standard SHI process are associated with the lack of data, for example BIPS images, or a

Scottish saline lagoons: Impacts and challenges of climate change

Science.gov (United States)

Angus, Stewart

2017-11-01

The majority of Scotland's saline lagoons are located on the low-lying coastlines of the Western Isles and the northern archipelagos of Orkney and Shetland, where recorded annual relative sea level rise rates are among the highest in Scotland. The sediment-impounded lagoons of Orkney and Shetland will either lose their impoundment and become incorporated in marine coastal waters, or become increasingly saline, as relative sea levels rise. The rock-basin lagoons of the Western Isles will retain their restricted exchange with the sea but will also become more saline with rising sea level. Specialist lagoonal organisms tend to have wide salinity tolerances but may succumb to competition from marine counterparts. In all areas, there are sufficient fresh-water inland water bodies with potential to be captured as lagoons to compensate for loss of extent and number, but the specialist lagoon biota tend to have limited dispersal powers. It is thus possible that they will be unable to transfer to their analogue sites before existing lagoons become fully marine, giving conservation managers the problem of deciding on management options: leave natural processes to operate without interference, manage the saline inflow to maintain the current salinity regime, or translocate lagoon organisms perceived as threatened by rising salinities. Timing of conversion and capture is unpredictable due to local topography and complications caused by variable stratification.

Measurements of distribution coefficient for Sn, Pb and Th on sand stone and tuff in saline type groundwater

International Nuclear Information System (INIS)

Nakazawa, Toshiyuki; Okada, Kenichi; Muroi, Masayuki; Shibata, Masahiro; Sasamoto, Hiroshi

2004-02-01

Japan Nuclear Cycle Development Institute (JNC) has developed the sorption database for bentonite and rocks in order to assess the retardation capacities of important radioactive elements in natural and engineered barriers in the H12 report. However, there are not enough distribution coefficient data for radioactive elements in saline type groundwater in the database. Sn (tin), Pb (lead) and Th(thorium) are important radioactive elements for performance assessment of high level radioactive waste disposal, thus we carried out the batch sorption experiments for these radioactive elements on sand stone and tuff. The experiments for each radioactive element were performed on the following conditions; Sn: Kd measurements using the solutions (distilled water or artificial sea water) reacted with sand stone. Pb: Kd measurements using solution (artificial sea water) reacted with sand stone or tuff. Th: Kd measurements using solution (artificial sea water) reacted with sand stone as a function of carbonate concentration. The results of experiment are summarized below; In the case of Sn, Kd were 0.4-1 m 3 /kg in distilled water type and approximately 1 m 3 /kg in artificial sea water type. And also, Kd was 0.3 m 3 /kg in artificial sea water adjusted Ph 12. In artificial sea water type, it was suggested that Kd decreased with pH. In the case of Pb, Kd were approximately 2 m 3 /kg on sand stone and 4-10 m 3 /kg on tuff in artificial sea water type. Kd on tuff was a little larger than that on sand stone. There were no distinctly differences depending on solid-liquid separation methods. In the case of Th, Kd was approximately 1-8 m 3 /kg in artificial sea water type. On the other hand, sorption of Th on sand stone was not observed (i.e., Kd = 0 m 3 /kg) in high carbonate solution. It was estimated that low Kd in high carbonate solution might be caused by speciation of because Th could form the anions in the solution such as hydroxo-carbonate complexes and carbonate complexes

Application of Rock-Eval pyrolysis to the detection of hydrocarbon property in sandstone-type uranium deposits

International Nuclear Information System (INIS)

Sun Ye; Li Ziying; Guo Qingyin; Xiao Xinjian

2006-01-01

Rock-Eval pyrolysis is introduced into the research of uranium geology by means of oil-gas geochemical evaluation. Hydrocarbon (oil-gas) components in DS sandstone-type uranium deposit are detected quantitatively. Through analyzing the oil-gas bearing categories of the uranium-bearing sandstones, the internal relationships between the uranium deposit and the oil-gas are revealed. Rock-Eval pyrolysis is an effective method to study the interaction between inorganic and organic matters, and should be extended to the study of sandstone-type uranium deposits. (authors)

An review on geology study of carbonaceous-siliceous-pelitic rock type uranium deposit in China and the strategy for its development

International Nuclear Information System (INIS)

Zhao Fengmin

2009-01-01

Carbonaceous-siliceous-pelitic rock type uranium deposit was founded by Chinese uranium geologist, it refers to the uranium deposit hosted by non or light metamophosed carbonate,siliceous rock, pelitic rock and their intermediates. It is one of the important types uranium deposit in China. A lot of this type deposits have been discovered in China and their temporal-spatial distribution pattern and mineralization features have been basically identified, and the rich experience have layed a good foundation for the future exploration. Although the ore of this type is not favourable economically, it is still available. Because carbonaceous-siliceous-pelitic rock type uranium deposit has great resource potential, metallogenic study and exploration efforts should be projected differentially according to their economic profit so as to meet the uranium resource demand of nuclear power development in China. (authors)

Tracing groundwater salinization processes in coastal aquifers: a hydrogeochemical and isotopic approach in the Na-Cl brackish waters of northwestern Sardinia, Italy

Directory of Open Access Journals (Sweden)

G. Mongelli

2013-07-01

Full Text Available Throughout the Mediterranean, salinization threatens water quality, especially in coastal areas. This salinization is the result of concomitant processes related to both seawater intrusion and water–rock interaction, which in some cases are virtually indistinguishable. In the Nurra region of northwestern Sardinia, recent salinization related to marine water intrusion has been caused by aquifer exploitation. However, the geology of this region records a long history from the Palaeozoic to the Quaternary, and is structurally complex and comprises a wide variety of lithologies, including Triassic evaporites. Determining the origin of the saline component of the Jurassic and Triassic aquifers in the Nurra region may provide a useful and more general model for salinization processes in the Mediterranean area, where the occurrence of evaporitic rocks in coastal aquifers is a common feature. In addition, due to intensive human activity and recent climatic change, the Nurra has become vulnerable to desertification and, in common with other Mediterranean islands, surface water resources periodically suffer from severe shortages. With this in mind, we report new data regarding brackish and surface waters (outcrop and lake samples of the Na-Cl type from the Nurra region, including major ions and selected trace elements (B, Br, I, and Sr, in addition to isotopic data including δ18O, δD in water, and δ34S and δ18O in dissolved SO4. To identify the origin of the salinity more precisely, we also analysed the mineralogical and isotopic composition of Triassic evaporites. The brackish waters have Cl contents of up to 2025 mg L−1 , and the ratios between dissolved ions and Cl, with the exception of the Br / Cl ratio, are not those expected on the basis of simple mixing between rainwater and seawater. The δ18O and δD data indicate that most of the waters fall between the regional meteoric water line and the global meteoric water line, supporting the

Tracing groundwater salinization processes in coastal aquifers: a hydrogeochemical and isotopic approach in the Na-Cl brackish waters of northwestern Sardinia, Italy

Science.gov (United States)

Mongelli, G.; Monni, S.; Oggiano, G.; Paternoster, M.; Sinisi, R.

2013-07-01

Throughout the Mediterranean, salinization threatens water quality, especially in coastal areas. This salinization is the result of concomitant processes related to both seawater intrusion and water-rock interaction, which in some cases are virtually indistinguishable. In the Nurra region of northwestern Sardinia, recent salinization related to marine water intrusion has been caused by aquifer exploitation. However, the geology of this region records a long history from the Palaeozoic to the Quaternary, and is structurally complex and comprises a wide variety of lithologies, including Triassic evaporites. Determining the origin of the saline component of the Jurassic and Triassic aquifers in the Nurra region may provide a useful and more general model for salinization processes in the Mediterranean area, where the occurrence of evaporitic rocks in coastal aquifers is a common feature. In addition, due to intensive human activity and recent climatic change, the Nurra has become vulnerable to desertification and, in common with other Mediterranean islands, surface water resources periodically suffer from severe shortages. With this in mind, we report new data regarding brackish and surface waters (outcrop and lake samples) of the Na-Cl type from the Nurra region, including major ions and selected trace elements (B, Br, I, and Sr), in addition to isotopic data including δ18O, δD in water, and δ34S and δ18O in dissolved SO4. To identify the origin of the salinity more precisely, we also analysed the mineralogical and isotopic composition of Triassic evaporites. The brackish waters have Cl contents of up to 2025 mg L-1 , and the ratios between dissolved ions and Cl, with the exception of the Br / Cl ratio, are not those expected on the basis of simple mixing between rainwater and seawater. The δ18O and δD data indicate that most of the waters fall between the regional meteoric water line and the global meteoric water line, supporting the conclusion that they are

Summary of northern Atlantic coastal plain hydrology and its relation to disposal of high-level radioactive waste in buried crystalline rock; a preliminary appraisal

Science.gov (United States)

Lloyd, O.B.; Larson, J.D.; Davis, R.W.

1985-01-01

Interpretation of available hydrologic data suggests that some areas beneath the Coastal Plain in the States of Delaware, Maryland, New Jersey, North Carolina, and Virginia might have some potential for the disposal of nuclear waste in crystalline rock that is buried beneath the Coastal Plain sediments. The areas of major interest occur where the top of the basement rock lies between 1,000 and 4,000 feet below sea level, the aquifer(s) immediately above the basement rock are saturated with saline water, confining material overlies the saline water bearing aquifer(s), and groundwater flow in the saline water aquifer(s) can be established. Preliminary data on (1) the distribution and thickness of the lowermost aquifers and confining beds, (2) the distribution of hydraulic conductivity in the lowermost aquifers, (3) estimated hydraulic heads and inferred direction of lateral groundwater flow for 1980, and (4) the distribution of saline water and brine, indicate eastern parts of the study area relatively best meet most of the criteria proposed for sediments that would overlie any potential buried crystalline-rock disposal site.

Application feasibility study of evaluation technology for long-term rock behavior. 2. Parameter setting of variable compliance type model and application feasibility study for rock behavior evaluation

International Nuclear Information System (INIS)

Sato, Shin; Noda, Masaru; Niunoya, Sumio; Hata, Koji; Matsui, Hiroya; Mikake, Shinichiro

2012-01-01

Creep phenomenon is one of the long-term rock behaviors. In many of rock-creep studies, model and parameter have been verified in 2D analysis using model parameter acquired by uniaxial compression test etc considering rock types. Therefore, in this study model parameter was set by uniaxial compression test with classified rock samples which were taken from pilot boring when the main shaft was constructed. Then, comparison between measured value and 3D excavation analysis with identified parameter was made. By and large, the study showed that validity of identification methodology of parameter to identify reproduction of measured value and analysis method. (author)

Average contents of uranium and thorium in the most important types of rocks of the Ukrainian shield

International Nuclear Information System (INIS)

Belevtsev, Ya.N.; Egorov, Yu.P.; Titov, V.K.; Sukhinin, A.M.; Grechishnikova, Z. M.; Zayats, V.B.; Tikhonenko, V.A.; Zhukova, A.M.

1975-01-01

The data given concern uranium and thorium contents in the most important rock types of the Ukraina shield. The smallest quantities of uranium are characteristic for the vulcanic rocks of basic and ultrabasic rocks. Archean formations, whose source materials were mainly basic and ultrabasic vulcanites, are marked by this low uranium content. The highest uranium content is observed in the clastogenic rocks of low Proterozoic. The average uranium content is observed in silty argellite rocks represented by crystal slates and paragneissis. Rheomorphic and metasomatic granites and granosyenites of low and middle Proterozoic are also characterized by an increased content of uranium. The platform precipitation rocks of high Proterozoic possess a relatively low uranium content. Thorium concentrations with low thorium-uranium proportions in granites, syenites and granosyenites prove their enrichment in uranium

Trend Analysis of Soil Salinity in Different Land Cover Types Using Landsat Time Series Data (case Study Bakhtegan Salt Lake)

Science.gov (United States)

Taghadosi, M. M.; Hasanlou, M.

2017-09-01

Soil salinity is one of the main causes of desertification and land degradation which has negative impacts on soil fertility and crop productivity. Monitoring salt affected areas and assessing land cover changes, which caused by salinization, can be an effective approach to rehabilitate saline soils and prevent further salinization of agricultural fields. Using potential of satellite imagery taken over time along with remote sensing techniques, makes it possible to determine salinity changes at regional scales. This study deals with monitoring salinity changes and trend of the expansion in different land cover types of Bakhtegan Salt Lake district during the last two decades using multi-temporal Landsat images. For this purpose, per-pixel trend analysis of soil salinity during years 2000 to 2016 was performed and slope index maps of the best salinity indicators were generated for each pixel in the scene. The results of this study revealed that vegetation indices (GDVI and EVI) and also salinity indices (SI-1 and SI-3) have great potential to assess soil salinity trends in vegetation and bare soil lands respectively due to more sensitivity to salt features over years of study. In addition, images of May had the best performance to highlight changes in pixels among different months of the year. A comparative analysis of different slope index maps shows that more than 76% of vegetated areas have experienced negative trends during 17 years, of which about 34% are moderately and highly saline. This percent is increased to 92% for bare soil lands and 29% of salt affected soils had severe salinization. It can be concluded that the areas, which are close to the lake, are more affected by salinity and salts from the lake were brought into the soil which will lead to loss of soil productivity ultimately.

Hydrogeologic framework and salinity distribution of the Floridan aquifer system of Broward County, Florida

Science.gov (United States)

Reese, Ronald S.; Cunningham, Kevin J.

2014-01-01

Concerns about water-level decline and seawater intrusion in the surficial Biscayne aquifer, currently the principal source of water supply to Broward County, prompted a study to refine the hydrogeologic framework of the underlying Floridan aquifer system to evaluate its potential as an alternative source of supply. This report presents cross sections that illustrate the stratigraphy and hydrogeology in eastern Broward County; maps of the upper surfaces and thicknesses of several geologic formations or units within the Floridan aquifer system; and maps of two of the potentially productive water-bearing zones within the system, the Upper Floridan aquifer and the Avon Park permeable zone. An analysis of data on rock depositional textures, associated pore networks, and flow zones in the Floridan aquifer system shows that groundwater moves through the system in two ways. These data support a conceptual, dual-porosity model of the system wherein groundwater moves either as concentrated flow in discrete, thin bedding-plane vugs or zones of vuggy megaporosity, or as diffuse flow through rocks with primarily interparticle and moldic-particle porosity. Because considerable exchange of groundwater may occur between the zones of vuggy and matrix-dominated porosity, understanding the distribution of that porosity and flow zone types is important to evaluating the suitability of the several units within the Floridan aquifer system for managing the water through practices such as aquifer storage and recovery (ASR). The salinity of the water in the Floridan aquifer system is highest in the central part of the study area, and lower toward the north and south. Although salinity generally increases with depth, in the western part of the study area a zone of relatively high saline water is perched above water of lower salinity in the underlying Avon Park permeable zone. Overall, the areas of highest salinity in the aquifer system coincide with those with the lowest estimated

Simulation of CO2 Sequestration at Rock Spring Uplift, Wyoming: Heterogeneity and Uncertainties in Storage Capacity, Injectivity and Leakage

Energy Technology Data Exchange (ETDEWEB)

Deng, Hailin [Los Alamos National Laboratory; Dai, Zhenxue [Los Alamos National Laboratory; Jiao, Zunsheng [Wyoming State Geological Survey; Stauffer, Philip H. [Los Alamos National Laboratory; Surdam, Ronald C. [Wyoming State Geological Survey

2011-01-01

Many geological, geochemical, geomechanical and hydrogeological factors control CO{sub 2} storage in subsurface. Among them heterogeneity in saline aquifer can seriously influence design of injection wells, CO{sub 2} injection rate, CO{sub 2} plume migration, storage capacity, and potential leakage and risk assessment. This study applies indicator geostatistics, transition probability and Markov chain model at the Rock Springs Uplift, Wyoming generating facies-based heterogeneous fields for porosity and permeability in target saline aquifer (Pennsylvanian Weber sandstone) and surrounding rocks (Phosphoria, Madison and cap-rock Chugwater). A multiphase flow simulator FEHM is then used to model injection of CO{sub 2} into the target saline aquifer involving field-scale heterogeneity. The results reveal that (1) CO{sub 2} injection rates in different injection wells significantly change with local permeability distributions; (2) brine production rates in different pumping wells are also significantly impacted by the spatial heterogeneity in permeability; (3) liquid pressure evolution during and after CO{sub 2} injection in saline aquifer varies greatly for different realizations of random permeability fields, and this has potential important effects on hydraulic fracturing of the reservoir rock, reactivation of pre-existing faults and the integrity of the cap-rock; (4) CO{sub 2} storage capacity estimate for Rock Springs Uplift is 6614 {+-} 256 Mt at 95% confidence interval, which is about 36% of previous estimate based on homogeneous and isotropic storage formation; (5) density profiles show that the density of injected CO{sub 2} below 3 km is close to that of the ambient brine with given geothermal gradient and brine concentration, which indicates CO{sub 2} plume can sink to the deep before reaching thermal equilibrium with brine. Finally, we present uncertainty analysis of CO{sub 2} leakage into overlying formations due to heterogeneity in both the target saline

Studies of electrical properties of low-resistivity sandstones based on digital rock technology

Science.gov (United States)

Yan, Weichao; Sun, Jianmeng; Zhang, Jinyan; Yuan, Weiguo; Zhang, Li; Cui, Likai; Dong, Huaimin

2018-02-01

Electrical properties are important parameters to quantitatively calculate water saturation in oil and gas reservoirs by well logging interpretation. It is usual that oil layers show high resistivity responses, while water layers show low-resistivity responses. However, there are low-resistivity oil zones that exist in many oilfields around the world, leading to difficulties for reservoir evaluation. In our research, we used digital rock technology to study different internal and external factors to account for low rock resistivity responses in oil layers. We first constructed three-dimensional digital rock models with five components based on micro-computed tomography technology and x-ray diffraction experimental results, and then oil and water distributions in pores were determined by the pore morphology method. When the resistivity of each component was assigned, rock resistivities were calculated by using the finite element method. We collected 20 sandstone samples to prove the effectiveness of our numerical simulation methods. Based on the control variate method, we studied the effects of different factors on the resistivity indexes and rock resistivities. After sensitivity analyses, we found the main factors which caused low rock resistivities in oil layers. For unfractured rocks, influential factors arranged in descending order of importance were porosity, clay content, temperature, water salinity, heavy mineral, clay type and wettability. In addition, we found that the resistivity index could not provide enough information to identify a low-resistivity oil zone by using laboratory rock-electric experimental results. These results can not only expand our understandings of the electrical properties of low-resistivity rocks from oil layers, but also help identify low-resistivity oil zones better.

Chemical quality of surface waters and sedimentation in the Saline River basin, Kansas

Science.gov (United States)

Jordan, Paul Robert; Jones, B.F.; Petri, Lester R.

1964-01-01

This report gives the results of an investigation of the sediment and dissolved minerals that are transported by the Saline River and its tributaries. The Saline River basin is in western and central Kansas; it is long and narrow and covers 3,420 square miles of rolling plains, which is broken in some places by escarpments and small areas of badlands. In the western part the uppermost bedrock consists predominantly of calcareous elastic sedimentary rocks of continental origin of Pliocene age and in most places is covered by eolian deposits of Pleistocene and Recent age. In the central part the ex posed bedrock consists predominantly of calcareous marine sedimentary rocks of Late Cretaceous age. In the eastern part the exposed bedrock consists mainly of noncalcareous continental and littoral elastic sedimentary rocks of Early Cretaceous and Permian age. Fluvial deposits are in the valleys, and eolian materials are present over much of the uplands. Average precipitation increases rather uniformly from about 18 inches per year in the west to almost 28 inches per year in the east. Runoff is not affected by irrigation nor regulated by large structures, but it is closely related to precipitation. Average runoff increases from less than 0.2 inch per year in the west to more than 1.5 inches per year in the east. Aquifers of the flood-plain and terrace deposits and of the Cretaceous Dakota Sandstone are the major sources of ground-water accretion to the streams. In the upper reaches of the Saline River, the water is only slightly mineralized; during the period of record the specific conductance near Wakeeney never exceeded 750 micromhos per centimeter. In the lower reaches, however, the water is slightly mineralized during periods of high flow and is highly mineralized during periods of low flow; the specific conductance near Russell exceeded 1,500 micromhos per centimeter more than 80 percent of the time. Near Russell, near Wilson, and at Tescott the water is of the

Hard-Rock Stability Analysis for Span Design in Entry-Type Excavations with Learning Classifiers

Directory of Open Access Journals (Sweden)

Esperanza García-Gonzalo

2016-06-01

Full Text Available The mining industry relies heavily on empirical analysis for design and prediction. An empirical design method, called the critical span graph, was developed specifically for rock stability analysis in entry-type excavations, based on an extensive case-history database of cut and fill mining in Canada. This empirical span design chart plots the critical span against rock mass rating for the observed case histories and has been accepted by many mining operations for the initial span design of cut and fill stopes. Different types of analysis have been used to classify the observed cases into stable, potentially unstable and unstable groups. The main purpose of this paper is to present a new method for defining rock stability areas of the critical span graph, which applies machine learning classifiers (support vector machine and extreme learning machine. The results show a reasonable correlation with previous guidelines. These machine learning methods are good tools for developing empirical methods, since they make no assumptions about the regression function. With this software, it is easy to add new field observations to a previous database, improving prediction output with the addition of data that consider the local conditions for each mine.

Hard-Rock Stability Analysis for Span Design in Entry-Type Excavations with Learning Classifiers.

Science.gov (United States)

García-Gonzalo, Esperanza; Fernández-Muñiz, Zulima; García Nieto, Paulino José; Bernardo Sánchez, Antonio; Menéndez Fernández, Marta

2016-06-29

The mining industry relies heavily on empirical analysis for design and prediction. An empirical design method, called the critical span graph, was developed specifically for rock stability analysis in entry-type excavations, based on an extensive case-history database of cut and fill mining in Canada. This empirical span design chart plots the critical span against rock mass rating for the observed case histories and has been accepted by many mining operations for the initial span design of cut and fill stopes. Different types of analysis have been used to classify the observed cases into stable, potentially unstable and unstable groups. The main purpose of this paper is to present a new method for defining rock stability areas of the critical span graph, which applies machine learning classifiers (support vector machine and extreme learning machine). The results show a reasonable correlation with previous guidelines. These machine learning methods are good tools for developing empirical methods, since they make no assumptions about the regression function. With this software, it is easy to add new field observations to a previous database, improving prediction output with the addition of data that consider the local conditions for each mine.

Effects of temperature and salinity on resting metabolism in two ...

African Journals Online (AJOL)

This study investigates the resting metabolic rate (RMR; mg O2 g/h) of the resident rock pool fish Caffrogobius caffer and the transient sparid Diplodus sargus capensis at a range of salinities (5, 15, 25, 35 and 45 PSU) and temperatures (14, 20 and 28°C) using closed-vessel respirometry. Both species were temperature ...

Rock mechanics for hard rock nuclear waste repositories

International Nuclear Information System (INIS)

Heuze, F.E.

1981-09-01

The mined geologic burial of high level nuclear waste is now the favored option for disposal. The US National Waste Terminal Storage Program designed to achieve this disposal includes an extensive rock mechanics component related to the design of the wastes repositories. The plan currently considers five candidate rock types. This paper deals with the three hard rocks among them: basalt, granite, and tuff. Their behavior is governed by geological discontinuities. Salt and shale, which exhibit behavior closer to that of a continuum, are not considered here. This paper discusses both the generic rock mechanics R and D, which are required for repository design, as well as examples of projects related to hard rock waste storage. The examples include programs in basalt (Hanford/Washington), in granitic rocks (Climax/Nevada Test Site, Idaho Springs/Colorado, Pinawa/Canada, Oracle/Arizona, and Stripa/Sweden), and in tuff

Aerodynamic control of NASP-type vehicles through vortex manipulation. Volume 3: Wing rock experiments

Science.gov (United States)

Suarez, Carlos J.; Smith, Brooke C.; Kramer, Brian R.; Ng, T. Terry; Ong, Lih-Yenn; Malcolm, Gerald N.

1993-01-01

Free-to-roll tests were conducted in water and wind tunnels in an effort to investigate the mechanisms of wing rock on a NASP-type vehicle. The configuration tested consisted of a highly-slender forebody and a 78 deg swept delta wing. In the water tunnel test, extensive flow visualization was performed and roll angle histories were obtained. In the wind tunnel test, the roll angle, forces and moments, and limited forebody and wing surface pressures were measured during the wing rock motion. A limit cycle oscillation was observed for angles of attack between 22 deg and 30 deg. In general, the experiments confirmed that the main flow phenomena responsible for the wing-body-tail wing rock are the interactions between the forebody and the wing vortices. The variation of roll acceleration (determined from the second derivative of the roll angle time history) with roll angle clearly slowed the energy balance necessary to sustain the limit cycle oscillation. Different means of suppressing wing rock by controlling the forebody vortices using small blowing jets were also explored. Steady blowing was found to be capable of suppressing wing rock, but significant vortex asymmetrices are created, causing the model to stop at a non-zero roll angle. On the other hand, alternating pulsed blowing on the left and right sides of the fore body was demonstrated to be a potentially effective means of suppressing wing rock and eliminating large asymmetric moments at high angles of attack.

Geophysical, geochemical and hydrological analyses of water-resource vulnerability to salinization: case of the Uburu-Okposi salt lakes and environs, southeast Nigeria

Science.gov (United States)

Ukpai, S. N.; Okogbue, C. O.

2017-11-01

Until this study, the location and depth of the saline units in Uburu-Okposi salt lake areas and environs have been unknown. This study aimed at delineating the saline lithofacies and dispersal configurations to water bodies, using electrical geophysical methods such as constant separation traversing (CST) and vertical electrical sounding (VES). Results showed weathered zones that represent aquifers mostly at the fourth geoelectric layer: between upper layered aquitards and underlying aquitards at depths 30-140 m. Lateral distribution of resistivity variance was defined by the CST, whereas the VES tool, targeted at low-resistivity zones, detected isolated saline units with less than 10 ohm-m at depths generally >78 m. The saline lithofacies were suspected to link freshwater zones via shear zones, which steer saline water towards the salt lakes and influence the vulnerability of groundwater to salinization. The level of salinization was verified by water sampling and analysis, and results showed general alkaline water type with a mean pH of 7.66. Water pollution was indicated: mean total dissolved solids (TDS) 550 mg/l, electrical conductivity (EC) 510 μS/cm, salinity 1.1‰, Cl- 200 mg/l, N03 -35.5 mg/l, Na+ 19.6 mg/l and Ca2+ 79.3 mg/l. The salinity is controlled by NaCl salt, as deduced from correlation analysis using the software package Statistical Product for Service Solutions (SPSS). Generally, concentrations of dissolved ions in the water of the area are enhanced via mechanisms such as evaporation, dissociation of salts, precipitation run off and leaching of dissolved rock minerals.

Epigenetic alterations of sedimentary rocks at deposits

International Nuclear Information System (INIS)

Komarova, G.V.; Kondrat'eva, I.A.; Zelenova, O.I.

1980-01-01

Notions are explained, and technique for studying epigenetic alterations of sedimentary rocks at uranium deposits is described. Main types of epigenetic transformations and their mineralogic-geochemical characteristics are considered. Rock alterations, accompanying uranium mineralization, can be related to 2 types: oxidation and reduction. The main mineralogic-geochemical property of oxidation transformations is epigenetic limonitization. Stratal limonitization in primary grey-coloured terrigenic rocks and in epigenetically reduced (pyritized) rocks, as well as in rock, subjected to epigenetic gleying, are characterized. Reduction type of epigenetic transformations is subdivided into sulphidic and non-sulphidic (gley) subtypes. Sulphidic transformations in grey-coloured terrigenic rocks with organic substance of carbonic row, in rocks, containing organic substance of oil row, sulphide transformations of sedimentary rocks, as well as gley transformations, are considered

Intraspecific variation in growth of marsh macrophytes in response to salinity and soil type: Implications for wetland restoration

Science.gov (United States)

Howard, R.J.

2010-01-01

Genetic diversity within plant populations can influence plant community structure along environmental gradients. In wetland habitats, salinity and soil type are factors that can vary along gradients and therefore affect plant growth. To test for intraspecific growth variation in response to these factors, a greenhouse study was conducted using common plants that occur in northern Gulf of Mexico brackish and salt marshes. Individual plants of Distichlis spicata, Phragmites australis, Schoenoplectus californicus, and Schoenoplectus robustus were collected from several locations along the coast in Louisiana, USA. Plant identity, based on collection location, was used as a measure of intraspecific variability. Prepared soil mixtures were organic, silt, or clay, and salinity treatments were 0 or 18 psu. Significant intraspecific variation in stem number, total stem height, or biomass was found in all species. Within species, response to soil type varied, but increased salinity significantly decreased growth in all individuals. Findings indicate that inclusion of multiple genets within species is an important consideration for marsh restoration projects that include vegetation plantings. This strategy will facilitate establishment of plant communities that have the flexibility to adapt to changing environmental conditions and, therefore, are capable of persisting over time. ?? Coastal and Estuarine Research Federation 2009.

THM-coupled modeling of selected processes in argillaceous rock relevant to rock mechanics; THM-Gekoppelte Modellierung ausgewaehlter gesteinsmechanisch relevanter Prozesse im Tongestein

Energy Technology Data Exchange (ETDEWEB)

Czaikowski, Oliver [Gesellschaft fuer Anlagen- und Reaktorsicherheit (GRS) mbH, Braunschweig (Germany). Repository Safety Research Div.

2012-08-15

Scientific investigations in European countries other than Germany concentrate not only on granite formations (Switzerland, Sweden) but also on argillaceous rock formations (France, Switzerland, Belgium) to assess their suitability as host and barrier rock for the final storage of radioactive waste. In Germany, rock salt has been under thorough study as a host rock over the past few decades. According to a study by the German Federal Institute for Geosciences and Natural Resources, however, not only salt deposits but also argillaceous rock deposits are available at relevant depths and of extensions in space which make final storage of high-level radioactive waste basically possible in Germany. Equally qualified findings about the suitability/unsuitability of non-saline rock formations require fundamental studies to be conducted nationally because of the comparatively low level of knowledge. The article presents basic analyses of coupled mechanical and hydraulic properties of argillaceous rock formations as host rock for a repository. The interaction of various processes is explained on the basis of knowledge derived from laboratory studies, and open problems are deduced. For modeling coupled processes, a simplified analytical computation method is proposed and compared with the results of numerical simulations, and the limits to its application are outlined. (orig.)

A survey of lunar rock types and comparison of the crusts of earth and moon

Science.gov (United States)

Wood, J. A.

1977-01-01

The principal known types of lunar rocks are briefly reviewed, and their chemical relationships discussed. In the suite of low-KREEP highland rocks, Fe/(Fe + Mg) in the normative mafic minerals increases and the albite content of normative plagio-clase decreases as the total amount of normative plagioclase increases, the opposite of the trend predicted by the Bowen reaction principle. The distribution of compositions of rocks from terrestrial layered mafic intrusives is substantially different: here the analyses fall in several discrete clusters (anorthositic rocks, norites, granophyres and ferrogabbros, ultramafics), and the chemical trends noted above are not reproduced. It is suggested that the observed trends in lunar highland rocks could be produced by crystal fractionation in a deep global surface magma system if (1) plagiociase tended to float, upon crystallization, and (2) the magma was kept agitated and well mixed (probably by thermal convection) until crystallization was far advanced and relatively little residual liquid was left. After the crustal system solidified, but before extensive cooling had developed a thick, strong lithosphere, mantle convection was able to draw portions of the lunar anorthositic crust down into the mantle.

Fluid and rock interaction in permeable volcanic rock

International Nuclear Information System (INIS)

Lindley, J.I.

1985-01-01

Four types of interrelated changes -geochemical, mineralogic, isotopic, and physical - occur in Oligocene volcanic units of the Mogollon-Datil volcanic field, New Mexico. These changes resulted from the operation of a geothermal system that, through fluid-rock interaction, affected 5 rhyolite ash-flow tuffs and an intercalated basaltic andesite lava flow causing a potassium metasomatism type of alteration. (1) Previous studies have shown enrichment of rocks in K 2 O as much as 130% of their original values at the expense of Na 2 O and CaO with an accompanying increase in Rb and decreases in MgO and Sr. (2) X-ray diffraction results of this study show that phenocrystic plagioclase and groundmass feldspar have been replaced with pure potassium feldspar and quartz in altered rock. Phenocrystic potassium feldspar, biotite, and quartz are unaffected. Pyroxene in basaltic andesite is replaced by iron oxide. (3) delta 18 O increases for rhyolitic units from values of 8-10 permil, typical of unaltered rock, to 13-15 permil, typical of altered rock. Basaltic andesite, however, shows opposite behavior with a delta 18 of 9 permil in unaltered rock and 6 permit in altered. (4) Alteration results in a density decrease. SEM revealed that replacement of plagioclase by fine-grained quartz and potassium feldspar is not a volume for volume replacement. Secondary porosity is created in the volcanics by the chaotic arrangement of secondary crystals

Statistical analysis of Thematic Mapper Simulator data for the geobotanical discrimination of rock types in southwest Oregon

Science.gov (United States)

Morrissey, L. A.; Weinstock, K. J.; Mouat, D. A.; Card, D. H.

1984-01-01

An evaluation of Thematic Mapper Simulator (TMS) data for the geobotanical discrimination of rock types based on vegetative cover characteristics is addressed in this research. A methodology for accomplishing this evaluation utilizing univariate and multivariate techniques is presented. TMS data acquired with a Daedalus DEI-1260 multispectral scanner were integrated with vegetation and geologic information for subsequent statistical analyses, which included a chi-square test, an analysis of variance, stepwise discriminant analysis, and Duncan's multiple range test. Results indicate that ultramafic rock types are spectrally separable from nonultramafics based on vegetative cover through the use of statistical analyses.

Improved characterization of reservoir behavior by integration of reservoir performances data and rock type distributions

Energy Technology Data Exchange (ETDEWEB)

Davies, D.K.; Vessell, R.K. [David K. Davies & Associates, Kingwood, TX (United States); Doublet, L.E. [Texas A& M Univ., College Station, TX (United States)] [and others

1997-08-01

An integrated geological/petrophysical and reservoir engineering study was performed for a large, mature waterflood project (>250 wells, {approximately}80% water cut) at the North Robertson (Clear Fork) Unit, Gaines County, Texas. The primary goal of the study was to develop an integrated reservoir description for {open_quotes}targeted{close_quotes} (economic) 10-acre (4-hectare) infill drilling and future recovery operations in a low permeability, carbonate (dolomite) reservoir. Integration of the results from geological/petrophysical studies and reservoir performance analyses provide a rapid and effective method for developing a comprehensive reservoir description. This reservoir description can be used for reservoir flow simulation, performance prediction, infill targeting, waterflood management, and for optimizing well developments (patterns, completions, and stimulations). The following analyses were performed as part of this study: (1) Geological/petrophysical analyses: (core and well log data) - {open_quotes}Rock typing{close_quotes} based on qualitative and quantitative visualization of pore-scale features. Reservoir layering based on {open_quotes}rock typing {close_quotes} and hydraulic flow units. Development of a {open_quotes}core-log{close_quotes} model to estimate permeability using porosity and other properties derived from well logs. The core-log model is based on {open_quotes}rock types.{close_quotes} (2) Engineering analyses: (production and injection history, well tests) Material balance decline type curve analyses to estimate total reservoir volume, formation flow characteristics (flow capacity, skin factor, and fracture half-length), and indications of well/boundary interference. Estimated ultimate recovery analyses to yield movable oil (or injectable water) volumes, as well as indications of well and boundary interference.

Rock.XML - Towards a library of rock physics models

Science.gov (United States)

Jensen, Erling Hugo; Hauge, Ragnar; Ulvmoen, Marit; Johansen, Tor Arne; Drottning, Åsmund

2016-08-01

Rock physics modelling provides tools for correlating physical properties of rocks and their constituents to the geophysical observations we measure on a larger scale. Many different theoretical and empirical models exist, to cover the range of different types of rocks. However, upon reviewing these, we see that they are all built around a few main concepts. Based on this observation, we propose a format for digitally storing the specifications for rock physics models which we have named Rock.XML. It does not only contain data about the various constituents, but also the theories and how they are used to combine these building blocks to make a representative model for a particular rock. The format is based on the Extensible Markup Language XML, making it flexible enough to handle complex models as well as scalable towards extending it with new theories and models. This technology has great advantages as far as documenting and exchanging models in an unambiguous way between people and between software. Rock.XML can become a platform for creating a library of rock physics models; making them more accessible to everyone.

Salinity-dependent contact angle alteration in oil/brine/silicate systems : The effect of temperature

NARCIS (Netherlands)

Haagh, Martin E.J.; Schilderink, Nathalie; Duits, Michel H.G.; Siretanu, Igor; Mugele, Frieder; Collins, Ian R.

To understand the success of low salinity water flooding in improving oil recovery, it is important to identify the molecular scale mechanisms that control the wettability and thus the adhesion between oil and rock. Previous experiments have attributed the wettability alteration in core flood

Desiccation-crack-induced salinization in deep clay sediment

Directory of Open Access Journals (Sweden)

S. Baram

2013-04-01

Full Text Available A study on water infiltration and solute transport in a clayey vadose zone underlying a dairy farm waste source was conducted to assess the impact of desiccation cracks on subsurface evaporation and salinization. The study is based on five years of continuous measurements of the temporal variation in the vadose zone water content and on the chemical and isotopic composition of the sediment and pore water in it. The isotopic composition of water stable isotopes (δ18O and δ2H in water and sediment samples, from the area where desiccation crack networks prevail, indicated subsurface evaporation down to ~ 3.5 m below land surface, and vertical and lateral preferential transport of water, following erratic preferential infiltration events. Chloride (Cl− concentrations in the vadose zone pore water substantially increased with depth, evidence of deep subsurface evaporation and down flushing of concentrated solutions from the evaporation zones during preferential infiltration events. These observations led to development of a desiccation-crack-induced salinization (DCIS conceptual model. DCIS suggests that thermally driven convective air flow in the desiccation cracks induces evaporation and salinization in relatively deep sections of the subsurface. This conceptual model supports previous conceptual models on vadose zone and groundwater salinization in fractured rock in arid environments and extends its validity to clayey soils in semi-arid environments.

Disc cutter wear and rock texture in hard rock TBM tunneling

International Nuclear Information System (INIS)

Koizumi, Yu; Tsusaka, Kimikazu; Tanimoto, Chikaosa; Nakagawa, Shigeo; Fujita, Naoya

2008-01-01

Disc cutter wear in TBM tunneling is caused by initial fragmentation of a solid rock face (the primary fragmentation) and fragmentation of residual rock pieces between a cutterhead and the face (the secondary fragmentation). In two projects through sedimentary and granitic rocks, the authors investigated the relationships between the rate of cutter wear caused by the primary fragmentation, point load index and the grain size and contents of abrasive minerals. As a result, it was found that the tensile strength and the mineral contents of rocks significantly influenced the cutter wear in both projects and thus it is necessary to take into account of rock type. (author)

Salinity change in the Baltic Sea during the last 8,500 years: evidence, causes and models

Energy Technology Data Exchange (ETDEWEB)

Westman, Per; Wastegaard, Stefan; Schoning, Kristian [Stockholm Univ. (Sweden). Dept. of Quaternary Research; Gustafsson, Bo [Oceanus Havsundersoekningar, Goeteborg (Sweden); Omstedt, Anders [SMHI, Norrkoeping (Sweden)

1999-12-01

The salinity influences which ecosystems will dominate in the coastal area and what property radionuclides have. Salinity is also an important boundary condition for the transport models in the geosphere. Knowledge about the past salinity is important background to evaluate the hydrology and geochemistry in the rock and further to assess the radiological consequences of possible releases from a radioactive repository. This report concerns the salinity in the Baltic Sea during the last 8500 calendar years BP. Shore-level data for the inlet areas and proxy (indirect) data for the palaeo-salinity and the climate are reviewed. These data is further used in a steady-state model for the salt exchange between the Baltic Sea and Kattegat. This will then be extended to a model of the future development of the salinity in the Baltic Sea. We conclude that the changes in the inlet cross-section areas together with a 15% to 60% lower net freshwater input compared to the present input can explain the higher salinity in the Baltic Sea during earlier times.

Salinity change in the Baltic Sea during the last 8,500 years: evidence, causes and models

International Nuclear Information System (INIS)

Westman, Per; Wastegaard, Stefan; Schoning, Kristian; Omstedt, Anders

1999-12-01

The salinity influences which ecosystems will dominate in the coastal area and what property radionuclides have. Salinity is also an important boundary condition for the transport models in the geosphere. Knowledge about the past salinity is important background to evaluate the hydrology and geochemistry in the rock and further to assess the radiological consequences of possible releases from a radioactive repository. This report concerns the salinity in the Baltic Sea during the last 8500 calendar years BP. Shore-level data for the inlet areas and proxy (indirect) data for the palaeo-salinity and the climate are reviewed. These data is further used in a steady-state model for the salt exchange between the Baltic Sea and Kattegat. This will then be extended to a model of the future development of the salinity in the Baltic Sea. We conclude that the changes in the inlet cross-section areas together with a 15% to 60% lower net freshwater input compared to the present input can explain the higher salinity in the Baltic Sea during earlier times

Hydrological characteristics of Japanese rock

International Nuclear Information System (INIS)

Ijiri, Yuji; Sawada, Atsushi; Akahori, Kuniaki

1999-11-01

It is crucial to evaluate the hydrogeological characteristics of rock in Japan in order to assess the performance of geosphere. This report summarizes the hydrogeological characteristics of various rock types obtained from broad literature surveys and the fields experiments at the Kamaishi mine in northern Japan and at the Tono mine in central Japan. It is found that the hydraulic conductivity of rock mass ranges from 10 -9 m/s to 10 -8 m/s, whereas the hydraulic conductivity of fault zone ranges from 10 -9 m/s to 10 -3 m/s. It is also found that the hydraulic conductivity tends to decrease with depth. Therefore, the hydraulic conductivity of rock mass at the depth of a repository will be smaller than above values. From the investigations at outcrops and galleries throughout the country, fractures are observed as potential pathways in all rock types. All kinds of crystalline rocks and pre-Neogene sedimentary rocks are classified as fractured media where fracture flow is dominant. Among these rocks, granitic rock is considered the archetype fractured media. On the other hand, andesite, tuff and Neogene sedimentary rocks are considered as intermediate between fractured media and porous media where flow in fractures as well as in rock matrix are significant. (author)

Rock properties data base

Energy Technology Data Exchange (ETDEWEB)

Jackson, R.; Gorski, B.; Gyenge, M.

1991-03-01

As mining companies proceed deeper and into areas whose stability is threatened by high and complex stress fields, the science of rock mechanics becomes invaluable in designing underground mine strata control programs. CANMET's Mining Research Laboratories division has compiled a summary of pre- and post-failure mechanical properties of rock types which were tested to provide design data. The 'Rock Properties Data Base' presents the results of these tests, and includes many rock types typical of Canadian mine environments. The data base also contains 'm' and 's' values determined using Hoek and Brown's failure criteria for both pre- and post-failure conditions. 7 refs., 3 tabs., 9 figs., 1 append.

Towards a theory of ecotone resilience: coastal vegetation on a salinity gradient.

Science.gov (United States)

Jiang, Jiang; Gao, Daozhou; DeAngelis, Donald L

2012-08-01

Ecotones represent locations where vegetation change is likely to occur as a result of climate and other environmental changes. Using a model of an ecotone vulnerable to such future changes, we estimated the resilience of the ecotone to disturbances. The specific ecotone is that between two different vegetation types, salinity-tolerant and salinity-intolerant, along a gradient in groundwater salinity. In the case studied, each vegetation type, through soil feedback loops, promoted local soil salinity levels that favor itself in competition with the other type. Bifurcation analysis was used to study the system of equations for the two vegetation types and soil salinity. Alternative stable equilibria, one for salinity-tolerant and one for salinity intolerant vegetation, were shown to exist over a region of the groundwater salinity gradient, bounded by two bifurcation points. This region was shown to depend sensitively on parameters such as the rate of upward infiltration of salinity from groundwater into the soil due to evaporation. We showed also that increasing diffusion rates of vegetation can lead to shrinkage of the range between the two bifurcation points. Sharp ecotones are typical of salt-tolerant vegetation (mangroves) near the coastline and salt-intolerant vegetation inland, even though the underlying elevation and groundwater salinity change very gradually. A disturbance such as an input of salinity to the soil from a storm surge could upset this stable boundary, leading to a regime shift of salinity-tolerant vegetation inland. We showed, however, that, for our model as least, a simple pulse disturbance would not be sufficient; the salinity would have to be held at a high level, as a 'press', for some time. The approach used here should be generalizable to study the resilience of a variety of ecotones to disturbances. Published by Elsevier Inc.

A chemical redox reaction to generate rock salt-type materials: the case of Na3V2O5.

Science.gov (United States)

Adamczyk, E; Anger, E; Freire, M; Pralong, V

2018-02-27

Chemical redox reactions are extremely efficient to prepare fully reduced or oxidized phases that are formed during the topotactic insertion/extraction of alkaline ions. Herein, we report these reactions and discuss the possibility to generate new ordered or disordered rock salt-type structures depending on the structure of the mother phase. We have shown that a disordered rock salt-type structure is formed when the transition element is located at the tetrahedral site, as exemplified by the formation of Na 3 V 2 O 5 upon chemical reduction of V 2 O 5 .

Rock Physics of Reservoir Rocks with Varying Pore Water Saturation and Pore Water Salinity

DEFF Research Database (Denmark)

Katika, Konstantina

experiments, the rock is subjected to high external stresses that resemble the reservoir stresses; 2) the fluid distribution within the pore space changes during the flow through experiments and wettability alterations may occur; 3) different ions, present in the salt water injected in the core, interact......Advanced waterflooding (injection of water with selective ions in reservoirs) is a method of enhanced oil recovery (EOR) that has attracted the interest of oil and gas companies that exploit the Danish oil and gas reservoirs. This method has been applied successfully in oil reservoirs...... and in the Smart Water project performed in a laboratory scale in order to evaluate the EOR processes in selected core plugs. A major step towards this evaluation is to identify the composition of the injected water that leads to increased oil recovery in reservoirs and to define changes in the petrophysical...

An Integrated Rock Typing Approach for Unraveling the Reservoir Heterogeneity of Tight Sands in the Whicher Range Field of Perth Basin, Western Australia

DEFF Research Database (Denmark)

Ilkhchi, Rahim Kadkhodaie; Rezaee, Reza; Harami, Reza Moussavi

2014-01-01

Tight gas sands in Whicher Range Field of Perth Basin show large heterogeneity in reservoir characteristics and production behavior related to depositional and diagenetic features. Diagenetic events (compaction and cementation) have severely affected the pore system. In order to investigate...... the petrophysical characteristics, reservoir sandstone facies were correlated with core porosity and permeability and their equivalent well log responses to describe hydraulic flow units and electrofacies, respectively. Thus, very tight, tight, and sub-tight sands were differentiated. To reveal the relationship...... between pore system properties and depositional and diagenetic characteristics in each sand type, reservoir rock types were extracted. The identified reservoir rock types are in fact a reflection of internal reservoir heterogeneity related to pore system properties. All reservoir rock types...

Construction of full-scale shaft seals in crystalline rock

International Nuclear Information System (INIS)

Martino, J.B.; Dixon, D.A.; Onagi, D.; Kim, C-S; Holowick, B.

2011-01-01

The Underground Research Laboratory (URL) was constructed to investigate concepts related to geological disposal of used nuclear fuel. This involved investigating the rock mass by undertaking in situ experiments using a multi disciplinary technical approach. The decision was made in 2003 to close the URL. Part of the closure process involved installing seals in the access and ventilation shafts at locations where they intersected an ancient thrust fault (Fracture Zone 2 -- FZ2). FZ2 is an active hydraulic pathway in the Lac du Bonnet batholith and this feature is the dominating structural and hydrogeological feature at the URL site. Above FZ2 the groundwater has a low salinity and is dominated by surface-related processes. With increasing depth in the batholith, surface-related effects decrease and the salinity of the groundwater increases to 90 g/L total dissolved solids. The decision to install the seals was made as part of the due diligence for the site closure to ensure that the saline groundwater located at depth down strike and below the thrust fault would not enter the closed underground openings and mix with less saline shallow groundwater. The construction of each seal involved the installation of a heavily reinforced low alkalinity concrete component keyed into the surrounding rock. The concrete supported and restrained a central clay-sand component, which was capped by an unreinforced concrete component. The clay-sand component spans the exposure of the thrust fault in each shaft. This paper describes the construction of the main shaft seal and the ventilation shaft seal. The construction of the shaft seals at the URL was part of the Nuclear Legacy Liabilities Program (NLLP) being funded by Natural Resources Canada (NRCan). (author)

Construction of full-scale shaft seals in crystalline rock

Energy Technology Data Exchange (ETDEWEB)

Martino, J.B.; Dixon, D.A.; Onagi, D.; Kim, C-S; Holowick, B. [Atomic Energy of Canada Limited, Pinawa, MB (Canada)

2011-07-01

The Underground Research Laboratory (URL) was constructed to investigate concepts related to geological disposal of used nuclear fuel. This involved investigating the rock mass by undertaking in situ experiments using a multi disciplinary technical approach. The decision was made in 2003 to close the URL. Part of the closure process involved installing seals in the access and ventilation shafts at locations where they intersected an ancient thrust fault (Fracture Zone 2 -- FZ2). FZ2 is an active hydraulic pathway in the Lac du Bonnet batholith and this feature is the dominating structural and hydrogeological feature at the URL site. Above FZ2 the groundwater has a low salinity and is dominated by surface-related processes. With increasing depth in the batholith, surface-related effects decrease and the salinity of the groundwater increases to 90 g/L total dissolved solids. The decision to install the seals was made as part of the due diligence for the site closure to ensure that the saline groundwater located at depth down strike and below the thrust fault would not enter the closed underground openings and mix with less saline shallow groundwater. The construction of each seal involved the installation of a heavily reinforced low alkalinity concrete component keyed into the surrounding rock. The concrete supported and restrained a central clay-sand component, which was capped by an unreinforced concrete component. The clay-sand component spans the exposure of the thrust fault in each shaft. This paper describes the construction of the main shaft seal and the ventilation shaft seal. The construction of the shaft seals at the URL was part of the Nuclear Legacy Liabilities Program (NLLP) being funded by Natural Resources Canada (NRCan). (author)

Source rock

Directory of Open Access Journals (Sweden)

Abubakr F. Makky

2014-03-01

Full Text Available West Beni Suef Concession is located at the western part of Beni Suef Basin which is a relatively under-explored basin and lies about 150 km south of Cairo. The major goal of this study is to evaluate the source rock by using different techniques as Rock-Eval pyrolysis, Vitrinite reflectance (%Ro, and well log data of some Cretaceous sequences including Abu Roash (E, F and G members, Kharita and Betty formations. The BasinMod 1D program is used in this study to construct the burial history and calculate the levels of thermal maturity of the Fayoum-1X well based on calibration of measured %Ro and Tmax against calculated %Ro model. The calculated Total Organic Carbon (TOC content from well log data compared with the measured TOC from the Rock-Eval pyrolysis in Fayoum-1X well is shown to match against the shale source rock but gives high values against the limestone source rock. For that, a new model is derived from well log data to calculate accurately the TOC content against the limestone source rock in the study area. The organic matter existing in Abu Roash (F member is fair to excellent and capable of generating a significant amount of hydrocarbons (oil prone produced from (mixed type I/II kerogen. The generation potential of kerogen in Abu Roash (E and G members and Betty formations is ranging from poor to fair, and generating hydrocarbons of oil and gas prone (mixed type II/III kerogen. Eventually, kerogen (type III of Kharita Formation has poor to very good generation potential and mainly produces gas. Thermal maturation of the measured %Ro, calculated %Ro model, Tmax and Production index (PI indicates that Abu Roash (F member exciting in the onset of oil generation, whereas Abu Roash (E and G members, Kharita and Betty formations entered the peak of oil generation.

