Isotopic evidence for identifying the mechanism of salinization of groundwater in Bacolod City,Negros Occidental

International Nuclear Information System (INIS)

Castaneda, Soledad S.; Almoneda, Rosalinda V.; Sucgang, Raymond J.; Desengano, Daisy; Lim, Fatima

2008-01-01

Saline water is easily identified by measurement of the conductivity of the ionic species in the water. In groundwater, it is important to identify the mechanism of salinization for proper management of the resource. Salinization may come from: a) leaching of salts by percolating water, b) intrusion of modern saltwater bodies of connate water, and c) concentration of dissolved salts due to evaporation. The salinity and isotopic concentrations of 18 O, 2 H, and 3 H of the water sources were used to assess the processes which lead to the salinization of groundwater in Bacolod City, Negros Occidental. The isotopic composition of deep groundwater, river water, and springs cluster along the LMWL with δ 18 O ranging from -7.9 ''promille'' to -6.5 ''promille'' and δ 2 H ranging from -52.6 ''promille'' to -39.1''promille''. Two isotopically distinct groups of deep groundwater were deleated; the higher elevation wells yielding isotopically depleted waters while the lowland wells yielding relatively enriched water with higher conductivity. The shallow coastal wells exhibited more enriched isotope values with δ 18 O values from 6.10 ''promille''-5.61''promille'' and δ 2 H from -43.1''promille'' to -38.8''promille'' and highest conductivity. The relative enrichment in the isotopic composition of the deep groundwater in the lowland and the shallow groundwater along the coast is attributed to saltwater intrusion. The process of salinization in these waters is differentiated based on the relationship between their isotopic compositions and the chlorine concentrations. The high salinity of the isotopically enriched and old deep groundwater inland is attributed to mixing with connate water. On the other hand , mixing with modern sea water is evident in the deep and shallow coastal wells. (author)

Assessment of groundwater salinity in Nellore district using multi ...

Indian Academy of Sciences (India)

water samples at six locations close to the electrical resistivity survey sites also suggest high ... Electrical resistivity imaging; Nellore district; groundwater salinity; geochemistry. ..... Sasaki Y 1992 Resolution of resistivity tomography inferred.

Site scale groundwater flow in Olkiluoto - complementary simulations

International Nuclear Information System (INIS)

Loefman, J.

2000-06-01

This work comprises of the complementary simulations to the previous groundwater flow analysis at the Olkiluoto site. The objective is to study the effects of flow porosity, conceptual model for solute transport, fracture zones, land uplift and initial conditions on the results. The numerical simulations are carried out up to 10000 years into the future employing the same modelling approach and site-specific flow and transport model as in the previous work except for the differences in the case descriptions. The result quantities considered are the salinity and the driving force in the vicinity of the repository. The salinity field and the driving force are sensitive to the flow porosity and the conceptual model for solute transport. Ten-fold flow porosity and the dual-porosity approach retard the transport of solutes in the bedrock resulting in brackish groundwater conditions at the repository at 10000 years A.P. (in the previous work the groundwater in the repository turned into fresh). The higher driving forces can be attributed to the higher concentration gradients resulting from the opposite effects of the land uplift, which pushes fresh water deeper and deeper into the bedrock, and the higher flow porosity and the dual-porosity model, which retard the transport of solutes. The cases computed (unrealistically) without fracture zones and postglacial land uplift show that they both have effect on the results and can not be ignored in the coupled and transient groundwater flow analyses. The salinity field and the driving force are also sensitive to the initial salinity field especially at the beginning during the first 500 years A.P. The sensitivity will, however, diminish as soon as fresh water dilutes brackish and saline water and decreases the concentration gradients. Fresh water conditions result in also a steady state for the driving force in the repository area. (orig.)

A groundwater salinity hotspot and its connection to an intermittent stream identified by environmental tracers (Mt Lofty Ranges, South Australia)

Science.gov (United States)

Anderson, Thomas A.; Bestland, Erick A.; Soloninka, Lesja; Wallis, Ilka; Banks, Edward W.; Pichler, Markus

2017-12-01

High and variable levels of salinity were investigated in an intermittent stream in a high-rainfall area (˜800 mm/year) of the Mt. Lofty Ranges of South Australia. The groundwater system was found to have a local, upslope saline lens, referred to here as a groundwater salinity `hotspot'. Environmental tracer analyses (δ18O, δ2H, 87/86Sr, and major elements) of water from the intermittent stream, a nearby permanent stream, shallow and deep groundwater, and soil-water/runoff demonstrate seasonal groundwater input of very saline composition into the intermittent stream. This input results in large salinity increases of the stream water because the winter wet-season stream flow decreases during spring in this Mediterranean climate. Furthermore, strontium and water isotope analyses demonstrate: (1) the upslope-saline-groundwater zone (hotspot) mixes with the dominant groundwater system, (2) the intermittent-stream water is a mixture of soil-water/runoff and the upslope saline groundwater, and (3) the upslope-saline-groundwater zone results from the flushing of unsaturated-zone salts from the thick clayey regolith and soil which overlie the metamorphosed shale bedrock. The preferred theory on the origin of the upslope-saline-groundwater hotspot is land clearing of native deep-rooted woodland, followed by flushing of accumulated salts from the unsaturated zone due to increased recharge. This cause of elevated groundwater and surface-water salinity, if correct, could be widespread in Mt. Lofty Ranges areas, as well as other climatically and geologically similar areas with comparable hydrogeologic conditions.

Problems of irrigated agriculture in saline groundwater areas: farmers' perceptions

International Nuclear Information System (INIS)

Ahmad, S.; Yasin, M.; Ahmad, M.M.; Hussain, Z.; Khan, Z.; Akbar, G.

2005-01-01

A research study was conducted using participatory interactive dialogue in the brackish groundwater area of Mona SCARP-II, Bhalwal district Sargodha, Pakistan. The Participatory Rural Appraisal (PRA) was conducted in thirteen villages to identify macro- and micro-level issues related to irrigated agriculture in saline groundwater areas. SCARP tube wells have been abandoned or few have been handed over to farmers' organizations. Groundwater in the Indus basin contributes around 35% to the total water available for agriculture. Water quality of 60% area of the Indus basin is marginal to brackish. Minimum land holding of cultivated land in the elected villages varied from 0.10 to 4 ha. The maximum land holding of cultivated area in selected villages varied for 6 to 50 ha. However, the average size of farm was around 4 ha. The average salt-affected area per household was 17% of the total cultivated area. The salt-affected lands in 8 villages out of 13 were barren, where mainly rice crop is grown during kharif season. About 67% farms had access to conjunctive use of water, as water from both canal and private tube wells is available. In addition, 10% farms were having tube well water only. Therefore, 77% farms are having access to the groundwater. According to the farmers' perceptions, 100% villages have fresh groundwater to a depth of 7.5 m and 62% villages had depth ranging from 15-30 m. Furthermore, in all thirteen selected villages, groundwater quality beyond 30 m depth was brackish. Laboratory analysis confirmed the farmer's perception that groundwater quality is a function of depth. About 92% farmers groups indicated that non-availability and high price of inputs was a major problem. The second major issue was related to the shortage of canal water supplies and 77% villages are facing this problem. Moreover, 31% farmers' groups of selected villages indicated that water logging and salinity are the major concerns affecting agricultural productivity. This figure is

Impact of hydrogeological factors on groundwater salinization due to ocean-surge inundation

Science.gov (United States)

Yang, Jie; Zhang, Huichen; Yu, Xuan; Graf, Thomas; Michael, Holly A.

2018-01-01

Ocean surges cause seawater inundation of coastal inland areas. Subsequently, seawater infiltrates into coastal aquifers and threatens the fresh groundwater resource. The severity of resulting salinization can be affected by hydrogeological factors including aquifer properties and hydrologic conditions, however, little research has been done to assess these effects. To understand the impacts of hydrogeological factors on groundwater salinization, we numerically simulated an ocean-surge inundation event on a two-dimensional conceptual coastal aquifer using a coupled surface-subsurface approach. We varied model permeability (including anisotropy), inland hydraulic gradient, and recharge rate. Three salinization-assessment indicators were developed, based on flushing time, depth of salt penetration, and a combination of the two, weighted flushing time, with which the impact of hydrogeological factors on groundwater vulnerability to salinization were quantitatively assessed. The vulnerability of coastal aquifers increases with increasing isotropic permeability. Low horizontal permeability (kx) and high vertical permeability (kz) lead to high aquifer vulnerability, and high kx and low kz lead to low aquifer vulnerability. Vulnerability decreases with increasing groundwater hydraulic gradient and increasing recharge rate. Additionally, coastal aquifers with a low recharge rate (R ≤ 300 mm yr-1) may be highly vulnerable to ocean-surge inundation. This study shows how the newly introduced indicators can be used to quantitatively assess coastal aquifer vulnerability. The results are important for global vulnerability assessment of coastal aquifers to ocean-surge inundation.

Integral Analysis of Field Work and Laboratory Electrical Resistivity Imaging for Saline Water Intrusion Prediction in Groundwater

Science.gov (United States)

Zawawi, M. H.; Zahar, M. F.; Hashim, M. M. M.; Hazreek, Z. A. M.; Zahari, N. M.; Kamaruddin, M. A.

2018-04-01

Saline water intrusion is a serious threat to the groundwater as many part of the world utilize groundwater as their main source of fresh water supply. The usage of high salinity level of water as drinking water can lead to a very serious health hazard towards human. Saline water intrusion is a process by which induced flow of seawater into freshwater aquifer along the coastal area. It might happen due to human action and/or by natural event. The climate change and rise up of sea level may speed up the saline water intrusion process. The conventional method for distinguishing and checking saltwater interference to groundwater along the coast aquifers is to gather and test the groundwater from series of observation wells (borehole) with an end goal to give the important information about the hydrochemistry data to conclude whether the water in the well are safe to consume or not. An integrated approach of field and laboratory electrical resistivity investigation is proposed for indicating the contact region between saline and fresh groundwater. It was found that correlation for both soilbox produced almost identical curvilinear trends for 2% increment of seawater tested using sand sample. This project contributes towards predicting the saline water intrusion to the groundwater by non-destructive test that can replaced the conventional method of groundwater monitoring using series of boreholes in the coastal area

Salinity of deep groundwater in California: Water quantity, quality, and protection

Science.gov (United States)

Kang, Mary; Jackson, Robert B.

2016-01-01

Deep groundwater aquifers are poorly characterized but could yield important sources of water in California and elsewhere. Deep aquifers have been developed for oil and gas extraction, and this activity has created both valuable data and risks to groundwater quality. Assessing groundwater quantity and quality requires baseline data and a monitoring framework for evaluating impacts. We analyze 938 chemical, geological, and depth data points from 360 oil/gas fields across eight counties in California and depth data from 34,392 oil and gas wells. By expanding previous groundwater volume estimates from depths of 305 m to 3,000 m in California’s Central Valley, an important agricultural region with growing groundwater demands, fresh [groundwater volume is almost tripled to 2,700 km3, most of it found shallower than 1,000 m. The 3,000-m depth zone also provides 3,900 km3 of fresh and saline water, not previously estimated, that can be categorized as underground sources of drinking water (USDWs; freshwater zones and USDWs, respectively, in the eight counties. Deeper activities, such as wastewater injection, may also pose a potential threat to groundwater, especially USDWs. Our findings indicate that California’s Central Valley alone has close to three times the volume of fresh groundwater and four times the volume of USDWs than previous estimates suggest. Therefore, efforts to monitor and protect deeper, saline groundwater resources are needed in California and beyond. PMID:27354527

Coastal hazards and groundwater salinization on low coral islands.

Science.gov (United States)

Terry, James P.; Chui, T. F. May

2016-04-01

Remote oceanic communities living on low-lying coral islands (atolls) without surface water rely for their survival on the continuing viability of fragile groundwater resources. These exist in the form of fresh groundwater lenses (FGLs) that develop naturally within the porous coral sand and gravel substrate. Coastal hazards such as inundation by high-energy waves driven by storms and continuing sea-level rise (SLR) are among many possible threats to viable FGL size and quality on atolls. Yet, not much is known about the combined effects of wave washover during powerful storms and SLR on different sizes of coral island, nor conversely how island size influences lens resilience against damage. This study investigates FGL damage by salinization (and resilience) caused by such coastal hazards using a modelling approach. Numerical modelling is carried out to generate steady-state FGL configurations at three chosen island sizes (400, 600 and 800 m widths). Steady-state solutions reveal how FGL dimensions are related in a non-linear manner to coral island size, such that smaller islands develop much more restricted lenses than larger islands. A 40 cm SLR scenario is then imposed. This is followed by transient simulations to examine storm-induced wave washover and subsequent FGL responses to saline damage over a 1 year period. Smaller FGLs display greater potential for disturbance by SLR, while larger and more robust FGLs tend to show more resilience. Further results produce a somewhat counterintuitive finding: in the post-SLR condition, FGL vulnerability to washover salinization may actually be reduced, owing to the thinner layer of unsaturated substrate lying above the water table into which saline water can infiltrate during a storm event. Nonetheless, combined washover and SLR impacts imply overall that advancing groundwater salinization may lead to some coral islands becoming uninhabitable long before they are completely submerged by sea-level rise, thereby calling

Strategies for safe exploitation of fresh water through multi-strainer skimming wells in saline groundwater areas

International Nuclear Information System (INIS)

Alam, M.M.; Jaffery, H.M.; Hanif, M.

2005-01-01

Due to growing population of Pakistan, there is a tremendous pressure on our agriculture sector to increase its production to meet the food and fiber requirement. Water is a basic need to increase the agriculture production and to bring more areas under cultivation. The exploitation of groundwater resources is increasing because of limited surface water availability. Statistics indicated that number of public and private tube-wells have increased to more than 5 lacs. Over exploitations of groundwater caused a number of environmental problems including salt water intrusion and increase in the soil and groundwater salinity. A large number of fresh water tube-wells have started pumping saline groundwater in various parts of Pakistan indicating up-coning of saline groundwater in the relatively fresh water aquifers. Use of poor quality groundwater for irrigation is considered as one of the major causes of salinity in the areas of irrigated agriculture. Indiscriminate pumping of the groundwater of marginal quality through skimming fresh water overlain by saline groundwater can not be helpful in the long run. It can add to the root zone salinity and ultimately reduction of crops yield. Mona Reclamation Experimental Project (MREP) is conducting a collaborative research study on 'Root Zone Salinity Management using Fractional Skimming Wells with Pressurized Irrigation' under a research and studies portfolio of the country wide National Drainage Programme (NDP) MREP, IWMI Pakistan and Water Resources Research Institute of PARC are collaborators in this joint research effort. MREP is responsible to specifically address the objective of the study to identify and test a limited number of promising skimming well techniques in the shallow fresh water aquifers which could control the saline water up-coning phenomenon as a consequence of groundwater pumping. Detailed investigations have been done at various locations in the north-central part of Chaj Doab (Sargodha Region) in the

What Drives Saline Circulation Cells in Coastal Aquifers? An Energy Balance for Density-Driven Groundwater Systems

Science.gov (United States)

Harvey, C. F.; Michael, H. A.

2017-12-01

We formulate the energy balance for coastal groundwater systems and apply it to: (1) Explain the energy driving offshore saline circulation cells, and; (2) Assess the accuracy of numerical simulations of coastal groundwater systems. The flow of fresh groundwater to the ocean is driven by the loss of potential energy as groundwater drops from the elevation of the inland watertable, where recharge occurs, to discharge at sea level. This freshwater flow creates an underlying circulation cell of seawater, drawn into coastal aquifers offshore and discharging near shore, that adds to total submarine groundwater discharge. The saline water in the circulation cell enters and exits the aquifer through the sea floor at the same hydraulic potential. Existing theory explains that the saline circulation cell is driven by mixing of fresh and saline without any additional source of potential or mechanical power. This explanation raises a basic thermodynamic question: what is the source of energy that drives the saline circulation cell? Here, we resolve this question by building upon Hubbert's conception of hydraulic potential to formulate an energy balance for density-dependent flow and salt transport through an aquifer. We show that, because local energy dissipation within the aquifer is proportional to the square of the groundwater velocity, more groundwater flow may be driven through an aquifer for a given energy input if local variations in velocity are smoothed. Our numerical simulations of coastal groundwater systems show that dispersion of salt across the fresh-saline interface spreads flow over larger volumes of the aquifer, smoothing the velocity field, and increasing total flow and submarine groundwater discharge without consuming more power. The energy balance also provides a criterion, in addition to conventional mass balances, for judging the accuracy of numerical solutions of non-linear density-dependent flow problems. Our results show that some numerical

Salty or Sweet: Exploring the Challenges of Groundwater Salinization Within a Sustainability Framework

Science.gov (United States)

Basu, N. B.; Van Meter, K. J.; Tate, E.

2012-12-01

In semi-arid to arid landscapes under intensive irrigation, groundwater salinization can be a persistent and critical problem, leading to reduced agricultural productivity, limited access to fresh drinking water, and ultimately desertification. It is estimated that in India alone, problems of salinity are now affecting over 6 million hectares of agricultural land. In villages of the Mewat district of Haryana in Northern India, subsistence-level farming is the primary source of income, and farming families live under serious threat from increasing salinity levels, both in terms of crop production and adequate supplies of drinking water. The Institute for Rural Research and Development (IRRAD), a non-governmental organization (NGO) working in Mewat, has taken an innovative approach in this area to problems of groundwater salinization, using check dams and rainwater harvesting ponds to recharge aquifers in the freshwater zones of upstream hill areas, and to create freshwater pockets within the saline groundwater zones of down-gradient areas. Initial, pilot-scale efforts have led to apparent success in raising groundwater levels in freshwater zones and changing the dynamics of encroaching groundwater salinity, but the expansion of such efforts to larger-scale restoration is constrained by the availability of adequate resources. Under such resource constraints, which are typical of international development work, it becomes critical to utilize a decision-analysis framework to quantify both the immediate and long-term effectiveness and sustainability of interventions by NGOs such as IRRAD. In the present study, we have developed such a framework, linking the climate-hydrological dynamics of monsoon driven systems with village-scale socio-economic attributes to evaluate the sustainability of current restoration efforts and to prioritize future areas for intervention. We utilize a multi-dimensional metric that takes into account both physical factors related to water

Airborne EM, Lithology and in-situ Data Used for Quantizing Groundwater Salinity in Zeeland (NL)

Science.gov (United States)

Meyer, U.; Siemon, B.; van Baaren, E.; Dabekaussen, W.; Delsman, J. R.; Karaoulis, M.; Gunnink, J.; Pauw, P.; Vermaas, T.

2017-12-01

In a setting of predominantly saline surface waters in Zeeland, the Netherlands, the only available shallow fresh groundwater is present in the form of freshwater lenses floating on top of the saline groundwater. This fresh water is vital for agricultural, industrial, ecological, water conservation and drinking water functions. An essential first step for managing the usable water properly is to know the present spatial fresh-brackish-saline groundwater distribution. As traditional salinity monitoring is labor-intensive, airborne electromagnetics, which is fast and can cover large areas in short time, is an efficient alternative. A consortium of BGR, Deltares and TNO conducted FRESHEM Zeeland (FREsh Salt groundwater distribution by Helicopter ElectroMagnetic survey in the Province of Zeeland) in 2014-17. An area of more than 2000 square km was surveyed using BGR's helicopter-borne geophysical system totaling to about 9,600 line-km. The HEM data, after inversion to 2.5 Million resistivity-depth models for each of the three 1D inversion procedures applied (Marquardt single site, smooth and sharp laterally constrained inversion), served as base-line information for further interpretation. A probabilistic Monte Carlo approach combines HEM resistivities, 3D lithology model data (GeoTOP), laboratory results (formation factor and surface conductivity) and local in-situ groundwater measurements for the translation of resistivity to Chloride concentration. The resulting 3D voxel model enables stakeholders to implement spatial Chloride concentration in their groundwater models.

Simulating Salt Movement using a Coupled Salinity Transport Model in a Variably Saturated Agricultural Groundwater System

Science.gov (United States)

Tavakoli Kivi, S.; Bailey, R. T.; Gates, T. K.

2017-12-01

Salinization is one of the major concerns in irrigated agricultural fields. Increasing salinity concentrations are due principally to a high water table that results from excessive irrigation, canal seepage, and a lack of efficient drainage systems, and lead to decreasing crop yield. High groundwater salinity loading to nearby river systems also impacts downstream areas, with saline river water diverted for application on irrigated fields. To assess the different strategies for salt remediation, we present a reactive transport model (UZF-RT3D) coupled with a salinity equilibrium chemistry module for simulating the fate and transport of salt ions in a variably-saturated agricultural groundwater system. The developed model accounts not for advection, dispersion, nitrogen and sulfur cycling, oxidation-reduction, sorption, complexation, ion exchange, and precipitation/dissolution of salt minerals. The model is applied to a 500 km2 region within the Lower Arkansas River Valley (LARV) in southeastern Colorado, an area acutely affected by salinization in the past few decades. The model is tested against salt ion concentrations in the saturated zone, total dissolved solid concentrations in the unsaturated zone, and salt groundwater loading to the Arkansas River. The model now can be used to investigate salinity remediation strategies.

Bank storage buffers rivers from saline regional groundwater: an example from the Avon River Australia

Science.gov (United States)

Gilfedder, Benjamin; Hofmann, Harald; Cartwrighta, Ian

2014-05-01

Groundwater-surface water interactions are often conceptually and numerically modeled as a two component system: a groundwater system connected to a stream, river or lake. However, transient storage zones such as hyporheic exchange, bank storage, parafluvial flow and flood plain storage complicate the two component model by delaying the release of flood water from the catchment. Bank storage occurs when high river levels associated with flood water reverses the hydraulic gradient between surface water and groundwater. River water flows into the riparian zone, where it is stored until the flood water recede. The water held in the banks then drains back into the river over time scales ranging from days to months as the hydraulic gradient returns to pre-flood levels. If the frequency and amplitude of flood events is high enough, water held in bank storage can potentially perpetually remain between the regional groundwater system and the river. In this work we focus on the role of bank storage in buffering river salinity levels against saline regional groundwater on lowland sections of the Avon River, Victoria, Australia. We hypothesize that the frequency and magnitude of floods will strongly influence the salinity of the stream water as banks fill and drain. A bore transect (5 bores) was installed perpendicular to the river and were instrumented with head and electrical conductivity loggers measuring for two years. We also installed a continuous 222Rn system in one bore. This data was augmented with long-term monthly EC from the river. During high rainfall events very fresh flood waters from the headwaters infiltrated into the gravel river banks leading to a dilution in EC and 222Rn in the bores. Following the events the fresh water drained back into the river as head gradients reversed. However the bank water salinities remained ~10x lower than regional groundwater levels during most of the time series, and only slightly above river water. During 2012 SE Australia

Minimal groundwater leakage restricts salinity in a hydrologically terminal basin of northwest Australia

Science.gov (United States)

Skrzypek, Grzegorz; Dogramaci, Shawan; Rouillard, Alexandra; Grierson, Pauline

2016-04-01

The Fortescue Marsh (FM) is one of the largest wetlands of arid northwest Australia (~1200 km2) and is thought to act as a terminal basin for the Upper Fortescue River catchment. Unlike the playa lake systems that predominate in most arid regions, where salinity is driven by inflow and evaporation of groundwater, the hydrological regime of the FM is driven by inundation from irregular cyclonic events [1]. Surface water of the FM is fresh to brackish and the salinity of the deepest groundwater (80 m b.g.l.) does not exceed 160 g/L; salt efflorescences are rarely present on the surface [2]. In this study, we tested the hypothesis that persistent but low rates of groundwater outflow have restricted the accumulation of salt in the FM over time. Using hydrological, hydrochemical data and dimensionless time evaporation modelling along with the water and salt budget, we calculated the time and the annual groundwater discharge volume that would be required to achieve and maintain the range of salinity levels observed in the Marsh. Groundwater outflow from alluvial and colluvial aquifers to the Lower Fortescue catchment is limited by an extremely low hydraulic gradient of 0.001 and is restricted to a relatively small 'alluvial window' of 0.35 km2 because of the elevation of the basement bedrock at the Marsh outflow. We show that if the Marsh was 100% "leakage free" i.e., a true terminal basin for the Upper Fortescue Catchment, the basin water would have achieved salt saturation after ~45 ka. This is not the case and only a very small outflow of saline groundwater of water volume) is needed to maintain the current salinity conditions. The minimum time required to develop the current hydrochemical composition of the water in the Marsh and the steady-state conditions for salt concentration is between 58 and 164 ka. This is a minimum age of the Marsh but it can be much older as nearly steady-state conditions could be maintained infinitely. Our approach using a combined water

The Slow Moving Threat of Groundwater Salinization: Mechanisms, Costs, and Adaptation Strategies

Science.gov (United States)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2016-12-01

Population growth, the Green Revolution, and climate uncertainties have accelerated overdraft in groundwater basins worldwide, which in some regions is converting these basins into closed hydrologic systems, where the dominant exits for water are evapotranspiration and pumping. Irrigated agricultural basins are particularly at risk to groundwater salinization, as naturally occurring (i.e., sodium, potassium, chloride) and anthropogenic (i.e., nitrate fertilizers) salts leach back into the water table through the root zone, while a large portion of pumped groundwater leaves the system as it is evapotranspired by crops. Decreasing water quality associated with increases in Total Dissolved Solids (TDS) has been documented in aquifers across the United States in the past half century. This study suggests that the increase in TDS in aquifers can be partially explained by closed basin hydrogeology and rock-water interactions leading to groundwater salinization. This study will present: (1) a report on historical water quality in the Tulare basin, (2) a forward simulation of salt balance in Tulare Basin based on the Department of Water Resources numerical model C2VSim, and a simple mixing model, (3) an economic analysis forecasting the cost of desalination under varying degrees of managed groundwater recharge where the basin is gradually filled, avoiding hydraulic closure.

Distinct kinetics and mechanisms of mZVI particles aging in saline and fresh groundwater: H2 evolution and surface passivation.

Science.gov (United States)

Xin, Jia; Tang, Fenglin; Zheng, Xilai; Shao, Haibing; Kolditz, Olaf; Lu, Xin

2016-09-01

Application of microscale zero-valent iron (mZVI) is a promising technology for in-situ contaminated groundwater remediation; however, its longevity is negatively impacted by surface passivation, especially in saline groundwater. In this study, the aging behavior of mZVI particles was investigated in three media (milli-Q water, fresh groundwater and saline groundwater) using batch experiments to evaluate their potential corrosion and passivation performance under different field conditions. The results indicated that mZVI was reactive for 0-7 days of exposure to water and then gradually lost H2-generating capacity over the next hundred days in all of the tested media. In comparison, mZVI in saline groundwater exhibited the fastest corrosion rate during the early phase (0-7 d), followed by the sharpest kinetic constant decline in the latter phases. The SEM-EDS and XPS analyses demonstrated that in the saline groundwater, a thin and compact oxide film was immediately formed on the surface and significantly shielded the iron reactive site. Nevertheless, in fresh groundwater and milli-Q water, a passive layer composed of loosely and unevenly distributed precipitates slowly formed, with abundant reactive sites available to support continuous iron corrosion. These findings provide insight into the molecular-scale mechanism that governs mZVI passivation and provide implications for long-term mZVI application in saline contaminated groundwater. Copyright © 2016 Elsevier Ltd. All rights reserved.

The Effects of High Salinity Groundwater on the Performance of Clay Barriers

International Nuclear Information System (INIS)

Savage, David

2005-08-01

Potential changes in groundwater chemistry during the operational or post-closure periods of the Swedish repository for spent fuel could affect the performance of both the bentonite buffer and repository backfill. For example, the up-coning of saline groundwater could lead to decreased swelling pressures in both the bentonite buffer and tunnel backfills, and could also induce 'piping'. SKB is considering these issues as part of its 'SR-Can' safety assessment. This report reviews evidence for the behaviour of swelling clays in groundwaters of varying salinity with special relevance to the SKB programme. Smectite clays can absorb water into clay inter-layers with the most important parameters being: the surface density of charge of the clay; the charge and solvation behaviour of the inter-layer ions; and the electrolyte concentration or activity of water. Two categories of swelling are generally observed: innercrystalline swelling caused by the hydration of the exchangeable cations in the dry clay; and osmotic swelling, resulting from concentration gradients in ion concentrations between clay surfaces and pore water. Several models exist to interpret and predict the swelling behaviour of clays. SKB currently prefer an interpretation of clay swelling pressure where clay particles are viewed as 'macro-ions' and the entire clay-water system can be considered as a 'polyelectrolyte'. SKB use the term 'Donnan exclusion' to estimate the amount of introduced ions into the clay and hence the amount of reduced swelling pressure due to contact with a saline solution. Donnan exclusion is the process whereby the migration of anions through the narrow aqueous film surrounding clay platelets is restricted due to the repulsion by the negative charge of the clay platelets. SKB's experimental work shows that: There is an exponential relation between swelling pressure and mean basal interlamellar spacing of the clay. Ions from the external electrolyte solution enter the clay volume

The Effects of High Salinity Groundwater on the Performance of Clay Barriers

Energy Technology Data Exchange (ETDEWEB)

Savage, David [Quintessa Ltd., Nottingham (United Kingdom)

2005-07-01

Potential changes in groundwater chemistry during the operational or post-closure periods of the Swedish repository for spent fuel could affect the performance of both the bentonite buffer and repository backfill. For example, the up-coning of saline groundwater could lead to decreased swelling pressures in both the bentonite buffer and tunnel backfills, and could also induce 'piping'. SKB is considering these issues as part of its 'SR-Can' safety assessment. This report reviews evidence for the behaviour of swelling clays in groundwaters of varying salinity with special relevance to the SKB programme. Smectite clays can absorb water into clay inter-layers with the most important parameters being: the surface density of charge of the clay; the charge and solvation behaviour of the inter-layer ions; and the electrolyte concentration or activity of water. Two categories of swelling are generally observed: innercrystalline swelling caused by the hydration of the exchangeable cations in the dry clay; and osmotic swelling, resulting from concentration gradients in ion concentrations between clay surfaces and pore water. Several models exist to interpret and predict the swelling behaviour of clays. SKB currently prefer an interpretation of clay swelling pressure where clay particles are viewed as 'macro-ions' and the entire clay-water system can be considered as a 'polyelectrolyte'. SKB use the term 'Donnan exclusion' to estimate the amount of introduced ions into the clay and hence the amount of reduced swelling pressure due to contact with a saline solution. Donnan exclusion is the process whereby the migration of anions through the narrow aqueous film surrounding clay platelets is restricted due to the repulsion by the negative charge of the clay platelets. SKB's experimental work shows that: There is an exponential relation between swelling pressure and mean basal interlamellar spacing of the clay. Ions from the

Groundwater Salinity Simulation of a Subsurface Reservoir in Taiwan

Science.gov (United States)

Fang, H. T.

2015-12-01

The subsurface reservoir is located in Chi-Ken Basin, Pescadores (a group islands located at western part of Taiwan). There is no river in these remote islands and thus the freshwater supply is relied on the subsurface reservoir. The basin area of the subsurface reservoir is 2.14 km2 , discharge of groundwater is 1.27×106m3 , annual planning water supplies is 7.9×105m3 , which include for domestic agricultural usage. The annual average temperature is 23.3oC, average moisture is 80~85%, annual average rainfall is 913 mm, but ET rate is 1975mm. As there is no single river in the basin; the major recharge of groundwater is by infiltration. Chi-Ken reservoir is the first subsurface reservoir in Taiwan. Originally, the water quality of the reservoir is good. The reservoir has had the salinity problem since 1991 and it became more and more serious from 1992 until 1994. Possible reason of the salinity problem was the shortage of rainfall or the leakage of the subsurface barrier which caused the seawater intrusion. The present study aimed to determine the leakage position of subsurface barrier that caused the salinity problem. In order to perform the simulation for different possible leakage position of the subsurface reservoir, a Groundwater Modeling System (GMS) is used to define soils layer data, hydro-geological parameters, initial conditions, boundary conditions and the generation of three dimension meshes. A three dimension FEMWATER(Yeh , 1996) numerical model was adopted to find the possible leakage position of the subsurface barrier and location of seawater intrusion by comparing the simulation of different possible leakage with the observations. 1.By assuming the leakage position in the bottom of barrier, the simulated numerical result matched the observation better than the other assumed leakage positions. It showed that the most possible leakage position was at the bottom of the barrier. 2.The research applied three dimension FEMWATER and GMS as an interface

Contributions of groundwater conditions to soil and water salinization

Science.gov (United States)

Salama, Ramsis B.; Otto, Claus J.; Fitzpatrick, Robert W.

Salinization is the process whereby the concentration of dissolved salts in water and soil is increased due to natural or human-induced processes. Water is lost through one or any combination of four main mechanisms: evaporation, evapotranspiration, hydrolysis, and leakage between aquifers. Salinity increases from catchment divides to the valley floors and in the direction of groundwater flow. Salinization is explained by two main chemical models developed by the authors: weathering and deposition. These models are in agreement with the weathering and depositional geological processes that have formed soils and overburden in the catchments. Five soil-change processes in arid and semi-arid climates are associated with waterlogging and water. In all represented cases, groundwater is the main geological agent for transmitting, accumulating, and discharging salt. At a small catchment scale in South and Western Australia, water is lost through evapotranspiration and hydrolysis. Saline groundwater flows along the beds of the streams and is accumulated in paleochannels, which act as a salt repository, and finally discharges in lakes, where most of the saline groundwater is concentrated. In the hummocky terrains of the Northern Great Plains Region, Canada and USA, the localized recharge and discharge scenarios cause salinization to occur mainly in depressions, in conjunction with the formation of saline soils and seepages. On a regional scale within closed basins, this process can create playas or saline lakes. In the continental aquifers of the rift basins of Sudan, salinity increases along the groundwater flow path and forms a saline zone at the distal end. The saline zone in each rift forms a closed ridge, which coincides with the closed trough of the groundwater-level map. The saline body or bodies were formed by evaporation coupled with alkaline-earth carbonate precipitation and dissolution of capillary salts. Résumé La salinisation est le processus par lequel la

Submarine groundwater discharge to a small estuary estimated from radon and salinity measurements and a box model

Directory of Open Access Journals (Sweden)

J. Crusius

2005-01-01

Full Text Available Submarine groundwater discharge was quantified by a variety of methods for a 4-day period during the early summer of 2004, in Salt Pond, adjacent to Nauset Marsh, on Cape Cod, USA. Discharge estimates based on radon and salinity took advantage of the presence of the narrow channel connecting Salt Pond to Nauset Marsh, which allowed constructing whole-pond mass balances as water flowed in and out due to tidal fluctuations. The data suggest that less than one quarter of the discharge in the vicinity of Salt Pond happened within the pond itself, while three quarters or more of the discharge occurred immediately seaward of the pond, either in the channel or in adjacent regions of Nauset Marsh. Much of this discharge, which maintains high radon activities and low salinity, is carried into the pond during each incoming tide. A box model was used as an aid to understand both the rates and the locations of discharge in the vicinity of Salt Pond. The model achieves a reasonable fit to both the salinity and radon data assuming submarine groundwater discharge is fresh and that most of it occurs either in the channel or in adjacent regions of Nauset Marsh. Salinity and radon data, together with seepage meter results, do not rule out discharge of saline groundwater, but suggest either that the saline discharge is at most comparable in volume to the fresh discharge or that it is depleted in radon. The estimated rate of fresh groundwater discharge in the vicinity of Salt Pond is 3000-7000 m3 d-1. This groundwater flux estimated from the radon and salinity data is comparable to a value of 3200-4500 m3 d-1 predicted by a recent hydrologic model (Masterson, 2004; Colman and Masterson, 2004, although the model predicts this rate of discharge to the pond whereas our data suggest most of the groundwater bypasses the pond prior to discharge. Additional work is needed to determine if the measured rate of discharge is representative of the long-term average, and to

The origin of brackish and saline groundwater in the coastal area of the Netherlands

NARCIS (Netherlands)

Post, VEA; Van der Plicht, H; Meijer, HAJ

An explanation is presented for the origin of brackish to saline groundwater in the coastal area of the Netherlands based on geological, chemical (chlorinity), isotopic and geophysical data. A critical review of all possible salinization mechanisms shows that the origin of the brackish water is

Investigating groundwater salinity in the Machile-Zambezi Basin (Zambia) with hydrogeophysical methods

DEFF Research Database (Denmark)

Chongo, Mkhuzo; A. Nyambe, Imasiku; Larsen, Flemming

resources worldwide. This thesis presents the application of geo-electrical and electromagnetic methods for the investigation of groundwater salinity in the Machile-Zambezi Basin in south western Zambia, southern central Africa. Aerial and ground based transient electromagnetic measurenments were used...... use of direct current and transient electromagnetic data in one optimization. The result from the regional mapping with transient electromagnetic measurenments showed a spatial distribution of electrical resistivity that indicated block faulting in the Machile-Zambezi Basin. Saline groundwater...... parameters. This was for a coupled flow and solute transport model setup for the Kasaya transect under the forcing of evapotranspiration. Performance of the coupled hydrogeophysical inversion was better with the inclusion of direct current data in comparison to the use of transient electromagnetic data alone...

Origins and processes of groundwater salinization in the urban coastal aquifers of Recife (Pernambuco, Brazil): A multi-isotope approach

International Nuclear Information System (INIS)

Cary, Lise; Petelet-Giraud, Emmanuelle; Bertrand, Guillaume; Kloppmann, Wolfram; Aquilina, Luc; Martins, Veridiana; Hirata, Ricardo; Montenegro, Suzana; Pauwels, Hélène; Chatton, Eliot; Franzen, Melissa; Aurouet, Axel; Lasseur, Eric; Picot, Géraldine; Guerrot, Catherine; Fléhoc, Christine

2015-01-01

In the coastal multilayer aquifer system of a highly urbanized southern city (Recife, Brazil), where groundwaters are affected by salinization, a multi-isotope approach (Sr, B, O, H) was used to investigate the sources and processes of salinization. The high diversity of the geological bodies, built since the Atlantic opening during the Cretaceous, highly constrains the heterogeneity of the groundwater chemistry, e.g. Sr isotope ratios, and needs to be integrated to explain the salinization processes and groundwater pathways. A paleoseawater intrusion, most probably the 120 ky B.P. Pleistocene marine transgression, and cationic exchange are clearly evidenced in the most salinized parts of the Cabo and Beberibe aquifers. All 87 Sr/ 86 Sr values are above the past and present-day seawater signatures, meaning that the Sr isotopic signature is altered due to additional Sr inputs from dilution with different freshwaters, and water–rock interactions. Only the Cabo aquifer presents a well-delimitated area of Na-HCO 3 water typical of a freshening process. The two deep aquifers also display a broad range of B concentrations and B isotope ratios with values among the highest known to date (63–68.5‰). This suggests multiple sources and processes affecting B behavior, among which mixing with saline water, B sorption on clays and mixing with wastewater. The highly fractionated B isotopic values were explained by infiltration of relatively salty water with B interacting with clays, pointing out the major role played by (palaeo)-channels for the deep Beberibe aquifer recharge. Based on an increase of salinity at the end of the dry season, a present-day seawater intrusion is identified in the surficial Boa Viagem aquifer. Our conceptual model presents a comprehensive understanding of the major groundwater salinization pathways and processes, and should be of benefit for other southern Atlantic coastal aquifers to better address groundwater management issues. - Highlights: �

Characterization of mechanisms and processes of groundwater salinization in irrigated coastal area using statistics, GIS, and hydrogeochemical investigations.

Science.gov (United States)

Bouzourra, Hazar; Bouhlila, Rachida; Elango, L; Slama, Fairouz; Ouslati, Naceur

2015-02-01

Coastal aquifers are at threat of salinization in most parts of the world. This study was carried out in coastal shallow aquifers of Aousja-Ghar El Melh and Kalâat el Andalous, northeastern of Tunisia with an objective to identify sources and processes of groundwater salinization. Groundwater samples were collected from 42 shallow dug wells during July and September 2007. Chemical parameters such as Na(+), Ca(2+), Mg(2+), K(+), Cl(-), SO4 (2-), HCO3 (-), NO3 (-), Br(-), and F(-) were analyzed. The combination of hydrogeochemical, statistical, and GIS approaches was used to understand and to identify the main sources of salinization and contamination of these shallow coastal aquifers as follows: (i) water-rock interaction, (ii) evapotranspiration, (iii) saltwater is started to intrude before 1972 and it is still intruding continuously, (iv) irrigation return flow, (v) sea aerosol spray, and finally, (vi) agricultural fertilizers. During 2005/2006, the overexploitation of the renewable water resources of aquifers caused saline water intrusion. In 2007, the freshening of a brackish-saline groundwater occurred under natural recharge conditions by Ca-HCO3 meteoric freshwater. The cationic exchange processes are occurred at fresh-saline interfaces of mixtures along the hydraulic gradient. The sulfate reduction process and the neo-formation of clays minerals characterize the hypersaline coastal Sebkha environments. Evaporation tends to increase the concentrations of solutes in groundwater from the recharge areas to the discharge areas and leads to precipitate carbonate and sulfate minerals.

Geochemical and isotopic determination of deep groundwater contributions and salinity to the shallow groundwater and surface water systems, Mesilla Basin, New Mexico, Texas, and Mexico

Science.gov (United States)

Robertson, A.; Carroll, K. C.; Kubicki, C.; Purtshert, R.

2017-12-01

The Mesilla Basin/Conejos-Médanos aquifer system, extending from southern New Mexico to Chihuahua, Mexico, is a priority transboundary aquifer under the 2006 United States­-Mexico Transboundary Aquifer Assessment Act. Declining water levels, deteriorating water quality, and increasing groundwater use by municipal, industrial, and agricultural users on both sides of the international border raise concerns about long-term aquifer sustainability. Relative contributions of present-day and "paleo" recharge to sustainable fresh groundwater yields has not been determined and evidence suggests that a large source of salinity at the distal end of the Mesilla Basin is saline discharge from deep groundwater flow. The magnitude and distribution of those deep saline flow paths are not determined. The contribution of deep groundwater to discharge and salinity in the shallow groundwater and surface water of the Mesilla Basin will be determined by collecting discrete groundwater samples and analyzing for aqueous geochemical and isotopic tracers, as well as the radioisotopes of argon and krypton. Analytes include major ions, trace elements, the stable isotopes of water, strontium and boron isotopes, uranium isotopes, the carbon isotopes of dissolved inorganic carbon, noble gas concentrations and helium isotope ratios. Dissolved gases are extracted and captured from groundwater wells using membrane contactors in a process known as ultra-trace sampling. Gas samples are analyzed for radioisotope ratios of krypton by the ATTA method and argon by low-level counting. Effectiveness of the ultra-trace sampling device and method was evaluated by comparing results of tritium concentrations to the krypton-85 content. Good agreement between the analyses, especially in samples with undetectable tritium, indicates that the ultra-trace procedure is effective and confirms that introduction of atmospheric air has not occurred. The geochemistry data indicate a complex system of geochemical

The distribution and origins of extremely acidic saline groundwaters in the south of Western Australia - Groundwater and digital mapping datasets provide new insights

Science.gov (United States)

Lillicrap, Adam M.; Biermann, Vera; George, Richard J.; Gray, David J.; Oldham, Carolyn E.

2018-01-01

Some of the largest extents of naturally occurring acidic waters are found across southern Australia. The origins of these systems remain poorly understood with many hypotheses for their genesis. Australian government agency groundwater datasets and mapping data (vegetation, geology, regolith and soils) for south-western Australia, unavailable to previous researchers, were statistically analysed to better understand the origins of acidic groundwater and guide additional fieldwork to study the origins of acidic saline groundwater. The groundwater data showed a distinct bimodal distribution in pH; the 'acid' population had a median pH of 3.5 and the larger 'non-acid' population had a median pH of 6.6. Acidic groundwater became progressively more common further from the coast towards the drier internally drained regions. Acidic groundwater was mostly confined to the lower slopes and valley floors with localised controls on distribution. Paradoxically, subsoil alkalinity within the internally drained inland regions had the strongest correlation with acidic groundwater (r2 = 0.85). Vegetation was also a strong predictor of acidic groundwater. Acidic groundwater had the highest occurrence under Eucalyptus woodlands and shrublands that grew on alkaline calcareous soils. Pre-clearing soil data in areas with acidic saline groundwater showed that the upper 1 m of the unsaturated zone had a pH around 8 while the pH at depths greater than 5 m decreased to calcium is sourced from the deeper profile where the root biota exchanges calcium for hydrogen ions to maintain charge balance. Iron is mobilised from the upper soil profile and concentrates lower in the profile at depths >1.5 m. There, the iron is reduced around roots and the alkalinity generated by microbial iron reduction is removed by biogenic calcification processes. The iron moves in solution further down the profile following roots where it comes in contact with the oxygenated unsaturated zone matrix and is oxidised

Origins and processes of groundwater salinization in the urban coastal aquifers of Recife (Pernambuco, Brazil): A multi-isotope approach

Energy Technology Data Exchange (ETDEWEB)

Cary, Lise, E-mail: l.cary@brgm.fr [BRGM French Geological Survey, 3 Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Petelet-Giraud, Emmanuelle [BRGM French Geological Survey, 3 Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Bertrand, Guillaume [Institute of Geosciences, University of São Paulo, Rua do Lago, 562 Butantã, 05508-080 Sao Paulo (Brazil); Kloppmann, Wolfram [BRGM French Geological Survey, 3 Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Aquilina, Luc [OSUR-Géosciences Rennes, Université Rennes 1 — CNRS, 35000 Rennes (France); Martins, Veridiana; Hirata, Ricardo [Institute of Geosciences, University of São Paulo, Rua do Lago, 562 Butantã, 05508-080 Sao Paulo (Brazil); Montenegro, Suzana [Civil Engineering Department, Federal University of Pernambuco, 50740 Recife, PE Brazil (Brazil); Pauwels, Hélène [BRGM French Geological Survey, 3 Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); Chatton, Eliot [OSUR-Géosciences Rennes, Université Rennes 1 — CNRS, 35000 Rennes (France); Franzen, Melissa [CPRM, Brazilian Geologic Survey, Avenida Sul 2291, Recife PE (Brazil); Aurouet, Axel [Géo-Hyd, 101 rue Jacques Charles, 45160 Olivet (France); Lasseur, Eric; Picot, Géraldine; Guerrot, Catherine; Fléhoc, Christine [BRGM French Geological Survey, 3 Avenue Claude Guillemin, 45060 Orléans Cedex 2 (France); and others

2015-10-15

In the coastal multilayer aquifer system of a highly urbanized southern city (Recife, Brazil), where groundwaters are affected by salinization, a multi-isotope approach (Sr, B, O, H) was used to investigate the sources and processes of salinization. The high diversity of the geological bodies, built since the Atlantic opening during the Cretaceous, highly constrains the heterogeneity of the groundwater chemistry, e.g. Sr isotope ratios, and needs to be integrated to explain the salinization processes and groundwater pathways. A paleoseawater intrusion, most probably the 120 ky B.P. Pleistocene marine transgression, and cationic exchange are clearly evidenced in the most salinized parts of the Cabo and Beberibe aquifers. All {sup 87}Sr/{sup 86}Sr values are above the past and present-day seawater signatures, meaning that the Sr isotopic signature is altered due to additional Sr inputs from dilution with different freshwaters, and water–rock interactions. Only the Cabo aquifer presents a well-delimitated area of Na-HCO{sub 3} water typical of a freshening process. The two deep aquifers also display a broad range of B concentrations and B isotope ratios with values among the highest known to date (63–68.5‰). This suggests multiple sources and processes affecting B behavior, among which mixing with saline water, B sorption on clays and mixing with wastewater. The highly fractionated B isotopic values were explained by infiltration of relatively salty water with B interacting with clays, pointing out the major role played by (palaeo)-channels for the deep Beberibe aquifer recharge. Based on an increase of salinity at the end of the dry season, a present-day seawater intrusion is identified in the surficial Boa Viagem aquifer. Our conceptual model presents a comprehensive understanding of the major groundwater salinization pathways and processes, and should be of benefit for other southern Atlantic coastal aquifers to better address groundwater management issues

Salinization of the soil solution decreases the further accumulation of salt in the root zone of the halophyte Atriplex nummularia Lindl. growing above shallow saline groundwater.

Science.gov (United States)

Alharby, Hesham F; Colmer, Timothy D; Barrett-Lennard, Edward G

2018-01-01

Water use by plants in landscapes with shallow saline groundwater may lead to the accumulation of salt in the root zone. We examined the accumulation of Na + and Cl - around the roots of the halophyte Atriplex nummularia Lindl. and the impacts of this increasing salinity for stomatal conductance, water use and growth. Plants were grown in columns filled with a sand-clay mixture and connected at the bottom to reservoirs containing 20, 200 or 400 mM NaCl. At 21 d, Na + and Cl - concentrations in the soil solution were affected by the salinity of the groundwater, height above the water table and the root fresh mass density at various soil depths (P soil solution therefore had a feedback effect on further salinization within the root zone. © 2017 John Wiley & Sons Ltd.

Origin and distribution of saline groundwaters in the upper Miocene aquifer system, coastal Rhodope area, northeastern Greece

Science.gov (United States)

Petalas, C. P.; Diamantis, I. B.

1999-06-01

This paper describes the origins and distribution of saline groundwaters in the coastal area of Rhodope, Greece. The aquifer system includes two aquifers within coarse-grained alluvial sediments in the coastal part of the study area. Two major water-quality groups occur in the study area, namely Ca2+-rich saline groundwater and Ca2+-poor, almost fresh groundwater. The main process controlling the groundwater chemistry is the exchange of calcium and sodium between the aquifer matrix and intruding seawater. The natural salt water in the study area is probably residual water that infiltrated the aquifer system during repeated marine transgressions in late Pleistocene time. Seawater intrusion into the coastal aquifer system occurs as a result of overpumping in two seawater wedges separated vertically by a low-permeability layer. The rate of intrusion averages 0.8 m/d and is less than expected due to a decline of the aquifer's permeability at the interface with the seawater. The application of several hydrochemical techniques (Piper and Durov diagrams; Na+/Cl-, Ca2+/Cl-, Mg2+/Cl-, and Br-/Cl- molar ratios; Ca2+/Mg2+ weight ratio; and chloride concentrations), combined with field observations, may lead to a better explanation of the origin of the saline groundwater.

A New Method to Infer Advancement of Saline Front in Coastal Groundwater Systems by 3D: The Case of Bari (Southern Italy Fractured Aquifer

Directory of Open Access Journals (Sweden)

Costantino Masciopinto

2016-02-01

Full Text Available A new method to study 3D saline front advancement in coastal fractured aquifers has been presented. Field groundwater salinity was measured in boreholes of the Bari (Southern Italy coastal aquifer with depth below water table. Then, the Ghyben-Herzberg freshwater/saltwater (50% sharp interface and saline front position were determined by model simulations of the freshwater flow in groundwater. Afterward, the best-fit procedure between groundwater salinity measurements, at assigned water depth of 1.0 m in boreholes, and distances of each borehole from the modelled freshwater/saltwater saline front was used to convert each position (x, y in groundwater to the water salinity concentration at depth of 1.0 m. Moreover, a second best-fit procedure was applied to the salinity measurements in boreholes with depth z. These results provided a grid file (x, y, z, salinity suitable for plotting the actual Bari aquifer salinity by 3D maps. Subsequently, in order to assess effects of pumping on the saltwater-freshwater transition zone in the coastal aquifer, the Navier-Stokes (N-S equations were applied to study transient density-driven flow and salt mass transport into freshwater of a single fracture. The rate of seawater/freshwater interface advancement given by the N-S solution was used to define the progression of saline front in Bari groundwater, starting from the actual salinity 3D map. The impact of pumping of 335 L·s−1 during the transition period of 112.8 days was easily highlighted on 3D salinity maps of Bari aquifer.

Study of groundwater chemistry and salinization in Rechna Doab using hydrochemical and isotopic tools

International Nuclear Information System (INIS)

Sajjad, M.I.; Tasneem, M.A.; Akram, W.; Ahmad, M.; Hussain, S.D.; Khan, I.H.

1991-09-01

Isotopic and chemical characterization of groundwater in Rechna Doab were studied. Samples of water from existing shallow and deep wells, etc. were collected and analyzed for their major ionic and stable isotopic (/sup 2/H, /sup 18/O) contents. The chemical data was used to have a knowledge of various aspects of water chemistry. Different compositional types of water existing in the area were identified. It was observed that groundwater at most of the locations belongs to sodium bicarbonate type. The geochemical evaluation of groundwater was also studied. It is suggested that infiltering water picks up carbon dioxide during percolation through the soil zone. This CO/sub 2/rich water upon interaction with the sediments dissolves more soluble ions. With the increase in salinity soluble remains in solution. Chemical quality of water was evaluated for various uses and found satisfactory in most of the cases. Stable isotopic values in combination with conservative ion (Cl) concentration were used to identify the process of groundwater salinization. Three possible processes, mixing with connate marine water, concentration of salts by evaporation and dissolution of salts from sediments was found to be the operating mechanism under the prevailing conditions. (author)

The integrated impacts of natural processes and human activities on groundwater salinization in the coastal aquifers of Beihai, southern China

Science.gov (United States)

Li, Qinghua; Zhang, Yanpeng; Chen, Wen; Yu, Shaowen

2018-03-01

Salinization in coastal aquifers is usually related to both seawater intrusion and water-rock interaction. The results of chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai, southern China. The concentrations of the major ions that dominate in seawater (Cl-, Na+, Ca2+, Mg2+ and SO4 2- ), as well as the isotopic content and ratios (2H, 18O, 87Sr/86Sr and 13C), suggest that the salinization occurring in the aquifer of the coastal plain is related to seawater and that the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization has occurred in an area that is significantly influenced by land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds are identified in the shallowest confined aquifer (I) in the middle of the area (site BBW2). Leakage from this polluted confined aquifer causes the salinization of groundwater in the underlying confined aquifer (II). At the coastal monitoring site (BBW3), confined aquifer I and lower confined aquifer II are heavily contaminated by seawater intrusion. The weak connectivity between the upper aquifers, and the seaward movement of freshwater, prevents saltwater from encroaching the deepest confined aquifer (III). A conceptual model is presented. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for the planning and sustainable management of groundwater resources in this region.

A geochemical approach to determine sources and movement of saline groundwater in a coastal aquifer.

Science.gov (United States)

Anders, Robert; Mendez, Gregory O; Futa, Kiyoto; Danskin, Wesley R

2014-01-01

Geochemical evaluation of the sources and movement of saline groundwater in coastal aquifers can aid in the initial mapping of the subsurface when geological information is unavailable. Chloride concentrations of groundwater in a coastal aquifer near San Diego, California, range from about 57 to 39,400 mg/L. On the basis of relative proportions of major-ions, the chemical composition is classified as Na-Ca-Cl-SO4, Na-Cl, or Na-Ca-Cl type water. δ(2)H and δ(18)O values range from -47.7‰ to -12.8‰ and from -7.0‰ to -1.2‰, respectively. The isotopically depleted groundwater occurs in the deeper part of the coastal aquifer, and the isotopically enriched groundwater occurs in zones of sea water intrusion. (87)Sr/(86)Sr ratios range from about 0.7050 to 0.7090, and differ between shallower and deeper flow paths in the coastal aquifer. (3)H and (14)C analyses indicate that most of the groundwater was recharged many thousands of years ago. The analysis of multiple chemical and isotopic tracers indicates that the sources and movement of saline groundwater in the San Diego coastal aquifer are dominated by: (1) recharge of local precipitation in relatively shallow parts of the flow system; (2) regional flow of recharge of higher-elevation precipitation along deep flow paths that freshen a previously saline aquifer; and (3) intrusion of sea water that entered the aquifer primarily during premodern times. Two northwest-to-southeast trending sections show the spatial distribution of the different geochemical groups and suggest the subsurface in the coastal aquifer can be separated into two predominant hydrostratigraphic layers. © 2013, National Ground Water Association.

Provision of Desalinated Irrigation Water by the Desalination of Groundwater within a Saline Aquifer

Directory of Open Access Journals (Sweden)

David D. J. Antia

2016-12-01

Full Text Available Irrigated land accounts for 70% of global water usage and 30% of global agricultural production. Forty percent of this water is derived from groundwater. Approximately 20%–30% of the groundwater sources are saline and 20%–50% of global irrigation water is salinized. Salinization reduces crop yields and the number of crop varieties which can be grown on an arable holding. Structured ZVI (zero valent iron, Fe0 pellets desalinate water by storing the removed ions as halite (NaCl within their porosity. This allows an “Aquifer Treatment Zone” to be created within an aquifer, (penetrated by a number of wells (containing ZVI pellets. This zone is used to supply partially desalinated water directly from a saline aquifer. A modeled reconfigured aquifer producing a continuous flow (e.g., 20 m3/day, 7300 m3/a of partially desalinated irrigation water is used to illustrate the impact of porosity, permeability, aquifer heterogeneity, abstraction rate, Aquifer Treatment Zone size, aquifer thickness, optional reinjection, leakage and flow by-pass on the product water salinity. This desalination approach has no operating costs (other than abstraction costs (and ZVI regeneration and may potentially be able to deliver a continuous flow of partially desalinated water (30%–80% NaCl reduction for $0.05–0.5/m3.

Geochemical evolution of groundwater salinity at basin scale: a case study from Datong basin, Northern China.

Science.gov (United States)

Wu, Ya; Wang, Yanxin

2014-05-01

A hydrogeochemical investigation using integrated methods of stable isotopes ((18)O, (2)H), (87)Sr/(86)Sr ratios, Cl/Br ratios, chloride-mass balance, mass balance and hydrogeochemical modeling was conducted to interpret the geochemical evolution of groundwater salinity in Datong basin, northern China. The δ(2)H, δ(18)O ratios in precipitation exhibited a local meteoric water line of δ(2)H = 6.4 δ(18)O -5 (R(2) = 0.94), while those in groundwater suggested their meteoric origin in a historically colder climatic regime with a speculated recharge rate of less than 20.5 mm overall per year, in addition to recharge from a component of deep residual ancient lake water enriched with Br. According to the Sr isotope binary mixing model, the mixing of recharges from the Shentou karst springs (24%), the western margins (11%) and the eastern margins (65%) accounts for the groundwater from the deep aquifers of the down-gradient parts in the central basin is a possible mixing mechanism. In Datong, hydrolysis of silicate minerals is the most important hydrogeochemical process responsible for groundwater chemistry, in addition to dissolution of carbonate and evaporites. In the recharge areas, silicate chemical weathering is typically at the bisiallitization stage, while that in the central basin is mostly at the monosiallitization stage with limited evidence of being in equilibrium with gibbsite. Na exchange with bound Ca, Mg prevails at basin scale, and intensifies with groundwater salinity, while Ca, Mg exchange with bound Na locally occurs in the east pluvial and alluvial plains. Although groundwater salinity increases with the progress of water-rock/sediment interactions along the flow path, as a result of carbonate solubility control and continuous evapotranspiration, Na-HCO3 and Na-Cl-SO4 types of water are usually characterized respectively in the deep and the shallow aquifers of an inland basin with a silicate terrain in an arid climatic regime.

Salinity Impacts on Agriculture and Groundwater in Delta Regions

Science.gov (United States)

Clarke, D.; Salehin, M.; Jairuddin, M.; Saleh, A. F. M.; Rahman, M. M.; Parks, K. E.; Haque, M. A.; Lázár, A. N.; Payo, A.

2015-12-01

Delta regions are attractive for high intensity agriculture due to the availability of rich sedimentary soils and of fresh water. Many of the world's tropical deltas support high population densities which are reliant on irrigated agriculture. However environmental changes such as sea level rise, tidal inundation and reduced river flows have reduced the quantity and quality of water available for successful agriculture. Additionally, anthropogenic influences such as the over abstraction of ground water and the increased use of low quality water from river inlets has resulted in the accumulation of salts in the soils which diminishes crop productivity. Communities based in these regions are usually reliant on the same water for drinking and cooking because surface water is frequently contaminated by commercial and urban pollution. The expansion of shallow tube well systems for drinking water and agricultural use over the last few decades has resulted in mobilisation of salinity in the coastal and estuarine fringes. Sustainable development in delta regions is becoming constrained by water salinity. However salinity is often studied as an independent issue by specialists working in the fields of agriculture, community water supply and groundwater. The lack of interaction between these disciplines often results in corrective actions being applied to one sector without fully assessing the effects of these actions on other sectors. This paper describes a framework for indentifying the causes and impacts of salinity in delta regions based on the source-pathway-receptor framework. It uses examples and scenarios from the Ganges-Brahmaputra-Meghna delta in Bangladesh together with field measurements and observations made in vulnerable coastal communities. The paper demonstrates the importance of creating an holistic understanding of the development and management of water resources to reduce the impact of salinity in fresh water in delta regions.

Assessment of groundwater salinization mechanisms in Santiago Island - Cabo Verde: An environmental isotopic approach

International Nuclear Information System (INIS)

Carreira, P.M.; Nunes, D.; Marques, J.M.; Pina, A.; Mota Gomes, A.; Almeida, E.; Goncalves, R.; Monteiro Santos, F.

2007-01-01

Two sampling campaigns were carried out at Santiago Island - Cabo Verde under the scope of an isotopic and geochemical research study. An evaluation of the groundwater systems was carried out through the application of environmental isotopes and geochemical data in order to answer questions such as: origin and mechanisms of groundwater recharge; relation between the hydrochemical evolution of the groundwater systems with the geological matrix (minerals dissolution) or mixture with seawater and aerosol marine influence; identification of seawater intrusion mechanisms and, determination of the apparent groundwater 'age'. The results obtained so far are not conclusive on the identification of the process responsible for the increase of salinity. In general, all the data obtained seems to indicate that the waters have the same isotopic history but different geochemical evolution, which depends on the weathering and permeability of the rocks. (author)

Assessment of groundwater quality using geographical information system (GIS), at north-east Cairo, Egypt.

Science.gov (United States)

El-Shahat, M F; Sadek, M A; Mostafa, W M; Hagagg, K H

2016-04-01

The present investigation has been conducted to delineate the hydrogeochemical and environmental factors that control the water quality of the groundwater resources in the north-east of Cairo. A complementary approach based on hydrogeochemistry and a geographical information system (GIS) based protectability index has been employed for conducting this work. The results from the chemical analysis revealed that the groundwater of the Quaternary aquifer is less saline than that of the Miocene aquifer and the main factors that control the groundwater salinity in the studied area are primarily related to the genesis of the original recharging water modified after by leaching, dissolution, cation exchange, and fertilizer leachate. The computed groundwater quality index (WQI) falls into two categories: fair for almost all the Miocene groundwater samples, while the Quaternary groundwater samples are all have a good quality. The retarded flow and non-replenishment of the Miocene aquifer compared to the renewable active recharge of the Quaternary aquifer can explain this variation of WQI. The index and overlay approach exemplified by the DUPIT index has been used to investigate the protectability of the study aquifers against diffuse pollutants. Three categories (highly protectable less vulnerable, moderately protectable moderately vulnerable and less protectable highly vulnerable) have been determined and areally mapped.

The integrated impacts of natural processes and human activities on the origin and processes of groundwater salinization in the coastal aquifers of Beihai, Southern China

Science.gov (United States)

Li, Q.; Zhan, Y., , Dr; Chen, W. Ms; Yu, S., , Dr

2017-12-01

Salinization in coastal aquifers usually is the results of contamination related to both seawater intrusion and water-rock interaction. The chemical and isotopic methods were combined to identify the origin and processes of groundwater salinization in Daguansha area of Beihai. The concentrations of the major ions that dominate in sea water (Cl-, Na+, Ca2+, Mg2+ and SO2- 4), as well as the isotopic ratios (2H, 18O, 87Sr/86Sr and 13C) suggest that the salinization occurring in the aquifer water of the coastal plain is related to seawater and the prevailing hydrochemical processes are evaporation, mixing, dissolution and ion exchange. For the unconfined aquifer, groundwater salinization occurred in parts of the area, which is significantly influenced by the land-based sea farming. The integrated impacts of seawater intrusion from the Beibuwan Gulf and infiltration of seawater from the culture ponds is identified in the confined aquifer I at site BBW2. In consequence, the leakage from this polluted aquifer causes the salinization of groundwater in the confined aquifer II. At site BBW3, the confined aquifer I and lower confined aquifer II are remarkably contaminated by seawater intrusion. The weak connectivity with upper aquifers and seaward movement of freshwater prevents saltwater from encroaching the confined aquifer III. Above all, understanding of the origin and processes of groundwater salinization will provide essential information for sustainable planning and management of groundwater resources in this region.

Implications of deep drainage through saline clay for groundwater recharge and sustainable cropping in a semi-arid catchment, Australia

Science.gov (United States)

Timms, W. A.; Young, R. R.; Huth, N.

2012-04-01

The magnitude and timing of deep drainage and salt leaching through clay soils is a critical issue for dryland agriculture in semi-arid regions (2000 mm yr-1) such as parts of Australia's Murray-Darling Basin (MDB). In this rare study, hydrogeological measurements and estimations of the historic water balance of crops grown on overlying Grey Vertosols were combined to estimate the contribution of deep drainage below crop roots to recharge and salinization of shallow groundwater. Soil sampling at two sites on the alluvial flood plain of the Lower Namoi catchment revealed significant peaks in chloride concentrations at 0.8-1.2 m depth under perennial vegetation and at 2.0-2.5 m depth under continuous cropping indicating deep drainage and salt leaching since conversion to cropping. Total salt loads of 91-229 t ha-1 NaCl equivalent were measured for perennial vegetation and cropping, with salinity to ≥ 10 m depth that was not detected by shallow soil surveys. Groundwater salinity varied spatially from 910 to 2430 mS m-1 at 21 to 37 m depth (N = 5), whereas deeper groundwater was less saline (290 mS m-1) with use restricted to livestock and rural domestic supplies in this area. The Agricultural Production Systems Simulator (APSIM) software package predicted deep drainage of 3.3-9.5 mm yr-1 (0.7-2.1% rainfall) based on site records of grain yields, rainfall, salt leaching and soil properties. Predicted deep drainage was highly episodic, dependent on rainfall and antecedent soil water content, and over a 39 yr period was restricted mainly to the record wet winter of 1998. During the study period, groundwater levels were unresponsive to major rainfall events (70 and 190 mm total), and most piezometers at about 18 m depth remained dry. In this area, at this time, recharge appears to be negligible due to low rainfall and large potential evapotranspiration, transient hydrological conditions after changes in land use and a thick clay dominated vadose zone. This is in

Satellite data analysis for identification of groundwater salinization effects on coastal forest for monitoring purposes

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M. Barbarella

2015-05-01

Full Text Available In the phreatic aquifer below the San Vitale pinewood (Ravenna, Italy, natural and anthropogenic land subsidence, the low topography and the artificial drainage system have led to widespread saltwater intrusion. Since changes in the groundwater concentration induce variations in the vegetation properties, recognizable by different spectral bands, a comparison between satellite images, ASTER and Worldview-2, was made using the NDVI. The aim was to identify the portions of pinewood affected by salinization through a procedure that could reduce the expensive and time consuming ground monitoring campaigns. Moreover, the Worldview-2 high resolutions were used to investigate the Thermophilic Deciduous Forest (TDF spectral behaviour without the influence of the allochthonous Pinus pinea species that is scattered throughout the pinewood. The NDVI, calculated with traditional bands, identified the same stressed areas using both satellite data. Instead, the new Red-Edge band of the Worldview-2 image allowed a greater correlation between NDVI and groundwater salinity.

Physical hydrogeology and environmental isotopes to constrain the age, origins, and stability of a low-salinity groundwater lens formed by periodic river recharge: Murray Basin, Australia

Science.gov (United States)

Cartwright, Ian; Weaver, Tamie R.; Simmons, Craig T.; Fifield, L. Keith; Lawrence, Charles R.; Chisari, Robert; Varley, Simon

2010-01-01

SummaryA low-salinity (total dissolved solids, TDS, Australia. Hydraulic heads, surface water elevations, δ 18O values, major ion geochemistry, 14C activities, and 3H concentrations show that the lens is recharged from the Murray River largely through the riverbank with limited recharge through the floodplain. Recharge of the lens occurs mainly at high river levels and the low-salinity groundwater forms baseflow to some river reaches during times of low river levels. Within the lens, flow through the shallow Channel Sands and deeper Parilla Sands aquifers is sub-horizontal. While the Blanchetown Clay locally separates the Channel Sands and the Parilla Sands, the occurrence of recently recharged low-salinity groundwater below the Blanchetown Clay suggests that there is considerable leakage through this unit, implying that it is not an efficient aquitard. The lateral margin of the lens with the regional groundwater (TDS >25,000 mg/L) is marked by a hectometer to kilometer scale transition in TDS concentrations that is not stratigraphically controlled. Rather this boundary represents a mixing zone with the regional groundwater, the position of which is controlled by the rate of recharge from the river. The lens is part of an active and dynamic hydrogeological system that responds over years to decades to changes in river levels. The lens has shrunk during the drought of the late 1990s to the mid 2000s, and it will continue to shrink unless regular high flows in the Murray River are re-established. Over longer timescales, the rise of the regional water table due to land clearing will increase the hydraulic gradient between the regional groundwater and the groundwater in the lens, which will also cause it to degrade. Replacement of low-salinity groundwater in the lens with saline groundwater will ultimately increase the salinity of the Murray River reducing its utility for water supply and impacting riverine ecosystems.

Strontium isotopes as an indicator for groundwater salinity sources in the Kirkuk region, Iraq

Energy Technology Data Exchange (ETDEWEB)

Sahib, Layth Y. [Institute for Applied Geosciences, Technische Universität Darmstadt, Schnittspahnstraße 9, 64287 Darmstadt (Germany); Geology Department, College of Science, University of Baghdad, Jadreya, Baghdad (Iraq); Marandi, Andres; Schüth, Christoph [Institute for Applied Geosciences, Technische Universität Darmstadt, Schnittspahnstraße 9, 64287 Darmstadt (Germany)

2016-08-15

The Kirkuk region in northern Iraq hosts some of the largest oil fields in the Middle East. Several anticline structures enabled vertical migration and entrapment of the oil. Frequently, complex fracture systems and faults cut across the Eocene and middle Oligocene reservoirs and the cap rock, the Fatha Formation of Miocene age. Seepage of crude oil and oil field brines are therefore a common observation in the anticline axes and contamination of shallow groundwater resources is a major concern. In this study, 65 water samples were collected in the Kirkuk region to analyze and distinguish mixing processes between shallow groundwater resources, uprising oil field brines, and dissolution of gypsum and halite from the Fatha Formation. Hydrochemical analyses of the water samples included general hydrochemistry, stable water isotopes, as well as strontium concentrations and for 22 of the samples strontium isotopes ({sup 87}Sr/{sup 86}Sr). Strontium concentrations increased close to the anticline axes with highest concentrations in the oil field brines (300 mg/l). Strontium isotopes proved to be a valuable tool to distinguish mixing processes as isotope signatures of the oil field brines and of waters from the Fatha Formation are significantly different. It could be shown, that mixing of shallow groundwater with oil field brines is occurring close to the major fault zones in the anticlines but high concentrations of strontium in the water samples are mainly due to dissolution from the Fatha Formation. - Highlights: • This field study evaluates the salinity sources in the groundwater in Kirkuk region. • Salinity is related to evaporates dissolving and/or mixing with oil field brine. • Strontium isotopes proved to be a valuable tool to distinguish mixing processes.

A GIS cost model to assess the availability of freshwater, seawater, and saline groundwater for algal biofuel production in the United States.

Science.gov (United States)

Venteris, Erik R; Skaggs, Richard L; Coleman, Andre M; Wigmosta, Mark S

2013-05-07

A key advantage of using microalgae for biofuel production is the ability of some algal strains to thrive in waters unsuitable for conventional crop irrigation such as saline groundwater or seawater. Nonetheless, the availability of sustainable water supplies will provide significant challenges for scale-up and development of algal biofuels. We conduct a partial techno-economic assessment based on the availability of freshwater, saline groundwater, and seawater for use in open pond algae cultivation systems. We explore water issues through GIS-based models of algae biofuel production, freshwater supply (constrained to less than 5% of mean annual flow per watershed) and costs, and cost-distance models for supplying seawater and saline groundwater. We estimate that, combined, these resources can support 9.46 × 10(7) m(3) yr(-1) (25 billion gallons yr(-1)) of renewable biodiesel production in the coterminous United States. Achievement of larger targets requires the utilization of less water efficient sites and relatively expensive saline waters. Despite the addition of freshwater supply constraints and saline water resources, the geographic conclusions are similar to our previous results. Freshwater availability and saline water delivery costs are most favorable for the coast of the Gulf of Mexico and Florida peninsula, where evaporation relative to precipitation is moderate. As a whole, the barren and scrub lands of the southwestern U.S. have limited freshwater supplies, and large net evaporation rates greatly increase the cost of saline alternatives due to the added makeup water required to maintain pond salinity. However, this and similar analyses are particularly sensitive to knowledge gaps in algae growth/lipid production performance and the proportion of freshwater resources available, key topics for future investigation.

Geochemical tracing and hydrogeochemical modelling of water-rock interactions during salinization of alluvial groundwater (Upper Rhine Valley, France)

Energy Technology Data Exchange (ETDEWEB)

Lucas, Y., E-mail: yann.lucas@eost.u-strasbg.fr [Universite de Strasbourg et CNRS, Laboratoire d' Hydrologie et de Geochimie de Strasbourg, Ecole et Observatoire des Sciences de la Terre, 1, rue Blessig, 67084 Strasbourg Cedex (France); Schmitt, A.D., E-mail: anne-desiree.schmitt@univ-fcomte.fr [Universite de Strasbourg et CNRS, Laboratoire d' Hydrologie et de Geochimie de Strasbourg, Ecole et Observatoire des Sciences de la Terre, 1, rue Blessig, 67084 Strasbourg Cedex (France)] [Universite de Franche-Comte et CNRS-UMR 6249, Chrono-Environnement, 16, Route de Gray, 25030 Besancon Cedex (France); Chabaux, F., E-mail: francois.chabaux@eost.u-strasbg.fr [Universite de Strasbourg et CNRS, Laboratoire d' Hydrologie et de Geochimie de Strasbourg, Ecole et Observatoire des Sciences de la Terre, 1, rue Blessig, 67084 Strasbourg Cedex (France); Clement, A.; Fritz, B. [Universite de Strasbourg et CNRS, Laboratoire d' Hydrologie et de Geochimie de Strasbourg, Ecole et Observatoire des Sciences de la Terre, 1, rue Blessig, 67084 Strasbourg Cedex (France); Elsass, Ph. [BRGM, GEODERIS, 1, rue Claude Chappe, 57070 Metz (France); Durand, S. [Universite de Strasbourg et CNRS, Laboratoire d' Hydrologie et de Geochimie de Strasbourg, Ecole et Observatoire des Sciences de la Terre, 1, rue Blessig, 67084 Strasbourg Cedex (France)

2010-11-15

Research highlights: {yields} Major and trace elements along with strontium and uranium isotopic ratios show that groundwater geochemical characteristics along the saline plumes cannot reflect a conservative mixing. {yields} A coupled hydrogeochemical model demonstrates that cationic exchange between alkalis from polluted waters and alkaline-earth elements from montmorillonite present in the host rock of the aquifer is the primary process. {yields} The model requires only a small amount of montmorillonite. {yields} It is necessary to consider the pollution history to explain the important chloride, sodium and calcium concentration modifications. {yields} The model shows that the rapidity of the cationic exchange reactions insures a reversibility of the cation fixation on clays in the aquifer. - Abstract: In the southern Upper Rhine Valley, groundwater has undergone intensive saline pollution caused by the infiltration of mining brines, a consequence of potash extraction carried out during the 20th century. Major and trace elements along with Sr and U isotopic ratios show that groundwater geochemical characteristics along the saline plumes cannot reflect conservative mixing between saline waters resulting from the dissolution of waste heaps and one or more unpolluted end-members. The results imply the occurrence of interactions between host rocks and polluted waters, and they suggest that cationic exchange mechanisms are the primary controlling process. A coupled hydrogeochemical model has been developed with the numerical code KIRMAT, which demonstrates that cationic exchange between alkalis from polluted waters and alkaline-earth elements from montmorillonite present in the host rock of the aquifer is the primary process controlling the geochemical evolution of the groundwater. The model requires only a small amount of montmorillonite (between 0.75% and 2.25%), which is in agreement with the observed mineralogical composition of the aquifer. The model also proves

Implications of deep drainage through saline clay for groundwater recharge and sustainable cropping in a semi-arid catchment, Australia

Directory of Open Access Journals (Sweden)

W. A. Timms

2012-04-01

Full Text Available The magnitude and timing of deep drainage and salt leaching through clay soils is a critical issue for dryland agriculture in semi-arid regions (<500 mm yr⁻¹ rainfall, potential evapotranspiration >2000 mm yr⁻¹ such as parts of Australia's Murray-Darling Basin (MDB. In this rare study, hydrogeological measurements and estimations of the historic water balance of crops grown on overlying Grey Vertosols were combined to estimate the contribution of deep drainage below crop roots to recharge and salinization of shallow groundwater. Soil sampling at two sites on the alluvial flood plain of the Lower Namoi catchment revealed significant peaks in chloride concentrations at 0.8–1.2 m depth under perennial vegetation and at 2.0–2.5 m depth under continuous cropping indicating deep drainage and salt leaching since conversion to cropping. Total salt loads of 91–229 t ha⁻¹ NaCl equivalent were measured for perennial vegetation and cropping, with salinity to ≥ 10 m depth that was not detected by shallow soil surveys. Groundwater salinity varied spatially from 910 to 2430 mS m⁻¹ at 21 to 37 m depth (N = 5, whereas deeper groundwater was less saline (290 mS m⁻¹ with use restricted to livestock and rural domestic supplies in this area. The Agricultural Production Systems Simulator (APSIM software package predicted deep drainage of 3.3–9.5 mm yr⁻¹ (0.7–2.1% rainfall based on site records of grain yields, rainfall, salt leaching and soil properties. Predicted deep drainage was highly episodic, dependent on rainfall and antecedent soil water content, and over a 39 yr period was restricted mainly to the record wet winter of 1998. During the study period, groundwater levels were unresponsive to major rainfall events (70 and 190 mm total, and most piezometers at about 18 m depth remained dry. In this area, at this time, recharge appears to be negligible due to low

Monitoring soil coverage and yield of cowpea furrow irrigated with saline water

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Antonia Leila Rocha Neves

Full Text Available Abstract Cowpea crop is of great importance for northeast Brazil. The objective of this work was to evaluate the application of saline water in different developing stages on plant growth and changes in soil characteristics, measured by soil coverage, and on yield of cowpea plants. The experiment was conducted under field conditions, during the dry season in a completely randomized block design with five treatments and five replications. Each experimental unit consisted of 4 lines of plants with 5.0 m long. The treatments evaluated were: 1. irrigation with groundwater with electrical conductivity (ECw of 0.8 dS m-1 during the whole crop cycle; 2. saline water (5.0 dS m-1 during the whole crop cycle; 3, 4 and 5. saline water (5.0 dS m-1 up to 22nd, during 23rd to 42nd and from the 43rd to 62nd days after sowing, respectively, and groundwater in the remaining period. Soil coverage was evaluated by digital images using the software ENVI for image processing and classification. It was found that the continuous use of saline water inhibits plant growth, while irrigation with saline water during germination and initial growth stages caused retardation in plant development, but in this last case a recovery was observed in the final part of the experimental period. For treatments 2 and 3, a reduction was verified in the number of pods and in seed production, as compared to other treatments. Irrigation with saline water during 23 to 42 and 43 to 62 days after sowing did not affect reproductive and vegetative growth, but the saline water application in the pre-flowering (treatment 4 caused anticipation of the reproductive cycle.

Response to recharge variation of thin rainwater lenses and their mixing zone with underlying saline groundwater

Directory of Open Access Journals (Sweden)

S. Eeman

2012-10-01

Full Text Available In coastal zones with saline groundwater, fresh groundwater lenses may form due to infiltration of rain water. The thickness of both the lens and the mixing zone, determines fresh water availability for plant growth. Due to recharge variation, the thickness of the lens and the mixing zone are not constant, which may adversely affect agricultural and natural vegetation if saline water reaches the root zone during the growing season. In this paper, we study the response of thin lenses and their mixing zone to variation of recharge. The recharge is varied using sinusoids with a range of amplitudes and frequencies. We vary lens characteristics by varying the Rayleigh number and Mass flux ratio of saline and fresh water, as these dominantly influence the thickness of thin lenses and their mixing zone. Numerical results show a linear relation between the normalised lens volume and the main lens and recharge characteristics, enabling an empirical approximation of the variation of lens thickness. Increase of the recharge amplitude causes increase and the increase of recharge frequency causes a decrease in the variation of lens thickness. The average lens thickness is not significantly influenced by these variations in recharge, contrary to the mixing zone thickness. The mixing zone thickness is compared to that of a Fickian mixing regime. A simple relation between the travelled distance of the centre of the mixing zone position due to variations in recharge and the mixing zone thickness is shown to be valid for both a sinusoidal recharge variation and actual records of daily recharge data. Starting from a step response function, convolution can be used to determine the effect of variable recharge in time. For a sinusoidal curve, we can determine delay of lens movement compared to the recharge curve as well as the lens amplitude, derived from the convolution integral. Together the proposed equations provide us with a first order approximation of lens

Long-term changes in pond permanence, size, and salinity in Prairie Pothole Region wetlands: The role of groundwater-pond interaction

Science.gov (United States)

LaBaugh, James W.; Rosenberry, Donald O.; Mushet, David M.; Neff, Brian; Nelson, Richard D.; Euliss, Ned H.

2018-01-01

Study RegionCottonwood Lake area wetlands, North Dakota, U.S.A.Study FocusFluctuations in pond permanence, size, and salinity are key features of prairie-pothole wetlands that provide a variety of wetland habitats for waterfowl in the northern prairie of North America. Observation of water-level and salinity fluctuations in a semi-permanent wetland pond over a 20-year period, included periods when the wetland occasionally was dry, as well as wetter years when the pond depth and surface extent doubled while volume increased 10 times.New hydrological insights for the study regionCompared to all other measured budget components, groundwater flow into the pond often contributed the least water (8–28 percent) but the largest amount (>90 percent) of specific solutes to the water and solute budgets of the pond. In drier years flow from the pond into groundwater represented > 10 percent of water loss, and in 1992 was approximately equal to evapotranspiration loss. Also during the drier years, export of calcium, magnesium, sodium, potassium, chloride, and sulfate by flow from the pond to groundwater was substantial compared with previous or subsequent years, a process that would have been undetected if groundwater flux had been calculated as a net value. Independent quantification of water and solute gains and losses were essential to understand controls on water-level and salinity fluctuations in the pond in response to variable climate conditions.

Investigation on the Sources of Recharge and Salinity in Deep Groundwater System Underlying a Coastal City of Bangladesh by Combined Geochemical and Isotopic Approaches

Science.gov (United States)

Rahman, M.; Tokunaga, T.

2017-12-01

The Khulna city, situated in the southwestern coastal Bangladesh, has been abstracting deep groundwater (DGW, >150 m below ground level, bgl) since 1970s due to the prevalence of salinity, iron, and arsenic in shallow groundwater (SGW, groundwater management and ensuring long-term freshwater supply for the Khulna city, Bangladesh.

An integrated hydrogeochemical and isotopic approach to study groundwater Salinization in the overexploited aquifers of Indo-Gangetic Plain, a part of NCR Delhi

Science.gov (United States)

Kumari, R.

2017-12-01

roundwater resources in arid and semi-arid areas are highly vulnerable to salinity problems. Inadequate availability of surface water supply, vagaries of mansoonal rainfall and overexploitation due to population pressure and rapid landuse change induced decline in groundwater levels and salinization has been observed in many Asian cities. After green revolution, large part of Indo-Gangetic plain groundwater salinization has been reported. One such region is National Capital Region, Delhi- India's largest and the world's second largest agglomeration of people and economic hub of Northern India. The present study includes National capital territory, Delhi, Gurgaon and Faridabad. In the present study, different graphical plots, Piper plot, saturation index values (using PHREEQC), stable isotopes (δ18O and δD) and GIS is used to create the database for analysis of spatial variation in respective water quality parameters as well as to decipher the hydrogeochemical process occurring in the area. Major ions are analysed to describe the composition and distribution of salinization and dissolution/precipitation dynamics. It was observed that groundwater weathering is governed by carbonate and silicate weathering and reverse ion-exchange, however due to semi-arid climate evaporation is also playing a major role in groundwater chemistry and salinity of the area. δ18O and δD regression line of groundwater samples of the study area is below the LMWL also suggest from non-equilibrium fractionation during evaporation. Large lateral variation in chloride concentration indicates impact of evapotranspiration rate during recharge. Most of water facies are of Na-Cl. Stable isotope (δ18O and δD) analysis helps to identify evaporation and to better understand recharge processes and mixing dynamics in the study region. Limited availability of surface water supply, no pricing exists for groundwater extraction has resulted in a widespread decline in the water table and intermixing of

Numerical Study of Groundwater Flow and Salinity Distribution Cycling Controlled by Seawater/Freshwater Interaction in Karst Aquifer Using SEAWAT

Science.gov (United States)

Xu, Z.; Hu, B.

2017-12-01

The interest to predict seawater intrusion and salinity distribution in Woodville Karst Plain (WKP) has increased due to the huge challenge on quality of drinkable water and serious environmental problems. Seawater intrudes into the conduit system from submarine karst caves at Spring Creek Spring due to density difference and sea level rising, nowadays the low salinity has been detected at Wakulla Spring which is 18 km from coastal line. The groundwater discharge at two major springs and salinity distribution in this area is controlled by the seawater/freshwater interaction under different rainfall conditions: during low rainfall periods, seawater flow into the submarine spring through karst windows, then the salinity rising at the submarine spring leads to seawater further intrudes into conduit system; during high rainfall periods, seawater is pushed out by fresh water discharge at submarine spring. The previous numerical studies of WKP mainly focused on the density independent transport modeling and seawater/freshwater discharge at major karst springs, in this study, a SEAWAT model has been developed to fully investigate the salinity distribution in the WKP under repeating phases of low rainfall and high rainfall periods, the conduit system was simulated as porous media with high conductivity and porosity. The precipitation, salinity and discharge at springs were used to calibrate the model. The results showed that the salinity distribution in porous media and conduit system is controlled by the rainfall change, in general, the salinity distribution inland under low rainfall conditions is much higher and wider than the high rainfall conditions. The results propose a prediction on the environmental problem caused by seawater intrusion in karst coastal aquifer, in addition, provide a visual and scientific basis for future groundwater remediation.

Investigating the salinization and freshening processes of coastal groundwater resources in Urmia aquifer, NW Iran.

Science.gov (United States)

Amiri, Vahab; Nakhaei, Mohammad; Lak, Razyeh; Kholghi, Majid

2016-04-01

This paper presents the results of an assessment about interaction between Urmia Lake (UL) and coastal groundwater in the Urmia aquifer (UA). This aquifer is the most significant contributor to the freshwater supply of the coastal areas. The use of hydrochemical facies can be very useful to identify the saltwater encroachment or freshening phases in the coastal aquifers. In this study, the analysis of salinization/freshening processes was carried out through the saturation index (SI), ionic deltas (Δ), binary diagrams, and hydrochemical facies evolution (HFE) diagram. Based on the Gibbs plot, the behavior of the major ions showed that the changes in the chemical composition of the groundwater are mainly controlled by the water-soil/rock interaction zone and few samples are relatively controlled by evaporation. A possible explanation for this phenomenon is that the deposited chloride and sulfate particles can form the minor salinity source in some coastal areas when washed down by precipitation. The SI calculations showed that all groundwater samples, collected in these periods, show negative saturation indices, which indicate undersaturation with respect to anhydrite, gypsum, and halite. In addition, except in a few cases, all other samples showed the undersaturation with respect to the carbonate minerals such as aragonite, calcite, and dolomite. Therefore, these minerals are susceptible to dissolution. In the dry season, the SI calculations showed more positive values with respect to dolomite, especially in the northern part of UA, which indicated a higher potential for precipitation and deposition of dolomite. The percentage of saltwater in the groundwater samples of Urmia plain was very low, ranging between 0.001 and 0.79 % in the wet season and 0.0004 and 0.81 % in the dry season. The results of HFE diagram, which was taken to find whether the aquifer was in the saltwater encroachment phase or in the freshening phase, indicated that except for a few wells

Resistivity-Chemistry Integrated Approaches for Investigating Groundwater Salinity of Water Supply and Agricultural Activity at Island Coastal Area

Science.gov (United States)

Baharuddin, M. F. T.; Masirin, M. I. M.; Hazreek, Z. A. M.; Azman, M. A. A.; Madun, A.

2018-04-01

Groundwater suitability for water supply and agriculture in an island coastal area may easily be influenced by seawater intrusion. The aim of this study was to investigate seawater intrusion to the suitability of the groundwater for water supply and oil palm cultivation on Carey Island in Malaysia. This is the first study that used integrated method of geo-electrical resistivity and hydrogeochemical methods to investigate seawater intrusion to the suitability of groundwater for water supply and oil palm cultivation at two different surface elevation and land cover. The relationship between earth resistivity, total dissolved solids and earth conductivity was derived with water type classifications and crop suitability classification according to salinity, used to identify water types and also oil palm tolerance to salinity. Results from the contour resistivity and conductivity maps showed that the area facing severe coastal erosion (east area) exhibited unsuitable groundwater condition for water supply and oil palm at the unconfined aquifer thickness of 7.8 m and 14.1 m, respectively. Comparing to the area that are still intact with mangrove (west area), at the same depth, groundwater condition exhibits suitable usage for both socioeconomic activities. Different characteristics of surface elevation and land cover are paramount factors influencing saltwater distribution at the west and east area. By the end of the twenty-first century there will no longer be suitable water for supply and oil palm plantation based on the local sea-level rise prediction and Ghyben–Herzberg assumption (sharp interface), focusing on the severe erosion area of the study site.

Numerical assessment of the origin of deep salinity in a low permeability fractured medium

International Nuclear Information System (INIS)

Guimera, Jordi; Ruiz, Eduardo; Luna, Miguel; Arcos, David; Domenech, Cristina; Jordana, Salvador; Saegusa, Hiromitsu; Iwatsuki, Teruki

2007-01-01

Many possible origins have been proposed for the saline groundwater observed in many deep geological environments. In particular, samples obtained from deep boreholes located in granite at the Mizunami Underground Research Laboratory in Central Japan show total dissolved solids increasing to 50 mmol/L at depths below 800 m. Different hypothesis have been formulated to explain the observed fluid composition, among them, long-term water-rock interaction, mixing with residual fluids of magmatic origin and relict seawater dating from Miocene times. A review of the hydrochemical and isotopic data suggests that the three above hypotheses may be valid, at least to different degrees, or that processes acting over more recent geological times may be involved. The origin of the salinity was assessed by simulating land emersion by means of changing the upper recharge boundary. In this manner the Miocene seawater was modeled as being continually mixed with fresh water until the present time. The effects of different retardation processes were considered by varying factors such as matrix diffusion and fracture conductivity. Finally, geochemical reactions reproduced trends in major ions and master variables. This study shows that the salinity observed in the boreholes can be explained qualitatively as residual Miocene age seawater subjected to alteration due to long-term contact with the host material and continuous mixing with meteoric groundwater. (authors)

Sulfur isotopic study of sulfate in the aquifer of Costa de Hermosillo (Sonora, Mexico) in relation to upward intrusion of saline groundwater, irrigation pumping and land cultivation

International Nuclear Information System (INIS)

Szynkiewicz, Anna; Medina, Miguel Rangel; Modelska, Magdalena; Monreal, Rogelio; Pratt, Lisa M.

2008-01-01

Groundwater from the Costa de Hermosillo aquifer has been used extensively for irrigation over the past 60 a in the Sonora region of northwestern Mexico resulting in salinization of fresh groundwater resources. Salinization of groundwater is most pronounced on the western/coastal side of the aquifer, with an aerial extent of 26.7 km 2 , where maximum values are reported for conductivity (31 mS/cm) and Cl - concentrations (16,271 mg/L). Salinization is likely to increase if groundwater pumping continues at levels comparable to the present time. Upward incursion of marine water into the aquifer is inferred from δ 2 H (-7.2 per mille ) and δ 18 O (+1.6 per mille ) compositions of groundwater samples with the highest conductivity. Compared to modern seawater in the Gulf of California, ratios of SO 4 /Cl and Cl/Br are small (0.01 and 33, respectively) and the S isotopic composition of SO 4 2- is high (+32.7%) in the most saline portions of the Costa de Hermosillo. This saline groundwater is inferred to result from an earlier phase of dissimilatory bacterial SO 4 2- reduction coupled to decomposition of organic matter in marine blue clays deposited during the Miocene/Pliocene transgression. The isotopic composition of present-day surface discharge from agricultural fields is substantially enriched in 32 S due to widespread application of (NH 4 ) 2 SO 4 fertilizers and potential mobilization of S from mineral resources. Surface water discharging from irrigated fields has δ 34 S values ranging from -2.1 to 3.3 per mille which are distinctly different from groundwater and surface water in adjacent non-agricultural areas with δ 34 S values ranging from 5.2 to 13.5 per mille . Prolonged irrigation pumping that promotes the incursion of air to the subsurface could enhance the weathering of S-bearing minerals such as magmatic sulfides, producing 32 S-enriched SO 4 2-

Baseline Geochemistry of Natural Occurring Methane and Saline Groundwater in an Area of Unconventional Shale Gas Development Through Time

Science.gov (United States)

Harkness, J.; Darrah, T.; Warner, N. R.; Whyte, C. J.; Moore, M. T.; Millot, R.; Kloppmann, W.; Jackson, R. B.; Vengosh, A.

2017-12-01

Naturally occurring methane is nearly ubiquitous in most sedimentary basins and delineating the effects of anthropogenic contamination sources from geogenic sources is a major challenge for evaluating the impact of unconventional shale gas development on water quality. This study employs a broadly integrated study of various geochemical techniques to investigate the geochemical variations of groundwater and surface water before, during, and after hydraulic fracturing.This approache combines inorganic geochemistry (major cations and anions), stable isotopes of select inorganic constituents including strontium (87Sr/86Sr), boron (δ11B), lithium (δ7Li), and carbon (δ13C-DIC), select hydrocarbon molecular (methane, ethane, propane, butane, and pentane) and isotopic tracers (δ13C-CH4, δ13C-C2H6), tritium (3H), and noble gas elemental and isotopic composition (He, Ne, Ar) to apportion natural and anthropogenic sources of natural gas and salt contaminants both before and after drilling. Methane above 1 ccSTP/L in groundwater samples awas strongly associated with elevated salinity (chloride >50 mg/L).The geochemical and isotopic analysis indicate saline groundwater originated via naturally occurring processes, presumably from the migration of deeper methane-rich brines that have interacted extensively with coal lithologies. The chemistry and gas compostion of both saline and fresh groundwater wells did not change following the installation of nearby shale-gas wells.The results of this study emphasize the value of baseline characterization of water quality in areas of fossil fuel exploration. Overall this study presents a comprehensive geochemical framework that can be used as a template for assessing the sources of elevated hydrocarbons and salts to water resources in areas potentially impacted by oil and gas development.

Environmental isotope studies related to groundwater flow and saline encroachment in the chalk aquifer of Lincolnshire, England

International Nuclear Information System (INIS)

Lloyd, J.W.; Howard, K.W.F.

1978-01-01

The isotopes of tritium and carbon are used to study part of the North Lincolnshire Chalk aquifer in England. The tritium data support the view that the aquifer is a thin fissure system and indicate that some changes in flow direction have occurred due to recent abstraction. The data are also consistent with other chemical data in elucidating groundwater entering the Chalk from deeper aquifers. Carbon isotopes are used to distinguish between saline water bodies and suggest that saline water was entrapped within the aquifer in the Eemian and Flandrian stages of the Pleistocene. (orig.) [de

Using geochemical investigations for determining the interaction between groundwater and saline water in arid areas: case of the Wadi Ouazzi basin (Morocco

Directory of Open Access Journals (Sweden)

R. El Moukhayar

2015-04-01

Full Text Available The characteristics of the Essaouira basin water resources are a semi-arid climate, which is severely impacted by the climate (quantity and quality. Considering the importance of the Essaouira aquifer in the groundwater supply of the region, a study was conducted in order to understand groundwater evolution in this aquifer. The Essaouira aquifer is a coastal aquifer located on the Atlantic coastline of southern Morocco, corresponding to a sedimentary basin with an area of nearly 200 km2. The control of the fluid exchange and the influence of mixing zones between the groundwater and saline water was investigated by sampling from 20 wells, drillings and sources belonging to the Plio-Quaternary and Turonian aquifers. It is hypothesized that groundwater major ions chemistry can be employed to determine the interaction between the groundwater and saline water (coastal aquifers. Groundwater samples examined for electric conductivity and temperature showed that waters belonging to the Plio-Quaternary and Turonian aquifers present very variable electric conductivities, from 900 μs/cm to 3880 μs/cm. Despite this variability, they are from the same family and are characterized by sodium-chloride facies. However, a good correlation exists between the electrical conductivity and chloride and sodium contents. The lower electrical conductivities are situated in the North quarter immediately to the south of the Wadi Ouazzi.

Thin-Film Composite Pressure Retarded Osmosis Membranes for Sustainable Power Generation from Salinity Gradients

KAUST Repository

Yip, Ngai Yin

2011-05-15

Pressure retarded osmosis has the potential to produce renewable energy from natural salinity gradients. This work presents the fabrication of thin-film composite membranes customized for high performance in pressure retarded osmosis. We also present the development of a theoretical model to predict the water flux in pressure retarded osmosis, from which we can predict the power density that can be achieved by a membrane. The model is the first to incorporate external concentration polarization, a performance limiting phenomenon that becomes significant for high-performance membranes. The fabricated membranes consist of a selective polyamide layer formed by interfacial polymerization on top of a polysulfone support layer made by phase separation. The highly porous support layer (structural parameter S = 349 μm), which minimizes internal concentration polarization, allows the transport properties of the active layer to be customized to enhance PRO performance. It is shown that a hand-cast membrane that balances permeability and selectivity (A = 5.81 L m-2 h-1 bar-1, B = 0.88 L m-2 h-1) is projected to achieve the highest potential peak power density of 10.0 W/m2 for a river water feed solution and seawater draw solution. The outstanding performance of this membrane is attributed to the high water permeability of the active layer, coupled with a moderate salt permeability and the ability of the support layer to suppress the undesirable accumulation of leaked salt in the porous support. Membranes with greater selectivity (i.e., lower salt permeability, B = 0.16 L m-2 h-1) suffered from a lower water permeability (A = 1.74 L m-2 h-1 bar-1) and would yield a lower peak power density of 6.1 W/m2, while membranes with a higher permeability and lower selectivity (A = 7.55 L m-2 h-1 bar-1, B = 5.45 L m-2 h-1) performed poorly due to severe reverse salt permeation, resulting in a similar projected peak power density of 6.1 W/m2. © 2011 American Chemical Society.

Environmental isotope study related to groundwater age, flow system and saline water origin in Quaternary aquifers of North China Plain

International Nuclear Information System (INIS)

Zhang Zhigan; Payne, B.R.

1988-01-01

An isotopic hydrology section across the North China Plain has been studied to investigate problems of groundwater age, flow system and saline water origin in a semi-arid pre-mountain artesian basin. Two local and one regional flow system along the section have been recognized. Turnover time of water for alluvial fan, shallow and regional systems are estimated to be the order of 10 2 , 10 3 , and 10 4 years respectively. Specific flow rates for the three systems have been calculated. Only less than 5 percent of flow from alluvial fan is drained by the regional flow system and the rest, in natural conditions, discharges at surface in the front edge of an alluvial fan and forms a groundwater discharge belt at a good distance away from the mountain foot. Developed in the alluvial plain and coastal plain areas the shallow flow system embraces a series of small local systems. Groundwater in these systems appears to be the salt carrier during continental salinization. It washes salt out of the recharge area and deep-occurred strata by circulating and carries it up to the surface in lowland areas. Consequently, in parallel with salinization at surface a desalinization process occurs at depth, which provides an additional explanation for the existing thick deep fresh water zone in most arid and semi-arid regions, where continental salting process is in progress. (author). 6 refs, 8 figs, 4 tabs

Fully integrated physically-based numerical modelling of impacts of groundwater extraction on surface and irrigation-induced groundwater interactions: case study Lower River Murray, Australia

Science.gov (United States)

Alaghmand, S.; Beecham, S.; Hassanli, A.

2013-07-01

Combination of reduction in the frequency, duration and magnitude of natural floods, rising saline water-table in floodplains and excessive evapotranspiration have led to an irrigation-induced groundwater mound forced the naturally saline groundwater onto the floodplain in the Lower River Murray. It is during the attenuation phase of floods that these large salt accumulations are likely to be mobilised and will discharge into the river. The Independent Audit Group for Salinity highlighted this as the most significant risk in the Murray-Darling Basin. South Australian government and catchment management authorities have developed salt interception schemes (SIS). This is to pump the highly saline groundwater from the floodplain aquifer to evaporation basins in order to reduce the hydraulic gradient that drives the regional saline groundwater towards the River Murray. This paper investigates the interactions between a river (River Murray in South Australia) and a saline semi-arid floodplain (Clarks Floodplain) significantly influenced by groundwater lowering (Bookpurnong SIS). Results confirm that groundwater extraction maintain a lower water-table and more fresh river water flux to the saline floodplain aquifer. In term of salinity, this may lead to less amount of solute stored in the floodplain aquifer. This occurs through two mechanisms; extracting some of the solute mass from the system and changing the floodplain groundwater regime from a losing to gaining one. Finally, it is shown that groundwater extraction is able to remove some amount of solute stored in the unsaturated zone and mitigate the floodplain salinity risk.

Features of acid-saline systems of Southern Australia

International Nuclear Information System (INIS)

Dickson, Bruce L.; Giblin, Angela M.

2009-01-01

The discovery of layered, SO 4 -rich sediments on the Meridiani Planum on Mars has focused attention on understanding the formation of acid-saline lakes. Many salt lakes have formed in southern Australia where regional groundwaters are characterized by acidity and high salinity and show features that might be expected in the Meridiani sediments. Many (but not all) of the acid-saline Australian groundwaters are found where underlying Tertiary sediments are sulfide-rich. When waters from the formations come to the surface or interact with oxidised meteoric water, acid groundwaters result. In this paper examples of such waters around Lake Tyrrell, Victoria, and Lake Dey-Dey, South Australia, are reviewed. The acid-saline groundwaters typically have dissolved solids of 30-60 g/L and pH commonly 4 and MgSO 4 ) or differential separation of elements with differing solubility (K, Na, Ti, Cr). Thus, it is considered unlikely that groundwaters or evaporative salt-lake systems, as found on earth, were involved. Instead, these features point to a water-poor system with local alteration and very little mobilization of elements

Rainwater lens dynamics and mixing between infiltrating rainwater and upward saline groundwater seepage beneath a tile-drained agricultural field

NARCIS (Netherlands)

Louw, de P.G.B.; Eeman, S.; Oude Essink, G.H.P.; Vermue, E.; Post, V.E.A.

2013-01-01

Thin rainwater lenses (RW-lenses) near the land surface are often the only source of freshwater in agricultural areas with regionally-extensive brackish to saline groundwater. The seasonal and inter-annual dynamics of these lenses are poorly known. Here this knowledge gap is addressed by

Quantifying anthropogenic contributions to century-scale groundwater salinity changes, San Joaquin Valley, California, USA

Science.gov (United States)

Hansen, Jeffrey; Jurgens, Bryant; Fram, Miranda S.

2018-01-01

Total dissolved solids (TDS) concentrations in groundwater tapped for beneficial uses (drinking water, irrigation, freshwater industrial) have increased on average by about 100 mg/L over the last 100 years in the San Joaquin Valley, California (SJV). During this period land use in the SJV changed from natural vegetation and dryland agriculture to dominantly irrigated agriculture with growing urban areas. Century-scale salinity trends were evaluated by comparing TDS concentrations and major ion compositions of groundwater from wells sampled in 1910 (Historic) to data from wells sampled in 1993-2015 (Modern). TDS concentrations in subregions of the SJV, the southern (SSJV), western (WSJV), northeastern (NESJV), and southeastern (SESJV) were calculated using a cell-declustering method. TDS concentrations increased in all regions, with the greatest increases found in the SSJV and SESJV. Evaluation of the Modern data from the NESJV and SESJV found higher TDS concentrations in recently recharged (post-1950) groundwater from shallow (soil amendments combined. Bicarbonate showed the greatest increase among major ions, resulting from enhanced silicate weathering due to recharge of irrigation water enriched in CO2 during the growing season. The results of this study demonstrate that large anthropogenic changes to the hydrologic regime, like massive development of irrigated agriculture in semi-arid areas like the SJV, can cause large changes in groundwater quality on a regional scale.

Validation on groundwater flow model including sea level change. Modeling on groundwater flow in coastal granite area

International Nuclear Information System (INIS)

Hasegawa, Takuma; Miyakawa, Kimio

2009-01-01

It is important to verify the groundwater flow model that reproduces pressure head, water chemistry, and groundwater age. However, water chemistry and groundwater age are considered to be influenced by historical events. In this study, sea level change during glacial-interglacial cycle was taken into account for simulating salinity and groundwater age at coastal granite area. As a result of simulation, salinity movement could not catch up with sea level changes, and mixing zone was formed below the fresh-water zone. This mixing zone was observed in the field measurement, and the observed salinities were agreed with simulated results including sea level change. The simulated residence time including sea level change is one-tenth of steady state. The reason is that the saline water was washed out during regression and modern sea-water was infiltrated during transgression. As mentioned before, considering sea level change are important to reproduce salinity and helium age at coastal area. (author)

Impact of groundwater levels on evaporation and water-vapor fluxes in highly saline soils

Science.gov (United States)

Munoz, J. F.; Hernández, M. F.; Braud, I.; Gironas, J. A.; Suarez, F. I.

2012-12-01

In aquifers of arid and hyper-arid zones, such as those occurring in the Chilean Andes high plateau, it is important to determine both the quantity and location of water discharges at the temporal scales of interest to close the basin's water budget and thus, to manage the water resource properly. In zones where shallow aquifers are the main source of water, overexploitation of the water resource changes the dynamics of water, heat and solute transport in the vadose zone. As aquifers are exploited, fluctuations in depth to groundwater are exacerbated. These fluctuations modify both soil structure and evaporation from the ground, which is typically the most important discharge from the water budget and is very difficult to estimate. Therefore, a correct quantification of evaporation from these soils is essential to improve the accuracy of the water balance estimation. The objective of this study was to investigate the evaporation processes and water-vapor fluxes in a soil column filled with a saline soil from the Salar del Huasco basin, Chile. Water content, electrical conductivity and temperature at different depths in the soil profile were monitored to determine the liquid and vapor fluxes within the soil column. The results showed that evaporation is negligible when the groundwater table is deeper than 1 m. For shallower groundwater levels, evaporation increases in an exponential fashion reaching a value of 3 mm/day when the groundwater table is near the surface of the ground. These evaporation rates are on the same order of magnitude than the field measurements, but slightly lower due to the controlled conditions maintained in the laboratory. Isothermal fluid fluxes were predominant over the non-isothermal fluid and water vapor fluxes. The net flux for all the phreatic levels tested in the laboratory showed different behaviors, with ascending or descending flows as a consequence of changes in water content and temperature distribution within the soil. It was

Geochemical behavior of Cs, Sr, Tc, Np, and U in saline groundwaters: Sorption experiments on shales and their clay mineral components: Progress report

International Nuclear Information System (INIS)

Meyer, R.E.; Arnold, W.D.; Ho, P.C.; Case, F.I.; O'Kelley, G.D.

1987-11-01

The Sedimentary Rock Program at the Oak Ridge National Laboratory is investigating shale to determine its potential suitability as a host rock for the disposal of high-level radioactive wastes (HLW). In support of this program, preliminary studies were carried out on sorption of cesium, strontium, technetium, neptunium, and uranium onto Chattanooga (Upper Dowelltown), Pierre, Green River Formation, Nolichucky, and Pumpkin Valley Shales under oxic conditions (air present). Three simulated groundwaters were used. One of the groundwaters was a synthetic brine made up to simulate highly saline groundwaters in the Pumpkin Valley Shale. The second was a 100/1 dilution of this groundwater and the third was 0.03 M NaHCO 3 . Moderate to significant sorption was observed under most conditions for all of the tested radionuclides except technetium. Moderate technetium sorption occurred on Upper Dowelltown Shale, and although technetium sorption was low on the other shales, it was higher than expected for Tc(VII), present as the anion TcO 4 - . Little sorption of strontium onto the shales was observed from the concentrated saline groundwater. These data can be used in a generic fashion to help assess the sorption characteristics of shales in support of a national survey. 10 refs., 4 figs., 23 tabs

Modelling the salinization of a coastal lagoon-aquifer system

Science.gov (United States)

Colombani, N.; Mastrocicco, M.

2017-08-01

In this study, a coastal area constituted by alternations of saline-brackish lagoons and freshwater bodies was studied and modelled to understand the hydrological processes occurring between the lagoons, the groundwater system of the Po River Delta (Italy) and the Adriatic Sea. The contribution of both evaporation and anthropogenic factors on groundwater salinization was assessed by means of soil, groundwater and surface water monitoring. Highresolution multi-level samplers were used to capture salinity gradients within the aquifer and surface water bodies. Data were employed to calibrate a density-dependent numerical transport model implemented with SEAWAT code along a transect perpendicular to the coast line. The results show that the lagoon is hydraulically well connected with the aquifer, which provides the major source of salinity because of the upcoming of paleo-seawater from the aquitard laying at the base of the unconfined aquifer. On the contrary, the seawater (diluted by the freshwater river outflow) creates only a limited saltwater wedge. The increase in groundwater salinity could be of serious concern, especially for the pinewood located in the dune near the coast, sensitive to salinity increases. This case study represents an interesting paradigm for other similar environmental setting, where the assumption of classical aquifer salinization from a saltwater wedge intruding from the sea is often not representative of the actual aquifer’s salinization mechanisms.

Coastal groundwater salinization: Focus on the vertical variability in a multi-layered aquifer through a multi-isotope fingerprinting (Roussillon Basin, France)

Energy Technology Data Exchange (ETDEWEB)

Petelet-Giraud, Emmanuelle, E-mail: e.petelet@brgm.fr [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France); Négrel, Philippe [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France); Aunay, Bertrand [BRGM, Réunion Agency, 5, rue Sainte-Anne, CS 51016, 97404 Saint Denis Cedex (France); Ladouche, Bernard; Bailly-Comte, Vincent [BRGM Montpellier Agency, 1039, rue de Pinville, 34000 Montpellier (France); Guerrot, Catherine; Flehoc, Christine [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France); Pezard, Philippe; Lofi, Johanna [Géosciences Montpellier, UMR 5243, Université de Montpellier, cc069, Place Eugène Bataillon, 34095 Montpellier Cedex 05 (France); Dörfliger, Nathalie [BRGM, Avenue C. Guillemin, BP 36009, 45060 Orléans Cedex 02 (France)

2016-10-01

The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place. The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000 μS·cm{sup −1}. The δ{sup 2}H–δ{sup 18}O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using {sup 3}H, {sup 14}C and CFCs/SF6. S(SO{sub 4}) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers {sup 87}Sr/{sup 86}Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120 m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation. Finally, combining the results of this study and those of Caballero and Ladouche (2015

Investigation of pressure retarded osmosis power production

Directory of Open Access Journals (Sweden)

Taousanidis Nikolaos

2017-01-01

Full Text Available A major source of energy exists where there is mixing between aqueous solutions of different salinities. This energy source is particularly concentrated where fresh water rivers flow on to the ocean. The power, represented by the osmotic pressure difference between fresh water and salt water, may be called salinity gradient power. In this study the pressure retarded osmosis method for the extraction of salinity gradients’ energy is investigated, main problems and difficulties are pointed out and finally the whole subject is justified with experimental results.

Modeling Effects of Groundwater Basin Closure, and Reversal of Closure, on Groundwater Quality

Science.gov (United States)

Pauloo, R.; Guo, Z.; Fogg, G. E.

2017-12-01

Population growth, the expansion of agriculture, and climate uncertainties have accelerated groundwater pumping and overdraft in aquifers worldwide. In many agricultural basins, a water budget may be stable or not in overdraft, yet disconnected ground and surface water bodies can contribute to the formation of a "closed" basin, where water principally exits the basin as evapotranspiration. Although decreasing water quality associated with increases in Total Dissolved Solids (TDS) have been documented in aquifers across the United States in the past half century, connections between water quality declines and significant changes in hydrologic budgets leading to closed basin formation remain poorly understood. Preliminary results from an analysis with a regional-scale mixing model of the Tulare Lake Basin in California indicate that groundwater salinization resulting from open to closed basin conversion can operate on a decades-to-century long time scale. The only way to reverse groundwater salinization caused by basin closure is to refill the basin and change the hydrologic budget sufficiently for natural groundwater discharge to resume. 3D flow and transport modeling, including the effects of heterogeneity based on a hydrostratigraphic facies model, is used to explore rates and time scales of groundwater salinization and its reversal under different water and land management scenarios. The modeling is also used to ascertain the extent to which local and regional heterogeneity need to be included in order to appropriately upscale the advection-dispersion equation in a basin scale groundwater quality management model. Results imply that persistent managed aquifer recharge may slow groundwater salinization, and complete reversal may be possible at sufficiently high water tables.

Salinization and Saline Environments

Science.gov (United States)

Vengosh, A.

2003-12-01

One of the most conspicuous phenomena of water-quality degradation, particularly in arid and semi-arid zones, is salinization of water and soil resources. Salinization is a long-term phenomenon, and during the last century many aquifers and river basins have become unsuitable for human consumption owing to high levels of salinity. Future exploitation of thousands of wells in the Middle East and in many other water-scarce regions in the world depends, to a large extent, on the degree and rate of salinization. Moreover, every year a large fraction of agricultural land is salinized and becomes unusable.Salinization is a global environmental phenomenon that affects many different aspects of our life (Williams, 2001a, b): changing the chemical composition of natural water resources (lakes, rivers, and groundwater), degrading the quality of water supply to the domestic and agriculture sectors, contribution to loss of biodiversity, taxonomic replacement by halotolerant species ( Williams, 2001a, b), loss of fertile soil, collapse of agricultural and fishery industries, changing of local climatic conditions, and creating severe health problems (e.g., the Aral Basin). The damage due to salinity in the Colorado River Basin alone, for example, ranges between 500 and 750 million per year and could exceed 1 billion per year if the salinity in the Imperial Dam increases from 700 mg L-1 to 900 mg L-1 (Bureau of Reclamation, 2003, USA). In Australia, accelerating soil salinization has become a massive environmental and economic disaster. Western Australia is "losing an area equal to one football oval an hour" due to spreading salinity ( Murphy, 1999). The annual cost for dryland salinity in Australia is estimated as AU700 million for lost land and AU$130 million for lost production ( Williams et al., 2002). In short, the salinization process has become pervasive.Salinity in water is usually defined by the chloride content (mg L-1) or total dissolved solids content (TDS, mg L-1or g

Long-term changes in pond permanence, size, and salinity in Prairie Pothole Region wetlands: The role of groundwater-pond interaction

Directory of Open Access Journals (Sweden)

James W. LaBaugh

2018-06-01

New hydrological insights for the study region: Compared to all other measured budget components, groundwater flow into the pond often contributed the least water (8–28 percent but the largest amount (>90 percent of specific solutes to the water and solute budgets of the pond. In drier years flow from the pond into groundwater represented > 10 percent of water loss, and in 1992 was approximately equal to evapotranspiration loss. Also during the drier years, export of calcium, magnesium, sodium, potassium, chloride, and sulfate by flow from the pond to groundwater was substantial compared with previous or subsequent years, a process that would have been undetected if groundwater flux had been calculated as a net value. Independent quantification of water and solute gains and losses were essential to understand controls on water-level and salinity fluctuations in the pond in response to variable climate conditions.

Hydrogeochemistry of deep groundwaters in the central part of the Fennoscandian Shields

International Nuclear Information System (INIS)

Blomqvist, R.

1999-01-01

Saline groundwaters are frequent in the central part of the Fennoscandian Shield. The results indicate large variations in groundwater chemistry and in the spatial distribution of saline groundwaters. The depths of the fresh/saline groundwater boundaries vary considerably but generally the boundary is located at 300-600 m. In some cases fresh bicarbonate groundwaters are encountered throughout the drill hole. More commonly, however, bicarbonate waters occur only as an upper layer, up to a few hundred metres in extent, overlying chloride waters of varying salinity. In coastal areas saline groundwaters are frequently found much closer to ground surface. Long-term water-rock interaction and incursions of present/ancient sea water are considered the main processes affecting the evolution of the saline groundwater bodies, while isolation from the surface-close hydrological cycle seems to be a prerequisite for the preservation of these waters. Ancient preferential leaching of low-Rb/Sr minerals (most likely plagioclase) and/or fluid inclusions are the main contribution for dissolved solids in water-rock interaction. The strontium isotope results imply that saline groundwaters in crystalline rocks do not evolve as isolated small pockets with a restricted volume of rock but may constitute more open systems in which lateral hydrogeochemical interaction extends over distances of at least hundreds of metres. One potential mechanism for formation of young calcites is related to glacial rebound where release of stress and increase in temperature in fractures make the groundwaters oversaturated with respect to calcite. Δ 18 depleted groundwaters have been observed from several sampling sites in Finland, indicative of glacial meltwater intrusion in the bedrock. As saline waters have been documented to have long residence times and are not associated with active meteoric water circulation, bedrock suites hosted by saline groundwaters could be considered as potential repository

A regional analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1997-05-01

A regional groundwater model of the Aespoe area has been formulated and applied. The model is three-dimensional, based on a grid of 100x100x36 cells and covers an area of 10x10 km 2 and a depth of 3 km. Equations are solved for the Darcy velocities and the salinity distribution, gravitational effects are thus fully accounted for. The model is used to simulate the general hydrology of the area as well as the influence of the Aespoe Hard Rock Laboratory (HRL). A specific task of the study is to evaluate relevant boundary conditions for the site-model and to show how these are influenced by Aespoe HRL. Studies of the stochastic conductivity field and the effect of density stratification are also reported. The general conclusion of the study is that the model provides a realistic and consistent picture of the area studied. Main arguments for this statement are: The formulation of the model is based on relevant conservation laws and embodies all physical processes believed to be important for the problem considered. The importance of gravitational forces is emphasised. A high resolution grid, which resolves topographical features and at the same time can simulate the effect of the HRL is used. Transmissivities and conductivities used in the model are based on field data. The model has been calibrated, using measured groundwater levels and salinity distributions with good results. A range of sensitivity studies has been carried out. These demonstrate that the model responds to variations in input data, for example the conductivity field in a realistic way. The model can thus be used to generate boundary conditions for a site scale model. The basic objective, to account for the regional influence in a site model, can hence be achieved. 7 refs, 32 figs

Application of isotope techniques to investigate groundwater pollution in India

International Nuclear Information System (INIS)

Shivanna, K.; Navada, S.V.; Kulkarni, K.M.; Sinha, U.K.; Sharma, S.

1998-01-01

Environmental isotopes ( 2 H, 18 O, 34 S, 3 H, and 14 C) techniques have been used along with hydrogeology and hydrochemistry to investigate: (a). the source of salinity and origin of sulphate in groundwaters of coastal Orissa, Orissa State, India and (b) to study the source of salinity in deep saline groundwaters of charnockite terrain at Kokkilimedu, South of Chennai, India. In the first case, as a part of large drinking water supply project, thousands of hand pumps were installed from 1985. Many of them became quickly unacceptable for potable supply due to salinity, increased iron and sulphate contents of the groundwater. In this alluvial, multiaquifer system, fresh, brackish and saline groundwaters occur in a rather complicated fashion. The conditions change from phreatic to confined flowing type with increasing depth. The results of the isotope geochemical investigation indicate that the shallow groundwater (depth/<50m) is fresh and modern. Groundwater salinity in intermediate aquifer (50 - 100m) is due to the Flandrian transgression during Holocene period. Fresh and modern deep groundwater forms a well developed aquifer which receives recharge through weathered basement rock. The saline groundwater found below the fresh deep aquifer have marine water entrapped during late Pleistocene. The source of high sulphate in the groundwater is of marine origin. In the second case, under the host rock characterization programme, the charnockite rock formation at Kokkilimedu, Kalpakkam was evaluated to assess its suitability as host medium for location of a geological repository for high level radioactive waste. Four deep boreholes were drilled in this area, the depth varying from 200 to 618 m. In these boreholes, large variations in groundwater salinity were observed over a distance of only a few hundred meters and no regional pattern could be identified. The results of the isotope investigation show that there are two different sources of salinity in this area. Among

Sorption of caesium and strontium onto calcium silicate hydrate in saline groundwater

International Nuclear Information System (INIS)

Sugiyama, D.; Fujita, T.

2005-01-01

Full text of publication follows: In the concept for radioactive waste disposal in Japan, cement is a potential waste packaging and backfilling material and is expected to provide chemical containment. The sorption of radionuclides onto cement materials, which controls the aqueous concentrations of elements in the pore-water, is a very important parameter when considering the release of radionuclides from the near field of a cementitious radioactive waste repository. Many safety assessment calculations currently assume radionuclide retardation as linear sorption equilibrium and describe it with a distribution ratio (R d value). In this study, the sorption mechanism is discussed by measuring the sorption isotherm of caesium, strontium (10 -5 ∼ 10 -2 mol dm -3 ) and sodium (10 -4 ∼ 10 -1 mol dm -3 ) onto Calcium Silicate Hydrate (C-S-H gel, Ca/Si 0.65 ∼ 1.2) at a liquid:solid ratio of 100:1, to support the assumption. In addition, the competitive sorption between caesium or strontium, and sodium is studied by sorption measurements using a range of sodium chloride concentration to simulate different ionic strengths in saline groundwater. The initial and equilibrated aqueous compositions were measured in the sorption experiments and it was found that caesium, strontium and sodium were sorbed by substitution for Ca in C-S-H phases by examining the mass balance. Based on the experimental results, we propose a modelling approach in which the ion-exchange model is employed and the presence of some calcium sites with different ion-exchange log K values in C-S-H is assumed by considering the composition and the structure of C-S-H. The modelling calculation results predict the measured Rd values well and also describe the competition of sorption of caesium or strontium, and sodium in the experiments. The log K values for sorption of each cation element decreased as Ca/Si ratio of C-S-H gel increased. This agrees with the trend that C-S-H gel is negatively charged at low

On the Sources of Salinity in Groundwater under Plain Areas. Insights from {delta}{sup 18}O, {delta}{sup 2}H and Hydrochemistry in the Azul River Basin, Argentina

Energy Technology Data Exchange (ETDEWEB)

Zabala, M. E.; Varni, M.; Weinzettel, P. [Instituto de Hidrologia de llanuras, Azul (Argentina); Manzano, M. [Technical University of Cartagena (Spain)

2013-07-15

The Azul River basin, with some 6200 km{sup 2}, is located in the plains of Buenos Aires Province, Argentina. The Azul River flows along 160 km from the Tandilia Range, in the SW, to the Channel 11, in the NE. Average annual precipitation is 1005 mm (1988-2000); mean reference evapotranspiration is 1090 mm. The geology consists of Miocene to recent sediments, mostly sands and silts with some clay and calcrete layers, overlying crystalline rocks and marine sediments. The water table is shallow and groundwater in the aquifer upper 30 m displays an increasing salinity from SW to NE. The previous hypothesis to explain the salinity was infiltration of evapo-concentrated surface water, as the small soil slope in the northern basin (< 0.2%) induces rainfall accumulation in lowlands, where water evaporates prior to infiltration. But recent chemical and isotopic data reveal two salinity sources: evaporation of recent recharge water, and mixing with old saline groundwater of yet unknown origin. (author)

Complex relationship between groundwater velocity and concentration of radioactive contaminants

International Nuclear Information System (INIS)

Kaszeta, F.E.; Bond, F.W.

1980-01-01

This paper uses the results from the Multi-component Mass Transport model to examine the complex interrelationship between groundwater velocity and contaminant dispersion, decay, and retardation with regard to their influence on the contaminant concentration distribution as it travels through the geosphere to the biosphere. The rate of transport of contaminants through the geosphere is governed by groundwater velocity, leach rate, and contaminant retardation. The dominant characteristics of the contaminant concentration distribution are inherited during leaching and modified during transport by dilution, dispersion and decay. For a hypothetical non-decaying, non-dispersing contaminant with no retardation properties, the shape of the source term distribution is governed by the groundwater velocity (dilution) and leach rate. This distribution remains unchanged throughout transport. Under actual conditions, however, dispersion, decay and retardation modify the concentration distribution during both leaching and transport. The amount of dispersion is determined by the distance traveled, but it does have a greater peak-reducing influence on spiked distributions than square-shaped distributions. Decay acts as an overall scaling factor on the concentration distribution. Retardation alters the contaminant travel time and therefore indirectly influences the amount of dilution, dispersion and decay. Simple relationships between individual parameters and groundwater velocity as they influence peak concentration do not exist. For those cases where the source term is not solubility-limited and flow past the waste is independent of regional hydrologic conditions, a threshold concentration occurs at a specific groundwater velocity where the effects of dilution balance those of dispersion and decay

Modelling saline intrusion for repository performance assessment

International Nuclear Information System (INIS)

Jackson, C.P.

1989-04-01

UK Nirex Ltd are currently considering the possibility of disposal of radioactive waste by burial in deep underground repositories. The natural pathway for radionuclides from such a repository to return to Man's immediate environment (the biosphere) is via groundwater. Thus analyses of the groundwater flow in the neighbourhood of a possible repository, and consequent radionuclide transport form an important part of a performance assessment for a repository. Some of the areas in the UK that might be considered as possible locations for a repository are near the coast. If a repository is located in a coastal region seawater may intrude into the groundwater flow system. As seawater is denser than fresh water buoyancy forces acting on the intruding saline water may have significant effects on the groundwater flow system, and consequently on the time for radionuclides to return to the biosphere. Further, the chemistry of the repository near-field may be strongly influenced by the salinity of the groundwater. It is therefore important for Nirex to have a capability for reliably modelling saline intrusion to an appropriate degree of accuracy in order to make performance assessments for a repository in a coastal region. This report describes work undertaken in the Nirex Research programme to provide such a capability. (author)

Simulation of Groundwater-Level and Salinity Changes in the Eastern Shore, Virginia

Science.gov (United States)

Sanford, Ward E.; Pope, Jason P.; Nelms, David L.

2009-01-01

Groundwater-level and salinity changes have been simulated with a groundwater model developed and calibrated for the Eastern Shore of Virginia. The Eastern Shore is the southern part of the Delmarva Peninsula that is occupied by Accomack and Northampton Counties in Virginia. Groundwater is the sole source of freshwater to the Eastern Shore, and demands for water have been increasing from domestic, industrial, agricultural, and public-supply sectors of the economy. Thus, it is important that the groundwater supply be protected from overextraction and seawater intrusion. The best way for water managers to use all of the information available is usually to compile this information into a numerical model that can simulate the response of the system to current and future stresses. A detailed description of the geology, hydrogeology, and historical groundwater extractions was compiled and entered into the numerical model. The hydrogeologic framework is composed of a surficial aquifer under unconfined conditions, a set of three aquifers and associated overlying confining units under confined conditions (the upper, middle, and lower Yorktown-Eastover Formation), and an underlying confining unit (the St. Marys Formation). An estimate of the location and depths of two major paleochannels was also included in the framework of the model. Total withdrawals from industrial, commercial, public-supply, and some agricultural wells were compiled from the period 1900 through 2003. Reported pumpage from these sources increased dramatically during the 1960s and 70s, up to currently about 4 million gallons per day. Domestic withdrawals were estimated on the basis of population census districts and were assigned spatially to the model on the assumption that domestic users are located close to roads. A numerical model was created using the U.S. Geological Survey (USGS) code SEAWAT to simulate both water levels and concentrations of chloride (representing salinity). The model was

Seasonal plant water uptake patterns in the saline southeast Everglades ecotone.