Rock Slope Design Criteria

Science.gov (United States)

2010-06-01

Based on the stratigraphy and the type of slope stability problems, the flat lying, Paleozoic age, sedimentary : rocks of Ohio were divided into three design units: 1) competent rock design unit consisting of sandstones, limestones, : and siltstones ...

Experimental studies of low salinity water flooding in carbonate reservoirs: A new promising approach

DEFF Research Database (Denmark)

Zahid, Adeel; Shapiro, Alexander; Skauge, Arne

2012-01-01

Low salinity water flooding is well studied for sandstone reservoirs, both laboratory and field tests have showed improvement in the oil recovery in many cases. Up to very recently, the low salinity effect has been indeterminated for carbonates. Most recently, Saudi Aramco reported that substantial...... additional oil recovery can be achieved when successively flooding composite carbonate core plugs with various diluted versions of seawater. The experimental data on carbonates is very limited, so more data and better understanding of the mechanisms involved is needed to utilize this method for carbonate...... reservoirs. In this paper, we have experimentally investigated the oil recovery potential of low salinity water flooding for carbonate rocks. We used both reservoir carbonate and outcrop chalk core plugs. The flooding experiments were carried out initially with the seawater, and afterwards additional oil...

Rock types and ductile structures on a rock domain basis, and fracture orientation and mineralogy on a deformation zone basis. Preliminary site description. Forsmark area - version 1.2

Energy Technology Data Exchange (ETDEWEB)

Stephens, Michael [Geological Survey of Sweden, Uppsala (Sweden); Forssberg, Ola [Golder Associates AB, Uppsala (Sweden)

2006-09-15

This report presents the results of the analysis of base geological data in order to establish the dominant rock type, the subordinate rock types and the orientation of ductile mineral fabrics within each rock domain included in the regional geological model, version 1.2. An assessment of the degree of homogeneity of each domain is also provided. The analytical work has utilised the presentation of data in the form of histograms and stereographic projections. Fisher means and K values or best-fit great circles and corresponding pole values have been calculated for the ductile structural data. These values have been used in the geometric modelling of rock domains in the regional model, version 1.2. Furthermore, all analytical results have been used in the assignment of properties to rock domains in this model. A second analytical component reported here addresses the orientation and mineralogy of fractures in the deterministic deformation zones that are included in the regional geological model, version 1.2. The analytical work has once again utilised the presentation of data in the form of histograms and stereographic projections. Fisher means and K values are presented for the orientation of fracture sets in the deterministic deformation zones that have been identified with the help of new borehole data. The frequencies of occurrence of different minerals along the fractures in these deformation zones as well as the orientation of fractures in the zones, along which different minerals occur, are also presented. The results of the analyses have been used in the establishment of a conceptual structural model for the Forsmark site and in the assignment of properties to deterministic deformation zones in model version 1.2.

Effect of salt type and concentration on the growth and lipid content of Chlorella vulgaris in synthetic saline wastewater for biofuel production.

Science.gov (United States)

Church, Jared; Hwang, Jae-Hoon; Kim, Keug-Tae; McLean, Rebecca; Oh, You-Kwan; Nam, Bora; Joo, Jin Chul; Lee, Woo Hyoung

2017-11-01

Microalgae can offer several benefits for wastewater treatment with their ability to produce large amounts of lipids for biofuel production and the high economic value of harvested biomass for biogas and fertilizer. This study found that salt concentration (∼45gL -1 ) had more of an effect than salt type on metabolisms of Chlorella vulgaris for wastewater treatment and biofuel production. Salinity stress decreased the algal growth rate in wastewater by 0.003day -1 permScm -1 and slightly reduced nutrient removal rates. However, salinity stress was shown to increase total lipid content from 11.5% to 16.1% while also increasing the saturated portions of fatty acids in C. vulgaris. In addition, salinity increased the algal settling rate from 0.06 to 0.11mday -1 which could potentially reduce the cost of harvesting for algal biofuel production. Overall, C. vulgaris makes a suitable candidate for high salinity wastewater cultivation and biofuel production. Copyright © 2017 Elsevier Ltd. All rights reserved.

In situ measurement of flow characteristics of natural saline rock in loose zones for gas and saline solutions in given rock stress conditions. Final report; In-situ-Ermittlung von Stroemungskennwerten natuerlicher Salzgesteine in Auflockerungszonen gegenueber Gas und Salzloesungen unter den gegebenen Spannungsbedingungen im Gebirge. Abschlussbericht

Energy Technology Data Exchange (ETDEWEB)

Haefner, F.; Belohlavek, K.U.; Behr, A.; Foerster, S.; Pohl, A.

2001-04-01

A method and equipment were developed for measuring the extension of loose zones around worked areas in saline rock and for in situ measurement of very small permeabilities and porosities in these zones. The experiments are based on unsteady borehole logs with flowing gases or liquids with special multiple pack systems that enable measurements from 4 cm to 15 m from the cavern contour. The measurements were evaluated by a specially developed software with automatic parameter identification. Permeabilities were identified between 10{sup 14} m{sup 2} and the detection limit of 10{sup 24} m{sup 2} and effective porosities of less than 0.1% at experimental times of several minutes up to several days. The logs were made in 3 mines in Stassfurt rock salt at depths of 700 and 500 m with different geological and geomechanical boundary conditions, worked in different ways and for different periods of time (between a few days and 37 years). Some of the findings were validated by ultrasonic measurements. [German] Fuer die Ermittlung der Ausdehnung von Auflockerungszonen um bergmaennisch aufgefahrene Strecken/Hohlraeume im Salzgestein und zur In-situ-Bestimmung kleinster Permeabilitaeten und Porositaeten in diesen Bereichen wurde ein Verfahren und eine praktikable Versuchsausruestung entwickelt. Diese eignet sich auch fuer Frac-Untersuchungen. Basis der Versuchsdurchfuehrungen sind instationaere Bohrlochuntersuchungen mit Gasen oder Fluessigkeiten als Stroemungsfluid unter Einsatz spezieller Mehrfachpackersysteme. Damit sind Messungen ab 4 cm Abstand zur Hohlraumkontur bis zu 15 m moeglich. Die Versuchsauswertung erfolgt mittels einer speziell entwickelten Software mit automatischer Parameteridentifikation, die die instationaere Stroemung um die Versuchsbohrung raeumlich vollstaendig beschreibt. Permeabilitaeten wurden je nach Abstand zur Hohlraumkontur zwischen 10{sup -14} m{sup 2} und der Nachweisgrenze 10{sup -24} m{sup 2} und effektive Porositaeten bis <0,1% ermittelt, bei

Geosphere migration studies as support for the comparison of candidate sites for disposal of radioactive waste in rock-salt

International Nuclear Information System (INIS)

Glasbergen, P.; Hassanizadeh, S.M.; Noordijk, H.; Sauter, F.

1988-01-01

The Dutch research program on the geological disposal of radioactive waste was designed to supply a basis for the selection of combinations of three factors, i.e., type of rock-salt formation, site, and disposal technique, satisfying radiological standards and other criteria for final disposal. The potential sites have been grouped according to the type of rock-salt formation (e.g. bedded salt and salt domes) and two classes of depth below the surface of the ground. Values for geohydrological parameters were obtained by extrapolation of data from existing boreholes and analysis of the sedimentary environment. A three-dimensional model of groundwater flow and contaminant transport, called METROPOL, has been developed. To investigate the effect of high salinity on nuclide transport properly, a theoretical experimental study was carried out. Use of a thermodynamic approach showed that terms related to salt mass fraction have to be added to Darcy's and Fick's laws. An experimental study to investigate effects of these modifications is in progress. 8 refs.; 8 figs.; 1 table

Evaluation of Rock Bolt Support for Polish Hard Rock Mines

Science.gov (United States)

Skrzypkowski, Krzysztof

2018-03-01

The article presents different types of rock bolt support used in Polish ore mining. Individual point resin and expansion rock bolt support were characterized. The roof classes for zinc and lead and copper ore mines were presented. Furthermore, in the article laboratory tests of point resin rock bolt support in a geometric scale of 1:1 with minimal fixing length of 0.6 m were made. Static testing of point resin rock bolt support were carried out on a laboratory test facility of Department of Underground Mining which simulate mine conditions for Polish ore and hard coal mining. Laboratory tests of point resin bolts were carried out, especially for the ZGH Bolesław, zinc and lead "Olkusz - Pomorzany" mine. The primary aim of the research was to check whether at the anchoring point length of 0.6 m by means of one and a half resin cartridge, the type bolt "Olkusz - 20A" is able to overcome the load.The second purpose of the study was to obtain load - displacement characteristic with determination of the elastic and plastic range of the bolt. For the best simulation of mine conditions the station steel cylinders with an external diameter of 0.1 m and a length of 0.6 m with a core of rock from the roof of the underground excavations were used.

Soil salinization in different natural zones of intermontane depressions in Tuva

Science.gov (United States)

Chernousenko, G. I.; Kurbatskaya, S. S.

2017-11-01

Soil salinization features in semidesert, dry steppe, and chernozemic steppe zones within intermontane depressions in the central part of the Tuva Republic are discussed. Chernozems, chestnut soils, and brown desert-steppe soils of these zones are usually nonsaline. However, salinization of these zonal soils is possible in the case of the presence of salt-bearing parent materials (usually, the derivatives of Devonian deposits). In different natural zones of the intermontane depressions, salt-affected soils are mainly allocated to endorheic lake basins, where they are formed in places of discharge of mineral groundwater, and to river valleys. The composition and content of salts in the natural waters are dictated by the local hydrogeological conditions. The total content of dissolved solids in lake water varies from 1 to 370 g/L; the water is usually of the sulfate-chloride or chloride-sulfate salinity type; in some cases, soda-sulfate water is present. Soil salinity around the lakes is usually of the chloride-sulfate-sodium type; gypsum is often present in the profiles. Chloride salinization rarely predominates in this part of Tuva, because chlorides are easily leached off from the mainly coarse-textured soils. In some cases, the predominance of magnesium over sodium is observed in the composition of dissolved salts, which may be indicative of the cryogenic transformation of soil salts. Soda-saline soils are present in all the considered natural zones on minor areas. It is hardly possible to make unambiguous statements about the dominance of the particular type of salinity in the given natural zones. Zonal salinity patterns are weakly expressed in salinization of hydromorphic soils. However, a tendency for more frequent occurrence of soda-saline soils in steppe landscapes and chloride-sulfate salinization (often, with participation of gypsum) in the dry steppe and semidesert landscapes is observed.

Saline water in southeastern New Mexico

Science.gov (United States)

Hiss, W.L.; Peterson, J.B.; Ramsey, T.R.

1969-01-01

Saline waters from formations of several geologic ages are being studied in a seven-county area in southeastern New Mexico and western Texas, where more than 30,000 oil and gas tests have been drilled in the past 40 years. This area of 7,500 sq. miles, which is stratigraphically complex, includes the northern and eastern margins of the Delaware Basin between the Guadalupe and Glass Mountains. Chloride-ion concentrations in water produced from rocks of various ages and depths have been mapped in Lea County, New Mexico, using machine map-plotting techniques and trend analyses. Anomalously low chloride concentrations (1,000-3,000 mg/l) were found along the western margin of the Central Basin platform in the San Andres and Capitan Limestone Formations of Permian age. These low chloride-ion concentrations may be due to preferential circulation of ground water through the more porous and permeable rocks. Data being used in the study were obtained principally from oil companies and from related service companies. The P.B.W.D.S. (Permian Basin Well Data System) scout-record magnetic-tape file was used as a framework in all computer operations. Shallow or non-oil-field water analyses acquired from state, municipal, or federal agencies were added to these data utilizing P.B.W.D.S.-compatible reference numbers and decimal latitude-longitude coordinates. Approximately 20,000 water analyses collected from over 65 sources were coded, recorded on punch cards and stored on magnetic tape for computer operations. Extensive manual and computer error checks for duplication and accuracy were made to eliminate data errors resulting from poorly located or identified samples; non-representative or contaminated samples; mistakes in coding, reproducing or key-punching; laboratory errors; and inconsistent reporting. The original 20,000 analyses considered were reduced to 6,000 representative analyses which are being used in the saline water studies. ?? 1969.

Salinity-Dependent Contact Angle Alteration in Oil/Brine/Silicate Systems : the Critical Role of Divalent Cations

NARCIS (Netherlands)

Haagh, Martinus Everardus Johannes; Sîretanu, Igor; Duits, Michel; Mugele, Friedrich Gunther

2017-01-01

The effectiveness of water flooding oil recovery depends to an important extent on the competitive wetting of oil and water on the solid rock matrix. Here, we use macroscopic contact angle goniometry in highly idealized model systems to evaluate how brine salinity affects the balance of wetting

Measurement of diffusive properties of intact rock

Energy Technology Data Exchange (ETDEWEB)

Harvey, K B

1996-12-01

In the Postclosure Assessment of a Reference System for the Disposal of Canada`s Nuclear Fuel Waste (Goodwin et al. 1994) the disposal vault is assumed to be surrounded by a zone of intact rock, referred to as the `exclusion zone.` A sensitivity analysis of the relative effectiveness of the several engineered and natural barriers that contribute to the safety of the reference disposal system has shown that this zone of intact rock is the most effective of these barriers to the movement of radionuclides through the reference system. Peer review of the geosphere model used in the case study for the EIS (Environmental Impact Statement) of the Canadian Nuclear Fuel Waste Management Program has identified the need to quantify the properties of the intact rock surrounding the disposal vault that would control the transport of radionuclides by diffusion. The Postclosure Assessment also identified the need for appropriate values of the free water diffusion coefficient (D{sub o}) for {sup 129}1 and {sup 14}C. The measurement of rock resistivity allows the calculation of the Formation Factor for a rock This review describes the Formation Factor, diffusivity, permeability, and porosity, and how these properties might be measured or inferred for insitu rock under the conditions that apply to the intact rock surrounding a potential disposal vault. The importance of measuring the intrinsic diffusion coefficient (D{sup i}) of diffusing species under solution salinities simulating those of groundwaters is emphasised, and a method of measurement is described that is independent of the diffusing medium, and which would be appropriate for measurements made in chemically complex media such as groundwaters. (author). 95 refs., 4 tabs., 39 figs.

Measurement of diffusive properties of intact rock

International Nuclear Information System (INIS)

Harvey, K.B.

1996-12-01

In the Postclosure Assessment of a Reference System for the Disposal of Canada's Nuclear Fuel Waste (Goodwin et al. 1994) the disposal vault is assumed to be surrounded by a zone of intact rock, referred to as the 'exclusion zone.' A sensitivity analysis of the relative effectiveness of the several engineered and natural barriers that contribute to the safety of the reference disposal system has shown that this zone of intact rock is the most effective of these barriers to the movement of radionuclides through the reference system. Peer review of the geosphere model used in the case study for the EIS (Environmental Impact Statement) of the Canadian Nuclear Fuel Waste Management Program has identified the need to quantify the properties of the intact rock surrounding the disposal vault that would control the transport of radionuclides by diffusion. The Postclosure Assessment also identified the need for appropriate values of the free water diffusion coefficient (D o ) for 129 1 and 14 C. The measurement of rock resistivity allows the calculation of the Formation Factor for a rock This review describes the Formation Factor, diffusivity, permeability, and porosity, and how these properties might be measured or inferred for insitu rock under the conditions that apply to the intact rock surrounding a potential disposal vault. The importance of measuring the intrinsic diffusion coefficient (D i ) of diffusing species under solution salinities simulating those of groundwaters is emphasised, and a method of measurement is described that is independent of the diffusing medium, and which would be appropriate for measurements made in chemically complex media such as groundwaters. (author). 95 refs., 4 tabs., 39 figs

Rare earth element mobility in arc-type volcanic rocks

International Nuclear Information System (INIS)

Kuschel, E.; Smith, I.E.M.

1990-01-01

Some samples from arc-type volcanic suites collected in northern New Zealand and southeastern Papua New Guinea show rare earth element (REE) and Y abundances which are enriched relative to the those typical of their respective associations. This enrichment appears to be the result of an alteration process which selectively mobilises the REE and re-precipitates them as REE-bearing minerals in veins and interstitial patches. The alteration is on a micron scale and is not detected in routine petrographic examination. It is emphasised that the pattern of REE mobility in young, fresh rocks is important to igneous geochemists who use REE abundances to constrain petrogenetic models and may also be important because it indicates the operation of a natural REE enrichment process which could operate in the formation of economic REE deposits. 3 refs., 5 figs

The siliceous-calcareous-argillaceous rock type uranium deposit in south subzone of Western Qinling

International Nuclear Information System (INIS)

Qian Farong; Zhou Dean; Ji Hongfang

1995-11-01

The siliceous-calcareous-argillaceous rock type uranium deposit in south subzone of western Qinling is an inland found type deposit with specific mineralization and good potentiality. The mineralization distributes along definite horizons and occurs in siliceous layer and lenses of siliceous-calcareous rocks. Orebody presents in forms of stratoid, lenticular and irregular veins and controlled by factorial structures. Ore is identified as massive and sandy and each characterized by various mineral compositions and element associations. The study shows that the mineralizing materials are mainly derived from ore-bearing strata. The metallogenic environment has characteristics of middle-low temperature and supergene The metallogenesis underwent three stages: (1) Sedimentation-diagenesis of the ore-bearing strata led to preliminary concentration of uranium; (2) Polytectonic activities accompanied by underground hydrothermal process resulted in the industrial concentration of uranium; and (3) Orebody reworked by oxidation-denudation and leaching, locally has taken place secondary concentration. The deposit in origin attributes to polygenesis dominated by underground hydrothermal metallogenesis. Main metallogenic epoch happens during the periods of Late Yanshan and Himalayan. According to the geological-tectonic conditions the further prospecting direction in study area is proposed. (3 refs., 5 figs., 9 tabs.)

Critical issues in soft rocks

OpenAIRE

Milton Assis Kanji

2014-01-01

This paper discusses several efforts made to study and investigate soft rocks, as well as their physico-mechanical characteristics recognized up to now, the problems in their sampling and testing, and the possibility of its reproduction through artificially made soft rocks. The problems in utilizing current and widespread classification systems to some types of weak rocks are also discussed, as well as other problems related to them. Some examples of engineering works in soft rock or in soft ...

Rock strength under explosive loading

International Nuclear Information System (INIS)

Rimer, N.; Proffer, W.

1993-01-01

This presentation emphasizes the importance of a detailed description of the nonlinear deviatoric (strength) response of the surrounding rock in the numerical simulation of underground nuclear explosion phenomenology to the late times needed for test ban monitoring applications. We will show how numerical simulations which match ground motion measurements in volcanic tuffs and in granite use the strength values obtained from laboratory measurements on small core samples of these rocks but also require much lower strength values after the ground motion has interacted with the rock. The underlying physical mechanisms for the implied strength reduction are not yet well understood, and in fact may depend on the particular rock type. However, constitutive models for shock damage and/or effective stress have been used successfully at S-Cubed in both the Geophysics Program (primarily for DARPA) and the Containment Support Program (for DNA) to simulate late time ground motions measured at NTS in many different rock types

Effects of salinity and flooding on post-hurricane regeneration potential in coastal wetland vegetation.

Science.gov (United States)

Middleton, Beth A

2016-08-01

The nature of regeneration dynamics after hurricane flooding and salinity intrusion may play an important role in shaping coastal vegetation patterns. The regeneration potentials of coastal species, types and gradients (wetland types from seaward to landward) were studied on the Delmarva Peninsula after Hurricane Sandy using seed bank assays to examine responses to various water regimes (unflooded and flooded to 8 cm) and salinity levels (0, 1, and 5 ppt). Seed bank responses to treatments were compared using a generalized linear models approach. Species relationships to treatment and geographical variables were explored using nonmetric multidimensional scaling. Flooding and salinity treatments affected species richness even at low salinity levels (1 and 5 ppt). Maritime forest was especially intolerant of salinity intrusion so that species richness was much higher in unflooded and low salinity conditions, despite the proximity of maritime forest to saltmarsh along the coastal gradient. Other vegetation types were also affected, with potential regeneration of these species affected in various ways by flooding and salinity, suggesting relationships to post-hurricane environment and geographic position. Seed germination and subsequent seedling growth in coastal wetlands may in some cases be affected by salinity intrusion events even at low salinity levels (1 and 5 ppt). These results indicate that the potential is great for hurricanes to shift vegetation type in sensitive wetland types (e.g., maritime forest) if post-hurricane environments do not support the regeneration of extent vegetation. This article is a U.S. Government work and is in the public domain in the USA. © Botanical Society of America (outside the USA) 2016.

Rock-degrading endophytic bacteria in cacti

Science.gov (United States)

M. Esther Puente; Ching Y. Li; Yoav Bashan

2009-01-01

A plant-bacterium association of the cardon cactus (Pachycereus pringlei) and endophytic bacteria promotes establishment of seedlings and growth on igneous rocks without soil. These bacteria weather several rock types and minerals, unbind significant amounts of useful minerals for plants from the rocks, fix in vitro N2. produce...

Ore-controlling mechanism of carbonaceous-siliceous-pelitic rock type uranium deposits with down-faulted red basins in the southeast continental margin of Yangtze plate

International Nuclear Information System (INIS)

Zhang Zilong; Qi Fucheng; He Zhongbo; Li Zhixing; Wang Wenquan; Yu Jinshui

2012-01-01

One of the important ore-concentrated areas of carbonaceous-siliceous-pelitic rock type uranium deposits is the Southeast continental margin of Yangtze plate. Sedimentary-exogenously transformed type and sedimentary- hydrothermal superimposed transformed type uranium deposits are always distributed at or near the edge of down-faulted red ba sins. In this paper, the distributions of the deposits are analyzed with the relation to down-faulted red basins. The connective effect and ore-controlling mechanism are proposed of carbonaceous-siliceous-pelitic rock type uranium deposits with marginal fractures of red basins. (authors)

Coupled geochemical/hydrogeological modelling to assess the origin of salinity at the Tono area (Japan)

International Nuclear Information System (INIS)

Guimera, Jordi; Ruiz, Eduardo; Luna, Miguel; Arcos, David; Jordana, Salvador; Saegusa, Hiromitsu

2005-01-01

Numerical models are powerful tools for the characterization of groundwater flow, especially when integrating geochemical and hydrogeological data. This paper describes modeling exercises performed in the area surrounding the Mizunami Underground Research Laboratory (MIU) Construction Site in central Japan. A particular issue being investigated at the MIU Site is the presence of saline water detected at depth in certain boreholes. The main objective of this study is to develop conceptual physical models for the origin of this salinity and to test these conceptual models using numerical modeling techniques. One scenario being investigated is that the saline fluids represent residual Miocene age seawater which has been slightly altered by water-rock interactions. It is likely that during Miocene times, seawater inundated the Tono area. This hypothesis is partially supported by carbon and oxygen isotopic data of the calcite fracture filling materials. (author)

Electromagnetic exploration in high-salinity groundwater zones: case studies from volcanic and soft sedimentary sites in coastal Japan

Science.gov (United States)

Suzuki, Koichi; Kusano, Yukiko; Ochi, Ryota; Nishiyama, Nariaki; Tokunaga, Tomochika; Tanaka, Kazuhiro

2017-01-01

Estimating the spatial distribution of groundwater salinity in coastal plain regions is becoming increasingly important for site characterisation and the prediction of hydrogeological environmental conditions resulting from radioactive waste disposal and underground CO2 storage. In previous studies of the freshwater-saltwater interface, electromagnetic methods were used for sites characterised by unconsolidated deposits or Neocene soft sedimentary rocks. However, investigating the freshwater-saltwater interface in hard rock sites (e.g. igneous areas) is more complex, with the permeability of the rocks greatly influenced by fractures. In this study, we investigated the distribution of high-salinity groundwater at two volcanic rock sites and one sedimentary rock site, each characterised by different hydrogeological features. Our investigations included (1) applying the controlled source audio-frequency magnetotelluric (CSAMT) method and (2) conducting laboratory tests to measure the electrical properties of rock core samples. We interpreted the 2D resistivity sections by referring to previous data on geology and geochemistry of groundwater. At the Tokusa site, an area of inland volcanic rocks, low resistivity zones were detected along a fault running through volcanic rocks and shallow sediments. The results suggest that fluids rise through the Tokusa-Jifuku Fault to penetrate shallow sediments in a direction parallel to the river, and some fluids are diluted by rainwater. At the Oki site, a volcanic island on a continental shelf, four resistivity zones (in upward succession: low, high, low and high) were detected. The results suggest that these four zones were formed during a transgression-regression cycle caused by the last glacial period. At the Saijo site, located on a coastal plain composed of thick sediments, we observed a deep low resistivity zone, indicative of fossil seawater remnant from a transgression after the last glacial period. The current coastal

Susceptibility to saline contamination of coastal confined aquifer of the Uraba banana axis with hydrogeochemical and isotopic techniques

International Nuclear Information System (INIS)

Paredes Zuniga, Vanessa

2010-01-01

The project has covered an area of study of 8916 km 2 is located in the Northwestern part of the Department of Antioquia, Colombia. Interest area is geologically constituted by tertiary sedimentary rocks (T1 and T2) and alluvial deposits (Quaternary). Hydrogeological units, potentially better use of groundwater, have been established for the unit T2 (confined aquifer) and quaternary deposits.) The area has been of 2600 mm/year to 3600 mm/year of average rainfall. The susceptibility to saline contamination has been determined of coastal aquifer of the Uraba banana axis. Hydrochemical and geological information, geophysics, hydraulic and hydrochemical is used improving existing conceptual hydrogeological model. A hydrochemical characterization has been performed to evaluate the processes of salinity in the confined aquifer. The integration of geological information, geophysical and hydrogeological has been methodology used to validate the hydraulic characteristics of the aquifer, its geometry and operation, updating the conceptual hydrogeological model. The use of complementary tools been able to determine and identify processes that may affect natural physico-chemical characteristics of groundwater. The results have showed that salinization processes present in the coastal aquifer of Uraba Banana Axis could be linked to water-rock interaction, to mixtures with water have become saline as a result of transgression - regression processes in the former study. The hydrogeochemical techniques have become a complementary tool to the hydrogeology allowing respond the questions were presented in complex systems, such as the case of coastal aquifers, where sanitation is usually associated with saline intrusion processes and can also be obeying the conjunction with other hydroclimatological and hydrodynamic aspects. (author) [es

A site scale analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1997-10-01

The objective of the study is to develop, calibrate and apply a numerical simulation model of the Aespoe area. An area of 1.8 x 1.8 km 2 , centred around the Aespoe Hard Rock Laboratory (HRL), gives the horizontal extent of the model. In the vertical direction the model follows the topography at the upper boundary and has a lower boundary at 1000 metres below sea level. The model is based on a mathematical model that includes equations for the Darcy velocities, mass conservation and salinity distribution. Gravitational effects are thus fully accounted for. A regional groundwater model was used to generate boundary conditions for vertical and bottom boundaries. Transmissivities of fracture zones and conductivities for the rock in between, as used in the model, are based on field data. An extensive calibration of the model is carried out, using data for natural conditions (i.e. prior to the construction of the Aespoe HRL), drawdowns from a pump test and data collected during the excavation of the tunnel. A satisfactory agreement with field data is obtained by the calibration. Main results from the model include vertical and horizontal sections of flow, salinity and hydraulic head distributions for natural conditions and for completed tunnel. A sensitivity study, where boundary conditions and material properties are modified, is also carried out. The model is also used to describe some characteristic features of the site like infiltration rates, flux statistics at a depth of 450 metres, salinity of inflows to the tunnel and flow and salinity distributions in fracture zones. The general conclusion of the study is that the model developed can simulate the conditions at Aespoe, both natural and with Aespoe HRL present, in a realistic manner

Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

Energy Technology Data Exchange (ETDEWEB)

Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

2003-11-15

The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

Evaluation of Five Sedimentary Rocks Other Than Salt for Geologic Repository Siting Purposes

International Nuclear Information System (INIS)

Croff, A.G.; Lomenick, T.F.; Lowrie, R.S.; Stow, S.H.

2003-01-01

The US Department of Energy (DOE), in order to increase the diversity of rock types under consideration by the geologic disposal program, initiated the Sedimary ROck Program (SERP), whose immediate objectiv eis to evaluate five types of secimdnary rock - sandstone, chalk, carbonate rocks (limestone and dolostone), anhydrock, and shale - to determine the potential for siting a geologic repository. The evaluation of these five rock types, together with the ongoing salt studies, effectively results in the consideration of all types of relatively impermeable sedimentary rock for repository purposes. The results of this evaluation are expressed in terms of a ranking of the five rock types with respect to their potential to serve as a geologic repository host rock. This comparative evaluation was conducted on a non-site-specific basis, by use of generic information together with rock evaluation criteria (RECs) derived from the DOE siting guidelines for geologic repositories (CFR 1984). An information base relevant to rock evaluation using these RECs was developed in hydrology, geochemistry, rock characteristics (rock occurrences, thermal response, rock mechanics), natural resources, and rock dissolution. Evaluation against postclosure and preclosure RECs yielded a ranking of the five subject rocks with respect to their potential as repository host rocks. Shale was determined to be the most preferred of the five rock types, with sandstone a distant second, the carbonate rocks and anhydrock a more distant third, and chalk a relatively close fourth.

The Practical Application of Aqueous Geochemistry in Mapping Groundwater Flow Systems in Fractured Rock Masses

Science.gov (United States)

Bursey, G.; Seok, E.; Gale, J. E.

2017-12-01

Flow to underground mines and open pits takes place through an interconnected network of regular joints/fractures and intermediate to large scale structural features such as faults and fracture zones. Large scale features can serve either as high permeability pathways or as barriers to flow, depending on the internal characteristics of the structure. Predicting long term water quality in barrier-well systems and long-term mine water inflows over a mine life, as a mine expands, requires the use of a 3D numerical flow and transport code. The code is used to integrate the physical geometry of the fractured-rock mass with porosity, permeability, hydraulic heads, storativity and recharge data and construct a model of the flow system. Once that model has been calibrated using hydraulic head and permeability/inflow data, aqueous geochemical and isotopic data provide useful tools for validating flow-system properties, when one is able to recognize and account for the non-ideal or imperfect aspects of the sampling methods used in different mining environments. If groundwater samples are collected from discrete depths within open boreholes, water in those boreholes have the opportunity to move up or down in response to the forces that drive groundwater flow, whether they be hydraulic gradients, gas pressures, or density differences associated with variations in salinity. The use of Br/Cl ratios, for example, can be used to determine if there is active flow into, or out of, the boreholes through open discontinuities in the rock mass (i.e., short-circuiting). Natural groundwater quality can also be affected to varying degrees by mixing with drilling fluids. The combined use of inorganic chemistry and stable isotopes can be used effectively to identify dilution signals and map the dilution patterns through a range of fresh, brackish and saline water types. The stable isotopes of oxygen and hydrogen are nearly ideal natural tracers of water, but situations occur when deep

Proceedings of the Fourteenth International Symposium on Water-Rock Interaction

Energy Technology Data Exchange (ETDEWEB)

Hellmann, Roland [Institute for Earth Sciences - ISTerre, CNRS UMR 5275 Grenoble (France); Pitsch, Helmut [IRSN, DSDP, SPIIC, BP17, 92262 Fontenay-aux-Roses Cedex (France)

2013-07-01

The 14. edition of the International Symposium on Water-Rock Interaction was held from 9-14 June 2013 in the Palais des Papes in the historic city of Avignon, located in southeastern France. As is the tradition with WRI symposia, earth scientists and guests from around the world convened over a week's time to exchange the latest ideas, advances, and data covering some of the most important aspects of rock-water interactions. The research that was presented in both oral and poster format covered studies derived from experimental and laboratory work, modeling and theoretical approaches, and field measurements. The presentations at the symposium showed the immense range of conditions associated with natural, experimental, and theoretical rock-water systems, encompassing a wide range of pH, as well as temperature and pressure conditions ranging from ambient to beyond the critical point of water. In addition, as can be evidenced from the presentations, many water-rock systems are increasingly being described in terms of control by both abiotic and biogeochemical processes. Advances in fundamental WRI research are also making significant contributions to better understanding current environmental problems, which are quite often highlighted in today's media headlines. Reflecting the importance of these environmental and societal challenges, an important number of presentations in this symposium described the current state of the knowledge concerning acid mine drainage, geological CO{sub 2} sequestration, shale gas extraction, aquifer salinization and diminishing potable water resources, and nuclear waste storage. Some 260 manuscripts were submitted to WRI-14 by scientists from 37 countries. Each manuscript was peer reviewed for scientific content by two reviewers. In the end, 230 manuscripts were accepted for either oral or poster presentation at the symposium. Each one of these papers can be found in this special symposium volume. The WRI-14 symposium has been

Proceedings of the Fourteenth International Symposium on Water-Rock Interaction

International Nuclear Information System (INIS)

Hellmann, Roland; Pitsch, Helmut

2013-01-01

The 14. edition of the International Symposium on Water-Rock Interaction was held from 9-14 June 2013 in the Palais des Papes in the historic city of Avignon, located in southeastern France. As is the tradition with WRI symposia, earth scientists and guests from around the world convened over a week's time to exchange the latest ideas, advances, and data covering some of the most important aspects of rock-water interactions. The research that was presented in both oral and poster format covered studies derived from experimental and laboratory work, modeling and theoretical approaches, and field measurements. The presentations at the symposium showed the immense range of conditions associated with natural, experimental, and theoretical rock-water systems, encompassing a wide range of pH, as well as temperature and pressure conditions ranging from ambient to beyond the critical point of water. In addition, as can be evidenced from the presentations, many water-rock systems are increasingly being described in terms of control by both abiotic and biogeochemical processes. Advances in fundamental WRI research are also making significant contributions to better understanding current environmental problems, which are quite often highlighted in today's media headlines. Reflecting the importance of these environmental and societal challenges, an important number of presentations in this symposium described the current state of the knowledge concerning acid mine drainage, geological CO 2 sequestration, shale gas extraction, aquifer salinization and diminishing potable water resources, and nuclear waste storage. Some 260 manuscripts were submitted to WRI-14 by scientists from 37 countries. Each manuscript was peer reviewed for scientific content by two reviewers. In the end, 230 manuscripts were accepted for either oral or poster presentation at the symposium. Each one of these papers can be found in this special symposium volume. The WRI-14 symposium has been

ROCK1 and ROCK2 are Required for Non-Small Cell Lung Cancer Anchorage-Independent Growth and Invasion

OpenAIRE

Vigil, Dominico; Kim, Tai Young; Plachco, Ana; Garton, Andrew J.; Castaldo, Linda; Pachter, Jonathan A.; Dong, Hanqing; Chen, Xin; Tokar, Brianna; Campbell, Sharon L.; Der, Channing J.

2012-01-01

Evidence is emerging that the closely related ROCK1 and ROCK2 serine/threonine kinases support the invasive and metastatic growth of a spectrum of human cancer types. Therefore, inhibitors of ROCK are under preclinical development. However, a key step in their development involves the identification of genetic biomarkers that will predict ROCK inhibitor anti-tumor activity. One identified mechanism for ROCK activation in cancer involves the loss of function of the DLC1 tumor suppressor gene, ...

Geochemical modelling of grout-groundwater-rock interactions at the seal-rock interface

International Nuclear Information System (INIS)

Alcorn, S.; Christian-Frear, T.

1992-02-01

Theoretical investigations into the longevity of repository seals have dealt primarily with the development of a methodology to evaluate interactions between portland cement-based grout and groundwater. Evaluation of chemical thermodynamic equilibria among grout, groundwater, and granitic host rock phases using the geochemical codes EQ3NR/EQ6 suggests that a fracture filled with grout and saturated with groundwater will tend to fill and 'tighten' with time. These calculations predict that some grout and rock phases will dissolve, and that there will be precipitation of secondary phases which collectively have a larger overall volume than that of the material dissolved. Model assumptions include sealing of the fracture in a sluggish hydrologic regime (low gradient) characterized by a saline groundwater environment. The results of the calculations suggest that buffering of the fracture seals chemical system by the granitic rock may be important in determining the long-term fate of grout seals and the resulting phase assemblage in the fracture. The similarity of the predicted reaction product phases to those observed in naturally filled fractures suggests that with time equilibrium will be approached and grouted fractures subject to low hydrologic gradients will continue to seal. If grout injected into fractures materially reduces groundwater flux, the approach to chemical equilibrium will likely be accelerated. In light of this, even very thin or imperfectly grouted fractures would tighten in suitable hydrogeologic environments. In order to determine the period of time necessary to approach equilibrium, data on reaction rates are required. (au)

Bulk and Surface Aqueous Speciation of Calcite: Implications for Low-Salinity Waterflooding of Carbonate Reservoirs

KAUST Repository

Yutkin, Maxim P.

2017-08-25

Low-salinity waterflooding (LSW) is ineffective when reservoir rock is strongly water-wet or when crude oil is not asphaltenic. Success of LSW relies heavily on the ability of injected brine to alter surface chemistry of reservoir crude-oil brine/rock (COBR) interfaces. Implementation of LSW in carbonate reservoirs is especially challenging because of high reservoir-brine salinity and, more importantly, because of high reactivity of the rock minerals. Both features complicate understanding of the COBR surface chemistries pertinent to successful LSW. Here, we tackle the complex physicochemical processes in chemically active carbonates flooded with diluted brine that is saturated with atmospheric carbon dioxide (CO2) and possibly supplemented with additional ionic species, such as sulfates or phosphates. When waterflooding carbonate reservoirs, rock equilibrates with the injected brine over short distances. Injected-brine ion speciation is shifted substantially in the presence of reactive carbonate rock. Our new calculations demonstrate that rock-equilibrated aqueous pH is slightly alkaline quite independent of injected-brine pH. We establish, for the first time, that CO2 content of a carbonate reservoir, originating from CO2-rich crude oil and gas, plays a dominant role in setting aqueous pH and rock-surface speciation. A simple ion-complexing model predicts the calcite-surface charge as a function of composition of reservoir brine. The surface charge of calcite may be positive or negative, depending on speciation of reservoir brine in contact with the calcite. There is no single point of zero charge; all dissolved aqueous species are charge determining. Rock-equilibrated aqueous composition controls the calcite-surface ion-exchange behavior, not the injected-brine composition. At high ionic strength, the electrical double layer collapses and is no longer diffuse. All surface charges are located directly in the inner and outer Helmholtz planes. Our evaluation of

Regulation of ROCK Activity in Cancer

DEFF Research Database (Denmark)

Morgan-Fisher, Marie; Wewer, Ulla M; Yoneda, Atsuko

2013-01-01

, these findings demonstrate additional modes to regulate ROCK activity. This review describes the molecular mechanisms of ROCK activity regulation in cancer, with emphasis on ROCK isoform-specific regulation and interaction partners, and discusses the potential of ROCKs as therapeutic targets in cancer.......Cancer-associated changes in cellular behavior, such as modified cell-cell contact, increased migratory potential, and generation of cellular force, all require alteration of the cytoskeleton. Two homologous mammalian serine/threonine kinases, Rho-associated protein kinases (ROCK I and II), are key...... regulators of the actin cytoskeleton acting downstream of the small GTPase Rho. ROCK is associated with cancer progression, and ROCK protein expression is elevated in several types of cancer. ROCKs exist in a closed, inactive conformation under quiescent conditions, which is changed to an open, active...

The Usability of Rock-Like Materials for Numerical Studies on Rocks

Science.gov (United States)

Zengin, Enes; Abiddin Erguler, Zeynal

2017-04-01

artificial simulations. The results obtained from these laboratory tests and modelling studies were compared with the other researcher's studies in respect to failure mechanism of different type of rocks. It can be concluded that there is similar failure mechanism between concrete and rock materials. Therefore, the results obtained from concrete samples that would be prepared at different porosity and pore sizes can be used in future studies in selection micro-mechanical and physical properties to constitute synthetic rock materials for understanding failure mechanism of rocks having complex inherent structures such as vuggy rocks or heavily jointed rock masses.

Genetic aspects of barite mineralization related to rocks of the teschenite association in the Silesian Unit, Outer Western Carpathians, Czech Republic

Directory of Open Access Journals (Sweden)

Jirásek Jakub

2017-04-01

Full Text Available Barite is a relatively uncommon phase in vein and amygdule mineralizations hosted by igneous rocks of the teschenite association in the Silesian Unit (Western Carpathians. In macroscopically observable sizes, it has been reported from 10 sites situated only in the Czech part of the Silesian Unit. Microscopic barite produced by the hydrothermal alteration of rock matrix and also by the supergene processes is more abundant. We examined four samples of barite by mineralogical and geochemical methods. Electron microprobe analyses proved pure barites with up to 0.038 apfu Sr and without remarkable internal zonation. Fluid inclusion and sulphur isotope data suggests that multiple sources of fluid components have been involved during barite crystallization. Barite contains primary and secondary aqueous all-liquid (L or less frequent two-phase (L+V aqueous fluid inclusions with variable salinity (0.4-2.9 wt. % NaCl eq. and homogenization temperatures between 77 and 152 °C. The higher-salinity fluid endmember was probably Cretaceous seawater and the lower-salinity one was probably diagenetic water derived from surrounding flysch sediments during compaction and thermal alteration of clay minerals. The δ34S values of barite samples range between -1.0 ‰ and +16.4 ‰ CDT suggesting participation of two sources of sulphate, one with a near-zero δ34S values probably derived from wall rocks and another with high δ34S values being most probably sulphate from the Cretaceous seawater. All results underline the role of externally derived fluids during post-magmatic alteration of bodies of rock of the teschenite association.

Original geochemical types and epigenetic alteration of rocks in prospecting target stratum for uranium deposit in the southeast of Songliao basin

International Nuclear Information System (INIS)

Lin Jinrong; Tian Hua; Dong Wenming; Xia Yuliang; Qi Daneng; Yao Shancong; Zheng Jiwei

2009-01-01

By comprehensive analysis on informations of regional geology and evaluating drillhole works of uranium resources in the southeast of Songliao basin, lithofacies-palaeogeography features, lithologies and sandbody characteristics of target layes in Quantou formation, Yaojia formation and Sifangtai formation have been basically found out. By research on geochemical environment of rocks in target layez, types of original geochemistry and epigenetic alteration have been identified and classified. The types of original geochemistry have been divided into types of original oxidation and original reduction, and the types of epigenetic alteration have been divided into types of reduction by oil-gas and coalbed gas and epigenetic oxidation. By comparative study on mineral and chemical characteristics of original geochemistry and epigenetic oxidation, identification marks for oil-gas and coalbed gas reduced epigenetic oxidation have been proposed. It is proposed that uranium was strongly pre-concentrated in original sandstone that bearing carboniferous matter, and reduction by oil-gas and coalbed gas made uranium superimpose and concentrate in alterated rocks. (authors)

Remote Sensing of Rock Type in the Visible and Near-Infrared,

Science.gov (United States)

Visible and near-infrared spectra of minerals and rocks have been measured and evaluated in terms of remote sensing applications. The authors...difficult or impossible to use in a generalized remote sensing effort in which the composition of all rocks is to be mapped. Instead, this spectral

Vapour loss (``boiling'') as a mechanism for fluid evolution in metamorphic rocks

Science.gov (United States)

Trommsdorff, Volkmar; Skippen, George

1986-11-01

The calculation of fluid evolution paths during reaction progress is considered for multicomponent systems and the results applied to the ternary system, CO2-H2O-NaCl. Fluid evolution paths are considered for systems in which a CO2-rich phase of lesser density (vapour) is preferentially removed from the system leaving behind a saline aqueous phase (liquid). Such “boiling” leads to enrichment of the residual aqueous phase in dissolved components and, for certain reaction stoichiometries, to eventual saturation of the fluids in salt components. Distinctive textures, particularly radiating growths of prismatic minerals such as tremolite or diopside, are associated with saline fluid inclusions and solid syngenetic salt inclusions at a number of field localities. The most thoroughly studied of these localities is Campolungo, Switzerland, where metasomatic rocks have developed in association with fractures and veins at 500° C and 2,000 bars of pressure. The petrography of these rocks suggests that fluid phase separation into liquid and vapour has been an important process during metasomatism. Fracture systems with fluids at pressure less than lithostatic may facilitate the loss of the less dense vapour phase to conditions of the amphibolite facies.

Mass Dependent Fractionation of Hg Isotopes in Source Rocks, Mineral Deposits and Spring Waters of the California Coast Ranges, USA

Science.gov (United States)

Smith, C. N.; Kesler, S. E.; Blum, J. D.; Rytuba, J. J.

2007-12-01

We present here the first study of the isotopic composition of Hg in rocks, ore deposits, and active hydrothermal systems from the California Coast Ranges, one of Earth's largest Hg-depositing systems. The Franciscan Complex and Great Valley Sequence, which form the bedrock in the California Coast Ranges, are intruded and overlain by Tertiary volcanic rocks including the Clear Lake Volcanic Sequence. These rocks contain two types of Hg deposits, hot-spring deposits that form at shallow depths (<300 m) and silica-carbonate deposits that extend to greater depths (200 to 1000 m), as well as active springs and geothermal systems that release Hg to the present surface. The Franciscan Complex and Great Valley Sequence contain clastic sedimentary rocks with higher concentrations of Hg than volcanic rocks of the Clear Lake Volcanic Field. Mean Hg isotope compositions for all three rock units are similar, although the range of values in Franciscan Complex rocks is greater than in either Great Valley or Clear Lake rocks. Hot spring and silica-carbonate Hg deposits have similar average isotopic compositions that are indistinguishable from averages for the three rock units, although δ202Hg values for the Hg deposits have a greater variance than the country rocks. Precipitates from dilute spring and saline thermal waters in the area have similarly large variance and a mean δ202Hg value that is significantly lower than the ore deposits and rocks. These observations indicate there is little or no isotopic fractionation during release of Hg from its source rocks into hydrothermal solutions. Isotopic fractionation does appear to take place during transport and concentration of Hg in deposits, especially in their uppermost parts. Boiling of hydrothermal fluids is likely the most important process causing of the observed Hg isotope fractionation. This should result in the release of Hg with low δ202Hg values into the atmosphere from the top of these hydrothermal systems and a

Radioactivities (dose rates) of rocks in Japan

International Nuclear Information System (INIS)

Matsuda, Hideharu; Minato, Susumu

1995-01-01

The radioactive distribution (radiation doses) of major rocks in Japan was monitored to clarify the factors influencing terrestrial gamma-ray absorbed dose rates. The rock samples were reduced to powder and analyzed by well-type NaI(Tl) scintillation detector and pulse height analyzer. Terrestrial gamma-ray dose rates were estimated in terms of gamma radiation dose rate 1 m above the ground. The radioactivity concentration was highest in acidic rock which contains much SiO 2 among igneous rock, followed by neutral rock, basic rock, and ultrabasic rock. The radioactive concentration was 30-40% lower in acidic and clastic rocks than those of the world average concentration. Higher radioactive concentration was observed in soils than the parent rocks of sedimentary rock and metamorphic rock. The gamma radiation dose rate was in proportion to the radioactive concentration of the rocks. To clarify the radioactive effect in the change course of rocks into soils, comparative measurement of outcrop and soil radioactive concentrations is important. (S.Y.)

Experimental investigation of CO2-brine-rock interactions at elevated temperature and pressure: Implications for CO2 sequestration in deep-saline aquifers

Science.gov (United States)

Rosenbauer, R.J.; Koksalan, T.; Palandri, J.L.

2005-01-01

Deep-saline aquifers are potential repositories for excess CO2, currently being emitted to the atmosphere from anthropogenic activities, but the reactivity of supercritical CO2 with host aquifer fluids and formation minerals needs to be understood. Experiments reacting supercritical CO2 with natural and synthetic brines in the presence and absence of limestone and plagioclase-rich arkosic sandstone showed that the reaction of CO2-saturated brine with limestone results in compositional, mineralogical, and porosity changes in the aquifer fluid and rock that are dependent on initial brine composition, especially dissolved calcium and sulfate. Experiments reacting CO2-saturated, low-sulfate brine with limestone dissolved 10% of the original calcite and increased rock porosity by 2.6%. Experiments reacting high-sulfate brine with limestone, both in the presence and absence of supercritical CO2, were characterized by the precipitation of anhydrite, dolomitization of the limestone, and a final decrease in porosity of 4.5%. However, based on favorable initial porosity changes of about 15% due to the dissolution of calcite, the combination of CO2 co-injection with other mitigation strategies might help alleviate some of the well-bore scale and formation-plugging problems near the injection zone of a brine disposal well in Paradox Valley, Colorado, as well as provide a repository for CO2. Experiments showed that the solubility of CO2 is enhanced in brine in the presence of limestone by 9% at 25 ??C and 6% at 120 ??C and 200 bar relative to the brine itself. The solubility of CO2 is enhanced also in brine in the presence of arkosic sandstone by 5% at 120 ??C and 300 bar. The storage of CO 2 in limestone aquifers is limited to only ionic and hydraulic trapping. However, brine reacted with supercritical CO2 and arkose yielded fixation and sequestration of CO2 in carbonate mineral phases. Brine desiccation was observed in all experiments containing a discrete CO2 phase

Management of human-induced salinization in the Berg River catchment (South Africa)

CSIR Research Space (South Africa)

Jovanovic, Nebojsa

2010-09-01

Full Text Available Impacts on Salinity in Western Cape Waters. Water Research Commission Report No. K5/1503, Pretoria, South Africa. In press. Figure 1: Location and 20 m Digital Elevation Model of the Berg River basin. The red square indicates the approximate position..., and German Federal Ministry for Education and Research (BMBF) for funding, SA Rock Drill, Caren Jarmain (University of KwaZulu Natal), University of the Western Cape, farmers, United States Geological Survey Historic land uses: ?Pre-1700 savanna, nomadic...

Rock properties influencing impedance spectra (IS) studied by lab measurements on porous model systems

Energy Technology Data Exchange (ETDEWEB)

Volkmann, J.; Klitzsch, N.; Mohnke, O. [RWTH Aachen Univ. (Germany). Applied Geophysics and Geothermal Energy; Schleifer, N. [Wintershall Holding GmbH, Barnstorf (Germany)

2013-08-01

The wetting condition of reservoir rocks is a crucial parameter for the estimation of reservoir characteristics like permeability and saturation with residual oil or water. Since standard methods are often costly, at least in terms of time, we aim at assessing wettability of reservoir rocks using impedance spectroscopy (IS), a frequency dependent measurement of complex electric resistivity. This approach is promising, because IS is sensitive to the electrochemical properties of the inner surface of rocks which, on the other hand, are decisively influencing wettability. Unfortunately, there is large number of rock parameters - besides wettability - influencing the impedance spectra often not exactly known for natural rock samples. Therefore, we study model systems to improve the understanding of the underlying mechanisms and to quantify the influencing parameters. The model systems consist of sintered porous silica beads of different sizes leading to samples with different pore sizes. The main advantage of these samples compared to natural rocks is their well-defined and uniform mineralogical composition and thus their uniform electrochemical surface property. In order to distinguish pore geometry and fluid electrochemistry effects on the IS properties we measured the IS response of the fully water saturated model systems in a wide frequency range - from 1 mHz to 35 MHz - to capture different often overlapping polarization processes. With these measurements we study the influence of pore or grain size, fluid conductivity, and wettability (contact angle) on the impedance spectra. The influence of wettability was studied by modifying the originally hydrophilic inner surface into a hydrophobic state. The wettability change was verified by contact angle measurements. As results, we find pore size dependent relaxation times and salinity dependent chargeabilities for the hydrophilic samples in the low frequency range (< 10 kHz), whereas for the hydrophobic samples

Remote Sensing Soil Salinity Map for the San Joaquin Vally, California

Science.gov (United States)

Scudiero, E.; Skaggs, T. H.; Anderson, R. G.; Corwin, D. L.