Science.gov (United States)

Ewe, Sharon M L; Sternberg, Leonel da S L; Childers, Daniel L

2007-07-01

The purpose of this study was to determine the seasonal water use patterns of dominant macrophytes coexisting in the coastal Everglades ecotone. We measured the stable isotope signatures in plant xylem water of Rhizophora mangle, Cladium jamaicense, and Sesuvium portulacastrum during the dry (DS) and wet (WS) seasons in the estuarine ecotone along Taylor River in Everglades National Park, FL, USA. Shallow soilwater and deeper groundwater salinity was also measured to extrapolate the salinity encountered by plants at their rooting zone. Average soil water oxygen isotope ratios (delta(18)O) was enriched (4.8 +/- 0.2 per thousand) in the DS relative to the WS (0.0 +/- 0.1 per thousand), but groundwater delta(18)O remained constant between seasons (DS: 2.2 +/- 0.4 per thousand; WS: 2.1 +/- 0.1 per thousand). There was an inversion in interstitial salinity patterns across the soil profile between seasons. In the DS, shallow water was euhaline [i.e., 43 practical salinity units (PSU)] while groundwater was less saline (18 PSU). In the WS, however, shallow water was fresh (i.e., 0 PSU) but groundwater remained brackish (14 PSU). All plants utilized 100% (shallow) freshwater during the WS, but in the DS R. mangle switched to a soil-groundwater mix (delta 55% groundwater) while C. jamaicense and S. portulacastrum continued to use euhaline shallow water. In the DS, based on delta(18)O data, the roots of R. mangle roots were exposed to salinities of 25.4 +/- 1.4 PSU, less saline than either C. jamaicense (39.1 +/- 2.2 PSU) or S. portulacastrum (38.6 +/- 2.5 PSU). Although the salinity tolerance of C. jamaicense is not known, it is unlikely that long-term exposure to high salinity is conducive to the persistence of this freshwater marsh sedge. This study increases our ecological understanding of how water uptake patterns of individual plants can contribute to ecosystem levels changes, not only in the southeast saline Everglades, but also in estuaries in general in response to

Effect of Underground Saline Water on the Growth Characteristic of Tamarix austromongolica in Halomorphic Soil

Science.gov (United States)

Iwama, Kenji; Kobayashi, Koji; Kaneki, Ryoichi; Furukawa, Masayuki; Odani, Hiromichi

It is important to evaluate the salt tolerance of native plants in order to utilize them for improving halomorphic soil in arid regions. Tamarix austromongolica, a dominant species in Inner Mongolia, China, has the property of salt absorption and expected soil desalinization. The effect of salt concentration in groundwater on the growth of stock diameter and shoot length were evaluated by cultivation experiments, growing the plants from cuttings for two years. Though the plants grew well in 1% salt concentration of groundwater, the evapotranspiration in the second year was reduced because of the growth of the root system. The growth of the plants and evapotranspiration were reduced with increasing groundwater salinity of 3 to 5%, but most plants did not die. In contrast, the plants which were supplied with groundwater of 7% salt concentration in the second year started to die in about a month, and two thirds of them died within five months. Thus the results showed that the tolerant limit of salinity of the plants in groundwater was 7%, and the growth was constrained with groundwater salinity of 3 to 5% concentration. The plants that survived with 7% salinity in the second year, however, were grown in groundwater salt concentration of 3% to 5% in the first year. This result indicated that saline stress might have changed the characteristic of salinity tolerance of the plant.

Effect of reducing groundwater on the retardation of redox-sensitive radionuclides

Directory of Open Access Journals (Sweden)

Rose TP

2008-12-01

Full Text Available Abstract Laboratory batch sorption experiments were used to investigate variations in the retardation behavior of redox-sensitive radionuclides. Water-rock compositions were designed to simulate subsurface conditions at the Nevada Test Site (NTS, where a suite of radionuclides were deposited as a result of underground nuclear testing. Experimental redox conditions were controlled by varying the oxygen content inside an enclosed glove box and by adding reductants into the testing solutions. Under atmospheric (oxidizing conditions, radionuclide distribution coefficients varied with the mineralogic composition of the sorbent and the water chemistry. Under reducing conditions, distribution coefficients showed marked increases for 99Tc (from 1.22 at oxidizing to 378 mL/g at mildly reducing conditions and 237Np (an increase from 4.6 to 930 mL/g in devitrified tuff, but much smaller variations in alluvium, carbonate rock, and zeolitic tuff. This effect was particularly important for 99Tc, which tends to be mobile under oxidizing conditions. A review of the literature suggests that iodine sorption should decrease under reducing conditions when I- is the predominant species; this was not consistently observed in batch tests. Overall, sorption of U to alluvium, devitrified tuff, and zeolitic tuff under atmospheric conditions was less than in the glove-box tests. However, the mildly reducing conditions achieved here were not likely to result in substantial U(VI reduction to U(IV. Sorption of Pu was not affected by the decreasing Eh conditions achieved in this study, as the predominant sorbed Pu species in all conditions was expected to be the low-solubility and strongly sorbing Pu(OH4. Depending on the aquifer lithology, the occurrence of reducing conditions along a groundwater flowpath could potentially contribute to the retardation of redox-sensitive radionuclides 99Tc and 237Np, which are commonly identified as long-term dose contributors in the risk

The use of Time Domain Electromagnetic method and Continuous Vertical Electrical Sounding to map groundwater salinity in the Barotse sub-basin, Zambia

DEFF Research Database (Denmark)

Chongo, Mkhuzo; Wibroe, Johanne; Staal-Thomsen, K.

2011-01-01

-concentration of salts in interdune deposits, which were subsequently buried due to dune migration about 32 to 4 thousands of years ago or kilo annums (ka). The occurrence of saline groundwater could also possibly be linked to evaporation of a former Lake Paleo Makgadikgadi, an extensive endorheic lake system that once...

Towards a theory of ecotone resilience: coastal vegetation on a salinity gradient.

Science.gov (United States)

Jiang, Jiang; Gao, Daozhou; DeAngelis, Donald L

2012-08-01

Ecotones represent locations where vegetation change is likely to occur as a result of climate and other environmental changes. Using a model of an ecotone vulnerable to such future changes, we estimated the resilience of the ecotone to disturbances. The specific ecotone is that between two different vegetation types, salinity-tolerant and salinity-intolerant, along a gradient in groundwater salinity. In the case studied, each vegetation type, through soil feedback loops, promoted local soil salinity levels that favor itself in competition with the other type. Bifurcation analysis was used to study the system of equations for the two vegetation types and soil salinity. Alternative stable equilibria, one for salinity-tolerant and one for salinity intolerant vegetation, were shown to exist over a region of the groundwater salinity gradient, bounded by two bifurcation points. This region was shown to depend sensitively on parameters such as the rate of upward infiltration of salinity from groundwater into the soil due to evaporation. We showed also that increasing diffusion rates of vegetation can lead to shrinkage of the range between the two bifurcation points. Sharp ecotones are typical of salt-tolerant vegetation (mangroves) near the coastline and salt-intolerant vegetation inland, even though the underlying elevation and groundwater salinity change very gradually. A disturbance such as an input of salinity to the soil from a storm surge could upset this stable boundary, leading to a regime shift of salinity-tolerant vegetation inland. We showed, however, that, for our model as least, a simple pulse disturbance would not be sufficient; the salinity would have to be held at a high level, as a 'press', for some time. The approach used here should be generalizable to study the resilience of a variety of ecotones to disturbances. Published by Elsevier Inc.

A site scale analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1997-10-01

The objective of the study is to develop, calibrate and apply a numerical simulation model of the Aespoe area. An area of 1.8 x 1.8 km 2 , centred around the Aespoe Hard Rock Laboratory (HRL), gives the horizontal extent of the model. In the vertical direction the model follows the topography at the upper boundary and has a lower boundary at 1000 metres below sea level. The model is based on a mathematical model that includes equations for the Darcy velocities, mass conservation and salinity distribution. Gravitational effects are thus fully accounted for. A regional groundwater model was used to generate boundary conditions for vertical and bottom boundaries. Transmissivities of fracture zones and conductivities for the rock in between, as used in the model, are based on field data. An extensive calibration of the model is carried out, using data for natural conditions (i.e. prior to the construction of the Aespoe HRL), drawdowns from a pump test and data collected during the excavation of the tunnel. A satisfactory agreement with field data is obtained by the calibration. Main results from the model include vertical and horizontal sections of flow, salinity and hydraulic head distributions for natural conditions and for completed tunnel. A sensitivity study, where boundary conditions and material properties are modified, is also carried out. The model is also used to describe some characteristic features of the site like infiltration rates, flux statistics at a depth of 450 metres, salinity of inflows to the tunnel and flow and salinity distributions in fracture zones. The general conclusion of the study is that the model developed can simulate the conditions at Aespoe, both natural and with Aespoe HRL present, in a realistic manner

Long-Term Retardation of Uranium in the KURT Environment

International Nuclear Information System (INIS)

Baik, Min Hoon; Shin, Joo Do; Park, Tae Jin

2016-01-01

One of possibilities resolving this issue is to study the migration and retardation processes of radionuclides in the subsurface environments by using naturally occurring radionuclides as analogues of radioactive waste. To date, however, the long-term behavior of radionuclides in a granitic groundwater system is not yet fully understood. The ubiquitous presence of uranium (U) in rocks makes it an ideal natural analogue for studying the behaviors of radionuclides in a deep geological repository for the final disposal of HLW. In this study, long-term retardation behavior of natural uranium was investigated using granite rock samples taken from the KURT (KAERI Underground Research Tunnel), located in Daejeon city. The distribution of uranium and its binding mechanism in granite samples were investigated using the sequential chemical extraction (SCE) technique combined with X-ray diffraction (XRD) and ICP-MS methods. In this study, the long-term retardation of uranium in the KURT environment was investigated using SCE and EPMA techniques combined with ICP-MS and XRD. Results showed that long-term interaction of rock with groundwater can change U species and mineralize dissolved U, which can consequently contribute to the retardation of U in the fractured granitic rock environment. This study will help us to understand the long-term behavior of radionuclides migrating through the fractured granite rock and then enhance the reliability of the safety assessment for a HLW repository

The model for solubility of CO2 in saline groundwater with complex ions and the application on Erdos basin

International Nuclear Information System (INIS)

Wang Lu; Yu Qingchun

2014-01-01

To obtain accurate solubility of CO 2 is one of problems that need solutions urgently in CO 2 sequestration within saline groundwater. However, there are few data published for solubility of CO 2 under geological sequestration conditions. In order to fill the gap of the experimental study, the solubility of CO 2 in five formations of Erdos Basin was explored in this research. Groundwater samples in five reservoirs were carried out through an observation well in the Erdos Basin. The chemical composition was determined and experiments measuring CO 2 solubility were carried out in the synthetic water samples. Krichevsky-Kasarnovsky equation was established to analyze the experimental data. The relationship between concentration of K + , Na + , Ca 2+ , Mg 2+ and the solubility of CO 2 was analyzed and an excellent liner fit was found, which quantifies the impact of ions on the solubility of cO 2 . Solubility data were compared to the model prediction over the temperature and pressure ranges of 318 ∼ 348 K and 8 ∼ 11 MPa. The average absolute deviation is 2.11%. The results can be used as a parameter for the evaluation of the CO 2 storage capacity in deep saline aquifer of Erdos Basin. (authors)

Shallow rainwater lenses in deltaic areas with saline seepage

NARCIS (Netherlands)

Louw, de P.G.B.; Eeman, S.; Siemon, B.; `Voortman, B.R.; Gunnink, J.; Baaren, E.S.; Oude Essink, G.H.P.

2011-01-01

In deltaic areas with saline seepage, freshwater availability is often limited to shallow rainwater lenses lying on top of saline groundwater. Here we describe the characteristics and spatial variability of such lenses in areas with saline seepage and the mechanisms that control their occurrence and

Shallow rainwater lenses in deltaic areas with saline seepage

NARCIS (Netherlands)

De Louw, Perry G.B.; Eeman, Sara; Siemon, Bernhard; Voortman, Bernard R.; Gunnink, Jan; Van Baaren, Esther S.; Oude Essink, Gualbert

2011-01-01

In deltaic areas with saline seepage, fresh water availability is often limited to shallow rainwater lenses lying on top of saline groundwater. Here we describe the characteristics and spatial variability of such lenses in areas with saline seepage and the mechanisms that control their occurrence

Airborne and ground-based transient electromagnetic mapping of groundwater salinity in the Machile–Zambezi Basin, southwestern Zambia

DEFF Research Database (Denmark)

Chongo, Mkhuzo; Vest Christiansen, Anders; Tembo, Alice

2015-01-01

The geological and morphological evolution of the Kalahari Basin of Southern Africa has given rise to a complex hydrogeological regime that is affected by water quality issues. Among these concerns is the occurrence of saline groundwater. Airborne and ground-based electromagnetic surveying...... of a low-resistivity (below 13 Ωm) valley that extends southwestwards into the Makgadikgadi salt pans. The electrical resistivity distribution is indicative of a full graben related to the Okavango–Linyati Fault system as a result of propagation of the East African Rift Valley System into Southern Africa...

Evaluation of effects of changes in canal management and precipitation patterns on salinity in Biscayne Bay, Florida, using an integrated surface-water/groundwater model

Science.gov (United States)

Lohmann, Melinda A.; Swain, Eric D.; Wang, John D.; Dixon, Joann

2012-01-01

Biscayne National Park, located in Biscayne Bay in southeast Florida, is one of the largest marine parks in the country and sustains a large natural marine fishery where numerous threatened and endangered species reproduce. In recent years, the bay has experienced hypersaline conditions (salinity greater than 35 practical salinity units) of increasing magnitude and duration. Hypersalinity events were particularly pronounced during April to August 2004 in nearshore areas along the southern and middle parts of the bay. Prolonged hypersaline conditions can cause degradation of water quality and permanent damage to, or loss of, brackish nursery habitats for multiple species of fish and crustaceans as well as damage to certain types of seagrasses that are not tolerant of extreme changes in salinity. To evaluate the factors that contribute to hypersalinity events and to test the effects of possible changes in precipitation patterns and canal flows into Biscayne Bay on salinity in the bay, the U.S. Geological Survey constructed a coupled surface-water/groundwater numerical flow model. The model is designed to account for freshwater flows into Biscayne Bay through the canal system, leakage of salty bay water into the underlying Biscayne aquifer, discharge of fresh and salty groundwater from the Biscayne aquifer into the bay, direct effects of precipitation on bay salinity, indirect effects of precipitation on recharge to the Biscayne aquifer, direct effects of evapotranspiration (ET) on bay salinity, indirect effects of ET on recharge to the Biscayne aquifer, and maintenance of mass balance of both water and solute. The model was constructed using the Flow and Transport in a Linked Overland/Aquifer Density Dependent System (FTLOADDS) simulator, version 3.3, which couples the two-dimensional, surface-water flow and solute-transport simulator SWIFT2D with the density-dependent, groundwater flow an solute-transport simulator SEAWAT. The model was calibrated by a trial

Using of pH as a tool to predict salinity of groundwater for irrigation purpose using artificial neural network

Directory of Open Access Journals (Sweden)

Mahmoud Nasr

2014-01-01

Full Text Available Monitoring of groundwater quality is one of the important tools to provide adequate information about water management. In the present study, artificial neural network (ANN with a feed-forward back-propagation was designed to predict groundwater salinity, expressed by total dissolved solids (TDS, using pH as an input parameter. Groundwater samples were collected from a 36 m depth well located in the experimental farm of the City of Scientific Researches and Technological Applications (SRTA City, New Borg El-Arab City, Alexandria, Egypt. The network structure was 1–5–3–1 and used the default Levenberg–Marquardt algorithm for training. It was observed that, the best validation performance, based on the mean square error, was 14819 at epoch 0, and no major problems or over-fitting occurred with the training step. The simulated output tracked the measured data with a correlation coefficient (R-value of 0.64, 0.67 and 0.90 for training, validation and test, respectively. In this case, the network response was acceptable, and simulation could be used for entering new inputs.

Pressure retarded osmosis from hypersaline sources - A review

DEFF Research Database (Denmark)

Bajraktari, Niada; Hélix-Nielsen, Claus; Madsen, Henrik T.

2017-01-01

for commercialization. The scope of this paper is to review the existing knowledge on the use of hypersaline waters in the salinity gradient process, pressure retarded osmosis. Although only few papers have had the specific aim of investigating hypersaline waters, concentrated solutions have been used in many papers...

Salinization of aquifers at the regional scale by marine transgression: Time scales and processes

Science.gov (United States)

Armandine Les Landes, A.; Davy, P.; Aquilina, L.

2014-12-01

Saline fluids with moderate concentrations have been sampled and reported in the Armorican basement at the regional scale (northwestern France). The horizontal and vertical distributions of high chloride concentrations (60-1400mg/L) at the regional scale support the marine origin and provide constraints on the age of these saline fluids. The current distribution of fresh and "saline" groundwater at depth is the result mostly of processes occurring at geological timescales - seawater intrusion processes followed by fresh groundwater flushing -, and only slightly of recent anthropogenic activities. In this study, we focus on seawater intrusion mechanisms in continental aquifers. We argue that one of the most efficient processes in macrotidal environments is the gravity-driven downconing instability below coastal salinized rivers. 2-D numerical experiments have been used to quantify this process according to four main parameter types: (1) the groundwater system permeability, (2) the salinity degree of the river, (3) the river width and slope, and (4) the tidal amplitude. A general expression of the salinity inflow rates have been derived, which has been used to estimate groundwater salinization rates in Brittany, given the geomorphological and environmental characteristics (drainage basin area, river widths and slopes, tidal range, aquifer permeability). We found that downconing below coastal rivers entail very high saline rates, indicating that this process play a major role in the salinization of regional aquifers. This is also likely to be an issue in the context of climate change, where sea-level rise is expected.

Influence of seawater intrusion on microbial communities in groundwater.

Science.gov (United States)

Unno, Tatsuya; Kim, Jungman; Kim, Yumi; Nguyen, Son G; Guevarra, Robin B; Kim, Gee Pyo; Lee, Ji-Hoon; Sadowsky, Michael J

2015-11-01

Groundwater is the sole source of potable water on Jeju Island in the Republic of (South) Korea. Groundwater is also used for irrigation and industrial purposes, and it is severely impacted by seawater intrusion in coastal areas. Consequently, monitoring the intrusion of seawater into groundwater on Jeju is very important for health and environmental reasons. A number of studies have used hydrological models to predict the deterioration of groundwater quality caused by seawater intrusion. However, there is conflicting evidence of intrusion due to complicated environmental influences on groundwater quality. Here we investigated the use of next generation sequencing (NGS)-based microbial community analysis as a way to monitor groundwater quality and detect seawater intrusion. Pristine groundwater, groundwater from three coastal areas, and seawater were compared. Analysis of the distribution of bacterial species clearly indicated that the high and low salinity groundwater differed significantly with respect to microbial composition. While members of the family Parvularculaceae were only identified in high salinity water samples, a greater percentage of the phylum Actinobacteria was predominantly observed in pristine groundwater. In addition, we identified 48 shared operational taxonomic units (OTUs) with seawater, among which the high salinity groundwater sample shared a greater number of bacterial species with seawater (6.7%). In contrast, other groundwater samples shared less than 0.5%. Our results suggest that NGS-based microbial community analysis of groundwater may be a useful tool for monitoring groundwater quality and detect seawater intrusion. This technology may also provide additional insights in understanding hydrological dynamics. Copyright © 2015 Elsevier B.V. All rights reserved.

Regional distribution of microbes in groundwater from Haestholmen, Kivetty, Olkiluoto and Romuvaara, Finland

Energy Technology Data Exchange (ETDEWEB)

Haveman, S.A.; Nilsson, E.L.; Pedersen, K. [Goeteborg University (Sweden)

2000-06-01

Groundwater was sampled with the PAVE groundwater sampling system from eight boreholes at Haestholmen, Kivetty, Olkiluoto and Romuvaara, Finland, in 1998 and 1999, for investigation of microbial populations. The groundwater samples had a wide range of salinity and chemistry and contained 104-105 cells per ml, which is typical for subsurface groundwater. In preparing culture media, two approaches were used and compared. Natural, groundwater-based media were prepared from groundwater from the same section of each borehole tested, and synthetic media were prepared based on groundwater chemistry data. No significant difference was observed between the two types of media for brackish and saline groundwater. The groundwater to a depth of 750 m contained mainly sulphate-reducing bacteria (SRB), ironreducing bacteria (IRB) and heterotrophic acetogenic (HA) bacteria. Autotrophic acetogenic (AA) bacteria and methanogenic archaea were found in some samples. Iron-reducing and HA bacteria predominated in brackish groundwater from Haestholmen, with SRB present in smaller numbers. A different microbial population was found in deep saline groundwater from Haestholmen and Olkiluoto that consists of a large proportion of a saline or brine end member. No SRB or AA bacteria were cultured; instead, the microbial population consisted of HA bacteria and either IRB or methanogens. In Olkiluoto, SRB predominated in the brackish and saline groundwater at depths to about 500 m, while methanogens were found in deeper saline groundwater. Stable isotope data (C-13) indicated that the methanogens are part of an autotrophic population consuming dissolved inorganic carbon (DIC) and hydrogen and producing methane and organic carbon. This deep ecosystem may be independent of surface life processes. A high-level radioactive waste (HLW) repository at 500 m depth in the Fennoscandian Shield will be inhabited by SRB, IRB and acetogens. Methanogens may also be present. These anaerobic micro

Recent state report: Groundwater programmes of variable density

International Nuclear Information System (INIS)

Fein, E.

1991-12-01

This report summarises basic facts and data that may be helpful in decisions about the development of a groundwater programme for the calculation of saline groundwater movements. Generally accepted requirements of a rapid groundwater programme for the assessment of flow mechanisms above salt domes are defined. It also describes the possibilities offered by similar programmes already in progress on a national and international basis and discusses state-of-the-art numerical methods and hardware in respect of speed and efficiency of the relevant computer programmes. The availability of a rapid groundwater programme would make it possible for model calculations in connection with long-term safety analyses to take account of the influence of salinity on groundwater movements in extended and complex model regions. (orig./DG) [de

Geophysical and geochemical characterisation of groundwater resources in Western Zambia

DEFF Research Database (Denmark)

Chongo, Mkhuzo; Banda, Kawawa Eddy; Bauer-Gottwein, Peter

Zambia’s rural water supply system depends on groundwater resources to a large extent. However, groundwater resources are variable in both quantity and quality across the country and a national groundwater resources assessment and mapping program is presently not in place. In the Machile area...... in South-Western Zambia, groundwater quality problems are particularly acute. Saline groundwater occurrence is widespread and affects rural water supply, which is mainly based on shallow groundwater abstraction using hand pumps. This study has mapped groundwater quality variations in the Machile area using...... both ground-based and airborne geophysical methods as well as extensive water quality sampling. The occurrence of saline groundwater follows a clear spatial pattern and appears to be related to the palaeo Lake Makgadikgadi, whose northernmost extension reached into the Machile area. Because the lake...

Influence of natural organic matter fouling and osmotic backwash on pressure retarded osmosis energy production from natural salinity gradients.

Science.gov (United States)

Yip, Ngai Yin; Elimelech, Menachem

2013-01-01

Pressure retarded osmosis (PRO) has the potential to produce clean, renewable energy from natural salinity gradients. However, membrane fouling can lead to diminished water flux productivity, thus reducing the extractable energy. This study investigates organic fouling and osmotic backwash cleaning in PRO and the resulting impact on projected power generation. Fabricated thin-film composite membranes were fouled with model river water containing natural organic matter. The water permeation carried foulants from the feed river water into the membrane porous support layer and caused severe water flux decline of ∼46%. Analysis of the water flux behavior revealed three phases in membrane support layer fouling. Initial foulants of the first fouling phase quickly adsorbed at the active-support layer interface and caused a significantly greater increase in hydraulic resistance than the subsequent second and third phase foulants. The water permeability of the fouled membranes was lowered by ∼39%, causing ∼26% decrease in projected power density. A brief, chemical-free osmotic backwash was demonstrated to be effective in removing foulants from the porous support layer, achieving ∼44% recovery in projected power density. The substantial performance recovery after cleaning was attributed to the partial restoration of the membrane water permeability. This study shows that membrane fouling detrimentally impacts energy production, and highlights the potential strategies to mitigate fouling in PRO power generation with natural salinity gradients.

Natural radionuclides in groundwaters

International Nuclear Information System (INIS)

Laul, J.C.

1990-01-01

The U-234 and Th-230 radionuclides are highly retarded by factors of 10 4 to 10 5 in basalt groundwater (Hanford) and briny groundwaters from Texas and geothermal brine from the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na + and Cl - ions and RaCl 2 is soluble in brines. Pb-210 is soluble in SSGF brine, probably as a chloride complex. The U-234/Th-230 ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. 19 refs., 3 figs

Combining ground-based and airborne EM through Artificial Neural Networks for modelling glacial till under saline groundwater conditions

DEFF Research Database (Denmark)

Gunnink, J.L.; Bosch, A.; Siemon, B.

2012-01-01

Airborne electromagnetic (AEM) methods supply data over large areas in a cost-effective way. We used ArtificialNeural Networks (ANN) to classify the geophysical signal into a meaningful geological parameter. By using examples of known relations between ground-based geophysical data (in this case...... electrical conductivity, EC, from electrical cone penetration tests) and geological parameters (presence of glacial till), we extracted learning rules that could be applied to map the presence of a glacial till using the EC profiles from the airborne EM data. The saline groundwater in the area was obscuring...

Shallow rainwater lenses in deltaic areas with saline seepage

Directory of Open Access Journals (Sweden)

P. G. B. de Louw

2011-12-01

Full Text Available In deltaic areas with saline seepage, freshwater availability is often limited to shallow rainwater lenses lying on top of saline groundwater. Here we describe the characteristics and spatial variability of such lenses in areas with saline seepage and the mechanisms that control their occurrence and size. Our findings are based on different types of field measurements and detailed numerical groundwater models applied in the south-western delta of the Netherlands. By combining the applied techniques we could extrapolate measurements at point scale (groundwater sampling, temperature and electrical soil conductivity (TEC-probe measurements, electrical cone penetration tests (ECPT to field scale (continuous vertical electrical soundings (CVES, electromagnetic survey with EM31, and even to regional scale using helicopter-borne electromagnetic measurements (HEM. The measurements show a gradual mixing zone between infiltrating fresh rainwater and upward flowing saline groundwater. The mixing zone is best characterized by the depth of the centre of the mixing zone D_mix, where the salinity is half that of seepage water, and the bottom of the mixing zone B_mix, with a salinity equal to that of the seepage water (Cl-conc. 10 to 16 g l⁻¹. D_mix is found at very shallow depth in the confining top layer, on average at 1.7 m below ground level (b.g.l., while B_mix lies about 2.5 m b.g.l. The model results show that the constantly alternating upward and downward flow at low velocities in the confining layer is the main mechanism of mixing between rainwater and saline seepage and determines the position and extent of the mixing zone (D_mix and B_mix. Recharge, seepage flux, and drainage depth are the controlling factors.

Influence of basalt/groundwater interactions on radionuclide migration

International Nuclear Information System (INIS)

Vandegrift, G.F.

1984-01-01

The work presented here is a partial summary of the experimental results obtained in the Laboratory Analog Program. Two aspects of this effort are (1) the interaction between simulated basaltic groundwater and basalt fissures that were either freshly cleaved or laboratory altered by hydrothermal treatment with the simulated groundwater and (2) the effect of this interaction on radionuclide migration through these basalt fissures. The following conclusions of this study bear heavily on the predicted safety of a basalt repository: Sorption properties of freshly fissured basalt and naturally aged basalt are quite different for different chemical species. Analog experiments predict that aged basalt would be an effective retarder of cesium, but would be much less so for actinide elements. Distribution ratios measured from batch experiments with finely ground rock samples (presenting unaltered rock surfaces) are not a reliable means of predicting radionuclide migration in geological repositories. As the near-repository area is resaturated by groundwater, its ability to retard actinide migration will be degraded with time. Disturbing the natural flow of groundwater through the repository area by constructing and backfilling the repository will modify the composition of groundwater. This modified groundwater is likely to interact with and to modify naturally aged basalt surfaces downstream from the repository

Thermodynamic and energy efficiency analysis of power generation from natural salinity gradients by pressure retarded osmosis.

Science.gov (United States)

Yip, Ngai Yin; Elimelech, Menachem

2012-05-01

The Gibbs free energy of mixing dissipated when fresh river water flows into the sea can be harnessed for sustainable power generation. Pressure retarded osmosis (PRO) is one of the methods proposed to generate power from natural salinity gradients. In this study, we carry out a thermodynamic and energy efficiency analysis of PRO work extraction. First, we present a reversible thermodynamic model for PRO and verify that the theoretical maximum extractable work in a reversible PRO process is identical to the Gibbs free energy of mixing. Work extraction in an irreversible constant-pressure PRO process is then examined. We derive an expression for the maximum extractable work in a constant-pressure PRO process and show that it is less than the ideal work (i.e., Gibbs free energy of mixing) due to inefficiencies intrinsic to the process. These inherent inefficiencies are attributed to (i) frictional losses required to overcome hydraulic resistance and drive water permeation and (ii) unutilized energy due to the discontinuation of water permeation when the osmotic pressure difference becomes equal to the applied hydraulic pressure. The highest extractable work in constant-pressure PRO with a seawater draw solution and river water feed solution is 0.75 kWh/m(3) while the free energy of mixing is 0.81 kWh/m(3)-a thermodynamic extraction efficiency of 91.1%. Our analysis further reveals that the operational objective to achieve high power density in a practical PRO process is inconsistent with the goal of maximum energy extraction. This study demonstrates thermodynamic and energetic approaches for PRO and offers insights on actual energy accessible for utilization in PRO power generation through salinity gradients. © 2012 American Chemical Society

Integrating an artificial intelligence approach with k-means clustering to model groundwater salinity: the case of Gaza coastal aquifer (Palestine)

Science.gov (United States)

Alagha, Jawad S.; Seyam, Mohammed; Md Said, Md Azlin; Mogheir, Yunes

2017-12-01

Artificial intelligence (AI) techniques have increasingly become efficient alternative modeling tools in the water resources field, particularly when the modeled process is influenced by complex and interrelated variables. In this study, two AI techniques—artificial neural networks (ANNs) and support vector machine (SVM)—were employed to achieve deeper understanding of the salinization process (represented by chloride concentration) in complex coastal aquifers influenced by various salinity sources. Both models were trained using 11 years of groundwater quality data from 22 municipal wells in Khan Younis Governorate, Gaza, Palestine. Both techniques showed satisfactory prediction performance, where the mean absolute percentage error (MAPE) and correlation coefficient ( R) for the test data set were, respectively, about 4.5 and 99.8% for the ANNs model, and 4.6 and 99.7% for SVM model. The performances of the developed models were further noticeably improved through preprocessing the wells data set using a k-means clustering method, then conducting AI techniques separately for each cluster. The developed models with clustered data were associated with higher performance, easiness and simplicity. They can be employed as an analytical tool to investigate the influence of input variables on coastal aquifer salinity, which is of great importance for understanding salinization processes, leading to more effective water-resources-related planning and decision making.

Salinity-gradient power: Evaluation of pressure-retarded osmosis and reverse electrodialysis

NARCIS (Netherlands)

Post, J.W.; Veerman, J.; Hamelers, H.V.M.; Euverink, G.J.W.; Metz, S.J.; Nymeijer, K.; Buisman, C.J.N.

2007-01-01

A huge potential to obtain clean energy exists from mixing water streams with different salt concentrations. Two membrane-based energy conversion techniques are evaluated: pressure-retarded osmosis and reverse electrodialysis. From the literature, a comparison is not possible since the reported

Electromagnetic exploration in high-salinity groundwater zones: case studies from volcanic and soft sedimentary sites in coastal Japan

Science.gov (United States)

Suzuki, Koichi; Kusano, Yukiko; Ochi, Ryota; Nishiyama, Nariaki; Tokunaga, Tomochika; Tanaka, Kazuhiro

2017-01-01

Estimating the spatial distribution of groundwater salinity in coastal plain regions is becoming increasingly important for site characterisation and the prediction of hydrogeological environmental conditions resulting from radioactive waste disposal and underground CO2 storage. In previous studies of the freshwater-saltwater interface, electromagnetic methods were used for sites characterised by unconsolidated deposits or Neocene soft sedimentary rocks. However, investigating the freshwater-saltwater interface in hard rock sites (e.g. igneous areas) is more complex, with the permeability of the rocks greatly influenced by fractures. In this study, we investigated the distribution of high-salinity groundwater at two volcanic rock sites and one sedimentary rock site, each characterised by different hydrogeological features. Our investigations included (1) applying the controlled source audio-frequency magnetotelluric (CSAMT) method and (2) conducting laboratory tests to measure the electrical properties of rock core samples. We interpreted the 2D resistivity sections by referring to previous data on geology and geochemistry of groundwater. At the Tokusa site, an area of inland volcanic rocks, low resistivity zones were detected along a fault running through volcanic rocks and shallow sediments. The results suggest that fluids rise through the Tokusa-Jifuku Fault to penetrate shallow sediments in a direction parallel to the river, and some fluids are diluted by rainwater. At the Oki site, a volcanic island on a continental shelf, four resistivity zones (in upward succession: low, high, low and high) were detected. The results suggest that these four zones were formed during a transgression-regression cycle caused by the last glacial period. At the Saijo site, located on a coastal plain composed of thick sediments, we observed a deep low resistivity zone, indicative of fossil seawater remnant from a transgression after the last glacial period. The current coastal

Natural radionuclides in groundwaters

International Nuclear Information System (INIS)

Laul, J.C.

1992-01-01

The 234 U and 230 Th radionuclides are highly retarded by factors of 10 4 to 10 5 in basalt groundwater (Hanford) and briny groundwaters from Texas, and geothermal brine form the Salton Sea Geothermal Field (SSGF). In basalt groundwaters (low ionic strength), Ra is highly sorbed, while in brines (high ionic strength), Ra is soluble. This is probably because the sorption sites are saturated with Na + and Cl - ions, and RaCl 2 is soluble in brines. 210 Pb is soluble in SSGF brine, probably as a chloride complex. The 234 U/ 230 Th ratios in basalt groundwaters and brines from Texas and SSGF are nearly unity, indicating that U is in the +4 state, suggesting a reducing environment for these aquifers. (author) 19 refs.; 3 figs

Effects of experimental parameters on the sorption of cesium, strontium, and uranium from saline groundwaters onto shales: Progress report

International Nuclear Information System (INIS)

Meyer, R.E.; Arnold, W.D.; Case, F.I.; O'Kelley, G.D.

1988-11-01

This report concerns an extension of the first series of experiments on the sorption properties of shales and their clay mineral components reported earlier. Studies on the sorption of cesium and strontium were carried out on samples of Chattanooga (Upper Dowelltown), Pierre, Green River Formation, Nolichucky, and Pumpkin Valley Shales that had been heated to 120/degree/C in a 0.1-mol/L NaCl solution for periods up to several months and on samples of the same shales which had been heated to 250/degree/C in air for six months, to simulate limiting scenarios in a HLW repository. To investigate the kinetics of the sorption process in shale/groundwater systems, strontium sorption experiments were done on unheated Pierre, Green River Formation, Nolichucky, and Pumpkin Valley Shales in a diluted, saline groundwater and in 0.03-mol/L NaHCO 3 , for periods of 0.25 to 28 days. Cesium sorption kinetics tests were performed on the same shales in a concentrated brine for the same time periods. The effect of the water/rock (W/R) ratio on sorption for the same combinations of unheated shales, nuclides, and groundwaters used in the kinetics experiments was investigated for a range of W/R ratios of 3 to 20 mL/g. Because of the complexity of the shale/groundwater interaction, a series of tests was conducted on the effects of contact time and W/R ratio on the pH of a 0.03-mol/L NaHCO 3 simulated groundwater in contact with shales. 8 refs., 12 figs., 15 tabs

Potential impact of climate change on groundwater resources in the Central Huai Luang Basin, Northeast Thailand.

Science.gov (United States)

Pholkern, Kewaree; Saraphirom, Phayom; Srisuk, Kriengsak

2018-08-15

The Central Huai Luang Basin is one of the important rice producing areas of Udon Thani Province in Northeastern Thailand. The basin is underlain by the rock salt layers of the Maha Sarakham Formation and is the source of saline groundwater and soil salinity. The regional and local groundwater flow systems are the major mechanisms responsible for spreading saline groundwater and saline soils in this basin. Climate change may have an impact on groundwater recharge, on water table depth and the consequences of waterlogging, and on the distribution of soil salinity in this basin. Six future climate conditions from the SEACAM and CanESM2 models were downscaled to investigate the potential impact of future climate conditions on groundwater quantity and quality in this basin. The potential impact was investigated by using a set of numerical models, namely HELP3 and SEAWAT, to estimate the groundwater recharge and flow and the salt transport of groundwater simulation, respectively. The results revealed that within next 30years (2045), the future average annual temperature is projected to increase by 3.1°C and 2.2°C under SEACAM and CanESM2 models, respectively, while the future precipitation is projected to decrease by 20.85% under SEACAM and increase by 18.35% under the CanESM2. Groundwater recharge is projected to increase under the CanESM2 model and to slightly decrease under the SEACAM model. Moreover, for all future climate conditions, the depths of the groundwater water table are projected to continuously increase. The results showed the impact of climate change on salinity distribution for both the deep and shallow groundwater systems. The salinity distribution areas are projected to increase by about 8.08% and 56.92% in the deep and shallow groundwater systems, respectively. The waterlogging areas are also projected to expand by about 63.65% from the baseline period. Copyright © 2018 Elsevier B.V. All rights reserved.

Occurrence and distribution of organophosphorus flame retardants and plasticizers in anthropogenically affected groundwater.

Science.gov (United States)

Regnery, J; Püttmann, W; Merz, C; Berthold, G

2011-02-01

Occurrence and distribution of chlorinated and non-chlorinated organophosphates in 72 groundwater samples from Germany under different recharge/infiltration conditions were investigated. Tris(2-chloro-1-methylethyl) phosphate (TCPP) and tris(2-chloroethyl) phosphate (TCEP) were the most frequently detected organophosphates in groundwater samples. Highest individual organophosphate concentrations (>0.1 µg L(-1)) were determined in groundwater polluted by infiltrating leachate and groundwater recharged via riverbank filtration of organophosphate-loaded recipients. In samples from springs and deep groundwater monitoring wells that are not affected by surface waters, organophosphate concentrations were mostly below the limit of detection. The occurrence (3-9 ng L(-1)) of TCPP and TCEP in samples from aquifers with groundwater ages between 20 and 45 years indicates the persistence of both compounds within the aquifer. At urban sites organophosphate-loaded precipitation, surface runoff, and leakage of wastewater influenced groundwater quality. For rural sites, where groundwater recharge is only influenced by precipitation, organophosphates were very rarely detectable in groundwater.

Salinization and arsenic contamination of surface water in southwest Bangladesh.

Science.gov (United States)

Ayers, John C; George, Gregory; Fry, David; Benneyworth, Laura; Wilson, Carol; Auerbach, Leslie; Roy, Kushal; Karim, Md Rezaul; Akter, Farjana; Goodbred, Steven

2017-09-11

To identify the causes of salinization and arsenic contamination of surface water on an embanked island (i.e., polder) in the tidal delta plain of SW Bangladesh we collected and analyzed water samples in the dry (May) and wet (October) seasons in 2012-2013. Samples were collected from rice paddies (wet season), saltwater ponds used for brine shrimp aquaculture (dry season), freshwater ponds and tidal channels (both wet and dry season), and rainwater collectors. Continuous measurements of salinity from March 2012 to February 2013 show that tidal channel water increases from ~0.15 ppt in the wet season up to ~20 ppt in the dry season. On the polder, surface water exceeds the World Health Organization drinking water guideline of 10 μg As/L in 78% of shrimp ponds and 27% of rice paddies, raising concerns that produced shrimp and rice could have unsafe levels of As. Drinking water sources also often have unsafe As levels, with 83% of tubewell and 43% of freshwater pond samples having >10 μg As/L. Water compositions and field observations are consistent with shrimp pond water being sourced from tidal channels during the dry season, rather than the locally saline groundwater from tubewells. Irrigation water for rice paddies is also obtained from the tidal channels, but during the wet season when surface waters are fresh. Salts become concentrated in irrigation water through evaporation, with average salinity increasing from 0.43 ppt in the tidal channel source to 0.91 ppt in the rice paddies. Our observations suggest that the practice of seasonally alternating rice and shrimp farming in a field has a negligible effect on rice paddy water salinity. Also, shrimp ponds do not significantly affect the salinity of adjacent surface water bodies or subjacent groundwater because impermeable shallow surface deposits of silt and clay mostly isolate surface water bodies from each other and from the shallow groundwater aquifer. Bivariate plots of conservative element

Saline water intrusion toward groundwater: Issues and its control

Directory of Open Access Journals (Sweden)

Purnama S

2012-10-01

Full Text Available Nowadays, saline water pollution has been gaining its importance as the major issue around the world, especially in the urban coastal area. Saline water pollution has major impact on human life and livelihood. It ́s mainly a result from static fossil water and the dynamics of sea water intrusion. The problem of saline water pollution caused by seawater intrusion has been increasing since the beginning of urban population. The problem of sea water intrusion in the urban coastal area must be anticipated as soon as possible especially in the urban areas developed in coastal zones,. This review article aims to; (i analyze the distribution of saline water pollution on urban coastal area in Indonesia and (ii analyze some methods in controlling saline water pollution, especially due to seawater intrusion in urban coastal area. The strength and weakness of each method have been compared, including (a applying different pumping patterns, (b artificial recharge, (c extraction barrier, (d injection barrier and (e subsurface barrier. The best method has been selected considering its possible development in coastal areas of developing countries. The review is based considering the location of Semarang coastal area, Indonesia. The results have shown that artificial recharge and extraction barrier are the most suitable methods to be applied in the area.

The hydrological and geochemical isolation of a freshwater bog within a saline fen in north-eastern Alberta

Directory of Open Access Journals (Sweden)

S.J. Scarlett

2013-10-01

Full Text Available In the oil sands development region near Fort McMurray, Alberta, wetlands cover ~62 % of the landscape, and ~95 % of these wetlands are peatlands. A saline fen was studied as a reference site for peatland reclamation. Despite highly saline conditions, a freshwater bog was observed in the path of local saline groundwater flow. The purpose of this study was to identify the hydrological controls that have allowed the development and persistence of a bog in this setting. The presence of bog vegetation and its dilute water chemistry suggest that saline groundwater from the fen rarely enters the bog, which functions predominantly as a groundwater recharge system. Chloride (Cl– and sodium (Na+ were the dominant ions in fen water, with concentrations averaging 5394 and 2307 mg L-1, respectively, while the concentrations in bog water were 5 and 4 mg L-1, respectively. These concentrations were reflected by salinity and electrical conductivity measurements, which in the fen averaged 9.3 ppt, and 15.8 mS cm-1, respectively, and in the bog averaged 0.1 ppt and 0.3 mS cm-1, respectively. A small ridge in the mineral substratum was found at the fen–bog margin, which created a persistent groundwater mound. Under the dry conditions experienced in early summer, groundwater flow was directed away from the bog at a rate of 14.6 mm day-1. The convex water table at the fen-bog margin impeded flow of saline water into the bog and instead directed it around the bog margin. However, the groundwater mound was eliminated during flooding in autumn, when the horizontal hydraulic gradient across the margin became negligible, suggesting the possibility of saline water ingress into the bog under these conditions.

Measurements of distribution coefficient for Sn, Pb and Th on sand stone and tuff in saline type groundwater

International Nuclear Information System (INIS)

Nakazawa, Toshiyuki; Okada, Kenichi; Muroi, Masayuki; Shibata, Masahiro; Sasamoto, Hiroshi

2004-02-01

Japan Nuclear Cycle Development Institute (JNC) has developed the sorption database for bentonite and rocks in order to assess the retardation capacities of important radioactive elements in natural and engineered barriers in the H12 report. However, there are not enough distribution coefficient data for radioactive elements in saline type groundwater in the database. Sn (tin), Pb (lead) and Th(thorium) are important radioactive elements for performance assessment of high level radioactive waste disposal, thus we carried out the batch sorption experiments for these radioactive elements on sand stone and tuff. The experiments for each radioactive element were performed on the following conditions; Sn: Kd measurements using the solutions (distilled water or artificial sea water) reacted with sand stone. Pb: Kd measurements using solution (artificial sea water) reacted with sand stone or tuff. Th: Kd measurements using solution (artificial sea water) reacted with sand stone as a function of carbonate concentration. The results of experiment are summarized below; In the case of Sn, Kd were 0.4-1 m 3 /kg in distilled water type and approximately 1 m 3 /kg in artificial sea water type. And also, Kd was 0.3 m 3 /kg in artificial sea water adjusted Ph 12. In artificial sea water type, it was suggested that Kd decreased with pH. In the case of Pb, Kd were approximately 2 m 3 /kg on sand stone and 4-10 m 3 /kg on tuff in artificial sea water type. Kd on tuff was a little larger than that on sand stone. There were no distinctly differences depending on solid-liquid separation methods. In the case of Th, Kd was approximately 1-8 m 3 /kg in artificial sea water type. On the other hand, sorption of Th on sand stone was not observed (i.e., Kd = 0 m 3 /kg) in high carbonate solution. It was estimated that low Kd in high carbonate solution might be caused by speciation of because Th could form the anions in the solution such as hydroxo-carbonate complexes and carbonate complexes

Coupled flow and salinity transport modelling in semi-arid environments

DEFF Research Database (Denmark)

Bauer-Gottwein, Peter; Held, R.J.; Zimmermann, S.

2006-01-01

Numerical groundwater modelling is used as the base for sound aquifer system analysis and water resources assessment. In many cases, particularly in semi-arid and arid regions, groundwater flow is intricately linked to salinity transport. A case in point is the Shashe River Valley in Botswana. A ...

Evidence for Upward Flow of Saline Water from Depth into the Mississippi River Valley Alluvial Aquifer in Southeastern Arkansas

Science.gov (United States)

Larsen, D.; Paul, J.

2017-12-01

Groundwater salinization is occurring in the Mississippi River Valley Alluvial (MRVA) aquifer in southeastern Arkansas (SE AR). Water samples from the MRVA aquifer in Chicot and Desha counties have yielded elevated Cl-concentrations with some as high as 1,639 mg/L. Considering that the MRVA aquifer is the principle source of irrigation water for the agricultural economy of SE AR, salinization needs to be addressed to ensure the sustainability of crop, groundwater, and soil resources in the area. The origin of elevated salinity in MRVA aquifer was investigated using spatial and factor analysis of historical water quality data, and sampling and tracer analysis of groundwater from irrigation, municipal, and flowing industrial wells in SE AR. Spatial analysis of Cl- data in relation to soil type, geomorphic features and sand-blow density indicate that the Cl- anomalies are more closely related to the sand-blow density than soil data, suggesting an underlying tectonic control for the distribution of salinity. Factor analysis of historical geochemical data from the MRVA and underlying Sparta aquifer shows dilute and saline groups, with saline groups weighted positively with Cl- or Na+ and Cl-. Tracer data suggest a component of evaporatively evolved crustal water of pre-modern age has mixed with younger, fresher meteoric sources in SE AR to create the saline conditions in the MRVA aquifer. Stable hydrogen and oxygen values of waters sampled from the Tertiary Sparta and MRVA aquifers deviate from the global and local meteoric water lines along an evaporative trend (slope=4.4) and mixing line with Eocene Wilcox Group groundwaters. Ca2+ and Cl- contents vary with Br- along mixing trends between dilute MRVA water and Jurassic Smackover Formation pore fluids in southern AR. Increasing Cl- content with C-14 age in MRVA aquifer groundwater suggests that the older waters are more saline. Helium isotope ratios decrease with He gas content for more saline water, consistent with

Paleoenvironmental and paleohydrochemical conditions of dolomite formation within a saline wetland in arid northwest Australia

Science.gov (United States)

Mather, Caroline C.; Skrzypek, Grzegorz; Dogramaci, Shawan; Grierson, Pauline F.

2018-04-01

Groundwater dolocrete occurring within the Fortescue Marsh, a large inland wetland in the Pilbara region of northwest Australia, has been investigated to provide paleoenvironmental and paleohydrological records and further the understanding of low temperature dolomite formation in terrestrial settings over the Quaternary Period. Two major phases of groundwater dolocrete formation are apparent from the presence of two distinct units of dolocrete, based on differences in depth, δ18O values and mineral composition. Group 1 (G1) occurs at depth 20-65 m b.g.l. (below ground level) and contains stoichiometric dolomite with δ18O values of -4.02-0.71‰. Group 2 (G2) is shallower (0-23 m b.g.l.), occurring close to the current groundwater level, and contains Ca-rich dolomite ± secondary calcite with a comparatively lower range of δ18O values (-7.74 and -6.03‰). Modelled δ18O values of paleogroundwater from which older G1 dolomite precipitated indicated highly saline source water, which had similar stable oxygen isotope compositions to relatively old brine groundwater within the Marsh, developed under a different hydroclimatic regime. The higher δ18O values suggest highly evaporitic conditions occurred at the Marsh, which may have been a playa lake to saline mud flat environment. In contrast, G2 dolomite precipitated from comparatively fresher water, and modelled δ18O values suggested formation from mixing between inflowing fresher groundwater with saline-brine groundwater within the Marsh. The δ18O values of the calcite indicates formation from brackish to saline groundwater, which suggests this process may be associated with coeval gypsum dissolution. In contrast to the modern hydrology of the Marsh, which is surface water dependent and driven by a flood and drought regime, past conditions conducive to dolomite precipitation suggest a groundwater dependent system, where shallow groundwaters were influenced by intensive evaporation.

Effluent salinity of pipe drains and tube-wells : a case study from the Indus plain

NARCIS (Netherlands)

Kelleners, T.J.

2001-01-01

Keywords: anisotropy, aquifer, desalinization, effluent salinity, groundwater, irrigation, salt-water upconing, soil salinity, stream-function, subsurface drainage

Irrigated agriculture in arid and semi-arid zones often suffers from waterlogging and salinity problems.

Development, evolution, and destruction of the saline mineral area of Eocene Lake Uinta, Piceance Basin, western Colorado

Science.gov (United States)

Johnson, Ronald C.; Brownfield, Michael E.

2015-01-01

Halite and the sodium bicarbonate mineral nahcolite were deposited in Eocene-age saline Lake Uinta in the Piceance Basin, northwestern Colorado. Variations in the areal extent of saline mineral deposition through time were studied using descriptions of core and outcrop. Saline minerals have been extensively leached by groundwater, and the original extent of saline deposition was determined from the distribution of empty vugs and collapse breccias. Because vugs and breccias strongly influence groundwater movement, determining where leaching has occurred is an important consideration for in-situ oil shale extraction methods currently being developed.

Water sources accessed by arid zone riparian trees in highly saline environments, Australia.

Science.gov (United States)

Costelloe, Justin F; Payne, Emily; Woodrow, Ian E; Irvine, Elizabeth C; Western, Andrew W; Leaney, Fred W

2008-05-01

The flow regimes of arid zone rivers are often highly variable, and shallow groundwater in the alluvial aquifers can be very saline, thus constraining the availability and quality of the major water sources available to riparian trees-soil water, shallow groundwater and stream water. We have identified water sources and strategies used by riparian trees in more highly saline and arid conditions than previously studied for riparian trees of arid zone rivers. Our research focused on the riparian species Eucalyptus coolabah, one of the major riparian trees of ephemeral arid zone rivers in Australia. The water sources available to this riparian tree were examined using delta(18)O isotope data from xylem, soil water, groundwater and surface water. Additionally, soil chloride and matric potential data were used to infer zones of water availability for root uptake. Despite the saline conditions, the trees used a mixture of soil water and groundwater sources, but they did not use surface water directly. The study identified three strategies used to cope with typically high groundwater and soil water salinities. Firstly, the trees preferentially grow in zones of most frequent flushing by infiltrating streamflow, such as the bank-tops of channels. Secondly, the trees limit water use by having low transpiration rates. Thirdly, the trees are able to extract water at very low osmotic potentials, with water uptake continuing at chloride concentrations of at least 20,000-30,000 mg L(-1).

Hydrogeochemical interpretation of the groundwater at the Haestholmen site, Finland

International Nuclear Information System (INIS)

Nordstrom, D.K.

1986-11-01

This investigation forms a part of the research aimed at marking an assessment of the suitability of rapakivi granite at Haestholmen, an island off the southeastern coast of Finland, for the storage of reactor waste from the Loviisa nuclear power plant. The purpose of this study is to provide preliminary interpretations of the groundwater chemistry based on analyses of groundwater samples taken from several drillholes down to depths of 200 m, as well as other hydrogeological studies made on the site. Chemical analyses of grounfwaters at Haestholmen have demonstrated a fresh-water/saline-water interface at 60-150 m depth, depending on the distance from the coast. The main conclusions from this study are that (1) the saline water has a seawater origin, (2) the saline water is most likely old Baltic seawater from the early to middle Holocene, (3) this seawater has been chemically modified by at least four processes: calcite precipitation, fluorite dissolution and precipitation, Na-K-Mg-Ca cation exchange and sulfate reduction, (4) the saline groundwaters are not chemically uniform with depth and (5) the saline water chemistry reflects a structural control by the bedrock

Performance Limiting Effects in Power Generation from Salinity Gradients by Pressure Retarded Osmosis

KAUST Repository

Yip, Ngai Yin

2011-12-01

Pressure retarded osmosis has the potential to utilize the free energy of mixing when fresh river water flows into the sea for clean and renewable power generation. Here, we present a systematic investigation of the performance limiting phenomena in pressure retarded osmosis-external concentration polarization, internal concentration polarization, and reverse draw salt flux-and offer insights on the design criteria of a high performance pressure retarded osmosis power generation system. Thin-film composite polyamide membranes were chemically modified to produce a range of membrane transport properties, and the water and salt permeabilities were characterized to determine the underlying permeability-selectivity trade-off relationship. We show that power density is constrained by the trade-off between permeability and selectivity of the membrane active layer. This behavior is attributed to the opposing influence of the beneficial effect of membrane water permeability and the detrimental impact of reverse salt flux coupled with internal concentration polarization. Our analysis reveals the intricate influence of active and support layer properties on power density and demonstrates that membrane performance is maximized by tailoring the water and salt permeabilities to the structural parameters. An analytical parameter that quantifies the relative influence of each performance limiting phenomena is employed to identify the dominant effect restricting productivity. External concentration polarization is shown to be the main factor limiting performance at high power densities. Enhancement of the hydrodynamic flow conditions in the membrane feed channel reduces external concentration polarization and thus, yields improved power density. However, doing so will also incur additional operating costs due to the accompanying hydraulic pressure loss. This study demonstrates that by thoughtful selection of the membrane properties and hydrodynamic conditions, the detrimental

The groundwater circulation in the Finnsjoe area - the impact of density gradients. Part A, B, C

International Nuclear Information System (INIS)

Ahlbom, K.; Svensson, U.

1991-11-01

Saline groundwater is found in many boreholes at the Finnsjoen site. The occurrences and depths to the saline water vary however greatly between different boreholes. This report presents a conceptual model which can explain most of these differences. The model is based on several assumptions. The background and relevance for using these assumptions are discussed and estimated depths to the interface between non-saline and saline groundwater, based on the conceptual model, are presented. (au)

Assessment of groundwater and soil quality degradation using multivariate and geostatistical analyses, Dakhla Oasis, Egypt

Science.gov (United States)

Masoud, Alaa A.; El-Horiny, Mohamed M.; Atwia, Mohamed G.; Gemail, Khaled S.; Koike, Katsuaki

2018-06-01

Salinization of groundwater and soil resources has long been a serious environmental hazard in arid regions. This study was conducted to investigate and document the factors controlling such salinization and their inter-relationships in the Dakhla Oasis (Egypt). To accomplish this, 60 groundwater samples and 31 soil samples were collected in February 2014. Factor analysis (FA) and hierarchical cluster analysis (HCA) were integrated with geostatistical analyses to characterize the chemical properties of groundwater and soil and their spatial patterns, identify the factors controlling the pattern variability, and clarify the salinization mechanism. Groundwater quality standards revealed emergence of salinization (av. 885.8 mg/L) and extreme occurrences of Fe2+ (av. 17.22 mg/L) and Mn2+ (av. 2.38 mg/L). Soils were highly salt-affected (av. 15.2 dS m-1) and slightly alkaline (av. pH = 7.7). Evaporation and ion-exchange processes governed the evolution of two main water types: Na-Cl (52%) and Ca-Mg-Cl (47%), respectively. Salinization leads the chemical variability of both resources. Distinctive patterns of slight salinization marked the northern part and intense salinization marked the middle and southern parts. Congruence in the resources clusters confirmed common geology, soil types, and urban and agricultural practices. Minimizing the environmental and socioeconomic impacts of the resources salinization urges the need for better understanding of the hydrochemical characteristics and prediction of quality changes.

Using environmental isotopes along with major hydro-geochemical compositions to assess deep groundwater formation and evolution in eastern coastal China

Science.gov (United States)

Xu, Naizheng; Gong, Jianshi; Yang, Guoqiang

2018-01-01

Hydrochemical analysis and environmental isotopic tracing are successfully applied to study groundwater evolution processes. Located in eastern China, the Jiangsu Coastal Plain is characterized by an extensively exploited deep groundwater system, and groundwater salinization has become the primary water environmental problem. This paper provides a case study on the use of a hydrochemical and environmental isotopic approach to assess possible mixing and evolution processes at Yoco Port, Jiangsu Province, China. Hydrochemical and isotopic patterns of deep groundwater allow one to distinguish different origins in deep water systems. HCO3- is the dominant anion in the freshwater samples, whereas Na+ and Cl- are the dominant major ions in the saline samples. According to δ18O, δ2H and 14C dating, the fresh water is derived from precipitation under a colder climate during the Glacial Maximum (Dali Glacial), while the saline groundwater is influenced by glacial-interglacial cycles during the Holocene Hypsithermal. The δ18O, δ2H and 3H data confirm that deep groundwater in some boreholes is mixed with overlying saline water. The deep groundwater reservoir can be divided into a saline water sector and a fresh water sector, and each show distinct hydrochemical and isotopic compositions. The saline groundwater found in the deep aquifer cannot be associated with present seawater intrusion. Since the Last Glacial Maximum in the Late Pleistocene, the deep groundwater flow system has evolved to its current status with the decrease in ice cover and the rising of sea level. However, the hydraulic connection is strengthened by continuous overexploitation, and deep groundwater is mixed with shallow groundwater at some points.

Hydrochemical analysis of groundwater using multivariate statistical methods - The Volta region, Ghana

Science.gov (United States)

Banoeng-Yakubo, B.; Yidana, S.M.; Nti, E.

2009-01-01

Q and R-mode multivariate statistical analyses were applied to groundwater chemical data from boreholes and wells in the northern section of the Volta region Ghana. The objective was to determine the processes that affect the hydrochemistry and the variation of these processes in space among the three main geological terrains: the Buem formation, Voltaian System and the Togo series that underlie the area. The analyses revealed three zones in the groundwater flow system: recharge, intermediate and discharge regions. All three zones are clearly different with respect to all the major chemical parameters, with concentrations increasing from the perceived recharge areas through the intermediate regions to the discharge areas. R-mode HCA and factor analysis (using varimax rotation and Kaiser Criterion) were then applied to determine the significant sources of variation in the hydrochemistry. This study finds that groundwater hydrochemistry in the area is controlled by the weathering of silicate and carbonate minerals, as well as the chemistry of infiltrating precipitation. This study finds that the ??D and ??18O data from the area fall along the Global Meteoric Water Line (GMWL). An equation of regression derived for the relationship between ??D and ??18O bears very close semblance to the equation which describes the GMWL. On the basis of this, groundwater in the study area is probably meteoric and fresh. The apparently low salinities and sodicities of the groundwater seem to support this interpretation. The suitability of groundwater for domestic and irrigation purposes is related to its source, which determines its constitution. A plot of the sodium adsorption ratio (SAR) and salinity (EC) data on a semilog axis, suggests that groundwater serves good irrigation quality in the area. Sixty percent (60%), 20% and 20% of the 67 data points used in this study fall within the medium salinity - low sodicity (C2-S1), low salinity -low sodicity (C1-S1) and high salinity - low

Biogeochemical cycling of arsenic in coastal salinized aquifers: Evidence from sulfur isotope study

International Nuclear Information System (INIS)

Kao, Yu-Hsuan; Wang, Sheng-Wei; Liu, Chen-Wuing; Wang, Pei-Ling; Wang, Chung-Ho; Maji, Sanjoy Kumar

2011-01-01

Arsenic (As) contamination of groundwater, accompanied by critical salinization, occurs in the southwestern coastal area of Taiwan. Statistical analyses and geochemical calculations indicate that a possible source of aqueous arsenic is the reductive dissolution of As-bearing iron oxyhydroxides. There are few reports of the influence of sulfate-sulfide redox cycling on arsenic mobility in brackish groundwater. We evaluated the contribution of sulfate reduction and sulfide re-oxidation on As enrichment using δ 34 S [SO 4 ] and δ 18 O [SO 4 ] sulfur isotopic analyses of groundwater. Fifty-three groundwater samples were divided into groups of high-As content and salinized (Type A), low-As and non-salinized (Type B), and high-As and non-salinized (Type C) groundwaters, based on hydro-geochemical analysis. The relatively high enrichment of 34 S [SO 4 ] and 18 O [SO 4 ] present in Type A, caused by microbial-mediated reduction of sulfate, and high 18 O enrichment factor (ε [SO 4 -H 2 O] ), suggests that sulfur disproportionation is an important process during the reductive dissolution of As-containing iron oxyhydroxides. Limited co-precipitation of ion-sulfide increased the rate of As liberation under anaerobic conditions. In contrast to this, Type B and Type C groundwater samples showed high δ 18 O [SO 4 ] and low δ 34 S [SO 4 ] values under mildly reducing conditions. Base on 18 O mass balance calculations, the oxide sources of sulfate are from infiltrated atmospheric O 2 , caused by additional recharge of dissolved oxygen and sulfide re-oxidation. The anthropogenic influence of extensive pumping also promotes atmospheric oxygen entry into aquifers, altering redox conditions, and increasing the rate of As release into groundwater. - Highlights: → Seawater intrusion and elevated As are the main issues of groundwater in Taiwan. → Sulfur and oxygen isotopes of sulfate were analyzed to evaluate the As mobility. → Reductive dissolution of Fe minerals and

Environmental isotope study of a groundwater supply project in the Kalahari of Gordonia

International Nuclear Information System (INIS)

Verhagen, B.T.

1984-01-01

A feasibility study for a central fresh groundwater supply scheme in the Kalahari of the Gordonia district, South Africa, provided the opportunity to study fresh and saline water occurrences in detail with environmental isotopes. The isotopic and chemical signals show a clear contrast among groundwaters below a river bed, an extended fresh groundwater body and saline groundwaters in close proximity to the river. Carbon-14, tritium and stable-isotope data lead to a vertical rain recharge model rather than a regional flow mechanism for an understanding of the various water occurrences, their interrelationships and varied hydrochemistry. (author)

Effects of groundwater withdrawals from the Hurricane Fault zone on discharge of saline water from Pah Tempe Springs, Washington County, Utah

Science.gov (United States)

Gardner, Philip M.

2018-04-10

Pah Tempe Springs, located in Washington County, Utah, contribute about 95,000 tons of dissolved solids annually along a 1,500-foot gaining reach of the Virgin River. The river gains more than 10 cubic feet per second along the reach as thermal, saline springwater discharges from dozens of orifices located along the riverbed and above the river on both banks. The spring complex discharges from fractured Permian Toroweap Limestone where the river crosses the north-south trending Hurricane Fault. The Bureau of Reclamation Colorado River Basin Salinity Control Program is evaluating the feasibility of capturing and desalinizing the discharge of Pah Tempe Springs to improve downstream water quality in the Virgin River. The most viable plan, identified by the Bureau of Reclamation in early studies, is to capture spring discharge by pumping thermal groundwater from within the Hurricane Fault footwall damage zone and to treat this water prior to returning it to the river.Three multiple-day interference tests were conducted between November 2013 and November 2014, wherein thermal groundwater was pumped from fractured carbonate rock in the fault damage zone at rates of up to 7 cubic feet per second. Pumping periods for these tests lasted approximately 66, 74, and 67 hours, respectively, and the tests occurred with controlled streamflows of approximately 2.0, 3.5, and 24.5 cubic feet per second, respectively, in the Virgin River upstream from the springs reach. Specific conductance, water temperature, and discharge were monitored continuously in the river (upstream and downstream of the springs reach) at selected individual springs, and in the pumping discharge during each of the tests. Water levels were monitored in three observation wells screened in the thermal system. Periodic stream and groundwater samples were analyzed for dissolved-solids concentration and the stable isotopes of oxygen and hydrogen. Additional discrete measurements of field parameters (specific

Groundwater geochemistry of Isla de Mona, Puerto Rico

Science.gov (United States)

Wicks, C.M.; Troester, J.W.

1998-01-01

In this study, we explore the differences between the hydrogeochemical processes observed in a setting that is open to input from the land surface and in a setting that is closed with respect to input from the land surface. The closed setting was a water-filled passage in a cave. Samples of groundwater and of a solid that appeared to be suspended in the relatively fresh region of saline-freshwater mixing zone were collected. The solid was determined to be aragonite. Based on the analyses of the composition and saturation state of the groundwater, the mixing of fresh and saline water and precipitation of aragonite are the controlling geochemical processes in this mixing zone. We found no evidence of sulfate reduction. Thus, this mixing zone is similar to that observed in Caleta Xel Ha, Quintana Roo, also a system that is closed with respect to input from the land surface. The open setting was an unconfined aquifer underlying the coastal plain along which four hand-dug wells are located. Two wells are at the downgradient ends of inferred flowpaths and one is along a flowpath. The composition of the groundwater in the downgradient wells is sulfide-rich and brackish. In contrast, at the well located along a flow line, the groundwater is oxygenated and brackish. All groundwater is oversaturated with respect to calcite, aragonite, and dolomite. The composition is attributed to mixing of fresh and saline groundwater, CO2 outgassing, and sulfate reduction. This mixing zone is geochemically similar to that observed in blue holes and cenotes.

Natural-analog studies for partial validation of conceptual models of radionuclide retardation at the Waste Isolation Pilot Plant (WIPP)

International Nuclear Information System (INIS)

Ward, D.B.; Brookins, D.G.

1990-01-01

Transport by groundwater within the Culebra Dolomite, an aquifer above the Waste Isolation Pilot Plant (WIPP), is the most probable mechanism for long-term release of radionuclides to the accessible environment. Radionuclides could be retarded by sorption if the groundwater is exposed to sufficient amounts of fracture-lining clays. In this natural-analog study, distributions of U and trace metals have been examined to constrain the strength of clay/solute interactions within the Culebra. Uranium solid/liquid distribution ratios, calculated from U concentrations of groundwaters and consanguineous fracture-filling clays, range from ∼80 to 800 m ell/g and imply retardation factors of 60 to 500 using a fracture-flow model. Retardation factors inferred from uranium-series disequilibria and 14 C ages in Culebra groundwaters alone are much lower (∼10), implying that clays may contain a significant unreactive component of U. Such a possibility is corroborated by Rb/Sr ages; these imply long-term stability of the clays,with resetting occurring more than 250 Ma ago. Factor analysis and mass-balance calculations suggest, however, that Mg-rich clays are dissolving in Pleistocene-age groundwaters and/or are converting to Na-rich smectites, and that B and Li are taken up from the water by the clays. Apparently, the solution chemistry reflects gradual equilibration of clays with groundwater, but thus far the bulk of the clays remain structurally intact. Measurements of the distribution of U in the Culebra will be more meaningful if the inert and exchangeable components of the U content of the clays can be quantified. 26 refs., 3 figs., 2 tabs

Geochemistry and environmental isotope of groundwater from the upper Cretaceous aquifer of Orontes basin (Syria)

International Nuclear Information System (INIS)

Al-Charideh, A.

2010-03-01

Chemical and environmental isotopes have been used for studying the Upper Cretaceous aquifer systems in the Middle Orontes basin. The results indicate that the salinity of groundwater (0.2 to 2 g/l) reveals the dissolution of evaporate rocks is the main factor of high salinity especially in the Homes depression. The degree of salinity and its spaces distribution are basically related to the pattern of groundwater movement in the Upper cretaceous aquifer. The stable isotopes composition of groundwater in the Homes depression are more depleted by -2.5% and -17.0% for δ 18 O and δ 2 H respectively, than the groundwater from Hama elevation, suggested different origin and recharge time between this two groundwater groups. Estimates of their mean subsurface residence times have been constrained on the basis of 14 C D IC. The corrected ages of groundwater are recent and less to 10 thousand years in Hama uplift. However, the corrected age of groundwater in the Homs depression range between 10 to 25 thousand years indicate late Pleistocene recharge period. (author)

The origin of groundwater salinity in granitic rocks: identification and characterisation of chloride sources; Origine de la salinite des eaux souterraines en milieu granitique: identification et caracterisation des sources de chlorure

Energy Technology Data Exchange (ETDEWEB)

Savoye, S.

1998-04-29

Hydrogeological research in crystalline rocks, developed either in geothermics or in feasibility studies for geological disposal of radioactive waste, points out a wide range of chloride contents in associated groundwaters. The aim of this dissertation is to identify the possible origins of chloride in groundwaters within different geological conditions. The three possible chloride reservoirs (chloride-bearing minerals, fluid inclusions, micro-porosity) located in rock have been characterised by studying samples from eight granitic sites with different technical approaches (electronic microbeam, alkaline fusion, micro-thermometry, crush-leaching, diffusion experiment). Firstly, this allows the definition of a new typology of the sites, by considering not only hydrogeological features but also occurrence of salt-rich fluid inclusions with sedimentary origin. Secondly, the use of tracers (such as Cl/Br ratio, {delta}{sup 37}Cl) and mass balance calculations shows that the contribution of fluid inclusions trapped in quartz and chloride-bearing minerals cannot account for the high salinity of groundwater. In this case, the chloride origin could be of sedimentary type. Chloride would be stored in micro-porosity and in fluid inclusions trapped in carbonates. Thirdly, we have pointed out the importance of micro-porosity, acting more as a sieve and a buffer than as a source. Finally, we have shown that the low salinity of groundwaters has not always an internal origin. (author) 187 refs.

Groundwater flow modelling at the Olkiluoto site, Finland

International Nuclear Information System (INIS)

Loefman, J.

1996-01-01

Preliminary site investigations for spent fuel disposal has been carried out at the Olkiluoto site, Finland. During the investigations high salt concentrations were measured in the groundwater samples deep in the bedrock. In this study, the groundwater flow is analyzed at Olkiluoto taking into account the effects of salinity. The transient simulations are performed by solving coupled and non-linear partial differential equations describing the flow and solute transport. A site-specific simulation model for flow and transport is developed on the basis of the field investigations. The simulations are carried out for a period that started when the highest hills at Olkiluoto rose above sea level. The simulation period continues until the present day. The results of the coupled simulations were strongly dependent on the poorly known initial salinity distribution in the solution domain. The DP approximation together with the EC approximation proved to be a useful complementary approach when simulating solute transport in a fractured rock mass. The simulations also confirm the assumption that the realistic simulation of groundwater flow at Olkiluoto requires taking into account the effects of salinity

Porewater salinity and the development of swelling pressure in bentonite-based buffer and backfill materials

Energy Technology Data Exchange (ETDEWEB)

Dixon, D.A. [Atomic Energy of Canada Limited (Canada)

2000-06-01

At the depths proposed for a nuclear fuel waste repository, it is likely that saline groundwater conditions will be encountered in the granitic rocks of Finland and Canada. The potential for saline groundwater to influence of the ability of bentonite-based buffer and backfilling materials to swell and thereby generate swelling pressure has been reviewed. Based on the data collected from existing literature, it would appear that porewater salinities as high as 100 g/l will not compromise the ability of confined, bentonite-based materials to develop a swelling pressure of at least 100 kPa on its confinement, provided the effective clay dry density (ECDD), exceeds approximately 0.9 Mg/m{sup 3}. At densities less than approximately 0.9 Mg/m{sup 3} the swelling pressure of bentonite-based materials may be reduced and become sensitive to salt concentration. The influence of porewater salinity on swelling pressure can be compared on the basis of the ECDD required to develop 100 kPa of swelling pressure. In order to generate 100 kPa of swelling pressure an ECDD of approximately 0.7 Mg/m{sup 3} is required to be present under fresh water or brackish porewater conditions. This density would need to be increased to approximately 0.9 Mg/m{sup 3} where the groundwater conditions were saline. The impact that groundwater salinity will have on density specifications for buffer and backfilling materials are discussed with reference to the nuclear fuel waste disposal concepts of Finland and Canada. (orig.)

A Geology-Based Estimate of Connate Water Salinity Distribution

Science.gov (United States)

2014-09-01

poses serious environmental concerns if connate water is mobilized into shallow aquifers or surface water systems. Estimating the distribution of...groundwater flow and salinity transport near the Herbert Hoover Dike (HHD) surrounding Lake Okeechobee in Florida . The simulations were conducted using the...on the geologic configuration at equilibrium, and the horizontal salinity distribution is strongly linked to aquifer connectivity because

Development, Testing, and Application of a Coupled Hydrodynamic Surface-Water/Groundwater Model (FTLOADDS) with Heat and Salinity Transport in the Ten Thousand Islands/Picayune Strand Restoration Project Area, Florida

Science.gov (United States)

Swain, Eric D.; Decker, Jeremy D.

2009-01-01

A numerical model application was developed for the coastal area inland of the Ten Thousand Islands (TTI) in southwestern Florida using the Flow and Transport in a Linked Overland/Aquifer Density-Dependent System (FTLOADDS) model. This model couples a two-dimensional dynamic surface-water model with a three-dimensional groundwater model, and has been applied to several locations in southern Florida. The model application solves equations for salt transport in groundwater and surface water, and also simulates surface-water temperature using a newly enhanced heat transport algorithm. One of the purposes of the TTI application is to simulate hydrologic factors that relate to habitat suitability for the West Indian Manatee. Both salinity and temperature have been shown to be important factors for manatee survival. The inland area of the TTI domain is the location of the Picayune Strand Restoration Project, which is designed to restore predevelopment hydrology through the filling and plugging of canals, construction of spreader channels, and the construction of levees and pump stations. The effects of these changes are simulated to determine their effects on manatee habitat. The TTI application utilizes a large amount of input data for both surface-water and groundwater flow simulations. These data include topography, frictional resistance, atmospheric data including rainfall and air temperature, aquifer properties, and boundary conditions for tidal levels, inflows, groundwater heads, and salinities. Calibration was achieved by adjusting the parameters having the largest uncertainty: surface-water inflows, the surface-water transport dispersion coefficient, and evapotranspiration. A sensitivity analysis did not indicate that further parameter changes would yield an overall improvement in simulation results. The agreement between field data from GPS-tracked manatees and TTI application results demonstrates that the model can predict the salinity and temperature

Groundwater flow and solute transport at the Mourquong saline-water disposal basin, Murray Basin, southeastern Australia

Science.gov (United States)

Simmons, Craig; Narayan, Kumar; Woods, Juliette; Herczeg, Andrew

2002-03-01

Saline groundwater and drainage effluent from irrigation are commonly stored in some 200 natural and artificial saline-water disposal basins throughout the Murray-Darling Basin of Australia. Their impact on underlying aquifers and the River Murray, one of Australia's major water supplies, is of serious concern. In one such scheme, saline groundwater is pumped into Lake Mourquong, a natural groundwater discharge complex. The disposal basin is hydrodynamically restricted by low-permeability lacustrine clays, but there are vulnerable areas in the southeast where the clay is apparently missing. The extent of vertical and lateral leakage of basin brines and the processes controlling their migration are examined using (1) analyses of chloride and stable isotopes of water (2H/1H and 18O/16O) to infer mixing between regional groundwater and lake water, and (2) the variable-density groundwater flow and solute-transport code SUTRA. Hydrochemical results indicate that evaporated disposal water has moved at least 100 m in an easterly direction and that there is negligible movement of brines in a southerly direction towards the River Murray. The model is used to consider various management scenarios. Salt-load movement to the River Murray was highest in a "worst-case" scenario with irrigation employed between the basin and the River Murray. Present-day operating conditions lead to little, if any, direct movement of brine from the basin into the river. Résumé. Les eaux souterraines salées et les effluents de drainage de l'irrigation sont stockés dans environ 200 bassins naturels ou artificiels destinés à retenir les eaux salines dans tout le bassin de Murray-Darling, en Australie. Leur impact sur les aquifères sous-jacents et sur la rivière Murray, l'une des principales ressources en eau d'Australie, constitue un problème grave. Dans une telle situation, les eaux souterraines salines sont pompées dans le lac Mourquong, complexe dans lequel les nappes se d

Overview of groundwater management approaches at salinisation risk

Science.gov (United States)

Polemio, Maurizio; Zuffianò, Livia Emanuela

2013-04-01

All natural waters contain dissolved minerals from interactions with atmospheric and soil gases, mixing with other solutions, and/or interactions with the biosphere and lithosphere. In many cases, these processes result in natural waters containing solute or salinity above concentrations recommended for a specified use, which creates significant social and economic problems. Groundwater salinisation can be caused by natural phenomena and anthropogenic activities. For the former case, we can distinguish terrestrial and marine phenomena. Approximately 16% of the total area of continental earth is potentially involved in groundwater salinisation. Seawater intrusion can be considered to be the primary phenomenon to be studied in terms of groundwater salinisation. Three schematic approaches to the protection of groundwater via salinisation mitigation and/or groundwater salinity improvement are described based on the classifications of the primary salinisation sources and focusing on the effect of seawater intrusion. The complexity of these approaches generally increases due to difficulties caused by groundwater quality and quantity degradation and increased demand for quality water. In order from the lowest to the highest complexity, these approaches are the engineering approach, the discharge management approach, and the water and land management approach. The engineering approach is realised on the local or detailed scale with the purpose of controlling the salinisation, optimising the well discharge with specific technical solutions and/or completing works to improve the quality and/or quantity of the discharged fresh groundwater. The discharge management approach encompasses at least an entire coastal aquifer and defines rules concerning groundwater utilisation and well discharge. The water and land management approach should be applied on the regional scale. Briefly, this approach becomes necessary when one or more need creates an overall framework of high

Groundwater Hydrochemical Zoning in Inland Plains and its Genetic Mechanisms

Directory of Open Access Journals (Sweden)

Liting Xing

2018-06-01

Full Text Available Pore water in inland plain areas, generally having poor water quality, contain complex hydrochemical properties. In order to examine groundwater chemical composition formation characteristics, groundwater in the Jiyang area of Lubei Plain was studied using stratified monitoring of drilling, analysis of water level and water quality, isotope analysis, ion ratio coefficient and isothermal adsorption experiments, hydrochemical characteristics, and analysis of variations in different shallow depths. Results show that: (1 Numerous hydrochemistry types are present in the diving. Along with the direction of groundwater flow, total dissolved solids (TDS of diving in the study area generally increases and the hydrochemical type changes from the HCO3 type to the HCO3·SO4 type, Cl·HCO3 type and the Cl·SO4 type. (2 Shallow brackish water and freshwater in the horizontal direction are alternately distributed, and shallow brackish water is distributed in the area between old channels, showing sporadic spots or bands, whose hydrochemistry type is predominantly Cl·SO4-Na·Mg·Ca. (3 Affected by the sedimentary environment, hydrodynamic conditions and other factors; diving, middle brackish water and deep freshwater are vertically deposited in the study area. The dynamics of middle brackish water quality are stable due to the sedimentary environment and clay deposits. The hydrochemistry types of middle brackish water are mainly Cl·SO4-Mg·Na and SO4·Cl-Na·Mg, while the deep confined water is dominated by HCO3. (4 The optimal adsorption isotherms of Na+, Ca2+ and Mg2+ in groundwater from clay, with a thickness raging from 6–112 m, conformed to the Henry equation and the Langmuir equation. The retardation of Na+, Ca2+ and Mg2+ in groundwater differed with differing depths of the clay deposit. The trend of change in retardation strength correlates strongly with the TDS of groundwater. Groundwater in the inland plain area is affected by complicated

Management of saline soils in Israel

International Nuclear Information System (INIS)

Rawitz, E.

1983-01-01

The main soil salinity problem in Israel is the danger of gradual salinization as a result of excessively efficient water management. Aquifer management is aimed at preventing flow of groundwater into the ocean, causing a creeping salinization at a rate of about 2 ppm per year. Successful efforts to improve irrigation efficiency brought with them the danger of salt accumulation in the soil. A ten-year monitoring programme carried out by the Irrigation Extension Service at 250 sampling sites showed that appreciable salt accumulation indeed occurred during the rainless irrigation season. However, where annual rainfall is more than about 350 mm this salt accumulation is adequately leached out of the root zone by the winter rains. Soil salinity in the autumn is typically two to three times that in the spring, a level which does not affect yields adversely. In the drier regions of the country long-term increasing soil salinity has been observed, and leaching is required. This is generally accomplished during the pre-irrigation given in the spring, whose size is determined by the rainfall amount of the preceding winter. The increasing need to utilize brackish groundwater and recycled sewage effluent requires special measures, which have so far been successful. In particular, drip irrigation with its high average soil-water potential regime and partial wetting of the soil volume has achieved high yields under adverse conditions. However, the long-term trend of water-quality deterioration is unavoidable under present conditions, and will eventually necessitate either major changes in agricultural patterns or the provision of desalinated water for dilution of the irrigation water. (author)

Hydrochemical Characteristics and Formation of the Saline or Salty Springs in Eastern Sichuan Basin of China

Science.gov (United States)

Zhou, X.

2017-12-01

Saline or salty springs provide important information on the hydrogeochemical processes and hydrology within subsurface aquifers. More than 20 saline and salty springs occur in the core of anticlines in the eastern Sichuan Basin in southwestern China where the Lower and Middle Triassic carbonates outcrop. Water samples of 8 saline and salty springs (including one saline hot spring) were collected for analyses of the major and minor constituents, trace elements and stable oxygen and hydrogen isotopes. The TDS of the springs range from 4 to 83 g/L, and they are mainly of Cl-Na type. Sr, Ba and Li are the predominant trace elements. The δ2H and δ18O of the water samples indicate that they are of meteoric origin. The source of salinity of the springs originates from dissolution of minerals in the carbonates, including halite, gypsum, calcite and dolomite. The formation mechanism of the springs is that groundwater receives recharge from infiltration of precipitation, undergoes shallow or deep circulation in the core of the anticline and incongruent dissolution of the salt-bearing carbonates occurs, and emerges in the river valley in the form of springs with relatively high TDS. The 8 springs can be classified into 4 springs of shallow groundwater circulation and 4 springs of deep groundwater circulation according to the depth of groundwater circulation, 7 springs of normal temperature and 1 hot spring according to temperature. There are also 2 up-flow springs: the carbonate aquifers are overlain by relatively impervious sandstone and shale, groundwater may flows up to the ground surface through the local portion of the overlying aquiclude where fractures were relatively well developed, and emerges as an up-flow spring. Knowledge of the hydrochemical characteristics and the geneses of the saline and salty springs are of important significance for the utilization and preservation of the springs.

Submarine groundwater discharge within a landslide scar at the French Mediterranean coast

NARCIS (Netherlands)

Oehler, Till; Mogollón, José M.; Moosdorf, Nils; Winkler, Andreas; Kopf, Achim; Pichler, Thomas

2017-01-01

Submarine groundwater discharge (SGD), the flow of fresh and saline groundwater from the seabed into the coastal ocean, has been intensively investigated in the recent years. This research has usually been restricted to shallow water and intertidal areas, whereas knowledge about groundwater seepage

Evaluation of the fast orthogonal search method for forecasting chloride levels in the Deltona groundwater supply (Florida, USA)

Science.gov (United States)

El-Jaat, Majda; Hulley, Michael; Tétreault, Michel

2018-02-01

Despite the broad impact and importance of saltwater intrusion in coastal aquifers, little research has been directed towards forecasting saltwater intrusion in areas where the source of saltwater is uncertain. Saline contamination in inland groundwater supplies is a concern for numerous communities in the southern US including the city of Deltona, Florida. Furthermore, conventional numerical tools for forecasting saltwater contamination are heavily dependent on reliable characterization of the physical characteristics of underlying aquifers, information that is often absent or challenging to obtain. To overcome these limitations, a reliable alternative data-driven model for forecasting salinity in a groundwater supply was developed for Deltona using the fast orthogonal search (FOS) method. FOS was applied on monthly water-demand data and corresponding chloride concentrations at water supply wells. Groundwater salinity measurements from Deltona water supply wells were applied to evaluate the forecasting capability and accuracy of the FOS model. Accurate and reliable groundwater salinity forecasting is necessary to support effective and sustainable coastal-water resource planning and management. The available (27) water supply wells for Deltona were randomly split into three test groups for the purposes of FOS model development and performance assessment. Based on four performance indices (RMSE, RSR, NSEC, and R), the FOS model proved to be a reliable and robust forecaster of groundwater salinity. FOS is relatively inexpensive to apply, is not based on rigorous physical characterization of the water supply aquifer, and yields reliable estimates of groundwater salinity in active water supply wells.

Performance Limiting Effects in Power Generation from Salinity Gradients by Pressure Retarded Osmosis

KAUST Repository

Yip, Ngai Yin; Elimelech, Menachem

2011-01-01

Pressure retarded osmosis has the potential to utilize the free energy of mixing when fresh river water flows into the sea for clean and renewable power generation. Here, we present a systematic investigation of the performance limiting phenomena

The immigration model and its implications of natural radionuclides of coastal groundwater in Xiamen

International Nuclear Information System (INIS)

Cai Minggang; Huang Yipu; Chen Min; Liu Guangshan

2004-01-01

from 14.0 to 333.0, with the average value of 177.8, almost two orders higher than that of P r,Rn-222 /A Rn-222 , while α-recoil supply rate (P r )from the aquifer rocks of both nuclides are within the same order. This shows that retardation of different nuclides by groundwater are differ greatly: α-recoil supply rate of 224 Ra by aquifers rock is much faster than other radionuclides in Xiamen costal groundwater, revealing aquifers rock have strong retardation on radium isotopes, while the immigration scale of 222 Rn is longer than radium isotopes in groundwater. This model enable us to estimate the retardation factor of radium isotopes (R f, Ra ) in groundwater, which ranges from 0.04 x 10 3 to 2.19 x 10 3 , with average value 0.8 x 10 3 . Retardation factor of radium in groundwater decrease from land to sea, while its liveliness extent increase gradually, which result in the decreasing of 222 Rn of groundwater in a certain degree. Calculation by this mass balance model also showed that, 224 Ra/ 228 Ra ) a.r. of groundwater are mainly controlled by this two factors: α-recoil in aquifer solid pool and retardation by rocks. The relative contribution of the former declined seaward, and the extent of retardation also weaken gradually. It is concluded that from land to sea, the co-operation of this two effect make 224 Ra/ 228 Ra)a.r. increase gradually. (authors)

The immigration model and its implications of natural radionuclides of coastal groundwater in Xiamen

International Nuclear Information System (INIS)

Cai Minggang; Huang Yipu; Chen Min; Liu Guangshan

2005-01-01

ranges from 14.0 to 333.0, with the average value of 177.8, almost two orders higher than that of P r,Rn-222 /A Rn-222 , while α-recoil supply rate (P r ) from the aquifer rocks of both nuclides are within the same order. This shows that retardation of different nuclides by groundwater are differ greatly: α-recoil supply rate of 224 Ra by aquifers rock is much faster than other radionuclides in Xiamen costal groundwater, revealing aquifers rock have strong retardation on radium isotopes, while the immigration scale of 222 Rn is longer than radium isotopes in groundwater. This model enable us to estimate the retardation factor of radium isotopes (R f,Ra ) in groundwater, which ranges from 0.04 x 10 3 to 2.19 x 10 3 , with average value 0.8 x 10 3 . Retardation factor of radium in groundwater decrease from land to sea, while its liveliness extent increase gradually, which result in the decreasing of 222 Rn of groundwater in a certain degree. Calculation by this mass balance model also showed that, 224 Ra/ 228 Ra) a.r. of groundwater are mainly controlled by this two factors: α-recoil in aquifer solid pool and retardation by rocks. The relative contribution of the former declined seaward, and the extent of retardation also weaken gradually. It is concluded that from land to sea, the co-operation of this two effect make 224 Ra/ 228 Ra)a.r. increase gradually.

A laboratory scale analysis of groundwater flow and salinity distribution in the Aespoe area

International Nuclear Information System (INIS)

Svensson, Urban

1999-12-01

This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author(s) and do not necessarily coincide with those of the client. The objective of the study is to develop, calibrate and apply a numerical simulation model of the Aespoe Hard Rock Laboratory (HRL). An area of 800 x 600 centred around the HRL, gives the horizontal extent of the model. In the vertical direction the model covers the depth interval from 200 to 560 metres. The model is based on a mathematical model that includes equations for the Darcy velocities, mass conservation and salinity distribution. Gravitational effects are thus fully accounted for. A site scale groundwater model was used to generate boundary conditions for all boundaries. Transmissivities of major fracture zones are based on field data. Fractures and fracture zones with a length scale between 5 and 320 metres are accounted for by a novel method that is based on a discrete fracture network. A small background conductivity is added to account for fractures smaller than the grid size, which is metres. A calibration of the model is carried out, using field data from the Aespoe HRL. A satisfactory agreement with field data is obtained. Main results from the model include vertical and horizontal sections of flow, salinity and hydraulic head distributions for completed tunnel. A sensitivity study, where the properties of the conductivity field are modified, is also carried out. The general conclusion of the study is that the model developed can simulate the conditions at the Aespoe HRL in a realistic manner

On the origins of hypersaline groundwater in the Nile Delta Aquifer

Science.gov (United States)

van Engelen, Joeri; Oude Essink, Gualbert H. P.; Kooi, Henk; Bierkens, Marc F. P.

2017-04-01

The fresh groundwater resources in the Nile Delta, Egypt, are of eminent socio-economic importance. These resources are under major stress due to population growth, the anticipated sea level rise and increased groundwater extraction rates, making fresh water availability the most challenging issue in this area. Up till now, numerous groundwater studies mainly focused on sea water intrusion on the top 100m of the groundwater system and assumed salinities not exceeding that of Mediterranean sea water, as there was no knowledge on groundwater in the deeper coastal parts of the Quaternary Nile Delta aquifer (that ranges up to 1000m depth). Recently, however, the Egyptian Research Institute for Groundwater (RIGW) collected salinity measurements and found a widespread occurrence of "hypersaline" groundwater: groundwater with salinities largely exceeding that of sea water at 600m depth (Nofal et al., 2015). This hypersaline groundwater greatly influences flow patterns and the fresh water potential of the aquifer. This research focuses on the origins of the hypersaline groundwater and the possible processes causing its transport. We consider all relevant salinization processes in the Nile Delta aquifer, over a time domain of up to 2.5 million years, which is the time span in which the aquifer got deposited. The following hypotheses were investigated with a combination of analytical solutions and numerical modelling: upward salt transport due to a) molecular diffusion, b) thermal buoyancy, c) consolidation-induced advection and dispersion, or downward transport due to d) composition buoyancy (salt inversion). We conclude that hypotheses a) and b) can be rejected, but c) and d) are both possible with the available information. An enhanced chemical analysis is suggested for further research, to determine the origins of this hypersaline water. This information in combination with the conclusions drawn in this research will give more insight in the potential amount of non

Marine water from mid-Holocene sea level highstand trapped in a coastal aquifer: Evidence from groundwater isotopes, and environmental significance

Energy Technology Data Exchange (ETDEWEB)

Lee, Stephen [School of Civil, Environmental and Chemical Engineering, RMIT University, Melbourne (Australia); Currell, Matthew, E-mail: Matthew.currell@rmit.edu.au [School of Civil, Environmental and Chemical Engineering, RMIT University, Melbourne (Australia); Cendón, Dioni I. [Australian Nuclear Science and Technology Organisation, Kirrawee (Australia); Connected Water Initiative, School of Biological, Earth and Environmental Sciences, University of New South Wales (UNSW), Sydney (Australia)

2016-02-15

A multi-layered coastal aquifer in southeast Australia was assessed using environmental isotopes, to identify the origins of salinity and its links to palaeo-environmental setting. Spatial distribution of groundwater salinity (electrical conductivity values ranging from 0.395 to 56.1 mS/cm) was examined along the coastline along with geological, isotopic and chemical data. This allowed assessment of different salinity sources and emplacement mechanisms. Molar chloride/bromide ratios range from 619 to 1070 (621 to 705 in samples with EC > 15 mS/cm), indicating salts are predominantly marine. Two distinct vertical salinity profiles were observed, one with increasing salinity with depth and another with saline shallow water overlying fresh groundwater. The saline shallow groundwater (EC = 45.4 to 55.7 mS/cm) has somewhat marine-like stable isotope ratios (δ{sup 18}O = − 2.4 to − 1.9 ‰) and radiocarbon activities indicative of middle Holocene emplacement (47.4 to 60.4 pMC). This overlies fresher groundwater with late Pleistocene radiocarbon ages and meteoric stable isotopes (δ{sup 18}O = − 5.5 to − 4.6‰). The configuration suggests surface inundation of the upper sediments by marine water during the mid-Holocene (c. 2–8 kyr BP), when sea level was 1–2 m above today's level. Profiles of chloride, stable isotopes, and radiocarbon indicate mixing between this pre-modern marine water and fresh meteoric groundwater to varying degrees around the coastline. Mixing calculations using chloride and stable isotopes show that in addition to fresh-marine water mixing, some salinity is derived from transpiration by halophytic vegetation (e.g. mangroves). The δ{sup 13}C ratios in saline water (− 17.6 to − 18.4‰) also have vegetation/organic matter signatures, consistent with emplacement by surface inundation and extensive interaction between vegetation and recharging groundwater. Saline shallow groundwater is preserved only in areas where low

Hydrogeochemistry and Stable Isotope Studies of Groundwater in the Ga West Municipal Area, Ghana

International Nuclear Information System (INIS)

Saka, David

2011-07-01

This study assesses groundwater in the Ga West Municipal Area of Ghana using hydrogeochemistry and stable isotope approaches. High salinity groundwaters are obtained in the municipality which poses problems for current and future domestic water supply exploitation. The increase in salinity is related to the dissolution of minerals in the host rocks and the evaporative concentration of solutes. The dominant groundwater composition in both shallow and deep wells sampled is Na-Cl, with concentration increasing substantially with well depths. The mixing process between freshwater and saline water was observed in the shift from CaHCO3 facies to Ca-Cl facies. Schoeller diagrams showed that groundwater movement in the study area is mostly vertical, moving from the shallow groundwaters towards the deep groundwaters. There were however few exceptions where no relationship was established between the shallow and the deep groundwaters. The oxygen and hydrogen isotope compositions in the groundwater samples suggest that groundwater recharge is of meteoric origin, with few samples showing evidence of evaporation. An average deuterium excess of rainfall of 14.2‰ was observed, which indicates the significance of kinetic evaporation due to low humidity conditions prevalent in the study area. The d-excess also indicates modern recharge along the Akwapim-Togo Ranges. Groundwater analysis for trace metals indicates that 93% of the groundwaters have Iron concentration above recommended limits. However, Cu, Zn, Pb, Cd and Cr have values within the acceptable limits. Generally, about 40% of the groundwaters sampled are not suitable for drinking and domestic purposes based on comparison with international standards for drinking water. (au)

Application of factor analysis and electrical resistivity to understand groundwater contributions to coastal embayments in semi-arid and hypersaline coastal settings

Energy Technology Data Exchange (ETDEWEB)

Bighash, Paniz, E-mail: Bighash.p@gmail.com; Murgulet, Dorina

2015-11-01

Groundwater contributions and sources of salinity to Oso Bay in south Texas were investigated using multivariate statistical analysis of geochemical data and multitemporal electrical resistivity tomography surveys. Both analysis of geochemical data and subsurface imaging techniques identified two commonalities for the investigated system: 1) hypersaline water occurs near the groundwater/surface water interface during wet conditions creating reverse hydraulic gradients due to density effects. The development and downward movement of these fluids as continuous plumes deflect fresher groundwater discharge downward and laterally away from the surface; and 2) more pronounced upwelling of fresher groundwater occurs during drought periods when density inversions are more defined and are expected to overcome dispersion and diffusion processes and create sufficiently large-enough unstable gradients that induce density-difference convection. Salinity mass-balance models derived from time-difference resistivity tomograph and in-situ salinity data reaffirm these findings indicating that groundwater upwelling is more prominent during dry to wet conditions in 2013 (~ 545.5 m{sup 3}/d) and is less pronounced during wet to dry conditions in 2012 (~ 262.7 m{sup 3}/d) for the 224 m{sup 2} area surveyed. Findings show that the highly saline nature of water in this area and changes in salinity regimes can be attributed to a combination of factors, namely: surface outflows, evapoconcentration, recirculation of hypersaline groundwaters, and potential trapped oil field brines. Increased drought conditions will likely exacerbate the rate at which salinity levels are increasing in bays and estuaries in semi-arid regions where both hypersaline groundwater discharge and high evaporation rates occur simultaneously. - Highlights: • Study of salinity regimes in relation to groundwater in a coastal semiarid setting • Factor analysis defined dominant factors influencing water quality

Application of factor analysis and electrical resistivity to understand groundwater contributions to coastal embayments in semi-arid and hypersaline coastal settings

International Nuclear Information System (INIS)

Bighash, Paniz; Murgulet, Dorina

2015-01-01

Groundwater contributions and sources of salinity to Oso Bay in south Texas were investigated using multivariate statistical analysis of geochemical data and multitemporal electrical resistivity tomography surveys. Both analysis of geochemical data and subsurface imaging techniques identified two commonalities for the investigated system: 1) hypersaline water occurs near the groundwater/surface water interface during wet conditions creating reverse hydraulic gradients due to density effects. The development and downward movement of these fluids as continuous plumes deflect fresher groundwater discharge downward and laterally away from the surface; and 2) more pronounced upwelling of fresher groundwater occurs during drought periods when density inversions are more defined and are expected to overcome dispersion and diffusion processes and create sufficiently large-enough unstable gradients that induce density-difference convection. Salinity mass-balance models derived from time-difference resistivity tomograph and in-situ salinity data reaffirm these findings indicating that groundwater upwelling is more prominent during dry to wet conditions in 2013 (~ 545.5 m 3 /d) and is less pronounced during wet to dry conditions in 2012 (~ 262.7 m 3 /d) for the 224 m 2 area surveyed. Findings show that the highly saline nature of water in this area and changes in salinity regimes can be attributed to a combination of factors, namely: surface outflows, evapoconcentration, recirculation of hypersaline groundwaters, and potential trapped oil field brines. Increased drought conditions will likely exacerbate the rate at which salinity levels are increasing in bays and estuaries in semi-arid regions where both hypersaline groundwater discharge and high evaporation rates occur simultaneously. - Highlights: • Study of salinity regimes in relation to groundwater in a coastal semiarid setting • Factor analysis defined dominant factors influencing water quality variations. �

Brackish groundwater in the United States

Science.gov (United States)

Stanton, Jennifer S.; Anning, David W.; Brown, Craig J.; Moore, Richard B.; McGuire, Virginia L.; Qi, Sharon L.; Harris, Alta C.; Dennehy, Kevin F.; McMahon, Peter B.; Degnan, James R.; Böhlke, John Karl

2017-04-05

For some parts of the Nation, large-scale development of groundwater has caused decreases in the amount of groundwater that is present in aquifer storage and that discharges to surface-water bodies. Water supply in some areas, particularly in arid and semiarid regions, is not adequate to meet demand, and severe drought is affecting large parts of the United States. Future water demand is projected to heighten the current stress on groundwater resources. This combination of factors has led to concerns about the availability of freshwater to meet domestic, agricultural, industrial, mining, and environmental needs. To ensure the water security of the Nation, currently [2016] untapped water sources may need to be developed.Brackish groundwater is an unconventional water source that may offer a partial solution to current and future water demands. In support of the national census of water resources, the U.S. Geological Survey completed the national brackish groundwater assessment to better understand the occurrence and characteristics of brackish groundwater in the United States as a potential water resource. Analyses completed as part of this assessment relied on previously collected data from multiple sources; no new data were collected. Compiled data included readily available information about groundwater chemistry, horizontal and vertical extents and hydrogeologic characteristics of principal aquifers (regionally extensive aquifers or aquifer systems that have the potential to be used as a source of potable water), and groundwater use. Although these data were obtained from a wide variety of sources, the compiled data are biased toward shallow and fresh groundwater resources; data representing groundwater that is at great depths and is saline were not as readily available.One of the most important contributions of this assessment is the creation of a database containing chemical characteristics and aquifer information for the known areas with brackish groundwater

Biogeochemical cycling of arsenic in coastal salinized aquifers: Evidence from sulfur isotope study

Energy Technology Data Exchange (ETDEWEB)

Kao, Yu-Hsuan [Department of Bioenvironmental Systems Engineering, National Taiwan University, Taipei 106, Taiwan, ROC (China); Wang, Sheng-Wei [Agricultural Engineering Research Center, Chungli 320, Taiwan, ROC (China); Liu, Chen-Wuing, E-mail: lcw@gwater.agec.ntu.edu.tw [Department of Bioenvironmental Systems Engineering, National Taiwan University, Taipei 106, Taiwan, ROC (China); Wang, Pei-Ling [Institute of Oceanography, National Taiwan University, Taipei 106, Taiwan, ROC (China); Wang, Chung-Ho [Institute of Earth Sciences, Academia Sinica, Taipei 115, Taiwan, ROC (China); Maji, Sanjoy Kumar [Department of Bioenvironmental Systems Engineering, National Taiwan University, Taipei 106, Taiwan, ROC (China)

2011-10-15

Arsenic (As) contamination of groundwater, accompanied by critical salinization, occurs in the southwestern coastal area of Taiwan. Statistical analyses and geochemical calculations indicate that a possible source of aqueous arsenic is the reductive dissolution of As-bearing iron oxyhydroxides. There are few reports of the influence of sulfate-sulfide redox cycling on arsenic mobility in brackish groundwater. We evaluated the contribution of sulfate reduction and sulfide re-oxidation on As enrichment using {delta}{sup 34}S{sub [SO{sub 4]}} and {delta}{sup 18}O{sub [SO{sub 4]}} sulfur isotopic analyses of groundwater. Fifty-three groundwater samples were divided into groups of high-As content and salinized (Type A), low-As and non-salinized (Type B), and high-As and non-salinized (Type C) groundwaters, based on hydro-geochemical analysis. The relatively high enrichment of {sup 34}S{sub [SO{sub 4]}} and {sup 18}O{sub [SO{sub 4]}} present in Type A, caused by microbial-mediated reduction of sulfate, and high {sup 18}O enrichment factor ({epsilon}{sub [SO{sub 4-H{sub 2O]}}}), suggests that sulfur disproportionation is an important process during the reductive dissolution of As-containing iron oxyhydroxides. Limited co-precipitation of ion-sulfide increased the rate of As liberation under anaerobic conditions. In contrast to this, Type B and Type C groundwater samples showed high {delta}{sup 18}O{sub [SO{sub 4]}} and low {delta}{sup 34}S{sub [SO{sub 4]}} values under mildly reducing conditions. Base on {sup 18}O mass balance calculations, the oxide sources of sulfate are from infiltrated atmospheric O{sub 2}, caused by additional recharge of dissolved oxygen and sulfide re-oxidation. The anthropogenic influence of extensive pumping also promotes atmospheric oxygen entry into aquifers, altering redox conditions, and increasing the rate of As release into groundwater. - Highlights: {yields} Seawater intrusion and elevated As are the main issues of groundwater in Taiwan

Drought-induced recharge promotes long-term storage of porewater salinity beneath a prairie wetland

Science.gov (United States)

Levy, Zeno F.; Rosenberry, Donald O.; Moucha, Robert; Mushet, David M.; Goldhaber, Martin B.; LaBaugh, James W.; Fiorentino, Anthony J.; Siegel, Donald I.

2018-02-01

Subsurface storage of sulfate salts allows closed-basin wetlands in the semiarid Prairie Pothole Region (PPR) of North America to maintain moderate surface water salinity (total dissolved solids [TDS] from 1 to 10 g L-1), which provides critical habitat for communities of aquatic biota. However, it is unclear how the salinity of wetland ponds will respond to a recent shift in mid-continental climate to wetter conditions. To understand better the mechanisms that control surface-subsurface salinity exchanges during regional dry-wet climate cycles, we made a detailed geoelectrical study of a closed-basin prairie wetland (P1 in the Cottonwood Lake Study Area, North Dakota) that is currently experiencing record wet conditions. We found saline lenses of sulfate-rich porewater (TDS > 10 g L-1) contained in fine-grained wetland sediments 2-4 m beneath the bathymetric low of the wetland and within the currently ponded area along the shoreline of a prior pond stand (c. 1983). During the most recent drought (1988-1993), the wetland switched from a groundwater discharge to recharge function, allowing salts dissolved in surface runoff to move into wetland sediments beneath the bathymetric low of the basin. However, groundwater levels during this time did not decline to the elevation of the saline lenses, suggesting these features formed during more extended paleo-droughts and are stable in the subsurface on at least centennial timescales. We hypothesize a "drought-induced recharge" mechanism that allows wetland ponds to maintain moderate salinity under semiarid climate. Discharge of drought-derived saline groundwater has the potential to increase the salinity of wetland ponds during wet climate.

Influence of irrigation on the level, salinity and flow of groundwater at ...

African Journals Online (AJOL)

2010-03-31

Mar 31, 2010 ... piezometers had to be measured, all readings were taken within 3 days. Water levels were measured to estab- lish the effect of rainfall, drainage and irrigation on the groundwater level. These levels were also used to gener- ate groundwater contour maps and to determine the groundwater flow directions.

Radionuclide transport and retardation in tuff

International Nuclear Information System (INIS)

Vine, E.N.; Bayhurst, B.P.; Daniels, W.R.; DeVilliers, S.J.; Erdal, B.R.; Lawrence, F.O.; Wolfsberg, K.

1980-01-01

Batch measurements provide an understanding of which experimental variables are important. For example, sorption ratios vary little with particle size (and surface area); however, groundwater composition and rock composition are quite important. A general correlation has been identified between mineralogy (major phases) and degree of sorption for strontium, cesium, and barium. Although these are approximate, a more detailed analysis may be possible as more samples are studied and the data base increased. Data from crushed tuff columns indicate that, except in simple cases where sorption coefficients are relatively low, and ion-exchange equilibria not only exist but are the dominant mechanism for removal of radioisotopes from solution, the simple relation between the sorption ratio R/sub d/ (or K/sub d/) and the relative velocity of radionuclides with respect to groundwater velocity may be insufficient to permit accurate modeling of the retardation of radionuclides. Additional work on whole core columns and larger blocks of intact material is required to better understand radionuclide sorption and transport through rock

Modelling souring in a high salinity reservoir

Energy Technology Data Exchange (ETDEWEB)

Adams, Michael; Crossland, Alan; Stott, Jim

2006-03-15

CAPCIS Ltd (Capcis) have developed a souring model for use in highly saline reservoirs where salinity limits the growth of sulphate reducing bacteria (SRB). Capcis have successfully applied the model to a field in North Africa. The conceptual basis of the model considers the course of the H2S from generation in the reservoir including dilution, sulphide retardation and scavenging and H2S fluid phase partitioning. At each stage mathematical equations governing the behaviour of the H2S were produced. In order to estimate the potential for H2S generation, it is required to know the chemistry of the injection and formation waters, as well as the properties of the indigenous SRB, i.e. the maximum salinity for their growth. This is determined by bottle testing of H2S generation by SRB at a range of injection/formation water ratios. The maximum salinity for SRB growth then determines the mixing ratios at which H2S generation takes place. Sulphide retardation due to adsorption at immobile interfaces was empirically modeled from reservoir data. Sulphide scavenging due to reaction with iron generated from corrosion was also modelled. Reservoir mineral scavenging was not modelled but could be incorporated in an extension to the model. Finally, in order to compute the gas-phase concentration of generated H2S, the H2S in the well stream is partitioned between the gas, oil and water phases. Capcis has carried out detailed computations of H2S solubility in crude oil and formation waters and the derivation of distribution ratios based on the respective partition coefficients using Gerard's line method, a modification of Henry's Law. (author) (tk)

Potential effects of alterations to the hydrologic system on the distribution of salinity in the Biscayne aquifer in Broward County, Florida

Science.gov (United States)

Hughes, Joseph D.; Sifuentes, Dorothy F.; White, Jeremy T.

2016-03-15

To address concerns about the effects of water-resource management practices and rising sea level on saltwater intrusion, the U.S. Geological Survey in cooperation with the Broward County Environmental Planning and Community Resilience Division, initiated a study to examine causes of saltwater intrusion and predict the effects of future alterations to the hydrologic system on salinity distribution in eastern Broward County, Florida. A three-dimensional, variable-density solute-transport model was calibrated to conditions from 1970 to 2012, the period for which data are most complete and reliable, and was used to simulate historical conditions from 1950 to 2012. These types of models are typically difficult to calibrate by matching to observed groundwater salinities because of spatial variability in aquifer properties that are unknown, and natural and anthropogenic processes that are complex and unknown; therefore, the primary goal was to reproduce major trends and locally generalized distributions of salinity in the Biscayne aquifer. The methods used in this study are relatively new, and results will provide transferable techniques for protecting groundwater resources and maximizing groundwater availability in coastal areas. The model was used to (1) evaluate the sensitivity of the salinity distribution in groundwater to sea-level rise and groundwater pumping, and (2) simulate the potential effects of increases in pumping, variable rates of sea-level rise, movement of a salinity control structure, and use of drainage recharge wells on the future distribution of salinity in the aquifer.

Depth-resolved phase retardation measurements for laser-assisted non-ablative cartilage reshaping

Energy Technology Data Exchange (ETDEWEB)

Youn, Jong-In [Beckman Laser Institute and Medical Clinic, University of California, Irvine, CA 92612 (United States); Vargas, Gracie [Center for Bioengineering, University of Texas Medical Branch, Galveston, TX 77555 (United States); Wong, Brian J F [Beckman Laser Institute and Medical Clinic, University of California, Irvine, CA 92612 (United States); Milner, Thomas E [Department of Biomedical Engineering, University of Texas at Austin, Austin, TX 78712 (United States)

2005-05-07

Since polarization-sensitive optical coherence tomography (PS-OCT) is emerging as a new technique for determining phase retardation in biological materials, we measured phase retardation changes in cartilage during local laser heating for application to laser-assisted cartilage reshaping. Thermally-induced changes in phase retardation of nasal septal cartilage following Nd:YAG laser irradiation were investigated using a PS-OCT system. A PS-OCT system and infrared imaging radiometer were used to record, respectively, depth-resolved images of the Stokes parameters of light backscattered from ex vivo porcine nasal septal cartilage and radiometric temperature changes following laser irradiation. PS-OCT images of cartilage were recorded before (control), during and after laser irradiation. From the measured Stokes parameters (I, Q, U and V), an estimate of the relative phase retardation between two orthogonal polarizations was computed to determine birefringence in cartilage. Phase retardation images of light backscattered from cartilage show significant changes in retardation following laser irradiation. To investigate the origin of retardation changes in response to local heat generation, we differentiated two possible mechanisms: dehydration and thermal denaturation. PS-OCT images of cartilage were recorded after dehydration in glycerol and thermal denaturation in heated physiological saline. In our experiments, observed retardation changes in cartilage are primarily due to dehydration. Since dehydration is a principal source for retardation changes in cartilage over the range of heating profiles investigated, our studies suggest that the use of PS-OCT as a feedback control methodology for non-ablative cartilage reshaping requires further investigation.

Depth-resolved phase retardation measurements for laser-assisted non-ablative cartilage reshaping

International Nuclear Information System (INIS)

Youn, Jong-In; Vargas, Gracie; Wong, Brian J F; Milner, Thomas E

2005-01-01

Since polarization-sensitive optical coherence tomography (PS-OCT) is emerging as a new technique for determining phase retardation in biological materials, we measured phase retardation changes in cartilage during local laser heating for application to laser-assisted cartilage reshaping. Thermally-induced changes in phase retardation of nasal septal cartilage following Nd:YAG laser irradiation were investigated using a PS-OCT system. A PS-OCT system and infrared imaging radiometer were used to record, respectively, depth-resolved images of the Stokes parameters of light backscattered from ex vivo porcine nasal septal cartilage and radiometric temperature changes following laser irradiation. PS-OCT images of cartilage were recorded before (control), during and after laser irradiation. From the measured Stokes parameters (I, Q, U and V), an estimate of the relative phase retardation between two orthogonal polarizations was computed to determine birefringence in cartilage. Phase retardation images of light backscattered from cartilage show significant changes in retardation following laser irradiation. To investigate the origin of retardation changes in response to local heat generation, we differentiated two possible mechanisms: dehydration and thermal denaturation. PS-OCT images of cartilage were recorded after dehydration in glycerol and thermal denaturation in heated physiological saline. In our experiments, observed retardation changes in cartilage are primarily due to dehydration. Since dehydration is a principal source for retardation changes in cartilage over the range of heating profiles investigated, our studies suggest that the use of PS-OCT as a feedback control methodology for non-ablative cartilage reshaping requires further investigation

On the incorrect derivation and use of in-situ retardation factors from natural isotope profiles

International Nuclear Information System (INIS)

McKinley, I.G.; Alexander, W.R.

1996-01-01

The characterization of the retardation of radionuclides during their transport by deep groundwaters is complex, time-consuming and, in many cases, inherently limited by technical problems. The stated goal of many natural analogue studies is thus the direct quantification of solute retardation in-situ in relevant geological environments. This paper reviews the claims for a methodology for determining in-situ retardation factors from a mathematical deconvolution of multiple radioisotope measurements of natural decay series elements. It is concluded that the assumptions involved in development of the mathematical approach are geochemically inconsistent and inapplicable to most geological systems of interest. Misapplications of this model are identified and the dangers of accepting its nonsensical output are discussed. (orig.)

Impact of Coastal Development and Marsh Width Variability on Groundwater Quality in Estuarine Tidal Creeks

Science.gov (United States)

Shanahan, M.; Wilson, A. M.; Smith, E. M.

2017-12-01

Coastal upland development has been shown to negatively impact surface water quality in tidal creeks in the southeastern US, but less is known about its impact on groundwater. We sampled groundwater in the upland and along the marsh perimeter of tidal creeks located within developed and undeveloped watersheds. Samples were analyzed for salinity, dissolved organic carbon, nitrogen and phosphorus concentrations. Groundwater samples collected from the upland in developed and undeveloped watersheds were compared to study the impact of development on groundwater entering the marsh. Groundwater samples collected along the marsh perimeter were analyzed to study the impact of marsh width variability on groundwater quality within each creek. Preliminary results suggest a positive correlation between salinity and marsh width in undeveloped watersheds, and a higher concentration of nutrients in developed versus undeveloped watersheds.

The value of iodide as a parameter in the chemical characterisation of groundwaters

Science.gov (United States)

Lloyd, J. W.; Howard, K. W. F.; Pacey, N. R.; Tellam, J. H.

1982-06-01

Brackish and saline groundwaters can severely constrain the use of fresh groundwaters. Their chemical characterisation is important in understanding the hydraulic conditions controlling their presence in an aquifer. Major ions are frequently of limited value but minor ions can be used. Iodide in groundwater is particularly significant in many environments due to the presence of soluble iodine in aquifer matrix materials. Iodide is found in groundwaters in parts of the English Chalk aquifer in concentrations higher than are present in modern seawater. Its presence is considered as a indication of groundwater residence and is of use in the characterisation of fresh as well as saline waters. Under certain circumstances modern seawater intrusion into aquifers along English estuaries produces groundwaters which are easily identified due to iodide enrichment from estuarine muds. In other environments iodide concentrations are of value in distinguishing between groundwaters in limestones and shaly gypsiferous rocks as shown by a study in Qatar, while in an alluvial aquifer study in Peru iodide has been used to identify groundwaters entering the aquifer from adjacent granodiorites.

Monitoring and Modelling of Salinity Behaviour in Drinking Water Ponds in Southern Bangladesh

Science.gov (United States)

Hoque, M. A.; Williams, A.; Mathewson, E.; Rahman, A. K. M. M.; Ahmed, K. M.; Scheelbeek, P. F. D.; Vineis, P.; Butler, A. P.

2015-12-01

Drinking water in southern Bangladesh is provided by a variety of sources including constructed storage ponds, seasonal rainwater and, ubiquitously saline, shallow groundwater. The ponds, the communal reservoirs for harvested rainwater, also tend to be saline, some as high as 2 g/l. Drinking water salinity has several health impacts including high blood pressure associated major risk factor for several cardio-vascular diseases. Two representative drinking water ponds in Dacope Upazila of Khulna District in southwest Bangladesh were monitored over two years for rainfall, evaporation, pond and groundwater level, abstraction, and solute concentration, to better understand the controls on drinking water salinity. Water level monitoring at both ponds shows groundwater levels predominantly below the pond level throughout the year implying a downward gradient. The grain size analysis of the underlying sediments gives an estimated hydraulic conductivity of 3E-8 m/s allowing limited seepage loss. Water balance modelling indicates that the seepage has a relatively minor effect on the pond level and that the bulk of the losses come from the combination of evaporation and abstraction particularly in dry season when precipitation, the only inflow to the pond, is close to zero. Seasonal variation in salinity (electrical conductivities, EC, ranged between 1500 to 3000 μS/cm) has been observed, and are primarily due to dilution from rainfall and concentration from evaporation, except on one occasion when EC reached 16,000 μS/cm due to a breach in the pond levee. This event was analogous to the episodic inundation that occurs from tropical cyclone storm surges and appears to indicate that such events are important for explaining the widespread salinisation of surface water and shallow groundwater bodies in coastal areas. A variety of adaptations (either from practical protection measures) or novel alternative drinking sources (such as aquifer storage and recovery) can be applied

Geochemical processes controlling water salinization in an irrigated basin in Spain: Identification of natural and anthropogenic influence

Energy Technology Data Exchange (ETDEWEB)

Merchán, D., E-mail: d.merchan@igme.es [Geological Survey of Spain — IGME, C/Manuel Lasala 44 9B, 50006 Zaragoza (Spain); Auqué, L.F.; Acero, P.; Gimeno, M.J. [University of Zaragoza — Department of Earth Sciences (Geochemical Modelling Group), C/Pedro Cerbuna 12, 50009 Zaragoza (Spain); Causapé, J. [Geological Survey of Spain — IGME, C/Manuel Lasala 44 9B, 50006 Zaragoza (Spain)

2015-01-01

Salinization of water bodies represents a significant risk in water systems. The salinization of waters in a small irrigated hydrological basin is studied herein through an integrated hydrogeochemical study including multivariate statistical analyses and geochemical modeling. The study zone has two well differentiated geologic materials: (i) Quaternary sediments of low salinity and high permeability and (ii) Tertiary sediments of high salinity and very low permeability. In this work, soil samples were collected and leaching experiments conducted on them in the laboratory. In addition, water samples were collected from precipitation, irrigation, groundwater, spring and surface waters. The waters show an increase in salinity from precipitation and irrigation water to ground- and, finally, surface water. The enrichment in salinity is related to the dissolution of soluble mineral present mainly in the Tertiary materials. Cation exchange, precipitation of calcite and, probably, incongruent dissolution of dolomite, have been inferred from the hydrochemical data set. Multivariate statistical analysis provided information about the structure of the data, differentiating the group of surface waters from the groundwaters and the salinization from the nitrate pollution processes. The available information was included in geochemical models in which hypothesis of consistency and thermodynamic feasibility were checked. The assessment of the collected information pointed to a natural control on salinization processes in the Lerma Basin with minimal influence of anthropogenic factors. - Highlights: • Salinization in Lerma Basin was controlled by the dissolution of soluble salts. • Water salinization and nitrate pollution were found to be independent processes. • High NO{sub 3}, fresh groundwater evolved to lower NO{sub 3}, higher salinity surface water. • Inverse and direct geochemical modeling confirmed the hypotheses. • Salinization was a natural ongoing process

Combining geochemical tracers with geophysical tools to study groundwater quality in Mesilla Bolson of the semi-arid Rio Grande watershed

Science.gov (United States)

Ma, L.; Hiebing, M.; Garcia, S.; Szynkiewicz, A.; Doser, D. I.

2017-12-01

Mesilla Bolson is an important alluvial aquifer system of the semi-arid Rio Grande watershed in southern New Mexico and West Texas. It is one of the two major groundwater sources for the City of El Paso in Texas and provides about 30% of the region's domestic groundwater needs. Groundwater from Mesilla Bolson is also extensively used for agriculture irrigation in this region. However, high concentrations of total dissolved solids in some areas of this region significantly impact groundwater quality for the Rio Grande alluvial aquifer. For example, an increase in groundwater salinity is generally observed from north to south within the aquifer. Some previous researchers have suggested this salinity change is due to 1) runoff and recharge from agricultural activity; 2) natural upwelling of deeper brackish groundwater; and 3) water-rock interactions in the aquifer. To better study how agricultural and municipal practices contribute to increasing salinity, we sampled 50 wells of the Mesilla Bolson in 2015-2016 for uranium (234U/238U), strontium (87Sr/86Sr), boron (d11B), and sulfur (d34S) isotope compositions to characterize major salinity sources of groundwater. In addition, we applied a geophysical gravity survey to determine the possible influences of faults and other subsurface structures on groundwater quality in this region. Our multi-isotope results suggest that the groundwater resources of this alluvial aquifer have been already impacted by human activities and groundwater recharge to the alluvial aquifer is affected by surface processes such as i) the return flows from the Rio Grande surface water used for irrigation, ii) municipal discharges, and iii) irrigation with the reclaimed city water. However, natural upwelling is also probably responsible for the salinity increase near some fault areas, primarily due to water-rock interactions such as dissolution of evaporites within the deeper basin. In some areas of the Mesilla Bolson, fault systems act as conduits

Remote sensing for assessing the zone of benefit where deep drains improve productivity of land affected by shallow saline groundwater.

Science.gov (United States)

Kobryn, H T; Lantzke, R; Bell, R; Admiraal, R

2015-03-01

The installation of deep drains is an engineering approach to remediate land salinised by the influence of shallow groundwater. It is a costly treatment and its economic viability is, in part, dependent on the lateral extent to which the drain increases biological productivity by lowering water tables and soil salinity (referred to as the drains' zone of benefit). Such zones may be determined by assessing the biological productivity response of adjacent vegetation over time. We tested a multi-temporal satellite remote sensing method to analyse temporal and spatial changes in vegetation condition surrounding deep drainage sites at five locations in the Western Australian wheatbelt affected by dryland salinity-Morawa, Pithara, Beacon, Narembeen and Dumbleyung. Vegetation condition as a surrogate for biological productivity was assessed by Normalised Difference Vegetation Index (NDVI) during the peak growing season. Analysis was at the site scale within a 1000 m buffer zone from the drains. There was clear evidence of NDVI increasing with elevation, slope and distance from the drain. After accounting for elevation, slope and distance from the drain, there was a significant increase in NDVI across the five locations after installation of deep drains. Changes in NDVI after drainage were broadly consistent with measured changes at each site in groundwater levels after installation of the deep drains. However, this study assessed the lateral extent of benefit for biological productivity and gave a measure of the area of benefit along the entire length of the drain. The method demonstrated the utility of spring NDVI images for rapid and relatively simple assessment of the change in site condition after implementation of drainage, but approaches for further improvement of the procedure were identified. Copyright © 2014 Elsevier Ltd. All rights reserved.

Development of a Conductivity Sensor for Monitoring Groundwater Resources to Optimize Water Management in Smart City Environments.

Science.gov (United States)

Parra, Lorena; Sendra, Sandra; Lloret, Jaime; Bosch, Ignacio

2015-08-26

The main aim of smart cities is to achieve the sustainable use of resources. In order to make the correct use of resources, an accurate monitoring and management is needed. In some places, like underground aquifers, access for monitoring can be difficult, therefore the use of sensors can be a good solution. Groundwater is very important as a water resource. Just in the USA, aquifers represent the water source for 50% of the population. However, aquifers are endangered due to the contamination. One of the most important parameters to monitor in groundwater is the salinity, as high salinity levels indicate groundwater salinization. In this paper, we present a specific sensor for monitoring groundwater salinization. The sensor is able to measure the electric conductivity of water, which is directly related to the water salinization. The sensor, which is composed of two copper coils, measures the magnetic field alterations due to the presence of electric charges in the water. Different salinities of the water generate different alterations. Our sensor has undergone several tests in order to obtain a conductivity sensor with enough accuracy. First, several prototypes are tested and are compared with the purpose of choosing the best combination of coils. After the best prototype was selected, it was calibrated using up to 30 different samples. Our conductivity sensor presents an operational range from 0.585 mS/cm to 73.8 mS/cm, which is wide enough to cover the typical range of water salinities. With this work, we have demonstrated that it is feasible to measure water conductivity using solenoid coils and that this is a low cost application for groundwater monitoring.

Geophysical Characterization Of Groundwater in the Mangrove Lakes Region of Everglades National Park.

Science.gov (United States)

Kiflai, M. E.; Whitman, D.; Price, R.; Frankovich, T.; Allen, J.

2017-12-01

Everglades National Park has been adversely impacted by past human activities that altered freshwater flow through the system. The Comprehensive Everglades Restoration Plan (CERP) makes an effort to increase the flow of fresh water and modify the groundwater chemistry in Everglades National Park (ENP). This paper aims to present the changes in surface and ground water chemistry in response to CERP project. Electromagnetic (EM) surveys were conducted in Alligator Creek (West Lake) and McCormick Creek (Seven Palm) from 2013 to 2017. During the survey a GSSI Profiler EMP-400, multi- frequency Electromagnetic (EM) conductivity meter was deployed in a flat bottomed plastic kayak towed behind a motorized skiff. An inverse model of the data is performed by constraining the resistivity value of the surface water fixed. Then, the salinity of the groundwater is estimated by assuming a formation factor of 5. In the McCormick Creek system, between January 2016 and February 2017 the salinity of the groundwater shows a considerable decreases. In the northern end of Seven Palm, the salinity decreases from 3.64 PSU in 2016 to 2.5 PSU in 2017. In the southern end the salinity decreases from 8.05 PSU in 2016 to 3.05 in 2017. This demonstrates how the salinity of the groundwater increase from north to south and decreases yearly. Future work will integrate the EM data with DC resistivity measurements collected from a floating Schlumberger array.

Application of factor analysis and electrical resistivity to understand groundwater contributions to coastal embayments in semi-arid and hypersaline coastal settings.

Science.gov (United States)

Bighash, Paniz; Murgulet, Dorina

2015-11-01

Groundwater contributions and sources of salinity to Oso Bay in south Texas were investigated using multivariate statistical analysis of geochemical data and multitemporal electrical resistivity tomography surveys. Both analysis of geochemical data and subsurface imaging techniques identified two commonalities for the investigated system: 1) hypersaline water occurs near the groundwater/surface water interface during wet conditions creating reverse hydraulic gradients due to density effects. The development and downward movement of these fluids as continuous plumes deflect fresher groundwater discharge downward and laterally away from the surface; and 2) more pronounced upwelling of fresher groundwater occurs during drought periods when density inversions are more defined and are expected to overcome dispersion and diffusion processes and create sufficiently large-enough unstable gradients that induce density-difference convection. Salinity mass-balance models derived from time-difference resistivity tomograph and in-situ salinity data reaffirm these findings indicating that groundwater upwelling is more prominent during dry to wet conditions in 2013 (~545.5m(3)/d) and is less pronounced during wet to dry conditions in 2012 (~262.7 m(3)/d) for the 224 m(2) area surveyed. Findings show that the highly saline nature of water in this area and changes in salinity regimes can be attributed to a combination of factors, namely: surface outflows, evapoconcentration, recirculation of hypersaline groundwaters, and potential trapped oil field brines. Increased drought conditions will likely exacerbate the rate at which salinity levels are increasing in bays and estuaries in semi-arid regions where both hypersaline groundwater discharge and high evaporation rates occur simultaneously. Published by Elsevier B.V.

Management scenarios for the Jordan River salinity crisis

Science.gov (United States)

Farber, E.; Vengosh, A.; Gavrieli, I.; Marie, Amarisa; Bullen, T.D.; Mayer, B.; Holtzman, R.; Segal, M.; Shavit, U.

2005-01-01

Recent geochemical and hydrological findings show that the water quality of the base flow of the Lower Jordan River, between the Sea of Galilee and the Dead Sea, is dependent upon the ratio between surface water flow and groundwater discharge. Using water quality data, mass-balance calculations, and actual flow-rate measurements, possible management scenarios for the Lower Jordan River and their potential affects on its salinity are investigated. The predicted scenarios reveal that implementation of some elements of the Israel-Jordan peace treaty will have negative effects on the Jordan River water salinity. It is predicted that removal of sewage effluents dumped into the river (???13 MCM/a) will significantly reduce the river water's flow and increase the relative proportion of the saline groundwater flux into the river. Under this scenario, the Cl content of the river at its southern point (Abdalla Bridge) will rise to almost 7000 mg/L during the summer. In contrast, removal of all the saline water (16.5 MCM/a) that is artificially discharged into the Lower Jordan River will significantly reduce its Cl concentration, to levels of 650-2600 and 3000-3500 mg/L in the northern and southern areas of the Lower Jordan River, respectively. However, because the removal of either the sewage effluents or the saline water will decrease the river's discharge to a level that could potentially cause river desiccation during the summer months, other water sources must be allocated to preserve in-stream flow needs and hence the river's ecosystem. ?? 2005 Elsevier Ltd. All rights reserved.