2015-12-01

Soil salinization is a major natural hazard to worldwide agriculture. We present a remote imagery approach that maps salinity within a range (i.e., salinities less than 20 dS m-1, when measured as the electrical conductivity of the soil saturation extract), accuracy, and resolution most relevant to agriculture. A case study is presented for the western San Joaquin Valley (WSJV), California, USA (~870,000 ha of farmland) using multi-year Landsat 7 ETM+ canopy reflectance and the Canopy Response Salinity Index (CRSI). Highly detailed salinity maps for 22 fields (542 ha) established from apparent soil electrical conductivity directed sampling were used as ground-truth (sampled in 2013), totaling over 5000 pixels (30×30 m) with salinity values in the range of 0 to 35.2 dS m-1. Multi-year maximum values of CRSI were used to model soil salinity. In addition, soil type, elevation, meteorological data, and crop type were evaluated as covariates. The fitted model (R2=0.73) was validated: i) with a spatial k-folds (i.e., leave-one-field-out) cross-validation (R2=0.61), ii) versus salinity data from three independent fields (sampled in 2013 and 2014), and iii) by determining the accuracy of the qualitative classification of white crusted land as extremely-saline soils. The effect of land use change is evaluated over 2396 ha in the Broadview Water District from a comparison of salinity mapped in 1991 with salinity predicted in 2013 from the fitted model. From 1991 to 2013 salinity increased significantly over the selected study site, bringing attention to potential negative effects on soil quality of shifting from irrigated agriculture to fallow-land. This is cause for concern since over the 3 years of California's drought (2010-2013) the fallow land in the WSJV increased from 12.7% to 21.6%, due to drastic reduction in water allocations to farmers.

Thermo-hydro-chemical performance assessment of CO2 storage in saline aquifer

International Nuclear Information System (INIS)

Le Gallo, Y.; Trenty, L.; Michel, A.

2007-01-01

Research and development methodologies for the storage of CO 2 in geological formation are in developing over the last 10 years. In this context, numerical simulators are the practical tools to understand the physical processes involved by acid gas injection and evaluate the long term stability of the storage. CO 2 storage models can be seen as a mix between two types of models: a reservoir model coupling multiphase flow in porous media with local phase equilibrium and a hydrogeochemical model coupling transport in aqueous phase with local chemical equilibrium and kinetic reaction laws. A 3D-multiphase model, COORES, was built to assess the influence of different driving forces both hydrodynamic and geomechanics as well as geochemical on the CO 2 plume behavior during injection and storage (1000 years). Different coupling strategies were used to model these phenomena: - pressure, temperature and diffusion are solved implicitly for better numerical stability; - geochemical reactions involve heterogeneous kinetically-controlled reactions between the host rock and the CO 2 -rich aqueous phase which imply an implicit coupling with fluid flow; From the assumed initial mineral composition (6 minerals), aqueous species (10 chemical elements and 37 aqueous species), the geochemical alteration of the host rocks (sand and shale) is directly linked with the CO 2 plume evolution. A performance assessment using an experimental design approach is used to quantify the different driving forces and parameter influences. In the case of CO 2 injection in a saline quartz rich aquifer used to illustrate the model capabilities, the geochemical changes of the host rock have a small influence on the CO 2 distribution at the end of storage life (here 1000 years) compared to the other hydrodynamic mechanisms: free CO 2 (gas or supercritical), or trapped (capillary and in-solution). (authors)

Do laboratory salinity tolerances of freshwater animals correspond with their field salinity?

Energy Technology Data Exchange (ETDEWEB)

Kefford, Ben J.; Papas, Phil J.; Metzeling, Leon; Nugegoda, Dayanthi

2004-06-01

The degree to which laboratory derived measures of salinity tolerance reflect the field distributions of freshwater biota is uncertain. In this paper we compare laboratory-derived acute salinity tolerance (LC{sub 50} values) of freshwater macroinvertebrates (range 5.5-76 mS/cm) and fish (range 2.7-82 mS/cm) from southeastern Australia with the salinity from which they have been collected in the field. Only 4% of the macroinvertebrates were collected at salinity levels substantially higher than their 72-h LC{sub 50} obtained from directly transferring animals from low salinity water to the water they were tested (direct transfer LC{sub 50}). This LC{sub 50} value was correlated with the maximum salinity at which a species had been collected. For common macroinvertebrates, the maximum field salinity was approximated by the direct transfer 72-h LC{sub 50}. For adult freshwater fish, 21% of species were collected at salinities substantially greater than their acute direct transfer LC{sub 50} and there was a weak relationship between these two variables. Although there was a weak correlation between the direct transfer LC{sub 50} of early life stages of freshwater fish and the maximum field salinity, 58% of the field distribution were in higher than their LC{sub 50} values. In contrast, LC{sub 50} determined from experiments that acclimated adult fish to higher salinity (slow acclimation) provided a better indication of the field distribution: with only one fish species (7%) being in conflict with their maximum field salinity and a strong positive relationship between these variables. This study shows that laboratory measures of acute salinity tolerance can reflect the maximum salinity that macroinvertebrate and fish species inhabit and are consistent with some anecdotal observations from other studies. - Acute laboratory salinity tolerances relate to maximum salinity where organisms occur in nature.

Do laboratory salinity tolerances of freshwater animals correspond with their field salinity?

International Nuclear Information System (INIS)

Kefford, Ben J.; Papas, Phil J.; Metzeling, Leon; Nugegoda, Dayanthi

2004-01-01

The degree to which laboratory derived measures of salinity tolerance reflect the field distributions of freshwater biota is uncertain. In this paper we compare laboratory-derived acute salinity tolerance (LC 50 values) of freshwater macroinvertebrates (range 5.5-76 mS/cm) and fish (range 2.7-82 mS/cm) from southeastern Australia with the salinity from which they have been collected in the field. Only 4% of the macroinvertebrates were collected at salinity levels substantially higher than their 72-h LC 50 obtained from directly transferring animals from low salinity water to the water they were tested (direct transfer LC 50 ). This LC 50 value was correlated with the maximum salinity at which a species had been collected. For common macroinvertebrates, the maximum field salinity was approximated by the direct transfer 72-h LC 50 . For adult freshwater fish, 21% of species were collected at salinities substantially greater than their acute direct transfer LC 50 and there was a weak relationship between these two variables. Although there was a weak correlation between the direct transfer LC 50 of early life stages of freshwater fish and the maximum field salinity, 58% of the field distribution were in higher than their LC 50 values. In contrast, LC 50 determined from experiments that acclimated adult fish to higher salinity (slow acclimation) provided a better indication of the field distribution: with only one fish species (7%) being in conflict with their maximum field salinity and a strong positive relationship between these variables. This study shows that laboratory measures of acute salinity tolerance can reflect the maximum salinity that macroinvertebrate and fish species inhabit and are consistent with some anecdotal observations from other studies. - Acute laboratory salinity tolerances relate to maximum salinity where organisms occur in nature

Professional users handbook for rock bolting

Energy Technology Data Exchange (ETDEWEB)

Stillborg, B.

1986-01-01

The paper is a practical handbook which reviews the basic principles of rock bolting and sets out the design considerations used for most types of rockbolts in current use. It discusses the characteristics of these bolts and gives information on installation procedures and the observations and measurement of rockbolt performance. Rockbolting is considered under the following chapter headings: review of typical rockbolt systems; rockbolt installation; testing of rockbolts; design considerations; design of rock reinforcement; monitoring; cost of rock bolting; and Atlas Lopco auxillary equipment for rock bolting. 45 refs.

Origin of salinity in produced waters from the Palm Valley gas field, Northern Territory, Australia

International Nuclear Information System (INIS)

Andrew, Anita S.; Whitford, David J.; Berry, Martin D.; Barclay, Stuart A.; Giblin, Angela M.

2005-01-01

The chemical composition and evolution of produced waters associated with gas production in the Palm Valley gas field, Northern Territory, has important implications for issues such as gas reserve calculations, reservoir management and saline water disposal. The occurrence of saline formation water in the Palm Valley field has been the subject of considerable debate. There were no occurrences of mobile water early in the development of the field and only after gas production had reduced the reservoir pressure, was saline formation water produced. Initially this was in small quantities but has increased dramatically with time, particularly after the initiation of compression in November 1996. The produced waters range from highly saline (up to 300,000 mg/L TDS), with unusual enrichments in Ca, Ba and Sr, to low salinity fluids that may represent condensate waters. The Sr isotopic compositions of the waters ( 87 Sr/ 86 Sr = 0.7041-0.7172) are also variable but do not correlate closely with major and trace element abundances. Although the extreme salinity suggests possible involvement of evaporite deposits lower in the stratigraphic sequence, the Sr isotopic composition of the high salinity waters suggests a more complex evolutionary history. The formation waters are chemically and isotopically heterogeneous and are not well mixed. The high salinity brines have Sr isotopic compositions and other geochemical characteristics more consistent with long-term residence within the reservoir rocks than with present-day derivation from a more distal pool of brines associated with evaporites. If the high salinity brines entered the reservoir during the Devonian uplift and were displaced by the reservoir gas into a stagnant pool, which has remained near the reservoir for the last 300-400 Ma, then the size of the brine pool is limited. At a minimum, it might be equivalent to the volume displaced by the reservoired gas

Rock-colonizing plants: abundance of the endemic cactus Mammillaria fraileana related to rock type in the southern Sonoran Desert

Science.gov (United States)

Blanca R. Lopez; Yoav Bashan; Macario Bacilio; Gustavo. De la Cruz-Aguero

2009-01-01

Establishment, colonization, and permanence of plants affect biogenic and physical processes leading to development of soil. Rockiness, temperature, and humidity are accepted explanations to the influence and the presence of rock-dwelling plants, but the relationship between mineral and chemical composition of rocks with plant abundance is unknown in some regions. This...

Anisotropy effect on strengths of metamorphic rocks

Directory of Open Access Journals (Sweden)

Ahmet Özbek

2018-02-01

Full Text Available This paper aims to study the effect of anisotropy on strengths of several metamorphic rocks of southern (Çine submassif of Menderes metamorphic massif in southwest Turkey. Four different metamorphic rocks including foliated phyllite, schist, gneiss and marble (calcschist were selected and examined. Discontinuity surveys were made along lines for each rock and evaluated with DIPS program. L-type Schmidt hammer was applied in the directions parallel and perpendicular to foliation during the field study. Several hand samples and rock blocks were collected during the field study for measurements of dry and saturated densities, dry and saturated unit weights and porosity, and for petrographic analysis and strength determination in laboratory. L- and N-type Schmidt hammers were applied in the directions perpendicular (anisotropy angle of 0° and parallel (anisotropy angle of 90° to the foliation on selected blocks of phyllite, schist, gneiss and marble (calcschist. The phyllite and schist have higher porosity and lower density values than the other rocks. However, coarse crystalline gneiss and marble (calcschist have higher rebound values and strengths, and they are classified as strong–very strong rocks. Generally, the rebound values in the direction perpendicular to the foliation are slightly higher than that in the direction parallel to foliation. Rebound values of N-type Schmidt hammer are higher than the L-type values except for phyllite. Sometimes, the rebound values of laboratory and field applications gave different results. This may result from variable local conditions such as minerals differentiation, discontinuities, water content, weathering degree and thickness of foliated structure.

Deposition of a saline giant in the Mississippian Windsor Group, Nova Scotia, and the nascent Late Paleozoic Ice Age

Science.gov (United States)

MacNeil, Laura A.; Pufahl, Peir K.; James, Noel P.

2018-01-01

Saline giants are vast marine evaporite deposits that currently have no modern analogues and remain one of the most enigmatic of chemical sedimentary rocks. The Mississippian Windsor Group (ca. 345 Ma), Maritimes Basin, Atlantic Canada is a saline giant that consists of two evaporite-rich sedimentary sequences that are subdivided into five subzones. Sequence 1 is composed almost entirely of thick halite belonging to Subzone A (Osagean). Sequence 2 is in unconformable contact and comprised of stacked carbonate-evaporite peritidal cycles of Subzones B through E (Meramecian). Subzone B, the focus of research herein, documents the transition from wholly evaporitic to open marine conditions and thus, preserves an exceptional window into the processes forming saline giants. Lithofacies stacking patterns in Subzone B reveal that higher-order fluctuations in relative sea level produced nine stacked parasequences interpreted to reflect high frequency glacioeustatic oscillations during the onset of the Late Paleozoic Ice Age. Each parasequence reflects progradation of intertidal and sabkha sediments over subtidal carbonate and evaporite deposits. Dissimilarities in cycle composition between sub-basins imply the development of contrasting brine chemistries from differing recharge rates with the open ocean. What the Windsor Group shows is that evaporite type is ostensibly linked to the amplitude and frequency of sea level rise and fall during deposition. True saline giants, like the basinwide evaporites of Sequence 1, apparently require low amplitude, long frequency changes in sea level to promote the development of stable brine pools that are only periodically recharged with seawater. By contrast, the high amplitude, short frequency glacioeustatic variability in sea level that controlled the accumulation of peritidal evaporites in Subzone B produce smaller, subeconomic deposits with more complex facies relationships.

Interactions of Various types between Rock and Alkali-Activated Blast Furnace Slag

Directory of Open Access Journals (Sweden)

Mec Pavel

2017-03-01

Full Text Available Alkali-activated binders (AAB are very intensively studied materials nowadays. Because of possible usage as secondary raw materials, they can be environmentally efficient. Intensive research is focused especially on binder matrix, composition and its structure. For industrial usage, it is necessary to work with some aggregate for the preparation of mortars and concretes. Due to different structures of alkali-activated binders, the interaction with the aggregate will be different in comparison to an ordinary Portland cement binder. This paper deals with the study of interactions between several types of rocks used as aggregate and alkali-activated blast furnace slag. The research was focused especially on mechanical properties of prepared mortars.

Experimental Rock-on-Rock Abrasive Wear Under Aqueous Conditions: its Role in Subglacial Abrasion

Science.gov (United States)

Rutter, E. H.; Lee, A. G.

2003-12-01

We have determined experimentally the rate of abrasive wear of rock on rock for a range of rock types as a function of normal stress and shear displacement. Unlike abrasive wear in fault zones, where wear products accumulate as a thickening gouge zone, in our experiments wear particles were removed by flowing water. The experiments are thus directly pertinent to one of the most important processes in subglacial erosion, and to some extent in river incision. Wear was produced between rotating discs machined from rock samples and measured from the progressive approach of the disc axes towards each other under various levels of normal load. Shear displacements of several km were produced. Optical and scanning electron microscopy were used to study the worn rock surfaces, and particle size distributions in wear products were characterized using a laser particle size analyzer. Rock types studied were sandstones of various porosities and cement characteristics, schists and a granite. In all cases abrasion rate decreased logarithmically with displacement by up to 2 orders of magnitude until a steady state was approached, but only after at least 1 km displacement. The more porous, less-well cemented rocks wore fastest. Amount of abrasion could be characterized quantitatively using an exponentially decaying plus a steady-state term. Wear rate increased non-linearly with normal contact stress, apparently to an asymptote defined by the unconfined compressive strength. Microstructural study showed that the well-cemented and/or lowest porosity rocks wore by progressive abrasion of grains without plucking, whereas whole grains were plucked out of weakly-cemented and/or more porous rocks. This difference in behavior was reflected in wear-product particle size distributions. Where whole-grain plucking was possible, wear products were dominated by particles of the original grain size rather than finer rock flour. Comparison of our results to glacier basal abrasive wear estimated

Sorption of cesium in intact rock

International Nuclear Information System (INIS)

Puukko, E.

2014-04-01

The mass distribution coefficient K d is used in performance assessment (PA) to describe sorption of a radionuclide on rock. The R d is determined using crushed rock which causes uncertainty in converting the R d values to K d values for intact rock. This work describes a method to determine the equilibrium of sorption on intact rock. The rock types of the planned Olkiluoto waste disposal site were T-series mica gneiss (T-MGN), T-series tonalite granodiorite granite gneiss (T-TGG), P-series tonalite granodiorite granite gneiss (P-TGG) and pegmatitic granite (PGR). These rocks contain different amount of biotite which is the main sorbing mineral. The sorption of cesium on intact rock slices was studied by applying an electrical field to speed up migration of cesium into the rock. Cesium is in the solution as a noncomplex cation Cs + and it is sorbed by ion exchange. The tracer used in the experiments was 134 Cs. The experimental sorption on the intact rock is compared with values calculated using the in house cation exchange sorption model (HYRL model) in PHREEQC program. The observed sorption on T-MGN and T-TGG rocks was close to the calculated values. Two PGR samples were from a depth of 70 m and three samples were from a depth of 150 m. Cesium sorbed more than predicted on the two 70 m PGR samples. The sorption of Cs on the three 150 m PGR samples was small which was consistent with the calculations. The pegmatitic granite PGR has the smallest content of biotite of the four rock types. In the case of P-TGG rock the observed values of sorption were only half of the calculated values. Two kind of slices were cut from P-TGG drill core. The slices were against and to the direction of the foliation of the biotite rims. The sorption of cesium on P-TGG rock was same in both cases. The results indicated that there was no effect of the directions of the electric field and the foliation of biotite in the P-TGG rock. (orig.)

Implicit fracture modelling in FLAC3D: Assessing the behaviour of fractured shales, carbonates and other fractured rock types

NARCIS (Netherlands)

Osinga, S.; Pizzocolo, F.; Veer, E.F. van der; Heege, J.H. ter

2016-01-01

Fractured rocks play an important role in many types of petroleum and geo-energy operations. From fractured limestone reservoirs to unconventionals, understanding the geomechanical behaviour and the dynamically coupled (dual) permeability system is paramount for optimal development of these systems.

Regulation of ROCK Activity in Cancer

Science.gov (United States)

Morgan-Fisher, Marie; Wewer, Ulla M.

2013-01-01

Cancer-associated changes in cellular behavior, such as modified cell-cell contact, increased migratory potential, and generation of cellular force, all require alteration of the cytoskeleton. Two homologous mammalian serine/threonine kinases, Rho-associated protein kinases (ROCK I and II), are key regulators of the actin cytoskeleton acting downstream of the small GTPase Rho. ROCK is associated with cancer progression, and ROCK protein expression is elevated in several types of cancer. ROCKs exist in a closed, inactive conformation under quiescent conditions, which is changed to an open, active conformation by the direct binding of guanosine triphosphate (GTP)–loaded Rho. In recent years, a number of ROCK isoform-specific binding partners have been found to modulate the kinase activity through direct interactions with the catalytic domain or via altered cellular localization of the kinases. Thus, these findings demonstrate additional modes to regulate ROCK activity. This review describes the molecular mechanisms of ROCK activity regulation in cancer, with emphasis on ROCK isoform-specific regulation and interaction partners, and discusses the potential of ROCKs as therapeutic targets in cancer. PMID:23204112

The effectiveness of dispersants under various temperature and salinity regimes

International Nuclear Information System (INIS)

Fingas, M.; Fieldhouse, B.; Wang, Z.; Environment Canada, Ottawa, ON

2005-01-01

A series of tests were conducted to determine the effectiveness of dispersants in Arctic waters where salinity and temperature interactions play a critical role. In particular, Corexit 9500 was tested on Alaska North Slope oil at different temperatures and salinity using the ASTM standard test and variations of this test. Results were compared to the only historically reported test in which both temperature and salinity were changed over a range of values. This series of tests demonstrated that there is an interaction between salinity, temperature and dispersant effectiveness. It was shown that conventional and currently available dispersants are nearly ineffective at 0 salinity. Dispersant effectiveness peaks at 20 to 40 units of salinity, depending on the type of dispersant. Corexit is less sensitive to salinity, while Corexit 9527 is more sensitive to salinity. There is a smooth gradient of effectiveness with salinity both as the salinity rises to a peak point of effectiveness and as it exceeds this value. Results from the 2 field trials in fresh water suggest that laboratory tests correctly conclude that the effectiveness of dispersants is very low in freshwater. The study also examined several analytical factors such as the total petroleum hydrocarbon (TPH) versus relative petroleum hydrocarbon (RPH) methods, specific versus general calibration curves, and automatic versus manual baseline placement. The analytical variations of effectiveness by RPH or TPH methods do not affect the fundamental relationship between salinity and temperature. 6 refs., 6 tabs., 8 figs

Permanganate diffusion and reaction in sedimentary rocks.

Science.gov (United States)

Huang, Qiuyuan; Dong, Hailiang; Towne, Rachael M; Fischer, Timothy B; Schaefer, Charles E

2014-04-01

In situ chemical oxidation using permanganate has frequently been used to treat chlorinated solvents in fractured bedrock aquifers. However, in systems where matrix back-diffusion is an important process, the ability of the oxidant to migrate and treat target contaminants within the rock matrix will likely determine the overall effectiveness of this remedial approach. In this study, a series of diffusion experiments were performed to measure the permanganate diffusion and reaction in four different types of sedimentary rocks (dark gray mudstone, light gray mudstone, red sandstone, and tan sandstone). Results showed that, within the experimental time frame (~2 months), oxidant migration into the rock was limited to distances less than 500 μm. The observed diffusivities for permanganate into the rock matrices ranged from 5.3 × 10(-13) to 1.3 × 10(-11) cm(2)/s. These values were reasonably predicted by accounting for both the rock oxidant demand and the effective diffusivity of the rock. Various Mn minerals formed as surface coatings from reduction of permanganate coupled with oxidation of total organic carbon (TOC), and the nature of the formed Mn minerals was dependent upon the rock type. Post-treatment tracer testing showed that these Mn mineral coatings had a negligible impact on diffusion through the rock. Overall, our results showed that the extent of permanganate diffusion and reaction depended on rock properties, including porosity, mineralogy, and organic carbon. These results have important implications for our understanding of long-term organic contaminant remediation in sedimentary rocks using permanganate. Copyright © 2014 Elsevier B.V. All rights reserved.

The mineralogy and petrology of I-type cosmic spherules: Implications for their sources, origins and identification in sedimentary rocks

Science.gov (United States)

Genge, Matthew J.; Davies, Bridie; Suttle, Martin D.; van Ginneken, Matthias; Tomkins, Andrew G.

2017-12-01

I-type cosmic spherules are micrometeorites that formed by melting during atmospheric entry and consist mainly of iron oxides and FeNi metal. I-types are important because they can readily be recovered from sedimentary rocks allowing study of solar system events over geological time. We report the results of a study of the mineralogy and petrology of 88 I-type cosmic spherules recovered from Antarctica in order to evaluate how they formed and evolved during atmospheric entry, to constrain the nature of their precursors and to establish rigorous criteria by which they may be conclusively identified within sediments and sedimentary rocks. Two textural types of I-type cosmic spherule are recognised: (1) metal bead-bearing (MET) spherules dominated by Ni-poor (100 and suggest that metal from H-group ordinary, CM, CR and iron meteorites may form the majority of particles. Oxidation during entry heating increases in the series MET 80 wt% Ni comprising a particle mass fraction of exchange of Ni between wüstite and metal, and magnetite and wüstite are suggested as proxies for the rate of oxidation and cooling rate respectively. Variations in magnetite and wüstite crystal sizes are also suggested to relate to cooling rate allowing relative entry angle of particles to be evaluated. The formation of secondary metal in the form of sub-micron Ni-rich or Pt-group nuggets and as symplectite with magnetite was also identified and suggested to occur largely due to the exsolution of metallic alloys during decomposition of non-stoichiometric wüstite. Weathering is restricted to replacement of metal by iron hydroxides. The following criteria are recommended for the conclusive identification of I-type spherules within sediments and sedimentary rocks: (i) spherical particle morphologies, (ii) dendritic crystal morphologies, (iii) the presence of wüstite and magnetite, (iv) Ni-bearing wüstite and magnetite, and (v) the presence of relict FeNi metal.

Structural Analysis: Folds Classification of metasedimentary rock in the Peninsular Malaysia

Science.gov (United States)

Shamsuddin, A.

2017-10-01

Understanding shear zone characteristics of deformation are a crucial part in the oil and gas industry as it might increase the knowledge of the fracture characteristics and lead to the prediction of the location of fracture zones or fracture swarms. This zone might give high influence on reservoir performance. There are four general types of shear zones which are brittle, ductile, semibrittle and brittle-ductile transition zones. The objective of this study is to study and observe the structural geometry of the shear zones and its implication as there is a lack of understanding, especially in the subsurface area because of the limitation of seismic resolution. A field study was conducted on the metasedimentary rocks (shear zone) which are exposed along the coastal part of the Peninsular Malaysia as this type of rock resembles the types of rock in the subsurface. The analysis in this area shows three main types of rock which are non-foliated metaquartzite and foliated rock which can be divided into slate and phyllite. Two different fold classification can be determined in this study. Layer 1 with phyllite as the main type of rock can be classified in class 1C and layer 2 with slate as the main type of rock can be classified in class 1A. This study will benefit in predicting the characteristics of the fracture and fracture zones.

Sorptivity of rocks and soils of the van Genuchten-Mualem type

Energy Technology Data Exchange (ETDEWEB)

Zimmerman, R.W.; Bodvarsson, G.S. [Lawrence Berkeley Lab., CA (United States)

1991-06-01

One hydrological process that will have great relevance to the performance of the proposed underground radioactive waste repository at Yucca Mountain, Nevada, is that of the absorption of water from a water-filled fracture into the adjacent unsaturated rock formation. The rate at which water is imbibed by a rock depends on the hydrological properties of the rock and on the initial saturation (or initial capillary suction) of the formation. The hydrological properties that affect imbibition are the relative permeability function and the capillary pressure function. These functions are often collectively referred to as the `characteristic functions` of the porous medium. For one-dimensional absorption, it can be shown that, regardless of the details of the characteristic functions, the total amount of water imbibed by the formation, per unit surface area, will be proportional to the square root of the elapsed time. Hence the ability of a rock or soil to imbibe water can be quantified by a parameter known as the sorptivity S, which is defined such that the cumulative volumetric liquid influx per unit area is given by Q = S{radical}t. The paper discusses the simplification of these characteristic functions of porous medium.

Rocks and geology in the San Francisco Bay region

Science.gov (United States)

Stoffer, Philip W.

2002-01-01

The landscape of the San Francisco Bay region is host to a greater variety of rocks than most other regions in the United States. This introductory guide provides illustrated descriptions of 46 common and important varieties of igneous, sedimentary, and metamorphic rock found in the region. Rock types are described in context of their identification qualities, how they form, and where they occur in the region. The guide also provides discussion about of regional geology, plate tectonics, the rock cycle, the significance of the selected rock types in relation to both earth history and the impact of mineral resources on the development in the region. Maps and text also provide information where rocks, fossils, and geologic features can be visited on public lands or in association with public displays in regional museums, park visitor centers, and other public facilities.

Technical support for GEIS: radioactive waste isolation in geologic formations. Volume 18. Facility construction feasibility and costs by rock type

International Nuclear Information System (INIS)

1978-04-01

The results of a study that compared the general engineering feasibility and unit costs associated with sinking shafts and mining storage rooms in the four rock types (salt, granite, shale, basalt) are presented in this volume. The report includes a discussion of the general effects of rock characteristics on shaft and mine design, the application of these design considerations to the specific designs developed for the Draft GEIS, shaft and mine construction techniques, and the unit cost comparison. The repository designs upon which this comparison was based are presented in other volumes of this series

Absolute Salinity, ''Density Salinity'' and the Reference-Composition Salinity Scale: present and future use in the seawater standard TEOS-10

Science.gov (United States)

Wright, D. G.; Pawlowicz, R.; McDougall, T. J.; Feistel, R.; Marion, G. M.

2011-01-01

Salinity plays a key role in the determination of the thermodynamic properties of seawater and the new TEOS-101 standard provides a consistent and effective approach to dealing with relationships between salinity and these thermodynamic properties. However, there are a number of practical issues that arise in the application of TEOS-10, both in terms of accuracy and scope, including its use in the reduction of field data and in numerical models. First, in the TEOS-10 formulation for IAPSO Standard Seawater, the Gibbs function takes the Reference Salinity as its salinity argument, denoted SR, which provides a measure of the mass fraction of dissolved material in solution based on the Reference Composition approximation for Standard Seawater. We discuss uncertainties in both the Reference Composition and the Reference-Composition Salinity Scale on which Reference Salinity is reported. The Reference Composition provides a much-needed fixed benchmark but modified reference states will inevitably be required to improve the representation of Standard Seawater for some studies. However, the Reference-Composition Salinity Scale should remain unaltered to provide a stable representation of salinity for use with the TEOS-10 Gibbs function and in climate change detection studies. Second, when composition anomalies are present in seawater, no single salinity variable can fully represent the influence of dissolved material on the thermodynamic properties of seawater. We consider three distinct representations of salinity that have been used in previous studies and discuss the connections and distinctions between them. One of these variables provides the most accurate representation of density possible as well as improvements over Reference Salinity for the determination of other thermodynamic properties. It is referred to as "Density Salinity" and is represented by the symbol SAdens; it stands out as the most appropriate representation of salinity for use in dynamical physical

Absolute Salinity, "Density Salinity" and the Reference-Composition Salinity Scale: present and future use in the seawater standard TEOS-10

Science.gov (United States)

Wright, D. G.; Pawlowicz, R.; McDougall, T. J.; Feistel, R.; Marion, G. M.

2010-08-01

Salinity plays a key role in the determination of the thermodynamic properties of seawater and the new TEOS-101 standard provides a consistent and effective approach to dealing with relationships between salinity and these thermodynamic properties. However, there are a number of practical issues that arise in the application of TEOS-10, both in terms of accuracy and scope, including its use in the reduction of field data and in numerical models. First, in the TEOS-10 formulation for IAPSO Standard Seawater, the Gibbs function takes the Reference Salinity as its salinity argument, denoted SR, which provides a measure of the mass fraction of dissolved material in solution based on the Reference Composition approximation for Standard Seawater. We discuss uncertainties in both the Reference Composition and the Reference-Composition Salinity Scale on which Reference Salinity is reported. The Reference Composition provides a much-needed fixed benchmark but modified reference states will inevitably be required to improve the representation of Standard Seawater for some studies. The Reference-Composition Salinity Scale should remain unaltered to provide a stable representation of salinity for use with the TEOS-10 Gibbs function and in climate change detection studies. Second, when composition anomalies are present in seawater, no single salinity variable can fully represent the influence of dissolved material on the thermodynamic properties of seawater. We consider three distinct representations of salinity that have been used in previous studies and discuss the connections and distinctions between them. One of these variables provides the most accurate representation of density possible as well as improvements over Reference Salinity for the determination of other thermodynamic properties. It is referred to as "Density Salinity" and is represented by the symbol SAdens; it stands out as the most appropriate representation of salinity for use in dynamical physical

Exploring How Weathering Related Stresses and Subcritical Crack Growth May Influence the Size of Sediment Produced From Different Rock Types.

Science.gov (United States)

Eppes, M. C.; Hallet, B.; Hancock, G. S.; Mackenzie-Helnwein, P.; Keanini, R.

2016-12-01

outcrops of granite, sandstone, and quartzite found in Shenandoah National Park, Virginia. Preliminary results reveal that many observed cracking characteristics are consistent with our hypotheses linking subcritical crack growth, weathering stresses and the production of different sized sediment from different rock types.

Rock Slope Design Criteria : Executive Summary Report

Science.gov (United States)

2010-06-01

Based on the stratigraphy and the type of slope stability problems, the flat lying, Paleozoic age, sedimentary rocks of Ohio were divided into three design units: 1) competent rock design unit consisting of sandstones, limestones, and siltstones that...

Thermally induced rock stress increment and rock reinforcement response

International Nuclear Information System (INIS)

Hakala, M.; Stroem, J.; Nujiten, G.; Uotinen, L.; Siren, T.; Suikkanen, J.

2014-07-01

deformation zones is included. The main conclusion is that, despite deep reaching damage potential, in all the load cases studied the currently designed and used reinforcement types and configurations (rock bolts, shotcrete) are capable of handling the dead weight of the damaged rock should this occur, with damage occurring on the shotcrete liner. The long term safety and stability of the repository during its lifetime can be guaranteed by perceiving the reinforcement strategy in two stages. Firstly, by installing the rock reinforcement to sustain the initial stresses and short term increases from the start of deposition with a monitoring programme in place. Secondly, by installing additional reinforcement, if found necessary through monitoring and observation of the underground facilities. In this way, the effect of any time dependent rock stress increase affecting the reinforcement structures can be observed, in addition to creep based damage, thus providing a better level of safety than a single stage design. (orig.)

Thermally induced rock stress increment and rock reinforcement response

Energy Technology Data Exchange (ETDEWEB)

Hakala, M. [KMS Hakala Oy, Nokia (Finland); Stroem, J.; Nujiten, G.; Uotinen, L. [Rockplan, Helsinki (Finland); Siren, T.; Suikkanen, J.

2014-07-15

brittle deformation zones is included. The main conclusion is that, despite deep reaching damage potential, in all the load cases studied the currently designed and used reinforcement types and configurations (rock bolts, shotcrete) are capable of handling the dead weight of the damaged rock should this occur, with damage occurring on the shotcrete liner. The long term safety and stability of the repository during its lifetime can be guaranteed by perceiving the reinforcement strategy in two stages. Firstly, by installing the rock reinforcement to sustain the initial stresses and short term increases from the start of deposition with a monitoring programme in place. Secondly, by installing additional reinforcement, if found necessary through monitoring and observation of the underground facilities. In this way, the effect of any time dependent rock stress increase affecting the reinforcement structures can be observed, in addition to creep based damage, thus providing a better level of safety than a single stage design. (orig.)

Comparison of laboratory, in situ, and rock mass measurements of the hydraulic conductivity of metamorphic rock at the Savannah River Plant near Aiken, South Carolina

International Nuclear Information System (INIS)

Marine, I.W.

1980-01-01

In situ testing of exploratory wells in metamorphic rock indicates that two types of fracturing occur in the rock mass. Rock containing small openings that permit only extremely slow movement of water is termed virtually impermeable rock. Rock containing openings of sufficient size to permit transmission of water at a significantly faster rate is termed hydraulically transmissive rock. Laboratory methods are unsuitable for measuring hydraulic conductivity in hydraulically transmissive rock; however, for the virtually impermeable rock, values comparable to the in situ tests are obtained. The hydraulic conductivity of the rock mass over a large region is calculated by using the hydraulic gradient, porosity, and regional velocity. This velocity is determined by dividing the inferred travel distance by the age of water which is determined by the helium content of the water. This rock mass hydraulic conductivity value is between the values measured for the two types of fractures, but is closer to the measured value for the virtually impermeable rock. This relationship is attributed to the control of the regional flow rate by the virtually impermeable rock where the discrete fractures do not form a continuous open connection through the entire rock mass. Thus, laboratory methods of measuring permeability in metamorphic rock are of value if they are properly applied

Magnetic mineralogy and rock magnetic properties of silicate and carbonatite rocks from Oldoinyo Lengai volcano (Tanzania)

Science.gov (United States)

Mattsson, H. B.; Balashova, A.; Almqvist, B. S. G.; Bosshard-Stadlin, S. A.; Weidendorfer, D.

2018-06-01

Oldoinyo Lengai, a stratovolcano in northern Tanzania, is most famous for being the only currently active carbonatite volcano on Earth. The bulk of the volcanic edifice is dominated by eruptive products produced by silica-undersaturated, peralkaline, silicate magmas (effusive, explosive and/or as cumulates at depth). The recent (2007-2008) explosive eruption produced the first ever recorded pyroclastic flows at this volcano and the accidental lithics incorporated into the pyroclastic flows represent a broad variety of different rock types, comprising both extrusive and intrusive varieties, in addition to various types of cumulates. This mix of different accidental lithics provides a unique insight into the inner workings of the world's only active carbonatite volcano. Here, we focus on the magnetic mineralogy and the rock magnetic properties of a wide selection of samples spanning the spectrum of Oldoinyo Lengai rock types compositionally, as well from a textural point of view. Here we show that the magnetic properties of most extrusive silicate rocks are dominated by magnetite-ulvöspinel solid solutions, and that pyrrhotite plays a larger role in the magnetic properties of the intrusive silicate rocks. The natrocarbonatitic lavas, for which the volcano is best known for, show distinctly different magnetic properties in comparison with the silicate rocks. This discrepancy may be explained by abundant alabandite crystals/blebs in the groundmass of the natrocarbonatitic lavas. A detailed combination of petrological/mineralogical studies with geophysical investigations is an absolute necessity in order to understand, and to better constrain, the overall architecture and inner workings of the subvolcanic plumbing system. The results presented here may also have implications for the quest in order to explain the genesis of the uniquely natrocarbonatitic magmas characteristic of Oldoinyo Lengai.

Geohydromechanical Processes in the Excavation Damaged Zone in Crystalline Rock, Rock Salt, and Indurated and Plastic Clays

International Nuclear Information System (INIS)

Tsang, Chin-Fu; Bernier, Frederic; Davies, Christophe

2004-01-01

The creation of an excavation disturbed zone or excavation damaged zone is expected around all man-made openings in geologic formations. Macro- and micro-fracturing, and in general a redistribution of in situ stresses and rearrangement of rock structures, will occur in this zone, resulting in drastic changes of permeability to flow, mainly through the fractures and cracks induced by excavation. Such an EDZ may have significant implications for the operation and long-term performance of an underground nuclear waste repository. Various issues of concern need to be evaluated, such as processes creating fractures in the excavation damaged zone, the degree of permeability increase, and the potential for sealing or healing (with permeability reduction) in the zone. In recent years, efforts along these lines have been made for a potential repository in four rock types-crystalline rock, salt, indurated clay, and plastic clay-and these efforts have involved field, laboratory, and theoretical studies. The present work involves a synthesis of the ideas and issues that emerged from presentations and discussions on EDZ in these four rock types at a CLUSTER Conference and Workshop held in Luxembourg in November, 2003. First, definitions of excavation disturbed and excavation damaged zones are proposed. Then, an approach is suggested for the synthesis and intercomparison of geohydromechanical processes in the EDZ for the four rock types (crystalline rock, salt, indurated clay, and plastic clay). Comparison tables of relevant processes, associated factors, and modeling and testing techniques are developed. A discussion of the general state-of-the-art and outstanding issues are also presented. A substantial bibliography of relevant papers on the subject is supplied at the end of the paper

High salinity conveys thermotolerance in the coral model Aiptasia

KAUST Repository

Gegner, Hagen M.

2017-12-15

The endosymbiosis between dinoflagellate algae of the genus Symbiodinium and stony corals provides the foundation of coral reef ecosystems. Coral bleaching, the expulsion of endosymbionts from the coral host tissue as a consequence of heat or light stress, poses a threat to reef ecosystem functioning on a global scale. Hence, a better understanding of the factors contributing to heat stress susceptibility and tolerance is needed. In this regard, some of the most thermotolerant corals also live in particularly saline habitats, but possible effects of high salinity on thermotolerance in corals are anecdotal. Here we test the hypothesis that high salinity may lead to increased thermotolerance. We conducted a heat stress experiment at low, intermediate, and high salinities using a set of host-endosymbiont combinations of the coral model Aiptasia. As expected, all host-endosymbiont combinations showed reduced photosynthetic efficiency and endosymbiont loss during heat stress, but the severity of bleaching was significantly reduced with increasing salinities for one of the host-endosymbiont combinations. Our results show that higher salinities can convey increased thermotolerance in Aiptasia, although this effect seems to be dependent on the particular host strain and/or associated symbiont type. This finding may help explain the extraordinarily high thermotolerance of corals in high salinity environments such as the Red Sea and the Persian/Arabian Gulf and provides novel insight regarding factors that contribute to thermotolerance. Since our results are based on a salinity effect in symbiotic sea anemones, it remains to be determined whether this salinity effect can also be observed in stony corals.

High salinity conveys thermotolerance in the coral model Aiptasia

KAUST Repository

Gegner, Hagen M.; Ziegler, Maren; Radecker, Nils; Buitrago Lopez, Carol; Aranda, Manuel; Voolstra, Christian R.

2017-01-01

The endosymbiosis between dinoflagellate algae of the genus Symbiodinium and stony corals provides the foundation of coral reef ecosystems. Coral bleaching, the expulsion of endosymbionts from the coral host tissue as a consequence of heat or light stress, poses a threat to reef ecosystem functioning on a global scale. Hence, a better understanding of the factors contributing to heat stress susceptibility and tolerance is needed. In this regard, some of the most thermotolerant corals also live in particularly saline habitats, but possible effects of high salinity on thermotolerance in corals are anecdotal. Here we test the hypothesis that high salinity may lead to increased thermotolerance. We conducted a heat stress experiment at low, intermediate, and high salinities using a set of host-endosymbiont combinations of the coral model Aiptasia. As expected, all host-endosymbiont combinations showed reduced photosynthetic efficiency and endosymbiont loss during heat stress, but the severity of bleaching was significantly reduced with increasing salinities for one of the host-endosymbiont combinations. Our results show that higher salinities can convey increased thermotolerance in Aiptasia, although this effect seems to be dependent on the particular host strain and/or associated symbiont type. This finding may help explain the extraordinarily high thermotolerance of corals in high salinity environments such as the Red Sea and the Persian/Arabian Gulf and provides novel insight regarding factors that contribute to thermotolerance. Since our results are based on a salinity effect in symbiotic sea anemones, it remains to be determined whether this salinity effect can also be observed in stony corals.

A review of theories on the origins of saline waters and brines in the Canadian Precambrian Shield

International Nuclear Information System (INIS)

Bottomley, D.J.

1996-02-01

Groundwater at depths greater that 500 m in the Canadian Precambrian Shield is typically saline with a sodium-calcium/chloride chemical composition. Brines with dissolved solid concentrations exceeding 100 g/L have been encountered in several deep mines (>1000 m) on the Shield. Theories on the origins of these deep saline waters and brines can be grouped into two general categories: (1) autochthonous (in situ) origins attributable to silicate mineral hydrolysis over geologic time scales, leaching of fluid inclusions or radiolysis effects, and (2) allochthonous (external) sources caused by the infiltration of brine of modified seawater origins in the geologic past. Although the chemical and isotopic compositions of these waters clearly reflect the effects of reaction between the water and their silicate host rocks, it is unlikely that the high chlorinity of the brines is in an autochthonous attribute. It is proposed that the compositions of these brines are most compatible with the Paleozoic residual brine hypothesis of Spencer (1987). This theory invokes deep infiltration of a high-density residual brine, formed by the evaporation of seawater during Devonian time, into underlying Precambrian basement rocks where subsequent chemical modifications occurred. (author) 39 refs., 2 figs

Fault rocks and uranium mineralization

International Nuclear Information System (INIS)

Tong Hangshou.

1991-01-01

The types of fault rocks, microstructural characteristics of fault tectonite and their relationship with uranium mineralization in the uranium-productive granite area are discussed. According to the synthetic analysis on nature of stress, extent of crack and microstructural characteristics of fault rocks, they can be classified into five groups and sixteen subgroups. The author especially emphasizes the control of cataclasite group and fault breccia group over uranium mineralization in the uranium-productive granite area. It is considered that more effective study should be made on the macrostructure and microstructure of fault rocks. It is of an important practical significance in uranium exploration

Establishment of tunnel-boring machine disk cutter rock-breaking model from energy perspective

Directory of Open Access Journals (Sweden)

Liwei Song

2015-12-01

Full Text Available As the most important cutting tools during tunnel-boring machine tunneling construction process, V-type disk cutter’s rock-breaking mechanism has been researched by many scholars all over the world. Adopting finite element method, this article focused on the interaction between V-type disk cutters and the intact rock to carry out microscopic parameter analysis methods: first, the stress model of rock breaking was established through V-type disk cutter motion trajectory analysis; second, based on the incremental theorem of the elastic–plastic theory, the strain model of the relative changes of rock displacement during breaking process was created. According to the principle of admissible work by energy method of the elastic–plastic theory to analyze energy transfer rules in the process of breaking rock, rock-breaking force of the V-type disk cutter could be regarded as the external force in the rock system. Finally, by taking the rock system as the reference object, the total potential energy equivalent model of rock system was derived to obtain the forces of the three directions acting on V-type disk cutter during the rock-breaking process. This derived model, which has been proved to be effective and scientific through comparisons with some original force models and by comparative analysis with experimental data, also initiates a new research strategy taking the view of the micro elastic–plastic theory to study the rock-breaking mechanism.

Effect of type of explosives and physical-mechanical properties of explosive rock on formation of toxic gases in atmosphere of shafts

Science.gov (United States)

Mindeli, E. O.; Khudyakov, M. Y.

1981-01-01

The quality of toxic gases formed during explosive work in underground shafts depends upon the type of explosives and the conditions of explosion. Several types of explosives and rocks were examined. All remaining conditions were maintained the same (sandy-argillaceous stemming, electrical method of explosions, diameter of blast holes, and the direct triggering of charges).

Porewater salinity and the development of swelling pressure in bentonite-based buffer and backfill materials

Energy Technology Data Exchange (ETDEWEB)

Dixon, D.A. [Atomic Energy of Canada Limited (Canada)

2000-06-01

At the depths proposed for a nuclear fuel waste repository, it is likely that saline groundwater conditions will be encountered in the granitic rocks of Finland and Canada. The potential for saline groundwater to influence of the ability of bentonite-based buffer and backfilling materials to swell and thereby generate swelling pressure has been reviewed. Based on the data collected from existing literature, it would appear that porewater salinities as high as 100 g/l will not compromise the ability of confined, bentonite-based materials to develop a swelling pressure of at least 100 kPa on its confinement, provided the effective clay dry density (ECDD), exceeds approximately 0.9 Mg/m{sup 3}. At densities less than approximately 0.9 Mg/m{sup 3} the swelling pressure of bentonite-based materials may be reduced and become sensitive to salt concentration. The influence of porewater salinity on swelling pressure can be compared on the basis of the ECDD required to develop 100 kPa of swelling pressure. In order to generate 100 kPa of swelling pressure an ECDD of approximately 0.7 Mg/m{sup 3} is required to be present under fresh water or brackish porewater conditions. This density would need to be increased to approximately 0.9 Mg/m{sup 3} where the groundwater conditions were saline. The impact that groundwater salinity will have on density specifications for buffer and backfilling materials are discussed with reference to the nuclear fuel waste disposal concepts of Finland and Canada. (orig.)

Ground water chemistry and water-rock interaction at Olkiluoto

International Nuclear Information System (INIS)

Pitkaenen, P.; Front, K.

1992-02-01

Bedrock investigations for the final repository for low- and intermediate level wastes (VLJ repository) generated at the Olkiluoto (TVO-I and TVO-II) nuclear power plant, stareted in 1980. Since 1988 the area has been investigated for the final disposal of spent nuclear fuel. In the report the geochemistry at the nuclear waste investigation site, Olkiluoto, is evaluated. The hydrogeological data are collected from boreholes drilled down to 1000-m depth into Proterozoic crystalline bedrock. The interpretation is based on groundwater chemistry and isotope data, mineralogical data, and the structure and hydrology of the bedrock, using correlation diagrams and thermodynamic calculations (PHREEQE). The hydrogeochemistry and major processes controlling the groundwater chemistry are discussed. The groundwater types are characterized by water-rock interaction but they also show features of other origins. The fresh and brackish waters are contaminated by varying amounts of young meteoric water and brackish seawater. The saline water contains residues of possibly ancient hydrothermal waters, imprints of which are occasionally seen in the rock itself. Different mixing phenomenas are indicated by the isotope contents (O-l8/H-2, H-3) and the Ca/Cl, Na/Cl, HCO 3 /Cl, SO 4 /Cl, Br/Cl, SI(calcite)/SI(dolomite) ratios. The interaction between bedrock and groundwater is reflected by the behaviour of pH, Eh, Ca, Mg, Na, K, Fe, HCO 3 and S0 4 . Dissolution and precipitation of calcite and pyrite, and aluminosilicate hydrolysis play the major role in defining the groundwater composition of the above components

The Usability of Noise Level from Rock Cutting for the Prediction of Physico-Mechanical Properties of Rocks

Science.gov (United States)

Delibalta, M. S.; Kahraman, S.; Comakli, R.

2015-11-01

Because the indirect tests are easier and cheaper than the direct tests, the prediction of rock properties from the indirect testing methods is important especially for the preliminary investigations. In this study, the predictability of the physico-mechanical rock properties from the noise level measured during cutting rock with diamond saw was investigated. Noise measurement test, uniaxial compressive strength (UCS) test, Brazilian tensile strength (BTS) test, point load strength (Is) test, density test, and porosity test were carried out on 54 different rock types in the laboratory. The results were statistically analyzed to derive estimation equations. Strong correlations between the noise level and the mechanical rock properties were found. The relations follow power functions. Increasing rock strength increases the noise level. Density and porosity also correlated strongly with the noise level. The relations follow linear functions. Increasing density increases the noise level while increasing porosity decreases the noise level. The developed equations are valid for the rocks with a compressive strength below 150 MPa. Concluding remark is that the physico-mechanical rock properties can reliably be estimated from the noise level measured during cutting the rock with diamond saw.

Geotechnical properties of rock

Energy Technology Data Exchange (ETDEWEB)

Jackson, R.; Gorski, B.; Gyenge, M.

1995-12-31

The manual is a compilation of the geotechnical properties of many types of rock that are typical of Canadian mining environments. Included are values for density, porosity, compressive and shear wave velocity, uniaxial compressive strength, Young`s modulus, and Poisson`s ratio. The data base contains material constants that were determined using the Hoek and Brown failure criteria for both before and after failure conditions. 76 data sheets of rock properties in Canadian mines are included. 7 refs., 85 figs., 3 tabs.

Absolute Salinity, ''Density Salinity'' and the Reference-Composition Salinity Scale: present and future use in the seawater standard TEOS-10

Directory of Open Access Journals (Sweden)

D. G. Wright

2011-01-01

Full Text Available Salinity plays a key role in the determination of the thermodynamic properties of seawater and the new TEOS-10¹ standard provides a consistent and effective approach to dealing with relationships between salinity and these thermodynamic properties. However, there are a number of practical issues that arise in the application of TEOS-10, both in terms of accuracy and scope, including its use in the reduction of field data and in numerical models.

First, in the TEOS-10 formulation for IAPSO Standard Seawater, the Gibbs function takes the Reference Salinity as its salinity argument, denoted S_R, which provides a measure of the mass fraction of dissolved material in solution based on the Reference Composition approximation for Standard Seawater. We discuss uncertainties in both the Reference Composition and the Reference-Composition Salinity Scale on which Reference Salinity is reported. The Reference Composition provides a much-needed fixed benchmark but modified reference states will inevitably be required to improve the representation of Standard Seawater for some studies. However, the Reference-Composition Salinity Scale should remain unaltered to provide a stable representation of salinity for use with the TEOS-10 Gibbs function and in climate change detection studies.

Second, when composition anomalies are present in seawater, no single salinity variable can fully represent the influence of dissolved material on the thermodynamic properties of seawater. We consider three distinct representations of salinity that have been used in previous studies and discuss the connections and distinctions between them. One of these variables provides the most accurate representation of density possible as well as improvements over Reference Salinity for the determination of other thermodynamic properties. It is referred to as "Density Salinity" and is represented by the symbol

Sodium kinetics in hypertonic saline abortion

International Nuclear Information System (INIS)

Telfer, N.; Ballard, C.S.; McKee, D.R.

1975-01-01

The sodium kinetics of hypertonic saline abortions have been followed by measuring the radioactivity and the sodium concentrations in amniotic fluid, maternal plasma, urine, the foetus and placenta after intrauterine installation of 20% hypertonic saline labelled with 22 Na in order to determine the reason for abortion of a dead foetus in 24 to 48 hours, and reasons for sodium reactions. There is dilution of the 300 ml of amniotic fluid to a maximum of 1.5 to 2.0 litres in an exponential fashion, by the influx of mainly maternal water, slowing after 8 hours. There is an exponential type of increase in plasma radioactivity, also slowing after 8 hours. However, equilibration is never reached, the specific activity of the amniotic fluid remaining 10 times that of the plasma, and the sodium concentration 3 times that of the plasma. The urine equilibrates with the plasma, and about 3% of the administered dose is lost in 22 hours. The largest foetus and placenta picked up the least radioactivity. Thus, a more mature foetus may be protected to some degree against the hypertonic saline action; this has been observed clinically. Hyperkaliaemia was found in all four subjects, and hypoglycaemia occurred sporadically. These were not accompanied by any symptoms. Factors associated with expulsion of the dead foetus are dehydration and decreased circulation associated with fibrinoid necrosis of the placenta, which may also account for cessation of equilibration between maternal plasma and amniotic fluid. Although no saline reactions occurred, the role of extrauterine deposition of hypertonic saline, as shown in one subject, might be considered. (author)

Synthetic Rock Analogue for Permeability Studies of Rock Salt with Mudstone

Directory of Open Access Journals (Sweden)

Hongwu Yin

2017-09-01

Full Text Available Knowledge about the permeability of surrounding rock (salt rock and mudstone interlayer is an important topic, which acts as a key parameter to characterize the tightness of gas storage. The goal of experiments that test the permeability of gas storage facilities in rock salt is to develop a synthetic analogue to use as a permeability model. To address the permeability of a mudstone/salt layered and mixed rock mass in Jintan, Jiangsu Province, synthetic mixed and layered specimens using the mudstone and the salt were fabricated for permeability testing. Because of the gas “slippage effect”, test results are corrected by the Klinkenberg method, and the permeability of specimens is obtained by regression fitting. The results show that the permeability of synthetic pure rock salt is 6.9 × 10−20 m2, and its porosity is 3.8%. The permeability of synthetic mudstone rock is 2.97 × 10−18 m2, with a porosity 17.8%. These results are close to those obtained from intact natural specimens. We also find that with the same mudstone content, the permeability of mixed specimens is about 40% higher than for the layered specimens, and with an increase in the mudstone content, the Klinkenberg permeability increases for both types of specimens. The permeability and mudstone content have a strong exponential relationship. When the mudstone content is below 40%, the permeability increases only slightly with mudstone content, whereas above this threshold, the permeability increases rapidly with mudstone content. The results of the study are of use in the assessment of the tightness of natural gas storage facilities in mudstone-rich rock salt formations in China.

Conceptual and safety-related questions in the final storage of radioactive waste - a comparison of various types of host rock

International Nuclear Information System (INIS)

Kleemann, U.

2005-01-01

The German Federal Office for Radiation Protection (BfS) in early November published the synthesis report (BfS 2005) about the conceptual and safety-related specific questions associated with the final storage of radioactive waste. In addition to a condensed version of twelve individual projects, the report contains a description of the results of the peer review and the workshops carried out, in particular an evaluation comparing different types of host rock in Germany. The whole project constitutes a comprehensive documentation of the current state of the art. Findings are expressed at a general level referring neither to the suitability of any specific repository site nor to that of salts as a repository formation, but covering all potential repository formations in deep geologic strata in Germany. The limits to and possibilities of, generic comparisons of various types of host rock are shown. It si seen that, in principle, none of the host rock varieties in Germany would be preferable to others. Numerous problems can be solved only for specific sites, thus requiring site comparisons. While some questions indicate a need for regulatory treatment, the need for basic research is considered to be low. The contribution presents the main findings made in each of the specific projects and the evaluations by the Office. (orig.)

Extrapolation of bulk rock elastic moduli of different rock types to high pressure conditions and comparison with texture-derived elastic moduli

Science.gov (United States)

Ullemeyer, Klaus; Lokajíček, Tomás; Vasin, Roman N.; Keppler, Ruth; Behrmann, Jan H.

2018-02-01

In this study elastic moduli of three different rock types of simple (calcite marble) and more complex (amphibolite, micaschist) mineralogical compositions were determined by modeling of elastic moduli using texture (crystallographic preferred orientation; CPO) data, experimental investigation and extrapolation. 3D models were calculated using single crystal elastic moduli, and CPO measured using time-of-flight neutron diffraction at the SKAT diffractometer in Dubna (Russia) and subsequently analyzed using Rietveld Texture Analysis. To define extrinsic factors influencing elastic behaviour, P-wave and S-wave velocity anisotropies were experimentally determined at 200, 400 and 600 MPa confining pressure. Functions describing variations of the elastic moduli with confining pressure were then used to predict elastic properties at 1000 MPa, revealing anisotropies in a supposedly crack-free medium. In the calcite marble elastic anisotropy is dominated by the CPO. Velocities continuously increase, while anisotropies decrease from measured, over extrapolated to CPO derived data. Differences in velocity patterns with sample orientation suggest that the foliation forms an important mechanical anisotropy. The amphibolite sample shows similar magnitudes of extrapolated and CPO derived velocities, however the pattern of CPO derived velocity is closer to that measured at 200 MPa. Anisotropy decreases from the extrapolated to the CPO derived data. In the micaschist, velocities are higher and anisotropies are lower in the extrapolated data, in comparison to the data from measurements at lower pressures. Generally our results show that predictions for the elastic behavior of rocks at great depths are possible based on experimental data and those computed from CPO. The elastic properties of the lower crust can, thus, be characterized with an improved degree of confidence using extrapolations. Anisotropically distributed spherical micro-pores are likely to be preserved, affecting

Mechanical properties of granitic rocks from Gideaa, Sweden

International Nuclear Information System (INIS)

Ljunggren, C.; Stephansson, O.; Alm, O.; Hakami, H.; Mattila, U.

1985-10-01

The elastic and mechanical properties were determined for two rock types from the Gideaa study area. Gideaa is located approximately 30 km north-east of Oernskoeldsvik, Northern Sweden. The rock types that were tested were migmatitic gneiss and migmatitic granite. The following tests were conducted: - sound velocity measurements; - uniaxial compression tests with acoustic emission recording; - brazilian disc tests; - triaxial tests; - three point bending tests. All together, 12 rock samples were tested with each test method. Six samples of these were migmatic gneiss and six samples were migmatitic granite. The result shows that the migmatitic gneiss has varying strength properties with low compressive strength in comparison with its high tensile strength. The migmatitic granite, on the other hand, is found to have parameter values similar to other granitic rocks. With 15 refs. (Author)

Water-rock interaction and chemistry of groundwaters from the Canadian Shield

International Nuclear Information System (INIS)

Frape, S.K.; Fritz, P.; McNutt, R.H.

1984-01-01

The chemical and isotopic compositions of groundwaters in the crystalline rocks of the Canadian Shield reflect different degrees of rock-water interactions. The chemistry of the shallow, geochemically immature ground waters and especially of the major cations is controlled by local rock compositions, whereby dissolution reactions dominate. Conservative constituents, such as chloride and bromide, however, are not entirely a result of such reactions but appear to be readily added from leachable salts during the initial stages of the geochemical evolution of these waters. Their concentration changes little as major cations increase, until concentrations of Total Dissolved Solids (TDS) reach 3000 to 5000 mg l -1 . The isotopic composition of these shallow waters reflects local, present day precipitations. In contrast to the shallow groundwaters, the isotopic and chemical compositions of the deep, saline waters and brines are determined by extensive, low-temperature rock-water interactions. This is documented in major ion chemistries, 18 O contents and strontium isotopic compositions. These data indicate that the deep brines have been contained in hydrologically isolated pockets. The almost total loss of primary compositions make discussions on the origin of these brines very speculative. However, all brines from across the Canadian Shield have a very similar chemical composition, which probably reflects a common geochemical history. (author)

Neutron pole figures compared with magnetic preferred orientations of different rock types

International Nuclear Information System (INIS)

Hansen, Anke; Chadima, Martin; Cifelli, Francesca; Brokmeier, H.-G.Heinz-Guenter; Siemes, Heinrich

2004-01-01

Neutron diffraction is an excellent tool for pole figure measurement of rock samples. Due to high penetration depth of neutrons for most materials neutron diffraction represents an efficient tool to measure complete pole figures with reliable grain statistics even in coarse grained or inequi-granular materials. In the field of structural geology, the measurement of anisotropy of magnetic susceptibility is a standard technique to reveal the tectonic history of deformed rocks. The application of both techniques on still ongoing studies of Precambrian, Carboniferous and Quaternary rocks which are characterised by fundamental different tectonic evolutions and mineralogical compositions shows the wide field of relevance and importance of these methods in understanding tectonic processes in detail

A comparison of sputum induction methods: ultrasonic vs compressed-air nebulizer and hypertonic vs isotonic saline inhalation.

Science.gov (United States)

Loh, L C; Eg, K P; Puspanathan, P; Tang, S P; Yip, K S; Vijayasingham, P; Thayaparan, T; Kumar, S

2004-03-01

Airway inflammation can be demonstrated by the modem method of sputum induction using ultrasonic nebulizer and hypertonic saline. We studied whether compressed-air nebulizer and isotonic saline which are commonly available and cost less, are as effective in inducing sputum in normal adult subjects as the above mentioned tools. Sixteen subjects underwent weekly sputum induction in the following manner: ultrasonic nebulizer (Medix Sonix 2000, Clement Clarke, UK) using hypertonic saline, ultrasonic nebulizer using isotonic saline, compressed-air nebulizer (BestNeb, Taiwan) using hypertonic saline, and compressed-air nebulizer using isotonic saline. Overall, the use of an ultrasonic nebulizer and hypertonic saline yielded significantly higher total sputum cell counts and a higher percentage of cell viability than compressed-air nebulizers and isotonic saline. With the latter, there was a trend towards squamous cell contaminations. The proportion of various sputum cell types was not significantly different between the groups, and the reproducibility in sputum macrophages and neutrophils was high (Intraclass correlation coefficient, r [95%CI]: 0.65 [0.30-0.91] and 0.58 [0.22-0.89], p compressed-air nebulizers and isotonic saline. We conclude that in normal subjects, although both nebulizers and saline types can induce sputum with reproducible cellular profile, ultrasonic nebulizers and hypertonic saline are more effective but less well tolerated.

Smart Rocking Armour Units

OpenAIRE

Hofland, B.; Arefin, Syed Shamsil; van der Lem, Cock; van gent, Marcel

2018-01-01

This paper describes a method to measure the rocking motion of lab-scale armour units. Sensors as found in mobile phones are used. These sensors, data-storage and battery are all embedded in the model units, such that they can be applied without wires attached to them. The technique is applied to double-layer units in order to compare the results to the existing knowledge for this type of armour layers. In contrast to previous research, the gyroscope reading is used to determine the (rocking)...

Development of a coastal drought index using salinity data

Science.gov (United States)

Conrads, Paul; Darby, Lisa S.

2017-01-01

A critical aspect of the uniqueness of coastal drought is the effects on the salinity dynamics of creeks, rivers, and estuaries. The location of the freshwater–saltwater interface along the coast is an important factor in the ecological and socioeconomic dynamics of coastal communities. Salinity is a critical response variable that integrates hydrologic and coastal dynamics including sea level, tides, winds, precipitation, streamflow, and tropical storms. The position of the interface determines the composition of freshwater and saltwater aquatic communities as well as the freshwater availability for water intakes. Many definitions of drought have been proposed, with most describing a decline in precipitation having negative impacts on the water supply. Indices have been developed incorporating data such as rainfall, streamflow, soil moisture, and groundwater levels. These water-availability drought indices were developed for upland areas and may not be ideal for characterizing coastal drought. The availability of real-time and historical salinity datasets provides an opportunity for the development of a salinity-based coastal drought index. An approach similar to the standardized precipitation index (SPI) was modified and applied to salinity data obtained from sites in South Carolina and Georgia. Using the SPI approach, the index becomes a coastal salinity index (CSI) that characterizes coastal salinity conditions with respect to drought periods of higher-saline conditions and wet periods of higher-freshwater conditions. Evaluation of the CSI indicates that it provides additional coastal response information as compared to the SPI and the Palmer hydrologic drought index, and the CSI can be used for different estuary types and for comparison of conditions along coastlines.

Rock Physical Interpretation of the Relationship between Dynamic and Static Young's Moduli of Sedimentary Rocks

Science.gov (United States)

Takahashi, T.

2017-12-01

The static Young's modulus (deformability) of a rock is indispensable for designing and constructing tunnels, dams and underground caverns in civil engineering. Static Young's modulus which is an elastic modulus at large strain level is usually obtained with the laboratory tests of rock cores sampled in boreholes drilled in a rock mass. A deformability model of the entire rock mass is then built by extrapolating the measurements based on a rock mass classification obtained in geological site characterization. However, model-building using data obtained from a limited number of boreholes in the rock mass, especially a complex rock mass, may cause problems in the accuracy and reliability of the model. On the other hand, dynamic Young's modulus which is the modulus at small strain level can be obtained from seismic velocity. If dynamic Young's modulus can be rationally converted to static one, a seismic velocity model by the seismic method can be effectively used to build a deformability model of the rock mass. In this study, we have, therefore, developed a rock physics model (Mavko et al., 2009) to estimate static Young's modulus from dynamic one for sedimentary rocks. The rock physics model has been generally applied to seismic properties at small strain level. In the proposed model, however, the sandy shale model, one of rock physics models, is extended for modeling the static Young's modulus at large strain level by incorporating the mixture of frictional and frictionless grain contacts into the Hertz-Mindlin model. The proposed model is verified through its application to the dynamic Young's moduli derived from well log velocities and static Young's moduli measured in the tri-axial compression tests of rock cores sampled in the same borehole as the logs were acquired. This application proves that the proposed rock physics model can be possibly used to estimate static Young's modulus (deformability) which is required in many types of civil engineering applications

Geochronology, geochemistry, and petrogenesis of late Permian to early Triassic mafic rocks from Darongshan, South China: Implications for ultrahigh-temperature metamorphism and S-type granite generation

Science.gov (United States)

Xu, Wang-Chun; Luo, Bi-Ji; Xu, Ya-Jun; Wang, Lei; Chen, Qi

2018-05-01

The role of the mantle in generating ultrahigh-temperature metamorphism and peraluminous S-type granites, and the extent of crust-mantle interaction are topics fundamental to our understanding of the Earth's evolution. In this study we present geochronological, geochemical, and Sr-Nd-Hf isotopic data for dolerites and mafic volcanic rocks from the Darongshan granite complex belt in western Cathaysia, South China. LA-ICP-MS U-Pb zircon analyses yielded magma crystallization ages of ca. 250-248 Ma for the dolerites, which are coeval with eruption of the mafic volcanic rocks, ultrahigh-temperature metamorphism, and emplacement of S-type granites in the Darongshan granite complex belt. The mafic volcanic rocks are high-K calc-alkaline or shoshonitic, enriched in Th, U, and light rare earth elements, and depleted in Nb, Ta and Ti. The dolerites are characterized by high Fe2O3tot (11.61-20.39 wt%) and TiO2 (1.62-3.17 wt%), and low MgO (1.73-4.38 wt%), Cr (2.8-10.8 ppm) and Ni (2.5-11.4 ppm). Isotopically, the mafic volcanic rocks have negative whole-rock εNd(t) values (-6.7 to -9.0) and high ISr values (0.71232 to 0.71767), which are slightly depleted compared with the dolerite samples (εNd(t) = -10.3 to -10.4 and ISr = 0.71796 to 0.71923). Zircons in the dolerites have εHf(t) values of -7.6 to -10.9. The mafic volcanic rocks are interpreted to have resulted from the partial melting of an enriched lithospheric mantle source with minor crustal contamination during ascent, whereas the dolerites formed by late-stage crystallization of enriched lithospheric mantle-derived magmas after fractionation of olivine and pyroxene. The formation of these mantle-derived mafic rocks may be attributed to transtension along a NE-trending strike-slip fault zone that was related to oblique subduction of the Paleo-Pacific plate beneath South China. Such underplated mafic magmas would provide sufficient heat for the generation of ultrahigh-temperature metamorphism and S-type granites, and

Na+/K+-ATPase and vacuolar-type H+-ATPase in the gills of the aquatic air-breathing fish Trichogaster microlepis in response to salinity variation.

Science.gov (United States)

Huang, Chun-Yen; Chao, Pei-Lin; Lin, Hui-Chen

2010-03-01

The aquatic air-breathing fish, Trichogaster microlepis, can be found in fresh water and estuaries. We further evaluated the changes in two important osmoregulatory enzymes, Na(+)/K(+)-ATPase (NKA) and vacuolar-type H(+)-ATPase (VHA), in the gills when fish were subjected to deionized water (DW), fresh water (FW), and salinated brackish water (salinity of 10 g/L). Fish were sampled only 4 days after experimental transfer. The mortality, plasma osmolality, and Na(+) concentration were higher in 10 g/L acclimated fish, while their muscle water content decreased with elevated external salinity. The highest NKA protein abundance was found in the fish gills in 10 g/L, and NKA activity was highest in the DW and 10 g/L acclimated fish. The VHA protein levels were highest in 10 g/L, and VHA activity was highest in the DW treatment. From immunohistochemical results, we found three different cell populations: (1) NKA-immunoreactive (NKA-IR) cells, (2) both NKA-IR and HA-IR cells, and (3) HA-IR cells. NKA-IR cells in the lamellar and interlamellar regions significantly increased in DW and 10 g/L treatments. Only HA-IR cells in the lamellar region were significantly increased in DW. In the interlamellar region, there was no difference in the number of HA-IR cells among the three treated. From these results, T. microlepis exhibited osmoregulatory ability in DW and 10 g/L treatments. The cell types involved in ionic regulation were also examined with immunofluorescence staining; three ionocyte types were found which were similar to the zebrafish model. Copyright 2009 Elsevier B.V. All rights reserved.

Microbial Fluid-Rock Interactions in Chalk Samples and Salinity Factor in Divalent Ca2+ ions Release for Microbial Enhanced Oil Recovery Purposes

DEFF Research Database (Denmark)

Jimoh, Ismaila Adetunji; Rudyk, Svetlana Nikolayevna; Søgaard, Erik Gydesen

2011-01-01

In this study, laboratory experiments were performed on chalk samples from Danish sector of the North Sea to study microbial fluid-rock interactions with carbonate rock and to evaluate the dissolution of rock matrix (CaCO3). Result showed that the average concentration of Ca2+ ions after microbia...

Summary of United States Geological Survey investigations of fluid-rock-waste reactions in evaporite environments under repository conditions

International Nuclear Information System (INIS)

Stewart, D.B.; Jones, B.F.; Roedder, E.; Potter, R.W. II

1980-01-01

The interstitial and inclusion fluids contained in rock salt and anhydrite, though present in amounts less than 1 weight per cent, are chemically aggressive and may react with canisters or wastes. The three basic types of fluids are: (1) bitterns residual from saline mineral precipitation including later recrystallization reactions; (2) brines containing residual solutes from the formation of evaporite that have been extensively modified by reactions with contiguous carbonate of clastic rocks; and (3) re-solution brines resulting from secondary dehydration of evaporite minerals or solution of saline minerals by undersaturated infiltrating waters. Fluid composition can indicate that meteoric flow systems have contacted evaporites or that fluids from evaporites have migrated into other formations. The movement of fluids trapped in fluid inclusions in salt from southeast New Mexico is most sensitive to ambient temperature and to inclusion size, although several other factors such as thermal gradient and vapour/liquid ratio are also important. There is no evidence of a threshold temperature for movement of inclusions. Empirical data are given for determining the amount of brine reaching the heat source if the temperature, approximate amount of total dissolved solids, and Ca:Mg ratio in the brine are known. SrCl 2 and CsCl can reach high concentrations in saturated NaCl solutions and greatly depress the liquidus. The possibility that such fluids, if generated, could migrate from a high-level waste repository must be minimized because the fluid would contain its own radiogenic energy source in the first decades after repository closure, thus changing the thermal evolution of the repository from designed values. (author)

X-ray microtomography application in pore space reservoir rock.

Science.gov (United States)

Oliveira, M F S; Lima, I; Borghi, L; Lopes, R T

2012-07-01

Characterization of porosity in carbonate rocks is important in the oil and gas industry since a major hydrocarbons field is formed by this lithology and they have a complex media porous. In this context, this research presents a study of the pore space in limestones rocks by x-ray microtomography. Total porosity, type of porosity and pore size distribution were evaluated from 3D high resolution images. Results show that carbonate rocks has a complex pore space system with different pores types at the same facies. Copyright © 2011 Elsevier Ltd. All rights reserved.

ONKALO rock mechanics model (RMM) - Version 2.0

International Nuclear Information System (INIS)

Moenkkoenen, H.; Hakala, M.; Paananen, M.; Laine, E.

2012-02-01

The Rock Mechanics Model of the ONKALO rock volume is a description of the significant features and parameters related to rock mechanics. The main objective is to develop a tool to predict the rock properties, quality and hence the potential for stress failure which can then be used for continuing design of the ONKALO and the repository. This is the second implementation of the Rock Mechanics Model and it includes sub-models of the intact rock strength, in situ stress, thermal properties, rock mass quality and properties of the brittle deformation zones. Because of the varying quantities of available data for the different parameters, the types of presentations also vary: some data sets can be presented in the style of a 3D block model but, in other cases, a single distribution represents the whole rock volume hosting the ONKALO. (orig.)

Geochemical modelling of worst-case leakage scenarios at potential CO2-storage sites - CO2 and saline water contamination of drinking water aquifers

Science.gov (United States)

Szabó, Zsuzsanna; Edit Gál, Nóra; Kun, Éva; Szőcs, Teodóra; Falus, György

2017-04-01

Carbon Capture and Storage is a transitional technology to reduce greenhouse gas emissions and to mitigate climate change. Following the implementation and enforcement of the 2009/31/EC Directive in the Hungarian legislation, the Geological and Geophysical Institute of Hungary is required to evaluate the potential CO2 geological storage structures of the country. Basic assessment of these saline water formations has been already performed and the present goal is to extend the studies to the whole of the storage complex and consider the protection of fresh water aquifers of the neighbouring area even in unlikely scenarios when CO2 injection has a much more regional effect than planned. In this work, worst-case scenarios are modelled to understand the effects of CO2 or saline water leaks into drinking water aquifers. The dissolution of CO2 may significantly change the pH of fresh water which induces mineral dissolution and precipitation in the aquifer and therefore, changes in solution composition and even rock porosity. Mobilization of heavy metals may also be of concern. Brine migration from CO2 reservoir and replacement of fresh water in the shallower aquifer may happen due to pressure increase as a consequence of CO2 injection. The saline water causes changes in solution composition which may also induce mineral reactions. The modelling of the above scenarios has happened at several methodological levels such as equilibrium batch, kinetic batch and kinetic reactive transport simulations. All of these have been performed by PHREEQC using the PHREEQC.DAT thermodynamic database. Kinetic models use equations and kinetic rate parameters from the USGS report of Palandri and Kharaka (2004). Reactive transport modelling also considers estimated fluid flow and dispersivity of the studied formation. Further input parameters are the rock and the original ground water compositions of the aquifers and a range of gas-phase CO2 or brine replacement ratios. Worst-case scenarios

Combined interpretation of radar, hydraulic, and tracer data from a fractured-rock aquifer near Mirror Lake, New Hampshire, USA

Science.gov (United States)

Day-Lewis, F. D.; Lane, J.W.; Gorelick, S.M.

2006-01-01

An integrated interpretation of field experimental cross-hole radar, tracer, and hydraulic data demonstrates the value of combining time-lapse geophysical monitoring with conventional hydrologic measurements for improved characterization of a fractured-rock aquifer. Time-lapse difference-attenuation radar tomography was conducted during saline tracer experiments at the US Geological Survey Fractured Rock Hydrology Research Site near Mirror Lake, Grafton County, New Hampshire, USA. The presence of electrically conductive saline tracer effectively illuminates permeable fractures or pathways for geophysical imaging. The geophysical results guide the construction of three-dimensional numerical models of ground-water flow and solute transport. In an effort to explore alternative explanations for the tracer and tomographic data, a suite of conceptual models involving heterogeneous hydraulic conductivity fields and rate-limited mass transfer are considered. Calibration data include tracer concentrations, the arrival time of peak concentration at the outlet, and steady-state hydraulic head. Results from the coupled inversion procedure suggest that much of the tracer mass migrated outside the three tomographic image planes, and that solute is likely transported by two pathways through the system. This work provides basic and site-specific insights into the control of permeability heterogeneity on ground-water flow and solute transport in fractured rock. ?? Springer-Verlag 2004.

Estimates of matter yield and N-uptake in sorghum grown on saline and non-saline soils manured with dhaincha (sesbania aculeata) plant residues utilizing 15N tracer techniques

International Nuclear Information System (INIS)

Kurdali, F.

2002-11-01

Pot experiments were conducted to study the effect of manuring with three types of plant residues (roots, shoots or roots plus shoots) of Dhaincha (Sesbania aculeata Pers.) on the yield and N-uptake of Sorghum bicolor grown in saline and non-saline soils. For measuring various sources of N-uptake, two isotopic dilution techniques were utilized by adding to these soils either 15 N-labelled inorganic N-fertilizer (indirect method) or 15 N-labelled sesbania leaves (direct method). For the indirect method, both soils manured with each type of sesbania residue, received four split applications of 15 N-labelled ammonium sulphate. Results indicated that each type of sesbania residue, applied as a green manure, resulted in significant increases in both dry matter yield and N-uptake of sorghum as compared with the un manured control. Moreover, sesbania residues decreased the harmful effect of salinity on plant growth. Percentages of N derived from residues (%Ndfr) in sorghum grown in non saline soil ranged between 3.9 and 33%; whereas, in saline soil, the observed values ranged between 4.9 and 19.8%. N recoveries in sorghum grown in non saline soil were 61, 45 and 37% of the total amount contained in the sesbania root, shoot and root plus shoot; whereas, values in sorghum grown in saline soils were 48, 14,8 and 15.7%, respectively. The beneficial effects of sesbania residues have been attributed not only to the additional N availability to the plants, but also to its effects on the enhancement of soil N uptake. Percentages and amounts of Ndfr calculated using the indirect method were not significantly different from those obtained by the direct method indicating that the indirect method used herein is feasible and simple for measuring N release from organic residues. It is suggested that the use of Sesbania aculeata residues, particularly the shoots, as a green manure, can provide a substantial portion of total N in sorghum. Moreover, the use of sesbania green manure in

On the K-Ar ages of the rocks of two kinds existed in the Kamuikotan metamorphic rocks located in the Horokanai district, Hokkaido

International Nuclear Information System (INIS)

Imaizumi, Masayuki; Ueda, Yoshio.

1981-01-01

In the Fransiscan metamorphic rocks known as the typical high-pressure type metamorphic belts, existence of the blocks of high grade metamorphic rocks of older age in the widely distributed low grade ones of younger age is commonly noticed. This feature has been explained as a phenomenon that the blocks had been tectonically mixed with the surroundings - so-called tectonic blocks - based on the absolute age determination of the component minerals. The Kamuikotan tectonic belt is a melange zone in which occur various kinds of metamorphic rocks of high-pressure and low-pressure types. The high-pressure Kamuikotan metamorphic rocks can be classified into two kinds based upon the modes of occurrence and mineral paragenesis. One is the low grade metamorphic rocks of greenschist and glaucophane schist and the other, the high grade metamorphic rocks of epidote glaucophane schist and epidote amphibolite. The high grade metamorphic rocks always occur as isolated blocks in the low grade metamorphics and associated serpentinite. The report discusses the age of muscovites separated from the two types of high-pressure Kamuikotan metamorphic rocks in the Horokanai district, central Hokkaido. The muscovites separated from the low grade metamorphics of the district give the age of 72 - 116 m.y., while those separated from the high grade metamorphics give the age of 132 - 145 m.y. These ages seem to agree with the idea that the blocks of high grade metamorphics (epidote glaucophane schist and epidote amphibolite) would be the ''tectonic blocks'' - namely the fragments tectonically mixed into the low grade metamorphics of younger age. (author)

Cell type-specific responses to salinity - the epidermal bladder cell transcriptome of Mesembryanthemum crystallinum.

Science.gov (United States)

Oh, Dong-Ha; Barkla, Bronwyn J; Vera-Estrella, Rosario; Pantoja, Omar; Lee, Sang-Yeol; Bohnert, Hans J; Dassanayake, Maheshi

2015-08-01

Mesembryanthemum crystallinum (ice plant) exhibits extreme tolerance to salt. Epidermal bladder cells (EBCs), developing on the surface of aerial tissues and specialized in sodium sequestration and other protective functions, are critical for the plant's stress adaptation. We present the first transcriptome analysis of EBCs isolated from intact plants, to investigate cell type-specific responses during plant salt adaptation. We developed a de novo assembled, nonredundant EBC reference transcriptome. Using RNAseq, we compared the expression patterns of the EBC-specific transcriptome between control and salt-treated plants. The EBC reference transcriptome consists of 37 341 transcript-contigs, of which 7% showed significantly different expression between salt-treated and control samples. We identified significant changes in ion transport, metabolism related to energy generation and osmolyte accumulation, stress signalling, and organelle functions, as well as a number of lineage-specific genes of unknown function, in response to salt treatment. The salinity-induced EBC transcriptome includes active transcript clusters, refuting the view of EBCs as passive storage compartments in the whole-plant stress response. EBC transcriptomes, differing from those of whole plants or leaf tissue, exemplify the importance of cell type-specific resolution in understanding stress adaptive mechanisms. No claim to original US government works. New Phytologist © 2015 New Phytologist Trust.

Effect of salinity on cell growth and β-carotene production in ...

African Journals Online (AJOL)

Urmia Lake, the second largest hyper-saline lake by area in the world, has fluctuated in salinity over time, but recently, it has reached a maximum of 360 g/l. Dunaliella is a type of halophile green-orange microalgae especially found in lake and salty fields and is known for its antioxidant activity; because of its ability to create ...

Strength and Permeability Evolution of Compressed Bentonite in Response to Salinity and Temperature Changes

Science.gov (United States)

Winnard, B. R.; Mitchell, T. M.; Browning, J.; Cuss, R. J.; Norris, S.; Meredith, P. G.

2017-12-01

Deep geological repositories are the preferred solution to dispose of radioactive waste; design concepts for these disposal facilities include compacted, saturated bentonite as a buffer between waste canister and host rock. Bentonite is favoured for its high swelling capacity, low permeability, and radionuclide retention properties. However, its thermo-hydro-mechanical tolerances must be thoroughly tested to ensure adequate long term performance. Climate variations are likely to induce periods of permafrost, and consequently, changes in groundwater salinity at depth. We performed laboratory experiments investigating effects of temperature and salinity change on uniaxial compressive strength (UCS), and permeability of compacted MX-80 bentonite cylinders. These specimens (moisture content = 22.9±0.1%, dry density = 1.66±0.02 g.cm-3) were compacted with deionised water, and a range of wt% NaCl, CaCl2, or KCl, to compare the effects of compaction fluid. Samples of compressed bentonite were cooled to -20 °C, and heated to 90 ºC, a possible temperature forecast for a repository dependent on factors such as geographical location, waste type, and facility design. Tests were all performed at room temperature, however in situ temperature tests are planned. The UCS of samples that experienced freeze thaw, and 40 ºC treatment failed at 6.5 MPa, with 4% strain, maintaining the same values as untreated bentonite compacted with deionised water. Samples compacted with saline solutions also yielded similar strengths, of 7 MPa, and failed at 4%. However, the 90 ºC, regardless of compaction fluid, failed at 15-18 MPa, at just 2% strain. In all experiments, the spread of strain accommodated varied inconsistently, however, peak stress was uniform. Further experiments into heterogeneity are needed to understand the responsible mechanisms. To obtain permeability, we utilised the pore pressure oscillation (PPO) technique with argon as the pore fluid. We also tested water as the pore

Growth and root development of four mangrove seedlings under varying salinity

Science.gov (United States)

Basyuni, M.; Keliat, D. A.; Lubis, M. U.; Manalu, N. B.; Syuhada, A.; Wati, R.; Yunasfi

2018-03-01

This present study describes four mangrove seedlings namely Bruguiera cylindrica, B. sexangula, Ceriops tagal, and Rhizophora apiculata in response to salinity with particular emphasis to root development. The seedlings of four mangroves were grown for 5 months in 0%, 0.5%, 1.5%, 2.0% and 3.0% salt concentration. Salinity significantly decreased the growth (diameter and plant height) of all mangrove seedlings. Root developments were observed from the tap and lateral root. The number, length and diameter of both roots-typed of B. cylindrica, B. sexangula and C. tagal seedlings significantly decreased with increasing salt concentration with optimum development at 0.5% salinity. By contrast, the number, length, and diameter of tap root of R. apiculata seedlings were significantly enhanced by salt with maximal stimulation at 0.5%, and this increase was attenuated by increasing salinity. On the other hand, lateral root development of R. apiculata significantly thrived up to 1.5% salinity then decreasing with the increasing salinity. The different response of root development suggested valuable information for mangrove rehabilitation in North Sumatra and their adaption to withstand salt stress.

Classification and Distribution of Mars Pathfinder Rocks Using Quantitative Morphologic Indices

Science.gov (United States)

Yingst, R. A.; Biederman, K. L.; Monhead, A. M.; Haldemann, A. F. C.; Kowalczyk, M. R.

2004-01-01

The Mars Pathfinder (MPF) landing site was predicted to contain a broad sampling of rock types varying in mineralogical, physical, mechanical and geochemical characteristics. Although rocks have been divided into several spectral categories based on Imager for Mars Pathfinder visible/near-infrared spectra, it has not been fully determined which of these stem from intrinsic mineralogical differences between rocks or rock surfaces, and which result from factors such as physical or chemical weathering. This has made isolation of unique mineralogy's difficult. Efforts in isolating and classifying spectral units among MPF rocks and soils have met with varying degrees of success, and the current understanding is such that many factors influencing spectral signatures cannot be quantified to a sufficient level so they may be removed. The result is that fundamental questions regarding information needed to reveal the present and past interactions between the rocks and rock surfaces and the Martian environment remain unanswered. But it is possible to approach the issue of identifying distinct rock and rock surface types from a different angle.

Effect of Hydrothermal Alteration on Rock Properties in Active Geothermal Setting

Science.gov (United States)

Mikisek, P.; Bignall, G.; Sepulveda, F.; Sass, I.

2012-04-01

Hydrothermal alteration records the physical-chemical changes of rock and mineral phases caused by the interaction of hot fluids and wall rock, which can impact effective permeability, porosity, thermal parameters, rock strength and other rock properties. In this project, an experimental approach has been used to investigate the effects of hydrothermal alteration on rock properties. A rock property database of contrastingly altered rock types and intensities has been established. The database details horizontal and vertical permeability, porosity, density, thermal conductivity and thermal heat capacity for ~300 drill core samples from wells THM12, THM13, THM14, THM17, THM18, THM22 and TH18 in the Wairakei-Tauhara geothermal system (New Zealand), which has been compared with observed hydrothermal alteration type, rank and intensity obtained from XRD analysis and optical microscopy. Samples were selected from clay-altered tuff and intercalated siltstones of the Huka Falls Formation, which acts as a cap rock at Wairakei-Tauhara, and tuffaceous sandstones of the Waiora Formation, which is a primary reservoir-hosting unit for lateral and vertical fluid flows in the geothermal system. The Huka Falls Formation exhibits argillic-type alteration of varying intensity, while underlying Waiora Formations exhibits argillic- and propylithic-type alteration. We plan to use a tempered triaxial test cell at hydrothermal temperatures (up to 200°C) and pressures typical of geothermal conditions, to simulate hot (thermal) fluid percolation through the rock matrix of an inferred "reservoir". Compressibility data will be obtained under a range of operating (simulation reservoir) conditions, in a series of multiple week to month-long experiments that will monitor change in permeability and rock strength accompanying advancing hydrothermal alteration intensity caused by the hot brine interacting with the rock matrix. We suggest, our work will provide new baseline information concerning

Toxicity of antifouling biocides to the intertidal harpacticoid copepod Tigriopus japonicus (Crustacea, Copepoda): Effects of temperature and salinity

International Nuclear Information System (INIS)

Kwok, K.W.H.; Leung, K.M.Y.

2005-01-01

Intertidal harpacticoid copepods are commonly used in eco-toxicity tests worldwide. They predominately live in mid-high shore rock pools and often experience a wide range of temperature and salinity fluctuation. Most eco-toxicity tests are conducted at fixed temperature and salinity and thus the influence of these environmental factors on chemical toxicity is largely unknown. This study investigated the combined effect of temperature and salinity on the acute toxicity of the copepod Tigriopus japonicus against two common biocides, copper (Cu) and tributyltin (TBT) using a 2 x 3 x 4 factorial design (i.e. two temperatures: 25 and 35 o C; three salinities: 15.0 per mille , 34.5 per mille and 45.0 per mille ; three levels of the biocide plus a control). Copper sulphate and tributyltin chloride were used as the test chemicals while distilled water and acetone were utilised as solvents for Cu and TBT respectively. 96h-LC50s of Cu and TBT were 1024 and 0.149 μg l -1 respectively (at 25 o C; 34.5 per mille ) and, based on these results, nominal biocide concentrations of LC0 (i.e. control), LC30, LC50 and LC70 were employed. Analysis of Covariance using 'concentration' as the covariate and both 'temperature' and 'salinity' as fixed factors, showed a significant interaction between temperature and salinity effects for Cu, mortality increasing with temperature but decreasing with elevated salinity. A similar result was revealed for TBT. Both temperature and salinity are, therefore, important factors affecting the results of acute eco-toxicity tests using these marine copepods. We recommend that such eco-toxicity tests should be conducted at a range of environmentally realistic temperature/salinity regimes, as this will enhance the sensitivity of the test and improve the safety margin in line with the precautionary principle

Toxicity of antifouling biocides to the intertidal harpacticoid copepod Tigriopus japonicus (Crustacea, Copepoda): Effects of temperature and salinity

Energy Technology Data Exchange (ETDEWEB)

Kwok, K.W.H. [Swire Institute of Marine Science, Department of Ecology and Biodiversity, University of Hong Kong, Pokfulam, Hong Kong (China); Leung, K.M.Y. [Swire Institute of Marine Science, Department of Ecology and Biodiversity, University of Hong Kong, Pokfulam, Hong Kong (China)]. E-mail: kmyleung@hkucc.hku.hk

2005-07-01

Intertidal harpacticoid copepods are commonly used in eco-toxicity tests worldwide. They predominately live in mid-high shore rock pools and often experience a wide range of temperature and salinity fluctuation. Most eco-toxicity tests are conducted at fixed temperature and salinity and thus the influence of these environmental factors on chemical toxicity is largely unknown. This study investigated the combined effect of temperature and salinity on the acute toxicity of the copepod Tigriopus japonicus against two common biocides, copper (Cu) and tributyltin (TBT) using a 2 x 3 x 4 factorial design (i.e. two temperatures: 25 and 35 {sup o}C; three salinities: 15.0 per mille , 34.5 per mille and 45.0 per mille ; three levels of the biocide plus a control). Copper sulphate and tributyltin chloride were used as the test chemicals while distilled water and acetone were utilised as solvents for Cu and TBT respectively. 96h-LC50s of Cu and TBT were 1024 and 0.149 {mu}g l{sup -1} respectively (at 25 {sup o}C; 34.5 per mille ) and, based on these results, nominal biocide concentrations of LC0 (i.e. control), LC30, LC50 and LC70 were employed. Analysis of Covariance using 'concentration' as the covariate and both 'temperature' and 'salinity' as fixed factors, showed a significant interaction between temperature and salinity effects for Cu, mortality increasing with temperature but decreasing with elevated salinity. A similar result was revealed for TBT. Both temperature and salinity are, therefore, important factors affecting the results of acute eco-toxicity tests using these marine copepods. We recommend that such eco-toxicity tests should be conducted at a range of environmentally realistic temperature/salinity regimes, as this will enhance the sensitivity of the test and improve the safety margin in line with the precautionary principle.

Review of geoscientific data of relevance to disposal of spent nuclear fuel in deep boreholes in crystalline rock

International Nuclear Information System (INIS)

Marsic, Nico; Grundfelt, Bertil

2013-09-01

from the hole at Outokumpu is there information under all headings. A general conclusion is that data available from deep boreholes demonstrate that there are conductive fractures also at depth. However, the hydrogeochemistry and isotope data suggest that the water in these fractures has been isolated from surface processes for a very long time. Despite this, it appears that the origin of these deep groundwaters is ancient meteoric water rather than fluid inclusions. The deep waters are generally saline, but the salinity varies in a non-regular fashion. Thus, the present study confirm the conceptual picture from the previous studies that the saline groundwater found below a halocline located at 1-2 kilometres depth in flat areas with crystalline rock is virtually stagnant. The results from the Outokumpu hole seem to more clearly explain the origin of the salinity in the deep groundwater than the earlier studies

Review of geoscientific data of relevance to disposal of spent nuclear fuel in deep boreholes in crystalline rock

Energy Technology Data Exchange (ETDEWEB)

Marsic, Nico; Grundfelt, Bertil [Kemakta Konsult AB, Stockholm (Sweden)

2013-09-15

from the hole at Outokumpu is there information under all headings. A general conclusion is that data available from deep boreholes demonstrate that there are conductive fractures also at depth. However, the hydrogeochemistry and isotope data suggest that the water in these fractures has been isolated from surface processes for a very long time. Despite this, it appears that the origin of these deep groundwaters is ancient meteoric water rather than fluid inclusions. The deep waters are generally saline, but the salinity varies in a non-regular fashion. Thus, the present study confirm the conceptual picture from the previous studies that the saline groundwater found below a halocline located at 1-2 kilometres depth in flat areas with crystalline rock is virtually stagnant. The results from the Outokumpu hole seem to more clearly explain the origin of the salinity in the deep groundwater than the earlier studies.

Respirable dust measured downwind during rock dust application.

Science.gov (United States)

Harris, M L; Organiscak, J; Klima, S; Perera, I E

2017-05-01

The Pittsburgh Mining Research Division of the U.S. National Institute for Occupational Safety and Health (NIOSH) conducted underground evaluations in an attempt to quantify respirable rock dust generation when using untreated rock dust and rock dust treated with an anticaking additive. Using personal dust monitors, these evaluations measured respirable rock dust levels arising from a flinger-type application of rock dust on rib and roof surfaces. Rock dust with a majority of the respirable component removed was also applied in NIOSH's Bruceton Experimental Mine using a bantam duster. The respirable dust measurements obtained downwind from both of these tests are presented and discussed. This testing did not measure miners' exposure to respirable coal mine dust under acceptable mining practices, but indicates the need for effective continuous administrative controls to be exercised when rock dusting to minimize the measured amount of rock dust in the sampling device.

Natural radioactivity of the rocks from the Moon and planets

Energy Technology Data Exchange (ETDEWEB)

Surkov, Yu.A. (AN SSSR, Moscow. Inst. Geokhimii i Analiticheskoj Khimii)

1982-01-01

Tha data on natural radioactivity of rocks (U, Th and K contents) from the Moon, Venus and Mars obtained by means of cosmic means are analyzed. The Moon rock radioactivity has been measured in situ (from orbital vehicles) as well as in the samples of lunar material delivered to the Earth and as for Venus and Mars rocks - by landing vehicles. It has been found that the main specific feature of the Moon and the Earth group planets is the presence of two geomorphological types of the structure of their surface composed by two different types of the matter. The ancient continent regions are made up by feldspar rock - gabbroanorthosite at the Moon (and possibly at the Mars) and granite-metamorphic at the Earth (and possibly at the Venus). The younger ''marine'' regions are composed by basalt rock. The presence at the Moon of two types of crust (marine and continental ones) having a different nature is clearly reflected on the Moon radioactivity map where marine regions (15% of the total surface) which have high radioactivity and continental regions with a relatively low radioactivity can be seen. The discovery of rocks on the Venus surface highly enriched by U, Th and K speaks of their melting from the primary matter in the depth of the Earth. The Marsian rock by the natural radioelement content is close to igneous rocks of the Earth crust of the basic composition and lunar marine basalts.

Natural radioactivity of the rocks from the Moon and planets

International Nuclear Information System (INIS)

Surkov, Yu.A.

1982-01-01

Tha data on natural radioactivity of rocks (U, Th and K contents) from the Moon, Venus and Mars obtained by means of cosmic means are analyzed. The Moon rock radioactivity has been measured in situ (from orbital vehicles) as well as in the samples of lunar material delivered to the Earth and as for Venus and Mars rocks - by landing vehicles. It has been found that the main specific feature of the Moon and the Earth group planets is the presence of two geomorphological types of the structure of their surface composed by two different types of the matter. The ancient contineent regions are made up by feldspar rock - gabbroanorthosite at the Moon (and possibly at the Mars) and granite-metamorphic at the Earth (and possibly at the Venus). The younger ''marine'' regions are composed by basalt rock. The presence at the Moon of two types of crust (marine and continental ones) having a different nature is clearly reflected on the Moon radioactivity map where marine regions (15% of the total surface) which have high radioactivity and continental regions with a relatively low radioactivity can be seen. The discovery of rocks on the Venus surface highly enriched by U, Th and K speaks of their melting from the primary matter in the depth of the Earth. The Marsian rock by the natural radioelement content is close to igneous rocks of the Earth crust of the basic composition and lunar marine basalts

Microstructural controls on the macroscopic behavior of geo-architected rock samples

Science.gov (United States)

Mitchell, C. A.; Pyrak-Nolte, L. J.

2017-12-01

Reservoir caprocks, are known to span a range of mechanical behavior from elastic granitic units to visco-elastic shale units. Whether a rock will behave elastically, visco-elastically or plastically depends on both the compositional and textural or microsctructural components of the rock, and how these components are spatially distributed. In this study, geo-architected caprock fabrication was performed to develop synthetic rock to study the role of rock rheology on fracture deformations, fluid flow and geochemical alterations. Samples were geo-architected with Portland Type II cement, Ottawa sand, and different clays (kaolinite, illite, and Montmorillonite). The relative percentages of these mineral components are manipulated to generate different rock types. With set protocols, the mineralogical content, texture, and certain structural aspects of the rock were controlled. These protocols ensure that identical samples with the same morphological and mechanical characteristics are constructed, thus overcoming issues that may arise in the presence of heterogeneity and high anisotropy from natural rock samples. Several types of homogeneous geo-architected rock samples were created, and in some cases the methods were varied to manipulate the physical parameters of the rocks. Characterization of rocks that the samples exhibit good repeatability. Rocks with the same mineralogical content generally yielded similar compressional and shear wave velocities, UCS and densities. Geo-architected rocks with 10% clay in the matrix had lower moisture content and effective porosities than rocks with no clay. The process by which clay is added to the matrix can strongly affect the resulting compressive strength and physical properties of the geo-architected sample. Acknowledgment: This material is based upon work supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Geosciences Research Program under Award Number (DE-FG02-09ER16022).

Metamorphic Rock-Hosted Orogenic Gold Deposit Type as a Source of Langkowala Placer Gold, Bombana, Southeast Sulawesi

Directory of Open Access Journals (Sweden)

Arifudin Idrus

2014-06-01

Full Text Available DOI: 10.17014/ijog.v6i1.114In 2008, placer gold was discovered in Langkowala area (Bombana Regency, Southeast Sulawesi, Indonesia, and more than 60,000 traditional gold miners in the early 2009 have been operating by digging vertical pits and panning active stream sediments. The grade of placer gold ranges from 50 to 140 g/t. Local geological framework indicates that the placer gold is not related to volcanic rock-related hydrothermal gold deposit, e.g. epithermal, skarn or porphyry. This paper describes a preliminary study on possible primary deposit type as a source of the Langkowala (Bombana secondary placer gold. A field study indicates that the Langkowala (Bombana placer/paleoplacer gold is possibly related to gold-bearing quartz veins/veinlets hosted by metamorphic rocks particularly mica schist and metasediments in the area. These quartz veins/veinlets are currently recognized in metamorphic rocks at Wumbubangka Mountains, a northern flank of Rumbia Mountain Range. Sheared, segmented quartz veins/veinlets are of 2 cm to 2 m in width and contain gold in a grade varying between 2 and 61 g/t. At least, there are two generations of the quartz veins. The first generation of quartz vein is parallel to foliation of mica schist and metasediments with general orientation of N 300oE/60o; the second quartz vein generation crosscut the first quartz vein and the foliation of the wallrock. The first quartz veins are mostly sheared/deformed, brecciated, and occasionally sigmoidal, whereas the second quartz veins are relatively massive. The similar quartz veins/veinlets types are also probably present in Mendoke Mountain Range, in the northern side of Langkowala area. This primary gold deposit is called as ‘orogenic gold type’. The orogenic gold deposit could be a new target of gold exploration in Indonesia in the future.

Characterization of mechanisms and processes of groundwater salinization in irrigated coastal area using statistics, GIS, and hydrogeochemical investigations.

Science.gov (United States)

Bouzourra, Hazar; Bouhlila, Rachida; Elango, L; Slama, Fairouz; Ouslati, Naceur

2015-02-01

Coastal aquifers are at threat of salinization in most parts of the world. This study was carried out in coastal shallow aquifers of Aousja-Ghar El Melh and Kalâat el Andalous, northeastern of Tunisia with an objective to identify sources and processes of groundwater salinization. Groundwater samples were collected from 42 shallow dug wells during July and September 2007. Chemical parameters such as Na(+), Ca(2+), Mg(2+), K(+), Cl(-), SO4 (2-), HCO3 (-), NO3 (-), Br(-), and F(-) were analyzed. The combination of hydrogeochemical, statistical, and GIS approaches was used to understand and to identify the main sources of salinization and contamination of these shallow coastal aquifers as follows: (i) water-rock interaction, (ii) evapotranspiration, (iii) saltwater is started to intrude before 1972 and it is still intruding continuously, (iv) irrigation return flow, (v) sea aerosol spray, and finally, (vi) agricultural fertilizers. During 2005/2006, the overexploitation of the renewable water resources of aquifers caused saline water intrusion. In 2007, the freshening of a brackish-saline groundwater occurred under natural recharge conditions by Ca-HCO3 meteoric freshwater. The cationic exchange processes are occurred at fresh-saline interfaces of mixtures along the hydraulic gradient. The sulfate reduction process and the neo-formation of clays minerals characterize the hypersaline coastal Sebkha environments. Evaporation tends to increase the concentrations of solutes in groundwater from the recharge areas to the discharge areas and leads to precipitate carbonate and sulfate minerals.

Geochemistry of silicate-rich rocks can curtail spreading of carbon dioxide in subsurface aquifers.

Science.gov (United States)

Cardoso, S S S; Andres, J T H

2014-12-11

Pools of carbon dioxide are found in natural geological accumulations and in engineered storage in saline aquifers. It has been thought that once this CO2 dissolves in the formation water, making it denser, convection streams will transport it efficiently to depth, but this may not be so. Here, we assess theoretically and experimentally the impact of natural chemical reactions between the dissolved CO2 and the rock formation on the convection streams in the subsurface. We show that, while in carbonate rocks the streaming of dissolved carbon dioxide persists, the chemical interactions in silicate-rich rocks may curb this transport drastically and even inhibit it altogether. These results challenge our view of carbon sequestration and dissolution rates in the subsurface, suggesting that pooled carbon dioxide may remain in the shallower regions of the formation for hundreds to thousands of years. The deeper regions of the reservoir can remain virtually carbon free.

Modeling rock specimens through 3D printing: Tentative experiments and prospects

Science.gov (United States)

Jiang, Quan; Feng, Xiating; Song, Lvbo; Gong, Yahua; Zheng, Hong; Cui, Jie

2016-02-01

Current developments in 3D printing (3DP) technology provide the opportunity to produce rock-like specimens and geotechnical models through additive manufacturing, that is, from a file viewed with a computer to a real object. This study investigated the serviceability of 3DP products as substitutes for rock specimens and rock-type materials in experimental analysis of deformation and failure in the laboratory. These experiments were performed on two types of materials as follows: (1) compressive experiments on printed sand-powder specimens in different shapes and structures, including intact cylinders, cylinders with small holes, and cuboids with pre-existing cracks, and (2) compressive and shearing experiments on printed polylactic acid cylinders and molded shearing blocks. These tentative tests for 3DP technology have exposed its advantages in producing complicated specimens with special external forms and internal structures, the mechanical similarity of its product to rock-type material in terms of deformation and failure, and its precision in mapping shapes from the original body to the trial sample (such as a natural rock joint). These experiments and analyses also successfully demonstrate the potential and prospects of 3DP technology to assist in the deformation and failure analysis of rock-type materials, as well as in the simulation of similar material modeling experiments.

Rock excavation by pulsed electron beams

International Nuclear Information System (INIS)

Avery, R.T.; Keefe, D.; Brekke, T.L.; Finnie, I.