Limits to the availability of groundwater in Africa

Science.gov (United States)

Edmunds, W. Mike

2012-06-01

shown, from numerous studies, to be almost entirely non-renewable, 'fossil' water, recharged under wetter early Holocene or late Pleistocene climates, prior to onset of a more arid climate around 4500 years BP (Edmunds et al 2004). Small amounts of modern recharge (for example in the Atlas Mountains or Tibesti) are insufficient to have an impact on the drawdown of distant well fields. It is critical, therefore, to base resource estimates for any development on knowledge of the locally renewable amounts from rainfall and to consider mining palaeo-reserves only as a last resort. Hydrogeological techniques are available to quantify modern recharge (Scanlon and Cook 2002, Scanlon et al 2006) and rates can vary widely according to rock type and landscape; reliance on modelled estimates alone could be misleading. Water quality is also a limiting factor in quantifying usable fresh groundwater storage. In addition to the regional or local problems caused by fluoride, in areas of East and West Africa (MacDonald et al 2012), salinity, above all, will restrict the total usable storage for domestic use and food production, most notably in semi-arid or arid areas. Groundwater salinity arises from various sources, including lithologies containing evaporite minerals, residual sea water (especially in continental coastal margins) and evapotranspiration. As a general rule, salinity increases with depth (older waters tend to more saline), but an additional problem arises where salinity has built up due to aridification over several millennia. Playas and sebkhats are surface expressions of this salinity accumulation from surface water or groundwater discharge, but clearance of native vegetation also increases recharge and leads to salinity increase (George et al 1997). Near-surface salt accumulation may be drawn down into cones of depression in areas of development. One of the largest artesian aquifers, the Continental Intercalaire of Algeria and Tunisia, has groundwater discharge with a

A Multi-Methodology for improving Adelaide's Groundwater Management

Science.gov (United States)

Batelaan, Okke; Banks, Eddie; Batlle-Aguilar, Jordi; Breciani, Etienne; Cook, Peter; Cranswick, Roger; Smith, Stan; Turnadge, Chris; Partington, Daniel; Post, Vincent; Pool Ramirez, Maria; Werner, Adrian; Xie, Yueqing; Yang, Yuting

2015-04-01

Groundwater is a strategic and vital resource in South Australia playing a crucial role in sustaining a healthy environment, as well as supporting industries and economic development. In the Adelaide metropolitan region ten different aquifer units have been identified, extending to more than 500 m below sea level. Although salinity within most of these aquifers is variable, water suitable for commercial, irrigation and/or potable use is predominantly found in the deeper Tertiary aquifers. Groundwater currently contributes only 9000 ML/yr of Adelaide's total water consumption of 216,000 ML, while in the Northern Adelaide Plains 17000 ML/yr is used. However, major industries, market gardeners, golf courses, and local councils are highly dependent on this resource. Despite recent rapid expansion in managed aquifer recharge, and the potential for increased extraction of groundwater, particularly for the commercial and irrigation supplies, little is known about the sources and ages of Adelaide's groundwater. The aim of this study is therefore to provide a robust conceptualisation of Adelaide's groundwater system. The study focuses on three important knowledge gaps: 1. Does groundwater flow from the Adelaide Hills into the sedimentary aquifers on the plains? 2. What is the potential for encroachment of seawater if groundwater extraction increases? 3. How isolated are the different aquifers, or does water leak from one to the other? A multi-tool approach has been used to improve the conceptual understanding of groundwater flow processes; including the installation of new groundwater monitoring wells from the hills to the coast, an extensive groundwater sampling campaign of new and existing groundwater wells for chemistry and environmental tracers analysis, and development of a regional scale numerical model rigorously tested under different scenario conditions. The model allows quantification of otherwise hardly quantifiable quantities such as flow across fault zones and

Review of risk from potential emerging contaminants in UK groundwater

OpenAIRE

Stuart, Marianne; Lapworth, Dan; Crane, Emily; Hart, Alwyn

2012-01-01

This paper provides a review of the types of emerging organic groundwater contaminants (EGCs) which are beginning to be found in the UK. EGCs are compounds being found in groundwater that were previously not detectable or known to be significant and can come from agricultural, urban and rural point sources. EGCs include nanomaterials, pesticides, pharmaceuticals, industrial compounds, personal care products, fragrances, water treatment by-products, flame retardants and surfactants, as well a...

Soil salinization in the agricultural lands of Rhodope District, northeastern Greece.

Science.gov (United States)

Pisinaras, V; Tsihrintzis, V A; Petalas, C; Ouzounis, K

2010-07-01

The objective of this study was to identify seasonal and spatial trends and soil salinization patterns in a part of Rhodope District irrigated land, northeastern Greece, located east of Vistonis Lagoon. The study area is irrigated from a coastal aquifer, where salt water intrusion occurs because of extensive groundwater withdrawals. Fourteen monitoring sites were established in harvest fields in the study area, where soil samples were collected. Electrical conductivity (ECe), pH, and ion concentrations were determined in the saturated paste extract of the soil samples in the laboratory using standard methods. A clear tendency was observed for ECe to increase from April to September, i.e., within the irrigation period, indicating the effect of saline groundwater to soil. In the last years, the change from moderately sensitive (e.g., corn) to moderately tolerant crops (e.g., cotton) in the south part of the study area indicates the impacts of soil salinity. The study proposes management methods to alleviate this problem.

Water quality analysis of groundwater in crystalline basement rocks, Northern Ghana

Science.gov (United States)

Anku, Y.S.; Banoeng-Yakubo, B.; Asiedu, D.K.; Yidana, S.M.

2009-01-01

Hydrochemical data are presented for groundwater samples, collected from fractured aquifers in parts of northern Ghana. The data was collected to assess the groundwater suitability for domestic and agricultural use. Results of the study reveal that the pH of the groundwater in the area is slightly acidic to slightly alkaline. The electrical conductivity values, total dissolved solids (TDS) values and calcium, magnesium and sodium concentrations in the groundwater are generally below the limit set by the WHO for potable water supply. On the basis of activity diagrams, groundwater from the fractured aquifers appears to be stable within the montmorillonite field, suggesting weathering of silicate minerals. An inverse distance weighting interpolator with a power of 2 was applied to the data points to produce prediction maps for nitrate and fluoride. The distribution maps show the presence of high nitrate concentrations (50-194??mg/l) in some of the boreholes in the western part of the study area indicating anthropogenic impact on the groundwater. Elevated fluoride level (1.5-4??mg/l), higher than the WHO allowable fluoride concentration of 1.5, is recorded in the groundwater underlying the northeastern part of the study area, more specifically Bongo and its surrounding communities of the Upper East region. Results of this study suggest that groundwater from the fractured aquifers in the area exhibit low sodicity-low salinity (S1-C1), low sodicity-medium salinity (S1-C2) characteristics [United States Salinity Laboratory (USSL) classification scheme]. All data points from this study plot within the 'Excellent to good' category on a Wilcox diagram. Groundwater in this area thus appears to provide irrigation water of excellent quality. The hydrochemical results indicate that, although nitrate and fluoride concentrations in some boreholes are high, the groundwater in the study area, based on the parameters analyzed, is chemically potable and suitable for domestic and

Simulating the effect of water management decisions on groundwater flow and quality in the Kyzylkum Irrigation Scheme, Kazakhstan

Science.gov (United States)

Naudascher, R. M.; Marti, B. S.; Siegfried, T.; Wolfgang, K.; Anselm, K.

2017-12-01

The Kyzylkum Irrigation Scheme lies north of the Chardara reservoir on the banks of the river Syr Darya in South Kazakhstan. It was designed as a model Scheme and developed to a size of 74'000 ha during Soviet times for rice and cotton production. However, since the 1990s only very limited funds were available for maintenance and as a result, problems like water logging and salinization of soils and groundwater are now omnipresent in the scheme. The aim of this study was to develop a numerical groundwater flow model for the region in Modflow and to evaluate the effect of various infrastructure investments on phreatic evaporation (a major driver for soil salinization). Decadal groundwater observation data from 2011 to 2015 were used to calibrate the annual model and to validate the monthly model. Scenarios simulated were (partial) lining of main and/or secondary and tertiary canal system, improvement of drainage via horizontal canals or pumps, combinations of these and a joint groundwater-surface-water use scenario. Although the annual average model is sufficient to evaluate the yearly water balance, the transient model is a prerequisite for analysing measures against water logging and salinization, both of which feature strong seasonality. The transient simulation shows that a combination of leakage reduction (lining of canals) and drainage improvement measures is needed to lower the groundwater levels enough to avoid phreatic evaporation. To save water, joint surface water and groundwater irrigation can be applied in areas where groundwater salinity is low enough but without proper lining of canals, it is not sufficient to mitigate the ongoing soil degradation due to salinization and water logging.

Factors controlling the evolution of groundwater dynamics and chemistry in the Senegal River Delta

Directory of Open Access Journals (Sweden)

Abdoul Aziz Gning

2017-04-01

New hydrological insights for the region: Results show that groundwater far away from rivers and outside irrigated plots has evolved from marine water to brines under the influence of evapotranspiration. Near rivers, salinity of groundwater is lower than seawater and groundwater mineralization seems to evolve in the direction of softening through cationic exchanges related to permanent contact with fresh water. Despite large volumes of water used for rice cultivation, groundwater does not show any real softening trend in the cultivated parcels. Results show that the mechanisms that contribute to repel salt water from the sediments correspond to a lateral flush near permanent surface water streams and not to vertical drainage and dilution with rainfall or irrigation water. It is however difficult to estimate the time required to come back to more favorable conditions of groundwater salinity.

Influence of groundwater composition on subsurface iron and arsenic removal

KAUST Repository

Moed, David H.; Van Halem, Doris; Verberk, J. Q J C; Amy, Gary L.; Van Dijk, Johannis C.

2012-01-01

Subsurface arsenic and iron removal (SAR/SIR) is a novel technology to remove arsenic, iron and other groundwater components by using the subsoil. This research project investigated the influence of the groundwater composition on subsurface treatment. In anoxic sand column experiments, with synthetic groundwater and virgin sand, it was found that several dissolved substances in groundwater compete for adsorption sites with arsenic and iron. The presence of 0.01 mmol L -1phosphate, 0.2 mmol L -1 silicate, and 1 mmol L -1 nitrate greatly reduced the efficiency of SAR, illustrating the vulnerability of this technology in diverse geochemical settings. SIR was not as sensitive to other inorganic groundwater compounds, though iron retardation was limited by 1.2 mmol L -1 calcium and 0.06 mmol L -1 manganese. © IWA Publishing 2012.

Influence of groundwater composition on subsurface iron and arsenic removal

KAUST Repository

Moed, David H.

2012-06-01

Subsurface arsenic and iron removal (SAR/SIR) is a novel technology to remove arsenic, iron and other groundwater components by using the subsoil. This research project investigated the influence of the groundwater composition on subsurface treatment. In anoxic sand column experiments, with synthetic groundwater and virgin sand, it was found that several dissolved substances in groundwater compete for adsorption sites with arsenic and iron. The presence of 0.01 mmol L -1phosphate, 0.2 mmol L -1 silicate, and 1 mmol L -1 nitrate greatly reduced the efficiency of SAR, illustrating the vulnerability of this technology in diverse geochemical settings. SIR was not as sensitive to other inorganic groundwater compounds, though iron retardation was limited by 1.2 mmol L -1 calcium and 0.06 mmol L -1 manganese. © IWA Publishing 2012.

Salinity Trends in the Upper Colorado River Basin Upstream From the Grand Valley Salinity Control Unit, Colorado, 1986-2003

Science.gov (United States)

Leib, Kenneth J.; Bauch, Nancy J.

2008-01-01

Salinity Control Unit was 10,700 tons/year. This accounts for approximately 27 percent of the decrease observed downstream from the Grand Valley Salinity Control Unit. Salinity loads were decreasing at the fastest rate (6,950 tons/year) in Region 4, which drains an area between the Colorado River at Cameo, Colorado (station CAMEO) and Colorado River above Glenwood Springs, Colorado (station GLEN) streamflow-gaging stations. Trends in salinity concentration and streamflow were tested at station CAMEO to determine if salinity concentration, streamflow, or both are controlling salinity loads upstream from the Grand Valley Salinity Control Unit. Trend tests of individual ion concentrations were included as potential indicators of what sources (based on mineral composition) may be controlling trends in the upper Colorado. No significant trend was detected for streamflow from 1986 to 2003 at station CAMEO; however, a significant downward trend was detected for salinity concentration. The trend slope indicates that salinity concentration is decreasing at a median rate of about 3.54 milligrams per liter per year. Five major ions (calcium, magnesium, sodium, sulfate, and chloride) were tested for trends. The results indicate that processes within source areas with rock and soil types (or other unidentified sources) bearing calcium, sodium, and sulfate had the largest effect on the downward trend in salinity load upstream from station CAMEO. Downward trends in salinity load resulting from ground-water sources and/or land-use change were thought to be possible reasons for the observed decreases in salinity loads; however, the cause or causes of the decreasing salinity loads are not fully understood. A reduction in the amount of ground-water percolation from Region 4 (resulting from work done through Federal irrigation system improvement programs as well as privately funded irrigation system improvements) has helped reduce annual salinity load from Region 4 by approxima

Emerging organic contaminants in groundwater

OpenAIRE

Stuart, Marianne; Lapworth, Dan

2013-01-01

Emerging organic contaminants (ECs) are compounds now being found in groundwater from agricultural, urban sources that were previously not detectable, or thought to be significant. ECs include pesticides and degradates, pharmaceuticals, industrial compounds, personal care products, fragrances, water treatment by-products, flame retardants and surfactants, as well as ‘life-style’ compounds such as caffeine and nicotine. ECs may have adverse effects on aquatic ecosystems and human health. Freq...

Rational Exploitation and Utilizing of Groundwater in Jiangsu Coastal Area

Science.gov (United States)

Kang, B.; Lin, X.

2017-12-01

Jiangsu coastal area is located in the southeast coast of China, where is a new industrial base and an important coastal and Land Resources Development Zone of China. In the areas with strong human exploitation activities, regional groundwater evolution is obviously affected by human activities. In order to solve the environmental geological problems caused by groundwater exploitation fundamentally, we must find out the forming conditions of regional groundwater hydrodynamic field, and the impact of human activities on groundwater hydrodynamic field evolution and hydrogeochemical evolition. Based on these results, scientific management and reasonable exploitation of the regional groundwater resources can be provided for the utilization. Taking the coastal area of Jiangsu as the research area, we investigate and analyze of the regional hydrogeological conditions. The numerical simulation model of groundwater flow was established according to the water power, chemical and isotopic methods, the conditions of water flow and the influence of hydrodynamic field on the water chemical field. We predict the evolution of regional groundwater dynamics under the influence of human activities and climate change and evaluate the influence of groundwater dynamic field evolution on the environmental geological problems caused by groundwater exploitation under various conditions. We get the following conclusions: Three groundwater exploitation optimal schemes were established. The groundwater salinization was taken as the primary control condition. The substitution model was proposed to model groundwater exploitation and water level changes by BP network method.Then genetic algorithm was used to solve the optimization solution. Three groundwater exploitation optimal schemes were submit to local water resource management. The first sheme was used to solve the groundwater salinization problem. The second sheme focused on dual water supply. The third sheme concerned on emergency water

The influence of fish ponds and salinization on groundwater quality in the multi-layer coastal aquifer system in Israel

Science.gov (United States)

Tal, A.; Weinstein, Y.; Yechieli, Y.; Borisover, M.

2017-08-01

This study focuses on the impact of surface reservoirs (fish ponds) on a multi aquifer coastal system, and the relation between the aquifer and the sea. The study was conducted in an Israeli Mediterranean coastal aquifer, which includes a sandy phreatic unit and two confined calcareous sandstone units. The geological description is based on 52 wells, from which 33 samples were collected for stable isotope analysis and 25 samples for organic and inorganic parameters. Hydraulic head and chemical measurements suggest that there is an hydraulic connection between the fish ponds above the aquifer and the phreatic unit, whereas the connection with the confined units is very limited. The phreatic unit is characterized by a low concentration of oxygen and high concentrations of ammonium and phosphate, while the confined units are characterized by higher oxygen and much lower ammonium and phosphate concentrations. Organic matter fluorescence was found to be a tool to distinguish the contribution of the pond waters, whereby a pond water signature (characterized by proteinaceous (tryptophan-like) and typical humic-matter fluorescence) was found in the phreatic aquifer. The phreatic unit is also isotopically enriched, similar to pond waters, with δ18O of -1‰ and δD of -4.6‰, indicating enhanced evaporation of the pond water before infiltration, whereas there is a depleted isotopic composition in the confined units (δ18O = -4.3‰, δD = -20.4‰), which are also OM-poor. The Phreeqc model was used for quantitative calculation of the effect of pond losses on the different units. The Dissolved Inorganic Nitrogen (DIN) in the upper unit increases downstream from the ponds toward the sea, probably due to organic matter degradation, suggesting contribution of DIN from shallow groundwater flow to the sea. 87Sr/86Sr and Mg/Ca in the brackish and saline groundwater of the lower confined units increase toward seawater value, suggesting that the salinization process in the region

Using the SIMGRO regional hydrological model to evaluate salinity control measures in an irrigation area

NARCIS (Netherlands)

Kupper, E.; Querner, E.P.; Morábito, J.A.; Menenti, M.

2002-01-01

In irrigated areas with drainage and an important interaction with the groundwater system, it is often difficult to predict effects of measures to control salinity. Therefore, in order to evaluate measures to control salinity the SIMGRO integrated regional hydrological model was extended with a

Dissolution rate of alpha-doped UO2 in natural groundwater

International Nuclear Information System (INIS)

Ollila, Kaija; Myllykylä, Emmi; Tanhua-Tyrkkö, Merja; Lavonen, Tiina

2013-01-01

The objective of this work is to determine whether the presence of trace elements in natural groundwaters affects the dissolution rate of uranium dioxide in the presence of alpha radiation that causes radiolysis of water. The study is a part of the project Reducing Uncertainty in Performance Prediction (REDUPP) under the Seventh Framework Programme of the European Atomic Energy Community (EURATOM). The project aims to reduce uncertainties related to the extrapolation of the results of laboratory experiments to the conditions expected under geologic disposal. Thus far, synthetic groundwater has been normally used in the experiments. The synthetic groundwaters used do not contain all of the chemical elements that occur in natural groundwaters. Three natural groundwaters were chosen for the dissolution experiments with 0%, 5%, and 10% 233 U-doped UO 2 samples. These include a brackish groundwater, a saline groundwater and a low ionic strength groundwater. At the time of writing this paper, the dissolution experiments have been finished in the first groundwater, which was a moderately saline, brackish groundwater. The groundwater samples for the experiments were taken from a borehole in the Olkiluoto site in Finland. The measurements for dissolution rates were conducted under reducing conditions established using metallic iron in solution and an argon atmosphere in the glove box. The isotope dilution method was used to decrease uncertainties due to precipitation and sorption effects. The resulting dissolution rates in OL-KR6 natural groundwater were generally somewhat higher than the rates measured previously in synthetic groundwaters under similar redox conditions. No clear effect of alpha radiolysis could be seen for tests with lower SA/V, while those for higher SA/V indicated that the dissolution rate was higher for the 10% 233 U-doped UO 2 , suggesting the effect of alpha radiolysis under these conditions

Effects of environmental conditions on soil salinity and arid region in Tunisia

International Nuclear Information System (INIS)

Ben Ahmed, C.; Ben Rouina, B.; Boukhris, M.

2009-01-01

The shortage of water resources of good water quality is becoming an issue in the arid and semi arid regions. for this reason, the use of water resources of marginal quality such as treated wastewater and saline groundwater has become and important consideration, particularly in arid region in Tunisia, where large quantities of saline water are used for irrigation. (Author)

Hydrogeochemical characterization and groundwater quality assessment in intruded coastal brine aquifers (Laizhou Bay, China).

Science.gov (United States)

Zhang, Xiaoying; Miao, Jinjie; Hu, Bill X; Liu, Hongwei; Zhang, Hanxiong; Ma, Zhen

2017-09-01

The aquifer in the coastal area of the Laizhou Bay is affected by salinization processes related to intense groundwater exploitation for brine resource and for agriculture irrigation during the last three decades. As a result, the dynamic balances among freshwater, brine, and seawater have been disturbed and the quality of groundwater has deteriorated. To fully understand the groundwater chemical distribution and evolution in the regional aquifers, hydrogeochemical and isotopic studies have been conducted based on the water samples from 102 observation wells. Groundwater levels and salinities in four monitoring wells are as well measured to inspect the general groundwater flow and chemical patterns and seasonal variations. Chemical components such as Na + , K + , Ca 2+ , Mg 2+ , Sr 2+ , Cl - , SO 4 2- , HCO 3 - , NO 3 - , F - , and TDS during the same period are analyzed to explore geochemical evolution, water-rock interactions, sources of salt, nitrate, and fluoride pollution in fresh, brackish, saline, and brine waters. The decreased water levels without typical seasonal variation in the southeast of the study area confirm an over-exploitation of groundwater. The hydrogeochemical characteristics indicate fresh-saline-brine-saline transition pattern from inland to coast where evaporation is a vital factor to control the chemical evolution. The cation exchange processes are occurred at fresh-saline interfaces of mixtures along the hydraulic gradient. Meanwhile, isotopic data indicate that the brine in aquifers was either originated from older meteoric water with mineral dissolution and evaporation or repeatedly evaporation of retained seawater with fresher water recharge and mixing in geological time. Groundwater suitability for drinking is further evaluated according to water quality standard of China. Results reveal high risks of nitrate and fluoride contamination. The elevated nitrate concentration of 560 mg/L, which as high as 28 times of the standard content

Groundwater System of Sundarbans (Basanti), West Bengal, India

DEFF Research Database (Denmark)

Kopmann, Moritz; Binning, Philip John; Bregnhøj, Henrik

2018-01-01

In Basanti, a rural block in the Sundarbans, West Bengal, the water availability is vital for its inhabitants. Groundwater levels are decreasing, and a proper understanding of key factors influencing the water resource is required. In the following, a social review of Basanti is given followed...... by a geologic and hydrostratigraphic analysis. The main hydrologic flows, a water balance, and the trend of salinity in the groundwater are presented. Finally, available long- and short-term drawdown data of South 24 Parganas and Basanti to determine groundwater level and annual recharge trends. The assessment...

Impact of water diversion on the hydrogeochemical characterization of surface water and groundwater in the Yellow River Delta

International Nuclear Information System (INIS)

Liu, Qiang; Li, Fadong; Zhang, Qiuying; Li, Jing; Zhang, Yan; Tu, Chun; Ouyang, Zhu

2014-01-01

Highlights: • We assess the response of different ecosystems to the water diversion. • We characterized the interaction between surface water and groundwater. • We use the Piper and HFE-D to illustrate the salinization process. - Abstract: The Yellow River Delta is undergoing severe ecosystem degradation through salinization caused mainly by seawater intrusion. The Yellow River diversion project, in operation since 2008, aims to mitigate a projected ecosystem disaster. We conducted field investigations across three ecosystems (Farmland, Wetland and Coast) in the delta to assess the effectiveness of the annual water pulse and determine the relationships between surface water and groundwater. The chemical characteristics of the groundwater in Farmland exclude the possibility of seawater intrusion. The Wetland is vulnerable to pollution by groundwater discharge from Farmland and to secondary salinization caused by rising water tables. The salinity values of groundwater at Coast sites likely reflect the presence of seawater trapped in the clay sediments, a premise corroborated through measurements of groundwater levels, stable isotopes and major ion signatures. Our δD–δ 18 O two-dimensional graphic plot demonstrated that groundwaters of Farmland and Wetland changed toward more depleted isotopic compositions following water diversion, but this was not the case in the Coast sites, where the water table varied little year-round. A hydrochemical facies evolution diagram (HFE-D) demonstrated that freshening is taking place in the largest portions of the aquifers and that, without sustained water diversion recharge, these underground water bodies may switch from freshening to salinization on a seasonal time scale. Thus, the qualities of waters in coastal aquifers in the Yellow River Delta are substantially influenced by the process of ecological water diversion, and also by land use practices and by the lithological properties of the drainage landscape

Hydrochemical and multivariate analysis of groundwater quality in the northwest of Sinai, Egypt.

Science.gov (United States)

El-Shahat, M F; Sadek, M A; Salem, W M; Embaby, A A; Mohamed, F A

2017-08-01

The northwestern coast of Sinai is home to many economic activities and development programs, thus evaluation of the potentiality and vulnerability of water resources is important. The present work has been conducted on the groundwater resources of this area for describing the major features of groundwater quality and the principal factors that control salinity evolution. The major ionic content of 39 groundwater samples collected from the Quaternary aquifer shows high coefficients of variation reflecting asymmetry of aquifer recharge. The groundwater samples have been classified into four clusters (using hierarchical cluster analysis), these match the variety of total dissolvable solids, water types and ionic orders. The principal component analysis combined the ionic parameters of the studied groundwater samples into two principal components. The first represents about 56% of the whole sample variance reflecting a salinization due to evaporation, leaching, dissolution of marine salts and/or seawater intrusion. The second represents about 15.8% reflecting dilution with rain water and the El-Salam Canal. Most groundwater samples were not suitable for human consumption and about 41% are suitable for irrigation. However, all groundwater samples are suitable for cattle, about 69% and 15% are suitable for horses and poultry, respectively.

Ground-water flow and saline water in the shallow aquifer system of the southern watersheds of Virginia Beach, Virginia

Science.gov (United States)

Smith, Barry S.

2003-01-01

-Eastover aquifer compose the hydrogeologic units of the shallow aquifer system of Virginia Beach. The Columbia and Yorktown-Eastover aquifers are poorly confined throughout most of the southern watersheds of Virginia Beach. The freshwater-to-saline-water distribution probably is in a dynamic equilibrium throughout most of the shallow aquifer system. Freshwater flows continually down and away from the center of the higher altitudes to mix with saline water from the tidal rivers, bays, salt marshes, and the Atlantic Ocean. Fresh ground water from the Columbia aquifer also leaks down through the Yorktown confining unit into the upper half of the Yorktown-Eastover aquifer and flows within the Yorktown-Eastover above saline water in the lower half of the aquifer. Ground-water recharge is minimal in much of the southern watersheds because the land surface generally is low and flat.

Changes in hydrology and salinity accompanying a century of agricultural conversion in Argentina.

Science.gov (United States)

Jayawickreme, Dushmantha H; Santoni, Celina S; Kim, John H; Jobbágy, Esteban G; Jackson, Robert B

2011-10-01

Conversions of natural woodlands to agriculture can alter the hydrologic balance, aquifer recharge, and salinity of soils and groundwater in ways that influence productivity and sustainable land use. Using a land-use change chronosequence in semiarid woodlands of Argentina's Espinal province, we examined the distribution of moisture and solutes and estimated recharge rates on adjacent plots of native woodlands and rain-fed agriculture converted 6-90 years previously. Soil coring and geoelectrical profiling confirmed the presence of spatially extensive salt accumulations in dry woodlands and pervasive salt losses in areas converted to agriculture. A 1.1-km-long electrical resistivity transect traversing woodland, 70-year-old agriculture, and woodland, for instance, revealed a low-resistivity (high-salinity) horizon between approximately 3 m and 13 m depth in the woodlands that was virtually absent in the agricultural site because of leaching. Nine-meter-deep soil profiles indicated a 53% increase in soil water storage after 30 or more years of cultivation. Conservative groundwater-recharge estimates based on chloride tracer methods in agricultural plots ranged from approximately 12 to 45 mm/yr, a substantial increase from the led to >95% loss of sulfate and chloride ions from the shallow vadose zone in most agriculture plots. These losses correspond to over 100 Mg of sulfate and chloride salts potentially released to the region's groundwater aquifers through time with each hectare of deforestation, including a capacity to increase groundwater salinity to >4000 mg/L from these ions alone. Similarities between our findings and those of the dryland salinity problems of deforested woodlands in Australia suggest an important warning about the potential ecohydrological risks brought by the current wave of deforestation in the Espinal and other regions of South America and the world.

Mapping deep aquifer salinity trends in the southern San Joaquin Valley using borehole geophysical data constrained by chemical analyses

Science.gov (United States)

Gillespie, J.; Shimabukuro, D.; Stephens, M.; Chang, W. H.; Ball, L. B.; Everett, R.; Metzger, L.; Landon, M. K.

2016-12-01

The California State Water Resources Control Board and the California Division of Oil, Gas and Geothermal Resources are collaborating with the U.S. Geological Survey to map groundwater resources near oil fields and to assess potential interactions between oil and gas development and groundwater resources. Groundwater resources having salinity less than 10,000 mg/L total dissolved solids may be classified as Underground Sources of Drinking Water (USDW) and subject to protection under the federal Safe Drinking Water Act. In this study, we use information from oil well borehole geophysical logs, oilfield produced water and groundwater chemistry data, and three-dimensional geologic surfaces to map the spatial distribution of salinity in aquifers near oil fields. Salinity in the southern San Joaquin Valley is controlled primarily by depth and location. The base of protected waters occurs at very shallow depths, often 1,500 meters, in the eastern part of the San Joaquin Valley where higher runoff from the western slopes of the Sierra Nevada provide relatively abundant aquifer recharge. Stratigraphy acts as a secondary control on salinity within these broader areas. Formations deposited in non-marine environments are generally fresher than marine deposits. Layers isolated vertically between confining beds and cut off from recharge sources may be more saline than underlying aquifers that outcrop in upland areas on the edge of the valley with more direct connection to regional recharge areas. The role of faulting is more ambiguous. In some areas, abrupt changes in salinity may be fault controlled but, more commonly, the faults serve as traps separating oil-bearing strata that are exempt from USDW regulations, from water-bearing strata that are not exempt.

Use of a time-domain electromagnetic method with geochemical tracers to explore the salinity anomalies in a small coastal aquifer in north-eastern Tunisia

Science.gov (United States)

Chekirbane, Anis; Tsujimura, Maki; Kawachi, Atsushi; Lachaal, Fethi; Isoda, Hiroko; Tarhouni, Jamila

2014-12-01

The study area is a small coastal plain in north-eastern Tunisia. It is drained by an ephemeral stream network and is subject to several pollutant discharges such as oilfield brine coming from a neighboring oil company and wastewater from Somâa city, located in the upstream of the plain. Furthermore, a hydraulic head near the coastal part of the aquifer is below sea level, suggesting that seawater intrusion may occur. A time-domain electromagnetic (TDEM) survey, based on 28 soundings, was conducted in Wadi Al Ayn and Daroufa plains to delineate the saline groundwater. Based on longitudinal and transversal resistivity two-dimensional pseudosections calibrated with boring data, the extent of saline water was identified. Geochemical tracers were combined with the resistivity dataset to differentiate the origin of groundwater salinization. In the upstream part of the plain, the infiltration of oilfield brine through the sandy bed of Wadi Al Ayn seems to have a considerable effect on groundwater salinization. However, in the coastal part of the aquifer, groundwater salinization is due to seawater intrusion and the saltwater is reaching an inland extent around 1.3 km from the shoreline. The contribution ratios of saline water bodies derived from the inverted chloride data vary for the oilfield brine from 1 to 13 % and for the seawater from 2 to 21 %.

Application of groundwater sustainability indicators to the Upper Pliocene aquifer in Ho Chi Minh city, Viet Nam

Science.gov (United States)

Ngo, T. M.; Lee, J.; Lee, H.; Woo, N. C.

2013-12-01

Groundwater plays an importance role for domestic, industrial, and agricultural uses in Ho Chi Minh city, Viet Nam. This study is objected to evaluate the sustainability of groundwater by using groundwater sustainability indicators (GWSIs) defined by UNESCO/IAEA/IAH Working Group on Groundwater Indicators at aquifer scale (the Upper Pliocene aquifer). There are four main indicators selected and one new indicator designed for the particular characteristic of Ho Chi Minh city which is under influence of by saline-water intrusion. The results indicated groundwater of the Upper Pliocene aquifer, the main groundwater supply source, is generally in the unsustainable state. The abstraction of groundwater, which was much greater than its capability, is probably causing the serious state of annual groundwater depletion and saline-water intrusion. The GWSIs, which expressed in such a simple way but scientifically-based and policy-relevant, proved its usefulness in evaluating the sustainability of groundwater at the aquifer scale in Ho Chi Minh city, and subsequently should be incorporated in water resource management practices.

Atoll groundwater movement and its response to climatic and sea-level fluctuations

Science.gov (United States)

Oberle, Ferdinand; Swarzenski, Peter W.; Storlazzi, Curt

2017-01-01

Groundwater resources of low-lying atoll islands are threatened due to short-term and long-term changes in rainfall, wave climate, and sea level. A better understanding of how these forcings affect the limited groundwater resources was explored on Roi-Namur in the Republic of the Marshall Islands. As part of a 16-month study, a rarely recorded island-overwash event occurred and the island’s aquifer’s response was measured. The findings suggest that small-scale overwash events cause an increase in salinity of the freshwater lens that returns to pre-overwash conditions within one month. The overwash event is addressed in the context of climate-related local sea-level change, which suggests that overwash events and associated degradations in freshwater resources are likely to increase in severity in the future due to projected rises in sea level. Other forcings, such as severe rainfall events, were shown to have caused a sudden freshening of the aquifer, with salinity levels retuning to pre-rainfall levels within three months. Tidal forcing of the freshwater lens was observed in electrical resistivity profiles, high-resolution conductivity, groundwater-level well measurements and through submarine groundwater discharge calculations. Depth-specific geochemical pore water measurements further assessed and confirmed the distinct boundaries between fresh and saline water masses in the aquifer. The identification of the freshwater lens’ saline boundaries is essential for a quantitative evaluation of the aquifers freshwater resources and help understand how these resources may be impacted by climate change and anthropogenic activities.

Atoll Groundwater Movement and Its Response to Climatic and Sea-Level Fluctuations

Directory of Open Access Journals (Sweden)

Ferdinand K. J. Oberle

2017-08-01

Full Text Available Groundwater resources of low-lying atoll islands are threatened due to short-term and long-term changes in rainfall, wave climate, and sea level. A better understanding of how these forcings affect the limited groundwater resources was explored on Roi-Namur in the Republic of the Marshall Islands. As part of a 16-month study, a rarely recorded island-overwash event occurred and the island’s aquifer’s response was measured. The findings suggest that small-scale overwash events cause an increase in salinity of the freshwater lens that returns to pre-overwash conditions within one month. The overwash event is addressed in the context of climate-related local sea-level change, which suggests that overwash events and associated degradations in freshwater resources are likely to increase in severity in the future due to projected rises in sea level. Other forcings, such as severe rainfall events, were shown to have caused a sudden freshening of the aquifer, with salinity levels retuning to pre-rainfall levels within three months. Tidal forcing of the freshwater lens was observed in electrical resistivity profiles, high-resolution conductivity, groundwater-level well measurements and through submarine groundwater discharge calculations. Depth-specific geochemical pore water measurements further assessed and confirmed the distinct boundaries between fresh and saline water masses in the aquifer. The identification of the freshwater lens’ saline boundaries is essential for a quantitative evaluation of the aquifers freshwater resources and help understand how these resources may be impacted by climate change and anthropogenic activities.

The deep hydrogeologic flow system underlying the Oak Ridge Reservation - Assessing the potential for active groundwater flow and origin of the brine

International Nuclear Information System (INIS)

Nativ, R.; Halleran, A.; Hunley, A.

1997-08-01

The deep hydrogeologic system underlying the Oak Ridge Reservation (ORR) contains contaminants such as radionuclides, heavy metals, nitrates, and organic compounds. The groundwater in the deep system is saline and has been considered to be stagnant in previous studies. This study was designed to address the following questions: is groundwater in the deep system stagnant; is contaminant migration controlled by diffusion only or is advection a viable mechanism; where are the potential outlet points? On the basis of existing and newly collected data, the nature of saline groundwater flow and potential discharge into shallow, freshwater systems was assessed. Data used for this purpose included (1) spatial and temporal pressures and hydraulic heads measured in the deep system, (2) hydraulic parameters of the formations in question, (3) spatial and temporal temperature variations at depth, and (4) spatial and temporal chemical and isotopic composition of the saline groundwater. The observations suggest that the saline water contained at depth is old but not isolated (in terms of recharge and discharge) from the overlying active, freshwater-bearing units. Influx of recent water does occur. Groundwater volumes involved in this flow are likely to be small. The origin of the saline groundwater was assessed by using existing and newly acquired chemical and isotopic data. The proposed model that best fits the data is modification of residual brine from which halite has been precipitated. Other models, such as ultrafiltration and halite dissolution, were also evaluated

The role of evapotranspiration in the groundwater hydrochemistry of an arid coastal wetland (Península Valdés, Argentina)

International Nuclear Information System (INIS)

Alvarez, María del Pilar; Carol, Eleonora; Dapeña, Cristina

2015-01-01

Coastal wetlands are complex hydrogeological systems, in which saline groundwater usually occurs. Salinity can be attributed to many origins, such as dissolution of minerals in the sediments, marine contribution and evapotranspiration, among others. The aim of this paper is to evaluate the processes that condition the hydrochemistry of an arid marsh, Playa Fracasso, located in Patagonia, Argentina. A study of the dynamics and geochemistry of the groundwater was carried out in each hydrogeomorphological unit, using major ion and isotope ( 18 O and 2 H) data, soil profiles descriptions and measurements, and recording of water tables in relation to the tidal flow. Water balances and analytical models based on isotope data were used to quantify the evaporation processes and to define the role of evaporation in the chemical composition of water. The results obtained show that the groundwater salinity of the marsh comes mainly from the tidal inflow, to which the halite and gypsum dissolution is added. These mineral facies are the result of the total evaporation of the marine water flooding that occurs mostly at the spring high tides. The isotope relationships in the fan and bajada samples show the occurrence of evaporation processes. Such processes, however, are not mainly responsible for the saline content of groundwater, which is actually generated by the dissolution of the typical evaporite facies of the arid environment sediments. It is concluded that the evapotranspiration processes condition groundwater quality. This is not only due to the saline enrichment caused by the evapotranspiration of shallow water, but also because such processes are the main drivers of the formation of soluble salts, which are then incorporated into the water by groundwater or tidal flow. - Highlights: • Tidal inflow and evapotranspiration processes condition the salinity of the marsh. • The total evaporation of marine water led the halite and gypsum precipitation. • The dissolution

The effects of withdrawals and drought on groundwater availability in the Northern Guam Lens Aquifer, Guam

Science.gov (United States)

Gingerich, Stephen B.

2013-01-01

Owing to population growth, freshwater demand on Guam has increased in the past and will likely increase in the future. During the early 1970s to 2010, groundwater withdrawals from the limestone Northern Guam Lens Aquifer, the main source of freshwater on the island, tripled from about 15 to 45 million gallons per day. Because of proposed military relocation to Guam and expected population growth, freshwater demand on Guam is projected to increase further. The expected increased demand for groundwater has led to concern over the long-term sustainability of withdrawals from existing and proposed wells. A three-dimensional numerical groundwater flow and transport model was developed to simulate the effects of hypothetical withdrawal and recharge scenarios on water levels and on the transition zone between freshwater and saltwater. The model was constructed by using average recharge during 1961–2005 and withdrawals from 2010. Hydraulic properties used to construct the model were initially based on published estimates but ultimately were adjusted to obtain better agreement between simulated and measured water levels and salinity profiles in the modeled area. Two hypothetical groundwater withdrawal scenarios were simulated: no withdrawal to simulate predevelopment conditions and withdrawal at 2010 rates under a 5-year drought. Simulation results indicate that prior to pumping; the fresh-water lens was 10 to 50 feet thicker in the Yigo-Tumon basin and more than 50 feet thicker in the Hagåtña basin. Results also indicate that continuing the 2010 withdrawal distribution during a 5-year drought would result in decreased water levels, a thinner freshwater lens, and increased salinity of water pumped from wells. The available water with an acceptable salinity (chloride concentration less than 200 milligrams per liter) would decrease from about 34 million gallons per day to 11.5 million gallons per day after 5 years but recover to pre-drought levels 5 years after the

Groundwater sustainability and groundwater/surface-water interaction in arid Dunhuang Basin, northwest China

Science.gov (United States)

Lin, Jingjing; Ma, Rui; Hu, Yalu; Sun, Ziyong; Wang, Yanxin; McCarter, Colin P. R.

2018-03-01

The Dunhuang Basin, a typical inland basin in northwestern China, suffers a net loss of groundwater and the occasional disappearance of the Crescent Lake. Within this region, the groundwater/surface-water interactions are important for the sustainability of the groundwater resources. A three-dimensional transient groundwater flow model was established and calibrated using MODFLOW 2000, which was used to predict changes to these interactions once a water diversion project is completed. The simulated results indicate that introducing water from outside of the basin into the Shule and Danghe rivers could reverse the negative groundwater balance in the Basin. River-water/groundwater interactions control the groundwater hydrology, where river leakage to the groundwater in the Basin will increase from 3,114 × 104 m3/year in 2017 to 11,875 × 104 m3/year in 2021, and to 17,039 × 104 m3/year in 2036. In comparison, groundwater discharge to the rivers will decrease from 3277 × 104 m3/year in 2017 to 1857 × 104 m3/year in 2021, and to 510 × 104 m3/year by 2036; thus, the hydrology will switch from groundwater discharge to groundwater recharge after implementing the water diversion project. The simulation indicates that the increased net river infiltration due to the water diversion project will raise the water table and then effectively increasing the water level of the Crescent Lake, as the lake level is contiguous with the water table. However, the regional phreatic evaporation will be enhanced, which may intensify soil salinization in the Dunhuang Basin. These results can guide the water allocation scheme for the water diversion project to alleviate groundwater depletion and mitigate geo-environmental problem.

The onshore influence of offshore fresh groundwater

Science.gov (United States)

Knight, Andrew C.; Werner, Adrian D.; Morgan, Leanne K.

2018-06-01

Freshwater contained within the submarine extensions of coastal aquifers is increasingly proposed as a freshwater source for coastal communities. However, the extent to which offshore freshwater supports onshore pumping is currently unknown on a global scale. This study provides the first attempt to examine the likely prevalence of situations where offshore freshwater influences onshore salinities, considering various sites from around the world. The groundwater conditions in twenty-seven confined and semi-confined coastal aquifers with plausible connections to inferred or observed offshore freshwater are explored. The investigation uses available onshore salinities and groundwater levels, and offshore salinity knowledge, in combination with analytical modelling, to develop simplified conceptual models of the study sites. Seven different conceptual models are proposed based on the freshwater-saltwater extent and insights gained from analytical modelling. We consider both present-day and pre-development conditions in assessing potential modern contributions to offshore fresh groundwater. Conceptual models also include interpretations of whether offshore freshwater is a significant factor influencing onshore salinities and well pumping sustainability. The results indicate that onshore water levels have declined between pre-development and present-day conditions in fourteen of the fifteen regions for which pre-development data are available. Estimates of the associated steady-state freshwater extents show the potential for considerable offshore fresh groundwater losses accompanying these declines. Both present-day and pre-development heads are insufficient to account for the observed offshore freshwater in all cases where adequate data exist. This suggests that paleo-freshwater and/or aquifer heterogeneities contribute significantly to offshore freshwater extent. Present-day heads indicate that active seawater intrusion (SWI) will eventually impact onshore pumping

Hoe Creek groundwater restoration, 1989

Energy Technology Data Exchange (ETDEWEB)

Renk, R.R.; Crader, S.E.; Lindblom, S.R.; Covell, J.R.

1990-01-01

During the summer of 1989, approximately 6.5 million gallons of contaminated groundwater were pumped from 23 wells at the Hoe Creek underground coal gasification site, near Gillette, Wyoming. The organic contaminants were removed using activated carbon before the water was sprayed on 15.4 acres at the sites. Approximately 2647 g (5.8 lb) of phenols and 10,714 g (23.6 lb) of benzene were removed from the site aquifers. Phenols, benzene, toluene, ethylbenzene, and naphthalene concentrations were measured in 43 wells. Benzene is the only contaminant at the site exceeds the federal standard for drinking water (5 {mu}g/L). Benzene leaches into the groundwater and is slow to biologically degrade; therefore, the benzene concentration has remained high in the groundwater at the site. The pumping operation affected groundwater elevations across the entire 80-acre site. The water levels rebounded quickly when the pumping operation was stopped on October 1, 1989. Removing contaminated groundwater by pumping is not an effective way to clean up the site because the continuous release of benzene from coal tars is slow. Benzene will continue to leach of the tars for a long time unless its source is removed or the leaching rate retarded through mitigation techniques. The application of the treated groundwater to the surface stimulated plant growth. No adverse effects were noted or recorded from some 60 soil samples taken from twenty locations in the spray field area. 20 refs., 52 figs., 8 tabs.

Composition and fluxes of submarine groundwater along the Caribbean coast of the Yucatan Peninsula

Science.gov (United States)

Null, Kimberly A.; Knee, Karen L.; Crook, Elizabeth D.; de Sieyes, Nicholas R.; Rebolledo-Vieyra, Mario; Hernández-Terrones, Laura; Paytan, Adina

2014-04-01

Submarine groundwater discharge (SGD) to the coastal environment along the eastern Yucatan Peninsula, Quintana Roo, Mexico was investigated using a combination of tracer mass balances and analytical solutions. Two distinct submarine groundwater sources including water from the unconfined surficial aquifer discharging at the beach face and water from a deeper aquifer discharging nearshore through submarine springs (ojos) were identified. The groundwater of nearshore ojos was saline and significantly enriched in short-lived radium isotopes (223Ra, 224Ra) relative to the unconfined aquifer beach face groundwater. We estimated SGD from ojos using 223Ra and used a salinity mass balance to estimate the freshwater discharge at the beach face. Analytical calculations were also used to estimate wave set-up and tidally driven saline seepage into the surf zone and were compared to the salinity-based freshwater discharge estimates. Results suggest that average SGD from ojos along the Yucatan Peninsula Caribbean coast is on the order of 308 m3 d-1 m-1 and varies between sampling regions. Higher discharge was observed in the southern regions (568 m3 d-1 m-1) compared to the north (48 m3 d-1 m-1). Discharge at the beach face was in the range of 3.3-8.5 m3 d-1 m-1 for freshwater and 2.7 m3 d-1 m-1 for saline water based on the salinity mass balance and wave- and tidally-driven discharge, respectively. Although discharge from the ojos was larger in volume than discharge from the unconfined aquifer at the beach face, dissolved inorganic nitrogen (DIN) was significantly higher in beach groundwater; thus, discharge of this unconfined beach aquifer groundwater contributed significantly to total DIN loading to the coast. DIN fluxes were up to 9.9 mol d-1 m-1 from ojos and 2.1 mol d-1 m-1 from beach discharge and varied regionally along the 500 km coastline sampled. These results demonstrate the importance of considering the beach zone as a significant nutrient source to coastal waters

Groundwater quality assessment in the village of Lutfullapur Nawada, Loni, District Ghaziabad, Uttar Pradesh, India.

Science.gov (United States)

Singh, Vinod K; Bikundia, Devendra Singh; Sarswat, Ankur; Mohan, Dinesh

2012-07-01

The groundwater quality for drinking, domestic and irrigation in the village Lutfullapur Nawada, Loni, district Ghaziabad, U.P., India, has been assessed. Groundwater samples were collected, processed and analyzed for temperature, pH, conductivity, salinity, total alkalinity, carbonate alkalinity, bicarbonate alkalinity, total hardness, calcium hardness, magnesium hardness, total solids, total dissolved solids, total suspended solids, nitrate-nitrogen, chloride, fluoride, sulfate, phosphate, silica, sodium, potassium, calcium, magnesium, total chromium, cadmium, copper, iron, nickel, lead and zinc. A number of groundwater samples showed levels of electrical conductivity (EC), alkalinity, chloride, calcium, sodium, potassium and iron exceeding their permissible limits. Except iron, the other metals (Cr, Cd, Cu, Ni, Pb, and Zn) were analyzed below the permissible limits. The correlation matrices for 28 variables were performed. EC, salinity, TS and TDS had significant positive correlations among themselves and also with NO (3) (-) , Cl(-), alkalinity, Na(+), K(+), and Ca(2+). Fluoride was not significantly correlated with any of the parameters. NO (3) (-) was significantly positively correlated with Cl(-), alkalinity, Na(+), K(+) and Ca(2+). Chloride also correlated significantly with alkalinity, Na(+), K(+) and Ca(2+). Sodium showed a strong and positive correlation with K(+) and Ca(2+). pH was negatively correlated with most of the physicochemical parameters. This groundwater is classified as a normal sulfate and chloride type. Base-exchange indices classified 73% of the groundwater sources as the Na(+)-SO (4) (2-) type. The meteoric genesis indices demonstrated that 67% of groundwater sources belong to a deep meteoric water percolation type. Hydrochemical groundwater evaluations revealed that most of the groundwaters belong to the Na(+)-K(+)-Cl(-)-SO (4) (2-) type followed by Na(+)-K(+)-HCO (3) (-) type. Salinity, chlorinity and SAR indices indicated that majority

Water management of the uranium production facility in Brazil (Caetite, BA): potential impacts over groundwater quality

International Nuclear Information System (INIS)

Lamego, Fernando; Santos, Robson Rodger; Silva, L. Ferreira da; Fernandes, Horst Monken

2008-01-01

The uranium unit of Caetite - in charge of all the 'yellow cake' produced in Brazil - is located in the semi-arid Northeast region at Bahia State. The geological uranium content of the ore is 3000 ppm, which is mainly associated with albite (NaAlSi 8 O 8 ), and its extraction is achieved by means of a Heap-Leach process. This process has a low water demand, which is supplied by a network of wells, but can contribute to change the groundwater quality and in some cases the extinguishing of wells was observed. The managing of liquid mining wastes formed by drainage waters from mine pit and solid waste piles is not enough to avoid unwarranted releases in the environment, which turn necessary the waste treatment through passing them into the industrial plant in order to reduce radionuclide concentrations. The groundwater is Na-HCO 3 type water and relative high concentration of Cl are observed in some groundwater. It seems that levels of uranium in groundwaters are mainly a consequence of the complexation of the metal by carbonates (or other anions) and not by any sort of the contamination of these waters by the drainage accumulated in the open pit. The speciation modelling allows identifying some areas where the replenishment of the aquifer is more active, but in general the recharge is a fast process run by direct infiltration. The stable isotope data (δ 2 H and δ 18 O) showed that evaporation plays a role during the infiltration, causing the groundwater salinization. These data discard the possibility that groundwater salinization was caused by discharge of deeper saline groundwater through faults associated to a regional groundwater flow system. The presence of an active shallow groundwater flow system offers better possibility for sustainable use of the groundwater resources in this semi-arid region of Brazil. (author)

(99)Tc(VII) Retardation, Reduction, and Redox Rate Scaling in Naturally Reduced Sediments.

Science.gov (United States)

Liu, Yuanyuan; Liu, Chongxuan; Kukkadapu, Ravi K; McKinley, James P; Zachara, John; Plymale, Andrew E; Miller, Micah D; Varga, Tamas; Resch, Charles T

2015-11-17

An experimental and modeling study was conducted to investigate pertechnetate (Tc(VII)O4(-)) retardation, reduction, and rate scaling in three sediments from Ringold formation at U.S. Department of Energy's Hanford site, where (99)Tc is a major contaminant in groundwater. Tc(VII) was reduced in all the sediments in both batch reactors and diffusion columns, with a faster rate in a sediment containing a higher concentration of HCl-extractable Fe(II). Tc(VII) migration in the diffusion columns was reductively retarded with retardation degrees correlated with Tc(VII) reduction rates. The reduction rates were faster in the diffusion columns than those in the batch reactors, apparently influenced by the spatial distribution of redox-reactive minerals along transport paths that supplied Tc(VII). X-ray computed tomography and autoradiography were performed to identify the spatial locations of Tc(VII) reduction and transport paths in the sediments, and results generally confirmed the newly found behavior of reaction rate changes from batch to column. The results from this study implied that Tc(VII) migration can be reductively retarded at Hanford site with a retardation degree dependent on reactive Fe(II) content and its distribution in sediments. This study also demonstrated that an effective reaction rate may be faster in transport systems than that in well-mixed reactors.

Pharmaceuticals as Groundwater Tracers - Applications and Limitations

Science.gov (United States)

Scheytt, T. J.; Mersmann, P.; Heberer, T.

2003-12-01

Pharmaceutically active substances and metabolites are found at concentrations up to the microgram/L-level in groundwater samples from the Berlin (Germany) area and from several other places world wide. Among the compounds detected in groundwater are clofibric acid, propyphenazone, diclofenac, ibuprofen, and carbamazepine. Clofibric acid, the active metabolite of clofibrate and etofibrate (blood lipid regulators) is detected in groundwater at maximum concentrations of 7300 ng/L. Among the most important input paths of drugs are excretion and disposal into the sewage system. Groundwater contamination is likely to be due to leaky sewage systems, influent streams, bank filtration, and irrigation with effluent water from sewage treatment plants. There are no known natural sources of the above mentioned pharmaceuticals. The use of pharmaceuticals as tracers may include: (a) Quantification of infiltration from underground septic tanks (b) Detection of leaky sewage systems / leaky sewage pipes (c) Estimation of the effectiveness of sewage treatment plants (d) Identification of transport pathways of other organic compounds (e) Quantification of surface water / groundwater interaction (f) Characterization of the biodegradation potential. The use of pharmaceuticals as tracers is limited by variations in input. These variations depend on the amount of drugs prescribed and used in the study area, the social structure of the community, the amount of hospital discharge, and temporal concentration variations. Furthermore, the analysis of trace amounts of pharmaceuticals is sophisticated and expensive and may therefore limit the applicability of pharmaceuticals as tracers. Finally, the transport and degradation behavior of pharmaceuticals is not fully understood. Preliminary experiments in the laboratory were conducted using sediment material and groundwater from the Berlin area to evaluate the transport and sorption behavior of selected drugs. Results of the column experiments

Groundwater quality for irrigation of deep aquifer in southwestern zone of Bangladesh

Directory of Open Access Journals (Sweden)

Mirza A.T.M. Tanvir Rahman

2012-07-01

Full Text Available In coastal regions of Bangladesh, sources of irrigation are rain, surface and groundwater. Due to rainfall anomaly andsaline contamination, it is important to identify deep groundwater that is eligible for irrigation. The main goal of the study wasto identify deep groundwater which is suitable for irrigation. Satkhira Sadar Upazila, at the southwestern coastal zone ofBangladesh, was the study area, which was divided into North, Center and South zones. Twenty samples of groundwaterwere analyzed for salinity (0.65-4.79 ppt, sodium absorption ratio (1.14-11.62, soluble sodium percentage (32.95-82.21, electricalconductivity (614-2082.11 μS/cm, magnesium adsorption ratio (21.96-26.97, Kelly’s ratio (0.48-4.62, total hardness(150.76-313.33 mg/l, permeability index (68.02-94.16 and residual sodium bi-carbonate (79.68-230.72 mg/l. Chemical constituentsand values were compared with national and international standards. Northern deep groundwater has the highest salinityand chemical concentrations. Salinity and other chemical concentrations show a decreasing trend towards the south. Lowchemical concentrations in the southern region indicate the best quality groundwater for irrigation.

The source of groundwater salinization in the Indus basin - an isotopic evidence

International Nuclear Information System (INIS)

Sajjad, M.I.; Hussain, S.D.; Tasneem, M.A.; Ahmad, M.; Khan, I.H.; Akram, W.; Waheed, R.

1991-09-01

The isotopic and chemical studies were carried out in three regions of the Indus Basin to ascertain the source of salinity. Samples collected from the Faisalabad are in Rechna Doab, Chaj Doab and Mardan Valley, were analysed on mass spectrometer for D/H, 18O/16O and 34S/32S ratios. Electrical conductivities and pH measurements were made in situ while the analyses of various cations/anions were made in the laboratory. The isotopic results show that the salinity is mainly due to the dissolution of sediments salts by the infiltrating sweet water. The chemical data also support this conclusion. The rise in salinity is also partly due to the use of fertilizers and evaporation processes. (author)

Geochemical processes controlling water salinization in an irrigated basin in Spain: identification of natural and anthropogenic influence.

Science.gov (United States)

Merchán, D; Auqué, L F; Acero, P; Gimeno, M J; Causapé, J

2015-01-01

Salinization of water bodies represents a significant risk in water systems. The salinization of waters in a small irrigated hydrological basin is studied herein through an integrated hydrogeochemical study including multivariate statistical analyses and geochemical modeling. The study zone has two well differentiated geologic materials: (i) Quaternary sediments of low salinity and high permeability and (ii) Tertiary sediments of high salinity and very low permeability. In this work, soil samples were collected and leaching experiments conducted on them in the laboratory. In addition, water samples were collected from precipitation, irrigation, groundwater, spring and surface waters. The waters show an increase in salinity from precipitation and irrigation water to ground- and, finally, surface water. The enrichment in salinity is related to the dissolution of soluble mineral present mainly in the Tertiary materials. Cation exchange, precipitation of calcite and, probably, incongruent dissolution of dolomite, have been inferred from the hydrochemical data set. Multivariate statistical analysis provided information about the structure of the data, differentiating the group of surface waters from the groundwaters and the salinization from the nitrate pollution processes. The available information was included in geochemical models in which hypothesis of consistency and thermodynamic feasibility were checked. The assessment of the collected information pointed to a natural control on salinization processes in the Lerma Basin with minimal influence of anthropogenic factors. Copyright © 2014 Elsevier B.V. All rights reserved.

Geostatistical methods in evaluating spatial variability of groundwater quality in Al-Kharj Region, Saudi Arabia

Science.gov (United States)

Al-Omran, Abdulrasoul M.; Aly, Anwar A.; Al-Wabel, Mohammad I.; Al-Shayaa, Mohammad S.; Sallam, Abdulazeam S.; Nadeem, Mahmoud E.

2017-11-01

The analyses of 180 groundwater samples of Al-Kharj, Saudi Arabia, recorded that most groundwaters are unsuitable for drinking uses due to high salinity; however, they can be used for irrigation with some restriction. The electric conductivity of studied groundwater ranged between 1.05 and 10.15 dS m-1 with an average of 3.0 dS m-1. Nitrate was also found in high concentration in some groundwater. Piper diagrams revealed that the majority of water samples are magnesium-calcium/sulfate-chloride water type. The Gibbs's diagram revealed that the chemical weathering of rock-forming minerals and evaporation are influencing the groundwater chemistry. A kriging method was used for predicting spatial distribution of salinity (EC dS m-1) and NO3 - (mg L-1) in Al-Kharj's groundwater using data of 180 different locations. After normalization of data, variogram was drawn, for selecting suitable model for fitness on experimental variogram, less residual sum of squares value was used. Then cross-validation and root mean square error were used to select the best method for interpolation. The kriging method was found suitable methods for groundwater interpolation and management using either GS+ or ArcGIS.

Environmental isotopes investigation in groundwater of Challaghatta ...

African Journals Online (AJOL)

Administrator

Radiogenic isotopes (3H and 14C) and stable isotope (18O) together with TDS, EC and salinity of water were used to ..... Tritium (3H). Relative dating of groundwater has been carried ... that falls to Earth has small amounts of tritium. During the.

Numerical prediction of 239Pu migration for groundwater pollution in the infiltration case

International Nuclear Information System (INIS)

Liu Dongxu; Si Gaohua; Wang Qinghai; Yu Jing

2010-01-01

In terms of the study on site selection of geological disposal of LIL radioactive waste in north-west China, a numerical prediction of 239 Pu migration for potential groundwater pollution in the unsaturated zone was conducted with the HYDRUS-ID model. The results showed that the groundwater will not be contaminated by the migration of soluble 239 Pu. And there is a faint possibility that 239 Pu migration through groundwater path might have an unacceptable impact on ecosphere. Measurements of the distribution coefficient, K d , are critical in the determination of sorption-induced retardation of radionuclide transport. (authors)

Characterization of Intrinsic PAH Biodegradation in Groundwater During Tidal Cycles at the Naval Station Norfolk: Interim Report

National Research Council Canada - National Science Library

Boyd, Thomas

2002-01-01

.... Groundwater at the site is impacted by subsurface fuel spill(s). Groundwater was assessed for fuel hydrocarbon concentrations, stable carbon isotope fingerprints, temperature, salinity, total microbial carbon demand, and PAH mineralization rates...

Untangling the effects of shallow groundwater and deficit irrigation on irrigation water productivity in arid region: New conceptual model.

Science.gov (United States)

Xue, Jingyuan; Huo, Zailin; Wang, Fengxin; Kang, Shaozhong; Huang, Guanhua

2018-04-01

Water scarcity and salt stress are two main limitations for agricultural production. Groundwater evapotranspiration (ET g ) with upward salt movement plays an important role in crop water use and water productivity in arid regions, and it can compensate the impact of deficit irrigation on crop production. Thus, comprehensive impacts of shallow groundwater and deficit irrigation on crop water use results in an improvement of irrigation water productivity (IWP). However, it is difficult to quantify the effects of groundwater and deficit irrigation on IWP. In this study, we built an IWP evaluation model coupled with a water and salt balance model and a crop yield estimation model. As a valuable tool of IWP simulation, the calibrated model was used to investigate the coupling response of sunflower IWP to irrigation water depths (IWDs), groundwater table depth (GTDs) and groundwater salinities (GSs). A total of 210 scenarios were run in which five irrigation water depths (IWDs) and seven groundwater table depths (GTDs) and six groundwater salinities (GSs) were used. Results indicate that increasing GS clearly increases the negative effect on a crop's actual evapotranspiration (ET a ) as salt accumulation in root zone. When GS is low (0.5-1g/L), increasing GTD produces more positive effect than negative effect. In regard to relatively high GS (2-5g/L), the negative effect of shallow-saline groundwater reaches a maximum at 2m GTD. Additionally, the salt concentration in the root zone maximizes its value at 2.0m GTD. In most cases, increasing GTD and GS reduces the benefits of irrigation water and IWP. The IWP increases with decreasing irrigation water. Overall, in arid regions, capillary rise of shallow groundwater can compensate for the lack of irrigation water and improve IWP. By improving irrigation schedules and taking advantages of shallow saline groundwater, we can obtain higher IWP. Copyright © 2017 Elsevier B.V. All rights reserved.

Salinity sources of Kefar Uriya wells in the Judea Group aquifer of Israel. Part 1—conceptual hydrogeological model

Science.gov (United States)

Avisar, D.; Rosenthal, E.; Flexer, A.; Shulman, H.; Ben-Avraham, Z.; Guttman, J.

2003-01-01

In the Yarkon-Taninim groundwater basin, the karstic Judea Group aquifer contains groundwater of high quality. However, in the western wells of the Kefar Uriya area located in the foothills of the Judea Mountains, brackish groundwater was locally encountered. The salinity of this water is caused presumably by two end members designated as the 'Hazerim' and 'Lakhish' water types. The Hazerim type represents surface water percolating through a highly fractured thin chalky limestone formation overlying the Judea Group aquifer. The salinity of the water derives conjointly from several sources such as leachates from rendzina and grumosols, dissolution of caliche crusts which contain evaporites and of rock debris from the surrounding formations. This surface water percolates downwards into the aquifer through a funnel- or chimney-like mechanism. This local salinization mechanism supercedes another regional process caused by the Lakhish waters. These are essentially diluted brines originating from deep formations in the western parts of the Coastal Plain. The study results show that salinization is not caused by the thick chalky beds of the Senonian Mt Scopus Group overlying the Judea Group aquifer, as traditionally considered but prevalently by aqueous leachates from soils and rock debris. The conceptual qualitative hydrogeological model of the salinization as demonstrated in this study, is supported by a quantitative hydrological model presented in another paper in this volume.

The `Henry Problem' of `density-driven' groundwater flow versus Tothian `groundwater flow systems' with variable density: A review of the influential Biscayne aquifer data.

Science.gov (United States)

Weyer, K. U.

2017-12-01

Coastal groundwater flow investigations at the Biscayne Bay, south of Miami, Florida, gave rise to the concept of density-driven flow of seawater into coastal aquifers creating a saltwater wedge. Within that wedge, convection-driven return flow of seawater and a dispersion zone were assumed by Cooper et al. (1964) to be the cause of the Biscayne aquifer `sea water wedge'. This conclusion was based on the chloride distribution within the aquifer and on an analytical model concept assuming convection flow within a confined aquifer without taking non-chemical field data into consideration. This concept was later labelled the `Henry Problem', which any numerical variable density flow program must be able to simulate to be considered acceptable. Both, `density-driven flow' and Tothian `groundwater flow systems' (with or without variable density conditions) are driven by gravitation. The difference between the two are the boundary conditions. 'Density-driven flow' occurs under hydrostatic boundary conditions while Tothian `groundwater flow systems' occur under hydrodynamic boundary conditions. Revisiting the Cooper et al. (1964) publication with its record of piezometric field data (heads) showed that the so-called sea water wedge has been caused by discharging deep saline groundwater driven by gravitational flow and not by denser sea water. Density driven flow of seawater into the aquifer was not found reflected in the head measurements for low and high tide conditions which had been taken contemporaneously with the chloride measurements. These head measurements had not been included in the flow interpretation. The very same head measurements indicated a clear dividing line between shallow local fresh groundwater flow and saline deep groundwater flow without the existence of a dispersion zone or a convection cell. The Biscayne situation emphasizes the need for any chemical interpretation of flow pattern to be supported by head data as energy indicators of flow fields

Adsorption and Retardation of PFASs in Soil

Science.gov (United States)

Chen, W.; Yan, N.; Fu, X.; Carroll, K. C.; Holguin, F. O. O.; Brusseau, M. L.