1976-03-01

If an intense short pulse of megavolt electrons is deposited in a brittle solid, dynamic spalling can be made to occur with removal of material. Experiments were made on several types of hard rock; results are reproducible and well-described theoretically. An accelerator with a rapidly-pulsed scanning electron beam was designed that could tunnel in hard rock about ten times faster than conventional drill/blast methods

Uranium in alkaline rocks

Energy Technology Data Exchange (ETDEWEB)

Murphy, M.; Wollenberg, H.; Strisower, B.; Bowman, H.; Flexser, S.; Carmichael, I.

1978-04-01

Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential.

Uranium in alkaline rocks

International Nuclear Information System (INIS)

Murphy, M.; Wollenberg, H.; Strisower, B.; Bowman, H.; Flexser, S.; Carmichael, I.

1978-04-01

Geologic and geochemical criteria were developed for the occurrence of economic uranium deposits in alkaline igneous rocks. A literature search, a limited chemical analytical program, and visits to three prominent alkaline-rock localities (Ilimaussaq, Greenland; Pocos de Caldas, Brazil; and Powderhorn, Colorado) were made to establish criteria to determine if a site had some uranium resource potential. From the literature, four alkaline-intrusive occurrences of differing character were identified as type-localities for uranium mineralization, and the important aspects of these localities were described. These characteristics were used to categorize and evaluate U.S. occurrences. The literature search disclosed 69 U.S. sites, encompassing nepheline syenite, alkaline granite, and carbonatite. It was possible to compare two-thirds of these sites to the type localities. A ranking system identified ten of the sites as most likely to have uranium resource potential

Multiparameter Monitoring and Prevention of Fault-Slip Rock Burst

OpenAIRE

Hu, Shan-chao; Tan, Yun-liang; Ning, Jian-guo; Guo, Wei-Yao; Liu, Xue-sheng

2017-01-01

Fault-slip rock burst is one type of the tectonic rock burst during mining. A detailed understanding of the precursory information of fault-slip rock burst and implementation of monitoring and early warning systems, as well as pressure relief measures, are essential to safety production in deep mines. This paper first establishes a mechanical model of stick-slip instability in fault-slip rock bursts and then reveals the failure characteristics of the instability. Then, change rule of mining-i...

Salinity-Dependent Contact Angle Alteration in Oil/Brine/Silicate Systems: the Critical Role of Divalent Cations

OpenAIRE

Haagh, Martinus Everardus Johannes; Sîretanu, Igor; Duits, Michel; Mugele, Friedrich Gunther

2017-01-01

The effectiveness of water flooding oil recovery depends to an important extent on the competitive wetting of oil and water on the solid rock matrix. Here, we use macroscopic contact angle goniometry in highly idealized model systems to evaluate how brine salinity affects the balance of wetting forces and to infer the microscopic origin of the resultant contact angle alteration. We focus, in particular, on two competing mechanisms debated in the literature, namely, double-layer expansion and ...

Tales from the tomb: the microbial ecology of exposed rock surfaces.

Science.gov (United States)

Brewer, Tess E; Fierer, Noah

2018-03-01

Although a broad diversity of eukaryotic and bacterial taxa reside on rock surfaces where they can influence the weathering of rocks and minerals, these communities and their contributions to mineral weathering remain poorly resolved. To build a more comprehensive understanding of the diversity, ecology and potential functional attributes of microbial communities living on rock, we sampled 149 tombstones across three continents and analysed their bacterial and eukaryotic communities via marker gene and shotgun metagenomic sequencing. We found that geographic location and climate were important factors structuring the composition of these communities. Moreover, the tombstone-associated microbial communities varied as a function of rock type, with granite and limestone tombstones from the same cemeteries harbouring taxonomically distinct microbial communities. The granite and limestone-associated communities also had distinct functional attributes, with granite-associated bacteria having more genes linked to acid tolerance and chemotaxis, while bacteria on limestone were more likely to be lichen associated and have genes involved in photosynthesis and radiation resistance. Together these results indicate that rock-dwelling microbes exhibit adaptations to survive the stresses of the rock surface, differ based on location, climate and rock type, and seem pre-disposed to different ecological strategies (symbiotic versus free-living lifestyles) depending on the rock type. © 2017 Society for Applied Microbiology and John Wiley & Sons Ltd.

Geochemical investigation of petroleum source rocks by using Rock- Eval data in the Agha-Jari oilfield

Directory of Open Access Journals (Sweden)

Behzad khani

2015-01-01

Full Text Available In this study, 40 drilling cutting of the Pabdeh, Gurpi, kazhdumi and Gadvan Formations from the Agha-Jari Oilfield were analyzed by using Rock-Eval pyrolysis. In order to recognizing sedimentary environmental conditions of studied Formations, they are divided to 4 zones which A (Kazhdumi Formation#187 and C (Kazhdumi Formation#140 zones show reduction conditions by presence of sea organic materials and B (Gadvan Formation #140 and D(Gadvan Formation#187 zones show oxidation conditions by presence of continental organic materials to basin. Based on the Rock-Eval pyrolysis data, the Pabeh, Gurpi, Kazhdumi and Gadvan Formations have variable hydrocarbon generative potential. HI vs. OI plot revealed that the kerogen type in this Formations is a mixed of types II & III. The intensity of matrix effect in the Pabdeh, Gurpi, Kazhdumi and Gadvan Formations was compared by using S2 vs. TOC plot and calculating its regression equation. The results show that the significant amount of S2 adsorption by matrix was happened in the Pabdeh (4.98-6.96 mg HC/gr rock in wells 113 and 121 and Gurpi Formations ‌(4.33 mg HC/gr rock in well 113 which is due to their low thermal maturity‌(Tmax

Physiology response of fourth generation saline resistant soybean (Glycine max (L.) Merrill) with application of several types of antioxidants

Science.gov (United States)

Manurung, I. R.; Rosmayati; Rahmawati, N.

2018-02-01

Antioxidant applications are expected to reduce the adverse effects of soil saline. This research was conducted in plastic house, Plant Tissue Laboratory Faculty of Agriculture and Plant Physiology Laboratory Faculty of Mathematic and Natural Science, Universitas Sumatera Utara, Medan also in Research Centers and Industry Standardization, Medan from July-December 2016. The objective of the research was to know the effect of various antioxidant treatments with different concentrations (control, ascorbic acid 250, 500 and 750 ppm; salicylic acid 250, 500 and 750 ppm; α-tocopherol 250, 500 and 750 ppm) on fourth generation soybean physiology in saline condition (Electric Conductivity 5-6 dS/m). The results of this research showed that the antioxidant type and concentration affected not significantly to physiology of fourth generation soybean. Descriptively the highest average of superoxide dismutase and peroxide dismutase was showed on ascorbic acid 250 ppm. The highest average of ascorbate peroxidase was showed on α-tocopherol 750 ppm. The highest average of carotenoid content was showed on ascorbic acid 500 ppm. The highest average of chlorophyll content was showed on α-tocopherol 250 ppm. The highest average of ratio of K/Na was showed on salicylic acid 250 ppm.

Aquifer composition and the tendency toward scale-deposit formation during reverse osmosis desalination - Examples from saline ground water in New Mexico, USA

Science.gov (United States)

Huff, G.F.

2006-01-01

Desalination is expected to make a substantial contribution to water supply in the United States by 2020. Currently, reverse osmosis is one of the most cost effective and widely used desalination technologies. The tendency to form scale deposits during reverse osmosis is an important factor in determining the suitability of input waters for use in desalination. The tendency toward scale formation of samples of saline ground water from selected geologic units in New Mexico was assessed using simulated evaporation. All saline water samples showed a strong tendency to form CaCO3 scale deposits. Saline ground water samples from the Yeso Formation and the San Andres Limestone showed relatively stronger tendencies to form CaSO4 2H2O scale deposits and relatively weaker tendencies to form SiO2(a) scale deposits than saline ground water samples from the Rio Grande alluvium. Tendencies toward scale formation in saline ground water samples from the Dockum Group were highly variable. The tendencies toward scale formation of saline waters from the Yeso Formation, San Andres Limestone, and Rio Grande alluvium appear to correlate with the mineralogical composition of the geologic units, suggesting that scale-forming tendencies are governed by aquifer composition and water-rock interaction. ?? 2006 Elsevier B.V. All rights reserved.

Saline groundwater in crystalline bedrock

International Nuclear Information System (INIS)

Lampen, P.

1992-11-01

The State-of-art report describes research made on deep saline groundwaters and brines found in crystalline bedrock, mainly in site studies for nuclear waste disposal. The occurrence, definitions and classifications of saline groundwaters are reviewed with a special emphasis on the different theories concerning the origins of saline groundwaters. Studies of the saline groundwaters in Finland and Sweden have been reviewed more thoroughly. Also the mixing of different bodies of groundwaters, observations of the contact of saline groundwaters and permafrost, and the geochemical modelling of saline groundwaters as well as the future trends of research have been discussed. (orig.)

Analysis of the behavior of radionuclides migration in fractured medium in different types of rocks matrices

International Nuclear Information System (INIS)

Sá, Ludimila Silva Salles de; Silveira, Cláudia Siqueira da; Lima, Zelmo Rodrigues de

2017-01-01

In management of radioactive wastes, the current trend is to dispose the radioactive waste for long life and high activity in permanent repositories of depth, geologically stable and low permeability. Thus, it is relevant to analyze the groundwater movement process, because the mechanism by which the radionuclides in a repository with fractures could return to the surface would be through the groundwater circulation system. A common problem encountered is the modeling of the migration of radionuclides in a fractured medium. The objective of this work is to evaluate the behavior of the migration of radionuclides in two types of rock matrix, considering the following properties: volumetric density, porosity, distribution coefficient and molecular diffusion coefficient. The physical system adopted consists of the matrix rock containing a discrete fracture in a porous medium saturated with water. The partial differential equations that describe the radionuclide movement were discretized by finite differences, and the Implicit Euler method was adopted. While for the convective term the numerical scheme of progressive differences was used

Fractures and Rock Mechanics, Phase 1

DEFF Research Database (Denmark)

Havmøller, Ole; Krogsbøll, Anette

1997-01-01

The main objectives of the project are to combine geological description of fractures, chalk types and rock mechanical properties, and to investigate whether the chosen outcrops can be used as analogues to reservoir chalks. Five chalk types, representing two outcrop localities: Stevns...

Rock excavation by pulsed electron beams

International Nuclear Information System (INIS)

Avery, R.T.; Keefe, D.; Brekke, T.L.; Finnie, I.

1976-01-01

If an intense short pulse of megavolt electrons is deposited in a brittle solid, dynamic spalling can be made to occur with removal of material. Experiments have been made on several types of hard rock; results are reproducible and well-described theoretically. An accelerator with a rapid-pulsed scanning electron-beam has been designed that could tunnel in hard rock about ten times faster than conventional drill/blast methods. (author)

Rock index properties for geoengineering in the Paradox Basin

International Nuclear Information System (INIS)

O'Rourke, J.E.; Rey, P.H.; Alviti, E.; Capps, C.C.

1986-02-01

Previous researchers have investigated the use of a number of rapid index tests that can be used on core samples, or in situ, to determine rock properties needed for geoengineering design, or to predict construction performance in these rock types. Selected research is reviewed, and the correlations of index tests with laboratory tests of rock properties found by the earlier investigators are discussed. The selection and testing of rock core samples from the Gibson Dome No. 1 borehole in Paradox Basin are described. The samples consist primarily of non-salt rock above salt cycle 6, but include some samples of anhydrite and salt cycle 6. The index tests included the point load test, Schmidt hammer rebound test, and abrasion hardness test. Statistical methods were used to analyze the correlations of index test data with laboratory test data of rock properties for the same core. Complete statistical results and computer-generated graphics are presented; these results are discussed in relation to the work of earlier investigations for index testing of similar rock types. Generally, fair to good correlations were obtained for predicting unconfined compressive strength and Young's modulus for sandstone and siltstone, while poorer correlations were found for limestone. This may be due to the large variability of limestone properties compared to the small number of samples. Overall, the use of index tests to assess rock properties at Paradox Basin appears to be practial for some conceptual and preliminary design needs, and the technique should prove useful at any salt repository site. However, it is likely that specific correlations should be demonstrated separately for each site, and the data base for establishing the correlations should probably include at least several hundred data points for each type

Mechanical properties of rock at high temperatures

International Nuclear Information System (INIS)

Kinoshita, Naoto; Abe, Tohru; Wakabayashi, Naruki; Ishida, Tsuyoshi.

1997-01-01

The laboratory tests have been performed in order to investigate the effects of temperature up to 300degC and pressure up to 30 MPa on the mechanical properties of three types of rocks, Inada granite, Sanjoume andesite and Oya tuff. The experimental results indicated that the significant differences in temperature dependence of mechanical properties exist between the three rocks, because of the difference of the factors which determine the mechanical properties of the rocks. The effect of temperature on the mechanical properties for the rocks is lower than that of pressure and water content. Temperature dependence of the mechanical properties is reduced by increase in pressure in the range of pressure and temperature investigated in this paper. (author)

Effects of atmospheric moisture on rock resistivity.

Science.gov (United States)

Alvarez, R.

1973-01-01

This study examines the changes in resistivity of rock samples as induced by atmospheric moisture. Experiments were performed on samples of hematitic sandstone, pyrite, and galena. The sandstone underwent a change in resistivity of four orders of magnitude when it was measured in a vacuum of 500 ntorr and in air of 37% relative humidity. Pyrite and galena showed no variations in resistivity when they were measured under the same conditions. These results, plus others obtained elsewhere, indicate that rocks of the resistive type are affected in their electrical properties by atmospheric moisture, whereas rocks of the conductive type are not. The experimental evidence obtained is difficult to reconcile with a model of aqueous electrolytic conduction on the sample surface. It is instead suggested that adsorbed water molecules alter the surface resistivity in a manner similar to that observed in semiconductors and insulators.

Fracture characteristics in Japanese rock

International Nuclear Information System (INIS)

Ijiri, Yuji; Sawada, Atsushi; Akahori, Kuniaki

1999-11-01

It is crucial for the performance assessment of geosphere to evaluate the characteristics of fractures that can be dominant radionuclide migration pathways from a repository to biosphere. This report summarizes the characteristics of fractures obtained from broad literature surveys and the fields surveys at the Kamaishi mine in northern Japan and at outcrops and galleries throughout the country. The characteristics of fractures described in this report are fracture orientation, fracture shape, fracture frequency, fracture distribution in space, transmissivity of fracture, fracture aperture, fracture fillings, alteration halo along fracture, flow-wetted surface area in fracture, and the correlation among these characteristics. Since granitic rock is considered the archetype fractured media, a large amount of fracture data is available in literature. In addition, granitic rock has been treated as a potential host rock in many overseas programs, and has JNC performed a number of field observations and experiments in granodiorite at the Kamaishi mine. Therefore, the characteristics of fractures in granitic rock are qualitatively and quantitatively clarified to some extent in this report, while the characteristics of fractures in another rock types are not clarified. (author)

Thermal Inertia of Rocks and Rock Populations

Science.gov (United States)

Golombek, M. P.; Jakosky, B. M.; Mellon, M. T.

2001-01-01

The effective thermal inertia of rock populations on Mars and Earth is derived from a model of effective inertia versus rock diameter. Results allow a parameterization of the effective rock inertia versus rock abundance and bulk and fine component inertia. Additional information is contained in the original extended abstract.

X-ray microtomography application in pore space reservoir rock

Energy Technology Data Exchange (ETDEWEB)

Oliveira, M.F.S.; Lima, I. [Nuclear Instrumentation Laboratory, COPPE/UFRJ, P.O. Box 68509, 21.941-972, Rio de Janeiro (Brazil); Borghi, L. [Geology Department, Geosciences Institute, Federal University of Rio de Janeiro, Brazil. (Brazil); Lopes, R.T., E-mail: ricardo@lin.ufrj.br [Nuclear Instrumentation Laboratory, COPPE/UFRJ, P.O. Box 68509, 21.941-972, Rio de Janeiro (Brazil)

2012-07-15

Characterization of porosity in carbonate rocks is important in the oil and gas industry since a major hydrocarbons field is formed by this lithology and they have a complex media porous. In this context, this research presents a study of the pore space in limestones rocks by x-ray microtomography. Total porosity, type of porosity and pore size distribution were evaluated from 3D high resolution images. Results show that carbonate rocks has a complex pore space system with different pores types at the same facies. - Highlights: Black-Right-Pointing-Pointer This study is about porosity parameter in carbonate rocks by 3D X-Ray Microtomography. Black-Right-Pointing-Pointer This study has become useful as data input for modeling reservoir characterization. Black-Right-Pointing-Pointer This technique was able to provide pores, grains and mineralogical differences among the samples.

Deep rock damage in the San Andreas Fault revealed by P- and S-type fault-zone-guided waves

Science.gov (United States)

Ellsworth, William L.; Malin, Peter E.

2011-01-01

Damage to fault-zone rocks during fault slip results in the formation of a channel of low seismic-wave velocities. Within such channels guided seismic waves, denoted by Fg, can propagate. Here we show with core samples, well logs and Fg-waves that such a channel is crossed by the SAFOD (San Andreas Fault Observatory at Depth) borehole at a depth of 2.7 km near Parkfield, California, USA. This laterally extensive channel extends downwards to at least half way through the seismogenic crust, more than about 7 km. The channel supports not only the previously recognized Love-type- (FL) and Rayleigh-type- (FR) guided waves, but also a new fault-guided wave, which we name FF. As recorded 2.7 km underground, FF is normally dispersed, ends in an Airy phase, and arrives between the P- and S-waves. Modelling shows that FF travels as a leaky mode within the core of the fault zone. Combined with the drill core samples, well logs and the two other types of guided waves, FF at SAFOD reveals a zone of profound, deep, rock damage. Originating from damage accumulated over the recent history of fault movement, we suggest it is maintained either by fracturing near the slip surface of earthquakes, such as the 1857 Fort Tejon M 7.9, or is an unexplained part of the fault-creep process known to be active at this site.

Effects of Weathering on TIR Spectra and Rock Classification

Science.gov (United States)

McDowell, M. L.; Hamilton, V. E.; Riley, D.

2006-03-01

Changes in mineralogy due to weathering are detectable in the TIR and cause misclassification of rock types. We survey samples over a range of lithologies and attempt to provide a method of correction for rock identification from weathered spectra.

Studying physical properties of deformed intact and fractured rocks by micro-scale hydro-mechanical-seismicity model

Science.gov (United States)

Raziperchikolaee, Samin

The pore pressure variation in an underground formation during hydraulic stimulation of low permeability formations or CO2 sequestration into saline aquifers can induce microseismicity due to fracture generation or pre-existing fracture activation. While the analysis of microseismic data mainly focuses on mapping the location of fractures, the seismic waves generated by the microseismic events also contain information for understanding of fracture mechanisms based on microseismic source analysis. We developed a micro-scale geomechanics, fluid-flow and seismic model that can predict transport and seismic source behavior during rock failure. This model features the incorporation of microseismic source analysis in fractured and intact rock transport properties during possible rock damage and failure. The modeling method considers comprehensive grains and cements interaction through a bonded-particle-model. As a result of grain deformation and microcrack development in the rock sample, forces and displacements in the grains involved in the bond breakage are measured to determine seismic moment tensor. In addition, geometric description of the complex pore structure is regenerated to predict fluid flow behavior of fractured samples. Numerical experiments are conducted for different intact and fractured digital rock samples, representing various mechanical behaviors of rocks and fracture surface properties, to consider their roles on seismic and transport properties of rocks during deformation. Studying rock deformation in detail provides an opportunity to understand the relationship between source mechanism of microseismic events and transport properties of damaged rocks to have a better characterizing of fluid flow behavior in subsurface formations.

Sr–Nd isotopic compositions of Paleoproterozoic metavolcanic rocks from the southern Ashanti volcanic belt, Ghana

OpenAIRE

Dampare, Samuel; Shibata, Tsugio; Asiedu, Daniel; Okano, Osamu; Manu, Johnson; Sakyi, Patrick

2009-01-01

Neodymium (Nd) and strontium (Sr) isotopic data are presented for Paleoproterozoic metavolcanic rocks in the southern part of the Ashanti volcanic belt of Ghana. The metavolcanic rocks are predominantly basalts/basaltic andesites and andesites with minor dacites. Two types of basalts/basaltic andesites (B/A), Type I and Type II, have been identified. The Type I B/A are stratigraphically overlain by the Type II B/A, followed by the andesites and the dacites. The analyzed volcanic rocks commonl...

Unwinding after high salinity stress: Pea DNA helicase 45 over- expression in tobacco confers high salinity tolerance without affecting yield (abstract)

International Nuclear Information System (INIS)

Tuteja, N.

2005-01-01

Soil salinity is an increasing threat for agriculture and is a major factor in reducing plant productivity; therefore, it is necessary to obtain salinity-tolerant varieties. A typical characteristic of soil salinity is the induction of multiple stress- inducible genes. Some of the genes encoding osmolytes, ion channels or enzymes are able to confer salinity-tolerant phenotypes when transferred to sensitive plants. As salinity stress affects the cellular gene-expression machinery, it is evident that molecules involved in nucleic acid processing including helicases, are likely to be affected as well. DNA helicases unwind duplex DNA and are involved in replication, repair, recombination and transcription while RNA helicases unfold the secondary structures in RNA and are involved in transcription, ribosome biogenesis and translation initiation. We have earlier reported the isolation of a pea DNA helicase 45 (PDH45) that exhibits striking homology with eIF-4A (Plant J. 24:219-230,2000). Here we report that PDH45 mRNA is induced in pea seedlings in response to high salt and its over- expression driven by a constitutive CAMV-355-promoter in tobacco plants confers salinity tolerance, thus suggesting a new pathway for manipulating stress tolerance in crop plants. The T0 transgenic plants showed high-levels of PDH45 protein in normal and stress conditions, as compared to wild type (WT) plants. The T0 transgenics also showed tolerance to high salinity as tested by a leaf disc senescence assay. The T1 transgenics were able to grow to maturity and set normal viable seeds under continuous salinity stress, without any reduction in plant yield, in terms of seed weight. Measurement of Na/sup +/ ions in different parts of the plant showed higher accumulation in the old leaves and negligible in seeds of T1 transgenic lines as compared with the WT plants. The possible mechanism of salinity tolerance will be discussed. Over-expression of PDH45 provides a possible example of the

Changes of hypertonic saline-induced masseter muscle pain characteristics, by an infusion of the serotonin receptor type 3 antagonist granisetron.

Science.gov (United States)

Christidis, Nikolaos; Ioannidou, Kiriaki; Milosevic, Milena; Segerdahl, Märta; Ernberg, Malin

2008-10-01

This study aimed to investigate whether granisetron reduces masseter muscle pain and allodynia induced by hypertonic saline. Fifteen healthy women and 15 age-matched healthy men participated in this randomized, placebo-controlled, double-blinded study. They first received bilateral injections of hypertonic saline into the masseter muscles (internal control). The evoked pain intensity and the pressure-pain threshold (PPT) were recorded during 30 minutes. Granisetron was then injected on one side and placebo (normal saline) on the contralateral side. Two minutes thereafter, the hypertonic saline injections were repeated. Pain and PPT were again recorded. The first injection of hypertonic saline induced pain of similar intensity, duration, and pain area on both sides, but with larger pain area in the women (P = .017). The PPT did not change significantly. The second injection of hypertonic saline induced considerably less pain (62.5%), of shorter duration (44.1%), and of smaller area (77.4%) on the side pretreated with granisetron (P = .005). The PPT was increased on the granisetron side in the men (P = .002). The results of this study show that local injection of a single dose of granisetron attenuates masseter muscle pain induced by hypertonic saline. This article presents the changes of hypertonic saline-induced masseter muscle pain characteristics by infusion of granisetron. It appears that the pain-inducing effect in this experimental pain model is partly due to activation of 5-HT3-receptors. Hence, the results indicate that granisetron might offer a new treatment approach for localized myofascial pain.

Effect of Different Alternate Irrigation Strategies using Saline and Non-Saline Water on Corn Yield, Salinity and Moisture Distribution in Soil Profile

Directory of Open Access Journals (Sweden)

Ali Reza Kiani

2017-01-01

Full Text Available Introduction: Lack of water and deterioration in the quality of soil and water resources are considered to be the prime cause of reduced crop yield in arid and semi-arid regions ‘More crop per drop’ by trickle irrigation, deficit irrigation, and uncommon water are the best strategies for mitigating water crises. Different irrigation management strategies are needed to increase production in different areas. In areas where sufficient water is available, a full irrigation strategy could be a suitable option, while in areas where water is limited, deficit irrigation would be an appropriate method, and finally in areas where water resources are saline, management strategies for achieving sustainable production as well as economic yields would be suitable. Maize is the third most important grain crop in the world following wheat and rice and it is the main source of nutrition for humans and animals. Because of the importance of maize in the world, increasing maize production under environmental stresses is a big challenge for agricultural scientists. Different methods of irrigation and the use of saline water that had satisfactory results for increasing agricultural production have been studied by several investigators . The main objective of this study was to establish an efficient use of limited water resources as well as to explore the possibility of replacing saline water with fresh water using different management techniques. Materials and Methods: A field experiment was conducted over two maize cropping seasons (2012–2013 in northern Iran (Gorgan Agricultural Research Station to compare different alternate irrigation scenarios using saline water on corn yield, salinity and soil moisture distribution in a randomized complete block design with three replications. Treatments were: T1 and T2 = 100 and 50 % of crop water requirement with non-saline water, respectively; T3 and T4 = variable and fixed full irrigation with saline and non-saline

The effects of bacteria on crystalline rock

International Nuclear Information System (INIS)

Brown, D.A.

1994-01-01

Many reactions involving inorganic minerals at water-rock interfaces have now been recognized to be bacterially mediated; these reactions could have a significant effect in the excavation of vaults for toxic and radioactive waste disposal. To investigate the role that bacteria play in the natural aqueous environment of crystalline rock the microbial growth factors of nutrition, energy and environment are described. Microbial activity has been investigated in Atomic Energy of Canada's Underground Research Laboratory (URL), situated in the Archean granitic Lac du Bonnet Batholith, Winnipeg, Manitoba. Faults, initiated in the Early Proterozoic, and later-formed fractures, provide ground-water pathways. Planktonic bacteria, free-swimming in the groundwater, have been observed in over 100 underground borehole samples. The number of bacteria varied from 10 3 to 10 5 mL -1 and appeared to decrease with depth and with increased salinity of the water. However, in the natural environment of deep (100-500 m) crystalline rocks, where nutrition is limited, formation of biofilms by sessile bacteria is a successful survival strategy. Natural biofilms at the URL and biofilms grown in bioreactors have been studied. The biofilms can accumulate different elements, depending upon the local environment. Precipitates of iron have been found in all the biofilms studied, where they are either passively accumulated or utilized as an energy source. Within the biofilm active and extensive biogeochemical immobilization of dissolved elements is controlled by distinct bacterial activities which are sufficiently discrete for hematite and siderite to be precipitated in close proximity

Fine-grained sheet silicate rocks

International Nuclear Information System (INIS)

Weaver, C.E.

1977-09-01

Considerable interest has been shown in the possibility of using shales as repositories for radioactive waste and a variety of other waste products, and it appears that over the next few years much money and effort will be expended to investigate and test a wide variety of shales. If shales are to be studied in detail by a large number of investigators, it is important that all concerned have the same concept of what constitutes a shale. The term shale and other terms for fine-grained rocks have been used for many years and have been continually redefined. Most definitions predate the development of modern instrumentation and are based on field observations and intuition; however, the main problem is the diversity of definitions. An attempt is made here to develop a simple, rational classification of fine-grained sediments, and it is hoped that this classification will eliminate some of the present ambiguity. In order that the classification be pertinent, mineral composition and textural data were compiled and evaluated. The data on unconsolidated and consolidated sediments were contrasted and the effects of burial diagenesis assessed. It was found necessary to introduce a new term, physil, to describe all sheet silicate minerals. In contrast to the term clay mineral, the term physil has no size connotation. A simple classification is proposed that is based on the percentage of physils and grain size. In Part II the fine-grained physil rocks are classified on the basis of physil type, non-physil minerals, and texture. Formations are listed which have the mineral and textural characteristics of the most important rock types volumetrically. Selected rock types, and the formations in which they can be found, are recommended for laboratory study to determine their suitability for the storage of high-level radioactive waste

Some clastic rocks as parent rocks in beech forests of Brezovica - Južni Kučaj

Directory of Open Access Journals (Sweden)

Joksimović Vesna

2003-01-01

Full Text Available On the large forest areas, where the measures of soil quality improvement are absent or rarely undertaken, the rocks are the sources of a great number of elements in plant nutrition and one of the factors affecting the contents of some elements in plants. The aim of the study is to determine the differences in the contents of Cu, Zn, Mn, Ni, Fe, Cd, Co, Pb and Cr in the beech leaves developed in the same climate conditions, on morphologically similar terrains, composed of different types of sedimentary rocks. This paper presents the study results of the contents of the above elements in argillites, sandstones (grauwackes and microconglomerates occurring as the parent rocks in high beech forests in the region of GJ Bogovina (Brezovica Južni Kučaj and in the leaves of beech developed on these rocks.

A Review of Rock Bolt Monitoring Using Smart Sensors

Directory of Open Access Journals (Sweden)

Gangbing Song

2017-04-01

Full Text Available Rock bolts have been widely used as rock reinforcing members in underground coal mine roadways and tunnels. Failures of rock bolts occur as a result of overloading, corrosion, seismic burst and bad grouting, leading to catastrophic economic and personnel losses. Monitoring the health condition of the rock bolts plays an important role in ensuring the safe operation of underground mines. This work presents a brief introduction on the types of rock bolts followed by a comprehensive review of rock bolt monitoring using smart sensors. Smart sensors that are used to assess rock bolt integrity are reviewed to provide a firm perception of the application of smart sensors for enhanced performance and reliability of rock bolts. The most widely used smart sensors for rock bolt monitoring are the piezoelectric sensors and the fiber optic sensors. The methodologies and principles of these smart sensors are reviewed from the point of view of rock bolt integrity monitoring. The applications of smart sensors in monitoring the critical status of rock bolts, such as the axial force, corrosion occurrence, grout quality and resin delamination, are highlighted. In addition, several prototypes or commercially available smart rock bolt devices are also introduced.

A Review of Rock Bolt Monitoring Using Smart Sensors.

Science.gov (United States)

Song, Gangbing; Li, Weijie; Wang, Bo; Ho, Siu Chun Michael

2017-04-05

Rock bolts have been widely used as rock reinforcing members in underground coal mine roadways and tunnels. Failures of rock bolts occur as a result of overloading, corrosion, seismic burst and bad grouting, leading to catastrophic economic and personnel losses. Monitoring the health condition of the rock bolts plays an important role in ensuring the safe operation of underground mines. This work presents a brief introduction on the types of rock bolts followed by a comprehensive review of rock bolt monitoring using smart sensors. Smart sensors that are used to assess rock bolt integrity are reviewed to provide a firm perception of the application of smart sensors for enhanced performance and reliability of rock bolts. The most widely used smart sensors for rock bolt monitoring are the piezoelectric sensors and the fiber optic sensors. The methodologies and principles of these smart sensors are reviewed from the point of view of rock bolt integrity monitoring. The applications of smart sensors in monitoring the critical status of rock bolts, such as the axial force, corrosion occurrence, grout quality and resin delamination, are highlighted. In addition, several prototypes or commercially available smart rock bolt devices are also introduced.

Thermal conductivity of the rocks in the Bureau of Mines Standard Rock Suite

International Nuclear Information System (INIS)

Morgan, M.T.; West, G.A.

1980-01-01

Thermal conductivities of eight rocks from the Bureau of Mines Standard Rock Suite were measured in air over the temperature range 373 to 533 0 K (100 to 260 0 C). The thermal conductivities of these rocks were measured to furnish standards for future comparisons with host rock from prospective nuclear waste repository sites. The thermal conductivity at a given temperature decreased by as much as 9% after a specimen had been heated to the maximum temperature (533 0 K), but additional heating cycles had no further effect. This decrease was smallest in the igneous rocks and largest in the sedimentary types. Variations due to orientation were within the precision of measurements (+- 5%). In most cases the thermal conductivities were linear with the reciprocal of the temperature and were within 14% of published data obtained by other methods. Measurements were made by a cut-bar comparison method in which the sample was sandwiched between two reference or metering bars made of Pyroceram 9606 glass-ceramic. The apparatus consisted of a Dynatech Model TCFCM-N20 comparative thermal conductivity analyzer controlled by a Hewlett Packard Model 3052A data acquisition system. A program was written to increment and cycle the temperature in steps between predetermined initial and maximum values. At each step the thermal conductivity was measured after steady-state conditions were established. The rocks furnished by the Bureau of Mines were quarried in large and fairly homogeneous lots for use by researchers at various laboratories. To investigate any anisotropy, cores were taken from each rock cube perpendicular to each of the cube faces. Samples 2 in. in diameter and approx. 0.75 in. thick were prepared from the cores and were dried in a vacuum oven for at least one month prior to taking measurements

Study on investigation and evaluation methods of deep seated sedimentary rocks. Chemical weathering, pore water squeezing and relationships of physical properties of sedimentary rocks

International Nuclear Information System (INIS)

Oyama, Takahiro; Suzuki, Koichi

2006-01-01

Chemical weathering, porewater squeezing and physical properties for the sedimentary rocks were examined. Chemical weathering potential of rocks was described by the sulfur as a acceleration factor of weathering and carbonate contents as a neutralization factor of it. The carbonate contents in the rocks were measured accurately by the gas pressure measurement method. Pore water squeezing method was applied for the semi-hard sedimentary rocks (Opalinusclay). The chemical change of extracted pore water under high pressure conditions was estimated. Physical property of sedimentary rocks have relationship among the porosity and permeability and resistivity coefficient in the same rock types. It is possible to estimate the water permeability from the geophysical tests. (author)

Fire effects on rock images and similar cultural resources [Chapter 5

Science.gov (United States)

Roger E. Kelly; Daniel F. McCarthy

2012-01-01

Throughout human global history, people have purposely altered natural rock surfaces by drilling, drawing, painting, incising, pecking, abrading and chiseling images into stone. Some rock types that present suitable media surfaces for these activities are fine-grained sandstones and granites, basalts, volcanic tuff, dolomites, and limestones. Commonly called rock...

Salinity and pH effects on floating and emergent macrophytes in a constructed wetland.

Science.gov (United States)

Hadad, H R; Mufarrege, M M; Di Luca, G A; Maine, M A

2017-04-01

Salvinia herzogii, Pistia stratiotes and Eichhornia crassipes (floating species) were the dominant macrophytes in a constructed wetland (CW) over the first years of operation. Later, the emergent Typha domingensis displaced the floating species, becoming dominant. The industrial effluent treated at this CW showed high pH and salinity. The aim of this work was to study the tolerance of floating species and T. domingensis exposed to different pH and salinity treatments. Treatments at pH 8, 9, 10 and 11 and salinities of 2,000; 3,000; 4,000; 6,000; and 8,000 mg L -1 were performed. Floating macrophytes were unable to tolerate the studied pH and salinity ranges, while T. domingensis tolerated higher pH and salinity values. Many industrial effluents commonly show high pH and salinity. T. domingensis demonstrated to be a suitable macrophyte to treat this type of effluents.

Rock pushing and sampling under rocks on Mars

Science.gov (United States)

Moore, H.J.; Liebes, S.; Crouch, D.S.; Clark, L.V.

1978-01-01

Viking Lander 2 acquired samples on Mars from beneath two rocks, where living organisms and organic molecules would be protected from ultraviolet radiation. Selection of rocks to be moved was based on scientific and engineering considerations, including rock size, rock shape, burial depth, and location in a sample field. Rock locations and topography were established using the computerized interactive video-stereophotogrammetric system and plotted on vertical profiles and in plan view. Sampler commands were developed and tested on Earth using a full-size lander and surface mock-up. The use of power by the sampler motor correlates with rock movements, which were by plowing, skidding, and rolling. Provenance of the samples was determined by measurements and interpretation of pictures and positions of the sampler arm. Analytical results demonstrate that the samples were, in fact, from beneath the rocks. Results from the Gas Chromatograph-Mass Spectrometer of the Molecular Analysis experiment and the Gas Exchange instrument of the Biology experiment indicate that more adsorbed(?) water occurs in samples under rocks than in samples exposed to the sun. This is consistent with terrestrial arid environments, where more moisture occurs in near-surface soil un- der rocks than in surrounding soil because the net heat flow is toward the soil beneath the rock and the rock cap inhibits evaporation. Inorganic analyses show that samples of soil from under the rocks have significantly less iron than soil exposed to the sun. The scientific significance of analyses of samples under the rocks is only partly evaluated, but some facts are clear. Detectable quantities of martian organic molecules were not found in the sample from under a rock by the Molecular Analysis experiment. The Biology experiments did not find definitive evidence for Earth-like living organisms in their sample. Significant amounts of adsorbed water may be present in the martian regolith. The response of the soil

Tackling the salinity-pollution nexus in coastal aquifers from arid regions using nitrate and boron isotopes.

Science.gov (United States)

Re, V; Sacchi, E

2017-05-01

pollution drivers. The results indicate two main origins for human-induced pollution: (i) manure and septic effluents, especially in urban areas, and (ii) synthetic fertilizers in agricultural areas. In the latter, δ 15 N-enriched values highlight a mixture of those sources, possibly related to unbalanced fertilization and agricultural return flow. Boron isotopes (δ 11 B) were hence studied to further distinguish the nitrate origin in the presence of multiple sources and mixing processes. The results indicate that in the study area, the high geochemical background for B and Cl, associated to the complex water-rock interaction processes, limit the application of the coupled δ 11 B and δ 15 N isotopic systematics to the detection of sources of groundwater pollution. In fact, despite the exceedingly high nitrate contents, the depleted δ 11 B values that characterize synthetic fertilizers and sewage leakages could not be detected. Therefore, even if in saline groundwater the anthropogenic contribution has a negligible effect in terms of salinity input, with both sewage and irrigation water not very charged, the associated nitrate content fuels up water-rock interaction processes, eventually leading to a mineralization increase.

Engineering and Design: Characterization and Measurement of Discontinuities in Rock Slopes

National Research Council Canada - National Science Library

1983-01-01

This ETL provides guidance for characterizing and measuring rock discontinuities on natural slopes or slopes constructed in rock above reservoirs, darn abutments, or other types of constructed slopes...

The Changes of P-fractions and Solubility of Phosphate Rock in Ultisol Treated by Organic Matter and Phosphate Rock

Directory of Open Access Journals (Sweden)

Heru Bagus Pulunggono

2012-09-01

Full Text Available Phosphorus (P is one of the essential elements for plant, however, its availability is mostly very low in acid soils. It is well documented that application of phosphate rock and organic matter are able to change the level of availability of P-form in acid soils. The objective of the research were to evaluate the changes of P-fractions ( resin-P, NaHCO3-Pi, and NaHCO3-Po and phosphate rock dissolution which were induced by application of organic matter (Imperata cylindrica, Pueraria javanica, dan Colopogonium mucunoides and phosphate rock in Utisol Lampung. The experiment was designed in a completely randomized design with three factors and three replications. The first factor was the types of organic matter (I. cylindrica, P. javanica, and C. mucunoides, the second factor was the rate of organic matter (0, 2.5, and 5%, and the third factor was the rate of phosphate rock (0, 40, and 80 mg P kg-1. The results showed that in the rate of 0 and 1% organic matter, the type of organic matter did not affect P-fraction of NaHCO3-Pi, but in the rate of 2.5 and 5%, NaHCO3-Pi due to application of P. javanica, and C. mucunoides higher than due to application of I. cylindrica. However, the increasing rate of organic matter increased NaHCO3-Pi. Then, P-fraction of Resin-Pi was affected by the type of organic matter, the rate of organic matter, and the rate of phosphate rock, respectively. P-fraction of resin-Pi due to application of P. javanica, and C. mucunoides was higher than due to application of I. cylindrica, but the effect of P. javanica, and C. mucunoides was not different. Increasing the rate of organic matter and phosphate rock increased P-fraction of resin-Pi and NaHCO3-Pi, but P-fraction of NaHCO3-Po was not affected by all treatments. Meanwhile, dissolution of phosphate rock was affected by the kind of organic matter and soil reaction. In the rate of 5% organic matter, dissolution of phosphate rock by application of I. cylindrica (70% was higher

Increase of urban lake salinity by road deicing salt

International Nuclear Information System (INIS)

Novotny, Eric V.; Murphy, Dan; Stefan, Heinz G.

2008-01-01

Over 317,000 tonnes of road salt (NaCl) are applied annually for road deicing in the Twin Cities Metropolitan Area (TCMA) of Minnesota. Although road salt is applied to increase driving safety, this practice influences environmental water quality. Thirteen lakes in the TCMA were studied over 46 months to determine if and how they respond to the seasonal applications of road salt. Sodium and chloride concentrations in these lakes were 10 and 25 times higher, respectively, than in other non-urban lakes in the region. Seasonal salinity/chloride cycles in the lakes were correlated with road salt applications: High concentrations in the winter and spring, especially near the bottom of the lakes, were followed by lower concentrations in the summer and fall due to flushing of the lakes by rainfall runoff. The seasonal salt storage/flushing rates for individual lakes were derived from volume-weighted average chloride concentration time series. The rate ranged from 9 to 55% of a lake's minimum salt content. In some of the lakes studied salt concentrations were high enough to stop spring turnover preventing oxygen from reaching the benthic sediments. Concentrations above the sediments were also high enough to induce convective mixing of the saline water into the sediment pore water. A regional analysis of historical water quality records of 38 lakes in the TCMA showed increases in lake salinity from 1984 to 2005 that were highly correlated with the amount of rock salt purchased by the State of Minnesota. Chloride concentrations in individual lakes were positively correlated with the percent of impervious surfaces in the watershed and inversely with lake volume. Taken together, the results show a continuing degradation of the water quality of urban lakes due to application of NaCl in their watersheds

Finding a solution: Heparinised saline versus normal saline in the maintenance of invasive arterial lines in intensive care.

Science.gov (United States)

Everson, Matthew; Webber, Lucy; Penfold, Chris; Shah, Sanjoy; Freshwater-Turner, Dan

2016-11-01

We assessed the impact of heparinised saline versus 0.9% normal saline on arterial line patency. Maintaining the patency of arterial lines is essential for obtaining accurate physiological measurements, enabling blood sampling and minimising line replacement. Use of heparinised saline is associated with risks such as thrombocytopenia, haemorrhage and mis-selection. Historical studies draw variable conclusions but suggest that normal saline is at least as effective at maintaining line patency, although recent evidence has questioned this. We conducted a prospective analysis of the use of heparinised saline versus normal saline on unselected patients in the intensive care of our hospital. Data concerning duration of 471 lines insertion and reason for removal was collected. We found a higher risk of blockage for lines flushed with normal saline compared with heparinised saline (RR = 2.15, 95% CI 1.392-3.32, p  ≤ 0.001). Of the 56 lines which blocked initially (19 heparinised saline and 37 normal saline lines), 16 were replaced with new lines; 5 heparinised saline lines and 11 normal saline lines were reinserted; 5 of these lines subsequently blocked again, 3 of which were flushed with normal saline. Our study demonstrates a clinically important reduction in arterial line longevity due to blockages when flushed with normal saline compared to heparinised saline. We have determined that these excess blockages have a significant clinical impact with further lines being inserted after blockage, resulting in increased risks to patients, wasted time and cost of resources. Our findings suggest that the current UK guidance favouring normal saline flushes should be reviewed.

Historical rock falls in Yosemite National Park, California (1857-2011)

Science.gov (United States)

Stock, Greg M.; Collins, Brian D.; Santaniello, David J.; Zimmer, Valerie L.; Wieczorek, Gerald F.; Snyder, James B.

2013-01-01

Inventories of rock falls and other types of landslides are valuable tools for improving understanding of these events. For example, detailed information on rock falls is critical for identifying mechanisms that trigger rock falls, for quantifying the susceptibility of different cliffs to rock falls, and for developing magnitude-frequency relations. Further, inventories can assist in quantifying the relative hazard and risk posed by these events over both short and long time scales. This report describes and presents the accompanying rock fall inventory database for Yosemite National Park, California. The inventory database documents 925 events spanning the period 1857–2011. Rock falls, rock slides, and other forms of slope movement represent a serious natural hazard in Yosemite National Park. Rock-fall hazard and risk are particularly relevant in Yosemite Valley, where glacially steepened granitic cliffs approach 1 km in height and where the majority of the approximately 4 million yearly visitors to the park congregate. In addition to damaging roads, trails, and other facilities, rock falls and other slope movement events have killed 15 people and injured at least 85 people in the park since the first documented rock fall in 1857. The accompanying report describes each of the organizational categories in the database, including event location, type of slope movement, date, volume, relative size, probable trigger, impact to humans, narrative description, references, and environmental conditions. The inventory database itself is contained in a Microsoft Excel spreadsheet (Yosemite_rock_fall_database_1857-2011.xlsx). Narrative descriptions of events are contained in the database, but are also provided in a more readable Adobe portable document format (pdf) file (Yosemite_rock_fall_database_narratives_1857-2011.pdf) available for download separate from the database.

Modelling soil salinity in Oued El Abid watershed, Morocco

Science.gov (United States)

Mouatassime Sabri, El; Boukdir, Ahmed; Karaoui, Ismail; Arioua, Abdelkrim; Messlouhi, Rachid; El Amrani Idrissi, Abdelkhalek

2018-05-01

Soil salinisation is a phenomenon considered to be a real threat to natural resources in semi-arid climates. The phenomenon is controlled by soil (texture, depth, slope etc.), anthropogenic factors (drainage system, irrigation, crops types, etc.), and climate factors. This study was conducted in the watershed of Oued El Abid in the region of Beni Mellal-Khenifra, aimed at localising saline soil using remote sensing and a regression model. The spectral indices were extracted from Landsat imagery (30 m resolution). A linear correlation of electrical conductivity, which was calculated based on soil samples (ECs), and the values extracted based on spectral bands showed a high accuracy with an R2 (Root square) of 0.80. This study proposes a new spectral salinity index using Landsat bands B1 and B4. This hydro-chemical and statistical study, based on a yearlong survey, showed a moderate amount of salinity, which threatens dam water quality. The results present an improved ability to use remote sensing and regression model integration to detect soil salinity with high accuracy and low cost, and permit intervention at an early stage of salinisation.

Study on performance of a simultaneous spectrometer of ICP emission source for the determination of the major elements in rocks

International Nuclear Information System (INIS)

Vieira, M.D.

1987-01-01

The optimization of operational parameters of a simultaneous spectrometer coupled to an ICP excitation source in order to establish an analytical method for the simultaneous determination of the major elements in rocks is studied. The mutual spectral interferences, calibration curves for the acid and saline matrix and the internal standard method with ytrium are analyzed. (M.J.C.) [pt

Small-scale bentonite injection test on rock

International Nuclear Information System (INIS)

Pusch, R.

1978-03-01

When radiactive waste is disposed a sealing of the rock is very valuable since it reduces the rate of water percolation and diffusion. In an earlier report injection of bentonite gels by means of over-pressure and subsequent electrophoresis has been suggested. The present report describes a rock test series where bentonite injection was applied. For the test an approximately cubical block of about 1 m 3 was selected. The rock type was diorite with a fairly high frequency of quartz denses. The block was kept in a basin during the test in order to maintain the water saturation. Holes were bored in the block. A bentonite slurry with 1000 percent water content was injected. It was shown that the bentonite had a sealing effect but the depth of extrusion into rock joints was not large because of gelation. Electro-Kinetic injection of montmorillonite was found to be a more promising technique for rock lightening

Salinity drives archaeal distribution patterns in high altitude lake sediments on the Tibetan Plateau.

Science.gov (United States)

Liu, Yongqin; Priscu, John C; Xiong, Jinbo; Conrad, Ralf; Vick-Majors, Trista; Chu, Haiyan; Hou, Juzhi

2016-03-01

Archaeal communities and the factors regulating their diversity in high altitude lakes are poorly understood. Here, we provide the first high-throughput sequencing study of Archaea from Tibetan Plateau lake sediments. We analyzed twenty lake sediments from the world's highest and largest plateau and found diverse archaeal assemblages that clustered into groups dominated by methanogenic Euryarchaeota, Crenarchaeota and Halobacteria/mixed euryarchaeal phylotypes. Statistical analysis inferred that salinity was the major driver of community composition, and that archaeal diversity increased with salinity. Sediments with the highest salinities were mostly dominated by Halobacteria. Crenarchaeota dominated at intermediate salinities, and methanogens were present in all lake sediments, albeit most abundant at low salinities. The distribution patterns of the three functional types of methanogens (hydrogenotrophic, acetotrophic and methylotrophic) were also related to changes in salinity. Our results show that salinity is a key factor controlling archaeal community diversity and composition in lake sediments on a spatial scale that spans nearly 2000 km on the Tibetan Plateau. © FEMS 2016. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Salinity Alters the Polyisoprenoid Alcohol Content and Composition of Both Salt-Secreting and Non–Salt-Secreting Mangrove Seedlings

Directory of Open Access Journals (Sweden)

Mohammad Basyuni

2017-10-01

Full Text Available The effects of salinity on the polyisoprenoid alcohol content and composition of the salt-secreting mangrove species Avicennia marina and Sonneratia alba and the non–salt-secreting species Bruguiera gymnorrhiza and Kandelia obovata were studied. The seedlings of mangroves were grown for 5 months under 0% and 3% salt concentrations. The occurrence, content, and distribution of four mangrove seedlings were analyzed by two-dimensional thin layer chromatography. The structural groups of the polyprenols and dolichols in the leaves and roots were classified into two types (I and II. In type I, dolichols predominated over polyprenols (more than 90%, whereas in type II, the occurrence of both polyprenols and dolichols was observed. Polyprenols were not detected in the leaves of A. marina and B. gymnorrhiza under 0% salt (control, but were detected in small amounts in K. obovata leaves; however, significant amounts were found in the 3% salinity group. This finding in A. marina, B. gymnorrhiza, and K. obovata leaves implies a change to the structural group: under 0% salt concentrations, the groups are classified as type I, but become type II under 3% salt concentrations. The occurrence of ficaprenol (C50–55 was found only in the leaves of the non–salt-secreting species B. gymnorrhiza and K. obovata under 3% salinity and not in the salt-secreting species A. marina or S. alba. It is noteworthy that the polyisoprenoid type in the roots of the four species showed no change under salinity; the two salt-secreting species A. marina and S. alba contained type I under 0% and 3% salt concentrations. On the other hand, type II polyisoprenoids were identified in the non–salt-secreting species B. gymnorrhiza and K. obovata under 0% and 3% salinity conditions. This finding suggested that polyisoprenoids play a protective role against salinity in the mangrove leaves of both salt-secreting and non–salt-secreting species.

The Interplay Between Saline Fluid Flow and Dynamic Permeability in Magmatic-Hydrothermal Systems

Science.gov (United States)

Weis, P.

2014-12-01

Magmatic-hydrothermal ore deposits document the interplay between saline fluid flow and rock permeability. Numerical simulations of multi-phase flow of variably miscible, compressible H20-NaCl fluids in concert with a dynamic permeability model can reproduce characteristics of porphyry copper and epithermal gold systems. This dynamic permeability model incorporates depth-dependent permeability profiles characteristic for tectonically active crust as well as pressure- and temperature-dependent relationships describing hydraulic fracturing and the transition from brittle to ductile rock behavior. In response to focused expulsion of magmatic fluids from a crystallizing upper crustal magma chamber, the hydrothermal system self-organizes into a hydrological divide, separating an inner part dominated by ascending magmatic fluids under near-lithostatic pressures from a surrounding outer part dominated by convection of colder meteoric fluids under near-hydrostatic pressures. This hydrological divide also provides a mechanism to transport magmatic salt through the crust, and prevents the hydrothermal system to become "clogged" by precipitation of solid halite due to depressurization of saline, high-temperature magmatic fluids. The same physical processes at similar permeability ranges, crustal depths and flow rates are relevant for a number of active systems, including geothermal resources and excess degassing at volcanos. The simulations further suggest that the described mechanism can separate the base of free convection in high-enthalpy geothermal systems from the magma chamber as a driving heat source by several kilometers in the vertical direction in tectonic settings with hydrous magmatism. This hydrology would be in contrast to settings with anhydrous magmatism, where the base of the geothermal systems may be closer to the magma chamber.

Petrography, fine stratigraphy and petrofacies of the Stassfurt rock salt (Zechstein 2) in the development region of ASSE II salt mine near Brunswick

International Nuclear Information System (INIS)

Diem, W.

1985-01-01

The Stassfurt rock salt (Na2) in the Asse II salt mine constitutes a saline sequence of the sub-Hercynian basin. In the anticline of the Asse II the Na2 constitutes a core of the anticline with an interior special folding. The combination of underground mapping with the investigations of the salt petrography permits the recognition of stratigraphic unities and with it sedimentary and early diagenetic formation processes for the stratigraphic beds of the Hauptsalz (Na2β), the Speisesalz (Na2SP) and the Polyhalitbaenkchensalz (Na2P). An additional postdiagenetic new formation of minerals from the overlying Stassfurt potash layer (K2C) can be recognized in the kieseritic region of the ''Carnallitisch-Kieseritische Ueberganssalz (Na2K+C)'' and in the ''Tonliniensalz'' (Na2TL). The lower part of the Na2β belongs to a saline basin facies. In the upper part of the Na2β structural and textural characteristics refer to the swallowing of the saline sedimentation room. Simultaneously, more and more terrestrial influences of the saline sedimentation become conspicuous in the northwestern part of the Asse II. They have their clearest facies in the only locally formed Tonliniensalz (Na2TL). The petrographic review of the ''polyhalite region'', which encloses the upper part of the Na2β, the Na2SP and the Na2P, rendered obvious indications for a pseudomorphic origin of polyhalite from primarily sedimened gypsum. The replacement of anhydrite by polyhalite was compared to it as being of unimportant significance. The quantitative parts of the accessory minerals (polyhalite, anhydrite, kieserite, sylvite, carnallite) were determined by means of geochemical investigations in the stratigraphic horizons of Na2 in the mine Asse II. A regional comparison with the saline sedimentation of Zechstein 2 in the sub-Hercynian basin shows a progressive saline sedimentation cycle of the Stassfurt type for the fine stratigraphic division of the Na2 in Asse II. (orig./HP) [de

Model to Assess the Quality of Magmatic Rocks for Reliable and Sustainable Constructions

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Mihaela Toderaş

2017-10-01

Full Text Available Geomechanical assessment of rocks requires knowledge of phenomena that occur under the influence of internal and external factors at a macroscopic or microscopic scale, when rocks are submitted to different actions. To elucidate the quantitative and qualitative geomechanical behavior of rocks, knowing their geological and physical–mechanical characteristics becomes an imperative. Mineralogical, petrographical and chemical analyses provided an opportunity to identify 15 types of igneous rocks (gabbro, diabases, granites, diorites, rhyolites, andesites, and basalts, divided into plutonic and volcanic rocks. In turn, these have been grouped into acidic, neutral (intermediate and basic magmatites. A new ranking method is proposed, based on considering the rock characteristics as indicators of quantitative assessment, and the grading system, by given points, allowing the rocks framing in admissibility classes. The paper is structured into two parts, experimental and interpretation of experimental data, showing the methodology to assess the quality of igneous rocks analyzed, and the results of theoretical and experimental research carried out on the analyzed rock types. The proposed method constitutes an appropriate instrument for assessment and verification of the requirements regarding the quality of rocks used for sustainable construction.

Saline agriculture: A technology for economic utilization and improvement of saline environments (abstract)

International Nuclear Information System (INIS)

Aslam, Z.; Malik, K.A.; Khurshid, S.J.; Awan, A.R.; Akram, M.; Hashmi, Z.; Ali, Y.; Gulnaz, A.; Hussain, M.; Hussain, F.

2005-01-01

The salinity problem is one of the severe constraints for agriculture in Pakistan. In a socio-economic and salinity and drainage survey over an area of about 25000 acres of salt-affected land recently, crop production is found to be very low. Livestock is underfed and malnourished. Pakistan has spent and allocated over one billion US dollars on Salinity Control and Reclamation Projects (SCARP), of course, with dubious results. Over the years, a Saline Agriculture Technology has been developed as a cheap alternative at NIAB for comfortably living with salinity and to profitably utilize saline land rather than its reclamation. The soil improvement is a fringe benefit in this approach. The Saline Agriculture Technology has been tested at laboratory level, at field stations and at farms of some progressive farmers. Now we are sharing this technology with farming communities through a 'Saline Agriculture Farmer Participatory Development Project in Pakistan', with assistance from the National Rural Support Programme. The new project has been launched simultaneously in all four provinces of Pakistan on 25000 acres of salt-affected land. Under this project seeds of salt tolerant crop varieties wheat, cotton, rice, castor, brassica and barley and saplings of trees/shrubs, e.g. Acacia ampliceps, A. nilotica, Casuarina glauca, ber, jaman, etc selected for development work in various institutions of Pakistan are being provided to farmers. Know-how on new irrigation techniques like bed-and-corrugation and bed-and-furrow, agronomic practices like laser land leveling, planting on beds and in auger holes and soil/water amendment practices (use of gypsum and mineral acids) are being shared with farmers. These interventions are quite efficient, save water up to 40% and enable farmers to utilize bad quality water. In general, farmers are being familiarized with prevalent animal diseases, nutritional problems and prophylactic techniques. They are being helped in developing Saline

Features of the distribution of uranium in igneous rocks - uranium deposits associated with igneous rocks

International Nuclear Information System (INIS)

Soerensen, H.

1977-01-01

The generally accepted main features of the distribution of uranium and thorium in igneous rocks are briefly reviewed. It is pointed out that uranium in most cases examined is strongly partitioned into the melt during consolidation of magmas and that uranium is concentrated in the most volatile-rich parts of magmas. The mode of emplacement and the consolidation of magmas control the retention or the expulsion of the volatile phase from consolidating magmas and also the distribution of uranium between magmas and the volatile phase. After a brief review of the types of uranium deposits associated with igneous rocks it is concluded that it is difficult to establish universally valid exploration criteria to be used in the search of these types of deposit. It is emphasized, however, that detailed petrological and geochemical studies may be useful in outlining exploration targets. (author)

Simulation of hydraulic disturbances caused by the underground rock characterisation facility in Olkiluoto, Finland

International Nuclear Information System (INIS)

Loefman, J.; Ferenc, M.

2004-01-01

Spent fuel from the Finnish nuclear power plants will be disposed of in a repository to be excavated in crystalline bedrock at a depth of 400-700 metres in Olkiluoto. The extensive site investigations carried out since the early 1980's will next focus on the construction of an underground rock characterisation facility (ONKALO) in 2004-2010. The open tunnel system will constitute a major hydraulic disturbance for the site's groundwater conditions for hundreds of years. Especially, inflow of groundwater into the tunnels results in a drawdown of groundwater table and upcoming of deep saline groundwater, which the present study aimed to assess by means of a 3D finite element simulation. The modelled bedrock volume, which horizontally covered the whole Olkiluoto island, was conceptually divided into hydraulic units, planar fracture zones and sparsely fractured rock between the zones, which were both separately treated as porous media. The geometry of the fracture zones was based on the geological bedrock model. Simulations showed that without engineering measures (e.g. grouting) taken to limit inflow of groundwater into the open tunnels, the hydraulic disturbances could be drastic. The tunnels draw groundwater from all directions in the bedrock. A major part of inflow comes from the well-conductive subhorizontal fracture zones intersected by the access tunnel and the shaft. The simulations show that the resulting drawdown of groundwater table may be from tens to hundreds of metres and the depressed area may extend over the area of the island. The results also indicate that the salinity of groundwater is gradually rising around and below the tunnel system, and locally concentration (TDS) may rise rather high in the vicinity of the tunnels. However, the disturbances can significantly be reduced by the grouting of rock. (orig.)

Engineering rock mass classification of the Olkiluoto investigation site

Energy Technology Data Exchange (ETDEWEB)

Aeikaes, K. [ed.; Hagros, A.; Johansson, E. [Saanio and Riekkola Consulting Engineers, Helsinki (Finland)] [and others

2000-06-01

Olkiluoto in Eurajoki is being investigated as a possible site for the final disposal of spent nuclear fuel from the Finnish nuclear power plants. The selection of the depth, placement and layout of the repository is affected by the constructability of the bedrock. The constructability, in turn, is influenced by several properties of the host rock, such as its Ethology, the extent of fracturing, its hydrogeological properties and rock engineering characteristics and also by the magnitude and orientation of the in situ stresses and the chemistry of the groundwater. The constructability can be evaluated by the application of a rock classification system in which the properties of the host rock are assessed against common rock engineering judgements associated with underground construction. These judgements are based partly on measurements of in situ stresses and the properties of the bedrock determined from rock samples, but an important aspect is also the practical experience which has been gained during underground excavation in similar conditions and rock types. The aim of the engineering rock mass classification was to determine suitable bedrock volumes for the construction of the repository and has used data from the site characterisation programme carried out at Olkiluoto, which consisted of both surface studies and borehole investigations. The classification specifies three categories of constructability - normal, demanding and very demanding. In addition, rock mass quality has also been classified according to the empirical Q-system to enable a comparison to be made. The rock mass parameters that determine the constructability of the bedrock at Olkiluoto depend primarily on the depth and the Ethology, as well as on whether construction takes place in intact or in fractured rock. The differences in the characteristics of intact rock within a single rock type have been shown to be small. The major lithological unit at Olkiluoto, the mica gneiss, lies in the

Mineralogical and geochemical characteristics of Miocene pelitic sedimentary rocks from the south-western part of the Pannonian Basin System (Croatia: Implications for provenance studies

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Anita Grizelj

2017-01-01

Full Text Available Fifty-two samples of Miocene pelitic sedimentary rock from outcrops on Medvednica, Moslavačka Gora and Psunj Mts., and boreholes in the Sava Depression and the Požega Sub-depression were investigated. These sediments formed in different marine (with normal and reduced salinity, brackish, and freshwater environments, depending on the development stage of the Pannonian Basin System. Carbonate minerals, clay minerals and quartz are the main constituents of all pelitic sedimentary rocks, except in those from Moslavačka Gora Mt in which carbonate minerals are not present. Feldspars, pyrite, opal-CT, and hematite are present as minor constituents in some rocks. Besides calcite, dependent on the sedimentary environment and diagenetic changes, high-magnesium calcite, aragonite, dolomite and ankerite/Ca-dolomite are also present. Smectite or illite-smectite is the main clay minerals in the samples. Minor constituents, present in almost all samples, are detrital illite and kaolinite. In some samples chlorite is also present in a low amount. Major elements, trace elements and rare earth elements patterns used in provenance analysis show that all analysed samples have a composition similar to the values of the upper continental crust (UCC. The contents of major and trace elements as well as SiO2/Al2O3, K2O/Al2O3, Na2O/K2O, Eu/Eu*, La/Sc, Th/Sc, La/Co Th/Co, Th/Cr, Ce/Ce* and LREE/HREE ratios, show that the analysed pelitic sedimentary rocks were formed by weathering of different types of mostly acidic (silicic, i.e. felsic rocks.

Cl/Br ratios and chlorine isotope evidences for groundwater salinization and its impact on groundwater arsenic, fluoride and iodine enrichment in the Datong basin, China.

Science.gov (United States)

Li, Junxia; Wang, Yanxin; Xie, Xianjun

2016-02-15

In order to identify the salinization processes and its impact on arsenic, fluoride and iodine enrichment in groundwater, hydrogeochemical and environmental isotope studies have been conducted on groundwater from the Datong basin, China. The total dissolved solid (TDS) concentrations in groundwater ranged from 451 to 8250 mg/L, and 41% of all samples were identified as moderately saline groundwater with TDS of 3000-10,000 mg/L. The results of groundwater Cl concentrations, Cl/Br molar ratio and Cl isotope composition suggest that three processes including water-rock interaction, surface saline soil flushing, and evapotranspiration result in the groundwater salinization in the study area. The relatively higher Cl/Br molar ratio in groundwater from multiple screening wells indicates the contribution of halite dissolution from saline soil flushed by vertical infiltration to the groundwater salinization. However, the results of groundwater Cl/Br molar ratio model indicate that the effect of saline soil flushing practice is limited to account for the observed salinity variation in groundwater. The plots of groundwater Cl vs. Cl/Br molar ratio, and Cl vs δ(37)Cl perform the dominant effects of evapotranspiration on groundwater salinization. Inverse geochemical modeling results show that evapotranspiration may cause approximately 66% loss of shallow groundwater to account for the observed hydrochemical pattern. Due to the redox condition fluctuation induced by irrigation activities and evapotranspiration, groundwater salinization processes have negative effects on groundwater arsenic enrichment. For groundwater iodine and fluoride enrichment, evapotranspiration partly accounts for their elevation in slightly saline water. However, too strong evapotranspiration would restrict groundwater fluoride concentration due to the limitation of fluorite solubility. Copyright © 2015. Published by Elsevier B.V.

Dextrose saline compared with normal saline rehydration of hyperemesis gravidarum: a randomized controlled trial.

Science.gov (United States)

Tan, Peng Chiong; Norazilah, Mat Jin; Omar, Siti Zawiah

2013-02-01

To compare 5% dextrose-0.9% saline against 0.9% saline solution in the intravenous rehydration of hyperemesis gravidarum. Women at their first hospitalization for hyperemesis gravidarum were enrolled on admission to the ward and randomly assigned to receive either 5% dextrose-0.9% saline or 0.9% saline by intravenous infusion at a rate 125 mL/h over 24 hours in a double-blind trial. All participants also received thiamine and an antiemetic intravenously. Oral intake was allowed as tolerated. Primary outcomes were resolution of ketonuria and well-being (by 10-point visual numerical rating scale) at 24 hours. Nausea visual numerical rating scale scores were obtained every 8 hours for 24 hours. Persistent ketonuria rates after the 24-hour study period were 10 of 101 (9.9%) compared with 11 of 101 (10.9%) (P>.99; relative risk 0.9, 95% confidence interval 0.4-2.2) and median (interquartile range) well-being scores at 24 hours were 9 (8-10) compared with 9 (8-9.5) (P=.73) in the 5% dextrose-0.9% saline and 0.9% saline arms, respectively. Repeated measures analysis of variance of the nausea visual numerical rating scale score as assessed every 8 hours during the 24-hour study period showed a significant difference in favor of the 5% dextrose-0.9% saline arm (P=.046) with the superiority apparent at 8 and 16 hours, but the advantage had dissipated by 24 hours. Secondary outcomes of vomiting, resolution of hyponatremia, hypochloremia and hypokalemia, length of hospitalization, duration of intravenous antiemetic, and rehydration were not different. Intravenous rehydration with 5% dextrose-0.9% saline or 0.9% saline solution in women hospitalized for hyperemesis gravidarum produced similar outcomes. ISRCTN Register, www.controlled-trials.com/isrctn, ISRCTN65014409. I.

Recent advances in analysis and prediction of Rock Falls, Rock Slides, and Rock Avalanches using 3D point clouds

Science.gov (United States)

Abellan, A.; Carrea, D.; Jaboyedoff, M.; Riquelme, A.; Tomas, R.; Royan, M. J.; Vilaplana, J. M.; Gauvin, N.

2014-12-01

The acquisition of dense terrain information using well-established 3D techniques (e.g. LiDAR, photogrammetry) and the use of new mobile platforms (e.g. Unmanned Aerial Vehicles) together with the increasingly efficient post-processing workflows for image treatment (e.g. Structure From Motion) are opening up new possibilities for analysing, modeling and predicting rock slope failures. Examples of applications at different scales ranging from the monitoring of small changes at unprecedented level of detail (e.g. sub millimeter-scale deformation under lab-scale conditions) to the detection of slope deformation at regional scale. In this communication we will show the main accomplishments of the Swiss National Foundation project "Characterizing and analysing 3D temporal slope evolution" carried out at Risk Analysis group (Univ. of Lausanne) in close collaboration with the RISKNAT and INTERES groups (Univ. of Barcelona and Univ. of Alicante, respectively). We have recently developed a series of innovative approaches for rock slope analysis using 3D point clouds, some examples include: the development of semi-automatic methodologies for the identification and extraction of rock-slope features such as discontinuities, type of material, rockfalls occurrence and deformation. Moreover, we have been improving our knowledge in progressive rupture characterization thanks to several algorithms, some examples include the computing of 3D deformation, the use of filtering techniques on permanently based TLS, the use of rock slope failure analogies at different scales (laboratory simulations, monitoring at glacier's front, etc.), the modelling of the influence of external forces such as precipitation on the acceleration of the deformation rate, etc. We have also been interested on the analysis of rock slope deformation prior to the occurrence of fragmental rockfalls and the interaction of this deformation with the spatial location of future events. In spite of these recent advances

Investigation of Lake Water Salinity by Using Four-Band Salinity Algorithm on WorldView-2 Satellite Image for a Saline Industrial Lake

Science.gov (United States)

Budakoǧlu, Murat; Karaman, Muhittin; Damla Uça Avcı, Z.; Kumral, Mustafa; Geredeli (Yılmaz), Serpil

2014-05-01

Salinity of a lake is an important characteristic since, these are potentially industrial lakes and the degree of salinity can significantly be used for determination of mineral resources and for the production management. In the literature, there are many studies of using satellite data for salinity related lake studies such as determination of salinity distribution and detection of potential freshwater sources in less salt concentrated regions. As the study area Lake Acigol, located in Denizli (Turkey) was selected. With it's saline environment, it's the major sodium sulphate production resource of Turkey. In this study, remote sensing data and data from a field study was used and correlated. Remote sensing is an efficient tool to monitor and analyze lake properties by using it complementary to field data. Worldview-2 satellite data was used in this study which consists of 8 bands. At the same time with the satellite data acquisition, a field study was conducted to collect the salinity values in 17 points of the laker with using YSI 556 Multiparametre for measurements. The values were measured as salinity amount in grams per kilogram solution and obtained as ppt unit. It was observed that the values vary from 34 ppt - 40.1 ppt and the average is 38.056 ppt. In Thalassic serie, the lake was in mixoeuhaline state in the time of issue. As a first step, ATCOR correction was performed on satellite image for atmospheric correction. There were some clouds on the lake field, hence it was decided to continue the study by using the 12 sampling points which were clear on the image. Then, for each sampling point, a spectral value was obtained by calculating the average at a 11*11 neighborhood. The relation between the spectral reflectance values and the salinity was investigated. The 4-band algorithm, which was used for determination of chlorophyll-a distribution in highly turbid coastal environment by Wei (2012) was applied. Salinity α (Λi-1 / Λj-1) * (Λk-1 / Λm-1) (i

Variscan thrusting in I- and S-type granitic rocks of the Tribeč Mountains, Western Carpathians (Slovakia: evidence from mineral compositions and monazite dating

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Broska Igor

2015-12-01

Full Text Available The Tribeč granitic core (Tatric Superunit, Western Carpathians, Slovakia is formed by Devonian/Lower Carboniferous, calc-alkaline I- and S-type granitic rocks and their altered equivalents, which provide a rare opportunity to study the Variscan magmatic, post-magmatic and tectonic evolution. The calculated P-T-X path of I-type granitic rocks, based on Fe-Ti oxides, hornblende, titanite and mica-bearing equilibria, illustrates changes in redox evolution. There is a transition from magmatic stage at T ca. 800–850 °C and moderate oxygen fugacity (FMQ buffer to an oxidation event at 600 °C between HM and NNO up to the oxidation peak at 480 °C and HM buffer, to the final reduction at ca. 470 °C at ΔNN= 3.3. Thus, the post-magmatic Variscan history recorded in I-type tonalites shows at early stage pronounced oxidation and low temperature shift back to reduction. The S-type granites originated at temperature 700–750 °C at lower water activity and temperature. The P-T conditions of mineral reactions in altered granitoids at Variscan time (both I and S-types correspond to greenschist facies involving formation of secondary biotite. The Tribeč granite pluton recently shows horizontal and vertical zoning: from the west side toward the east S-type granodiorites replace I-type tonalites and these medium/coarse-grained granitoids are vertically overlain by their altered equivalents in greenschist facies. Along the Tribeč mountain ridge, younger undeformed leucocratic granite dykes in age 342±4.4 Ma cut these metasomatically altered granitic rocks and thus post-date the alteration process. The overlaying sheet of the altered granites is in a low-angle superposition on undeformed granitoids and forms “a granite duplex” within Alpine Tatric Superunit, which resulted from a syn-collisional Variscan thrusting event and melt formation ~340 Ma. The process of alteration may have been responsible for shifting the oxidation trend to the observed

Environmental Evaluation of Soil Salinity with Various Watering Technologies Assessment.

Science.gov (United States)

Seitkaziev, Adeubay; Shilibek, Kenzhegali; Fakhrudenova, Idiya; Salybayev, Satybaldy; Zhaparova, Sayagul; Duisenbayeva, Saule; Bayazitova, Zulfia; Aliya, Maimakova; Seitkazieva, Karlygash; Aubakirov, Hamit

2018-01-01

  The purpose of this study is to develop mathematical tools for evaluating the level of environmental safety of various watering technologies. A set of indicators, was developed with regard to the natural factors, the nature of the man-induced load, degradation type, and characteristics of the disruption of humification conditions. Thermal and physical characteristics of the soil, the state of its surface, and meteorological factors, including air temperature, relative humidity, precipitation, wind speed, solar radiation, etc. were studied with a view to determining the heat and air exchange in the soil. An environmental evaluation of the methods for saline land development was conducted with regard to the heat and moisture supply. This tool can be used to determine the level of environmental safety of soil salinization during the environmental evaluation of the investigation of soil salinity with various watering technologies.

A system of nomenclature for rocks in Olkiluoto

International Nuclear Information System (INIS)

Mattila, J.

2006-06-01

Due to international interest in the Finnish deep repository project at Olkiluoto (SW Finland) and the need for collaboration between scientists involved in site investigations for the disposal of spent nuclear fuel in other countries, a well-documented system of rock nomenclature is required, based on existing classification schemes and international recommendations. The BGS (British Geological Survey) rock classification scheme is the most comprehensive rock classification scheme and the basic principles behind it are utilised for the system of nomenclature for rocks in Olkiluoto. The BGS classification system is based on the use of descriptive names and a clear hierarchy, making it possible to classify rocks at different levels depending on the specific goals of the study, the level of available information, and the expertise of the user. Each rock type is assigned a root name, which is based on structural and textural characteristics or modal compositions of the rock and the root names are refined with qualifier terms as prefixes. Qualifier terms refer to the structure or modal composition of the rock. The bedrock at the Olkiluoto site consists of metamorphic and igneous rocks. The metamorphic rocks consist of migmatitic gneisses and (non-migmatitic) gneisses, which are further divided according to their structural characteristics and modal compositions, the former into stromatic, veined, diatexitic gneisses, the latter into mica, quartz, mafic and TGG gneisses. Igneous rocks consist of pegmatitic granites, K-feldspar porphyry and diabases. (orig.)

Numerical assessment of the origin of deep salinity in a low permeability fractured medium

International Nuclear Information System (INIS)

Guimera, Jordi; Ruiz, Eduardo; Luna, Miguel; Arcos, David; Domenech, Cristina; Jordana, Salvador; Saegusa, Hiromitsu; Iwatsuki, Teruki

2007-01-01

Many possible origins have been proposed for the saline groundwater observed in many deep geological environments. In particular, samples obtained from deep boreholes located in granite at the Mizunami Underground Research Laboratory in Central Japan show total dissolved solids increasing to 50 mmol/L at depths below 800 m. Different hypothesis have been formulated to explain the observed fluid composition, among them, long-term water-rock interaction, mixing with residual fluids of magmatic origin and relict seawater dating from Miocene times. A review of the hydrochemical and isotopic data suggests that the three above hypotheses may be valid, at least to different degrees, or that processes acting over more recent geological times may be involved. The origin of the salinity was assessed by simulating land emersion by means of changing the upper recharge boundary. In this manner the Miocene seawater was modeled as being continually mixed with fresh water until the present time. The effects of different retardation processes were considered by varying factors such as matrix diffusion and fracture conductivity. Finally, geochemical reactions reproduced trends in major ions and master variables. This study shows that the salinity observed in the boreholes can be explained qualitatively as residual Miocene age seawater subjected to alteration due to long-term contact with the host material and continuous mixing with meteoric groundwater. (authors)

Correlation between thermal gradient and flexure-type deformation as a potential trigger for exfoliation-related rock falls (Invited)

Science.gov (United States)

Collins, B. D.; Stock, G. M.

2010-12-01

temperatures. Consecutive terrestrial lidar data sets collected at a 12-hour interval during this period confirm the magnitude and geometric configuration of deformation. Temperature and light data indicate a direct link to flake deformation, with peak expansion (crack opening) in late-afternoon, within four hours of peak solar radiation and within two hours after peak temperatures (up to 50°C). Likewise, peak contraction (crack closing) occurs in mid-morning at opposite diurnal cycle, synchronous with low solar radiation and air temperature (down to -1°C). We interpret the lag between solar radiation, temperature and deformation to be caused by the response time needed for thermal propagation through the granitic flake itself, but infer that temperature may play the dominant role. With continued data collection we anticipate assessing potential cumulative deformation of the flake, which could contribute to moment-inducing tensile stresses within the entire flake or to crack tip propagation at the attachment points. Thus, this data may provide an explanation for many exfoliation-type rock falls occurring in Yosemite and elsewhere.

Qualitative and quantitative changes in detrital reservoir rocks caused by CO2-brine-rock interactions during first injection phases (Utrillas sandstones, northern Spain)

Science.gov (United States)

Berrezueta, E.; Ordóñez-Casado, B.; Quintana, L.

2016-01-01

The aim of this article is to describe and interpret qualitative and quantitative changes at rock matrix scale of lower-upper Cretaceous sandstones exposed to supercritical (SC) CO2 and brine. The effects of experimental injection of CO2-rich brine during the first injection phases were studied at rock matrix scale, in a potential deep sedimentary reservoir in northern Spain (Utrillas unit, at the base of the Cenozoic Duero Basin).Experimental CO2-rich brine was exposed to sandstone in a reactor chamber under realistic conditions of deep saline formations (P ≈ 7.8 MPa, T ≈ 38 °C and 24 h exposure time). After the experiment, exposed and non-exposed equivalent sample sets were compared with the aim of assessing possible changes due to the effect of the CO2-rich brine exposure. Optical microscopy (OpM) and scanning electron microscopy (SEM) aided by optical image analysis (OIA) were used to compare the rock samples and get qualitative and quantitative information about mineralogy, texture and pore network distribution. Complementary chemical analyses were performed to refine the mineralogical information and to obtain whole rock geochemical data. Brine composition was also analyzed before and after the experiment.The petrographic study of contiguous sandstone samples (more external area of sample blocks) before and after CO2-rich brine injection indicates an evolution of the pore network (porosity increase ≈ 2 %). It is probable that these measured pore changes could be due to intergranular quartz matrix detachment and partial removal from the rock sample, considering them as the early features produced by the CO2-rich brine. Nevertheless, the whole rock and brine chemical analyses after interaction with CO2-rich brine do not present important changes in the mineralogical and chemical configuration of the rock with respect to initial conditions, ruling out relevant precipitation or dissolution at these early stages to rock-block scale. These results

Martian soil stratigraphy and rock coatings observed in color-enhanced Viking Lander images

Science.gov (United States)

Strickland, E. L., III

1979-01-01

Subtle color variations of martian surface materials were enhanced in eight Viking Lander (VL) color images. Well-defined soil units recognized at each site (six at VL-1 and four at VL-2), are identified on the basis of color, texture, morphology, and contact relations. The soil units at the Viking 2 site form a well-defined stratigraphic sequence, whereas the sequence at the Viking 1 site is only partially defined. The same relative soil colors occur at the two sites, suggesting that similar soil units are widespread on Mars. Several types of rock surface materials can be recognized at the two sites; dark, relatively 'blue' rock surfaces are probably minimally weathered igneous rock, whereas bright rock surfaces, with a green/(blue + red) ratio higher than that of any other surface material, are interpreted as a weathering product formed in situ on the rock. These rock surface types are common at both sites. Soil adhering to rocks is common at VL-2, but rare at VL-1. The mechanism that produces the weathering coating on rocks probably operates planet-wide.

Influence of substrate rocks on Fe-Mn crust composition

Science.gov (United States)

Hein, J.R.; Morgan, C.L.

1999-01-01

Principal Component and other statistical analyses of chemical and mineralogical data of Fe-Mn oxyhydroxide crusts and their underlying rock substrates in the central Pacific indicate that substrate rocks do not influence crust composition. Two ridges near Johnston Atoll were dredged repetitively and up to seven substrate rock types were recovered from small areas of similar water depths. Crusts were analyzed mineralogically and chemically for 24 elements, and substrates were analyzed mineralogically and chemically for the 10 major oxides. Compositions of crusts on phosphatized substrates are distinctly different from crusts on substrates containing no phosphorite. However, that relationship only indicates that the episodes of phosphatization that mineralized the substrate rocks also mineralized the crusts that grew on them. A two-fold increase in copper contents in crusts that grew on phosphatized clastic substrate rocks, relative to crusts on other substrate rock types, is also associated with phosphatization and must have resulted from chemical reorganization during diagenesis. Phosphatized crusts show increases in Sr, Zn, Ca, Ba, Cu, Ce, V, and Mo contents and decreases in Fe, Si, and As contents relative to non-phosphatized crusts. Our statistical results support previous studies which show that crust compositions reflect predominantly direct precipitation from seawater (hydrogenetic), and to lesser extents reflect detrital input and diagenetic replacement of parts of the older crust generation by carbonate fluorapatite.

Mechanisms controlling rock coast evolution in paraglacial landscapes - examples from Arctic, Antarctic and Scandinavian regions

Science.gov (United States)

Strzelecki, M. C.; Lim, M.; Kasprzek, M.; Swirad, Z. M.; Rachlewicz, G.; Migoń, P.; Pawlowski, L.; Jaskolski, M.

2017-12-01

This paper presents the results of an investigation into the processes controlling development of paraglacial rock coast systems in Hornsund, Svalbard, Admiralty Bay, South Shetland Islands and Gotland Island, Scandinavia. A suite of nested geomorphological and geophysical methods have been applied to characterize the functioning of rock cliffs, shore platforms and stacks influenced by lithological control and geomorphic processes driven by paraglacial coast environments - both in glaciated and deglaciated study sites. Rock hardness, quantified by Schmidt hammer rebound tests, demonstrate strong spatial control on the degree of rock weathering (rock strength) along studied rock coasts. Elevation controlled geomorphic zones are identified and linked to distinct processes and mechanisms, transitioning from peak hardness values at the icefoot/sea-ice through the wave and storm dominated scour zones to the lowest values on the cliff tops, where the effects of periglacial weathering dominate. Observations of rock surface change using a traversing micro-erosion meter (TMEM) indicate that significant changes in erosion rates occur at the junction between shore platform and the cliff toe, where rock erosion is facilitated by frequent wetting and drying and operation of nivation and sea ice processes (formation and melting of snow patches and icefoot complexes). Electrical resistivity tomography (ERT) surveys have been used to investigate frozen ground control on rock coast dynamics and reveal the strong interaction with marine processes in polar coastal settings. In Gotland, Scandinavia the morphology of rocky coastal landforms (rauks) bear traces of numerous environmental changes that occurred in Baltic region over the Holocene including salinity, temperature, ice-cover/storminess and relative sea-level. The results are synthesised to propose a new conceptual model of paraglacial rock coast systems, with the aim of contributing towards a unifying concept of cold region

Estimating the Wet-Rock P-Wave Velocity from the Dry-Rock P-Wave Velocity for Pyroclastic Rocks

Science.gov (United States)

Kahraman, Sair; Fener, Mustafa; Kilic, Cumhur Ozcan

2017-07-01

Seismic methods are widely used for the geotechnical investigations in volcanic areas or for the determination of the engineering properties of pyroclastic rocks in laboratory. Therefore, developing a relation between the wet- and dry-rock P-wave velocities will be helpful for engineers when evaluating the formation characteristics of pyroclastic rocks. To investigate the predictability of the wet-rock P-wave velocity from the dry-rock P-wave velocity for pyroclastic rocks P-wave velocity measurements were conducted on 27 different pyroclastic rocks. In addition, dry-rock S-wave velocity measurements were conducted. The test results were modeled using Gassmann's and Wood's theories and it was seen that estimates for saturated P-wave velocity from the theories fit well measured data. For samples having values of less and greater than 20%, practical equations were derived for reliably estimating wet-rock P-wave velocity as function of dry-rock P-wave velocity.

Correlations between ultrasonic pulse wave velocities and rock properties of quartz-mica schist

Directory of Open Access Journals (Sweden)

Bharti Chawre

2018-06-01

Full Text Available Physico-mechanical properties are critically important parameters for rocks. This study aims to examine some of the rock properties of quartz-mica schist (QMS rocks in a cost-effective manner by establishing correlations between non-destructive and destructive tests. Using simple regression analysis, good correlations were obtained between the pulse wave velocities and the properties of QMS rocks. The results were further improved by using multiple regression analysis as compared to those obtained by the simple linear regression analysis. The results were also compared to the ones obtained by other empirical equations available. The general equations encompassing all types of rocks did not give reliable results of rock properties and showed large relative errors, ranging from 23% to 1146%. It is suggested that empirical correlations must be investigated separately for different types of rocks. The general empirical equations should not be used for the design and planning purposes before they are verified at least on one rock sample from the project site, as they may contain large unacceptable errors. Keywords: Pulse wave velocity, Physico-mechanical properties, Quartz-mica schist (QMS rocks, Non-destructive methods, Static elastic constants, Dynamic elastic constants

How Does Salinity Shape Bacterial and Fungal Microbiomes of Alnus glutinosa Roots?

Science.gov (United States)

Thiem, Dominika; Gołębiewski, Marcin; Hulisz, Piotr; Piernik, Agnieszka; Hrynkiewicz, Katarzyna

2018-01-01

Black alder (Alnus glutinosa Gaertn.) belongs to dual mycorrhizal trees, forming ectomycorrhizal (EM) and arbuscular (AM) root structures, as well as represents actinorrhizal plants that associate with nitrogen-fixing actinomycete Frankia sp. We hypothesized that the unique ternary structure of symbionts can influence community structure of other plant-associated microorganisms (bacterial and fungal endophytes), particularly under seasonally changing salinity in A. glutinosa roots. In our study we analyzed black alder root bacterial and fungal microbiome present at two forest test sites (saline and non-saline) in two different seasons (spring and fall). The dominant type of root microsymbionts of alder were ectomycorrhizal fungi, whose distribution depended on site (salinity): Tomentella, Lactarius, and Phialocephala were more abundant at the saline site. Mortierella and Naucoria (representatives of saprotrophs or endophytes) displayed the opposite tendency. Arbuscular mycorrhizal fungi belonged to Glomeromycota (orders Paraglomales and Glomales), however, they represented less than 1% of all identified fungi. Bacterial community structure depended on test site but not on season. Sequences affiliated with Rhodanobacter, Granulicella, and Sphingomonas dominated at the saline site, while Bradyrhizobium and Rhizobium were more abundant at the non-saline site. Moreover, genus Frankia was observed only at the saline site. In conclusion, bacterial and fungal community structure of alder root microsymbionts and endophytes depends on five soil chemical parameters: salinity, phosphorus, pH, saturation percentage (SP) as well as total organic carbon (TOC), and seasonality does not appear to be an important factor shaping microbial communities. Ectomycorrhizal fungi are the most abundant symbionts of mature alders growing in saline soils. However, specific distribution of nitrogen-fixing Frankia (forming root nodules) and association of arbuscular fungi at early stages of

'Escher' Rock

Science.gov (United States)

2004-01-01

[figure removed for brevity, see original site] Chemical Changes in 'Endurance' Rocks [figure removed for brevity, see original site] Figure 1 This false-color image taken by NASA's Mars Exploration Rover Opportunity shows a rock dubbed 'Escher' on the southwestern slopes of 'Endurance Crater.' Scientists believe the rock's fractures, which divide the surface into polygons, may have been formed by one of several processes. They may have been caused by the impact that created Endurance Crater, or they might have arisen when water leftover from the rock's formation dried up. A third possibility is that much later, after the rock was formed, and after the crater was created, the rock became wet once again, then dried up and developed cracks. Opportunity has spent the last 14 sols investigating Escher, specifically the target dubbed 'Kirchner,' and other similar rocks with its scientific instruments. This image was taken on sol 208 (Aug. 24, 2004) by the rover's panoramic camera, using the 750-, 530- and 430-nanometer filters. The graph above shows that rocks located deeper into 'Endurance Crater' are chemically altered to a greater degree than rocks located higher up. This chemical alteration is believed to result from exposure to water. Specifically, the graph compares ratios of chemicals between the deep rock dubbed 'Escher,' and the more shallow rock called 'Virginia,' before (red and blue lines) and after (green line) the Mars Exploration Rover Opportunity drilled into the rocks. As the red and blue lines indicate, Escher's levels of chlorine relative to Virginia's went up, and sulfur down, before the rover dug a hole into the rocks. This implies that the surface of Escher has been chemically altered to a greater extent than the surface of Virginia. Scientists are still investigating the role water played in influencing this trend. These data were taken by the rover's alpha particle X-ray spectrometer.

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai, southern China

Science.gov (United States)

Li, Qinghua; Zhang, Yanpeng; Chen, Wen; Yu, Shaowen

2018-03-01

Salinization in coastal aquifers is usually related to both seawater intrusion and water-rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl-, Na+, Ca2+, Mg2+ and SO4 2- ), as well as the isotopic content and ratios (2H, 18O, 87Sr/86Sr and 13C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.

Geochemical evolution of groundwater salinity at basin scale: a case study from Datong basin, Northern China.

Science.gov (United States)

Wu, Ya; Wang, Yanxin

2014-05-01

A hydrogeochemical investigation using integrated methods of stable isotopes ((18)O, (2)H), (87)Sr/(86)Sr ratios, Cl/Br ratios, chloride-mass balance, mass balance and hydrogeochemical modeling was conducted to interpret the geochemical evolution of groundwater salinity in Datong basin, northern China. The δ(2)H, δ(18)O ratios in precipitation exhibited a local meteoric water line of δ(2)H = 6.4 δ(18)O -5 (R(2) = 0.94), while those in groundwater suggested their meteoric origin in a historically colder climatic regime with a speculated recharge rate of less than 20.5 mm overall per year, in addition to recharge from a component of deep residual ancient lake water enriched with Br. According to the Sr isotope binary mixing model, the mixing of recharges from the Shentou karst springs (24%), the western margins (11%) and the eastern margins (65%) accounts for the groundwater from the deep aquifers of the down-gradient parts in the central basin is a possible mixing mechanism. In Datong, hydrolysis of silicate minerals is the most important hydrogeochemical process responsible for groundwater chemistry, in addition to dissolution of carbonate and evaporites. In the recharge areas, silicate chemical weathering is typically at the bisiallitization stage, while that in the central basin is mostly at the monosiallitization stage with limited evidence of being in equilibrium with gibbsite. Na exchange with bound Ca, Mg prevails at basin scale, and intensifies with groundwater salinity, while Ca, Mg exchange with bound Na locally occurs in the east pluvial and alluvial plains. Although groundwater salinity increases with the progress of water-rock/sediment interactions along the flow path, as a result of carbonate solubility control and continuous evapotranspiration, Na-HCO3 and Na-Cl-SO4 types of water are usually characterized respectively in the deep and the shallow aquifers of an inland basin with a silicate terrain in an arid climatic regime.

Saline agriculture in Mediterranean environments

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Albino Maggio

2011-03-01

Full Text Available Salinization is increasingly affecting world's agricultural land causing serious yield loss and soil degradation. Understanding how we could improve crop productivity in salinized environments is therefore critical to meet the challenging goal of feeding 9.3 billion people by 2050. Our comprehension of fundamental physiological mechanisms in plant salt stress adaptation has greatly advanced over the last decades. However, many of these mechanisms have been linked to salt tolerance in simplified experimental systems whereas they have been rarely functionally proven in real agricultural contexts. In-depth analyses of specific crop-salinity interactions could reveal important aspects of plant salt stress adaptation as well as novel physiological/agronomic targets to improve salinity tolerance. These include the developmental role of root vs. shoot systems respect to water-ion homeostasis, morphological vs. metabolic contributions to stress adaptation, developmental processes vs. seasonal soil salinity evolution, residual effects of saline irrigation in non-irrigated crops, critical parameters of salt tolerance in soil-less systems and controlled environments, response to multiple stresses. Finally, beneficial effects of salinization on qualitative parameters such as stress-induced accumulation of high nutritional value secondary metabolites should be considered, also. In this short review we attempted to highlight the multifaceted nature of salinity in Mediterranean agricultural systems by summarizing most experimental activity carried out at the Department of Agricultural Engineering and Agronomy of University of Naples Federico II in the last few years.

N2-fixation in fababean (vicia faba l.) grown in saline and non saline conditions using 15N tracer technique

International Nuclear Information System (INIS)

Khalifa, Kh.; Kurdali, F.

2002-09-01

A pot experiment was conducted to study the performance of growing fababean and barley under saline conditions, in terms of, dry matter yield, total nitrogen and, percentages and amount of N derived from soil, fertilizer and atmosphere using 15 N isotope dilution method. Three saline treatments were performed: First, plants were grown in saline soil and irrigated with saline water (Ws Ss), Second, Plants were grown in saline soil and irrigated with saline water (Ws Ss); and Third, Plants grown in non saline soil and irrigated with saline water (Ws Sn). Furthermore, a control treatment was performed by using non-saline soil and non-saline water (Wn Sn). The different salinity treatments reduced plant growth and the reduction was more pronounced in fababean than in barley. However, under conditions of either saline soil-soft irrigation water or non saline soil-salty irrigation water, the relative growth reduction did not exceed 50% of the control; whereas, a significant negative effect was obtained when plants were grown under completely saline conditions of both soil and irrigation water. Percentage of N 2 -fixed (% Ndfa) was not negatively affected by saline conditions. However, our results clearly demonstrated that the effect of salinity in fababean was more evident on plant growth than on N 2 -fixing activity. Further studies are needed to obtain more salt tolerant faba bean genotypes in terms of growth and yield. This could be simultaneously improve yield and N 2 -fixation under sever saline conditions. (author)

Hydrological evaluation of five sedimentary rocks for high-level waste disposal

International Nuclear Information System (INIS)

Lomenick, T.F.; Kanehiro, B.Y.

1986-01-01

Utilizing performance criteria that are based upon siting guidelines issued by DOE for postclosure as well as preclosure conditions, a preliminary hydrologic evaluation and ranking is being conducted to determine the suitability of five sedimentary rocks as potential host rocks for a high-level radioactive waste repository. Based upon both quantitative and qualitative considerations, the hydrological ranking of the rocks in order of their potential as a host rock for the disposal of radioactive wastes would be shale, anhydrock, sandstone, chalk, and carbonates, with the first three rocks being significantly better than the remaining two types

Reactive solute transport in an asymmetrical fracture-rock matrix system

Science.gov (United States)

Zhou, Renjie; Zhan, Hongbin

2018-02-01

The understanding of reactive solute transport in a single fracture-rock matrix system is the foundation of studying transport behavior in the complex fractured porous media. When transport properties are asymmetrically distributed in the adjacent rock matrixes, reactive solute transport has to be considered as a coupled three-domain problem, which is more complex than the symmetric case with identical transport properties in the adjacent rock matrixes. This study deals with the transport problem in a single fracture-rock matrix system with asymmetrical distribution of transport properties in the rock matrixes. Mathematical models are developed for such a problem under the first-type and the third-type boundary conditions to analyze the spatio-temporal concentration and mass distribution in the fracture and rock matrix with the help of Laplace transform technique and de Hoog numerical inverse Laplace algorithm. The newly acquired solutions are then tested extensively against previous analytical and numerical solutions and are proven to be robust and accurate. Furthermore, a water flushing phase is imposed on the left boundary of system after a certain time. The diffusive mass exchange along the fracture/rock matrixes interfaces and the relative masses stored in each of three domains (fracture, upper rock matrix, and lower rock matrix) after the water flushing provide great insights of transport with asymmetric distribution of transport properties. This study has the following findings: 1) Asymmetric distribution of transport properties imposes greater controls on solute transport in the rock matrixes. However, transport in the fracture is mildly influenced. 2) The mass stored in the fracture responses quickly to water flushing, while the mass stored in the rock matrix is much less sensitive to the water flushing. 3) The diffusive mass exchange during the water flushing phase has similar patterns under symmetric and asymmetric cases. 4) The characteristic distance

Geomechanical Anisotropy and Rock Fabric in Shales

Science.gov (United States)

Huffman, K. A.; Connolly, P.; Thornton, D. A.

2017-12-01

Digital rock physics (DRP) is an emerging area of qualitative and quantitative scientific analysis that has been employed on a variety of rock types at various scales to characterize petrophysical, mechanical, and hydraulic rock properties. This contribution presents a generic geomechanically focused DRP workflow involving image segmentation by geomechanical constituents, generation of finite element (FE) meshes, and application of various boundary conditions (i.e. at the edge of the domain and at boundaries of various components such as edges of individual grains). The generic workflow enables use of constituent geological objects and relationships in a computational based approach to address specific questions in a variety of rock types at various scales. Two examples are 1) modeling stress dependent permeability, where it occurs and why it occurs at the grain scale; 2) simulating the path and complexity of primary fractures and matrix damage in materials with minerals or intervals of different mechanical behavior. Geomechanical properties and fabric characterization obtained from 100 micron shale SEM images using the generic DRP workflow are presented. Image segmentation and development of FE simulation composed of relatively simple components (elastic materials, frictional contacts) and boundary conditions enable the determination of bulk static elastic properties. The procedure is repeated for co-located images at pertinent orientations to determine mechanical anisotropy. The static moduli obtained are benchmarked against lab derived measurements since material properties (esp. frictional ones) are poorly constrained at the scale of investigation. Once confidence in the input material parameters is gained, the procedure can be used to characterize more samples (i.e. images) than is possible from rock samples alone. Integration of static elastic properties with grain statistics and geologic (facies) conceptual models derived from core and geophysical logs

The effects of salinity in the soil water balance: A Budyko's approach

Science.gov (United States)

Perri, S.; Viola, F.; Molini, A.

2017-12-01

Soil degradation and water scarcity pose important constraints on productivity and development of arid and semi-arid countries. Among the main causes of loss of soil fertility, aridification and soil salinization are deeply connected threats enhanced by climate change. Assessing water availability is fundamental for a large number of applications especially in arid regions. An approach often adopted to estimate the long-term rainfall partitioning into evapotranspiration and runoff is the Budyko's curve. However, the classical Budyko framework might not be able to properly reproduce the water balance in salt affected basins, especially under elevated soil salinization conditions. Salinity is a limiting factor for plant transpiration (as well as growth) affecting both short and long term soil moisture dynamics and ultimately the hydrologic balance. Soluble salts cause a reduction of soil water potential similar to the one arising from droughts, although plant adaptations to soil salinity show extremely different traits and can vary from species to species. In a similar context, the salt-tolerance plants are expected to control the amount of soil moisture lost to transpiration in saline soils, also because salinity reduces evaporation. We propose a simple framework to include the effects of salinization on the surface energy and water balance within a simple Budyko approach. By introducing the effects of salinity in the stochastic water balance we are able to include the influence of vegetation type (i.e. in terms of salt-tolerance) on evapotranspiration-runoff partitioning under different climatic conditions. The water balance components are thus compared to data obtained from arid salt-affected regions.

One Song, Many Works: A Pluralist Ontology of Rock

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Dan Burkett

2016-01-01

Full Text Available A number of attempts have been made to construct a plausible ontology of rock music. Each of these ontologies identifies a single type of ontological entity as the “work” in rock music. Yet, all the suggestions advanced to date fail to capture some important considerations about how we engage with music of this tradition. This prompted Lee Brown to advocate a healthy skepticism of higher-order musical ontologies. I argue here that we should instead embrace a pluralist ontology of rock, an ontology that recognizes more than one kind of entity as “the work” in rock music. I contend that this approach has a number of advantages over other ontologies of rock, including that of allowing us to make some comparisons across ontological kinds.

Ground Water movement in crystalline rock aquifers

International Nuclear Information System (INIS)

Serejo, A.N.C.; Freire, C.; Siqueira, H.B. de; Frischkorn, H.; Torquato, J.R.F.; Santiago, M.M.F.; Barbosa, P.C.

1984-01-01

Ground water movement studies were performed in crystalline rock aquifers from the upper Acarau River hydrographic basin, state of Ceara, Brazil. The studies included carbon-14, 18 O/ 16 O and tritium measurements as well as chemical analysis. A total of 35 wells were surveyed during drought seasons. Carbon-14 values displayed little variation which implied that the water use was adequate despite of the slower recharge conditions. Fairly constant isotopic 18 O/ 16 O ratio values in the wells and their similarity with rainwater values indicated that the recharge is done exclusively by pluvial waters. A decreasing tendency within the tritium concentration values were interpreted as a periodic rainwater renewal for these aquifers. The chemical analysis demonstrated that there is in fact no correlation between salinity and the time the water remains in the aquifer itself. (D.J.M.) [pt

Xenon NMR measurements of permeability and tortuosity in reservoir rocks.

Science.gov (United States)

Wang, Ruopeng; Pavlin, Tina; Rosen, Matthew Scott; Mair, Ross William; Cory, David G; Walsworth, Ronald Lee

2005-02-01

In this work we present measurements of permeability, effective porosity and tortuosity on a variety of rock samples using NMR/MRI of thermal and laser-polarized gas. Permeability and effective porosity are measured simultaneously using MRI to monitor the inflow of laser-polarized xenon into the rock core. Tortuosity is determined from measurements of the time-dependent diffusion coefficient using thermal xenon in sealed samples. The initial results from a limited number of rocks indicate inverse correlations between tortuosity and both effective porosity and permeability. Further studies to widen the number of types of rocks studied may eventually aid in explaining the poorly understood connection between permeability and tortuosity of rock cores.

Ways of distinguishing epigenetic types of gray-colored rocks in sheet-infiltration deposits

International Nuclear Information System (INIS)

Rasulova, S.D.; Yashunskii, Yu.V.

1994-01-01

At an infiltration deposit of uranium in Upper-Cretaceous sandy-clay alluvial deposits (Central Kyzylkum), six stages of postsedimentation epigenetic transformations were distinguished. The genesis of altered rocks was determined mostly by mineralogical methods. A new methodological technique is suggested, which calls for analysis of the textural, structural, and mineral correspondence of ferruginous components of gray-colored and oxidized rocks in the region of their contact and makes it possible to typify epigenetic changes in conditions of repeated change in the direction of geochemical processes

The ammonium content in the Malayer igneous and metamorphic rocks (Sanandaj-Sirjan Zone, Western Iran)

Science.gov (United States)

Ahadnejad, Vahid; Hirt, Ann Marie; Valizadeh, Mohammad-Vali; Bokani, Saeed Jabbari

2011-04-01

The ammonium (NH4+) contents of the Malayer area (Western Iran) have been determined by using the colorimetric method on 26 samples from igneous and metamorphic rocks. This is the first analysis of the ammonium contents of Iranian metamorphic and igneous rocks. The average ammonium content of metamorphic rocks decreases from low-grade to high-grade metamorphic rocks (in ppm): slate 580, phyllite 515, andalusite schist 242. In the case of igneous rocks, it decreases from felsic to mafic igneous types (in ppm): granites 39, monzonite 20, diorite 17, gabbro 10. Altered granitic rocks show enrichment in NH4+ (mean 61 ppm). The high concentration of ammonium in Malayer granites may indicate metasedimentary rocks as protoliths rather than meta-igneous rocks. These granitic rocks (S-types) have high K-bearing rock-forming minerals such as biotite, muscovite and K-feldspar which their potassium could substitute with ammonium. In addition, the high ammonium content of metasediments is probably due to inheritance of nitrogen from organic matter in the original sediments. The hydrothermally altered samples of granitic rocks show highly enrichment of ammonium suggesting external sources which intruded additional content by either interaction with metasedimentary country rocks or meteoritic solutions.