2017-12-01

Per- and poly-fluorinated alkyl substances (PFASs) are emerging contaminants of concern that are present in the subsurface at numerous military and industrial facilities. Knowledge of the retention behavior of these compounds in the subsurface environment is critical for effective risk characterization and remediation. The objective of this research is to investigate the role of adsorption at the air-water interface on PFAS retention in vadose-zone systems. Surface tensions were measured for select PFAS to determine interfacial adsorption coefficients. Column experiments were conducted to characterize retardation and transport under saturated and unsaturated flow conditions. The impact of soil properties and groundwater constituents on surface tension, solid-phase adsorption, and interfacial adsorption was investigated.

Salinization may attack you from behind: upconing and related long-term downstream salinization in the Amsterdam Water Supply Dunes (Invited)

Science.gov (United States)

Olsthoorn, T.

2010-12-01

Groundwater from the Amsterdam Water Supply Dunes (GE: 52.35°N 4.55°E) has been used for the drinking water supply of Amsterdam since 1853. During the first half of the 20th century, severe intrusion and upconing occurred, with many of the wells turning brackish or saline. Already in 1903, the hydrologist/director of the Amsterdam Water Supply, Pennink, predicted this, based on his unique sand-box modeling, which he published in 1915 in the form of a large-size hard-bound book in four languages showing detailed black and white photographs of his tests. This book is now on the web: http://www.citg.tudelft.nl/live/pagina.jsp?id=68e12562-a4d2-489a-b82e-deca5dd32c42&lang=en Pennink devoted much of his work on saltwater upconing below wells, which he so feared. He simulated simultaneous flow of fresh and salt water, using milk to represent the saltwater having about the same density. With our current modeling tools, we can simulate his experiments, allowing to better understand his setup and even to verify our code. Pennink took interest in the way these cones form and in the point at which the salt water enters the screen. Surprizing, at least to many, is that this entry point is not necessarily the screen bottom. Measurements of the salinity distribution in salinized wells in the Amsterdam Water Supply Dune area confirmed this thirty years later when salinzation was severely occurring. The curved cone shape under ambient flow conditions provides part of the explanation why a short-term shut down of a well almost immediately diminishes salt concentrations, but salinization downstream of the wells in case with substantial lateral groundwater flow is not affected. Downstream salinization due to extraction was clearly shown in Pennink's experiments. However, the phenomenon seems still largely unknown or ignored. Downstream salinization also affects downstream heads for years after extraction has stopped. The presentation demonstrates and explains these local and more

Evaluation of the Marine Intrusion in Havana Province Groundwater Using Hydrochemical and Isotopic Tools

Energy Technology Data Exchange (ETDEWEB)

Alvarez, A. M.; Bombuse, D. L.; Estevez Alvarez, J. R. [Centro de Aplicaciones Tecnologicas y Desarrollo Nuclear (CEADEN), Havana (Cuba); others, and

2013-07-15

In the present paper the spatial distribution and temporal evolution of the saline intrusion in the most important aquifer of Havana province is presented. Results were obtained through the application of hydrochemical and isotopic tools. Studies were carried out within the framework of the IAEA Regional Project RLA/8/041. The survey was carried out in 2008 during the dry and rainy seasons. Sampling points were selected according to a monitoring network located along the north-south line following the main groundwater flow direction. Stable isotopes ({sup 2}H and {sup 18}O) were used to identify and characterize the groundwater origin and mixing processes. Changes in the chemical composition of groundwater were shown to be mainly controlled by the groundwater and seawater mixing process, followed by cation exchange reactions and a Ca-Mg precipitation process due to the strong influence of the costal wetland. A gradual decreasing of the spatial and temporal saline intrusion was observed. (author)

Radiocarbon dating of groundwater in tertiary sediments of the eastern Murray Basin

International Nuclear Information System (INIS)

Drury, L.W.; Calf, G.E.

1984-01-01

The Tertiary sediments located in the eastern part of the Murray Basin contain one of the most important low salinity groundwater resources in New South Wales. It is imperative that the hydrogeological environment in which the groundwater occurs be thoroughly understood to allow adequate management of the resource. A radiocarbon dating project was carried out on 37 groundwater samples from bores screened in these unconsolidated sediments. The results indicate water ages in the range 'modern' to 15 800 years. Groundwater recharge areas are indicated and rates of groundwater recharge and movement determined. The latter shows close correlation with velocity values quantitatively determined by Darcy's law

Radiocarbon dating of groundwater in Tertiary sediments of the eastern Murray Basin

Energy Technology Data Exchange (ETDEWEB)

Drury, L.W. (Water Resources Commission of New South Wales, Sydney (Australia)); Calf, G.E. (Australian Atomic Energy Commission Research Establishment, Lucas Heights. Isotope Div.); Dharmasiri, J.K. (Colombo Univ. (Sri Lanka))

1984-01-01

The Tertiary sediments located in the eastern part of the Murray Basin contain one of the most important low salinity groundwater resources in New South Wales. It is imperative that the hydrogeological environment in which the groundwater occurs be thoroughly understood to allow adequate management of the resource. A radiocarbon dating project was carried out on 37 groundwater samples from bores screened in these unconsolidated sediments. The results indicate water ages in the range 'modern' to 15 800 years. Groundwater recharge areas are indicated and rates of groundwater recharge and movement determined. The latter shows close correlation with velocity values quantitatively determined by Darcy's law.

Isotope and minor element geochemistry of high arsenic groundwater from Hangjinhouqi, the Hetao Plain, Inner Mongolia

International Nuclear Information System (INIS)

Deng Yamin; Wang Yanxin; Ma Teng

2009-01-01

High As groundwater is widely distributed in the northwestern Hetao Plain, an arid region with slow groundwater flow. Arsenic concentration in groundwater ranges from 1 to 1000 μg/L. Most water samples have elevated salinities, with Cl and/or HCO 3 as the dominant anions and Na as the dominant cation. High concentrations of As in shallow aquifers are associated with strongly reducing conditions, as evidenced by high concentrations of dissolved organic C (DOC), NH 4 , dissolved sulfide, arsenite and dissolved CH 4 , and relatively low concentrations of NO 3 - and SO 4 2- . Results of the hydrochemical, and H and O isotope geochemical studies indicate that evapotranspiration is an important process controlling the enrichment of Na and Cl as well as trace elements such as As, B, F and Br in groundwater. In Na-HCO 3 -dominated groundwaters, As, B and F were enriched. Decades of irrigation using Yellow River water has resulted in elevation of the groundwater level, which has accelerated salt accumulation in shallow groundwater and surface soil. In addition, irrigation is responsible for the release of some components from aquifer materials and mixing with saline groundwaters, as indicated by minor element and isotope geochemical data. Used to trace groundwater flow paths, Sr isotope composition also indicates that bedrock weathering is one of the primary sources of As in groundwater in the study area.

Fluoride contamination in groundwater resources of Alleppey, southern India

Directory of Open Access Journals (Sweden)

Dhanya Raj

2017-01-01

Full Text Available Alleppey is one of the thickly populated coastal towns of the Kerala state in southern India. Groundwater is the main source of drinking water for the 240,991 people living in this region. The groundwater is being extracted from a multi-layer aquifer system of unconsolidated to semi-consolidated sedimentary formations, which range in age from Recent to Tertiary. The public water distribution system uses dug and tube wells. Though there were reports on fluoride contamination, this study reports for the first time excess fluoride and excess salinity in the drinking water of the region. The quality parameters, like Electrical Conductivity (EC ranges from 266 to 3900 μs/cm, the fluoride content ranges from 0.68 to 2.88 mg/L, and the chloride ranges between the 5.7 to 1253 mg/L. The main water types are Na-HCO3, Na-CO3 and Na-Cl. The aqueous concentrations of F− and CO32− show positive correlation whereas F− and Ca2+ show negative correlation. The source of fluoride in the groundwater could be from dissolution of fluorapatite, which is a common mineral in the Tertiary sediments of the area. Long residence time, sediment–groundwater interaction and facies changes (Ca-HCO3 to Na-HCO3 during groundwater flow regime are the major factors responsible for the high fluoride content in the groundwater of the area. High strontium content and high EC in some of the wells indicate saline water intrusion that could be due to the excess pumping from the deeper aquifers of the area. The water quality index computation has revealed that 62% of groundwater belongs to poor quality and is not suitable for domestic purposes as per BIS and WHO standards. Since the groundwater is the only source of drinking water in the area, proper treatment strategies and regulating the groundwater extraction are required as the quality deterioration poses serious threat to human health.

Groundwater flow processes and mixing in active volcanic systems: the case of Guadalajara (Mexico)

Science.gov (United States)

Hernández-Antonio, A.; Mahlknecht, J.; Tamez-Meléndez, C.; Ramos-Leal, J.; Ramírez-Orozco, A.; Parra, R.; Ornelas-Soto, N.; Eastoe, C. J.

2015-09-01

Groundwater chemistry and isotopic data from 40 production wells in the Atemajac and Toluquilla valleys, located in and around the Guadalajara metropolitan area, were determined to develop a conceptual model of groundwater flow processes and mixing. Stable water isotopes (δ2H, δ18O) were used to trace hydrological processes and tritium (3H) to evaluate the relative contribution of modern water in samples. Multivariate analysis including cluster analysis and principal component analysis were used to elucidate distribution patterns of constituents and factors controlling groundwater chemistry. Based on this analysis, groundwater was classified into four groups: cold groundwater, hydrothermal groundwater, polluted groundwater and mixed groundwater. Cold groundwater is characterized by low temperature, salinity, and Cl and Na concentrations and is predominantly of Na-HCO3-type. It originates as recharge at "La Primavera" caldera and is found predominantly in wells in the upper Atemajac Valley. Hydrothermal groundwater is characterized by high salinity, temperature, Cl, Na and HCO3, and the presence of minor elements such as Li, Mn and F. It is a mixed-HCO3 type found in wells from Toluquilla Valley and represents regional flow circulation through basaltic and andesitic rocks. Polluted groundwater is characterized by elevated nitrate and sulfate concentrations and is usually derived from urban water cycling and subordinately from agricultural return flow. Mixed groundwaters between cold and hydrothermal components are predominantly found in the lower Atemajac Valley. Twenty-seven groundwater samples contain at least a small fraction of modern water. The application of a multivariate mixing model allowed the mixing proportions of hydrothermal fluids, polluted waters and cold groundwater in sampled water to be evaluated. This study will help local water authorities to identify and dimension groundwater contamination, and act accordingly. It may be broadly applicable to

Application of a Coupled Vegetation Competition and Groundwater Simulation Model to Study Effects of Sea Level Rise and Storm Surges on Coastal Vegetation

Directory of Open Access Journals (Sweden)

Su Yean Teh

2015-09-01

Full Text Available Global climate change poses challenges to areas such as low-lying coastal zones, where sea level rise (SLR and storm-surge overwash events can have long-term effects on vegetation and on soil and groundwater salinities, posing risks of habitat loss critical to native species. An early warning system is urgently needed to predict and prepare for the consequences of these climate-related impacts on both the short-term dynamics of salinity in the soil and groundwater and the long-term effects on vegetation. For this purpose, the U.S. Geological Survey’s spatially explicit model of vegetation community dynamics along coastal salinity gradients (MANHAM is integrated into the USGS groundwater model (SUTRA to create a coupled hydrology–salinity–vegetation model, MANTRA. In MANTRA, the uptake of water by plants is modeled as a fluid mass sink term. Groundwater salinity, water saturation and vegetation biomass determine the water available for plant transpiration. Formulations and assumptions used in the coupled model are presented. MANTRA is calibrated with salinity data and vegetation pattern for a coastal area of Florida Everglades vulnerable to storm surges. A possible regime shift at that site is investigated by simulating the vegetation responses to climate variability and disturbances, including SLR and storm surges based on empirical information.

Bentonite as a colloid source in groundwaters at Olkiluoto

International Nuclear Information System (INIS)

Vuorinen, U.; Hirvonen, H.

2005-02-01

In this work bentonite was studied as a potential source of colloids in Olkiluoto groundwaters. Samples were collected at two groundwater stations, PVA1 at 37.5 m dept and PVA3 at 95.6 m depth, in the VLJ-tunnel. The deeper groundwater at PVA3 was more saline (2.6g/L of Cl-) than the shallow at PVA1 (0.8g/L of Cl-). A bentonite source had been assembled at each groundwater station so that two sample lines were available for water samples; one for collecting a sample before and the other for collecting a sample after interaction with bentonite. Before starting the actual colloid sampling groundwaters from both sample lines at both stations were analysed. Only minor alterations, mostly within the uncertainty limits of the analysis methods, were brought about in the water chemistries after interaction with the bentonite sources. The only clear changes were seen in the concentration of iron which decreased after interaction with bentonite in the groundwaters at both stations. After groundwater sampling the actual colloid sampling was performed. The water samples were collected and treated inside a movable nitrogen filled glove-box. The samples could be collected from each sampling line directly in the glove-box via two quick-couplings that had been assembled on the front face of the box. The sample lines had been assembled with 0.45 μm filters before entering the glove-box, because only colloids smaller than 0.45 μm were of interest, as they are not prone to sedimentation in slow groundwater flows and therefore could act as potential radionuclide carriers. Colloid samples were collected and treated similarly from both sampling lines at both groundwater stations. For estimating the colloid content the groundwater samples were filtered with centrifugal ultrafiltration tubes of different cut-off values (0.3 μm, 300kD and 10kD). The ultrafiltrations produced the colloid-containing concentrate fractions and the soluble substances-containing filtrate fractions. In

Evaluation of promising technologies for soil salinity amelioration in Timpaki (Crete): a participatory approach

Science.gov (United States)

Panagea, I. S.; Daliakopoulos, I. N.; Tsanis, I. K.; Schwilch, G.

2016-02-01

Soil salinity management can be complex, expensive, and time demanding, especially in arid and semi-arid regions. Besides taking no action, possible management strategies include amelioration and adaptation measures. Here we apply the World Overview of Conservation Approaches and Technologies (WOCAT) framework for the systematic analysis and evaluation and selection of soil salinisation amelioration technologies in close collaboration with stakeholders. The participatory approach is applied in the RECARE (Preventing and Remediating degradation of soils in Europe through Land Care) project case study of Timpaki, a semi-arid region in south-central Crete (Greece) where the main land use is horticulture in greenhouses irrigated by groundwater. Excessive groundwater abstractions have resulted in a drop of the groundwater level in the coastal part of the aquifer, thus leading to seawater intrusion and in turn to soil salinisation. The documented technologies are evaluated for their impacts on ecosystem services, cost, and input requirements using a participatory approach and field evaluations. Results show that technologies which promote maintaining existing crop types while enhancing productivity and decreasing soil salinity are preferred by the stakeholders. The evaluation concludes that rainwater harvesting is the optimal solution for direct soil salinity mitigation, as it addresses a wider range of ecosystem and human well-being benefits. Nevertheless, this merit is offset by poor financial motivation making agronomic measures more attractive to users.

Dissolution of unirradiated UO2 fuel in synthetic groundwater. Final report (1996-1998)

International Nuclear Information System (INIS)

Ollila, K.

1999-05-01

This study was a part of the EU R and D programme 1994-1998: Nuclear Fission Safety, entitled 'Source term for performance assessment of spent fuel as a waste form'. The research carried out at VTT Chemical Technology was focused on the effects of granitic groundwater composition and redox conditions on UO 2 solubility and dissolution mechanisms. The synthetic groundwater compositions simulated deep granitic fresh and saline groundwaters, and the effects of the near-field material, bentonite, on very saline groundwater. Additionally, the Spanish granite/bentonite water was used. The redox conditions (Eh), which are obviously the most important factors that influence on UO 2 solubility under the disposal conditions of spent fuel, varied from strongly oxidising (air-saturated), anaerobic (N 2 , O 2 2 , low Eh). The objective of the air-saturated dissolution experiments was to yield the maximum solution concentrations of U, and information on the formation of secondary phases that control the concentrations, with different groundwater compositions. The static batch solubility experiments of long duration (up to 1-2 years) were performed using unirradiated UO 2 pellets and powder. Under anaerobic and reducing conditions, the solubilities were also approached from oversaturation. The results of the oxic, air-saturated dissolution experiments with UO 2 powder showed that the increase in the salinity ( -5 M, were at the level of the theoretical solubility of schoepite or another uranyl oxide hydrate, e.g. becquerelite (possibly Na-polyuranate). The higher alkalinity of the fresh (Allard) composition increased the aqueous U concentration. Only some kind of oxidised U-phase (U 3 O 8 -UO 3 ) was identified with XRD when studying possible secondary phases after the contact time of one year with all groundwater compositions. Longer contact times are needed to identify secondary phases predicted by modelling (EQ3/6). In the anoxic dissolution experiments with UO 2 pellets, the

The hydrogeochemical and isotopic investigations of the two-layered Shiraz aquifer in the northwest of Maharlou saline lake, south of Iran

Science.gov (United States)

Tajabadi, Mehdi; Zare, Mohammad; Chitsazan, Manouchehr

2018-03-01

Maharlou saline lake is the outlet of Shiraz closed basin in southern Iran, surrounded by several disconnected alluvial fresh water aquifers. These aquifers in the west and northwest of the lake are recharged by karstic anticlines such as Kaftarak in the north and Barmshour in the south. Here groundwater salinity varies along the depth so that better quality water is located below brackish or saline waters. The aim of this study is to investigate the reason for the salinity anomaly and the origin of the fresher groundwater in lower depth. Hence, the change in groundwater salinity along depth has been investigated by means of a set of geoelectrical, hydrogeological, hydrogeochemical, and environmental isotopes data. The interpretation of geoelectrical profiles and hydrogeological data indicates that the aquifer in the southeast of Shiraz plain is a two-layer aquifer separated by a fine-grained (silt and clay) layer with an approximate thickness of 40 m at the depth of about 100-120 m. Hydrgeochemistry showed that the shallow aquifer is recharged by Kaftarak karstic anticline and is affected by the saline lake water. The lake water fraction varies in different parts from zero for shallow aquifer close to the karstic anticlines to ∼70 percent in the margin of the lake. The deep aquifer is protected from the intrusion of saline lake water due to the presence of the above-mentioned confining layer with lake water fraction of zero. The stable isotopes signatures also indicate that the 'fresh' groundwater belonging to the deep aquifer is not subject to severe evaporation or mixing which is typical of the karstic water of the area. It is concluded that the characteristics of the deep aquifer are similar to those of the karstic carbonate aquifer. This karstic aquifer is most probably the Barmshour carbonated anticline buried under the shallow aquifer in the southern part. It may also be the extension of the Kaftarak anticline in the northern part.

A Search for Freshwater in the Saline Aquifers of Coastal Bangladesh

Science.gov (United States)

Peters, C.; Hornberger, G. M.

2017-12-01

Can we locate pockets of freshwater amidst brackish groundwater in remote villages in Bangladesh? This study explores what we can infer about local groundwater-surface water (GW-SW) interactions in the polders of coastal Bangladesh. In this underdeveloped region, the shallow groundwater is primarily brackish with unpredictable apportioning of freshwater pockets. We use transects of piezometers, cores, electromagnetic induction, and water chemistry surveys to explore two sources of potential fresh groundwater: (1) tidal channel-aquifer exchange and (2) meteoric recharge. Freshwater is difficult to find due to disparate subsurface lithology, asymmetrical tidal dynamics, extreme seasonal fluctuations in rainfall, and limited field data. Observations suggest substantial lateral variability in shallow subsurface conductivity profiles as well as tidal pressure signals in piezometers. Nevertheless, active exchange of freshwater may be limited due to low permeability of banks and surface sediments limits. Small scale heterogeneity in delta formation likely caused much of the groundwater salinity variation. Without adequate ground truthing of groundwater quality, the ability to deduce the exact location of freshwater pockets may be restricted.

Improved aquifer characterization and the optimization of the design of brackish groundwater desalination systems

KAUST Repository

Malivaa, Robert G.

2011-07-01

Many water scarce regions possess brackish-water resources that can be desalted to provide alternative water supplies. Brackish groundwater desalination by reverse osmosis (RO) is less expensive than seawater systems because of reduced energy and pretreatment requirements and lesser volumes of concentrate that require disposal. Development of brackish groundwater wellfields include the same hydraulic issues that affect conventional freshwater wellfields. Managing well interference and prevention of adverse impacts such as land subsidence are important concerns. RO systems are designed to treat water whose composition falls within a system-specific envelope of salinities and ion concentrations. A fundamental requirement for the design of brackish groundwater RO systems is prediction of the produced water chemistry at both the start of pumping and after 10-20 years of operation. Density-dependent solute-transport modeling is thus an integral component of the design of brackish groundwater RO systems. The accuracy of groundwater models is dependent upon the quality of the hydrogeological data upon which they are based. Key elements of the aquifer characterization are the determination of the three-dimensional distribution of salinity within the aquifer and the evaluation of aquifer heterogeneity with respect to hydraulic conductivity. It is necessary to know from where in a pumped aquifer (or aquifer zone) water is being produced and the contribution of vertical flow to the produced water. Unexpected, excessive vertical migration (up-coning) of waters that are more saline has adversely impacted some RO systems because the salinity of the water delivered to the system exceeded the system design parameters. Improved aquifer characterization is possible using advanced geophysical techniques, which can, in turn, lead to more accurate solute-transport models. Advanced borehole geophysical logs, such as nuclear magnetic resonance, were run as part of the exploratory test

Radionuclide migration in groundwater. Annual progress report for 1982

International Nuclear Information System (INIS)

Robertson, D.E.; Toste, A.P.; Abel, K.H.; Brodzinski, R.L.

1984-01-01

Research has continued at a low-level waste disposal facility to characterize the physicochemical species of radionuclides migrating in groundwater. This facility consists of an unlined basin and connecting trench which receives effluent water containing low levels of a wide variety of fission and activation products and trace amounts of transuranic radionuclides. The effluent water percolates through the soil and a small fraction of it emerges at seepage springs located some 260 meters from the trench. The disposal basin and trench are very efficient in retaining most of the radionuclides, but trace amounts of a number of radionuclides existing in mobile chemical forms migrate in the groundwater from the trench to the springs. This facility provides the opportunity for characterizing the rates and mechanisms of radionuclide migration in groundwaters, identifying retardation processes, and validating geochemical models. 13 references, 25 figures, 23 tables

Geostatistical analysis of groundwater chemistry in Japan. Evaluation of the base case groundwater data set

Energy Technology Data Exchange (ETDEWEB)

Salter, P.F.; Apted, M.J. [Monitor Scientific LLC, Denver, CO (United States); Sasamoto, Hiroshi; Yui, Mikazu

1999-05-01

information on depth and temperature reduces the number of samples to 7,140. These waters are then screened on the basis of thermal imprints effects (recorded temperature > predicted temperature from geothermal gradient and depth information). These 880 thermally altered waters are used in volcanism scenario analyses. The remaining samples are divided into two groups, groundwaters at < 200m depth and groundwaters > 200m depth. The former group is identified for use in the uplift and erosion scenario (in which the repository may approach closer to the ground surface in the far future due to these two processes). The remaining 950 samples define the deep groundwaters for a potential repository. A subset (560 samples) of the 950 deep samples based on maximum sample depth information is selected by JNC considering rock formation (excluded Quaternary unconsolidate sediments) as the Deep Repository Groundwater Dataset for the PCA/HCA. Combined PCA and HCA of the Deep Repository Groundwater Dataset substantiates three reference groundwater categories: 1) a dilute, Na-HCO3 type groundwater possibly divided into two subtypes based on pH [one with high pH ({approx}8) and one with low pH ({approx}6), 2) a higher temperature ({approx}40degC) moderate ionic strength Na-HCO3 type groundwater with pH between 7 and 9; and 3) a saline (near seawater ionic strength), high pH ({approx}8) brine. Comparison of these results with the proposed hypothetical reference groundwater samples indicates that some of the proposed reference groundwaters do not appear to closely represent any of the categories derived by PCA/HCA for the deep Japanese groundwater data sets used. There may be several reasons for this. First, the initial data set of 15,000 samples does not necessarily represent a complete, uniform coverage of groundwater have been eliminated before PCA/HCA because the samples lacked one of key major chemical variables selected for the analyses (e.g., Na{sup +}). Thus, in order to assure a broad

Influence of intermittent water releases on groundwater chemistry at the lower reaches of the Tarim River, China.

Science.gov (United States)

Chen, Yong-jin; Chen, Ya-ning; Liu, Jia-zhen; Zhang, Er-xun

2009-11-01

Based on the data of the depths and the chemical properties of groundwater, salinity in the soil profile, and the basic information on each delivery of water collected from the years 2000 to 2006, the varied character of groundwater chemistry and related factors were studied. The results confirmed the three stages of the variations in groundwater chemistry influenced by the intermittent water deliveries. The factors that had close relations to the variations in groundwater chemistry were the distances of monitoring wells from the water channel, the depths of the groundwater, water flux in watercourse, and the salinities in soils. The relations between chemical variation and groundwater depths indicated that the water quality was the best with the groundwater varying from 5 to 6 m. In addition, the constructive species in the study area can survive well with the depth of groundwater varying from 5 to 6 m, so the rational depth of groundwater in the lower reaches of the Tarim River should be 5 m or so. The redistribution of salts in the soil profile and its relations to the chemical properties and depths of groundwater revealed the linear water delivery at present combining with surface water supply in proper sections would promote water quality optimized and speed up the pace of ecological restoration in the study area.

Groundwater dependent pools in seasonal and permanent streams in the Clare Valley of South Australia

Directory of Open Access Journals (Sweden)

Erick Bestland

2017-02-01

In this Mediterranean climate with cool wet winters and dry hot summers strong salinity changes (up to 2.5 times due to seasonal cycles of wetting and drying were observed in surface water. Oxygen and hydrogen isotope values from pool sites showed strong evaporative enrichment during the dry season with up to 50% net evaporation calculated. Water isotopes from groundwater, however, cluster at the depleted end of the local meteoric water line and most do not show change despite significant seasonal salinity changes. Strontium isotope values and concentrations from the pools over the one year period do not define a mixing relationship. Instead, most pool sites have unchanging strontium isotope values despite the large seasonal change in salinity indicating strong evaporation of groundwater fed pools during this drought year.

Groundwater recharge studies using isotope-chemical techniques in wadi gharandal, sinai peninsula(E G))

International Nuclear Information System (INIS)

Awad, M.A.A.; Salem, W.M.; Ezzeldin

1999-01-01

Wadi Gharandal lies on southwestern part of sinai peninsula with its outlets into the Gulf of suez. Eight groundwater samples were collected from quaternary aquifer in wadi gharandal to identify the sources of replenishment and evaluation of its water quality. The variation in chemical composition of water samples is due to water-rock interaction and the effect of sea spray. The distribution of chemical species in the examined groundwater samples is controlled by geography and climate conditions prevailing in the area of study. The salinity increase towards the gulf of suez. The isotopic data indicate that precipitation and floods are considered to be the main sources of recharge in this area. The investigated groundwater samples are found to be suitable for irrigation purposes based on sodium adsorption ratio (SAR) and unsuitable for domestic usages due to high salinity and hardness values

Hydrochemical and isotopic characterization of groundwater in the Ghis-Nekor plain (northern Morocco)

Science.gov (United States)

Chafouq, D.; El Mandour, A.; Elgettafi, M.; Himi, M.; Chouikri, I.; Casas, A.

2018-03-01

The coastal aquifer of Ghis-Nekor (Morocco) was studied to identify the major processes causing salinization of groundwater. In fact, a geochemical approach multi tracer (general chemistry and isotopes - δ2H, δ18O-H2O, δ34S, δ18O-SO4) was utilized, with the hydrodynamics to explain the processes responsible for the salinization of groundwater, and for identttifying areas most vulnerable to seawater intrusion. The recharge of the aquifer is mainly by the Al-Khattabi dam, the Nekor River and the Ghis River, on the eastern border of the plain. The water that feeds the aquifer shows a relatively high level of salinity and for this reason, the majority of sampled wells indicate high values of electric conductivity and total salinity which arrives at 7.5 g L-1. The plot of the geochemical results analyzes of groundwater in the Piper diagram shows two distinct chemical facies; sodium chloride-facies and chlorinated calcium and magnesium sulfated facies. The concentrations of 18O range between -4.15‰ and -5.73‰, while the values of 2H range between -28.4‰ and -41.7‰. The Nekor river water is depleted in heavy isotopes, and the isotopic compositions are in the order on -6‰ for 18O and -40.5‰ for deuterium. Most of the wells have a slope <8 indicating a slight evaporation before infiltration. The data show low and variable d-excess values (range from -0.02‰ to 11.6‰), reflect recharge during different climatic conditions. The isotopic concentrations of 18O-SO4 vary between 4.35‰ and 8.60‰, while the 34S isotope values range from -4.3‰ to 9.9‰. For Ghis River, these values are between -4.4‰ and 4.95‰, respectively, for sulfur and oxygen. The interpretation of the chemical and isotopic results suggesting the intrusion of seawater to increase salinity of groundwater in the region is low. However, only the NE area shows probable contamination of seawater. In contrast, wells are saline independent of seawater intrusion, the origin of the high

hydrochemical evolution of groundwater in jimeta- yola area ...

African Journals Online (AJOL)

DJFLEX

development of groundwater resources for water supply ... water business has led to the proliferation of shallow ... Areas liable to flooding ...... by salinization process of the aquifer which act ..... Malaysia. Environmental Geology 56(8): 1721-. 1732. Barcelona, M. J., Gibb, J. P., Helfrich, .... World Health Organization, 1993.

LASTRIG -A Multiple Parametric Method of Assessment of Salinization Vulnerability of a Coastal Aquifer in Pennar Delta, India

Science.gov (United States)

Kesireddy, K.; Mareddy, A.

2007-05-01

Coastal populations are critically dependent upon the coastal aquifers for their freshwater requirements. Excessive withdrawal of groundwater leads to saline incursion and the consequent degradation of quality and quantity of freshwater. The paper describes a multiple parametric method of assessment of vulnerability of the coastal aquifer in Pennar delta, south India, in the context of the hydrogeological, biophysical, geochemical and socioeconomic environments of the delta. Seven parameters, forming the acronym LASTRIG viz. landuse, aquifer type, soil depth, groundwater table, rainfall, soil infiltration and geomorphology are made use in the assessment, and involve the use of remote sensing, GIS and modeling tools. The parameters are weighted, and a suitable ranking system has been designed to quantify the degree of vulnerability of the aquifer for salinization. It has been found that zones with high vulnerability index correlate well with zones of high TDS and chloride contents of groundwater. This observation thus validates the geochemical basis of the proposed LASTRIG system. The new system has been found useful in the management of the groundwater resources of the delta region. It has been made use of identify the aquifer segments which are in danger of being degraded, to enable the decision- makers to design counter measures to avoid further deterioration in water quality. Where the groundwater has already been rendered non-potable because of saline incursion, the LASTRIG index could be made use to identify possible use of that water for drinking by cattle, and for growing of salt-tolerant vegetables (e.g. beetroot and lettuce), and trees (e.g. casuarinas obese, Prosopis juliflora)

Impact of coastal forcing and groundwater recharge on the growth of a fresh groundwater lens in a mega-scale beach nourishment

Science.gov (United States)

Huizer, Sebastian; Radermacher, Max; de Vries, Sierd; Oude Essink, Gualbert H. P.; Bierkens, Marc F. P.

2018-02-01

For a large beach nourishment called the Sand Engine - constructed in 2011 at the Dutch coast - we have examined the impact of coastal forcing (i.e. natural processes that drive coastal hydro- and morphodynamics) and groundwater recharge on the growth of a fresh groundwater lens between 2011 and 2016. Measurements of the morphological change and the tidal dynamics at the study site were incorporated in a calibrated three-dimensional and variable-density groundwater model of the study area. Simulations with this model showed that the detailed incorporation of both the local hydro- and morphodynamics and the actual recharge rate can result in a reliable reconstruction of the growth in fresh groundwater resources. In contrast, the neglect of tidal dynamics, land-surface inundations, and morphological changes in model simulations can result in considerable overestimations of the volume of fresh groundwater. In particular, wave runup and coinciding coastal erosion during storm surges limit the growth in fresh groundwater resources in dynamic coastal environments, and should be considered at potential nourishment sites to delineate the area that is vulnerable to salinization.

Model Prediction of Secondary Soil Salinization in the Keriya Oasis, Northwest China

Directory of Open Access Journals (Sweden)

Jumeniyaz Seydehmet

2018-02-01

Full Text Available Significant anthropogenic and biophysical changes have caused fluctuations in the soil salinization area of the Keriya Oasis in China. The Driver-Pressure-State-Impact-Response (DPSIR sustainability framework and Bayesian networks (BNs were used to integrate information from anthropogenic and natural systems to model the trend of secondary soil salinization. The developed model predicted that light salinization (vegetation coverage of around 15–20%, soil salt 5–10 g/kg of the ecotone will increase in the near term but decelerate slightly in the future, and that farmland salinization will decrease in the near term. This trend is expected to accelerate in the future. Both trends are attributed to decreased water logging, increased groundwater exploitation, and decreased ratio of evaporation/precipitation. In contrast, severe salinization (vegetation coverage of around 2%, soil salt ≥20 g/kg of the ecotone will increase in the near term. This trend will accelerate in the future because decreased river flow will reduce the flushing of severely salinized soil crust. Anthropogenic factors have negative impacts and natural causes have positive impacts on light salinization of ecotones. In situations involving severe farmland salinization, anthropogenic factors have persistent negative impacts.

Salinity of irrigation water in the Philippi farming area of the Cape ...

African Journals Online (AJOL)

Salinity of irrigation water in the Philippi farming area of the Cape Flats, Cape Town, ... Isotope analysis was done for the summer samples so as to assess effects of ... It is concluded that the accumulation of salts in groundwater and soil in the ...

Groundwater flow in a closed basin with a saline shallow lake in a volcanic area: Laguna Tuyajto, northern Chilean Altiplano of the Andes

Energy Technology Data Exchange (ETDEWEB)

Herrera, Christian, E-mail: cherrera@ucn.cl [Departamento de Ciencias Geológicas, Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); Centro de Investigación Tecnológica del Agua en el Desierto (CEITSAZA), Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); Custodio, Emilio [Department of Geo-Engineering, Technical University of Catalonia/Barcelona Tech (UPC), Barcelona (Spain); Chong, Guillermo [Departamento de Ciencias Geológicas, Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); Lambán, Luis Javier [Geological Institute of Spain (IGME), Zaragoza (Spain); Riquelme, Rodrigo; Wilke, Hans [Departamento de Ciencias Geológicas, Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); Jódar, Jorge [Department of Geo-Engineering, Technical University of Catalonia/Barcelona Tech (UPC), Barcelona (Spain); Urrutia, Javier; Urqueta, Harry [Departamento de Ciencias Geológicas, Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); Centro de Investigación Tecnológica del Agua en el Desierto (CEITSAZA), Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); Sarmiento, Alvaro [Departamento de Ciencias Geológicas, Universidad Católica del Norte, Casilla 1280, Antofagasta (Chile); and others

2016-01-15

Laguna Tuyajto is a small, shallow saline water lake in the Andean Altiplano of northern Chile. In the eastern side it is fed by springs that discharge groundwater of the nearby volcanic aquifers. The area is arid: rainfall does not exceed 200 mm/year in the rainiest parts. The stable isotopic content of spring water shows that the recharge is originated mainly from winter rain, snow melt, and to a lesser extent from some short and intense sporadic rainfall events. Most of the spring water outflowing in the northern side of Laguna Tuyajto is recharged in the Tuyajto volcano. Most of the spring water in the eastern side and groundwater are recharged at higher elevations, in the rims of the nearby endorheic basins of Pampa Colorada and Pampa Las Tecas to the East. The presence of tritium in some deep wells in Pampa Colorada and Pampa Las Tecas indicates recent recharge. Gas emission in recent volcanoes increase the sulfate content of atmospheric deposition and this is reflected in local groundwater. The chemical composition and concentration of spring waters are the result of meteoric water evapo-concentration, water–rock interaction, and mainly the dissolution of old and buried evaporitic deposits. Groundwater flow is mostly shallow due to a low permeability ignimbrite layer of regional extent, which also hinders brine spreading below and around the lake. High deep temperatures near the recent Tuyajto volcano explain the high dissolved silica contents and the δ{sup 18}O shift to heavier values found in some of the spring waters. Laguna Tuyajto is a terminal lake where salts cumulate, mostly halite, but some brine transfer to the Salar de Aguas Calientes-3 cannot be excluded. The hydrogeological behavior of Laguna Tuyajto constitutes a model to understand the functioning of many other similar basins in other areas in the Andean Altiplano. - Highlights: • Recent volcanism formations play a key role in producing recharge. • Groundwater can flow across local

Groundwater flow in a closed basin with a saline shallow lake in a volcanic area: Laguna Tuyajto, northern Chilean Altiplano of the Andes

International Nuclear Information System (INIS)

Herrera, Christian; Custodio, Emilio; Chong, Guillermo; Lambán, Luis Javier; Riquelme, Rodrigo; Wilke, Hans; Jódar, Jorge; Urrutia, Javier; Urqueta, Harry; Sarmiento, Alvaro

2016-01-01

Laguna Tuyajto is a small, shallow saline water lake in the Andean Altiplano of northern Chile. In the eastern side it is fed by springs that discharge groundwater of the nearby volcanic aquifers. The area is arid: rainfall does not exceed 200 mm/year in the rainiest parts. The stable isotopic content of spring water shows that the recharge is originated mainly from winter rain, snow melt, and to a lesser extent from some short and intense sporadic rainfall events. Most of the spring water outflowing in the northern side of Laguna Tuyajto is recharged in the Tuyajto volcano. Most of the spring water in the eastern side and groundwater are recharged at higher elevations, in the rims of the nearby endorheic basins of Pampa Colorada and Pampa Las Tecas to the East. The presence of tritium in some deep wells in Pampa Colorada and Pampa Las Tecas indicates recent recharge. Gas emission in recent volcanoes increase the sulfate content of atmospheric deposition and this is reflected in local groundwater. The chemical composition and concentration of spring waters are the result of meteoric water evapo-concentration, water–rock interaction, and mainly the dissolution of old and buried evaporitic deposits. Groundwater flow is mostly shallow due to a low permeability ignimbrite layer of regional extent, which also hinders brine spreading below and around the lake. High deep temperatures near the recent Tuyajto volcano explain the high dissolved silica contents and the δ"1"8O shift to heavier values found in some of the spring waters. Laguna Tuyajto is a terminal lake where salts cumulate, mostly halite, but some brine transfer to the Salar de Aguas Calientes-3 cannot be excluded. The hydrogeological behavior of Laguna Tuyajto constitutes a model to understand the functioning of many other similar basins in other areas in the Andean Altiplano. - Highlights: • Recent volcanism formations play a key role in producing recharge. • Groundwater can flow across local

Groundwater Discharges to Rivers in the Western Canadian Oil Sands Region

Science.gov (United States)

Ellis, J.; Jasechko, S.

2016-12-01

Groundwater discharges into rivers impacts the movement and fate of nutrients and contaminants in the environment. Understanding groundwater-surface water interactions is especially important in the western Canadian oil sands, where groundwater contamination risks are elevated and baseline water chemistry data is lacking, leading to substantial uncertainties about anthropogenic influences on local river quality. High salinity groundwater springs sourced from deep aquifers, comprised of Pleistocene-aged glacial meltwater, are known to discharge into many rivers in the oil sands. Understanding connections between deep aquifers and surficial waterways is important in order to determine natural inputs into these rivers and to assess the potential for injected wastewater or oil extraction fluids to enter surface waters. While these springs have been identified, their spatial distribution along rivers has not been fully characterized. Here we present river chemistry data collected along a number of major river corridors in the Canadian oil sands region. We show that saline groundwater springs vary spatially along the course of these rivers and tend to be concentrated where the rivers incise Devonian- or Cretaceous-aged aquifers along an evaporite dissolution front. Our results suggest that water sourced from Devonian aquifers may travel through bitumen-bearing Cretaceous units and discharge into local rivers, implying a strong groundwater-surface water connection in specialized locations. These findings indicate that oil sands process-affected waters that are injected at depth have the potential to move through these aquifers and reach the rivers at the surface at some time in the future. Groundwater-surface water interactions remain key to understanding the risks oil sands activities pose to aquatic ecosystems and downstream communities.

Identification of saline water intrusion in part of Cauvery deltaic region, Tamil Nadu, Southern India: using GIS and VES methods

Science.gov (United States)

Gnanachandrasamy, G.; Ramkumar, T.; Venkatramanan, S.; Chung, S. Y.; Vasudevan, S.

2016-06-01

We use electrical resistivity data arrayed in a 2715 km2 region with 30 locations to identify the saline water intrusion zone in part of Cauvery deltaic region, offshore Eastern India. From this dataset we are able to derive information on groundwater quality, thickness of aquifer zone, structural and stratigraphic conditions relevant to groundwater conditions, and permeability of aquifer systems. A total of 30 vertical electrode soundings (VES) were carried out by Schlumberger electrode arrangement to indicate complete lithology of this region using curve matching techniques. The electrical soundings exhibited that H and HK type curves were suitable for 16 shallow locations, and QH, KQ, K, KH, QQ, and HA curves were fit for other location. Low resistivity values suggested that saline water intrusion occurred in this region. According to final GIS map, most of the region was severely affected by seawater intrusion due to the use of over-exploitation of groundwater.The deteriorated groundwater resources in this coastal region should raise environmental and health concerns.

Tertiary strata and hydro-geological conditions, figures for movement of groundwater above Gorleben

International Nuclear Information System (INIS)

Giesel, W.

1984-01-01

In order to determine the movement of groundwater, a geo-hydraulic model is used. From the results, one can deduce that the movement of groundwater reaches down to closely above the salt strata, and that groundwater from this depth can flow back to the biosphere after one to several 1000 years. The highly saline water in the depth of the trough is treated separately. Geo-physical borehole measurements have shown that the salty groundwater in the trough moves northwards. 10 3 to 10 4 m 3 of salt/annum are transported away from the trough. (DG) [de

Millennial changes of the Baltic Sea salinity. Studies of the sensitivity of the salinity to climate change

International Nuclear Information System (INIS)

Gustafsson, Bo G.

2004-05-01

An important question for safety assessments of nuclear waste repositories is the salinity of the Baltic Sea under different conditions. The salinity affects the potential recipient ecosystems, the water turnover along the coast and the hydrology as well as the groundwater chemistry. In this report a model that enables computation of the Baltic Sea salinity for different sea level positions and freshwater supplies is presented. The model is used to compute the salinities in Baltic proper, Bothnian Sea and Bothnian Bay for all combinations of global sea level changes from -10 m to 10 m and freshwater supplies from 0 to 60,000 m 3 /s. The results are presented in a series of graphs that enables the reader to make an assessment of the impact of a given climatic change. The model is also used to compute the decrease of the salinity in Bothnian Sea and Bothnian Bay during the next few millennia due to the postglacial uplift. The results show that modest changes in global sea level, say ±1 m, give a salinity change of the order of 1 psu in southern Baltic proper. Changing the freshwater supply with about 2,000 m 3 /s (approximately 10%) gives a similar salinity change. Further, a sea level drop of about 5 m or an increase of the freshwater supply by a factor of 3 is needed to reduce the salinity in southern Baltic proper below 1 psu. In this limit large parts of the Baltic would be limnic. A 50% decrease of the freshwater supply increase the salinity in the southern Baltic proper by a factor of 2 to some 15 psu, but the effect is even more drastic in Bothnian Sea and Bothnian Bay where the salinity increase to 13 and 10 psu, respectively. A less windy climate might have a significant effect in lowering the Baltic salinity due to a combined effect of lowered mixing in Kattegat and lowered exchange between Kattegat and the Baltic. A windier climate will not have such strong effect since increased mixing does not affect the Baltic as much. Most probably the shoreline

Millennial changes of the Baltic Sea salinity. Studies of the sensitivity of the salinity to climate change

Energy Technology Data Exchange (ETDEWEB)

Gustafsson, Bo G. [Oceanus Havsundersoekningar, Goeteborg (Sweden)

2004-05-01

An important question for safety assessments of nuclear waste repositories is the salinity of the Baltic Sea under different conditions. The salinity affects the potential recipient ecosystems, the water turnover along the coast and the hydrology as well as the groundwater chemistry. In this report a model that enables computation of the Baltic Sea salinity for different sea level positions and freshwater supplies is presented. The model is used to compute the salinities in Baltic proper, Bothnian Sea and Bothnian Bay for all combinations of global sea level changes from -10 m to 10 m and freshwater supplies from 0 to 60,000 m{sup 3}/s. The results are presented in a series of graphs that enables the reader to make an assessment of the impact of a given climatic change. The model is also used to compute the decrease of the salinity in Bothnian Sea and Bothnian Bay during the next few millennia due to the postglacial uplift. The results show that modest changes in global sea level, say {+-}1 m, give a salinity change of the order of 1 psu in southern Baltic proper. Changing the freshwater supply with about 2,000 m{sup 3}/s (approximately 10%) gives a similar salinity change. Further, a sea level drop of about 5 m or an increase of the freshwater supply by a factor of 3 is needed to reduce the salinity in southern Baltic proper below 1 psu. In this limit large parts of the Baltic would be limnic. A 50% decrease of the freshwater supply increase the salinity in the southern Baltic proper by a factor of 2 to some 15 psu, but the effect is even more drastic in Bothnian Sea and Bothnian Bay where the salinity increase to 13 and 10 psu, respectively. A less windy climate might have a significant effect in lowering the Baltic salinity due to a combined effect of lowered mixing in Kattegat and lowered exchange between Kattegat and the Baltic. A windier climate will not have such strong effect since increased mixing does not affect the Baltic as much. Most probably the

Identification of the microbes mediating Fe reduction in a deep saline aquifer and their influence during managed aquifer recharge.

Science.gov (United States)

Ko, Myoung-Soo; Cho, Kyungjin; Jeong, Dawoon; Lee, Seunghak

2016-03-01

In this study, indigenous microbes enabling Fe reduction under saline groundwater conditions were identified, and their potential contribution to Fe release from aquifer sediments during managed aquifer recharge (MAR) was evaluated. Sediment and groundwater samples were collected from a MAR feasibility test site in Korea, where adjacent river water will be injected into the confined aquifer. The residual groundwater had a high salinity over 26.0 psu, as well as strong reducing conditions (dissolved oxygen, DOaquifer were found to be Citrobacter sp. However, column experiments to simulate field operation scenarios indicated that additional Fe release would be limited during MAR, as the dominant microbial community in the sediment would shift from Citrobacter sp. to Pseudomonas sp. and Limnohabitans sp. as river water injection alters the pore water chemistry. Copyright © 2015 Elsevier B.V. All rights reserved.

Groundwater flow in a closed basin with a saline shallow lake in a volcanic area: Laguna Tuyajto, northern Chilean Altiplano of the Andes.

Science.gov (United States)

Herrera, Christian; Custodio, Emilio; Chong, Guillermo; Lambán, Luis Javier; Riquelme, Rodrigo; Wilke, Hans; Jódar, Jorge; Urrutia, Javier; Urqueta, Harry; Sarmiento, Alvaro; Gamboa, Carolina; Lictevout, Elisabeth

2016-01-15

Laguna Tuyajto is a small, shallow saline water lake in the Andean Altiplano of northern Chile. In the eastern side it is fed by springs that discharge groundwater of the nearby volcanic aquifers. The area is arid: rainfall does not exceed 200mm/year in the rainiest parts. The stable isotopic content of spring water shows that the recharge is originated mainly from winter rain, snow melt, and to a lesser extent from some short and intense sporadic rainfall events. Most of the spring water outflowing in the northern side of Laguna Tuyajto is recharged in the Tuyajto volcano. Most of the spring water in the eastern side and groundwater are recharged at higher elevations, in the rims of the nearby endorheic basins of Pampa Colorada and Pampa Las Tecas to the East. The presence of tritium in some deep wells in Pampa Colorada and Pampa Las Tecas indicates recent recharge. Gas emission in recent volcanoes increase the sulfate content of atmospheric deposition and this is reflected in local groundwater. The chemical composition and concentration of spring waters are the result of meteoric water evapo-concentration, water-rock interaction, and mainly the dissolution of old and buried evaporitic deposits. Groundwater flow is mostly shallow due to a low permeability ignimbrite layer of regional extent, which also hinders brine spreading below and around the lake. High deep temperatures near the recent Tuyajto volcano explain the high dissolved silica contents and the δ(18)O shift to heavier values found in some of the spring waters. Laguna Tuyajto is a terminal lake where salts cumulate, mostly halite, but some brine transfer to the Salar de Aguas Calientes-3 cannot be excluded. The hydrogeological behavior of Laguna Tuyajto constitutes a model to understand the functioning of many other similar basins in other areas in the Andean Altiplano. Copyright © 2015 Elsevier B.V. All rights reserved.

Predicting salt advection in groundwater from saline aquaculture ponds

Science.gov (United States)

Verrall, D. P.; Read, W. W.; Narayan, K. A.

2009-01-01

SummaryThis paper predicts saltwater advection in groundwater from leaky aquaculture ponds. A closed form solution for the potential function, stream function and velocity field is derived via the series solutions method. Numerically integrating along different streamlines gives the location (or advection front) of saltwater throughout the domain for any predefined upper time limit. Extending this process produces a function which predicts advection front location against time. The models considered in this paper are easily modified given knowledge of the required physical parameters.

Dryland Salinity in the North Stirling Land Conservation District, Western Australia: Simulation and Management Options

Science.gov (United States)

Gomboso, J.; Ghassemi, F.; Appleyard, S. J.

1997-01-01

The North Stirling Land Conservation District consists of approximately 100,000 hectares north of the Stirling Range National Park, Western Australia. Clearing of land for agriculture occurred in the 1960's and early 1970's. The groundwater is highly saline, and, since clearing, the water table has risen by as much as 12 m; it is now generally less than 3 m below ground level throughout the area. The rise in groundwater levels following clearing and the use of crops and pastures requiring low water use have caused dramatic secondary salinisation over a short period of time. Groundwater flow was simulated with models of steady-state and transient groundwater flow. By incorporating economic simulations with the calibrated transient hydrogeological model, estimates of the expected gross margin losses were made. Three salinity-management strategies were simulated. Results indicate that 1) under the `do-nothing' strategy, future gross margins are expected to decline; 2) under the agronomic strategy, the rate of water-table rise would be reduced and foregone agricultural production losses would be less than the `do-nothing' strategy; and 3) under the agroforestry strategy, the water table is expected to decline in the long term, which would increase future agricultural production levels and, hence, profitability.

Identifying the effects of human pressure on groundwater quality to support water management strategies in coastal regions: A multi-tracer and statistical approach (Bou-Areg region, Morocco)

Energy Technology Data Exchange (ETDEWEB)

Re, V., E-mail: re@unive.it [Department of Molecular Sciences and Nanosystems, Ca’ Foscari University of Venice, Calle Larga Santa Marta 2137, Dorsoduro, 40123 Venice (Italy); National Engineering School of Sfax (ENIS) - Laboratory of Radio-Analysis and Environment (LRAE) Sfax (Tunisia); Sacchi, E. [Department of Earth and Environmental Sciences, University of Pavia, Via Ferrata 1, 27100 Pavia (Italy); Mas-Pla, J. [Grup de Geologia Aplicada i Ambiental (GAIA), Centre de Geologia i Cartografia Ambientals (GEOCAMB), Department of Environmental Sciences, University of Girona, 17071 Girona (Spain); Catalan Institute for Water Research (ICRA), 17003 Girona (Spain); Menció, A. [Grup de Geologia Aplicada i Ambiental (GAIA), Centre de Geologia i Cartografia Ambientals (GEOCAMB), Department of Environmental Sciences, University of Girona, 17071 Girona (Spain); El Amrani, N. [Faculty of Sciences and techniques, University Hassan 1er, Settat (Morocco)

2014-12-01

Groundwater pollution from anthropogenic sources is a serious concern affecting several coastal aquifers worldwide. Increasing groundwater exploitation, coupled with point and non-point pollution sources, are the main anthropogenic impacts on coastal environments and are responsible for severe health and food security issues. Adequate management strategies to protect groundwater from contamination and overexploitation are of paramount importance, especially in arid prone regions, where coastal aquifers often represent the main freshwater resource to sustain human needs. The Bou-Areg Aquifer (Morocco) is a perfect example of a coastal aquifer constantly exposed to all the negative externalities associated with groundwater use for agricultural purposes, which lead to a general increase in aquifer salinization. In this study data on 61 water samples, collected in June and November 2010, were used to: (i) track groundwater composition changes related to the use of irrigation water from different sources, (ii) highlight seasonal variations to assess aquifer vulnerability, and (iii) present a reproducible example of multi-tracer approach for groundwater management in rural coastal areas. Hydrogeochemical results show that Bou-Areg groundwater is characterized by – high salinity, associated with a remarkable increase in bicarbonate content in the crop growing season, due to more intense biological activity in irrigated soils. The coupled multi-tracer and statistical analysis confirms the strong dependency on irrigation activities as well as a clear identification of the processes governing the aquifer’s hydrochemistry in the different seasons. Water Rock Interaction (WRI) dominates the composition of most of groundwater samples in the Low Irrigation season (L-IR) and Agricultural Return Flow (ARF) mainly affects groundwater salinization in the High Irrigation season (H-IR) in the same areas naturally affected by WRI. In the central part of the plain River Recharge (RR

Identifying the effects of human pressure on groundwater quality to support water management strategies in coastal regions: A multi-tracer and statistical approach (Bou-Areg region, Morocco)

International Nuclear Information System (INIS)

Re, V.; Sacchi, E.; Mas-Pla, J.; Menció, A.; El Amrani, N.

2014-01-01

Groundwater pollution from anthropogenic sources is a serious concern affecting several coastal aquifers worldwide. Increasing groundwater exploitation, coupled with point and non-point pollution sources, are the main anthropogenic impacts on coastal environments and are responsible for severe health and food security issues. Adequate management strategies to protect groundwater from contamination and overexploitation are of paramount importance, especially in arid prone regions, where coastal aquifers often represent the main freshwater resource to sustain human needs. The Bou-Areg Aquifer (Morocco) is a perfect example of a coastal aquifer constantly exposed to all the negative externalities associated with groundwater use for agricultural purposes, which lead to a general increase in aquifer salinization. In this study data on 61 water samples, collected in June and November 2010, were used to: (i) track groundwater composition changes related to the use of irrigation water from different sources, (ii) highlight seasonal variations to assess aquifer vulnerability, and (iii) present a reproducible example of multi-tracer approach for groundwater management in rural coastal areas. Hydrogeochemical results show that Bou-Areg groundwater is characterized by – high salinity, associated with a remarkable increase in bicarbonate content in the crop growing season, due to more intense biological activity in irrigated soils. The coupled multi-tracer and statistical analysis confirms the strong dependency on irrigation activities as well as a clear identification of the processes governing the aquifer’s hydrochemistry in the different seasons. Water Rock Interaction (WRI) dominates the composition of most of groundwater samples in the Low Irrigation season (L-IR) and Agricultural Return Flow (ARF) mainly affects groundwater salinization in the High Irrigation season (H-IR) in the same areas naturally affected by WRI. In the central part of the plain River Recharge (RR

Transboundary geophysical mapping of geological elements and salinity distribution critical for the assessment of future sea water intrusion in response to sea level rise

Directory of Open Access Journals (Sweden)

F. Jørgensen

2012-07-01

Full Text Available Geophysical techniques are increasingly being used as tools for characterising the subsurface, and they are generally required to develop subsurface models that properly delineate the distribution of aquifers and aquitards, salt/freshwater interfaces, and geological structures that affect groundwater flow. In a study area covering 730 km² across the border between Germany and Denmark, a combination of an airborne electromagnetic survey (performed with the SkyTEM system, a high-resolution seismic survey and borehole logging has been used in an integrated mapping of important geological, physical and chemical features of the subsurface. The spacing between flight lines is 200–250 m which gives a total of about 3200 line km. About 38 km of seismic lines have been collected. Faults bordering a graben structure, buried tunnel valleys, glaciotectonic thrust complexes, marine clay units, and sand aquifers are all examples of geological structures mapped by the geophysical data that control groundwater flow and to some extent hydrochemistry. Additionally, the data provide an excellent picture of the salinity distribution in the area and thus provide important information on the salt/freshwater boundary and the chemical status of groundwater. Although the westernmost part of the study area along the North Sea coast is saturated with saline water and the TEM data therefore are strongly influenced by the increased electrical conductivity there, buried valleys and other geological elements are still revealed. The mapped salinity distribution indicates preferential flow paths through and along specific geological structures within the area. The effects of a future sea level rise on the groundwater system and groundwater chemistry are discussed with special emphasis on the importance of knowing the existence, distribution and geometry of the mapped geological elements, and their control on the groundwater salinity distribution is assessed.

An Investigation of Groundwater Flow on a Coastal Barrier using Multi Electrode Profiling

DEFF Research Database (Denmark)

Poulsen, Søren Erbs; Christensen, Steen; Rasmussen, Keld Rømer

2008-01-01

Preliminary geophysical and hydrogeological investigations indicate that multi-electrode profiling (MEP) can be used to monitor groundwater salinity on a coastal barrier where a shallow thin aquifer discharges to the North Sea. A monitoring system including five groups of piezometers and five MEP...... groundwater modeling we hope to be able to quantify how time varying recharge, tides, and storms hitting the barrier affect groundwater flow and discharge to the sea. At the conference we will present monitoring results from the winter and spring 2008....

Effect of Pumping on Groundwater Levels: A Case Study

Science.gov (United States)

Sindhu, G.; Vijayachandran, Lekshmi

2018-06-01

Groundwater is a major source for drinking and domestic purposes. Nowadays, extensive pumping has become a major issue of concern since pumping has led to rapid decline in the groundwater table, thus imposing landward gradient, leading to saline water intrusion especially in coastal areas. Groundwater pumping has seen its utmost effect on coastal aquifer systems, where the sea-ward gradient gets disturbed due to anthropogenic influences. Hence, a groundwater flow modelling of an aquifer system is essential for understanding the various hydro-geologic conditions, which can be used to study the responses of the aquifer system with regard to various pumping scenarios. Besides, a model helps to predict the water levels for the future period with respect to changing environment. In this study, a finite element groundwater flow model of a coastal aquifer system at Aakulam, Trivandrum district is developed, calibrated and simulated using the software Finite Element subsurface Flow system (FEFLOW 6.2).This simulated model is then used to predict the groundwater levels for a future 5 year period during pre monsoon and post monsoon season.

Effect of Pumping on Groundwater Levels: A Case Study

Science.gov (United States)

Sindhu, G.; Vijayachandran, Lekshmi

2018-03-01

Groundwater is a major source for drinking and domestic purposes. Nowadays, extensive pumping has become a major issue of concern since pumping has led to rapid decline in the groundwater table, thus imposing landward gradient, leading to saline water intrusion especially in coastal areas. Groundwater pumping has seen its utmost effect on coastal aquifer systems, where the sea-ward gradient gets disturbed due to anthropogenic influences. Hence, a groundwater flow modelling of an aquifer system is essential for understanding the various hydro-geologic conditions, which can be used to study the responses of the aquifer system with regard to various pumping scenarios. Besides, a model helps to predict the water levels for the future period with respect to changing environment. In this study, a finite element groundwater flow model of a coastal aquifer system at Aakulam, Trivandrum district is developed, calibrated and simulated using the software Finite Element subsurface Flow system (FEFLOW 6.2).This simulated model is then used to predict the groundwater levels for a future 5 year period during pre monsoon and post monsoon season.

Hydrochemical evaluation of groundwater quality in the Çavuşçayı basin, Sungurlu-Çorum, Turkey

Science.gov (United States)

Çelik, Mehmet; Yıldırım, Turgut

2006-06-01

The purpose of this study is to investigate the quality and usage possibility of groundwater in the Çavuşçayı basin and suggest the best water structure for the groundwater use. Results from hydrochemical analyses reveal that groundwater is mostly affected by salty (Na+ Cl-) waters of the Incik Formation and brackish (Ca2+, Mg2+ SO{4/2-}) waters of the Bayındır Formation. The Alibaba saltpan discharged (2 l/s) from the Incik Formation is used for salt production. In the basin, salinity risk increases with depth and along the groundwater flow direction. Therefore, shallow water and trenches opened in the alluvium aquifer at the east of the basin were determined to yield suitable water with no Na+ and Cl- contamination. Following the heavy rainy period, waters of less salinity and conductivity are possibly used for agriculture.

Development of a coastal drought index using salinity data

Science.gov (United States)

Conrads, Paul; Darby, Lisa S.

2017-01-01

A critical aspect of the uniqueness of coastal drought is the effects on the salinity dynamics of creeks, rivers, and estuaries. The location of the freshwater–saltwater interface along the coast is an important factor in the ecological and socioeconomic dynamics of coastal communities. Salinity is a critical response variable that integrates hydrologic and coastal dynamics including sea level, tides, winds, precipitation, streamflow, and tropical storms. The position of the interface determines the composition of freshwater and saltwater aquatic communities as well as the freshwater availability for water intakes. Many definitions of drought have been proposed, with most describing a decline in precipitation having negative impacts on the water supply. Indices have been developed incorporating data such as rainfall, streamflow, soil moisture, and groundwater levels. These water-availability drought indices were developed for upland areas and may not be ideal for characterizing coastal drought. The availability of real-time and historical salinity datasets provides an opportunity for the development of a salinity-based coastal drought index. An approach similar to the standardized precipitation index (SPI) was modified and applied to salinity data obtained from sites in South Carolina and Georgia. Using the SPI approach, the index becomes a coastal salinity index (CSI) that characterizes coastal salinity conditions with respect to drought periods of higher-saline conditions and wet periods of higher-freshwater conditions. Evaluation of the CSI indicates that it provides additional coastal response information as compared to the SPI and the Palmer hydrologic drought index, and the CSI can be used for different estuary types and for comparison of conditions along coastlines.

The origin of groundwater composition in the Pampeano Aquifer underlying the Del Azul Creek basin, Argentina.

Science.gov (United States)

Zabala, M E; Manzano, M; Vives, L

2015-06-15

The Pampean plain is the most productive region in Argentina. The Pampeano Aquifer beneath the Pampean plain is used mostly for drinking water. The study area is the sector of the Pampeano Aquifer underlying the Del Azul Creek basin, in Buenos Aires province. The main objective is to characterize the chemical and isotopic compositions of groundwater and their origin on a regional scale. The methodology used involved the identification and characterization of potential sources of solutes, the study of rain water and groundwater chemical and isotopic characteristics to deduce processes, the development of a hydrogeochemical conceptual model, and its validation by hydrogeochemical modelling with PHREEQC. Groundwater samples come mostly from a two-depth monitoring network of the "Dr. Eduardo J. Usunoff" Large Plains Hydrology Institute (IHLLA). Groundwater salinity increases from SW to NE, where groundwater is saline. In the upper basin groundwater is of the HCO3-Ca type, in the middle basin it is HCO3-Na, and in the lower basin it is ClSO4-NaCa and Cl-Na. The main processes incorporating solutes to groundwater during recharge in the upper basin are rain water evaporation, dissolution of CO2, calcite, dolomite, silica, and anorthite; cationic exchange with Na release and Ca and Mg uptake, and clay precipitation. The main processes modifying groundwater chemistry along horizontal flow at 30 m depth from the upper to the lower basin are cationic exchange, dissolution of silica and anorthite, and clay precipitation. The origin of salinity in the middle and lower basin is secular evaporation in a naturally endorheic area. In the upper and middle basins there is agricultural pollution. In the lower basin the main pollution source is human liquid and solid wastes. Vertical infiltration through the boreholes annular space during the yearly flooding stages is probably the pollution mechanism of the samples at 30 m depth. Copyright © 2015 Elsevier B.V. All rights reserved.

The origin of groundwater composition in the Pampeano Aquifer underlying the Del Azul Creek basin, Argentina

International Nuclear Information System (INIS)

Zabala, M.E.; Manzano, M.; Vives, L.