On the Sources of Salinity in Groundwater under Plain Areas. Insights from {delta}{sup 18}O, {delta}{sup 2}H and Hydrochemistry in the Azul River Basin, Argentina

Energy Technology Data Exchange (ETDEWEB)

Zabala, M. E.; Varni, M.; Weinzettel, P. [Instituto de Hidrologia de llanuras, Azul (Argentina); Manzano, M. [Technical University of Cartagena (Spain)

2013-07-15

The Azul River basin, with some 6200 km{sup 2}, is located in the plains of Buenos Aires Province, Argentina. The Azul River flows along 160 km from the Tandilia Range, in the SW, to the Channel 11, in the NE. Average annual precipitation is 1005 mm (1988-2000); mean reference evapotranspiration is 1090 mm. The geology consists of Miocene to recent sediments, mostly sands and silts with some clay and calcrete layers, overlying crystalline rocks and marine sediments. The water table is shallow and groundwater in the aquifer upper 30 m displays an increasing salinity from SW to NE. The previous hypothesis to explain the salinity was infiltration of evapo-concentrated surface water, as the small soil slope in the northern basin (< 0.2%) induces rainfall accumulation in lowlands, where water evaporates prior to infiltration. But recent chemical and isotopic data reveal two salinity sources: evaporation of recent recharge water, and mixing with old saline groundwater of yet unknown origin. (author)

Effect of salinity on nitrogenase activity and composition of the active diazotrophic community in intertidal microbial mats

NARCIS (Netherlands)

Severin, I.; Confurius-Guns, V.; Stal, L.J.

2012-01-01

Microbial mats are often found in intertidal areas experiencing a large range of salinities. This study investigated the effect of changing salinities on nitrogenase activity and on the composition of the active diazotrophic community ( transcript libraries) of three types of microbial mats situated

Rock Art Paintings (Rock Inscriptions) At Gebel Abraq, South Eastern Desert, Egypt

International Nuclear Information System (INIS)

Zaghloul, E.A.; Yehia, M.A.; Elewa, H.H.

2003-01-01

This article presents rock art painting in an area located at the scarp face of Wadi Abraq (Latitude 230 28' N and Longitude 340 45' E). The site is a sandstone protruding ledge rising about 30m. above the ground level. The Gebel Abraq paintings depict a tropical fauna including Elephants, Giraffes, Cows and Ostrich denoting that the area was previously subjected to intensive rainfall during the last pluvial periods. The result was a savana type of land. During recent times, the climate became dry and the communities were forced to move to other areas wher natural springs are still flowing such as Ain Abraq and Bir Abu-Safa. The present founding of the prehistoric paintings (Graffiti) has revealed a mass of evidence that many of the concepts regarding Sahara rock art should be studied

Shallow rainwater lenses in deltaic areas with saline seepage

Directory of Open Access Journals (Sweden)

P. G. B. de Louw

2011-12-01

Full Text Available In deltaic areas with saline seepage, freshwater availability is often limited to shallow rainwater lenses lying on top of saline groundwater. Here we describe the characteristics and spatial variability of such lenses in areas with saline seepage and the mechanisms that control their occurrence and size. Our findings are based on different types of field measurements and detailed numerical groundwater models applied in the south-western delta of the Netherlands. By combining the applied techniques we could extrapolate measurements at point scale (groundwater sampling, temperature and electrical soil conductivity (TEC-probe measurements, electrical cone penetration tests (ECPT to field scale (continuous vertical electrical soundings (CVES, electromagnetic survey with EM31, and even to regional scale using helicopter-borne electromagnetic measurements (HEM. The measurements show a gradual mixing zone between infiltrating fresh rainwater and upward flowing saline groundwater. The mixing zone is best characterized by the depth of the centre of the mixing zone D_mix, where the salinity is half that of seepage water, and the bottom of the mixing zone B_mix, with a salinity equal to that of the seepage water (Cl-conc. 10 to 16 g l⁻¹. D_mix is found at very shallow depth in the confining top layer, on average at 1.7 m below ground level (b.g.l., while B_mix lies about 2.5 m b.g.l. The model results show that the constantly alternating upward and downward flow at low velocities in the confining layer is the main mechanism of mixing between rainwater and saline seepage and determines the position and extent of the mixing zone (D_mix and B_mix. Recharge, seepage flux, and drainage depth are the controlling factors.

Salinity, temperature and density data for the Canadian Beaufort Sea shelf, March 1988

Energy Technology Data Exchange (ETDEWEB)

Hopky, G E; Chiperzak, D B; Lawrence, M J

1988-01-01

This report contains salinity, temperature and density (CTD) data collected in the waters of the Canadian Beaufort Sea Shelf during March 1988. Salinity and temperature profile data were measured using a Guildline Model 8870 probe deployed from the ice surface. Ice thickness was also measured. Density was calculated using salinity and temperature values. CTD profiles were measured at five stations. The maximum depths of profiles measured from the ice surface ranged from 31.2 to 16.8 dbar. Salinity and temperature measurements ranged from 0.35 to 34.83, and -1.87 to 1.08/sup 0/C, respectively. The data presented in this report will assist in the identification and delineation of potential habitat types, as part of the Critical Arctic Estuarine and Marine Habitat Project of the Northern Oil and Gas Program. 5 refs., 7 figs., 6 tabs.

Selection of the host rock for high level radioactive waste repository in China

International Nuclear Information System (INIS)

Jin Yuanxin; Wang Wenguang; Chen Zhangru

2001-01-01

The authors has briefly introduced the experiences of the host rock selection and the host rock types in other countries for high level radioactive waste repository. The potential host rocks in China are investigated. They include granite, tuff, clay, basalt, salt, and loess. The report has expounded the distributions, scale, thickness, mineral and chemical composition, construction, petrogenesis and the ages of the rock. The possibility of these rocks as the host rock has been studied. The six pieces of distribution map of potential rocks have been made up. Through the synthetical study, it is considered that granite as the host rock of high level radioactive waste repository is possible

Correlating P-wave Velocity with the Physico-Mechanical Properties of Different Rocks

Science.gov (United States)

Khandelwal, Manoj

2013-04-01

In mining and civil engineering projects, physico-mechanical properties of the rock affect both the project design and the construction operation. Determination of various physico-mechanical properties of rocks is expensive and time consuming, and sometimes it is very difficult to get cores to perform direct tests to evaluate the rock mass. The purpose of this work is to investigate the relationships between the different physico-mechanical properties of the various rock types with the P-wave velocity. Measurement of P-wave velocity is relatively cheap, non-destructive and easy to carry out. In this study, representative rock mass samples of igneous, sedimentary, and metamorphic rocks were collected from the different locations of India to obtain an empirical relation between P-wave velocity and uniaxial compressive strength, tensile strength, punch shear, density, slake durability index, Young's modulus, Poisson's ratio, impact strength index and Schmidt hammer rebound number. A very strong correlation was found between the P-wave velocity and different physico-mechanical properties of various rock types with very high coefficients of determination. To check the sensitivity of the empirical equations, Students t test was also performed, which confirmed the validity of the proposed correlations.

Compact rock material gas permeability properties

Energy Technology Data Exchange (ETDEWEB)

Wang, Huanling, E-mail: whl_hm@163.com [Key Laboratory of Coastal Disaster and Defence, Ministry of Education, Hohai University, Nanjing 210098 (China); LML, University of Lille, Cite Scientifique, 59655 Villeneuve d’Ascq (France); Xu, Weiya; Zuo, Jing [Institutes of Geotechnical Engineering, Hohai University, Nanjing 210098 (China)

2014-09-15

Natural compact rocks, such as sandstone, granite, and rock salt, are the main materials and geological environment for storing underground oil, gas, CO{sub 2,} shale gas, and radioactive waste because they have extremely low permeabilities and high mechanical strengths. Using the inert gas argon as the fluid medium, the stress-dependent permeability and porosity of monzonitic granite and granite gneiss from an underground oil storage depot were measured using a permeability and porosity measurement system. Based on the test results, models for describing the relationships among the permeability, porosity, and confining pressure of rock specimens were analyzed and are discussed. A power law is suggested to describe the relationship between the stress-dependent porosity and permeability; for the monzonitic granite and granite gneiss (for monzonitic granite (A-2), the initial porosity is approximately 4.05%, and the permeability is approximately 10{sup −19} m{sup 2}; for the granite gneiss (B-2), the initial porosity is approximately 7.09%, the permeability is approximately 10{sup −17} m{sup 2}; and the porosity-sensitivity exponents that link porosity and permeability are 0.98 and 3.11, respectively). Compared with moderate-porosity and high-porosity rocks, for which φ > 15%, low-porosity rock permeability has a relatively lower sensitivity to stress, but the porosity is more sensitive to stress, and different types of rocks show similar trends. From the test results, it can be inferred that the test rock specimens’ permeability evolution is related to the relative particle movements and microcrack closure.

Biogeochemical cycling of arsenic in coastal salinized aquifers: Evidence from sulfur isotope study

International Nuclear Information System (INIS)

Kao, Yu-Hsuan; Wang, Sheng-Wei; Liu, Chen-Wuing; Wang, Pei-Ling; Wang, Chung-Ho; Maji, Sanjoy Kumar

2011-01-01

Arsenic (As) contamination of groundwater, accompanied by critical salinization, occurs in the southwestern coastal area of Taiwan. Statistical analyses and geochemical calculations indicate that a possible source of aqueous arsenic is the reductive dissolution of As-bearing iron oxyhydroxides. There are few reports of the influence of sulfate-sulfide redox cycling on arsenic mobility in brackish groundwater. We evaluated the contribution of sulfate reduction and sulfide re-oxidation on As enrichment using δ 34 S [SO 4 ] and δ 18 O [SO 4 ] sulfur isotopic analyses of groundwater. Fifty-three groundwater samples were divided into groups of high-As content and salinized (Type A), low-As and non-salinized (Type B), and high-As and non-salinized (Type C) groundwaters, based on hydro-geochemical analysis. The relatively high enrichment of 34 S [SO 4 ] and 18 O [SO 4 ] present in Type A, caused by microbial-mediated reduction of sulfate, and high 18 O enrichment factor (ε [SO 4 -H 2 O] ), suggests that sulfur disproportionation is an important process during the reductive dissolution of As-containing iron oxyhydroxides. Limited co-precipitation of ion-sulfide increased the rate of As liberation under anaerobic conditions. In contrast to this, Type B and Type C groundwater samples showed high δ 18 O [SO 4 ] and low δ 34 S [SO 4 ] values under mildly reducing conditions. Base on 18 O mass balance calculations, the oxide sources of sulfate are from infiltrated atmospheric O 2 , caused by additional recharge of dissolved oxygen and sulfide re-oxidation. The anthropogenic influence of extensive pumping also promotes atmospheric oxygen entry into aquifers, altering redox conditions, and increasing the rate of As release into groundwater. - Highlights: → Seawater intrusion and elevated As are the main issues of groundwater in Taiwan. → Sulfur and oxygen isotopes of sulfate were analyzed to evaluate the As mobility. → Reductive dissolution of Fe minerals and

Study of fluid inclusions in rodioactive mineralized pegmatites, dara area northern eastern desert, Egypt

International Nuclear Information System (INIS)

Ali, B.H.; Abdel Warith, A.

2003-01-01

Numerous pegmatite pockets of un zoned and zoned types are the most important rock types from the radioactive point of view. They occur at the marginal parts and higher topographic level of G.Dara younger granites. Zoned pegmatites are composed of extremely coarse-grained milky quartz core, intermediate zone and wall zone. The alteration zone is found at the contact between quartz core and intermediate zone. It is recorded the highest radioactive values due to their mineral composition, as a result of alteration processes associated with radioactive minerals. Only two alteration zones (P1 and P2) has been studied in this paper. The late magmatic alteration process (hematization, kaolinization, chloritization and fluortization) of the pegmatite resulted in the formation of chlorite, fluorite, clay minerals and carbonates (calcite) in the alteration zones as mineral assemblage. opaque minerals are found as pyrite, iron oxyhydroxide and garnet. Fluid inclusion studies by microthermometry were carried out on authigenic minerals (such as quartz and fluorite) in alteration zones (primary fluid inclusions). This study revealed that, at least two stages of the post-magmatic hydrothermal alteration are involved. The first stages of high temperature, low saline fluids are involved. The first stage is of high temperature, low saline fluids which characterized with hematization and/or chloritization resulted from fluid-rock interaction with late magmatic fluids that very probably mixed with external low salinity fluids along brittle structure. The second stage is of low temperature the main role in re high saline fluids characterized the fluoritized alteration due to consequent reaction with wall rocks and mixing with meteoric water. Mixing of low salinity meteoric water with hot a sending saline hydrothermal solution leads to ph change and continuous interaction with wall rock

Rock fragmentation

Energy Technology Data Exchange (ETDEWEB)

Brown, W.S.; Green, S.J.; Hakala, W.W.; Hustrulid, W.A.; Maurer, W.C. (eds.)

1976-01-01

Experts in rock mechanics, mining, excavation, drilling, tunneling and use of underground space met to discuss the relative merits of a wide variety of rock fragmentation schemes. Information is presented on novel rock fracturing techniques; tunneling using electron beams, thermocorer, electric spark drills, water jets, and diamond drills; and rock fracturing research needs for mining and underground construction. (LCL)

Influence of salinity and water regime on tomato for processing

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Vito Cantore

2012-03-01

Full Text Available The effects of salinity and watering regime on tomato crop are reported. The trials have been carried out over two years in Southern Italy on a deep loam soil. Three saline levels of irrigation water (with electrical conductivity of 0.5, 5 and 10 dS m-1, three watering regimes (at 20, 40 and 60% of available water depletion, and two cultivars (HLY19 and Perfectpeel were compared. The overall results related to the salinity tolerance are in agreement with those from the literature indicating that water salinity reduced marketable yield by 55% in respect to the control treatments. The irrigation regimes that provided higher total and marketable yield were at 40 and 60% of available water depletion (on average, 90.5 and 58.1 Mg ha-1 against 85.3 and 55.5 Mg ha-1 of the 20% available water depletion. Saline and irrigation treatments did not affect sunburned fruits, while affected incidence of fruits with blossom-end rot. The former disease appeared more dramatically in saline treatments (+28% in respect to the control, and occurred mainly in HLY19. The disease incidence was by 52% lower in W2 respect to the W1 and W3. Fruit firmness was higher in S0, whereas it was not affected by irrigation regimes. Total soluble solids and dry matter content of tomato fruits were increased by salinity, whereas it was not affected by irrigation regimes and cultivars. The pH and the titratable acidity remained unchanged between the years, the cultivar and the saline and irrigation treatments. Similarly to the last parameters, the fruit ascorbic acid content remained unchanged in relation to the treatments, but it was higher in HLY19. The recommended thresholds of easily available water to preserve total and marketable yield were at 40 and 60%, respectively. Watering more frequently, instead, on the soil type of the trial, probably caused water-logging and root hypoxia affecting negatively yield.

Salinity Affects the Composition of the Aerobic Methanotroph Community in Alkaline Lake Sediments from the Tibetan Plateau.

Science.gov (United States)

Deng, Yongcui; Liu, Yongqin; Dumont, Marc; Conrad, Ralf

2017-01-01

Lakes are widely distributed on the Tibetan Plateau, which plays an important role in natural methane emission. Aerobic methanotrophs in lake sediments reduce the amount of methane released into the atmosphere. However, no study to date has analyzed the methanotroph community composition and their driving factors in sediments of these high-altitude lakes (>4000 m). To provide new insights on this aspect, the abundance and composition in the sediments of six high-altitude alkaline lakes (including both freshwater and saline lakes) on the Tibetan Plateau were studied. The quantitative PCR, terminal restriction fragment length polymorphism, and 454-pyrosequencing methods were used to target the pmoA genes. The pmoA gene copies ranged 10 4 -10 6 per gram fresh sediment. Type I methanotrophs predominated in Tibetan lake sediments, with Methylobacter and uncultivated type Ib methanotrophs being dominant in freshwater lakes and Methylomicrobium in saline lakes. Combining the pmoA-pyrosequencing data from Tibetan lakes with other published pmoA-sequencing data from lake sediments of other regions, a significant salinity and alkalinity effect (P = 0.001) was detected, especially salinity, which explained ∼25% of methanotroph community variability. The main effect was Methylomicrobium being dominant (up to 100%) in saline lakes only. In freshwater lakes, however, methanotroph composition was relatively diverse, including Methylobacter, Methylocystis, and uncultured type Ib clusters. This study provides the first methanotroph data for high-altitude lake sediments (>4000 m) and shows that salinity is a driving factor for the community composition of aerobic methanotrophs.

Dietary flexibility in three representative waterbirds across salinity and depth gradients in salt ponds of San Francisco Bay

Science.gov (United States)

Takekawa, John Y.; Miles, A.K.; Tsao-Melcer, D. C.; Schoellhamer, D.H.; Fregien, S.; Athearn, N.D.

2009-01-01

Salt evaporation ponds have existed in San Francisco Bay, California, for more than a century. In the past decade, most of the salt ponds have been retired from production and purchased for resource conservation with a focus on tidal marsh restoration. However, large numbers of waterbirds are found in salt ponds, especially during migration and wintering periods. The value of these hypersaline wetlands for waterbirds is not well understood, including how different avian foraging guilds use invertebrate prey resources at different salinities and depths. The aim of this study was to investigate the dietary flexibility of waterbirds by examining the population number and diet of three feeding guilds across a salinity and depth gradient in former salt ponds of the Napa-Sonoma Marshes. Although total invertebrate biomass and species richness were greater in low than high salinity salt ponds, waterbirds fed in ponds that ranged from low (20 g l-1) to very high salinities (250 g l -1). American avocets (surface sweeper) foraged in shallow areas at pond edges and consumed a wide range of prey types (8) including seeds at low salinity, but preferred brine flies at mid salinity (40-80 g l-1). Western sandpipers (prober) focused on exposed edges and shoal habitats and consumed only a few prey types (2-4) at both low and mid salinities. Suitable depths for foraging were greatest for ruddy ducks (diving benthivore) that consumed a wide variety of invertebrate taxa (5) at low salinity, but focused on fewer prey (3) at mid salinity. We found few brine shrimp, common in higher salinity waters, in the digestive tracts of any of these species. Dietary flexibility allows different guilds to use ponds across a range of salinities, but their foraging extent is limited by available water depths. ?? 2009 USGS, US Government.

Cl/Br ratios and chlorine isotope evidences for groundwater salinization and its impact on groundwater arsenic, fluoride and iodine enrichment in the Datong basin, China

Energy Technology Data Exchange (ETDEWEB)

Li, Junxia; Wang, Yanxin, E-mail: yx.wang@cug.edu.cn; Xie, Xianjun

2016-02-15

In order to identify the salinization processes and its impact on arsenic, fluoride and iodine enrichment in groundwater, hydrogeochemical and environmental isotope studies have been conducted on groundwater from the Datong basin, China. The total dissolved solid (TDS) concentrations in groundwater ranged from 451 to 8250 mg/L, and 41% of all samples were identified as moderately saline groundwater with TDS of 3000–10,000 mg/L. The results of groundwater Cl concentrations, Cl/Br molar ratio and Cl isotope composition suggest that three processes including water-rock interaction, surface saline soil flushing, and evapotranspiration result in the groundwater salinization in the study area. The relatively higher Cl/Br molar ratio in groundwater from multiple screening wells indicates the contribution of halite dissolution from saline soil flushed by vertical infiltration to the groundwater salinization. However, the results of groundwater Cl/Br molar ratio model indicate that the effect of saline soil flushing practice is limited to account for the observed salinity variation in groundwater. The plots of groundwater Cl vs. Cl/Br molar ratio, and Cl vs δ{sup 37}Cl perform the dominant effects of evapotranspiration on groundwater salinization. Inverse geochemical modeling results show that evapotranspiration may cause approximately 66% loss of shallow groundwater to account for the observed hydrochemical pattern. Due to the redox condition fluctuation induced by irrigation activities and evapotranspiration, groundwater salinization processes have negative effects on groundwater arsenic enrichment. For groundwater iodine and fluoride enrichment, evapotranspiration partly accounts for their elevation in slightly saline water. However, too strong evapotranspiration would restrict groundwater fluoride concentration due to the limitation of fluorite solubility. - Highlights: • Natural high arsenic, fluoride and iodine groundwater co-occur with saline water. �

Cl/Br ratios and chlorine isotope evidences for groundwater salinization and its impact on groundwater arsenic, fluoride and iodine enrichment in the Datong basin, China

International Nuclear Information System (INIS)

Li, Junxia; Wang, Yanxin; Xie, Xianjun

2016-01-01

In order to identify the salinization processes and its impact on arsenic, fluoride and iodine enrichment in groundwater, hydrogeochemical and environmental isotope studies have been conducted on groundwater from the Datong basin, China. The total dissolved solid (TDS) concentrations in groundwater ranged from 451 to 8250 mg/L, and 41% of all samples were identified as moderately saline groundwater with TDS of 3000–10,000 mg/L. The results of groundwater Cl concentrations, Cl/Br molar ratio and Cl isotope composition suggest that three processes including water-rock interaction, surface saline soil flushing, and evapotranspiration result in the groundwater salinization in the study area. The relatively higher Cl/Br molar ratio in groundwater from multiple screening wells indicates the contribution of halite dissolution from saline soil flushed by vertical infiltration to the groundwater salinization. However, the results of groundwater Cl/Br molar ratio model indicate that the effect of saline soil flushing practice is limited to account for the observed salinity variation in groundwater. The plots of groundwater Cl vs. Cl/Br molar ratio, and Cl vs δ"3"7Cl perform the dominant effects of evapotranspiration on groundwater salinization. Inverse geochemical modeling results show that evapotranspiration may cause approximately 66% loss of shallow groundwater to account for the observed hydrochemical pattern. Due to the redox condition fluctuation induced by irrigation activities and evapotranspiration, groundwater salinization processes have negative effects on groundwater arsenic enrichment. For groundwater iodine and fluoride enrichment, evapotranspiration partly accounts for their elevation in slightly saline water. However, too strong evapotranspiration would restrict groundwater fluoride concentration due to the limitation of fluorite solubility. - Highlights: • Natural high arsenic, fluoride and iodine groundwater co-occur with saline water. • Groundwater

Multiparameter Monitoring and Prevention of Fault-Slip Rock Burst

Directory of Open Access Journals (Sweden)

Shan-chao Hu

2017-01-01

Full Text Available Fault-slip rock burst is one type of the tectonic rock burst during mining. A detailed understanding of the precursory information of fault-slip rock burst and implementation of monitoring and early warning systems, as well as pressure relief measures, are essential to safety production in deep mines. This paper first establishes a mechanical model of stick-slip instability in fault-slip rock bursts and then reveals the failure characteristics of the instability. Then, change rule of mining-induced stress and microseismic signals before the occurrence of fault-slip rock burst are proposed, and multiparameter integrated early warning methods including mining-induced stress and energy are established. Finally, pressure relief methods targeting large-diameter boreholes and coal seam infusion are presented in accordance with the occurrence mechanism of fault-slip rock burst. The research results have been successfully applied in working faces 2310 of the Suncun Coal Mine, and the safety of the mine has been enhanced. These research results improve the theory of fault-slip rock burst mechanisms and provide the basis for prediction and forecasting, as well as pressure relief, of fault-slip rock bursts.

Climatology and seasonality of upper ocean salinity: a three-dimensional view from argo floats

Science.gov (United States)

Chen, Ge; Peng, Lin; Ma, Chunyong

2018-03-01

Primarily due to the constraints of observation technologies (both field and satellite measurements), our understanding of ocean salinity is much less mature compared to ocean temperature. As a result, the characterizations of the two most important properties of the ocean are unfortunately out of step: the former is one generation behind the latter in terms of data availability and applicability. This situation has been substantially changed with the advent of the Argo floats which measure the two variables simultaneously on a global scale since early this century. The first decade of Argo-acquired salinity data are analyzed here in the context of climatology and seasonality, yielding the following main findings for the global upper oceans. First, the six well-defined "salty pools" observed around ±20° in each hemisphere of the Pacific, Atlantic and Indian Oceans are found to tilt westward vertically from the sea surface to about 600 m depth, forming six saline cores within the subsurface oceans. Second, while potential temperature climatology decreases monotonically to the bottom in most places of the ocean, the vertical distribution of salinity can be classified into two categories: A double-halocline type forming immediately above and below the local salinity maximum around 100-150 m depths in the tropical and subtropical oceans, and a single halocline type existing at about 100 m depth in the extratropical oceans. Third, in contrast to the midlatitude dominance for temperature, seasonal variability of salinity in the oceanic mixed layer has a clear tropical dominance. Meanwhile, it is found that a two-mode structure with annual and semiannual periodicities can effectively penetrate through the upper ocean into a depth of 2000 m. Fourth, signature of Rossby waves is identified in the annual phase map of ocean salinity within 200-600 m depths in the tropical oceans, revealing a strongly co-varying nature of ocean temperature and salinity at specific depths

Elastic Rock Heterogeneity Controls Brittle Rock Failure during Hydraulic Fracturing

Science.gov (United States)

Langenbruch, C.; Shapiro, S. A.

2014-12-01

For interpretation and inversion of microseismic data it is important to understand, which properties of the reservoir rock control the occurrence probability of brittle rock failure and associated seismicity during hydraulic stimulation. This is especially important, when inverting for key properties like permeability and fracture conductivity. Although it became accepted that seismic events are triggered by fluid flow and the resulting perturbation of the stress field in the reservoir rock, the magnitude of stress perturbations, capable of triggering failure in rocks, can be highly variable. The controlling physical mechanism of this variability is still under discussion. We compare the occurrence of microseismic events at the Cotton Valley gas field to elastic rock heterogeneity, obtained from measurements along the treatment wells. The heterogeneity is characterized by scale invariant fluctuations of elastic properties. We observe that the elastic heterogeneity of the rock formation controls the occurrence of brittle failure. In particular, we find that the density of events is increasing with the Brittleness Index (BI) of the rock, which is defined as a combination of Young's modulus and Poisson's ratio. We evaluate the physical meaning of the BI. By applying geomechanical investigations we characterize the influence of fluctuating elastic properties in rocks on the probability of brittle rock failure. Our analysis is based on the computation of stress fluctuations caused by elastic heterogeneity of rocks. We find that elastic rock heterogeneity causes stress fluctuations of significant magnitude. Moreover, the stress changes necessary to open and reactivate fractures in rocks are strongly related to fluctuations of elastic moduli. Our analysis gives a physical explanation to the observed relation between elastic heterogeneity of the rock formation and the occurrence of brittle failure during hydraulic reservoir stimulations. A crucial factor for understanding

Efficacy of nebulised L-adrenaline with 3% hypertonic saline versus normal saline in bronchiolitis

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Shabnam Sharmin

2016-08-01

Full Text Available Background: Bronchiolitis is one of the most common respiratory diseases requiring hospitalization. Nebulized epineph­rine and salbutamol therapy has been used in different centres with varying results. Objective: The objective of the study was to compare the efficacy of nebulised adrenaline diluted with 3% hypertonic saline with nebulised adrenaline diluted with normal saline in bronchiolitis. Methods: Fifty three infants and young children with bronchiolitis, age ranging from 2 months to 2 years, presenting in the emergency department of Manikganj Sadar Hospital were enrolled in the study. After initial evaluation, patients were randomized to receive either nebulized adrenaline I .5 ml ( 1.5 mg diluted with 2 ml of3% hypertonic saline (group I ornebulised adrenaline 1.5 ml (1.5 mg diluted with 2 ml of normal saline (group II. Patients were evaluated again 30 minutes after nebulization. Results: Twenty eight patients in the group I (hypertonic saline and twenty five in groupII (normal saline were included in the study. After nebulization, mean respiratory rate decreased from 63.7 to 48.1 (p<.01, mean clinical severity score decreased from 8.5 to 3.5 (p<.01 and mean oxygen satw·ation increased 94.7% to 96.9% (p<.01 in group I. In group II, mean respiratory rate decreased from 62.4 to 47.4 (p<.01, mean clinical severity score decreased from 7.2 to 4.1 (p<.01 and mean oxygen saturation increased from 94. 7% to 96. 7% (p<.01. Mean respiratory rate decreased by 16 in group I versus 14.8 (p>.05 in group 11, mean clinical severity score decreased by 4.6 in group versus 3 (p<.05 in group, and mean oxygen saturation increased by 2.2% and 1.9% in group and group respectively. Difference in reduction in clinical severity score was statistically significant , though the changes in respiratory rate and oxygen saturation were not statistically significant. Conclusion: The study concluded that both nebulised adrenaline diluted with 3% hypertonic saline and

Physiological Response to Salinity Stress by Primed Seedsof Three Species of Lawn

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SH. Sedaghathoor

2015-03-01

Full Text Available Salinity is one of the most important ecological stresses which have undesirable effects on seed germination. This study was carried out to evaluate the germination of three species of lawn (Poa pratensis, Lolium perenne, Cynodon dactylon seeds under salinity stress. The effect of different treatments (Gibberellins 50 mgl-1, 2% CaCl2 and hydroprimig in 24 hours was evaluated on total germination, mean daily germination, maximum and mean germination percent in three species of lawn, under four levels of salinity (0, 3, 6, 9 dS/m. Priming factor (Gibberellins and water was more effective than salinity on the seed germination. Among lawn types, Lolium perenne and Cynodon dactylon indicated greater seed germination percentage and germination rate. The least rate and percentage of germination belonged to Poa pratensis. Among priming treatments, gibberellins had the greatest effect on germination, followed by hydropriming. However, interaction effects of "Lolium × CaCl2" were greater than other treatments on the mean daily germination and germination value. Based on the results, seed priming specially Gibberellins could be an appropriate substrate to improve seed germination in lawns, when grown under salinity.

Development of a Unified Rock Bolt Model in Discontinuous Deformation Analysis

Science.gov (United States)

He, L.; An, X. M.; Zhao, X. B.; Zhao, Z. Y.; Zhao, J.

2018-03-01

In this paper, a unified rock bolt model is proposed and incorporated into the two-dimensional discontinuous deformation analysis. In the model, the bolt shank is discretized into a finite number of (modified) Euler-Bernoulli beam elements with the degrees of freedom represented at the end nodes, while the face plate is treated as solid blocks. The rock mass and the bolt shank deform independently, but interact with each other through a few anchored points. The interactions between the rock mass and the face plate are handled via general contact algorithm. Different types of rock bolts (e.g., Expansion Shell, fully grouted rebar, Split Set, cone bolt, Roofex, Garford and D-bolt) can be realized by specifying the corresponding constitutive model for the tangential behavior of the anchored points. Four failure modes, namely tensile failure and shear failure of the bolt shank, debonding along the bolt/rock interface and loss of the face plate, are available in the analysis procedure. The performance of a typical conventional rock bolt (fully grouted rebar) and a typical energy-absorbing rock bolt (D-bolt) under the scenarios of suspending loosened blocks and rock dilation is investigated using the proposed model. The reliability of the proposed model is verified by comparing the simulation results with theoretical predictions and experimental observations. The proposed model could be used to reveal the mechanism of each type of rock bolt in realistic scenarios and to provide a numerical way for presenting the detailed profile about the behavior of bolts, in particular at intermediate loading stages.

An experimental study of velocities under pressure for ancient oceanic rocks

Digital Repository Service at National Institute of Oceanography (India)

Sarma, K.V.L.N.S.

Seismic velocities of Indus suture rock types from Dras-Sanko-Kargil, Kashmir Himalaya, as a function of pressure up to 10 kbar were studied. The high-pressure measurements on the rocks reflect the depthwise increase in velocity, and in general...

Salinization of aquifers at the regional scale by marine transgression: Time scales and processes

Science.gov (United States)

Armandine Les Landes, A.; Davy, P.; Aquilina, L.

2014-12-01

Saline fluids with moderate concentrations have been sampled and reported in the Armorican basement at the regional scale (northwestern France). The horizontal and vertical distributions of high chloride concentrations (60-1400mg/L) at the regional scale support the marine origin and provide constraints on the age of these saline fluids. The current distribution of fresh and "saline" groundwater at depth is the result mostly of processes occurring at geological timescales - seawater intrusion processes followed by fresh groundwater flushing -, and only slightly of recent anthropogenic activities. In this study, we focus on seawater intrusion mechanisms in continental aquifers. We argue that one of the most efficient processes in macrotidal environments is the gravity-driven downconing instability below coastal salinized rivers. 2-D numerical experiments have been used to quantify this process according to four main parameter types: (1) the groundwater system permeability, (2) the salinity degree of the river, (3) the river width and slope, and (4) the tidal amplitude. A general expression of the salinity inflow rates have been derived, which has been used to estimate groundwater salinization rates in Brittany, given the geomorphological and environmental characteristics (drainage basin area, river widths and slopes, tidal range, aquifer permeability). We found that downconing below coastal rivers entail very high saline rates, indicating that this process play a major role in the salinization of regional aquifers. This is also likely to be an issue in the context of climate change, where sea-level rise is expected.

A new water permeability measurement method for unsaturated tight materials using saline solutions

International Nuclear Information System (INIS)

Malinsky, Laurent; Talandier, Jean

2012-01-01

Document available in extended abstract form only. Relative water permeability of material in a radioactive waste disposal is a key parameter to simulate and predict saturation state evolution. In this paper we present a new measurement method and the results obtained for Callovo-Oxfordian (Cox) clay-stone, host rock of the underground Andra laboratory at Bure (Meuse/Haute-Marne). Relative water permeability of such a low permeability rock as Cox clay-stone has been measured up to now by an indirect method. It consists in submitting a rock sample to successive relative humidity steps imposed by saline solutions. The transient mass variation during each step and the mass at hydric equilibrium are interpreted generally by using an inverse analysis method. The water relative permeability function of water saturation is derived from water diffusion coefficient evolution and water retention curve. The proposed new method consists in directly measuring the water flux across a flat cylindrical submitted to a relative humidity gradient. Two special cells have been developed. The tightness of the lateral sample surface is insured by crushing a polyurethane ring surrounding the sample set in an aluminium device placed over a Plexiglas vessel filled with a saline solution. One of the cells is designed to allow humidity measurement in the cell. These cells can also be used to measure the relative humidity produced by a saline solution or by an unsaturated material. During a permeability measurement, the cell with the sample to be tested is continuously weighted in a Plexiglas box in which a saline solution imposes a different relative humidity at the upper sample face. The experimental set-up is shown on Figure 1. The mean permeability of the sample is proportional to the rate of mass variation when steady state is reached. The result of one test is shown on Figure 2(a). Twenty four permeability measurements have been performed on four argillite samples of 15 mm in height and

A global algorithm for estimating Absolute Salinity

Science.gov (United States)

McDougall, T. J.; Jackett, D. R.; Millero, F. J.; Pawlowicz, R.; Barker, P. M.

2012-12-01

The International Thermodynamic Equation of Seawater - 2010 has defined the thermodynamic properties of seawater in terms of a new salinity variable, Absolute Salinity, which takes into account the spatial variation of the composition of seawater. Absolute Salinity more accurately reflects the effects of the dissolved material in seawater on the thermodynamic properties (particularly density) than does Practical Salinity. When a seawater sample has standard composition (i.e. the ratios of the constituents of sea salt are the same as those of surface water of the North Atlantic), Practical Salinity can be used to accurately evaluate the thermodynamic properties of seawater. When seawater is not of standard composition, Practical Salinity alone is not sufficient and the Absolute Salinity Anomaly needs to be estimated; this anomaly is as large as 0.025 g kg-1 in the northernmost North Pacific. Here we provide an algorithm for estimating Absolute Salinity Anomaly for any location (x, y, p) in the world ocean. To develop this algorithm, we used the Absolute Salinity Anomaly that is found by comparing the density calculated from Practical Salinity to the density measured in the laboratory. These estimates of Absolute Salinity Anomaly however are limited to the number of available observations (namely 811). In order to provide a practical method that can be used at any location in the world ocean, we take advantage of approximate relationships between Absolute Salinity Anomaly and silicate concentrations (which are available globally).

Migmatitic rocks southwest of the Barberton greenstone belt

International Nuclear Information System (INIS)

Robb, L.J.; Anhaeusser, C.R.

1981-01-01

A geologic survey was done on the migmatitic rocks southwest of the Barberton greenstone belt. A table is given on the chemical analyses of components from migmatic outcrops in this area, as well as on the chemical analyses of some selected rock types found in greenstone xenoliths, together with leuco-biotite tomalite/tronomjemite gneisses in the area surrounding the Boesmanskop syenite pluton. Isotope dating was also used in the survey

Geochemical characteristics of Lower Jurassic source rocks in the Zhongkouzi Basin

Science.gov (United States)

Niu, Haiqing; Han, Xiaofeng; Wei, Jianshe; Zhang, Huiyuan; Wang, Baowen

2018-01-01

Zhongkouzi basin is formed in Mesozoic and Cenozoic and developed on the Hercynian folded belt, the degree of exploration for oil and gas is relatively low hitherto. In order to find out the geochemical characteristics of the source rocks and the potentials for hydrocarbon generation. The research result shows that by analysis the geochemical characteristics of outcrop samples and new core samples in Longfengshan Group, Longfengshan Group are most developed intervals of favorable source rocks. They are formed in depression period of the basin when the sedimentary environments is salt water lacustrine and the water is keeping stable; The organic matter abundance is middle-higher, the main kerogen type is II1-II2 and few samples act as III type, The organic matter maturity is low maturity to medium maturity. The organic matter maturity of the source rock from eastern part of the basin is higher than in the western region. The source rock of Longfengshan Group are in the hydrocarbon generation threshold. The great mass of source rocks are matured and in the peak stage of oil generation.

Rock Core Tests, Proposed Duplicate Lock-Phase 2, Starved Rock Lock and Dam, Illinois River, Illinois

Science.gov (United States)

1975-06-01

defined as being rlppable to marginally rippable by Caterpillar Tractor Company. A cheap, fast seismic refraction survey could verify that this is an...Ore RIPPABLE MARGINAL NGN RIPPABLE Figure 4. Rippability ranges for typical rock types - D9G caterpillar (from performance manual

Favorability for uranium in tertiary sedimentary rocks, southwestern Montana

International Nuclear Information System (INIS)

Wopat, M.A.; Curry, W.E.; Robins, J.W.; Marjaniemi, D.K.

1977-10-01

Tertiary sedimentary rocks in the basins of southwestern Montana were studied to determine their favorability for potential uranium resources. Uranium in the Tertiary sedimentary rocks was probably derived from the Boulder batholith and from silicic volcanic material. The batholith contains numerous uranium occurrences and is the most favorable plutonic source for uranium in the study area. Subjective favorability categories of good, moderate, and poor, based on the number and type of favorable criteria present, were used to classify the rock sequences studied. Rocks judged to have good favorability for uranium deposits are (1) Eocene and Oligocene strata and undifferentiated Tertiary rocks in the western Three Forks basin and (2) Oligocene rocks in the Helena basin. Rocks having moderate favorability consist of (1) Eocene and Oligocene strata in the Jefferson River, Beaverhead River, and lower Ruby River basins, (2) Oligocene rocks in the Townsend and Clarkston basins, (3) Miocene and Pliocene rocks in the Upper Ruby River basin, and (4) all Tertiary sedimentary formations in the eastern Three Forks basin, and in the Grasshopper Creek, Horse Prairie, Medicine Lodge Creek, Big Sheep Creek, Deer Lodge, Big Hole River, and Bull Creek basins. The following have poor favorability: (1) the Beaverhead Conglomerate in the Red Rock and Centennial basins, (2) Eocene and Oligocene rocks in the Upper Ruby River basin, (3) Miocene and Pliocene rocks in the Townsend, Clarkston, Smith River, and Divide Creek basins, (4) Miocene through Pleistocene rocks in the Jefferson River, Beaverhead River, and Lower Ruby River basins, and (5) all Tertiary sedimentary rocks in the Boulder River, Sage Creek, Muddy Creek, Madison River, Flint Creek, Gold Creek, and Bitterroot basins

Studying Vegetation Salinity: From the Field View to a Satellite-Based Perspective

Directory of Open Access Journals (Sweden)

Rachel Lugassi

2017-02-01

Full Text Available Salinization of irrigated lands in the semi-arid Jezreel Valley, Northern Israel results in soil-structure deterioration and crop damage. We formulated a generic rule for estimating salinity of different vegetation types by studying the relationship between Cl/Na and different spectral slopes in the visible–near infrared–shortwave infrared (VIS–NIR–SWIR spectral range using both field measurements and satellite imagery (Sentinel-2. For the field study, the slope-based model was integrated with conventional partial least squares (PLS analyses. Differences in 14 spectral ranges, indicating changes in salinity levels, were identified across the VIS–NIR–SWIR region (350–2500 nm. Next, two different models were run using PLS regression: (i using spectral slope data across these ranges; and (ii using preprocessed spectral reflectance. The best model for predicting Cl content was based on continuum removal reflectance (R2 = 0.84. Satisfactory correlations were obtained using the slope-based PLS model (R2 = 0.77 for Cl and R2 = 0.63 for Na. Thus, salinity contents in fresh plants could be estimated, despite masking of some spectral regions by water absorbance. Finally, we estimated the most sensitive spectral channels for monitoring vegetation salinity from a satellite perspective. We evaluated the recently available Sentinel-2 imagery’s ability to distinguish variability in vegetation salinity levels. The best estimate of a Sentinel-2-based vegetation salinity index was generated based on a ratio between calculated slopes: the 490–665 nm and 705–1610 nm. This index was denoted as the Sentinel-2-based vegetation salinity index (SVSI (band 4 − band 2/(band 5 + band 11.

Effect of Salinity on Germination and Its Relationship with Vegetative growth in Bromus danthoniae Genotypes from Saline and Non-Saline Areas of Iran

Directory of Open Access Journals (Sweden)

M. Rezaei

2018-02-01

Full Text Available Bromus danthoniae Trin. is an annual grass species that is well adapted to harsh climates and could be considered as an important genetic resources for tolerance to environmental stresses such as salinity. In this study, 24 genotypes collected from Ilam, Kurdistan, Kermanshah (non-saline areas and West Azerbaijan (saline area: shores of Uremia Salt Lake provinces of Iran were investigated at the germination stage under salt treatments with concentrations of 0, 60, 120, 180, 240 and 300 mM sodium chloride. Germination percentage, germination rate index, seed vigor, root length, shoot length and seedling fresh and dry weights were measured. In addition, the relationship between the percentage of germination in 300 mM sodium chloride and the survival rate (% after four weeks in 350 mM sodium chloride at the vegetative stage was evaluated. The results of analysis of variance showed that salinity treatments caused significant reductions in all the studied traits. Genotypic variation and the interaction of genotype × salt treatments were also significant. Genotypes USLN3 and KER4 were found to be the most tolerant and sensitive genotypes to salinity stress, with 13% and 98% reduction in germination percentage at 300 mM NaCl, respectively. Cluster analysis divided the genotypes into three groups, with one group containing only tolerant genotypes from Uremia Salt Lake, another one comprising only sensitive genotypes from non-saline regions, and the third one containing genotypes from both regions. The correlation between the germination percentage and the survival rate at the vegetative stage was not significant, indicating that different mechanisms are, perhaps, responsible for salinity tolerance at the germination and vegetative stages in B. danthoniae.

CUMULATE ROCKS ASSOCIATED WITH CARBONATE ASSIMILATION, HORTAVÆR COMPLEX, NORTH-CENTRAL NORWAY

Science.gov (United States)

Barnes, C. G.; Prestvik, T.; Li, Y.

2009-12-01

The Hortavær igneous complex intruded high-grade metamorphic rocks of the Caledonian Helgeland Nappe Complex at ca. 466 Ma. The complex is an unusual mafic-silicic layered intrusion (MASLI) because the principal felsic rock type is syenite and because the syenite formed in situ rather than by deep-seated partial melting of crustal rocks. Magma differentiation in the complex was by assimilation, primarily of calc-silicate rocks and melts with contributions from marble and semi-pelites, plus fractional crystallization. The effect of assimilation of calcite-rich rocks was to enhance stability of fassaitic clinopyroxene at the expense of olivine, which resulted in alkali-rich residual melts and lowering of silica activity. This combination of MASLI-style emplacement and carbonate assimilation produced three types of cumulate rocks: (1) Syenitic cumulates formed by liquid-crystal separation. As sheets of mafic magma were loaded on crystal-rich syenitic magma, residual liquid was expelled, penetrating the overlying mafic sheets in flame structures, and leaving a cumulate syenite. (2) Reaction cumulates. Carbonate assimilation, illustrated by a simple assimilation reaction: olivine + calcite + melt = clinopyroxene + CO2 resulted in cpx-rich cumulates such as clinopyroxenite, gabbro, and mela-monzodiorite, many of which contain igneous calcite. (3) Magmatic skarns. Calc-silicate host rocks underwent partial melting during assimilation, yielding a Ca-rich melt as the principal assimilated material and permitting extensive reaction with surrounding magma to form Kspar + cpx + garnet-rich ‘cumulate’ rocks. Cumulate types (2) and (3) do not reflect traditional views of cumulate rocks but instead result from a series of melt-present discontinuous (peritectic) reactions and partial melting of calc-silicate xenoliths. In the Hortavær complex, such cumulates are evident because of the distinctive peritectic cumulate assemblages. It is unclear whether assimilation of �

CO{sub 2} storage in saline aquifers; Stockage du CO{sub 2} dans les aquiferes salins

Energy Technology Data Exchange (ETDEWEB)

Bentham, M.; Kirby, G. [British Geological Survey (BGS), Kingsley Dunham Centre, Keyworth, Nottingham (United Kingdom)

2005-06-01

Saline aquifers represent a promising way for CO{sub 2} sequestration. Storage capacities of saline aquifers are very important around the world. The Sleipner site in the North Sea is currently the single case world-wide of CO{sub 2} storage in a saline aquifer. A general review is given on the specific risks for CO{sub 2} storage in saline aquifer. The regional distribution of CO{sub 2} storage potential is presented. Finally, the knowledge gaps and the future research in this field are defined. (authors)

Radwaste storage in crystalline rocks: a natural analog

International Nuclear Information System (INIS)

Brookins, D.G.; Abashian, M.S.; Cohen, L.H.; Wollenberg, H.A.

1982-01-01

The Eldora-Bryan Stock (Colorado) intruded the 1.4-1.6 billion year old metamorphic rocks of the Idaho Springs Formation 55 million years ago. The stock may be considered a giant analog of a radwaste form without canister or engineered backfill barriers. The authors' lanthanide studies show the following: (1) The intrusive rocks remained as a closed system. (2) Lanthanide/chondrite versus ionic radius plots show only local redistribution in the immediate contact zone, and that rocks in this zone have not gained lanthanides from the magma. (3) No whole rock perturbations for the lanthanides are noted at distances greater than 3 m from the contact. Stable oxygen isotopic variations show a narrow 9.0 +- 0.3 per mille range for the intrusive rocks and whole rock values from 7.6 to 10.0 per mille for the intruded rocks. The authors conclude: (1) The Idaho Springs Formation was not penetrated by hydrothermal fluids from the Eldora-Bryan magma except possibly on a local scale within 3 m of the contact. (2) The light lanthanides may be locally redistributed in the immediate contact zone, but without additions from the magma. (3) The oxygen isotopic data imply lack of hydrothermal fluids from the magma penetrating the intruded rocks, even in the highest temperature contact zones. Whole rock data imply closed system conditions for Rb, Sr, Th, U, Pb even where mineral ages have been lowered. Data for Co, Cr, Sc, Fe, Cs also indicate retention in whole rock systems and no exchange with the magma. The combined chemical, isotopic, petrographic and theoretical data and calculations indicate suitability of rocks of the Idaho Springs Formation, and thus of many types of crystalline rocks as well, for possible use for the storage of radioactive waste

Rock mechanics stability at Olkiluoto, Haestholmen, Kivetty and Romuvaara

International Nuclear Information System (INIS)

Johansson, E.; Rautakorpi, J.

2000-02-01

Posiva Oy is studying the suitability of the Finnish bedrock for the geological disposal of spent nuclear fuel at four sites, Olkiluoto in Eurajoki, Haestholmen in Loviisa, Kivetty in Aeaenekoski and Romuvaara in Kuhmo. To enable the rock properties to be specified in great detail, the site-selection research programme has included rock mechanics investigations such as the measurement of in-situ rock stress and laboratory tests on rock samples. This report presents the results of the rock mechanics analyses performed on the main rock types at the Olkiluoto, Romuvaara, Kivetty and Haestholmen sites. The objective of this study was to assess the near-field stability of the final disposal tunnels and deposition holes at each of the investigation sites. Two empirical methods and a numerical method based on three-dimensional element code (3DEC) were used the analysis tools. A statistical approach was used to select the necessary input data and to specify the cases being analysed. The stability of the KBS-3 and MLH (Medium Long Hole) repository concepts during the pre-closure and post-closure phases was analysed. The repository depths investigated lay between 300 m and 700 m. The empirical methods are based on the study of the ratios between rock strength and the in-situ stress which could result in possible fracturing of the rock mass. Interpretation of the numerical analyses is based on the assumption of an elastic distribution of stress around the disposal tunnel and the deposition hole and the brittle rock strength criterion. The results obtained in this study indicate that in general, the rock mechanics conditions during the pre-closure and post-closure phases at each of the investigated sites remain good and stable between the studied depth levels, especially when the deposition rooms are oriented in a direction parallel to the major in-situ stress. If the disposal tunnels are orientated in a direction perpendicular to the major in-situ stress, the resultant

Elbow, forearm, wrist, and hand injuries among sport rock climbers.

Science.gov (United States)

Holtzhausen, L M; Noakes, T D

1996-07-01

Sport rock climbing with its repetitive high-torque movements in gaining the ascent of a rock face or wall, often in steep overhanging positions, is associated with a unique distribution and form of upper limb injuries. In this article, we review the biomechanical aspects of sport rock climbing and the types of injuries commonly encountered in the forearm, wrist, and hand regions of elite sport rock climbers. Because elbow, forearm, wrist, and hand injuries predominate, representing 62% of the total injuries encountered, these anatomical areas have been selected for review. The predominant source of data are the published work of Bollen et al. The remaining sources were obtained through electronic search of the Medline and Current Contents Databases (last searched May 1995). German and French articles were included in the search criteria. Only studies dealing with acute soft tissue and overuse injuries amongst sport rock climbers were selected. Data were extracted directly from the sourced articles. The following injuries have been described in detail with regard to their presentation, diagnosis, treatment, and prevention amongst sport rock climbers: medial epicondylitis, brachialis tendonitis, biceps brachii tendonitis, ulnar collateral ligament sprain of the elbow, carpal tunnel syndrome, digital flexor tendon pulley sheath tears, interphalangeal joint effusions, fixed flexion deformities of the interphalangeal joints, and collateral ligament tears of the interphalangeal joints. Many of the injuries are specific to the handhold types used by the rock climber. Accurate diagnosis and effective treatment of these unique injuries will be facilitated by a wider understanding of the biomechanical aspects of rock climbing and an awareness of the patterns and incidence of injuries in this sport.

Rock burst governance of working face under igneous rock

Science.gov (United States)

Chang, Zhenxing; Yu, Yue

2017-01-01

As a typical failure phenomenon, rock burst occurs in many mines. It can not only cause the working face to cease production, but also cause serious damage to production equipment, and even result in casualties. To explore how to govern rock burst of working face under igneous rock, the 10416 working face in some mine is taken as engineering background. The supports damaged extensively and rock burst took place when the working face advanced. This paper establishes the mechanical model and conducts theoretical analysis and calculation to predict the fracture and migration mechanism and energy release of the thick hard igneous rock above the working face, and to obtain the advancing distance of the working face when the igneous rock fractures and critical value of the energy when rock burst occurs. Based on the specific conditions of the mine, this paper put forward three kinds of governance measures, which are borehole pressure relief, coal seam water injection and blasting pressure relief.

Establishment of land model at the Shika Nuclear Power Plant. Mainly, on rock board classification

International Nuclear Information System (INIS)

Katagawa, Hideki; Hashimoto, Toru; Hirano, Shuji

1999-01-01

In order to grasp engineering properties of basic land of constructions, there is rock board classification as a method to classify whole of rock board to some groups considerable to be nearly equal on its properties. Among the method, various methods in response to its aim and characteristics are devised, and for a classification to hard rock board, the Denken type rock board classification considering degree of weathering to its main element and so forth are well known. The basic rock board of the Shika Nuclear Power Plant is composed of middle and hard types of rock, and its weathering is limited to its shallow portion, most of which are held at fresh condition. For such land, a new classification standard in response to characteristics of land was established. Here were introduced on a progress to establish a new classification standard, its application results and rock board properties. (G.K.)

Relationship between fluvial clastic sediment and source rock abundance in Rapti river basin of central Nepal Himalayas

International Nuclear Information System (INIS)

Tamrakar Naresh Kazi; Shresth Madhusudan Bhakta

2008-01-01

Many tributaries from carbonate sedimentary, metamorphic and igneous rocks of the Lesser Himalayan and clastic sedimentary rocks of the Sub-Himalayan Ranges carry gravelly sediments to the Rapti River. River bar sediments were analyzed for composition and texture to evaluate downstream changes in properties, and to establish relationship between proportion of clasts and the abundance of rock types in the source areas. Percent quartzite clast or granite clast increases whereas that of carbonate, schist or slate decreases along downstream. The largest grain size decreases downstream, whereas fatness index and sphericity tend to increase. Despite of little diminish in relative abundance of rock types in source areas along the river, the relative proportion of corresponding clast type shows rapid reduction (e.g. slate or phyllite or carbonate clasts) or rapid enhancement (e.g. granite clast). The relationships of quartzite clast and schist clasts with their corresponding source rocks are statistically significant suggesting that these clasts can provide clue to source rock abundance. About 85 to 94% of the gravel clasts represent rock types of the Lesser Himalayan Range suggesting that this range has been contributing enormous amount of sediments.

A global algorithm for estimating Absolute Salinity

Directory of Open Access Journals (Sweden)

T. J. McDougall

2012-12-01

Full Text Available The International Thermodynamic Equation of Seawater – 2010 has defined the thermodynamic properties of seawater in terms of a new salinity variable, Absolute Salinity, which takes into account the spatial variation of the composition of seawater. Absolute Salinity more accurately reflects the effects of the dissolved material in seawater on the thermodynamic properties (particularly density than does Practical Salinity.

When a seawater sample has standard composition (i.e. the ratios of the constituents of sea salt are the same as those of surface water of the North Atlantic, Practical Salinity can be used to accurately evaluate the thermodynamic properties of seawater. When seawater is not of standard composition, Practical Salinity alone is not sufficient and the Absolute Salinity Anomaly needs to be estimated; this anomaly is as large as 0.025 g kg⁻¹ in the northernmost North Pacific. Here we provide an algorithm for estimating Absolute Salinity Anomaly for any location (x, y, p in the world ocean.

To develop this algorithm, we used the Absolute Salinity Anomaly that is found by comparing the density calculated from Practical Salinity to the density measured in the laboratory. These estimates of Absolute Salinity Anomaly however are limited to the number of available observations (namely 811. In order to provide a practical method that can be used at any location in the world ocean, we take advantage of approximate relationships between Absolute Salinity Anomaly and silicate concentrations (which are available globally.

Validation of choice and determination of geotechnology parameters with regard to stress–strain state of rocks

Science.gov (United States)

Freidin, AM; Neverov, SA; Neverov, AA; Konurin, AI

2018-03-01

The paper illustrates efficiency and reliability of types of rock mass stress state conditioned by geological and structural features of rocks in design, selection and validation of geotechnology parameters. The authors of the paper present calculation of stresses in rock mass under sublevel stoping depending on the type of the geosphere and on the depth of the ore body occurrence.

Organic compositions of lacustrine source rocks in Jiyang super-depression and its implication to petroleum geology

Institute of Scientific and Technical Information of China (English)

无

2006-01-01

The compositions of organic matter in four immature source rocks from Tertiary strata of Jiyang super-depression, the most typical continental rift subsidence basin in East China, have been studied by different extracting methods with CHCl3, MAC and CS2/NMP, respectively. The results suggest that there are great differences among the chemical compositions of organic matter in the source rocks derived from different depositional environments. About 79% of all the organic matter exists by non- covalent bond in the Es4 source rocks which were deposited under the saline lacustrine, indicating that its organic matter is not the real kerogen, but mainly composed of soluble organic matter which is easy to generate hydrocarbon at lower temperature. This is why the immature oils were derived from Es4 source rocks in Dongying depression. In contrast, around 60% of organic matter exists by covalent bond in Es3 source rocks which were deposited under the deep brackish-fresh lacustrine, showing that Es3 source rocks are mainly composed of kerogen producing mature hydrocarbon at higher temperature. The thermal simulation experiments, upon the remaining solid source rocks which were sequentially extracted by the three solvents, have been carried out. The chloroform extracts from the simulation product have been compared with the other three solvent extracts gained at room temperature. It is obvious that remarkable odd/even predominance (OEP) is mainly the characteristic of soluble organic matter; phytane mostly exists in the soluble organic matter by means of non-covalent bonds and characteristics of soluble organic matter are similar to these in immature oils produced in Jiyang super-depression.

Control over surrounding rocks deformation of soft floor and whole-coal gateways with trapezoidal supports

Energy Technology Data Exchange (ETDEWEB)

Zhai, X.; Li, D.; Shao, Q.; Sun, Y. [Henan Polytechnic University, Jaozuo (China). Dept. of Resource and Material Engineering

2005-06-01

The coal seams of Guengcun Coal mine of Yima Coal Group Co. Ltd. are prone to spontaneous combustion. Fully mechanized longwall mining with sublevel caving is used as the mining method. Based on the characteristics of the gateways of the 1301 coal face and of the roof coal seams, the natural equilibrium arch theory was used to design the parameters of 11 mine-type metal supports. Then, in-situ supporting experiments were carried out. The results indicate that under the action of virgin rock stress, the width of broken rocks zone of surrounding rocks is 1.7-2.0 m in the return heading and 1.1-1.3 m in the outgoing headway and their surrounding rocks belong to the IV-type soft rock and the III-type common surrounding rock respectively. Therefore, under the movable abutment pressure, the gateway deformation is serious. At the same time, the accumulated water on gateway floor must be drained in time. These measures were taken in the 1302 and 1304 coal faces in Gengcun colliery, and satisfactory results have been obtained. 8 refs., 3 figs.

The Slow Moving Threat of Groundwater Salinization: Mechanisms, Costs, and Adaptation Strategies

Science.gov (United States)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2016-12-01

Population growth, the Green Revolution, and climate uncertainties have accelerated overdraft in groundwater basins worldwide, which in some regions is converting these basins into closed hydrologic systems, where the dominant exits for water are evapotranspiration and pumping. Irrigated agricultural basins are particularly at risk to groundwater salinization, as naturally occurring (i.e., sodium, potassium, chloride) and anthropogenic (i.e., nitrate fertilizers) salts leach back into the water table through the root zone, while a large portion of pumped groundwater leaves the system as it is evapotranspired by crops. Decreasing water quality associated with increases in Total Dissolved Solids (TDS) has been documented in aquifers across the United States in the past half century. This study suggests that the increase in TDS in aquifers can be partially explained by closed basin hydrogeology and rock-water interactions leading to groundwater salinization. This study will present: (1) a report on historical water quality in the Tulare basin, (2) a forward simulation of salt balance in Tulare Basin based on the Department of Water Resources numerical model C2VSim, and a simple mixing model, (3) an economic analysis forecasting the cost of desalination under varying degrees of managed groundwater recharge where the basin is gradually filled, avoiding hydraulic closure.

Classification Scheme for Diverse Sedimentary and Igneous Rocks Encountered by MSL in Gale Crater

Science.gov (United States)

Schmidt, M. E.; Mangold, N.; Fisk, M.; Forni, O.; McLennan, S.; Ming, D. W.; Sumner, D.; Sautter, V.; Williams, A. J.; Gellert, R.

2015-01-01

The Curiosity Rover landed in a lithologically and geochemically diverse region of Mars. We present a recommended rock classification framework based on terrestrial schemes, and adapted for the imaging and analytical capabilities of MSL as well as for rock types distinctive to Mars (e.g., high Fe sediments). After interpreting rock origin from textures, i.e., sedimentary (clastic, bedded), igneous (porphyritic, glassy), or unknown, the overall classification procedure (Fig 1) involves: (1) the characterization of rock type according to grain size and texture; (2) the assignment of geochemical modifiers according to Figs 3 and 4; and if applicable, in depth study of (3) mineralogy and (4) geologic/stratigraphic context. Sedimentary rock types are assigned by measuring grains in the best available resolution image (Table 1) and classifying according to the coarsest resolvable grains as conglomerate/breccia, (coarse, medium, or fine) sandstone, silt-stone, or mudstone. If grains are not resolvable in MAHLI images, grains in the rock are assumed to be silt sized or smaller than surface dust particles. Rocks with low color contrast contrast between grains (e.g., Dismal Lakes, sol 304) are classified according to minimum size of apparent grains from surface roughness or shadows outlining apparent grains. Igneous rocks are described as intrusive or extrusive depending on crystal size and fabric. Igneous textures may be described as granular, porphyritic, phaneritic, aphyric, or glassy depending on crystal size. Further descriptors may include terms such as vesicular or cumulate textures.

Numerical Study on CO2-Brine-Rock Interaction of Enhanced Geothermal Systems with CO2 as Heat Transmission Fluid

Directory of Open Access Journals (Sweden)

Wan Yuyu

2016-01-01

Full Text Available Enhanced Geothermal Systems (EGS with CO2 instead of water as heat transmission fluid is an attractive concept for both geothermal resources development and CO2 geological sequestration. Previous studies show that CO2 has lots of favorable properties as heat transmission fluid and also can offer geologic storage of CO2 as an ancillary benefit. However, after CO2 injection into geological formations, chemical reaction between brine and rock can change chemical characteristics of saline and properties of rock such as porosity and permeability. Is this advantage or disadvantage for EGS operating? To answer this question, we have performed chemically reactive transport modeling to investigate fluid-rock interactions and CO2 mineral carbonation of Enhanced Geothermal Systems (EGS site at Desert Peak (Nevada operated with CO2. The simulation results show that (1 injection CO2 can create a core zone fulfilled with CO2 as main working domain for EGS, and (2 CO2 storage can induced self-enhancing alteration of EGS.

Millennial changes of the Baltic Sea salinity. Studies of the sensitivity of the salinity to climate change

International Nuclear Information System (INIS)

Gustafsson, Bo G.

2004-05-01

An important question for safety assessments of nuclear waste repositories is the salinity of the Baltic Sea under different conditions. The salinity affects the potential recipient ecosystems, the water turnover along the coast and the hydrology as well as the groundwater chemistry. In this report a model that enables computation of the Baltic Sea salinity for different sea level positions and freshwater supplies is presented. The model is used to compute the salinities in Baltic proper, Bothnian Sea and Bothnian Bay for all combinations of global sea level changes from -10 m to 10 m and freshwater supplies from 0 to 60,000 m 3 /s. The results are presented in a series of graphs that enables the reader to make an assessment of the impact of a given climatic change. The model is also used to compute the decrease of the salinity in Bothnian Sea and Bothnian Bay during the next few millennia due to the postglacial uplift. The results show that modest changes in global sea level, say ±1 m, give a salinity change of the order of 1 psu in southern Baltic proper. Changing the freshwater supply with about 2,000 m 3 /s (approximately 10%) gives a similar salinity change. Further, a sea level drop of about 5 m or an increase of the freshwater supply by a factor of 3 is needed to reduce the salinity in southern Baltic proper below 1 psu. In this limit large parts of the Baltic would be limnic. A 50% decrease of the freshwater supply increase the salinity in the southern Baltic proper by a factor of 2 to some 15 psu, but the effect is even more drastic in Bothnian Sea and Bothnian Bay where the salinity increase to 13 and 10 psu, respectively. A less windy climate might have a significant effect in lowering the Baltic salinity due to a combined effect of lowered mixing in Kattegat and lowered exchange between Kattegat and the Baltic. A windier climate will not have such strong effect since increased mixing does not affect the Baltic as much. Most probably the shoreline

Millennial changes of the Baltic Sea salinity. Studies of the sensitivity of the salinity to climate change

Energy Technology Data Exchange (ETDEWEB)

Gustafsson, Bo G. [Oceanus Havsundersoekningar, Goeteborg (Sweden)

2004-05-01

An important question for safety assessments of nuclear waste repositories is the salinity of the Baltic Sea under different conditions. The salinity affects the potential recipient ecosystems, the water turnover along the coast and the hydrology as well as the groundwater chemistry. In this report a model that enables computation of the Baltic Sea salinity for different sea level positions and freshwater supplies is presented. The model is used to compute the salinities in Baltic proper, Bothnian Sea and Bothnian Bay for all combinations of global sea level changes from -10 m to 10 m and freshwater supplies from 0 to 60,000 m{sup 3}/s. The results are presented in a series of graphs that enables the reader to make an assessment of the impact of a given climatic change. The model is also used to compute the decrease of the salinity in Bothnian Sea and Bothnian Bay during the next few millennia due to the postglacial uplift. The results show that modest changes in global sea level, say {+-}1 m, give a salinity change of the order of 1 psu in southern Baltic proper. Changing the freshwater supply with about 2,000 m{sup 3}/s (approximately 10%) gives a similar salinity change. Further, a sea level drop of about 5 m or an increase of the freshwater supply by a factor of 3 is needed to reduce the salinity in southern Baltic proper below 1 psu. In this limit large parts of the Baltic would be limnic. A 50% decrease of the freshwater supply increase the salinity in the southern Baltic proper by a factor of 2 to some 15 psu, but the effect is even more drastic in Bothnian Sea and Bothnian Bay where the salinity increase to 13 and 10 psu, respectively. A less windy climate might have a significant effect in lowering the Baltic salinity due to a combined effect of lowered mixing in Kattegat and lowered exchange between Kattegat and the Baltic. A windier climate will not have such strong effect since increased mixing does not affect the Baltic as much. Most probably the

Development of a Coastal Drought Index Using Salinity Data

Science.gov (United States)

Conrads, P. A.; Darby, L. S.

2014-12-01

The freshwater-saltwater interface in surface-water bodies along the coast is an important factor in the ecological and socio-economic dynamics of coastal communities. It influences community composition in freshwater and saltwater ecosystems, determines fisheries spawning habitat, and controls freshwater availability for municipal and industrial water intakes. These dynamics may be affected by coastal drought through changes in Vibrio bacteria impacts on shellfish harvesting and occurrence of wound infection, fish kills, harmful algal blooms, hypoxia, and beach closures. There are many definitions of drought, with most describing a decline in precipitation having negative impacts on water supply and agriculture. Four general types of drought are recognized: hydrological, agricultural, meteorological, and socio-economic. Indices have been developed for these drought types incorporating data such as rainfall, streamflow, soil moisture, groundwater levels, and snow pack. These indices were developed for upland areas and may not be appropriate for characterizing drought in coastal areas. Because of the uniqueness of drought impacts on coastal ecosystems, a need exists to develop a coastal drought index. The availability of real-time and historical salinity datasets provides an opportunity to develop a salinity-based coastal drought index. The challenge of characterizing salinity dynamics in response to drought is excluding responses attributable to occasional saltwater intrusion events. Our approach to develop a coastal drought index modified the Standardized Precipitation Index and applied it to sites in South Carolina and Georgia, USA. Coastal drought indices characterizing 1-, 3-, 6-, 9-, and12-month drought conditions were developed. Evaluation of the coastal drought index indicates that it can be used for different estuary types, for comparison between estuaries, and as an index for wet conditions (high freshwater inflow) in addition to drought conditions.

For Those About to Rock : Naislaulajat rock-genressä

OpenAIRE

Herranen, Linda

2015-01-01

For those about to rock – naislaulajat rock-genressä antaa lukijalleen kokonaisvaltaisen käsityksen naisista rock-genressä: rockin historiasta, sukupuolittuneisuudesta, seksismistä, suomalaisten naislaulajien menestyksestä. Työn aineisto on koottu aihepiirin kirjallisuudesta ja alalla toimiville naislaulajille teetettyjen kyselyiden tuloksista. Lisäksi avaan omia kokemuksiani ja ajatuksiani, jotta näkökulma naisista rock-genressä tulisi esille mahdollisimman monipuolisesti. Ajatus aihees...

Stepwise Rock-Eval pyrolysis as a tool for typing heterogeneous organic matter in soils

Energy Technology Data Exchange (ETDEWEB)

Hetenyi, M.; Nyilas, T.; Toth, T.M. [Department of Mineralogy, Geochemistry and Petrology, University of Szeged, P.O. Box 651, H-6701 Szeged (Hungary)

2005-08-15

This paper presents an application of Rock-Eval pyrolysis for estimating the proportion of the components with different thermal stability in soil organic matter, the maturity of which corresponds to the early stage of diagenesis. For testing the validity of the modified Rock-Eval method, parallel series of pyrolysis were carried out on sedimentary rock samples. The temperature program was selected on the basis of the results obtained from stepwise Rock-Eval pyrolysis and from the mathematical deconvolution of pyrograms. The proportion of the original biomolecules in soil organic matter was calculated by the integration of pyrograms below 350{sup o}C and could be determined rapidly by one single pyrolysis using 350{sup o}C as initial cracking temperature. At 380{sup o}C, both the mathematical and the experimental methods provide reliable information about the proportion of the humic substances. Conversely, for rock samples, mathematical deconvolution of the pyrograms showed the heterogeneity of the sedimentary organic matter, the maturity of which corresponds to late diagenesis, without any estimation of the proportion of the different components. The rate of organic carbon accumulation in the studied soils and the decomposition rate of biopolymers were interpreted as a function of land-use and redox conditions. Differences in the precursor vegetation and in the environmental parameters resulted in markedly reduced carbon storage and higher degree of humification in the agricultural soil than in the adjacent forest soil. Redox conditions strongly affected both the amount and the elemental composition of the stored organic matter. The decomposition rate of biopolymers appeared to be controlled mainly by the contribution of resistant lignin components to the source biomass and, to a lesser extent, by redox conditions.

Proceedings of the 3. Canada-US rock mechanics symposium and 20. Canadian rock mechanics symposium : rock engineering 2009 : rock engineering in difficult conditions

Energy Technology Data Exchange (ETDEWEB)

NONE

2009-07-01

This conference provided a forum for geologists, mining operators and engineers to discuss the application of rock mechanics in engineering designs. Members of the scientific and engineering communities discussed challenges and interdisciplinary elements involved in rock engineering. New geological models and methods of characterizing rock masses and ground conditions in underground engineering projects were discussed along with excavation and mining methods. Papers presented at the conference discussed the role of rock mechanics in forensic engineering. Geophysics, geomechanics, and risk-based approaches to rock engineering designs were reviewed. Issues related to high pressure and high flow water conditions were discussed, and new rock physics models designed to enhance hydrocarbon recovery were presented. The conference featured 84 presentations, of which 9 have been catalogued separately for inclusion in this database. tabs., figs.

Saline water irrigation for crop production

Energy Technology Data Exchange (ETDEWEB)

Khan, A R [Directorate of Water Management Research, Indian Council of Agricultural Research (ICAR), Walmi Complex, P.O. - Phulwari Sharif, Patna (India); [Abdus Salam International Centre for Theoretical Physics, Trieste (Italy); Singh, S S; Singh, S R [Directorate of Water Management Research, Indian Council of Agricultural Research (ICAR), Walmi Complex, P.O. - Phulwari Sharif, Patna (India)

2001-05-01

Salinity is one of agriculture's most complex production problems. Excessive salts from irrigation water or high water tables can severely limit crop production. Years of saline water irrigation on poorly drained soils can eventually make economic crop production impossible. About 10% of all land are affected by salinity problems. They occur in every continent in different proportions, more frequently in arid and semi-arid areas. This paper discusses a range of problems related to use of saline water for crop irrigation.

Saline water irrigation for crop production

International Nuclear Information System (INIS)

Khan, A.R.; Singh, S.S.; Singh, S.R.

2001-05-01

Salinity is one of agriculture's most complex production problems. Excessive salts from irrigation water or high water tables can severely limit crop production. Years of saline water irrigation on poorly drained soils can eventually make economic crop production impossible. About 10% of all land are affected by salinity problems. They occur in every continent in different proportions, more frequently in arid and semi-arid areas. This paper discusses a range of problems related to use of saline water for crop irrigation

Halophytic Companion Plants Improve Growth and Physiological Parameters of Tomato Plants Grown under Salinity

International Nuclear Information System (INIS)

Karakas, S.; Cullu, M. A.; Kaya, C.; Dikilitas, M.

2016-01-01

Salinity becomes a major concern when soil salt concentration becomes excessive in growth medium. Halophytes are capable of accumulating high concentrations of NaCl in their tissues, thus using halophytic plants in crop rotations or even in mixed cropping systems may be a promising management practices to mitigate salt stress related yield loses. Salinity induced yield losses and related physiological parameters on tomato plants (Lycopersicon esculentum Mill. cv. SC2121) grown with or without halophytic companion plants (SalsolasodaL. and Portulacaoleracea L.) were investigated in pot experiment. Treatments consist of four soil type (collected from Harran plain-Turkey) with similar physical properties but varying in salinity level: electrical conductivity (EC): 0.9, 4.2, 7.2, and 14.1 dS m/sup -1/. The reduction in plant total dry weight was 24, 19, and 48 percent in soils with slight (4.2dS m/sup -1/), moderate (7.2 dS m/sup -1/) and high (14.1 dS m/sup -1/) salinity as compared to non-saline soil (0.9 dS m/sup -1/), respectively. Leaf content of proline, malondialdehyde (MDA), catalase (CAT) and peroxidase (POX) enzyme activity increased with increasing level of salinity. In tomato plants grown in consociation with Salsolasoda, salinity induced DM decrease was only 6, 12 and 28% in soils with slight, moderate and high salinity as compared to non-saline soil, respectively. However, when Portulaca oleracea used as companion plant, no significant change in biomass or fruit yield was observed. This study showed that mixed planting with Salsolasodain high saline soils may be an effective phyto-remediation technique that may secure yield formation and quality of tomato. (author)

40 CFR 230.25 - Salinity gradients.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Salinity gradients. 230.25 Section 230.25 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY (CONTINUED) OCEAN DUMPING SECTION 404(b... Physical and Chemical Characteristics of the Aquatic Ecosystem § 230.25 Salinity gradients. (a) Salinity...

Art Rocks with Rock Art!

Science.gov (United States)

Bickett, Marianne

2011-01-01

This article discusses rock art which was the very first "art." Rock art, such as the images created on the stone surfaces of the caves of Lascaux and Altimira, is the true origin of the canvas, paintbrush, and painting media. For there, within caverns deep in the earth, the first artists mixed animal fat, urine, and saliva with powdered minerals…

Uranium deposits in granitic rocks

International Nuclear Information System (INIS)

Nishimori, R.K.; Ragland, P.C.; Rogers, J.J.W.; Greenberg, J.K.

1977-01-01

This report is a review of published data bearing on the geology and origin of uranium deposits in granitic, pegmatitic and migmatitic rocks with the aim of assisting in the development of predictive criteria for the search for similar deposits in the U.S. Efforts were concentrated on the so-called ''porphyry'' uranium deposits. Two types of uranium deposits are primarily considered: deposits in pegmatites and alaskites in gneiss terrains, and disseminations of uranium in high-level granites. In Chapter 1 of this report, the general data on the distribution of uranium in igneous and metamorphic rocks are reviewed. Chapter 2 contains some comments on the classification of uranium deposits associated with igneous rocks and a summary of the main features of the geology of uranium deposits in granites. General concepts of the behavior of uranium in granites during crustal evolution are reviewed in Chapter 3. Also included is a discussion of the relationship of uranium mineralization in granites to the general evolution of mobile belts, plus the influence of magmatic and post-magmatic processes on the distribution of uranium in igneous rocks and related ore deposits. Chapter 4 relates the results of experimental studies on the crystallization of granites to some of the geologic features of uranium deposits in pegmatites and alaskites in high-grade metamorphic terrains. Potential or favorable areas for igneous uranium deposits in the U.S.A. are delineated in Chapter 5. Data on the geology of specific uranium deposits in granitic rocks are contained in Appendix 1. A compilation of igneous rock formations containing greater than 10 ppM uranium is included in Appendix 2. Appendix 3 is a report on the results of a visit to the Roessing area. Appendix 4 is a report on a field excursion to eastern Canada

Characterizing fractured plutonic rocks of the Canadian shield for deep geological disposal of Canada's radioactive wastes

International Nuclear Information System (INIS)

Lodha, G.S.; Davison, C.C.; Gascoyne, M.

1998-01-01

Since 1978 AECL has been investigating plutonic rocks of the Canadian Shield as a potential medium for the disposal of Canada's nuclear fuel waste. During the last two years this study has been continued as part of Ontario Hydro's used fuel disposal program. Methods have been developed for characterizing the geotechnical conditions at the regional scale of the Canadian Shield as well as for characterizing conditions at the site scale and the very near-field scale needed for locating and designing disposal vault rooms and waste emplacement areas. The Whiteshell Research Area (WRA) and the Underground Research Laboratory (URL) in southeastern Manitoba have been extensively used to develop and demonstrate the different scales of characterization methods. At the regional scale, airborne magnetic and electromagnetic surveys combined with LANDSAT 5 and surface gravity survey data have been helpful in identifying boundaries of the plutonic rocks , overburden thicknesses, major lineaments that might be geological structures, lithological contacts and depths of the batholiths. Surface geological mapping of exposed rock outcrops, combined with surface VLF/EM, radar and seismic reflection surveys were useful in identifying the orientation and depth continuity of low-dipping fracture zones beneath rock outcrops to a depth of 500 to 1000 m. The surface time-domain EM method has provided encouraging results for identifying the depth of highly saline pore waters. The regional site scale investigations at the WRA included the drilling of twenty deep boreholes (> 500 m) at seven separate study areas. Geological core logging combined with borehole geophysical logging, TV/ATV logging, flowmeter logging and full waveform sonic logging in these boreholes helped to confirm the location of hydro geologically important fractures, orient cores and infer the relative permeability of some fracture zones. Single-hole radar and crosshole seismic tomography surveys were useful to establish the

Natural radionuclides in the rocks of the Valle del Cervo Pluton in Piedmont.

Science.gov (United States)

Sesana, Lucia; Fumagalli, Marco; Carnevale, Mauro; Polla, Giancarla; Facchini, Ugo; Colombo, Annita; Tunesi, Annalisa; De Capitani, Luisa; Rusconi, Rosella

2006-01-01

Monitoring of the gamma radiation in Valle del Cervo Pluton was performed by determining U and Th contents in the main rock types cropping out over the entire area and pertaining to the granitic complex, syenitic complex and monzonitic complex. In particular, syenitic rocks were largely used as building and ornamental materials (e.g. Sienite della Balma). All the samples are fresh and do not present joints or fractures filled with U minerals. In the crushed samples the activity of uranium varies from 346 to 764 Bq/kg. Concentration of thorium varies from 202 to 478 Bq/kg. For all the analysed rocks uranium activity is higher than thorium one. The lowest value of radioactive concentration is referred to rocks of the granitic complex. The most active rocks are syenites. The data confirm the high activities of Valle del Cervo rock types, strongly connected with high K content of the source magma (geochemical signature); on the contrary, the activity seems to be not related to the location of the samples.

Numerical simulation of rock cutting using 2D AUTODYN

International Nuclear Information System (INIS)

Woldemichael, D E; Rani, A M Abdul; Lemma, T A; Altaf, K

2015-01-01

In a drilling process for oil and gas exploration, understanding of the interaction between the cutting tool and the rock is important for optimization of the drilling process using polycrystalline diamond compact (PDC) cutters. In this study the finite element method in ANSYS AUTODYN-2D is used to simulate the dynamics of cutter rock interaction, rock failure, and fragmentation. A two-dimensional single PDC cutter and rock model were used to simulate the orthogonal cutting process and to investigate the effect of different parameters such as depth of cut, and back rake angle on two types of rocks (sandstone and limestone). In the simulation, the cutting tool was dragged against stationary rock at predetermined linear velocity and the depth of cut (1,2, and 3 mm) and the back rake angles(-10°, 0°, and +10°) were varied. The simulation result shows that the +10° back rake angle results in higher rate of penetration (ROP). Increasing depth of cut leads to higher ROP at the cost of higher cutting force. (paper)

Impact of salinity on cathode catalyst performance in microbial fuel cells (MFCs)

KAUST Repository

Wang, Xi

2011-10-01

Several alternative cathode catalysts have been proposed for microbial fuel cells (MFCs), but effects of salinity (sodium chloride) on catalyst performance, separate from those of conductivity on internal resistance, have not been previously examined. Three different types of cathode materials were tested here with increasingly saline solutions using single-chamber, air-cathode MFCs. The best MFC performance was obtained using a Co catalyst (cobalt tetramethoxyphenyl porphyrin; CoTMPP), with power increasing by 24 ± 1% to 1062 ± 9 mW/m2 (normalized to the projected cathode surface area) when 250 mM NaCl (final conductivity of 31.3 mS/cm) was added (initial conductivity of 7.5 mS/cm). This power density was 25 ± 1% higher than that achieved with Pt on carbon cloth, and 27 ± 1% more than that produced using an activated carbon/nickel mesh (AC) cathode in the highest salinity solution. Linear sweep voltammetry (LSV) was used to separate changes in performance due to solution conductivity from those produced by reductions in ohmic resistance with the higher conductivity solutions. The potential of the cathode with CoTMPP increased by 17-20 mV in LSVs when the NaCl addition was increased from 0 to 250 mM independent of solution conductivity changes. Increases in current were observed with salinity increases in LSVs for AC, but not for Pt cathodes. Cathodes with CoTMPP had increased catalytic activity at higher salt concentrations in cyclic voltammograms compared to Pt and AC. These results suggest that special consideration should be given to the type of catalyst used with more saline wastewaters. While Pt oxygen reduction activity is reduced, CoTMPP cathode performance will be improved at higher salt concentrations expected for wastewaters containing seawater. © 2011, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Migmatites and migmatite-like rocks of Olkiluoto

International Nuclear Information System (INIS)

Kaerki, A.

2015-02-01

Bedrock of the Olkiluoto Island in the western end of the Palaeoproterozoic Svecofennian Accretionary Arc Complex, SW Finland is composed of high-grade metamorphic pelites, arenites and intermediate, arc type metavolcanic rocks intruded by granodioritic to tonalitic plutonic rocks. Regional metamorphism culminated with voluminous migmatization in the temperature of 660 - 700 deg C and relatively low pressure of about 3.5 - 4 kbar. The end result of polyphase metamorphism and deformation is a metamorphic rock succession composed of diverse migmatite rocks, metatexites and diatexites. Metatexites are migmatites in which several, discrete components can be detected, and in which the paleosome with some pre-partial-melting textures is identifiable. Diatexites are more advanced migmatites in which the pre-migmatization structures are often totally destroyed and the rock is dominated by different neosome components meaning leucosome, melanosome or mesosome. Based on the migmatite structures the metatexites of Olkiluoto have been classified into six subgroups. Dike-structured metatexites are composed of well preserved paleosome intruded by one single set of narrow, subparallel leucosome dikes which cover ca. 5 - 10 % of the whole rock volume. Net-structure is composed of a network of narrow leucosome dikes which show a reticulated structure in a plane section and cover less than 30 % of the whole rock volume. Breccia-structure is composed of angular or rounded paleosome blocks surrounded by moderate amount of leucosome. Patch-structure is composed of irregular leucosome patches which intruded the well preserved paleosome and compose typically 20 - 70 % of the rock volume. Layer-structure is characterized by more or less regular leucosome dikes sub-parallel to the foliation of the well preserved paleosome. Vein-structured metatexites and also diatexites include a set of pipe-like, longish leucosome veins most probably generated by synchronous melting and deformation

Migmatites and migmatite-like rocks of Olkiluoto

Energy Technology Data Exchange (ETDEWEB)

Kaerki, A. [Kivitieto Oy, Oulu (Finland)

2015-02-15

Bedrock of the Olkiluoto Island in the western end of the Palaeoproterozoic Svecofennian Accretionary Arc Complex, SW Finland is composed of high-grade metamorphic pelites, arenites and intermediate, arc type metavolcanic rocks intruded by granodioritic to tonalitic plutonic rocks. Regional metamorphism culminated with voluminous migmatization in the temperature of 660 - 700 deg C and relatively low pressure of about 3.5 - 4 kbar. The end result of polyphase metamorphism and deformation is a metamorphic rock succession composed of diverse migmatite rocks, metatexites and diatexites. Metatexites are migmatites in which several, discrete components can be detected, and in which the paleosome with some pre-partial-melting textures is identifiable. Diatexites are more advanced migmatites in which the pre-migmatization structures are often totally destroyed and the rock is dominated by different neosome components meaning leucosome, melanosome or mesosome. Based on the migmatite structures the metatexites of Olkiluoto have been classified into six subgroups. Dike-structured metatexites are composed of well preserved paleosome intruded by one single set of narrow, subparallel leucosome dikes which cover ca. 5 - 10 % of the whole rock volume. Net-structure is composed of a network of narrow leucosome dikes which show a reticulated structure in a plane section and cover less than 30 % of the whole rock volume. Breccia-structure is composed of angular or rounded paleosome blocks surrounded by moderate amount of leucosome. Patch-structure is composed of irregular leucosome patches which intruded the well preserved paleosome and compose typically 20 - 70 % of the rock volume. Layer-structure is characterized by more or less regular leucosome dikes sub-parallel to the foliation of the well preserved paleosome. Vein-structured metatexites and also diatexites include a set of pipe-like, longish leucosome veins most probably generated by synchronous melting and deformation

Saline instillation before tracheal suctioning decreases the incidence of ventilator-associated pneumonia.

Science.gov (United States)

Caruso, Pedro; Denari, Silvia; Ruiz, Soraia A L; Demarzo, Sergio E; Deheinzelin, Daniel

2009-01-01

To compare the incidence of ventilator-associated pneumonia (VAP) with or without isotonic saline instillation before tracheal suctioning. As a secondary objective, we compared the incidence of endotracheal tube occlusion and atelectasis. Randomized clinical trial. The study was conducted in a medical surgical intensive care unit of an oncologic hospital. We selected consecutive patients needing mechanical ventilation for >72 hrs. Patients were allocated into two groups: a saline group that received instillation of 8 mL of saline before tracheal suctioning and a control group which did not. VAP was diagnosed based on clinical suspicion and confirmed by bronchoalveolar lavage quantitative culture. The incidence of atelectasis on daily chest radiography and endotracheal tube occlusions were recorded. The sample size was calculated to a power of 80% and a type I error probability of 5%. One hundred thirty patients were assigned to the saline group and 132 to the control group. The baseline demographic variables were similar between groups. The rate of clinically suspected VAP was similar in both groups. The incidence of microbiological proven VAP was significantly lower in the saline group (23.5% x 10.8%; p = 0.008) (incidence density/1.000 days of ventilation 21.22 x 9.62; p < 0.01). Using the Kaplan-Meier curve analysis, the proportion of patients remaining without VAP was higher in the saline group (p = 0.02, log-rank test). The relative risk reduction of VAP in the saline instillation group was 54% (95% confidence interval, 18%-74%) and the number needed to treat was eight (95% confidence interval, 5-27). The incidence of atelectases and endotracheal tube occlusion were similar between groups. Instillation of isotonic saline before tracheal suctioning decreases the incidence of microbiological proven VAP.

Mineralogical and textural characteristics of Kakul (Hazara) phosphate rock, NWFP, Pakistan

International Nuclear Information System (INIS)

Mehmood, R.; Bhatti, M.A.; Kazmi, K.R.; Mehmood, A.; Sheikh, S.T.; Aleem Shah, S.A.

2010-01-01

Various types of minerals, present in phosphate rock of Hazara area of Khyber Pukhtoonkhwa Province of Pakistan, were identified and their concentration was determined using a suitable method. The characteristics of the rock were defined by petrography, X-ray diffraction, and chemical analysis and the textural characteristics such as grain size, grain shape and their arrangement in the rock body were also investigated. The degree of liberation of phosphate-bearing mineral was studied by the particle-counting method. Mineralogical and textural observations indicated that fine-grained rock may be suitable for beneficiation by the froth flotation separation technique. (author)

Variation in the Abundance of OsHAK1 Transcript Underlies the Differential Salinity Tolerance of an indica and a japonica Rice Cultivar

Directory of Open Access Journals (Sweden)

Guang Chen

2018-01-01

Full Text Available Salinity imposes a major constraint over the productivity of rice. A set of chromosome segment substitution lines (CSSLs, derived from a cross between the japonica type cultivar (cv. Nipponbare (salinity sensitive and the indica type cv. 9311 (moderately tolerant, was scored using a hydroponics system for their salinity tolerance at the seedling stage. Two of the CSSLs, which share a ∼1.2 Mbp stretch of chromosome 4 derived from cv. Nipponbare, were as sensitive to the stress as cv. Nipponbare itself. Fine mapping based on an F2 population bred from a backcross between one of these CSSLs and cv. 9311 narrowed this region to 95 Kbp, within which only one gene (OsHAK1 exhibited a differential (lower transcript abundance in cv. Nipponbare and the two CSSLs compared to in cv. 9311. The gene was up-regulated by exposure to salinity stress both in the root and the shoot, while a knockout mutant proved to be more salinity sensitive than its wild type with respect to its growth at both the vegetative and reproductive stages. Seedlings over-expressing OsHAK1 were more tolerant than wild type, displaying a superior photosynthetic rate, a higher leaf chlorophyll content, an enhanced accumulation of proline and a reduced level of lipid peroxidation. At the transcriptome level, the over-expression of OsHAK1 stimulated a number of stress-responsive genes as well as four genes known to be involved in Na+ homeostasis and the salinity response (OsHKT1;5, OsSOS1, OsLti6a and OsLti6b. When the stress was applied at booting through to maturity, the OsHAK1 over-expressors out-yielded wild type by 25%, and no negative pleiotropic effects were expressed in plants gown under non-saline conditions. The level of expression of OsHAK1 was correlated with Na+/K+ homeostasis, which implies that the gene should be explored a target for molecular approaches to the improvement of salinity tolerance in rice.

Geochemical behavior of Cs, Sr, Tc, Np, and U in saline groundwaters: Sorption experiments on shales and their clay mineral components: Progress report

International Nuclear Information System (INIS)

Meyer, R.E.; Arnold, W.D.; Ho, P.C.; Case, F.I.; O'Kelley, G.D.

1987-11-01

The Sedimentary Rock Program at the Oak Ridge National Laboratory is investigating shale to determine its potential suitability as a host rock for the disposal of high-level radioactive wastes (HLW). In support of this program, preliminary studies were carried out on sorption of cesium, strontium, technetium, neptunium, and uranium onto Chattanooga (Upper Dowelltown), Pierre, Green River Formation, Nolichucky, and Pumpkin Valley Shales under oxic conditions (air present). Three simulated groundwaters were used. One of the groundwaters was a synthetic brine made up to simulate highly saline groundwaters in the Pumpkin Valley Shale. The second was a 100/1 dilution of this groundwater and the third was 0.03 M NaHCO 3 . Moderate to significant sorption was observed under most conditions for all of the tested radionuclides except technetium. Moderate technetium sorption occurred on Upper Dowelltown Shale, and although technetium sorption was low on the other shales, it was higher than expected for Tc(VII), present as the anion TcO 4 - . Little sorption of strontium onto the shales was observed from the concentrated saline groundwater. These data can be used in a generic fashion to help assess the sorption characteristics of shales in support of a national survey. 10 refs., 4 figs., 23 tabs

Wisconsin Glaciation of the Sierra Nevada (79,000-15,000 yr B.P.) as Recorded by Rock Flour in Sediments of Owens Lake, California

Science.gov (United States)

Bischoff, James L.; Cummins, Kathleen

2001-01-01

Chemical analyses of the clay-sized fractions of 564 continuous sediment samples (200-yr resolution) from composite core OL90/92 allow quantification of an abundance of glacial rock flour. Rock flour produced during glacier advances is represented by clay-sized plagioclase, K-feldspar, and biotite in homogeneous internal composition. The abundance of rock flour is deemed proportional to the intensity of glacies advances. Age control for the composite section is provided by combining previously published radiocarbon dates on organics, U/Th dates on ostracode shells, and U/Th dates on saline minerals from nearby Searles Lake correlated to OL92 by pollen. The rock flour record displays three levels of variability: (1) a dominant one of about 20,000 yr related to summer insolation and precipitation; (2) an intermediate one of 3000-5000 yr, perhaps related to North Atlantic Heinrich events; and (3) a minor one of 1000-2000 yr, perhaps related to North Atlantic thermohaline-driven air-temperature variation.

Coupled Large Scale Hydro-mechanical Modelling for cap-rock Failure Risk Assessment of CO2 Storage in Deep Saline Aquifers

International Nuclear Information System (INIS)

Rohmer, J.; Seyedi, D.M.

2010-01-01

This work presents a numerical strategy of large scale hydro-mechanical simulations to assess the risk of damage in cap-rock formations during a CO 2 injection process. The proposed methodology is based on the development of a sequential coupling between a multiphase fluid flow (TOUGH2) and a hydro-mechanical calculation code (Code-Aster) that enables us to perform coupled hydro-mechanical simulation at a regional scale. The likelihood of different cap-rock damage mechanisms can then be evaluated based on the results of the coupled simulations. A scenario based approach is proposed to take into account the effect of the uncertainty of model parameters on damage likelihood. The developed methodology is applied for the cap-rock failure analysis of deep aquifer of the Dogger formation in the context of the Paris basin multilayered geological system as a demonstration example. The simulation is carried out at a regional scale (100 km) considering an industrial mass injection rate of CO 2 of 10 Mt/y. The assessment of the stress state after 10 years of injection is conducted through the developed sequential coupling. Two failure mechanisms have been taken into account, namely the tensile fracturing and the shear slip reactivation of pre-existing fractures. To deal with the large uncertainties due to sparse data on the layer formations, a scenario based strategy is undertaken. It consists in defining a first reference modelling scenario considering the mean values of the hydro-mechanical properties for each layer. A sensitivity analysis is then carried out and shows the importance of both the initial stress state and the reservoir hydraulic properties on the cap-rock failure tendency. On this basis, a second scenario denoted 'critical' is defined so that the most influential model parameters are taken in their worst configuration. None of these failure criteria is activated for the considered conditions. At a phenomenological level, this study points out three key

Fractures and Rock Mechanics, Phase 1

DEFF Research Database (Denmark)

Krogsbøll, Anette; Jakobsen, Finn; Madsen, Lena

1997-01-01

The main objective of the project is to combine geological descriptions of fractures, chalk types and rock mechanical properties in order to investigate whether the chosen outcrops can be used as analogues to reservoir chalks. This report deals with 1) geological descriptions of outcrop locality...

Electrocapillary Phenomena at Edible Oil/Saline Interfaces.

Science.gov (United States)

Nishimura, Satoshi; Ohzono, Takuya; Shoji, Kohei; Yagihara, Shin; Hayashi, Masafumi; Tanaka, Hisao

2017-03-01

Interfacial tension between edible oil and saline was measured under applied electric fields to understand the electrocapillary phenomena at the edible oil/saline interfaces. The electric responses of saline droplets in edible oil were also observed microscopically to examine the relationship between the electrocapillary phenomena and interfacial polarization. When sodium oleate (SO) was added to edible oil (SO-oil), the interfacial tension between SO-oil and saline decreased. However, no decrease was observed for additive-free oil or oleic acid (OA)-added oil (OA-oil). Microscopic observations suggested that the magnitude of interfacial polarization increased in the order of additive-free oil oil oil. The difference in electrocapillary phenomena between OA- and SO-oils was closely related to the polarization magnitude. In the case of SO-oil, the decrease in interfacial tension was remarkably larger for saline (pH 5.4~5.6) than that for phosphate-buffered saline (PBS, pH 7.2~7.4). However, no difference was observed between the electric responses of PBS and saline droplets in SO-oil. The difference in electrocapillary phenomena for PBS and saline could not be simply explained in terms of polarization magnitude. The ratio of ionized and non-ionized OA at the interfaces changed with the saline pH, possibly leading to the above difference.

Genetically modified plants for salinity stress tolerance (abstract)

International Nuclear Information System (INIS)

Sopory, S.K.; Singia-Pareek, S.I.; Kumar, S.; Rajgopal, D.; Aggarwal, P.; Kumar, D.; Reddy, K.M.

2005-01-01

Several recent reports have indicated that the area under salinity is on the increase and currently very few genotypes of important crop plants are available for cultivation under these conditions. In this regard, identification of novel stress responsive genes and transgenic approach offers an important strategy to develop salt tolerant plants. Using an efficient PCR-based cDNA subtraction method a large number of genes upregulated under salinity and dehydration stress have been identified also in rice and Pennisetum. Functional analysis of some of these genes is being done using transgenic approach. Earlier, we reported on the role of one of the stress regulated genes, glyoxalse I in conferring salinity tolerance. We now show that by manipulating the expression of both the genes of the glyoxalse pathway, glyoxalse I and II together, the ability of the double transgenic plants to tolerate salinity stress is greatly enhanced as compared to the single transgenic plants harbouring either the glyoxalse I or glyoxalse II. The cDNA for glyoxalse II was cloned from rice and mobilized into pCAMBIA vector having hptII gene as the selection marker. The seedlings of the T1 generation transgenic plants survived better under high salinity compared to the wild type plants; the double transgenics had higher limits of tolerance as compared to the lines transformed with single gene. A similar trend was seen even when plants were grown in pots under glass house conditions and raised to maturity under the continued presence of NaCl. In this, the transgenic plants were able to grow, flower and set seeds. The overexpression of glyoxalse pathway was also found to confer stress tolerance in rice. We have also isolated a gene encoding vacuolar sodium/proton antiporter from Pennisetum and over expressed in Brassica juncea and rice. The transgenic plants were able to tolerate salinity stress. Our work along with many others' indicates the potential of transgenic technology in developing

Biogeochemical cycling of arsenic in coastal salinized aquifers: Evidence from sulfur isotope study

Energy Technology Data Exchange (ETDEWEB)

Kao, Yu-Hsuan [Department of Bioenvironmental Systems Engineering, National Taiwan University, Taipei 106, Taiwan, ROC (China); Wang, Sheng-Wei [Agricultural Engineering Research Center, Chungli 320, Taiwan, ROC (China); Liu, Chen-Wuing, E-mail: lcw@gwater.agec.ntu.edu.tw [Department of Bioenvironmental Systems Engineering, National Taiwan University, Taipei 106, Taiwan, ROC (China); Wang, Pei-Ling [Institute of Oceanography, National Taiwan University, Taipei 106, Taiwan, ROC (China); Wang, Chung-Ho [Institute of Earth Sciences, Academia Sinica, Taipei 115, Taiwan, ROC (China); Maji, Sanjoy Kumar [Department of Bioenvironmental Systems Engineering, National Taiwan University, Taipei 106, Taiwan, ROC (China)

2011-10-15

Arsenic (As) contamination of groundwater, accompanied by critical salinization, occurs in the southwestern coastal area of Taiwan. Statistical analyses and geochemical calculations indicate that a possible source of aqueous arsenic is the reductive dissolution of As-bearing iron oxyhydroxides. There are few reports of the influence of sulfate-sulfide redox cycling on arsenic mobility in brackish groundwater. We evaluated the contribution of sulfate reduction and sulfide re-oxidation on As enrichment using {delta}{sup 34}S{sub [SO{sub 4]}} and {delta}{sup 18}O{sub [SO{sub 4]}} sulfur isotopic analyses of groundwater. Fifty-three groundwater samples were divided into groups of high-As content and salinized (Type A), low-As and non-salinized (Type B), and high-As and non-salinized (Type C) groundwaters, based on hydro-geochemical analysis. The relatively high enrichment of {sup 34}S{sub [SO{sub 4]}} and {sup 18}O{sub [SO{sub 4]}} present in Type A, caused by microbial-mediated reduction of sulfate, and high {sup 18}O enrichment factor ({epsilon}{sub [SO{sub 4-H{sub 2O]}}}), suggests that sulfur disproportionation is an important process during the reductive dissolution of As-containing iron oxyhydroxides. Limited co-precipitation of ion-sulfide increased the rate of As liberation under anaerobic conditions. In contrast to this, Type B and Type C groundwater samples showed high {delta}{sup 18}O{sub [SO{sub 4]}} and low {delta}{sup 34}S{sub [SO{sub 4]}} values under mildly reducing conditions. Base on {sup 18}O mass balance calculations, the oxide sources of sulfate are from infiltrated atmospheric O{sub 2}, caused by additional recharge of dissolved oxygen and sulfide re-oxidation. The anthropogenic influence of extensive pumping also promotes atmospheric oxygen entry into aquifers, altering redox conditions, and increasing the rate of As release into groundwater. - Highlights: {yields} Seawater intrusion and elevated As are the main issues of groundwater in Taiwan

A meta-analysis of soil salinization effects on nitrogen pools, cycles and fluxes in coastal ecosystems.

Science.gov (United States)

Zhou, Minghua; Butterbach-Bahl, Klaus; Vereecken, Harry; Brüggemann, Nicolas

2017-03-01

Salinity intrusion caused by land subsidence resulting from increasing groundwater abstraction, decreasing river sediment loads and increasing sea level because of climate change has caused widespread soil salinization in coastal ecosystems. Soil salinization may greatly alter nitrogen (N) cycling in coastal ecosystems. However, a comprehensive understanding of the effects of soil salinization on ecosystem N pools, cycling processes and fluxes is not available for coastal ecosystems. Therefore, we compiled data from 551 observations from 21 peer-reviewed papers and conducted a meta-analysis of experimental soil salinization effects on 19 variables related to N pools, cycling processes and fluxes in coastal ecosystems. Our results showed that the effects of soil salinization varied across different ecosystem types and salinity levels. Soil salinization increased plant N content (18%), soil NH 4 + (12%) and soil total N (210%), although it decreased soil NO 3 - (2%) and soil microbial biomass N (74%). Increasing soil salinity stimulated soil N 2 O fluxes as well as hydrological NH 4 + and NO 2 - fluxes more than threefold, although it decreased the hydrological dissolved organic nitrogen (DON) flux (59%). Soil salinization also increased the net N mineralization by 70%, although salinization effects were not observed on the net nitrification, denitrification and dissimilatory nitrate reduction to ammonium in this meta-analysis. Overall, this meta-analysis improves our understanding of the responses of ecosystem N cycling to soil salinization, identifies knowledge gaps and highlights the urgent need for studies on the effects of soil salinization on coastal agro-ecosystem and microbial N immobilization. Additional increases in knowledge are critical for designing sustainable adaptation measures to the predicted intrusion of salinity intrusion so that the productivity of coastal agro-ecosystems can be maintained or improved and the N losses and pollution of the natural

Investigation of trace uranium content in rock phosphate ore samples from Kurun-Uro area, Nuba Mountains, Sudan

International Nuclear Information System (INIS)

Ali, Abdel Majid Abdel Galil Mohammed

1999-07-01

This investigation was carried out mainly to test the trace uranium level content in rock phosphate, which was used as a low cost fertilizer. Two types of rock phosphate were examined, namely, Kurun and Uro rocks from Nuba Mountains in the Southern Kurdufan province, Sudan.This area has a high background natural radioactivity. Moreover, it contains a rock phosphate zone lying between J. Kurun and Uro. The work included analytical methods carried out for thr rock phosphate samples using spectrophotometric and X-ray fluorescence techniques. The results obtained were compared with the data from literature and they showed a good agreement.The data was statistically analyzed to compare the results by the two techniques. The results of uranium content determined by the two analytical methods were significantly similar.The instrumental analysis revealed that different. Uranium content in the rocks phosphate samples of Uro type was found to be 1.6 times higher than Kurun type. (Author)

Metamorphic rock-hosted orogenic gold deposit style at Bombana (Southeast Sulawesi and Buru Island (Maluku: Their key features and significances for gold exploration in Eastern Indonesia