2015-01-01

The Pampean plain is the most productive region in Argentina. The Pampeano Aquifer beneath the Pampean plain is used mostly for drinking water. The study area is the sector of the Pampeano Aquifer underlying the Del Azul Creek basin, in Buenos Aires province. The main objective is to characterize the chemical and isotopic compositions of groundwater and their origin on a regional scale. The methodology used involved the identification and characterization of potential sources of solutes, the study of rain water and groundwater chemical and isotopic characteristics to deduce processes, the development of a hydrogeochemical conceptual model, and its validation by hydrogeochemical modelling with PHREEQC. Groundwater samples come mostly from a two-depth monitoring network of the “Dr. Eduardo J. Usunoff” Large Plains Hydrology Institute (IHLLA). Groundwater salinity increases from SW to NE, where groundwater is saline. In the upper basin groundwater is of the HCO 3 -Ca type, in the middle basin it is HCO 3 -Na, and in the lower basin it is ClSO 4 –NaCa and Cl–Na. The main processes incorporating solutes to groundwater during recharge in the upper basin are rain water evaporation, dissolution of CO 2 , calcite, dolomite, silica, and anorthite; cationic exchange with Na release and Ca and Mg uptake, and clay precipitation. The main processes modifying groundwater chemistry along horizontal flow at 30 m depth from the upper to the lower basin are cationic exchange, dissolution of silica and anorthite, and clay precipitation. The origin of salinity in the middle and lower basin is secular evaporation in a naturally endorheic area. In the upper and middle basins there is agricultural pollution. In the lower basin the main pollution source is human liquid and solid wastes. Vertical infiltration through the boreholes annular space during the yearly flooding stages is probably the pollution mechanism of the samples at 30 m depth. - Highlights: • The work studies the

The origin of groundwater composition in the Pampeano Aquifer underlying the Del Azul Creek basin, Argentina

Energy Technology Data Exchange (ETDEWEB)

Zabala, M.E., E-mail: mzabala@faa.unicen.edu.ar [Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Av. Rivadavia 1917, C1033AAJ Ciudad Autónoma de Buenos Aires (Argentina); Instituto de Hidrología de Llanuras “Dr. Eduardo J. Usunoff”, Av. República Italia 780, 7300 Azul, Provincia Buenos Aires (Argentina); Manzano, M., E-mail: marisol.manzano@upct.es [Escuela de Ingeniería de Caminos, Canales y Puertos y de Ingeniería de Minas, Universidad Politécnica de Cartagena, P° de Alfonso XIII 52, E-30203 Cartagena (Spain); Vives, L., E-mail: lvives@faa.unicen.edu.ar [Instituto de Hidrología de Llanuras “Dr. Eduardo J. Usunoff”, Av. República Italia 780, 7300 Azul, Provincia Buenos Aires (Argentina)

2015-06-15

The Pampean plain is the most productive region in Argentina. The Pampeano Aquifer beneath the Pampean plain is used mostly for drinking water. The study area is the sector of the Pampeano Aquifer underlying the Del Azul Creek basin, in Buenos Aires province. The main objective is to characterize the chemical and isotopic compositions of groundwater and their origin on a regional scale. The methodology used involved the identification and characterization of potential sources of solutes, the study of rain water and groundwater chemical and isotopic characteristics to deduce processes, the development of a hydrogeochemical conceptual model, and its validation by hydrogeochemical modelling with PHREEQC. Groundwater samples come mostly from a two-depth monitoring network of the “Dr. Eduardo J. Usunoff” Large Plains Hydrology Institute (IHLLA). Groundwater salinity increases from SW to NE, where groundwater is saline. In the upper basin groundwater is of the HCO{sub 3}-Ca type, in the middle basin it is HCO{sub 3}-Na, and in the lower basin it is ClSO{sub 4}–NaCa and Cl–Na. The main processes incorporating solutes to groundwater during recharge in the upper basin are rain water evaporation, dissolution of CO{sub 2}, calcite, dolomite, silica, and anorthite; cationic exchange with Na release and Ca and Mg uptake, and clay precipitation. The main processes modifying groundwater chemistry along horizontal flow at 30 m depth from the upper to the lower basin are cationic exchange, dissolution of silica and anorthite, and clay precipitation. The origin of salinity in the middle and lower basin is secular evaporation in a naturally endorheic area. In the upper and middle basins there is agricultural pollution. In the lower basin the main pollution source is human liquid and solid wastes. Vertical infiltration through the boreholes annular space during the yearly flooding stages is probably the pollution mechanism of the samples at 30 m depth. - Highlights: • The

The Use of gamma-Irradiation in Counteracting the Effect of Salinity for Cultivation of Barley and Pea Plants

International Nuclear Information System (INIS)

Aly, M.A.S.; Afifi, L.M.; Kamel, H.A.; Mostafa, I.Y.; Kord, M.A.

2000-01-01

The biochemical changes induced by salinity in two economic plants (Barley and Pea) and the probable counteraction of gamma irradiation for enhancement of growth were studied. The data obtained revealed that the reduction in pigments content due to salinity treatment was more pronounced in pea plants than barley. However, gamma irradiation caused a significant increase in pigment content of both plants. The interaction effect of salinity and radiation varied from an increase in case of barley to a reduction in peas. In both plants, soluble sugars content increased due to salinity and /or gamma-radiation. Moreover, total carbohydrates increased due to the combined treatment. A matched increase in free proline content was recorded with increase of salinity. While, gamma-irradiation showed a different trend. Protein and nucleic acids contents were proportionally decreased with increase of salinity levels, whereas gamma radiation induced an increase in both protein and nucleic acids content. A progressive reduction in the yield by increasing salinity was observed, while gamma-irradiation increased the yield of both plants. 14 CO 2 fixation was reduced by salinity treatment while gamma-radiation increased it. Contrary to 14 CO 2 fixation, salinity enhanced respiration, while radiation retarded it

Effect of punping on temporal changes in groundwater quality

NARCIS (Netherlands)

Kamra, S.K.; Khajanchi Lal,; Singh, O.P.; Boonstra, J.

2002-01-01

Pumping studies were conducted at five sites distributed over a 3000 ha area in the Gohana block in Haryana state of India. The project area is a part of the Indo-Gangetic plain and lies in a topographical depression susceptible to waterlogging, soil salinity and groundwater pollution from

Uranium and Cesium sorption to bentonite colloids in high salinity and carbonate-rich environments: Implications for radionuclide transport

Science.gov (United States)

Tran, E. L.; Teutsch, N.; Klein-BenDavid, O.; Weisbrod, N.

2017-12-01

When radionuclides are leaked into the subsurface due to engineered waste disposal container failure, the ultimate barrier to migration of radionuclides into local aquifers is sorption to the surrounding rock matrix and sediments, which often includes a bentonite backfill. The extent of this sorption is dependent on pH, ionic strength, surface area availability, radionuclide concentration, surface mineral composition, and solution chemistry. Colloidal-sized bentonite particles eroded from the backfill have been shown to facilitate the transport of radionuclides sorbed to them away from their source. Thus, sorption of radionuclides such as uranium and cesium to bentonite surfaces can be both a mobilization or retardation factor. Though numerous studies have been conducted to-date on sorption of radionuclides under low ionic strength and carbonate-poor conditions, there has been little research conducted on the behavior of radionuclides in high salinities and carbonate rich conditions typical of aquifers in the vicinity of some potential nuclear repositories. This study attempts to characterize the sorption properties of U(VI) and Cs to bentonite colloids under these conditions using controlled batch experiments. Results indicated that U(VI) undergoes little to no sorption to bentonite colloids in a high-salinity (TDS= 9000 mg/L) artificial groundwater. This lack of sorption was attributed to the formation of CaUO2(CO3)22- and Ca2UO2(CO3)3 aqueous ions which stabilize the UO22+ ions in solution. In contrast, Cs exhibited greater sorption, the extent to which was influenced greatly by the matrix water's ionic strength and the colloid concentration used. Surprisingly, when both U and Cs were together, the presence of U(VI) in solution decreased Cs sorption, possibly due to the formation of stabilizing CaUO2(CO3)22- anions. The implications of this research are that rather than undergoing colloid-facilitated transport, U(VI) is expected to migrate similarly to a

Basic characteristic test of buffer/backfill material under Horonobe groundwater condition

International Nuclear Information System (INIS)

Kikuchi, Hirohito; Tanai, Kenji

2005-02-01

By the second progress report (H12) on research and development for the geological disposal of high-level radioactive waste (HLW) in Japan, Japan Nuclear Cycle Development Institute (JNC) extended the data base of basic properties of compacted bentonite which were mainly obtained by using distilled water as test fluid. This report presents influence of Horonobe groundwater on the basic properties of buffer and backfill material. The Horonobe groundwater is a type of saline groundwater. The groundwater was sampled at GL-300 m or deeper by using bore hole HDB-6 of the underground laboratory of Horonobe site. In addition, basic properties are also obtained by using distilled water, synthetic seawater, and NaCl solution. Experimental results are as follows; 1) Swelling characteristics, hydraulic characteristics and mechanical characteristics of the buffer material and backfill material decrease by the influence of saline water. The relationship between effective clay density and swelling stress is described by the following equation. σ = exp (2.5786ρ b 3 - 12.238ρ b 2 + 21.818ρ b - 14.035) where σ is swelling stress [MPa], ρ b is effective clay density [Mg/m 3 ]. The relationship between effective clay density and intrinsic permeability is described by the following equation. κ = exp (-41.466 + 4.316ρ b - 4.069ρ b 2 ) where κ is intrinsic permeability [m 2 ], ρ b is effective clay density [Mg/m 3 ]. The relationship between effective clay density and unconfined compressive strength is described by the following equation. qu = 1.4 x 10 -4 exp (5.637ρ b ) where qu is unconfined compressive strength [MPa], ρ b is effective clay density [Mg/m 3 ]. 2) Saline water doesn't influence the thermal characteristic of the buffer material. The thermal conductivity and specific heat are derived by using the relationship that was obtained so far. (author)

Geoelectric imaging for saline water intrusion in Geopark zone of Ciletuh Bay, Indonesia

Science.gov (United States)

Ardi, N. D.; Iryanti, M.; Asmoro, C. P.; Yusuf, A.; Sundana, A. N. A.; Safura, H. Y.; Fitri, M.; Anggraeni, M.; Kurniawan, R.; Afrianti, R.; Sumarni

2018-05-01

Saline water intrusion in estuary is an urgent ecological encounter across the world. The Ciletuh Bay, located in the southern Sukabumi district, is an area with high cultivated potential becoming one of the most important geology tourism zones in Indonesia. However, salt water intrusion along the creek is a natural spectacle that disturbs the economic growth of the whole region. This research was intended at plotting the subsurface level of saltwater interventions into aquifers at the northern part of Ciletuh creek, Indonesia. The study implemented geoelectric imaging methods. 37 imaging datum were acquired using Wenner array configuration. The saline water were identified across the study area. The result of two dimensional cross-sectional resistivity shows that there is an indication of sea content in our measured soil, i.e. the smallest resistivity value is 0.579 Ωm found at a depth of 12.4 m to 19.8 m at a track length of 35 m to 60 m is categorized in the clayey which shows low groundwater quality. However, when compared with the results of direct observation of groundwater from the wells of residents, the water obtained is brackish water. A water chemistry test is conducted to ascertain the initial results of this method so that a potential sea intrusion potential map can be interpreted more clearly. This can consequently help as an extrapolative model to define depth to saline water at any site within the saline water zone in the study area.

Dissolution of unirradiated UO{sub 2} fuel in synthetic groundwater. Final report (1996-1998)

Energy Technology Data Exchange (ETDEWEB)

Ollila, K. [VTT Chemical Technology, Espoo (Finland)

1999-05-01

This study was a part of the EU R and D programme 1994-1998: Nuclear Fission Safety, entitled `Source term for performance assessment of spent fuel as a waste form`. The research carried out at VTT Chemical Technology was focused on the effects of granitic groundwater composition and redox conditions on UO{sub 2} solubility and dissolution mechanisms. The synthetic groundwater compositions simulated deep granitic fresh and saline groundwaters, and the effects of the near-field material, bentonite, on very saline groundwater. Additionally, the Spanish granite/bentonite water was used. The redox conditions (Eh), which are obviously the most important factors that influence on UO{sub 2} solubility under the disposal conditions of spent fuel, varied from strongly oxidising (air-saturated), anaerobic (N{sub 2}, O{sub 2} < l ppm) to reducing (N{sub 2}, low Eh). The objective of the air-saturated dissolution experiments was to yield the maximum solution concentrations of U, and information on the formation of secondary phases that control the concentrations, with different groundwater compositions. The static batch solubility experiments of long duration (up to 1-2 years) were performed using unirradiated UO{sub 2} pellets and powder. Under anaerobic and reducing conditions, the solubilities were also approached from oversaturation. The results of the oxic, air-saturated dissolution experiments with UO{sub 2} powder showed that the increase in the salinity (< 1.7 M) had a minor effect on the measured steady-state concentrations of U. The concentrations, (1.2 ...2.5) x 10{sup -5} M, were at the level of the theoretical solubility of schoepite or another uranyl oxide hydrate, e.g. becquerelite (possibly Na-polyuranate). The higher alkalinity of the fresh (Allard) composition increased the aqueous U concentration. Only some kind of oxidised U-phase (U{sub 3}O{sub 8}-UO{sub 3}) was identified with XRD when studying possible secondary phases after the contact time of one year

Environmental impact of municipal dumpsite leachate on ground-water quality in Jawaharnagar, Rangareddy, Telangana, India

Science.gov (United States)

Soujanya Kamble, B.; Saxena, Praveen Raj

2017-10-01

The aim of the present work was to study the impact of dumpsite leachate on ground-water quality of Jawaharnagar village. Leachate and ground-water samples were investigated for various physico-chemical parameters viz., pH, total dissolved solids (TDS), total hardness (TH), calcium (Ca2+), magnesium (Mg2+), sodium (Na+), potassium (K+), chloride (Cl-), carbonates (CO3 2-), bicarbonates (HCO3 -), nitrates (NO3 -), and sulphates (SO4 2-) during dry and wet seasons in 2015 and were reported. The groundwater was hard to very hard in nature, and the concentrations of total dissolved solids, chlorides, and nitrates were found to be exceeding the permissible levels of WHO drinking water quality standards. Piper plots revealed that the dominant hydrochemical facies of the groundwater were of calcium chloride (CaCl2) type and alkaline earths (Ca2+ and Mg2+) exceed the alkali (Na+ and SO4 2-), while the strong acids (Cl- and SO4 2-) exceed the weak acids (CO3 2- and HCO3 -). According to USSL diagram, all the ground-water samples belong to high salinity and low-sodium type (C3S1). Overall, the ground-water samples collected around the dumpsite were found to be polluted and are unfit for human consumption but can be used for irrigation purpose with heavy drainage and irrigation patterns to control the salinity.

Geophysical and Seawater intrusion models to distinguish Modern and Palaeo salinity in the Central Godvari Delta, Andhra Pradesh, India

Science.gov (United States)

Lagudu, S.; Nandan, M. J.; Durgaprasad, M.; Gurunadha Rao, V. V. S.

2015-12-01

Central Godavari Delta is located in the East coast of Andhra Pradesh along Bay of Bengal. Ample surface water is made available for irrigation and aqua culture through well distributed canals drawn from Godavari River since last 150 years. Groundwater in the area is highly saline though the groundwater levels are very shallow ranging from 1 to 3 m below ground level. Integrated Electrical Resistivity Tomograms (ERT), hydrochemical (pH, TDS, Ca2+, Mg2+, K+, F-, Cl-, SO42-, NO3-, HCO3- and CO3-), isotopic (Br- and δ18O ) and density dependant solute tranport (SEAWAT) modelling studies have been carried out for four years (2006, 2007, 2014 and 2015) to identify the salinity sources and to understand the possible extent of seawater intrusion. The integration of all these data sets revealed that coarse grained sands exhibits resistivity of 4-20 Ωm forming the surface layer, clay layer exhibits Na2++ K+) and (Ca2++Mg2+), (Na+-Cl- ) vs. Ca2++Mg2+-HCO3--SO42-)) and ionic ratios ( Na2+/Cl-, SO42-/Cl-, Mg2+/Ca2+, Mg2+/Cl- and Cl-/Br) and δ18O does not reflect any modern seawater signatures. These models indicated that salinity in the shallow wells is due to dissolution of evaporitic minerals and ion exchange processes. In the pumping wells the salinity is due to upconing of entrapped sea water that belongs to Palaeo origin and wells located near the coast and mudflats is due to physical mixing of marine water. The estimated regional groundwater balance using SEAWAT model indicate significant amount of submarine groundwater discharge as outfall to the Bay of Bengal. Assuming observed hydrological conditions, no considerable advance in seawater intrusion would be expected into the delta region.

Groundwater management in northern Iraq

Science.gov (United States)

Stevanovic, Zoran; Iurkiewicz, Adrian

2009-03-01

Groundwater is vital and the sole resource in most of the studied region of northern Iraq. It has a significant role in agriculture, water supply and health, and the elimination of poverty in rural areas. Although Iraq is currently dramatically disturbed by complex political and socio-economic problems, in its northern part, i.e. the Kurdish-inhabited region, fast urbanization and economic expansion are visible everywhere. Monitoring and water management schemes are necessary to prevent aquifer over-exploitation in the region. Artificial recharge with temporary runoff water, construction of subsurface dams and several other aquifer management and regulation measures have been designed, and some implemented, in order to improve the water situation. Recommendations, presented to the local professionals and decision-makers in water management, include creation of Water Master Plans and Water User Associations, synchronization of drilling programmes, rehabilitation of the existing well fields, opening of new well fields, and the incorporation of new spring intakes in some areas with large groundwater reserves, as well as construction of numerous small-scale schemes for initial in situ water treatment where saline groundwater is present.

Groundwater: A review of the 1989 literature

International Nuclear Information System (INIS)

Miller, C.T.; Mayer, A.S.

1990-01-01

This review was prepared under the auspices of the WPCF Research Committee of the annual Literature Review issue of the Journal; because of logistical reasons it could not be published in June. However, in view of the growing importance of the subject, the review is presented here as a supplement to the June Literature Review issue that has not been through the Journal peer review process. In this review, distinctions are made between single-, two-, and three-phase systems. Single-phase systems refer to groundwater systems subjected to saturated flow conditions, whereas the two- and three-phase systems include groundwater systems subjected to unsaturated flow conditions, or conditions influenced by immiscible organic fluids such as petroleum products. Within the single-, two-, and three-phase system categories, subdivisions are made between physical, chemical, or biological processes such as hydrodynamics, sorption/desorption, chemical reactions, and biodegradation. Specialized areas such as radon and radionuclide transport, facilitated transport, and saline groundwaters also are treated separately. Rounding out this year's review, papers concerning groundwater quality monitoring, remediation, and management are discussed

The assessment of groundwater geochemistry of some wells in Rafsanjan plain, Iran

Directory of Open Access Journals (Sweden)

Milad Mirzaei Aminiyan

2016-07-01

Full Text Available Water quality is the critical factor that influence on human health and quantity and quality of grain production in semi-humid and semi-arid area. Groundwater and irrigation water quality play important roles in main production this crop. For this purpose, 94 well water samples were taken from 25 wells and samples analyzed. The results showed that four main types of water were found: Na-Cl, K-Cl, Na-SO4, and K-SO4. It seems that most wells in terms of water quality (salinity and alkalinity and based on Wilcox diagram have critical status. The analysis suggested that more than 87% of the well water samples have high values of EC that these values are higher than into critical limit EC value for irrigation water, which may be due to the sandy soils in this area. Most groundwater were relatively unsuitable for irrigation but it could be used by application of correct management such as removing and reducing the ion concentrations of Cl‾, SO42‾, Na+ and total hardness in groundwater and also the concentrated deep groundwater was required treatment to reduce the salinity and sodium hazard. Given that irrigation water quality in this area was relatively unsuitable for most agriculture production but pistachio tree was adapted to this area conditions. The integrated management of groundwater for irrigation is the way to solve water quality issues not only in Rafsanjan area, but also in other arid and semi-arid areas.

Transboundary geophysical mapping of geological elements and salinity distribution critical for the assessment of future sea water intrusion in response to sea level rise

DEFF Research Database (Denmark)

Joergensen, F.; Scheer, W.; Thomsen, S.

2012-01-01

Geophysical techniques are increasingly being used as tools for characterising the subsurface, and they are generally required to develop subsurface models that properly delineate the distribution of aquifers and aquitards, salt/freshwater interfaces, and geological structures that affect......, and sand aquifers are all examples of geological structures mapped by the geophysical data that control groundwater flow and to some extent hydrochemistry. Additionally, the data provide an excellent picture of the salinity distribution in the area and thus provide important information on the salt...... revealed. The mapped salinity distribution indicates preferential flow paths through and along specific geological structures within the area. The effects of a future sea level rise on the groundwater system and groundwater chemistry are discussed with special emphasis on the importance of knowing...

Using radon-222 to study coastal groundwater/surface-water interaction in the Crau coastal aquifer (southeastern France)

Science.gov (United States)

Mayer, Adriano; Nguyen, Bach Thao; Banton, Olivier

2016-11-01

Radon has been used to determine groundwater velocity and groundwater discharge into wetlands at the southern downstream boundary of the Crau aquifer, southeastern France. This aquifer constitutes an important high-quality freshwater resource exploited for agriculture, industry and human consumption. An increase in salinity occurs close to the sea, highlighting the need to investigate the water balance and groundwater behavior. Darcy velocity was estimated using radon activities in well waters according to the Hamada "single-well method" (involving comparison with radon in groundwater in the aquifer itself). Measurements done at three depths (7, 15 and 21 m) provided velocity ranging from a few mm/day to more than 20 cm/day, with highest velocities observed at the 15-m depth. Resulting hydraulic conductivities agree with the known geology. Waters showing high radon activity and high salinity were found near the presumed shoreline at 3,000 years BP, highlighting the presence of ancient saltwater. Radon activity has also been measured in canals, rivers and ponds, to trace groundwater discharges and evaluate water balance. A model of the radon spatial evolution explains the observed radon activities. Groundwater discharge to surface water is low in pond waters (4 % of total inputs) but significant in canals (55 l/m2/day).

Modelling of thermally driven groundwater flow in a facility for disposal of spent nuclear fuel in deep boreholes

Energy Technology Data Exchange (ETDEWEB)

Marsic, Nico; Grundfelt, Bertil [Kemakta Konsult AB, Stockholm (Sweden)

2013-09-15

In this report calculations are presented of buoyancy driven groundwater flow caused by the emission of residual heat from spent nuclear fuel deposited in deep boreholes from the ground surface in combination with the natural geothermal gradient. This work has been conducted within SKB's programme for evaluation of alternative methods for final disposal of spent nuclear fuel. The basic safety feature of disposal of spent nuclear fuel in deep boreholes is that the groundwater at great depth has a higher salinity, and hence a higher density, than more superficial groundwater. The result of this is that the deep groundwater becomes virtually stagnant. The study comprises analyses of the effects of different inter-borehole distances as well as the effect of different permeabilities in the backfill and sealing materials in the borehole and of different shapes of the interface between fresh and saline groundwater. The study is an update of a previous study published in 2006. In the present study, the facility design proposed by Sandia National Laboratories has been studied. In this design, steel canisters containing two BWR elements or one PWR element are stacked on top of each other between 3 and 5 kilometres depth. In order to host all spent fuel from the current Swedish nuclear programme, about 80 such holes are needed. The model used in this study comprises nine boreholes spaced 100 metres alternatively 50 metres apart in a 3{Chi}3 matrix. In one set of calculations the salinity in the groundwater was assumed to increase from zero above 700 metres depth to 10% by weight at 1500 metres depth and below. In another set, a sharper salinity gradient was applied in which the salinity increased from 0 to 10% between 1400 and 1500 metres depth. A geothermal gradient of 16 deg C/km was applied. The heat output from the spent fuel was assumed to decrease by time in manner consistent with the radioactive decay in the fuel. When the inter-borehole distance decreased from

Synthetic organic compounds and their transformation products in groundwater: occurrence, fate and mitigation.

Science.gov (United States)

Postigo, Cristina; Barceló, Damià

2015-01-15

Groundwater constitutes the main source of public drinking water supply in many regions. Thus, the contamination of groundwater resources by organic chemicals is a matter of growing concern because of its potential effects on public health. The present manuscript compiles the most recent works related to the study of synthetic organic compounds (SOCs) in groundwater, with special focus on the occurrence of contaminants not or barely covered by previously published reviews, e.g., pesticide and pharmaceutical transformation products, lifestyle products, and industrial chemicals such as corrosion inhibitors, brominated and organophosphate flame retardants, plasticizers, volatile organic compounds (VOCs), and polycyclic aromatic hydrocarbons (PAHs). Moreover, the main challenges in managed aquifer recharge, i.e., reclaimed water injection and infiltration, and riverbank filtration, regarding natural attenuation of organic micropollutants are discussed, and insights into the future chemical quality of groundwater are provided. Copyright © 2014 Elsevier B.V. All rights reserved.

Anaerobic oxidation of methane by sulfate in hypersaline groundwater of the Dead Sea aquifer

Science.gov (United States)

Avrahamov, N; Antler, G; Yechieli, Y; Gavrieli, I; Joye, S B; Saxton, M; Turchyn, A V; Sivan, O

2014-01-01

Geochemical and microbial evidence points to anaerobic oxidation of methane (AOM) likely coupled with bacterial sulfate reduction in the hypersaline groundwater of the Dead Sea (DS) alluvial aquifer. Groundwater was sampled from nine boreholes drilled along the Arugot alluvial fan next to the DS. The groundwater samples were highly saline (up to 6300 mm chlorine), anoxic, and contained methane. A mass balance calculation demonstrates that the very low δ13CDIC in this groundwater is due to anaerobic methane oxidation. Sulfate depletion coincident with isotope enrichment of sulfur and oxygen isotopes in the sulfate suggests that sulfate reduction is associated with this AOM. DNA extraction and 16S amplicon sequencing were used to explore the microbial community present and were found to be microbial composition indicative of bacterial sulfate reducers associated with anaerobic methanotrophic archaea (ANME) driving AOM. The net sulfate reduction seems to be primarily controlled by the salinity and the available methane and is substantially lower as salinity increases (2.5 mm sulfate removal at 3000 mm chlorine but only 0.5 mm sulfate removal at 6300 mm chlorine). Low overall sulfur isotope fractionation observed (34ε = 17 ± 3.5‰) hints at high rates of sulfate reduction, as has been previously suggested for sulfate reduction coupled with methane oxidation. The new results demonstrate the presence of sulfate-driven AOM in terrestrial hypersaline systems and expand our understanding of how microbial life is sustained under the challenging conditions of an extremely hypersaline environment. PMID:25039851

Simulation of groundwater flow pathlines and freshwater/saltwater transition zone movement, Manhasset Neck, Nassau County, New York

Science.gov (United States)

Misut, Paul; Aphale, Omkar

2014-01-01

A density-dependent groundwater flow and solute transport model of Manhasset Neck, Long Island, New York, was used to analyze (1) the effects of seasonal stress on the position of the freshwater/saltwater transition zone and (2) groundwater flowpaths. The following were used in the simulation: 182 transient stress periods, representing the historical record from 1920 to 2011, and 44 transient stress periods, representing future hypothetical conditions from 2011 to 2030. Simulated water-level and salinity (chloride concentration) values are compared with values from a previously developed two-stress-period (1905–1944 and 1945–2005) model. The 182-stress-period model produced salinity (chloride concentration) values that more accurately matched the observed salinity (chloride concentration) values in response to hydrologic stress than did the two-stress-period model, and salinity ranged from zero to about 3 parts per thousand (equivalent to zero to 1,660 milligrams per liter chloride). The 182-stress-period model produced improved calibration statistics of water-level measurements made throughout the study area than did the two-stress-period model, reducing the Lloyd aquifer root mean square error from 7.0 to 5.2 feet. Decreasing horizontal and vertical hydraulic conductivities (fixed anisotropy ratio) of the Lloyd and North Shore aquifers by 20 percent resulted in nearly doubling the simulated salinity(chloride concentration) increase at Port Washington observation well N12508. Groundwater flowpath analysis was completed for 24 production wells to delineate water source areas. The freshwater/saltwater transition zone moved toward and(or) away from wells during future hypothetical scenarios.

Spatiotemporal Distribution of Soil Moisture and Salinity in the Taklimakan Desert Highway Shelterbelt

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Yuan Huang

2015-08-01

Full Text Available Salinization and secondary salinization often appear after irrigation with saline water. The Taklimakan Desert Highway Shelterbelt has been irrigated with saline ground water for more than ten years; however, soil salinity in the shelterbelt has not been evaluated. The objective of this study was to analyze the spatial and temporal distribution of soil moisture and salinity in the shelterbelt system. Using a non-uniform grid method, soil samples were collected every two days during one ten-day irrigation cycle in July 2014 and one day in spring, summer, and autumn. The results indicated that soil moisture declined linearly with time during the irrigation cycle. Soil moisture was greatest in the southern and eastern sections of the study area. In contrast to soil moisture, soil electrical conductivity increased from 2 to 6 days after irrigation, and then gradually decreased from 6 to 8 days after irrigation. Soil moisture was the greatest in spring and the least in summer. In contrast, soil salinity increased from spring to autumn. Long time drip-irrigation with saline groundwater increased soil salinity slightly. The soil salt content was closely associated with soil texture. The current soil salt content did not affect plant growth, however, the soil in the shelterbelt should be continuously monitored to prevent salinization in the future.

Monitoring of heavy metal pollution of groundwater in a phreatic aquifer in Mersin-Turkey.

Science.gov (United States)

Demirel, Z

2007-09-01

In this study, heavy metal contents of groundwater from the Mersin aquifer were determined with photometric methods and used to determine the main factors controlling the pollution of groundwater in the area. Using MapInfo GIS software, spatial analysis and integration were carried out for mapping drinking water quality in the basin. From the photometric heavy metal analysis, it is inferred that the excess concentration of Fe, Ni, Mn, Mo and Cu at some locations is the cause of undesirable quality for drinking purposes. Similarly, the EC thematic map shows that considerable areas in the basin are having high salinity hazards. The reason for excess concentration of various heavy metals is the industrial activities and petroleum pipelines and salinity levels show the sea water intrusion.

Chemical and radiochemical characteristics of groundwater in the Culebra Dolomite, southeastern New Mexico

International Nuclear Information System (INIS)

Chapmen, J.B.

1988-03-01

The nation's first geologic repository for radioactive waste is being excavated in southeastern New Mexico at the Waste Isolation Pilot Plant (WIPP). Post-closure radioactive release scenarios from WIPP often involve hydrologic transport of radionuclides through the overlying Rustler Formation, in the Culebra Dolomite Member. The Environmental Evaluation Group (EEG) has conducted an investigation of the chemistry of culebra groundwater. Analysis revealed the following: salinities in Culebra groundwater generally increase from west to east; a Na-Cl type water dominates over most of the sampled area with a Ca-SO 4 type occurring in the southern to southwestern area; exclusive of the low-salinity southern area, most wells located on the same general flow path have similar ion ratios; dissolved uranium content in Culebra groundwater is relatively high, with marked disequilibrium between U-238 and U-234 activities; Ra-226 and Ra-228 are sometimes present in relatively large amounts; Th-228 was detected in samples from 5 wells; and Cs-137 was detected in several samples. 39 refs., 21 figs., 2 tabs

Investigation of the groundwater composition at potential radioactive waste disposal sites in Sweden

International Nuclear Information System (INIS)

Wikberg, P.T.

1984-02-01

Within an investigation program of sites suitable for an underground repository for spent nuclear fuel the groundwater has been characterized. Until now seven areas have been investigated. The groundwater has been pumped up from several isolated sections at depth of 100 m to 600 m in boreholes in each area. Each test section has been pumped continuously for at least two weeks. During the pumping period the water was characterized in the field and sampled for later analysis. Most of the characterized waters are non saline and the concentration of the different constituents varies within a rather narrow interval. Saline waters with much higher concentrations of chloride, sulphate, sodium and calcium have been encountered. The groundwater characterization includes field monitoring of the physico-chemical parameters pH, redox potential, free sulphide concentration, dissolved oxygen concentration and conductivity. These parameters are measured in a flow through cell where the water passes before coming in contact with the air. The redox potential measurements have been successful. A new equipment for measurements in the sampling section has been constructed. Preliminary tests have given very promising results

Site scale groundwater flow in Haestholmen

International Nuclear Information System (INIS)

Loefman, J.

1999-05-01

Haestholmen, the neighbouring islands and the mainland. In the vicinity of the repository water flows sloping downwards and/or horizontally towards the nearest fracture zones. The zones R1OAB and R14 L 25 constitute the most important flow routes from the repository to the surface. The actual amount of water flowing in the tunnels is about 740 m 3 /a. The average driving force in the intact rock near the repository varies with time between 0.034-0.53 %. The salinity content of groundwater in the bedrock is changing with time due to the postglacial land uplift. Eventually, after 10000 years A.P. brackish and saline water in the bedrock will be flushed by fresh water down to the depth of about 1000 meters below the present Haestholmen island. (orig.)

The potentiality of Trichoderma harzianum in alleviation the adverse effects of salinity in faba bean plants.

Science.gov (United States)

Abd El-Baki, G K; Mostafa, Doaa

2014-12-01

The interaction between sodium chloride and Trichoderma harzianum (T24) on growth parameters, ion contents, MDA content, proline, soluble proteins as well as SDS page protein profile were studied in Vicia faba Giza 429. A sharp reduction was found in fresh and dry mass of shoots and roots with increasing salinity. Trichoderma treatments promoted the growth criteria as compared with corresponding salinized plants. The water content and leaf area exhibited a marked decrease with increasing salinity. Trichoderma treatments induced a progressive increase in both parameters. Both proline and MDA contents were increased progressively as the salinity rose in the soil. Trichoderma treatments considerably retarded the accumulation of both parameters in shoots and roots. Both Na+ and K+ concentration increased in both organs by enhancing salinity levels. The treatment with Trichoderma harzianum enhanced the accumulation of both ions. Exposure of plants to different concentrations of salinity, or others treated with Trichoderma harzianum produced marked changes in their protein pattern. Three types of alterations were observed: the synthesis of certain proteins declined significantly, specific synthesis of certain other proteins were markedly observed and synthesis of a set specific protein was induced de novo in plant treated with Trichoderma harzianum.

Hydrogeologic framework and salinity distribution of the Floridan aquifer system of Broward County, Florida

Science.gov (United States)

Reese, Ronald S.; Cunningham, Kevin J.

2014-01-01

Concerns about water-level decline and seawater intrusion in the surficial Biscayne aquifer, currently the principal source of water supply to Broward County, prompted a study to refine the hydrogeologic framework of the underlying Floridan aquifer system to evaluate its potential as an alternative source of supply. This report presents cross sections that illustrate the stratigraphy and hydrogeology in eastern Broward County; maps of the upper surfaces and thicknesses of several geologic formations or units within the Floridan aquifer system; and maps of two of the potentially productive water-bearing zones within the system, the Upper Floridan aquifer and the Avon Park permeable zone. An analysis of data on rock depositional textures, associated pore networks, and flow zones in the Floridan aquifer system shows that groundwater moves through the system in two ways. These data support a conceptual, dual-porosity model of the system wherein groundwater moves either as concentrated flow in discrete, thin bedding-plane vugs or zones of vuggy megaporosity, or as diffuse flow through rocks with primarily interparticle and moldic-particle porosity. Because considerable exchange of groundwater may occur between the zones of vuggy and matrix-dominated porosity, understanding the distribution of that porosity and flow zone types is important to evaluating the suitability of the several units within the Floridan aquifer system for managing the water through practices such as aquifer storage and recovery (ASR). The salinity of the water in the Floridan aquifer system is highest in the central part of the study area, and lower toward the north and south. Although salinity generally increases with depth, in the western part of the study area a zone of relatively high saline water is perched above water of lower salinity in the underlying Avon Park permeable zone. Overall, the areas of highest salinity in the aquifer system coincide with those with the lowest estimated

The local groundwater regime at the Harwell research site

International Nuclear Information System (INIS)

Alexander, J.; Holmes, D.C.

1983-01-01

Three deep and two shallow boreholes have been drilled at the Harwell Research Site as part of a national research programme into the feasibility of disposal of low and intermediate level radioactive wastes to geologic formations. Various hydrogeological and geochemical techniques have been employed in these boreholes, each of which samples a separate formation of interest, to determine the pattern of groundwater movement under the research site. Significant vertical hydraulic gradients have been identified which produce vertically downwards groundwater movement from the surface to a depth of 200 m (Corallian aquifer). Groundwater moves vertically upwards, from greater depths, through the Oxford Clay to the Corallian aquifer. However,the apparently very low hydraulic conductivity of the Oxford Clay results in extremely low flow velocities and long transit times. Groundwaters from the Corallian formation possess higher salinities than those of the characteristic regional groundwaters, and preliminary isotopic data suggest that some groundwater mixing with connate waters has occurred. The chemical nature of groundwaters from the Great Oolite Group, suggest that contamination due to the drilling and completion procedure has taken place. Due to the low hydraulic conductivity in this formation clearance of contaminants will require the implementation of a long-term abstraction programme. (author)

Alternative Options for Safe Drinking Water in Arsenic and Salinity Affected Bornal-Iliasabad Union of Kalia Upazila, Narail District, Bangladesh

Science.gov (United States)

Rahman, M. M.; Hasan, M. A.; Ahmed, K. M.; Nawrin, N.

2016-12-01

The study area, Bornal-Ilisabad union, Kalia, Narail is one of the most vulnerable areas of Bangladesh in terms of access to safe drinking water. Shallow groundwater of this area is highly arsenic contaminated (mostly >500 μg/L) and deep groundwater is saline (EC ranges 1 to 8 mS/cm). Local communities rely on rainwater for drinking and cooking purposes during the monsoon and rest of the year they use surface water from pond which are mostly polluted. In areas where surface water is not available people are compelled to use arsenic contaminated groundwater and thus exposing themselves to serious health hazard. Principal objective of the research is to evaluate the effectiveness of managed aquifer recharge (MAR) and subsurface arsenic removal (SAR) technology in mitigating groundwater salinity and arsenic, to provide alternative sources of safe water. Surface water (pond water) and rainwater collected from roof top are used as source water to be recharged into the target aquifer for the MAR system. Source water is filtered through a sand filtration unit to remove turbidity and microorganisms before recharging through infiltration wells. For SAR system, on the other hand, a certain volume (2000L) of groundwater is abstracted from the target aquifer and then aerated for about half an hour to saturate with oxygen. The oxygenated water is injected into the aquifer and kept there for 6-8 hours and then abstracted for use. The MAR system constructed in the study area is found very effective in reducing groundwater salinity. The electrical conductivity (EC) of the groundwater of MAR system has been reduced 72-81% from the initial EC value of 3.4 mS/cm. A significant improvement in groundwater arsenic and iron concentration is also observed. The system is yielding groundwater with arsenic within permissible limit of Bangladesh drinking water standard (50 μg/L) which was 100 μg/L before introduction of MAR system. The SAR system is also found effective in reducing

Synopsis of strontium isotope variations in groundwater at Aspo, southern Sweden

Science.gov (United States)

Peterman, Z.E.; Wallin, B.

1999-01-01

Strontium isotope ratios are used to identify end-member ground-water compositions at Aspo in southeastern Sweden where the Hard Rock Laboratory (HRL) has been constructed to evaluate the suitability of crystalline rock for the geologic disposal of nuclear waste. The Hard Rock Laboratory is a decline (tunnel) constructed in 1.8 Ga-old granitic rock that forms islands in an archipelago along the Swedish coast. Ground-water samples were obtained for isotopic analyses from boreholes drilled from the surface and from side boreholes drilled within the HRL. Infiltration at Aspo occurs primarily through fractures zones in the granitic bedrock beneath thin soils throughout the area. Because of extremely low Sr concentrations, rain and snow are not important contributors to the Sr isotope budget of the ground-water system. At shallow levels, water percolating downward along fractures and fracture zones acquires a ??87Sr between +9.5 and +10.0??? and maintains this value downward while Sr concentrations increase by two orders of magnitude. Ground-water samples from both boreholes and from in the HRL show the effects of mixing with saline waters containing as much as 59 mg/L Sr and ??87Sr values as large as +13.92%, Baltic Sea water is a potential component of the groundwater system with ??87Sr values only slightly larger than modern marine values (+0.3???) but with much lower concentrations (1.5 mg/L) than ocean water (8 mg/L). However, because of large Sr concentration differences between the saline groundwater (59 mg/L) and Baltic Sea water (1.5 rag/L), ??87Sr values are not particularly sensitive indicators of sea-water intrusion even though their ??87Sr values differ substantially.

STUDY ON IMPACT OF SALINE WATER INUNDATION ON FRESHWATER AQUACULTURE IN SUNDARBAN USING RISK ANALYSIS TOOLS

Directory of Open Access Journals (Sweden)

B.K Chand

2012-11-01

Full Text Available The impact of saline water inundation on freshwater aquaculture was evaluated through risk assessment tools. Fishponds in low-lying areas of Sagar and Basanti block are prone to saline water flooding. Respondents of Sagar block considered events like cyclone and coastal flooding as extreme risk; erratic monsoon, storm surge and land erosion as high risk; temperature rise, sea level rise, hot & extended summer and precipitation as medium risk. Likewise, in Basanti block the respondents rated cyclone as extreme risk; erratic monsoon, storm surge as high risk; temperature rise, hot & extended summer, land erosion, and precipitation as medium risk; coastal flooding and sea level rise as low risk. Fish farmers of Sagar block classified the consequences of saline water flooding like breach of pond embankment and mass mortality of fishes as extreme risk; escape of existing fish stock and diseases as high risk; entry of unwanted species, retardation of growth and deterioration of water quality as medium risk; and damage of pond environment as low risk. Farmers of Basanti block categorised breach of pond dyke, mass mortality of fishes and entry of unwanted species as extreme risk; escape of fish and diseases as high risk; retardation of growth as medium risk; deterioration of water quality and damage of pond environment as low risk. To reduce the threats against saline water ingression, farmers are taking some coping measures like increase in pond dyke height; repair and strengthening of dyke; plantation on dyke; dewatering and addition of fresh water; application of chemicals/ lime/ dung; addition of tree branches in pond for hide outs etc.

Empirical tools for simulating salinity in the estuaries in Everglades National Park, Florida

Science.gov (United States)

Marshall, F. E.; Smith, D. T.; Nickerson, D. M.

2011-12-01

Salinity in a shallow estuary is affected by upland freshwater inputs (surface runoff, stream/canal flows, groundwater), atmospheric processes (precipitation, evaporation), marine connectivity, and wind patterns. In Everglades National Park (ENP) in South Florida, the unique Everglades ecosystem exists as an interconnected system of fresh, brackish, and salt water marshes, mangroves, and open water. For this effort a coastal aquifer conceptual model of the Everglades hydrologic system was used with traditional correlation and regression hydrologic techniques to create a series of multiple linear regression (MLR) salinity models from observed hydrologic, marine, and weather data. The 37 ENP MLR salinity models cover most of the estuarine areas of ENP and produce daily salinity simulations that are capable of estimating 65-80% of the daily variability in salinity depending upon the model. The Root Mean Squared Error is typically about 2-4 salinity units, and there is little bias in the predictions. However, the absolute error of a model prediction in the nearshore embayments and the mangrove zone of Florida Bay may be relatively large for a particular daily simulation during the seasonal transitions. Comparisons show that the models group regionally by similar independent variables and salinity regimes. The MLR salinity models have approximately the same expected range of simulation accuracy and error as higher spatial resolution salinity models.

Ra-226 and Rn-222 in saline water compartments of the Aral Sea region

International Nuclear Information System (INIS)

Schettler, Georg; Oberhänsli, Hedi; Hahne, Knut

2015-01-01

Highlights: • 222 Rn and 226 Ra concentrations in different water compartments of the Aral Sea region. • 226 Ra-analysis based on 222 Rn-ingrowth versus MS-analysis after solid-phase extraction. • 226 Ra in different groundwater types of the Aral Sea Basin. • 222 Rn distribution in the Aral Sea, western basin. - Abstract: The Aral Sea has been shrinking since 1963 due to extensive irrigation and the corresponding decline in the river water inflow. Understanding of the current hydrological situation demands an improved understanding of the surface water/groundwater dynamics in the region. 222 Rn and 226 Ra measurements can be used to trace groundwater discharge into surface waters. Data of these radiometric parameters were not previously available for the study region. We determined 222 Rn activities after liquid phase extraction using Liquid Scintillation Counting (LSC) with peak-length discrimination and analyzed 226 Ra concentrations in different water compartments of the Amu Darya Delta (surface waters, unconfined groundwater, artesian water, and water profiles from the closed Large Aral Sea (western basin). The water samples comprise a salinity range between 1 and 263 g/l. The seasonal dynamics of solid/water interaction under an arid climate regime force the hydrochemical evolution of the unconfined groundwater in the Amu Darya Delta to high-salinity Na(Mg)Cl(SO 4 ) water types. The dissolved radium concentrations in the waters were mostly very low due to mineral over-saturation, extensive co-precipitation of radium and adsorption of radium on coexisting solid substrates. The analysis of very low 226 Ra concentrations (<10 ppq) at remote study sites is a challenge. We used the water samples to test and improve different analytical methods. In particular, we modified a procedure developed for the α-spectrometric determination of 226 Ra after solid phase extraction of radium using 3M Empore™ High Performance Extraction Disks (Purkl, 2002) for the

Embedded regional/Local-scale model of natural transients in saline groundwater flow. Illustrated using the Beberg Site

International Nuclear Information System (INIS)

Marsic, Niko; Hartley, Lee; Sanchez-Friera, Paula; Morvik, Arnfinn

2002-04-01

the model parameters and structural representation. As for the SR 97 regional-scale model the high salinity below Zone 2 could not be reproduced with a highly transmissive zone. A reasonable match could only be achieved if a semi-impermeable band be included in the core of Zone 2, and the position of Zone 2 had to be taken from the detailed geometry defined in Andersson et al. rather than SR 97. 7) Structural model: the calibration demonstrated the important effect that sub-horizontal fracture zones could have on deep groundwater flows, and the importance of having a good structural interpretation of such zones. Aspects such as hydraulic anisotropy, layering, fracture zone truncation and interconnection will be important to characterise in any site either by direct measurement and/or by using modelling to test the ability of different structural models to predict hydraulic and chemical properties in deep boreholes. In fact, this is a good example of how a flow model calibration exercise can augment structural interpretation and help constrain it. 8) Flexible representation: new tools for representing fracture zones and rock volumes allow flexibility in how a structural model is represented e.g. wedge shaped zones and hydraulic anisotropy. 9) Modelling barriers: proved to be non-trivial since approximating the thickness or representation of flow through a thin barrier relative to the grid size can lead to an over-prediction of flow rates through barriers. For standard elements, if only a thin band of elements, one or two thick, is used to model a semi-impermeable barrier, then the flow across the zone may be larger than expected. This is because small flows can 'leak' across element corners because of the lack of localised mass balance. This is not the case with mixed-elements, which motivates more investigation of this element type. 10) Transport statistics: indicate that neither salinity nor release-time has a great effect on statistics of travel times or canister

Integrating geochemical investigations and geospatial assessment to understand the evolutionary process of hydrochemistry and groundwater quality in arid areas.

Science.gov (United States)

El Alfy, Mohamed; Alharbi, Talal; Mansour, Basma

2018-04-12

Groundwater is the key for life in arid areas. Aquifer overexploitation and climatic conditions can significantly deteriorate groundwater quality. The Al-Qassim area in central Saudi Arabia is characterized by dense agricultural use and is irrigated mainly by fossil groundwater from the Saq Aquifer. Understanding the area's hydrochemistry, major factors governing groundwater quality, and alternative uses of the groundwater are the main goals of this study. Groundwater samples were collected and examined for major, minor, and trace elements. Ionic relationships, hydrochemical facies, geospatial distributions, and multivariate analyses were conducted to assess the hydrochemical processes at play. The salinity and nitrate concentrations of the Saq Aquifer's groundwater were found to increase in the outcrop areas more than the confined areas. The spatial distributions were fragmented by three main factors: (i) modern recharge by relatively brackish water, (ii) irrigation return flow in intensive farming areas, and (iii) overexploitation and draining of deep and relatively saline zones of the aquifer. Seven water types were found representing the alkaline water with a predominance of sulfate-chloride ions and earth alkaline water with a predominance of sulfate and chloride. Mixing between fresh and brackish water, dissolution of mineral phases, silicate weathering, and reverse ion exchange were recognized as the evolutionary processes, while evaporation played a minor role. Cluster analyses characterized the fresh groundwater zone, modern groundwater recharge zone, and anthropogenic influence zone. In the confined areas, nearly all the groundwater was appropriate for domestic use and irrigation. In the outcrop areas, some limitations were found due to unsuitable conditions.

A prototype cell for extracting energy from a water salinity difference by means of double layer expansion in nanoporous carbon electrodes

NARCIS (Netherlands)

Brogioli, D.; Zhao, R.; Biesheuvel, P.M.

2011-01-01

Electrical energy can be obtained from the controlled mixing of fresh (river) and saline (sea) water. Existing technologies such as pressure retarded osmosis and reverse electrodialysis make use of ion-exchange membranes which must be crossed by either the water or the ions. Recently a new physical

Hydrogeologic controls and geochemical indicators of groundwater movement in the Niles Cone and southern East Bay Plain groundwater subbasins, Alameda County, California

Science.gov (United States)

Teague, Nicholas F.; Izbicki, John A.; Borchers, Jim; Kulongoski, Justin T.; Jurgens, Bryant C.

2018-02-01

Beginning in the 1970s, Alameda County Water District began infiltrating imported water through ponds in repurposed gravel quarries at the Quarry Lakes Regional Park, in the Niles Cone groundwater subbasin, to recharge groundwater and to minimize intrusion of saline, San Francisco Bay water into freshwater aquifers. Hydraulic connection between distinct aquifers underlying Quarry Lakes allows water to recharge the upper aquifer system to depths of 400 feet below land surface, and the Deep aquifer to depths of more than 650 feet. Previous studies of the Niles Cone and southern East Bay Plain groundwater subbasins suggested that these two subbasins may be hydraulically connected. Characterization of storage capacities and hydraulic properties of the complex aquifers and the structural and stratigraphic controls on groundwater movement aids in optimal storage and recovery of recharged water and provides information on the ability of aquifers shared by different water management agencies to fulfill competing storage and extraction demands. The movement of recharge water through the Niles Cone groundwater subbasin from Quarry Lakes and the possible hydraulic connection between the Niles Cone and the southern East Bay Plain groundwater subbasins were investigated using interferometric synthetic aperture radar (InSAR), water-chemistry, and isotopic data, including tritium/helium-3, helium-4, and carbon-14 age-dating techniques.InSAR data collected during refilling of the Quarry Lakes recharge ponds show corresponding ground-surface displacement. Maximum uplift was about 0.8 inches, reasonable for elastic expansion of sedimentary materials experiencing an increase in hydraulic head that resulted from pond refilling. Sodium concentrations increase while calcium and magnesium concentrations in groundwater decrease along groundwater flowpaths from the Niles Cone groundwater subbasin through the Deep aquifer to the northwest toward the southern East Bay Plain groundwater

In situ bioremediation under high saline conditions

International Nuclear Information System (INIS)

Bosshard, B.; Raumin, J.; Saurohan, B.

1995-01-01

An in situ bioremediation treatability study is in progress at the Salton Sea Test Base (SSTB) under the NAVY CLEAN 2 contract. The site is located in the vicinity of the Salon Sea with expected groundwater saline levels of up to 50,000 ppm. The site is contaminated with diesel, gasoline and fuel oils. The treatability study is assessing the use of indigenous heterotrophic bacteria to remediate petroleum hydrocarbons. Low levels of significant macro nutrients indicate that nutrient addition of metabolic nitrogen and Orthophosphate are necessary to promote the process, requiring unique nutrient addition schemes. Groundwater major ion chemistry indicates that precipitation of calcium phosphorus compounds may be stimulated by air-sparging operations and nutrient addition, which has mandated the remedial system to include pneumatic fracturing as an option. This presentation is tailored at an introductory level to in situ bioremediation technologies, with some emphasize on innovations in sparge air delivery, dissolved oxygen uptake rates, nutrient delivery, and pneumatic fracturing that should keep the expert's interest

Phreatophytes under stress: transpiration and stomatal conductance of saltcedar (Tamarix spp.) in a high-salinity environment

Science.gov (United States)

Glenn, Edward P.; Nagler, Pamela L.; Morino, Kiyomi; Hultine, Kevin

2013-01-01

Background and aims: We sought to understand the environmental constraints on an arid-zone riparian phreatophtye, saltcedar (Tamarix ramosissima and related species and hybrids), growing over a brackish aquifer along the Colorado River in the western U.S. Depth to groundwater, meteorological factors, salinity and soil hydraulic properties were compared at stress and non-stressed sites that differed in salinity of the aquifer, soil properties and water use characteristics, to identify the factors depressing water use at the stress site.

Soil salinization in different natural zones of intermontane depressions in Tuva

Science.gov (United States)

Chernousenko, G. I.; Kurbatskaya, S. S.

2017-11-01

Soil salinization features in semidesert, dry steppe, and chernozemic steppe zones within intermontane depressions in the central part of the Tuva Republic are discussed. Chernozems, chestnut soils, and brown desert-steppe soils of these zones are usually nonsaline. However, salinization of these zonal soils is possible in the case of the presence of salt-bearing parent materials (usually, the derivatives of Devonian deposits). In different natural zones of the intermontane depressions, salt-affected soils are mainly allocated to endorheic lake basins, where they are formed in places of discharge of mineral groundwater, and to river valleys. The composition and content of salts in the natural waters are dictated by the local hydrogeological conditions. The total content of dissolved solids in lake water varies from 1 to 370 g/L; the water is usually of the sulfate-chloride or chloride-sulfate salinity type; in some cases, soda-sulfate water is present. Soil salinity around the lakes is usually of the chloride-sulfate-sodium type; gypsum is often present in the profiles. Chloride salinization rarely predominates in this part of Tuva, because chlorides are easily leached off from the mainly coarse-textured soils. In some cases, the predominance of magnesium over sodium is observed in the composition of dissolved salts, which may be indicative of the cryogenic transformation of soil salts. Soda-saline soils are present in all the considered natural zones on minor areas. It is hardly possible to make unambiguous statements about the dominance of the particular type of salinity in the given natural zones. Zonal salinity patterns are weakly expressed in salinization of hydromorphic soils. However, a tendency for more frequent occurrence of soda-saline soils in steppe landscapes and chloride-sulfate salinization (often, with participation of gypsum) in the dry steppe and semidesert landscapes is observed.

Review of risk from potential emerging contaminants in UK groundwater.

Science.gov (United States)

Stuart, Marianne; Lapworth, Dan; Crane, Emily; Hart, Alwyn

2012-02-01

This paper provides a review of the types of emerging organic groundwater contaminants (EGCs) which are beginning to be found in the UK. EGCs are compounds being found in groundwater that were previously not detectable or known to be significant and can come from agricultural, urban and rural point sources. EGCs include nanomaterials, pesticides, pharmaceuticals, industrial compounds, personal care products, fragrances, water treatment by-products, flame retardants and surfactants, as well as caffeine and nicotine. Many are relatively small polar molecules which may not be effectively removed by drinking water treatment. Data from the UK Environment Agency's groundwater screening programme for organic pollutants found within the 30 most frequently detected compounds a number of EGCs such as pesticide metabolites, caffeine and DEET. Specific determinands frequently detected include pesticides metabolites, pharmaceuticals including carbamazepine and triclosan, nicotine, food additives and alkyl phosphates. This paper discusses the routes by which these compounds enter groundwater, their toxicity and potential risks to drinking water and the environment. It identifies challenges that need to be met to minimise risk to drinking water and ecosystems. Copyright © 2012. Published by Elsevier B.V.

Fire retardant formulations

DEFF Research Database (Denmark)

2017-01-01

The present invention relates to compositions where a substrate is liable to catch fire such as bituminous products, paints, carpets or the like. The invention relates to a composition comprising 40-95 weight % of a substrate to be rendered fire resistant such as bituminous material or paint......, carpets which substrate is mixed with 5-60 weight % of a fire retardant component. The invention relates to a fire retardant component comprising or being constituted of attapulgite, and a salt being a source of a blowing or expanding agent, where the attapulgite and the salt are electrostatically...... connected by mixing and subjecting the mixture of the two components to agitation. Also, the invention relates to compositions comprising 40-95 weight % of a substrate to be rendered fire resistant mixed with 5-60 weight % of a fire retardant according to claim 1 or 2, which fire retardant component...

Groundwater flow in a relatively old oceanic volcanic island: The Betancuria area, Fuerteventura Island, Canary Islands, Spain

Energy Technology Data Exchange (ETDEWEB)

Herrera, Christian, E-mail: cherrera@ucn.cl [Universidad Católica del Norte, Av. Angamos 0610, Antofagasta (Chile); Custodio, Emilio [Department of Geo-Engineering, Technical University of Catalonia (UPC), Barcelona (Spain)

2014-10-15

The island of Fuerteventura is the oldest of the Canary Islands' volcanic archipelago. It is constituted by volcanic submarine and subaerial activity and intrusive Miocene events, with some residual later volcanism and Quaternary volcanic deposits that have favored groundwater recharge. The climate is arid, with an average rainfall that barely attains 60 mm/year in the coast and up to 200 mm/year in the highlands. The aquifer recharge is small but significant; it is brackish due to large airborne atmospheric salinity, between 7 and 15 g m{sup −2} year{sup −1} of chloride deposition, and high evapo-concentration in the soil. The average recharge is estimated to be less than about 5 mm/year at low altitude and up to 10 mm/year in the highlands, and up to 20 mm/year associated to recent lava fields. Hydrochemical and water isotopic studies, supported by water table data and well and borehole descriptions, contribute a preliminary conceptual model of groundwater flow and water origin in the Betancuria area, the central area of the island. In general, water from springs and shallow wells tends to be naturally brackish and of recent origin. Deep saline groundwater is found and is explained as remnants of very old marine water trapped in isolated features in the very low permeability intrusive rocks. Preliminary radiocarbon dating indicates that this deep groundwater has an apparent age of less than 5000 years BP but it is the result of mixing recent water recharge with very old deep groundwater. Most of the groundwater flow occurs through the old raised volcanic shield of submarine and subaerial formations and later Miocene subaerial basalts. Groundwater transit time through the unsaturated zone is of a few decades, which allows the consideration of long-term quasi-steady state recharge. Transit times are up to a few centuries through the saturated old volcanics and up to several millennia in the intrusive formations, where isolated pockets of very old water may

Salinization in a stratified aquifer induced by heat transfer from well casings

Science.gov (United States)

van Lopik, Jan H.; Hartog, Niels; Zaadnoordijk, Willem Jan; Cirkel, D. Gijsbert; Raoof, Amir

2015-12-01

The temperature inside wells used for gas, oil and geothermal energy production, as well as steam injection, is in general significantly higher than the groundwater temperature at shallower depths. While heat loss from these hot wells is known to occur, the extent to which this heat loss may result in density-driven flow and in mixing of surrounding groundwater has not been assessed so far. However, based on the heat and solute effects on density of this arrangement, the induced temperature contrasts in the aquifer due to heat transfer are expected to destabilize the system and result in convection, while existing salt concentration contrasts in an aquifer would act to stabilize the system. To evaluate the degree of impact that may occur under field conditions, free convection in a 50-m-thick aquifer driven by the heat loss from penetrating hot wells was simulated using a 2D axisymmetric SEAWAT model. In particular, the salinization potential of fresh groundwater due to the upward movement of brackish or saline water in a stratified aquifer is studied. To account for a large variety of well applications and configurations, as well as different penetrated aquifer systems, a wide range of well temperatures, from 40 to 100 °C, together with a range of salt concentration (1-35 kg/m3) contrasts were considered. This large temperature difference with the native groundwater (15 °C) required implementation of a non-linear density equation of state in SEAWAT. We show that density-driven groundwater flow results in a considerable salt mass transport (up to 166,000 kg) to the top of the aquifer in the vicinity of the well (radial distance up to 91 m) over a period of 30 years. Sensitivity analysis showed that density-driven groundwater flow and the upward salt transport was particularly enhanced by the increased heat transport from the well into the aquifer by thermal conduction due to increased well casing temperature, thermal conductivity of the soil, as well as decreased

Desiccation-crack-induced salinization in deep clay sediment

Directory of Open Access Journals (Sweden)

S. Baram

2013-04-01

Full Text Available A study on water infiltration and solute transport in a clayey vadose zone underlying a dairy farm waste source was conducted to assess the impact of desiccation cracks on subsurface evaporation and salinization. The study is based on five years of continuous measurements of the temporal variation in the vadose zone water content and on the chemical and isotopic composition of the sediment and pore water in it. The isotopic composition of water stable isotopes (δ18O and δ2H in water and sediment samples, from the area where desiccation crack networks prevail, indicated subsurface evaporation down to ~ 3.5 m below land surface, and vertical and lateral preferential transport of water, following erratic preferential infiltration events. Chloride (Cl− concentrations in the vadose zone pore water substantially increased with depth, evidence of deep subsurface evaporation and down flushing of concentrated solutions from the evaporation zones during preferential infiltration events. These observations led to development of a desiccation-crack-induced salinization (DCIS conceptual model. DCIS suggests that thermally driven convective air flow in the desiccation cracks induces evaporation and salinization in relatively deep sections of the subsurface. This conceptual model supports previous conceptual models on vadose zone and groundwater salinization in fractured rock in arid environments and extends its validity to clayey soils in semi-arid environments.

Water quality assessment and hydrochemical characterization of Zamzam groundwater, Saudi Arabia

Science.gov (United States)

Al-Barakah, Fahad N.; Al-jassas, Abdurahman M.; Aly, Anwar A.

2017-11-01

This study focuses on chemical and microbial analyses of 50 Zamzam water samples, Saudi Arabia. The soluble ions, trace elements, total colony counts, total coliform group, and E. coli were determined and compared with WHO standards. The obtained results indicated that the dissolved salts, soluble cations and anions, Pb, Cd, As, Zn, Cu, Ni, Co, Fe, Mn, Cr, PO4 3-, NO2 -, Br-, F-, NH4 +, and Li+, were within permissible limits for all samples. Yet, 2% of waters contain NO3 - at slightly high concentration. The water quality index (WQI) reveals that 94% of the samples were excellent for drinking (class I). While the remaining was unsuitable due to total coliform group contamination "class (V)". Durov diagram suggest no clear facies and dominant water type can be noted. It indicates mixing processes of two or more different facies might be occurring in the groundwater system. All studied waters were undersaturated with respect to halite, gypsum, fluorite, and anhydrite. These minerals tend to dissolve and increase water salinity. A direct relationship between Zamzam water salinity and rainfall is recorded. The water salinity fluctuated between 4500 mg L-1 (year 1950) and 500 mg L-1 (year 2015) based on rainfall extent. The approach applied can be used to similar groundwater worldwide.

Groundwater table rise in northwest Nile Delta:Problems and Recommendations

International Nuclear Information System (INIS)

El-Sayed, S. A.; Atta, E. R.; Al-Ashri, K. M.

2012-01-01

The present research work is devoted to evaluate the surrounding zones of a site which could be selected for construction of radiation facility. It is a model study to investigate the factors that protect sites from the risks of groundwater rising. The study area (village 17 and the related cultivated lands) lies in Bangar El Sukar area, south Alexandria Governorate. The area is suffering from the groundwater table rise phenomenon and its relevant problems (water logging, soil salinization and degradation of buildings). This water table rise is investigated using the hydrogeological, hydrogeochemical and isotopic approaches. The groundwater table of the Pleistocene-Holocene aquifer rises due to uncontrolled irrigation and drainage systems and the lack of municipal sewage system as well as soil and aquifer characteristics. The aquifer is being shallow and exists under semi-confined conditions. It consists of heterogeneous deposits (very fine to coarse grained sand, clay and calcareous rock fragments). Depths to water vary between 0.85 m and 1.44 m from ground surface. The groundwater (TDS 3331 mg/l, averagely) is a mixture of both the fresh water of the irrigation canals (TDS = 544.2 mg/l) and the more saline water (TDS = 5505 mg/l, averagely) of the drains used in irrigation. Nile water is considered the main recharge source to these types of waters. The recharge to the aquifer occurs by seepage from the canals and/or by the infiltration of the return flow after irrigation. The infiltration rate is moderately rapid (ranging from 1.8 mm/min to 2.6 mm/min). The groundwater moves from south to north with an average hydraulic gradient reaching about 1.7 x 10-3. The average rate of groundwater flow through the aquifer varies between 1799 m2/day and 543.65 m2/day. In order to avoid the risks related to the problem and its environmental impacts, proper recommendations are presented. Suggested design for a constructed net of drainage system and pumped well is presented in

A daily salt balance model for stream salinity generation processes following partial clearing from forest to pasture

Directory of Open Access Journals (Sweden)

M. A. Bari

2006-01-01

Full Text Available We developed a coupled salt and water balance model to represent the stream salinity generation process following land use changes. The conceptual model consists of three main components with five stores: (i Dry, Wet and Subsurface Stores, (ii a saturated Groundwater Store and (iii a transient Stream zone Store. The Dry and Wet Stores represent the salt and water movement in the unsaturated zone and also the near-stream dynamic saturated areas, responsible for the generation of salt flux associated with surface runoff and interflow. The unsaturated Subsurface Store represents the salt bulge and the salt fluxes. The Groundwater Store comes into play when the groundwater level is at or above the stream invert and quantifies the salt fluxes to the Stream zone Store. In the stream zone module, we consider a 'free mixing' between the salt brought about by surface runoff, interflow and groundwater flow. Salt accumulation on the surface due to evaporation and its flushing by initial winter flow is also incorporated in the Stream zone Store. The salt balance model was calibrated sequentially following successful application of the water balance model. Initial salt stores were estimated from measured salt profile data. We incorporated two lumped parameters to represent the complex chemical processes like diffusion-dilution-dispersion and salt fluxes due to preferential flow. The model has performed very well in simulating stream salinity generation processes observed at Ernies and Lemon experimental catchments in south west of Western Australia. The simulated and observed stream salinity and salt loads compare very well throughout the study period with NSE of 0.7 and 0.4 for Ernies and Lemon catchment respectively. The model slightly over predicted annual stream salt load by 6.2% and 6.8%.

Tackling the salinity-pollution nexus in coastal aquifers from arid regions using nitrate and boron isotopes.

Science.gov (United States)

Re, V; Sacchi, E

2017-05-01

Salinization and nitrate pollution are generally ascertained as the main issues affecting coastal aquifers worldwide. In arid zones, where agricultural activities also result in soil salinization, both phenomena tend to co-exist and synergically contribute to alter groundwater quality, with severe negative impacts on human populations and natural ecosystems' wellbeing. It becomes therefore necessary to understand if and to what extent integrated hydrogeochemical tools can help in distinguishing among possible different salinization and nitrate contamination origins, in order to provide adequate science-based support to local development and environmental protection. The alluvial plain of Bou-Areg (North Morocco) extends over about 190 km 2 and is separated from the Mediterranean Sea by the coastal Lagoon of Nador. Its surface is covered for more than 60% by agricultural activities, although the region has been recently concerned by urban population increase and tourism expansion. All these activities mainly rely on groundwater exploitation and at the same time are the main causes of both aquifer and lagoon water quality degradation. For this reason, it was chosen as a case study representative of the typical situation of coastal aquifers in arid zones worldwide, where a clear identification of salinization and pollution sources is fundamental for the implementation of locally oriented remedies and long-term management strategies. Results of a hydrogeochemical investigation performed between 2009 and 2011 show that the Bou-Areg aquifer presents high salinity (often exceeding 100 mg/L in TDS) due to both natural and anthropogenic processes. The area is also impacted by nitrate contamination, with concentrations generally exceeding the WHO statutory limits for drinking water (50 mg/L) and reaching up to about 300 mg/L, in both the rural and urban/peri-urban areas. The isotopic composition of dissolved nitrates (δ 15 N NO3 and δ 18 O NO ) was used to constrain

Distribution of natural uranium in groundwater around Kudankulam

International Nuclear Information System (INIS)

Selvi, B.S.; Vijayakumar, B.; Rana, B.K.; Ravi, P.M.

2016-01-01

A systematic study was carried out to estimate the uranium concentration in the ground water around Kudankulam in Southern Tamil Nadu. The uranium concentration in ground water varies from 0.2 to 6.6 μg/l, with a mean value of 2.0 μg/l. The Quantalase uranium analyzer was used to measure the uranium concentration. These groundwater samples were analyzed for the water quality parameters such as pH, conductance, total dissolved solids (TDS), salinity, chloride, and sulfate. An attempt has been made to correlate the uranium concentration with the water quality parameters. It is observed that conductance, TDS, salinity, chloride, and sulfate show positive correlation with uranium concentration. (author)

Desalination of brackish groundwater and concentrate disposal by deep well injection

NARCIS (Netherlands)

Wolthek, N.; Raat, K.; Ruijter, J.A.; Kemperman, Antonius J.B.; Oosterhof, A.

2013-01-01

In the province of Friesland (in the Northern part of The Netherlands), problems have arisen with the abstraction of fresh groundwater due to salinization of wells by upcoming of brackish water. A solution to this problem is to intercept (abstract) the upcoming brackish water, desalinate it with a

Marine electrical resistivity imaging of submarine groundwater discharge: Sensitivity analysis and application in Waquoit Bay, Massachusetts, USA

Science.gov (United States)

Henderson, Rory; Day-Lewis, Frederick D.; Abarca, Elena; Harvey, Charles F.; Karam, Hanan N.; Liu, Lanbo; Lane, John W.

2010-01-01

Electrical resistivity imaging has been used in coastal settings to characterize fresh submarine groundwater discharge and the position of the freshwater/salt-water interface because of the relation of bulk electrical conductivity to pore-fluid conductivity, which in turn is a function of salinity. Interpretation of tomograms for hydrologic processes is complicated by inversion artifacts, uncertainty associated with survey geometry limitations, measurement errors, and choice of regularization method. Variation of seawater over tidal cycles poses unique challenges for inversion. The capabilities and limitations of resistivity imaging are presented for characterizing the distribution of freshwater and saltwater beneath a beach. The experimental results provide new insight into fresh submarine groundwater discharge at Waquoit Bay National Estuarine Research Reserve, East Falmouth, Massachusetts (USA). Tomograms from the experimental data indicate that fresh submarine groundwater discharge may shut down at high tide, whereas temperature data indicate that the discharge continues throughout the tidal cycle. Sensitivity analysis and synthetic modeling provide insight into resolving power in the presence of a time-varying saline water layer. In general, vertical electrodes and cross-hole measurements improve the inversion results regardless of the tidal level, whereas the resolution of surface arrays is more sensitive to time-varying saline water layer.

Geochemical modelling of groundwater evolution and residence time at the Haestholmen site

Energy Technology Data Exchange (ETDEWEB)

Pitkaenen, P.; Luukkonen, A. [VTT Communities and Infrastructure, Espoo (Finland); Ruotsalainen, P. [Fintact Oy, Helsinki (Finland); Leino- Forsman, H.; Vuorinen, U. [VTT Chemical Technology, Espoo (Finland)

2001-01-01

, palaeo-Baltic stages, land uplift and aricient hydrothernal events, have had a significant effect on local palaechydrogeological conditions. They have caused great variability, which is observable in the chemical data notably in water types and stable isotopes of water ({delta}{sup 18} H and {delta}{sup 18}O). The salinity variation observed at Haestholmen is mainly derived from mixing of the end-members originated from these events. Dilute, meteoric based HCO{sub 3}-rich groundwater dominates in the upper 50 to 150 m (variation between the island and mainland part, respectively). The water type has recharged since the site began to rise above sea level about 5000 years ago, but it is mainly young, less than 50 years old, reflecting dynamic hydrogeological conditions. Brackish SO{sub 4}-rich groundwater has been obtained between 50m and 600m. Groundwater infiltrated from the Litorina Sea (7 500-2 500 years BP) forms the bulk at 50-350m. Deeper, the brackish groundwater mixture contains significant portions of glacial melt and pre-Weichselian sea-water derived from e.g. the Eem stage or some older sea stage. Saline groundwater is obtained below 600m. Hydrothermal water-rock interaction (probably Precambrian) is interpreted as being the origin of the brine end-member diluted in saline groundwater, but it also contains a small sea-water component. The influence of water-rock interaction is also significant for chemical conditions. It principally controls the pH and redox conditions. Carbonate interaction with fracture calcite and dolomite, especially dedolomitisation, may be major processes controlling the pH at level 7.5 to 8. Redox conditions are mainly dominated by microbial Fe and SO{sub 4} reduction (though a small amount), which determines Eh at a level of -200{+-}50 mV in the brackish and saline groundwater layer. It is noteworthy that the significance of the host rock is prominent for hydrogeochemical conditions in crystalline bedrock. This is clearly observable

Initial site characterisation of a dissolved hydrocarbon groundwater plume discharging to a surface water environment

International Nuclear Information System (INIS)

Westbrook, S.J.; Commonwealth Scientific and Industrial Research Organisation Land and Water, Wembley, WA; Davis, G.B.; Rayner, J.L.; Fisher, S.J.; Clement, T.P.

2000-01-01

Preliminary characterisation of a dissolved hydrocarbon groundwater plume flowing towards a tidally- and seasonally-forced estuarine system has been completed at a site in Perth, Western Australia. Installation and sampling of multiport boreholes enabled fine scale (0.5-m) vertical definition of hydrocarbon concentrations. Vertical electrical conductivity profiles from multiport and spear probe sampling into the river sediments indicated that two groundwater/river water interfaces or dispersion zones are present: (a) an upper dispersion zone between brackish river water and groundwater, and (b) a lower interface between groundwater and deeper saline water. On-line water level loggers show that near-shore groundwater levels are also strongly influence by tidal oscillation. Results from the initial site characterisation will be used to plan further investigations of contaminated groundwater/surface water interactions and the biodegradation processes occurring at the site

Geochemical modelling of groundwater evolution and residence time at the Olkiluoto site

International Nuclear Information System (INIS)

Pitkaenen, P.; Luukkonen, A.; Ruotsalainen, P.; Leino-Forsman, H.; Vuorinen, U.

1999-05-01

external conditions such as glaciation, palaeo Baltic stages, land uplift and ancient hydrothermal events, have had a significant effect on local palaeohydrogeological conditions. They have caused great variability, which is observable in the chemical data notably in salinity (up to 70 g/l), water type and contents of conservative parameters, such as Cl, Br and stable isotopes of water. However, their influence is also significant on the water-rock interaction that principally controls the pH and redox conditions - varying 7.5 to 8 and -200 to -300 mV, respectively - in the groundwater, although the calculated mass transfer in the reactions is minor compared with conservative mixing at the site. Calcite in fractures is interpreted to principally control pH level in groundwater. Sulphidic redox conditions dominate in the upper 500 m in brackish and slightly saline groundwater. Deeper sulphur species are absent and methanic processes are obtained. The water types can be connected to certain palaeo stages. This enables to estimate mean residence time of groundwaters. Current meteoric recharge stage (< 2500 a) mainly dominates in the upper 150 m. Groundwater from Litorina stage (7500-2500 a ago) forms the bulk at 100 - 250 m. Glacial melt water (about 10 000 a old) is an important component of groundwater between 100 - 500 m. However, any remarks of oxygen intrusion cannot be interpreted neither from mineralogy nor from groundwater. Deeper, subglacial and older saline groundwater predominates. Despite the current locations of different groundwater bodies it seems according to hydrogeochemical interpretation that dynamic flow conditions has been limited to upper 150 - 200 m. (orig.)

Geochemical modelling of groundwater evolution and residence time at the Olkiluoto site

Energy Technology Data Exchange (ETDEWEB)

Pitkaenen, P.; Luukkonen, A. [VTT Communities and Infrastructure, Espoo (Finland); Ruotsalainen, P. [Fintact Oy (Finland); Leino-Forsman, H.; Vuorinen, U. [VTT Chemical Technology, Espoo (Finland)

1999-05-01

external conditions such as glaciation, palaeo Baltic stages, land uplift and ancient hydrothermal events, have had a significant effect on local palaeohydrogeological conditions. They have caused great variability, which is observable in the chemical data notably in salinity (up to 70 g/l), water type and contents of conservative parameters, such as Cl, Br and stable isotopes of water. However, their influence is also significant on the water-rock interaction that principally controls the pH and redox conditions - varying 7.5 to 8 and -200 to -300 mV, respectively - in the groundwater, although the calculated mass transfer in the reactions is minor compared with conservative mixing at the site. Calcite in fractures is interpreted to principally control pH level in groundwater. Sulphidic redox conditions dominate in the upper 500 m in brackish and slightly saline groundwater. Deeper sulphur species are absent and methanic processes are obtained. The water types can be connected to certain palaeo stages. This enables to estimate mean residence time of groundwaters. Current meteoric recharge stage (< 2500 a) mainly dominates in the upper 150 m. Groundwater from Litorina stage (7500-2500 a ago) forms the bulk at 100 - 250 m. Glacial melt water (about 10 000 a old) is an important component of groundwater between 100 - 500 m. However, any remarks of oxygen intrusion cannot be interpreted neither from mineralogy nor from groundwater. Deeper, subglacial and older saline groundwater predominates. Despite the current locations of different groundwater bodies it seems according to hydrogeochemical interpretation that dynamic flow conditions has been limited to upper 150 - 200 m. (orig.) 82 refs.

Effects of road salts on groundwater and surface water ...

Science.gov (United States)

Road salts are a growing environmental concern in urban watersheds. We examined groundwater (GW) and surface water (SW) dynamics of Na+ and Cl− in Minebank Run (MBR), an urban stream in Maryland, USA. We observed an increasing salinity trend in this restored stream. Current baseflow salinity does not exceed water quality recommendations, but rapid “first flush” storm flow was approximately one-third that of seawater. Comparisons between the upstream and downstream study reaches suggest that a major interstate highway is the primary road salt source. A heavily used road parallels most of MBR and was an additional source to GW concentrations, especially the downstream right bank. A baseflow synoptic survey identified zones of increased salinity. Downstream piezometer wells exhibited increases in salt concentrations and there was evidence that Na+ is exchanging Ca2+ and Mg2+ on soils. SW salt concentrations were generally elevated above GW concentrations. Salinity levels persisted at MBR throughout the year and were above background levels at Bynum Run, a nearby reference stream not bisected by a major highway, suggesting that GW is a long-term reservoir for accumulating road salts. Chronic salinity levels may be high enough to damage vegetation and salinity peaks could impact other biota. Beneficial uses and green infrastructure investments may be at risk from salinity driven degradation. Therefore, road salt may represent an environmental risk that could af

Site scale groundwater flow in Olkiluoto

International Nuclear Information System (INIS)

Loefman, J.

1999-03-01

/or upwards. In the vicinity of the repository water flows sloping downwards to north towards the fracture zones R1OHY and R21 as well as to south and southwest towards the zone R18L. The subhorizontal fracture zone R21 dipping from northwest below the repository constitutes the most important flow route from the repository to the surface. The actual amount of water flowing in the tunnels is about 12-18 m 3 /a. The average driving force in the intact rock near the repository is a gradient of 0.6-0.8 %. The salinity content of groundwater in the bedrock is changing with time due to the postglacial land uplift. Eventually, after 10000 years A.P. brackish and saline water in the bedrock will be flushed by fresh water down to the depth of about 600 meters below the area of the present island. (orig.)

Site scale groundwater flow in Haestholmen

Energy Technology Data Exchange (ETDEWEB)

Loefman, J. [VTT Energy, Espoo (Finland)

1999-05-01

Haestholmen, the neighbouring islands and the mainland. In the vicinity of the repository water flows sloping downwards and/or horizontally towards the nearest fracture zones. The zones R1OAB and R14{sub L}25 constitute the most important flow routes from the repository to the surface. The actual amount of water flowing in the tunnels is about 740 m{sup 3}/a. The average driving force in the intact rock near the repository varies with time between 0.034-0.53 %. The salinity content of groundwater in the bedrock is changing with time due to the postglacial land uplift. Eventually, after 10000 years A.P. brackish and saline water in the bedrock will be flushed by fresh water down to the depth of about 1000 meters below the present Haestholmen island. (orig.) 57 refs.

Site scale groundwater flow in Olkiluoto

Energy Technology Data Exchange (ETDEWEB)

Loefman, J. [VTT Energy, Espoo (Finland)

1999-03-01

/or upwards. In the vicinity of the repository water flows sloping downwards to north towards the fracture zones R1OHY and R21 as well as to south and southwest towards the zone R18L. The subhorizontal fracture zone R21 dipping from northwest below the repository constitutes the most important flow route from the repository to the surface. The actual amount of water flowing in the tunnels is about 12-18 m{sup 3}/a. The average driving force in the intact rock near the repository is a gradient of 0.6-0.8 %. The salinity content of groundwater in the bedrock is changing with time due to the postglacial land uplift. Eventually, after 10000 years A.P. brackish and saline water in the bedrock will be flushed by fresh water down to the depth of about 600 meters below the area of the present island. (orig.) 63 refs.

Biogeochemical transport in the Loxahatchee River estuary, FL: The role of submarine groundwater discharge

Science.gov (United States)

Swarzenski, P.; Orem, B.; McPherson, B.; Baskaran, M.; Wan, Y.

2005-05-01

The distributions of dissolved organic carbon (DOC), silica, select trace elements (Mn, Fe, Ba, Sr, Co, V,) and a suite of naturally-occurring radionuclides in the U/Th decay series (222Rn, 223,224,226,228Ra, 238U) were studied during high and low discharge conditions in the Loxahatchee River estuary, Florida. The zero-salinity endmember of this still relatively pristine estuary may reflect not only river-borne constituents, but also those advected during active groundwater/surface-water discharge. During low discharge conditions, with the notable exception of Co, trace metals indicate nearly conservative mixing from a salinity of ~12 through the estuary (This statement contracdicts with what is said in p. 7). In contrast, of the trace metals studied, only Sr, Fe, U and V exhibited conservative estuarine mixing during high discharge. Dissolved organic carbon and Si concentrations were highest at zero salinities, and generally decreased with an increase in salinity during both discharge regimes, indicating removal of land-derived dissolved organic matter and silica in the estuary. Suspended particulate matter (SPM) concentrations were generally lowest ( 28 dpm L-1) at the freshwater endmember of the estuary, and appear to identify regions of the river most influenced by active submarine groundwater discharge (where is the data that show this?). Activities of four naturally-occurring isotopes of Ra (223,224,226,228Ra) in this estuary and select adjacent shallow groundwater wells indicate mean estuarine water mass residence times of less than 1 day; values in close agreement to those calculated by tidal prism and tidal period. A radium-based model for estimating submarine groundwater discharge to the Loxahatchee River estuary yielded an average of 1.03 V 3.84 x 105 m3 day-1, depending on river discharge stage as well as slight variations in the particular Ra models used. Such calculated flux estimates are in close agreement with results obtained from a 2-day

Groundwater sampling and chemical characterisation of the Laxemar deep borehole KLX02

International Nuclear Information System (INIS)

Laaksoharju, M.; Skaarman, C.; Smellie, J.; Nilsson, A.C.

1995-02-01

The Laxemar deep borehole, KLX02 (1705 m depth), located close to the Aespoe Hard Rock Laboratory (HRL), has been investigated. Groundwater sampling was conducted on two occasions and using different methods. The first sampling was taken in the open borehole using the so-called Tube sampler; the second sampling carried out using the SKB-packer equipment to isolate pre-determined borehole sections. Groundwater compositions consist of two distinct groupings; one shallow to intermediate Sodium-Bicarbonate type (Na(Ca,K):HC 3 Cl(SO 4 )) to a depth of 1000 m, and the other of deep origin, a calcium-chloride type (Ca-Na(K):Cl-SO 4 (Br)), occurring below 1000 m. The deep brines contain up to 46000 mg of Cl per litre. The influence of borehole activities are seen in the tritium data which record significant tritium down to 1000 m, and even to 1420 m. Mixing modelling shows that water from the 1960's is the main source for this tritium. The high tritium values in the 1090-1096.2 m section are due to contamination of 1% shallow water from 1960 and 2% of modern shallow water. The upper 800 m of bedrock at Laxemar lies within a groundwater recharge area; the sub-vertical to moderate angled fracture zones facilitate groundwater circulation to considerable depths, at least to 800 m, thus accounting for some of the low saline brackish groundwaters in these conducting fracture zones. Below 1000 m the system is hydraulically and geochemically 'closed' such that highly saline brines exist in a near-stagnant environment. 30 refs, 22 figs, 8 tabs

Ground-water contamination and legal controls in Michigan

Science.gov (United States)

Deutsch, Morris

1963-01-01

The great importance of the fresh ground-water resources of Michigan is evident because 90 percent of the rural and about 70 percent of the total population of the State exclusive of the Detroit metropolitan area are supplied from underground sources. The water-supply and public-health problems that have been caused by some cases of ground-water contamination in the State illustrate the necessity of protecting this vital resource.Manmade and natural contaminants, including many types of chemical and organic matter, have entered many of the numerous aquifers of the State. Aquifers have been contaminated by waste-laden liquids percolating from the surface or from the zone of aeration and by direct injection to the aquifer itself. Industrial and domestic wastes, septic tanks, leaking sewers, flood waters or other poor quality surface waters, mine waters, solids stored or spread at the surface, and even airborne wastes all have been sources of ground-water contamination in Michigan. In addition, naturally occurring saline waters have been induced into other aquifers by overpumping or unrestricted flow from artesian wells, possibly by dewatering operations, and by the deepening of surface stream channels. Vertical migration of saline waters through open holes from formations underlying various important aquifers also has spoiled some of the fresh ground waters in the State. In spite of the contamination that has occurred, however, the total amount of ground water that has been spoiled is only a small part of the total resource. Neither is the contamination so widespread as that of the surface streams of Michigan.Overall legal authority to control most types of ground-water contamination in the State has been assigned by the Michigan Legislature to the Water Resources Commission, although the Department of Conservation and the Health Department also exercise important water-pollution control functions. The Michigan Supreme Court, in an important case upholding the power

Geochemical and isotopic characterization of groundwater resources in El Hicha region, Gabes, southern Tunisia

International Nuclear Information System (INIS)

Ben Hamouda, M.F.; Ben Kraiem, H.; Mahjoub, A.; Labidi, B.; Ghoudi, R.; Hamrouni, H.; Nasr, H.; Zouari, K.; Froehlich, K.; Sajjad, M.I.; Garcia-Agudo, E.

2002-01-01

The groundwater study area is located in the southern part of Tunisia at some kilometers from the Mediterranean Sea, about 35 km north of the town Gabes. It extends over 300 km 2 and is bounded by the Gulf of Gabes in the East, El Hamma in the West and Skhira in the North. This region is characterized by a semi-arid climate with an average annual rainfall of about 180 mm and a potential evaporation of 2130 mm per year. The groundwater resources of the region are represented by four hydrogeological units: the Continental Intercalaire, the Sfax Aquifer, the Jeffara Aquifer and the shallow aquifer of El Hicha. The dug wells and boreholes used for groundwater abstraction in this region reach depths between a few meters and about 170m. The upper zone of 50m depths is formed by sandy clay and gypsum, and the lower zone of 50 to 70m depths consists of sandy layers. The salinity measured in groundwater samples from this area is rather high; the values range between 5 and 7g/l. Since the water will be used to grow salt-tolerant plants, it is important to know the origin of the groundwater (to assess its availability) and the source(s) of its salinity. To this end, groundwater samples for isotope and chemical analysis were taken from 6 dug wells, 6 boreholes (one of them is an artesian well), a spring and a drainage canal. Each site was sampled in March, June, July, September and December 1999. During these sampling campaigns, in-situ measurements of temperature and electrolytic conductivity were carried out

Geochemical Investigations of Groundwater Stability

International Nuclear Information System (INIS)

Bath, Adrian

2006-05-01

The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in

Chemical interaction of fresh and saline waters with compacted bentonite

International Nuclear Information System (INIS)

Muurinen, A.; Lehikoinen, J.; Melamed, A.; Pitkaenen, P.

1996-01-01

The interaction of compacted sodium bentonite with fresh and saline ground-water simulant was studied. The parameters varied in the experiments were the compositions of the solutions and oxygen and carbon dioxide content in the surroundings. The main interests of the study were the chemical changes in the experimental solution, bentonite porewater and bentonite together with the microstructural properties of bentonite. The major processes with fresh water were the diffusion of sodium, potassium, sulphate, bicarbonate and chloride from bentonite to the solution, and the diffusion of calcium and magnesium from the solution into bentonite. The major processes in the experiments with saline water were the diffusion of the sodium, magnesium, sulphate and bicarbonate from bentonite into the solution, and the diffusion of calcium from the solution into bentonite

Origin and geochemistry of saline spring waters in the Athabasca oil sands region, Alberta, Canada

International Nuclear Information System (INIS)

Gue, Anita E.; Mayer, Bernhard; Grasby, Stephen E.

2015-01-01

Highlights: • Saline groundwater enters the Athabasca and Clearwater rivers in the AOSR via springs. • High TDS is due to subsurface dissolution of Devonian evaporites and carbonates. • Low δ 18 O values, and 3 H and 14 C data suggest some Laurentide glacial meltwater input. • Bacterial sulfate reduction, methanogenesis, and CH 4 oxidation were identified. • Metal and PAH contents are reported; bitumen does not appear to be major influence. - Abstract: The geochemistry of saline spring waters in the Athabasca oil sands region (AOSR) in Alberta (Canada) discharging from Devonian carbonate rocks into the Athabasca and Clearwater rivers was characterized for major ions, trace elements, dissolved gases, and polycyclic aromatic hydrocarbons (PAHs). In addition, stable isotope analyses of H 2 O, SO 4 , dissolved inorganic carbon (DIC), Sr, and CH 4 were used to trace the sources of spring waters and their dissolved solutes, and to identify subsurface processes affecting water chemistry. The spring waters had δ 18 O values as low as −23.5‰, suggesting they are composed of up to 75% Laurentide glacial meltwater. Tritium and radiocarbon age-dating results, analyzed for three spring waters, supported a glacial origin. The high salinity of the spring waters (TDS 7210–51,800 mg/L) was due to dissolution of Devonian evaporite and carbonate deposits in the subsurface. Spring waters were affected by bacterial (dissimilatory) sulfate reduction, methanogenesis, and methane oxidation. Trace elements were present in spring waters at varying concentrations, with only one spring containing several predominant oil sands metals (As, Fe, Mo, Ni, Se, Zn) suggesting bitumen as a source. Five springs contained elements (Al, As, B, Fe, Se) at concentrations exceeding water quality guidelines for the protection of aquatic life. Seven PAHs were detected in spring waters (total PAH concentrations ranged from 7.3 to 273.6 ng/L), but most springs contained a maximum of two PAHs

COLOUR LEARNING IN RETARDED CHILDREN*

African Journals Online (AJOL)

COLOUR LEARNING IN RETARDED CHILDREN* !\\'fRS E. K~SEBOOM, Principal, ADS. LEVIN, M.B., M.R.C.P., D.C.H., Hon. Medical Officer, Hamlet B School for. Retarded Children, Johannesburg. '... silly children, with no understanding .. -'. Jeremiah 4:22. Tt has been observed' that mentally retarded children have.

Water cycle and salinity dynamics in the mangrove forests of Europa and Juan de Nova Islands, southwest Indian Ocean.

Science.gov (United States)

Lambs, Luc; Mangion, Perrine; Mougin, Eric; Fromard, François

2016-01-30

The functioning of mangrove forests found on small coralline islands is characterized by limited freshwater inputs. Here, we present data on the water cycling of such systems located on Europa and Juan de Nova Islands, Mozambique Channel. In order to better understand the water cycle and mangrove growth conditions, we have analysed the hydrological and salinity dynamics of the systems by gauge pressure and isotopic tracing (δ18O and δ2H values). Both islands have important seawater intrusion as measured by the water level change and the high salinities in the karstic ponds. Europa Island displays higher salinity stress, with its inner lagoon, but presents a pluri-specific mangrove species formation ranging from shrub to forest stands. No freshwater signal could be detected around the mangrove trees. On Juan de Nova Island, the presence of sand and detrital sediment allows the storage of some amount of rainfall to form a brackish groundwater. The mangrove surface area is very limited with only small mono-specific stands being present in karstic depression. On the drier Europa Island, the salinity of all the water points is equal to or higher than that of the seawater, and on Juan de Nova the groundwater salinity is lower (5 to 20 PSU). This preliminary study shows that the karstic pothole mangroves exist due to the sea connection through the fractured coral and the high tidal dynamics.

Tidal variability of nutrients in a coastal coral reef system influenced by groundwater

Science.gov (United States)

Wang, Guizhi; Wang, Shuling; Wang, Zhangyong; Jing, Wenping; Xu, Yi; Zhang, Zhouling; Tan, Ehui; Dai, Minhan

2018-02-01

To investigate variation in nitrite, nitrate, phosphate, and silicate in a spring-neap tide in a coral reef system influenced by groundwater discharge, we carried out a time-series observation of these nutrients and 228Ra, a tracer of groundwater discharge, in the Luhuitou fringing reef at Sanya Bay in the South China Sea. The maximum 228Ra, 45.3 dpm 100 L-1, appeared at low tide and the minimum, 14.0 dpm 100 L-1, appeared during a flood tide in the spring tide. The activity of 228Ra was significantly correlated with water depth and salinity in the spring-neap tide, reflecting the tidal-pumping feature of groundwater discharge. Concentrations of all nutrients exhibited strong diurnal variation, with a maximum in the amplitude of the diel change for nitrite, nitrate, phosphate, and silicate in the spring tide of 0.46, 1.54, 0.12, and 2.68 µM, respectively. Nitrate and phosphate were negatively correlated with water depth during the spring tide but showed no correlation during the neap tide. Nitrite was positively correlated with water depth in the spring and neap tide due to mixing of nitrite-depleted groundwater and nitrite-rich offshore seawater. They were also significantly correlated with salinity (R2 ≥ 0.9 and P reef system was closely related with biological processes during both tidal periods, but the biological influence appeared to be less dominant, as inferred from the less significant correlations (R2 = 0.16) during the spring tide when groundwater discharge was more prominent. Thus, the variability of nutrients in the coral reef system was regulated mainly by biological uptake and release in a spring-neap tide and impacted by mixing of tidally driven groundwater and offshore seawater during spring tide.

Research on flame retardation of wool fibers

International Nuclear Information System (INIS)

Enomoto, Ichiro; Ametani, Kazuo; Sawai, Takeshi

1990-01-01

Flame retardant, vinyl phosphonate oligomer, was uniformly impregnated in wool fibers, and by irradiating low energy electron beam or cobalt-60 gamma ray, the flame retardation of fabrics was attempted, as the results, the following knowledges were obtained. At the rate of sticking of flame retardant lower than that in cotton fabrics, sufficient flame retarding property can be given. The flame retarding property withstands 30 times of washing. The lowering of strength due to the processing hardly arose. For the flame retardation, gamma-ray was more effective than electron beam. Since the accidents of burning clothes have occurred frequently, their flame retardation has been demanded. So far the flame retardation of cotton fabrics has been advanced, but this time the research on the flame retardation of wool fabrics was carried out by the same method. The experimental method is explained. As for the performance of the processed fabrics, the rate of sticking of the flame retardant, the efficiency of utilization, the flame retarding property, the endurance in washing and the tensile and tearing strength were examined. As the oxygen index was higher, the flame retarding property was higher, and in the case of the index being more than 27, the flame retarding property is sufficient, that is, the rate of sticking of 6% in serge and 5% in muslin. (K.I.)

Modeling groundwater quality in an arid agricultural environment in the face of an uncertain climate: the case of Mewat District, India

Science.gov (United States)

Weber, M. C.; Ward, A. S.; Muste, M.

2014-12-01

The salinization of groundwater resources is a widespread problem in arid agricultural environments. In Mewat District (Haryana, India), groundwater salinity has rendered much of the accessible supply unfit for human consumption or agriculture. Historically, this closed basin retained fresh pockets of water at the foothills of the Aravalli Hills, where monsoonal precipitation runoff from the mountains was recharged through infiltration or facilitated by man-made structures. To date, an increasing number of pumps supply the region with fresh water for consumption and agriculture leading to shrinking the freshwater zone at an accelerated pace. The potential for increased human consumption corroborated with the effects of climate change bring uncertainty about the future of water security for the Mewat communities, most of them critically bound to the existence of local water. This study addresses the sustainability of the freshwater supply under a range of land interventions and climate scenarios, using a 2-D groundwater flow and transport model. Our results quantify potential futures for this arid, groundwater-dependent location, using numerical groundwater modeling to quantify interactions between human water use, infrastructure, and climate. Outcomes of this modeling study will inform an NGO active in the area on sustainable management of groundwater resources.

Flame retardancy and thermal degradation of cotton textiles based on UV-curable flame retardant coatings

Energy Technology Data Exchange (ETDEWEB)

Xing, Weiyi [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzai Road, Hefei, Anhui 230026 (China); Suzhou Institute for Advanced Study, University of Science and Technology of China, 166 Ren' ai Road, Suzhou, Jiangsu 215123 (China); Jie, Ganxin [State Key Laboratory of Environmental Adaptability for Industrial Products, China National Electric Apparatus Research Institute, Guangzhou 510300 (China); Song, Lei; Hu, Shuang; Lv, Xiaoqi; Wang, Xin [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzai Road, Hefei, Anhui 230026 (China); Hu, Yuan, E-mail: yuanhu@ustc.edu.cn [State Key Laboratory of Fire Science, University of Science and Technology of China, 96 Jinzai Road, Hefei, Anhui 230026 (China); Suzhou Institute for Advanced Study, University of Science and Technology of China, 166 Ren' ai Road, Suzhou, Jiangsu 215123 (China)

2011-01-20

The flame retardant coatings were prepared through UV-curable technique using tri(acryloyloxyethyl) phosphate (TAEP) and triglycidyl isocyanurate acrylate (TGICA). Results from FTIR-ATR spectroscopy and scanning electron microscopy (SEM) showed that flame retardant coatings were successfully coated onto the surface of cotton fabrics. The flame retardancy of the treated fabrics was studied by Micro-scale Combustion Calorimeter (MCC) and limited oxygen index (LOI). The cottons coated flame retardant coatings had the lower peak heat release rate (PHRR), heat release capacity (HRC), total heat of combustion (THC) and higher LOI value compared with untreated cotton. The results from TGA test showed that the flame retardant coatings lowered the decomposition temperature of treated fabric. The thermal decomposition of cottons was monitored by real time FTIR analysis and thermogravimetric analysis/infrared spectrometry (TGA-IR). The enhanced flame retardant action might be caused by thermal decomposition of TAEP structure, producing acidic intermediates, which could react with fabrics to alter its thermal decomposition process.

Effects of Groundwater Development on Uranium: Central Valley, California, USA

Science.gov (United States)

Jurgens, B.C.; Fram, M.S.; Belitz, K.; Burow, K.R.; Landon, M.K.

2010-01-01

Uranium (U) concentrations in groundwater in several parts of the eastern San Joaquin Valley, California, have exceeded federal and state drinking water standards during the last 20 years. The San Joaquin Valley is located within the Central Valley of California and is one of the most productive agricultural areas in the world. Increased irrigation and pumping associated with agricultural and urban development during the last 100 years have changed the chemistry and magnitude of groundwater recharge, and increased the rate of downward groundwater movement. Strong correlations between U and bicarbonate suggest that U is leached from shallow sediments by high bicarbonate water, consistent with findings of previous work in Modesto, California. Summer irrigation of crops in agricultural areas and, to lesser extent, of landscape plants and grasses in urban areas, has increased Pco2 concentrations in the soil zone and caused higher temperature and salinity of groundwater recharge. Coupled with groundwater pumping, this process, as evidenced by increasing bicarbonate concentrations in groundwater over the last 100 years, has caused shallow, young groundwater with high U concentrations to migrate to deeper parts of the groundwater system that are tapped by public-supply wells. Continued downward migration of U-affected groundwater and expansion of urban centers into agricultural areas will likely be associated with increased U concentrations in public-supply wells. The results from this study illustrate the potential long-term effects of groundwater development and irrigation-supported agriculture on water quality in arid and semiarid regions around the world. Journal compilation ?? 2009 National Ground Water Association. No claim to original US government works.

Impact of hydrological alterations on river-groundwater exchange and water quality in a semi-arid area: Nueces River, Texas.

Science.gov (United States)

Murgulet, Dorina; Murgulet, Valeriu; Spalt, Nicholas; Douglas, Audrey; Hay, Richard G

2016-12-01

There is a lack of understanding and methods for assessing the effects of anthropogenic disruptions, (i.e. river fragmentation due to dam construction) on the extent and degree of groundwater-surface water interaction and geochemical processes affecting the quality of water in semi-arid, coastal catchments. This study applied a novel combination of electrical resistivity tomography (ERT) and elemental and isotope geochemistry in a coastal river disturbed by extended drought and periodic flooding due to the operation of multiple dams. Geochemical analyses show that the saltwater barrier causes an increase in salinity in surface water in the downstream river as a result of limited freshwater inflows, strong evaporation effects on shallow groundwater and mostly stagnant river water, and is not due to saltwater intrusion by tidal flooding. Discharge from bank storage is dominant (~84%) in the downstream fragment and its contribution could increase salinity levels within the hyporheic zone and surface water. When surface water levels go up due to upstream freshwater releases the river temporarily displaces high salinity water trapped in the hyporheic zone to the underlying aquifer. Geochemical modeling shows a higher contribution of distant and deeper groundwater (~40%) in the upstream river and lower discharge from bank storage (~13%) through the hyporheic zone. Recharge from bank storage is a source of high salt to both upstream and downstream portions of the river but its contribution is higher below the dam. Continuous ERT imaging of the river bed complements geochemistry findings and indicate that while lithologically similar, downstream of the dam, the shallow aquifer is affected by salinization while fresher water saturates the aquifer in the upstream fragment. The relative contribution of flows (i.e. surface water releases or groundwater discharge) as related to the river fragmentation control changes of streamwater chemistry and likely impact the interpretation

Tidal variability of nutrients in a coastal coral reef system influenced by groundwater

Directory of Open Access Journals (Sweden)

G. Wang

2018-02-01

Full Text Available To investigate variation in nitrite, nitrate, phosphate, and silicate in a spring–neap tide in a coral reef system influenced by groundwater discharge, we carried out a time-series observation of these nutrients and 228Ra, a tracer of groundwater discharge, in the Luhuitou fringing reef at Sanya Bay in the South China Sea. The maximum 228Ra, 45.3 dpm 100 L−1, appeared at low tide and the minimum, 14.0 dpm 100 L−1, appeared during a flood tide in the spring tide. The activity of 228Ra was significantly correlated with water depth and salinity in the spring–neap tide, reflecting the tidal-pumping feature of groundwater discharge. Concentrations of all nutrients exhibited strong diurnal variation, with a maximum in the amplitude of the diel change for nitrite, nitrate, phosphate, and silicate in the spring tide of 0.46, 1.54, 0.12, and 2.68 µM, respectively. Nitrate and phosphate were negatively correlated with water depth during the spring tide but showed no correlation during the neap tide. Nitrite was positively correlated with water depth in the spring and neap tide due to mixing of nitrite-depleted groundwater and nitrite-rich offshore seawater. They were also significantly correlated with salinity (R2  ≥  0.9 and P < 0.05 at the ebb flow of the spring tide, negative for nitrate and phosphate and positive for nitrite, indicating the mixing of nitrite-depleted, nitrate- and phosphate-rich less saline groundwater and nitrite-rich, nitrate- and phosphate-depleted saline offshore seawater. We quantified variation in oxidized nitrogen (NOx and phosphate contributed by biological processes based on deviations from mixing lines of these nutrients. During both the spring and neap tide biologically contributed NOx and phosphate were significantly correlated with regression slopes of 4.60 (R2  =  0.16 in the spring tide and 13.4 (R2  =  0.75 in the neap tide, similar to the composition of these

Recharge behavior to groundwater in the command area of Heran distributary, Sanghar, Sindh

International Nuclear Information System (INIS)

Lashari, B.K.

2004-01-01

Determination of net recharge to the groundwater is of prime importance while managing irrigation and drainage system of the area. Without knowing the groundwater and recharge both systems irrigation and drainage, are two sides of one coin may mislead. In order to determine net recharge to the groundwater, the data of important parameters such as irrigation delivery at head of the channel, total losses, crop water requirement, water table fluctuation, operation hours of tube wells and surface drain discharge and shallow as well as deep ground water quality were measured for Rabi season (November, 1999 to March, 2000). Using different approaches such as actual observation of inflow and outflow components, change of water table and SURFER (Software), the net recharge was determined. Results have shown that in Rabi season, the groundwater is recharged except in the month of January (canal closure period) and March, depending on various irrigation and drainage factors, which are complex. Shallow groundwater quality was observed good and use able due to recharge by surface water. About 41 % of command area was under shallow water table with salinity of water 300-800 ppm, 29 % was under water quality of 800-1300 ppm, 9% was between 1800-2300 ppm and rest 12% of the area was observed more than 2300 ppm. The quality of fresh water pump lifting water from the depth of 40 ft was up to 2400 ppm and deeper pump water quality was about 25000 ppm in scavenger and saline tube wells. Average water table was about 3.0 ft and fluctuation was between 2.38-3.8 feet in spite of running the tube wells.(author)

Pressure Retarded Osmosis (PRO): Past experiences, current developments, and future prospects

KAUST Repository

Sarp, S.; Li, Z.; Saththasivam, J.

2016-01-01

Pressure Retarded Osmosis (PRO) has attracted worldwide attention with respect to its salinity gradient energy production potential, and low energy desalination applications. PRO processes, which use Seawater Reverse Osmosis (SWRO) brine as draw solutions, have a higher potential of being applied to any new, and existing membrane based seawater desalination systems, as an energy production and/or conservation process. Hydraulic pressure is applied on a high salinity draw solution, and the hydraulic pressure of the high salinity draw solution can be kept relatively constant during operation, even though the volumetric flow rate is to be increased. Therefore, the draw side of the PRO process can be considered near-isobaric, in most cases. The harvested Gibbs free energy of mixing, and the volumetric expansion can explain this near-isobaric behavior of the draw side in the PRO process. Thus, PRO can be used to multiply the internal energy of the draw solution with respect to the ratio of the permeated water flux. Even though PRO has very high theoretical potential for energy production and/or recovery, there are several shortcomings, which should be answered before the realization of the scale up applications, such as; thermodynamic process optimization, high power density membranes, and high efficiency hydraulic pressure conversion and recovery systems. This review gives detailed information about the PRO process including; (1) theoretical background, (2) membranes for PRO, (3) experimental and large scale applications, and (4) economic feasibility of PRO applications.

Pressure Retarded Osmosis (PRO): Past experiences, current developments, and future prospects

KAUST Repository

Sarp, S.

2016-01-16

Pressure Retarded Osmosis (PRO) has attracted worldwide attention with respect to its salinity gradient energy production potential, and low energy desalination applications. PRO processes, which use Seawater Reverse Osmosis (SWRO) brine as draw solutions, have a higher potential of being applied to any new, and existing membrane based seawater desalination systems, as an energy production and/or conservation process. Hydraulic pressure is applied on a high salinity draw solution, and the hydraulic pressure of the high salinity draw solution can be kept relatively constant during operation, even though the volumetric flow rate is to be increased. Therefore, the draw side of the PRO process can be considered near-isobaric, in most cases. The harvested Gibbs free energy of mixing, and the volumetric expansion can explain this near-isobaric behavior of the draw side in the PRO process. Thus, PRO can be used to multiply the internal energy of the draw solution with respect to the ratio of the permeated water flux. Even though PRO has very high theoretical potential for energy production and/or recovery, there are several shortcomings, which should be answered before the realization of the scale up applications, such as; thermodynamic process optimization, high power density membranes, and high efficiency hydraulic pressure conversion and recovery systems. This review gives detailed information about the PRO process including; (1) theoretical background, (2) membranes for PRO, (3) experimental and large scale applications, and (4) economic feasibility of PRO applications.

Remote Sensing Monitoring of Changes in Soil Salinity: A Case Study in Inner Mongolia, China

Directory of Open Access Journals (Sweden)

Jingwei Wu

2008-11-01

Full Text Available This study used archived remote sensing images to depict the history of changes in soil salinity in the Hetao Irrigation District in Inner Mongolia, China, with the purpose of linking these changes with land and water management practices and to draw lessons for salinity control. Most data came from LANDSAT satellite images taken in 1973, 1977, 1988, 1991, 1996, 2001, and 2006. In these years salt-affected areas were detected using a normal supervised classification method. Corresponding cropped areas were detected from NVDI (Normalized Difference Vegetation Index values using an unsupervised method. Field samples and agricultural statistics were used to estimate the accuracy of the classification. Historical data concerning irrigation/drainage and the groundwater table were used to analyze the relation between changes in soil salinity and land and water management practices. Results showed that: (1 the overall accuracy of remote sensing in detecting soil salinity was 90.2%, and in detecting cropped area, 98%; (2 the installation/innovation of the drainage system did help to control salinity; and (3 a low ratio of cropped land helped control salinity in the Hetao Irrigation District. These findings suggest that remote sensing is a useful tool to detect soil salinity and has potential in evaluating and improving land and water management practices.

Remote Sensing Monitoring of Changes in Soil Salinity: A Case Study in Inner Mongolia, China.

Science.gov (United States)

Wu, Jingwei; Vincent, Bernard; Yang, Jinzhong; Bouarfa, Sami; Vidal, Alain

2008-11-07

This study used archived remote sensing images to depict the history of changes in soil salinity in the Hetao Irrigation District in Inner Mongolia, China, with the purpose of linking these changes with land and water management practices and to draw lessons for salinity control. Most data came from LANDSAT satellite images taken in 1973, 1977, 1988, 1991, 1996, 2001, and 2006. In these years salt-affected areas were detected using a normal supervised classification method. Corresponding cropped areas were detected from NVDI (Normalized Difference Vegetation Index) values using an unsupervised method. Field samples and agricultural statistics were used to estimate the accuracy of the classification. Historical data concerning irrigation/drainage and the groundwater table were used to analyze the relation between changes in soil salinity and land and water management practices. Results showed that: (1) the overall accuracy of remote sensing in detecting soil salinity was 90.2%, and in detecting cropped area, 98%; (2) the installation/innovation of the drainage system did help to control salinity; and (3) a low ratio of cropped land helped control salinity in the Hetao Irrigation District. These findings suggest that remote sensing is a useful tool to detect soil salinity and has potential in evaluating and improving land and water management practices.

Isotopic and chemical composition of groundwater in the Bolivian Altiplano, present space evolution records hydrologic conditions since 11,000 Yr

International Nuclear Information System (INIS)

Coudrain, A.; Talbi, A.; Loubet, M.; Gallaire, R.; Jusserand, C.; Ramirez, E.; Ledoux, E.

1999-01-01

The phreatic aquifer of the central Altiplano shows a Cl concentration that increases from 0.5 meq l -1 upstream to 150 meq l -1 downstream. The main outflow process from the aquifer is the upward flow E into the unsaturated zone associated to evaporation close to soil surface. A relation has been established for any arid zone areas on the base of isotopic profiles: E (mm yr -1 ) = 63 Z -1.5 where Z (m) is the water table depth under soil surface. The aquifer under study may have acquired its high chlorine content during last lacustrine phase (Tauca, 12 ka BP). Arguments for this hypothesis are: (i) maximum level of the lake (3780 m) higher than present soil elevation in the area, (ii) same order of salinity in the paleolake and in the more saline groundwater, (iii) weak molar ratio of Li/Cl in saline groundwater and in the Tauca, (iv) modelling of Cl transport over 11,000 years consistent with observed spatial evolution of Cl in groundwater. To this scenario, might be superimposed the assumption of a delay for the convective transfer of salt towards south by the coupled effects of accumulation of salt in the unsaturated zone by evaporation from the aquifer during thousand or so years, and of the subsequent return of this salt downwards to the aquifer during some short rainy periods. The 87 Sr/ 86 Sr, major and trace element compositions of surface and groundwater support this proposed scenario. (author)

Low salinity hydrocarbon water disposal through deep subsurface drip irrigation: leaching of native selenium

Science.gov (United States)

Bern, Carleton R.; Engle, Mark A.; Boehlke, Adam R.; Zupancic, John W.; Brown, Adrian; Figueroa, Linda; Wolkersdorfer, Christian

2013-01-01

A subsurface drip irrigation system is being used in Wyoming’s Powder River Basin that treats high sodium, low salinity, coal bed methane (CBM) produced water with sulfuric acid and injects it into cropped fields at a depth of 0.92 m. Dissolution of native gypsum releases calcium that combats soil degradation that would otherwise result from high sodium water. Native selenium is leached from soil by application of the CBM water and traces native salt mobilization to groundwater. Resulting selenium concentrations in groundwater at this alluvial site were generally low (0.5–23 μg/L) compared to Wyoming’s agricultural use suitability standard (20 μg/L).

Local Equilibrium and Retardation Revisited.

Science.gov (United States)

Hansen, Scott K; Vesselinov, Velimir V

2018-01-01

In modeling solute transport with mobile-immobile mass transfer (MIMT), it is common to use an advection-dispersion equation (ADE) with a retardation factor, or retarded ADE. This is commonly referred to as making the local equilibrium assumption (LEA). Assuming local equilibrium, Eulerian textbook treatments derive the retarded ADE, ostensibly exactly. However, other authors have presented rigorous mathematical derivations of the dispersive effect of MIMT, applicable even in the case of arbitrarily fast mass transfer. We resolve the apparent contradiction between these seemingly exact derivations by adopting a Lagrangian point of view. We show that local equilibrium constrains the expected time immobile, whereas the retarded ADE actually embeds a stronger, nonphysical, constraint: that all particles spend the same amount of every time increment immobile. Eulerian derivations of the retarded ADE thus silently commit the gambler's fallacy, leading them to ignore dispersion due to mass transfer that is correctly modeled by other approaches. We then present a particle tracking simulation illustrating how poor an approximation the retarded ADE may be, even when mobile and immobile plumes are continually near local equilibrium. We note that classic "LEA" (actually, retarded ADE validity) criteria test for insignificance of MIMT-driven dispersion relative to hydrodynamic dispersion, rather than for local equilibrium. Published 2017. This article is a U.S. Government work and is in the public domain in the USA.

The long-term impacts of anthropogenic and natural processes on groundwater deterioration in a multilayered aquifer.

Science.gov (United States)

Sheikhy Narany, Tahoora; Sefie, Anuar; Aris, Ahmad Zaharin

2018-07-15

In many regions around the world, there are issues associated with groundwater resources due to human and natural factors. However, the relation between these factors is difficult to determine due to the large number of parameters and complex processes required. In order to understand the relation between land use allocations, the intrinsic factors of the aquifer, climate change data and groundwater chemistry in the multilayered aquifer system in Malaysia's Northern Kelantan Basin, twenty-two years hydrogeochemical data set was used in this research. The groundwater salinisation in the intermediate aquifer, which mainly extends along the coastal line, was revealed through the hydrogeochemical investigation. Even so, there had been no significant trend detected on groundwater salinity from 1989 to 2011. In contrast to salinity, as seen from the nitrate contaminations there had been significantly increasing trends in the shallow aquifer, particularly in the central part of the study area. Additionally, a strong association between high nitrate values and the areas covered with palm oil cultivations and mixed agricultural have been detected by a multiple correspondence analysis (MCA), which implies that the increasing nitrate concentrations are associated with nitrate loading from the application of N-fertilisers. From the process of groundwater salinisation in the intermediate aquifer, could be seen that it has a strong correlation the aquifer lithology, specifically marine sediments which are influenced by the ancient seawater trapped within the sediments. Copyright © 2018 Elsevier B.V. All rights reserved.

Coastal Water Quality Modeling in Tidal Lake: Revisited with Groundwater Intrusion

Science.gov (United States)

Kim, C.

2016-12-01

A new method for predicting the temporal and spatial variation of water quality, with accounting for a groundwater effect, has been proposed and applied to a water body partially connected to macro-tidal coastal waters in Korea. The method consists of direct measurement of environmental parameters, and it indirectly incorporates a nutrients budget analysis to estimate the submarine groundwater fluxes. Three-dimensional numerical modeling of water quality has been used with the directly collected data and the indirectly estimated groundwater fluxes. The applied area is Saemangeum tidal lake that is enclosed by 33km-long sea dyke with tidal openings at two water gates. Many investigations of groundwater impact reveal that 10 50% of nutrient loading in coastal waters comes from submarine groundwater, particularly in the macro-tidal flat, as in the west coast of Korea. Long-term monitoring of coastal water quality signals the possibility of groundwater influence on salinity reversal and on the excess mass outbalancing the normal budget in Saemangeum tidal lake. In the present study, we analyze the observed data to examine the influence of submarine groundwater, and then a box model is demonstrated for quantifying the influx and efflux. A three-dimensional numerical model has been applied to reproduce the process of groundwater dispersal and its effect on the water quality of Saemangeum tidal lake. The results show that groundwater influx during the summer monsoon then contributes significantly, 20% more than during dry season, to water quality in the tidal lake.

Hydrogeological, petrophysical and hydrogeochemical characteristics of the groundwater aquifers east of Wadi El-Natrun, Egypt

Directory of Open Access Journals (Sweden)

Zenhom E. Salem

2016-06-01

The concentrations of TDS and the dissolved elements are higher in the shallow groundwater compared to the deeper one, which could be related to soil salinity and evaporation processes. Ion exchange, water–rock interaction and evaporation processes are the main geochemical processes affecting the chemistry of the studied groundwater. Sodium chloride/bicarbonate types are the most common chemical types in the study area. Most of the water samples are of old meteoric origin (Na2SO4 type and old marine origin (MgCl2 type. On the basis of SAR and EC values it is concluded that most of the groundwater samples are suitable for irrigation purposes.

Development of A Mississippi River Alluvial Aquifer Groundwater Model

Science.gov (United States)

Karakullukcu, R. E.; Tsai, F. T. C.; Bhatta, D.; Paudel, K.; Kao, S. C.

2017-12-01

The Mississippi River Alluvial Aquifer (MRAA) underlies the Mississippi River Valley of the northeastern Louisiana, extending from the north border of Louisiana and Arkansas to south central of Louisiana. The MRAA has direct contact with the Mississippi River. However, the interaction between the Mississippi River and the alluvial aquifer is largely unknown. The MRAA is the second most used groundwater source in Louisiana's aquifers with about 390 million gallons per day, which is about 25% of all groundwater withdrawals in Louisiana. MRAA is the major water source to agriculture in the northeastern Louisiana. The groundwater withdrawals from the MRAA increases annually for irrigation. High groundwater pumping has caused significant groundwater level decline and elevated salinity in the aquifer. Therefore, dealing with agricultural irrigation is the primary purpose for managing the MRAA. The main objective of this study is to develop a groundwater model as a tool for the MRAA groundwater management. To do so, a hydrostratigraphy model of the MRAA was constructed by using nearly 8,000 drillers' logs and electric logs collected from Louisiana Department of Natural Resources. The hydrostratigraphy model clearly shows that the Mississippi River cuts into the alluvial aquifer. A grid generation technique was developed to convert the hydrostratigraphy model into a MODFLOW model with 12 layers. A GIS-based method was used to estimate groundwater withdrawals for irrigation wells based on the crop location and acreage from the USDACropScape - Cropland Data Layer. Results from the Variable Infiltration Capacity (VIC) model were used to determine potential recharge. NHDPlusV2 data was used to determine water level for major streams for the MODFLOW River Package. The groundwater model was calibrated using groundwater data between 2004 and 2015 to estimate aquifer hydraulic conductivity, specific yield, specific storage, river conductance, and surficial recharge.

Optical tool for salinity detection by remote sensing spectroscopy: application on Oran watershed, Algeria

Science.gov (United States)

Abdellatif, Dehni; Mourad, Lounis

2017-07-01

Soil salinity is a complex problem that affects groundwater aquifers and agricultural lands in the semiarid regions. Remote sensing and spectroscopy database systems provide accuracy for salinity autodetection and dynamical delineation. Salinity detection techniques using polychromatic wavebands by field geocomputation and experimental data are time consuming and expensive. This paper presents an automated spectral detection and identification of salt minerals using a monochromatic waveband concept from multispectral bands-Landsat 8 Operational Land Imager (OLI) and Thermal InfraRed Sensor (TIRS) and spectroscopy United States Geological Survey database. For detecting mineral salts related to electrolytes, such as electronical and vibrational transitions, an integrated approach of salinity detection related to the optical monochromatic concept has been addressed. The purpose of this paper is to discriminate waveband intrinsic spectral similarity using the Beer-Lambert and Van 't Hoff laws for spectral curve extraction such as transmittance, reflectance, absorbance, land surface temperature, molar concentration, and osmotic pressure. These parameters are primordial for hydrodynamic salinity modeling and continuity identification using chemical and physical approaches. The established regression fitted models have been addressed for salt spectroscopy validation for suitable calibration and validation. Furthermore, our analytical tool is conducted for better decision interface using spectral salinity detection and identification in the Oran watershed, Algeria.

Issues of Sustainability of Coastal Groundwater Resources: Benin, West Africa

Directory of Open Access Journals (Sweden)

Andrew D. Mullen

2010-08-01

Full Text Available The largest city in Benin, West Africa (Cotonou, is reliant upon groundwater for its public water supply. This groundwater is derived from the Godomey well field which is located approximately 5 Km north of the coast of the Atlantic Ocean and in close proximity to Lake Nokoue—a shallow lake containing water with elevated concentration of chloride and other elements. Historical data indicate increased chloride concentration in a number of wells nearest to the lake, with unknown contribution from groundwater encroachment from the coastal area. Hence, there is substantial interest in better characterizing this groundwater system for the purpose of determining appropriate management practices and degree of sustainability. Among the efforts attempted to date are a series of numerical models ranging from assessment of flow to a recent effort to include density-dependent transport from the lake. In addition, substantial field characterization has been pursued including assessment of shallow water chemistry along the region of the coastal lagoon and border of the lake, characterization of hydraulic response to pumpage in the aquifer system, estimation of the distribution of electrical resistivity with depth along the coastal lagoons, and installation of multi-level piezometers at seven locations in the lake. When integrated across methods, these numerical and field results indicate that the lake remains a primary concern in terms of a source of salinity in the aquifer. Further, the coastal region appears to be more complex than previously suggested and may represent a future source of salt-water encroachment as suggested by current presence of saline waters at relatively shallow depths along the coast. Finally, hydraulic testing suggests that both natural and pumping-based fluctuations in water levels are present in this system. Substantial additional characterization and modeling efforts may provide a significantly greater understanding of the

Natural and human drivers of salinity in reservoirs and their implications in water supply operation through a Decision Support System

Science.gov (United States)

Contreras, Eva; Gómez-Beas, Raquel; Linares-Sáez, Antonio

2016-04-01

Salt can be a problem when is originally in aquifers or when it dissolves in groundwater and comes to the ground surface or flows into streams. The problem increases in lakes hydraulically connected with aquifers affecting water quality. This issue is even more alarming when water resources are used for urban and irrigation supply and water quantity and quality restrict that water demand. This work shows a data based and physical modeling approach in the Guadalhorce reservoir, located in southern Spain. This water body receives salt contribution from mainly groundwater flow, getting salinity values in the reservoir from 3500 to 5500 μScm-1. Moreover, Guadalhorce reservoir is part of a complex system of reservoirs fed from the Guadalhorce River that supplies all urban, irrigation, tourism, energy and ecology water uses, which makes that implementation and validation of methods and tools for smart water management is required. Meteorological, hydrological and water quality data from several monitoring networks and data sources, with both historical and real time data during a 40-years period, were used to analyze the impact salinity. On the other hand, variables that mainly depend on the dam operation, such as reservoir water level and water outflow, were also analyzed to understand how they affect to salinity in depth and time. Finally surface and groundwater inflows to the reservoir were evaluated through a physically based hydrological model to forecast when the major contributions take place. Reservoir water level and surface and groundwater inflows were found to be the main drivers of salinity in the reservoir. When reservoir water level is high, daily water inflow around 0.4 hm3 causes changes in salinity (both drop and rise) up to 500 μScm-1, but no significant changes are found when water level falls 2-3 m. However the gradual water outflows due to dam operation and consequent decrease in reservoir water levels makes that, after dry periods, salinity

Using SWAT-MODFLOW to simulate groundwater flow and groundwater-surface water interactions in an intensively irrigated stream-aquifer system

Science.gov (United States)

Wei, X.; Bailey, R. T.

2017-12-01

Agricultural irrigated watersheds in semi-arid regions face challenges such as waterlogging, high soil salinity, reduced crop yield, and leaching of chemical species due to extreme shallow water tables resulting from long-term intensive irrigation. Hydrologic models can be used to evaluate the impact of land management practices on water yields and groundwater-surface water interactions in such regions. In this study, the newly developed SWAT-MODFLOW, a coupled surface/subsurface hydrologic model, is applied to a 950 km2 watershed in the Lower Arkansas River Valley (southeastern Colorado). The model accounts for the influence of canal diversions, irrigation applications, groundwater pumping, and earth canal seepage losses. The model provides a detailed description of surface and subsurface flow processes, thereby enabling detailed description of watershed processes such as runoff, infiltration, in-streamflow, three-dimensional groundwater flow in a heterogeneous aquifer system with sources and sinks (e.g. pumping, seepage to subsurface drains), and spatially-variable surface and groundwater exchange. The model was calibrated and tested against stream discharge from 5 stream gauges in the Arkansas River and its tributaries, groundwater levels from 70 observation wells, and evapotranspiration (ET) data estimated from satellite (ReSET) data during the 1999 to 2007 period. Since the water-use patterns within the study area are typical of many other irrigated river valleys in the United States and elsewhere, this modeling approach is transferable to other regions.

Isotopic and geochemical tracers in the evaluation of groundwater residence time and salinization problems at Santiago Island, Cape Verde

International Nuclear Information System (INIS)

Carreira, Paula M.; Nunes, Dina; Marques, Jose M.; Monteiro Santos, Fernando A.; Goncalves, Rui; Pina, Antonio; Mota Gomes, Antonio

2013-01-01

Stable isotopes (δ 18 O, δ 2 H) and tritium ( 3 H), together with geochemistry and geophysical data, were used for evaluating groundwater recharge sources, flow paths, and residence times in a watershed on Santiago Island, Cape Verde, West Africa. Stable isotopes indicate the predominance of high-elevation precipitation that undergoes little evaporation prior to groundwater recharge. Low tritium concentrations at seven sampling sites indicate groundwater residence times greater than 50 years. Higher tritium values at other locations suggest more recent recharge. Young ages indicate local recharge and potential groundwater vulnerability to surface contamination and/or salt-water intrusion. Geochemical results indicate that water-rock interaction mechanisms are the major processes responsible for the groundwater quality (mainly calcium-bicarbonate type), reflecting the lithological composition of subsurface soil. (authors)

Isotopic and geochemical tracers in the evaluation of groundwater residence time and salinization problems at Santiago Island, Cape Verde

Energy Technology Data Exchange (ETDEWEB)

Carreira, Paula M.; Nunes, Dina [Quimica Analitica e Ambiental, IST/ITN, Universidade Tecnica de Lisboa, Estrada Nacional no. 10, 2686-953 Sacavem (Portugal); Marques, Jose M. [Centro de Petrologia e Geoquimica. Instituto Superior Tecnico, UTL, Av. Rovisco Pais, 1049-001 Lisboa (Portugal); Monteiro Santos, Fernando A. [Universidade de Lisboa-IDL, 1749-016 Lisboa (Portugal); Goncalves, Rui [Inst. Politecnico de Tomar, Quinta do Contador, Estrada da Serra, 2300 Tomar (Portugal); Pina, Antonio; Mota Gomes, Antonio [Instituto Superior de Educacao, Praia, Santiago (Cape Verde)

2013-07-01

Stable isotopes (δ{sup 18}O, δ{sup 2}H) and tritium ({sup 3}H), together with geochemistry and geophysical data, were used for evaluating groundwater recharge sources, flow paths, and residence times in a watershed on Santiago Island, Cape Verde, West Africa. Stable isotopes indicate the predominance of high-elevation precipitation that undergoes little evaporation prior to groundwater recharge. Low tritium concentrations at seven sampling sites indicate groundwater residence times greater than 50 years. Higher tritium values at other locations suggest more recent recharge. Young ages indicate local recharge and potential groundwater vulnerability to surface contamination and/or salt-water intrusion. Geochemical results indicate that water-rock interaction mechanisms are the major processes responsible for the groundwater quality (mainly calcium-bicarbonate type), reflecting the lithological composition of subsurface soil. (authors)

Geochemical Investigations of Groundwater Stability

Energy Technology Data Exchange (ETDEWEB)

Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

2006-05-15

The report describes geochemical parameters and methods that provide information about the hydrodynamic stability of groundwaters in low permeability fractured rocks that are potential hosts for radioactive waste repositories. Hydrodynamic stability describes the propensity for changes in groundwater flows over long timescales, in terms of flow rates and flow directions. Hydrodynamic changes may also cause changes in water compositions, but the related issue of geochemical stability of a potential repository host rock system is outside the scope of this report. The main approaches to assessing groundwater stability are numerical modelling, measurement and interpretation of geochemical indicators in groundwater compositions, and analyses and interpretations of secondary minerals and fluid inclusions in these minerals. This report covers the latter two topics, with emphasis on geochemical indicators. The extent to which palaeohydrogeology and geochemical stability indicators have been used in past safety cases is reviewed. It has been very variable, both in terms of the scenarios considered, the stability indicators considered and the extent to which the information was explicitly or implicitly used in assessing FEPs and scenarios in the safety cases. Geochemical indicators of hydrodynamic stability provide various categories of information that are of hydrogeological relevance. Information about groundwater mixing, flows and water sources is potentially provided by the total salinity of groundwaters, their contents of specific non-reactive solutes (principally chloride) and possibly of other solutes, the stable isotopic ratio of water, and certain characteristics of secondary minerals and fluid inclusions. Information pertaining directly to groundwater ages and the timing of water and solute movements is provided by isotopic systems including tritium, carbon-14, chlorine-36, stable oxygen and hydrogen isotopes, uranium isotopes and dissolved mobile gases in